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Sample records for bacteria-free solution derived

  1. ANALYTIC SOLUTION AND NUMERICAL SOLUTION TO ENDOLYMPH EQUATION USING FRACTIONAL DERIVATIVE

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    In this paper,we study the solution to the endolymph equation using the fractional derivative of arbitrary orderλ(0<λ<1).The exact analytic solution is given by using Laplace transform in terms of Mittag-Leffler functions.We then evaluate the approximate numerical solution using MATLAB.

  2. Photodegradation in Micellar Aqueous Solutions of Erythrosin Esters Derivatives.

    Science.gov (United States)

    Herculano, Leandro Silva; Lukasievicz, Gustavo Vinicius Bassi; Sehn, Elizandra; Caetano, Wilker; Pellosi, Diogo Silva; Hioka, Noboru; Astrath, Nelson Guilherme Castelli; Malacarne, Luis Carlos

    2015-07-01

    Strong light absorption and high levels of singlet oxygen production indicate erythrosin B as a viable candidate as a photosensitizer in photodynamic therapy or photodynamic inactivation of microorganisms. Under light irradiation, erythrosin B undergoes a photobleaching process that can decrease the production of singlet oxygen. In this paper, we use thermal lens spectroscopy to investigate photobleaching in micellar solutions of erythrosin ester derivatives: methyl, butyl, and decyl esters in low concentrations of non-ionic micellar aqueous solutions. Using a previously developed thermal lens model, it was possible to determine the photobleaching rate and fluorescence quantum efficiency for dye-micelle solutions. The results suggest that photobleaching is related to the intensity of the dye-micelle interaction and demonstrate that the thermal lens technique can be used as a sensitive tool for quantitative measurement of photochemical properties in very diluted solutions.

  3. Solution to the ghost problem in fourth order derivative theories

    CERN Document Server

    Mannheim, P D

    2006-01-01

    We present a solution to the ghost problem in fourth order derivative theories. In particular we study the Pais-Uhlenbeck fourth order oscillator model, a model which serves as a prototype for theories which are based on second plus fourth order derivative actions. Via a Dirac constraint method quantization we construct the appropriate quantum-mechanical Hamiltonian and Hilbert space for the system. We find that while the second-quantized Fock space of the general Pais-Uhlenbeck model does indeed contain the negative norm energy eigenstates which are characteristic of higher derivative theories, in the limit in which we switch off the second order action, such ghost states are found to move off shell, with the spectrum of asymptotic in and out S-matrix states of the pure fourth order theory which results being found to be completely devoid of states with either negative energy or negative norm. We provide additional insight into the structure of the Pais-Uhlenbeck theory by quantizing it via path integration ...

  4. Periodic Wave Solutions of Generalized Derivative Nonlinear Schr(o)dinger Equation

    Institute of Scientific and Technical Information of China (English)

    ZHA Qi-Lao; LI Zhi-Bin

    2008-01-01

    A Darboux transformation of the generalized derivative nonlinear Schr(o)dinger equation is derived. As an application, some new periodic wave solutions of the generalized derivative nonlinear Schr(o)dinger equation are explicitly given.

  5. On the decay of higher order derivatives of solutions to Ladyzhenskaya model for incompressible viscous flows

    Institute of Scientific and Technical Information of China (English)

    DONG BoQing; JIANG Wei

    2008-01-01

    This article concerns large time behavior of Ladyzhenskaya model for incompressible viscous flows in R3. Based on linear Lp-Lq estimates, the auxiliary decay properties of the solutions and generalized Gronwall type arguments, some optimal upper and lower bounds for the decay of higher order derivatives of solutions are derived without assuming any decay properties of solutions and using Fourier splitting technology.

  6. Nodulin gene expression and ENOD2 localization in effective, nitrogen fixing and ineffective, bacteria-free nodules of alfalfa.

    NARCIS (Netherlands)

    Wiel, van de C.C.M.; Nurris, J.H.; Bocheneck, B.; Dickstein, R.; Bisseling, T.; Hirsch, A.M.

    1990-01-01

    Alfalfa plants form bacteria-free nodules in response to a number of agents, including Rhizobium meliloti exo mutants, Agrobacterium tumefaciens transconjugants carrying cloned R. meliloti nodulation genes, and compounds that function as auxin transport inhibitors, N-( 1-naphthyl)phthalamic acid or

  7. Computational Solutions of Distributed Order Reaction-Diffusion Systems Associated with Riemann-Liouville Derivatives

    Directory of Open Access Journals (Sweden)

    Ram K. Saxena

    2015-04-01

    Full Text Available This article is in continuation of the authors research attempts to derive computational solutions of an unified reaction-diffusion equation of distributed order associated with Caputo derivatives as the time-derivative and Riesz-Feller derivative as space derivative. This article presents computational solutions of distributed order fractional reaction-diffusion equations associated with Riemann-Liouville derivatives of fractional orders as the time-derivatives and Riesz-Feller fractional derivatives as the space derivatives. The method followed in deriving the solution is that of joint Laplace and Fourier transforms. The solution is derived in a closed and computational form in terms of the familiar Mittag-Leffler function. It provides an elegant extension of results available in the literature. The results obtained are presented in the form of two theorems. Some results associated specifically with fractional Riesz derivatives are also derived as special cases of the most general result. It will be seen that in case of distributed order fractional reaction-diffusion, the solution comes in a compact and closed form in terms of a generalization of the Kampé de Fériet hypergeometric series in two variables. The convergence of the double series occurring in the solution is also given.

  8. Spherically Symmetric Solutions in Higher-Derivative Gravity

    CERN Document Server

    Lü, H; Pope, C N; Stelle, K S

    2015-01-01

    Extensions of Einstein gravity with quadratic curvature terms in the action arise in most effective theories of quantised gravity, including string theory. This article explores the set of static, spherically symmetric and asymptotically flat solutions of this class of theories. An important element in the analysis is the careful treatment of a Lichnerowicz-type `no-hair' theorem. From a Frobenius analysis of the asymptotic small-radius behaviour, the solution space is found to split into three asymptotic families, one of which contains the classic Schwarzschild solution. These three families are carefully analysed to determine the corresponding numbers of free parameters in each. One solution family is capable of arising from coupling to a distributional shell of matter near the origin; this family can then match on to an asymptotically flat solution at spatial infinity without encountering a horizon. Another family, with horizons, contains the Schwarzschild solution but includes also non-Schwarzschild black...

  9. Spherically symmetric solutions in higher-derivative gravity

    Science.gov (United States)

    Lü, H.; Perkins, A.; Pope, C. N.; Stelle, K. S.

    2015-12-01

    Extensions of Einstein gravity with quadratic curvature terms in the action arise in most effective theories of quantized gravity, including string theory. This article explores the set of static, spherically symmetric and asymptotically flat solutions of this class of theories. An important element in the analysis is the careful treatment of a Lichnerowicz-type "no-hair" theorem. From a Frobenius analysis of the asymptotic small-radius behavior, the solution space is found to split into three asymptotic families, one of which contains the classic Schwarzschild solution. These three families are carefully analyzed to determine the corresponding numbers of free parameters in each. One solution family is capable of arising from coupling to a distributional shell of matter near the origin; this family can then match onto an asymptotically flat solution at spatial infinity without encountering a horizon. Another family, with horizons, contains the Schwarzschild solution but includes also non-Schwarzschild black holes. The third family of solutions obtained from the Frobenius analysis is nonsingular and corresponds to "vacuum" solutions. In addition to the three families identified from near-origin behavior, there are solutions that may be identified as "wormholes," which can match symmetrically onto another sheet of spacetime at finite radius.

  10. On the Solutions Fractional Riccati Differential Equation with Modified Riemann-Liouville Derivative

    Directory of Open Access Journals (Sweden)

    Mehmet Merdan

    2012-01-01

    Full Text Available Fractional variational iteration method (FVIM is performed to give an approximate analytical solution of nonlinear fractional Riccati differential equation. Fractional derivatives are described in the Riemann-Liouville derivative. A new application of fractional variational iteration method (FVIM was extended to derive analytical solutions in the form of a series for these equations. The behavior of the solutions and the effects of different values of fractional order are indicated graphically. The results obtained by the FVIM reveal that the method is very reliable, convenient, and effective method for nonlinear differential equations with modified Riemann-Liouville derivative

  11. On the decay of higher order derivatives of solutions to Ladyzhenskaya model for incompressible viscous flows

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    This article concerns large time behavior of Ladyzhenskaya model for incompressible viscous flows in R~3.Based on linear L~P-L~q estimates,the auxiliary decay properties of the solutions and generalized Gronwall type arguments,some optimal upper and lower bounds for the decay of higher order derivatives of solutions are derived without assuming any decay properties of solutions and using Fourier splitting technology.

  12. Modulation equations for spatially periodic systems: derivation and solutions

    NARCIS (Netherlands)

    Schielen, R.; Doelman, A.

    2001-01-01

    We study a class of partial dierential equations in one spatial dimension, which can be seen as model equations for the analysis of pattern formation in physical systems dened on unbounded, weakly oscillating domains. We perform a linear and weakly nonlinear stability analysis for solutions that bif

  13. Rheological properties of silica suspensions in aqueous cellulose derivatives solutions

    Science.gov (United States)

    Ryo, Y.; Kawaguchi, M.

    1992-05-01

    The rheological properties of the silica suspensions in aqueous solutions of hydroxypropylmethylcellulose (HPMC) were investigated in terms of the shear stress and storage and loss moduli (G' and G`) as a function of silica content, HPMC concentration, and HPMC molecular weight by using a coaxial cylinder rheometer.

  14. High School Forum. The Solution: "Derivation of the Ideal Gas Law."

    Science.gov (United States)

    Herron, J. Dudley, Ed.

    1980-01-01

    Presents responses to an earlier report concerning a procedure for the derivation of the Ideal Gas Law from Charles', Boyle's, and other gas laws. Logic errors and solutions that work are discussed. (CS)

  15. Exact solutions of a class of fractional Hamiltonian equations involving Caputo derivatives

    Energy Technology Data Exchange (ETDEWEB)

    Baleanu, Dumitru [Department of Mathematics and Computer Sciences, Faculty of Arts and Sciences, Cankaya University, Ankara 06530 (Turkey); Trujillo, Juan J [Departamento de Analisis Matematico, University of La Laguna, 38271 La Laguna, Tenerife (Spain)], E-mail: dumitru@cankaya.edu.tr, E-mail: JTrujill@ullmat.es, E-mail: baleanu@venus.nipne.ro

    2009-11-15

    The fractional Hamiltonian equations corresponding to the Lagrangians of constrained systems within Caputo derivatives are investigated. The fractional phase space is obtained and the exact solutions of some constrained systems are obtained.

  16. POSITIVE SOLUTIONS TO SYSTEMS OF SECOND ORDER NONLOCAL BOUNDARY VALUE PROBLEMS WITH FIRST ORDER DERIVATIVES

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    This paper investigates the existence of positive solutions to systems of second order nonlocal boundary value problems with first order derivatives, in which the nonlinear term is not required to be continuous and involves first order derivatives. The main tool used in this paper is a fixed point index theory in a cone.

  17. Positive Solution of a Nonlinear Fractional Differential Equation Involving Caputo Derivative

    Directory of Open Access Journals (Sweden)

    Changyou Wang

    2012-01-01

    Full Text Available This paper is concerned with a nonlinear fractional differential equation involving Caputo derivative. By constructing the upper and lower control functions of the nonlinear term without any monotone requirement and applying the method of upper and lower solutions and the Schauder fixed point theorem, the existence and uniqueness of positive solution for the initial value problem are investigated. Moreover, the existence of maximal and minimal solutions is also obtained.

  18. Quenching of nucleotide-derived radicals by bisbenzimidazole derivative Hoechst-33258 in aqueous solution

    Indian Academy of Sciences (India)

    H Mohan; A Adhikary; V Jain; J P Mittal

    2000-08-01

    The pulse radiolysis technique has been employed to investigate the reaction of DNA-minor-groove ligand bisbenzimidazole Hoechst 33258 with pyrimidine and purine nucleotide-derived radicals. Formation of an N-centred Hoechst-33258 radical is observed. Bimolecular rate constants and the yields of Hoechst-33258 radical have been evaluated. While the rate constant for the reaction of pyrimidine-derived radicals with Hoechst-33258 remained the same (1-2) × 109 dm3 mol-1s-1, the yields of the Hoechst-33258 radical varied from 25% (5 -cytidine monophosphate) to 75% (5 -guanosine monophosphate) under anoxic conditions. The rate constant values for the reaction of purine-derived radicals with Hoechst-33258, under oxic and anoxic conditions, remained the same whereas with pyrimidine-derived radicals, the rate constant value under oxic conditions was about two orders of magnitude lower than under anoxic conditions. The difference in the yields of Hoechst-33258 radical with various nucleotide-derived radicals suggest the formation of different types of radicals and that the reaction mainly occurs by electron transfer from Hoechst-33258 to the nucleotide radicals.

  19. Stability of Travelling Wave Solutions of the Derivative Ginzburg—Landau Equations

    Institute of Scientific and Technical Information of China (English)

    BolingGuo; BainianLU; 等

    1997-01-01

    The existence of travelling wave solution of the quinitic Ginzburg-Landau equation with derivatives is proved by the geometric singular perturbation theory.The stability of the wave solution is presented by topological methods which are proposed in Alexander,Gardner and Jones[6].The Chern number of the unstable augmented bundle is used to count the number of the linearizing operator L.For derivative Ginzburg-Landau equations,the Chern number of the unstable augmented bundle is equal to zero.I.e.c1(ε)=0,then the wave solution is stable.

  20. A class of exact solutions of higher derivative gravity in four dimensions

    Directory of Open Access Journals (Sweden)

    M. H. Dehghani

    2005-09-01

    Full Text Available  In this paper we consider the action of higher derivative gravity up to the second order terms in the scalars made from the Ricci scalar, Ricci and Riemann tensors. We use the Bach- Lanczos identity of the Weyl tensor in four dimensions and show that the solutions of 4-dimensional Einstein equations with cosmological constant term in vacuum, which are known as Einstein metrics, satisfy the field equations of higher derivative gravity. We also find that the field equations of higher derivative gravity are not satisfied by the solutions of Einstein equations in higher dimensions or in the presence of matter.

  1. Aminopyrimidine derivatives as inhibitors for corrosion of 1018 carbon steel in nitric acid solution

    Energy Technology Data Exchange (ETDEWEB)

    Abdallah, M. [Chemistry Department, Faculty of Science, Benha University, Benha (Egypt)]. E-mail: metwally552@hotmail.com; Helal, E.A. [Corrosion Department, Badr El-Din Petroleum company (Egypt); Fouda, A.S. [Chemistry Department, Faculty of Science, Mansoura University, Mansoura 35516 (Egypt)]. E-mail: asfouda@yahoo.com

    2006-07-15

    The effect of some aminopyrimidine derivatives on the corrosion of 1018 carbon steel in 0.05 M HNO{sub 3} solution was studied using weight loss and polarization techniques. The percentage inhibition efficiency was found to increase with increasing concentration of inhibitor and with decreasing temperature. The addition of KI to aminopyrimidine derivatives enhanced the inhibition efficiency due to synergistic effect. The inhibitors are adsorbed on the steel surface according to Temkin isotherm. Some thermodynamic functions were computed and discussed. It was found that the aminopyrimidine derivatives provide a good protection to steel against pitting corrosion in chloride containing solutions.

  2. Computational solutions of unified fractional reaction-diffusion equations with composite fractional time derivative

    Science.gov (United States)

    Saxena, R. K.; Mathai, A. M.; Haubold, H. J.

    2015-10-01

    This paper deals with the investigation of the computational solutions of an unified fractional reaction-diffusion equation, which is obtained from the standard diffusion equation by replacing the time derivative of first order by the generalized fractional time-derivative defined by Hilfer (2000), the space derivative of second order by the Riesz-Feller fractional derivative and adding the function ϕ (x, t) which is a nonlinear function governing reaction. The solution is derived by the application of the Laplace and Fourier transforms in a compact and closed form in terms of the H-function. The main result obtained in this paper provides an elegant extension of the fundamental solution for the space-time fractional diffusion equation obtained earlier by Mainardi et al. (2001, 2005) and a result very recently given by Tomovski et al. (2011). Computational representation of the fundamental solution is also obtained explicitly. Fractional order moments of the distribution are deduced. At the end, mild extensions of the derived results associated with a finite number of Riesz-Feller space fractional derivatives are also discussed.

  3. Explicit and exact travelling wave solutions for the generalized derivative Schroedinger equation

    Energy Technology Data Exchange (ETDEWEB)

    Huang Dingjiang [Department of Applied Mathematics, Dalian University of Technology, Dalian 116024 (China)]. E-mail: hdj8116@163.com; Li Desheng [Department of Applied Mathematics, Dalian University of Technology, Dalian 116024 (China); Department of Mathematics, Shenyang Normal University, Shenyang 110034 (China); Zhang Hongqing [Department of Applied Mathematics, Dalian University of Technology, Dalian 116024 (China)

    2007-02-15

    In this paper, a new auxiliary equation expansion method and its algorithm is proposed by studying a first order nonlinear ordinary differential equation with a sixth-degree nonlinear term. Being concise and straightforward, the method is applied to the generalized derivative Schroedinger equation. As a result, some new exact travelling wave solutions are obtained which include bright and dark solitary wave solutions, triangular periodic wave solutions and singular solutions. This algorithm can also be applied to other nonlinear wave equations in mathematical physics.

  4. CONSTRUCTION OF GENERAL SUBSUMPTIVE SOLUTIONS OF BOOLEAN EQUATIONS VIA COMPLETE-SUM DERIVATION

    Directory of Open Access Journals (Sweden)

    Ali Muhammad Ali Rushdi

    2014-01-01

    Full Text Available Boolean-equation solving permeates many diverse areas of modern science. To solve a system of Boolean equations, one usually combines them into an equivalent single Boolean equation whose set of solutions is exactly the same as that of the original system of equations. One of the general classes of solutions for Boolean equations is the subsumptive general solution, in which each variable is expressed as an interval decided by a double inequality in terms of the succeeding variables. The solution validity depends on the satisfaction of a required consistency condition. In this study, we introduce a novel method (henceforth called the CS method for producing subsumptive Boolean-equation solutions based on deriving the complete sum of the pertinent Boolean function . The complete sum is a disjunction of all prime implicants of and nothing else. It explicitly shows all information about in the most compact form. We demonstrate the proposed CS solutions in terms of four examples, covering Boolean algebras of different sizes and using two prominent methods for deriving . Occasionally, the consistency condition results in a collapse of the underlying Boolean algebra into a smaller subalgebra. We also illustrate how an expansion tree (typically reduced to an acyclic graph can be used to deduce a complete list of all particular solutions from the subsumptive solution. The present CS method yields correct solutions, since it fits into the frame of the most general subsumptive solution. Among competing subsumptive methods, the CS method strikes a reasonable tradeoff between the conflicting requirements of less computational cost and more compact form for the solution obtained. In fact, it is the second best known method from both criteria of efficiency and compactness of solution.

  5. Phase-transition and aggregation characteristics of a thermoresponsive dextran derivative in aqueous solutions.

    Science.gov (United States)

    Shi, Huan-Ying; Zhang, Li-Ming

    2006-10-16

    Grafting of poly(N-vinylcaprolactam) side chains onto a hydrophilic dextran backbone was found to provide the dextran with new, thermoresponsive properties in aqueous solutions. Depending on its solution concentration, the resulting dextran derivative could exhibit a temperature-induced phase-transition and critical transition temperature (T(c)). Different anions and cations of added salts, including five potassium salts and five alkali-metal chlorides, were observed to influence the T(c) value of its aqueous solution. Except for potassium iodide, all added salts were found to lower the T(c) value. The addition of the surfactant, cationic cetyltrimethylammonium bromide or anionic sodium dodecyl sulfate, resulted in an increase of the T(c) value. With the help of the Coomassie Brilliant Blue dye as a polarity probe, the formation of hydrophobic aggregates above the T(c) was revealed for this new dextran derivative in aqueous solution.

  6. Mild solutions for nonlocal fractional semilinear functional differential inclusions involving Caputo derivative

    Directory of Open Access Journals (Sweden)

    Ahmed G. Ibrahim

    2014-05-01

    Full Text Available In this paper, we prove various existence results of a mild solution for a fractional nonlocal functional semilinear differential inclusion involving Caputo derivative in Banach spaces. We consider the case when the values of the orient field are convex as well as nonconvex. Moreover, we study the topological structure of solution sets. Our results extend or generalize results proved in recent papers.

  7. S-asymptotically -periodic Solutions of R-L Fractional Derivative-Integral Equation

    Institute of Scientific and Technical Information of China (English)

    WANG Bing

    2015-01-01

    The aim of this paper is to study the S-asymptotically ω-periodic solutions of R-L fractional derivative-integral equation:is a linear densely defined operator of sectorial type on a completed Banach space X, f is a continuous function satisfying a suitable Lipschitz type condition. We will use the contraction mapping theory to prove problem (1) and (2) has a unique S-asymptotically ω-periodic solution if the function f satisfies Lipshcitz condition.

  8. Anti-inflammatory activity of nanocrystalline silver-derived solutions in porcine contact dermatitis

    Directory of Open Access Journals (Sweden)

    Wang JianFei

    2010-02-01

    Full Text Available Abstract Background Nanocrystalline silver dressings have anti-inflammatory activity, unlike solutions containing Ag+ only, which may be due to dissolution of multiple silver species. These dressings can only be used to treat surfaces. Thus, silver-containing solutions with nanocrystalline silver properties could be valuable for treating hard-to-dress surfaces and inflammatory conditions of the lungs and bowels. This study tested nanocrystalline silver-derived solutions for anti-inflammatory activity. Methods Inflammation was induced on porcine backs using dinitrochlorobenzene. Negative and positive controls were treated with distilled water. Experimental groups were treated with solutions generated by dissolving nanocrystalline silver in distilled water adjusted to starting pHs of 4 (using CO2, 5.6 (as is, 7, and 9 (using Ca(OH2. Solution samples were analyzed for total silver. Daily imaging, biopsying, erythema and oedema scoring, and treatments were performed for three days. Biopsies were processed for histology, immunohistochemistry (for IL-4, IL-8, IL-10, TNF-α, EGF, KGF, KGF-2, and apoptotic cells, and zymography (MMP-2 and -9. One-way ANOVAs with Tukey-Kramer post tests were used for statistical analyses. Results Animals treated with pH 7 and 9 solutions showed clear visual improvements. pH 9 solutions resulted in the most significant reductions in erythema and oedema scores. pH 4 and 7 solutions also reduced oedema scores. Histologically, all treatment groups demonstrated enhanced re-epithelialisation, with decreased inflammation. At 24 h, pMMP-2 expression was significantly lowered with pH 5.6 and 9 treatments, as was aMMP-2 expression with pH 9 treatments. In general, treatment with silver-containing solutions resulted in decreased TNF-α and IL-8 expression, with increased IL-4, EGF, KGF, and KGF-2 expression. At 24 h, apoptotic cells were detected mostly in the dermis with pH 4 and 9 treatments, nowhere with pH 5.6, and in both the

  9. Approximate analytical solution of diffusion equation with fractional time derivative using optimal homotopy analysis method

    Directory of Open Access Journals (Sweden)

    S. Das

    2013-12-01

    Full Text Available In this article, optimal homotopy-analysis method is used to obtain approximate analytic solution of the time-fractional diffusion equation with a given initial condition. The fractional derivatives are considered in the Caputo sense. Unlike usual Homotopy analysis method, this method contains at the most three convergence control parameters which describe the faster convergence of the solution. Effects of parameters on the convergence of the approximate series solution by minimizing the averaged residual error with the proper choices of parameters are calculated numerically and presented through graphs and tables for different particular cases.

  10. Loss of solution in the symmetry improved Phi-derivable expansion scheme

    CERN Document Server

    Markó, Gergely; Szép, Zsolt

    2016-01-01

    We consider the two-loop Phi-derivable approximation for the O(2)-symmetric scalar model, augmented by the symmetry improvement introduced in [A. Pilaftsis and D. Teresi, Nucl. Phys. B874, 594 (2013)], which enforces Goldstone's theorem in the broken phase. Although the corresponding equations admit a solution in the presence of a large enough infrared (IR) regulating scale, we argue that, for smooth ultraviolet (UV) regulators, the solution is lost when the IR scale becomes small enough. Infrared regular solutions exist for certain non-analytic UV regulators, but we argue that these solutions are artifacts which should disappear when the sensitivity to the UV regulator is removed by a renormalization procedure. The loss of solution is observed both at zero and at finite temperature, although it is simpler to identify in the latter case. We also comment on possible ways to cure this problem.

  11. Enzyme stabilization by glass-derived silicates in glass-exposed aqueous solutions

    Science.gov (United States)

    Ives, J.A.; Moffett, J.R.; Arun, P.; Lam, D.; Todorov, T.I.; Brothers, A.B.; Anick, D.J.; Centeno, J.; Namboodiri, M.A.A.; Jonas, W.B.

    2010-01-01

    Objectives: To analyze the solutes leaching from glass containers into aqueous solutions, and to show that these solutes have enzyme activity stabilizing effects in very dilute solutions. Methods: Enzyme assays with acetylcholine esterase were used to analyze serially succussed and diluted (SSD) solutions prepared in glass and plastic containers. Aqueous SSD preparations starting with various solutes, or water alone, were prepared under several conditions, and tested for their solute content and their ability to affect enzyme stability in dilute solution. Results: We confirm that water acts to dissolve constituents from glass vials, and show that the solutes derived from the glass have effects on enzymes in the resultant solutions. Enzyme assays demonstrated that enzyme stability in purified and deionized water was enhanced in SSD solutions that were prepared in glass containers, but not those prepared in plastic. The increased enzyme stability could be mimicked in a dose-dependent manner by the addition of silicates to the purified, deionized water that enzymes were dissolved in. Elemental analyses of SSD water preparations made in glass vials showed that boron, silicon, and sodium were present at micromolar concentrations. Conclusions: These results show that silicates and other solutes are present at micromolar levels in all glass-exposed solutions, whether pharmaceutical or homeopathic in nature. Even though silicates are known to have biological activity at higher concentrations, the silicate concentrations we measured in homeopathic preparations were too low to account for any purported in vivo efficacy, but could potentially influence in vitro biological assays reporting homeopathic effects. ?? 2009 The Faculty of Homeopathy.

  12. Analytical Solutions of the Space-Time Fractional Derivative of Advection Dispersion Equation

    Directory of Open Access Journals (Sweden)

    Abdon Atangana

    2013-01-01

    Full Text Available Fractional advection-dispersion equations are used in groundwater hydrology to model the transport of passive tracers carried by fluid flow in porous medium. A space-time fractional advection-dispersion equation (FADE is a generalization of the classical ADE in which the first-order space derivative is replaced with Caputo or Riemann-Liouville derivative of order , and the second-order space derivative is replaced with the Caputo or the Riemann-Liouville fractional derivative of order . We derive the solution of the new equation in terms of Mittag-Leffler functions using Laplace transfrom. Some examples are given. The results from comparison let no doubt that the FADE is better in prediction than ADE.

  13. Boundedness of a Derived Function of a Solution About a Class of Diffusion Variational Equations

    Institute of Scientific and Technical Information of China (English)

    Kun Hui LIU

    2004-01-01

    In this paper the boundedness of a derived function of a solution about a class of diffusion variational equations is discussed. The application of it to related stochastic analysis problems is also illustrated. What should be emphasized is that the problem discussed and the ways proved in this paper are fundamentally new and the conclusion of this paper is fairly profound.

  14. Classification of kink type solutions to the extended derivative nonlinear Schrödinger equation

    DEFF Research Database (Denmark)

    Wyller, J.; Fla, T.; Juul Rasmussen, J.

    1998-01-01

    The Raman Extended Derivative Non Linear Schrodinger (R-EDNLS) equation which models single mode propagation in optical fibers, is shown to possess travelling and stationary kink envelope solutions of monotonic and oscillatory type. These structures have been called optical shocks in analogy...

  15. Explicit N-Fold Darboux Transformations and Soliton Solutions for Nonlinear Derivative Schrodinger Equations

    Institute of Scientific and Technical Information of China (English)

    FAN Eh-Gui

    2001-01-01

    An explicit N-fold Darboux transformation for a coupled of derivative nonlinear Schrodinger equations is constructed with the help of a gauge transformation of spectral problems. As a reduction, the Darboux transformation for well-known Gerdjikov-Ivanov equation is further obtained, from which a general form of N-soliton solutions for Gerdjikov-Ivanov equation is given.``

  16. On the analytical solution of Fornberg–Whitham equation with the new fractional derivative

    Indian Academy of Sciences (India)

    Olaniyi Samuel Iyiola; Gbenga Olayinka Ojo

    2015-10-01

    Motivated by the simplicity, natural and efficient nature of the new fractional derivative introduced by R Khalil et al in J. Comput. Appl. Math. 264, 65 (2014), analytical solution of space-time fractional Fornberg–Whitham equation is obtained in series form using the relatively new method called q-homotopy analysis method (q-HAM). The new fractional derivative makes it possible to introduce fractional order in space to the Fornberg–Whitham equation and be able to obtain its solution. This work displays the elegant nature of the application of q-HAM to solve strongly nonlinear fractional differential equations. The presence of the auxiliary parameter h helps in an effective way to obtain better approximation comparable to exact solutions. The fraction-factor in this method gives it an edge over other existing analytical methods for nonlinear differential equations. Comparisons are made on the existence of exact solutions to these models. The analysis shows that our analytical solutions converge very rapidly to the exact solutions.

  17. Recovery of palladium from a spent automobile catalyst leaching solution by a thiodiglycolamide derivative

    OpenAIRE

    2015-01-01

    In the sequence of previous research on the development of novel liquid-liquid amidetype compounds to efficiently and selectively extract platinum-group metals (PGMs) from concentrated hydrochloric acid media, a specific thiodiglycolamide derivative – N,N’-dimethyl-N,N’-dicyclohexylthiodiglycolamide (DMDCHTDGA) – has been applied for the recovery of palladium(II) from a spent automobile catalyst leaching solution, containing palladium(II) and rhodium(III) as PGMs. The results obtained are rat...

  18. Analytical Solutions of a Space-Time Fractional Derivative of Groundwater Flow Equation

    Directory of Open Access Journals (Sweden)

    Abdon Atangana

    2014-01-01

    Full Text Available The classical Darcy law is generalized by regarding the water flow as a function of a noninteger order derivative of the piezometric head. This generalized law and the law of conservation of mass are then used to derive a new equation for groundwater flow. Two methods including Frobenius and Adomian decomposition method are used to obtain an asymptotic analytical solution to the generalized groundwater flow equation. The solution obtained via Frobenius method is valid in the vicinity of the borehole. This solution is in perfect agreement with the data observed from the pumping test performed by the institute for groundwater study on one of their boreholes settled on the test site of the University of the Free State. The test consisted of the pumping of the borehole at the constant discharge rate Q and monitoring the piezometric head for 350 minutes. Numerical solutions obtained via Adomian method are compared with the Barker generalized radial flow model for which a fractal dimension for the flow is assumed. Proposition for uncertainties in groundwater studies was given.

  19. Viscoelastic properties of aqueous guar gum derivative solutions under large amplitude oscillatory shear (LAOS).

    Science.gov (United States)

    Szopinski, Daniel; Luinstra, Gerrit A

    2016-11-20

    The industrial relevant nonlinear viscoelastic properties of aqueous carboxymethyl hydroxypropyl guar gum (CMHPG) and non-ionic hydroxypropyl guar gum (HPG) solutions between semi-dilute and concentrated solution state were investigated by large amplitude oscillatory shear flow (LAOS). Aqueous CMHPG and HPG solutions enter the nonlinear flow regime at deformations γ0>100%. The nonlinear stress waveforms were analyzed by FT-rheology and orthogonal stress decomposition along the MITlaos framework. A rheological fingerprint is generated (Pipkin space) showing that the guar gum derivative solutions undergo a shear-thinning at high strains, which is preceded by a thickening above a minimum strain rate at intermediate strains. The influence and breakup of superstructures/aggregates gives a "rheological fingerprint", a function of the applied deformation and time scale (Pipkin space). A characteristic process time was found that scales exponentially with the overlap parameter with an exponent of 4/2, and is proposed to represent the relaxation process of the superstructure in solution.

  20. Solution behaviour of new cationic surfactants derived from Guerbet alcohols and their use in hair conditioners.

    Science.gov (United States)

    Yahagi, K; Hoshino, N; Hirota, H

    1991-10-01

    Summary The solution behaviour of new cationic surfactants, synthesized by using long-chain Guerbet alcohols, in water was investigated by a polarizing microscopic technique, differential scanning calorimetry, and electric conductivity measurements. These surfactants show the gel-liquid crystalline phase transition to be lower than 0 degrees C and form lamellar liquid crystals even in cold water and at low concentrations of surfactants. The sorption of cationic surfactants from aqueous solutions onto hair was determined as a function of temperature. The effect of adsorbed cationic surfactants on the critical surface tension and kinetic frictional coefficients of hair surface have been investigated. These surface characteristics of hair treated with quaternary ammonium compounds derived from Guerbet alcohols were found to be significantly improved. These results can be explained by the high ability of sorption onto hair. Hair rinses and conditioners having excellent ease of combing or brushing for wet and dry hair can be formulated by the application of these cationic surfactants.

  1. Study of a Triazole Derivative as Corrosion Inhibitor for Mild Steel in Phosphoric Acid Solution

    Directory of Open Access Journals (Sweden)

    Lin Wang

    2012-01-01

    Full Text Available The corrosion inhibition by a triazole derivative (PAMT on mild steel in phosphoric acid (H3PO4 solution has been investigated by weight loss and polarization methods. The experimental results reveal that the compound has a significant inhibiting effect on the corrosion of steel in H3PO4 solution. It also shows good corrosion inhibition at higher concentration of H3PO4. Potentiodynamic polarization studies have shown that the compound acts as a mixed-type inhibitor retarding the anodic and cathodic corrosion reactions with predominant effect on the cathodic reaction. The values of inhibition efficiency obtained from weight loss and polarization measurements are in good agreement. The adsorption of this compound is found to obey the Langmuir adsorption isotherm. Some kinetic and thermodynamic parameters such as apparent activation energy, frequency factor, and adsorption free energy have been calculated and discussed.

  2. SANS structural characterization of fullerenol-derived star polymers in solutions

    CERN Document Server

    Jeng, U S; Wang, L Y; Chiang, L Y; Ho, D L; Han, C C

    2002-01-01

    We have studied the chain conformations of fullerenol-derived star polymers in two organic solvents using small-angle neutron scattering (SANS). The SANS results indicate that the six poly(urethane-ether) arms, chemically bonded on the fullerenol of the C sub 6 sub 0 -based star polymer, have a Gaussian chain conformation in toluene. However, these arms exhibit a pronounced excluded-volume effect in dimethylformamide solutions. We use a scattering model, with the polydispersity of the polymer taken into account, and a fractal model to extract the radius of gyration R sub g values and the persistence lengths of the C sub 6 sub 0 -star polymers in these two organic solutions. (orig.)

  3. Impairment of mineralization by metavanadate and decavanadate solutions in a fish bone-derived cell line.

    Science.gov (United States)

    Tiago, Daniel M; Laizé, Vincent; Cancela, M Leonor; Aureliano, Manuel

    2008-06-01

    Vanadium, a trace metal known to accumulate in bone and to mimic insulin, has been shown to regulate mammalian bone formation using in vitro and in vivo systems. In the present work, short- and long-term effects of metavanadate (containing monomeric, dimeric, tetrameric and pentameric vanadate species) and decavanadate (containing decameric vanadate species) solutions on the mineralization of a fish bone-derived cell line (VSa13) were studied and compared to that of insulin. After 2 h of incubation with vanadate (10 microM in monomeric vanadate), metavanadate exhibited higher accumulation rates than decavanadate (6.85 +/- 0.40 versus 3.95 +/- 0.10 microg V/g of protein, respectively) in fish VSa13 cells and was also shown to be less toxic when applied for short periods. In longer treatments with both metavanadate and decavanadate solutions, similar effects were promoted: stimulation of cell proliferation and strong impairment (75%) of extracellular matrix (ECM) mineralization. The effect of both vanadate solutions (5 microM in monomeric vanadate), on ECM mineralization was increased in the presence of insulin (10 nM). It is concluded that chronic treatment with both vanadate solutions stimulated fish VSa13 cells proliferation and prevented ECM mineralization. Newly developed VSa13 fish cells appeared to be appropriate in the characterization of vanadate effects on vertebrate bone formation, representing a good alternative to mammalian systems.

  4. A Complete Parametric Solutions of Eigenstructure Assignment by State-Derivative Feedback for Linear Control Systems

    Directory of Open Access Journals (Sweden)

    T. H. S. Abdelaziz

    2005-01-01

    Full Text Available In this paper we introduce a complete parametric approach for solving the problem of eigenstructure assignment via state-derivative feedback for linear systems. This problem is always solvable for any controllable systems iff the open-loop system matrix is nonsingular. In this work, two parametric solutions to the feedback gain matrix are introduced that describe the available degrees of freedom offered by the state-derivative feedback in selecting the associated eigenvectors from an admissible class. These freedoms can be utilized to improve robustness of the closed-loop system. Accordingly, the sensitivity of the assigned eigenvalues to perturbations in the system and gain matrix is minimized. Numerical examples are included to show the effectiveness of the proposed approach. 

  5. The Approximate Solutions of Three-Dimensional Diffusion and Wave Equations within Local Fractional Derivative Operator

    Directory of Open Access Journals (Sweden)

    Hassan Kamil Jassim

    2016-01-01

    Full Text Available We used the local fractional variational iteration transform method (LFVITM coupled by the local fractional Laplace transform and variational iteration method to solve three-dimensional diffusion and wave equations with local fractional derivative operator. This method has Lagrange multiplier equal to minus one, which makes the calculations more easily. The obtained results show that the presented method is efficient and yields a solution in a closed form. Illustrative examples are included to demonstrate the high accuracy and fast convergence of this new method.

  6. Metabolic Engineering of Yeast to Produce Fatty Acid-derived Biofuels: Bottlenecks and Solutions

    Directory of Open Access Journals (Sweden)

    Jiayuan eSheng

    2015-06-01

    Full Text Available Fatty acid-derived biofuels can be a better solution than bioethanol to replace petroleum fuel, since they have similar energy content and combustion properties as current transportation fuels. The environmentally friendly microbial fermentation process has been used to synthesize advanced biofuels from renewable feedstock. Due to their robustness as well as the high tolerance to fermentation inhibitors and phage contamination, yeast strains such as Saccharomyces cerevisiae and Yarrowia lipolytica have attracted tremendous attention in recent studies regarding the production of fatty acid-derived biofuels, including fatty acids, fatty acid ethyl esters, fatty alcohols, and fatty alkanes. However, the native yeast strains cannot produce fatty acids and fatty acid-derived biofuels in large quantities. To this end, we have summarized recent publications in this review on metabolic engineering of yeast strains to improve the production of fatty acid-derived biofuels, identified the bottlenecks that limit the productivity of biofuels, and categorized the appropriate approaches to overcome these obstacles.

  7. Anisotropic surface hole-transport property of triphenylamine-derivative single crystal prepared by solution method

    Science.gov (United States)

    Umeda, Minoru; Katagiri, Mitsuhiko; Shironita, Sayoko; Nagayama, Norio

    2016-12-01

    This paper reports the anisotropic hole transport at the triphenylamine-derivative single crystal surface prepared by a solution method. Triphenylamine derivatives are commonly used in a hole-transport material for organic photoconductors of laser-beam printers, in which the materials are used as an amorphous form. For developing organic photovoltaics using the photoconductor's technology, preparation of a single crystal seems to be a specific way by realizing the high mobility of an organic semiconductor. In this study, a single crystal of 4-(2,2-diphenylethenyl)-N,N-bis(4-methylphenyl)-benzenamine (TPA) was prepared and its anisotropic hole-transport property measured. First, the hole-transport property of the TPA was investigated based on its chemical structure and electrochemical redox characteristics. Next, a large-scale single crystal formation at a high rate was developed by employing a solution method based on its solubility and supersolubility curves. The grown TPA was found to be a single crystal based on the polarization micrograph observation and crystallographic analysis. For the TPA single crystal, an anisotropic surface conduction was found, which was well explained by its molecular stack structure. The measured current in the long-axis direction is one order of magnitude greater than that of amorphous TPA.

  8. Pyrrolidinone derivatives as processing additives for solution processed organic solar cells

    Science.gov (United States)

    Vongsaysy, Uyxing; Pavageau, Bertrand; Servant, Laurent; Aziz, Hany

    2014-10-01

    Processing additives are widely used to increase the efficiency of solution processed organic solar cells. We use the Hansen solubility parameters (HSPs) to investigate novel processing additives. The HSPs predict pyrrolidinone derivatives to be efficient processing additives for OSC systems based on poly(3-hexylthiophene)/[6,6]-phenyl-C61- butyric acid methyl ester (P3HT/PCBM). Two pyrrolidinone derivatives are identified: 1-methyl-2-pyrrolidinone and 1- benzyl-2-pyrrolidinone. The processing additives are introduced with various concentrations in the formulation of P3HT and PCBM solution. The electrical characterizations show that the two processing additives significantly increase the short circuit current and thus the power conversion efficiency of the OSCs. The results thus highlight HSPs as an effective and relatively straightforward tool that can be employed to optimize OSC morphology from a theoretical standpoint. Such a tool will be invaluable for identifying additives for novel high efficiency polymer species as they are synthesized, and thus to streamline the device fabrication and device optimization process.

  9. Low-temperature solution-processed graphene oxide derivative hole transport layer for organic solar cells

    Science.gov (United States)

    Zheng, Qiao; Fang, Guojia; Cheng, Fei; Lei, Hongwei; Qin, Pingli; Zhan, Caimao

    2013-04-01

    A Mo6+ cation modified graphene oxide (GO) derivative of GO-Mo was synthesized by a low-temperature solution method with different amounts of ammonium heptamolybdate (Mo-precursor) added into the GO solutions. The GO-Mo products were characterized through Raman microspectroscopy, scanning electron microscopy, transmission electron microscopy, energy dispersive x-ray spectroscopy and x-ray photoelectron spectroscopy measurements and their photoelectric properties were systematically investigated. Organic bulk heterojunction solar cells with GO-Mo as the hole transport layer (HTL) were fabricated and their performance as a function of the number of GO-Mo layers was also studied. The performance of these devices was much better than that of the device with GO as the HTL. The best performance of the device with a power conversion efficiency of 2.61%, an open-circuit voltage of 0.59 V and a short-circuit current density of 9.02 mA cm-2 were obtained. Finally, the effect of the Mo-precursor weight in the GO solution on the device performance was discussed.

  10. Two pyrazine derivatives as inhibitors of the cold rolled steel corrosion in hydrochloric acid solution

    Energy Technology Data Exchange (ETDEWEB)

    Deng Shuduan, E-mail: dengshuduan@163.co [Faculty of Wood Science and Decoration Technology, Southwest Forestry University, Kunming 650224 (China); Li Xianghong; Fu Hui [Department of Fundamental Courses, Southwest Forestry University, Kunming 650224 (China)

    2011-02-15

    Research highlights: Two pyrazine derivatives of 2-aminopyrazine (AP) and 2-amino-5-bromopyrazine (ABP) are good inhibitors for the corrosion of steel in 1.0 M HCl solution. The inhibition efficiency follows the order: ABP > AP. The substitution Br of ABP is the additional centre of adsorption and increases the electron density of pyrazine ring, which can facilitate its adsorption on the metal surface. For either ABP or AP, the adsorption obeys Langmuir adsorption isotherm. Both ABP and AP act as mixed-type inhibitors. - Abstract: The inhibition effect of two pyrazine derivatives of 2-aminopyrazine (AP) and 2-amino-5-bromopyrazine (ABP) on the corrosion of cold rolled steel (CRS) in 1.0 M hydrochloric acid (HCl) was studied by weight loss, potentiodynamic polarization curves, and electrochemical impedance spectroscopy (EIS) methods. The results show that both AP and ABP are good inhibitors, and inhibition efficiency follows the order: ABP > AP. The adsorption of each inhibitor on CRS surface obeys Langmuir adsorption isotherm. Potentiodynamic polarization curves show that two pyrazine derivatives act as mixed-type inhibitors. EIS spectra exhibit one capacitive loop and confirm the inhibitive ability.

  11. Local Fractional Fourier Series Solutions for Nonhomogeneous Heat Equations Arising in Fractal Heat Flow with Local Fractional Derivative

    Directory of Open Access Journals (Sweden)

    Ai-Min Yang

    2014-03-01

    Full Text Available The fractal heat flow within local fractional derivative is investigated. The nonhomogeneous heat equations arising in fractal heat flow are discussed. The local fractional Fourier series solutions for one-dimensional nonhomogeneous heat equations are obtained. The nondifferentiable series solutions are given to show the efficiency and implementation of the present method.

  12. Technique for Calculating Solution Derivatives With Respect to Geometry Parameters in a CFD Code

    Science.gov (United States)

    Mathur, Sanjay

    2011-01-01

    A solution has been developed to the challenges of computation of derivatives with respect to geometry, which is not straightforward because these are not typically direct inputs to the computational fluid dynamics (CFD) solver. To overcome these issues, a procedure has been devised that can be used without having access to the mesh generator, while still being applicable to all types of meshes. The basic approach is inspired by the mesh motion algorithms used to deform the interior mesh nodes in a smooth manner when the surface nodes, for example, are in a fluid structure interaction problem. The general idea is to model the mesh edges and nodes as constituting a spring-mass system. Changes to boundary node locations are propagated to interior nodes by allowing them to assume their new equilibrium positions, for instance, one where the forces on each node are in balance. The main advantage of the technique is that it is independent of the volumetric mesh generator, and can be applied to structured, unstructured, single- and multi-block meshes. It essentially reduces the problem down to defining the surface mesh node derivatives with respect to the geometry parameters of interest. For analytical geometries, this is quite straightforward. In the more general case, one would need to be able to interrogate the underlying parametric CAD (computer aided design) model and to evaluate the derivatives either analytically, or by a finite difference technique. Because the technique is based on a partial differential equation (PDE), it is applicable not only to forward mode problems (where derivatives of all the output quantities are computed with respect to a single input), but it could also be extended to the adjoint problem, either by using an analytical adjoint of the PDE or a discrete analog.

  13. Some new solutions derived from the nonlinear (2+1)-dimensional Toda equation an efficient method of creating solutions

    Institute of Scientific and Technical Information of China (English)

    Bai Cheng-Lin; Zhang Xia; Zhang Li-Hua

    2009-01-01

    This paper presents a new and efficient approach for constructing exact solutions to nonlinear differential-differenceequations (NLDDEs) and lattice equation. By using this method via symbolic computation system MAPLE, we obtained abundant soliton-like and/or period-form solutions to the (2+l)-dimensional Toda equation. It seems that solitary wave solutions are merely special cases in one family. Furthermore, the method can also be applied to other nonlinear differential-difference equations.

  14. Synthesis of an amphiphilic rhodamine derivative and characterization of its solution and thin film properties

    Energy Technology Data Exchange (ETDEWEB)

    Aviv, Hagit [Department of Chemistry, Bar-Ilan University, Ramat-Gan (Israel); Bar-Ilan University Institute for Nanotechnology and Advanced Materials, Ramat-Gan (Israel); Harazi, Sivan [Department of Chemistry, Bar-Ilan University, Ramat-Gan (Israel); Department of Physics, Bar-Ilan University, Ramat-Gan (Israel); Bar-Ilan University Institute for Nanotechnology and Advanced Materials, Ramat-Gan (Israel); Schiff, Dillon [Department of Chemistry, Bar-Ilan University, Ramat-Gan (Israel); Bar-Ilan University Institute for Nanotechnology and Advanced Materials, Ramat-Gan (Israel); Ramon, Yoni [Department of Chemistry, Bar-Ilan University, Ramat-Gan (Israel); Department of Physics, Bar-Ilan University, Ramat-Gan (Israel); Bar-Ilan University Institute for Nanotechnology and Advanced Materials, Ramat-Gan (Israel); Tischler, Yaakov R., E-mail: yrt@biu.ac.il [Department of Chemistry, Bar-Ilan University, Ramat-Gan (Israel); Bar-Ilan University Institute for Nanotechnology and Advanced Materials, Ramat-Gan (Israel)

    2014-08-01

    Here we present characterization of solution and thin film properties of Lissamine rhodamine B sulfonyl didodecyl amine (LRSD), an amphiphilic derivative of rhodamine. LRSD was synthesized by functionalizing Lissamine rhodamine B sulfonyl chloride (LRSC) with didodecylamine via a straightforward sulfonylation reaction. LRSD's long alkane chains make it highly soluble in chloroform, with a marked increase in brightness compared to the starting material. LRSD is shown to form well-defined robust micelles in water, without the addition of a co-surfactant and stable monolayers at the air–water interface. The greater lipophilicity of LRSD also enables doping into non-polar polymeric host matrices such as polystyrene with less aggregation and hence higher fluorescence quantum yield than LRSC or even rhodamine B. The monolayers of LRSD were prepared via Langmuir–Blodgett deposition and showed shifts in the photoluminescence peak from 575 nm to 595 nm, as the surface pressure is varied from 3 mN/m to 11 mN/m. - Highlights: • Lissamine rhodamine B sulfonyl didodecyl amine (LRSD) is soluble in chloroform. • LRSD shows robust quantum yield in solution and as a dopant in thin film. • LRSD is an amphiphilic rhodamine dye that forms compact fluorescent micelles. • LRSD forms a stable isotherm when spread at the air–water interface.

  15. Inhibitive effect of some thiadiazole derivatives on C-steel corrosion in neutral sodium chloride solution

    Energy Technology Data Exchange (ETDEWEB)

    El-Taib Heakal, F., E-mail: fakihaheakal@yahoo.com [Chemistry Department, Faculty of Science, Cairo University, Giza 12613 (Egypt); Fouda, A.S. [Chemistry Department, Faculty of Science, El-Mansoura University, El-Mansoura (Egypt); Radwan, M.S. [Petrogulf Misr Company, Maadi, Cairo (Egypt)

    2011-01-01

    Electrochemical techniques were used to investigate the effect of concentration of three new thiadiazole derivatives (I-III) on the corrosion behavior of C-steel in 0.5 M NaCl solution through the analysis of electrochemical measurements including open circuit potential (OCP), Tafel polarization and electrochemical impedance spectroscopy (EIS). Polarization curves showed that the compounds studied act as anodic type inhibitors, where the inhibition efficiency increases with increase in inhibitor concentration and decreases with rise in temperature. An adherent layer of inhibitor molecules on the surface is proposed to account for their inhibitive action in which the organic molecules adsorb on the active anodic sites following Langmuir isotherm. The thermodynamic parameters of adsorption and corrosion processes were determined and discussed. The results also indicated that pitting potential at higher anodic polarization of C-steel in 0.5 M NaCl solution becomes more positive the higher the concentration of the additive, suggesting that these inhibitors acts as retarding catalyst for pitting corrosion. EIS data confirm well the electrochemical dc results and the results are all in good agreement with the calculated quantum chemical HOMO and LUMO energies of the tested molecules, as well as with surface examination via scanning electron microscope.

  16. Substituent Effects on the Photodeprotection Reactions of Selected Ketoprofen Derivatives in Phosphate Buffered Aqueous Solutions

    Science.gov (United States)

    Liu, Mingyue; Li, Ming-De; Huang, Jinqing; Li, Tianlu; Liu, Han; Li, Xuechen; Phillips, David Lee

    2016-02-01

    Photodeprotection is an important reaction that has been attracting broad interest for use in a variety of applications. Recent advances in ultrafast and vibrational time-resolved spectroscopies can facilitate obtaining data to help unravel the reaction mechanisms involving in the photochemical reactions of interest. The kinetics and reaction mechanisms for the photodeprotection reactions of ketoprofen derivatives containing three different substituents (ibuprofen, Br and I) were investigated by femtosecond transient absorption (fs-TA) and nanosecond time-resolved resonance Raman (ns-TR3) spectroscopy methods in phosphate buffered solutions (PBS). Fs-TA allows us to detect the decay kinetics of the triplet species as the key precursor for formation of a carbanion species for three different substituents attached to ketoprofen. To characterize the structural and electronic properties of the corresponding carbanion and triplet intermediates, TR3 spectroscopic experiments were conducted. The transient spectroscopy work reveals that the different substituents affect the photodecarboxylation reaction to produce carbon dioxide which in turn influences the generation of the carbanion species which determines the rate of the photorelease of the functional groups attached on the ketoprofen parent molecule. The fingerprint TR3 spectroscopy results suggest that ketoprofen derivatives may be deactivated to produce a triplet carbanion when increasing the atom mass of the halogen atoms.

  17. Sorption of ammonium and phosphate from aqueous solution by biochar derived from phytoremediation plants

    Institute of Scientific and Technical Information of China (English)

    Zheng ZENG; Muhammad Tariq RAFIQ; Song-da ZHANG; Ting-qiang LI; Feng-liang ZHAO; Zhen-li HE; He-ping ZHAO; Xiao-e YANG; Hai-long WANG; Jing ZHAO

    2013-01-01

    The study on biochar derived from plant biomass for environmental applications is attracting more and more attention. Twelve sets of biochar were obtained by treating four phytoremediation plants, Salix rosthorni Seemen, Thalia dealbata, Vetiveria zizanioides, and Phragmites sp., sequential y through pyrolysis at 500 °C in a N2 environ-ment, and under different temperatures (500, 600, and 700 °C) in a CO2 environment. The cation exchange capacity and specific surface area of biochar varied with both plant species and pyrolysis temperature. The magnesium (Mg) content of biochar derived from T. dealbata (TC) was obviously higher than that of the other plant biochars. This bi-ochar also had the highest sorption capacity for phosphate and ammonium. In terms of biomass yields, adsorption capacity, and energy cost, T. dealbata biochar produced at 600 °C (TC600) is the most promising sorbent for removing contaminants (N and P) from aqueous solution. Therefore, T. dealbata appears to be the best candidate for phyto-remediation application as its biomass can make a good biochar for environmental cleaning.

  18. Sorption of ammonium and phosphate from aqueous solution by biochar derived from phytoremediation plants.

    Science.gov (United States)

    Zeng, Zheng; Zhang, Song-da; Li, Ting-qiang; Zhao, Feng-liang; He, Zhen-li; Zhao, He-ping; Yang, Xiao-e; Wang, Hai-long; Zhao, Jing; Rafiq, Muhammad Tariq

    2013-12-01

    The study on biochar derived from plant biomass for environmental applications is attracting more and more attention. Twelve sets of biochar were obtained by treating four phytoremediation plants, Salix rosthornii Seemen, Thalia dealbata, Vetiveria zizanioides, and Phragmites sp., sequentially through pyrolysis at 500 °C in a N2 environment, and under different temperatures (500, 600, and 700 °C) in a CO2 environment. The cation exchange capacity and specific surface area of biochar varied with both plant species and pyrolysis temperature. The magnesium (Mg) content of biochar derived from T. dealbata (TC) was obviously higher than that of the other plant biochars. This biochar also had the highest sorption capacity for phosphate and ammonium. In terms of biomass yields, adsorption capacity, and energy cost, T. dealbata biochar produced at 600 °C (TC600) is the most promising sorbent for removing contaminants (N and P) from aqueous solution. Therefore, T. dealbata appears to be the best candidate for phytoremediation application as its biomass can make a good biochar for environmental cleaning.

  19. Solution properties and emulsification properties of amino acid-based gemini surfactants derived from cysteine.

    Science.gov (United States)

    Yoshimura, Tomokazu; Sakato, Ayako; Esumi, Kunio

    2013-01-01

    Amino acid-based anionic gemini surfactants (2C(n)diCys, where n represents an alkyl chain with a length of 10, 12, or 14 carbons and "di" and "Cys" indicate adipoyl and cysteine, respectively) were synthesized using the amino acid cysteine. Biodegradability, equilibrium surface tension, and dynamic light scattering were used to characterize the properties of gemini surfactants. Additionally, the effects of alkyl chain length, number of chains, and structure on these properties were evaluated by comparing previously reported gemini surfactants derived from cystine (2C(n)Cys) and monomeric surfactants (C(n)Cys). 2C(n)diCys shows relatively higher biodegradability than does C(n)Cys and previously reported sugar-based gemini surfactants. Both critical micelle concentration (CMC) and surface tension decrease when alkyl chain length is increased from 10 to 12, while a further increase in chain length to 14 results in increased CMC and surface tension. This indicates that long-chain gemini surfactants have a decreased aggregation tendency due to the steric hindrance of the bulky spacer as well as premicelle formation at concentrations below the CMC and are poorly packed at the air/water interface. Formation of micelles (measuring 2 to 5 nm in solution) from 2C(n)diCys shows no dependence on alkyl chain length. Further, shaking the mixtures of aqueous 2C(n)diCys surfactant solutions and squalane results in the formation of oil-in-water type emulsions. The highly stable emulsions are formed using 2C₁₂diCys or 2C₁₄diCys solution and squalane in a 1:1 or 2:1 volume ratio.

  20. A new method for deriving analytical solutions of partial differential equations-Algebraically explicit analytical solutions of two-buoyancy natural convection in porous media

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Analytical solutions of governing equations of various phenomena have their irre-placeable theoretical meanings. In addition, they can also be the benchmark solu-tions to verify the outcomes and codes of numerical solutions, and even to develop various numerical methods such as their differencing schemes and grid generation skills as well. A hybrid method of separating variables for simultaneous partial differential equation sets is presented. It is proposed that different methods of separating variables for different independent variables in the simultaneous equa-tion set may be used to improve the solution derivation procedure, for example, using the ordinary separating method for some variables and using extraordinary methods of separating variables, such as the separating variables with addition promoted by the first author, for some other variables. In order to prove the ability of the above-mentioned hybrid method, a lot of analytical exact solutions of two-buoyancy convection in porous media are successfully derived with such a method. The physical features of these solutions are given.

  1. Adsorption of phenol and reactive dye from aqueous solution on activated carbons derived from solid wastes.

    Science.gov (United States)

    Nakagawa, Kyuya; Namba, Akio; Mukai, Shin R; Tamon, Hajime; Ariyadejwanich, Pisit; Tanthapanichakoon, Wiwut

    2004-04-01

    Activated carbons were produced from several solid wastes, namely, waste PET, waste tires, refuse derived fuel and wastes generated during lactic acid fermentation from garbage. Activated carbons having various pore size distributions were obtained by the conventional steam-activation method and via the pre-treatment method (i.e., mixture of raw materials with a metal salt, carbonization and acid treatment prior to steam-activation) that was proposed by the authors. The liquid-phase adsorption characteristics of organic compounds from aqueous solution on the activated carbons were determined to confirm the applicability of these carbons, where phenol and a reactive dye, Black5, were employed as representative adsorbates. The hydrophobic surface of the carbons prepared was also confirmed by water vapor adsorption. The characteristics of a typical commercial activated carbon were also measured and compared. It was found that the activated carbons with plentiful mesopores prepared from PET and waste tires had quite high adsorption capacity for large molecules. Therefore they are useful for wastewater treatment, especially, for removal of bulky adsorbates.

