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Sample records for au melange co2-ch4

  1. CO2/CH4, CH4/H-2 and CO2/CH4/H-2 separations at high pressures using Mg-2(dobdc)

    NARCIS (Netherlands)

    Z.R. Herm; R. Krishna; J.R. Long

    2012-01-01

    High-pressure separations of binary and ternary mixtures of CO2, CH4, and H2 are relevant to carbon dioxide capture as well as hydrogen and natural gas purification. Metal-organic frameworks represent a class of porous materials that could be used to accomplish these separations, and Mg2(dobdc) (dob

  2. Reprint of: CO2/CH4, CH4/H-2 and CO2/CH4/H-2 separations at high pressures using Mg-2(dobdc)

    NARCIS (Netherlands)

    Z.R. Herm; R. Krishna; J.R. Long

    2012-01-01

    High-pressure separations of binary and ternary mixtures of CO2, CH4, and H2 are relevant to carbon dioxide capture as well as hydrogen and natural gas purification. Metal-organic frameworks represent a class of porous materials that could be used to accomplish these separations, and Mg2(dobdc) (dob

  3. Computer Simulation of Adsorption and Separation of CO2/CH4 in Modified COF-102

    Institute of Scientific and Technical Information of China (English)

    朱玉俊; 周建海; 胡军; 刘洪来; 胡英

    2011-01-01

    Covalent organic framework (COF) is a porous material with low density and large BET (Brtmauer-Emmett-Teller) surface area. They have great potential in gas adsorption and separation. In this work, the adsorption of pure CO2 and CO2/CH4 mixture on modified COF-102 was simulated by using GCMC (grand canonical Monte Carlo). Metal Li was incorporated into COF-102 through three doping methods, including charge exchange, O^--Li6+ dipolar interaction and O^--Li^+ chemical bonding. The influence of Li doping on the adsorption of CO2 was studied. The results showed that among the three methods, the dipole doping is the best way to improve CO2 adsorption performance. Further, the ligands of COF-102 were replaced by extended aromatic moieties, such as diphenyl and pyrene. The adsorption capacity of CO2 and CH4, and the selectivity of CO2/CH4 on the ligand-replaced COF-102 were studied. The capacity of CO2 and CH4 on the ligand-replaced COF-102 had obvious changes; hence the selectivity of CO2/CH4 can be adjusted accordingly.

  4. The incorporation of graphene oxide into polysulfone mixed matrix membrane for CO2/CH4 separation

    Science.gov (United States)

    Zahri, K.; Goh, P. S.; Ismail, A. F.

    2016-06-01

    Carbon dioxide (CO2) is often found as the main impurity in natural gas, where methane (CH4) is the major component. The presence of CO2 in natural gas leads to several problems such as reducing the energy content of natural gas and cause pipeline corrosion. Thus it must be removed to meet specifications (CO2 ≤ 2 mol%) before the gas can be delivered to the pipeline. In this work, hollow fiber mixed matrix membrane (MMM) were fabricated by embedding graphene oxide (GO) into a polysulfone (PSf) polymer matrix to improve membrane properties as well as its separation performance towards CO2/CH4 gas. The membrane properties were investigated for pristine membrane and mixed matrix membrane filled with filler loading of 0.25%. The synthesized GO and properties of fabricated membranes were characterized and studied using TEM, AFM, XRD, FTIR and SEM respectively. The permeance of pure gases and ideal selectivity of CO2/CH4 gas were determined using pure gas permeation experiment. GO has affinity towards CO2 gas. The nanosheet structure creates path for small molecule gas and restricted large molecule gas to pass through the membrane. The incorporation of GO in PSf polymer enhanced the permeance of CO 2 and CO2/CH4 separation from 64.47 to 86.80 GPU and from 19 to 25 respectively.

  5. Deactivation and Coke Accumulation during CO2/CH4 Reforming over Pt Catalysts

    OpenAIRE

    Bitter, J.H.; Seshan, K.; Lercher, J.A.

    2001-01-01

    The Deactivation of Pt catalysts used in the generation of synthesis gas via CO2/CH4 reforming depends strongly on the support and the metalparticle size. Methods of Physicochemical characterization such as X-ray absorption spectroscopy and hydrogen chemisorption suggest that carbon formation (most likely from methane) rather than sintering is the main cause of catalyst deactivation. The rate of carbon formation decreased in the order Pt/y-Al2O3 >> Pt/TiO2 > Pt/ZrO2. Carbon was formed on the ...

  6. Synergetic effect of carbon nanopore size and surface oxidation on CO2 capture from CO2/CH4 mixtures

    OpenAIRE

    Furmaniak, Sylwester; KOWALCZYK, PIOTR; Terzyk, Artur P.; Gauden, Piotr A.; Harris , P. J. F.

    2013-01-01

    We have studied the synergetic effect of confinement (carbon nanopore size) and surface chemistry (the number of carbonyl groups) on CO2 capture from its mixtures with CH4 at typical operating conditions for industrial adsorptive separation (298 K and compressed CO2CH4 mixtures). Although both confinement and surface oxidation have an impact on the efficiency of CO2/CH4 adsorptive separation at thermodynamics equilibrium, we show that surface functionalization is the most important factor in ...

  7. Selective Adsorption and Selective Transport Diffusion of CO2-CH4 Binary Mixture in Coal Ultramicropores.

    Science.gov (United States)

    Zhao, Yongliang; Feng, Yanhui; Zhang, Xinxin

    2016-09-01

    The adsorption and diffusion of the CO2-CH4 mixture in coal and the underlying mechanisms significantly affect the design and operation of any CO2-enhanced coal-bed methane recovery (CO2-ECBM) project. In this study, bituminous coal was fabricated based on the Wiser molecular model and its ultramicroporous parameters were evaluated; molecular simulations were established through Grand Canonical Monte Carlo (GCMC) and Molecular Dynamic (MD) methods to study the effects of temperature, pressure, and species bulk mole fraction on the adsorption isotherms, adsorption selectivity, three distinct diffusion coefficients, and diffusivity selectivity of the binary mixture in the coal ultramicropores. It turns out that the absolute adsorption amount of each species in the mixture decreases as temperature increases, but increases as its own bulk mole fraction increases. The self-, corrected, and transport diffusion coefficients of pure CO2 and pure CH4 all increase as temperature or/and their own bulk mole fractions increase. Compared to CH4, the adsorption and diffusion of CO2 are preferential in the coal ultramicropores. Adsorption selectivity and diffusivity selectivity were simultaneously employed to reveal that the optimal injection depth for CO2-ECBM is 800-1000 m at 308-323 K temperature and 8.0-10.0 MPa. PMID:27518119

  8. Airborne measurements of CO2, CH4 and HCN in boreal biomass burning plumes

    Science.gov (United States)

    O'Shea, Sebastian J.; Bauguitte, Stephane; Muller, Jennifer B. A.; Le Breton, Michael; Archibald, Alex; Gallagher, Martin W.; Allen, Grant; Percival, Carl J.

    2013-04-01

    Biomass burning plays an important role in the budgets of a variety of atmospheric trace gases and particles. For example, fires in boreal Russia have been linked with large growths in the global concentrations of trace gases such as CO2, CH4 and CO (Langenfelds et al., 2002; Simpson et al., 2006). High resolution airborne measurements of CO2, CH4 and HCN were made over Eastern Canada onboard the UK Atmospheric Research Aircraft FAAM BAe-146 from 12 July to 4 August 2011. These observations were made as part of the BORTAS project (Quantifying the impact of BOReal forest fires on Tropospheric oxidants over the Atlantic using Aircraft and Satellites). Flights were aimed at transecting and sampling the outflow from the commonly occurring North American boreal forest fires during the summer months and to investigate and identify the chemical composition and evolution of these plumes. CO2 and CH4 dry air mole fractions were determined using an adapted system based on a Fast Greenhouse Gas Analyser (FGGA, Model RMT-200) from Los Gatos Research Inc, which uses the cavity enhanced absorption spectroscopy technique. In-flight calibrations revealed a mean accuracy of 0.57 ppmv and 2.31 ppbv for 1 Hz observations of CO2 and CH4, respectively, during the BORTAS project. During these flights a number of fresh and photochemically-aged plumes were identified using simultaneous HCN measurements. HCN is a distinctive and useful marker for forest fire emissions and it was detected using chemical ionisation mass spectrometry (CIMS). In the freshest plumes, strong relationships were found between CH4, CO2 and other tracers for biomass burning. From this we were able to estimate that 8.5 ± 0.9 g of CH4 and 1512 ± 185 g of CO2 were released into the atmosphere per kg of dry matter burnt. These emission factors are in good agreement with estimates from previous studies and can be used to calculate budgets for the region. However for aged plumes the correlations between CH4 and other

  9. 金属有机骨架材料在CO2/CH4吸附分离中的研究进展%Progress of adsorption-based CO2/CH4 separation by metal organic frameworks

    Institute of Scientific and Technical Information of China (English)

    张所瀛; 刘红; 刘朋飞; 吴培培; 杨祝红; 阳庆元; 陆小华

    2014-01-01

    CO2/CH4分离能耗高是生物甲烷过程核心难题之一。金属有机骨架材料(metal organic frameworks,MOFs)由于其优异的CO2吸附分离性能,被视为最具潜力的CO2分离捕集材料,近年来引起了广泛的关注。本文结合沼气的特点和MOFs研究的最新进展,对MOFs材料在CO2/CH4吸附分离过程的相关实验研究工作进行了综述。%The high energy penalty of CO2 separation from biogas is a core problem in the biomethane process. Metal organic frameworks (MOFs) have recently attracted intense research interest because of their ultra-high CO2 adsorption capacity and potential applications as novel adsorbents to reduce energy cost. The recent progress of experimental researches on adsorption-based CO2/CH4 separation by MOFs is reviewed.

  10. Screening metal-organic framework-based mixed-matrix membranes for CO2/CH4 separations

    OpenAIRE

    Keskin, Seda; Eruçar, İlknur

    2011-01-01

    1 Screening Metal Organic Framework-based Mixed Matrix Membranes for CO2/CH4 Separations Ilknur Erucar† and Seda Keskin‡* †Department of Computational Sciences and Engineering, Koç University, 34450, Istanbul, Turkey ‡Department of Chemical and Biological Engineering, Koç University, 34450, Istanbul, Turkey Submitted to Ind. Eng. Chem. Res. Abstract In this study, the challenge of selecting metal organic frameworks (MOFs) as filler particles in high performance mixe...

  11. CO2 CH4 and N20 fluxes during land conversion in early bioenergy systems

    Science.gov (United States)

    Zenone, T.

    2012-04-01

    CO2 CH4 and N20 fluxes during land conversion in early bioenergy systems Terenzio Zenone1-2, Jiquan Chen1-2, Ilya Gelfand3-4, G. Philip Robertson3-4 1 Department of Environmental Sciences, University of Toledo, Toledo, OH USA 2 Great Lakes Bioenergy Research Center, Michigan State University, East Lansing, MI USA 3 W.K. Kellogg Biological Station, Michigan State University, Hickory Corners, MI USA 4Department of Crop and Soil Sciences, Michigan State University, East Lansing, MI USA Environmental sustainability of bioenergy crop cultivation represents an important challenge and is a topic of intensive scientific and political debate worldwide due to increasing societal needs for renewable energy. Despite the increasing knowledge related to potential bioenergy systems, the effect of land use change (LUC) on GHG fluxes during the conversion remains poorly understood but is likely to be substantial. In order to tackle this issue the Great lake Bioenergy Research Center (GLBRC) of the US Department of Energy (DOE) has established a field experiment and deployed a cluster of eddy-covariance towers to quantify the magnitude and changes of ecosystem carbon assimilation, loss, and balance during the conversion and establishment years in a permanent prairie and four types of candidate biofuel systems [Conservation Reserve Program (CRP) grassland, switchgrass, mixed-species restored prairie and corn]. Six sites were converted to soybean in 2009 before establishing the bioenergy systems in 2010 while one site was kept grassland as reference. Soil N2O and CH4 fluxes were measured biweekly with static chambers in four replicate locations in each fields, within the footprint of the eddy covariance tower using static chamber GHG flux protocols of the KBS LTER site. Our field observations, made between January 2009 through December 2010, showed that conversion of CRP to soybean induced net C emissions during the conversion year that ranging from 288 g C m-2, to 173 g C m-2 . while

  12. Winter greenhouse gas fluxes (CO2, CH4 and N2O from a subalpine grassland

    Directory of Open Access Journals (Sweden)

    L. Merbold

    2013-05-01

    Full Text Available Although greenhouse gas emissions during winter contribute significantly to annual balances, their quantification is still highly uncertain in snow-covered ecosystems. Here, carbon dioxide (CO2, methane (CH4 and nitrous oxide (N2O fluxes were measured at a subalpine managed grassland in Switzerland using concentration gradients within the snowpack (CO2, CH4, N2O and the eddy covariance method (CO2 during the winter 2010/2011. Our objectives were (1 to identify the temporal and spatial variation of greenhouse gases (GHGs and their drivers, and (2 to estimate the GHG budget of the site during this specific season (1 December–31 March, 121 days. Mean winter fluxes (December–March based on the gradient method were 0.77 ± 0.54 μmol m−2 s−1 for CO2 (1.19 ± 1.05 μmol m−2 s−1 measured by eddy covariance, −0.14 ± 0.09 nmol m−2 s−1 for CH4 and 0.23 ± 0.23 nmol m−2 s−1 for N2O, respectively. In comparison with the CO2 fluxes measured by eddy covariance, the gradient technique underestimated the effluxes by 50%. While CO2 and CH4 fluxes decreased with the progressing winter season, N2O fluxes did not follow a seasonal pattern. The major variables correlating with the fluxes of CO2 and CH4 were soil temperature and snow water equivalent, which is based on snow height and snow density. N2O fluxes were only explained poorly by any of the measured environmental variables. Spatial variability across the valley floor was smallest for CO2 and largest for N2O. During the winter season 2010/2011, greenhouse gas fluxes ranged between 550 ± 540 g CO2 m−2 estimated by the eddy covariance approach and 543 ± 247 g CO2 m−2, −0.4 ± 0.01 g CH4 m−2 and 0.11 ± 0.1 g N2O m−2 derived by the gradient technique. Total seasonal greenhouse gas emissions from the grassland were between 574 ± 276 and 581 ± 569 g CO2 eq. m−2, with N2O contributing 5% to the overall budget and CH4 reducing the budget by 0.1%. Cumulative budgets of CO2 were

  13. CO2, CH4, and DOC Flux During Long Term Thaw of High Arctic Tundra

    Science.gov (United States)

    Stackhouse, B. T.; Vishnivetskaya, T. A.; Layton, A.; Bennett, P.; Mykytczuk, N.; Lau, C. M.; Whyte, L.; Onstott, T. C.

    2013-12-01

    Arctic regions are expected to experience temperature increases of >4° C by the end of this century. This warming is projected to cause a drastic reduction in the extent of permafrost at high northern latitudes, affecting an estimated 1000 Pg of SOC in the top 3 m. Determining the effects of this temperature change on CO2 and CH4 emissions is critical for defining source constraints to global climate models. To investigate this problem, 18 cores of 1 m length were collected in late spring 2011 before the thawing of the seasonal active layer from an ice-wedge polygon near the McGill Arctic Research Station (MARS) on Axel Heiberg Island, Nunavut, Canada (N79°24, W90°45). Cores were collected from acidic soil (pH 5.5) with low SOC (~1%), summertime active layer depth between 40-70 cm (2010-2013), and sparse vegetation consisting primarily of small shrubs and sedges. Cores were progressively thawed from the surface over the course of 14 weeks to a final temperature of 4.5° C and held at that temperature for 15 months under the following conditions: in situ water saturation conditions versus fully water saturated conditions using artificial rain fall, surface light versus no surface light, cores from the polygon edge, and control cores with a permafrost table maintained at 70 cm depth. Core headspaces were measured weekly for CO2, CH4, H2, CO, and O2 flux during the 18 month thaw experiment. After ~20 weeks of thawing maximum, CO2 flux for the polygon edge and dark treatment cores were 3.0×0.7 and 1.7×0.4 mmol CO2 m-2 hr-1, respectively. The CO2 flux for the control, saturated, and in situ saturation cores reached maximums of 0.6×0.2, 0.9×0.5, and 0.9×0.1 mmol CO2 m-2 hr-1, respectively. Field measurements of CO2 flux from an adjacent polygon during the mid-summer of 2011 to 2013 ranged from 0.3 to 3.7 mmol CO2 m-2 hr-1. Cores from all treatments except water saturated were found to consistently oxidize CH4 at ~atmospheric concentrations (2 ppmv) with a maximum

  14. Experimental measurements of vapor-liquid equilibria of the H2O + CO2 + CH4 ternary system

    Science.gov (United States)

    Qin, J.; Rosenbauer, R.J.; Duan, Zhenhao

    2008-01-01

    Reported are the experimental measurements on vapor-liquid equilibria in the H2O + CO2 + CH4 ternary system at temperatures from (324 to 375) K and pressures from (10 to 50) MPa. The results indicate that the CH4 solubility in the ternary mixture is about 10 % to 40 % more than that calculated by interpolation from the Henry's law constants of the binary system, H2O + CH4, and the solubility of CO2 is 6 % to 20 % more than what is calculated by the interpolation from the Henry's law constants of the binary mixture, H 2O + CO2. ?? 2008 American Chemical Society.

  15. Fluxes of CO2,CH4 and N2O from alpine grassland in the Tibetan Plateau

    Institute of Scientific and Technical Information of China (English)

    PEIZhiyong; OUYANGHua; ZHOUCaiping; XUXingliang

    2003-01-01

    Using static chamber technique,fluxes of CO2,CH4 and N2O were measured in the alpine grassland area from July 2000 to July 2001,determinations of mean fluxes showed that CO2 and N2O were generally released from the soil,while the alpine grassland accounted for a weak CH4 sink.Fluxes of CO2,CH4 and N2O ranged widely.The highest CO2 emission occurred in August,whereas almost 90?of the whole year emission occurred in the growing season.But the variations of CH4 and N2O fluxes did not show any clear patterns over the one-year-experiment.During a daily variation,the maximum CO2 emission occurred at 16:00,and then decreased to the minimum emission in the early morning.Daily pattern analyses indicated that the variation in CO2 fluxes was positively related to air temperatures(R2=0.73)and soil temperatures at a depth of 5 cm(R2=0.86),whereas daily variations in CH4 and N2O fluxes were poorly explained by soil temperatures and climatic variables.CO2 emissions in this area were much lower than other grasslands in plain areas.

  16. Fluxes of the greenhouse gases (CO2, CH4 and N2O) above a short-rotation poplar plantation after conversion from agricultural land

    OpenAIRE

    Zona, D.; I. A. Janssens; M. Aubinet; Gioli, B.; Vicca, S.; Fichot, R.; Ceulemans, R.

    2013-01-01

    Abstract: The increasing demand for renewable energy may lead to the conversion of millions of hectares into bioenergy plantations with a possible substantial transitory carbon (C) loss. In this study we report on the greenhouse gas fluxes (CO2, CH4, and N2O) measured using eddy covariance of a short-rotation bioenergy poplar plantation converted from agricultural fields. During the first six months after the establishment of the plantation (JuneDecember 2010) there were substantial CO2, CH4,...

  17. Plasticization-resistant hollow fiber membranes for CO2/CH4 separation based on a thermally crosslinkable polyimide

    KAUST Repository

    Chen, Chien-Chiang

    2011-10-01

    Decarboxylation-induced thermal crosslinking has been demonstrated to be effective for stabilizing membranes against plasticization in dense films. This study extends this promising crosslinking approach from dense films to industrially relevant asymmetric hollow fiber membranes. Crosslinkable asymmetric hollow fiber membranes were spun from a carboxylic acid containing polyimide, 6FDA-DAM:DABA. Dope and spinning conditions were optimized to obtain fibers with a defect-free selective skin layer. It is found that slightly defective fibers suffered severe selectivity loss after thermal crosslinking, suggesting that defect-free property is essential to the performance of the resulting crosslinked hollow fiber membranes. The crosslinked fibers were tested for CO 2/CH 4 separation. The excellent plasticization resistance under high pressure feeds (with highest CO 2 partial pressure of 400psia) suggests that these robust membranes are promising for aggressive natural gas purification. © 2011 Elsevier B.V.

  18. Molecular simulations on diameter effect of carbon nanotube for separation of CO2/CH4%不同管径碳纳米管中CO2/CH4分离的分子模拟

    Institute of Scientific and Technical Information of China (English)

    曹伟; 吕玲红; 黄亮亮; 王珊珊; 朱育丹

    2014-01-01

    Biomethane route has large potential in emission reduction and energy saving. One of the key issues is separation of biogas in operating conditions of 333 K and 0.1 MPa. Grand canonical Monte Carlo (GCMC) and equilibrium molecular dynamics simulations (EMD) were used to compute adsorption loadings and self-diffusivities of CH4/CO2 at various diameters of carbon nanotube (CNT) bundles. Single component and equimolar gases were simulated. CO2 always had larger adsorption loading and diffusion coefficient than CH4 as the result of relatively strong interaction between CO2 molecules and tube walls, due to the confined capacity. The permselectivity reached a maximum in closely 1 nm, and under such conditions the separation process was controlled by adsorption rather than diffusion.%生物甲烷路线在CO2减排和节能方面有很大的应用前景。而对生物沼气的分离是此路线的一个关键问题,特别是在60℃和0.1 MPa下。巨正则Monte Carlo(GCMC)和平衡分子动力学(EMD)的分子模拟方法研究CO2和CH4在不同管径的碳纳米管(CNT)中的吸附和扩散,可以从分子层面研究生物沼气的分离机理。分别计算了CO2/CH4二元混合物吸附量、吸附选择性、自扩散系数和渗透选择性等参数。模拟结果表明:由于碳管的受限空间和CO2与碳纳米管壁面分子之间强相互作用,导致二元等物质的量的混合物CO2/CH4的吸附量和扩散系数的差异。CO2的吸附量和自扩散系数都比CH4的大。渗透选择性在碳管管径达到最接近1 nm时达到最大值,此时混合物的分离过程是吸附控制,而非扩散控制。

  19. Molecular simulations on diameter effect of carbon nanotube for separation of CO2/CH4%不同管径碳纳米管中CO2/CH4分离的分子模拟

    Institute of Scientific and Technical Information of China (English)

    曹伟; 吕玲红; 黄亮亮; 王珊珊; 朱育丹

    2014-01-01

    生物甲烷路线在CO2减排和节能方面有很大的应用前景。而对生物沼气的分离是此路线的一个关键问题,特别是在60℃和0.1 MPa下。巨正则Monte Carlo(GCMC)和平衡分子动力学(EMD)的分子模拟方法研究CO2和CH4在不同管径的碳纳米管(CNT)中的吸附和扩散,可以从分子层面研究生物沼气的分离机理。分别计算了CO2/CH4二元混合物吸附量、吸附选择性、自扩散系数和渗透选择性等参数。模拟结果表明:由于碳管的受限空间和CO2与碳纳米管壁面分子之间强相互作用,导致二元等物质的量的混合物CO2/CH4的吸附量和扩散系数的差异。CO2的吸附量和自扩散系数都比CH4的大。渗透选择性在碳管管径达到最接近1 nm时达到最大值,此时混合物的分离过程是吸附控制,而非扩散控制。%Biomethane route has large potential in emission reduction and energy saving. One of the key issues is separation of biogas in operating conditions of 333 K and 0.1 MPa. Grand canonical Monte Carlo (GCMC) and equilibrium molecular dynamics simulations (EMD) were used to compute adsorption loadings and self-diffusivities of CH4/CO2 at various diameters of carbon nanotube (CNT) bundles. Single component and equimolar gases were simulated. CO2 always had larger adsorption loading and diffusion coefficient than CH4 as the result of relatively strong interaction between CO2 molecules and tube walls, due to the confined capacity. The permselectivity reached a maximum in closely 1 nm, and under such conditions the separation process was controlled by adsorption rather than diffusion.

  20. Continuous CO2/CH4/CO measurements (2012-2014) at Beromünster tall tower station in Switzerland

    Science.gov (United States)

    Satar, Ece; Berhanu, Tesfaye A.; Brunner, Dominik; Henne, Stephan; Leuenberger, Markus

    2016-05-01

    The understanding of the continental carbon budget is essential to predict future climate change. In order to quantify CO2 and CH4 fluxes at the regional scale, a measurement system was installed at the former radio tower in Beromünster as part of the Swiss greenhouse gas monitoring network (CarboCount CH). We have been measuring the mixing ratios of CO2, CH4 and CO on this tower with sample inlets at 12.5, 44.6, 71.5, 131.6 and 212.5 m above ground level using a cavity ring down spectroscopy (CRDS) analyzer. The first 2-year (December 2012-December 2014) continuous atmospheric record was analyzed for seasonal and diurnal variations and inter-species correlations. In addition, storage fluxes were calculated from the hourly profiles along the tower. The atmospheric growth rates from 2013 to 2014 determined from this 2-year data set were 1.78 ppm yr-1, 9.66 ppb yr-1 and -1.27 ppb yr-1 for CO2, CH4 and CO, respectively. After detrending, clear seasonal cycles were detected for CO2 and CO, whereas CH4 showed a stable baseline suggesting a net balance between sources and sinks over the course of the year. CO and CO2 were strongly correlated (r2 > 0.75) in winter (DJF), but almost uncorrelated in summer. In winter, anthropogenic emissions dominate the biospheric CO2 fluxes and the variations in mixing ratios are large due to reduced vertical mixing. The diurnal variations of all species showed distinct cycles in spring and summer, with the lowest sampling level showing the most pronounced diurnal amplitudes. The storage flux estimates exhibited reasonable diurnal shapes for CO2, but underestimated the strength of the surface sinks during daytime. This seems plausible, keeping in mind that we were only able to calculate the storage fluxes along the profile of the tower but not the flux into or out of this profile, since no Eddy covariance flux measurements were taken at the top of the tower.

  1. Measuring and modeling the competitive adsorption of CO2, CH4, and N2 on a dry coal.

    Science.gov (United States)

    Ottiger, Stefan; Pini, Ronny; Storti, Giuseppe; Mazzotti, Marco

    2008-09-01

    Data on the adsorption behavior of CO 2, CH 4, and N 2 on coal are needed to develop enhanced coalbed methane (ECBM) recovery processes, a technology where the recovery of CH 4 is enhanced by injection of a gas stream consisting of either pure CO 2, pure N 2, or a mixture of both. The pure, binary, and ternary adsorption of these gases on a dry coal from the Sulcis Coal Province in Italy has been measured at pressures up to 180 bar and temperatures of 45 and 70 degrees C for the pure gases and of 45 degrees C for the mixtures. The experiments were performed in a system consisting of a magnetic suspension balance using a gravimetric-chromatographic technique. The excess adsorption isotherms are successfully described using a lattice density functional theory model based on the Ono-Kondo equations exploiting information about the structure of the coal, the adsorbed gases, and the interaction between them. The results clearly show preferential adsorption of CO 2 over CH 4 and N 2, which therefore indicate that ECBM may be a viable option for the permanent storage of CO 2. PMID:18680385

  2. Buckybowls as adsorbents for CO2, CH4, and C2H2: Binding and structural insights from computational study.

    Science.gov (United States)

    Hussain, M Althaf; Vijay, Dolly; Sastry, G Narahari

    2016-01-30

    Noncovalent functionalization of buckybowls sumanene (S), corannulene (R), and coronene (C) with greenhouse gases (GGs) such as CO2 , CH4 (M), and C2 H2 (A) has been studied using hybrid density functional theory. The propensity and preferences of these small molecules to interact with the concave and convex surfaces of the buckybowls has been quantitatively estimated. The results indicate that curvature plays a significant role in the adsorption of these small molecules on the π surface and it is observed that buckybowls have higher binding energies (BEs) compared with their planar counterpart coronene. The concave surface of the buckybowl is found to be more feasible for adsorption of small molecules. BEs of small molecules towards π systems is CO2  > A > M and the BEs of π systems toward small molecules is S > R > C. Obviously, the binding preference is dictated by the way in which various noncovalent interactions, such as π···π, lone pair···π, and CH···π manifest themselves on carbaneous surfaces. To delineate the intricate details of the interactions, we have employed Bader's quantum theory of atoms in molecule and localized molecular orbital energy decomposition analysis (LMO-EDA). LMO-EDA, which measures the contribution of various components and traces the physical origin of the interactions, indicates that the complexes are stabilized largely by dispersion interactions.

  3. Novel preparation of NaA/carbon nanocomposite thin films with high permeance for CO2/CH4 separation

    Institute of Scientific and Technical Information of China (English)

    Zhi Hui Zhou; Jian Hua Yang; Li Feng Chang; Yan Zhang; Wei Guo Sun; Jin Qu Wang

    2007-01-01

    Novel NaA/carbon nanocomposite thin films were successfully prepared on a porous α-Al2O3 substrate by incorporating nanosized NaA zeolite into novolak-type phenolic resin. The prepared films were characterized by XRD, SEM and single gas permeation tests. The NaA zeolite/carbon nanocomposite thin films exhibited that the ideal separation factor of CO2/CH4 was 28.4and the carbon dioxide flux was 3.39 × 10-7 mol/(Pa m2 s) at room temperature and under a pressure difference of 100 kPa, which was two orders of magnitude higher than that of pure carbon membrane prepared at the same procedures and conditions as those of composite films. From the SEM images, the films were continuous and highly intergrown. Compared with carbon membranes, the thickness of nanocomposite films was drastically decreased, which was helpful to reduce the diffusion resistance and increase the flux of gas permeance.

