Resonant excitation and the decay of autoionization states in a strong electromagnetic field

International Nuclear Information System (INIS)

Andryushin, A.I.; Kazakov, A.E.; Fedorov, M.V.

1985-01-01

Photoionization of atoms involving resonant excitation of the auto-ionization state is studied. The evolution of the total ionization probability, its dependence on the frequency of the resonance radiation and also the photoelectron energy spectrum are investigated. It is shown that the energy of the final state of the system may be localized either in the vicinity of E approximately Esub(α), where Esub(α) is the auto-ionization energy, or in the vicinity of E approximately Esub(α)+h/2πω where h/2πω is the quantum energy of the resonance radiation. The photoelectron specturum in the region E approximately Esub(α)+h/2πω as a whole is similar to the electron spectrum on photoionization of atoms involving resonance excitation of the bound state. A strong effect on the photoelectron spectrum in the region E approximately Esub(α) is exerted by interference of various decay channels of the ground state in the resonance field which leads to the appearance in the spectrum of a characteristic structure of the Fano type. Interence also affects the widths of the two spectral curves, the relatve amount of electrons in the two energy ranges and also other characteristics of the ionization process. It is shown that the presence of a noninterfering photoionization channel of the autoionization state ensures the finiteness of the swidths and heights of the spectral curves and the absence of complete ''coherency merging''

An experimental study of the role of autoionizing states of H2 (D2) in the production of energetic protons (deuterons) by electron impact

International Nuclear Information System (INIS)

Landau, M.

1982-06-01

The autoionizing state study seemed interesting to be taken up again in energy ranges corresponding to formation thresholds, a device well adapted to this range was available concerning electron measurements. Among other things, the overlapping autoionizing states have been displayed; proton kinetic energy distribution appropriate to each state at its formation threshold have been got. The whole of these results represents a proton (and D + ) production mechanism study contribution via autoionizing states. The theory used to describe autoionization cross-section calculations are recalled. Experimental results are presented, discussed, compared to experimental results and theoretical predictions [fr

Analysis of correlation effects in autoionizing doubly excited states of barium using Coulomb Green's function

International Nuclear Information System (INIS)

Poirier, M.

1997-01-01

Though one would expect that large-angular momentum doubly excited states exhibit weak electronic correlations, it is shown in this paper that a first-order perturbation theory ignoring such correlations may completely fail in predicting correct autoionization probabilities: quadrupolar transitions are poorly described by lowest-order perturbation theory, except for very large angular momenta. Inclusion of second-order dipole-dipole term considerably improves the accuracy of the method. This effect is computed using Coulomb Green's function in its analytical form, probably applied here for the first time to autoionization processes. Examples are given in barium for 5d j 5g [k[ states (j=3/2, 5/2) and for 5d 5/2 nl [k[ states with l > 4. (orig.)

Two-electron excitation in slow ion-atom collisions: Excitation mechanisms and interferences among autoionizing states

International Nuclear Information System (INIS)

Kimura, M.; Rice Univ., Houston, TX

1990-01-01

The two-electron capture or excitation process resulting from collisions of H + and O 6+ ions with He atoms in the energy range from 0.5 keV/amu to 5 keV/amu is studied within a molecular representation. The collision dynamics for formation of doubly excited O 4+ ions and He** atoms and their (n ell, n'ell ') populations are analyzed in conjunction with electron correlations. Autoionizing states thus formed decay through the Auger process. An experimental study of an ejected electron energy spectrum shows ample structures in addition to two characteristic peaks that are identified by atomic and molecular autoionizations. These structures are attributable to various interferences among electronic states and trajectories. We examine the dominant sources of the interferences. 12 refs., 5 figs

A molecular clock for autoionization decay

International Nuclear Information System (INIS)

Medišauskas, Lukas; Bello, Roger Y; Palacios, Alicia; González-Castrillo, Alberto; Martín, Fernando; Morales, Felipe; Plimak, Lev; Smirnova, Olga; Ivanov, Misha Yu

2017-01-01

The ultrafast decay of highly excited electronic states is resolved with a molecular clock technique, using the vibrational motion associated to the ionic bound states as a time-reference. We demonstrate the validity of the method in the context of autoionization of the hydrogen molecule, where nearly exact full dimensional ab-initio calculations are available. The vibrationally resolved photoionization spectrum provides a time–energy mapping of the autoionization process into the bound states that is used to fully reconstruct the decay in time. A resolution of a fraction of the vibrational period is achieved. Since no assumptions are made on the underlying coupled electron–nuclear dynamics, the reconstruction procedure can be applied to describe the general problem of the decay of highly excited states in other molecular targets. (paper)

Autoionizing states in highly ionized oxygen, fluorine and silicon

International Nuclear Information System (INIS)

Forester, J.P.; Peterson, R.S.; Griffin, P.M.; Pegg, D.J.; Haselton, H.H.; Liao, K.H.; Sellin, I.A.; Mowat, J.R.; Thoe, R.S.

1975-01-01

Autoionizing states in high Z 3-electron ions associated with core excited configurations of the type 1s2snl and 1s2pnl are reported. The electron decay-in-flight spectra of lithium-like oxygen, fluorine, and silicon ions are presented. Initial beam energies of 6.75-MeV oxygen and fluorine ions and 22.5-MeV silicon ions were used. Stripping and excitation were done by passing the beams through a thin carbon foil. The experimental technique is described. 4 figs, 1 table, 7 refs

Electronic structure and the mechanism of autoionization for doubly excited states

International Nuclear Information System (INIS)

Komninos, Y.; Makri, N.; Nicolaides, C.A.

1986-01-01

Apart from pure phenomenology, the rigorous and quantitative study of many-electron autoionizing states presents intriguing questions as regards their structure and dynamics. In this paper we present an analysis of such states within a state specific theory with application to five low-lying doubly excited states (DES) of He. The zeroth order description is multiconfigurational and is obtained numerically at the MCHF level. In this way, major radial and angular correlations are accounted for accurately, and reliable predictions can be made without the requirement of large computations. The additional localized correlation is obtained by optimizing variationally analytic virtual orbitals. (orig./WL)

Electron spectra resulting from autoionization in low-energy Li+ + He collisions

International Nuclear Information System (INIS)

Yagishita, A.; Wakiya, K.; Takayanagi, T.; Suzuki, H.; Koike, F.

1979-09-01

Spectra of electrons ejected from doubly excited states of helium have been extensively measured at several observation angles fro impact with lithium ions at energies lower than 5 KeV. ''Molecular-autoionization'' spectra have been found at forward observation angles, and analyzed in terms of the Gerber-Niehaus theory with modification. The spectral shapes of atomic-autoionization peaks have been discussed in relation to both the Barker-Berry effect and the Doppler effect. Excitation cross sections of autoionizing states have been determined by a new method that uses simultaneous impact of ions and electrons. (author)

1P autoionization states of He in the elastic scattering region

International Nuclear Information System (INIS)

Chen, I.H.

1975-01-01

Following the method of Feshbach projection operator formalism, 1 P autoionization states of He in the n = 1 to n = 2 energy region was investigated. Variational functionals are constructed for solving the closed channel components and these results are compared with the absorption spectrum measured by Madden and Codling. In the open channel components the Coulomb wave function is used. Together with closed channel components, we calculate the line width of 1 P and 3 P resonance states. Comparison of these results with the previous calculation and with experimental data is also discussed

Excitation of autoionizing states of helium by 100 keV proton impact: II. Excitation cross sections and mechanisms of excitation

Energy Technology Data Exchange (ETDEWEB)

Godunov, A.L. [Department of Physics, Tulane University, New Orleans, LA 70118-5698 (United States); Ivanov, P.B.; Schipakov, V.A. [Troitsk Institute of Innovation and Fusion Research Troitsk, Moscow region, 142092 (Russian Federation); Moretto-Capelle, P.; Bordenave-Montesquieu, D.; Bordenave-Montesquieu, A. [Laboratoire Collisions, Agregats, Reactivite, IRSAMC, UMR 5589, CNRS-Universite Paul Sabatier, 31062 Toulouse Cedex (France)

2000-03-14

Mechanisms of two-electron excitation of the (2s{sup 2}){sup 1} S, (2p{sup 2} ){sup 1} D and (2s2p){sup 1} P autoionizing states of helium are studied both experimentally and theoretically. It is shown that an explicit introduction of a kinematic factor, with a process-specific phase leads to a productive parametrization of experimental cross sections of ionization, allowing one to extract cross sections of excitation of autoionizing states. Using a new fitting procedure together with the proposed parametrization made it possible to obtain the excitation cross sections and magnetic sublevel population from electron spectra as well as, for the first time, to resolve the contribution of resonance and interference components to resonance profiles. Interference with direct ionization is shown to contribute significantly into resonance formation even for backward ejection angles. We demonstrate theoretically that the excitation cross sections thus extracted from experimental electron spectra hold information about the interaction of autoionizing states with an adjacent continuum. (author)

Precision angle-resolved autoionization resonances in Ar and Ne

Energy Technology Data Exchange (ETDEWEB)

Berrah, N.; Langer, B.; Gorczyca, T.W. [Western Michigan Univ., Kalamazoo, MI (United States)] [and others

1997-04-01

Theoretical work has shown that the electron angular distribution and the shape of the autoionization resonances are crucial to the understanding of certain types of electron-electron correlation. Autoionization resonances in Ne (Ar) result from the decay of the excited discrete state Ne{sup *} 2s2p{sup 6} np (Ar{sup *} 3s3p{sup 6} np) into the continuum state Ne{sup +} 2s{sup 2}2p{sup 5} + e{sup {minus}} (ks,kd) (Ar{sup +} 3s{sup 2}3p{sup 5} + e{sup {minus}} (ks,kd)). Since the continuum can also be reached by direct photoionization, both paths add coherently, giving rise to interferences that produce the characteristic Beutler-Fano line shape. In this work, the authors report on quantitative angle-resolved electron spectrometry studies of (a) the Ne 2s{sup 2}2p{sup 6} {r_arrow} 2s2p{sup 6} np (n=3-5) autoionizing resonances and the 2s{sup 2}2p{sup 6} {r_arrow} 2p{sup 4}3s3p doubly excited resonance, (b) the Ar 3s{sup 2}3p{sup 6} {r_arrow} 3s3p{sup 6} np (n=4-9) autoionization resonances and extended R-matrix calculations of the angular-distribution parameters for both Ne and Ar measurements. Their results are compared with previous theoretical work by Taylor.

Polarization of fluorescence: a probe of molecular autoionization

International Nuclear Information System (INIS)

Leroi, G.E.; Dehmer, J.L.; Parr, A.C.; Poliakoff, E.D.

1983-01-01

The polarization of fluorescence from excited-state molecular photoions provides a direct probe of the photoionization dynamics and the symmetry signatures of autoionizing resonances. Measurements on CO 2 and CS 2 are presented as examples

Effects of autoionizing states on two-photon double ionization of the H2 molecule

International Nuclear Information System (INIS)

Guan, Xiaoxu; Bartschat, Klaus; Schneider, Barry I; Koesterke, Lars

2014-01-01

Treating the effects of autoionizing intermediate states on two-photon double ionization (DI) of the H 2 molecule using time-dependent laser pulses is a significant computational challenge. Relatively long exposure times are critical to understanding the dynamics. Using the fixed-nuclei approximation, we demonstrate how the doubly excited states enhance the angle-integrated generalized cross sections in H 2 , and how they affect the angular distribution pattern of the ejected electrons. As the energy approaches the threshold for sequential DI, there is a sharp rise in the cross section due to virtual sequential ionization

Autoionization: recent developments and applications

International Nuclear Information System (INIS)

Temkin, A.

1985-01-01

This volume reviews significant advances in calculational techniques and also includes a comprehensive treatment of important new applications of autoionization in solar spectral diagnostics. Chapters include: theory and calculation of resonances, autoionization of two-electron atoms and ions, extension of the Feshbach projection operator formalism to many-electron atomic targets, the hole-projection method for calculating Feshbach resonances and inner-shell vacancies, and complex rotation and applications to atomic and molecular resonances. The concluding chapter deals with the diagnostics of solar and astrophysical plasmas dependent on autoionization phenomena. It is a volume designed to be a useful source of information for atomic, molecular, and chemical physicists, astrophysicists, and other space scientists and those in related fields interested in recent developments in ionization

Electron impact excitation of the lowest doublet and quartet core-excited autoionizing states in Rb atoms

International Nuclear Information System (INIS)

Borovik, A; Roman, V; Zatsarinny, O; Bartschat, K

2013-01-01

Electron impact excitation of the (4p 5 5s 2 ) 2 P 3/2,1/2 and (4p 5 4d5s) 4 P 1/2,3/2,5/2 autoionizing states in rubidium atoms was studied experimentally by measuring the ejected-electron excitation functions and theoretically by employing a fully relativistic Dirac B-spline R-matrix (close-coupling) model. The experimental data were collected in an impact energy range from the respective excitation thresholds up to 50 eV with an incident electron energy resolution of 0.2 eV and an observation angle of 54.7°. Absolute values of the excitation cross sections were obtained by normalizing to the theoretical predictions. The observed near-threshold resonance structures were also analysed by comparison with theory. For the 2 P 3/2,1/2 doublet states, a detailed analysis of the R-matrix results reveals that the most intense resonances are related to odd-parity negative-ion states with dominant configurations 4p 5 5s5p 2 and 4p 5 4d5s6s. The measured excitation functions for the 2 P 1/2 and 4 P J states indicate a noticeable cascade population due to the radiative decay from high-lying autoionizing states. A comparative analysis with similar data for other alkali atoms is also presented.

Interference between radiative emission and autoionization in the decay of excited states of atoms

International Nuclear Information System (INIS)

Armstrong, L. Jr.; Theodosiou, C.E.; Wall, M.J.

1978-01-01

An excited state of an atom which can autoionize can also undergo radiative decay. We consider the interaction between the final states resulting from these two modes of decay, and its effects on such quantities as the fluorescence yield of the excited state, excitation profile of the excited state, and the spectra of the emitted photons and electrons. It is shown that the fraction of decays of the excited state resulting in a photon (fluorescence yield) is particularly sensitive to the details of the final-state interaction. In lowest order in the final-state interaction, the fluorescence yield is increased by a factor (1 + 1/q 2 ) from the traditional value, where q is the Fano q parameter relating to the excited state and the final atomic state

Exit channels of autoionization resonances in atoms

International Nuclear Information System (INIS)

Krause, M.O.

1985-01-01

In many-electron atoms with open shells strong autoionization resonances occur when an electron from an inner, weakly bound subshell is excited. Usually, the resonance state lies above several ionization thresholds and, hence, will decay into more than one exit or continuum channel. Several cases are discussed in which the resonance state is induced by synchrotron radiation, and the exit channels are differentiated and characterized by the analysis of the ejected electrons

Coulomb focusing and ''path'' interference of autoionizing electrons produced in 10 keV He+ + He collisions

International Nuclear Information System (INIS)

Swenson, J.K.; Burgdoerfer, J.; Meyer, F.W.; Havener, C.C.; Gregory, D.C.; Stolterfoht, N.

1991-01-01

Autoionizing electrons emitted following low energy ion-atom collisions may scatter significantly from the receding spectator ion's attractive Coulomb field. In such cases the observed electron intensity is ''focused'' in the direction of the scattering ion as a result of the effective compression of the emission solid angle. In addition, interference may occur between trajectories, corresponding to electrons scattering around opposite sides of the ion, which lead to the same final laboratory electron energy and emission angle. This Coulomb ''path'' interference mechanism manifests itself in the uncharacteristically rapid angular dependence of the He target 2s 2 1 S autoionizing state measured near 0 degree following low energy He + + He collisions. A classical trajectory model for Coulomb focusing is presented and a semi-classical approximation is used to model the Coulomb ''path'' interference mechanism. In this description we account for the evolution of the phase of the autoionizing state until its decay and the path dependence of the amplitude of the emitted electron following decay of the autoionizing state. Calculated model lineshapes, which include contributions from adjacent overlapping resonances, reproduce quite well the angular dependence observed in the data near 0 degree. 14 refs., 7 figs

Observation of even-parity autoionization states of uranium by three-colour photoionization optogalvanic spectroscopy in U–Ne hollow cathode discharges

International Nuclear Information System (INIS)

Mandal, P.K.; Seema, A.U.; Das, R.C.; Shah, M.L.; Dev, Vas; Suri, B.M.

2013-01-01

Three-colour three-step photoionization spectroscopy of uranium has been performed in a U–Ne hollow cathode discharge tube by temporally resolving three-colour photoionization optogalvanic (PIOG) signal from the normal optogalvanic (OG) signal using three tunable pulsed dye lasers. U–Ne hollow cathode discharge tube has been used as a source of uranium atomic vapours and photoionization detector. Using this technique, photoionization spectra of uranium have been investigated systematically in the energy region 52,150–52,590 cm −1 , through three different excitation pathways, originating from its ground state, 0 cm −1 ( 5 L o 6 ). By analysing the three-colour photoionization spectra sixty new even-parity autoionization resonances of uranium have been identified and their probable total angular momentum (J) values have been assigned according to the J-momentum selection rule. The J-value of five autoionization resonances, which have been observed either through all three excitation pathways or through two different excitation pathways where J-value of the second excited levels differs by two, has been assigned uniquely. -- Highlights: ► Three-colour photoionization optogalvanic spectroscopy of uranium was performed in a U–Ne hollow cathode discharge tube. ► Hollow cathode discharge tube was used as a source of atomic vapour and laser ionisation detector. ► Uranium photoionization spectra were investigated through three different three-colour photoionization schemes. ► Sixty new even-parity autoionization levels of uranium were identified. ► J-value of five autoionization levels was assigned uniquely

Autoionization spectral line shapes in dense plasmas

International Nuclear Information System (INIS)

Rosmej, F.B.; Hoffmann, D.H.H.; Faenov, A.Ya.; Pikuz, T.A.; Suess, W.; Geissel, M.

2001-01-01

The distortion of resonance line shapes due to the accumulation of a large number of satellite transitions is discovered by means of X-ray optical methods with simultaneous high spectral (λ/δλ≅8000) and spatial resolution (δx≅7 μm). Disappearance of the He α resonance line emission near the target surface is observed while Rydberg satellite intensity accumulates near the resonance line position. He β and He γ resonance line shapes are also shown to be seriously affected by opacity, higher-order line emissions from autoionizing states and inhomogeneous spatial emission. Opposite to resonance line emissions the He β satellites originate only from a very narrow spatial interval. New temperature and density diagnostics employing the 1s2131' and 1s3131'-satellites are developed. Moreover, even-J components of the satellite line emissions were resolved in the present high resolution experiments. Line transitions from the autoionizing states 1s2131' are therefore also proposed for space resolved Stark broadening analysis and local high density probing. Theorists are encouraged to provide accurate Stark broadening data for the transitions 1s2131 ' →1s 2 21+hv

Electron-impact excitation autoionization of Ga II

International Nuclear Information System (INIS)

Pindzola, M.S.; Griffin, D.C.; Bottcher, C.

1982-01-01

The general-reaction theory of Feshbach is applied, within the framework of the distorted-wave approximation, to the calculation of excitation-autoionization resonances in the electron-impact ionization of Ga + . Although the spectrum of autoionizing levels for Ga + is quite complex, we focus our attention on the important 3d 10 4s 2 → 3d 9 4s 2 4p inner-shell excitations. For excitation of the 3d 9 4s 2 4p 1 P 1 autoionizing level we make a general-reaction-theory calculation for the dominant partial-wave cross section and compute a typical resonance profile in the ejected-electron differential cross section. We find that the quantum-mechanical interference between the direct and indirect processes has a small effect on the total ionization cross section. Employing an independent-processes approximation we calculate excitation-autoionization contributions to all twelve levels of the 3d 9 4s 2 4p configuration. Using the results of our calculations and their comparison with a recent crossed-beam experiment by Rogers et al., we discuss the accuracy of the distorted-wave method and the effects of configuration interaction on energy levels and excitation cross sections

Vibrational autoionization in PF3: Doing violence to the propensity rule

International Nuclear Information System (INIS)

Berkowitz, J.; Greene, J.P.

1984-01-01

The photoionization spectrum of PF + 3 in its threshold region displays two prominent progressions of autoionization peaks. When these are analyzed, together with earlier photoabsorption studies and a photoelectron spectrum, they lead to the conclusion that vibrational autoionization is occurring, with Δν< or =-13. This conclusion stands in sharp contrast with the current theory of vibrational autoionization, which predicts a propensity rule Δν = -1. Other examples from the recent literature are summarized, to suggest that a more general theory of vibrational autoionization is required

Autoionization resonances in the photoabsorption spectra of Fe{sup n+} iron ions

Energy Technology Data Exchange (ETDEWEB)

Konovalov, A. V., E-mail: alkonvit@yandex.ru; Ipatov, A. N., E-mail: andrei-ipatov@mail.ru [Peter the Great St. Petersburg State Polytechnic University (Russian Federation)

2016-11-15

The photoabsorption cross sections of a neutral iron atom, as well as positive Fe{sup +} and Fe{sup 2+} ions, are calculated in the relativistic random-phase approximation with exchange in the energy range 20–160 eV. The wavefunctions of the ground and excited states are calculated in the single-configuration Hartree–Fock–Dirac approximation. The resultant photoabsorption spectra are compared with experimental data and with the results of calculations based on the nonrelativistic spin-polarized version of the random-phase approximation with exchange. Series of autoionization resonance peaks, as well as giant autoionization resonance lines corresponding to discrete transitions 3p → 3d, are clearly observed in the photoabsorption cross sections. The conformity of the positions of calculated peaks of giant autoionization resonances with experimental data is substantially improved by taking into account additionally the correlation electron–electron interaction based on the model of the dynamic polarization potential.

Electron Correlation in the Ionization Continuum of Molecules: Photoionization of N2 in the Vicinity of the Hopfield Series of Autoionizing States.

Science.gov (United States)

Klinker, Markus; Marante, Carlos; Argenti, Luca; González-Vázquez, Jesús; Martín, Fernando

2018-02-15

Direct measurement of autoionization lifetimes by using time-resolved experimental techniques is a promising approach when energy-resolved spectroscopic methods do not work. Attosecond time-resolved experiments have recently provided the first quantitative determination of autoionization lifetimes of the lowest members of the well-known Hopfield series of resonances in N 2 . In this work, we have used the recently developed XCHEM approach to study photoionization of the N 2 molecule in the vicinity of these resonances. The XCHEM approach allows us to describe electron correlation in the molecular electronic continuum at a level similar to that provided by multireference configuration interaction methods in bound state calculations, a necessary condition to accurately describe autoionization, shakeup, and interchannel couplings occurring in this range of photon energies. Our results show that electron correlation leading to interchannel mixing is the main factor that determines the magnitude and shape of the N 2 photoionization cross sections, as well as the lifetimes of the Hopfield resonances. At variance with recent speculations, nonadiabatic effects do not seem to play a significant role. These conclusions are supported by the very good agreement between the calculated cross sections and those determined in synchrotron radiation and attosecond experiments.

Femtosecond laser control of the angular distribution of electrons due to autoionization

International Nuclear Information System (INIS)

Bajema, M.L.; Jones, R.R.; Gallagher, T.F.

2004-01-01

Using two 500-fs laser pulses and a controlled time delay between them we are able to manipulate the angular distributions of the electrons ejected by autoionization of Ca atoms in the 4p 3/2 21s and 4p 3/2 19d states. Subsequent to their isolated core excitation by a 500-fs 393-nm laser pulse, Ca 4p 3/2 21s(19d) Rydberg atoms coherently evolve, via configuration interaction, into the degenerate 4p 1/2 ns(nd) states. While in the 4p 1/2 ns(nd) states atoms can be de-excited to bound 4sns(nd) levels using a 500-fs 397-nm pulse. Removing these atoms from the autoionizing states leads to a greater fraction of electrons leaving the atom along the direction of the laser polarization than is possible through direct excitation of 4 3/2 ns(nd) or 4p 1/2 ns(nd) using either the 393- or 397-nm pulse alone

Theory of laser-assisted autoionization by attosecond light pulses

International Nuclear Information System (INIS)

Zhao, Z.X.; Lin, C.D.

2005-01-01

We present a quantum theory of the decay of an autoionizing state created in the attosecond xuv (extreme ultraviolet) pump and laser probe measurements within the strong field approximation employing resonance parameters from Fano's theory. From the electron spectra versus the pump-probe time delay, we show how the lifetimes of the resonances can be extracted directly from the time domain measurements

Electromagnetically induced transparency in systems with degenerate autoionizing levels in Λ-configuration

Czech Academy of Sciences Publication Activity Database

Dinh, T.B.; Leoński, W.; Long, V.C.; Peřina ml., Jan

2013-01-01

Roč. 43, č. 3 (2013), s. 471-484 ISSN 0078-5466 Institutional support: RVO:68378271 Keywords : electromagnetically induced transparency (EIT) * lambda configuration * autoionizing states * double Fano profile Subject RIV: BH - Optics, Masers, Lasers Impact factor: 0.643, year: 2013

Coulomb focusing and path'' interference of autoionizing electrons produced in 10 keV He sup + + He collisions

Energy Technology Data Exchange (ETDEWEB)

Swenson, J.K. (Lawrence Livermore National Lab., CA (USA)); Burgdoerfer, J. (Tennessee Univ., Knoxville, TN (USA)); Meyer, F.W.; Havener, C.C.; Gregory, D.C.; Stolterfoht, N. (Oak Ridge National Lab., TN (USA))

1991-03-13

Autoionizing electrons emitted following low energy ion-atom collisions may scatter significantly from the receding spectator ion's attractive Coulomb field. In such cases the observed electron intensity is focused'' in the direction of the scattering ion as a result of the effective compression of the emission solid angle. In addition, interference may occur between trajectories, corresponding to electrons scattering around opposite sides of the ion, which lead to the same final laboratory electron energy and emission angle. This Coulomb path'' interference mechanism manifests itself in the uncharacteristically rapid angular dependence of the He target 2s{sup 2} {sup 1}S autoionizing state measured near 0{degree} following low energy He{sup +} + He collisions. A classical trajectory model for Coulomb focusing is presented and a semi-classical approximation is used to model the Coulomb path'' interference mechanism. In this description we account for the evolution of the phase of the autoionizing state until its decay and the path dependence of the amplitude of the emitted electron following decay of the autoionizing state. Calculated model lineshapes, which include contributions from adjacent overlapping resonances, reproduce quite well the angular dependence observed in the data near 0{degree}. 14 refs., 7 figs.

Laser-optogalvanic studies of the 4p5 ns and nd autoionizing resonances in krypton

International Nuclear Information System (INIS)

Baig, M A; Hanif, M; Aslam, M

2008-01-01

We report new measurements of the odd-parity autoionizing resonances in krypton using resonant two-photon excitation from the 4p 5 5s[3/2] 2 metastable level in a mild DC discharge and an optogalvanic detection technique. We have observed the 4p 5 ns [1/2] 0,1 , 4p 5 nd [3/2] 2 and 4p 5 nd [5/2] 2,3 autoionizing resonances excited from three intermediate levels 4p 5 5p' [1/2] 1 , 4p 5 5p' [3/2] 1 and 4p 5 5p' [3/2] 2 . The spectra are notable for the absence of the broad autoionizing 4p 5 nd [3/2] 1 series which dominates in the photo-absorption spectrum from the ground state. The prominent transitions follow ΔK = ΔJ = Δl selection rules of the JK-coupling scheme. We report nearly 100 new energy levels in krypton besides the quantum defects and the reduced widths Γ r Γ(ν) 3 of the nd' [3/2] 2 , nd' [5/2] 2 and nd' [5/2] 3 Rydberg states

Identification of weak autoionizing resonances observed through fluorescence from the satellite states of Ar+

International Nuclear Information System (INIS)

McLaughlin, K.W.; Yenen, O.; Samson, J.A.R.

1997-01-01

Photoionization accompanied by excitation of the residual ionic state violates an independent electron model since, according to QED, photons interact only with individual electrons. By allowing measurements at a threshold event with high resolution, the observation of the fluorescence from the decay of these excited states (satellite states) is a sensitive method in the study of electron-electron interactions, providing complementary information to photoelectron spectroscopy. In the measurements reported here, an atomic beam of argon has been photoionized with 34 to 39 eV synchrotron radiation at beamline 9.0.1 of the Advanced Light Source. This energy range encompasses the 3p 4 [ 3 P] 4p 4 P, 2 P, and 2 D as well as the [ 1 D]4p 2 F satellite states of Ar + . By observing the fine-structure resolved fluorescence from these satellite states, new Rydberg series and extensions of previously known series have been resolved with an energy resolution of 3 meV. With the high photon flux available from the high resolution monochromator of beamline 9.0.1, even the weakly excited [ 3 P] 4p ( 2 S) ns,d autoionizing structure has been observed for the first time

Calculation of autoionization positions and widths with applications to Penning ionization reactions

International Nuclear Information System (INIS)

Isaacson, A.D.

1978-08-01

Using an approximate evaluation of Miller's golden rule formula to calculate autoionization widths which allows for the consideration only of L 2 functions, the positions and lifetimes of the lowest 1 , 3 P autoionizing states of He have been obtained to reasonable accuracy. This method has been extended to molecular problems, and the ab initio configuration interaction potential energy and width surfaces for the He(2 3 S) + H 2 system have been obtained. Quantum mechanical close-coupling calculations of ionization cross sections using the complex V* - (i/2) GAMMA-potential have yielded rate constants in good agreement with the experimental results of Lindinger, et al. The potential energy surface of the He(2 1 S) + H 2 system has also been obtained and exhibits not only a high degree of anisotropy, but also contains a relative maximum for a perpendicular (C 2 /sub v/) approach which appears to arise from s-p hybridization of the outer He orbital. However, similar ab initio calculations on the He(2 1 S) + Ar system do not show such anomalous structure. In addition, the complex poles of the S-matrix (Siegert eigenvalues) were calculated for several autoionizing states of He and H - , with encouraging results even for quite modest basis sets. This method was extended to molecular problems, and results obtained for the He(2 3 S) + H and He(2 1 S) + H systems. 75 references

Quasimolecular autoionization in the collisions He+ - He, H2

International Nuclear Information System (INIS)

Ogurtsov, G.N.; Krupyshev, A.G.; Gordeev, Yu.S.

1993-01-01

Data on the autoionization transition level width dependence Γ(R) for He + - He, He + - H 2 pairs are obtained. Data on the probability of autoionization transition in a three-atom quasimolecule are obtained for the first time. It is shown that Γ(R) values for He + - He 2 quasimolecule exceed notably the similar values for isoelectron He + - He quasimolecule and may reach ∼ 1 eV. 6 refs., 2 figs

4pnp J=0e-2e autoionizing series of calcium: experimental and theoretical analysis

International Nuclear Information System (INIS)

Bolovinos, A.; Luc-Koenig, E.; Assimopoulos, S.; Lyras, A.; Karapanagioti, N.E.; Crete Univ., Iraklion; Charalambidis, D.; Crete Univ., Iraklion; Aymar, M.

1996-01-01

The even parity 4pnp J=0, 1, 2 doubly excited autoionizing states of neutral calcium in an atomic beam are investigated by a two-step isolated core excitation (ICE) method using two different combinations of polarization of the laser beams. The different excited energy levels are assigned to nine autoionizing Rydberg series 4p 1/2,3/2 np J=0, 1, 2 for 8≤n≤22. The theoretical interpretation is achieved by a combination of the eigenchannel R-matrix theory and the multichannel quantum defect (MQDT) method. Two, five and six closed interacting channels are introduced for the J=0, J=1 and J=2 series respectively. Theoretical energy level positions, autoionization widths and excitation profiles are compared with the experimental data, confirming the identification of the observed structures and providing evidence of extended mixing between the 4p 1/2 np and 4p 3/2 np series. (orig.). With 9 figs., 3 tabs

Systematic investigation of electron impact excitation-autoionization from the ground state of highly charged GaI-like ions through ΔN = 1 transitions

International Nuclear Information System (INIS)

Oreg, J.; Bar-Shalom, A.; Goldstein, W.H.; Mandlebaum, P.; Mittnik, D.; Meroz, E.; Schwob, J.L.; Klapisch, M.

1991-01-01

A systematic variation in the line intensity ratios of GaI-like and ZnI-like ions of rare earth elements has been recently observed in spectra emitted in a low density, high temperature Tokamak plasma. This variation is shown to be correlated with the gradual opening of autoionizing channels through inner-shell excited configurations of the GaI-like charge-state. These channels enhance the indirect ionization rate of GaI-like ions through excitation-autoionization (EA), effecting the ionization balance and temperatures of greatest abundance. The authors a systematic investigations of EA and direct impact ionizations (DI) in the GaI-like isoelectronic sequence from Mo (Z = 42) to Dy (Z = 66). As Z decreases from Dy to Pr (Z = 59) the levels of the configuration 3d 9 4p4f, which are excited from the ground state by strong dipole collisional transitions, gradually cross the first ionization limit of the ion and are responsible for this ionization enhancement. When Z decreases further an additional channel is opened through the configuration 3d 9 4p4d

Electron streaking in the autoionization region of H2

International Nuclear Information System (INIS)

Palacios, Alicia; González-Castrillo, Alberto; Martín, Fernando

2015-01-01

We use a UV-pump/IR-probe scheme, combining a single attosecond UV pulse and a 750 nm IR pulse, to explore laser-assisted photoionization of the hydrogen molecule in the autoionization region. The electron energy distributions exhibit unusual streaking patterns that are explored for different angles of the electron ejection with respect to the polarization vector and the molecular axis. Moreover, by controlling the time delay between the pulses, we observe that one can suppress the autoionization channel. (paper)

Excitation of autoionizing states of helium by 100 keV proton impact: theory and experiment

International Nuclear Information System (INIS)

Godunov, A.L.; Moretto-Capelle, P.; Bordenave-Montesquieu, D.; Benhenni, M.; Bordenave-Montesquieu, A.

1997-01-01

A joint theoretical and experimental study of the excitation of the autoionizing (2s 2 ) 1 S, (2p 2 ) 1 D and (2s2p) 1 P states of helium by 100 keV proton impact is presented for the first time. The role of the three-body Coulomb interaction in the final state between the ejected electron, the scattered proton and the recoil helium ion is emphasized. Calculations have been carried out with inclusion of the three-body Coulomb interaction and within an expansion of a two-electron excitation amplitude in powers of projectile-target interaction up to the second order. A new parametrization is proposed to describe resonance profiles distorted by the Coulomb interaction in the final state (CIFS). New high-resolution (up to 68 meV) measurements of electron emission spectra made it possible to resolve the near-lying (2p 2 ) 1 D and (2s2p) 1 P resonances and reveal an evident distortion of the resonance profiles by CIFS for forward electron ejection angles below 40 o . (author)

Enhanced asymmetry in few-cycle attosecond pulse ionization of He in the vicinity of autoionizing resonances

International Nuclear Information System (INIS)

Djiokap, J M Ngoko; Starace, Anthony F; Hu, S X; Jiang Weichao; Peng Liangyou

2012-01-01

By solving the two-active-electron, time-dependent Schrödinger equation in its full dimensionality, we investigate the carrier-envelope phase (CEP) dependence of single ionization of He to the He + (1s) state triggered by an intense few-cycle attosecond pulse with carrier frequency ω corresponding to the energy ℏω = 36 eV. Effects of electron correlations are probed by comparing projections of the final state of the two-electron wave packet onto field-free highly correlated Jacobi matrix wave functions with projections onto uncorrelated Coulomb wave functions. Significant differences are found in the vicinity of autoionizing resonances. Owing to the broad bandwidths of our 115 and 230 as pulses and their high intensities (1–2 PW cm −2 ), asymmetries are found in the differential probability for ionization of electrons parallel and antiparallel to the linear polarization axis of the laser pulse. These asymmetries stem from interference of the one- and two-photon ionization amplitudes for producing electrons with the same momentum along the linear polarization axis. Whereas these asymmetries generally decrease with increasing ionized electron kinetic energy, we find a large enhancement of the asymmetry in the vicinity of two-electron doubly excited (autoionizing) states on an energy scale comparable to the widths of the autoionizing states. The CEP dependence of the energy-integrated asymmetry agrees very well with the predictions of time-dependent perturbation theory (Pronin et al 2009 Phys. Rev. A 80 063403). (paper)

Systematic investigation of electron impact excitation-autoionization from the ground state of highly charged GaI-like ions through ΔN=1 transitions

International Nuclear Information System (INIS)

Oreg, J.; Bar-Shalom, A.; Mandlebaum, P.; Mittnik, D.; Meroz, E.; Schwob, J.L.; Klapisch, M.

1991-01-01

A systematic variation in the line intensity ratios of GaI-like and ZnI-like ions of rare earth elements has been recently observed in spectra emitted in a low density, high temperature tokamak plasma. This variation is shown to be correlated with the gradual opening of autoionizing channels through inner-shell excited configurations of the GaI-like charge-state. These channels enhance the indirect ionization rate of GaI-like ions through excitation-autoionization (EA), effecting the ionization balance and temperatures of greatest abundance. We present a systematic investigation of EA and direct impact ionization (DI) in the GaI-like isoelectronic sequence from Mo (Z = 42) to Dy (Z = 66). As Z decreases from Dy to Pr (Z = 59) the levels of the configuration 3d 9 4p4f, which are excited from the ground state by strong dipole collisional transitions, gradually cross the first ionization limit of the ion and are responsible for this ionization enhancement. When Z decreases further an additional channel is opened through the configuration 3d 9 4p4d. 9 refs., 3 figs., 1 tab

Simple discretization method for autoionization widths. III. Molecules

International Nuclear Information System (INIS)

Macas, A.; Martn, F.; Riera, A.; Yanez, M.

1987-01-01

We apply a new method to calculate widths of two-electron Feshbach resonances, which was described in detail and applied to atomic systems in preceding articles (this issue), to molecular and quasimolecular autoionizing states. For simplicity in the programming effort, we restrict our calculations to the small-R region where one-centered expansions are sufficiently accurate to describe the wave functions. As test cases, positions and widths for the H 2 , He 2 /sup 2+/, HeH + , and LiHe/sup 3+/ resonances of lowest energy are computed for R<0.6 a.u. The advantage of using block-diagonalization techniques to define diabatic resonant states instead of generalizing the Feshbach formalism is pointed out

Identification of weak autoionizing resonances observed through fluorescence from the satellite states of Ar{sup +}

Energy Technology Data Exchange (ETDEWEB)

McLaughlin, K.W.; Yenen, O.; Samson, J.A.R. [Univ. of Nebraska, Lincoln, NE (United States)] [and others

1997-04-01

Photoionization accompanied by excitation of the residual ionic state violates an independent electron model since, according to QED, photons interact only with individual electrons. By allowing measurements at a threshold event with high resolution, the observation of the fluorescence from the decay of these excited states (satellite states) is a sensitive method in the study of electron-electron interactions, providing complementary information to photoelectron spectroscopy. In the measurements reported here, an atomic beam of argon has been photoionized with 34 to 39 eV synchrotron radiation at beamline 9.0.1 of the Advanced Light Source. This energy range encompasses the 3p{sup 4} [{sup 3}P] 4p {sup 4}P, {sup 2}P, and {sup 2}D as well as the [{sup 1}D]4p {sup 2}F satellite states of Ar{sup +}. By observing the fine-structure resolved fluorescence from these satellite states, new Rydberg series and extensions of previously known series have been resolved with an energy resolution of 3 meV. With the high photon flux available from the high resolution monochromator of beamline 9.0.1, even the weakly excited [{sup 3}P] 4p ({sup 2}S) ns,d autoionizing structure has been observed for the first time.

Excitation of autoionizing states of helium by 100 keV proton impact: theory and experiment

Energy Technology Data Exchange (ETDEWEB)

Godunov, A.L.; Moretto-Capelle, P.; Bordenave-Montesquieu, D.; Benhenni, M.; Bordenave-Montesquieu, A. [Universite Paul Sabatier, Toulouse (France). Laboratoire Collisions, Agregats, Reactivite; Schipakov, V.A. [Troitsk Institute for Innovation and Fusion Research, Moscow (Russian Federation)

1997-12-14

A joint theoretical and experimental study of the excitation of the autoionizing (2s{sup 2}){sup 1}S, (2p{sup 2}){sup 1}D and (2s2p){sup 1}P states of helium by 100 keV proton impact is presented for the first time. The role of the three-body Coulomb interaction in the final state between the ejected electron, the scattered proton and the recoil helium ion is emphasized. Calculations have been carried out with inclusion of the three-body Coulomb interaction and within an expansion of a two-electron excitation amplitude in powers of projectile-target interaction up to the second order. A new parametrization is proposed to describe resonance profiles distorted by the Coulomb interaction in the final state (CIFS). New high-resolution (up to 68 meV) measurements of electron emission spectra made it possible to resolve the near-lying (2p{sup 2}){sup 1}D and (2s2p){sup 1}P resonances and reveal an evident distortion of the resonance profiles by CIFS for forward electron ejection angles below 40{sup o}. (author).

Forces on nuclei moving on autoionizing molecular potential energy surfaces.

Science.gov (United States)

Moiseyev, Nimrod

2017-01-14

Autoionization of molecular systems occurs in diatomic molecules and in small biochemical systems. Quantum chemistry packages enable calculation of complex potential energy surfaces (CPESs). The imaginary part of the CPES is associated with the autoionization decay rate, which is a function of the molecular structure. Molecular dynamics simulations, within the framework of the Born-Oppenheimer approximation, require the definition of a force field. The ability to calculate the forces on the nuclei in bio-systems when autoionization takes place seems to rely on an understanding of radiative damages in RNA and DNA arising from the release of slow moving electrons which have long de Broglie wavelengths. This work addresses calculation of the real forces on the nuclei moving on the CPES. By using the transformation of the time-dependent Schrödinger equation, previously used by Madelung, we proved that the classical forces on nuclei moving on the CPES correlated with the gradient of the real part of the CPES. It was proved that the force on the nuclei of the metastable molecules is time independent although the probability to detect metastable molecules exponentially decays. The classical force is obtained from the transformed Schrödinger equation when ℏ=0 and the Schrödinger equation is reduced to the classical (Newtonian) equations of motion. The forces on the nuclei regardless on what potential energy surface they move (parent CPES or product real PESs) vary in time due to the autoionization process.

Excitation of the helium autoionizing states in He++He collisions, between 3 and 140 keV

International Nuclear Information System (INIS)

Bordenave-Montesquieu, A.; Gleizes, A.; Benoit-Cattin, P.

1982-01-01

The autoionization of the helium atom has been experimentally studied in He + +He collisions between 3 and 140 keV by electron spectrometry. The excitation of the two collision partners has been considered. Above 10 keV, the shapes and excitation cross sections of the 2s 2 1 S, 2s2p 3 P, 2p 2 1 D, and 2s2p 1 P are determined by a numerical fitting procedure which is reported in detail; below 10 keV the ( 1 D+ 1 P), and 2p 2 1 S line intensities are obtained by planimetry since important post-collision effects are observed. From the angular distributions measured below 15 keV, the relative sublevel populations are deduced for the 2p 2 1 D and 2s2p 1 P levels and are compared with those obtained by other authors in a coincidence experiment; the excitation processes are then discussed within the quasimolecular-excitation model. For the highest collision energies, the asymmetry of the angular distributions with respect to 90 0 as well as the line shapes above 100 keV are interpreted by the occurrence of sudden electronic transitions to the continuum. A comparison of the differential cross sections for emission of electrons by autoionization of the fast and slow particles permits us to show that the quasimolecule model cannot explain what is observed above a collision velocity of about 0.5 a.u. The dependence of the total cross sections against the collision energy is also discussed in terms of an evolution of the excitation mechanism from a quasimolecular to an atomic one; the specific variation of the 2s2p 3 P cross section strengthens this interpretation. These total cross sections are compared with those estimated from earlier H + +He data published by us; similar autoionization cross-section values are expected for the two systems at high collision velocity

Non-statistically populated autoionizing levels of Li-like carbon: Hidden-crossings

International Nuclear Information System (INIS)

Deveney, E.F.; Krause, H.F.; Jones, N.L.

1995-01-01

The intensities of the Auger-electron lines from autoionizing (AI) states of Li-like (1s2s2l) configurations excited in ion-atom collisions vary as functions of the collision parameters such as, for example, the collision velocity. A statistical population of the three-electron levels is at best incomplete and underscores the intricate dynamical development of the electronic states. The authors compare several experimental studies to calculations using ''hidden-crossing'' techniques to explore some of the details of these Auger-electron intensity variation phenomena. The investigations show promising results suggesting that Auger-electron intensity variations can be used to probe collision dynamics

Near-threshold electron-impact excitation of the (2p53s2)2P3/2,1/2 autoionizing states in sodium

International Nuclear Information System (INIS)

Borovik, A; Zatsarinny, O; Bartschat, K

2008-01-01

The ejected-electron excitation functions of the J = 3/2, 1/2 components of the (2p 5 3s 2 ) 2 P leading autoionizing doublet in sodium atoms were measured at an incident electron energy resolution of 0.25 eV over the incident electron energy range from the lowest excitation threshold up to 36 eV. On the basis of 56-state R-matrix (close-coupling) calculations, the observed strong near-threshold structures were classified as negative-ion resonances with likely configurations 2p 5 3s 2 3p and 2p 5 3s3p 2

The identification of autoionizing states of atomic chromium for the resonance ionization laser ion source of the ISOLDE radioactive ion beam facility

CERN Document Server

Goodacre, T Day

2017-01-01

The resonance ionization laser ion source (RILIS) is the principal ion source of the ISOLDE radioactive beam facility based at CERN. Using the method of in-source resonance ionization spectroscopy, an optimal three-step, three-resonance photo-ionization scheme has been developed for chromium. The scheme uses an ionizing transition to one of the 14 newly observed autoionizing states. This work increases the range of ISOLDE-RILIS ionized beams to 32 chemical elements. Details of the spectroscopic studies are described and the new ionization scheme is summarized. A link to the complete version of this document will be added here following publication:

The 4p6 autoionization cross section of Rb atoms excited by low-energy electron impact

International Nuclear Information System (INIS)

Borovik, A; Roman, V; Kupliauskienė, A

2012-01-01

The autoionization cross section of rubidium atoms was obtained by measuring the total normalized intensities of ejected-electron spectra arising from the decay of the 4p 5 n 1 l 1 n 2 l 2 autoionizing levels. The electron impact energy range from the 4p 6 excitation threshold at 15.31 up to 50 eV was investigated. The cross section reaches the maximum value of (2.9 ± 0.6) × 10 −16  cm 2 at 21.8 eV impact energy. The general behaviours of the cross section and the role of particular autoionizing configurations in its formation were considered on the basis of large-scale configuration interaction calculations of energies, cross sections, autoionization probabilities in 5snl(n ⩽ 7; l ⩽ 4) and 4d nl(n ⩽ 5; l ⩽ 2) configurations as well as the measured excitation functions for the lowest levels in 5s 2 and 4d5s configurations. The resonance behaviour of the cross section between 15.3 and 18.5 eV impact energy is caused exclusively by the negative-ion resonances present close to the excitation thresholds of the (5s 2 ) 2 P and (4d5s) 4 P autoionizing levels. At higher impact energies, the autoionization cross section is composed of contributions from the high-lying quartet and doublet levels in 4d5s, 5p and 5s5p, 5d, 6s, 6p configurations. From the comparison of the present data with available experimental and calculated ionization cross sections, the 5s + 4p 6 direct ionization cross section of rubidium atoms was determined with the maximum value of (7.2 ± 2.2) × 10 −16  cm 2 at 36 eV. It was also found that the 4p 6 excitation–autoionization is the dominant indirect ionization process contributing over 30% of the total single ionization of rubidium atoms by electron impact in the 15.3–50 eV energy range. (paper)

Angular correlation of autoionization electrons and photons emitted from collisionally aligned atomic states

International Nuclear Information System (INIS)

Eichler, J.; Fritsch, W.

1976-01-01

The angular correlation of autoionization electrons or of photons ejected from collisionally aligned excited atoms is calculated assuming unpolarized beam and target, and polarization-insensitive detectors. Starting from the two-step hypothesis for the formation and decay of the intermediate excited atoms, the angular correlation is expressed in terms of the density matrix describing the excited system. Using the symmetries of the density matrix, a minimal set of independent matrix elements is given and the conditions for which a complete determination of this set is experimentally possible are discussed. For the case of electron emission, simple examples are pointed out in which the angular correlation is independent of the reduced Coulomb matrix elements describing the decay. (author)

Excitation of the helium autoionizing states in He/sup +/+He collisions, between 3 and 140 keV

Energy Technology Data Exchange (ETDEWEB)

Bordenave-Montesquieu, A.; Gleizes, A.; Benoit-Cattin, P.

1982-01-01

The autoionization of the helium atom has been experimentally studied in He/sup +/+He collisions between 3 and 140 keV by electron spectrometry. The excitation of the two collision partners has been considered. Above 10 keV, the shapes and excitation cross sections of the 2s/sup 2/ /sup 1/S, 2s2p /sup 3/P, 2p/sup 2/ /sup 1/D, and 2s2p /sup 1/P are determined by a numerical fitting procedure which is reported in detail; below 10 keV the (/sup 1/D+/sup 1/P), and 2p/sup 2/ /sup 1/S line intensities are obtained by planimetry since important post-collision effects are observed. From the angular distributions measured below 15 keV, the relative sublevel populations are deduced for the 2p/sup 2/ /sup 1/D and 2s2p/sup 1/ P levels and are compared with those obtained by other authors in a coincidence experiment; the excitation processes are then discussed within the quasimolecular-excitation model. For the highest collision energies, the asymmetry of the angular distributions with respect to 90 /sup 0/ as well as the line shapes above 100 keV are interpreted by the occurrence of sudden electronic transitions to the continuum. A comparison of the differential cross sections for emission of electrons by autoionization of the fast and slow particles permits us to show that the quasimolecule model cannot explain what is observed above a collision velocity of about 0.5 a.u. The dependence of the total cross sections against the collision energy is also discussed in terms of an evolution of the excitation mechanism from a quasimolecular to an atomic one; the specific variation of the 2s2p /sup 3/P cross section strengthens this interpretation. These total cross sections are compared with those estimated from earlier H/sup +/+He data published by us; similar autoionization cross-section values are expected for the two systems at high collision velocity.

Interaction between resonances through autoionization continua near the 4s-threshold in KrII

International Nuclear Information System (INIS)

Demekhin, Ph V; Petrov, I D; Lagutin, B M; Sukhorukov, V L; Vollweiler, F; Klumpp, S; Ehresmann, A; Schartner, K-H; Schmoranzer, H

2005-01-01

The interaction between resonances through autoionization continua and the interaction between autoionization continua were investigated theoretically and experimentally for the photoionization process of the 4p- and 4s-shells and for the population of 4p 4 ( 3 P)5s 4 P J , 4p 4 ( 3 P)5s 2 P J and 4p 4 ( 3 P)4d 4 D J satellites of KrII. Cross sections for the satellite production and the angular distribution parameter of the fluorescence radiation were measured by photon-induced fluorescence spectroscopy after excitationx with linearly polarized monochromatized synchrotron radiation at exciting-photon energies between 28.45 eV and 29.95 eV with an exciting-photon energy resolution of 10 meV (FWHM). Measured cross sections are in good agreement with the computed ones. A refined assignment of resonances in the proximity of the 4s 1 4p 6 5p resonance was performed. It was concluded that there is a strong influence of the core rearrangement, of the interaction between resonances through the autoionization continua and of the interaction between autoionization continua, on the investigated processes on the basis of the observed good overall agreement between the computed and measured quantities

Three-colour photoionization optogalvanic spectroscopy in U-Ne hollow cathode discharges: observation of even-parity autoionization states of uranium

International Nuclear Information System (INIS)

Mandal, P.K.; Seema, A.U.; Das, R.C.; Shah, M.L.; Dev, Vas; Suri, B.M.