  2. Adsorption of Paraquat dichloride from aqueous solution by activated carbon derived from used tires.

    Science.gov (United States)

    Hamadi, Nadhem K; Sri Swaminathan; Chen, Xiao Dong

    2004-08-09

    The removal of pesticide from wastewater under different batch experimental conditions, using a car tire derived activated carbon was investigated. The pesticide utilized in the study was Paraquat dichloride (1,1-dimethyl-4,4-bipyridyl dichloride), which is a well known herbicide. The adsorbent was produced from the pyrolysis and activation of used tires (TAC). The performances of this adsorbent and a commercial activated carbon F300 (CAC) have been compared. It was determined that the adsorption of Paraquat was weakly pH dependent. The effects of particle size, carbon dosage, temperature and the initial concentration of the Paraquat were studied. Further experiments investigating the regeneration capabilities of the tire-supplied carbon were performed. The regenerated carbons that were washed with basic pH solution were found to have the best sorption capacity recovery. It was found that the rate of sorption of Paraquat onto the carbon is very fast with almost 90% of the maximum possible adsorption taking place in the first 5 min. Nevertheless, the batch sorption kinetics was fitted for a first-order reversible reaction, a pseudo-first-order reaction and a pseudo-second-order reaction. The pseudo-second-order chemical reaction model appears to provide the best correlation. The applicability of the Langmuir isotherm for the present system has been evaluated at different temperatures. The isotherms show that the sorption capacity of CAC decreases with temperature and the dominant mechanism of CAC adsorption is physical sorption.

  3. Hydrological Excitation of Polar Motion Derived from GRACE Gravity Field Solutions

    Directory of Open Access Journals (Sweden)

    L. Seoane

    2011-01-01

    Full Text Available The influence of the continental water storage on the polar motion is not well known. Different models have been developed to evaluate these effects and compared to geodetic observations. However, previous studies have shown large discrepancies mainly attributed to the lack of global measurements of related hydrological parameters. Now, from the observations of the GRACE mission, we can estimate the polar motion excitation due to the global hydrology. Data processing of GRACE data is carried out by several centers of analysis, we focus on the new solution computed by the Groupe de Recherche de Géodésie Spatiale. At annual scales, excitations derived from GRACE data are in better agreement with geodetic observations than models estimates. The main contribution to the hydrological excitation comes from the monsoon climates regions where GRACE and models estimates are in a very good agreement. Still, the effect of the north high latitudes regions, where the principal areas of snow cover are found, cannot be neglected. At these regions, GRACE and models estimated contributions to polar motion excitations show significant discrepancies. Finally, GRACE-based excitations reveal the possible influence of water storage variations in exciting polar motion around the frequency of 3 cycles per year.

  4. The inhibitive effect of bipyrazolic derivatives on the corrosion of steel in hydrochloric acid solution

    Energy Technology Data Exchange (ETDEWEB)

    Tebbji, K. [Laboratoire de Chimie des Eaux et Corrosion, Faculte des Sciences, B.P. 717, Oujda (Morocco); Hammouti, B. [Laboratoire de Chimie des Eaux et Corrosion, Faculte des Sciences, B.P. 717, Oujda (Morocco); Oudda, H. [Laboratoire des Procedes de Separation, Faculte des Sciences, Kenitra (Morocco); Ramdani, A. [Laboratoire de Chimie Organique-Physique, Faculte des Sciences, B.P. 717, Oujda (Morocco); Benkadour, M. [Laboratoire de Chimie des Eaux et Corrosion, Faculte des Sciences, B.P. 717, Oujda (Morocco)

    2005-12-15

    The effect of two pyrazole-type organic compounds, namely ethyl 5,5'-dimethyl-1'H-1,3'-bipyrazole-3 carboxylate (P1) and 3,5,5'-trimethyl-1'H-1,3'-bipyrazole (P2) on the corrosion behaviour of steel in 1 M hydrochloric acid (HCl) solution is investigated at 308 K by weight loss measurements, potentiodynamic polarisation and impedance spectroscopy (EIS) methods. The inhibition efficiencies obtained from cathodic Tafel plots, gravimetric and EIS methods are in good agreement. Results obtained show that the compound P2 is the best inhibitor and its efficiency reaches 84% at 10{sup -3} M. Potentiodynamic polarisation studies show that pyrazolic derivatives are cathodic-type inhibitors and these compounds act on the cathodic reaction without changing the mechanism of the hydrogen evolution reaction. The inhibition efficiency of P2 is temperature-dependent in the range from 308 to 353 K and the associated activation energy has been determined. P2 adsorbs on the steel surface according to Langmuir adsorption model. The calculation of the total partial charge of inhibitor atoms is computed.

  5. Tubulin binding, protein-bound conformation in solution, and antimitotic cellular profiling of noscapine and its derivatives.

    Science.gov (United States)

    Bennani, Youssef L; Gu, Wenxin; Canales, Angeles; Díaz, Fernando J; Eustace, Brenda K; Hoover, Russell R; Jiménez-Barbero, Jesus; Nezami, Azin; Wang, Tiansheng

    2012-03-08

    Noscapine and its 7-hydroxy and 7-amino derivatives were characterized for their binding to tubulin. A solution NMR structure of these compounds bound to tubulin shows that noscapine and its 7-aniline derivative do not compete for the same binding site nor does its small molecule crystal structure match its tubulin-bound conformation. These compounds were also tested for their antiproliferative effects on a panel hepatocellular carcinoma cell lines.

  6. Extensional flow behavior of aqueous guar gum derivative solutions by capillary breakup elongational rheometry (CaBER).

    Science.gov (United States)

    Szopinski, Daniel; Handge, Ulrich A; Kulicke, Werner-Michael; Abetz, Volker; Luinstra, Gerrit A

    2016-01-20

    The extensional rheological properties of aqueous ionic carboxymethyl hydroxypropyl guar gum (CMHPG) and non-ionic hydroxypropyl guar gum (HPG) solutions between the semi-dilute solution state and the concentrated network solution state were investigated by capillary breakup elongational rheometry (CaBER). Carboxymethylated guar gum derivatives show an instable filament formation in deionized water. The ratio of elongational relaxation time λE over the shear relaxation time λS follows a power law of λE/λS∼(c · [η])(-2). The difference of the relaxation times in shear and elongation can be related to the loss of entanglements and superstructures in elongational flows at higher strains.

  7. Radiation-induced reduction of quinoxalin-2-one derivatives in aqueous solutions

    Science.gov (United States)

    Skotnicki, Konrad; De la Fuente, Julio R.; Cañete, Alvaro; Bobrowski, Krzysztof

    2016-07-01

    Quinoxaline-2-one derivatives have been proposed as potential drugs in treatments of various diseases since some of them showed a variety of pharmacological properties. The kinetics and spectral characteristics of the transients formed in the reactions of hydrated electrons (eaq-) with quinoxalin-2-(1H)-one (Q) and its methyl derivative, 3-methyl quinoxalin-2-(1H)-one (3-MeQ) were studied by pulse radiolysis in aqueous solutions at pH ranging from 5 to 14. The transient absorption spectra recorded in the reactions of (eaq-) with Q and 3-MeQ at pH 7 consisted of a broad, almost flat band in the range 390-450 nm and were assigned to the respective protonated radical anions (QH•/3-MeQH•) at N4 atom in a pyrazin-2-one ring. On the other hand, the transient absorption spectra recorded in the reactions of (eaq-) with Q and 3-MeQ at pH 13 are characterized by a broad band with a much better pronounced maximum at λmax=390 nm and higher intensity (in comparison to that at pH 7) and were assigned to the respective radical anions (Q•-/3-MeQ•-). Both forms are involved in the prototropic equilibrium with the pKa located at pH≥13.5. The rate constants of the reactions of (eaq-) with Q and 3-MeQ were found to be at pH 7 (2.6±0.1)×1010 M-1 s-1 and (2.1±0.1)×1010 M-1 s-1 and at pH 13 (1.6±0.1)×1010 M-1 s-1 and (1.3±0.1)×1010 M-1 s-1, respectively. Semi-empirical quantum mechanical calculations reproduce fairly well the spectral features of the experimental absorption spectra and show that protonated radical anions at nitrogen atom (N4) in both molecules are the most stable hydrogenated radicals.

  8. Multiple positive solutions for singular boundary-value problems with derivative dependence on finite and infinite intervals

    Directory of Open Access Journals (Sweden)

    Baoqiang Yan

    2006-07-01

    Full Text Available In this paper, Krasnoselskii's theorem and the fixed point theorem of cone expansion and compression are improved. Using the results obtained, we establish the existence of multiple positive solutions for the singular second-order boundary-value problems with derivative dependance on finite and infinite intervals.

  9. Derivation of Varying Specific Heat Gasdynamic Functions,Normal Shock Analytical Solution and its Improvements

    Institute of Scientific and Technical Information of China (English)

    TsuiChih-Ya

    1992-01-01

    A set of new gasdynamic functions with varying specific heat are deriveo for the first time.An original analytical solution of normal shock waves is owrked out therewith.This solution is thereafter further improved by not involving total temperature,Illustrative examples of comparison are given,including also some approximate solutions to show the orders of their errors.

  10. Analytic solutions of Oldroyd-B fluid with fractional derivatives in a circular duct that applies a constant couple

    Directory of Open Access Journals (Sweden)

    M.B. Riaz

    2016-12-01

    Full Text Available The aim of this article was to analyze the rotational flow of an Oldroyd-B fluid with fractional derivatives, induced by an infinite circular cylinder that applies a constant couple to the fluid. Such kind of problem in the settings of fractional derivatives has not been found in the literature. The solutions are based on an important remark regarding the governing equation for the non-trivial shear stress. The solutions that have been obtained satisfy all imposed initial and boundary conditions and can easily be reduced to the similar solutions corresponding to ordinary Oldroyd-B, fractional/ordinary Maxwell, fractional/ordinary second-grade, and Newtonian fluids performing the same motion. The obtained results are expressed in terms of Newtonian and non-Newtonian contributions. Finally, the influence of fractional parameters on the velocity, shear stress and a comparison between generalized and ordinary fluids is graphically underlined.

  11. Discreet Solutions for Matrix Systems in Partial Derivatives Hyperbolic and Singular

    CERN Document Server

    Salazar, Manuel J

    2011-01-01

    In this paper we study the construction of a discrete solution for a hyperbolic system of partial differentials of the strongly coupled type. In its construction, the discrete separation of matricial variable method was followed. Two separate equations in differences were obtained: a singular matricial and the other one a Sturm Liouville vectorial problem, which by the superposition principle yield a stable discrete solution.

  12. (Anti-) de Sitter Electrically Charged Black Hole Solutions in Higher-Derivative Gravity

    CERN Document Server

    Lin, Kai; Pavan, A B; Abdalla, E

    2016-01-01

    In this paper, static electrically charged black hole solutions with cosmological constant are investigated in an Einstein-Hilbert theory of gravity with additional quadratic curvature terms. Beside the analytic Schwarzschild (Anti-) de Sitter solutions, non-Schwarzschild (Anti-) de Sitter solutions are also obtained numerically by employing the shooting method. The results show that there exist two groups of asymptotically (Anti-) de Sitter spacetimes for both charged and uncharged black holes. In particular, it was found that for uncharged black holes the first group can be reduced to the Schwarzschild (Anti-) de Sitter solution, while the second group is intrinsically different from a Schwarzschild (Anti-) de Sitter solution even when the charge and the cosmological constant become zero.

  13. Reactions of the radical cations of methylated benzene derivatives in aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Sehested, K.; Holcman, J.

    1978-03-23

    The radical cations of methylated benzene decompose in acid solution into the corresponding methylbenzyl radical and a proton. The rate constant for this reaction decreases by three orders of magnitude as the number of methyl groups increases from one to five. The rate constants can be correlated with the ionization potential of the parent compound. In neutral solution the reverse reaction to the acid-catalyzed OH adduct conversion occurs and the radical cations react with water to form the OH adduct. In slightly alkaline solution the radical cations of the higher methylated benzenes (n greater than or equal to 3) react with hydroxide ions forming the OH adduct.

  14. Efficient Syntheses of 1,2,3-Triazoloamide Derivatives Using Solid- and Solution-Phase Synthetic Approaches

    Directory of Open Access Journals (Sweden)

    Doohyun Lee

    2015-11-01

    Full Text Available Efficient synthetic routes for the preparation of secondary and tertiary 1,2,3-triazoloamide derivatives were developed. A secondary α-1,2,3-triazoloamide library was constructed and expanded by a previously developed solid-phase synthetic route and a tertiary 1,2,3-triazoloamide library was constructed by a parallel solution-phase synthetic route. The synthetic routes rely on amide formation with secondary amines and chloro-acid chlorides; SN2 reaction with sodium azide; and the selective [3 + 2] Hüisgen cycloaddition with appropriate terminal alkynes. The target secondary and tertiary 1,2,3-triazoloamide derivatives were obtained with three-diversity points in excellent overall yields and purities using the reported solid- and solution-phase synthetic routes, respectively.

  15. Application of adsorption process by activated carbon derived from scrap tires for Pb+2 removal from aqueous solutions

    OpenAIRE

    Edris Hoseinzadeh; Ali Reza Rahmani; Ghorban Asgari; Mohamad Taghi Samadi; Ghodratollah Roshanaei; Mohammad Reza Zare

    2013-01-01

    Background and Aim: Heavy metals have been recognized as very poisonous elements and their discharge into water sources can cause damaging effects on human and environmental health. The present study aimed at producing activated carbon from scrap tires and using it in removing Pb+2 from synthetic aqueous solutions. Materials and Methods: In this experimental study, activated carbon powder was derived from scrap tires under laboratory conditions. The effect of Pb (II) ions wi...

  16. Symmetries and exact solutions of the time fractional Harry-Dym equation with Riemann-Liouville derivative

    Science.gov (United States)

    Huang, Qing; Zhdanov, Renat

    2014-09-01

    In this paper, group analysis of the time fractional Harry-Dym equation with Riemann-Liouville derivative is performed. Its maximal symmetry group in Lie’s sense and the corresponding optimal system of subgroups are determined. Similarity reductions of the equation under study are performed. As a result, the reduced fractional ordinary differential equations are deduced, and some group invariant solutions in explicit form are obtained as well.

  17. Scattering from the Finite-Length, Dielectric Circular Cylinder: Part I - Derivation of an Analytical Solution

    Science.gov (United States)

    2015-07-01

    the direct response and the single and double ground bounce contributions. An arbitrarily oriented cylinder is treated by augmenting the solution with...response and the single and double ground bounce contributions. An arbitrarily oriented cylinder is treated by augmenting the solution with...angle in azimuth (measured from + x̂ ). Without the loss of generality, a vertically polarized (TMz) plane wave is taken as the source of excitation

  18. Unified derivation of exact solutions to the relativistic Coulomb problem: Lie algebraic approach

    Science.gov (United States)

    Panahi, H.; Baradaran, M.; Savadi, A.

    2015-10-01

    Exact algebraic solutions of the D-dimensional Dirac and Klein-Gordon equations for the Coulomb potential are obtained in a unified treatment. It is shown that two cases are reducible to the same basic equation, which can be solved exactly. Using the Lie algebraic approach, the general exact solutions of the problem are obtained within the framework of representation theory of the sl(2) Lie algebra.

  19. Corrosion Inhibition of Imidazoline Derivates with Benzene Rings on Mild Steel in CO2-Saturated Brine Solution

    Institute of Scientific and Technical Information of China (English)

    CHEN Guo-hao; ZHAO Jing-mao

    2012-01-01

    Corrosion inhibition of three imidazoline derivates with different numbers of benzcne rings,namely 2-phenyl-1-ethylamino imidazoline(CI-1),2-phcnyl-1-ethylamino-1-methylbenzyl quaternary imidazoline(CI-12) and 2-phcnyl-1-bcnzoyl ethylamino imidazoline(CI-13),on mild steel in CO2-saturated brine solution was evaluated by mass-loss method and potentiodynamic polarization method.The results show that the three imidazoline derivates can inhibit CO2 corrosion effectively with CI-12 ranking the highest.They mainly restrain the anodic dissolution and act as anodic-type inhibitors.The adsorptions of these derivates on the mild steel surface follow the Langmuir adsorption isothermal equation and belong to chemical adsorption.

  20. Solutions for the Cell Cycle in Cell Lines Derived from Human Tumors

    Directory of Open Access Journals (Sweden)

    B. Zubik-Kowal

    2006-01-01

    Full Text Available The goal of the paper is to compute efficiently solutions for model equations that have the potential to describe the growth of human tumor cells and their responses to radiotherapy or chemotherapy. The mathematical model involves four unknown functions of two independent variables: the time variable t and dimensionless relative DNA content x. The unknown functions can be thought of as the number density of cells and are solutions of a system of four partial differential equations. We construct solutions of the system, which allow us to observe the number density of cells for different t and x values. We present results of our experiments which simulate population kinetics of human cancer cells in vitro. Our results show a correspondence between predicted and experimental data.

  1. Explicit Derivation of Yang-Mills Self-Dual Solutions on non-Commutative Harmonic Space

    CERN Document Server

    Belhaj, A; Sahraoui, E L; Saidi, E H

    2001-01-01

    We develop the noncommutative harmonic space (NHS) analysis to study the problem of solving the non-linear constraint eqs of noncommutative Yang-Mills self-duality in four-dimensions. We show that this space, denoted also as NHS($\\eta,\\theta$), has two SU(2) isovector deformations $\\eta^{(ij)}$ and $\\theta^{(ij)}$ parametrising respectively two noncommutative harmonic subspaces NHS($\\eta,0$) and NHS($0,\\theta$) used to study the self-dual and anti self-dual noncommutative Yang-Mills solutions. We formulate the Yang-Mills self-dual constraint eqs on NHS($\\eta,0$) by extending the idea of harmonic analyticity to linearize them. Then we give a perturbative self-dual solution recovering the ordinary one. Finally we present the explicit computation of an exact self-dual solution.

  2. Removal of trivalent samarium from aqueous solutions by activated biochar derived from cactus fibres

    Institute of Scientific and Technical Information of China (English)

    Loukia Hadjittofi; Styliana Charalambous; Ioannis Pashalidis

    2016-01-01

    The efficiency of activated biochar fibres obtained fromOpuntia Ficus Indica regarding the sorption of trivalent samarium (Sm(III)) from aqueous solutions was investigated by batch experiments. The effect of various physicochemical parameters (e.g. pH, initial metal concentration, ionic strength, temperature and contact time) on the Sm(III) adsorption was studied and the surface species were characterized by FTIR spectroscopy prior to and after the lanthanide sorption. The experimental results showed that the acti-vated biochar fibres possessed extraordinary sorption capacity for Sm(III) in acidic solutions (qmax=90 g/kg, pH 3.0) and near neutral solutions (qmax=350 g/kg, pH 6.5). This was attributed to the formation of samarium complexes with the surface carboxylic moieties, available in high density on the lamellar structures of the bio-sorbent.

  3. Theoretical investigations into the nucleation of silica growth in basic solution part II--derivation and benchmarking of a first principles kinetic model of solution chemistry.

    Science.gov (United States)

    McIntosh, Grant J

    2013-10-28

    A kinetic model of silicate oligomerization in water, up to and including tetramer formation, has been compiled exclusively from rate constants derived from transition state theory based on either quantum chemical data (derived under a hybrid solvation framework) for all bond breaking-forming reactions, or using empirically-based approximated pKa's and diffusion coefficients for rate constants of pH-based and bimolecular steps. The rate constants, based on an exhaustive search of all relevant elementary steps, form the basis of our kinetic model; numerical solution of the resulting rate equations allows the simulation of the reaction system, given a set of initial conditions and with almost no restriction on concentrations, pH, or reaction time, in a matter of only minutes. The model, which we believe contains all possible isomers of both neutral and singly anionic clusters, has been extensively benchmarked and reproduces a number of important experimental observations in the range pH ≈ 4-10. In particular, it provides a good description of the dominant products; product yields and reaction times (also as a function of pH) are in agreement with experiment; the linear relationship between the log of the rate of silica dissolution and pH is well reproduced; the origin of silica scaling naturally arises; and we can also simulate the observed fourth order dependence of the rate of monomer consumption on H4SiO4 concentration. This should be a general approach to exploring solution phase chemistry, and could be a useful complement to more conventional molecular dynamics and Monte Carlo modelling approaches in understanding complex reaction networks in solution.

  4. Quasi-periodic solutions for d-dimensional beam equation with derivative nonlinear perturbation

    Energy Technology Data Exchange (ETDEWEB)

    Mi, Lufang, E-mail: milufang@126.com [Department of Mathematics, Binzhou University, Shandong 256600 (China); Cong, Hongzi, E-mail: conghongzi@dlut.edu.cn [School of Mathematical Sciences, Dalian University of Technology, Liaoning 116024 (China)

    2015-07-15

    In this paper, we consider the d-dimensional beam equation with convolution potential under periodic boundary conditions. We will apply the Kolmogorov-Arnold-Moser theorem in Eliasson and Kuksin [Ann. Math. 172, 371-435 (2010)] into this system and obtain that for sufficiently small ε, there is a large subset S′ of S such that for all s ∈ S′, the solution u of the unperturbed system persists as a time-quasi-periodic solution which has all Lyapunov exponents equal to zero and whose linearized equation is reducible to constant coefficients.

  5. New solutions of reflection equation derived from type B BMW algebras

    Science.gov (United States)

    Häring-Oldenburg, Reinhard

    1996-09-01

    We use B-type knot theory to find new solutions of Sklyanin's reflection equation in a systematic way. This generalizes the well known Baxterization of Birman - Wenzl algebras and should describe integrable systems which are restricted to a half plane.

  6. Radiolytic degradation of gallic acid and its derivatives in aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Melo, R. [Instituto Tecnologico e Nuclear, UCQR, Estrada Nacional No. 10, Apartado 21, 2686-953, Sacavem (Portugal); Leal, J.P. [Instituto Tecnologico e Nuclear, UCQR, Estrada Nacional No. 10, Apartado 21, 2686-953, Sacavem (Portugal); Centro Quimica e Bioquimica, Faculdade de Ciencias da Universidade de Lisboa, 1749-016 Lisboa (Portugal); Takacs, E., E-mail: takacs@iki.kfki.hu [Institute of Isotopes, Hungarian Academy of Sciences, P.O. Box 77, H-1525 Budapest (Hungary); Wojnarovits, L. [Institute of Isotopes, Hungarian Academy of Sciences, P.O. Box 77, H-1525 Budapest (Hungary)

    2009-12-30

    Polyphenols, like gallic acid (GA) released in the environment in larger amount, by inducing some unwanted oxidations, may constitute environmental hazard: their concentration in wastewater should be controlled. Radiolytic degradation of GA was investigated by pulse radiolysis and final product techniques in dilute aqueous solution. Subsidiary measurements were made with 3,4,5-trimethoxybenzoic acid (TMBA) and 3,4,5-trihydroxy methylbenzoate (MGA). The hydroxyl radical and hydrogen atom intermediates of water radiolysis react with the solute molecules yielding cyclohexadienyl radicals. The radicals formed in GA and MGA solutions in acid/base catalyzed water elimination decay to phenoxyl radicals. This reaction is not observed in TMBA solution. The hydrated electron intermediate of water decomposition adds to the carbonyl oxygen, the anion thus formed protonates on the ring forming cyclohexadienyl radical or on the carbonyl group forming carbonyl centred radical. The GA intermediates formed during reaction with primary water radicals in presence of oxygen transform to non-aromatic molecules, e.g., to aliphatic carboxylic acids.

  7. Deriving analytic solutions for compact binary inspirals without recourse to adiabatic approximations

    CERN Document Server

    Galley, Chad R

    2016-01-01

    We utilize the dynamical renormalization group formalism to calculate the real space trajectory of a compact binary inspiral for long times via a systematic resummation of secularly growing terms. This method generates closed form solutions without orbit averaging, and the accuracy can be systematically improved. The expansion parameter is $v^5 \

  8. The Removal of Phenol and Its Derivatives from Aqueous Solutions by Adsorption on Petroleum Asphaltene

    Directory of Open Access Journals (Sweden)

    Omer El-Amin Ahmed Adam

    2013-01-01

    Full Text Available This research describes the adsorption of phenol and o-substituted phenols and xylenol isomers on petroleum asphaltenes from aqueous solution. The results revealed that the adsorption equilibrium data were best fitted with the generalized and Freundlich isotherms. For o-substituted phenols, it was found that electron-withdrawing groups increase the adsorption capacity. The uptake of these phenols decreases in the order: o-nitrophenol > o-chlorophenol > o-aminophenol > o-cresol > phenol, while the adsorption of xylenol isomers decreases in the order: 2,6-xylenol > 2,5-xylenol > 3,5-xylenol > 3,4-xylenol. Batch equilibrium results at different temperatures suggest that the adsorption of 2,6-xylenol and 3,5-xylenol onto asphaltene is an endothermic process, values obtained were positive indicating a nonspontaneous process with increasing randomness at the solid-solution interface. The influence of solution pH on the adsorption of 3,5-xylenol on asphaltenes was also investigated. The adsorption process was found to be independent on the solution pH. The adsorption capacity of 3,5-xylenol was found to increase with the decrease in particle size of the adsorbent.

  9. Removal of Cu(II Ions from Aqueous Solutions by Adsorption Onto Activated Carbon Derived From Olive Waste Cakes

    Directory of Open Access Journals (Sweden)

    Hesham G. Ibrahim

    2016-04-01

    Full Text Available This paper studied the ability of using local activated carbon (LAC derived from olive waste cakes as an adsorbent for the removal of Cu(II ions from aqueous solution by batch operation. Various operating parameters such as solution pH, adsorbent dosage, initial metal ions concentration, and equilibrium contact time have been studied. The results indicated that the adsorption of Cu(II increased with the increasing pH, and the optimum solution pH for the adsorption of Cu(II was found to be 5. The adsorption process increases with increasing dosage of LAC, also the amount of Cu(II removed changes with Cu(II initial concentration and contact time. Adsorption was rapid and occurred within 25 min. for Cu(II concentration range from 60 to 120 mg/l isothermally at 30±1 oC. Maximum adsorption occurs at Cu(II initial concentration lesser than 100 mg/l by using adsorbent dosage (1.2 g/l. The equilibrium adsorption data for Cu(II were fitted well with the Langmuir and Freundlich adsorption isotherm models. The maximum adsorption capacity of LAC was found to be 106.383 mg/g. So, the results indicated the suitability use of the activated carbon derived from olive waste cakes (LAC as low cost and natural material for reliable removal of Cu(II from water and wastewater effluents.

  10. Solution-derived sodalite made with Si- and Ge-ethoxide precursors for immobilizing electrorefiner salt

    Energy Technology Data Exchange (ETDEWEB)

    Riley, Brian J.; Lepry, William C.; Crum, Jarrod V.

    2016-01-01

    Chlorosodalite has the general form of Na8(AlSiO4)6Cl2 and this paper describes experiments conducted to synthesize sodalite to immobilize a mixed chloride salt using solution-based techniques. Sodalites were made using different Group IV contributions from either Si(OC2H5)4 or Ge(OC2H5)4, NaAlO2, and a simulated spent electrorefiner salt solution containing a mixture of alkali, alkaline earth, and lanthanide chlorides. Additionally, 6 glass binders at low loadings of 5 mass% were evaluated as sintering aids for the consolidation process. The approach of using the organic Group IV additives can be used to produce large quantities of sodalite at room temperature and shows promise over a method where colloidal silica is used as the silica source. However, the small particle sizes inhibited densification during pressure-less sintering.

  11. Soliton solutions in two-dimensional Lorentz-violating higher derivative scalar theory

    CERN Document Server

    Passos, E; Brito, F A; Menezes, R; Mota-Silva, J C; Santos, J R L

    2016-01-01

    This paper shows a new approach to obtain analytical topological defects for a 2D Myers-Pospelov Lagrangian for two scalar fields. Such a Lagrangian presents higher-order kinetic terms, which lead us to equations of motion which are non-trivial to be integrated. Here we describe three possible scenarios for the equations of motion, named by time-like, space-like and light-like respectively. We started our investigation with a kink-like travelling wave Ansatz for the free theory, which led us to constraints for the dispersion relations of each scenario. We also introduced a method to obtain analytical solution for the general theory in the three mentioned scenarios. We exemplified the method and discussed the behavior of the defects solutions.

  12. Deriving Coarse-Grained Charges from All-Atom Systems: An Analytic Solution.

    Science.gov (United States)

    McCullagh, Peter; Lake, Peter T; McCullagh, Martin

    2016-09-13

    An analytic method to assign optimal coarse-grained charges based on electrostatic potential matching is presented. This solution is the infinite size and density limit of grid-integration charge-fitting and is computationally more efficient by several orders of magnitude. The solution is also minimized with respect to coarse-grained positions which proves to be an extremely important step in reproducing the all-atom electrostatic potential. The joint optimal-charge optimal-position coarse-graining procedure is applied to a number of aggregating proteins using single-site per amino acid resolution. These models provide a good estimate of both the vacuum and Debye-Hückel screened all-atom electrostatic potentials in the vicinity and in the far-field of the protein. Additionally, these coarse-grained models are shown to approximate the all-atom dimerization electrostatic potential energy of 10 aggregating proteins with good accuracy.

  13. Chloramphenicol Derivatives as Antibacterial and Anticancer Agents: Historic Problems and Current Solutions

    Directory of Open Access Journals (Sweden)

    George P. Dinos

    2016-06-01

    Full Text Available Chloramphenicol (CAM is the D-threo isomer of a small molecule, consisting of a p-nitrobenzene ring connected to a dichloroacetyl tail through a 2-amino-1,3-propanediol moiety. CAM displays a broad-spectrum bacteriostatic activity by specifically inhibiting the bacterial protein synthesis. In certain but important cases, it also exhibits bactericidal activity, namely against the three most common causes of meningitis, Haemophilus influenzae, Streptococcus pneumoniae and Neisseria meningitidis. Resistance to CAM has been frequently reported and ascribed to a variety of mechanisms. However, the most important concerns that limit its clinical utility relate to side effects such as neurotoxicity and hematologic disorders. In this review, we present previous and current efforts to synthesize CAM derivatives with improved pharmacological properties. In addition, we highlight potentially broader roles of these derivatives in investigating the plasticity of the ribosomal catalytic center, the main target of CAM.

  14. Quantum-mechanical study and spectral analysis on some derivatives of Rhodamine in solutions

    Science.gov (United States)

    Benchea, Andreea-Celia; Babusca, Daniela; Dimitriu, Dan Gheorghe; Dorohoi, Dana Ortansa

    2017-02-01

    Rhodamine derivatives (B and 6G) are heterocyclic compounds, related to florone. They are widely used as dyes with numerous biotechnological applications. The quantum-mechanical, electro-optical and spectral properties of the isolated molecules in the ground state were determined using molecular modeling programs. The visible electronic absorption spectra of 6G and B Rhodamine were recorded in solvents with different macroscopic parameters. Dipolar moments and polarizabilities of the studied Rhodamines in the excited state were determined by solvatochromic study.

  15. Derivation and Solution of Multifrequency Radiation Diffusion Equations for Homogeneous Refractive Lossy Media

    Energy Technology Data Exchange (ETDEWEB)

    Shestakov, A I; Vignes, R M; Stolken, J S

    2010-01-05

    Starting from the radiation transport equation for homogeneous, refractive lossy media, we derive the corresponding time-dependent multifrequency diffusion equations. Zeroth and first moments of the transport equation couple the energy density, flux and pressure tensor. The system is closed by neglecting the temporal derivative of the flux and replacing the pressure tensor by its diagonal analogue. The system is coupled to a diffusion equation for the matter temperature. We are interested in modeling annealing of silica (SiO{sub 2}). We derive boundary conditions at a planar air-silica interface taking account of reflectivities. The spectral dimension is discretized into a finite number of intervals leading to a system of multigroup diffusion equations. Three simulations are presented. One models cooling of a silica slab, initially at 2500 K, for 10 s. The other two are 1D and 2D simulations of irradiating silica with a CO{sub 2} laser, {lambda} = 10.59 {micro}m. In 2D, we anneal a disk (radius = 0.4, thickness = 0.4 cm) with a laser, Gaussian profile (r{sub 0} = 0.5 mm for 1/e decay).

  16. X-ray CT-Derived Soil Characteristics Explain Varying Air, Water, and Solute Transport Properties across a Loamy Field

    DEFF Research Database (Denmark)

    Paradelo Pérez, Marcos; Katuwal, Sheela; Møldrup, Per;

    2016-01-01

    The characterization of soil pore space geometry is important for explaining fluxes of air, water, and solutes through soil and understanding soil hydrogeochemical functions. X-ray computed tomography (CT) can be applied for this characterization, and in this study CT-derived parameters were used...... be factors that increased the uncertainty of the relationships. Nevertheless, the results confirmed the potential of X-ray CT visualization techniques for estimating fluxes through soil at the field scale....... to explain water, air, and solute transport through soil. Forty-five soil columns (20 by 20 cm) were collected from an agricultural field in Estrup, Denmark, and subsequently scanned using a medical CT scanner. Nonreactive tracer leaching experiments were performed in the laboratory along with measurements...

  17. Mild solutions for a problem involving fractional derivatives in the nonlinearity and in the non-local conditions

    Directory of Open Access Journals (Sweden)

    Tatar Nasser-eddine

    2011-01-01

    Full Text Available Abstract A second-order abstract problem of neutral type with derivatives of non-integer order in the nonlinearity as well as in the nonlocal conditions is investigated. This model covers many of the existing models in the literature. It extends the integer order case to the fractional case in the sense of Caputo. A fixed point theorem is used to prove existence of mild solutions. AMS Subject Classification 26A33, 34K40, 35L90, 35L70, 35L15, 35L07

  18. A Novel Operational Matrix of Caputo Fractional Derivatives of Fibonacci Polynomials: Spectral Solutions of Fractional Differential Equations

    Directory of Open Access Journals (Sweden)

    Waleed M. Abd-Elhameed

    2016-09-01

    Full Text Available Herein, two numerical algorithms for solving some linear and nonlinear fractional-order differential equations are presented and analyzed. For this purpose, a novel operational matrix of fractional-order derivatives of Fibonacci polynomials was constructed and employed along with the application of the tau and collocation spectral methods. The convergence and error analysis of the suggested Fibonacci expansion were carefully investigated. Some numerical examples with comparisons are presented to ensure the efficiency, applicability and high accuracy of the proposed algorithms. Two accurate semi-analytic polynomial solutions for linear and nonlinear fractional differential equations are the result.

  19. Acoustical studies of some derivatives of 1,5-benzodiazepines formamide and tetrahydrofuran solutions at 298.15 K

    Science.gov (United States)

    Baluja, S.; Movaliya, J.; Godvani, N.

    2009-12-01

    Some derivatives of 1,5-benzodiazepines have been synthesized and characterized by TLC, IR, NMR, and Mass Spectral data. The ultrasonic velocity, density and viscosity of these synthesized compounds have been measured in dimethyl formamide and tetrahydrofuran at 298.15 K. From these experimental data, various acoustical parameters such as isentropic compressibility, intermolecular free path length, molar compressibility, Rao’s molar sound function, relaxation strength, internal pressure, free volume etc., have been calculated which helps in understanding the molecular interactions occurring in these solutions.

  20. Two-photon absorption of [2.2]paracyclophane derivatives in solution: A theoretical investigation

    Science.gov (United States)

    Ferrighi, Lara; Frediani, Luca; Fossgaard, Eirik; Ruud, Kenneth

    2007-12-01

    The two-photon absorption of a class of [2.2]paracyclophane derivatives has been studied using quadratic response and density functional theories. For the molecules investigated, several effects influencing the two-photon absorption spectra have been investigated, such as side-chain elongation, hydrogen bonding, the use of ionic species, and solvent effects, the latter described by the polarizable continuum model. The calculations have been carried out using a recent parallel implementation of the polarizable continuum model in the DALTON code. Special attention is given to those aspects that could explain the large solvent effect on the two-photon absorption cross sections observed experimentally for this class of compounds.

  1. Potential biosorbent derived from Calligonum polygonoides for removal of methylene blue dye from aqueous solution.

    Science.gov (United States)

    Nasrullah, Asma; Khan, Hizbullah; Khan, Amir Sada; Man, Zakaria; Muhammad, Nawshad; Khan, Muhammad Irfan; Abd El-Salam, Naser M

    2015-01-01

    The ash of C. polygonoides (locally called balanza) was collected from Lakki Marwat, Khyber Pakhtunkhwa, Pakistan, and was utilized as biosorbent for methylene blue (MB) removal from aqueous solution. The ash was used as biosorbent without any physical or chemical treatment. The biosorbent was characterized by using various techniques such as Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). The particle size and surface area were measured using particle size analyzer and Brunauer-Emmett-Teller equation (BET), respectively. The SEM and BET results expressed that the adsorbent has porous nature. Effects of various conditions such as initial concentration of methylene blue (MB), initial pH, contact time, dosage of biosorbent, and stirring rate were also investigated for the adsorption process. The rate of the adsorption of MB on biomass sample was fast, and equilibrium has been achieved within 1 hour. The kinetics of MB adsorption on biosorbent was studied by pseudo-first- and pseudo-second-order kinetic models and the pseudo-second-order has better mathematical fit with correlation coefficient value (R (2)) of 0.999. The study revealed that C. polygonoides ash proved to be an effective, alternative, inexpensive, and environmentally benign biosorbent for MB removal from aqueous solution.

  2. Adsorption of Cu(II from aqueous solution using activated carbon derived from mangosteen peel

    Directory of Open Access Journals (Sweden)

    Yandan Chen

    2012-11-01

    Full Text Available Effects of the mixing method of K2CO3 with the source biomass and thermal history on the properties of the mangosteen peel activated carbons (MSACs were investigated. The one-step impregnation activation process was found to be remarkably effective in increasing the mesoporosity of the activated carbon (L-MSAC as well as BET surface area (SBET and total pore volume, compared to the solid-solid dry mixing method in a two-stage process. The better fit of Langmuir isotherm indicates a maximum adsorption capacity of Cu(II to be 21.74 mg•g−1 for L-MSAC, which makes it a promising adsorbent for the removal of copper ion from aqueous solutions.

  3. Orientational ordering of solution derived epitaxial Gd-doped ceria nanowires induced by nanoscratching

    Energy Technology Data Exchange (ETDEWEB)

    Zabaleta, Jone; Mestres, Narcis; Abellan, Patricia; Gibert, Marta; Sandiumenge, Felip; Puig, Teresa; Obradors, Xavier, E-mail: jzabaleta@icmab.es, E-mail: narcis.mestres@icmab.es [Institut de Ciencia de Materials de Barcelona, ICMAB-CSIC, Campus de la UAB, Bellaterra, 08193 Barcelona, Catalunya (Spain)

    2010-01-15

    When one-dimensional nanostructures are epitaxially grown on a substrate a key goal is to control the nanowire's position and orientation. Nanoscratching of single crystalline (001)- LaAlO{sub 3} substrates is demonstrated to be extraordinarily effective in directing the self-assembly of Ce{sub 0.9}Gd{sub 0.1}O{sub 2-y} epitaxial nanowires grown by chemical solution deposition. The local anisotropic elastic strain field imposed by the indentation lines is responsible for the breaking of the pre-existing orientation energy degeneracy and selects the nanowires' orientation parallel to the lines to an extent that can reach 100%.

  4. Wafer-scale solution-derived molecular gate dielectrics for low-voltage graphene electronics

    Energy Technology Data Exchange (ETDEWEB)

    Sangwan, Vinod K.; Jariwala, Deep; McMorrow, Julian J.; He, Jianting; Lauhon, Lincoln J. [Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208 (United States); Everaerts, Ken [Department of Chemistry, Northwestern University, Evanston, Illinois 60208 (United States); Grayson, Matthew [Department of Electrical Engineering and Computer Science, Northwestern University, Evanston, Illinois 60208 (United States); Marks, Tobin J., E-mail: t-marks@northwestern.edu, E-mail: m-hersam@northwestern.edu; Hersam, Mark C., E-mail: t-marks@northwestern.edu, E-mail: m-hersam@northwestern.edu [Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208 (United States); Department of Chemistry, Northwestern University, Evanston, Illinois 60208 (United States)

    2014-02-24

    Graphene field-effect transistors are integrated with solution-processed multilayer hybrid organic-inorganic self-assembled nanodielectrics (SANDs). The resulting devices exhibit low-operating voltage (2 V), negligible hysteresis, current saturation with intrinsic gain >1.0 in vacuum (pressure < 2 × 10{sup −5} Torr), and overall improved performance compared to control devices on conventional SiO{sub 2} gate dielectrics. Statistical analysis of the field-effect mobility and residual carrier concentration demonstrate high spatial uniformity of the dielectric interfacial properties and graphene transistor characteristics over full 3 in. wafers. This work thus establishes SANDs as an effective platform for large-area, high-performance graphene electronics.

  5. Wafer-scale solution-derived molecular gate dielectrics for low-voltage graphene electronics

    Science.gov (United States)

    Sangwan, Vinod K.; Jariwala, Deep; Everaerts, Ken; McMorrow, Julian J.; He, Jianting; Grayson, Matthew; Lauhon, Lincoln J.; Marks, Tobin J.; Hersam, Mark C.

    2014-02-01

    Graphene field-effect transistors are integrated with solution-processed multilayer hybrid organic-inorganic self-assembled nanodielectrics (SANDs). The resulting devices exhibit low-operating voltage (2 V), negligible hysteresis, current saturation with intrinsic gain >1.0 in vacuum (pressure < 2 × 10-5 Torr), and overall improved performance compared to control devices on conventional SiO2 gate dielectrics. Statistical analysis of the field-effect mobility and residual carrier concentration demonstrate high spatial uniformity of the dielectric interfacial properties and graphene transistor characteristics over full 3 in. wafers. This work thus establishes SANDs as an effective platform for large-area, high-performance graphene electronics.

  6. Removal of Lead (II Ions from Aqueous Solutions onto Activated Carbon Derived from Waste Biomass

    Directory of Open Access Journals (Sweden)

    Murat Erdem

    2013-01-01

    Full Text Available The removal of lead (II ions from aqueous solutions was carried out using an activated carbon prepared from a waste biomass. The effects of various parameters such as pH, contact time, initial concentration of lead (II ions, and temperature on the adsorption process were investigated. Energy Dispersive X-Ray Spectroscopy (EDS analysis after adsorption reveals the accumulation of lead (II ions onto activated carbon. The Langmuir and Freundlich isotherm models were applied to analyze equilibrium data. The maximum monolayer adsorption capacity of activated carbon was found to be 476.2 mg g−1. The kinetic data were evaluated and the pseudo-second-order equation provided the best correlation. Thermodynamic parameters suggest that the adsorption process is endothermic and spontaneous.

  7. A simple derivation of the critical condition for the ultrasonic atomization of polymer solutions.

    Science.gov (United States)

    Kim, Hyungsu; Lee, Jaegeun; Won, You-Yeon

    2015-08-01

    A simple model is proposed for the ultrasonic atomization of polymer solutions. In this model, the atomization process is approximated as an equilibrium process. It is shown that the minimum attainable droplet size is determined by two parameters, the (Rayleigh) acoustic pressure acting on the surface of the liquid, and the surface tension of the liquid. Increasing the viscosity of the liquid suppresses the formation of small-sized droplets because of increased attenuation of the sound wave and thus decreased acoustic pressure. Lowering the surface tension of the liquid (e.g., by spreading a surfactant film on the liquid surface) has the opposite effect of enhancing the formation of smaller droplets. Also, there exists a maximum limit for the droplet size, because when the produced droplet is too large, the aspiration flow is unable to carry the droplet against sedimentation. These predictions are supported by experimental observations.

  8. Sensing of polymeric sensor-based rhodamine B derivative for metal cations in complete aqueous solution

    Indian Academy of Sciences (India)

    TONG-MOU GENG; XIE WANG; FENG ZHU; HUI JIANG; YU WANG

    2017-02-01

    The water-soluble polymeric chemosensor poly(AM-GRBD) has been synthesized by precipitation copolymerization with the functional monomer, GRBD, which was made of N$"$-(rhodamine B-yl) diethylenetriamineand glycidyl methacrylate (GMA) and a hydrophilic co-monomer acrylamide (AM). The chemical sensor behaved as a fluorescent and chromogenic sensor towards various heavy metal cations and transition metal cations; particularly,Cr$^{3+}$, Fe$^{3+}$ and Hg$^{2+}$ ions in completely aqueous media. The fluorescence of poly(AM-GRBD) was enhanced by Cr$^{3+}, Fe$^{3+}$ and Hg$^{2+}$ metal ions. Moreover, during titration of Cr$^{3+}$, Hg$^{2+}$ or Fe$^{3+}$ to the aqueous solution of poly(AM-GRBD), the visual colour changed from colourless to pink or brown yellow under visible light.

  9. Structure solution with ARCIMBOLDO using fragments derived from distant homology models.

    Science.gov (United States)

    Sammito, Massimo; Meindl, Kathrin; de Ilarduya, Iñaki M; Millán, Claudia; Artola-Recolons, Cecilia; Hermoso, Juan A; Usón, Isabel

    2014-09-01

    Molecular replacement, one of the general methods used to solve the crystallographic phase problem, relies on the availability of suitable models for placement in the unit cell of the unknown structure in order to provide initial phases. ARCIMBOLDO, originally conceived for ab initio phasing, operates at the limit of this approach, using small, very accurate fragments such as polyalanine α-helices. A distant homolog may contain accurate building blocks, but it may not be evident which sub-structure is the most suitable purely from the degree of conservation. Trying out all alternative possibilities in a systematic way is computationally expensive, even if effective. In the present study, the solution of the previously unknown structure of MltE, an outer membrane-anchored endolytic peptidoglycan lytic transglycosylase from Escherichia coli, is described. The asymmetric unit contains a dimer of this 194 amino acid protein. The closest available homolog was the catalytic domain of Slt70 (PDB code 1QTE). Originally, this template was used omitting contiguous spans of aminoacids and setting as many ARCIMBOLDO runs as models, each aiming to locate two copies sequentially with PHASER. Fragment trimming against the correlation coefficient prior to expansion through density modification and autotracing in SHELXE was essential. Analysis of the figures of merit led to the strategy to optimize the search model against the experimental data now implemented within ARCIMBOLDO-SHREDDER (http://chango.ibmb.csic.es/SHREDDER). In this strategy, the initial template is systematically shredded, and fragments are scored against each unique solution of the rotation function. Results are combined into a score per residue and the template is trimmed accordingly.

  10. Colorimetric chemosensor of symmetrical benzoylthiourea derivatives as for detection of Cu2+ in aqueous solution

    Science.gov (United States)

    Hamedan, N. A.; Hasan, S.; Zaki, H. M.; Alias, N. Z.

    2017-02-01

    A novel receptor, designed with a combination of oxygen (O), nitrogen (N) and sulfur (S) -binding sites for metal ions was synthesized. Ortho (A), meta (B) and para (C) bearing benzoyl thiourea were designed and synthesized with triamine group to apply as colorimetric chemosensors for detection of Cu2+. The structure was confirmed by characterized the compound using Elemental analysis, Fourier Infrared (FTIR) and proton Nuclear Magnetic Resonance (1H NMR) spectroscopy. Functional groups of C=O, N-H, C=N and C=S were found at 1677 cm-1, 3240 cm-1, 1591 cm-1, 1024 cm-1 respectively while 1H NMR shows peaks of alkane (CH2), benzene (Ar-H), CONH, CSNH at 3.68 – 4.14, 7.16 – 7.86, 8.74, and 9.2 respectively. Elemental analysis for A, B and C C20H21N5O2S2Br2 found was compatible with the expected theoretical calculation. For an application, all of these three sensors showed excellent colorimetric specific selectivity and high sensitivity for Cu2+ in acetonitrile/water binary solutions, so only A was selected for further studies towards sensitivity. When Cu2+ was added to the solution of A, a dramatic color change from yellow to green, while other cations Fe2+, Zn2+, Ni2+, Co2+, Cr3+ and Mn2+ did not interfere with the recognition process for Cu2+. The detection limit of the sensor C toward Cu2+ was 1.15 x 10-5 M, which is less sensitive that sensor A and B with a detection limit of 6.2 x 10-6 M and 1.5 x 10-6 M respectively. This indicated that the sensor A and B might be useful as an efficient chemical sensor.

  11. Lignocellulosic-derived modified agricultural waste: development, characterisation and implementation in sequestering pyridine from aqueous solutions.

    Science.gov (United States)

    Ahmed, Md Juned K; Ahmaruzzaman, M; Reza, Ruhul A

    2014-08-15

    The development and characterisation of modified agricultural waste (MAW) by H3PO4 activation is addressed in this study for sequestering pyridine from aqueous solutions. The adsorbent is characterised by carbon, hydrogen and nitrogen content of 55.53%, 3.28% and 0.98% respectively. The adsorbent also shows acidic (carboxylic, lactonic, phenolic groups) and basic carbon surface functionalities, functional groups viz. hydroxyl, carboxylic acid and bounded water molecules, BET surface area of 1254.67 m(2) g(-1), heterogeneous surface morphology and graphite like XRD patterns. Adsorption of pyridine is executed to evaluate the adsorptive uptake in batch (q(e)=107.18 mg g(-1)) as well as in column system (q(e)=140.94 mg g(-1)). The adsorption process followed the pseudo-second-order kinetics with the Langmuir isotherm best representing the equilibrium adsorption data. The thermodynamic parameters (ΔH(o)=9.39 kJ mol(-1), ΔG(o)=-5.99 kJ mol(-1), ΔS(o)=50.76 J K(-1) mol(-1)) confirm the endothermic and spontaneous nature of the adsorption process with increase in randomness at solid/solution interface. The adsorption mechanism is governed by electrostatic and π-π dispersive interactions as well as by a two stage diffusion phenomena. Thermally regenerated spent MAW exhibited better adsorption efficiency for five adsorption-desorption cycles than chemically regenerated. The low-cost of MAW (USD 10.714 per kg) and favourable adsorption parameters justifies its use in the adsorptive removal of pyridine.

  12. Solution structure of telomere binding domain of AtTRB2 derived from Arabidopsis thaliana

    Energy Technology Data Exchange (ETDEWEB)

    Yun, Ji-Hye [Department of Biochemistry, College of Life Science and Biotechnology, Yonsei University, Seoul 120-749 (Korea, Republic of); Lee, Won Kyung [Department of Systems Biology, College of Life Science and Biotechnology, Yonsei University, Seoul 120-749 (Korea, Republic of); Kim, Heeyoun [Department of Biochemistry, College of Life Science and Biotechnology, Yonsei University, Seoul 120-749 (Korea, Republic of); Kim, Eunhee; Cheong, Chaejoon [Magnetic Resonance Team, Korea Basic Science Institute (KBSI), Ochang, Chungbuk 363-883 (Korea, Republic of); Cho, Myeon Haeng [Department of Systems Biology, College of Life Science and Biotechnology, Yonsei University, Seoul 120-749 (Korea, Republic of); Lee, Weontae, E-mail: wlee@spin.yonsei.ac.kr [Department of Biochemistry, College of Life Science and Biotechnology, Yonsei University, Seoul 120-749 (Korea, Republic of)

    2014-09-26

    Highlights: • We have determined solution structure of Myb domain of AtTRB2. • The Myb domain of AtTRB2 is located in the N-terminal region. • The Myb domain of AtTRB2 binds to plant telomeric DNA without fourth helix. • Helix 2 and 3 of the Myb domain of AtTRB2 are involved in DNA recognition. • AtTRB2 is a novel protein distinguished from other known plant TBP. - Abstract: Telomere homeostasis is regulated by telomere-associated proteins, and the Myb domain is well conserved for telomere binding. AtTRB2 is a member of the SMH (Single-Myb-Histone)-like family in Arabidopsis thaliana, having an N-terminal Myb domain, which is responsible for DNA binding. The Myb domain of AtTRB2 contains three α-helices and loops for DNA binding, which is unusual given that other plant telomere-binding proteins have an additional fourth helix that is essential for DNA binding. To understand the structural role for telomeric DNA binding of AtTRB2, we determined the solution structure of the Myb domain of AtTRB2 (AtTRB2{sub 1–64}) using nuclear magnetic resonance (NMR) spectroscopy. In addition, the inter-molecular interaction between AtTRB2{sub 1–64} and telomeric DNA has been characterized by the electrophoretic mobility shift assay (EMSA) and NMR titration analyses for both plant (TTTAGGG)n and human (TTAGGG)n telomere sequences. Data revealed that Trp28, Arg29, and Val47 residues located in Helix 2 and Helix 3 are crucial for DNA binding, which are well conserved among other plant telomere binding proteins. We concluded that although AtTRB2 is devoid of the additional fourth helix in the Myb-extension domain, it is able to bind to plant telomeric repeat sequences as well as human telomeric repeat sequences.

  13. SOLUTION PROPERTIES OF ANTITUMOR CARBOXYMETHYLATED DERIVATIVES OF α-(1→3)-D-GLUCAN FROM GANODERMA LUCIDUM

    Institute of Scientific and Technical Information of China (English)

    Li-na Zhang; Mei Zhang; Jing-hua Chen; Fan-bo Zeng

    2001-01-01

    Fractions of a water insoluble α-(1→3)-D-glucan (GL) extracted from Ganoderma lucidum were carboxymethylated (CM) to obtain water-soluble carboxymethylated derivatives (CM-GL) having a degree of substitution (DS) of 0.38~0.51. Weight-average molecular weight Mw and intrinsic viscosity [η] of the samples CM-GL were measured by gel permeation chromatography combined with laser light scattering (GPC-LLS) and viscometry. The CM-GL exhibits a stiffer chain in aqueous solution at 25℃ than the original glucan. The antitumor activities against Ehrlich ascites carcinoma (EAC,5 × 106) of the carboxymethylated derivatives from the α-glucan and curdlan, a β-glucan, are significantly higher than those of the original glucans. The effects of the relatively low molecular weight, expanded chains and better water-solubility of the CM-GL on the enhancement of antitumor activity could not be neglected. The chain stiffness decreased speedily with increase of temperature from 40 to 60℃ or NaOH concentration from 0.1 to 0.4 in the solution, respectively, and the change of the chain stiffness is reversible.

  14. Photostability of alpha-tocopherol ester derivatives in solutions and liposomes. Spectroscopic and LC-MS studies.

    Science.gov (United States)

    Neunert, Grazyna; Szwengiel, Artur; Walejko, Piotr; Witkowski, Stanislaw; Polewski, Krzysztof

    2016-07-01

    α-Tocopherol (Toc) is known to degrade to the tocopheroxyl radicals (Toc) by exposure to UV light irradiation. In the present study, the stability of Toc ester derivatives exposed to UV light was investigated and compared with Toc in organic solution and in phospholipid vesicles. To follow the depletion of Toc and its esters the absorbance and fluorescence methods were applied whereas degradation products were detected using LC-MS method. The irradiation with UVB light of air-equilibrated solutions of di-α-Tocopheryl malonate (DTMO), α-Tocopheryl malonate (TMO) and α-Tocopheryl succinate (TS) strongly modifies their absorption and fluorescence spectra. Upon UVB irradiation, absorption band at 279/285nm becomes less pronounced indicating the photodegradation of esters. During irradiation, the fluorescence maximum of esters at 305nm shifts to 326nm, a maximum characteristic for Toc. Photorecovery of Toc from its esters derivatives was finally confirmed by LC-MS method. Among studied esters, only α-tocopheryl nicotinate (TN) did not undergo depletion and appeared resistant to UVB radiation. Kinetic studies indicated that photoinduced transformation occurs through the first order consecutive reaction chain mechanism. The photodissociation of Toc esters in the liposomes occurred with one order of magnitude slower than in organic solvents. Using MS/MS method it was found that final stable product of irradiation was α-tocopheryl quinone (TQ), an animal and plant metabolite of Toc.

  15. In situ x-ray diffraction of solution-derived ferroelectric thin films for quantitative phase and texture evolution measurement

    Science.gov (United States)

    Nittala, Krishna; Mhin, Sungwook; Jones, Jacob L.; Robinson, Douglas S.; Ihlefeld, Jon F.; Brennecka, Geoff L.

    2012-11-01

    An in situ measurement technique is developed and presented, which utilizes x-rays from a synchrotron source with a two-dimensional detector to measure thin film microstructural and crystallographic evolution during heating. A demonstration experiment is also shown wherein the measured diffraction patterns are used to describe phase and texture evolution during heating and crystallization of solution-derived thin films. The diffraction images are measured sequentially while heating the thin film with an infrared lamp. Data reduction methodologies and representations are also outlined to extract phase and texture information from the diffraction images as a function of time and temperature. These techniques and data reduction methods are demonstrated during crystallization of solution-derived lead zirconate titanate ferroelectric thin films heated at a rate of 30 °C/min and using an acquisition time of 8 s. During heating and crystallization, a PtxPb type phase was not observed. A pyrochlore phase was observed prior to the formation and growth of the perovskite phase. The final crystallized films are observed to have both 111 and 100 texture components. The in situ measurement methodology developed in this work allows for acquiring diffraction images in times as low as 0.25 s and can be used to investigate changes during crystallization at faster heating rates. Moreover, the experiments are shown to provide unique information during materials processing.

  16. SOLUTIONING

    Directory of Open Access Journals (Sweden)

    Maria de Hoyos Guajardo, Ph.D. Candidate, M.Sc., B.Eng.

    2004-11-01

    Full Text Available The theory that is presented below aims to conceptualise how a group of undergraduate students tackle non-routine mathematical problems during a problem-solving course. The aim of the course is to allow students to experience mathematics as a creative process and to reflect on their own experience. During the course, students are required to produce a written ‘rubric’ of their work, i.e., to document their thoughts as they occur as well as their emotionsduring the process. These ‘rubrics’ were used as the main source of data.Students’ problem-solving processes can be explained as a three-stage process that has been called ‘solutioning’. This process is presented in the six sections below. The first three refer to a common area of concern that can be called‘generating knowledge’. In this way, generating knowledge also includes issues related to ‘key ideas’ and ‘gaining understanding’. The third and the fourth sections refer to ‘generating’ and ‘validating a solution’, respectively. Finally, once solutions are generated and validated, students usually try to improve them further before presenting them as final results. Thus, the last section deals with‘improving a solution’. Although not all students go through all of the stages, it may be said that ‘solutioning’ considers students’ main concerns as they tackle non-routine mathematical problems.

