Asymptotic solutions of magnetohydrodynamics equations near the derivatives discontinuity lines
International Nuclear Information System (INIS)
Asymptotic solutions of one-dimensional and scalar magnetohydrodynamics equations near the derivatives discontinuity lines have been discussed. The equations of magnetohydrodynamics for the cases of finite and infinite conductivities are formulated and the problem of eigenvalues and eigenvectors is solved. The so called transport equations which describe the behaviour of derivatives in solutions of the quasilinear equations have been used to find the asymptotic solutions of the magnetohydrodynamics equations. (S.B.)
Mika Tanda
2015-01-01
We compute alien derivatives of the WKB solutions of the Gauss hypergeometric differential equation with a large parameter and discuss the singularity structures of the Borel transforms of the WKB solution expressed in terms of its alien derivatives.
Institute of Scientific and Technical Information of China (English)
DONG BoQing; JIANG Wei
2008-01-01
This article concerns large time behavior of Ladyzhenskaya model for incompressible viscous flows in R3. Based on linear Lp-Lq estimates, the auxiliary decay properties of the solutions and generalized Gronwall type arguments, some optimal upper and lower bounds for the decay of higher order derivatives of solutions are derived without assuming any decay properties of solutions and using Fourier splitting technology.
Directory of Open Access Journals (Sweden)
Ram K. Saxena
2015-04-01
Full Text Available This article is in continuation of the authors research attempts to derive computational solutions of an unified reaction-diffusion equation of distributed order associated with Caputo derivatives as the time-derivative and Riesz-Feller derivative as space derivative. This article presents computational solutions of distributed order fractional reaction-diffusion equations associated with Riemann-Liouville derivatives of fractional orders as the time-derivatives and Riesz-Feller fractional derivatives as the space derivatives. The method followed in deriving the solution is that of joint Laplace and Fourier transforms. The solution is derived in a closed and computational form in terms of the familiar Mittag-Leffler function. It provides an elegant extension of results available in the literature. The results obtained are presented in the form of two theorems. Some results associated specifically with fractional Riesz derivatives are also derived as special cases of the most general result. It will be seen that in case of distributed order fractional reaction-diffusion, the solution comes in a compact and closed form in terms of a generalization of the Kampé de Fériet hypergeometric series in two variables. The convergence of the double series occurring in the solution is also given.
Spherically Symmetric Solutions in Higher-Derivative Gravity
Lü, H; Pope, C N; Stelle, K S
2015-01-01
Extensions of Einstein gravity with quadratic curvature terms in the action arise in most effective theories of quantised gravity, including string theory. This article explores the set of static, spherically symmetric and asymptotically flat solutions of this class of theories. An important element in the analysis is the careful treatment of a Lichnerowicz-type `no-hair' theorem. From a Frobenius analysis of the asymptotic small-radius behaviour, the solution space is found to split into three asymptotic families, one of which contains the classic Schwarzschild solution. These three families are carefully analysed to determine the corresponding numbers of free parameters in each. One solution family is capable of arising from coupling to a distributional shell of matter near the origin; this family can then match on to an asymptotically flat solution at spatial infinity without encountering a horizon. Another family, with horizons, contains the Schwarzschild solution but includes also non-Schwarzschild black...
Spherically symmetric solutions in higher-derivative gravity
Lü, H.; Perkins, A.; Pope, C. N.; Stelle, K. S.
2015-12-01
Extensions of Einstein gravity with quadratic curvature terms in the action arise in most effective theories of quantized gravity, including string theory. This article explores the set of static, spherically symmetric and asymptotically flat solutions of this class of theories. An important element in the analysis is the careful treatment of a Lichnerowicz-type "no-hair" theorem. From a Frobenius analysis of the asymptotic small-radius behavior, the solution space is found to split into three asymptotic families, one of which contains the classic Schwarzschild solution. These three families are carefully analyzed to determine the corresponding numbers of free parameters in each. One solution family is capable of arising from coupling to a distributional shell of matter near the origin; this family can then match onto an asymptotically flat solution at spatial infinity without encountering a horizon. Another family, with horizons, contains the Schwarzschild solution but includes also non-Schwarzschild black holes. The third family of solutions obtained from the Frobenius analysis is nonsingular and corresponds to "vacuum" solutions. In addition to the three families identified from near-origin behavior, there are solutions that may be identified as "wormholes," which can match symmetrically onto another sheet of spacetime at finite radius.
On the Solutions Fractional Riccati Differential Equation with Modified Riemann-Liouville Derivative
Directory of Open Access Journals (Sweden)
Mehmet Merdan
2012-01-01
Full Text Available Fractional variational iteration method (FVIM is performed to give an approximate analytical solution of nonlinear fractional Riccati differential equation. Fractional derivatives are described in the Riemann-Liouville derivative. A new application of fractional variational iteration method (FVIM was extended to derive analytical solutions in the form of a series for these equations. The behavior of the solutions and the effects of different values of fractional order are indicated graphically. The results obtained by the FVIM reveal that the method is very reliable, convenient, and effective method for nonlinear differential equations with modified Riemann-Liouville derivative
On the derivation and solution of the black-scholes option pricing model
David CHAPPELL
1992-01-01
The derivation and solution of the celebrated Black-Scholes Option Pricing Formula is set out in rather more detail than has appeared in the literature so far. One problem with the Black-Scholes analysis is that the mathematical skills required in the derivation and particularly in the solution of the model are fairly advanced and probably unfamiliar to most economists. This paper derives the partial differential equation for the call option price and gives full details of its sol...
Exact solutions of a class of fractional Hamiltonian equations involving Caputo derivatives
Energy Technology Data Exchange (ETDEWEB)
Baleanu, Dumitru [Department of Mathematics and Computer Sciences, Faculty of Arts and Sciences, Cankaya University, Ankara 06530 (Turkey); Trujillo, Juan J [Departamento de Analisis Matematico, University of La Laguna, 38271 La Laguna, Tenerife (Spain)], E-mail: dumitru@cankaya.edu.tr, E-mail: JTrujill@ullmat.es, E-mail: baleanu@venus.nipne.ro
2009-11-15
The fractional Hamiltonian equations corresponding to the Lagrangians of constrained systems within Caputo derivatives are investigated. The fractional phase space is obtained and the exact solutions of some constrained systems are obtained.
Derivative Estimates for the Solution of Hyp erb olic Aﬃne Sphere Equation
Institute of Scientific and Technical Information of China (English)
Wu Ya-dong; Rong Xiao-chun
2015-01-01
Considering the hyperbolic affine sphere equation in a smooth strictly convex bounded domain with zero boundary values, the sharp derivative estimates of any order for its convex solution are obtained.
Non-traditional solutions of cellulose and it's derivatives and their processing products
Grinshpan, D. D.; Savitskaya, T. A.; Tsygankova, N. G.
2003-01-01
The main achievements of the Laboratory of cellulose solutions and their processing products in the field of the elaboration of new cellulose dissolving processes, the homogeneous synthesis of cellulose derivatives, the elaboration of the incompatible polymer solutions stabilization, the creation of new film - fabric materials and filtering equipments on their base, the preparation of hard quickly disintegrated drug forms (tablets, granules) using new water soluble cellulose derivative have b...
Indian Academy of Sciences (India)
H Mohan; A Adhikary; V Jain; J P Mittal
2000-08-01
The pulse radiolysis technique has been employed to investigate the reaction of DNA-minor-groove ligand bisbenzimidazole Hoechst 33258 with pyrimidine and purine nucleotide-derived radicals. Formation of an N-centred Hoechst-33258 radical is observed. Bimolecular rate constants and the yields of Hoechst-33258 radical have been evaluated. While the rate constant for the reaction of pyrimidine-derived radicals with Hoechst-33258 remained the same (1-2) × 109 dm3 mol-1s-1, the yields of the Hoechst-33258 radical varied from 25% (5 -cytidine monophosphate) to 75% (5 -guanosine monophosphate) under anoxic conditions. The rate constant values for the reaction of purine-derived radicals with Hoechst-33258, under oxic and anoxic conditions, remained the same whereas with pyrimidine-derived radicals, the rate constant value under oxic conditions was about two orders of magnitude lower than under anoxic conditions. The difference in the yields of Hoechst-33258 radical with various nucleotide-derived radicals suggest the formation of different types of radicals and that the reaction mainly occurs by electron transfer from Hoechst-33258 to the nucleotide radicals.
Interaction of derived polymers from pyrrole with biocompatible solutions
International Nuclear Information System (INIS)
This work presents a study about the synthesis by plasma, the electric properties and superficial interaction of polymers derived from pyrrole doped with Iodine with potential use as bio material. Poly-pyrrole is a semiconductor and biocompatible polymer with potential application in the development of artificial muscles and implants where the electric interaction between cells and material is an important variable. The syntheses were made at 13.5 MHz in a glass tubular reactor of 1500 cm3 with electrodes of 6.5 cm diameter and stainless steel flanges. An electrode was connected to the RF terminal of the power supply that is combined with a matching coupling resistance. The monomer and dopant used in this work were pyrrole and Iodine respectively, in closed containers. They were vaporized and injected separately into the reactor at room temperature and 0.1 mbar. The vapors of the reagents mixed freely in the reactor. The synthesis time was 240 min at 40, 60, 80 and 100 W. The polymers were obtained as thin films adhered to the reactor walls. The films were washed and swollen with distilled water and removed from the reactor walls with a small spatula. The polymers were irradiated with gamma rays at 18 and 22 KGy. Due to the fact that the doses are cumulative, the final dose applied was 40 KGy. The polymers characterization was carried out by Fourier Transform Infrared Spectroscopy, thermogravimetric analysis (TGA), scanning electron microscopy, contact angle, electrical conductivity and X-ray diffraction. The analyses indicates that the polymers have very similar structure in almost the entire power range, showing C-O, C=C, C-H, O-H, N-H bonds with a predominantly amorphous structure. The TGA analyses showed that the material has 4 or 5 loses of material. The first one starts after that 115 C except for the material irradiated at 40 KGy, this one begins in 87 C, the second one is in the interval of 196 and 295 C, the third one between 311 and 500 C, and the last
Positive Solution of a Nonlinear Fractional Differential Equation Involving Caputo Derivative
Directory of Open Access Journals (Sweden)
Changyou Wang
2012-01-01
Full Text Available This paper is concerned with a nonlinear fractional differential equation involving Caputo derivative. By constructing the upper and lower control functions of the nonlinear term without any monotone requirement and applying the method of upper and lower solutions and the Schauder fixed point theorem, the existence and uniqueness of positive solution for the initial value problem are investigated. Moreover, the existence of maximal and minimal solutions is also obtained.
Stability of Travelling Wave Solutions of the Derivative Ginzburg—Landau Equations
Institute of Scientific and Technical Information of China (English)
BolingGuo; BainianLU; 等
1997-01-01
The existence of travelling wave solution of the quinitic Ginzburg-Landau equation with derivatives is proved by the geometric singular perturbation theory.The stability of the wave solution is presented by topological methods which are proposed in Alexander,Gardner and Jones[6].The Chern number of the unstable augmented bundle is used to count the number of the linearizing operator L.For derivative Ginzburg-Landau equations,the Chern number of the unstable augmented bundle is equal to zero.I.e.c1（ε）=0,then the wave solution is stable.
Aminopyrimidine derivatives as inhibitors for corrosion of 1018 carbon steel in nitric acid solution
Energy Technology Data Exchange (ETDEWEB)
Abdallah, M. [Chemistry Department, Faculty of Science, Benha University, Benha (Egypt)]. E-mail: metwally552@hotmail.com; Helal, E.A. [Corrosion Department, Badr El-Din Petroleum company (Egypt); Fouda, A.S. [Chemistry Department, Faculty of Science, Mansoura University, Mansoura 35516 (Egypt)]. E-mail: asfouda@yahoo.com
2006-07-15
The effect of some aminopyrimidine derivatives on the corrosion of 1018 carbon steel in 0.05 M HNO{sub 3} solution was studied using weight loss and polarization techniques. The percentage inhibition efficiency was found to increase with increasing concentration of inhibitor and with decreasing temperature. The addition of KI to aminopyrimidine derivatives enhanced the inhibition efficiency due to synergistic effect. The inhibitors are adsorbed on the steel surface according to Temkin isotherm. Some thermodynamic functions were computed and discussed. It was found that the aminopyrimidine derivatives provide a good protection to steel against pitting corrosion in chloride containing solutions.
A class of exact solutions of higher derivative gravity in four dimensions
Directory of Open Access Journals (Sweden)
M. H. Dehghani
2005-09-01
Full Text Available In this paper we consider the action of higher derivative gravity up to the second order terms in the scalars made from the Ricci scalar, Ricci and Riemann tensors. We use the Bach- Lanczos identity of the Weyl tensor in four dimensions and show that the solutions of 4-dimensional Einstein equations with cosmological constant term in vacuum, which are known as Einstein metrics, satisfy the field equations of higher derivative gravity. We also find that the field equations of higher derivative gravity are not satisfied by the solutions of Einstein equations in higher dimensions or in the presence of matter.
Thermodynamic properties of ethanol solution of chiral camphors and its derivatives
Energy Technology Data Exchange (ETDEWEB)
Kimura, Takayoshi [Department of Chemistry, Kinki University, Kowakae, Higashi-Osaka 577-8502 (Japan)], E-mail: kimura@chem.kindai.ac.jp; Iwama, Sekai; Kido, Satoko; Khan, Mohammad Abdullah [Department of Chemistry, Kinki University, Kowakae, Higashi-Osaka 577-8502 (Japan)
2009-10-15
Enthalpies of mixing and the densities of ethanol solution of R- and S-enantiomers of camphor, 10-camphorsulfonamide, 10-camphorsulfonic acid, camphorquinone, and 10-camphorsulfonyl chloride have been measured for a wide range of mole fractions of heterochiral components at 298.15 K. Enthalpies of mixing were exothermic for all concentrations and heterochiral solutions were more stable than each of the homochiral solutions. Enthalpic stabilization of mixing of heterochiral solutions was increased with a decreasing concentration of all the camphor derivatives measured. The sequence of enthalpic stabilization on mixing was 10-camphorsulfonyl chloride, 10-camphorsulfonic acid, 10-camphorsulfonamide, camphor, and camphorquinone. Apparent molar volumes were determined and excess volumes of mixing of heterochiral solutions were small and negative. Enthalpic stabilizations were found to be dependent on dipole-dipole interaction between solutes and solvents.
Classification of kink type solutions to the extended derivative nonlinear Schrödinger equation
DEFF Research Database (Denmark)
Wyller, J.; Fla, T.; Juul Rasmussen, J.
1998-01-01
with hydrodynamical shocks or optical double layers in analogy with electrostatic double layers in plasma physics. Hydrodynamical equations for the action density and local wave number are derived and shock wave solutions of the Rankine-Hugionot type are constructed. They are consistent with the kink structures when......The Raman Extended Derivative Non Linear Schrodinger (R-EDNLS) equation which models single mode propagation in optical fibers, is shown to possess travelling and stationary kink envelope solutions of monotonic and oscillatory type. These structures have been called optical shocks in analogy...
S-asymptotically -periodic Solutions of R-L Fractional Derivative-Integral Equation
Institute of Scientific and Technical Information of China (English)
WANG Bing
2015-01-01
The aim of this paper is to study the S-asymptotically ω-periodic solutions of R-L fractional derivative-integral equation:is a linear densely defined operator of sectorial type on a completed Banach space X, f is a continuous function satisfying a suitable Lipschitz type condition. We will use the contraction mapping theory to prove problem (1) and (2) has a unique S-asymptotically ω-periodic solution if the function f satisfies Lipshcitz condition.
Directory of Open Access Journals (Sweden)
S. Das
2013-12-01
Full Text Available In this article, optimal homotopy-analysis method is used to obtain approximate analytic solution of the time-fractional diffusion equation with a given initial condition. The fractional derivatives are considered in the Caputo sense. Unlike usual Homotopy analysis method, this method contains at the most three convergence control parameters which describe the faster convergence of the solution. Effects of parameters on the convergence of the approximate series solution by minimizing the averaged residual error with the proper choices of parameters are calculated numerically and presented through graphs and tables for different particular cases.
Enzyme stabilization by glass-derived silicates in glass-exposed aqueous solutions
Ives, J.A.; Moffett, J.R.; Arun, P.; Lam, D.; Todorov, T.I.; Brothers, A.B.; Anick, D.J.; Centeno, J.; Namboodiri, M.A.A.; Jonas, W.B.
2010-01-01
Objectives: To analyze the solutes leaching from glass containers into aqueous solutions, and to show that these solutes have enzyme activity stabilizing effects in very dilute solutions. Methods: Enzyme assays with acetylcholine esterase were used to analyze serially succussed and diluted (SSD) solutions prepared in glass and plastic containers. Aqueous SSD preparations starting with various solutes, or water alone, were prepared under several conditions, and tested for their solute content and their ability to affect enzyme stability in dilute solution. Results: We confirm that water acts to dissolve constituents from glass vials, and show that the solutes derived from the glass have effects on enzymes in the resultant solutions. Enzyme assays demonstrated that enzyme stability in purified and deionized water was enhanced in SSD solutions that were prepared in glass containers, but not those prepared in plastic. The increased enzyme stability could be mimicked in a dose-dependent manner by the addition of silicates to the purified, deionized water that enzymes were dissolved in. Elemental analyses of SSD water preparations made in glass vials showed that boron, silicon, and sodium were present at micromolar concentrations. Conclusions: These results show that silicates and other solutes are present at micromolar levels in all glass-exposed solutions, whether pharmaceutical or homeopathic in nature. Even though silicates are known to have biological activity at higher concentrations, the silicate concentrations we measured in homeopathic preparations were too low to account for any purported in vivo efficacy, but could potentially influence in vitro biological assays reporting homeopathic effects. ?? 2009 The Faculty of Homeopathy.
Analytical Solutions of the Space-Time Fractional Derivative of Advection Dispersion Equation
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Abdon Atangana
2013-01-01
Full Text Available Fractional advection-dispersion equations are used in groundwater hydrology to model the transport of passive tracers carried by fluid flow in porous medium. A space-time fractional advection-dispersion equation (FADE is a generalization of the classical ADE in which the first-order space derivative is replaced with Caputo or Riemann-Liouville derivative of order , and the second-order space derivative is replaced with the Caputo or the Riemann-Liouville fractional derivative of order . We derive the solution of the new equation in terms of Mittag-Leffler functions using Laplace transfrom. Some examples are given. The results from comparison let no doubt that the FADE is better in prediction than ADE.
Real analytic quasi-periodic solutions for the derivative nonlinear Schrödinger equations
Geng, Jiansheng; Wu, Jian
2012-10-01
In this paper, we show that one dimension derivative nonlinear Schrödinger equation admits a whitney smooth family of small amplitude, real analytic quasi-periodic solutions with two Diophantine frequencies. The proof is based on a partial Birkhoff normal form reduction and an abstract infinite dimensional Kolmogorov-Arnold-Moser (KAM) theorem.
Existence of solutions and positive solutions to a fourth-order two-point BVP with second derivative
Institute of Scientific and Technical Information of China (English)
姚庆六
2004-01-01
Several existence theorems were established for a nonlinear fourth-order two-point boundary value problem with second derivative by using Leray-Schauder fixed point theorem, equivalent norm and technique on system of integral equations. The main conditions of our results are local. In other words, the existence of the solution can be determined by considering the "height" of the nonlinear term on a bounded set. This class of problems usually describes the equilibrium state of an elastic beam which is simply supported at both ends.
A formal derivation for the Blasius similarity solution for flat-plate boundary layer
Lin, Hao
2015-11-01
The Blasius solution is a classical solution for a laminar boundary layer attached to a semi-infinite flat plate. The key of the solution strategy is to reduce the boundary layer equations, which are PDEs, to a set of ODEs, using a similarity variable transform. Conceptually, the similarity suggests that the velocity profile in each transverse cross-section appears ``self-similar''. In many classical text books and typical classroom lectures on fluid mechanics, the existence of the similarity solution is argued heuristically. The similarity variable is defined a priori so as to collapse the PDEs. It appears somewhat mystical that the PDEs can be perfectly reduced via such an approach. Here we present a rigorous derivation for the existence of a similarity solution, which naturally arises from the fact that there is no apparent streamwise length scale for a semi-infinite plate. Conversely, a similarity solution cannot exist if the plate size is finite. This derivation can be useful in fluids education, in topics including similarity, scaling arguments, and boundary layer theory.
On the analytical solution of Fornberg–Whitham equation with the new fractional derivative
Indian Academy of Sciences (India)
Olaniyi Samuel Iyiola; Gbenga Olayinka Ojo
2015-10-01
Motivated by the simplicity, natural and efficient nature of the new fractional derivative introduced by R Khalil et al in J. Comput. Appl. Math. 264, 65 (2014), analytical solution of space-time fractional Fornberg–Whitham equation is obtained in series form using the relatively new method called q-homotopy analysis method (q-HAM). The new fractional derivative makes it possible to introduce fractional order in space to the Fornberg–Whitham equation and be able to obtain its solution. This work displays the elegant nature of the application of q-HAM to solve strongly nonlinear fractional differential equations. The presence of the auxiliary parameter h helps in an effective way to obtain better approximation comparable to exact solutions. The fraction-factor in this method gives it an edge over other existing analytical methods for nonlinear differential equations. Comparisons are made on the existence of exact solutions to these models. The analysis shows that our analytical solutions converge very rapidly to the exact solutions.
Energy Technology Data Exchange (ETDEWEB)
Cosman, M.; Patel, D.J. [Memorial Sloan Kettering Cancer Center, New York, NY (United States). Cellular Biochemistry and Biophysics Program; Hingerty, B.E. [Oak Ridge National Lab., TN (United States). Health and Safety Research Div.; Amin, S. [American Health Foundation, Valhalla, NY (United States); Broyde, S.; Geacintov, N.E. [New York Univ., NY (United States)
1995-12-31
Site-specifically modified oligonucleotides were derived from the reactions of stereoisomeric polycyclic aromatic diol epoxide metabolite model compounds with oligonucleotides of defined base composition and sequence. The NMR solution structures of ten different adducts studied so far are briefly described, and it is shown that stereochemical factors and the nature of the oligonucleotide context of the complementary strands, exert a powerful influence on the conformational features of these adducts.
ÇATAV, Şükrü Serter; BEKAR, İsmail; ATEŞ, Büşra Seda; ERGAN, Gökhan; OYMAK, Funda; ÜLKER, Elif Deniz; TAVŞANOĞLU, Çağatay
2012-01-01
The role of smoke as a fire-related germination cue is well known in many parts of the world, including Mediterranean-type ecosystems; however, it has been neglected in the Mediterranean Basin (MB). We studied the germination response of 5 woody species found in the eastern MB (south-western Turkey) to smoke solutions derived from different plant species. Of the 5 species examined, 2 [Sarcopoterium spinosum (L.) Spach and Satureja thymbra L.] showed significant increments in germination perce...
Anti-de Sitter-wave solutions of higher derivative theories.
Gürses, Metin; Hervik, Sigbjørn; Şişman, Tahsin Çağrı; Tekin, Bayram
2013-09-01
We show that the recently found anti-de Sitter (AdS)-plane and AdS-spherical wave solutions of quadratic curvature gravity also solve the most general higher derivative theory in D dimensions. More generally, we show that the field equations of such theories reduce to an equation linear in the Ricci tensor for Kerr-Schild spacetimes having type-N Weyl and type-N traceless Ricci tensors. PMID:25166648
International Nuclear Information System (INIS)
Highlights: • 4-PPM and 5-PPM are new good inhibitors for steel in HCl solution. • Inhibition efficiency follows the order: 4-PPM > 5-PPM. • The adsorption of phenylpyrimidine inhibitor obeys Langmuir adsorption isotherm. • There is a correlation between quantum chemical parameters and inhibition action. • 4-PPM and 5-PPM molecules adsorb on Fe (0 0 1) surface in the nearly flat manner. - Abstract: The inhibition effect of two phenylpyrimidine derivatives of 4-phenylpyrimidine (4-PPM) and 5-phenylpyrimidine (5-PPM) on the corrosion of cold rolled steel (CRS) in HCl solution was studied by weight loss, polarization curves, electrochemical impedance spectroscopy (EIS) and scanning electron microscope (SEM) methods. Quantum chemical calculation and molecular dynamics (MD) were applied to theoretically determine the relationship between molecular structure and inhibition efficiency. The results show that two phenylpyrimidine derivatives are good inhibitors, and inhibition efficiency follows the order: 4-PPM > 5-PPM. The adsorption of each inhibitor on steel surface obeys Langmuir adsorption isotherm. Two phenylpyrimidine derivatives act as mixed-type inhibitors
Inhibition effect of two mercaptopyrimidine derivatives on cold rolled steel in HCl solution
International Nuclear Information System (INIS)
Highlights: • AHMP and DHMP are good mixed-type inhibitors for steel in HCl solution. • AHMP exhibits better inhibitive ability than DHMP. • Inhibition efficiency remains constant from 6 to 156 h. • N8 and O9 atoms of AHMP exhibits more active than those of DHMP. • AHMP and DHMP molecules adsorb on Fe (0 0 1) surface with a nearby flat orientation. - Abstract: The inhibition effect of two mercaptopyrimidine derivatives of 4-amino-6-hydroxy-2-mercaptopyrimidine (AHMP) and 4,6-dihydroxy-2-mercaptopyrimidine (DHMP) on cold rolled steel (CRS) in HCl solution was studied by weight loss, potentiodynamic polarization curves, electrochemical impedance spectroscopy (EIS), scanning electron microscope (SEM), quantum chemical calculation and molecular dynamics (MD) simulations methods. The results show that both mercaptopyrimidine derivatives act as good inhibitors, and inhibition efficiency follows the order: AHMP > DHMP. The adsorption of either inhibitor on steel surface obeys Langmuir adsorption isotherm. Two mercaptopyrimidine derivatives are mixed-type inhibitors. The inhibitor molecules adsorb on the Fe (0 0 1) surface in the nearly flat manner
SANS structural characterization of fullerenol-derived star polymers in solutions
Jeng, U S; Wang, L Y; Chiang, L Y; Ho, D L; Han, C C
2002-01-01
We have studied the chain conformations of fullerenol-derived star polymers in two organic solvents using small-angle neutron scattering (SANS). The SANS results indicate that the six poly(urethane-ether) arms, chemically bonded on the fullerenol of the C sub 6 sub 0 -based star polymer, have a Gaussian chain conformation in toluene. However, these arms exhibit a pronounced excluded-volume effect in dimethylformamide solutions. We use a scattering model, with the polydispersity of the polymer taken into account, and a fractal model to extract the radius of gyration R sub g values and the persistence lengths of the C sub 6 sub 0 -star polymers in these two organic solutions. (orig.)
International Nuclear Information System (INIS)
The influence of concentration of particular reagents on the kinetics of Ce(IV) reduction by 2,6-dimethyl and 3,5-dimethyl-anisole as well as 2-methoxy-5-methyl- and 4-methoxy-2-methyl-aniline in perchloric acid solution was investigated, establishing the stoichiometry of these processes. Some intermediate products - macromolecular, derivatives of p-benzoquinone and 4,4'-diphenoquinone - were separated and identified. The effects of substituents and the conditions of performed oxidation processes on the kind and yields of the resultant products were considered. (author). 22 refs, 1 fig., 1 tab
Numerical solution of the exterior oblique derivative BVP using the direct BEM formulation
Čunderlík, Róbert; Špir, Róbert; Mikula, Karol
2016-04-01
The fixed gravimetric boundary value problem (FGBVP) represents an exterior oblique derivative problem for the Laplace equation. A direct formulation of the boundary element method (BEM) for the Laplace equation leads to a boundary integral equation (BIE) where a harmonic function is represented as a superposition of the single-layer and double-layer potential. Such a potential representation is applied to obtain a numerical solution of FGBVP. The oblique derivative problem is treated by a decomposition of the gradient of the unknown disturbing potential into its normal and tangential components. Our numerical scheme uses the collocation with linear basis functions. It involves a triangulated discretization of the Earth's surface as our computational domain considering its complicated topography. To achieve high-resolution numerical solutions, parallel implementations using the MPI subroutines as well as an iterative elimination of far zones' contributions are performed. Numerical experiments present a reconstruction of a harmonic function above the Earth's topography given by the spherical harmonic approach, namely by the EGM2008 geopotential model up to degree 2160. The SRTM30 global topography model is used to approximate the Earth's surface by the triangulated discretization. The obtained BEM solution with the resolution 0.05 deg (12,960,002 nodes) is compared with EGM2008. The standard deviation of residuals 5.6 cm indicates a good agreement. The largest residuals are obviously in high mountainous regions. They are negative reaching up to -0.7 m in Himalayas and about -0.3 m in Andes and Rocky Mountains. A local refinement in the area of Slovakia confirms an improvement of the numerical solution in this mountainous region despite of the fact that the Earth's topography is here considered in more details.
Metabolic Engineering of Yeast to Produce Fatty Acid-derived Biofuels: Bottlenecks and Solutions
Directory of Open Access Journals (Sweden)
Jiayuan eSheng
2015-06-01
Full Text Available Fatty acid-derived biofuels can be a better solution than bioethanol to replace petroleum fuel, since they have similar energy content and combustion properties as current transportation fuels. The environmentally friendly microbial fermentation process has been used to synthesize advanced biofuels from renewable feedstock. Due to their robustness as well as the high tolerance to fermentation inhibitors and phage contamination, yeast strains such as Saccharomyces cerevisiae and Yarrowia lipolytica have attracted tremendous attention in recent studies regarding the production of fatty acid-derived biofuels, including fatty acids, fatty acid ethyl esters, fatty alcohols, and fatty alkanes. However, the native yeast strains cannot produce fatty acids and fatty acid-derived biofuels in large quantities. To this end, we have summarized recent publications in this review on metabolic engineering of yeast strains to improve the production of fatty acid-derived biofuels, identified the bottlenecks that limit the productivity of biofuels, and categorized the appropriate approaches to overcome these obstacles.
Institute of Scientific and Technical Information of China (English)
QIANG Ji-Ye; FEI Jin-Xi; CAI Gui-Ping; ZHENG Chun-Long
2007-01-01
With the aid of an improved projective approach and a linear variable separation method,new types of variable separation solutions (including solitary wave solutions,periodic wave solutions,and rational function solutions)with arbitrary functions for (2+1)-dimensional Korteweg-de Vries system are derived.Usually,in terms of solitary wave solutions and rational function solutions,one can find some important localized excitations.However,based on the derived periodic wave solution in this paper,we find that some novel and significant localized coherent excitations such as dromions,peakons,stochastic fractal patterns,regular fractal patterns,chaotic line soliton patterns as well as chaotic patterns exist in the KdV system as considering appropriate boundary conditions and/or initial qualifications.
Zheng, Qiao; Fang, Guojia; Cheng, Fei; Lei, Hongwei; Qin, Pingli; Zhan, Caimao
2013-04-01
A Mo6+ cation modified graphene oxide (GO) derivative of GO-Mo was synthesized by a low-temperature solution method with different amounts of ammonium heptamolybdate (Mo-precursor) added into the GO solutions. The GO-Mo products were characterized through Raman microspectroscopy, scanning electron microscopy, transmission electron microscopy, energy dispersive x-ray spectroscopy and x-ray photoelectron spectroscopy measurements and their photoelectric properties were systematically investigated. Organic bulk heterojunction solar cells with GO-Mo as the hole transport layer (HTL) were fabricated and their performance as a function of the number of GO-Mo layers was also studied. The performance of these devices was much better than that of the device with GO as the HTL. The best performance of the device with a power conversion efficiency of 2.61%, an open-circuit voltage of 0.59 V and a short-circuit current density of 9.02 mA cm-2 were obtained. Finally, the effect of the Mo-precursor weight in the GO solution on the device performance was discussed.
Trombetta, Mark; Julian, Thomas B.; Wickerham, D. Lawrence; Steed, David L.
2015-01-01
Objective: To establish a safety profile for amnion-derived cellular cytokine solution following topical application in patients undergoing whole breast radiotherapy for breast cancer. Materials and Methods: Twenty female patients with early-stage breast cancer were enrolled in 2 separate cohorts of an institutional review board–approved phase I protocol. Cohort 1 consisted of 10 patients who received topical amnion-derived cellular cytokine solution to the breast immediately following the fi...
Technique for Calculating Solution Derivatives With Respect to Geometry Parameters in a CFD Code
Mathur, Sanjay
2011-01-01
A solution has been developed to the challenges of computation of derivatives with respect to geometry, which is not straightforward because these are not typically direct inputs to the computational fluid dynamics (CFD) solver. To overcome these issues, a procedure has been devised that can be used without having access to the mesh generator, while still being applicable to all types of meshes. The basic approach is inspired by the mesh motion algorithms used to deform the interior mesh nodes in a smooth manner when the surface nodes, for example, are in a fluid structure interaction problem. The general idea is to model the mesh edges and nodes as constituting a spring-mass system. Changes to boundary node locations are propagated to interior nodes by allowing them to assume their new equilibrium positions, for instance, one where the forces on each node are in balance. The main advantage of the technique is that it is independent of the volumetric mesh generator, and can be applied to structured, unstructured, single- and multi-block meshes. It essentially reduces the problem down to defining the surface mesh node derivatives with respect to the geometry parameters of interest. For analytical geometries, this is quite straightforward. In the more general case, one would need to be able to interrogate the underlying parametric CAD (computer aided design) model and to evaluate the derivatives either analytically, or by a finite difference technique. Because the technique is based on a partial differential equation (PDE), it is applicable not only to forward mode problems (where derivatives of all the output quantities are computed with respect to a single input), but it could also be extended to the adjoint problem, either by using an analytical adjoint of the PDE or a discrete analog.
International Nuclear Information System (INIS)
Fibroblast growth factors (FGFs) bind to extracellular matrices, especially heparin-like carbohydrates of heparansulfate proteoglycans which stabilize FGFs to protect against inactivation by heat, acid, proteolysis and oxidation. Moreover, binding of FGFs to cell surface proteoglycans promotes to form oligomers, which is essential for receptor oligomerization and activation. In the present study, we determined the solution structure of acidic FGF using a series of triple resonance multi-dimensional NMR experiments and simulated annealing calculations. Furthermore, we prepared the sample complexed with a heparin-derived hexasaccharide which is a minimum unit for aFGF binding. From the chemical shift differences between free aFGF and aFGF-heparin complex, we concluded that the major heparin binding site was located on the regions 110-131 and 17-21. The binding sites are quite similar to those observed for bFGF-heparin hexasaccharide complex, showing that both FGFs recognize heparin- oligosaccharides in a similar manner
Solid-State and Solution Structures of Glycinimine-Derived Lithium Enolates.
Jin, Kyoung Joo; Collum, David B
2015-11-18
A combination of crystallographic, spectroscopic, and computational studies was applied to study the structures of lithium enolates derived from glycinimines of benzophenone and (+)-camphor. The solvents examined included toluene and toluene containing various concentrations of tetrahydrofuran, N,N,N',N'-tetramethylethylenediamine (TMEDA), (R,R)-N,N,N',N'-tetramethylcyclohexanediamine [(R,R)-TMCDA], and (S,S)-N,N,N',N'-tetramethylcyclohexanediamine [(S,S)-TMCDA]. Crystal structures show chelated monomers, symmetric disolvated dimers, S4-symmetric tetramers, and both S6- and D3d-symmetric hexamers. (6)Li NMR spectroscopic studies in conjunction with the method of continuous variations show how these species distribute in solution. Density functional theory computations offer insights into experimentally elusive details. PMID:26554898
Yao, Ying; Gao, Bin; Inyang, Mandu; Zimmerman, Andrew R; Cao, Xinde; Pullammanappallil, Pratap; Yang, Liuyan
2011-06-15
Biochar converted from agricultural residues or other carbon-rich wastes may provide new methods and materials for environmental management, particularly with respect to carbon sequestration and contaminant remediation. In this study, laboratory experiments were conducted to investigate the removal of phosphate from aqueous solution by biochar derived from anaerobically digested sugar beet tailings (DSTC). Batch adsorption kinetic and equilibrium isotherm experiments and post-adsorption characterizations using SEM-EDS, XRD, and FTIR suggested that colloidal and nano-sized MgO (periclase) particles on the biochar surface were the main adsorption sites for aqueous phosphate. Batch adsorption experiments also showed that both initial solution pH and coexisting anions could affect the adsorption of phosphate onto the DSTC biochar. Of the mathematical models used to describe the adsorption kinetics of phosphate removal by the biochar, the Ritchie N_th-order (N=1.14) model showed the best fit. Two heterogeneous isotherm models (Freundlich and Langmuir-Freundlich) fitted the experimental isotherm of phosphate adsorption onto the biochar better than the Langmuir adsorption model. Our results suggest that biochar converted from anaerobically digested sugar beet tailings is a promising alternative adsorbent, which can be used to reclaim phosphate from water or reduce phosphate leaching from fertilized soils. In addition, there is no need to regenerate the exhausted biochar because the phosphate-laden biochar contains abundance of valuable nutrients, which may be used as a slow-release fertilizer to enhance soil fertility and to sequester carbon. PMID:21497441
Energy Technology Data Exchange (ETDEWEB)
Aviv, Hagit [Department of Chemistry, Bar-Ilan University, Ramat-Gan (Israel); Bar-Ilan University Institute for Nanotechnology and Advanced Materials, Ramat-Gan (Israel); Harazi, Sivan [Department of Chemistry, Bar-Ilan University, Ramat-Gan (Israel); Department of Physics, Bar-Ilan University, Ramat-Gan (Israel); Bar-Ilan University Institute for Nanotechnology and Advanced Materials, Ramat-Gan (Israel); Schiff, Dillon [Department of Chemistry, Bar-Ilan University, Ramat-Gan (Israel); Bar-Ilan University Institute for Nanotechnology and Advanced Materials, Ramat-Gan (Israel); Ramon, Yoni [Department of Chemistry, Bar-Ilan University, Ramat-Gan (Israel); Department of Physics, Bar-Ilan University, Ramat-Gan (Israel); Bar-Ilan University Institute for Nanotechnology and Advanced Materials, Ramat-Gan (Israel); Tischler, Yaakov R., E-mail: yrt@biu.ac.il [Department of Chemistry, Bar-Ilan University, Ramat-Gan (Israel); Bar-Ilan University Institute for Nanotechnology and Advanced Materials, Ramat-Gan (Israel)
2014-08-01
Here we present characterization of solution and thin film properties of Lissamine rhodamine B sulfonyl didodecyl amine (LRSD), an amphiphilic derivative of rhodamine. LRSD was synthesized by functionalizing Lissamine rhodamine B sulfonyl chloride (LRSC) with didodecylamine via a straightforward sulfonylation reaction. LRSD's long alkane chains make it highly soluble in chloroform, with a marked increase in brightness compared to the starting material. LRSD is shown to form well-defined robust micelles in water, without the addition of a co-surfactant and stable monolayers at the air–water interface. The greater lipophilicity of LRSD also enables doping into non-polar polymeric host matrices such as polystyrene with less aggregation and hence higher fluorescence quantum yield than LRSC or even rhodamine B. The monolayers of LRSD were prepared via Langmuir–Blodgett deposition and showed shifts in the photoluminescence peak from 575 nm to 595 nm, as the surface pressure is varied from 3 mN/m to 11 mN/m. - Highlights: • Lissamine rhodamine B sulfonyl didodecyl amine (LRSD) is soluble in chloroform. • LRSD shows robust quantum yield in solution and as a dopant in thin film. • LRSD is an amphiphilic rhodamine dye that forms compact fluorescent micelles. • LRSD forms a stable isotherm when spread at the air–water interface.
Energy Technology Data Exchange (ETDEWEB)
El-Taib Heakal, F., E-mail: fakihaheakal@yahoo.com [Chemistry Department, Faculty of Science, Cairo University, Giza 12613 (Egypt); Fouda, A.S. [Chemistry Department, Faculty of Science, El-Mansoura University, El-Mansoura (Egypt); Radwan, M.S. [Petrogulf Misr Company, Maadi, Cairo (Egypt)
2011-01-01
Electrochemical techniques were used to investigate the effect of concentration of three new thiadiazole derivatives (I-III) on the corrosion behavior of C-steel in 0.5 M NaCl solution through the analysis of electrochemical measurements including open circuit potential (OCP), Tafel polarization and electrochemical impedance spectroscopy (EIS). Polarization curves showed that the compounds studied act as anodic type inhibitors, where the inhibition efficiency increases with increase in inhibitor concentration and decreases with rise in temperature. An adherent layer of inhibitor molecules on the surface is proposed to account for their inhibitive action in which the organic molecules adsorb on the active anodic sites following Langmuir isotherm. The thermodynamic parameters of adsorption and corrosion processes were determined and discussed. The results also indicated that pitting potential at higher anodic polarization of C-steel in 0.5 M NaCl solution becomes more positive the higher the concentration of the additive, suggesting that these inhibitors acts as retarding catalyst for pitting corrosion. EIS data confirm well the electrochemical dc results and the results are all in good agreement with the calculated quantum chemical HOMO and LUMO energies of the tested molecules, as well as with surface examination via scanning electron microscope.
Institute of Scientific and Technical Information of China (English)
Zheng ZENG; Muhammad Tariq RAFIQ; Song-da ZHANG; Ting-qiang LI; Feng-liang ZHAO; Zhen-li HE; He-ping ZHAO; Xiao-e YANG; Hai-long WANG; Jing ZHAO
2013-01-01
The study on biochar derived from plant biomass for environmental applications is attracting more and more attention. Twelve sets of biochar were obtained by treating four phytoremediation plants, Salix rosthorni Seemen, Thalia dealbata, Vetiveria zizanioides, and Phragmites sp., sequential y through pyrolysis at 500 °C in a N2 environ-ment, and under different temperatures (500, 600, and 700 °C) in a CO2 environment. The cation exchange capacity and specific surface area of biochar varied with both plant species and pyrolysis temperature. The magnesium (Mg) content of biochar derived from T. dealbata (TC) was obviously higher than that of the other plant biochars. This bi-ochar also had the highest sorption capacity for phosphate and ammonium. In terms of biomass yields, adsorption capacity, and energy cost, T. dealbata biochar produced at 600 °C (TC600) is the most promising sorbent for removing contaminants (N and P) from aqueous solution. Therefore, T. dealbata appears to be the best candidate for phyto-remediation application as its biomass can make a good biochar for environmental cleaning.
Yoshimura, Tomokazu; Sakato, Ayako; Esumi, Kunio
2013-01-01
Amino acid-based anionic gemini surfactants (2C(n)diCys, where n represents an alkyl chain with a length of 10, 12, or 14 carbons and "di" and "Cys" indicate adipoyl and cysteine, respectively) were synthesized using the amino acid cysteine. Biodegradability, equilibrium surface tension, and dynamic light scattering were used to characterize the properties of gemini surfactants. Additionally, the effects of alkyl chain length, number of chains, and structure on these properties were evaluated by comparing previously reported gemini surfactants derived from cystine (2C(n)Cys) and monomeric surfactants (C(n)Cys). 2C(n)diCys shows relatively higher biodegradability than does C(n)Cys and previously reported sugar-based gemini surfactants. Both critical micelle concentration (CMC) and surface tension decrease when alkyl chain length is increased from 10 to 12, while a further increase in chain length to 14 results in increased CMC and surface tension. This indicates that long-chain gemini surfactants have a decreased aggregation tendency due to the steric hindrance of the bulky spacer as well as premicelle formation at concentrations below the CMC and are poorly packed at the air/water interface. Formation of micelles (measuring 2 to 5 nm in solution) from 2C(n)diCys shows no dependence on alkyl chain length. Further, shaking the mixtures of aqueous 2C(n)diCys surfactant solutions and squalane results in the formation of oil-in-water type emulsions. The highly stable emulsions are formed using 2C₁₂diCys or 2C₁₄diCys solution and squalane in a 1:1 or 2:1 volume ratio.
Institute of Scientific and Technical Information of China (English)
CAI RuiXian; LIU QiBin
2008-01-01
Analytical solutions of governing equations of various phenomena have their irre-placeable theoretical meanings. In addition, they can also be the benchmark solu-tions to verify the outcomes and codes of numerical solutions, and even to develop various numerical methods such as their differencing schemes and grid generation skills as well. A hybrid method of separating variables for simultaneous partial differential equation sets is presented. It is proposed that different methods of separating variables for different independent variables in the simultaneous equa-tion set may be used to improve the solution derivation procedure, for example, using the ordinary separating method for some variables and using extraordinary methods of separating variables, such as the separating variables with addition promoted by the first author, for some other variables. In order to prove the ability of the above-mentioned hybrid method, a lot of analytical exact solutions of two-buoyancy convection in porous media are successfully derived with such a method. The physical features of these solutions are given.
Institute of Scientific and Technical Information of China (English)
2008-01-01
Analytical solutions of governing equations of various phenomena have their irre-placeable theoretical meanings. In addition, they can also be the benchmark solu-tions to verify the outcomes and codes of numerical solutions, and even to develop various numerical methods such as their differencing schemes and grid generation skills as well. A hybrid method of separating variables for simultaneous partial differential equation sets is presented. It is proposed that different methods of separating variables for different independent variables in the simultaneous equa-tion set may be used to improve the solution derivation procedure, for example, using the ordinary separating method for some variables and using extraordinary methods of separating variables, such as the separating variables with addition promoted by the first author, for some other variables. In order to prove the ability of the above-mentioned hybrid method, a lot of analytical exact solutions of two-buoyancy convection in porous media are successfully derived with such a method. The physical features of these solutions are given.
Fouda, A. S.; Mohamed, A. K.; Mostafa, H. A.
1998-01-01
The inhibition of corrosion of copper in 2M HNO3 solution by some arylmethylene cyanothioacetamide derivatives was tested using polarization measurements. The results showed that these compounds act as mixed type inhibitors and inhibition efficiencies up to 90% can be obtained. The inhibition was assumed to occur via physical adsorption of the inhibitor molecules fitting a Frumkin isotherm. The influence of the substituent group on the inhibition efficiency of the inhibitor was explained in terms of the density of the electron cloud on the cyanothioacetamide moiety and the mode of adsorption. The increase in temperature was found to increase the corrosion in absence and in presence of inhibitors. Some thermodynamic functions were also computed and discussed. L'inhibition de la corrosion du cuivre dans des solutions 2M HNO3 par quelques dérivés d'arylméthylène cyanothioacétamides a été testée par des mesures de polarisation. Les résultats montrent que ces composés se comportent comme des inhibiteurs mixtes. Des efficacités d'inhibition jusqu'à 90 % peuvent être obtenues. L'inhibition est supposée se produire par l'adsorption des molécules d'inhibiteur suivant une isotherme de Frumkin. L'influence de groupe substituant sur l'efficacité de l'inhibiteur a été interprétée en terme de densité du nuage électronique sur la partie cyanothioacétamide et de mode d'adsorption. L'augmentation de la température augmente la corrosion en l'absence et en présence d'inhibiteur. Certaines fonctions thermodynamiques ont également été calculées et discutées.
International Nuclear Information System (INIS)
Interaction of native calf thymus DNA (ctDNA) with the actinocin derivatives containing protonated diethylamino groups, dimethylamino groups and unsubstituted amino groups and having different length of the alkyl chain have been studied by the method of viscometry. An anomalous hydrodynamic behavior of solutions of DNA with very low amount of ligands prepared under conditions of semidilute solution was revealed. We assumed that such an anomalous behavior of solutions of DNA complexes with actinocin derivatives associated with the formation of intermolecular crosslinks while the preparation of the complex was in terms of overlapping of macromolecular coils in solution. Comparative study of the hydrodynamic behavior of the DNA complexes with various actinocin structures lead us to the conclusion of the formation of crosslinks by the compounds containing protonated diethylamino groups
Complex formation between neptunium(V) and various thiosemicarbazide derivatives in aqueous solution
International Nuclear Information System (INIS)
Complex formation between neptunium(V) and various thiosemicarbazide derivatives in solution has been studied spectrophotometrically in the pH range 4-10. Stepwise formation of three types of complexes, with composition NpO2HA, NpO2A-, and NpOHA2-, has been demonstrated with salicylaldehyde thiosemicarbazone (H2L) and salicylaldehyde S-methyl-isothiosemicarbazone (H2Q) at t = 25 +/- 10C and μ = 0.05. The logarithmic stability constants of the first two complexes are 5.14 +/- 0.06, 11.85 +/- 0.04 and 8.42 +/- 0.09, 13.33 +/- 0.015 for H2L and H2Q, respectively; equilibrium constants for the formation of hydroxo complexes of the form NpO2OHL2- and NpO2OHQ2- were also determined, and found to be equal to (2.23 +/-0.37) x 10-5 and (5.02 +/- 0.9) x 10-5, respectively. In the case of S-methyl-N1,N4-bis(salicylidene)isothiosemicarbazide (H2Z), only one type of complex is formed under these experimental conditions, namely, NpO2Z-, with a logarithmic stability constant of 4.78 +/- 0.03. Dissociation constants for H2Q and H2Z were also determined
Hydrological Excitation of Polar Motion Derived from GRACE Gravity Field Solutions
Directory of Open Access Journals (Sweden)
L. Seoane
2011-01-01
Full Text Available The influence of the continental water storage on the polar motion is not well known. Different models have been developed to evaluate these effects and compared to geodetic observations. However, previous studies have shown large discrepancies mainly attributed to the lack of global measurements of related hydrological parameters. Now, from the observations of the GRACE mission, we can estimate the polar motion excitation due to the global hydrology. Data processing of GRACE data is carried out by several centers of analysis, we focus on the new solution computed by the Groupe de Recherche de Géodésie Spatiale. At annual scales, excitations derived from GRACE data are in better agreement with geodetic observations than models estimates. The main contribution to the hydrological excitation comes from the monsoon climates regions where GRACE and models estimates are in a very good agreement. Still, the effect of the north high latitudes regions, where the principal areas of snow cover are found, cannot be neglected. At these regions, GRACE and models estimated contributions to polar motion excitations show significant discrepancies. Finally, GRACE-based excitations reveal the possible influence of water storage variations in exciting polar motion around the frequency of 3 cycles per year.
Curcumin Derivatives as Green Corrosion Inhibitors for α-Brass in Nitric Acid Solution
Fouda, A. S.; Elattar, K. M.
2012-11-01
1,7- Bis-(4-hydroxy-3-methoxy-phenyl)-hepta-1,6-diene-4-arylazo-3,5-dione I-V have been investigated as corrosion inhibitors for α-brass in 2 M nitric acid solution using weight-loss and galvanostatic polarization techniques. The efficiency of the inhibitors increases with the increase in the inhibitor concentration but decreases with a rise in temperature. The conjoint effect of the curcumin derivatives and KSCN has also been studied. The apparent activation energy ( E a*) and other thermodynamic parameters for the corrosion process have also been calculated. The galvanostatic polarization data indicated that the inhibitors were of mixed-type, but the cathode is more polarized than the anode. The slopes of the cathodic and anodic Tafel lines ( b c and b a) are maintained approximately equal for various inhibitor concentrations. However, the value of the Tafel slopes increases together as inhibitor concentration increases. The adsorption of these compounds on α-brass surface has been found to obey the Frumkin's adsorption isotherm. The mechanism of inhibition was discussed in the light of the chemical structure of the undertaken inhibitors.
Franz, Michael G.; Payne, Wyatt G.; Xing, Liyu; Naidu, D. K; Salas, R. E; Marshall, Vivienne S.; Trumpower, C. J; Smith, Charlotte A; Steed, David L.; Robson, M. C.
2008-01-01
Objective: Growth factors demonstrate mixed results improving wound healing. Amnion-derived multipotent cells release physiologic levels of growth factors and tissue inhibitors of metalloproteinases. This solution was tested in models of acute and chronic wound healing. Methods: Acute model: Sprague-Dawley rats underwent laparotomy incisions. The midline fascia was primed with phosphate-buffered saline, unconditioned media, or amnion-derived cellular cytokine suspension prior to incision. Bre...