2013-01-01

Three-colour three-step photoionization spectroscopy of uranium has been performed in a U-Ne hollow cathode discharge tube by temporally resolving three-colour photoionization optogalvanic (PIOG) signal from the normal optogalvanic (OG) signal using three tunable pulsed dye lasers. U-Ne hollow cathode discharge tube has been used as a source of uranium atomic vapour and photoionization detector. Using this technique, photoionization spectra of uranium have been investigated systematically in the energy region 52150-52590 cm -1 , through three different excitation pathways, originating from its ground state, 0 cm -1 ( 5 L 0 6 ). By analyzing the three-colour photoionization spectra sixty new even-parity autoionization resonances of uranium have been identified and their probable total angular momentum (J) values have been assigned according to the J-momentum selection rule. (author)

Identification of very low energy projectile autoionizing transitions in high velocity collisions using zero-degree Auger electron spectroscopy

International Nuclear Information System (INIS)

Zouros, T.J.M.; Liao, C.; Montenegro, E.C.; Hagmann, S.; Richard, P.; Grabbe, S.; Bhalla, C.P.; Wong, K.L.

1995-01-01

The unusual looking ''mesa''-shaped cusp observed in O 3+ collisions with He [N. Stolterfoht et al., Proc. 2nd US-Mexico Symp. on Atomic and Molecular Phy. eds. A. Cisneros and T. Morgan (Instituto de Fysica, Cuernavaca, Mexico, 1986) p. 51.], has been investigated using zero-degree electron spectroscopy, in both high resolution singles measurements and lower resolution electron-projectile coincidence measurements at 10, 15 and 23 MeV. The high resolution studies indicate the ''mesa'' peak to be actually composed of primarily two (other than the cusp) very strong autoionizing peaks corresponding to energies of 60 and 100 meV in the emitter frame. The coincidence studies, indicate these lines to originate from excitation of the O 3+ ion followed by autoionization. Ongoing Hartree-Fock-Slater calculations, severely tested at these extremely small transition energies, indicate that these lines can indeed result from the autoionization of t he O 3+ (1s 2 2s2p5l) Rydberg states produced during the collision. Furthermore, the unusually sharp edges of these lines giving rise to the characteristic ''mesa''-shape look, can be explained in terms of the kinematic constraints imposed by the energy and angular acceptance range of the spectrometer. (orig.)

Quenching H2 autoionization interferences with ultrashort xuv laser pulses

International Nuclear Information System (INIS)

González-Castrillo, Alberto; Palacios, Alicia; Martín, Fernando; Bachau, Henri

2012-01-01

In contrast with atomic photoionization or molecular direct photoionization, in the autoionization region, electron and proton kinetic-energy differential probabilities resulting from a short pulse cannot be reconstructed by the incoherent superposition of those resulting from long pulses.

Influence of increasing nuclear charge on the Rydberg spectra of Xe, Cs+, and Ba++: Correlation, term dependence, and autoionization

International Nuclear Information System (INIS)

Hill, W.T. III; Cheng, K.T.; Johnson, W.R.; Lucatorto, T.B.; McIlrath, T.J.; Sugar, J.

1982-01-01

The first experimental-theoretical study of Rydberg autoionizing resonances along an isoelectronic sequence is presented. This analysis demonstrates the intimate connection between electron-electron correlation, term-dependence, and autoionization and underscores the power of multichannel quantum defect theory in analyzing complex spectra

Autoionization of inner atomic shells during β decay

International Nuclear Information System (INIS)

Batkin, I.S.; Kopytin, I.V.; Smirnov, Y.G.; Churakova, T.A.

1981-01-01

A theory describing the autoionization of inner atomic shells in nuclear β decay has been developed. It is shown on the basis of diagram technique that in first order in Z -1 the matrix element of the process is represented in the form of the sum of two terms, one of which corresponds to ionization of an electron shell of an atom with sudden change of the charge of the nucleus, and the other to direct interaction of a β particle with the electrons of the atomic shell. Specific calculations are carried out in the nonrelativistic approximation with use of electron wave functions and a Green's function constructed with a Teitz screened Coulomb potential, the systematic inclusion of the contribution of the direct mechanism being carried out for the first time. For the case of β decay of the isotopes 35 S, 45 Ca, 63 Ni, 147 Pm, and 151 Sm we have calculated the shape of the spectrum of shakeup electrons and the integrated probability of autoionization of the K shell. It was found that the contribution of the direct mechanism in all cases considered is significant

Relativistic decay widths of autoionization processes: The relativistic FanoADC-Stieltjes method

Energy Technology Data Exchange (ETDEWEB)

Fasshauer, Elke, E-mail: Elke.Fasshauer@uit.no [Centre for Theoretical and Computational Chemistry, Department of Chemistry, University of Tromsø–The Arctic University of Norway, N-9037 Tromsø (Norway); Theoretische Chemie, Universität Heidelberg, Im Neuenheimer Feld 229, D-69120 Heidelberg (Germany); Kolorenč, Přemysl [Institute of Theoretical Physics, Faculty of Mathematics and Physics, Charles University in Prague, V Holešovičkách 2, 180 00 Prague (Czech Republic); Pernpointner, Markus [Theoretische Chemie, Universität Heidelberg, Im Neuenheimer Feld 229, D-69120 Heidelberg (Germany)

2015-04-14

Electronic decay processes of ionized systems are, for example, the Auger decay or the Interatomic/ Intermolecular Coulombic Decay. In both processes, an energetically low lying vacancy is filled by an electron of an energetically higher lying orbital and a secondary electron is instantaneously emitted to the continuum. Whether or not such a process occurs depends both on the energetic accessibility and the corresponding lifetime compared to the lifetime of competing decay mechanisms. We present a realization of the non-relativistically established FanoADC-Stieltjes method for the description of autoionization decay widths including relativistic effects. This procedure, being based on the Algebraic Diagrammatic Construction (ADC), was adapted to the relativistic framework and implemented into the relativistic quantum chemistry program package Dirac. It is, in contrast to other existing relativistic atomic codes, not limited to the description of autoionization lifetimes in spherically symmetric systems, but is instead also applicable to molecules and clusters. We employ this method to the Auger processes following the Kr3d{sup −1}, Xe4d{sup −1}, and Rn5d{sup −1} ionization. Based on the results, we show a pronounced influence of mainly scalar-relativistic effects on the decay widths of autoionization processes.

Kinetic and spectral descriptions of autoionization phenomena associated with atomic processes in plasmas

Science.gov (United States)

Jacobs, Verne L.

2017-06-01

This investigation has been devoted to the theoretical description and computer modeling of atomic processes giving rise to radiative emission in energetic electron and ion beam interactions and in laboratory plasmas. We are also interested in the effects of directed electron and ion collisions and of anisotropic electric and magnetic fields. In the kinetic-theory description, we treat excitation, de-excitation, ionization, and recombination in electron and ion encounters with partially ionized atomic systems, including the indirect contributions from processes involving autoionizing resonances. These fundamental collisional and electromagnetic interactions also provide particle and photon transport mechanisms. From the spectral perspective, the analysis of atomic radiative emission can reveal detailed information on the physical properties in the plasma environment, such as non-equilibrium electron and charge-state distributions as well as electric and magnetic field distributions. In this investigation, a reduced-density-matrix formulation is developed for the microscopic description of atomic electromagnetic interactions in the presence of environmental (collisional and radiative) relaxation and decoherence processes. Our central objective is a fundamental microscopic description of atomic electromagnetic processes, in which both bound-state and autoionization-resonance phenomena can be treated in a unified and self-consistent manner. The time-domain (equation-of-motion) and frequency-domain (resolvent-operator) formulations of the reduced-density-matrix approach are developed in a unified and self-consistent manner. This is necessary for our ultimate goal of a systematic and self-consistent treatment of non-equilibrium (possibly coherent) atomic-state kinetics and high-resolution (possibly overlapping) spectral-line shapes. We thereby propose the introduction of a generalized collisional-radiative atomic-state kinetics model based on a reduced

Excitation energies, radiative and autoionization rates, dielectronic satellite lines, and dielectronic recombination rates for excited states of Rb-like W from Kr-like W [Relativistic atomic data for Rb-like tungsten

International Nuclear Information System (INIS)

Safronova, University I.; Safronova, A. S.; Beiersdorfer, P.

2016-01-01

Energy levels, radiative transition probabilities, and autoionization rates for [Ni]4s 2 4p 6 nl, [Ni]4s 2 4p 5 4l ′ nl (l ′ =d,f,n = 4–7), [Ni]4s4p 6 4l ′ nl, (l ′ =d,f,n = 4–7), [Ni]4s 2 4p 5 5l ′ nl (n = 5–7), and [Ni]4s4p 6 6l ′ nl (n = 6–7) states in Rb-like tungsten (W37+) are calculated using the relativistic many-body perturbation theory method (RMBPT code) and the Hartree–Fock-relativistic method (COWAN code). Autoionizing levels above the [Ni]4s 2 4p 6 threshold are considered. It is found that configuration mixing among [Ni]4s 2 4p 5 4l ′ nl and [Ni]4s4p 6 4l ′ nl plays an important role for all atomic characteristics. Branching ratios relative to the first threshold and intensity factors are calculated for satellite lines, and dielectronic recombination (DR) rate coefficients are determined for the [Ni]4s 2 4p 6 nl (n = 4–7) singly excited states, as well as the [Ni]4s 2 4p 5 4dnl, [Ni]4s 2 4p 5 4fnl, [Ni]4s4p 6 4dnl, [Ni]4s 2 4p 6 4fnl, (n = 4–6), and [Ni]4s 2 4p 5 5l ′ 5l doubly excited nonautoionizing states in Rb-like W37+ ion. Contributions from the [Ni]4s24p 6 4fnl (n = 6–7), [Ni]4s 2 4p 5 5l ′ nl (n = 5–6), and [Ni]4s 2 4p 5 6l ′ nl (n = 6–7) doubly excited autoionizing states are evaluated numerically. The high-n state (with n up to 500) contributions are very important for high temperatures. These contributions are determined by using a scaling procedure. Synthetic dielectronic satellite spectra from Rb-like W are simulated in a broad spectral range from 8 to 70 Å. Here, these calculations provide highly accurate values for a number of W 37+ properties useful for a variety of applications including for fusion applications.

Zero degree target electron spectroscopy: Double excitation, autoionization of helium in fast e, H+, He+, and He2+ collisions

International Nuclear Information System (INIS)

Wang, H.; Bruch, R.; Yan, Y.

1994-01-01

The authors have measured zero degree high-resolution spectra and double differential cross sections (DDCS) for double - excitation-autoionization of Helium atoms. They have also measured direct ionization DDCS at zero degree observation angle. The cross sections are absolutely calibrated. Electrons from the energy 150 to 1000 eV, protons from 100 keV to 1.5 MeV, He + from 400 keV to 1.5 MeV, and He 2+ from 400 keV to 1.6 MeV were used as projectiles. The zero degree observation angle provides a unique opportunity to maximize the interaction between the emitted electron, the ionized target atom, and the charged projectile particles. The doubly excited autoionizing (2lnl') states of He have been observed as a function of the collision conditions such as impact velocity, projectile charge sign, and type of projectile, specifically for the dominating (2p 2 ) 1 D → (lsεd) and (2s2p) 1 P 0 → (lsεp) channels

Using block diagonalization to determine dissociating autoionizing states: Application to N2H, and the outlook for SH

Directory of Open Access Journals (Sweden)

Kashinski D.O.

2015-01-01

Full Text Available We describe our implementation of the block diagonalization method for calculating the potential surfaces necessary to treat dissociative recombination (DR of electrons with N2H+. Using the methodology we have developed over the past few years, we performed multi-reference, configuration interaction calculations for N2H+ and N2H with a large active space using the GAMESS electronic structure code. We treated both linear and bent geometries of the molecules, with N2 fixed at its equilibrium separation. Because of the strong Rydberg-valence coupling in N2H, it is essential to isolate the appropriate dissociating, autoionizing states. Our procedure requires only modest additional effort beyond the standard methodology. The results indicate that the crossing between the dissociating neutral curve and the initial ion potential is not favorably located for DR, even if the molecule bends. The present calculations thereby confirm our earlier results for linear N2H and reinforce the conclusion that the direct mechanism for DR is likely to be inefficient. We also describe interesting features of our preliminary calculations on SH.

Autoionization spectra of He excited by fast (MeV) H+, He+, and Li/sup n+/ (n = 1,2,3) ions

International Nuclear Information System (INIS)

Schneider, D.; Arcuni, P.; Bruch, P.; Stoeffler, W.

1983-01-01

Autoionization spectra of He following excitation by 1 to 3 MeV H + , He + , and Li/sup n+/ (n = 1,2,3) have been measured as a function of observation angle. The (2p 2 ) 1 D and (2s2p) 1 P resonances have been examined and a strong dependence on projectile velocities, charge state and observation angle was found

Autoionizing energy levels and extended spectral analysis of copper-like gallium and germanium (Ga III, Ge IV)

International Nuclear Information System (INIS)

Ryabtsev, A.N.; Wyart, J.F.

1987-01-01

The spark spectra of doubly ionized gallium and triply ionized germanium have been observed. Lines broadened by autoionization have been attributed to 3d 9 4p 2 - 3d 10 4p transitions on the basis of parametric studies of the configurations 3d 9 4p 2 + 3d 9 4s4d. Line strengths and autoionization widths support the identifications. The analysis of the 3d 10 nl system has been corrected and extended. The ionization energy of Ge IV is 368 720 cm -1 ± 10 cm -1 . (orig.)

Autoionizing Rydberg series in alkali atoms

International Nuclear Information System (INIS)

Kulov, M.A.; Ivanov, V.K.; Cherepkov, N.A.

2004-01-01

Full text: The results of many-body calculations of autoionizing resonance structure in neutral potassium, rubidium and cesium associated with the ns 2 np 6 (n+1)s → nsnp 6 (n+1)smp Rydberg excitations are presented. The numerical method based on the Many-Body Perturbation Theory takes into account the dynamic polarization and screening of electron-electron interaction by collective motion of the whole electronic system. The many-electron effects are shown to determine the resonance shapes. The numerically obtained cross section for photoionization of 3p electrons in neutral K in the vicinity of the 3s threshold is presented. The structure has the complex shape of 3s → mp resonances due to different behavior of electrons with the opposite spin projections

Autoionization structure of nitric oxide (NO) at the first ionization limit

International Nuclear Information System (INIS)

Miescher, E.; Lee, Y.T.; California Univ., Berkeley; Guertler, P.

1977-12-01

A new and more detailed interpretation is given to the fine structure in the photoionization curve of cold NO observed by Ng, Mahan and Lee (J. Chem. Phys. 65 (1976) 1975). Resonances are assigned to autoionizing np and nd delta Rydberg levels which give prominent diffuse absorption bands in a spectrum recorded with the synchrotron radiation continuum. Δv [de

Autoionization spectra of He excited by fast (MeV) H/sup +/, He/sup +/, and Li/sup n+/ (n = 1,2,3) ions

Energy Technology Data Exchange (ETDEWEB)

Schneider, D.; Arcuni, P.; Bruch, P.; Stoeffler, W.

1983-01-01

Autoionization spectra of He following excitation by 1 to 3 MeV H/sup +/, He/sup +/, and Li/sup n+/ (n = 1,2,3) have been measured as a function of observation angle. The (2p/sup 2/)/sup 1/D and (2s2p)/sup 1/P resonances have been examined and a strong dependence on projectile velocities, charge state and observation angle was found.

Signatures of attosecond electronic–nuclear dynamics in the one-photon ionization of molecular hydrogen: analytical model versus ab initio calculations

International Nuclear Information System (INIS)

Medišauskas, Lukas; Ivanov, Misha Yu; Morales, Felipe; Plimak, Lev; Smirnova, Olga; Palacios, Alicia; González-Castrillo, Alberto; Martín, Fernando

2015-01-01

We present an analytical model based on the time-dependent WKB approximation to reproduce the photoionization spectra of an H 2 molecule in the autoionization region. We explore the nondissociative channel, which is the major contribution after one-photon absorption, and we focus on the features arising in the energy differential spectra due to the interference between the direct and the autoionization pathways. These features depend on both the timescale of the electronic decay of the autoionizing state and the time evolution of the vibrational wavepacket created in this state. With full ab initio calculations and with a one-dimensional approach that only takes into account the nuclear wavepacket associated to the few relevant electronic states we compare the ground state, the autoionizing state, and the background continuum electronic states. Finally, we illustrate how these features transform from molecular-like to atomic-like by increasing the mass of the system, thus making the electronic decay time shorter than the nuclear wavepacket motion associated with the resonant state. In other words, autoionization then occurs faster than the molecular dissociation into neutrals. (paper)

Doubly and triply excited states for different plasma sources

International Nuclear Information System (INIS)

More, R.M.; Safronova, U.I.

2000-01-01

Autoionizing rates of doubly excited states as nln'l' configurations with n=2-9 and n'=2-9 are calculated. Analytical expressions of decay amplitude for two-electron system are derived. Expressions for autoionizing rates with averaging over LS are obtained for many-electron systems. The n and l dependence of doubly excited states as nln'l' configurations are investigated. (author)

Excitation of the (2p2)1D and (2s2p)1P autoionizing states of helium by 200 eV electron impact

International Nuclear Information System (INIS)

Godunov, A.L.; McGuire, J.H.; Schipakov, V.S.; Crowe, A.

2002-01-01

We report full second Born calculations with inclusion of post-collision interactions for excitation of the (2p 2 ) 1 D and (2s2p) 1 P autoionizing states of helium by 200 eV electron impact. The calculations are compared to (e, 2e) measurements of McDonald and Crowe (McDonald D G and Crowe A 1993 J. Phys. B: At. Mol. Opt. Phys. 26 2887-97) and Lower and Weigold (Lower J and Weigold E 1990 J. Phys. B: At. Mol. Opt. Phys. 23 2819-45). It is shown that post-collision interactions or Coulomb interactions in the final state between the scattered particle, the ejected electron and the recoil ion have a strong influence on both the direct ionization and resonance profiles around the binary lobe. The second-order terms in the amplitude of double electron excitation also play an observable role under these kinematic conditions. Reasonable agreement is found between the full-scale calculations and the experimental data. (author). Letter-to-the-editor

Effect of excitation-autoionization processes on the line emission of Zn I-- and GaI--like rare-earth ions in hot coronal plasmas

International Nuclear Information System (INIS)

Mandelbaum, P.; Finkenthal, M.; Meroz, E.; Schwob, J.L.; Oreg, J.; Goldstein, W.H.; Klapisch, M.; Osterheld, L.; Bar Shalom, A.; Lippman, S.; Huang, L.K.; Moos, H.W.

1990-01-01

A systematic variation in the line-intensity ratios of GaI-- and ZnI--like Pr (Z=59) to Dy (Z=66) ions has been observed in spectra emitted by atoms injected in a low-density high-temperature tokamak plasma. This variation is shown to be correlated with the progressive closing of the autoionizing channels through the excited 3d 9 4s 2 4p4f configuration in the GaI--like ionization state as Z increases

Angular distributions of autoionization electrons from Ne(2p43s2) 1D in Li+-Ne collisions

International Nuclear Information System (INIS)

Oud, M.; Pas, S.F. te; Westerveld, W.B.; Niehaus, A.

1993-01-01

Angular distributions of autoionization electrons from Ne(2p 4 3s 2 ) 1 D due to Li + -Ne collisions measured in coincidence with the scattered projectile ions are presented. The measurements are performed at four different collision energies between 1.0 keV and 3.0 keV, and the complex population amplitudes for the excited 1 D state are determined. A nearly pure M = O sublevel population is found with respect to an axis coinciding with the direction of the angular distribution. The direction of the angular distribution is found to deviate from the final direction of the asymptotic internuclear axis. (author)

Dielectronic recombination rate coefficients to the excited states of CIII from CIV

Energy Technology Data Exchange (ETDEWEB)

Safronova, U.; Kato, Takako; Ohira, Mituhiko

1996-07-01

Energy levels, radiative transition probabilities and autoionization rates for CIII including 1s{sup 2}2pnl` (n=2/6, l`{<=}(n-1)) and 1s{sup 2}3lnl` (n=3/6, l`{<=}(n-1)) states were calculated by using multi-configurational Hartree-Fock (Cowan code) method. Autoionizing levels above the 1s{sup 2}2s and 1s{sup 2}2p thresholds were considered and their contributions were computed. Branching ratios on the autoionization rate to the first threshold and intensity factor were calculated for satellite lines of CIII ion. The dielectronic recombination rate coefficients to the excited states for n=2-6 were calculated. The values for the excited states higher than n=6 were extrapolated and the total dielectronic recombination rate coefficients were also derived. The rate coefficients to the excited states were fitted to an analytical formula and the fitting parameters are given. (author)

Optical studies of multiply excited states

International Nuclear Information System (INIS)

Mannervik, S.

1989-01-01

Optical studies of multiply-excited states are reviewed with emphasis on emission spectroscopy. From optical measurements, properties such as excitation energies, lifetimes and autoionization widths can be determined with high accuracy, which constitutes a challenge for modern computational methods. This article mainly covers work on two-, three- and four-electron systems, but also sodium-like quartet systems. Furthermore, some comments are given on bound multiply-excited states in negative ions. Fine structure effects on transition wavelengths and lifetimes (autoionization) are discussed. In particular, the most recent experimental and theoretical studies of multiply-excited states are covered. Some remaining problems, which require further attention, are discussed in more detail. (orig.) With 228 refs

Evidence of the 2s2p(1P) doubly excited state in the harmonic generation spectrum of helium

International Nuclear Information System (INIS)

Ngoko Djiokap, J. M.; Starace, Anthony F.

2011-01-01

By solving the two-active-electron time-dependent Schroedinger equation in an intense, ultrashort laser field, we investigate evidence of electron correlations in the high-order harmonic generation spectrum of helium. As the frequency of the driving laser pulse varies from 4.6 to 6.6 eV, the 13th, 11th, and 9th harmonics sequentially become resonant with the transition between the ground state and the isolated 2s2p( 1 P) autoionizing state of helium, which dramatically enhances these harmonics and changes their profiles. When each of the 9th and 13th harmonics are in resonance with this autoionizing state, there is also a low-order multiphoton resonance with a Rydberg state, resulting in a particularly large enhancement of these harmonics relative to neighboring harmonics. When the 11th harmonic is in resonance with the 2s2p( 1 P) autoionizing state, the 13th harmonic is simultaneously in resonance with numerous higher-energy autoionizing states, resulting in a competition between these two harmonics for intensity. These results demonstrate that even electron correlations occurring over a narrow energy interval can have a significant effect on strong-field processes such as harmonic generation.

Autoionic microscopy of damage regions of single atom displacement cascades in metals

International Nuclear Information System (INIS)

Suvorov, A.L.

1981-01-01

The defect region formation characterized by zones of depletion with atoms and interstitial halos arizing during displacement cascade development in an irradiated metal is considered. in experimental autoionmicroscopic analysis technique is used. The analysis procedure is briefly discussed: the experiment, the defect identification on autoionic image microphotos, computer data processing. The technique was applied for pure tungsten irradiated with 12 and 5.8 MeV deuterons and fission neutrons, and for tungsten-1.5% ThO 2 alloy irradiated with fast neutrons from fission fragments

Auto transfer to Rydberg states during ion-atom collisions

International Nuclear Information System (INIS)

Bachau, H.; Harel, C.; Barat, M.; Roncin, P.; Bordenave-Montesquieu, A.; Moretto-Capelle, P.; Benoit-Cattin, P.; Gleizes, A.; Benhenni, M.

1993-01-01

Electron capture by slow multiply charged ions colliding on rare-gas targets is known to populate highly excited states of the projectile. On the basis of experimental measurement of energy and angle differential cross-sections we have shown that capture to a resonant doubly excited state may lead to Autoionizing Double Capture (ADC) as well as to True Double Capture (TDC). In this model TDC appears as a two step post-collisional process, the state populated by the collision decays to (or delutes into) a dense adjacent Rydberg series, followed by radiative deexcitation of the inner electron of the (3,n) Rydberg states. We report here new experimental observations in electron spectra measured in N 7+ +He. Auto transfer to Rydber states has also important consequences on the determination of the lifetime of the autoionizing states, some discrepancies between theoretical width values for low N 5+ (4,4) resonant states will be discussed and partially resolved

Auto transfer to Rydberg states during ion-atom collisions

Energy Technology Data Exchange (ETDEWEB)

Bachau, H.; Harel, C. (Laboratoire des Collisions Atomiques, Unite Propre de Recherche 260 du CNRS, Universite Bordeaux I, 351 Cours de la Liberation, 33405 Talence (France)); Barat, M.; Roncin, P. (Laboratoire des Collisions Atomiques et Moleculaires, Unite associee 281 du CNRS, Universite de Paris Sud, Batiment 351, 91405 Orsay (France)); Bordenave-Montesquieu, A.; Moretto-Capelle, P.; Benoit-Cattin, P.; Gleizes, A.; Benhenni, M. (IRSAMC, Unite associee 770 du CNRS, Universite Paul Sabatier, 118 route de Narbonne, 31062 Toulouse (France))

1993-06-05

Electron capture by slow multiply charged ions colliding on rare-gas targets is known to populate highly excited states of the projectile. On the basis of experimental measurement of energy and angle differential cross-sections we have shown that capture to a resonant doubly excited state may lead to Autoionizing Double Capture (ADC) as well as to True Double Capture (TDC). In this model TDC appears as a two step post-collisional process, the state populated by the collision decays to (or delutes into) a dense adjacent Rydberg series, followed by radiative deexcitation of the inner electron of the (3,n) Rydberg states. We report here new experimental observations in electron spectra measured in [ital N][sup 7+]+[ital He]. Auto transfer to Rydber states has also important consequences on the determination of the lifetime of the autoionizing states, some discrepancies between theoretical width values for low [ital N][sup 5+](4,4) resonant states will be discussed and partially resolved.

Influence of Doppler and 'Stark' effects on the shape of the autoionization peaks in electron energy spectra produced in ion-atom collisions

International Nuclear Information System (INIS)

Gleizes, A.; Benoit-Cattin, P.; Bordenave-Montesquieu, A.; Merchez, H.

1976-01-01

A detailed study is given of the influence of the Doppler shift and broadening on the spectra of electrons ejected by autoionization in collisions between heavy particles. General formulae have been obtained which permit the validity of results already published by other authors to be discussed. These results have been applied to the spectra of electrons ejected in He + -He collisions at 15 keV. The variation of the width of the autoionization peaks against ejection angle is well explained by Doppler broadening. On the contrary, the shape of these peaks cannot be due to the Doppler effect but rather to the Stark effect which is also studied in various experimental cases; it has been verified that the latter effect disappears in collisions between neutral particles for which symmetric peaks at 15 keV are obtained. (author)

Decay of hollow states in time-dependent density functional theory

Energy Technology Data Exchange (ETDEWEB)

Kapoor, Varun; Bauer, Dieter [Institut fuer Physik, Wismarsche Str. 43-45, Universitaet Rostock, Rostock-18051 (Germany)

2012-07-01

Hollow or multiply excited states are inaccessible in time dependent density functional theory (TDDFT) using adiabatic Kohn-Sham potentials. We determine the exact Kohn Sham (KS) potential for doubly excited states in an exactly solvable model Helium atom. The exact single-particle density corresponds to the energetically lowest quasi-stationary state in the exact KS potential. We describe how this exact potential controls the decay by a barrier whose origin is traced back to phase of the exact KS orbital. The potential controls the barrier height and width in order for the density to tunnel out and decay with the same rate as the doubly excited state in the ab initio time-dependent Schroedinger calculation. Instead, adiabatic KS potentials only show direct photoionization but no autoionization. A frequency-dependent linear response kernel would be necessary in order to capture the decay of autoionizing states.

Non-LTE profiles of the Al I autoionization lines. [for solar model atmospheres

Science.gov (United States)

Finn, G. D.; Jefferies, J. T.

1974-01-01

A non-LTE formulation is given for the transfer of radiation in the autoionizing lines of neutral aluminum at 1932 and 1936 A through both the Bilderberg and Harvard-Smithsonian model atmospheres. Numerical solutions for the common source function of these lines and their theoretical line profiles are calculated and compared with the corresponding LTE profiles. The results show that the non-LTE profiles provide a better match with the observations. They also indicate that the continuous opacity of the standard solar models should be increased in this wavelength region if the center-limb variations of observed and theoretical profiles of these lines are to be in reasonable agreement.

Autoionization spectra of He excited by fast (MeV) H/sup +/, He/sup +/, and Li/sup n//sup +/ (N = 1,2,3) ions

Energy Technology Data Exchange (ETDEWEB)

Schneider, D.; Arcuni, P.; Bruch, P.; Stoeffler, W.

1983-01-01

Autoionization spectra of He following excitation by 1 to 3 MeV H/sup +/, He/sup +/, and Li/sup n//sup +/ (n = 1,2,3) have been measured as a function of observation angle. The (2p/sup 2/)/sup 1/D and (2s2p)/sup 1/P resonances have been examined and a strong dependence on projectile velocities, charge state and observation angle was found. The measurements were performed in a crossed-beam scattering chamber. The target-gas pressure was in the order of 10/sup -4/ Torr. The secondary electrons have been energy analyzed by a 45/sup 0/ parallel-plate analyzer. Results are presented and discussed. (WHK)

On the violation of the exponential decay law in atomic physics: ab initio calculation of the time-dependence of the He-1s2p24P non-stationary state

International Nuclear Information System (INIS)

Nicolaides, C.A.; Mercouris, T.

1996-01-01

The detailed time dependence of the decay of a three-electron autoionizing state close to threshold has been obtained ab initio by solving the time-dependent Schrodinger equation (TDSE). The theory allows the definition and computation of energy-dependent matrix elements in terms of the appropriate N-electron wavefunctions, representing the localized initial state, Ψ O , the stationary scattering states of the continuous spectrum, U( e psilon ) , and the localized excited states, Ψ n , of the effective Hamiltonian QHQ, where Q ''ident to'' |Ψ O > O |. The time-dependent wavefunction is expanded over these states and the resulting coupled equations with time-dependent coefficients (in the thousands) are solved to all orders by a Taylor series expansion technique. The robustness of the method was verified by using a model interaction in analytic form and comparing the results from two different methods for integrating the TDSE (appendix B). For the physically relevant application, the chosen state was the He - 1s2p 24 P shape resonance, about which very accurate theoretical and experimental relevant information exists. Calculations using accurate wavefunctions and an energy grid of 20.000 points in the range 0.0-21.77 eV show that the effective interaction depends on energy in a state-specific manner, thereby leading to state-specific characteristics of non-exponential decay over about 6 x 10 4 au of time, from which a width of Γ = 5.2 meV and a lifetime of 1.26 x 10 -13 s is deduced. The results suggest that either in this state or in other autoionizing states close to threshold, NED may have sufficient presence to make the violation of the law of exponential decay observable. (Author)

Focusing effects by one and two Coulomb centers in the autoionization of He

Energy Technology Data Exchange (ETDEWEB)

MartInez, S; Otranto, S [CONICET and Dto. de Fisica, Universidad Nacional del Sur, 8000 Bahia Blanca (Argentina); Suarez, S; Garibotti, C R, E-mail: smartine@criba.edu.a, E-mail: sotranto@uns.edu.a [CONICET and Centro Atomico Bariloche, 8400 S. C. de Bariloche (Argentina)

2009-11-01

In this work we consider the autoionization of He following double electron capture in He{sup 2+} + H{sub 2} collisions at an impact energy of 14 keV/amu. The post-collisional interaction with the two Coulomb centers is treated within the Barrachina-Macek model by employing the {Phi}{sub 2} correlated wave function introduced by Gasaneo et al to represent the continuum of the emitted electron in the field of two Coulomb centers. We compare the angular profiles in the electron spectrum with those obtained following double electron capture for the collision system He{sup 2+}+ He. Clear differences are observed in the spectra obtained for the atomic and molecular targets.

Photoionization dynamics of excited molecular states

International Nuclear Information System (INIS)

Dehmer, J.L.; O'Halloran, M.A.; Tomkins, F.S.; Dehmer, P.M.; Pratt, S.T.

1987-01-01

Resonance Enhanced Multiphoton Ionization (REMPI) utilizes tunable dye lasers to ionize an atom or molecule by first preparing an excited state by multiphoton absorption and then ionizing that state before it can decay. This process is highly selective with respect to both the initial and resonant intermediate states of the target, and it can be extremely sensitive. In addition, the products of the REMPI process can be detected as needed by analyzing the resulting electrons, ions, fluorescence, or by additional REMPI. This points to a number of opportunities for exploring excited state physics and chemistry at the quantum-state-specific level. Here we will first give a brief overview of the large variety of experimental approaches to excited state phenomena made possible by REMPI. Then we will examine in more detail, recent studies of the three photon resonant, four photon (3 + 1) ionization of H 2 via the C 'PI/sup u/ state. Strong non-Franck-Condon behavior in the photoelectron spectra of this nominally simple Rydberg state has led to the examination of a variety of dynamical mechanisms. Of these, the role of doubly excited autoionizing states now seems decisive. Progress on photoelectron studies of autoionizing states in H 2 , excited in a (2 + 1) REMPI process via the E, F 1 Σ/sub g/ + will also be briefly discussed. 26 refs., 7 figs

Studies of photoionization processes from ground-state and excited-state atoms and molecules

International Nuclear Information System (INIS)

Ederer, D.L.; Parr, A.C.; West, J.B.

1982-01-01

Recent triply-differential photoelectron spectroscopy experiments designed for the study of correlation effects in atoms and molecules are described. Final-state symmetry of the n=2 state of helium has been determined. The non-Franck-Condon behavior of vibrational branching ratios and large variations of the angular asymmetry parameter has been observed for shape resonances and autoionizing resonances in CO and other molecules. Recent observations of the photoionization of excited sodium atoms are also described

Comparison of explicit and effective models for calculating ionic populations in argon plasmas

International Nuclear Information System (INIS)

Abdallah, J. Jr.; Clark, R.E.H.

1994-01-01

Calculations have been performed to model the state populations of argon plasmas at electron densities at and above those required for the validity of coronal equilibrium. Both effective and explicit models have been used, and both are based on the same set of atomic cross sections. The effective model includes ground and singly excited states explicitly, while the effect of autoionizing states is accounted for by branching factors which describe their depopulation into the various non-autoionizing states. The explicit model considers both autoionizing and non-autoionizing states explicitly. The effective model requires a significantly reduced amount of computer time and memory. Good agreement between the two models can be obtained through moderate densities if the branching factors include electron density dependent terms which describe the collisional stabilization of each autoionizing state. The effective model breaks down as density is increased because the population of individual autoionizing states become significant. Results for both ionization balance and radiated power loss are presented. (Author)

Photoemission study of Kr 3d→np autoionization resonances

International Nuclear Information System (INIS)

Lindle, D.W.; Heimann, P.A.; Ferrett, T.A.; Piancastelli, M.N.; Shirley, D.A.

1987-01-01

Resonant photoelectron spectra of Kr have been taken in the photon-energy ranges of the 3d/sub 5/2/→5p,6p and 3d/sub 3/2/→5p excitations. The spectra, which closely resemble normal Kr + 3d/sup -1/ Auger spectra, illustrate the importance of ''spectator'' Auger-like decay for inner-shell resonances, in which the initially excited electron does not participate in the core-hole deexcitation process, except to respond to the change in the atomic potential. Possible assignments for some of the spectator decay channels are discussed based on photoemission intensity measurements at the different 3d resonances. These assignments suggest that shake-up (e.g., 5p→6p) of the ''spectator'' electron during the decay process is not quite as important as previously suspected. The resonance profiles of some of the more intense satellites have been determined over the 3d→np resonances. Very small resonance effects also were observed in the partial cross section for 4p subshell ionization, which produced asymmetric Fano-type profiles. The 4p angular distribution, in contrast, exhibits a pronounced effect in the resonance energy range. The 4p results demonstrate that nonspectator autoionization also is present

Summarizing Simulation Results using Causally-relevant States

Science.gov (United States)

Parikh, Nidhi; Marathe, Madhav; Swarup, Samarth

2016-01-01

As increasingly large-scale multiagent simulations are being implemented, new methods are becoming necessary to make sense of the results of these simulations. Even concisely summarizing the results of a given simulation run is a challenge. Here we pose this as the problem of simulation summarization: how to extract the causally-relevant descriptions of the trajectories of the agents in the simulation. We present a simple algorithm to compress agent trajectories through state space by identifying the state transitions which are relevant to determining the distribution of outcomes at the end of the simulation. We present a toy-example to illustrate the working of the algorithm, and then apply it to a complex simulation of a major disaster in an urban area. PMID:28042620

Dielectronic recombination rate coefficients to the excited states of CII from CIII

International Nuclear Information System (INIS)

Kato, Takako; Safronova, U.; Ohira, Mituhiko.

1996-02-01

Energy levels, radiative transition probabilities and autoionization rates for CII including 1s 2 2l2l'nl'' (n=2-6, l'≤(n-1)) states were calculated by using multi-configurational Hartree-Fock (Cowan code) method. Autoionizing levels above three thresholds: 1s 2 2s 2 ( 1 S), 1s 2 2s2p( 3 P), 1s 2 2s2p( 1 P) were considered. Branching ratios related to the first threshold and the intensity factor were calculated for satellite lines of CII ion. The dielectronic recombination rate coefficients to the excited states for n=2-6 are calculated with these atomic data. The rate coefficients are fitted to an analytical formula and the fit parameters are given. The values for higher excited states than n=6 are extrapolated and the total dielectronic recombination rate coefficients are derived. The effective recombination rate coefficient for different electron densities are also derived. (author)

The energy structure and decay channels of the 4p6-shell excited states in Sr

Science.gov (United States)

Kupliauskienė, A.; Kerevičius, G.; Borovik, V.; Shafranyosh, I.; Borovik, A.

2017-11-01

The ejected-electron spectra arising from the decay of the 4p{}5{{nln}}{\\prime }{l}{\\prime }{n}{\\prime\\prime }{l}{\\prime\\prime } autoionizing states in Sr atoms have been studied precisely at the incident-electron energies close to excitation and ionization thresholds of the 4{{{p}}}6 subshell. The excitation behaviors for 58 lines observed between 12 and 21 eV ejected-electron kinetic energy have been investigated. Also, the ab initio calculations of excitation energies, autoionization probabilities and electron-impact excitation cross sections of the states 4p{}5{{nln}}{\\prime }{l}{\\prime }{n}{\\prime\\prime }{l}{\\prime\\prime } (nl = 4d, 5s, 5p; {n}{\\prime }{l}{\\prime } = 4d, 5s, 5p; {n}{\\prime\\prime }{l}{\\prime\\prime } = 5s, 6s, 7s, 8s, 9s, 5p, 6p, 5d, 6d, 7d, 8d, 4f, 5g) have been performed by employing the large-scale configuration-interaction method in the basis of the solutions of Dirac-Fock-Slater equations. The obtained experimental and theoretical data have been used for the accurate identification of the 60 lines in ejected-electron spectra and the 68 lines observed earlier in photoabsorption spectra. The excitation and decay processes for 105 classified states in the 4p55s{}2{nl}, 4p54d{}2{nl} and 4p55s{{nln}}{\\prime }{l}{\\prime } configurations have been considered in detail. In particular, most of the states lying below the ionization threshold of the 4p6 subshell at 26.92 eV possess up to four decay channels with formation of Sr+ in 5s{}1/2, 4d{}3/{2,5/2} and 5p{}1/{2,3/2} states. Two-step autoionization and two-electron Auger transitions with formation of Sr2+ in the 4p6 {}1{{{S}}}0 ground state are the main decay paths for high-lying autoionizing states. The excitation threshold of the 4{{{p}}}6 subshell in Sr has been established at 20.98 ± 0.05 eV.

Atomic dynamics with photon-dressed core states

International Nuclear Information System (INIS)

Robicheaux, F.

1993-01-01

This paper describes the atomic dynamics when a Rydberg atom is in a laser field which is resonant with a dipole-allowed core transition. The main approximation is to completely ignore the (short-range, direct) interaction of the outer electron with the resonant laser which is the same approximation used with great success in calculating the spectrum due to isolated core excitations (ICE). The atom autoionizes when the core absorbs a photon, because the electron can then inelastically scatter from the excited core state, gaining enough energy to escape the atom. Despite neglecting the direct interaction between the outermost electron and the laser, the laser profoundly affects the autoionization dynamics. This effect is incorporated through a frame transformation between the dressed and undressed core states which only utilizes the field free atomic scattering parameters. A two-color experiment is proposed which might be able to measure nonperturbative effects arising from the dressed core states. The usual ICE transition rate is obtained through a perturbative expansion. Generic effects are examined through a model problem. A calculation of the Mg spectrum when the driving laser is tuned to the 3s 1/2- 3p 1/2 or the 3s 1/2- 3p 3/2 transition is presented

High-resolution measurements and multichannel quantum defect analysis of spectral line shapes of autoionizing Rydberg series

International Nuclear Information System (INIS)

Ueda, Kiyoshi

1997-01-01

Spectral line shapes for autoionizing Rydberg series are briefly reviewed within the framework of multichannel quantum defect theory (MQDT). Recent high-resolution measurements and MQDT analysis for the spectra line shapes are reviewed for the mp 5 ( 2 P 1/2 )ns ' and nd ' J=1 odd spectra of the Ar, Kr, and Xe atoms (m=3,4,5 for Ar, Kr, and Xe) and the 3p 5 ( 2 P 1/2 )nd ' J=2 and 3 odd spectra of Ar*3p 5 4p excited atoms. Some results are also discussed for the Ca 4p( 2 P 1/2,3/2 )ns and nd J=1 odd spectrum and the Ba 5d( 2 P 5/2 )nd J=1 odd spectrum

D. C. electric field behavior of high lying states in atomic uranium

International Nuclear Information System (INIS)

Paisner, J.A.; Carlson, L.R.; Worden, E.F.; Johnson, S.A.; May, C.A.; Solarz, R.W.

1976-01-01

The effects of D. C. electric fields on high lying Rydberg and valence states in atomic uranium have been studied. Results of measurements of Stark shifts, lifetime lengthening via l-mixing, critical fields for ionization, barrier tunneling, and the appearance of zero-field parity forbidden transitions are presented for atomic uranium along with the observation of field induced autoionization of valence states. 3 figs

Molecular (Feshbach) treatment of charge exchange Li3++He collisions. I. Energies and couplings

International Nuclear Information System (INIS)

Martin, F.; Riera, A.; Yanez, M.

1986-01-01

We point out a fundamental difference between the molecular treatment of charge exchange X/sup n/++H(1s) and X/sup n/++He(1s 2 ) collisions, which is that the latter process involves molecular states that are formally autoionizing. Then standard ab initio methods do not, in general, yield the relevant wave functions that are needed in the collision treatment, irrespective of whether quasimolecular autoionization be significant or not during the collision. We implement a particularly simple and useful form of the Feshbach formalism to calculate the energies of those two electron systems, and a method to evaluate the corresponding dynamical couplings is presented for the first time. Our implementation of this formalism together with the new computational techniques involved are presented in detail

Molecular (Feshbach) treatment of charge exchange Li/sup 3 +/+He collisions. I. Energies and couplings

Energy Technology Data Exchange (ETDEWEB)

Martin, F.; Riera, A.; Yanez, M.

1986-05-15

We point out a fundamental difference between the molecular treatment of charge exchange X/sup n/++H(1s) and X/sup n/++He(1s/sup 2/) collisions, which is that the latter process involves molecular states that are formally autoionizing. Then standard ab initio methods do not, in general, yield the relevant wave functions that are needed in the collision treatment, irrespective of whether quasimolecular autoionization be significant or not during the collision. We implement a particularly simple and useful form of the Feshbach formalism to calculate the energies of those two electron systems, and a method to evaluate the corresponding dynamical couplings is presented for the first time. Our implementation of this formalism together with the new computational techniques involved are presented in detail.

Superexcited states of molecules

International Nuclear Information System (INIS)

Nakamura, Hiroki; Takagi, Hidekazu.

1990-01-01

The report addresses the nature and major features of molecule's superexcited states, focusing on their involvement in dynamic processes. It also outlines the quantum defect theory which allows various processes involving these states to be treated in a unified way. The Rydberg state has close relation with an ionized state with a positive energy. The quantum defect theory interprets such relation. Specifically, the report first describes the quantum defect theory focusing on its basic principle. The multi-channel quantum defect theory is then outlined centering on how to describe a Rydberg-type superexcited state. Description of a dissociative double-electron excited state is also discussed. The quantum defect theory is based on the fact that the physics of the motion of a Rydberg electron vary with the region in the electron's coordinate space. Finally, various molecular processes that involve a superexcited state are addressed focusing on autoionization, photoionization, dissociative recombination and bonding ionization of diatomic molecules. (N.K.)

Auto transfer to Rydberg states and indirect stabilization following double capture

Energy Technology Data Exchange (ETDEWEB)

Roncin, P.; Gaboriaud, M.N.; Barat, M. (Paris-11 Univ., 91 - Orsay (France)); Bordenave-Montesquieu, A.; Moretto-Capelle, P.; Benhenni, M. (Toulouse-3 Univ., 31 (France)); Bachau, H.; Harel, C. (Bordeaux-1 Univ., 33 (France))

1993-11-28

Two-electron capture by slow multiply charged ions colliding on rare-gas target at keV energies is known to populate doubly excited states of the projectile with large cross sections. Though these states are dominantly autoionizing, important radiative decay following double capture have been reported, among which the direct observation of the fluorescence from Rydberg states. A mechanism based on post-collisional effects was proposed, in which Rydberg states are fed from the quasi-symmetrical doubly excited states initially populated. In this paper, a quantitative analysis of this effect is developed leading to a simple model which is applied to N[sup 7+] on He and Ar collisions. (author).

Auto transfer to Rydberg states and indirect stabilization following double capture

International Nuclear Information System (INIS)

Roncin, P.; Gaboriaud, M.N.; Barat, M.; Bordenave-Montesquieu, A.; Moretto-Capelle, P.; Benhenni, M.; Bachau, H.; Harel, C.

1993-01-01

Two-electron capture by slow multiply charged ions colliding on rare-gas target at keV energies is known to populate doubly excited states of the projectile with large cross sections. Though these states are dominantly autoionizing, important radiative decay following double capture have been reported, among which the direct observation of the fluorescence from Rydberg states. A mechanism based on post-collisional effects was proposed, in which Rydberg states are fed from the quasi-symmetrical doubly excited states initially populated. In this paper, a quantitative analysis of this effect is developed leading to a simple model which is applied to N 7+ on He and Ar collisions. (author)

Electron-impact excitation-autoionization in the cadmium isoelectronic sequence: A case of target term dependence in scattering theory

International Nuclear Information System (INIS)

Pindzola, M.S.; Griffin, D.C.; Bottcher, C.

1983-01-01

Excitation-autoionization contributions to electron-impact ionization are calculated for several atomic ions in the cadmium isoelectronic sequence. We calculate excitation cross sections in the distorted-wave approximation and compare them in one case to a calculation in the close-coupling approximation. We focus attention on the 4d 10 5s 2 →4d 9 5s 2 nf inner-shell excitations in In + , Sb 3+ , and Xe 6+ . Hartree-Fock atomic structure calculations for the 4d 9 5s 2 nf configurations are found to be highly term dependent. Thus our predictions for the total ionization cross section from the 5s subshell for these ions exhibit strong target term dependence. Our Xe 6+ results are found to be in excellent agreement with the recent experimental crossed-beam measurements of Gregory and Crandall

l dependence of dielectronic recombination from a continuum of finite bandwidth in a static electric field

International Nuclear Information System (INIS)

Shuman, E.S.; Evans, C.M.; Gallagher, T.F.

2004-01-01

It should be possible to separate experimentally the contributions to dielectronic recombination (DR) of energetically unresolved intermediate autoionizing Rydberg nl states using electric fields. This notion is based on two essential ideas. First, electric fields enhance the DR rate by Stark-mixing low-l states with high autoionization rates with high-l states with low autoionization rates. Second, the field at which an l state becomes Stark mixed is determined by its quantum defect, a known function of l. Consequently, the electric-field dependence of the DR rate should reflect the l dependence of the autoionization rates and thus the contributions of the zero-field nl states to the DR rate. This notion cannot be tested experimentally by examining true DR. However, it can be tested by studying DR from a continuum of finite bandwidth (CFB), for in this case the intermediate Rydberg nl states are restricted to a single value of l. Specifically, we have examined the electric-field dependence of DR from two CFB's, the Ba 6p 3/2 11d and 6p 3/2 8g states. In these two cases the intermediate autoionizing Rydberg states are restricted to the Ba 6p 1/2 nd and 6p 1/2 ng states (l=2 and 4), which have quantum defects of 0.25 and 0.02, respectively. For the same n they are Stark mixed at fields differing by an order of magnitude. We show experimentally that enhancement of the DR rate occurs at fields differing by a factor of 10 for nd and ng states of the same n, as expected, confirming that the field dependence of DR can be used to extract information about the contributions of energetically unresolved l states to the zero-field DR rate

Nonadiabatic electron wavepacket dynamics behind molecular autoionization

Science.gov (United States)

Matsuoka, Takahide; Takatsuka, Kazuo

2018-01-01

A theoretical method for real-time dynamics of nonadiabatic reorganization of electronic configurations in molecules is developed, with dual aim that the intramolecular electron dynamics can be probed by means of direct and/or indirect photoionizations and that the physical origins behind photoionization signals attained in the time domain can be identified in terms of the language of time-dependent quantum chemistry. In doing so, we first formulate and implement a new computational scheme for nonadiabatic electron dynamics associated with molecular ionization, which well fits in the general theory of nonadiabatic electron dynamics. In this method, the total nonadiabatic electron wavepackets are propagated in time directly with complex natural orbitals without referring to Hartree-Fock molecular orbitals, and the amount of electron flux from a molecular region leading to ionization is evaluated in terms of the relevant complex natural orbitals. In the second half of this paper, we apply the method to electron dynamics in the elementary processes consisting of the Auger decay to demonstrate the methodological significance. An illustrative example is taken from an Auger decay starting from the 2a1 orbital hole-state of H2O+. The roles of nuclear momentum (kinetic) couplings in electronic-state mixing during the decay process are analyzed in terms of complex natural orbitals, which are schematically represented in the conventional language of molecular symmetry of the Hartree-Fock orbitals.

Application of the stabilization method to the molecular states of LiHe3+: Energies and radial couplings

International Nuclear Information System (INIS)

Macias, A.; Mendizabal, R.; Pelayo, F.; Riera, A.; Yaez, M.

1986-01-01

We have used the stabilization method to perform calculations on autoionizing states of the LiHe 3+ system which are involved in Li 3+ +He collisions. The molecular energies and radial couplings are calculated with use of programs developed at our laboratory. For both short and large internuclear distances, the stabilization treatment is complemented by block-diagonalization techniques. Our calculations allow us to draw conclusions on the conditions under which these methods can be used to calculate energy positions and radial couplings for states that lie in an ionization continuum

Application of the stabilization method to the molecular states of LiHeT : Energies and radial couplings

Energy Technology Data Exchange (ETDEWEB)

Macias, A.; Mendizabal, R.; Pelayo, F.; Riera, A.; Yaez, M.

1986-01-01

We have used the stabilization method to perform calculations on autoionizing states of the LiHeT system which are involved in LiT +He collisions. The molecular energies and radial couplings are calculated with use of programs developed at our laboratory. For both short and large internuclear distances, the stabilization treatment is complemented by block-diagonalization techniques. Our calculations allow us to draw conclusions on the conditions under which these methods can be used to calculate energy positions and radial couplings for states that lie in an ionization continuum.

Two-electron excitation to Rydberg levels in fast I6+ on hydrogen collisions

International Nuclear Information System (INIS)

Liao, C.; Hagmann, S.; Zouros, T.J.M.; Montenegro, E.C.; Toth, G.; Richard, P.; Grabbe, S.; Bhalla, C.P.

1995-01-01

The emission of electrons in the forward direction in collisions of 0.3 MeV/u I 6+ with H 2 has been studied, and strong autoionization peaks are observed on the shoulder of the cusp peak. The energies of these autoionization lines in the projectile rest frame are determined by high-resolution electron spectroscopy. Using the electron projectile final charge state coincidence technique, we probe different collision mechanisms, which create continuum electrons that are slow in the projectile rest frame. We conclude that the observed autoionization lines are due to two electron excitation to projectile Rydberg levels. (orig.)

Workshop report of problems relating to multi-electron excited ions in plasma

International Nuclear Information System (INIS)

Fujimoto, Takashi; Suzuki, Hiroshi; Takayanagi, Toshinobu; Koike, Fumihiro; Nakamura, Koji.