  17. The Use of Microwave Derived Activated Carbon for Removal of Heavy Metal in Aqueous Solution

    Directory of Open Access Journals (Sweden)

    Rafeah Wahi

    2011-09-01

    Full Text Available Palm oil processing waste which is palm oil kernel shell (POKS was converted to activated carbon (POKS AC through 7 min microwave pyrolysis at temperature 270 °C followed by chemical activation using NaOH and HCl. The adsorption study on Ni(II, Cu(II and Cr(IV was conducted to evaluate the efficiency of the prepared activated carbon to remove heavy metal. The adsorption capacity was determined as a function of adsorbate initial concentration and adsorbent dosage. Based on Langmuir isotherm, Ni(II showed highest adsorption capacity of 40.98 mg/g, followed by Cr(IV and Cu(II with adsorption capacity of 40.60 mg/g and 13.69 mg/g, respectively. Cr(IV and Cu(II showed better fitting to Freundlich isotherm model with high correlation regression indicating the applicability of heterogeneous adsorption. Ni(II show better fitting with Langmuir isotherm that indicate monolayer coverage. The use of POKS AC is not only effective for adsorption of Cr(IV, Ni(II and Cu(II in aqueous solution but also helps to overcome the over abundance of POKS waste problem.

  18. Removal of Congo Red and Methylene Blue from Aqueous Solutions by Vermicompost-Derived Biochars.

    Science.gov (United States)

    Yang, Gang; Wu, Lin; Xian, Qiming; Shen, Fei; Wu, Jun; Zhang, Yanzong

    2016-01-01

    Biochars, produced by pyrolyzing vermicompost at 300, 500, and 700°C were characterized and their ability to adsorb the dyes Congo red (CR) and Methylene blue (MB) in an aqueous solution was investigated. The physical and chemical properties of biochars varied significantly based on the pyrolysis temperatures. Analysis of the data revealed that the aromaticity, polarity, specific surface area, pH, and ash content of the biochars increased gradually with the increase in pyrolysis temperature, while the cation exchange capacity, and carbon, hydrogen, nitrogen and oxygen contents decreased. The adsorption kinetics of CR and MB were described by pseudo-second-order kinetic models. Both of Langmuir and Temkin model could be employed to describe the adsorption behaviors of CR and MB by these biochars. The biochars generated at higher pyrolysis temperature displayed higher CR adsorption capacities and lower MB adsorption capacities than those compared with the biochars generated at lower pyrolysis temperatures. The biochar generated at the higher pyrolytic temperature displayed the higher ability to adsorb CR owing to its promoted aromaticity, and the cation exchange is the key factor that positively affects adsorption of MB.

  19. Investigations of the inhibition of copper corrosion in nitric acid solutions by ketene dithioacetal derivatives

    Energy Technology Data Exchange (ETDEWEB)

    Fiala, A. [Laboratoire de chimie moleculaire du controle de l' environnement et des mesures physico-chimiques, faculte des sciences exactes, universite Mentouri-Constantine, route de Ain-El-Bey, Constantine (Algeria)], E-mail: abdelfiala@yahoo.fr; Chibani, A. [Laboratoire de chimie moleculaire du controle de l' environnement et des mesures physico-chimiques, faculte des sciences exactes, universite Mentouri-Constantine, route de Ain-El-Bey, Constantine (Algeria); Darchen, A. [Laboratoire d' electrochimie, ecole nationale superieure de chimie de Rennes, avenue du general-Leclerc, 35700 Rennes (France); Boulkamh, A.; Djebbar, K. [Laboratoire de chimie moleculaire du controle de l' environnement et des mesures physico-chimiques, faculte des sciences exactes, universite Mentouri-Constantine, route de Ain-El-Bey, Constantine (Algeria)

    2007-10-15

    Ketene dithioacetal derivatives, namely 3-[bis(methylthio)methylene] pentane-2,4-dione (1), 3-(1,3-dithian-2-ylidene) pentane-2,4-dione (2) and 3-(1,3-dithiolan-2-ylidene) pentane-2,4-dione (3) were synthesized and their respective capacity to inhibit copper corrosion in 3 M HNO{sub 3} was investigated by means of weight loss, potentiodynamic polarization, scanning electron microscopy (SEM) and energy dispersive X-ray fluorescence (XRF). The obtained results indicate that the addition of these compounds significantly decreases the corrosion rate. Potentiodynamic polarization studies clearly showed that the inhibition efficiency increases with increasing concentration of the investigated compounds at a fixed temperature, but decreases with increasing temperature. These results on the whole showed that the studied substances are good cathodic inhibitors for copper corrosion in nitric acid medium. SEM and energy dispersive X-ray (EDAX) examination of the copper surface revealed that these compounds prevented copper from corrosion by adsorption on its surface to form a protective film, which acts as a barrier to aggressive agents. The presence of these organic compounds adsorbed on the electrode surface was confirmed by XRF investigations.

  20. Protonation and Solvation Thermodynamics of Some Naphthol Derivatives in KCl Aqueous Solution of Different Ionic Strengths

    Directory of Open Access Journals (Sweden)

    Farid I. El-Dossoki

    2016-01-01

    Full Text Available The acid-base properties of naphthalen-1-ol (L1, naphthalene-1,5-diol (L2, and 4-amino-3-hydroxynaphthalene-1-sulphonic acid (L3 were characterized from pH-metric measurements in pure water and in different concentrations (0–4 mol kg−1 of aqueous KCl solutions at the temperature range of T = (293.15 to 213.15 K at 5 K intervals. The results reveal that naphthalen-1-ol and naphthalene-1,5-diol molecules have two ionisable protons (of the hydroxyl groups while 4-amino-3-hydroxynaphthalene-1-sulphonic acid has three ionisable protons (hydrogen ion of the hydroxyl group, SO3H, and NH3+. Modeling of the data was done by applying Debye-Hückel model. The protonation and the solvation processes of all studied ligands are spontaneous and endothermic processes. Also the solubilities of naphthalen-1-ol, naphthalene-1,5-diol, and 4-amino-3-hydroxynaphthalene-1-sulphonic acid were determined. The data were analyzed using Setschenow equation and the values of Setschenow coefficients (km were determined. From the solubility data, the activity coefficients were obtained. The values of the total solubilities (ST for naphthalen-1-ol and naphthalene-1,5-diol were found equal to the values of their neutral species (S0. On the other hand, the total solubility for 4-amino-3-hydroxynaphthalene-1-sulphonic acid is different from that of its neutral species. The results also indicate solubility decrease in pure water from L1-L2-L3.

  1. Acceleration of the effect of solute on the entropy-volume cross fluctuation density in aqueous 2-butoxyethanol, 1-propanol, and glycerol: The fourth derivative of Gibbs energy

    Science.gov (United States)

    Yoshida, Koh; Baluja, Shipra; Inaba, Akira; Koga, Yoshikata

    2011-06-01

    Using a differential pressure perturbation calorimetry developed by us recently [K. Yoshida, S. Baluja, A. Inaba, K. Tozaki, and Y. Koga, "Experimental determination of third derivative of G (III): Differential pressure perturbation calorimetry (II)," J. Solution Chem. (in press)], we experimentally determined the partial molar S-V cross fluctuation density of solute B, SVδB, in binary aqueous solutions for B = 1-propanol (1P) and glycerol (Gly). This third derivative of G provides information about the effect of solute B on the S-V cross fluctuation density, SVδ, in aqueous solution as the concentration of B varies. Having determined SVδB by better than 1% uncertainty, we evaluated for the first time the fourth derivative quantity SVδB-B = N(∂SVδB /∂nB) for B = 1P and Gly graphically without resorting to any fitting functions within several percent. This model-free quantity gives information about the acceleration of the effect of solute B on SVδ. By comparing fourth derivative quantities, SVδB-B, among B = 1P, Gly, and 2-butoxyethanol obtained previously, the distinction of the effect of solute on H2O becomes clearer than before when only the third derivative quantities were available.

  2. The Role of Liver in Determining Serum Colon-Derived Uremic Solutes.

    Directory of Open Access Journals (Sweden)

    Cheng-Jui Lin

    Full Text Available Evidence has shown that indoxyl sulfate (IS and p-cresyl sulfate (PCS may be alternative predictors of clinical outcomes in chronic kidney disease (CKD. Both toxins are derived from the gastrointestinal tract and metabolised in the liver. However, it is unclear whether the liver affects the production of IS and PCS. Here, we explore the association between IS and PCS levels in liver cirrhosis and a CKD-based cohort (N = 115. Liver and kidney function was assessed and classified by a Child-Pugh score (child A-C and a modified version of the Modification of Diet in Renal Disease (MDRD equation (Stages 1-4, respectively. An animal model was also used to confirm the two toxin levels in a case of liver fibrosis. In patients with early liver cirrhosis (child A, IS and PCS were significantly associated with CKD stages. In contrast, serum IS and PCS did not significantly change in advanced liver cirrhosis (child C. A stepwise multiple linear regression analysis also showed that T-PCS was significantly associated with stages of liver cirrhosis after adjusting for other confounding factors (B = -2.29, p = 0.012. Moreover, the serum and urine levels of T-PCS and T-IS were significantly lower in rats with liver failure than in those without (p<0.01, p<0.05 and p<0.01, p<0.05, respectively. These results indicated that in addition to the kidneys, the liver was an essential and independent organ in determining serum IS and PCS levels. The production rate of IS and PCS was lower in patients with advanced liver cirrhosis.

  3. Highly Selective Derivative Spectrophotometry for Determination of Nickel Using 1-(2-Pyridylazo)-2-naphthol in Tween 80 Micellar Solutions

    Energy Technology Data Exchange (ETDEWEB)

    Eskandari, Habibollah [University of Mohaghegh Ardebili, Ardebil (Iran, Islamic Republic of)

    2004-08-15

    A spectrophotometric and first derivative spectrophotometric method was developed in aquatic Tween 80 micellar solutions for selective determination of nickel without using any pre-separation step. 1-(2-Pyridylazo)- 2-naphthol (PAN), as a sensitive chromogenic complexing agent formed a red-colored Ni(II)-PAN complex in Tween 80 media with satisfactory solubility and stability. Conditions such as pH, PAN concentration, type and concentration of micellizing agent were optimized. Molar absorptivity of Ni-PAN complex was found 4.62 x 10{sup 4} L cm{sup -1} mol{sup -1} at 569 nm, under the optimum condition. Calibration graphs were derived by zero, first and second derivative spectrophotometry at maximum wavelengths of 569, 578 and 571 nm with linear ranges of 30-1800, 20-2500 and 30-2000 ng mL{sup -1}, respectively. Precision as standard deviation as well as accuracy as recovery percent were in the range of 1-20 ng mL{sup -1} and 93.3-103.3%, respectively, for the entire of the linear ranges. Spectrophotometric detection limit was 3 ng mL{sup -1} and effects of diverse ions on the first derivative determination of nickel were studied to investigate selectivity of the method. Interferences of cobalt and copper on the nickel determination were prevented using o-phenanthroline as masking agent. The recommended procedures were applied to the various synthetic and stainless steel alloys, tea leaves and human hair, with satisfactory results.

  4. Potential mechanisms of cadmium removal from aqueous solution by Canna indica derived biochar

    Energy Technology Data Exchange (ETDEWEB)

    Cui, Xiaoqiang; Fang, Siyu; Yao, Yiqiang; Li, Tingqiang [Ministry of Education Key Laboratory of Environmental Remediation and Ecological Health, College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310058 (China); Ni, Qijun [The 702 Research Institute of China Shipbuilding Industry Corporation, Wuxi 214082 (China); Yang, Xiaoe, E-mail: xyang@zju.edu.cn [Ministry of Education Key Laboratory of Environmental Remediation and Ecological Health, College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310058 (China); He, Zhenli [Indian River Research and Education Center, Institute of Food and Agricultural Sciences, University of Florida, Fort Pierce, FL 34951 (United States)

    2016-08-15

    The objective of this study was to investigate the mechanisms of cadmium (Cd) sorption on biochars produced at different temperature (300–600 °C) and their quantitative contribution. The sorption isotherms and kinetics of Cd{sup 2+} sorption on biochars were determined and fitted to different models. The Cd{sup 2+} sorption data could be well described by a simple Langmuir model, and the pseudo second order kinetic model best fitted the kinetic data. The maximum sorption capacity (Q{sub m}) obtained from the Langmuir model for CIB500 was 188.8 mg g{sup −1}, which was greater than that of biochars produced at other temperature. Precipitation with minerals, ion exchange, complexation with surface oxygen-containing functional groups, and coordination with π electrons were the possible mechanisms of Cd{sup 2+} sorption on the biochars. The contribution of each mechanism varied with the pyrolysis temperature. With increasing pyrolysis temperature, the contribution of surface complexation and metal ion exchange decreased from 24.5% and 43.3% to 0.7% and 4.7%, while the contribution of precipitation and Cd{sup 2+}-π interaction significantly increased from 29.7% and 2.5% to 89.5% and 5.1%, respectively. Overall, the precipitation with minerals and metal ion exchange dominated Cd{sup 2+} sorption on the biochars (accounted for 73.0–94.1%), and precipitation with minerals was the primary mechanism of Cd{sup 2+} sorption on the high-temperature biochars (≥ 500 °C) (accounted for 86.1–89.5%). - Highlights: • Sorption capacity of metal on biochars is affected by pyrolysis temperature. • Biochar derived from Canna indica at 500 °C has a high sorption capacity for Cd{sup 2+}. • Cd{sup 2+} sorption on the biochars fits a pseudo second order and Langmuir model. • Precipitation and ion exchange mechanisms dominated Cd{sup 2+} sorption on the biochars.

  5. Corrosion Inhibition Performance of Triazole Derivatives on Copper-Nickel Alloy in 3.5 wt.% NaCl Solution

    Science.gov (United States)

    Jiang, B.; Jiang, S. L.; Liu, X.; Ma, A. L.; Zheng, Y. G.

    2015-12-01

    This study investigates the performance of three triazole derivatives with different molecular structures as corrosion inhibitors for the copper-nickel alloy CuNi 90/10 in 3.5 wt.% NaCl solution. Inhibition behavior was systematically determined through electrochemical measurements, scanning electron microscopy, energy-dispersive spectroscopy, and Fourier transform infrared spectroscopy. In addition, adsorption behavior and the inhibition mechanism were investigated via quantum chemical calculation and molecular dynamic simulation. Experimental results indicate that the three inhibitors with triazole rings and heteroatoms exhibited excellent corrosion inhibition capabilities on the copper-nickel alloy surface through physisorption and chemisorption. In particular, 3-amino-5-mercapto-1,2,4-triazole showed the best inhibition capability according to the concentration ranges considered in the experiments. The results of quantum chemical calculation agreed with the experimental findings.

  6. Excited state intramolecular proton transfer and charge transfer dynamics of a 2-(2'-hydroxyphenyl)benzoxazole derivative in solution.

    Science.gov (United States)

    Kim, Chul Hoon; Park, Jaehun; Seo, Jangwon; Park, Soo Young; Joo, Taiha

    2010-05-13

    Excited state intramolecular proton transfer (ESIPT) and subsequent intramolecular charge transfer (ICT) dynamics of a 2-(2'-hydroxyphenyl)benzoxazole derivative conjugated with an electron withdrawing group (HBOCE) in solutions and a polymer film has been investigated by femtosecond time-resolved fluorescence (TRF) and TRF spectra measurements without the conventional spectral reconstruction method. TRF with high enough resolution (benzoxazole groups is invoked to account for the dispersive ESIPT dynamics in liquids. From the TRF spectra of both the enol and keto isomers, we have identified the ICT reaction of the keto isomer occurring subsequent to the ESIPT. The ICT proceeds also by two time constants of near instantaneous and 2.7 ps. Since the ICT dynamics of HBOCE is rather close to the polar solvation dynamics, we argue that the ICT is barrierless and determined mostly by the solvent fluctuation.

  7. The Synthesis of Imidazoline Derivative Compounds as Corrosion Inhibitor towards Carbon Steel in 1% NaCl Solution

    Directory of Open Access Journals (Sweden)

    Deana Wahyuningrum

    2008-03-01

    Full Text Available Oleic imidazoline is one of the nitrogen containing heterocyclic compounds that has been widely used as commercial corrosion inhibitor, especially in minimizing the carbon dioxide induced corrosion process in oilfield mining. In this present work, some imidazoline derivative compounds have been synthesized utilizing both conventional and microwave assisted organic synthesis (MAOS methods, in order to determine their corrosion inhibition properties on carbon steel surface. The MAOS method is more effective in synthesizing these compounds than the conventional method regarding to the higher chemical yields of products (91% to 94% and the shorter reaction times (7 to 10 minutes. The characterization of corrosion inhibition activities of the synthesized products towards carbon steel in 1% NaCl solution was determined by the Tafel plot method. The corrosion inhibition activities of compound 1b ((Z-2-(2-(heptadec-8-enyl-4,5-dihydroimidazol-1-ylethanamine, 2b ((Z-2-(2-(heptadec-8-enyl-4,5-dihydroimidazol-1-ylethanol and 3b (2-(2-heptadecyl-4,5-dihydroimidazol-1-ylethanamine at 8 ppm concentration in 1% NaCl solution are, respectively, 32.18%, 39.59% and 12.73%. The heptadec-8-enyl and hydroxyethyl substituents at C(2 and N(1 position of imidazoline ring, respectively, gave the most effective corrosion inhibition activity towards carbon steel compared to the presence of other substituents. The increase in concentrations of compound 1b, 2b and 3b in 1% NaCl solution tends to improve their corrosion inhibition activities. Based on the analysis of the free Gibbs adsorption energy (DG0ads values of compound 1b, 2b and 3b (-32.97, -34.34 and -31.27 kJ/mol, respectively, these compounds have the potential to interact with carbon steel through semi-physiosorption or semi-chemisorption.

  8. Competitive removal of hazardous dyes from aqueous solution by MIL-68(Al): Derivative spectrophotometric method and response surface methodology approach

    Science.gov (United States)

    Tehrani, Mahnaz Saghanejhad; Zare-Dorabei, Rouholah

    2016-05-01

    MIL-68(Al) as a metal-organic framework (MOF) was synthesized and characterized by different techniques such as SEM, BET, FTIR, and XRD analysis. This material was then applied for simulations removal of malachite green (MG) and methylene blue (MB) dyes from aqueous solutions using second order derivative spectrophotometric method (SODS) which was applied to resolve the overlap between the spectra of these dyes. The dependency of dyes removal efficiency in binary solutions was examined and optimized toward various parameters including initial dye concentration, pH of the solution, adsorbent dosage and ultrasonic contact time using central composite design (CCD) under response surface methodology (RSM) approach. The optimized experimental conditions were set as pH 7.78, contact time 5 min, initial MB concentration 22 mg L- 1, initial MG concentration 12 mg L- 1 and adsorbent dosage 0.0055 g. The equilibrium data was fitted to isotherm models such as Langmuir, Freundlich and Tempkin and the results revealed the suitability of the Langmuir model. The maximum adsorption capacity of 666.67 and 153.85 mg g- 1 was obtained for MB and MG removal respectively. Kinetics data fitting to pseudo-first order, pseudo-second order and Elovich models confirmed the applicability of pseudo-second order kinetic model for description of the mechanism and adsorption rate. Dye-loaded MIL-68(Al) can be easily regenerated using methanol and applied for three frequent sorption/desorption cycles with high performance. The impact of ionic strength on removal percentage of both dyes in binary mixture was studied by using NaCl and KCl soluble salts at different concentrations. According to our findings, only small dosage of the proposed MOF is considerably capable to remove large amounts of dyes at room temperature and in very short time that is a big advantage of MIL-68(Al) as a promising adsorbent for adsorptive removal processes.

  9. NMR solution structure of the peptide fragment 1-30, derived from unprocessed mouse Doppel protein, in DHPC micelles.

    Science.gov (United States)

    Papadopoulos, Evangelos; Oglecka, Kamila; Mäler, Lena; Jarvet, Jüri; Wright, Peter E; Dyson, H Jane; Gräslund, Astrid

    2006-01-10

    The downstream prion-like Doppel (Dpl) protein is a homologue related to the prion protein (PrP). Dpl is expressed in the brains of mice that do not express PrP, and Dpl is known to be toxic to neurons. One mode of toxicity has been suggested to involve direct membrane interactions. PrP under certain conditions of cell trafficking retains an uncleaved signal peptide, which may also hold for the much less studied Dpl. For a peptide with a sequence derived from the N-terminal part (1-30) of mouse Dpl (mDpl(1-30)) CD spectroscopy shows about 40% alpha-helical structure in DHPC and SDS micelles. In aqueous solution it is mostly a random coil. The three-dimensional solution structure was determined by NMR for mDpl(1-30) associated with DHPC micelles. 2D 1H NMR spectra of the peptide in q = 0.25 DMPC/DHPC bicelles only showed signals from the unstructured termini, indicating that the structured part of the peptide resides within the lipid bilayer. Together with 2H2O exchange data in the DHPC micelle solvent, these results show an alpha-helix protected from solvent exchange between residues 7 and 19, and suggest that the alpha-helical segment can adopt a transmembrane localization also in a membrane. Leakage studies with entrapped calcein in large unilamellar phospholipid vesicles showed that the peptide is almost as membrane perturbing as melittin, known to form pores in membranes. The results suggest a possible channel formation mechanism for the unprocessed Dpl protein, which may be related to toxicity through direct cell membrane interaction and damage.

  10. Some aromatic hydrazone derivatives as inhibitors for the corrosion of C-steel in phosphoric acid solution.

    Science.gov (United States)

    Fouda, Abd El-Aziz S; Al-Sarawy, Ahmed A; Radwan, Mohamed S

    2006-01-01

    The effect of furfural benzoylhydrazone and its derivatives (I-VII) as corrosion inhibitors for C-steel in 1M phosphoric acid solution has been studied by weight-loss and galvanostatic polarization techniques. A significant decrease in the corrosion rate of C-steel was observed in the presence of the investigated inhibitors. This study revealed that, the inhibition efficiency increases with increasing the inhibitor concentration, and the addition of iodide ions enhances it to a considerable extent. The effect of temperature on the inhibition efficiency of these compounds was studied using weight-loss method. Activation energy (E(a)*) and other thermodynamic parameters for the corrosion process were calculated and discussed. The galvanostatic polarization data indicated that, the inhibitors were of mixed-type, but the cathode is more polarized than the anode. The adsorption of these compounds on C-steel surface has been found to obey Frumkin's adsorption isotherm. The mechanism of inhibition was discussed in the light of the chemical structure of the undertaken inhibitors.

  11. Reactivity of some S-bridge containing diphenyl derivatives (sulfides, sulfoxides, sulfones) towards ortho-positronium atoms in dimethylsulfoxide solution

    Energy Technology Data Exchange (ETDEWEB)

    Levay, Bela [Department of Nuclear Chemistry, Eoetvoes Lorand University, Budapest (Hungary)], E-mail: levay@para.chem.elte.hu; Szabo, Denes [Department of Organic Chemistry, Eoetvoes Lorand University, Budapest (Hungary)

    2006-08-01

    The effect of changes in the chemical structure of organic sulfur compounds on their reactivity towards an ortho-positronium (o-Ps) atom was investigated by positron annihilation lifetime spectroscopy in dimethylsulfoxide solutions. S-bridge containing molecules with very similar structural frameworks were selected as model systems, such as, diphenyl sulfide, sulfoxide and sulfone, and their derivatives. The effect of the type of the S-bridge on the reactivity increased in the order of S < SO < SO{sub 2} in all groups of the compounds with similar substituents on their phenyl groups. The same trend was observed for the calculated excess positive charge on the sulfur atoms and the LUMO energies of the molecules too. As it was expected, electron-withdrawing substituents on the aromatic rings increased both the reactivity and the negative values of the LUMO energy of the molecules (COOH < NO{sub 2}) whereas those with electron-donating character (CH{sub 3}O) showed the opposite effect.

  12. sym-Trisubstituted 1,3,5-Triazine Derivatives as Promising Organic Corrosion Inhibitors for Steel in Acidic Solution.

    Science.gov (United States)

    El-Faham, Ayman; Dahlous, Kholood A; Al Othman, Zeid A; Al-Lohedan, Hamad A; El-Mahdy, Gamal A

    2016-03-31

    Triazine derivatives, namely, 2,4,6-tris(quinolin-8-yloxy)-1,3,5-triazine (T3Q), N²,N⁴,N⁶-tris(pyridin-2-ylmethyl)-1,3,5-triazine-2,4,6-triamine (T3AMPy) and 2,2',2''-[(1,3,5-triazine-2,4,6-triyl)tris(azanediyl)] tris(ethan-1-ol) (T3EA) were synthesized and their inhibition of steel corrosion in hydrochloric acid solution was investigated using electrochemical techniques. The corrosion protection of the prepared compounds increased with increasing concentration and reached up to 98% at 250 ppm. The adsorption of T3Q, T3AMPy, and T3EA on the steel surface was in accordance with the Langmuir adsorption isotherm. The electrochemical results revealed that T3Q, T3AMPy and T3EA act as excellent organic inhibitors and can labeled as mixed type inhibitors. The efficiencies of the tested compounds were affected by the nature of the side chain present in the triazine ring, where T3EA gave the least inhibition while T3Q and T3AMPy gave higher and almost the same inhibition effects. The inhibition efficiencies obtained from the different electrochemical techniques were in good agreement.

  13. Azobenzene-derived tris-β-diketonate lanthanide complexes: reversible trans-to-cis photoisomerization in solution and solid state.

    Science.gov (United States)

    Lin, Li-Rong; Wang, Xuan; Wei, Gao-Ning; Tang, Hui-Hui; Zhang, Hui; Ma, Li-Hua

    2016-10-14

    Novel azobenzene-derived β-diketonates (4,4,5,5,6,6,6-heptafluoro-1-azobenzene-1,3-hexanedione (LA), 4,4,5,5,6,6,6-heptafluoro-1-(4-dimethylamino)azobenzene-1,3-hexanedione (LB)) were designed and their complexes with lanthanide cations (La(3+), Eu(3+), Gd(3+), Yb(3+)) were prepared and characterized by (1)H NMR, FT-IR, and elemental analysis. Three of the complexes were crystallized successfully and identified by X-ray diffraction. It was significant to find that LA showed remarkably reversible trans-to-cis isomerization properties, however, LB, bearing an electron donor compared with LA, slowed down the isomerization to an extent. The presence of Ln(iii) enhanced the reversible trans-to-cis isomerization properties of both LA and LB a little upon photoirradiation in organic solvents, and amazingly increased the fatigue resistance. In addition, the complexes doped in polymethyl methacrylate (PMMA) films produced a similar phenomenon as well as when in solution. Theoretical calculations based on time dependent density functional theory (TD-DFT) were performed for geometry optimization and to determine the excitation energies of LA and LB to gain further insight into the electronic structure of the complexes, and the data were consistent with the experimental results. The excellent reversible photoisomerization properties of the newly designed Ln(iii) complexes can offer important advantages that will help with the further study of these materials to reach their full potential in applications such as molecular switching devices.

  14. Synthesis and characterization of a J-aggregating TDBC derivative in solution and in Langmuir–Blodgett films

    Energy Technology Data Exchange (ETDEWEB)

    Aviv, Hagit [Department of Chemistry, Bar-Ilan University (Israel); Institute for Nanotechnology and Advanced Materials, Bar-Ilan University (Israel); Tischler, Yaakov R., E-mail: yrt@biu.ac.il [Department of Chemistry, Bar-Ilan University (Israel); Institute for Nanotechnology and Advanced Materials, Bar-Ilan University (Israel)

    2015-02-15

    Here we present the synthesis and optical characterization of a new amphiphilic cyanine dye, 1,1′-dioctadecane-3,3′-di(4-sulfobutyl)-5,5′,6,6′-tetrachloro -benzimidazolocarbo-cyanine (C18S4). C18S4 is a derivative of the heavily studied J-aggregating cyanine dye TDBC that was designed specifically for creating stable amphiphilic monolayers when spread at an air–water interface. Unlike TDBC, which readily J-aggregates in water, we show that C18S4 introduced into water tends to produce micelles with monomeric spectral properties and only exhibits strong J-aggregation after an emulsification procedure and a week of dye reorganization. When deposited on a Langmuir Blodgett (LB) trough, C18S4 forms a stable monolayer with a repeatable isotherm. Layers transferred via LB deposition to a functionalized glass substrate show pronounced J-aggregation, depending on the surface transfer pressure. Layers transferred at 35 mN/m present an intense narrow absorption spectrum peaked at λ=589 nm with FWHM=523 cm{sup −1} (18 nm). The accompanying fluorescence shows a narrow spectrum with FWHM=332 cm{sup −1} (11.5 nm) and a Stokes shift less than 1 nm. The ability to create J-aggregates of C18S4 via LB deposition provides control over the J-aggregation process of TDBC-like molecules and can ultimately lead to tuning the J-aggregate coupling for specific experiments and applications. - Highlights: • C18S4 is an amphiphilic J-aggregating cyanine dye. • C18S4 J-aggregates in aqueous solution. • C18S4 forms a stable isotherm when spread at the air–water interface. • C18S4 J-aggregates at an air–water interface upon compression. • Langmuir–Blodgett J-aggregated films have narrow absorption and emission spectra.

  15. Properties of cationic monosubstituted tetraalkylammonium cyclodextrin derivatives – their stability, complexation ability in solution or when deposited on solid anionic surface

    Directory of Open Access Journals (Sweden)

    Martin Popr

    2015-02-01

    Full Text Available The thermal stability of the monosubstituted cationic cyclodextrin (CD derivatives PEMEDA-β-CD and PEMPDA-β-CD, which differ in their substituent linker length (ethylene and propylene, respectively, was studied via 1H NMR experiments. PEMPDA-β-CD exhibited higher resistance towards the Hofmann degradation and was chosen as a more suitable host molecule for further studies. Inclusion properties of PEMPDA-β-CD in solution with a series of simple aromatic guests (salicylic acid, p-methoxyphenol and p-nitroaniline were determined by isothermal titration calorimetry (ITC and compared to the native β-CD. Permanently charged cationic CD derivatives were successfully deposited on the anionic solid surface of polymeric Nafion® 117 membrane via electrostatic interactions. Deposition kinetics and coverage of the surface were determined by ELSD. Finally, the ability of the CD derivatives bound to the solid surface to encapsulate aromatic compounds from aqueous solution was measured by UV–vis spectroscopy. The obtained results are promising for future industrial applications of the monosubstituted β-CD derivatives, because the preparation of cationic CD derivatives is applicable in large scale, without the need of chromatographic purification. Their ionic deposition on a solid surface is simple, yet robust and a straightforward process as well.

  16. Properties of cationic monosubstituted tetraalkylammonium cyclodextrin derivatives – their stability, complexation ability in solution or when deposited on solid anionic surface

    OpenAIRE

    Martin Popr; Filippov, Sergey K; Nikolai Matushkin; Juraj Dian; Jindřich Jindřich

    2015-01-01

    The thermal stability of the monosubstituted cationic cyclodextrin (CD) derivatives PEMEDA-β-CD and PEMPDA-β-CD, which differ in their substituent linker length (ethylene and propylene, respectively), was studied via 1H NMR experiments. PEMPDA-β-CD exhibited higher resistance towards the Hofmann degradation and was chosen as a more suitable host molecule for further studies. Inclusion properties of PEMPDA-β-CD in solution with a series of simple aromatic guests (salicylic acid, p-methoxypheno...

  17. An efficient one-pot three-component synthesis of tetrahydrobenzo[b]pyran and 3,4-dihydropyrano[c]chromene derivatives using starch solution as catalyst

    Institute of Scientific and Technical Information of China (English)

    Nourallah Hazeri; Malek Taher Maghsoodlou; Fatemeh Mir; Mehrnoosh Kangani; Hamideh Saravani; Ebrahim Molashahi

    2014-01-01

    Tetrahydrobenzo[b]pyran and 3,4-dihydropyrano[c]chromene derivatives were synthesized via a one-pot three-component condensation of aromatic aldehydes with malononitrile and dimedone or 4-hydroxycoumarin in excellent yields in the presence of starch solution as a highly efficient ho-mogenous catalyst. The use of a nontoxic and biodegradable catalyst, simple work-up procedure, and short reaction time are advantages of this method.

  18. Exhaustive derivation of static self-consistent multi-soliton solutions in the matrix Bogoliubov-de Gennes systems

    CERN Document Server

    Takahashi, Daisuke A

    2015-01-01

    The matrix-generalized Bogoliubov-de Gennes systems are recently considered by the present author [arXiv:1509.04242], and the time-dependent and self-consistent multi-soliton solutions are constructed based on the ansatz method. In this paper, restricting the problem to the static case, we exhaustively determine the self-consistent solutions using the inverse scattering theory. Solving the gap equation, we rigorously prove that the self-consistent potential must be reflectionless. As a supplementary topic, we elucidate the relation between the stationary self-consistent potentials and the soliton solutions in the matrix nonlinear Schr\\"odinger equation. The asymptotic formulae of multi-soliton solutions for sufficiently isolated solitons are also presented.

  19. Control of the intermolecular photodimerization of anthracene derivatives by hydrogen bonding of urea groups in dilute solution.

    Science.gov (United States)

    Matsumoto, Hisato; Nishimura, Yoshinobu; Arai, Tatsuo

    2016-08-04

    The photodimerization reaction of anthracene derivatives was performed by capitalizing on intermolecular hydrogen bonds. Anthracene derivatives that can control the dimerization reaction depending on the substitution site were designed by using two anthryl moieties and one urea group, referred to as N,N'-dianthracen-n-ylurea, nDAU (n = 1, 2 and 9), which are symmetrically substituted by 1-anthryl, 2-anthryl and 9-anthryl groups, respectively. We investigated the excimer emission and photodimerization reaction of these anthracene-urea derivatives using absorption, emission, and (1)H NMR spectroscopy along with fluorescence decay measurements. All derivatives showed a concentration dependence of their fluorescence spectra and multiple fluorescence lifetime components even at 10(-6) M. Significantly, 9DAU resulted in an intermolecular photodimerization reaction. These differences in photoreactivity of nDAU may depend on variations in the overlap of the intermolecularly associated anthracene rings of nDAU by hydrogen bonding between intermolecular urea moieties. Furthermore, the dimerization quantum yield of 9DAU was reduced by the addition of tetrabutylammonium acetate (TBAAc). Consequently, we revealed that the substitution site and the addition of TBAAc affected the dimerization reaction of anthracene-urea derivatives.

  20. Temperature field due to time-dependent heat sources in a large rectangular grid - Derivation of analytical solution

    Energy Technology Data Exchange (ETDEWEB)

    Claesson, J.; Probert, T. [Lund Univ. (Sweden). Dept. of Building Physics and Mathematical Physics

    1996-01-01

    The temperature field in rock due to a large rectangular grid of heat releasing canisters containing nuclear waste is studied. The solution is by superposition divided into different parts. There is a global temperature field due to the large rectangular canister area, while a local field accounts for the remaining heat source problem. The global field is reduced to a single integral. The local field is also solved analytically using solutions for a finite line heat source and for an infinite grid of point sources. The local solution is reduced to three parts, each of which depends on two spatial coordinates only. The temperatures at the envelope of a canister are given by a single thermal resistance, which is given by an explicit formula. The results are illustrated by a few numerical examples dealing with the KBS-3 concept for storage of nuclear waste. 8 refs.

  1. Deriving the properties of space time using the non-compressible solutions of the Navier-Stokes Equations

    CERN Document Server

    McDuffee, Ryan

    2016-01-01

    Recent observations of gravitational waves by the Laser Interferometer Gravitational-Wave Observatory (LIGO) has confirmed one of the last outstanding predictions in general relativity and in the process opened up a new frontier in astronomy and astrophysics. Additionally the observation of gravitational waves has also given us the data needed to deduce the physical properties of space time. Bredberg et al have shown in their 2011 paper titled From Navier-Stokes to Einstein, that for every solution of the incompressible Navier-Stokes equation in p + 1 dimensions, there is a uniquely associated dual" solution of the vacuum Einstein equations in p + 2 dimensions. The author shows that the physical properties of space time can be deduced using the recent measurements from the Laser Interferometer Gravitational-Wave Observatory and solutions from the incompressible Navier-Stokes equation.

  2. Exact solutions for the flow of non-Newtonian fluid with fractional derivative in an annular pipe

    Institute of Scientific and Technical Information of China (English)

    TONG Dengke; WANG Ruihe; YANG Heshan

    2005-01-01

    This paper deals with some unsteady unidirectional transient flows of Oldroyd-B fluid in an annular pipe. The fractional calculus approach in the constitutive relationship model Oldroyd-B fluid is introduced and a generalized Jeffreys model with the fractional calculus has been built. Exact solutions of some unsteady flows of Oldroyd-B fluid in an annular pipe are obtained by using Hankel transform and Laplace transform for fractional calculus. The following four problems have been studied: (1) Poiseuille flow due to a constant pressure gradient; (2) axial Couette flow in an annulus; (3) axial Couette flow in an annulus due to a longitudinal constant shear; (4) Poiseuille flow due to a constant pressure gradient and a longitudinal constant shear. The well-known solutions for Navier-Stokes fluid, as well as those corresponding to a Maxwell fluid and a second grade one, appear as limited cases of our solutions.

  3. Exact solutions for the flow of non-Newtonian fluid with fractional derivative in an annular pipe

    Science.gov (United States)

    Tong, Dengke; Wang, Ruihe; Yang, Heshan

    2005-08-01

    This paper deals with some unsteady unidirectional transient flows of Oldroyd-B fluid in an annular pipe. The fractional calculus approach in the constitutive relationship model Oldroyd-B fluid is introduced and a generalized Jeffreys model with the fractional calculus has been built. Exact solutions of some unsteady flows of Oldroyd-B fluid in an annular pipe are obtained by using Hankel transform and Laplace transform for fractional calculus. The following four problems have been studied: (1) Poiseuille flow due to a constant pressure gradient; (2) axial Couette flow in an annulus; (3) axial Couette flow in an annulus due to a longitudinal constant shear; (4) Poiseuille flow due to a constant pressure gradient and a longitudinal constant shear. The well-known solutions for Navier-Stokes fluid, as well as those corresponding to a Maxwell fluid and a second grade one, appear as limited cases of our solutions.

  4. Numerical solution of fractional-in-space nonlinear Schrödinger equation with the Riesz fractional derivative

    Science.gov (United States)

    Owolabi, Kolade M.; Atangana, Abdon

    2016-09-01

    In this paper, dynamics of time-dependent fractional-in-space nonlinear Schrödinger equation with harmonic potential V(x),x in R in one, two and three dimensions have been considered. We approximate the Riesz fractional derivative with the Fourier pseudo-spectral method and advance the resulting equation in time with both Strang splitting and exponential time-differencing methods. The Riesz derivative introduced in this paper is found to be so convenient to be applied in models that are connected with applied science, physics, and engineering. We must also report that the Riesz derivative introduced in this work will serve as a complementary operator to the commonly used Caputo or Riemann-Liouville derivatives in the higher-dimensional case. In the numerical experiments, one expects the travelling wave to evolve from such an initial function on an infinite computational domain (-∞, ∞) , which we truncate at some large, but finite values L. It is important that the value of L is chosen large enough to give enough room for the wave function to propagate. We observe a different distribution of complex wave functions for the focusing and defocusing cases.

  5. The comparative photodegradation activities of pentachlorophenol (PCP) and polychlorinated biphenyls (PCBs) using UV alone and TiO2-derived photocatalysts in methanol soil washing solution.

    Science.gov (United States)

    Zhou, Zeyu; Zhang, Yaxin; Wang, Hongtao; Chen, Tan; Lu, Wenjing

    2014-01-01

    Photochemical treatment is increasingly being applied to remedy environmental problems. TiO2-derived catalysts are efficiently and widely used in photodegradation applications. The efficiency of various photochemical treatments, namely, the use of UV irradiation without catalyst or with TiO2/graphene-TiO2 photodegradation methods was determined by comparing the photodegadation of two main types of hydrophobic chlorinated aromatic pollutants, namely, pentachlorophenol (PCP) and polychlorinated biphenyls (PCBs). Results show that photodegradation in methanol solution under pure UV irradiation was more efficient than that with either one of the catalysts tested, contrary to previous results in which photodegradation rates were enhanced using TiO2-derived catalysts. The effects of various factors, such as UV light illumination, addition of methanol to the solution, catalyst dosage, and the pH of the reaction mixture, were examined. The degradation pathway was deduced. The photochemical treatment in methanol soil washing solution did not benefit from the use of the catalysts tested. Pure UV irradiation was sufficient for the dechlorination and degradation of the PCP and PCBs.

  6. The comparative photodegradation activities of pentachlorophenol (PCP and polychlorinated biphenyls (PCBs using UV alone and TiO2-derived photocatalysts in methanol soil washing solution.

    Directory of Open Access Journals (Sweden)

    Zeyu Zhou

    Full Text Available Photochemical treatment is increasingly being applied to remedy environmental problems. TiO2-derived catalysts are efficiently and widely used in photodegradation applications. The efficiency of various photochemical treatments, namely, the use of UV irradiation without catalyst or with TiO2/graphene-TiO2 photodegradation methods was determined by comparing the photodegadation of two main types of hydrophobic chlorinated aromatic pollutants, namely, pentachlorophenol (PCP and polychlorinated biphenyls (PCBs. Results show that photodegradation in methanol solution under pure UV irradiation was more efficient than that with either one of the catalysts tested, contrary to previous results in which photodegradation rates were enhanced using TiO2-derived catalysts. The effects of various factors, such as UV light illumination, addition of methanol to the solution, catalyst dosage, and the pH of the reaction mixture, were examined. The degradation pathway was deduced. The photochemical treatment in methanol soil washing solution did not benefit from the use of the catalysts tested. Pure UV irradiation was sufficient for the dechlorination and degradation of the PCP and PCBs.

  7. Structural and functional characterization of solute binding proteins for aromatic compounds derived from lignin: p-coumaric acid and related aromatic acids.

    Science.gov (United States)

    Tan, Kemin; Chang, Changsoo; Cuff, Marianne; Osipiuk, Jerzy; Landorf, Elizabeth; Mack, Jamey C; Zerbs, Sarah; Joachimiak, Andrzej; Collart, Frank R

    2013-10-01

    Lignin comprises 15-25% of plant biomass and represents a major environmental carbon source for utilization by soil microorganisms. Access to this energy resource requires the action of fungal and bacterial enzymes to break down the lignin polymer into a complex assortment of aromatic compounds that can be transported into the cells. To improve our understanding of the utilization of lignin by microorganisms, we characterized the molecular properties of solute binding proteins of ATP-binding cassette transporter proteins that interact with these compounds. A combination of functional screens and structural studies characterized the binding specificity of the solute binding proteins for aromatic compounds derived from lignin such as p-coumarate, 3-phenylpropionic acid and compounds with more complex ring substitutions. A ligand screen based on thermal stabilization identified several binding protein clusters that exhibit preferences based on the size or number of aromatic ring substituents. Multiple X-ray crystal structures of protein-ligand complexes for these clusters identified the molecular basis of the binding specificity for the lignin-derived aromatic compounds. The screens and structural data provide new functional assignments for these solute-binding proteins which can be used to infer their transport specificity. This knowledge of the functional roles and molecular binding specificity of these proteins will support the identification of the specific enzymes and regulatory proteins of peripheral pathways that funnel these compounds to central metabolic pathways and will improve the predictive power of sequence-based functional annotation methods for this family of proteins.

  8. Experimental data of biomaterial derived from Malva sylvestris and charcoal tablet powder for Hg2+ removal from aqueous solutions

    Directory of Open Access Journals (Sweden)

    Alireza Rahbar

    2016-09-01

    Full Text Available In this experimental data article, a novel biomaterial was provided from Malva sylvestris and characterized its properties using various instrumental techniques. The operating parameters consisted of pH and adsorbent dose on Hg2+ adsorption from aqueous solution using M. sylvestris powder (MSP were compared with charcoal tablet powder (CTP, a medicinal drug. The data acquired showed that M. sylvestris is a viable and very promising alternative adsorbent for Hg2+ removal from aqueous solutions. The experimental data suggest that the MSP is a potential adsorbent to use in medicine for treatment of poisoning with heavy metals; however, the application in animal models is a necessary step before the eventual application of MSP in situations involving humans.

  9. The performance studies on swallow-tailed naphthalene diimide derivatives in solution processed inverted bulk heterojunction solar cells

    Science.gov (United States)

    Turkmen, Gulsah; Sarica, Hizir; Erten-Ela, Sule

    2014-10-01

    Two different soluble swallow-tailed naphthalene diimide derivatives were synthesized, 1,4:5,8-naphthalene diimides (NDIs), N,N‧-bis-(1-butylpentyl)-naphthalenetetracarboxylic-1,4:5,8-biscarboximide (NDI-1) and N,N‧-bis-(1-pentylhexyl)-naphthalenetetracarboxylic-1,4:5,8-biscarboximide (NDI-2). Thermal stabilities were also measured with thermal gravimetry analyser (TGA). Naphthalene diimides showed high thermal stability. NDI derivatives exhibited good thermal stabilities that thermal decomposition peak appeared at 438 °C and 421 °C, respectively for NDI-1 and NDI-2. Highly soluble naphthalene diimide derivatives were used in inverted bulk heterojunction solar cells. Two different ZnO cathode layers were used to fabricate bulk heterojunction solar cells. One of them was single layer consists of dense ZnO layer and the other was double layer comprising porous ZnO layer onto dense ZnO layer. Inverted bulk heterojunction devices were designed in a FTO/ ZnO (single or double layer)/P3HT:C60:NDI device geometry. Best efficiency was obtained for FTO/ZnO (single or double layer)/P3HT:C60:NDI-2 device as 8.78 mA/cm2 of short circuit photocurrent density, 300 mV of open circuit voltage, 0.28 of filling factor, 0.74 of overall conversion efficiency.

  10. Enhanced corrosion resistance of mild steel in hydrochloric acid solution by new thiadiazole derivatives: Electrochemical, theoretical and XPS studies

    Energy Technology Data Exchange (ETDEWEB)

    Bentiss, Fouad; Lebrini, Mounim; Lagrenee, Michel [Laboratoire de Cristallochimie et Physicochimie du Solide, CNRS UMR 8012, ENSCL, BP. 108, F-59652 Villeneuve d' Ascq Cedex (France); Herve, Vezin [Laboratoire de Chimie Organique et Macromoleculaire, CNRS UMR 8009, USTL Bat C3, F-59655 Villeneuve d' Ascq Cedex (France)

    2004-07-01

    In this work, a new class of thiadiazole derivatives, namely 3,5-bis(2-thienyl)-1,3,4-thiadiazole (2-TTH) and 3,5-bis(3-thienyl)-1,3,4-thiadiazole (3-TTH), have been studied as possible corrosion inhibitors for mild steel in molar hydrochloric acid (1M HCl). Polarisation curves and AC impedance methods have been used. These studies have shown that the thiadiazole derivatives were very good inhibitors for mild steel in 1M HCl. Comparison of results showed that 3-TTH was the best inhibitor. The potential of zero charge (PZC) of mild steel was studied by ac impedance method, and the mechanism of adsorption has been predicted. X-ray photoelectron spectroscopy surface analysis with thiadiazole derivatives shows that it chemisorbed at the mild steel/HCl interface. The adsorption of these inhibitors followed Langmuir's adsorption isotherm. The electronic properties of 2-TTH and 3-TTH, obtained using the AM1 semi-empirical quantum chemical approach, were correlated with their experimental efficiencies using the linear resistance model (LR). (authors)

  11. On the existence and uniqueness of solutions of optimal control problems of linear distributed systems which are not solved with respect to the time derivative

    Energy Technology Data Exchange (ETDEWEB)

    Plekhanova, Marina V; Fedorov, Vladimir E

    2011-04-30

    We investigate optimal control problems for linear distributed systems which are not solved with respect to the time derivative and whose homogeneous part admits a degenerate strongly continuous solution semigroup. To this end, we first obtain theorems on the existence of a unique strong solution of the Cauchy problem. This enables us to formulate sufficient conditions for the solubility of the optimal control problems under consideration. In contrast to earlier papers on a similar topic, we substantially weaken the conditions on the quality functional with respect to the state function. The abstract results thus obtained are illustrated by an example of an optimal control problem for the linearized system of Navier-Stokes equations.

  12. Monitoring of praseodymium(III) ions in aqueous solutions, soil and sediment samples by a PVC membrane sensor based on a furan-triazole derivative

    Energy Technology Data Exchange (ETDEWEB)

    Pourjavid, Mohammad Reza [Islamic Azad University, Tehran (Iran, Islamic Republic of). Dept. of Medicinal Chemistry. Nuclear Science and Technology Research Institute; Rezaee, Mohammad; Hosseini, Majid Haji [Nuclear Science and Technology Research Institute, Tehran (Iran, Islamic Republic of); Razavi, Taherehsadat, E-mail: pourjavid@gmail.com [Research Institute of Petroleum Industry, Tehran (Iran, Islamic Republic of). Instrumental Analysis Dept.

    2012-07-01

    A furan-triazole derivative has been explored as an ionophore for preparation of a highly selective Pr(III) membrane sensor. The proposed sensor exhibits a Nernstian response for Pr(III) activity over a wide concentration range with a detection limit of 5.2 x 10{sup -8}M. Its response is independent of pH of the solution in the range 3.0-8.8 and offers the advantages of fast response time. To investigate the analytical applicability of the sensor, it was applied successfully as an indicator electrode in potentiometric titration of Pr(III) solution and also in the direct and indirect determination of trace Pr(III) ions in some samples. (author)

  13. Electrochemical behaviour of Cu-30Ni alloy in 3 per cent NaCl (pH = 9.25) solution in presence of triazole derivatives compounds

    Energy Technology Data Exchange (ETDEWEB)

    Es-Salah, K. [Ibno Tofai Univ., Laboratoire d' Electrochimie des Etudes de Corrosion et d' Environnement, Faculte des Sciences, Kenitra (Morocco)]|[Paris Univ., Paris (France). Laboratoire de Physique des Liquides et Electrochimie; Benmessoud, M.; Hajjaji, N.; Srhiri, A. [Ibno Tofai Univ., Laboratoire d' Electrochimie des Etudes de Corrosion et d' Environnement, Faculte des Sciences, Kenitra (Morocco); Takenouti, H. [Paris Univ., Paris (France). Laboratoire de Physique des Liquides et Electrochimie

    2006-07-01

    This study investigated the electrochemical behaviour of of a copper-nickel alloy solution without and with the addition of triazole derivatives compounds. In particular, the rotating disc electrode technique was used to examine a mixture of Cu-30Ni in aerated 3 per cent NaCl solution of pH 9.25 with 3 - amino - 1,2,4 triazole, bitriazole. The corrosion rate and the kenitic charge that control the interface process were determined by potentiodynamic measurements and electrochemical impedance spectroscopy. The results showed that all the compounds influenced the cathodic and anodic process, indicating corrosion inhibition for the alloy. Electrochemical testing showed that the inhibition efficiency increased with increasing concentration and increasing immersion time at open circuit potential. It was demonstrated that the inhibition mixture provided more protection than ATA and BiTA.

  14. Adsorption Properties and Inhibition of C38 Steel Corrosion in Hydrochloric Solution by Some Indole Derivates: Temperature Effect, Activation Energies, and Thermodynamics of Adsorption

    Directory of Open Access Journals (Sweden)

    M. Lebrini

    2013-01-01

    Full Text Available The corrosion rates in the presence of some indole derivates, namely, 9H-pyrido[3,4-b]indole (norharmane and 1-methyl-9H-pyrido[3,4-b]indole (harmane, as inhibitors of C38 steel corrosion inhibitor in 1 M HCl solution, were measured by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS techniques, in the range of temperatures from 25 to 55∘C. Results obtained revealed that the organic compounds investigated have inhibiting properties for all temperatures. The inhibition was assumed to occur via adsorption of the indole molecules on the metal surface. Adsorption of indole derivates was found to follow the Langmuir isotherm. The apparent activation energies, enthalpies, and entropies of the dissolution process and the free energies and enthalpies for the adsorption process were determined by potentiodynamic polarization and electrochemical impedance. The fundamental thermodynamic functions were used to collect important information about indole inhibitory behaviour.

  15. Derivation of formulas for root-mean-square errors in location, orientation, and shape in triangulation solution of an elongated object in space

    Science.gov (United States)

    Long, S. A. T.

    1974-01-01

    Formulas are derived for the root-mean-square (rms) displacement, slope, and curvature errors in an azimuth-elevation image trace of an elongated object in space, as functions of the number and spacing of the input data points and the rms elevation error in the individual input data points from a single observation station. Also, formulas are derived for the total rms displacement, slope, and curvature error vectors in the triangulation solution of an elongated object in space due to the rms displacement, slope, and curvature errors, respectively, in the azimuth-elevation image traces from different observation stations. The total rms displacement, slope, and curvature error vectors provide useful measure numbers for determining the relative merits of two or more different triangulation procedures applicable to elongated objects in space.

  16. A tiny step towards a theory of functional derivative equations —A strong solution of the space-time hopf equation

    Science.gov (United States)

    Inoue, Atsushi

    In this note, we construct a strong solution of the space-time Hopf equation, (partial /{partial t} - vΔ ){δ Z(η )}/{δ η _ell (x,t)} = ileft[ {tilde T^* left\\{ {{δ ^2 Z(η )}/{δ η _j (x,t)δ η _k (x,t)}} right\\}} right]^ell + if^ell (x,t)Z(η ) with certain subsidary conditions, which is an example of functional derivative equations and is manageable using a tiny part of "analysis in functional spaces".

  17. Structural characterization and solution properties of a galacturonate polysaccharide derived from Aloe vera capable of in situ gelation.

    Science.gov (United States)

    McConaughy, Shawn D; Stroud, Paul A; Boudreaux, Brent; Hester, Roger D; McCormick, Charles L

    2008-02-01

    A series of highly purified galacturonate polysaccharides have been extracted from the Aloe vera plant and analyzed in terms of chemical composition and molecular weight. This Aloe vera polysaccharide (AvP) has been found to exist as a high molecular weight species and possess a unique chemical composition, including a high galacturonic acid (GalA) content and low degree of methyl ester substitution. These factors facilitate gel formation upon exposure to low concentrations of calcium ions, leading to potential application in formulations designed for in situ nasal or subcutaneous protein delivery. Thorough examination of classic dilute solution properties, the [eta]-M(w), and R(g)-M(w) relationships, persistence length (L(p)), and inherent chain stiffness (B parameter), indicate an expanded random coil in aqueous salt solutions. The critical concentration for transition from dilute to concentrated solution, C(e), was determined by measuring both the zero shear viscosity (eta(o)) and fluorescence emission of the probe molecule 1,8-anilino-1-naphthalene sulfonic acid (1,8-ANS) as a function of polymer concentration. Examination of zeta potential and C(e) as a function of ionic strength indicates that the shift in C(e) from 0.60 to 0.30 wt % is related to an increased occurrence of intermolecular interactions at high salt concentrations. Additionally, dynamic rheology data are presented highlighting the ability of AvP to form gels at low polymer and calcium ion concentrations, exemplifying the technological potential of this polysaccharide for in situ drug delivery.

  18. Solution regularity and co-normal derivatives for elliptic systems with non-smooth coefficients on Lipschitz domains

    OpenAIRE

    Mikhailov, SE

    2013-01-01

    This is the post-print version of the Article. The official published version can be accessed from the link below - Copyright @ 2013 Elsevier Elliptic PDE systems of the second order with coefficients from L∞ or Holder-Lipschitz spaces are considered in the paper. Continuity of the operators in corresponding Sobolev spaces is stated and the internal (local) solution regularity theorems are generalized to the non-smooth coefficient case. For functions from the Sobolev space H^s(Omega), 0.5

  19. Multiple positive solutions for singular m-point boundary-value problems with nonlinearities depending on the derivative

    Directory of Open Access Journals (Sweden)

    Baoqiang Yan

    2008-10-01

    Full Text Available Using the fixed point theorem in cones, this paper shows the existence of multiple positive solutions for the singular $m$-point boundary-value problem $$displaylines{ x''(t+a(tf(t,x(t,x'(t=0,quad 0

  20. Induced alignment of a solution-cast discotic hexabenzocoronene derivative for electronic devices investigated by surface X-ray diffraction

    DEFF Research Database (Denmark)

    Bunk, Oliver; Nielsen, Martin Meedom; Sølling, Theis Ivan

    2003-01-01

    A surface X-ray diffraction study is presented showing that highly ordered and uniaxially aligned hexa(3,7-dimethyl-octanyl)hexa-peri-hexabenzocoronene (HBC-C8,2) films can be fabricated by crystallization from solution onto friction-transferred poly(tetrafluoroethylene) (PTFE) layers. Three...... crystalline HBC-C8,2 majority phases result. In all three phases, the HBC-C8,2 molecules self-organize into columns which are uniaxially aligned along the direction defined by the PTFE macromolecules of the substrate. The three phases are quite similar, the major difference being their orientation...

  1. DNA derived fluorescent bio-dots for sensitive detection of mercury and silver ions in aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Song, Ting [Laboratory of Environmental Science and Technology, Xinjiang Technical Institute of Physics & Chemistry, Key Laboratory of Functional Materials and Devices for Special Environments, Chinese Academy of Sciences, Urumqi 830011 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Zhu, Xuefeng, E-mail: zhuxf@ms.xjb.ac.cn [Laboratory of Environmental Science and Technology, Xinjiang Technical Institute of Physics & Chemistry, Key Laboratory of Functional Materials and Devices for Special Environments, Chinese Academy of Sciences, Urumqi 830011 (China); Zhou, Shenghai [Laboratory of Environmental Science and Technology, Xinjiang Technical Institute of Physics & Chemistry, Key Laboratory of Functional Materials and Devices for Special Environments, Chinese Academy of Sciences, Urumqi 830011 (China); Yang, Guang [Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education and International Center for Dielectric Research, Xi’an Jiaotong University, Xi’an 710049 (China); Gan, Wei [Laboratory of Environmental Science and Technology, Xinjiang Technical Institute of Physics & Chemistry, Key Laboratory of Functional Materials and Devices for Special Environments, Chinese Academy of Sciences, Urumqi 830011 (China); Yuan, Qunhui, E-mail: yuanqh@ms.xjb.ac.cn [Laboratory of Environmental Science and Technology, Xinjiang Technical Institute of Physics & Chemistry, Key Laboratory of Functional Materials and Devices for Special Environments, Chinese Academy of Sciences, Urumqi 830011 (China)

    2015-08-30

    Highlights: • First application of a DNA derived fluorescent bio-dot for metal sensing. • Bio-dot was conveniently obtained via a mild thermal hydro-thermal synthesis. • Bio-dot was directly used for fluorescent sensing without further modification. • Bio-dot showed good fluorescent sensing property for Hg(II) and Ag(I). • Formation of T–Hg–T and C–Ag–C structures played key roles in sensing. - Abstract: Inspired by the high affinity between heavy metal ions and bio-molecules as well as the low toxicity of carbon-based quantum dots, we demonstrated the first application of a DNA derived carbonaceous quantum dots, namely bio-dots, in metal ion sensing. The present DNA-derived bio-dots contain graphitic carbon layers with 0.242 nm lattice fringes, exhibit excellent fluorescence property and can be obtained via a facile hydrothermal preparation procedure. Hg(II) and Ag(I) are prone to be captured by the bio-dots due to the existence of residual thymine (T) and cytosine (C) groups, resulting in a quenched fluorescence while other heavy metal ions would cause negligible changes on the fluorescent signals of the bio-dots. The bio-dots could be used as highly selective toxic-free biosensors, with two detecting linear ranges of 0–0.5 μM and 0.5–6 μM for Hg(II) and one linear range of 0–10 μM for Ag(I). The detection limits (at a signal-to-noise ratio of 3) were estimated to be 48 nM for Hg(II) and 0.31 μM for Ag(I), respectively. The detection of Hg(II) and Ag(I) could also be realized in the real water sample analyses, with satisfying recoveries ranging from 87% to 100%.

