Sample records for autoignition

  1. Turbulent deflagrations, autoignitions, and detonations

    KAUST Repository

    Bradley, Derek


    Measurements of turbulent burning velocities in fan-stirred explosion bombs show an initial linear increase with the fan speed and RMS turbulent velocity. The line then bends over to form a plateau of high values around the maximum attainable burning velocity. A further increase in fan speed leads to the eventual complete quenching of the flame due to increasing localised extinctions because of the flame stretch rate. The greater the Markstein number, the more readily does flame quenching occur. Flame propagation along a duct closed at one end, with and without baffles to increase the turbulence, is subjected to a one-dimensional analysis. The flame, initiated at the closed end of the long duct, accelerates by the turbulent feedback mechanism, creating a shock wave ahead of it, until the maximum turbulent burning velocity for the mixture is attained. With the confining walls, the mixture is compressed between the flame and the shock plane up to the point where it might autoignite. This can be followed by a deflagration to detonation transition. The maximum shock intensity occurs with the maximum attainable turbulent burning velocity, and this defines the limit for autoignition of the mixture. For more reactive mixtures, autoignition can occur at turbulent burning velocities that are less than the maximum attainable one. Autoignition can be followed by quasi-detonation or fully developed detonation. The stability of ensuing detonations is discussed, along with the conditions that may lead to their extinction. © 2012 by Pleiades Publishing, Ltd.

  2. Effect of hydrogen addition on autoignited methane lifted flames

    KAUST Repository

    Choin, Byung Chul


    Autoignited lifted flames in laminar jets with hydrogen-enriched methane fuels have been investigated experimentally in heated coflow air. The results showed that the autoignited lifted flame of the methane/hydrogen mixture, which had an initial temperature over 920 K, the threshold temperature for autoignition in methane jets, exhibited features typical of either a tribrachial edge or mild combustion depending on fuel mole fraction and the liftoff height increased with jet velocity. The liftoff height in the hydrogen-assisted autoignition regime was dependent on the square of the adiabatic ignition delay time for the addition of small amounts of hydrogen, as was the case for pure methane jets. When the initial temperature was below 920 K, where the methane fuel did not show autoignition behavior, the flame was autoignited by the addition of hydrogen, which is an ignition improver. The liftoff height demonstrated a unique feature in that it decreased nonlinearly as the jet velocity increased. The differential diffusion of hydrogen is expected to play a crucial role in the decrease in the liftoff height with increasing jet velocity.

  3. Auto-Ignition and Heat Release Correlations for Controlled Auto-Ignition Combustion in Gasoline Engines

    Institute of Scientific and Technical Information of China (English)


    Auto-ignition and heat release correlations for controlled auto-ignition (CAI) combustion were derived from extensive in-cylinder pressure data of a four-stroke gasoline engine operating in CAI combustion mode. Abundant experiments were carried out under a wide range of air/fuel ratio,speed and residual gas fraction to ensure that the combustion correlations can be used in the entire CAI engine operation range. Furthermore, a more accurate method to compute the residual gas fraction was proposed by calculating the working fluid temperature at the exhaust valve close timing in the experiments. The heat release correlation was described in two parts, one is for the first slower heat release process at low temperature, and the other is for the second faster heat release process at high temperature. Finally the heat release correlation was evaluated on the single cylinder gasoline engine running with CAI combustion by comparing the experimental data with the 1-D engine simulation results obtained with the aid of the GT-Power simulation program. The results show that the predicted loads and ignition timings match closely with the measurements.

  4. Autoignited and non-autoignited lifted flames of pre-vaporized n-heptane in coflow jets at elevated temperatures

    KAUST Repository

    Choi, Sangkyu


    The characteristics of laminar lifted flames of pre-vaporized n-heptane in coflow jets were investigated under both non-autoignited and autoignited conditions by varying the initial temperature. The fuel tested was n-heptane considering the importance as a primary reference fuel for gasoline and its low temperature ignition behavior at relatively low pressure. The results showed that the lifted flame edge in the non-autoignited regime had a tribrachial structure with lean and rich premixed flame wings together with a trailing diffusion flame. The liftoff heights correlated reasonably well with the fuel jet velocity scaled by the stoichiometric laminar burning velocity regardless of the initial temperature and the nitrogen dilution. The liftoff velocity multiplied by the buoyancy-induced velocity and the blowout velocity scaled by the mole fraction of the fuel correlated well with the stoichiometric laminar burning velocity. When the initial temperature was above 900. K, flames were autoignited without any external ignition source. Autoignited lifted flames with both tribrachial edges and mild combustion characteristics were observed. The correlation of the liftoff height with the calculated adiabatic ignition delay time was weak, unlike in cases with gaseous fuels of C1-C4 hydrocarbons in which the liftoff height of the autoignited flames correlated well with the square of the adiabatic ignition delay time. When the mole fraction of the fuel was small, mild combustion behaviors were exhibited with edge flames without distinct tribrachial structures. The liftoff height was correlated with the fuel jet velocity scaled by the initial fuel mass fraction, while the dependence on the ignition delay time was weak when compared with the gaseous fuels. © 2013 The Combustion Institute.

  5. Direct Numerical Simulations of Turbulent Autoigniting Hydrogen Jets (United States)

    Asaithambi, Rajapandiyan

    Autoignition is an important phenomenon and a tool in the design of combustion engines. To study autoignition in a canonical form a direct numerical simulation of a turbulent autoigniting hydrogen jet in vitiated coflow conditions at a jet Reynolds number of 10,000 is performed. A detailed chemical mechanism for hydrogen-air combustion and non-unity Lewis numbers for species transport is used. Realistic inlet conditions are prescribed by obtaining the velocity eld from a fully developed turbulent pipe flow simulation. To perform this simulation a scalable modular density based method for direct numerical simulation (DNS) and large eddy simulation (LES) of compressible reacting flows is developed. The algorithm performs explicit time advancement of transport variables on structured grids. An iterative semi-implicit time advancement is developed for the chemical source terms to alleviate the chemical stiffness of detailed mechanisms. The algorithm is also extended from a Cartesian grid to a cylindrical coordinate system which introduces a singularity at the pole r = 0 where terms with a factor 1/r can be ill-defined. There are several approaches to eliminate this pole singularity and finite volume methods can bypass this issue by not storing or computing data at the pole. All methods however face a very restrictive time step when using a explicit time advancement scheme in the azimuthal direction (theta) where the cell sizes are of the order DelrDeltheta. We use a conservative finite volume based approach to remove the severe time step restriction imposed by the CFL condition by merging cells in the azimuthal direction. In addition, fluxes in the radial direction are computed with an implicit scheme to allow cells to be clustered along the jet's shear layer. This method is validated and used to perform the large scale turbulent reacting simulation. The resulting flame structure is found to be similar to a turbulent diusion flame but stabilized by autoignition at the

  6. Experiment and Simulation of Autoignition in Jet Flames and its Relevance to Flame Stabilization and Structure

    KAUST Repository

    Al-Noman, Saeed M.


    Autoignition characteristics of pre-vaporized iso-octane, primary reference fuels, gasolines, and dimethyl ether (DME) have been investigated experimentally in a coflow with elevated temperature of air. With the coflow air at relatively low initial temperatures below autoignition temperature Tauto, an external ignition source was required to stabilize the flame. Non-autoignited lifted flames had tribrachial edge structures and their liftoff heights correlated well with the jet velocity scaled by the stoichiometric laminar burning velocity, indicating the importance of the edge propagation speed on flame stabilization balanced with local flow velocity. At high initial temperatures over Tauto, the autoignited flames were stabilized without requiring an external ignition source. The autoignited lifted flames exhibited either tribrachial edge structures or Mild combustion behaviors depending on the level of fuel dilution. For the iso-octane and n-heptane fuels, two distinct transition behaviors were observed in the autoignition regime from a nozzle-attached flame to a lifted tribrachial-edge flame and then a sudden transition to lifted Mild combustion as the jet velocity increased at a certain fuel dilution level. The liftoff data of the autoignited flames with tribrachial edges were analyzed based on calculated ignition delay times for the pre-vaporized fuels. Analysis of the experimental data suggested that ignition delay time may be much less sensitive to initial temperature under atmospheric pressure conditions as compared with predictions. For the gasoline fuels for advanced combustion engines (FACEs), and primary reference fuels (PRFs), autoignited liftoff data were correlated with Research Octane Number and Cetane Number. For the DME fuel, planar laser-induced fluorescence (PLIF) of formaldehyde (CH2O) and CH* chemiluminescence were visualized qualitatively. In the autoignition regime for both tribrachial structure and mild combustion, formaldehyde were found

  7. Characteristics of autoignited laminar lifted flames in heated coflow jets of carbon monoxide/hydrogen mixtures

    KAUST Repository

    Choi, Byungchul


    The characteristics of autoignited lifted flames in laminar jets of carbon monoxide/hydrogen fuels have been investigated experimentally in heated coflow air. In result, as the jet velocity increased, the blowoff was directly occurred from the nozzle-attached flame without experiencing a stabilized lifted flame, in the non-autoignited regime. In the autoignited regime, the autoignited lifted flame of carbon monoxide diluted by nitrogen was affected by the water vapor content in the compressed air oxidizer, as evidenced by the variation of the ignition delay time estimated by numerical calculation. In particular, in the autoignition regime at low temperatures with added hydrogen, the liftoff height of the autoignited lifted flames decreased and then increased as the jet velocity increased. Based on the mechanism in which the autoignited laminar lifted flame is stabilized by ignition delay time, the liftoff height can be influenced not only by the heat loss, but also by the preferential diffusion between momentum and mass diffusion in fuel jets during the autoignition process. © 2012 The Korean Society of Mechanical Engineers.

  8. Auto-ignition and stabilization mechanism of diluted H2 jet flame

    Institute of Scientific and Technical Information of China (English)

    Wei FENG; Zhi-jun WU; Jun DENG; Li-guang LI


    The controllable active thermo-atmosphere combustor (CATAC) has become a utilizable and effective facility because it benefits the optical diagnostics and modeling.This paper presents the modeling research of the auto-ignition and flames of the H2/N2 (H2/CH4/N2,or H2/H2O2/N2) mixture on a CATAC,and shows curves varying with temperatures of auto-ignition delay,the height of the site of auto-ignition of lifted flames,and flame lift-off height.The results of auto-ignition delay and the lifi-off height are compared the experimental results to validate the model.A turning point can be seen on each curve,identified with criterion temperature.It can be concluded that when the co-flow temperature is higher than the criterion temperature,the auto-ignition and lifted flame of the mixture are not stable.Conversely,below the criterion temperature,the mixture will auto-ignite in a stable fashion.Stabilization mechanisms of auto-ignition and lifted flames are analyzed in terms of the criterion temperature.

  9. Autoignited laminar lifted flames of methane, ethylene, ethane, and n-butane jets in coflow air with elevated temperature

    KAUST Repository

    Choi, Byungchul


    The autoignition characteristics of laminar lifted flames of methane, ethylene, ethane, and n-butane fuels have been investigated experimentally in coflow air with elevated temperature over 800. K. The lifted flames were categorized into three regimes depending on the initial temperature and fuel mole fraction: (1) non-autoignited lifted flame, (2) autoignited lifted flame with tribrachial (or triple) edge, and (3) autoignited lifted flame with mild combustion. For the non-autoignited lifted flames at relatively low temperature, the existence of lifted flame depended on the Schmidt number of fuel, such that only the fuels with Sc > 1 exhibited stationary lifted flames. The balance mechanism between the propagation speed of tribrachial flame and local flow velocity stabilized the lifted flames. At relatively high initial temperatures, either autoignited lifted flames having tribrachial edge or autoignited lifted flames with mild combustion existed regardless of the Schmidt number of fuel. The adiabatic ignition delay time played a crucial role for the stabilization of autoignited flames. Especially, heat loss during the ignition process should be accounted for, such that the characteristic convection time, defined by the autoignition height divided by jet velocity was correlated well with the square of the adiabatic ignition delay time for the critical autoignition conditions. The liftoff height was also correlated well with the square of the adiabatic ignition delay time. © 2010 The Combustion Institute.

  10. Autoignited laminar lifted flames of methane/hydrogen mixtures in heated coflow air

    KAUST Repository

    Choi, Byungchul


    Autoignited lifted flame behavior in laminar jets of methane/hydrogen mixture fuels has been investigated experimentally in heated coflow air. Three regimes of autoignited lifted flames were identified depending on initial temperature and hydrogen to methane ratio. At relatively high initial temperature, addition of a small amount of hydrogen to methane improved ignition appreciably such that the liftoff height decreased significantly. In this hydrogen-assisted autoignition regime, the liftoff height increased with jet velocity, and the characteristic flow time - defined as the ratio of liftoff height to jet velocity - correlated well with the square of the adiabatic ignition delay time. At lower temperature, the autoignited lifted flame demonstrated a unique feature in that the liftoff height decreased with increasing jet velocity. Such behavior has never been observed in lifted laminar and turbulent jet flames. A transition regime existed between these two regimes at intermediate temperature. © 2011 The Combustion Institute.

  11. Autoignition of turbulent hydrogen jet in a coflow of heated air

    Energy Technology Data Exchange (ETDEWEB)

    Patwardhan, Saurabh S.; Lakshmisha, K.N. [Department of Aerospace Engineering, Indian Institute of Science, Bangalore 560012 (India)


    Autoignition of hydrogen, leading to flame development under turbulent flow conditions is numerically investigated including a detailed chemical mechanism. The chosen configuration consists of a turbulent jet of hydrogen diluted with nitrogen which is issued into a coflow of heated air. Numerical simulations are performed with the Conditional Moment Closure model, to capture the transient evolution of the flow. Turbulence closure is achieved using the k-{epsilon} model. Simulations revealed that the injected hydrogen mixes with coflowing air, autoignites and a stable diffusion flame is established. Sometimes, flashback of the ignited mixture is observed, whereby the flame travels upstream and stabilizes. It is found that the constants assumed in various modeling terms can severely influence the degree of mixing. Hence, certain modifications to these constants are suggested, and improved predictions are obtained. The sensitivity of autoignition length to the coflow temperature is investigated. The predicted autoignition lengths show a reasonable agreement with the experimental data and LES results. (author)

  12. Comparative Autoignition Trends in Butanol Isomers at Elevated Pressure

    KAUST Repository

    Weber, Bryan W.


    Autoignition experiments of stoichiometric mixtures of s-, t-, and i-butanol in air have been performed using a heated rapid compression machine (RCM). At compressed pressures of 15 and 30 bar and for compressed temperatures in the range 715-910 K, no evidence of a negative temperature coefficient region in terms of ignition delay response is found. The present experimental results are also compared with previously reported RCM data of n-butanol in air. The order of reactivity of the butanols is n-butanol > s-butanol ≈ i-butanol > t-butanol at the lower pressure but changes to n-butanol > t-butanol > s-butanol > i-butanol at higher pressure. In addition, t-butanol shows preignition heat release behavior, which is especially evident at higher pressures. To help identify the controlling chemistry leading to this preignition heat release, off-stoichiometric experiments are further performed at 30 bar compressed pressure, for t-butanol at φ = 0.5 and φ = 2.0 in air. For these experiments, higher fuel loading (i.e., φ = 2.0) causes greater preignition heat release (as indicated by greater pressure rise) than the stoichiometric or φ = 0.5 cases. Comparison of the experimental ignition delays with the simulated results using two literature kinetic mechanisms shows generally good agreement, and one mechanism is further used to explore and compare the fuel decomposition pathways of butanol isomers. Using this mechanism, the importance of peroxy chemistry in the autoignition of the butanol isomers is highlighted and discussed. © 2013 American Chemical Society.

  13. Autoignition and Combustion of Natural Gas in a 4 Stroke HCCI Engine (United States)

    Jun, Daesu; Ishii, Kazuaki; Iida, Norimasa

    Homogeneous charge compression ignition (HCCI) is regarded as the next generation combustion regime in terms of high thermal efficiency and low emissions. It is difficult to control autoignition timing and combustion duration because they are controlled primarily by the chemical kinetics of fuel-air mixture. In this study, it was investigated the characteristics of autoignition and combustion of natural gas in a 4 stroke HCCI engine. And also, to clarify the influence of n-butane on autoignition and combustion of natural gas, it was changed the blend ratio of n-butane from 0mol% to 10mol% in methane/n-butane/air mixtures. Autoignition strongly depends on in-cylinder gas temperature. Autoignition of natural gas occurs when in-cylinder gas temperature reaches in a range of 1000±100K under this experimental condition. To realize high thermal efficiency and low CO emissions, it is necessary to prepare operation conditions that maximum cycle temperature is over 1500K. Autoignition temperature is 25K lower by increasing n-butane blend ratio of 10%. As the blend ratio of n-butane increases, the maximum cycle temperature increases, and THC, CO emissions reduce.

  14. Investigation of Auto-ignition of Several Single Fuels

    Directory of Open Access Journals (Sweden)



    Full Text Available HCCI operating principals have been widely investigated yet the uncontrollable combustion of HCCI is the major obstacle in its development. This paper is trying to increase the understanding on the auto-ignition and combustion process of several fuels to be applied in HCCI combustion system. The investigation includes the combustion behavior of 4 fuels, gasoline (RON95, diesel, n-heptane, isooctane, The investigation was done in constant volume chamber with elevated temperature (800°C. Four lambdas were tested for each fuel namely 0.8, 1, 1.2 and 2. It is found that these fuels can be categorized into two major categories based on combustion characteristics, homogeneous and diffusive combustion. Gasoline and isooctane, homogeneous combustion, shows almost the same behavior where the increase in lambda will increase the combustion delay even though isooctane shows much longer delayed compared to gasoline. While diesel and n-heptane, diffusive combustion, has no ignition delay yet showing different behavior on the later parts of the combustion where diesel effecting 10-90% combustion stage while n-heptane on 90-100%.

  15. Investigation of the Livengood-Wu integral for modelling autoignition in a high-pressure bomb (United States)

    Hu, Zhixin; Somers, Bart L. M. T.; Cracknell, Roger F.; Bradley, Derek


    The reaction progress variable, which is widely used in premixed and diffusion combustion studies, comprises a set of pre-selected intermediate species to denote reaction progress. Progress towards autoignition can also be traced by the Livengood-Wu (LW) integral. Autoignition occurs when the LW integral attains a value of unity. This concept is further explored by applying it to an inhomogeneous mixture scenario, to determine the time and place of autoignition occurrence. A semidetailed mechanism (137 species and 633 reactions) for n-heptane/iso-octane/toluene is used in this study. Two numerical schemes based on the LW integral are proposed and incorporated into a computational fluid dynamics platform, to model autoignition in a 3D configuration, when a spray is injected into a constant volume bomb under diesel engine conditions. Tabulated chemistry, a traditional method of modelling autoignition using information from pre-calculated igniting diffusion flames, is also used for comparison purposes. The associated predicted pressure profiles are compared with experimental measurements.

  16. Numerical study of laminar nonpremixed methane flames in coflow jets: Autoignited lifted flames with tribrachial edges and MILD combustion at elevated temperatures

    KAUST Repository

    M. Al-Noman, Saeed


    Autoignition characteristics of laminar nonpremixed methane jet flames in high-temperature coflow air are studied numerically. Several flame configurations are investigated by varying the initial temperature and fuel mole fraction. At a relatively low initial temperature, a non-autoignited nozzle-attached flame is simulated at relatively low jet velocity. When the initial temperature is higher than that required for autoignition, two regimes are investigated: an autoignited lifted flame with tribrachial edge structure and an autoignited lifted flame with Mild combustion. The autoignited lifted flame with tribrachial edge exhibited three branches: lean and rich premixed flame wings and a trailing diffusion flame. Characteristics of kinetic structure for autoignited lifted flames are discussed based on the kinetic structures of homogeneous autoignition and flame propagation of stoichiometric mixture. Results showed that a transition from autoignition to flame propagation modes occurs for reasonably stoichiometric mixtures. The autoignited lifted flame with Mild combustion occurs when methane fuel is highly diluted with nitrogen. The kinetic structure analysis shows that the characteristics of Mild combustion can be treated as an autoignited lean premixed lifted flame. Transition behavior from Mild combustion to nozzle-attached flame was investigated by increasing the fuel mole fraction. As the maximum flame temperature increases with decreasing liftoff height, the kinetic structure showed a transition behavior from autoignition to flame propagation of a lean premixed flame. © 2016 The Combustion Institute

  17. Dynamics of autoignitive DME/air coflow flames in oscillating flows (United States)

    Deng, Sili; Zhao, Peng; Mueller, Michael; Law, Chung


    The structure and dynamics of laminar nonpremixed dimethyl ether (DME)/air coflow flames were investigated at elevated temperatures and pressures, conditions at which autoignition times become competitive with flame times. Computations with detailed chemistry were performed for DME and heated coflow air at 30 atm with uniform but sinusoidally oscillating inlet velocities. These unsteady cases were compared with steady flames to elucidate the effect of oscillation frequency on the flame dynamics. In the oscillating reacting flow, periodic but hysteretic transition occurs between a multibrachial autoignition front that locates downstream at high inlet velocity and a tribrachial flame that locates upstream at low inlet velocity. The finite induction time for autoignition results in this hysteretic behavior, which diminishes at lower oscillation frequency as there is more time for chemistry to respond to the hydrodynamic changes and consequently approach steady state.

  18. Intermediate species measurement during iso-butanol auto-ignition

    KAUST Repository

    Ji, Weiqi


    © 2015 The Combustion Institute.Published by Elsevier Inc. All rights reserved. This work presents the time histories of intermediate species during the auto-ignition of iso-butanol at high pressure and intermediate temperature conditions obtained using a rapid compression machine and recently developed fast sampling system. Iso-butanol ignition delays were acquired for iso-butanol/O2 mixture with an inert/O2 ratio of 7.26, equivalence ratio of 0.4, in the temperature range of 840-950 K and at pressure of 25 bar. Fast sampling and gas chromatography were used to acquire and quantify the intermediate species during the ignition delay of the same mixture at P = 25.3 bar and T = 905 K. The ignition delay times and quantitative measurements of the mole fraction time histories of methane, ethene, propene, iso-butene, iso-butyraldehyde, iso-butanol, and carbon monoxide were compared with predictions from the detailed mechanisms developed by Sarathy et al., Merchant et al., and Cai et al. It is shown that while the Sarathy mechanism well predicts the overall ignition delay time, it overpredicts ethene by a factor of 6-10, underpredicts iso-butene by a factor of 2, and overpredicts iso-butyraldehyde by a factor of 2. Reaction path and sensitivity analyses were carried out to identify the reactions responsible for the observed inadequacy. The rates of iso-butanol hydrogen atom abstraction by OH radical and the beta-scission reactions of hydroxybutyl radicals were updated based on recently published quantum calculation results. Significant improvements were achieved in predicting ignition delay at high pressures (25 and 30 bar) and the species concentrations of ethene and iso-butene. However, the updated mechanism still overpredicts iso-butyraldehyde concentrations. Also, the updated mechanism degrades the prediction in ignition delay at lower pressure (15 bar) compared to the original mechanism developed by Sarathy et al.

  19. Modeling of NO sensitization of IC engines surrogate fuels auto-ignition and combustion

    CERN Document Server

    Anderlohr, Jörg; Bounaceur, Roda; Battin-Leclerc, Frédérique


    This paper presents a new chemical kinetic model developed for the simulation of auto-ignition and combustion of engine surrogate fuel mixtures sensitized by the presence of NOx. The chemical mechanism is based on the PRF auto-ignition model (n-heptane/iso-octane) of Buda et al. [1] and the NO/n-butane/n-pentane model of Glaude et al. [2]. The later mechanism has been taken as a reference for the reactions of NOx with larger alcanes (n-heptane, iso-octane). A coherent two components engine fuel surrogate mechanism has been generated which accounts for the influence of NOx on auto-ignition. The mechanism has been validated for temperatures between 700 K and 1100 K and pressures between 1 and 10 atm covering the temperature and pressure ranges characteristic of engine post-oxidation thermodynamic conditions. Experiments used for validation include jet stirred reactor conditions for species evolution as a function of temperature, as well as diesel HCCI engine experiments for auto-ignition delay time measurements...

  20. Kinetic modelling of a surrogate diesel fuel applied to 3D auto-ignition in HCCI engines

    CERN Document Server

    Bounaceur, Roda; Fournet, René; Battin-Leclerc, Frédérique; Jay, S; Da Cruz, A Pires


    The prediction of auto-ignition delay times in HCCI engines has risen interest on detailed chemical models. This paper described a validated kinetic mechanism for the oxidation of a model Diesel fuel (n-decane and α-methylnaphthalene). The 3D model for the description of low and high temperature auto-ignition in engines is presented. The behavior of the model fuel is compared with that of n-heptane. Simulations show that the 3D model coupled with the kinetic mechanism can reproduce experimental HCCI and Diesel engine results and that the correct modeling of auto-ignition in the cool flame region is essential in HCCI conditions.

  1. Impact of numerical method on auto-ignition in a temporally evolving mixing layer at various initial conditions (United States)

    Rosiak, A.; Tyliszczak, A.


    Numerical analysis of the auto-ignition of turbulent mixing layer between the cold fuel (hydrogen) and hot oxidizer (air) is presented. The research were performed using an Implicit-Large Eddy Simulation (ILES) method with attention on auto-ignition time, flame kernel localisation and propagation. We focused on an impact of discretization method on auto-ignition scenario and flame development. The results obtained showed that numerical approach plays an important role and to some extent may falsify the results, especially for low oxidiser temperatures.

  2. Autoignition characteristics of laminar lifted jet flames of pre-vaporized iso-octane in heated coflow air

    KAUST Repository

    Alnoman, Saeed


    The stabilization characteristics of laminar non-premixed jet flames of pre-vaporized iso-octane, one of the primary reference fuels for octane rating, have been studied experimentally in heated coflow air. Non-autoignited and autoignited lifted flames were analyzed. With the coflow air at relatively low initial temperatures below 940 K, an external ignition source was required to stabilize the flame. These lifted flames had tribrachial edge structures and their liftoff heights correlated well with the jet velocity scaled by stoichiometric laminar burning velocity, indicating the importance of the edge propagation speed on flame stabilization. At high initial temperatures over 940 K, the autoignited flames were stabilized without requiring an external ignition source. These autoignited lifted flames exhibited either tribrachial edge structures or mild combustion behaviors depending on the level of fuel dilution. Two distinct transition behaviors were observed in the autoignition regime from a nozzle-attached flame to a lifted tribrachial-edge flame and then to lifted mild combustion as the jet velocity increased at a certain fuel dilution level. The liftoff data of the autoignited flames with tribrachial edges were analyzed based on calculated ignition delay times. Analysis of the experimental data suggested that ignition delay time may be much less sensitive to initial temperature under atmospheric pressure conditions as compared with predictions. © 2015 Elsevier Ltd. All rights reserved.

  3. Modeling of autoignition and NO sensitization for the oxidation of IC engine surrogate fuels

    CERN Document Server

    Anderlohr, Jörg; Da Cruz, A Pires; Battin-Leclerc, Frédérique; 10.1016/j.combustflame.2008.09.009


    This paper presents an approch for modeling with one single kinetic mechanism the chemistry of the autoignition and combustion processes inside an internal combustion engine, as well as the chemical kinetics governing the post-oxidation of unburned hydrocarbons in engine exhaust gases. Therefore a new kinetic model was developed, valid over a wide range of temperatures including the negative temperature coefficient regime. The model simulates the autoignition and the oxidation of engine surrogate fuels composed of n-heptane, iso-octane and toluene, which are sensitized by the presence of nitric oxides. The new model was obtained from previously published mechanisms for the oxidation of alkanes and toluene where the coupling reactions describing interactions between hydrocarbons and NOx were added. The mechanism was validated against a wide range of experimental data obtained in jet-stirred reactors, rapid compression machines, shock tubes and homogenous charge compression ignition engines. Flow rate and sensi...

  4. Effects of methyl substitution on the auto-ignition of C16 alkanes

    KAUST Repository

    Lapuerta, Magín


    The auto-ignition quality of diesel fuels, quantified by their cetane number or derived cetane number (DCN), is a critical design property to consider when producing and upgrading synthetic paraffinic fuels. It is well known that auto-ignition characteristics of paraffinic fuels depend on their degree of methyl substitution. However, there remains a need to study the governing chemical functionalities contributing to such ignition characteristics, especially in the case of methyl substitutions, which have not been studied in detail. In this work, the auto-ignition of 2,6,10-trimethyltridecane has been compared with the reference hydrocarbons used for cetane number determination, i.e. n-hexadecane and heptamethylnonane, all of them being C16 isomers. Results from a constant-volume combustion chamber under different pressure and temperature initial conditions showed that the ignition delay time for both cool flame and main combustion events increased less from n-hexadecane to trimethyltridecane than from trimethyltridecane to heptamethylnonane. Additional experimental results from blends of these hydrocarbons, together with kinetic modelling, showed that auto-ignition times and combustion rates were correlated to the concentration of the functional groups indicative of methyl substitution, although not in a linear manner. When the concentration of these functional groups decreased, the first stage OH radical concentration increased and ignition delay times decreased, whereas when their concentration increased, H2O2 production was slower and ignition was retarded. Contrary to the ignition delay times, DCN was correlated linearly with functional groups, thus homogenizing the range of values and clarifying the differences between fuels.

  5. Reduction of Large Detailed Chemical Kinetic Mechanisms for Autoignition Using Joint Analyses of Reaction Rates and Sensitivities

    Energy Technology Data Exchange (ETDEWEB)

    Saylam, A; Ribaucour, M; Pitz, W J; Minetti, R


    A new technique of reduction of detailed mechanisms for autoignition, which is based on two analysis methods is described. An analysis of reaction rates is coupled to an analysis of reaction sensitivity for the detection of redundant reactions. Thresholds associated with the two analyses have a great influence on the size and efficiency of the reduced mechanism. Rules of selection of the thresholds are defined. The reduction technique has been successfully applied to detailed autoignition mechanisms of two reference hydrocarbons: n-heptane and iso-octane. The efficiency of the technique and the ability of the reduced mechanisms to reproduce well the results generated by the full mechanism are discussed. A speedup of calculations by a factor of 5.9 for n-heptane mechanism and by a factor of 16.7 for iso-octane mechanism is obtained without losing accuracy of the prediction of autoignition delay times and concentrations of intermediate species.

  6. Global reaction mechanism for the auto-ignition of full boiling range gasoline and kerosene fuels (United States)

    Vandersickel, A.; Wright, Y. M.; Boulouchos, K.


    Compact reaction schemes capable of predicting auto-ignition are a prerequisite for the development of strategies to control and optimise homogeneous charge compression ignition (HCCI) engines. In particular for full boiling range fuels exhibiting two stage ignition a tremendous demand exists in the engine development community. The present paper therefore meticulously assesses a previous 7-step reaction scheme developed to predict auto-ignition for four hydrocarbon blends and proposes an important extension of the model constant optimisation procedure, allowing for the model to capture not only ignition delays, but also the evolutions of representative intermediates and heat release rates for a variety of full boiling range fuels. Additionally, an extensive validation of the later evolutions by means of various detailed n-heptane reaction mechanisms from literature has been presented; both for perfectly homogeneous, as well as non-premixed/stratified HCCI conditions. Finally, the models potential to simulate the auto-ignition of various full boiling range fuels is demonstrated by means of experimental shock tube data for six strongly differing fuels, containing e.g. up to 46.7% cyclo-alkanes, 20% napthalenes or complex branched aromatics such as methyl- or ethyl-napthalene. The good predictive capability observed for each of the validation cases as well as the successful parameterisation for each of the six fuels, indicate that the model could, in principle, be applied to any hydrocarbon fuel, providing suitable adjustments to the model parameters are carried out. Combined with the optimisation strategy presented, the model therefore constitutes a major step towards the inclusion of real fuel kinetics into full scale HCCI engine simulations.

  7. Characteristics of Syngas Auto-ignition at High Pressure and Low Temperature Conditions with Thermal Inhomogeneities

    KAUST Repository

    Pal, Pinaki


    Effects of thermal inhomogeneities on syngas auto-ignition at high-pressure low-temperature conditions, relevant to gas turbine operation, are investigated using detailed one-dimensional numerical simulations. Parametric tests are carried out for a range of thermodynamic conditions (T = 890-1100 K, P = 3-20 atm) and composition (Ф = 0.1, 0.5). Effects of global thermal gradients and localized thermal hot spots are studied. In the presence of a thermal gradient, the propagating reaction front transitions from spontaneous ignition to deflagration mode as the initial mean temperature decreases. The critical mean temperature separating the two distinct auto-ignition modes is computed using a predictive criterion and found to be consistent with front speed and Damkohler number analyses. The hot spot study reveals that compression heating of end-gas mixture by the propagating front is more pronounced at lower mean temperatures, significantly advancing the ignition delay. Moreover, the compression heating effect is dependent on the domain size.

  8. Large Eddy Simulation of Autoignition in a Turbulent Hydrogen Jet Flame Using a Progress Variable Approach

    Directory of Open Access Journals (Sweden)

    Rohit Kulkarni


    Full Text Available The potential of a progress variable formulation for predicting autoignition and subsequent kernel development in a nonpremixed jet flame is explored in the LES (Large Eddy Simulation context. The chemistry is tabulated as a function of mixture fraction and a composite progress variable, which is defined as a combination of an intermediate and a product species. Transport equations are solved for mixture fraction and progress variable. The filtered mean source term for the progress variable is closed using a probability density function of presumed shape for the mixture fraction. Subgrid fluctuations of the progress variable conditioned on the mixture fraction are neglected. A diluted hydrogen jet issuing into a turbulent coflow of preheated air is chosen as a test case. The model predicts ignition lengths and subsequent kernel growth in good agreement with experiment without any adjustment of model parameters. The autoignition length predicted by the model depends noticeably on the chemical mechanism which the tabulated chemistry is based on. Compared to models using detailed chemistry, significant reduction in computational costs can be realized with the progress variable formulation.

  9. Numerical investigation of kinetic energy dynamics during autoignition of n-heptane/air mixture (United States)

    Lucena Kreppel Paes, Paulo; Brasseur, James; Xuan, Yuan


    Many engineering applications involve complex turbulent reacting flows, where nonlinear, multi-scale turbulence-combustion couplings are important. Direct representation of turbulent reacting flow dynamics is associated with prohibitive computational costs, which makes it necessary to employ turbulent combustion models to account for the effects of unresolved scales on resolved scales. Classical turbulence models are extensively employed in reacting flow simulations. However, they rely on assumptions about the energy cascade, which are valid for incompressible, isothermal homogeneous isotropic turbulence. A better understanding of the turbulence-combustion interactions is required for the development of more accurate, physics-based sub-grid-scale models for turbulent reacting flows. In order to investigate the effects of reaction-induced density, viscosity, and pressure variations on the turbulent kinetic energy, Direct Numerical Simulation (DNS) of autoignition of partially-premixed, lean n-heptane/air mixture in three-dimensional homogeneous isotropic turbulence has been performed. This configuration represents standard operating conditions of Homogeneous-Charge Compression-Ignition (HCCI) engines. The differences in the turbulent kinetic energy balance between the present turbulent reacting flow and incompressible, isothermal homogeneous isotropic turbulence are highlighted at different stages during the autoignition process.

  10. Impact of Formaldehyde Addition on Auto-Ignition in Internal-Combustion Engines (United States)

    Kuwahara, Kazunari; Ando, Hiromitsu; Furutani, Masahiro; Ohta, Yasuhiko

    By employing a direct-injection diesel engine equipped with a common-rail type of injection system, by adding formaldehyde (CH2O) to the intake air, and by changing the fuel-injection timing, the compression ratio and the intake-air temperature, a mechanism for CH2O as a fuel additive to affect auto-ignition was discussed. Unlike an HCCI type of engine, the diesel engine can expose an air-fuel mixture only to a limited range of the in-cylinder temperature before the ignition, and can separate low- and high-temperature parts of the mechanism. When low-temperature oxidation starts at a temperature above 900K, there are cases that the CH2O advances the ignition timing. Below 900K, to the contrary, it always retards the timing. It is because, above 900K, a part of the CH2O changes into CO together with H2O2 as an ignition promoter. Below 900K, on the other hand, the CH2O itself acts as an OH radical scavenger against cool-flame reaction, from the beginning of low-temperature oxidation. Then, the engine was modified for its extraordinary function as a gasoline-knocking generator, in order that an effect of CH2O on knocking could be discussed. The CH2O retards the onset of auto-ignition of an end gas. Judging from a large degree of the retardation, the ignition is probably triggered below 900K.

  11. Auto-ignition of lubricating oil working at high pressures in a compressor for an air conditioner

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Chul Jin; Choi, Hyo Hyun [Department of Mechanical Engineering, Sejong University, Seoul 143-747 (Korea, Republic of); Sohn, Chae Hoon, E-mail: [Department of Mechanical Engineering, Sejong University, Seoul 143-747 (Korea, Republic of)


    Auto-ignition of lubricating oil working in a compressor for an air conditioner is studied experimentally. The adopted lubricating oil is an unknown mixture with multi-components and known to have flash point temperature of 170 deg. C. First, its auto-ignition temperature is measured 365 deg. C at atmospheric pressure. The lubricating oil works under high-pressure condition up to 30 atm and it is heated and cooled down repeatedly. Accordingly, auto-ignition temperatures or flammable limits of lubricating oil are required at high pressures with respect to fire safety. Because there is not a standard test method for the purpose, a new ignition-test method is proposed in this study and thereby, auto-ignition temperatures are measured over the pressure range below 30 atm. The measured temperatures range from 215 deg. C to 255 deg. C and they strongly depend on pressure of gas mixture consisting of oil vapor, nitrogen, and oxygen. They are close to flash point temperature and the lubricating oil can be hazardous when it works for high-pressure operating condition and abundant air flows into a compressor.

  12. A detailed experimental study of n-propylcyclohexane autoignition in lean conditions

    Energy Technology Data Exchange (ETDEWEB)

    Crochet, M.; Minetti, R.; Ribaucour, M.; Vanhove, G. [PhysicoChimie des Processus de Combustion et de l' Atmosphere (PC2A), UMR 8522 CNRS - Universite de Lille 1, 59655 Villeneuve d' Ascq Cedex (France)


    The autoignition chemistry of lean n-propylcyclohexane/''air'' mixtures ({phi} = 0.3, 0.4, 0.5) was investigated in a rapid compression machine at compressed gas temperatures ranging from 620 to 930 K and pressures ranging from 0.45 to 1.34 MPa. Cool flame and ignition delay times were measured. Cool flame delay times were found to follow an Arrhenius behavior, and a correlation including pressure and equivalence ratio dependences was deduced. The present ignition delay data were compared with recent experimental results and simulations from the available thermokinetic models in the literature. Negative temperature coefficient zones were observed when plotting ignition delay times versus compressed gas temperature. The oxidation products were identified and quantified during the ignition delay period. Formation pathways for the C{sub 9} bicyclic ethers and conjugate alkenes are proposed. The experimental data provide an extensive database to test detailed thermokinetic oxidation models. (author)

  13. Experimental Autoignition of C4-C6 Saturated and Unsaturated Methyl and Ethyl Esters

    CERN Document Server

    Bennadji, Hayet; Coniglio-Jaubert, Lucie; Billaud, Francis; Glaude, Pierre-Alexandre; Battin-Leclerc, Frédérique


    Autoignition delay times, ?, of methyl crotonate, methyl acrylate, ethyl butanoate, ethyl crotonate, and ethyl acrylate were studied in shock tube experiments. A series of mixtures diluted with argon, of varying fuel/oxygen equivalence ratios (?=0.25, 0.4, 1.0, and 2.0), were measured behind reflected shock waves over the temperature range of 1280-1930 K, pressure range of 7-9.65 atm, during which the logarithm of ? varies linearly as a function of the inverse temperature for all equivalence ratios. The ignition delay time decreases as temperature rises. The dependence of ? on temperature, and reactant concentrations is given in an empirical correlation. The results provide a database for the validation of small saturated and unsaturated esters kinetic mechanisms at elevated temperatures and pressure combustion.


    Directory of Open Access Journals (Sweden)

    Neven Duić


    Full Text Available The adaptation of auto-ignition tabulation for effective use of complex chemical mechanisms will be presented in this paper. Taking cool flame ignition phenomenon into account could improve numerical simulations of combustion in compression ignition engines. Current approaches of successful simulation of this phenomenon are based on the extraction of ignition delay times, heat releases and also reaction rates from tabulated data dependant on four parameters: temperature, pressure, equivalence ratio and exhaust gasses mass fraction. The methods described here were used to create lookup tables including cool flame using a comprehensive chemical mechanism without including reaction rates data (as used by other authors. The method proved to be stable for creating tables and these results will be shown, as well as initial implementation results using the tables in computational fluid dynamics software.

  15. Numerical simulation of the autoignition of hydrogen-air mixtures behind shock waves (United States)

    Tereza, A. M.; Smirnov, V. N.; Vlasov, P. A.; Lyubimov, A. V.; Sokolova, I. L.; Shumova, V. V.; Ziborov, V. S.


    Problems related to the autoignition of hydrogen-air mixtures are highly important for the operation safety of nuclear reactors and for hydrogen power engineering. In spite of extensive studies in this area, there are still many problems directly concerned with the ignition delay times of H2/O2 mixtures and with the conditions under which these processes occur. This paper deals with the numerical analysis of the data available in the literature on O, H, and OH yields in order to determine the influence of the primary channels of the initiation of H2/Air mixtures. The numerical modeling of the available literature data on the ignition delays of hydrogen-air mixtures made it possible to describe the shock tube measurements of ignition delays within the framework of a unified kinetic mechanism over a temperature range of 930-2500 K at pressures from 0.1 to 8.7 MPa.

  16. Three-stage autoignition of gasoline in an HCCI engine: An experimental and chemical kinetic modeling investigation

    Energy Technology Data Exchange (ETDEWEB)

    Machrafi, Hatim; Cavadias, Simeon [UPMC Universite Paris 06, LGPPTS, Ecole Nationale Superieure de Chimie de Paris (France); UPMC Universite Paris 06, Institut Jean Le Rond D' Alembert (France)


    The alternative HCCI combustion mode presents a possible means for decreasing the pollution with respect to conventional gasoline or diesel engines, while maintaining the efficiency of a diesel engine or even increasing it. This paper investigates the possibility of using gasoline in an HCCI engine and analyzes the autoignition of gasoline in such an engine. The compression ratio that has been used is 13.5, keeping the inlet temperature at 70 C, varying the equivalence ratio from 0.3 to 0.54, and the EGR (represented by N{sub 2}) ratio from 0 to 37 vol%. For comparison, a PRF95 and a surrogate containing 11 vol% n-heptane, 59 vol% iso-octane, and 30 vol% toluene are used. A previously validated kinetic surrogate mechanism is used to analyze the experiments and to yield possible explanations to kinetic phenomena. From this work, it seems quite possible to use the high octane-rated gasoline for autoignition purposes, even under lean inlet conditions. Furthermore, it appeared that gasoline and its surrogate, unlike PRF95, show a three-stage autoignition. Since the PRF95 does not contain toluene, it is suggested by the kinetic mechanism that the benzyl radical, issued from toluene, causes this so-defined ''obstructed preignition'' and delaying thereby the final ignition for gasoline and its surrogate. The results of the kinetic mechanism supporting this explanation are shown in this paper. (author)

  17. Third O2 addition reactions promote the low-temperature auto-ignition of n-alkanes

    KAUST Repository

    Wang, Zhandong


    Comprehensive low-temperature oxidation mechanisms are needed to accurately predict fuel auto-ignition properties. This paper studies the effects of a previously unconsidered third O2 addition reaction scheme on the simulated auto-ignition of n-alkanes. We demonstrate that this extended low-temperature oxidation scheme has a minor effect on the simulation of n-pentane ignition; however, its addition significantly improves the prediction of n-hexane auto-ignition under low-temperature rapid compression machine conditions. Additional simulations of n-hexane in a homogeneous charge compression ignition engine show that engine-operating parameters (e.g., intake temperature and combustion phasing) are significantly altered when the third O2 addition kinetic mechanism is considered. The advanced combustion phasing is initiated by the formation and destruction of additional radical chain-branching intermediates produced in the third O2 addition process, e.g. keto-dihydroperoxides and/or keto-hydroperoxy cyclic ethers. Our results indicate that third O2 addition reactions accelerate low-temperature radical chain branching at conditions of relevance to advance engine technologies, and therefore these chemical pathways should also be considered for n-alkanes with 6 or more carbon atoms. © 2015 The Combustion Institute.