  4. Fluxes of CO2, CH4 and N2O from soil of burned grassland savannah of central Africa

    Directory of Open Access Journals (Sweden)

    R. Valentini

    2010-06-01

    Full Text Available Grassland savannah ecosystems subject to frequent fires are considered to have an almost neutral carbon balance, as the C released during burning mostly balance the C fixed by the photosynthetic process. However, burning might modify the net soil-atmosphere exchange of GHGs in the post burning phase so that the radiative balance of the site might shift from neutrality. In the present study the impact of fire on soil fluxes of CO2, CH4 and N2O was investigated in a grassland savannah (Congo Brazzaville where high frequency burning is the typical management form of the region. An area was preserved for one season from annual burning and was used as "unburned" treatment. Two field campaigns were carried on at different time length from the fire event, 1 month, in the middle of the dry season, and 8 months after, at the end of the growing season. CO2, CH4 and N2O fluxes, as well as several soil parameters, were measured in each campaign from burned and unburned plots. Rain events were simulated at each campaign to evaluate magnitude and length of the generated GHG flux pulses. In laboratory experiments, on soil samples from the two treatments, microbial biomass, net N mineralization, net nitrification, N2O, NO and CO2 emissions were analyzed in function of soil water and/or temperature variations. Results showed that fire had a significant effect on GHG fluxes but the effect was transient, as after 8 months differences between treatments were no longer significant. One month after burning CO2 soil emissions were significantly lower in the burned plots, CH4 fluxes were dominated by net emissions rather than net consumption in the unburned area and fire shifted the CH4 flux distribution towards more negative values. No significant effect of fire was observed in the field on N2O fluxes. It was assumed that the low water content was the main limiting factor as in fact laboratory data showed that only above 75% of water saturation, N2O emissions

  5. Highly stable CO2/N2 and CO2/CH4 selectivity in hyper-cross-linked heterocyclic porous polymers.

    Science.gov (United States)

    Saleh, Muhammad; Lee, Han Myoung; Kemp, K Christian; Kim, Kwang S

    2014-05-28

    The largest obstacles for landfill/flue gas separation using microporous materials are small adsorption values and low selectivity ratios. This study demonstrates that these adsorption and selectivity challenges can be overcome by utilizing a series of hyper-cross-linked heterocyclic polymer networks. These microporous organic polymers (MOPs) were synthesized in a single step by inexpensive Friedel-Crafts-catalyzed reactions using dimethoxymethane as an external linker. The amorphous networks show moderate Brunauer-Emmett-Teller surface areas up to 1022 m(2) g(-1), a narrow pore size distribution in the range from 6 to 8 Å, and high physicochemical stability. Owing to the presence of the heteroatomic pore surfaces in the networks, they exhibit maximum storage capacities for CO2 of 11.4 wt % at 273 K and 1 atm. Additionally, remarkable selectivity ratios for CO2 adsorption over N2 (100) and CH4 (15) at 273 K were obtained. More importantly, as compared with any other porous materials, much higher selectivity for CO2/N2 (80) and CO2/CH4 (15) was observed at 298 K, showing that these selectivity ratios remain high at elevated temperature. The very high CO2/N2 selectivity values are ascribed to the binding affinity of abundantly available electron-rich basic heteroatoms, high CO2 isoteric heats of adsorption (49-38 kJ mol(-1)), and the predominantly microporous nature of the MOPs. Binding energies calculated using the high level of ab initio theory showed that the selectivity is indeed attributed to the heteroatom-CO2 interactions. By employing an easy and economical synthesis procedure these MOPs with high thermochemical stability are believed to be a promising candidate for selective CO2 capture.

  6. Pure- and mixed-gas CO2/CH4 separation properties of PIM-1 and an amidoxime-functionalized PIM-1

    KAUST Repository

    Swaidan, Raja

    2014-05-01

    The prototypical solution-processable polymer of intrinsic microporosity, PIM-1, and derivatives thereof offer combinations of permeability and selectivity that make them potential candidate materials for membrane-based gas separations. Paramount to the design and evaluation of PIMs for economical natural gas sweetening is a high and stable CO2/CH4 selectivity under realistic, mixed-gas conditions. Here, amidoxime-functionalized PIM-1 (AO-PIM-1) was prepared and examined for fundamental structure/property relationships. Qualitative NLDFT pore-size distribution analyses of physisorption isotherms (N2 at -196 oC; CO2 at 0 oC) reveal a tightened microstructure indicating size-sieving ultra-microporosity (<7Å). AO-PIM-1 demonstrated a three-fold increase in αD(CO2/CH4) over PIM-1, surpassing the 2008 upper bound with P(CO2)=1153Barrer and ideal α(CO2/CH4)=34. Under a 50:50 CO2:CH4 mixed-gas feed, AO-PIM-1 showed less selectivity loss than PIM-1, maintaining a mixed-gas α(CO2/CH4) ~21 across a 20bar pressure range. Conversely, PIM-1 endured up to 60% increases in mixed-gas CH4 permeability over pure-gas values concurrent with a selectivity of only ~8 at 20bar. A pervasive intermolecular hydrogen bonding network in AO-PIM-1 predominantly yields a rigidified microstructure that mitigates CO2-induced matrix dilations, reducing detrimental mixed-gas CH4 copermeation. © 2014 Elsevier B.V.

  7. Winter greenhouse gas emissions (CO2, CH4 and N2O from a sub-alpine grassland

    Directory of Open Access Journals (Sweden)

    F. Hagedorn

    2013-01-01

    Full Text Available Carbon dioxide (CO2, methane (CH4 and nitrous oxide (N2O fluxes were measured during the winter 2010/2011 at a~sub-alpine managed grassland in Switzerland using concentration gradients within the snowpack (CO2, CH4, N2O and the eddy covariance method (CO2. Measured snow densities were used to calculate the respective greenhouse gas (GHG fluxes. Mean winter fluxes based on the gradient method were 0.74 ± 0.53 μmol m−2 s−1 for CO2, −0.14 ± 0.09 nmol m−2 s−1 for CH4 and 0.23 ± 0.23 nmol m−2 s−1 for N2O, respectively. While CO2 and CH4 fluxes decreased with progressing winter season N2O fluxes did not follow a~seasonal pattern. Key variables driving the fluxes of CO2 and CH4 were soil surface temperatures and snow-water equivalent. N2O fluxes were only poorly explained by any of the measured factors in the soil and snow. Spatial variability across the valley floor was smallest for CO2 and largest for N2O. During the winter season 2010/2011 (November–April greenhouse gas fluxes accumulated to 631–670 g CO2 m−2, −0.04 g CH4 m−2 and 0.13 g N2O m−2. Total greenhouse gas emissions from the grassland were between 669–709 g CO2 eq. m−2, with N2O contributing 5% to the overall budget and CH4 reducing the budget by less than 1%. In comparison with the CO2 fluxes measured by eddy covariance, the gradient technique underestimated the effluxes during the main winter period by 40% but yielded similar fluxes on a seasonal basis. Cumulative budgets of CO2 were smaller than emission reported for other sub-alpine meadows in the Swiss Alps and the Rocky Mountains. It remains unclear how GHG emissions are altered by changes in climate and according snow conditions.

  8. Calculation of 2-temperature plasma thermo-physical properties considering condensed phases: application to CO2-CH4 plasma: part 1. Composition and thermodynamic properties

    Science.gov (United States)

    Wu, Yi; Chen, Zhexin; Rong, Mingzhe; Cressault, Yann; Yang, Fei; Niu, Chunping; Sun, Hao

    2016-10-01

    As the first part of this series of papers, a new calculation method for composition and thermodynamic properties of 2-temperature plasma considering condensed species under local chemical equilibrium (LCE) and local phase equilibrium assumption is presented. The 2-T mass action law and chemical potential are used to determine the composition of multiphase system. The thermo-physical properties of CO2-CH4 mixture, which may be a possible substitution for SF6, are calculated by this method as an example. The influence of condensed graphite, non-LTE effect, mixture ratio and pressure on the thermo-physical properties has been discussed. The results will serve as reliable reference data for computational simulation of CO2-CH4 plasmas.

  9. Calculation of 2-temperature plasma thermo-physical properties considering condensed phases: application to CO2-CH4 plasma: part 2. Transport coefficients

    Science.gov (United States)

    Niu, Chunping; Chen, Zhexin; Rong, Mingzhe; Wang, Chunlin; Wu, Yi; Yang, Fei; Wang, Xiaohua; Pang, Qingping

    2016-10-01

    The transport coefficients, namely thermal conductivity, viscosity and electrical conductivity, of CO2-CH4 mixture in and out of LTE are calculated in this paper. The calculation was based on local chemical equilibrium (LCE) and local phase equilibrium assumption. The 2-temperature composition results obtained with consideration of condensed phase in the previous paper (Part I) of this series were used in this calculation. The transport coefficients were calculated by classical Chapman-Enskog method simplified by Devoto. The results are presented for different temperatures (300-30 000 K), pressures (0.1-10 atm), non-equilibrium degrees (1-5), and CH4 molar proportions (0-100%). The influence of condensed graphite, non-LTE effect, mixture ratio and pressure on the composition and thermodynamic properties has been discussed. The results will serve as reliable reference data for computational simulation of CO2-CH4 plasmas.

  10. Pure- and Mixed-Gas Permeation Properties of Highly Selective and Plasticization Resistant Hydroxyl-Diamine-Based 6FDA Polyimides for CO2/CH4 Separation

    KAUST Repository

    Alaslai, Nasser

    2016-01-05

    The effect of hydroxyl functionalization on the m-phenylene diamine moiety of 6FDA dianhydride-based polyimides was investigated for gas separation applications. Pure-gas permeability coefficients of He, H2, N2, O2, CH4, and CO2 were measured at 35 °C and 2 atm. The introduction of hydroxyl groups in the diamine moiety of 6FDA-diaminophenol (DAP) and 6FDA-diamino resorcinol (DAR) polyimides tightened the overall polymer structure due to increased charge transfer complex formation compared to unfunctionalized 6FDA-m-phenylene diamine (mPDA). The BET surface areas based on nitrogen adsorption of 6FDA-DAP (54 m2g−1) and of 6FDA-DAR (45 m2g−1) were ~18% and 32% lower than that of 6FDA-mPDA (66 m2g−1). 6FDA-mPDA had a pure-gas CO2 permeability of 14 Barrer and CO2/CH4 selectivity of 70. The hydroxyl-functionalized polyimides 6FDA-DAP and 6FDA-DAR exhibited very high pure-gas CO2/CH4 selectivities of 92 and 94 with moderate CO2 permeability of 11 and 8 Barrer, respectively. It was demonstrated that hydroxyl-containing polyimide membranes maintained very high CO2/CH4 selectivity (~ 75 at CO2 partial pressure of 10 atm) due to CO2 plasticization resistance when tested under high-pressure mixed-gas conditions. Functionalization with hydroxyl groups may thus be a promising strategy towards attaining highly selective polyimides for economical membrane-based natural gas sweetening.

  11. Fluxes of CO2, CH4 and N2O from a temperate forest soil: the effects of leaves and humus layers

    OpenAIRE

    Dong, Y.; D. Scharffe; J. M. Lobert; Crutzen, P. J.; Sanhueza, E.

    2011-01-01

    Fluxes of CO2, CH4, and N2O from forest soils were measured with an enclosed chamber technique between October 1990 and December 1991 in a deciduous forest near Darmstadt, Germany. Flux measurements were made before and after the removal of leaves and humus layer from the forest floor, and gas fluxes from the leaves and humus alone were also measured as well as depth profiles of CH4, N2O, and soil moisture. Except for N2O, large seasonal variations were observed with generally higher gas flux...

  12. Adsorption Kinetics of CO2, CH4, and their Equimolar Mixture on Coal from the Black Warrior Basin, West-Central Alabama

    Energy Technology Data Exchange (ETDEWEB)

    Gruszkiewicz, Miroslaw {Mirek} S [ORNL; Naney, Michael {Mike} T [ORNL; Blencoe, James {Jim} G [ORNL; Cole, David R [ORNL; Pashin, Jack C. [Geological Survey of Alabama; Carroll, Richard E. [Geological Survey of Alabama

    2009-01-01

    Laboratory experiments were conducted to investigate the adsorption kinetic behavior of pure and mixed gases (CO2, CH4, approximately equimolar CO2 + CH4 mixtures, and He) on a coal sample obtained from the Black Warrior Basin at the Littleton Mine (Twin Pine Coal Company), Jefferson County, west-central Alabama. The sample was from the Mary Lee coal zone of the Pottsville Formation (Lower Pennsylvanian). Experiments with three size fractions (45-150 m, 1-2 mm, and 5-10 mm) of crushed coal were performed at 40 C and 35 C over a pressure range of 1.4 6.9 MPa to simulate coalbed methane reservoir conditions in the Black Warrior Basin and provide data relevant for enhanced coalbed methane recovery operations. The following key observations were made: (1) CO2 adsorption on both dry and water-saturated coal is much more rapid than CH4 adsorption; (2) water saturation decreases the rates of CO2 and CH4 adsorption on coal surfaces, but it appears to have minimal effects on the final magnitude of CO2 or CH4 adsorption if the coal is not previously exposed to CO2; (3) retention of adsorbed CO2 on coal surfaces is significant even with extreme pressure cycling; and (4) adsorption is significantly faster for the 45-150 m size fraction compared to the two coarser fractions.

  13. Adsorption kinetics of CO2, CH4, and their equimolar mixture on coal from the Black Warrior Basin, West-Central Alabama

    Science.gov (United States)

    Gruszkiewicz, M.S.; Naney, M.T.; Blencoe, J.G.; Cole, D.R.; Pashin, J.C.; Carroll, R.E.

    2009-01-01

    Laboratory experiments were conducted to investigate the adsorption kinetic behavior of pure and mixed gases (CO2, CH4, approximately equimolar CO2 + CH4 mixtures, and He) on a coal sample obtained from the Black Warrior Basin at the Littleton Mine (Twin Pine Coal Company), Jefferson County, west-central Alabama. The sample was from the Mary Lee coal zone of the Pottsville Formation (Lower Pennsylvanian). Experiments with three size fractions (45-150????m, 1-2??mm, and 5-10??mm) of crushed coal were performed at 40????C and 35????C over a pressure range of 1.4-6.9??MPa to simulate coalbed methane reservoir conditions in the Black Warrior Basin and provide data relevant for enhanced coalbed methane recovery operations. The following key observations were made: (1) CO2 adsorption on both dry and water-saturated coal is much more rapid than CH4 adsorption; (2) water saturation decreases the rates of CO2 and CH4 adsorption on coal surfaces, but it appears to have minimal effects on the final magnitude of CO2 or CH4 adsorption if the coal is not previously exposed to CO2; (3) retention of adsorbed CO2 on coal surfaces is significant even with extreme pressure cycling; and (4) adsorption is significantly faster for the 45-150????m size fraction compared to the two coarser fractions. ?? 2008 Elsevier B.V.

  14. Role of intrachain rigidity in the plasticization of intrinsically microporous triptycene-based polyimide membranes in mixed-Gas CO2/CH4 separations

    KAUST Repository

    Swaidan, Raja

    2014-11-11

    Based on high-pressure pure- and mixed-gas (50:50) CO2/CH4 separation properties of two intrinsically microporous triptycene-based polyimides (TPDA-TMPD and TPDA-6FpDA), the intrachain rigidity central to "conventional PIM" design principles is not a singular solution to intrinsic plasticization resistance. Despite the significant intrachain rigidity in TPDA-TMPD, a 300% increase in PMIX(CH4), 50% decrease in α(CO2/CH4) from 24 to 12, and continuous increase in PMIX(CO2) occurred from 4 to 30 bar. On the other hand, the more flexible and densely packed TPDA-6FpDA exhibited a slight upturn in PMIX(CO2) at 20 bar similar to a dense cellulose acetate (CA) film, also reported here, despite a 4-fold higher CO2 sorption capacity. Microstructural investigations suggest that the interconnected O2- and H2-sieving ultramicroporosity of TPDA-TMPD is more sensitive to slight CO2-induced dilations and is the physical basis for a more extensive and accelerated plasticization. Interchain rigidity, potentially by interchain interactions, is emphasized and may be facilitated by intrachain mobility.

  15. Ten years of CO2, CH4, CO and N2O fluxes over Western Europe inferred from atmospheric measurements at Mace Head, Ireland

    Directory of Open Access Journals (Sweden)

    S. G. Jennings

    2008-01-01

    Full Text Available We estimated CO2, CH4, CO and N2O emission fluxes over the British Isles and Western Europe using atmospheric radon observations and concentrations recorded at the Mace Head Atmospheric Research Station between 1996 and 2005. We classified hourly concentration data into either long-range European or regional sources from Ireland and UK, by using local wind speed data in conjunction with 222Rn and 212Pb threshold criteria. This leads to the selection of about 7% of the total data for both sectors. We then used continuous 222Rn measurements and assumptions on the surface emissions of 222Rn to deduce the unknown fluxes of CO2, CH4, CO and N2O. Our results have been compared to the UNFCCC, EMEP and EDGAR statistical inventories and to inversion results for CH4. For Western Europe, we found yearly mean fluxes of 4.1±1.5 106 kg CO2 km−2 yr−1 , 11.9±2.0 103 kg CH4 km−2 yr−1, 12.8±4.2 103 kg CO km−2 yr−1 and 520.2±129.2 kg N2O km−2 yr−1, respectively, for CO2, CH4, CO and N2O over the period 1996–2005. The method based upon 222Rn to infer emissions has many sources of systematic errors, in particular its poorly known and variable footprint, uncertainties in 222Rn soil fluxes and in atmospheric mixing of air masses with background air. However, these biases are likely to remain constant in the long-term, which makes the method quite efficient to detect trends in fluxes. Over the last ten years period, the decrease of the anthropogenic CH4, CO and N2O emissions in Europe estimated by inventories (respectively −30%, −35% and −23% is confirmed by the Mace Head data within 2%. Therefore, the 222Rn method provides an independent way of verification of changes in national emissions derived from inventories. Using European-wide estimates of the CO/CO2 emission ratio, we also found that it is possible to separate the fossil fuel CO2 emissions contribution from the one of total CO2 fluxes. The fossil fuel CO2 emissions and their trends

  16. Sub-arctic Wetland Greenhouse Gases (CO2, CH4 & N2O) Emissions are Driven by Interactions of Environmental Controls and Herbivore Grazers

    Science.gov (United States)

    Kelsey, K.; Leffler, A. J.; Beard, K. H.; Choi, R. T.; Welker, J. M.

    2015-12-01

    Climate change is increasing temperatures, altering precipitation regimes and causing earlier growing seasons, particularly at northern latitudes. Such changes in local environmental conditions have the potential to affect biogeochemical cycling including the exchange of greenhouses gases between the atmosphere and the terrestrial biosphere. In addition to the effects of these environmental controls, animals such as migratory geese also influence biogeochemical cycles through grazing, trampling and delivering nutrient-rich fecal matter. In this work we aimed to quantify how local environmental conditions and the presence of grazing interact as drivers of emissions of three key greenhouse gases, CO2, CH4 and N2O, in coastal wetlands of the Yukon Kuskokwim Delta. We explored the magnitude of emissions across gradients of soil temperature and water table depth, and across vegetation types related to the presence of grazing, ranging from no vegetation through grazed and ungrazed vegetation. We also investigated emissions from grazed areas using experimental manipulations of the timing of grazing and advancement of the growing season. We found that local environmental conditions and use by grazers exert interacting controls on emissions of CO2, CH4 and N2O. Emissions of CO2 and CH4 were positively related to soil temperature and CH4 emissions were inversely related to water table depth, but the relationship varied by vegetation type. Net emissions of CO2 were greatest in ungrazed vegetation types (6.62 umols CO2 m-2 sec-1; p=0.0007) whereas CH4 emissions were greatest in the grazed vegetation (122.56 nmols CH4 m-2 sec-1; p=0.037). Flux of N2O was less than 1 nmol N2O m-2 sec-1 across all landscape positions under typical grazing and temperature conditions, but emissions were stimulated to over 10 nmols m-2 sec-1 when grazing occurred early relative to a typical season. Our results indicate that environmental conditions and the presence of migratory herbivores are both

  17. Fluid geochemistry and soil gas fluxes (CO2-CH4-H2S) at a promissory Hot Dry Rock Geothermal System: The Acoculco caldera, Mexico

    Science.gov (United States)

    Peiffer, L.; Bernard-Romero, R.; Mazot, A.; Taran, Y. A.; Guevara, M.; Santoyo, E.

    2014-09-01

    The Acoculco caldera has been recognized by the Mexican Federal Electricity Company (CFE) as a Hot Dry Rock Geothermal System (HDR) and could be a potential candidate for developing an Enhanced Geothermal System (EGS). Apart from hydrothermally altered rocks, geothermal manifestations within the Acoculco caldera are scarce. Close to ambient temperature bubbling springs and soil degassing are reported inside the caldera while a few springs discharge warm water on the periphery of the caldera. In this study, we infer the origin of fluids and we characterize for the first time the soil degassing dynamic. Chemical and isotopic (δ18O-δD) analyses of spring waters indicate a meteoric origin and the dissolution of CO2 and H2S gases, while gas chemical and isotopic compositions (N2/He, 3He/4He, 13C, 15N) reveal a magmatic contribution with both MORB- and arc-type signatures which could be explained by an extension regime created by local and regional fault systems. Gas geothermometry results are in agreement with temperature measured during well drilling (260 °C-300 °C). Absence of well-developed water reservoir at depth impedes re-equilibration of gases upon surface. A multi-gas flux survey including CO2, CH4 and H2S measurements was performed within the caldera. Using the graphical statistical analysis (GSA) approach, CO2 flux measurements were classified in two populations. Population A, representing 95% of measured fluxes is characterized by low values (mean: 18 g m- 2 day- 1) while the remaining 5% fluxes belonging to Population B are much higher (mean: 5543 g m- 2 day- 1). This low degassing rate probably reflects the low permeability of the system, a consequence of the intense hydrothermal alteration observed in the upper 800 m of volcanic rocks. An attempt to interpret the origin and transport mechanism of these fluxes is proposed by means of flux ratios as well as by numerical modeling. Measurements with CO2/CH4 and CO2/H2S flux ratios similar to mass ratios

  18. Technical Note: Latitude-time variations of atmospheric column-average dry air mole fractions of CO2, CH4 and N2O

    Directory of Open Access Journals (Sweden)

    M. Rettinger

    2012-08-01

    Full Text Available We present a comparison of an atmospheric general circulation model (AGCM-based chemistry-transport model (ACTM simulation with total column measurements of CO2, CH4 and N2O from the Total Carbon Column Observing Network (TCCON. The model is able to capture observed trends, seasonal cycles and inter hemispheric gradients at most sampled locations for all three species. The model-observation agreements are best for CO2, because the simulation uses fossil fuel inventories and an inverse model estimate of non-fossil fuel fluxes. The ACTM captures much of the observed seasonal variability in CO2 and N2O total columns (~81 % variance, R>0.9 between ACTM and TCCON for 19 out of 22 cases. These results suggest that the transport processes in troposphere and stratosphere are well represented in ACTM. Thus the poor correlation between simulated and observed CH4 total columns, particularly at tropical and extra-tropical sites, have been attributed to the uncertainties in surface emissions and loss by hydroxyl radicals. While the upward-looking total column measurements of CO2 contains surface flux signals at various spatial and temporal scales, the N2O measurements are strongly affected by the concentration variations in the upper troposphere and stratosphere.

  19. Greenhouse Gas Emissions (CO2-CH4 From Municipal Solid Waste Management Using Life Cycle Assessment (LCA in Mahdsht City (IRAN

    Directory of Open Access Journals (Sweden)

    Naderi M

    2014-08-01

    Full Text Available Waste production is inevitable in any society and consequently waste management is one of the main roles of any municipality. Therefore, it is necessary to evaluate different waste management scenarios. According to the amount and composition of the generated waste, considering environmental, economic and technical issues, several options are existed. Life Cycle Assessment (LCA as a decision support tool has been used in several cases to select the most appropriate option. In this paper, production of greenhouse gases (CO2-CH4 in different waste management options in Mahdasht city (Iran has been studied using IWM software and LCA application. Two scenarios has been defined, the first includes direct and complete transferring of waste to the landfill, and the second includes transferring of 76% of total waste to the landfill and recycling 20% and composting 4%. The questionnaires were fulfilled by the staffs and field surveying. The life cycle inventory cataloging was done using the IWM-1model according to environmental point of view. The amount of produced greenhouse gases in the first scenario is about 9,218 tons and in the second scenario is about 6,801 tons. Results indicate that implementing recycling and composting operation can lead to the 26% reduction in greenhouse gas emissions and energy consumption reduction of a waste management system.

  20. AC plasma torch with a H2O/CO2/CH4 mix as the working gas for methane reforming

    International Nuclear Information System (INIS)

    This paper presents results of investigations implemented during construction of the three-phase ac plasma torch working on a mixture of steam with carbon dioxide and methane (H2O/CO2/CH4) with power upto 120 kW. Such thermal plasma generators are needed in industrial technologies for methane reforming with the aim of producing the syngas comprising of the hydrogen and carbon mono-oxide (H2/CO). It was shown that during plasma torch work there are two character parts of the high-voltage arc. In these parts, the arc column has a different diameter and temperature about (8.5  −  8.3) · 103 K and (10.5  −  10.0) · 103 K, respectively. The plasma torch output characteristics have been obtained for working regimes with various flow rates of the methane (0.0–0.8 g s−1) in the plasma-forming mix and constant flow rates of the carbon dioxide and water steam (each of 3.0 g s−1). For the mentioned mix of gases, the unit generates plasma with the mass-average temperature ∼(3.2–3.3) · 103K and the thermal efficiency ∼94–96%. This provides effective reforming of methane. (paper)

  1. Frequency Comb Spectroscopy of CO(2), CH(4), H(2)O, and Isotopes Over a 2 km Outdoor Path: Concentration Retrievals Using Different Absorption Models

    Science.gov (United States)

    Rieker, G. B.; Giorgetta, F. R.; Coddington, I.; Swann, W. C.; Zolot, A. M.; Sinclair, L. C.; Baumann, E.; Cromer, C.; Newbury, N.

    2014-06-01

    A dual frequency comb spectrometer is used to make high signal-to-noise measurements of atmospheric absorption from 5990 to 6260 cm-1 with 0.0033 cm-1 point spacing and ˜4·10-8 cm-1 resolution over a 2 km outdoor air path. The spectra, which encompass over 700 absorption features of CO2, CH4, and H2O, are fit with several absorption models to assess the quality of the models and to retrieve the various species concentrations and air temperature. The models tested include the HITRAN 2008 and 2012 spectral databases with Voigt line-shape profiles as well as a recent model for CO2 that includes the effects of line mixing and speed dependence. Residuals are typically less than 2% of the peak absorbance, except for the HITRAN 2012 CH4 model, which exhibits larger residuals. Species concentration retrievals using the models are compared with a calibrated point sensor mounted on a tower near the open air path.

  2. Potential of a geostationary geoCARB mission to estimate surface emissions of CO2, CH4 and CO in a polluted urban environment: case study Shanghai

    Science.gov (United States)

    O'Brien, Denis M.; Polonsky, Igor N.; Utembe, Steven R.; Rayner, Peter J.

    2016-09-01

    This paper describes a numerical experiment to test the ability of the proposed geoCARB satellite to estimate emissions of trace gases (CO2, CH4 and CO) in the polluted urban environment of Shanghai. The meteorology over Shanghai is simulated with the Weather Research and Forecasting (WRF) model for a 9-day period in August 2010. The meteorology includes water and ice clouds. The chemistry version of WRF (WRF-Chem V3.6.1) is used to predict the chemical composition, mass density and number density of aerosol species. Spectra in the bands measured by geoCARB are calculated, including the effects of polarisation and multiple scattering of radiation by clouds, aerosols and molecules. Instrument noise is added, and column-averaged trace-gas mole fractions are estimated from the noisy spectra using an algorithm based on that for the Greenhouse Gases Observing Satellite (GOSAT) and the Orbiting Carbon Observatory-2 (OCO-2) but adapted to geoCARB. As expected, the high aerosol loadings are challenging. However, when the retrieval algorithm is provided with regionally adjusted aerosol optical properties, as might be determined from observations of dark targets within the field of regard, the accuracies of retrieved concentrations are comparable to those reported earlier for geoCARB. Statistics of the errors in the retrieved column-averaged concentrations are used to predict the reduction in uncertainty of surface emissions possible with remotely sensed data.