1979-08-01

A workshop was held to discuss the problems relating to multiple electron-excited ions in plasma. The first part of this report deals with the problems of satellite lines. The satellite lines from laser plasma and vacuum sparks are discussed. Review papers on satellite lines and bielectronic recombination are also presented. The second part of this report deals with the problems of autoionization. Theory, comment on the compound state, observation of autoionization and resonance scattering, excitation cross-section, inner shell ionization, excitation through autoionization, and the bielectronic recombination of helium-like ions are discussed. (Kato, T.)

Electron impact excitation and ionization of laser-excited sodium atoms Na*(7d)

International Nuclear Information System (INIS)

Nienhaus, J.; Dorn, A.; Mehlhorn, W.; Zatsarinny, O.I.

1997-01-01

We have investigated the ejected-electron spectrum following impact excitation and ionization of laser-excited Na * (nl) atoms by 1.5 keV electrons. By means of two-laser excitation 3s → 3p 3/2 → 7d and subsequent cascading transitions about 8% (4%) of the target atoms were in excited states with n > 3 (7d). The experimental ejected-electron spectrum due to the decay of Auger and autoionization states of laser-excited atoms Na * (nl) with n = 4-7 has been fully interpreted by comprehensive calculations of the energies, cross sections and decay probabilities of the corresponding states. The various processes contributing to the ejected-electron spectrum are with decreasing magnitude: 2s ionization leading to 2s2p 6 nl Auger states, 2p → 3s excitation leading to 2p 5 3s( 1 P)nl autoionization states and 2s → 3l' excitation leading to 2s2p 6 3l'( 1 L)nl autoionization states. (Author)

Amplitudes and state parameters from ion- and atom-atom excitation processes

International Nuclear Information System (INIS)

Andersen, T.; Horsdal-Pedersen, E.

1984-01-01

This chapter examines single collisions between two atomic species, one of which is initially in a 1 S state (there is only one initial spin channel). The collisions are characterized by a definite scattering plane and a definite orientation. Topics considered include an angular correlation between scattered particles and autoionization electrons or polarized photons emitted from states excited in atomic collisions (photon emission, electron emission, selectivity excited target atoms), experimental methods for obtaining information on the alignment and orientation parameters of atoms or ions excited in specific collisions, results of experiments and numerical calculations (quasi-oneelectron systems, He + -He collisions, other collision systems), and future aspects and possible applications of the polarizedphoton, scattered-particle coincidence techniques to atomic spectroscopy

Jahn-Teller effect in Rydberg series: A multi-state vibronic coupling problem

International Nuclear Information System (INIS)

Staib, A.; Domcke, W.; Sobolewski, A.L.

1990-01-01

Two simple limiting cases of Jahn-Teller (JT) coupling in Rydberg states of polyatomic molecules are considered, namely (i) JT coupling in Rydberg orbitals as well as in the ionization continuum (nondegenerate ion core, degenerate Rydberg series) and (ii) JT coupling in the ion core (degenerate ion core, nondegenerate Rydberg series). For both models simple and efficient algorithms for the computation of spectra (dynamical JT effect) are developed. The orbital JT effect is shown to represent a novel type of multi-state vibronic coupling, giving rise to interesting spectroscopic phenomena, among them resonant inter-Rydberg perturbations and JT induced autoionization. Particular attention is paid to the demonstration of the characteristic spectroscopic signatures of the two types of JT coupling in Rydberg states. (orig.)

Electron streaking and dissociation in laser-assisted photoionization of molecular hydrogen

International Nuclear Information System (INIS)

Palacios, Alicia; González-Castrillo, Alberto; Martín, Fernando

2014-01-01

We report ab initio calculations on laser-assisted photoionization of the hydrogen molecule in the energy region where autoionization from doubly excited states is expected to occur. We use a UV-pump/IR-probe scheme in which an isolated attosecond UV pulse and a 750 nm IR pulse are combined. The IR pulse has a relatively low intensity (10 12 W cm −2 ), which allows us to perform a perturbative analysis of the calculated ionization probabilities differential in either electron or nuclear energy or both. We show that, for dissociative ionization, the electron energy distributions as a function of time delay exhibit unusual streaking patterns that are due to the presence of autoionizing states. These patterns significantly differ from the standard ones observed in direct single ionization of atoms and molecules. We also show that, by using such a pump–probe scheme, one can suppress autoionization from doubly excited states for time delays between 0 and 4 fs. (paper)

Studies of electron correlation in the photoionization process

International Nuclear Information System (INIS)

Rosenberg, R.A.

1979-03-01

Electron correlation is a result of the interaction of two or more electrons confined in a region of space, and may conveniently be treated under the formalism of configuration interaction (CI). Photoionization provides a rather direct experimental method for studying CI. The types of CI involved in the photoionization process can be divided into three categories: initial-state configuration interaction (ISCI), final-ionic-state configuration interaction (FISCI), and continuum-state configuration interaction (CSCI). The photoelecton spectroscopy of Ba, Sm, Eu, and Yb was studied using both HeI (22.22 eV) and NeI (16.85 eV) radiation. Satellite structure observed in these spectra using NeI (and for Yb, HeI also) radiation could be satisfactorily explained by ISCI alone. The HeI spectra of Sm, Eu, and, in particular, Ba showed dramatic changes in the satellite population which could only be explained by autoionization, a special form of CSCI. The detailed nature of this mechanism was explored in Ba with synchrotron radiation. It was found that the autoionizing level decays preferentially via an Auger-type mechanism. Further insight into autoionization was gained in the electron impact/ejected electron spectra of Ba (5p 6 6s 2 ) and Yb (5p 6 4f 14 6s 2 ). Autoionizing levels excited above the first (5p) -1 threshold decayed primarily in a two-step Auger process, leading to a relatively large number of doubly charged ions. For autoionizing states below the (5p) -1 limit, decay appears to go to ground and excited states of the singly charged ion. The first experimental determination of the lifetime of the XeII 5s5p 6 2 S/sub 1/2/ state yielded a value of 34.4(6) ns. Reasonable agreement with theory could only be reached by including both FISCI and relativistic effects in calculating the lifetime. 173 references, 43 figures, 10 tables

Veterinarian-Client Communication Skills: Current State, Relevance, and Opportunities for Improvement.

Science.gov (United States)

McDermott, Michael P; Tischler, Victoria A; Cobb, Malcolm A; Robbé, Iain J; Dean, Rachel S

2015-01-01

Communication is increasingly recognized as a core skill for veterinary practitioners, and in recent years, attention to communication competency and skills training has increased. To gain an up-to-date assessment of the current state of veterinary communication skills and training, we conducted a survey among veterinary practitioners in the United Kingdom and United States in 2012/2013. The questionnaire was used to assess the current state, relevance, and adequacy of veterinary communication skills among veterinary practitioners, to assess interest in further training, and to understand perceived challenges in communicating with clients. There was an overall response rate of 29.6% (1,774 of 6,000 recipients), with a higher response rate for UK-based practitioners (39.7%) than practitioners in the US (19.5%). Ninety-eight percent of respondents agreed that communication skills were as important as or more important than clinical knowledge. Forty-one percent of respondents had received formal veterinary communication skills training during veterinary school, and 47% had received training post-graduation. Thirty-five percent said their veterinary communication skills training during veterinary school prepared them well or very well for communicating with clients about the health of their pets, compared to 61% of those receiving post-graduate training. Forty percent said they would be interested in further veterinary communication skills training, with the preferred methods being simulated consultations and online training. While there has been increased emphasis on communication skills training during and after veterinary school, there is a need for more relevant and accessible training.

Dielectronic recombination rate coefficients to excited states of Be-like oxygen

Energy Technology Data Exchange (ETDEWEB)

Murakami, Izumi; Safronova, Ulyana I.; Kato, Takako

2001-05-01

We have calculated energy levels, radiative transition probabilities, and autoionization rates for Be-like oxygen (O{sup 4+}) including ls{sup 2}2lnl' (n=2 - 8, l {<=} n - 1) and 1s{sup 2}3l'nl (n=3 - 6, l {<=} n - l) states by multi-configurational Hartree-Fock method (Cowan code) and perturbation theory Z-expansion method (MZ code). The state selective dielectronic recombination rate coefficients to excited states of Be-like O ions are obtained. Configuration mixing plays an important role for the principal quantum number n distribution of the dielectronic recombination rate coefficients for 2snl (n {<=} 5) levels at low electron temperature. The orbital angular momentum quantum number l distribution of the rate coefficients shows a peak at l = 4. The total dielectronic recombination rate coefficient is derived as a function of electron temperature. (author)

Resonance-enhanced multiphoton ionization photoelectron spectroscopy of even-parity autoionizing Rydberg states of atomic sulphur

NARCIS (Netherlands)

Woutersen, S.; de Milan, J.B.; de Lange, C.A.; Buma, W.J.

1997-01-01

Several previously unobserved Rydberg states of the sulphur atom above the lowest ionization threshold are identified and assigned using (2 + 1) resonance-enhanced multiphoton-ionization photoelectron spectroscopy. All states were accessed by two-photon transitions from either the 3P ground or the

Local charge exchange of He{sup +} ions at Aluminum surfaces

Energy Technology Data Exchange (ETDEWEB)

Riccardi, P., E-mail: pierfrancesco.riccardi@fis.unical.it [Dipartimento di Fisica, Università della Calabria and INFN – Gruppo collegato di Cosenza, Via P. Bucci cubo 33C, Arcavacata di Rende, Cosenza (Italy); Sindona, A. [Dipartimento di Fisica, Università della Calabria and INFN – Gruppo collegato di Cosenza, Via P. Bucci cubo 33C, Arcavacata di Rende, Cosenza (Italy); Dukes, C.A. [Laboratory for Astrophysics and Surface Physics, Materials Science and Engineering University of Virginia, Charlottesville, VA 22904 (United States)

2017-04-04

We report on experiments designed to observe the correlation between the autoionization of doubly excited helium atoms and the Auger decay of 2p vacancies in Al. The autoionizing states are formed when incident He{sup +*} and He{sup ++} are neutralized by resonant electron capture at the surface. 2p excitation in Al occurs in dielectronic charge transfer during the close encounter of an excited helium ion and an Al atom. These results clarify the mechanism for Al-2p excitation in the case of singly charged ground state He{sup +}(1s) ion impact, where the dielectronic transition occurs after promotion of the 1s electron of incoming ions. - Highlights: • We observe the correlation between autoionization of doubly excited helium atoms and the Auger decay of 2p vacancies in Al. • 2p excitation in Al occurs in dielectronic charge transfer during the close encounter of an excited helium ion and an Al atom. • These results clarify the mechanism for Al-2p excitation in the case of singly charged ground state He{sup +}(1s) ion impact.

First Double Excitation Cross Sections of Helium Measured for 100-keV Proton Impact

International Nuclear Information System (INIS)

Moretto-Capelle, P.; Bordenave-Montesquieu, D.; Bordenave-Montesquieu, A.; Godunov, A.L.; Schipakov, V.A.

1997-01-01

Excitation cross sections of the (2s 2 ) 1 S, (2p 2 ) 1 D , and (2s2p) 1 P autoionizing states of helium, produced in collisions with 100-keV protons, have been measured for the first time. Using a high resolution electron spectroscopy together with a recently proposed parametrization of autoionizing resonances distorted by Coulomb interaction in the final state makes it possible to extract from electron spectra total cross sections as well as magnetic sublevel populations. These new experimental data are briefly compared with out theoretical calculations. copyright 1997 The American Physical Society

Effects of autoionizing states on two-photon double ionization of the H2 molecule

International Nuclear Information System (INIS)

Guan, Xiaoxu; Bartschat, Klaus; Koesterke, Lars; Schneider, Barry I

2014-01-01

We report angle-resolved and angle-integrated cross sections for two-photon double-ionization of H by a strong laser pulse. The effect of doubly excited states on the predicted cross sections is addressed.

Dynamic modification of the fragmentation of COq+ excited states generated with high-order harmonics

International Nuclear Information System (INIS)

Cao, W.; De, S.; Singh, K. P.; Chen, S.; Laurent, G.; Ray, D.; Ben-Itzhak, I.; Cocke, C. L.; Schoeffler, M. S.; Belkacem, A.; Osipov, T.; Rescigno, T.; Alnaser, A. S.; Bocharova, I. A.; Zherebtsov, S.; Kling, M. F.; Litvinyuk, I. V.

2010-01-01

The dynamic process of fragmentation of CO q+ excited states is investigated using a pump-probe approach. EUV radiation (32-48 eV) generated by high-order harmonics was used to ionize and excite CO molecules and a time-delayed infrared (IR) pulse (800 nm) was used to influence the evolution of the dissociating multichannel wave packet. Two groups of states, separable experimentally by their kinetic-energy release (KER), are populated by the EUV and lead to C + -O + fragmentation: direct double ionization of the neutral molecule and fragmentation of the cation leading to C + -O*, followed by autoionization of O*. The IR pulse was found to modify the KER of the latter group in a delay-dependent way which is explained with a model calculation.

Doubly excited circular Ba(6pj, 21c) states: e-e interaction effects in weak external fields

International Nuclear Information System (INIS)

Chen, L.; Cheret, M.; Poirier, M.; Roussel, F.; Bolzinger, T.; Spiess, G.

1992-01-01

The behaviour of doubly excited circular atoms in weak parallel electric and magnetic fields has been studied. The Hamiltonian, including the e-e interaction between the two excited electrons, Stark and Zeeman effects, is diagonalized in a truncated basis. The Rydberg electron, initially in a circular state, experiences a mixing of its orbital and magnetic quantum numbers, due to the presence of the external fields and to the excitation of the inner electron. This mixing depends on the spatial symmetry of the excited core and on the amplitude of the electric field. It can be detected by the field-ionization method which provides a new way for studying non-autoionizing doubly excited states. (orig.)

Observation of Cd 4d95s25p J=3 autoionizing levels in (e,2e) energy spectra

International Nuclear Information System (INIS)

Martin, N.L.S.; Bauman, R.P.; Wilson, M.

1998-01-01

Cadmium (e,2e) energy spectra have been measured for kinematics corresponding to a momentum transfer of 1 a.u. Two previously unknown cadmium autoinizing levels have been observed. Their energies are in excellent agreement with existing ab initio structure calculations of the 4d 9 5s 2 5p J=3 levels. One level is easily seen at an ejected-electron direction along the momentum-transfer axis, but is absent for a direction 39 degree away from this axis. The opposite is true for the other level; it is absent in the former, but present in the latter case. This behavior is in agreement with a calculation that takes into account that the J=3 levels can autoionize into both singlet and triplet 5sEf continua. The intensity of the new levels, relative to the well-known 4d 9 5s 2 5p J=1 levels, agrees well with a plane-wave Born approximation calculation for the J=3 levels. The third 4d 9 5s 2 5p J=3 level is calculated to lie within the broad 4d 9 5s 2 5p 1 P 1 level and cannot be seen in the present experiments. copyright 1998 The American Physical Society

Resonant inelastic scattering of quasifree electrons on ions

International Nuclear Information System (INIS)

Grabbe, S.

1994-01-01

Several studies of resonant-transfer excitation (RTE) have been reported in ion-atom collisions where the doubly excited autoionizing states are produced. Such a complex collision can be approximated as the scattering of quasifree electrons of the target from the projectile ion. Most of the investigations have been restricted to the deexcitation of the autoionizing states to the ground state by Auger electron emission. It has been shown that there is a strong interference between the elastic scattering amplitude and the resonance amplitude. The authors present here the cases where the corresponding interference is between the inelastic scattering and the resonance process. Recent work on 3 ell 3 ell ' resonances that decay predominantly to n=2 states will be presented for C 5+ -molecular hydrogen collisions

Strong enhancement of Penning ionization for asymmetric atom pairs in cold Rydberg gases: the Tom and Jerry effect

KAUST Repository

Efimov, D K

2016-05-18

We consider Penning ionization of Rydberg atom pairs as an Auger-type process induced by the dipole-dipole interaction and employ semiclassical formulae for dipole transitions to calculate the autoionization width as a function of the principal quantum numbers, n d, n i, of both atoms. While for symmetric atom pairs with the well-known increase of the autoionization width with increasing n 0 is obtained, the result for asymmetric pairs is counterintuitive - for a fixed n i of the ionizing atom of the pair, the autoionization width strongly increases with decreasing n d of the de-excited atom. For H Rydberg atoms this increase reaches two orders of magnitude at the maximum of the n d dependence, and the same type of counterintuitive behavior is exhibited also by Na, Rb and Cs atoms. This is a purely quantum-mechanical effect, which points towards existence of optimal (we call them \\'Tom\\' and \\'Jerry\\' for \\'big\\' and \\'small\\') pairs of Rydberg atoms with respect to autoionization efficiency. Building on the model of population redistribution in cold Rydberg gases proposed in [1], we demonstrate that population evolution following the initial laser excitation of Rydberg atoms in state n 0 would eventually lead to the formation of such Tom-Jerry pairs with which feature autoionization widths that are enhanced by several orders of magnitude compared to that of two atoms in the initial laser-excited state n 0. We also show that in the high-density regime of cold Rydberg gas experiments the ionization rate of Tom-Jerry pairs can be substantially larger than the blackbody radiation-induced photoionization rate. © 2016 IOP Publishing Ltd.

Production of the Q2 doubly excited states of the hydrogen molecule by electron impact in a single step

Science.gov (United States)

Santos, Leonardo O.; Rocha, Alexandre B.; Faria, Nelson Velho de Castro; Jalbert, Ginette

2017-03-01

We calculate the single step cross sections for excitation of Q 2 states of H2 and its subsequent dissociation. The cross section calculations were performed within the first Born approximation and the electronic wave functions were obtained via State-Averaged Multiconfigurational Self-Consistent Field followed by Configuration Interaction. We have assumed autoionization is the only important process competing with dissociation into neutral atoms. We have estimated its probability through a semi classical approach and compared with results of literature. Special attention was given to the Q 2 1Σg +(1) state which, as has been shown in a previous work, may dissociate into H(2 sσ) + H(2 sσ) fragments (some figures in this article are in colour only in the electronic version).

Many-body physics with alkaline-earth Rydberg lattices

Energy Technology Data Exchange (ETDEWEB)

Mukherjee, R; Nath, R; Pohl, T [Max Planck Institute for the Physics of Complex Systems, Noethnitzer Strasse 38, 01187 Dresden (Germany); Millen, J; Jones, M P A, E-mail: rick@pks.mpg.de [Department of Physics, Durham University, Durham DH1 3LE (United Kingdom)

2011-09-28

We explore the prospects for confining alkaline-earth Rydberg atoms in an optical lattice via optical dressing of the secondary core-valence electron. Focussing on the particular case of strontium, we identify experimentally accessible magic wavelengths for simultaneous trapping of ground and Rydberg states. A detailed analysis of relevant loss mechanisms shows that the overall lifetime of such a system is limited only by the spontaneous decay of the Rydberg state, and is not significantly affected by photoionization or autoionization. The van der Waals C{sub 6} coefficients for the Sr(5sns {sup 1}S{sub 0}) Rydberg series are calculated, and we find that the interactions are attractive. Finally we show that the combination of magic-wavelength lattices and attractive interactions could be exploited to generate many-body Greenberger-Horne-Zeilinger states.

Stark shifts and widths of a hydrogen atom in Debye plasmas

International Nuclear Information System (INIS)

Yu, A.C.H.; Ho, Y.K.

2005-01-01

A computational scheme has been developed and used to investigate the influence of the plasma environments on modified atomic autoionization for isolated atoms/ions by using the complex coordinate rotation method which is proved to be a very simple and powerful tool to analyze the position and the width of a resonance. The Debye screening potential is employed to describe the effects of the plasma environments. Stark shifts and widths on the ground state of hydrogen are reported for field strength up to F=0.12 a.u. Slater-type basis wave functions are used to describe the system and angular-momentum states up to L=11 are included when the external electric field is turned on. Converged results are obtained by using different maximum angular-momentum states. The modified autoionization for various Debye lengths ranging from infinite to a small value of 0.86 are reported. It has been observed that for a given temperature and under the influence of a given external electric field, the resonance energy and the autoionization width increase for increasing electron density in the plasma. A discussion on the physical implication of our results is made

Photoionization of Ar2 at high resolution

International Nuclear Information System (INIS)

Dehmer, P.M.

1982-01-01

The relative photoionization cross section of Ar 2 was determined at a resolution of 0.07 A in the wavelength region from 800 to 850 A using a new photoionization mass spectrometer that combines a high intensity helium continuum lamp with a free supersonic molecular beam source. In the region studied, the photoionization cross section is dominated by autoionization of molecular Rydberg states, and the structure is diffuse owing to the combined effects of autoionization and predissociation. The molecular photoionization spectrum is extremely complex and shows little resemblence either to the corresponding atomic spectrum (indicating that the spectrum of the dimer is not simply a perturbed atomic spectrum) or to the molecular absorption spectrum at longer wavelengths. The regular vibrational progressions seen at longer wavelengths are absent above the first ionization potential. Detailed spectroscopic analysis is possible for only a small fraction of the observed features; however, vibrational intervals of 50--100 cm -1 suggest that some of the Rydberg states have B 2 Pi/sub 3/2g/ ionic cores. A comparison of the absorption and photoionization spectra shows that, at wavelengths shorter than approx.835 A, many of the excited states decay via mechanisms other than autoionization

First Double Excitation Cross Sections of Helium Measured for 100-keV Proton Impact

Energy Technology Data Exchange (ETDEWEB)

Moretto-Capelle, P.; Bordenave-Montesquieu, D.; Bordenave-Montesquieu, A. [Laboratoire Collisions, Agregats, Reactivite, IRSAMC, UMR 5589, CNRS and Universite Paul Sabatier, 31062 Toulouse Cedex (France); Godunov, A.L.; Schipakov, V.A. [Troitsk Institute for Innovation and Fusion Research, Troitsk, Moscow region, 142092 (Russia)

1997-12-01

Excitation cross sections of the (2s{sup 2}){sup 1}S, (2p{sup 2}){sup 1}D , and (2s2p){sup 1}P autoionizing states of helium, produced in collisions with 100-keV protons, have been measured for the first time. Using a high resolution electron spectroscopy together with a recently proposed parametrization of autoionizing resonances distorted by Coulomb interaction in the final state makes it possible to extract from electron spectra {ital total cross sections} as well as {ital magnetic sublevel populations.} These new experimental data are briefly compared with out theoretical calculations. {copyright} {ital 1997} {ital The American Physical Society}

Accelerated Recombination in Cold Dense Plasmas with Metastable Ions due to Resonant Deexcitation

International Nuclear Information System (INIS)

Ralchenko, Yu.V.; Maron, M.

2001-01-01

In a recombining plasma the metastable states are known to accumulate population thereby slowing down the recombination process. We show that a proper account of the doubly-excited autoionizing states, populated through collisional 3-body recombination of metastable ions, results in a significant acceleration of recombination. 3-body recombination followed by collisional (de)excitations and autoionization effectively produces deexcitation via the following chain of elementary events: A fully time-dependent collisional-radiative (CR) modeling for stripped ions of carbon recombining in a cold dense plasma demonstrates an order of magnitude faster recombination of He-like ions. The CR model used in calculations is discussed in details

On the relevance of the final ionic state to the (e,2e) TDCS

International Nuclear Information System (INIS)

Stefani, G.

1990-01-01

The He II n=2 satellite in the He ionisation spectrum is investigated by measuring the angular dependence of the (e, 2e) triple differential cross section (TDCS) in asymmetric geometry for the first time, at moderate momentum transfer (0.8 a 0 -1 ) and low ejected electron energy (20 eV). The generalised oscillator strengths for the transitions to the n=1 and n=2 He II states are derived from the TDCS and their ratio is in fair agreement with a recent close coupling calculation. The experimental angular distribution of the n=2 TDCS shows peculiarities, typical of continuum final-state correlations, which appear to be much more relevant when the final ionic state is the excited one. (author)

Investigation of triply excited states of Li-like ions in fast ion-atom collisions by zero-degree Auger projectile electron spectroscopy

International Nuclear Information System (INIS)

Zouros, T.J.M.; Benis, E.P.; Zamkov, M.; Lin, C.D.; Lee, T.G.; Richard, P.; Gorczyca, T.W.; Morishita, T.

2005-01-01

The production of triply excited states of Li-like systems has recently been extended beyond the lithium atom using two different ion-atom collisional techniques: (a) Triple-electron capture into 2s2p 2 and 2p 3 states of F 6+ formed in fast collisions of bare F 9+ ions with Ar and Kr atoms and (b) 180 deg. resonant scattering of quasi-free electrons of H 2 from the 1s2s 3 S metastable state of He-like B, C, N, O and F ions via the 2s2p 2 2 D resonance. Autoionization energies, decay branching ratios and production cross sections for these states were measured using zero-degree Auger projectile electron spectroscopy and compared to theoretical calculations using hyperspherical close coupling (HSCC) and R-matrix methods

Equation of state experiments and theory relevant to planetary modelling

International Nuclear Information System (INIS)

Ross, M.; Graboske, H.C. Jr.; Nellis, W.J.

1981-01-01

In recent years there have been a number of static and shockwave experiments on the properties of planetary materials. The highest pressure measurements, and the ones most relevant to planetary modelling, have been obtained by shock compression. Of particular interest to the Jovian group are results for H 2 , H 2 O, CH 4 and NH 3 . Although the properties of metallic hydrogen have not been measured, they have been the subject of extensive calculations. In addition recent shock wave experiments on iron report to have detected melting under Earth core conditions. From this data theoretical models have been developed for computing the equations of state of materials used in planetary studies. A compelling feature that has followed from the use of improved material properties is a simplification in the planetary models. (author)

Amplitude modulation of atomic wave functions. Final report

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-11-01

The major theoretical advance has been to show that one can modulate Rydberg wave functions using either of two methods: (1) the amplitude modulation technique which depends on autoionization to deplete part of the wave function, or (2) a phase modulation method, which uses a change in the core potential to create a localized phase shift in the wave function. Essentially, these two methods can both be seen as using the core potential to change the Rydberg wave function, using the imaginary part of the potential to do amplitude modulation, or using the real part of the potential to do phase modulation. This work will be published as the authors acquire experimental results which show the differences between the two methods. One of the results of this theoretical study is that the initial proposal to study Barium 6snd states had a significant flaw. Neither the autoionization time, nor the quantum defect shifts are very large in these cases. This means that the modulation is relatively small. This shows itself primarily in the difficulty of seeing significant population redistribution into different 6snd states. The authors intend to correct this in the next funding cycle either: (a) by using the more quickly decaying Ba 6pnf states to modulate 6snd states, or (b) by using Sr 5 snd states, as outlined in this report. Their first, low power experiments are complete. These experiments have used two pulses to do a temporal version of the Ramsey separated oscillatory fields excitation. The two pulses are generated by passing the single pulse through a Michelson-Morley interferometer, which is computer controlled to sweep one arm through 2.5 {micro}m in steps of 10 nm. The second pulse`s excitation interferes with that of the first pulse, and so the total excitation has a sinusoidal variation (with a time period equal to the optical period) on top of a constant background. The amplitude of the total variation should decay at half of the rate decay rate of the autoionizing

Ionization yield and absorption spectra reveal superexcited Rydberg state relaxation processes in H{sub 2}O and D{sub 2}O

Energy Technology Data Exchange (ETDEWEB)

Fillion, J-H [LERMA, CNRS-UMR 8112, Observatoire de Paris-Meudon, 5 place J Janssen, F-92195, Meudon (France); Dulieu, F [LERMA, CNRS-UMR 8112, Observatoire de Paris-Meudon, 5 place J Janssen, F-92195, Meudon (France); Baouche, S [LERMA, CNRS-UMR 8112, Observatoire de Paris-Meudon, 5 place J Janssen, F-92195, Meudon (France); Lemaire, J-L [LERMA, CNRS-UMR 8112, Observatoire de Paris-Meudon, 5 place J Janssen, F-92195, Meudon (France); Jochims, H W [Institut fuer Physikalische und Theoretische Chemie der Freien Universitaet Berlin, Takustrasse 3, D-14195 Berlin 33 (Germany); Leach, S [LERMA, CNRS-UMR 8112, Observatoire de Paris-Meudon, 5 place J Janssen, F-92195, Meudon (France)

2003-07-14

The absorption cross section and the ionization quantum yield of H{sub 2}O have been measured using a synchrotron radiation source between 9 and 22 eV. Comparison between the two curves highlights competition between relaxation processes for Rydberg states converging to the first A-tilde {sup 2}A{sub 1} and to the second B-tilde {sup 2}B{sub 2} excited states of H{sub 2}O{sup +}. Comparison with D{sub 2}O absorption and ionization yields, derived from Katayama et al (1973 J. Chem. Phys. 59 4309), reveals specific energy-dependent deuteration effects on competitive predissociation and autoionization relaxation channels. Direct ionization was found to be only slightly affected by deuteration.

Fluorescence excitation involving multiple electron transition states of N{sub 2} and CO{sub 2}

Energy Technology Data Exchange (ETDEWEB)

Wu, C.Y.R.; Chen, F.Z.; Hung, T.; Judge, D.L. [Univ. of Southern California, Los Angeles, CA (United States)

1997-04-01

The electronic states and electronic structures of N{sub 2} and CO{sub 2} in the 8-50 eV energy region have been studied extensively both experimentally and theoretically. In the energy region higher than 25 eV there exists many electronic states including multiple electron transition (MET) states which are responsible for producing most of the dissociative photoionization products. The electronic states at energies higher than 50 eV have been mainly determined by Auger spectroscopy, double charge transfer, photofragment spectroscopy and ion-ion coincidence spectroscopy. The absorption and ionization spectra of these molecules at energies higher than 50 eV mainly show a monotonic decrease in cross section values and exhibit structureless features. The decay channels of MET and Rydberg (or superexcited) states include autoionization, ionization, dissociative ionization, predissociation, and dissociation while those of single ion and multiple ion states may involve predissociation. and dissociation processes. The study of fluorescence specifically probes electronically excited species resulting from the above-mentioned decay channels and provides information for understanding the competition among these channels.

Photoelectron studies of multiphoton processes in small molecules

International Nuclear Information System (INIS)

Pratt, S.T.; O'Halloran, M.A.; Tomkins, F.S.; Dehmer, J.L.; Dehmer, P.M.

1987-01-01

The three photon resonant, four photon ionization (3 + 1) spectra of H 2 via 1 π/sub u/, v' = 0 - 4 levels display strong non-Franck-Condon behavior that is not reproduced by calculations that assume direct excitation from the C 1 π/sub u/ Rydberg state into the ionization continuum. Recently, an explanation for this behavior has been proposed that involves an autoionizing, doubly-excited electronic state at the four photon energy. This explanation is examined in light of new (3 + 1) spectra obtained via the C 1 π/sub u/, v' = 5, 6 levels and new (3 + 1) spectra obtained via the C 1 π/sup u/, v' = 0 - 4 levels of D 2 . The new data support the explanation based on autoionization of a doubly excited state. 23 refs., 6 figs

Direct Imaging of Transient Fano Resonances in N_{2} Using Time-, Energy-, and Angular-Resolved Photoelectron Spectroscopy.

Science.gov (United States)

Eckstein, Martin; Yang, Chung-Hsin; Frassetto, Fabio; Poletto, Luca; Sansone, Giuseppe; Vrakking, Marc J J; Kornilov, Oleg

2016-04-22

Autoionizing Rydberg states of molecular N_{2} are studied using time-, energy-, and angular-resolved photoelectron spectroscopy. A femtosecond extreme ultraviolet pulse with a photon energy of 17.5 eV excites the resonance and a subsequent IR pulse ionizes the molecule before the autoionization takes place. The angular-resolved photoelectron spectra depend on pump-probe time delay and allow for the distinguishing of two electronic states contributing to the resonance. The lifetime of one of the contributions is determined to be 14±1  fs, while the lifetime of the other appears to be significantly shorter than the time resolution of the experiment. These observations suggest that the Rydberg states in this energy region are influenced by the effect of interference stabilization and merge into a complex resonance.

Reactions of Ground State Nitrogen Atoms N(4S) with Astrochemically-Relevant Molecules on Interstellar Dusts

Science.gov (United States)

Krim, Lahouari; Nourry, Sendres

2015-06-01

In the last few years, ambitious programs were launched to probe the interstellar medium always more accurately. One of the major challenges of these missions remains the detection of prebiotic compounds and the understanding of reaction pathways leading to their formation. These complex heterogeneous reactions mainly occur on icy dust grains, and their studies require the coupling of laboratory experiments mimicking the extreme conditions of extreme cold and dilute media. For that purpose, we have developed an original experimental approach that combine the study of heterogeneous reactions (by exposing neutral molecules adsorbed on ice to non-energetic radicals H, OH, N...) and a neon matrix isolation study at very low temperatures, which is of paramount importance to isolate and characterize highly reactive reaction intermediates. Such experimental approach has already provided answers to many questions raised about some astrochemically-relevant reactions occurring in the ground state on the surface of dust grain ices in dense molecular clouds. The aim of this new present work is to show the implication of ground state atomic nitrogen on hydrogen atom abstraction reactions from some astrochemically-relevant species, at very low temperatures (3K-20K), without providing any external energy. Under cryogenic temperatures and with high barrier heights, such reactions involving N(4S) nitrogen atoms should not occur spontaneously and require an initiating energy. However, the detection of some radicals species as byproducts, in our solid samples left in the dark for hours at 10K, proves that hydrogen abstraction reactions involving ground state N(4S) nitrogen atoms may occur in solid phase at cryogenic temperatures. Our results show the efficiency of radical species formation stemming from non-energetic N-atoms and astrochemically-relevant molecules. We will then discuss how such reactions, involving nitrogen atoms in their ground states, might be the first key step

Branching ratios in the radiative decay of helium doubly excited states

International Nuclear Information System (INIS)

Coreno, M.; Prince, K. C.; Richter, R.; De Simone, M.; Bucar, K.; Zitnik, M.

2005-01-01

The doubly excited singlet states of He below the N=2 threshold may decay by autoionization or fluorescence. In the fluorescence decay channel, most decay cascades consist of emission of three photons, of which the first is a VUV photon, the second is in or near the visible range, and the last is another VUV photon. We have studied the fluorescence channel decay dynamics of the (2,0 n ) (2,1 n ) and (2,-1 n ) 1 P, n=3-7, states by wavelength dispersed photon-induced fluorescence spectroscopy. We have detected the photons in the second step of the cascade and determined the branching ratios for the strongest lines in this step. From these data we are able to calculate the branching ratios of the first step in the cascade. The results are in good agreement with calculations of the main decay channels of the higher resonances, but about 20-30 % lower, and so we are able to describe quantitatively the whole fluorescence cascade of the above-mentioned doubly excited states

Theoretical studies on the interaction and dynamics in the colisional systems Hg+Li,Na,P and Ar*(4s3P2,0)+Hg,H

International Nuclear Information System (INIS)

Thiel, L.

2004-01-01

The central aim of this work is the detailed theoretical characterization of the autoionization process in collisions of metastable argon atoms with mercury and hydrogen atoms, Ar * (4s 3 P 2,0 ) + Hg and Ar * (4s 3 P 2,0 ) + H(1s). The autoionization process in the collision complexes Ar * (4s 3 P 2,0 ) + Hg und Ar * (4s 3 P 2,0 ) + H(1s) was investigated using the local complex potential approximation. Within this approach the entrance channel is described by a complex resonance potential whose imaginary part - the socalled autoionization width describes the ionization probability as a function of the internuclear distance. For both investigated systems, this work presents the first ab initio treatment of the autoionization process. In the collision complex Ar * + Hg, the asymptote of the entrance channel lies energetically above the asymptote of the exit channel Ar + Hg + . Both Penning ionization (PI) Ar * + Hg → Ar + Hg + + e - and associative ionization (AI) Ar * + Hg → ArHg + + e - are possible at thermal collision energies. The resonance potential and the autoionization width which describe the entrance channel were determined in MRCI calculations in which the resonance state was de- fined through Feshbach projection based on orbital occupancy. Taking the spin-orbit interaction in the Ar + core into account, the calculated complex potentials are able to reproduce the available experimental data such as the absolute ionization cross sections, the collision energy dependence of the relative cross sections for Penning and assoziative ionization and the electron energy spectra. (orig.)

Effects of collisions on level populations and dielectronic recombination rates of multiply charged ions

International Nuclear Information System (INIS)

Jacobs, V.L.; Davis, J.

1978-01-01

A generalization of previously reported statistical theories is developed for determining the excited-level populations and the ionization-recombination balance of multiply charged atomic ions in an optically thin high-temperature plasma. Account is taken of the most important collisional and radiative processes involving bound and autoionizing levels in three consecutive ionization stages. We obtain a set of rate equations for the population densities of the low-lying levels which contains effective excitation, ionization, and recombination rates describing indirect transitions through the more highly excited bound and autoionizing levels. The familiar corona-model equations for the ground-state populations are recovered by making the assumption that all excited states decay by only spontaneous radiative or autoionization processes. When collisional processes become efficient in depopulating the highly excited levels important in dielectronic recombination, the effective rate of recombination must be described by a collisional-dielectronic recombination coefficient. Results of calculations are presented for the collisional-dielectronic recombination rate coefficients for recombination of Fe +8 --Fe +13 ions. At an electron density of 10 16 cm -3 , dielectronic recombination is still the dominant recombination process. However, the collisional-dielectronic recombination rate coefficients are found to be reduced by about an order of magnitude from their corona-model values due to the effects of multiple-collisional excitations on the populations of the highly excited bound levels of the recombined ion. The dielectronic recombination rates into these highly excited levels are found to be enhanced by the effects of collisionally induced angular momentum redistribution on the populations of the autoionizing levels

Absolute partial photoionization cross sections of ethylene

Science.gov (United States)

Grimm, F. A.; Whitley, T. A.; Keller, P. R.; Taylor, J. W.

1991-07-01

Absolute partial photoionization cross sections for ionization out of the first four valence orbitals to the X 2B 3u, A 2B 3g, B 2A g and C 2B 2u states of the C 2H 4+ ion are presented as a function of photon energy over the energy range from 12 to 26 eV. The experimental results have been compared to previously published relative partial cross sections for the first two bands at 18, 21 and 24 eV. Comparison of the experimental data with continuum multiple scattering Xα calculations provides evidence for extensive autoionization to the X 2B 3u state and confirms the predicted shape resonances in ionization to the A 2B 3g and B 2A g states. Identification of possible transitions for the autoionizing resonances have been made using multiple scattering transition state calculations on Rydberg excited states.

Recent advances in the 5f-relevant electronic states and unconventional superconductivity of actinide compounds

International Nuclear Information System (INIS)

Haga, Yoshinori; Sakai, Hironori; Kambe, Shinsaku

2007-01-01

Recent advances in the understanding of the 5f-relevant electronic states and unconventional superconducting properties are reviewed in actinide compounds of UPd 2 Al 3 . UPt 3 , URu 2 Si 2 , UGe 2 , and PuRhGa 5 . These are based on the experimental results carried out on high-quality single crystal samples, including transuranium compounds, which were grown by using combined techniques. The paring state and the gap structure of these superconductors are discussed, especially for the corresponding Fermi surfaces which were clarified by the de Haas-van Alphen experiment and the energy band calculations. A detailed systematic study using the NQR/NMR spectroscopy reveals the d-wave superconductivity in PuRhGa 5 and the difference of magnetic excitations due to the difference of ground states in U-, Np-, and Pu-based AnTGa 5 (T: transition metal) compounds. (author)

Electron and ion angular distributions in resonant dissociative photoionization of H{sub 2} and D{sub 2} using linearly polarized light

Energy Technology Data Exchange (ETDEWEB)

Fernandez, Jorge; MartIn, Fernando [Departamento de Quimica C-9, Universidad Autonoma de Madrid, 28049 Madrid (Spain)], E-mail: fernando.martin@uam.es

2009-04-15

We have evaluated fully differential electron angular distributions in H{sub 2} and D{sub 2} dissociative photoionization by using linearly polarized light of 20, 27 and 33 eV. At 20 eV, the distributions exhibit simple p-wave patterns, which is the signature of direct ionization through the X{sup 2}{sigma}{sub g}{sup +}(1s{sigma}{sub g}) channel. At 27 eV, where the Q{sub 1} autoionizing states are populated, we observe a similar pattern, except when the molecule is oriented perpendicularly to the polarization direction and the energy of the ejected electron is small. In contrast, at 33 eV, autoionization from the Q{sub 1} and Q{sub 2} states leads to interferences between the X{sup 2}{sigma}{sub g}{sup +}(1s{sigma}{sub g}) and {sup 2}{sigma}{sub u}{sup +}(2p{sigma}{sub u}) ionization channels that result in a strong asymmetry of the electron angular distributions along the molecular axis. This asymmetry changes rapidly with the energy of the ejected electron. Electron angular distributions integrated over all possible molecular orientations or ion angular distributions integrated over electron emission angle show no reminiscence of the above phenomena, but the corresponding asymmetry parameters dramatically change with electron and ion energies in the region of autoionizing states.

XFEL resonant photo-pumping of dense plasmas and dynamic evolution of autoionizing core hole states

OpenAIRE

Rosmej, F. B.; Moinard, A.; Renner, O.; Galtier, E.; Lee, J. J.; Nagler, B.; Heimann, P. A.; Schlotter, W.; Turner, J. J.; Lee, R. W.; Makita, M.; Riley, D.; Seely, J.

2016-01-01

Similarly to the case of LIF (Laser-Induced Fluorescence), an equally revolutionary impact to science is expected from resonant X-ray photo-pumping. It will particularly contribute to a progress in high energy density science: pumped core hole states create X-ray transitions that can escape dense matter on a 10 fs-time scale without essential photoabsorption, thus providing a unique possibility to study matter under extreme conditions. In the first proof of principle experiment at the X-ray F...

Theoretical Studies of Electron Interaction with Molecular Ions and Mutual Neutralization - HeH and BeH

International Nuclear Information System (INIS)

Larson, Asa

2012-01-01

Reactions driven through electronic resonant states of HeH and BeH are discussed. These reactions are dissociative recombination (DR), resonant vibrational excitations (VE) and resonant dissociative excitations (DE). Another process is mutual neutralization (MN). HeH: The electronic resonant states of HeH are calculated using the full Configuration Interaction (CI) method with a large basis set. To obtain the autoionization widths electron scattering calculations are carried out using the Complex-Kohn variational method. The target ion is then described with a multi- reference CI wave function. Non-adiabatic couplings between the resonant states are computed using a method developed by V. Sidis. Cross sections for VE and DE of HeH in different vibrational states are computed by solving a driven Schroedinger equation and including autoionization using a local model. The non-adiabatic couplings between the resonant states are neglected. The cross sections become large when the energy is high enough to capture into the resonant states. The computed cross section for DE with the ion in the ground vibrational state is in very good agreement with measurement. The MN reaction, He + + H - →He*+ H, will be studied using strictly diabatic states. Autoionization will be included using the local model and the cross section will be computed by numerically solving a Matrix-Riccati equation for the radial wave function. BeH: We have previously studied DR of BeH + including the capture into electronic resonant states. Electronic couplings between the neutral states were included using a quasidiabatization procedure. Using the multi-channel quantum defect theory, the non-adiabatic couplings to the Rydberg states are now also incorporated. The indirect process results in sharp oscillations in the cross section and it influences the low temperature thermal rate coefficient for the reaction. Resonant VE and DE of BeH + in different vibrational states are investigated. The cross

Effect of Mental State on the Rate of Identifying the Relevancy of Documents Retrieved in a Search

Directory of Open Access Journals (Sweden)

Faezeh Farhoudi

2009-07-01

Full Text Available The present study investigates the link between various users’ mental state while searching information systems with the outcome of the resulting documents retrieved. Various factors such as user knowledge, search skills, motivation and aims influence the decisions and evaluation of users regarding documents retrieved. MMPI instrument was used to identify users’ mental states. The sample was drawn from female senior students of librarianship, using systematic random sampling. The findings indicated that anxiety and depression have significant inverse relationship to the rate of relevancy identification of the documents retrieved by the users.

Studies of electron correlation in the photoionization process

Energy Technology Data Exchange (ETDEWEB)

Rosenberg, Richard Allen [Univ. of California, Berkeley, CA (United States)

1979-03-01

Electron correlation is a result of the interaction of two or more electrons confined in a region of space, and may conveniently be treated under the formalism of configuration interaction (CI). Photoionization provides a rather direct experimental method for studying configuration interaction. The types of CI involved in the photoionization process can be divided into three categories: initial state configuration interaction (ISCI), final ionic state configuration interaction (FISCI), and continuum state configuration interaction (CSCI). This thesis deals with experimental studies which reveal how the various types of CI may become manifested in photoionization. The experimental methods utilized in this work are photoelectron spectroscopy (PES), electron impact spectroscopy (EIS), and time-resolved fluorescence spectroscopy. The EIS was carried out following the discovery that the UV lamp on a Perkin-Elmer photoelectron spectrometer could be utilized as a source of low energy electrons. The time-resolved fluorescence work utilized both the tunability and the time structure of the radiation available at the Stanford Synchrotron Radiation Laboratory (SSRL). A commercial photoelectron spectrometer equipped with a conventional UV lamp (Hei, Nei) was employed for some of the PES studies, and a novel time-of-flight photoelectron spectrometer was developed for the PES work performed using synchrotron radiation. The PES of Ba, Sm, Eu, and Yb was studied using both Hei (22.22 eV) and Nei (16.85 eV) radiation. Satellite structure observed in these spectra using Nei (and for Yb, Hei also) radiation could be satisfactorily explained by ISCI alone. The Hei spectra of Sm, Eu, and, in particular, Ba showed dramatic changes in the satellite population which could only be explained by a new mechanism, autoionization, which is a special form of CSCI. The detailed nature of this mechanism was explored in Ba using synchrotron radiation. It was found that the autoionizing level decays

Study on the AMO data production and evaluation techniques

Energy Technology Data Exchange (ETDEWEB)

Rhee, Yong Joo; Yoo, B. D.; Choe, A. S.; Han, J. M.; Jung, E. C.; Rho, S. P.; Yi, J. H.; Jeong, D. Y.; Lee, K. S.; Park, H. M.; Kim, S. K.; Song, K. S.; Lee, J. M

1998-01-01

AMODS (Atomic, Molecular, and Optical Database System) which can be accessed with the URL http://amods.kaeri.re.kr consists of a computer system which is an Alpha workstation 600 with UNIX O/S and the APACHE 1.2 WWW server installed on an independently mounted file system of 4.3 GB. Currently the data in AMODS is mostly atom-related and consists of atomic spectral lines, atomic transition probabilities, atomic energy levels, atomic transition lines, and CODATA 86 as well as several reference data. Meanwhile spectroscopic parameter of Sm which is one of the rare earth elements, has been measured, resulting in production of 36 isotope shift data of the high-lying even parity states, followed by the measurement of autoionization states. New 31 autoionization states are found and energy levels of them are measured. The Fano`s q parameters are determined through the theoretical analysis of the experimental data. (author). 11 refs., 3 tabs., 15 figs

Study on the AMO data production and evaluation techniques

International Nuclear Information System (INIS)

Rhee, Yong Joo; Yoo, B. D.; Choe, A. S.; Han, J. M.; Jung, E. C.; Rho, S. P.; Yi, J. H.; Jeong, D. Y.; Lee, K. S.; Park, H. M.; Kim, S. K.; Song, K. S.; Lee, J. M.

1998-01-01

AMODS (Atomic, Molecular, and Optical Database System) which can be accessed with the URL http://amods.kaeri.re.kr consists of a computer system which is an Alpha workstation 600 with UNIX O/S and the APACHE 1.2 WWW server installed on an independently mounted file system of 4.3 GB. Currently the data in AMODS is mostly atom-related and consists of atomic spectral lines, atomic transition probabilities, atomic energy levels, atomic transition lines, and CODATA 86 as well as several reference data. Meanwhile spectroscopic parameter of Sm which is one of the rare earth elements, has been measured, resulting in production of 36 isotope shift data of the high-lying even parity states, followed by the measurement of autoionization states. New 31 autoionization states are found and energy levels of them are measured. The Fano's q parameters are determined through the theoretical analysis of the experimental data. (author). 11 refs., 3 tabs., 15 figs

Spectroscopy of electrons ejected after charge exchange between multicharged ions and atoms

International Nuclear Information System (INIS)

Bordenave-Montesquieu, A.; Benoit-Cattin, P.; Boujema, M.; Gleizes, A.

1988-01-01

This report concerns a study of two-electron capture into autoionizing states from helium and hydrogen targets. Possible capture mechanisms are discussed. Also multiple-capture processes involving more than two electrons are discussed. 41 refs.; 9 figs.; 1 table

Synchrotron-based valence shell photoionization of CH radical

Energy Technology Data Exchange (ETDEWEB)

Gans, B., E-mail: berenger.gans@u-psud.fr, E-mail: christian.alcaraz@u-psud.fr; Falvo, C. [Institut des Sciences Moléculaires d’Orsay (ISMO), CNRS, Univ. Paris-Sud, Université Paris-Saclay, F-91405 Orsay (France); Holzmeier, F.; Röder, A. [Institut of Physical and Theoretical Chemistry, University of Würzburg, Am Hubland, D-97074 Würzburg (Germany); Krüger, J.; Garcia, G. A. [Synchrotron SOLEIL, L’Orme des Merisiers, Saint Aubin BP 48, F-91192 Gif sur Yvette Cedex (France); Lopes, A.; Alcaraz, C., E-mail: berenger.gans@u-psud.fr, E-mail: christian.alcaraz@u-psud.fr [Laboratoire de Chimie Physique, UMR 8000 CNRS—Univ. Paris-Sud, Univ. Paris-Saclay, Bât. 350, Centre Universitaire Paris-Sud, F-91405 Orsay Cedex (France); Fittschen, C. [Université Lille, CNRS, UMR 8522–PC2A–Physicochimie des Processus de Combustion et de l’Atmosphère, F-59000 Lille (France); Loison, J.-C. [Institut des Sciences Moléculaires, UMR 5255 CNRS—Université de Bordeaux, Bât. A12, 351 cours de la Libération, F-33405 Talence Cedex (France)

2016-05-28

We report the first experimental observations of X{sup +} {sup 1}Σ{sup +}←X {sup 2}Π and a{sup +} {sup 3}Π←X {sup 2}Π single-photon ionization transitions of the CH radical performed on the DESIRS beamline at the SOLEIL synchrotron facility. The radical was produced by successive hydrogen-atom abstractions on methane by fluorine atoms in a continuous microwave discharge flow tube. Mass-selected ion yields and photoelectron spectra were recorded as a function of photon energy using a double imaging photoelectron/photoion coincidence spectrometer. The ion yield appears to be strongly affected by vibrational and electronic autoionizations, which allow the observation of high Rydberg states of the neutral species. The photoelectron spectra enable the first direct determinations of the adiabatic ionization potential and the energy of the first triplet state of the cation with respect to its singlet ground state. This work also brings valuable information on the complex electronic structure of the CH radical and its cation and adds new observations to complement our understanding of Rydberg states and autoionization processes.

Post-coma persons emerging from a minimally conscious state with multiple disabilities make technology-aided phone contacts with relevant partners

NARCIS (Netherlands)

Lancioni, G.E.; Singh, N.N.; O'Reilly, M.F.; Sigafoos, J.; Oliva, D.; Campodonico, F.; D'Amico, F.; Buonocunto, F.; Sacco, V.; Didden, H.C.M.

2013-01-01

Post-coma individuals emerging from a minimally conscious state with multiple disabilities may enjoy contact with relevant partners (e.g., family members and friends), but may not have easy access to them. These two single-case studies assessed whether those individuals could make contact with

Astrophysical relevance of γ transition energies

International Nuclear Information System (INIS)

Rauscher, Thomas

2008-01-01

The relevant γ energy range is explicitly identified where additional γ strength must be located to have an impact on astrophysically relevant reactions. It is shown that folding the energy dependences of the transmission coefficients and the level density leads to maximal contributions for γ energies of 2≤E γ ≤4 unless quantum selection rules allow isolated states to contribute. Under this condition, electric dipole transitions dominate. These findings allow us to more accurately judge the relevance of modifications of the γ strength for astrophysics

Inter-Series Interactions on the Atomic Photoionization Spectra Studied by the Phase-Shifted Multichannel-Quantum Defect Theory

Directory of Open Access Journals (Sweden)

Chun-Woo Lee

2017-05-01

Full Text Available Development in mathematical formulations of parameterizing the resonance structures using the phase-shifted multichannel quantum defect theory (MQDT and their use in analyzing the effect of inter-series interactions on the autoionizing Rydberg spectra is reviewed. Reformulation of the short-range scattering matrix into the form analogous to S = SBSR in scattering theory are the crucial step in this development. Formulation adopts different directions and goals depending on whether autoionizing series converge to the same limit (degenerate or to different limits (nondegenerate because of the different nature of the perturbation. For the nondegenerate case, finding the simplest form of profile index functions of the autoionizing spectra with the minimal number of parameters is the main goal and some results are reviewed. For the degenerate case where perturbation acts uniformly throughout the entire series, isolation of the overlapped autoionizing series into the unperturbed autoionizing series is the key objective in research and some results in that direction are reviewed.