  18. Numerical and experimental studies of ethanol flames and autoignition theory for higher alkanes (United States)

    Saxena, Priyank

    In order to enhance the fuel efficiency of an engine and to control pollutant formation, an improved understanding of the combustion chemistry of the fuels at a fundamental level is paramount. This knowledge can be gained by developing detailed reaction mechanisms of the fuels for various combustion processes and by studying combustion analytically employing reduced-chemistry descriptions. There is a need for small detailed reaction mechanisms for alkane and alcohol fuels with reduced uncertainties in their combustion chemistry that are computationally cheaper in multidimensional CFD calculations. Detailed mechanisms are the starting points in identifying reduced-chemistry descriptions of combustion processes to study problems analytically. This research includes numerical, experimental and analytical studies. The first part of the dissertation consists of numerical and experimental studies of ethanol flames. Although ethanol has gained popularity as a possible low-pollution source of renewable energy, significant uncertainties remain in its combustion chemistry. To begin to address ethanol combustion, first a relatively small detailed reaction mechanism, commonly known as the San Diego Mech, is developed for the combustion of hydrogen, carbon monoxide, formaldehyde, methane, methanol, ethane, ethylene, and acetylene, in air or oxygen-inert mixtures. This mechanism is tested for autoignition, premixed-flame burning velocities, and structures and extinction of diffusion flames and of partially premixed flames of many of these fuels. The reduction in uncertainties in the combustion chemistry can best be achieved by consistently updating a reaction mechanism with reaction rate data for the elementary steps based on newer studies in literature and by testing it against as many experimental conditions as available. The results of such a testing for abovementioned fuels are reported here along with the modifications of reaction-rate parameters of the most important

  19. Experiments and modeling of the autoignition of methylcyclohexane at high pressure

    KAUST Repository

    Weber, Bryan W.


    New experimental data are collected for methyl-cyclohexane (MCH) autoignition in a heated rapid compression machine (RCM). Three mixtures of MCH/O2/N2/Ar at equivalence ratios of φ=0.5, 1.0, and 1.5 are studied and the ignition delays are measured at compressed pressure of 50bar and for compressed temperatures in the range of 690-900K. By keeping the fuel mole fraction in the mixture constant, the order of reactivity, in terms of inverse ignition delay, is measured to be φ=0.5>φ=1.0>φ=1.5, demonstrating the dependence of the ignition delay on oxygen concentration. In addition, an existing model for the combustion of MCH is updated with new reaction rates and pathways, including substantial updates to the low-temperature chemistry. The new model shows good agreement with the overall ignition delays measured in this study, as well as the ignition delays measured previously in the literature using RCMs and shock tubes. This model therefore represents a strong improvement compared to the previous version, which uniformly over-predicted the ignition delays. Chemical kinetic analyses of the updated mechanism are also conducted to help understand the fuel decomposition pathways and the reactions controlling the ignition. Combined, these results and analyses suggest that further investigation of several of the low-temperature fuel decomposition pathways is required. © 2014 The Combustion Institute.

  20. Numerical Simulations of a Prechamber Autoignition Engine Operating on Natural Gas

    Directory of Open Access Journals (Sweden)

    Daniel Favrat


    Full Text Available

    At our laboratory extensive research has been conducted on the conversion of conventional Diesel cogeneration engines to operation on natural gas and biogas. In the framework of this research, a numerical simulation of a prechamber autoignition gas engine has been performed based on an experimental test case. With a simplified finite-rate/eddy-dissipation model for the combustion of natural gas, it was possible to properly reproduce the experiment considering the combustion duration, ignition timing and overall energy balance. A modification of the original cylindrical-conical prechamber geometry to a simpler cylindrical one was tested with the simulation model. The influence of burnt gases inside the prechamber was assessed simulating the mixture formation inside the prechamber. The simulations showed little effect of taking into account the non-homogeneities in the gas phase on the combustion duration. The new cylindrical geometry envisaged did not show any improvement in the combustion homogeneity inside the prechamber and its volume (limited by the real engine geometry is in fact not sufficient to properly ignite the main chamber according to the simulations. The model can be used to further guide design modifications of the prechamber engine to improve performance.

  1. Auto-ignitions of a methane/air mixture at high and intermediate temperatures (United States)

    Leschevich, V. V.; Martynenko, V. V.; Penyazkov, O. G.; Sevrouk, K. L.; Shabunya, S. I.


    A rapid compression machine (RCM) and a shock tube (ST) have been employed to study ignition delay times of homogeneous methane/air mixtures at intermediate-to-high temperatures. Both facilities allow measurements to be made at temperatures of 900-2000 K, at pressures of 0.38-2.23 MPa, and at equivalence ratios of 0.5, 1.0, and 2.0. In ST experiments, nitrogen served as a diluent gas, whereas in RCM runs the diluent gas composition ranged from pure nitrogen to pure argon. Recording pressure, UV, and visible emissions identified the evolution of chemical reactions. Correlations of ignition delay time were generated from the data for each facility. At temperatures below 1300 K, a significant reduction of average activation energy from 53 to 15.3 kcal/mol was obtained. Moreover, the RCM data showed significant scatter that dramatically increased with decreasing temperature. An explanation for the abnormal scatter in the data was proposed based on the high-speed visualization of auto-ignition phenomena and experiments performed with oxygen-free and fuel-free mixtures. It is proposed that the main reason for such a significant reduction of average activation energy is attributable to the premature ignition of ultrafine particles in the reactive mixture.

  2. The vitiation effects of water vapor and carbon dioxide on the autoignition characteristics of kerosene (United States)

    Liang, Jin-Hu; Wang, Su; Zhang, Sheng-Tao; Yue, Lian-Jie; Fan, Bing-Cheng; Zhang, Xin-Yu; Cui, Ji-Ping


    In ground tests of hypersonic scramjet, the high-enthalpy airstream produced by burning hydrocarbon fuels often contains contaminants of water vapor and carbon dioxide. The contaminants may change the ignition characteristics of fuels between ground tests and real flights. In order to properly assess the influence of the contaminants on ignition characteristics of hydrocarbon fuels, the effect of water vapor and carbon dioxide on the ignition delay times of China RP-3 kerosene was studied behind reflected shock waves in a preheated shock tube. Experiments were conducted over a wider temperature range of 800-1 500K, at a pressure of 0.3 MPa, equivalence ratios of 0.5 and 1, and oxygen concentration of 20%. Ignition delay times were determined from the onset of the excited radical OH emission together with the pressure profile. Ignition delay times were measured for four cases: (1) clean gas, (2) gas vitiated with 10% and 20% water vapor in mole, (3) gas vitiated with 10% carbon dioxide in mole, and (4) gas vitiated with 10% water vapor and 10% carbon dioxide, 20% water vapor and 10% carbon dioxide in mole. The results show that carbon dioxide produces an inhibiting effect at temperatures below 1 300 K when ϕ = 0.5, whereas water vapor appears to accelerate the ignition process below a critical temperature of about 1 000 K when ϕ = 0.5. When both water vapor and carbon dioxide exist together, a minor inhibiting effect is observed at ϕ = 0.5, while no effect is found at ϕ = 1.0. The results are also discussed preliminary by considering both the combustion reaction mechanism and the thermophysics properties of the fuel mixtures. The current measurements demonstrate vitiation effects of water vapor and carbon dioxide on the autoignition characteristics of China RP-3 kerosene at air-like O2 concentration. It is important to account for such effects when data are extrapolated from ground testing to real flight conditions.

  3. Comparative Shock-Tube Study of Autoignition and Plasma-Assisted Ignition of C2-Hydrocarbons (United States)

    Kosarev, Ilya; Kindysheva, Svetlana; Plastinin, Eugeny; Aleksandrov, Nikolay; Starikovskiy, Andrey


    The dynamics of pulsed picosecond and nanosecond discharge development in liquid water, ethanol and hexane Using a shock tube with a discharge cell, ignition delay time was measured in a lean (φ = 0.5) C2H6:O2:Ar mixture and in lean (φ = 0.5) and stoichiometric C2H4:O2:Ar mixtures with a high-voltage nanosecond discharge and without it. The measured results were compared with the measurements made previously with the same setup for C2H6-, C2H5OH- and C2H2-containing mixtures. It was shown that the effect of plasma on ignition is almost the same for C2H6, C2H4 and C2H5OH. The reduction in time is smaller for C2H2, the fuel that is well ignited even without the discharge. Autoignition delay time was independent of the stoichiometric ratio for C2H6 and C2H4, whereas this time in stoichiometric C2H2- and C2H5OH-containing mixtures was noticeably shorter than that in the lean mixtures. Ignition after the discharge was not affected by a change in the stoichiometric ratio for C2H2 and C2H4, whereas the plasma-assisted ignition delay time for C2H6 and C2H5OH decreased as the equivalence ratio changed from 1 to 0.5. Ignition delay time was calculated in C2-hydrocarbon-containing mixtures under study by simulating separately discharge and ignition processes. Good agreement was obtained between new measurements and calculated ignition delay times.

  4. Combined impact of branching and unsaturation on the autoignition of binary blends in a motored engine

    KAUST Repository

    Kang, Dongil


    The impact of a branched and unsaturated compound (diisobutylene) mixed with simple hydrocarbons such as n-heptane and isooctane in binary blends on the autoignition behavior were investigated in a modified cooperative fuel research (CFR) engine at an equivlanece ratio of 0.5 and intake temperature of 120 °C. From this test condition, a homogeneous charge of fuel and intake air can be achieved. The test fuels were prepared by addition of 5-20 vol % diisobutylene into n-heptane and isooctane. The engine compression ratio (CR) was gradually increased from the lowest point to the point where significant high temperature heat release (HTHR) was observed, and this point is also referred to as the critical compression ratio (CCR). Heat release analysis showed that each n-heptane blend had a noticeable low temperature heat release (LTHR), which was not observed in the isooctane blends. The gradual addition of diisobutylene into each primary reference fuel contributed to retarded high temperature heat release in these binary blends, increasing the in-cylinder temperature and decreasing formation of CO. The 15 and 20 vol % blends of diisobutylene in isooctane were not able to reach high temperature heat release in the CFR engine system under these test conditions. The fundamental ignition behavior such as CCR and calculated % LTHR show the impact of the presence of the C-C double bond on ignition reactivity. Species concentration profiles obtained in condensed products from the engine exhaust were measured via gas chromatrography-mass spectrometry and -flame ionization detector. The major intermediate species for each blend were captured at a compression ratio selected just before the high temperature heat release was observed. Most intermediate species were derived from n-heptane and isooctane, while diisobutylene rarely participated in forming any major species, with the exception of the formation of 4,4-dimethyl-2-pentanone. Addition of diisobutylene exhibited opposite

  5. An experimental and numerical investigation on the influence of external gas recirculation on the HCCI autoignition process in an engine: Thermal, diluting, and chemical effects

    Energy Technology Data Exchange (ETDEWEB)

    Machrafi, Hatim; Cavadias, Simeon [UPMC Universite Paris 06, LGPPTS, Ecole Nationale Superieure de Chimie de Paris, 11, rue de Pierre et Marie Curie, 75005 Paris (France); UPMC Universite Paris 06, FRT, Institut Jean Le Rond D' Alembert, 2, place de la Gare de Ceinture, 78210 St Cyr l' Ecole (France); Guibert, Philippe [UPMC Universite Paris 06, FRT, Institut Jean Le Rond D' Alembert, 2, place de la Gare de Ceinture, 78210 St Cyr l' Ecole (France)


    In order to contribute to the solution of controlling the autoignition in a homogeneous charge compression ignition (HCCI) engine, parameters linked to external gas recirculation (EGR) seem to be of particular interest. Experiments performed with EGR present some difficulties in interpreting results using only the diluting and thermal aspect of EGR. Lately, the chemical aspect of EGR is taken more into consideration, because this aspect causes a complex interaction with the dilution and thermal aspects of EGR. This paper studies the influence of EGR on the autoignition process and particularly the chemical aspect of EGR. The diluents present in EGR are simulated by N{sub 2} and CO{sub 2}, with dilution factors going from 0 to 46 vol%. For the chemically active species that could be present in EGR, the species CO, NO, and CH{sub 2}O are used. The initial concentration in the inlet mixture of CO and NO is varied between 0 and 170 ppm, while that of CH{sub 2}O alters between 0 and 1400 ppm. For the investigation of the effect of the chemical species on the autoignition, a fixed dilution factor of 23 vol% and a fixed EGR temperature of 70 C are maintained. The inlet temperature is held at 70 C, the equivalence ratios between 0.29 and 0.41, and the compression ratio at 10.2. The fuels used for the autoignition are n-heptane and PRF40. It appeared that CO, in the investigated domain, did not influence the ignition delays, while NO had two different effects. At concentrations up until 45 ppm, NO advanced the ignition delays for the PRF40 and at higher concentrations, the ignition delayed. The influence of NO on the autoignition of n-heptane seemed to be insignificant, probably due to the higher burn rate of n-heptane. CH{sub 2}O seemed to delay the ignition. The results suggested that especially the formation of OH radicals or their consumption by the chemical additives determines how the reactivity of the autoignition changed. (author)

  6. A Phenomenological Model for Prediction Auto-Ignition and Soot Formation of Turbulent Diffusion Combustion in a High Pressure Common Rail Diesel Engine

    Directory of Open Access Journals (Sweden)

    Qinghui Zhou


    Full Text Available A new phenomenological model, the TP (Temperature Phase model, is presented to carry out optimization calculations for turbulent diffusion combustion in a high-pressure common rail diesel engine. Temperature is the most important parameter in the TP model, which includes two parts: an auto-ignition and a soot model. In the auto-ignition phase, different reaction mechanisms are built for different zones. For the soot model, different methods are used for different temperatures. The TP model is then implemented in KIVA code instead of original model to carry out optimization. The results of cylinder pressures, the corresponding heat release rates, and soot with variation of injection time, variation of rail pressure and variation of speed among TP model, KIVA standard model and experimental data are analyzed. The results indicate that the TP model can carry out optimization and CFD (computational fluid dynamics and can be a useful tool to study turbulent diffusion combustion.

  7. Autoignition characterization of primary reference fuels and n-heptane/n-butanol mixtures in a constant volume combustion device and homogeneous charge compression ignition engine

    KAUST Repository

    Baumgardner, Marc E.


    In this study, the autoignition behavior of primary reference fuels (PRF) and blends of n-heptane/n-butanol were examined in a Waukesha Fuel Ignition Tester (FIT) and a Homogeneous Charge Compression Engine (HCCI). Fourteen different blends of iso-octane, n-heptane, and n-butanol were tested in the FIT - 28 test runs with 25 ignition measurements for each test run, totaling 350 individual tests in all. These experimental results supported previous findings that fuel blends with high alcohol content can exhibit very different ignition delay periods than similarly blended reference fuels. The experiments further showed that n-butanol blends behaved unlike PRF blends when comparing the autoignition behavior as a function of the percentage of low reactivity component. The HCCI and FIT experimental results favorably compared against single and multizone models with detailed chemical kinetic mechanisms - both an existing mechanism as well as one developed during this study were used. The experimental and modeling results suggest that that the FIT instrument is a valuable tool for analysis of high pressure, low temperature chemistry, and autoignition for future fuels in advanced combustion engines. Additionally, in both the FIT and engine experiments the fraction of low temperature heat release (fLTHR) was found to correlate very well with the crank angle of maximum heat release and shows promise as a useful metric for fuel reactivity in advanced combustion applications. © 2013 American Chemical Society.

  8. Investigation of Spark Ignition and Autoignition in Methane and Air Using Computational Fluid Dynamics and Chemical Reaction Kinetics. A numerical Study of Ignition Processes in Internal Combustion Engines

    Energy Technology Data Exchange (ETDEWEB)

    Nordrik, R.


    The processes in the combustion chamber of internal combustion engines have received increased attention in recent years because their efficiencies are important both economically and environmentally. This doctoral thesis studies the ignition phenomena by means of numerical simulation methods. The fundamental physical relations include flow field conservation equations, thermodynamics, chemical reaction kinetics, transport properties and spark modelling. Special attention is given to the inclusion of chemical kinetics in the flow field equations. Using his No Transport of Radicals Concept method, the author reduces the computational efforts by neglecting the transport of selected intermediate species. The method is validated by comparison with flame propagation data. A computational method is described and used to simulate spark ignition in laminar premixed methane-air mixtures and the autoignition process of a methane bubble surrounded by hot air. The spark ignition simulation agrees well with experimental results from the literature. The autoignition simulation identifies the importance of diffusive and chemical processes acting together. The ignition delay times exceed the experimental values found in the literature for premixed ignition delay, presumably because of the mixing process and lack of information on low temperature reactions in the skeletal kinetic mechanism. Transient turbulent methane jet autoignition is simulated by means of the KIVA-II code. Turbulent combustion is modelled by the Eddy Dissipation Concept. 90 refs., 81 figs., 3 tabs.

  9. The development and experimental validation of a reduced ternary kinetic mechanism for the auto-ignition at HCCI conditions, proposing a global reaction path for ternary gasoline surrogates

    Energy Technology Data Exchange (ETDEWEB)

    Machrafi, Hatim; Cavadias, Simeon; Amouroux, Jacques [UPMC Universite Paris 06, LGPPTS, Ecole Nationale Superieure de Chimie de Paris, 11, rue de Pierre et Marie Curie, 75005 Paris (France)


    To acquire a high amount of information of the behaviour of the Homogeneous Charge Compression Ignition (HCCI) auto-ignition process, a reduced surrogate mechanism has been composed out of reduced n-heptane, iso-octane and toluene mechanisms, containing 62 reactions and 49 species. This mechanism has been validated numerically in a 0D HCCI engine code against more detailed mechanisms (inlet temperature varying from 290 to 500 K, the equivalence ratio from 0.2 to 0.7 and the compression ratio from 8 to 18) and experimentally against experimental shock tube and rapid compression machine data from the literature at pressures between 9 and 55 bar and temperatures between 700 and 1400 K for several fuels: the pure compounds n-heptane, iso-octane and toluene as well as binary and ternary mixtures of these compounds. For this validation, stoichiometric mixtures and mixtures with an equivalence ratio of 0.5 are used. The experimental validation is extended by comparing the surrogate mechanism to experimental data from an HCCI engine. A global reaction pathway is proposed for the auto-ignition of a surrogate gasoline, using the surrogate mechanism, in order to show the interactions that the three compounds can have with one another during the auto-ignition of a ternary mixture. (author)

  10. Structural, Optical, and Compactness Characteristics of Nanocrystalline CaNb2O6 Synthesized through an Autoigniting Combustion Method

    Directory of Open Access Journals (Sweden)

    K. C. Mathai


    Full Text Available Nanoparticles of calcium metaniobate compound are prepared by an autoigniting combustion technique and its structural, optical, and dielectric properties are investigated. The X-ray diffraction, Fourier-transform Raman, and infrared studies reveal that calcium metaniobate possesses phase pure orthorhombic columbite structure with space group of Pbcn. The average particle size of the as-prepared nanoparticles obtained from both the Scherrer formula and transmission electron microscopy is ~37 nm. The optical band gap calculated from Tauc's Plot is 3.25 eV. Photoluminescence studies reveal that Calcium metaniobate can be used as an idealphotoluminarmaterial. The powders are pelletised and sintered at an optimized temperature of 1350∘C in a short duration of two hours, yielding a high density. The morphology of the sintered pellet is further examined using scanning electron microscopy. The dielectric constant and loss factor values measured at 5 MHz for a well-sintered Calcium metaniobate pellet are found to be 27.6 and 5.3×10−4 respectively, at room temperature.

  11. An experimental and numerical analysis of the HCCI auto-ignition process of primary reference fuels, toluene reference fuels and diesel fuel in an engine, varying the engine parameters

    Energy Technology Data Exchange (ETDEWEB)

    Machrafi, Hatim; Cavadias, Simeon [UPMC Universite Paris 06, LGPPTS, Ecole Nationale Superieure de Chimie de Paris, 11, rue de Pierre et Marie Curie, 75005 Paris (France); UPMC Universite Paris 06, Institut Jean Le Rond D' Alembert, 2, place de la Gare de Ceinture, 78210 St Cyr-I' Ecole (France); Gilbert, Philippe [UPMC Universite Paris 06, Institut Jean Le Rond D' Alembert, 2, place de la Gare de Ceinture, 78210 St Cyr-I' Ecole (France)


    For a future HCCI engine to operate under conditions that adhere to environmental restrictions, reducing fuel consumption and maintaining or increasing at the same time the engine efficiency, the choice of the fuel is crucial. For this purpose, this paper presents an auto-ignition investigation concerning the primary reference fuels, toluene reference fuels and diesel fuel, in order to study the effect of linear alkanes, branched alkanes and aromatics on the auto-ignition. The auto-ignition of these fuels has been studied at inlet temperatures from 25 to 120 C, at equivalence ratios from 0.18 to 0.53 and at compression ratios from 6 to 13.5, in order to extend the range of investigation and to assess the usability of these parameters to control the auto-ignition. It appeared that both iso-octane and toluene delayed the ignition with respect to n-heptane, while toluene has the strongest effect. This means that aromatics have higher inhibiting effects than branched alkanes. In an increasing order, the inlet temperature, equivalence ratio and compression ratio had a promoting effect on the ignition delays. A previously experimentally validated reduced surrogate mechanism, for mixtures of n-heptane, iso-octane and toluene, has been used to explain observations of the auto-ignition process. (author)

  12. Influence of variable valve timings on the gas exchange process in a controlled auto-ignition engine

    Energy Technology Data Exchange (ETDEWEB)

    Milovanovic, N.; Chen, R. [Loughborough University (United Kingdom). Aeronautical and Autumotive Dept.; Turner, J. [Lotus Engineering (United Kingdom). Powertrain Research Dept.


    The controlled auto-ignition (CAI) engine concept has the potential to be highly efficient and to produce low NO{sub x} and particulate matter emissions. However, the problem of controlling the combustion over the entire load/speed range limits its practical application. The CAI combustion is controlled by the chemical kinetics of the charge mixture, with no influence of the flame diffusion or turbulent propagation. Therefore, to achieve successful control of the CAI process, the composition, temperature and pressure of the charge mixture at the inlet valve closure (IC) point has to be controlled. The use of the variable valve timing strategy, which enables quick changes in the amount of trapped hot exhaust gases, shows the potential for control of CAI combustion. The aim of this paper is to analyse the influence of the variable valve timing strategy on the gas exchange process, the process between the first valve open event (EO) and the last valve closing event (IC), in a CAI engine fuelled with standard gasoline fuel (95RON). The gas exchange process affects the engine parameters and charge properties and therefore plays a crucial role in determining the control of the CAI process. Analysis is performed by experimental and modelling approaches. A single-cylinder research engine equipped with a fully variable valvetrain (FVVT ) system was used for the experimental study. A combined code consisting of a detailed chemical kinetics code and one-dimensional fluid dynamics code was used for the modelling study. The results obtained indicate that the variable valve timing strategy has a strong influence on the gas exchange process, which in turn influences the engine parameters and the cylinder charge properties, and hence the control of the CAI process. The EC timing has the strongest effect, followed by the 10 timing, while the EO and IC timings have minor effects. (author)

  13. The autoignition of C{sub 8}H{sub 10} aromatics at moderate temperatures and elevated pressures

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Hsi-Ping S.; Oehlschlaeger, Matthew A. [Department of Mechanical, Aerospace, and Nuclear Engineering, Rensselaer Polytechnic Institute, Troy, NY (United States)


    The autoignition of C{sub 8}H{sub 10} aromatic/air mixtures (ortho-xylene, meta-xylene, para-xylene, and ethylbenzene in air) has been studied in a shock tube at temperatures of 941-1408 K, pressures of 9-45 atm, and equivalence ratios of {phi}=1.0 and 0.5. Ignition times were determined using electronically excited OH emission and pressure measurements. The measurements illustrate the differences in reactivity for the C{sub 8}H{sub 10} aromatics under the studied conditions. Ethylbenzene was by far the most reactive C{sub 8}H{sub 10} aromatic with ignition times a factor of two to three shorter than the xylenes. The xylene isomers exhibited ignition times that were similar, with o-xylene the most reactive, p-xylene the least reactive, and m-xylene just slightly more reactive than p-xylene. The p-xylene ignition times are almost identical to previous measurements for toluene at the same conditions. The differences in reactivity can be attributed to the C-H and C-C bond strengths in the alkyl side chains and the proximity of the methyl groups in the xylenes. These results represent the first ignition measurements for C{sub 8}H{sub 10} aromatics at the elevated-pressure moderate-temperature conditions studied, providing needed targets for kinetic modeling at engine-relevant conditions. Kinetic modeling illustrates the importance of the methylbenzyl + HO{sub 2} reaction and indicates further study of this reaction is warranted. (author)

  14. Development and application of autoignition burner%自动点火燃烧器的研制与应用

    Institute of Scientific and Technical Information of China (English)

    李卫权; 白田增; 吴德; 富玉海; 仪忠建; 任严


    钻井、井下作业及油井测试过程中将产生含有较多甲烷、乙烷以及少量易挥发的液态烃及微量的二氧化碳、氮、硫化氢等杂质的伴生气,给安全生产带来重大隐患。为了解决该问题,研发了自动点火燃烧器,该装置用太阳能电池板提供能源,当伴生气压力超过0.1 MPa时,控制系统自动打火点燃液化气,引燃燃烧区内伴生气。现场应用表明,该燃烧器结构设计合理,拆装、运输方便,使用过程中不产生明火,比以往同类手动产品更加安全可靠。%Drilling, downhole operation and oil well testing will generate associated gas which has high content of methane, ethane, small content of volatile liquid hydrocarbon as well as trace amount of carbon dioxide, nitrogen, hydrogen sulifde and other impurities, bringing about major hidden danger to production safety. An autoignition burner is developed, which adopts solar panel to provide energy. When associated gas pressure exceeds 0.1 MPa, control system will enable automatic ignition to ignite liqueifed gas combustion rod, thus to ignite the associated gas in combustion area. It is shown from ifeld application that the burner features reasonable structure design, convenient assembly or disassembly and transportation, and is not easy to generate open ifre, thus the burner is safer and more reliable than previous similar manual products.

  15. The possibility of controlled auto-ignition (CAI) in gasoline engine and gas to liquid (GTL) as a fuel of diesel engine in Korea

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, D. [Korea Inst. of Machinery and Materials, Daejou (Korea)


    A significant challenge grows from the ever-increasing demands for the optimization of performance, emissions, fuel economy and drivability. The most powerful technologies in the near future to improve these factors are believed Controlled Auto-Ignition (CAI) in gasoline engine and Gas to Liquid (GTL) as a fuel of Diesel engine. In recent years there has been an increasing trend to use more complex valvetrain designs from traditional camshaft driven mechanical systems to camless electromagnetic or electrohydraulic solutions. Comparing to fixed valve actuation systems, variable valve actuation (VVA) should be powerful to optimize the engine cycle. The matching of valve events to the engine performance and to emission requirements at a given engine or vehicle operating condition can be further optimized to the Controlled Auto-Ignition (CAI) in gasoline engine, which has benefits in NOx emission, fuel consumption, combustion stability and intake throttle load. In case of Diesel engine, the increasing demands for NOx and soot emission reduction have introduced aftertreatment technologies recently, but been in need of basic solution for the future, such as a super clean fuel like Gas to Liquid (GTL), which has benefits in comparability to diesel fuel, independency from crude oil and reduction of CO, THC and soot emissions. Korea looks to the future with these kinds of technologies, and tries to find the possibility for reaching the future targets in the internal combustion engine. (orig.)

  16. Experimental and Numerical Study on Effect of Sample Orientation on Auto-Ignition and Piloted Ignition of Poly(methyl methacrylate

    Directory of Open Access Journals (Sweden)

    Fei Peng


    Full Text Available In this work, the effect of seven different sample orientations from 0° to 90° on pilot and non-pilot ignition of PMMA (poly(methyl methacrylate exposed to radiation has been studied with experimental and numerical methods. Some new and significant conclusions are drawn from the study, including a U-shape curve of ignition time and critical mass flux as sample angle increases for pilot ignition conditions. However, in auto-ignition, the ignition time and critical mass flux increases with sample angle α. Furthermore, a computational fluid dynamic model have been built based on the Fire Dynamics Simulator (FDS6 code to investigate the mechanisms controlling the dependence on sample orientation of the ignition of PMMA under external radiant heating. The results of theoretical analysis and modeling results indicate the decrease of total incident heat flux at sample surface plays the dominant role during the ignition processes of auto-ignition, but the volatiles gas flow has greater influence for piloted ignition conditions.

  17. Influence of fuel type, dilution and equivalence ratio on the emission reduction from the auto-ignition in an Homogeneous Charge Compression Ignition engine

    Energy Technology Data Exchange (ETDEWEB)

    Machrafi, Hatim [UPMC Universite Paris 06, ENSCP, 11 rue de Pierre et Marie Curie, 75005 Paris (France); UPMC Universite Paris 06, Institut Jean Le Rond D' Alembert, 4 place Jussieu, 75252 Paris cedex 05 (France); Universite Libre de Bruxelles, TIPs - Fluid Physics, CP165/67, 50 Avenue F.D. Roosevelt, 1050 Brussels (Belgium); Cavadias, Simeon [UPMC Universite Paris 06, ENSCP, 11 rue de Pierre et Marie Curie, 75005 Paris (France); UPMC Universite Paris 06, Institut Jean Le Rond D' Alembert, 4 place Jussieu, 75252 Paris cedex 05 (France); Amouroux, Jacques [UPMC Universite Paris 06, ENSCP, 11 rue de Pierre et Marie Curie, 75005 Paris (France)


    One technology that seems to be promising for automobile pollution reduction is the Homogeneous Charge Compression Ignition (HCCI). This technology still faces auto-ignition and emission-control problems. This paper focuses on the emission problem, since it is incumbent to realize engines that pollute less. For this purpose, this paper presents results concerning the measurement of the emissions of CO, NO{sub x}, CO{sub 2}, O{sub 2} and hydrocarbons. HCCI conditions are used, with equivalence ratios between 0.26 and 0.54, inlet temperatures of 70 C and 120 C and compression ratios of 10.2 and 13.5, with different fuel types: gasoline, gasoline surrogate, diesel, diesel surrogate and mixtures of n-heptane/toluene. The effect of dilution is considered for gasoline, while the effect of the equivalence ratio is considered for all the fuels. No significant amount of NO{sub x} has been measured. It appeared that the CO, O{sub 2} and hydrocarbon emissions were reduced by decreasing the toluene content of the fuel and by decreasing the dilution. The opposite holds for CO{sub 2}. The reduction of the hydrocarbon emission appears to compete with the reduction of the CO{sub 2} emission. Diesel seemed to produce less CO and hydrocarbons than gasoline when auto-ignited. An example of emission reduction control is presented in this paper. (author)

  18. An experimental and numerical analysis of the influence of the inlet temperature, equivalence ratio and compression ratio on the HCCI auto-ignition process of Primary Reference Fuels in an engine

    Energy Technology Data Exchange (ETDEWEB)

    Machrafi, Hatim [UPMC Universite Paris 06, LGPPTS, Ecole Nationale Superieure de Chimie de Paris, 11, rue de Pierre et Marie Curie, 75005 Paris (France); UPMC Universite Paris 06, Institut Jean Le Rond D' Alembert (France); Cavadiasa, Simeon [UPMC Universite Paris 06, Institut Jean Le Rond D' Alembert (France)


    In order to understand better the auto-ignition process in an HCCI engine, the influence of some important parameters on the auto-ignition is investigated. The inlet temperature, the equivalence ratio and the compression ratio were varied and their influence on the pressure, the heat release and the ignition delays were measured. The inlet temperature was changed from 25 to 70 C and the equivalence ratio from 0.18 to 0.41, while the compression ratio varied from 6 to 13.5. The fuels that were investigated were PRF40 and n-heptane. These three parameters appeared to decrease the ignition delays, with the inlet temperature having the least influence and the compression ratio the most. A previously experimentally validated reduced surrogate mechanism, for mixtures of n-heptane, iso-octane and toluene, has been used to explain observations of the auto-ignition process. The same kinetic mechanism is used to better understand the underlying chemical and physical phenomena that make the influence of a certain parameter change according to the operating conditions. This can be useful for the control of the auto-ignition process in an HCCI engine. (author)

  19. Direct numerical simulations of exhaust gas recirculation effect on multistage autoignition in the negative temperature combustion regime for stratified HCCI flow conditions by using H2O2 addition (United States)

    El-Asrag, Hossam A.; Ju, Yiguang


    Direct numerical simulations (DNSs) of a stratified flow in a homogeneous compression charge ignition (HCCI) engine are performed to investigate the exhaust gas recirculation (EGR) and temperature/mixture stratification effects on the autoignition of synthetic dimethyl ether (DME) in the negative temperature combustion region. Detailed chemistry for a DME/air mixture is employed and solved by a hybrid multi-time scale (HMTS) algorithm to reduce the computational cost. The effect of ? to mimic the EGR effect on autoignition are studied. The results show that adding ? enhances autoignition by rapid OH radical pool formation (34-46% reduction in ignition delay time) and changes the ignition heat release rates at different ignition stages. Sensitivity analysis is performed and the important reactions pathways affecting the autoignition are specified. The DNS results show that the scales introduced by thermal and mixture stratifications have a strong effect after the low temperature chemistry (LTC) ignition especially at the locations of high scalar dissipation rates. Compared to homogenous ignition, stratified ignitions show similar first autoignition delay times, but 18% reduction in the second and third ignition delay times. The results also show that molecular transport plays an important role in stratified low temperature ignition, and that the scalar mixing time scale is strongly affected by local ignition in the stratified flow. Two ignition-kernel propagation modes are observed: a wave-like, low-speed, deflagrative mode and a spontaneous, high-speed, ignition mode. Three criteria are introduced to distinguish these modes by different characteristic time scales and Damkhöler numbers using a progress variable conditioned by an ignition kernel indicator. The low scalar dissipation rate flame front is characterized by high displacement speeds and high mixing Damkhöler number. The proposed criteria are applied successfully at the different ignition stages and

  20. Study on Auto-ignition Temperature of Ferrous Sulfide%硫化亚铁自燃温度影响研究

    Institute of Scientific and Technical Information of China (English)

    徐伟; 张淑娟; 王振刚


    Self-ignition of ferrous sulfide is one of the most important hazards for fire and explosion in the petrochemical industry .In order to avoid such accidents ,the auto-ignition temperature of sulfide ferrous in different particle sizes and the mixture of sulfur and ferrous sulfide are measured by spontaneous combustion temperature tester .The results show that the ignition temperature firstly decreases and then increases with the increase of specific surface area of ferrous sulfide and after-wards with the continuing increase of particle size ,the auto-ignition temperature remains stable .The mixture of sulfur and ferrous sulfide affects cooperatively each other and the auto-ignition temperature of the mixture is lower 116 .3 ℃ than that of ferrous sulfide .This effect greatly increases the runaway risk of the spontaneous combustion of ferrous sulfide ,and brings a great deal of inconvenience to take security measures .%硫化亚铁自燃是引起石油化工行业火灾爆炸事故的重要原因之一.为了规避此类事故的发生 ,利用自燃温度测试仪测定了不同粒径硫化亚铁以及硫磺与硫化亚铁混合物的自燃温度.结果表明 :随着硫化亚铁粒径比表面积的增大 ,其自燃温度先减小后增大 ,之后随着粒径的继续增大 ,自燃温度基本保持平稳状态 ;硫磺与硫化亚铁混合物自燃温度彼此具有协同作用 ,其自燃温度比硫化亚铁自燃温度降低了116 .3 ℃ ,使硫化亚铁自燃失控危险性大大增加 ,为采取安防措施带来了极大的不便.

  1. Enhanced photocatalytic activity of (La, N) co-doped TiO2 by TiCl4 sol-gel autoigniting synthesis

    Institute of Scientific and Technical Information of China (English)


    (La, N) co-doped TiO2 photocatalysts were synthesized using TiCl4 sol-gel autoigniting synthesis (SAS) starting from a plished in the formation of TiO2 nanocrystals. The prepared samples were characterized by using X-ray diffraction (XRD), X-ray photoemission spectroscopy (XPS) and UV-vis diffuse reflectance spectra. The results indicated that nitrogen and lanthanum were incorporated into the lattice and interstices of titania nanocrystals, which resulted in narrowing the band gap and promoting the separation of photoexcited hole-electron pairs, respectively, and showing expected red-shifts and enhanced photocatalytic activity under visible light. The mechanism on nitrogen doping and enhancement in photocatalytic activity of (La, N) co-doped titania by SAS was discussed in detail.

  2. Preparation and characterization of (metal, nitrogen)-codoped TiO2 by TiCl4 sol-gel auto-igniting synthesis

    Institute of Scientific and Technical Information of China (English)

    LIU Zhongqing; ZHOU Yanping; LI Zhenhua; WANG Yichao; GE Changchun


    The nitrogen-doped and (metal, nitrogen)-codoped TiO2 photocatalysts (metal = Ag, Ce, Fe, La) were synthesized by sol-gel auto-igniting synthesis (SAS) with the complex compound sol of TiCl4-NH4NO3-citri acid-metal nitrateNH3.H2O as a precursor. The products were characterized by means of XRD, XPS, and UV-Vis diffuse reflectance spectra,and their photocatalytic activity was investigated under visible light. It was found that all the synthesized powders showed good absorption for visible light, and that the radius and alterable valence states of doping metallic cations played important roles on their photocatalytic activity. These results were discussed in detail.

  3. Influence of cerium ions on the anatase-rutile phase transition of TiO2 prepared by sol-gel auto-igniting synthesis

    Institute of Scientific and Technical Information of China (English)

    YAN Qingzhi; SU Xintai; ZHOU Yanping; GE Changchun


    The anatase-rutile phase transformation of TiO2 doped cerium up to 5 mol% was studied by X-ray diffraction and X-ray photoelectron spectroscopy. The samples were prepared by sol-gel auto-igniting synthesis process from a TiO(NO3)2-Ce(NO3)2-NH4NO3-citric acid complex compound system. The combusted amorphous powders were calcined at different temperatures. Significant structural changes were observed during the various stages of the phase transformation.It was concluded that at low dopant contents, cerium ions were incorporated into the TiO2 structure, and the anatase phase was stabilized; but at larger amounts, part of the dopant was segregated on the surface of TiO2 and the rutile formation was accelerated at elevated calcination temperature.

  4. Numerical Analysis of Autoignition and Combustion of n-Butane and Air Mixture in Homogeneous-Charge Compression-Ignition Engine Using Elementary Reactions (United States)

    Yamasaki, Yudai; Iida, Norimasa

    The present study focuses on clarifying the combustion mechanism of the homogeneous-charge compression-ignition (HCCI) engine in order to control ignition and combustion as well as to reduce HC and CO emissions and to maintain high combustion efficiency by calculating the chemical kinetics of elementary reactions. For the calculations, n-butane was selected as fuel since it is a fuel with the smallest carbon number in the alkane family that shows two-stage autoignition (heat release with low-temperature reaction (LTR) and with high-temperature reaction (HTR)) similarly to higher hydrocarbons such as gasoline. The CHEMKIN code was used for the calculations assuming zero dimensions in the combustion chamber and adiabatic change. The results reveal the heat release mechanism of the LTR and HTR, the control factor of ignition timing and combustion speed, and the condition need to reduce HC and CO emissions and to maintain high combustion efficiency.

  5. A computational study of syngas auto-ignition characteristics at high-pressure and low-temperature conditions with thermal inhomogeneities

    KAUST Repository

    Pal, Pinaki


    A computational study was conducted to investigate the characteristics of auto-ignition in a syngas mixture at high-pressure and low-temperature conditions in the presence of thermal inhomogeneities. Highly resolved one-dimensional numerical simulations incorporating detailed chemistry and transport were performed. The temperature inhomogeneities were represented by a global sinusoidal temperature profile and a local Gaussian temperature spike (hot spot). Reaction front speed and front Damköhler number analyses were employed to characterise the propagating ignition front. In the presence of a global temperature gradient, the ignition behaviour shifted from spontaneous propagation (strong) to deflagrative (weak), as the initial mean temperature of the reactant mixture was lowered. A predictive Zel\\'dovich–Sankaran criterion to determine the transition from strong to weak ignition was validated for different parametric sets. At sufficiently low temperatures, the strong ignition regime was recovered due to faster passive scalar dissipation of the imposed thermal fluctuations relative to the reaction timescale, which was quantified by the mixing Damköhler number. In the presence of local hot spots, only deflagrative fronts were observed. However, the fraction of the reactant mixture consumed by the propagating front was found to increase as the initial mean temperature was lowered, thereby leading to more enhanced compression-heating of the end-gas. Passive scalar mixing was not found to be important for the hot spot cases considered. The parametric study confirmed that the relative magnitude of the Sankaran number translates accurately to the quantitative strength of the deflagration front in the overall ignition advancement. © 2015 Taylor & Francis

  6. Auto-ignition modelling: analysis of the dilution effects by the unburnt gases and of the interactions with turbulence for diesel homogeneous charge compression ignition (HCCI) engines; Modelisation de l'auto-inflammation: analyse des effets de la dilution par les gaz brules et des interactions avec la turbulence dediee aux moteurs Diesel a charge homogene

    Energy Technology Data Exchange (ETDEWEB)

    Subramanian, G.


    Homogeneous Charge Compression Ignition (HCCI) is an alternative engine combustion process that offers the potential for substantial reductions in both NO{sub x} and particulate matter still providing high Diesel-like efficiencies. Combustion in HCCI mode takes place essentially by auto-ignition. It is mainly controlled by the chemical kinetics. It is therefore necessary to introduce detailed chemistry effects in combustion CFD codes in order to properly model the HCCI combustion process. The objective of this work is to develop an auto-ignition model including detailed chemical kinetics and its interactions with turbulence. Also, a comprehensive study has been performed to analyze the chemical influence of CO and H{sub 2} residual species on auto-ignition, which can be present in the exhaust gases. A new auto-ignition model, TKI-PDF (Tabulated Kinetics for Ignition - with turbulent mixing interactions through a pdf approach) dedicated to RANS 3D engine combustion CFD calculations is proposed. The TKI-PDF model is formulated in order to accommodate the detailed chemical kinetics of auto-ignition coupled with turbulence/chemistry interactions. The complete model development and its validation against experimental results are presented in two parts. The first part of this work describes the detailed chemistry input to the model. The second part is dedicated to the turbulent mixing description. A method based on a progress variable reaction rate tabulation is used. A look-up table for the progress variable reaction rates has been built through constant volume complex chemistry simulations. Instantaneous local reaction rates inside the CFD computational cell are then calculated by linear interpolation inside the look-up table depending on the local thermodynamic conditions. In order to introduce the turbulent mixing effects on auto-ignition, a presumed pdf approach is used. The model has been validated in different levels. First, the detailed kinetic approach was

  7. Low temperature oxidation, co-oxidation and auto-ignition of olefinic and aromatic blending compounds: Experimental study of interactions during the oxidation of a surrogate fuel; Oxydation, co-oxydation et auto-inflammation a basses temperatures d'alcenes et aromatiques types: etude experimentale des interactions au sein d'un carburant-modele

    Energy Technology Data Exchange (ETDEWEB)

    Vanhove, G.


    The low-temperature (600-900 K) and high-pressure (5-25 bar) oxidation and auto-ignition of the three position isomers of hexene, of binary mixtures of 1-hexene, toluene and iso-octane, and of a surrogate fuel composed of these three compounds were studied in motor conditions using a rapid compression machine. Auto-ignition delay times were measured as long as intermediate products concentrations during the delay. The results show that the oxidation chemistry of the hexenes is very dependent on the position of the double bond inside the molecule, and that strong interactions between the oxidation mechanisms of hydrocarbons in mixtures can occur. The data obtained concerning the surrogate fuel give a good insight into the behaviour of a practical gasoline after an homogeneous charge compression. (author)

  8. Fuel governor for controlled autoignition engines

    Energy Technology Data Exchange (ETDEWEB)

    Jade, Shyam; Hellstrom, Erik; Stefanopoulou, Anna; Jiang, Li


    Methods and systems for controlling combustion performance of an engine are provided. A desired fuel quantity for a first combustion cycle is determined. One or more engine actuator settings are identified that would be required during a subsequent combustion cycle to cause the engine to approach a target combustion phasing. If the identified actuator settings are within a defined acceptable operating range, the desired fuel quantity is injected during the first combustion cycle. If not, an attenuated fuel quantity is determined and the attenuated fuel quantity is injected during the first combustion cycle.

  9. Autoignition Chemistry of Surrogate Fuel Components in an Engine Environment (United States)


    Environment David L. Miller and Nicholas P. Cernansky Mechanical Engineering and Mechanics Drexel University, Philadelphia, Pennsylvania, 19104... Engineering and Mechanics Department at Drexel University, and utilized an existing single cylinder research engine facility. The facility...a single-cylinder, variable compression ratio research engine . The program objectives were to determine the branching pathways of JP-8 components at

  10. The Interdependence of Various Types of Autoignition and Knock (United States)


    HUGH L. DRYHKN, PH. D., Director of Aeronautical Research JOHN F. VICTORY, LL.M., Executiie Secretary JOHN W. CHOWI.EY, JH ., H. S., Associate...J F A^M £J F • J F * t _JM F *^B * J r * r JHV * ~ JJl F

  11. Effect of Materials on the Autoignition of Cyclopentane

    Energy Technology Data Exchange (ETDEWEB)

    Donna Post Guillen; Mark Walls


    Cyclopentane, a flammable hydrocarbon, is being considered as a working fluid for waste heat recovery applications. Experiments were conducted to determine the ignition delay time (IDT) of cyclopentane using an Ignition Quality Test (IQT) device. Two sets of experiments were conducted per ASTM D6890 (with exception to charge pressure and temperature) to determine ignition delay of the fuel at atmospheric pressure for normal air ({approx}21% oxygen) and vitiated air (13.3% oxygen) at a temperature of 530 C. Operation of the IQT device at a much lower pressure (1 bar) than normal operation (21.1 bar) led to very rich conditions and wetting of the stainless steel chamber walls. Catalytic effects produced small IDTs. Experiments were repeated with a modified injector to prevent wall wetting, resulting in average IDTs that are substantially longer.