  3. Effects of hydroxyl-functionalization and sub-Tg thermal annealing on high pressure pure- and mixed-gas CO2/CH4 separation by polyimide membranes based on 6FDA and triptycene-containing dianhydrides

    KAUST Repository

    Swaidan, Raja

    2015-02-01

    A sub-Tg thermally-annealed (250°C, 24h) ultra-microporous PIM-polyimide bearing a 9,10-diisopropyl-triptycene contortion center and hydroxyl-functionalized diamine (2,2-bis(3-amino-4-hydroxyphenyl)-hexafluoropropane, APAF) exhibited plasticization resistance up to 50bar for a 1:1 CO2/CH4 feed mixture, with a 9-fold higher CO2 permeability (30Barrer) and 2-fold increase in CO2/CH4 permselectivity (~50) over conventional dense cellulose acetate membranes at 10bar CO2 partial pressure. Interestingly, mixed-gas CO2/CH4 permselectivities were 10-20% higher than those evaluated under pure-gas conditions due to reduction of mixed-gas CH4 permeability by co-permeation of CO2. Gas transport, physisorption and fluorescence studies indicated a sieving pore-structure engaged in inter-chain charge transfer complexes (CTCs), similar to that of low-free-volume 6FDA-APAF polyimide. The isosteric heat of adsorption of CO2 as well as CO2/CH4 solubility selectivities varied negligibly upon replacement of OH with CH3 but CTC formation was hindered, CO2 sorption increased, CO2 permeability increased ~3-fold, CO2/CH4 permselectivity dropped to ~30 and CH4 mixed-gas co-permeation increased. These results suggest that hydroxyl-functionalization did not cause preferential polymer-gas interactions but primarily elicited diffusion-dominated changes owing to a tightened microstructure more resistant to CO2-induced dilations. Solution-processable hydroxyl-functionalized PIM-type polyimides provide a new platform of advanced materials that unites the high selectivities of low-free-volume polymers with the high permeabilities of PIM-type materials particularly for natural gas sweetening applications.

  4. Beyond the Methanogenic Black-Box: Greenhouse Gas Fluxes (CO2, CH4, N2O) as Evidence for Wetlands as Dynamic Redox Systems

    Science.gov (United States)

    Mcnicol, G.; Knox, S. H.; Sturtevant, C. S.; Baldocchi, D. D.; Silver, W. L.

    2015-12-01

    Seminal wetland research in the 1990s demonstrated that annual methane (CH4) fluxes scaled positively with ecosystem production across distinctive wetlands globally. This relationship implies a model of flooded wetland ecosystems as 'methanogenic black-boxes'; poised at a low redox state, and tending to release a fixed fraction of incoming annual productivity as CH4. In contrast, recent studies have reported high ratios of carbon dioxide (CO2) to CH4 emissions, and are adding to a body of evidence suggesting wetlands can vary more widely in their redox state. To explore this apparent incongruence we used principles of redox thermodynamics and laboratory experiments to develop predictions of wetland greenhouse gas (GHG) fluxes under different redox regimes. We then used a field study to test the hypothesis that ecosystem seasonality in gross primary productivity (GPP) and temperature would drive changes in GHG emissions, mediated by a dynamic - as opposed to static - redox regime. We estimated wetland GHG emissions from an emergent marsh in the Sacramento Delta, CA from March 2014-2015. We measured CO2, CH4 and N2O emissions via diffusion and ebullition with manual sampling, and whole-ecosystem fluxes of CO2 and CH4 using eddy-covariance. Ebullition and diffusive CH4 fluxes were strongly seasonal, with minimum rates (0.86 and 0.35 mg C-CH­­4 m-2 yr-1, respectively) during winter, and maximum rates (1.3 and 1.8 g C-CH­­4 m-2 yr-1, respectively) during the summer growing season. In contrast, winter diffusive CO2 fluxes (494 g C-CO2 m-2 yr-1) and fall bubble CO2 concentrations (1.49%) were highest, despite being seasons of lower GPP, temperature, and CH4 flux. Further, diffusive and ebullition fluxes of N2O showed zero net flux only during spring and summer months, whereas the wetland was a significant source of N2O during winter (81.2 ± 24.4 mg N-N2O m-2 yr-1). These seasonal flux dynamics contradict a 'methanogenic black box' model of wetland redox, which

  5. Soil-atmospheric exchange of CO2, CH4, and N2O in three subtropical forest ecosystems in southern China

    Science.gov (United States)

    Tang, X.; Liu, S.; Zhou, G.; Zhang, Dongxiao; Zhou, C.

    2006-01-01

    The magnitude, temporal, and spatial patterns of soil-atmospheric greenhouse gas (hereafter referred to as GHG) exchanges in forests near the Tropic of Cancer are still highly uncertain. To contribute towards an improvement of actual estimates, soil-atmospheric CO2, CH4, and N2O fluxes were measured in three successional subtropical forests at the Dinghushan Nature Reserve (hereafter referred to as DNR) in southern China. Soils in DNR forests behaved as N2O sources and CH4 sinks. Annual mean CO2, N2O, and CH4 fluxes (mean ?? SD) were 7.7 ?? 4.6MgCO2-Cha-1 yr-1, 3.2 ?? 1.2 kg N2ONha-1 yr-1, and 3.4 ?? 0.9 kgCH4-Cha-1 yr-1, respectively. The climate was warm and wet from April through September 2003 (the hot-humid season) and became cool and dry from October 2003 through March 2004 (the cool-dry season). The seasonality of soil CO2 emission coincided with the seasonal climate pattern, with high CO2 emission rates in the hot-humid season and low rates in the cool-dry season. In contrast, seasonal patterns of CH4 and N2O fluxes were not clear, although higher CH4 uptake rates were often observed in the cool-dry season and higher N2O emission rates were often observed in the hot-humid season. GHG fluxes measured at these three sites showed a clear increasing trend with the progressive succession. If this trend is representative at the regional scale, CO2 and N2O emissions and CH4 uptake in southern China may increase in the future in light of the projected change in forest age structure. Removal of surface litter reduced soil CO2 effluxes by 17-44% in the three forests but had no significant effect on CH4 absorption and N2O emission rates. This suggests that microbial CH4 uptake and N2O production was mainly related to the mineral soil rather than in the surface litter layer. ?? 2006 Blackwell Publishing Ltd.

  6. Ground-based, integrated path differential absorption LIDAR measurement of CO2, CH4, and H2O near 1.6  μm.

    Science.gov (United States)

    Wagner, Gerd A; Plusquellic, David F

    2016-08-10

    A ground-based, integrated path, differential absorption light detection and ranging (IPDA LIDAR) system is described and characterized for a series of nighttime studies of CO2, CH4, and H2O. The transmitter is based on an actively stabilized, continuous-wave, single-frequency external-cavity diode laser (ECDL) operating from 1.60 to 1.65 μm. The fixed frequency output of the ECDL is microwave sideband tuned using an electro-optical phase modulator driven by an arbitrary waveform generator and filtered using a confocal cavity to generate a sequence of 123 frequencies separated by 300 MHz. The scan sequence of single sideband frequencies of 600 ns duration covers a 37 GHz region at a spectral scan rate of 10 kHz (100 μs per scan). Simultaneously, an eye-safe backscatter LIDAR system at 1.064 μm is used to monitor the atmospheric boundary layer. IPDA LIDAR measurements of the CO2 and CH4 dry air mixing ratios are presented in comparison with those from a commercial cavity ring-down (CRD) instrument. Differences between the IPDA LIDAR and CRD concentrations in several cases appear to be well correlated with the atmospheric aerosol structure from the backscatter LIDAR measurements. IPDA LIDAR dry air mixing ratios of CO2 and CH4 are determined with fit uncertainties of 2.8 μmol/mol (ppm) for CO2 and 22 nmol/mol (ppb) for CH4 over 30 s measurement periods. For longer averaging times (up to 1200 s), improvements in these detection limits by up to 3-fold are estimated from Allan variance analyses. Two sources of systematic error are identified and methods to remove them are discussed, including speckle interference from wavelength decorrelation and the seed power dependence of amplified spontaneous emission. Accuracies in the dry air retrievals of CO2 and CH4 in a 30 s measurement period are estimated at 4 μmol/mol (1% of ambient levels) and 50 nmol/mol (3%), respectively. PMID:27534472

  7. CO2, CH4 and N2O fluxes in an Ultisol treated with sewage sludge and cultivated with castor bean Fluxos de CO2, CH4 e N2O de um Argissolo tratado com lodo de esgoto e cultivado com mamona

    Directory of Open Access Journals (Sweden)

    Jonas Jacob Chiaradia

    2009-12-01

    Full Text Available Organic residue application into soil alter the emission of gases to atmosphere and CO2, CH4, N2O may contribute to increase the greenhouse effect. This experiment was carried out in a restoration area on a dystrophic Ultisol (PVAd to quantify greenhouse gas (GHG emissions from soil under castor bean cultivation, treated with sewage sludge (SS or mineral fertilizer. The following treatments were tested: control without N; FertMin = mineral fertilizer; SS5 = 5 t ha-1 SS (37.5 kg ha-1 N; SS10 = 10 t ha-1 SS (75 kg ha-1 N; and SS20 = 20 t ha-1 SS (150 kg ha-1 N. The amount of sludge was based on the recommended rate of N for castor bean (75 kg ha-1, the N level of SS and the mineralization fraction of N from SS. Soil gas emission was measured for 21 days. Sewage sludge and mineral fertilizers altered the CO2, CH4 and N2O fluxes. Soil moisture had no effect on GHG emissions and the gas fluxes was statistically equivalent after the application of FertMin and of 5 t ha-1 SS. The application of the entire crop N requirement in the form of SS practically doubled the Global Warming Potential (GWP and the C equivalent emissions in comparison with FertMin treatments.A aplicação de resíduos orgânicos no solo pode alterar a emissão de gases para atmosfera e dentre estes, CO2, CH4 e N2O, podem contribuir para o aumento do efeito estufa. Este ensaio foi realizado com o objetivo de quantificar a emissão de gases do efeito estufa (GEE de um Argissolo Vermelho-Amarelo distrófico (PVAd tratado com lodo de esgoto (LE e cultivado com mamoneira em área de reforma de canavial. Os tratamentos testados foram: Controle sem N; FertMin = fertilizante mineral; LE5 = 5 t ha-1 de LE, equivalente a 37,5 kg ha-1 de N; LE10 = 10 t ha-1 de LE, equivalente a 75 kg ha-1 de N; e LE20 = 20 t ha-1 de LE, equivalente a 150 kg ha-1 de N. A quantidade de lodo foi baseada na rate recomendada de N para a mamoneira (75 kg ha-1, nas quantidades de N no LE e na fração de mineraliza

  8. High pressure pure- and mixed-gas separation of CO2/CH4 by thermally-rearranged and carbon molecular sieve membranes derived from a polyimide of intrinsic microporosity

    KAUST Repository

    Swaidan, Raja

    2013-11-01

    Natural gas sweetening, one of the most promising venues for the growth of the membrane gas separation industry, is dominated by polymeric materials with relatively low permeabilities and moderate selectivities. One strategy towards improving the gas transport properties of a polymer is enhancement of microporosity either by design of polymers of intrinsic microporosity (PIMs) or by thermal treatment of polymeric precursors. For the first time, the mixed-gas CO2/CH4 transport properties are investigated for a complete series of thermally-rearranged (TR) (440°C) and carbon molecular sieve (CMS) membranes (600, 630 and 800°C) derived from a polyimide of intrinsic microporosity (PIM-6FDA-OH). The pressure dependence of permeability and selectivity is reported up to 30bar for 1:1, CO2:CH4 mixed-gas feeds at 35°C. The TR membrane exhibited ~15% higher CO2/CH4 selectivity relative to pure-gas feeds due to reductions in mixed-gas CH4 permeability reaching 27% at 30bar. This is attributed to increased hindrance of CH4 transport by co-permeation of CO2. Interestingly, unusual increases in mixed-gas CH4 permeabilities relative to pure-gas values were observed for the CMS membranes, resulting in up to 50% losses in mixed-gas selectivity over the applied pressure range. © 2013 Elsevier B.V.

  9. Fluxes of CO2, CH4 and N2O at two European beech forests: linking soil gas production profiles with soil and stem fluxes

    Science.gov (United States)

    Maier, Martin; Machacova, Katerina; Halaburt, Ellen; Haddad, Sally; Urban, Otmar; Lang, Friederike

    2016-04-01

    Soil and plant surfaces are known to exchange greenhouse gases with the atmosphere. Some gases like nitrous oxide (N2O) and methane (CH4) can be produced and re-consumed in different soil depths and soil compartments, so that elevated concentrations of CH4 or N2O in the soil do not necessarily mean a net efflux from the soil into the atmosphere. Soil aeration, and thus the oxygen status can underlay a large spatial variability within the soil on the plot and profile scale, but also within soil aggregates. Thus, conditions suitable for production and consumption of CH4 and N2O can vary on different scales in the soil. Plant surfaces can also emit or take up CH4 and N2O, and these fluxes can significantly contribute to the net ecosystem exchange. Since roots usually have large intercellular spaces or aerenchyma they may represent preferential transport ways for soil gases, linking possibly elevated soil gas concentrations in the subsoil in a "shortcut" to the atmosphere. We tested the hypothesis that the spatial variability of the soil-atmosphere fluxes of CO2, CH4 and N2O is caused by the heterogeneity in soil properties. Therefore, we measured soil-atmosphere gas fluxes, soil gas concentrations and soil diffusivity profiles and did a small scale field assessment of soil profiles on the measurments plots. We further tried to link vertical profiles of soil gas concentrations and diffusivity to derive the production and consumption profiles, and to link these profiles to the stem-atmosphere flux rates of individual trees. Measurements were conducted in two mountain beech forests with different geographical and climatic conditions (White Carpathians, Czech Republic; Black Forest, Germany). Gas fluxes at stem and soil levels were measured simultaneously using static chamber systems and chromatographic and continuous laser analyses. Monitoring simultaneously vertical soil gas profiles allowed to assess the within-soil gas fluxes, and thus to localize the production and

  10. Spatial variability of greenhouse gases emissions (CO2, CH4, N2O) in a tropical hydroelectric reservoir flooding primary forest (Petit Saut Reservoir, French Guiana)

    Science.gov (United States)

    Cailleaud, Emilie; Guérin, Frédéric; Bouillon, Steven; Sarrazin, Max; Serça, Dominique

    2014-05-01

    At the Petit Saut Reservoir (PSR, French Guiana, South America), vertical profiles were performed at 5 stations in the open waters (OW) and 6 stations in two shallow flooded forest (FF) areas between April 2012 and September 2013. Measurements included physico-chemical parameters, ammonium, nitrate and dissolved greenhouse gas (CO2, CH4, N2O) concentrations, dissolved and particulate organic carbon (DOC, POC) and nitrogen (PN), δ13C-POC and δ15N-PN . The diffusive fluxes were calculated from surface concentrations. The aim of this study was to estimate the spatial variations of greenhouse gas emissions at a dentrical hydroelectric reservoir located in the tropics and flooding primary forest. Twenty years after impoundment, the water column of the PSR is permanently and tightly stratified thermally in the FF whereas in the OW, the thermal gradients are not as stable. The different hydrodynamical behaviours between the two different zones have significant consequences on the biogeochemistry: oxygen barely diffuses down to the hypolimnion in the FF whereas destratification occurs sporadically during the rainy season in the OW. Although we found the same range of POC in the FF and the OW (2.5-29 μmol L-1) and 20% more DOC at the bottom of OW than in the FF (229-878 μmol L-1), CO2 and CH4 concentrations were always significantly higher in the FF (CO2: 11-1412 μmol L-1, CH4: 0.001-1015 μmol L-1) than in the OW. On average, the CO2 concentrations were 30-40% higher in the FF than in the OW and the CH4 concentrations were three times higher in the FF than in the OW. The δ13C-POC and C:N values did not suggest substantial differences in the sources of OM between the FF and OW. At all stations, POC at the bottom has an isotopic signature slightly lighter than the terrestrial OM in the surrounding forest whereas the isotopic signature of surface POM would result from phytoplankton and methanotrophs. The vertical profiles of nitrogen compounds reveal that the main

  11. Fluxes of CO2, CH4 and N2O from alpine grassland in the Tibetan Plateau%青藏高原高寒草原生态系统CO2,CH4和N2O排放通量研究

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    Using static chamber technique, fluxes of CO2, CHh and N2O were measured in the alpinegrassland area from July 2000 to July 2001, determinations of mean fluxes showed that CO2 and N2Owere generally released from the soil, while the alpine grassland accounted for a weak CH4 sink.Fluxes of CO2, CH4 and N2O ranged widely. The highest CO2 emission occurred in August, whereasalmost 90% of the whole year emission occurred in the growing season. But the variations of CH4and N2O fluxes did not show any clear patterns over the one-year-experiment. During a dailyvariation, the maximum CO2 emission occurred at 16:00, and then decreased to the minimumemission in the early morning. Daily pattern analyses indicated that the variation in CO2 fluxes waspositively related to air temperatures (R2=0.73) and soil temperatures at a depth of 5 cm (R2=4).86),whereas daily variations in CH4 and N2O fluxes were poorly explained by soil temperatures andclimatic variables. CO2 emissions in this area were much lower than other grasslands in plain areas.

  12. 助剂对CO2/CH4重整Ni基催化剂性能的影响%Influence of promoters to the performances of Ni-based catalyst for CO2 reforming of methane

    Institute of Scientific and Technical Information of China (English)

    李基涛; 陈明旦; 严前古; 万惠霖; 区泽棠

    1999-01-01

    用程序升温(TPR、TPO)和活性评价等方法研究助剂(MgO,CaO,La2O3和Ce2O3)对CO2/CH4重整制合成气Ni基催化剂性能的影响.结果表明MgO和Ce2O3能较多地提高CH4和CO2的转化率,助剂Ce2O3能最有效地抑制催化剂的积炭.

  13. Continuous multi-plot measurements of CO2, CH4, N2O and H2O in a managed boreal forest - The importance of accounting for all greenhouse gases

    Science.gov (United States)

    Vestin, P.; Mölder, M.; Sundqvist, E.; Båth, A.; Lehner, I.; Weslien, P.; Klemedtsson, L.; Lindroth, A.

    2015-12-01

    In order to assess the effects of different management practices on the exchange of greenhouse gases (GHG), it is desirable to perform repeated and parallel measurements on both experimental and control plots. Here we demonstrate how a system system combining eddy covariance and gradient techniques can be used to perform this assessment in a managed forest ecosystem.The net effects of clear-cutting and stump harvesting on GHG fluxes were studied at the ICOS site Norunda, Sweden. Micrometeorological measurements (i.e., flux-gradient measurements in 3 m tall towers) allowed for quantification of CO2, CH4 and H2O fluxes (from May 2010) as well as N2O and H2O fluxes (from June 2011) at two stump harvested plots and two control plots. There was one wetter and one drier plot of each treatment. Air was continuously sampled at two heights in the towers and gas concentrations were analyzed for CH4, CO2, H2O (LGR DLT-100, Los Gatos Research) and N2O, H2O (QCL Mini Monitor, Aerodyne Research). Friction velocities and sensible heat fluxes were measured by sonic anemometers (Gill Windmaster, Gill Instruments Ltd). Automatic chamber measurements (CO2, CH4, H2O) were carried out in the adjacent forest stand and at the clear-cut during 2010.Average CO2 emissions for the first year ranged between 14.4-20.2 ton CO2 ha-1 yr-1. The clear-cut became waterlogged after harvest and a comparison of flux-gradient data and chamber data (from the adjacent forest stand) indicated a switch from a weak CH4 sink to a significant source at all plots. The CH4 emissions ranged between 0.8-4.5 ton CO2-eq. ha-1 yr-1. N2O emissions ranged between 0.4-2.6 ton CO2-eq. ha-1 yr-1. Enhanced N2O emission on the drier stump harvested plot was the only clear treatment effect on GHG fluxes that was observed. Mean CH4 and N2O emissions for the first year of measurements amounted up to 29% and 20% of the mean annual CO2 emissions, respectively. This highlights the importance of including all GHGs when assessing

  14. Evolution of CO$_2$, CH$_4$, and OCS abundances relative to H$_2$O in the coma of comet 67P around perihelion from Rosetta/VIRTIS-H observations

    CERN Document Server

    Bockelée-Morvan, D; Erard, S; Capaccioni, F; Leyrat, C; Filacchione, G; Drossart, P; Encrenaz, T; Biver, N; de Sanctis, M -C; Schmitt, B; Kührt, E; Capria, M -T; Combes, M; Combi, M; Fougere, N; Arnold, G; Fink, U; Ip, W; Migliorini, A; Piccioni, G; Tozzi, G

    2016-01-01

    Infrared observations of the coma of 67P/Churyumov-Gerasimenko were carried out from July to September 2015, i.e., around perihelion (13 August 2015), with the high-resolution channel of the VIRTIS instrument onboard Rosetta. We present the analysis of fluorescence emission lines of H$_2$O, CO$_2$, $^{13}$CO$_2$, OCS, and CH$_4$ detected in limb sounding with the field of view at 2.7-5 km from the comet centre. Measurements are sampling outgassing from the illuminated southern hemisphere, as revealed by H$_2$O and CO$_2$ raster maps, which show anisotropic distributions, aligned along the projected rotation axis. An abrupt increase of water production is observed six days after perihelion. In the mean time, CO$_2$, CH$_4$, and OCS abundances relative to water increased by a factor of 2 to reach mean values of 32%, 0.47%, and 0.18%, respectively, averaging post-perihelion data. We interpret these changes as resulting from the erosion of volatile-poor surface layers. Sustained dust ablation due to the sublimati...

  15. 大气CO2、CH4、CO高精度观测混合标气配制方法%Preparation of mixed standards for high accuracy CO2/CH4/CO measurements

    Institute of Scientific and Technical Information of China (English)

    姚波; 黄建青; 周凌晞; 方双喜; 刘立新; 夏玲君; 李培昌; 王红阳

    2013-01-01

    CO2/CH4/CO mixed standards in dry clean air are critical for high accuracy measurement. Water vapor concentration and 813 C in CO2 can significantly influence optical measurement methods. In this study, a custom-made preparation system was built to prepare the required mixed standards. Ambient air was pressurized into cylinders and target gases were adjusted by filling in high concentration gases or absorption. The absorption efficiencies of ASCARITE Ⅱ and Sofnocat423 were 99.7% and 99. 8% , respectively. Water vapor in the mixing standards was less than 3.7 × 10-6. Seven testing standards were made at Waliguan global background station in Qinghai Province. The deviations of the prepared concentrations from the target concentrations were less than 10 × 10-6, 30 × 10-9 and 30 × 10-9 for CO2, CH4 and CO, respectively. 813 in CO2 was within ambient range in these testing standards. The method has already been employed to produce qualified standards for high accuracy greenhouse gases measurements at Chinese background stations, and these standards met the requirement of World Meteorological Organization/Global Atmosphere Watch ( WMO/ GAW).%高精度、高准确度的大气CO2、CH4、CO浓度观测需使用以干洁大气为底气的标气.标气中水汽含量及CO2的δ13C对基于光学原理的观测系统有不可忽视的影响.本研究利用自组装的混合标气配制系统,以环境大气为底气,并通过添加高浓度气体或利用吸附剂吸附,调节目标物种浓度.CO2和CO吸附效率分别达99.7%和99.8%,标气水汽含量小于3.7×10-6(物质的量分数,下同),可配制不同浓度范围的CO2、CH4、CO混合标气.在青海瓦里关全球大气本底站配制环境大气浓度范围的标气,CO2、CH4、CO实际配制浓度同目标浓度的偏差小于10×10-6、30×10-9、30×10-9,CO2中δ13C同实际大气接近.本方法配制的标气已应用于我国本底站大气CO2、CH4、CO高精度观测,符合世界气象组织/

  16. Study on CO2, CH4 and N2 Adsorption and Desorption Law of Seam%煤层对CO2、CH4和N2吸附/解吸规律研究

    Institute of Scientific and Technical Information of China (English)

    涂乙; 谢传礼; 李武广; 赵兴华; 吴萌

    2012-01-01

    针对目前我国煤层气开发中存在的产气率低、煤层气开采理论规律研究欠缺等问题,根据试验对比分析了不同温度15、20、25、30℃时,CO2、CH4和N2在煤岩中的吸附/解吸规律。试验结果表明,当温度升高时,气体分子的平均自由程越大,气体吸附量变小;对同一种煤介,当压力相同时,临界温度高的气体,具有较强的吸附能力,煤层对CO2、CH4和N2吸附能力依次下降;压力升高时,煤层对气体的吸附量变大;降压解吸过程存在解吸滞后现象,温度降低显著,这与吸附、解吸表达式和吸热反应有关。%According to the low methane gas production rate, insufficient study on the coal bed methane mining theoretical law and other problems existed in China coal bed methane development, based on the test comparisons, the adsorption and desorption laws of CO2, CH4 and N2 in coal and rock were analyzed with different temperatures of 15, 20, 25 and 30 ℃. The test results showed that when the temperature raised, the higher the mean free path of the gas molecules, the smaller the gas adsorption value would be. As for the same medium, when the pressure was the same, the gas with a high critical temperature would have a high adsorption capacity and the C02, CH4 and N2 adsorption capacity of the seam would reduce in sequence. When the pressure increased, the gas adsorption value of the seam would be increased. There was an desorption hysteresis existed in the pressure releasing and desorption process. When the temperature decreased, the desorption hysteresis would be obvious which was related to the adsorption and desorption expression and the endothermic reaction.

  17. Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10 volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3 and SO2

    Science.gov (United States)

    Simpson, I. J.; Blake, N. J.; Barletta, B.; Diskin, G. S.; Fuelberg, H. E.; Gorham, K.; Huey, L. G.; Meinardi, S.; Rowland, F. S.; Vay, S. A.; Weinheimer, A. J.; Yang, M.; Blake, D. R.