Radiation-induced reduction of quinoxalin-2-one derivatives in aqueous solutions
Skotnicki, Konrad; De la Fuente, Julio R.; Cañete, Alvaro; Bobrowski, Krzysztof
2016-07-01
Quinoxaline-2-one derivatives have been proposed as potential drugs in treatments of various diseases since some of them showed a variety of pharmacological properties. The kinetics and spectral characteristics of the transients formed in the reactions of hydrated electrons (eaq-) with quinoxalin-2-(1H)-one (Q) and its methyl derivative, 3-methyl quinoxalin-2-(1H)-one (3-MeQ) were studied by pulse radiolysis in aqueous solutions at pH ranging from 5 to 14. The transient absorption spectra recorded in the reactions of (eaq-) with Q and 3-MeQ at pH 7 consisted of a broad, almost flat band in the range 390-450 nm and were assigned to the respective protonated radical anions (QH•/3-MeQH•) at N4 atom in a pyrazin-2-one ring. On the other hand, the transient absorption spectra recorded in the reactions of (eaq-) with Q and 3-MeQ at pH 13 are characterized by a broad band with a much better pronounced maximum at λmax=390 nm and higher intensity (in comparison to that at pH 7) and were assigned to the respective radical anions (Q•-/3-MeQ•-). Both forms are involved in the prototropic equilibrium with the pKa located at pH≥13.5. The rate constants of the reactions of (eaq-) with Q and 3-MeQ were found to be at pH 7 (2.6±0.1)×1010 M-1 s-1 and (2.1±0.1)×1010 M-1 s-1 and at pH 13 (1.6±0.1)×1010 M-1 s-1 and (1.3±0.1)×1010 M-1 s-1, respectively. Semi-empirical quantum mechanical calculations reproduce fairly well the spectral features of the experimental absorption spectra and show that protonated radical anions at nitrogen atom (N4) in both molecules are the most stable hydrogenated radicals.
Complex formation between neptunium(V) and various thiosemicarbazide derivatives in aqueous solution
Energy Technology Data Exchange (ETDEWEB)
Chuguryan, D.G.; Dzyubenko, V.I.; Gerbeleu, N.V.
1987-01-01
Complex formation between neptunium(V) and various thiosemicarbazide derivatives in solution has been studied spectrophotometrically in the pH range 4-10. Stepwise formation of three types of complexes, with composition NpO/sub 2/HA, NpO/sub 2/A/sup -/, and NpOHA/sup 2 -/, has been demonstrated with salicylaldehyde thiosemicarbazone (H/sub 2/L) and salicylaldehyde S-methyl-isothiosemicarbazone (H/sub 2/Q) at t = 25 +/- 1/sup 0/C and ..mu.. = 0.05. The logarithmic stability constants of the first two complexes are 5.14 +/- 0.06, 11.85 +/- 0.04 and 8.42 +/- 0.09, 13.33 +/- 0.015 for H/sub 2/L and H/sub 2/Q, respectively; equilibrium constants for the formation of hydroxo complexes of the form NpO/sub 2/OHL/sup 2 -/ and NpO/sub 2/OHQ/sup 2 -/ were also determined, and found to be equal to (2.23 +/-0.37) x 10/sup -5/ and (5.02 +/- 0.9) x 10/sup -5/, respectively. In the case of S-methyl-N/sub 1/,N/sub 4/-bis(salicylidene)isothiosemicarbazide (H/sub 2/Z), only one type of complex is formed under these experimental conditions, namely, NpO/sub 2/Z/sup -/, with a logarithmic stability constant of 4.78 +/- 0.03. Dissociation constants for H/sub 2/Q and H/sub 2/Z were also determined.
Institute of Scientific and Technical Information of China (English)
TsuiChih－Ya
1992-01-01
A set of new gasdynamic functions with varying specific heat are deriveo for the first time.An original analytical solution of normal shock waves is owrked out therewith.This solution is thereafter further improved by not involving total temperature,Illustrative examples of comparison are given,including also some approximate solutions to show the orders of their errors.
Lee, Yun-Gun; Park, Hong-Gyu; Jeong, Hae-Chang; Lee, Ju Hwan; Heo, Gi-Seok; Seo, Dae-Shik
2015-06-29
Solution-derived HfYGaO films have been treated by ion beam (IB) irradiation and used as liquid crystal (LC) alignment layers. Solution processing was adopted due to its simplicity, high throughput, and facile composition modification. Homogeneous and uniform LC alignment was achieved on the IB-irradiated HfYGaO films, and when these films were adopted in twisted nematic (TN) cells, electro-optical performance comparable to that of TN cells with conventional polyimide layers was achieved, with almost no capacitance-voltage hysteresis. Moreover, LC cells based on IB-irradiated HfYGaO films had a high thermal budget. The proposed IB-irradiated solution-derived HfYGaO films have considerable potential for use in advanced LC applications. PMID:26191738
(Anti-) de Sitter Electrically Charged Black Hole Solutions in Higher-Derivative Gravity
Lin, Kai; Qian, Wei-Liang; Pavan, A. B.; Abdalla, E.
2016-01-01
In this paper, static electrically charged black hole solutions with cosmological constant are investigated in an Einstein-Hilbert theory of gravity with additional quadratic curvature terms. Beside the analytic Schwarzschild (Anti-) de Sitter solutions, non-Schwarzschild (Anti-) de Sitter solutions are also obtained numerically by employing the shooting method. The results show that there exist two groups of asymptotically (Anti-) de Sitter spacetimes for both charged and uncharged black hol...
Jiang, Shidong; Luo, Li-Shi
2016-07-01
The integral equation for the flow velocity u (x ; k) in the steady Couette flow derived from the linearized Bhatnagar-Gross-Krook-Welander kinetic equation is studied in detail both theoretically and numerically in a wide range of the Knudsen number k between 0.003 and 100.0. First, it is shown that the integral equation is a Fredholm equation of the second kind in which the norm of the compact integral operator is less than 1 on Lp for any 1 ≤ p ≤ ∞ and thus there exists a unique solution to the integral equation via the Neumann series. Second, it is shown that the solution is logarithmically singular at the endpoints. More precisely, if x = 0 is an endpoint, then the solution can be expanded as a double power series of the form ∑n=0∞∑m=0∞cn,mxn(xln x)m about x = 0 on a small interval x ∈ (0 , a) for some a > 0. And third, a high-order adaptive numerical algorithm is designed to compute the solution numerically to high precision. The solutions for the flow velocity u (x ; k), the stress Pxy (k), and the half-channel mass flow rate Q (k) are obtained in a wide range of the Knudsen number 0.003 ≤ k ≤ 100.0; and these solutions are accurate for at least twelve significant digits or better, thus they can be used as benchmark solutions.
Liimatainen, Henrikki; Sirviö, Juho; Sundman, Ola; Visanko, Miikka; Hormi, Osmo; Niinimäki, Jouko
2011-10-01
The flocculation behavior of cationic, quaternary ammonium groups containing cellulosic biopolymers, CDACs, synthesized by cationizing dialdehyde cellulose in mild aqueous solution was studied in a kaolin suspension. In particular, the role of CDAC dosage and solution pH, NaCl concentration, and temperature were clarified. In addition, the initial apparent charge densities (CDs), particle sizes, ζ-potential, and stability of CDs were determined. CDACs possessed a high flocculation activity in neutral and acidic solutions, but a significant decrease was observed in alkaline solutions (pH >9). This was also seen as a decline in the apparent CD and particle size of the CDACs in alkaline conditions. The measurements also indicated that the apparent CD decreased to a constant level of 3 mmol/g in aqueous solutions. However, no notable decrease in flocculation performance was obtained after several days of storage. Moreover, the variation of NaCl concentration and temperature did not affect the flocculation activity. PMID:21862324
(Anti-) de Sitter Electrically Charged Black Hole Solutions in Higher-Derivative Gravity
Lin, Kai; Pavan, A B; Abdalla, E
2016-01-01
In this paper, static electrically charged black hole solutions with cosmological constant are investigated in an Einstein-Hilbert theory of gravity with additional quadratic curvature terms. Beside the analytic Schwarzschild (Anti-) de Sitter solutions, non-Schwarzschild (Anti-) de Sitter solutions are also obtained numerically by employing the shooting method. The results show that there exist two groups of asymptotically (Anti-) de Sitter spacetimes for both charged and uncharged black holes. In particular, it was found that for uncharged black holes the first group can be reduced to the Schwarzschild (Anti-) de Sitter solution, while the second group is intrinsically different from a Schwarzschild (Anti-) de Sitter solution even when the charge and the cosmological constant become zero.
(Anti-) de Sitter electrically charged black-hole solutions in higher-derivative gravity
Lin, Kai; Qian, Wei-Liang; Pavan, A. B.; Abdalla, E.
2016-06-01
In this paper, static electrically charged black-hole solutions with cosmological constant are investigated in an Einstein-Hilbert theory of gravity with additional quadratic curvature terms. Beside the analytic Schwarzschild (Anti-) de Sitter solutions, non-Schwarzschild (Anti-) de Sitter solutions are also obtained numerically by employing the shooting method. The results show that there exist two groups of asymptotically (Anti-) de Sitter spacetimes for both charged and uncharged black holes. In particular, it was found that for uncharged black holes the first group can be reduced to the Schwarzschild (Anti-) de Sitter solution, while the second group is intrinsically different from a Schwarzschild (Anti-) de Sitter solution even when the charge and the cosmological constant become zero.
Mohammed, K. Elboree
2015-10-01
In this paper, we investigate the traveling wave solutions for the nonlinear dispersive equation, Korteweg-de Vries Zakharov-Kuznetsov (KdV-ZK) equation and complex coupled KdV system by using extended simplest equation method, and then derive the hyperbolic function solutions include soliton solutions, trigonometric function solutions include periodic solutions with special values for double parameters and rational solutions. The properties of such solutions are shown by figures. The results show that this method is an effective and a powerful tool for handling the solutions of nonlinear partial differential equations (NLEEs) in mathematical physics.
Huang, Qing; Zhdanov, Renat
2014-09-01
In this paper, group analysis of the time fractional Harry-Dym equation with Riemann-Liouville derivative is performed. Its maximal symmetry group in Lie’s sense and the corresponding optimal system of subgroups are determined. Similarity reductions of the equation under study are performed. As a result, the reduced fractional ordinary differential equations are deduced, and some group invariant solutions in explicit form are obtained as well.
Edris Hoseinzadeh; Ali Reza Rahmani; Ghorban Asgari; Mohamad Taghi Samadi; Ghodratollah Roshanaei; Mohammad Reza Zare
2013-01-01
Background and Aim: Heavy metals have been recognized as very poisonous elements and their discharge into water sources can cause damaging effects on human and environmental health. The present study aimed at producing activated carbon from scrap tires and using it in removing Pb+2 from synthetic aqueous solutions. Materials and Methods: In this experimental study, activated carbon powder was derived from scrap tires under laboratory conditions. The effect of Pb (II) ions wi...
Unified derivation of exact solutions to the relativistic Coulomb problem: Lie algebraic approach
Panahi, H.; Baradaran, M.; Savadi, A.
2015-10-01
Exact algebraic solutions of the D-dimensional Dirac and Klein-Gordon equations for the Coulomb potential are obtained in a unified treatment. It is shown that two cases are reducible to the same basic equation, which can be solved exactly. Using the Lie algebraic approach, the general exact solutions of the problem are obtained within the framework of representation theory of the sl(2) Lie algebra.
DEFF Research Database (Denmark)
Paradelo Pérez, Marcos; Katuwal, Sheela; Møldrup, Per;
2016-01-01
when the limiting macroporosity (the minimum macroporosity for every 0.6-mm layer along the soil column) was used, suggesting that soil layers with the narrowest macropore section restricted the flow through the whole soil column. Water, air, and solute transport were related with the CT......The characterization of soil pore space geometry is important for explaining fluxes of air, water, and solutes through soil and understanding soil hydrogeochemical functions. X-ray computed tomography (CT) can be applied for this characterization, and in this study CT-derived parameters were used...... to explain water, air, and solute transport through soil. Forty-five soil columns (20 by 20 cm) were collected from an agricultural field in Estrup, Denmark, and subsequently scanned using a medical CT scanner. Nonreactive tracer leaching experiments were performed in the laboratory along with measurements...
Ashworth, D. G.; Bowyer, M. D. J.; Oven, R.
1995-06-01
Commencing with the LSS integro-differential equation, an approximate transport equation is derived from which the moments of the range distribution may be obtained. The resulting equation set is known as the Kent Range ALgorithm (KRAL). The method for numerical solution of these equations, when written as a set of coupled second order ordinary differential equations (ODEs) of the initial value type, is then outlined. Solution is achieved by recasting the equation set in the form of first order ODEs designed for iterative solution. The technique used is an iterative refinement (or residual correction) procedure and the set of first order ODEs is called the Kent Optimised Range ALgorithm (KORAL). Finally, the first three moments from KORAL, first and second order PRAL codes and the full transport equation code KUBBIC-91 are compared with Monte Carlo data obtained from a TRIM code modified to treat targets of infinite extent. Comparisons are performed using consistent nuclear and electronic energy loss models.
Explicit Derivation of Yang-Mills Self-Dual Solutions on non-Commutative Harmonic Space
Belhaj, A; Sahraoui, E L; Saidi, E H
2001-01-01
We develop the noncommutative harmonic space (NHS) analysis to study the problem of solving the non-linear constraint eqs of noncommutative Yang-Mills self-duality in four-dimensions. We show that this space, denoted also as NHS($\\eta,\\theta$), has two SU(2) isovector deformations $\\eta^{(ij)}$ and $\\theta^{(ij)}$ parametrising respectively two noncommutative harmonic subspaces NHS($\\eta,0$) and NHS($0,\\theta$) used to study the self-dual and anti self-dual noncommutative Yang-Mills solutions. We formulate the Yang-Mills self-dual constraint eqs on NHS($\\eta,0$) by extending the idea of harmonic analyticity to linearize them. Then we give a perturbative self-dual solution recovering the ordinary one. Finally we present the explicit computation of an exact self-dual solution.
Removal of trivalent samarium from aqueous solutions by activated biochar derived from cactus fibres
Institute of Scientific and Technical Information of China (English)
Loukia Hadjittofi; Styliana Charalambous; Ioannis Pashalidis
2016-01-01
The efficiency of activated biochar fibres obtained fromOpuntia Ficus Indica regarding the sorption of trivalent samarium (Sm(III)) from aqueous solutions was investigated by batch experiments. The effect of various physicochemical parameters (e.g. pH, initial metal concentration, ionic strength, temperature and contact time) on the Sm(III) adsorption was studied and the surface species were characterized by FTIR spectroscopy prior to and after the lanthanide sorption. The experimental results showed that the acti-vated biochar fibres possessed extraordinary sorption capacity for Sm(III) in acidic solutions (qmax=90 g/kg, pH 3.0) and near neutral solutions (qmax=350 g/kg, pH 6.5). This was attributed to the formation of samarium complexes with the surface carboxylic moieties, available in high density on the lamellar structures of the bio-sorbent.
Solutions for the Cell Cycle in Cell Lines Derived from Human Tumors
Directory of Open Access Journals (Sweden)
B. Zubik-Kowal
2006-01-01
Full Text Available The goal of the paper is to compute efficiently solutions for model equations that have the potential to describe the growth of human tumor cells and their responses to radiotherapy or chemotherapy. The mathematical model involves four unknown functions of two independent variables: the time variable t and dimensionless relative DNA content x. The unknown functions can be thought of as the number density of cells and are solutions of a system of four partial differential equations. We construct solutions of the system, which allow us to observe the number density of cells for different t and x values. We present results of our experiments which simulate population kinetics of human cancer cells in vitro. Our results show a correspondence between predicted and experimental data.
Quasi-periodic solutions for d-dimensional beam equation with derivative nonlinear perturbation
Energy Technology Data Exchange (ETDEWEB)
Mi, Lufang, E-mail: milufang@126.com [Department of Mathematics, Binzhou University, Shandong 256600 (China); Cong, Hongzi, E-mail: conghongzi@dlut.edu.cn [School of Mathematical Sciences, Dalian University of Technology, Liaoning 116024 (China)
2015-07-15
In this paper, we consider the d-dimensional beam equation with convolution potential under periodic boundary conditions. We will apply the Kolmogorov-Arnold-Moser theorem in Eliasson and Kuksin [Ann. Math. 172, 371-435 (2010)] into this system and obtain that for sufficiently small ε, there is a large subset S′ of S such that for all s ∈ S′, the solution u of the unperturbed system persists as a time-quasi-periodic solution which has all Lyapunov exponents equal to zero and whose linearized equation is reducible to constant coefficients.
Galley, Chad R
2016-01-01
We utilize the dynamical renormalization group formalism to calculate the real space trajectory of a compact binary inspiral for long times via a systematic resummation of secularly growing terms. This method generates closed form solutions without orbit averaging, and the accuracy can be systematically improved. The expansion parameter is $v^5 \
New solutions of reflection equation derived from type B BMW algebras
Häring-Oldenburg, Reinhard
1996-09-01
We use B-type knot theory to find new solutions of Sklyanin's reflection equation in a systematic way. This generalizes the well known Baxterization of Birman - Wenzl algebras and should describe integrable systems which are restricted to a half plane.
Directory of Open Access Journals (Sweden)
Hesham G. Ibrahim
2016-04-01
Full Text Available This paper studied the ability of using local activated carbon (LAC derived from olive waste cakes as an adsorbent for the removal of Cu(II ions from aqueous solution by batch operation. Various operating parameters such as solution pH, adsorbent dosage, initial metal ions concentration, and equilibrium contact time have been studied. The results indicated that the adsorption of Cu(II increased with the increasing pH, and the optimum solution pH for the adsorption of Cu(II was found to be 5. The adsorption process increases with increasing dosage of LAC, also the amount of Cu(II removed changes with Cu(II initial concentration and contact time. Adsorption was rapid and occurred within 25 min. for Cu(II concentration range from 60 to 120 mg/l isothermally at 30±1 oC. Maximum adsorption occurs at Cu(II initial concentration lesser than 100 mg/l by using adsorbent dosage (1.2 g/l. The equilibrium adsorption data for Cu(II were fitted well with the Langmuir and Freundlich adsorption isotherm models. The maximum adsorption capacity of LAC was found to be 106.383 mg/g. So, the results indicated the suitability use of the activated carbon derived from olive waste cakes (LAC as low cost and natural material for reliable removal of Cu(II from water and wastewater effluents.
International Nuclear Information System (INIS)
Graphical abstract: -- Highlights: •1,3-Dibenzylthiourea/DBTU and 1-benzyl-3-diisopropylthiourea/DPTU were studied. •DPTU and DBTU act as good corrosion inhibitors for C-steel in acid solution. •The inhibition efficiency of DPTU and DBTU increased with concentration. •DBU did not act as an effective corrosion inhibitor for C-steel in acid solution. •The sulphur atom may play an important role in the inhibition process. -- Abstract: The behaviour of 1,3-dibenzylthiourea (DBTU) and 1-benzyl-3-diisopropylthiourea (DPTU) have been investigated as carbon steel corrosion inhibitors in HCl solution by weight loss measurements, potentiodynamic polarization curves, electrochemical impedance and scanning electron microscopy analysis. Quantum chemical calculation was applied to correlate electronic structure parameters of thiourea derivatives with their inhibition performances. DPTU results were slightly superior to those obtained in the presence of DBTU, showing that the replacement of one benzyl group for two isopropyl groups enhances the inhibitory properties. The 1,3-dibenzylurea derivative has also been studied in order to assess the importance of the sulphur atom to the inhibitory effect
Directory of Open Access Journals (Sweden)
Claus Larsen
2007-10-01
Full Text Available A series of model phenol carbonate ester prodrugs encompassing derivatives with fatty acid-like structures were synthesized and their stability as a function of pH (range 0.4 Ã¢Â€Â“ 12.5 at 37Ã‚Â°C in aqueous buffer solutions investigated. The hydrolysis rates in aqueous solutions differed widely, depending on the selected pro-moieties (alkyl and aryl substituents. The observed reactivity differences could be rationalized by the inductive and steric properties of the substituent groups when taking into account that the mechanism of hydrolysis may change when the type of pro-moiety is altered, e.g. n-alkyl vs. t-butyl. Hydrolysis of the phenolic carbonate ester 2-(phenoxycarbonyloxy-acetic acid was increased due to intramolecular catalysis, as compared to the derivatives synthesized from ÃÂ‰-hydroxy carboxylic acids with longer alkyl chains. The carbonate esters appear to be less reactive towards specific acid and base catalyzed hydrolysis than phenyl acetate. The results underline that it is unrealistic to expect that phenolic carbonate ester prodrugs can be utilized in ready to use aqueous formulations. The stability of the carbonate ester derivatives with fatty acid-like structures, expected to interact with the plasma protein human serum albumin, proved sufficient for further in vitro and in vivo evaluation of the potential of utilizing HSA binding in combination with the prodrug approach for optimization of drug pharmacokinetics.
Energy Technology Data Exchange (ETDEWEB)
Riley, Brian J.; Lepry, William C.; Crum, Jarrod V.
2016-01-01
Chlorosodalite has the general form of Na8(AlSiO4)6Cl2 and this paper describes experiments conducted to synthesize sodalite to immobilize a mixed chloride salt using solution-based techniques. Sodalites were made using different Group IV contributions from either Si(OC2H5)4 or Ge(OC2H5)4, NaAlO2, and a simulated spent electrorefiner salt solution containing a mixture of alkali, alkaline earth, and lanthanide chlorides. Additionally, 6 glass binders at low loadings of 5 mass% were evaluated as sintering aids for the consolidation process. The approach of using the organic Group IV additives can be used to produce large quantities of sodalite at room temperature and shows promise over a method where colloidal silica is used as the silica source. However, the small particle sizes inhibited densification during pressure-less sintering.
Process optimization of solution derived YBa2Cu3O7-x superconducting oxide films
International Nuclear Information System (INIS)
Superconducting YBa2Cu3O7-x films were deposited on LaAlO3 and other single crystal substrates from carboxylate precursor solutions by spin-coating. Films up to 1.5 μm were prepared and fired at 780-950C under controlled ambient. Processing parameters such as temperature, ambient, time, thickness, and substrate were investigated and shown to significantly affect film microstructure and properties. Highly oriented films with Tc(onset) ∼ 90k and Tc(zero) ∼ 86 K were fabricated under near optimized processing conditions. This talk focuses on film thickness and substrate effects on electrical and magnetic properties and also on orientation and interfacial reactions. Understanding and control of these processing parameters are key factors in the fabrication of thin films from solution precursors
Deriving Coarse-Grained Charges from All-Atom Systems: An Analytic Solution.
McCullagh, Peter; Lake, Peter T; McCullagh, Martin
2016-09-13
An analytic method to assign optimal coarse-grained charges based on electrostatic potential matching is presented. This solution is the infinite size and density limit of grid-integration charge-fitting and is computationally more efficient by several orders of magnitude. The solution is also minimized with respect to coarse-grained positions which proves to be an extremely important step in reproducing the all-atom electrostatic potential. The joint optimal-charge optimal-position coarse-graining procedure is applied to a number of aggregating proteins using single-site per amino acid resolution. These models provide a good estimate of both the vacuum and Debye-Hückel screened all-atom electrostatic potentials in the vicinity and in the far-field of the protein. Additionally, these coarse-grained models are shown to approximate the all-atom dimerization electrostatic potential energy of 10 aggregating proteins with good accuracy.
Soliton solutions in two-dimensional Lorentz-violating higher derivative scalar theory
Passos, E; Brito, F A; Menezes, R; Mota-Silva, J C; Santos, J R L
2016-01-01
This paper shows a new approach to obtain analytical topological defects for a 2D Myers-Pospelov Lagrangian for two scalar fields. Such a Lagrangian presents higher-order kinetic terms, which lead us to equations of motion which are non-trivial to be integrated. Here we describe three possible scenarios for the equations of motion, named by time-like, space-like and light-like respectively. We started our investigation with a kink-like travelling wave Ansatz for the free theory, which led us to constraints for the dispersion relations of each scenario. We also introduced a method to obtain analytical solution for the general theory in the three mentioned scenarios. We exemplified the method and discussed the behavior of the defects solutions.
Institute of Scientific and Technical Information of China (English)
Yan Baoqiang
2008-01-01
The existence of at least two positive solutions is presented for the singular second-order boundary value problem {1/p(t)x'(t)'+Φ(t)f(t,x(t),p(t)x'(t)))=0,0<1<1, lim t→0p(t)x'(t) = 0, x(1) = 0, by using the fixed point index, where f may be singular at x = 0 and px' = 0.
Solution structure of a soluble fragment derived from a membrane protein by shotgun proteolysis
Allen, Mark D.; Christie, Mary; Jones, Peter; Porebski, Benjamin T.; Roome, Brendan; Freund, Stefan M V; Buckle, Ashley M.; Bycroft, Mark; Christ, Daniel
2015-01-01
We have previously reported a phage display method for the identification of protein domains on a genome-wide scale (shotgun proteolysis). Here we present the solution structure of a fragment of the Escherichia coli membrane protein yrfF, as identified by shotgun proteolysis, and determined by NMR spectroscopy. Despite the absence of computational predictions, the fragment formed a well-defined beta-barrel structure, distantly falling within the OB-fold classification. Our results highlight t...
International Nuclear Information System (INIS)
The activated carbons (ACs) prepared from cattle manure compost (CMC) with various pore structure and surface chemistry were used to remove phenol and methylene blue (MB) from aqueous solutions. The adsorption equilibrium and kinetics of two organic contaminants onto the ACs were investigated and the schematic models for the adsorptive processes were proposed. The result shows that the removal of functional groups from ACs surface leads to decreasing both rate constants for phenol and MB adsorption. It also causes the decrement of MB adsorption capacity. However, the decrease of surface functional groups was found to result in the increase of phenol adsorption capacity. In our schematic model for adsorptive processes, the presence of acidic functional groups on the surface of carbon is assumed to act as channels for diffusion of adsorbate molecules onto small pores, therefore, promotes the adsorption rate of both phenol and MB. In phenol solution, water molecules firstly adsorb on surface oxygen groups by H-bonding and subsequently form water clusters, which cause partial blockage of the micropores, deduce electrons from the π-electron system of the carbon basal planes, hence, impede or prevent phenol adsorption. On the contrary, in MB solution, the oxygen groups prefer to combine with MB+ cations than water molecules, which lead to the increase of MB adsorption capacity.
Directory of Open Access Journals (Sweden)
George P. Dinos
2016-06-01
Full Text Available Chloramphenicol (CAM is the D-threo isomer of a small molecule, consisting of a p-nitrobenzene ring connected to a dichloroacetyl tail through a 2-amino-1,3-propanediol moiety. CAM displays a broad-spectrum bacteriostatic activity by specifically inhibiting the bacterial protein synthesis. In certain but important cases, it also exhibits bactericidal activity, namely against the three most common causes of meningitis, Haemophilus influenzae, Streptococcus pneumoniae and Neisseria meningitidis. Resistance to CAM has been frequently reported and ascribed to a variety of mechanisms. However, the most important concerns that limit its clinical utility relate to side effects such as neurotoxicity and hematologic disorders. In this review, we present previous and current efforts to synthesize CAM derivatives with improved pharmacological properties. In addition, we highlight potentially broader roles of these derivatives in investigating the plasticity of the ribosomal catalytic center, the main target of CAM.
A closed-form solution for the price of cross-commodity electricity derivatives
Tsitakis, D.; Xanthopoulos, S.; Yannacopoulos, A. N.
2006-11-01
We present a method for the valuation of two types of cross-commodity electricity options, European spark spread options and locational spread options. Since the underlying assets here are non-tradeable, the methodology of Black-Scholes-Merton cannot be directly applied. Nevertheless, assuming only absence of arbitrage we provide a closed-form analytic formula for the price of the derivatives in the case where the spot prices of the underlying process follow an exponential Ornstein-Uhlenbeck process.
Directory of Open Access Journals (Sweden)
Waleed M. Abd-Elhameed
2016-09-01
Full Text Available Herein, two numerical algorithms for solving some linear and nonlinear fractional-order differential equations are presented and analyzed. For this purpose, a novel operational matrix of fractional-order derivatives of Fibonacci polynomials was constructed and employed along with the application of the tau and collocation spectral methods. The convergence and error analysis of the suggested Fibonacci expansion were carefully investigated. Some numerical examples with comparisons are presented to ensure the efficiency, applicability and high accuracy of the proposed algorithms. Two accurate semi-analytic polynomial solutions for linear and nonlinear fractional differential equations are the result.
International Nuclear Information System (INIS)
Effect of 3.5-di-tret-butylpyrocatechol and its analogues on radical hexane transformations in deaerated solutions under impact of gamma-radiation is studied. It is shown that e.5-di-tret-butylpyrocatechol is by two-three times more effective by than its derivatives inhibits the formation of hexyle recombination products. It is shown by UV-, IR- and chromato-mass-spectrometry methods that adduct of alkyl radicals and 3.5-di-tret-butylpyrocatechenol has the structure of monoalkyl ether
Solute-Derived Thermal Stabilization of Nano-sized Grains in Melt-Spun Aluminum
Baker, A. H.; Sanders, P. G.; Lass, E. A.; Kapoor, Deepak; Kampe, S. L.
2016-08-01
Thermal stabilization of nanograined metallic microstructures (or nanostructures) can be difficult due to the large driving force for growth that arises from the inherently significant boundary area. Kinetic approaches for stabilization of the nanostructure effective at low homologous temperatures often fail at higher homologous temperatures. Alternatively, thermodynamic approaches for thermal stabilization may offer higher temperature stability. In this research, modest alloying of aluminum with solute (1 pct by mole Sc, Yb, or Sr) was examined as a means to thermodynamically stabilize a bulk nanostructure at elevated temperatures. Following 1-hour annealing treatments at 673 K (400 °C) (0.72 Tm), 773 K (500 °C) (0.83 Tm), and 873 K (600 °C) (0.94 Tm), the alloys remain nanocrystalline (analysis of X-ray diffraction peaks and direct observation of TEM dark-field micrographs, with the efficacy of stabilization: Sr ≈ Yb > Sc. The disappearance of intermetallic phases in the Sr- and Yb-containing alloys in the X-ray diffraction spectra is observed to occur coincident with the stabilization after annealing, suggesting that precipitates dissolve and the boundaries are enriched with solute.
Solute-Derived Thermal Stabilization of Nano-sized Grains in Melt-Spun Aluminum
Baker, A. H.; Sanders, P. G.; Lass, E. A.; Kapoor, Deepak; Kampe, S. L.
2016-08-01
Thermal stabilization of nanograined metallic microstructures (or nanostructures) can be difficult due to the large driving force for growth that arises from the inherently significant boundary area. Kinetic approaches for stabilization of the nanostructure effective at low homologous temperatures often fail at higher homologous temperatures. Alternatively, thermodynamic approaches for thermal stabilization may offer higher temperature stability. In this research, modest alloying of aluminum with solute (1 pct by mole Sc, Yb, or Sr) was examined as a means to thermodynamically stabilize a bulk nanostructure at elevated temperatures. Following 1-hour annealing treatments at 673 K (400 °C) (0.72 Tm), 773 K (500 °C) (0.83 Tm), and 873 K (600 °C) (0.94 Tm), the alloys remain nanocrystalline ( Sc. The disappearance of intermetallic phases in the Sr- and Yb-containing alloys in the X-ray diffraction spectra is observed to occur coincident with the stabilization after annealing, suggesting that precipitates dissolve and the boundaries are enriched with solute.
Wafer-scale solution-derived molecular gate dielectrics for low-voltage graphene electronics
Energy Technology Data Exchange (ETDEWEB)
Sangwan, Vinod K.; Jariwala, Deep; McMorrow, Julian J.; He, Jianting; Lauhon, Lincoln J. [Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208 (United States); Everaerts, Ken [Department of Chemistry, Northwestern University, Evanston, Illinois 60208 (United States); Grayson, Matthew [Department of Electrical Engineering and Computer Science, Northwestern University, Evanston, Illinois 60208 (United States); Marks, Tobin J., E-mail: t-marks@northwestern.edu, E-mail: m-hersam@northwestern.edu; Hersam, Mark C., E-mail: t-marks@northwestern.edu, E-mail: m-hersam@northwestern.edu [Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208 (United States); Department of Chemistry, Northwestern University, Evanston, Illinois 60208 (United States)
2014-02-24
Graphene field-effect transistors are integrated with solution-processed multilayer hybrid organic-inorganic self-assembled nanodielectrics (SANDs). The resulting devices exhibit low-operating voltage (2 V), negligible hysteresis, current saturation with intrinsic gain >1.0 in vacuum (pressure < 2 × 10{sup −5} Torr), and overall improved performance compared to control devices on conventional SiO{sub 2} gate dielectrics. Statistical analysis of the field-effect mobility and residual carrier concentration demonstrate high spatial uniformity of the dielectric interfacial properties and graphene transistor characteristics over full 3 in. wafers. This work thus establishes SANDs as an effective platform for large-area, high-performance graphene electronics.
Wafer-scale solution-derived molecular gate dielectrics for low-voltage graphene electronics
Sangwan, Vinod K.; Jariwala, Deep; Everaerts, Ken; McMorrow, Julian J.; He, Jianting; Grayson, Matthew; Lauhon, Lincoln J.; Marks, Tobin J.; Hersam, Mark C.
2014-02-01
Graphene field-effect transistors are integrated with solution-processed multilayer hybrid organic-inorganic self-assembled nanodielectrics (SANDs). The resulting devices exhibit low-operating voltage (2 V), negligible hysteresis, current saturation with intrinsic gain >1.0 in vacuum (pressure < 2 × 10-5 Torr), and overall improved performance compared to control devices on conventional SiO2 gate dielectrics. Statistical analysis of the field-effect mobility and residual carrier concentration demonstrate high spatial uniformity of the dielectric interfacial properties and graphene transistor characteristics over full 3 in. wafers. This work thus establishes SANDs as an effective platform for large-area, high-performance graphene electronics.
Removal of Lead (II Ions from Aqueous Solutions onto Activated Carbon Derived from Waste Biomass
Directory of Open Access Journals (Sweden)
Murat Erdem
2013-01-01
Full Text Available The removal of lead (II ions from aqueous solutions was carried out using an activated carbon prepared from a waste biomass. The effects of various parameters such as pH, contact time, initial concentration of lead (II ions, and temperature on the adsorption process were investigated. Energy Dispersive X-Ray Spectroscopy (EDS analysis after adsorption reveals the accumulation of lead (II ions onto activated carbon. The Langmuir and Freundlich isotherm models were applied to analyze equilibrium data. The maximum monolayer adsorption capacity of activated carbon was found to be 476.2 mg g−1. The kinetic data were evaluated and the pseudo-second-order equation provided the best correlation. Thermodynamic parameters suggest that the adsorption process is endothermic and spontaneous.
Energy Technology Data Exchange (ETDEWEB)
Zabaleta, Jone; Mestres, Narcis; Abellan, Patricia; Gibert, Marta; Sandiumenge, Felip; Puig, Teresa; Obradors, Xavier, E-mail: jzabaleta@icmab.es, E-mail: narcis.mestres@icmab.es [Institut de Ciencia de Materials de Barcelona, ICMAB-CSIC, Campus de la UAB, Bellaterra, 08193 Barcelona, Catalunya (Spain)
2010-01-15
When one-dimensional nanostructures are epitaxially grown on a substrate a key goal is to control the nanowire's position and orientation. Nanoscratching of single crystalline (001)- LaAlO{sub 3} substrates is demonstrated to be extraordinarily effective in directing the self-assembly of Ce{sub 0.9}Gd{sub 0.1}O{sub 2-y} epitaxial nanowires grown by chemical solution deposition. The local anisotropic elastic strain field imposed by the indentation lines is responsible for the breaking of the pre-existing orientation energy degeneracy and selects the nanowires' orientation parallel to the lines to an extent that can reach 100%.
Pinto, Thais F; Bezerra, Cícero W B; Silva, Domingos S A; Silva, Edson C DA; Vieira, Adriana P; Airoldi, Claudio; Melo, Júlio C P DE; Silva, Hildo A S; Santana, Sirlane A A
2016-09-01
The adsorption of Violet Remazol 5R (VR 5) on wood sawdust modified with succinic anhydride (SSA) as a function of contact time, pH, and initial dye concentrations was investigated using a batch technique under ambient conditions. The SSA obtained was confirmed by IR spectroscopy, thermogravimetry and 13C NMR, and degrees of substitution (DS) were calculated. A study on the effect of the pH on the adsorption of VR 5 showed that the optimum pH was 2.0. The interactions were assayed with respect to the pseudo-first-order and pseudo-second-order kinetic models, and were found to follow closely the pseudo-second-order. The isotherm was adjusted to the Langmuir, the Freundlich and the Temkin sorption models. SSA is a promising material for the removal of dye textile from aqueous solutions, and under conditions studied the removal percentage achieved was 51.7%. PMID:27580360
Adsorption of Cu(II from aqueous solution using activated carbon derived from mangosteen peel
Directory of Open Access Journals (Sweden)
Yandan Chen
2012-11-01
Full Text Available Effects of the mixing method of K2CO3 with the source biomass and thermal history on the properties of the mangosteen peel activated carbons (MSACs were investigated. The one-step impregnation activation process was found to be remarkably effective in increasing the mesoporosity of the activated carbon (L-MSAC as well as BET surface area (SBET and total pore volume, compared to the solid-solid dry mixing method in a two-stage process. The better fit of Langmuir isotherm indicates a maximum adsorption capacity of Cu(II to be 21.74 mg•g−1 for L-MSAC, which makes it a promising adsorbent for the removal of copper ion from aqueous solutions.
Structure solution with ARCIMBOLDO using fragments derived from distant homology models.
Sammito, Massimo; Meindl, Kathrin; de Ilarduya, Iñaki M; Millán, Claudia; Artola-Recolons, Cecilia; Hermoso, Juan A; Usón, Isabel
2014-09-01
Molecular replacement, one of the general methods used to solve the crystallographic phase problem, relies on the availability of suitable models for placement in the unit cell of the unknown structure in order to provide initial phases. ARCIMBOLDO, originally conceived for ab initio phasing, operates at the limit of this approach, using small, very accurate fragments such as polyalanine α-helices. A distant homolog may contain accurate building blocks, but it may not be evident which sub-structure is the most suitable purely from the degree of conservation. Trying out all alternative possibilities in a systematic way is computationally expensive, even if effective. In the present study, the solution of the previously unknown structure of MltE, an outer membrane-anchored endolytic peptidoglycan lytic transglycosylase from Escherichia coli, is described. The asymmetric unit contains a dimer of this 194 amino acid protein. The closest available homolog was the catalytic domain of Slt70 (PDB code 1QTE). Originally, this template was used omitting contiguous spans of aminoacids and setting as many ARCIMBOLDO runs as models, each aiming to locate two copies sequentially with PHASER. Fragment trimming against the correlation coefficient prior to expansion through density modification and autotracing in SHELXE was essential. Analysis of the figures of merit led to the strategy to optimize the search model against the experimental data now implemented within ARCIMBOLDO-SHREDDER (http://chango.ibmb.csic.es/SHREDDER). In this strategy, the initial template is systematically shredded, and fragments are scored against each unique solution of the rotation function. Results are combined into a score per residue and the template is trimmed accordingly.
Solution structure of telomere binding domain of AtTRB2 derived from Arabidopsis thaliana
Energy Technology Data Exchange (ETDEWEB)
Yun, Ji-Hye [Department of Biochemistry, College of Life Science and Biotechnology, Yonsei University, Seoul 120-749 (Korea, Republic of); Lee, Won Kyung [Department of Systems Biology, College of Life Science and Biotechnology, Yonsei University, Seoul 120-749 (Korea, Republic of); Kim, Heeyoun [Department of Biochemistry, College of Life Science and Biotechnology, Yonsei University, Seoul 120-749 (Korea, Republic of); Kim, Eunhee; Cheong, Chaejoon [Magnetic Resonance Team, Korea Basic Science Institute (KBSI), Ochang, Chungbuk 363-883 (Korea, Republic of); Cho, Myeon Haeng [Department of Systems Biology, College of Life Science and Biotechnology, Yonsei University, Seoul 120-749 (Korea, Republic of); Lee, Weontae, E-mail: wlee@spin.yonsei.ac.kr [Department of Biochemistry, College of Life Science and Biotechnology, Yonsei University, Seoul 120-749 (Korea, Republic of)
2014-09-26
Highlights: • We have determined solution structure of Myb domain of AtTRB2. • The Myb domain of AtTRB2 is located in the N-terminal region. • The Myb domain of AtTRB2 binds to plant telomeric DNA without fourth helix. • Helix 2 and 3 of the Myb domain of AtTRB2 are involved in DNA recognition. • AtTRB2 is a novel protein distinguished from other known plant TBP. - Abstract: Telomere homeostasis is regulated by telomere-associated proteins, and the Myb domain is well conserved for telomere binding. AtTRB2 is a member of the SMH (Single-Myb-Histone)-like family in Arabidopsis thaliana, having an N-terminal Myb domain, which is responsible for DNA binding. The Myb domain of AtTRB2 contains three α-helices and loops for DNA binding, which is unusual given that other plant telomere-binding proteins have an additional fourth helix that is essential for DNA binding. To understand the structural role for telomeric DNA binding of AtTRB2, we determined the solution structure of the Myb domain of AtTRB2 (AtTRB2{sub 1–64}) using nuclear magnetic resonance (NMR) spectroscopy. In addition, the inter-molecular interaction between AtTRB2{sub 1–64} and telomeric DNA has been characterized by the electrophoretic mobility shift assay (EMSA) and NMR titration analyses for both plant (TTTAGGG)n and human (TTAGGG)n telomere sequences. Data revealed that Trp28, Arg29, and Val47 residues located in Helix 2 and Helix 3 are crucial for DNA binding, which are well conserved among other plant telomere binding proteins. We concluded that although AtTRB2 is devoid of the additional fourth helix in the Myb-extension domain, it is able to bind to plant telomeric repeat sequences as well as human telomeric repeat sequences.
Institute of Scientific and Technical Information of China (English)
Li-na Zhang; Mei Zhang; Jing-hua Chen; Fan-bo Zeng
2001-01-01
Fractions of a water insoluble α-(1→3)-D-glucan (GL) extracted from Ganoderma lucidum were carboxymethylated (CM) to obtain water-soluble carboxymethylated derivatives (CM-GL) having a degree of substitution (DS) of 0.38～0.51. Weight-average molecular weight Mw and intrinsic viscosity [η] of the samples CM-GL were measured by gel permeation chromatography combined with laser light scattering (GPC-LLS) and viscometry. The CM-GL exhibits a stiffer chain in aqueous solution at 25℃ than the original glucan. The antitumor activities against Ehrlich ascites carcinoma (EAC,5 × 106) of the carboxymethylated derivatives from the α-glucan and curdlan, a β-glucan, are significantly higher than those of the original glucans. The effects of the relatively low molecular weight, expanded chains and better water-solubility of the CM-GL on the enhancement of antitumor activity could not be neglected. The chain stiffness decreased speedily with increase of temperature from 40 to 60℃ or NaOH concentration from 0.1 to 0.4 in the solution, respectively, and the change of the chain stiffness is reversible.
Neunert, Grazyna; Szwengiel, Artur; Walejko, Piotr; Witkowski, Stanislaw; Polewski, Krzysztof
2016-07-01
α-Tocopherol (Toc) is known to degrade to the tocopheroxyl radicals (Toc) by exposure to UV light irradiation. In the present study, the stability of Toc ester derivatives exposed to UV light was investigated and compared with Toc in organic solution and in phospholipid vesicles. To follow the depletion of Toc and its esters the absorbance and fluorescence methods were applied whereas degradation products were detected using LC-MS method. The irradiation with UVB light of air-equilibrated solutions of di-α-Tocopheryl malonate (DTMO), α-Tocopheryl malonate (TMO) and α-Tocopheryl succinate (TS) strongly modifies their absorption and fluorescence spectra. Upon UVB irradiation, absorption band at 279/285nm becomes less pronounced indicating the photodegradation of esters. During irradiation, the fluorescence maximum of esters at 305nm shifts to 326nm, a maximum characteristic for Toc. Photorecovery of Toc from its esters derivatives was finally confirmed by LC-MS method. Among studied esters, only α-tocopheryl nicotinate (TN) did not undergo depletion and appeared resistant to UVB radiation. Kinetic studies indicated that photoinduced transformation occurs through the first order consecutive reaction chain mechanism. The photodissociation of Toc esters in the liposomes occurred with one order of magnitude slower than in organic solvents. Using MS/MS method it was found that final stable product of irradiation was α-tocopheryl quinone (TQ), an animal and plant metabolite of Toc. PMID:27107331
Removal of Congo Red and Methylene Blue from Aqueous Solutions by Vermicompost-Derived Biochars.
Yang, Gang; Wu, Lin; Xian, Qiming; Shen, Fei; Wu, Jun; Zhang, Yanzong
2016-01-01
Biochars, produced by pyrolyzing vermicompost at 300, 500, and 700°C were characterized and their ability to adsorb the dyes Congo red (CR) and Methylene blue (MB) in an aqueous solution was investigated. The physical and chemical properties of biochars varied significantly based on the pyrolysis temperatures. Analysis of the data revealed that the aromaticity, polarity, specific surface area, pH, and ash content of the biochars increased gradually with the increase in pyrolysis temperature, while the cation exchange capacity, and carbon, hydrogen, nitrogen and oxygen contents decreased. The adsorption kinetics of CR and MB were described by pseudo-second-order kinetic models. Both of Langmuir and Temkin model could be employed to describe the adsorption behaviors of CR and MB by these biochars. The biochars generated at higher pyrolysis temperature displayed higher CR adsorption capacities and lower MB adsorption capacities than those compared with the biochars generated at lower pyrolysis temperatures. The biochar generated at the higher pyrolytic temperature displayed the higher ability to adsorb CR owing to its promoted aromaticity, and the cation exchange is the key factor that positively affects adsorption of MB. PMID:27144922
Heterocoagulated clay-derived adsorbents for phosphate decontamination from aqueous solution.
Gan, Fangqun; Luo, Yufeng; Hang, Xiaoshuai; Zhao, Hongting
2016-01-15
A series of nanocomposite adsorbents were prepared by heterocoagulation of negatively charged delaminated montmorillonite (Mt) and positively charged synthetic layered double hydroxide (LDH) colloids with different LDH loading amounts. The mineralogy and physicochemical properties of the resulting nanocomposites were characterized. Their potential applications for phosphate (P) removal from aqueous solution, as a function of P concentration (2.5-200 mg/L), contact time (1 min-48 h) and pH (3-10), were evaluated by using batch adsorption modes. It was found that the adsorption data could be well described by both Freundlich and Langmuir isotherm models. The maximum adsorption capacity of three different LDH heterocoagulated montmorillonites (LDH-Mts) for P removal was found to increase with LDH loadings, reaching 12.6, 16.2 and 23.3 mg/g respectively; Adsorption kinetic data revealed that 90% of adsorption onto LDH-Mts was completed within 1 h (h) and the adsorption process could be well described by the pseudo-second-order model. These results demonstrated that heterocoagulation of Mt and LDH could preserve the adsorption capacity of LDH for P and enhance the stability of both clay minerals, and LDH-Mts could be effectively used as a potential promising filtration medium for P removal.
Solution derived p-ZnO/n-Si nanowire heterojunctions for photodetection
Pradel, Ken C.; Jevasuwan, Wipakorn; Suwardy, Joko; Bando, Yoshio; Fukata, Naoki; Wang, Zhong Lin
2016-08-01
While there is considerable interest in zinc oxide nanomaterials for optoelectronics research, one weakness of the material is the difficulty in producing p-type zinc oxide. This can be attributed to a number of factors such as acceptor instability, donor compensation during growth, and the formation of deep acceptors. Recently, it was discovered that antimony is a stable p-type dopant in hydrothermally grown ZnO nanowires, and this method has been modified to produce ultra-long nanowires and homojunction thin films. In order to broaden the applicability of this new material, it is important to investigate how it interacts with other semiconducting nanomaterials. In this work we demonstrate a solution grown p-ZnO/n-Si nanowire heterojunction. After investigating its basic materials properties, we show its applicability as an photodetector with responsivity as high as 1.02 A/W at 442 nm, an order of magnitude higher than similar nanostructures based on n-type ZnO and p-type Si.
The Use of Microwave Derived Activated Carbon for Removal of Heavy Metal in Aqueous Solution
Directory of Open Access Journals (Sweden)
Rafeah Wahi
2011-09-01
Full Text Available Palm oil processing waste which is palm oil kernel shell (POKS was converted to activated carbon (POKS AC through 7 min microwave pyrolysis at temperature 270 °C followed by chemical activation using NaOH and HCl. The adsorption study on Ni(II, Cu(II and Cr(IV was conducted to evaluate the efficiency of the prepared activated carbon to remove heavy metal. The adsorption capacity was determined as a function of adsorbate initial concentration and adsorbent dosage. Based on Langmuir isotherm, Ni(II showed highest adsorption capacity of 40.98 mg/g, followed by Cr(IV and Cu(II with adsorption capacity of 40.60 mg/g and 13.69 mg/g, respectively. Cr(IV and Cu(II showed better fitting to Freundlich isotherm model with high correlation regression indicating the applicability of heterogeneous adsorption. Ni(II show better fitting with Langmuir isotherm that indicate monolayer coverage. The use of POKS AC is not only effective for adsorption of Cr(IV, Ni(II and Cu(II in aqueous solution but also helps to overcome the over abundance of POKS waste problem.
International Nuclear Information System (INIS)
solutions of soluble silicates synthesized have been clarified in Costa Rica from diatomite in almost 50% of their initial coloration. Clarification and removal of iron oxides have been achieved in a higher order of 50% m/m expressed as Fe2 O3. Activated carbon treatment has clarified the scope of [31-57]%, but not significantly decreases the iron content. The application of NaClO to 3% m/m clarifies the scope of [28-51]%, and reduced iron by 48% m/m. The land alone has been shown that is not very effective filter to clarify, [0-14]%, but is effective for the stripping of iron by 68% m/m. Other procedures are effective in clarifying the scope of [42-51]% and reduced the amount of iron in the field of [48-66]%. The synthesis of soluble glasses is possible to clarify for conditioning with commercial purposes diverse, treatment methodologies and analytical control, simple and economical. (author)
The Role of Liver in Determining Serum Colon-Derived Uremic Solutes.
Directory of Open Access Journals (Sweden)
Cheng-Jui Lin
Full Text Available Evidence has shown that indoxyl sulfate (IS and p-cresyl sulfate (PCS may be alternative predictors of clinical outcomes in chronic kidney disease (CKD. Both toxins are derived from the gastrointestinal tract and metabolised in the liver. However, it is unclear whether the liver affects the production of IS and PCS. Here, we explore the association between IS and PCS levels in liver cirrhosis and a CKD-based cohort (N = 115. Liver and kidney function was assessed and classified by a Child-Pugh score (child A-C and a modified version of the Modification of Diet in Renal Disease (MDRD equation (Stages 1-4, respectively. An animal model was also used to confirm the two toxin levels in a case of liver fibrosis. In patients with early liver cirrhosis (child A, IS and PCS were significantly associated with CKD stages. In contrast, serum IS and PCS did not significantly change in advanced liver cirrhosis (child C. A stepwise multiple linear regression analysis also showed that T-PCS was significantly associated with stages of liver cirrhosis after adjusting for other confounding factors (B = -2.29, p = 0.012. Moreover, the serum and urine levels of T-PCS and T-IS were significantly lower in rats with liver failure than in those without (p<0.01, p<0.05 and p<0.01, p<0.05, respectively. These results indicated that in addition to the kidneys, the liver was an essential and independent organ in determining serum IS and PCS levels. The production rate of IS and PCS was lower in patients with advanced liver cirrhosis.