  12. Predictive modeling and reducing cyclic variability in autoignition engines

    Energy Technology Data Exchange (ETDEWEB)

    Hellstrom, Erik; Stefanopoulou, Anna; Jiang, Li; Larimore, Jacob


    Methods and systems are provided for controlling a vehicle engine to reduce cycle-to-cycle combustion variation. A predictive model is applied to predict cycle-to-cycle combustion behavior of an engine based on observed engine performance variables. Conditions are identified, based on the predicted cycle-to-cycle combustion behavior, that indicate high cycle-to-cycle combustion variation. Corrective measures are then applied to prevent the predicted high cycle-to-cycle combustion variation.

  13. Preignition and Autoignition Behavior of the Xylene Isomers (United States)


    1771. Gong, X., 2005, The effects of DTBP on the oxidation of SI primary reference fuels – a study in an HCCI engine and in a pressurized flow... HCCI engines , Proceedings of the Combustion Institute 31:2895-2902. U. S. Army Tank-Automotive and Armaments Command (TACOM), 2001, JP-8: The...Additional experiments were conducted in a single cylinder research engine . Neat 0- and m-xylene were oxidized in the reactor under preignition conditions

  14. Investigation of JP-8 Autoignition Under Vitiated Combustion Conditions (United States)


    combustion engines and HCCI systems rather than low pressure combustion devices that are of interest in the current study. This data provides insight...2011 Directed by: Professor Gregory Jackson, Chair Department of Mechanical Engineering Limited data on jet fuel ignition and oxidation at...Fuller 2011 ii Acknowledgements This research has been supported and funded by Combustion Science and Engineering , Inc. through the following

  15. Preignition and Autoignition Behavior of the Xylene Isomers (United States)


    24 Figure 3-4: Engine piston position at (a) IVC (10° bTDC), (b) IVC (34° aBDC), (c) EVO 40° bBDC), and (d) EVC (15° aTDC...displacement is 611.6 cm3. The intake valve opening (IVO), intake valve closing (IVC), exhaust valve opening (EVO), and exhaust valve closing ( EVC ...the exhaust stroke as combustion products exit the cylinder. Figure 3-4(d) shows the 23 engine at EVC . As seen in Fig. 3-4 and as with most engines

  16. Low and High Temperature Combustion Chemistry of Butanol Isomers in Premixed Flames and Autoignition Systems

    Energy Technology Data Exchange (ETDEWEB)

    Sarathy, S M; Pitz, W J; Westbrook, C K; Mehl, M; Yasunaga, K; Curran, H J; Tsujimura, T; Osswald, P; Kohse-Hoinghaus, K


    Butanol is a fuel that has been proposed as a bio-derived alternative to conventional petroleum derived fuels. The structural isomer in traditional 'bio-butanol' fuel is n-butanol, but newer conversion technologies produce iso-butanol as a fuel. In order to better understand the combustion chemistry of bio-butanol, this study presents a comprehensive chemical kinetic model for all the four isomers of butanol (e.g., 1-, 2-, iso- and tert-butanol). The proposed model includes detailed high temperature and low temperature reaction pathways. In this study, the primary experimental validation target for the model is premixed flat low-pressure flame species profiles obtained using molecular beam mass spectrometry (MBMS). The model is also validated against previously published data for premixed flame velocity and n-butanol rapid compression machine and shock tube ignition delay. The agreement with these data sets is reasonably good. The dominant reaction pathways at the various pressures and temperatures studied are elucidated. At low temperature conditions, we found that the reaction of alphahydroxybutyl with O{sub 2} was important in controlling the reactivity of the system, and for correctly predicting C{sub 4} aldehyde profiles in low pressure premixed flames. Enol-keto isomerization reactions assisted by HO{sub 2} were also found to be important in converting enols to aldehydes and ketones in the low pressure premixed flames. In the paper, we describe how the structural features of the four different butanol isomers lead to differences in the combustion properties of each isomer.

  17. Autoignition and flame stabilisation processes in turbulent non-premixed hot coflow flames

    NARCIS (Netherlands)

    Oldenhof , E.


    This dissertation examines stabilisation processes in turbulent non-premixed jet flames, created by injecting gaseous fuel into a co-flowing stream of hot, low-oxygen combustion products. Being able to predict whether and how a flame achieves stable and reliable combustion is a matter of great pract

  18. Experimental and Theoretical Studies of Autoignition and Burning Speed of JP8 and DF-2 (United States)


    Isooctane and Indolence at High Pressure and Temperature." Combustion and Flame 48: 191-210, 1982. [3] Elia, M., Moore,P., Ulinski, M., and Metghalchi...34Burning Velocities of Mixtures of Air with Methanol, Isooctane and Indolence at High Pressure and Temperature." Combustion and Flame 48: 191-210

  19. Dilution effects on the controlled auto-ignition (CAI) combustion of hydrocarbon and alcohol fuels


    Oakley, A.; Zhao, H.; Ma, T.; Ladommatos, N


    Copyright © 2001 SAE International. This paper is posted on this site with permission from SAE International. Further use of this paper is not permitted without permission from SAE This paper presents results from an experimental programme researching the in-cylinder conditions necessary to obtain homogenous CAI (or HCCI) combustion in a 4-stroke engine. The fuels under investigation include three blends of Unleaded Gasoline, a 95 RON Primary Reference Fuel, Methanol, and Ethanol. This wor...

  20. A Regime Diagram for Autoignition of Homogeneous Reactant Mixtures with Turbulent Velocity and Temperature Fluctuations

    KAUST Repository

    Im, Hong G.


    A theoretical scaling analysis is conducted to propose a diagram to predict weak and strong ignition regimes for a compositionally homogeneous reactant mixture with turbulent velocity and temperature fluctuations. The diagram provides guidance on expected ignition behavior based on the thermo-chemical properties of the mixture and the flow/scalar field conditions. The analysis is an extension of the original Zeldovich’s analysis by combining the turbulent flow and scalar characteristics in terms of the characteristic Damköhler and Reynolds numbers of the system, thereby providing unified and comprehensive understanding of the physical and chemical mechanisms controlling ignition characteristics. Estimated parameters for existing experimental measurements in a rapid compression facility show that the regime diagram predicts the observed ignition characteristics with good fidelity.

  1. Impact of fuel molecular structure on auto-ignition behavior – Design rules for future high performance gasolines

    KAUST Repository

    Boot, Michael D.


    At a first glance, ethanol, toluene and methyl tert-butyl ether look nothing alike with respect to their molecular structures. Nevertheless, all share a similarly high octane number. A comprehensive review of the inner workings of such octane boosters has been long overdue, particularly at a time when feedstocks for transport fuels other than crude oil, such as natural gas and biomass, are enjoying a rapidly growing market share. As high octane fuels sell at a considerable premium over gasoline, diesel and jet fuel, new entrants into the refining business should take note and gear their processes towards knock resistant compounds if they are to maximize their respective bottom lines. Starting from crude oil, the route towards this goal is well established. Starting from biomass or natural gas, however, it is less clear what dots on the horizon to aim for. The goal of this paper is to offer insight into the chemistry behind octane boosters and to subsequently distill from this knowledge, taking into account recent advances in engine technology, multiple generic design rules that guarantee good anti-knock performance. Careful analysis of the literature suggests that highly unsaturated (cyclic) compounds are the preferred octane boosters for modern spark-ignition engines. Additional side chains of any variety will dilute this strong performance. Multi-branched paraffins come in distant second place, owing to their negligible sensitivity. Depending on the type and location of functional oxygen groups, oxygenates can have a beneficial, neutral or detrimental impact on anti-knock quality.

  2. Microwave-Plasma-Coupled Re-Ignition of Methane-and-Oxygen Mixture Under Auto-Ignition Temperature (United States)


    setup and the components for the microwave power supply , and the measurement system are shown. It consists of a power supply , two directional couplers...dramatically increase through Stage II. Calculations show that, in our configuration, 18% of the total methane undergoes reforming to syngas at 30 W of

  3. Reduced chemical reaction mechanisms: experimental and HCCI modelling investigations of autoignition processes of iso-octane in internal combustion engines


    Machrafi, Hatim; Lombaert, K.; Cavadias, S; Guibert, P.; Amouroux, J


    A semi-reduced (70 species, 210 reactions) and a skeletal (27 species, 29 reactions) chemical reaction mechanism for iso-octane are constructed from a semi-detailed iso-octane mechanism (84 species, 412 reactions) of the Chalmers University of Technology in Sweden. The construction of the reduced mechanisms is performed by using reduction methods such as the quasi-steady-state assumption and the partial equilibrium assumption. The obtained reduced iso-octane mechanisms show, at the mentioned ...

  4. One pot auto-ignition based synthesis of novel Sr{sub 2}CeO{sub 4}: Ho{sup 3+} nanophosphor for photoluminescent applications

    Energy Technology Data Exchange (ETDEWEB)

    Monika, D.L., E-mail: [Prof. C.N.R. Rao Centre for Nano Research, Tumkur University, Tumkur 572103 (India); Nagabhushana, H., E-mail: [Prof. C.N.R. Rao Centre for Nano Research, Tumkur University, Tumkur 572103 (India); Nagabhushana, B.M. [Department of Chemistry, M. S. Ramaiah Institute of Technology, Bangalore 560054 (India); Sharma, S.C. [Dayananda Sagar University, Shavige Malleshwara Hills, Kumaraswamy Layout, Bangalore 560078 (India); Anantharaju, K.S. [Department of Science, Research Center, East West Institute of Technology, Bangalore 560 091 (India); Daruka Prasad, B. [Department of Physics, BMS Institute of Technology, VTU-Belagavi, Bangalore 560 064 (India); Shivakumara, C. [Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560 012 (India)


    Ho{sup 3+} (0.25–7 mol%) doped Sr{sub 2}CeO{sub 4} nanophosphors were synthesized by solution combustion method using urea as fuel. The structural properties of the nanophosphors were investigated by powder X-ray diffraction studies (PXRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) techniques. UV–Visible and photoluminescence (PL) spectroscopic techniques were used for analysing the optical properties of the nanoparticles. PXRD and TEM results revealed the formation of Sr{sub 2}CeO{sub 4}: Ho{sup 3+} nanocrystalline particles with orthorhombic crystal structure. From the UV–Vis studies the optical band gap energy found to decrease from 5.9 to 5.74 eV with increase in dopant concentration. The PL spectra exhibit the broad excitation band from 200 to 400 nm which concurs well with the commercial near UV LED. The PL spectra vary with the dopant content due to energy transfer from the host to the activator. In this present work we demonstrate that color tuning of phosphor can be achieved by merely varying the Ho{sup 3+} ions concentration. The CIE and CCT chromaticity coordinates suggests Sr{sub 2}CeO{sub 4}: Ho{sup 3+} nanophosphors may be potentially applicable as promising single – phased phosphors for lighting applications. - Highlights: • For the first time we report the luminescence studies on Ho{sup 3+}: Sr{sub 2}CeO{sub 4} phosphor. • Pure orthorhombic phosphor is obtained by one pot solution combustion method. • Color tuning of the phosphor is achieved by merely varying Ho{sup 3+} concentration. • Energy transfer involved in color tuning is discussed in detail.

  5. Development and Parametric Evaluation of a Tabulated Chemistry Tool for the Simulation of n-Heptane Low-Temperature Oxidation and Autoignition Phenomena


    George Vourliotakis; Dionysios I. Kolaitis; Founti, Maria A.


    Accurate modelling of preignition chemical phenomena requires a detailed description of the respective low-temperature oxidative reactions. Motivated by the need to simulate a diesel oil spray evaporation device operating in the “stabilized” cool flame regime, a “tabulated chemistry” tool is formulated and evaluated. The tool is constructed by performing a large number of kinetic simulations, using the perfectly stirred reactor assumption. n-Heptane is used as a surrogate fuel for diesel oil ...

  6. A parametric study on the emissions from an HCCI alternative combustion engine resulting from the auto-ignition of primary reference fuels

    Energy Technology Data Exchange (ETDEWEB)

    Machrafi, Hatim; Cavadias, Simeon; Amouroux, Jacques [UPMC Universite Paris 06, LGPPTS, Ecole Nationale Superieure de Chimie de Paris, 11, rue de Pierre et Marie Curie, 75005 Paris (France)


    The homogeneous charge compression ignition is an alternative combustion technology that can reduce automobile pollution, provided that the exhaust emission can be controlled. A parametric study can be useful in order to gain more understanding in the emission reduction possibilities via this new combustion technology. For this purpose, the inlet temperature, the equivalence ratio and the compression ratio are changed, respectively, from 30 to 70{sup o}C, 0.28 to 0.41 and 6 to 14. Also the diluting, thermal and chemical effects of exhaust gas recirculation were studied. The emission of CO, CO{sub 2}, O{sub 2} and hydrocarbons has been measured using primary reference fuels. It appears that an increase in the inlet temperature, the EGR temperature, the equivalence ratio and the compression ratio results into a decrease of the emissions of CO and the hydrocarbons of up to 75%. The emission of CO{sub 2} increased, however, by 50%. The chemical parameters showed more complicated effects, resulting into a decrease or increase of the emissions, depending on whether the overall reactivity increased or not. If the reactivity increased, generally, the emissions of CO and hydrocarbons increased, while that of CO{sub 2} increased. The increase of CO{sub 2} emissions could be compensated by altering the compression ratio and the EGR parameters, making it possible to control the emission of the HCCI engine. (author)

  7. The Preignition and Autoignition Oxidation of Alternatives to Petroleum Derived JP-8 and their Surrogate Components in a Pressurized Flow Reactor and Single Cylinder Research Engine (United States)


    designs such as HCCI engines , where ignition relies on the chemistry of the fuel. An initial mixture of 59.4% n-decane/40.6% iso-octane was...Octane Oxidation for HCCI Engines . Fuel, Vol. 85, 2593-2604. Koert, D. N., N. P. Cernansky. (1992). A Flow Reactor for the Study of...Reactor and Single Cylinder Research Engine A Thesis Submitted to the Faculty of Drexel University by Matthew S. Kurman in partial

  8. 丙醇/正庚烷混合燃料的着火特性%Autoignition of Propanol Isomers/n-Heptane Blend Fuels

    Institute of Scientific and Technical Information of China (English)

    杨峥; 王玥; 吕兴才; 黄震


    在一台快速压缩机上研究了不同比例的丙醇/正庚烷二元混合燃料在当量比为1.0、压缩上止点压力2,MPa、压缩温度为650~850,K时的着火延迟.利用混合燃料的详细动力学机理开展了丙醇/正庚烷着火特性的化学反应动力学分析.研究结果表明,在本文实验条件下和温度范围内,丙醇/正庚烷的着火延迟在不同的温度范围呈现不同的变化规律.在丙醇比例较低时,正丙醇/正庚烷混合燃料的着火延迟高于异丙醇/正庚烷混合燃料;丙醇比例较高时,二者的着火延迟非常接近.化学动力学分析表明,由于正庚烷低温反应根池的建立,丙醇在着火过程中也呈现出两阶段燃烧现象.路径分析表明,上止点温度的提高可使部分羟丙烷基发生裂解并增强系统活性.进一步的敏感性分析表明,对正丙醇/正庚烷混合燃料,正庚烷的脱氢反应和链分支反应对促进着火始终有重要影响,随着正丙醇比例的增加,正丙醇对混合燃料着火的抑制与促进都有较大的影响.异丙醇/正庚烷混合燃料的着火在异丙醇比例较大或上止点温度较高时对异丙醇的氧化更加敏感,抑制着火的反应始终为小分子基团的反应.%Ignition delay time of propanol isomers/n-heptane mixtures was measured using a rapid compression ma-chine at compressed pressure of 2,MPa,within the compressed temperature range of 650—850,K and with equiva-lence ratio of 1.0. Reaction kinetics analysis was performed using a detailed mechanism of blend fuels. Under the ex-perimental conditions in this study,the ignition delay of the blend fuels displays different varying patterns in different temperature ranges. The ignition delay time of i-propanol/n-heptane is shorter than that of n-propanol/n-heptane when the propanol fraction is low. When the propanol fraction is high,their ignition delay times become very close to each other. The chemical kinetics analysis indicates that propanol isomers also exhibit two-stageoxidation behavior because of the low temperature reactivity radical pool produced by n-heptane. The higher compressed temperature can make a small part of the hydroxypropyl radicals undergo scission reaction and improve system activity. Sensitivity analysis shows that for the n-propanol/n-heptane blends,H-abstraction and chain-branching reaction from the n-heptane al-ways play a dominant role in the reaction with a promoting effect,while the H-abstraction from the n-propanol be-comes important when the n-propanol fraction is high. For i-propanol/n-heptane mixtures,the ignition of the blend fuels is more sensitive to the oxidation of the i-propanol at high compressed temperature or propanol fractions,while the major inhibiting reactions are always some elementary reactions of small radicals.

  9. Development and Experimental Validation of Large Eddy Simulation Techniques for the Prediction of Combustion-Dynamic Process in Syngas Combustion: Characterization of Autoignition, Flashback, and Flame-Liftoff at Gas-Turbine Relevant Operating Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Ihme, Matthias [Univ. of Michigan, Ann Arbor, MI (United States); Driscoll, James [Univ. of Michigan, Ann Arbor, MI (United States)


    The objective of this closely coordinated experimental and computational research effort is the development of simulation techniques for the prediction of combustion processes, relevant to the oxidation of syngas and high hydrogen content (HHC) fuels at gas-turbine relevant operating conditions. Specifically, the research goals are (i) the characterization of the sensitivity of syngas ignition processes to hydrodynamic processes and perturbations in temperature and mixture composition in rapid compression machines and ow-reactors and (ii) to conduct comprehensive experimental investigations in a swirl-stabilized gas turbine (GT) combustor under realistic high-pressure operating conditions in order (iii) to obtain fundamental understanding about mechanisms controlling unstable flame regimes in HHC-combustion.

  10. Role of Volatility in the Development of JP-8 Surrogates for Diesel Engine Application (United States)


    terms of spray, autoignition, and combustion characteristics in multi-phase heterogeneous combustion conditions. Experiments Optical Accessible Rapid... heterogeneous combustion system, density is a very important factor for autoignition processes because a fuel is injected by volume in diesel engines...a Molybdenum Carbide Catalyst”, Applied Catalysis A: General, 394(1): 62-70, 2011. 54. Henein, N

  11. 排气道废气再循环策略下实现汽油可控自燃的气门定时区域%Test on valve timing region to realize gasoline controlled autoignition combustion under the strategy of exhaust gas recirculation in exhaust port

    Institute of Scientific and Technical Information of China (English)

    程鹏; 李华; 王有坤; 池俊成; 李国; 郭英男; 庄宇华


    在装备有电控液压驱动可变气门机构的单缸机试验系统上,研究了使用排气道废气再循环(EGR)策略实现汽油可控自燃(CAI)时,气门定时对汽油CAI的影响.试验结果表明,在转速1000 r/min、过量空气系数入为1条件下,采用进气门开启定时不变时(IVO=40°CAATDC)排气门关闭定时,(EVC)在126~176°CA ATDC范围内能够实现汽油CAI;采用EVC定时不变(EVC=146°CA ATDC)时,IVO在28~60°CA ATDC范围内也能够实现汽油CAI.EVC对从排气道吸入的废气的影响要大于IVO.在能实现汽油CAI的气门定时区域内,IVO变化范围仅为45°CA,EVC变化范围可达120°CA.

  12. Experimental studies of factors influencing the self-ignition of gaseous and liquid fuel free jets; Experimentelle Untersuchungen von Einflussfaktoren auf die Selbstzuendung von gasfoermigen und fluessigen Brennstofffreistrahlen

    Energy Technology Data Exchange (ETDEWEB)

    Pfeifer, Christian


    In the present work, the investigation of influencing factors on the auto-ignition of gaseous and liquid free fuel jets are presented. The fuel dimethyl ether (DME) is injected into a high pressure/high temperature atmosphere. The temperature of up to 770 K and pressure of 40 bar enable auto-ignition of the transient free fuel jet during the inflow. To study the influences on the auto-ignition of the gaseous free jet, an extended autoignition probability is established. It includes the time and space resolved auto-ignition probability concerning the ignition limit of the fuel/air-mixture. This state of the autoignition probability is expanded by the auto-ignition probability concerning the local mixture temperature. To gain information of the local temperature, the molar mixture is applied as database. Therefrom the adiabatic local temperature is calculated. To determine a limiting temperature, above which auto-ignition of the local mixture is feasible, a numerical study with the software package HOMREA is performed. Additionally the influence of the flow field on the auto-ignition probability is investigated. As experimental database the time resolved velocity field of the instationary fuel jet is applied and the local strain rate is obtained. To define a critical strain rate, above which an auto-ignition is not possible, a numerical simulation with INSFLA is performed. A coupling of these three single ignition probabilities yield an extended auto-ignition probability. It reveals an abrupt rise in the local ignition probability over a large spatial extend. This time and space resolved rise of the calculated ignition probability shows an excellent agreement with high-speed video sequences of the auto-ignition of the free fuel jet and also with studies of the Laser-induced fluorescence (LIF) of formaldehyde. It turns out that the influence of the flow on the auto-ignition under the conditions of the experiment is negligible. To study the characteristics of the

  13. Coupled nonequilibrium flow, energy and radiation transport for hypersonic planetary entry (United States)

    Frederick, Donald Jerome

    An ever increasing demand for energy coupled with a need to mitigate climate change necessitates technology (and lifestyle) changes globally. An aspect of the needed change is a decrease in the amount of anthropogenically generated CO2 emitted to the atmosphere. The decrease needed cannot be expected to be achieved through only one source of change or technology, but rather a portfolio of solutions are needed. One possible technology is Carbon Capture and Storage (CCS), which is likely to play some role due to its combination of mature and promising emerging technologies, such as the burning of hydrogen in gas turbines created by pre-combustion CCS separation processes. Thus research on effective methods of burning turbulent hydrogen jet flames (mimicking gas turbine environments) are needed, both in terms of experimental investigation and model development. The challenge in burning (and modeling the burning of) hydrogen lies in its wide range of flammable conditions, its high diffusivity (often requiring a diluent such as nitrogen to produce a lifted turbulent jet flame), and its behavior under a wide range of pressures. In this work, numerical models are used to simulate the environment of a gas turbine combustion chamber. Concurrent experimental investigations are separately conducted using a vitiated coflow burner (which mimics the gas turbine environment) to guide the numerical work in this dissertation. A variety of models are used to simulate, and occasionally guide, the experiment. On the fundamental side, mixing and chemistry interactions motivated by a H2/N2 jet flame in a vitiated coflow are investigated using a 1-D numerical model for laminar flows and the Linear Eddy Model for turbulent flows. A radial profile of the jet in coflow can be modeled as fuel and oxidizer separated by an initial mixing width. The effects of species diffusion model, pressure, coflow composition, and turbulent mixing on the predicted autoignition delay times and mixture

  14. Modelling studies of the oxidation and auto-ignition of alkanes, aromatics, and their mixtures at high pressure between 600 and 1500 K: reduction of detailed mechanisms: measurements of the building up of soot; Etudes par modelisation de l'oxydation et de l'autoinflammation d'alcanes et d'aromatiques purs et de melanges a haute pression entre 600 et 1500 K: reduction de mecanismes detailles: mesure de la formation des suies

    Energy Technology Data Exchange (ETDEWEB)

    Saylam, A.


    The understanding and control of many combustion phenomena requires an interactive work between experiments and modelling. The presentation of the two coupled approaches is a prerequisite to demonstrate the complexity of the phenomena (Chapters I and II). This complexity often precludes from fully elucidating the details of the chemistry of hydrocarbon oxidations. Such a failure has been shown by an attempt to improve the mechanism of oxidation of iso-octane (Chapter III). Hundreds of species and thousands of reactions come into play during the oxidation of an hydrocarbon and they all must be included into the detailed mechanisms. The need for smaller mechanisms logically has led to devise a technique of reduction (Chapter IV). Predictive thermo-kinetic mechanisms have been built, reduced, and validated with new experimental data and data collected from previous work or published elsewhere (Chapter V). Laser diagnostic techniques have been used to measure soot particles and PAH inside a methane flame (Chapter VI). (author)

  15. Numerical simulation and validation of SI-CAI hybrid combustion in a CAI/HCCI gasoline engine (United States)

    Wang, Xinyan; Xie, Hui; Xie, Liyan; Zhang, Lianfang; Li, Le; Chen, Tao; Zhao, Hua


    SI-CAI hybrid combustion, also known as spark-assisted compression ignition (SACI), is a promising concept to extend the operating range of CAI (Controlled Auto-Ignition) and achieve the smooth transition between spark ignition (SI) and CAI in the gasoline engine. In this study, a SI-CAI hybrid combustion model (HCM) has been constructed on the basis of the 3-Zones Extended Coherent Flame Model (ECFM3Z). An ignition model is included to initiate the ECFM3Z calculation and induce the flame propagation. In order to precisely depict the subsequent auto-ignition process of the unburned fuel and air mixture independently after the initiation of flame propagation, the tabulated chemistry concept is adopted to describe the auto-ignition chemistry. The methodology for extracting tabulated parameters from the chemical kinetics calculations is developed so that both cool flame reactions and main auto-ignition combustion can be well captured under a wider range of thermodynamic conditions. The SI-CAI hybrid combustion model (HCM) is then applied in the three-dimensional computational fluid dynamics (3-D CFD) engine simulation. The simulation results are compared with the experimental data obtained from a single cylinder VVA engine. The detailed analysis of the simulations demonstrates that the SI-CAI hybrid combustion process is characterised with the early flame propagation and subsequent multi-site auto-ignition around the main flame front, which is consistent with the optical results reported by other researchers. Besides, the systematic study of the in-cylinder condition reveals the influence mechanism of the early flame propagation on the subsequent auto-ignition.

  16. Self-ignition phenomena in DI gasoline engines; Selbstzuendungsphaenomene in Ottomotoren mit Direkteinspritzung

    Energy Technology Data Exchange (ETDEWEB)

    Palaveev, Stefan [MOT Forschungs- und Entwicklungsgesellschaft fuer Motorentechnik, Optik und Thermodynamik mbH, Karlsruhe (Germany); Dahnz, Christoph [Karlsruhe Univ. (DE). Inst. fuer Kolbenmaschinen (IFKM)


    With the cost of natural resources rising and environmental awareness increasing, combustion engine manufacturers are focusing their research and development efforts on improving engine efficiency and reduction of exhaust emissions. Engine downsizing is one of the concepts that can reduce the fuel consumption of gasoline engines. Downsizing improves significantly the specific fuel consumption of part-load operating points by shifting them into engine operating map areas with better efficiencies. This is achieved by reducing engine displacement at constant engine speed. In order to obtain the same level of power output, the engines are boosted. However, this high level of power density and thermal loading at full-load operation can cause autoignition of the fuel-air-mixture. In addition to the engine knocking that is typical in spark ignition engines, other sporadic autoignition phenomena take place before the electrical spark breakdown. In the case of premature autoignition heat release starts well before TDC and results in steep rises in both pressure and temperature in the combustion chamber. Such enormous overloads could cause engine failure in a short time. This study aims to provide an overview of the theoretical basics of the autoignition processes at full load engine operation. It also analyzed the impact of some important factors, such as fuel and lubricant properties, mixture formation and injector position. Finally, the study discusses gasoline direct injection as a method to improve thermal efficiency in the context of full-load engine operation. (orig.)

  17. Development and Validation of Chemical Kinetic Mechanism Reduction Scheme for Large-Scale Mechanisms

    DEFF Research Database (Denmark)

    Poon, Hiew Mun; Ng, Hoon Kiat; Gan, Suyin


    This work is an extension to a previously reported work on chemical kinetic mechanism reduction scheme for large-scale mechanisms. Here, Perfectly Stirred Reactor (PSR) was added as a criterion of data source for mechanism reduction instead of using only auto-ignition condition. As a result, a re...

  18. A 50 cc Two-Stroke DI Compression Ignition Engine Fuelled by DME

    DEFF Research Database (Denmark)

    Hansen, Kim Rene; Nielsen, Claus Suldrup; Sorenson, Spencer C


    The low auto-ignition temperature, rapid evaporation and high cetane number of dimethyl ether (DME) enables the use of low-pressure direct injection in compression ignition engines, thus potentially bringing the cost of the injection system down. This in turn holds the promise of bringing CI effi...

  19. Characterizing Gaseous Fuels for Their Knock Resistance based on the Chemical and Physical Properties of the Fuel

    NARCIS (Netherlands)

    Levinsky, Howard; Gersen, Sander; van Essen, Martijn; van Dijk, Gerco


    A method is described to characterize the effects of changes in the composition of gaseous fuels on engine knock by computing the autoignition process during the compression and burn periods of the engine cycle. To account for the effects of fuel composition on the in-cylinder pressure and temperatu

  20. Ignition properties of methane/hydrogen mixtures in a rapid compression machine

    NARCIS (Netherlands)

    Gersen, S.; Anikin, N. B.; Mokhov, A. V.; Levinsky, H. B.


    We investigate changes in the combustion behavior of methane, the primary component of natural gas, upon hydrogen addition by characterizing the autoignition behavior of methane/hydrogen mixtures in a rapid compression machine (RCM). Ignition delay times were measured under stoichiometric conditions

  1. Laser-assisted homogeneous charge ignition in a constant volume combustion chamber (United States)

    Srivastava, Dhananjay Kumar; Weinrotter, Martin; Kofler, Henrich; Agarwal, Avinash Kumar; Wintner, Ernst


    Homogeneous charge compression ignition (HCCI) is a very promising future combustion concept for internal combustion engines. There are several technical difficulties associated with this concept, and precisely controlling the start of auto-ignition is the most prominent of them. In this paper, a novel concept to control the start of auto-ignition is presented. The concept is based on the fact that most HCCI engines are operated with high exhaust gas recirculation (EGR) rates in order to slow-down the fast combustion processes. Recirculated exhaust gas contains combustion products including moisture, which has a relative peak of the absorption coefficient around 3 μm. These water molecules absorb the incident erbium laser radiations ( λ=2.79 μm) and get heated up to expedite ignition. In the present experimental work, auto-ignition conditions are locally attained in an experimental constant volume combustion chamber under simulated EGR conditions. Taking advantage of this feature, the time when the mixture is thought to "auto-ignite" could be adjusted/controlled by the laser pulse width optimisation, followed by its resonant absorption by water molecules present in recirculated exhaust gas.

  2. Volatilization Mechanism of 1-Ethyl-3-methylimidazolium Bromide Ionic Liquid (Briefing Charts) (United States)


    Distribution A: Approved for public release; distribution unlimited JPC -A 2008, 112, 7816 Hypergolic Ignition Autoignition at ambient P & T MMH...Tf2N]: 8.59 ± 0.03 eV PIE curves and structures C+A- + h C+A + e- C+ + A + e- JPC -A 2010, 114, 879 • Dissociative photoionization

  3. Physicochemical effects of varying fuel composition on knock characteristics of natural gas mixtures

    NARCIS (Netherlands)

    Gersen, Sander; van Essen, Martijn; van Dijk, Gerco; Levinsky, Howard


    The physicochemical origins of how changes in fuel composition affect autoignition of the end gas, leading to engine knock, are analyzed for a natural gas engine. Experiments in a lean-burn, high-speed medium-BMEP gas engine are performed using a reference natural gas with systematically varied frac

  4. Computational characterization of ignition regimes in a syngas/air mixture with temperature fluctuations

    KAUST Repository

    Pal, Pinaki


    Auto-ignition characteristics of compositionally homogeneous reactant mixtures in the presence of thermal non-uniformities and turbulent velocity fluctuations were computationally investigated. The main objectives were to quantify the observed ignition characteristics and numerically validate the theory of the turbulent ignition regime diagram recently proposed by Im et al. 2015 [29] that provides a framework to predict ignition behavior . a priori based on the thermo-chemical properties of the reactant mixture and initial flow and scalar field conditions. Ignition regimes were classified into three categories: . weak (where deflagration is the dominant mode of fuel consumption), . reaction-dominant strong, and . mixing-dominant strong (where volumetric ignition is the dominant mode of fuel consumption). Two-dimensional (2D) direct numerical simulations (DNS) of auto-ignition in a lean syngas/air mixture with uniform mixture composition at high-pressure, low-temperature conditions were performed in a fixed volume. The initial conditions considered two-dimensional isotropic velocity spectrums, temperature fluctuations and localized thermal hot spots. A number of parametric test cases, by varying the characteristic turbulent Damköhler and Reynolds numbers, were investigated. The evolution of the auto-ignition phenomena, pressure rise, and heat release rate were analyzed. In addition, combustion mode analysis based on front propagation speed and computational singular perturbation (CSP) was applied to characterize the auto-ignition phenomena. All results supported that the observed ignition behaviors were consistent with the expected ignition regimes predicted by the theory of the regime diagram. This work provides new high-fidelity data on syngas ignition characteristics over a broad range of conditions and demonstrates that the regime diagram serves as a predictive guidance in the understanding of various physical and chemical mechanisms controlling auto-ignition

  5. Effects of different injection parameters on the performance of gasoline engines with controlled self-ignition; Auswirkungen unterschiedlicher Einspritzparameter auf das Betriebsverhalten mit kontrollierter Selbstzuendung von Ottokraftstoff

    Energy Technology Data Exchange (ETDEWEB)

    Sarikoc, Fatih [MOT Forschungs- und Entwicklungsgesellschaft fuer Motorentechnik, Optik und Thermodynamik mbH, Karlsruhe (Germany); Guenthner, Michael; Rottengruber, Hermann; Spicher, Ulrich [BMW Group, Muenchen (Germany)


    The flexibility in injection parameters associated with direct injection provides additional variables to influence the combustion behavior of the controlled autoignition process. In addition to the injection timing, the injection pressure and the type of injector (multihole injector vs. outward-opening injector) can be included with these injection parameters. In this work, the influence of these injection parameters on engine operating behavior with controlled autoignition are presented and discussed. These investigations were performed on a single-cylinder research engine with a centrally located injector. In addition to thermodynamic analyses, 3D-CFD calculations of the mixture formation process and the fuel distribution were performed. Injecting during the negative valve overlap period enhances the combustion stability, especially at lower loads and lower engine speeds. Optical investigations compare the spray evaporation behavior of two different injector types during the negative valve overlap period with various injection configurations. (orig.)

  6. Advanced fuel chemistry for advanced engines.

    Energy Technology Data Exchange (ETDEWEB)

    Taatjes, Craig A.; Jusinski, Leonard E.; Zador, Judit; Fernandes, Ravi X.; Miller, James A.


    Autoignition chemistry is central to predictive modeling of many advanced engine designs that combine high efficiency and low inherent pollutant emissions. This chemistry, and especially its pressure dependence, is poorly known for fuels derived from heavy petroleum and for biofuels, both of which are becoming increasingly prominent in the nation's fuel stream. We have investigated the pressure dependence of key ignition reactions for a series of molecules representative of non-traditional and alternative fuels. These investigations combined experimental characterization of hydroxyl radical production in well-controlled photolytically initiated oxidation and a hybrid modeling strategy that linked detailed quantum chemistry and computational kinetics of critical reactions with rate-equation models of the global chemical system. Comprehensive mechanisms for autoignition generally ignore the pressure dependence of branching fractions in the important alkyl + O{sub 2} reaction systems; however we have demonstrated that pressure-dependent 'formally direct' pathways persist at in-cylinder pressures.


    Institute of Scientific and Technical Information of China (English)

    Shi Hong-hui; Tetsu Sakakura


    The fluid mechanics in the generation of hypervelocity water jets, light oil jets and glycerin jets was studied. Framing high-speed photography and single-shot photography were used to observe the jets directly. The purposes of this study is to investigate the disintegration and atomization processes at the velocity of 2km/s-3km/s as well as the auto-ignition and self-combustion of the light oil jets. Therefore, in the jet velocity measurement in addition to the high-speed photography, the results by other methods such as the laser beams cutting method and the shock wave detection using pressure transducers were also given. In the observation of the jets events, the illumination phenomenon was found, which may be regarded as the result of the auto-ignition and combustion of the light oil jets. Finally, the Munroe jet was studied.

  8. Fundamental Interactions in Gasoline Compression Ignition Engines with Fuel Stratification (United States)

    Wolk, Benjamin Matthew

    Transportation accounted for 28% of the total U.S. energy demand in 2011, with 93% of U.S. transportation energy coming from petroleum. The large impact of the transportation sector on global climate change necessitates more-efficient, cleaner-burning internal combustion engine operating strategies. One such strategy that has received substantial research attention in the last decade is Homogeneous Charge Compression Ignition (HCCI). Although the efficiency and emissions benefits of HCCI are well established, practical limits on the operating range of HCCI engines have inhibited their application in consumer vehicles. One such limit is at high load, where the pressure rise rate in the combustion chamber becomes excessively large. Fuel stratification is a potential strategy for reducing the maximum pressure rise rate in HCCI engines. The aim is to introduce reactivity gradients through fuel stratification to promote sequential auto-ignition rather than a bulk-ignition, as in the homogeneous case. A gasoline-fueled compression ignition engine with fuel stratification is termed a Gasoline Compression Ignition (GCI) engine. Although a reasonable amount of experimental research has been performed for fuel stratification in GCI engines, a clear understanding of how the fundamental in-cylinder processes of fuel spray evaporation, mixing, and heat release contribute to the observed phenomena is lacking. Of particular interest is gasoline's pressure sensitive low-temperature chemistry and how it impacts the sequential auto-ignition of the stratified charge. In order to computationally study GCI with fuel stratification using three-dimensional computational fluid dynamics (CFD) and chemical kinetics, two reduced mechanisms have been developed. The reduced mechanisms were developed from a large, detailed mechanism with about 1400 species for a 4-component gasoline surrogate. The two versions of the reduced mechanism developed in this work are: (1) a 96-species version and (2

  9. Mechanism reduction for multicomponent surrogates: a case study using toluene reference fuels

    CERN Document Server

    Niemeyer, Kyle E


    Strategies and recommendations for performing skeletal reductions of multicomponent surrogate fuels are presented, through the generation and validation of skeletal mechanisms for a three-component toluene reference fuel. Using the directed relation graph with error propagation and sensitivity analysis method followed by a further unimportant reaction elimination stage, skeletal mechanisms valid over comprehensive and high-temperature ranges of conditions were developed at varying levels of detail. These skeletal mechanisms were generated based on autoignition simulations, and validation using ignition delay predictions showed good agreement with the detailed mechanism in the target range of conditions. When validated using phenomena other than autoignition, such as perfectly stirred reactor and laminar flame propagation, tight error control or more restrictions on the reduction during the sensitivity analysis stage were needed to ensure good agreement. In addition, tight error limits were needed for close pr...

  10. Abnormal combustion caused by lubricating oil in high BMEP gas engines

    Energy Technology Data Exchange (ETDEWEB)

    Yasueda, Shinji [Kyushu Univ. (Japan). GDEC Gas and Diesel Engine; Takasaki, Koji; Tajima, Hiroshi [Kyushu Univ. (Japan). Lab. of Engine and Combustion (ECO)


    In recent years, abnormal combustion with high peak firing pressure has been experienced on gas engines with high brake mean effective pressures. The abnormality is detected not as pre-ignition but as knocking. Research, including visualisation tests on a single-cylinder engine, has confirmed the phenomenon to be pre-ignition caused by the auto-ignition of in-cylinder lubricant, causing cyclical variations of peak firing pressure on premix combustion gas engines. (orig.)

  11. Performance of HCCI Diesel Engine under the Influence of Various Working and Geometrical Parameters


    Karthikeya Sharma, T.; G. Amba Prasada Rao; K.Madhu Murthy


    Homogenous-charge-compression-ignition (HCCI) engines have the benefit of high efficiency with low emissions of NO and particulates. These benefits are due to the autoignition process of the dilute mixture of fuel and air during compression. Homogenous Compression ignition (HCCI) is a combustion concept, which is a hybrid between Otto engine and Diesel engine. The other emissions like HC and CO are high but can be after treated by a catalyst. This paper reviews the Characteristics of HCCI com...

  12. Turbulence-combustion interaction in direct injection diesel engine

    Directory of Open Access Journals (Sweden)

    Bencherif Mohamed


    Full Text Available The experimental measures of chemical species and turbulence intensity during the closed part of the engine combustion cycle are today unattainable exactly. This paper deals with numerical investigations of an experimental direct injection Diesel engine and a commercial turbocharged heavy duty direct injection one. Simulations are carried out with the kiva3v2 code using the RNG (k-ε model. A reduced mechanism for n-heptane was adopted for predicting auto-ignition and combustion processes. From the calibrated code based on experimental in-cylinder pressures, the study focuses on the turbulence parameters and combustion species evolution in the attempt to improve understanding of turbulence-chemistry interaction during the engine cycle. The turbulent kinetic energy and its dissipation rate are taken as representative parameters of turbulence. The results indicate that chemistry reactions of fuel oxidation during the auto-ignition delay improve the turbulence levels. The peak position of turbulent kinetic energy coincides systematically with the auto-ignition timing. This position seems to be governed by the viscous effects generated by the high pressure level reached at the auto-ignition timing. The hot regime flame decreases rapidly the turbulence intensity successively by the viscous effects during the fast premixed combustion and heat transfer during other periods. It is showed that instable species such as CO are due to deficiency of local mixture preparation during the strong decrease of turbulence energy. Also, an attempt to build an innovative relationship between self-ignition and maximum turbulence level is proposed. This work justifies the suggestion to determine otherwise the self-ignition timing.

  13. Adaptive methods in computational fluid dynamics of chemically reacting flows (United States)

    Rogg, B.


    Possible approaches to fully implicit adaptive algorithms suitable for the numerical simulation of unsteady two-dimensional reactive flows are examined. Emphasis is placed on self-adaptive gridding procedures applicable to time-dependent two-dimensional reactive flows. Pulsating flame propagation, autoignition in a nonpremixed flow, flame propagation in a strained mixing layer, and hot-spot-like self-ignition are considered as examples.

  14. Performance and analysis of a 4-stroke multi-cylinder gasoline engine with CAI combustion


    Zhao, H.; Li, J; Ma, T.; Ladommatos, N


    Copyright © 2002 SAE International. This paper is posted on this site with permission from SAE International. Further use of this paper is not permitted without permission from SAE Controlled Auto-Ignition (CAI) combustion was realised in a production type 4-stroke 4-cylinder gasoline engine without intake charge heating or increasing compression ratio. The CAI engine operation was achieved using substantially standard components modified only in camshafts to restrict the gas exchange proc...

  15. Investigation of combustion, performance and emission characteristics of 2-stroke and 4-stroke spark ignition and CAI/HCCI operations in a DI gasoline


    Y. Zhang; Zhao, H.


    In order to develop more efficient and cleaner gasoline engines, a number of new engine operating strategies have been proposed and researched on different engines, including the spark ignition (SI) and controlled autoignition (CAI) or HCCI in both 2-stroke and 4-stroke cycles in a poppet valve engine. In this work, a single cylinder direct injection gasoline engine equipped with an electro-hydraulic valve-train system has been commissioned and used to achieve seven different operating modes,...

  16. Ignition-promoting effect of NO2 on methane, ethane and methane/ethane mixtures in a rapid compression machine

    DEFF Research Database (Denmark)

    Gersen, S.; Mokhov, A.V.; Darmeveil, J.H.


    Autoignition delay times of stoichiometric methane, ethane and methane/ethane mixtures doped with 100 and 270ppm of NO2 have been measured in a RCM in the temperature range 900–1050K and pressures from 25 to 50bar. The measurements show that addition of NO2 to CH4/O2/N2/Ar and CH4/C2H6/O2/N2/Ar m...

  17. Ignition of Isomers of Pentane: An Experimental and Kinetic Modeling Study (United States)


    diesel engines [26,27], and ignition under homogeneous charge compres- sion ignition ( HCCI ) conditions [26,28]. Kinetic modeling shows that the isomers of...Introduction Hydrocarbon ignition is important in many prac- tical combustion systems, including internal com- bustion engines , detonations, pulse combustors...tem- peratures are similar to those in automotive engines during diesel ignition and end-gas autoignition in spark-ignition engines . The RCM provides

  18. <研究論文>DME燃料による予混合圧縮自己着火機関の特性


    嶽間沢, 秀孝


    It converted so that a small engine could be operated by Homogeneous Charge Compression Ignition (HCCI) combustion with dimethyl ether (DME). It is difficult to control auto-ignition timing in HCCI combustion. The sound performances and the exhaust temperature of compression ignition combustion engine fueled with DME and diesel fuel were investigated. As a result, it succeeded in continuous smokeless operation of an efficient internal combustion engine by DME homogeneous charge system.

  19. Self-ignition of diesel spray combustion (United States)

    Dhuchakallaya, Isares; Watkins, A. P.