    2010-12-01

    Oil sands comprise 30% of the world's oil reserves and the crude oil reserves in Canada's oil sands deposits are second only to Saudi Arabia. The extraction and processing of oil sands is much more challenging than for light sweet crude oils because of the high viscosity of the bitumen contained within the oil sands and because the bitumen is mixed with sand and contains chemical impurities such as sulphur. Despite these challenges, the importance of oil sands is increasing in the energy market. To our best knowledge this is the first peer-reviewed study to characterize volatile organic compounds (VOCs) emitted from Alberta's oil sands mining sites. We present high-precision gas chromatography measurements of 76 speciated C2-C10 VOCs (alkanes, alkenes, alkynes, cycloalkanes, aromatics, monoterpenes, oxygenated hydrocarbons, halocarbons and sulphur compounds) in 17 boundary layer air samples collected over surface mining operations in northeast Alberta on 10 July 2008, using the NASA DC-8 airborne laboratory as a research platform. In addition to the VOCs, we present simultaneous measurements of CO2, CH4, CO, NO, NO2, NOy, O3 and SO2, which were measured in situ aboard the DC-8. Carbon dioxide, CH4, CO, NO, NO2, NOy, SO2 and 53 VOCs (e.g., non-methane hydrocarbons, halocarbons, sulphur species) showed clear statistical enhancements (1.1-397×) over the oil sands compared to local background values and, with the exception of CO, were greater over the oil sands than at any other time during the flight. Twenty halocarbons (e.g., CFCs, HFCs, halons, brominated species) either were not enhanced or were minimally enhanced (local background, respectively. These SO2 levels are comparable to maximum values measured in heavily polluted megacities such as Mexico City and are attributed to coke combustion. By contrast, relatively poor correlations between CH4, ethane and propane suggest low levels of natural gas leakage despite its heavy use at the surface mining sites. Instead

  18. Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2–C10 volatile organic compounds (VOCs, CO2, CH4, CO, NO, NO2, NOy, O3 and SO2

    Directory of Open Access Journals (Sweden)

    A. J. Weinheimer

    2010-08-01

    Full Text Available Oil sands comprise 30% of the world's oil reserves and the crude oil reserves in Canada's oil sands deposits are second only to Saudi Arabia. The extraction and processing of oil sands is much more challenging than for light sweet crude oils because of the high viscosity of the bitumen contained within the oil sands and because the bitumen is mixed with sand and contains chemical impurities such as sulphur. Despite these challenges, the importance of oil sands is increasing in the energy market. To our best knowledge this is the first peer-reviewed study to characterize volatile organic compounds (VOCs emitted from Alberta's oil sands mining sites. We present high-precision gas chromatography measurements of 76 speciated C2–C10 VOCs (alkanes, alkenes, alkynes, cycloalkanes, aromatics, monoterpenes, oxygenates, halocarbons, and sulphur compounds in 17 boundary layer air samples collected over surface mining operations in northeast Alberta on 10 July 2008, using the NASA DC-8 airborne laboratory as a research platform. In addition to the VOCs, we present simultaneous measurements of CO2, CH4, CO, NO, NO2, NOy, O3 and SO2, which were measured in situ aboard the DC-8. Methane, CO, CO2, NO, NO2, NOy, SO2 and 53 VOCs (e.g., halocarbons, sulphur species, NMHCs showed clear statistical enhancements (up to 1.1–397× over the oil sands compared to local background values and, with the exception of CO, were higher over the oil sands than at any other time during the flight. Twenty halocarbons (e.g., CFCs, HFCs, halons, brominated species either were not enhanced or were minimally enhanced (4–C9 alkanes, C5–C6 cycloalkanes, C6–C8 aromatics, together with CO; and (2 emissions associated with the mining effort (i.e., CO2, CO, CH4, NO, NO2, NOy, SO2, C2–C4 alkanes, C2–C4 alkenes, C9 aromatics, short-lived solvents such as C2Cl4 and C2HCl3, and longer-lived species such as HCFC-22 and HCFC-142b. Prominent in the second group, SO2 and NO were

  19. CO_2、CH_4和N_2在不同硅铝比β沸石上的吸附分离性能%Adsorption separation of CO_2, CH_4 and N_2 on β-zeolite with different SiO_2/Al_2O_3 ratios

    Institute of Scientific and Technical Information of China (English)

    徐晓亮; 赵兴祥; 孙林兵; 刘晓勤

    2009-01-01

    The adsorption separation of CO_2, CH_4 and N_2 was studied via volumetric measurements of t3-zeolite samples with different SiO_2/Al_2O_3 ratios at 273 and 303 K. Results showed that all the obtained adsorption isotherms are well correlated with the Langmuir-Freundlich model. For a certain sample, the adsorption capacity for CO_2 is much higher than that for CH_4 and N_2. The adsorption capacity for CO_2 increases with the decrease in SiO_2/Al_2O_3 ratio under same temperature and pressure. The Henry law's constant and adsorption equilibrium selectivity of CO_2, CH_4, and N_2 on different β-zeolite samples were calculated via Virial equation, showing that the β-zeolite samples have higher equilibrium selectivity for CO_2 over N_2 and CH_4. The selectivity of CO_2 over N_2 and CH_4 increases with the decrease in SiO_2/Al_2O_3 ratio. Therefore, the β-zeolite sample with a low SiO_2/Al_2O_3 ratio is a good candidate for the separation of carbon dioxide from its mixture with methane and nitrogen. The isosteric adsorption heat for CO_2, CH_4 and N_2 calculated by Clausius-Clapeyron equation is independent with the increase of adsorption loading, which indicates that β-zeolite is an energetically homogenous adsorbent.%采用体积法在273 K和303 K温度下对CO_2,CH_4和N_2在不同硅/铝比的β沸石上的吸附分离性能进行了研究.实验结果表明,Langmuir-Freundlich模型能够较好地拟合吸附实验数据;同一样品上,CO_2的吸附量要大于CH_4和N_2的吸附量;随着硅铝比的减小CO_2的吸附量增加,而硅/铝比对CH_4和N_2的吸附量的影响较小.通过结合Virial方程计算CO_2、CH_4和N_2在不同硅/铝比β沸石上的亨利定律常数和吸附选择性,发现所研究样品对CO_2/CH_4和CO_2/N_2均具有很高的吸附选择性,随着样品硅/铝比的减小,CO_2/CH_4和CO_2/N_2的吸附选择性显著增加,说明较低硅/铝比β沸石有利于分离CO_2.用Clausius-Ciapeyron方程求得CO_2,CH_4和N_2在不

  20. The controlling factors and coupling of soil CO2, CH4 and N2O fluxes in a temperate needle-broadleaved mixed forest%温带针阔混交林土壤碳氮气体通量的主控因子与耦合关系

    Institute of Scientific and Technical Information of China (English)

    党旭升; 李林森; 王磊; 程淑兰; 方华军; 于贵瑞; 韩士杰; 张军辉; 王淼; 王永生; 徐敏杰

    2015-01-01

    Carbon dioxide ( CO2 ) , methane ( CH4 ) and nitrous oxide ( N2 O) are three major greenhouse gases, accounting for 80% of global warming. Forest ecosystems comprise the largest carbon stocks in terrestrial ecosystems, and function as important sinks and sources of atmospheric CO2 , CH4 and N2 O. Complicated interactions occur during the generation and absorption of soil CO2 , CH4 and N2 O, including synergies, tradeoffs, and randomness. High-latitude forests are experiencing the effects of significant global change ( e. g., warming, changed precipitation, and increased nitrogen deposition) , leading to great uncertainty in estimates of soil greenhouse gas fluxes. Furthermore, the factors controlling the coupling of soil CO2 , CH4 and N2 O fluxes remain unclear. This study was conducted in the temperate needle-broadleaved mixed forest of Changbai Mountain, Northeast China. The net exchange fluxes of soil CO2 , CH4 and N2 O, as well as soil temperature and soil moisture, were measured over four years (2005–2009) using static chamber and gas chromatograph techniques. The results showed that temperate needle-broadleaved mixed forest soils behaved as a source of atmospheric CO2 and N2 O but a sink of atmospheric CH4 over the course of the study. The average soil CH4 , CO2 and N2 O fluxes were estimated at -1.30 kg CH4 hm-2 a-1 , 15102.2 kg CO2 hm-2 a-1 , and 6.13 kg N2 O hm-2 a-1 , respectively. In addition, soil CO2 flux exhibited significant seasonality, and was mainly affected by soil temperature, followed by soil moisture. Seasonal variation in soil CH4 flux was less significant than that of soil CO2 and N2 O fluxes; moreover, it was positively correlated with soil moisture. When soil temperatures were within a threshold range, soil moisture determined CH4 production and oxidation in soil profiles by regulating CH4 and O2 diffusion as well as methanotrophic community activity. Similar to soil CO2 flux, soil N2 O flux was significantly correlated with soil

  1. Research on Relationship Among CO2, CH4 and N2O Emission Fluxes in Freshwater Marsh Ecosystem%沼泽湿地生态系统CO2、CH4和N2O排放通量的相互关系研究

    Institute of Scientific and Technical Information of China (English)

    卢妍; 徐洪文; 宋长春

    2011-01-01

    利用静态暗箱/气相色谱法连续两个生长季(2003 -2004年)对三江平原小叶章草甸和毛果苔草沼泽CO2、CH4和N2O的排放通量进行野外原位观测.结果表明:两种类型湿地的生长季均为温室气体的排放源,三种温室气体排放通量之间的关系是,CO2和CH4、CO2和N2O、CH4和N2O排放通量之间均为正相关,但显著性水平视不同湿地类型以及不同年份而异.表明它们之间的相互关系受湿地类型以及环境因素的影响,本研究结果迸一步证明了植物在沼泽湿地温室气体排放中的关键性作用.%CO2, CH4 and N2O fluxes were measured using the technique of closed opaque chamber and gas chromatography system. The experiment was carried out during 2003-2004 growing seasons in field of Calamagrostis angustifoli meadow and Carex lasiocarpa marsh in the Sanjiang Plain. The results showed that the two wetlands both were emission sources of greenhouse gases during growing seasons. There was a positively significant correlation between CO2 and CH4 emission fluxes, CO2 and N2O emission fluxes, and CH4 and N2O emission fluxes. But the level was different in various wetlands or years. It indicated that the relationship was influenced by wetland types and environmental factors. It was proved further that plants played a key role in greenhouse gases emission in freshwater marsh ecosystem.

  2. 北极新奥尔松地区夏季近地面CO2、CH4和N2O浓度的观测研究%SPATIAL AND TEMPORAL VARIATIONS IN CO2, CH4 AND N2O CONCENTRATION IN NY-(A)LESUND, SVALBARD

    Institute of Scientific and Technical Information of China (English)

    陈清清; 朱仁斌; 徐华

    2013-01-01

    not show evidently higher atmospheric concentrations of CO2,CH4 and N2O concentration.%2008和2009年夏在北极新奥尔松地区(Ny-(A)lesund)不同苔原区域(鸟类保护区、海滩苔原、矿区、人类活动区等)监测CO2、CH4和N2O近地面浓度的时空变化并分析其可能的影响因素.2008年7月25日-8月13日和2009年7月13-26日,在不同观测区域设置常规和非常规采样点采集气体样品共239瓶并妥善保存.实验室内使用气相色谱(GC)测定准确真空瓶中温室气体(CO2、CH4和N2O)的浓度.鸟类保护区的日变化中,2008年鸟类保护区CO2和N2O日变化浓度均大于2009年约30 ppm和25 ppb.2008年海滩苔原CO2浓度均高于2009年约30 ppm;N2O浓度低于2009年11 ppb;2008年鸟类保护区CH4浓度低于2009年,而海滩苔原2008年浓度高于2009年,差值均约为0.7 ppm.这些年际变化可能由环境条件(天气变化等)和地表覆盖情况的变化引起.高海鸟活动区(HB) CO2浓度低于海鸟活动较少的区域(MB和LB);鸟类保护区CO2浓度低于海滩苔原,N2O浓度高于海滩苔原,主要原因是海鸟活动和鸟粪增加了土壤营养元素,影响苔藓植被发育并改变苔原土壤上垫面的覆盖状况.综合不同苔原区域:新奥尔松地区CO2和CH4浓度高于ZEP (Zeppelin Station)监测平均浓度,地表向大气输送CO2和CH4;而N2O低于ZEP监测的平均浓度,地表从大气吸收N2O.不同区域影响因素不同:鸟类保护区、海滩苔原和鸟岛主要是受到海鸟活动影响;矿区主要是受水分和土壤基质影响;站区和机场受到人类活动影响但并不明显,总的来说直接原因是由于地表覆盖情况以及地形不同引起.

  3. Strain development in unconfined coals exposed to CO2, CH4 and Ar: Effect of moisture

    NARCIS (Netherlands)

    Bergen, F. van; Spiers, C.; Floor, G.; Bots, P.

    2009-01-01

    Field experiments and laboratory studies have shown that swelling of coal takes place upon contact with carbon dioxide at underground pressure and temperature conditions. Understanding this swelling behavior is crucial for predicting the performance of future carbon dioxide sequestration operations

  4. An improved gas chromatography for rapid measurement of CO2,CH4 and N2O

    Institute of Scientific and Technical Information of China (English)

    WANG Ying-hong; WANG Yue-si; SUN Yang; XU Zhong-jun; LIU Guang-ren

    2006-01-01

    Combining improved injector, gas line and valve-driving modules, a GC equipped with FID and ECD, could simultaneously measure CH4, CO2 and N2O in an air sample within 4 min. Test results showed that the system has high sensitivity, resolution and precision; the linear response range of the system meets the requirement of in situ flux measurements. Thus, the system is suitable for monitoring fluxes of main greenhouse gases in terrestrial ecosystem since it is easy to use, efficacious, stable and reliable to collect data.

  5. Adsorptive separation of CO2/CH4/CO gas mixtures at high pressures

    NARCIS (Netherlands)

    R. Krishna

    2012-01-01

    The major objective of this communication is to compare the performance of three metal-organic frameworks (MOFs): CuBTC, MIL-101, and Zn(bdc)dabco, with that of NaX zeolite for selective adsorption of CO2 from mixtures containing CH4 and CO in a pressure swing adsorption (PSA) unit operating at pres

  6. CO2, CH4 and particles flux measurements in Florence, Italy

    Science.gov (United States)

    Gioli, Beniamino; Toscano, Piero; Zaldei, Alessandro; Fratini, Gerardo; Miglietta, Franco

    2013-04-01

    We report a synthesis of seven years of eddy covariance (EC) flux measurements in the city of Florence, Italy. The measurement site is located in a densely urbanized area in the central city area, where fluxes are governed by anthropogenic emissions, considering the lack of green-space in the flux footprint. EC flux measurements of CO2 are made long-term since seven years, while short-term campaigns have been aimed at measuring CH4 and particles fluxes. CO2 and CH4 densities are measured with fast open-path sensors, while particles in the range 0.32 - 7.00 µm optical diameter are measured with a custom-built optical counter. CO2 long-term fluxes are always a net source, with a small inter-annual variability associated with a high seasonality, ranging from 39 to 172% of the mean annual value in summer and winter respectively. CH4 fluxes to the atmosphere are relevant, representing about 8% of CO2-equivalent emissions, and do not exhibit any significant seasonality. Relative contributions of road traffic and domestic heating to observed emissions has been estimated through multi-variate analysis combined with inventorial data and emission proxies such as traffic counters and gas network flow rates, revealing that domestic heating accounts for more than 80% of observed CO2 fluxes. Heating and road traffic are instead responsible for only 14% of observed CH4 fluxes, while the major residual part is likely dominated by gas network leakages. Particles flux data show a smaller seasonal trend and a pronounced weekend decrease, highlighting that the contribution of heating to particle emissions is relatively small compared to road traffic. Dynamics at hourly time scales during week and week-end days allows the analysis of the coupled role of emission strength and atmospheric processes such as advection and entrainment in regulating atmospheric concentrations. This set of observations highlights the potential of urban EC flux measurements as a validation tool for inventorial based estimates, and as a planning and verification tool for emission reduction policies that may be applied by city administrators. Challenges and limitations of EC in urban environments are finally highlighted.

  7. Experiments on neutron-attenuation by water-lead mixtures; Etude experimentale de l'attenuation des neutrons dans les melanges plomb-eau

    Energy Technology Data Exchange (ETDEWEB)

    Beauge, R.; Millot, J.P.; Rastoin, J. [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    The penetration of fission neutrons in water-lead mixtures has been investigated in the NAIADE facility. The slopes of the thermal and fast fluxes (the latter measured with a dosimeter) remain similar when the volume proportion of water is greater than 65 per cent. For smaller water contents, the measurements show the evidence of streaming presumably due to slowing-down neutrons of energy smaller than 300 keV. (author) [French] La propagation des neutrons de fission a ete etudiee dans les melanges plomb-eau au moyen du dispositif NAIADE. La pente du flux thermique et la pente du flux rapide (obtenue au moyen d'un dosimetre) restent voisines lorsque la proportion d'eau dans le melange depasse 65 pour cent en volume. Pour des proportions inferieures les mesures mettent en evidence un 'streaming' de neutrons en ralentissement d'energie probablement inferieure a 300 keV. (auteur)

  8. Temporal and spatial variations of soil CO2, CH4 and N2O fluxes at three differently managed grasslands

    Directory of Open Access Journals (Sweden)

    D. Imer

    2013-09-01

    Full Text Available A profound understanding of temporal and spatial variabilities of soil carbon dioxide (CO2, methane (CH4 and nitrous oxide (N2O fluxes between terrestrial ecosystems and the atmosphere is needed to reliably quantify these fluxes and to develop future mitigation strategies. For managed grassland ecosystems, temporal and spatial variabilities of these three soil greenhouse gas (GHG fluxes occur due to changes in environmental drivers as well as fertilizer applications, harvests and grazing. To assess how such changes affect soil GHG fluxes at Swiss grassland sites, we studied three sites along an altitudinal gradient that corresponds to a management gradient: from 400 m a.s.l. (intensively managed to 1000 m a.s.l. (moderately intensive managed to 2000 m a.s.l. (extensively managed. The alpine grassland was included to study both effects of extensive management on CH4 and N2O fluxes and the different climate regime occurring at this altitude. Temporal and spatial variabilities of soil GHG fluxes and environmental drivers on various timescales were determined along transects of 16 static soil chambers at each site. All three grasslands were N2O sources, with mean annual soil fluxes ranging from 0.15 to 1.28 nmol m−2 s−1. Contrastingly, all sites were weak CH4 sinks, with soil uptake rates ranging from −0.56 to −0.15 nmol m−2 s−1. Mean annual soil and plant respiration losses of CO2, measured with opaque chambers, ranged from 5.2 to 6.5 μmol m−2 s−1. While the environmental drivers and their respective explanatory power for soil N2O emissions differed considerably among the three grasslands (adjusted r2 ranging from 0.19 to 0.42, CH4 and CO2 soil fluxes were much better constrained (adjusted r2 ranging from 0.46 to 0.80 by soil water content and air temperature, respectively. Throughout the year, spatial heterogeneity was particularly high for soil N2O and CH4 fluxes. We found permanent hot spots for soil N2O emissions as well as locations of permanently lower soil CH4 uptake rates at the extensively managed alpine site. Including hot spots was essential to obtain a representative mean soil flux for the respective ecosystem. At the intensively managed grassland, management effects clearly dominated over effects of environmental drivers on soil N2O fluxes. For CO2 and CH4, the importance of management effects did depend on the status of the vegetation (LAI.

  9. A measurement system for continuous observations of CO2, CH4, H2O and CO onboard passenger aircraft

    Science.gov (United States)

    Gerbig, Christoph; Filges, Annette; Franke, Harald; Klaus, Christoph; Chen, Huilin

    2013-04-01

    Improved quantification and understanding of surface-atmosphere exchange fluxes of greenhouse gases (GHGs) caused by natural as well as anthropogenic processes is of paramount importance in a world of a changing climate and ever increasing emissions. Top-down estimation of GHG fluxes is traditionally done by inverse transport modeling, using GHG observations from a global network of stations. Uncertainties in modeled vertical transport rates (moist convection, turbulent mixing, stratosphere-troposphere exchange) however greatly affect the quality of flux estimates. More recently, remote sensing of vertical column mole fractions of GHGs have become available for inverse modeling, reducing the impact of vertical transport uncertainties to first order. However, those need validation against in-situ observations. A strategy for regular, global in-situ atmospheric profiling of GHGs, covering at least the troposphere, is thus needed to provide validation of remote sensing and of forward transport modeling of GHGs, to serve as input for inverse modeling, and to reduce the impact of transport uncertainties. IAGOS-ERI (In-service Aircraft for a Global Observing System - European Research Infrastructure) exploits the synergy between globally operating civil aviation and the need for long-term monitoring of atmospheric composition. Within the framework of IAGOS-ERI a cavity ring-down spectroscopy (CRDS) based measurement system for greenhouse gases was designed, tested, and qualified for deployment on commercial airliners. The design meets requirements regarding physical dimensions (size, weight), performance (long-term stability, low maintenance, robustness, full automation) and safety issues (fire prevention regulations, airworthiness). The system uses components of a commercially available CRDS instrument (G2401-m, Picarro Inc.) mounted into a frame suitable for integration in the avionics bay of the Airbus A-340. The first of the IAGOS GHG packages is scheduled for integration in mid 2013. The aim is to have seven systems operational within four years, providing for long-term GHG observations with near-global coverage. To enable robust and automated operation of the IAGOS GHG package over six-month deployment periods, numerous technical issues had to be addressed. An inlet system, designed as virtual impactor to eliminate sampling of larger aerosols, ice particles, and water droplets, provides additional positive ram-pressure to ensure operation without an upstream sampling pump. Furthermore, no sample drying is required, as the simultaneously measured water vapor mole fraction is used to correct for dilution and spectroscopic effects. This also enables the collection of science-quality water vapor measurements throughout the atmosphere. To allow for trace gas measurements to be fully traceable to WMO scales, a two-standard calibration system has been designed and tested that periodically provides calibration gas to the instrument during flight and on ground for each six-month deployment period. We present results from recent test flights and laboratory tests that document the performance for GHG and water vapor measurements. Furthermore, future applications of the IAGOS-GHG data stream, provided in near-real-time via SatCom to the weather prediction centres, will be discussed.

  10. Development and performance evaluation of Polydimethyl siloxane/Polysulfone (PDMS/PSF) composite membrane for CO2/CH4 separation

    Science.gov (United States)

    Suleman, M. S.; Lau, K. K.; Yeong, Y. F.

    2016-06-01

    Asymmetric polysulfone (PSF) membrane was developed by phase inversion in this study. Polysulfone (PSF) membrane was modified to develop a composite polymeric membrane. Polydimethyl siloxane (PDMS) was used to modify the PSF membrane. PDMS/PSF composite membrane was developed by dip coating of PDMS over PSF. Developed membranes were characterized in terms of membrane morphology by scanning electron microscope (SEM). Micro structure of polysulfone (PSF) membrane confirmed that developed membrane was asymmetric. Dense PDMS coating in microstructure of composite membrane was observed. Membrane swelling experiments were performed by immersing developed membranes in water for specific time period. PDMS/PSF composite membrane resisted water swelling as compared to PSF membrane. Performance of the membrane was evaluated before and after swelling within the pressure range of 2-10 bar. Reasonable decrement in permeance and selectivity was observed after membrane swelling. Thus, membrane swelling affected the separation performance of both PSF and PDMS/PSF composite membrane by decreasing the permeance and selectivity values.

  11. Adsorption-induced deformation of microporous materials: coal swelling induced by CO2-CH4 competitive adsorption.

    Science.gov (United States)

    Brochard, Laurent; Vandamme, Matthieu; Pellenq, Roland J-M; Fen-Chong, Teddy

    2012-02-01

    Carbon dioxide injection in coal seams is known to improve the methane production of the coal seam, while ensuring a safe and long-term carbon sequestration. This improvement is due to the preferential adsorption of CO(2) in coal with respect to CH(4): an injection of CO(2) thus results in a desorption of CH(4). However, this preferential adsorption is also known to cause a differential swelling of coal, which results in a significant decrease in the reservoir permeability during the injection process. Recent studies have shown that adsorption in coal micropores (few angströms in size) is the main cause of the swelling. In this work, we focus on the competitive adsorption behavior of CO(2) and CH(4) in micropores. We perform molecular simulations of adsorption with a realistic atomistic model for coal. The competitive adsorption is studied at various temperatures and pressures representative of those in geological reservoirs. With the help of a poromechanical model, we then quantify the subsequent differential swelling induced by the computed adsorption behaviors. The differential swelling is almost insensitive to the geological temperatures and pressures considered here and is proportional to the CO(2) mole fraction in the coal. PMID:22185459

  12. Global greenhouse gas (CO2, CH4) and carbon monoxide column data products retrieved from SCIAMACHY/ENVISAT

    International Nuclear Information System (INIS)

    Full text: Carbon dioxide (CO2) and methane (CH4) are the two most important anthropogenic greenhouse gases and carbon monoxide (CO) is an important air pollutant. SCIAMACHY on ENVISAT is the first satellite instrument whose measurements are sensitive to concentration changes of these 'carbon gases' at all atmospheric altitude levels down to the Earth's surface where their source/sink signals are largest. Data products for all three gases covering the first three years of ENVISAT (2003-2005) have been generated using the WFM-DOAS scientific retrieval algorithm developed at the University of Bremen. These data products form part of the ESA PROMOTE and EU GEMS climate change and air quality related services. The data sets will be presented and discussed focusing on a comparison with global model simulations. (author)

  13. Stress-strain response of pre-compacted granular coal samples exposed to CO2, CH4, He and Ar

    NARCIS (Netherlands)

    Bergen, F. van; Hol, S.; Spiers, C.J.

    2011-01-01

    The interaction between supercritical carbon dioxide and coal has been the subject of many studies in recent years. This paper reports two different types of swelling experiments, one on confined and one on unconfined samples of pre-pressed, crushed bituminous coal, performed at gas or fluid pressur

  14. Thermodynamic and kinetic aspects of CO2 capture by hydrate crystallization: application on a CO2-CH4 mixture

    International Nuclear Information System (INIS)

    The CO2 capture using gas hydrate crystallisation is a rupture technology to recover CO2 from gas emitted by industry. The goal is to find cheaper energy solutions to sequester CO2 than conventional processes (amine absorption and TSA / PSA processes). The objective is to study the thermodynamic and kinetic conditions of a process to capture CO2 by the formation of gas hydrates. Gas hydrates have properties of selectivity and a large storage capacity for a separation of gas. The thermodynamic aspects were to determine the phase diagrams to see the feasibility of this technique. We showed that the operating pressures may be important in cases where the liquid phase is only made up of water. To reduce compression costs, we used the TBAB (Tetra-Butyl-Ammonium-Bromide) as an additive. The use of this additive can reduce considerably the operating pressures by 16. However, this pressure gain is accompanied by a loss of storage capacity. We also showed that the model of Van der Waals and Platteeuw is able to describe the phase diagrams obtained. The effect of TBAB on the gas solubility is also determined with different behaviours depending of the gas. For the kinetic part, we showed experimentally a preferential consumption of CO2 in the first moments of the crystallization. A kinetic model based on material and population balances adapted for gas mixtures is proposed. The model describes well the evolution of total gas consumption and the phenomenon of preferential consumption of CO2 at the beginning of the crystallization. This model with good kinetic parameters is able to monitor the size of crystals which is an important feature for transportation aspects of gas hydrates. (author)

  15. Estimating ice-melange properties with repeat UAV surveys over Store Glacier, West Greenland

    Science.gov (United States)

    Toberg, Nick; Ryan, Johnny; Christoffersen, Poul; Snooke, Neal; Todd, Joe; Hubbard, Alun

    2016-04-01

    In the past decade, tidewater outlet glaciers of the Greenland ice sheet (GrIS) have thinned and retreated when compared to the 1980s when the ice sheet was in a state of dynamic balance. With a growing amount of ice discharged into the sea by tidewater glaciers as well as more ice melting on the surface, the Greenland Ice Sheet has become the single largest cryospheric source of global sea level rise. Today, the ice sheet causes sea level rise of 1 mm per year, highlighting the need to understand the ice sheet's response to climate change. Atmospheric warming will inevitably continue to increase surface meltwater production, but the dynamic response, which includes hundreds of fast-flowing tidewater glaciers, is largely unknown. To develop new understanding of ice sheet dynamics, we investigated the mechanism whereby icebergs break off tidewater glaciers and form a proglacial ice melange. This melange is rigid in winter when sea ice and friction along the sidewalls of the fjord, or even at the sea floor, hold it together. The result is a resistive force, which reduces the rate of iceberg calving when the ice melange is rigid and is lost when the melange disappears in the summer. From early May to late July 2014, we launched unmanned aerial vehicles (UAVs) from a basecamp on a bluff overlooking the calving front of Store Glacier, a 5 km wide tidewater glacier flowing into Uummannaq Fjord in West Greenland. The Skywalker X8 UAVs had a wing-span of 2.1m and a payload containing a high resolution camera, an autopilot system and a GPS data logger. We generated almost 70,000 georeferenced images during 63 sorties over the glacier during a 10 week field season starting 13 May 2014. The images were used to construct orhorectified mosaics and digital elevation models of the proglacial melange with Photoscan structure-from-motion software. The imagery and the DEMs were analysed statistically to understand the spatial characteristics of the ice melange. By combining the

  16. elaboration de polymere a empreinte moleculaire destine au developpement d'un capteur des pesticides.

    OpenAIRE

    belladgham, wahiba

    2016-01-01

    Dans le present travail , notre interet s'est porté sur l'elaboration des materiaux a empreinte moleculaire MIP destines au developpement dun capteur des pesticides danc notre cas , la synthese du MIP s'est faite en polymerisant sous irradiation UV , LE MELANGE CONSTITUE .

  17. Supported Pd-Au Membrane Reactor for Hydrogen Production: Membrane Preparation, Characterization and Testing

    Directory of Open Access Journals (Sweden)

    Adolfo Iulianelli

    2016-05-01

    Full Text Available A supported Pd-Au (Au 7wt% membrane was produced by electroless plating deposition. Permeation tests were performed with pure gas (H2, H2, N2, CO2, CH4 for long time operation. After around 400 h under testing, the composite Pd-Au membrane achieved steady state condition, with an H2/N2 ideal selectivity of around 500 at 420 °C and 50 kPa as transmembrane pressure, remaining stable up to 1100 h under operation. Afterwards, the membrane was allocated in a membrane reactor module for methane steam reforming reaction tests. As a preliminary application, at 420 °C, 300 kPa of reaction pressure, space velocity of 4100 h−1, 40% methane conversion and 35% hydrogen recovery were reached using a commercial Ni/Al2O3 catalyst. Unfortunately, a severe coke deposition affected irreversibly the composite membrane, determining the loss of the hydrogen permeation characteristics of the supported Pd-Au membrane.

  18. Characterization of freeze-dried egg melange long stored after irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Bakalivanov, Stefan; Tsvetkova, Eli; Bakalivanova, Todorka; Tsvetkov, Tsvetan [Institute of Cryobiology and Food Technologies, 53 bd. Cherni vrah, 1407 Sofia (Bulgaria); Kaloyanov, Nikolay [University of Chemical Technology and Metallurgy, 8, bd. Kliment Ohridski, 1756 Sofia (Bulgaria)], E-mail: nikolaykaloyanov@yahoo.com; Grigorova, Stoyanka; Alexieva, Vanja [Institute of Cryobiology and Food Technologies, 53 bd. Cherni vrah, 1407 Sofia (Bulgaria)

    2008-01-15

    During the 4-year period of storage at room temperature of the freeze-dried (control group) and the freeze-dried and gamma-irradiated (2.0 and 3.5 kGy) whole hen's egg melange, no significant changes were found into the sensory and functional characteristics till the 28th month. The change in the number of SH groups was not unidirectional up to the 28th month and then it started to decrease in all investigated samples. During the entire period of investigation the amount of malondialdehyde in all three groups of egg melange was considerably below the allowed limit for foodstuffs. The most significant fractions of the protein spectra showed a general tendency of decrease during the storage.

  19. Geochemical Monitoring Of The Gas Hydrate Production By CO2/CH4 Exchange In The Ignik Sikumi Gas Hydrate Production Test Well, Alaska North Slope

    Science.gov (United States)

    Lorenson, T. D.; Collett, T. S.; Ignik Sikumi, S.