Strong enhancement of Penning ionization for asymmetric atom pairs in cold Rydberg gases: the Tom and Jerry effect

KAUST Repository

Efimov, D K; Miculis, K; Bezuglov, N N; Ekers, Aigars

2016-01-01

with which feature autoionization widths that are enhanced by several orders of magnitude compared to that of two atoms in the initial laser-excited state n 0. We also show that in the high-density regime of cold Rydberg gas experiments the ionization rate

Multi-step laser spectroscopy in atomic uranium

International Nuclear Information System (INIS)

Solarz, R.W.; Paisner, J.A.; Carlson, L.R.; May, C.A.; Johnson, S.A.

1975-01-01

The use of multistep photoionization techniques to measure lifetimes, cross sections, and branching ratios in uranium is described. The measurement of autoionization behavior, the assignment of new levels, and the observation of Rydberg states are also described. Experimental data are presented for all parameters

NATOs Relevance to United States Enduring National Interests Time to Remove the Training Wheels but Continue to Hold the Handle Bars

Science.gov (United States)

2016-06-10

advice, and friendship will have a lasting and positive effect on not only my military career but also my professional & personal life after the Army...if NATO didn’t exist today, the United States would not seek to create it.”1 Magnus Petersson flrnher asserts that within the United States...this topic relevant to the current and emerging strategic environment.7 Magnus Petersson, The US-NATO Debate: From Libya to Ukraine. (New York

The British welfare state and mental health problems: the continuing relevance of the work of Claus Offe.

Science.gov (United States)

Pilgrim, David

2012-09-01

It is now over thirty years since Claus Offe theorised the crisis tendencies of the welfare state in late capitalism. As part of that work he explored ongoing and irresolvable forms of crisis management in parliamentary democracies: capitalism cannot live with the welfare state but also cannot live without it. This article examines the continued relevance of this analysis by Offe, by applying its basic assumptions to the response of the British welfare state to mental health problems, at the turn of the twenty first century. His general theoretical abstractions are tested against the empirical picture of mental health service priorities, evident since the 1980s, in sections dealing with: re-commodification tendencies; the ambiguity of wage labour in the mental health workforce; the emergence of new social movements; and the limits of legalism. © 2012 The Author. Sociology of Health & Illness © 2012 Foundation for the Sociology of Health & Illness/Blackwell Publishing Ltd.

Multiple capture investigated by coincident electron spectroscopy in X7++Ar, at 70 keV

International Nuclear Information System (INIS)

Moretto-Capelle, P.; Bordenave-Montesquieu, D.; Bordenave-Montesquieu, A.

1999-01-01

The multiple electron capture in N 7+ + Ar and F 7+ (1s 2 ) + Ar systems is investigated at 70 keV with a new electron-recoil ion charge coincidence experiment. The whole electron energy range has been studied. Up to six electrons are found to be captured into autoionizing states. The recoil ion charge distribution associated with the emission of electrons is similar for both systems and found to be in good agreement with the prediction of Niehaus's model roughly adapted to take into account autoionizing cascades. New findings for the coincident double and triple captures are briefly discussed. A capture of an inner L-shell electron of Ar into the K-shell of the projectile is also observed in N 7+ + Ar collisions. (orig.)

Theory and computation of triply excited resonances: Application to states of He-

International Nuclear Information System (INIS)

Nicolaides, C.A.; Piangos, N.A.; Komninos, Y.

1993-01-01

Autoionizing multiply excited states offer unusual challenges to the theory of electronic structure and spectra because of the presence of strong electron correlations, of their occasional weak binding, of their proximity to more than one threshold, and of their degeneracy with many continua. Here we discuss a theory that addresses these difficulties in conjunction with the computation of their wave functions and intrinsic properties. Emphasis is given on the justification of the possible presence of self-consistently obtained open-channel-like (OCL) correlating configurations in the square-integrable representation of such states and on their effect on the energy E and the width Γ. Application of the theory has allowed the prediction of two hitherto unknown He - triply excited resonances, the 2s2p 2 2 P (E=59.71 eV, above the He ground state, Γ=79 meV) and the 2p 3 2 Do (E=59.46 eV, Γ=282 meV) (1 a.u.=27.2116 eV). These resonances are above the singly excited states of He and are embedded in its doubly excited spectrum. The relatively broad 2p 3 2 Do state interacts strongly with the He 2s2p 3 Po εd continuum. The effect of this interaction has been studied in terms of the coupling with fixed core scattering states as well as with a self-consistently computed OCL bound configuration

Providing Decision-Relevant Information for a State Climate Change Action Plan

Science.gov (United States)

Wake, C.; Frades, M.; Hurtt, G. C.; Magnusson, M.; Gittell, R.; Skoglund, C.; Morin, J.

2008-12-01

Carbon Solutions New England (CSNE), a public-private partnership formed to promote collective action to achieve a low carbon society, has been working with the Governor appointed New Hampshire Climate Change Policy Task Force (NHCCTF) to support the development of a state Climate Change Action Plan. CSNE's role has been to quantify the potential carbon emissions reduction, implementation costs, and cost savings at three distinct time periods (2012, 2025, 2050) for a range of strategies identified by the Task Force. These strategies were developed for several sectors (transportation and land use, electricity generation and use, building energy use, and agriculture, forestry, and waste).New Hampshire's existing and projected economic and population growth are well above the regional average, creating additional challenges for the state to meet regional emission reduction targets. However, by pursuing an ambitious suite of renewable energy and energy efficiency strategies, New Hampshire may be able to continue growing while reducing emissions at a rate close to 3% per year up to 2025. This suite includes efficiency improvements in new and existing buildings, a renewable portfolio standard for electricity generation, avoiding forested land conversion, fuel economy gains in new vehicles, and a reduction in vehicle miles traveled. Most (over 80%) of these emission reduction strategies are projected to provide net economic savings in 2025.A collaborative and iterative process was developed among the key partners in the project. The foundation for the project's success included: a diverse analysis team with leadership that was committed to the project, an open source analysis approach, weekly meetings and frequent communication among the partners, interim reporting of analysis, and an established and trusting relationship among the partners, in part due to collaboration on previous projects.To develop decision-relevant information for the Task Force, CSNE addressed

Indirect double photoionization of water

Science.gov (United States)

Resccigno, T. N.; Sann, H.; Orel, A. E.; Dörner, R.

2011-05-01

The vertical double ionization thresholds of small molecules generally lie above the dissociation limits corresponding to formation of two singly charged fragments. This gives the possibility of populating singly charged molecular ions by photoionization in the Franck-Condon region at energies below the lowest dication state, but above the dissociation limit into two singly charged fragment ions. This process can produce a superexcited neutral fragment that autoionizes at large internuclear separation. We study this process in water, where absorption of a photon produces an inner-shell excited state of H2O+ that fragments to H++OH*. The angular distribution of secondary electrons produced by OH* when it autoionizes produces a characteristic asymmetric pattern that reveals the distance, and therefore the time, at which the decay takes place. LBNL, Berkeley, CA, J. W. Goethe Universität, Frankfurt, Germany. Work performed under auspices of US DOE and supported by OBES, Div. of Chemical Sciences.

Photoionization using the xchem approach: Total and partial cross sections of Ne and resonance parameters above the 2 s22 p5 threshold

Science.gov (United States)

Marante, Carlos; Klinker, Markus; Kjellsson, Tor; Lindroth, Eva; González-Vázquez, Jesús; Argenti, Luca; Martín, Fernando

2017-08-01

The XCHEM approach interfaces well established quantum chemistry packages with scattering numerical methods in order to describe single-ionization processes in atoms and molecules. This should allow one to describe electron correlation in the continuum at the same level of accuracy as quantum chemistry methods do for bound states. Here we have applied this method to study multichannel photoionization of Ne in the vicinity of the autoionizing states lying between the 2 s22 p5 and 2 s 2 p6 ionization thresholds. The calculated total photoionization cross sections are in very good agreement with the absolute measurement of Samson et al. [J. Electron Spectrosc. Relat. Phenom. 123, 265 (2002), 10.1016/S0368-2048(02)00026-9], and with independent benchmark calculations performed at the same level of theory. From these cross sections, we have extracted resonance positions, total autoionization widths, Fano profile parameters, and correlation parameters for the lowest three autoionizing states. The values of these parameters are in good agreement with those reported in earlier theoretical and experimental work. We have also evaluated β asymmetry parameter and partial photoionization cross sections and, from the latter, partial autoionization widths and Starace parameters for the same resonances, not yet available in the literature. Resonant features in the calculated β parameter are in good agreement with the experimental observations. We have found that the three lowest resonances preferentially decay into the 2 p-1ɛ d continuum rather than into the 2 p-1ɛ s one [Phys. Rev. A 89, 043415 (2014), 10.1103/PhysRevA.89.043415], in agreement with previous expectations, and that in the vicinity of the resonances the partial 2 p-1ɛ s cross section can be larger than the 2 p-1ɛ d one, in contrast with the accepted idea that the latter should amply dominate in the whole energy range. These results show the potential of the XCHEM approach to describe highly correlated process

Atomic and Molecular Complex Resonances from Real Eigenvalues Using Standard (Hermitian) Electronic Structure Calculations

Czech Academy of Sciences Publication Activity Database

Landau, A.; Haritan, I.; Kaprálová-Žďánská, Petra Ruth; Moiseyev, N.

2016-01-01

Roč. 120, č. 19 (2016), s. 3098-3108 ISSN 1089-5639 R&D Projects: GA MŠk(CZ) LG13029 Institutional support: RVO:68378271 Keywords : autoionizing states * coordinate calculation * scattering resonances Subject RIV: CF - Physical ; Theoretical Chemistry OBOR OECD: Physical chemistry Impact factor: 2.847, year: 2016

Evidence for correlated double-electron capture in slow O6+ + He collisions

International Nuclear Information System (INIS)

Phaneuf, R.A.; Meyer, F.W.; Havener, C.C.; Stolterfoht, N.; Swenson, J.K.; Shafroth, S.M.

1987-01-01

Double electron capture by few-electron multicharged ions during slow collisions with He may result in Auger-decaying product states of the projectile, provided the initial projectile charge exceeds +4. These autoionizing states can be characterized by either (nearly) equivalent electron configurations, in which the two captured electrons occupy essentially the same or adjacent shells, or by non-equivalent configurations, in which one of the electrons is in a Rydberg state. Using the method of zero-degree Auger spectroscopy, the authors have verified population of both types of autoionizing states by double electron capture during slow collisions of O 6+ with He: for these systems, both LMM Auger electrons, attributed to the (nearly) equivalent electron configuration (1s 2 ) 3iota3iota' or (1s 2 )3iota4iota', and L 1 L 23 M-Coster Kronig electrons, attributed to the non-equivalent electron configurations (1s 2 )2pniota, were observed. Comparison of the LMM Auger electron and Coster Kronig electron production cross sections suggests that the correlated double capture process is of comparable importance to the sequential single capture mechanism

Costs Systems: Relevance, Feasibility And Usefulness According To Public Officials In The State Of Paraná (Brazil

Directory of Open Access Journals (Sweden)

Luciane Maria Gonçalves Franco

2013-06-01

Full Text Available The aim in this study is to get to know the level of understanding and adoption of cost systems in cities in the State of Paraná. A descriptive study with a qualitative approach was undertaken. Data were collected through the application of a questionnaire in 67 cities in the State of Paraná. Descriptive analysis was used and Spearman’s correlation coefficient was applied to achieve the research objective. Among the study results, the following stand out: the incipient nature of knowledge about the relevance, feasibility and usefulness of a cost system; resulting from public officials’ limited knowledge, mainly about topics related to the budgetary and financial feasibility of adopting cost systems; an environment for the cost system, implemented costs systems and operating systems; although the answers obtained to proposals about cost information and control were significantly coherent.

Relevance Feedback in Content Based Image Retrieval: A Review

Directory of Open Access Journals (Sweden)

Manesh B. Kokare

2011-01-01

Full Text Available This paper provides an overview of the technical achievements in the research area of relevance feedback (RF in content-based image retrieval (CBIR. Relevance feedback is a powerful technique in CBIR systems, in order to improve the performance of CBIR effectively. It is an open research area to the researcher to reduce the semantic gap between low-level features and high level concepts. The paper covers the current state of art of the research in relevance feedback in CBIR, various relevance feedback techniques and issues in relevance feedback are discussed in detail.

Multiple capture investigated by coincident electron spectroscopy in X{sup 7+}+Ar, at 70 keV

Energy Technology Data Exchange (ETDEWEB)

Moretto-Capelle, P.; Bordenave-Montesquieu, D.; Bordenave-Montesquieu, A. [Universite Paul Sabatier, Toulouse (France). Lab. Collisions-Agregats-Reactivite

1999-11-01

The multiple electron capture in N{sup 7+} + Ar and F{sup 7+}(1s{sup 2}) + Ar systems is investigated at 70 keV with a new electron-recoil ion charge coincidence experiment. The whole electron energy range has been studied. Up to six electrons are found to be captured into autoionizing states. The recoil ion charge distribution associated with the emission of electrons is similar for both systems and found to be in good agreement with the prediction of Niehaus`s model roughly adapted to take into account autoionizing cascades. New findings for the coincident double and triple captures are briefly discussed. A capture of an inner L-shell electron of Ar into the K-shell of the projectile is also observed in N{sup 7+} + Ar collisions. (orig.) 10 refs.

Synchrotron light sources: The search for quantum chaos

International Nuclear Information System (INIS)

Schlachter, Fred

2001-01-01

A storage ring is a specialized synchrotron in which a stored beam of relativistic electrons produces radiation in the vuv and x-ray regions of the spectrum. High-brightness radiation is used at the ALS to study doubly excited autoionizing states of the helium atom in the search for quantum chaos

Efficient mass-selective three-photon ionization of zirconium atoms

Science.gov (United States)

Page, Ralph H.

1994-01-01

In an AVLIS process, .sup.91 Zr is selectively removed from natural zirconium by a three-step photoionization wherein Zr atoms are irradiated by a laser beam having a wavelength .lambda..sub.1, selectively raising .sup.91 Zr atoms to an odd-parity E.sub.1 energy level in the range of 16000-19000 cm.sup.-1, are irradiated by a laser beam having a wavelength .lambda..sub.2 to raise the atoms from an E.sub.l level to an even-parity E.sub.2 energy level in the range of 35000-37000 cm.sup.-1 and are irradiated by a laser beam having a wavelength .lambda..sub.3 to cause a resonant transition of atoms from an E.sub.2 level to an autoionizing level above 53506 cm.sup.-1. .lambda..sub.3 wavelengths of 5607, 6511 or 5756 .ANG. will excite a zirconium atom from an E.sub.2 energy state of 36344 cm.sup.-1 to an autoionizing level; a .lambda..sub.3 wavelength of 5666 .ANG. will cause an autoionizing transition from an E.sub.2 level of 36068 cm.sup.-1 ; and a .lambda. .sub.3 wavelength of 5662 .ANG. will cause an ionizing resonance of an atom at an E.sub.2 level of 35904 cm.sup.-1.

Design and construction of a Fourier transform soft x-ray interferometer

International Nuclear Information System (INIS)

Spring, John A.

2000-01-01

Helium, with its two electrons and one nucleus, is a three-body system. One of the models for investigating correlated electron motion in this system is autoionization, produced via double excitation of the electrons. Predictions about the autoionization spectrum of helium have differed from each other and from preliminary experimental data. However, previous experiments have not been able to distinguish among the theoretical predictions because their energy resolution is not high enough to resolve the narrow linewidths of quasi-forbidden peaks and the resonances that appear in the highest excited states. Consequently, a team of researchers at Lawrence Berkeley National Laboratory have embarked on a project for building a high-resolution Fourier-Transform Soft X-ray (or VUV) interferometer (FTSX) to provide definitive data to answer remaining questions about the autoionization spectrum of helium. The design and construction of this interferometer is described in detail below, including the use of a flexure stage to provide the large path length difference necessary for high resolution measurements, the manufacture of x-ray beamsplitters, a description of the software, and the solution to the problems of stick-slip, vibration, and alignment. Current progress of its development is also described, as well as future goals

THE CURRENT STATE OF KNOWLEDGE IN THE VALUE RELEVANCE RESEARCH FIELD

Directory of Open Access Journals (Sweden)

Carmen- Alexandra BALTARIU

2015-04-01

Full Text Available The purpose of this paper is to assess the scientific literature referring to the value relevance of reported accounting information over a twelve year period starting from 2002. The approach of the paper is a theoretical (conceptual one. In order to complete the purpose of the paper we selected as research method the longitudinal qualitative analysis. The qualitative analysis carried out presents a deductive character. Our conclusions regarding the general characteristics of the research field pertaining to the value relevance of reported accounting information are drawn based on the main results and scientific contributions identified in the research field of interest.

XFEL resonant photo-pumping of dense plasmas and dynamic evolution of autoionizing core hole states

Science.gov (United States)

Rosmej, F. B.; Moinard, A.; Renner, O.; Galtier, E.; Lee, J. J.; Nagler, B.; Heimann, P. A.; Schlotter, W.; Turner, J. J.; Lee, R. W.; Makita, M.; Riley, D.; Seely, J.

2016-03-01

Similarly to the case of LIF (Laser-Induced Fluorescence), an equally revolutionary impact to science is expected from resonant X-ray photo-pumping. It will particularly contribute to a progress in high energy density science: pumped core hole states create X-ray transitions that can escape dense matter on a 10 fs-time scale without essential photoabsorption, thus providing a unique possibility to study matter under extreme conditions. In the first proof of principle experiment at the X-ray Free Electron Laser LCLS at SCLAC [Seely, J., Rosmej, F.B., Shepherd, R., Riley, D., Lee, R.W. Proposal to Perform the 1st High Energy Density Plasma Spectroscopic Pump/Probe Experiment”, approved LCLS proposal L332 (2010)] we have successfully pumped inner-shell X-ray transitions in dense plasmas. The plasma was generated with a YAG laser irradiating solid Al and Mg targets attached to a rotating cylinder. In parallel to the optical laser beam, the XFEL was focused into the plasma plume at different delay times and pump energies. Pumped X-ray transitions have been observed with a spherically bent crystal spectrometer coupled to a Princeton CCD. By using this experimental configuration, we have simultaneously achieved extremely high spectral (λ/δλ ≈ 5000) and spatial resolution (δx≈70 μm) while maintaining high luminosity and a large spectral range covered (6.90 - 8.35 Å). By precisely measuring the variations in spectra emitted from plasma under action of XFEL radiation, we have successfully demonstrated transient X- ray pumping in a dense plasma.

Two-color photoionization and photoelectron studies by combining infrared and vacuum ultraviolet

International Nuclear Information System (INIS)

Ng, C.Y.

2005-01-01

Recent developments of two-color infrared (IR)-vacuum ultraviolet (VUV) and VUV-IR photoionization and photoelectron detection schemes for spectroscopic studies are described. By preparing molecules in selected rovibrational states by IR excitation prior to VUV-photoionization, state-selected and state-to-state photoionization cross sections can be obtained by IR-VUV-photoionization efficiency (IR-VUV-PIE) and IR-VUV-pulsed field ionization-photoelectron (IR-VUV-PFI-PE) measurements, respectively. Rotationally resolved autoionizing Rydberg states converging to excited ionic states, which cannot be observed by single-photon VUV-PIE measurements, can be examined by the IR-VUV-PIE scheme. By monitoring the photoion and the PFI-PE intensities at a fixed VUV energy as a function of IR frequency, the respective IR photoion and IR absorption spectra of the corresponding neutral molecule can be measured. Two-color VUV-IR photo-induced Rydberg ionization (PIRI) experiment, in which high-n Rydberg states are prepared by VUV-photoexcitation followed by IR-induced autoionization, has also been demonstrated. Since the IR-VUV-PIE, IR-VUV-PFI-PE, and VUV-IR-PIRI methods do not require the existence of a bound intermediate electronic state in the UV and are generally applicable to all molecules, the development of these two-color photoionization and photoelectron schemes is expected to significantly enhance the scope of VUV spectroscopy and chemistry

Level-resolved distorted-wave cross-sections of electron impact ionization of Ar{sup 5+}

Energy Technology Data Exchange (ETDEWEB)

Yumak, A; Yavuz, I; Altun, Z, E-mail: zikalt@superonline.co [Department of Physics, Marmara University, Istanbul, 34722 (Turkey)

2009-11-01

Electron impact ionization cross sections of Ar{sup 5+} were calculated using configuration-average (CADW) and level-resolved (LRDW) distorted-wave methods. Direct ionization cross-sections of 2s, 2p, 3s and 3p subshells were calculated within a CADW approximation. The contributions from the excitation autoionization channels were evaluated assuming single excitations from the 2s, 2p, and 3s subshells and in both CADW and LRDW methods. The radiative stabilization of the excitation autoionization channels were found to reduce the excitation autoionization by a small amount.

NATO’s Relevance to United States Enduring National Interests Time to Remove the Training Wheels but Continue to Hold the Handle Bars

Science.gov (United States)

2016-06-10

advice, and friendship will have a lasting and positive effect on not only my military career but also my professional & personal life after the Army...if NATO didn’t exist today, the United States would not seek to create it.”1 Magnus Petersson flrnher asserts that within the United States...this topic relevant to the current and emerging strategic environment.7 Magnus Petersson, The US-NATO Debate: From Libya to Ukraine. (New York

From Heavy-Ion Collisions to Compact Stars: Equation of State and Relevance of the System Size

Directory of Open Access Journals (Sweden)

Sylvain Mogliacci

2018-01-01

Full Text Available In this article, we start by presenting state-of-the-art methods allowing us to compute moments related to the globally conserved baryon number, by means of first principle resummed perturbative frameworks. We focus on such quantities for they convey important properties of the finite temperature and density equation of state, being particularly sensitive to changes in the degrees of freedom across the quark-hadron phase transition. We thus present various number susceptibilities along with the corresponding results as obtained by lattice quantum chromodynamics collaborations, and comment on their comparison. Next, omitting the importance of coupling corrections and considering a zero-density toy model for the sake of argument, we focus on corrections due to the small size of heavy-ion collision systems, by means of spatial compactifications. Briefly motivating the relevance of finite size effects in heavy-ion physics, in opposition to the compact star physics, we present a few preliminary thermodynamic results together with the speed of sound for certain finite size relativistic quantum systems at very high temperature.

Why relevance theory is relevant for lexicography

DEFF Research Database (Denmark)

Bothma, Theo; Tarp, Sven

2014-01-01

This article starts by providing a brief summary of relevance theory in information science in relation to the function theory of lexicography, explaining the different types of relevance, viz. objective system relevance and the subjective types of relevance, i.e. topical, cognitive, situational...... that is very important for lexicography as well as for information science, viz. functional relevance. Since all lexicographic work is ultimately aimed at satisfying users’ information needs, the article then discusses why the lexicographer should take note of all these types of relevance when planning a new...... dictionary project, identifying new tasks and responsibilities of the modern lexicographer. The article furthermore discusses how relevance theory impacts on teaching dictionary culture and reference skills. By integrating insights from lexicography and information science, the article contributes to new...

State-dependent cognition and its relevance to cultural evolution.

Science.gov (United States)

Nettle, Daniel

2018-02-05

Individuals cope with their worlds by using information. In humans in particular, an important potential source of information is cultural tradition. Evolutionary models have examined when it is advantageous to use cultural information, and psychological studies have examined the cognitive biases and priorities that may transform cultural traditions over time. However, these studies have not generally incorporated the idea that individuals vary in state. I argue that variation in state is likely to influence the relative payoffs of using cultural information versus gathering personal information; and also that people in different states will have different cognitive biases and priorities, leading them to transform cultural information in different ways. I explore hunger as one example of state variable likely to have consequences for cultural evolution. Variation in state has the potential to explain why cultural traditions and dynamics are so variable between individuals and populations. It offers evolutionarily-grounded links between the ecology in which individuals live, individual-level cognitive processes, and patterns of culture. However, incorporating heterogeneity of state also makes the modelling of cultural evolution more complex, particularly if the distribution of states is itself influenced by the distribution of cultural beliefs and practices. Copyright © 2018 Elsevier B.V. All rights reserved.

Probing microhydration effect on the electronic structure of the GFP chromophore anion: Photoelectron spectroscopy and theoretical investigations

Energy Technology Data Exchange (ETDEWEB)

Bhaskaran-Nair, Kiran; Shelton, William A. [Cain Department of Chemical Engineering, Louisiana State University, Baton Rouge, Louisiana 70803 (United States); Center for Computation and Technology, Louisiana State University, Baton Rouge, Louisiana 70803 (United States); Valiev, Marat; Kowalski, Karol, E-mail: karol.kowalski@pnnl.gov [William R. Wiley Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, K8-91, P.O. Box 999, Richland, Washington 99352 (United States); Deng, S. H. M.; Wang, Xue-Bin, E-mail: xuebin.wang@pnnl.gov [Physical Sciences Division, Pacific Northwest National Laboratory, K8-88, P.O. Box 999, Richland, Washington 99352 (United States)

2015-12-14

The photophysics of the Green Fluorescent Protein (GFP) chromophore is critically dependent on its local structure and on its environment. Despite extensive experimental and computational studies, there remain many open questions regarding the key fundamental variables that govern this process. One outstanding problem is the role of autoionization as a possible relaxation pathway of the excited state under different environmental conditions. This issue is considered in our work through combined experimental and theoretical studies of microsolvated clusters of the deprotonated p-hydroxybenzylidene-2,3-dimethylimidazolinone anion (HBDI{sup −}), an analog of the GFP chromophore. Through selective generation of microsolvated structures of predetermined size and subsequent analysis of experimental photoelectron spectra by high level ab initio methods, we are able to precisely identify the structure of the system, establish the accuracy of theoretical data, and provide reliable description of auto-ionization process as a function of hydrogen-bonding environment. Our study clearly illustrates the first few water molecules progressively stabilize the excited state of the chromophore anion against the autodetached neutral state, which should be an important trait for crystallographic water molecules in GFPs that has not been fully explored to date.

Strong forward-backward asymmetries in electron emission from overlapping resonance states in fast C3+ on He collisions

International Nuclear Information System (INIS)

Yamazaki, Y.; Miller, P.D.; Krause, H.F.; Pepmiller, P.L.; Datz, S.; Sellin, I.A.

1986-01-01

Autoionizing electrons from the configuration 1s 2 2pnl produced by transfer and excitation were measured for 2.5 to 5.0 MeV C 3+ + He-gas collision employing the method of zero-degree Auger spectroscopy. The elctron analyzer was operated with an energy resolution of 300 MeV (FWHM), which corresponds to the projectile rest frame energy resolution (approx.40 MeV)

Dielectronic recombination of P5+ and Cl7+ in configuration-average, LS-coupling, and intermediate-coupling approximations

International Nuclear Information System (INIS)

Badnell, N.R.; Pindzola, M.S.

1989-01-01

We have calculated dielectronic recombination cross sections and rate coefficients for the Ne-like ions P 5+ and Cl 7+ in configuration-average, LS-coupling, and intermediate-coupling approximations. Autoionization into excited states reduces the cross sections and rate coefficients by substantial amounts in all three methods. There is only rough agreement between the configuration-average cross-section results and the corresponding intermediate-coupling results. There is good agreement, however, between the LS-coupling cross-section results and the corresponding intermediate-coupling results. The LS-coupling and intermediate-coupling rate coefficients agree to better than 5%, while the configuration-average rate coefficients are about 30% higher than the other two coupling methods. External electric field effects, as calculated in the configuration-average approximation, are found to be relatively small for the cross sections and completely negligible for the rate coefficients. Finally, the general formula of Burgess was found to overestimate the rate coefficients by roughly a factor of 5, mainly due to the neglect of autoionization into excited states

National inventory of Global Change relevant research in Norway; Nasjonal kartlegging av global change-relevant forskning

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-05-01

The Norwegian Global Change Committee has made an inventory of global change research (GCR) projects funded by the Research Council of Norway (RCN) in 2001. In lack of a rigid definition, GCR was defined as research that can be considered relevant to the science agenda of the four major international global change programmes DIVERSITAS, IGBP, IHDP and WCRP. Relevance was judged based on the objectives stated for each of the international programmes and their core projects. It was not attempted to check whether the projects had any kind of link to the programmes they were considered relevant for. The grants provided by the RCN in 2001 to GCR as defined above amounts to about 77 mill. NOK. Based on a recent survey on climate change research it is reasonable to estimate that the RCN finances between 30 and 40 % of all GCR in Norway. Accordingly, the total value of Norwegian research relevant to the four international global change programmes in 2001 can be estimated to 192 - 254 mill. NOK.

Energy redistribution in the dissociation of low Rydberg states of HeH and 02

International Nuclear Information System (INIS)

Zande, W.J.A. van der.

1988-01-01

In this thesis the dissocation process is studied of the diatomic molecules, heliumhydride and molecular oxygen. In ch.'s 2-4 results on the spectroscopy and dissociative decay of the excited states of heliumhydride (HeH) are explained. The positions and dissociation pathways of the A 2 Σ + and B 2 Π states are determined and a theoretical description of the decay of these states are given. An isotope dependent dissociation behaviour of the C 2 /σ + Rydberg state is reported which explained with this theory. In ch.'s 5-7 observations are presented regarding the first Rydberg states of molecular oxygen. The spectroscopy of the (3sσ)d 1 Π g and C 3 Π g states is treated, and the stability and decay of these Rydberg states is discussed qualitatively. An experimental study is described of the (3sσ)d 1 Π g , v=4-8 states. By isotope studies and resolving rotational lines and the measurements of natural linewidths quantitative estimates have been acquired on coupling strengths, positions of repulsive valence states and perturbations reported in literature from REMPI experiments. The electronic coupling strengths between the C 3 Π g state and the 3 Π g valence state has been established. Observed spin-orbit interactions have been quantified and the dissociation of the multiplet states (C 3 Π g , ω=0-2 has been correlated with the multiplet states of the fragment O 3 P J=0-2 . The spectroscopy of the (3sσ3) Rydberg states which con- verge to and are formed in collisions with the O + 2 , a 4 Π μ ion state, is treated. The (3sσ) 5 /π μ state competition between auto-ionizations and (pre-)dissociation has been observed. 207 refs.; 36 figs.; 18 tabs

Neutrophil programming dynamics and its disease relevance.

Science.gov (United States)

Ran, Taojing; Geng, Shuo; Li, Liwu

2017-11-01

Neutrophils are traditionally considered as first responders to infection and provide antimicrobial host defense. However, recent advances indicate that neutrophils are also critically involved in the modulation of host immune environments by dynamically adopting distinct functional states. Functionally diverse neutrophil subsets are increasingly recognized as critical components mediating host pathophysiology. Despite its emerging significance, molecular mechanisms as well as functional relevance of dynamically programmed neutrophils remain to be better defined. The increasing complexity of neutrophil functions may require integrative studies that address programming dynamics of neutrophils and their pathophysiological relevance. This review aims to provide an update on the emerging topics of neutrophil programming dynamics as well as their functional relevance in diseases.

State of the States 2016: Arts Education State Policy Summary

Science.gov (United States)

Aragon, Stephanie

2016-01-01

The "State of the States 2016" summarizes state policies for arts education identified in statute or administrative code for all 50 states and the District of Columbia. Information is based on a comprehensive search of state education statute and codes on each state's relevant websites. Complete results from this review are available in…

Dissociative photoionization of IBr following I(4d) and Br(3d) inner-shell excitations in the range of 60 ∼ 133 eV: remarkable biased charge spread relevant to the core-hole states

International Nuclear Information System (INIS)

Boo, Bong Hyun; Koyano, Inosuke

2002-01-01

Dissociative photoionization of an interhalogen molecule, iodine monobromide (IBr), spanning the I(4d) and the Br(3d) inner-shell excitation/ionization regions has been studied by using time-of-flight (TOF) mass spectrometry coupled to synchrotron radiation in the range of 60 ∼ 133 eV. The total and the individual photoion yields have been recorded as functions of the photon energy. Here, a giant shape resonance has been observed owing to the I(4d 10 ) →I(4d 9 εf) transition, the transition probability for which outweighs that for the Br(3d 10 ) →Br(3d 9 εf) excitation. In addition to the huge resonance, discrete resonances owing to the Br(3d) -1 IBr(4pσ + ) and the Br(3d -1 )Br(5p) transitions, with very weak intensities, are observed at 70.5 and 73.6 eV and have spin-orbit splittings of = 1.0 and = 0.9 eV, respectively. The dissociation processes of singly and doubly charged parent ions have also been evaluated from the variations of the individual ion and photoion-photoion coincidence (PIPICO) yields with the photon energy. Below the Br(3d) threshold, including the Br(3d) discrete excitation region, 60 + and I 2+ ions are exclusively formed with a trace number of Br + ions. Slightly above the Br(3d) threshold, more specifically at 77.5 eV, however, photoionization events leading to the formations of Br + and Br 2- prevail. At higher energies beyond the Br(3d) threshold, 78 + and I 2+ turn out to exceed again those for Br + and Br 2+ , respectively. Over the entire energy range examined, a remarkable biased charge spread in dissociative photoionization events is observed, presumably reflecting the fact that charge localized mostly in the excited atoms relevant to the specific inner-shell excitation, which can be accounted for mainly by a two-step decay process via a fast dissociation followed by autoionization upon vuv absorption

Production of the Ne Auger electrons by Ne/sup +/ bombardment of Mg and Al surfaces

Energy Technology Data Exchange (ETDEWEB)

Ferrante, J; Pepper, S V [National Aeronautics and Space Administration, Cleveland, Ohio (USA). Lewis Research Center

1976-07-01

The authors have bombarded Mg and Al surfaces with Ne/sup +/ ions and in this letter present evidence for the production of an inner shell vacancy in the Ne by the asymmetric Ne-Mg and Ne-Al collision. In addition, autoionization states of neutral Ne have been observed. These states are to be distinguished from the more usual case in Auger electron spectroscopy of de-excitation of an ion with a core vacancy.

Laser techniques for extreme-ultraviolet spectroscopy

International Nuclear Information System (INIS)

Harris, S.E.; Young, J.F.; Caro, R.G.; Falcone, R.W.; Holmgren, D.E.; Walker, D.J.; Wang, J.C.; Rothenberg, J.E.; Willison, J.R.

1983-06-01

In this paper we describe several techniques for using lasers to study core-excited energy levels in the spectral region between 10 eV and 100 eV. We are particularly interested in levels that are metastable against autoionization and, in some cases, against both autoionization and radiation

Condensation induced water hammer (CIWH). Relevance in the nuclear industry and state of science and technology

Energy Technology Data Exchange (ETDEWEB)

Swidersky, Harald [TUeV Sued Industrie Service GmbH, Muenchen (Germany)

2013-03-15

Condensation-induced water hammers (CIWH) are consequences of rapid condensation of steam in partially filled pipes. They present a particular hazard potential, as they seem to occur spontaneously and out of stagnation. The entire process still eludes a secured analytical or numerical predictability and determination of the fluid dynamic loads. The simulation of these processes is one of the most difficult tasks of thermal hydraulic transient analyses. Condensation induced water hammers in plants - mostly power plants - can lead to significant costs if they result in long downtimes, detailed analyses and upgrades. In this contribution, the phenomenon CIWH is explained and the relevance for nuclear engineering will be discussed. An outlook on the actual requirements of regulatory guidelines and the state of science and technology will be given. (orig.)

Condensation induced water hammer (CIWH). Relevance in the nuclear industry and state of science and technology

International Nuclear Information System (INIS)

Swidersky, Harald

2013-01-01

Condensation-induced water hammers (CIWH) are consequences of rapid condensation of steam in partially filled pipes. They present a particular hazard potential, as they seem to occur spontaneously and out of stagnation. The entire process still eludes a secured analytical or numerical predictability and determination of the fluid dynamic loads. The simulation of these processes is one of the most difficult tasks of thermal hydraulic transient analyses. Condensation induced water hammers in plants - mostly power plants - can lead to significant costs if they result in long downtimes, detailed analyses and upgrades. In this contribution, the phenomenon CIWH is explained and the relevance for nuclear engineering will be discussed. An outlook on the actual requirements of regulatory guidelines and the state of science and technology will be given. (orig.)

Atomic excitation and recombination in external fields

International Nuclear Information System (INIS)

Nayfeh, M.H.; Clark, C.W.

1985-01-01

This volume offers a timely look at Rydberg states of atoms in external fields and dielectronic recombination. Each topic provides authoritative coverage, presents a fresh account of a flourishing field of current atomic physics and introduces new opportunities for discovery and development. Topics considered include electron-atom scattering in external fields; observations of regular and irregular motion as exemplified by the quadratic zeeman effect and other systems; Rydberg atoms in external fields and the Coulomb geometry; crossed-field effects in the absorption spectrum of lithium in a magnetic field; precise studies of static electric field ionization; widths and shapes of stark resonances in sodium above the saddle point; studies of electric field effects and barium autoionizing resonances; autoionization and dielectronic recombination in plasma electric microfields; dielectronic recombination measurements on multicharged ions; merged beam studies of dielectronic recombination; Rydberg atoms and dielectronic recombination in astrophysics; and observations on dielectronic recombination

Relevant Scatterers Characterization in SAR Images

Science.gov (United States)

Chaabouni, Houda; Datcu, Mihai

2006-11-01

Recognizing scenes in a single look meter resolution Synthetic Aperture Radar (SAR) images, requires the capability to identify relevant signal signatures in condition of variable image acquisition geometry, arbitrary objects poses and configurations. Among the methods to detect relevant scatterers in SAR images, we can mention the internal coherence. The SAR spectrum splitted in azimuth generates a series of images which preserve high coherence only for particular object scattering. The detection of relevant scatterers can be done by correlation study or Independent Component Analysis (ICA) methods. The present article deals with the state of the art for SAR internal correlation analysis and proposes further extensions using elements of inference based on information theory applied to complex valued signals. The set of azimuth looks images is analyzed using mutual information measures and an equivalent channel capacity is derived. The localization of the "target" requires analysis in a small image window, thus resulting in imprecise estimation of the second order statistics of the signal. For a better precision, a Hausdorff measure is introduced. The method is applied to detect and characterize relevant objects in urban areas.

Electron-impact ionization of Mo+

International Nuclear Information System (INIS)

Ludlow, J.A.; Loch, S.D.; Pindzola, M.S.

2005-01-01

The electron-impact direct ionization cross section for Mo + is calculated using both nonperturbative close-coupling and perturbative distorted-wave methods. When distorted-wave calculations for 4d 5 →4d 4 direct ionization are added to distorted-wave calculations for 4p→nl excitation-autoionization, the experimental measurements are found to be 60% lower than the theoretical predictions. Inclusion of nonperturbative three-body Coulomb effects, present in time-dependent close-coupling calculations, are found to reduce the distorted-wave 4d 5 →4d 4 direct ionization cross section by 25%. This is by far the largest reduction yet seen when comparing the two methods for direct subshell ionization of an atomic positive ion in the ground state. However, when the close-coupling calculations for 4d 5 →4d 4 direct ionization are added to distorted-wave calculations for 4p→nl excitation-autoionization, the experimental measurements are still 45% lower than the theoretical predictions. Although we further investigate correlation effects in the initial target state and term-dependent potential effects in the ejected electron state in an attempt to understand the small magnitude of the experimental measurements, the discrepancy between theory and experiment remains unexplained

Cross sections for the vibrational excitation of the H2 X 1Σ+g(v) levels generated by electron collisional excitation of the higher singlet states

International Nuclear Information System (INIS)

Hiskes, J.R.

1991-01-01

The excitation cross sections, σ(v,v double-prime), for an H 2 molecule initially in any one of the 15 vibrational levels, v belonging to the ground electronic state and excited to a final vibrational level, v double-prime are evaluated for direct excitations via all members of the excited electronic singlet spectrum. Account is taken of predissociation, autoionization, and radiative decay of the excited electronic spectrum that leads to a final population distribution for the ground electronic state, X 1 Σ + g (v double-prime). For v=0, account is taken explicitly of transitions via the B, C, B', and D electronic states in evaluating the cross sections. The additional contribution of excitations via all Rydberg states lying above the D state enhances these cross sections by approximately 10%. For v>0, cross sections are evaluated taking explicit account of transitions through the B and C states; higher singlet excitations enhance these values by 25%. The choice of the reference total cross sections remains a subjective one, causing the values calculated here to have a possible uncertainty of +20% -30% . For excitations occurring within a hydrogen discharge, collisional excitation-ionization events among the intermediate singlet states will effectively quench the v, v double-prime excitation process for discharge densities in excess of the range 10 15 --10 16 electrons/cm -3

Charge state distributions from highly charged ions channeled at a metal surface

International Nuclear Information System (INIS)

Folkerts, L.; Meyer, F.W.; Schippers, S.

1994-01-01

The vast majority of the experimental work in the field of multicharged ion-surface interactions, to date, has focused on x-ray and particularly on electron emission. These experiments include measurements of the total electron yield, the emission statistics of the electrons, and, most of all, the electron energy distributions. So far, little attention has been paid to the fate of the multicharged projectile ions after the scattering. To our knowledge, the only measurement of the charge state distribution of the scattered ions is the pioneering experiment of de Zwart et al., who measured the total yield of scattered 1+, 2+, and 3+ ions as a function of the primary charge state q (q = 1--11) for 20 key Ne, Ar, and Kr ions after reflection from a polycrystalline tungsten target. Their main finding is the sudden onset of scattered 3+ ions when inner-shell vacancies are present in the primary particles. This suggests that a certain fraction of the inner-shell vacancies survives the entire collision event, and decays via autoionization on the outgoing path. Since the projectiles scattered in the neutral charge state could not be detected in the experiment of de Zwart et al., they were not able to provide absolute charge state fractions. In our present experiment, we focus on the scattered projectiles, measuring both the final charge state and the total scattering angle with a single 2D position sensitive detector (PSD). This method gives us the number of positive, as well as neutral and negative, scattered ions, thus allowing us to extract absolute charge state fractions. Using a well-prepared single Au(110) crystal and a grazing incidence geometry, we were able to observe surface channeling along the [001] channels

Electron capture and transfer-ionization processes in {sup 4}He{sup 2+}+Ar collision at 12.5 keV amu{sup -1}

Energy Technology Data Exchange (ETDEWEB)

Moretto-Capelle, P.; Bordenave-Montesquieu, D.; Bordenave-Montesquieu, A.; Benhenni, M. [Laboratoire Collisions, Agregats, Reactivite, IRSAMC, UMR 5589 CNRS and Universite Paul Sabatier, 31062 Toulouse Cedex (France)

1998-05-14

Electron emission in the {sup 4}He{sup 2+}+Ar collisional system has been investigated at 35 deg. and 12.5 keV amu{sup -1} collision velocity, in coincidence with the recoil target ion charges. Direct single ionization is found to be negligible with respect to single-electron capture. Contributions of transfer-ionization processes are stressed in the production of Ar{sup 2+} to Ar{sup 4+} ions; those of direct ionization, double excitation of the target and double capture into autoionization states of helium are instead found to be much less probable. Among the two-electron processes which explain the formation of Ar{sup 2+} ions, the double capture into autoionizing states of helium remains unimportant with respect to a pure transfer ionization process (one captured electron plus one ionized electron). The measured predominant production of Ar{sup 3+} ions illustrates the role played by three-electron processes, mainly a two-electron transfer accompanied by a single-target ionization. Finally, the formation of Ar{sup 4+} ions is connected with more complex transfer ionization processes. A qualitative analysis of these results is made within the quasimolecular approach. (author). Letter-to-the-editor.

Gamma radiation and temperature influence on the chemical effect produced by isomeric transition in the telluric acid

International Nuclear Information System (INIS)

Muriel G, M.

1976-01-01

When the gamma radiation due to the isomeric transition is internally converted an autoionization is produced. For atoms with a high atomic number this autoionization can be a large one and produce a fragmentation in a molecule. In the specific case of the solid state these fragments remain trapped in different places of the crystalline system. This can be considered as chemical change in the original molecule. These damages produced by the nuclear transformation can be measured by different methods: heating, gamma rays, pressure, etc. In this work the results of an experimental measurement of the behavior of the crystalline telluric acid molecule fragments under gamma radiation (0 to 20 Mrads) with controlled temperature of 2 0 C (-196 0 C to 50 0 C) it is presented. It was observed that the values of the mentioned behavior vary rapidly at first for relatively low doses and that for larger doses these values remained constant. Besides with a lower temperature these variation are progressively lower. (author)

Experimental approaches to the measurement of dielectronic recombination

International Nuclear Information System (INIS)

Datz, S.

1984-01-01

In dielectronic recombination, the first step involves a continuum electron which excites a previously bound electron and, in so doing, loses just enough energy to be captured in a bound state (nl). This results in a doubly excited ion of a lower charge state which may either autoionize or emit a photon resulting in a stabilized recombination. The complete signature of the event is an ion of reduced charge and an emitted photon. Methods of measuring this event are discussed

Collisional ionization

International Nuclear Information System (INIS)

Arnaud, M.

1985-07-01

In low density, thin plasmas (such as stellar coronae, interstellar medium, intracluster medium) the ionization process is governed by collision between electrons and ions in their ground state. In view of the recent improvements we thought an updating of ionization rates was really needed. The work is based on both experimental data and theoretical works and give separate estimates for the direct and autoionization rates

SCROLL, a superconfiguration collisional radiative model with external radiation

International Nuclear Information System (INIS)

Bar-Shalom, A.; Oreg, J.; Klapisch, M.

2000-01-01

A collisional radiative model for calculating non-local thermodynamical-equilibrium (non-LTE) spectra of heavy atoms in hot plasmas has been developed. It takes into account the numerous excited an autoionizing states by using superconfigurations. These are split systematically until the populations converge. The influence of an impinging radiation field has recently been added to the model. The effect can be very important. (author)

Evaluating U.S. States climate change initiatives

International Nuclear Information System (INIS)

Silva, P.

2004-01-01

This paper evaluates sub-federal efforts to mitigate climate change in the United States through a range of climate-relevant initiatives, identifying principal trends and detailing climate-relevant initiatives in several states. These strategies include renewable electricity mandates, State and regional greenhouse gas emissions inventories, mandatory greenhouse gas emissions reporting, State greenhouse gas emissions caps, greenhouse gas emissions reductions from motor vehicles, and greenhouse gas emissions cap-and-trade programs for electric generation in several States. Many municipalities in the United States are also pursuing a range of climate-relevant initiatives, those actions are beyond the scope of this paper, but it should be noted they also influence state and national consideration of climate-relevant initiatives in the United States. (author)

Evaluating U.S. States climate change initiatives

Energy Technology Data Exchange (ETDEWEB)

Silva, P

2004-07-01

This paper evaluates sub-federal efforts to mitigate climate change in the United States through a range of climate-relevant initiatives, identifying principal trends and detailing climate-relevant initiatives in several states. These strategies include renewable electricity mandates, State and regional greenhouse gas emissions inventories, mandatory greenhouse gas emissions reporting, State greenhouse gas emissions caps, greenhouse gas emissions reductions from motor vehicles, and greenhouse gas emissions cap-and-trade programs for electric generation in several States. Many municipalities in the United States are also pursuing a range of climate-relevant initiatives, those actions are beyond the scope of this paper, but it should be noted they also influence state and national consideration of climate-relevant initiatives in the United States. (author)

An accurate test of calculated positions and lifetimes for Ne6+(1s23lnl') 1L states (n=3 and 4) using a high-resolution electron spectroscopy

International Nuclear Information System (INIS)

Bordenave-Montesquieu, A.; Moretto-Capelle, P.; Bordenave-Montesquieu, D.

2003-01-01

An accurate test of available calculations for the autoionizing doubly excited states belonging to the Be-like 1s 2 3lnl ' Rydberg series of neon (positions and lifetimes) is presented in this short communication. These theoretical data are used to calculate electron line shapes which are compared, through a fitting procedure, with a high-resolution electron spectrum measured in Ne 8+ (1s 2 ) + He collisional system, at 80 keV collision energy and 13.1 deg. observation angle. Present tests concern the n=3 and n=4 singlet states. It is found that some of these calculations suffer from large discrepancies with experiment and do not allow a description of the electron spectrum. A quantitative comparison of measured and calculated post-collisional Coulomb interaction-shifted line positions is also given and briefly discussed; for one theoretical data set, the agreement with experiment is found to be generally within ±50 meV; in contrast agreement with other data often considerably scatters within ±500 meV and sometimes more

THE CURRENT STATE OF KNOWLEDGE IN THE VALUE RELEVANCE RESEARCH FIELD

OpenAIRE

Carmen- Alexandra BALTARIU

2015-01-01

The purpose of this paper is to assess the scientific literature referring to the value relevance of reported accounting information over a twelve year period starting from 2002. The approach of the paper is a theoretical (conceptual) one. In order to complete the purpose of the paper we selected as research method the longitudinal qualitative analysis. The qualitative analysis carried out presents a deductive character. Our conclusions regarding the general characteristics of the research fi...

Deep learning relevance

DEFF Research Database (Denmark)

Lioma, Christina; Larsen, Birger; Petersen, Casper

2016-01-01

train a Recurrent Neural Network (RNN) on existing relevant information to that query. We then use the RNN to "deep learn" a single, synthetic, and we assume, relevant document for that query. We design a crowdsourcing experiment to assess how relevant the "deep learned" document is, compared...... to existing relevant documents. Users are shown a query and four wordclouds (of three existing relevant documents and our deep learned synthetic document). The synthetic document is ranked on average most relevant of all....

The Value Relevance Of Value Added And Stakeholder Compensation Across Business Cultures

OpenAIRE

John Darcy

2011-01-01

This research performed a partial test of the instrumental validity of the stakeholder model by examining the value relevance of value added relative to income and the incremental value relevance of two stakeholder compensation components of value added, wages and interest for Japan, Germany, United States, and United Kingdom.

Dissociative photoionization of molecular hydrogen. A joint experimental and theoretical study of the electron-electron correlations induced by XUV photoionization and nuclear dynamics on IR-laser dressed transition states

Energy Technology Data Exchange (ETDEWEB)

Fischer, Andreas

2015-01-13

In this thesis, the dissociative single-ionization of molecular hydrogen is investigated in a kinematically complete experiment by employing extreme ultraviolet attosecond pulse trains and infrared femtosecond laser pulses. Induced by the absorption of a single XUV photon, a pronounced energy-dependent asymmetry of the relative emission direction of the photoelectron and the ion is observed. The asymmetry pattern is explained in terms of an interference of two ionization pathways involving a doubly-excited state. This interpretation is validated by a semi-classical model which only takes the nuclear motion into account. Using this model and the observed asymmetry, it is furthermore possible to disentangle the two dissociation pathways which allows for the determination of the autoionization lifetime of the contributing doubly-excited state as a function of the internuclear distance. Moreover, using a pump-probe experiment the dissociation dynamics of molecular hydrogen is investigated. A time-delay dependent momentum distribution of the fragments is observed. With a combined quantum mechanical and semi-classical approach the mechanism giving rise to the observed time-dependence is identified in terms of an intuitive elevator mechanism.

Soft Sensing of Key State Variables in Fermentation Process Based on Relevance Vector Machine with Hybrid Kernel Function

Directory of Open Access Journals (Sweden)

Xianglin ZHU

2014-06-01

Full Text Available To resolve the online detection difficulty of some important state variables in fermentation process with traditional instruments, a soft sensing modeling method based on relevance vector machine (RVM with a hybrid kernel function is presented. Based on the characteristic analysis of two commonly-used kernel functions, that is, local Gaussian kernel function and global polynomial kernel function, a hybrid kernel function combing merits of Gaussian kernel function and polynomial kernel function is constructed. To design optimal parameters of this kernel function, the particle swarm optimization (PSO algorithm is applied. The proposed modeling method is used to predict the value of cell concentration in the Lysine fermentation process. Simulation results show that the presented hybrid-kernel RVM model has a better accuracy and performance than the single kernel RVM model.