  2. Hydrazino-methoxy-1,3,5-triazine Derivatives' Excellent Corrosion Organic Inhibitors of Steel in Acidic Chloride Solution.

    Science.gov (United States)

    El-Faham, Ayman; Osman, Sameh M; Al-Lohedan, Hamad A; El-Mahdy, Gamal A

    2016-06-01

    The corrosion inhibition performance of 2-hydrazino-4,6-dimethoxy-1,3,5-tirazine (DMeHT), 2,4-dihydrazino-6-methoxy-1,3,5-triaizine (DHMeT), and 2,4,6-tridydrazino-1,3,5-triaizne (TH₃) on steel corrosion in acidic media was examined using electrochemical techniques. The results showed 2,4-Ddihydrazino-6-methoxy-1,3,5-triaizine (DHMeT) gave the best corrosion protection performance among the other hydrazino derivatives even at a low concentration of 25 ppm (95%). The number of hydrazino groups play an important role in the corrosion inhibition, where the two hydrazine groups increased the electrostatic interactions between the protonated tested compounds, the negatively charged steel surface resulted from the adsorption of the chloride anions, and the presence of the methoxy group made the compound more reliable for formation of film protection on the surface of steel through the lone pair of oxygen atoms. Electrochemical Impedance Spectroscopy (EIS) measurements suggested that the corrosion process of steel in presence of the hydrazino-s-triazine derivatives (TH₃, DMeHT and DHMeT) were being controlled by the charge transfer reaction. Polarization curves indicated that the examined TH₃, DMeHT and DHMeT behaved as mixed type inhibitors.

  3. Synthesis, characterizations, antibacterial and photoluminescence studies of solution combustion-derived α-Al2O3 nanoparticles

    Directory of Open Access Journals (Sweden)

    P.A. Prashanth

    2015-09-01

    Full Text Available In this work, we report a novel, economical, low temperature solution combustion synthesis (SCS method to prepare α-Al2O3 (Corundum nanoparticles. Powder X-ray diffraction (PXRD, field emission scanning electron microscopy (FE-SEM, high-resolution transmission electron microscopy (HR-TEM, Fourier transform infrared spectroscopy (FT-IR, BET surface area and ultraviolet visible spectroscopy (UV–vis measurements were used to characterize the product. Antibacterial studies were examined against gram −ve Klebsiella aerogenes, Escherichia coli, Pseudomonas desmolyticum and gram +ve Staphylococcus aureus bacteria by agar well diffusion method. The α-Al2O3 nanoparticles showed substantial effect on all the four bacterial strains. Photoluminescence (PL measurements under excitation at about 255 nm show that the alumina nanoparticles have emission peaks at 394 and 392 nm.

  4. Subduction-derived solute-rich fluid contributions to lavas of the Trans-Mexican Volcanic Belt

    Science.gov (United States)

    LaGatta, A.; Goldstein, S. L.; Langmuir, C. H.; Martin, A.; Carrasco-Nunez, G.; Cai, Y.

    2013-12-01

    Comparison of the chemical and Sr-Nd-Pb isotope compositions of calcalkaline lavas of the Trans-Mexican Volcanic Belt (TMVB), with subducted sediments (DSDP Site 487) and East Pacific Rise (EPR) basalts, elucidates the effects of solute rich fluids from the subducted ocean crust and sediments on volcanic front lavas. DSDP Site 487 contains a lower unit of hydrothermally affected Mn-rich sediment, and an upper unit of terrigenous detritus. Both sediment types and the subducted EPR basalts have chemical and isotopic distinctions that can be traced to the TMVB lavas, despite the thick continental crust. All these subduction components contribute across the arc, and they contribute most of the Pb and Sr (~50-80%) in the calcalkaline lavas. However, there is an along-arc variation in their contributions. In the western TMVB (e.g. Colima) an aqueous rich melt from subducted EPR basalt predominates (characterized by high Pb/Ce and low Pb and Sr isotope ratios). The central and eastern TMVB (Toluca to Pico de Orizaba) also sees the influence of an aqueous rich melt mixture from the Mn-rich sediment (characterized by high Pb/Ce and high seawater-like Sr isotope ratios, and low Sr isotope ratios), along with increasing contributions eastward from terrigenous sediment (showing higher Pb isotope ratios). Crustal assimilation also becomes more important eastwards (especially in Pico de Orizaba), but never masks the subduction contributions. The Mexican subduction component shows the fluid-mobile (e.g. Sr and Pb) and immobile LILE elements (e.g. Th and La) moving together in their enrichment, suggesting the nature of this component is a solute rich fluid or hydrous silicate melt. Alkali basalts in the TMVB showing 'ocean island basalt-like' trace element patterns for most elements are another important end member for TMVB lavas. The calcalkaline lavas appear to be mixtures of components from the subduction package and the depleted melt-residues of these (high Nb) alkali basalts

  5. CO2 Extraction from Ambient Air Using Alkali-Metal Hydroxide Solutions Derived from Concrete Waste and Steel Slag

    Science.gov (United States)

    Stolaroff, J. K.; Lowry, G. V.; Keith, D. W.

    2003-12-01

    To mitigate global climate change, deep reductions in CO2 emissions are required in the coming decades. Carbon sequestration will play a crucial role in this reduction. Early adoption of carbon sequestration in low-cost niche markets will help develop the technology and experience required for large-scale deployment. One such niche may be the use of alkali metals from industrial waste streams to form carbonate minerals, a safe and stable means of sequestering carbon. In this research, the potential of using two industrial waste streams---concrete and steel slag---for sequestering carbon is assessed. The scheme is outlined as follows: Ca and Mg are leached with water from a finely ground bed of steel slag or concrete. The resulting solution is sprayed through air, capturing CO2 and forming solid carbonates, and collected. The feasibility of this scheme is explored with a combination of experiments, theoretical calculations, cost accounting, and literature review. The dissolution kinetics of steel slag and concrete as a function of particle size and pH is examined. In stirred batch reactors, the majority of Ca which dissolved did so within the first hour, yielding between 50 and 250 (mg; Ca)/(g; slag) and between 10 and 30 (mg; Ca)/(g; concrete). The kinetics of dissolution are thus taken to be sufficiently fast to support the type of scheme described above. As proof-of-concept, further experiments were performed where water was dripped slowly through a stagnant column of slag or concrete and collected at the bottom. Leachate Ca concentrations in the range of 15 mM were achieved --- sufficient to support the scheme. Using basic physical principles and numerical methods, the quantity of CO2 captured by falling droplets is estimated. Proportion of water loss and required pumping energy is similarly estimated. The results indicate that sprays are capable of capturing CO2 from the air and that the water and energy requirements are tractable. An example system for

  6. Intramolecular and intermolecular hydrogen-bonding effects on photophysical properties of 2'-aminoacetophenone and its derivatives in solution.

    Science.gov (United States)

    Shimada, Hirofumi; Nakamura, Akihito; Yoshihara, Toshitada; Tobita, Seiji

    2005-04-01

    Effects of intra- and intermolecular hydrogen-bonds on the photophysical properties of 2'-aminoacetophenone derivatives (X-C6H4-COCH3) having a substituted amino group (X) with different hydrogen-bonding ability to the carbonyl oxygen (X: NH2(AAP), NHCH3(MAAP), N(CH3)2(DMAAP), NHCOCH3(AAAP), NHCOCF3(TFAAP)) are investigated by means of steady-state and time-resolved fluorescence spectroscopy and time-resolved thermal lensing. Based on the photophysical parameters obtained in aprotic solvents with different polarity and protic solvents with different hydrogen-bonding ability, the characteristic photophysical behavior of the 2'-aminoacetophenone derivatives is discussed in terms of hydrogen-bonding and n,pi*-pi,pi* vibronic coupling. The dominant deactivation process of AAP and MAAP in nonpolar aprotic solvents is the extremely fast internal conversion (k(ic)= 1.0 x 10(11) s(-1) for AAP and 3.9 x 10(10) s(-1) for MAAP in n-hexane). The internal conversion rates of both compounds decrease markedly with increasing solvent polarity, suggesting that vibronic interactions between close-lying S1(pi,pi*) and S2(n,pi*) states lead to the large increase in the non-radiative decay rate of the lowest excited singlet state. It is also suggested that for MAAP, which has a stronger hydrogen-bond as compared to AAP, an intramolecular hydrogen-bonding induced deactivation is involved in the dissipation of the S1 state. For DMAAP, which cannot possess an intramolecular hydrogen-bond, the primary relaxation mechanism of the S1 state in nonpolar aprotic solvents is the intersystem crossing to the triplet state, whereas in protic solvents very efficient internal conversion due to intermolecular hydrogen-bonding is induced. In contrast, the fluorescence spectra of AAAP and TFAAP, which have an amino group with a much stronger hydrogen-bonding ability, give strongly Stokes-shifted fluorescence, indicating that these compounds undergo excited-state intramolecular proton transfer reaction

  7. Bacteria-Derived Compatible Solutes Ectoine and 5α-Hydroxyectoine Act as Intestinal Barrier Stabilizers to Ameliorate Experimental Inflammatory Bowel Disease.

    Science.gov (United States)

    Abdel-Aziz, Heba; Wadie, Walaa; Scherner, Olaf; Efferth, Thomas; Khayyal, Mohamed T

    2015-06-26

    Earlier studies showed that the compatible solute ectoine (1) given prophylactically before induction of colitis by 2,4,6-trinitrobenzenesulfonic acid (TNBS) in rats prevented histological changes induced in the colon and the associated rise in inflammatory mediators. This study was therefore conducted to investigate whether ectoine (1) and its 5α-hydroxy derivative (2) would also be effective in treating an already established condition. Two days after inducing colitis in rats by instilling TNBS/alcohol in the colon, animals were treated orally once daily for 1 week with either 1 or 2 (50, 100, 300 mg/kg). Twenty-four hours after the last drug administration rats were sacrificed. Ulcerative lesions and colon mass indices were reduced by 1 and 2 in a bell-shaped manner. Best results were obtained with 100 mg/kg ectoine (1) and 50 mg/kg 5α-hydroxyectoine (2). The solutes normalized the rise in myeloperoxidase, TNFα, and IL-1β induced by TNBS but did not affect levels of reduced glutathione or ICAM-1, while reducing the level of fecal calprotectin, an established marker for inflammatory bowel disease. The findings indicate that the naturally occurring compatible solutes ectoine (1) and 5α-hydroxyectoine (2) possess an optimum concentration that affords maximal intestinal barrier stabilization and could therefore prove useful for better management of human inflammatory bowel disease.

  8. Electrochemical and theoretical investigation on the corrosion inhibition of mild steel by thiosalicylaldehyde derivatives in hydrochloric acid solution

    Energy Technology Data Exchange (ETDEWEB)

    Behpour, M. [Department of Chemistry, Faculty of Science, University of Kashan, Kashan (Iran, Islamic Republic of)], E-mail: m.behpour@kashanu.ac.ir; Ghoreishi, S.M.; Soltani, N.; Salavati-Niasari, M.; Hamadanian, M.; Gandomi, A. [Department of Chemistry, Faculty of Science, University of Kashan, Kashan (Iran, Islamic Republic of)

    2008-08-15

    Inhibitory effect of three Schiff bases 2-{l_brace}[(2-sulfanylphenyl)imino]methyl{r_brace}]phenol (A), 2-{l_brace}[(2)-1-(4-methylphenyl)methylidene]amino{r_brace}-1-benznethiol (B), and 2-[(2-sulfanylphen-yl)ethanimidoyl)]phenol (C) on corrosion of mild steel in 15% HCl solution has been studied using weight loss measurements, polarization and electrochemical impedance spectroscopy (EIS) methods. The results of the investigation show that the compounds A and B with mean efficiency of 99% at 200 mg/L additive concentration have fairly good inhibiting properties for mild steel corrosion in hydrochloric acid, and they are as mixed inhibitor. All measurements show that inhibition efficiencies increase with increase in inhibitor concentration. This reveals that inhibitive actions of inhibitors were mainly due to adsorption on mild steel surface. Adsorption of these inhibitors follows the Langmuir adsorption isotherm. Thermodynamic adsorption parameters (K{sub ads}, {delta}G{sub ads}) of studied Schiff bases were calculated using the Langmuir adsorption isotherm. Activation parameters of the corrosion process such as activation energies, E{sub a}, activation enthalpies, {delta}H{sup *}, and activation entropies, {delta}S{sup *}, were calculated by the obtained corrosion currents at different temperatures. Obvious correlation was found between the corrosion inhibition efficiency and the calculated parameters. The obtained theoretical results have been adapted with the experimental data.

  9. Very large photoconduction enhancement upon self-assembly of a new triindole derivative in solution-processed films

    Energy Technology Data Exchange (ETDEWEB)

    Gallego-Gomez, Francisco; Villalvilla, Jose M.; Quintana, Jose A.; Diaz-Garcia, Maria A. [Instituto Universitario de Materiales de Alicante and Dpto. Fisica Aplicada, Universidad de Alicante, 03080 Alicante (Spain); Garcia-Frutos, Eva M.; Gutierrez-Puebla, Enrique; Monge, Angeles; Gomez-Lor, Berta [Instituto de Ciencia de Materiales de Madrid, CSIC, C/Sor Juana Ines de la Cruz 3, 28049 Madrid (Spain)

    2011-02-22

    A new carbazole-related small molecule exhibiting self-assembly into ordered nanostructures in solution-processed cast films has been synthesized and its charge-photogeneration and -transport properties have been investigated. Large photoconductivity was measured in the amorphous state while an enormous improvement in the photoconduction properties was observed when the molecules spontaneously organized. Photocurrents increased upon self-assembly by up to four orders of magnitude, mostly due to the drastic enhancement of the charge photogeneration. A greatly favorable arrangement of the aromatic cores in the resulting nanostructures, which were characterized by X-ray analysis, may explain these improvements. Photocurrents of mA cm{sup -2}, on/off ratios of 10{sup 4} and quantum efficiencies of unity at low field and light intensity, which are among the best values reported to date, along with the simplicity of fabrication, give this readily-available organic system great potential for use in plastic optoelectronic devices. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  10. Removal of phosphate from aqueous solution using magnesium-alginate/chitosan modified biochar microspheres derived from Thalia dealbata.

    Science.gov (United States)

    Cui, Xiaoqiang; Dai, Xi; Khan, Kiran Yasmin; Li, Tingqiang; Yang, Xiaoe; He, Zhenli

    2016-10-01

    The objective of this study was to determine the feasibility of using magnesium-alginate/chitosan modified biochar microspheres to enhance removal of phosphate from aqueous solution. The introduction of MgCl2 substantially increased surface area of biochar (116.2m(2)g(-1)), and both granulation with alginate/chitosan and modification with magnesium improved phosphate sorption on the biochars. Phosphate sorption on the biochars could be well described by a simple Langmuir model, and the MgCl2-alginate modified biochar microspheres exhibited the highest phosphate sorption capacity (up to 46.56mgg(-1)). The pseudo second order kinetic model better fitted the kinetic data, and both the Yoon-Nelson and Thomas models were superior to other models in describing phosphate dynamic sorption. Precipitation with minerals and ligand exchange were the possible mechanisms of phosphate sorption on the modified biochars. These results imply that MgCl2-alginate modified biochar microspheres have potential as a green cost-effective sorbent for remediating P contaminated water environment.

  11. Stereoselective synthesis of lanthionine derivatives in aqueous solution and their incorporation into the peptidoglycan of Escherichia coli.

    Science.gov (United States)

    Denoël, Thibaut; Zervosen, Astrid; Gerards, Thomas; Lemaire, Christian; Joris, Bernard; Blanot, Didier; Luxen, André

    2014-09-01

    The three diastereoisomers-(R,R), (S,S) and meso-of lanthionine were synthesized in aqueous solution with high diastereoselectivity (>99%). The (S) and (R) enantiomers of two differently protected sulfamidates were opened by nucleophilic attack of (R) or (S)-cysteine. Acidification and controlled heating liberated the free lanthionines. Using the same chemistry, an α-benzyl lanthionine was also prepared. The proposed method, which avoids the need of enrichment by recrystallization, opens the way to the labelling of these compounds with (35)S. Furthermore, in vivo bioincorporation into Escherichia coli W7 was studied. No incorporation of α-benzyl lanthionine was observed. In contrast, meso-lanthionine can effectively replace meso-diaminopimelic acid in vivo, while in the presence of (R,R)-lanthionine the initial increase of bacterial growth was followed by cell lysis. In the future, meso-[(35)S]lanthionine could be used to study the biosynthesis of peptidoglycan and its turnover in relation to cell growth and division.

  12. Activated biochar derived from cactus fibres--preparation, characterization and application on Cu(II) removal from aqueous solutions.

    Science.gov (United States)

    Hadjittofi, Loukia; Prodromou, Melpomeni; Pashalidis, Ioannis

    2014-05-01

    The adsorption efficiency of activated biochar prepared from cactus fibres regarding the removal of Cu(II) from aqueous solutions has been investigated as a function of various physicochemical parameters (e.g. pH, initial metal concentration, ionic strength, temperature and contact time). Activation of the biochar took place using nitric acid oxidation and characterisation was performed by SEM analysis, FTIR spectroscopy, N2 adsorption and acid-base titrations. The results show that laminar structures constitute the material and carboxylic moieties are the predominant binding sites. The experimental data were analyzed by the Langmuir, Freundlich and Dubinin-Radushkevich adsorption models and the monolayer adsorption capacity was found to be 3.5 mol kg(-1). The effect of ionic strength and temperature on the adsorption efficiency indicates that at low pH outer-sphere and at near neutral pH inner-sphere complexes are the predominant surface species and the kinetic data obtained were fitted very well by the Lagergren rate expression.

  13. Arsenic(V) removal from aqueous solutions using an anion exchanger derived from coconut coir pith and its recovery.

    Science.gov (United States)

    Anirudhan, T S; Unnithan, Maya R

    2007-01-01

    The performance of a new anion exchanger (AE) prepared from coconut coir pith (CP), for the removal of arsenic(V) [As(V)] from aqueous solutions was evaluated in this study. The adsorbent (CP-AE) carrying dimethylaminohydroxypropyl weak base functional group was synthesized by the reaction of CP with epichlorohydrin and dimethylamine followed by treatment of hydrochloric acid. IR spectroscopy results confirm the presence of -NH(+)(CH(3))(2)Cl(-) group in the adsorbent. XRD studies confirm the decrease of crystallinity in CP-AE compared to CP, and it favours the protrusion of the functional group into the aqueous medium. Batch experiments were conducted to examine the efficiency of the adsorbent on As(V) removal. Maximum removal of 99.2% was obtained for an initial concentration of 1 mgl(-1) As(V) at pH 7.0 and an adsorbent dose of 2 gl(-1). The kinetics of sorption of As(V) onto CP-AE was described using the pseudo-second-order model. The equilibrium isotherms were determined for different temperatures and the results were analysed using the Langmuir equation. The temperature dependence indicates an exothermic process. Utility of the adsorbent was tested by removing As(V) from simulated groundwater. Regeneration studies were performed using 0.1N HCl. Batch adsorption-desorption studies illustrate that CP-AE could be used to remove As(V) from ground water and other industrial effluents.

  14. Adsorption properties and inhibition of mild steel corrosion in hydrochloric solution by some newly synthesized diamine derivatives: Experimental and theoretical investigations

    Energy Technology Data Exchange (ETDEWEB)

    Herrag, L.; Hammouti, B.; Elkadiri, S.; Aouniti, A. [Laboratoire de Chimie Appliquee et Environnement, LCAE-URAC18, Faculte des Sciences, Universite Mohammed Premier, B.P. 717, M-6000 Oujda (Morocco); Jama, C. [Unite Materiaux et Transformations (UMET), Ingenierie des Systemes Polymeres, CNRS UMR 8207, ENSCL, B.P. 90108, F-59652 Villeneuve d' Ascq Cedex (France); Vezin, H. [Laboratoire de Spectrochimie Infrarouge et Raman (LASIR), UMR-CNRS 8516, Universite des Sciences et Technologies de Lille, Batiment C5, F-59655 Villeneuve d' Ascq Cedex (France); Bentiss, F., E-mail: fbentiss@enscl.f [Laboratoire de Chimie de Coordination et d' Analytique (LCCA), Faculte des Sciences, Universite Chouaib Doukkali, B.P. 20, M-24000 El Jadida (Morocco)

    2010-09-15

    New diamine derivatives, namely 2-[{l_brace}2-[bis-(2-hydroxyethyl)amino]ethyl{r_brace}(2-hydroxyethyl)amino]ethanol (DAME) and 2-[{l_brace}2-[bis-(2-hydroxyethyl)amino]ethyl{r_brace}(2-hydroxyethyl)amino]propanol (DAMP) were synthesised and their inhibitive action against the corrosion of mild steel in 1 M HCl solution were investigated at 308 K. The detailed study of DAME is given using gravimetric measurements and polarization curves method. Results show that DAME is a good inhibitor and inhibition efficiency reaches 91.7% at 10{sup -3} M. Tafel polarization study revealed that DAME acts as a mixed-type inhibitor. The inhibitor adsorption process in mild steel/DAME/hydrochloric acid system was studied at different temperatures (308-353 K) by means of weight loss measurements. The adsorption of DAME on steel surface obeyed Langmuir's adsorption isotherm. The kinetic and thermodynamic parameters for mild steel corrosion and inhibitor adsorption, respectively, were determined and discussed. The comparative study of inhibitive performance of the two diamine derivatives revealed that DAME is more effective than DAMP. Quantitative Structure-Activity Relationship (QSAR) approach has been conducted in attempt to correlate the corrosion inhibition properties of these diamine derivatives with their calculated quantum chemical parameters.

  15. Adsorption of lead ions from aqueous solution using porous carbon derived from rubber tires: experimental and computational study.

    Science.gov (United States)

    Saleh, Tawfik A; Gupta, Vinod K; Al-Saadi, Abdulaziz A

    2013-04-15

    Effective activated porous carbon (AC) was prepared by thermal treatment of waste rubber tires and was further activated using oxidizing agents like nitric acid and hydrogen peroxide. The tire-derived porous carbon was characterized by means of FTIR and X-ray diffraction. Careful analysis of the IR spectra of the synthesized AC reveals a number of bands centered at about 3400, 2350, 1710, 1650, and 1300-1000cm(-1), proving the existence of hydroxyl and carboxylic groups on the surface of AC in addition to CC double bonds. The developed AC was tested and evaluated as a potential adsorbent for the removal of lead (II) ions. Experimental parameters, such as contact time, initial concentration, adsorbent dosage, and pH were optimized. AC was effective in a pH range between 4 and 7 with a highest uptake of lead ions at pH 5 and 6. For further understanding of the chemistry behind the process, density functional theory (DFT) calculations were performed at the B3LYP/6-31G(d) level adopting a functionalized pyrene molecule as a model. The binding energy of Pb(II) ion toward carboxylic acid, carbonyl, and hydroxyl groups was calculated. A binding energy in the range of 310-340kcal/mol, which is considered to be high and to be indicative of a chemisorptions process, was predicted. The adsorption of the lead ion toward the CO groups in relatively all cases shows more stable binding compared to the sorption toward the alcohol groups.

  16. Mononuclear and polynuclear complexes ligated by an iminodiacetic acid derivative: synthesis, structure, solution studies and magnetic properties.

    Science.gov (United States)

    Puentes, Roberto; Torres, Julia; Kremer, Carlos; Cano, Joan; Lloret, Francesc; Capucci, Davide; Bacchi, Alessia

    2016-03-28

    Two novel families of coordination polymers, [Ln(bzlida)(Hbzlida)]·H2O (Ln = La, Nd) and [Ln2(bzlida)3]·3H2O (Ln = Nd, Sm, Eu, Gd) were prepared by hydrothermal reaction of Ln2O3 with benzyliminodiacetic acid (H2bzlida). The conditions of synthesis, in particular the pH value, were selected on the basis of previous speciation studies reported in this work. The first type of complex consists of 1D chains built by a fully deprotonated ligand bridging two lanthanide ions and protonated Hbzlida(-) ligands connecting three cations. The second type is formed by [Ln2(bzlida)3] bimetallic units in which the ligand has a tridentate NOO coordination mode. This is expanded to a 2D network through carboxylate linkers. Under similar synthetic conditions but including copper acetate in the reaction mixture, a new compound was also obtained and characterized: [Cu(bzlida)2{Er(AcO)(H2O)5}2][Cu(bzlida)2]·6H2O (AcO = acetate). This salt is made up of the [Cu(bzlida)2{Er(AcO)(H2O)5}2](2+) heterotrimetallic complex cation containing an acetato bridge, and the [Cu(bzlida)2](2-) anion. The same reaction produces the monomeric [Cu(Hbzlida)2]·4H2O whose structure was also elucidated. Magnetic properties of the Gd(iii) derivative were studied and analyzed experimentally and theoretically. The results are compared and discussed with respect to those reported in the literature and a magnetostructural correlation is suggested.

  17. Solution structures, dynamics, and ice growth inhibitory activity of peptide fragments derived from an antarctic yeast protein.

    Directory of Open Access Journals (Sweden)

    Syed Hussinien H Shah

    Full Text Available Exotic functions of antifreeze proteins (AFP and antifreeze glycopeptides (AFGP have recently been attracted with much interest to develop them as commercial products. AFPs and AFGPs inhibit ice crystal growth by lowering the water freezing point without changing the water melting point. Our group isolated the Antarctic yeast Glaciozyma antarctica that expresses antifreeze protein to assist it in its survival mechanism at sub-zero temperatures. The protein is unique and novel, indicated by its low sequence homology compared to those of other AFPs. We explore the structure-function relationship of G. antarctica AFP using various approaches ranging from protein structure prediction, peptide design and antifreeze activity assays, nuclear magnetic resonance (NMR studies and molecular dynamics simulation. The predicted secondary structure of G. antarctica AFP shows several α-helices, assumed to be responsible for its antifreeze activity. We designed several peptide fragments derived from the amino acid sequences of α-helical regions of the parent AFP and they also showed substantial antifreeze activities, below that of the original AFP. The relationship between peptide structure and activity was explored by NMR spectroscopy and molecular dynamics simulation. NMR results show that the antifreeze activity of the peptides correlates with their helicity and geometrical straightforwardness. Furthermore, molecular dynamics simulation also suggests that the activity of the designed peptides can be explained in terms of the structural rigidity/flexibility, i.e., the most active peptide demonstrates higher structural stability, lower flexibility than that of the other peptides with lower activities, and of lower rigidity. This report represents the first detailed report of downsizing a yeast AFP into its peptide fragments with measurable antifreeze activities.

  18. Interaction of derived polymers from pyrrole with biocompatible solutions; Interaccion de polimeros derivados de pirrol con soluciones biocompatibles

    Energy Technology Data Exchange (ETDEWEB)

    Lopez G, O. G.

    2010-07-01

    This work presents a study about the synthesis by plasma, the electric properties and superficial interaction of polymers derived from pyrrole doped with Iodine with potential use as bio material. Poly-pyrrole is a semiconductor and biocompatible polymer with potential application in the development of artificial muscles and implants where the electric interaction between cells and material is an important variable. The syntheses were made at 13.5 MHz in a glass tubular reactor of 1500 cm{sup 3} with electrodes of 6.5 cm diameter and stainless steel flanges. An electrode was connected to the RF terminal of the power supply that is combined with a matching coupling resistance. The monomer and dopant used in this work were pyrrole and Iodine respectively, in closed containers. They were vaporized and injected separately into the reactor at room temperature and 0.1 mbar. The vapors of the reagents mixed freely in the reactor. The synthesis time was 240 min at 40, 60, 80 and 100 W. The polymers were obtained as thin films adhered to the reactor walls. The films were washed and swollen with distilled water and removed from the reactor walls with a small spatula. The polymers were irradiated with gamma rays at 18 and 22 KGy. Due to the fact that the doses are cumulative, the final dose applied was 40 KGy. The polymers characterization was carried out by Fourier Transform Infrared Spectroscopy, thermogravimetric analysis (TGA), scanning electron microscopy, contact angle, electrical conductivity and X-ray diffraction. The analyses indicates that the polymers have very similar structure in almost the entire power range, showing C-O, C=C, C-H, O-H, N-H bonds with a predominantly amorphous structure. The TGA analyses showed that the material has 4 or 5 loses of material. The first one starts after that 115 C except for the material irradiated at 40 KGy, this one begins in 87 C, the second one is in the interval of 196 and 295 C, the third one between 311 and 500 C, and the

  19. Cost-effective electrostatic-sprayed SrAl2O4:Eu2+ phosphor coatings by using salted sol–gel derived solution

    Indian Academy of Sciences (India)

    Kyu-Seog Hwang; Bo-An Kang; Sung-Dai Kim; Seung Hwangbo; Jim-Tae Kim

    2011-08-01

    3 Mol% of europium doped strontium aluminate (SrAl2O4:Eu2+) coatings on silicon substrates were prepared by electrostatic spray deposition method using a salted sol–gel derived solution as a starting material. Asdeposited films at 100°C for 5 h were heated at 1100°C for 2 h under a reducing ambient atmosphere of 95%N2 + 5%H2 . Nanocrystalline SrAl2O4 film was confirmed by surface morphological and crystallographic analyses. Monitored at 520 nm, the excitation spectrum showed a broad band from 300 ∼ 500 nm and the emission intensity showed a maximum yellow peak intensity at 512 nm with a broad band from 460 ∼ 610 nm.

  20. Synthesis, electrochemical, spectrophotometric and potentiometric studies of two azo-compounds derived from 4-amino-2-methylquinoline in ethanolic-aqueous buffered solutions

    Energy Technology Data Exchange (ETDEWEB)

    El-Attar, Mona A.; Ghoneim, Mohamed M. [Analytical Chemistry Research Unit, Chemistry Department, Tanta University (Egypt); Ismail, Iqbal M., E-mail: maema.2011@yahoo.com [Chemistry Department, Faculty of Science, King Abdul Aziz University, Jeddah (Saudi Arabia)

    2012-08-15

    Two azo-compounds, 2-methyl-4-(5-amino-2-hydroxy-phenylazo)-quinoline (2) and 2-methyl-4-(2-hydroxy-5-nitrophenylazo)-quinoline, derived from 4-amino-2-methylquinoline were synthesized. Their chemical structures were characterized and confirmed by means of elemental chemical analysis, infrared (IR) spectroscopy, {sup 1}H nuclear magnetic resonance (NMR) and mass spectrometry (MS). The electrochemical behavior of the starting compound (4-amino-2-methylquinoline) and of the two synthesized azo-derivatives was studied at the mercury electrode in the B-R universal buffer at various pH values (2-11.5) containing 40% (v/v) ethanol using dc-polarography, cyclic voltammetry and controlled-potential coulometry. Their electrode reaction pathways were elucidated and discussed. The dissociation constants (pKa) of the examined compounds, stability constants and stoichiometry of their complexes in solution with some transition metal ions (Co(II), Ni(II), Cu(II), La(III) and UO{sup 2+}{sub 2}) were determined. (author)

  1. A steady state solution for ditch drainage problem with special reference to seepage face and unsaturated zone flow contribution: Derivation of a new drainage spacing eqaution

    Science.gov (United States)

    Yousfi, Ammar; Mechergui, Mohammed

    2016-04-01

    al. (2001). In this work, a novel solution based on theoretical approach will be adapted to incorporate both the seepage face and the unsaturated zone flow contribution for solving ditch drained aquifers problems. This problem will be tackled on the basis of the approximate 2D solution given by Castro-Orgaz et al. (2012). This given solution yields the generalized water table profile function with a suitable boundary condition to be determined and provides a modified DF theory which permits as an outcome the analytical determination of the seepage face. To assess the ability of the developed equation for water-table estimations, the obtained results were compared with numerical solutions to the 2-D problem under different conditions. It is shown that results are in fair agreement and thus the resulting model can be used for designing ditch drainage systems. With respect to drainage design, the spacings calculated with the newly derived equation are compared with those computed from the DF theory. It is shown that the effect of the unsaturated zone flow contribution is limited to sandy soils and The calculated maximum increase in drain spacing is about 30%. Keywords: subsurface ditch drainage; unsaturated zone; seepage face; water-table, ditch spacing equation

  2. Novel magnetic porous carbon spheres derived from chelating resin as a heterogeneous Fenton catalyst for the removal of methylene blue from aqueous solution.

    Science.gov (United States)

    Ma, Junjun; Zhou, Lincheng; Dan, Wenfeng; Zhang, He; Shao, Yanming; Bao, Chao; Jing, Lingyun

    2015-05-15

    Porous magnetic carbon spheres (MCS) were prepared from carbonized chelating resin composites derived from ethylenediaminetetraacetic acid-modified macroporous polystyrene (PS-EDTA) resin, and then loaded with iron composites via ion exchange. The resulting composites were characterized for this study using X-ray diffraction, MÖssbauer spectroscopy, and Raman spectroscopy, X-ray photoelectron spectroscopy, Brunauer-Emmett-Teller surface area method, scanning electron microscopy, and vibrating sample magnetometry. The porous magnetic carbon spheres were then used, in the existence of H2O2 and NH2OH, with a view to remove methylene blue from the aqueous solution by catalyze a heterogeneous Fenton reaction. Results indicated excellent removal rates and removal efficiency for this catalytic system. Optimal degradation was achieved (nearly 100% within 10 min) using initial concentrations of 5 mmol H2O2 L(-1), 2.5 mmol L(-1) NH2OH and 40 mg L(-1) methylene blue. The catalyst retained its activity after six reuses, indicating strong stability and reusability. Porosity of the catalyst contributed to its high activity, suggesting its potential application for the industrial treatment of wastewater.

  3. Nanostructural control in solution-derived epitaxial Ce{sub 1-x}Gd{sub x}O{sub 2-y} films

    Energy Technology Data Exchange (ETDEWEB)

    Coll, M; Gazquez, J; Sandiumenge, F; Puig, T; Obradors, X [Institut de Ciencia de Materials de Barcelona, CSIC Campus de la UAB, E-08193 Bellaterra, Catalonia (Spain); Espinos, J P [Instituto de Ciencia de Materiales de Sevilla, CSIC Avenida Americo Vespucio s/n Isla de la Cartuja, E-41092 Sevilla (Spain); Huehne, R [IFW Dresden, Leibniz Institute for Solid State and Materials Research, Dresden, Helmholtzstrasse 20, D-01069 (Germany)], E-mail: felip@icmab.cat

    2008-10-01

    A novel mechanism based on aliovalent doping, allowing fine tuning of the nanostructure and surface topography of solution-derived ceria films, is reported. While under reducing atmospheric conditions, non-doped ceria films are inherently polycrystalline due to an interstitial amorphous Ce{sub 2}C{sub 3} phase that inhibits grain growth, a high quality epitaxial film can be achieved simply by doping with Gd{sup 3+} cations. Gd{sup 3+} {r_reversible} Ce{sup 4+} substitutions within the lattice are accompanied by charge-compensating oxygen vacancies throughout the volume of the crystallites acting as an efficient vehicle to reduce the barrier for grain boundary motion caused by interstitial Ce{sub 2}C{sub 3}. In this way, the original nanostructure is self-purified by pushing the amorphous Ce{sub 2}C{sub 3} phase towards the free surface of the film. Once a full epitaxial cube-on-cube oriented ceria film is obtained, its surface morphology is dictated by the interplay between faceting on low energy {l_brace}110{r_brace} and/or {l_brace}111{r_brace} pyramidal planes and truncation of those pyramids by (001) ones. The development of the latter requires the suppression of their polar character which is thought to be achieved by charge compensation between the dopand and oxygen along <100> directions.

  4. Derivative Chameleons

    CERN Document Server

    Noller, Johannes

    2012-01-01

    We consider generalized chameleon models where the conformal coupling between matter and gravitational geometries is not only a function of the chameleon field \\phi, but also of its derivatives via higher order co-ordinate invariants. Specifically we consider the first such non-trivial conformal factor A(\\phi,X), where X is the canonical kinetic term for \\phi. The associated phenomenology is investigated and we show that such theories have a new generic mass-altering mechanism, potentially assisting the generation of a sufficiently large chameleon mass in dense environments. The most general effective potential is derived for such derivative chameleon setups and explicit examples are given. Interestingly this points us to the existence of a purely derivative chameleon protected by a shift symmetry for \\phi. We also discuss potential ghost-like instabilities associated with mass-lifting mechanisms and find another, mass-lowering and instability-free, branch of solutions. This suggests that, barring fine-tuning...

  5. Hi ro ta双线性导数方法求解K dV方程的双周期波解%Doubly periodic hirota bilinear derivative method for solving double periodic wave solution of KdV equations

    Institute of Scientific and Technical Information of China (English)

    梁聪刚; 王鸿章

    2015-01-01

    Nonlinear evolution equations are mathematical model obtained during the period that people learn and illustrate phenomena of nature .It’s very important to do research on the condition of the solution to the model ,and its explicit solution is more necessary in carrying out a research .Hirota bilinear derivative method is one of the effective methods to solve the exact solutions of nonlinear evolution equations .By using the Hirota bilinear derivative meth‐od ,and with the aid of auxiliary jacobian function ,bilinear derivative method is applied to e‐duce the solution of KdV equations ,and finally the double periodic wave solutions and solitary wave solution are numerically simulated .%非线性发展方程是人们认识和解释自然界许多现象时得到的数学模型,研究这些模型的解的性态十分重要,其显式解更是人们研究所必需的。 Hirota双线性导数方法是求解非线性发展方程精确解的非常有效的方法之一。本文利用 Hirota双线性导数方法,并借助于辅助雅可比矰函数,利用Hirota提出的双线性导数方法,导出kdv方程的解,最后并对双周期波解和孤立波解进行了数值模拟。

  6. The solution of the Painlevé equations as special functions of catastrophes, defined by a rejection in these equations of terms with derivative

    CERN Document Server

    Kiselev, O M

    1999-01-01

    The relation between the Painleve equations and the algebraic equations with the catastrophe theory point of view are considered. The asymptotic solutions with respect to the small parameter of the Painleve equations different types are discussed. The qualitative analysis of the relation between algebraic and fast oscillating solutions is done for Painleve-2 as an example.

  7. Wave Solutions

    CERN Document Server

    Christov, Ivan C

    2012-01-01

    In classical continuum physics, a wave is a mechanical disturbance. Whether the disturbance is stationary or traveling and whether it is caused by the motion of atoms and molecules or the vibration of a lattice structure, a wave can be understood as a specific type of solution of an appropriate mathematical equation modeling the underlying physics. Typical models consist of partial differential equations that exhibit certain general properties, e.g., hyperbolicity. This, in turn, leads to the possibility of wave solutions. Various analytical techniques (integral transforms, complex variables, reduction to ordinary differential equations, etc.) are available to find wave solutions of linear partial differential equations. Furthermore, linear hyperbolic equations with higher-order derivatives provide the mathematical underpinning of the phenomenon of dispersion, i.e., the dependence of a wave's phase speed on its wavenumber. For systems of nonlinear first-order hyperbolic equations, there also exists a general ...

  8. Photoanodic properties of sol-gel-derived iron oxide thin films with embedded gold nanoparticles: effects of polyvinylpyrrolidone in coating solutions

    Energy Technology Data Exchange (ETDEWEB)

    Hida, Yoshihiro [Department of Materials Science and Engineering, Kansai University, 3-3-35 Yamate-cho, Suita 564-8680 (Japan); Kozuka, Hiromitsu [Department of Materials Science and Engineering, Kansai University, 3-3-35 Yamate-cho, Suita 564-8680 (Japan)]. E-mail: kozuka@ipcku.kansai-u.ac.jp

    2005-04-08

    Fe{sub 2}O{sub 3} thin films containing dispersed Au nanoparticles were prepared on nesa silica glass substrates, using Fe(NO){sub 3}.9H{sub 2}O-HAuCl{sub 4}.4H{sub 2}O-CH{sub 3}COCH{sub 2}COCH{sub 3}-CH{sub 3}OC{sub 2}H{sub 4}OH solutions containing polyvinylpyrrolidone (PVP). The photoanodic properties were studied in a three-electrode cell with the film sample as the working electrode and an aqueous buffer solution of pH=7 as the supporting electrolyte. The Au particles increased photoanodic quantum efficiency at wavelengths <500-600 nm. Quantum efficiency was further increased by modifying the microstructure of the film electrodes through the addition of PVP. The maximum incident photon to current efficiency (IPCE) of about 20% was achieved in an Au-dispersed film prepared from a solution containing PVP. PVP in coating solutions provided the fired films with an increase in size of the grains and voids between them and in donor density, either of which could contribute to the increased IPCE.

  9. Structural investigation of aryllithium clusters in solution. I. A 13C and 7Li NMR studyof phenyllithium and some methyl-substituted phenyllithium derivatives

    NARCIS (Netherlands)

    Koten, G. van; Wehman, E.; Jastrzebski, J.T.B.H.; Ernsting, J.M.; Grove, D.M.

    1988-01-01

    }1{}3{C and }7{Li NMR spectra of phenyllithium and several methyl subsituted phenyllithium derivatives have been recorded in the presence of known amounts of coordinating solvents such as monodentate diethyl ether and THF and the potentially bidentate TMEDA (tetramethylethylenediamine). The relative

  10. Derivative chameleons

    Science.gov (United States)

    Noller, Johannes

    2012-07-01

    We consider generalized chameleon models where the conformal coupling between matter and gravitational geometries is not only a function of the chameleon field phi, but also of its derivatives via higher order co-ordinate invariants (such as ∂μphi∂μphi,squphi,...). Specifically we consider the first such non-trivial conformal factor A(phi,∂μphi∂μphi). The associated phenomenology is investigated and we show that such theories have a new generic mass-altering mechanism, potentially assisting the generation of a sufficiently large chameleon mass in dense environments. The most general effective potential is derived for such derivative chameleon setups and explicit examples are given. Interestingly this points us to the existence of a purely derivative chameleon protected by a shift symmetry for phi → phi+c. We also discuss potential ghost-like instabilities associated with mass-lifting mechanisms and find another, mass-lowering and instability-free, branch of solutions. This suggests that, barring fine-tuning, stable derivative models are in fact typically anti-chameleons that suppress the field's mass in dense environments. Furthermore we investigate modifications to the thin-shell regime and prove a no-go theorem for chameleon effects in non-conformal geometries of the disformal type.

  11. Selective and visual Ca(2+) ion recognition in solution and in a self-assembly organogel of the terpyridine-based derivative triggered by ultrasound.

    Science.gov (United States)

    Geng, Lijun; Li, Yajuan; Wang, Zengyao; Wang, Yanqiu; Feng, Guoliang; Pang, Xuelei; Yu, Xudong

    2015-11-07

    A new kind of terpyridine-based Ca(2+) sensor TS was designed and studied based on the internal charge transfer (ICT). In the diluted solution state, TS sensed Ca(2+) and Mg(2+) ions among test ions via an "off-on" approach as seen from fluorescence spectra of test ions. Moreover, TS was able to form stable fluorescent gels in organic solvents accelerated by ultrasound, indicating the ultrasound responsive properties of TS molecules. The S-gel of TS could be successfully used to selectively recognize Ca(2+) through fluorescent emission color and morphological changes, which was different from that of the solution state. It was predicated that the competition between the self-assembly of TS molecules and the host–guest interaction of TS with Ca(2+) or Mg(2+) was responsible for the sensing properties. To the best of our knowledge, this is the first example that organogels could selectively sense Ca2+ ions.

  12. Thiazol-4-one derivatives from the reaction of monosubstituted thioureas with maleimides: structures and factors determining the selectivity and tautomeric equilibrium in solution

    Directory of Open Access Journals (Sweden)

    Alena S. Pankova

    2016-11-01

    Full Text Available 2-(Alkyl(arylaminothiazol-4(5H-ones can regioselectively be prepared from monoalkyl(arylthioureas and maleimides. In solution, the former heterocycles exist in a tautomeric equilibrium with 2-(alkyl(aryliminothiazolidin-4-ones and the substituent on the exocyclic nitrogen atom governs the ratio of these tautomers. Isomers with the alkyl group in the endocyclic position can be obtained from N-methyl(ethylthioureas. 2D NMR spectroscopy and DFT calculations rationalize experimental results.

  13. First- and Second-Derivative Spectrophotometry for Simultaneous Determination of Copper and Cobalt by 1-(2-Pyridylazo)-2-naphthol in Tween 80 Micellar Solutions

    OpenAIRE

    Eskandari, Habibollah; SAGHSELOO, Ali Ghanbari

    2014-01-01

    1-(2-Pyridylazo)-2-naphthol (PAN) has been used for the simultaneous determination of copper and cobalt at trace levels. PAN at pH 1.89 forms red and green complexes with copper and cobalt, respectively, which are soluble in aqueous Tween 80 micellar media and are stable for at least 3 days. Under optimum conditions, calibration graphs were obtained for individual determination of copper and cobalt by zero- and first-derivative spectrophotometry and for simultaneous determination by ...

  14. First- and Second-Derivative Spectrophotometry for Simultaneous Determination of Copper and Cobalt by 1-(2-Pyridylazo)-2-naphthol in Tween 80 Micellar Solutions

    OpenAIRE

    Eskandari, Habibollah; SAGHSELOO, Ali Ghanbari

    2006-01-01

    1-(2-Pyridylazo)-2-naphthol (PAN) has been used for the simultaneous determination of copper and cobalt at trace levels. PAN at pH 1.89 forms red and green complexes with copper and cobalt, respectively, which are soluble in aqueous Tween 80 micellar media and are stable for at least 3 days. Under optimum conditions, calibration graphs were obtained for individual determination of copper and cobalt by zero- and first-derivative spectrophotometry and for simultaneous determination by ...

  15. Effect of TiCl{sub 4} concentration on the structure of its aqueous solutions and on the properties and photoactivity of derived nanocrystalline titania

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Liwei, E-mail: liweiwangy@hotmail.com [Department of Chemistry and Chemical Engineering, Minjiang University, Fuzhou 350108 (China); Egerton, Terry A., E-mail: terry.egerton@ncl.ac.uk [School of Chemical Engineering and Advanced Materials, Newcastle University, Newcastle NE1 7RU (United Kingdom)

    2014-10-15

    The influence of the concentration of aqueous TiCl{sub 4} solution on the phase formation, morphology and particle size of the titanium dioxide hydrolysis product was investigated by XRD and TEM. Significant features, observed in the Raman spectra of the TiCl{sub 4} solutions with a concentration >3 M, demonstrated that the TiCl{sub 4} had hydrolysed. As the formal concentration of TiCl{sub 4} decreased from 4.98 to 1 M, the Raman spectra changed qualitatively. Despite the changes in the Raman spectra of these precursor solutions, the TiO{sub 2} product was mainly rutile in all cases. However, at low TiCl{sub 4} concentrations small amounts of anatase were also observed. Electron microscopy suggested that the anatase particles were significantly smaller than the rutile and also indicated increasing aggregation of the product from the more dilute TiCl{sub 4} solutions. The optical properties and photoactivities of the TiO{sub 2} powders prepared at different concentrations were also investigated. The powder synthesized from 5 M TiCl{sub 4} showed the highest UV extinction. The photoactivity of the product, determined by the photocatalytic oxidation of propan-2-ol (isopropanol) to propanone (acetone), was not significantly modified by changes in the concentration of the starting TiCl{sub 4}. The possibility that the relatively low area of most rutiles contributes to the reported photocatalytic activity of rutile being lower than that of anatase is discussed. - Highlights: • Properties of TiO{sub 2} made from TiCl{sub 4} of decreasing concentration are reported. • Raman spectra change as TiCl{sub 4} concentrations decrease from 5 to 2.5 M. • Rutile is the major product from hydrolysis of 1 M–5 M TiCl{sub 4} solutions. • Optical properties are changed. • Activity for photocatalysis of propan-2-ol is unaltered.

  16. Selective production of hemicellulose-derived carbohydrates from wheat straw using dilute HCl or FeCl3 solutions under mild conditions. X-ray and thermo-gravimetric analysis of the solid residues.

    Science.gov (United States)

    Marcotullio, G; Krisanti, E; Giuntoli, J; de Jong, W

    2011-05-01

    The present work explores the combined production of hemicellulose-derived carbohydrates and an upgraded solid residue from wheat straw using a dilute-acid pretreatment at mild temperature. Dilute aqueous HCl solutions were studied at temperatures of 100 and 120°C, and they were compared to dilute FeCl(3) under the same conditions. Comparable yields of soluble sugars and acetic acid were obtained, affording an almost complete removal of pentoses when using 200 mM aqueous solutions at 120°C. The solid residues of pretreatment were characterized showing a preserved crystallinity of the cellulose, and a almost complete removal of ash forming matter other than Si. Results showed upgraded characteristic of the residues for thermal conversion applications compared to the untreated wheat straw.

  17. Thiazol-4-one derivatives from the reaction of monosubstituted thioureas with maleimides: structures and factors determining the selectivity and tautomeric equilibrium in solution

    Science.gov (United States)

    Golubev, Pavel R; Khlebnikov, Alexander F; Ivanov, Alexander Yu; Kuznetsov, Mikhail A

    2016-01-01

    2-(Alkyl(aryl)amino)thiazol-4(5H)-ones can regioselectively be prepared from monoalkyl(aryl)thioureas and maleimides. In solution, the former heterocycles exist in a tautomeric equilibrium with 2-(alkyl(aryl)imino)thiazolidin-4-ones and the substituent on the exocyclic nitrogen atom governs the ratio of these tautomers. Isomers with the alkyl group in the endocyclic position can be obtained from N-methyl(ethyl)thioureas. 2D NMR spectroscopy and DFT calculations rationalize experimental results. PMID:28144325

  18. Experimental and theoretical studies on the corrosion inhibition of copper by two indazole derivatives in 3.0% NaCl solution.

    Science.gov (United States)

    Qiang, Yujie; Zhang, Shengtao; Xu, Shenying; Li, Wenpo

    2016-06-15

    Corrosion experiments and theoretical calculations were performed to investigate the inhibition mechanism of indazole (IA) and 5-aminoindazole (AIA) for copper in NaCl solution. The results obtained from weight loss and electrochemical experiments are in good agreement, and reveal that these compounds are high-efficiency inhibitors with inhibition efficiency order: AIA>IA, which was further confirmed by field emission scanning electronic microscope (FESEM) observation. Besides, the quantum chemical calculations and molecular dynamics (MD) simulation showed that both studied inhibitors are adsorbed strongly on the copper surface in parallel mode. The adsorption of these molecules on copper substrate was found to obey Langmuir isotherm.

  19. Synthesis, molecular structure (X-ray and DFT), and solution behavior of titanium 4-Acyl-5-pyrazolonates. Correlations with related antitumor beta-diketonato derivatives.

    Science.gov (United States)

    Caruso, Francesco; Pettinari, Claudio; Marchetti, Fabio; Natanti, Paolo; Phillips, Christine; Tanski, Joseph; Rossi, Miriam

    2007-09-03

    Previously reported structure-activity relationships have shown two features for effective antitumor activity of titanium beta-diketone complexes: (a) ligand asymmetry and (b) the presence of planar substitutents on the ligand. Mono- and dinuclear derivatives, studied with diffraction and DFT methods show that (a) is consistent with different Ti-O(beta-diketonato) bond lengths, which are longer than Ti-O(oxo) and Ti-O(alkoxy) ones. pi-pi features observed in dinuclear derivatives correlate with strong reactivity of related complexes with DNA and support DNA intercalation by such planar groups, in agreement with (b). Large variation for Ti-O bond lengths and Ti-O-C bond angles in the ethoxy moiety is associated with the titanium withdrawing effect and oxygen bonding s character; it is confirmed through exploration of the Cambridge crystallographic database. This ethoxy geometrical flexibility also suggests versatile accommodation in protein pockets and/or other biological targets. Electrospray ionization mass spectrometry (ESI-MS) spectra show formation of di- and trinuclear Ti-4-acyl-5-pyrazolonato cationic oligomers. Hydrolysis/oligomerization is also described by NMR results.

  20. Challenges in the Application of Fractional Derivative Models in Capturing Solute Transport in Porous Media: Darcy-Scale Fractional Dispersion and the Influence of Medium Properties

    Directory of Open Access Journals (Sweden)

    Yong Zhang

    2013-01-01

    Full Text Available Heterogeneous media consisting of segregated flow regions are fractional-order systems, where the regional-scale anomalous diffusion can be described by the fractional derivative model (FDM. The standard FDM, however, first, cannot characterize the Darcy-scale dispersion through repacked sand columns, and second, the link between medium properties and model parameters remains unknown. To fill these two knowledge gaps, this study applies a tempered fractional derivative model (TFDM to capture bromide transport through laboratory repacked sand. Column transport experiments are conducted first, where glass beads and silica sand with different diameters are repacked individually. Late-time tails are observed in the breakthrough curves (BTC of bromide even in relatively homogeneous glass beads. The TFDM can capture the observed subdiffusion, especially the late-time BTC with a transient declining rate. Results also show that both the size distribution of repacked sand and the magnitude of fluid velocity can affect subdiffusion. In particular, a wider sand size distribution or a smaller flow rate can enhance the subdiffusion, leading to a smaller time index and a higher truncation parameter in the TFDM. Therefore, the Darcy-scale dispersion follows the tempered stable law, and the model parameters might be related to the soil size and flow conditions.

  1. Imperfect DNA lesion repair in the semiconservative quasispecies model: Derivation of the Hamming class equations and solution of the single-fitness peak landscape

    Science.gov (United States)

    Tannenbaum, Emmanuel; Sherley, James L.; Shakhnovich, Eugene I.

    2004-12-01

    This paper develops a Hamming class formalism for the semiconservative quasispecies equations with imperfect lesion repair, first presented and analytically solved in Y. Brumer and E.I. Shakhnovich (q-bio.GN/0403018, 2004). Starting from the quasispecies dynamics over the space of genomes, we derive an equivalent dynamics over the space of ordered sequence pairs. From this set of equations, we are able to derive the infinite sequence length form of the dynamics for a class of fitness landscapes defined by a master genome. We use these equations to solve for a generalized single-fitness-peak landscape, where the master genome can sustain a maximum number of lesions and remain viable. We determine the mean equilibrium fitness and error threshold for this class of landscapes, and show that when lesion repair is imperfect, semiconservative replication displays characteristics from both conservative replication and semiconservative replication with perfect lesion repair. The work presented here provides a formulation of the model which greatly facilitates the analysis of a relatively broad class of fitness landscapes, and thus serves as a convenient springboard into biological applications of imperfect lesion repair.

  2. Co-pigmentation of pelargonidin derivatives in strawberry and red radish model solutions by the addition of phenolic fractions from mango peels.

    Science.gov (United States)

    Müller-Maatsch, Judith; Bechtold, Lena; Schweiggert, Ralf M; Carle, Reinhold

    2016-12-15

    Pelargonidin-based colors suffer from notorious instability. A phenolic mango peel extract and defined phenolic fractions thereof were shown to effectively modulate the visible absorption of anthocyanins from strawberry (Fragaria x ananassa Duch.) and red radish (Raphanus sativus L.) by intermolecular co-pigmentation. Consistently, non-acylated pelargonidin derivatives from strawberry exerted significantly greater hyper- and bathochromic spectral shifts than their acylated counterparts from red radish. The addition of low molecular-weight co-pigments such as gallic acid and monogalloyl glucoses to strawberry anthocyanins led to strong hyperchromic shifts from 30% to 48%, while gallotannins (>six galloyl units) exerted smaller co-pigmentation effects (36±2%; Δλmax 13nm), possibly due to steric hindrances. In contrast, penta- and hexa-O-galloyl-glucose induced greatest and most stable co-pigmentation effects (53±2%; Δλmax 13nm). Irrespective of the underlying mechanisms and the responsible compounds, phenolic mango peel extracts might represent suitable color enhancers for coloring foodstuff, particularly for those containing non-acylated pelargonidin derivatives.

  3. Analysis Of Solute Concentration And Concentration Derivative Distribution By Means Of Frameshift Fourier And Other Algorithms Applied To Rayleigh Interferometric And Fresnel Fringe Patterns

    Science.gov (United States)

    Rowe, Arthur J.; Jones, S. W.; Thomas, D.; Harding, Stephen E.

    1989-11-01

    The equilibrium distribution of particles dispersed in an aqueous solute situated in a centrifugal accelerative field is routinely studied by means of an optical trace recorded photographically. Rayleigh interferometric fringe patterns have been widely used to give this trace, in which the displacement of the parallel fringes is directly related to particle concentration differences. We have developed a simple but highly efficient frameshift algorithm for automatic interpretation of these patternsl . Results obtained from extensive use and further definition of this algorithm confirm its validity and utility. We have also studied algorithms for the interpretation of Fresnel fringe patterns yielded by an alternative optical system. These more complex patterns involving non parallel fringes can be analysed successfully, subject to certain conditions, with a precision similar to that obtained using Rayleigh interference optics.

  4. Adsorption Kinetics for the Removal of Fluoride from Aqueous Solution by Activated Carbon Adsorbents Derived from the Peels of Selected Citrus Fruits

    Directory of Open Access Journals (Sweden)

    C. Chakrapani

    2010-01-01

    Full Text Available Activated carbons (ACs were prepared from the peels of Citrus documana, Citrus medica and Citrus aurantifolia fruits. Adsorption of fluoride onto these activated carbons was investigated. Effect of contact time in the removal of fluoride from aqueous solution at neutral pH was studied. Five kinetic models; the pseudo first- and second-order equations, intraparticle diffusion, pore diffusion and the Elovich equation, were selected to follow adsorption process. Adsorption of fluoride onto adsorbents could be described by pseudo second-order equation. Kinetic parameters; rate constants, equilibrium adsorption capacities and correlation coefficients, for each kinetic equation were calculated and discussed. The good fitting of kinetic data to pore diffusion and Elovich equations indicate that pore diffusion plays a vital role in controlling the rate of the reaction.