    This work presents the development and implementation of auto-ignition modelling for DI diesel engines by using the probability density function-eddy break-up (PDF-EBU) model. The key concept of this approach is to combine the chemical reaction rate dealing with low-temperature mode, and the turbulence reaction rate governing the high-temperature part by a reaction progress variable coupling function which represents the level of reaction. The average reaction rate here is evaluated by a PDF averaging approach. In order to assess the potential of this developed model, the well-known Shell ignition model is chosen to compare in auto-ignition analysis. In comparison, the PDF-EBU ignition model yields the ignition delay time in good agreement with the Shell ignition model prediction. However, the ignition kernel location predicted by the Shell model is slightly nearer injector than that by the PDF-EBU model leading to shorter lift-off length. As a result, the PDF-EBU ignition model developed here are fairly satisfactory in predicting the auto-ignition of diesel engines with the Shell ignition model.

  20. Numerical study of a jet-in-hot-coflow burner with hydrogen-addition using the Flamelet Generated Manifolds technique (United States)

    Abtahizadeh, Seyed Ebrahim; van Oijen, Jeroen; de Goey, Philip


    Recently Mild combustion is subjected to intensive research because of its unique ability to provide high efficiency and low pollutant combustion simultaneously in industrial heating processes. In most practical Mild combustion applications, a fuel jet is ignited due to recirculation of hot burned gases. The impact of burned gases on autoignition and flame stabilization has been studied in a laboratory jet-in-hot-coflow (JHC) burner. Results of this study help us to understand recent experimental observations of the Delft group (DJHC burner) in which Dutch Natural Gas (DNG) is mixed with various amounts of H2. The main focus is on the modeling of autoignition in the DJHC burner by using the Flamelet Generated Manifolds (FGM) technique. In this technique, kinetic information is tabulated with a few controlling variables which results in a significant decrease in simulation time. The FGM tabulation has been performed using igniting laminar counterflow diffusion flames. Since H2 is present in the fuel composition, it is essential to include preferential diffusion effects in the table due to the high diffusivity of H2. Based on results, the FGM table is capable to reproduce the autoignition of hydrogen containing fuel predicted by detailed chemistry in 1D counterflow flames. The Authors gratefully acknowledge financial support of the Dutch Technology Foundation STW.

  1. A fundamental study of the oxidation behavior of SI primary reference fuels with propionaldehyde and DTBP as an additive (United States)

    Johnson, Rodney

    In an effort to combine the benefits of SI and CI engines, Homogeneous Charge Compression Ignition (HCCI) engines are being developed. HCCI combustion is achieved by controlling the temperature, pressure, and composition of the fuel and air mixture so that autoignition occurs in proper phasing with the piston motion. This control system is fundamentally more challenging than using a spark plug or fuel injector to determine ignition timing as in SI and CI engines, respectively. As a result, this is a technical barrier that must be overcome to make HCCI engines applicable to a wide range of vehicles and viable for high volume production. One way to tailor the autoignition timing is to use small amounts of ignition enhancing additives. In this study, the effect of the addition of DTBP and propionaldehyde on the autoignition behavior of SI primary reference fuels was investigated. The present work was conducted in a new research facility built around a single cylinder Cooperative Fuels Research (CFR) octane rating engine but modified to run in HCCI mode. It focused on the effect of select oxygenated hydrocarbons on hydrocarbon fuel oxidation, specifically, the primary reference fuels n-heptane and iso-octane. This work was conducted under HCCI operating conditions. Previously, the operating parameters for this engine were validated for stable combustion under a wide range of operating parameters such as engine speeds, equivalence ratios, compression ratios and inlet manifold temperature. The stable operating range under these conditions was recorded and used for the present study. The major focus of this study was to examine the effect of the addition of DTBP or propionaldehyde on the oxidation behavior of SI primary reference fuels. Under every test condition the addition of the additives DTBP and propionaldehyde caused a change in fuel oxidation. DTBP always promoted fuel oxidation while propionaldehyde promoted oxidation for lower octane number fuels and delayed

  2. Effects of substitution on counterflow ignition and extinction of C3 and C4 alcohols

    KAUST Repository

    Alfazazi, Adamu


    Dwindling reserves and inherent uncertainty in the price of conventional fuels necessitates a search for alternative fuels. Alcohols represent a potential source of energy for the future. The structural features of an alcohol fuel have a direct impact on combustion properties. In particular, substitution in alcohols can alter the global combustion reactivity. In this study, experiments and numerical simulations were conducted to investigate the critical conditions of extinction and autoignition of n-propanol, 1-butanol, iso-propanol and iso-butanol in non-premixed diffusion flames. Experiments were carried out in the counterflow configuration, while simulations were conducted using a skeletal chemical kinetic model for the C3 and C4 alcohols. The fuel stream consists of the pre-vaporized fuel diluted with nitrogen, while the oxidizer stream is air. The experimental results show that autoignition temperatures of the tested alcohols increase in the following order: iso-propanol > iso-butanol > 1-butanol ≈ n-propanol. The simulated results for the branched alcohols agree with the experiments, while the autoignition temperature of 1-butanol is slightly higher than that of n-propanol. For extinction, the experiments show that the extinction limits of the tested fuels increase in the following order: n-propanol ≈ 1-butanol > iso-butanol > iso-propanol. The model suggests that the extinction limits of 1-butanol is slightly higher than n-propanol with extinction strain rate of iso-butanol and iso-propanol maintaining the experimentally observed trend. The transport weighted enthalpy (TWE) and radical index (Ri) concepts were utilized to rationalize the observed reactivity trends for these fuels.

  3. Ethanol oxidation: kinetics of the alpha-hydroxyethyl radical + O2 reaction. (United States)

    da Silva, Gabriel; Bozzelli, Joseph W; Liang, Long; Farrell, John T


    Bioethanol is currently a significant gasoline additive and the major blend component of flex-fuel formulations. Ethanol is a high-octane fuel component, and vehicles designed to take advantage of higher octane fuel blends could operate at higher compression ratios than traditional gasoline engines, leading to improved performance and tank-to-wheel efficiency. There are significant uncertainties, however, regarding the mechanism for ethanol autoignition, especially at lower temperatures such as in the negative temperature coefficient (NTC) regime. We have studied an important chemical process in the autoignition and oxidation of ethanol, reaction of the alpha-hydroxyethyl radical with O2(3P), using first principles computational chemistry, variational transition state theory, and Rice-Ramsperger-Kassel-Marcus (RRKM)/master equation simulations. The alpha-hydroxyethyl + O2 association reaction is found to produce an activated alpha-hydroxy-ethylperoxy adduct with ca. 37 kcal mol(-1) of excess vibrational energy. This activated adduct predominantly proceeds to acetaldehyde + HO(2), with smaller quantities of the enol vinyl alcohol (ethenol), particularly at higher temperatures. The reaction to acetaldehyde + HO2 proceeds with such a low barrier that collision stabilization of C2O3H5 isomers is unimportant, even for high-pressure/low-temperature conditions. The short lifetimes of these radicals precludes the chain-branching addition of a second O2 molecule, responsible for NTC behavior in alkane autoignition. This result helps to explain why ignition delays for ethanol are longer than those for ethane, despite ethanol having a weaker C-C bond energy. Given its relative instability, it is also unlikely that the alpha-hydroxy-ethylperoxy radical acts as a major acetaldehyde sink in the atmosphere, as has been suggested.

  4. 汽油机

    Institute of Scientific and Technical Information of China (English)


    Competitive surface interactions of critical additives with piston ring/cylinder liner components under lubricated breaking-in conditions; Controlled autoignition combustion process with an electromechanical valve train;CSI - controlled auto ignition - the best solution for the fuel consumption - versus emission trade-off?; Cycle-to-cycle variations: Their influence on cycle resolved gas temperature and unbumed hydrocarbons from a camless gasoline compression ignition engine;Demands on Formula One engines and subsequent development strategies;Description of the Kangoo fitted with a range extender;

  5. A numerical study of HCCI combustion of PRF mixtures compared with PCCI experiments

    Energy Technology Data Exchange (ETDEWEB)

    Van Wijngaarden, B.


    For automotive applications engines that produce less soot and NOx are desired. For that reason the Homogeneous Charge Compression Ignition (HCCI) principle is investigated all over the world, including the technical universities of Berlin (TUB) and Eindhoven. HCCI combines a homogeneous charge, as in an Otto engine with the autoignition principle of a Diesel engine. Auto-ignition and almost instantaneous combustion of a homogeneous charge leads to almost zero soot emissions, lower temperatures and thereby much lower NOx emissions. Auto-ignition timing however, depends on the fuel and its chemistry, which is very sensitive to the applied conditions, being pressure, temperature, equivalence ratio ({phi}), dilution with EGR and engine speed. To study this systematically a 0D model with PRF fuels is used (Primary Reference Fuels are n-heptane, iso-octane and mixtures). A 0D model is chosen because it excludes complex fluid dynamics and thereby allows the use of detailed combustion mechanisms, describing the (PRF) chemistry. Furthermore the model has a multi zone possibility to evaluate in-homogeneities of the charge. PRF fuels are used because n-heptane (CN=55) auto-ignites like a diesel and iso-octane (ON=100) approaches gasoline. For the PRF chemistry three combustion mechanisms were selected, of which two were validated showing a great difference in predicted ignition delay and sensitivity to changes. Furthermore the model was validated with a PCCI (Premixed Charge Compression Ignition) experiment. Extensive comparisons with PCCI experiments from the TUB showed that when the moment of injection was used to launch the chemistry in the model, only the Soyhan mechanism predicted the ignition close to the experimental ignition moment. Furthermore a 7 zone model was able to approach the experimental CO and NOX emissions. Finally none of the mechanisms was able to predict a pressure profile similar to the experiments. More zones and or a better mechanism could improve

  6. A numerical analysis of the effects of a stratified pre-mixture on homogeneous charge compression ignition combustion

    Energy Technology Data Exchange (ETDEWEB)

    Jamsran, Narankhuu; Lim, Ock Taeck [University of Ulsan, Ulsan (Korea, Republic of)


    We investigated the efficacy of fuel stratification in a pre-mixture of dimethyl ether (DME) and n-butane, which have different autoignition characteristics, for reducing the pressure rise rate (PRR) of homogeneous charge compression ignition engines. A new chemical reaction model was created by mixing DME and n-butane and compared with existing chemical reaction models to verify the effects observed. The maximum PRR depended on the mixture ratio. When DME was charged with stratification and n-butane was charged with homogeneity, the maximum PRR was the lowest among all the mixtures studied. Calculations were performed using CHEMKIN and modified using SENKIN software.

  7. Fuel mixture stratification as a method for improving homogeneous charge compression ignition engine operation (United States)

    Dec, John E.; Sjoberg, Carl-Magnus G.


    A method for slowing the heat-release rate in homogeneous charge compression ignition ("HCCI") engines that allows operation without excessive knock at higher engine loads than are possible with conventional HCCI. This method comprises injecting a fuel charge in a manner that creates a stratified fuel charge in the engine cylinder to provide a range of fuel concentrations in the in-cylinder gases (typically with enough oxygen for complete combustion) using a fuel with two-stage ignition fuel having appropriate cool-flame chemistry so that regions of different fuel concentrations autoignite sequentially.

  8. Visualization study of ignition modes behind bifurcated-reflected shock waves


    Yamashita, Hiroki; Kasahara, Jiro; Sugiyama, Yuta; Matsuo, Akiko


    This study was a numerical and experimental investigation of low-temperature auto-ignitions behindreflected shock waves in which a shock tube was employed as the experimental system. We used ahigh-speed video camera and the Schlieren method to visualize the ignition phenomena. Experimentswere performed over a temperature range from 549 ± 10 to 1349 ± 11 K and a pressure range from56 ± 2 to 203 ± 13 kPa, and a non-diluted stoichiometric acetylene–oxygen mixture was chosen as thecombustible gas...

  9. Development and validation of a generic reduced chemical kinetic mechanism for CFD spray combustion modelling of biodiesel fuels

    DEFF Research Database (Denmark)

    Cheng, Xinwei; Ng, Hoon Kiat; Ho, Jee Hou


    In this reported work, a generic reduced biodiesel chemical kinetic mechanism, with components of methyl decanoate (C11H22O2, MD), methyl-9-decenoate (C11H20O2, MD9D) and n-heptane (C7H16) was built to represent the methyl esters of coconut, palm, rapeseed and soybean. The reduced biodiesel...... and detailed mechanism predictions, for each zero-dimensional (0D) auto-ignition and extinction process using CHEMKIN-PRO. Maximum percentage errors of less than 40.0% were recorded when the predicted ignition delay (ID) periods for coconut, palm, rapeseed and soybean methyl esters were compared to those...

  10. The potential of di-methyl ether (DME) as an alternative fuel for compression-ignition engines: A review


    Arcoumanis, C.; Bae, C.; Crookes, R.; Kinoshita, E


    This paper reviews the properties and application of di-methyl ether (DME) as a candidate fuel for compression-ignition engines. DME is produced by the conversion of various feedstock such as natural gas, coal, oil residues and bio-mass. To determine the technical feasibility of DME, the review compares its key properties with those of diesel fuel that are relevant to this application. DME’s diesel engine-compatible properties are its high cetane number and low auto-ignition temperature. In a...

  11. Oxidation of Alkane Rich Gasoline Fuels and their Surrogates in a Motored Engine

    KAUST Repository

    Shankar, Vijai S B


    The validation of surrogates formulated using a computational framework by Ahmed et al.[1]for two purely paraffinic gasoline fuels labelled FACE A and FACE C was undertaken in this study. The ability of these surrogate mixtures to be used in modelling LTC engines was accessed by comparison of their low temperature oxidation chemistry with that of the respective parent fuel as well as a PRF based on RON. This was done by testing the surrogate mixtures in a modified Cooperative Fuels Research (CFR) engine running in Controlled Autoignition Mode (CAI) mode. The engine was run at a constant speed of 600 rpm at an equivalence ratio of 0.5 with the intake temperature at 150 °C and a pressure of 98 kPa. The low temperature reactivity of the fuels were studied by varying the compression ratio of the engine from the point were very only small low temperature heat release was observed to a point beyond which auto-ignition of the fuel/air mixture occurred. The apparent heat release rates of different fuels was calculated from the pressure histories using first law analysis and the CA 50 times of the low temperature heat release (LTHR) were compared. The surrogates reproduced the cool flame behavior of the parent fuels better than the PRF across all compression ratios.

  12. Experimental Study of Ignition over Impact-Driven Supersonic Liquid Fuel Jet

    Directory of Open Access Journals (Sweden)

    Anirut Matthujak


    Full Text Available This study experimentally investigates the mechanism of the ignition of the supersonic liquid fuel jet by the visualization. N-Hexadecane having the cetane number of 100 was used as a liquid for the jet in order to enhance the ignition potential of the liquid fuel jet. Moreover, the heat column and the high intensity CO2 laser were applied to initiate the ignition. The ignition over the liquid fuel jet was visualized by a high-speed digital video camera with a shadowgraph system. From the shadowgraph images, the autoignition or ignition of the supersonic liquid fuel jet, at the velocity of 1,186 m/s which is a Mach number relative to the air of 3.41, did not take place. The ignition still did not occur, even though the heat column or the high intensity CO2 laser was alone applied. The attempt to initiate the ignition over the liquid fuel jet was achieved by applying both the heat column and the high intensity CO2 laser. Observing the signs of luminous spots or flames in the shadowgraph would readily indicate the presence of ignitions. The mechanism of the ignition and combustion over the liquid fuel jet was clearly clarified. Moreover, it was found that the ignition over the supersonic liquid fuel jet in this study was rather the force ignition than being the auto-ignition induced by shock wave heating.

  13. Experimental and Modeling Investigation of the Effectof H2S Addition to Methane on the Ignition and Oxidation at High Pressures

    DEFF Research Database (Denmark)

    Gersen, Sander; van Essen, Martijn; Darmeveil, Harry;


    The autoignition and oxidation behavior of CH4/H2S mixtures has been studied experimentally in a rapid compression machine (RCM) and a high-pressure flow reactor. The RCM measurements show that the addition of 1% H2S to methane reduces the autoignition delay time by a factor of 2 at pressures...... ranging from 30 to 80 bar and temperatures from 930 to 1050 K. The flow reactor experiments performed at 50 bar show that, for stoichiometric conditions,a large fraction of H2S is already consumed at 600 K, while temperatures above 750 K are needed to oxidize 10% methane. A detailed chemical kinetic model...... has been established, describing the oxidation of CH4 and H2S as well as the formation and consumption of organo sulfuric species. Computations with the modelshow good agreement with the ignition measurements, provided that reactions of H2S and SH with peroxides (HO2 and CH3OO) are constrained...

  14. Conditional moment closure for two-phase flows - A review of recent developments and application to various spray combustion configurations (United States)

    Wright, Y. M.; Bolla, M.; Boulouchos, K.; Borghesi, G.; Mastorakos, E.


    Energy conversion devices of practical interest such as engines or combustors operate in highly turbulent flow regimes. Due to the nature of the hydrocarbon fuels employed, the oxidation chemistry involves a broad range of time-scales some of which cannot be decoupled from the flow. Among the approaches utilised to tackle the modelling of turbulent combustion, Conditional Moment Closure (CMC), belonging to the computationally efficient class of presumed PDF methods, has shown great potential. For single-phase flows it has been demonstrated on non-premixed turbulent lifted and opposed jets, lifted flames and auto-igniting jets. Here we seek to review recent advances in both modelling and application of CMC for auto-ignition of fuel sprays. The experiments chosen for code validation and model improvement include generic spray test rigs with dimensions of passenger car as well as large two-stroke marine engines. Data for a broad range of operating conditions of a heavy-duty truck engine is additionally employed to assess the predictive capability of the model with respect to NOx emissions. An outlook on future enhancements including e.g. LES-CMC formulation also for two-phase flows as well as developments in the field of soot emissions are summarised briefly.

  15. Modes of reaction front propagation and end-gas combustion of hydrogen/air mixtures in a closed chamber

    KAUST Repository

    Shi, Xian


    Modes of reaction front propagation and end-gas combustion of hydrogen/air mixtures in a closed chamber are numerically investigated using an 1-D unsteady, shock-capturing, compressible and reacting flow solver. Different combinations of reaction front propagation and end-gas combustion modes are observed, i.e., 1) deflagration without end-gas combustion, 2) deflagration to end-gas autoignition, 3) deflagration to end-gas detonation, 4) developing or developed detonation, occurring in the sequence of increasing initial temperatures. Effects of ignition location and chamber size are evaluated: the asymmetric ignition is found to promote the reactivity of unburnt mixture compared to ignitions at center/wall, due to additional heating from asymmetric pressure waves. End-gas combustion occurs earlier in smaller chambers, where end-gas temperature rise due to compression heating from the deflagration is faster. According to the ξ−ε regime diagram based on Zeldovich theory, modes of reaction front propagation are primarily determined by reactivity gradients introduced by initial ignition, while modes of end-gas combustion are influenced by the total amount of unburnt mixture at the time when autoignition occurs. A transient reactivity gradient method is provided and able to capture the occurrence of detonation.

  16. Numerical Investigation Into Effect of Fuel Injection Timing on CAI/HCCI Combustion in a Four-Stroke GDI Engine (United States)

    Cao, Li; Zhao, Hua; Jiang, Xi; Kalian, Navin


    The Controlled Auto-Ignition (CAI) combustion, also known as Homogeneous Charge Compression Ignition (HCCI), was achieved by trapping residuals with early exhaust valve closure in conjunction with direct injection. Multi-cycle 3D engine simulations have been carried out for parametric study on four different injection timings in order to better understand the effects of injection timings on in-cylinder mixing and CAI combustion. The full engine cycle simulation including complete gas exchange and combustion processes was carried out over several cycles in order to obtain the stable cycle for analysis. The combustion models used in the present study are the Shell auto-ignition model and the characteristic-time combustion model, which were modified to take the high level of EGR into consideration. A liquid sheet breakup spray model was used for the droplet breakup processes. The analyses show that the injection timing plays an important role in affecting the in-cylinder air/fuel mixing and mixture temperature, which in turn affects the CAI combustion and engine performance.

  17. Application of micro-genetic algorithm for calibration of kinetic parameters in HCCI engine combustion model

    Institute of Scientific and Technical Information of China (English)

    Haozhong HUANG; Wanhua SU


    The micro-genetic algorithm (μGA) as a highly effective optimization method, is applied to calibrate to a newly developed reduced chemical kinetic model (40 species and 62 reactions) for the homogeneous charge compression ignition (HCCI) combustion of n-heptane to improve its autoignition predictions for different engine operating conditions. The seven kinetic parameters of the calibrated model are determined using a combination of the Micro-Genetic Algorithm and the SENKIN program of CHEMKIN chemical kinetics software package. Simulation results show that the autoignition predictions of the calibrated model agree better with those of the detailed chemical kinetic model (544 species and 2 446 reactions) than the original model over the range of equivalence ratios from 0.1-1.3 and temperature from 300-3 000 K. The results of this study have demonstrated that the μGA is an effective tool to facilitate the calibration of a large number of kinetic parameters in a reduced kinetic model.

  18. Impact of branched structures on cycloalkane ignition in a motored engine: Detailed product and conformational analyses

    KAUST Repository

    Kang, Dongil


    The ignition process of ethylcyclohexane (ECH) and its two isomers, 1,3-dimethylcyclohexane (13DMCH) and 1,2-dimethylcyclohexane (12DMCH) was investigated in a modified CFR engine. The experiment was conducted with intake air temperature of 155. °C, equivalence ratio of 0.5 and engine speed of 600. rpm. The engine compression ratio (CR) was gradually increased in a stepwise manner until autoignition occurred. It was found that ECH exhibited a significantly higher oxidation reactivity compared to its two isomers. The autoignition criterion was based on CO emissions and the apparent heat release rates. Ethylcyclohexane (ECH) indicated noticeable two stage ignition behavior, while less significant heat release occurred for the two isomers at comparable conditions. The mole fractions of unreacted fuel and stable intermediate species over a wide range of compression ratios were analyzed by GC-MS and GC-FID. Most of the species indicated constant rates of formation and the trends of relative yield to unreacted fuel are well in agreement with the oxidation reactivity in the low temperature regime. The major intermediate species are revealed as a group of conjugate olefins, which possess the same molecular structure as the original fuel compound except for the presence of a double carbon bond. Conjugate olefins were mostly formed through (1,4) H-shift isomerization during the low temperature oxidation of alkylcyclohexanes. Conformation analysis explains the reactivity differences in the three isomers as well as the fractions of intermediate species. The hydrogen availability located in alkyl substituents plays an important role in determining oxidation reactivity, requiring less activation energy for abstraction through the (1,5) H-shift isomerization. This reactivity difference contributes to building up the major intermediate species observed during oxidation of each test fuel. 12DMCH, whose ignition reactivity is the lowest, less favors β-scission of C-C backbone of

  19. Performance of HCCI Diesel Engine under the Influence of Various Working and Geometrical Parameters

    Directory of Open Access Journals (Sweden)

    T. Karthikeya Sharma


    Full Text Available Homogenous-charge-compression-ignition (HCCI engines have the benefit of high efficiency with low emissions of NO and particulates. These benefits are due to the autoignition process of the dilute mixture of fuel and air during compression. Homogenous Compression ignition (HCCI is a combustion concept, which is a hybrid between Otto engine and Diesel engine. The other emissions like HC and CO are high but can be after treated by a catalyst. This paper reviews the Characteristics of HCCI combustion in direct injection diesel engines under various governing factors in HCCI operations such as injection timing, injection pressure, piston bowl geometry, compression ratio, intake charge temperature, exhaust gas recirculation (EGR and supercharging or turbo charging are discussed in this review. The effects of design and operating parameters on HCCI diesel combustion, emissions particularly NOx and soot are reviewed.

  20. N+2 Advanced Low NOx Combustor Technology Final Report (United States)

    Herbon, John; Aicholtz, John; Hsieh, Shih-Yang; Viars, Philip; Birmaher, Shai; Brown, Dan; Patel, Nayan; Carper, Doug; Cooper, Clay; Fitzgerald, Russell


    In accordance with NASAs technology goals for future subsonic vehicles, this contract identified and developed new combustor concepts toward meeting N+2 generation (2020) LTO (landing and take-off) NOx emissions reduction goal of 75 from the standard adopted at Committee on Aviation Environmental Protection 6 (CAEP6). Based on flame tube emissions, operability, and autoignition testing, one concept was down selected for sector testing at NASA. The N+2 combustor sector successfully demonstrated 75 reduction for LTO NOx (vs. CAEP6) and cruise NOx (vs. 2005 B777-200 reference) while maintaining 99.9 cruise efficiency and no increase in CO and HC emissions.The program also developed enabling technologies for the combustion system including ceramic matrix composites (CMC) liner materials, active combustion control concepts, and laser ignition for improved altitude relight.

  1. Effects of natural gas composition on ignition delay under diesel conditions (United States)

    Naber, J. D.; Siebers, D. L.; Dijulio, S. S.; Westbrook, C. K.


    Effects of variations in natural gas composition on autoignition of natural gas under direct-injection (DI) diesel engine conditions were studied experimentally in a constant-volume combustion vessel and computationally using a chemical kinetic model. Four fuel blends were investigated: pure methane, a capacity weighted mean natural gas, a high ethane content natural gas, and a natural gas with added propane typical of peak shaving conditions. Experimentally measured ignition delays were longest for pure methane and became progressively shorter as ethane and propane concentrations increased. At conditions characteristic of a DI compression ignition natural gas engine at Top Dead Center (CR = 23:1, p = 6.8 MPa, T = 1150K), measured ignition delays for the four fuels varied from 1.8 ms for the peak shaving and high ethane gases to 2.7 ms for pure methane. Numerically predicted variations in ignition delay as a function of natural gas composition agreed with these measurements.

  2. Internal combustion engine using premixed combustion of stratified charges (United States)

    Marriott, Craig D.; Reitz, Rolf D. (Madison, WI


    During a combustion cycle, a first stoichiometrically lean fuel charge is injected well prior to top dead center, preferably during the intake stroke. This first fuel charge is substantially mixed with the combustion chamber air during subsequent motion of the piston towards top dead center. A subsequent fuel charge is then injected prior to top dead center to create a stratified, locally richer mixture (but still leaner than stoichiometric) within the combustion chamber. The locally rich region within the combustion chamber has sufficient fuel density to autoignite, and its self-ignition serves to activate ignition for the lean mixture existing within the remainder of the combustion chamber. Because the mixture within the combustion chamber is overall premixed and relatively lean, NO.sub.x and soot production are significantly diminished.

  3. 3rd International Workshop on Turbulent Spray Combustion

    CERN Document Server

    Gutheil, Eva


    This book reflects the results of the 2nd and 3rd International Workshops on Turbulent Spray Combustion. The focus is on progress in experiments and numerical simulations for two-phase flows, with emphasis on spray combustion. Knowledge of the dominant phenomena and their interactions allows development of predictive models and their use in combustor and gas turbine design. Experts and young researchers present the state-of-the-art results, report on the latest developments and exchange ideas in the areas of experiments, modelling and simulation of reactive multiphase flows. The first chapter reflects on flame structure, auto-ignition and atomization with reference to well-characterized burners, to be implemented by modellers with relative ease. The second chapter presents an overview of first simulation results on target test cases, developed at the occasion of the 1st International Workshop on Turbulent Spray Combustion. In the third chapter, evaporation rate modelling aspects are covered, while the fourth ...

  4. Thermal Behaviour of AP Based CMDB Propellants with Stabilizers

    Directory of Open Access Journals (Sweden)

    S. N. Asthana


    Full Text Available Stability test results and DTA studies indicate the superiority of molecular sieve (MS over zirconium silicate (ZrSiO/sub 4/ as the stabilizer for a composite modified double base (CMDB system. Shelf life as computed from autoignition test results was 30 years for MS-based composition which is almost double the life of ZrSiO/sub 4/, but approximately half the life of resorcinol-based composition which was used as a reference. Higher stabilizing effect of MS as compared to ZrSiO/sub 4/ has been explained on the basis of the presence of channels and cavities in its structure, which makes it an effective adsorbent for decomposition catalysing species. Poor stabilization capability of m-dinitrobenzene as compared to resorcinol suggests the catalytic involvement of acidic decomposition products of nitrate esters in autodecomposition process of CMDB propellants.

  5. Modelling of diesel spray flame under engine-like conditions using an accelerated eulerian stochastic fields method: A convergence study of the number of stochastic fields

    DEFF Research Database (Denmark)

    Pang, Kar Mun; Jangi, Mehdi; Bai, X.-S.

    generated similar results. The principal motivation for ESF compared to Lagrangian particle based PDF is the relative ease of implementation of the former into Eulerian computational fluid dynamics(CFD) codes [5]. Several works have attempted to implement the ESF model for the simulations of diesel spray......The use of transported Probability Density Function(PDF) methods allows a single model to compute the autoignition, premixed mode and diffusion flame of diesel combustion under engine-like conditions [1,2]. The Lagrangian particle based transported PDF models have been validated across a wide range...... combustion under engine-like conditions.The current work aims to further evaluate the performance of the ESF model in this application, with an emphasis on examining the convergence of the number of stochastic fields, nsf. Five test conditions, covering both the conventional diesel combustion and low...

  6. On the importance of graph search algorithms for DRGEP-based mechanism reduction methods

    CERN Document Server

    Niemeyer, Kyle E


    The importance of graph search algorithm choice to the directed relation graph with error propagation (DRGEP) method is studied by comparing basic and modified depth-first search, basic and R-value-based breadth-first search (RBFS), and Dijkstra's algorithm. By using each algorithm with DRGEP to produce skeletal mechanisms from a detailed mechanism for n-heptane with randomly-shuffled species order, it is demonstrated that only Dijkstra's algorithm and RBFS produce results independent of species order. In addition, each algorithm is used with DRGEP to generate skeletal mechanisms for n-heptane covering a comprehensive range of autoignition conditions for pressure, temperature, and equivalence ratio. Dijkstra's algorithm combined with a coefficient scaling approach is demonstrated to produce the most compact skeletal mechanism with a similar performance compared to larger skeletal mechanisms resulting from the other algorithms. The computational efficiency of each algorithm is also compared by applying the DRG...

  7. Microwave assisted synthesis,sinterability and properties of Ca-Zn co-doped LaCrO_3 as interconnect material for IT-SOFCs

    Institute of Scientific and Technical Information of China (English)

    陈永红; 卢肖永; 丁岩芝; 刘杏芹; 孟广耀


    The interconnect materials La0.7Ca0.3Cr1-xZnxO3-δ(x=0,0.01,0.03,0.05,0.07) were prepared by a microwave assisted sol-gel auto-ignition process.The crystalline structures of the samples were characterized by X-ray diffraction(XRD) and the lattice parameters were evaluated with Rietveld method.For Ca-Zn co-doped LaCrO3 with x=0.03,the sintering activity was improved,and the relative density came up to 96.5% for the sample sintered at 1300 oC for 10 h.The electrical conductivity of the samples was increased fr...

  8. A case of deep burns, while diving The Lusitania.

    LENUS (Irish Health Repository)

    Curran, John N


    We present the first documented case of severe burns, sustained by a diver as a result of auto-ignition of air-activated heat packs at high partial pressure of oxygen and high ambient pressure. Our patient was diving the shipwreck of The Lusitania off the south coast of Ireland. This is a significant wreck, lying 90 metres down on the seabed. Torpedoed by a German U-boat in 1915, its loss prompted American involvement in WW1. Several unlikely events combined in this case to bring about serious and life threatening injuries. Herein we discuss the case and explore some of the physical and chemical processes that lead to these injuries.

  9. Influence of Turbulent Fluctuations on Detonation Propagation

    CERN Document Server

    Maxwell, Brian McN; Lau-Chapdelaine, Sebastien S M; Falle, Sam A E G; Sharpe, Gary J; Radulescu, Matei I


    The present study addresses the reaction zone structure and burning mechanism of unstable detonations. Experiments investigated mainly two-dimensional methane-oxygen cellular detonations in a thin channel geometry. The sufficiently high temporal resolution permitted to determine the PDF of the shock distribution, a power-law with an exponent of -3, and the burning rate of unreacted pockets from their edges - through surface turbulent flames with a speed approximately 3-7 times larger than the laminar one at the local conditions. Numerical simulations were performed using a novel Large Eddy Simulation method where the reactions due to both auto-ignition and turbulent transport and treated exactly at the sub-grid scale in a reaction-diffusion formulation. The model is an extension of Kerstein & Menon's Linear Eddy Model for Large Eddy Simulation to treat flows with shock waves and rapid gasdynamic transients. The two-dimensional simulations recovered well the amplification of the laminar flame speed owing t...

  10. Reduced Toxicity Fuel Satellite Propulsion System Including Catalytic Decomposing Element with Hydrogen Peroxide (United States)

    Schneider, Steven J. (Inventor)


    A reduced toxicity fuel satellite propulsion system including a reduced toxicity propellant supply for consumption in an axial class thruster and an ACS class thruster. The system includes suitable valves and conduits for supplying the reduced toxicity propellant to the ACS decomposing element of an ACS thruster. The ACS decomposing element is operative to decompose the reduced toxicity propellant into hot propulsive gases. In addition the system includes suitable valves and conduits for supplying the reduced toxicity propellant to an axial decomposing element of the axial thruster. The axial decomposing element is operative to decompose the reduced toxicity propellant into hot gases. The system further includes suitable valves and conduits for supplying a second propellant to a combustion chamber of the axial thruster, whereby the hot gases and the second propellant auto-ignite and begin the combustion process for producing thrust.

  11. An experimental and kinetic modelling study of the oxidation of the four isomers of butanol

    CERN Document Server

    Moss, J T; Oehlschlaeger, M A; Biet, Joffrey; Warth, Valérie; Glaude, Pierre-Alexandre; Battin-Leclerc, Frédérique; 10.1021/jp806464p


    Butanol, an alcohol which can be produced from biomass sources, has received recent interest as an alternative to gasoline for use in spark ignition engines and as a possible blending compound with fossil diesel or biodiesel. Therefore, the autoignition of the four isomers of butanol (1-butanol, 2-butanol, iso-butanol, and tert-butanol) has been experimentally studied at high temperatures in a shock tube and a kinetic mechanism for description of their high-temperature oxidation has been developed. Ignition delay times for butanol/oxygen/argon mixtures have been measured behind reflected shock waves at temperatures and pressures ranging from approximately 1200 to 1800 K and 1 to 4 bar. Electronically excited OH emission and pressure measurements were used to determine ignition delay times. A detailed kinetic mechanism has been developed to describe the oxidation of the butanol isomers and validated by comparison to the shock tube measurements. Reaction flux and sensitivity analysis indicate that the consumpti...

  12. Los Alamos National Security, LLC Request for Information on how industry may partner with the Laboratory on KIVA software.

    Energy Technology Data Exchange (ETDEWEB)

    Mcdonald, Kathleen Herrera [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)


    KIVA is a family of Fortran-based computational fluid dynamics software developed by LANL. The software predicts complex fuel and air flows as well as ignition, combustion, and pollutant-formation processes in engines. The KIVA models have been used to understand combustion chemistry processes, such as auto-ignition of fuels, and to optimize diesel engines for high efficiency and low emissions. Fuel economy is heavily dependent upon engine efficiency, which in turn depends to a large degree on how fuel is burned within the cylinders of the engine. Higher in-cylinder pressures and temperatures lead to increased fuel economy, but they also create more difficulty in controlling the combustion process. Poorly controlled and incomplete combustion can cause higher levels of emissions and lower engine efficiencies.

  13. Thermal explosion in oscillating ambient conditions (United States)

    Novozhilov, Vasily


    Thermal explosion problem for a medium with oscillating ambient temperature at its boundaries is considered. This is a new problem in thermal explosion theory, not previously considered in a distributed system formulation, but important for combustion and fire science. It describes autoignition of wide range of fires (such as but not limited to piles of biosolids and other organic matter; storages of munitions, explosives, propellants) subjected to temperature variations, such as seasonal or day/night variation. The problem is considered in formulation adopted in classical studies of thermal explosion. Critical conditions are determined by frequency and amplitude of ambient temperature oscillations, as well as by a number of other parameters. Effects of all the parameters on critical conditions are quantified. Results are presented for the case of planar symmetry. Development of thermal explosion in time is also considered, and a new type of unsteady thermal explosion development is discovered where thermal runaway occurs after several periods of temperature oscillations within the medium.

  14. A Study on Homogeneous Charge Compression Ignition Gasoline Engines (United States)

    Kaneko, Makoto; Morikawa, Koji; Itoh, Jin; Saishu, Youhei

    A new engine concept consisting of HCCI combustion for low and midrange loads and spark ignition combustion for high loads was introduced. The timing of the intake valve closing was adjusted to alter the negative valve overlap and effective compression ratio to provide suitable HCCI conditions. The effect of mixture formation on auto-ignition was also investigated using a direct injection engine. As a result, HCCI combustion was achieved with a relatively low compression ratio when the intake air was heated by internal EGR. The resulting combustion was at a high thermal efficiency, comparable to that of modern diesel engines, and produced almost no NOx emissions or smoke. The mixture stratification increased the local A/F concentration, resulting in higher reactivity. A wide range of combustible A/F ratios was used to control the compression ignition timing. Photographs showed that the flame filled the entire chamber during combustion, reducing both emissions and fuel consumption.

  15. Modeling of scalar dissipation rates in flamelet models for low temperature combustion engine simulations

    CERN Document Server

    Gupta, Saurabh; Pal, Pinaki; Im, Hong G


    The flamelet approach offers a viable framework for combustion modeling of homogeneous charge compression ignition (HCCI) engines under stratified mixture conditions. Scalar dissipation rate acts as a key parameter in flamelet-based combustion models which connects the physical mixing space to the reactive space. The aim of this paper is to gain fundamental insights into turbulent mixing in low temperature combustion (LTC) engines and investigate the modeling of scalar dissipation rate. Three direct numerical simulation (DNS) test cases of two-dimensional turbulent auto-ignition of a hydrogen-air mixture with different correlations of temperature and mixture fraction are considered, which are representative of different ignition regimes. The existing models of mean and conditional scalar dissipation rates, and probability density functions (PDFs) of mixture fraction and total enthalpy are a priori validated against the DNS data.

  16. Simulation Analysis of Combustion Parameters and Emission Characteristics of CNG Fueled HCCI Engine

    Directory of Open Access Journals (Sweden)

    P. M. Diaz


    Full Text Available The naturally aspirated compressed natural gas (CNG fueled homogeneous charge compression ignition (HCCI engine operation region is narrow between heavy knock at rich air-fuel mixture side and misfire at the lean air-fuel mixture side. However, high activation energy is needed to attain autoignition temperature of CNG fueled HCCI engine. This paper seeks to provide guidance in overcoming challenges of CNG fueled HCCI engine by using CHEMKIN. It is used to investigate the fundamental characteristics of the homogeneous charge compression ignition combustion process for different air-fuel mixture inlet temperature, relative air-fuel ratio of 2.5, and with hemispherical bowl types of combustion chambers. The variation of various properties like the peak cylinder pressure, peak cylinder temperature, CO emission, NO emission, soot emission, and HC emission are studied. It is necessary to develop new combustion models to simulate and predict all parameters with high accuracy.

  17. Optimization of a Reduced Chemical Kinetic Model for HCCI Engine Simulations by Micro-Genetic Algorithm

    Institute of Scientific and Technical Information of China (English)


    A reduced chemical kinetic model (44 species and 72 reactions) for the homogeneous charge compression ignition (HCCI) combustion of n-heptane was optimized to improve its autoignition predictions under different engine operating conditions. The seven kinetic parameters of the optimized model were determined by using the combination of a micro-genetic algorithm optimization methodology and the SENKIN program of CHEMKIN chemical kinetics software package. The optimization was performed within the range of equivalence ratios 0.2-1.2, initial temperature 310-375 K and initial pressure 0.1-0.3 MPa. The engine simulations show that the optimized model agrees better with the detailed chemical kinetic model (544 species and 2 446 reactions) than the original model does.

  18. Effects of Direct Fuel Injection Strategies on Cycle-by-Cycle Variability in a Gasoline Homogeneous Charge Compression Ignition Engine: Sample Entropy Analysis

    Directory of Open Access Journals (Sweden)

    Jacek Hunicz


    Full Text Available In this study we summarize and analyze experimental observations of cyclic variability in homogeneous charge compression ignition (HCCI combustion in a single-cylinder gasoline engine. The engine was configured with negative valve overlap (NVO to trap residual gases from prior cycles and thus enable auto-ignition in successive cycles. Correlations were developed between different fuel injection strategies and cycle average combustion and work output profiles. Hypothesized physical mechanisms based on these correlations were then compared with trends in cycle-by-cycle predictability as revealed by sample entropy. The results of these comparisons help to clarify how fuel injection strategy can interact with prior cycle effects to affect combustion stability and so contribute to design control methods for HCCI engines.

  19. Development and Validation of a Reduced DME Mechanism Applicable to Various Combustion Modes in Internal Combustion Engines

    Directory of Open Access Journals (Sweden)

    Gregory T. Chin


    Full Text Available A 28-species reduced chemistry mechanism for Dimethyl Ether (DME combustion is developed on the basis of a recent detailed mechanism by Zhao et al. (2008. The construction of reduced chemistry was carried out with automatic algorithms incorporating newly developed strategies. The performance of the reduced mechanism is assessed over a wide range of combustion conditions anticipated to occur in future advanced piston internal combustion engines, such as HCCI, SAHCCI, and PCCI. Overall, the reduced chemistry gives results in good agreement with those from the detailed mechanism for all the combustion modes tested. While the detailed mechanism by Zhao et al. (2008 shows reasonable agreement with the shock tube autoignition delay data, the detailed mechanism requires further improvement in order to better predict HCCI combustion under engine conditions.

  20. Ideal Thermodynamic Cycle Analysis for the Meletis-Georgiou Vane Rotary Engine Concept

    Directory of Open Access Journals (Sweden)

    Demos P. Georgiou


    Full Text Available The Meletis-Georgiou is a patented Vane Rotary Engine concept that incorporates separate compression-expansion chambers and a modified Otto (or Miller cycle, characterized by (Exhaust Gas Recirculation at elevated pressures. This is implemented by transferring part of the expansion chamber volume into the compression one through the coordinated action of two vane diaphragms. This results into a very high gas temperature at the end of the compression, something that permits autoignition under all conditions for a Homogeneous Compression Ignition (HCCI version of the engine. The relevant parametric analysis of the ideal cycle shows that the new cycle gives ideal thermal efficiencies of the order of 60% to 70% under conditions corresponding to homogeneous compression engines but at reduced pressures when compared against the corresponding Miller cycle.

  1. A study of structural, optical and dielectric properties of crystalline Sr2Nb2O7 nanoparticles synthesized by a modified combustion technique (United States)

    Mathai, K. C.; Vidya, S.; Solomon, Sam; Thomas, J. K.


    Nanocrystalline Strontium Pyroniobate is synthesized by a novel auto-igniting combustion technique. The X-Ray diffraction studies reveal that Strontium Niobate possesses orthorhombic structure. Phase purity and structure of the nanopowder is further examined using Fourier-Transform Infrared and Raman spectroscopy. The average particle size of the as prepared nanoparticles from the Transmission Electron Microscopy is 30 nm. Sr2Nb2O7 is a photoluminescent material and the optical band gap determined from the UV-DRS spectrum is 2.7eV. The sample is sintered at an optimized temperature of 1350°C for 2 hours and obtained maximum density. The dielectric constant and loss factor values obtained at 5MHz for a well-sintered Strontium Niobate pellet is found to be 40 and 3.9×10-3 respectively, at room temperature.

  2. Biferroic LuCrO{sub 3}: Structural characterization, magnetic and dielectric properties

    Energy Technology Data Exchange (ETDEWEB)

    Durán, A., E-mail: [Universidad Nacional Autónoma de México, Centro de Nanociencias y Nanotecnología, Km. 107 Carretera Tijuana-Ensenada, Apartado Postal 14, C.P. 22800 Ensenada, BC (Mexico); Meza F, C.; Morán, E.; Alario-Franco, M.A. [Departamento de Química Inorgánica y Laboratorio Complutense de Altas Presiones, Facultad de Química, Universidad Complutense de Madrid, EU, 28040 Madrid (Spain); Ostos, C., E-mail: [Instituto de Química, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia)


    Multiferroic LuCrO{sub 3} perovskite-type structure (Pbnm) obtained via auto-ignition synthesis was characterized by a combination of X-ray diffraction (XRD) and thermogravimetric (TG) techniques, and through magnetization and permittivity measurements. Results showed that amorphous combustion powders were fully transformed to orthorhombic LuCrO{sub 3} structure at 1200 K after the first LuCrO{sub 4} crystallization at 700 K. The magnetic response displays thermal irreversibility between zero-field-cooling and field-cooling condition which is due to spin canted AF switching at 116 K. Accordingly, a hysteresis loop in the M(H) data confirms weak ferromagnetism in LuCrO{sub 3}. On the other hand, the permittivity measurement shows a broad peak transition typical of relaxor-type ferroelectrics transition at ∼450 K. Electrical conductivity increases as temperature increases showing an anomaly around the diffuse phase transition. The diffuse phase transition and the formation of the charge carriers are discussed in terms of a local distortion around the Lu Site. - Highlights: • Multiferroic LuCrO{sub 3} was successfully obtained via auto-ignition synthesis. • Amorphous powder is transformed first to LuCrO{sub 4} (700 K) and next to LuCrO{sub 3} (1100 K). • The CrO{sub 6} octahedra are tilted away and rotates from the ideal octahedral shape. • LuCrO{sub 3} exhibits a canted AFM transition (116 K) and a relaxor ferroelectric behavior. • Tilting and rotation of CrO{sub 6} octahedra influenced transport properties on LuCrO{sub 3}.