    2012-12-01

    Hydrocarbon gases, nitrogen, carbon dioxide and water were collected from production streams at the Ignik Sikumi gas hydrate production test well (TD, 791.6 m), drilled on the Alaska North Slope. The well was drilled to test the feasibility of producing methane by carbon dioxide injection that replaces methane in the solid gas hydrate. The Ignik Sikumi well penetrated a stratigraphically-bounded prospect within the Eileen gas hydrate accumulation. Regionally, the Eileen gas hydrate accumulation overlies the more deeply buried Prudhoe Bay, Milne Point, and Kuparuk River oil fields and is restricted to the up-dip portion of a series of nearshore deltaic sandstone reservoirs in the Sagavanirktok Formation. Hydrate-bearing sandstones penetrated by Ignik Sikumi well occur in three primary horizons; an upper zone, ("E" sand, 579.7 - 597.4 m) containing 17.7 meters of gas hydrate-bearing sands, a middle zone ("D" sand, 628.2 - 648.6 m) with 20.4 m of gas hydrate-bearing sands and a lower zone ("C" sand, 678.8 - 710.8 m), containing 32 m of gas hydrate-bearing sands with neutron porosity log-interpreted average gas hydrate saturations of 58, 76 and 81% respectively. A known volume mixture of 77% nitrogen and 23% carbon dioxide was injected into an isolated section of the upper part of the "C" sand to start the test. Production flow-back part of the test occurred in three stages each followed by a period of shut-in: (1) unassisted flowback; (2) pumping above native methane gas hydrate stability conditions; and (3) pumping below the native methane gas hydrate stability conditions. Methane production occurred immediately after commencing unassisted flowback. Methane concentration increased from 0 to 40% while nitrogen and carbon dioxide concentrations decreased to 48 and 12% respectively. Pumping above the hydrate stability phase boundary produced gas with a methane concentration climbing above 80% while the carbon dioxide and nitrogen concentrations fell to 2 and 18% respectively. Pumping below the gas hydrate stability phase boundary occurred in two periods with the composition of the produced gases continually increasing in methane reaching an excess of 96%, along with carbon dioxide decreasing to <1% and nitrogen to ~3%. The isotopic composition of all the gases was monitored. Methane carbon and hydrogen isotopic compositions remained stable throughout the test, while the carbon dioxide carbon became isotopically heavier. Nitrogen isotopic composition remained stable or became slightly isotopically depleted at the later phase of the test. These results imply that the produced methane was not isotopically fractionated, whereas carbon dioxide was fractionated becoming isotopically heavier at the end of each production phase. In addition, water samples were analyzed during the production phase documenting an increase in salinity.

  20. The IAGOS GHG package: a measurement system for continuous airborne observations of CO2, CH4, H2O and CO

    Science.gov (United States)

    Gerbig, C.; Filges, A.; Franke, H.; Klaus, C.; Chen, H.

    2012-12-01

    A cavity ring-down spectroscopy (CRDS) based measurement system for greenhouse gases was designed, tested, and qualified for deployment on commercial airliners within the IAGOS-ERI (In-service Aircraft for a Global Observing System - European Research Infrastructure) project. The design meets requirements regarding physical dimensions (size, weight), performance (long term stability, low maintenance, robustness, full automation) and safety issues (fire prevention regulations). The system uses components of a commercially available CRDS instrument (G2401-m, Picarro Inc.) integrated in a frame suitable for integration in the avionics bay of the Airbus A-340. The first of the IAGOS GHG packages is scheduled for integration in early 2013. The aim is to have seven systems operational within four years, providing for long-term GHG observations with near-global coverage. To enable robust and automated operation of the IAGOS GHG package over six-month deployment periods, numerous technical issues had to be addressed. An inlet system, designed as virtual impactor to eliminate sampling of larger aerosols, ice particles, and water droplets, and provides additional positive ram-pressure. In combination with a lowered sample flow of 0.1 slpm, this ensures a fully controlled sample pressure in the cavity of 140 torr throughout the aircraft altitude operating range up to 12.5 km without the need of an upstream sampling pump. Furthermore, no sample drying is required, as the simultaneously measured water vapor mole fraction is used to correct for dilution and spectroscopic effects. This also enables the collection of science-quality water vapor measurements throughout the atmosphere. To allow for trace gas measurements to be fully traceable to WMO scales, a two-standard calibration system has been designed and tested that periodically provides calibration gas to the instrument during flight and on ground. A targeted six-month deployment cycle followed by maintenance of the package ensures a safe operation. During maintenance, calibration gases are analysed and replenished, and a functional inspection, followed by replacement of depleted or damaged parts, will be undertaken. Spare instrumentation will be used to provide for year-round GHG measurements on board each aircraft. We present results from recent test flights and laboratory tests that document the performance for GHG and water vapor measurements. Furthermore, future applications of the IAGOS-GHG data stream, provided in near-real-time via SatCom to the weather prediction centres, will be discussed, including the improved estimation of GHG budgets at regional to continental scales, the assessment of vertical transport in atmospheric models through comparison with observed vertical tracer distributions, and the validation of remote sensing measurements of GHGs.

  1. Spatial variability and temporal dynamics of greenhouse gas (CO2, CH4, N2O concentrations and fluxes along the Zambezi River mainstem and major tributaries

    Directory of Open Access Journals (Sweden)

    C. R. Teodoru

    2014-11-01

    Full Text Available Spanning over 3000 km in length and with a catchment of approximately 1.4 million km2, the Zambezi River is the fourth largest river in Africa and the largest flowing into the Indian Ocean from the African continent. As part of a~broader study on the riverine biogeochemistry in the Zambezi River basin, we present data on greenhouse gas (GHG, carbon dioxide (CO2, methane (CH4, and nitrous oxide (N2O concentrations and fluxes collected along the Zambezi River, reservoirs and several of its tributaries during 2012 and 2013 and over two climatic seasons (dry and wet to constrain the interannual variability, seasonality and spatial heterogeneity along the aquatic continuum. All GHGs concentrations showed high spatial variability (coefficient of variation: 1.01 for CO2, 2.65 for CH4 and 0.21 for N2O. Overall, there was no unidirectional pattern along the river stretch (i.e. decrease or increase towards the ocean, as the spatial heterogeneity of GHGs appeared to be determined mainly by the connectivity with floodplains and wetlands, and the presence of man-made structures (reservoirs and natural barriers (waterfalls, rapids. Highest CO2 and CH4 concentrations in the mainstream river were found downstream of extensive floodplains/wetlands. Undersaturated CO2 conditions, in contrast, were characteristic for the surface waters of the two large reservoirs along the Zambezi mainstem. N2O concentrations showed the opposite pattern, being lowest downstream of floodplains and highest in reservoirs. Among tributaries, highest concentrations of both CO2 and CH4 were measured in the Shire River whereas low values were characteristic for more turbid systems such as the Luangwa and Mazoe rivers. The interannual variability in the Zambezi River was relatively large for both CO2 and CH4, and significantly higher concentrations (up to two fold were measured during wet seasons compared to the dry season. Interannual variability of N2O was less pronounced but generally higher values were found during the dry season. Overall, both concentrations and fluxes of CO2 and CH4 were well below the median/average values reported for tropical rivers, streams and reservoirs. A first-order mass balance suggests that carbon (C transport to the ocean represents the major component (59% of the budget (largely in the form of DIC, while only 38% of total C yield is annually emitted into the atmosphere, mostly as CO2 (98%, and 3% is removed by sedimentation in reservoirs.

  2. Greenhouse Gas Emissions (CO2-CH4) From Municipal Solid Waste Management Using Life Cycle Assessment (LCA) in Mahdsht City (IRAN)

    OpenAIRE

    Naderi M; Salari Baghon Abad M; Amiri M; Rezazadeh M

    2014-01-01

    Waste production is inevitable in any society and consequently waste management is one of the main roles of any municipality. Therefore, it is necessary to evaluate different waste management scenarios. According to the amount and composition of the generated waste, considering environmental, economic and technical issues, several options are existed. Life Cycle Assessment (LCA) as a decision support tool has been used in several cases to select the most appropriate option. In this paper, pro...

  3. The net GHG (CO2, CH4 and N2O) footprint of a newly impounded subtropical hydroelectric reservoir: Nam Theun 2

    Science.gov (United States)

    Deshmukh, Chandrashekhar; Guérin, Frédéric; Delon, Claire; Pighini, Sylvie; Vongkhamsao, Axay; Descloux, Stéphane; Chanudet, Vincent; Tardif, Raphael; Godon, Arnaud; Guédant, Pierre; Galy-Lacaux, Corinne; Zouiten, Cyril; Oliva, Priscia; Audry, Stéphane; Serça, Dominique

    2013-04-01

    There is a rising concern over the contribution of hydroelectric reservoirs to global anthropogenic greenhouse gases (GHGs) emissions. We present here the first comprehensive assessment of GHGs footprint associated with the creation of the Nam Theun 2 (NT2) hydroelectric reservoir in subtropical region of the Lao People's Democratic Republic. This assessment is the results of a monthly monitoring that have been conducted over 4 year (2008-to date). The carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) sources and sinks were quantified before and after impoundment, which began in May 2008. Before impoundment, the landscape to be flooded was a sink of carbon dioxide (-73 ± 225 Gg CO2eq yr-1),roughly neutral in terms of methane (7 ± 11 Gg CO2eq yr-1), and a source of nitrous oxide (345 ± 158 Gg CO2eq yr-1). After impoundment, total CO2 and CH4 emissions increased and N2O emissions decreased. For the year 2010, CO2 (791 ± 54 Gg CO2eq yr-1) and CH4 (644 ± 124 Gg CO2eq yr-1) contributed equally to the total gross GHG emissions from NT2 (54 and 43% for CO2 and CH4, respectively) whereas N2O contributed only 3% (47 ± 29 Gg CO2eq yr-1). The GHG emissions remained constant in 2011. Our results indicate that most of the GHG (around 90%) were emitted from reservoir water surface and the drawdown area, and only 10% were emitted by degassing at the turbines and from diffusive emissions downstream of the turbines and the dam, a percentage lower than reported for other hydroelectric reservoirs. With a total emissions of 1482 ± 207 and 1298 ± 200 Gg CO2eq yr-1 for year 2010 and 2011, gross NT2 emissions are about an order of magnitude higher than pre-impoundment emissions (276 ± 393 Gg CO2eq yr-1). With a net GHG emissions of 1203 ± 601 (2010) and 1022 ± 594 (2011) Gg CO2eq yr-1, and an annual power generation of about 6 TWh, GHG emission factor equal to 0.20 (2010) and 0.17 (2011) Mg CO2eq MWh-1 for NT2 which is up to five times lower than the emission factor of a thermal power plant (ranging from 0.44 to 1.05 Mg CO2eq MWh-1). Since emissions are supposed to decrease with the age of the reservoir, 2010 emission factor probably corresponds to the maximum value that would be reached for this reservoir. Work is in progress to predict the trends of GHG emissions over the projected life span (e.g. 100 years) of the reservoir. Integration of net GHG emissions at this time scale will allow a better comparison of emission factor of hydropower generation with other alternate energy sources. Keywords: Net GHG emissions, subtropical hydroelectric reservoir, Nam Theun 2

  4. The IAGOS-core greenhouse gas package : a measurement system for continuous airborne observations of CO2, CH4, H2O and CO

    NARCIS (Netherlands)

    Filges, Annette; Gerbig, Christoph; Chen, Huilin; Franke, Harald; Klaus, Christoph; Jordan, Armin

    2015-01-01

    Within the framework of IAGOS-ERI (In-service Aircraft for a Global Observing System - European Research Infrastructure), a cavity ring-down spectroscopy (CRDS)-based measurement system for the autonomous measurement of the greenhouse gases (GHGs) CO2 and CH4, as well as CO and water vapour was desi

  5. Differences in the Spatial Variability Among CO2, CH 4, and N 2O Gas Fluxes from an Urban Forest Soil in Japan.

    Science.gov (United States)

    Bellingrath-Kimura, Sonoko Dorothea; Kishimoto-Mo, Ayaka Wenhong; Oura, Noriko; Sekikawa, Seiko; Yonemura, Seichiro; Sudo, Shigeto; Hayakawa, Atsushi; Minamikawa, Kazunori; Takata, Yusuke; Hara, Hiroshi

    2015-02-01

    The spatial variability of carbon dioxide (CO(2)), methane (CH(4)), and nitrous oxide (N(2)O) fluxes from forest soil with high nitrogen (N) deposition was investigated at a rolling hill region in Japan. Gas fluxes were measured on July 25th and December 5th, 2008 at 100 points within a 100 × 100 m grid. Slope direction and position influenced soil characteristics and site-specific emissions were found. The CO(2) flux showed no topological difference in July, but was significantly lower in December for north-slope with coniferous trees. Spatial dependency of CH(4) fluxes was stronger than that of CO(2) or N(2)O and showed a significantly higher uptake in hill top, and emissions in the valley indicating strong influence of water status. N(2)O fluxes showed no spatial dependency and exhibited high hot spots at different topology in July and December. The high N deposition led to high N(2)O fluxes and emphasized the spatial variability. PMID:24736940

  6. Validation of the Greenhouse Gas Balance of The Netherlands. Observational constraints on CO2, CH4 and N2O from atmospheric monitoring station Lutjewad

    Energy Technology Data Exchange (ETDEWEB)

    Van der Laan, S.

    2010-10-22

    A method is described to determine the atmospheric greenhouse gas emissions for a large area using in-situ measurements. The method was applied to determine the Dutch emissions for fossil fuel-based carbon dioxide (FFCO{sub 2}), methane (CH{sub 4}) and nitrous oxide (N{sub 2}O). These are the three main anthropogenic greenhouse gases which are held mainly responsible for the current climate changes. It is for the first time that the national emissions are determined using atmospheric measurements. Until now, countries report their emissions (e.g. because of the Kyoto protocol) based on an estimation about the amount of sources (e.g. factories, traffic etc.) and a set of pre-defined conversion factors to calculate the amount of greenhouse gases depending on the usage. It is however well-known that this method is very susceptible to errors and depends strongly on how accurate the polluters submit their data. Needless to say, the necessity for an independent method was high. For the Netherlands, the results are very encouraging. The emissions which were submitted by the Netherlands are: (4.5 {+-} 0.2) kt km{sup -2} a{sup -1} for FFCO2, (18.3{+-}3.3) t km{sup -2} a{sup -1} for CH4 and (1.3{+-}0.6) t km{sup -2} a{sup -1} for N2O. The results based on the observational-based approach were comparable (resp.): (4.7 {+-} 1.6) kt km{sup -2} a{sup -1}, (22.3 {+-} 5.6) t km{sup -2} a{sup -1}, and (1.5 {+-} 0.4) t km{sup -2} a{sup -1}. The Netherlands is one of the highest emitters of greenhouse gases per capita, and is apparently honest about it.

  7. Differences in the Spatial Variability Among CO2, CH 4, and N 2O Gas Fluxes from an Urban Forest Soil in Japan.

    Science.gov (United States)

    Bellingrath-Kimura, Sonoko Dorothea; Kishimoto-Mo, Ayaka Wenhong; Oura, Noriko; Sekikawa, Seiko; Yonemura, Seichiro; Sudo, Shigeto; Hayakawa, Atsushi; Minamikawa, Kazunori; Takata, Yusuke; Hara, Hiroshi

    2015-02-01

    The spatial variability of carbon dioxide (CO(2)), methane (CH(4)), and nitrous oxide (N(2)O) fluxes from forest soil with high nitrogen (N) deposition was investigated at a rolling hill region in Japan. Gas fluxes were measured on July 25th and December 5th, 2008 at 100 points within a 100 × 100 m grid. Slope direction and position influenced soil characteristics and site-specific emissions were found. The CO(2) flux showed no topological difference in July, but was significantly lower in December for north-slope with coniferous trees. Spatial dependency of CH(4) fluxes was stronger than that of CO(2) or N(2)O and showed a significantly higher uptake in hill top, and emissions in the valley indicating strong influence of water status. N(2)O fluxes showed no spatial dependency and exhibited high hot spots at different topology in July and December. The high N deposition led to high N(2)O fluxes and emphasized the spatial variability.

  8. Fighting global warming: The potential of photocatalysis against CO2, CH4, N2O, CFCs, tropospheric O3, BC and other major contributors to climate change

    OpenAIRE

    De Richter, Renaud; Caillol, Sylvain

    2011-01-01

    International audience At the laboratory scale, photocatalysis is a promising method to convert many air pollutants such as nitrogen oxides and volatile organic compounds, to safer products for human health but also environmentally more acceptable, such as nitrate and carbon dioxide. Indoor and industrial applications of photocatalysis to remove local air pollutants from the atmosphere are now numerous. Large scale outdoor applications of photocatalysis started with self-cleaning glass, co...

  9. Comprehensive laboratory and field testing of cavity ring-down spectroscopy analyzers measuring H2O, CO2, CH4 and CO

    Science.gov (United States)

    Yver Kwok, C.; Laurent, O.; Guemri, A.; Philippon, C.; Wastine, B.; Rella, C. W.; Vuillemin, C.; Truong, F.; Delmotte, M.; Kazan, V.; Darding, M.; Lebègue, B.; Kaiser, C.; Xueref-Rémy, I.; Ramonet, M.

    2015-09-01

    To develop an accurate measurement network of greenhouse gases, instruments in the field need to be stable and precise and thus require infrequent calibrations and a low consumption of consumables. For about 10 years, cavity ring-down spectroscopy (CRDS) analyzers have been available that meet these stringent requirements for precision and stability. Here, we present the results of tests of CRDS instruments in the laboratory (47 instruments) and in the field (15 instruments). The precision and stability of the measurements are studied. We demonstrate that, thanks to rigorous testing, newer models generally perform better than older models, especially in terms of reproducibility between instruments. In the field, we see the importance of individual diagnostics during the installation phase, and we show the value of calibration and target gases that assess the quality of the data. Finally, we formulate recommendations for use of these analyzers in the field.

  10. Visualizing MOF Mixed Matrix Membranes at the Nanoscale: Towards Structure-Performance Relationships in CO 2 /CH 4 Separation Over NH 2 -MIL-53(Al)@PI

    NARCIS (Netherlands)

    Rodenas, T.; Van Dalen, M.; Garcia-Perez, E.; Serra-Crespo, P.; Zornoza, B.; Kapteijn, F.; Gascon, J.

    2013-01-01

    Mixed matrix membranes (MMMs) composed of metal organic framework (MOF) fi llers embedded in a polymeric matrix represent a promising alternative for CO 2 removal from natural gas and biogas. Here, MMMs based on NH 2 -MIL-53(Al) MOF and polyimide are successfully synthesized with MOF loadings up to

  11. Historical contribution by country of three greenhouse gases (CO2, CH4, N2O) to the climate change and Equity principle

    International Nuclear Information System (INIS)

    The historical contribution by country to climate change can be used as a basis of analysis for a second period of commitments to the burden share. The historical greenhouse gases emission inventory is an important tool to evaluate the common but differentiated responsibilities of groups according to the principle of the UN Framework Convention on Climate Convention (1992). This paper aims to discuss the differences among the meaning of the GHG historical emissions in terms of development patterns and suggests that different weights for different sectors should be taken into account. GHG emissions due to enteric fermentation from domestic livestock, for example, are linked to different regional activities such as food production, cultural expression or even religion meaning, depending on the region analyzed. Emissions due to fossil fuel sector represent in the majority a not feasible consumption pattern in terms of sustainable development

  12. Sensitivity of the boreal forest-mire ecotone CO2, CH4, and N2O global warming potential to rainy and dry weather

    Science.gov (United States)

    Ťupek, Boris; Minkkinen, Kari; Vesala, Timo; Nikinmaa, Eero

    2015-04-01

    In a mosaic of well drained forests and poorly drained mires of boreal landscape the weather events such as drought and rainy control greenhouse gas dynamics and ecosystem global warming potential (GWP). In forest-mire ecotone especially in ecosystems where CO2 sink is nearly balanced with CO2 source, it's fairly unknown whether the net warming effect of emissions of gases with strong radiative forcing (CH4 and N2O) could offset the net cooling effect of CO2 sequestration. We compared the net ecosystem CO2 exchange (NEE) estimated from the carbon sequestrations of forest stands and forest floor CO2 fluxes against CH4 and N2O fluxes of nine forest/mire site types along the soil moisture gradient in Finland. The ground water of nine sites changed between 10 m in upland forests and 0.1 m in mires, and weather during three years ranged between exceptionally wet and dry for the local climate. The NEE of upland forests was typically a sink of CO2, regardless the weather. Though, xeric pine forest was estimated to be a source of CO2 during wet and intermediate year and became a weak sink only in dry year. The NEE of forest-mire transitions ranged between a sink in dry year, while increased stand carbon sequestration could offset the reduced forest floor CO2 emission, and a source in wet year. The NEE of two sparsely forested mires strongly differed. The lawn type mire was balanced around zero and the hummock type mire was relatively strong NEE sink, regardless the weather. Generally, nearly zero N2O emission could not offset the cooling effect of net CH4 sink and net CO2 sink of upland forest and forest-mire transitions. However in sparsely forested mires, with N2O emission also nearly zero, the CH4 emission during wet and intermediate year played important role in turning the net cooling effect of NEE into a net warming. When evaluating GWP of boreal landscapes, undisturbed forest-mire transitions should be regarded as net cooling ecosystems instead of hotspots of net warming.

  13. Shipborne solar absorption measurements of CO2, CH4, N2O and CO and comparison with SCIAMACHY WFM-DOAS retrievals

    OpenAIRE

    Warneke, T.; De Beek, R.; M. Buchwitz; Notholt, J.; Schulz, A.; V. Velazco; O. Schrems

    2005-01-01

    CO, CH4, N2O and CO2 were retrieved from high resolution solar absorption spectra obtained during a ship cruise from Capetown to Bremerhaven in January/February 2003 by Fourier Transform Infrared (FTIR) spectroscopy. Precisions of better than 0.5% for the column averaged volume mixing ratios (VMR) of CH4 and CO2 are achieved using of O2 as a reference gas. Shipborne FTIR-measurements of CO and data from SCIAMACHY/ENVISAT retrieved by the Weighting Function Modified Different...

  14. Calculation of CO2,CH4 and H2S Solubilities in Aquenous Electrolyte Solution at High Prssure and High Temperature

    Institute of Scientific and Technical Information of China (English)

    1997-01-01

    This paper reports an investigation into the characterisation of liquid-vapor electrolyte solutions at high pressure and high temperature,A procedure to enable calculations of methane,carbon dioxide and hydrogen sulphide solubilities in brines(0-6m.) for temperature from 25 to 350℃ and for pressures from 1 to 1800 bar is presented.The model is based on Helgeson,Kirkham and Flowers modified equations of state(HKF)and on the semi-empirical interaction model introduced by Pitzer,HKF modified equations of state are used to calculate the reference fugacity of gas species,and the Pitzer ionic interaction model is used to calculate the activity coefficient of dissolved species(i.e.ionic or neutral).The efficiency of the combination of the two models is confirmed by several comparisons with data in the literature.

  15. Post-synthetic modification of porphyrin-encapsulating metal-organic materials by cooperative addition of inorganic salts to enhance CO 2/CH 4 selectivity

    KAUST Repository

    Zhang, ZhenJie

    2012-08-21

    Keeping MOM: Reaction of biphenyl-3,4\\',5-tricarboxylate and Cd(NO 3) 2 in the presence of meso-tetra(N-methyl-4-pyridyl) porphine tetratosylate afforded porph@MOM-11, a microporous metal-organic material (MOM) that encapsulates cationic porphyrins and solvent in alternating open channels. Porph@MOM-11 has cation and anion binding sites that facilitate cooperative addition of inorganic salts (such as M +Cl -) in a stoichiometric fashion. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. Studies on genesis of chromite and PGE in Naein ophiolite melange

    Directory of Open Access Journals (Sweden)

    Reza Shamsipour Dehkordi

    2011-10-01

    Full Text Available Nain ophiolite melange is located 140 Km east of Isfahan. Based on the geological studies, this area belongs to Mesozoic ophiolite of Urumieh – Dokhtar zone, west of central Iran. Country rocks are pridotite and serpentinized pridotite. The pridotite rocks are composed of Harzburgite, Lherzolite and replacement Dunite which is belong to spinel pridotite facies. Paragenesis of ore minerals are Chromite, Irarsite, Magnetite, Hematite, Pentlandite, Millerite, Chalcopyrite, Pyrite, and Covelline. Geochemical surveys of host rock and chromite show tholeiite series of magma and alpine type chromite. PGE (Ir, Pt, Pd, and Os are enriched in chromite. REE spider diagram pattern show the processes of boninitic magma and partial melting.

  17. Redução da emissão de CO2, CH4 e H2S através da compostagem de dejetos suínos Reduction emissions of CO2, CH4 and H2S through composting of swine manure

    Directory of Open Access Journals (Sweden)

    Luana G. Sardá

    2010-09-01

    Full Text Available Em conjunto com o crescente desenvolvimento da tecnologia para a produção de suínos ocorreu uma forte exploração e degradação do ambiente, razão pela qual a atividade se transformou em fonte poluidora das regiões produtoras. Buscam-se, então, alternativas que minimizem o potencial poluidor do atual sistema de produção. O trabalho proposto foi comparar o perfil de emissão de dióxido de carbono (CO2, metano (CH4 e gás sulfídrico (H2S do manejo de dejetos suínos nas formas sólida (compostagem e líquida (esterqueira, e avaliar a eficiência do processo de compostagem através dos parâmetros físico-químicos. O ensaio foi implantado no campo experimental da EMBRAPA Suínos e Aves, localizada no município de Concórdia, SC. Contatou-se, na compostagem, uma redução de 7 vezes na emissão de CH4, com relação à esterqueira; a emissão de CO2 representou 78,5% do carbono total mineralizado. Considerando-se que a emissão de H2S foi expressiva apenas no manejo dos dejetos na forma líquida, pode-se afirmar que o manejo dos resíduos na forma sólida é uma alternativa para a redução dos impactos ambientais pela mitigação do efeito estufa e pela redução de odores.In conjunction with the development of technologies for the production of swine meat, a strong exploration and degradation of the environment occurred and the activity became a source of pollution in the producing regions. Therefore, there is a need for alternative technologies that minimize the pollutant potential of the current system of production. The proposed work was to analyze and to compare the emission of carbon dioxide (CO2, methane (CH4 and hydrogen sulfide (H2S between the management of swine manure in solid form (composting and liquid manure (deep pit, and assess the efficiency of the process of composting through the physical and chemical parameters. The test was implemented in the experimental field of Embrapa Suínos e Aves, located in Concordia (SC. The results have showed that composting reduces 7 times the CH4 emission comparing to deep pit, and emission of CO2 represented 78.5% of total mineralized carbon. Considering that the emission of H2S was significant only in the management of waste in liquid form, then management of waste in solid form can reduce the environmental impacts, which tends to be beneficial in terms of mitigation of greenhouse effect and may contribute to the reduction of odors.

  18. Une alternative au cobalt pour la synthese de nanotubes de carbone monoparoi par plasma inductif thermique

    Science.gov (United States)

    Carrier, Jean-Francois

    Les nanotubes de carbone de type monoparoi (C-SWNT) sont une classe recente de nanomateriaux qui ont fait leur apparition en 1991. L'interet qu'on leur accorde provient des nombreuses proprietes d'avant-plan qu'ils possedent. Leur resistance mecanique serait des plus rigide, tout comme ils peuvent conduire l'electricite et la chaleur d'une maniere inegalee. Non moins, les C-SWNT promettent de devenir une nouvelle classe de plateforme moleculaire, en servant de site d'attache pour des groupements reactifs. Les promesses de ce type particulier de nanomateriau sont nombreuses, la question aujourd'hui est de comment les realiser. La technologie de synthese par plasma inductif thermique se situe avantageusement pour la qualite de ses produits, sa productivite et les faibles couts d'operation. Par contre, des recherches recentes ont permis de mettre en lumiere des risques d'expositions reliees a l'utilisation du cobalt, comme catalyseur de synthese; son elimination ou bien son remplacement est devenu une preoccupation importante. Quatre recettes alternatives ont ete mises a l'essai afin de trouver une alternative plus securitaire a la recette de base; un melange catalytique ternaire, compose de nickel, de cobalt et d'oxyde d'yttrium. La premiere consiste essentiellement a remplacer la proportion massique de cobalt par du nickel, qui etait deja present dans la recette de base. Les trois options suivantes contiennent de nouveaux catalyseurs, en remplacement au Co, qui sont apparus dans plusieurs recherches scientifiques au courant des dernieres annees: le dioxyde de zircone (ZrO2), dioxyde de manganese (MnO2) et le molybdene (Mo). La methode utilisee consiste a vaporiser la matiere premiere, sous forme solide, dans un reacteur plasma a haute frequence (3 MHz) a paroi refroidi. Apres le passage dans le plasma, le systeme traverse une section dite de "croissance", isolee thermiquement a l'aide de graphite, afin de maintenir une certaine plage de temperature favorable a la

  19. Application of radiolarians and other fossils in non-Smith strata--Exemplified by the A'nyêmaqên melange belt in East Kunlun Mts

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The main character of melange strata in an orogenic belt is the integration of mixed materials due to the superposition, displacement or loss of various tectonic slices (blocks) of different origins and environments, different scales, different grades of deformation and metamorphism, and different stages of tectonic evolution. The approach to non-Smith strata in an orogenic belt is to focus on the understanding of the age, facies, tectonic setting of the original formation and the process of deformation-metamorphism of each tectonic slice, reconstruct the history of dispersal and integration of these tectonic slices in time and space, i.e. 4-dimensional. This paper studies the age and facies of the original formation of tectonic slices in the A'nyêmaqên melange belt based on new data of radiolarians, sporo-pollen and trace fossils, and cast new lights on the research of the evolution process of that belt.