International Nuclear Information System (INIS)
Water pollution caused by ammonia nitrogen has attracted a great attention as its toxicity affects both the environment and human health. The objective of this paper was to investigate the adsorption behavior of NH4+-N from aqueous solution by activated carbons prepared from rice husk. The physico-chemical properties of the activated carbon were characterized by Brunauer-Emmett-Teller (BET) test, Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). It was found that the NH4+-N adsorption on the rice husk derived carbons was dependent on adsorbent dosage and solution pH. The adsorption kinetics and isotherms of NH4+-N by rice husk carbon were also investigated, and good correlation coefficients were obtained for the pseudo-second order kinetic equation. Dubinin-Radushkevitch (D-R) adsorption isotherm model could better describe the adsorption behavior of NH4+-N on the rice husk carbon. Calculated by D-R model, the adsorption course of NH4+-N on the rice husk carbon was favored chemical ion-exchange mechanism. Moreover, the activated carbon adsorbed NH4+-N was highly fertilizer conservation especially for the nitrogen element. It was proposed that the amount of removed NH4+-N from aqueous solutions would increase evidently treated by rice husk carbon if combined with biological method. -- Highlights: ► The dosage of rice husk carbon and pH affected the removal of NH4+-N from aqueous solution. ► D-R model could better describe the adsorption behavior of NH4+-N on the rice husk carbon. ► The removing of NH4+-N would be risen by rice husk carbon if combined with biological method.
Improved light emission utilizing polyfluorene derivatives by thermal printing and solution process
Kasama, Daisuke; Takata, Ryotaro; Kajii, Hirotake; Inoue, Jun; Yoshino, Katsumi; Ohmori, Yutaka
2009-08-01
The emission properties of polymer light-emitting diode (PLEDs), using blue emissive poly(9,9-dioctylfluorene) (PFO) and yellow-green emissive poly[9,9-dioctylfluorenyl-2,7-diyl)-co-1, 4-benzo-{2,1'-3}- thiadiazole)] (F8BT) fabricated by the spin-coating method, the toluene vapor method and the thermal printing method, were investigated. poly(2,7-(9,9-din-octylfluorene)-alt-(1,4-phenylene-( (4-sec-butylphenyl)imino)-1,4-phenylene)) (TFB) is useful for buffer layer and a dopant when we use the spin-coating method. When we use TFB as interlayer of PLED, TFB acts as exciton-blocking layer, thus prevents luminescence quenching. When we use TFB with 2-(4-biphenylyl)-5-phenyl-1,3,4-oxadiazole (PBD) as dopants of PFO, better current efficiency was achieved, compared to PFO only device. This result derives from these materials working as hole and electron transporting molecules. The blue and yellow-green PLEDs fabricated by the spincoating method showed maximum efficiencies of approximately 1.1 and 1cd/A, respectively. The device with bis[1-(9,9-dimethyl-9H-fluoren-2-yl)-isoquinoline](acetylacetonate)iridium(III) (Ir(fliq)2acac) doped in PFO showed red-emission and a maximum efficiency of approximately 1cd/A. Current efficiencies of PLEDs with the β phase of PFO fabricated by the thermal printing method and the toluene vapor method were found to have better emission efficiency than that with the amorphous phase of PFO by the spin-coating method. The EL spectra of PLEDs using PFO and PFO:F8BT fabricated by the thermal printing method were polarized. The transient characteristics of PLEDs using β phase of PFO were better than amorphous phase of that. It is expected to improve the characteristics of PLEDs by the optimization of the thermal printing method. We demonstrated improved light emission of PLEDs with the high-quality β phase by the thermal printing method.
Jiang, B.; Jiang, S. L.; Liu, X.; Ma, A. L.; Zheng, Y. G.
2015-12-01
This study investigates the performance of three triazole derivatives with different molecular structures as corrosion inhibitors for the copper-nickel alloy CuNi 90/10 in 3.5 wt.% NaCl solution. Inhibition behavior was systematically determined through electrochemical measurements, scanning electron microscopy, energy-dispersive spectroscopy, and Fourier transform infrared spectroscopy. In addition, adsorption behavior and the inhibition mechanism were investigated via quantum chemical calculation and molecular dynamic simulation. Experimental results indicate that the three inhibitors with triazole rings and heteroatoms exhibited excellent corrosion inhibition capabilities on the copper-nickel alloy surface through physisorption and chemisorption. In particular, 3-amino-5-mercapto-1,2,4-triazole showed the best inhibition capability according to the concentration ranges considered in the experiments. The results of quantum chemical calculation agreed with the experimental findings.
Kim, Chul Hoon; Park, Jaehun; Seo, Jangwon; Park, Soo Young; Joo, Taiha
2010-05-13
Excited state intramolecular proton transfer (ESIPT) and subsequent intramolecular charge transfer (ICT) dynamics of a 2-(2'-hydroxyphenyl)benzoxazole derivative conjugated with an electron withdrawing group (HBOCE) in solutions and a polymer film has been investigated by femtosecond time-resolved fluorescence (TRF) and TRF spectra measurements without the conventional spectral reconstruction method. TRF with high enough resolution (benzoxazole groups is invoked to account for the dispersive ESIPT dynamics in liquids. From the TRF spectra of both the enol and keto isomers, we have identified the ICT reaction of the keto isomer occurring subsequent to the ESIPT. The ICT proceeds also by two time constants of near instantaneous and 2.7 ps. Since the ICT dynamics of HBOCE is rather close to the polar solvation dynamics, we argue that the ICT is barrierless and determined mostly by the solvent fluctuation.
Tehrani, Mahnaz Saghanejhad; Zare-Dorabei, Rouholah
2016-05-01
MIL-68(Al) as a metal-organic framework (MOF) was synthesized and characterized by different techniques such as SEM, BET, FTIR, and XRD analysis. This material was then applied for simulations removal of malachite green (MG) and methylene blue (MB) dyes from aqueous solutions using second order derivative spectrophotometric method (SODS) which was applied to resolve the overlap between the spectra of these dyes. The dependency of dyes removal efficiency in binary solutions was examined and optimized toward various parameters including initial dye concentration, pH of the solution, adsorbent dosage and ultrasonic contact time using central composite design (CCD) under response surface methodology (RSM) approach. The optimized experimental conditions were set as pH 7.78, contact time 5 min, initial MB concentration 22 mg L- 1, initial MG concentration 12 mg L- 1 and adsorbent dosage 0.0055 g. The equilibrium data was fitted to isotherm models such as Langmuir, Freundlich and Tempkin and the results revealed the suitability of the Langmuir model. The maximum adsorption capacity of 666.67 and 153.85 mg g- 1 was obtained for MB and MG removal respectively. Kinetics data fitting to pseudo-first order, pseudo-second order and Elovich models confirmed the applicability of pseudo-second order kinetic model for description of the mechanism and adsorption rate. Dye-loaded MIL-68(Al) can be easily regenerated using methanol and applied for three frequent sorption/desorption cycles with high performance. The impact of ionic strength on removal percentage of both dyes in binary mixture was studied by using NaCl and KCl soluble salts at different concentrations. According to our findings, only small dosage of the proposed MOF is considerably capable to remove large amounts of dyes at room temperature and in very short time that is a big advantage of MIL-68(Al) as a promising adsorbent for adsorptive removal processes.
Tehrani, Mahnaz Saghanejhad; Zare-Dorabei, Rouholah
2016-05-01
MIL-68(Al) as a metal-organic framework (MOF) was synthesized and characterized by different techniques such as SEM, BET, FTIR, and XRD analysis. This material was then applied for simulations removal of malachite green (MG) and methylene blue (MB) dyes from aqueous solutions using second order derivative spectrophotometric method (SODS) which was applied to resolve the overlap between the spectra of these dyes. The dependency of dyes removal efficiency in binary solutions was examined and optimized toward various parameters including initial dye concentration, pH of the solution, adsorbent dosage and ultrasonic contact time using central composite design (CCD) under response surface methodology (RSM) approach. The optimized experimental conditions were set as pH7.78, contact time 5min, initial MB concentration 22mgL(-1), initial MG concentration 12mgL(-1) and adsorbent dosage 0.0055g. The equilibrium data was fitted to isotherm models such as Langmuir, Freundlich and Tempkin and the results revealed the suitability of the Langmuir model. The maximum adsorption capacity of 666.67 and 153.85mgg(-1) was obtained for MB and MG removal respectively. Kinetics data fitting to pseudo-first order, pseudo-second order and Elovich models confirmed the applicability of pseudo-second order kinetic model for description of the mechanism and adsorption rate. Dye-loaded MIL-68(Al) can be easily regenerated using methanol and applied for three frequent sorption/desorption cycles with high performance. The impact of ionic strength on removal percentage of both dyes in binary mixture was studied by using NaCl and KCl soluble salts at different concentrations. According to our findings, only small dosage of the proposed MOF is considerably capable to remove large amounts of dyes at room temperature and in very short time that is a big advantage of MIL-68(Al) as a promising adsorbent for adsorptive removal processes. PMID:26890205
Energy Technology Data Exchange (ETDEWEB)
Salahinejad, E., E-mail: salahinejad@kntu.ac.ir [Faculty of Materials Science and Engineering, K.N. Toosi University of Technology, Tehran (Iran, Islamic Republic of); School of Materials Science and Engineering, Helmerich Advanced Technology Research Center, Oklahoma State University, Tulsa, OK (United States); Department of Materials Science and Engineering, School of Engineering, Shiraz University, Shiraz (Iran, Islamic Republic of); Hadianfard, M.J. [Department of Materials Science and Engineering, School of Engineering, Shiraz University, Shiraz (Iran, Islamic Republic of); Vashaee, D. [School of Electrical and Computer Engineering, Helmerich Advanced Technology Research Center, Oklahoma State University, Tulsa, OK (United States); Tayebi, L., E-mail: lobat.tayebi@okstate.edu [School of Materials Science and Engineering, Helmerich Advanced Technology Research Center, Oklahoma State University, Tulsa, OK (United States); School of Chemical Engineering, Oklahoma State University, Stillwater, OK (United States)
2014-03-15
Highlights: • By increasing pH, the thermal stability of the amorphous particles increases. • pH did not affect the size and morphology of the synthesized nanoparticles. • The thermal behavior was explained by the adsorption of hydroxide ions. -- Abstract: This paper concerns with the effect of pH on the structure and crystallization behavior of particulate sol–gel derived zirconium titanate. According to differential scanning calorimetry, it was found that the thermal stability of the synthesized amorphous particles was enhanced by increasing the precursor solution pH value from 4 to 10, as confirmed by X-ray diffraction. Transmission electron microscopy studies on the xerogel and crystallized nanoparticles showed that the pH value does not fairly affect their size and morphology; thus, these structural features cannot have a meaningful contribution to the detected crystallization difference. The realized thermal behavior was explained based on a mechanism relating to the adsorption of hydroxide ions (OH{sup −}) existing in the medium to metallic hydroxide precipitates synthesized during the sol–gel process. In this regard, it was speculated that the more the pH value is increased, as reasonably accompanied by the more hydroxide adsorption, the more the crystallization event is inhibited.
El-Faham, Ayman; Dahlous, Kholood A; Al Othman, Zeid A; Al-Lohedan, Hamad A; El-Mahdy, Gamal A
2016-03-31
Triazine derivatives, namely, 2,4,6-tris(quinolin-8-yloxy)-1,3,5-triazine (T3Q), N²,N⁴,N⁶-tris(pyridin-2-ylmethyl)-1,3,5-triazine-2,4,6-triamine (T3AMPy) and 2,2',2''-[(1,3,5-triazine-2,4,6-triyl)tris(azanediyl)] tris(ethan-1-ol) (T3EA) were synthesized and their inhibition of steel corrosion in hydrochloric acid solution was investigated using electrochemical techniques. The corrosion protection of the prepared compounds increased with increasing concentration and reached up to 98% at 250 ppm. The adsorption of T3Q, T3AMPy, and T3EA on the steel surface was in accordance with the Langmuir adsorption isotherm. The electrochemical results revealed that T3Q, T3AMPy and T3EA act as excellent organic inhibitors and can labeled as mixed type inhibitors. The efficiencies of the tested compounds were affected by the nature of the side chain present in the triazine ring, where T3EA gave the least inhibition while T3Q and T3AMPy gave higher and almost the same inhibition effects. The inhibition efficiencies obtained from the different electrochemical techniques were in good agreement.
Fouda, Abd El-Aziz S; Al-Sarawy, Ahmed A; Radwan, Mohamed S
2006-01-01
The effect of furfural benzoylhydrazone and its derivatives (I-VII) as corrosion inhibitors for C-steel in 1M phosphoric acid solution has been studied by weight-loss and galvanostatic polarization techniques. A significant decrease in the corrosion rate of C-steel was observed in the presence of the investigated inhibitors. This study revealed that, the inhibition efficiency increases with increasing the inhibitor concentration, and the addition of iodide ions enhances it to a considerable extent. The effect of temperature on the inhibition efficiency of these compounds was studied using weight-loss method. Activation energy (E(a)*) and other thermodynamic parameters for the corrosion process were calculated and discussed. The galvanostatic polarization data indicated that, the inhibitors were of mixed-type, but the cathode is more polarized than the anode. The adsorption of these compounds on C-steel surface has been found to obey Frumkin's adsorption isotherm. The mechanism of inhibition was discussed in the light of the chemical structure of the undertaken inhibitors.
International Nuclear Information System (INIS)
After briefly reviewing the present understanding of the nucleation process of YBCO films, a new approach is presented to enhance the stability of c-axis nucleation in epitaxial chemical solution deposited YBCO thin films derived from TFA precursors. We show that with silver addition to the TFA precursor c-axis nucleation can be reached in a wide range of temperature thus keeping high percolating Jc. We argue that silver reduces supersaturation and makes more stable the c-axis nuclei without modifying Tc. Additional advantages of silver addition are an enhanced surface smootheness and a reduced porosity of the YBCO films. The second reported topic relates to the discovery of an adverse relationship between percolating Jc and YBCO films mesostrain, as determined through X-ray diffraction line broadening. We show that mesostrain is enhanced in processes leading to inefficient strain healing at grain boundaries, for instance annealing times too short or growth temperatures too low. It is suggested that the strained regions at the low angle grain boundaries lead to a weak link behavior which can be microscopically understood on the basis of pair formation prevention, as proposed by the bond contraction pairing model.
Obradors, X.; Martínez-Julián, F.; Zalamova, K.; Vlad, V. R.; Pomar, A.; Palau, A.; Llordés, A.; Chen, H.; Coll, M.; Ricart, S.; Mestres, N.; Granados, X.; Puig, T.; Rikel, M.
2012-11-01
After briefly reviewing the present understanding of the nucleation process of YBCO films, a new approach is presented to enhance the stability of c-axis nucleation in epitaxial chemical solution deposited YBCO thin films derived from TFA precursors. We show that with silver addition to the TFA precursor c-axis nucleation can be reached in a wide range of temperature thus keeping high percolating Jc. We argue that silver reduces supersaturation and makes more stable the c-axis nuclei without modifying Tc. Additional advantages of silver addition are an enhanced surface smootheness and a reduced porosity of the YBCO films. The second reported topic relates to the discovery of an adverse relationship between percolating Jc and YBCO films mesostrain, as determined through X-ray diffraction line broadening. We show that mesostrain is enhanced in processes leading to inefficient strain healing at grain boundaries, for instance annealing times too short or growth temperatures too low. It is suggested that the strained regions at the low angle grain boundaries lead to a weak link behavior which can be microscopically understood on the basis of pair formation prevention, as proposed by the bond contraction pairing model.
Energy Technology Data Exchange (ETDEWEB)
Levay, Bela [Department of Nuclear Chemistry, Eoetvoes Lorand University, Budapest (Hungary)], E-mail: levay@para.chem.elte.hu; Szabo, Denes [Department of Organic Chemistry, Eoetvoes Lorand University, Budapest (Hungary)
2006-08-01
The effect of changes in the chemical structure of organic sulfur compounds on their reactivity towards an ortho-positronium (o-Ps) atom was investigated by positron annihilation lifetime spectroscopy in dimethylsulfoxide solutions. S-bridge containing molecules with very similar structural frameworks were selected as model systems, such as, diphenyl sulfide, sulfoxide and sulfone, and their derivatives. The effect of the type of the S-bridge on the reactivity increased in the order of S < SO < SO{sub 2} in all groups of the compounds with similar substituents on their phenyl groups. The same trend was observed for the calculated excess positive charge on the sulfur atoms and the LUMO energies of the molecules too. As it was expected, electron-withdrawing substituents on the aromatic rings increased both the reactivity and the negative values of the LUMO energy of the molecules (COOH < NO{sub 2}) whereas those with electron-donating character (CH{sub 3}O) showed the opposite effect.
Little, Mark P; Gola, Anna; Tzoulaki, Ioanna; Vandoolaeghe, Wendy
2009-01-01
The paper of Little et al. (PloS Comput Biol 2009 5(10) e1000539) outlined a system of reaction-diffusion equations that were used to describe induction of atherosclerotic disease. These were solved by considering an equilibrium solution and small perturbations around this equilibrium. Here we consider slight variant sets of assumptions that could be used to derive equilibrium solutions. In general they do not imply any change in the numerical results relating to monocyte chemo-attractant pro...
Institute of Scientific and Technical Information of China (English)
曹建莉
2007-01-01
Finite-dimensional integrable Hamiltonian systems, obtained through the nonlinearization of the 3×3 spectral problems associated with the Manakov and the derivative Manakov equations, are investigated. A generating function method is used to give a simple and effective way to prove the involutivity of integrals. Finite-parameter solutions of the Manakov and the derivative Manakov equations are calculated based on the commutative systems of ordinary differential equations with these integrals as Hamiltonians.
Chatterjee, Kausik
2016-06-01
The objective of this paper is the extension and application of a newly-developed Green's function Monte Carlo (GFMC) algorithm to the estimation of the derivative of the solution of the one-dimensional (1D) Helmholtz equation subject to Neumann and mixed boundary conditions problems. The traditional GFMC approach for the solution of partial differential equations subject to these boundary conditions involves "reflecting boundaries" resulting in relatively large computational times. My work, inspired by the work of K.K. Sabelfeld is philosophically different in that there is no requirement for reflection at these boundaries. The underlying feature of this algorithm is the elimination of the use of reflecting boundaries through the use of novel Green's functions that mimic the boundary conditions of the problem of interest. My past work has involved the application of this algorithm to the estimation of the solution of the 1D Laplace equation, the Helmholtz equation and the modified Helmholtz equation. In this work, this algorithm has been adapted to the estimation of the derivative of the solution which is a very important development. In the traditional approach involving reflection, to estimate the derivative at a certain number of points, one has to a priori estimate the solution at a larger number of points. In the case of a one-dimensional problem for instance, to obtain the derivative of the solution at a point, one has to obtain the solution at two points, one on each side of the point of interest. These points have to be close enough so that the validity of the first-order approximation for the derivative operator is justified and at the same time, the actual difference between the solutions at these two points has to be at least an order of magnitude higher than the statistical error in the estimation of the solution, thus requiring a significantly larger number of random-walks than that required for the estimation of the solution. In this new approach
Lin, Li-Rong; Wang, Xuan; Wei, Gao-Ning; Tang, Hui-Hui; Zhang, Hui; Ma, Li-Hua
2016-10-14
Novel azobenzene-derived β-diketonates (4,4,5,5,6,6,6-heptafluoro-1-azobenzene-1,3-hexanedione (LA), 4,4,5,5,6,6,6-heptafluoro-1-(4-dimethylamino)azobenzene-1,3-hexanedione (LB)) were designed and their complexes with lanthanide cations (La(3+), Eu(3+), Gd(3+), Yb(3+)) were prepared and characterized by (1)H NMR, FT-IR, and elemental analysis. Three of the complexes were crystallized successfully and identified by X-ray diffraction. It was significant to find that LA showed remarkably reversible trans-to-cis isomerization properties, however, LB, bearing an electron donor compared with LA, slowed down the isomerization to an extent. The presence of Ln(iii) enhanced the reversible trans-to-cis isomerization properties of both LA and LB a little upon photoirradiation in organic solvents, and amazingly increased the fatigue resistance. In addition, the complexes doped in polymethyl methacrylate (PMMA) films produced a similar phenomenon as well as when in solution. Theoretical calculations based on time dependent density functional theory (TD-DFT) were performed for geometry optimization and to determine the excitation energies of LA and LB to gain further insight into the electronic structure of the complexes, and the data were consistent with the experimental results. The excellent reversible photoisomerization properties of the newly designed Ln(iii) complexes can offer important advantages that will help with the further study of these materials to reach their full potential in applications such as molecular switching devices.
Energy Technology Data Exchange (ETDEWEB)
Aviv, Hagit [Department of Chemistry, Bar-Ilan University (Israel); Institute for Nanotechnology and Advanced Materials, Bar-Ilan University (Israel); Tischler, Yaakov R., E-mail: yrt@biu.ac.il [Department of Chemistry, Bar-Ilan University (Israel); Institute for Nanotechnology and Advanced Materials, Bar-Ilan University (Israel)
2015-02-15
Here we present the synthesis and optical characterization of a new amphiphilic cyanine dye, 1,1′-dioctadecane-3,3′-di(4-sulfobutyl)-5,5′,6,6′-tetrachloro -benzimidazolocarbo-cyanine (C18S4). C18S4 is a derivative of the heavily studied J-aggregating cyanine dye TDBC that was designed specifically for creating stable amphiphilic monolayers when spread at an air–water interface. Unlike TDBC, which readily J-aggregates in water, we show that C18S4 introduced into water tends to produce micelles with monomeric spectral properties and only exhibits strong J-aggregation after an emulsification procedure and a week of dye reorganization. When deposited on a Langmuir Blodgett (LB) trough, C18S4 forms a stable monolayer with a repeatable isotherm. Layers transferred via LB deposition to a functionalized glass substrate show pronounced J-aggregation, depending on the surface transfer pressure. Layers transferred at 35 mN/m present an intense narrow absorption spectrum peaked at λ=589 nm with FWHM=523 cm{sup −1} (18 nm). The accompanying fluorescence shows a narrow spectrum with FWHM=332 cm{sup −1} (11.5 nm) and a Stokes shift less than 1 nm. The ability to create J-aggregates of C18S4 via LB deposition provides control over the J-aggregation process of TDBC-like molecules and can ultimately lead to tuning the J-aggregate coupling for specific experiments and applications. - Highlights: • C18S4 is an amphiphilic J-aggregating cyanine dye. • C18S4 J-aggregates in aqueous solution. • C18S4 forms a stable isotherm when spread at the air–water interface. • C18S4 J-aggregates at an air–water interface upon compression. • Langmuir–Blodgett J-aggregated films have narrow absorption and emission spectra.
Khaled, K. F.
2010-09-01
The effects of thiourea derivatives, namely N-methyl thiourea (MTU), N-propyl thiourea (PTU) and N-allyl thiourea (ATU) on the corrosion behaviour of iron in 1.0 M solution of HNO 3 have been investigated in relation to the concentration of thiourea derivatives. The experimental data obtained using the techniques of weight loss, Tafel polarization and electrochemical impedance spectroscopy, EIS. The results showed that these compounds revealed a good corrosion inhibition, (ATU) being the most efficient and (MTU) the least. Computational studies have been used to find the most stable adsorption sites for thiourea derivatives. This information help to gain further insight about corrosion system, such as the most likely point of attack for corrosion on iron (1 1 0), the most stable site for thiourea derivatives adsorption and the binding energy of the adsorbed layer. The efficiency order of the inhibitors obtained by experimental results was verified by theoretical analysis.
Energy Technology Data Exchange (ETDEWEB)
Park, Hong-Gyu; Lee, Yun-Gun; Jang, Sang Bok; Lee, Ju Hwan; Jeong, Hae-Chang; Seo, Dae-Shik, E-mail: dsseo@yonsei.ac.kr [Information Display Device Laboratory, Department of Electrical and Electronic Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 120-749 (Korea, Republic of); Oh, Byeong-Yun [ZeSHTech Co., Ltd., Business Incubator, Gwangju Institute of Science and Technology, 123, Cheomdangwagi-ro, Buk-gu, Gwangju 500-712 (Korea, Republic of)
2015-11-15
Hafnium yttrium gallium oxide (HfYGaO) films were applied to liquid crystal displays (LCDs) as liquid crystal (LC) alignment layers, replacing conventional polyimide (PI) layers. The HfYGaO alignment layers were prepared by fabricating solution-processed HfYGaO films, annealing them, and treating them with ion-beam (IB) irradiation. The authors studied the effects of annealing temperature and IB irradiation of the solution-derived HfYGaO films on the orientation of LC molecules. The LC molecules on the solution-derived HfYGaO films were homogeneously and uniformly aligned by IB irradiation, irrespective of the annealing temperature. Atomic force microscopy analyses revealed that the surface reformation of the HfYGaO films induced by IB irradiation strengthened the van der Waals force between the LC molecules and the HfYGaO films, leading to uniform LC alignment. Enhanced electro-optical characteristics were observed in the twisted-nematic (TN) LCDs based on IB-irradiated HfYGaO films compared with those of TN-LCDs based on PI layers, demonstrating the high application potential of the proposed solution-derived HfYGaO films as LC alignment layers.
International Nuclear Information System (INIS)
Azo-dyes derivative (HL) sorbent was synthesized according to the literature to be used in the adsorption and preconcentration of Th(IV) ions from aqueous solution and it was exposed to immobilization, and new solid support material was obtained. For this purpose, azo-dyes derivative (HL) was chemically bonded to silica gel surface immobilized 3-chloropropyl trimethoxysilane, then analyzed by FTIR, BET, SEM and elemental analysis. The influence of the solution pH, initial Th(IV) concentration, amount of sorbent, contact time, temperature and foreign ion effect was investigated. The maximum Th(IV) uptake capacity was found to be 24.85 ± 0.2 mg/g. (author)
Takahashi, Daisuke A
2015-01-01
The matrix-generalized Bogoliubov-de Gennes systems are recently considered by the present author [arXiv:1509.04242], and the time-dependent and self-consistent multi-soliton solutions are constructed based on the ansatz method. In this paper, restricting the problem to the static case, we exhaustively determine the self-consistent solutions using the inverse scattering theory. Solving the gap equation, we rigorously prove that the self-consistent potential must be reflectionless. As a supplementary topic, we elucidate the relation between the stationary self-consistent potentials and the soliton solutions in the matrix nonlinear Schr\\"odinger equation. The asymptotic formulae of multi-soliton solutions for sufficiently isolated solitons are also presented.
Institute of Scientific and Technical Information of China (English)
Nourallah Hazeri; Malek Taher Maghsoodlou; Fatemeh Mir; Mehrnoosh Kangani; Hamideh Saravani; Ebrahim Molashahi
2014-01-01
Tetrahydrobenzo[b]pyran and 3,4-dihydropyrano[c]chromene derivatives were synthesized via a one-pot three-component condensation of aromatic aldehydes with malononitrile and dimedone or 4-hydroxycoumarin in excellent yields in the presence of starch solution as a highly efficient ho-mogenous catalyst. The use of a nontoxic and biodegradable catalyst, simple work-up procedure, and short reaction time are advantages of this method.
Mahmood, A.; Parveen, S.; Ara, A.; Khan, N. A.
2009-08-01
The velocity field and the associated shear stress corresponding to the torsional oscillatory flow of a generalized Maxwell fluid, between two infinite coaxial circular cylinders, are determined by means of the Laplace and Hankel transforms. Initially, the fluid and cylinders are at rest and after some time both cylinders suddenly begin to oscillate around their common axis with different angular frequencies of their velocities. The solutions that have been obtained are presented under integral and series forms in terms of generalized G and R functions. Moreover, these solutions satisfy the governing differential equation and all imposed initial and boundary conditions. The respective solutions for the motion between the cylinders, when one of them is at rest, can be obtained from our general solutions. Furthermore, the corresponding solutions for the similar flow of ordinary Maxwell fluid are also obtained as limiting cases of our general solutions. At the end, flows corresponding to the ordinary Maxwell and generalized Maxwell fluids are shown and compared graphically by plotting velocity profiles at different values of time and some important results are remarked.
Ghosh, Uttam; Sengupta, Srijan; Sarkar, Susmita; Das, Shantanu
2015-01-01
There is no unified method to solve the fractional differential equation. The type of derivative here used in this paper is of Jumarie formulation, for the several differential equations studied. Here we develop an algorithm to solve the linear fractional differential equation composed via Jumarie fractional derivative in terms of Mittag-Leffler function; and show its conjugation with ordinary calculus. In these fractional differential equations the one parameter Mittag-Leffler function plays...
Soklakov, Andrei N.
2013-01-01
Quantitative Structuring is a rigorous framework for the design of financial products. We show how it incorporates traditional investment ideas while supporting a more accurate expression of clients' views on the market. We briefly touch upon adjacent topics regarding the safety of financial derivatives and the role of pricing models in product design.
Energy Technology Data Exchange (ETDEWEB)
Jeong, Hae-Chang; Park, Hong-Gyu; Lee, Ju Hwan; Seo, Dae-Shik, E-mail: dsseo@yonsei.ac.kr [Information Display Device Laboratory, Department of Electrical and Electronic Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 120-749 (Korea, Republic of); Oh, Byeong-Yun [ZeSHTech Co., Ltd., Business Incubator, Gwangju Institute of Science and Technology, 123, Cheomdangwagi-ro, Buk-gu, Gwangju 500-712 (Korea, Republic of)
2015-11-15
The authors demonstrate a high performance electrically controlled birefringence (ECB) mode with solution-derived La{sub 2}O{sub 3} films at various molar concentrations. Uniform and homogeneous liquid crystal (LC) alignment was spontaneously achieved on the La{sub 2}O{sub 3} films for lanthanum concentrations at ratios greater than and equal to 0.2. A preferred orientation of LC molecules appeared along the filling direction, and the LC alignment was maintained via van der Waals force by nanocrystals of the La{sub 2}O{sub 3} films. The LC alignment mechanism was confirmed by x-ray photoelectron spectroscopy and high-resolution transmission electron microscopy analysis. Superior electro-optical characteristics of the ECB cells constructed with solution-derived La{sub 2}O{sub 3} films were observed, which suggests that the proposed solution-derived La{sub 2}O{sub 3} films have strong potential for use in the production of advanced LC displays.
Exact solutions for the flow of non-Newtonian fluid with fractional derivative in an annular pipe
Institute of Scientific and Technical Information of China (English)
TONG; Dengke; WANG; Ruihe; YANG; Heshan
2005-01-01
This paper deals with some unsteady unidirectional transient flows of Oldroyd-B fluid in an annular pipe. The fractional calculus approach in the constitutive relationship model Oldroyd-B fluid is introduced and a generalized Jeffreys model with the fractional calculus has been built. Exact solutions of some unsteady flows of Oldroyd-B fluid in an annular pipe are obtained by using Hankel transform and Laplace transform for fractional calculus. The following four problems have been studied: (1) Poiseuille flow due to a constant pressure gradient; (2) axial Couette flow in an annulus; (3) axial Couette flow in an annulus due to a longitudinal constant shear; (4) Poiseuille flow due to a constant pressure gradient and a longitudinal constant shear. The well-known solutions for Navier-Stokes fluid, as well as those corresponding to a Maxwell fluid and a second grade one, appear as limited cases of our solutions.
Energy Technology Data Exchange (ETDEWEB)
Claesson, J.; Probert, T. [Lund Univ. (Sweden). Dept. of Building Physics and Mathematical Physics
1996-01-01
The temperature field in rock due to a large rectangular grid of heat releasing canisters containing nuclear waste is studied. The solution is by superposition divided into different parts. There is a global temperature field due to the large rectangular canister area, while a local field accounts for the remaining heat source problem. The global field is reduced to a single integral. The local field is also solved analytically using solutions for a finite line heat source and for an infinite grid of point sources. The local solution is reduced to three parts, each of which depends on two spatial coordinates only. The temperatures at the envelope of a canister are given by a single thermal resistance, which is given by an explicit formula. The results are illustrated by a few numerical examples dealing with the KBS-3 concept for storage of nuclear waste. 8 refs.
McDuffee, Ryan
2016-01-01
Recent observations of gravitational waves by the Laser Interferometer Gravitational-Wave Observatory (LIGO) has confirmed one of the last outstanding predictions in general relativity and in the process opened up a new frontier in astronomy and astrophysics. Additionally the observation of gravitational waves has also given us the data needed to deduce the physical properties of space time. Bredberg et al have shown in their 2011 paper titled From Navier-Stokes to Einstein, that for every solution of the incompressible Navier-Stokes equation in p + 1 dimensions, there is a uniquely associated dual" solution of the vacuum Einstein equations in p + 2 dimensions. The author shows that the physical properties of space time can be deduced using the recent measurements from the Laser Interferometer Gravitational-Wave Observatory and solutions from the incompressible Navier-Stokes equation.
Owolabi, Kolade M.; Atangana, Abdon
2016-09-01
In this paper, dynamics of time-dependent fractional-in-space nonlinear Schrödinger equation with harmonic potential V(x),x in R in one, two and three dimensions have been considered. We approximate the Riesz fractional derivative with the Fourier pseudo-spectral method and advance the resulting equation in time with both Strang splitting and exponential time-differencing methods. The Riesz derivative introduced in this paper is found to be so convenient to be applied in models that are connected with applied science, physics, and engineering. We must also report that the Riesz derivative introduced in this work will serve as a complementary operator to the commonly used Caputo or Riemann-Liouville derivatives in the higher-dimensional case. In the numerical experiments, one expects the travelling wave to evolve from such an initial function on an infinite computational domain (-∞, ∞) , which we truncate at some large, but finite values L. It is important that the value of L is chosen large enough to give enough room for the wave function to propagate. We observe a different distribution of complex wave functions for the focusing and defocusing cases.
Tan, Kemin; Chang, Changsoo; Cuff, Marianne; Osipiuk, Jerzy; Landorf, Elizabeth; Mack, Jamey C; Zerbs, Sarah; Joachimiak, Andrzej; Collart, Frank R
2013-10-01
Lignin comprises 15-25% of plant biomass and represents a major environmental carbon source for utilization by soil microorganisms. Access to this energy resource requires the action of fungal and bacterial enzymes to break down the lignin polymer into a complex assortment of aromatic compounds that can be transported into the cells. To improve our understanding of the utilization of lignin by microorganisms, we characterized the molecular properties of solute binding proteins of ATP-binding cassette transporter proteins that interact with these compounds. A combination of functional screens and structural studies characterized the binding specificity of the solute binding proteins for aromatic compounds derived from lignin such as p-coumarate, 3-phenylpropionic acid and compounds with more complex ring substitutions. A ligand screen based on thermal stabilization identified several binding protein clusters that exhibit preferences based on the size or number of aromatic ring substituents. Multiple X-ray crystal structures of protein-ligand complexes for these clusters identified the molecular basis of the binding specificity for the lignin-derived aromatic compounds. The screens and structural data provide new functional assignments for these solute-binding proteins which can be used to infer their transport specificity. This knowledge of the functional roles and molecular binding specificity of these proteins will support the identification of the specific enzymes and regulatory proteins of peripheral pathways that funnel these compounds to central metabolic pathways and will improve the predictive power of sequence-based functional annotation methods for this family of proteins.
Directory of Open Access Journals (Sweden)
Alireza Rahbar
2016-09-01
Full Text Available In this experimental data article, a novel biomaterial was provided from Malva sylvestris and characterized its properties using various instrumental techniques. The operating parameters consisted of pH and adsorbent dose on Hg2+ adsorption from aqueous solution using M. sylvestris powder (MSP were compared with charcoal tablet powder (CTP, a medicinal drug. The data acquired showed that M. sylvestris is a viable and very promising alternative adsorbent for Hg2+ removal from aqueous solutions. The experimental data suggest that the MSP is a potential adsorbent to use in medicine for treatment of poisoning with heavy metals; however, the application in animal models is a necessary step before the eventual application of MSP in situations involving humans.
Reactions between cerium(IV) and methyl-6-x-derivatives of aniline in perchloric acid solutions
International Nuclear Information System (INIS)
The oxidation of 2,6-dimethyl-, 2-isopropyl-6-methyl, 2-chloro-6-methyl-and 2-methyl-6-nitro aniline with cerium(IV) in perchloric acid solutions has been examined. It has been found that the concentration of hydrogen ions and the basicity of nitrogen atom in the amine group decide about the resultant intermediate products. Some of these products can be practically prepared using cerium(IV) as an oxidizing agent. (author). 16 refs, 1 tab
International Nuclear Information System (INIS)
La2Zr2O7/NiW buffer layers as very promising buffer layers for coated conductors were fabricated by chemical solution deposition using cheap precursors, La-acetate and Zr-(IV) n-propoxide (70% w/w in n-propanol). The effects on the orientation and microstructure of La2Zr2O7 buffer layers, including seed layer, thickness and solution concentration, were investigated. The results showed that insertion of a seed layer could obviously improve the crystallization and orientation, and decrease of single layer thickness could also obviously improve the in-plane orientation. The results of all metalorganic depositions derived YBCO/CeO2/La2Zr2O7/NiW showed that the prepared La2Zr2O7 buffer layers were suitable for coated conductors using all metalorganic depositions
Energy Technology Data Exchange (ETDEWEB)
Pourjavid, Mohammad Reza [Islamic Azad University, Tehran (Iran, Islamic Republic of). Dept. of Medicinal Chemistry. Nuclear Science and Technology Research Institute; Rezaee, Mohammad; Hosseini, Majid Haji [Nuclear Science and Technology Research Institute, Tehran (Iran, Islamic Republic of); Razavi, Taherehsadat, E-mail: pourjavid@gmail.com [Research Institute of Petroleum Industry, Tehran (Iran, Islamic Republic of). Instrumental Analysis Dept.
2012-07-01
A furan-triazole derivative has been explored as an ionophore for preparation of a highly selective Pr(III) membrane sensor. The proposed sensor exhibits a Nernstian response for Pr(III) activity over a wide concentration range with a detection limit of 5.2 x 10{sup -8}M. Its response is independent of pH of the solution in the range 3.0-8.8 and offers the advantages of fast response time. To investigate the analytical applicability of the sensor, it was applied successfully as an indicator electrode in potentiometric titration of Pr(III) solution and also in the direct and indirect determination of trace Pr(III) ions in some samples. (author)
Energy Technology Data Exchange (ETDEWEB)
Maia, Ana M.S.; Vidal, Rosangela R.L.; Balaban, Rosangela C., E-mail: balaban@supercabo.com.b [Universidade Federal do Rio Grande do Norte (LAPET/DQ/UFRN), Natal, RN (Brazil). Dept. de Quimica. Lab. de Pesquisa em Petroleo; Villetti, Marcos A. [Universidade Federal de Santa Maria (DF/UFSM), RS (Brazil). Dept. de Fisica; Borsali, Redouane [Universite Bordeaux 1, Pessac Cedex (France)
2011-07-01
A hydrophobically-modified polyacrylamide and two partially hydrolyzed derivatives containing hydrophobic and carboxylic groups were prepared by micellar polymerization and post hydrolysis. The molecular weight, second virial coefficient and radius of gyration were determined by static light scattering (SLS). Dynamic light scattering (DLS) and small-angle X-ray scattering (SAXS) were employed to determine the aggregate formation and type of chain packing in the semidilute regime, respectively. The behavior of solutions in dilute and semidilute regimes was also studied by viscometry and rheology. The hydrophobically-modified polyacrylamide showed a tendency to form aggregates due to the hydrophobic groups, but not enough to increase apparent viscosity. The partially hydrolyzed derivatives did not show the same aggregate-forming tendency. Rather, they exhibited anisotropic behavior, due to the charge density introduced into the polymer chain, which led to a more elongated macromolecular conformation and higher viscosity. (author)
Long, S. A. T.
1974-01-01
Formulas are derived for the root-mean-square (rms) displacement, slope, and curvature errors in an azimuth-elevation image trace of an elongated object in space, as functions of the number and spacing of the input data points and the rms elevation error in the individual input data points from a single observation station. Also, formulas are derived for the total rms displacement, slope, and curvature error vectors in the triangulation solution of an elongated object in space due to the rms displacement, slope, and curvature errors, respectively, in the azimuth-elevation image traces from different observation stations. The total rms displacement, slope, and curvature error vectors provide useful measure numbers for determining the relative merits of two or more different triangulation procedures applicable to elongated objects in space.
Directory of Open Access Journals (Sweden)
M. Lebrini
2013-01-01
Full Text Available The corrosion rates in the presence of some indole derivates, namely, 9H-pyrido[3,4-b]indole (norharmane and 1-methyl-9H-pyrido[3,4-b]indole (harmane, as inhibitors of C38 steel corrosion inhibitor in 1 M HCl solution, were measured by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS techniques, in the range of temperatures from 25 to 55∘C. Results obtained revealed that the organic compounds investigated have inhibiting properties for all temperatures. The inhibition was assumed to occur via adsorption of the indole molecules on the metal surface. Adsorption of indole derivates was found to follow the Langmuir isotherm. The apparent activation energies, enthalpies, and entropies of the dissolution process and the free energies and enthalpies for the adsorption process were determined by potentiodynamic polarization and electrochemical impedance. The fundamental thermodynamic functions were used to collect important information about indole inhibitory behaviour.
McConaughy, Shawn D; Stroud, Paul A; Boudreaux, Brent; Hester, Roger D; McCormick, Charles L
2008-02-01
A series of highly purified galacturonate polysaccharides have been extracted from the Aloe vera plant and analyzed in terms of chemical composition and molecular weight. This Aloe vera polysaccharide (AvP) has been found to exist as a high molecular weight species and possess a unique chemical composition, including a high galacturonic acid (GalA) content and low degree of methyl ester substitution. These factors facilitate gel formation upon exposure to low concentrations of calcium ions, leading to potential application in formulations designed for in situ nasal or subcutaneous protein delivery. Thorough examination of classic dilute solution properties, the [eta]-M(w), and R(g)-M(w) relationships, persistence length (L(p)), and inherent chain stiffness (B parameter), indicate an expanded random coil in aqueous salt solutions. The critical concentration for transition from dilute to concentrated solution, C(e), was determined by measuring both the zero shear viscosity (eta(o)) and fluorescence emission of the probe molecule 1,8-anilino-1-naphthalene sulfonic acid (1,8-ANS) as a function of polymer concentration. Examination of zeta potential and C(e) as a function of ionic strength indicates that the shift in C(e) from 0.60 to 0.30 wt % is related to an increased occurrence of intermolecular interactions at high salt concentrations. Additionally, dynamic rheology data are presented highlighting the ability of AvP to form gels at low polymer and calcium ion concentrations, exemplifying the technological potential of this polysaccharide for in situ drug delivery.
DEFF Research Database (Denmark)
Bunk, Oliver; Nielsen, Martin Meedom; Sølling, Theis Ivan;
2003-01-01
crystalline HBC-C8,2 majority phases result. In all three phases, the HBC-C8,2 molecules self-organize into columns which are uniaxially aligned along the direction defined by the PTFE macromolecules of the substrate. The three phases are quite similar, the major difference being their orientation......A surface X-ray diffraction study is presented showing that highly ordered and uniaxially aligned hexa(3,7-dimethyl-octanyl)hexa-peri-hexabenzocoronene (HBC-C8,2) films can be fabricated by crystallization from solution onto friction-transferred poly(tetrafluoroethylene) (PTFE) layers. Three...
Inoue, Atsushi
In this note, we construct a strong solution of the space-time Hopf equation, (partial /{partial t} - vΔ ){δ Z(η )}/{δ η _ell (x,t)} = ileft[ {tilde T^* left\\{ {{δ ^2 Z(η )}/{δ η _j (x,t)δ η _k (x,t)}} right\\}} right]^ell + if^ell (x,t)Z(η ) with certain subsidary conditions, which is an example of functional derivative equations and is manageable using a tiny part of "analysis in functional spaces".
International Nuclear Information System (INIS)
Highlights: • First application of a DNA derived fluorescent bio-dot for metal sensing. • Bio-dot was conveniently obtained via a mild thermal hydro-thermal synthesis. • Bio-dot was directly used for fluorescent sensing without further modification. • Bio-dot showed good fluorescent sensing property for Hg(II) and Ag(I). • Formation of T–Hg–T and C–Ag–C structures played key roles in sensing. - Abstract: Inspired by the high affinity between heavy metal ions and bio-molecules as well as the low toxicity of carbon-based quantum dots, we demonstrated the first application of a DNA derived carbonaceous quantum dots, namely bio-dots, in metal ion sensing. The present DNA-derived bio-dots contain graphitic carbon layers with 0.242 nm lattice fringes, exhibit excellent fluorescence property and can be obtained via a facile hydrothermal preparation procedure. Hg(II) and Ag(I) are prone to be captured by the bio-dots due to the existence of residual thymine (T) and cytosine (C) groups, resulting in a quenched fluorescence while other heavy metal ions would cause negligible changes on the fluorescent signals of the bio-dots. The bio-dots could be used as highly selective toxic-free biosensors, with two detecting linear ranges of 0–0.5 μM and 0.5–6 μM for Hg(II) and one linear range of 0–10 μM for Ag(I). The detection limits (at a signal-to-noise ratio of 3) were estimated to be 48 nM for Hg(II) and 0.31 μM for Ag(I), respectively. The detection of Hg(II) and Ag(I) could also be realized in the real water sample analyses, with satisfying recoveries ranging from 87% to 100%
Energy Technology Data Exchange (ETDEWEB)
Song, Ting [Laboratory of Environmental Science and Technology, Xinjiang Technical Institute of Physics & Chemistry, Key Laboratory of Functional Materials and Devices for Special Environments, Chinese Academy of Sciences, Urumqi 830011 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Zhu, Xuefeng, E-mail: zhuxf@ms.xjb.ac.cn [Laboratory of Environmental Science and Technology, Xinjiang Technical Institute of Physics & Chemistry, Key Laboratory of Functional Materials and Devices for Special Environments, Chinese Academy of Sciences, Urumqi 830011 (China); Zhou, Shenghai [Laboratory of Environmental Science and Technology, Xinjiang Technical Institute of Physics & Chemistry, Key Laboratory of Functional Materials and Devices for Special Environments, Chinese Academy of Sciences, Urumqi 830011 (China); Yang, Guang [Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education and International Center for Dielectric Research, Xi’an Jiaotong University, Xi’an 710049 (China); Gan, Wei [Laboratory of Environmental Science and Technology, Xinjiang Technical Institute of Physics & Chemistry, Key Laboratory of Functional Materials and Devices for Special Environments, Chinese Academy of Sciences, Urumqi 830011 (China); Yuan, Qunhui, E-mail: yuanqh@ms.xjb.ac.cn [Laboratory of Environmental Science and Technology, Xinjiang Technical Institute of Physics & Chemistry, Key Laboratory of Functional Materials and Devices for Special Environments, Chinese Academy of Sciences, Urumqi 830011 (China)
2015-08-30
Highlights: • First application of a DNA derived fluorescent bio-dot for metal sensing. • Bio-dot was conveniently obtained via a mild thermal hydro-thermal synthesis. • Bio-dot was directly used for fluorescent sensing without further modification. • Bio-dot showed good fluorescent sensing property for Hg(II) and Ag(I). • Formation of T–Hg–T and C–Ag–C structures played key roles in sensing. - Abstract: Inspired by the high affinity between heavy metal ions and bio-molecules as well as the low toxicity of carbon-based quantum dots, we demonstrated the first application of a DNA derived carbonaceous quantum dots, namely bio-dots, in metal ion sensing. The present DNA-derived bio-dots contain graphitic carbon layers with 0.242 nm lattice fringes, exhibit excellent fluorescence property and can be obtained via a facile hydrothermal preparation procedure. Hg(II) and Ag(I) are prone to be captured by the bio-dots due to the existence of residual thymine (T) and cytosine (C) groups, resulting in a quenched fluorescence while other heavy metal ions would cause negligible changes on the fluorescent signals of the bio-dots. The bio-dots could be used as highly selective toxic-free biosensors, with two detecting linear ranges of 0–0.5 μM and 0.5–6 μM for Hg(II) and one linear range of 0–10 μM for Ag(I). The detection limits (at a signal-to-noise ratio of 3) were estimated to be 48 nM for Hg(II) and 0.31 μM for Ag(I), respectively. The detection of Hg(II) and Ag(I) could also be realized in the real water sample analyses, with satisfying recoveries ranging from 87% to 100%.
Ford Versypt, Ashlee N.; Arendt, Paul D.; Pack, Daniel W.; Braatz, Richard D.
2015-01-01
A mathematical reaction-diffusion model is defined to describe the gradual decomposition of polymer microspheres composed of poly(D,L-lactic-co-glycolic acid) (PLGA) that are used for pharmaceutical drug delivery over extended periods of time. The partial differential equation (PDE) model treats simultaneous first-order generation due to chemical reaction and diffusion of reaction products in spherical geometry to capture the microsphere-size-dependent effects of autocatalysis on PLGA erosion that occurs when the microspheres are exposed to aqueous media such as biological fluids. The model is solved analytically for the concentration of the autocatalytic carboxylic acid end groups of the polymer chains that comprise the microspheres as a function of radial position and time. The analytical solution for the reaction and transport of the autocatalytic chemical species is useful for predicting the conditions under which drug release from PLGA microspheres transitions from diffusion-controlled to erosion-controlled release, for understanding the dynamic coupling between the PLGA degradation and erosion mechanisms, and for designing drug release particles. The model is the first to provide an analytical prediction for the dynamics and spatial heterogeneities of PLGA degradation and erosion within a spherical particle. The analytical solution is applicable to other spherical systems with simultaneous diffusive transport and first-order generation by reaction. PMID:26284787
Directory of Open Access Journals (Sweden)
Ashlee N Ford Versypt
Full Text Available A mathematical reaction-diffusion model is defined to describe the gradual decomposition of polymer microspheres composed of poly(D,L-lactic-co-glycolic acid (PLGA that are used for pharmaceutical drug delivery over extended periods of time. The partial differential equation (PDE model treats simultaneous first-order generation due to chemical reaction and diffusion of reaction products in spherical geometry to capture the microsphere-size-dependent effects of autocatalysis on PLGA erosion that occurs when the microspheres are exposed to aqueous media such as biological fluids. The model is solved analytically for the concentration of the autocatalytic carboxylic acid end groups of the polymer chains that comprise the microspheres as a function of radial position and time. The analytical solution for the reaction and transport of the autocatalytic chemical species is useful for predicting the conditions under which drug release from PLGA microspheres transitions from diffusion-controlled to erosion-controlled release, for understanding the dynamic coupling between the PLGA degradation and erosion mechanisms, and for designing drug release particles. The model is the first to provide an analytical prediction for the dynamics and spatial heterogeneities of PLGA degradation and erosion within a spherical particle. The analytical solution is applicable to other spherical systems with simultaneous diffusive transport and first-order generation by reaction.
International Nuclear Information System (INIS)
We report a versatile optical sensor by incorporating the indicator dye 4-phenyl-2,6-bis(2,3,5,6-tetrahydrobenzo[b][1,4,7]trioxononin-9-yl)pyrylium perchlorate into a sol-gel layer. The proposed optical sensor that is stable, fast and highly selective to Hg2+ ions shows a significant absorbance signal change on exposure to an aqueous solution containing mercury(II) ion. The sensing film is able to determine mercury(II) ion in aqueous solution with a high selectivity over a wide dynamic range between 1.52 x 10-9 and 1.70 x 10-2 M, at pH 5, and a lower detection limit of 1.11 x 10-9 M. Validation of the assay method revealed excellent performance characteristics for Hg2+ ions over a wide variety of other metal ions, including good selectivity, long-term response stability and high reproducibility. Applications, for the direct determination of mercury(II) in real samples, gave the results with good correlation with the data obtained by using cold vapor atomic absorption spectrometry.
Prenesti, Enrico; Berto, Silvia; Daniele, Pier Giuseppe
2003-01-01
In this study we considered π-methyl- L-histidine (π-methis) and τ-methyl- L-histidine (τ-methis) as ligands for copper(II) ion, in order to clarify, by means of ultraviolet (UV) spectroscopy in aqueous solution ( T=25 °C, I=0.1 M), some aspects of the co-ordination mode with respect to other ligands of a previous study in which copper(II) complexes of L-histidine, N-acetyl- L-histidine, histamine, L-histidine methyl ester or carnosine were investigated. Particularly, UV spectra (300-400 nm) were recorded on solutions at various pH values, containing each binary system Cu-L; afterwards, an UV absorption spectrum for single complexes was calculated, taking into account the chemical model previously assessed, in order to fulfil a correct spectrum-structure correlation. The problem related to the eventual superimposition of the CT shoulder (≈330 nm) to copper(II) of OH - and imidazole pyridine nitrogen groups were now solved by means of a comparison of the UV spectra of dimer species formed by both π-methis or τ-methis. Finally, copper(II) complex formation with 2,2'-bipyridine was taken into account to compare the behaviour of pyridine (from 2,2'-bipyridine) and pyridine imidazole nitrogens (from π-methis or τ-methis) with respect to the UV charge transfer process to copper(II) ion.