Investigation by high resolution electron spectroscopy of the helium-like 3lnl' Rydberg series in double capture processes at low collision velocity: auto transfer to Rydberg states and electron stabilization

International Nuclear Information System (INIS)

Bordenave-Montesquieu, A.; Moretto-Capelle, P.; Gonzalez, A.; Benhenni, M.; Bachau, H.; Sanchez, I.

1994-01-01

A high resolution electron spectrometry of the (3lnl') Ryberg series populated in N 7+ + He and Ne 10+ + He collisions at 10 q keV, 10 o allows us to observe, for the first time by this method, two post-collisional effects. First, it is found with nitrogen ions that, when n increases from n = 4 to 9, the L-distribution peaks more and more on the high angular momentum states. This is qualitatively understood as a Stark deformation of the Rydberg orbit by the Coulomb field of the receding ion. Also, in the n range where the double capture process populates symmetrical 4l4l' states (n>9), an enhancement of the intensities of the 3lnl' Rydberg lines is observed for both collisonal systems. This is thought to be a signature of the so-called auto transfer to Rydberg states effect. The transfer of population from the 3l4l' to the 3lnl' states is found to be favoured against a direct autoionization of these 4l4l' states into the n = 2 continuum. These experimental findings together with preliminary spectroscopic calculations concerning the configuration interaction of the Ne 8+ (4l4l') states with the Ne 8+ (3lnl') Rydberg series are also discussed within the context of the electron stabilization which follows a double capture. (Author)

Comment on 'Experimental study of single- and double-electron transfer in slow Ne8++He collisions using photon and electron spectroscopy'

International Nuclear Information System (INIS)

Bordenave-Montesquieu, A.; Moretto-Capelle, P.; Bordenave-Montesquieu, D.

2002-01-01

In this Comment we question the recent emphasis by Langereis et al. [Phys. Rev. A 60, 2917 (1999)] that excitation of triplet states in double-capture processes is noticeable in the Ne 8+ (1s 2 ) 1 S+He(1s 2 ) 1 S collisional system at 80 keV. We demonstrate that all their identified Ne 6+ (1s 2 3lnl ' ) autoionizing transitions can be perfectly explained by excitation of singlet states alone. In our opinion their findings based on electron spectroscopy rely on too inaccurate spectrum analysis and theoretical input data

High-resolution Auger spectroscopy on 79 MeV Ar5+, 89 MeV Ar6+, and 136 MeV Ar7+ ions after excitation by helium

International Nuclear Information System (INIS)

Schneider, T.

1988-01-01

In this thesis the atomic structure of highly excited Ar 6+ and Ar 7+ ions was studied. For this 79 MeV Ar 5+ , 89 MeV Ar 6+ , and 136 MeV Ar 7+ ions of a heavy ion accelerator were excited by a He gas target to autoionizing states and the Auger electrons emitted in the decay were measured in highly-resolving state. The spectra were taken under an observational angle of zero degree relative to the beam axis in order to minimize the kinematical broadening of the Auger lines. (orig./HSI) [de

Ionization photophysics and Rydberg spectroscopy of diacetylene

KAUST Repository

Schwell, Martin

2012-11-01

Photoionization of diacetylene was studied using synchrotron radiation over the range 8-24 eV, with photoelectron-photoion coincidence (PEPICO) and threshold photoelectron-photoion coincidence (TPEPICO) techniques. Mass spectra, ion yields, total and partial ionization cross-sections were measured. The adiabatic ionization energy of diacetylene was determined as IE ad=(10.17±0.01) eV, and the appearance energy of the principal fragment ion C4H+ as AE=(16.15±0.03) eV. Calculated appearance energies of other fragment ions were used to infer aspects of dissociation pathways forming the weaker fragment ions C+ 4, C3H+, C+3 and C 4H+. Structured autoionization features observed in the PEPICO spectrum of diacetylene in the 11-13 eV region were assigned to vibrational components of three new Rydberg series, R1(nsσg, n=4-11), R2(ndσg, n=4-7) and R3(ndδg, n=4-6) converging to the A2Πu state of the cation, and to a new series R01(nsσg, n=3) converging to the B\\' 2Σ+u state of the cation. The autoionization mechanisms and their consistence with specific selection rules are discussed. © 2012 Taylor and Francis.

Ionization photophysics and Rydberg spectroscopy of diacetylene

KAUST Repository

Schwell, Martin; Bé nilan, Yves; Fray, Nicolas; Gazeau, Marie Claire; Es-sebbar, Et-touhami; Gaie-Levrel, Franç ois; Champion, Norbert; Leach, Sydney Sydney

2012-01-01

Photoionization of diacetylene was studied using synchrotron radiation over the range 8-24 eV, with photoelectron-photoion coincidence (PEPICO) and threshold photoelectron-photoion coincidence (TPEPICO) techniques. Mass spectra, ion yields, total and partial ionization cross-sections were measured. The adiabatic ionization energy of diacetylene was determined as IE ad=(10.17±0.01) eV, and the appearance energy of the principal fragment ion C4H+ as AE=(16.15±0.03) eV. Calculated appearance energies of other fragment ions were used to infer aspects of dissociation pathways forming the weaker fragment ions C+ 4, C3H+, C+3 and C 4H+. Structured autoionization features observed in the PEPICO spectrum of diacetylene in the 11-13 eV region were assigned to vibrational components of three new Rydberg series, R1(nsσg, n=4-11), R2(ndσg, n=4-7) and R3(ndδg, n=4-6) converging to the A2Πu state of the cation, and to a new series R01(nsσg, n=3) converging to the B' 2Σ+u state of the cation. The autoionization mechanisms and their consistence with specific selection rules are discussed. © 2012 Taylor and Francis.

Photoionization studies with molecular beams

International Nuclear Information System (INIS)

Ng, C.Y.

1976-09-01

A molecular beam photoionization apparatus which combines the advantages of both the molecular beam method with photoionization mass spectrometry has been designed and constructed for carrying out some unique photoionization experiments. Rotational cooling during the supersonic expansion has resulted in high resolution photoionization efficiency curves for NO, ICl, C 2 H 2 and CH 3 I. The analysis of these spectra has yielded ionization potentials for these molecules to an accuracy of +- 3 MeV. Detailed autoionization structures were also resolved. This allows the investigation of the selection rules for autoionization, and the identification of the Rydberg series which converge to the excited states of the molecular ions. The degree of relaxation for thermally populated excited states has been examined using NO and ICl as examples. As a result of adiabatic cooling, a small percentage of dimers is also formed during the expansion. The photoionization efficiency curves for (NO) 2 , ArICl, Ar 2 , Kr 2 and Xe 2 have been obtained near the thresholds. Using the known dissociation energies of the (NO) 2 , Ar 2 , Kr 2 and Xe 2 van der Waals molecules, the corresponding dissociation energies for NO-NO + , Ar 2 + , Kr 2 + , and Xe 2 + have been determined. The ionization mechanisms for this class of molecules are examined and discussed

Mapping Catalytically Relevant Edge Electronic States of MoS2

Science.gov (United States)

2018-01-01

Molybdenum disulfide (MoS2) is a semiconducting transition metal dichalcogenide that is known to be a catalyst for both the hydrogen evolution reaction (HER) as well as for hydro-desulfurization (HDS) of sulfur-rich hydrocarbon fuels. Specifically, the edges of MoS2 nanostructures are known to be far more catalytically active as compared to unmodified basal planes. However, in the absence of the precise details of the geometric and electronic structure of the active catalytic sites, a rational means of modulating edge reactivity remain to be developed. Here we demonstrate using first-principles calculations, X-ray absorption spectroscopy, as well as scanning transmission X-ray microscopy (STXM) imaging that edge corrugations yield distinctive spectroscopic signatures corresponding to increased localization of hybrid Mo 4d states. Independent spectroscopic signatures of such edge states are identified at both the S L2,3 and S K-edges with distinctive spatial localization of such states observed in S L2,3-edge STXM imaging. The presence of such low-energy hybrid states at the edge of the conduction band is seen to correlate with substantially enhanced electrocatalytic activity in terms of a lower Tafel slope and higher exchange current density. These results elucidate the nature of the edge electronic structure and provide a clear framework for its rational manipulation to enhance catalytic activity. PMID:29721532

Atomic data for dielectronic recombination into Mg-like Fe

International Nuclear Information System (INIS)

Murakami, I.; Kato, T.; Kato, D.; Safronova, U.I.; Cowan, T.E.; Ralchenko, Yu.

2006-03-01

Energy levels, radiative transition probabilities, and autoionization rates for 1s 2 2s 2 2p 6 3l'nl (n=3-12, l≤n-1) and 1s 2 2s 2 2p 6 4l'nl (n=4-7, l≤n-1) states in Mg-like iron (Fe 14+ ) are calculated by the Hartree-Fock-Relativistic method (Cowan code) and the relativistic many-body perturbation theory method (RMBPT code). Autoionizing levels above three thresholds 1s 2 2s 2 2p 6 3s, 1s 2 2s 2 2p 6 3p, and 1s 2 2s 2 2p 6 3d are considered. It is found that configuration mixing [3sns + 3pnp + 3dnd], [3snp + 3pns + 3pnd + 3dnp] play an important role for all atomic characteristics. Branching ratios relative to the first threshold and intensity factors for satellite lines are calculated, and dielectronic recombination (DR) rate coefficients are determined for the excited 444 odd-parity and 419 even-parity states. It is shown that the contribution of the highly-excited states is very important for calculation of DR rates. Contribution from the excited 1s 2 2s 2 2p 6 3l'nl states with n≥12 and 1s 2 2s 2 2p 6 4l'nl states with n≥7 to DR rate coefficients are estimated by extrapolation of all atomic characteristics. The total DR rate coefficient is derived as a function of electron temperature. (author)

An accurate test of calculated positions and lifetimes for Ne{sup 6+}(1s{sup 2}3lnl{sup '}) {sup 1}L states (n=3 and 4) using a high-resolution electron spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Bordenave-Montesquieu, A. E-mail: abm@irsamc.ups-tlse.fr; Moretto-Capelle, P.; Bordenave-Montesquieu, D

2003-05-01

An accurate test of available calculations for the autoionizing doubly excited states belonging to the Be-like 1s{sup 2}3lnl{sup '} Rydberg series of neon (positions and lifetimes) is presented in this short communication. These theoretical data are used to calculate electron line shapes which are compared, through a fitting procedure, with a high-resolution electron spectrum measured in Ne{sup 8+}(1s{sup 2}) + He collisional system, at 80 keV collision energy and 13.1 deg. observation angle. Present tests concern the n=3 and n=4 singlet states. It is found that some of these calculations suffer from large discrepancies with experiment and do not allow a description of the electron spectrum. A quantitative comparison of measured and calculated post-collisional Coulomb interaction-shifted line positions is also given and briefly discussed; for one theoretical data set, the agreement with experiment is found to be generally within {+-}50 meV; in contrast agreement with other data often considerably scatters within {+-}500 meV and sometimes more.

Is QCD relevant to nuclear physics

International Nuclear Information System (INIS)

Thomas, A.W.

1985-01-01

A review is given of recent work on baryon structure in a number of QCD-motivated models. After establishing a prima facie case that the quark model should be relevant in a consistent description of the nucleus over a wide range of momentum transfer, the author looks for experimental confirmation. The discussion includes the search for exotic states, for a six quark component of the deuteron, and an up to date report on the interpretation of the EMC effect. (Auth.)

State-specific reactions and autoionization dynamics of Ar2+ produced by synchrotron radiation

Czech Academy of Sciences Publication Activity Database

Franceschi, P.; Thissen, R.; Dutuit, O.; Alcaraz, Ch.; Soldi-Lose, H.; Bassi, D.; Ascenzi, D.; Tosi, P.; Žabka, Ján; Herman, Zdeněk; Coreno, M.; De Simone, M.

2009-01-01

Roč. 280, 1-3 (2009), s. 119-127 ISSN 1387-3806 R&D Projects: GA AV ČR IAA400400702 Institutional research plan: CEZ:AV0Z40400503 Keywords : argon * dications * photoionization * ion molecule reaction Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 2.117, year: 2009

Resource Efficiency. What does it mean and why is it relevant? Policy Brief

Energy Technology Data Exchange (ETDEWEB)

Jansen, J.C. [ECN Policy Studies, Petten (Netherlands)

2013-04-15

The European Commission has launched a Resource-Efficient Europe as one of its seven flagship initiatives under the Europe 2020 Strategy and has published the document 'Roadmap to a Resource-Efficient Europe'. The Roadmap specifies a proposed pathway to action for a resource efficient Europe. This document sets out to describe the essence of the resource efficiency concept and to sketch the relevance of EU resource efficiency policy for application at EU member state level with special reference to the Netherlands. The following questions will be addressed: What is resource efficiency?; How does it relate to sustainability and environmental footprint?; What is the relevance of EU resource efficiency policy for the member states?; Which aspects of resource efficiency are relevant for the Netherlands?; and To what extent is resource efficiency reflected in current Dutch policies?.

A identidade nacional portuguesa: conteúdo e relevância

Directory of Open Access Journals (Sweden)

Cabral Manuel Villaverde

2003-01-01

Full Text Available This article discusses the relative merits of the instrumentalist and primordialist theses concerning the roles of the State and the nation in the production of contemporary national identities, as well as presenting a brief genealogy of Portuguese national identity. However, the attempt to anchor this identity in a purported "national character" reveals the reductionism and normative dimension of identitary ideology. The research is thus reoriented towards the relevance of national sentiment in current Portuguese society, observing that this sentiment constitutes a relevant symbolic resource, particularly for purposes of political mobilization.

Long-Range Predissociation in Two-Color Photoassociation of Ultracold Na Atoms

International Nuclear Information System (INIS)

Molenaar, P.A.; van der Straten, P.; Heideman, H.G.

1996-01-01

We report two-color photoassociative ionization of sodium in a magneto-optical trap. The experimental results yield information on both singly and doubly excited states. We find that the highest bound vibrational levels (v approx-gt 20) of the singly excited 0 g - state predissociate into the 3 2 P 3/2 +3 2 S 1/2 (F g =1) dissociation continuum due to avoided crossings of the hyperfine components of this potential with other molecular symmetries. Based on symmetry and energy consideration we argue that a doubly excited 1 u state remains autoionizing even when only a few GHz above the dissociation continuum. copyright 1996 The American Physical Society

Photoionization dynamics of excited Ne, Ar, Kr and Xe atoms near threshold

International Nuclear Information System (INIS)

Sukhorukov, V L; Petrov, I D; Schäfer, M; Merkt, F; Ruf, M-W; Hotop, H

2012-01-01

A review of experimental and theoretical studies of the threshold photoionization of the heavier rare-gas atoms is presented, with particular emphasis on the autoionization resonances in the spectral region between the lowest two ionization thresholds 2 P 3/2 and 2 P 1/2 , accessed from the ground or excited states. Observed trends in the positions, widths and shapes of the autoionization resonances depending on the atomic number, the principal quantum number n, the orbital angular momentum quantum number ℓ and further quantum numbers specifying the fine- and hyperfine-structure levels are summarized and discussed in the light of ab initio and multichannel quantum defect theory calculations. The dependence of the photoionization spectra on the initially prepared neutral state are also discussed, including results on the photoionization cross sections and photoelectron angular distributions of polarized excited states. The effects of various approximations in the theoretical treatment of photoionization in these systems are analysed. The very large diversity of observed phenomena and the numerous anomalies in spectral structures associated with the threshold ionization of the rare-gas atoms can be described in terms of a limited set of interactions and dynamical processes. Examples are provided illustrating characteristic aspects of the photoionization, and sets of recommended parameters describing the energy-level structure and photoionization dynamics of the rare-gas atoms are presented which were extracted in a critical analysis of the very large body of experimental and theoretical data available on these systems in the literature. (topical review)

Absolute photoionization cross sections of atomic oxygen

Science.gov (United States)

Samson, J. A. R.; Pareek, P. N.

1985-01-01

The absolute values of photoionization cross sections of atomic oxygen were measured from the ionization threshold to 120 A. An auto-ionizing resonance belonging to the 2S2P4(4P)3P(3Do, 3So) transition was observed at 479.43 A and another line at 389.97 A. The experimental data is in excellent agreement with rigorous close-coupling calculations that include electron correlations in both the initial and final states.

Photoionisation of O6+ below the n=3 threshold of the reduced ion

International Nuclear Information System (INIS)

Faye, N.A.B.; Wague, A.

1994-01-01

Near the n=3 threshold of residual ion O 7+ , the resonant photoionization of the multicharged ion O 6+ is considered by calculating the excitation energies, associated wave-functions, partial and total widths of the 1 P (-) and 3 P (-) autoionizing states. These calculations are made in the diagonalization approximation in the LS coupling scheme. The results are compared with the available theoretical results obtained by authors using other theoretical approaches. (author). 16 refs, 5 tabs

Resonance ionization scheme development for europium

Energy Technology Data Exchange (ETDEWEB)

Chrysalidis, K., E-mail: katerina.chrysalidis@cern.ch; Goodacre, T. Day; Fedosseev, V. N.; Marsh, B. A. [CERN (Switzerland); Naubereit, P. [Johannes Gutenberg-Universität, Institiut für Physik (Germany); Rothe, S.; Seiffert, C. [CERN (Switzerland); Kron, T.; Wendt, K. [Johannes Gutenberg-Universität, Institiut für Physik (Germany)

2017-11-15

Odd-parity autoionizing states of europium have been investigated by resonance ionization spectroscopy via two-step, two-resonance excitations. The aim of this work was to establish ionization schemes specifically suited for europium ion beam production using the ISOLDE Resonance Ionization Laser Ion Source (RILIS). 13 new RILIS-compatible ionization schemes are proposed. The scheme development was the first application of the Photo Ionization Spectroscopy Apparatus (PISA) which has recently been integrated into the RILIS setup.

Time-resolved and steady-state studies of biologically and chemically relevant systems using laser, absorption, and fluorescence spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Barnes, Charles Ashley [Iowa State Univ., Ames, IA (United States)

2014-12-20

In Chapter 2 several experimental and data analysis methods used in this thesis are described. In Chapter 3 steady-state fluorescence spectroscopy was used to determine the concentration of the efflux pump inhibitors (EPIs), pheophorbide a and pyropheophorbide a, in the feces of animals and it was found that their levels far exceed those reported to be inhibitory to efflux pumps. In Chapter 4 the solvation dynamics of 6-Propionyl-2-(N,Ndimethyl) aminonaphthalene (PRODAN) was studied in reverse micelles. The two fluorescent states of PRODAN solvate on different time scales and as such care must be exercised in solvation dynamic studies involving it and its analogs. In Chapter 5 we studied the experimental and theoretical solvation dynamics of coumarin 153 (C153) in wild-type (WT) and modified myoglobins. Based on the nuclear magnetic resonance (NMR) spectroscopy and time-resolved fluorescence studies, we have concluded that it is important to thoroughly characterize the structure of a protein and probe system before comparing the theoretical and experimental results. In Chapter 6 the photophysical and spectral properties of a derivative of the medically relevant compound curcumin called cyclocurcumin was studied. Based on NMR, fluorescence, and absorption studies, the ground- and excited-states of cyclocurcumin are complicated by the existence of multiple structural isomers. In Chapter 7 the hydrolysis of cellulose by a pure form of cellulase in an ionic liquid, HEMA, and its aqueous mixtures at various temperatures were studied with the goal of increasing the cellulose to glucose conversion for biofuel production. It was found that HEMA imparts an additional stability to cellulase and can allow for faster conversion of cellulose to glucose using a pre-treatment step in comparison to only buffer.

High-resolution, three-step resonance ionization mass spectrometry of gadolinium

International Nuclear Information System (INIS)

Blaum, K.; Wendt, K.; Bushaw, B.A.; Noertershaeuser, W.

2001-01-01

High-resolution resonance ionization mass spectrometry has been used to measure triple-resonance autoionization (AI) spectra of gadolinium. Al resonances as narrow as 10 MHz have been observed and isotope shifts and hyperfine structure have been measured in selected AI states. The strongest AI state observed at 49663.576 cm-1 with a photoionization cross section of >3.6x10 -15 cm 2 was found to have an overall detection efficiency of >3x10 -5 , allowing application to a number of ultratrace determination problems. Analytical measurements with a diode-laser-based system have been successfully performed on bio-medical tissue samples

Triplet Excited States as a Source of Relevant (Bio)Chemical Information

OpenAIRE

Jiménez Molero, María Consuelo; Miranda Alonso, Miguel Ángel

2014-01-01

The properties of triplet excited states are markedly medium-dependent, which turns this species into valuable tools for investigating the microenvironments existing in protein binding pockets. Monitoring of the triplet excited state behavior of drugs within transport proteins (serum albumins and alpha(1)-acid glycoproteins) by laser flash photolysis constitutes a valuable source of information on the strength of interaction, conformational freedom and protection from oxygen or other external...

Investigation by high resolution electron spectroscopy of the helium-like 3lnl' Rydberg series in double capture processes at low collision velocity: auto transfer to Rydberg states and electron stabilization

Energy Technology Data Exchange (ETDEWEB)

Bordenave-Montesquieu, A.; Moretto-Capelle, P.; Gonzalez, A.; Benhenni, M. (Toulouse-3 Univ., 31 (France)); Bachau, H.; Sanchez, I. (Bordeaux-1 Univ., 33 - Talence (France). Lab. des Collisions Atomiques)

1994-09-28

A high resolution electron spectrometry of the (3lnl') Ryberg series populated in N[sup 7+] + He and Ne[sup 10+] + He collisions at 10 q keV, 10[sup o] allows us to observe, for the first time by this method, two post-collisional effects. First, it is found with nitrogen ions that, when n increases from n = 4 to 9, the L-distribution peaks more and more on the high angular momentum states. This is qualitatively understood as a Stark deformation of the Rydberg orbit by the Coulomb field of the receding ion. Also, in the n range where the double capture process populates symmetrical 4l4l' states (n>9), an enhancement of the intensities of the 3lnl' Rydberg lines is observed for both collisonal systems. This is thought to be a signature of the so-called auto transfer to Rydberg states effect. The transfer of population from the 3l4l' to the 3lnl' states is found to be favoured against a direct autoionization of these 4l4l' states into the n = 2 continuum. These experimental findings together with preliminary spectroscopic calculations concerning the configuration interaction of the Ne[sup 8+] (4l4l') states with the Ne[sup 8+](3lnl') Rydberg series are also discussed within the context of the electron stabilization which follows a double capture. (Author).

Electron and molecular ion collisions relevant to divertor plasma

International Nuclear Information System (INIS)

Takagi, H.

2005-01-01

We introduce the concept of the multi-channel quantum defect theory (MQDT) and show the outline of the MQDT newly extended to include the dissociative states. We investigate some molecular processes relevant to the divertor plasma by using the MQDT: the dissociative recombination, dissociative excitation, and rotation-vibrational transition in the hydrogen molecular ion and electron collisions. (author)

Relevant multi-setting tight Bell inequalities for qubits and qutrits

International Nuclear Information System (INIS)

Deng Dongling; Zhou Zisui; Chen Jingling

2009-01-01

In the celebrated paper [D. Collins, N. Gisin, J. Phys. A Math. Gen. 37 (2004) 1775], Collins and Gisin presented for the first time a three-setting Bell inequality (here we call it CG inequality for simplicity) which is relevant to the Clauser-Horne-Shimony-Holt (CHSH) inequality. Inspired by their brilliant ideas, we obtained some multi-setting tight Bell inequalities, which are relevant to the CHSH inequality and the CG inequality. Moreover, we generalized the method in the paper [J.L. Chen, D.L. Deng, Phys. Rev. A 79 (2009) 012115] to construct Bell inequality for qubits to higher dimensional system. Based on the generalized method, we present, for the first time, a three-setting tight Bell inequality for two qutrits, which is maximally violated by nonmaximally entangled states and relevant to the Collins-Gisin-Linden-Massar-Popescu inequality.

Auger transitions in singly and multiply ionized atoms

International Nuclear Information System (INIS)

Mehlhorn, W.

1978-01-01

Some recent progress in Auger and autoionizing electron spectrometry of free metal atoms and of multiply ionized atoms is reviewed. The differences which arise between the spectra of atoms in the gaseous and the solid state are due to solid state effects. This will be shown for Cd as an example. The super Coster-Kronig transitions 3p-3d 2 (hole notation) and Coster-Kronig transitions 3p-3d 4s have been measured and compared with free-atom calculations for free Zn atoms. The experimental width GAMMA(3p)=(2.1+-0.2)eV found for the free atom agrees with the value obtained for solid Zn but is considerably smaller than the theoretical value for the free atom. Autoionizing spectra of Na following an L-shell excitation or ionization by different particles are compared and discussed. The nonisotropic angular distribution of electrons from the transition 2p 5 3s 2 2 Psub(3/2)→2p 6 +e - is compared with theoretical calculations. Two examples for Auger spectrometry of multiply ionized atoms are given: (1) excitation of neon target atoms by light and heavy ions, and (2) excitation of projectile ions Be + and B + in single gas collisions with CH 4 . A strong alignment of the excited atoms has also been found here

Heterogeneous reaction mechanisms and kinetics relevant to the CVD of semiconductor materials

Energy Technology Data Exchange (ETDEWEB)

Creighton, J.R.; Coltrin, M.E.

1994-03-01

This report documents the state of the art in experimental and theoretical techniques for determining reaction mechanisms and chemical kinetics of heterogeneous reactions relevant to the chemical vapor deposition of semiconductor materials. It summarizes the most common ultra-high vacuum experimental techniques that are used and the types of rate information available from each. Several case studies of specific chemical systems relevant to the microelectronics industry are described. Theoretical methods for calculating heterogeneous reaction rate constants are also summarized.

Missouri State information handbook: formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1980-01-01

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of Missouri. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature chairmen, and a summary of recent relevant legislative action; a description of the organization and structure of local governments affected by remedial action at the St. Louis area sites; a summary of relevant local ordinances and regulations; an identification of relevant public interest groups; a list of radio stations, television stations, and newspapers that provide public information to the St. Louis area or to Jefferson City; and the full text of relevant statutes and regulations

Missouri State information handbook: formerly utilized sites remedial action program

Energy Technology Data Exchange (ETDEWEB)

None

1980-12-31

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of Missouri. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature chairmen, and a summary of recent relevant legislative action; a description of the organization and structure of local governments affected by remedial action at the St. Louis area sites; a summary of relevant local ordinances and regulations; an identification of relevant public interest groups; a list of radio stations, television stations, and newspapers that provide public information to the St. Louis area or to Jefferson City; and the full text of relevant statutes and regulations.

User perspectives on relevance criteria

DEFF Research Database (Denmark)

Maglaughlin, Kelly L.; Sonnenwald, Diane H.

2002-01-01

, partially relevant, or not relevant to their information need; and explained their decisions in an interview. Analysis revealed 29 criteria, discussed positively and negatively, that were used by the participants when selecting passages that contributed or detracted from a document's relevance......This study investigates the use of criteria to assess relevant, partially relevant, and not-relevant documents. Study participants identified passages within 20 document representations that they used to make relevance judgments; judged each document representation as a whole to be relevant...... matter, thought catalyst), full text (e.g., audience, novelty, type, possible content, utility), journal/publisher (e.g., novelty, main focus, perceived quality), and personal (e.g., competition, time requirements). Results further indicate that multiple criteria are used when making relevant, partially...

Enabling Collaborative Analysis: State Evaluation Groups, the Electronic State File, and Collaborative Analysis Tools

International Nuclear Information System (INIS)

Eldridge, C.; Gagne, D.; Wilson, B.; Murray, J.; Gazze, C.; Feldman, Y.; Rorif, F.

2015-01-01

The timely collection and analysis of all safeguards relevant information is the key to drawing and maintaining soundly-based safeguards conclusions. In this regard, the IAEA has made multidisciplinary State Evaluation Groups (SEGs) central to this process. To date, SEGs have been established for all States and tasked with developing State-level approaches (including the identification of technical objectives), drafting annual implementation plans specifying the field and headquarters activities necessary to meet technical objectives, updating the State evaluation on an ongoing basis to incorporate new information, preparing an annual evaluation summary, and recommending a safeguards conclusion to IAEA senior management. To accomplish these tasks, SEGs need to be staffed with relevant expertise and empowered with tools that allow for collaborative access to, and analysis of, disparate information sets. To ensure SEGs have the requisite expertise, members are drawn from across the Department of Safeguards based on their knowledge of relevant data sets (e.g., nuclear material accountancy, material balance evaluation, environmental sampling, satellite imagery, open source information, etc.) or their relevant technical (e.g., fuel cycle) expertise. SEG members also require access to all available safeguards relevant data on the State. To facilitate this, the IAEA is also developing a common, secure platform where all safeguards information can be electronically stored and made available for analysis (an electronic State file). The structure of this SharePoint-based system supports IAEA information collection processes, enables collaborative analysis by SEGs, and provides for management insight and review. In addition to this common platform, the Agency is developing, deploying, and/or testing sophisticated data analysis tools that can synthesize information from diverse information sources, analyze diverse datasets from multiple viewpoints (e.g., temporal, geospatial

Relevance of Programs for Emotionally Disturbed Youth in Other Lands

Science.gov (United States)

David, Henry P.

1970-01-01

A survey of current trends was conducted in more than 40 countries. Focus was on the organization of services and their relevance for evolving practices in the United States. Apparent was a willingness to experiment with administrative and therapeutic roles. Ideological differences are important determinants of the organization, range, and quality…

The observation of the Ne-like ion resonance line satellites for CrXV ... Ni XIX CO2-laser produced plasma

International Nuclear Information System (INIS)

Khakhalin, S.Ya.; Faenov, A.Ya.; Skobelev, I.Yu.; Pikuz, S.A.; Nilsen, J.; Osterheld, A.

1994-01-01

We present an analysis of dielectronic satellite spectra of Ne-like ion resonance lines for elements from Cr to Ni. For these low-Z elements, we use spectra from strongly underionized CO 2 -laser produced plasma to minimize the emission from open L-shell ions. This simplifies the spectra and allows the identification of satellite lines caused by radiative transitions from autoionizing states of sodium like ions. Good agreement between the satellite structure calculations and the experimental emission spectra is obtained. (orig.)

Effects of configuration interaction on photoabsorption spectra in the continuum

International Nuclear Information System (INIS)

Komninos, Yannis; Nicolaides, Cleanthes A.

2004-01-01

It is pointed out that the proper interpretation of a recently published experimental spectrum from the multilaser photoionization of Sr [Eichmann et al., Phys. Rev. Lett. 90, 233004 (2003)] must account for a radiative transition between two autoionizing states. The application of orthonormality selection rules and of configuration-interaction theory involving the continuous spectrum and the quasicontinuum of the upper part of Rydberg series explains quantitatively the appearance, the shape, and the variation of heights of the observed peaks of resonances

Study of emission process in hot, optically thin plasma: application to solar active regions

International Nuclear Information System (INIS)

Steenman-Clark, Lois.

1983-06-01

Analysis of soft X-ray got in hot and weak density plasmas, such as those in TOKAMAKS and in solar flares, needs a detailed knowledge of emission processes. In this work are presented spectroscopic diagnostics which can be deduced from such spectra analysis and results are applied to magnesium solar spectrum analysis. An important improvement is brought to collisional calculation corresponding to forbidden line populating. For this line, The relative importance of autoionizing states effect, called also resonance effect is studied [fr

The observation of the Ne-like ion resonance line satellites for CrXV. Ni XIX CO[sub 2]-laser produced plasma

Energy Technology Data Exchange (ETDEWEB)

Khakhalin, S.Ya. (MISDC, NPO ' ' VNIIFTRI' ' , Mendeleevo (Russian Federation)); Faenov, A.Ya. (MISDC, NPO ' ' VNIIFTRI' ' , Mendeleevo (Russian Federation)); Skobelev, I.Yu. (MISDC, NPO ' ' VNIIFTRI' ' , Mendeleevo (Russian Federation)); Pikuz, S.A. (P. N. Lebedev Physical Inst., Russian Academy of Science, Moscow (Russian Federation)); Nilsen, J. (Lawrence Livermore National Lab., Livermore, CA (United States)); Osterheld, A. (Lawrence Livermore National Lab., Livermore, CA (United States))

1994-08-01

We present an analysis of dielectronic satellite spectra of Ne-like ion resonance lines for elements from Cr to Ni. For these low-Z elements, we use spectra from strongly underionized CO[sub 2]-laser produced plasma to minimize the emission from open L-shell ions. This simplifies the spectra and allows the identification of satellite lines caused by radiative transitions from autoionizing states of sodium like ions. Good agreement between the satellite structure calculations and the experimental emission spectra is obtained. (orig.).

Experimental (e, 2e) study of exchange interferences in the resonant Auger decay of Ar induced by electron impact

International Nuclear Information System (INIS)

Paripás, Béla; Palásthy, Béla; Žitnik, Matjaz

2013-01-01

Highlights: •The interference of autoionizing resonances with a common final ionic state is measured. •We have developed a method to experimentally verify for the exchange interference effect. •The sum of kinetic energies of the two detected electrons is kept constant. •Mainly the interference effects of [2p 3/2 ]4p and [2p 1/2 ]4p resonances in argon are studied. •The results possibly indicate small exchange interference effects. -- Abstract: Any two autoionizing resonances with a common final ionic state can be made to interfere by an appropriate selection of electron impact energy. To reveal the exchange interference effects a selective detection of electron pairs related to the selected final state is desired. We have performed a constant ionic state (e, 2e) experiment (CIS) isolating the final state by keeping the sum of transmission energies of two independent electron spectrometers constant. In the focus of this work are the exchange interference effects of 2p 3/2 −1 4p and 2p 1/2 −1 4p resonances in argon decaying to the 3p −2 ( 1 D)4p 2 P, 2 D final ionic state with energy E F = 37.3 ± 0.2 eV. We have developed a method to experimentally verify for the exchange interference effect. It is based on a comparison of the CIS spectrum recorded at the critical primary electron energy that activates the interferences, and the constructed, interference-free CIS spectrum that is build up from the CIS spectrum measured at primary electron energy away from the critical value. The results possibly indicate small exchange interference effects that may have been considerably smeared out at present experimental energy resolution

State diagrams of tokamaks and state transitions

International Nuclear Information System (INIS)

Minardi, E.

1992-01-01

In a simple one-fluid cylindrical model of transport and of dissipative effects, the family of the magnetic states of the Tokamak which correspond to a vanishing entropy production in the confinement region is characterized by a define relation or ''state equation'' involving the relevant parameters of the discharge. An investigation is made as to how the entropy production changes when the current density profile is rearranged by a perturbation which conserves the poloidal magnetic flux. It is shown that for a sufficiently short time interval, that is to say t 2 E τ s where τ E is the energy confinement time and τ s is the resistive time, neighbouring bifurcating equilibria exist which can be reached with a flux-conserving transition and with increase of the magnetic entropy. The family of these new states can also be characterized by a state equation involving the relevant discharge parameters. When the state equations of the two families are simultaneously satisfied by the same set of parameter values, a flux-conserving, entropy-increasing transition may take place between states of the two families. The modifications of the current density and of the temperature profiles involved in the transition and the conditions that the discharge parameters should satisfy in order that the transition could occur are investigated. (author)

Missouri state information handbook formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1980-01-01

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and rgulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of Missouri. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; a description of the organization and structure of local governments affected by remedial action at the St. Louis area sites; a summary of relevant local ordinances and regulations; an identification of relevant public interest groups; a list of radio stations, television stations and newspapers that provide public information to the St. Louis area or to Jefferson City; and the full text of relevant statutes and regulations

Iowa state information handbook: formerly utilized sites remedial action program

Energy Technology Data Exchange (ETDEWEB)

None

1981-02-09

This volume is one of a series produced under contract with the DOE, By Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the state of Iowa. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; the full test of relevant statutes and regulations.

California state information handbook: formerly utilized sites remedial action program

Energy Technology Data Exchange (ETDEWEB)

None

1981-02-09

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the state of California. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; the full text of relevant statutes and regulations.

Pennsylvania state information handbook: formerly utilized sites remedial action program

Energy Technology Data Exchange (ETDEWEB)

None

1980-12-31

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and State levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of Pennsylvania. It contains a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations.

Illinois state information handbook: formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1980-01-01

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of Illinois. It contains a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; the full text of relevant statutes and regulations

Illinois State information handbook: formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1980-01-01

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of Illinois. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations

Massachusetts state information handbook: formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1981-01-01

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the state of Massachusetts. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; the full text of relevant statutes and regulations

Florida state information handbook: formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1981-01-01

This volume is one of a series produced under contract with DOE, Office of Nuclear Waste Management, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the federal and state levels, the pertinent programs they administer, each affected state legislature, and current federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of Florida. It contains a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations

Massachusetts state information handbook: formerly utilized sites remedial action program

Energy Technology Data Exchange (ETDEWEB)

None

1981-02-09

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the state of Massachusetts. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; the full text of relevant statutes and regulations.

Oregon state information handbook: formerly utilized sites remedial action program

Energy Technology Data Exchange (ETDEWEB)

None

1980-12-31

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of Oregon. It contains a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations.

Maryland State information handbook: formerly utilized sites remedial action program

Energy Technology Data Exchange (ETDEWEB)

None

1980-12-31

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Handbook Series Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of Maryland. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations.

Pennsylvania state information handbook formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1980-01-01

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of Pennsylvania. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations

Maryland State information handbook: formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1980-01-01

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Handbook Series Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of Maryland. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations

Pennsylvania state information handbook: formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1980-01-01

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and State levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of Pennsylvania. It contains a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations

Iowa state information handbook: formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1981-01-01

This volume is one of a series produced under contract with the DOE, By Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the state of Iowa. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; the full test of relevant statutes and regulations

California state information handbook: formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1981-01-01

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the state of California. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; the full text of relevant statutes and regulations

Florida state information handbook: formerly utilized sites remedial action program

Energy Technology Data Exchange (ETDEWEB)

None

1981-02-27

This volume is one of a series produced under contract with DOE, Office of Nuclear Waste Management, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the federal and state levels, the pertinent programs they administer, each affected state legislature, and current federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of Florida. It contains a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations.

Maryland state information handbook: formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1980-01-01

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and State levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of Maryland. It contains a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations

Oregon state information handbook: formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1980-01-01

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of Oregon. It contains a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations

Oregon state information handbook formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1980-01-01

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administater, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of Oregon. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations

Ohio state information handbook: formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1981-01-01

This volume is one of a series produced under contract with the DOE, by POLITECH CORPORATION to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the state of Ohio. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; the full test of relevant statutes and regulations

Ohio state information handbook: formerly utilized sites remedial action program

Energy Technology Data Exchange (ETDEWEB)

1981-02-09

This volume is one of a series produced under contract with the DOE, by POLITECH CORPORATION to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the state of Ohio. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; the full test of relevant statutes and regulations.

Oregon state information handbook formerly utilized sites remedial action program

Energy Technology Data Exchange (ETDEWEB)

None

1980-12-31

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administater, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of Oregon. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations.

Functional dyspepsia: Are psychosocial factors of relevance?

Institute of Scientific and Technical Information of China (English)

Sandra Barry; Timothy G Dinan

2006-01-01

The pathogenesis of Functional Dyspepsia (FD) remains unclear, appears diverse and is thus inadequately understood. Akin to other functional gastrointestinal disorders, research has demonstrated an association between this common diagnosis and psychosocial factors and psychiatric morbidity. Conceptualising the relevance of these factors within the syndrome of FD requires application of the biopsychosocial model of disease.Using this paradigm, dysregulation of the reciprocal communication between the brain and the gut is central to symptom generation, interpretation and exacerbation.Appreciation and understanding of the neurobiological correlates of various psychological states is also relevant.The view that psychosocial factors exert their influence in FD predominantly through motivation of health care seeking also persists. This appears too one-dimensional an assertion in light of the evidence available supporting a more intrinsic aetiological link. Evolving understanding of pathogenic mechanisms and the heterogeneous nature of the syndrome will facilitate effective management.Co-morbid psychiatric illness warrants treatment with conventional therapies. Acknowledging the relevance of psychosocial variables in FD, the degree of which is subject to variation, has implications for assessment and management. Available evidence suggests psychological therapies may benefit FD patients particularly those with chronic symptoms. The rationale for use of psychotropic medications in FD is apparent but the evidence base to support the use of antidepressant pharmacotherapy is to date limited.

Parsimonious relevance models

NARCIS (Netherlands)

Meij, E.; Weerkamp, W.; Balog, K.; de Rijke, M.; Myang, S.-H.; Oard, D.W.; Sebastiani, F.; Chua, T.-S.; Leong, M.-K.

2008-01-01

We describe a method for applying parsimonious language models to re-estimate the term probabilities assigned by relevance models. We apply our method to six topic sets from test collections in five different genres. Our parsimonious relevance models (i) improve retrieval effectiveness in terms of

Secondary-electron-production cross sections for electron-impact ionization of molecular nitrogen

International Nuclear Information System (INIS)

Goruganthu, R.R.; Wilson, W.G.; Bonham, R.A.

1987-01-01

Measurements of the double-differential cross section (DDCS), as a function of the ejected energy, angle, and primary energy for electron-impact ionization of molecular nitrogen are reported at incident energies of 200, 500, 1000, and 2000 eV. The ejection angle was varied from 30 0 to 150 0 in steps of 15 0 . The cross sections were obtained by use of a crossed-beam apparatus with an effusive gas source and a pulsed electron beam. Scattered and ejected electrons were energy analyzed by time-of-flight analysis from below 2 eV to the primary energy. The relative measurements were placed on an absolute scale by matching the experimental elastic differential cross sections to absolute measurements at each primary energy. Comparisons of the DDCS with previous reported values revealed significant differences. The DDCS were fitted to a Legendre polynomial expansion as a function of the ejection angle. Platzman plot analysis was carried out on the energy distributions determined from the fit coefficients. The total ionization cross sections at these primary energies were deduced from this plot. An autoionization feature at 2.3 eV was observed for the first time in measurements of this nature and has been assigned as due to a Rydberg state converging to the B 2 Σ/sub u/ + ionic state which decays to the X 2 Σ/sub g/ + ground state of N 2 + . An analysis of the autoionization lines observed in the present work in the range 0.4--2.5 eV is also presented

Triplet excited States as a source of relevant (bio)chemical information.

Science.gov (United States)

Jiménez, M Consuelo; Miranda, Miguel A

2014-01-01

The properties of triplet excited states are markedly medium-dependent, which turns this species into valuable tools for investigating the microenvironments existing in protein binding pockets. Monitoring of the triplet excited state behavior of drugs within transport proteins (serum albumins and α1-acid glycoproteins) by laser flash photolysis constitutes a valuable source of information on the strength of interaction, conformational freedom and protection from oxygen or other external quenchers. With proteins, formation of spatially confined triplet excited states is favored over competitive processes affording ionic species. Remarkably, under aerobic atmosphere, the triplet decay of drug@protein complexes is dramatically longer than in bulk solution. This offers a convenient dynamic range for assignment of different triplet populations or for stereochemical discrimination. In this review, selected examples of the application of the laser flash photolysis technique are described, including drug distribution between the bulk solution and the protein cavities, or between two types of proteins, detection of drug-drug interactions inside proteins, and enzyme-like activity processes mediated by proteins. Finally, protein encapsulation can also modify the photoreactivity of the guest. This is illustrated by presenting an example of retarded photooxidation.

Adult education and the State: Gramsci, the historical materialist tradition and relevant others

Directory of Open Access Journals (Sweden)

Leona M. English

2012-09-01

Full Text Available This paper focuses on the relationship between adult education and the State within the context of hegemonic globalization and the all pervasive neoliberal ideology. It draws from a variety of sources and provides an overview of discussions concerning the State giving pride of place to the Historical Materialist tradition in the area. Using a Gramscian perspective, it argues that contrary to the widespread mantra that the state has receded into the background in this era of globalization, we argue that the State remains ever so present in this context and, if anything, remains central to the Neoliberal project.

State of the States 2009. Renewable Energy Development and the Role of Policy

Energy Technology Data Exchange (ETDEWEB)

Doris, Elizabeth [National Renewable Energy Lab. (NREL), Golden, CO (United States); McLaren, Joyce [National Renewable Energy Lab. (NREL), Golden, CO (United States); Healey, Victoria [National Renewable Energy Lab. (NREL), Golden, CO (United States); Hockett, Stephen [National Renewable Energy Lab. (NREL), Golden, CO (United States)

2009-10-01

This report tracks the progress of U.S. renewable energy development at the state level, with metrics on development status and reviews of relevant policies. The analysis offers state-by-state policy suggestions and develops performance-based evaluation metrics to accelerate and improve renewable energy development.

Polarization-dependent spectra in the photoassociative ionization of cold atoms in a bright sodium beam

International Nuclear Information System (INIS)

Ramirez-Serrano, Jaime; DeGraffenreid, William; Weiner, John

2002-01-01

We report measurements of cold photoassociative ionization (PAI) spectra obtained from collisions within a slow, bright Na atomic beam. A high-brightness atom flux, obtained by optical cooling and focusing of the atom beam, permits a high degree of alignment and orientation of binary collisions with respect to the laboratory atom-beam axis. The results reveal features of PAI spectra not accessible in conventional magneto-optical trap studies. We take advantage of this high degree of alignment to selectively excite autoionizing doubly excited states of specific symmetry

Orbital angular momentum exchange in post-collision interaction

International Nuclear Information System (INIS)

van der Burgt, P.J.M.; van Eck, J.; Heideman, H.G.M.

1985-01-01

The authors study the exchange of orbital angular mementum between the scattered and the ejected electron. The angular distribution of electrons ejected by the He (2s 2 ) 2 S autoionizing state after its excitation via the He (2s2p 2 ) 2 D resonance is measured. Taking into accout interference with electrons from the direct ionization of helium, the authors are able to show that the measured anisotropic angular distribution is the result of an orbital angular momentum exchange during the post-collision interaction

Effect of couplings in the resonance continuum

International Nuclear Information System (INIS)

Royal, J; Larson, A; Orel, A E

2004-01-01

Electronic coupling of two or more resonances via the electron scattering continuum is investigated. The effect of this coupling as a function of the resonance curves and autoionization widths is investigated, and the conditions for the maximum effect are determined. The theory is applied to two physical problems, the product state distribution produced by the dissociative recombination of electrons with HeH + and a one-dimensional model for ion-pair production resulting from electron collisions with H + 3 . It is found that the coupling does not affect the product state distribution in HeH + but produces a significant effect in the H + 3 model

British Literature: Increasing Relevancy for High School Seniors through Multicultural Augmentation.

Science.gov (United States)

Kirkland, Nancy C.

A practicum aimed to increase the relevancy (to the ethnically diverse students of contemporary classrooms) of the regular high school senior English course in British literature and composition by expanding the curriculum to include selections from countries (other than the United States) influenced by the British Colonial Empire. Using a…

The six quark s-wave state and its relevance for the NN system

International Nuclear Information System (INIS)

Hoegaasen, H.

The lowest lying six quark states are discussed by extrapolating the spectroscopic knowledge we have from the well known three quark sector. It is shown how the mixing of a six quark state with a proton-neutron state forming the deuteron can correlate the experimental data on the electromagnetic form-factor, the production of spectator isobars in exclusive reactions, and the spatial wave-function of the Δ isobar in the deuteron. (Auth.)

New Mexico state information handbook: formerly utilized sites remedial action program

Energy Technology Data Exchange (ETDEWEB)

None

2014-12-31

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of New Mexico. It contains a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations.

New York state information handbook formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1980-01-01

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying our the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of New York. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations

New Mexico state information handbook: formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1980-01-01

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of New Mexico. It contains a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations

New Mexico state information handbook formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1980-01-01

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Informaion Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of New Mexico. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations

New York state information handbook: formerly utilized sites remedial action program

International Nuclear Information System (INIS)

1980-01-01

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of New York. It contains a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations

New York state information handbook formerly utilized sites remedial action program

Energy Technology Data Exchange (ETDEWEB)

None

1980-12-31

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying our the Formerly Utilized Sites Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of New York. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations.

New Mexico state information handbook formerly utilized sites remedial action program

Energy Technology Data Exchange (ETDEWEB)

None

1980-12-31

This volume is one of a series produced under contract with the DOE, by Politech Corporation to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Formerly Utilized Sites Remedial Action Program. This Informaion Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the State of New Mexico. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations.

Joint Concept Correlation and Feature-Concept Relevance Learning for Multilabel Classification.

Science.gov (United States)

Zhao, Xiaowei; Ma, Zhigang; Li, Zhi; Li, Zhihui

2018-02-01

In recent years, multilabel classification has attracted significant attention in multimedia annotation. However, most of the multilabel classification methods focus only on the inherent correlations existing among multiple labels and concepts and ignore the relevance between features and the target concepts. To obtain more robust multilabel classification results, we propose a new multilabel classification method aiming to capture the correlations among multiple concepts by leveraging hypergraph that is proved to be beneficial for relational learning. Moreover, we consider mining feature-concept relevance, which is often overlooked by many multilabel learning algorithms. To better show the feature-concept relevance, we impose a sparsity constraint on the proposed method. We compare the proposed method with several other multilabel classification methods and evaluate the classification performance by mean average precision on several data sets. The experimental results show that the proposed method outperforms the state-of-the-art methods.

Predictors of cognitive impairment assessed by Mini Mental State Examination in community-dwelling older adults: relevance of the step test.

Science.gov (United States)

Muscari, Antonio; Spiller, Ilaria; Bianchi, Giampaolo; Fabbri, Elisa; Forti, Paola; Magalotti, Donatella; Pandolfi, Paolo; Zoli, Marco

2018-07-15

Several predictors of cognitive impairment assessed by Mini Mental State Examination (MMSE) have previously been identified. However, which predictors are the most relevant and what is their effect on MMSE categories remains unclear. Cross-sectional and longitudinal study using data from 1116 older adults (72.6 ± 5.6 years, 579 female), 350 of whom were followed for 7 years. At baseline, the following variables were collected: personal data, marital status, occupation, anthropometric measures, risk factors, previous cardiovascular events, self-rated health and physical activity during the last week. Furthermore, routine laboratory tests, abdominal echography and a step test (with measurement of the time needed to ascend and descend two steps 20 times) were performed. The associations of these variables with cross-sectional cognitive deficit (MMSE cognitive decline (decrease of MMSE score over 7 years of follow-up) were investigated using logistic regression models. Cross-sectional cognitive deficit was independently associated with school education ≤ 5 years, prolonged step test duration, having been blue collar or housewife (P ≤ 0.0001 for all) and, with lower significance, with advanced age, previous stroke and poor recent physical activity (P cognitive decline was mainly associated with step test duration (P = 0.0001) and diastolic blood pressure (P = 0.0002). The MMSE categories mostly associated with step test duration were orientation, attention, calculation and language, while memory appeared to be poorly or not affected. In our cohort of older adults, step test duration was the most relevant predictor of cognitive impairment. Copyright © 2018 Elsevier Inc. All rights reserved.

Photoionization studies with molecular beams

Energy Technology Data Exchange (ETDEWEB)

Ng, C.Y.

1976-09-01

A molecular beam photoionization apparatus which combines the advantages of both the molecular beam method with photoionization mass spectrometry has been designed and constructed for carrying out some unique photoionization experiments. Rotational cooling during the supersonic expansion has resulted in high resolution photoionization efficiency curves for NO, ICl, C/sub 2/H/sub 2/ and CH/sub 3/I. The analysis of these spectra has yielded ionization potentials for these molecules to an accuracy of +- 3 MeV. Detailed autoionization structures were also resolved. This allows the investigation of the selection rules for autoionization, and the identification of the Rydberg series which converge to the excited states of the molecular ions. The degree of relaxation for thermally populated excited states has been examined using NO and ICl as examples. As a result of adiabatic cooling, a small percentage of dimers is also formed during the expansion. The photoionization efficiency curves for (NO)/sub 2/, ArICl, Ar/sub 2/, Kr/sub 2/ and Xe/sub 2/ have been obtained near the thresholds. Using the known dissociation energies of the (NO)/sub 2/, Ar/sub 2/, Kr/sub 2/ and Xe/sub 2/ van der Waals molecules, the corresponding dissociation energies for NO-NO/sup +/, Ar/sub 2//sup +/, Kr/sub 2//sup +/, and Xe/sub 2//sup +/ have been determined. The ionization mechanisms for this class of molecules are examined and discussed.