  3. Combustion in Homogeneous Charge Compression Ignition Engines: Experiments and Detailed Chemical Kinetic Simulations

    Energy Technology Data Exchange (ETDEWEB)

    Flowers, D L


    Homogeneous charge compression ignition (HCCI) engines are being considered as an alternative to diesel engines. The HCCI concept involves premixing fuel and air prior to induction into the cylinder (as is done in current spark-ignition engine) then igniting the fuel-air mixture through the compression process (as is done in current diesel engines). The combustion occurring in an HCCI engine is fundamentally different from a spark-ignition or Diesel engine in that the heat release occurs as a global autoignition process, as opposed to the turbulent flame propagation or mixing controlled combustion used in current engines. The advantage of this global autoignition is that the temperatures within the cylinder are uniformly low, yielding very low emissions of oxides of nitrogen (NO{sub x}, the chief precursors to photochemical smog). The inherent features of HCCI combustion allows for design of engines with efficiency comparable to, or potentially higher than, diesel engines. While HCCI engines have great potential, several technical barriers exist which currently prevent widespread commercialization of this technology. The most significant challenge is that the combustion timing cannot be controlled by typical in-cylinder means. Means of controlling combustion have been demonstrated, but a robust control methodology that is applicable to the entire range of operation has yet to be developed. This research focuses on understanding basic characteristics of controlling and operating HCCI engines. Experiments and detailed chemical kinetic simulations have been applied to the characterize some of the fundamental operational and design characteristics of HCCI engines. Experiments have been conducted on single and multi-cylinder engines to investigate general features of how combustion timing affects the performance and emissions of HCCI engines. Single-zone modeling has been used to characterize and compare the implementation of different control strategies. Multi

  4. A PDF Simulation of the Lifted Turbulent H2/N2 Jet Flame%抬举湍流H2/N2射流火焰的PDF模拟

    Institute of Scientific and Technical Information of China (English)

    王海峰; 陈义良


    A lifted turbulent H2/N2 jet flame in a hot and vitiated coflow is investigated numerically to explore the issues of autoignition as well as the flame lift-off. The composition probability density function (PDF) method is employed to facilitate the implementation of detailed chemical kinetics. A multiple-time-scale κ-ε turbulence model is combined for the calculation of flow and turbulence fields. Detailed chemical reaction mechanisms of hydrogen oxidation are incorporated in the calculation. The predictions are compared with experimental data. The flame lift-off height and auto-ignition process are reproduced accurately by the model.%采用数值方法研究了一个高温燃烧产物环境中的抬举湍流H2/N2射流火焰,对火焰的自然和抬举特性进行了研究.采用标量联合概率密度函数(PDF)方法处理详细的化学动力学过程,而湍流流场采用一个多时间尺度(MTS)κ-ε湍流模型计算.计算中结合了一套描述氢气氧化的详细化学反应动力学机理.计算结果和实验数据进行了对比,表明所采用的模型可以精确的模拟火焰抬举高度和自然的过程.

  5. Construction and validation of detailed kinetic models for the combustion of gasoline surrogates; Construction et validation de modeles cinetiques detailles pour la combustion de melanges modeles des essences

    Energy Technology Data Exchange (ETDEWEB)

    Touchard, S.


    The irreversible reduction of oil resources, the CO{sub 2} emission control and the application of increasingly strict standards of pollutants emission lead the worldwide researchers to work to reduce the pollutants formation and to improve the engine yields, especially by using homogenous charge combustion of lean mixtures. The numerical simulation of fuel blends oxidation is an essential tool to study the influence of fuel formulation and motor conditions on auto-ignition and on pollutants emissions. The automatic generation helps to obtain detailed kinetic models, especially at low temperature, where the number of reactions quickly exceeds thousand. The main purpose of this study is the generation and the validation of detailed kinetic models for the oxidation of gasoline blends using the EXGAS software. This work has implied an improvement of computation rules for thermodynamic and kinetic data, those were validated by numerical simulation using CHEMKIN II softwares. A large part of this work has concerned the understanding of the low temperature oxidation chemistry of the C5 and larger alkenes. Low and high temperature mechanisms were proposed and validated for 1 pentene, 1-hexene, the binary mixtures containing 1 hexene/iso octane, 1 hexene/toluene, iso octane/toluene and the ternary mixture of 1 hexene/toluene/iso octane. Simulations were also done for propene, 1-butene and iso-octane with former models including the modifications proposed in this PhD work. If the generated models allowed us to simulate with a good agreement the auto-ignition delays of the studied molecules and blends, some uncertainties still remains for some reaction paths leading to the formation of cyclic products in the case of alkenes oxidation at low temperature. It would be also interesting to carry on this work for combustion models of gasoline blends at low temperature. (author)

  6. Fuel Flexible, Low Emission Catalytic Combustor for Opportunity Fuel Applications

    Energy Technology Data Exchange (ETDEWEB)

    Eteman, Shahrokh


    Limited fuel resources, increasing energy demand and stringent emission regulations are drivers to evaluate process off-gases or process waste streams as fuels for power generation. Often these process waste streams have low energy content and/or highly reactive components. Operability of low energy content fuels in gas turbines leads to issues such as unstable and incomplete combustion. On the other hand, fuels containing higher-order hydrocarbons lead to flashback and auto-ignition issues. Due to above reasons, these fuels cannot be used directly without modifications or efficiency penalties in gas turbine engines. To enable the use of these wide variety of fuels in gas turbine engines a rich catalytic lean burn (RCL®) combustion system was developed and tested in a subscale high pressure (10 atm.) rig. The RCL® injector provided stability and extended turndown to low Btu fuels due to catalytic pre-reaction. Previous work has shown promise with fuels such as blast furnace gas (BFG) with LHV of 85 Btu/ft3 successfully combusted. This program extends on this work by further modifying the combustor to achieve greater catalytic stability enhancement. Fuels containing low energy content such as weak natural gas with a Lower Heating Value (LHV) of 6.5 MJ/m3 (180 Btu/ft3 to natural gas fuels containing higher hydrocarbon (e.g ethane) with LHV of 37.6 MJ/m3 (1010 Btu/ft3) were demonstrated with improved combustion stability; an extended turndown (defined as the difference between catalytic and non-catalytic lean blow out) of greater than 250oF was achieved with CO and NOx emissions lower than 5 ppm corrected to 15% O2. In addition, for highly reactive fuels the catalytic region preferentially pre-reacted the higher order hydrocarbons with no events of flashback or auto-ignition allowing a stable and safe operation with low NOx and CO emissions.

  7. N型CaMnO3热电材料的制备及性能研究%Preparation and Properties of N-type CaMnO3 Thermoelectric Materials

    Institute of Scientific and Technical Information of China (English)



    该文通过实验研究了采用自燃法并在不同的温度下煅烧试样合成 Ca1-xSmxMnO3(x=0~0.06)粉末的工艺,以及在Ca位上掺杂不同含量的 Sm元素对材料性能的影响。自燃法结合球磨工艺可以制得平均粒径在2μm左右的Ca1-xSmxMnO3(x=0~0.06)超细粉末。X射线衍射(XRD)分析表明自燃法可以合成物相单一的 Ca1-xSmx MnO3(x=0~0.06)粉末材料。在CaMnO3热电材料的Ca位上掺杂 Sm 元素降低了材料的 Seebeck 系数,但同时也降低了材料的电阻率,而电导率增加幅度高于 Seebeck系数的降低幅度,故而总体上Ca1-xSmxMnO3(x=0~0.06)热电陶瓷材料的功率因子也增大了,从而有望使材料达到较高的热电优值,具有一定的商业应用价值。%In this paper,thermoelectric oxide Ca1-xSmxMnO3 (x=0~0.06)powder was synthesized by auto-igni-tion and the reaction temperature of the CaMnO3 synthesis process were investigated.We also studied the thermoelec-tric performance depending on different content of Sm element into Ca site.The Ca1-xSmxMnO3 (x=0~0.06)ultra fine powder with mean particle size of about 2μm has been successfully synthesized by auto-ignition combining with the ball mill process.X-ray diffraction showed that Ca1-xSmxMnO3 has formed by auto-ignition without distinguished im-purity.The Ca-site of CaMnO3 doped with Sm reduced the Seebeck coefficient and at the same time,the electrical con-ductivity was significantly improved and the power factor of Ca1-xSmxMnO3 TE materials was increased.Therefore, the TE merit of Ca1-xSmxMnO3 may come to a high level and have some commercial applications.

  8. An Investigation of Compressed Natural Gas Engine for Nitrogen Oxides Reduction

    Directory of Open Access Journals (Sweden)

    P. M. Diaz


    Full Text Available Problem statement: This study describes the use of Reformer Gas (RG to alter NOx emission in a CNG-fueled HCCI engine. Comparison with diesel, natural gas has a very high octane number (≈120 and high auto-ignition temperature (≈600°C. Composed mostly of methane, natural gas is the only common fuel to manifest relatively pure, single-stage combustion. Other fuels have stronger low-temperature reaction and the required entropy for main stage combustion can be obtained from the low temperature heat release as a result of compression to moderate pressure and temperature. In deviation, the methane molecule resists destruction by free radicals and produces negligible heat release at low temperature. In consequences, in CNG-fueled HCCI engines the activation energy required for auto-ignition must be obtained by extreme levels of charge heating and compression. This causes inherently to a high rate of heat release. HCCI operation with pure CNG fuel was attained but not really practical due to very high NOx production. While HCCI operation is usually described as a low NOx technique, the knocking behavior when running with pure CNG raised the peak combustion temperature to a value well above normal combustion and the critical Zeldovich NOx production threshold, giving very high indicated NOx emissions. Approach: One approach to improving these properties is to convert part of the base CNG fuel to Reformer Gas (RG. In this study, modified COMET engine was operated in HCCI mode using a mixture of CNG fuel and simulated RG (75% H2 and 25% CO can be produced on-board from CNG using low current and non-thermal plasma boosted fuel converter. Results: This study shows that despite of having various RG mass fractions, λ was the dominant factor in reducing NOx production and increasing RG mass fraction had only a small effect on increasing NOx. This disconnect between the overall equivalence ratio and RG fraction shows that the real benefit of the

  9. Natural Gas for Advanced Dual-Fuel Combustion Strategies (United States)

    Walker, Nicholas Ryan

    Natural gas fuels represent the next evolution of low-carbon energy feedstocks powering human activity worldwide. The internal combustion engine, the energy conversion device widely used by society for more than one century, is capable of utilizing advanced combustion strategies in pursuit of ultra-high efficiency and ultra-low emissions. Yet many emerging advanced combustion strategies depend upon traditional petroleum-based fuels for their operation. In this research the use of natural gas, namely methane, is applied to both conventional and advanced dual-fuel combustion strategies. In the first part of this work both computational and experimental studies are undertaken to examine the viability of utilizing methane as the premixed low reactivity fuel in reactivity controlled compression ignition, a leading advanced dual-fuel combustion strategy. As a result, methane is shown to be capable of significantly extending the load limits for dual-fuel reactivity controlled compression ignition in both light- and heavy-duty engines. In the second part of this work heavy-duty single-cylinder engine experiments are performed to research the performance of both conventional dual-fuel (diesel pilot ignition) and advanced dual-fuel (reactivity controlled compression ignition) combustion strategies using methane as the premixed low reactivity fuel. Both strategies are strongly influenced by equivalence ratio; diesel pilot ignition offers best performance at higher equivalence ratios and higher premixed methane ratios, whereas reactivity controlled compression ignition offers superior performance at lower equivalence ratios and lower premixed methane ratios. In the third part of this work experiments are performed in order to determine the dominant mode of heat release for both dual-fuel combustion strategies. By studying the dual-fuel homogeneous charge compression ignition and single-fuel spark ignition, strategies representative of autoignition and flame propagation

  10. Transient flow characteristics of a high speed rotary valve (United States)

    Browning, Patrick H.

    Pressing economic and environmental concerns related to the performance of fossil fuel burning internal combustion engines have revitalized research in more efficient, cleaner burning combustion methods such as homogeneous charge compression ignition (HCCI). Although many variations of such engines now exist, several limiting factors have restrained the full potential of HCCI. A new method patented by West Virginia University (WVU) called Compression Ignition by Air Injection (CIBAI) may help broaden the range of effective HCCI operation. The CIBAI process is ideally facilitated by operating two synchronized piston-cylinders mounted head-to-head with one of the cylinders filled with a homogeneous mixture of air and fuel and the other cylinder filled with air. A specialized valve called the cylinder connecting valve (CCV) separates the two cylinders, opens just before reaching top dead center (TDC), and allows the injection air into the charge to achieve autoignition. The CCV remains open during the entire power stroke such that upon ignition the rapid pressure rise in the charge cylinder forces mass flow back through the CCV into the air-only cylinder. The limited mass transfer between the cylinders through the CCV limits the theoretical auto ignition timing capabilities and thermal efficiency of the CIBAI cycle. Research has been performed to: (1) Experimentally measure the transient behavior of a potential CCV design during valve opening between two chambers maintained at constant pressure and again at constant volume; (2) Develop a modified theoretical CCV mass flow model based upon the measured cold flow valve performance that is capable of predicting the operating conditions required for successful mixture autoignition; (3) Make recommendations for future CCV designs to maximize CIBAI combustion range. Results indicate that the modified-ball CCV design offers suitable transient flow qualities required for application to the CIBAI concept. Mass injection events

  11. DNS of a turbulent, self-igniting n-dodecane / air jet (United States)

    Borghesi, Giulio; Chen, Jacqueline


    A direct numerical simulation of a turbulent, self-igniting temporal jet between n-dodecane and diluted air at p =25 bar has been conducted to clarify certain aspects of diesel engine combustion. The thermodynamics conditions were selected to result in a two-stage ignition event, in which low- and high-temperature chemical reactions play an equally important role during the ignition process. Jet parameters were tuned to yield a target ignition Damkohler number of 0.4, a value representative of conditions found in diesel spray flames. Chemical reactions were described by a 35-species reduced mechanism, including both the low- and high-temperature reaction pathways of n-dodecane. The present work focuses on the influence of low-temperature chemistry on the overall ignition transient. We also study the structure of the flames formed at the end of the autoignition transient. Recent studies on diluted dimethyl ether / air flames at pressure and temperature conditions similar to those investigated in this work revealed the existence of tetra- and penta-brachial flames, and it is of interest to determine whether similar flame structures also exist when diesel-like fuels are used.

  12. Vehicle driving cycle performance of the spark-less di-ji hydrogen engine

    Energy Technology Data Exchange (ETDEWEB)

    Boretti, Alberto A. [School of Science and Engineering, University of Ballarat, PO Box663, Ballarat, VIC 3353 (Australia)


    The paper describes coupled CFD combustion simulations and CAE engine performance computations to describe the operation over the full range of load and speed of an always lean burn, Direct Injection Jet Ignition (DI-JI) hydrogen engine. Jet ignition pre-chambers and direct injection are enablers of high efficiencies and load control by quantity of fuel injected. Towards the end of the compression stroke, a small quantity of hydrogen is injected within the spark-less pre-chamber of the DI-JI engine, where it mixes with the air entering from the main chamber and auto-ignites because of the high temperature of the hot glow plug. Then, jets of partially combusted hot gases enter the main chamber igniting there in the bulk, over multiple ignition points, lean stratified mixtures of air and fuel. Engine maps of brake specific fuel consumption vs. speed and brake mean effective pressure are computed first. CAE vehicle simulations are finally performed evaluating the fuel consumption over emission cycles of a vehicle equipped with this engine. (author)

  13. Detailed thermodynamic analyses of high-speed compressible turbulence (United States)

    Towery, Colin; Darragh, Ryan; Poludnenko, Alexei; Hamlington, Peter


    Interactions between high-speed turbulence and flames (or chemical reactions) are important in the dynamics and description of many different combustion phenomena, including autoignition and deflagration-to-detonation transition. The probability of these phenomena to occur depends on the magnitude and spectral content of turbulence fluctuations, which can impact a wide range of science and engineering problems, from the hypersonic scramjet engine to the onset of Type Ia supernovae. In this talk, we present results from new direct numerical simulations (DNS) of homogeneous isotropic turbulence with turbulence Mach numbers ranging from 0 . 05 to 1 . 0 and Taylor-scale Reynolds numbers as high as 700. A set of detailed analyses are described in both Eulerian and Lagrangian reference frames in order to assess coherent (structural) and incoherent (stochastic) thermodynamic flow features. These analyses provide direct insights into the thermodynamics of strongly compressible turbulence. Furthermore, presented results provide a non-reacting baseline for future studies of turbulence-chemistry interactions in DNS with complex chemistry mechanisms. This work was supported by the Air Force Office of Scientific Research (AFOSR) under Award No. FA9550-14-1-0273, and the Department of Defense (DoD) High Performance Computing Modernization Program (HPCMP) under a Frontier project award.

  14. Numerical investigation of CAI Combustion in the Opposed- Piston Engine with Direct and Indirect Water Injection (United States)

    Pyszczek, R.; Mazuro, P.; Teodorczyk, A.


    This paper is focused on the CAI combustion control in a turbocharged 2-stroke Opposed-Piston (OP) engine. The barrel type OP engine arrangement is of particular interest for the authors because of its robust design, high mechanical efficiency and relatively easy incorporation of a Variable Compression Ratio (VCR). The other advantage of such design is that combustion chamber is formed between two moving pistons - there is no additional cylinder head to be cooled which directly results in an increased thermal efficiency. Furthermore, engine operation in a Controlled Auto-Ignition (CAI) mode at high compression ratios (CR) raises a possibility of reaching even higher efficiencies and very low emissions. In order to control CAI combustion such measures as VCR and water injection were considered for indirect ignition timing control. Numerical simulations of the scavenging and combustion processes were performed with the 3D CFD multipurpose AVL Fire solver. Numerous cases were calculated with different engine compression ratios and different amounts of directly and indirectly injected water. The influence of the VCR and water injection on the ignition timing and engine performance was determined and their application in the real engine was discussed.

  15. Final Report - Low Temperature Combustion Chemistry And Fuel Component Interactions

    Energy Technology Data Exchange (ETDEWEB)

    Wooldridge, Margaret [Univ. of Michigan, Ann Arbor, MI (United States)


    Recent research into combustion chemistry has shown that reactions at “low temperatures” (700 – 1100 K) have a dramatic influence on ignition and combustion of fuels in virtually every practical combustion system. A powerful class of laboratory-scale experimental facilities that can focus on fuel chemistry in this temperature range is the rapid compression facility (RCF), which has proven to be a versatile tool to examine the details of fuel chemistry in this important regime. An RCF was used in this project to advance our understanding of low temperature chemistry of important fuel compounds. We show how factors including fuel molecular structure, the presence of unsaturated C=C bonds, and the presence of alkyl ester groups influence fuel auto-ignition and produce variable amounts of negative temperature coefficient behavior of fuel ignition. We report new discoveries of synergistic ignition interactions between alkane and alcohol fuels, with both experimental and kinetic modeling studies of these complex interactions. The results of this project quantify the effects of molecular structure on combustion chemistry including carbon bond saturation, through low temperature experimental studies of esters, alkanes, alkenes, and alcohols.

  16. Analysis of advanced biofuels.

    Energy Technology Data Exchange (ETDEWEB)

    Dec, John E.; Taatjes, Craig A.; Welz, Oliver; Yang, Yi


    Long chain alcohols possess major advantages over ethanol as bio-components for gasoline, including higher energy content, better engine compatibility, and less water solubility. Rapid developments in biofuel technology have made it possible to produce C{sub 4}-C{sub 5} alcohols efficiently. These higher alcohols could significantly expand the biofuel content and potentially replace ethanol in future gasoline mixtures. This study characterizes some fundamental properties of a C{sub 5} alcohol, isopentanol, as a fuel for homogeneous-charge compression-ignition (HCCI) engines. Wide ranges of engine speed, intake temperature, intake pressure, and equivalence ratio are investigated. The elementary autoignition reactions of isopentanol is investigated by analyzing product formation from laser-photolytic Cl-initiated isopentanol oxidation. Carbon-carbon bond-scission reactions in the low-temperature oxidation chemistry may provide an explanation for the intermediate-temperature heat release observed in the engine experiments. Overall, the results indicate that isopentanol has a good potential as a HCCI fuel, either in neat form or in blend with gasoline.

  17. Cool Flames in Propane-Oxygen Premixtures at Low and Intermediate Temperatures at Reduced-Gravity (United States)

    Pearlman, Howard; Foster, Michael; Karabacak, Devrez


    The Cool Flame Experiment aims to address the role of diffusive transport on the structure and the stability of gas-phase, non-isothermal, hydrocarbon oxidation reactions, cool flames and auto-ignition fronts in an unstirred, static reactor. These reactions cannot be studied on Earth where natural convection due to self-heating during the course of slow reaction dominates diffusive transport and produces spatio-temporal variations in the thermal and thus species concentration profiles. On Earth, reactions with associated Rayleigh numbers (Ra) less than the critical Ra for onset of convection (Ra(sub cr) approx. 600) cannot be achieved in laboratory-scale vessels for conditions representative of nearly all low-temperature reactions. In fact, the Ra at 1g ranges from 10(exp 4) - 10(exp 5) (or larger), while at reduced-gravity, these values can be reduced two to six orders of magnitude (below Ra(sub cr)), depending on the reduced-gravity test facility. Currently, laboratory (1g) and NASA s KC-135 reduced-gravity (g) aircraft studies are being conducted in parallel with the development of a detailed chemical kinetic model that includes thermal and species diffusion. Select experiments have also been conducted at partial gravity (Martian, 0.3gearth) aboard the KC-135 aircraft. This paper discusses these preliminary results for propane-oxygen premixtures in the low to intermediate temperature range (310- 350 C) at reduced-gravity.

  18. Cool flames at terrestrial, partial, and near-zero gravity

    Energy Technology Data Exchange (ETDEWEB)

    Foster, Michael; Pearlman, Howard [Department of Mechanical Engineering and Mechanics, Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104 (United States)


    Natural convection plays an important role in all terrestrial, Lunar, and Martian-based, unstirred, static reactor cool flame and low-temperature autoignitions, since the Rayleigh number (Ra) associated with the self-heating of the reaction exceeds the critical Ra (approximately 600) for onset of convection. At near-zero gravity, Ra<600 can be achieved and the effects of convection suppressed. To systematically vary the Ra without varying the mixture stoichiometry, reactor pressure, or vessel size, cool flames are studied experimentally in a closed, unstirred, static reactor subject to different gravitational accelerations (terrestrial, 1g; Martian, 0.38g; Lunar, 0.16g; and reduced gravity, {approx}10{sup -2}g). Representative results show the evolution of the visible light emission using an equimolar n-butane:oxygen premixture at temperatures ranging from 320 to 350? deg C (593-623 K) at subatmospheric pressures. For representative reduced-gravity, spherically propagating cool flames, the flame radius based on the peak light intensity is plotted as a function of time and the flame radius (and speed) is calculated from a polynomial fit to data. A skeletal chemical kinetic Gray-Yang model developed previously for a one-dimensional, reactive-diffusive system by Fairlie and co-workers is extended to a two-dimensional axisymmetric, spherical geometry. The coupled species, energy, and momentum equations are solved numerically and the spatio-temporal variations in the temperature profiles are presented. A qualitative comparison is made with the experimental results. (author)

  19. Experimental cross-correlation nitrogen Q-branch CARS thermometry in a spark ignition engine (United States)

    Lockett, R. D.; Ball, D.; Robertson, G. N.


    A purely experimental technique was employed to derive temperatures from nitrogen Q-branch Coherent Anti-Stokes Raman Scattering (CARS) spectra, obtained in a high pressure, high temperature environment (spark ignition Otto engine). This was in order to obviate any errors arising from deficiencies in the spectral scaling laws which are commonly used to represent nitrogen Q-branch CARS spectra at high pressure. The spectra obtained in the engine were compared with spectra obtained in a calibrated high pressure, high temperature cell, using direct cross-correlation in place of the minimisation of sums of squares of residuals. The technique is demonstrated through the measurement of air temperature as a function of crankshaft angle inside the cylinder of a motored single-cylinder Ricardo E6 research engine, followed by the measurement of fuel-air mixture temperatures obtained during the compression stroke in a knocking Ricardo E6 engine. A standard CARS programme (SANDIA's CARSFIT) was employed to calibrate the altered non-resonant background contribution to the CARS spectra that was caused by the alteration to the mole fraction of nitrogen in the unburned fuel-air mixture. The compression temperature profiles were extrapolated in order to predict the auto-ignition temperatures.

  20. Manufacture of intelligent oven for roasting jinhua crisp cake%金华酥饼智能烤炉的研制

    Institute of Scientific and Technical Information of China (English)



    Aiming at the problem that operating and roasting of jinhua crisp cake could not reach automation, and the crisp, fra-grant, fragile degree of the finished product could not attain the level that the traditional charcoal stove roasts, the system of an intelligent controlled oven was intrduced first. Adopting the temperature sensor, autoignition system, microcontroller technology and the craft database of roasting Jinhua crisp cake, the cleaning problem of the traditional properties food produces was solved.The research results indicate that it lay the foundations of optimizing the crisp cakes oven.%针对目前金华酥饼烤制无法实现自动化,并且成品的酥、香、脆程度不能接近传统炭炉烤制水平的问题,首先介绍了金华酥饼烤炉智能控制系统的组成及其实现方法;然后采用温度传感器、自动点火系统、单片机控制技术以及金华酥饼烤制工艺数据库.解决了传统风味食品的洁净化生产问题.研究结果表明,该研究为进一步优化酥饼烤炉奠定了基础.

  1. Do sealless pumps belong in hydrocarbon processing services?

    Energy Technology Data Exchange (ETDEWEB)

    Bennett, Shawn L. [Sundyne Corporation, Arvada, CO (Brazil)


    Sealless pump technology seems unimaginable in the hot, dirty and high-pressure world of hydrocarbon processing. Furthermore the high flow rates typical of the industry seem incompatible with sealless pumps. Seals and their environmental controls used in conventional technologies are not immune from these factors making sealless worth another look. In October 2000 the Sealless Centrifugal Pump Specification API 685 was published. This specification lends sealless pumps credibility and emphasizes the proper application of the technology. In many process units seal leaks can be extremely dangerous and costly. The heavy hydrocarbons can auto-ignite and light hydrocarbons will tend to find a source of ignition. The ever-increasing requirements for clean fuels are driving many of the current refinery upgrades. Best Also available control technology requirements and additional focus on Environmental Health and Safety increase the attractiveness of sealless technology to mitigate the hazards associated with seal leaks. Sealless has a place in hydrocarbon processing to eliminate seals, provide mechanical simplification, and ensure personnel/environmental protection. The proper application involves evaluating canned motor/magnetic drive technology, API 685 Guidelines, and vapor pressure versus pump circuit pressure analysis. There are four (4) specific processes where sealless pumps should be targeted: Alkylation, Sulfur Recovery/Hydrotreating, Naphtha Reforming Production, and Neutralization. (author)

  2. Dynamic control of a homogeneous charge compression ignition engine (United States)

    Duffy, Kevin P.; Mehresh, Parag; Schuh, David; Kieser, Andrew J.; Hergart, Carl-Anders; Hardy, William L.; Rodman, Anthony; Liechty, Michael P.


    A homogenous charge compression ignition engine is operated by compressing a charge mixture of air, exhaust and fuel in a combustion chamber to an autoignition condition of the fuel. The engine may facilitate a transition from a first combination of speed and load to a second combination of speed and load by changing the charge mixture and compression ratio. This may be accomplished in a consecutive engine cycle by adjusting both a fuel injector control signal and a variable valve control signal away from a nominal variable valve control signal. Thereafter in one or more subsequent engine cycles, more sluggish adjustments are made to at least one of a geometric compression ratio control signal and an exhaust gas recirculation control signal to allow the variable valve control signal to be readjusted back toward its nominal variable valve control signal setting. By readjusting the variable valve control signal back toward its nominal setting, the engine will be ready for another transition to a new combination of engine speed and load.

  3. Annual Report FY2014 Alternative Fuels DISI Engine Research

    Energy Technology Data Exchange (ETDEWEB)

    Sjoberg, Carl-Magnus G. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)


    Due to concerns about future petroleum supply and accelerating climate change, increased engine efficiency and alternative fuels are of interest. This project contributes to the science-base needed by industry to develop highly efficient DISI engines that also beneficially exploit the different properties of alternative fuels. Lean operation is studied since it can provide higher efficiencies than traditional non-dilute stoichiometric operation. Since lean operation can lead to issues with ignition stability, slow flame propagation and low combustion efficiency, focus is on techniques that can overcome these challenges. Specifically, fuel stratification can be used to ensure ignition and completeness of combustion, but may lead to soot and NOx emissions challenges. Advanced ignition system and intake air preheating both promote ignition stability. Controlled end-gas autoignition can be used maintain high combustion efficiency for ultra-lean well-mixed conditions. However, the response of both combustion and exhaust emission to these techniques depends on the fuel properties. Therefore, to achieve optimal fuel-economy gains, the combustion-control strategies of the engine must adopt to the fuel being utilized.

  4. Numerical Studies on Controlling Gaseous Fuel Combustion by Managing the Combustion Process of Diesel Pilot Dose in a Dual-Fuel Engine

    Directory of Open Access Journals (Sweden)

    Mikulski Maciej


    Full Text Available Protection of the environment and counteracting global warming require finding alternative sources of energy. One of the methods of generating energy from environmentally friendly sources is increasing the share of gaseous fuels in the total energy balance. The use of these fuels in compression-ignition (CI engines is difficult due to their relatively high autoignition temperature. One solution for using these fuels in CI engines is operating in a dualfuel mode, where the air and gas mixture is ignited with a liquid fuel dose. In this method, a series of relatively complex chemical processes occur in the engine's combustion chamber, related to the combustion of individual fuel fractions that interact with one another. Analysis of combustion of specific fuels in this type of fuel injection to the engine is difficult due to the fact that combustion of both fuel fractions takes place simultaneously. Simulation experiments can be used to analyse the impact of diesel fuel combustion on gaseous fuel combustion. In this paper, we discuss the results of simulation tests of combustion, based on the proprietary multiphase model of a dual-fuel engine. The results obtained from the simulation allow for analysis of the combustion process of individual fuels separately, which expands the knowledge obtained from experimental tests on the engine.

  5. Numerical and Experimental Investigation of Combustion and Knock in a Dual Fuel Gas/Diesel Compression Ignition Engine

    Directory of Open Access Journals (Sweden)

    A. Gharehghani


    Full Text Available Conventional compression ignition engines can easily be converted to a dual fuel mode of operation using natural gas as main fuel and diesel oil injection as pilot to initiate the combustion. At the same time, it is possible to increase the output power by increasing the diesel oil percentage. A detailed performance and combustion characteristic analysis of a heavy duty diesel engine has been studied in dual fuel mode of operation where natural gas is used as the main fuel and diesel oil as pilot. The influence of intake pressure and temperature on knock occurrence and the effects of initial swirl ratio on heat release rate, temperature-pressure and emission levels have been investigated in this study. It is shown that an increase in the initial swirl ratio lengthens the delay period for auto-ignition and extends the combustion period while it reduces NOx. There is an optimum value of the initial swirl ratio for a certain mixture intake temperature and pressure conditions that can achieve high thermal efficiency and low NOx emissions while decreases the tendency to knock. Simultaneous increase of intake pressure and initial swirl ratio could be the solution to power loss and knock in dual fuel engine.

  6. A criterion based on computational singular perturbation for the construction of reduced mechanism for dimethyl ether oxidation

    Directory of Open Access Journals (Sweden)

    Wu Zuozhu


    Full Text Available A criterion based on the computational singular perturbation (CSP method is proposed in order to determine the number of quasi-steady state (QSS species. This criterion is employed for the reduction of a detailed chemical kinetics mechanism for the oxidation of dimethyl ether (DME, involving 55 species and 290 reactions, leading to a 20 steps reduced mechanism which involves 26 species. A software package, named I-CSP, was developed to make the reduction process algorithmic. Input to the I-CSP includes (i the detailed mechanism, (ii the numerical solution of the problem for a specific set of operating conditions, (iii the number of quasi steady state (QSS species. The resulting reduced mechanism was validated both in homogenous reactor, including auto-ignition and PSR, over a wide range of pressures and equivalence ratios, and in a one-dimensional, unstretched, premixed, laminar steady DME/Air flame. Comparison of the results calculated with the detailed and the reduced mechanisms shows excellent agreement in the case of homogenous reactor, but discrepancies can be observed in the case of the premixed laminar flame.

  7. NASA Tech Briefs, June 2009 (United States)


    Topics covered include: Device for Measuring Low Flow Speed in a Duct, Measuring Thermal Conductivity of a Small Insulation Sample, Alignment Jig for the Precise Measurement of THz Radiation, Autoignition Chamber for Remote Testing of Pyrotechnic Devices, Microwave Power Combiners for Signals of Arbitrary Amplitude, Synthetic Foveal Imaging Technology, Airborne Antenna System for Minimum-Cycle-Slip GPS Reception, Improved Starting Materials for Back-Illuminated Imagers, Multi-Modulator for Bandwidth-Efficient Communication, Some Improvements in Utilization of Flash Memory Devices, GPS/MEMS IMU/Microprocessor Board for Navigation, T/R Multi-Chip MMIC Modules for 150 GHz, Pneumatic Haptic Interfaces, Device Acquires and Retains Rock or Ice Samples, Cryogenic Feedthrough Test Rig, Improved Assembly for Gas Shielding During Welding or Brazing, Two-Step Plasma Process for Cleaning Indium Bonding Bumps, Tool for Crimping Flexible Circuit Leads, Yb14MnSb11 as a High-Efficiency Thermoelectric Material, Polyimide-Foam/Aerogel Composites for Thermal Insulation, Converting CSV Files to RKSML Files, Service Management Database for DSN Equipment, Chemochromic Hydrogen Leak Detectors, Compatibility of Segments of Thermoelectric Generators, Complementary Barrier Infrared Detector, JPL Greenland Moulin Exploration Probe, Ultra-Lightweight Self-Deployable Nanocomposite Structure for Habitat Applications, and Room-Temperature Ionic Liquids for Electrochemical Capacitors.

  8. New Combustion Technology on Homogeneous Charge Compression Ignition%均质压燃在内燃机燃烧技术中的应用

    Institute of Scientific and Technical Information of China (English)

    周晶磊; 夏鸿文; 任超伟


    均质压燃(HCCI)是一种新的燃烧方式,它是预混混合气在压缩过程中温度升高达到自燃温度以后发生的燃烧现象。本文阐述了“均质压燃、低温燃烧”新一代内燃机燃烧技术的背景、研究现状以及所取得的主要研究进展。%With the rapid development of national economy, there are a lot of automobiles in China. The main power devices of automobiles are internal combustion engines, which faces more challenges, such as energy saving and environmental protection. But these challenges are advantageous to improve automo-tive technologies and spur a new generation, energy saving and low emission cars to appear. HCCI (Homo-geneous Charge Compression Ignition) is a new kind of combustion mode, which is the autoignition of pre-mixtures when their temperature is high enough to self-ignition by compression. This combustion can reduce the emission of NOX and particulate matters, in addition, use many fuel, so HCCI has been a research hot spot in internal combustion engine field.This paper focuses on the background, the technical route and the key scientific advances and achievements of new combustion technology on the Homogeneous Charge Compression Ignition (HCCI) .

  9. Experiments on Induction Times of Diesel-Fuels and its Surrogates (United States)

    Eigenbrod, Christian; Reimert, Manfredo; Marks, Guenther; Rickmers, Peter; Klinkov, Konstantin; Moriue, Osamu

    Aiming for as low polluting combustion control as possible in Diesel-engines or gas-turbines, pre-vaporized and pre-mixed combustion at low mean temperature levels marks the goal. Low-est emissions of nitric-oxides are achievable at combustion temperatures associated to mixture ratios close to the lean flammability limit. In order to prevent local mixture ratios to be below the flammability limit (resulting in flame extinction or generation of unburned hydrocarbons and carbon-monoxide) or to be richer than required (resulting in more nitric-oxide than possi-ble), well-stirred conditioning is required. The time needed for spray generation, vaporization and turbulent mixing is limited through the induction time to self-ignition in a hot high-pressure ambiance. Therefore, detailed knowledge about the autoignition of fuels is a pre-requisit. Experiments were performed at the Bremen drop tower to investigate the self-ignition behavior of single droplets of fossil-Diesel oil, rapeseed-oil, Gas-to-Liquid (GTL) synthetic Diesel-oil and the fossil Diesel surrogates n-heptane, n-tetradecane, 50 n-tetradecane/ 50 1-methylnaphthalene as well as on the GTL-surrogates n-tetradecane / bicyclohexyl and n-tetradecane / 2,2,4,4,6,8,8-heptamethylnonane (iso-cetane). The rules for selection of the above fuels and the experimental results are presented and dis-cussed.

  10. Numerical Study of Stratified Charge Combustion in Wave Rotors (United States)

    Nalim, M. Razi


    A wave rotor may be used as a pressure-gain combustor effecting non-steady flow, and intermittent, confined combustion to enhance gas turbine engine performance. It will be more compact and probably lighter than an equivalent pressure-exchange wave rotor, yet will have similar thermodynamic and mechanical characteristics. Because the allowable turbine blade temperature limits overall fuel/air ratio to sub-flammable values, premixed stratification techniques are necessary to burn hydrocarbon fuels in small engines with compressor discharge temperature well below autoignition conditions. One-dimensional, unsteady numerical simulations of stratified-charge combustion are performed using an eddy-diffusivity turbulence model and a simple reaction model incorporating a flammability limit temperature. For good combustion efficiency, a stratification strategy is developed which concentrates fuel at the leading and trailing edges of the inlet port. Rotor and exhaust temperature profiles and performance predictions are presented at three representative operating conditions of the engine: full design load, 40% load, and idle. The results indicate that peak local gas temperatures will result in excessive temperatures within the rotor housing unless additional cooling methods are used. The rotor itself will have acceptable temperatures, but the pattern factor presented to the turbine may be of concern, depending on exhaust duct design and duct-rotor interaction.

  11. Improved Stiff ODE Solvers for Combustion CFD (United States)

    Imren, A.; Haworth, D. C.


    Increasingly large chemical mechanisms are needed to predict autoignition, heat release and pollutant emissions in computational fluid dynamics (CFD) simulations of in-cylinder processes in compression-ignition engines and other applications. Calculation of chemical source terms usually dominates the computational effort, and several strategies have been proposed to reduce the high computational cost associated with realistic chemistry in CFD. Central to most strategies is a stiff ordinary differential equation (ODE) solver to compute the change in composition due to chemical reactions over a computational time step. Most work to date on stiff ODE solvers for computational combustion has focused on backward differential formula (BDF) methods, and has not explicitly considered the implications of how the stiff ODE solver couples with the CFD algorithm. In this work, a fresh look at stiff ODE solvers is taken that includes how the solver is integrated into a turbulent combustion CFD code, and the advantages of extrapolation-based solvers in this regard are demonstrated. Benefits in CPU time and accuracy are demonstrated for homogeneous systems and compression-ignition engines, for chemical mechanisms that range in size from fewer than 50 to more than 7,000 species.

  12. Terascale High-Fidelity Simulations of Turbulent Combustion with Detailed Chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Im, Hong G [University of Michigan; Trouve, Arnaud [University of Maryland; Rutland, Christopher J [University of Wisconsin; Chen, Jacqueline H [Sandia National Laboratories


    The TSTC project is a multi-university collaborative effort to develop a high-fidelity turbulent reacting flow simulation capability utilizing terascale, massively parallel computer technology. The main paradigm of our approach is direct numerical simulation (DNS) featuring highest temporal and spatial accuracy, allowing quantitative observations of the fine-scale physics found in turbulent reacting flows as well as providing a useful tool for development of sub-models needed in device-level simulations. The code named S3D, developed and shared with Chen and coworkers at Sandia National Laboratories, has been enhanced with new numerical algorithms and physical models to provide predictive capabilities for spray dynamics, combustion, and pollutant formation processes in turbulent combustion. Major accomplishments include improved characteristic boundary conditions, fundamental studies of auto-ignition in turbulent stratified reactant mixtures, flame-wall interaction, and turbulent flame extinction by water spray. The overarching scientific issue in our recent investigations is to characterize criticality phenomena (ignition/extinction) in turbulent combustion, thereby developing unified criteria to identify ignition and extinction conditions. The computational development under TSTC has enabled the recent large-scale 3D turbulent combustion simulations conducted at Sandia National Laboratories.

  13. Knock Prediction Using a Simple Model for Ignition Delay

    KAUST Repository

    Kalghatgi, Gautam


    An earlier paper has shown the ability to predict the phasing of knock onset in a gasoline PFI engine using a simple ignition delay equation for an appropriate surrogate fuel made up of toluene and PRF (TPRF). The applicability of this approach is confirmed in this paper in a different engine using five different fuels of differing RON, sensitivity, and composition - including ethanol blends. An Arrhenius type equation with a pressure correction for ignition delay can be found from interpolation of previously published data for any gasoline if its RON and sensitivity are known. Then, if the pressure and temperature in the unburned gas can be estimated or measured, the Livengood-Wu integral can be estimated as a function of crank angle to predict the occurrence of knock. Experiments in a single cylinder DISI engine over a wide operating range confirm that this simple approach can predict knock very accurately. The data presented should enable engineers to study knock or other auto-ignition phenomena e.g. in premixed compression ignition (PCI) engines without explicit chemical kinetic calculations. © Copyright 2016 SAE International.

  14. Measuring hydroperoxide chain-branching agents during n-pentane low-temperature oxidation

    KAUST Repository

    Rodriguez, Anne


    The reactions of chain-branching agents, such as HO and hydroperoxides, have a decisive role in the occurrence of autoignition. The formation of these agents has been investigated in an atmospheric-pressure jet-stirred reactor during the low-temperature oxidation of n-pentane (initial fuel mole fraction of 0.01, residence time of 2s) using three different diagnostics: time-of-flight mass spectrometry combined with tunable synchrotron photoionization, time-of-flight mass spectrometry combined with laser photoionization, and cw-cavity ring-down spectroscopy. These three diagnostics enable a combined analysis of HO, C-C, and C alkylhydroperoxides, C-C alkenylhydroperoxides, and C alkylhydroperoxides including a carbonyl function (ketohydroperoxides). Results using both types of mass spectrometry are compared for the stoichiometric mixture. Formation data are presented at equivalence ratios from 0.5 to 2 for these peroxides and of two oxygenated products, ketene and pentanediones, which are not usually analyzed during jet-stirred reactor oxidation. The formation of alkenylhydroperoxides during alkane oxidation is followed for the first time. A recently developed model of n-pentane oxidation aids discussion of the kinetics of these products and of proposed pathways for C-C alkenylhydroperoxides and the pentanediones.

  15. Fundamental studies of fuel chemistry as related to internal combustion engine phenomena. Technical progress report, July 1, 1988--June 30, 1989

    Energy Technology Data Exchange (ETDEWEB)

    Dryer, F.L.; Brezinsky, K.


    The present research effort was initiated with the intent of providing substantially improved insights (through homogeneous gas phase kinetic studies at different constant pressures) to the fuel chemistry issues important to autoignition in engines. The conditions of the proposed experiments were chosen to represent those similar to the engine parameters under knocking conditions: temperatures in the range of 700--1,100K, pressures from one to approximately 20 atmospheres and stoichiometries around one. A major part of the proposed research has been to design and construct a variable pressure flow reactor facility in which a range of reaction pressures, and in fact, lower reaction temperatures could be accessed. The reactor facility design and construction are nearly complete, and initial testing has begun to compare the overall experimental operating characteristics of the reactor with the design parameters. Experiments on Isobutene/oxygen mixtures have also been conducted in the existing atmospheric pressure flow reactor at about 1,150 K and in an equivalence ratio range of pyrolysis with about 100 ppm oxygen background to 0.42. A detailed kinetic model has been developed to interpret the pyrolysis and oxidation characteristics. 89 refs.