Diaferia, Carlo; Mercurio, Flavia Anna; Giannini, Cinzia; Sibillano, Teresa; Morelli, Giancarlo; Leone, Marilisa; Accardo, Antonella
2016-01-01
Water soluble fibers of PEGylated tetra-phenylalanine (F4), chemically modified at the N-terminus with the DOTA chelating agent, have been proposed as innovative contrast agent (CA) in Magnetic Resonance Imaging (MRI) upon complexation of the gadolinium ion. An in-depth structural characterization of PEGylated F4-fibers, in presence (DOTA-L6-F4) and in absence of DOTA (L6-F4), is reported in solution and at the solid state, by a multiplicity of techniques including CD, FTIR, NMR, DLS, WAXS and SAXS. This study aims to better understand how the aggregation process influences the performance of nanostructures as MRI CAs. Critical aggregation concentrations for L6-F4 (43 μM) and DOTA-L6-F4 (75 μM) indicate that self-aggregation process occurs in the same concentration range, independently of the presence of the CA. The driving force for the aggregation is the π-stacking between the side chains of the aromatic framework. CD, FTIR and WAXS measurements indicate an antiparallel β-sheet organization of the monomers in the resulting fibers. Moreover, WAXS and FTIR experiments point out that in solution the nanomaterials retain the same morphology and monomer organizations of the solid state, although the addition of the DOTA chelating agent affects the size and the degree of order of the fibers. PMID:27220817
Energy Technology Data Exchange (ETDEWEB)
Yari, Abdollah, E-mail: a.yari@ymail.com [Department of Chemistry, Lorestan University, Falakalaflak Street, 68178-17133 Khorramabad (Iran, Islamic Republic of); Abdoli, Hamzeh Adelpour [Department of Chemistry, Lorestan University, Falakalaflak Street, 68178-17133 Khorramabad (Iran, Islamic Republic of)
2010-06-15
We report a versatile optical sensor by incorporating the indicator dye 4-phenyl-2,6-bis(2,3,5,6-tetrahydrobenzo[b][1,4,7]trioxononin-9-yl)pyrylium perchlorate into a sol-gel layer. The proposed optical sensor that is stable, fast and highly selective to Hg{sup 2+} ions shows a significant absorbance signal change on exposure to an aqueous solution containing mercury(II) ion. The sensing film is able to determine mercury(II) ion in aqueous solution with a high selectivity over a wide dynamic range between 1.52 x 10{sup -9} and 1.70 x 10{sup -2} M, at pH 5, and a lower detection limit of 1.11 x 10{sup -9} M. Validation of the assay method revealed excellent performance characteristics for Hg{sup 2+} ions over a wide variety of other metal ions, including good selectivity, long-term response stability and high reproducibility. Applications, for the direct determination of mercury(II) in real samples, gave the results with good correlation with the data obtained by using cold vapor atomic absorption spectrometry.
El-Faham, Ayman; Osman, Sameh M; Al-Lohedan, Hamad A; El-Mahdy, Gamal A
2016-06-01
The corrosion inhibition performance of 2-hydrazino-4,6-dimethoxy-1,3,5-tirazine (DMeHT), 2,4-dihydrazino-6-methoxy-1,3,5-triaizine (DHMeT), and 2,4,6-tridydrazino-1,3,5-triaizne (TH₃) on steel corrosion in acidic media was examined using electrochemical techniques. The results showed 2,4-Ddihydrazino-6-methoxy-1,3,5-triaizine (DHMeT) gave the best corrosion protection performance among the other hydrazino derivatives even at a low concentration of 25 ppm (95%). The number of hydrazino groups play an important role in the corrosion inhibition, where the two hydrazine groups increased the electrostatic interactions between the protonated tested compounds, the negatively charged steel surface resulted from the adsorption of the chloride anions, and the presence of the methoxy group made the compound more reliable for formation of film protection on the surface of steel through the lone pair of oxygen atoms. Electrochemical Impedance Spectroscopy (EIS) measurements suggested that the corrosion process of steel in presence of the hydrazino-s-triazine derivatives (TH₃, DMeHT and DHMeT) were being controlled by the charge transfer reaction. Polarization curves indicated that the examined TH₃, DMeHT and DHMeT behaved as mixed type inhibitors.
El-Faham, Ayman; Osman, Sameh M; Al-Lohedan, Hamad A; El-Mahdy, Gamal A
2016-01-01
The corrosion inhibition performance of 2-hydrazino-4,6-dimethoxy-1,3,5-tirazine (DMeHT), 2,4-dihydrazino-6-methoxy-1,3,5-triaizine (DHMeT), and 2,4,6-tridydrazino-1,3,5-triaizne (TH₃) on steel corrosion in acidic media was examined using electrochemical techniques. The results showed 2,4-Ddihydrazino-6-methoxy-1,3,5-triaizine (DHMeT) gave the best corrosion protection performance among the other hydrazino derivatives even at a low concentration of 25 ppm (95%). The number of hydrazino groups play an important role in the corrosion inhibition, where the two hydrazine groups increased the electrostatic interactions between the protonated tested compounds, the negatively charged steel surface resulted from the adsorption of the chloride anions, and the presence of the methoxy group made the compound more reliable for formation of film protection on the surface of steel through the lone pair of oxygen atoms. Electrochemical Impedance Spectroscopy (EIS) measurements suggested that the corrosion process of steel in presence of the hydrazino-s-triazine derivatives (TH₃, DMeHT and DHMeT) were being controlled by the charge transfer reaction. Polarization curves indicated that the examined TH₃, DMeHT and DHMeT behaved as mixed type inhibitors. PMID:27258241
Room temperature electrical properties of solution derived p-type Cu2ZnSnS4 thin films
Gupta, Goutam Kumar; Dixit, Ambesh
2016-05-01
Electrical properties of solution processed Cu2ZnSnS4 (CZTS) compound semiconductor thin film structures on molybdenum (Mo) coated glass substrates are investigated using Mott-Schottky and Impedance spectroscopy measurements at room temperature. These measurements are carried out in sodium sulfate (Na2SO4) electrolytic medium at pH ~ 9.5. The inversion/depletion/accumulation regions are clearly observed in CZTS semiconductor -Na2SO4 electrolyte interface and measured flat band potential is ~ -0.27 V for CZTS thin film electrode. The positive slope of the depletion region confirms the intrinsic p-type characteristics of CZTS thinfilms with ~ 2.5× 1019 holes/m3. The high frequency impedance measurements showed ~ 30 Ohm electrolyte resistance for the investigated configuration.
Stolaroff, J. K.; Lowry, G. V.; Keith, D. W.
2003-12-01
To mitigate global climate change, deep reductions in CO2 emissions are required in the coming decades. Carbon sequestration will play a crucial role in this reduction. Early adoption of carbon sequestration in low-cost niche markets will help develop the technology and experience required for large-scale deployment. One such niche may be the use of alkali metals from industrial waste streams to form carbonate minerals, a safe and stable means of sequestering carbon. In this research, the potential of using two industrial waste streams---concrete and steel slag---for sequestering carbon is assessed. The scheme is outlined as follows: Ca and Mg are leached with water from a finely ground bed of steel slag or concrete. The resulting solution is sprayed through air, capturing CO2 and forming solid carbonates, and collected. The feasibility of this scheme is explored with a combination of experiments, theoretical calculations, cost accounting, and literature review. The dissolution kinetics of steel slag and concrete as a function of particle size and pH is examined. In stirred batch reactors, the majority of Ca which dissolved did so within the first hour, yielding between 50 and 250 (mg; Ca)/(g; slag) and between 10 and 30 (mg; Ca)/(g; concrete). The kinetics of dissolution are thus taken to be sufficiently fast to support the type of scheme described above. As proof-of-concept, further experiments were performed where water was dripped slowly through a stagnant column of slag or concrete and collected at the bottom. Leachate Ca concentrations in the range of 15 mM were achieved --- sufficient to support the scheme. Using basic physical principles and numerical methods, the quantity of CO2 captured by falling droplets is estimated. Proportion of water loss and required pumping energy is similarly estimated. The results indicate that sprays are capable of capturing CO2 from the air and that the water and energy requirements are tractable. An example system for
Shimada, Hirofumi; Nakamura, Akihito; Yoshihara, Toshitada; Tobita, Seiji
2005-04-01
Effects of intra- and intermolecular hydrogen-bonds on the photophysical properties of 2'-aminoacetophenone derivatives (X-C6H4-COCH3) having a substituted amino group (X) with different hydrogen-bonding ability to the carbonyl oxygen (X: NH2(AAP), NHCH3(MAAP), N(CH3)2(DMAAP), NHCOCH3(AAAP), NHCOCF3(TFAAP)) are investigated by means of steady-state and time-resolved fluorescence spectroscopy and time-resolved thermal lensing. Based on the photophysical parameters obtained in aprotic solvents with different polarity and protic solvents with different hydrogen-bonding ability, the characteristic photophysical behavior of the 2'-aminoacetophenone derivatives is discussed in terms of hydrogen-bonding and n,pi*-pi,pi* vibronic coupling. The dominant deactivation process of AAP and MAAP in nonpolar aprotic solvents is the extremely fast internal conversion (k(ic)= 1.0 x 10(11) s(-1) for AAP and 3.9 x 10(10) s(-1) for MAAP in n-hexane). The internal conversion rates of both compounds decrease markedly with increasing solvent polarity, suggesting that vibronic interactions between close-lying S1(pi,pi*) and S2(n,pi*) states lead to the large increase in the non-radiative decay rate of the lowest excited singlet state. It is also suggested that for MAAP, which has a stronger hydrogen-bond as compared to AAP, an intramolecular hydrogen-bonding induced deactivation is involved in the dissipation of the S1 state. For DMAAP, which cannot possess an intramolecular hydrogen-bond, the primary relaxation mechanism of the S1 state in nonpolar aprotic solvents is the intersystem crossing to the triplet state, whereas in protic solvents very efficient internal conversion due to intermolecular hydrogen-bonding is induced. In contrast, the fluorescence spectra of AAAP and TFAAP, which have an amino group with a much stronger hydrogen-bonding ability, give strongly Stokes-shifted fluorescence, indicating that these compounds undergo excited-state intramolecular proton transfer reaction
Characterization of rapid thermally processed LiMn2O4 thin films derived from solution deposition
Institute of Scientific and Technical Information of China (English)
MA Ming-you; XIAO Zhuo-bing; Li Xin-hai; WU Xian-ming; HE Ze-qiang; CHEN Shang
2006-01-01
Cathode material LiMn2O4 thin films were prepared through solution deposition followed by rapid thermal annealing. The phase identification and surface morphology were studied by X-ray diffraction and scanning electron microscopy. Electrical and electrochemical properties were examined by four-probe method, cyclic voltammetry and galvanostatic charge-discharge experiments. The results show that the film prepared by this method is homogeneous, dense and crack-free. As the annealing temperature and annealing time increase, the electronic resistivity decreases, while the capacity of the films increases generally. For the thin films annealed at different temperatures for 2 min, the thin film annealed at 800 ℃ has the best cycling behavior with the capacity loss of 0.021% per cycle. While for the thin films annealed at 750 ℃ for different times, the film annealed for 4 min possesses the best cycling performance with a capacity loss of 0.025% per cycle. For the lithium diffusion coefficient in LiMn2O4 thin film, its magnitude order is 10-11 cm2·s-1.
Energy Technology Data Exchange (ETDEWEB)
Gallego-Gomez, Francisco; Villalvilla, Jose M.; Quintana, Jose A.; Diaz-Garcia, Maria A. [Instituto Universitario de Materiales de Alicante and Dpto. Fisica Aplicada, Universidad de Alicante, 03080 Alicante (Spain); Garcia-Frutos, Eva M.; Gutierrez-Puebla, Enrique; Monge, Angeles; Gomez-Lor, Berta [Instituto de Ciencia de Materiales de Madrid, CSIC, C/Sor Juana Ines de la Cruz 3, 28049 Madrid (Spain)
2011-02-22
A new carbazole-related small molecule exhibiting self-assembly into ordered nanostructures in solution-processed cast films has been synthesized and its charge-photogeneration and -transport properties have been investigated. Large photoconductivity was measured in the amorphous state while an enormous improvement in the photoconduction properties was observed when the molecules spontaneously organized. Photocurrents increased upon self-assembly by up to four orders of magnitude, mostly due to the drastic enhancement of the charge photogeneration. A greatly favorable arrangement of the aromatic cores in the resulting nanostructures, which were characterized by X-ray analysis, may explain these improvements. Photocurrents of mA cm{sup -2}, on/off ratios of 10{sup 4} and quantum efficiencies of unity at low field and light intensity, which are among the best values reported to date, along with the simplicity of fabrication, give this readily-available organic system great potential for use in plastic optoelectronic devices. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)
Hadjittofi, Loukia; Prodromou, Melpomeni; Pashalidis, Ioannis
2014-05-01
The adsorption efficiency of activated biochar prepared from cactus fibres regarding the removal of Cu(II) from aqueous solutions has been investigated as a function of various physicochemical parameters (e.g. pH, initial metal concentration, ionic strength, temperature and contact time). Activation of the biochar took place using nitric acid oxidation and characterisation was performed by SEM analysis, FTIR spectroscopy, N2 adsorption and acid-base titrations. The results show that laminar structures constitute the material and carboxylic moieties are the predominant binding sites. The experimental data were analyzed by the Langmuir, Freundlich and Dubinin-Radushkevich adsorption models and the monolayer adsorption capacity was found to be 3.5 mol kg(-1). The effect of ionic strength and temperature on the adsorption efficiency indicates that at low pH outer-sphere and at near neutral pH inner-sphere complexes are the predominant surface species and the kinetic data obtained were fitted very well by the Lagergren rate expression. PMID:24718356
Denoël, Thibaut; Zervosen, Astrid; Gerards, Thomas; Lemaire, Christian; Joris, Bernard; Blanot, Didier; Luxen, André
2014-09-01
The three diastereoisomers-(R,R), (S,S) and meso-of lanthionine were synthesized in aqueous solution with high diastereoselectivity (>99%). The (S) and (R) enantiomers of two differently protected sulfamidates were opened by nucleophilic attack of (R) or (S)-cysteine. Acidification and controlled heating liberated the free lanthionines. Using the same chemistry, an α-benzyl lanthionine was also prepared. The proposed method, which avoids the need of enrichment by recrystallization, opens the way to the labelling of these compounds with (35)S. Furthermore, in vivo bioincorporation into Escherichia coli W7 was studied. No incorporation of α-benzyl lanthionine was observed. In contrast, meso-lanthionine can effectively replace meso-diaminopimelic acid in vivo, while in the presence of (R,R)-lanthionine the initial increase of bacterial growth was followed by cell lysis. In the future, meso-[(35)S]lanthionine could be used to study the biosynthesis of peptidoglycan and its turnover in relation to cell growth and division.
Abdel-Aziz, Heba; Wadie, Walaa; Scherner, Olaf; Efferth, Thomas; Khayyal, Mohamed T
2015-06-26
Earlier studies showed that the compatible solute ectoine (1) given prophylactically before induction of colitis by 2,4,6-trinitrobenzenesulfonic acid (TNBS) in rats prevented histological changes induced in the colon and the associated rise in inflammatory mediators. This study was therefore conducted to investigate whether ectoine (1) and its 5α-hydroxy derivative (2) would also be effective in treating an already established condition. Two days after inducing colitis in rats by instilling TNBS/alcohol in the colon, animals were treated orally once daily for 1 week with either 1 or 2 (50, 100, 300 mg/kg). Twenty-four hours after the last drug administration rats were sacrificed. Ulcerative lesions and colon mass indices were reduced by 1 and 2 in a bell-shaped manner. Best results were obtained with 100 mg/kg ectoine (1) and 50 mg/kg 5α-hydroxyectoine (2). The solutes normalized the rise in myeloperoxidase, TNFα, and IL-1β induced by TNBS but did not affect levels of reduced glutathione or ICAM-1, while reducing the level of fecal calprotectin, an established marker for inflammatory bowel disease. The findings indicate that the naturally occurring compatible solutes ectoine (1) and 5α-hydroxyectoine (2) possess an optimum concentration that affords maximal intestinal barrier stabilization and could therefore prove useful for better management of human inflammatory bowel disease.
Chao, B. F.
2016-09-01
The equivalent water thickness (EWT, including mascon) solutions derived from the GRACE time-variable gravity (TVG) data are gaining recognition. We examine the physics of this practice from first principle in light of the non-uniqueness of 3-D gravitational inversion. We raise caveats on the indiscriminate utilization of the EWT solutions, because a surface EWT solution cannot represent an internal process in a physically meaningful way. In practice, EWT is often a good-enough representation of the reality as the predominant TVG signals do originate from surficial processes such as the water cycle, but it should be recognized that all internal geophysical processes leave signatures to different extent in the TVG observations. Treating all TVG as EWT will render physical quantities in general not directly resolvable by gravity to be misinterpreted. As the TVG observations span longer and improve in precision, the gravity itself, rather than EWT, should still be the quantity of choice. This is not just a problem of model uncertainties or numerical errors, but one in the understanding and treatment in the interest of the rigor of physics.
Energy Technology Data Exchange (ETDEWEB)
Khaled, K.F. [Electrochemistry Research Laboratory, Chemistry Department, Faculty of Education, Ain Shams University, Roxy, Cairo (Egypt); Materials and Corrosion Laboratory, Chemistry Department, Faculty of Science, Taif University, Taif, 888 Hawiya (Saudi Arabia)], E-mail: khaledrice2003@yahoo.com; Al-Qahtani, M.M. [Materials and Corrosion Laboratory, Chemistry Department, Faculty of Science, Taif University, Taif, 888 Hawiya (Saudi Arabia)
2009-01-15
Corrosion inhibition of aluminum in 1.0 M HCl was investigated in the absence and presence of different concentrations of tetrazole derivatives namely, 1-phenyl-1H-tetrazole-5-thiol (A), 1-phenyl-1H-tetrazole (B), 1H-tetrazol-5-amine (C), 1H-tetrazole (D). Weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) measurements were employed. Impedance measurements showed that the charge transfer resistance increased and double layer capacitance decreased with increase in the inhibitor's concentration. Potentiodynamic polarization study showed that the inhibitors acted as cathodic-type inhibitors. Also, results obtained reveal that compound A is the best inhibitor and the inhibition efficiency (IE%) follows the sequence: A > B > C > D. Obvious correlations were found between corrosion inhibition efficiency and some quantum chemical parameters such as energy of highest occupied molecular orbital (HOMO), energy of lowest unoccupied molecular orbital (LUMO), HOMO-LUMO energy gap and electronic density etc. Calculated results indicated that the difference in inhibition efficiencies between these compounds can be clearly explained in terms of frontier molecular orbital theory. The inhibitor performance depends mainly on the type of function groups substituted on tetrazole ring. The adsorption of these compounds on the aluminum surface obeys a Langmuir adsorption isotherm and has a mixed physisorption and chemisorption mechanism.
Energy Technology Data Exchange (ETDEWEB)
Herrag, L.; Hammouti, B.; Elkadiri, S.; Aouniti, A. [Laboratoire de Chimie Appliquee et Environnement, LCAE-URAC18, Faculte des Sciences, Universite Mohammed Premier, B.P. 717, M-6000 Oujda (Morocco); Jama, C. [Unite Materiaux et Transformations (UMET), Ingenierie des Systemes Polymeres, CNRS UMR 8207, ENSCL, B.P. 90108, F-59652 Villeneuve d' Ascq Cedex (France); Vezin, H. [Laboratoire de Spectrochimie Infrarouge et Raman (LASIR), UMR-CNRS 8516, Universite des Sciences et Technologies de Lille, Batiment C5, F-59655 Villeneuve d' Ascq Cedex (France); Bentiss, F., E-mail: fbentiss@enscl.f [Laboratoire de Chimie de Coordination et d' Analytique (LCCA), Faculte des Sciences, Universite Chouaib Doukkali, B.P. 20, M-24000 El Jadida (Morocco)
2010-09-15
New diamine derivatives, namely 2-[{l_brace}2-[bis-(2-hydroxyethyl)amino]ethyl{r_brace}(2-hydroxyethyl)amino]ethanol (DAME) and 2-[{l_brace}2-[bis-(2-hydroxyethyl)amino]ethyl{r_brace}(2-hydroxyethyl)amino]propanol (DAMP) were synthesised and their inhibitive action against the corrosion of mild steel in 1 M HCl solution were investigated at 308 K. The detailed study of DAME is given using gravimetric measurements and polarization curves method. Results show that DAME is a good inhibitor and inhibition efficiency reaches 91.7% at 10{sup -3} M. Tafel polarization study revealed that DAME acts as a mixed-type inhibitor. The inhibitor adsorption process in mild steel/DAME/hydrochloric acid system was studied at different temperatures (308-353 K) by means of weight loss measurements. The adsorption of DAME on steel surface obeyed Langmuir's adsorption isotherm. The kinetic and thermodynamic parameters for mild steel corrosion and inhibitor adsorption, respectively, were determined and discussed. The comparative study of inhibitive performance of the two diamine derivatives revealed that DAME is more effective than DAMP. Quantitative Structure-Activity Relationship (QSAR) approach has been conducted in attempt to correlate the corrosion inhibition properties of these diamine derivatives with their calculated quantum chemical parameters.
Energy Technology Data Exchange (ETDEWEB)
Feng, Lijuan [Institute of Chemistry, Northeast Normal University, Changchun 130024 (China); Center of Analytical and Testing, Beihua University, Jilin 132013, P.R China (China); Tong, Cuiyan, E-mail: tongcy959@nenu.edu.cn [Institute of Chemistry, Northeast Normal University, Changchun 130024 (China); He, Yao; Liu, Bingxin; Wang, Chunyu; Sha, Jie [Institute of Chemistry, Northeast Normal University, Changchun 130024 (China); Lü, Changli, E-mail: lucl055@nenu.edu.cn [Institute of Chemistry, Northeast Normal University, Changchun 130024 (China)
2014-02-15
A new fluorescent sensor based on single water-soluble β-cyclodextrin (β-CD) molecule as the support carrier of donor and acceptor complex was designed, and used for TNT detection by fluorescence resonance energy transfer (FRET). In this sensing platform, per-6-amino-β-CD (per-6-NH{sub 2}-β-CD) was used as the detection vehicle. The probe dye of fluorescein 5(6)-isothiocyanate (FITC) was covalently linked onto the per-6-NH{sub 2}-β-CD rim with the grafting molar ratio of 1:1, the residual amino groups of per-6-NH{sub 2}-β-CD can adsorb TNT molecules by forming Meisenheimer complex (TNT–amine complex) with TNT. The absorbtion spectrum of this complex has a spectral overlapping with the emission of FITC in aqueous solution, so it can strongly suppress the fluorescence emission of the adjacent FITC through FRET on β-CD vehicle. This FRET-based fluorescent sensing technique provides a facile, ultrasensitive and selective detection method for TNT molecule. The observed linear fluorescence intensity change could allow the quantitative detection TNT with the detection limit of 20 nM in water. -- Highlights: • Per-6-NH{sub 2}-β-CD was functionalized with fluorescein 5(6)-isothiocyanate. • The PL quenching of FITC-(NH{sub 2})-CD is sensitive to the content of TNT due to FRET. • The PL sensor allows a quantitative detection TNT with a detection limit of 20 nM. • Our strategy opens up a new perspective in the design of sensor for various analytes.
Puentes, Roberto; Torres, Julia; Kremer, Carlos; Cano, Joan; Lloret, Francesc; Capucci, Davide; Bacchi, Alessia
2016-03-28
Two novel families of coordination polymers, [Ln(bzlida)(Hbzlida)]·H2O (Ln = La, Nd) and [Ln2(bzlida)3]·3H2O (Ln = Nd, Sm, Eu, Gd) were prepared by hydrothermal reaction of Ln2O3 with benzyliminodiacetic acid (H2bzlida). The conditions of synthesis, in particular the pH value, were selected on the basis of previous speciation studies reported in this work. The first type of complex consists of 1D chains built by a fully deprotonated ligand bridging two lanthanide ions and protonated Hbzlida(-) ligands connecting three cations. The second type is formed by [Ln2(bzlida)3] bimetallic units in which the ligand has a tridentate NOO coordination mode. This is expanded to a 2D network through carboxylate linkers. Under similar synthetic conditions but including copper acetate in the reaction mixture, a new compound was also obtained and characterized: [Cu(bzlida)2{Er(AcO)(H2O)5}2][Cu(bzlida)2]·6H2O (AcO = acetate). This salt is made up of the [Cu(bzlida)2{Er(AcO)(H2O)5}2](2+) heterotrimetallic complex cation containing an acetato bridge, and the [Cu(bzlida)2](2-) anion. The same reaction produces the monomeric [Cu(Hbzlida)2]·4H2O whose structure was also elucidated. Magnetic properties of the Gd(iii) derivative were studied and analyzed experimentally and theoretically. The results are compared and discussed with respect to those reported in the literature and a magnetostructural correlation is suggested. PMID:26906084
Directory of Open Access Journals (Sweden)
Syed Hussinien H Shah
Full Text Available Exotic functions of antifreeze proteins (AFP and antifreeze glycopeptides (AFGP have recently been attracted with much interest to develop them as commercial products. AFPs and AFGPs inhibit ice crystal growth by lowering the water freezing point without changing the water melting point. Our group isolated the Antarctic yeast Glaciozyma antarctica that expresses antifreeze protein to assist it in its survival mechanism at sub-zero temperatures. The protein is unique and novel, indicated by its low sequence homology compared to those of other AFPs. We explore the structure-function relationship of G. antarctica AFP using various approaches ranging from protein structure prediction, peptide design and antifreeze activity assays, nuclear magnetic resonance (NMR studies and molecular dynamics simulation. The predicted secondary structure of G. antarctica AFP shows several α-helices, assumed to be responsible for its antifreeze activity. We designed several peptide fragments derived from the amino acid sequences of α-helical regions of the parent AFP and they also showed substantial antifreeze activities, below that of the original AFP. The relationship between peptide structure and activity was explored by NMR spectroscopy and molecular dynamics simulation. NMR results show that the antifreeze activity of the peptides correlates with their helicity and geometrical straightforwardness. Furthermore, molecular dynamics simulation also suggests that the activity of the designed peptides can be explained in terms of the structural rigidity/flexibility, i.e., the most active peptide demonstrates higher structural stability, lower flexibility than that of the other peptides with lower activities, and of lower rigidity. This report represents the first detailed report of downsizing a yeast AFP into its peptide fragments with measurable antifreeze activities.
Puentes, Roberto; Torres, Julia; Kremer, Carlos; Cano, Joan; Lloret, Francesc; Capucci, Davide; Bacchi, Alessia
2016-03-28
Two novel families of coordination polymers, [Ln(bzlida)(Hbzlida)]·H2O (Ln = La, Nd) and [Ln2(bzlida)3]·3H2O (Ln = Nd, Sm, Eu, Gd) were prepared by hydrothermal reaction of Ln2O3 with benzyliminodiacetic acid (H2bzlida). The conditions of synthesis, in particular the pH value, were selected on the basis of previous speciation studies reported in this work. The first type of complex consists of 1D chains built by a fully deprotonated ligand bridging two lanthanide ions and protonated Hbzlida(-) ligands connecting three cations. The second type is formed by [Ln2(bzlida)3] bimetallic units in which the ligand has a tridentate NOO coordination mode. This is expanded to a 2D network through carboxylate linkers. Under similar synthetic conditions but including copper acetate in the reaction mixture, a new compound was also obtained and characterized: [Cu(bzlida)2{Er(AcO)(H2O)5}2][Cu(bzlida)2]·6H2O (AcO = acetate). This salt is made up of the [Cu(bzlida)2{Er(AcO)(H2O)5}2](2+) heterotrimetallic complex cation containing an acetato bridge, and the [Cu(bzlida)2](2-) anion. The same reaction produces the monomeric [Cu(Hbzlida)2]·4H2O whose structure was also elucidated. Magnetic properties of the Gd(iii) derivative were studied and analyzed experimentally and theoretically. The results are compared and discussed with respect to those reported in the literature and a magnetostructural correlation is suggested.
Energy Technology Data Exchange (ETDEWEB)
Lopez G, O. G.
2010-07-01
This work presents a study about the synthesis by plasma, the electric properties and superficial interaction of polymers derived from pyrrole doped with Iodine with potential use as bio material. Poly-pyrrole is a semiconductor and biocompatible polymer with potential application in the development of artificial muscles and implants where the electric interaction between cells and material is an important variable. The syntheses were made at 13.5 MHz in a glass tubular reactor of 1500 cm{sup 3} with electrodes of 6.5 cm diameter and stainless steel flanges. An electrode was connected to the RF terminal of the power supply that is combined with a matching coupling resistance. The monomer and dopant used in this work were pyrrole and Iodine respectively, in closed containers. They were vaporized and injected separately into the reactor at room temperature and 0.1 mbar. The vapors of the reagents mixed freely in the reactor. The synthesis time was 240 min at 40, 60, 80 and 100 W. The polymers were obtained as thin films adhered to the reactor walls. The films were washed and swollen with distilled water and removed from the reactor walls with a small spatula. The polymers were irradiated with gamma rays at 18 and 22 KGy. Due to the fact that the doses are cumulative, the final dose applied was 40 KGy. The polymers characterization was carried out by Fourier Transform Infrared Spectroscopy, thermogravimetric analysis (TGA), scanning electron microscopy, contact angle, electrical conductivity and X-ray diffraction. The analyses indicates that the polymers have very similar structure in almost the entire power range, showing C-O, C=C, C-H, O-H, N-H bonds with a predominantly amorphous structure. The TGA analyses showed that the material has 4 or 5 loses of material. The first one starts after that 115 C except for the material irradiated at 40 KGy, this one begins in 87 C, the second one is in the interval of 196 and 295 C, the third one between 311 and 500 C, and the
Indian Academy of Sciences (India)
Kyu-Seog Hwang; Bo-An Kang; Sung-Dai Kim; Seung Hwangbo; Jim-Tae Kim
2011-08-01
3 Mol% of europium doped strontium aluminate (SrAl2O4:Eu2+) coatings on silicon substrates were prepared by electrostatic spray deposition method using a salted sol–gel derived solution as a starting material. Asdeposited films at 100°C for 5 h were heated at 1100°C for 2 h under a reducing ambient atmosphere of 95%N2 + 5%H2 . Nanocrystalline SrAl2O4 film was confirmed by surface morphological and crystallographic analyses. Monitored at 520 nm, the excitation spectrum showed a broad band from 300 ∼ 500 nm and the emission intensity showed a maximum yellow peak intensity at 512 nm with a broad band from 460 ∼ 610 nm.
Directory of Open Access Journals (Sweden)
N. B. Raut
2014-01-01
Full Text Available Soft computing techniques are very much needed to design the environmental related systems these days. Soft computing (SC is a set of computational methods that attempt to determine satisfactory approximate solutions to find a model for real-world problems. Techniques such as artificial neural networks, fuzzy logic, and genetic algorithms can be used in solving complex environmental problems. Self-organizing feature map (SOFM model is proposed in monitoring and collecting of the data that are real time and static datasets acquired through pollution monitoring sensors and stations in the distilleries. In the environmental monitoring systems the ultimate requirement is to establish controls for the sensor based data acquisition systems and needs interactive and dynamic reporting services. SOFM techniques are used for data analysis and processing. The processed data is used for control system which even feeds to the treatment systems. Cocos nucifera activated carbon commonly known as coconut shell activated carbon (CSC was utilized for the treatment of distillery spent wash. Batch and column studies were done to investigate the kinetics and effect of operating parameter on the rate of adsorption. Since the quantum of spent water generated from the sugar industry allied distillery units is huge, this low cost adsorbent is found to be an attractive economic option. Equilibrium adsorption date was generated to plot Langmuir and Tempkin adsorption isotherm. The investigation reveals that though with lower adsorption capacities CSC seems to be technically feasible solution for treating sugar distillery spent. Efforts are made in this paper to build informatics for derived activated carbon for solving the problem of treatment of distillery spent wash. Capsule. Coconut shell derived activated carbon was synthesized, characterized, and successfully employed as a low cost adsorbent for treatment of distillery spent wash.
International Nuclear Information System (INIS)
In order to develop a new method for the preparation of the [99Tcm(CO)2(NO)-L] (L=DTPA, EDTA, EHIDA) complexes in aqueous solution, two different procedures were developed: one is formation of the metal-tricarbonyl-ligand complex and subsequent nitrosylation; another is nitrosylation of the metal-tricarbonyl precursor followed by reaction with the ligand. The optimal labeling conditions were studied. Results of TLC and HPLC indicate that the radiochemical yields derived from the two methods list above are all more than 90%. It's an easier new way to prepare [99Tcm(CO)2(NO)-L] complexes in aqueous solution with high efficiency. The newly developed [99Tcm(CO)2(NO)-L] complexes are stable at room temperature during 1 half-life of the isotope. At the same time, the lipophility and net charge of [99Tcm(CO)2(NO)-L] complexes are also changed comparing with that of corresponding [99Tcm(CO)3]+ core complexes. It opens a new field for designing radiopharmaceuticals. (authors)
International Nuclear Information System (INIS)
The complexation abilities of different thiacalix[4]arene derivatives towards some rare earth metal ions, metallic pollutants, and noble metals have been investigated in liquid-liquid experiments. Thiacalix[4]arene dissolved in chloroform effectively extracts Pd(II) (in acidic chloride media) and also Ag(I), Cd(II), Sm(III) and Ce(III), all buffered at pH 6 or 8. The modification of this compound to form an amide derivative results in an effective extraction of noble metals, ranked according to Au(III) > Pd(II) > Pt(IV) > Ag(I). Moreover, a supported liquid membrane system for silver transport has been developed based on thiacalix[4]arene dissolved in NPOE, and parameters affecting its efficiency have been investigated, such as the stripping composition and the pH of the feed solution. Finally, the selectivity of the membrane system has been evaluated by using as feed sources mixtures of silver and other metal ions
Geiger, Yasmin; Gottlieb, Hugo E; Akbey, Ümit; Oschkinat, Hartmut; Goobes, Gil
2016-05-01
Smart materials are created in nature at interfaces between biomolecules and solid materials. The ability to probe the structure of functional peptides that engineer biogenic materials at this heterogeneous setting can be facilitated tremendously by use of DNP-enhanced solid-state NMR spectroscopy. This sensitive NMR technique allows simple and quick measurements, often without the need for isotope enrichment. Here, it is used to characterize a pentalysine peptide, derived from a diatom's silaffin protein. The peptide accelerates the formation of bioinspired silica and gets embedded inside the material as it is formed. Two-dimensional DNP MAS NMR of the silica-bound peptide and solution NMR of the free peptide are used to derive its secondary structure in the two states and to pinpoint some subtle conformational changes that the peptide undergoes in order to adapt to the silica environment. In addition, interactions between abundant lysine residues and silica surface are identified, and proximity of other side chains to silica and to neighboring peptide molecules is discussed. PMID:26451953
Energy Technology Data Exchange (ETDEWEB)
El-Attar, Mona A.; Ghoneim, Mohamed M. [Analytical Chemistry Research Unit, Chemistry Department, Tanta University (Egypt); Ismail, Iqbal M., E-mail: maema.2011@yahoo.com [Chemistry Department, Faculty of Science, King Abdul Aziz University, Jeddah (Saudi Arabia)
2012-08-15
Two azo-compounds, 2-methyl-4-(5-amino-2-hydroxy-phenylazo)-quinoline (2) and 2-methyl-4-(2-hydroxy-5-nitrophenylazo)-quinoline, derived from 4-amino-2-methylquinoline were synthesized. Their chemical structures were characterized and confirmed by means of elemental chemical analysis, infrared (IR) spectroscopy, {sup 1}H nuclear magnetic resonance (NMR) and mass spectrometry (MS). The electrochemical behavior of the starting compound (4-amino-2-methylquinoline) and of the two synthesized azo-derivatives was studied at the mercury electrode in the B-R universal buffer at various pH values (2-11.5) containing 40% (v/v) ethanol using dc-polarography, cyclic voltammetry and controlled-potential coulometry. Their electrode reaction pathways were elucidated and discussed. The dissociation constants (pKa) of the examined compounds, stability constants and stoichiometry of their complexes in solution with some transition metal ions (Co(II), Ni(II), Cu(II), La(III) and UO{sup 2+}{sub 2}) were determined. (author)
Yousfi, Ammar; Mechergui, Mohammed
2016-04-01
al. (2001). In this work, a novel solution based on theoretical approach will be adapted to incorporate both the seepage face and the unsaturated zone flow contribution for solving ditch drained aquifers problems. This problem will be tackled on the basis of the approximate 2D solution given by Castro-Orgaz et al. (2012). This given solution yields the generalized water table profile function with a suitable boundary condition to be determined and provides a modified DF theory which permits as an outcome the analytical determination of the seepage face. To assess the ability of the developed equation for water-table estimations, the obtained results were compared with numerical solutions to the 2-D problem under different conditions. It is shown that results are in fair agreement and thus the resulting model can be used for designing ditch drainage systems. With respect to drainage design, the spacings calculated with the newly derived equation are compared with those computed from the DF theory. It is shown that the effect of the unsaturated zone flow contribution is limited to sandy soils and The calculated maximum increase in drain spacing is about 30%. Keywords: subsurface ditch drainage; unsaturated zone; seepage face; water-table, ditch spacing equation
Rauf, Muhammad Khawar; Zaib, Sumera; Talib, Ammara; Ebihara, Masahiro; Badshah, Amin; Bolte, Michael; Iqbal, Jamshed
2016-09-15
A facile and robust microwave-assisted solution phase parallel synthesis protocol was exercised for the development of a 38-member library of N,N'-disubstituted thiourea analogues (1-38) by using an identical set of conditions. The reaction time for synthesis of N,N'-disubstituted thiourea analogues was drastically reduced from a reported duration of 8-12h for conventional methods to only 1.5-2.0min. All the derivatives (1-38) were characterized by physico-analytical techniques such as elemental analysis in combination with FT-IR, (1)H, (13)C NMR and by single crystal XRD analysis have also been performed. These compounds were screened for their in vitro urease inhibition activities. Majority of compounds exhibited potent urease inhibition activities, however, the most significant activity was found for 16, with an IC50 value of 1.23±0.1μM. Furthermore, the synthesized compounds were screened for their cytotoxic potential against lungs cancer cell lines. Cell culture studies demonstrated significant toxicity of the compounds on the cell lines, and the levels of toxicity were altered in the presence of various side groups. The molecular docking studies of the most potent inhibitors were performed to identify the probable binding modes in the active site of the urease enzymes. These compounds have a great potential and significance for further investigations. PMID:27480030
Directory of Open Access Journals (Sweden)
Zaira Zaman Chowdhury,
2012-05-01
Full Text Available The feasibility of granular activated carbon (GAC derived from Mangostene (Mangostana garcinia fruit shell to remove lead, Pb2+ cations was investigated in batch and fixed bed sorption systems. Batch experiments were carried out to study equilibrium isotherms, kinetics, and thermodynamics by using an initial lead (Pb2+ ions concentration of 50 to 100 mg/L at pH 5.5. Equilibrium data were fitted using Langmuir, Freundlich, and Temkin linear equation models at temperatures 30°C, 50°C, and 70°C. Langmuir maximum monolayer sorption capacity was 25.00 mg/g at 30°C. The experimental data were best represented by pseudo-second-order and Elovich models. The sorption process was found to be feasible, endothermic, and spontaneous. In column experiments, the effects of initial cation concentration (50 mg/L, 70 mg/L, and 100 mg/L, bed height (4.5 cm and 3 cm, and flow rate (1 mL/min and 3 mL/min on the breakthrough characteristics were evaluated. Breakthrough curves were further analyzed by using Thomas and Yoon Nelson models to study column dynamics. The column was regenerated and reused consecutively for four cycles. The result demonstrated that the prepared activated carbon was suitable for removal of Pb2+ from synthetic aqueous solution using batch, as well as fixed bed sorption systems.
Energy Technology Data Exchange (ETDEWEB)
Obradors, X., E-mail: Xavier.obradors@icmab.es [Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC), Campus Universitat Autonoma de Barcelona, 08193 Bellaterra (Spain); Martinez-Julian, F.; Zalamova, K.; Vlad, V.R.; Pomar, A.; Palau, A.; Llordes, A.; Chen, H.; Coll, M.; Ricart, S.; Mestres, N.; Granados, X.; Puig, T. [Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC), Campus Universitat Autonoma de Barcelona, 08193 Bellaterra (Spain); Rikel, M. [Nexans Superconductors, 50354 Huerth (Germany)
2012-11-20
After briefly reviewing the present understanding of the nucleation process of YBCO films, a new approach is presented to enhance the stability of c-axis nucleation in epitaxial chemical solution deposited YBCO thin films derived from TFA precursors. We show that with silver addition to the TFA precursor c-axis nucleation can be reached in a wide range of temperature thus keeping high percolating J{sub c}. We argue that silver reduces supersaturation and makes more stable the c-axis nuclei without modifying T{sub c}. Additional advantages of silver addition are an enhanced surface smootheness and a reduced porosity of the YBCO films. The second reported topic relates to the discovery of an adverse relationship between percolating J{sub c} and YBCO films mesostrain, as determined through X-ray diffraction line broadening. We show that mesostrain is enhanced in processes leading to inefficient strain healing at grain boundaries, for instance annealing times too short or growth temperatures too low. It is suggested that the strained regions at the low angle grain boundaries lead to a weak link behavior which can be microscopically understood on the basis of pair formation prevention, as proposed by the bond contraction pairing model.
Kwon, Do-Kyun; Goh, Yumin; Son, Dongsu; Kim, Baek-Hyun; Bae, Hyunjeong; Perini, Steve; Lanagan, Michael
2016-01-01
A sol-gel-derived powder synthesis method has been used to prepare BaTiO3-NaNbO3 (BT-NN) solid-solution ceramic samples with various compositions. Fine and homogeneous complex perovskite ceramics were obtained at lower processing temperatures than used in conventional solid-state processing. The ferroelectric and relaxor ferroelectric properties of the sol-gel-synthesized (1 - x)BaTiO3- xNaNbO3 [(1 - x)BT- xNN] ceramics in the wide composition range of 0 Curie temperature, Burns temperature, freezing temperature, γ, diffuseness parameter ( δ), and activation energy were determined from the temperature and frequency dependency of the real part of the dielectric permittivity for various BT-NN compositions using the Curie-Weiss law and Vögel-Fulcher relationship. The systematic changes of these parameters with respect to composition indicate that a continuous crossover between BT-based relaxor and NN-based relaxor occurs at a composition near x = 0.4.
Directory of Open Access Journals (Sweden)
Claus Larsen
2007-10-01
Full Text Available With the overall objective of assessing the potential of utilizing plasma protein binding interactions in combination with the prodrug approach for improving the pharmacokinetics of drug substances, a series of model carbonate ester prodrugs of phenol, encompassing derivatives with fatty acid-like structures, were characterized in vitro. Stability of the derivatives was studied in aqueous solution, human serum albumin solution, human plasma, and rat liver homogenate at 37Ã‚Â°C. Stability of the derivatives in aqueous solution varied widely, with half-lives ranging from 31 to 1.7 ÃƒÂ— 104 min at pH 7.4 and 37Ã‚Â°C. The carbonate esters were subject to catalysis by plasma esterases except for the t-butyl and acetic acid derivatives, which were stabilized in both human plasma and human serum albumin solutions relative to buffer. In most cases, however, hydrolysis was accelerated in the presence of human serum albumin indicating that the derivatives interacted with the protein, a finding which was confirmed using the p-nitrophenyl acetate kinetic assay. Different human serum albumin binding properties of the phenol model prodrugs with fatty acid-like structure and neutral carbonate esters were observed. In the context of utilizing plasma protein binding in combination with the prodrug approach for optimizing drug pharmacokinetics, the esterase-like properties of human serum albumin towards the carbonate esters potentially allowing the protein to act as a catalyst of parent compound regenerations is interesting.
Brizuela, Alicia B.; Raschi, Ana B.; Castillo, María V.; Davies, Lilian; Romano, Elida; Brandán, Silvia A.
2014-09-01
In this study, aqueous solutions at different molar concentrations of sodium cyclamate in water were completely characterized by HATR (Horizontal Attenuated Total Reflectance) and Raman spectroscopies. The theoretical structures of cyclamate ion, the zwitterionic and neutral forms of the cyclamic acid and its dimer were optimized in gas and aqueous solution phases by using the hybrid B3LYP/6-31G* method. The solvent effects for the four species in aqueous solutions were simulated by using self-consistent reaction field (SCRF) calculations employing the integral equation formalism variant (IEFPCM) model. The complete assignments of the vibrational spectra of all the forms of cyclamic acid were performed taking into account the factor group analysis with the Scaled Quantum Mechanics Force Field (SQMFF) methodology. The existence of the zwitterionic and neutral forms of the cyclamic acid and its dimer in a solution of cyclamate in water is evidenced by characteristic bands in the HATR and Raman spectra. The dimerization of cyclamate in aqueous solution was previously reported by conductimetric method. The natural population analysis (NPA) and Merz-Kollman (MK) charges, molecular electrostatic potential (MEP), natural bond orbital (NBO) and atoms in molecules (AIM) calculations predict for all the species the principal donor and acceptor sites for the H bonds formation in aqueous solution. The SQM force fields for the cyclamate ion, the zwitterionic and neutral species of the cyclamic acid were obtained and their corresponding force constants in both phases were reported. Additionally, the solvation energies for those species were reported.
Christov, Ivan C
2012-01-01
In classical continuum physics, a wave is a mechanical disturbance. Whether the disturbance is stationary or traveling and whether it is caused by the motion of atoms and molecules or the vibration of a lattice structure, a wave can be understood as a specific type of solution of an appropriate mathematical equation modeling the underlying physics. Typical models consist of partial differential equations that exhibit certain general properties, e.g., hyperbolicity. This, in turn, leads to the possibility of wave solutions. Various analytical techniques (integral transforms, complex variables, reduction to ordinary differential equations, etc.) are available to find wave solutions of linear partial differential equations. Furthermore, linear hyperbolic equations with higher-order derivatives provide the mathematical underpinning of the phenomenon of dispersion, i.e., the dependence of a wave's phase speed on its wavenumber. For systems of nonlinear first-order hyperbolic equations, there also exists a general ...
Qiang, Yujie; Zhang, Shengtao; Xu, Shenying; Li, Wenpo
2016-06-15
Corrosion experiments and theoretical calculations were performed to investigate the inhibition mechanism of indazole (IA) and 5-aminoindazole (AIA) for copper in NaCl solution. The results obtained from weight loss and electrochemical experiments are in good agreement, and reveal that these compounds are high-efficiency inhibitors with inhibition efficiency order: AIA>IA, which was further confirmed by field emission scanning electronic microscope (FESEM) observation. Besides, the quantum chemical calculations and molecular dynamics (MD) simulation showed that both studied inhibitors are adsorbed strongly on the copper surface in parallel mode. The adsorption of these molecules on copper substrate was found to obey Langmuir isotherm.
Institute of Scientific and Technical Information of China (English)
LI Song-mei; ZHANG Hong-rui; LIU Jian-hua
2007-01-01
The corrosion behavior of aluminum alloy 2024-T3 was studied in 3.5% NaCl solution with two fluorescence quinoline compounds named 8-hydroxy-quinoline(8HQ) and 8-hydroxy-quinoline-5-sulfonic acid(HQS). The open circuit potential(OCP) test result indicates that both compounds change the alloy corrosion potential by adsorbing on the electrode surface. Polarization measurements show that 8HQ is a mixed type inhibitor by blocking the active sites of the metal surface, while HQS is a corrosion accelerator by activating the cathodic reaction. Changes of the impedance parameters in the electrochemical impedance spectroscopy(EIS) are related to the adsorption of 8HQ on the metal surface, which leads to the formation of a protective layer. The impedance diagram in the solution with HQS is similar to the one without additional organic compounds. The morphology and composition of the protective layer were studied by using SEM/EDS. The result confirms the function of the additions that the effect of 8HQ is due to the insoluble aluminum chelate, Al(HQ)3, to prevent adsorption of chloride ion, while the effect of HQS is to break down the oxide film.
Müller-Maatsch, Judith; Bechtold, Lena; Schweiggert, Ralf M; Carle, Reinhold
2016-12-15
Pelargonidin-based colors suffer from notorious instability. A phenolic mango peel extract and defined phenolic fractions thereof were shown to effectively modulate the visible absorption of anthocyanins from strawberry (Fragaria x ananassa Duch.) and red radish (Raphanus sativus L.) by intermolecular co-pigmentation. Consistently, non-acylated pelargonidin derivatives from strawberry exerted significantly greater hyper- and bathochromic spectral shifts than their acylated counterparts from red radish. The addition of low molecular-weight co-pigments such as gallic acid and monogalloyl glucoses to strawberry anthocyanins led to strong hyperchromic shifts from 30% to 48%, while gallotannins (>six galloyl units) exerted smaller co-pigmentation effects (36±2%; Δλmax 13nm), possibly due to steric hindrances. In contrast, penta- and hexa-O-galloyl-glucose induced greatest and most stable co-pigmentation effects (53±2%; Δλmax 13nm). Irrespective of the underlying mechanisms and the responsible compounds, phenolic mango peel extracts might represent suitable color enhancers for coloring foodstuff, particularly for those containing non-acylated pelargonidin derivatives. PMID:27451227
Reineker, P.; Kühne, R.
1980-03-01
Starting from the stochastic Liouville equation of the full Haken-Strobl model, describing the coupled coherent and incoherent motion of excitons in molecular crystals, the Nakajima-Zwanzig generalized master equation (GME) for the probability of finding an exciton at a specific lattice site is derived by an exact straightforward evaluation of its memory function. Various recently derived generalized master equations describing the excition motion are obtained as limiting cases and the Born approximation is discussed. It is shown that, even in the case of nearest-neighbor interaction in the stochastic Liouville equation, in the GME generalized time-dependent transition rates evolve between non-nearest neighbors and that their time behavior shows damped oscillations. Applying the Born approximation to the GME, the range of the generalized transition rates reduces to that of the interaction in the stochastic Liouville equation. Furthermore in this approximation the transition rates show a purely exponential decay with increasing time. Taking into account the interaction with an arbitrary number of neighbors, the mean square displacement of the exciton motion is calculated exactly from the GME. Finally the GME is solved exactly in the general case and several limiting expressions are discussed.
Rowe, Arthur J.; Jones, S. W.; Thomas, D.; Harding, Stephen E.
1989-11-01
The equilibrium distribution of particles dispersed in an aqueous solute situated in a centrifugal accelerative field is routinely studied by means of an optical trace recorded photographically. Rayleigh interferometric fringe patterns have been widely used to give this trace, in which the displacement of the parallel fringes is directly related to particle concentration differences. We have developed a simple but highly efficient frameshift algorithm for automatic interpretation of these patternsl . Results obtained from extensive use and further definition of this algorithm confirm its validity and utility. We have also studied algorithms for the interpretation of Fresnel fringe patterns yielded by an alternative optical system. These more complex patterns involving non parallel fringes can be analysed successfully, subject to certain conditions, with a precision similar to that obtained using Rayleigh interference optics.