  20. Application of radiolarians and other fossils in non-Smith strata——Exemplified by the A’nyemaqen melange belt in East Kunlun Mts.

    Institute of Scientific and Technical Information of China (English)

    张克信; 黄继春; 殷鸿福; 王国灿; 王永标; 冯庆来; 田军

    2000-01-01

    The main character of melange strata in an erogenic belt is the integration of mixed materials due to the superposition, displacement or loss of various tectonic slices (blocks) of different origins and environments, different scales, different grades of deformation and metamor-phism, and different stages of tectonic evolution. The approach to non-Smith strata in an erogenic belt is to focus on the understanding of the age, facies, tectonic setting of the original formation and the process of deformation-metamorphism of each tectonic slice, reconstruct the history of dispersal and integration of these tectonic slices in time and space, i.e. 4-dimensional. This paper studies the age and facies of the original formation of tectonic slices in the A’nyemaqen melange belt based on new data of radiolarians, sporo-pollen and trace fossils, and cast new lights on the research of the evolution process of that belt.

  1. "Atmospheric Measurements by Ultra-Light SpEctrometer" (AMULSE) dedicated to vertical profile measurements of greenhouse gases (CO2, CH4) under stratospheric balloons: instrumental development and field application.

    Science.gov (United States)

    Maamary, Rabih; Joly, Lilian; Decarpenterie, Thomas; Cousin, Julien; Dumelié, Nicolas; Grouiez, Bruno; Albora, Grégory; Chauvin, Nicolas; Miftah-El-Khair, Zineb; Legain, Dominique; Tzanos, Diane; Barrié, Joel; Moulin, Eric; Ramonet, Michel; Bréon, François-Marie; Durry, Georges

    2016-04-01

    Human activities disrupt natural biogeochemical cycles such as the carbon and contribute to an increase in the concentrations of the greenhouse gases (carbone dioxide and methane) in the atmosphere. The current atmospheric transport modeling (the vertical trade) still represents an important source of uncertainty in the determination of regional flows of greenhouse gases, which means that a good knowledge of the vertical distribution of CO2 is necessary to (1) make the link between the ground measurements and spatial measurements that consider an integrated concentration over the entire column of the atmosphere, (2) validate and if possible improve CO2 transport model to make the link between surface emissions and observed concentration. The aim of this work is to develop a lightweight instrument (based on mid-infrared laser spectrometry principles) for in-situ measuring at high temporal/spatial resolution (5 Hz) the vertical profiles of the CO2 and the CH4 using balloons (meteorological and BSO at high precision levels (authorizations, costs and logistics flights. These laser spectrometers are built on recent instrumental developments. Several flights were successfully done in the region Champagne-Ardenne and in Canada recently. Aknowledgments: The authors acknowledge financial supports from CNES, CNRS défi instrumental and the region Champagne-Ardenne.

  2. "Atmospheric Measurements by Ultra-Light SpEctrometer" (AMULSE) dedicated to vertical profile measurements of greenhouse gases (CO2, CH4) under stratospheric balloons: instrumental development and field application.

    Science.gov (United States)

    Maamary, Rabih; Joly, Lilian; Decarpenterie, Thomas; Cousin, Julien; Dumelié, Nicolas; Grouiez, Bruno; Albora, Grégory; Chauvin, Nicolas; Miftah-El-Khair, Zineb; Legain, Dominique; Tzanos, Diane; Barrié, Joel; Moulin, Eric; Ramonet, Michel; Bréon, François-Marie; Durry, Georges

    2016-04-01

    Human activities disrupt natural biogeochemical cycles such as the carbon and contribute to an increase in the concentrations of the greenhouse gases (carbone dioxide and methane) in the atmosphere. The current atmospheric transport modeling (the vertical trade) still represents an important source of uncertainty in the determination of regional flows of greenhouse gases, which means that a good knowledge of the vertical distribution of CO2 is necessary to (1) make the link between the ground measurements and spatial measurements that consider an integrated concentration over the entire column of the atmosphere, (2) validate and if possible improve CO2 transport model to make the link between surface emissions and observed concentration. The aim of this work is to develop a lightweight instrument (based on mid-infrared laser spectrometry principles) for in-situ measuring at high temporal/spatial resolution (5 Hz) the vertical profiles of the CO2 and the CH4 using balloons (meteorological and BSO at high precision levels (logistics flights. These laser spectrometers are built on recent instrumental developments. Several flights were successfully done in the region Champagne-Ardenne and in Canada recently. Aknowledgments: The authors acknowledge financial supports from CNES, CNRS défi instrumental and the region Champagne-Ardenne.

  3. ÉMISSION DE GAZ A EFFET DE SERRE (CO2, CH4) PAR UNE RETENUE DE BARRAGE HYDROÉLECTRIQUE EN ZONE TROPICALE (PETIT-SAUT, GUYANE FRANÇAISE) :
    EXPÉRIMENTATION ET MODÉLISATION

    OpenAIRE

    Guérin, Frédéric

    2006-01-01

    The emissions of carbon dioxide (CO2) and methane (CH4) and the carbon cycle in the Petit-Saut reservoir and in the Sinnamary River (French Guiana) were studied with an aim of developing a coupled physical/biogeochemical model. The development of this model required the study of three processes controlling these emissions: (i) CO2 and CH4 production during the mineralization in anoxic condition of organic matter (OM) from soils and plants, (ii) aerobic CH4 oxidation in the water column of the...

  4. Long-term measurements of atmospheric trace gases (CO2, CH4, N2O, SF6, CO, H2), O2, and δ13CH4 isotopes at Weybourne Atmospheric Observatory, UK: past, present and future

    Science.gov (United States)

    Manning, Andrew C.; Forster, Grant L.; Oram, David E.; Reeves, Claire E.; Pickers, Penelope A.; Barningham, S. Thomas; Sturges, William T.; Bandy, Brian; Nisbet, Euan G.; Lowry, David; Fisher, Rebecca; Fleming, Zoe

    2016-04-01

    The Weybourne Atmospheric Observatory (WAO) is situated on the north Norfolk Coast (52.95°N, 1.13°E) in the United Kingdom and is run by the University of East Anglia (UEA), with support from the UK National Centre for Atmospheric Science (NCAS). In 2016, the WAO became a UK-ICOS (Integrated Carbon Observing System) monitoring station. Since 2008, we have been collecting high-precision long-term in situ measurements of atmospheric carbon dioxide (CO2), oxygen (O2), carbon monoxide (CO) and molecular hydrogen (H2), as well as regular bag sampling for δ13CH4. In early 2013, the measurement of atmospheric methane (CH4) commenced, and nitrous oxide (N2O) and sulphur hexafluoride (SF6) began in 2014. We summarise the CO2, O2, CH4, N2O, SF6, CO, H2 and δ13CH4 measurements made to date and highlight some key features observed (e.g. seasonal cycles, long-term trends, pollution events and deposition events). We summarise how the long-term measurements fit into other broader projects which have helped to support the long term time-series at WAO over the years, and highlight how we contribute to broader global atmospheric observation networks.

  5. How well can we assess impacts of agricultural land management changes on the total greenhouse gas balance (CO2, CH4 and N2O) of tropical rice-cropping systems with biogeochemical models?

    Science.gov (United States)

    Kraus, David; Weller, Sebastian; Janz, Baldur; Klatt, Steffen; Santabárbara, Ignacio; Haas, Edwin; Werner, Christian; Wassmann, Reiner; Kiese, Ralf; Butterbach-Bahl, Klaus

    2016-04-01

    Paddy rice cultivation is increasingly challenged by physical and economic irrigation water scarcity. This already results in the trend of converting paddy rice to upland crop cultivation (e.g., maize, aerobic rice) in large parts of South East Asia. Such land management change from flooded lowland systems to well-aerated upland systems drastically affects soil C and N cycling and related emissions of greenhouse gases. Emissions of methane (CH4) are expected to decrease, while emissions of nitrous oxide (N2O) will most likely increase. In addition to such fast evolving 'pollution swapping' it is expected that on longer time scales significant amounts of soil organic carbon (SOC) stocks will be lost in form of carbon dioxide (CO2). Within the DFG-funded research unit ICON (Introducing non-flooded crops in rice-dominated landscapes: Impact on carbon, nitrogen and water cycles), we investigated environmental impacts of land management change from historical paddy rice cultivation to the upland crops maize and aerobic rice at experimental sites at the International Rice Research Institute (IRRI), the Philippines. To present, more than three years of continuous measurement data of CH4 and N2O emissions under different fertilization regimes have been collected. In addition, measurements of SOC contents and bulk densities in different soil horizons allow for an overall very good characterization of the environmental impacts of mentioned land management change. In this contribution we will show how well mentioned land management change effects in tropical agricultural systems can be represented and thus better understood by the help of process-based biogeochemical models. Seasonal emissions of CH4 and N2O are simulated with r2 values of 0.85 and 0.78 and average underestimations of 15 and 14 %, respectively. These underestimations predominantly originate from treatments in which no fertilizer is applied (CH4) as well as uncertainties of soil hydrology (N2O). Long-term development of SOC stocks is highly influenced by the soil oxygen status as well as the growth of photosynthetic active aquatic biomass. Moreover, simulation results demonstrate that short-term GHG balances may considerably differ from long-term balances. Simulated total GHG emissions 2.5 years after land management change are highest for upland crop - paddy rice rotations due to pronounced losses of soil organic carbon. In contrast, over a longer period of several decades total GHG emissions are highest for double cropping of paddy rice clearly dominated by CH4 emissions. Simulation results suggest that approx. 2.8 - 3.4 t C ha-1 yr-1 residue incorporation after harvest is needed in order to sustain stable SOC stocks in mixed upland crop - paddy rice systems.

  6. How well can we assess impacts of agricultural land management changes on the total greenhouse gas balance (CO2, CH4 and N2O) of tropical rice-cropping systems with biogeochemical models?

    Science.gov (United States)

    Kraus, David; Weller, Sebastian; Janz, Baldur; Klatt, Steffen; Santabárbara, Ignacio; Haas, Edwin; Werner, Christian; Wassmann, Reiner; Kiese, Ralf; Butterbach-Bahl, Klaus

    2016-04-01

    Paddy rice cultivation is increasingly challenged by physical and economic irrigation water scarcity. This already results in the trend of converting paddy rice to upland crop cultivation (e.g., maize, aerobic rice) in large parts of South East Asia. Such land management change from flooded lowland systems to well-aerated upland systems drastically affects soil C and N cycling and related emissions of greenhouse gases. Emissions of methane (CH4) are expected to decrease, while emissions of nitrous oxide (N2O) will most likely increase. In addition to such fast evolving 'pollution swapping' it is expected that on longer time scales significant amounts of soil organic carbon (SOC) stocks will be lost in form of carbon dioxide (CO2). Within the DFG-funded research unit ICON (Introducing non-flooded crops in rice-dominated landscapes: Impact on carbon, nitrogen and water cycles), we investigated environmental impacts of land management change from historical paddy rice cultivation to the upland crops maize and aerobic rice at experimental sites at the International Rice Research Institute (IRRI), the Philippines. To present, more than three years of continuous measurement data of CH4 and N2O emissions under different fertilization regimes have been collected. In addition, measurements of SOC contents and bulk densities in different soil horizons allow for an overall very good characterization of the environmental impacts of mentioned land management change. In this contribution we will show how well mentioned land management change effects in tropical agricultural systems can be represented and thus better understood by the help of process-based biogeochemical models. Seasonal emissions of CH4 and N2O are simulated with r2 values of 0.85 and 0.78 and average underestimations of 15 and 14 %, respectively. These underestimations predominantly originate from treatments in which no fertilizer is applied (CH4) as well as uncertainties of soil hydrology (N2O). Long-term development of SOC stocks is highly influenced by the soil oxygen status as well as the growth of photosynthetic active aquatic biomass. Moreover, simulation results demonstrate that short-term GHG balances may considerably differ from long-term balances. Simulated total GHG emissions 2.5 years after land management change are highest for upland crop - paddy rice rotations due to pronounced losses of soil organic carbon. In contrast, over a longer period of several decades total GHG emissions are highest for double cropping of paddy rice clearly dominated by CH4 emissions. Simulation results suggest that approx. 2.8 - 3.4 t C ha‑1 yr‑1 residue incorporation after harvest is needed in order to sustain stable SOC stocks in mixed upland crop - paddy rice systems.

  7. Gridino melange zone of the Belomorian eclogite province: Succession of tectonic events and structural position of mafic dyke swarms

    Science.gov (United States)

    Babarina, I. I.; Sibelev, O. S.; Stepanova, A. V.

    2014-07-01

    Based on relationships between Paleoproterozoic mafic dykes, lithotectonic complexes, and tectonic structures of the Gridino Zone in the Belomorian eclogite province of the Fennoscandian Shield, deformations have been divided into groups differing in age and the succession of tectonic events has been reconstructed. The formation of Neoarchean eclogite-bearing melange was related to disintegration of large eclogite sheets in the course of near-horizontal ductile flow accompanied by syntectonic granitoid magmatism, multiple migmatization, and granulite-to amphibolite-facies metamorphism. The exotic blocks, including eclogites, were incorporated into TTG gneisses as sheets and lenses up to a few hundreds of meters in thickness and oriented conformably with gneissic banding. As a result of ductile flow, the lithotectonic complexes were transported at the level of discrete brittle-ductile deformations expressed as strike-slip faults and associated folds. Under conditions of a relatively rigid medium, individual structural elements underwent rotation approximately through 90° in plan view. Under the extension regime in the Early Paleoproterozoic, several swarms of mafic dykes were injected into the already cold framework rocks, as is evident from dyke morphology. The dykes crosscut all predated structures, included turned blocks, and are therefore important reference points for subdivision of Neoarchean and Paleoproterozoic processes. The Svecofennian postdyke tectonic activity was accompanied by local shearing and boudinage of metabasic rocks, development of quartz and pegmatite veins along tension cracks, disharmonic folding, and discrete retrograde metamorphism up to amphibolite-facies conditions. The postdyke deformations did not exert a substantial effect on the previously formed regional structure.

  8. Melanges, No. 23.

    Science.gov (United States)

    Melanges, 1997

    1997-01-01

    Articles on second language teaching and learning include: "Ethnographie comparee de la salle de classe en France et en grande-Bretagne" (Comparative Ethnography of the Classroom Environment in France and Great Britain) (F. Carton); "Pour une approche micro et macro du francais parle dans la formation des enseignants de FLE" (Toward a Micro and…

  9. Ultra-relativistic Au+Au and d+Au collisions:

    Science.gov (United States)

    Back, B. B.; Baker, M. D.; Ballintijn, M.; Barton, D. S.; Betts, R. R.; Bickley, A. A.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Chai, Z.; Decowski, M. P.; García, E.; Gburek, T.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Hauer, M.; Heintzelman, G. A.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Hołyński, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C. M.; Lin, W. T.; Manly, S.; McLeod, D.; Mignerey, A. C.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Remsberg, L. P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Seals, H.; Sedykh, I.; Skulski, W.; Smith, C. E.; Stankiewicz, M. A.; Steinberg, P.; Stephans, G. S. F.; Sukhanov, A.; Tang, J.-L.; Tonjes, M. B.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Vaurynovich, S. S.; Verdier, R.; Veres, G. I.; Wenger, E.; Wolfs, F. L. H.; Wosiek, B.; Woźniak, K.; Wuosmaa, A. H.; Wysłouch, B.

    In this talk I will review PHOBOS data on charged particle multiplicities, obtained in Au+Au and d+Au collisions at RHIC. The general features of the Au+Au pseudorapidity distributions results will be discussed and compared to those of /line{p}p collisions. The total charged particle multiplicity, scaled by the number of participant pairs, is observed to be about 40% higher in Au+Au collisions than in /line{p}p and d+Au systems, but, surprisingly at the same level of e+e- collisions. Limiting fragmentation scaling is seen to be obeyed in Au+Au collisions.

  10. Au pair trajectories

    DEFF Research Database (Denmark)

    Dalgas, Karina Märcher

    2015-01-01

    Since 2000, thousands of young Filipino migrants have come to Denmark as au pairs. Officially, they are there to “broaden their cultural horizons” by living temporarily with a Danish host family, but they also conduct domestic labor in exchange for food and money, which allows them to send...... ethnographic component of the dissertation consists of four articles, all emphasizing the au pairs’ agency by viewing their migration as a dynamic personal and social experience. Arguing that Filipina au pairs tend to be understood primarily from the perspective of their precarious situation as domestic...... of their Danish host families. Based on their migratory status as au pairs, these young migrants must therefore negotiate the different moral and contractual rights and obligations that characterize the local and transnational family ties in which they are engaged. This study of Filipina au pair migration through...

  11. Denmark's national inventory report. Submitted under the United Nations framework convention on climate change, 1990-2001. Emission inventories

    International Nuclear Information System (INIS)

    This report is Denmark's National Inventory Report reported to the Conference of the Parties under the United Nations Framework Convention on Climate Change (UNFCCC) due bye 15 April 2003. The report contains information on Denmark's inventories for all years' from 1990 to 2001 for CO2, CH4, N2O, CO, NMVOC, SO2, HFCs, PFCs and SF6. (au)

  12. Denmark's national inventory report 2006 - Submitted under the United Nations framework convention on climate change, 1990-2004. Emission inventories

    International Nuclear Information System (INIS)

    This report is Denmark's National Inventory Report reported to the Conference of the Parties under the United Nations Framework Convention on Climate Change (UNFCCC) due by 15 April 2006. The report contains information on Denmark's inventories for all years' from 1990 to 2004 for CO2, CH4, N2O, HFCs, PFCs and SF6, CO, NMVOC, SO2. (au)

  13. Denmark's National Inventory Reports. Submitted under the United Nations framework convention on climate change

    International Nuclear Information System (INIS)

    This report is Denmark's National Inventory Report reported to the Conference of the Parties under the United Nations Framework Convention on Climate Change (UNFCCC) due by 15 April 2000. The report contains information on Denmark's inventories for all years from 1990 to 1998 for CO2, CH4, N2O, NOx, CO, NMVOC, SO2, HFCs, PFCs and SF. (au)

  14. Catalytic activity of Au nanoparticles

    DEFF Research Database (Denmark)

    Larsen, Britt Hvolbæk; Janssens, Ton V.W.; Clausen, Bjerne;

    2007-01-01

    Au is usually viewed as an inert metal, but surprisingly it has been found that Au nanoparticles less than 3–5 nm in diameter are catalytically active for several chemical reactions. We discuss the origin of this effect, focusing on the way in which the chemical activity of Au may change with par......Au is usually viewed as an inert metal, but surprisingly it has been found that Au nanoparticles less than 3–5 nm in diameter are catalytically active for several chemical reactions. We discuss the origin of this effect, focusing on the way in which the chemical activity of Au may change...... with particle size. We find that the fraction of low-coordinated Au atoms scales approximately with the catalytic activity, suggesting that atoms on the corners and edges of Au nanoparticles are the active sites. This effect is explained using density functional calculations....

  15. Magnetic susceptibilities of liquid Cr-Au, Mn-Au and Fe-Au alloys

    Energy Technology Data Exchange (ETDEWEB)

    Ohno, S.; Shimakura, H. [Niigata University of Pharmacy and Applied Life Sciences, Higashijima, Akiha-ku, Niigata 956-8603 (Japan); Tahara, S. [Faculty of Science, University of the Ryukyus, Nishihara-cho, Okinawa 903-0213 (Japan); Okada, T. [Niigata College of Technology, Kamishin’eicho, Nishi-ku, Niigata 950-2076 (Japan)

    2015-08-17

    The magnetic susceptibility of liquid Cr-Au, Mn-Au, Fe-Au and Cu-Au alloys was investigated as a function of temperature and composition. Liquid Cr{sub 1-c}Au{sub c} with 0.5 ≤ c and Mn{sub 1-c}Au{sub c} with 0.3≤c obeyed the Curie-Weiss law with regard to their dependence of χ on temperature. The magnetic susceptibilities of liquid Fe-Au alloys also exhibited Curie-Weiss behavior with a reasonable value for the effective number of Bohr magneton. On the Au-rich side, the composition dependence of χ for liquid TM-Au (TM=Cr, Mn, Fe) alloys increased rapidly with increasing TM content, respectively. Additionally, the composition dependences of χ for liquid Cr-Au, Mn-Au, and Fe-Au alloys had maxima at compositions of 50 at% Cr, 70 at% Mn, and 85 at% Fe, respectively. We compared the composition dependences of χ{sub 3d} due to 3d electrons for liquid binary TM-M (M=Au, Al, Si, Sb), and investigated the relationship between χ{sub 3d} and E{sub F} in liquid binary TM-M alloys at a composition of 50 at% TM.

  16. Analysis of hydrogen-deuterium mixtures and of mixtures of heavy-water and light-water by means of a mass spectrometer; Analyse des melanges hydrogene-deuterium et des melanges d'eau lourde et d'eau legere au moyen du spectrometre de masse

    Energy Technology Data Exchange (ETDEWEB)

    Chenouard, J.; Gueron, J.; Roth, E

    1951-07-01

    The differences between hydrogen and deuterium with respect to the capture of thermal neutrons (hydrogen = 0.31 barn; deuterium 0.00065 barn) explains the interest of detecting small variations of the isotopic composition of the heavy waters used in the Chatillon nuclear pile. The aim of this report is to describe and discuss the method used since more than a year for the dosimetry of heavy waters. After a recall of the principle of mass spectroscopy analysis of deuterium-hydrogen mixtures, the preciseness of the results is presented and the balancing method used for the determination of the isotopic composition of hydrogen-deuterium mixtures is explained in detail. Finally, a brief comparison of the preciseness of mass spectroscopy measurements with the analyses made with other methods is performed. Some calculations and the tables of results are presented in appendixes. (J.S.)

  17. Etre touareg au Mali

    OpenAIRE

    Edmond BERNUS

    1992-01-01

    Après une présentation générale de leur espace, de leur culture commune, des stéréotypes dont ils font l'objet, les Touaregs maliens sont décrits dans leurs diversités régionales. Les révoltes passées, celle de Firhoun, le héros de 1916, puis celle de l'Adrar des Iforas en 1963-64 contre le gouvernement de Modibo Keita, précédent la révolte qui s'étend depuis 1990 au Niger et au Mali avec des guerriers sachant manier armes et voitures. Attaques et répression sauvage se succèdent dans une spir...

  18. Introduction au droit commercial

    OpenAIRE

    Thirion, Nicolas; Delvaux, Thierry; Benoit-Moury, Anne

    2009-01-01

    Le cours d'introduction au droit commercial, destiné à des non-juristes, a pour objet de décrire, dans ses grandes lignes, le régime juridique applicable à l'organisation et au fonctionnement de l'économie. Les liens avec des disciplines autres que le droit, notamment l'économie et l'histoire, seront privilégiés, afin d'adapter la matière aux besoins et centres d'intérêts d'étudiants en sciences humaines. Après une introduction générale, le cours s'articule autour de la trilogie fondamentale ...

  19. Antibacterial Au nanostructured surfaces

    Science.gov (United States)

    Wu, Songmei; Zuber, Flavia; Brugger, Juergen; Maniura-Weber, Katharina; Ren, Qun

    2016-01-01

    We present here a technological platform for engineering Au nanotopographies by templated electrodeposition on antibacterial surfaces. Three different types of nanostructures were fabricated: nanopillars, nanorings and nanonuggets. The nanopillars are the basic structures and are 50 nm in diameter and 100 nm in height. Particular arrangement of the nanopillars in various geometries formed nanorings and nanonuggets. Flat surfaces, rough substrate surfaces, and various nanostructured surfaces were compared for their abilities to attach and kill bacterial cells. Methicillin-resistant Staphylococcus aureus, a Gram-positive bacterial strain responsible for many infections in health care system, was used as the model bacterial strain. It was found that all the Au nanostructures, regardless their shapes, exhibited similar excellent antibacterial properties. A comparison of live cells attached to nanotopographic surfaces showed that the number of live S. aureus cells was technological platform for engineering Au nanotopographies by templated electrodeposition on antibacterial surfaces. Three different types of nanostructures were fabricated: nanopillars, nanorings and nanonuggets. The nanopillars are the basic structures and are 50 nm in diameter and 100 nm in height. Particular arrangement of the nanopillars in various geometries formed nanorings and nanonuggets. Flat surfaces, rough substrate surfaces, and various nanostructured surfaces were compared for their abilities to attach and kill bacterial cells. Methicillin-resistant Staphylococcus aureus, a Gram-positive bacterial strain responsible for many infections in health care system, was used as the model bacterial strain. It was found that all the Au nanostructures, regardless their shapes, exhibited similar excellent antibacterial properties. A comparison of live cells attached to nanotopographic surfaces showed that the number of live S. aureus cells was information (ESI) available. See DOI: 10.1039/c5nr06157a

  20. Magnetic susceptibilities of liquid Cr-Au, Mn-Au and Fe-Au alloys

    Science.gov (United States)

    Ohno, S.; Shimakura, H.; Tahara, S.; Okada, T.

    2015-08-01

    The magnetic susceptibility of liquid Cr-Au, Mn-Au, Fe-Au and Cu-Au alloys was investigated as a function of temperature and composition. Liquid Cr1-cAuc with 0.5 ≤ c and Mn1-cAuc with 0.3≤c obeyed the Curie-Weiss law with regard to their dependence of χ on temperature. The magnetic susceptibilities of liquid Fe-Au alloys also exhibited Curie-Weiss behavior with a reasonable value for the effective number of Bohr magneton. On the Au-rich side, the composition dependence of χ for liquid TM-Au (TM=Cr, Mn, Fe) alloys increased rapidly with increasing TM content, respectively. Additionally, the composition dependences of χ for liquid Cr-Au, Mn-Au, and Fe-Au alloys had maxima at compositions of 50 at% Cr, 70 at% Mn, and 85 at% Fe, respectively. We compared the composition dependences of χ3d due to 3d electrons for liquid binary TM-M (M=Au, Al, Si, Sb), and investigated the relationship between χ3d and EF in liquid binary TM-M alloys at a composition of 50 at% TM.

  1. 农田土壤主要温室气体(CO2、CH4、N2O)的源/汇强度及其温室效应研究进展%Research advances on source/sink intensities and greenhouse effects of CO2,CH4 and N2O in agricultural soils

    Institute of Scientific and Technical Information of China (English)

    张玉铭; 胡春胜; 张佳宝; 董文旭; 王玉英; 宋利娜

    2011-01-01

    气候变化是当今全球面临的重大挑战,人类社会生产生活引起的温室气体排放是全球气候变暖的主要原因.大气中CO2、CH4和N2O是最重要的温室气体,对温室效应的贡献率占了近80%.据估计,大气中每年有5%~20%的CO2、15%~30%的CH4、80%~90%的N2O来源于土壤,而农田土壤是温室气体的重要排放源.本文重点阐述了农田土壤温室气体产生、排放或吸收机理及其影响因素,指出土地利用方式和农业生产力水平等人为控制因素通过影响土壤和作物生长条件来影响农田土壤温室气体产生与排放或吸收.所以,我们可以从人类活动对农田生态系统的影响着手,通过改善农业生产方式和作物生长条件来探索温室气体减排措施,达到固碳/氨增汇的目的.对国内外关于农田温室气体排放的源/汇强度及其综合温室效应评估的最新研究进展进行了综述,指出正确估算与评价农田土壤温室气体的源/汇强度及其对大气中主要温室气体浓度变化的贡献,有助于为温室气体减排以及减少气候变化预测的不确定性提供理论依据.%Climate change is an increasing global challenge. Greenhouse gas emission via anthropogenic processes is the main cause of global warming. CO3, CH4, and N2O are the main greenhouse gases, accounting for =80% of greenhouse effect. It is estimated that each year, 5%~20% of CO2, 15%-30% of CR, and 80%~90% of N2O in air are emitted from soils. Agricultural soils are the main sources of greenhouse gas emission. This work expatiated the mechanisms and affecting factors of greenhouse gas formation, emission and absorption in agricultural soils. And the contribution of farmland ecosystem to greenhouse effects was discussed. It was indicated that anthropogenic factors such as land use and agricultural activity influenced greenhouse gas formation, emission and absorption in agricultural soils. Because anthropogenic processes affected agricultural ecosystems, greenhouse gas emission reductions for stabilized carbon and nitrogen were possible through improved agricultural cultivation and production systems. This study summarized the latest research advances in source/sink intensities of greenhouse gas emissions from farmlands and how that contributes to greenhouse effect. The study suggested that accurate estimation of source/sink intensities of greenhouse gases and ap-propriate assessments of greenhouse gas effects were the theoretical basis for reducing greenhouse gas emissions and uncertainties inpredicting climate change.

  2. Vehicle emissions of greenhouse gases and related tracers from a tunnel study: : CO: CO2, N2O: CO2, CH4: CO2, O2: CO2 ratios, and the stable isotopes 13C and 18O in CO2 and CO

    NARCIS (Netherlands)

    Popa, Maria Elena; Vollmer, M. K.; Jordan, A.; Brand, W. A.; Pathirana, S. L.; Rothe, M.; Röckmann, T.