Measuring Teacher Dispositions: Identifying Workplace Personality Traits Most Relevant to Teaching Professionals

Science.gov (United States)

Yao, Yuankun; Pagnani, Alexander; Thomas, Matt; Abellan-Pagnani, Luisa; Brown, Terrell; Buchanan, Dawna Lisa

2017-01-01

What personality traits represent dispositions most relevant to teaching professionals? Could an instrument reflecting work personality traits for a wide variety of professions provide a valid assessment of dispositions for teacher candidates? This study analyzed the internal structure of a state mandated dispositions assessment that was adapted…

The photoabsorption of Eu, Eu{sup +} and Eu{sup 2+} in the vicinity of 4 Th thresholds

Energy Technology Data Exchange (ETDEWEB)

Amusia, M.Ya.; Chernysheva, L.V. E-mail: larissa.chernysheva@pop.ioffe.rssi.ru; Ivanov, V.K

2000-08-01

The results of calculations of the total and partial photoionisation cross-sections of neutral Europium and its ions in the photon energy range from the threshold up to 270 eV are presented. The calculations were performed within the multi-channel Spin-Polarized Random Phase Approximation with Exchange. The main attention is given to the giant autoionizing resonance associated with the 4 Th {yields} 4 f discrete transition to vacant states in the 4f{sup 7} subshell. The comparisons with experimental data obtained recently and the results of previous calculations are made.

The photoabsorption of Eu, Eu+ and Eu2+ in the vicinity of 4 Th thresholds

International Nuclear Information System (INIS)

Amusia, M.Ya.; Chernysheva, L.V.; Ivanov, V.K.

2000-01-01

The results of calculations of the total and partial photoionisation cross-sections of neutral Europium and its ions in the photon energy range from the threshold up to 270 eV are presented. The calculations were performed within the multi-channel Spin-Polarized Random Phase Approximation with Exchange. The main attention is given to the giant autoionizing resonance associated with the 4 Th → 4 f discrete transition to vacant states in the 4f 7 subshell. The comparisons with experimental data obtained recently and the results of previous calculations are made.

Study of a high and low pressure plasma produced in a He-N2 mixture: application to spontaneous emissions by radiative collisions

International Nuclear Information System (INIS)

Marcum, S.D.

1983-01-01

This thesis is centered on the study of the energy transfer from helium metastable atoms to ground state nitrogen molecules by the process of radiative collisions. Experimental techniques employed include the analysis of spontaneous emission from the reaction: He(2 3 S)+N 2 (X,v=0) → He(1 1 S)+(N 2 sup(R)(B,v'=4,5) → N 2 sup(R)(X,v'')+hω), where R indicates highly excited nitrogen Rydberg states. As the lower level Rydberg states are autoionizing, the net effect of the radiative collision is identical that of Penning ionization where the Rydberg to states are intermediates. The results of this study lend support to the validity of a radiative collision based laser amplifier model proposed in the thesis [fr

A Bridge between Two Cultures: Uncovering the Chemistry Concepts Relevant to the Nursing Clinical Practice

Science.gov (United States)

Brown, Corina E.; Henry, Melissa L. M.; Barbera, Jack; Hyslop, Richard M.

2012-01-01

This study focused on the undergraduate course that covers basic topics in general, organic, and biological (GOB) chemistry at a mid-sized state university in the western United States. The central objective of the research was to identify the main topics of GOB chemistry relevant to the clinical practice of nursing. The collection of data was…

Making Deferred Taxes Relevant

NARCIS (Netherlands)

Brouwer, Arjan; Naarding, Ewout

2018-01-01

We analyse the conceptual problems in current accounting for deferred taxes and provide solutions derived from the literature in order to make International Financial Reporting Standards (IFRS) deferred tax numbers value-relevant. In our view, the empirical results concerning the value relevance of

Essays on the relevance and use of dirty surplus accounting flows in Europe

NARCIS (Netherlands)

Wang, Y.

2006-01-01

This thesis intends to add empirical evidence to a recently heavily debated regulatory issue, the necessity of promoting a clean surplus income statement. I document the magnitude, and assess the relevance of dirty surplus accounting flows in European member states. In particular, this thesis

Resonant satellite transitions in argon

International Nuclear Information System (INIS)

Samson, J.A.R.; Lee Eunmee; Chung, Y.

1990-01-01

The production of specific Ar + satellite states has been studied with synchrotron radiation at wavelengths between 300 and 350 A with an effective energy resolution of 20 meV. The specific states studied were the ( 3 P)4p( 2 P 3/2 ), ( 1 D)4p( 2 F 7/2 ), and ( 1 D)4p( 2 P 1/2 ) states. The fluorescent radiation emitted from these excited ionic states was measured at 4766, 4611, and 4133 A by the use of narrow band interference filters. The variation of the fluorescence intensity was measured as a function of wavelength. This provided a measure of the relative cross section for production of the satellite states. Each satellite state was found to be completely dominated by autoionization of the neutral doubly excited states (3s 2 3p 4 )nl, n'l' found in this spectral region. (orig.)

Electron-impact ionization of Pbq+ ions for q=1-10

International Nuclear Information System (INIS)

Loch, S.D.; Ludlow, J.A.; Pindzola, M.S.; Scheuermann, F.; Kramer, K.; Fabian, B.; Huber, K.; Salzborn, E.

2005-01-01

Theoretical calculations and experimental crossed-beam measurements are compared for electron-impact single ionization of Pb q+ ions for q=1-10. We compare with two main theoretical methods. First, we check against configuration-average distorted-wave calculations, which include both direct-ionization and indirect excitation-autoionization contributions. Second, for ion stages Pb + through to Pb 5+ , we calculate the dominant excitation-autoionization channels using level-resolved distorted-wave theory to evaluate the excitation cross sections. We find that for ion stages Pb + , Pb 2+ , and Pb 3+ , distorted-wave theory significantly overestimates the total-ionization cross section, due to an overestimation of the direct-ionization cross section from the 5d subshell. For ion stages Pb 4+ through to Pb 10+ there is good agreement between theory and experiment. We find evidence for significant metastable fraction in the ion beam of the experiment for ion stages Pb 2+ , Pb 3+ , Pb 4+ , Pb 5+ , and Pb 6+ . For ion stage Pb 3+ we find that the level-resolved distorted-wave calculation of the excitation autoionization results in a slight reduction of the configuration-average theoretical results, due to splitting of levels within the autoionizing configurations. We also investigate two semiempirical methods of calculating the direct-ionization cross sections: namely, the Lotz method and the binary encounter Bethe method. We find that both methods provide results which are significantly lower than the distorted-wave method for the 5d-subshell direct ionization of Pb + , Pb 2+ , and Pb 3+ . For the higher ion stages, both methods are lower than the distorted-wave direct-ionization cross-section results, trending towards the distorted-wave results as the ion stage increases

One- and two-electron processes in collisions between hydrogen molecules and slow highly charged ions

International Nuclear Information System (INIS)

Wells, E.; Carnes, K.D.; Tawara, H.; Ali, R.; Sidky, Emil Y.; Illescas, Clara; Ben-Itzhak, I.

2005-01-01

A coincidence time-of-flight technique coupled with projectile charge state analysis was used to study electron capture in collisions between slow highly charged ions and hydrogen molecules. We found single electron capture with no target excitation to be the dominant process for both C 6+ projectiles at a velocity of 0.8 atomic units and Ar 11+ projectiles at v 0.63 a.u. Double electron capture and transfer excitation, however, were found to be comparable and occur about 30% of the time relative to single capture. Most projectiles (96%) auto-ionize quickly following double capture into doubly excited states. The data are compared to classical and quantum mechanical model calculations

Availability of safety relevant specialists for operation and supervision of nuclear power plants in the new EU member states; Verfuegbarkeit sicherheitsrelevanter Fachkraefte fuer Betrieb und Aufsicht von Kernkraftwerken in den EU-Mitgliedslaendern

Energy Technology Data Exchange (ETDEWEB)

Glaubitz, Dietmar; Dagbjartsson, Sigurdur; Wenzel, Herbert [Fichtner Management Beratung AG, Stuttgart (Germany)

2009-07-01

On behalf of the European commission the availability of safety relevant specialists for operation and supervision of nuclear power plants in the new EU member states was investigated. Based on information of the NPP operators and the authorities in the EU member states the authors studied the age distribution of the skilled personnel, the possibilities for long-term availability of an adequate number of experts, securing of qualification and the contribution of universities for competence preservation. Recommendations concern the cooperation of universities and NOO operators in the fields of education, training and systematic programs at the key players (training on the job).

Autoionization study of the Argon 2p satellites excited near the argon 2s threshold

International Nuclear Information System (INIS)

Wang, H.; Glans, P.; Hemmers, O.

1997-01-01

The dynamics of near-threshold photoionization is a complex phenomenon in which the many-electron character of the wavefunctions plays an important role. According to generalized time-independent resonant scattering theory, the transition matrix element from an initial state to a final state is the summation of the amplitudes of direct photoionization and an indirect term in which intermediate states are involved and the resonant behavior is embedded. Studies of the interference effects of intermediate states have been explored in the cases where the direct term is negligible. In the present work, electron time-of-flight spectra of the Ar 2p satellites were measured at two angles (magic and 0 degrees) in the dipole plane with the exciting photon energy tuned in the vicinity of the Ar 2s threshold. For excitation far below or above the 2s threshold, the 2p satellites spectrum is dominated by 3p to np shakeup contributions upon the ionization of a 2p electron

Autoionization study of the Argon 2p satellites excited near the argon 2s threshold

Energy Technology Data Exchange (ETDEWEB)

Wang, H.; Glans, P.; Hemmers, O. [Univ. of Nevada, Las Vegas, NV (United States)] [and others

1997-04-01

The dynamics of near-threshold photoionization is a complex phenomenon in which the many-electron character of the wavefunctions plays an important role. According to generalized time-independent resonant scattering theory, the transition matrix element from an initial state to a final state is the summation of the amplitudes of direct photoionization and an indirect term in which intermediate states are involved and the resonant behavior is embedded. Studies of the interference effects of intermediate states have been explored in the cases where the direct term is negligible. In the present work, electron time-of-flight spectra of the Ar 2p satellites were measured at two angles (magic and 0{degrees}) in the dipole plane with the exciting photon energy tuned in the vicinity of the Ar 2s threshold. For excitation far below or above the 2s threshold, the 2p satellites spectrum is dominated by 3p to np shakeup contributions upon the ionization of a 2p electron.

Wigner-Eisenbud-Smith photoionization time delay due to autoioinization resonances

Science.gov (United States)

Deshmukh, P. C.; Kumar, A.; Varma, H. R.; Banerjee, S.; Manson, Steven T.; Dolmatov, V. K.; Kheifets, A. S.

2018-03-01

An empirical ansatz for the complex photoionization amplitude and Wigner-Eisenbud-Smith time delay in the vicinity of a Fano autoionization resonance are proposed to evaluate and interpret the time delay in the resonant region. The utility of this expression is evaluated in comparison with accurate numerical calculations employing the ab initio relativistic random phase approximation and relativistic multichannel quantum defect theory. The indisputably good qualitative agreement (and semiquantitative agreement) between corresponding results of the proposed model and results produced by the ab initio theories proves the usability of the model. In addition, the phenomenology of the time delay in the vicinity of multichannel autoionizing resonances is detailed.

Collecting Safeguards Relevant Trade Information: The IAEA Procurement Outreach Programme

International Nuclear Information System (INIS)

Schot, P.; El Gebaly, A.; Tarvainen, M.

2010-01-01

The increasing awareness of activities of transnational procurement networks to covertly acquire sensitive nuclear related dual use equipment prompted an evolution of safeguards methodologies. One of the responses to this challenge by the Department of Safeguards in the IAEA was to establish the Trade and Technology Unit (TTA) in November 2004 to analyse and report on these covert nuclear related trade activities. To obtain information relevant to this analysis, TTA is engaging States that might be willing to provide this information to the Secretariat on a voluntary basis. This paper will give an overview of current activities, sum up the results achieved and discuss suggestions to further improve this programme made by Member States. (author)

Spatially Compact Neural Clusters in the Dorsal Striatum Encode Locomotion Relevant Information.

Science.gov (United States)

Barbera, Giovanni; Liang, Bo; Zhang, Lifeng; Gerfen, Charles R; Culurciello, Eugenio; Chen, Rong; Li, Yun; Lin, Da-Ting

2016-10-05

An influential striatal model postulates that neural activities in the striatal direct and indirect pathways promote and inhibit movement, respectively. Normal behavior requires coordinated activity in the direct pathway to facilitate intended locomotion and indirect pathway to inhibit unwanted locomotion. In this striatal model, neuronal population activity is assumed to encode locomotion relevant information. Here, we propose a novel encoding mechanism for the dorsal striatum. We identified spatially compact neural clusters in both the direct and indirect pathways. Detailed characterization revealed similar cluster organization between the direct and indirect pathways, and cluster activities from both pathways were correlated with mouse locomotion velocities. Using machine-learning algorithms, cluster activities could be used to decode locomotion relevant behavioral states and locomotion velocity. We propose that neural clusters in the dorsal striatum encode locomotion relevant information and that coordinated activities of direct and indirect pathway neural clusters are required for normal striatal controlled behavior. VIDEO ABSTRACT. Published by Elsevier Inc.

The relevance of "non-relevant metabolites" from plant protection products (PPPs) for drinking water: the German view.

Science.gov (United States)

Dieter, Hermann H

2010-03-01

"Non-relevant metabolites" are those degradation products of plant protection products (PPPs), which are devoid of the targeted toxicities of the PPP and devoid of genotoxicity. Most often, "non-relevant metabolites" have a high affinity to the aquatic environment, are very mobile within this environment, and, usually, are also persistent. Therefore, from the point of drinking water hygiene, they must be characterized as "relevant for drinking water" like many other hydrophilic/polar environmental contaminants of different origins. "Non-relevant metabolites" may therefore penetrate to water sources used for abstraction of drinking water and may thus ultimately be present in drinking water. The presence of "non-relevant metabolites" and similar trace compounds in the water cycle may endanger drinking water quality on a long-term scale. During oxidative drinking water treatment, "non-relevant metabolites" may also serve as the starting material for toxicologically relevant transformation products similar to processes observed by drinking water disinfection with chlorine. This hypothesis was recently confirmed by the detection of the formation of N-nitroso-dimethylamine from ozone and dimethylsulfamide, a "non-relevant metabolite" of the fungicide tolylfluanide. In order to keep drinking water preferably free of "non-relevant metabolites", the German drinking water advisory board of the Federal Ministry of Health supports limiting their penetration into raw and drinking water to the functionally (agriculturally) unavoidable extent. On this background, the German Federal Environment Agency (UBA) recently has recommended two health related indication values (HRIV) to assess "non-relevant metabolites" from the view of drinking water hygiene. Considering the sometimes incomplete toxicological data base for some "non-relevant metabolites", HRIV also have the role of health related precautionary values. Depending on the completeness and quality of the toxicological

Kurds, states and tribes

NARCIS (Netherlands)

Bruinessen, M.M. van

2002-01-01

At most times, Kurdish society has existed at the periphery of, and functioned as a buffer between, two or more neighbouring states. From c. 1500 until the First World War, the relevant states were the Ottoman Empire in the west and Safavid, later Qajar Iran in the east (with Russia and the

The Limits to Relevance

Science.gov (United States)

Averill, M.; Briggle, A.

2006-12-01

Science policy and knowledge production lately have taken a pragmatic turn. Funding agencies increasingly are requiring scientists to explain the relevance of their work to society. This stems in part from mounting critiques of the "linear model" of knowledge production in which scientists operating according to their own interests or disciplinary standards are presumed to automatically produce knowledge that is of relevance outside of their narrow communities. Many contend that funded scientific research should be linked more directly to societal goals, which implies a shift in the kind of research that will be funded. While both authors support the concept of useful science, we question the exact meaning of "relevance" and the wisdom of allowing it to control research agendas. We hope to contribute to the conversation by thinking more critically about the meaning and limits of the term "relevance" and the trade-offs implicit in a narrow utilitarian approach. The paper will consider which interests tend to be privileged by an emphasis on relevance and address issues such as whose goals ought to be pursued and why, and who gets to decide. We will consider how relevance, narrowly construed, may actually limit the ultimate utility of scientific research. The paper also will reflect on the worthiness of research goals themselves and their relationship to a broader view of what it means to be human and to live in society. Just as there is more to being human than the pragmatic demands of daily life, there is more at issue with knowledge production than finding the most efficient ways to satisfy consumer preferences or fix near-term policy problems. We will conclude by calling for a balanced approach to funding research that addresses society's most pressing needs but also supports innovative research with less immediately apparent application.

Nostalgia's place among self-relevant emotions.

Science.gov (United States)

van Tilburg, Wijnand A P; Wildschut, Tim; Sedikides, Constantine

2017-07-24

How is nostalgia positioned among self-relevant emotions? We tested, in six studies, which self-relevant emotions are perceived as most similar versus least similar to nostalgia, and what underlies these similarities/differences. We used multidimensional scaling to chart the perceived similarities/differences among self-relevant emotions, resulting in two-dimensional models. The results were revealing. Nostalgia is positioned among self-relevant emotions characterised by positive valence, an approach orientation, and low arousal. Nostalgia most resembles pride and self-compassion, and least resembles embarrassment and shame. Our research pioneered the integration of nostalgia among self-relevant emotions.

Double photoexcitation of helium in a strong dc electric field

International Nuclear Information System (INIS)

Harries, James R.; Sullivan, James P.; Sternberg, James B.; Obara, Satoshi; Suzuki, Tadayuki; Azuma, Yoshiro; Hammond, Peter; Bozek, John; Berrah, Nora; Halka, Monica

2003-01-01

We report the first experimental measurements of the effect of an applied field on the photoexcitation and autoionization of doubly excited states of helium. Ground-state photoionization spectra have been measured in the region below the He + (N=2) threshold with static electric fields of up to 84.4 kV/cm across the interaction region. The results are compared to the theoretical calculations of Chung et al. [J. Phys. B10.1088/0953-4075/34/2/304 34, 165 (2001)], which are the only calculations available in this regime. Transitions to several states in the N=2, n=6 manifold are assigned, and a wealth of new structure is observed. Our data show that many more series are mixed in by the field than those predicted by theory

Vulcan: A steady-state tokamak for reactor-relevant plasma–material interaction science

International Nuclear Information System (INIS)

Olynyk, G.M.; Hartwig, Z.S.; Whyte, D.G.; Barnard, H.S.; Bonoli, P.T.; Bromberg, L.; Garrett, M.L.; Haakonsen, C.B.; Mumgaard, R.T.; Podpaly, Y.A.

2012-01-01

Highlights: ► A new scaling for obtaining reactor similarity in the divertor of scaled tokamaks. ► Conceptual design for a tokamak (“Vulcan”) to implement this new scaling. ► Demountable superconducting coils and compact neutron shielding. ► Helium-cooled high-temperature vacuum vessel and first wall. ► High-field-side lower hybrid current drive for non-inductive operation. - Abstract: An economically viable magnetic-confinement fusion reactor will require steady-state operation and high areal power density for sufficient energy output, and elevated wall/blanket temperatures for efficient energy conversion. These three requirements frame, and couple to, the challenge of plasma–material interaction (PMI) for fusion energy sciences. Present and planned tokamaks are not designed to simultaneously meet these criteria. A new and expanded set of dimensionless figures of merit for PMI have been developed. The key feature of the scaling is that the power flux across the last closed flux surface P/S ≃ 1 MW m −2 is to be held constant, while scaling the core volume-averaged density weakly with major radius, n ∼ R −2/7 . While complete similarity is not possible, this new “P/S” or “PMI” scaling provides similarity for the most critical reactor PMI issues, compatible with sufficient current drive efficiency for non-inductive steady-state core scenarios. A conceptual design is developed for Vulcan, a compact steady-state deuterium main-ion tokamak which implements the P/S scaling rules. A zero-dimensional core analysis is used to determine R = 1.2 m, with a conventional reactor aspect ratio R/a = 4.0, as the minimum feasible size for Vulcan. Scoping studies of innovative fusion technologies to support the Vulcan PMI mission were carried out for three critical areas: a high-temperature, helium-cooled vacuum vessel and divertor design; a demountable superconducting toroidal field magnet system; and a steady-state lower hybrid current drive system

An Analysis of State Music Education Certification and Licensure Practices in the United States

Science.gov (United States)

May, Brittany Nixon; Willie, Karen; Worthen, Cherilyn; Pehrson, Allyssa

2017-01-01

Teacher certification and licensure practices for music educators vary by state. Enhancing music teacher educator knowledge of state music education certification and licensure practices can inform music teacher preparation and improve future music teacher quality. The purpose of this study was to compile relevant information for music educators…

Prioritising the relevant information for learning and decision making within orbital and ventromedial prefrontal cortex.

Science.gov (United States)

Walton, Mark E; Chau, Bolton K H; Kennerley, Steven W

2015-02-01

Our environment and internal states are frequently complex, ambiguous and dynamic, meaning we need to have selection mechanisms to ensure we are basing our decisions on currently relevant information. Here, we review evidence that orbitofrontal (OFC) and ventromedial prefrontal cortex (VMPFC) play conserved, critical but distinct roles in this process. While OFC may use specific sensory associations to enhance task-relevant information, particularly in the context of learning, VMPFC plays a role in ensuring irrelevant information does not impinge on the decision in hand.

Relevance theory: pragmatics and cognition.

Science.gov (United States)

Wearing, Catherine J

2015-01-01

Relevance Theory is a cognitively oriented theory of pragmatics, i.e., a theory of language use. It builds on the seminal work of H.P. Grice(1) to develop a pragmatic theory which is at once philosophically sensitive and empirically plausible (in both psychological and evolutionary terms). This entry reviews the central commitments and chief contributions of Relevance Theory, including its Gricean commitment to the centrality of intention-reading and inference in communication; the cognitively grounded notion of relevance which provides the mechanism for explaining pragmatic interpretation as an intention-driven, inferential process; and several key applications of the theory (lexical pragmatics, metaphor and irony, procedural meaning). Relevance Theory is an important contribution to our understanding of the pragmatics of communication. © 2014 John Wiley & Sons, Ltd.

Relevant Subspace Clustering

DEFF Research Database (Denmark)

Müller, Emmanuel; Assent, Ira; Günnemann, Stephan

2009-01-01

Subspace clustering aims at detecting clusters in any subspace projection of a high dimensional space. As the number of possible subspace projections is exponential in the number of dimensions, the result is often tremendously large. Recent approaches fail to reduce results to relevant subspace...... clusters. Their results are typically highly redundant, i.e. many clusters are detected multiple times in several projections. In this work, we propose a novel model for relevant subspace clustering (RESCU). We present a global optimization which detects the most interesting non-redundant subspace clusters...... achieves top clustering quality while competing approaches show greatly varying performance....

Molecular frame photoemission: a probe of electronic/nuclear photo-dynamics and polarization state of the ionizing light

International Nuclear Information System (INIS)

Veyrinas, Kevin

2015-01-01

This is thesis is dedicated to the study and the use of the remarkable properties of the molecular frame photoelectron angular distribution (MFPAD). This observable is a very sensitive probe of both the photoionization (PI) processes in small molecules, through the determination of the magnitudes and relative phases of the dipole matrix elements, and the polarization state of the ionizing light, which is entirely encoded in the MFPAD in terms of the Stokes parameters (s1, s2, s3). MFPAD measurements take advantage of dissociative photoionization (DPI) processes by combining an electron-ion 3D momentum spectroscopy technique with the use of different radiation facilities: SOLEIL synchrotron (DESIRS and PLEIADES beamlines) and the XUV PLFA beamline (SLIC, LIDyL Attophysics group, CEA Saclay) based on the interaction of a strong laser field with a gaseous target called high harmonic generation (HHG). The first part of the thesis is devoted to the complete characterization of the polarization state of an incoming radiation. In this context, an original 'molecular polarimetry' method is introduced and demonstrated by comparison with a VUV optical polarimeter available on the DESIRS beamline. Using this method to determine the full polarization ellipse of HHG radiation generated in different conditions on the XUV PLFA facility leads to original results that include the challenging disentanglement of the circular and unpolarized components of the studied radiation. The second part deals with the study of DPI of the H 2 , D 2 and HD molecules induced by circularly polarized light at resonance with the doubly excited states Q1 and Q2. In this energy region (30-35 eV) where direct ionization, autoionization and dissociation compete on a femtosecond timescale, the photonic excitation gives rise to complex ultrafast electronic and nuclear coupled dynamics. The remarkable asymmetries observed in the circular dichroism in the molecular frame, compared to quantum

THE MODERNISATION OF STATE AID CONTROL AND ITS OBJECTIVES: CLARITY, RELEVANCE, EFFECTIVENESS

Directory of Open Access Journals (Sweden)

Vittorio Di Bucci

2014-12-01

Full Text Available On 8 May 2012, the Commission adopted its Communication on State aid modernisation. Two years later, most elements of the reform have come into force. This was the most comprehensive overhaul in the history of State aid control. First, the Council quickly agreed to amendments of the Enabling Regulation, enlarging the scope of measures that can be exempted from notification, and of the Procedural Regulation, enhancing the investigative powers of the Commission and introducing the possibility for the Commission to intervene in national litigation. Second, the Commission issued new versions, based on a common structure, of its horizontal guidelines and frameworks: regional aid, risk finance, environmental protection with the addition of energy, research and development and innovation, rescuing and restructuring of undertakings in difficulty, a new document concerning important projects of common European interest, and some important sectorial instruments (broadband, aviation. Third, the Commission adopted a new de minimis regulation and a new, comprehensive block exemption regulation, intended to cover the majority of national aid measures. Fourth, a new notice on the notion of aid, yet to be finally adopted, should provide interpretative guidance. The result of the exercise is a considerable clarification of the rules, an improvement of the procedural tools and a limitation of the obligation to notify State aid projects. In turn, this should allow the Commission to work more efficiently, to reduce the duration of its procedures and to focus on the most distortive measures.

VUV Fourier-Transform absorption study of the npπ1 Πu-, v, N ←X1 Σg+, v″ = 0,N″ transitions in D2

Science.gov (United States)

Glass-Maujean, M.; Jungen, Ch.; Dickenson, G. D.; Ubachs, W.; de Oliveira, N.; Joyeux, D.; Nahon, L.

2015-09-01

The DESIRS beamline of the SOLEIL synchrotron facility, equipped with a vacuum ultraviolet Fourier-Transform spectrometer has been used to measure Q (N″) (N -N″ = 0) absorption transitions of the D2 molecule. Some 212 Q-lines were assigned and their transition frequencies determined up to excitation energies of 137 000 cm-1 above the ground state, thereby extending the earlier work by various authors, and considerably improving the spectral accuracy (<0.1 cm-1). The assignments have been aided by first principles multichannel quantum defect theory (MQDT) calculations which also provide predictions of the autoionization widths of the upper levels.

The dielectronic satellites to the 2s-3p Ne-like krypton resonance lines

International Nuclear Information System (INIS)

Khakhalin, S.Ya.; Dyakin, V.M.; Faenov, A.Ya.; Fiedorowicz, H.; Bartnik, A.; Parys, P.; Nilsen, J.; Osterheld, A.

1994-01-01

We present an analysis of dielectronic satellite spectra of 2p 6 -2s2p 6 3p Ne-like krypton resonance lines. The satellite structure was registered with high (better than λ/Δλ > 3500) spectral resolution in the emission of a laser irradiated gas puff target. We perform an unambiguous identification of satellite lines caused by radiative transitions from autoionizing states of sodium-like krypton ions. A total of about 20 spectral features are identified, most of them for the first time. Very good agreement between the satellite structure calculations and experimental emission spectra is obtained. (orig.)

Charge-exchange-induced formation of hollow atoms in high-intensity laser-produced plasmas

Energy Technology Data Exchange (ETDEWEB)

Rosmej, F.B. [TU-Darmstadt, Institut fuer Kernphysik, Darmstadt (Germany); Faenov, A.Ya.; Pikuz, T.A.; Magunov, A.I.; Skobelev, I.Yu. [Multicharged Ions Spectra Data Center of VNIIFTRI, Mendeleevo (Russian Federation); Auguste, T.; D' Oliveira, P.; Hulin, S.; Monot, P. [Commissariat a lEnergie Atomique DSM/DRECAM/SPAM, Gif-Sur-Yvette Cedex (France); Andreev, N.E.; Chegotov, M.V.; Veisman, M.E. [High Energy Density Research Centre, Institute of High Temperatures of Russian Academy of Sciences, Moscow (Russian Federation)

1999-03-14

For the first time registration of high-resolution soft x-ray emission and atomic data calculations of hollow-atom dielectronic satellite spectra of highly charged nitrogen have been performed. Double-electron charge-exchange processes from excited states are proposed for the formation of autoionizing levels nln'l' in high-intensity laser-produced plasmas, when field-ionized ions penetrate into the residual gas. Good agreement is found between theory and experiment. Plasma spectroscopy with hollow ions is proposed and a temperature diagnostic for laser-produced plasmas in the long-lasting recombining regime is developed. (author). Letter-to-the-editor.

The dielectronic satellites to the 2s-3p Ne-like krypton resonance lines

Energy Technology Data Exchange (ETDEWEB)

Khakhalin, S.Ya. (MISDC, NPO ' ' VNIIFTRI' ' , Mendeleevo (Russian Federation)); Dyakin, V.M. (MISDC, NPO ' ' VNIIFTRI' ' , Mendeleevo (Russian Federation)); Faenov, A.Ya. (MISDC, NPO ' ' VNIIFTRI' ' , Mendeleevo (Russian Federation)); Fiedorowicz, H. (Inst. of Optoelectronics, Warsaw (Poland)); Bartnik, A. (Inst. of Optoelectronics, Warsaw (Poland)); Parys, P. (Inst. of Plasma Physics and Laser Microfusion, Warsaw (Poland)); Nilsen, J. (Lawrence Livermore National Lab., Livermore, CA (United States)); Osterheld, A. (Lawrence Livermore National Lab., Livermore, CA (United States))

1994-08-01

We present an analysis of dielectronic satellite spectra of 2p[sup 6]-2s2p[sup 6]3p Ne-like krypton resonance lines. The satellite structure was registered with high (better than [lambda]/[Delta][lambda] > 3500) spectral resolution in the emission of a laser irradiated gas puff target. We perform an unambiguous identification of satellite lines caused by radiative transitions from autoionizing states of sodium-like krypton ions. A total of about 20 spectral features are identified, most of them for the first time. Very good agreement between the satellite structure calculations and experimental emission spectra is obtained. (orig.).

Profiles of Dialogue for Relevance

Directory of Open Access Journals (Sweden)

Douglas Walton

2016-12-01

Full Text Available This paper uses argument diagrams, argumentation schemes, and some tools from formal argumentation systems developed in artificial intelligence to build a graph-theoretic model of relevance shown to be applicable (with some extensions as a practical method for helping a third party judge issues of relevance or irrelevance of an argument in real examples. Examples used to illustrate how the method works are drawn from disputes about relevance in natural language discourse, including a criminal trial and a parliamentary debate.

Science and the struggle for relevance

NARCIS (Netherlands)

Hessels, L.K.|info:eu-repo/dai/nl/304832863

2010-01-01

This thesis deals with struggles for relevance of university researchers, their efforts to make their work correspond with ruling standards of relevance and to influence these standards. Its general research question is: How to understand changes in the struggle for relevance of Dutch academic

Phase squeezed states

International Nuclear Information System (INIS)

Chizhov, A.V.; Paris, M.G.A.

1998-01-01

Phase squeezed states of a single mode radiation field have been introduced as eigenstates of a linear combination of lowering and raising operators. The explicit expression in the Fock basis has been obtained and some relevant properties have been illustrated. (author)

International Cooperation Among States in Globalized Era: The Decline of State Sovereignty

Directory of Open Access Journals (Sweden)

- Koesrianti

2013-09-01

Full Text Available This article discusses the national sovereignty and regionalism in the context of the membership of a state into regional economic organisations. It concludes that in nowadays-shrinking world the traditional concept of sovereignty is less relevant since states have suffered a loss in their sovereignty. It found that member states of regional economic organisations have to cede a degree of sovereignty, such as in the EU. This phenomenon however is not the case for NAFTA and AFTA.

Culturally Relevant Cyberbullying Prevention

OpenAIRE

Phillips, Gregory John

2017-01-01

In this action research study, I, along with a student intervention committee of 14 members, developed a cyberbullying intervention for a large urban high school on the west coast. This high school contained a predominantly African American student population. I aimed to discover culturally relevant cyberbullying prevention strategies for African American students. The intervention committee selected video safety messages featuring African American actors as the most culturally relevant cyber...

Doubly excited helium. From strong correlation to chaos

International Nuclear Information System (INIS)

Jiang, Yuhai

2006-03-01

In the present dissertation, the double excitation states of helium including the autoionization decay of these states were studied experimentally and theoretically in a broad energy region, which includes the transition from strong correlation below the low single ionization thresholds (SIT) to the region of quantum chaos at energies very close to the double-ionization threshold. Two kind of experiments were performed, namely total-ion-yield measurements with the aim to observe total cross sections (TCS) and electron time-of-flight (TOF) measurements to obtain partial cross sections (PCS) as well as angular distribution parameters (ADP). Both types of measurements were performed at the third generation synchrotron radiation facility BESSY II in Berlin. The TCSs were recorded up to the SIT I 15 , and they were found to be in in excellent agreement with state-of-the-art complex-rotation calculations performed recently by D. Delande. These experimental and theoretical data on the TCSs were analyzed in order to study quantum chaos in doubly excited helium, and interesting signatures of quantum chaos were found. The TOF technique allowed to measure PCSs and ADPs in the energy regions from I 5 to I 9 and I 7 , respectively. These experimental data provide a critical assessment of theoretical models that can be used to explore the dynamics of strong correlation as well as quantum chaos in helium. In the theoretical part of this dissertation, the n- and l-specific PCSs and ADPs below I 4 were calculated employing the R-matrix method. The present theoretical results agree well with a recent experimental study of l-specific PCSs below I 4 by J.R. Harries et al. An analysis of patterns in the PCSs and ADPs on the basis of the present experimental and theoretical l-specific data allowed to improve the present understanding of autoionization decay dynamics in this two-electron atom. (orig.)

New Jersey state information handbook: Formerly Utilized Sites Remedial Action Program

International Nuclear Information System (INIS)

1980-01-01

Under the implied authority of the Atomic Energy Act of 1954, as amended, radiological surveys and research work has been conducted to determine radiological conditions at former MED/AEC sites. As of this time, 31 sites in 13 states have been identified that require or may require remedial action. This volume is one of a series produced under contract with DOE, Office of Nuclear Waste Management, by POLITECH CORPORATION to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the state of New Jersey. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations. The loose-leaf format used in these volumes will allow the material to be updated periodically as the Remedial Action Program progresses

New Jersey state information handbook: Formerly Utilized Sites Remedial Action Program

Energy Technology Data Exchange (ETDEWEB)

None

1980-10-31

Under the implied authority of the Atomic Energy Act of 1954, as amended, radiological surveys and research work has been conducted to determine radiological conditions at former MED/AEC sites. As of this time, 31 sites in 13 states have been identified that require or may require remedial action. This volume is one of a series produced under contract with DOE, Office of Nuclear Waste Management, by POLITECH CORPORATION to develop a legislative and regulatory data base to assist the FUSRAP management in addressing the institutional and socioeconomic issues involved in carrying out the Remedial Action Program. This Information Handbook series contains information about all relevant government agencies at the Federal and state levels, the pertinent programs they administer, each affected state legislature, and current Federal and state legislative and regulatory initiatives. This volume is a compilation of information about the state of New Jersey. It contains: a description of the state executive branch structure; a summary of relevant state statutes and regulations; a description of the structure of the state legislature, identification of the officers and committee chairmen, and a summary of recent relevant legislative action; and the full text of relevant statutes and regulations. The loose-leaf format used in these volumes will allow the material to be updated periodically as the Remedial Action Program progresses.

Observation of dielectronic satellites in the K-spectrum of argon ions in plasma produced by femtosecond laser pulses

International Nuclear Information System (INIS)

Magunov, A.I.; Faenov, A.Ya.; Skobelev, I.Yu.; Pikuz, T.A.; Biemont, E.; Quinet, P.; Blasco, F.; Bonte, C.; Dorchies, F.; Caillaud, T.; Salin, F.; Stenz, C.

2002-01-01

The satellite structure of 1s2p 1,3 P 1 -1s 21 S 0 lines of the He-like argon ion in plasma produced by a 45-fs laser pulse in a gas-jet cluster target is measured with a high spectral resolution. Radiation transitions 2p → 1s from autoionizing states (AISs) are detected for ions ranging from Li-like to F-like. The spectrum observed is theoretically simulated with the use of the spectroscopic data for the AISs of multicharged ions obtained within the multiconfiguration relativistic Hartree-Fock method. Good agreement with experimental data is obtained when the main population channels of these states are taken into account for typical values of cluster-target plasma parameters

Kernel-Based Relevance Analysis with Enhanced Interpretability for Detection of Brain Activity Patterns

Directory of Open Access Journals (Sweden)

Andres M. Alvarez-Meza

2017-10-01

Full Text Available We introduce Enhanced Kernel-based Relevance Analysis (EKRA that aims to support the automatic identification of brain activity patterns using electroencephalographic recordings. EKRA is a data-driven strategy that incorporates two kernel functions to take advantage of the available joint information, associating neural responses to a given stimulus condition. Regarding this, a Centered Kernel Alignment functional is adjusted to learning the linear projection that best discriminates the input feature set, optimizing the required free parameters automatically. Our approach is carried out in two scenarios: (i feature selection by computing a relevance vector from extracted neural features to facilitating the physiological interpretation of a given brain activity task, and (ii enhanced feature selection to perform an additional transformation of relevant features aiming to improve the overall identification accuracy. Accordingly, we provide an alternative feature relevance analysis strategy that allows improving the system performance while favoring the data interpretability. For the validation purpose, EKRA is tested in two well-known tasks of brain activity: motor imagery discrimination and epileptic seizure detection. The obtained results show that the EKRA approach estimates a relevant representation space extracted from the provided supervised information, emphasizing the salient input features. As a result, our proposal outperforms the state-of-the-art methods regarding brain activity discrimination accuracy with the benefit of enhanced physiological interpretation about the task at hand.

4- states of 16O

International Nuclear Information System (INIS)

Barker, F.C.; Smith, R.; Morrison, I.; Amos, K.A.

1981-01-01

A three-state isospin-mixing model is fitted to available data on pion scattering and nucleon pickup relevant to the 4 - states of 16 O at 17.79, 18.98 and 19.80 MeV. An excellent fit to all data is obtained, and the state descriptions are shown to be consistent with inelastic proton scattering measurements. The 18.98 MeV state is predominantly 1p-1h T = 1, while the other two states have significant isospin mixing and 3p-3h admixtures

Evolutionary relevance facilitates visual information processing.

Science.gov (United States)

Jackson, Russell E; Calvillo, Dusti P

2013-11-03

Visual search of the environment is a fundamental human behavior that perceptual load affects powerfully. Previously investigated means for overcoming the inhibitions of high perceptual load, however, generalize poorly to real-world human behavior. We hypothesized that humans would process evolutionarily relevant stimuli more efficiently than evolutionarily novel stimuli, and evolutionary relevance would mitigate the repercussions of high perceptual load during visual search. Animacy is a significant component to evolutionary relevance of visual stimuli because perceiving animate entities is time-sensitive in ways that pose significant evolutionary consequences. Participants completing a visual search task located evolutionarily relevant and animate objects fastest and with the least impact of high perceptual load. Evolutionarily novel and inanimate objects were located slowest and with the highest impact of perceptual load. Evolutionary relevance may importantly affect everyday visual information processing.

Time-dependent reduced density matrix functional theory applied to laser-driven, correlated two-electron dynamics

Energy Technology Data Exchange (ETDEWEB)

Brics, Martins; Kapoor, Varun; Bauer, Dieter [Institut fuer Physik, Universitaet Rostock, 18051 Rostock (Germany)

2013-07-01

Time-dependent density functional theory (TDDFT) with known and practicable exchange-correlation potentials does not capture highly correlated electron dynamics such as single-photon double ionization, autoionization, or nonsequential ionization. Time-dependent reduced density matrix functional theory (TDRDMFT) may remedy these problems. The key ingredients in TDRDMFT are the natural orbitals (NOs), i.e., the eigenfunctions of the one-body reduced density matrix (1-RDM), and the occupation numbers (OCs), i.e., the respective eigenvalues. The two-body reduced density matrix (2-RDM) is then expanded in NOs, and equations of motion for the NOs can be derived. If the expansion coefficients of the 2-RDM were known exactly, the problem at hand would be solved. In practice, approximations have to be made. We study the prospects of TDRDMFT following a top-down approach. We solve the exact two-electron time-dependent Schroedinger equation for a model Helium atom in intense laser fields in order to study highly correlated phenomena such as the population of autoionizing states or single-photon double ionization. From the exact wave function we calculate the exact NOs, OCs, the exact expansion coefficients of the 2-RDM, and the exact potentials in the equations of motion. In that way we can identify how many NOs and which level of approximations are necessary to capture such phenomena.

Kinematics of 3-body in Ionization Collision

International Nuclear Information System (INIS)

Della Picca, Renata

2003-01-01

In this thesis we study three body problems in the frame of the collision theory. First, we deal with the process of autoionization by ion impact where the line profile of the electron emitted is strongly affected by the post-collision interaction with the Coulomb field of the outgoing projectile.Here we analyze how these effects are modified when the projectile velocity is in the close vicinity of the resonant electron velocity.In this energy range, the analysis of the resonance contribution is hindered by the characteristic 'electron capture to the continuum' divergence in the direct term.Here we present a detailed theoretical study of the interplay between both contributions, based on a generalization of the Final-State Interaction model.Finally we propose a modified parameterization of the autoionization line shape in the vicinity of the ECC cusp.Secondly, we study the direct ionization of an atomic target by the impact of a charge projectile, through analysis of the quintuple differential cross section (QDCS) which gives the most complete information about a ionization collision.Its study, without any approximation on the mass ratios can unveil new, not previously observed, structures.In particular, in this work the ionization of Hydrogen molecules by the impact of positrons and muons was studied and a new structure that has not been identified until now was found. Its main characteristics and a possible explanation are presented

Professional Interaction, Relevant Practical Experience, and Intellectual Contributions at Nondoctoral AACSB-Accredited Accounting Programs

Science.gov (United States)

Arlinghaus, Barry P.

2008-01-01

In this article, the author discusses a survey of faculty members at nondoctoral AACSB-accredited accounting programs in the United States. The purpose of the survey was to determine the environment for professional interaction and relevant experience in light of institutional demands for intellectual contributions. The findings show that the…

Evolutionary Relevance Facilitates Visual Information Processing

Directory of Open Access Journals (Sweden)

Russell E. Jackson

2013-07-01

Full Text Available Visual search of the environment is a fundamental human behavior that perceptual load affects powerfully. Previously investigated means for overcoming the inhibitions of high perceptual load, however, generalize poorly to real-world human behavior. We hypothesized that humans would process evolutionarily relevant stimuli more efficiently than evolutionarily novel stimuli, and evolutionary relevance would mitigate the repercussions of high perceptual load during visual search. Animacy is a significant component to evolutionary relevance of visual stimuli because perceiving animate entities is time-sensitive in ways that pose significant evolutionary consequences. Participants completing a visual search task located evolutionarily relevant and animate objects fastest and with the least impact of high perceptual load. Evolutionarily novel and inanimate objects were located slowest and with the highest impact of perceptual load. Evolutionary relevance may importantly affect everyday visual information processing.

The Relevance of Health Literacy to mHealth.

Science.gov (United States)

Kreps, Gary L

2017-01-01

This chapter examines the importance of health literacy to the design and use of mobile digital health information technology (mHealth) applications. Over the past two decades mHealth has evolved to become a major health communication channel for delivering health care, promoting health, and tracking health behaviors. Yet, there are serious communication challenges that must be addressed concerning the best way to design and utilize mHealth application to achieve key health promotion goals, including assuring the appropriateness and effectiveness of mHealth messaging for audiences with different communication competencies, styles, and health literacy levels, to ensure that mHealth applications are truly effective tools for health promotion. Health literacy is one of the major communication issues relevant to the effective use of mHealth. To be effective, mHealth applications need to match the messages conveyed via these mobile media to the specific health communication needs, orientations, and competencies of intended audience members. Unfortunately, current evidence suggests that many mHealth applications are difficult for audiences to utilize because they provide health information that is not easy for many consumers to understand and apply. Health literacy refers to the ability of participants within the health care system to accurately interpret and utilize relevant health information and resources to achieve their health goals. Evidence suggests that many consumers possess limited levels of health literacy to adequately understand health information, especially when they are feeling ill, since health literacy is both a trait (limited education, language facility, etc.), and a state condition (based on how their current physical and mental states influence their abilities to communicate effectively). Therefore, it is incumbent upon mHealth developers to design and utilize message systems. Strategies for designing and implementing mHealth applications to meet

Coherent states approach to Penning trap

International Nuclear Information System (INIS)

Fernandez, David J; Velazquez, Mercedes

2009-01-01

By using a matrix technique, which allows us to identify directly the ladder operators, the Penning trap coherent states are derived as eigenstates of the appropriate annihilation operators. These states are compared with those obtained through the displacement operator. The associated wavefunctions and mean values for some relevant operators in these states are also evaluated. It turns out that the Penning trap coherent states minimize the Heisenberg uncertainty relation

Culturally Relevant Human Subjects Protection Training: A Case Study in Community-Engaged Research in the United States.

Science.gov (United States)

Kue, Jennifer; Szalacha, Laura A; Happ, Mary Beth; Crisp, Abigail L; Menon, Usha

2018-02-01

Non-academic members of research teams, such as community members, can perceive traditional human subjects protection training as lacking in cultural relevance. We present a case exemplar of the development of a human subjects protection training for research staff with limited English proficiency and/or no or limited research experience. Seven modules were adapted for language, cultural examples, etc., from the standard Collaborative Institutional Training Initiative (CITI) human subjects protection training. Non-academic research staff completed a day-long training in human subjects protection (six modules) and our research protocol (one module). We assessed comprehension of content with PowerPoint slides and module quizzes. All participants successfully passed each module quiz with ≥ 80% correct. Questions answered incorrectly were discussed before proceeding to the next module. To meet the increasing demand for collaborative community-engaged research with underserved minority populations, human subjects protection training protocols can be adapted successfully to reflect real-world situations and provide culturally relevant materials to help non-academic research staff better understand the importance and necessity of research ethics.

Positronic complexes with unnatural parity

International Nuclear Information System (INIS)

Bromley, M. W. J.; Mitroy, J.; Varga, K.

2007-01-01

The structure of the unnatural parity states of PsH, LiPs, NaPs, and KPs are investigated with the configuration interaction and stochastic variational methods. The binding energies (in hartree) are found to be 8.17x10 -4 , 4.42x10 -4 , 15.14x10 -4 , and 21.80x10 -4 , respectively. These states are constructed by first coupling the two electrons into a configuration which is predominantly 3 P e , and then adding a p-wave positron. All the active particles are in states in which the relative angular momentum between any pair of particles is at least L=1. The LiPs state is Borromean since there are no three-body bound subsystems (of the correct symmetry) of the (Li + , e - , e - , e + ) particles that make up the system. The dominant decay mode of these states will be radiative decay into a configuration that autoionizes or undergoes positron annihilation

Progress in zirconium resonance ionization spectroscopy

International Nuclear Information System (INIS)

Page, R.H.; Dropinski, S.C.; Worden, E.F.; Stockdale, J.A.D.

1993-01-01

The authors have examined the stepwise-resonant three-photon-ionization spectrum of neutral zirconium atoms using three separately-tunable pulsed visible dye lasers. The ground-level (first-step) transitions were chosen on the basis of demonstrated 91 Zr selectivity. Lifetimes of even-parity levels around 36,000 cm -1 , measured with the delayed-photoionization technique, range from 10 to 100 nsec. Direct ionization cross sections appear to be less than 10 -17 cm 2 ; newly-detected autoionizing levels give peak ionization cross sections (inferred from saturation fluences) up to 10 -15 cm 2 . Portions of Rydberg series converging to the 315 and 763 cm -1 levels of Zr + were identified. Clumps of autoionizing levels are thought to be due to Rydberg-valence mixing

Performance of tungsten-based materials and components under ITER and DEMO relevant steady-state thermal loads

Energy Technology Data Exchange (ETDEWEB)

Ritz, Guillaume Henri

2011-07-01

In nuclear fusion devices the surfaces directly facing the plasma are irradiated with high energy fluxes. The most intense loads are deposited on the divertor located at the bottom of the plasma chamber, which has to withstand continuous heat loads with a power density of several MW . m{sup -2} as well as transient events. These are much shorter (in the millisecond and sub-millisecond regime) but deposit a higher power densities of a few GW . m{sup -2}. The search for materials that can survive to those severe loading conditions led to the choice of tungsten which possesses advantageous attributes such as a high melting point, high thermal conductivity, low thermal expansion and an acceptable activation rate. These properties made it an attractive and promising candidate as armor material for divertors of future fusion devices such as ITER and DEMO. For the DEMO divertor, conceptual studies on helium-cooled tungsten plasma-facing components were performed. The concept was realized and tested under DEMO specific cyclic thermal loads. The examination of the plasma-facing components by microstructural analyses before and after thermal loading enabled to determine the mechanisms for components failure. Among others, it clearly showed the impact of the tungsten grade and the thermal stress induced crack formation on the performance of the armor material and in general of the plasma-facing component under high heat loads. A tungsten qualification program was launched to study the behaviour of various tungsten grades, in particular the crack formation, under fusion relevant steady-state thermal loads. In total, seven commercially available materials from two industrial suppliers were investigated. As the material's thermal response is strongly related to its microstructure, this program comprised different material geometries and manufacturing technologies. It also included the utilization of an actively cooled specimen holder which has been designed to perform

Performance of tungsten-based materials and components under ITER and DEMO relevant steady-state thermal loads

International Nuclear Information System (INIS)

Ritz, Guillaume Henri

2011-01-01

In nuclear fusion devices the surfaces directly facing the plasma are irradiated with high energy fluxes. The most intense loads are deposited on the divertor located at the bottom of the plasma chamber, which has to withstand continuous heat loads with a power density of several MW . m -2 as well as transient events. These are much shorter (in the millisecond and sub-millisecond regime) but deposit a higher power densities of a few GW . m -2 . The search for materials that can survive to those severe loading conditions led to the choice of tungsten which possesses advantageous attributes such as a high melting point, high thermal conductivity, low thermal expansion and an acceptable activation rate. These properties made it an attractive and promising candidate as armor material for divertors of future fusion devices such as ITER and DEMO. For the DEMO divertor, conceptual studies on helium-cooled tungsten plasma-facing components were performed. The concept was realized and tested under DEMO specific cyclic thermal loads. The examination of the plasma-facing components by microstructural analyses before and after thermal loading enabled to determine the mechanisms for components failure. Among others, it clearly showed the impact of the tungsten grade and the thermal stress induced crack formation on the performance of the armor material and in general of the plasma-facing component under high heat loads. A tungsten qualification program was launched to study the behaviour of various tungsten grades, in particular the crack formation, under fusion relevant steady-state thermal loads. In total, seven commercially available materials from two industrial suppliers were investigated. As the material's thermal response is strongly related to its microstructure, this program comprised different material geometries and manufacturing technologies. It also included the utilization of an actively cooled specimen holder which has been designed to perform sophisticated

Does emotion help or hinder reasoning? The moderating role of relevance.

Science.gov (United States)

Blanchette, Isabelle; Gavigan, Sarah; Johnston, Kathryn

2014-06-01

Some prior research has shown that emotion impairs logicality in deductive reasoning tasks, while other research suggests improved performance with emotional contents. We suggest that relevance, whether the affective state is associated with the semantic contents of the reasoning task, may be crucial in explaining these apparently inconsistent findings. This hypothesis is based on a framework distinguishing between integral emotions, where affective responses are evoked by the semantic contents of the target task, and incidental emotions, where affective responses are not related to the task. In 4 experiments we examined the effect of emotion on conditional reasoning when affective responses were relevant and irrelevant. We used images presented simultaneously with the reasoning stimuli (Experiments 1, 2, and 3) or videos presented prior to the reasoning stimuli (Experiment 4) that were either emotional or neutral and semantically related or not to the conditional statements. Results showed that emotion decreased the proportion of normatively correct responses only in the irrelevant condition. In the relevant condition, emotion did not produce reliable deleterious effects. We used reaction time and skin conductance measures to investigate the physiological and cognitive correlates of these effects. Results are discussed in terms of the distinction between incidental and integral emotions. PsycINFO Database Record (c) 2014 APA, all rights reserved.