  5. Alternative Donor--Acceptor Stacks from Crown Ethers and Naphthalene Diimide Derivatives: Rapid, Selective Formation from Solution and Solid State Grinding

    Energy Technology Data Exchange (ETDEWEB)

    Advanced Light Source; Liu, Yi; Klivansky, Liana; Cao, Dennis; Snauko, Marian; Teat, Simon J.; Struppe, Jochem O.; Koshkakaryan, Gayane

    2009-01-22

    Self assembling {pi}-conjugated molecules into ordered structures are of increasing interest in the field of organic electronics. One particular example is charge transfer complexes containing columnar alternative donor-acceptor (ADA) stacks, where neutral and ionic ground states can be readily tuned to modulate electrical, optical, and ferroelectrical properties. Aromatic-aromatic and charge transfer interactions have been the leading driving forces in assisting the self-assembly of ADA stacks. Various folding structures containing ADA stacks were assembled in solution with the aid of solvophobic or ion-binding interactions. Meanwhile, examples of solid ADA stacks, which are more appealing for practical use in devices, were obtained from cocrystalization of binary components or mesophase assembly of liquid crystals in bulk blends. Regardless of these examples, faster and more controllable approaches towards precise supramolecular order in the solid state are still highly desirable.

  6. Synthesis of novel palladium(II) complexes with oxalic acid diamide derivatives and their interaction with nucleosides and proteins. Structural, solution, and computational study.

    Science.gov (United States)

    Mrkalić, Emina M; Jelić, Ratomir M; Klisurić, Olivera R; Matović, Zoran D

    2014-10-28

    Novel palladium complexes, KH[Pd(obap)]2·3H2O (3) with oxamido-N-aminopropyl-N'-benzoic acid and [Pd(apox)] (4) with N,N'-bis(3-aminopropyl)ethanediamide, were synthesized. Exhaustive synthetic, solution and structural studies of the two Pd(ii) complexes are reported. The binary and ternary systems of the Pd(ii) ion with H2apox or H3obap as primary ligands and nucleosides (Ado or Cyt) as secondary ligands, are investigated in order to better understand their equilibrium chemistry. The relative stabilities of the ternary complexes are determined and compared with those of the corresponding binary complexes in terms of their Δlog K values. The species distribution of all complexes in solution is evaluated. Fluorescence spectroscopy data shows that the fluorescence quenching of HSA is a result of the formation of the [PdL]-HSA complex. The structure of complex 3 is confirmed using X-ray crystallography. The results are compared to those obtained for palladium complexes of similar structures. Density functional theory (DFT) has been applied for modelling and energetic analysis purposes. The nature of the Pd-N(O) bond interaction is analyzed using NBO. We report here docking simulation experiments in order to predict the most probable mechanism of pro-drug-action. The next free binding energy order of the best scores from the [PdL]-DNA docking simulations, cis-[Pt(NH3)2(H2O)2](2+) > [Pd(obap)] > [Pd(mda)], has been observed in the case of DNA alteration. For the ER and cytosolic stress mechanisms the results of the docking simulations to the chaperons Grp78 and Hsc70 are promising for possible applications as potent protein inhibitors (Ki of [Pd(mda)]/GRP78 being ∼66 μM and Ki for [Pd(obap)]/HSC70 being 14.39 μM).

  7. Improved identification of the solution space of aerosol microphysical properties derived from the inversion of profiles of lidar optical data, part 2: simulations with synthetic optical data.

    Science.gov (United States)

    Kolgotin, Alexei; Müller, Detlef; Chemyakin, Eduard; Romanov, Anton

    2016-12-01

    We developed a mathematical scheme that allows us to improve retrieval products obtained from the inversion of multiwavelength Raman/HSRL lidar data, commonly dubbed "3 backscatter+2 extinction" (3β+2α) lidar. This scheme works independently of the automated inversion method that is currently being developed in the framework of the Aerosol-Cloud-Ecosystem (ACE) mission and which is successfully applied since 2012 [Atmos. Meas. Tech.7, 3487 (2014)10.5194/amt-7-3487-2014; "Comparison of aerosol optical and microphysical retrievals from HSRL-2 and in-situ measurements during DISCOVER-AQ 2013 (California and Texas)," in International Laser Radar Conference, July 2015, paper PS-C1-14] to data collected with the first airborne multiwavelength 3β+2α high spectral resolution lidar (HSRL) developed at NASA Langley Research Center. The mathematical scheme uses gradient correlation relationships we presented in part 1 of our study [Appl. Opt.55, 9839 (2016)APOPAI0003-693510.1364/AO.55.009839] in which we investigated lidar data products and particle microphysical parameters from one and the same set of optical lidar profiles. For an accurate assessment of regression coefficients that are used in the correlation relationships we specially designed the proximate analysis method that allows us to search for a first-estimate solution space of particle microphysical parameters on the basis of a look-up table. The scheme works for any shape of particle size distribution. Simulation studies demonstrate a significant stabilization of the various solution spaces of the investigated aerosol microphysical data products if we apply this gradient correlation method in our traditional regularization technique. Surface-area concentration can be estimated with an uncertainty that is not worse than the measurement error of the underlying extinction coefficients. The retrieval uncertainty of the effective radius is as large as ±0.07  μm for fine mode particles and approximately

  8. Photo-degradation of basic green 1 and basic red 46 dyes in their binary solution by La2O3-Al2O3nanocomposite using first-order derivative spectra and experimental design methodology.

    Science.gov (United States)

    Fahimirad, Bahareh; Asghari, Alireza; Rajabi, Maryam

    2017-02-10

    In this work, the lanthanum oxide-aluminum oxide (La2O3-Al2O3) nanocomposite is introduced as an efficient photocatalyst for the photo-degradation of the dyes basic green 1 (BG1) and basic red 46 (BR46) in their binary aqueous solution under the UV light irradiation. The properties of this catalyst are determined by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), Brunauer-Emmett-Teller (BET), and UV-visible spectrophotometry. The first-order derivative spectra are used for the simultaneous analysis of the dyes in their binary solution. The screening investigations indicate that five parameters including the catalyst dosage, concentration of the dyes, irradiation time, and solution pH have significant effects on the photo-degradation of the dyes. The effects of these variables together with their interactions in the photo-degradation of the dyes are studied using the Box-Behnken design (BBD). Under the optimum experimental conditions, obtained via the desirability function, the photo-catalytic activities of La2O3-Al2O3 and pure Al2O3 are also investigated. The results obtained show an enhancement in the photo-catalytic activity when La2O3 nanoparticles are loaded on the surface of Al2O3 nanoparticles.

  9. An investigation into the adsorption of thorium(IV) from aqueous solutions by a carboxylate-functionalised graft copolymer derived from titanium dioxide-densified cellulose.

    Science.gov (United States)

    Anirudhan, T S; Sreekumari, S S; Jalajamony, S

    2013-02-01

    The use of a carboxylate-functionalized graft copolymer (PGTDC-COOH) based on titanium dioxide-densified cellulose (TDC) for the removal and recovery of thorium(IV) [Th(IV)] from industrial wastewater is reported in this paper. Infrared spectroscopy and X-ray diffractometer were used to characterize the adsorbent material. Batch equilibrium experiments showed that the adsorbent exhibited 98.6 ± 3.1% adsorption from an initial concentration of 10 mg/L Th(IV) solution at pH 5.0. The sorption kinetics have been analysed by pseudo-first-order and pseudo-second-order kinetic models and the adsorption kinetics was described by pseudo-second-order model. The experimental data obeyed Langmuir isotherm and the maximum monolayer adsorption capacity for Th(IV) was also found to be 92.23 ± 2.4 mg/g at 30 °C. The desorption capacity of HCl concentrations of different strengths ranging from 0.001 to 0.1 M was also studied. Maximum desorption of 98.2 ± 2.8% for Th(IV) occurred with 0.1 M HCl. The adsorption efficiency towards Th(IV) ion removal was tested using artificial sea water. Almost complete removal was possible with 3.5 g of the adsorbent from 1 L of the sea water.

  10. Treatment of a non-azo dye aqueous solution by CWAO in continuous reactor using a Ni catalyst derived from hydrotalcite-like precursor.

    Science.gov (United States)

    Vallet, Ana; Besson, Michèle; Ovejero, Gabriel; García, Juan

    2012-08-15

    Catalytic wet air oxidation (CWAO) of a Basic Yellow 11 (BY11) aqueous solution, chosen as a model of a hardly biodegradable non-azo dye was carried out in a continuous-flow trickle-bed reactor, using nickel supported over hydrotalcite precursor calcined at 550°C. An increase in the reaction temperature (120-180°C), and a decrease in dye concentration (1000-3000 ppm) or liquid flow rate (0.1-0.7 mL min(-1)) enhanced the CWAO performance in a 30 and 19% for the variation of the temperature and concentration respectively. After a small leaching observed within the first hours, the catalyst proved to be very stable during the 65-day reaction. The CWAO process was found to be very efficient, achieving BY11 conversion up to 95% and TOC conversion up to 85% at 0.1 mL min(-1) and 180°C under 5 MPa air.

  11. Removal of Pb(II), Cu(II), and Cd(II) from aqueous solutions by biochar derived from KMnO4 treated hickory wood.

    Science.gov (United States)

    Wang, Hongyu; Gao, Bin; Wang, Shenseng; Fang, June; Xue, Yingwen; Yang, Kai

    2015-12-01

    In this work, a novel approach was developed to prepare an engineered biochar from KMnO4 treated hickory wood through slow pyrolysis (600°C). Characterization experiments with various tools showed that the engineered biochar surface was covered with MnOx ultrafine particles. In comparison to the pristine biochar, the engineered biochar also had more surface oxygen-containing functional groups and much larger surface area. Batch sorption experiments showed that the engineered biochar had strong sorption ability to Pb(II), Cu(II), and Cd(II) with maximum sorption capacities of 153.1, 34.2, and 28.1mg/g, respectively, which were significantly higher than that of the pristine biochar. Batch sorption experiments also showed that the dosage, initial solution pH, and ionic strength affected the removal of the heavy metals by the biochars. The removal of the metals by the engineered biochar was mainly through surface adsorption mechanisms involving both the surface MnOx particles and oxygen-containing groups.

  12. Treatment of a non-azo dye aqueous solution by CWAO in continuous reactor using a Ni catalyst derived from hydrotalcite-like precursor

    Energy Technology Data Exchange (ETDEWEB)

    Vallet, Ana, E-mail: avallet@quim.ucm.es [Grupo de Catalisis y Procesos de Separacion (CyPS), Departamento de Ingenieria Quimica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, Avda. Complutense s/n, 28040 Madrid (Spain); Besson, Michele, E-mail: michele.besson@ircelyon.univ-lyon1.fr [IRCELYON, Institut de recherches sur la catalyse et l' environnement de Lyon, UMR5256 CNRS-Universite Lyon1, 2 Avenue Albert Einstein, F-69626 Villeurbanne Cedex (France); Ovejero, Gabriel; Garcia, Juan [Grupo de Catalisis y Procesos de Separacion (CyPS), Departamento de Ingenieria Quimica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, Avda. Complutense s/n, 28040 Madrid (Spain)

    2012-08-15

    Highlights: Black-Right-Pointing-Pointer Ni supported over hydrotalcite calcined precursors as catalyst. Black-Right-Pointing-Pointer Catalytic wet air oxidation in trickle bed reactor for Basic Yellow 11 removal. Black-Right-Pointing-Pointer Dye removal depends on temperature, initial dye concentration and flow rate. Black-Right-Pointing-Pointer The catalyst proved to be stable and efficient for the dye degradation. - Abstract: Catalytic wet air oxidation (CWAO) of a Basic Yellow 11 (BY11) aqueous solution, chosen as a model of a hardly biodegradable non-azo dye was carried out in a continuous-flow trickle-bed reactor, using nickel supported over hydrotalcite precursor calcined at 550 Degree-Sign C. An increase in the reaction temperature (120-180 Degree-Sign C), and a decrease in dye concentration (1000-3000 ppm) or liquid flow rate (0.1-0.7 mL min{sup -1}) enhanced the CWAO performance in a 30 and 19% for the variation of the temperature and concentration respectively. After a small leaching observed within the first hours, the catalyst proved to be very stable during the 65-day reaction. The CWAO process was found to be very efficient, achieving BY11 conversion up to 95% and TOC conversion up to 85% at 0.1 mL min{sup -1} and 180 Degree-Sign C under 5 MPa air.

  13. Inhibition Effects of a Synthesized Novel 4-Aminoantipyrine Derivative on the Corrosion of Mild Steel in Hydrochloric Acid Solution together with Quantum Chemical Studies

    Directory of Open Access Journals (Sweden)

    Abu Bakar Mohamad

    2013-06-01

    Full Text Available 1,5-Dimethyl-4-((2-methylbenzylideneamino-2-phenyl-1H-pyrazol-3(2H-one (DMPO was synthesized to be evaluated as a corrosion inhibitor. The corrosion inhibitory effects of DMPO on mild steel in 1.0 M HCl were investigated using electrochemical impedance spectroscopy (EIS, potentiodynamic polarization, open circuit potential (OCP and electrochemical frequency modulation (EFM. The results showed that DMPO inhibited mild steel corrosion in acid solution and indicated that the inhibition efficiency increased with increasing inhibitor concentration. Changes in the impedance parameters suggested an adsorption of DMPO onto the mild steel surface, leading to the formation of protective films. The novel synthesized corrosion inhibitor was characterized using UV-Vis, FT-IR and NMR spectral analyses. Electronic properties such as highest occupied molecular orbital energy, lowest unoccupied molecular orbital energy (EHOMO and ELUMO, respectively and dipole moment (μ were calculated and discussed. The results showed that the corrosion inhibition efficiency increased with an increase in the EHOMO values but with a decrease in the ELUMO value.

  14. Inhibition effects of a synthesized novel 4-aminoantipyrine derivative on the corrosion of mild steel in hydrochloric acid solution together with quantum chemical studies.

    Science.gov (United States)

    Junaedi, Sutiana; Al-Amiery, Ahmed A; Kadihum, Abdulhadi; Kadhum, Abdul Amir H; Mohamad, Abu Bakar

    2013-06-04

    1,5-Dimethyl-4-((2-methylbenzylidene)amino)-2-phenyl-1H-pyrazol-3(2H)-one (DMPO) was synthesized to be evaluated as a corrosion inhibitor. The corrosion inhibitory effects of DMPO on mild steel in 1.0 M HCl were investigated using electrochemical impedance spectroscopy (EIS), potentiodynamic polarization, open circuit potential (OCP) and electrochemical frequency modulation (EFM). The results showed that DMPO inhibited mild steel corrosion in acid solution and indicated that the inhibition efficiency increased with increasing inhibitor concentration. Changes in the impedance parameters suggested an adsorption of DMPO onto the mild steel surface, leading to the formation of protective films. The novel synthesized corrosion inhibitor was characterized using UV-Vis, FT-IR and NMR spectral analyses. Electronic properties such as highest occupied molecular orbital energy, lowest unoccupied molecular orbital energy (EHOMO and ELUMO, respectively) and dipole moment (μ) were calculated and discussed. The results showed that the corrosion inhibition efficiency increased with an increase in the EHOMO values but with a decrease in the ELUMO value.

  15. Fabrication and icing property of superhydrophilic and superhydrophobic aluminum surfaces derived from anodizing aluminum foil in a sodium chloride aqueous solution

    Science.gov (United States)

    Song, Meirong; Liu, Yuru; Cui, Shumin; Liu, Long; Yang, Min

    2013-10-01

    An aluminum foil with a rough surface was first prepared by anodic treatment in a neutral aqueous solution with the help of pitting corrosion of chlorides. First, the hydrophobic Al surface (contact angle around 79°) became superhydrophilic (contact angle smaller than 5°) after the anodizing process. Secondly, the superhydrophilic Al surface became superhydrophobic (contact angle larger than 150°) after being modified by oleic acid. Finally, the icing property of superhydrophilic, untreated, and superhydrophobic Al foils were investigated in a refrigerated cabinet at -12 °C. The mean total times to freeze a water droplet (6 μL) on the three foils were 17 s, 158 s and 1604 s, respectively. Thus, the superhydrophilic surface accelerates the icing process, while the superhydrophobic surface delays the process. The main reason for this transition might mainly result from the difference of the contact area of the water droplet with Al substrate: the increase in contact area with Al substrate will accelerate the heat conduct process, as well as the icing process; the decrease in contact area with Al substrate will delay the heat conduct process, as well as the icing process. Compared to the untreated Al foil, the contact area of the water droplet with the Al substrate was higher on superhydrophilic surface and smaller on the superhydrophobic surface, which led to the difference of the heat transfer time as well as the icing time.

  16. Effect of electrochemical treatment in H2SO4 aqueous solution on carbon material derived from cellulose with added guanidine phosphate

    Science.gov (United States)

    Tsubota, Toshiki; Wang, Chuanshu; Murakami, Naoya; Ohno, Teruhisa

    2013-03-01

    The electrochemical treatment in a 1 M H2SO4 aqueous solution is applied to the carbon material synthesized from cellulose mixed with guanidine phosphate. The capacitance value increased by the addition of guanidine phosphate; furthermore, the value significantly increased by the electrochemical treatment and was higher than 350 F g-1 at 50 mA g-1. The process used in this study, that is, removing the lignin from wood waste products, such as bamboo, and then mixing with guanidine phosphate before the heat treatment followed by an electrochemical treatment, should be of benefit for the synthesis of a high performance material for the electrodes of electrochemical capacitors. The significant enhancement of the capacitance value appears in the range of 1.5 V∼2.8 V vs. Ag/AgCl for the applied maximum voltage. This voltage range is consistent with the voltage for the significant enhancement of the current value in the CV curve. The change in the capacitance value should be related to the electrochemical reaction of the water electrolysis. The XPS data indicated that the concentrations of both the N atom and the O atom on the surface increased after the electrochemical process.

  17. Implementation and Optimization of DFT-D/COSab with Respect to Basis Set and Functional: Application to Polar Processes of Furfural Derivatives in Solution.

    Science.gov (United States)

    Peverati, Roberto; Baldridge, Kim K

    2009-10-13

    The implementation, optimization, and performance of DFT-D, including the effects of solvation, has been tested on applications of polar processes in solution, where dispersion and hydrogen bonding is known to be involved. Solvent effects are included using our ab initio continuum solvation strategy, COSab, a conductor-like continuum solvation model, modified for ab initio in the quantum chemistry program GAMESS. Structure and properties are investigated across various functionals to evaluate their ability to properly model dispersion and solvation effects. The commonly used S22 set with accurate interaction energies of organic complexes has been used for parametrization studies of dispersion parameters and relevant solvation parameters. Dunning's correlation consistent basis sets, cc-pVnZ (n = D, T), are used in the optimization, together with the Grimme B97-D exchange-correlation functional. Both water (ε = 78.4) and ether (ε = 4.33) environments are considered. Optimized semiempirical dispersion correction parameters and solvent extent radii are proposed for several functionals. We find that special parametrization of the semiempirical dispersion correction when used together in the DFT-D/COSab approach is not necessary. The global performance is quite acceptable in terms of chemical accuracy and suggests that this approach is a reliable as well as economical method for evaluation of solvent effects in systems with dispersive interactions. The resulting theory is applied to a group of push-pull pyrrole systems to illustrate the effects of donor/acceptor and solvation on their conformational and energetic properties.

  18. Mercury(II) removal from aqueous solutions and wastewaters using a novel cation exchanger derived from coconut coir pith and its recovery

    Energy Technology Data Exchange (ETDEWEB)

    Anirudhan, T.S. [Department of Chemistry, University of Kerala, Kariavattom, Trivandrum 695581 (India)], E-mail: tsani@rediffmail.com; Divya, L.; Ramachandran, M. [Department of Chemistry, University of Kerala, Kariavattom, Trivandrum 695581 (India)

    2008-09-15

    A new adsorbent (PGCP-COOH) having carboxylate functional group at the chain end was synthesized by grafting poly(hydroxyethylmethacrylate) onto coconut coir pith, CP (a coir industry-based lignocellulosic residue), using potassium peroxydisulphate as an initiator and in the presence of N,N'-methylenebisacrylamide as a cross-linking agent. The adsorbent was characterized with the help of infrared spectroscopy, powder X-ray diffraction, scanning electron microscopy, and potentiometric titrations. The ability of PGCP-COOH to remove Hg(II) from aqueous solutions was assessed using batch adsorption technique under kinetic and equilibrium conditions. Adsorbent exhibits very high adsorption potential for Hg(II) and more than 99.0% removal was achieved in the pH range 5.5-8.0. Adsorption process was found to follow first-order-reversible kinetics. An increase of ionic strength of the medium caused a decrease in metal removal, indicating the occurrence of outer-sphere surface complex mechanism. The equilibrium data were fitted well by the Freundlich isotherm model (R{sup 2} = 0.99; {chi}{sup 2} 1.81). The removal efficiency was tested using chlor-alkali industry wastewater. Adsorption isotherm experiments were also conducted for comparison using a commercial carboxylate-functionalized ion exchanger, Ceralite IRC-50. Regeneration experiments were tried for four cycles and results indicate a capacity loss of <9.0%.

  19. Mercury(II) removal from aqueous solutions and wastewaters using a novel cation exchanger derived from coconut coir pith and its recovery.

    Science.gov (United States)

    Anirudhan, T S; Divya, L; Ramachandran, M

    2008-09-15

    A new adsorbent (PGCP-COOH) having carboxylate functional group at the chain end was synthesized by grafting poly(hydroxyethylmethacrylate) onto coconut coir pith, CP (a coir industry-based lignocellulosic residue), using potassium peroxydisulphate as an initiator and in the presence of N,N'-methylenebisacrylamide as a cross-linking agent. The adsorbent was characterized with the help of infrared spectroscopy, powder X-ray diffraction, scanning electron microscopy, and potentiometric titrations. The ability of PGCP-COOH to remove Hg(II) from aqueous solutions was assessed using batch adsorption technique under kinetic and equilibrium conditions. Adsorbent exhibits very high adsorption potential for Hg(II) and more than 99.0% removal was achieved in the pH range 5.5-8.0. Adsorption process was found to follow first-order-reversible kinetics. An increase of ionic strength of the medium caused a decrease in metal removal, indicating the occurrence of outer-sphere surface complex mechanism. The equilibrium data were fitted well by the Freundlich isotherm model (R(2)=0.99; chi(2)=1.81). The removal efficiency was tested using chlor-alkali industry wastewater. Adsorption isotherm experiments were also conducted for comparison using a commercial carboxylate-functionalized ion exchanger, Ceralite IRC-50. Regeneration experiments were tried for four cycles and results indicate a capacity loss of <9.0%.

  20. SOMO (SOlution MOdeler) differences between X-Ray- and NMR-derived bead models suggest a role for side chain flexibility in protein hydrodynamics.

    Science.gov (United States)

    Rai, Nithin; Nöllmann, Marcelo; Spotorno, Bruno; Tassara, Giovanni; Byron, Olwyn; Rocco, Mattia

    2005-05-01

    Reduced numbers of frictional/scattering centers are essential for tractable hydrodynamic and small-angle scattering data modeling. We present a method for generating medium-resolution models from the atomic coordinates of proteins, basically by using two nonoverlapping spheres of differing radii per residue. The computed rigid-body hydrodynamic parameters of BPTI, RNase A, and lysozyme models were compared with a large database of critically assessed experimental values. Overall, very good results were obtained, but significant discrepancies between X-ray- and NMR-derived models were found. Interestingly, they could be accounted for by properly considering the extent to which highly mobile surface side chains differently affect translational/rotational properties. Models of larger structures, such as fibrinogen fragment D and citrate synthase, also produced consistent results. Foremost among this method's potential applications is the overall conformation and dynamics of modular/multidomain proteins and of supramolecular complexes. The possibility of merging data from high- and low-resolution structures greatly expands its scope.

  1. Comparison of rice husk- and dairy manure-derived biochars for simultaneously removing heavy metals from aqueous solutions: role of mineral components in biochars.

    Science.gov (United States)

    Xu, Xiaoyun; Cao, Xinde; Zhao, Ling

    2013-08-01

    Rice husk biochar (RHBC) and dairy manure biochar (DMBC) were prepared as sorbents for simultaneously removing Pb, Cu, Zn, and Cd from aqueous solutions. DMBC was more effective in removing all the four heavy metals than RHBC, with the removal capacities of above 486 mmol kg(-1) for each metal, much higher than those of RHBC (65.5-140 mmol kg(-1)). RHBC showed stronger competition for metal removal than DMBC when the four metals coexisted, with Pb the least affected and Cd the most inhibited. When each metal was 1mM in the multi-metal system, the metal removal by RHBC was reduced by 38.4-100%, much higher than that reduced by 2-40.9% for DMBC. The stronger competition for metals removal by RHBC was due to the fact that all metals competed only for the ionized phenolic-O(-) groups, while the removal of metals by DMBC resulted not only from the complexation with ionized hydroxyl-O(-) groups but also from the precipitation of metals with CO3(2-) and/or PO4(3-) that were rich in DMBC, resulting in less competition. The different mechanisms for the removal of metals by the two biochars were evidenced by the instrumental analysis of XRD, FTIR, and SEM as well as chemical modeling of Visual MINTEQ. Results indicated the waste biomass can be converted into value-added biochar as sorbents for removal of heavy metals and the removal ability varies with different biochar feedstock sources where the mineral components such as CO3(2-), PO4(3-) originated from the feedstock play an important role in the sorption nature of biochar.

  2. On Solutions of

    Directory of Open Access Journals (Sweden)

    Schaefer Philip W

    2002-01-01

    Full Text Available Rotationally symmetric solutions are derived for some nonlinear equations of the form in the title in terms of elementary functions. Under suitable assumptions, the nonexistence of entire solutions is also proved for the inequality in the title as well as some radial upper bounds are obtained. These results are the consequence of an appropriate differential inequality.

  3. Surface-enhanced Raman scattering studies on the interaction of phosphonate derivatives of imidazole, thiazole, and pyridine with a silver electrode in aqueous solution.

    Science.gov (United States)

    Podstawka, Edyta; Kudelski, Andrzej; Olszewski, Tomasz K; Boduszek, Bogdan

    2009-07-23

    Surface-enhanced Raman scattering (SERS) spectra from phosphonate derivatives of N-heterocyclic aromatic compounds immobilized on an electrochemically roughened silver electrode surface are reported and compared to Raman spectra of the corresponding solid species. The tested compounds contain imidazole [ImMeP ([hydroxy-(1H-imidazol-5-yl)-methyl]-phosphonic acid) and (ImMe)2P (bis[hydroxy-(1H-imidazol-4-yl)-methyl]-phosphinic acid)]; thiazole [BAThMeP ((butylamino-thiazol-2-yl-methyl)-phosphonic acid) and BzAThMeP ((benzylamino-thiazol-2-yl-methyl)-phosphonic acid)]; and pyridine ((PyMe)2P (bis[(hydroxy-pyridin-3-yl-methyl)]-phosphinic acid) aromatic rings. Changes in wavenumber, broadness, and the enhancement of N-heterocyclic aromatic ring bands upon adsorption are consistent with the adsorption primarily occurring through the N lone pair of electrons with the ring arranged in a largely edge-on manner for ImMeP and BzAThMeP or in a slightly inclined orientation to the silver electrode surface at an intermediate angle from the surface normal for (ImMe)2P, BAThMeP, and (PyMe)2P. A strong enhancement of a roughly 1500 cm(-1) SERS signal for ImMeP and (PyMe)2P is also observed. This phenomenon is attributed to the formation of a localized C=C bond, which is accompanied by a decrease in the ring-surface pi-electrons' overlap. In addition, more intense SERS bands due to the benzene ring in BzAThMeP are observed than those observed for the thiazole ring, which suggests a preferential adsorption of benzene. Some interaction of a phosphonate unit is also suggested but with moderate strength between biomolecules. The strength of the P=O coordination to the silver electrode is highest for ImMeP but lowest for BzAThMeP. For all studied biomolecules, the contribution of the structural components to their ability to interact with their receptors was correlated with the SERS patterns.

  4. Solid State Structure and Solution Thermodynamics of Three-Centered Hydrogen Bonds (O∙∙∙H∙∙∙O Using N-(2-Benzoyl-phenyl Oxalyl Derivatives as Model Compounds

    Directory of Open Access Journals (Sweden)

    Carlos Z. Gómez-Castro

    2014-09-01

    Full Text Available Intramolecular hydrogen bond (HB formation was analyzed in the model compounds N-(2-benzoylphenylacetamide, N-(2-benzoylphenyloxalamate and N1,N2-bis(2-benzoylphenyloxalamide. The formation of three-center hydrogen bonds in oxalyl derivatives was demonstrated in the solid state by the X-ray diffraction analysis of the geometric parameters associated with the molecular structures. The solvent effect on the chemical shift of H6 [δH6(DMSO-d6–δH6(CDCl3] and Δδ(ΝΗ/ΔT measurements, in DMSO-d6 as solvent, have been used to establish the energetics associated with intramolecular hydrogen bonding. Two center intramolecular HB is not allowed in N-(2-benzoylphenylacetamide either in the solid state or in DMSO-d6 solution because of the unfavorable steric effects of the o-benzoyl group. The estimated ΔHº and ΔSº values for the hydrogen bonding disruption by DMSO-d6 of 28.3(0.1 kJ·mol−1 and 69.1(0.4 J·mol−1·K−1 for oxalamide, are in agreement with intramolecular three-center hydrogen bonding in solution. In the solid, the benzoyl group contributes to develop 1-D and 2-D crystal networks, through C–H∙∙∙A (A = O, π and dipolar C=O∙∙∙A (A = CO, π interactions, in oxalyl derivatives. To the best of our knowledge, this is the first example where three-center hydrogen bond is claimed to overcome steric constraints.

  5. 芳香植物源营养液对梨树的抑菌和营养效应%Effect of Aromatic Plant-Derived Nutrient Solution on Inhibition of Harmful Bacteria and Nutrition for Pear Plants

    Institute of Scientific and Technical Information of China (English)

    刘艳娜; 崔楠楠; 张杰; 于凤鸣; 张立彬; 姚允聪

    2011-01-01

    [目的]为有机果品生产提供一种制作简便、成本低廉的芳香植物源营养抑菌制剂的制作方法,探讨喷施该营养液对梨树的抑菌和营养效应.[方法]以芳香植物孔雀草、紫苏、神香草、薄荷、香矢车菊地上部分为材料,经发酵制成营养液,以分别喷施上述5种芳香植物源营养液(Tr1-Tr5)、5种植物的混合营养液(Tr6)为处理,喷施南国春氨基酸叶面肥( Tr7)和清水(Tr8)为对照(CK),检测其对二年生盆栽南水梨/杜梨幼树黑星病、轮纹病、腐烂病的抑菌效果及营养生长、叶片养分含量的效果.[结果]芳香植物源营养液田间叶面喷施和实验室抑菌试验均对梨树黑星病、轮纹病和腐烂病有显著的抑菌效果;田间叶面喷施5种芳香植物源营养液与南国春氨基酸叶面肥均能显著地促进新梢生长,提高叶面积,提高叶片矿质元素含量(除P元素外);其中喷施神香草营养液(Tr3)对于南水梨幼树生长发育的促进作用较显著;喷施孔雀草营养液(Tr1)和薄荷营养液(Tr4)对梨树病害的抑制效果较显著.[结论]田间叶面喷施芳香植物源营养液能够提高梨叶片养分含量,改善营养生长状况,有效抑制梨黑星病、轮纹病、腐烂病害的发生.%[Objective] The objective of this study is to provide a simple, low cost, and effective plant nutrition agent for organic fruit production and explore the bacteriostat effects of aromatic plant-derived nutrient solution on Venturia pirina Aderh, Pnysalospora pinicola Nose and Valisa mali vegetative growth and blade nutrient content. [ Method ] Biennial potted nanshui pear Pyrus pyrifolia (Burm. F.) Nakai/Pyras betulaefolia Bunge trees were selected as materials for treatments of foliar application with plant-derived nutrient solutions. The treatments were Tagetes patula (Trl), Perilla frutescens (Tr2), Hyssopus officinalis (Tr3), Mentha canadensis (Tr4), Centaurea cyanu (Tr5), as well as their

  6. Synthesis, structural characterization, solution behavior, and in vitro antiproliferative properties of a series of gold complexes with 2-(2'-pyridyl)benzimidazole as ligand: comparisons of gold(III) versus gold(I) and mononuclear versus binuclear derivatives.

    Science.gov (United States)

    Serratrice, Maria; Cinellu, Maria A; Maiore, Laura; Pilo, Maria; Zucca, Antonio; Gabbiani, Chiara; Guerri, Annalisa; Landini, Ida; Nobili, Stefania; Mini, Enrico; Messori, Luigi

    2012-03-05

    A variety of gold(III) and gold(I) derivatives of 2-(2'-pyridyl)benzimidazole (pbiH) were synthesized and fully characterized and their antiproliferative properties evaluated in a representative ovarian cancer cell line. The complexes include the mononuclear species [(pbi)AuX(2)] (X = Cl, 1; OAc, 2), [(pbiH)AuCl] (3), [(pbiH)Au(PPh(3))][PF(6)] (4-PF(6)), and [(pbi)Au(L)] (L = PPh(3), 5; TPA, 6), and the binuclear gold(I)/gold(I) and gold(I)/gold(III) derivatives [(PPh(3))(2)Au(2)(μ(2)-pbi)][PF(6)] (10-PF(6)), [ClAu(μ(3)-pbi)AuCl(2)] (7),and [(PPh(3))Au(μ(3)-pbi)AuX(2)][PF(6)] (X = Cl, 8-PF(6); OAc, 9-PF(6)). The molecular structures of 6, 7, and 10-PF(6) were determined by X-ray diffraction analysis. The chemical behavior of these compounds in solution was analyzed both by cyclic voltammetry in DMF and absorption UV-vis spectroscopy in an aqueous buffer. Overall, the stability of these gold compounds was found to be acceptable for the cellular studies. For all complexes, relevant antiproliferative activities in vitro were documented against A2780 human ovarian carcinoma cells, either resistant or sensitive to cisplatin, with IC(50) values falling in the low micromolar or even in the nanomolar range. The investigated gold compounds were found to overcome resistance to cisplatin to a large degree. Results are interpreted and discussed in the frame of current knowledge on cytotoxic and antitumor gold compounds.

  7. Influence of pyrazole derivatives in I{sup -}/I{sub 3}{sup -} redox electrolyte solution on Ru(II)-dye-sensitized TiO{sub 2} solar cell performance

    Energy Technology Data Exchange (ETDEWEB)

    Kusama, Hitoshi; Arakawa, Hironori [Photoreaction Control Research Center (PCRC), National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565 (Japan)

    2005-01-31

    The influence of pyrazole additives in an I{sup -}/I{sub 3}{sup -} redox electrolyte solution on the performance of a bis(tetrabutylammonium)cis-bis(thiocyanato)bis(2,2'-bipyridine-4-carboxylic acid, 4'-carboxylate)ruthenium(II) (N719) dye-sensitized TiO{sub 2} solar cell was studied. The current-voltage characteristics of the cell were measured using 18 different pyrazole derivatives. All of the pyrazole additives enhanced the open-circuit photovoltage (V{sub oc}) and the solar energy conversion efficiency ({eta}), but reduced the short-circuit photocurrent density (J{sub sc}). Most of the pyrazoles improved fill factor (ff). The physical and chemical properties of the pyrazoles were computationally calculated in order to elucidate the reasons for the additive effects on cell performance. The greater the partial charge of the nitrogen atom at position 2 in the pyrazole group, the larger the V{sub oc,} but the smaller the J{sub sc} values. As the dipole moment of the pyrazole derivatives increased, the V{sub oc} value increased, but the J{sub sc} value decreased. The V{sub oc} of the cell also increased as the ionization energy of the pyrazoles decreased. These results suggest that the electron donicity of the pyrazole additives affected the interaction with the nanocrystalline TiO{sub 2} photoelectrode, the I{sup -}/I{sub 3}{sup -} electrolyte, and the acetonitrile solvent, which changed the Ru(II)-dye-sensitized solar cell performance.

  8. Nuclear magnetic resonance solution structure of an N(2)-guanine DNA adduct derived from the potent tumorigen dibenzo[a,l]pyrene: intercalation from the minor groove with ruptured Watson-Crick base pairing.

    Science.gov (United States)

    Tang, Yijin; Liu, Zhi; Ding, Shuang; Lin, Chin H; Cai, Yuqin; Rodriguez, Fabian A; Sayer, Jane M; Jerina, Donald M; Amin, Shantu; Broyde, Suse; Geacintov, Nicholas E

    2012-12-04

    The most potent tumorigen identified among the polycyclic aromatic hydrocarbons (PAH) is the nonplanar fjord region dibenzo[a,l]pyrene (DB[a,l]P). It is metabolically activated in vivo through the widely studied diol epoxide (DE) pathway to form covalent adducts with DNA bases, predominantly guanine and adenine. The (+)-11S,12R,13R,14S DE enantiomer forms adducts via its C14 position with the exocyclic amino group of guanine. Here, we present the first nuclear magnetic resonance solution structure of a DB[a,l]P-derived adduct, the 14R-(+)-trans-anti-DB[a,l]P-N(2)-dG (DB[a,l]P-dG) lesion in double-stranded DNA. In contrast to the stereochemically identical benzo[a]pyrene-derived N(2)-dG adduct (B[a]P-dG) in which the B[a]P rings reside in the B-DNA minor groove on the 3'-side of the modifed deoxyguanosine, in the DB[a,l]P-derived adduct the DB[a,l]P rings intercalate into the duplex on the 3'-side of the modified base from the sterically crowded minor groove. Watson-Crick base pairing of the modified guanine with the partner cytosine is broken, but these bases retain some stacking with the bulky DB[a,l]P ring system. This new theme in PAH DE-DNA adduct conformation differs from (1) the classical intercalation motif in which Watson-Crick base pairing is intact at the lesion site and (2) the base-displaced intercalation motif in which the damaged base and its partner are extruded from the helix. The structural considerations that lead to the intercalated conformation of the DB[a,l]P-dG lesion in contrast to the minor groove alignment of the B[a]P-dG adduct, and the implications of the DB[a,l]P-dG conformational motif for the recognition of such DNA lesions by the human nucleotide excision repair apparatus, are discussed.

  9. Growth of ferroelectric Ba{sub 0.8}Sr{sub 0.2}TiO{sub 3} epitaxial films by ultraviolet pulsed laser irradiation of chemical solution derived precursor layers

    Energy Technology Data Exchange (ETDEWEB)

    Queraltó, A.; Pérez del Pino, A., E-mail: aperez@icmab.es; Mata, M. de la; Tristany, M.; Gómez, A.; Obradors, X.; Puig, T. [Institut de Ciència de Materials de Barcelona, Consejo Superior de Investigaciones Científicas (ICMAB-CSIC), Campus UAB, 08193 Bellaterra, Catalonia (Spain); Arbiol, J. [Institut de Ciència de Materials de Barcelona, Consejo Superior de Investigaciones Científicas (ICMAB-CSIC), Campus UAB, 08193 Bellaterra, Catalonia (Spain); Institució Catalana de Recerca i Estudis Avançats (ICREA), Passeig Lluís Companys, 23, 08010 Barcelona, Catalonia (Spain)

    2015-06-29

    Highly crystalline epitaxial Ba{sub 0.8}Sr{sub 0.2}TiO{sub 3} (BST) thin-films are grown on (001)-oriented LaNiO{sub 3}-buffered LaAlO{sub 3} substrates by pulsed laser irradiation of solution derived barium-zirconium-titanium precursor layers using a UV Nd:YAG laser source at atmospheric conditions. The structural analyses of the obtained films, studied by X-ray diffractometry and transmission electron microscopy, demonstrate that laser processing allows the growth of tens of nm-thick BST epitaxial films with crystalline structure similar to that of films obtained through conventional thermal annealing methods. However, the fast pulsed nature of the laser employed leads to crystallization kinetic evolution orders of magnitude faster than in thermal treatments. The combination of specific photothermal and photochemical mechanisms is the main responsible for the ultrafast epitaxial laser-induced crystallization. Piezoresponse microscopy measurements demonstrate equivalent ferroelectric behavior in laser and thermally annealed films, being the piezoelectric constant ∼25 pm V{sup −1}.

  10. Existence of noncontinuable solutions

    Directory of Open Access Journals (Sweden)

    Miroslav Bartusek

    2007-02-01

    Full Text Available This paper presents necessary and sufficient conditions for an n-th order differential equation to have a non-continuable solution with finite limits of its derivatives up to the orders n-2 at the right-hand end point of the definition interval.

  11. Multi-angle inversion of formation densities based on the accurate solutions of Zoeppritz's partial derivative equations%基于Zoeppritz偏导方程精确解的地层密度多角度反演

    Institute of Scientific and Technical Information of China (English)

    刘福平; 孟宪军; 王玉梅; 慎国强; 肖加奇

    2012-01-01

    基于Zoeppritz方程对介质密度偏导数所建立的偏导方程的精确解,构造了多角度反演地层介质密度的反演方程,在偏导数求解过程中考虑了介质密度对波速度的影响因素,并由此实现了利用反射系数梯度精确解计算地层密度的多角度联合反演.通过数值算例考察了计算方法,结果显示:反演方法对层状地层模型不论反射波是否存在相干现象均获得了较好的反演结果,反演迭代10次后计算结果的最大相对误差能够收敛到1%之内;随着反演角度的增加地层介质密度反演的精度逐步提高,反演具有自动校正能力,有快的计算速度.本方法克服了传统AVO(Amplitude Versus Offset)基于Zoeppritz方程近似所遇到的困难,不受反演角度大小及反射界面对波反射强弱的限制,为地层介质密度的多角度包括大角度反演提供了一种新的快速有效的计算方法.%Based on the accurate solutions of Zoeppritz's partial derivative equations, which is the derivative equations of Zoeppritz equations with respect to densities of formation, we have constructed the multi-angle inverse equations for inversion of formation densities, and realized the multi-angle inversion of formation densities with the accurate solution of reflected coefficient's grads of seismic wave. We have also given numerical examples for different stratum models. The results show that whether there is interference between two reflected waves from different reflection interfaces or not, the precisions of inverse results are very good, if only the iterative times of inversion are over 10, the largest relative error of inverse results is less than 1%; with the increasing of inverse angles the precision of multi-angle inverse results is gradually improved; the inversion has emending function itself, and has high running speeds. This method has overcome the difficulty that conventional AVO( Amplitude Versus Offset) approximate methods are

  12. Compatible Solutes Ectoine and Its Derivate Hydroxyectoine%相容性溶质四氢嘧啶及其羟基化衍生物的研究进展

    Institute of Scientific and Technical Information of China (English)

    朱道辰; 刘杏荣

    2011-01-01

    四氢嘧啶类化合物是嗜盐以及耐盐菌胞内合成的一类能够抵御外界高盐胁迫的相容性溶质,概述了四氢嘧啶及其衍生物的理化特征以及在嗜盐微生物中抵御外界高渗透压的作用机理.主要阐述了四氢嘧啶类相容性溶质的生物合成途径、膜运输机理、分泌释放机制、高密度发酵生产等方面在细胞、分子水平上的最新研究进展以及前景展望.并且综述了四氢嘧啶类在精细化工、生物医药及生物制造等行业的应用研究以及发展前景,探讨了未来的研究方向.%Ectoine and its derivatives are de novo synthesized by halophilic or halotolerant bacteria as compatible solutes. The characteristic of ectoines in biochemical and physiological role of osmotic stress defence in microorganisms was introduced, the protective properties of ectoines for cells were descirbed and transferred to enzyme, nucleic acid, and human skin ete. Data were analyzed and summarized in the synthesis pathway of ectoines and transporters system in the halophilic bacteria on the cell and molecular level, and the production of ectoines by halophic bacteria was described, such as downshock and milking process. In addition, the applications of ectoines were also summarized, which would be useful in the field of biology industry, medicine treatment and cosmetic for prevent aging of skin etc.

  13. Survival in a rat model of lethal hemorrhagic shock is prolonged following resuscitation with a small volume of a solution containing a drag-reducing polymer derived from aloe vera.

    Science.gov (United States)

    Macias, Carlos A; Kameneva, Marina V; Tenhunen, Jyrki J; Puyana, Juan-Carlos; Fink, Mitchell P

    2004-08-01

    Drag-reducing polymers (DRP) increase tissue perfusion at constant driving pressure. We sought to evaluate the effects of small-volume resuscitation with a solution containing a DRP in a rat model of hemorrhage. Anesthetized rats were hemorrhaged at a constant rate over 25 min. In protocol A, total blood loss was 2.45 mL/100 g, whereas in protocol B, total blood loss was 3.15 mL/100 g. Five minutes after hemorrhage, the animals were resuscitated with 7 mL/kg of either normal saline (NS) or NS containing 50 microg/mL of an aloe vera-derived DRP. In protocol B, a third group (CON) was not resuscitated. Whole-body O2 consumption (Vo2) and CO2 production (Vco2) were measured using indirect calorimetry. In protocol A, 5/10 rats in the NS group and 8/10 rats in the DRP group survived for 4 h (P = 0.14). Mean arterial pressure was higher in the DRP-treated group than in the NS-treated group 45 min after resuscitation (89 +/- 8 vs. 68 +/- 5 mmHg, respectively; P < 0.05). In protocol B, survival rates over 2 h in the DRP, NS, and CON groups were 5/15, 1/14, and 0/7, respectively (P < 0.05). Compared with NS-treated rats, those resuscitated with DRP achieved a higher peak Vo2 (9.0 +/- 1.0 vs. 6,3+/- 1.0 mL/kg/min) and Vco2 (9.0 +/- 1.1 vs. 6.0 +/- 1.0 mL/kg/min) after resuscitation. We conclude that resuscitation with a small volume of DRP prolongs survival in rats with lethal hemorrhagic shock.

  14. Hemoglobin derivatives

    Science.gov (United States)

    ... this page: //medlineplus.gov/ency/article/003371.htm Hemoglobin derivatives To use the sharing features on this page, please enable JavaScript. Hemoglobin derivatives are altered forms of hemoglobin . Hemoglobin is ...

  15. Exact solution for generalized pairing

    OpenAIRE

    Pan, Feng; J.P. Draayer

    1997-01-01

    An infinite dimensional algebra, which is useful for deriving exact solutions of the generalized pairing problem, is introduced. A formalism for diagonalizing the corresponding Hamiltonian is also proposed. The theory is illustrated with some numerical examples.

  16. Nuclear magnetic resonance studies of an N2-guanine adduct derived from the tumorigen dibenzo[a,l]pyrene in DNA: impact of adduct stereochemistry, size, and local DNA sequence on solution conformations.

    Science.gov (United States)

    Rodríguez, Fabián A; Liu, Zhi; Lin, Chin H; Ding, Shuang; Cai, Yuqin; Kolbanovskiy, Alexander; Kolbanovskiy, Marina; Amin, Shantu; Broyde, Suse; Geacintov, Nicholas E

    2014-03-25

    The dimensions and arrangements of aromatic rings (topology) in adducts derived from the reactions of polycyclic aromatic hydrocarbon (PAH) diol epoxide metabolites with DNA influence the distortions and stabilities of double-stranded DNA, and hence their recognition and processing by the human nucleotide excision repair (NER) system. Dibenzo[a,l]pyrene (DB[a,l]P) is a highly tumorigenic six-ring PAH, which contains a nonplanar and aromatic fjord region that is absent in the structurally related bay region five-ring PAH benzo[a]pyrene (B[a]P). The PAH diol epoxide-DNA adducts formed include the stereoisomeric 14S and 14R trans-anti-DB[a,l]P-N(2)-dG and the stereochemically analogous 10S- and 10R-B[a]P-N(2)-dG (B[a]P-dG) guanine adducts. However, nuclear magnetic resonance (NMR) solution studies of the 14S-DB[a,l]P-N(2)-dG adduct in DNA have not yet been presented. Here we have investigated the 14S-DB[a,l]P-N(2)-dG adduct in two different sequence contexts using NMR methods with distance-restrained molecular dynamics simulations. In duplexes with dC opposite the adduct deleted, a well-resolved base-displaced intercalative adduct conformation can be observed. In full duplexes, in contrast to the intercalated 14R stereoisomeric adduct, the bulky DB[a,l]P residue in the 14S adduct is positioned in a greatly widened and distorted minor groove, with significant disruptions and distortions of base pairing at the lesion site and two 5'-side adjacent base pairs. These unique structural features are significantly different from those of the stereochemically analogous but smaller B[a]P-dG adduct. The greater size and different topology of the DB[a,l]P aromatic ring system lead to greater structurally destabilizing DNA distortions that are partially compensated by stabilizing DB[a,l]P-DNA van der Waals interactions, whose combined effects impact the NER response to the adduct. These structural results broaden our understanding of the structure-function relationship in NER.

  17. Decoupling solution moduli of bigravity

    Science.gov (United States)

    Yılmaz, Nejat Tevfik

    2016-12-01

    A complete classification of exact solutions of ghost-free, massive bigravity is derived which enables the dynamical decoupling of the background, and the foreground metrics. The general decoupling solution space of the two metrics is constructed. Within this branch of the solution space the foreground metric theory becomes general relativity (GR) with an additional effective cosmological constant, and the background metric dynamics is governed by plain GR.

  18. Financial Derivatives

    DEFF Research Database (Denmark)

    Wigan, Duncan

    2013-01-01

    Contemporary derivatives mark the development of capital and constitute a novel form of ownership. By reconfiguring the temporal, spatial and legal character of ownership derivatives present a substantive challenge to the tax collecting state. While fiscal systems are nationally bounded and inheren...... and inherently static, capital itself is unprecedentedly mobile, fluid and fungible. As such derivatives raise the specter of ‘financial weapons of mass destruction’....

  19. Kinetic and analytical study on precipitation reactions with /sup 110/AgNO/sub 3/ of some di(. beta. -chloroethyl)amine derivatives and hydrochlorides with esters of N-(p-aminobenzoyl)-L-aspartic acid as carriers from dimethylformamide - water solution

    Energy Technology Data Exchange (ETDEWEB)

    Cecal, Al.; Sunel, V.; Ghimiciu, L. (Institutul Politehnic, Iasi (Romania))

    1983-01-01

    The kinetics of precipitation reactions with /sup 110/AgNO/sub 3/ of some di(..beta..-chloroethyl) amine derivates and hydrochlorides with esters of N-(p-aminobenzoyl)-L-aspartic acid as carriers in dimethylformamide-water mixture, were studied. The rate constants of these reactions were of the order of 10/sup -4/ lxmol/sup -1/xmin/sup -1/. The concentrations of the corresponding hydrochloride solutions were measured by radiometric titration with /sup 110/AgNO/sub 3/ solution of given concentration.

  20. New double Wronskian solutions of the AKNS equation

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Soliton solutions, rational solutions, Matveev solutions, complexitons and interaction solutions of the AKNS equation are derived through a matrix method for constructing double Wronskian entries. The latter three solutions are novel. Moreover, rational solutions of the nonlinear Schr(o)dinger equation are obtained by reduction.

  1. New double Wronskian solutions of the AKNS equation

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Soliton solutions, rational solutions, Matveev solutions, complexitons and interaction solutions of the AKNS equation are derived through a matrix method for constructing double Wronskian entries. The latter three solutions are novel. Moreover, rational solutions of the nonlinear Schrodinger equation are obtained by reduction.

  2. Numerical Solutions of Fractional Boussinesq Equation

    Institute of Scientific and Technical Information of China (English)

    WANG Qi

    2007-01-01

    Based upon the Adomian decomposition method,a scheme is developed to obtain numerical solutions of a fractional Boussinesq equation with initial condition,which is introduced by replacing some order time and space derivatives by fractional derivatives.The fractional derivatives are described in the Caputo sense.So the traditional Adomian decomposition method for differential equations of integer order is directly extended to derive explicit and numerical solutions of the fractional differential equations.The solutions of our model equation are calculated in the form of convergent series with easily computable components.

  3. Hyperscaling Violating Solutions in Generalised EMD Theory

    CERN Document Server

    Li, Li

    2016-01-01

    This short note is devoted to deriving scaling but hyperscaling violating solutions in a generalised Einstein-Maxwell-Dilaton theory with an arbitrary number of scalars and vectors. We obtain analytic solutions in some special case and discuss the physical constraints on the allowed parameter range in order to have a well-defined holographic ground-state solution.

  4. Explicit solutions of Boussinesq-Burgers equation

    Institute of Scientific and Technical Information of China (English)

    Wang Zheng-Yan; Chen Ai-Hua

    2007-01-01

    Darboux transformation with multi-parameters for the Boussinesq-Burgers (B-B) equation is derived. For an application, some important explicit solutions of the B-B equation are obtained, including 2N-soliton solution and periodic solution. Finally, some elegant and interesting figures are plotted.

  5. Soil Solution

    NARCIS (Netherlands)

    Sonneveld, C.; Voogt, W.

    2009-01-01

    The characteristics of the soil solution in the root environment in the greenhouse industry differ much from those for field grown crops. This is caused firstly by the growing conditions in the greenhouse, which strongly differ from those in the field and secondly the function attributed to the soil

  6. Plugging solution

    Energy Technology Data Exchange (ETDEWEB)

    Tomashevskiy, L.P.; Boldin, V.M.; Borovikov, P.A.; Fedorova, G.G.; Koshelova, I.F.; Krivoshchekova, N.P.; Prokhorevich, L.D.; Prudnikova, N.N.; Vin, L.R.

    1982-01-01

    This solution is designed to quickly harden in a cool environment. Phenoformaldyhyde tar is used as a hardening agent along with a modified diethyleneglycol in the amounts of (part by weight): phenoformaldyhyde tar and diethyleneglycol=1oo; acidic hardener=8-16; water=2-4.

  7. Podcast solutions

    CERN Document Server

    Geoghegan, Michael W

    2005-01-01

    Podcasting is the art of recording radio show style audio tracks, then distributing them to listeners on the Web via podcasting software such as iPodder. From downloading podcasts to producing a track for fun or profit, ""Podcast Solutions"" covers the entire world of podcasting with insight, humor, and the unmatched wisdom of experience.

  8. PACSPLUS Solutions

    Directory of Open Access Journals (Sweden)

    Reza A Zoroofi

    2007-08-01

    Full Text Available Medal Electronic (ME Engineering Company provides high quality systems, software and services in medical image management, processing and visualization. We assist health care professionals to improve and extend the efficiency of their practices with cost effective solutions. ME is the developer of several medical software including MEDAL-PACS, 3D-Sonosoft, Analytical-Electrophoresis, CBONE and Rhino-Plus. ME is also the exclusive distributor of PACSPLUS in Iran. PACSPLUS is an international, standard, scalable and enterprise PACS solution. PACSPLUS is of ISO, CE and FDA-510 approvals. It is now operational in more than 1000 clinical environment throughout the globe. We discuss about the key features of PACSPLUS system for dealing with real world challenge in PACS as well as the PACS solu-tions needed to fulfill the demands of the clinicians in Iran. Our experience in developing high-end medical software confirms our capability in providing the PACSPLUS as an ultimate PACS solution in Iran.

  9. Green Solutions

    Institute of Scientific and Technical Information of China (English)

    LU LING

    2010-01-01

    @@ World Expo's China Pavilion is a large crimson building,but it's green at heart.The pavilion,a magnificent symbol of Chinese culture,is also a "green landmark" on the world stage,thanks to German company Siemens' energy-saving solutions.

  10. Global Derivatives

    DEFF Research Database (Denmark)

    Andersen, Torben Juul

    ." - Steen Parsholt, Chairman and CEO, Aon Nordic Region. "Andersen has done a wonderful job of developing a comprehensive text that deals with risk management in global markets. I would recommend this book to any student or businessman who has a need to better understand the risks and risk management...... management practice. Of particular note is the global and integrated approach chosen in this book which should be of special interest to aspiring managers active in global and international markets." - Dr Jean-Pierre Zigrand, Lecturer in Finance, London School of Economics, UK. More than 90 per cent...... management situations. Its key features include: derivatives are introduced in a global market perspective; describes major derivative pricing models for practical use, extending these principles to valuation of real options; practical applications of derivative instruments are richly illustrated...

  11. Electricity derivatives

    CERN Document Server

    Aïd, René

    2015-01-01

    Offering a concise but complete survey of the common features of the microstructure of electricity markets, this book describes the state of the art in the different proposed electricity price models for pricing derivatives and in the numerical methods used to price and hedge the most prominent derivatives in electricity markets, namely power plants and swings. The mathematical content of the book has intentionally been made light in order to concentrate on the main subject matter, avoiding fastidious computations. Wherever possible, the models are illustrated by diagrams. The book should allow prospective researchers in the field of electricity derivatives to focus on the actual difficulties associated with the subject. It should also offer a brief but exhaustive overview of the latest techniques used by financial engineers in energy utilities and energy trading desks.

  12. Semianalytic Solution of Space-Time Fractional Diffusion Equation

    Directory of Open Access Journals (Sweden)

    A. Elsaid

    2016-01-01

    Full Text Available We study the space-time fractional diffusion equation with spatial Riesz-Feller fractional derivative and Caputo fractional time derivative. The continuation of the solution of this fractional equation to the solution of the corresponding integer order equation is proved. The series solution of this problem is obtained via the optimal homotopy analysis method (OHAM. Numerical simulations are presented to validate the method and to show the effect of changing the fractional derivative parameters on the solution behavior.

  13. Functionalized polymers for binding to solutes in aqueous solutions

    Science.gov (United States)

    Smith, Barbara F.; Robison, Thomas W.

    2006-11-21

    A functionalized polymer for binding a dissolved molecule in an aqueous solution is presented. The polymer has a backbone polymer to which one or more functional groups are covalently linked. The backbone polymer can be such polymers as polyethylenimine, polyvinylamine, polyallylamine, and polypropylamine. These polymers are generally water-soluble, but can be insoluble when cross-linked. The functional group can be for example diol derivatives, polyol derivatives, thiol and dithiol derivatives, guest-host groups, affinity groups, beta-diphosphonic acids, and beta-diamides

  14. Radiative Transfer in spheres I. Analytical Solutions

    CERN Document Server

    Aboughantous, C

    2001-01-01

    A nonsingular analytical solution for the transfer equation in a pure absorber is obtained in central symmetry and in a monochromatic radiation field. The native regular singularity of the equation is removed by applying a linear transformation to the frame of reference. Two different ap-proaches are used to carry out the solution. In the first approach the angular derivative is interpreted in an original way that made it possible to discard this derivative from the equation for all black body media without upsetting the conservation of energy. In this approach the analytic solution is expressible in terms of exponential integrals without approximations but for practical considerations the solution is presented in the form of Gauss-Legendre quadrature for quantitative evaluation of the solutions. In the second approach the angular derivative is approximated by a new set of discrete ordinates that guarantees the closer of the set of equations and the conservation of energy. The solutions from the two approache...

  15. Effective Gravity and Homogenous Solutions

    CERN Document Server

    Müller, Daniel

    2013-01-01

    Near the singularity, gravity should be modified to an effective theory, in the same sense as with the Euler-Heisenberg electrodynamics. This effective gravity surmounts to higher derivative theory, and as is well known, a much more reacher theory concerning the solution space. On the other hand, as a highly non linear theory, the understanding of this solution space must go beyond the linearized approach. In this talk we will present some results previously published by collaborators and myself, concerning solutions for vacuum spatially homogenous cases of Bianchi types $I$ and $VII_A$. These are the anisotropic generalizations of the cosmological spatially "flat", and "open" models respectively. The solutions present isotropisation in a weak sense depending on the initial condition. Also, depending on the initial condition, singular solutions are obtained.