  16. Thermodynamic analysis of fuels in gas phase: ethanol, gasoline and ethanol - gasoline predicted by DFT method. (United States)

    Neto, A F G; Lopes, F S; Carvalho, E V; Huda, M N; Neto, A M J C; Machado, N T


    This paper presents a theoretical study using density functional theory to calculate thermodynamics properties of major molecules compounds at gas phase of fuels like gasoline, ethanol, and gasoline-ethanol mixture in thermal equilibrium on temperature range up to 1500 K. We simulated a composition of gasoline mixture with ethanol for a thorough study of thermal energy, enthalpy, Gibbs free energy, entropy, heat capacity at constant pressure with respect to temperature in order to study the influence caused by ethanol as an additive to gasoline. We used semi-empirical computational methods as well in order to know the efficiency of other methods to simulate fuels through this methodology. In addition, the ethanol influence through the changes in percentage fractions of chemical energy released in combustion reaction and the variations on thermal properties for autoignition temperatures of fuels was analyzed. We verified how ethanol reduces the chemical energy released by gasoline combustion and how at low temperatures the gas phase fuels in thermal equilibrium have similar thermodynamic behavior. Theoretical results were compared with experimental data, when available, and showed agreement. Graphical Abstract Thermodynamic analysis of fuels in gas phase.

  17. Effects of compression and expansion ramp fuel injector configuration on scramjet combustion and heat transfer (United States)

    Stouffer, Scott D.; Baker, N. R.; Capriotti, D. P.; Northam, G. B.


    A scramjet combustor with four wall-ramp injectors containing Mach-1.7 fuel jets in the base of the ramps was investigated experimentally. During the test program, two swept ramp injector designs were evaluated. One swept-ramp model had 10-deg compression-ramps and the other had 10-deg expansion cavities between flush wall ramps. The scramjet combustor model was instrumented with pressure taps and heat-flux gages. The pressure measurements indicated that both injector configurations were effective in promoting mixing and combustion. Autoignition occurred for the compression-ramp injectors, and the fuel began to burn immediately downstream of the injectors. In tests of the expansion ramps, a pilot was required to ignite the fuel, and the fuel did not burn for a distance of at least two gaps downstream of the injectors. Once initiated, combustion was rapid in this configuration. Heat transfer measurements showed that the heat flux differed greatly both across the width of the combustor and along the length of the combustor.

  18. Effect of metal-ion-to-fuel ratio on the phase formation of bioceramic phosphates synthesized by self-propagating combustion

    Directory of Open Access Journals (Sweden)

    Swamiappan Sasikumar and Rajagopalan Vijayaraghavan


    Full Text Available Synthetic calcium hydroxyapatite (HAP, Ca10 (PO46 (OH2 is a well-known bioceramic material used in orthopedic and dental applications because of its excellent biocompatibility and bone-bonding ability due to its structural and compositional similarity to human bone. Here we report, for the first time, the synthesis of HAP by combustion employing tartaric acid as a fuel. Calcium nitrate is used as the source of calcium and diammonium hydrogen phosphate serves as the source of phosphate ions. Reaction processing parameters such as the pH, fuel-oxidant ratio and autoignition temperature are controlled and monitored. The products were characterized by powder x-ray diffraction, which revealed the formation of a hexagonal hydroxyapatite phase. Fourier transform infrared spectroscopy (FT-IR spectra showed that the substitution of a carbonate ion occurs at the phosphate site. The morphology of the particles was imaged by scanning electron microscopy, which also revealed that the particles are of submicron size. Thermal analysis showed that the phase formation takes place at the time of combustion. Surface area and porosity analysis showed that the surface area is high and that the pores are of nanometer size. The mean grain size of the HAP powder, determined by the Debye–Scherrer formula, is in the range 20–30 nm. Chemical analyses to determine the Ca : P atomic ratio in synthesized ceramics were performed, and it was found to be 1 : 1.66.

  19. Large eddy simulation of combustion characteristics in a kerosene fueled rocket-based combined-cycle engine combustor (United States)

    Huang, Zhi-wei; He, Guo-qiang; Qin, Fei; Cao, Dong-gang; Wei, Xiang-geng; Shi, Lei


    This study reports combustion characteristics of a rocket-based combined-cycle engine combustor operating at ramjet mode numerically. Compressible large eddy simulation with liquid kerosene sprayed and vaporized is used to study the intrinsic unsteadiness of combustion in such a propulsion system. Results for the pressure oscillation amplitude and frequency in the combustor as well as the wall pressure distribution along the flow-path, are validated using experimental data, and they show acceptable agreement. Coupled with reduced chemical kinetics of kerosene, results are compared with the simultaneously obtained Reynolds-Averaged Navier-Stokes results, and show significant differences. A flow field analysis is also carried out for further study of the turbulent flame structures. Mixture fraction is used to determine the most probable flame location in the combustor at stoichiometric condition. Spatial distributions of the Takeno flame index, scalar dissipation rate, and heat release rate reveal that different combustion modes, such as premixed and non-premixed modes, coexisted at different sections of the combustor. The RBCC combustor is divided into different regions characterized by their non-uniform features. Flame stabilization mechanism, i.e., flame propagation or fuel auto-ignition, and their relative importance, is also determined at different regions in the combustor.

  20. Analysis of Ignition Behavior in a Turbocharged Direct Injection Dual Fuel Engine Using Propane and Methane as Primary Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Polk, A. C.; Gibson, C. M.; Shoemaker, N. T.; Srinivasan, K. K.; Krishnan, S. R.


    This paper presents experimental analyses of the ignition delay (ID) behavior for diesel-ignited propane and diesel-ignited methane dual fuel combustion. Two sets of experiments were performed at a constant speed (1800 rev/min) using a 4-cylinder direct injection diesel engine with the stock ECU and a wastegated turbocharger. First, the effects of fuel-air equivalence ratios (© pilot ¼ 0.2-0.6 and © overall ¼ 0.2-0.9) on IDs were quantified. Second, the effects of gaseous fuel percent energy substitution (PES) and brake mean effective pressure (BMEP) (from 2.5 to 10 bar) on IDs were investigated. With constant © pilot (> 0.5), increasing © overall with propane initially decreased ID but eventually led to premature propane autoignition; however, the corresponding effects with methane were relatively minor. Cyclic variations in the start of combustion (SOC) increased with increasing © overall (at constant © pilot), more significantly for propane than for methane. With increasing PES at constant BMEP, the ID showed a nonlinear (initially increasing and later decreasing) trend at low BMEPs for propane but a linearly decreasing trend at high BMEPs. For methane, increasing PES only increased IDs at all BMEPs. At low BMEPs, increasing PES led to significantly higher cyclic SOC variations and SOC advancement for both propane and methane. Finally, the engine ignition delay (EID) was also shown to be a useful metric to understand the influence of ID on dual fuel combustion.

  1. Detailed Chemical Kinetic Reaction Mechanisms for Primary Reference Fuels for Diesel Cetane Number and Spark-Ignition Octane Number

    Energy Technology Data Exchange (ETDEWEB)

    Westbrook, C K; Pitz, W J; Mehl, M; Curran, H J


    For the first time, a detailed chemical kinetic reaction mechanism is developed for primary reference fuel mixtures of n-hexadecane and 2,2,4,4,6,8,8-heptamethyl nonane for diesel cetane ratings. The mechanisms are constructed using existing rules for reaction pathways and rate expressions developed previously for the primary reference fuels for gasoline octane ratings, n-heptane and iso-octane. These reaction mechanisms are validated by comparisons between computed and experimental results for shock tube ignition and for oxidation under jet-stirred reactor conditions. The combined kinetic reaction mechanism contains the submechanisms for the primary reference fuels for diesel cetane ratings and submechanisms for the primary reference fuels for gasoline octane ratings, all in one integrated large kinetic reaction mechanism. Representative applications of this mechanism to two test problems are presented, one describing fuel/air autoignition variations with changes in fuel cetane numbers, and the other describing fuel combustion in a jet-stirred reactor environment with the fuel varying from pure 2,2,4,4,6,8,8-heptamethyl nonane (Cetane number of 15) to pure n-hexadecane (Cetane number of 100). The final reaction mechanism for the primary reference fuels for diesel fuel and gasoline is available on the web.

  2. New insights into the low-temperature oxidation of 2-methylhexane

    KAUST Repository

    Wang, Zhandong


    In this work, we studied the low-temperature oxidation of a stoichiometric 2-methylhexane/O2/Ar mixture in a jet-stirred reactor coupled with synchrotron vacuum ultraviolet photoionization molecular-beam mass spectrometry. The initial gas mixture was composed of 2% 2-methyhexane, 22% O2 and 76% Ar and the pressure of the reactor was kept at 780Torr. Low-temperature oxidation intermediates with two to five oxygen atoms were observed. The detection of C7H14O5 and C7H12O4 species suggests that a third O2 addition process occurs in 2-methylhexane low-temperature oxidation. A detailed kinetic model was developed that describes the third O2 addition and subsequent reactions leading to C7H14O5 (keto-dihydroperoxide and dihydroperoxy cyclic ether) and C7H12O4 (diketo-hydroperoxide and keto-hydroperoxy cyclic ether) species. The kinetics of the third O2 addition reactions are discussed and model calculations were performed that reveal that third O2 addition reactions promote 2-methylhexane auto-ignition at low temperatures. © 2016 The Combustion Institute.

  3. Signature of ferro–paraelectric transition in biferroic LuCrO{sub 3} from electron paramagnetic resonance and non-resonant microwave absorption

    Energy Technology Data Exchange (ETDEWEB)

    Alvarez, G., E-mail: [Escuela Superior de Física y Matemáticas del Instituto Politécnico Nacional, U.P.A.L.M, Edificio 9, Av. Instituto Politécnico Nacional S/N, San Pedro Zacatenco, México DF 07738 (Mexico); Montiel, H. [Centro de Ciencias Aplicadas y Desarrollo Tecnológico de la Universidad Nacional Autónoma de México, Cd. Universitaria, A.P. 70-186, México DF 04510 (Mexico); Durán, A. [Centro de Nanociencias y Nanotecnología de la Universidad Nacional Autónoma de México, Km. 107, Carretera Tijuana-Ensenada, Apartado Postal 14, C.P. 22800 Ensenada, B.C. México (Mexico); Conde-Gallardo, A. [Departamento de Física, CINVESTAV-IPN, A.P. 14-740, México DF 07360 (Mexico); Zamorano, R. [Escuela Superior de Física y Matemáticas del Instituto Politécnico Nacional, U.P.A.L.M, Edificio 9, Av. Instituto Politécnico Nacional S/N, San Pedro Zacatenco, México DF 07738 (Mexico)


    An electron paramagnetic resonance (EPR) study in the polycrystalline biferroic LuCrO{sub 3} is carried out at X-band (8.8–9.8 GHz) in the 295–510 K temperature range. For all the temperatures, the EPR spectra show a single broad line attributable to Cr{sup 3+} (S = 3/2) ions. The onset of a ferro–paraelectric transition has been determined from the temperature dependence of the parameters deduced from EPR spectra: the peak-to-peak linewidth (ΔH{sub pp}), the g-factor and the integral intensity (I{sub EPR}). Magnetically modulated microwave absorption spectroscopy (MAMMAS) and low-field microwave absorption (LFMA) are used to give further information on this material, where these techniques give also evidence of the ferro–paraelectric transition; indicating a behavior in agreement with a diffuse phase transition. - Highlights: • LuCrO{sub 3} powders are obtained via auto-ignition synthesis. • EPR is employed to study the onset of the ferro–paraelectric transition. • MAMMAS and LFMA techniques are used to give further information on this material.

  4. Thermal decomposition of selected chlorinated hydrocarbons during gas combustion in fluidized bed

    Directory of Open Access Journals (Sweden)

    Olek Malgorzata


    Full Text Available Abstract Background The process of thermal decomposition of dichloromethane (DCM and chlorobenzene (MCB during the combustion in an inert, bubbling fluidized bed, supported by LPG as auxiliary fuel, have been studied. The concentration profiles of C6H5CI, CH2Cl2, CO2, CO, NOx, COCl2, CHCl3, CH3Cl, C2H2, C6H6, CH4 in the flue gases were specified versus mean bed temperature. Results The role of preheating of gaseous mixture in fluidized bed prior to its ignition inside bubbles was identified as important factor for increase the degree of conversion of DCM and MCB in low bed temperature, in comparison to similar process in the tubular reactor. Conclusions Taking into account possible combustion mechanisms, it was identified that autoignition in bubbles rather than flame propagation between bubbles is needed to achieve complete destruction of DCM and MCB. These condition occurs above 900°C causing the degree of conversion of chlorine compounds of 92-100%.

  5. Consistent Conditional Moment Closure Modelling of a Lifted Turbulent Jet Flame Using the Presumed β-PDF Approach

    Directory of Open Access Journals (Sweden)

    Ahmad El Sayed


    Full Text Available A lifted H2/N2 turbulent jet flame issuing into a vitiated coflow is investigated using the conditional moment closure. The conditional velocity (CV and the conditional scalar dissipation rate (CSDR submodels are chosen such that they are fully consistent with the moments of the presumed β probability density function (PDF. The CV is modelled using the PDF-gradient diffusion model. Two CSDR submodels based on the double integration of the homogeneous and inhomogeneous mixture fraction PDF transport equations are implemented. The effect of CSDR modelling is investigated over a range of coflow temperatures (Tc and the stabilisation mechanism is determined from the analysis of the transport budgets and the history of radical build-up ahead of the stabilisation height. For all Tc, the balance between chemistry, axial convection, and micromixing, and the absence of axial diffusion upstream of the stabilisation height indicate that the flame is stabilized by autoignition. This conclusion is confirmed from the rapid build-up of HO2 ahead of H, O, and OH. The inhomogeneous CSDR modelling yields higher dissipation levels at the most reactive mixture fraction, which results in longer ignition delays and larger liftoff heights. The effect of the spurious sources arising from homogeneous modelling is found to be small but nonnegligible, mostly notably within the flame zone.

  6. Real fuel effects on flame extinction and re-ignition (United States)

    Zhao, Xinyu; Wu, Bifen; Xu, Chao; Lu, Tianfeng; Chen, Jacqueline H.


    Flame-vortex interactions have significant implications in studying combustion in practical aeronautical engines, and can be used to facilitate the model development in capturing local extinction and re-ignition. To study the interactions between the complex fuel and the intense turbulence that are commonly encountered in engines, direct numerical simulations of the interactions between a flame and a vortex pair are carried out using a recently-developed 24-species reduced chemistry for n-dodecane. Both non-premixed and premixed flames with different initial and inlet thermochemical conditions are studied. Parametric studies of different vortex strengths and orientations are carried out to induce maximum local extinction and re-ignition. Chemical-explosive-mode-analysis based flame diagnostic tools are used to identify different modes of combustion, including auto-ignition and extinction. Results obtained from the reduced chemistry are compared with those obtained from one-step chemistry to quantify the effect of fuel pyrolysis on the extinction limit. Effects of flame curvature, heat loss and unsteadiness on flame extinction are also explored. Finally, the validity of current turbulent combustion models to capture the local extinction and re-ignition will be discussed.

  7. Relative Explosive Strength of Some Explosive Mixtures Containing Urea and/or Peroxides

    Institute of Scientific and Technical Information of China (English)

    Ahmed K. HUSSEIN; Svatopluk ZEMAN; Muhamed SUCESKA; Marcela JUNGOVA


    Several mixtures, based on urea derivatives and some inorganic oxidants, including also alumina, were studied by means of ballistic mortar techniques with TNT as the reference standard. The detonation pressure(P), detonation velocity(D), detonation energy(Q), and volume of gaseous product at standard temperature and pressure (STP), V, were calculated using EXPLO5 V6.3 thermochemical code. The performance of the mixtures studied was discussed in relation to their thermal reactivity, determined by means of differential thermal analysis (DTA). It is shown that the presence of hydrogen peroxide in the form of its complex with urea (i.e. as UHP) has a positive influence on the explosive strength of the corresponding mixtures which is linked to the hydroxy-radical formation in the mixtures during their initiation reaction. These radicals might initiate (at least partially) powdered aluminum into oxidation in the CJ plane of the detonation wave. Mixtures containing UHP and magnesium are dangerous because of potential auto-ignition.

  8. Control of the low-load region in partially premixed combustion (United States)

    Ingesson, Gabriel; Yin, Lianhao; Johansson, Rolf; Tunestal, Per


    Partially premixed combustion (PPC) is a low temperature, direct-injection combustion concept that has shown to give promising emission levels and efficiencies over a wide operating range. In this concept, high EGR ratios, high octane-number fuels and early injection timings are used to slow down the auto-ignition reactions and to enhance the fuel and are mixing before the start of combustion. A drawback with this concept is the combustion stability in the low-load region where a high octane-number fuel might cause misfire and low combustion efficiency. This paper investigates the problem of low-load PPC controller design for increased engine efficiency. First, low-load PPC data, obtained from a multi-cylinder heavy- duty engine is presented. The data shows that combustion efficiency could be increased by using a pilot injection and that there is a non-linearity in the relation between injection and combustion timing. Furthermore, intake conditions should be set in order to avoid operating points with unfavourable global equivalence ratio and in-cylinder temperature combinations. Model predictive control simulations were used together with a calibrated engine model to find a gas-system controller that fulfilled this task. The findings are then summarized in a suggested engine controller design. Finally, an experimental performance evaluation of the suggested controller is presented.

  9. Dual fuel diesel engine operation using LPG (United States)

    Mirica, I.; Pana, C.; Negurescu, N.; Cernat, Al; Nutu, N. C.


    Diesel engine fuelling with LPG represents a good solution to reduce the pollutant emissions and to improve its energetic performances. The high autoignition endurance of LPG requires specialized fuelling methods. From all possible LPG fuelling methods the authors chose the diesel-gas method because of the following reasons: is easy to be implemented even at already in use engines; the engine does not need important modifications; the LPG-air mixture has a high homogeneity with favorable influences over the combustion efficiency and over the level of the pollutant emissions, especially on the nitrogen oxides emissions. This paper presents results of the theoretical and experimental investigations on operation of a LPG fuelled heavy duty diesel engine at two operating regimens, 40% and 55%. For 55% engine load is also presented the exhaust gas recirculation influence on the pollutant emission level. Was determined the influence of the diesel fuel with LPG substitution ratio on the combustion parameters (rate of heat released, combustion duration, maximum pressure, maximum pressure rise rate), on the energetic parameters (indicate mean effective pressure, effective efficiency, energetic specific fuel consumption) and on the pollutant emissions level. Therefore with increasing substitute ratio of the diesel fuel with LPG are obtained the following results: the increase of the engine efficiency, the decrease of the specific energetic consumption, the increase of the maximum pressure and of the maximum pressure rise rate (considered as criteria to establish the optimum substitute ratio), the accentuated reduction of the nitrogen oxides emissions level.

  10. Selection and Use of Manganese Dioxide by Neanderthals (United States)

    Heyes, Peter J.; Anastasakis, Konstantinos; de Jong, Wiebren; van Hoesel, Annelies; Roebroeks, Wil; Soressi, Marie


    Several Mousterian sites in France have yielded large numbers of small black blocs. The usual interpretation is that these ‘manganese oxides’ were collected for their colouring properties and used in body decoration, potentially for symbolic expression. Neanderthals habitually used fire and if they needed black material for decoration, soot and charcoal were readily available, whereas obtaining manganese oxides would have incurred considerably higher costs. Compositional analyses lead us to infer that late Neanderthals at Pech-de-l’Azé I were deliberately selecting manganese dioxide. Combustion experiments and thermo-gravimetric measurements demonstrate that manganese dioxide reduces wood’s auto-ignition temperature and substantially increases the rate of char combustion, leading us to conclude that the most beneficial use for manganese dioxide was in fire-making. With archaeological evidence for fire places and the conversion of the manganese dioxide to powder, we argue that Neanderthals at Pech-de-l’Azé I used manganese dioxide in fire-making and produced fire on demand.

  11. Performance of a flameless combustion furnace using biogas and natural gas. (United States)

    Colorado, A F; Herrera, B A; Amell, A A


    Flameless combustion technology has proved to be flexible regarding the utilization of conventional fuels. This flexibility is associated with the main characteristic of the combustion regime, which is the mixing of the reactants above the autoignition temperature of the fuel. Flameless combustion advantages when using conventional fuels are a proven fact. However, it is necessary to assess thermal equipments performance when utilizing bio-fuels, which usually are obtained from biomass gasification and the excreta of animals in bio-digesters. The effect of using biogas on the performance of an experimental furnace equipped with a self-regenerative Flameless burner is reported in this paper. All the results were compared to the performance of the system fueled with natural gas. Results showed that temperature field and uniformity are similar for both fuels; although biogas temperatures were slightly lower due to the larger amount of inert gases (CO(2)) in its composition that cool down the reactions. Species patterns and pollutant emissions showed similar trends and values for both fuels, and the energy balance for biogas showed a minor reduction of the efficiency of the furnace; this confirms that Flameless combustion is highly flexible to burn conventional and diluted fuels. Important modifications on the burner were not necessary to run the system using biogas. Additionally, in order to highlight the advantages of the Flameless combustion regime, some comparisons of the burner performance working in Flameless mode and working in conventional mode are presented.

  12. Mechanism and kinetics of low-temperature oxidation of a biodiesel surrogate: methyl propanoate radicals with oxygen molecule. (United States)

    Le, Xuan T; Mai, Tam V T; Ratkiewicz, Artur; Huynh, Lam K


    This paper presents a computational study on the low-temperature mechanism and kinetics of the reaction between molecular oxygen and alkyl radicals of methyl propanoate (MP), which plays an important role in low-temperature oxidation and/or autoignition processes of the title fuel. Their multiple reaction pathways either accelerate the oxidation process via chain branching or inhibit it by forming relatively stable products. The potential energy surfaces of the reactions between three primary MP radicals and molecular oxygen, namely, C(•)H2CH2COOCH3 + O2, CH3C(•)HCOOCH3 + O2, and CH3CH2COOC(•)H2 + O2, were constructed using the accurate composite CBS-QB3 method. Thermodynamic properties of all species as well as high-pressure rate constants of all reaction channels were derived with explicit corrections for tunneling and hindered internal rotations. Our calculation results are in good agreement with a limited number of scattered data in the literature. Furthermore, pressure- and temperature-dependent rate constants for all reaction channels on the multiwell-multichannel potential energy surfaces were computed with the quantum Rice-Ramsperger-Kassel (QRRK) and the modified strong collision (MSC) theories. This procedure resulted in a thermodynamically consistent detailed kinetic submechanism for low-temperature oxidation governed by the title process. A simplified mechanism, which consists of important reactions, is also suggested for low-temperature combustion at engine-like conditions.

  13. Influence of Cr deficiency on sintering, thermal expansion and electrical properties of La0.75Sr0.25Cr1-xO3-δ as a SOFC interconnect material (United States)

    Ren, Yi; Ma, Wen; Li, Xiaoying; Wang, Jun; Bai, Yu; Dong, Hongying


    The SOFC interconnect materials La0.75Sr0.25Cr1-xO3-δ (x = 0-0.04) were prepared using an auto-ignition process. The influences of Cr deficiency on their sintering, thermal expansion and electrical properties were investigated. All the samples were pure perovskite phase after sintering at 1400∘C for 4 h. The cell volume of La0.75Sr0.25Cr1-xO3-δ decreased with increasing Cr deficient content. The relative density of the sintered bulk samples increased from 93.2% (x = 0) to a maximum value of 94.7% (x = 0.02) and then decreased to 87.7% (x = 0.04). The thermal expansion coefficients of the sintered bulk samples were in the range of 10.60-10.98 × 10-6K-1 (30-1000∘C), which are compatible with that of YSZ. Among the investigated samples, the sample with 0.02 Cr deficiency had a maximum conductivity of 40.4 Scm-1 and the lowest Seebeck coefficient of 154.8 μVK-1 at 850∘C in pure He. The experimental results indicate that La0.75Sr0.25Cr0.98O3-δ has the best properties and is much suitable for SOFC interconnect material application.

  14. Imaging Studies of the Effects of Ethanol/Gasoline Blends on Spark-Assisted HCCI (United States)

    Fatouraie, Mohammad; Wooldridge, Margaret


    Spark assist (SA) has been demonstrated to extend the operating limits of homogeneous charge compression ignition (HCCI) modes of engine operation. This experimental investigation focuses on the effects caused by the SA HCCI operation on ignition and combustion properties of 100% indolene and 70% indolene/30% ethanol blends. The spark assist effects are compared to base line HCCI for each blend by varying spark timing at different fuel/air equivalence ratio (φ= 0.4--0.6). High speed imaging is used to understand the effects of flame propagation on heat release rates. Ethanol generally improves engine performance with higher indicated mean effective pressure (IMEP) and higher stability compared to 100% indolene. SA advances phasing within a range of 5 CAD at lower engine speeds (700 rpm) and 11 CAD at higher engine speeds (1200 rpm). SA does not affect heat release rates until immediately (within 5 CAD) prior to autoignition. Unlike previous studies, flames were not observed for all SA conditions. During SA operation, more fuel mass was burned by flame propagation with gasoline compared to E30.

  15. FY2015 Annual Report for Alternative Fuels DISI Engine Research.

    Energy Technology Data Exchange (ETDEWEB)

    Sjöberg, Carl-Magnus G. [Sandia National Lab. (SNL-CA), Livermore, CA (United States)


    Climate change and the need to secure energy supplies are two reasons for a growing interest in engine efficiency and alternative fuels. This project contributes to the science-base needed by industry to develop highly efficient DISI engines that also beneficially exploit the different properties of alternative fuels. Our emphasis is on lean operation, which can provide higher efficiencies than traditional non-dilute stoichiometric operation. Since lean operation can lead to issues with ignition stability, slow flame propagation and low combustion efficiency, we focus on techniques that can overcome these challenges. Specifically, fuel stratification is used to ensure ignition and completeness of combustion but has soot- and NOx- emissions challenges. For ultralean well-mixed operation, turbulent deflagration can be combined with controlled end-gas auto-ignition to render mixed-mode combustion that facilitates high combustion efficiency. However, the response of both combustion and exhaust emissions to these techniques depends on the fuel properties. Therefore, to achieve optimal fuel-economy gains, the engine combustion-control strategies must be adapted to the fuel being utilized.

  16. Effects of Exhaust Gas Recirculation on the Homogeneous Charge Combustion Process of n-Heptane at Different Load Conditions

    Institute of Scientific and Technical Information of China (English)

    LIU Dexin; FENG Hongqing; ZHENG Jincai; MILLER David L; CERNANSKY Nicholas P


    Effects of exhaust gas recirculation (EGR) on homogeneous charge combustion of n-heptane was studied through simulation and experiment. Experiments were carried out in a single cylinder, four-stroke, air cooled engine and a single cylinder, two-stroke, water cooled engine. In the four-stroke engine, experiments of the effects of EGR were examined using heated N2 addition as a surrogate for external EGR and modifying engine to increase internal EGR. The ignition timing was sensitive to EGR due to thermal and chemical effects. EGR or extra air is a key factor in eliminating knock during mid-load conditions. For higher load operation the only way to avoid knock is to control reaction timing through the use of spark ignition. Experimental and modeling results from the two-stroke engine show that auto-ignition can be avoided by increasing the engine speed. The two-stroke engine experiments indicate that high levels of internal EGR can enable spark ignition at lean conditions. At higher load conditions, increasing the engine speed is an effective method to control transition from homogeneous charge compression ignition (HCCI) operation to non-HCCI operation and successful spark ignition of a highly dilute mixture can avoid serious knock.

  17. Development, characterization, sintering, dielectric and optical properties of NdBa2ZrO5.5 nanocrystals

    Indian Academy of Sciences (India)

    V Ratheesh Kumar; P R S Wariar; R Pazhani; J K Thomas; R Jose; J Koshy


    Nanocrystalline NdBa2ZrO5.5 has been successfully synthesized through a single step auto-ignition combustion route for the first time. X-ray diffraction and Fourier transform infrared spectroscopy revealed that the combustion product is phase pure and has an ordered cubic perovskite structure. The phase transitions and thermal stability of the nanopowder were investigated by differential thermal and thermogravimetric analyses. Transmission electron microscopy results indicated that the particle sizes are 20–30 nm. Selected area electron diffraction pattern has shown that as-prepared powder is polycrystalline in nature. The optical absorption spectra analysis confirmed that the material falls to the semiconducting range with a bandgap of ∼3.69 eV and therefore, could be used as transparent wide bandgap semiconductor. The relative density of the sintered sample is ∼96% at 1510 °C for 2 h. The surface morphology of the sintered pellet has been studied by scanning electron microscopy and the average grain size observed is ∼0.7 m. Dielectric constant (r) of NdBa2ZrO5.5 at 5 MHz is 29.6 and loss factor (tan ) is 4 × 10-2 at room temperature.

  18. Experimental study of the supercritical water oxidation of recalcitrant compounds under hydrothermal flames using tubular reactors. (United States)

    Cabeza, Pablo; Bermejo, M Dolores; Jiménez, Cristina; Cocero, M José


    The hydrothermal flame is a new method of combustion that takes place in supercritical water oxidation reactions when the temperature is higher than the autoignition temperature. In these conditions, waste can be completely mineralized in residence times of milliseconds without the formation of by-products typical of conventional combustion. The object of this work is to study the hydrothermal flame formation in aqueous streams with high concentrations of recalcitrant compounds: an industrial waste with a high concentration of acetic acid and various concentrated solutions of ammonia. A tubular reactor with a residence time of 0.7 s was used. Oxygen was used as the oxidant and isopropyl alcohol (IPA) as co-fuel to reach the operation temperature required. The increase of IPA concentrations in the feeds resulted in a better TOC removal. For mixtures containing acetic acid, 99% elimination of TOC was achieved at temperatures higher than 750 °C. In the case of mixtures containing ammonia, TOC removals reached 99% while maximum total nitrogen removals were never higher than 94%, even for reaction temperatures higher than 710 °C. Ignition was observed at concentrations as high as 6% wt NH(3) with 2% wt IPA while at IPA concentrations below 2% wt IPA, the ammonia did not ignite.

  19. Compendium of Experimental Cetane Numbers

    Energy Technology Data Exchange (ETDEWEB)

    Yanowitz, J.; Ratcliff, M. A.; McCormick, R. L.; Taylor, J. D.; Murphy, M. J.


    This report is an updated version of the 2004 Compendium of Experimental Cetane Number Data and presents a compilation of measured cetane numbers for pure chemical compounds. It includes all available single compound cetane number data found in the scientific literature up until March 2014 as well as a number of unpublished values, most measured over the past decade at the National Renewable Energy Laboratory. This Compendium contains cetane values for 389 pure compounds, including 189 hydrocarbons and 201 oxygenates. More than 250 individual measurements are new to this version of the Compendium. For many compounds, numerous measurements are included, often collected by different researchers using different methods. Cetane number is a relative ranking of a fuel's autoignition characteristics for use in compression ignition engines; it is based on the amount of time between fuel injection and ignition, also known as ignition delay. The cetane number is typically measured either in a single-cylinder engine or a constant volume combustion chamber. Values in the previous Compendium derived from octane numbers have been removed, and replaced with a brief analysis of the correlation between cetane numbers and octane numbers. The discussion on the accuracy and precision of the most commonly used methods for measuring cetane has been expanded and the data has been annotated extensively to provide additional information that will help the reader judge the relative reliability of individual results.

  20. The Measurement and Prediction of Combustible Properties of Dimethylacetamide (DMAc)

    Energy Technology Data Exchange (ETDEWEB)

    Ha, Dong-Myeong [Semyung University, Jecheon (Korea, Republic of)


    The usage of the correct combustion characteristic of the treated substance for the safety of the process is critical. For the safe handling of dimethylacetamide (DMAc) being used in various ways in the chemical industry, the flash point and the autoignition temperature (AIT) of DMAc was experimented. And, the lower explosion limit of DMAc was calculated by using the lower flash point obtained in the experiment. The flash points of DMAc by using the Setaflash and Pensky-Martens closed-cup testers measured 61 .deg. C and 65 .deg. C, respectively. The flash points of DMAc by using the Tag and Cleveland automatic open cup testers are measured 68 .deg. C and 71 .deg. C. The AIT of DMAc by ASTM 659E tester was measured as 347 .deg. C. The lower explosion limit by the measured flash point 61 .deg. C was calculated as 1.52 vol%. It was possible to predict lower explosion limit by using the experimental flash point or flash point in the literature.

  1. Eléments d'analyse du cliquetis et de ses effets Elements for Analyzing Knocking and Its Effects

    Directory of Open Access Journals (Sweden)

    Douaud A.


    Full Text Available On présente dans cet article une synthèse des travaux théoriques et expérimentaux relatifs à la génération du cliquetis et à ses effets sur le fonctionnement du moteur. L'apparition du cliquetis est décrite par un mécanisme global de délai d'auto-inflammation. Des exemples d'application portant sur l'identification du délai de carburants quelconques et sur l'optimisation de l'ensemble moteurs-carburants documentent cette approche. Le cliquetis a pour conséquence un accroissement de sollicitations mécaniques et thermiques des parois de la chambre de combustion. Des méthodes et résultats d'investigation de ces phénomènes sont présentés. A synthesis is presented of theoretical and experimental research concerning the generating of knocking and its effects on engine running. The appearance of knocking is described by an overall mechanism of autoignition delay. This approach is documented by applied examples concerning the identification of the delay involved with any type of fuel and the optimizing of engine-fuel systems. Knocking causes an increase in mechanical and thermal stresses on combustion-chamber walls. Investigational methods and results concerning these phenomena are described.

  2. Vehicle Integrated Photovoltaics for Compression Ignition Vehicles: An Experimental Investigation of Solar Alkaline Water Electrolysis for Improving Diesel Combustion and a Solar Charging System for Reducing Auxiliary Engine Loads (United States)

    Negroni, Garry Inocentes

    Vehicle-integrated photovoltaic electricity can be applied towards aspiration of hydrogen-oxygen-steam gas produced through alkaline electrolysis and reductions in auxiliary alternator load for reducing hydrocarbon emissions in low nitrogen oxide indirect-injection compression-ignition engines. Aspiration of 0.516 ± 0.007 liters-per-minute of gas produced through alkaline electrolysis of potassium-hydroxide 2wt.% improves full-load performance; however, part-load performance decreases due to auto-ignition of aspirated gas prior to top-dead center. Alternator load reductions offer improved part-load and full-load performance with practical limitations resulting from accessory electrical loads. In an additive approach, solar electrolysis can electrochemically convert solar photovoltaic electricity into a gas comprised of stoichiometric hydrogen and oxygen gas. Aspiration of this hydrogen-oxygen gas enhances combustion properties decreasing emissions and increased combustion efficiency in light-duty diesel vehicles. The 316L stainless steel (SS) electrolyser plates are arranged with two anodes and three cathodes space with four bipolar plates delineating four stacks in parallel with five cells per stack. The electrolyser was tested using potassium hydroxide 2 wt.% and hydronium 3wt.% at measured voltage and current inputs. The flow rate output from the reservoir cell was measured in parallel with the V and I inputs producing a regression model correlating current input to flow rate. KOH 2 wt.% produced 0.005 LPM/W, while H9O44 3 wt.% produced less at 0.00126 LPM/W. In a subtractive approach, solar energy can be used to charge a larger energy storage device, as is with plug-in electric vehicles, in order to alleviate the engine of the mechanical load placed upon it by the vehicles electrical accessories through the alternator. Solar electrolysis can improve part-load emissions and full-load performance. The average solar-to-battery efficiency based on the OEM rated

  3. Experimental investigation of gasoline compression ignition combustion in a light-duty diesel engine (United States)

    Loeper, C. Paul

    Due to increased ignition delay and volatility, low temperature combustion (LTC) research utilizing gasoline fuel has experienced recent interest [1-3]. These characteristics improve air-fuel mixing prior to ignition allowing for reduced emissions of nitrogen oxides (NOx) and soot (or particulate matter, PM). Computational fluid dynamics (CFD) results at the University of Wisconsin-Madison's Engine Research Center (Ra et al. [4, 5]) have validated these attributes and established baseline operating parameters for a gasoline compression ignition (GCI) concept in a light-duty diesel engine over a large load range (3-16 bar net IMEP). In addition to validating these computational results, subsequent experiments at the Engine Research Center utilizing a single cylinder research engine based on a GM 1.9-liter diesel engine have progressed fundamental understanding of gasoline autoignition processes, and established the capability of critical controlling input parameters to better control GCI operation. The focus of this thesis can be divided into three segments: 1) establishment of operating requirements in the low-load operating limit, including operation sensitivities with respect to inlet temperature, and the capabilities of injection strategy to minimize NOx emissions while maintaining good cycle-to-cycle combustion stability; 2) development of novel three-injection strategies to extend the high load limit; and 3) having developed fundamental understanding of gasoline autoignition kinetics, and how changes in physical processes (e.g. engine speed effects, inlet pressure variation, and air-fuel mixture processes) affects operation, develop operating strategies to maintain robust engine operation. Collectively, experimental results have demonstrated the ability of GCI strategies to operate over a large load-speed range (3 bar to 17.8 bar net IMEP and 1300-2500 RPM, respectively) with low emissions (NOx and PM less than 1 g/kg-FI and 0.2 g/kg-FI, respectively), and low

  4. Crude glycerol combustion: Particulate, acrolein, and other volatile organic emissions

    KAUST Repository

    Steinmetz, Scott


    Crude glycerol is an abundant by-product of biodiesel production. As volumes of this potential waste grow, there is increasing interest in developing new value added uses. One possible use, as a boiler fuel for process heating, offers added advantages of energy integration and fossil fuel substitution. However, challenges to the use of crude glycerol as a boiler fuel include its low energy density, high viscosity, and high autoignition temperature. We have previously shown that a refractory-lined, high swirl burner can overcome challenges related to flame ignition and stability. However, critical issues related to ash behavior and the possible formation of acrolein remained. The work presented here indicates that the presence of dissolved catalysts used during the esterification and transesterification processes results in extremely large amounts of inorganic species in the crude glycerol. For the fuels examined here, the result is a submicron fly ash comprised primarily of sodium carbonates, phosphates, and sulfates. These particles report to a well-developed accumulation mode (0.3-0.7 μm diameter), indicating extensive ash vaporization and particle formation via nucleation, condensation, and coagulation. Particle mass emissions were between 2 and 4 g/m3. These results indicate that glycerol containing soluble catalyst is not suitable as a boiler fuel. Fortunately, process improvements are currently addressing this issue. Additionally, acrolein is of concern due to its toxicity, and is known to be formed from the low temperature thermal decomposition of glycerol. Currently, there is no known reliable method for measuring acrolein in sources. Acrolein and emissions of other volatile organic compounds were characterized through the use of a SUMMA canister-based sampling method followed by GC-MS analysis designed for ambient measurements. Results indicate crude glycerol combustion produces relatively small amounts of acrolein (∼15 ppbv) and other volatile organic

  5. A multipurpose reduced chemical-kinetic mechanism for methanol combustion (United States)

    Fernández-Tarrazo, Eduardo; Sánchez-Sanz, Mario; Sánchez, Antonio L.; Williams, Forman A.


    A multipurpose reduced chemical-kinetic mechanism for methanol combustion comprising 8 overall reactions and 11 reacting chemical species is presented. The development starts by investigating the minimum set of elementary reactions needed to describe methanol combustion with reasonable accuracy over a range of conditions of temperature, pressure, and composition of interest in combustion. Starting from a 27-step mechanism that has been previously tested and found to give accurate predictions of ignition processes for these conditions, it is determined that the addition of 11 elementary reactions taken from its basis (San Diego) mechanism extends the validity of the description to premixed-flame propagation, strain-induced extinction of non-premixed flames, and equilibrium composition and temperatures, giving results that compare favourably with experimental measurements and also with computations using the 247-step detailed San Diego mechanism involving 50 reactive species. Specifically, premixed-flame propagation velocities and extinction strain rates for non-premixed counterflow flames calculated with the 38-step mechanism show departures from experimental measurements and detailed-chemistry computations that are roughly on the order of 10%, comparable with expected experimental uncertainties. Similar accuracy is found in comparisons of autoignition times over the range considered, except at very high temperatures, under which conditions the computations tend to overpredict induction times for all of the chemistry descriptions tested. From this 38-step mechanism, the simplification is continued by introducing steady-state approximations for the intermediate species CH3, CH4, HCO, CH3O, CH2OH, and O, leading to an 8-step reduced mechanism that provides satisfactory accuracy for all conditions tested. The flame computations indicate that thermal diffusion has a negligible influence on methanol combustion in all cases considered and that a mixture-average species

  6. An experimental and kinetic modeling study of the oxidation of the four isomers of butanol. (United States)

    Moss, Jeffrey T; Berkowitz, Andrew M; Oehlschlaeger, Matthew A; Biet, Joffrey; Warth, Valérie; Glaude, Pierre-Alexandre; Battin-Leclerc, Frédérique


    Butanol, an alcohol which can be produced from biomass sources, has received recent interest as an alternative to gasoline for use in spark ignition engines and as a possible blending compound with fossil diesel or biodiesel. Therefore, the autoignition of the four isomers of butanol (1-butanol, 2-butanol, iso-butanol, and tert-butanol) has been experimentally studied at high temperatures in a shock tube, and a kinetic mechanism for description of their high-temperature oxidation has been developed. Ignition delay times for butanol/oxygen/argon mixtures have been measured behind reflected shock waves at temperatures and pressures ranging from approximately 1200 to 1800 K and 1 to 4 bar. Electronically excited OH emission and pressure measurements were used to determine ignition-delay times. The influence of temperature, pressure, and mixture composition on ignition delay has been characterized. A detailed kinetic mechanism has been developed to describe the oxidation of the butanol isomers and validated by comparison to the shock-tube measurements. Reaction flux and sensitivity analysis illustrates the relative importance of the three competing classes of consumption reactions during the oxidation of the four butanol isomers: dehydration, unimolecular decomposition, and H-atom abstraction. Kinetic modeling indicates that the consumption of 1-butanol and iso-butanol, the most reactive isomers, takes place primarily by H-atom abstraction resulting in the formation of radicals, the decomposition of which yields highly reactive branching agents, H atoms and OH radicals. Conversely, the consumption of tert-butanol and 2-butanol, the least reactive isomers, takes place primarily via dehydration, resulting in the formation of alkenes, which lead to resonance stabilized radicals with very low reactivity. To our knowledge, the ignition-delay measurements and oxidation mechanism presented here for 2-butanol, iso-butanol, and tert-butanol are the first of their kind.

  7. A computational methodology for formulating gasoline surrogate fuels with accurate physical and chemical kinetic properties

    KAUST Repository

    Ahmed, Ahfaz


    Gasoline is the most widely used fuel for light duty automobile transportation, but its molecular complexity makes it intractable to experimentally and computationally study the fundamental combustion properties. Therefore, surrogate fuels with a simpler molecular composition that represent real fuel behavior in one or more aspects are needed to enable repeatable experimental and computational combustion investigations. This study presents a novel computational methodology for formulating surrogates for FACE (fuels for advanced combustion engines) gasolines A and C by combining regression modeling with physical and chemical kinetics simulations. The computational methodology integrates simulation tools executed across different software platforms. Initially, the palette of surrogate species and carbon types for the target fuels were determined from a detailed hydrocarbon analysis (DHA). A regression algorithm implemented in MATLAB was linked to REFPROP for simulation of distillation curves and calculation of physical properties of surrogate compositions. The MATLAB code generates a surrogate composition at each iteration, which is then used to automatically generate CHEMKIN input files that are submitted to homogeneous batch reactor simulations for prediction of research octane number (RON). The regression algorithm determines the optimal surrogate composition to match the fuel properties of FACE A and C gasoline, specifically hydrogen/carbon (H/C) ratio, density, distillation characteristics, carbon types, and RON. The optimal surrogate fuel compositions obtained using the present computational approach was compared to the real fuel properties, as well as with surrogate compositions available in the literature. Experiments were conducted within a Cooperative Fuels Research (CFR) engine operating under controlled autoignition (CAI) mode to compare the formulated surrogates against the real fuels. Carbon monoxide measurements indicated that the proposed surrogates

  8. Electromagnetic and microwave absorption properties of single-walled carbon nanotubes and CoFe{sub 2}O{sub 4} nanocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Li, Guo; Sheng, Leimei, E-mail:; Yu, Liming; An, Kang; Ren, Wei; Zhao, Xinluo, E-mail:


    Highlights: • LPA-SWCNTs have been abundantly fabricated by a facile, time-saving, economical and non-hazardous method using DC arc discharge technique in low-pressure air. • The electromagnetic and microwave absorption properties of LPA-SWCNTs, CoFe{sub 2}O{sub 4} nanocrystals and LPA-SWCNT/CoFe{sub 2}O{sub 4} nanocomposites were investigated and the LPA-SWCNT/CoFe{sub 2}O{sub 4} nanocomposites exhibited excellent microwave absorption properties. • The Debye theory and impedance matching were used to analyze the electromagnetic parameters and microwave absorption properties. - Abstract: Single-walled carbon nanotubes were facilely and abundantly synthesized by low-pressure air arc discharge method (LPA-SWCNTs), and CoFe{sub 2}O{sub 4} nanocrystals were synthesized by a nitrate citric acid sol–gel auto-ignition method. The electromagnetic and microwave absorption properties of LPA-SWCNTs, CoFe{sub 2}O{sub 4} nanocrystals and their nanocomposites were investigated. The LPA-SWCNT/CoFe{sub 2}O{sub 4} nanocomposites showed excellent microwave absorption properties. The minimum efficient reflection loss is −30.7 dB at 12.9 GHz for 10 wt% of LPA-SWCNTs in the nanocomposites, and an effective absorption bandwidth with a reflection loss below −10 dB is 7.2 GHz. The Debye equation and impedance matching were introduced to explain the microwave absorption properties. Compared with the single-component materials, the LPA-SWCNT/CoFe{sub 2}O{sub 4} nanocomposites are an excellent candidate for microwave absorbers.