    2014-01-01

    Measurements of CO2, CO, N2O and CH4 mole fractions, O2/N2 ratios and the stable isotopes 13C and 18O in CO2 and CO have been performed in air samples from the Islisberg highway tunnel (Switzerland). The molar CO : CO2 ratios, with an average of (4.15 ± 0.34) ppb:ppm, are lower than reported in prev

  3. Vivre, vivre au Japon

    OpenAIRE

    Tardits, Manuel

    2014-01-01

    Comment faire face au caractère récurrent des catastrophes naturelles et liées à l’homme ? À la prévention, on se doit d’adjoindre une vision écologique plus large et renouvelée. Un débat sur le modèle énergétique du nucléaire et sur nos modèles de développement urbains et sociétaux s’impose.

  4. Des femmes au tribunal

    OpenAIRE

    Le Pape, Marc

    2010-01-01

    Les archives judiciaires constituent une source essentielle pour les études des sociabilités africaines en situation coloniale. Cet article prend appui sur l’analyse des procès tenus, entre 1923 et 1939, au tribunal du premier degré d’Abidjan, il vise à décrire les argumentations contradictoires par lesquelles femmes et hommes expliquent leurs différends dans l’espace du prétoire. Les registres issus des « juridictions indigènes » permettent également d’apprécier sur quels repères se fondent ...

  5. Des ignames au riz

    OpenAIRE

    Ivanoff, Jacques

    2003-01-01

    L'igname a toujours été une nourriture importante pour les populations littorales et nomades du monde insulindien. Cependant, avec l'installation du héros civilisateur Gaman le Malais chez le peuple de la reine Sibian, le riz va devenir la composante essentielle des repas moken. En intégrant Gaman en son sein, la société moken va devoir répondre au double défi posé par la menace de la riziculture et de l'islam. En donnant femme à Gaman, en adoptant le nomadisme pour échapper à l'islam ...

  6. Introduction au titre I

    OpenAIRE

    2015-01-01

    Pline a eu dans sa carrière d’homme public à défendre les intérêts de l’Etat et des particuliers, à épurer des comptes, à juger et arbitrer. Ainsi le voulait l’ordonnancement du cursus honorum du Bas-Empire, héritier sur tous ces points de la tradition des charges publiques de la République. Les premières tâches du petiturus furent essentiellement judiciaires - on songe au vigintivirat - et elles se poursuivirent par des fonctions de moyenne importance (préture consulat) puis de haute adminis...

  7. Photoelectrochemical studies of DNA-tagged biomolecules on Au and Au/Ni/Au multilayer nanowires

    Directory of Open Access Journals (Sweden)

    Swaminathan Viswanathan

    2011-01-01

    Full Text Available Abstract The use of nanowires (NWs for labeling, sensing, and sorting is the basis of detecting biomolecules attached on NWs by optical and magnetic properties. In spite of many advantages, the use of biomolecules-attached NWs sensing by photoelectrochemical (PEC study is almost non-existent. In this article, the PEC study of dye-attached single-stranded DNA on Au NWs and Au-Ni-Au multilayer NWs prepared by pulse electrodeposition are investigated. Owing to quantum-quenching effect, the multilayer Au NWs exhibit low optical absorbance when compared with Au NWs. The tagged Au NWs show good fluorescence (emission at 570 nm, indicating significant improvement in the reflectivity. Optimum results obtained for tagged Au NWs attached on functionalized carbon electrodes and its PEC behavior is also presented. A twofold enhancement in photocurrent is observed with an average dark current of 10 μA for Au NWs coated on functionalized sensing electrode. The importance of these PEC and optical studies provides an inexpensive and facile processing platform for Au NWs that may be suitable for biolabeling applications.

  8. Le marketing au concret

    OpenAIRE

    Gaglio, Gérald

    2010-01-01

    Le terme “marketing” suscite généralement la méfiance, car il est spontanément associé à l’idée de manipulation. Au-delà, que font, concrètement, les “gens du marketing” ? Afin d’apporter des pistes de réponse à cette question, nous nous penchons dans cet article sur les enjeux relatifs à un matériau censé alimenter les réflexions et décisions des marketeurs : les études qualitatives de marketing research réalisées dans le cadre de réunions de consommateurs. Cette approche nous conduit à expl...

  9. Introduction au titre II

    OpenAIRE

    2015-01-01

    159. L’objet de notre propos est de démontrer que l’Administration dispose, à la suite du juge, d’un véritable pouvoir normatif. L’admettre suppose d’en identifier les différentes manifestations qui s’expriment essentiellement par voie de circulaires administratives, de réponses ministérielles et d’avis administratifs et qui ne sauraient être assimilées au pouvoir réglementaire que l’Administration détient par ailleurs. L’ordre logique de la démonstration sera donc semblable à celui adopté po...

  10. Electrochemical study of chemical properties in ethanolamine and its mixtures with water; Etude electrochimique de proprietes chimiques dans l'ethanolamine et ses melanges avec l'eau

    Energy Technology Data Exchange (ETDEWEB)

    Grall, M. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1964-12-01

    This work is concerned with the study of acid-base reactions and of complex formation in ethanolamine and its mixtures with water. The ionic product of the solvent has been determined by an electro-chemical study of the H{sup +}/H{sub 2} system. The reduction curves for ethanolamine-water mixtures, for different acidities, have made it possible to follow the variations in the size of the pH domain as a function of the composition of the solvent. The form of this variation has been explained on the basis of the dielectric constant and the solvation of the proton by the ethanolamine. In the second part, the electrochemical systems of mercury have been studied by anodic polarography. In order to establish a parallel between the acid-base reactions and complex formation reactions, we have studied the stability of Hg (CN){sub 2} in water-ethanolamine mixtures. It has been possible to deduce the law for the variation of pK{sub c} with solvent composition. The representative graph of this function passes through a minimum for a proportion of about 50 per cent of ethanolamine as in the case of acids. This variation has been explained by the predominating influence of {epsilon} for ethanolamine propositions of over 50 per cent and by that of the solvation of Hg{sup 2+} for proportions of under 50 per cent. (author) [French] Ce travail porte sur l'etude des reactions acides-bases et de formation de complexes dans l'ethanolamine et ses melanges avec l'eau. Le produit ionique du solvant a pu etre determine par l'etude electro-chimique du systeme H{sup +}/H{sub 2}. Les courbes de reduction des melanges ethanolamine-eau, pour des acidites variables, ont permis de suivre les variations de l'etendue du domaine de pH, en fonction de la composition du solvant. L'allure de cette variation a ete expliquee en faisant intervenir la constante dielectrique et la solvatation du proton par l'ethanolamine. Dans une deuxieme partie, les systemes

  11. Face au risque

    CERN Document Server

    Grosse, Christian; November, Valérie

    2007-01-01

    Ce volume collectif sur le risque inaugure la collection L'ÉQUINOXE. Ancré dans l'histoire pour mesurer les continuités et les ruptures, il illustre la manière dont les sciences humaines évaluent et mesurent les enjeux collectifs du risque sur les plans politiques, scientifiques, énergétiques, juridiques et éthiques. Puisse-t-il nourrir la réflexion sur la culture et la prévention du risque. Ses formes épidémiques, écologiques, sociales, terroristes et militaires nourrissent les peurs actuelles, structurent les projets sécuritaires et constituent - sans doute - les défis majeurs à notre modernité. Dans la foulée de la richesse scientifique d'Equinoxe, L'ÉQUINOXE hérite de son esprit en prenant à son tour le pari de contribuer - non sans risque - à enrichir en Suisse romande et ailleurs le champ éditorial des sciences humaines dont notre société a besoin pour forger ses repères. Après Face au risque suivra cet automne Du sens des Lumières. (MICHEL PORRET Professeur Ordinaire à la F...

  12. Thermodynamic assessment of Au-Zr system

    Institute of Scientific and Technical Information of China (English)

    李志华; 金展鹏; 刘华山

    2003-01-01

    Au-Zr binary system was reassessed by using the calculation phase diagram (CALPHAD) technique based on experimental thermodynamic data and newly reported phase diagrams. The excess Gibbs energies of the three terminal solutions and the liquid phases were formulated with Redlich-Kister polynomial. All the intermetallic phases were treated as stoichiometric compounds with the exception of ZrAu which is modeled by a two-sublattice model, (Au,Zr) : (Au, Zr). The results show that there exist seven intermetallics: Zr3Au, Zr2Au, Zr5Au4,Zr7Au10, ZrAu2 , ZrAu3, and ZrAu4 in the system. The eutectoid reaction: β(Zr) →α(Zr)+Zr3Au takes place at 1 048 K and the maximal solubility of Au in α-Zr is 4.7 % (mole fraction). The maximal solubility of Zr in Au is 6.0%(mole fraction) at 1 347 K. The homogeneity range of ZrAu phase is about 44.5%-52.9%(mole fraction) of Au. The present assessment fits experimental data very well.

  13. Flow in Au+Au collisions at RHIC

    Science.gov (United States)

    Belt Tonjes, Marguerite; PHOBOS Collaboration; Back, B. B.; Baker, M. D.; Ballintijn, M.; Barton, D. S.; Betts, R. R.; Bickley, A. A.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Decowski, M. P.; García, E.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Heintzelman, G. A.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Holynski, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C. M.; Lin, W. T.; Manly, S.; McLeod, D.; Mignerey, A. C.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Remsberg, L. P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Skulski, W.; Steinberg, P.; Stephans, G. S. F.; Sukhanov, A.; Tang, J.-L.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Verdier, R.; Wolfs, F. L. H.; Wosiek, B.; Wozniak, K.; Wuosmaa, A. H.; Wyslouch, B.

    2004-08-01

    The study of flow can provide information on the initial state dynamics and the degree of equilibration attained in heavy-ion collisions. This contribution presents results for both elliptic and directed flow as determined from data recorded by the PHOBOS experiment in Au+Au runs at RHIC at \\sqrt{s_{{\\rm NN}}} = 19.6, 130 and 200 GeV. The PHOBOS detector provides a unique coverage in pseudorapidity for measuring flow at RHIC. The systematic dependence of flow on pseudorapidity, transverse momentum, centrality and energy is discussed.

  14. Multiscale Modeling of Au-Island Ripening on Au(100

    Directory of Open Access Journals (Sweden)

    Karin Kleiner

    2011-01-01

    Full Text Available We describe a multiscale modeling hierarchy for the particular case of Au-island ripening on Au(100. Starting at the microscopic scale, density functional theory was used to investigate a limited number of self-diffusion processes on perfect and imperfect Au(100 surfaces. The obtained structural and energetic information served as basis for optimizing a reactive forcefield (here ReaxFF, which afterwards was used to address the mesoscopic scale. Reactive force field simulations were performed to investigate more diffusion possibilities at a lower computational cost but with similar accuracy. Finally, we reached the macroscale by means of kinetic Monte Carlo (kMC simulations. The reaction rates for the reaction process database used in the kMC simulations were generated using the reactive force field. Using this strategy, we simulated nucleation, aggregation, and fluctuation processes for monoatomic high islands on Au(100 and modeled their equilibrium shape structures. Finally, by calculating the step line tension at different temperatures, we were able to make a direct comparison with available experimental data.

  15. Relative Distribution of Au48+ ~ Au52+ in Au Plasma by Ionization Dynamics

    Institute of Scientific and Technical Information of China (English)

    ZHU Zhi-Yan; ZHU Zheng-He; JIANG Gang

    2003-01-01

    The present work proposes a theoretical method called ionization dynamics to derive the ionic charge state distribution. Using relativistic quantum mechanics to calculate the energy level lifetime and average ionic lifetime of each ion, the first-order ionization rate constant can be obtained. Based on these data, from the solution of differential equations for consecutive-irreversible ionization reactions, one will be able to derive the ionic charge state distribution.The calculated average positive charge 49.24 of Au48+ ~ Au52+ and their relative distribution are in good agreement with the results of Lawrence Livermore National Laboratory.

  16. AU Political Solution in Libya

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    May 3,2011 The African Union(AU),through its High-Level ad hoc Committee on the Situation in Libya and the Commission, is driven by the conviction that, ultimately,only a political solution will make it possible to promote,in a sustainable way,the legitimate aspira-

  17. Global polarization measurement in Au+Au collisions

    CERN Document Server

    Abelev, B I; Ahammed, Z; Anderson, B D; Arkhipkin, D; Averichev, G S; Bai, Y; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Baumgart, S; Belaga, V V; Bellingeri-Laurikainen, A; Bellwied, R; Benedosso, F; Betts, R R; Bhardwaj, S; Bhasin, A; Bhati, A K; Bichsel, H; Bielcik, J; Bielcikova, J; Bland, L C; Blyth, S L; Bombara, M; Bonner, B E; Botje, M; Bouchet, J; Brandin, A V; Bravar, A; Burton, T P; Bystersky, M; Cai, X Z; Caines, H; Calderón de la Barca-Sanchez, M; Callner, J; Catu, O; Cebra, D; Chajecki, Z; Chaloupka, P; Chattopadhyay, S; Chen, H F; Chen, J H; Chen, J Y; Cheng, J; Cherney, M; Chikanian, A; Christie, W; Chung, S U; Coffin, J P; Cormier, T M; Cosentino, M R; Cramer, J G; Crawford, H J; Das, D; Dash, S; Daugherity, M; De Moura, M M; Dedovich, T G; De Phillips, M; Derevshchikov, A A; Didenko, L; Dietel, T; Djawotho, P; Dogra, S M; Dong, X; Drachenberg, J L; Draper, J E; Du, F; Dunin, V B; Dunlop, J C; Dutta-Majumdar, M R; Eckardt, V; Edwards, W R; Efimov, L G; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Estienne, M; Fachini, P; Fatemi, R; Fedorisin, J; Feng, A; Filip, P; Finch, E; Fine, V; Fisyak, Yu; Fu, J; Gagliardi, C A; Gaillard, L; Ganti, M S; García-Solis, E; Ghazikhanian, V; Ghosh, P; Gorbunov, Y N; Gos, H; Grebenyuk, O; Grosnick, D; Grube, B; Guertin, S M; Guimaraes, K S F F; Gupta, N; Haag, B; Hallman, T J; Hamed, A; Harris, J W; He, W; Heinz, M; Henry, T W; Heppelmann, S; Hippolyte, B; Hirsch, A; Hjort, E; Hoffman, A M; Hoffmann, G W; Hofman, D J; Hollis, R S; Horner, M J; Huang, H Z; Hughes, E W; Humanic, T J; Igo, G; Iordanova, A; Jacobs, P; Jacobs, W W; Jakl, P; Jia, F; Jones, P G; Judd, E G; Kabana, S; Kang, K; Kapitan, J; Kaplan, M; Keane, D; Kechechyan, A; Kettler, D; Khodyrev, V Yu; Kiryluk, J; Kisiel, A; Kislov, E M; Klein, S R; Knospe, A G; Kocoloski, A; Koetke, D D; Kollegger, T; Kopytine, M; Kotchenda, L; Kouchpil, V; Kowalik, K L; Kravtsov, P; Kravtsov, V I; Krüger, K; Kuhn, C; Kulikov, A I; Kumar, A; Kurnadi, P; Kuznetsov, A A; Lamont, M A C; Landgraf, J M; Lange, S; La Pointe, S; Laue, F; Lauret, J; Lebedev, A; Lednicky, R; Lee, C H; Lehocka, S; Le Vine, M J; Li, C; Li, Q; Li, Y; Lin, G; Lin, X; Lindenbaum, S J; Lisa, M A; Liu, F; Liu, H; Liu, J; Liu, L; Ljubicic, T; Llope, W J; Longacre, R S; Love, W A; Lu, Y; Ludlam, T; Lynn, D; Ma, G L; Ma, J G; Ma, Y G; Mahapatra, D P; Majka, R; Mangotra, L K; Manweiler, R; Margetis, S; Markert, C; Martin, L; Matis, H S; Matulenko, Yu A; McClain, C J; McShane, T S; Melnik, Yu M; Meschanin, A; Millane, J; Miller, M L; Minaev, N G; Mioduszewski, S; Mischke, A; Mitchell, J; Mohanty, B; Morozov, D A; Munhoz, M G; Nandi, B K; Nattrass, C; Nayak, T K; Nelson, J M; Nepali, C; Netrakanti, P K; Nogach, L V; Nurushev, S B; Odyniec, Grazyna Janina; Ogawa, A; Okorokov, V; Oldenburg, M; Olson, D; Pachr, M; Pal, S K; Panebratsev, Yu A; Pavlinov, A I; Pawlak, T; Peitzmann, T; Perevozchikov, V; Perkins, C; Peryt, W; Phatak, S C; Planinic, M; Pluta, J; Poljak, N; Porile, N; Poskanzer, A M; Potekhin, M V; Potrebenikova, E V; Potukuchi, B V K S; Prindle, D; Pruneau, C; Putschke, J; Qattan, I A; Raniwala, R; Raniwala, S; Ray, R L; Relyea, D; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevski, O V; Romero, J L; Rose, A; Roy, C; Ruan, L; Russcher, M J; Sahoo, R; Sakrejda, I; Sakuma, T; Salur, S; Sandweiss, J; Sarsour, M; Sazhin, P S; Schambach, J; Scharenberg, R P; Schmitz, N; Seger, J; Selyuzhenkov, I; Seyboth, P; Shabetai, A; Shahaliev, E; Shao, M; Sharma, M; Shen, W Q; Shimansky, S S; Sichtermann, E P; Simon, F; Singaraju, R N; Smirnov, N; Snellings, R; Sørensen, P; Sowinski, J; Speltz, J; Spinka, H M; Srivastava, B; Stadnik, A; Stanislaus, T D S; Staszak, D; Stock, R; Strikhanov, M N; Stringfellow, B C; Suaide, A A P; Suarez, M C; Subba, N L; Sumbera, M; Sun, X M; Sun, Z; Surrow, B; Symons, T J M; Szanto de Toledo, A; Takahashi, J; Tang, A H; Tarnowsky, T J; Thomas, J H; Timmins, A R; Timoshenko, S; Tokarev, M; Trainor, T A; Trentalange, S; Tribble, R E; Tsai, O D; Ulery, J; Ullrich, T; Underwood, D G; Van Buren, G; Van der Kolk, N; Van Leeuwen, M; Van der Molen, A M; Varma, R; Vasilevski, I M; Vasilev, A N; Vernet, R; Vigdor, S E; Viyogi, Y P; Vokal, S; Voloshin, S A; Wada, M; Waggoner, W T; Wang, F; Wang, G; Wang, J S; Wang, X L; Wang, Y; Webb, J C; Westfall, G D; Whitten, C; Wieman, H; Wissink, S W; Witt, R; Wu, J; Wu, Y; Xu, N; Xu, Q H; Xu, Z; Yepes, P; Yoo, I K; Yue, Q; Yurevich, V I; Zawisza, M; Zhan, W; Zhang, H; Zhang, W M; Zhang, Y; Zhang, Z P; Zhao, Y; Zhong, C; Zhou, J; Zoulkarneev, R; Zoulkarneeva, Y; Zubarev, A N; Zuo, J X

    2007-01-01

    The system created in non-central relativistic nucleus-nucleus collisions possesses large orbital angular momentum. Due to spin-orbit coupling, particles produced in such a system could become globally polarized along the direction of the system angular momentum. We present the results of Lambda and anti-Lambda hyperon global polarization measurements in Au+Au collisions at sqrt{s_NN}=62.4 GeV and 200 GeV performed with the STAR detector at RHIC. The observed global polarization of Lambda and anti-Lambda hyperons in the STAR acceptance is consistent with zero within the precision of the measurements. The obtained upper limit, |P_{Lambda,anti-Lambda}| <= 0.02, is compared to the theoretical values discussed recently in the literature.

  18. Onset of nuclear matter expansion in Au+Au collisions

    CERN Document Server

    Crochet, Philippe; Gobbi, A; Donà, R; Coffin, J P; Fintz, P; Guillaume, G; Jundt, F; Kühn, C E; Roy, C; De Schauenburg, B; Tizniti, L; Wagner, P; Alard, J P; Amouroux, V; Andronic, A; Basrak, Z; Bastid, N; Belyaev, I; Best, D; Biegansky, J; Butà, A; Caplar, R; Cindro, N; Dupieux, P; Dzelalija, M; Fan, Z G; Fodor, Z; Fraysse, L; Freifelder, R P; Herrmann, N; Hildenbrand, K D; Hong, B H; Jeong, S C; Kecskeméti, J; Kirejczyk, M; Koncz, P; Korolija, M; Kotte, R; Lebedev, A; Leifels, Y; Man'ko, V I; Moisa, D; Mösner, J; Neubert, W; Pelte, D; Petrovici, M; Pinkenburg, C H; Pras, P; Ramillien, V; Reisdorf, W; Ritman, J L; Sadchikov, A G; Schüll, D; Seres, Z; Sikora, B; Simion, V; Siwek-Wilczynska, K; Sodan, U; Teh, K M; Trzaska, M; Vasilev, M A; Wang, G S; Wessels, J P; Wienold, T; Wisniewski, K; Wohlfarth, D; Zhilin, A V

    1997-01-01

    Using the FOPI detector at GSI Darmstadt, excitation functions of collective flow components were measured for the Au+Au system, in the reaction plane and out of this plane, at seven incident energies ranging from 100AMeV to 800AMeV. The threshold energies, corresponding to the onset of sideward-flow (balance energy) and squeeze-out effect (transition energy), are extracted from extrapolations of these excitation functions toward lower beam energies for charged products with Z>2. The transition energy is found to be larger than the balance energy. The impact parameter dependence of both balance and transition energies, when extrapolated to central collisions, suggests comparable although slightly higher values than the threshold energy for the radial flow. The relevant parameter seems to be the energy deposited into the system in order to overcome the attractive nuclear forces.

  19. Charge fluctuations in Au+Au collisions at RHIC energy

    Institute of Scientific and Technical Information of China (English)

    CAI; Xu(蔡勖); ZHOU; Daimei(周代梅); SA; Benhao(萨本豪)

    2003-01-01

    A hadron and string cascade model, JPCIAE, together with the corresponding Monte Carlo eventgenerator, has been employed in this paper to investigate further the charge fluctuations in Au+Au collisions at√Snn= 130 GeV. The default JPCIAE calculations are in good agreement with PHENIX and STAR data. Wefound that the thermal predictions for the π gas, the resonance π gas and quark matter deviate, respectively,from the corresponding dynamical simulations from the JPCIAE model. The discrepancies were also foundbetween the π charge fluctuations and the charge fluctuations of all species of hadrons. However the chargefluctuations for "π from ρ and ω decay" and for all the hadrons from resonance decay are close to each other,indicating the correlation between positively and negatively charged hadrons is not sensitive to the species ofhadrons. This work shows further that it is questionable to use the charge fluctuations as a signature of QGP.

  20. Nuclear Modification of Jet Fragmentation in Au+Au Collisions

    Science.gov (United States)

    Rowan, Zachary; Phenix Collaboration

    2015-10-01

    The characterization of energy in the quark gluon plasma is facilitated by measurements of modifications to the observed jet fragmentation. A favorable channel of study relies on direct photons created in the initial parton interactions of heavy ion collisions. Such a photon traverses the created medium unscathed and grants us a proxy for the transverse momentum of an away side jet. PHENIX Au+Au data recorded at √{sNN} = 200 GeV during RHIC run 14 benefit from the background rejection capability of the silicon vertex detector, enabling the extraction of a higher purity hadron signal. This advantage, combined with a larger integrated luminosity, allows previous PHENIX measurements of fragmentation functions to be extended to greater jet energies. In this talk, the status of the analysis of direct photon hadron correlations with the new data set will be discussed.

  1. Decay spectroscopy of $^{178}$Au

    CERN Document Server

    Whitmore, B

    In this thesis, the neutron-deficient nucleus $^{178}$Au is investigated through decay spectroscopy. Si and HPGe detectors were used to analyse the decay radiation of $^{178}$Au and its daughter nuclei. Previous studies have been unable to distinguish decay radiation from different isomeric states of this nucleus. This thesis represents the first time such isomeric discrimination has been achieved, and presents tentative spin assignments of both the ground state and an isomer. The neutron-deficient gold isotopes are an area of interest for the study of shape coexistence. This is the phenomenon exhibited by nuclei able to exist at a number of close lying energy minima, each reflecting a distinct type of deformation. It is hoped that studies such as this can help identify the evolution of nuclear deformation in this region of the nuclear chart.

  2. Introduction au filtre de Kalman

    OpenAIRE

    Alazard, Daniel

    2006-01-01

    Ce document est une introduction au filtre optimal de Kalman appliquée aux systèmes linéaires. On suppose connues la théorie des asservissements linéaires et du filtrage fréquentiel (continu et discret) ainsi que les notions d'états pour représenter les systèmes dynamiques linéaires.

  3. L’apprentissage au CERN

    CERN Multimedia

    Staff Association

    2016-01-01

    En 1961, sur la base du constat que l’évolution du marché du travail nécessitait un besoin croissant de personnel qualifié, le 1er accord entre la République et canton de Genève et le CERN fut signé. Cet accord avait notamment pour objet la formation professionnelle de jeunes électroniciens et techniciens de laboratoires en physique. Le CERN, acteur local économique d’importance, soulignait par cet accord sa volonté de participer au développement économique et social local. Le 1er apprenti arriva au CERN en 1965. En 1971, le centre d’apprentissage fut créé ; il accueille aujourd’hui plus d’une vingtaine d’apprentis au total, à raison d’environ six nouveaux apprentis chaque année. Cet apprentissage est dédié aux jeunes âgés e...

  4. Fabricating a Homogeneously Alloyed AuAg Shell on Au Nanorods to Achieve Strong, Stable, and Tunable Surface Plasmon Resonances

    KAUST Repository

    Huang, Jianfeng

    2015-08-13

    Colloidal metal nanocrystals with strong, stable, and tunable localized surface plasmon resonances (SPRs) can be useful in a corrosive environment for many applications including field-enhanced spectroscopies, plasmon-mediated catalysis, etc. Here, a new synthetic strategy is reported that enables the epitaxial growth of a homogeneously alloyed AuAg shell on Au nanorod seeds, circumventing the phase segregation of Au and Ag encountered in conventional synthesis. The resulting core–shell structured bimetallic nanorods (AuNR@AuAg) have well-mixed Au and Ag atoms in their shell without discernible domains. This degree of mixing allows AuNR@AuAg to combine the high stability of Au with the superior plasmonic activity of Ag, thus outperforming seemingly similar nanostructures with monometallic shells (e.g., Ag-coated Au NRs (AuNR@Ag) and Au-coated Au NRs (AuNR@Au)). AuNR@AuAg is comparable to AuNR@Ag in plasmonic activity, but that it is markedly more stable toward oxidative treatment. Specifically, AuNR@AuAg and AuNR@Ag exhibit similarly strong signals in surface-enhanced Raman spectroscopy that are some 30-fold higher than that of AuNR@Au. When incubated with a H2O2 solution (0.5 m), the plasmonic activity of AuNR@Ag immediately and severely decayed, whereas AuNR@AuAg retained its activity intact. Moreover, the longitudinal SPR frequency of AuNR@AuAg can be tuned throughout the red wavelengths (≈620–690 nm) by controlling the thickness of the AuAg alloy shell. The synthetic strategy is versatile to fabricate AuAg alloyed shells on different shaped Au, with prospects for new possibilities in the synthesis and application of plasmonic nanocrystals.

  5. Initial state geometry and fluctuations in Au+Au, Cu+Au and U+U collisions at RHIC

    OpenAIRE

    Schenke, Bjoern; Tribedy, Prithwish; Venugopalan, Raju

    2014-01-01

    We study within the IP-Glasma and two-component MC-Glauber models the effects of initial state geometry and fluctuations on multiplicities and eccentricities for several collision species at the Relativistic Heavy Ion Collider (RHIC). These include copper-gold (Cu+Au), gold-gold (Au+Au), and uranium-uranium (U+U) collisions. The multiplicity densities per participant pair are very similar in all systems studied. Ellipticities vary strongly between collision systems, most significantly for cen...

  6. Predicted Habitat Suitability for Leptoseris in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This raster denotes predicted habitat suitability for Leptoseris in the Au'au Channel region. Maximum Entropy (MaxEnt) modeling software was used to create this...

  7. Predicted Habitat Suitability for Montipora Corals in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This raster denotes predicted habitat suitability for Montipora in the Au'au Channel region. Maximum Entropy (MaxEnt) modeling software was used to create this...

  8. Predicted Habitat Suitability for Leptoseris Corals in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This raster denotes predicted habitat suitability for Leptoseris in the Au'au Channel region. Maximum Entropy (MaxEnt) modeling software was used to create this...

  9. Predicted Habitat Suitability for Porites Corals in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This raster denotes predicted habitat suitability for Porites in the Au'au Channel region. Maximum Entropy (MaxEnt) modeling software was used to create this...

  10. Predicted Habitat Suitability for All Mesophotic Corals in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This dataset is located between the islands of Maui, Lanai, Molokai and Kahoolawe, and includes the Au'au Channel as well as parts of the Kealaikahiki, Alalakeiki...

  11. Predicted Habitat Suitability for Porites in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This raster denotes predicted habitat suitability for Porites in the Au'au Channel region. Maximum Entropy (MaxEnt) modeling software was used to create this...

  12. Predicted Habitat Suitability for All Mesophotic Corals in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This raster denotes predicted habitat suitability for all mesophotic corals in the Au'au Channel region. Maximum Entropy (MaxEnt) modeling software was used to...