Energy Technology Data Exchange (ETDEWEB)
Advanced Light Source; Liu, Yi; Klivansky, Liana; Cao, Dennis; Snauko, Marian; Teat, Simon J.; Struppe, Jochem O.; Koshkakaryan, Gayane
2009-01-22
Self assembling {pi}-conjugated molecules into ordered structures are of increasing interest in the field of organic electronics. One particular example is charge transfer complexes containing columnar alternative donor-acceptor (ADA) stacks, where neutral and ionic ground states can be readily tuned to modulate electrical, optical, and ferroelectrical properties. Aromatic-aromatic and charge transfer interactions have been the leading driving forces in assisting the self-assembly of ADA stacks. Various folding structures containing ADA stacks were assembled in solution with the aid of solvophobic or ion-binding interactions. Meanwhile, examples of solid ADA stacks, which are more appealing for practical use in devices, were obtained from cocrystalization of binary components or mesophase assembly of liquid crystals in bulk blends. Regardless of these examples, faster and more controllable approaches towards precise supramolecular order in the solid state are still highly desirable.
Zhang, Keke; Kong, Dali; Schubert, Gerald
2015-06-01
The standard thermal wind equation (TWE) relating the vertical shear of a flow to the horizontal density gradient in an atmosphere has been used to calculate the external gravitational signature produced by zonal winds in the interiors of giant gaseous planets. We show, however, that in this application the TWE needs to be generalized to account for an associated gravitational perturbation. We refer to the generalized equation as the thermal-gravitational wind equation (TGWE). The generalized equation represents a two-dimensional kernel integral equation with the Green’s function in its integrand and is hence much more difficult to solve than the standard TWE. We develop an extended spectral method for solving the TGWE in spherical geometry. We then apply the method to a generic gaseous Jupiter-like object with idealized zonal winds. We demonstrate that solutions of the TGWE are substantially different from those of the standard TWE. We conclude that the TGWE must be used to estimate the gravitational signature of zonal winds in giant gaseous planets.
Peverati, Roberto; Baldridge, Kim K
2009-10-13
The implementation, optimization, and performance of DFT-D, including the effects of solvation, has been tested on applications of polar processes in solution, where dispersion and hydrogen bonding is known to be involved. Solvent effects are included using our ab initio continuum solvation strategy, COSab, a conductor-like continuum solvation model, modified for ab initio in the quantum chemistry program GAMESS. Structure and properties are investigated across various functionals to evaluate their ability to properly model dispersion and solvation effects. The commonly used S22 set with accurate interaction energies of organic complexes has been used for parametrization studies of dispersion parameters and relevant solvation parameters. Dunning's correlation consistent basis sets, cc-pVnZ (n = D, T), are used in the optimization, together with the Grimme B97-D exchange-correlation functional. Both water (ε = 78.4) and ether (ε = 4.33) environments are considered. Optimized semiempirical dispersion correction parameters and solvent extent radii are proposed for several functionals. We find that special parametrization of the semiempirical dispersion correction when used together in the DFT-D/COSab approach is not necessary. The global performance is quite acceptable in terms of chemical accuracy and suggests that this approach is a reliable as well as economical method for evaluation of solvent effects in systems with dispersive interactions. The resulting theory is applied to a group of push-pull pyrrole systems to illustrate the effects of donor/acceptor and solvation on their conformational and energetic properties.
Directory of Open Access Journals (Sweden)
Abu Bakar Mohamad
2013-06-01
Full Text Available 1,5-Dimethyl-4-((2-methylbenzylideneamino-2-phenyl-1H-pyrazol-3(2H-one (DMPO was synthesized to be evaluated as a corrosion inhibitor. The corrosion inhibitory effects of DMPO on mild steel in 1.0 M HCl were investigated using electrochemical impedance spectroscopy (EIS, potentiodynamic polarization, open circuit potential (OCP and electrochemical frequency modulation (EFM. The results showed that DMPO inhibited mild steel corrosion in acid solution and indicated that the inhibition efficiency increased with increasing inhibitor concentration. Changes in the impedance parameters suggested an adsorption of DMPO onto the mild steel surface, leading to the formation of protective films. The novel synthesized corrosion inhibitor was characterized using UV-Vis, FT-IR and NMR spectral analyses. Electronic properties such as highest occupied molecular orbital energy, lowest unoccupied molecular orbital energy (EHOMO and ELUMO, respectively and dipole moment (μ were calculated and discussed. The results showed that the corrosion inhibition efficiency increased with an increase in the EHOMO values but with a decrease in the ELUMO value.
Energy Technology Data Exchange (ETDEWEB)
Vallet, Ana, E-mail: avallet@quim.ucm.es [Grupo de Catalisis y Procesos de Separacion (CyPS), Departamento de Ingenieria Quimica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, Avda. Complutense s/n, 28040 Madrid (Spain); Besson, Michele, E-mail: michele.besson@ircelyon.univ-lyon1.fr [IRCELYON, Institut de recherches sur la catalyse et l' environnement de Lyon, UMR5256 CNRS-Universite Lyon1, 2 Avenue Albert Einstein, F-69626 Villeurbanne Cedex (France); Ovejero, Gabriel; Garcia, Juan [Grupo de Catalisis y Procesos de Separacion (CyPS), Departamento de Ingenieria Quimica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, Avda. Complutense s/n, 28040 Madrid (Spain)
2012-08-15
Highlights: Black-Right-Pointing-Pointer Ni supported over hydrotalcite calcined precursors as catalyst. Black-Right-Pointing-Pointer Catalytic wet air oxidation in trickle bed reactor for Basic Yellow 11 removal. Black-Right-Pointing-Pointer Dye removal depends on temperature, initial dye concentration and flow rate. Black-Right-Pointing-Pointer The catalyst proved to be stable and efficient for the dye degradation. - Abstract: Catalytic wet air oxidation (CWAO) of a Basic Yellow 11 (BY11) aqueous solution, chosen as a model of a hardly biodegradable non-azo dye was carried out in a continuous-flow trickle-bed reactor, using nickel supported over hydrotalcite precursor calcined at 550 Degree-Sign C. An increase in the reaction temperature (120-180 Degree-Sign C), and a decrease in dye concentration (1000-3000 ppm) or liquid flow rate (0.1-0.7 mL min{sup -1}) enhanced the CWAO performance in a 30 and 19% for the variation of the temperature and concentration respectively. After a small leaching observed within the first hours, the catalyst proved to be very stable during the 65-day reaction. The CWAO process was found to be very efficient, achieving BY11 conversion up to 95% and TOC conversion up to 85% at 0.1 mL min{sup -1} and 180 Degree-Sign C under 5 MPa air.
Tsubota, Toshiki; Wang, Chuanshu; Murakami, Naoya; Ohno, Teruhisa
2013-03-01
The electrochemical treatment in a 1 M H2SO4 aqueous solution is applied to the carbon material synthesized from cellulose mixed with guanidine phosphate. The capacitance value increased by the addition of guanidine phosphate; furthermore, the value significantly increased by the electrochemical treatment and was higher than 350 F g-1 at 50 mA g-1. The process used in this study, that is, removing the lignin from wood waste products, such as bamboo, and then mixing with guanidine phosphate before the heat treatment followed by an electrochemical treatment, should be of benefit for the synthesis of a high performance material for the electrodes of electrochemical capacitors. The significant enhancement of the capacitance value appears in the range of 1.5 V∼2.8 V vs. Ag/AgCl for the applied maximum voltage. This voltage range is consistent with the voltage for the significant enhancement of the current value in the CV curve. The change in the capacitance value should be related to the electrochemical reaction of the water electrolysis. The XPS data indicated that the concentrations of both the N atom and the O atom on the surface increased after the electrochemical process.
Tang, Zhehong; Chen, Jieyu; Bai, Yulong; Zhao, Shifeng
2016-08-01
Lead-free magnetoelectric composite films combining Bi4Ti3O12 and CoFe2O4 were synthesized by chemical solution deposition on Pt (100)/Ti/SiO2/Si substrate. Morphological and electrical domain structure, ferroelectric, leakage, dielectric, piezoelectric, magnetic and magnetoelectric properties were investigated for Bi4Ti3O12/CoFe2O4 composite films. Well-defined interfaces between Bi4Ti3O12 and CoFe2O4 film layers and electrical domain structure were observed. The composite films show the coexistence of ferroelectric and ferromagnetic orders at room temperature. Larger piezoelectric coefficient and magnetization are obtained for the composite films, which is contributed to the magnetoelectric effect since it originates from the interface coupling through mechanical strain transfer. This work presents a feasible way to modulate the magnetoelectric coupling in ferromagnetic/ferroelectric composite films for developing lead-free micro-electro-mechanical system and information storage devices.
International Nuclear Information System (INIS)
A new adsorbent (PGCP-COOH) having carboxylate functional group at the chain end was synthesized by grafting poly(hydroxyethylmethacrylate) onto coconut coir pith, CP (a coir industry-based lignocellulosic residue), using potassium peroxydisulphate as an initiator and in the presence of N,N'-methylenebisacrylamide as a cross-linking agent. The adsorbent was characterized with the help of infrared spectroscopy, powder X-ray diffraction, scanning electron microscopy, and potentiometric titrations. The ability of PGCP-COOH to remove Hg(II) from aqueous solutions was assessed using batch adsorption technique under kinetic and equilibrium conditions. Adsorbent exhibits very high adsorption potential for Hg(II) and more than 99.0% removal was achieved in the pH range 5.5-8.0. Adsorption process was found to follow first-order-reversible kinetics. An increase of ionic strength of the medium caused a decrease in metal removal, indicating the occurrence of outer-sphere surface complex mechanism. The equilibrium data were fitted well by the Freundlich isotherm model (R2 = 0.99; χ2 1.81). The removal efficiency was tested using chlor-alkali industry wastewater. Adsorption isotherm experiments were also conducted for comparison using a commercial carboxylate-functionalized ion exchanger, Ceralite IRC-50. Regeneration experiments were tried for four cycles and results indicate a capacity loss of <9.0%
Rai, Nithin; Nöllmann, Marcelo; Spotorno, Bruno; Tassara, Giovanni; Byron, Olwyn; Rocco, Mattia
2005-05-01
Reduced numbers of frictional/scattering centers are essential for tractable hydrodynamic and small-angle scattering data modeling. We present a method for generating medium-resolution models from the atomic coordinates of proteins, basically by using two nonoverlapping spheres of differing radii per residue. The computed rigid-body hydrodynamic parameters of BPTI, RNase A, and lysozyme models were compared with a large database of critically assessed experimental values. Overall, very good results were obtained, but significant discrepancies between X-ray- and NMR-derived models were found. Interestingly, they could be accounted for by properly considering the extent to which highly mobile surface side chains differently affect translational/rotational properties. Models of larger structures, such as fibrinogen fragment D and citrate synthase, also produced consistent results. Foremost among this method's potential applications is the overall conformation and dynamics of modular/multidomain proteins and of supramolecular complexes. The possibility of merging data from high- and low-resolution structures greatly expands its scope.
Numerical Asymptotic Solutions Of Differential Equations
Thurston, Gaylen A.
1992-01-01
Numerical algorithms derived and compared with classical analytical methods. In method, expansions replaced with integrals evaluated numerically. Resulting numerical solutions retain linear independence, main advantage of asymptotic solutions.
Podstawka, Edyta; Kudelski, Andrzej; Olszewski, Tomasz K; Boduszek, Bogdan
2009-07-23
Surface-enhanced Raman scattering (SERS) spectra from phosphonate derivatives of N-heterocyclic aromatic compounds immobilized on an electrochemically roughened silver electrode surface are reported and compared to Raman spectra of the corresponding solid species. The tested compounds contain imidazole [ImMeP ([hydroxy-(1H-imidazol-5-yl)-methyl]-phosphonic acid) and (ImMe)2P (bis[hydroxy-(1H-imidazol-4-yl)-methyl]-phosphinic acid)]; thiazole [BAThMeP ((butylamino-thiazol-2-yl-methyl)-phosphonic acid) and BzAThMeP ((benzylamino-thiazol-2-yl-methyl)-phosphonic acid)]; and pyridine ((PyMe)2P (bis[(hydroxy-pyridin-3-yl-methyl)]-phosphinic acid) aromatic rings. Changes in wavenumber, broadness, and the enhancement of N-heterocyclic aromatic ring bands upon adsorption are consistent with the adsorption primarily occurring through the N lone pair of electrons with the ring arranged in a largely edge-on manner for ImMeP and BzAThMeP or in a slightly inclined orientation to the silver electrode surface at an intermediate angle from the surface normal for (ImMe)2P, BAThMeP, and (PyMe)2P. A strong enhancement of a roughly 1500 cm(-1) SERS signal for ImMeP and (PyMe)2P is also observed. This phenomenon is attributed to the formation of a localized C=C bond, which is accompanied by a decrease in the ring-surface pi-electrons' overlap. In addition, more intense SERS bands due to the benzene ring in BzAThMeP are observed than those observed for the thiazole ring, which suggests a preferential adsorption of benzene. Some interaction of a phosphonate unit is also suggested but with moderate strength between biomolecules. The strength of the P=O coordination to the silver electrode is highest for ImMeP but lowest for BzAThMeP. For all studied biomolecules, the contribution of the structural components to their ability to interact with their receptors was correlated with the SERS patterns.
Li, Yan; Xie, Qiying; Hu, Qian; Li, Chengping; Huang, Zhangjie; Yang, Xiangjun; Guo, Hong
2016-01-01
Hollow magnetic Fe3O4@NH2-MIL-101(Fe) derived from metal-organic frameworks are fabricated through a general facile strategy. The synthetic parameters are regulated to control the shape of the as-prepared samples. The concentration of phosphates decreased sharply from the initial 0.60 to 0.045 mg.L−1 with the exposure time in 50 minutes. The correlation between the most significant parameters such as contact time, adsorbent dose, pH, as well as adsorption capacities was optimized, and the effects of these parameters on the removal efficiency of phosphates were investigated. Surface functionalization of magnetic hollow materials is a well-designed way to bridge the gap between high adsorption activity, excellent separation and recovery of phosphates from the water treatment system. Therefore, it exhibits a remarkable selective removal of phosphates from aqueous solution. PMID:27470443
Li, Yan; Xie, Qiying; Hu, Qian; Li, Chengping; Huang, Zhangjie; Yang, Xiangjun; Guo, Hong
2016-01-01
Hollow magnetic Fe3O4@NH2-MIL-101(Fe) derived from metal-organic frameworks are fabricated through a general facile strategy. The synthetic parameters are regulated to control the shape of the as-prepared samples. The concentration of phosphates decreased sharply from the initial 0.60 to 0.045 mg.L(-1) with the exposure time in 50 minutes. The correlation between the most significant parameters such as contact time, adsorbent dose, pH, as well as adsorption capacities was optimized, and the effects of these parameters on the removal efficiency of phosphates were investigated. Surface functionalization of magnetic hollow materials is a well-designed way to bridge the gap between high adsorption activity, excellent separation and recovery of phosphates from the water treatment system. Therefore, it exhibits a remarkable selective removal of phosphates from aqueous solution. PMID:27470443
Directory of Open Access Journals (Sweden)
Carlos Z. Gómez-Castro
2014-09-01
Full Text Available Intramolecular hydrogen bond (HB formation was analyzed in the model compounds N-(2-benzoylphenylacetamide, N-(2-benzoylphenyloxalamate and N1,N2-bis(2-benzoylphenyloxalamide. The formation of three-center hydrogen bonds in oxalyl derivatives was demonstrated in the solid state by the X-ray diffraction analysis of the geometric parameters associated with the molecular structures. The solvent effect on the chemical shift of H6 [δH6(DMSO-d6–δH6(CDCl3] and Δδ(ΝΗ/ΔT measurements, in DMSO-d6 as solvent, have been used to establish the energetics associated with intramolecular hydrogen bonding. Two center intramolecular HB is not allowed in N-(2-benzoylphenylacetamide either in the solid state or in DMSO-d6 solution because of the unfavorable steric effects of the o-benzoyl group. The estimated ΔHº and ΔSº values for the hydrogen bonding disruption by DMSO-d6 of 28.3(0.1 kJ·mol−1 and 69.1(0.4 J·mol−1·K−1 for oxalamide, are in agreement with intramolecular three-center hydrogen bonding in solution. In the solid, the benzoyl group contributes to develop 1-D and 2-D crystal networks, through C–H∙∙∙A (A = O, π and dipolar C=O∙∙∙A (A = CO, π interactions, in oxalyl derivatives. To the best of our knowledge, this is the first example where three-center hydrogen bond is claimed to overcome steric constraints.
PbZr0.4Ti0.6O3 and Ba0.9Sr0.1TiO3 reflectors derived from chemical solutions containing polymers.
Hu, G J; Shang, J L; Sun, Y; Zhang, T; Wu, J; Xie, J
2008-09-15
Ba(0.9)Sr(0.1)TiO3 (BST)-based and PbZr(0.4)Ti(0.6)O(3)-based quasi-periodic multilayers consisting of dense and porous ferroelectric layers have been fabricated by solgel technique using chemical solutions containing polyethylene glycol (PEG) or polyvinylpyrrolidone k30 (PVP). All multilayers exhibit good performance as dielectric mirrors. For each multilayer, the maximum peak reflectivity is over 90% and the photonic stopband width is no less than 30 nm at room temperature. The reflection-band position can be easily tuned by varying the thickness of the bilayer. With the same processing conditions and number of periods, the Bragg reflection performance is almost the same for quasi-periodic PZT multilayers derived from two precursors containing different polymers. The BST multilayers deposited by using a PVP-containing precursor are superior in optical properties, including peak reflectivities and stop-band width, to those deposited by using the PEG-containing solution. PMID:18794931
Energy Technology Data Exchange (ETDEWEB)
Queraltó, A.; Pérez del Pino, A., E-mail: aperez@icmab.es; Mata, M. de la; Tristany, M.; Gómez, A.; Obradors, X.; Puig, T. [Institut de Ciència de Materials de Barcelona, Consejo Superior de Investigaciones Científicas (ICMAB-CSIC), Campus UAB, 08193 Bellaterra, Catalonia (Spain); Arbiol, J. [Institut de Ciència de Materials de Barcelona, Consejo Superior de Investigaciones Científicas (ICMAB-CSIC), Campus UAB, 08193 Bellaterra, Catalonia (Spain); Institució Catalana de Recerca i Estudis Avançats (ICREA), Passeig Lluís Companys, 23, 08010 Barcelona, Catalonia (Spain)
2015-06-29
Highly crystalline epitaxial Ba{sub 0.8}Sr{sub 0.2}TiO{sub 3} (BST) thin-films are grown on (001)-oriented LaNiO{sub 3}-buffered LaAlO{sub 3} substrates by pulsed laser irradiation of solution derived barium-zirconium-titanium precursor layers using a UV Nd:YAG laser source at atmospheric conditions. The structural analyses of the obtained films, studied by X-ray diffractometry and transmission electron microscopy, demonstrate that laser processing allows the growth of tens of nm-thick BST epitaxial films with crystalline structure similar to that of films obtained through conventional thermal annealing methods. However, the fast pulsed nature of the laser employed leads to crystallization kinetic evolution orders of magnitude faster than in thermal treatments. The combination of specific photothermal and photochemical mechanisms is the main responsible for the ultrafast epitaxial laser-induced crystallization. Piezoresponse microscopy measurements demonstrate equivalent ferroelectric behavior in laser and thermally annealed films, being the piezoelectric constant ∼25 pm V{sup −1}.
DEFF Research Database (Denmark)
Wigan, Duncan
2013-01-01
Contemporary derivatives mark the development of capital and constitute a novel form of ownership. By reconﬁguring the temporal, spatial and legal character of ownership derivatives present a substantive challenge to the tax collecting state. While ﬁscal systems are nationally bounded and inheren......Contemporary derivatives mark the development of capital and constitute a novel form of ownership. By reconﬁguring the temporal, spatial and legal character of ownership derivatives present a substantive challenge to the tax collecting state. While ﬁscal systems are nationally bounded...
Conduction heat transfer solutions
International Nuclear Information System (INIS)
This text is a collection of solutions to a variety of heat conduction problems found in numerous publications, such as textbooks, handbooks, journals, reports, etc. Its purpose is to assemble these solutions into one source that can facilitate the search for a particular problem solution. Generally, it is intended to be a handbook on the subject of heat conduction. This material is useful for engineers, scientists, technologists, and designers of all disciplines, particularly those who design thermal systems or estimate temperatures and heat transfer rates in structures. More than 500 problem solutions and relevant data are tabulated for easy retrieval. There are twelve sections of solutions which correspond with the class of problems found in each. Geometry, state, boundary conditions, and other categories are used to classify the problems. A case number is assigned to each problem for cross-referencing, and also for future reference. Each problem is concisely described by geometry and condition statements, and many times a descriptive sketch is also included. At least one source reference is given so that the user can review the methods used to derive the solutions. Problem solutions are given in the form of equations, graphs, and tables of data, all of which are also identified by problem case numbers and source references
DEFF Research Database (Denmark)
Andersen, Torben Juul
""In Global Derivatives: A Strategic Risk Management Perspective", Torben Juul Andersen has succeeded to gather in one book a complete and thorough summary and an easy-to-read explanation of all types of derivative instruments and their background, and their use in modern management of risk...... approaches to dealing in the global business environment." - Sharon Brown-Hruska, Commissioner, Commodity Futures Trading Commission, USA. "This comprehensive survey of modern risk management using derivative securities is a fine demonstration of the practical relevance of modern derivatives theory to risk...... management practice. Of particular note is the global and integrated approach chosen in this book which should be of special interest to aspiring managers active in global and international markets." - Dr Jean-Pierre Zigrand, Lecturer in Finance, London School of Economics, UK. More than 90 per cent...
International Nuclear Information System (INIS)
Reviewed in this statement are methods of preparing solutions to be used in laboratory experiments to examine technical issues related to the safe disposal of nuclear waste from power generation. Each approach currently used to prepare solutions has advantages and any one approach may be preferred over the others in particular situations, depending upon the goals of the experimental program. These advantages are highlighted herein for three approaches to solution preparation that are currently used most in studies of nuclear waste disposal. Discussion of the disadvantages of each approach is presented to help a user select a preparation method for his particular studies. Also presented in this statement are general observations regarding solution preparation. These observations are used as examples of the types of concerns that need to be addressed regarding solution preparation. As shown by these examples, prior to experimentation or chemical analyses, laboratory techniques based on scientific knowledge of solutions can be applied to solutions, often resulting in great improvement in the usefulness of results
Simon Gray and Joanna Place
2006-01-01
Derivatives, ranging from relatively simple forward contracts to complicated options products, are an increasingly important feature of financial markets worldwide. They are already being used in many emerging markets, and as the financial sector becomes deeper and more stable, their use is certain to grow. This Handbook provides a basic guide to the different types of derivatives traded, including the pricing and valuation of the products, and accounting and statistical treatment. Also, it a...
DEFF Research Database (Denmark)
Efeoglu, Arkin; Møller, Charles; Serie, Michel
2013-01-01
This paper outlines an artifact building and evaluation proposal. Design Science Research (DSR) studies usually consider encapsulated artifact that have relationships with other artifacts. The solution prototype as a composed artifact demands for a more comprehensive consideration in its systemat...
Aïd, René
2015-01-01
Offering a concise but complete survey of the common features of the microstructure of electricity markets, this book describes the state of the art in the different proposed electricity price models for pricing derivatives and in the numerical methods used to price and hedge the most prominent derivatives in electricity markets, namely power plants and swings. The mathematical content of the book has intentionally been made light in order to concentrate on the main subject matter, avoiding fastidious computations. Wherever possible, the models are illustrated by diagrams. The book should allow prospective researchers in the field of electricity derivatives to focus on the actual difficulties associated with the subject. It should also offer a brief but exhaustive overview of the latest techniques used by financial engineers in energy utilities and energy trading desks.
Numerical Solutions of Fractional Boussinesq Equation
Institute of Scientific and Technical Information of China (English)
WANG Qi
2007-01-01
Based upon the Adomian decomposition method,a scheme is developed to obtain numerical solutions of a fractional Boussinesq equation with initial condition,which is introduced by replacing some order time and space derivatives by fractional derivatives.The fractional derivatives are described in the Caputo sense.So the traditional Adomian decomposition method for differential equations of integer order is directly extended to derive explicit and numerical solutions of the fractional differential equations.The solutions of our model equation are calculated in the form of convergent series with easily computable components.
Energy Technology Data Exchange (ETDEWEB)
Vagner, G.R.; Garaev, A.S.; Guzenko, L.P.; Khaber, N.V.; Kruglitskii, N.N.; Kurochkin, B.M.; Shumilov, V.A.
1981-03-23
Proposed is a plugging solution which contains cement, hydrophilic biosilica, polymer, and water, and which is distinguished by the fact that in order to increase the strength properties of the stone with simultaneous increase in its resistance to the effect of corrosive bed water under conditions of normal temperatures, as hydrophilic biosilica the solution contains carboxy aerosil or aminoethoxy aerosil, and as a polymer, carboxylate divinyl styrene latex and it also contains sodium with the following ingredient ratio, wt %: 63.47-66.08% cement, 0.66-1.28% carboxylate divinyl styrene latex, 1.26-1.32% sodium chloride, 0.22-0.36% carboxy aerosil or aminoethoxy aerosil, and the rest water. The plugging solution is distinguished by the fact that carboxy aerosil or aminoethoxy aerosil have a specific surface of 50-300 m/g.
Hyperscaling Violating Solutions in Generalised EMD Theory
Li, Li
2016-01-01
This short note is devoted to deriving scaling but hyperscaling violating solutions in a generalised Einstein-Maxwell-Dilaton theory with an arbitrary number of scalars and vectors. We obtain analytic solutions in some special case and discuss the physical constraints on the allowed parameter range in order to have a well-defined holographic ground-state solution.
Directory of Open Access Journals (Sweden)
Reza A Zoroofi
2007-08-01
Full Text Available Medal Electronic (ME Engineering Company provides high quality systems, software and services in medical image management, processing and visualization. We assist health care professionals to improve and extend the efficiency of their practices with cost effective solutions. ME is the developer of several medical software including MEDAL-PACS, 3D-Sonosoft, Analytical-Electrophoresis, CBONE and Rhino-Plus. ME is also the exclusive distributor of PACSPLUS in Iran. PACSPLUS is an international, standard, scalable and enterprise PACS solution. PACSPLUS is of ISO, CE and FDA-510 approvals. It is now operational in more than 1000 clinical environment throughout the globe. We discuss about the key features of PACSPLUS system for dealing with real world challenge in PACS as well as the PACS solu-tions needed to fulfill the demands of the clinicians in Iran. Our experience in developing high-end medical software confirms our capability in providing the PACSPLUS as an ultimate PACS solution in Iran.
Semianalytic Solution of Space-Time Fractional Diffusion Equation
Directory of Open Access Journals (Sweden)
A. Elsaid
2016-01-01
Full Text Available We study the space-time fractional diffusion equation with spatial Riesz-Feller fractional derivative and Caputo fractional time derivative. The continuation of the solution of this fractional equation to the solution of the corresponding integer order equation is proved. The series solution of this problem is obtained via the optimal homotopy analysis method (OHAM. Numerical simulations are presented to validate the method and to show the effect of changing the fractional derivative parameters on the solution behavior.
Hill, Colin
2010-01-01
Recently we reported a role for compatible solute uptake in mediating bile tolerance and increased gastrointestinal persistence in the foodborne pathogen Listeria monocytogenes.1 Herein, we review the evolution in our understanding of how these low molecular weight molecules contribute to growth and survival of the pathogen both inside and outside the body, and how this stress survival mechanism may ultimately be used to target and kill the pathogen. PMID:21326913
Chemistry of ruthenium in nitric acid solution with special regard to nuclear fuel solutions
International Nuclear Information System (INIS)
A review is given concerning the published knowledge about the chemistry of ruthenium in nitric acid solution with special reference to nitric acid nuclear fuel solutions. Possibilities of the spectroscopic description of the different existing ruthenium complexes are discussed and papers are presented dealing with the estimation of the proportions of the different ruthenium compounds in nuclear fuel solutions. Finally, arguments are derived for the preparation of ruthenium-containing model solutions, which adequately simulate the composition of real nuclear fuel solutions. (author)
Functionalized polymers for binding to solutes in aqueous solutions
Smith, Barbara F.; Robison, Thomas W.
2006-11-21
A functionalized polymer for binding a dissolved molecule in an aqueous solution is presented. The polymer has a backbone polymer to which one or more functional groups are covalently linked. The backbone polymer can be such polymers as polyethylenimine, polyvinylamine, polyallylamine, and polypropylamine. These polymers are generally water-soluble, but can be insoluble when cross-linked. The functional group can be for example diol derivatives, polyol derivatives, thiol and dithiol derivatives, guest-host groups, affinity groups, beta-diphosphonic acids, and beta-diamides
Radiative Transfer in spheres I. Analytical Solutions
Aboughantous, C
2001-01-01
A nonsingular analytical solution for the transfer equation in a pure absorber is obtained in central symmetry and in a monochromatic radiation field. The native regular singularity of the equation is removed by applying a linear transformation to the frame of reference. Two different ap-proaches are used to carry out the solution. In the first approach the angular derivative is interpreted in an original way that made it possible to discard this derivative from the equation for all black body media without upsetting the conservation of energy. In this approach the analytic solution is expressible in terms of exponential integrals without approximations but for practical considerations the solution is presented in the form of Gauss-Legendre quadrature for quantitative evaluation of the solutions. In the second approach the angular derivative is approximated by a new set of discrete ordinates that guarantees the closer of the set of equations and the conservation of energy. The solutions from the two approache...
Institute of Scientific and Technical Information of China (English)
默会霞; 余东艳; 隋鑫
2014-01-01
Nonlinear Schr¨odinger equation is a general nonlinear model in modern science. Using the Ado-main decomposition method, we construct the approximate solutions to the (2+1) and (3+1) dimensional time fractional Sch¨ordinger equations with nonzero trapping potential. It is not necessary for us to decompose the solution function into real part and imaginary part as in relative references. So, the Adomain decomposition simplifies the procedure of solving the equation.%非线性薛定谔方程是现代科学中非常普遍的非线性模型之一。通过 Adomain分解，得到了(2+1)维和(3+1)维非零势阱时间分数阶薛定谔方程的近似解。利用Adomain 分解不用像相关文献中那样将解函数的实部和虚部分别去求解，从而简化了求解过程。
Equivalence of Network-Solution and PPP-Solution
Institute of Scientific and Technical Information of China (English)
PENG Lin; LIU Yanxiong; ZHOU Xinghua; WU Yongting
2006-01-01
The technique of precise point positioning (PPP) is gradually becoming a popular method in GPS data-processing. In GPS observation equation, the unknown parameters can be separated into two parts: global parameters and local parameters. The global parameters include orbit, satellite clock and geodynamic parameters. The local parameters are site-occupation-specific, such as position, tropospheric delay, etc. The formulas of local parameters are firstly derived under the network-solution and the PPP-solution conditions respectively. If the weight matrix of global parameters in PPP-solution is small enough, the cofactor matrices of local parameters are the same as that in network-solution. Then, 16 daily solutions are obtained in both PPP mode and network mode. Three sites are selected to compare the solutions. The experimental results demonstrated that the difference between two solutions in coordinates and tropospheric delays are only few millimeters. This level of difference can be neglected so that the solutions from both PPP mode and network mode can be taken as the same in the actual application.
On the solutions to accelerating cosmologies
Ito, M
2003-01-01
Motivated by recent accelerating cosmological model, we derive the solutions to vacuum Einstein equation in $(d+1)$-dimensional Minkowski space with $n$-dimensional hyperbolic manifold. The conditions of accelerating expansion are given in such a set up.
Morris, Simon Conway
2004-11-01
Life's Solution builds a persuasive case for the predictability of evolutionary outcomes. The case rests on a remarkable compilation of examples of convergent evolution, in which two or more lineages have independently evolved similar structures and functions. The examples range from the aerodynamics of hovering moths and hummingbirds to the use of silk by spiders and some insects to capture prey. Going against the grain of Darwinian orthodoxy, this book is a must read for anyone grappling with the meaning of evolution and our place in the Universe. Simon Conway Morris is the Ad Hominen Professor in the Earth Science Department at the University of Cambridge and a Fellow of St. John's College and the Royal Society. His research focuses on the study of constraints on evolution, and the historical processes that lead to the emergence of complexity, especially with respect to the construction of the major animal body parts in the Cambrian explosion. Previous books include The Crucible of Creation (Getty Center for Education in the Arts, 1999) and co-author of Solnhofen (Cambridge, 1990). Hb ISBN (2003) 0-521-82704-3
Directory of Open Access Journals (Sweden)
Mohammad Hossein Sattari
2016-06-01
Full Text Available In this article, the notion of $n-$derivation is introduced for all integers $ngeq 2$. Although all derivations are $n-$derivations, in general these notions are not equivalent. Some properties of ordinary derivations are investigated for $n-$derivations. Also, we show that under certain mild condition $n-$derivations are derivations.
On Alternative Optimal Solutions to Linear Fractional Optimization Problems
Institute of Scientific and Technical Information of China (English)
ShengjiaXue
2004-01-01
The structure of the optimal solution set is derived for linear fractional optimization problems with the representation theorem of polyhedral sets．And the computational procedure in determining all optimal solutions is also given．
Traveling Wave Solutions in a Reaction-Diffusion Epidemic Model
Sheng Wang; Wenbin Liu; Zhengguang Guo; Weiming Wang
2013-01-01
We investigate the traveling wave solutions in a reaction-diffusion epidemic model. The existence of the wave solutions is derived through monotone iteration of a pair of classical upper and lower solutions. The traveling wave solutions are shown to be unique and strictly monotonic. Furthermore, we determine the critical minimal wave speed.
A compact analytic solution describing optoacoustic phenomenon in absorbing fluid
Cundin, Luisiana; Barsalou, Norman; Voss, Shannon
2012-01-01
Derivation of an analytic, closed-form solution for Q-switched laser induced optoacoustic phenomenon in absorbing fluid media is presented. The solution assumes spherical symmetry as well for the forcing function, which represents heat deposition from Q-switched lasers. The Greens solution provided is a suitable kernel to generate more complex solutions arising in optoacoustics, optoacoustic spectroscopy, photoacoustic and photothermal problems.
Strongly nonlinear oscillators analytical solutions
Cveticanin, Livija
2014-01-01
This book provides the presentation of the motion of pure nonlinear oscillatory systems and various solution procedures which give the approximate solutions of the strong nonlinear oscillator equations. The book presents the original author’s method for the analytical solution procedure of the pure nonlinear oscillator system. After an introduction, the physical explanation of the pure nonlinearity and of the pure nonlinear oscillator is given. The analytical solution for free and forced vibrations of the one-degree-of-freedom strong nonlinear system with constant and time variable parameter is considered. Special attention is given to the one and two mass oscillatory systems with two-degrees-of-freedom. The criteria for the deterministic chaos in ideal and non-ideal pure nonlinear oscillators are derived analytically. The method for suppressing chaos is developed. Important problems are discussed in didactic exercises. The book is self-consistent and suitable as a textbook for students and also for profess...
Exact cosmological solutions for MOG
Energy Technology Data Exchange (ETDEWEB)
Roshan, Mahmood [Ferdowsi University of Mashhad, Department of Physics, P.O. Box 1436, Mashhad (Iran, Islamic Republic of)
2015-09-15
We find some new exact cosmological solutions for the covariant scalar-tensor-vector gravity theory, the so-called modified gravity (MOG). The exact solution of the vacuum field equations has been derived. Also, for non-vacuum cases we have found some exact solutions with the aid of the Noether symmetry approach. More specifically, the symmetry vector and also the Noether conserved quantity associated to the point-like Lagrangian of the theory have been found. Also we find the exact form of the generic vector field potential of this theory by considering the behavior of the relevant point-like Lagrangian under the infinitesimal generator of the Noether symmetry. Finally, we discuss the cosmological implications of the solutions. (orig.)
Twisting singular solutions of Bethe's equations
Nepomechie, Rafael I
2014-01-01
The Bethe equations for the periodic XXX and XXZ spin chains admit singular solutions, for which the corresponding eigenvalues and eigenvectors are ill-defined. We use a twist regularization to derive conditions for such singular solutions to be physical, in which case they correspond to genuine eigenvalues and eigenvectors of the Hamiltonian.
Institute of Scientific and Technical Information of China (English)
张耿崚; 陈志成; 林俊宏; 谢荣峯; 汪印; 赵峰; 施怡瑄; 邢贞娇; 陈水田
2014-01-01
Activated carbon was prepared from rice straw by carbonization and KOH activation, and was used as an adsorbent for the removal of a kind of pesticide, carbofuran (2,3-dihydro-2,2-dimethylbenzofuran-7-yl methylcarbamate) from aqueous solution. The effects of the initial carbofuran concentration, contact time, temperature and pH, on its adsorption capacity and kinetics were studied using a batch method. The surface area and average pore diameter of the activated carbon were 1304. 8 m2/g and 2. 39 nm, respectively. The maximum adsorption capacity of the activated carbon (296. 52 mg/g) for carbofuran was found to occur at 90 min, 30℃ and 200 mg/L initial carbofuran concentration with an adsorbent loading of 100 mg/L. Equilibrium adsorption isotherms were fitted better by the Langmuir model than the Freundlich and Temkin models. The adsorption follows a pseudo-second-order kinetics model.%以KOH为活化剂进行两段式活化程序,将废弃生物质材料转化为活性炭,并评估此活性炭吸对液相中农药(呋喃丹)的去除能力。结果表明,此活性炭具有大比表面积与高吸附能力可快速有效地去除液相中的呋喃丹。吸附前后的活性炭用扫描电子显微镜、元素分析仪与傅里叶变换红外光谱仪进行特征分析。活性炭的比表面积与平均孔径分别为1304.8 m2/g与2.39 nm。同时对不同的吸附参数进行批次分析,包括呋喃丹初始浓度,吸附时间、温度与酸碱度。最大吸附量(296.52mg/g)的吸附参数为90min、30益、吸附剂剂量100mg/L、180r/min、呋喃丹初始浓度200mg/L。根据三种平衡吸附等温线( Langmuir, Freundlich and Temkin)与动力学分析,Langmuir模式最符合此活性炭的吸附结果,伪二级动力学方程可预测此活性炭的吸附动力学。
Scaling solutions for Dilaton Quantum Gravity
Henz, Tobias; Pawlowski, Jan Martin; Wetterich, Christof
2016-01-01
Scaling solutions for the effective action in dilaton quantum gravity are investigated within the functional renormalization group approach. We find numerical solutions that connect ultraviolet and infrared fixed points as the ratio between scalar field and renormalization scale $k$ is varied. In the Einstein frame the quantum effective action corresponding to the scaling solutions becomes independent of $k$. The field equations derived from this effective action can be used directly for cosm...
Exact solution of phantom dark energy model
Institute of Scientific and Technical Information of China (English)
Wang Wen-Fu; Shui Zheng-Wei; Tang Bin
2010-01-01
We investigate the phantom dark energy model derived from the scalar field with a negative kinetic term. By assuming a particular relation between the time derivative of the phantom field and the Hubble function, an exact solution of the model is constructed. Absence of the 'big rip' singularity is shown explicitly. We then derive special features of phantom dark energy model and show that its predictions are consistent with all astrophysical observations.
Schwarzschild Solution: A Historical Perspective
Bartusiak, Marcia
2016-03-01
While eighteenth-century Newtonians had imagined a precursor to the black hole, the modern version has its roots in the first full solution to Einstein's equations of general relativity, derived by the German astronomer Karl Schwarzschild on a World War I battlefront just weeks after Einstein introduced his completed theory in November 1915. This talk will demonstrate how Schwarzschild's solution is linked to the black hole and how it took more than half a century for the physics community to accept that such a bizarre celestial object could exist in the universe.
Anisotropic higher derivative gravity and inflationary universe
Kao, W F
2006-01-01
Stability analysis of the Kantowski-Sachs type universe in pure higher derivative gravity theory is studied in details. The non-redundant generalized Friedmann equation of the system is derived by introducing a reduced one dimensional generalized KS type action. This method greatly reduces the labor in deriving field equations of any complicate models. Existence and stability of inflationary solution in the presence of higher derivative terms are also studied in details. Implications to the choice of physical theories are discussed in details in this paper.
Normal BGG solutions and polynomials
Cap, A; Hammerl, M
2012-01-01
First BGG operators are a large class of overdetermined linear differential operators intrinsically associated to a parabolic geometry on a manifold. The corresponding equations include those controlling infinitesimal automorphisms, higher symmetries, and many other widely studied PDE of geometric origin. The machinery of BGG sequences also singles out a subclass of solutions called normal solutions. These correspond to parallel tractor fields and hence to (certain) holonomy reductions of the canonical normal Cartan connection. Using the normal Cartan connection, we define a special class of local frames for any natural vector bundle associated to a parabolic geometry. We then prove that the coefficient functions of any normal solution of a first BGG operator with respect to such a frame are polynomials in the normal coordinates of the parabolic geometry. A bound on the degree of these polynomials in terms of representation theory data is derived. For geometries locally isomorphic to the homogeneous model of ...
Scaling solutions for Dilaton Quantum Gravity
Henz, Tobias; Wetterich, Christof
2016-01-01
Scaling solutions for the effective action in dilaton quantum gravity are investigated within the functional renormalization group approach. We find numerical solutions that connect ultraviolet and infrared fixed points as the ratio between scalar field and renormalization scale $k$ is varied. In the Einstein frame the quantum effective action corresponding to the scaling solutions becomes independent of $k$. The field equations derived from this effective action can be used directly for cosmology. Scale symmetry is spontaneously broken by a non-vanishing cosmological value of the scalar field. For the cosmology corresponding to our scaling solutions, inflation arises naturally. The effective cosmological constant becomes dynamical and vanishes asymptotically as time goes to infinity.
Zhang, Zhizeng; Zhao, Zhao; Li, Yongtao
2016-06-01
This paper attempts to verify the correctness of the analytical displacement solution in transversely isotropic rock mass, and to determine the scope of its application. The analytical displacement solution of a circular tunnel in transversely isotropic rock mass was derived firstly. The analytical solution was compared with the numerical solution, which was carried out by FLAC3D software. The results show that the expression of the analytical displacement solution is correct, and the allowable engineering range is that the dip angle is less than 15 degrees.
Nonequilibrium thermodynamics of pressure solution
Lehner, F. K.; Bataille, J.
1984-01-01
This paper is concerned with the thermodynamic theory of solution and precipitation processes in wet crustal rocks and with the mechanism of steady pressure-solution slip in ‘contact zones,’ such as grain-to-grain contacts, fracture surfaces, and permeable gouge layers, that are infiltrated by a mobile aqueous solution phase. A local dissipation jump condition at the phase boundary is fundamental to identifying the thermodynamic force driving the solution and precipitation process and is used here in setting up linear phenomenological relations to model near-equilibrium phase transformation kinetics. The local thermodynamic equilibrium of a stressed pure solid in contact with its melt or solution phase is governed by Gibbs's relation, which is rederived here, in a manner emphasizing its independence of constitutive assumptions for the solid while neglecting surface tension and diffusion in the solid. Fluid-infiltrated contact zones, such as those formed by rough surfaces, cannot generally be in thermodynamic equilibrium, especially during an ongoing process of pressure-solution slip, and the existing equilibrium formulations are incorrect in overlooking dissipative processes tending to eliminate fluctuations in superficial free energies due to stress concentrations near asperities, defects, or impurities. Steady pressure-solution slip is likely to exhibit a nonlinear dependence of slip rate on shear stress and effective normal stress, due to a dependence of the contact-zone state on the latter. Given that this dependence is negligible within some range, linear relations for pressure-solution slip can be derived for the limiting cases of diffusion-controlled and interface-reaction-controlled rates. A criterion for rate control by one of these mechanisms is set by the magnitude of the dimensionless quantity kδ/2C pD, where k is the interfacial transfer coefficient, δ is the mean diffusion path length, C p is the solubility at pressure p, and D is the mass
Exact vacuum solution of a (1+2)-dimensional Poincare gauge theory BTZ solution with torsion
Garcia, A A; Heinicke, C; Macías, A; Garcia, Alberto A.; Hehl, Friedrich W.; Heinicke, Christian; Macias, Alfredo
2003-01-01
In (1+2)-dimensional Poincar\\'e gauge gravity, we start from a Lagrangian depending on torsion and curvature which includes additionally {\\em translational} and {\\em Lorentzian} Chern-Simons terms. Limiting ourselves to to a specific subcase, the Mielke-Baekler (MB) model, we derive the corresponding field equations (of Einstein-Cartan-Chern-Simons type) and find the general vacuum solution. We determine the properties of this solution, in particular its mass and its angular momentum. For vanishing torsion, we recover the BTZ-solution. We also derive the general conformally flat vacuum solution with torsion. In this framework, we discuss {\\em Cartan's} (3-dimensional) {\\em spiral staircase} and find that it is not only a special case of our new vacuum solution, but can alternatively be understood as a solution of the 3-dimensional Einstein-Cartan theory with matter of constant pressure and constant torque. {\\em file 3dexact15.tex}
Fractional Diffusion based on Riemann-Liouville Fractional Derivatives
Hilfer, R.
2000-01-01
A fractional diffusion equation based on Riemann-Liouville fractional derivatives is solved exactly. The initial values are given as fractional integrals. The solution is obtained in terms of $H$-functions. It differs from the known solution of fractional diffusion equations based on fractional integrals. The solution of fractional diffusion based on a Riemann-Liouville fractional time derivative does not admit a probabilistic interpretation in contrast with fractional diffusion based on frac...
Synthesis and Aqueous Solution Viscosity of Hydrophobically Modified Xanthan Gum
Institute of Scientific and Technical Information of China (English)
QIAN Xiao-lin; WU Wen-hui; YU Pei-zhi; WANG Jian-quan
2007-01-01
Two xanthan gum derivatives hydrophobically modified by 4 or 8 tetradecyl chains per 100 xanthan gum structure units were synthesized. The derivatives were studied by scanning electron microscope and pyrene fluorescence spectrometry. And the aqueous solution apparent viscosity of the derivatives was investigated. The results indicate that the network of the derivatives with more hydrophobic groups is closer and tighter. With increasing of alkyl chain substitution degree, the hydrophobically associating interactions enhance in aqueous solution. Aqueous solution apparent viscosity of the derivatives increases with increasing of polymer concentration and alkyl substitution degree, and decreases with the increase of temperature. In the brine solution, the strong viscosity enhancement phenomenon appears. The interaction between the derivatives and surfactant sodium dodecylbenzene sulfonate is strong.
Institute of Scientific and Technical Information of China (English)
JIANG Ai-min; DING Hao-jiang
2005-01-01
In this paper, the specific solutions of orthotropic plane problems with body forces are derived. Then, based on the general solution in the case of distinct eigenvalues and the specific solution for density functionally graded orthotropic media, a series of beam problem, including the problems of cantilever beam with body forces depending only on z or on x coordinate and expressed by z or x polynomial is solved by the principle of superposition and the trial-and-error method.
One-soliton solutions from Laplace’s seed
Indian Academy of Sciences (India)
S Chaudhuri; K C Das
2002-03-01
One-soliton solutions of axially symmetric vacuum Einstein ﬁeld equations are presented in this paper. Two sets of Laplace’s solutions are used as seed and it is shown that the derived solutions reduce to some already known solutions when the constants are properly adjusted. An analysis of the solutions in terms of the Ernst potential is also presented. It is found that the solutions do not reduce to the Euclidean form at spatial inﬁnity. However, in the static limit, Weyl solutions are obtained for half integral -values.
Fractional Solutions of Bessel Equation with N-Method
Erdal Bas; Resat Yilmazer; Etibar Panakhov
2013-01-01
This paper deals with the design fractional solution of Bessel equation. We obtain explicit solutions of the equation with the help of fractional calculus techniques. Using the N-fractional calculus operator N ν method, we derive the fractional solutions of the equation.
The Peridic Wave Solutions for Two Nonlinear Evolution Equations
Institute of Scientific and Technical Information of China (English)
ZHANG Jin-Liang; WANG Ming-Liang; CHENG Dong-Ming; FANG Zong-De
2003-01-01
By using the F-expansion method proposed recently, the periodic wave solutions expressed by Jacobielliptic functions for two nonlinear evolution equations are derived. In the limit cases, the solitary wave solutions andthe other type of traveling wave solutions for the system are obtained.
Analytic solutions of a class of nonlinearly dynamic systems
Energy Technology Data Exchange (ETDEWEB)
Wang, M-C [System Engineering Institute of Tianjin University, Tianjin, 300072 (China); Zhao, X-S; Liu, X [Tianjin University of Technology and Education, Tianjin, 300222 (China)], E-mail: mchwang123@163.com.cn, E-mail: xszhao@mail.nwpu.edu.cn, E-mail: liuxinhubei@163.com.cn
2008-02-15
In this paper, the homotopy perturbation method (HPM) is applied to solve a coupled system of two nonlinear differential with first-order similar model of Lotka-Volterra and a Bratus equation with a source term. The analytic approximate solutions are derived. Furthermore, the analytic approximate solutions obtained by the HPM with the exact solutions reveals that the present method works efficiently.
Static Solutions of Einstein's Equations with Cylindrical Symmetry
Trendafilova, C. S.; Fulling, S. A.
2011-01-01
In analogy with the standard derivation of the Schwarzschild solution, we find all static, cylindrically symmetric solutions of the Einstein field equations for vacuum. These include not only the well-known cone solution, which is locally flat, but others in which the metric coefficients are powers of the radial coordinate and the spacetime is…
On rotational solutions for elliptically excited pendulum
International Nuclear Information System (INIS)
The author considers the planar rotational motion of the mathematical pendulum with its pivot oscillating both vertically and horizontally, so the trajectory of the pivot is an ellipse close to a circle. The analysis is based on the exact rotational solutions in the case of circular pivot trajectory and zero gravity. The conditions for existence and stability of such solutions are derived. Assuming that the amplitudes of excitations are not small while the pivot trajectory has small ellipticity the approximate solutions are found both for high and small linear dampings. Comparison between approximate and numerical solutions is made for different values of the damping parameter. -- Highlights: → We study rotations of the mathematical pendulum when its pivot moves along an ellipse. → There are stable exact solutions for a circular pivot trajectory and zero gravity. → Asymptotic solutions are found for an elliptical pivot trajectory
DEFF Research Database (Denmark)
Svenstrup, Mikkel
This Ph.D. thesis consists of four self-contained essays on valuation of interest rate derivatives. In particular derivatives related to management of interest rate risk care are considered.......This Ph.D. thesis consists of four self-contained essays on valuation of interest rate derivatives. In particular derivatives related to management of interest rate risk care are considered....
Synthetic Bioluminescent Coelenterazine Derivatives.
Nishihara, Ryo; Citterio, Daniel; Suzuki, Koji
2016-01-01
The development of coelenterazine (CTZ) derivatives resulting in superior optical characteristics is an efficient method to extend the range of its possible applications. Here, we describe the synthesis of three C-6 substituted CTZ derivatives retaining the recognition by Renilla luciferase (RLuc) and its derivatives. The novel derivatives are useful as bright blue-shifted CTZ derivatives, which can be used as an alternative to hitherto reported compound DeepBlueC™. PMID:27424892
Solutions manual to accompany Fundamentals of calculus
Morris, Carla C
2015-01-01
Solutions Manual to Accompany Fundamentals of Calculus the text that encourages students to use power, quotient, and product rules for solutions as well as stresses the importance of modeling skills. In addition to core integral and differential calculus coverage, the core book features finite calculus, which lends itself to modeling and spreadsheets. Specifically, finite calculus is applied to marginal economic analysis, finance, growth, and decay. Includes: Linear Equations and Functions The Derivative Using the Derivative Exponential and Logarithmic
Viscous fluid interpretation of some exact solutions
Energy Technology Data Exchange (ETDEWEB)
Carot, J.; Ibanez, J.
1985-09-01
An example of the equivalence between a perfect fluid and a viscous fluid is presented, showing that the Schwarzschild interior solution obtained from a perfect fluid can also be derived from a viscous fluid with heat conduction. The equivalence between a scalar field and a viscous fluid is investigated, showing that under certain circumstances, both can generate, from Einstein's equations, the same space-time geometry. Some examples are presented and, in particular, it is shown that every plane-symmetric solution deduced from a scalar field can also be derived from a viscous fluid.