  16. Effective Gravity and Homogenous Solutions

    Science.gov (United States)

    Müller, Daniel

    2015-01-01

    Near the singularity, gravity should be modified to an effective theory, in the same sense as with the Euler-Heisenberg electrodynamics. This effective gravity surmounts to higher derivative theory, and as is well known, a much more reacher theory concerning the solution space. On the other hand, as a highly non linear theory, the understanding of this solution space must go beyond the linearized approach. In this talk we will present some results previously published by collaborators and myself, concerning solutions for vacuum spatially homogenous cases of Bianchi types I and VIIA. These are the anisotropic generalizations of the cosmological spatially "flat", and "open" models respectively. The solutions present isotropisation in a weak sense depending on the initial condition. Also, depending on the initial condition, singular solutions are obtained.

  17. Solution Prototype

    DEFF Research Database (Denmark)

    Efeoglu, Arkin; Møller, Charles; Serie, Michel

    2013-01-01

    environment. The solution prototype that is composed from blending product and service prototype has particular impacts on the dualism of DSR’s “Build” and “Evaluate”. Since the mix between product and service prototyping can be varied, there is a demand for a more agile and iterative framework. Van de Ven’s...... research framework seems to fit this purpose. Van de Ven allows for an iterative research approach to problem solving with flexible starting point. The research activity is the result between the iteration of two dimensions. This framework focuses on the natural evaluation, particularly on ex......-ante validation. A correlation between Hevner’s and Van de Vens framework is analyzed, and finally the proposal is presented....

  18. A physical picture of atomic motions within the Dickerson DNA dodecamer in solution derived from joint ensemble refinement against NMR and large-angle X-ray scattering data.

    Science.gov (United States)

    Schwieters, Charles D; Clore, G Marius

    2007-02-06

    The structure and dynamics of the Dickerson DNA dodecamer [5'd(CGCGAATTCGCG)2] in solution have been investigated by joint simulated annealing refinement against NMR and large-angle X-ray scattering data (extending from 0.25 to 3 A-1). The NMR data comprise an extensive set of hetero- and homonuclear residual dipolar coupling and 31P chemical shift anisotropy restraints in two alignment media, supplemented by NOE and 3J coupling data. The NMR and X-ray scattering data cannot be fully ascribed to a single structure representation, indicating the presence of anisotropic motions that impact the experimental observables in different ways. Refinement with ensemble sizes (Ne) of >or=2 to represent the atomic motions reconciles all the experimental data within measurement error. Cross validation against both the dipolar coupling and X-ray scattering data suggests that the optimal ensemble size required to account for the current data is 4. The resulting ensembles permit one to obtain a detailed view of the conformational space sampled by the dodecamer in solution and permit one to analyze fluctuations in helicoidal parameters, sugar puckers, and BI-BII backbone transitions and to obtain quantitative metrics of atomic motion such as generalized order parameters and thermal B factors. The calculated order parameters are in good agreement with experimental order parameters obtained from 13C relaxation measurements. Although DNA behaves as a relatively rigid rod with a persistence length of approximately 150 bp, dynamic conformational heterogeneity at the base pair level is functionally important since it readily permits optimization of intermolecular protein-DNA interactions.

  19. Equivalence of Network-Solution and PPP-Solution

    Institute of Scientific and Technical Information of China (English)

    PENG Lin; LIU Yanxiong; ZHOU Xinghua; WU Yongting

    2006-01-01

    The technique of precise point positioning (PPP) is gradually becoming a popular method in GPS data-processing. In GPS observation equation, the unknown parameters can be separated into two parts: global parameters and local parameters. The global parameters include orbit, satellite clock and geodynamic parameters. The local parameters are site-occupation-specific, such as position, tropospheric delay, etc. The formulas of local parameters are firstly derived under the network-solution and the PPP-solution conditions respectively. If the weight matrix of global parameters in PPP-solution is small enough, the cofactor matrices of local parameters are the same as that in network-solution. Then, 16 daily solutions are obtained in both PPP mode and network mode. Three sites are selected to compare the solutions. The experimental results demonstrated that the difference between two solutions in coordinates and tropospheric delays are only few millimeters. This level of difference can be neglected so that the solutions from both PPP mode and network mode can be taken as the same in the actual application.

  20. X-ray diffraction, solution structure, and computational studies on derivatives of (3-sec-butyl-2,3-dihydro-1H-isoquinolin-4-ylidene)acetic acid: compounds with activity as calpain inhibitors.

    Science.gov (United States)

    Alonso, Mercedes; Chicharro, Roberto; Miranda, Carlos; Arán, Vicente J; Maestro, Miguel A; Herradón, Bernardo

    2010-01-15

    A thorough experimental and computational study of derivatives of (3-sec-butyl-2,3-dihydroisoquinolin-4-ylidene)acetic acid was performed. Some of these compounds are calpain inhibitors and could be useful as therapeutic agents, since this enzyme is a Ca(2+)-dependent cysteine protease involved in a wide variety of metabolic and physiological processes, whose over-activation is associated to several pathological conditions. To gain a better understanding of the structure-activity relationships, a structural analysis was carried out with (1)H and (13)C NMR spectroscopy and DFT calculations together with the X-ray diffraction data of three compounds. The solid state structures showed that the crystal packing as well as the intermolecular interactions depend on the substituent nature of the COOR group. Also, the reactivity of the exocyclic double bond was theoretically evaluated, finding that the more reactive compound is the most potent inhibitor of calpain (IC(50) = 25 nM).

  1. On the solutions to accelerating cosmologies

    CERN Document Server

    Ito, M

    2003-01-01

    Motivated by recent accelerating cosmological model, we derive the solutions to vacuum Einstein equation in $(d+1)$-dimensional Minkowski space with $n$-dimensional hyperbolic manifold. The conditions of accelerating expansion are given in such a set up.

  2. On Alternative Optimal Solutions to Linear Fractional Optimization Problems

    Institute of Scientific and Technical Information of China (English)

    ShengjiaXue

    2004-01-01

    The structure of the optimal solution set is derived for linear fractional optimization problems with the representation theorem of polyhedral sets.And the computational procedure in determining all optimal solutions is also given.

  3. Crystal growth and dielectric characterization of crystals derived from the solid-solution Ba{sub (1-x)}Na{sub x}Ti{sub (1-x)}Nb{sub x}O{sub 3} (BTNN)

    Energy Technology Data Exchange (ETDEWEB)

    Gacem, Lakhdar [ICMCB-CNRS, Universite de Bordeaux, 87 av. Schweitzer, 33608 Pessac (France); Departement de physique, Universite Mohamed Khider de Biskra, Biskra 07000 (Algeria); Ouadjaout, Djamel [UDTS, 2 Bd. Frantz Fanon, BP. 140 Alger-7 Merveilles, 16200 Alger (Algeria); Chaminade, Jean-Pierre, E-mail: chamin@icmcb-bordeaux.cnrs.fr [ICMCB-CNRS, Universite de Bordeaux, 87 av. Schweitzer, 33608 Pessac (France); Maglione, Mario; Von der Muehll, Regnault; Pechev, Stanislas [ICMCB-CNRS, Universite de Bordeaux, 87 av. Schweitzer, 33608 Pessac (France)

    2009-12-15

    Single crystals of (1 - x)BaTiO{sub 3} + xNaNbO{sub 3} (BTNN) for x = 0.84 were obtained by high temperature solution growth using Na{sub 2}B{sub 4}O{sub 7} as solvent. The room temperature crystal structure of BTNN 16/84-phase was determined from X-ray single crystal diffraction data, in the tetragonal system with space group P4bm. The refinement from 246 independent reflections led to the following parameters: a = b = 5.5845(3) A, c = 3.9453(2) A, V = 123.041(11) A{sup 3}, Z = 2, with final cR{sub wp} = 0.150 and R{sub B} = 0.041. The structure of BTNN 16/84-phase can be described as a three-dimensional framework built up from (Nb-Ti)O{sub 6} octahedra with Na and Ba in the dodecahedral site of perovskite-like type. Some mm{sup 3}-sized crystals have been selected and various dielectric measurements (ferroelectric, pyroelectric, and piezoelectric) have been performed. Transition from paraelectric to ferroelectric state at around 460 K has been observed to be in good agreement with ceramics of closer composition. Dielectric, piezoelectric and pyroelectric measurements on crystal confirm the ferroelectric behaviour of BTNN 16/84.

  4. Mixed Solutions in the Wronskian Form for a Nonisospectral Equation

    Institute of Scientific and Technical Information of China (English)

    张大军

    2004-01-01

    N-soliton solutions in the Wronskian form for the KdV equation with loss and nonuniformity terms were obtained. New rational-like solutions and mixed solutions were further derived. All these solutions were verified by direct substitutions into bilinear equation.

  5. Accurate estimates of solutions of second order recursions

    NARCIS (Netherlands)

    Mattheij, R.M.M.

    1975-01-01

    Two important types of two dimensional matrix-vector and second order scalar recursions are studied. Both types possess two kinds of solutions (to be called forward and backward dominant solutions). For the directions of these solutions sharp estimates are derived, from which the solutions themselve

  6. A compact analytic solution describing optoacoustic phenomenon in absorbing fluid

    CERN Document Server

    Cundin, Luisiana; Barsalou, Norman; Voss, Shannon

    2012-01-01

    Derivation of an analytic, closed-form solution for Q-switched laser induced optoacoustic phenomenon in absorbing fluid media is presented. The solution assumes spherical symmetry as well for the forcing function, which represents heat deposition from Q-switched lasers. The Greens solution provided is a suitable kernel to generate more complex solutions arising in optoacoustics, optoacoustic spectroscopy, photoacoustic and photothermal problems.

  7. Extension of Variable Separable Solutions for Nonlinear Evolution Equations

    Institute of Scientific and Technical Information of China (English)

    JIA Hua-Bing; ZHANG Shun-Li; XU Wei; ZHU Xiao-Ning; WANG Yong-Mao; LOU Sen-Yue

    2008-01-01

    We give the generalized definitions of variable separable solutions to nonlinear evolution equations, and characterize the relation between the functional separable solution and the derivative-dependent functional separablecation, we classify the generalized nonlinear diffusion equations that admit special functional separable solutions and obtain some exact solutions to the resulting equations.

  8. Exact cosmological solutions for MOG

    Energy Technology Data Exchange (ETDEWEB)

    Roshan, Mahmood [Ferdowsi University of Mashhad, Department of Physics, P.O. Box 1436, Mashhad (Iran, Islamic Republic of)

    2015-09-15

    We find some new exact cosmological solutions for the covariant scalar-tensor-vector gravity theory, the so-called modified gravity (MOG). The exact solution of the vacuum field equations has been derived. Also, for non-vacuum cases we have found some exact solutions with the aid of the Noether symmetry approach. More specifically, the symmetry vector and also the Noether conserved quantity associated to the point-like Lagrangian of the theory have been found. Also we find the exact form of the generic vector field potential of this theory by considering the behavior of the relevant point-like Lagrangian under the infinitesimal generator of the Noether symmetry. Finally, we discuss the cosmological implications of the solutions. (orig.)

  9. Strongly nonlinear oscillators analytical solutions

    CERN Document Server

    Cveticanin, Livija

    2014-01-01

    This book provides the presentation of the motion of pure nonlinear oscillatory systems and various solution procedures which give the approximate solutions of the strong nonlinear oscillator equations. The book presents the original author’s method for the analytical solution procedure of the pure nonlinear oscillator system. After an introduction, the physical explanation of the pure nonlinearity and of the pure nonlinear oscillator is given. The analytical solution for free and forced vibrations of the one-degree-of-freedom strong nonlinear system with constant and time variable parameter is considered. Special attention is given to the one and two mass oscillatory systems with two-degrees-of-freedom. The criteria for the deterministic chaos in ideal and non-ideal pure nonlinear oscillators are derived analytically. The method for suppressing chaos is developed. Important problems are discussed in didactic exercises. The book is self-consistent and suitable as a textbook for students and also for profess...

  10. Simplified solution of diffraction from a Lyot system

    Science.gov (United States)

    Wang, Yaujen; Vaughan, Arthur H.

    1988-01-01

    This paper presents a derivation of a simplified analytical solution of diffraction from a Lyot (1939) system designed for observation of the solar corona outside of eclipses. Applying the theorem of Papoulis (1986) to simplify the calculations, a simplified solution is derived which is found to be in reasonable agreement with the exact solution. The simplified solution suffices for the preliminary evaluation of the amount of diffraction reduction needed to meet certain system requirements and also serves as a guideline for further apodization.

  11. Twisting singular solutions of Bethe's equations

    CERN Document Server

    Nepomechie, Rafael I

    2014-01-01

    The Bethe equations for the periodic XXX and XXZ spin chains admit singular solutions, for which the corresponding eigenvalues and eigenvectors are ill-defined. We use a twist regularization to derive conditions for such singular solutions to be physical, in which case they correspond to genuine eigenvalues and eigenvectors of the Hamiltonian.

  12. On $n$-derivations

    Directory of Open Access Journals (Sweden)

    Mohammad Hossein Sattari

    2016-06-01

    Full Text Available In this article, the notion of $n-$derivation is introduced for all integers $ngeq 2$. Although all derivations are $n-$derivations,  in general these notions are not equivalent. Some properties of ordinary derivations are  investigated for $n-$derivations. Also, we show that under certain mild condition  $n-$derivations are derivations.

  13. Exact solution of phantom dark energy model

    Institute of Scientific and Technical Information of China (English)

    Wang Wen-Fu; Shui Zheng-Wei; Tang Bin

    2010-01-01

    We investigate the phantom dark energy model derived from the scalar field with a negative kinetic term. By assuming a particular relation between the time derivative of the phantom field and the Hubble function, an exact solution of the model is constructed. Absence of the 'big rip' singularity is shown explicitly. We then derive special features of phantom dark energy model and show that its predictions are consistent with all astrophysical observations.

  14. Schwarzschild Solution: A Historical Perspective

    Science.gov (United States)

    Bartusiak, Marcia

    2016-03-01

    While eighteenth-century Newtonians had imagined a precursor to the black hole, the modern version has its roots in the first full solution to Einstein's equations of general relativity, derived by the German astronomer Karl Schwarzschild on a World War I battlefront just weeks after Einstein introduced his completed theory in November 1915. This talk will demonstrate how Schwarzschild's solution is linked to the black hole and how it took more than half a century for the physics community to accept that such a bizarre celestial object could exist in the universe.

  15. Rice straw-derived activated carbons for the removal of carbofuran from an aqueous solution%利用稻杆衍生吸附剂去除液相中呋喃丹

    Institute of Scientific and Technical Information of China (English)

    张耿崚; 陈志成; 林俊宏; 谢荣峯; 汪印; 赵峰; 施怡瑄; 邢贞娇; 陈水田

    2014-01-01

    Activated carbon was prepared from rice straw by carbonization and KOH activation, and was used as an adsorbent for the removal of a kind of pesticide, carbofuran (2,3-dihydro-2,2-dimethylbenzofuran-7-yl methylcarbamate) from aqueous solution. The effects of the initial carbofuran concentration, contact time, temperature and pH, on its adsorption capacity and kinetics were studied using a batch method. The surface area and average pore diameter of the activated carbon were 1304. 8 m2/g and 2. 39 nm, respectively. The maximum adsorption capacity of the activated carbon (296. 52 mg/g) for carbofuran was found to occur at 90 min, 30℃ and 200 mg/L initial carbofuran concentration with an adsorbent loading of 100 mg/L. Equilibrium adsorption isotherms were fitted better by the Langmuir model than the Freundlich and Temkin models. The adsorption follows a pseudo-second-order kinetics model.%以KOH为活化剂进行两段式活化程序,将废弃生物质材料转化为活性炭,并评估此活性炭吸对液相中农药(呋喃丹)的去除能力。结果表明,此活性炭具有大比表面积与高吸附能力可快速有效地去除液相中的呋喃丹。吸附前后的活性炭用扫描电子显微镜、元素分析仪与傅里叶变换红外光谱仪进行特征分析。活性炭的比表面积与平均孔径分别为1304.8 m2/g与2.39 nm。同时对不同的吸附参数进行批次分析,包括呋喃丹初始浓度,吸附时间、温度与酸碱度。最大吸附量(296.52mg/g)的吸附参数为90min、30益、吸附剂剂量100mg/L、180r/min、呋喃丹初始浓度200mg/L。根据三种平衡吸附等温线( Langmuir, Freundlich and Temkin)与动力学分析,Langmuir模式最符合此活性炭的吸附结果,伪二级动力学方程可预测此活性炭的吸附动力学。

  16. New Similarity Reduction Solutions for the (2+1)-Dimensional Nizhnik-Novikov-Veselov Equation

    Institute of Scientific and Technical Information of China (English)

    ZHI Hong-Yan

    2013-01-01

    In this paper,some new formal similarity reduction solutions for the (2+ 1)-dimensional Nizhnik-Novikov-Veselov equation are derived.Firstly,we derive the similarity reduction of the NNV equation with the optimal system of the admitted one-dimensional subalgebras.Secondly,by analyzing the reduced equation,three types of similarity solutions are derived,such as multi-soliton like solutions,variable separations solutions,and KdV type solutions.

  17. New Exact Solutions and Localized Structures for (3+1)-Dimensional Burgers System

    Institute of Scientific and Technical Information of China (English)

    ZHANG Jing-Shang; LI Jiang-Bo; MA Song-Hua; REN Qing-Bao; FANG Jian-Ping; ZHENG Chun-Long

    2008-01-01

    With an extended mapping approach and a linear variable separation method, new families of variable separation solutions (including solitary wave solutions, periodic wave solutions, and rational function solutions) with arbitrary functions for (3+1)-dimensional Burgers system is derived. Based on the derived excitations, we obtain some novel localized coherent structures and study the interactions between solitons.

  18. Homogenous Balance Method and Exact Analytical Solutions for Whitham-Broer-Kaup Equations in Shallow Water

    Institute of Scientific and Technical Information of China (English)

    XIAZhi

    2004-01-01

    Based on the homogenous balance method and with the help of mathematica, the Backlund transformation and the transfer heat equation are derived. Analyzing the heat-transfer equation, the multiple soliton solutions and other exact analytical solution for Whitham-Broer-Kaup equations(WBK) are derived. These solutions contain Fan's, Xie's and Yan's results and other new types of analytical solutions, such as rational function solutions and periodic solutions. The method can also be applied to solve more nonlinear differential equations.

  19. Normal BGG solutions and polynomials

    CERN Document Server

    Cap, A; Hammerl, M

    2012-01-01

    First BGG operators are a large class of overdetermined linear differential operators intrinsically associated to a parabolic geometry on a manifold. The corresponding equations include those controlling infinitesimal automorphisms, higher symmetries, and many other widely studied PDE of geometric origin. The machinery of BGG sequences also singles out a subclass of solutions called normal solutions. These correspond to parallel tractor fields and hence to (certain) holonomy reductions of the canonical normal Cartan connection. Using the normal Cartan connection, we define a special class of local frames for any natural vector bundle associated to a parabolic geometry. We then prove that the coefficient functions of any normal solution of a first BGG operator with respect to such a frame are polynomials in the normal coordinates of the parabolic geometry. A bound on the degree of these polynomials in terms of representation theory data is derived. For geometries locally isomorphic to the homogeneous model of ...

  20. UNIFORM SUPERAPPROXIMATION OF THE DERIVATIVE OF TETRAHEDRAL QUADRATIC FINITE ELEMENT APPROXIMATION

    Institute of Scientific and Technical Information of China (English)

    Jing-hong Liu; Qi-ding Zhu

    2005-01-01

    In this paper,we will prove the derivative of tetrahedral quadratic finite element approximation is superapproximate to the derivative of the quadratic Lagrange interpolant of the exact solution in the L∞-norm, which can be used to enhance the accuracy of the derivative of tetrahedral quadratic finite element approximation to the derivative of the exact solution.

  1. The comparative study on analytical solutions and numerical solutions of displacement in transversely isotropic rock mass

    Science.gov (United States)

    Zhang, Zhizeng; Zhao, Zhao; Li, Yongtao

    2016-06-01

    This paper attempts to verify the correctness of the analytical displacement solution in transversely isotropic rock mass, and to determine the scope of its application. The analytical displacement solution of a circular tunnel in transversely isotropic rock mass was derived firstly. The analytical solution was compared with the numerical solution, which was carried out by FLAC3D software. The results show that the expression of the analytical displacement solution is correct, and the allowable engineering range is that the dip angle is less than 15 degrees.

  2. Nonequilibrium thermodynamics of pressure solution

    Science.gov (United States)

    Lehner, F. K.; Bataille, J.

    1984-01-01

    This paper is concerned with the thermodynamic theory of solution and precipitation processes in wet crustal rocks and with the mechanism of steady pressure-solution slip in ‘contact zones,’ such as grain-to-grain contacts, fracture surfaces, and permeable gouge layers, that are infiltrated by a mobile aqueous solution phase. A local dissipation jump condition at the phase boundary is fundamental to identifying the thermodynamic force driving the solution and precipitation process and is used here in setting up linear phenomenological relations to model near-equilibrium phase transformation kinetics. The local thermodynamic equilibrium of a stressed pure solid in contact with its melt or solution phase is governed by Gibbs's relation, which is rederived here, in a manner emphasizing its independence of constitutive assumptions for the solid while neglecting surface tension and diffusion in the solid. Fluid-infiltrated contact zones, such as those formed by rough surfaces, cannot generally be in thermodynamic equilibrium, especially during an ongoing process of pressure-solution slip, and the existing equilibrium formulations are incorrect in overlooking dissipative processes tending to eliminate fluctuations in superficial free energies due to stress concentrations near asperities, defects, or impurities. Steady pressure-solution slip is likely to exhibit a nonlinear dependence of slip rate on shear stress and effective normal stress, due to a dependence of the contact-zone state on the latter. Given that this dependence is negligible within some range, linear relations for pressure-solution slip can be derived for the limiting cases of diffusion-controlled and interface-reaction-controlled rates. A criterion for rate control by one of these mechanisms is set by the magnitude of the dimensionless quantity kδ/2C pD, where k is the interfacial transfer coefficient, δ is the mean diffusion path length, C p is the solubility at pressure p, and D is the mass

  3. Exact vacuum solution of a (1+2)-dimensional Poincare gauge theory BTZ solution with torsion

    CERN Document Server

    Garcia, A A; Heinicke, C; Macías, A; Garcia, Alberto A.; Hehl, Friedrich W.; Heinicke, Christian; Macias, Alfredo

    2003-01-01

    In (1+2)-dimensional Poincar\\'e gauge gravity, we start from a Lagrangian depending on torsion and curvature which includes additionally {\\em translational} and {\\em Lorentzian} Chern-Simons terms. Limiting ourselves to to a specific subcase, the Mielke-Baekler (MB) model, we derive the corresponding field equations (of Einstein-Cartan-Chern-Simons type) and find the general vacuum solution. We determine the properties of this solution, in particular its mass and its angular momentum. For vanishing torsion, we recover the BTZ-solution. We also derive the general conformally flat vacuum solution with torsion. In this framework, we discuss {\\em Cartan's} (3-dimensional) {\\em spiral staircase} and find that it is not only a special case of our new vacuum solution, but can alternatively be understood as a solution of the 3-dimensional Einstein-Cartan theory with matter of constant pressure and constant torque. {\\em file 3dexact15.tex}

  4. Sol-gel derived sorbents

    Science.gov (United States)

    Sigman, Michael E.; Dindal, Amy B.

    2003-11-11

    Described is a method for producing copolymerized sol-gel derived sorbent particles for the production of copolymerized sol-gel derived sorbent material. The method for producing copolymerized sol-gel derived sorbent particles comprises adding a basic solution to an aqueous metal alkoxide mixture for a pH.ltoreq.8 to hydrolyze the metal alkoxides. Then, allowing the mixture to react at room temperature for a precalculated period of time for the mixture to undergo an increased in viscosity to obtain a desired pore size and surface area. The copolymerized mixture is then added to an immiscible, nonpolar solvent that has been heated to a sufficient temperature wherein the copolymerized mixture forms a solid upon the addition. The solid is recovered from the mixture, and is ready for use in an active sampling trap or activated for use in a passive sampling trap.

  5. Synthesis and Aqueous Solution Viscosity of Hydrophobically Modified Xanthan Gum

    Institute of Scientific and Technical Information of China (English)

    QIAN Xiao-lin; WU Wen-hui; YU Pei-zhi; WANG Jian-quan

    2007-01-01

    Two xanthan gum derivatives hydrophobically modified by 4 or 8 tetradecyl chains per 100 xanthan gum structure units were synthesized. The derivatives were studied by scanning electron microscope and pyrene fluorescence spectrometry. And the aqueous solution apparent viscosity of the derivatives was investigated. The results indicate that the network of the derivatives with more hydrophobic groups is closer and tighter. With increasing of alkyl chain substitution degree, the hydrophobically associating interactions enhance in aqueous solution. Aqueous solution apparent viscosity of the derivatives increases with increasing of polymer concentration and alkyl substitution degree, and decreases with the increase of temperature. In the brine solution, the strong viscosity enhancement phenomenon appears. The interaction between the derivatives and surfactant sodium dodecylbenzene sulfonate is strong.

  6. Chemical and photochemical properties of chloroharmine derivatives in aqueous solutions.

    Science.gov (United States)

    Rasse-Suriani, Federico A O; Denofrio, M Paula; Yañuk, Juan G; Gonzalez, M Micaela; Wolcan, Ezequiel; Seifermann, Marco; Erra-Balsells, Rosa; Cabrerizo, Franco M

    2016-01-14

    Thermal and photochemical stability (Φ(R)), room temperature UV-vis absorption and fluorescence spectra, fluorescence quantum yields (Φ(F)) and lifetimes (τ(F)), quantum yields of hydrogen peroxide (Φ(H2O2)) and singlet oxygen (Φ(Δ)) production, and triplet lifetimes (τ(T)) have been obtained for the neutral and protonated forms of 6-chloroharmine, 8-chloroharmine and 6,8-dichloroharmine, in aqueous media. When it was possible, the effect of pH and oxygen concentration was evaluated. The nature of electronic transitions of protonated and neutral species of the three investigated chloroharmines was established using Time-Dependent Density Functional Theory (TD-DFT) calculations. The impact of all the foregoing observations on the biological role of the studied compounds is discussed.

  7. One-soliton solutions from Laplace’s seed

    Indian Academy of Sciences (India)

    S Chaudhuri; K C Das

    2002-03-01

    One-soliton solutions of axially symmetric vacuum Einstein field equations are presented in this paper. Two sets of Laplace’s solutions are used as seed and it is shown that the derived solutions reduce to some already known solutions when the constants are properly adjusted. An analysis of the solutions in terms of the Ernst potential is also presented. It is found that the solutions do not reduce to the Euclidean form at spatial infinity. However, in the static limit, Weyl solutions are obtained for half integral -values.

  8. Static Solutions of Einstein's Equations with Cylindrical Symmetry

    Science.gov (United States)

    Trendafilova, C. S.; Fulling, S. A.

    2011-01-01

    In analogy with the standard derivation of the Schwarzschild solution, we find all static, cylindrically symmetric solutions of the Einstein field equations for vacuum. These include not only the well-known cone solution, which is locally flat, but others in which the metric coefficients are powers of the radial coordinate and the spacetime is…

  9. Solutions of some class of nonlinear PDEs in mathematical physics

    Directory of Open Access Journals (Sweden)

    Shoukry El-Ganaini

    2016-04-01

    As a result, exact traveling wave solutions involving parameters have been obtained for the considered nonlinear equations in a concise manner. When these parameters are chosen as special values, the solitary wave solutions are derived. It is shown that the proposed technique provides a more powerful mathematical tool for constructing exact solutions for a broad variety of nonlinear PDEs in mathematical physics.

  10. Novel Wronskian Solutions of the KdV Equation

    Institute of Scientific and Technical Information of China (English)

    刘金; 邓淑芳

    2003-01-01

    The novel Wronskian solutions of the KdV equation were obtained as limits of the soliton solutions in the Wronskian form.These solutions were verified by direct substitution to satisfy the bilinear derivative form of the KdV equation and its Backlund trans-formation.

  11. Elliptic Equation and New Solutions to Nonlinear Wave Equations

    Institute of Scientific and Technical Information of China (English)

    FU Zun-Tao; LIU Shi-Kuo; LIU Shi-Da

    2004-01-01

    The new solutions to elliptic equation are shown, and then the elliptic equation is taken as a transformationand is applied to solve nonlinear wave equations. It is shown that more kinds of solutions are derived, such as periodicsolutions of rational form, solitary wave solutions of rational form, and so on.

  12. Analytic solutions of a class of nonlinearly dynamic systems

    Energy Technology Data Exchange (ETDEWEB)

    Wang, M-C [System Engineering Institute of Tianjin University, Tianjin, 300072 (China); Zhao, X-S; Liu, X [Tianjin University of Technology and Education, Tianjin, 300222 (China)], E-mail: mchwang123@163.com.cn, E-mail: xszhao@mail.nwpu.edu.cn, E-mail: liuxinhubei@163.com.cn

    2008-02-15

    In this paper, the homotopy perturbation method (HPM) is applied to solve a coupled system of two nonlinear differential with first-order similar model of Lotka-Volterra and a Bratus equation with a source term. The analytic approximate solutions are derived. Furthermore, the analytic approximate solutions obtained by the HPM with the exact solutions reveals that the present method works efficiently.

  13. Generalized Relativistic Chapman-Enskog Solution of the Boltzmann Equation

    CERN Document Server

    García-Perciante, A L; García-Colin, L S

    2007-01-01

    The Chapman-Enskog method of solution of the relativistic Boltzmann equation is generalized in order to admit a time-derivative term associated to the thermodynamic force in its first order solution. Both existence and uniqueness of such a solution are proved based on the standard theory of integral equations. The mathematical implications of the generalization here introduced are briefly explored.

  14. The Peridic Wave Solutions for Two Nonlinear Evolution Equations

    Institute of Scientific and Technical Information of China (English)

    ZHANG Jin-Liang; WANG Ming-Liang; CHENG Dong-Ming; FANG Zong-De

    2003-01-01

    By using the F-expansion method proposed recently, the periodic wave solutions expressed by Jacobielliptic functions for two nonlinear evolution equations are derived. In the limit cases, the solitary wave solutions andthe other type of traveling wave solutions for the system are obtained.

  15. A Comprehensive Analytical Solution of the Nonlinear Pendulum

    Science.gov (United States)

    Ochs, Karlheinz

    2011-01-01

    In this paper, an analytical solution for the differential equation of the simple but nonlinear pendulum is derived. This solution is valid for any time and is not limited to any special initial instance or initial values. Moreover, this solution holds if the pendulum swings over or not. The method of approach is based on Jacobi elliptic functions…

  16. Scale-invariant solutions to partial differential equations of fractional order with a moving boundary condition

    Energy Technology Data Exchange (ETDEWEB)

    Li Xicheng; Xu Mingyu [Institute of Applied Mathematics, School of Mathematics and System Science, Shandong University, Jinan 250100 (China); Wang Shaowei [Department of Mechanics and Engineering Science, Peking University, Beijing 100871 (China)], E-mail: xichengli@yahoo.com.cn

    2008-04-18

    In this paper, we give similarity solutions of partial differential equations of fractional order with a moving boundary condition. The solutions are given in terms of a generalized Wright function. The time-fractional Caputo derivative and two types of space-fractional derivatives are considered. The scale-invariant variable and the form of the solution of the moving boundary are obtained by the Lie group analysis. A comparison between the solutions corresponding to two types of fractional derivative is also given.

  17. Derived logarithmic geometry I

    OpenAIRE

    Steffen, Sagave; Timo, Schurg; Gabriele, Vezzosi

    2016-01-01

    In order to develop the foundations of logarithmic derived geometry, we introduce a model category of logarithmic simplicial rings and a notion of derived log \\'etale maps and use this to define derived log stacks.

  18. Solutions manual to accompany Fundamentals of calculus

    CERN Document Server

    Morris, Carla C

    2015-01-01

    Solutions Manual to Accompany Fundamentals of Calculus the text that encourages students to use power, quotient, and product rules for solutions as well as stresses the importance of modeling skills.  In addition to core integral and differential calculus coverage, the core book features finite calculus, which lends itself to modeling and spreadsheets.  Specifically, finite calculus is applied to marginal economic analysis, finance, growth, and decay.  Includes: Linear Equations and Functions The Derivative Using the Derivative Exponential and Logarithmic

  19. Novel Hyperbolic Homoclinic Solutions of the Helmholtz-Duffing Oscillators

    Directory of Open Access Journals (Sweden)

    Yang-Yang Chen

    2016-01-01

    Full Text Available The exact and explicit homoclinic solution of the undamped Helmholtz-Duffing oscillator is derived by a presented hyperbolic function balance procedure. The homoclinic solution of the self-excited Helmholtz-Duffing oscillator can also be obtained by an extended hyperbolic perturbation method. The application of the present homoclinic solutions to the chaos prediction of the nonautonomous Helmholtz-Duffing oscillator is performed. Effectiveness and advantage of the present solutions are shown by comparisons.

  20. Solutions of fractional diffusion equations by variation of parameters method

    Directory of Open Access Journals (Sweden)

    Mohyud-Din Syed Tauseef

    2015-01-01

    Full Text Available This article is devoted to establish a novel analytical solution scheme for the fractional diffusion equations. Caputo’s formulation followed by the variation of parameters method has been employed to obtain the analytical solutions. Following the derived analytical scheme, solution of the fractional diffusion equation for several initial functions has been obtained. Graphs are plotted to see the physical behavior of obtained solutions.

  1. Quantizing N=2 Multicenter Solutions

    CERN Document Server

    de Boer, Jan; Messamah, Ilies; Bleeken, Dieter Van den

    2009-01-01

    N=2 supergravity in four dimensions, or equivalently N=1 supergravity in five dimensions, has an interesting set of BPS solutions that each correspond to a number of charged centers. This set contains black holes, black rings and their bound states, as well as many smooth solutions. Moduli spaces of such solutions carry a natural symplectic form which we determine, and which allows us to study their quantization. By counting the resulting wavefunctions we come to an independent derivation of some of the wall-crossing formulae. Knowledge of the explicit form of these wavefunctions allows us to find quantum resolutions to some apparent classical paradoxes such as solutions with barely bound centers and those with an infinitely deep throat. We show that quantum effects seem to cap off the throat at a finite depth and we give an estimate for the corresponding mass gap in the dual CFT. This is an interesting example of a system where quantum effects cannot be neglected at macroscopic scales even though the curvatu...

  2. Optimal economic order quantity for buyer-distributor-vendor supply chain with backlogging derived without derivatives

    Science.gov (United States)

    Teng, Jinn-Tsair; Cárdenas-Barrón, Leopoldo Eduardo; Lou, Kuo-Ren; Wee, Hui Ming

    2013-05-01

    In this article, we first complement an inappropriate mathematical error on the total cost in the previously published paper by Chung and Wee [2007, 'Optimal the Economic Lot Size of a Three-stage Supply Chain With Backlogging Derived Without Derivatives', European Journal of Operational Research, 183, 933-943] related to buyer-distributor-vendor three-stage supply chain with backlogging derived without derivatives. Then, an arithmetic-geometric inequality method is proposed not only to simplify the algebraic method of completing prefect squares, but also to complement their shortcomings. In addition, we provide a closed-form solution to integral number of deliveries for the distributor and the vendor without using complex derivatives. Furthermore, our method can solve many cases in which their method cannot, because they did not consider that a squared root of a negative number does not exist. Finally, we use some numerical examples to show that our proposed optimal solution is cheaper to operate than theirs.

  3. Turbulence in dilute polymer solutions

    Science.gov (United States)

    Liberzon, A.; Guala, M.; Lüthi, B.; Kinzelbach, W.; Tsinober, A.

    2005-03-01

    The work reported below is a comparative study of the properties of turbulence with weak mean flow in a Newtonian fluid and in a dilute polymer solution with an emphasis on the small scale phenomena. The main tool used is a three-dimensional particle tracking system allowing to measure and follow in a Lagrangian manner the field of velocities, as well as velocity derivatives, and thus vorticity, strain, and a variety of related and dynamically significant quantities. The comparison of data from the two flows allows to directly observe the influence of polymers on these quantities as well as the evolution of material elements in the presence of polymers.

  4. NONLINEAR WAVES AND PERIODIC SOLUTION IN FINITE DEFORMATION ELASTIC ROD

    Institute of Scientific and Technical Information of China (English)

    Liu Zhifang; Zhang Shanyuan

    2006-01-01

    A nonlinear wave equation of elastic rod taking account of finite deformation, transverse inertia and shearing strain is derived by means of the Hamilton principle in this paper. Nonlinear wave equation and truncated nonlinear wave equation are solved by the Jacobi elliptic sine function expansion and the third kind of Jacobi elliptic function expansion method. The exact periodic solutions of these nonlinear equations are obtained, including the shock wave solution and the solitary wave solution. The necessary condition of exact periodic solutions, shock solution and solitary solution existence is discussed.

  5. Constrained Solutions of a System of Matrix Equations

    Directory of Open Access Journals (Sweden)

    Qing-Wen Wang

    2012-01-01

    Full Text Available We derive the necessary and sufficient conditions of and the expressions for the orthogonal solutions, the symmetric orthogonal solutions, and the skew-symmetric orthogonal solutions of the system of matrix equations AX=B and XC=D, respectively. When the matrix equations are not consistent, the least squares symmetric orthogonal solutions and the least squares skew-symmetric orthogonal solutions are respectively given. As an auxiliary, an algorithm is provided to compute the least squares symmetric orthogonal solutions, and meanwhile an example is presented to show that it is reasonable.

  6. Konopelchenko-Dubrovsky方程的周期解%Periodic Wave Solutions for Konopelchenko-Dubrovsky Equation

    Institute of Scientific and Technical Information of China (English)

    张金良; 张令元; 王明亮

    2005-01-01

    By using F-expansion method proposed recently, we derive the periodic wave solution expressed by Jacobi elliptic functions for Konopelchenko-Dubrovsky equation. In the limit case, the solitary wave solution and other type of the traveling wave solutions are derived.

  7. Cosmological Solutions of $f(T)$ Gravity

    CERN Document Server

    Paliathanasis, Andronikos; Leach, P G L

    2016-01-01

    In the cosmological scenario in $f\\left( T\\right) $ gravity, we find analytical solutions for an isotropic and homogeneous universe containing a dust fluid and radiation and for an empty anisotropic Bianchi I universe. The method that we apply is that of movable singularities of differential equations. For the isotropic universe, the solutions are expressed in terms of a Laurent expansion, while for the anisotropic universe we find a family of exact Kasner-like solutions in vacuum. Finally, we discuss when a nonlinear $f\\left( T\\right) $-gravity theory provides solutions for the teleparallel equivalence of general relativity and derive conditions for exact solutions of general relativity to solve the field equations of an $f(T)$ theory.

  8. Cosmological solutions of f (T ) gravity

    Science.gov (United States)

    Paliathanasis, Andronikos; Barrow, John D.; Leach, P. G. L.

    2016-07-01

    In the cosmological scenario in f (T ) gravity, we find analytical solutions for an isotropic and homogeneous universe containing a dust fluid and radiation and for an empty anisotropic Bianchi I universe. The method that we apply is that of movable singularities of differential equations. For the isotropic universe, the solutions are expressed in terms of a Laurent expansion, while for the anisotropic universe we find a family of exact Kasner-like solutions in vacuum. Finally, we discuss when a nonlinear f (T ) -gravity theory provides solutions for the teleparallel equivalence of general relativity and derive conditions for exact solutions of general relativity to solve the field equations of an f (T ) theory.

  9. Black holes in higher derivative gravity.

    Science.gov (United States)

    Lü, H; Perkins, A; Pope, C N; Stelle, K S

    2015-05-01

    Extensions of Einstein gravity with higher-order derivative terms arise in string theory and other effective theories, as well as being of interest in their own right. In this Letter we study static black-hole solutions in the example of Einstein gravity with additional quadratic curvature terms. A Lichnerowicz-type theorem simplifies the analysis by establishing that they must have vanishing Ricci scalar curvature. By numerical methods we then demonstrate the existence of further black-hole solutions over and above the Schwarzschild solution. We discuss some of their thermodynamic properties, and show that they obey the first law of thermodynamics.

  10. Asymptotic vacua with higher derivatives

    Energy Technology Data Exchange (ETDEWEB)

    Cotsakis, Spiros, E-mail: skot@aegean.gr [Department of Mathematics, American University of the Middle East, P.O. Box 220 Dasman, 15453 (Kuwait); Kadry, Seifedine, E-mail: Seifedine.Kadry@aum.edu.kw [Department of Mathematics, American University of the Middle East, P.O. Box 220 Dasman, 15453 (Kuwait); Kolionis, Georgios, E-mail: gkolionis@aegean.gr [Research group of Geometry, Dynamical Systems and Cosmology, University of the Aegean, Karlovassi 83200, Samos (Greece); Tsokaros, Antonios, E-mail: atsok@aegean.gr [Research group of Geometry, Dynamical Systems and Cosmology, University of the Aegean, Karlovassi 83200, Samos (Greece)

    2016-04-10

    We study limits of vacuum, isotropic universes in the full, effective, four-dimensional theory with higher derivatives. We show that all flat vacua as well as general curved ones are globally attracted by the standard, square root scaling solution at early times. Open vacua asymptote to horizon-free, Milne states in both directions while closed universes exhibit more complex logarithmic singularities, starting from initial data sets of a possibly smaller dimension. We also discuss the relation of our results to the asymptotic stability of the passage through the singularity in ekpyrotic and cyclic cosmologies.

  11. Asymptotic vacua with higher derivatives

    Directory of Open Access Journals (Sweden)

    Spiros Cotsakis

    2016-04-01

    Full Text Available We study limits of vacuum, isotropic universes in the full, effective, four-dimensional theory with higher derivatives. We show that all flat vacua as well as general curved ones are globally attracted by the standard, square root scaling solution at early times. Open vacua asymptote to horizon-free, Milne states in both directions while closed universes exhibit more complex logarithmic singularities, starting from initial data sets of a possibly smaller dimension. We also discuss the relation of our results to the asymptotic stability of the passage through the singularity in ekpyrotic and cyclic cosmologies.

  12. Frankenstein's glue: transition functions for approximate solutions

    Science.gov (United States)

    Yunes, Nicolás

    2007-09-01

    Approximations are commonly employed to find approximate solutions to the Einstein equations. These solutions, however, are usually only valid in some specific spacetime region. A global solution can be constructed by gluing approximate solutions together, but this procedure is difficult because discontinuities can arise, leading to large violations of the Einstein equations. In this paper, we provide an attempt to formalize this gluing scheme by studying transition functions that join approximate analytic solutions together. In particular, we propose certain sufficient conditions on these functions and prove that these conditions guarantee that the joined solution still satisfies the Einstein equations analytically to the same order as the approximate ones. An example is also provided for a binary system of non-spinning black holes, where the approximate solutions are taken to be given by a post-Newtonian expansion and a perturbed Schwarzschild solution. For this specific case, we show that if the transition functions satisfy the proposed conditions, then the joined solution does not contain any violations to the Einstein equations larger than those already inherent in the approximations. We further show that if these functions violate the proposed conditions, then the matter content of the spacetime is modified by the introduction of a matter shell, whose stress energy tensor depends on derivatives of these functions.

  13. Radially Symmetric Solutions of

    Directory of Open Access Journals (Sweden)

    William C. Troy

    2012-01-01

    Full Text Available We investigate solutions of and focus on the regime and . Our advance is to develop a technique to efficiently classify the behavior of solutions on , their maximal positive interval of existence. Our approach is to transform the nonautonomous equation into an autonomous ODE. This reduces the problem to analyzing the phase plane of the autonomous equation. We prove the existence of new families of solutions of the equation and describe their asymptotic behavior. In the subcritical case there is a well-known closed-form singular solution, , such that as and as . Our advance is to prove the existence of a family of solutions of the subcritical case which satisfies for infinitely many values . At the critical value there is a continuum of positive singular solutions, and a continuum of sign changing singular solutions. In the supercritical regime we prove the existence of a family of “super singular” sign changing singular solutions.

  14. Axisymmetric fundamental solutions for a finite layer with impeded boundaries

    Institute of Scientific and Technical Information of China (English)

    程泽海; 陈云敏; 凌道盛; 唐晓武

    2003-01-01

    Axisymmetrie fundamental solutions that are applied in the consolidation calculations of a finite clay layer with impeded boundaries were derived. Laplace and Hankel integral transforms were utilized with respect to time and radial coordinates, respectively in the analysis. The derivation of fundamental solutions considers two boundary-value problems involving unit point loading and ring loading in the vertical. The solut-ions are extended to circular distributed and strip distributed normal load. The computation and analysis of set-tlements, vertical total stress and excess pore pressure in the consolidation layer subject to circular loading are presented.

  15. PFP solution stabilization

    Energy Technology Data Exchange (ETDEWEB)

    Aftanas, B.L.

    1996-04-30

    This Functional Design Criteria (FDC) addresses remediation of the plutonium-bearing solutions currently in inventory at the Plutonium Finishing Plant (PFP). The recommendation from the Environmental Impact Statement (EIS) is that the solutions be treated thermally and stabilized as a solid for long term storage. For solutions which are not discardable, the baseline plan is to utilize a denitration process to stabilize the solutions prior to packaging for storage.

  16. Unsteady Stokes Equations: Some Complete General Solutions

    Indian Academy of Sciences (India)

    A Venkatlaxmi; B S Padmavathi; T Amaranath

    2004-05-01

    The completeness of solutions of homogeneous as well as non-homogeneous unsteady Stokes equations are examined. A necessary and sufficient condition for a divergence-free vector to represent the velocity field of a possible unsteady Stokes flow in the absence of body forces is derived.

  17. Multicapillary mixer of solutions.

    Science.gov (United States)

    Moskowitz, G W; Bowman, R L

    1966-07-22

    A mixer made from a bundle of glass tubules can mix two solutions within 30 microseconds, with a total-solution flow rate of 1.33 milliliters per second. One solution passes through the interstices of the bundle; the other moves through the lumens of the tubes.

  18. 不同保存液及放置时间对脐带源间充质干细胞存活率的影响%Influence of different preservation solutions and placing time on survival rate of umbilical cord-derived mesenchymal stem cells

    Institute of Scientific and Technical Information of China (English)

    李志刚; 贲亮; 韩宇; 毕薇薇

    2015-01-01

    背景:干细胞制备完成后的放置时间与其存活率的关系是临床应用安全、有效的基础。目的:观察不同保存液及不同保存时间对脐带源间充质干细胞存活率的影响,为干细胞有效期的确定提供重要依据。方法:选用脐带源间充质干细胞制备干细胞制剂,分别采用生理盐水、培养基、培养基+生理盐水、生理盐水含表皮生长因子、培养基含低分子肝素钙悬浮保存。使用冷藏箱模拟细胞运输条件,分别在第0,6,12,18,24,30,36,42,48小时取样,进行细胞总数和细胞活率的检测。结果与结论:各组在24 h内的细胞数量和细胞活率差别不大。24 h后,培养基组和培养基含低分子肝素钙组的细胞总数和细胞活率优于生理盐水含因子组、生理盐水组、培养基+生理盐水组。干细胞制剂制备完成后,冷藏运输24 h内细胞活率可达90%以上,保存液中的营养成分及合适的pH值,可使细胞活率显著提高。%BACKGROUND:The relationship between placing time after stem cel preparation and cel survival is the basis of safety and effectiveness for the clinical application. OBJECTIVE: To observe effects of different preservation solutions and different storage time on survival rate of umbilical cord-derived mesenchymal stem cels, and to provide important evidence for identifying effectiveness of stem cels. METHODS:Umbilical cord-derived mesenchymal stem cels were selected to prepare stem cel preparation, which was preserved in physiological saline, medium, medium+physiological saline, physiological saline containing epidermal growth factor, and medium containing low molecular heparin calcium suspension. Cold closet was selected for imitating celular transport conditions. Samples were obtained at 0, 6, 12, 18, 24, 30, 36, 42 and 48 hours. Total cel number and cel survival rate were detected. RESULTS AND CONCLUSION:The difference in cel number and

  19. Synthesis of isothiocyanate-derived mercapturic acids

    NARCIS (Netherlands)

    Vermeulen, M.; Zwanenburg, B.; Chittenden, G.J.F.; Verhagen, H.

    2003-01-01

    Twelve mercapturic acids derived from saturated and unsaturated aliphatic and aromatic isothiocyanates were synthesised, by adding isothiocyanate to a solution of N-acetyl-L-cysteine and sodium bicarbonate, in a typical yield of 77%. Isothiocyanates were synthesised first by adding the corresponding

  20. Analytical Solution for Isentropic Flows in Solids

    Science.gov (United States)

    Heuzé, Olivier

    2009-12-01

    In the XIXth century, Riemann gave the equations system and the exact solution for the isentropic flows in the case of the ideal gas. But to our knowledge, nothing has been done to apply it to condensed media. Many materials of practical interest, for instance metals, obey to the linear law D = c+s u, where D is the shock velocity, u the particle velocity, and c and s properties of the material. We notice that s is strongly linked to the fundamental derivative. This means that the assumption of constant fundamental derivative is useful in this case, as it was with the isentropic gamma in the Riemann solution. Then we can apply the exact Riemann solution for these materials. Although the use of the hypergeometric function is complicated in this case, we obtain a very good approximation with the development in power series.

  1. A NEW FRACTAL DERIVATION

    OpenAIRE

    Ji-Huan He

    2011-01-01

    A new fractal derive is defined, which is very easy for engineering applications to discontinuous problems, two simple examples are given to elucidate to establish governing equations with fractal derive and how to solve such equations, respectively.

  2. Distributed order reaction-diffusion systems associated with Caputo derivatives

    CERN Document Server

    Saxena, R K; Haubold, H J

    2011-01-01

    This paper deals with the investigation of the solution of an unified fractional reaction-diffusion equation of distributed order associated with the Caputo derivatives as the time-derivative and Riesz-Feller fractional derivative as the space-derivative. The solution is derived by the application of the joint Laplace and Fourier transforms in compact and closed form in terms of the H-function. The results derived are of general nature and include the results investigated earlier by other authors, notably by Mainardi et al. [23,24], for the fundamental solution of the space-time fractional equation, including Haubold et al. [13] and Saxena et al. [38] for fractional reaction-diffusion equations. The advantage of using the Riesz-Feller derivative lies in the fact that the solution of the fractional reaction-diffusion equation, containing this derivative, includes the fundamental solution for space-time fractional diffusion, which itself is a generalization of fractional diffusion, space-time fraction diffusion...

  3. The exact solutions for a nonisospectral nonlinear Schroedinger equation

    Energy Technology Data Exchange (ETDEWEB)

    Ning Tongke [Finance College, Shanghai Normal University, Shanghai 200234 (China)], E-mail: tkning@shnu.edu.cn; Zhang Weiguo; Jia Gao [Science College, University of Shanghai for Science and Technology, Shanghai 200093 (China)

    2009-10-30

    In this paper, lax pair for the nonisospectral nonlinear Schroedinger hierarchy is given, the time dependence of nonisospectral scattering data is derived and exact solutions for the nonisospectral nonlinear Schroedinger hierarchy are obtained through the inverse scattering transform.

  4. Derived equivalence of algebras

    Institute of Scientific and Technical Information of China (English)

    杜先能

    1997-01-01

    The derived equivalence and stable equivalence of algebras RmA and RmB are studied It is proved, using the tilting complex, that RmA and RmB are derived-equivalent whenever algebras A and B are derived-equivalent

  5. Solution-grown crystals for neutron radiation detectors, and methods of solution growth

    Science.gov (United States)

    Zaitseva, Natalia; Carman, M Leslie; Payne, Steve

    2014-10-28

    An organic crystal according to one embodiment includes an organic crystal comprising diphenylacetylene and stilbene or a stilbene derivative, the crystal having physical characteristics of formation from solution, the organic crystal exhibiting a signal response signature for neutrons from a radioactive source. A system according to one embodiment includes an organic crystal comprising diphenylacetylene and stilbene or a stilbene derivative, the crystal having physical characteristics of formation from solution, the organic crystal exhibiting a signal response signature for neutrons from a radioactive source; and a photodetector for detecting the signal response of the organic crystal. Methods of making such crystals are also provided.

  6. BIFURCATIONS OF TRAVELLING WAVE SOLUTIONS TO A COUPLED NONLINEAR WAVE SYSTEM

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Employ theory of bifurcations of dynamical systems to a system of coupled nonlin-ear equations, the existence of solitary wave solutions, kink wave solutions, anti-kink wave solutions and periodic wave solutions is obtained. Under different parametric conditions, various suffcient conditions to guarantee the existence of the above so-lutions are given. Some exact explicit parametric representations of travelling wave solutions are derived.

  7. Gauge invariant observables from Takahashi-Tanimoto scalar solutions in open string field theory

    CERN Document Server

    Zeze, Syoji

    2014-01-01

    Using Maccaferri's formula, we derive new wedge based solutions of open string field theory. The solutions are gauge equivalent to the Takahashi-Tanimoto scalar solutions. The classical action and the gauge invariant overlap are evaluated analytically. We find a perturbative vacuum solution whose gauge invariant observables vanish. We also identify a tachyon vacuum solution whose gauge invariant observables are identical to those of the Erler-Schnabl solution.

  8. Approximate solutions for fractured wells producing layered reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Bennett, C.O.; Camacho-V., R; Raghavan, R.; Reynolds, A.C.

    1985-10-01

    New analytical solutions for the response at a well intercepting a layered reservoir are derived. The well is assumed to produce at a constant rate or a constant pressure. We examine reservoir systems without interlayer communication and document the usefulness of these solutions, which enable us to obtain increased physical understanding of the performance of fractured wells in layered reservoirs. The influence of vertical variations in fracture conductivity is also considered. Example applications of the approximations derived here are also presented.

  9. The novel multi-solitary wave solution to the fifth-order KdV equation

    Institute of Scientific and Technical Information of China (English)

    Zhang Yi; Chen Deng-Yuan

    2004-01-01

    By using Hirota's method, the novel multi-solitary wave solutions to the fifth-order KdV equation are obtained.Furthermore, various new solitary wave solutions are also derived by a reconstructed bilinear Backlund transformation.

  10. An Interacting Dark Energy Model with Nonminimal Derivative Coupling

    CERN Document Server

    Nozari, Kourosh

    2016-01-01

    We study cosmological dynamics of an extended gravitational theory that gravity is coupled non-minimally with derivatives of a dark energy component and there is also a phenomenological interaction between the dark energy and dark matter. Depending on the direction of energy flow between the dark sectors, the phenomenological interaction gets two different signs. We show that this feature affects the existence of attractor solution, the rate of growth of perturbations and stability of the solutions. By considering an exponential potential as a self-interaction potential of the scalar field, we obtain accelerated scaling solutions that are attractors and have the potential to alleviate the coincidence problem. While in the absence of the nonminimal derivative coupling there is no attractor solution for phantom field when energy transfers from dark matter to dark energy, we show an attractor solution exists if one considers an explicit nonminimal derivative coupling for phantom field in this case of energy tran...

  11. Exact Solutions for a Higher-Order Nonlinear Schr(o)dinger Equation in Atmospheric Dynamics

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    By giving prior assumptions on the form of the solutions, we succeed to find several exact solutions for a higher-order nonlinear Schrodinger equation derived from one important model in the study of atmospheric and ocean dynamical systems. Our analytical solutions include bright and dark solitary waves, and periodical solutions, which can be used to explain atmospheric phenomena.

  12. New Exact Solutions for (1 + 1)-Dimensional Dispersion-Less System

    Institute of Scientific and Technical Information of China (English)

    WANG Xian-Jun; Naranmandula; FU Jing-Li; HU Jian-Guo; BAO Gang; Tubuxin

    2008-01-01

    Using improved homogeneous balance method, we obtain complex function form new exact solutions for the (1 + l)-dimensional dispersion-less system, and from the exact solutions we derive real function form solution of the field u. Based on this real function form solution, we find some new interesting coherent structures by selecting arbitrary functions appropriately.

  13. The exact solutions to (2+1)-dimensional nonlinear Schrǒdinger equation

    Institute of Scientific and Technical Information of China (English)

    ZHANG Jin-liang; WANG Ming-liang; FANG Zong-de

    2004-01-01

    By using the extended F-expansion method, the exact solutions,including periodic wave solutions expressed by Jacobi elliptic functions, for (2+1)-dimensional nonlinear Schrǒdinger equation are derived. In the limit cases, the solitary wave solutions and the other type of traveling wave solutions for the system are obtained.

  14. Wright functions governed by fractional directional derivatives and fractional advection diffusion equations

    CERN Document Server

    D'Ovidio, Mirko

    2012-01-01

    We consider fractional directional derivatives and establish some connection with stable densities. Solutions to advection equations involving fractional directional derivatives are presented and some properties investigated. In particular we obtain solutions written in terms of Wright functions by exploiting operational rules involving the shift operator. We also consider fractional advection diffusion equations involving fractional powers of the negative Laplace operator and directional derivatives of fractional order and discuss the probabilistic interpretations of solutions.

  15. Diffraction by a plane angular sector, a new derivation

    DEFF Research Database (Denmark)

    Hansen, Thokild B.

    1990-01-01

    An alternative derivation is given for the exact solution to the scattering problem in which a Hertz dipole illuminates a perfectly conducting plane angular sector. Specifically, the Ohm-Rayleigh method is used rather than that of Satterwhite (1969)......An alternative derivation is given for the exact solution to the scattering problem in which a Hertz dipole illuminates a perfectly conducting plane angular sector. Specifically, the Ohm-Rayleigh method is used rather than that of Satterwhite (1969)...

  16. Solutions to Organizational Paradox

    DEFF Research Database (Denmark)

    Li, Xin; Worm, Verner; Peihong, Xie

    Organizations face all kinds of paradoxical problems. There exist various solutions to organizational paradoxes. We develop a typology that lists nine possible logical approaches to understanding the relationship between paradoxical opposites, out of which we identify five types of solutions...... to organizational paradox. Four of the five solutions are explicitly associated with four prominent philosophies. We show the relevance of the five solutions to the real world by applying our scheme to understand different solutions to the generic strategy paradox. Finally, we address the question whether...... there is a superior solution and point out the paradox of paradox resolving, namely, paradoxes cannot be resolved once for all and we have to live with them....

  17. Rainfall interstation correlation functions derived for a class of generalized storm models

    NARCIS (Netherlands)

    Stol, P.T.