Seeing without knowing: task relevance dissociates between visual awareness and recognition.

Science.gov (United States)

Eitam, Baruch; Shoval, Roy; Yeshurun, Yaffa

2015-03-01

We demonstrate that task relevance dissociates between visual awareness and knowledge activation to create a state of seeing without knowing-visual awareness of familiar stimuli without recognizing them. We rely on the fact that in order to experience a Kanizsa illusion, participants must be aware of its inducers. While people can indicate the orientation of the illusory rectangle with great ease (signifying that they have consciously experienced the illusion's inducers), almost 30% of them could not report the inducers' color. Thus, people can see, in the sense of phenomenally experiencing, but not know, in the sense of recognizing what the object is or activating appropriate knowledge about it. Experiment 2 tests whether relevance-based selection operates within objects and shows that, contrary to the pattern of results found with features of different objects in our previous studies and replicated in Experiment 1, selection does not occur when both relevant and irrelevant features belong to the same object. We discuss these findings in relation to the existing theories of consciousness and to attention and inattentional blindness, and the role of cognitive load, object-based attention, and the use of self-reports as measures of awareness. © 2015 New York Academy of Sciences.

State-of-the-Art Review on Relevance of Genetic Algorithm to Internet Web Search

Directory of Open Access Journals (Sweden)

Kehinde Agbele

2012-01-01

Full Text Available People use search engines to find information they desire with the aim that their information needs will be met. Information retrieval (IR is a field that is concerned primarily with the searching and retrieving of information in the documents and also searching the search engine, online databases, and Internet. Genetic algorithms (GAs are robust, efficient, and optimizated methods in a wide area of search problems motivated by Darwin’s principles of natural selection and survival of the fittest. This paper describes information retrieval systems (IRS components. This paper looks at how GAs can be applied in the field of IR and specifically the relevance of genetic algorithms to internet web search. Finally, from the proposals surveyed it turns out that GA is applied to diverse problem fields of internet web search.

Working Toward Policy-Relevant Air Quality Emissions Scenarios

Science.gov (United States)

Holloway, T.

2010-12-01

Though much work has been done to develop accurate chemical emission inventories, few publicly available inventories are appropriate for realistic policy analysis. Emissions from the electricity and transportation sectors, in particular, respond in complex ways to policy, technology, and energy use change. Many widely used inventories, such as the EPA National Emissions Inventory, are well-suited for modeling current air quality, but do not have the specificity needed to address "what if?" questions. Changes in electricity demand, fuel prices, new power sources, and emission controls all influence the emissions from regional power production, requiring a plant-by-plant assessment to capture the spatially explicit impacts. Similarly, land use, freight distribution, or driving behavior will yield differentiated transportation emissions for urban areas, suburbs, and rural highways. We here present results from three recent research projects at the University of Wisconsin—Madison, where bottom-up emission inventories for electricity, freight transport, and urban vehicle use were constructed to support policy-relevant air quality research. These three studies include: 1) Using the MyPower electricity dispatch model to calculate emissions and air quality impacts of Renewable Portfolio Standards and other carbon-management strategies; 2) Using advanced vehicle and commodity flow data from the Federal Highway Administration to evaluate the potential to shift commodities from truck to rail (assuming expanded infrastructure), and assess a range of alternative fuel suggestions; and 3) Working with urban planners to connect urban density with vehicle use to evaluate the air quality impacts of smart-growth in major Midwest cities. Drawing on the results of these three studies, and on challenges overcome in their execution, we discuss the current state of policy-relevant emission dataset generation, as well as techniques and attributes that need to be further refined in order

The Development of Relevance in Information Retrieval

Directory of Open Access Journals (Sweden)

Mu-hsuan Huang

1997-12-01

Full Text Available This article attempts to investigate the notion of relevance in information retrieval. It discusses various definitions for relevance from historical viewpoints and the characteristics of relevance judgments. Also, it introduces empirical results of important related researches.[Article content in Chinese

Aspect-based Relevance Learning for Image Retrieval

NARCIS (Netherlands)

M.J. Huiskes (Mark)

2005-01-01

htmlabstractWe analyze the special structure of the relevance feedback learning problem, focusing particularly on the effects of image selection by partial relevance on the clustering behavior of feedback examples. We propose a scheme, aspect-based relevance learning, which guarantees that feedback

Thermochemical data for environmentally-relevant elements

International Nuclear Information System (INIS)

Markich, S.J.; Brown, P.L.

1999-01-01

This study provides an extensive stability constant (log K) database suitable for calculating the speciation of selected environmentally-relevant elements (H, Na, K, Ca, Mg, Fe, Mn, U, Al Pb, Zn, Cu and cd) in an aqueous system, where a model fulvic acid (comprising aspartic, citric, malonic, salicylic and tricarballylic acids) is used to simulate metal binding by dissolved organic material Stability constants for inorganic metal complexes and minerals were selected primarily from critical literature complications and/or reviews. In contrast, few critically evaluated data were available for metal complexes with aspartic, citric, malonic, salicylic and tricarballylic acids. Consequently, data from original research articles were carefully evaluated and compiled as part of the study, following defined selection criteria. to meet the objective of compiling a comprehensive and reliable database of stability constants, all relevant equilibria and species, ranging from simple binary metal complexes to more complex ternary and even quaternary, metal complexes were included where possible in addition to the selection of stability constants from empirical sources, estimates of stability constants were performed when this could be done reliably, based on the unified theory of metal ion complexation and/or linear tree energy relationships The stability constants are given as common logarithms (logo) in the form required by the HARPHRQ geochemical code and refer to the standard state, i.e 298.15 K (25 deg C), 10 5 Pa (1 atm) and, for all species, infinite dilution (ionic strength = 0 mol L -1 ). In addition to the compilation of stability constant data, an overview is given of geochemical speciation modelling in aqueous systems and available conceptual models of metal binding by humic substances. (authors)

A Peep into the Uncertainty-Complexity-Relevance Modeling Trilemma through Global Sensitivity and Uncertainty Analysis

Science.gov (United States)

Munoz-Carpena, R.; Muller, S. J.; Chu, M.; Kiker, G. A.; Perz, S. G.

2014-12-01

Model Model complexity resulting from the need to integrate environmental system components cannot be understated. In particular, additional emphasis is urgently needed on rational approaches to guide decision making through uncertainties surrounding the integrated system across decision-relevant scales. However, in spite of the difficulties that the consideration of modeling uncertainty represent for the decision process, it should not be avoided or the value and science behind the models will be undermined. These two issues; i.e., the need for coupled models that can answer the pertinent questions and the need for models that do so with sufficient certainty, are the key indicators of a model's relevance. Model relevance is inextricably linked with model complexity. Although model complexity has advanced greatly in recent years there has been little work to rigorously characterize the threshold of relevance in integrated and complex models. Formally assessing the relevance of the model in the face of increasing complexity would be valuable because there is growing unease among developers and users of complex models about the cumulative effects of various sources of uncertainty on model outputs. In particular, this issue has prompted doubt over whether the considerable effort going into further elaborating complex models will in fact yield the expected payback. New approaches have been proposed recently to evaluate the uncertainty-complexity-relevance modeling trilemma (Muller, Muñoz-Carpena and Kiker, 2011) by incorporating state-of-the-art global sensitivity and uncertainty analysis (GSA/UA) in every step of the model development so as to quantify not only the uncertainty introduced by the addition of new environmental components, but the effect that these new components have over existing components (interactions, non-linear responses). Outputs from the analysis can also be used to quantify system resilience (stability, alternative states, thresholds or tipping

Laser resonance ionization scheme development for tellurium and germanium at the dual Ti:Sa–Dye ISOLDE RILIS

CERN Document Server

Day Goodacre, T.; Fedosseev, V.N.; Forster, L.; Marsh, B.A.; Rossel, R.E.; Rothe, S.; Veinhard, M.

2016-01-01

The resonance ionization laser ion source (RILIS) is the principal ion source of the ISOLDE radioactive beam facility based at CERN. Using the method of in-source laser resonance ionization spectroscopy, a transition to a new autoionizing state of tellurium was discovered and applied as part of a three-step, three-resonance, photo-ionization scheme. In a second study, a three-step, two-resonance, photo-ionization scheme for germanium was developed and the ionization efficiency was measured at ISOLDE. This work increases the range of ISOLDE RILIS ionized beams to 31 elements. Details of the spectroscopy studies are described and the new ionization schemes are summarized.

Laser resonance ionization scheme development for tellurium and germanium at the dual Ti:Sa–Dye ISOLDE RILIS

Energy Technology Data Exchange (ETDEWEB)

Day Goodacre, T., E-mail: thomas.day.goodacre@cern.ch [CERN, CH-1211 Geneva 23 (Switzerland); School of Physics and Astronomy, The University of Manchester, Manchester M13 9PL (United Kingdom); Fedorov, D. [Petersburg Nuclear Physics Institute, 188350 Gatchina (Russian Federation); Fedosseev, V.N.; Forster, L.; Marsh, B.A. [CERN, CH-1211 Geneva 23 (Switzerland); Rossel, R.E. [CERN, CH-1211 Geneva 23 (Switzerland); Institut für Physik, Johannes Gutenberg Universität, D-55099 Mainz (Germany); Faculty of Design, Computer Science and Media, Hochschule RheinMain, Wiesbaden (Germany); Rothe, S.; Veinhard, M. [CERN, CH-1211 Geneva 23 (Switzerland)

2016-09-11

The resonance ionization laser ion source (RILIS) is the principal ion source of the ISOLDE radioactive beam facility based at CERN. Using the method of in-source laser resonance ionization spectroscopy, a transition to a new autoionizing state of tellurium was discovered and applied as part of a three-step, three-resonance, photo-ionization scheme. In a second study, a three-step, two-resonance, photo-ionization scheme for germanium was developed and the ionization efficiency was measured at ISOLDE. This work increases the range of ISOLDE RILIS ionized beams to 31 elements. Details of the spectroscopy studies are described and the new ionization schemes are summarized.

Dissociative recombination of molecular ions H2+

International Nuclear Information System (INIS)

Abarenov, A.V.; Marchenko, V.S.

1989-01-01

The total cross sections of dissociation and dissociative recombination of slow electrons and molecular ions H 2 + have been calculated in terms of the quasiclassical and dipole approximations. In the calculations allowance was made for the quantum nature of vibrational motion of heavy particles and presence of autoionization of divergence states of the H 2 (Σ u , nl) molecules. It is shown that the H 2 + ion dissociation cross sections are dominant in increase of the electron energy in the ε >or approx. 2-3 eV region for H 2 + (v) ion distribution over the vibrational levels characteristic for the beam experiments. 15 refs.; 5 figs

The excited J = 01 Σu+ levels of D2: Measurements and ab initio quantum defect study

Science.gov (United States)

Glass-Maujean, M.; Jungen, Ch.; Dickenson, G. D.; de Oliveira, N.; Ubachs, W.

2016-02-01

The DESIRS beamline of the SOLEIL synchrotron facility, equipped with a vacuum ultraviolet Fourier-transform spectrometer has been used to measure P (N″ = 1) (N -N″ = - 1) absorption transitions of the D2 molecule. Some 44 P-lines were assigned and their transition frequencies determined up to excitation energies of 134,000 cm-1 above the ground state, thereby extending the earlier work by various authors, and considerably improving the spectral accuracy (<0.1 cm-1). The assignments have been aided by first principles multichannel quantum defect theory (MQDT) calculations. These calculations also provide predictions of the autoionization widths of the upper levels which agree well with the observed resonance widths.

Current R and D status on material motion and interactions relevant to core disruptive accidents

Energy Technology Data Exchange (ETDEWEB)

Kondo, Satoru [Safety Engineering Division, O-arai Engineering Center, Power Reactor and Nuclear Fuel Development Corporation, O-arai, Ibaraki (Japan)

1994-07-01

In this paper, the current status of research and development activities are briefly reviewed on evaluation of material-coolant interactions and material movement and relocation relevant to the safety of liquid-metal fast reactors. Since the status of European activities are well summarized in other papers submitted to the present meeting, the activities in Japan and the United States are highlighted in this paper. The review includes: out-of-pile experiments, in-pile experiments and relevant computer code development. It is emphasized that improved understanding on material motion has contributed to establishing more realistic and rational safety evaluation methods, where various mitigation mechanisms are inherently effective. (author)

On the relevance of matrix coordinates for the inside of baryons

International Nuclear Information System (INIS)

Fatollahi, A.H.

2003-01-01

It is argued that one natural choice for the coordinates of the constituents of a baryonic state in a SU(N) gauge theory is the choice of N x N hermitian matrices. It is discussed that the relevance of matrix coordinates is supported at least by the restricted form of the color symmetry. Based on the previous investigations in this direction, the consequences of this idea are reviewed. The model has been considered in which it originates in the D0-branes of the string theory. (orig.)

Practical calculations of quantum breakup cross sections

International Nuclear Information System (INIS)

McCurdy, C. W.; Rescigno, T. N.

2000-01-01

The Schroedinger equation is solved numerically using the method of exterior complex scaling for several models of the breakup of an atom by electron impact. Using the accurate wave functions thereby obtained for these model problems, several well-known integral expressions for quantum-mechanical breakup amplitudes are tested. It is shown that some formally correct integral expressions for the breakup amplitudes can yield numerically unstable or poorly convergent results. Calculations are presented for a case with simple exponential potentials and a case in which a metastable state of the target, analogous to an autoionizing state, can decay into the breakup channel. For cases involving only short-range (non-Coulomb) interactions, alternative expressions can be found that are stable in calculations of practical scale. (c) 2000 The American Physical Society

Influencing Tomorrow: A Study of Emerging Influence Techniques and Their Relevance to United States Information Operations

Science.gov (United States)

2015-06-12

offers insights into an international network that has preserved a holistic identity, while simultaneously franchising globally . The Islamic State...preserved a holistic identity, while simultaneously franchising globally . The Islamic State of Iraq and the Levant is the second study and an...identity, while simultaneously franchising globally . The ISIL is an outstanding example of a regional non-state actor who rapidly claimed market share

Embedded promotions in online services: how goal-relevance ambiguity shapes response and affect.

Science.gov (United States)

Brasel, S Adam

2010-09-01

Adding promotions to online services is increasingly commonplace, yet consumers may have difficulty determining whether service-embedded promotions are goal-relevant, due to the linear and transactional nature of online services. This contextual effect of goal-relevance ambiguity on promotions is explored across three studies. An exploratory study utilizing actual service websites and a broad range of consumers as participants showed promotional elements in online services generated considerable confusion, and instructions labeling promotions as optional did little to relieve goal-relevance ambiguity. A second study using student participants inserted promotions into an online airline ticket service, a shopping site, a local news blog, and a news headline aggregator, to explore how linear and transactional sites such as online services compared to more exploratory or informational online environments. Results showed that service-embedded promotions enjoyed initial compliance far beyond promotions in traditional websites but also generated increased confusion, frustration, and anger. A third study utilizing student participants explored how varying levels of online service experience created differing responses to promotions in services; novices were less able to judge promotional goal-relevance and experienced more confusion, whereas experienced searchers were more likely to respond with frustration and anger. Many participants complied with promotional offers at the time of the service transaction, but stated intentions to use the promotion postservice were very low. The overall results spotlight goal-relevance ambiguity as an important driver of consumer response to online promotions, and highlight the role website context can play in the processing of online promotional elements. PsycINFO Database Record (c) 2010 APA, all rights reserved.

Improving Strategic Planning and Implementation in Universities through Competitive Intelligence Tools: A Means to Gaining Relevance

Science.gov (United States)

Hughes, Stephanie; White, Rebecca J.

2005-01-01

Institutions of higher education can use competitive intelligence (CI) techniques to become more relevant to their communities. In Stepping Forward as Stewards of Place the American Association of State Colleges and Universities (AASCU) provides a model for public engagement that emphasizes internal strategic planning, implementation, and…

Mobility-induced persistent chimera states

Science.gov (United States)

Petrungaro, Gabriela; Uriu, Koichiro; Morelli, Luis G.

2017-12-01

We study the dynamics of mobile, locally coupled identical oscillators in the presence of coupling delays. We find different kinds of chimera states in which coherent in-phase and antiphase domains coexist with incoherent domains. These chimera states are dynamic and can persist for long times for intermediate mobility values. We discuss the mechanisms leading to the formation of these chimera states in different mobility regimes. This finding could be relevant for natural and technological systems composed of mobile communicating agents.

The Personal Relevance of the Social Studies.

Science.gov (United States)

VanSickle, Ronald L.

1990-01-01

Conceptualizes a personal-relevance framework derived from Ronald L. VanSickle's five areas of life integrated with four general motivating goals from Abraham Maslow's hierarchy of needs and Richard and Patricia Schmuck's social motivation theory. Illustrates ways to apply the personal relevance framework to make social studies more relevant to…

The State Supervision (Control in the Sphere of Economic Activity: International Experience Relevant for Ukraine

Directory of Open Access Journals (Sweden)

Vdovychenko Larysa Yu.

2018-01-01

Full Text Available The attempts in the process of decentralization in Ukraine to implement the best international practices of the State supervision (control in the sphere of economic activity, in the process which depends on the status of deregulation and development of entrepreneurship, have caused the topicality of the problem set. The article is aimed at analyzing the international experience of application of the State supervision (control instruments in the sphere of economic activity and determination of the directions of their use in Ukraine. The stages of reforms of the control and supervision activity both in foreign countries and in Ukraine were considered. The directions and measures on creation of effective system of the State supervision (control in the sphere of economic activity, applied in the world countries, were systematized. Both the positive and the negative aspects of use of foreign instruments of the State supervision (control in the sphere of economic activity in Ukraine have been defined. Recommendations on formation of the national complex system of functioning of control-supervision activity have been given.

Relevance: An Interdisciplinary and Information Science Perspective

Directory of Open Access Journals (Sweden)

Howard Greisdorf

2000-01-01

Full Text Available Although relevance has represented a key concept in the field of information science for evaluating information retrieval effectiveness, the broader context established by interdisciplinary frameworks could provide greater depth and breadth to on-going research in the field. This work provides an overview of the nature of relevance in the field of information science with a cursory view of how cross-disciplinary approaches to relevance could represent avenues for further investigation into the evaluative characteristics of relevance as a means for enhanced understanding of human information behavior.

Relevance of equilibrium in multifragmentation

International Nuclear Information System (INIS)

Furuta, Takuya; Ono, Akira

2009-01-01

The relevance of equilibrium in a multifragmentation reaction of very central 40 Ca + 40 Ca collisions at 35 MeV/nucleon is investigated by using simulations of antisymmetrized molecular dynamics (AMD). Two types of ensembles are compared. One is the reaction ensemble of the states at each reaction time t in collision events simulated by AMD, and the other is the equilibrium ensemble prepared by solving the AMD equation of motion for a many-nucleon system confined in a container for a long time. The comparison of the ensembles is performed for the fragment charge distribution and the excitation energies. Our calculations show that there exists an equilibrium ensemble that well reproduces the reaction ensemble at each reaction time t for the investigated period 80≤t≤300 fm/c. However, there are some other observables that show discrepancies between the reaction and equilibrium ensembles. These may be interpreted as dynamical effects in the reaction. The usual static equilibrium at each instant is not realized since any equilibrium ensemble with the same volume as that of the reaction system cannot reproduce the fragment observables

Modeling Phase Equilibria for Acid Gas Mixtures using the Cubic-Plus-Association Equation of State. 3. Applications Relevant to Liquid or Supercritical CO2 Transport

DEFF Research Database (Denmark)

Tsivintzelis, Ioannis; Ali, Shahid; Kontogeorgis, Georgios

2014-01-01

density data for both CO2 and CO2–water and for vapor–liquid equilibrium for mixtures of CO2 with various compounds present in transport systems. In all of these cases we consider various possibilities for modeling CO2 (inert, self-associating using two-, three-, and four sites) and the possibility......The CPA (cubic-plus-association) equation of state is applied in this work to a wide range of systems of relevance to CO2 transport. Both phase equilibria and densities over extensive temperature and pressure ranges are considered. More specifically in this study we first evaluate CPA against......” for applying CPA to acid gas mixtures. The overall conclusion is that CPA performs satisfactorily; the model in most cases correlates well binary data and predicts with good accuracy multicomponent vapor–liquid equilibria. Among the various approaches investigated, the best ones are when cross association...

Solid state theory

CERN Document Server

Harrison, Walter A

2011-01-01

""A well-written text . . . should find a wide readership, especially among graduate students."" - Dr. J. I. Pankove, RCA.The field of solid state theory, including crystallography, semi-conductor physics, and various applications in chemistry and electrical engineering, is highly relevant to many areas of modern science and industry. Professor Harrison's well-known text offers an excellent one-year graduate course in this active and important area of research. While presenting a broad overview of the fundamental concepts and methods of solid state physics, including the basic quantum theory o

The Amygdala and the Relevance Detection Theory of Autism: An Evolutionary Perspective

Directory of Open Access Journals (Sweden)

Tiziana eZalla

2013-12-01

Full Text Available In the last few decades, there has been increasing interest in the role of the amygdala in psychiatric disorders and in particular its contribution to the socio-emotional impairments in autism spectrum disorders (ASDs. Given that the amygdala is a component structure of the social brain, several theoretical explanations compatible with amygdala dysfunction have been proposed to account for socio-emotional impairments in ASDs, including abnormal eye contact, gaze monitoring, face processing, mental state understanding and empathy. Nevertheless, many theoretical accounts, based on the Amygdala Theory of Autism, fail to elucidate the complex pattern of impairments observed in this population, which extends beyond the social domain. As posited by the Relevance Detector theory (Sander, Grafman and Zalla, 2003, the human amygdala is a critical component of a brain circuit involved in the appraisal of self-relevant events that include, but are not restricted to, social stimuli. Here, we propose that the behavioral and social-emotional features of ASDs may be better understood in terms of a disruption in a ‘Relevance Detector Network’ affecting the processing of stimuli that are relevant for the organism’s self-regulating functions. In the present review, we will first summarize the main literature supporting the involvement of the amygdala in socio-emotional disturbances in ASDs. Next, we will present a revised version of the amygdala Relevance Detector hypothesis and we will show that this theoretical framework can provide a better understanding of the heterogeneity of the impairments and symptomatology of ASDs. Finally, we will discuss some predictions of our model, and suggest new directions in the investigation of the role of the amygdala within the more generally disrupted cortical connectivity framework as a model of neural organization of the autistic brain.

Explaining citizens’ perceptions of international climate-policy relevance

International Nuclear Information System (INIS)

Schleich, Joachim; Faure, Corinne

2017-01-01

This paper empirically analyses the antecedents of citizens’ perceptions of the relevance of international climate policy. Its use of representative surveys in the USA, China and Germany controls for different environmental attitudes and socio-economic factors between countries. The findings of the micro-econometric analysis suggest that the perceived relevance of international climate policy is positively affected by its perceived effectiveness, approval of the key topics discussed at international climate conferences, and environmental attitudes, but is not affected by perceived procedural justice. A higher level of perceived trust in international climate policy was positively related to perceived relevance in the USA and in China, but not in Germany. Citizens who felt that they were well informed and that their position was represented at climate summits were more likely to perceive international climate policy as relevant in China in particular. Generally, the results show only weak evidence of socio-demographic effects. - Highlights: • Perceptions of climate-policy relevance increase with perceptions of effectiveness. • In China and the USA, trust increases perceptions of climate-policy relevance. • Environmental attitudes are related to perceptions of climate-policy relevance. • In China, well-informed citizens perceive climate policy as more relevant. • Socio-demographics only weakly affect perceptions of climate-policy relevance.

Family influences on mania-relevant cognitions and beliefs: a cognitive model of mania and reward.

Science.gov (United States)

Chen, Stephen H; Johnson, Sheri L

2012-07-01

The present study proposed and tested a cognitive model of mania and reward. Undergraduates (N = 284; 68.4% female; mean age = 20.99 years, standard deviation ± 3.37) completed measures of family goal setting and achievement values, personal reward-related beliefs, cognitive symptoms of mania, and risk for mania. Correlational analyses and structural equation modeling supported two distinct, but related facets of mania-relevant cognition: stably present reward-related beliefs and state-dependent cognitive symptoms in response to success and positive emotion. Results also indicated that family emphasis on achievement and highly ambitious extrinsic goals were associated with these mania-relevant cognitions. Finally, controlling for other factors, cognitive symptoms in response to success and positive emotion were uniquely associated with lifetime propensity towards mania symptoms. Results support the merit of distinguishing between facets of mania-relevant cognition and the importance of the family in shaping both aspects of cognition. © 2012 Wiley Periodicals, Inc.

Smallest chimera states

Science.gov (United States)

Maistrenko, Yuri; Brezetsky, Serhiy; Jaros, Patrycja; Levchenko, Roman; Kapitaniak, Tomasz

2017-01-01

We demonstrate that chimera behavior can be observed in small networks consisting of three identical oscillators, with mutual all-to-all coupling. Three different types of chimeras, characterized by the coexistence of two coherent oscillators and one incoherent oscillator (i.e., rotating with another frequency) have been identified, where the oscillators show periodic (two types) and chaotic (one type) behaviors. Typical bifurcations at the transitions from full synchronization to chimera states and between different types of chimeras have been described. Parameter regions for the chimera states are obtained in the form of Arnold tongues, issued from a singular parameter point. Our analysis suggests that chimera states can be observed in small networks relevant to various real-world systems.

Pain-relevant anxiety affects desire for pain relief, but not pain perception

Directory of Open Access Journals (Sweden)

Adriana Banozic

2017-01-01

Full Text Available Background: Pain context plays a significant role in the perception of pain. Despite recent interest in vicarious learning and anxiety in pain modulation, there have been no attempts to explore pain modulation by specific environmental cues. Aims: Therefore, the present study evaluated pain responses in the condition that was attributed as either anxiety relevant (AR or anxiety irrelevant. Materials and Methods: Participants were exposed to both conditions through social observational learning. Pain perception was assessed by means of a visual analog scale ranging from 0 = no pain to 10 = maximum imaginable pain. State anxiety, empathy, expectancy, and desire for pain relief were also measured at both neutral and emotionally inducing conditions. Results: No effect of relevancy of anxiety for the pain context on any of the pain-related constructs was found. However, participants in the AR condition reported an increased desire for pain relief. Maximizing similarities between observed and experienced pain context did not enhance observational learning effects in the emotionally inducing condition regardless of its relevance, but significant changes were found in comparison to the affectively neutral group. Conclusions: These results could have potentially significant clinical implications suggesting that even though observing painful procedures does not increase pain it could affect medication usage.

Studies on low energy ion-atom collisions by means of electron-spectroscopy

International Nuclear Information System (INIS)

Hirosi Suzuki

1991-01-01

The typical results of studies on autoionization processes produced by low energy ion-atom collisions are given by means of the ejected electron spectroscopy, which have been performed by Atomic Physics Group of Sophia University

Studies of Ionic Photoionization Using Relativistic Random Phase Approximation and Relativistic Multichannel Quantum Defect Theory

Science.gov (United States)

Haque, Ghousia Nasreen

The absorption of electromagnetic radiation by positive ions is one of the fundamental processes of nature which occurs in every intensely hot environment. Due to the difficulties in producing sufficient densities of ions in a laboratory, there are very few measurements of ionic photoabsorption parameters. On the theoretical side, some calculations have been made of a few major photoionization parameters, but generally speaking, most of the work done so far has employed rather simple single particle models and any theoretical work which has adequately taken into account intricate atomic many-body and relativistic effects is only scanty. In the present work, several complex aspects of atomic/ionic photoabsorption parameters have been studied. Non -resonant photoionization in neon and argon isonuclear as well as isoelectronic sequences has been studied using a very sophisticated technique, namely the relativistic random phase approximation (RRPA). This technique takes into account relativistic effects as well as an important class of major many-body effects on the same footing. The present calculations confirmed that gross features of photoionization parameters calculated using simpler models were not an artifact of the simple model. Also, the present RRPA calculations on K^+ ion and neutral Ar brought out the relative importance of various many-body effects such the inter-channel coupling. Inter-channel coupling between discrete bound state photoexcitation channels from an inner atomic/ionic level and photoionization continuum channels from an outer atomic/ionic level leads to the phenomena of autoionization resonances in the photoionization process. These resonances lead to very complex effects in the atomic/ionic photoabsorption spectra. These resonances have been calculated and studied in the present work in the neon and magnesium isoelectronic sequences using the relativistic multi-channel quantum defect theory (RMQDT) within the framework of the RRPA. The

Inoculating Relevance Feedback Against Poison Pills

NARCIS (Netherlands)

Dehghani, Mostafa; Azarbonyad, Hosein; Kamps, Jaap; Hiemstra, Djoerd; Marx, Maarten

2016-01-01

Relevance Feedback is a common approach for enriching queries, given a set of explicitly or implicitly judged documents to improve the performance of the retrieval. Although it has been shown that on average, the overall performance of retrieval will be improved after relevance feedback, for some

Theoretical studies of atomic transitions: Progress report, March 15, 1985-March 14, 1988

International Nuclear Information System (INIS)

Froese Fischer, C.

1987-09-01

Allowed and forbidden transitions have been studied for a number of atomic systems of interest in astrophysics, laser physics, or fusion research. All calculations have been based on the multiconfiguration Hartree-Fock (MCHF) method extended to include relativistic corrections in the Breit-Pauli approximation. The computer codes for this atomic structure software package were transferred to the CRAY supercomputer and modified for more convenient computation. Techniques were developed to enhance the range of problems considered, by either increasing the accuracy of prediction or increasing the complexity of problems considered. An example is the prediction of a bound state for Ca - for which experimental evidence was inconclusive. Several different types of problems have been considered. A study of energy levels and lifetimes of a Rydberg series can given insight into electronic structure and explain deviations from regular behavior, and a number of such studies were performed. With the MCHF + Breit-Pauli approach it has been possible to determine a large portion of a spectrum. In core excited quartets of Na, autoionization along spin-orbit mixing and term dependence were all important in predicting lifetimes in excellent agreement with the most recent experiments. Some photoionization studies were performed which, like autoionization require the calculation of continuum functions. Finally, an attempt was made to combine the MCHF method with many-body perturbation theory so as to build on the strengths of both. 13 refs., 2 figs., 3 tabs

Autonomia e relevância dos regimes The autonomy and relevance of regimes

Directory of Open Access Journals (Sweden)

Gustavo Seignemartin de Carvalho

2005-12-01

Full Text Available Teorias institucionalistas na disciplina de relações internacionais usualmente definem regimes como um conjunto de normas e regras formais ou informais que permitem a convergência de expectativas ou a padronização do comportamento de seus participantes em uma determinada área de interesses com o objetivo de resolver problemas de coordenação que tenderiam a resultados não pareto-eficientes. Como estas definições baseadas meramente na "eficiência" dos regimes não parecem suficientes para explicar sua efetividade, o presente artigo propõe uma definição diferente para regimes: a de arranjos políticos que permitem a redistribuição dos ganhos da cooperação pelos participantes em uma determinada área de interesses em um contexto de interdependência. Regimes possuiriam efetividade pela sua autonomia e relevância, ou seja, por possuírem existência objetiva autônoma da de seus participantes e por influenciarem seu comportamento e expectativas de maneiras que não podem ser reduzidas à ação individual de nenhum deles. O artigo inicia-se com uma breve discussão sobre as dificuldades terminológicas associadas ao estudo de regimes e a definição dos conceitos de autonomia e relevância. Em seguida, classifica os diversos autores participantes do debate em duas perspectivas distintas, uma que nega (não-autonomistas e outra que atribui (autonomistas aos regimes autonomia e relevância, e faz uma breve análise dos autores e tradições mais significativos para o debate, aprofundando-se nos autonomistas e nos argumentos que reforçam a hipótese aqui apresentada. Ao final, o artigo propõe uma decomposição analítica dos regimes nos quatro elementos principais que lhes propiciam autonomia e relevância: normatividade, atores, especificidade da área de interesses e interdependência complexa com o contexto.Regimes are defined by institutionalist theories in the discipline of International Relations as formal or informal sets

Clinical relevance in anesthesia journals

DEFF Research Database (Denmark)

Lauritsen, Jakob; Møller, Ann M

2006-01-01

The purpose of this review is to present the latest knowledge and research on the definition and distribution of clinically relevant articles in anesthesia journals. It will also discuss the importance of the chosen methodology and outcome of articles.......The purpose of this review is to present the latest knowledge and research on the definition and distribution of clinically relevant articles in anesthesia journals. It will also discuss the importance of the chosen methodology and outcome of articles....

Causal and Epistemic Relevance in Appeals to Authority

Directory of Open Access Journals (Sweden)

Sebastiano Lommi

2015-05-01

Full Text Available Appeals to authority have a long tradition in the history of argumentation theory. During the Middle Age they were considered legitimate and sound arguments, but after Locke’s treatment in the Essay Concerning Human Understanding their legitimacy has come under question. Traditionally, arguments from authority were considered informal arguments, but since the important work of Charles Hamblin (Hamblin, 1970 many attempts to provide a form for them have been done. The most convincing of them is the presumptive form developed by Douglas Walton and John Woods (Woods, Walton, 1974 that aims at taking into account the relevant contextual aspects in assessing the provisional validity of an appeal to authority. The soundness of an appeal depends on its meeting the adequacy conditions set to scrutinize all the relevant questions. I want to claim that this approach is compatible with the analysis of arguments in terms of relevance advanced by David Hitchcock (Hitchcock, 1992. He claims that relevance is a triadic relation between two items and a context. The first item is relevant to the second one in a given context. Different types of relevance relation exist, namely causal relevance and epistemic relevance. “Something is [causally] relevant to an outcome in a given situation if it helps to cause that outcome in the situation” (Hitchcock, 1992, p. 253, whereas it is epistemically relevant when it helps to achieve an epistemic goal in a given situation. I claim that we can adapt this conception to Walton and Krabbe’s theory of dialogue type (Walton, Krabbe, 1995, seeing the items of a relevance relation as the argument and its consequence and the context as the type of dialogue in which these arguments are advanced. According to this perspective, an argument from authority that meets the adequacy conditions has to be considered legitimate because it is an epistemically relevant relation. Therefore, my conclusion is that an analysis of appeals to

Making academic research more relevant: A few suggestions

Directory of Open Access Journals (Sweden)

Abinash Panda

2014-09-01

Full Text Available Academic research in the domain of management scholarship, though steeped in scientific and methodological rigour, is generally found to be of little relevance to practice. The authors of this paper have revisited the rigour-relevance debate in light of recent developments and with special reference to the management research scenario in India. The central thesis of the argument is that the gulf between rigour and relevance needs to be bridged to make academic research more relevant to business organizations and practitioners. They have offered some suggestions to enhance the relevance of academic research to practice.

Constitutional Law--State Action--Hiring and Promotion Practices of Private University Receiving Public Funds Held State Action--Braden v. University of Pittsburgh.

Science.gov (United States)

New York University Law Review, 1977

1977-01-01

In Braden vs University of Pittsburgh, a female professor filed suit against the University alleging sex discrimination in employment practices. The professor alleged that the school, which received state funds, was, in effect, a state actor and subject to constitutional restraints. This case and two relevant state action cases are discussed. (JMD)

Symposium: How (If at All is Gender Relevant to Comparative Philosophy?

Directory of Open Access Journals (Sweden)

Nkiru Nzegwu

2016-12-01

Full Text Available The symposium, “How (if at all is gender relevant to comparative philosophy,” focuses on relevance of gender as an analytic and critical tool in comparative philosophical understanding and debate. Nkiru Nzegwu argues that gender as conceived by contemporary Euro-American feminism did not exist in pre-colonial Yorùbá as well as many Native American societies, and that therefore employing gender as a conceptual category in understanding the philosophies of pre-colonial Yorùbá and other non-gendered societies constitutes a profound mistake. What’s more, doing so amounts to a totalizing Euro-American colonial imposition that does violence to nongendered societies that reject gender as an ontological category. Hence, gender is ill-suited as a universal comparative philosophical tool. Nzegwu’s three co-symposiasts, Mary I. Bockover, Maitrayee Chaudhuri, and María Luisa Femenías enrich and complicate this question by bringing to bear both conceptual, ethical and empirical considerations drawn from the United States, India, and Latin America respectively.

Probing polymer crystallization at processing-relevant cooling rates with synchrotron radiation

Energy Technology Data Exchange (ETDEWEB)

Cavallo, Dario, E-mail: Dario.cavallo@unige.it [University of Genoa, Dept. of Chemistry and Industrial Chemistry, Via Dodecaneso 31, 16146 Genoa (Italy); Portale, Giuseppe [ESRF, Dubble CRG, Netherlands Organization of Scientific Research (NWO), 38043 Grenoble (France); Androsch, René [Martin-Luther-University Halle-Wittenberg, Center of Engineering Sciences, D-06099 Halle/S. (Germany)

2015-12-17

Processing of polymeric materials to produce any kind of goods, from films to complex objects, involves application of flow fields on the polymer melt, accompanied or followed by its rapid cooling. Typically, polymers solidify at cooling rates which span over a wide range, from a few to hundreds of °C/s. A novel method to probe polymer crystallization at processing-relevant cooling rates is proposed. Using a custom-built quenching device, thin polymer films are ballistically cooled from the melt at rates between approximately 10 and 200 °C/s. Thanks to highly brilliant synchrotron radiation and to state-of-the-art X-ray detectors, the crystallization process is followed in real-time, recording about 20 wide angle X-ray diffraction patterns per second while monitoring the instantaneous sample temperature. The method is applied to a series of industrially relevant polymers, such as isotactic polypropylene, its copolymers and virgin and nucleated polyamide-6. Their crystallization behaviour during rapid cooling is discussed, with particular attention to the occurrence of polymorphism, which deeply impact material’s properties.

Quantum learning of coherent states

Energy Technology Data Exchange (ETDEWEB)

Sentis, Gael [Universitat Autonoma de Barcelona, Fisica Teorica: Informacio i Fenomens Quantics, Barcelona (Spain); Guta, Madalin; Adesso, Gerardo [University of Nottingham, School of Mathematical Sciences, Nottingham (United Kingdom)

2015-12-15

We develop a quantum learning scheme for binary discrimination of coherent states of light. This is a problem of technological relevance for the reading of information stored in a digital memory. In our setting, a coherent light source is used to illuminate a memory cell and retrieve its encoded bit by determining the quantum state of the reflected signal. We consider a situation where the amplitude of the states produced by the source is not fully known, but instead this information is encoded in a large training set comprising many copies of the same coherent state. We show that an optimal global measurement, performed jointly over the signal and the training set, provides higher successful identification rates than any learning strategy based on first estimating the unknown amplitude by means of Gaussian measurements on the training set, followed by an adaptive discrimination procedure on the signal. By considering a simplified variant of the problem, we argue that this is the case even for non-Gaussian estimation measurements. Our results show that, even in absence of entanglement, collective quantum measurements yield an enhancement in the readout of classical information, which is particularly relevant in the operating regime of low-energy signals. (orig.)

Quantum learning of coherent states

International Nuclear Information System (INIS)

Sentis, Gael; Guta, Madalin; Adesso, Gerardo

2015-01-01

We develop a quantum learning scheme for binary discrimination of coherent states of light. This is a problem of technological relevance for the reading of information stored in a digital memory. In our setting, a coherent light source is used to illuminate a memory cell and retrieve its encoded bit by determining the quantum state of the reflected signal. We consider a situation where the amplitude of the states produced by the source is not fully known, but instead this information is encoded in a large training set comprising many copies of the same coherent state. We show that an optimal global measurement, performed jointly over the signal and the training set, provides higher successful identification rates than any learning strategy based on first estimating the unknown amplitude by means of Gaussian measurements on the training set, followed by an adaptive discrimination procedure on the signal. By considering a simplified variant of the problem, we argue that this is the case even for non-Gaussian estimation measurements. Our results show that, even in absence of entanglement, collective quantum measurements yield an enhancement in the readout of classical information, which is particularly relevant in the operating regime of low-energy signals. (orig.)

A Compositional Relevance Model for Adaptive Information Retrieval

Science.gov (United States)

Mathe, Nathalie; Chen, James; Lu, Henry, Jr. (Technical Monitor)

1994-01-01

There is a growing need for rapid and effective access to information in large electronic documentation systems. Access can be facilitated if information relevant in the current problem solving context can be automatically supplied to the user. This includes information relevant to particular user profiles, tasks being performed, and problems being solved. However most of this knowledge on contextual relevance is not found within the contents of documents, and current hypermedia tools do not provide any easy mechanism to let users add this knowledge to their documents. We propose a compositional relevance network to automatically acquire the context in which previous information was found relevant. The model records information on the relevance of references based on user feedback for specific queries and contexts. It also generalizes such information to derive relevant references for similar queries and contexts. This model lets users filter information by context of relevance, build personalized views of documents over time, and share their views with other users. It also applies to any type of multimedia information. Compared to other approaches, it is less costly and doesn't require any a priori statistical computation, nor an extended training period. It is currently being implemented into the Computer Integrated Documentation system which enables integration of various technical documents in a hypertext framework.

Inferring relevance in a changing world

Directory of Open Access Journals (Sweden)

Robert C Wilson

2012-01-01

Full Text Available Reinforcement learning models of human and animal learning usually concentrate on how we learn the relationship between different stimuli or actions and rewards. However, in real world situations stimuli are ill-defined. On the one hand, our immediate environment is extremely multi-dimensional. On the other hand, in every decision-making scenario only a few aspects of the environment are relevant for obtaining reward, while most are irrelevant. Thus a key question is how do we learn these relevant dimensions, that is, how do we learn what to learn about? We investigated this process of representation learning experimentally, using a task in which one stimulus dimension was relevant for determining reward at each point in time. As in real life situations, in our task the relevant dimension can change without warning, adding ever-present uncertainty engendered by a constantly changing environment. We show that human performance on this task is better described by a suboptimal strategy based on selective attention and serial hypothesis testing rather than a normative strategy based on probabilistic inference. From this, we conjecture that the problem of inferring relevance in general scenarios is too computationally demanding for the brain to solve optimally. As a result the brain utilizes approximations, employing these even in simplified scenarios in which optimal representation learning is tractable, such as the one in our experiment.

Revolutionary land use change in the 21st century: Is (rangeland) science relevant?

Science.gov (United States)

Herrick, J.E.; Brown, J.R.; Bestelmeyer, B.T.; Andrews, S.S.; Baldi, G.; Davies, J.; Duniway, M.; Havstad, K.M.; Karl, J.W.; Karlen, D.L.; Peters, Debra P.C.; Quinton, J.N.; Riginos, C.; Shaver, P.L.; Steinaker, D.; Twomlow, S.

2012-01-01

Rapidly increasing demand for food, fiber, and fuel together with new technologies and the mobility of global capital are driving revolutionary changes in land use throughout the world. Efforts to increase land productivity include conversion of millions of hectares of rangelands to crop production, including many marginal lands with low resistance and resilience to degradation. Sustaining the productivity of these lands requires careful land use planning and innovative management systems. Historically, this responsibility has been left to agronomists and others with expertise in crop production. In this article, we argue that the revolutionary land use changes necessary to support national and global food security potentially make rangeland science more relevant now than ever. Maintaining and increasing relevance will require a revolutionary change in range science from a discipline that focuses on a particular land use or land cover to one that addresses the challenge of managing all lands that, at one time, were considered to be marginal for crop production. We propose four strategies to increase the relevance of rangeland science to global land management: 1) expand our awareness and understanding of local to global economic, social, and technological trends in order to anticipate and identify drivers and patterns of conversion; 2) emphasize empirical studies and modeling that anticipate the biophysical (ecosystem services) and societal consequences of large-scale changes in land cover and use; 3) significantly increase communication and collaboration with the disciplines and sectors of society currently responsible for managing the new land uses; and 4) develop and adopt a dynamic and flexible resilience-based land classification system and data-supported conceptual models (e.g., state-and-transition models) that represent all lands, regardless of use and the consequences of land conversion to various uses instead of changes in state or condition that are

Quantum electrodynamic effects for light and heavy nuclei

International Nuclear Information System (INIS)

Anon.

1973-01-01

The autoionization of positrons and the problem of vacuum polarization are discussed within the framework of quantum field theory. Various possible heavy ion experiments to check on the nonlinearity of electrodynamics are described. (8 figures) (U.S.)

Understanding solid state physics

CERN Document Server

Holgate, Sharon Ann

2009-01-01

Where Sharon Ann Holgate has succeeded in this book is in packing it with examples of the application of solid state physics to technology. … All the basic elements of solid state physics are covered … . The range of materials is good, including as it does polymers and glasses as well as crystalline solids. In general, the style makes for easy reading. … Overall this book succeeds in showing the relevance of solid state physics to the modern world … .-Contemporary Physics, Vol. 52, No. 2, 2011I was indeed amused and inspired by the wonderful images throughout the book, carefully selected by th

Reproducible and Verifiable Equations of State Using Microfabricated Materials

Science.gov (United States)

Martin, J. F.; Pigott, J. S.; Panero, W. R.

2017-12-01

Accurate interpretation of observable geophysical data, relevant to the structure, composition, and evolution of planetary interiors, requires precise determination of appropriate equations of state. We present the synthesis of controlled-geometry nanofabricated samples and insulation layers for the laser-heated diamond anvil cell. We present electron-gun evaporation, sputter deposition, and photolithography methods to mass-produce Pt/SiO2/Fe/SiO2 stacks and MgO insulating disks to be used in LHDAC experiments to reduce uncertainties in equation of state measurements due to large temperature gradients. We present a reanalysis of published iron PVT data to establish a statistically-valid extrapolation of the equation of state to inner core conditions with quantified uncertainties, addressing the complication of covariance in equation of state parameters. We use this reanalysis, together with the synthesized samples, to propose a scheme for measurement and validation of high-precision equations of state relevant to the Earth and super-Earth exoplanets.

The spectra of supersymmetric states in string theory

NARCIS (Netherlands)

Cheng, M.C.N.

2008-01-01

In this thesis we study the spectra of supersymmetric states in string theory compactifications with eight and sixteen supercharges, with special focus placed on the quantum states of black holes and the phenomenon of wall-crossing in these theories. A self-contained introduction to the relevant

Toward the Relevance of Platelet Subpopulations for Transfusion Medicine

Directory of Open Access Journals (Sweden)

Stefan Handtke

2018-02-01

Full Text Available Circulating platelets consist of subpopulations with different age, maturation state and size. In this review, we address the association between platelet size and platelet function and summarize the current knowledge on platelet subpopulations including reticulated platelets, procoagulant platelets and platelets exposing signals to mediate their clearance. Thereby, we emphasize the impact of platelet turnover as an important condition for platelet production in vivo. Understanding of the features that characterize platelet subpopulations is very relevant for the methods of platelet concentrate production, which may enrich or deplete particular platelet subpopulations. Moreover, the concept of platelet size being associated with platelet function may be attractive for transfusion medicine as it holds the perspective to separate platelet subpopulations with specific functional capabilities.

The Arthasastra: Assessing the Contemporary Relevance of an Ancient Indian Treatise on Statecraft

Science.gov (United States)

2016-06-10

12 Kauṭilya, The Arthashastra, trans. L N. Rangarajan (New Delhi: Penguin Books India, 1992), Kindle Location 562-571. Hereafter refered to as...of power. Hard power refers to a state’s influence originating from coercive usage of military and economic capability of a state. On the other hand... economic spectrum of a state’s affairs, this paper identifies concepts relevant to the modern idea of national power and uses them to assess China’s geo

The policy relevance of global environmental change research

International Nuclear Information System (INIS)

Yarnal, Brent

1996-01-01

Many scientists are striving to identify and promote the policy implications of their global change research. Much basic research on global environmental change cannot advance policy directly, but new projects can determine the relevance of their research to decision makers and build policy-relevant products into the work. Similarly, many ongoing projects can alter or add to the present science design to make the research policy relevant. Thus, this paper shows scientists working on global change how to make their research policy relevant. It demonstrates how research on physical global change relates to human dimensions studies and integrated assessments. It also presents an example of how policy relevance can be fit retroactively into a global change project (in this case, SRBEX-the Susquehanna River Basin Experiment) and how that addition can enhance the project's status and science. The paper concludes that policy relevance is desirable from social and scientific perspectives

Does relevance matter in academic policy research?

DEFF Research Database (Denmark)

Dredge, Dianne

2015-01-01

A reflection on whether relevance matters in tourism policy research. A debate among tourism scholars.......A reflection on whether relevance matters in tourism policy research. A debate among tourism scholars....

Community wind power ownership schemes in Europe and their relevance to the United States

Energy Technology Data Exchange (ETDEWEB)

Bolinger, Mark

2001-05-15

With varying success, the United States and Europe have followed a more or less parallel path of policies to support wind development over the past twenty years. Feed-in laws and tax incentives first popularized in California in the early 1980s and greatly expanded upon in Europe during the 1990s are gradually giving way to market-based support mechanisms such as renewable portfolio standards, which are being implemented in one form or another in ten US states and at least three European nations. At the same time, electricity markets are being liberalized in both the US and Europe, and many electricity consumers are being given the choice to support the development of renewable energy through higher tariffs, both in traditionally regulated and newly competitive markets. One notable area in which wind development in Europe and United States has not evolved in common, however, is with respect to the level of community ownership of wind turbines or clusters. While community ownership of wind projects is unheard of in the United States, in Europe, local wind cooperatives or other participatory business schemes have been responsible for a large share of total wind development. In Denmark, for example, approximately 80% of all wind turbines are either individually or cooperatively owned, and a similar pattern holds in Germany, the world leader in installed wind capacity. Sweden also has a strong wind cooperative base, and the UK has recently made forays into community wind ownership. Why is it that wind development has evolved this way in Europe, but not in the United States? What incremental effect have community-owned wind schemes had on European wind development? Have community-owned wind schemes driven development in Europe, or are they merely a vehicle through which the fundamental driving institutions have been channeled? Is there value to having community wind ownership in the US? Is there reason to believe that such schemes would succeed in the US? If so, which

Uses of solid state analogies in elementary particle theory

International Nuclear Information System (INIS)

Anderson, P.W.

1976-01-01

The solid state background of some of the modern ideas of field theory is reviewed, and additional examples of model situations in solid state or many-body theory which may have relevance to fundamental theories of elementary particles are adduced

Activity flow over resting-state networks shapes cognitive task activations.

Science.gov (United States)

Cole, Michael W; Ito, Takuya; Bassett, Danielle S; Schultz, Douglas H

2016-12-01

Resting-state functional connectivity (FC) has helped reveal the intrinsic network organization of the human brain, yet its relevance to cognitive task activations has been unclear. Uncertainty remains despite evidence that resting-state FC patterns are highly similar to cognitive task activation patterns. Identifying the distributed processes that shape localized cognitive task activations may help reveal why resting-state FC is so strongly related to cognitive task activations. We found that estimating task-evoked activity flow (the spread of activation amplitudes) over resting-state FC networks allowed prediction of cognitive task activations in a large-scale neural network model. Applying this insight to empirical functional MRI data, we found that cognitive task activations can be predicted in held-out brain regions (and held-out individuals) via estimated activity flow over resting-state FC networks. This suggests that task-evoked activity flow over intrinsic networks is a large-scale mechanism explaining the relevance of resting-state FC to cognitive task activations.

Mode and polarization state selected guided wave spectroscopy of orientational anisotrophy in model membrane cellulosic polymer films: relevance to lab-on-a-chip

Science.gov (United States)

Andrews, Mark P.; Kanigan, Tanya

2007-06-01

Orientation anisotropies in structural properties relevant to the use of cellulosic polymers as membranes for lab-on-chips were investigated for cellulose acetate (CA) and regenerated cellulose (RC) films deposited as slab waveguides. Anisotropy was probed with mode and polarization state selected guided wave Raman spectroscopy. CA exhibits partial chain orientation in the plane of the film, and this orientation is independent of sample substrate and film preparation conditions. RC films also show in-plane anisotropy, where the hexose sugar rings lie roughly in the plane of the film. Explanations are given of the role of artifacts in interpreting waveguide Raman spectra, including anomalous contributions to Raman spectra that arise from deviations from right angle scattering geometry, mode-dependent contributions to longitudinal electric field components and TETM mode conversion. We explore diffusion profiles of small molecules in cellulosic films by adaptations of an inverse-Wentzel-Kramers-Brillouin (iWKB) recursive, noninteger virtual mode index algorithm. Perturbations in the refractive index distribution, n(z), are recovered from the measured relative propagation constants, neffective,m, of the planar waveguide. The refractive index distribution then yields the diffusion profile.