New solutions for the confined horizontal aquifer
Akylas, Evangelos; Gravanis, Elias
2016-04-01
The Boussinesq equation is a dynamical equation for the free surface of saturated subsurface flows over an impervious bed. Boussinesq equation is non-linear. The non-linearity comes from the reduction of the dimensionality of the problem: The flow is assumed to be vertically homogeneous, therefore the flow rate through a cross section of the flow is proportional to the free surface height times the hydraulic gradient, which is assumed to be equal to the slope of the free surface. In the present work we consider the case of the subsurface flow with horizontal bed. This is a case with an infinite Henderson and Wooding parameter, that is, it is the limiting case where the non-linear term is present in the Boussinesq equation while the linear spatial derivative term vanishes. Nonetheless, no analogue of the kinematic wave exists in this case as there is no exact solution for the build-up phase. Neither is there an exact recession-phase solution that holds in early times, as the Boussinesq separable solution is actually an asymptotic solution for large times. We construct approximate solutions for the horizontal aquifer which utilize directly the dynamical content of the non-linear Boussinesq equation. The approximate character of the solution lies in the fact that we start with a pre-supposed form for the solution, an educated guess, based on the nature of the initial condition as well as empirical observations from the numerical solution of the problem. The forms we shall use are power series of the location variable x along the bed with time-dependent coefficients. The series are not necessarily analytic. The boundary conditions are incorporated in the structure of the series from the beginning. The time-dependent coefficients are then determined by applying the Boussinesq equation and its spatial derivatives at the end-points of the aquifer. The forms are chosen also on the basis of their solubility; we would like to be able to construct explicitly the approximate
Black holes in higher derivative gravity.
Lü, H; Perkins, A; Pope, C N; Stelle, K S
2015-05-01
Extensions of Einstein gravity with higher-order derivative terms arise in string theory and other effective theories, as well as being of interest in their own right. In this Letter we study static black-hole solutions in the example of Einstein gravity with additional quadratic curvature terms. A Lichnerowicz-type theorem simplifies the analysis by establishing that they must have vanishing Ricci scalar curvature. By numerical methods we then demonstrate the existence of further black-hole solutions over and above the Schwarzschild solution. We discuss some of their thermodynamic properties, and show that they obey the first law of thermodynamics.
Black holes in higher derivative gravity.
Lü, H; Perkins, A; Pope, C N; Stelle, K S
2015-05-01
Extensions of Einstein gravity with higher-order derivative terms arise in string theory and other effective theories, as well as being of interest in their own right. In this Letter we study static black-hole solutions in the example of Einstein gravity with additional quadratic curvature terms. A Lichnerowicz-type theorem simplifies the analysis by establishing that they must have vanishing Ricci scalar curvature. By numerical methods we then demonstrate the existence of further black-hole solutions over and above the Schwarzschild solution. We discuss some of their thermodynamic properties, and show that they obey the first law of thermodynamics. PMID:25978224
Black Holes in Higher-Derivative Gravity
Lu, H; Pope, C N; Stelle, K S
2015-01-01
Extensions of Einstein gravity with higher-order derivative terms arise in string theory and other effective theories, as well as being of interest in their own right. In this paper we study static black-hole solutions in the example of Einstein gravity with additional quadratic curvature terms. A Lichnerowicz-type theorem simplifies the analysis by establishing that they must have vanishing Ricci scalar curvature. By numerical methods we then demonstrate the existence of further black-hole solutions over and above the Schwarzschild solution. We discuss some of their thermodynamic properties, and show that they obey the first law of thermodynamics.
Asymptotic Behavior of Periodic Wave Solution to the Hirota-Satsuma Equation
Institute of Scientific and Technical Information of China (English)
WU Yong-Qi
2011-01-01
The one- and two-periodic wave solutions (or the Hirota-Satsuma (HS) equation are presented by using the Hirota derivative and Riemann theta function. The rigorous proofs on asymptotic behaviors of these two solutions are given such that soliton solution can be obtained from the periodic wave solution in an appropriate limiting procedure.%@@ The one- and two-periodic wave solutions for the Hirota-Satsuma (HS) equation are presented by using the Hirota derivative and Riemann theta function.The rigorous proofs on asymptotic behaviors of these two solutions are g/ven such that soliton solution can be obtained from the periodic wave solution in an appropriate limiting procedure.
Solutions of fractional diffusion equations by variation of parameters method
Directory of Open Access Journals (Sweden)
Mohyud-Din Syed Tauseef
2015-01-01
Full Text Available This article is devoted to establish a novel analytical solution scheme for the fractional diffusion equations. Caputo’s formulation followed by the variation of parameters method has been employed to obtain the analytical solutions. Following the derived analytical scheme, solution of the fractional diffusion equation for several initial functions has been obtained. Graphs are plotted to see the physical behavior of obtained solutions.
Novel Hyperbolic Homoclinic Solutions of the Helmholtz-Duffing Oscillators
Directory of Open Access Journals (Sweden)
Yang-Yang Chen
2016-01-01
Full Text Available The exact and explicit homoclinic solution of the undamped Helmholtz-Duffing oscillator is derived by a presented hyperbolic function balance procedure. The homoclinic solution of the self-excited Helmholtz-Duffing oscillator can also be obtained by an extended hyperbolic perturbation method. The application of the present homoclinic solutions to the chaos prediction of the nonautonomous Helmholtz-Duffing oscillator is performed. Effectiveness and advantage of the present solutions are shown by comparisons.
Strong shock implosion, approximate solution
Fujimoto, Y.; Mishkin, E. A.; Alejaldre, C.
1983-01-01
The self-similar, center-bound motion of a strong spherical, or cylindrical, shock wave moving through an ideal gas with a constant, γ= cp/ cv, is considered and a linearized, approximate solution is derived. An X, Y phase plane of the self-similar solution is defined and the representative curved of the system behind the shock front is replaced by a straight line connecting the mappings of the shock front with that of its tail. The reduced pressure P(ξ), density R(ξ) and velocity U1(ξ) are found in closed, quite accurate, form. Comparison with numerically obtained results, for γ= {5}/{3} and γ= {7}/{5}, is shown.
Static scalar field solutions in symmetric gravity
Hossenfelder, S.
2016-09-01
We study an extension of general relativity with a second metric and an exchange symmetry between the two metrics. Such an extension might help to address some of the outstanding problems with general relativity, for example the smallness of the cosmological constant. We here derive a family of exact solutions for this theory. In this two-parameter family of solutions the gravitational field is sourced by a time-independent massless scalar field. We find that the only limit in which the scalar field entirely vanishes is flat space. The regular Schwarzschild-solution is left with a scalar field hidden in the second metric’s sector.
Finite element solutions of free surface flows
Zarda, P. R.; Marcus, M. S.
1977-01-01
A procedure is presented for using NASTRAN to determine the flow field about arbitrarily shaped bodies in the presence of a free surface. The fundamental unknown of the problem is the velocity potential which must satisfy Laplace's equation in the fluid region. Boundary conditions on the free surface may involve second order derivatives in space and time. In cases involving infinite domains either a tractable radiation condition is applied at a truncated boundary or a series expansion is used and matched to the local finite elements. Solutions are presented for harmonic, transient, and steady state problems and compared to either exact solutions or other numerical solutions.
Institute of Scientific and Technical Information of China (English)
武丽君; 王朝旭; 张峰; 崔建国
2016-01-01
为探明玉米秸秆和玉米芯生物炭对水溶液中无机氮的吸附性能,研究了其对NH4+-N、NO3--N和NO2--N的吸附动力学过程；并用等温吸附模型对NH4+-N和NO3--N的吸附过程进行拟合,探讨制得生物炭对无机氮的吸附机理.结果表明,400℃和600℃制得玉米秸秆和玉米芯生物炭均呈碱性,表现为400℃<600℃；同种原材料,与400℃制得生物炭相比,600℃制得生物炭碱性含氧官能团数量较多,而酸性含氧官能团数量较少.400℃制得生物炭对NH4+-N的吸附能力较强(玉米秸秆和玉米芯生物炭的平衡吸附量分别为4.22和4.09mg/g)；而600℃制得生物炭对NO3--N和NO2--N的吸附能力较强(玉米秸秆和玉米芯生物炭对NO3--N的平衡吸附量分别为0.73和0.63mg/g；对NO2--N的平衡吸附量分别为0.55和0.35mg/g).与 NO3--N 和 NO2--N 相比,玉米秸秆和玉米芯生物炭对 NH4+-N 的吸附能力更强,4种生物炭对NH4+-N 的平衡吸附量是 NO3--N/NO2--N 的4.29~20.2倍.等温吸附模型拟合研究表明,玉米秸秆和玉米芯生物炭对水溶液中 NH4+-N 和NO3--N的吸附过程均可用Freundlich模型描述,其在生物炭表面的吸附是多分子层吸附.%In order to explore the adsorption characters of inorganic nitrogen in aqueous solution by maize straw- and corn cob-derived biochars, the adsorption kinetics of NH4+-N, NO3--N and NO2--N were studied. The adsorption processes of NH4+-N and NO3--N were fitted by Langmuir and Freundlich isothermal adsorption models, and the adsorption mechanisms were also elucidated. The results showed that the maize straw- and corn cob-derived biochars produced at 400℃ and 600℃ were both alkaline (400℃<600℃).As for the same raw material, the biochar produced at 600℃ showed relatively higher alkaline oxygen-containing functional group content and lower acidic oxygen-containing functional group content compared with the biochar produced at 400℃. The biochars produced at 400
NONLINEAR WAVES AND PERIODIC SOLUTION IN FINITE DEFORMATION ELASTIC ROD
Institute of Scientific and Technical Information of China (English)
Liu Zhifang; Zhang Shanyuan
2006-01-01
A nonlinear wave equation of elastic rod taking account of finite deformation, transverse inertia and shearing strain is derived by means of the Hamilton principle in this paper. Nonlinear wave equation and truncated nonlinear wave equation are solved by the Jacobi elliptic sine function expansion and the third kind of Jacobi elliptic function expansion method. The exact periodic solutions of these nonlinear equations are obtained, including the shock wave solution and the solitary wave solution. The necessary condition of exact periodic solutions, shock solution and solitary solution existence is discussed.
Constrained Solutions of a System of Matrix Equations
Directory of Open Access Journals (Sweden)
Qing-Wen Wang
2012-01-01
Full Text Available We derive the necessary and sufficient conditions of and the expressions for the orthogonal solutions, the symmetric orthogonal solutions, and the skew-symmetric orthogonal solutions of the system of matrix equations AX=B and XC=D, respectively. When the matrix equations are not consistent, the least squares symmetric orthogonal solutions and the least squares skew-symmetric orthogonal solutions are respectively given. As an auxiliary, an algorithm is provided to compute the least squares symmetric orthogonal solutions, and meanwhile an example is presented to show that it is reasonable.
2013-05-29
... derivatives transactions independently. \\9\\ 77 FR 5416 (Feb. 3, 2012). Question One. The Board asked if NCUA.... Conduct: Collateral Accounting reporting......... management. Counterparty exposure Transaction management... permitted under applicable state law to engage in derivatives transactions. It requires any credit...
Ji-Huan He
2011-01-01
A new fractal derive is defined, which is very easy for engineering applications to discontinuous problems, two simple examples are given to elucidate to establish governing equations with fractal derive and how to solve such equations, respectively.
Konopelchenko-Dubrovsky方程的周期解%Periodic Wave Solutions for Konopelchenko-Dubrovsky Equation
Institute of Scientific and Technical Information of China (English)
张金良; 张令元; 王明亮
2005-01-01
By using F-expansion method proposed recently, we derive the periodic wave solution expressed by Jacobi elliptic functions for Konopelchenko-Dubrovsky equation. In the limit case, the solitary wave solution and other type of the traveling wave solutions are derived.
Synthesis of isothiocyanate-derived mercapturic acids
Vermeulen, M.; Zwanenburg, B.; Chittenden, G.J.F.; Verhagen, H.
2003-01-01
Twelve mercapturic acids derived from saturated and unsaturated aliphatic and aromatic isothiocyanates were synthesised, by adding isothiocyanate to a solution of N-acetyl-L-cysteine and sodium bicarbonate, in a typical yield of 77%. Isothiocyanates were synthesised first by adding the corresponding
Solutions of the Bohr hamiltonian, a compendium
Fortunato, L
2004-01-01
The Bohr hamiltonian, also called collective hamiltonian, is one of the cornerstone of nuclear physics and a wealth of solutions (analytic or approximated) of the associated eigenvalue equation have been proposed over more than half a century (confining ourselves to the quadrupole degree of freedom). Each particular solution is associated with a peculiar form for the $V(\\beta,\\gamma)$ potential. The large number and the different details of the mathematical derivation of these solutions, as well as their increased and renewed importance for nuclear structure and spectroscopy, demand a thorough discussion. It is the aim of the present monograph to present in detail all the known solutions in $\\gamma-$unstable and $\\gamma-$stable cases, in a taxonomic and didactical way. In pursuing this task we especially stressed the mathematical side leaving the discussion of the physics to already published comprehensive material. The paper contains also a new approximate solution for the linear potential, and a new solutio...
Cosmological Solutions of $f(T)$ Gravity
Paliathanasis, Andronikos; Leach, P G L
2016-01-01
In the cosmological scenario in $f\\left( T\\right) $ gravity, we find analytical solutions for an isotropic and homogeneous universe containing a dust fluid and radiation and for an empty anisotropic Bianchi I universe. The method that we apply is that of movable singularities of differential equations. For the isotropic universe, the solutions are expressed in terms of a Laurent expansion, while for the anisotropic universe we find a family of exact Kasner-like solutions in vacuum. Finally, we discuss when a nonlinear $f\\left( T\\right) $-gravity theory provides solutions for the teleparallel equivalence of general relativity and derive conditions for exact solutions of general relativity to solve the field equations of an $f(T)$ theory.
Institute of Scientific and Technical Information of China (English)
李志刚; 贲亮; 韩宇; 毕薇薇
2015-01-01
背景：干细胞制备完成后的放置时间与其存活率的关系是临床应用安全、有效的基础。目的：观察不同保存液及不同保存时间对脐带源间充质干细胞存活率的影响，为干细胞有效期的确定提供重要依据。方法：选用脐带源间充质干细胞制备干细胞制剂，分别采用生理盐水、培养基、培养基+生理盐水、生理盐水含表皮生长因子、培养基含低分子肝素钙悬浮保存。使用冷藏箱模拟细胞运输条件，分别在第0，6，12，18，24，30，36，42，48小时取样，进行细胞总数和细胞活率的检测。结果与结论：各组在24 h内的细胞数量和细胞活率差别不大。24 h后，培养基组和培养基含低分子肝素钙组的细胞总数和细胞活率优于生理盐水含因子组、生理盐水组、培养基+生理盐水组。干细胞制剂制备完成后，冷藏运输24 h内细胞活率可达90%以上，保存液中的营养成分及合适的pH值，可使细胞活率显著提高。%BACKGROUND:The relationship between placing time after stem cel preparation and cel survival is the basis of safety and effectiveness for the clinical application. OBJECTIVE: To observe effects of different preservation solutions and different storage time on survival rate of umbilical cord-derived mesenchymal stem cels, and to provide important evidence for identifying effectiveness of stem cels. METHODS:Umbilical cord-derived mesenchymal stem cels were selected to prepare stem cel preparation, which was preserved in physiological saline, medium, medium+physiological saline, physiological saline containing epidermal growth factor, and medium containing low molecular heparin calcium suspension. Cold closet was selected for imitating celular transport conditions. Samples were obtained at 0, 6, 12, 18, 24, 30, 36, 42 and 48 hours. Total cel number and cel survival rate were detected. RESULTS AND CONCLUSION:The difference in cel number and
Dixon, R. M. W.
2008-01-01
Phonological and semantic principles which underlie the derivation of verbs from nouns and adjectives in English are examined. There is intricate phonological conditioning for suffix "-ize" and for suffix "-(i)fy"; a third major process is zero derivation. These derivational processes cover more than a score of semantic relations (some with…
Frankenstein's glue: transition functions for approximate solutions
Yunes, Nicolás
2007-09-01
Approximations are commonly employed to find approximate solutions to the Einstein equations. These solutions, however, are usually only valid in some specific spacetime region. A global solution can be constructed by gluing approximate solutions together, but this procedure is difficult because discontinuities can arise, leading to large violations of the Einstein equations. In this paper, we provide an attempt to formalize this gluing scheme by studying transition functions that join approximate analytic solutions together. In particular, we propose certain sufficient conditions on these functions and prove that these conditions guarantee that the joined solution still satisfies the Einstein equations analytically to the same order as the approximate ones. An example is also provided for a binary system of non-spinning black holes, where the approximate solutions are taken to be given by a post-Newtonian expansion and a perturbed Schwarzschild solution. For this specific case, we show that if the transition functions satisfy the proposed conditions, then the joined solution does not contain any violations to the Einstein equations larger than those already inherent in the approximations. We further show that if these functions violate the proposed conditions, then the matter content of the spacetime is modified by the introduction of a matter shell, whose stress energy tensor depends on derivatives of these functions.
Stable solutions for a catalytic converter
Energy Technology Data Exchange (ETDEWEB)
Byrne, H.; Norbury, J. (Univ. of Oxford (United Kingdom). Mathematical Inst.)
1994-06-01
A coupled system of partial differential equations that describes the evolution of solid and gas temperatures and gas concentration inside a catalytic converter is derived and examined. The use of a reaction term, which is a discontinuous function of the solid temperature and gas concentration, implies that two types of nontrivial solutions may occur. These are characterized by the manner in which the reaction switches off: either the solid temperature becomes too low (U-solutions) or the gaseous concentration is exhausted (G-solutions). This reaction term differs from the usual combustion term because the reaction is modeled as two-stage, with the large activation-energy limit then justifying the step-function approach adopted. First, steady solutions for which the gas and solid are in thermal equilibrium are studied, and a constraint relating the system's parameters is derived as a necessary condition for the existence of such solutions. Explicit solutions are presented for a particular class of reaction rates, with a linear stability analysis of one case indicating that G-solutions are stable while U-solutions are not. Steady solutions for which the solid and gas are no longer in thermal equilibrium are then considered. For a particular asymptotic limit (and choice of the reaction term), the construction of asymptotic power series expansions shows that the gas temperature exceeds the solid temperature at all points inside the converter. The analysis indicates that separate treatment of the solid and gaseous temperatures has no effect on the qualitative nature of the steady solutions, that is, their existence, stability, and parameter dependence.
Contact Lens Solution Toxicity
... rash and rashes clinical tools newsletter | contact Share | Contact Lens Solution Toxicity Information for adults A A A This image shows a reaction to contact lens solution. The prominent blood vessels and redness ...
Axisymmetric fundamental solutions for a finite layer with impeded boundaries
Institute of Scientific and Technical Information of China (English)
程泽海; 陈云敏; 凌道盛; 唐晓武
2003-01-01
Axisymmetrie fundamental solutions that are applied in the consolidation calculations of a finite clay layer with impeded boundaries were derived. Laplace and Hankel integral transforms were utilized with respect to time and radial coordinates, respectively in the analysis. The derivation of fundamental solutions considers two boundary-value problems involving unit point loading and ring loading in the vertical. The solut-ions are extended to circular distributed and strip distributed normal load. The computation and analysis of set-tlements, vertical total stress and excess pore pressure in the consolidation layer subject to circular loading are presented.
International Nuclear Information System (INIS)
This Functional Design Criteria (FDC) addresses remediation of the plutonium-bearing solutions currently in inventory at the Plutonium Finishing Plant (PFP). The recommendation from the Environmental Impact Statement (EIS) is that the solutions be treated thermally and stabilized as a solid for long term storage. For solutions which are not discardable, the baseline plan is to utilize a denitration process to stabilize the solutions prior to packaging for storage
Unsteady Stokes Equations: Some Complete General Solutions
Indian Academy of Sciences (India)
A Venkatlaxmi; B S Padmavathi; T Amaranath
2004-05-01
The completeness of solutions of homogeneous as well as non-homogeneous unsteady Stokes equations are examined. A necessary and sufficient condition for a divergence-free vector to represent the velocity field of a possible unsteady Stokes flow in the absence of body forces is derived.
Schwarzschild solution in extended teleparallel gravity
Nashed, G G L
2015-01-01
Tetrad field, with two unknown functions of radial coordinate and an angle $\\Phi$ which is the polar angle $\\phi$ times a function of the redial coordinate, is applied to the field equation of modified theory of gravity. Exact vacuum solution is derived whose scalar torsion, $T ={T^\\alpha}_{\\mu \
Analytic Solutions of Elastic Tunneling Problems
Strack, O.E.
2002-01-01
The complex variable method for solving two dimensional linearly elastic problems is used to obtain several fundamental analytical solutions of tunneling problems. The method is used to derive the general mathematical representation of problems involving resultant forces on holes in a half-plane
Weak Dynamic Programming Principle for Viscosity Solutions
Bouchard, Bruno; Touzi, Nizar
2011-01-01
We prove a weak version of the dynamic programming principle for standard stochastic control problems and mixed control-stopping problems, which avoids the technical difficulties related to the measurable selection argument. In the Markov case, our result is tailor-maid for the derivation of the dynamic programming equation in the sense of viscosity solutions.
Generalized \\delta-Derivations
Kaygorodov, Ivan
2011-01-01
We defined generalized \\delta-derivations of algebra A as linear mapping \\chi associated with usual \\delta-derivation \\phi by the rule \\chi(xy)=\\delta(\\chi(x)y+x\\phi(y))=\\delta(\\phi(x)y+x\\chi(y)) for any x,y \\in A. We described generalized \\delta-derivations of prime alternative algebras, prime Lie algebras and superalgebras, unital algebras, and semisimple finite-dimensional Jordan superalgebras. In this cases we proved that generalized \\delta-derivation is a generalized derivation or \\delta...
Direct Density Derivative Estimation.
Sasaki, Hiroaki; Noh, Yung-Kyun; Niu, Gang; Sugiyama, Masashi
2016-06-01
Estimating the derivatives of probability density functions is an essential step in statistical data analysis. A naive approach to estimate the derivatives is to first perform density estimation and then compute its derivatives. However, this approach can be unreliable because a good density estimator does not necessarily mean a good density derivative estimator. To cope with this problem, in this letter, we propose a novel method that directly estimates density derivatives without going through density estimation. The proposed method provides computationally efficient estimation for the derivatives of any order on multidimensional data with a hyperparameter tuning method and achieves the optimal parametric convergence rate. We further discuss an extension of the proposed method by applying regularized multitask learning and a general framework for density derivative estimation based on Bregman divergences. Applications of the proposed method to nonparametric Kullback-Leibler divergence approximation and bandwidth matrix selection in kernel density estimation are also explored. PMID:27140943
Existence of Minimizers for Fractional Variational Problems Containing Caputo Derivatives
Bourdin, Loïc; Odzijewicz, Tatiana; Delfim F. M. Torres
2012-01-01
International audience We study dynamic minimization problems of the calculus of variations with Lagrangian functionals containing Riemann–Liouville fractional integrals, classical and Caputo fractional derivatives. Under assumptions of regularity, coercivity and convexity, we prove existence of solutions.
An Interacting Dark Energy Model with Nonminimal Derivative Coupling
Nozari, Kourosh
2016-01-01
We study cosmological dynamics of an extended gravitational theory that gravity is coupled non-minimally with derivatives of a dark energy component and there is also a phenomenological interaction between the dark energy and dark matter. Depending on the direction of energy flow between the dark sectors, the phenomenological interaction gets two different signs. We show that this feature affects the existence of attractor solution, the rate of growth of perturbations and stability of the solutions. By considering an exponential potential as a self-interaction potential of the scalar field, we obtain accelerated scaling solutions that are attractors and have the potential to alleviate the coincidence problem. While in the absence of the nonminimal derivative coupling there is no attractor solution for phantom field when energy transfers from dark matter to dark energy, we show an attractor solution exists if one considers an explicit nonminimal derivative coupling for phantom field in this case of energy tran...
POSITIVE SOLUTIONS TO A SEMIPOSITONE SINGULAR NEUMANN BOUNDARY VALUE PROBLEM
Institute of Scientific and Technical Information of China (English)
无
2009-01-01
A semipositone singular boundary value problem (BVP for short) is discussed in this paper. By Krasnaselskii's fixed point theorem in cones,we derive suffcient conditions,which guarantee that the semipositone BVP has at least one positive solution.
D'Ovidio, Mirko
2012-01-01
We consider fractional directional derivatives and establish some connection with stable densities. Solutions to advection equations involving fractional directional derivatives are presented and some properties investigated. In particular we obtain solutions written in terms of Wright functions by exploiting operational rules involving the shift operator. We also consider fractional advection diffusion equations involving fractional powers of the negative Laplace operator and directional derivatives of fractional order and discuss the probabilistic interpretations of solutions.
Proteins in solution: Fractal surfaces in solutions
Directory of Open Access Journals (Sweden)
R. Tscheliessnig
2016-02-01
Full Text Available The concept of the surface of a protein in solution, as well of the interface between protein and 'bulk solution', is introduced. The experimental technique of small angle X-ray and neutron scattering is introduced and described briefly. Molecular dynamics simulation, as an appropriate computational tool for studying the hydration shell of proteins, is also discussed. The concept of protein surfaces with fractal dimensions is elaborated. We finish by exposing an experimental (using small angle X-ray scattering and a computer simulation case study, which are meant as demonstrations of the possibilities we have at hand for investigating the delicate interfaces that connect (and divide protein molecules and the neighboring electrolyte solution.
Rainfall interstation correlation functions derived for a class of generalized storm models
Stol, P.T.
1983-01-01
The complete derivation and solution of the rainfall interstation correlation function is described. The report emphasizes the mathematical treatment and the way in which the analytical solution can be obtained by calculus
Solution to manufacturing execution system; MES solution
Energy Technology Data Exchange (ETDEWEB)
Oikawa, H.; Kato, T.; Tanaka, M. [Fuji Electric Co. Ltd., Tokyo (Japan)
2000-05-10
In structuring supply chain management (SCM) in the manufacturing industry, the role of the manufacturing execution system (MES) is very important. In the region of SCM and enterprise resource planning (ERP), even if an optimum system is planned and supply chain planning (SCP) software is actually introduced, only a limited SCM effect can be expected. Fuji Electric has integrated long-cultivated manufacturing know-how into the solution to the MES with an intention to structure manufacturing-field-oriented SCM by linking solutions to SCM, ERP and logistics. (author)
Approximate solutions for fractured wells producing layered reservoirs
Energy Technology Data Exchange (ETDEWEB)
Bennett, C.O.; Camacho-V., R; Raghavan, R.; Reynolds, A.C.
1985-10-01
New analytical solutions for the response at a well intercepting a layered reservoir are derived. The well is assumed to produce at a constant rate or a constant pressure. We examine reservoir systems without interlayer communication and document the usefulness of these solutions, which enable us to obtain increased physical understanding of the performance of fractured wells in layered reservoirs. The influence of vertical variations in fracture conductivity is also considered. Example applications of the approximations derived here are also presented.
Molecular Thermodynamic Modeling of Fluctuation Solution Theory Properties
DEFF Research Database (Denmark)
O’Connell, John P.; Abildskov, Jens
2013-01-01
Fluctuation Solution Theory provides relationships between integrals of the molecular pair total and direct correlation functions and the pressure derivative of solution density, partial molar volumes, and composition derivatives of activity coefficients. For dense fluids, the integrals follow...... a relatively simple corresponding-states behavior even for complex systems, show welldefined relationships for infinite dilution properties in complex and near-critical systems, allow estimation of mixed-solvent solubilities of gases and pharmaceuticals, and can be expressed by simple perturbation models...
BIFURCATIONS OF TRAVELLING WAVE SOLUTIONS TO A COUPLED NONLINEAR WAVE SYSTEM
Institute of Scientific and Technical Information of China (English)
无
2008-01-01
Employ theory of bifurcations of dynamical systems to a system of coupled nonlin-ear equations, the existence of solitary wave solutions, kink wave solutions, anti-kink wave solutions and periodic wave solutions is obtained. Under different parametric conditions, various suffcient conditions to guarantee the existence of the above so-lutions are given. Some exact explicit parametric representations of travelling wave solutions are derived.
Fractional Derivative and Integral
Aygören, Aysel
2014-01-01
ABSTRACT: In this thesis we studied fractional order derivative and integral. In Chapter1, a brief history on the foundation of fractional derivative and integration has been given. In the second chapter, some definitions and theorems have been provided. Also some needed special functions such as Gamma, Beta, Mittag-Leffler and Wright function have taken place in this chapter. Properties of fractional derivative and integral are discussed in Chapter 3. We started to this chapter by the dis...
Developing a derivatives generator
Directory of Open Access Journals (Sweden)
Mircea Petic
2016-01-01
Full Text Available The article intends to highlight the particularities of the derivational morphology mechanisms that will help in lexical resources extension. Some computing approaches for derivational morphology are given for several languages, inclusively for Romanian. This paper deals with some preprocessing particularities, that are needed in the process of automatic generation. Then, generative mechanisms are presented in the form of derivational formal rules separately for prefixation and suffixation. The article ends with several approaches in automatic new generated words validation.
Duer, W. C.; And Others
1977-01-01
Discusses comparisons of packing densities derived from known molar volume data of liquids and solutions. Suggests further studies for using assemblies of spheres as models for simple liquids and solutions. (MLH)
Langmuir-Blodgett Films of Graphene Derivatives
DEFF Research Database (Denmark)
Petersen, Søren Vermehren
The work presented in this PhD thesis can be divided into two main categories: 1) Syn-thesis and Langmuir-Blodgett assembly of graphene derivatives and 2) Application and characterization of graphene derivatives as an interface material in molecular electron-ics. While the first category could...... be divided further, the synthesis and Langmuir-Blodgett results are intertwined in such a way that it would be more confusing to pre-sent them separately. The Langmuir-Blodgett deposition also played a crucial, but more isolated, part in the investigation of graphene derivatives as interface material....... Solution processable graphene in the form of chemically derived graphene has been synthesized through the modified Hummers method with subsequent reduction into reduced graphene oxide with hydrazine. The completeness of oxidation, the effect of the refinement steps and the reduction of the graphene oxide...
Approximate analytical solutions to the condensation-coagulation equation of aerosols
DEFF Research Database (Denmark)
Smith, Naftali R.; Shaviv, Nir J.; Svensmark, Henrik
2016-01-01
We present analytical solutions to the steady state nucleation-condensation-coagulation equation of aerosols in the atmosphere. These solutions are appropriate under different limits but more general than previously derived analytical solutions. For example, we provide an analytic solution to the...... of sulfuric acid....
Exact Solutions for a Higher-Order Nonlinear Schr(o)dinger Equation in Atmospheric Dynamics
Institute of Scientific and Technical Information of China (English)
无
2006-01-01
By giving prior assumptions on the form of the solutions, we succeed to find several exact solutions for a higher-order nonlinear Schrodinger equation derived from one important model in the study of atmospheric and ocean dynamical systems. Our analytical solutions include bright and dark solitary waves, and periodical solutions, which can be used to explain atmospheric phenomena.
Solutions to Organizational Paradox
DEFF Research Database (Denmark)
Li, Xin; Worm, Verner; Peihong, Xie
Organizations face all kinds of paradoxical problems. There exist various solutions to organizational paradoxes. We develop a typology that lists nine possible logical approaches to understanding the relationship between paradoxical opposites, out of which we identify five types of solutions...... to organizational paradox. Four of the five solutions are explicitly associated with four prominent philosophies. We show the relevance of the five solutions to the real world by applying our scheme to understand different solutions to the generic strategy paradox. Finally, we address the question whether...... there is a superior solution and point out the paradox of paradox resolving, namely, paradoxes cannot be resolved once for all and we have to live with them....
Institute of Scientific and Technical Information of China (English)
周凤麟; 徐洪焱
2012-01-01
This paper investigates the properties of the fixed-point of solution f(≠ 0) and its derivative f(I)(I = 1,2, · · ·) of higher order linear differential equationf(k) + Ak-1 (z)f(k-1) + · · · + A1(z)f' + A0(z)f = 0where Aj(z)(J = 0,1, · · · , k - 1) are meromorphic functions. And we obtain λP+1(f -z) = λP+1(f' -z) = λP+1(f" -z) = σp+1(f) ≥ σp(A0)when δ(∞,B) > 0, and max{I(A1),I(A2),· · · ,I(Ak-1)} < I{A0) = p or I(Aj) = p,0 < max{σp(A1),σp(A2),· · · ,σp(Ak-1)} < σp(A0) < ∞, p ∈N+ := N\\{0}. The theorems of this paper improve the previous results given by Chen, Belaidi.%研究了高阶线性微分方程f(k)+Ak-1(z)f(k-1)+…+A1(z)f′+A0(z)f=0的非零解f,及其一阶、二阶导数f(i)(i=1,2)的不动点性质,这里Aj(z)(j=0,1,…,k-1)为亚纯函数,得到了若δ(∞,A0)＞0,且满足max{i(A1),i(A2),…,i(Ak-1)}＜i(A0)=p或者i(Aj)=p,0＜max{σp(A1),σp(A2),…,σp(Ak-1)｝＜σp(A0)＜∞有(-λ)p+1(f-z).=(-λ)p+1(f〃-z)=(λ)p+1(f″-z)=σp+1(f)≥σp(A0)其中p∈N+∶=N\\{0}.所得结果改进了陈宗煊,Bela(i)di等人的结果.
Computational Derivation to Zeta Zeros and Prime Numbers
Chalmers, Gordon
2005-01-01
A route to the derivation of the numbers $s$ to the transcendental equation $\\zeta(s)=0$ is presented. The solutions to this equation require the solving of a geodesic flow in an infinite dimensional manifold. These solutions enable one approach to a formula generating the prime numbers.
Charged Vaidya Solution Satisfies Weak Energy Condition
Chatterjee, Soumyabrata; Virmani, Amitabh
2015-01-01
The external matter stress-tensor supporting charged Vaidya solution appears to violate weak energy condition in certain region of the spacetime. Motivated by this, a new interpretation of charged Vaidya solution was proposed by Ori [1] in which the energy condition continues to be satisfied. In this construction, one glues an outgoing Vaidya solution to the original ingoing Vaidya solution provided the surface where the external stress-tensor vanishes is spacelike. We revisit this study and extend it to higher-dimensions, to AdS settings, and to higher-derivative f(R) theories. In asymptotically flat space context, we explore in detail the case when the mass function m(v) is proportional to the charge function q(v). When the proportionality constant \
Solution of linear systems by a singular perturbation technique
Ardema, M. D.
1976-01-01
An approximate solution is obtained for a singularly perturbed system of initial valued, time invariant, linear differential equations with multiple boundary layers. Conditions are stated under which the approximate solution converges uniformly to the exact solution as the perturbation parameter tends to zero. The solution is obtained by the method of matched asymptotic expansions. Use of the results for obtaining approximate solutions of general linear systems is discussed. An example is considered to illustrate the method and it is shown that the formulas derived give a readily computed uniform approximation.
Exact Solutions on the Oscillating Plate of Maxwell Fluids
Directory of Open Access Journals (Sweden)
Kashif Ali Abro
2016-01-01
Full Text Available This work is related to establish the exact solutions of sine hyperbolic and cosine hyperbolic oscillations of Maxwell fluid over the velocity field and shear stress. Under the effects of sine hyperbolic and cosine hyperbolic oscillations, the general solutions are derived for the motions of incompressible Maxwell fluid. For the sack of the general solutions the mathematical techniques of integral transformations (Laplace and Fourier Sine transforms are applied. We have expressed the obtained solutions under form of theorem of convolutions product and integral notation, satisfying the boundary and initial conditions. The expressions for similar solutions are specialized as a limiting case of Newtonian fluid.
An Algebraic Solution for the Kermack-McKendrick Model
Carvalho, Alexsandro M
2016-01-01
We present an algebraic solution for the Susceptible-Infective-Removed (SIR) model originally presented by Kermack-McKendrick in 1927. Starting from the differential equation for the removed subjects presented by them in the original paper, we re-write it in a slightly different form in order to derive formally the solution, unless one integration. Then, using algebraic techniques and some well justified numerical assumptions we obtain an analytic solution for the integral. Finally, we compare the numerical solution of the differential equations of the SIR model with the analytically solution here proposed, showing an excellent agreement.
Cosmological Models with Fractional Derivatives and Fractional Action Functional
Institute of Scientific and Technical Information of China (English)
V.K. Shchigolev
2011-01-01
Cosmological models of a scalar field with dynamical equations containing fractional derivatives or derived from the Einstein-Hilbert action of fractional order, are constructed. A number of exact solutions to those equations of fractional cosmological models in both eases is given.
On the minimal speed and asymptotics of the wave solutions for the lotka volterra system
Hou, Xiaojie
2010-01-01
e study the minimal wave speed and the asymptotics of the traveling wave solutions of a competitive Lotka Volterra system. The existence of the traveling wave solutions is derived by monotone iteration. The asymptotic behaviors of the wave solutions are derived by comparison argument and the exponential dichotomy, which seems to be the key to understand the geometry and the stability of the wave solutions. Also the uniqueness and the monotonicity of the waves are investigated via a generalized sliding domain method.
Analytical Solution of the Time Fractional Fokker-Planck Equation
Directory of Open Access Journals (Sweden)
Sutradhar T.
2014-05-01
Full Text Available A nonperturbative approximate analytic solution is derived for the time fractional Fokker-Planck (F-P equation by using Adomian’s Decomposition Method (ADM. The solution is expressed in terms of Mittag- Leffler function. The present method performs extremely well in terms of accuracy, efficiency and simplicity.
Exact cosmological solutions of scale-invariant gravity theories
Barrow, J D; Barrow, John D.
2006-01-01
We have found new anisotropic vacuum solutions for the scale-invariant gravity theories which generalise Einstein's general relativity to a theory derived from the Lagrangian $R^{1+\\delta}$. These solutions are expanding universes of Kasner form with an initial spacetime singularity at $t=0 $ and exist for $-1/20$.
Approximate solution of the pairing Hamiltonian in the Berggren basis
Mercenne, A; Ploszajczak, M
2015-01-01
We derive the approximate solution for the pairing Hamiltonian in the Berggren ensemble of single particle states including bound, resonance and non-resonant scattering states. We show that this solution is reliable in the limit of a weak pairing interaction.
Blumenstyk, Goldie
1994-01-01
Heavy investment in derivatives, whose value derives from the price movement of some underlying security, has meant heavy losses for some colleges and universities despite the fact that institutional investors are required to assure that they understand the risks of such investment. (MSE)
Financial Derivatives in China
Institute of Scientific and Technical Information of China (English)
无
2006-01-01
Francis Repka sees bright prospects for the future development of the financial derivatives market in China. Repka,Vice President of the Asian Bond Finance Department of Societe Generale, says the situation in France just after the birth of derivatives was very similar to the situation in China today.
DEFF Research Database (Denmark)
Singh, Shailja; Agarwal, Drishti; Sharma, Kumkum;
2016-01-01
Synthetic quinoline derivatives continue to be considered as candidates for new drug discovery if they act against CQ-resistant strains of malaria even after the widespread emergence of resistance to CQ. In this study, we explored the activities of two series of new 4-aminoquinoline derivatives...
Numerical Integration with Derivatives
Institute of Scientific and Technical Information of China (English)
Hu Cheng
2006-01-01
A new formula with derivatives for numerical integration was presented. Based on this formula and the Richardson extrapolation process, a numerical integration method was established. It can converge faster than the Romberg's. With the same accuracy, the computation of the new numerical integration with derivatives is only half of that of Romberg's numerical integration.
Determination of Ascorbic Acid in Vegetables by Derivative Spectrophotometry
Aydoğmuş, Zeynep; ÇETİN, Sevil Müge
2002-01-01
Determination of ascorbic acid (AA) in garlic, green pepper and chestnut was performed by derivative spectrophotometry without using any pre-separation or background correction techniques. The method is based on the measurement of the distances between two extremum values (peak-to-peak amplitudes) in second and third order derivative spectra of the extracts. Ten percent trichloroacetic acid was found to be the most suitable extraction solution. In the second order derivative spectru...
The Adsorption Effect of Quaternized Chitosan Derivatives on Bile Acid
Institute of Scientific and Technical Information of China (English)
Shu Xian MENG; Ya Qing FENG; Wen Jin LI; Cai Xia YIN; Jin Ping DENG
2006-01-01
Three quaternized chitosan derivatives were synthesized and their adsorption performance of bile acid from aqueous solution was studied. The adsorption capacities and rates of bile acid onto quaternized chitosan derivatives were evaluated. The kinetic experimental data properly correlated with the second-order kinetic model, which indicated that the chemical sorption is the rate-limiting step. The results showed that the quaternized chitosan derivatives are favorable adsorbents for bile acid.
DEFF Research Database (Denmark)
Dyppel, Katja Joo
2013-01-01
in the Danish tax legislation. However, contracts known as forwards (terminskontrakter) and options (aftaler om køberetter og salgsretter) are generally included in the term financials contracts covered by the Danish Act on Taxation of Gains and Losses on Claims and Debt. The main part of the analysis deals...... with the scope of sections 29-33 of the Danish Act on Taxation of Gains and Losses on Claims and Debt and the tax consequences for the covered financial contracts. In the analysis of taxation of derivatives, the fundamental issues of qualification and tax treatment of the instruments are dealt with.......The main objective for this thesis is to analyse and systematise the Danish legislation on taxation of derivatives. According to financial terminology, a derivative is a financial instrument. Its value is derived from changes in the value of one or more underlying assets.The most common derivatives...
DEFF Research Database (Denmark)
Larsen, Niels Vesterdal; Breinbjerg, Olav
2004-01-01
To facilitate the validation of the numerical Method of Auxiliary Sources an analytical Method of Auxiliary Sources solution is derived in this paper. The Analytical solution is valid for transverse magnetic, and electric, plane wave scattering by circular impedance Cylinders, and it is derived...
Numerical integration of asymptotic solutions of ordinary differential equations
Thurston, Gaylen A.
1989-01-01
Classical asymptotic analysis of ordinary differential equations derives approximate solutions that are numerically stable. However, the analysis also leads to tedious expansions in powers of the relevant parameter for a particular problem. The expansions are replaced with integrals that can be evaluated by numerical integration. The resulting numerical solutions retain the linear independence that is the main advantage of asymptotic solutions. Examples, including the Falkner-Skan equation from laminar boundary layer theory, illustrate the method of asymptotic analysis with numerical integration.
Approximate solutions for fractured wells producing layered reservoirs
Energy Technology Data Exchange (ETDEWEB)
Bennett, C.O.; Reynolds, A.C.; Raghavan, R.
1983-01-01
New analytical solutions for the response at a well intercepting a layered reservoir are derived. The well is assumed to produce at a constant rate or at a constant pressure. Reservoir systems with and without interlayer communication were examined. The utility of these solutions is documented. An increased physical understanding of fractured wells in layered reservoirs was obtained from these solutions. The influence of vertical variations in fracture conductivity is considered also. 15 references.
General static spherically symmetric solutions in Horava gravity
Capasso, Dario
2009-01-01
We derive general static spherically symmetric solutions in the Horava theory of gravity with nonzero shift field. These represent "hedgehog" versions of black holes with radial "hair" arising from the shift field. For the case of the standard de Witt kinetic term (lambda =1) there is an infinity of solutions that exhibit a deformed version of reparametrization invariance away from the general relativistic limit. Special solutions also arise in the anisotropic conformal point lambda = 1/3.
New Rational Form Solutions to mKdV Equation
Institute of Scientific and Technical Information of China (English)
FU Zun-Tao; LIU Shi-Kuo; LIU Shi-Da
2005-01-01
In this paper, new basic functions, which are composed of three basic Jacobi elliptic functions, are chosen as components of finite expansion. This finite expansion can be taken as an ansatz and applied to solve nonlinear wave equations. As an example, mKdV equation is solved, and more new rational form solutions are derived, such as periodic solutions of rational form, solitary wave solutions of rational form, and so on.
Multiple optimal solutions to a sort of nonlinear optimization problem
Institute of Scientific and Technical Information of China (English)
Xue Shengjia
2007-01-01
The optimization problem is considered in which the objective function is pseudolinear(both pseudoconvex and pseudoconcave) and the constraints are linear. The general expression for the optimal solutions to the problem is derived with the representation theorem of polyhedral sets, and the uniqueness condition of the optimal solution and the computational procedures to determine all optimal solutions ( ifthe uniqueness condition is not satisfied ) are provided. Finally, an illustrative example is also given.
A 'simple' hybrid model for power derivatives
International Nuclear Information System (INIS)
This paper presents a method for valuing power derivatives using a supply-demand approach. Our method extends work in the field by incorporating randomness into the base load portion of the supply stack function and equating it with a noisy demand process. We obtain closed form solutions for European option prices written on average spot prices considering two different supply models: a mean-reverting model and a Markov chain model. The results are extensions of the classic Black-Scholes equation. The model provides a relatively simple approach to describe the complicated price behaviour observed in electricity spot markets and also allows for computationally efficient derivatives pricing. (author)
Haas, C; Drenth, J; Wilson, WW
1999-01-01
Tn recent publications it was pointed out that there is a correlation between the observed values of the solubility of proteins in aqueous solutions and the second virial coefficient of the solution. In this paper we give a theoretical explanation of this relation. The derived theoretical expression
Institute of Scientific and Technical Information of China (English)
Li Mo; Fei Yuan; Jian Yang
2011-01-01
In this paper, we give an overview of mobile backhaul solutions and propose an MPLS-centered solution that takes intoaccount timing synchronization, OAM, and protection： We also propose an evolved protection bandwidth allocation mechanism that makes the transport network as efficient as possible.
Another exact inflationary solution
Kruger, A T; Kruger, Adam T.; Norbury, John W.
2000-01-01
A new closed-form inflationary solution is given for a hyperbolic interaction potential. The method used to arrive at this solution is outlined as it appears possible to generate additional sets of equations which satisfy the model. In addition a new form of decaying cosmological constant is presented.
Solution structure of (+)-discodermolide.
Smith, A B; LaMarche, M J; Falcone-Hindley, M
2001-03-01
[structure: see text]. The solution structure of (+)-discodermolide (1) has been determined via 1- and 2-D NMR techniques in conjunction with Monte Carlo conformational analysis. Taken together, the results demonstrate that in solution (+)-discodermolide occupies a helical conformation remarkably similar to the solid state conformation.
Heat-regulated foaming in surfactant solutions
Energy Technology Data Exchange (ETDEWEB)
Pletnev, M.Y.; Eremina, L.D.; Vlasenko, I.G.
1984-01-01
This article examines the mechanism of the foam-inhibiting action resulting from the use of propylene oxide derivatives in solutions both of anionic and of nonionic surfactants. The objective is the creation of a detergent composition with heat-regulated foaming, which would foam well at 30-50/sup 0/ and poorly at 80-90/sup 0/, which is the usual temperature of washing machines. It is demonstrated that foaming can be regulated by the variation of the cloud points of solutions with the aid of additions of polypropylene glycols and their alkyl derivatives or block copolymers in solutions of surfactants. Foaming and foam stability decrease sharply above the cloud points of the solutions due to the foam-inhibiting action of the coacervate phase on the coexisting foam-forming solution. The foam inhibition of polypropylene glycols increases and becomes apparent at lower concentrations with the increase of the average molecular weight of the hydrophobic blocks, the increase of their relative content (in block copolymers with oxyethylene groups), and upon the introduction of alkyl groups.
Neace, James C.
1986-01-01
Process for removing diluent degradation products from a solvent extraction solution, which has been used to recover uranium and plutonium from spent nuclear fuel. A wash solution and the solvent extraction solution are combined. The wash solution contains (a) water and (b) up to about, and including, 50 volume percent of at least one-polar water-miscible organic solvent based on the total volume of the water and the highly-polar organic solvent. The wash solution also preferably contains at least one inorganic salt. The diluent degradation products dissolve in the highly-polar organic solvent and the organic solvent extraction solvent do not dissolve in the highly-polar organic solvent. The highly-polar organic solvent and the extraction solvent are separated.
Fuzzy Symmetric Solutions of Fuzzy Matrix Equations
Xiaobin Guo; Dequan Shang
2012-01-01
The fuzzy symmetric solution of fuzzy matrix equation AX˜=B˜, in which A is a crisp m×m nonsingular matrix and B˜ is an m×n fuzzy numbers matrix with nonzero spreads, is investigated. The fuzzy matrix equation is converted to a fuzzy system of linear equations according to the Kronecker product of matrices. From solving the fuzzy linear system, three types of fuzzy symmetric solutions of the fuzzy matrix equation are derived. Finally, two examples are given to illustrate the proposed method....
Exact solutions for Weyl fermions with gravity
Energy Technology Data Exchange (ETDEWEB)
Cianci, Roberto; Fabbri, Luca; Vignolo, Stefano [Universita di Genova, DIME Sez. Metodi e Modelli Matematici, Genoa (Italy)
2015-10-15
We consider the single-handed spinor field in interaction with its own gravitational field described by the set of field equations given by the Weyl field equations written in terms of derivatives that are covariant with respect to the gravitational connection plus Einstein field equations soured with the energy tensor of the spinor: for the Weyl spinor and the ensuing spacetime of Weyl-Lewis-Papapetrou structure, we find all exact solutions. The obtained solution for the metric tensor is that of a PP-wave spacetime, while the spinor field is a flag-dipole. (orig.)
Generalization of the Randall-Sundrum solution
Kisselev, A. V.
2016-08-01
The generalization of the Randall-Sundrum solution for the warp factor exp [ σ (y) ] in the scenario with one extra coordinate y, non-factorizable space-time geometry and two branes is obtained. It is shown that the function obtained σ (y) is symmetric with respect to an interchange of two branes. It also obeys the orbifold symmetry y → - y and explicitly reproduces jumps of its derivative on both branes. This solution is defined by the Einstein-Hilbert's equations up to a constant C. It is demonstrated that different values of C result in theories with quite different spectra of the Kaluza-Klein gravitons.
Generating Solutions to the Einstein - Maxwell Equations
Contopoulos, I G; Kleidis, K; Papadopoulos, D B; Witten, L
2015-01-01
The Einstein-Maxwell (E-M) equations in a curved spacetime that admits at least one Killing vector are derived, from a Lagrangian density adapted to symmetries. In this context, an auxiliary space of potentials is introduced, in which, the set of potentials associated to an original (seed) solution of the E-M equations are transformed to a new set, either by continuous transformations or by discrete transformations. In this article, continuous transformations are considered. Accordingly, originating from the so-called $\\gamma_A$-metric, other exact solutions to the E-M equations are recovered and discussed.
Exact solutions for Weyl fermions with gravity
Cianci, Roberto; Vignolo, Stefano
2015-01-01
We consider the single-handed spinor field in interaction with its own gravitational field described by the set of field equations given by Weyl field equations written in terms of derivatives that are covariant with respect to the gravitational connection plus Einstein field equations soured with the energy tensor of the spinor: for the Weyl spinor and the ensuing spacetime of Weyl-Lewis-Papapetrou structure, we will find all exact solutions. The solutions are flag-dipole PP-waves in a VSI-spacetime, and some of their properties are discussed in view of future developments.
Horizon Supertranslation and Degenerate Black Hole Solution
Cai, Rong-Gen; Zhang, Yun-Long
2016-01-01
In this note we first review the degenerate vacua arising from the BMS symmetries. According to the discussion in [1] one can define BMS-analogous supertranslation and superrotation for spacetime with black hole in Gaussian null coordinates. In the leading and subleading orders of near horizon approximation, the infinitely degenerate black hole solutions are derived by considering Einstein equations with or without cosmological constant, and they are related to each other by the diffeomorphism generated by horizon supertranslation. Higher order results and degenerate Rindler horizon solutions also are given in appendices.
Multivariate statistics exercises and solutions
Härdle, Wolfgang Karl
2015-01-01
The authors present tools and concepts of multivariate data analysis by means of exercises and their solutions. The first part is devoted to graphical techniques. The second part deals with multivariate random variables and presents the derivation of estimators and tests for various practical situations. The last part introduces a wide variety of exercises in applied multivariate data analysis. The book demonstrates the application of simple calculus and basic multivariate methods in real life situations. It contains altogether more than 250 solved exercises which can assist a university teacher in setting up a modern multivariate analysis course. All computer-based exercises are available in the R language. All R codes and data sets may be downloaded via the quantlet download center www.quantlet.org or via the Springer webpage. For interactive display of low-dimensional projections of a multivariate data set, we recommend GGobi.