    1983-01-01

    The complete derivation and solution of the rainfall interstation correlation function is described. The report emphasizes the mathematical treatment and the way in which the analytical solution can be obtained by calculus

  18. The Schwarzschild's Braneworld Solution

    CERN Document Server

    Ovalle, J

    2010-01-01

    In the context of the Randall-Sundrum braneworld, the minimal geometric deformation approach, which has been successfully used to generate exact interior solutions to Einstein's field equations for static braneworld stars with local and non-local bulk terms, is used to obtain the braneworld version of the Schwarzschild's interior solution. Using this new solution, the behaviour of the Weyl functions is elucidated in terms of the compactness for different stellar distributions.

  19. The Schwarzschild's Braneworld Solution

    Science.gov (United States)

    Ovalle, J.

    In the context of the Randall-Sundrum braneworld, the minimal geometric deformation approach, which has been successfully used to generate exact interior solutions to Einstein's field equations for static braneworld stars with local and nonlocal bulk terms, is used to obtain the braneworld version of the Schwarzschild's interior solution. Using this new solution, the behavior of the Weyl functions is elucidated in terms of the compactness for different stellar distributions.

  20. Exact solutions for nonlinear foam drainage equation

    Science.gov (United States)

    Zayed, E. M. E.; Al-Nowehy, Abdul-Ghani

    2017-02-01

    In this paper, the modified simple equation method, the exp-function method, the soliton ansatz method, the Riccati equation expansion method and the ( G^' }/G)-expansion method are used to construct exact solutions with parameters of the nonlinear foam drainage equation. When these parameters are taken to be special values, the solitary wave solutions and the trigonometric function solutions are derived from the exact solutions. The obtained results confirm that the proposed methods are efficient techniques for analytic treatments of a wide variety of nonlinear partial differential equations in mathematical physics. We compare our results together with each other yielding from these integration tools. Also, our results have been compared with the well-known results of others.

  1. Exact solutions for nonlinear foam drainage equation

    Science.gov (United States)

    Zayed, E. M. E.; Al-Nowehy, Abdul-Ghani

    2016-09-01

    In this paper, the modified simple equation method, the exp-function method, the soliton ansatz method, the Riccati equation expansion method and the ( G^' }/G) -expansion method are used to construct exact solutions with parameters of the nonlinear foam drainage equation. When these parameters are taken to be special values, the solitary wave solutions and the trigonometric function solutions are derived from the exact solutions. The obtained results confirm that the proposed methods are efficient techniques for analytic treatments of a wide variety of nonlinear partial differential equations in mathematical physics. We compare our results together with each other yielding from these integration tools. Also, our results have been compared with the well-known results of others.

  2. Pinching solutions of slender cylindrical jets

    Science.gov (United States)

    Papageorgiou, Demetrios T.; Orellana, Oscar

    1993-01-01

    Simplified equations for slender jets are derived for a circular jet of one fluid flowing into an ambient second fluid, the flow being confined in a circular tank. Inviscid flows are studied which include both surface tension effects and Kelvin-Helmholtz instability. For slender jets a coupled nonlinear system of equations is found for the jet shape and the axial velocity jump across it. The equations can break down after a finite time and similarity solutions are constructed, and studied analytically and numerically. The break-ups found pertain to the jet pinching after a finite time, without violation of the slender jet ansatz. The system is conservative and admissible singular solutions are those which conserve the total energy, mass, and momentum. Such solutions are constructed analytically and numerically, and in the case of vortex sheets with no surface tension certain solutions are given in closed form.

  3. An Algebraic Solution for the Kermack-McKendrick Model

    CERN Document Server

    Carvalho, Alexsandro M

    2016-01-01

    We present an algebraic solution for the Susceptible-Infective-Removed (SIR) model originally presented by Kermack-McKendrick in 1927. Starting from the differential equation for the removed subjects presented by them in the original paper, we re-write it in a slightly different form in order to derive formally the solution, unless one integration. Then, using algebraic techniques and some well justified numerical assumptions we obtain an analytic solution for the integral. Finally, we compare the numerical solution of the differential equations of the SIR model with the analytically solution here proposed, showing an excellent agreement.

  4. Polynomial Solutions to the Matrix Equation X−AXTB=C

    Directory of Open Access Journals (Sweden)

    Caiqin Song

    2014-01-01

    Full Text Available Solutions are constructed for the Kalman-Yakubovich-transpose equation X−AXTB=C. The solutions are stated as a polynomial of parameters of the matrix equation. One of the polynomial solutions is expressed by the symmetric operator matrix, controllability matrix, and observability matrix. Moreover, the explicit solution is proposed when the Kalman-Yakubovich-transpose matrix equation has a unique solution. The provided approach does not require the coefficient matrices to be in canonical form. In addition, the numerical example is given to illustrate the effectiveness of the derived method. Some applications in control theory are discussed at the end of this paper.

  5. On the minimal speed and asymptotics of the wave solutions for the lotka volterra system

    CERN Document Server

    Hou, Xiaojie

    2010-01-01

    e study the minimal wave speed and the asymptotics of the traveling wave solutions of a competitive Lotka Volterra system. The existence of the traveling wave solutions is derived by monotone iteration. The asymptotic behaviors of the wave solutions are derived by comparison argument and the exponential dichotomy, which seems to be the key to understand the geometry and the stability of the wave solutions. Also the uniqueness and the monotonicity of the waves are investigated via a generalized sliding domain method.

  6. Grammian Solutions to a Non-Isospectral Kadomtsev-Petviashvili Equation

    Institute of Scientific and Technical Information of China (English)

    ZHANG Da-Jun

    2006-01-01

    @@ Solutions in the Grammian form for a non-isospectral Kadomtsev-Petviashvili equation are derived by means of Pfaffian derivative formulae. Explicit entries of the Grammian are given. Non-isospectral dynamics of the solutions generated from the Grammian are investigated in an analytic way. The solutions obtained can describe line solitons in non-uniform media travelling with time-dependent amplitude and time-dependent direction. In addition, some other solutions have singularities.

  7. A molecular theory of large-solute diffusion

    Directory of Open Access Journals (Sweden)

    A.Yoshimori

    2007-12-01

    Full Text Available The limit of a large solute in the molecular theory of diffusion developed by Yamaguchi et al. [Yamaguchi T. et al., J. Chem. Phys., 2005, 123, 034504] is studied. By the limit, the Stokes approximation to the hydrodynamic equations is derived in the outside region of a diffusing solute. The limit of a large solute also leads to equations in the inside region of the solute. The analytical solution of the inside equation allows one to derive the boundary condition, which is needed on the surface of the solute when the hydrodynamic equations are calculated. The boundary condition includes stick and slip boundary conditions employed by the Stokes law, in the special case. Besides stick and slip conditions, other conditions can be expressed. The boundary condition depends on properties of a solvent.

  8. Analytical Solution of the Time Fractional Fokker-Planck Equation

    Directory of Open Access Journals (Sweden)

    Sutradhar T.

    2014-05-01

    Full Text Available A nonperturbative approximate analytic solution is derived for the time fractional Fokker-Planck (F-P equation by using Adomian’s Decomposition Method (ADM. The solution is expressed in terms of Mittag- Leffler function. The present method performs extremely well in terms of accuracy, efficiency and simplicity.

  9. Similarity solutions for radiation in time-dependent relativistic flows

    CERN Document Server

    Lucy, L B

    2004-01-01

    Exact analytic solutions are derived for radiation in time-dependent relativistic flows. The flows are spherically-symmetric homologous explosions or implosions of matter with a grey extinction coefficient. The solutions are suitable for testing numerical transfer codes, and this is illustrated for a fully relativistic Monte Carlo code.

  10. A NEW SOLUTION MODEL OF NONLINEAR DYNAMIC LEAST SQUARE ADJUSTMENT

    Institute of Scientific and Technical Information of China (English)

    陶华学; 郭金运

    2000-01-01

    The nonlinear least square adjustment is a head object studied in technology fields. The paper studies on the non-derivative solution to the nonlinear dynamic least square adjustment and puts forward a new algorithm model and its solution model. The method has little calculation load and is simple. This opens up a theoretical method to solve the linear dynamic least square adjustment.

  11. Twisting singular solutions of Betheʼs equations

    Science.gov (United States)

    Nepomechie, Rafael I.; Wang, Chunguang

    2014-12-01

    The Bethe equations for the periodic XXX and XXZ spin chains admit singular solutions, for which the corresponding eigenvalues and eigenvectors are ill-defined. We use a twist regularization to derive conditions for such singular solutions to be physical, in which case they correspond to genuine eigenvalues and eigenvectors of the Hamiltonian.

  12. On the solutions of fractional reaction-diffusion equations

    Directory of Open Access Journals (Sweden)

    Jagdev Singh

    2013-05-01

    Full Text Available In this paper, we obtain the solution of a fractional reaction-diffusion equation associated with the generalized Riemann-Liouville fractional derivative as the time derivative and Riesz-Feller fractional derivative as the space-derivative. The results are derived by the application of the Laplace and Fourier transforms in compact and elegant form in terms of Mittag-Leffler function and H-function. The results obtained here are of general nature and include the results investigated earlier by many authors.

  13. Approximate Analytical Solution for Nonlinear System of Fractional Differential Equations by BPs Operational Matrices

    Directory of Open Access Journals (Sweden)

    Mohsen Alipour

    2013-01-01

    Full Text Available We present two methods for solving a nonlinear system of fractional differential equations within Caputo derivative. Firstly, we derive operational matrices for Caputo fractional derivative and for Riemann-Liouville fractional integral by using the Bernstein polynomials (BPs. In the first method, we use the operational matrix of Caputo fractional derivative (OMCFD, and in the second one, we apply the operational matrix of Riemann-Liouville fractional integral (OMRLFI. The obtained results are in good agreement with each other as well as with the analytical solutions. We show that the solutions approach to classical solutions as the order of the fractional derivatives approaches 1.

  14. The Fixed-Point of Solution and its Derivative of the Higher Order Linear Differential Equation with Meromorphic Function Coefficients%高阶亚纯函数系数微分方程的解及其导数的不动点

    Institute of Scientific and Technical Information of China (English)

    周凤麟; 徐洪焱

    2012-01-01

    This paper investigates the properties of the fixed-point of solution f(≠ 0) and its derivative f(I)(I = 1,2, · · ·) of higher order linear differential equationf(k) + Ak-1 (z)f(k-1) + · · · + A1(z)f' + A0(z)f = 0where Aj(z)(J = 0,1, · · · , k - 1) are meromorphic functions. And we obtain λP+1(f -z) = λP+1(f' -z) = λP+1(f" -z) = σp+1(f) ≥ σp(A0)when δ(∞,B) > 0, and max{I(A1),I(A2),· · · ,I(Ak-1)} < I{A0) = p or I(Aj) = p,0 < max{σp(A1),σp(A2),· · · ,σp(Ak-1)} < σp(A0) < ∞, p ∈N+ := N\\{0}. The theorems of this paper improve the previous results given by Chen, Belaidi.%研究了高阶线性微分方程f(k)+Ak-1(z)f(k-1)+…+A1(z)f′+A0(z)f=0的非零解f,及其一阶、二阶导数f(i)(i=1,2)的不动点性质,这里Aj(z)(j=0,1,…,k-1)为亚纯函数,得到了若δ(∞,A0)>0,且满足max{i(A1),i(A2),…,i(Ak-1)}<i(A0)=p或者i(Aj)=p,0<max{σp(A1),σp(A2),…,σp(Ak-1)}<σp(A0)<∞有(-λ)p+1(f-z).=(-λ)p+1(f〃-z)=(λ)p+1(f″-z)=σp+1(f)≥σp(A0)其中p∈N+∶=N\\{0}.所得结果改进了陈宗煊,Bela(i)di等人的结果.

  15. Multiple optimal solutions to a sort of nonlinear optimization problem

    Institute of Scientific and Technical Information of China (English)

    Xue Shengjia

    2007-01-01

    The optimization problem is considered in which the objective function is pseudolinear(both pseudoconvex and pseudoconcave) and the constraints are linear. The general expression for the optimal solutions to the problem is derived with the representation theorem of polyhedral sets, and the uniqueness condition of the optimal solution and the computational procedures to determine all optimal solutions ( ifthe uniqueness condition is not satisfied ) are provided. Finally, an illustrative example is also given.

  16. Approximate solutions for fractured wells producing layered reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Bennett, C.O.; Reynolds, A.C.; Raghavan, R.

    1983-01-01

    New analytical solutions for the response at a well intercepting a layered reservoir are derived. The well is assumed to produce at a constant rate or at a constant pressure. Reservoir systems with and without interlayer communication were examined. The utility of these solutions is documented. An increased physical understanding of fractured wells in layered reservoirs was obtained from these solutions. The influence of vertical variations in fracture conductivity is considered also. 15 references.

  17. Testing of solutions for the Boussinesq wave equations on a solution of a potential tsunami model with ``simple'' source

    Science.gov (United States)

    Sekerzh-Zen'kovich, S. Ya.

    2015-10-01

    The Cauchy problem for the wave equations of Boussinesq type is treated by considering the initial conditions taken from the solution of generalized Cauchy problem for the potential model of tsunami with some "simple" impulsive source under the assumption that the depth of the liquid is constant. The solutions of the problem under consideration are derived in the form of a single integral giving the wave height at every point of observation at any time moment after the pulsed action of the source. The results of comparing the time history of the the height of tsunami waves at different distances from the source for different values of its characteristic radius (these histories are calculated using two solutions, namely, the solution derived here and the solution known for the potential tsunami model) are described. Conclusions concerning the accuracy of the tested solutions are made.

  18. Perfect Derived Propagators

    CERN Document Server

    Schulte, Christian

    2008-01-01

    When implementing a propagator for a constraint, one must decide about variants: When implementing min, should one also implement max? Should one implement linear equations both with and without coefficients? Constraint variants are ubiquitous: implementing them requires considerable (if not prohibitive) effort and decreases maintainability, but will deliver better performance. This paper shows how to use variable views, previously introduced for an implementation architecture, to derive perfect propagator variants. A model for views and derived propagators is introduced. Derived propagators are proved to be indeed perfect in that they inherit essential properties such as correctness and domain and bounds consistency. Techniques for systematically deriving propagators such as transformation, generalization, specialization, and channeling are developed for several variable domains. We evaluate the massive impact of derived propagators. Without derived propagators, Gecode would require 140000 rather than 40000 ...

  19. Solution structure of (+)-discodermolide.

    Science.gov (United States)

    Smith, A B; LaMarche, M J; Falcone-Hindley, M

    2001-03-01

    [structure: see text]. The solution structure of (+)-discodermolide (1) has been determined via 1- and 2-D NMR techniques in conjunction with Monte Carlo conformational analysis. Taken together, the results demonstrate that in solution (+)-discodermolide occupies a helical conformation remarkably similar to the solid state conformation.

  20. Mobile Backhaul Solutions

    Institute of Scientific and Technical Information of China (English)

    Li Mo; Fei Yuan; Jian Yang

    2011-01-01

    In this paper, we give an overview of mobile backhaul solutions and propose an MPLS-centered solution that takes intoaccount timing synchronization, OAM, and protection: We also propose an evolved protection bandwidth allocation mechanism that makes the transport network as efficient as possible.

  1. Relation between the solubility of proteins in aqueous solutions and the second virial coefficient of the solution

    NARCIS (Netherlands)

    Haas, C; Drenth, J; Wilson, WW

    1999-01-01

    Tn recent publications it was pointed out that there is a correlation between the observed values of the solubility of proteins in aqueous solutions and the second virial coefficient of the solution. In this paper we give a theoretical explanation of this relation. The derived theoretical expression

  2. Heat-regulated foaming in surfactant solutions

    Energy Technology Data Exchange (ETDEWEB)

    Pletnev, M.Y.; Eremina, L.D.; Vlasenko, I.G.

    1984-01-01

    This article examines the mechanism of the foam-inhibiting action resulting from the use of propylene oxide derivatives in solutions both of anionic and of nonionic surfactants. The objective is the creation of a detergent composition with heat-regulated foaming, which would foam well at 30-50/sup 0/ and poorly at 80-90/sup 0/, which is the usual temperature of washing machines. It is demonstrated that foaming can be regulated by the variation of the cloud points of solutions with the aid of additions of polypropylene glycols and their alkyl derivatives or block copolymers in solutions of surfactants. Foaming and foam stability decrease sharply above the cloud points of the solutions due to the foam-inhibiting action of the coacervate phase on the coexisting foam-forming solution. The foam inhibition of polypropylene glycols increases and becomes apparent at lower concentrations with the increase of the average molecular weight of the hydrophobic blocks, the increase of their relative content (in block copolymers with oxyethylene groups), and upon the introduction of alkyl groups.

  3. Cosmological Models with Fractional Derivatives and Fractional Action Functional

    Institute of Scientific and Technical Information of China (English)

    V.K. Shchigolev

    2011-01-01

    Cosmological models of a scalar field with dynamical equations containing fractional derivatives or derived from the Einstein-Hilbert action of fractional order, are constructed. A number of exact solutions to those equations of fractional cosmological models in both eases is given.

  4. Bolting Multicenter Solutions

    CERN Document Server

    Bena, Iosif; Katmadas, Stefanos; Turton, David

    2016-01-01

    We introduce a solvable system of equations that describes non-extremal multicenter solutions to six-dimensional ungauged supergravity coupled to tensor multiplets. The system involves a set of functions on a three-dimensional base metric. We obtain a family of non-extremal axisymmetric solutions that generalize the known multicenter extremal solutions, using a particular base metric that introduces a bolt. We analyze the conditions for regularity, and in doing so we show that this family does not include solutions that contain an extremal black hole and a smooth bolt. We determine the constraints that are necessary to obtain smooth horizonless solutions involving a bolt and an arbitrary number of Gibbons-Hawking centers.

  5. Bolting multicenter solutions

    Science.gov (United States)

    Bena, Iosif; Bossard, Guillaume; Katmadas, Stefanos; Turton, David

    2017-01-01

    We introduce a solvable system of equations that describes non-extremal multicenter solutions to six-dimensional ungauged supergravity coupled to tensor multiplets. The system involves a set of functions on a three-dimensional base metric. We obtain a family of non-extremal axisymmetric solutions that generalize the known multicenter extremal solutions, using a particular base metric that introduces a bolt. We analyze the conditions for regularity, and in doing so we show that this family does not include solutions that contain an extremal black hole and a smooth bolt. We determine the constraints that are necessary to obtain smooth horizonless solutions involving a bolt and an arbitrary number of Gibbons-Hawking centers.

  6. Exact solutions for Weyl fermions with gravity

    Energy Technology Data Exchange (ETDEWEB)

    Cianci, Roberto; Fabbri, Luca; Vignolo, Stefano [Universita di Genova, DIME Sez. Metodi e Modelli Matematici, Genoa (Italy)

    2015-10-15

    We consider the single-handed spinor field in interaction with its own gravitational field described by the set of field equations given by the Weyl field equations written in terms of derivatives that are covariant with respect to the gravitational connection plus Einstein field equations soured with the energy tensor of the spinor: for the Weyl spinor and the ensuing spacetime of Weyl-Lewis-Papapetrou structure, we find all exact solutions. The obtained solution for the metric tensor is that of a PP-wave spacetime, while the spinor field is a flag-dipole. (orig.)

  7. Generating Solutions to the Einstein - Maxwell Equations

    CERN Document Server

    Contopoulos, I G; Kleidis, K; Papadopoulos, D B; Witten, L

    2015-01-01

    The Einstein-Maxwell (E-M) equations in a curved spacetime that admits at least one Killing vector are derived, from a Lagrangian density adapted to symmetries. In this context, an auxiliary space of potentials is introduced, in which, the set of potentials associated to an original (seed) solution of the E-M equations are transformed to a new set, either by continuous transformations or by discrete transformations. In this article, continuous transformations are considered. Accordingly, originating from the so-called $\\gamma_A$-metric, other exact solutions to the E-M equations are recovered and discussed.

  8. Robinson-Trautman solutions to Einstein's equations

    Science.gov (United States)

    Davidson, William

    2017-02-01

    Solutions to Einstein's equations in the form of a Robinson-Trautman metric are presented. In particular, we derive a pure radiation solution which is non-stationary and involves a mass m, The resulting spacetime is of Petrov Type II A special selection of parametric values throws up the feature of the particle `rocket', a Type D metric. A suitable transformation of the complex coordinates allows the metrics to be expressed in real form. A modification, by setting m to zero, of the Type II metric thereby converting it to Type III, is then shown to admit a null Einstein-Maxwell electromagnetic field.

  9. Generalization of the Randall-Sundrum solution

    Science.gov (United States)

    Kisselev, A. V.

    2016-08-01

    The generalization of the Randall-Sundrum solution for the warp factor exp ⁡ [ σ (y) ] in the scenario with one extra coordinate y, non-factorizable space-time geometry and two branes is obtained. It is shown that the function obtained σ (y) is symmetric with respect to an interchange of two branes. It also obeys the orbifold symmetry y → - y and explicitly reproduces jumps of its derivative on both branes. This solution is defined by the Einstein-Hilbert's equations up to a constant C. It is demonstrated that different values of C result in theories with quite different spectra of the Kaluza-Klein gravitons.

  10. Equilibrium solutions of the shallow water equations

    CERN Document Server

    Weichman, P B; Weichman, Peter B.; Petrich, Dean M.

    2000-01-01

    A statistical method for calculating equilibrium solutions of the shallow water equations, a model of essentially 2-d fluid flow with a free surface, is described. The model contains a competing acoustic turbulent {\\it direct} energy cascade, and a 2-d turbulent {\\it inverse} energy cascade. It is shown, nonetheless that, just as in the corresponding theory of the inviscid Euler equation, the infinite number of conserved quantities constrain the flow sufficiently to produce nontrivial large-scale vortex structures which are solutions to a set of explicitly derived coupled nonlinear partial differential equations.

  11. Horizon Supertranslation and Degenerate Black Hole Solution

    CERN Document Server

    Cai, Rong-Gen; Zhang, Yun-Long

    2016-01-01

    In this note we first review the degenerate vacua arising from the BMS symmetries. According to the discussion in [1] one can define BMS-analogous supertranslation and superrotation for spacetime with black hole in Gaussian null coordinates. In the leading and subleading orders of near horizon approximation, the infinitely degenerate black hole solutions are derived by considering Einstein equations with or without cosmological constant, and they are related to each other by the diffeomorphism generated by horizon supertranslation. Higher order results and degenerate Rindler horizon solutions also are given in appendices.

  12. Multivariate statistics exercises and solutions

    CERN Document Server

    Härdle, Wolfgang Karl

    2015-01-01

    The authors present tools and concepts of multivariate data analysis by means of exercises and their solutions. The first part is devoted to graphical techniques. The second part deals with multivariate random variables and presents the derivation of estimators and tests for various practical situations. The last part introduces a wide variety of exercises in applied multivariate data analysis. The book demonstrates the application of simple calculus and basic multivariate methods in real life situations. It contains altogether more than 250 solved exercises which can assist a university teacher in setting up a modern multivariate analysis course. All computer-based exercises are available in the R language. All R codes and data sets may be downloaded via the quantlet download center  www.quantlet.org or via the Springer webpage. For interactive display of low-dimensional projections of a multivariate data set, we recommend GGobi.

  13. Axisymmetric fundamental solutions for a finite layer with impeded boundaries

    Institute of Scientific and Technical Information of China (English)

    程泽海; 陈云敏; 凌道盛; 唐晓武

    2003-01-01

    Axisymmetric fundamental solutions that are applied in the consolidation calculations of a finite clay layer with impeded boundaries were derived. Laplace and Hankel integral transforms were utilized with respect to time and radial coordinates, respectively in the analysis. The derivation of fundamental solutions considers two boundary-value problems involving unit point loading and ring loading in the vertical. The solutions are extended to circular distributed and strip distributed normal load. The computation and analysis of settlements, vertical total stress and excess pore pressure in the consolidation layer subject to circular loading are presented.

  14. The Adsorption Effect of Quaternized Chitosan Derivatives on Bile Acid

    Institute of Scientific and Technical Information of China (English)

    Shu Xian MENG; Ya Qing FENG; Wen Jin LI; Cai Xia YIN; Jin Ping DENG

    2006-01-01

    Three quaternized chitosan derivatives were synthesized and their adsorption performance of bile acid from aqueous solution was studied. The adsorption capacities and rates of bile acid onto quaternized chitosan derivatives were evaluated. The kinetic experimental data properly correlated with the second-order kinetic model, which indicated that the chemical sorption is the rate-limiting step. The results showed that the quaternized chitosan derivatives are favorable adsorbents for bile acid.

  15. Comment on the Exterior Solutions and Their Geometry in Scalar-Tensor Theories of Gravity

    Science.gov (United States)

    Tsuchida, T.; Watanabe, K.

    1999-01-01

    We study series of stationary solutions with asymptotic flatness properties in the Einstein-Maxwell-free scalar system because they are locally equivalent to the exterior solutions in some class of scalar-tensor theories of gravity. First, we classify spherical exterior solutions into two types of solutions, an apparently black hole type solution and an apparently worm hole type solution. The solutions contain three parameters, and we clarify their physical significance. Second, we reduce the field equations for the axisymmetric exterior solutions. We find that the reduced equations are partially the same as the Ernst equations. As simple examples, we derive new series of static, axisymmetric exterior solutions, which correspond to Voorhees's solutions. We then establish a non-trivial relation between the spherical exterior solutions and our new solutions. Finally, since null geodesics have conformally invariant properties, we study the local geometry of the exterior solutions by using the optical scalar equations and find some anomalous behavior of the null geodesics.

  16. Comment on the exterior solutions and their geometry in scalar-tensor theories of gravity

    CERN Document Server

    Tsuchida, T; Tsuchida, Tooru; Watanabe, Kazuya

    1999-01-01

    We study series of the stationary solutions with asymptotic flatness properties in the Einstein-Maxwell-free scalar system because they are locally equivalent with the exterior solutions in some class of the scalar-tensor theories of gravity. First, we classify spherical exterior solutions into two types of the solutions, an apparently black hole type solution and an apparently worm hole type solution. The solutions contain three parameters, and we clarify their physical significance. Second, we reduce the field equations for the axisymmetric exterior solutions. We find that the reduced equations are partially the same as the Ernst equations. As simple examples, we derive new series of the static, axisymmetric exterior solutions, which correspond to Voorhees's solutions. We then show a non-trivial relation between the spherical exterior solutions and our new solutions. Finally, since null geodesics have conformally invariant properties, we study the local geometry of the exterior solutions by using the optica...

  17. Scale up of proteoliposome derived Cochleate production.

    Science.gov (United States)

    Zayas, Caridad; Bracho, Gustavo; Lastre, Miriam; González, Domingo; Gil, Danay; Acevedo, Reinaldo; del Campo, Judith; Taboada, Carlos; Solís, Rosa L; Barberá, Ramón; Pérez, Oliver

    2006-04-12

    Cochleate are highly stable structures with promising immunological features. Cochleate structures are usually obtaining from commercial lipids. Proteoliposome derived Cochleate are derived from an outer membrane vesicles of Neisseria meningitidis B. Previously, we obtained Cochleates using dialysis procedures. In order to increase the production process, we used a crossflow system (CFS) that allows easy scale up to obtain large batches in an aseptic environment. The raw material and solutions used in the production process are already approved for human application. This work demonstrates that CFS is very efficient process to obtain Cochleate structures with a yield of more than 80% and the immunogenicity comparable to that obtained by dialysis membrane.

  18. Financial Derivatives in China

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Francis Repka sees bright prospects for the future development of the financial derivatives market in China. Repka,Vice President of the Asian Bond Finance Department of Societe Generale, says the situation in France just after the birth of derivatives was very similar to the situation in China today.

  19. Numerical Integration with Derivatives

    Institute of Scientific and Technical Information of China (English)

    Hu Cheng

    2006-01-01

    A new formula with derivatives for numerical integration was presented. Based on this formula and the Richardson extrapolation process, a numerical integration method was established. It can converge faster than the Romberg's. With the same accuracy, the computation of the new numerical integration with derivatives is only half of that of Romberg's numerical integration.

  20. 4-Aminoquinoline derivatives

    DEFF Research Database (Denmark)

    Singh, Shailja; Agarwal, Drishti; Sharma, Kumkum;

    2016-01-01

    Synthetic quinoline derivatives continue to be considered as candidates for new drug discovery if they act against CQ-resistant strains of malaria even after the widespread emergence of resistance to CQ. In this study, we explored the activities of two series of new 4-aminoquinoline derivatives...

  1. LR-PARSING DERIVED

    NARCIS (Netherlands)

    Hesselink, Wim H.

    1992-01-01

    The LR(k)-parsing algorithm is derived, i.e., presented and proved as an interplay between program development and parsing theory. The program development uses invariants and the new concept of weakest angelic precondition. The parsing theory involved relates rightmost derivability to three other tr

  2. Professional Hadoop solutions

    CERN Document Server

    Lublinsky, Boris; Yakubovich, Alexey

    2013-01-01

    The go-to guidebook for deploying Big Data solutions with Hadoop Today's enterprise architects need to understand how the Hadoop frameworks and APIs fit together, and how they can be integrated to deliver real-world solutions. This book is a practical, detailed guide to building and implementing those solutions, with code-level instruction in the popular Wrox tradition. It covers storing data with HDFS and Hbase, processing data with MapReduce, and automating data processing with Oozie. Hadoop security, running Hadoop with Amazon Web Services, best practices, and automating Hadoop processes i

  3. Taxation of Derivatives

    DEFF Research Database (Denmark)

    Dyppel, Katja Joo

    2013-01-01

    in the Danish tax legislation. However, contracts known as forwards (terminskontrakter) and options (aftaler om køberetter og salgsretter) are generally included in the term financials contracts covered by the Danish Act on Taxation of Gains and Losses on Claims and Debt. The main part of the analysis deals...... with the scope of sections 29-33 of the Danish Act on Taxation of Gains and Losses on Claims and Debt and the tax consequences for the covered financial contracts. In the analysis of taxation of derivatives, the fundamental issues of qualification and tax treatment of the instruments are dealt with.......The main objective for this thesis is to analyse and systematise the Danish legislation on taxation of derivatives. According to financial terminology, a derivative is a financial instrument. Its value is derived from changes in the value of one or more underlying assets.The most common derivatives...

  4. Time—periodic weak solutions

    Directory of Open Access Journals (Sweden)

    Eliana Henriques de Brito

    1990-01-01

    Full Text Available In continuing from previous papers, where we studied the existence and uniqueness of the global solution and its asymptotic behavior as time t goes to infinity, we now search for a time-periodic weak solution u(t for the equation whose weak formulation in a Hilbert space H isddt(u′,v+δ(u′,v+αb(u,v+βa(u,v+(G(u,v=(h,vwhere: ′=d/dt; (′ is the inner product in H; b(u,v, a(u,v are given forms on subspaces U⊂W, respectively, of H; δ>0, α≥0, β≥0 are constants and α+β>0; G is the Gateaux derivative of a convex functional J:V⊂H→[0,∞ for V=U, when α>0 and V=W when α=0, hence β>0; v is a test function in V; h is a given function of t with values in H.

  5. Solution to enterprise resource planning; ERP solution

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, M.; Okajima, E. [Fuji Electric Co. Ltd., Tokyo (Japan)

    2000-05-10

    The environment around enterprises has greatly changed in sluggish Japanese economy since the bubble burst. To make the total enterprise activity efficient and speedy and to flexibly meet changes in enterprise environments and diversified customer needs, enterprises are planning to shift the existing methods to enterprise resource planning (ERP) as the infrastructure of strategic enterprise management. This paper describes the solution to ERP which is package software for the key system, the core of enterprise basic business, and also an application example, giving guideline for restructuring the basic business. (author)

  6. New Soliton-like Solutions and Multi-soliton Structures for Broer-Kaup System with Variable Coefficients

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    By using the further extended tanh method [Phys. Lett. A 307 (2003) 269; Chaos, Solitons & Fractals 17(2003) 669] to the Broer-Kaup system with variable coefficients, abundant new soliton-like solutions and multi-soliton-like solutions are derived. Based on the derived multi-soliton-like solutions which contain arbitrary functions, some interesting multi-soliton structures are revealed.

  7. The Conductivity of Solutions.

    Science.gov (United States)

    Rayner-Canham, Geoff

    1993-01-01

    Presents historical background and modern explanations for the popular demonstration of showing conductivity of solutions through the insertion of a light-bulb conductivity tester into deionized water and water with salt in it. (PR)

  8. Convergent Aeronautics Solutions Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The Convergent Aeronautics Solutions (CAS) Project uses short-duration activities to establish early-stage concept and technology feasibility for high-potential...

  9. Piezoelectric Energy Harvesting Solutions

    Directory of Open Access Journals (Sweden)

    Renato Caliò

    2014-03-01

    Full Text Available This paper reviews the state of the art in piezoelectric energy harvesting. It presents the basics of piezoelectricity and discusses materials choice. The work places emphasis on material operating modes and device configurations, from resonant to non-resonant devices and also to rotational solutions. The reviewed literature is compared based on power density and bandwidth. Lastly, the question of power conversion is addressed by reviewing various circuit solutions.

  10. Brainmining emotive lateral solutions

    Directory of Open Access Journals (Sweden)

    Theodore Scaltsas

    2016-07-01

    Full Text Available BrainMining is a theory of creative thinking that shows how we should exploit the mind’s spontaneous natural disposition to use old solutions to address new problems – our Anchoring Cognitive Bias. BrainMining develops a simple and straightforward method to transform recalcitrant problems into types of problems which we have solved before, and then apply an old type of solution to them. The transformation makes the thinking lateral by matching up disparate types of problem and solution. It emphasises the role of emotive judgements that the agent makes, when she discerns whether a change of the values or the emotions and feelings in a situation, which would expand the space of solutions available for the problem at hand, would be acceptable or appropriate in the situation. A lateral solution for an intractable problem is thus spontaneously brainmined from the agent’s old solutions, to solve a transformed version of the intractable problem, possibly involving changes in the value system or the emotional profile of the situation, which the agent judges, emotively, will be acceptable, and even appropriate in the circumstances.

  11. New Axisymmetric Stationary Solutions of Five-dimensional Vacuum Einstein Equations with Asymptotic Flatness

    CERN Document Server

    Mishima, T; Mishima, Takashi; Iguchi, Hideo

    2006-01-01

    New axisymmetric stationary solutions of the vacuum Einstein equations in five-dimensional asymptotically flat spacetimes are given by solitonic solution-generating techniques. We show the equivalence between these solutions and the four-dimensional multi-solitonic ones derived from particular class of four-dimensional Weyl solutions. The solutions constructed here include different black rings from the ones obtained by Emparan and Reall.

  12. STUDY ON EXACT ANALYTICAL SOLUTIONS FOR TWO SYSTEMS OF NONLINEAR EVOLUTION EQUATIONS

    Institute of Scientific and Technical Information of China (English)

    闫振亚; 张鸿庆

    2001-01-01

    The homogeneous balance method was improved and applied to two systems of nonlinear evolution equations. As a result, several families of exact analytic solutions are derived by some new ansatzs. These solutions contain Wang's and Zhang's results and other new types of analytical solutions, such as rational fraction solutions and periodic solutions. The way can also be applied to solve more nonlinear partial differential equations.

  13. Oxidative rearrangements of tricyclic vinylcyclobutane derivatives

    OpenAIRE

    Grota, Juliane; Mattay, Jochen; Piech, Krzysztof; Bally, Thomas

    2006-01-01

    Three tricyclic vinylcyclobutanes (3-methylenetricyclo[5.3.0.02,6]decanes 1-3) have been subjected to ionization by photoinduced electron transfer in solution and by X-irradiation in Ar matrices. All three compounds undergo oxidative cycloreversion; the cleavage of the four-membered ring, however, occurs in a different direction depending on the presence of a methyl group in position 6 of the tricyclic framework. In those derivatives, cycloreversion is found to lead to 1-methyl-8-methylene-1,...

  14. Particle production in higher derivative theory

    Indian Academy of Sciences (India)

    G P Singh; A Beesham; R V Deshpande

    2000-05-01

    The effect of particle production on the evolution of the spatially flat Friedmann–Lemaitre–Robertson–Walker cosmological model during the early stages of the universe is analysed in the framework of higher derivative theory. The universe has been considered as an open thermodynamic system where particle production gives rise to a supplementary negative creation pressure in addition to the thermodynamic pressure. The dynamical behaviour of both exponential as well as power law solutions have been discussed.

  15. Robinson-Trautman solution with nonlinear electrodynamics

    Energy Technology Data Exchange (ETDEWEB)

    Tahamtan, T.; Svitek, O. [Charles University in Prague, Faculty of Mathematics and Physics, Institute of Theoretical Physics, Prague 8 (Czech Republic)

    2016-06-15

    Explicit Robinson-Trautman solutions with an electromagnetic field satisfying nonlinear field equations are derived and analyzed. The solutions are generated from the spherically symmetric ones. In all studied cases the electromagnetic field singularity is removed while the gravitational one persists. The models resolving the curvature singularity in spherically symmetric spacetimes could not be generalized to the Robinson-Trautman geometry using the generating method developed in this paper, which indicates that the removal of a singularity in the associated spherically symmetric case might be just a consequence of high symmetry. We show that the obtained solutions are generally of algebraic type II and reduce to type D in spherical symmetry. Asymptotically they tend to the spherically symmetric case as well. (orig.)

  16. Periodic solutions of Volterra integral equations

    Directory of Open Access Journals (Sweden)

    M. N. Islam

    1988-01-01

    Full Text Available Consider the system of equationsx(t=f(t+∫−∞tk(t,sx(sds,           (1andx(t=f(t+∫−∞tk(t,sg(s,x(sds.       (2Existence of continuous periodic solutions of (1 is shown using the resolvent function of the kernel k. Some important properties of the resolvent function including its uniqueness are obtained in the process. In obtaining periodic solutions of (1 it is necessary that the resolvent of k is integrable in some sense. For a scalar convolution kernel k some explicit conditions are derived to determine whether or not the resolvent of k is integrable. Finally, the existence and uniqueness of continuous periodic solutions of (1 and (2 are btained using the contraction mapping principle as the basic tool.

  17. Complete Solutions to Extended Stokes' Problems

    Directory of Open Access Journals (Sweden)

    Chi-Min Liu

    2008-01-01

    Full Text Available The main object of the present study is to theoretically solve the viscous flow of either a finite or infinite depth, which is driven by moving plane(s. Such a viscous flow is usually named as Stokes' first or second problems, which indicates the fluid motion driven by the impulsive or oscillating motion of the boundary, respectively. Traditional Stokes' problems are firstly revisited, and three extended problems are subsequently examined. Using some mathematical techniques and integral transforms, complete solutions which can exactly capture the flow characteristics at any time are derived. The corresponding steady-state and transient solutions are readily determined on the basis of complete solutions. Current results have wide applications in academic researches and are of significance for future studies taking more boundary conditions and non-Newtonian fluids into account.

  18. A time dependent solution for the operation of ion chambers in a high ionization background

    CERN Document Server

    Velissaris, C

    2005-01-01

    We have derived a time dependent solution describing the development of space charge inside an ion chamber subjected to an externally caused ionization rate N. The solution enables the derivation of a formula that the operational parameters of the chamber must satisfy for saturation free operation. This formula contains a correction factor to account for the finite duration of the ionization rate N.

  19. Exact Solutions for a Nonisospectral and Variable-Coefficient KdV Equation

    Institute of Scientific and Technical Information of China (English)

    DENG Shu-Fang

    2005-01-01

    The bilinear form for a nonisospectral and variable-coefficient KdV equation is obtained and some exact soliton solutions are derived through Hirota method and Wronskian technique. We also derive the bilinear transformation from its Lax pairs and find solutions with the help of the obtained bilinear transformation.

  20. Student Solutions Manual to accompany Understanding Physics

    Science.gov (United States)

    Cummings, Karen; Laws, Priscilla W.; Redish, Edward F.; Cooney, Patrick J.; Christman, J. Richard

    2004-05-01

    Work more effectively and check solutions as you go along with the text! This Student Solutions Manual is designed for use with Cummings' Understanding Physics. Its primary purpose is to show readers by example how to solve various types of problems given at the end of each chapter in the text. Most of the solutions start from definitions or fundamental relationships and the final equation is derived. This technique highlights the fundamentals and at the same time gives readers the opportunity to review the mathematical steps required to obtain a solution. The mere plugging of numbers into equations derived in the text is avoided for the most part. Readers will learn to examine any assumptions that are made in setting up and solving each problem. Using an interactive strategy, Understanding Physics provides a hands-on introduction to the fundamentals of physics. Built on the foundations of Halliday, Resnick, and Walker's Fundamentals of Physics, 6th Edition, this text represents the latest methods in physics instruction. Incorporating new approaches based on Physics Education Research (PER), this text is designed for courses that use computer-based laboratory tools, and promote Activity Based Physics in lectures, labs, and recitations.

  1. Passive House Solutions

    Energy Technology Data Exchange (ETDEWEB)

    Strom, I.; Joosten, L.; Boonstra, C. [DHV Sustainability Consultants, Eindhoiven (Netherlands)

    2006-05-15

    PEP stands for 'Promotion of European Passive Houses' and is a consortium of European partners, supported by the European Commission, Directorate General for Energy and Transport. In this working paper an overview is given of Passive House solutions. An inventory has been made of Passive House solutions for new build residences applied in each country. Based on this, the most common basic solutions have been identified and described in further detail, including the extent to which solutions are applied in common and best practice and expected barriers for the implementation in each country. An inventory per country is included in the appendix. The analysis of Passive House solutions in partner countries shows high priority with regard to the performance of the thermal envelope, such as high insulation of walls, roofs, floors and windows/ doors, thermal bridge-free construction and air tightness. Due to the required air tightness, special attention must be paid to indoor air quality through proper ventilation. Finally, efficient ((semi-)solar) heating systems for combined space and DHW heating still require a significant amount of attention in most partner countries. Other basic Passive House solutions show a smaller discrepancy with common practice and fewer barriers have been encountered in partner countries. In the next section, the general barriers in partner countries have been inventoried. For each type of barrier a suggested approach has been given. Most frequently encountered barriers in partner countries are: limited know-how; limited contractor skills; and acceptation of Passive Houses in the market. Based on the suggested approaches to overcoming barriers, this means that a great deal of attention must be paid to providing practical information and solutions to building professionals, providing practical training to installers and contractors and communication about the Passive House concept to the market.

  2. Boundedness of solutions for reversible system via Moser's twist theorem

    Science.gov (United States)

    Piao, Daxiong; Li, Wenling

    2008-05-01

    In this paper we consider the problem of the boundedness of all solutions for the reversible system It is shown that all the solutions are bounded provided that the ai(t) (0[less-than-or-equals, slant]i[less-than-or-equals, slant][(n-1)/2]) are of bounded variation in [0,1] and the derivatives of bj(t) and ai(t) are Lipschitzian. It is also shown that there exist ai's being discontinuous everywhere such that all solutions of the equation are bounded. This implies that the continuity of ai's is not necessary for the boundedness of solutions of the equation.

  3. On the solution of fractional evolution equations

    Energy Technology Data Exchange (ETDEWEB)

    Kilbas, Anatoly A [Department of Mathematics and Mechanics, Belarusian State University, 220050 Minsk (Belarus); Pierantozzi, Teresa [Departamento de Matematica Aplicada, Facultad de Informatica, Universidad Complutense, E-28040 Madrid (Spain); Trujillo, Juan J [Departamento de Analisis Matematico, Universidad de la Laguna, 38271 La Laguna-Tenerife (Spain); Vazquez, Luis [Departamento de Matematica Aplicada, Facultad de Informatica, Universidad Complutense, E-28040 Madrid (Spain)

    2004-03-05

    This paper is devoted to the solution of the bi-fractional differential equation ({sup C}D{sup {alpha}}{sub t}u)(t, x) = {lambda}({sup L}D{sup {beta}}{sub x}u)(t, x) (t>0, -{infinity} 0 and {lambda} {ne} 0, with the initial conditions lim{sub x{yields}}{sub {+-}}{sub {infinity}} u(t,x) = 0 u(0+,x)=g(x). Here ({sup C}D{sup {alpha}}{sub t}u)(t, x) is the partial derivative coinciding with the Caputo fractional derivative for 0 < {alpha} < 1 and with the usual derivative for {alpha} = 1, while ({sup L}D{sup {beta}}{sub x}u)(t, x)) is the Liouville partial fractional derivative ({sup L}D{sup {beta}}{sub t}u)(t, x)) of order {beta} > 0. The Laplace and Fourier transforms are applied to solve the above problem in closed form. The fundamental solution of these problems is established and its moments are calculated. The special case {alpha} = 1/2 and {beta} = 1 is presented, and its application is given to obtain the Dirac-type decomposition for the ordinary diffusion equation.

  4. Amphetamine derivative related deaths.

    Science.gov (United States)

    Lora-Tamayo, C; Tena, T; Rodríguez, A

    1997-02-28

    Amphetamine its methylendioxy (methylendioxyamphetamine methylenedioxymethylamphetamine, methylenedioxyethylamphetamine) and methoxy derivatives (p-methoxyamphetamine and p-methoxymethylamphetamine) are widely abused in Spanish society. We present here the results of a systematic study of all cases of deaths brought to the attention of the Madrid department of the Instituto Nacional de Toxicologia from 1993 to 1995 in which some of these drugs have been found in the cadaveric blood. The cases were divided into three categories: amphetamine and derivatives, amphetamines and alcohol, amphetamines and other drugs. Data on age, sex, clinical symptoms, morphological findings, circumstances of death, when known, and concentration of amphetamine derivatives, alcohol and other drugs in blood are given for each group. The information provided here may prove to be useful for the forensic interpretation of deaths which are directly or indirectly related to abuse of amphetamine derivatives.

  5. Maximum likelihood molecular clock comb: analytic solutions.

    Science.gov (United States)

    Chor, Benny; Khetan, Amit; Snir, Sagi

    2006-04-01

    Maximum likelihood (ML) is increasingly used as an optimality criterion for selecting evolutionary trees, but finding the global optimum is a hard computational task. Because no general analytic solution is known, numeric techniques such as hill climbing or expectation maximization (EM), are used in order to find optimal parameters for a given tree. So far, analytic solutions were derived only for the simplest model--three taxa, two state characters, under a molecular clock. Four taxa rooted trees have two topologies--the fork (two subtrees with two leaves each) and the comb (one subtree with three leaves, the other with a single leaf). In a previous work, we devised a closed form analytic solution for the ML molecular clock fork. In this work, we extend the state of the art in the area of analytic solutions ML trees to the family of all four taxa trees under the molecular clock assumption. The change from the fork topology to the comb incurs a major increase in the complexity of the underlying algebraic system and requires novel techniques and approaches. We combine the ultrametric properties of molecular clock trees with the Hadamard conjugation to derive a number of topology dependent identities. Employing these identities, we substantially simplify the system of polynomial equations. We finally use tools from algebraic geometry (e.g., Gröbner bases, ideal saturation, resultants) and employ symbolic algebra software to obtain analytic solutions for the comb. We show that in contrast to the fork, the comb has no closed form solutions (expressed by radicals in the input data). In general, four taxa trees can have multiple ML points. In contrast, we can now prove that under the molecular clock assumption, the comb has a unique (local and global) ML point. (Such uniqueness was previously shown for the fork.).

  6. Discrete derivative estimation in LISA Pathfinder data reduction

    CERN Document Server

    Ferraioli, Luigi; Vitale, Stefano

    2009-01-01

    Data analysis for the LISA Technology package (LTP) experiment to be flown aboard the LISA Pathfinder mission requires the solution of the system dynamics for the calculation of the force acting on the test masses (TMs) starting from interferometer position data. The need for a solution to this problem has prompted us to implement a discrete time domain derivative estimator suited for the LTP experiment requirements. We first report on the mathematical procedures for the definition of two methods; the first based on a parabolic fit approximation and the second based on a Taylor series expansion. These two methods are then generalized and incorporated in a more general class of five point discrete derivative estimators. The same procedure employed for the second derivative can be applied to the estimation of the first derivative and of a data smoother allowing defining a class of simple five points estimators for both. The performances of three particular realization of the five point second derivative estimat...

  7. Gorenstein derived functions

    DEFF Research Database (Denmark)

    Holm, Henrik Granau

    2004-01-01

    Over any associative ring R it is standard to derive HomR(􀀀;􀀀) using projective resolutions in the rst variable, or injective resolutions in the second variable, and doing this, one obtains Extn R(􀀀;􀀀) in both cases. We examine the situation where projective...... and injective modules are replaced by Gorenstein projective and Gorenstein injective ones, respectively. Furthermore, we derive the tensor product 􀀀 R 􀀀 using Gorenstein at modules....

  8. Brain derived neurotrophic factor

    DEFF Research Database (Denmark)

    Mitchelmore, Cathy; Gede, Lene

    2014-01-01

    Brain Derived Neurotrophic Factor (BDNF) is a neurotrophin with important functions in neuronal development and neuroplasticity. Accumulating evidence suggests that alterations in BDNF expression levels underlie a variety of psychiatric and neurological disorders. Indeed, BDNF therapies are curre......Brain Derived Neurotrophic Factor (BDNF) is a neurotrophin with important functions in neuronal development and neuroplasticity. Accumulating evidence suggests that alterations in BDNF expression levels underlie a variety of psychiatric and neurological disorders. Indeed, BDNF therapies...

  9. Towards combined global monthly gravity field solutions

    Science.gov (United States)

    Jaeggi, Adrian; Meyer, Ulrich; Beutler, Gerhard; Weigelt, Matthias; van Dam, Tonie; Mayer-Gürr, Torsten; Flury, Jakob; Flechtner, Frank; Dahle, Christoph; Lemoine, Jean-Michel; Bruinsma, Sean

    2014-05-01

    Currently, official GRACE Science Data System (SDS) monthly gravity field solutions are generated independently by the Centre for Space Research (CSR) and the German Research Centre for Geosciences (GFZ). Additional GRACE SDS monthly fields are provided by the Jet Propulsion Laboratory (JPL) for validation and outside the SDS by a number of other institutions worldwide. Although the adopted background models and processing standards have been harmonized more and more by the various processing centers during the past years, notable differences still exist and the users are more or less left alone with a decision which model to choose for their individual applications. This procedure seriously limits the accessibility of these valuable data. Combinations are well established in the area of other space geodetic techniques, such as the Global Navigation Satellite Systems (GNSS), Satellite Laser Ranging (SLR), and Very Long Baseline Interferometry (VLBI). Regularly comparing and combining space-geodetic products has tremendously increased the usefulness of the products in a wide range of disciplines and scientific applications. Therefore, we propose in a first step to mutually compare the large variety of available monthly GRACE gravity field solutions, e.g., by assessing the signal content over selected regions, by estimating the noise over the oceans, and by performing significance tests. We make the attempt to assign different solution characteristics to different processing strategies in order to identify subsets of solutions, which are based on similar processing strategies. Using these subsets we will in a second step explore ways to generate combined solutions, e.g., based on a weighted average of the individual solutions using empirical weights derived from pair-wise comparisons. We will also assess the quality of such a combined solution and discuss the potential benefits for the GRACE and GRACE-FO user community, but also address minimum processing

  10. Numerical methods for evaluating the derivatives of eigenvalues and eigenvectors

    Science.gov (United States)

    Rudisill, C. S.; Chu, Y.-Y.

    1975-01-01

    Two numerical methods are presented for computing the derivatives of eigenvalues and eigenvectors which do not require complete solution of the eigenvalue problem if only a few derivatives are sought. The 'iterative' method may be used to find the first derivative of one or all of the eigenvectors together with the second derivative of their eigenvalues in a self-adjoint system. If the left- and right-hand eigenvectors are known, the first derivative of the eigenvector corresponding to the largest eigenvalue and the second derivative of the largest eigenvalue may be obtained for a nonself-adjoint system. The 'algebraic' method may be used to find all orders of the derivatives, provided they exist, without requiring the left-hand eigenvectors.

  11. Derivation of a poroelastic flexural shell model

    CERN Document Server

    Mikelic, Andro

    2015-01-01

    In this paper we investigate the limit behavior of the solution to quasi-static Biot's equations in thin poroelastic flexural shells as the thickness of the shell tends to zero and extend the results obtained for the poroelastic plate by Marciniak-Czochra and Mikeli\\'c. We choose Terzaghi's time corresponding to the shell thickness and obtain the strong convergence of the three-dimensional solid displacement, fluid pressure and total poroelastic stress to the solution of the new class of shell equations. The derived bending equation is coupled with the pressure equation and it contains the bending moment due to the variation in pore pressure across the shell thickness. The effective pressure equation is parabolic only in the normal direction. As additional terms it contains the time derivative of the middle-surface flexural strain. Derivation of the model presents an extension of the results on the derivation of classical linear elastic shells by Ciarlet and collaborators to the poroelastic shells case. The n...

  12. Optimal hedging of Derivatives with transaction costs

    CERN Document Server

    Aurell, E; Aurell, Erik; Muratore-Ginanneschi, Paolo

    2005-01-01

    We investigate the optimal strategy over a finite time horizon for a portfolio of stock and bond and a derivative in an multiplicative Markovian market model with transaction costs (friction). The optimization problem is solved by a Hamilton-Bellman-Jacobi equation, which by the verification theorem has well-behaved solutions if certain conditions on a potential are satisfied. In the case at hand, these conditions simply imply arbitrage-free ("Black-Scholes") pricing of the derivative. While pricing is hence not changed by friction allow a portfolio to fluctuate around a delta hedge. In the limit of weak friction, we determine the optimal control to essentially be of two parts: a strong control, which tries to bring the stock-and-derivative portfolio towards a Black-Scholes delta hedge; and a weak control, which moves the portfolio by adding or subtracting a Black-Scholes hedge. For simplicity we assume growth-optimal investment criteria and quadratic friction.

  13. Derivatives on the isotropic tensor functions

    Institute of Scientific and Technical Information of China (English)

    DUI; Guansuo; WANG; Zhengdao; JIN; Ming

    2006-01-01

    The derivative of the isotropic tensor function plays an important part in continuum mechanics and computational mechanics, and also it is still an opening problem. By means of a scalar response function and solving a tensor equation, this problem is well studied. A compact explicit expression for the derivative of the isotropic tensor function is presented, which is valid for both distinct and repeated eigenvalue cases. Throughout the analysis, the formulation holds for general isotropic tensor functions without need to solve eigenvector problems or determine coefficients. On the theoretical side, a very simple solution of a tensor equation is obtained. As an application to continuum mechanics, a base-free expression for the Hill's strain rate is given, which is more compact than the existent results. Finally, with an example we compute the derivative of an exponent tensor function. And the efficiency of the present formulations is demonstrated.

  14. On alpha'-corrections to D-brane solutions

    CERN Document Server

    De Haro, S; Skenderis, K; Haro, Sebastian de; Sinkovics, Annamaria; Skenderis, Kostas

    2003-01-01

    We discuss the computation of the leading corrections to D-brane solutions due to higher derivative terms in the corresponding low energy effective action. We develop several alternative methods for analyzing the problem. In particular, we derive an effective one-dimensional action from which the field equations for spherically symmetric two-block brane solutions can be derived, show how to obtain first order equations, and discuss a few other approaches. We integrate the equations for extremal branes and obtain the corrections in terms of integrals of the evaluation of the higher derivative terms on the lowest order solution. To obtain completely explicit results one would need to know all leading higher derivative corrections which at present are not available. One of the known higher derivative terms is the R^4 term, and we obtain the corrections to the D3 brane solution due to this term alone. We note, however, that (unknown at present) higher terms depending on F_5 are expected to modify our result. We a...

  15. Study of abietic acid glycerol derivatives as microencapsulating materials.

    Science.gov (United States)

    Puranik, P K; Dorle, A K

    1991-01-01

    Abietic acid (85 per cent pure) was extracted from rosin N Grade and further standardized. Abietic acid derivatives were prepared by heating abietic acid with glycerol and intermediate reaction products with different acid values were collected. Salicylic acid granules were encapsulated using a 10 per cent solution of abietic acid and its derivatives by standard spray pan technique. The coated microcapsules were evaluated for moisture absorption, dissolution and flow properties. The result showed that abietic acid glycerol derivatives, AaG-54 and AaG-20 had better moisture protection properties. Dissolution studies indicate that these derivatives could be used for delayed release of drugs.

  16. XML problem, design, solution

    CERN Document Server

    Amiano, Mitch; Ethier, Kay; Thomas, Michael D

    2006-01-01

    Offering a unique approach to learning XML, this book walks readers through the process of building a complete, functional, end-to-end XML solutionFeatured case study is an online business product catalog that includes reports, data input/output, workflow, stylesheet formatting, RSS feeds, and integration with external services like Google, eBay, and AmazonThe format of presenting a problem and working through the design to come up with a solution enables readers to understand how XML markup allows a business to share data across applications internally or with partners or customers even thoug

  17. Microsoft big data solutions

    CERN Document Server

    Jorgensen, Adam; Welch, John; Clark, Dan; Price, Christopher; Mitchell, Brian

    2014-01-01

    Tap the power of Big Data with Microsoft technologies Big Data is here, and Microsoft's new Big Data platform is a valuable tool to help your company get the very most out of it. This timely book shows you how to use HDInsight along with HortonWorks Data Platform for Windows to store, manage, analyze, and share Big Data throughout the enterprise. Focusing primarily on Microsoft and HortonWorks technologies but also covering open source tools, Microsoft Big Data Solutions explains best practices, covers on-premises and cloud-based solutions, and features valuable case studies. Best of all,

  18. Calculus problems and solutions

    CERN Document Server

    Ginzburg, A

    2011-01-01

    Ideal for self-instruction as well as for classroom use, this text helps students improve their understanding and problem-solving skills in analysis, analytic geometry, and higher algebra. More than 1,200 problems appear in the text, with concise explanations of the basic notions and theorems to be used in their solution. Many are followed by complete answers; solutions for the others appear at the end of the book. Topics include sequences, functions of a single variable, limit of a function, differential calculus for functions of a single variable, fundamental theorems and applications of dif

  19. Positive Solutions for the Discrete Nonlinear Schrödinger Equation: A Priori Estimates and Convergence

    OpenAIRE

    Verbitsky, Anton

    2014-01-01

    We consider the discrete nonlinear stationary Schrödinger equation on a bounded n-dimensional box and on the whole space. In the first case we derive the existence of a positive classical solution of the corresponding continuous problem from a uniform a priori bound on positive discrete solutions for a general right hand side. In the second case we derive a uniform a priori bound on positive discrete solutions for the Schrödinger-type nonlinearity.

  20. Solution processed metal oxide thin film hole transport layers for high performance organic solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Steirer, K. Xerxes; Berry, Joseph J.; Chesin, Jordan P.; Lloyd, Matthew T.; Widjonarko, Nicodemus Edwin; Miedaner, Alexander; Curtis, Calvin J.; Ginley, David S.; Olson, Dana C.

    2017-01-10

    A method for the application of solution processed metal oxide hole transport layers in organic photovoltaic devices and related organic electronics devices is disclosed. The metal oxide may be derived from a metal-organic precursor enabling solution processing of an amorphous, p-type metal oxide. An organic photovoltaic device having solution processed, metal oxide, thin-film hole transport layer.