  9. Combustion Mode Design with High Efficiency and Low Emissions Controlled by Mixtures Stratification and Fuel Reactivity

    Directory of Open Access Journals (Sweden)

    Hu eWang


    Full Text Available This paper presents a review on the combustion mode design with high efficiency and low emissions controlled by fuel reactivity and mixture stratification that have been conducted in the authors’ group, including the charge reactivity controlled homogeneous charge compression ignition (HCCI combustion, stratification controlled premixed charge compression ignition (PCCI combustion, and dual-fuel combustion concepts controlled by both fuel reactivity and mixture stratification. The review starts with the charge reactivity controlled HCCI combustion, and the works on HCCI fuelled with both high cetane number fuels, such as DME and n-heptane, and high octane number fuels, such as methanol, natural gas, gasoline and mixtures of gasoline/alcohols, are reviewed and discussed. Since single fuel cannot meet the reactivity requirements under different loads to control the combustion process, the studies related to concentration stratification and dual-fuel charge reactivity controlled HCCI combustion are then presented, which have been shown to have the potential to achieve effective combustion control. The efforts of using both mixture and thermal stratifications to achieve the auto-ignition and combustion control are also discussed. Thereafter, both charge reactivity and mixture stratification are then applied to control the combustion process. The potential and capability of thermal-atmosphere controlled compound combustion mode and dual-fuel reactivity controlled compression ignition (RCCI/highly premixed charge combustion (HPCC mode to achieve clean and high efficiency combustion are then presented and discussed. Based on these results and discussions, combustion mode design with high efficiency and low emissions controlled by fuel reactivity and mixtures stratification in the whole operating range is proposed.

  10. Diesel combustion and emissions formation using multiple 2-D imaging diagnostics

    Energy Technology Data Exchange (ETDEWEB)

    Dec, J.E. [Sandia National Labs., Livermore, CA (United States)


    Understanding how emissions are formed during diesel combustion is central to developing new engines that can comply with increasingly stringent emission standards while maintaining or improving performance levels. Laser-based planar imaging diagnostics are uniquely capable of providing the temporally and spatially resolved information required for this understanding. Using an optically accessible research engine, a variety of two-dimensional (2-D) imaging diagnostics have been applied to investigators of direct-injection (DI) diesel combustion and emissions formation. These optical measurements have included the following laser-sheet imaging data: Mie scattering to determine liquid-phase fuel distributions, Rayleigh scattering for quantitative vapor-phase-fuel/air mixture images, laser induced incandescence (LII) for relative soot concentrations, simultaneous LII and Rayleigh scattering for relative soot particle-size distributions, planar laser-induced fluorescence (PLIF) to obtain early PAH (polyaromatic hydrocarbon) distributions, PLIF images of the OH radical that show the diffusion flame structure, and PLIF images of the NO radical showing the onset of NO{sub x} production. In addition, natural-emission chemiluminescence images were obtained to investigate autoignition. The experimental setup is described, and the image data showing the most relevant results are presented. Then the conceptual model of diesel combustion is summarized in a series of idealized schematics depicting the temporal and spatial evolution of a reacting diesel fuel jet during the time period investigated. Finally, recent PLIF images of the NO distribution are presented and shown to support the timing and location of NO formation hypothesized from the conceptual model.

  11. Additional chain-branching pathways in the low-temperature oxidation of branched alkanes

    KAUST Repository

    Wang, Zhandong


    Chain-branching reactions represent a general motif in chemistry, encountered in atmospheric chemistry, combustion, polymerization, and photochemistry; the nature and amount of radicals generated by chain-branching are decisive for the reaction progress, its energy signature, and the time towards its completion. In this study, experimental evidence for two new types of chain-branching reactions is presented, based upon detection of highly oxidized multifunctional molecules (HOM) formed during the gas-phase low-temperature oxidation of a branched alkane under conditions relevant to combustion. The oxidation of 2,5-dimethylhexane (DMH) in a jet-stirred reactor (JSR) was studied using synchrotron vacuum ultra-violet photoionization molecular beam mass spectrometry (SVUV-PI-MBMS). Specifically, species with four and five oxygen atoms were probed, having molecular formulas of C8H14O4 (e.g., diketo-hydroperoxide/keto-hydroperoxy cyclic ether) and C8H16O5 (e.g., keto-dihydroperoxide/dihydroperoxy cyclic ether), respectively. The formation of C8H16O5 species involves alternative isomerization of OOQOOH radicals via intramolecular H-atom migration, followed by third O2 addition, intramolecular isomerization, and OH release; C8H14O4 species are proposed to result from subsequent reactions of C8H16O5 species. The mechanistic pathways involving these species are related to those proposed as a source of low-volatility highly oxygenated species in Earth\\'s troposphere. At the higher temperatures relevant to auto-ignition, they can result in a net increase of hydroxyl radical production, so these are additional radical chain-branching pathways for ignition. The results presented herein extend the conceptual basis of reaction mechanisms used to predict the reaction behavior of ignition, and have implications on atmospheric gas-phase chemistry and the oxidative stability of organic substances. © 2015 The Combustion Institute.

  12. Risk analysis of fire explosion of refinery storage tanks and prevention%炼油厂储罐火灾爆炸事故风险分析与防范

    Institute of Scientific and Technical Information of China (English)



    The risk analysis is performed on six types of typical fire explosion accidents of refinery oil storage tanks caused by tank flooding, lightning, static-electricity, auto-ignition of ferrous sulfide, construction with fire and inappropriate unit operation, and effective measure have been proposed. It is pointed out that, to prevent big fire explosion accidents of oil storage tanks, the safety management shall be strengthened, the safety awareness of operation personnel be enhanced, the regulations be strictly followed, the inappropriate operations be prevented, the fire sources of tank farms be properly controlled, the safety facilities be properly examined and maintained to eliminate potential fire hazards in addition to various safety measures designed based upon new applicable codes and standards for intrinsic safety of tanks.%对炼化企业油品储罐因冒罐、雷击、静电、硫化亚铁自燃、用火施工作业、与生产运行装置协调不当等引发的6类典型火灾爆炸事故案例进行了风险分析,提出了有效的防范措施.指出为避免油品储罐发生重大火灾爆炸事故,除了按照新的标准规范不断完善油品储罐及罐区的各种安全措施,实现油罐的本质安全外,还应加强安全管理,提高操作人员的安全意识及素质,严格执行纪律,防止违规操作,加强对油品罐区各种火源的管理,加强各种安全设施的检查及维护,消除事故隐患.

  13. Tunable magnetic and magnetocaloric properties of La{sub 0.6}Sr{sub 0.4}MnO{sub 3} nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Ehsani, M. H., E-mail: [Department of Physics, Semnan University, Semnan 35195-363 (Iran, Islamic Republic of); Kameli, P. [Department of Physics, Isfahan University of Technology, Isfahan 84156-8311 (Iran, Islamic Republic of); Ghazi, M. E. [Department of Physics, Shahrood University, Shahrood (Iran, Islamic Republic of); Razavi, F. S.; Taheri, M. [Department of Physics, Brock University, St.Catharines, Ontario L2S 3A1 (Canada)


    Nanoparticles of La{sub 0.6}Sr{sub 0.4}MnO{sub 3} with different particle sizes are synthesized by the nitrate-complex auto-ignition method. The structural and magnetic properties of the samples are investigated by X-Ray diffraction (XRD), Fourier transform infra-red (FT-IR) spectroscopy, transmission electron microscopy (TEM), and DC magnetization measurements. The XRD study coupled with the Rietveld refinement shows that all samples crystallize in a rhombohedral structure with the space group of R-3 C. The FT-IR spectroscopy and TEM images indicate formation of the perovskite structure with the average sizes of 20, 40, and 100 nm for the samples sintered at 700, 800, and 1100 °C, respectively. The DC magnetization measurements confirm tuning of the magnetic properties due to the particle size effects, e.g., reduction in the ferromagnetic moment and increase in the surface spin disorder by decreasing the particle size. The magnetocaloric effect (MCE) study based on isothermal magnetization vs. filed measurements in all samples reveals a relatively large MCE around the Curie temperature of the samples. The peak around the Curie temperature gradually broadens with reduction of the particle size. The data obtained show that although variations in the magnetic entropy and adiabatic temperature decrease by lowering the particle size, variation in the relative cooling power values are the same for all samples. These results make this material a proper candidate in the magnetic refrigerator application above room temperature at moderate fields.

  14. Conditional Moment Closure Modelling of a Lifted H2/N2 Turbulent Jet Flame Using the Presumed Mapping Function Approach

    Directory of Open Access Journals (Sweden)

    Ahmad El Sayed


    Full Text Available A lifted hydrogen/nitrogen turbulent jet flame issuing into a vitiated coflow is investigated using the conditional moment closure (CMC supplemented by the presumed mapping function (PMF approach for the modelling of conditional mixing and velocity statistics. Using a prescribed reference field, the PMF approach yields a presumed probability density function (PDF for the mixture fraction, which is then used in closing the conditional scalar dissipation rate (CSDR and conditional velocity in a fully consistent manner. These closures are applied to a lifted flame and the findings are compared to previous results obtained using β-PDF-based closures over a range of coflow temperatures (Tc. The PMF results are in line with those of the β-PDF and compare well to measurements. The transport budgets in mixture fraction and physical spaces and the radical history ahead of the stabilisation height indicate that the stabilisation mechanism is susceptible to Tc. As in the previous β-PDF calculations, autoignition around the “most reactive” mixture fraction remains the controlling mechanism for sufficiently high Tc. Departure from the β-PDF predictions is observed when Tc is decreased as PMF predicts stabilisation by means of premixed flame propagation. This conclusion is based on the observation that lean mixtures are heated by downstream burning mixtures in a preheat zone developing ahead of the stabilization height. The spurious sources, which stem from inconsistent CSDR modelling, are further investigated. The findings reveal that their effect is small but nonnegligible, most notably within the flame zone.


    Institute of Scientific and Technical Information of China (English)

    郭建栋; 徐晓林; 王永忠; 张炎; 刘达颐; 石磊


    The ultra-fine superconducting YBa2Cu3O7-x powders were prepared by means of the gel combustion process using nitrates of Y, Ba and Cu as the starting materials and citric acid as the fuel. The resulting particle size and its superconducting properties is dependent on the nature of the auto-ignition reaction, which in turn depends upon the citrate-nitrate ratio in the gel. An attempt to determine the optimal citrate-nitrate ratio has been made in order to obtain pure, homogeneous and reasonably fine YBCO superconductor. In our experiments we found the best fuel-oxidant molar ratio to be 0.5.%纳米级细度的YBa2Cu3O7-x超导粉末有可能在第二代超导带材的研制中得到应用.超细YBa2Cu3O7-x超导粉末已经通过凝胶燃烧法制备成功.使用的起始物质是钇、钡、铜的硝酸盐以及作为燃烧剂的柠檬酸.产物颗粒的尺寸大小及其超导性能依赖于自燃过程的情况,而自燃过程又与凝胶中柠檬酸盐-硝酸盐的YBa2Cu3O7-x超导粉末.在本实验中我们发现最好的燃烧剂-氧化剂摩尔比为0.5.

  16. Photoionization mass spectrometric measurements of initial reaction pathways in low-temperature oxidation of 2,5-dimethylhexane. (United States)

    Rotavera, Brandon; Zádor, Judit; Welz, Oliver; Sheps, Leonid; Scheer, Adam M; Savee, John D; Akbar Ali, Mohamad; Lee, Taek Soon; Simmons, Blake A; Osborn, David L; Violi, Angela; Taatjes, Craig A


    Product formation from R + O2 reactions relevant to low-temperature autoignition chemistry was studied for 2,5-dimethylhexane, a symmetrically branched octane isomer, at 550 and 650 K using Cl-atom initiated oxidation and multiplexed photoionization mass spectrometry (MPIMS). Interpretation of time- and photon-energy-resolved mass spectra led to three specific results important to characterizing the initial oxidation steps: (1) quantified isomer-resolved branching ratios for HO2 + alkene channels; (2) 2,2,5,5-tetramethyltetrahydrofuran is formed in substantial yield from addition of O2 to tertiary 2,5-dimethylhex-2-yl followed by isomerization of the resulting ROO adduct to tertiary hydroperoxyalkyl (QOOH) and exhibits a positive dependence on temperature over the range covered leading to a higher flux relative to aggregate cyclic ether yield. The higher relative flux is explained by a 1,5-hydrogen atom shift reaction that converts the initial primary alkyl radical (2,5-dimethylhex-1-yl) to the tertiary alkyl radical 2,5-dimethylhex-2-yl, providing an additional source of tertiary alkyl radicals. Quantum-chemical and master-equation calculations of the unimolecular decomposition of the primary alkyl radical reveal that isomerization to the tertiary alkyl radical is the most favorable pathway, and is favored over O2-addition at 650 K under the conditions herein. The isomerization pathway to tertiary alkyl radicals therefore contributes an additional mechanism to 2,2,5,5-tetramethyltetrahydrofuran formation; (3) carbonyl species (acetone, propanal, and methylpropanal) consistent with β-scission of QOOH radicals were formed in significant yield, indicating unimolecular QOOH decomposition into carbonyl + alkene + OH.

  17. Feasibility of reduced gravity experiments involving quiescent, uniform particle cloud combustion (United States)

    Ross, Howard D.; Facca, Lily T.; Berlad, Abraham L.; Tangirala, Venkat


    The study of combustible particle clouds is of fundamental scientific interest as well as a practical concern. The principal scientific interests are the characteristic combustion properties, especially flame structure, propagation rates, stability limits, and the effects of stoichiometry, particle type, transport phenomena, and nonadiabatic processes on these properties. The feasibility tests for the particle cloud combustion experiment (PCCE) were performed in reduced gravity in the following stages: (1) fuel particles were mixed into cloud form inside a flammability tube; (2) when the concentration of particles in the cloud was sufficiently uniform, the particle motion was allowed to decay toward quiescence; (3) an igniter was energized which both opened one end of the tube and ignited the suspended particle cloud; and (4) the flame proceeded down the tube length, with its position and characteristic features being photographed by high-speed cameras. Gravitational settling and buoyancy effects were minimized because of the reduced gravity enviroment in the NASA Lewis drop towers and aircraft. Feasibility was shown as quasi-steady flame propagation which was observed for fuel-rich mixtures. Of greatest scientific interest is the finding that for near-stoichiometric mixtures, a new mode of flame propagation was observed, now called a chattering flame. These flames did not propagate steadily through the tube. Chattering modes of flame propagation are not expected to display extinction limits that are the same as those for acoustically undisturbed, uniform, quiescent clouds. A low concentration of fuel particles, uniformly distributed in a volume, may not be flammable but may be made flammable, as was observed, through induced segregation processes. A theory was developed which showed that chattering flame propagation was controlled by radiation from combustion products which heated the successive discrete laminae sufficiently to cause autoignition.

  18. A laser-based study of kerosine evaporation and -mixing for lean prevaporized combustion at elevated pressure; Lasermesstechnische Untersuchung der Kerosinverdampfung und -mischung fuer die magere Vormischverbrennung unter erhoehtem Druck

    Energy Technology Data Exchange (ETDEWEB)

    Brandt, M.


    The evaporation and mixing of a kerosine spray in the turbulent airstream of a prevaporizer is investigated at conditions prevailing in the combustion chamber of gas turbines. An experiment is described that allows to study an evaporating fuel spray downstream a prefilming airblast atomizer with Phase-Doppler anemometry, laser-induced fluorescence and an infrared light absorption technique. At an air pressure of 9 bars, an air temperature of 750 K, a mean air velocity of 120 m/s and a fuel flow rate of 1 g/s the kerosine spray evaporates completely without autoignition. At this operating condition the parameters air pressure, air temperature and air turbulence are varied. The influence of these parametric variations on the dropsize distribution, the evaporation rate and the concentration profiles of liquid and evaporated fuel is presented and discussed. (orig.) [German] Die Verdampfung und Vermischung eines Kerosinsprays in der turbulenten Luftstroemung eines Vorverdampfers wird unter Bedingungen untersucht, die in Brennkammern fuer Gasturbinen vorherrschen. Ein Experiment wird vorgestellt, welches es erlaubt, ein verdampfendes Kraftstoffspray stromab eines ebenen Luftstromzerstaeubers mit Filmleger mittels der Phasen-Doppler-Anemometrie, Laser-induzierter Fluoreszenz und einer Infrarotabsorptionsmesstechnik zu untersuchen. Bei einem Luftdruck von 9 bar, einer Vorwaermetemperatur der Luft von 750 K, einer mittleren Luftgeschwindigkeit von 120 m/s und einem Kraftstoffmassenstrom von 1 g/s verdampft das Kerosinspray vollstaendig, ohne die Selbstzuendungszeit zu erreichen. Bei dieser Betriebsbedingung werden die Parameter Luftdruck, Lufttemperatur und Turbulenzgrad variiert. Der Einfluss dieser Parameter auf das Tropfengroessenspektrum, den Verdampfungsgrad und die Konzentrationsprofile des fluessigen sowie des verdampften Kraftstoffs wird dargestellt und diskutiert. (orig.)

  19. Compendium of Experimental Cetane Numbers

    Energy Technology Data Exchange (ETDEWEB)

    Yanowitz, Janet [Ecoengineering, Sharonville, OH (United States); Ratcliff, Matthew A. [National Renewable Energy Lab. (NREL), Golden, CO (United States); McCormick, Robert L. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Taylor, J. D. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Murphy, M. J. [Battelle, Columbus, OH (United States)


    This report is an updated version of the 2014 Compendium of Experimental Cetane Number Data and presents a compilation of measured cetane numbers for pure chemical compounds. It includes all available single-compound cetane number data found in the scientific literature up until December 2016 as well as a number of previously unpublished values, most measured over the past decade at the National Renewable Energy Laboratory. This version of the compendium contains cetane values for 496 pure compounds, including 204 hydrocarbons and 292 oxygenates. 176 individual measurements are new to this version of the compendium, all of them collected using ASTM Method D6890, which utilizes an Ignition Quality Tester (IQT) a type of constant-volume combustion chamber. For many compounds, numerous measurements are included, often collected by different researchers using different methods. The text of this document is unchanged from the 2014 version, except for the numbers of compounds in Section 3.1, the Appendices, Table 1. Primary Cetane Number Data Sources and Table 2. Number of Measurements Included in Compendium. Cetane number is a relative ranking of a fuel's autoignition characteristics for use in compression ignition engines. It is based on the amount of time between fuel injection and ignition, also known as ignition delay. The cetane number is typically measured either in a single-cylinder engine or a constant-volume combustion chamber. Values in the previous compendium derived from octane numbers have been removed and replaced with a brief analysis of the correlation between cetane numbers and octane numbers. The discussion on the accuracy and precision of the most commonly used methods for measuring cetane number has been expanded, and the data have been annotated extensively to provide additional information that will help the reader judge the relative reliability of individual results.

  20. Chemiluminescence analysis of the effect of butanol-diesel fuel blends on the spray-combustion process in an experimental common rail diesel engine

    Directory of Open Access Journals (Sweden)

    Merola Simona Silvia S.


    Full Text Available Combustion process was studied from the injection until the late combustion phase in an high swirl optically accessible combustion bowl connected to a single cylinder 2-stroke high pressure common rail compression ignition engine. Commercial diesel and blends of diesel and n-butanol (20%: BU20 and 40%: BU40 were used for the experiments. A pilot plus main injection strategy was investigated fixing the injection pressure and fuel mass injected per stroke. Two main injection timings and different pilot-main dwell times were explored achieving for any strategy a mixing controlled combustion. Advancing the main injection start, an increase in net engine working cycle (>40% together with a strong smoke number decrease (>80% and NOx concentration increase (@50% were measured for all pilot injection timings. Compared to diesel fuel, butanol induced a decrease in soot emission and an increase in net engine working area when butanol ratio increased in the blend. A noticeable increase in NOx was detected at the exhaust for BU40 with a slight effect of the dwell-time. Spectroscopic investigations confirmed the delayed auto-ignition (~60 ms of the pilot injection for BU40 compared to diesel. The spectral features for the different fuels were comparable at the start of combustion process, but they evolved in different ways. Broadband signal caused by soot emission, was lower for BU40 than diesel. Different balance of the bands at 309 and 282 nm, due to different OH transitions, were detected between the two fuels. The ratio of these intensities was used to follow flame temperature evolution.

  1. Thermal, optical and dielectric properties of phase stabilized δ - Dy-Bi2O3 ionic conductors (United States)

    Bandyopadhyay, Swagata; Dutta, Abhigyan


    In this work, we have investigated the thermal, structural, optical and dielectric properties of Bi1-xDyxO1.5-δ (0.10≤x≤0.40) ionic conductors prepared by citrate auto-ignition method. The Thermo gravimetric-DTA analysis and X-Ray Diffraction pattern confirm the single δ-phase stabilization of doped system beyond 25 mol% doping concentration. XRD analysis also indicates that average crystallite size is maximum and micro strain is minimum for Bi0.75Dy0.25O1.5-δ composition. The optical band gap of the prepared compositions is obtained from the Ultraviolet- Visible spectroscopy that shows a red shift with the increase in Dy content. The presence of different structural bonds is confirmed from FT-IR spectroscopy analysis. Ionic transport property of the prepared compositions has been analyzed using Nyquist plot for dc conduction and Nernst-Einstein relation for ac conduction mechanism. This analysis indicates that the composition Bi0.75Dy0.25O1.5-δ shows highest conductivity. The dielectric properties of these ionic conductors have been analyzed using Havriliak-Negami (HN) formalism. The dielectric permittivity ε' (ω) of all the prepared compositions is found to be within the range 1.61-3.63(x102) in S.I. unit. Analysis of electric modulus data reveals that dielectric and modulus relaxation follows same mechanism. The time-temperature superposition principle has been verified from the scaling of modulus spectra.

  2. Direct numerical simulation of hydrogen turbulent lifted jet flame in a vitiated coflow

    Institute of Scientific and Technical Information of China (English)

    WANG ZhiHua; FAN JianRen; ZHOU JunHu; CEN KeFa


    The direct numerical simulation (DNS) method with 16 steps detailed chemical kinetics was applied to a lifted turbulent jet flame with H2/N2 fuel issuing into a wide hot coflow of lean combustion products, at temperature of 1045 K and low oxygen concentrations. The chemical reactions were handled by the library function of CHEMKIN which was called by the main program in every time step. Parallel computational technology based on message passing interface method (MPI) was used in the simulation. All the cases were run by 12 CPUs on a high performance computer system. Faver-averaged DNS results were obtained by long time averaging the transient profile and compared with the experimental data. The roll-up and evolution of the vortices in jet flame were well captured. The vortices in the same rotating direction attracted each other and those in different rotating directions repulsed each other. Through complex interactions between vortices, the original symmetrical vortex structure could be converted into nonsymmetrical and more complex structures by combination, distortion and splitting of the vortices. The transient profiles of H, OH and H2O mass fraction at 5.76 ms showed the flame structure in jet flame, especially the autoignition regions clearly. The lift-off height was about 9 d-11 d, in agreement with the experimental observation. At the corner point of the flame sheet indicated by OH and H profiles, the combustion was always enhanced by the flame curvature and extended resident time. The profiles of turbulence intensities show that the flames were diffused from the original two outside flame sheets into the core. The DNS results can be considered in developing more accurate and more universal turbulence models.

  3. Antiknock quality and ignition kinetics of 2-phenylethanol, a novel lignocellulosic octane booster

    KAUST Repository

    Shankar, Vijai


    High-octane quality fuels are important for increasing spark ignition engine efficiency, but their production comes at a substantial economic and environmental cost. The possibility of producing high anti-knock quality gasoline by blending high-octane bio-derived components with low octane naphtha streams is attractive. 2-phenyl ethanol (2-PE), is one such potential candidate that can be derived from lignin, a biomass component made of interconnected aromatic groups. We first ascertained the blending anti-knock quality of 2-PE by studying the effect of spark advancement on knock for various blends 2-PE, toluene, and ethanol with naphtha in a cooperative fuels research engine. The blending octane quality of 2-PE indicated an anti-knock behavior similar or slightly greater than that of toluene, and ethylbenzene, which could be attributed to either chemical kinetics or charge cooling effects. To isolate chemical kinetic effects, a model for 2-PE auto-ignition was developed and validated using ignition delay times measured in a high-pressure shock tube. Simulated ignition delay times of 2-PE were also compared to those of traditional high-octane gasoline blending components to show that the gas phase reactivity of 2-PE is lower than ethanol, and comparable to toluene, and ethylbenzene at RON, and MON relevant conditions. The gas-phase reactivity of 2-PE is largely controlled by its aromatic ring, while the effect of the hydroxyl group is minimal. The higher blending octane quality of 2-PE compared to toluene, and ethylbenzene can be attributed primarily to the effect of the hydroxyl group on increasing heat of vaporization. © 2016 The Combustion Institute.

  4. Synthesis of Nanocrystalline CaWO4 as Low-Temperature Co-fired Ceramic Material: Processing, Structural and Physical Properties (United States)

    Vidya, S.; Solomon, Sam; Thomas, J. K.


    Nanocrystalline scheelite CaWO4, a promising material for low-temperature co-fired ceramic (LTCC) applications, has been successfully synthesized through a single-step autoignition combustion route. Structural analysis of the sample was performed by powder x-ray diffraction (XRD), Fourier-transform infrared spectroscopy, and Raman spectroscopy. The XRD analysis revealed that the as-prepared sample was single phase with scheelite tetragonal structure. The basic optical properties and optical constants of the CaWO4 nanopowder were studied using ultraviolet (UV)-visible absorption spectroscopy, which showed that the material was a wide-bandgap semiconductor with bandgap of 4.7 eV at room temperature. The sample showed poor transmittance in the ultraviolet region but maximum transmission in the visible/near-infrared regions. The photoluminescence spectra recorded at different temperatures showed intense emission in the green region. The particle size estimated from transmission electron microscopy was 23 nm. The feasibility of CaWO4 for LTCC applications was studied from its sintering behavior. The sample was sintered at a relatively low temperature of 810°C to high density, without using any sintering aid. The surface morphology of the sintered sample was analyzed by scanning electron microscopy. The dielectric constant and loss factor of the sample measured at 5 MHz were found to be 10.50 and 1.56 × 10-3 at room temperature. The temperature coefficient of the dielectric constant was -88.71 ppm/°C. The experimental results obtained in this work demonstrate the potential of nano-CaWO4 as a low-temperature co-fired ceramic as well as an excellent luminescent material.

  5. Effects of CO_2 Dilution on Methane Ignition in Moderate or Intense Low-oxygen Dilution(MILD) Combustion:A Numerical Study

    Institute of Scientific and Technical Information of China (English)

    曹甄俊; 朱彤


    Homogeneous mixtures of CH4/air under moderate or intense low-oxygen dilution(MILD) combustion conditions were numerically studied to clarify the fundamental effects of exhaust gas recirculation(EGR),espe-cially CO2 in EGR gases,on ignition characteristics.Specifically,effects of CO2 addition on autoignition delay time were emphasized at temperature between 1200 K and 1600 K for a wide range of the lean-to-rich equivalence ratio(0.2~2).The results showed that the ignition delay time increased with equivalence ratio or CO2 dilution ratio.Fur-thermore,ignition delay time was seen to be exponentially related with the reciprocal of initial temperature.Special concern was given to the chemical effects of CO2 on the ignition delay time.The enhancement of ignition delay time with CO2 addition can be mainly ascribed to the decrease of H,O and OH radicals.The predictions of tem-perature profiles and mole fractions of CO and CO2 were strongly related to the chemical effects of CO2.A single ignition time correlation was obtained in form of Arrhenius-type for the entire range of conditions as a function of temperature,CH4 mole fraction and O2 mole fraction.This correlation could successfully capture the complex be-haviors of ignition of CH4/air/CO2 mixture.The results can be applied to MILD combustion as "reference time",for example,to predict ignition delay time in turbulent reacting flow.

  6. Chemical kinetic modeling of H{sub 2} applications

    Energy Technology Data Exchange (ETDEWEB)

    Marinov, N.M.; Westbrook, C.K.; Cloutman, L.D. [Lawrence Livermore National Lab., CA (United States)] [and others


    Work being carried out at LLNL has concentrated on studies of the role of chemical kinetics in a variety of problems related to hydrogen combustion in practical combustion systems, with an emphasis on vehicle propulsion. Use of hydrogen offers significant advantages over fossil fuels, and computer modeling provides advantages when used in concert with experimental studies. Many numerical {open_quotes}experiments{close_quotes} can be carried out quickly and efficiently, reducing the cost and time of system development, and many new and speculative concepts can be screened to identify those with sufficient promise to pursue experimentally. This project uses chemical kinetic and fluid dynamic computational modeling to examine the combustion characteristics of systems burning hydrogen, either as the only fuel or mixed with natural gas. Oxidation kinetics are combined with pollutant formation kinetics, including formation of oxides of nitrogen but also including air toxics in natural gas combustion. We have refined many of the elementary kinetic reaction steps in the detailed reaction mechanism for hydrogen oxidation. To extend the model to pressures characteristic of internal combustion engines, it was necessary to apply theoretical pressure falloff formalisms for several key steps in the reaction mechanism. We have continued development of simplified reaction mechanisms for hydrogen oxidation, we have implemented those mechanisms into multidimensional computational fluid dynamics models, and we have used models of chemistry and fluid dynamics to address selected application problems. At the present time, we are using computed high pressure flame, and auto-ignition data to further refine the simplified kinetics models that are then to be used in multidimensional fluid mechanics models. Detailed kinetics studies have investigated hydrogen flames and ignition of hydrogen behind shock waves, intended to refine the detailed reactions mechanisms.

  7. Development and application of laser techniques for studying fuel dynamics and NO formation in engines

    Energy Technology Data Exchange (ETDEWEB)

    Andersson, Oeivind


    was detected using two-photon induced fluorescence. The two signals were imaged on different portions of the same CCD camera. Water is used in a number of combustion applications, but it would be a great advantage if this technique could be developed for application in fuel sprays. It could then be used as an alternative to the fluorescent-exciplex technique commonly used for two-phase detection in such applications. The exciplex technique requires an oxygen-free atmosphere and can thus not be used in real combustion environments. Fuel dynamics have also been studied in DME sprays, both in a combustion vessel and in an optical diesel truck engine. The studies were made using laser-Rayleigh imaging and provided interesting information about the general development and autoignition of these sprays. Among other things it was found that autoignition occurred differently in the two environments. In the vessel, the sprays ignited around the periphery where fuel/air mixtures were close to stoichiometric. In the engine, however ignition occurred volumetrically throughout the cross section of the spray vortex. There is reason to believe that mixtures were fuel-rich in this region. The explanation for the different behaviours is assumed to be found in the temperature and density conditions of the atmospheres into which the sprays were injected. The results show that sprays can behave quite differently in different environments. A thorough study of the effects of temperature, density, and EGR on autoignition in sprays is highly desirable, since current models do not seem to give a general description of the phenomenon. Both the measurements in the DISI engine and the NO measurements in the SI engine show that laser spectroscopic techniques can be used for improving and developing computer-based design tools. In the case of the DISI engine, the data were used to validate results from CFD codes used for engine design. The NO data provided a database for development of a model for

  8. Combustion and emission characteristics of jet controlled compression ignition engine at different loads%射流控制压缩着火发动机不同负荷下燃烧及排放特性

    Institute of Scientific and Technical Information of China (English)

    张强; 杨培源; 隆武强; 田江平


    针对柴油预混合气着火相位难以直接控制的问题,提出射流控制压缩着火(jet controlled compression ignition, JCCI)方式。将一台单缸农用柴油机改造为JCCI发动机:压缩比降至12,增加一个带液化石油气(liquefied petroleum gas, LPG)供给通道和火花塞的点火室,并进行了JCCI发动机全负荷特性试验研究。试验结果表明:采用射流控制压缩着火方式可以有效控制发动机的燃烧相位和排放。在平均有效压力低于0.44 MPa的工况范围,NOx排放比原机降低较多,燃烧始点相位CA10与滞燃期几乎不随负荷增加而改变;在平均有效压力高于0.44直至0.54 MPa负荷范围内,燃烧始点相位迅速前移,滞燃期迅速减小,柴油提前自燃,射流对着火相位控制作用减弱,NOx排放迅速增加并超过原机;在全负荷范围,烟度始终维持在低水平,HC和CO排放较高。该研究可为柴油预混合燃烧着火相位控制提供参考。%One of the key points in diesel premixed combustion is the realization of combustion phasing control. The sensitivity of diesel to temperature and equivalent ratio was the crucial obstacle. In order to directly control the diesel premixed combustion phasing, a novel method called the jet controlled compression ignition (JCCI) for diesel premixed compression ignition was proposed. A single cylinder diesel engine was modified to study the JCCI system. First, a small ignition chamber comprising a gas fuel injector and a spark plug was mounted on the cylinder head in this diesel engine. Six small orifices were used to connect the ignition chamber and the main chamber. Furthermore, the compression ratio was reduced to 12 to avoid the auto-ignition of the premixed diesel fuel. Experiments were conducted on the JCCI engine under overall loads at a constant speed to study the trend of combustion and the emission characteristics of JCCI system. The results showed that

  9. Development and application of laser techniques for studying fuel dynamics and NO formation in engines

    Energy Technology Data Exchange (ETDEWEB)

    Andersson, Oeivind


    was detected using two-photon induced fluorescence. The two signals were imaged on different portions of the same CCD camera. Water is used in a number of combustion applications, but it would be a great advantage if this technique could be developed for application in fuel sprays. It could then be used as an alternative to the fluorescent-exciplex technique commonly used for two-phase detection in such applications. The exciplex technique requires an oxygen-free atmosphere and can thus not be used in real combustion environments. Fuel dynamics have also been studied in DME sprays, both in a combustion vessel and in an optical diesel truck engine. The studies were made using laser-Rayleigh imaging and provided interesting information about the general development and autoignition of these sprays. Among other things it was found that autoignition occurred differently in the two environments. In the vessel, the sprays ignited around the periphery where fuel/air mixtures were close to stoichiometric. In the engine, however ignition occurred volumetrically throughout the cross section of the spray vortex. There is reason to believe that mixtures were fuel-rich in this region. The explanation for the different behaviours is assumed to be found in the temperature and density conditions of the atmospheres into which the sprays were injected. The results show that sprays can behave quite differently in different environments. A thorough study of the effects of temperature, density, and EGR on autoignition in sprays is highly desirable, since current models do not seem to give a general description of the phenomenon. Both the measurements in the DISI engine and the NO measurements in the SI engine show that laser spectroscopic techniques can be used for improving and developing computer-based design tools. In the case of the DISI engine, the data were used to validate results from CFD codes used for engine design. The NO data provided a database for development of a model for

  10. An experimental study of different hydrocarbon components in natural gas and their impact on engine performance in a HCCI engine

    Energy Technology Data Exchange (ETDEWEB)

    Aaberg, Kristoffer


    Natural gas is a well suited fuel for HCCI (Homogenous Charge Compression Ignition) operation. Commercial natural gas consists of many different hydrocarbons where the lighter hydrocarbons, methane, ethane propane and butane are the most common and methane having the highest percentage. The composition of natural gas varies widely all over the world. It is well known that the higher hydrocarbons have a great impact on the ignition characteristics. As a spontaneous auto-ignition process initiates HCCI, this type of engine is very sensitive of the fuels ignition characteristics. To investigate the influence of the higher hydrocarbons an extensive test series was carried out. The impact of different concentrations of ethane, propane, iso- and n-butane were tested. Using different equivalence ratios, concentrations of the hydrocarbons, levels of EGR and levels of boost pressure the tests were carried out. Data collected during the testing were emission, mass flow, indicated mean effective pressure, inlet temperature and engine speed. From these data, specific emissions and efficiencies could be calculated. As a test a value of released heat per cycle was also evaluated, and used to check the mass flow. The results show that the ignition characteristics of the charge is very sensitive to fuel composition. A strong connection between the required inlet air temperature and the fuel composition was detected. With an increasing amount of heavier components in the gas, this temperature was decreased. This is connected to the octane number of the components. Much of the engine performance can be related to this change of temperature. Emissions and power output (imep) showed the highest dependency of the concentration of component gas. Butanes had the highest impact on the inlet temperature, followed by propane and ethane. With the use of 20% EGR the inlet temperature had to be raised. The impact of the component gases was the same as with no EGR. The combustion efficiency

  11. Homogeneous charge compression ignition (HCCI) - A comparison with spark ignition (SI) operation

    Energy Technology Data Exchange (ETDEWEB)

    Christensen, Magnus


    Homogeneous Charge Compression Ignition (HCCI) is the third alternative for combustion in engines. Here a homogeneous premixed charge is used as in a spark ignited engine but the charge is compressed to auto-ignition as in a diesel. The characteristics of HCCI was compared to spark ignition (SI) using a 1.6 liter single cylinder engine. Three different fuels were used; isooctane, ethanol and natural gas. HCCI could be used with all three fuels in a single cylinder engine with a fixed compression ratio. Some remarkable results were noted in the experiments. The indicated efficiency of HCCI was much better than for SI operation. The gross indicated efficiency showed values at 50% for the richer cases. This means that the fuel consumption at part load would be reduced to the half compared to SI operation. Very little NO{sub x} was generated with HCCI, only a few ppm. With isooctane, it ranged from 4 to below 1 ppm and with ethanol even lower values. However, HCCI generated more HC and CO. Operation was noisier with HCCI than with SI. Stable and efficient operation with HCCI could be obtained with {lambda} = 3.5 to 9 using isooctane, 3.5 to 6.5 using ethanol, and 2.5 to 3.5 using natural gas. Cycle to cycle variation of combustion was very low. Isooctane could be operated unthrottled without preheating. The selection of the high compression ratio, 21:1, was dependent on the high octane number for natural gas. The attainable IMEP was 5 bar. The limit to make higher IMEP was the rate of combustion. At IMEP 5 bar the main combustion, 10-90% burn duration, took place in less than 2 crank angle degrees (CAD). This is extremely fast and gives very high rate of pressure rise, which leads to noisy operation and high loads on the engine. The lean limit was given by unstable combustion with cycle to cycle variation of combustion, and with high emissions of unburned hydrocarbons and carbon monoxide Examination paper. 15 refs, 38 figs, 1 tab

  12. 缸内直喷发动机快速起动首循环喷雾的数值模拟%Numerical Simulation of First Cycle Spray during Quick Start for In-cylinder Direct Injection Engine

    Institute of Scientific and Technical Information of China (English)

    韩立伟; 洪伟; 高定伟; 苏岩; 谢方喜


    基于某缸内直喷(GDI)发动机建立了三维模拟平台,并对喷雾模型进行了验证,进而对GDI发动机起动时第2缸的喷雾和混合气形成进行了数值模拟,分析了不同喷油策略下压缩上止点时混合气的空燃比分布和着火情况,并与试验结果进行了对比分析。研究结果表明:喷油时刻距离上止点相对较远或者在上止点附近时,混合气在压缩上止点倾向于自燃;若混合气偏稀,即使喷油时刻在距离上止点相对中间的位置时,混合气仍倾向于自燃。通过试验结合数值模拟的方法,分析并指出了第2缸在不同喷油策略下发生自燃、可以点燃和失火的区域。%The 3D simulation platform for a gasoline direct injection (GDI) engine was established ,the spray model was veri-fied ,and the spray and gas mixture formation of the second cylinder during engine start was simulated .The air-fuel ratio and ignition condition at top dead centre (TDC) under different injection strategies were analyzed and compared with experimental results .The results show that the compressed mixture is easy to ignite spontaneously when the injection timing is relatively far from or is close to TDC .The lean mixture is still inclined to ignite spontaneously even though the injection timing is relatively middle from TDC .Through the test and numerical simulation ,the areas of auto-ignition ,ignition and misfire for the second cylinder are finally determined under different injection strategies .

  13. Multi-zone modelling of partially premixed low-temperature combustion in pilot-ignited natural-gas engines

    Energy Technology Data Exchange (ETDEWEB)

    Krishnan, S. R.; inivasan, K. K.


    Detailed results from a multi-zone phenomenological simulation of partially premixed advanced-injection low-pilot-ignited natural-gas low-temperature combustion are presented with a focus on early injection timings (the beginning of (pilot) injection (BOI)) and very small diesel quantities (2-3 per cent of total fuel energy). Combining several aspects of diesel and spark ignition engine combustion models, the closed-cycle simulation accounted for diesel autoignition, diesel spray combustion, and natural-gas combustion by premixed turbulent flame propagation. The cylinder contents were divided into an unburned zone, several pilot fuel zones (or 'packets') that modelled diesel evaporation and ignition, a flame zone for natural-gas combustion, and a burned zone. The simulation predicted the onset of ignition, cylinder pressures, and heat release rate profiles satisfactorily over a wide range of BOIs (20-60° before top dead centre (before TDC)) but especially well at early BOIs. Strong coupling was observed between pilot spray combustion in the packets and premixed turbulent combustion in the flame zone and, therefore, the number of ignition centres (packets) profoundly affected flame combustion. The highest local peak temperatures (greater than 2000 K) were observed in the packets, while the flame zone was much cooler (about 1650 K), indicating that pilot diesel spray combustion is probably the dominant source of engine-out emissions of nitrogen oxide (NOx). Further, the 60° before TDC BOI yielded the lowest average peak packet temperatures (about 1720 K) compared with the 20° before TDC BOI (about 2480 K) and 40° before TDC BOI (about 2700 K). These trends support experimental NOx trends, which showed the lowest NOx emissions for the 60°, 20°, and 40° before TDC BOIs in that order. Parametric studies showed that increasing the intake charge temperature, pilot quantity, and natural-gas equivalence ratio all led to


    Energy Technology Data Exchange (ETDEWEB)

    Simmons, F.; Kuntamukkula, M.; Alnajjar, M.; Quigley, D.; Freshwater, D.; Bigger, S.


    Pyrophoric reagents represent an important class of reactants because they can participate in many different types of reactions. They are very useful in organic synthesis and in industrial applications. The Occupational Safety and Health Administration (OSHA) and the National Fire Protection Association (NFPA) define Pyrophorics as substances that will self-ignite in air at temperatures of 130 F (54.4 C) or less. However, the U.S. Department of Transportation (DOT) uses criteria different from the auto-ignition temperature criterion. The DOT defines a pyrophoric material as a liquid or solid that, even in small quantities and without an external ignition source, can ignite within five minutes after coming in contact with air when tested according to the United Nations Manual of Tests and Criteria. The Environmental Protection Agency has adopted the DOT definition. Regardless of which definition is used, oxidation of the pyrophoric reagents by oxygen or exothermic reactions with moisture in the air (resulting in the generation of a flammable gas such as hydrogen) is so rapid that ignition occurs spontaneously. Due to the inherent nature of pyrophoric substances to ignite spontaneously upon exposure to air, special precautions must be taken to ensure their safe handling and use. Pyrophoric gases (such as diborane, dichloroborane, phosphine, etc.) are typically the easiest class of pyrophoric substances to handle since the gas can be plumbed directly to the application and used remotely. Pyrophoric solids and liquids, however, require the user to physically manipulate them when transferring them from one container to another. Failure to follow proper safety precautions could result in serious injury or unintended consequences to laboratory personnel. Because of this danger, pyrophorics should be handled only by experienced personnel. Users with limited experience must be trained on how to handle pyrophoric reagents and consult with a knowledgeable staff member prior

  15. Oxygen Compatibility of Brass-Filled PTFE Compared to Commonly Used Fluorinated Polymers for Oxygen Systems (United States)

    Herald, Stephen D.; Frisby, Paul M.; Davis, Samuel Eddie


    Safe and reliable seal materials for high-pressure oxygen systems sometimes appear to be extinct species when sought out by oxygen systems designers. Materials that seal well are easy to find, but these materials are typically incompatible with oxygen, especially in cryogenic liquid form. This incompatibility can result in seals that leak, or much worse, seals that easily ignite and burn during use. Materials that are compatible with oxygen are easy to find, such as the long list of compatible metals, but these metallic materials are limiting as seal materials. A material that seals well and is oxygen compatible has been the big game in the designer's safari. Scientists at the Materials Combustion Research Facility (MCRF), part of NASA/Marshall Space Flight Center (MSFC), are constantly searching for better materials and processes to improve the safety of oxygen systems. One focus of this effort is improving the characteristics of polymers used in the presence of an oxygen enriched environment. Very few systems can be built which contain no polymeric materials; therefore, materials which have good impact resistance, low heat of combustion, high auto-ignition temperature and that maintain good mechanical properties are essential. The scientists and engineers at the Materials Combustion Research Facility, in cooperation with seal suppliers, are currently testing a new formulation of polytetrafluoroethylene (PTFE) with Brass filler. This Brass-filled PTFE is showing great promise as a seal and seat material for high pressure oxygen systems. Early research has demonstrated very encouraging results, which could rank this material as one of the best fluorinated polymers ever tested. This paper will compare the data obtained for Brass-filled PTFE with other fluorinated polymers, such as TFE-Teflon (PTFE) , Kel-F 81, Viton A, Viton A-500, Fluorel , and Algoflon . A similar metal filled fluorinated polymer, Salox-M , was tested in comparison to Brass-filled PTFE to

  16. Relativistic outflow from two thermonuclear shell flashes on neutron stars (United States)

    in't Zand, J. J. M.; Keek, L.; Cavecchi, Y.