Axisymmetric fundamental solutions for a finite layer with impeded boundaries
Institute of Scientific and Technical Information of China (English)
程泽海; 陈云敏; 凌道盛; 唐晓武
2003-01-01
Axisymmetric fundamental solutions that are applied in the consolidation calculations of a finite clay layer with impeded boundaries were derived. Laplace and Hankel integral transforms were utilized with respect to time and radial coordinates, respectively in the analysis. The derivation of fundamental solutions considers two boundary-value problems involving unit point loading and ring loading in the vertical. The solutions are extended to circular distributed and strip distributed normal load. The computation and analysis of settlements, vertical total stress and excess pore pressure in the consolidation layer subject to circular loading are presented.
Particle production in higher derivative theory
Indian Academy of Sciences (India)
G P Singh; A Beesham; R V Deshpande
2000-05-01
The effect of particle production on the evolution of the spatially ﬂat Friedmann–Lemaitre–Robertson–Walker cosmological model during the early stages of the universe is analysed in the framework of higher derivative theory. The universe has been considered as an open thermodynamic system where particle production gives rise to a supplementary negative creation pressure in addition to the thermodynamic pressure. The dynamical behaviour of both exponential as well as power law solutions have been discussed.
Comment on the exterior solutions and their geometry in scalar-tensor theories of gravity
Tsuchida, T; Tsuchida, Tooru; Watanabe, Kazuya
1999-01-01
We study series of the stationary solutions with asymptotic flatness properties in the Einstein-Maxwell-free scalar system because they are locally equivalent with the exterior solutions in some class of the scalar-tensor theories of gravity. First, we classify spherical exterior solutions into two types of the solutions, an apparently black hole type solution and an apparently worm hole type solution. The solutions contain three parameters, and we clarify their physical significance. Second, we reduce the field equations for the axisymmetric exterior solutions. We find that the reduced equations are partially the same as the Ernst equations. As simple examples, we derive new series of the static, axisymmetric exterior solutions, which correspond to Voorhees's solutions. We then show a non-trivial relation between the spherical exterior solutions and our new solutions. Finally, since null geodesics have conformally invariant properties, we study the local geometry of the exterior solutions by using the optica...
Comment on the Exterior Solutions and Their Geometry in Scalar-Tensor Theories of Gravity
Tsuchida, T.; Watanabe, K.
1999-01-01
We study series of stationary solutions with asymptotic flatness properties in the Einstein-Maxwell-free scalar system because they are locally equivalent to the exterior solutions in some class of scalar-tensor theories of gravity. First, we classify spherical exterior solutions into two types of solutions, an apparently black hole type solution and an apparently worm hole type solution. The solutions contain three parameters, and we clarify their physical significance. Second, we reduce the field equations for the axisymmetric exterior solutions. We find that the reduced equations are partially the same as the Ernst equations. As simple examples, we derive new series of static, axisymmetric exterior solutions, which correspond to Voorhees's solutions. We then establish a non-trivial relation between the spherical exterior solutions and our new solutions. Finally, since null geodesics have conformally invariant properties, we study the local geometry of the exterior solutions by using the optical scalar equations and find some anomalous behavior of the null geodesics.
Brain derived neurotrophic factor
DEFF Research Database (Denmark)
Mitchelmore, Cathy; Gede, Lene
2014-01-01
Brain Derived Neurotrophic Factor (BDNF) is a neurotrophin with important functions in neuronal development and neuroplasticity. Accumulating evidence suggests that alterations in BDNF expression levels underlie a variety of psychiatric and neurological disorders. Indeed, BDNF therapies are...
Seepold, Ralf E D; Madrid, Natividad Martinez
2011-01-01
Embedded systems have an increasing importance in our everyday lives. The growing complexity of embedded systems and the emerging trend to interconnections between them lead to new challenges. Intelligent solutions are necessary to overcome these challenges and to provide reliable and secure systems to the customer under a strict time and financial budget. ""Solutions on Embedded Systems"" documents results of several innovative approaches that provide intelligent solutions in embedded systems. The objective is to present mature approaches, to provide detailed information on the implementation
Dissipative cosmological solutions
Chimento, Luis P.; Jakubi, Alejandro S.
1997-01-01
The exact general solution to the Einstein equations in a homogeneous Universe with a full causal viscous fluid source for the bulk viscosity index $m=1/2$ is found. We have investigated the asymptotic stability of Friedmann and de Sitter solutions, the former is stable for $m\\ge 1/2$ and the latter for $m\\le 1/2$. The comparison with results of the truncated theory is made. For $m=1/2$, it was found that families of solutions with extrema no longer remain in the full case, and they are repla...
Lublinsky, Boris; Yakubovich, Alexey
2013-01-01
The go-to guidebook for deploying Big Data solutions with Hadoop Today's enterprise architects need to understand how the Hadoop frameworks and APIs fit together, and how they can be integrated to deliver real-world solutions. This book is a practical, detailed guide to building and implementing those solutions, with code-level instruction in the popular Wrox tradition. It covers storing data with HDFS and Hbase, processing data with MapReduce, and automating data processing with Oozie. Hadoop security, running Hadoop with Amazon Web Services, best practices, and automating Hadoop processes i
Brain derived neurotrophic factor
DEFF Research Database (Denmark)
Mitchelmore, Cathy; Gede, Lene
2014-01-01
Brain Derived Neurotrophic Factor (BDNF) is a neurotrophin with important functions in neuronal development and neuroplasticity. Accumulating evidence suggests that alterations in BDNF expression levels underlie a variety of psychiatric and neurological disorders. Indeed, BDNF therapies are curre......Brain Derived Neurotrophic Factor (BDNF) is a neurotrophin with important functions in neuronal development and neuroplasticity. Accumulating evidence suggests that alterations in BDNF expression levels underlie a variety of psychiatric and neurological disorders. Indeed, BDNF therapies...
American derivatives : a review
Aase, Knut K.
1997-01-01
The paper gives an overview over the theory of pricing and hedging financial derivatives that can be exercised at any time during a fixed time interval [0, T]. The analysis makes use of the theory of optimal stopping, and as such it constitutes an interesting application of probability theory to the theory of financial economics. In this paper we concentrate on the main principles involved only, which means, for example, that we abstract from derivatives where the underlying asset pays ou...
Directory of Open Access Journals (Sweden)
Eliana Henriques de Brito
1990-01-01
Full Text Available In continuing from previous papers, where we studied the existence and uniqueness of the global solution and its asymptotic behavior as time t goes to infinity, we now search for a time-periodic weak solution u(t for the equation whose weak formulation in a Hilbert space H isddt(u′,v+δ(u′,v+αb(u,v+βa(u,v+(G(u,v=(h,vwhere: ′=d/dt; (′ is the inner product in H; b(u,v, a(u,v are given forms on subspaces U⊂W, respectively, of H; δ>0, α≥0, β≥0 are constants and α+β>0; G is the Gateaux derivative of a convex functional J:V⊂H→[0,∞ for V=U, when α>0 and V=W when α=0, hence β>0; v is a test function in V; h is a given function of t with values in H.
Solution to enterprise resource planning; ERP solution
Energy Technology Data Exchange (ETDEWEB)
Suzuki, M.; Okajima, E. [Fuji Electric Co. Ltd., Tokyo (Japan)
2000-05-10
The environment around enterprises has greatly changed in sluggish Japanese economy since the bubble burst. To make the total enterprise activity efficient and speedy and to flexibly meet changes in enterprise environments and diversified customer needs, enterprises are planning to shift the existing methods to enterprise resource planning (ERP) as the infrastructure of strategic enterprise management. This paper describes the solution to ERP which is package software for the key system, the core of enterprise basic business, and also an application example, giving guideline for restructuring the basic business. (author)
Directory of Open Access Journals (Sweden)
Shi-Fang Yuan
2014-01-01
Full Text Available Using the Kronecker product of matrices, the Moore-Penrose generalized inverse, and the complex representation of quaternion matrices, we derive the expressions of least squares solution with the least norm, least squares pure imaginary solution with the least norm, and least squares real solution with the least norm of the quaternion matrix equation AXB+CXD=E, respectively.
Institute of Scientific and Technical Information of China (English)
无
2005-01-01
By using the further extended tanh method [Phys. Lett. A 307 (2003) 269; Chaos, Solitons & Fractals 17(2003) 669] to the Broer-Kaup system with variable coefficients, abundant new soliton-like solutions and multi-soliton-like solutions are derived. Based on the derived multi-soliton-like solutions which contain arbitrary functions, some interesting multi-soliton structures are revealed.
Coopetitive game solutions for the eurozone economy
Carfì, D.; Magaudda, M.; Schilirò, D.
2010-01-01
This paper aims at providing, through a game theory model of coopetition, feasible solutions in a cooperative perspective to the problems that affect the Eurozone economy after the Greek crisis. In particular, it focuses on stability and growth as the primary goals, which should drive the Eurozone economy in consequence of the financial and economic crisis of the Greek economy with its effects throughout the Euro area. By means of two coopetitive models derived by an original general analytic...
A dyadic solution of relative pose problems
Bradley, Patrick Erik
2009-01-01
A hierarchical interval subdivision is shown to lead to a $p$-adic encoding of image data. This allows in the case of the relative pose problem in computer vision and photogrammetry to derive equations having 2-adic numbers as coefficients, and to use Hensel's lifting method to their solution. This method is applied to the linear and non-linear equations coming from eight, seven or five point correspondences. An inherent property of the method is its robustness.
Analytic Solutions of Elastic Tunneling Problems
Strack, O.E.
2002-01-01
The complex variable method for solving two dimensional linearly elastic problems is used to obtain several fundamental analytical solutions of tunneling problems. The method is used to derive the general mathematical representation of problems involving resultant forces on holes in a half-plane. Such problems are encountered in geomechanics during the excavation of tunnels. When tunnels are excavated the removal of the weighted material inside the tunnel causes the ground under the tunnel to...
The Conductivity of Solutions.
Rayner-Canham, Geoff
1993-01-01
Presents historical background and modern explanations for the popular demonstration of showing conductivity of solutions through the insertion of a light-bulb conductivity tester into deionized water and water with salt in it. (PR)
Convergent Aeronautics Solutions Project
National Aeronautics and Space Administration — The Convergent Aeronautics Solutions (CAS) Project uses short-duration activities to establish early-stage concept and technology feasibility for high-potential...
Cromolyn Sodium Nasal Solution
... is sometimes prescribed for other uses; ask your doctor or pharmacist for more information. ... the instructions provided with the solution. Ask your doctor, pharmacist, or respiratory therapist to demonstrate the proper technique. ...
Discrete derivative estimation in LISA Pathfinder data reduction
Ferraioli, Luigi; Vitale, Stefano
2009-01-01
Data analysis for the LISA Technology package (LTP) experiment to be flown aboard the LISA Pathfinder mission requires the solution of the system dynamics for the calculation of the force acting on the test masses (TMs) starting from interferometer position data. The need for a solution to this problem has prompted us to implement a discrete time domain derivative estimator suited for the LTP experiment requirements. We first report on the mathematical procedures for the definition of two methods; the first based on a parabolic fit approximation and the second based on a Taylor series expansion. These two methods are then generalized and incorporated in a more general class of five point discrete derivative estimators. The same procedure employed for the second derivative can be applied to the estimation of the first derivative and of a data smoother allowing defining a class of simple five points estimators for both. The performances of three particular realization of the five point second derivative estimat...
TUTUNEA MIHAELA FILOFTEIA
2012-01-01
The integration of activities, the business processes as well as their optimization, bring the perspective of profitable growth and create significant and competitive advantages in any company. The adoption of some ERP integrated software solutions, from SMEs’ perspective, must be considered as a very important management decision in medium and long term. ERP solutions, along with the transparent and optimized management of all internal processes, also offer an...
Piezoelectric Energy Harvesting Solutions
Caliò, Renato; Rongala, Udaya Bhaskar; Camboni, Domenico; Milazzo, Mario; Stefanini, Cesare; de Petris, Gianluca; Oddo, Calogero Maria
2014-01-01
This paper reviews the state of the art in piezoelectric energy harvesting. It presents the basics of piezoelectricity and discusses materials choice. The work places emphasis on material operating modes and device configurations, from resonant to non-resonant devices and also to rotational solutions. The reviewed literature is compared based on power density and bandwidth. Lastly, the question of power conversion is addressed by reviewing various circuit solutions. PMID:24618725
Conduction heat transfer solutions
International Nuclear Information System (INIS)
This text is a collection of solutions to a variety of heat conduction problems found in numerous publications, such as textbooks, handbooks, journals, reports, etc. Its purpose is to assemble these solutions into one source that can facilitate the search for a particular problem solution. Generally, it is intended to be a handbook on the subject of heat conduction. There are twelve sections of solutions which correspond with the class of problems found in each. Geometry, state, boundary conditions, and other categories are used to classify the problems. Each problem is concisely described by geometry and condition statements, and many times a descriptive sketch is also included. The introduction presents a synopsis on the theory, differential equations, and boundary conditions for conduction heat transfer. Some discussion is given on the use and interpretation of solutions. Supplementary data such as mathematical functions, convection correlations, and thermal properties are included for aiding the user in computing numerical values from the solutions. 155 figs., 92 refs., 9 tabs
Derivation of a poroelastic flexural shell model
Mikelic, Andro
2015-01-01
In this paper we investigate the limit behavior of the solution to quasi-static Biot's equations in thin poroelastic flexural shells as the thickness of the shell tends to zero and extend the results obtained for the poroelastic plate by Marciniak-Czochra and Mikeli\\'c. We choose Terzaghi's time corresponding to the shell thickness and obtain the strong convergence of the three-dimensional solid displacement, fluid pressure and total poroelastic stress to the solution of the new class of shell equations. The derived bending equation is coupled with the pressure equation and it contains the bending moment due to the variation in pore pressure across the shell thickness. The effective pressure equation is parabolic only in the normal direction. As additional terms it contains the time derivative of the middle-surface flexural strain. Derivation of the model presents an extension of the results on the derivation of classical linear elastic shells by Ciarlet and collaborators to the poroelastic shells case. The n...
Optimal hedging of Derivatives with transaction costs
Aurell, E; Aurell, Erik; Muratore-Ginanneschi, Paolo
2005-01-01
We investigate the optimal strategy over a finite time horizon for a portfolio of stock and bond and a derivative in an multiplicative Markovian market model with transaction costs (friction). The optimization problem is solved by a Hamilton-Bellman-Jacobi equation, which by the verification theorem has well-behaved solutions if certain conditions on a potential are satisfied. In the case at hand, these conditions simply imply arbitrage-free ("Black-Scholes") pricing of the derivative. While pricing is hence not changed by friction allow a portfolio to fluctuate around a delta hedge. In the limit of weak friction, we determine the optimal control to essentially be of two parts: a strong control, which tries to bring the stock-and-derivative portfolio towards a Black-Scholes delta hedge; and a weak control, which moves the portfolio by adding or subtracting a Black-Scholes hedge. For simplicity we assume growth-optimal investment criteria and quadratic friction.
Derivatives on the isotropic tensor functions
Institute of Scientific and Technical Information of China (English)
DUI; Guansuo; WANG; Zhengdao; JIN; Ming
2006-01-01
The derivative of the isotropic tensor function plays an important part in continuum mechanics and computational mechanics, and also it is still an opening problem. By means of a scalar response function and solving a tensor equation, this problem is well studied. A compact explicit expression for the derivative of the isotropic tensor function is presented, which is valid for both distinct and repeated eigenvalue cases. Throughout the analysis, the formulation holds for general isotropic tensor functions without need to solve eigenvector problems or determine coefficients. On the theoretical side, a very simple solution of a tensor equation is obtained. As an application to continuum mechanics, a base-free expression for the Hill's strain rate is given, which is more compact than the existent results. Finally, with an example we compute the derivative of an exponent tensor function. And the efficiency of the present formulations is demonstrated.
Protein folding, stability, and solvation structure in osmolyte solutions hydrophobicity
Montgomery Pettitt, B.
2008-03-01
The hydrophobic effect between solutes in aqueous solutions plays a central role in our understanding of recognition and folding of proteins and self assembly of lipids. Hydrophobicity induces nonideal solution behavior which plays a role in many aspects of biophysics. Work on the use of small biochemical compounds to crowd protein solutions indicates that a quantitative description of their non-ideal behavior is possible and straightforward. Here, we will show what the structural origin of this non-ideal solution behavior is from expression derived from a semi grand ensemble approach. We discuss the consequences of these findings regarding protein folding stability and solvation in crowded solutions through a structural analysis of the m-value or the change in free energy difference of a macromolecule in solution with respect to the concentration of a third component. This effect has recently been restudied and new mechanisms proposed for its origins in terms of transfer free energies and hydrophobicity.
Comment on: ‘Peakon and solitonic solutions for KdV-like equations’
Leite Freire, Igor
2016-04-01
In a recent paper (Wazwaz 2015 Phys. Scr. 90 045203) some evolution equations were considered. Among other results, it found peakon solutions for the equations under consideration. This sort of solution corresponds to weak solutions, piecewise smooth, with no derivative in a certain point, the peaks. In this note we show that the weak functions claimed as solutions are not solutions for at least two of the equations investigated.
Solutions of the U(N)σ models with the Wess-Zumino term
International Nuclear Information System (INIS)
We study finite action classical solutions of the Euclidean two-dimensional U(N) sigma models with the Wess-Zumino term. We show that these solutions are related to (and so can be derived from) the solutions of the Lax-pair problem for the corresponding U(N) sigma model (without the Wess-Zumino term). We discuss the value of the action for these solutions and prove that all these solutions are unstable. (orig.)
Robinson-Trautman solution with nonlinear electrodynamics
Energy Technology Data Exchange (ETDEWEB)
Tahamtan, T.; Svitek, O. [Charles University in Prague, Faculty of Mathematics and Physics, Institute of Theoretical Physics, Prague 8 (Czech Republic)
2016-06-15
Explicit Robinson-Trautman solutions with an electromagnetic field satisfying nonlinear field equations are derived and analyzed. The solutions are generated from the spherically symmetric ones. In all studied cases the electromagnetic field singularity is removed while the gravitational one persists. The models resolving the curvature singularity in spherically symmetric spacetimes could not be generalized to the Robinson-Trautman geometry using the generating method developed in this paper, which indicates that the removal of a singularity in the associated spherically symmetric case might be just a consequence of high symmetry. We show that the obtained solutions are generally of algebraic type II and reduce to type D in spherical symmetry. Asymptotically they tend to the spherically symmetric case as well. (orig.)
Iterative solution of Hermite boundary integral equations
Energy Technology Data Exchange (ETDEWEB)
Gray, Leonard J [ORNL; Nintcheu Fata, Sylvain [ORNL; Ma, Ding [ORNL
2008-01-01
An efficient iterative method for the solution of the linear equations arising from a Hermite boundary integral approximation has been developed. Along with equations for the boundary unknowns, the Hermite system incorporates equations for the first-order surface derivatives (gradient) of the potential, and is therefore substantially larger than the matrix for a corresponding linear approximation. However, by exploiting the structure of the Hermite matrix, a two-level iterative algorithm has been shown to provide a very efficient solution algorithm. In this approach, the boundary function unknowns are treated separately from the gradient, taking advantage of the sparsity and near-positive definiteness of the gradient equations. In test problems, the new algorithm significantly reduced computation time compared to iterative solution applied to the full matrix. This approach should prove to be even more effective for the larger systems encountered in three-dimensional analysis, and increased efficiency should come from pre-conditioning of the non-sparse matrix component.
Integer Solutions of a Special Diophantine Equation
Özkoç, Arzu; Tekcan, Ahmet
2011-09-01
Let t≠1 be an integer. In this work, we determine the integer solutions of Diophantine equation D:x2+(2-t2)y2+(-2t2-2t+2)x+(2t5-6t3+4t)y-t8+4t6-4t4+2t3+t2-2t = 0 over Z and also over finite fields Fp for primes p≥2. Also we derive some recurrence relations on the integer solutions (xn,yn) of D and formulate the the n—th solution (xn,yn) by using the simple continued fraction expansion of xn/yn.
A time dependent solution for the operation of ion chambers in a high ionization background
Velissaris, C
2005-01-01
We have derived a time dependent solution describing the development of space charge inside an ion chamber subjected to an externally caused ionization rate N. The solution enables the derivation of a formula that the operational parameters of the chamber must satisfy for saturation free operation. This formula contains a correction factor to account for the finite duration of the ionization rate N.
Smyrnakis, J.; Magiropoulos, M.; Kavoulakis, G. M.; Jackson, A. D.
2013-01-01
We derive solitary-wave solutions within the mean-field approximation in quasi-one-dimensional binary mixtures of Bose-Einstein condensates under periodic boundary conditions, for the case of an effective repulsive interatomic interaction. The particular gray-bright solutions that give the global energy minima are determined. Their characteristics and the associated dispersion relation are derived.
Exact Solutions for a Nonisospectral and Variable-Coefficient Kadomtsev-Petviashvili Equation
Institute of Scientific and Technical Information of China (English)
DENG Shu-Fang
2006-01-01
@@ The bilinear form for a nonisospectral and variable-coefficient Kadomtsev-Petviashvili equation is obtained and some exact soliton solutions are derived by the Hirota method and Wronskian technique. We also derive the bilinear B(a)cklund transformation from its Lax pairs and find solutions with the help of the obtained bilinear B(a)cklund transformation.
Exact Solutions for a Nonisospectral and Variable-Coefficient KdV Equation
Institute of Scientific and Technical Information of China (English)
DENG Shu-Fang
2005-01-01
The bilinear form for a nonisospectral and variable-coefficient KdV equation is obtained and some exact soliton solutions are derived through Hirota method and Wronskian technique. We also derive the bilinear transformation from its Lax pairs and find solutions with the help of the obtained bilinear transformation.
On the solution of fractional evolution equations
Energy Technology Data Exchange (ETDEWEB)
Kilbas, Anatoly A [Department of Mathematics and Mechanics, Belarusian State University, 220050 Minsk (Belarus); Pierantozzi, Teresa [Departamento de Matematica Aplicada, Facultad de Informatica, Universidad Complutense, E-28040 Madrid (Spain); Trujillo, Juan J [Departamento de Analisis Matematico, Universidad de la Laguna, 38271 La Laguna-Tenerife (Spain); Vazquez, Luis [Departamento de Matematica Aplicada, Facultad de Informatica, Universidad Complutense, E-28040 Madrid (Spain)
2004-03-05
This paper is devoted to the solution of the bi-fractional differential equation ({sup C}D{sup {alpha}}{sub t}u)(t, x) = {lambda}({sup L}D{sup {beta}}{sub x}u)(t, x) (t>0, -{infinity}
Energy Technology Data Exchange (ETDEWEB)
Strom, I.; Joosten, L.; Boonstra, C. [DHV Sustainability Consultants, Eindhoiven (Netherlands)
2006-05-15
PEP stands for 'Promotion of European Passive Houses' and is a consortium of European partners, supported by the European Commission, Directorate General for Energy and Transport. In this working paper an overview is given of Passive House solutions. An inventory has been made of Passive House solutions for new build residences applied in each country. Based on this, the most common basic solutions have been identified and described in further detail, including the extent to which solutions are applied in common and best practice and expected barriers for the implementation in each country. An inventory per country is included in the appendix. The analysis of Passive House solutions in partner countries shows high priority with regard to the performance of the thermal envelope, such as high insulation of walls, roofs, floors and windows/ doors, thermal bridge-free construction and air tightness. Due to the required air tightness, special attention must be paid to indoor air quality through proper ventilation. Finally, efficient ((semi-)solar) heating systems for combined space and DHW heating still require a significant amount of attention in most partner countries. Other basic Passive House solutions show a smaller discrepancy with common practice and fewer barriers have been encountered in partner countries. In the next section, the general barriers in partner countries have been inventoried. For each type of barrier a suggested approach has been given. Most frequently encountered barriers in partner countries are: limited know-how; limited contractor skills; and acceptation of Passive Houses in the market. Based on the suggested approaches to overcoming barriers, this means that a great deal of attention must be paid to providing practical information and solutions to building professionals, providing practical training to installers and contractors and communication about the Passive House concept to the market.
Maximum likelihood molecular clock comb: analytic solutions.
Chor, Benny; Khetan, Amit; Snir, Sagi
2006-04-01
Maximum likelihood (ML) is increasingly used as an optimality criterion for selecting evolutionary trees, but finding the global optimum is a hard computational task. Because no general analytic solution is known, numeric techniques such as hill climbing or expectation maximization (EM), are used in order to find optimal parameters for a given tree. So far, analytic solutions were derived only for the simplest model--three taxa, two state characters, under a molecular clock. Four taxa rooted trees have two topologies--the fork (two subtrees with two leaves each) and the comb (one subtree with three leaves, the other with a single leaf). In a previous work, we devised a closed form analytic solution for the ML molecular clock fork. In this work, we extend the state of the art in the area of analytic solutions ML trees to the family of all four taxa trees under the molecular clock assumption. The change from the fork topology to the comb incurs a major increase in the complexity of the underlying algebraic system and requires novel techniques and approaches. We combine the ultrametric properties of molecular clock trees with the Hadamard conjugation to derive a number of topology dependent identities. Employing these identities, we substantially simplify the system of polynomial equations. We finally use tools from algebraic geometry (e.g., Gröbner bases, ideal saturation, resultants) and employ symbolic algebra software to obtain analytic solutions for the comb. We show that in contrast to the fork, the comb has no closed form solutions (expressed by radicals in the input data). In general, four taxa trees can have multiple ML points. In contrast, we can now prove that under the molecular clock assumption, the comb has a unique (local and global) ML point. (Such uniqueness was previously shown for the fork.).
DEFF Research Database (Denmark)
Holm, Henrik Granau
2004-01-01
Over any associative ring R it is standard to derive HomR(;) using projective resolutions in the rst variable, or injective resolutions in the second variable, and doing this, one obtains Extn R(;) in both cases. We examine the situation where projective an...... injective modules are replaced by Gorenstein projective and Gorenstein injective ones, respectively. Furthermore, we derive the tensor product R using Gorenstein at modules.......Over any associative ring R it is standard to derive HomR(;) using projective resolutions in the rst variable, or injective resolutions in the second variable, and doing this, one obtains Extn R(;) in both cases. We examine the situation where projective and...
Towards combined global monthly gravity field solutions
Jaeggi, Adrian; Meyer, Ulrich; Beutler, Gerhard; Weigelt, Matthias; van Dam, Tonie; Mayer-Gürr, Torsten; Flury, Jakob; Flechtner, Frank; Dahle, Christoph; Lemoine, Jean-Michel; Bruinsma, Sean
2014-05-01
Currently, official GRACE Science Data System (SDS) monthly gravity field solutions are generated independently by the Centre for Space Research (CSR) and the German Research Centre for Geosciences (GFZ). Additional GRACE SDS monthly fields are provided by the Jet Propulsion Laboratory (JPL) for validation and outside the SDS by a number of other institutions worldwide. Although the adopted background models and processing standards have been harmonized more and more by the various processing centers during the past years, notable differences still exist and the users are more or less left alone with a decision which model to choose for their individual applications. This procedure seriously limits the accessibility of these valuable data. Combinations are well established in the area of other space geodetic techniques, such as the Global Navigation Satellite Systems (GNSS), Satellite Laser Ranging (SLR), and Very Long Baseline Interferometry (VLBI). Regularly comparing and combining space-geodetic products has tremendously increased the usefulness of the products in a wide range of disciplines and scientific applications. Therefore, we propose in a first step to mutually compare the large variety of available monthly GRACE gravity field solutions, e.g., by assessing the signal content over selected regions, by estimating the noise over the oceans, and by performing significance tests. We make the attempt to assign different solution characteristics to different processing strategies in order to identify subsets of solutions, which are based on similar processing strategies. Using these subsets we will in a second step explore ways to generate combined solutions, e.g., based on a weighted average of the individual solutions using empirical weights derived from pair-wise comparisons. We will also assess the quality of such a combined solution and discuss the potential benefits for the GRACE and GRACE-FO user community, but also address minimum processing
International Nuclear Information System (INIS)
Using the Green function techniques, the wave solutions were expressed of the radial inhomogeneous Schroedinger equation by means of the on-shell Jost and regular solutions. Using their boundary behaviour at r = infinity and r = 0, the wave solutions were re-expressed alternatively in terms of the off-shell Jost and regular solutions. Relations among the different generalized (fully off the energy shell) Jost functions are derived and the radial matrix elements of the transition and reaction (reactance) operators are given in terms of these Jost functions. The relations reflect the principle of detailed balance. (author)
On alpha'-corrections to D-brane solutions
De Haro, S; Skenderis, K; Haro, Sebastian de; Sinkovics, Annamaria; Skenderis, Kostas
2003-01-01
We discuss the computation of the leading corrections to D-brane solutions due to higher derivative terms in the corresponding low energy effective action. We develop several alternative methods for analyzing the problem. In particular, we derive an effective one-dimensional action from which the field equations for spherically symmetric two-block brane solutions can be derived, show how to obtain first order equations, and discuss a few other approaches. We integrate the equations for extremal branes and obtain the corrections in terms of integrals of the evaluation of the higher derivative terms on the lowest order solution. To obtain completely explicit results one would need to know all leading higher derivative corrections which at present are not available. One of the known higher derivative terms is the R^4 term, and we obtain the corrections to the D3 brane solution due to this term alone. We note, however, that (unknown at present) higher terms depending on F_5 are expected to modify our result. We a...
International Nuclear Information System (INIS)
In this note we construct families of asymptotically flat, smooth, horizonless solutions with a large number of non-trivial two-cycles (bubbles) of N = 1 five-dimensional supergravity with an arbitrary number of vector multiplets, which may or may not have the charges of a macroscopic black hole and which contain the known bubbling solutions as a sub-family. We do this by lifting various multi-center BPS states of type IIA compactified on Calabi-Yau three-folds and taking the decompactification (M-theory) limit. We also analyse various properties of these solutions, including the conserved charges, the shape, especially the (absence of) throat and closed timelike curves, and relate them to the various properties of the four-dimensional BPS states. We finish by briefly commenting on their degeneracies and their possible relations to the fuzzball proposal of Mathur et al
International Nuclear Information System (INIS)
This paper deals with in situ solution mining. A significant fraction of known U.S. uranium reserves occur as low grade mineralization in sedimentary sandstone deposits located between 40 and 200 meters subsurface. For a variety of reasons, such deposits may not be economically developable by any method other than in situ solution mining. This coupled with the current market price of uranium has led to significant development and application of in situ solution mining for uranium production during the past several years. The process consists of the ore body; well field; lixiviant; uranium recovery process; waste treatment processes; and aquifer restoration. A tabulation of firms involved with a summary of the leach chemistry used is given. 3 refs
Deriving diffeomorphism symmetry
Kleppe, Astri
2014-01-01
In an earlier article, we have "derived" space, as a part of the Random Dynamics project. In order to get locality we need to obtain reparametrization symmetry, or equivalently, diffeomorphism symmetry. There we sketched a procedure for how to get locality by first obtaining reparametrization symmetry, or equivalently, diffeomorphism symmetry. This is the object of the present article.
DEFF Research Database (Denmark)
Mosley, Cara A; Acker, Timothy M; Hansen, Kasper Bø;
2010-01-01
We describe a new class of subunit-selective antagonists of N-methyl D-aspartate (NMDA)-selective ionotropic glutamate receptors that contain the (E)-3-phenyl-2-styrylquinazolin-4(3H)-one backbone. The inhibition of recombinant NMDA receptor function induced by these quinazolin-4-one derivatives ...
Ferroelectricity in corundum derivatives
Ye, Meng; Vanderbilt, David
2016-04-01
The search for new ferroelectric (FE) materials holds promise for broadening our understanding of FE mechanisms and extending the range of application of FE materials. Here we investigate a class of A B O3 and A2B B'O6 materials that can be derived from the X2O3 corundum structure by mixing two or three ordered cations on the X site. Most such corundum derivatives have a polar structure, but it is unclear whether the polarization is reversible, which is a requirement for a FE material. In this paper, we propose a method to study the FE reversal path of materials in the corundum derivative family. We first categorize the corundum derivatives into four classes and show that only two of these allow for the possibility of FE reversal. We then calculate the energy profile and energy barrier of the FE reversal path using first-principles density functional methods with a structural constraint. Furthermore, we identify several empirical measures that can provide a rule of thumb for estimating the energy barriers. Finally, the conditions under which the magnetic ordering is compatible with ferroelectricity are determined. These results lead us to predict several potentially new FE materials.
Metal derivatives of tetrazoles
Energy Technology Data Exchange (ETDEWEB)
Gaponik, Pavel N; Voitekhovich, Sergei V; Ivashkevich, Oleg A [Research Institute for Physical Chemical Problems of the Belarusian State University, Minsk (Belarus)
2006-06-30
Published data on the synthesis, structure, properties and applications of metal derivatives of tetrazoles are generalised and described systematically. Compounds based on the anionic and neutral tetrazole forms, C- and N-mono- and C,N-disubstituted tetrazoles are considered.
DEFF Research Database (Denmark)
Foss, Kirsten; Foss, Nicolai Juul; Klein, Peter G.
2007-01-01
to subordinates, who exercise derived judgment. We call these employees `proxy-entrepreneurs', and ask how the firm's organizational structure - its formal and informal systems of rewards and punishments, rules for settling disputes and renegotiating agreements, means of evaluating performance and so on - can...
DEFF Research Database (Denmark)
Kokholm, Thomas
financial models, and most importantly, to be aware of their limitations. Following that belief, this thesis consists of three independent and self-contained papers, all dealing with topics in derivatives pricing. The first paper considers the pricing of traffic light options, which are appropriate...
Learning, investments and derivatives
Soklakov, Andrei N.
2011-01-01
The recent crisis and the following flight to simplicity put most derivative businesses around the world under considerable pressure. We argue that the traditional modeling techniques must be extended to include product design. We propose a quantitative framework for creating products which meet the challenge of being optimal from the investors point of view while remaining relatively simple and transparent.
O. Emre Ergungor
2007-01-01
Until recently, homeowners had no way to protect the value of their homes against losses that could result from housing market downturns. With the derivatives contracts introduced by the CME last year, homeowners now have some means of protection, and new and better products are more likely to follow from them.
Biotechnology and derived products
Microorganisms able to infect and kill insect pests, metabolites from plants and microorganisms, and transgenic crops are biotechnologically derived products that are being promoted for use to control insect pests in lieu of chemical insecticides. Products based on these technologies effectively co...
Amiano, Mitch; Ethier, Kay; Thomas, Michael D
2006-01-01
Offering a unique approach to learning XML, this book walks readers through the process of building a complete, functional, end-to-end XML solutionFeatured case study is an online business product catalog that includes reports, data input/output, workflow, stylesheet formatting, RSS feeds, and integration with external services like Google, eBay, and AmazonThe format of presenting a problem and working through the design to come up with a solution enables readers to understand how XML markup allows a business to share data across applications internally or with partners or customers even thoug
Calculus problems and solutions
Ginzburg, A
2011-01-01
Ideal for self-instruction as well as for classroom use, this text helps students improve their understanding and problem-solving skills in analysis, analytic geometry, and higher algebra. More than 1,200 problems appear in the text, with concise explanations of the basic notions and theorems to be used in their solution. Many are followed by complete answers; solutions for the others appear at the end of the book. Topics include sequences, functions of a single variable, limit of a function, differential calculus for functions of a single variable, fundamental theorems and applications of dif
Jorgensen, Adam; Welch, John; Clark, Dan; Price, Christopher; Mitchell, Brian
2014-01-01
Tap the power of Big Data with Microsoft technologies Big Data is here, and Microsoft's new Big Data platform is a valuable tool to help your company get the very most out of it. This timely book shows you how to use HDInsight along with HortonWorks Data Platform for Windows to store, manage, analyze, and share Big Data throughout the enterprise. Focusing primarily on Microsoft and HortonWorks technologies but also covering open source tools, Microsoft Big Data Solutions explains best practices, covers on-premises and cloud-based solutions, and features valuable case studies. Best of all,
Institute of Scientific and Technical Information of China (English)
ZHU Qiding; MENG Lingxiong
2004-01-01
In this paper the ultraconvergence of the derivative for odd-degree rectangular elements is addressed. A new, discrete least-squares patch recovery technique is proposed to post-process the solution derivatives. Such recovered derivatives are shown to possess ultraconvergence by using projection type interpolation.
Solutions of the supersymmetric U(N) /sigma/ models with the Wess-Zumino-Witten term
Energy Technology Data Exchange (ETDEWEB)
Piette, B.; Zait, R.A.; Zakrzewski, W.J.
1989-09-01
We present finite action classical solutions of the supersymmetric (Susy) U(N) sigma models with and without the Wess-Zumino-Witten (WZW) term. We derive solutions of the model with the WZW-term from the solutions of the Lax-pair problem for the corresponding model without this term. We study some properties of these solutions such as the value of their action and show that this value is related to that of the purely bosonic U(N) /sigma/-model. Moreover, we prove that all derived solutions are unstable. (orig.).
Approximate *-derivations and approximate quadratic *-derivations on C*-algebras
Directory of Open Access Journals (Sweden)
Park Choonkil
2011-01-01
Full Text Available Abstract In this paper, we prove the stability of *-derivations and of quadratic *-derivations on Banach *-algebras. We moreover prove the superstability of *-derivations and of quadratic *-derivations on C*-algebras. 2000 Mathematics Subject Classification: 39B52; 47B47; 46L05; 39B72.
Chaotic solutions of(2+1)-dimensional Broek-Kaup equation with variable coefficients
Institute of Scientific and Technical Information of China (English)
Yang Zheng; Ma Song-Hua; Fang Jian-Ping
2011-01-01
In this paper, an improved projective approach is used to obtain the variable separation solutions with two arbitrary functions of the(2+1)-dimensional Broek-Kaup equation with variable coefficients(VCBK). Based on the derived solitary wave solution and using a known chaotic system, some novel chaotic solutions are investigated.
An analytical solution of non-Fourier Chen-Holmes bioheat transfer equation
Institute of Scientific and Technical Information of China (English)
GOU Chenhua; CAI Ruixian
2005-01-01
An algebraically explicit analytical solution with heat wave effect is derived for the non-Fourier bioheat transfer Chen-Holmes model. Besides its important theoretical meaning (for example, to expand the understanding of heat wave phenomena in living tissues), this analytical solution is also valuable as the benchmark solution to check the numerical calculation and to develop various numerical computational approaches.
Aqueous polyethylene oxide solutions
International Nuclear Information System (INIS)
A number of aspects concerning the reorientation of polymer, water and ion hydration complexes have been studied in aqueous solution of polyethylene oxide (PEO). The polymer dynamics are investigated by 1H-PEO and 13C-PEO nuclear relaxation experiments. 162 refs.; 30 figs.; 19 tabs
Zee, van der S.E.A.T.M.; Leijnse, A.
2013-01-01
Solute transport is of importance in view of the movement of nutrient elements, e.g. towards the plant root system, and because of a broad range of pollutants. Pollution is not necessarily man induced, but may be due to geological or geohydrological causes, e.g. in the cases of pollution with arseni
Treatment of Aqueous Solutions
Van Spronsen, J.; Witkamp, G.J.
2013-01-01
The invention is directed to a process for the recovery or removal of one or more crystallizable compounds from an aqueous solution containing, apart from the said crystallizable compounds, one or more organic or inorganic scale- forming or scale-inducing materials having a lower solubility in water
Kabala, Z. J.
1997-08-01
Under the assumption that local solute dispersion is negligible, a new general formula (in the form of a convolution integral) is found for the arbitrary k-point ensemble moment of the local concentration of a solute convected in arbitrary m spatial dimensions with general sure initial conditions. From this general formula new closed-form solutions in m=2 spatial dimensions are derived for 2-point ensemble moments of the local solute concentration for the impulse (Dirac delta) and Gaussian initial conditions. When integrated over an averaging window, these solutions lead to new closed-form expressions for the first two ensemble moments of the volume-averaged solute concentration and to the corresponding concentration coefficients of variation (CV). Also, for the impulse (Dirac delta) solute concentration initial condition, the second ensemble moment of the solute point concentration in two spatial dimensions and the corresponding CV are demonstrated to be unbound. For impulse initial conditions the CVs for volume-averaged concentrations axe compared with each other for a tracer from the Borden aquifer experiment. The point-concentration CV is unacceptably large in the whole domain, implying that the ensemble mean concentration is inappropriate for predicting the actual concentration values. The volume-averaged concentration CV decreases significantly with an increasing averaging volume. Since local dispersion is neglected, the new solutions should be interpreted as upper limits for the yet to be derived solutions that account for local dispersion; and so should the presented CVs for Borden tracers. The new analytical solutions may be used to test the accuracy of Monte Carlo simulations or other numerical algorithms that deal with the stochastic solute transport. They may also be used to determine the size of the averaging volume needed to make a quasi-sure statement about the solute mass contained in it.
Institute of Scientific and Technical Information of China (English)
YANG Ling'e; GUO Boling
2006-01-01
By the uniform a priori estimate of solution about parameters, we prove the existence of global solution and inviscid limit to a generalized Ginzburg-Landau equations in two dimensions. We also prove that the solution to the Ginzburg-Landau equations converges to the weak solution to the derivative nonlinear Schrodinger equations.
Fundamental solutions of linear partial differential operators theory and practice
Ortner, Norbert
2015-01-01
This monograph provides the theoretical foundations needed for the construction of fundamental solutions and fundamental matrices of (systems of) linear partial differential equations. Many illustrative examples also show techniques for finding such solutions in terms of integrals. Particular attention is given to developing the fundamentals of distribution theory, accompanied by calculations of fundamental solutions. The main part of the book deals with existence theorems and uniqueness criteria, the method of parameter integration, the investigation of quasihyperbolic systems by means of Fourier and Laplace transforms, and the representation of fundamental solutions of homogeneous elliptic operators with the help of Abelian integrals. In addition to rigorous distributional derivations and verifications of fundamental solutions, the book also shows how to construct fundamental solutions (matrices) of many physically relevant operators (systems), in elasticity, thermoelasticity, hexagonal/cubic elastodynamics...
Polyharmonic Multiquadric Particular Solutions for Reissner/Mindlin Plate
Directory of Open Access Journals (Sweden)
Chia-Cheng Tsai
2015-01-01
Full Text Available Analytical particular solutions of the polyharmonic multiquadrics are derived for both the Reissner and Mindlin thick-plate models in a unified formulation. In the derivation, the three coupled second-order partial differential equations are converted into a product operator of biharmonic and Helmholtz operators using the Hörmander operator decomposition technique. Then a method is introduced to eliminate the Helmholtz operator, which enables the utilization of the polyharmonic multiquadrics. Then, the analytical particular solutions of displacements, shear forces, and bending or twisting moments corresponding to the polyharmonic multiquadrics are all explicitly derived. Numerical examples are carried out to validate these particular solutions. The results obtained by the present method are more accurate than those by the traditional multiquadrics and splines.
Analytic solutions of an unclassified artifact /
Energy Technology Data Exchange (ETDEWEB)
Trent, Bruce C.
2012-03-01
This report provides the technical detail for analytic solutions for the inner and outer profiles of the unclassified CMM Test Artifact (LANL Part Number 157Y-700373, 5/03/2001) in terms of radius and polar angle. Furthermore, analytic solutions are derived for the legacy Sheffield measurement hardware, also in terms of radius and polar angle, using part coordinates, i.e., relative to the analytic profile solutions obtained. The purpose of this work is to determine the exact solution for the “cosine correction” term inherent to measurement with the Sheffield hardware. The cosine correction is required in order to interpret the actual measurements taken by the hardware in terms of an actual part definition, or “knot-point spline definition,” that typically accompanies a component drawing. Specifically, there are two portions of the problem: first an analytic solution must be obtained for any point on the part, e.g., given the radii and the straight lines that define the part, it is required to find an exact solution for the inner and outer profile for any arbitrary polar angle. Next, the problem of the inspection of this part must be solved, i.e., given an arbitrary sphere (representing the inspection hardware) that comes in contact with the part (inner and outer profiles) at any arbitrary polar angle, it is required to determine the exact location of that intersection. This is trivial for the case of concentric circles. In the present case, however, the spherical portion of the profiles is offset from the defined center of the part, making the analysis nontrivial. Here, a simultaneous solution of the part profiles and the sphere was obtained.
Pushing schedule derivation method
Energy Technology Data Exchange (ETDEWEB)
Henriquez, B. [Compania Siderurgica Huachipato S.A., Talcahuano (Chile)
1996-12-31
The development of a Pushing Schedule Derivation Method has allowed the company to sustain the maximum production rate at CSH`s Coke Oven Battery, in spite of having single set oven machinery with a high failure index as well as a heat top tendency. The stated method provides for scheduled downtime of up to two hours for machinery maintenance purposes, periods of empty ovens for decarbonization and production loss recovery capability, while observing lower limits and uniformity of coking time.
Systems of integrable derivations
Directory of Open Access Journals (Sweden)
Vittoria Bonanzinga
1994-05-01
Full Text Available Let A be a commutative k-algebra, with k a subring of A. We give the definition of n-dimensional differentiation of A over k which formally extends the known one of unidimensional differentiation and we study the group of all n-dimensional differentiation of A over k. In the second part of the work we give some theorems of strong integrability for systems of derivations in terms of n-dimensional differentiation.
Hydrotropic Solubilization by Urea Derivatives: A Molecular Dynamics Simulation Study
Directory of Open Access Journals (Sweden)
Yong Cui
2013-01-01
Full Text Available Hydrotropy is a phenomenon where the presence of a large quantity of one solute enhances the solubility of another solute. The mechanism of this phenomenon remains a topic of debate. This study employed molecular dynamics simulation to investigate the hydrotropic mechanism of a series of urea derivatives, that is, urea (UR, methylurea (MU, ethylurea (EU, and butylurea (BU. A poorly water-soluble compound, nifedipine (NF, was used as the model solute that was solubilized. Structural, dynamic, and energetic changes upon equilibration were analyzed to supply insights to the solubilization mechanism. The study demonstrated that NF and urea derivatives underwent significant nonstoichiometric molecular aggregation in the aqueous solution, a result consistent with the self-aggregation of urea derivatives under the same conditions. The analysis of hydrogen bonding and energy changes revealed that the aggregation was driven by the partial restoration of normal water structure. The energetic data also suggested that the promoted solubilization of NF is favored in the presence of urea derivatives. While the solutes aggregated to a varying degree, the systems were still in single-phase liquid state as attested by their active dynamics.
Endostatin derivative angiogenesis inhibitors
Institute of Scientific and Technical Information of China (English)
ZHENG Meng-jie
2009-01-01
Objective To throw light on the superiority of the anti-angiogenesis activity of endostatin (ES) derivatives by reviewing the recent progress in the field of ES molecular structure modification.Data sources The data used in this article were mainly from PubMed with relevant English articles published from 1971 to May 2008.The search terms were "endostatin" and "angiothesis".Study selection Articles involved in the ES molecular structure modification and the original milestone articles were selected.Results A number of ES derivatives were designed and studied to improve its clinical relevance.The modified ES with polyethylene glycol (PEG),low molecular weight heparin (LMWH) and IgG Fc domain extended the circulation half-life.Meanwhile the recombinant ESs showed more potent anti-tumor activity than native ES in mouse xenografts.Mutated ES also changed its anti-angiogenesis activity.Conclusions The anti-angiogenesis treatment remains a promising tumor therapeutic strategy.New ES derivatives would be a good choice to meet the future challenge on clinical application of ES.
Bidifferential Calculus Approach to AKNS Hierarchies and Their Solutions
Directory of Open Access Journals (Sweden)
Aristophanes Dimakis
2010-07-01
Full Text Available We express AKNS hierarchies, admitting reductions to matrix NLS and matrix mKdV hierarchies, in terms of a bidifferential graded algebra. Application of a universal result in this framework quickly generates an infinite family of exact solutions, including e.g. the matrix solitons in the focusing NLS case. Exploiting a general Miura transformation, we recover the generalized Heisenberg magnet hierarchy and establish a corresponding solution formula for it. Simply by exchanging the roles of the two derivations of the bidifferential graded algebra, we recover ''negative flows'', leading to an extension of the respective hierarchy. In this way we also meet a matrix and vector version of the short pulse equation and also the sine-Gordon equation. For these equations corresponding solution formulas are also derived. In all these cases the solutions are parametrized in terms of matrix data that have to satisfy a certain Sylvester equation.
International Nuclear Information System (INIS)
The glide of edge and screw dislocation in solid solution is modeled through atomistic simulations in two model alloys of Ni(Al) and Al(Mg) described within the embedded atom method. Our approach is based on the study of the elementary interaction between dislocations and solutes to derive solid solution hardening of face centered cubic binary alloys. We identify the physical origins of the intensity and range of the interaction between a dislocation and a solute atom. The thermally activated crossing of a solute atom by a dislocation is studied at the atomistic scale. We show that hardening of edge and screw segments are similar. We develop a line tension model that reproduces quantitatively the atomistic calculations of the flow stress. We identify the universality class to which the dislocation depinning transition in solid solution belongs. (author)
A classical approach to higher-derivative gravity
International Nuclear Information System (INIS)
Two classical routes towards higher-derivative gravity theory are described. The first one is a geometrical route, starting from first principles. The second route is a formal one, and is based on a recent theorem by Castagnino et.al. [J. Math. Phys. 28 (1987) 1854]. A cosmological solution of the higher-derivative field equations is exhibited which in a classical framework singles out this gravitation theory. (author)
On the pricing and hedging of volatility derivatives
Howison, Sam; Rafailidis, Avraam; Rasmussen, Henrik
2003-01-01
We consider the pricing of a range of volatility derivatives, including volatility and variance swaps and swaptions. Under risk-neutral valuation we provide closed-form formulae for volatility-average and variance swaps for a variety of diffusion and jump-diffusion models for volatility. We describe a general partial differential equation framework for derivatives that have an extra dependence on an average of the volatility. We give approximate solutions of this equation for volatility produ...
AN ANALYTICAL SOLUTION FOR CALCULATING THE INITIATION OF SEDIMENT MOTION
Institute of Scientific and Technical Information of China (English)
Thomas LUCKNER; Ulrich ZANKE
2007-01-01
This paper presents an analytical solution for calculating the initiation of sediment motion and the risk of river bed movement. It thus deals with a fundamental problem in sediment transport, for which no complete analytical solution has yet been found. The analytical solution presented here is based on forces acting on a single grain in state of initiation of sediment motion. The previous procedures for calculating the initiation of sediment motion are complemented by an innovative combination of optical surface measurement technology for determining geometrical parameters and their statistical derivation as well as a novel approach for determining the turbulence effects of velocity fluctuations. This two aspects and the comparison of the solution functions presented here with the well known data and functions of different authors mainly differ the presented solution model for calculating the initiation of sediment motion from previous approaches. The defined values of required geometrical parameters are based on hydraulically laboratory tests with spheres. With this limitations the derivated solution functions permit the calculation of the effective critical transport parameters of a single grain, the calculation of averaged critical parameters for describing the state of initiation of sediment motion on the river bed, the calculation of the probability density of the effective critical velocity as well as the calculation of the risk of river bed movement. The main advantage of the presented model is the closed analytical solution from the equilibrium of forces on a single grain to the solution functions describing the initiation of sediment motion.
The sustainability solutions agenda.
Sarewitz, Daniel; Clapp, Richard; Crumbley, Cathy; Kriebel, David; Tickner, Joel
2012-01-01
Progress toward a more sustainable society is usually described in a "knowledge-first" framework, where science characterizes a problem in terms of its causes and mechanisms as a basis for subsequent action. Here we present a different approach-A Sustainability Solutions Agenda (SSA)-which seeks from the outset to identify the possible pathways to solutions. SSA focuses on uncovering paths to sustainability by improving current technological practice, and applying existing knowledge to identify and evaluate technological alternatives. SSA allows people and organizations to transition toward greater sustainability without sacrificing essential technological functions, and therefore does not threaten the interests that depend on those functions. Whereas knowledge-first approaches view scientific information as sufficient to convince people to take the right actions, even if those actions are perceived as against their immediate interests, SSA allows values to evolve toward greater attention to sustainability as a result of the positive experience of solving a problem. PMID:22776577
The sustainability solutions agenda.