  1. Novel Wronskian Solutions of the KdV Equation%KdV方程的新Wronskian解

    Institute of Scientific and Technical Information of China (English)

    刘金; 邓淑芳

    2003-01-01

    The novel Wronskian solutions of the KdV equation were obtained as limits of the soliton solutions in the Wronskian form.These solutions were verified by direct substitution to satisfy the bilinear derivative form of the KdV equation and its Backlund trans-formation.

  2. Asymptotic Behavior of Soliton Solutions with a Double Spectral Parameter for Principal Chiral Field

    Institute of Scientific and Technical Information of China (English)

    SONG Quan-Fu; ZHOU Zi-Xiang

    2005-01-01

    The soliton solutions with a double spectral parameter for the principal chiral field are derived by Darboux transformation. The asymptotic behavior of the solutions as time tends to infinity is obtained and the speeds of the peaks in the asymptotic solutions are not constants.

  3. New explicit and exact solutions of the Benney-Kawahara-Lin equation

    Institute of Scientific and Technical Information of China (English)

    Xie Yuan-Xi

    2009-01-01

    In this paper, we present a combination method of constructing the explicit and exact solutions of nonlinear partial differential equations. And as an illustrative example, we apply the method to the Benney-Kawahara-Lin equation and derive its many explicit and exact solutions which are all new solutions.

  4. Analytical solutions for the coefficient of variation of the volume-averaged solute concentration in heterogeneous aquifers

    Science.gov (United States)

    Kabala, Z. J.

    1997-08-01

    Under the assumption that local solute dispersion is negligible, a new general formula (in the form of a convolution integral) is found for the arbitrary k-point ensemble moment of the local concentration of a solute convected in arbitrary m spatial dimensions with general sure initial conditions. From this general formula new closed-form solutions in m=2 spatial dimensions are derived for 2-point ensemble moments of the local solute concentration for the impulse (Dirac delta) and Gaussian initial conditions. When integrated over an averaging window, these solutions lead to new closed-form expressions for the first two ensemble moments of the volume-averaged solute concentration and to the corresponding concentration coefficients of variation (CV). Also, for the impulse (Dirac delta) solute concentration initial condition, the second ensemble moment of the solute point concentration in two spatial dimensions and the corresponding CV are demonstrated to be unbound. For impulse initial conditions the CVs for volume-averaged concentrations axe compared with each other for a tracer from the Borden aquifer experiment. The point-concentration CV is unacceptably large in the whole domain, implying that the ensemble mean concentration is inappropriate for predicting the actual concentration values. The volume-averaged concentration CV decreases significantly with an increasing averaging volume. Since local dispersion is neglected, the new solutions should be interpreted as upper limits for the yet to be derived solutions that account for local dispersion; and so should the presented CVs for Borden tracers. The new analytical solutions may be used to test the accuracy of Monte Carlo simulations or other numerical algorithms that deal with the stochastic solute transport. They may also be used to determine the size of the averaging volume needed to make a quasi-sure statement about the solute mass contained in it.

  5. An Inexpensive Solution Calorimeter

    Science.gov (United States)

    Kavanagh, Emma; Mindel, Sam; Robertson, Giles; Hughes, D. E. Peter

    2008-01-01

    We describe the construction of a simple solution calorimeter, using a miniature bead thermistor as a temperature-sensing element. This has a response time of a few seconds and made it possible to carry out a thermometric reaction in under a minute, which led to minimal heat losses. Small temperature changes of 1 K associated with enthalpies of…

  6. Treatment of Aqueous Solutions

    NARCIS (Netherlands)

    Van Spronsen, J.; Witkamp, G.J.

    2013-01-01

    The invention is directed to a process for the recovery or removal of one or more crystallizable compounds from an aqueous solution containing, apart from the said crystallizable compounds, one or more organic or inorganic scale- forming or scale-inducing materials having a lower solubility in water

  7. Intestinal solute carriers

    DEFF Research Database (Denmark)

    Steffansen, Bente; Nielsen, Carsten Uhd; Brodin, Birger

    2004-01-01

    A large amount of absorptive intestinal membrane transporters play an important part in absorption and distribution of several nutrients, drugs and prodrugs. The present paper gives a general overview on intestinal solute carriers as well as on trends and strategies for targeting drugs and/or pro...

  8. School Solutions for Cyberbullying

    Science.gov (United States)

    Sutton, Susan

    2009-01-01

    This article offers solutions and steps to prevent cyberbullying. Schools can improve their ability to handle cyberbullying by educating staff members, students, and parents and by implementing rules and procedures for how to handle possible incidents. Among the steps is to include a section about cyberbullying and expectations in the student…

  9. Oral rehydration solutions.

    Science.gov (United States)

    1983-02-18

    In the US oral glucose electrolyte solutions have been marketed for over 30 years for the treatment of infantile diarrhea. Recently, oral solutions have been widely used instead of intravenous fluids for treatment of dehydration from diarrhea, especially in developing countries, where diarrhea is a major cause of death in infants and young children and facilities for intravenous fluid replacement are limited or unavailable. The high concentrations of glucose and other carbohydrates in older preparations may make the diarrhea worse. The use of 2-2 1/2% glucose, as in "Infalyte, Pedialyte R.S." and the World Health Organization (WHO) solution avoids the osmotic effect of unabsorbed glucose, makes the taste tolerable, and promotes coupled absorption of sodium from the intestine. Replacement solutions for fluid loss due to diarrhea should also contain about 20 mEq/L of potassium because diarrhea invariably results in a substantial loss of potassium. Although homemade mixtures of glucose electrolyte solutions and commercial powders that require dilution are less costly than ready to use commercial solutions, errors in mixing or diluting occur often and can have serious consequences. For rehydration after volume depletion, the sodium concentration of the replacement fluid should be between 50-90 mEq/L, regardless of the cause of the diarrhea, patient's age, or the serum sodium concentration. For early treatment of diarrhea to prevent dehydration or for maintenance of hydration after parenteral fluid replacement, 90 mEq/L of sodium is acceptable for adults and children, but may not be appropriate for infants who have a higher insensible water loss. When diarrhea in infants is not caused by cholera, some consultants prefer to use more dilute fluids that contain 50-60 mEq/L of sodium. When circulatory insufficiency (10-15% weight loss), severe vomiting, inability to drink, or severe gastric distention is present, parenteral fluid replacement is indicated. With 5-8% acute

  10. The existence of global solution and their weak limit of generalized Ginzburg-Landau equations in two dimensions

    Institute of Scientific and Technical Information of China (English)

    YANG Ling'e; GUO Boling

    2006-01-01

    By the uniform a priori estimate of solution about parameters, we prove the existence of global solution and inviscid limit to a generalized Ginzburg-Landau equations in two dimensions. We also prove that the solution to the Ginzburg-Landau equations converges to the weak solution to the derivative nonlinear Schrodinger equations.

  11. Fundamental solutions of linear partial differential operators theory and practice

    CERN Document Server

    Ortner, Norbert

    2015-01-01

    This monograph provides the theoretical foundations needed for the construction of fundamental solutions and fundamental matrices of (systems of) linear partial differential equations. Many illustrative examples also show techniques for finding such solutions in terms of integrals. Particular attention is given to developing the fundamentals of distribution theory, accompanied by calculations of fundamental solutions. The main part of the book deals with existence theorems and uniqueness criteria, the method of parameter integration, the investigation of quasihyperbolic systems by means of Fourier and Laplace transforms, and the representation of fundamental solutions of homogeneous elliptic operators with the help of Abelian integrals. In addition to rigorous distributional derivations and verifications of fundamental solutions, the book also shows how to construct fundamental solutions (matrices) of many physically relevant operators (systems), in elasticity, thermoelasticity, hexagonal/cubic elastodynamics...

  12. Analytic solution of an oscillatory migratory alpha^2 stellar dynamo

    CERN Document Server

    Brandenburg, Axel

    2016-01-01

    Analytic solutions of the mean-field induction equation predict a nonoscillatory dynamo for uniform helical turbulence or constant alpha effect in unbounded or periodic domains. Oscillatory dynamos are generally thought impossible for constant alpha. We present an analytic solution for a one-dimensional bounded domain resulting in oscillatory solutions for constant alpha, but different (Dirichlet and von Neumann or perfect conductor and vacuum) boundary conditions on the two ends. We solve a second order complex equation and superimpose two independent solutions to obey both boundary conditions. The solution has time-independent energy density. On one end where the function value vanishes, the second derivative is finite, which would not be correctly reproduced with sine-like expansion functions where a node coincides with an inflection point. The obtained solution may serve as a benchmark for numerical dynamo experiments and as a pedagogical illustration that oscillatory dynamos are possible for dynamos with...

  13. Computable solutions of fractional partial differential equations related to reaction-diffusion systems

    CERN Document Server

    Saxena, R K; Haubold, H J

    2011-01-01

    The object of this paper is to present a computable solution of a fractional partial differential equation associated with a Riemann-Liouville derivative of fractional order as the time-derivative and Riesz-Feller fractional derivative as the space derivative. The method followed in deriving the solution is that of joint Laplace and Fourier transforms. The solution is derived in a closed and computable form in terms of the H-function. It provides an elegant extension of the results given earlier by Debnath, Chen et al., Haubold et al., Mainardi et al., Saxena et al., and Pagnini et al. The results obtained are presented in the form of four theorems. Some results associated with fractional Schroeodinger equation and fractional diffusion-wave equation are also derived as special cases of the findings.

  14. Polyharmonic Multiquadric Particular Solutions for Reissner/Mindlin Plate

    Directory of Open Access Journals (Sweden)

    Chia-Cheng Tsai

    2015-01-01

    Full Text Available Analytical particular solutions of the polyharmonic multiquadrics are derived for both the Reissner and Mindlin thick-plate models in a unified formulation. In the derivation, the three coupled second-order partial differential equations are converted into a product operator of biharmonic and Helmholtz operators using the Hörmander operator decomposition technique. Then a method is introduced to eliminate the Helmholtz operator, which enables the utilization of the polyharmonic multiquadrics. Then, the analytical particular solutions of displacements, shear forces, and bending or twisting moments corresponding to the polyharmonic multiquadrics are all explicitly derived. Numerical examples are carried out to validate these particular solutions. The results obtained by the present method are more accurate than those by the traditional multiquadrics and splines.

  15. Analytic solutions of an unclassified artifact /

    Energy Technology Data Exchange (ETDEWEB)

    Trent, Bruce C.

    2012-03-01

    This report provides the technical detail for analytic solutions for the inner and outer profiles of the unclassified CMM Test Artifact (LANL Part Number 157Y-700373, 5/03/2001) in terms of radius and polar angle. Furthermore, analytic solutions are derived for the legacy Sheffield measurement hardware, also in terms of radius and polar angle, using part coordinates, i.e., relative to the analytic profile solutions obtained. The purpose of this work is to determine the exact solution for the “cosine correction” term inherent to measurement with the Sheffield hardware. The cosine correction is required in order to interpret the actual measurements taken by the hardware in terms of an actual part definition, or “knot-point spline definition,” that typically accompanies a component drawing. Specifically, there are two portions of the problem: first an analytic solution must be obtained for any point on the part, e.g., given the radii and the straight lines that define the part, it is required to find an exact solution for the inner and outer profile for any arbitrary polar angle. Next, the problem of the inspection of this part must be solved, i.e., given an arbitrary sphere (representing the inspection hardware) that comes in contact with the part (inner and outer profiles) at any arbitrary polar angle, it is required to determine the exact location of that intersection. This is trivial for the case of concentric circles. In the present case, however, the spherical portion of the profiles is offset from the defined center of the part, making the analysis nontrivial. Here, a simultaneous solution of the part profiles and the sphere was obtained.

  16. Essays on Derivatives Pricing

    DEFF Research Database (Denmark)

    Kokholm, Thomas

    financial models, and most importantly, to be aware of their limitations. Following that belief, this thesis consists of three independent and self-contained papers, all dealing with topics in derivatives pricing. The first paper considers the pricing of traffic light options, which are appropriate....... With the existence of a liquid market for derivatives with variance as underlying, such as VIX options, VIX futures and a well-developed over-the-counter market for options on variance swaps, it is important to consider models that are able to fit these markets while consistently pricing vanilla options...

  17. Generalized Normal Derivatives and Their Applications in DDMs with Nonmatching Grids and DG Methods

    Institute of Scientific and Technical Information of China (English)

    Qiya Hu

    2008-01-01

    A class of normal-like derivatives for functions with low regularity defined on Lipschitz domains are introduced and studied. It is shown that the new normal-like derivatives, which are called the generalized normal derivatives, preserve the major properties of the existing standard normal derivatives. The generalized normal derivatives are then applied to analyze the convergence of domain decomposition methods (DDMs) with nonmatching grids and discontinuous Galerkin (DG) methods for second-order elliptic problems. The approximate solutions generated by these methods still possess the optimal energy-norm error estimates, even if the exact solutions to the underlying elliptic problems admit very low regularities.

  18. New construction and ultraconvergence of derivative recovery operator for odd-degree rectangular elements

    Institute of Scientific and Technical Information of China (English)

    ZHU Qiding; MENG Lingxiong

    2004-01-01

    In this paper the ultraconvergence of the derivative for odd-degree rectangular elements is addressed. A new, discrete least-squares patch recovery technique is proposed to post-process the solution derivatives. Such recovered derivatives are shown to possess ultraconvergence by using projection type interpolation.

  19. Marchenko Equation for the Derivative Nonlinear Schr(o)dinger Equation

    Institute of Scientific and Technical Information of China (English)

    HUANG Nian-Ning

    2007-01-01

    A simple derivation of the Marchenko equation is given for the derivative nonlinear Schr(o)dinger equation.The kernel of the Marchenko equation is demanded to satisfy the conditions given by the compatibility equations.the soliton solutions to the Marchenko equation are verified.The derivation is not concerned with the revisions of Kaup and Newell.

  20. A fractional derivative approach to full creep regions in salt rock

    DEFF Research Database (Denmark)

    Zhou, H. W.; Wang, C. P.; Mishnaevsky, Leon;

    2013-01-01

    on the basis of time-based fractional derivative. The analytic solution for the fractional-derivative creep constitutive model is presented. The parameters of the fractional derivative creep model are determined by the Levenberg–Marquardt method on the basis of the experimental results of creep tests on salt...

  1. Bidifferential Calculus Approach to AKNS Hierarchies and Their Solutions

    Directory of Open Access Journals (Sweden)

    Aristophanes Dimakis

    2010-07-01

    Full Text Available We express AKNS hierarchies, admitting reductions to matrix NLS and matrix mKdV hierarchies, in terms of a bidifferential graded algebra. Application of a universal result in this framework quickly generates an infinite family of exact solutions, including e.g. the matrix solitons in the focusing NLS case. Exploiting a general Miura transformation, we recover the generalized Heisenberg magnet hierarchy and establish a corresponding solution formula for it. Simply by exchanging the roles of the two derivations of the bidifferential graded algebra, we recover ''negative flows'', leading to an extension of the respective hierarchy. In this way we also meet a matrix and vector version of the short pulse equation and also the sine-Gordon equation. For these equations corresponding solution formulas are also derived. In all these cases the solutions are parametrized in terms of matrix data that have to satisfy a certain Sylvester equation.

  2. Deriving diffeomorphism symmetry

    CERN Document Server

    Kleppe, Astri

    2014-01-01

    In an earlier article, we have "derived" space, as a part of the Random Dynamics project. In order to get locality we need to obtain reparametrization symmetry, or equivalently, diffeomorphism symmetry. There we sketched a procedure for how to get locality by first obtaining reparametrization symmetry, or equivalently, diffeomorphism symmetry. This is the object of the present article.

  3. Oxygenated Derivatives of Hydrocarbons

    Science.gov (United States)

    For the book entitled “Insect Hydrocarbons: Biology, Biochemistry and Chemical Ecology”, this chapter presents a comprehensive review of the occurrence, structure and function of oxygenated derivatives of hydrocarbons. The book chapter focuses on the occurrence, structural identification and functi...

  4. Quinazolin-4-one derivatives

    DEFF Research Database (Denmark)

    Mosley, Cara A; Acker, Timothy M; Hansen, Kasper Bø;

    2010-01-01

    We describe a new class of subunit-selective antagonists of N-methyl D-aspartate (NMDA)-selective ionotropic glutamate receptors that contain the (E)-3-phenyl-2-styrylquinazolin-4(3H)-one backbone. The inhibition of recombinant NMDA receptor function induced by these quinazolin-4-one derivatives ...

  5. AN ANALYTICAL SOLUTION FOR CALCULATING THE INITIATION OF SEDIMENT MOTION

    Institute of Scientific and Technical Information of China (English)

    Thomas LUCKNER; Ulrich ZANKE

    2007-01-01

    This paper presents an analytical solution for calculating the initiation of sediment motion and the risk of river bed movement. It thus deals with a fundamental problem in sediment transport, for which no complete analytical solution has yet been found. The analytical solution presented here is based on forces acting on a single grain in state of initiation of sediment motion. The previous procedures for calculating the initiation of sediment motion are complemented by an innovative combination of optical surface measurement technology for determining geometrical parameters and their statistical derivation as well as a novel approach for determining the turbulence effects of velocity fluctuations. This two aspects and the comparison of the solution functions presented here with the well known data and functions of different authors mainly differ the presented solution model for calculating the initiation of sediment motion from previous approaches. The defined values of required geometrical parameters are based on hydraulically laboratory tests with spheres. With this limitations the derivated solution functions permit the calculation of the effective critical transport parameters of a single grain, the calculation of averaged critical parameters for describing the state of initiation of sediment motion on the river bed, the calculation of the probability density of the effective critical velocity as well as the calculation of the risk of river bed movement. The main advantage of the presented model is the closed analytical solution from the equilibrium of forces on a single grain to the solution functions describing the initiation of sediment motion.

  6. From Goods to Solutions

    DEFF Research Database (Denmark)

    Chakkol, Mehmet; Johnson, Mark; Raja, Jawwad;

    2014-01-01

    Purpose – This paper aims to adopt service-dominant logic (SDL) to empirically explore network configurations resulting from the provision of goods, goods and services, and solutions. Design/methodology/approach – This paper uses a single, in-depth, exploratory case study in a truck manufacturer...... and its supply network. An abductive approach is adopted. In total, 54 semi-structured interviews were conducted. Findings – Three value propositions are clearly discernible within the truck provider. These range from a truck to a “solution”. These propositions have different supply network configurations...... different value propositions and the resulting network configurations are discussed. In so doing, evidence is provided of a more complex, tetradic network configuration for solutions, with varying degrees of interplay between actors in the flow of operand and operant resources to create value....

  7. The sustainability solutions agenda.

    Science.gov (United States)

    Sarewitz, Daniel; Clapp, Richard; Crumbley, Cathy; Kriebel, David; Tickner, Joel

    2012-01-01

    Progress toward a more sustainable society is usually described in a "knowledge-first" framework, where science characterizes a problem in terms of its causes and mechanisms as a basis for subsequent action. Here we present a different approach-A Sustainability Solutions Agenda (SSA)-which seeks from the outset to identify the possible pathways to solutions. SSA focuses on uncovering paths to sustainability by improving current technological practice, and applying existing knowledge to identify and evaluate technological alternatives. SSA allows people and organizations to transition toward greater sustainability without sacrificing essential technological functions, and therefore does not threaten the interests that depend on those functions. Whereas knowledge-first approaches view scientific information as sufficient to convince people to take the right actions, even if those actions are perceived as against their immediate interests, SSA allows values to evolve toward greater attention to sustainability as a result of the positive experience of solving a problem.

  8. Molecular Thermodynamic Modeling of Fluctuation Solution Theory Properties

    DEFF Research Database (Denmark)

    O’Connell, John P.; Abildskov, Jens

    2013-01-01

    Fluctuation Solution Theory provides relationships between integrals of the molecular pair total and direct correlation functions and the pressure derivative of solution density, partial molar volumes, and composition derivatives of activity coefficients. For dense fluids, the integrals follow...... for densities and gas solubilities, including ionic liquids and complex mixtures such as coal liquids. The approach is especially useful in systems with strong nonidealities. This chapter describes successful application of such modeling to a wide variety of systems treated over several decades and suggests how...

  9. Crisis in management solutions

    OpenAIRE

    BATYUK B.

    2013-01-01

    The paper discusses psychological properties of managers in stressful situations, their ability to make appropriate management decisions and act objectively according to the situation. The author conventionally divided into categories due to present management solutions in new crisis. The basis of the separation of management categories are psychological and personality and expertise of managers. Particular attention is paid to the managers ability to use their psychological data, combined wi...

  10. Earnest Rutherford, the solution

    CERN Multimedia

    2003-01-01

    If you did not make it to the Science & Society talk by John Campbell last week and are still wondering about the spelling of "Earnest", here is the solution: Two months after the birth of his fourth child on 30 August 1871 in Spring Grove, New Zealand, James Rutherford registered his son, who was recorded as "Earnest" in the Birth Register. Presumably the Registrar wrote the name down as it sounded and the father failed to notice the mistake when signing the Register.

  11. Solution Processing - Rodlike Polymers

    Science.gov (United States)

    1979-08-01

    side it necessary and identify by block number) Para-ordered Polymers High Modulus Fibers and Films Polybenzobisoxazoles Polybenzobisthiazoles 20...considerations important in solution processing are considered, with special emphasis on the dry-jet wet spinning process used to form fibers . Pertinent...Company, Summit, N.J. iii TABLE OF CONTENTS 1. INTRODUCTION ................ .......................... .. 1 2. REMARKS ON DRY-JET WET SPUN FIBER

  12. FRAUD PREVENTION SOLUTIONS

    OpenAIRE

    АЛИБЕКОВА Ю.К.

    2015-01-01

    Currently, business ethics and integrity of top managers and employees are often under a big question, so we cannot rely on them. Non-compliant behavior of top management and employees related to fraud and corrupt practices lead to huge financial losses, loss of reputation and litigations. Incidents of internal fraud and embezzlement are happening in every business imaginable. Fraud prevention solutions we recommend are the fundamental for corporate financial compliance. All stakeholders must...

  13. N-soliton solutions to the modified Boussinesq equation

    Institute of Scientific and Technical Information of China (English)

    LI Qiong; XIA Tie-cheng; CHEN Deng-yuan

    2009-01-01

    Searching for exact solutions to nonlinear evolution equations is a very important and interesting work in non-linear science. In this paper, the modified Boussinesq equation is derived from the modified Gel'fand-Dikii (mG-D) system. Furthermore, we study the modified Boussinesq equation by using the bilinear method and Wronskian technique, we obtain the N-soliton solutions to the above equation.

  14. ON SOLUTIONS OF MATRIX EQUATION AXAT + BYBT = C

    Institute of Scientific and Technical Information of China (English)

    Yuan-bei Deng; Xi-yan Hu

    2005-01-01

    By making use of the quotient singular value decomposition (QSVD) of a matrix pair,this paper establishes the necessary and sufficient conditions for the existence of and the expressions for the general solutions of the linear matrix equation AXAT + BYBT = C with the unknown X and Y, which may be both symmetric, skew-symmetric, nonnegative definite , positive definite or some cross combinations respectively. Also, the solutions of some optimal problems are derived.

  15. Notes on Solutions to Burgers-type Equations

    Institute of Scientific and Technical Information of China (English)

    FU Zun-Tao; LIU Shi-Da; LIU Shi-Kuo

    2004-01-01

    A transformation is introduced and applied to solve Burgers-type equations,such as Burgers equation,Burgers-KdV equation and Burgers-KdV-Kuramoto equation.Many kinds of travelling wave solutions including solitary wave solution are obtained,and it is shown that this is a powerful method to solve nonlinear equations with odd-order and even-order derivatives simultaneously.

  16. Two Special Solutions of the Non-ideal Magnetohydrodynamics

    Institute of Scientific and Technical Information of China (English)

    FENG Xue-Shang; LIU Yong; WEI Feng-Si; YE Zhan-Yin

    2000-01-01

    A special transformation is found to solve the Magnetohydrodynamic equations, by which two classes of exact analytic time-dependent solutions of magnetic annihilation for incompressible magnetic fluid have been obtained.The solutions derived here possesses scaling property with time t as the scale factor. We find that the current can perform the soliton-like behaviour in the case of asymmetric inflow. The relevant evolution characteristics in the process of magnetic annihilation are also revealed.

  17. Systematic solution-generation of five-dimensional black holes

    CERN Document Server

    Iguchi, Hideo; Mishima, Takashi

    2011-01-01

    Solitonic solution-generating methods are powerful tools to construct nontrivial black hole solutions of the higher-dimensional Einstein equations systematically. In five dimensions particularly, the solitonic methods can be successfully applied to the construction of asymptotically Minkowski spacetimes with multiple horizons. We review the solitonic methods applicable to higher-dimensional vacuum spacetimes and present some five-dimensional examples derived from the methods.

  18. Travelling wave solutions for ( + 1)-dimensional nonlinear evolution equations

    Indian Academy of Sciences (India)

    Jonu Lee; Rathinasamy Sakthivel

    2010-10-01

    In this paper, we implement the exp-function method to obtain the exact travelling wave solutions of ( + 1)-dimensional nonlinear evolution equations. Four models, the ( + 1)-dimensional generalized Boussinesq equation, ( + 1)-dimensional sine-cosine-Gordon equation, ( + 1)-double sinh-Gordon equation and ( + 1)-sinh-cosinh-Gordon equation, are used as vehicles to conduct the analysis. New travelling wave solutions are derived.

  19. Regularity of large solutions for the compressible magnetohydrodynamic equations

    Directory of Open Access Journals (Sweden)

    Qin Yuming

    2011-01-01

    Full Text Available Abstract In this paper, we consider the initial-boundary value problem of one-dimensional compressible magnetohydrodynamics flows. The existence and continuous dependence of global solutions in H 1 have been established in Chen and Wang (Z Angew Math Phys 54, 608-632, 2003. We will obtain the regularity of global solutions under certain assumptions on the initial data by deriving some new a priori estimates.

  20. The theorem on existence of singular solutions to nonlinear equations

    Directory of Open Access Journals (Sweden)

    Prusinska А.

    2005-01-01

    Full Text Available The aim of this paper is to present some applications of pregularity theory to investigations of nonlinear multivalued mappings. The main result addresses to the problem of existence of solutions to nonlinear equations in the degenerate case when the linear part is singular at the considered initial point. We formulate conditions for existence of solutions of equation F(x = 0 when first p - 1 derivatives of F are singular.

  1. Approximate *-derivations and approximate quadratic *-derivations on C*-algebras

    Directory of Open Access Journals (Sweden)

    Park Choonkil

    2011-01-01

    Full Text Available Abstract In this paper, we prove the stability of *-derivations and of quadratic *-derivations on Banach *-algebras. We moreover prove the superstability of *-derivations and of quadratic *-derivations on C*-algebras. 2000 Mathematics Subject Classification: 39B52; 47B47; 46L05; 39B72.

  2. An analytical solution to patient prioritisation in radiotherapy based on utilitarian optimisation.

    Science.gov (United States)

    Ebert, M A; Li, W; Jennings, L

    2014-03-01

    The detrimental impact of a radiotherapy waiting list can in part be compensated by patient prioritisation. Such prioritisation is phrased as an optimisation problem where the probability of local control for the overall population is the objective to be maximised and a simple analytical solution derived. This solution is compared with a simulation of a waiting list for the same population of patients. It is found that the analytical solution can provide an optimal ordering of patients though cannot explicitly constrain optimal waiting times. The simulation-based solution was undertaken using both the analytical solution and a numerical optimisation routine for daily patient ordering. Both solutions provided very similar results with the analytical approach reducing the calculation time of the numerical solution by several orders of magnitude. It is suggested that treatment delays due to resource limitations and resulting waiting lists be incorporated into treatment optimisation and that the derived analytical solution provides a mechanism for this to occur.

  3. Analysis of the singular solution branch of a prescribed mean curvature equation with singular nonlinearity

    CERN Document Server

    Brubaker, Nicholas D

    2011-01-01

    The existence and multiplicity of solutions to a quasilinear, elliptic partial differential equation (PDE) with singular non-linearity is analyzed. The PDE is a recently derived variant of a canonical model used in the modeling of Micro-Electro Mechanical Systems (MEMS). It is observed that the bifurcation curve of solutions terminates at single dead-end point, beyond which no classical solutions exist. A necessary condition for the existence of solutions is developed which reveals that this dead-end point corresponds to a blow-up in the solution derivative at a point internal to the domain. Using asymptotic analysis, an accurate prediction of this dead end point is obtained. An arc-length parameterization of the solution curve can be employed to continue solutions beyond the dead end point, however, all extra solutions are found to be multi-valued.

  4. An Approximate Solution for Spherical and Cylindrical Piston Problem

    Indian Academy of Sciences (India)

    S K Singh; V P Singh

    2000-02-01

    A new theory of shock dynamics (NTSD) has been derived in the form of a finite number of compatibility conditions along shock rays. It has been used to study the growth and decay of shock strengths for spherical and cylindrical pistons starting from a non-zero velocity. Further a weak shock theory has been derived using a simple perturbation method which admits an exact solution and also agrees with the classical decay laws for weak spherical and cylindrical shocks.

  5. Exact solutions for nonlinear partial fractional differential equations

    Institute of Scientific and Technical Information of China (English)

    Khaled A.Gepreel; Saleh Omran

    2012-01-01

    In this article,we use the fractional complex transformation to convert nonlinear partial fractional differential equations to nonlinear ordinary differential equations.We use the improved (G’/G)-expansion function method to calculate the exact solutions to the time-and space-fractional derivative foam drainage equation and the time-and space-fractional derivative nonlinear KdV equation.This method is efficient and powerful for solving wide classes of nonlinear evolution fractional order equations.

  6. Distributed order reaction-diffusion systems associated with Caputo derivatives

    Science.gov (United States)

    Saxena, R. K.; Mathai, A. M.; Haubold, H. J.

    2014-08-01

    This paper deals with the investigation of the solution of an unified fractional reaction-diffusion equation of distributed order associated with the Caputo derivatives as the time-derivative and Riesz-Feller fractional derivative as the space-derivative. The solution is derived by the application of the joint Laplace and Fourier transforms in compact and closed form in terms of the H-function. The results derived are of general nature and include the results investigated earlier by other authors, notably by Mainardi et al. ["The fundamental solution of the space-time fractional diffusion equation," Fractional Calculus Appl. Anal. 4, 153-202 (2001); Mainardi et al. "Fox H-functions in fractional diffusion," J. Comput. Appl. Math. 178, 321-331 (2005)] for the fundamental solution of the space-time fractional equation, including Haubold et al. ["Solutions of reaction-diffusion equations in terms of the H-function," Bull. Astron. Soc. India 35, 681-689 (2007)] and Saxena et al. ["Fractional reaction-diffusion equations," Astrophys. Space Sci. 305, 289-296 (2006a)] for fractional reaction-diffusion equations. The advantage of using the Riesz-Feller derivative lies in the fact that the solution of the fractional reaction-diffusion equation, containing this derivative, includes the fundamental solution for space-time fractional diffusion, which itself is a generalization of fractional diffusion, space-time fraction diffusion, and time-fractional diffusion, see Schneider and Wyss ["Fractional diffusion and wave equations," J. Math. Phys. 30, 134-144 (1989)]. These specialized types of diffusion can be interpreted as spatial probability density functions evolving in time and are expressible in terms of the H-function in compact forms. The convergence conditions for the double series occurring in the solutions are investigated. It is interesting to observe that the double series comes out to be a special case of the Srivastava-Daoust hypergeometric function of two variables

  7. Hydrotropic Solubilization by Urea Derivatives: A Molecular Dynamics Simulation Study

    Directory of Open Access Journals (Sweden)

    Yong Cui

    2013-01-01

    Full Text Available Hydrotropy is a phenomenon where the presence of a large quantity of one solute enhances the solubility of another solute. The mechanism of this phenomenon remains a topic of debate. This study employed molecular dynamics simulation to investigate the hydrotropic mechanism of a series of urea derivatives, that is, urea (UR, methylurea (MU, ethylurea (EU, and butylurea (BU. A poorly water-soluble compound, nifedipine (NF, was used as the model solute that was solubilized. Structural, dynamic, and energetic changes upon equilibration were analyzed to supply insights to the solubilization mechanism. The study demonstrated that NF and urea derivatives underwent significant nonstoichiometric molecular aggregation in the aqueous solution, a result consistent with the self-aggregation of urea derivatives under the same conditions. The analysis of hydrogen bonding and energy changes revealed that the aggregation was driven by the partial restoration of normal water structure. The energetic data also suggested that the promoted solubilization of NF is favored in the presence of urea derivatives. While the solutes aggregated to a varying degree, the systems were still in single-phase liquid state as attested by their active dynamics.

  8. Electrospinning chitosan/poly(ethylene oxide) solutions with essential oils: Correlating solution rheology to nanofiber formation.

    Science.gov (United States)

    Rieger, Katrina A; Birch, Nathan P; Schiffman, Jessica D

    2016-03-30

    Electrospinning hydrophilic nanofiber mats that deliver hydrophobic agents would enable the development of new therapeutic wound dressings. However, the correlation between precursor solution properties and nanofiber morphology for polymer solutions electrospun with or without hydrophobic oils has not yet been demonstrated. Here, cinnamaldehyde (CIN) and hydrocinnamic alcohol (H-CIN) were electrospun in chitosan (CS)/poly(ethylene oxide) (PEO) nanofiber mats as a function of CS molecular weight and degree of acetylation (DA). Viscosity stress sweeps determined how the oils affected solution viscosity and chain entanglement (Ce) concentration. Experimentally, the maximum polymer:oil mass ratio electrospun was 1:3 and 1:6 for CS/PEO:CIN and:H-CIN, respectively; a higher chitosan DA increased the incorporation of H-CIN only. The correlations determined for electrospinning plant-derived oils could potentially be applied to other hydrophobic molecules, thus broadening the delivery of therapeutics from electrospun nanofiber mats.

  9. Relationship between solution structure and phase behavior: a neutron scattering study of concentrated aqueous hexamethylenetetramine solutions.

    Science.gov (United States)

    Burton, R C; Ferrari, E S; Davey, R J; Finney, J L; Bowron, D T

    2009-04-30

    The water-hexamethylenetetramine system displays features of significant interest in the context of phase equilibria in molecular materials. First, it is possible to crystallize two solid phases depending on temperature, both hexahydrate and anhydrous forms. Second, saturated aqueous solutions in equilibrium with these forms exhibit a negative dependence of solubility (retrograde) on temperature. In this contribution, neutron scattering experiments (with isotopic substitution) of concentrated aqueous hexamethylenetetramine solutions combined with empirical potential structure refinement (EPSR) were used to investigate the time-averaged atomistic details of this system. Through the derivation of radial distribution functions, quantitative details emerge of the solution coordination, its relationship to the nature of the solid phases, and of the underlying cause of the solubility behavior of this molecule.

  10. Error Estimates for Approximate Solutions of the Riccati Equation with Real or Complex Potentials

    CERN Document Server

    Finster, Felix

    2008-01-01

    A method is presented for obtaining rigorous error estimates for approximate solutions of the Riccati equation, with real or complex potentials. Our main tool is to derive invariant region estimates for complex solutions of the Riccati equation. We explain the general strategy for applying these estimates and illustrate the method in typical examples, where the approximate solutions are obtained by glueing together WKB and Airy solutions of corresponding one-dimensional Schr"odinger equations.

  11. Fractional Derivative Cosmology

    CERN Document Server

    Roberts, Mark D

    2009-01-01

    The degree by which a function can be differentiated need not be restricted to integer values. Usually most of the field equations of physics are taken to be second order, curiosity asks what happens if this is only approximately the case and the field equations are nearly second order. For Robertson-Walker cosmology there is a simple fractional modification of the Friedman and conservation equations. In general fractional gravitational equations similar to Einstein's are hard to define as this requires fractional derivative geometry. What fractional derivative geometry might entail is briefly looked at and it turns out that even asking very simple questions in two dimensions leads to ambiguous or intractable results. A two dimensional line element which depends on the Gamma-function is looked at.

  12. Systems of integrable derivations

    Directory of Open Access Journals (Sweden)

    Vittoria Bonanzinga

    1994-05-01

    Full Text Available Let A be a commutative k-algebra, with k a subring of A. We give the definition of n-dimensional differentiation of A over k which formally extends the known one of unidimensional differentiation and we study the group of all n-dimensional differentiation of A over k. In the second part of the work we give some theorems of strong integrability for systems of derivations in terms of n-dimensional differentiation.

  13. Dynamic Stability Derivatives

    Science.gov (United States)

    2015-06-01

    time; i.e., is evaluated at the steady-state reference flight condition. However, this derivation provides no definitive information about limits of...dimensional straight- tapered wing in unsteady flow. Assume that the lift is defined by a function that depends on properties of the fluid (density...kinematic viscocity, and speed-of-sound; wing geometric characteristics (area, mean aerodynamic chord and taper ratio); and its motion (free-stream

  14. Probabilistic solution of relative entropy weighted control

    CERN Document Server

    Bierkens, Joris

    2012-01-01

    We show that stochastic control problems with a particular cost structure involving a relative entropy term admit a purely probabilistic solution, without the necessity of applying the dynamic programming principle. The argument is as follows. Minimization of the expectation of a random variable with respect to the underlying probability measure, penalized by relative entropy, may be solved exactly. In the case where the randomness is generated by a standard Brownian motion, this exact solution can be written as a Girsanov density. The stochastic process appearing in the Girsanov exponent has the role of control process, and the relative entropy of the change of probability measure is equal to the integral of the square of this process. An explicit expression for the control process may be obtained in terms of the Malliavin derivative of the density process. The theory is applied to the problem of minimizing the maximum of a Brownian motion (penalized by the relative entropy), leading to an explicit expressio...

  15. A solution to the problem of time

    CERN Document Server

    Shlaer, Benjamin

    2014-01-01

    Despite the severe ultraviolet problems with quantum gravity, infrared phenomena such as eternal inflation and black hole evaporation should enjoy fully quantum mechanical unitary time evolution. Currently this is not possible, the impediment being what is known as the problem of time. Here, we provide a solution by promoting the cosmological constant \\Lambda to a Lagrange multiplier constraining the metric volume element to be manifestly a total derivative. Because \\Lambda appears linearly in the Hamiltonian constraint, it unitarily generates time evolution, yielding a functional Schroedinger equation for gravity. Two pleasant side effects of this construction are that vacuum energy is completely sequestered from the cosmological constant problem, much like in unimodular gravity, and the natural foliation provided by the time variable defines a sensible solution to the measure problem.

  16. Schroedinger's radial equation - Solution by extrapolation

    Science.gov (United States)

    Goorvitch, D.; Galant, D. C.

    1992-01-01

    A high-accuracy numerical method for the solution of a 1D Schroedinger equation that is suitable for a diatomic molecule, obtained by combining a finite-difference method with iterative extrapolation to the limit, is presently shown to have several advantages over more conventional methods. Initial guesses for the term values are obviated, and implementation of the algorithm is straightforward. The method is both less sensitive to round-off error, and faster than conventional methods for equivalent accuracy. These advantages are illustrated through the solution of Schroedinger's equation for a Morse potential function suited for HCl and a numerically derived Rydberg-Klein-Rees potential function for the X 1Sigma(+) state of CO.

  17. Viscoelasticity of mixed polyacrylamide solution

    Institute of Scientific and Technical Information of China (English)

    徐丽娜

    2008-01-01

    The viscoelastic behavior of polyacrylamide solution is crucial for its application in various industries.The mixed polyacrylamide solution was prepared by mixing polyacrylamide with different relative molecular masses according to the defined mass fraction.The viscosity and elasticity of mixed polyacrylamide solution were separately tested with RS150 rheometer and capillary breakup extensional rheometer and compared with those of the single polyacrylamide solution which is directly provided by manufacturer without any mixing.The results indicate that the mixed and single polyacrylamide solutions have the same shear viscosity and intrinsic viscosity.However,some mixed polyacrylamide solutions have higher elasticity than single polyacrylamide solution.The flow resistance of mixed polyacrylamide with higher elasticity is also greater than that of single polyacrylamide solution in porous medium.This paper presents an effective method of mixing polyacrylamides with different relative molecular masses,which can enhance the elasticity of polyacrylamide solution and flowing resistance through porous medium.

  18. Endostatin derivative angiogenesis inhibitors

    Institute of Scientific and Technical Information of China (English)

    ZHENG Meng-jie

    2009-01-01

    Objective To throw light on the superiority of the anti-angiogenesis activity of endostatin (ES) derivatives by reviewing the recent progress in the field of ES molecular structure modification.Data sources The data used in this article were mainly from PubMed with relevant English articles published from 1971 to May 2008.The search terms were "endostatin" and "angiothesis".Study selection Articles involved in the ES molecular structure modification and the original milestone articles were selected.Results A number of ES derivatives were designed and studied to improve its clinical relevance.The modified ES with polyethylene glycol (PEG),low molecular weight heparin (LMWH) and IgG Fc domain extended the circulation half-life.Meanwhile the recombinant ESs showed more potent anti-tumor activity than native ES in mouse xenografts.Mutated ES also changed its anti-angiogenesis activity.Conclusions The anti-angiogenesis treatment remains a promising tumor therapeutic strategy.New ES derivatives would be a good choice to meet the future challenge on clinical application of ES.

  19. Rapid Regional Centroid Solutions

    Science.gov (United States)

    Wei, S.; Zhan, Z.; Luo, Y.; Ni, S.; Chen, Y.; Helmberger, D. V.

    2009-12-01

    The 2008 Wells Nevada Earthquake was recorded by 164 broadband USArray stations within a distance of 550km (5 degrees) with all azimuths uniformly sampled. To establish the source parameters, we applied the Cut and Paste (CAP) code to all the stations to obtain a mechanism (strike/dip/rake=35/41/-85) at a depth of 9km and Mw=5.9. Surface wave shifts range from -8s to 8s which are in good agreement with ambient seismic noise (ASN) predictions. Here we use this data set to test the accuracy of the number of stations needed to obtain adequate solutions (position of the compressional and tension axis) for mechanism. The stations were chosen at random where combinations of Pnl and surface waves were used to establish mechanism and depth. If the event is bracketed by two stations, we obtain an accurate magnitude with good solutions about 80% of the trials. Complete solutions from four stations or Pnl from 10 stations prove reliable in nearly all situations. We also explore the use of this dataset in locating the event using a combination of surface wave travel times and/or the full waveform inversion (CAPloc) that uses the CAP shifts to refine locations. If the mechanism is known (fixed) only a few stations is needed to locate an event to within 5km if date is available at less than 150km. In contrast, surface wave travel times (calibrated to within one second) produce amazing accurate locations with only 6 stations reasonably distributed. It appears this approach is easily automated as suggested by Scrivner and Helmberger (1995) who discussed travel times of Pnl and surface waves and the evolving of source accuracy as the various phases arrive.

  20. Periodic solutions and flip bifurcation in a linear impulsive system

    Institute of Scientific and Technical Information of China (English)

    Jiang Gui-Rong; Yang Qi-Gui

    2008-01-01

    In this paper,the dynamical behaviour of a linear impulsive system is discussed both theoretically and numerically.The existence and the stability of period-one solution are discussed by using a discrete map.The conditions of existence for flip bifurcation are derived by using the centre manifold theorem and bifurcation theorem.The bifurcation analysis shows that chaotic solutions appear via a cascade of period-doubling in some interval of parameters.Moreover,the periodic solutions,the bifurcation diagram,and the chaotic attractor,which show their consistence with the theoretical analyses,are given in an example.中图分类:O547

  1. ANALYSIS OF VISCOSITY ABNORMALITIES OF POLYELECTROLYTES IN DILUTE SOLUTIONS

    Institute of Scientific and Technical Information of China (English)

    Jian-qiang Chen; Yu-fang Shao; Zhen Yang; Hu Yang; Rong-shi Cheng

    2011-01-01

    It was found that the interface effects in viscous capillary flow influenced the process of viscosity measurement greatly,and the abnormal viscosity behaviors of polyelectrolytes as well as neutral polymers in dilute solution region were ascribed to interface effect.According to this theory,we have reviewed the previous viscosity data of derivatives of poly-2-vinylpyridine reported by Maclay and Fuoss first.Then,the abnormal viscosity behaviors of a series of sodium polystyrene sulfonate samples with various molecular weights in dilute aqueous solutions were studied further.The solute adsorption behaviors and structural information of polymers have been discussed carefully.

  2. Fast multigrid solution of the advection problem with closed characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Yavneh, I. [Israel Inst. of Technology, Haifa (Israel); Venner, C.H. [Univ. of Twente, Enschede (Netherlands); Brandt, A. [Weizmann Inst. of Science, Rehovot (Israel)

    1996-12-31

    The numerical solution of the advection-diffusion problem in the inviscid limit with closed characteristics is studied as a prelude to an efficient high Reynolds-number flow solver. It is demonstrated by a heuristic analysis and numerical calculations that using upstream discretization with downstream relaxation-ordering and appropriate residual weighting in a simple multigrid V cycle produces an efficient solution process. We also derive upstream finite-difference approximations to the advection operator, whose truncation terms approximate {open_quotes}physical{close_quotes} (Laplacian) viscosity, thus avoiding spurious solutions to the homogeneous problem when the artificial diffusivity dominates the physical viscosity.

  3. Wavelet Method for Numerical Solution of Parabolic Equations

    Directory of Open Access Journals (Sweden)

    A. H. Choudhury

    2014-01-01

    Full Text Available We derive a highly accurate numerical method for the solution of parabolic partial differential equations in one space dimension using semidiscrete approximations. The space direction is discretized by wavelet-Galerkin method using some special types of basis functions obtained by integrating Daubechies functions which are compactly supported and differentiable. The time variable is discretized by using various classical finite difference schemes. Theoretical and numerical results are obtained for problems of diffusion, diffusion-reaction, convection-diffusion, and convection-diffusion-reaction with Dirichlet, mixed, and Neumann boundary conditions. The computed solutions are highly favourable as compared to the exact solutions.

  4. Total Logistic Plant Solutions

    Directory of Open Access Journals (Sweden)

    Dusan Dorcak

    2016-02-01

    Full Text Available The Total Logistics Plant Solutions, plant logistics system - TLPS, based on the philosophy of advanced control processes enables complex coordination of business processes and flows and the management and scheduling of production in the appropriate production plans and planning periods. Main attributes of TLPS is to create a comprehensive, multi-level, enterprise logistics information system, with a certain degree of intelligence, which accepts the latest science and research results in the field of production technology and logistics. Logistic model of company understands as a system of mutually transforming flows of materials, energy, information, finance, which is realized by chain activities and operations

  5. In Search of Solutions

    DEFF Research Database (Denmark)

    Ørding Olsen, Anders

    Innovation is at the core of firms’ competitiveness. External knowledge is increasingly leveraged in the efforts to increase innovation performance by solving innovation related problems and thereby developing new technology, products or services. Using internal knowledge sources can be beneficial...... when pursuing minor performance improvements in existing technologies. However, reliance on internal knowledge sources carries a risk of organizational inertia related to problem understanding and solution development in the shape of path-dependencies and preferences for exploitation and reapplication...... involving universities, customers, competitors and suppliers in problem-solving firms can gain complementary perspectives, insights and technological knowledge as they pursue the development of innovative technologies....

  6. A micellar solution

    Energy Technology Data Exchange (ETDEWEB)

    Jewulski, J.

    1983-08-15

    The subject of the invention is a micellar solution used in oil extraction when flooding a deposit and washing out the critical zone. It contains ethanolamine salt of alkylobenzolsulfonic acid (10 to 56 percent by mass), higher alcohol (4 to 56 percent) an organic solvent and water (2.4 to 57.2 percent) and is distinguished by the fact that an amyl alcohol of the third series is used as the higher alcohol, while oil in a volume of 19 to 71 percent or gasoline in a volume of 6 to 16 percent) is used as the solvent.

  7. Shuttle Wastewater Solution Characterization

    Science.gov (United States)

    Adam, Niklas; Pham, Chau

    2011-01-01

    During the 31st shuttle mission to the International Space Station, STS-129, there was a clogging event in the shuttle wastewater tank. A routine wastewater dump was performed during the mission and before the dump was completed, degraded flow was observed. In order to complete the wastewater dump, flow had to be rerouted around the dump filter. As a result, a basic chemical and microbial investigation was performed to understand the shuttle wastewater system and perform mitigation tasks to prevent another blockage. Testing continued on the remaining shuttle flights wastewater and wastewater tank cleaning solutions. The results of the analyses and the effect of the mitigation steps are detailed in this paper.

  8. Glycosylation of solute carriers

    DEFF Research Database (Denmark)

    Pedersen, Nis Borbye; Carlsson, Michael C; Pedersen, Stine Helene Falsig

    2016-01-01

    as their posttranslational regulation, but only relatively little is known about the role of SLC glycosylation. Glycosylation is one of the most abundant posttranslational modifications of animal proteins and through recent advances in our understanding of protein-glycan interactions, the functional roles of SLC......Solute carriers (SLCs) are one of the largest groups of multi-spanning membrane proteins in mammals and include ubiquitously expressed proteins as well as proteins with highly restricted tissue expression. A vast number of studies have addressed the function and organization of SLCs as well...

  9. Credit derivatives and risk management

    OpenAIRE

    Michael S. Gibson

    2007-01-01

    The striking growth of credit derivatives suggests that market participants find them to be useful tools for risk management. I illustrate the value of credit derivatives with three examples. A commercial bank can use credit derivatives to manage the risk of its loan portfolio. An investment bank can use credit derivatives to manage the risks it incurs when underwriting securities. An investor, such as an insurance company, asset manager, or hedge fund, can use credit derivatives to align its...

  10. Langmuir-Blodgett Films of Graphene Derivatives

    DEFF Research Database (Denmark)

    Petersen, Søren Vermehren

    . Solution processable graphene in the form of chemically derived graphene has been synthesized through the modified Hummers method with subsequent reduction into reduced graphene oxide with hydrazine. The completeness of oxidation, the effect of the refinement steps and the reduction of the graphene oxide...... were investigated using the Langmuir-Blodgett technique. It was found that reduction of graphene oxide back into graphene did not seem possible in solution, while still maintaining its monolayer character. Instead, an alternative route for graphene synthesis was then designed. This involved...... immobilization of the monolayered graphene oxide via the Langmuir-Blodgett deposition technique prior to a three step reduction scheme involving hydrazine reduc-tion, sulfuric acid de-oxygenation, and thermal annealing. This method resulted in wrin-kle-free reduced graphene oxide with a negligible oxygen content...

  11. Approximate analytical solutions to the condensation-coagulation equation of aerosols

    CERN Document Server

    Smith, Naftali; Svensmark, Henrik

    2015-01-01

    We present analytical solutions to the steady state injection-condensation-coagulation equation of aerosols in the atmosphere. These solutions are appropriate under different limits but more general than previously derived analytical solutions. For example, we provide an analytic solution to the coagulation limit plus a condensation correction. Our solutions are then compared with numerical results. We show that the solutions can be used to estimate the sensitivity of the cloud condensation nuclei number density to the nucleation rate of small condensation nuclei and to changes in the formation rate of sulfuric acid.

  12. Solution and Positive Solution to Nonlinear Cantilever Beam Equations

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Using the decomposition technique of equation and the fixed point theorem, the existence of solution and positive solution is studied for a nonlinear cantilever beam equation. The equation describes the deformation of the elastic beam with a fixed end and a free end. The main results show that the equation has at least one solution or positive solution, provided that the "height" of nonlinear term is appropriate on a bounded set.

  13. A generic travelling wave solution in dissipative laser cavity

    Indian Academy of Sciences (India)

    BALDEEP KAUR; SOUMENDU JANA

    2016-10-01

    A large family of cosh-Gaussian travelling wave solution of a complex Ginzburg–Landau equation (CGLE), that describes dissipative semiconductor laser cavity is derived. Using perturbation method, the stability region is identified. Bifurcation analysis is done by smoothly varying the cavity loss coefficient to provide insight of the system dynamics. He’s variational method is adopted to obtain the standard sech-type and the notso-explored but promising cosh-Gaussian type, travelling wave solutions. For a given set of system parameters, only one sech solution is obtained, whereas several distinct solution points are derived for cosh-Gaussian case. These solutions yield a wide variety of travelling wave profiles, namely Gaussian, near-sech, flat-top and a cosh-Gaussian with variable central dip. A split-step Fourier method and pseudospectral method have been used for direct numerical solution of the CGLE and travelling wave profiles identical to the analytical profiles have been obtained. We also identified the parametric zone that promises an extremely large family of cosh-Gaussian travelling wave solutions with tunable shape. This suggests that the cosh-Gaussian profile is quite generic and would be helpful for further theoretical as well as experimental investigation on pattern formation, pulse dynamics and localization in semiconductor laser cavity.

  14. Fundamentals and advanced techniques in derivatives hedging

    CERN Document Server

    Bouchard, Bruno

    2016-01-01

    This book covers the theory of derivatives pricing and hedging as well as techniques used in mathematical finance. The authors use a top-down approach, starting with fundamentals before moving to applications, and present theoretical developments alongside various exercises, providing many examples of practical interest. A large spectrum of concepts and mathematical tools that are usually found in separate monographs are presented here. In addition to the no-arbitrage theory in full generality, this book also explores models and practical hedging and pricing issues. Fundamentals and Advanced Techniques in Derivatives Hedging further introduces advanced methods in probability and analysis, including Malliavin calculus and the theory of viscosity solutions, as well as the recent theory of stochastic targets and its use in risk management, making it the first textbook covering this topic. Graduate students in applied mathematics with an understanding of probability theory and stochastic calculus will find this b...

  15. Improving Energy Efficiency in Industrial Solutions – Walk the Talk

    DEFF Research Database (Denmark)

    Wegener, Dieter; Finkbeiner, Matthias; Holst, Jens-Christian

    2011-01-01

    This paper describes the outline of the energy efficiency and environmental care policy and management at Siemens Industry Solutions Division. This environmental policy coherently embraces strategic planning, eco-design of energy-efficient industrial processes and solutions, design evaluation...... and finally communication of both environmental and economic performance of solutions to customers. One of the main tools supporting eco-design and evaluation & controlling of derived design solutions is the so called “Eco-Care-Matrix” (ECM). The ECM simply visualizes the eco-efficiency of solutions compared...... to a given baseline. In order to prevent from “green washing” criticism and to ensure “walk the talk” attitude the ECM should be scientifically well-founded using appropriate and consistent methodology. The vertical axis of an ECM illustrates the environmental performance and the horizontal axis describes...

  16. Cosmological long-wavelength solutions and primordial black hole formation

    CERN Document Server

    Harada, Tomohiro; Nakama, Tomohiro; Koga, Yasutaka

    2015-01-01

    We construct cosmological long-wavelength solutions without symmetry in general gauge conditions compatible with the long-wavelength scheme. We then specify the relationship among the solutions in different time slicings. Nonspherical long-wavelength solutions are particularly important for primordial structure formation in the epoch of soft equations of state. Applying this framework to spherical symmetry, we show the equivalence between long-wavelength solutions in the constant mean curvature slicing and asymptotic quasi-homogeneous solutions in the comoving slicing. We derive the correspondence relation and compare the results of numerical simulations of primordial black hole (PBH) formation. In terms of $\\tilde{\\delta}_{c}$, the value which the averaged density perturbation at threshold in the comoving slicing would take at horizon entry in the first-order long-wavelength expansion, we find that the sharper the transition from the overdense region to the FRW universe is, the larger the $\\tilde{\\delta}_{c}...

  17. Solutions of two-factor models with variable interest rates

    Science.gov (United States)

    Li, Jinglu; Clemons, C. B.; Young, G. W.; Zhu, J.

    2008-12-01

    The focus of this work is on numerical solutions to two-factor option pricing partial differential equations with variable interest rates. Two interest rate models, the Vasicek model and the Cox-Ingersoll-Ross model (CIR), are considered. Emphasis is placed on the definition and implementation of boundary conditions for different portfolio models, and on appropriate truncation of the computational domain. An exact solution to the Vasicek model and an exact solution for the price of bonds convertible to stock at expiration under a stochastic interest rate are derived. The exact solutions are used to evaluate the accuracy of the numerical simulation schemes. For the numerical simulations the pricing solution is analyzed as the market completeness decreases from the ideal complete level to one with higher volatility of the interest rate and a slower mean-reverting environment. Simulations indicate that the CIR model yields more reasonable results than the Vasicek model in a less complete market.

  18. Zoology of instanton solutions in flat potential barriers

    CERN Document Server

    Battarra, Lorenzo; Lehners, Jean-Luc

    2013-01-01

    We perform a detailed study of the existence and the properties of O(4)-invariant instanton solutions in Einstein-scalar theory in the presence of flat potential barriers, i.e. barriers where the second derivative of the potential is small at the top of the barrier. We find a whole zoo of solutions: Hawking-Moss, Coleman-De Luccia (CdL), oscillating instantons, asymmetric CdL as well as other non-standard CdL-like solutions with additional negative modes in their spectrum of fluctuations. Our work shows how these different branches of solutions are connected to each other via "critical" instantons possessing an extra zero mode fluctuation. Overall, the space of finite action euclidean solutions to these theories with flat barriers is surprisingly rich and intricate.

  19. Analytical Solution for the Current Distribution in Multistrand Superconducting Cables

    CERN Document Server

    Bottura, L; Fabbri, M G

    2002-01-01

    Current distribution in multistrand superconducting cables can be a major concern for stability in superconducting magnets and for field quality in particle accelerator magnets. In this paper we describe multistrand superconducting cables by means of a distributed parameters circuit model. We derive a system of partial differential equations governing current distribution in the cable and we give the analytical solution of the general system. We then specialize the general solution to the particular case of uniform cable properties. In the particular case of a two-strand cable, we show that the analytical solution presented here is identical to the one already available in the literature. For a cable made of N equal strands we give a closed form solution that to our knowledge was never presented before. We finally validate the analytical solution by comparison to numerical results in the case of a step-like spatial distribution of the magnetic field over a short Rutherford cable, both in transient and steady ...

  20. The Paperless Solution

    Science.gov (United States)

    2001-01-01

    REI Systems, Inc. developed a software solution that uses the Internet to eliminate the paperwork typically required to document and manage complex business processes. The data management solution, called Electronic Handbooks (EHBs), is presently used for the entire SBIR program processes at NASA. The EHB-based system is ideal for programs and projects whose users are geographically distributed and are involved in complex management processes and procedures. EHBs provide flexible access control and increased communications while maintaining security for systems of all sizes. Through Internet Protocol- based access, user authentication and user-based access restrictions, role-based access control, and encryption/decryption, EHBs provide the level of security required for confidential data transfer. EHBs contain electronic forms and menus, which can be used in real time to execute the described processes. EHBs use standard word processors that generate ASCII HTML code to set up electronic forms that are viewed within a web browser. EHBs require no end-user software distribution, significantly reducing operating costs. Each interactive handbook simulates a hard-copy version containing chapters with descriptions of participants' roles in the online process.