    We study the exceptionally short (32-43 ms) precursors of two intermediate-duration thermonuclear X-ray bursts observed with the Rossi X-ray Timing Explorer from the neutron stars in 4U 0614+09 and 2S 0918-549. They exhibit photon fluxes that surpass those at the Eddington limit later in the burst by factors of 2.6 to 3.1. We are able to explain both the short duration and the super-Eddington flux by mildly relativistic outflow velocities of 0.1c to 0.3c subsequent to the thermonuclear shell flashes on the neutron stars. These are the highest velocities ever measured from any thermonuclear flash. The precursor rise times are also exceptionally short: about 1 ms. This is inconsistent with predictions for nuclear flames spreading laterally as deflagrations and suggests detonations instead. This is the first time that a detonation is suggested for such a shallow ignition column depth (yign ≈ 1010 g cm-2). The detonation would possibly require a faster nuclear reaction chain, such as bypassing the α-capture on 12C with the much faster 12C(p,γ)13N(α,p)16O process previously proposed. We confirm the possibility of a detonation, albeit only in the radial direction, through the simulation of the nuclear burning with a large nuclear network and at the appropriate ignition depth, although it remains to be seen whether the Zel'dovich criterion is met. A detonation would also provide the fast flame spreading over the surface of the neutron star to allow for the short rise times. This needs to be supported by future two-dimensional calculations of flame spreading at the relevant column depth. As an alternative to the detonation scenario, we speculate on the possibility that the whole neutron star surface burns almost instantly in the auto-ignition regime. This is motivated by the presence of 150 ms precursors with 30 ms rise times in some superexpansion bursts from 4U 1820-30 at low ignition column depths of ~108 g cm-2.

  17. Development and validation of an n-dodecane skeletal mechanism for spray combustion applications

    KAUST Repository

    Luo, Zhaoyu


    n-Dodecane is a promising surrogate fuel for diesel engine study because its physicochemical properties are similar to those of the practical diesel fuels. In the present study, a skeletal mechanism for n-dodecane with 105 species and 420 reactions was developed for spray combustion simulations. The reduction starts from the most recent detailed mechanism for n-alkanes consisting of 2755 species and 11,173 reactions developed by the Lawrence Livermore National Laboratory. An algorithm combining direct relation graph with expert knowledge (DRGX) and sensitivity analysis was employed for the present skeletal reduction. The skeletal mechanism was first extensively validated in 0-D and 1-D combustion systems, including auto-ignition, jet stirred reactor (JSR), laminar premixed flame and counter flow diffusion flame. Then it was coupled with well-established spray models and further validated in 3-D turbulent spray combustion simulations under engine-like conditions. These simulations were compared with the recent experiments with n-dodecane as a surrogate for diesel fuels. It can be seen that combustion characteristics such as ignition delay and flame lift-off length were well captured by the skeletal mechanism, particularly under conditions with high ambient temperatures. Simulations also captured the transient flame development phenomenon fairly well. The results further show that ignition delay may not be the only factor controlling the stabilisation of the present flames since a good match in ignition delay does not necessarily result in improved flame lift-off length prediction. The work of Zhaoyu Luo, Sibendu Som, Max Plomer, William J. Pitz, Douglas E. Longman and Tianfeng Lu was authored as part of their official duties as Employees of the United States Government and is therefore a work of the United States Government. In accordance with 17 USC. 105, no copyright protection is available for such works under US Law. S. Mani Sarathy hereby waives his right to

  18. Direct numerical simulations of the ignition of a lean biodiesel/air mixture with temperature and composition inhomogeneities at high pressure and intermediate temperature

    KAUST Repository

    Luong, Minhbau


    The effects of the stratifications of temperature, T, and equivalence ratio, φ{symbol}, on the ignition characteristics of a lean homogeneous biodiesel/air mixture at high pressure and intermediate temperature are investigated using direct numerical simulations (DNSs). 2-D DNSs are performed at a constant volume with the variance of temperature and equivalence ratio (T′ and φ{symbol}′) together with a 2-D isotropic velocity spectrum superimposed on the initial scalar fields. In addition, three different T s(-) φ{symbol} correlations are investigated: (1) baseline cases with T′ only or φ{symbol}′ only, (2) uncorrelated T s(-) φ{symbol} distribution, and (3) negatively-correlated T s(-) φ{symbol} distribution. It is found that the overall combustion is more advanced and the mean heat release rate is more distributed over time with increasing T′ and/or φ{symbol}′ for the baseline and uncorrelated T s(-) φ{symbol} cases. However, the temporal advancement and distribution of the overall combustion caused by T′ or φ{symbol}′ only are nearly annihilated by the negatively-correlated T s(-) φ{symbol} fields. The chemical explosive mode and Damköhler number analyses verify that for the baseline and uncorrelated T s(-) φ{symbol} cases, the deflagration mode is predominant at the reaction fronts for large T′ and/or φ{symbol}′. On the contrary, the spontaneous ignition mode prevails for cases with small T′ or φ{symbol}′, especially for cases with negative T s(-) φ{symbol} correlations, and hence, simultaneous auto-ignition occurs throughout the entire domain, resulting in an excessive rate of heat release. It is also found that turbulence with large intensity, u′, and a short time scale can effectively smooth out initial thermal and compositional fluctuations such that the overall combustion is induced primarily by spontaneous ignition. Based on the present DNS results, the generalization of the effects of T′, φ{symbol}′, and u

  19. Opposed Jet Burner Extinction Limits: Simple Mixed Hydrocarbon Scramjet Fuels vs Air (United States)

    Pellett, Gerald L.; Vaden, Sarah N.; Wilson, Lloyd G.


    Opposed Jet Burner tools have been used extensively by the authors to measure Flame Strength (FS) of laminar non-premixed H2 air and simple hydrocarbon (HC) air counterflow diffusion flames at 1-atm. FS represents a strain-induced extinction limit based on air jet velocity. This paper follows AIAA-2006-5223, and provides new HC air FSs for global testing of chemical kinetics, and for characterizing idealized flameholding potentials during early scramjet-like combustion. Previous FS data included six HCs, pure and N2-diluted; and three HC-diluted H2 fuels, where FS decayed very nonlinearly as HC was added to H2, due to H-atom scavenging. This study presents FSs on mixtures of (candidate surrogate) HCs, some with very high FS ethylene. Included are four binary gaseous systems at 300 K, and a hot ternary system at approx. 600 K. The binaries are methane + ethylene, ethane + ethylene, methane + ethane, and methane + propylene. The first three also form two ternary systems. The hot ternary includes both 10.8 and 21.3 mole % vaporized n-heptane and full ranges of methane + ethylene. Normalized FS data provide accurate means of (1) validating, globally, chemical kinetics for extinction of non-premixed flames, and (2) estimating (scaling by HC) the loss of incipient flameholding in scramjet combustors. The n-heptane is part of a proposed baseline simulant (10 mole % with 30% methane + 60% ethylene) that mimics the ignition of endothermically cracked JP-7 like kerosene fuel, as suggested by Colket and Spadaccini in 2001 in their shock tube Scramjet Fuels Autoignition Study. Presently, we use FS to gauge idealized flameholding, and define HC surrogates. First, FS was characterized for hot nheptane + methane + ethylene; then a hot 36 mole % methane + 64% ethylene surrogate was defined that mimics FS of the baseline simulant system. A similar hot ethane + ethylene surrogate can also be defined, but it has lower vapor pressure at 300 K, and thus exhibits reduced gaseous

  20. Hydrogen-or-Fossil-Combustion Nuclear Combined-Cycle Systems for Base- and Peak-Load Electricity Production

    Energy Technology Data Exchange (ETDEWEB)

    Forsberg, Charles W [ORNL; Conklin, Jim [ORNL


    A combined-cycle power plant is described that uses (1) heat from a high-temperature nuclear reactor to meet base-load electrical demands and (2) heat from the same high-temperature reactor and burning natural gas, jet fuel, or hydrogen to meet peak-load electrical demands. For base-load electricity production, fresh air is compressed; then flows through a heat exchanger, where it is heated to between 700 and 900 C by heat provided by a high-temperature nuclear reactor via an intermediate heat-transport loop; and finally exits through a high-temperature gas turbine to produce electricity. The hot exhaust from the Brayton-cycle gas turbine is then fed to a heat recovery steam generator that provides steam to a steam turbine for added electrical power production. To meet peak electricity demand, the air is first compressed and then heated with the heat from a high-temperature reactor. Natural gas, jet fuel, or hydrogen is then injected into the hot air in a combustion chamber, combusts, and heats the air to 1300 C-the operating conditions for a standard natural-gas-fired combined-cycle plant. The hot gas then flows through a gas turbine and a heat recovery steam generator before being sent to the exhaust stack. The higher temperatures increase the plant efficiency and power output. If hydrogen is used, it can be produced at night using energy from the nuclear reactor and stored until needed. With hydrogen serving as the auxiliary fuel for peak power production, the electricity output to the electric grid can vary from zero (i.e., when hydrogen is being produced) to the maximum peak power while the nuclear reactor operates at constant load. Because nuclear heat raises air temperatures above the auto-ignition temperatures of the various fuels and powers the air compressor, the power output can be varied rapidly (compared with the capabilities of fossil-fired turbines) to meet spinning reserve requirements and stabilize the electric grid. This combined cycle uses the

  1. Theoretical kinetics studies of two model reactions in biodiesel and diesel combustion (United States)

    Sha, Yuan

    We use 1-methylallyl radical (CH3CH=CH-CH2· ↔ CH3C·H-CH=CH2·) as a model of allylic radicals generated during combustion of unsaturated diesel fuel molecules. The chemically activated isomerization of 1-methylallyl generated in the highly exothermic (˜35 kcal/mol) OH + trans-2-butene reaction was considered by using RRKM/Master Equation calculations from 0.01 to 100 atm and from 300 to 700 K. Density functional theory (DFT) with the M05-2X, M06-2X and B3LYP functionals are used for structures, energies, vibrational frequencies, anharmonic constants, and the torsional potentials of methyl rotations. The cis:trans ratio formed upon quenching the radicals were, as might be expected, dependent on the functional, but, were even more sensitive when an vibrations were treated as anharmonic. The fraction of cis- 1-methylallyl is significant, if not dominant at 300 -700 K and 0.01 -10 atm. Sensitivity studies were carried out to determine the dependence of the cis:trans ratio on the extent of chemical activation, treatment of the K-rotor as active or inactive, and the rate of collisional energy transfer. All these parameters significantly influence the cis:trans ratio. The 1,5 H-migration reaction of 3-hydroperoxy-1-propylperoxy radical (HOOCH2CH2CH2OO·) is a important as a model of a critical propagation step in diesel autoignition from alkanes or molecules with long alkyl tails. Its product may be the meta-stable alpha,gamma-dihydroperoxypropyl radical or, if unstable, OH + 3-hydroperoxypropanal. To study the possibly different tunneling effects of the two possible products, the quantum mechanical rate constants, including tunneling, are directly determined using semi-classical transition state theory (SCTST) at 200 K to 1700 K. Small-curvature tunneling (SCT) is to compute tunneling corrections to classical rate constants. The two reactions do not have obvious tunneling differences at above 700 K. Below 700 K, SCTST tunneling corrections are significantly higher

  2. Structure and stabilization of hydrogen-rich transverse.

    Energy Technology Data Exchange (ETDEWEB)

    Lyra, Sgouria [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Wilde, B [Georgia Inst. of Technology, Atlanta, GA (United States); Kolla, Hemanth [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Seitzman, J. [Georgia Inst. of Technology, Atlanta, GA (United States); Lieuwen, T. C. [Georgia Inst. of Technology, Atlanta, GA (United States); Chen, Jacqueline H. [Sandia National Lab. (SNL-CA), Livermore, CA (United States)


    This paper reports the results of a joint experimental and numerical study of the ow characteristics and flame stabilization of a hydrogen rich jet injected normal to a turbulent, vitiated cross ow of lean methane combustion products. Simultaneous high-speed stereoscopic PIV and OH PLIF measurements were obtained and analyzed alongside three-dimensional direct numerical simulations of inert and reacting JICF with detailed H2/CO chemistry. Both the experiment and the simulation reveal that, contrary to most previous studies of reacting JICF stabilized in low-to-moderate temperature air cross ow, the present conditions lead to an autoigniting, burner-attached flame that initiates uniformly around the burner edge. Significant asymmetry is observed, however, between the reaction zones located on the windward and leeward sides of the jet, due to the substantially different scalar dissipation rates. The windward reaction zone is much thinner in the near field, while also exhibiting significantly higher local and global heat release than the much broader reaction zone found on the leeward side of the jet. The unsteady dynamics of the windward shear layer, which largely control the important jet/cross flow mixing processes in that region, are explored in order to elucidate the important flow stability implications arising in the reacting JICF. Vorticity spectra extracted from the windward shear layer reveal that the reacting jet is globally unstable and features two high frequency peaks, including a fundamental mode whose Strouhal number of ~0.7 agrees well with previous non-reacting JICF stability studies. The paper concludes with an analysis of the ignition, ame stabilization, and global structure of the burner-attached flame. Chemical explosive mode analysis (CEMA) shows that the entire windward shear layer, and a large region on the leeward side of the jet, are highly explosive prior to ignition and are dominated by non-premixed flame structures after

  3. Analysis of Thermal and Chemical Effets on Negative Valve Overlap Period Energy Recovery for Low-Temperature Gasoline Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Ekoto, Dr Isaac [Sandia National Laboratories (SNL); Peterson, Dr. Brian [University of Edinburgh; Szybist, James P [ORNL; Northrop, Dr. William [University of Minnesota


    A central challenge for efficient auto-ignition controlled low-temperature gasoline combustion (LTGC) engines has been achieving the combustion phasing needed to reach stable performance over a wide operating regime. The negative valve overlap (NVO) strategy has been explored as a way to improve combustion stability through a combination of charge heating and altered reactivity via a recompression stroke with a pilot fuel injection. The study objective was to analyze the thermal and chemical effects on NVO-period energy recovery. The analysis leveraged experimental gas sampling results obtained from a single-cylinder LTGC engine along with cylinder pressure measurements and custom data reduction methods used to estimate period thermodynamic properties. The engine was fueled by either iso-octane or ethanol, and operated under sweeps of NVO-period oxygen concentration, injection timing, and fueling rate. Gas sampling at the end of the NVO period was performed via a custom dump-valve apparatus, with detailed sample speciation by in-house gas chromatography. The balance of NVO-period input and output energy flows was calculated in terms of fuel energy, work, heat loss, and change in sensible energy. Experiment results were complemented by detailed chemistry single-zone reactor simulations performed at relevant mixing and thermodynamic conditions, with results used to evaluate ignition behavior and expected energy recovery yields. For the intermediate bulk-gas temperatures present during the NVO period (900-1100 K), weak negative temperature coefficient behavior with iso-octane fueling significantly lengthened ignition delays relative to similar ethanol fueled conditions. Faster ethanol ignition chemistry led to lower recovered fuel intermediate yields relative to similar iso-octane fueled conditions due to more complete fuel oxidation. From the energy analysis it was found that increased NVO-period global equivalence ratio, either from lower NVOperiod oxygen

  4. Thermodynamic and fluid mechanic analysis of rapid pressurization in a dead-end tube (United States)

    Leslie, Ian H.


    Three models have been applied to very rapid compression of oxygen in a dead-ended tube. Pressures as high as 41 MPa (6000 psi) leading to peak temperatures of 1400 K are predicted. These temperatures are well in excess of the autoignition temperature (750 K) of teflon, a frequently used material for lining hoses employed in oxygen service. These findings are in accord with experiments that have resulted in ignition and combustion of the teflon, leading to the combustion of the stainless steel braiding and catastrophic failure. The system analyzed was representative of a capped off-high-pressure oxygen line, which could be part of a larger system. Pressurization of the larger system would lead to compression in the dead-end line, and possible ignition of the teflon liner. The model consists of a large plenum containing oxygen at the desired pressure (500 to 6000 psi). The plenum is connected via a fast acting valve to a stainless steel tube 2 cm inside diameter. Opening times are on the order of 15 ms. Downstream of the valve is an orifice sized to increase filling times to around 100 ms. The total length from the valve to the dead-end is 150 cm. The distance from the valve to the orifice is 95 cm. The models describe the fluid mechanics and thermodynamics of the flow, and do not include any combustion phenomena. A purely thermodynamic model assumes filling to be complete upstream of the orifice before any gas passes through the orifice. This simplification is reasonable based on experiment and computer modeling. Results show that peak temperatures as high as 4800 K can result from recompression of the gas after expanding through the orifice. An approximate transient model without an orifice was developed assuming an isentropic compression process. An analytical solution was obtained. Results indicated that fill times can be considerably shorter than valve opening times. The third model was a finite difference, 1-D transient compressible flow model. Results from

  5. Heat production in depth up to 2500m via in situ combustion of methane using a counter-current heat-exchange reactor (United States)

    Schicks, Judith Maria; Spangenberg, Erik; Giese, Ronny; Heeschen, Katja; Priegnitz, Mike; Luzi-Helbing, Manja; Thaler, Jan; Abendroth, Sven; Klump, Jens


    In situ combustion is a well-known method used for exploitation of unconventional oil deposits such as heavy oil/bitumen reservoirs where the required heat is produced directly within the oil reservoir by combustion of a small percentage of the oil. A new application of in situ combustion for the production of methane from hydrate-bearing sediments was tested at pilot plant scale within the first phase of the German national gas hydrate project SUGAR. The applied method of in situ combustion was a flameless, catalytic oxidation of CH4 in a counter-current heat-exchange reactor with no direct contact between the catalytic reaction zone and the reservoir. The catalyst permitted a flameless combustion of CH4 with air to CO2 and H2O below the auto-ignition temperature of CH4 in air (868 K) and outside the flammability limits. This led to a double secured application of the reactor. The relatively low reaction temperature allowed the use of cost-effective standard materials for the reactor and prevented NOx formation. Preliminary results were promising and showed that only 15% of the produced CH4 was needed to be catalytically burned to provide enough heat to dissociate the hydrates in the environment and release CH4. The location of the heat source right within the hydrate-bearing sediment is a major advantage for the gas production from natural gas hydrates as the heat is generated where it is needed without loss of energy due to transportation. As part of the second period of the SUGAR project the reactor prototype of the first project phase was developed further to a borehole tool. The dimensions of this counter-current heat-exchange reactor are about 540 cm in length and 9 cm in diameter. It is designed for applications up to depths of 2500 m. A functionality test and a pressure test of the reactor were successfully carried out in October 2013 at the continental deep drilling site (KTB) in Windischeschenbach, Germany, in 600 m depth and 2000 m depth, respectively

  6. Automatic analysis and reduction of reaction mechanisms for complex fuel combustion

    Energy Technology Data Exchange (ETDEWEB)

    Nilsson, Daniel


    general, detailed calculations of temperature, pressure, concentration and flame velocity show excellent agreement with measurements. Skeletal mechanisms for PRF were constructed for the SI engine case, reproducing autoignition well on removal of reactions pertaining to 15% of the species. QSSA reduction was tested on the staged combustor and the engines, using pure and weighted lifetime indices. Monitoring NO concentrations in the staged combustor and ignition timing in the engines, good reproduction is possible while approximating about 70% of the species. However, some species have to be manually retained for accuracy and numerical stability. For improved ranking, sensitivity was added to the index applied to the premixed flames, in addition to necessary molecular transport information. The maximum atomic mass fraction occupied by a certain molecular species was also constrained to limit the mass and energy deficiency caused by QSSA. For methane, the laminar flame velocities as well as concentration profiles are well predicted by the most strongly reduced mechanism with five global reaction steps. For the kerosene surrogate mechanism, QSSA involving 50% of the species was successfully attempted.

  7. 高压瓦斯泄放自燃实验研究%Experimental study on self-ignition during discharge of high-pressure gas

    Institute of Scientific and Technical Information of China (English)

    余明高; 赵万里; 游浩


    Experimental system of self-ignition during discharge of high-pressure gas was designed and built, then self-ignition conditions of high-pressure gas in addition to its jet flame of nozzle propagating rule were investigated. The ex-perimental facility and test system were composed of high-pressure gas reservoir and conveying system, data acquisition and measurement system, rupture disk clamping system and the downstream releasing piping system. The results indi-cate that the self-ignition phenomenon is occurred during abrupt discharge of high-pressure gas into the atmosphere on some discharge conditions of discharging initial pressure and the downstream piping length, when higher pressure, the possibility of self-ignition is occurred with a short piping, furthermore, the pressure at which the auto-ignition is oc-curred appeared to be decreased with increasing the piping length. When self-ignition during discharge of high-pres-sure gas, energy of flame and shock is declined, shock wave velocity and overpressure also is decreased gradually with distance of flame propagation increasing, however, peak of overpressure of which damping is reduced gradually.%自行设计和搭建高压瓦斯泄放自燃实验平台,研究了高压瓦斯泄放自燃的发生条件及自燃时喷口射流火焰的传播规律.实验装置及测试系统由高压储瓦斯和输送系统、数据采集与测量系统、爆破片夹持系统和下游管道释放系统等设备组成.由实验得到,在一定泄放初始压力和下游释放管道长度条件下,高压瓦斯泄放到大气过程中会引发自燃现象;且在下游管道长度较短时,只有当泄放初压较高时才能引发自燃,而当下游管道长度增长时,发生自燃时的泄放初压会随之下降.高压瓦斯泄放自燃时,下游管道喷口射流火焰随其传播距离的增大,火焰及激波能量不断衰减,激波速度及其超压值也随之不断减小,然而激波超压峰值减幅逐渐缩小.

  8. Structure and Dynamics of Fuel Jets Injected into a High-Temperature Subsonic Crossflow: High-Data-Rate Laser Diagnostic Investigation under Steady and Oscillatory Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Lucht, Robert [Purdue Univ., West Lafayette, IN (United States); Anderson, William [Purdue Univ., West Lafayette, IN (United States)


    An investigation of subsonic transverse jet injection into a subsonic vitiated crossflow is discussed. The reacting jet in crossflow (RJIC) system investigated as a means of secondary injection of fuel in a staged combustion system. The measurements were performed in test rigs featuring (a) a steady, swirling crossflow and (b) a crossflow with low swirl but significant oscillation in the pressure field and in the axial velocity. The rigs are referred to as the steady state rig and the instability rig. Rapid mixing and chemical reaction in the near field of the jet injection is desirable in this application. Temporally resolved velocity measurements within the wake of the reactive jets using 2D-PIV and OH-PLIF at a repetition rate of 5 kHz were performed on the RJIC flow field in a steady state water-cooled test rig. The reactive jets were injected through an extended nozzle into the crossflow which is located in the downstream of a low swirl burner (LSB) that produced the swirled, vitiated crossflow. Both H2/N2 and natural gas (NG)/air jets were investigated. OH-PLIF measurements along the jet trajectory show that the auto-ignition starts on the leeward side within the wake region of the jet flame. The measurements show that jet flame is stabilized in the wake of the jet and wake vortices play a significant role in this process. PIV and OH–PLIF measurements were performed at five measurement planes along the cross- section of the jet. The time resolved measurements provided significant information on the evolution of complex flow structures and highly transient features like, local extinction, re-ignition, vortex-flame interaction prevalent in a turbulent reacting flow. Nanosecond-laser-based, single-laser-shot coherent anti-Stokes Raman scattering (CARS) measurements of temperature and H2 concentraiton were also performed. The structure and dynamics of a reacting transverse jet injected into a vitiated oscillatory crossflow presents a unique opportunity for

  9. Premixer Design for High Hydrogen Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Benjamin P. Lacy; Keith R. McManus; Balachandar Varatharajan; Biswadip Shome


    This 21-month project translated DLN technology to the unique properties of high hydrogen content IGCC fuels, and yielded designs in preparation for a future testing and validation phase. Fundamental flame characterization, mixing, and flame property measurement experiments were conducted to tailor computational design tools and criteria to create a framework for predicting nozzle operability (e.g., flame stabilization, emissions, resistance to flashback/flame-holding and auto-ignition). This framework was then used to establish, rank, and evaluate potential solutions to the operability challenges of IGCC combustion. The leading contenders were studied and developed with the most promising concepts evaluated via computational fluid dynamics (CFD) modeling and using the design rules generated by the fundamental experiments, as well as using GE's combustion design tools and practices. Finally, the project scoped the necessary steps required to carry the design through mechanical and durability review, testing, and validation, towards full demonstration of this revolutionary technology. This project was carried out in three linked tasks with the following results. (1) Develop conceptual designs of premixer and down-select the promising options. This task defined the ''gap'' between existing design capabilities and the targeted range of IGCC fuel compositions and evaluated the current capability of DLN pre-mixer designs when operated at similar conditions. Two concepts (1) swirl based and (2) multiple point lean direct injection based premixers were selected via a QFD from 13 potential design concepts. (2) Carry out CFD on chosen options (1 or 2) to evaluate operability risks. This task developed the leading options down-selected in Task 1. Both a GE15 swozzle based premixer and a lean direct injection concept were examined by performing a detailed CFD study wherein the aerodynamics of the design, together with the chemical kinetics of the

  10. A comprehensive experimental and detailed chemical kinetic modelling study of 2,5-dimethylfuran pyrolysis and oxidation. (United States)

    Somers, Kieran P; Simmie, John M; Gillespie, Fiona; Conroy, Christine; Black, Gráinne; Metcalfe, Wayne K; Battin-Leclerc, Frédérique; Dirrenberger, Patricia; Herbinet, Olivier; Glaude, Pierre-Alexandre; Dagaut, Philippe; Togbé, Casimir; Yasunaga, Kenji; Fernandes, Ravi X; Lee, Changyoul; Tripathi, Rupali; Curran, Henry J


    The pyrolytic and oxidative behaviour of the biofuel 2,5-dimethylfuran (25DMF) has been studied in a range of experimental facilities in order to investigate the relatively unexplored combustion chemistry of the title species and to provide combustor relevant experimental data. The pyrolysis of 25DMF has been re-investigated in a shock tube using the single-pulse method for mixtures of 3% 25DMF in argon, at temperatures from 1200-1350 K, pressures from 2-2.5 atm and residence times of approximately 2 ms. Ignition delay times for mixtures of 0.75% 25DMF in argon have been measured at atmospheric pressure, temperatures of 1350-1800 K at equivalence ratios (ϕ) of 0.5, 1.0 and 2.0 along with auto-ignition measurements for stoichiometric fuel in air mixtures of 25DMF at 20 and 80 bar, from 820-1210 K. This is supplemented with an oxidative speciation study of 25DMF in a jet-stirred reactor (JSR) from 770-1220 K, at 10.0 atm, residence times of 0.7 s and at ϕ = 0.5, 1.0 and 2.0. Laminar burning velocities for 25DMF-air mixtures have been measured using the heat-flux method at unburnt gas temperatures of 298 and 358 K, at atmospheric pressure from ϕ = 0.6-1.6. These laminar burning velocity measurements highlight inconsistencies in the current literature data and provide a validation target for kinetic mechanisms. A detailed chemical kinetic mechanism containing 2768 reactions and 545 species has been simultaneously developed to describe the combustion of 25DMF under the experimental conditions described above. Numerical modelling results based on the mechanism can accurately reproduce the majority of experimental data. At high temperatures, a hydrogen atom transfer reaction is found to be the dominant unimolecular decomposition pathway of 25DMF. The reactions of hydrogen atom with the fuel are also found to be important in predicting pyrolysis and ignition delay time experiments. Numerous proposals are made on the mechanism and kinetics of the previously unexplored

  11. Functional Diversity of Soil Microbial Community in Different Combustion Periods of Underground Coal Mine Fire%地下煤火不同燃烧阶段上覆土壤微生物群落功能多样性

    Institute of Scientific and Technical Information of China (English)

    胡雯; 张涛; 廖先燕; 吴尊凤; 牟文婷; 娄恺; 祖丽皮亚·玉努斯


    [Objective] The aim of the test was to reveal the functional diversity of microbial community in soils overlying during different periods of underground coal mine fire. [ Method ] BIOLOG metabolic fingerprinting method was used to analyze the functional diversity of soils overlying in weathering, oxidation, autoignition, complete combustion, sulphur emission, mirabilite emission and extinguish periods of underground coal mine fire in Jimsar County, Xinjiang. [ Result ] A distinct difference in the physiochemical property appeared among the soils overlying in different periods, and nitrate nitrogen reached to the maximum in spontaneous period, and organic matter was the lowest in extinguish period. Metabolic carbon sources for microbes in different periods were higher than the control site. Principal component analysis demonstrated that there was a clear difference in the two dimensions method by 31 kinds of carbon sources construction, which might suggest that microbial community structure of fire - impacted area changed dynamically. Correlation analysis revealed that soil Ph was remarkable factor of the carbon source utilization difference. [Conclusion] The functional diversity of microbial community in soils overlying was reduced by underground coal mine fire, and there was prominent difference in the diversity of microbial community, so these could afford reference about ecological restoration areas of underground coal mine fire.%[目的]了解不同燃烧阶段地下煤火上覆土壤微生物群落功能多样性.[方法]利用BIOLOG指纹图谱方法,分析新疆吉木萨尔县境内不同燃烧阶段地下煤火风化期、氧化期、自燃期、全面燃烧期、硫磺析出期、芒硝析出期和熄灭期的上覆土壤微生物功能多样性.[结果]地下煤火不同燃烧阶段上覆土壤理化性质差异显著,自燃期硝态氮含量最高,熄灭期有机质含量最低;不同时期微生物群落碳源利用能力及多样性均低于对照;主


    Energy Technology Data Exchange (ETDEWEB)

    Clifford E. Smith; Steven M. Cannon; Virgil Adumitroaie; David L. Black; Karl V. Meredith


    In this project, an advanced computational software tool was developed for the design of low emission combustion systems required for Vision 21 clean energy plants. Vision 21 combustion systems, such as combustors for gas turbines, combustors for indirect fired cycles, furnaces and sequestrian-ready combustion systems, will require innovative low emission designs and low development costs if Vision 21 goals are to be realized. The simulation tool will greatly reduce the number of experimental tests; this is especially desirable for gas turbine combustor design since the cost of the high pressure testing is extremely costly. In addition, the software will stimulate new ideas, will provide the capability of assessing and adapting low-emission combustors to alternate fuels, and will greatly reduce the development time cycle of combustion systems. The revolutionary combustion simulation software is able to accurately simulate the highly transient nature of gaseous-fueled (e.g. natural gas, low BTU syngas, hydrogen, biogas etc.) turbulent combustion and assess innovative concepts needed for Vision 21 plants. In addition, the software is capable of analyzing liquid-fueled combustion systems since that capability was developed under a concurrent Air Force Small Business Innovative Research (SBIR) program. The complex physics of the reacting flow field are captured using 3D Large Eddy Simulation (LES) methods, in which large scale transient motion is resolved by time-accurate numerics, while the small scale motion is modeled using advanced subgrid turbulence and chemistry closures. In this way, LES combustion simulations can model many physical aspects that, until now, were impossible to predict with 3D steady-state Reynolds Averaged Navier-Stokes (RANS) analysis, i.e. very low NOx emissions, combustion instability (coupling of unsteady heat and acoustics), lean blowout, flashback, autoignition, etc. LES methods are becoming more and more practical by linking together tens

  13. New technologies for integrated treatment of vent gas from sour water tank farm in refinery%炼厂酸性水罐区气体减排和治理新技术

    Institute of Scientific and Technical Information of China (English)

    方向晨; 刘忠生; 郭兵兵; 王海波


    Sour water tank farm is the largest waste water tank farm in refinery. The vent gas of which consists of H2S, ammonia, organic sulfides, oil vapor, steam and air. Direct emission of odor gas will pollute the air and waste oil vapor. The emission can be reduced more than 50% by degassing waste water, connecting vent gas pipelines together, reducing gas volume in the tank, arranging the drain time at night, etc. The fire by auto-ignition of FeS can be prevented by introducing inert gases to the tank. The vent gas of the tank farm is treated by "low-temperature diesel oil absorption-alkali absorption" ; The diesel oil comes from FCC fractionator and the rich absorption oil flows to hydrotreating unit. When the hydrogen sulfide is absorbed by sodium hydroxide or ammonia, the spent absorption liquid is treated in sour water tank. When hydrogen sulfide is absorbed by alcohol amine, the rich absorption liquid enters regeneration system. The removal rate of hydrogen sulfide and organic sulfides of the process is close to 100% and the recovery rate of NH3 is 60% -90% , the recovery rate of oil vapor is higher than 95% , and the oil vapor concentration in the purified gas is less than 25 g/cm3, and the emission concentrations (kg/h) of H2S, NH3, methyl mercaptan, dimethyl sulfide and dimethyl disulfide are all below (GB 14544-93) "Emission Standards for Odor Pollutants".%酸性水罐区是炼油厂最大的污水罐区,排放气中含有高浓度H2S,NH3,有机硫化物、油气、水蒸气和空气,直接排放导致空气恶臭污染严重且浪费油气资源.采用来水脱气罐、罐顶气连通管网、减少罐内气相空间体积、将排水高峰安排在夜间等措施,可减排气体50%以上.采用罐内气相空间惰性气保护,可防止硫化亚铁自燃引发火灾事故.罐区排放气采用“低温粗柴油吸收-碱液吸收”工艺,粗柴油来自催化裂化分馏塔或常压塔,富吸收油进加氢装置处理;采用

  14. On the Experimental and Theoretical Investigations of Lean Partially Premixed Combustion, Burning Speed, Flame Instability and Plasma Formation of Alternative Fuels at High Temperatures and Pressures (United States)

    Askari, Omid

    composition and thermodynamic properties. The method was applied to compute the thermodynamic properties of hydrogen/air and methane/air plasma mixtures for a wide range of temperatures (1,000-100,000 K), pressures (10-6-100 atm) and different equivalence ratios within flammability limit. In calculating the individual thermodynamic properties of the atomic species, the Debye-Huckel cutoff criterion has been used for terminating the series expression of the electronic partition function. A new differential-based multi-shell model was developed in conjunction with Schlieren photography to measure laminar burning speed and to study the flame instabilities for different alternative fuels such as syngas and GTL. Flame instabilities such as cracking and wrinkling were observed during flame propagation and discussed in terms of the hydrodynamic and thermo-diffusive effects. Laminar burning speeds were measured using pressure rise data during flame propagation and power law correlations were developed over a wide range of temperatures, pressures and equivalence ratios. As a part of this work, the effect of EGR addition and substitution of nitrogen with helium in air on flame morphology and laminar burning speed were extensively investigated. The effect of cell formation on flame surface area of syngas fuel in terms of a newly defined parameter called cellularity factor was also evaluated. In addition to that the experimental onset of auto-ignition and theoretical ignition delay times of premixed GTL/air mixture were determined at high pressures and low temperatures over a wide range of equivalence ratios.

  15. A Comprehensive Numerical Study on Effects of Natural Gas Composition on the Operation of an HCCI Engine Une étude numérique complète sur les effets de la composition du gaz naturel carburant sur le réglage d’un moteur HCCI

    Directory of Open Access Journals (Sweden)

    Jahanian O.


    Full Text Available Homogeneous Charge Compression Ignition (HCCI engine is a promising idea to reduce fuel consumption and engine emissions. Natural Gas (NG, usually referred as clean fuel, is an appropriate choice for HCCI engines due to its suitable capability of making homogenous mixture with air. However, varying composition of Natural Gas strongly affects the auto-ignition characteristics of in-cylinder mixture and the performance of the HCCI engine. This paper has focused on the influence of Natural Gas composition on engine operation in HCCI mode. Six different compositions of Natural Gas (including pure methane have been considered to study the engine performance via a thermo-kinetic zero-dimensional model. The simulation code covers the detailed chemical kinetics of Natural Gas combustion, which includes Zeldovich extended mechanism to evaluate NOx emission. Validations have been made using experimental data from other works to ensure the accuracy needed for comparison study. The equivalence ratio and the compression ratio are held constant but the engine speed and mixture initial temperature are changed for comparison study. Results show that the peak value of pressure/temperature of in-cylinder mixture is dependent of fuel Wobbe number. Furthermore, engine gross indicated power is linearly related to fuel Wobbe number. Gross indicated work, gross mean effective pressure, and NOx are the other parameters utilized to compare the performance of engine using different fuel compositions. Le moteur HCCI (Homogeneous Charge Compression Ignition, ou à allumage par compression d’une charge homogène est une idée prometteuse pour réduire la consommation de carburant et les émissions polluantes. Le gaz naturel, considéré généralement comme un carburant propre, est un choix approprié pour les moteurs HCCI en raison de sa capacité à former avec l’air un mélange homogène. Cependant, la composition du gaz naturel influe fortement sur les caract

  16. Industrial Gas Turbine Engine Catalytic Pilot Combustor-Prototype Testing

    Energy Technology Data Exchange (ETDEWEB)

    Etemad, Shahrokh [Precision Combustion, Inc., North Haven, CT (United States); Baird, Benjamin [Precision Combustion, Inc., North Haven, CT (United States); Alavandi, Sandeep [Precision Combustion, Inc., North Haven, CT (United States); Pfefferle, William [Precision Combustion, Inc., North Haven, CT (United States)


    PCI has developed and demonstrated its Rich Catalytic Lean-burn (RCL®) technology for industrial and utility gas turbines to meet DOE's goals of low single digit emissions. The technology offers stable combustion with extended turndown allowing ultra-low emissions without the cost of exhaust after-treatment and further increasing overall efficiency (avoidance of after-treatment losses). The objective of the work was to develop and demonstrate emission benefits of the catalytic technology to meet strict emissions regulations. Two different applications of the RCL® concept were demonstrated: RCL® catalytic pilot and Full RCL®. The RCL® catalytic pilot was designed to replace the existing pilot (a typical source of high NOx production) in the existing Dry Low NOx (DLN) injector, providing benefit of catalytic combustion while minimizing engine modification. This report discusses the development and single injector and engine testing of a set of T70 injectors equipped with RCL® pilots for natural gas applications. The overall (catalytic pilot plus main injector) program NOx target of less than 5 ppm (corrected to 15% oxygen) was achieved in the T70 engine for the complete set of conditions with engine CO emissions less than 10 ppm. Combustor acoustics were low (at or below 0.1 psi RMS) during testing. The RCL® catalytic pilot supported engine startup and shutdown process without major modification of existing engine controls. During high pressure testing, the catalytic pilot showed no incidence of flashback or autoignition while operating over a wide range of flame temperatures. In applications where lower NOx production is required (i.e. less than 3 ppm), in parallel, a Full RCL® combustor was developed that replaces the existing DLN injector providing potential for maximum emissions reduction. This concept was tested at industrial gas turbine conditions in a Solar Turbines, Incorporated high-pressure (17 atm.) combustion rig and in a modified Solar

  17. EGR对减少UHC和CO排放的影响与分析%Effect and Analysis of EGR on Reducing UHC and CO Emission in Homogeneous Charge Two-Stroke Engines

    Institute of Scientific and Technical Information of China (English)

    赵新顺; 刘德新; 丁伟东; 毛长青


    the cylinder prior to the first stage of auto-ignition. The importance of active species is confirmed by experiments where air or N2 with similar quantities to real EGR are used to dilute the charge.It was found that spark ignition was possible with real EGR but not possible with either air or N2.

  18. 3d Simulation of Di Diesel Combustion and Pollutant Formation Using a Two-Component Reference Fuel Simulation 3D de la combustion et de la formation des polluants dans un moteur Diesel à injection directe en utilisant un carburant de référence à deux composants

    Directory of Open Access Journals (Sweden)

    Barths H.


    Full Text Available By separating the fluid dynamic calculation from that of the chemistry, the unsteady flamelet model allows the use of comprehensive chemical mechanisms, which include several hundred reactions. This is necessary to describe the different processes that occur in a DI Diesel engine such as autoignition, the burnout in the partially premixed phase, the transition to diffusive burning, and formation of pollutants like NOx and soot. The highly nonlinear reaction rates need not to be simplified, and the complete structure of the combustion process is preserved. Using the Representative Interactive Flamelet (RIF model, the one-dimensional unsteady set of partial differential equations is solved online with the 3D CFD code. The flamelet solution is coupled to the flow and mixture field by several time dependent parameters (enthalpy, pressure, scalar dissipation rate. In return, the flamelet code yields the species concentrations, which are then used by the 3D CFD code to compute the temperature field and the density. The density is needed in the 3D CFD code for the solution of the turbulent flow and mixture field. Pollutant formation in a Volkswagen DI 1900 Diesel engine is investigated experimentally. The engine is fueled with Diesel and two reference fuels. One reference fuel is pure n-decane. The second is a two-component fuel consisting of 70% (liquid volume n-decane and of 30% (liquid volume alpha-methylnaphthalene (Idea-fuel. The experimental results show good agreement for the whole combustion cycle (ignition delay, maximum pressures, torque and pollutant formation between the two-component reference fuel and Diesel. The simulations are performed for both reference fuels and are compared to the experimental data. Nine different flamelet calculations are performed for each simulation to account for the variability of the scalar dissipation rate, and its effect on ignition is discussed. Pollutant formation (NOx and soot is predicted for both


    Energy Technology Data Exchange (ETDEWEB)

    Clifford E. Smith; Steven M. Cannon; Virgil Adumitroaie; David L. Black; Karl V. Meredith


    In this project, an advanced computational software tool was developed for the design of low emission combustion systems required for Vision 21 clean energy plants. Vision 21 combustion systems, such as combustors for gas turbines, combustors for indirect fired cycles, furnaces and sequestrian-ready combustion systems, will require innovative low emission designs and low development costs if Vision 21 goals are to be realized. The simulation tool will greatly reduce the number of experimental tests; this is especially desirable for gas turbine combustor design since the cost of the high pressure testing is extremely costly. In addition, the software will stimulate new ideas, will provide the capability of assessing and adapting low-emission combustors to alternate fuels, and will greatly reduce the development time cycle of combustion systems. The revolutionary combustion simulation software is able to accurately simulate the highly transient nature of gaseous-fueled (e.g. natural gas, low BTU syngas, hydrogen, biogas etc.) turbulent combustion and assess innovative concepts needed for Vision 21 plants. In addition, the software is capable of analyzing liquid-fueled combustion systems since that capability was developed under a concurrent Air Force Small Business Innovative Research (SBIR) program. The complex physics of the reacting flow field are captured using 3D Large Eddy Simulation (LES) methods, in which large scale transient motion is resolved by time-accurate numerics, while the small scale motion is modeled using advanced subgrid turbulence and chemistry closures. In this way, LES combustion simulations can model many physical aspects that, until now, were impossible to predict with 3D steady-state Reynolds Averaged Navier-Stokes (RANS) analysis, i.e. very low NOx emissions, combustion instability (coupling of unsteady heat and acoustics), lean blowout, flashback, autoignition, etc. LES methods are becoming more and more practical by linking together tens

  20. Use of Ethanol/Diesel Blend and Advanced Calibration Methods to Satisfy Euro 5 Emission Standards without DPF Utilisation d’un carburant Diesel éthanolé à l’aide de méthodes de calibration avancées afin de satisfaire les normes Euro 5 sans filtre à particules

    Directory of Open Access Journals (Sweden)

    Magand S.


    Full Text Available The use of biofuels has been extensively developed in the last years to diversify energy resources and to participate to the transportation greenhouse gas emissions reduction effort. One of the most promising renewable fuels for large scale production is the ethanol which is nowadays mainly used for spark-ignited engines; nonetheless the European market share of Diesel vehicles is around 60%. These issues lead us to propose an innovative fuel formulation using ethanol for Diesel engine applications. The key issues to deal with the use of ethanol in a Diesel blend are the miscibility, the flashpoint, the lubricity and the cetane number. An intensive work has been done to optimise the formulation coupling the use of ethanol, with first and second generations of Diesel biofuels. The application on a Euro 4-compliant Diesel turbocharged engine with high pressure exhaust gas recirculation shows an outstanding decrease of particulate matter emissions thanks to this oxygenated fuel. Nevertheless unburned hydrocarbons and carbon monoxide emissions could be an issue as well as NOx emissions if the engine control settings are not updated. Combustion analysis helps understanding the fuel effect on the resulting auto-ignition delay and the pilot injection combustion behaviour, which leads to modified engine output compared to Diesel fuel. Therefore, the optimisation of the fuel/engine matching is performed using advanced calibration methodologies combined with design of experiments at the engine test bed. First of all, global and mixed approaches are proposed and compared in warm operating conditions. Finally it permits to simultaneously drop nitrogen oxides emissions and particulate matter emissions. Global CO2 emissions reduction and noise decrease are also expected. To further investigate engine emissions potential reduction, the engine is set up on a dynamic test bed facility, allowing to reproduce cold New European Driving Cycle (NEDC. Several