Sarewitz, Daniel; Clapp, Richard; Crumbley, Cathy; Kriebel, David; Tickner, Joel
2012-01-01
Progress toward a more sustainable society is usually described in a "knowledge-first" framework, where science characterizes a problem in terms of its causes and mechanisms as a basis for subsequent action. Here we present a different approach-A Sustainability Solutions Agenda (SSA)-which seeks from the outset to identify the possible pathways to solutions. SSA focuses on uncovering paths to sustainability by improving current technological practice, and applying existing knowledge to identify and evaluate technological alternatives. SSA allows people and organizations to transition toward greater sustainability without sacrificing essential technological functions, and therefore does not threaten the interests that depend on those functions. Whereas knowledge-first approaches view scientific information as sufficient to convince people to take the right actions, even if those actions are perceived as against their immediate interests, SSA allows values to evolve toward greater attention to sustainability as a result of the positive experience of solving a problem.
Credit derivatives and risk management
Michael S. Gibson
2007-01-01
The striking growth of credit derivatives suggests that market participants find them to be useful tools for risk management. I illustrate the value of credit derivatives with three examples. A commercial bank can use credit derivatives to manage the risk of its loan portfolio. An investment bank can use credit derivatives to manage the risks it incurs when underwriting securities. An investor, such as an insurance company, asset manager, or hedge fund, can use credit derivatives to align its...
Solid solution luminescence properties
International Nuclear Information System (INIS)
Concentration and kinetic dependences of cathodo- and radioluminescence of Mn2+ ion in CaF2 base solid solutions with Zr, Hf, Pb additions are studied. It is shown that introduction of 2-3 mass % of Zr and Hf into matrix composition causes increase of Mn2+ luminescence intensity with simultaneous increase of persistance duration and a small shift of luminescence band to larger wave lengths. Pb introduction results in efficient quenching of luminescence. 5 refs.; 3 figs.; 1 tab
Earnest Rutherford, the solution
2003-01-01
If you did not make it to the Science & Society talk by John Campbell last week and are still wondering about the spelling of "Earnest", here is the solution: Two months after the birth of his fourth child on 30 August 1871 in Spring Grove, New Zealand, James Rutherford registered his son, who was recorded as "Earnest" in the Birth Register. Presumably the Registrar wrote the name down as it sounded and the father failed to notice the mistake when signing the Register.
АЛИБЕКОВА Ю.К.
2015-01-01
Currently, business ethics and integrity of top managers and employees are often under a big question, so we cannot rely on them. Non-compliant behavior of top management and employees related to fraud and corrupt practices lead to huge financial losses, loss of reputation and litigations. Incidents of internal fraud and embezzlement are happening in every business imaginable. Fraud prevention solutions we recommend are the fundamental for corporate financial compliance. All stakeholders must...
Business Solutions for Realeyes
Aditya, Katti
2009-01-01
The purpose of this report is to propose business solutions for a start-up firm called Realeyes that provides eye-tracking services in UK, Europe and United States. This report makes use of the research and interview findings from the group project that involved developing an international marketing plan for Realeyes to launch in Australia. However, the recommendations in this report have been made keeping in mind Realeyes’ global operations. After having laid the foundation with the lite...
Fundamental solution of an integro-differential transport equation
International Nuclear Information System (INIS)
The problems connected with the construction of generalized functions of the fundamental solution of a stationary single-velocity integro-differential neutron transport equation on the basis of the integral transformation technique and its applications are analyzed. A number of concrete expressions for the fundamental solutions in the tree-dimensional (spherical coordinates) and two-dimensional (cylindrical coordinates) geometries are derived. The most of the formula are apparently published for the first time
ON SOLUTIONS OF MATRIX EQUATION AXAT + BYBT = C
Institute of Scientific and Technical Information of China (English)
Yuan-bei Deng; Xi-yan Hu
2005-01-01
By making use of the quotient singular value decomposition (QSVD) of a matrix pair,this paper establishes the necessary and sufficient conditions for the existence of and the expressions for the general solutions of the linear matrix equation AXAT + BYBT = C with the unknown X and Y, which may be both symmetric, skew-symmetric, nonnegative definite , positive definite or some cross combinations respectively. Also, the solutions of some optimal problems are derived.
Notes on Solutions to Burgers-type Equations
Institute of Scientific and Technical Information of China (English)
FU Zun-Tao; LIU Shi-Da; LIU Shi-Kuo
2004-01-01
A transformation is introduced and applied to solve Burgers-type equations,such as Burgers equation,Burgers-KdV equation and Burgers-KdV-Kuramoto equation.Many kinds of travelling wave solutions including solitary wave solution are obtained,and it is shown that this is a powerful method to solve nonlinear equations with odd-order and even-order derivatives simultaneously.
Two Special Solutions of the Non-ideal Magnetohydrodynamics
Institute of Scientific and Technical Information of China (English)
FENG Xue-Shang; LIU Yong; WEI Feng-Si; YE Zhan-Yin
2000-01-01
A special transformation is found to solve the Magnetohydrodynamic equations, by which two classes of exact analytic time-dependent solutions of magnetic annihilation for incompressible magnetic fluid have been obtained.The solutions derived here possesses scaling property with time t as the scale factor. We find that the current can perform the soliton-like behaviour in the case of asymmetric inflow. The relevant evolution characteristics in the process of magnetic annihilation are also revealed.
Regularity of large solutions for the compressible magnetohydrodynamic equations
Directory of Open Access Journals (Sweden)
Qin Yuming
2011-01-01
Full Text Available Abstract In this paper, we consider the initial-boundary value problem of one-dimensional compressible magnetohydrodynamics flows. The existence and continuous dependence of global solutions in H 1 have been established in Chen and Wang (Z Angew Math Phys 54, 608-632, 2003. We will obtain the regularity of global solutions under certain assumptions on the initial data by deriving some new a priori estimates.
Solutions of Unified Fractional Schrödinger Equations
V.B.L. Chaurasia; Devendra Kumar
2012-01-01
We obtain the solution of a unified fractional Schrödinger equation. The solution is derived by the application of the Laplace and Fourier transforms in closed form in terms of the Mittag-Leffler function. The result obtained here is quite general in nature and capable of yielding a very large number of results (new and known) hitherto scattered in the literature. Most of results obtained are in a form suitable for numerical computation.
Nonlinear MHD-equations: symmetries, solutions and conservation laws
International Nuclear Information System (INIS)
To investigate stability and nonlinear effects in a high-temperature plasma the system of two scalar nonlinear equations is considered. The algebra of classical symmetries of this system and a certain natural part of its conservation laws are described. It is shown that first, with symmetries one can derive invariant (self-similar) solutions, second, acting with symmetry on the known solution the latter can be included into parametric family
Travelling wave solutions for ( + 1)-dimensional nonlinear evolution equations
Indian Academy of Sciences (India)
Jonu Lee; Rathinasamy Sakthivel
2010-10-01
In this paper, we implement the exp-function method to obtain the exact travelling wave solutions of ( + 1)-dimensional nonlinear evolution equations. Four models, the ( + 1)-dimensional generalized Boussinesq equation, ( + 1)-dimensional sine-cosine-Gordon equation, ( + 1)-double sinh-Gordon equation and ( + 1)-sinh-cosinh-Gordon equation, are used as vehicles to conduct the analysis. New travelling wave solutions are derived.
Severe service sealing solutions
International Nuclear Information System (INIS)
Successful sealing usually requires much more than initial leak-tightness. Friction and wear must also be acceptable, requiring a good understanding of tribology at the sealing interface. This paper describes various sealing solutions for severe service conditions. The CAN2A and CAN8 rotary face seals use tungsten carbide against carbon-graphite to achieve low leakage and long lifetime in nuclear main coolant pumps. The smaller CAN6 seal successfully uses tungsten carbide against silicon carbide in reactor water cleanup pump service. Where friction in CANDU fuelling machine rams must be essentially zero, a hydrostatic seal using two silicon carbide faces is the solution. In the NRU reactor moderator pumps, where pressure is much lower, eccentric seals that prevent boiling at the seal faces are giving excellent service. All these rotary face seals rely on supplementary elastomer seals between their parts. An integrated engineering approach to high performance sealing with O-rings is described. This is epitomized in critical Space Shuttle applications, but is increasingly being applied in CANDU plants. It includes gland design, selection and qualification of material, quality assurance, detection of defects and the effects of lubrication, surface finish, squeeze, stretch and volume constraints. In conclusion, for the severe service applications described, customized solutions have more than paid for themselves by higher reliability, lower maintenance requirements and reduced outage time. (author)
An Approximate Solution for Spherical and Cylindrical Piston Problem
Indian Academy of Sciences (India)
S K Singh; V P Singh
2000-02-01
A new theory of shock dynamics (NTSD) has been derived in the form of a finite number of compatibility conditions along shock rays. It has been used to study the growth and decay of shock strengths for spherical and cylindrical pistons starting from a non-zero velocity. Further a weak shock theory has been derived using a simple perturbation method which admits an exact solution and also agrees with the classical decay laws for weak spherical and cylindrical shocks.
An analytical solution to patient prioritisation in radiotherapy based on utilitarian optimisation.
Ebert, M A; Li, W; Jennings, L
2014-03-01
The detrimental impact of a radiotherapy waiting list can in part be compensated by patient prioritisation. Such prioritisation is phrased as an optimisation problem where the probability of local control for the overall population is the objective to be maximised and a simple analytical solution derived. This solution is compared with a simulation of a waiting list for the same population of patients. It is found that the analytical solution can provide an optimal ordering of patients though cannot explicitly constrain optimal waiting times. The simulation-based solution was undertaken using both the analytical solution and a numerical optimisation routine for daily patient ordering. Both solutions provided very similar results with the analytical approach reducing the calculation time of the numerical solution by several orders of magnitude. It is suggested that treatment delays due to resource limitations and resulting waiting lists be incorporated into treatment optimisation and that the derived analytical solution provides a mechanism for this to occur.
Fundamentals and advanced techniques in derivatives hedging
Bouchard, Bruno
2016-01-01
This book covers the theory of derivatives pricing and hedging as well as techniques used in mathematical finance. The authors use a top-down approach, starting with fundamentals before moving to applications, and present theoretical developments alongside various exercises, providing many examples of practical interest. A large spectrum of concepts and mathematical tools that are usually found in separate monographs are presented here. In addition to the no-arbitrage theory in full generality, this book also explores models and practical hedging and pricing issues. Fundamentals and Advanced Techniques in Derivatives Hedging further introduces advanced methods in probability and analysis, including Malliavin calculus and the theory of viscosity solutions, as well as the recent theory of stochastic targets and its use in risk management, making it the first textbook covering this topic. Graduate students in applied mathematics with an understanding of probability theory and stochastic calculus will find this b...
Construction of Benchmark Problems for Solution of Ordinary Differential Equations
Directory of Open Access Journals (Sweden)
Sangchul Lee
1994-01-01
Full Text Available An inverse method is introduced to construct benchmark problems for the numerical solution of initial value problems. Benchmark problems constructed in this fashion have a known exact solution, even though analytical solutions are generally not obtainable. The process leading to the exact solution makes use of an initially available approximate numerical solution. A smooth interpolation of the approximate solution is forced to exactly satisfy the differential equation by analytically deriving a small forcing function to absorb all of the errors in the interpolated approximate solution. Using this special case exact solution, it is possible to directly investigate the relationship between global errors of a candidate numerical solution process and the associated tuning parameters for a given code and a given problem. Under the assumption that the original differential equation is well-posed with respect to the small perturbations, we thereby obtain valuable information about the optimal choice of the tuning parameters and the achievable accuracy of the numerical solution. Five illustrative examples are presented.
Portfolio Selection Model with Derivative Securities
Institute of Scientific and Technical Information of China (English)
王春峰; 杨建林; 蒋祥林
2003-01-01
Traditional portfolio theory assumes that the return rate of portfolio follows normality. However, this assumption is not true when derivative assets are incorporated. In this paper a portfolio selection model is developed based on utility function which can capture asymmetries in random variable distributions. Other realistic conditions are also considered, such as liabilities and integer decision variables. Since the resulting model is a complex mixed-integer nonlinear programming problem, simulated annealing algorithm is applied for its solution. A numerical example is given and sensitivity analysis is conducted for the model.
DEFF Research Database (Denmark)
Foss, Kirsten; Foss, Nicolai Juul; Klein, Peter G.
may delegate a wide range of decision rights to subordinates, who exercise derived judgment. We call these employees "proxy-entrepreneurs," and ask how the firm's or-ganizational structure — its formal and informal systems of rewards and punishments, rules for settling disputes and renegotiating...... develop a framework for analyzing the tradeoff between productive and de-structive proxy-entrepreneurship. We link this analysis to the employment relation and ownership structure, providing new insights into these and related issues in the eco-nomic theory of the firm.Keywords: Judgment, entrepreneur...
Food derived carcinogenic amnoimidazoazaarenes
DEFF Research Database (Denmark)
Frandsen, Henrik
Carcinogenic aminoimidazoazaarenes are formed during cooking of meat and fish. Important factors for the formation of these compounds are meat type, cooking temperature and time. The compounds are genotoxic in bacterial and mammalian cells. In animal feeding studies the compounds tested so far we...... of the exocyclic amino group. Estimations of human cancer risk have indicated that ingestion of food containing aminoimidazoazaarenes are of importance....... found to be multiple organ carcinogens. The aminoimidazoazaarenes are metabolically activated by hydroxylation of the exocyclic aminogroup to the N-hydroxyamino derivative. The resultant proximate mutagens often need further activation by phase II transferases for formation of reactive species that form...
Higher-Derivative Supergravity and Moduli Stabilization
Energy Technology Data Exchange (ETDEWEB)
Ciupke, David; Westphal, Alexander [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany). Theory Group; Louis, Jan [Hamburg Univ. (Germany). Fachberich Physik; Hamburg Univ. (Germany). Zentrum fuer Mathematische Physik
2015-05-15
We review the ghost-free four-derivative terms for chiral superfields in N=1 supersymmetry and supergravity. These terms induce cubic polynomial equations of motion for the chiral auxiliary fields and correct the scalar potential. We discuss the different solutions and argue that only one of them is consistent with the principles of effective field theory. Special attention is paid to the corrections along flat directions which can be stabilized or destabilized by the higher-derivative terms. We then compute these higher-derivative terms explicitly for the type IIB string compactified on a Calabi-Yau orientifold with fluxes via Kaluza-Klein reducing the (α'){sup 3}R{sup 4} corrections in ten dimensions for the respective N=1 Kaehler moduli sector. We prove that together with flux and the known (α'){sup 3}-corrections the higher-derivative term stabilizes all Calabi-Yau manifolds with positive Euler number, provided the sign of the new correction is negative.
Error Estimates for Approximate Solutions of the Riccati Equation with Real or Complex Potentials
Finster, Felix
2008-01-01
A method is presented for obtaining rigorous error estimates for approximate solutions of the Riccati equation, with real or complex potentials. Our main tool is to derive invariant region estimates for complex solutions of the Riccati equation. We explain the general strategy for applying these estimates and illustrate the method in typical examples, where the approximate solutions are obtained by glueing together WKB and Airy solutions of corresponding one-dimensional Schr"odinger equations.
Backlund Transformations and Solutions of a Generalized Kadomtsev-Petviashvili Equation
Institute of Scientific and Technical Information of China (English)
王云虎; 陈勇
2012-01-01
In this paper, the bilinear form of a generalized Kadomtsev-Petviashvili equation is obtained by applying the binary Bell polynomials. The N-soliton solution and one periodic wave solution are presented by use of the Hirota direct method and the Riemann theta function, respectively. And then the asymptotic analysis demonstrates one periodic wave solution can be reduced to one soliton solution. In the end, the bilinear Backlund transformations are derived.
Solutions of the generalized Weierstrass representation in four-dimensional Euclidean space
P. Bracken; Grundland, A. M.
2003-01-01
Several classes of solutions of the generalized Weierstrass system, which induces constant mean curvature surfaces into four-dimensional Euclidean space are constructed. A gauge transformation allows us to simplify the system considered and derive factorized classes of solutions. A reduction of the generalized Weierstrass system to decoupled CP^1 sigma models is also considered. A new procedure for constructing certain classes of solutions, including elementary solutions (kinks and bumps) and...
Explicit analytical solutions of the coupled differential equations for porous material drying
Institute of Scientific and Technical Information of China (English)
蔡睿贤; 张娜
2000-01-01
Some explicit analytical solutions are derived for the coupled partial differential equation set describ-ing porous material drying with two extraordinary methods proposed by the authors, I.e. The method of separating vari-ables by addition and the method of evaluating the source term in reverse order. Besides their theoretical meaning, these solutions can also be the standard solutions for the computational solutions of heat and mass transfer.
Probabilistic solution of relative entropy weighted control
Bierkens, Joris
2012-01-01
We show that stochastic control problems with a particular cost structure involving a relative entropy term admit a purely probabilistic solution, without the necessity of applying the dynamic programming principle. The argument is as follows. Minimization of the expectation of a random variable with respect to the underlying probability measure, penalized by relative entropy, may be solved exactly. In the case where the randomness is generated by a standard Brownian motion, this exact solution can be written as a Girsanov density. The stochastic process appearing in the Girsanov exponent has the role of control process, and the relative entropy of the change of probability measure is equal to the integral of the square of this process. An explicit expression for the control process may be obtained in terms of the Malliavin derivative of the density process. The theory is applied to the problem of minimizing the maximum of a Brownian motion (penalized by the relative entropy), leading to an explicit expressio...
Maximally supersymmetric solutions of $R^2$ supergravity
Kuzenko, Sergei M
2016-01-01
There are five maximally supersymmetric backgrounds in four-dimensional off-shell N=1 supergravity, two of which are well known: Minkowski superspace M^{4|4} and anti-de Sitter superspace AdS^{4|4}. The three remaining supermanifolds support spacetimes of different topology, which are: R x S^3, AdS_3 x R, and a supersymmetric plane wave isometric to the Nappi-Witten group. As is well known, the Minkowski and anti-de Sitter superspaces are solutions of the Poincar\\'e and anti-de Sitter supergravity theories, respectively. Here we demonstrate that the other three superspaces are solutions of no-scale $R^2$ supergravity. We also present a new (probably the simplest) derivation of the maximally supersymmetric backgrounds of off-shell N=1 supergravity.
A numerical evaluation and regularization of Caputo fractional derivatives
Energy Technology Data Exchange (ETDEWEB)
Li Ming; Wang, Y J [Department of Mathematics, Taiyuan University of Technology, Shanxi (China); Xiong, X T [College of Mathematics and Information Science, Northwest Normal University, Gansu (China)
2011-04-01
Numerical evaluations of Caputo fractional derivatives for scattered noisy data is an important problem in scientific research and practical applications. Fractional derivatives have been applied recently to the numerical solution of problems in fluid and continuum mechanics. The Caputo fractional derivative of order {alpha} is given as follows (formula). The above definition includes a Volterra integral equation with weakly singular kernels and difficult to calculate. In this paper, a faster convergence numerical schedule is given and applied to solve several fractional-diffusion heat conduction problems. Convergence rates of interest are also presented here. Several numerical results are given to show the effectiveness of the proposed numerical schedule.
Mungan, Carl E.
2016-05-01
At the 2015 AAPT Summer Meeting, I presented four derivations of the formula for motional emf. Such physics derivations involve the construction of explanatory frameworks involving diagrams and mathematical models. Although textbooks devote considerable space to such explanations, many teachers and students spend their time on worksheets, end-of-chapter problems, and the like. The book is reduced to a bank of solved (i.e., example) and unsolved (i.e., homework) questions, along with equations in colored boxes that presumably are to be used to answer those questions. Such an approach encourages fragmentation of knowledge, the view that there is only one right answer to a problem with the goal of physics being to find that answer (neatly boxed of course), and the inability to reason about even a slightly different (much less a novel) situation. If we are to develop scientific literacy, significant course time must be devoted to explaining the structure of and support for the models and equations we use.
Viscoelasticity of mixed polyacrylamide solution
Institute of Scientific and Technical Information of China (English)
徐丽娜
2008-01-01
The viscoelastic behavior of polyacrylamide solution is crucial for its application in various industries.The mixed polyacrylamide solution was prepared by mixing polyacrylamide with different relative molecular masses according to the defined mass fraction.The viscosity and elasticity of mixed polyacrylamide solution were separately tested with RS150 rheometer and capillary breakup extensional rheometer and compared with those of the single polyacrylamide solution which is directly provided by manufacturer without any mixing.The results indicate that the mixed and single polyacrylamide solutions have the same shear viscosity and intrinsic viscosity.However,some mixed polyacrylamide solutions have higher elasticity than single polyacrylamide solution.The flow resistance of mixed polyacrylamide with higher elasticity is also greater than that of single polyacrylamide solution in porous medium.This paper presents an effective method of mixing polyacrylamides with different relative molecular masses,which can enhance the elasticity of polyacrylamide solution and flowing resistance through porous medium.
Charged Vaidya solution satisfies weak energy condition
Chatterjee, Soumyabrata; Ganguli, Suman; Virmani, Amitabh
2016-07-01
The external matter stress-tensor supporting charged Vaidya solution appears to violate weak energy condition in certain region of the spacetime. Motivated by this, a new interpretation of charged Vaidya solution was proposed by Ori (Class Quant Grav 8:1559, 1991) in which the energy condition continues to be satisfied. In this construction, one glues an outgoing Vaidya solution to the original ingoing Vaidya solution provided the surface where the external stress-tensor vanishes is spacelike. We revisit this study and extend it to higher-dimensions, to AdS settings, and to higher-derivative f( R) theories. In asymptotically flat space context, we explore in detail the case when the mass function m( v) is proportional to the charge function q( v). When the proportionality constant ν = q(v)/m(v) lies in between zero and one, we show that the surface where the external stress-tensor vanishes is spacelike and lies in between the inner and outer apparent horizons.
Analysis of the Keller–Segel Model with a Fractional Derivative without Singular Kernel
Directory of Open Access Journals (Sweden)
Abdon Atangana
2015-06-01
Full Text Available Using some investigations based on information theory, the model proposed by Keller and Segel was extended to the concept of fractional derivative using the derivative with fractional order without singular kernel recently proposed by Caputo and Fabrizio. We present in detail the existence of the coupled-solutions using the fixed-point theorem. A detailed analysis of the uniqueness of the coupled-solutions is also presented. Using an iterative approach, we derive special coupled-solutions of the modified system and we present some numerical simulations to see the effect of the fractional order.
Generalized Derivations and Bilocal Jordan Derivations of Nest Algebras
Directory of Open Access Journals (Sweden)
Dangui Yan
2011-01-01
Full Text Available Let H be a complex Hilbert space and B(H the collection of all linear bounded operators, A is the closed subspace lattice including 0 an H, then A is a nest, accordingly alg A={T∈B(H:TN⊆N, ∀N∈A} is a nest algebra. It will be shown that of nest algebra, generalized derivations are generalized inner derivations, and bilocal Jordan derivations are inner derivations.
Rapid Regional Centroid Solutions
Wei, S.; Zhan, Z.; Luo, Y.; Ni, S.; Chen, Y.; Helmberger, D. V.
2009-12-01
The 2008 Wells Nevada Earthquake was recorded by 164 broadband USArray stations within a distance of 550km (5 degrees) with all azimuths uniformly sampled. To establish the source parameters, we applied the Cut and Paste (CAP) code to all the stations to obtain a mechanism (strike/dip/rake=35/41/-85) at a depth of 9km and Mw=5.9. Surface wave shifts range from -8s to 8s which are in good agreement with ambient seismic noise (ASN) predictions. Here we use this data set to test the accuracy of the number of stations needed to obtain adequate solutions (position of the compressional and tension axis) for mechanism. The stations were chosen at random where combinations of Pnl and surface waves were used to establish mechanism and depth. If the event is bracketed by two stations, we obtain an accurate magnitude with good solutions about 80% of the trials. Complete solutions from four stations or Pnl from 10 stations prove reliable in nearly all situations. We also explore the use of this dataset in locating the event using a combination of surface wave travel times and/or the full waveform inversion (CAPloc) that uses the CAP shifts to refine locations. If the mechanism is known (fixed) only a few stations is needed to locate an event to within 5km if date is available at less than 150km. In contrast, surface wave travel times (calibrated to within one second) produce amazing accurate locations with only 6 stations reasonably distributed. It appears this approach is easily automated as suggested by Scrivner and Helmberger (1995) who discussed travel times of Pnl and surface waves and the evolving of source accuracy as the various phases arrive.
Periodic solutions and flip bifurcation in a linear impulsive system
Institute of Scientific and Technical Information of China (English)
Jiang Gui-Rong; Yang Qi-Gui
2008-01-01
In this paper,the dynamical behaviour of a linear impulsive system is discussed both theoretically and numerically.The existence and the stability of period-one solution are discussed by using a discrete map.The conditions of existence for flip bifurcation are derived by using the centre manifold theorem and bifurcation theorem.The bifurcation analysis shows that chaotic solutions appear via a cascade of period-doubling in some interval of parameters.Moreover,the periodic solutions,the bifurcation diagram,and the chaotic attractor,which show their consistence with the theoretical analyses,are given in an example.中图分类:O547
Adjoint P1 equations solution for neutron slowing down
International Nuclear Information System (INIS)
In some applications of perturbation theory, it is necessary know the adjoint neutron flux, which is obtained by the solution of adjoint neutron diffusion equation. However, the multigroup constants used for this are weighted in only the direct neutron flux, from the solution of direct P1 equations. In this work, the adjoint P1 equations are derived by the neutron transport equation, the reversion operators rules and analogies between direct and adjoint parameters. The direct and adjoint neutron fluxes resulting from the solution of P1 equations were used to three different weighting processes, to obtain the macrogroup macroscopic cross sections. It was found out noticeable differences among them. (author)
Fast multigrid solution of the advection problem with closed characteristics
Energy Technology Data Exchange (ETDEWEB)
Yavneh, I. [Israel Inst. of Technology, Haifa (Israel); Venner, C.H. [Univ. of Twente, Enschede (Netherlands); Brandt, A. [Weizmann Inst. of Science, Rehovot (Israel)
1996-12-31
The numerical solution of the advection-diffusion problem in the inviscid limit with closed characteristics is studied as a prelude to an efficient high Reynolds-number flow solver. It is demonstrated by a heuristic analysis and numerical calculations that using upstream discretization with downstream relaxation-ordering and appropriate residual weighting in a simple multigrid V cycle produces an efficient solution process. We also derive upstream finite-difference approximations to the advection operator, whose truncation terms approximate {open_quotes}physical{close_quotes} (Laplacian) viscosity, thus avoiding spurious solutions to the homogeneous problem when the artificial diffusivity dominates the physical viscosity.
Total Logistic Plant Solutions
Directory of Open Access Journals (Sweden)
Dusan Dorcak
2016-02-01
Full Text Available The Total Logistics Plant Solutions, plant logistics system - TLPS, based on the philosophy of advanced control processes enables complex coordination of business processes and flows and the management and scheduling of production in the appropriate production plans and planning periods. Main attributes of TLPS is to create a comprehensive, multi-level, enterprise logistics information system, with a certain degree of intelligence, which accepts the latest science and research results in the field of production technology and logistics. Logistic model of company understands as a system of mutually transforming flows of materials, energy, information, finance, which is realized by chain activities and operations
Radiographic solution contamination.
Hardman, P K; Tilmon, M F; Taylor, T S
1987-06-01
Contamination of processor solutions adversely affects the image quality of radiographic films. The purpose of this study was to determine the amount of developer or fixer contaminant that was necessary to produce a significant densitometric change in the base plus fog, speed, or contrast optical density readings for panoramic film. Significant differences in base plus fog (after 16 mL of fixer contaminant was added to developer), speed index (after 4 mL), and contrast index (after 8 mL) were observed in comparison with control values. PMID:3473399
Energy Technology Data Exchange (ETDEWEB)
Jewulski, J.
1983-08-15
The subject of the invention is a micellar solution used in oil extraction when flooding a deposit and washing out the critical zone. It contains ethanolamine salt of alkylobenzolsulfonic acid (10 to 56 percent by mass), higher alcohol (4 to 56 percent) an organic solvent and water (2.4 to 57.2 percent) and is distinguished by the fact that an amyl alcohol of the third series is used as the higher alcohol, while oil in a volume of 19 to 71 percent or gasoline in a volume of 6 to 16 percent) is used as the solvent.
Anisotropic Stars Exact Solutions
Dev, K; Dev, Krsna; Gleiser, Marcelo
2000-01-01
We study the effects of anisotropic pressure on the properties of spherically symmetric, gravitationally bound objects. We consider the full general relativistic treatment of this problem and obtain exact solutions for various form of equations of state connecting the radial and tangential pressures. It is shown that pressure anisotropy can have significant effects on the structure and properties of stellar objects. In particular, the maximum value of 2M/R can approach unity (2M/R < 8/9 for isotropic objects) and the surface redshift can be arbitrarily large.
Solution and Positive Solution to Nonlinear Cantilever Beam Equations
Institute of Scientific and Technical Information of China (English)
无
2008-01-01
Using the decomposition technique of equation and the fixed point theorem, the existence of solution and positive solution is studied for a nonlinear cantilever beam equation. The equation describes the deformation of the elastic beam with a fixed end and a free end. The main results show that the equation has at least one solution or positive solution, provided that the "height" of nonlinear term is appropriate on a bounded set.
Vacuum solutions with double duality properties of a quadratic Poincare gauge field theory
International Nuclear Information System (INIS)
We look for exact vacuum solutions of the gauge theory of the Poincare group with a lagrangian quadratic in torsion and curvature. First we find the trivial spherically symmetric solutions with vanishing torsion, also known from the Stephenson-Kilmister-Yang gravitational theory. Then, by means of a double duality ansatz for the curvature, we derive in a systematic way three different spherically symmetric vacuum solutions with dynamic torsion, all giving rise to a Schwarzschild-de Sitter metric with a fixed ''cosmological'' constant. We rederive the Baekler solution, find a time-reflected ''anti-Baekler'' solution, and discover a new solution with non-vanishing translational and rotational energy. (author)
Approximate analytical solutions to the condensation-coagulation equation of aerosols
Smith, Naftali; Svensmark, Henrik
2015-01-01
We present analytical solutions to the steady state injection-condensation-coagulation equation of aerosols in the atmosphere. These solutions are appropriate under different limits but more general than previously derived analytical solutions. For example, we provide an analytic solution to the coagulation limit plus a condensation correction. Our solutions are then compared with numerical results. We show that the solutions can be used to estimate the sensitivity of the cloud condensation nuclei number density to the nucleation rate of small condensation nuclei and to changes in the formation rate of sulfuric acid.
A generic travelling wave solution in dissipative laser cavity
Indian Academy of Sciences (India)
BALDEEP KAUR; SOUMENDU JANA
2016-10-01
A large family of cosh-Gaussian travelling wave solution of a complex Ginzburg–Landau equation (CGLE), that describes dissipative semiconductor laser cavity is derived. Using perturbation method, the stability region is identified. Bifurcation analysis is done by smoothly varying the cavity loss coefficient to provide insight of the system dynamics. He’s variational method is adopted to obtain the standard sech-type and the notso-explored but promising cosh-Gaussian type, travelling wave solutions. For a given set of system parameters, only one sech solution is obtained, whereas several distinct solution points are derived for cosh-Gaussian case. These solutions yield a wide variety of travelling wave profiles, namely Gaussian, near-sech, flat-top and a cosh-Gaussian with variable central dip. A split-step Fourier method and pseudospectral method have been used for direct numerical solution of the CGLE and travelling wave profiles identical to the analytical profiles have been obtained. We also identified the parametric zone that promises an extremely large family of cosh-Gaussian travelling wave solutions with tunable shape. This suggests that the cosh-Gaussian profile is quite generic and would be helpful for further theoretical as well as experimental investigation on pattern formation, pulse dynamics and localization in semiconductor laser cavity.
Deriving covariant holographic entanglement
Dong, Xi; Rangamani, Mukund
2016-01-01
We provide a gravitational argument in favour of the covariant holographic entanglement entropy proposal. In general time-dependent states, the proposal asserts that the entanglement entropy of a region in the boundary field theory is given by a quarter of the area of a bulk extremal surface in Planck units. The main element of our discussion is an implementation of an appropriate Schwinger-Keldysh contour to obtain the reduced density matrix (and its powers) of a given region, as is relevant for the replica construction. We map this contour into the bulk gravitational theory, and argue that the saddle point solutions of these replica geometries lead to a consistent prescription for computing the field theory Renyi entropies. In the limiting case where the replica index is taken to unity, a local analysis suffices to show that these saddles lead to the extremal surfaces of interest. We also comment on various properties of holographic entanglement that follow from this construction.
Zoology of instanton solutions in flat potential barriers
Battarra, Lorenzo; Lehners, Jean-Luc
2013-01-01
We perform a detailed study of the existence and the properties of O(4)-invariant instanton solutions in Einstein-scalar theory in the presence of flat potential barriers, i.e. barriers where the second derivative of the potential is small at the top of the barrier. We find a whole zoo of solutions: Hawking-Moss, Coleman-De Luccia (CdL), oscillating instantons, asymmetric CdL as well as other non-standard CdL-like solutions with additional negative modes in their spectrum of fluctuations. Our work shows how these different branches of solutions are connected to each other via "critical" instantons possessing an extra zero mode fluctuation. Overall, the space of finite action euclidean solutions to these theories with flat barriers is surprisingly rich and intricate.
Attractor Solutions in Lorentz Violating Scalar-Vector-Tensor Theory
Arianto, Freddy P; Triyanta,; Gunara, Bobby E
2008-01-01
We investigate properties of attractors for scalar field in the Lorentz violating scalar-vector-tensor theory of gravity. In this framework, both the effective coupling and potential functions determine the stabilities of the fixed points. In the model, we consider the constants of slope of the effective coupling and potential functions which lead to the quadratic effective coupling vector with the (inverse) power-law potential. For the case of purely scalar field, there are only two stable attractor solutions in the inflationary scenario. In the presence of a barotropic fluid, the fluid dominated solution is absent. We find two scaling solutions: the kinetic scaling solution and the scalar field scaling solutions. We show the stable attractors in regions of ($\\gamma$, $\\xi$) parameter space and in phase plane plot for different qualitative evolutions. From the standard nucleosynthesis, we derive the constraints for the value of the coupling parameter.
Solutions of two-factor models with variable interest rates
Li, Jinglu; Clemons, C. B.; Young, G. W.; Zhu, J.
2008-12-01
The focus of this work is on numerical solutions to two-factor option pricing partial differential equations with variable interest rates. Two interest rate models, the Vasicek model and the Cox-Ingersoll-Ross model (CIR), are considered. Emphasis is placed on the definition and implementation of boundary conditions for different portfolio models, and on appropriate truncation of the computational domain. An exact solution to the Vasicek model and an exact solution for the price of bonds convertible to stock at expiration under a stochastic interest rate are derived. The exact solutions are used to evaluate the accuracy of the numerical simulation schemes. For the numerical simulations the pricing solution is analyzed as the market completeness decreases from the ideal complete level to one with higher volatility of the interest rate and a slower mean-reverting environment. Simulations indicate that the CIR model yields more reasonable results than the Vasicek model in a less complete market.
Analytical Solution for the Current Distribution in Multistrand Superconducting Cables
Bottura, L; Fabbri, M G
2002-01-01
Current distribution in multistrand superconducting cables can be a major concern for stability in superconducting magnets and for field quality in particle accelerator magnets. In this paper we describe multistrand superconducting cables by means of a distributed parameters circuit model. We derive a system of partial differential equations governing current distribution in the cable and we give the analytical solution of the general system. We then specialize the general solution to the particular case of uniform cable properties. In the particular case of a two-strand cable, we show that the analytical solution presented here is identical to the one already available in the literature. For a cable made of N equal strands we give a closed form solution that to our knowledge was never presented before. We finally validate the analytical solution by comparison to numerical results in the case of a step-like spatial distribution of the magnetic field over a short Rutherford cable, both in transient and steady ...
Analytical solution for soil water redistribution during evaporation process.
Teng, Jidong; Yasufuku, Noriyuki; Liu, Qiang; Liu, Shiyu
2013-01-01
Simulating the dynamics of soil water content and modeling soil water evaporation are critical for many environmental and agricultural strategies. The present study aims to develop an analytical solution to simulate soil water redistribution during the evaporation process. This analytical solution was derived utilizing an exponential function to describe the relation of hydraulic conductivity and water content on pressure head. The solution was obtained based on the initial condition of saturation and an exponential function to model the change of surface water content. Also, the evaporation experiments were conducted under a climate control apparatus to validate the theoretical development. Comparisons between the proposed analytical solution and experimental result are presented from the aspects of soil water redistribution, evaporative rate and cumulative evaporation. Their good agreement indicates that this analytical solution provides a reliable way to investigate the interaction of evaporation and soil water profile. PMID:24355839
General solutions and causality for a Voigt medium
Energy Technology Data Exchange (ETDEWEB)
Duren, R.E.; Heestand, R.L. [Exxon Production Co., Houston, TX (United States)
1995-01-01
A 1-D wave equation solution for a propagating seismic pulse in a Voigt medium can be obtained by using a separation of variables to find time harmonic particular solutions and then superimposing the particular solutions. This superposition is a time convolution of the boundary condition (or incident pulse) and the medium`s impulse response. Even though causality is not introduced during the solution of the wave equation, the general solution is causal since the boundary condition is causal and the medium`s impulse response can be shown to be causal. The relationship between attenuation and phase velocity as well as their dependence on frequency arise from the form chosen for the particular solutions. The arbitrary constants associated with the particular solutions are determined by the boundary condition, and the initial condition is also dependent on the boundary condition; however, the initial condition is properly determined and does not depend on times after the initial time (thereby satisfying causality). The convolutional nature of the general solution allows it to also be expressed as a time convolution of the boundary conditions`s time derivative and the medium`s step function response. This expression can be viewed as a superposition of step function responses where the step function response is a particular solution to the wave equation obtained using an approach that is similar to one recently developed for propagating electric pulses. This new solution is obtained with the initial and boundary conditions being independently introduced during the solution of the wave equation. There is no frequency dependence in this solution, and the general solution is causal since it is a superposition of causal step function responses.
Amino acid derived 1,4-dialkyl substituted imidazolones
DEFF Research Database (Denmark)
Diness, Frederik; Meldal, Morten Peter
2010-01-01
A general method for synthesis of 1,4-substituted imidazolones from amino acids on solid support or in solution has been developed. Amino acid derived 3-Boc-(1,3)-oxazinane (Box) protected amino aldehyde building blocks were coupled through urea bonds to the amino terminal of dipeptides or amino ...
Ultradiscrete soliton equations derived from ultradiscrete permanent formulae
Energy Technology Data Exchange (ETDEWEB)
Nakamura, Shinya, E-mail: s-nakamura@moegi.waseda.jp [Major in Pure and Applied Mathematics, Graduate School of Fundamental Science and Engineering, Waseda University, 3-4-1, Okubo, Shinjuku-ku, Tokyo 169-8555 (Japan)
2011-07-22
We propose formulae of ultradiscrete permanent. Utilizing the formulae, ultradiscrete soliton equations and their multi-soliton solutions are obtained by a simple process. Changing variables and parameters of the formulae, we can derive the ultradiscrete Toda, KdV and hungry Lotka-Volterra equations. An extended version of the ultradiscrete hungry Lotka-Volterra equation is also proposed.
Weighted norm inequalities for derivatives and their applications
Nguyen Du Vi, Nhan; Dinh Thanh, Duc; Vu Kim, Tuan
2013-01-01
In this paper we establish several weighted norm inequalities for derivatives of products of composition and Laplace convolution of functions. Some generalizations including Yamada's and Opial-type inequalities are discussed. As applications we give Lp-weighted estimates for solutions of some integral equations.
Energy Technology Data Exchange (ETDEWEB)
Jahan, Kauser [Rowan Univ., Glassboro, NJ (United States)
2015-03-31
One of the most promising fuel alternatives is algae biodiesel. Algae reproduce quickly, produce oils more efficiently than crop plants, and require relatively few nutrients for growth. These nutrients can potentially be derived from inexpensive waste sources such as flue gas and wastewater, providing a mutual benefit of helping to mitigate carbon dioxide waste. Algae can also be grown on land unsuitable for agricultural purposes, eliminating competition with food sources. This project focused on cultivating select algae species under various environmental conditions to optimize oil yield. Membrane studies were also conducted to transfer carbon di-oxide more efficiently. An LCA study was also conducted to investigate the energy intensive steps in algae cultivation.
DEFF Research Database (Denmark)
Paradelo Pérez, Marcos; Katuwal, Sheela; Møldrup, Per;
The characterization of soil pore space geometry is important to predict the fluxes of air, water and solutes through soil and understand soil hydrogeochemical functions. X-ray computed tomography (CT) -derived parameters were evaluated as predictors of water, air and solute transport through soil...... the potential of X-ray CT visualization techniques for estimating fluxes through soil....
Experts' understanding of partial derivatives using the partial derivative machine
Roundy, David; Weber, Eric; Dray, Tevian; Bajracharya, Rabindra R.; Dorko, Allison; Smith, Emily M.; Manogue, Corinne A.
2015-12-01
[This paper is part of the Focused Collection on Upper Division Physics Courses.] Partial derivatives are used in a variety of different ways within physics. Thermodynamics, in particular, uses partial derivatives in ways that students often find especially confusing. We are at the beginning of a study of the teaching of partial derivatives, with a goal of better aligning the teaching of multivariable calculus with the needs of students in STEM disciplines. In this paper, we report on an initial study of expert understanding of partial derivatives across three disciplines: physics, engineering, and mathematics. We report on the central research question of how disciplinary experts understand partial derivatives, and how their concept images of partial derivatives differ, with a focus on experimentally measured quantities. Using the partial derivative machine (PDM), we probed expert understanding of partial derivatives in an experimental context without a known functional form. In particular, we investigated which representations were cued by the experts' interactions with the PDM. Whereas the physicists and engineers were quick to use measurements to find a numeric approximation for a derivative, the mathematicians repeatedly returned to speculation as to the functional form; although they were comfortable drawing qualitative conclusions about the system from measurements, they were reluctant to approximate the derivative through measurement. On a theoretical front, we found ways in which existing frameworks for the concept of derivative could be expanded to include numerical approximation.
An interacting dark energy model with nonminimal derivative coupling
Nozari, Kourosh; Behrouz, Noushin
2016-09-01
We study cosmological dynamics of an extended gravitational theory that gravity is coupled non-minimally with derivatives of a dark energy component and there is also a phenomenological interaction between the dark energy and dark matter. Depending on the direction of energy flow between the dark sectors, the phenomenological interaction gets two different signs. We show that this feature affects the existence of attractor solution, the rate of growth of perturbations and stability of the solutions. By considering an exponential potential as a self-interaction potential of the scalar field, we obtain accelerated scaling solutions that are attractors and have the potential to alleviate the coincidence problem. While in the absence of the nonminimal derivative coupling there is no attractor solution for phantom field when energy transfers from dark matter to dark energy, we show an attractor solution exists if one considers an explicit nonminimal derivative coupling for phantom field in this case of energy transfer. We treat the cosmological perturbations in this setup with details to show that with phenomenological interaction, perturbations can grow faster than the minimal case.
Institute of Scientific and Technical Information of China (English)
欧阳密; 吴启超; 余振伟; 李洪飞; 张诚
2014-01-01
Two novel potential solution-processed blue fluorescent emitters composed of a core fluorene-diphenylamine unit capped with either anthracene (FAn) or pyrene (FPy) were synthesized and characterized. They were both soluble in common organic solvents and solutions gave smooth films after spin coating. Their optical properties in solution and in the film were investigated by UV-visible and photoluminescence (PL) spectroscopy. The PL emission maximum of FAn and FPy in the film state were found to be 449 and 465 nm, respectively. The electrochemical properties of the as-prepared samples were studied by cyclic voltammetry. The estimated highest occupied molecular orbital (HOMO) energy levels were-5.37 and-5.36 eV for FAn and FPy, respectively. These results indicate that the introduction of diphenylamine effectively prevents plane stacking of the molecules in the solid state, which suppresses the formation of long-wavelength aggregates, and the high HOMO levels enhance the hole-injection ability of the compounds. The results of differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) indicate that the two materials have excellent thermal stability with the glass transition temperature of FAn reaching 207 °C and the thermal decomposition temperature as high as 439 ° C. The good performance of the fluorescent emitters makes them promising candidates as solution-processed blue organic light-emitting diodes.%合成了两类分别基于芘和蒽封端的芴-芳胺衍生物(FAn, FPy)的新型可溶液加工蓝色发光分子,两种材料均溶于常规的有机溶剂,并且可以旋涂成膜.通过紫外-可见光谱和荧光光谱对其在溶液中和固态薄膜下的光学性能进行了表征,发现这两类分子在固态下发射峰分别位于449和465 nm,属于蓝色发光材料.并通过循环伏安法表征了其电化学性能,计算得出FAn和FPy的最高占据分子轨道(HOMO)能级分别为-5.37和-5.36 eV.结果表明N-己基二苯胺
Frankenstein's glue: transition functions for approximate solutions
Energy Technology Data Exchange (ETDEWEB)
Yunes, Nicolas [Center for Gravitational Wave Physics, Institute for Gravitational Physics and Geometry, Department of Physics, Pennsylvania State University, University Park, PA 16802-6300 (United States)
2007-09-07
Approximations are commonly employed to find approximate solutions to the Einstein equations. These solutions, however, are usually only valid in some specific spacetime region. A global solution can be constructed by gluing approximate solutions together, but this procedure is difficult because discontinuities can arise, leading to large violations of the Einstein equations. In this paper, we provide an attempt to formalize this gluing scheme by studying transition functions that join approximate analytic solutions together. In particular, we propose certain sufficient conditions on these functions and prove that these conditions guarantee that the joined solution still satisfies the Einstein equations analytically to the same order as the approximate ones. An example is also provided for a binary system of non-spinning black holes, where the approximate solutions are taken to be given by a post-Newtonian expansion and a perturbed Schwarzschild solution. For this specific case, we show that if the transition functions satisfy the proposed conditions, then the joined solution does not contain any violations to the Einstein equations larger than those already inherent in the approximations. We further show that if these functions violate the proposed conditions, then the matter content of the spacetime is modified by the introduction of a matter shell, whose stress-energy tensor depends on derivatives of these functions.
Time-periodic solutions of the Benjamin-Ono equation
Energy Technology Data Exchange (ETDEWEB)
Ambrose , D.M.; Wilkening, Jon
2008-04-01
We present a spectrally accurate numerical method for finding non-trivial time-periodic solutions of non-linear partial differential equations. The method is based on minimizing a functional (of the initial condition and the period) that is positive unless the solution is periodic, in which case it is zero. We solve an adjoint PDE to compute the gradient of this functional with respect to the initial condition. We include additional terms in the functional to specify the free parameters, which, in the case of the Benjamin-Ono equation, are the mean, a spatial phase, a temporal phase and the real part of one of the Fourier modes at t = 0. We use our method to study global paths of non-trivial time-periodic solutions connecting stationary and traveling waves of the Benjamin-Ono equation. As a starting guess for each path, we compute periodic solutions of the linearized problem by solving an infinite dimensional eigenvalue problem in closed form. We then use our numerical method to continue these solutions beyond the realm of linear theory until another traveling wave is reached (or until the solution blows up). By experimentation with data fitting, we identify the analytical form of the solutions on the path connecting the one-hump stationary solution to the two-hump traveling wave. We then derive exact formulas for these solutions by explicitly solving the system of ODE's governing the evolution of solitons using the ansatz suggested by the numerical simulations.
Stationary and axisymmetric solutions of higher-dimensional general relativity
International Nuclear Information System (INIS)
We study stationary and axisymmetric solutions of General Relativity, i.e., pure gravity, in four or higher dimensions. D-dimensional stationary and axisymmetric solutions are defined as having D-2 commuting Killing vector fields. We derive a canonical form of the metric for such solutions that effectively reduces the Einstein equations to a differential equation on an axisymmetric D-2 by D-2 matrix field living in three-dimensional flat space (apart from a subclass of solutions that instead reduce to a set of equations on a D-2 by D-2 matrix field living in two-dimensional flat space). This generalizes the Papapetrou form of the metric for stationary and axisymmetric solutions in four dimensions, and furthermore generalizes the work on Weyl solutions in four and higher dimensions. We analyze then the sources for the solutions, which are in the form of thin rods along a line in the three-dimensional flat space that the matrix field can be seen to live in. As examples of stationary and axisymmetric solutions, we study the five-dimensional rotating black hole and the rotating black ring, write the metrics in the canonical form and analyze the structure of the rods for each solution
R.J. Stroeker (Roel)
2002-01-01
textabstractA Q-derived polynomial is a univariate polynomial, defined over the rationals, with the property that its zeros, and those of all its derivatives are rational numbers. There is a conjecture that says that Q-derived polynomials of degree 4 with distinct roots for themselves and all their
Stability of multi-compacton solutions and Backlund transformation in K(m,n,1)
International Nuclear Information System (INIS)
We introduce a fifth-order K(m,n,1) equation with nonlinear dispersion to obtain multi-compacton solutions by Adomian decomposition method. Using the homogeneous balance (HB) method, we derive a Backlund transformation of a special equation K(2,2,1) to determine some solitary solutions of the equation. To study the stability of multi-compacton solutions in K(m,n,1) and to obtain some conservation laws, we present a similar fifth-order equation derived from Lagrangian. We finally show the linear stability of all obtained multi-compacton solutions
Pan, Li-Hua; Hou, Peng-Fei; Chen, Jia-Yun
2016-08-01
The 2D steady-state solutions regarding the expressions of stress and strain for fluid-saturated, orthotropic, poroelastic plane are derived in this paper. For this object, the general solutions of the corresponding governing equation are first obtained and expressed in harmonic functions. Based on these compact general solutions, the suitable harmonic functions with undetermined constants for line fluid source in the interior of infinite poroelastic body and a line fluid source on the surface of semi-infinite poroelastic body are presented, respectively. The fundamental solutions can be obtained by substituting these functions into the general solution, and the undetermined constants can be obtained by the continuous conditions, equilibrium conditions and boundary conditions.
REFERENCE ARCHITECTURE FOR SMAC SOLUTIONS
Directory of Open Access Journals (Sweden)
Shankar Kambhampaty
2016-01-01
Full Text Available Web and internet computing is evolving into a combination of social media, mobile, analytics and cloud (SMAC solutions. There is a need for an integrated approach when developing solutions that address web scale requirements with technologies that enable SMAC solutions. This paper presents an architecture model for the integrated approach that can form the basis for solutions and result in reuse, integration and agility for the business and IT in an enterprise.
General Solution for the Static, Spherical and Asymptotically Flat Braneworld
Akama, Keiichi; Mukaida, Hisamitsu
2011-01-01
The general solution for the static, spherical and asymptotically flat braneworld is derived by solving the bulk Einstein equation and braneworld dynamics. We show that it involves a large arbitrariness, which reduces the predictability of the theories. Ways out of the difficulty are discussed.
An exact solution of Haugan's binary pulsar equation of motion
Weinstein, M.; Mor, A.
1988-05-01
In his work on the post-Newtonian arrival-time analysis for a pulsary binary system, Haugan (1985) derived and integrated the two-body equation of the motion of the pulsar. The purpose of the present study is to show that there is an exact solution to this nonlinear equation, without any need of far-reaching assumptions and neglected nonlinear terms.
Organisation and shape of micellar solutions of block-copolymers
Gaspard, J.P.; Creutz, S.; Bouchat, P.; Jerome, R.; Cohen Stuart, M.A.
1997-01-01
Diblock copolymers of polymethacrylic acid sodium salt, forming the hair, and styrene derivatives have been studied in aqueous solutions by SANS and SAXS. The influence of both the chemical nature and the length of the hydrophobic bloxk on the size and shape of micelles have been investigated. The m