Quantum information with Gaussian states

International Nuclear Information System (INIS)

Wang Xiangbin; Hiroshima, Tohya; Tomita, Akihisa; Hayashi, Masahito

2007-01-01

Quantum optical Gaussian states are a type of important robust quantum states which are manipulatable by the existing technologies. So far, most of the important quantum information experiments are done with such states, including bright Gaussian light and weak Gaussian light. Extending the existing results of quantum information with discrete quantum states to the case of continuous variable quantum states is an interesting theoretical job. The quantum Gaussian states play a central role in such a case. We review the properties and applications of Gaussian states in quantum information with emphasis on the fundamental concepts, the calculation techniques and the effects of imperfections of the real-life experimental setups. Topics here include the elementary properties of Gaussian states and relevant quantum information device, entanglement-based quantum tasks such as quantum teleportation, quantum cryptography with weak and strong Gaussian states and the quantum channel capacity, mathematical theory of quantum entanglement and state estimation for Gaussian states

Contribution to simple and double photoionization studies in several molecules excited by synchrotron radiation

International Nuclear Information System (INIS)

Lablanquie, Pascal

1984-01-01

This work is divided into two parts. Photoelectron spectrometry has enabled us to study the simple photoionisation in inner and outer shell of the N 2 molecule. The limits of an independent particle model, and the importance of electronic interactions have been outlined; an analysis of the structures situated at a photon energy of 23 eV revealed the behavior of two kinds of autoionizing states; the shape resonances of the Σ g + states have been compared. We have then built a new experimental set-up to study double photoionisation. The case of the CS 2 molecule has been examined by mass spectrometry associated to a PIPICO (PhotoIon-PhotoIon Coincidence) technique. An approach of the spectroscopy of the CS 2 ++ ion has been proposed; two dissociation paths of the ion have been observed, their mechanisms are discussed. (author) [fr

Relevance of Indian Summer Monsoon and its Tropical Indo-Pacific Climate Drivers for the Kharif Crop Production

Science.gov (United States)

Amat, Hemadri Bhusan; Karumuri, Ashok

2017-12-01

While the Indian agriculture has earlier been dependent on the Indian summer monsoon rainfall (ISMR), a multifold increase in irrigation and storage facilities raise a question whether the ISMR is still as relevant. We revisit this question using the latest observational climate datasets as well as the crop production data and find that the ISMR is still relevant for the Kharif crop production (KCP). In addition, in the recent changes in the tropical Indo-Pacific driver evolutions and frequency, particularly more frequent occurrence of the ENSO Modokis in place of the canonical ENSOs, we carry out a correlation analysis to estimate the impact of the various Indo-Pacific climate drivers on the rainfall of individual Indian states for the period 1998-2013, for which crop production data for the most productive Indian states, namely West Bengal, Odisha, United Andhra Pradesh (UAP), Haryana, Punjab, Karnataka, Kerala, Madhya Pradesh, Bihar and Uttar Pradesh are available. The results suggest that the KCP of the respective states are significantly correlated with the summer monsoon rainfall at the 95-99% confidence levels. Importantly, we find that the NINO 3.4 and ENSO Modoki indices have a statistically significant correlation with the KCP of most of the Indian states, particularly in states such as UAP and Karnataka, through induction of anomalous local convergence/divergence, well beyond the equatorial Indian Ocean. The KCP of districts in UAP also has a significant response to all the climate drivers, having implication for prediction of local crop yield.

Kinetic studies following state-selective laser excitation

International Nuclear Information System (INIS)

Keto, J.W.

1991-01-01

During the past year, we have made measurements of state-to-state energy transfer cross sections and radiative lifetimes for Xe*(6p,6p',7p) and Kr*(5p) states in xenon and krypton buffer gases. These results are relevant to kinetic models of both excimer lasers and the infrared xenon laser; and they are a significant improvement in the precision of the known radiative lifetimes. 3 refs., 2 figs., 2 tabs

Photoionization of FE3+ Ions

International Nuclear Information System (INIS)

Ovchinnikov, O.; Schlachter, F.

2003-01-01

Photoionization of Fe3+ ions was studied for the first time using synchrotron radiation from the Advanced Light Source (ALS) and the merged-beams technique. Fe3+ ions were successfully produced using ferrocene in an electron cyclotron resonance ion source (ECR). The measured yield of Fe4+ photoions as a function of photon energy revealed the presence of resonances that correspond to excitation of autoionizing states. These resonances are superimposed upon the photoion yield produced by direct photoionization, which is a smooth, slowly decreasing function of energy. The spectra for the photoionization of Fe3+ will be analyzed and compared with theory. The data collected will also serve to test models for the propagation of light through ionized matter.

Electron-helium S-wave model benchmark calculations. II. Double ionization, single ionization with excitation, and double excitation

Science.gov (United States)

Bartlett, Philip L.; Stelbovics, Andris T.

2010-02-01

The propagating exterior complex scaling (PECS) method is extended to all four-body processes in electron impact on helium in an S-wave model. Total and energy-differential cross sections are presented with benchmark accuracy for double ionization, single ionization with excitation, and double excitation (to autoionizing states) for incident-electron energies from threshold to 500 eV. While the PECS three-body cross sections for this model given in the preceding article [Phys. Rev. A 81, 022715 (2010)] are in good agreement with other methods, there are considerable discrepancies for these four-body processes. With this model we demonstrate the suitability of the PECS method for the complete solution of the electron-helium system.

US-Japan workshop on atomic collisions in solids: Abstracts of lectures

International Nuclear Information System (INIS)

1990-03-01

This report contains abstracts on the following topics: techniques of scanning probe microscopy; new types of radiation; a search for wake-riding electrons using slow antiproton beams; antiproton wake: theory; bending of swift ion beams by graphite foils; angular momentum distribution of autoionizing rydberg states: produced by 64 MeV S ions in collisions with C foils; multiphonon energy exchange in atom-surface collisions; plans for positron experiments; resonant coherent excitation: experiment; line shapes in resonant coherent excitation: theory; MUSE experiments and Monte Carlo simulation; inelastic interactions of electrons and positrons with solids; density fluctuation detection; cluster-impact fusion; a model for cluster-impact fusion; thoughts on cold fusion; and plasmon decay

L-shell photoabsorption spectroscopy for solid metals: Ti, V, Cr, Fe, Ni, Cu

International Nuclear Information System (INIS)

Del Grande, N.K.

1989-01-01

Synchrotron radiation measurements of near-threshold and broad-range (400--1500 eV) absolute photoabsorption cross sections were made for five transition metals with ±10% overall uncertainties. Fine structure details of 2p-3d autoionizing resonances are shown with better than 1.0 eV resolution for solid metals: Ti, V, Cr, Fe, Ni, and Cu. Fine structure similar to what we measured can be produced using a multi-configuration Dirac Fock (MCDF) model if a statistical distribution is assumed for the initial atomic states. Calculations were performed in intermediate coupling with configuration interactions by Mau H. Chen. The results are compared with other experimental work and theoretical methodologies. 18 refs., 7 figs

Nonadiabatic excited-state molecular dynamics: On-the-fly limiting of essential excited states

Energy Technology Data Exchange (ETDEWEB)

Nelson, Tammie [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Naumov, Artem [Skolkovo Institute of Science and Technology, Moscow 143026 (Russian Federation); Fernandez-Alberti, Sebastian [Universidad Nacional de Quilmes, Roque Saenz Pea 352, B1876BXD Bernal (Argentina); Tretiak, Sergei, E-mail: serg@lanl.gov [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

2016-12-20

The simulation of nonadiabatic dynamics in extended molecular systems involving hundreds of atoms and large densities of states is particularly challenging. Nonadiabatic coupling terms (NACTs) represent a significant numerical bottleneck in surface hopping approaches. Rather than using unreliable NACT cutting schemes, here we develop “on-the-fly” state limiting methods to eliminate states that are no longer essential for the non-radiative relaxation dynamics as a trajectory proceeds. We propose a state number criteria and an energy-based state limit. The latter is more physically relevant by requiring a user-imposed energy threshold. For this purpose, we introduce a local kinetic energy gauge by summing contributions from atoms within the spatial localization of the electronic wavefunction to define the energy available for upward hops. The proposed state limiting schemes are implemented within the nonadiabatic excited-state molecular dynamics framework to simulate photoinduced relaxation in poly-phenylene vinylene (PPV) and branched poly-phenylene ethynylene (PPE) oligomers for benchmark evaluation.

Doubly excited helium. From strong correlation to chaos

Energy Technology Data Exchange (ETDEWEB)

Jiang, Yuhai

2006-03-15

In the present dissertation, the double excitation states of helium including the autoionization decay of these states were studied experimentally and theoretically in a broad energy region, which includes the transition from strong correlation below the low single ionization thresholds (SIT) to the region of quantum chaos at energies very close to the double-ionization threshold. Two kind of experiments were performed, namely total-ion-yield measurements with the aim to observe total cross sections (TCS) and electron time-of-flight (TOF) measurements to obtain partial cross sections (PCS) as well as angular distribution parameters (ADP). Both types of measurements were performed at the third generation synchrotron radiation facility BESSY II in Berlin. The TCSs were recorded up to the SIT I{sub 15}, and they were found to be in in excellent agreement with state-of-the-art complex-rotation calculations performed recently by D. Delande. These experimental and theoretical data on the TCSs were analyzed in order to study quantum chaos in doubly excited helium, and interesting signatures of quantum chaos were found. The TOF technique allowed to measure PCSs and ADPs in the energy regions from I{sub 5} to I{sub 9} and I{sub 7}, respectively. These experimental data provide a critical assessment of theoretical models that can be used to explore the dynamics of strong correlation as well as quantum chaos in helium. In the theoretical part of this dissertation, the n- and l-specific PCSs and ADPs below I{sub 4} were calculated employing the R-matrix method. The present theoretical results agree well with a recent experimental study of l-specific PCSs below I{sub 4} by J.R. Harries et al. An analysis of patterns in the PCSs and ADPs on the basis of the present experimental and theoretical l-specific data allowed to improve the present understanding of autoionization decay dynamics in this two-electron atom. (orig.)

Electron stripping cross sections for light impurity ions in colliding with atomic hydrogens relevant to fusion research

International Nuclear Information System (INIS)

Tawara, H.

1992-04-01

Electron stripping (ionization) cross sections for impurity (carbon) ions with various charge states in collisions with atomic hydrogens have been surveyed. It has been found that these data are relatively limited both in collision energy and charge state and, in particular those necessary for high energy neutral beam injection (NBI) heating in fusion plasma research are scarce. Some relevant cross sections for carbon ions, C q+ (q = 0-5) have been estimated, based upon the existing data, empirical behavior and electron impact ionization data. (author)

Feature relevance assessment for the semantic interpretation of 3D point cloud data

Directory of Open Access Journals (Sweden)

M. Weinmann

2013-10-01

Full Text Available The automatic analysis of large 3D point clouds represents a crucial task in photogrammetry, remote sensing and computer vision. In this paper, we propose a new methodology for the semantic interpretation of such point clouds which involves feature relevance assessment in order to reduce both processing time and memory consumption. Given a standard benchmark dataset with 1.3 million 3D points, we first extract a set of 21 geometric 3D and 2D features. Subsequently, we apply a classifier-independent ranking procedure which involves a general relevance metric in order to derive compact and robust subsets of versatile features which are generally applicable for a large variety of subsequent tasks. This metric is based on 7 different feature selection strategies and thus addresses different intrinsic properties of the given data. For the example of semantically interpreting 3D point cloud data, we demonstrate the great potential of smaller subsets consisting of only the most relevant features with 4 different state-of-the-art classifiers. The results reveal that, instead of including as many features as possible in order to compensate for lack of knowledge, a crucial task such as scene interpretation can be carried out with only few versatile features and even improved accuracy.

Development of selective photoionization spectroscopy technology - Development of a computer program to calculate selective ionization of atoms with multistep processes

Energy Technology Data Exchange (ETDEWEB)

Kim, Young Soon; Nam, Baek Il [Myongji University, Seoul (Korea, Republic of)

1995-08-01

We have developed computer programs to calculate 2-and 3-step selective resonant multiphoton ionization of atoms. Autoionization resonances in the final continuum can be put into account via B-Spline basis set method. 8 refs., 5 figs. (author)

Evaluating automatic attentional capture by self-relevant information.

Science.gov (United States)

Ocampo, Brenda; Kahan, Todd A

2016-01-01

Our everyday decisions and memories are inadvertently influenced by self-relevant information. For example, we are faster and more accurate at making perceptual judgments about stimuli associated with ourselves, such as our own face or name, as compared with familiar non-self-relevant stimuli. Humphreys and Sui propose a "self-attention network" to account for these effects, wherein self-relevant stimuli automatically capture our attention and subsequently enhance the perceptual processing of self-relevant information. We propose that the masked priming paradigm and continuous flash suppression represent two ways to experimentally examine these controversial claims.

A review of electrochemistry of relevance to environment-assisted cracking in light water reactors

International Nuclear Information System (INIS)

Turnbull, A.; Psaila-Dombrowski, M.

1992-01-01

The electrochemistry of relevance to environment-assisted cracking in high temperature, low conductivity water is critically reviewed. The review covers corrosion potential and electrochemical polarisation measurements, thermodynamics, and also experimental measurements and mathematical modelling of the electrochemistry in cracks and crevices. There is a lack of critical data in relation to the electrode kinetics of relevant cathodic reduction reactions, namely H + , H 2 O, O 2 , H 2 O 2 and steady-state anodic reaction data are limited. Transient anodic current measurements, associated with initially film-free metal, have been made for a range of conditions but there is uncertainty regarding the role of fluid flow and transport processes on the current decay characteristics. A number of experimental measurements of potential and pH in crevices and cracks have been made but the experiments are difficult to carry out reliably and hence the range of data of relevance to practical conditions is very limited. Recent developments in mathematical modelling have significantly enhanced the qualitative understanding of the processes controlling the local electrochemistry in cracks and crevices but the reliability of the quantitative predictions is limited by the paucity of reliable input data. (Author)

Reflections on relevance: Psychotherapy and Psychosomatics in 2004.

Science.gov (United States)

Balon, Richard

2005-01-01

Relevance of an article is a highly desirable yet hardly predictable quality at the time of its publication. Article relevance is frequently measured by the impact factor of the journal where the article is published. Furthermore, impact factor, citation index and citation analysis are used as a measure of research progress and scientific wealth of a nation. The wisdom and significance of this approach to relevance is debatable and thus discussed here. In 2004, Psychotherapy and Psychosomatics published a variety of articles which, in the author's view, are clinically relevant. Several selected clinically relevant issues reviewed in this article include: the conceptualization of fibromyalgia as a stress disorder; the psychosocial impact and psychosocial interventions in cancer; the impact of alexithymia on patient care; the possible relationship between depression and nutrition (namely intake of folate and pyridoxal phosphate); the significance of hypercoagulability in panic-like anxiety; the questionable value of single isomer drugs, and the relevance and adequacy of clinimetrics versus psychometrics in clinical research. The reviewed issues seem to be relevant to clinical practice, research or both, but also to our critical thinking, and the critical review of the developments in psychiatry and psychology. Copyright 2005 S. Karger AG, Basel.

46 CFR 560.5 - Receipt of relevant information.

Science.gov (United States)

2010-10-01

... 46 Shipping 9 2010-10-01 2010-10-01 false Receipt of relevant information. 560.5 Section 560.5... FOREIGN PORTS § 560.5 Receipt of relevant information. (a) In making its decision on matters arising under... submissions should be supported by affidavits of fact and memorandum of law. Relevant information may include...

Relevance in the science classroom: A multidimensional analysis

Science.gov (United States)

Hartwell, Matthew F.

While perceived relevance is considered a fundamental component of adaptive learning, the experience of relevance and its conceptual definition have not been well described. The mixed-methods research presented in this dissertation aimed to clarify the conceptual meaning of relevance by focusing on its phenomenological experience from the students' perspective. Following a critical literature review, I propose an identity-based model of perceived relevance that includes three components: a contextual target, an identity target, and a connection type, or lens. An empirical investigation of this model that consisted of two general phases was implemented in four 9th grade-biology classrooms. Participants in Phase 1 (N = 118) completed a series of four open-ended writing activities focused on eliciting perceived personal connections to academic content. Exploratory qualitative content analysis of a 25% random sample of the student responses was used to identify the main meaning-units of the proposed model as well as different dimensions of student relevance perceptions. These meaning-units and dimensions provided the basis for the construction of a conceptual mapping sentence capturing students' perceived relevance, which was then applied in a confirmatory analysis to all other student responses. Participants in Phase 2 (N = 139) completed a closed survey designed based on the mapping sentence to assess their perceived relevance of a biology unit. The survey also included scales assessing other domain-level motivational processes. Exploratory factor analysis and non-metric multidimensional scaling indicated a coherent conceptual structure, which included a primary interpretive relevance dimension. Comparison of the conceptual structure across various groups (randomly-split sample, gender, academic level, domain-general motivational profiles) provided support for its ubiquity and insight into variation in the experience of perceived relevance among students of different

Ultrafast quantum control of ionization dynamics in krypton.

Science.gov (United States)

Hütten, Konrad; Mittermair, Michael; Stock, Sebastian O; Beerwerth, Randolf; Shirvanyan, Vahe; Riemensberger, Johann; Duensing, Andreas; Heider, Rupert; Wagner, Martin S; Guggenmos, Alexander; Fritzsche, Stephan; Kabachnik, Nikolay M; Kienberger, Reinhard; Bernhardt, Birgitta

2018-02-19

Ultrafast spectroscopy with attosecond resolution has enabled the real time observation of ultrafast electron dynamics in atoms, molecules and solids. These experiments employ attosecond pulses or pulse trains and explore dynamical processes in a pump-probe scheme that is selectively sensitive to electronic state of matter via photoelectron or XUV absorption spectroscopy or that includes changes of the ionic state detected via photo-ion mass spectrometry. Here, we demonstrate how the implementation of combined photo-ion and absorption spectroscopy with attosecond resolution enables tracking the complex multidimensional excitation and decay cascade of an Auger auto-ionization process of a few femtoseconds in highly excited krypton. In tandem with theory, our study reveals the role of intermediate electronic states in the formation of multiply charged ions. Amplitude tuning of a dressing laser field addresses different groups of decay channels and allows exerting temporal and quantitative control over the ionization dynamics in rare gas atoms.

Does relevance matter in academic policy research

DEFF Research Database (Denmark)

Dredge, Dianne

2015-01-01

A reflection on whether relevance matters in tourism policy research, and if so, to whom/what should it matter......A reflection on whether relevance matters in tourism policy research, and if so, to whom/what should it matter...

The foundation of the concept of relevance

DEFF Research Database (Denmark)

Hjørland, Birger

2010-01-01

that what was regarded as the most fundamental view by Saracevic in 1975 has not since been considered (with very few exceptions). Other views, which are based on less fruitful assumptions, have dominated the discourse on relevance in information retrieval and information science. Many authors have...... reexamined the concept of relevance in information science, but have neglected the subject knowledge view, hence basic theoretical assumptions seem not to have been properly addressed. It is as urgent now as it was in 1975 seriously to consider “the subject knowledge view” of relevance (which may also...... be termed “the epistemological view”). The concept of relevance, like other basic concepts, is influenced by overall approaches to information science, such as the cognitive view and the domain-analytic view. There is today a trend toward a social paradigm for information science. This paper offers...

Has Financial Statement Information become Less Relevant?

DEFF Research Database (Denmark)

Thinggaard, Frank; Damkier, Jesper

This paper presents insights into the question of whether accounting information based on the EU’s Accounting Directives has become less value-relevant to investors over time. The study is based on a research design first used by Francis and Schipper (1999), where value-relevance is measured......? The sample is based on non-financial companies listed on the Copenhagen Stock Exchange in the period 1984-2002. Our analyses show that all the applied accounting measures are value-relevant as investment strategies based on the information earn positive market-adjusted returns in our sample period....... The results provide some indication of a decline in the value-relevance of earnings information in the 1984-2001 period, and mixed, but not statistically reliable, evidence for accounting measures where book value information and asset values are also extracted from financial statements. The results seem...

Oil spill response issues in Washington State

International Nuclear Information System (INIS)

Lempriere, P.R.

1997-01-01

Washington State statutes and regulations applicable to oil transport and oil spills were described. Specific provisions of the statutes and regulations and other relevant matters were also discussed. Among these were: (1) Washington State oil spill prevention plans, (2) Washington State oil spill contingency plans, (3) best achievable protection, (4) Intertanko's lawsuit against Washington State, (5) oil spill removal organizations, (6) certificates of financial responsibility in Washington State, (7) extent of potential liability under Washington Law, (8) disposal of cleanup materials, and (9) definition of 'qualified individuals' on marine vessels having the authority to implement removal actions

State dependent pseudo-resonances and excess noise

OpenAIRE

Papoff, F.; D'Alessandro, G.; Oppo, G.Luca

2008-01-01

We show that strong response to nonresonant modulations and excess noise are state dependent in generic nonlinear systems; i.e., they affect some output states but are absent from others. This is demonstrated in complex Swift-Hohenberg models relevant to optics, where it is caused by the non-normality of the linearized stability operators around selected output states, even though the cavity modes are orthogonal. In particular, we find the effective parameters that control excess noise and th...

Relevant cost information for order acceptance decisions

NARCIS (Netherlands)

Wouters, M.J.F.

1997-01-01

Some economic considerations for order acceptance decisions are discussed. The relevant economic considerations for order acceptance are widely discussed in the literature: only those costs are relevant which would be avoidable by not accepting the order incremental costs plus opportunity costs .

Macroscale hydrologic modeling of ecologically relevant flow metrics

Science.gov (United States)

Wenger, Seth J.; Luce, Charles H.; Hamlet, Alan F.; Isaak, Daniel J.; Neville, Helen M.

2010-09-01

Stream hydrology strongly affects the structure of aquatic communities. Changes to air temperature and precipitation driven by increased greenhouse gas concentrations are shifting timing and volume of streamflows potentially affecting these communities. The variable infiltration capacity (VIC) macroscale hydrologic model has been employed at regional scales to describe and forecast hydrologic changes but has been calibrated and applied mainly to large rivers. An important question is how well VIC runoff simulations serve to answer questions about hydrologic changes in smaller streams, which are important habitat for many fish species. To answer this question, we aggregated gridded VIC outputs within the drainage basins of 55 streamflow gages in the Pacific Northwest United States and compared modeled hydrographs and summary metrics to observations. For most streams, several ecologically relevant aspects of the hydrologic regime were accurately modeled, including center of flow timing, mean annual and summer flows and frequency of winter floods. Frequencies of high and low flows in the summer were not well predicted, however. Predictions were worse for sites with strong groundwater influence, and some sites showed errors that may result from limitations in the forcing climate data. Higher resolution (1/16th degree) modeling provided small improvements over lower resolution (1/8th degree). Despite some limitations, the VIC model appears capable of representing several ecologically relevant hydrologic characteristics in streams, making it a useful tool for understanding the effects of hydrology in delimiting species distributions and predicting the potential effects of climate shifts on aquatic organisms.

PRESERVATION OF ARCHAEOLOGICAL MATERIALS IN ARID ENVIRONMENTS RELEVANT TO YUCCA MOUNTAIN

International Nuclear Information System (INIS)

N. Chapman, A. Dansie, C. McCombie

2006-01-01

The objective of this study was to evaluate archaeological materials from underground openings or shallow burial in arid environments relevant to Yucca Mountain and to draw conclusions about how their state and their environment of preservation could be of relevance to design and operational aspects of the high-level waste repository. The study has evaluated materials from cultures in the arid regions of the ancient Middle East and compared them with the preservation of ancient materials in dry cave sites in the Great Basin desert area of Nevada. The emphasis has been on materials found in undisturbed underground openings such as caves and un-backfilled tombs. Long-term preservation of such materials in underground openings and the stability of the openings themselves provide useful analogue information that serves as a reference point for considering the operation and evolution of the Yucca Mountain repository. Being able to shed light, by close physical and environmental analogy, on what happens in underground openings over many thousands of years provides valuable underpinning to illustrations of expected system performance and offers pointers towards optimizing repository system and operational design

Using small XML elements to support relevance

NARCIS (Netherlands)

G. Ramirez Camps (Georgina); T.H.W. Westerveld (Thijs); A.P. de Vries (Arjen)

2006-01-01

htmlabstractSmall XML elements are often estimated relevant by the retrieval model but they are not desirable retrieval units. This paper presents a generic model that exploits the information obtained from small elements. We identify relationships between small and relevant elements and use this

Passage relevance models for genomics search

Directory of Open Access Journals (Sweden)

Frieder Ophir

2009-03-01

Full Text Available Abstract We present a passage relevance model for integrating syntactic and semantic evidence of biomedical concepts and topics using a probabilistic graphical model. Component models of topics, concepts, terms, and document are represented as potential functions within a Markov Random Field. The probability of a passage being relevant to a biologist's information need is represented as the joint distribution across all potential functions. Relevance model feedback of top ranked passages is used to improve distributional estimates of query concepts and topics in context, and a dimensional indexing strategy is used for efficient aggregation of concept and term statistics. By integrating multiple sources of evidence including dependencies between topics, concepts, and terms, we seek to improve genomics literature passage retrieval precision. Using this model, we are able to demonstrate statistically significant improvements in retrieval precision using a large genomics literature corpus.

Clinically relevant incidental cardiovascular findings in CT examinations

International Nuclear Information System (INIS)

Voigt, P.; Fahnert, J.; Kahn, T.; Surov, A.; Schramm, D.; Bach, A.G.

2017-01-01

Incidental cardiovascular findings are a frequent phenomenon in computed tomography (CT) examinations. As the result of a dedicated PubMed search this article gives a systemic overview of the current literature on the most important incidental cardiovascular findings, their prevalence and clinical relevance. The majority of incidental cardiovascular findings are of only low clinical relevance; however, highly relevant incidental findings, such as aortic aneurysms, thromboses and thromboembolic events can also occasionally be found, especially in oncology patients. The scans from every CT examination should also be investigated for incidental findings as they can be of decisive importance for the further clinical management of patients, depending on their clinical relevance. (orig.) [de

Shippingport: A relevant decommissioning project

International Nuclear Information System (INIS)

Crimi, F.P.

1988-01-01

Because of Shippingport's low electrical power rating (72 MWe), there has been some misunderstanding on the relevancy of the Shippingport Station Decommissioning Project (SSDP) to a modern 1175 MWe commercial pressurized water reactor (PWR) power station. This paper provides a comparison of the major components of the reactor plant of the 72 MWe Shippingport Atomic Power Station and an 1175 MWe nuclear plant and the relevancy of the Shippingport decommissioning as a demonstration project for the nuclear industry. For the purpose of this comparison, Portland General Electric Company's 1175 MWe Trojan Nuclear Plant at Rainier, Oregon, has been used as the reference nuclear power plant. 2 refs., 2 figs., 1 tab

Clinical Relevance of Adipokines

Directory of Open Access Journals (Sweden)

Matthias Blüher

2012-10-01

Full Text Available The incidence of obesity has increased dramatically during recent decades. Obesity increases the risk for metabolic and cardiovascular diseases and may therefore contribute to premature death. With increasing fat mass, secretion of adipose tissue derived bioactive molecules (adipokines changes towards a pro-inflammatory, diabetogenic and atherogenic pattern. Adipokines are involved in the regulation of appetite and satiety, energy expenditure, activity, endothelial function, hemostasis, blood pressure, insulin sensitivity, energy metabolism in insulin sensitive tissues, adipogenesis, fat distribution and insulin secretion in pancreatic β-cells. Therefore, adipokines are clinically relevant as biomarkers for fat distribution, adipose tissue function, liver fat content, insulin sensitivity, chronic inflammation and have the potential for future pharmacological treatment strategies for obesity and its related diseases. This review focuses on the clinical relevance of selected adipokines as markers or predictors of obesity related diseases and as potential therapeutic tools or targets in metabolic and cardiovascular diseases.

When is a randomised controlled trial health equity relevant? Development and validation of a conceptual framework.

Science.gov (United States)

Jull, J; Whitehead, M; Petticrew, M; Kristjansson, E; Gough, D; Petkovic, J; Volmink, J; Weijer, C; Taljaard, M; Edwards, S; Mbuagbaw, L; Cookson, R; McGowan, J; Lyddiatt, A; Boyer, Y; Cuervo, L G; Armstrong, R; White, H; Yoganathan, M; Pantoja, T; Shea, B; Pottie, K; Norheim, O; Baird, S; Robberstad, B; Sommerfelt, H; Asada, Y; Wells, G; Tugwell, P; Welch, V

2017-09-25

Randomised controlled trials can provide evidence relevant to assessing the equity impact of an intervention, but such information is often poorly reported. We describe a conceptual framework to identify health equity-relevant randomised trials with the aim of improving the design and reporting of such trials. An interdisciplinary and international research team engaged in an iterative consensus building process to develop and refine the conceptual framework via face-to-face meetings, teleconferences and email correspondence, including findings from a validation exercise whereby two independent reviewers used the emerging framework to classify a sample of randomised trials. A randomised trial can usefully be classified as 'health equity relevant' if it assesses the effects of an intervention on the health or its determinants of either individuals or a population who experience ill health due to disadvantage defined across one or more social determinants of health. Health equity-relevant randomised trials can either exclusively focus on a single population or collect data potentially useful for assessing differential effects of the intervention across multiple populations experiencing different levels or types of social disadvantage. Trials that are not classified as 'health equity relevant' may nevertheless provide information that is indirectly relevant to assessing equity impact, including information about individual level variation unrelated to social disadvantage and potentially useful in secondary modelling studies. The conceptual framework may be used to design and report randomised trials. The framework could also be used for other study designs to contribute to the evidence base for improved health equity. © Article author(s) (or their employer(s) unless otherwise stated in the text of the article) 2017. All rights reserved. No commercial use is permitted unless otherwise expressly granted.

On the effects of the two-body non-fine-structure operators of the Breit-Pauli Hamiltonian

International Nuclear Information System (INIS)

Badnell, N.R.

1997-01-01

We have incorporated the two-body non-fine-structure operators of the Breit-Pauli Hamiltonian, namely contact spin-spin, two-body Darwin and orbit-orbit, into the program AUTOSTRUCTURE. Illustrative results are presented, including some for reactions involving the process of autoionization. (author)

Excitation of the inner 4d shell of neutral iodine

Energy Technology Data Exchange (ETDEWEB)

Pettini, M; Tozzi, G P [Osservatorio Astrofisico di Arcetri, Florence (Italy); Mazzoni, M [Florence Univ. (Italy). Ist. di Astronomia

1981-03-23

The absorption spectrum of neutral atomic iodine has been photographed in the EUV region and three strong autoionized resonances have been identified. A broad absorption feature has been observed and is ascribed to a collective exitation of the 4d inner shell.

Radioactive waste management: a summary of state laws and administration

International Nuclear Information System (INIS)

1983-09-01

This is the second update of Radioactive Waste Management: A Summary of State Laws and Administration. It completely replaces the first update (15 April 1983). The updated report covers the administration, the legislature and the laws in the 50 states related to radioactive waste. The report for each state is divided into four sections: Cover Page; Administrative; Legislative; and Applicable Legislation. The cover page indicates whether or not it is an Agreement State, the low-level waste compacts in which the state is listed as an eligible state, and the high-level waste repository site screening regions in which the state or a portion of it is located. Included under the compacts is a description of what the state has done or currently plans to do, as well as the compact status of other eligible states in the region. The Administrative section provides information on the governor, lead agencies, other involved administrative agencies, relevant commissions, boards and councils and various contacts. In a number of states, Boards of Health or similar boards are lead agencies, so they have been listed in that section. Each board's administrative agency is listed under it. The Legislative section provides general information on the legislature and lists legislative leaders, the relevant committees and their chairs, and a legislative contact. Many legislatures do not set a date for session adjournment, so the date listed represents a combination of information provided by the states and by the history of past sessions. In the section covering Applicable Legislation, laws related to radiation protection, low-level waste and high-level waste have been summarized. Hazardous waste siting laws are included for states that do not have a siting law covering radioactive waste. The section also contains summaries of relevant bills introduced in 1982 and 1983 legislative sessions and this disposition. In general, the information in this report is accurate as of July 15, 1983

The impact of positive, negative and topical relevance feedback

NARCIS (Netherlands)

Kaptein, Rianne; Kamps, Jaap; Hiemstra, Djoerd

2008-01-01

This document contains a description of experiments for the 2008 Relevance Feedback track. We experiment with different amounts of feedback, including negative relevance feedback. Feedback is implemented using massive weighted query expansion. Parsimonious query expansion using only relevant

Examining Hip-Hop as Culturally Relevant Pedagogy

Science.gov (United States)

Kim, Jung; Pulido, Isaura

2015-01-01

Culturally relevant pedagogy is a framework that conceptualizes the process of student learning as contingent upon educators' deep understanding of students' cultural backgrounds to co-construct knowledge and develop academic skills. Concurrently, there are a growing number of studies that explore hip-hop as a culturally relevant curriculum for…

Regulation of non-relevant metabolites of plant protection products in drinking and groundwater in the EU: Current status and way forward.

Science.gov (United States)

Laabs, V; Leake, C; Botham, P; Melching-Kollmuß, S

2015-10-01

Non-relevant metabolites are defined in the EU regulation for plant protection product authorization and a detailed definition of non-relevant metabolites is given in an EU Commission DG Sanco (now DG SANTE - Health and Food Safety) guidance document. However, in water legislation at EU and member state level non-relevant metabolites of pesticides are either not specifically regulated or diverse threshold values are applied. Based on their inherent properties, non-relevant metabolites should be regulated based on substance-specific and toxicity-based limit values in drinking and groundwater like other anthropogenic chemicals. Yet, if a general limit value for non-relevant metabolites in drinking and groundwater is favored, an application of a Threshold of Toxicological Concern (TTC) concept for Cramer class III compounds leads to a threshold value of 4.5 μg L(-1). This general value is exemplarily shown to be protective for non-relevant metabolites, based on individual drinking water limit values derived for a set of 56 non-relevant metabolites. A consistent definition of non-relevant metabolites of plant protection products, as well as their uniform regulation in drinking and groundwater in the EU, is important to achieve legal clarity for all stakeholders and to establish planning security for development of plant protection products for the European market. Copyright © 2015 Elsevier Inc. All rights reserved.

Bioenergetics of transient and steady-state anaerobic redox processes relevant to groundwater contamination

DEFF Research Database (Denmark)

Heimann, Axel Colin

I afhandlingen undersøges anaerob mikrobiel respiration for to forskellige typer af kontaminanter i grundvandet, klorerede ethener og arsen. En kombination af ren- og blandkultur eksperimenter, sedimentmikrokosmos studier og termodynamiske beregninger blev benyttet, for at belyse energetiske......). Ligeledes viste sediment mikrokosmer fra en arsen forurenet aquifer i Vietnam hurtig omsætning af As(V) til As(III) ledsaget af forholdsvis lave steady state brint niveauer. Sammen, tyder data på, at As(V) reduktion, mistænkt for at spille en rolle i arsen kontaminering i grundvandsystemer, er en meget...

Resonances in atomic few-body systems

International Nuclear Information System (INIS)

Mezei, J.Zs.; Kruppa, A.T.

2005-01-01

Complete text of publication follows. The variational method using a correlated Gaussian basis (SVM, see [1]) has proved to be an excellent method in calculating the characteristics of bound-states. Its trial and error procedures are very powerful to select an optimal basis, while the simple form of the trial function simplifies the calculations, because most of the matrix elements have analytic form. Combining the SVM with the complex rotational technique we are able to determine auto-ionizing states of Coulombic systems with three or more charged particles. Performing the complex rotation of the coordinates (r → re iθ the complex scaled Hamiltonian of a Coulombic system - only Coulomb interactions act between the particles - is a simple function of the rotational angle H(θ) Te -2iθ + Ve -iθ , where T,V are the kinetic and the potential energies of the system. In order to find the complex eigen energies of the rotated Hamiltonian, we have to solve the equation det/e -i2θ T i,j + e -iθ V ij - EΔ ij / = 0, where T ij and V i,j are the matrix elements of the original kinetic energy operator and the potential energy operator, while Δ ij are the overlap integrals of the basis elements. The SVM optimizes the non-linear parameters of the basis in a very specific way in order to get the best ground state energy. In the calculation of the excited auto-ionizing states we used the same set of parameters as for the ground state, because there are no simple recipes to optimize the parameters of a basis in a resonance state calculation. We have found that with the same set of non- linear parameters as for the ground state, we are able to describe all resonances of the Ps - (e + + e - + e - ) system calculated by Ho. We get almost the same accuracy as Ho, although Ho uses different bases for each resonant state. For the second resonance state in Table 1, our width is an order-of-magnitude smaller than Ho's, but our result is in a good agreement with recent calculations

Signal Enhancement as Minimization of Relevant Information Loss

OpenAIRE

Geiger, Bernhard C.; Kubin, Gernot

2012-01-01

We introduce the notion of relevant information loss for the purpose of casting the signal enhancement problem in information-theoretic terms. We show that many algorithms from machine learning can be reformulated using relevant information loss, which allows their application to the aforementioned problem. As a particular example we analyze principle component analysis for dimensionality reduction, discuss its optimality, and show that the relevant information loss can indeed vanish if the r...

TaBoo SeArch Algorithm with a Modified Inverse Histogram for Reproducing Biologically Relevant Rare Events of Proteins.

Science.gov (United States)

Harada, Ryuhei; Takano, Yu; Shigeta, Yasuteru

2016-05-10

The TaBoo SeArch (TBSA) algorithm [ Harada et al. J. Comput. Chem. 2015 , 36 , 763 - 772 and Harada et al. Chem. Phys. Lett. 2015 , 630 , 68 - 75 ] was recently proposed as an enhanced conformational sampling method for reproducing biologically relevant rare events of a given protein. In TBSA, an inverse histogram of the original distribution, mapped onto a set of reaction coordinates, is constructed from trajectories obtained by multiple short-time molecular dynamics (MD) simulations. Rarely occurring states of a given protein are statistically selected as new initial states based on the inverse histogram, and resampling is performed by restarting the MD simulations from the new initial states to promote the conformational transition. In this process, the definition of the inverse histogram, which characterizes the rarely occurring states, is crucial for the efficiency of TBSA. In this study, we propose a simple modification of the inverse histogram to further accelerate the convergence of TBSA. As demonstrations of the modified TBSA, we applied it to (a) hydrogen bonding rearrangements of Met-enkephalin, (b) large-amplitude domain motions of Glutamine-Binding Protein, and (c) folding processes of the B domain of Staphylococcus aureus Protein A. All demonstrations numerically proved that the modified TBSA reproduced these biologically relevant rare events with nanosecond-order simulation times, although a set of microsecond-order, canonical MD simulations failed to reproduce the rare events, indicating the high efficiency of the modified TBSA.

Alpha power gates relevant information during working memory updating.

Science.gov (United States)

Manza, Peter; Hau, Chui Luen Vera; Leung, Hoi-Chung

2014-04-23

Human working memory (WM) is inherently limited, so we must filter out irrelevant information in our environment or our mind while retaining limited important relevant contents. Previous work suggests that neural oscillations in the alpha band (8-14 Hz) play an important role in inhibiting incoming distracting information during attention and selective encoding tasks. However, whether alpha power is involved in inhibiting no-longer-relevant content or in representing relevant WM content is still debated. To clarify this issue, we manipulated the amount of relevant/irrelevant information using a task requiring spatial WM updating while measuring neural oscillatory activity via EEG and localized current sources across the scalp using a surface Laplacian transform. An initial memory set of two, four, or six spatial locations was to be memorized over a delay until an updating cue was presented indicating that only one or three locations remained relevant for a subsequent recognition test. Alpha amplitude varied with memory maintenance and updating demands among a cluster of left frontocentral electrodes. Greater postcue alpha power was associated with the high relevant load conditions (six and four dots cued to reduce to three relevant) relative to the lower load conditions (four and two dots reduced to one). Across subjects, this difference in alpha power was correlated with condition differences in performance accuracy. In contrast, no significant effects of irrelevant load were observed. These findings demonstrate that, during WM updating, alpha power reflects maintenance of relevant memory contents rather than suppression of no-longer-relevant memory traces.

Translation as secondary communication. The relevance theory ...

African Journals Online (AJOL)

Ernst-August Gutt started one of the greatest translation debates of the past ten years when he suggested that relevance theory holds the key to providing a unified account of translation. The bulk of the debate has been between practitioners of functional equivalence and advocates of a relevance theoretic approach to ...

State-of-the-art inventory

NARCIS (Netherlands)

Verhagen, H.J.; Van Gerven, K.A.J.; Akkerman, G.J.

2005-01-01

The present report provides a state-of-the-art inventory of relevant information and technical concepts for the ComCoast project, being the first phase of the research stages of Work Package 3 (WP3). This project was assigned to Royal Haskoning by CUR. The information scan was set-up in a systematic

Monochloramine Cometabolism by Nitrifying Biofilm Relevant ...

Science.gov (United States)

Recently, biological monochloramine removal (i.e., cometabolism) by a pure culture ammonia–oxidizing bacteria, Nitrosomonas europaea, and a nitrifying mixed–culture have been shown to increase monochloramine demand. Although important, these previous suspended culture batch kinetic experiments were not representative of drinking water distribution systems where bacteria grow predominantly as biofilm attached to pipe walls or sediments and physiological differences may exist between suspension and biofilm growth. Therefore, the current research was an important next step in extending the previous results to investigate monochloramine cometabolism by biofilm grown in annular reactors under drinking water relevant conditions. Estimated monochloramine cometabolism kinetics were similar to those of ammonia metabolism, and monochloramine cometabolism was a significant loss mechanism (25–40% of the observed monochloramine loss). These results demonstrated that monochloramine cometabolism occurred in drinking water relevant nitrifying biofilm; thus, cometabolism may be a significant contribution to monochloramine loss during nitrification episodes in distribution systems. Investigate whether or not nitrifying biofilm can biologically transform monochloramine under drinking water relevant conditions.

The Relevant Physical Trace in Criminal Investigation

Directory of Open Access Journals (Sweden)

Durdica Hazard

2016-01-01

Full Text Available A criminal investigation requires the forensic scientist to search and to interpret vestiges of a criminal act that happened in the past. The forensic scientist is one of the many stakeholders who take part in the information quest within the criminal justice system. She reads the investigation scene in search of physical traces that should enable her to tell the story of the offense/crime that allegedly occurred. The challenge for any investigator is to detect and recognize relevant physical traces in order to provide clues for investigation and intelligence purposes, and that will constitute sound and relevant evidence for the court. This article shows how important it is to consider the relevancy of physical traces from the beginning of the investigation and what might influence the evaluation process. The exchange and management of information between the investigation stakeholders are important. Relevancy is a dimension that needs to be understood from the standpoints of law enforcement personnel and forensic scientists with the aim of strengthening investigation and ultimately the overall judicial process.

Practical relevance of pattern uniqueness in forensic science.

Science.gov (United States)

Jayaprakash, Paul T

2013-09-10

Uniqueness being unprovable, it has recently been argued that individualization in forensic science is irrelevant and, probability, as applied for DNA profiles, should be applied for all identifications. Critiques against uniqueness have omitted physical matching, a realistic and tangible individualization that supports uniqueness. Describing case examples illustrating pattern matches including physical matching, it is indicated that individualizations are practically relevant for forensic science as they establish facts on a definitive basis providing firm leads benefitting criminal investigation. As a tenet of forensic identification, uniqueness forms a fundamental paradigm relevant for individualization. Evidence on the indeterministic and stochastic causal pathways of characteristics in patterns available in the related fields of science sufficiently supports the proposition of uniqueness. Characteristics involved in physical matching and matching achieved in patterned evidence existing in the state of nature are not events amenable for counting; instead these are ensemble of visible units occupying the entire pattern area stretching the probability of re-occurrence of a verisimilitude pattern into infinity offering epistemic support to uniqueness. Observational methods are as respectable as instrumental or statistical methods since they are capable of generating results that are tangible and obviously valid as in physical matching. Applying the probabilistic interpretation used for DNA profiles to the other patterns would be unbefitting since these two are disparate, the causal pathways of the events, the loci, in the manipulated DNA profiles being determinable. While uniqueness enables individualizations, it does not vouch for eliminating errors. Instead of dismissing uniqueness and individualization, accepting errors as human or system failures and seeking remedial measures would benefit forensic science practice and criminal investigation. Copyright © 2013

Software Helps Retrieve Information Relevant to the User

Science.gov (United States)

Mathe, Natalie; Chen, James

2003-01-01

The Adaptive Indexing and Retrieval Agent (ARNIE) is a code library, designed to be used by an application program, that assists human users in retrieving desired information in a hypertext setting. Using ARNIE, the program implements a computational model for interactively learning what information each human user considers relevant in context. The model, called a "relevance network," incrementally adapts retrieved information to users individual profiles on the basis of feedback from the users regarding specific queries. The model also generalizes such knowledge for subsequent derivation of relevant references for similar queries and profiles, thereby, assisting users in filtering information by relevance. ARNIE thus enables users to categorize and share information of interest in various contexts. ARNIE encodes the relevance and structure of information in a neural network dynamically configured with a genetic algorithm. ARNIE maintains an internal database, wherein it saves associations, and from which it returns associated items in response to a query. A C++ compiler for a platform on which ARNIE will be utilized is necessary for creating the ARNIE library but is not necessary for the execution of the software.

Electron impact ionization of multicharged ions

International Nuclear Information System (INIS)

Crandall, D.H.; Hasselquist, B.E.; Phaneuf, R.A.; Gregory, D.C.

1979-01-01

Cross sections were measured with a crossed-beams apparatus. Results for e - + N 4+ → N 5+ + 2e - and e - + O 4+ → O 5+ + 2e - are shown from 100 to 2000 eV. The contribution of excitation-autoionization is noted. 2 figures

49 CFR 556.9 - Public inspection of relevant information.

Science.gov (United States)

2010-10-01

... 49 Transportation 6 2010-10-01 2010-10-01 false Public inspection of relevant information. 556.9... NONCOMPLIANCE § 556.9 Public inspection of relevant information. Information relevant to a petition under this... Administration, 400 Seventh Street, SW., Washington, DC 20590. Copies of available information may be obtained in...

Android Smartphone Relevance to Military Weather Applications

Science.gov (United States)

2011-10-01

lithium -ion battery that may be replaced by the user (unlike Apple iPod Touch devices), thus spare batteries can be carried. If there is only sporadic...Android Smartphone Relevance to Military Weather Applications by David Sauter ARL-TR-5793 October 2011...Android Smartphone Relevance to Military Weather Applications David Sauter Computational and Information Sciences Directorate, ARL

Simulations of KSTAR high performance steady state operation scenarios

International Nuclear Information System (INIS)

Na, Yong-Su; Kessel, C.E.; Park, J.M.; Yi, Sumin; Kim, J.Y.; Becoulet, A.; Sips, A.C.C.

2009-01-01

We report the results of predictive modelling of high performance steady state operation scenarios in KSTAR. Firstly, the capabilities of steady state operation are investigated with time-dependent simulations using a free-boundary plasma equilibrium evolution code coupled with transport calculations. Secondly, the reproducibility of high performance steady state operation scenarios developed in the DIII-D tokamak, of similar size to that of KSTAR, is investigated using the experimental data taken from DIII-D. Finally, the capability of ITER-relevant steady state operation is investigated in KSTAR. It is found that KSTAR is able to establish high performance steady state operation scenarios; β N above 3, H 98 (y, 2) up to 2.0, f BS up to 0.76 and f NI equals 1.0. In this work, a realistic density profile is newly introduced for predictive simulations by employing the scaling law of a density peaking factor. The influence of the current ramp-up scenario and the transport model is discussed with respect to the fusion performance and non-inductive current drive fraction in the transport simulations. As observed in the experiments, both the heating and the plasma current waveforms in the current ramp-up phase produce a strong effect on the q-profile, the fusion performance and also on the non-inductive current drive fraction in the current flattop phase. A criterion in terms of q min is found to establish ITER-relevant steady state operation scenarios. This will provide a guideline for designing the current ramp-up phase in KSTAR. It is observed that the transport model also affects the predictive values of fusion performance as well as the non-inductive current drive fraction. The Weiland transport model predicts the highest fusion performance as well as non-inductive current drive fraction in KSTAR. In contrast, the GLF23 model exhibits the lowest ones. ITER-relevant advanced scenarios cannot be obtained with the GLF23 model in the conditions given in this work

Information Needs/Relevance

OpenAIRE

Wildemuth, Barbara M.

2009-01-01

A user's interaction with a DL is often initiated as the result of the user experiencing an information need of some kind. Aspects of that experience and how it might affect the user's interactions with the DL are discussed in this module. In addition, users continuously make decisions about and evaluations of the materials retrieved from a DL, relative to their information needs. Relevance judgments, and their relationship to the user's information needs, are discussed in this module. Draft

Probing Earth's State of Stress

Science.gov (United States)

Delorey, A. A.; Maceira, M.; Johnson, P. A.; Coblentz, D. D.

2016-12-01

The state of stress in the Earth's crust is a fundamental physical property that controls both engineered and natural systems. Engineered environments including those for hydrocarbon, geothermal energy, and mineral extraction, as well those for storage of wastewater, carbon dioxide, and nuclear fuel are as important as ever to our economy and environment. Yet, it is at spatial scales relevant to these activities where stress is least understood. Additionally, in engineered environments the rate of change in the stress field can be much higher than that of natural systems. In order to use subsurface resources more safely and effectively, we need to understand stress at the relevant temporal and spatial scales. We will present our latest results characterizing the state of stress in the Earth at scales relevant to engineered environments. Two important components of the state of stress are the orientation and magnitude of the stress tensor, and a measure of how close faults are to failure. The stress tensor at any point in a reservoir or repository has contributions from both far-field tectonic stress and local density heterogeneity. We jointly invert seismic (body and surface waves) and gravity data for a self-consistent model of elastic moduli and density and use the model to calculate the contribution of local heterogeneity to the total stress field. We then combine local and plate-scale contributions, using local indicators for calibration and ground-truth. In addition, we will present results from an analysis of the quantity and pattern of microseismicity as an indicator of critically stressed faults. Faults are triggered by transient stresses only when critically stressed (near failure). We show that tidal stresses can trigger earthquakes in both tectonic and reservoir environments and can reveal both stress and poroelastic conditions.

Study on the relevance of some of the description methods for plateau-honed surfaces

International Nuclear Information System (INIS)

Yousfi, M; Mezghani, S; Demirci, I; El Mansori, M

2014-01-01

Much work has been undertaken in recent years into the determination of a complete parametric description of plateau-honed surfaces with the intention of making a link between the process conditions, the surface topography and the required functional performances. Different advanced techniques (plateau/valleys decomposition using the normalized Abbott–Firestone curve or morphological operators, multiscale decomposition using continuous wavelets transform, etc) were proposed and applied in different studies. This paper re-examines the current state of developments and addresses a discussion on the relevance of the different proposed parameters and characterization methods for plateau-honed surfaces by considering the control loop manufacturing-characterization-function. The relevance of appropriate characterization is demonstrated through two experimental studies. They consider the effect of the most plateau honing process variables (the abrasive grit size and abrasive indentation velocity in finish-honing and the plateau-honing stage duration and pressure) on cylinder liner surface textures and hydrodynamic friction of the ring-pack system. (paper)

On relevant boundary perturbations of unitary minimal models

International Nuclear Information System (INIS)

Recknagel, A.; Roggenkamp, D.; Schomerus, V.

2000-01-01

We consider unitary Virasoro minimal models on the disk with Cardy boundary conditions and discuss deformations by certain relevant boundary operators, analogous to tachyon condensation in string theory. Concentrating on the least relevant boundary field, we can perform a perturbative analysis of renormalization group fixed points. We find that the systems always flow towards stable fixed points which admit no further (non-trivial) relevant perturbations. The new conformal boundary conditions are in general given by superpositions of 'pure' Cardy boundary conditions