  13. A Study of Parton Energy Loss in Au+Au Collisions at RHIC using Transport Theory

    OpenAIRE

    Nara, Y.; Vance, S. E.; Csizmadia, P.

    2001-01-01

    Parton energy loss in Au+Au collisions at RHIC energies is studied by numerically solving the relativistic Boltzmann equation for the partons including $2 \\leftrightarrow 2$ and $2 \\to 2 + final state radiation$ collision processes. Final particle spectra are obtained using two hadronization models; the Lund string fragmentation and independent fragmentation models. Recent, preliminary $\\pi^0$ transverse momentum distributions from central Au+Au collisions at RHIC are reproduced using gluon-g...

  14. Bright, NIR-emitting Au23 from Au25: characterization and applications including biolabeling.

    Science.gov (United States)

    Muhammed, Madathumpady Abubaker Habeeb; Verma, Pramod Kumar; Pal, Samir Kumar; Kumar, R C Arun; Paul, Soumya; Omkumar, Ramakrishnapillai Vyomakesannair; Pradeep, Thalappil

    2009-10-01

    A novel interfacial route has been developed for the synthesis of a bright-red-emitting new subnanocluster, Au(23), by the core etching of a widely explored and more stable cluster, Au(25)SG(18) (in which SG is glutathione thiolate). A slight modification of this procedure results in the formation of two other known subnanoclusters, Au(22) and Au(33). Whereas Au(22) and Au(23) are water soluble and brightly fluorescent with quantum yields of 2.5 and 1.3 %, respectively, Au(33) is organic soluble and less fluorescent, with a quantum yield of 0.1 %. Au(23) exhibits quenching of fluorescence selectively in the presence of Cu(2+) ions and it can therefore be used as a metal-ion sensor. Aqueous- to organic-phase transfer of Au(23) has been carried out with fluorescence enhancement. Solvent dependency on the fluorescence of Au(23) before and after phase transfer has been studied extensively and the quantum yield of the cluster varies with the solvent used. The temperature response of Au(23) emission has been demonstrated. The inherent fluorescence of Au(23) was used for imaging human hepatoma cells by employing the avidin-biotin interaction. PMID:19711391

  15. Initial state geometry and fluctuations in Au+Au, Cu+Au and U+U collisions at RHIC

    CERN Document Server

    Schenke, Bjoern; Venugopalan, Raju

    2014-01-01

    We study within the IP-Glasma and two-component MC-Glauber models the effects of initial state geometry and fluctuations on multiplicities and eccentricities for several collision species at the Relativistic Heavy Ion Collider (RHIC). These include copper-gold (Cu+Au), gold-gold (Au+Au), and uranium-uranium (U+U) collisions. The multiplicity densities per participant pair are very similar in all systems studied. Ellipticities vary strongly between collision systems, most significantly for central collisions, while fluctuation driven odd moments vary little between systems. Event-by-event distributions of eccentricities in mid-central collisions are wider in Cu+Au relative to Au+Au and U+U systems. An anti-correlation between multiplicity and eccentricity is observed in ultra central U+U collisions which is weaker in the IP-Glasma model than the two-component MC-Glauber model. In ultra central Au+Au collisions the two models predict opposite signs for the slope of this correlation. Measurements of elliptic flo...

  16. L’olivier au Maroc

    Directory of Open Access Journals (Sweden)

    El Mouhtadi Issam

    2014-03-01

    Full Text Available L’olivier est une culture traditionnelle sur le pourtour de la Méditerranée. Il est donc naturel de trouver cet arbre au Maroc où il est présent depuis des siècles. Cultivé surtout traditionnellement jusqu’à ses dernières années, il fait l’objet maintenant d’un plan de valorisation très ambitieux pour non seulement garder le Royaume à son niveau actuel (2e producteur mondial pour l’olive de conserve et 6e pour l’huile d’olive mais pour conquérir de nouveaux marchés au niveau mondial et profiter ainsi de l’engouement que connaît cette huile reconnue pour ses bienfaits. Le plan national « Maroc Vert » permet ainsi, grâce à des subventions conséquentes, non seulement de renouveler les vergers existant avec la variété traditionnelle picholine du Maroc, mais également la plantation de nouvelles variétés en super-intensif dans le but d’industrialiser au maximum de nouveaux vergers. Il en est de même pour la transformation des olives en huile de bonne qualité avec la mise en place d’unités de trituration modernes qui doivent supplanter à terme la multitude de « maâsra » et réduire ainsi l’impact environnemental dû aux margines. L’olive ne sera plus dans l’avenir que représentée par son huile et ses formes comestibles, mais les résidus de son extraction seront valorisés soit sous forme de combustible élaboré pour le grignon, soit sous forme d’une base de chimie verte pour les sous-produits du raffinage. D’autres applications sont actuellement à l’étude, car le Maroc à compris, comme tous les autres grands pays producteurs, que l’olive était un nouveau gisement de richesses.

  17. Study of Au+Au relativistic collisions with the Fopi-Phase I detector; Etude des collisions relativistes Au+Au avec le detecteur Fopi-Phase I

    Energy Technology Data Exchange (ETDEWEB)

    Dupieux, P.

    1995-01-01

    Au+Au relativistic collisions, in a 100-1000 MeV energy domain per nucleon, are described. Experiments have been carried out with the SIS accelerator at GSI/Darmstadt. Data are analysed with the FOPI-phase I detector. These data are compared with IQMD model (Isospin Quantum Molecular Dynamics) Predictions. (S.G). 80 refs., 77 figs., 5 tabs.

  18. English for au pairs the au pair's guide to learning English

    CERN Document Server

    Curtis, Lucy

    2014-01-01

    English for Au Pairs has interlinked stories about a group of au pairs new to England. Marta, an 18-year-old from Poland arrives in the UK to work as an au pair. Throughout her year-long stay she has many different experiences - some bad, some good - but with the support of her host family she finds new friends and improves her English. English for Au Pairs offers insight into the joys and difficulties of being an au pair while at the same time reinforcing English language learning through grammar explanations and exercises.

  19. Characteristic atom occupation patterns of Au3Cu, AuCu3, AuCuⅠ and AuCuⅡ based on experimental data of disordered alloys%以无序合金的实验数据为基础的Au3Cu,AuCu3,AuCuⅠ和AuCuⅡ的特征原子占据图

    Institute of Scientific and Technical Information of China (English)

    谢佑卿; 李艳芬; 刘心笔; 李晓波; 彭红建; 聂耀庄

    2011-01-01

    根据无序Au1-xCux合金的实验生成热和晶格常数得到只考虑近邻原子组态的特征原子的势能、体积和电子结构,计算L12-Au3Cu,L12-AuCu3和L10-AuCu化合物的特征原子占据(CAO)图、电子结构、能量和体积性质.Johasson-Linde(J-L)模型的CAO图表明,AuCuⅠ-AuCuⅡ转变是一个放热且体积缩小的反应,但正好与实验现象相反.根据Guymont-Feutelais-Legendre(G-F-L)模型的CAO图,AuCuⅡ晶胞由两个周期反相(PAD)的AuCuⅠ区域和两个PAD边界区域组成;从G-F-L模型的CAO图得出的公式可用来计算PAD AuCuⅠ区域和PAD边界区域的能量性质、体积性质和有序度及AuCuⅡ相的平均性质,计算结果与实验现象相吻合.%The potential energies, volumes and electronic structures of characteristic atoms coordinated by neighboring configurations were obtained from the experimental heats of formation and lattice parameters of disordered Au1-xCux alloys. From characteristic atom occupation (CAO) patterns of L12-Au3Cu, L12-AuCu3 and L10-AuCu compounds, their electronic structures, volumetric and energetic properties were calculated. The CAO pattern of Johasson-Linde(J-L) model shows that the transition AuCuⅠ→ AuCuⅡ is an exothermic and volume contraction reaction, which is opposite from experimental phenomena. According to CAO pattern of Guymont-Feutelais-Legendre(G-F-L) model, the AuCuⅡ cell consists of two periodic antidirection (PAD) AuCuⅠ regions and two PAD boundary regions. The equations derived from CAO pattern of G-F-L model can be used to calculate energetic properties, volumetric properties and ordering degrees of the PAD AuCul region and PAD boundary region, as well as corresponding average properties of the AuCuⅡ phase. The results are consistent with experimental phenomena.

  20. AU-EU “Strategic Partnership”

    DEFF Research Database (Denmark)

    Rodt, Annemarie Peen; Okeke, Jide

    2013-01-01

    This article appraises strategic partnership between the African Union (AU) and European Union (EU). It examines the context and nature of AU and EU security relations and explores the conditions under which partnership has a positive impact in this regard. This includes an evaluation of converge......This article appraises strategic partnership between the African Union (AU) and European Union (EU). It examines the context and nature of AU and EU security relations and explores the conditions under which partnership has a positive impact in this regard. This includes an evaluation...... of convergence between the two organizations and its effect or lack thereof on African security. The article concludes that events leading up to and initiatives following the 2007 Joint Africa–European Union Strategy have produced a degree of AU and EU convergence, which has had limited impact on the efficacy...

  1. Le curriculum scolaire au Chili

    OpenAIRE

    Cox, Cristián

    2012-01-01

    L’article examine l’usage historique du terme « curriculum » au Chili. Il aborde la configuration actuelle de la prescription curriculaire nationale : des « objectifs et contenus minimums », des « programmes d’études », et des « cartes de progrès des apprentissages ». On y décrit les institutions et les processus qui rendent compte de la genèse des définitions curriculaires en vigueur en 2010. Elles sont le résultat de deux étapes de réformes caractérisées par des processus consultatifs et pa...

  2. Portraits de femmes au Biafra

    OpenAIRE

    Ugochukwu, Françoise

    2011-01-01

    Cette étude considère l’impact de la guerre civile nigériane sur la vie quotidienne et les relations interpersonnelles des Biafrais telle qu’elle est présentée dans Femmes en guerre et autres nouvelles d’Achebe et Blow the Fire de Leslie Ofoegbu. Ces deux écrivains, dont l’un, déjà traduit dans plusieurs langues, a été le premier à projeter le pays igbo sur la scène internationale, et dont l’autre est une Écossaise mariée à un Nigérian et qui vécut au Biafra pendant les années de guerre, offr...

  3. Strain distributions of confined Au/Ag and Ag/Au nanoparticles

    Institute of Scientific and Technical Information of China (English)

    黄红华; 章英; 刘晓山; 骆兴芳; 袁彩雷; 叶双莉

    2015-01-01

    The strain distributions of Au/Ag and Ag/Au nanoparticles confined in the Al2O3 matrix with different core sizes are investigated by using the finite element method, respectively. The simulation results clearly indicate that the compressive strains exerted on the Au/Ag and Ag/Au nanoparticles can be induced by the Al2O3 matrix. Moreover, it can be found that the strain gradient existing in a Au/Ag nanoparticle is much larger than that in a Ag/Au nanoparticle, which could be due to the larger Young’s modulus of Au than that of Ag. With the core size increasing, the strain gradient existing in the Au/Ag nanoparticle becomes larger, while the strain gradient existing in the Ag/Au nanoparticle keeps constant. These different strain distributions may have significant infl uences on the structures and morphologies of the Au/Ag and Ag/Au nanoparticles, leading to the different physical properties for potential applications.

  4. Enhanced activity for supported Au clusters: Methanol oxidation on Au/TiO2(110)

    Science.gov (United States)

    Tenney, Samuel A.; Cagg, Brett A.; Levine, Mara S.; He, Wei; Manandhar, Kedar; Chen, Donna A.

    2012-08-01

    Gold clusters supported on TiO2(110) exhibit unusual activity for the oxidation of methanol to formaldehyde. Temperature programmed desorption studies of methanol on Au clusters show that both Au and titania sites are necessary for methanol reaction. Isotopic labeling experiments with CD3OH demonstrate that reaction occurs via Osbnd H bond scission to form a methoxy intermediate. When the TiO2 surface is oxidized with 18O2 before or after Au deposition, methanol reaction produces H218O below 300 K, indicating that oxygen from titania promotes Osbnd H bond scission and is incorporated into desorbing products. XPS experiments provide additional evidence that during methanol reaction on the Au/TiO2 surface, methanol adsorption occurs on TiO2, given that the titania support becomes slightly oxidized after exposure to methanol in the presence of Au clusters. While the role of TiO2 is to dissociate the Osbnd H bond and form the reactive methoxy intermediate, the role of the Au sites is to remove hydrogen from the surface as H2, thus preventing the recombination of methoxy and hydrogen to methanol. The decrease in formaldehyde yield with increasing Au coverage above 0.25 ML suggests that reaction occurs at Au-titania interfacial sites; scanning tunneling microscopy images of various Au coverages confirm that the number of interfacial sites at the perimeter of the Au clusters decreases as the Au coverage is increased between 0.25 and 5 ML.

  5. Au, Ag and Au:Ag colloidal nanoparticles synthesized by pulsed laser ablation as SERS substrates

    Directory of Open Access Journals (Sweden)

    M. Vinod

    2014-12-01

    Full Text Available Chemically pure colloidal suspensions of gold and silver nanoparticles were synthesized using pulsed laser ablation. The dependence of laser fluence on the surface plasmon characteristics of the nanoparticles was investigated. Au:Ag colloidal suspensions were prepared by mixing highly monodisperse Au and Ag nanocolloids. The plasmon band of these mixtures was found to be highly sensitive to Au:Ag concentration ratio and wavelength of the laser beam used in the ablation process. The Au:Ag mixture consists of almost spherical shaped nanostructures with a tendency to join with adjacent ones. The surface enhanced Raman scattering activity of the Au, Ag and Au:Ag colloidal suspensions was tested using crystal violet as probe molecules. Enhancement in Raman signal obtained with Au:Ag substrates was found to be promising and strongly depends on its plasmon characteristics.

  6. Au, Ag and Au:Ag colloidal nanoparticles synthesized by pulsed laser ablation as SERS substrates

    Institute of Scientific and Technical Information of China (English)

    M. Vinod; K.G.Gopchandran

    2014-01-01

    Chemically pure colloidal suspensions of gold and silver nanoparticles were synthesized using pulsed laser ablation. The dependence of laser fluence on the surface plasmon characteristics of the nanoparticles was investigated. Au:Ag colloidal suspensions were prepared by mixing highly monodisperse Au and Ag nanocolloids. The plasmon band of these mixtures was found to be highly sensitive to Au:Ag concentration ratio and wavelength of the laser beam used in the ablation process. The Au:Ag mixture consists of almost spherical shaped nanostructures with a tendency to join with adjacent ones. The surface enhanced Raman scattering activity of the Au, Ag and Au:Ag colloidal suspensions was tested using crystal violet as probe molecules. Enhancement in Raman signal obtained with Au:Ag substrates was found to be promising and strongly depends on its plasmon characteristics.

  7. Investigation of the Phase Equilibria of Sn-Cu-Au Ternary and Ag-Sn-Cu-Au Quaternary Systems and Interfacial Reactions in Sn-Cu/Au Couples

    Science.gov (United States)

    Yen, Yee-Wen; Jao, Chien-Chung; Hsiao, Hsien-Ming; Lin, Chung-Yung; Lee, Chiapyng

    2007-02-01

    The phase equilibria of the Sn-Cu-Au ternary, Ag-Sn-Cu-Au quaternary systems and interfacial reactions between Sn-Cu alloys and Au were experimentally investigated at specific temperatures in this study. The experimental results indicated that there existed three ternary intermetallic compounds (IMCs) and a complete solid solubility between AuSn and Cu6Sn5 phases in the Sn-Cu-Au ternary system at 200°C. No quaternary IMC was found in the isoplethal section of the Ag-Sn-Cu-Au quaternary system. Three IMCs, AuSn, AuSn2, and AuSn4, were found in all couples. The same three IMCs and (Au,Cu)Sn/(Cu,Au)6Sn5 phases were found in all Sn-Cu/Au couples. The thickness of these reaction layers increased with increasing temperature and time. The mechanism of IMC growth can be described by using the parabolic law. In addition, when the reaction time was extended and the Cu content of the alloy was increased, the AuSn4 phase disappeared gradually. The (Au, Cu)Sn and (Cu,Au)6Sn5 layers played roles as diffusion barriers against Sn in Sn-Cu/Au reaction couple systems.

  8. Controlled Synthesis of Au@AgAu Yolk-Shell Cuboctahedra with Well-Defined Facets.

    Science.gov (United States)

    Londono-Calderon, Alejandra; Bahena, Daniel; Yacaman, Miguel J

    2016-08-01

    The synthesis of Au@AgAu yolk-shell cuboctahedra nanoparticles formed by galvanic replacement in a seed-mediated method is described. Initially, single-crystal Au seeds are used for the formation of Au@Ag core-shell nanocubes, which serve as the template material for the deposition of an external Au layer. The well-controlled synthesis yields the formation of cuboctahedra nanoparticles with smooth inner and outer Au/Ag surfaces. The deposition/oxidation process is described to understand the formation of cuboctahedra and octahedra nanoparticles. The Au core maintains the initial morphology of the seed and remains static at the center of the yolk-shell because of residual Ag. Structural analysis of the shell indicates intrinsic stacking faults (SFs) near the surface. Energy dispersive X-ray spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS) compositional analysis show an Au-Ag nonordered alloy forming the shell. The three-dimensional structure of the nanoparticles presented open facets on the [111] as observed by electron tomography SIRT reconstruction over a stack of high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) images. The geometrical model was validated by analyzing the direction of streaks in coherent nanobeam diffraction (NBD). The catalytic activity was evaluated using a model reaction based on the reduction of 4-nitrophenol (4-NTP) by NaBH4 in the presence of Au@AgAu yolk-shell nanoparticles. PMID:27385583

  9. Thermodynamic assessment of Au-La and Au-Er binary systems

    Energy Technology Data Exchange (ETDEWEB)

    Dong, H.Q., E-mail: hongqun.dong@aalto.fi [Department of Electronics, Aalto University School of Science and Technology, FIN-02601 Espoo (Finland); Tao, X.M. [Key Laboratory of New Processing Technology for Nonferrous Metals and Materials of Ministry of Education, Department of Physics, Guangxi University, Nanning 530004 (China); Liu, H.S. [Scientific Center of Phase Diagrams and Materials Design, Central South University, Changsha, Hunan 410083 (China); Laurila, T.; Paulastro-Kroeckel, M. [Department of Electronics, Aalto University School of Science and Technology, FIN-02601 Espoo (Finland)

    2011-03-31

    Research highlights: > It's the first time that Au-La and Au-Er binary systems were thermodynamically assessed since 1985. > Besides, in the present work, the ab initio approach has been employed to calculate the formation enthalpies of the IMCs involved in Au-Er and Au-La binary systems, and then, by combining with all of the available experimental information, these two-system were thermodynamically optimized via CALPHAD method. Therefore, a more reliable thermodynamic description has been obtained for these systems. - Abstract: Phase relationships in Au-La and Au-Er binary systems have been thermodynamically assessed by using the CALPHAD technique. The existing thermodynamic descriptions of the systems were improved by incorporating the ab initio calculated enthalpies of formation of the intermetallic compounds, except for the Au{sub 51}La{sub 14} and Au{sub 10}Er{sub 7} phases. All the binary intermetallic compounds were treated as stoichiometric phases, while the solution phases, including liquid, fcc, bcc, and dhcp, were treated as substitutional solution phases and the excess Gibbs energies were formulated with Redlich-Kister polynomial function. As a result, two self-consist thermodynamic data sets for describing the Au-La and Au-Er binary systems were obtained.

  10. Melanges pedagogiques 1989 (Pedagogical Mixtures 1989).

    Science.gov (United States)

    Centre de Recherches et d'Applications Pedagogiques en Langues, Nancy (France).

    Seven articles, presented in English or French, address aspects of second language instruction. (Articles written in English have an abstract in French and articles in French have an accompanying English abstract.) They include the following: "Bilan d'une experience de sensibilisation interculturelle pour enseignants" (Report of an Experiment in…

  11. Innovation et recomposition territoriale au Maroc

    OpenAIRE

    Boujrouf, Saïd

    2013-01-01

    Introduction Les processus de recomposition territoriale au Maroc se caractérisent par une dynamique continue, reflet des grands changements qui ont affecté les différents secteurs du pays au cours du xxe siècle. Le renouvellement territorial au Maroc est un processus de recomposition permanent, depuis les trames traditionnelles (qu’elles soient tribale, confessionnelle liée aux confréries ou encore « seigneuriale » caïdale) jusqu’aux maillages territoriaux les plus récents en communes et rég...

  12. Être notable au Maghreb

    OpenAIRE

    Abouhani, Abdelghani; Amri-Salameh, Nelly; Blili, Leïla; Boubrik, Rahal; Boujarra, Hussein; Cattedra, Raffaele; CATUSSE, Myriam; Cheraï, Ahmed; Ettayeb, Mahmoud; Feneyrol, Olivier; Hénia, Abdelhamid; Jaïdi, Houcine; Kenbib, Mohammed; Khouaja, Ahmed; Lafi, Nora

    2014-01-01

    Le discours dominant dans les pays du Maghreb continue de stigmatiser les figures de notables dits traditionnels au nom de la modernité. L’usage scientifique de la notion de notable n’est pas pour autant disqualifié. Le présent ouvrage s’intéresse au système élitaire au Maghreb sur la longue durée, de l’Antiquité à nos jours. Il en étudie la dynamique en rapport avec les formes historiques du pouvoir et montre comment la notabilité a pris avec le temps des figures changeantes et des nominatio...

  13. Becoming independent through au pair migration

    DEFF Research Database (Denmark)

    Dalgas, Karina Märcher

    2015-01-01

    . This article argues that, despite this critique, au pairing does play an important formative role for young Filipinas because it opens up for experiences abroad that enable them to be recognised as independent adults in Philippine society. Rather than autonomy, however, au pairs define their independence...... in terms of their capacity to assume responsibility for others, thereby achieving a position of social respect. Based on ethnographic fieldwork in Denmark and the Philippines, this article explores how young Filipinas use the social, economic, and cultural resources they gain from their au pair stay abroad...

  14. Synthesis of ultrathin face-centered-cubic Au@Pt and Au@Pd core-shell nanoplates from hexagonal-close-packed Au square sheets

    KAUST Repository

    Fan, Zhanxi

    2015-03-17

    The synthesis of ultrathin face-centered-cubic (fcc) Au@Pt rhombic nanoplates is reported through the epitaxial growth of Pt on hexagonal-close-packed (hcp) Au square sheets (AuSSs). The Pt-layer growth results in a hcp-to-fcc phase transformation of the AuSSs under ambient conditions. Interestingly, the obtained fcc Au@Pt rhombic nanoplates demonstrate a unique (101)f orientation with the same atomic arrangement extending from the Au core to the Pt shell. Importantly, this method can be extended to the epitaxial growth of Pd on hcp AuSSs, resulting in the unprecedented formation of fcc Au@Pd rhombic nanoplates with (101)f orientation. Additionally, a small amount of fcc (100)f-oriented Au@Pt and Au@Pd square nanoplates are obtained with the Au@Pt and Au@Pd rhombic nanoplates, respectively. We believe that these findings will shed new light on the synthesis of novel noble bimetallic nanostructures. Phase change: Ultrathin Au@Pt and Au@Pd core-shell nanoplates were prepared from Au square sheets. A phase transformation from hexagonal close-packed (hcp) to face-centered cubic (fcc) is observed upon coating the hcp Au square sheets with Pt or Pd under ambient conditions. The prepared fcc Au@Pt and Au@Pd rhombic nanoplates demonstrate unique (101)f orientation (picture shows a typical fcc Au@Pt rhombic nanoplate). © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Et pourquoi pas au CERN ?

    CERN Multimedia

    Staff Association

    2015-01-01

    Télétravail ou travail à distance, aménagement des horaires de travail et autres évolutions favorables à un meilleur équilibre vie privée et vie professionnelle sont adoptés par nombre d’entreprises et d’organisations !   Rendu possible grâce au développement de nouvelles technologies dont Internet, le travail à distance séduit de plus en plus de personnels, ainsi que de plus en plus de sociétés qui y trouvent des avantages en matière de gestion de l’espace, de sécurité (moins de trajets domicile-entreprise), de développement durable (moins de pollution), de motivation et de bien-être de leurs personnels. Les horaires aménagés, voire les « core-hours1 », sont également des pratiques de plus e...

  16. Longitudinal scaling of net-protons in AuAu and pp collisions at RHIC energies

    Science.gov (United States)

    Videbaek, Flemming

    2008-10-01

    BRAHMS has studied net-protons distributions in Au+Au and p+p collisions at √sNN=62.4 and 200 GeV. Net-proton distributions reflect the net-baryon yields and can be used to extract the nuclear stopping in the collisions, thus providing information on baryon number transport and energy available for particle production. The talk will present final and preliminary results from the above mentioned systems. It will be shown that in p+p and in Au+Au central collisions that net-proton distributions exhibit longitudinal scaling once the target contribution to the projectile rapidity range is corrected for. The difference between p+p and Au+Au will be discussed. Aspects of future measurements at the LHC of net-baryons at mid-rapidity will be brought forth.

  17. Studying of the photoluminescence characteristics of Au(0)@Au(I)-thiolate core–shell nanoclusters

    International Nuclear Information System (INIS)

    The photoluminescence characteristics of Au(0)@Au(I)-thiolate Core–shell nanoclusters (Au-NCs), whose size is <2 nm, are investigated. We use the time-resolved single-photon counting technique and the transient absorption technique to distinguish the mechanism of the photoluminescence of Au-NCs. The dynamic spectral data show that the photoluminescence mechanism should be composed of the fluorescence and the phosphorescence. Meanwhile, Au-NCs have the aggregation induced photoluminescence enhancement property, which is attributed to the suppression of conversion from the singlet state to triplet state when they aggregated together. In addition, the photoluminescence characteristics of aggregated Au-NCs should be further improved through infiltrating them into photonic crystals

  18. Charged hadron transverse momentum distributions in Au+Au collisions at S=200 GeV

    Science.gov (United States)

    Roland, Christof; PHOBOS Collaboration; Back, B. B.; Baker, M. D.; Barton, D. S.; Betts, R. R.; Ballintijn, M.; Bickley, A. A.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Decowski, M. P.; García, E.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Heintzelman, G. A.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Hołyński, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C. M.; Lin, W. T.; Manly, S.; McLeod, D.; Michałowski, J.; Mignerey, A. C.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Remsberg, L. P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Skulski, W.; Steadman, S. G.; Steinberg, P.; Stephans, G. S. F.; Stodulski, M.; Sukhanov, A.; Tang, J.-L.; Teng, R.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Verdier, R.; Wadsworth, B.; Wolfs, F. L. H.; Wosiek, B.; Woźniak, K.; Wuosmaa, A. H.; Wysłouch, B.

    2003-03-01

    We present transverse momentum distributions of charged hadrons produced in Au+Au collisions at sqrt(s_NN) = 200 GeV. The evolution of the spectra for transverse momenta p_T from 0.25 to 5GeV/c is studied as a function of collision centrality over a range from 65 to 344 participating nucleons. We find a significant change of the spectral shape between proton-antiproton and peripheral Au+Au collisions. Comparing peripheral to central Au+Au collisions, we find that the yields at the highest p_T exhibit approximate scaling with the number of participating nucleons, rather than scaling with the number of binary collisions.

  19. Electrical conduction through self-assembled monolayers in molecular junctions: Au/molecules/Au versus Au/molecule/PEDOT:PSS/Au

    International Nuclear Information System (INIS)

    We fabricated and characterized a large number of octanedithiol (denoted as DC8) molecular devices as vertical metal-molecule-metal structure with or without using an intermediate conducting polymer layer of poly (3,4-ethylenedioxythiophene) stabilized with poly(4-styenesulfonic acid) (called as PEDOT:PSS). The electronic transport properties of DC8 molecular devices with and without PEDOT:PSS layer were statistically compared in terms of current density and device yield. The yields of the working molecular devices were found to be ∼ 1.75% (84 out of 4800 devices) for Au/DC8/Au junctions and ∼ 58% (74 out of 128 devices) for Au-DC8/PEDOT:PSS/Au junctions. The tunneling decay constants were obtained with the Simmons tunneling model and a multibarrier tunneling model for two kinds of molecular devices with and without PEDOT:PSS layer.

  20. Proton channeling in Au at low energies

    International Nuclear Information System (INIS)

    The electronic energy loss for low velocity protons channeled in the direction single crystal Au is calculated. The spatial distribution of valence electronic density in Au is calculated using Tight Binding Linear Muffin Tin Method. The proton trajectories are determined by numerical integration of the classical motion equation, and the energy loss is evaluated using the calculated valence electronic density in the friction term. The results allow to describe qualitatively the non linear behavior of energy loss with ion velocity observed experimentally. (author)

  1. Electrochemical Characterization of Protein Adsorption onto YNGRT-Au and VLGXE-Au Surfaces

    OpenAIRE

    Hanna Trzeciakiewicz; Jose Esteves-Villanueva; Rania Soudy; Kamaljit Kaur; Sanela Martic-Milne

    2015-01-01

    The adsorption of the proteins CD13, mucin and bovine serum albumin on VLGXE-Au and YNGRT-Au interfaces was monitored by electrochemical impedance spectroscopy in the presence of [Fe(CN)6]3−/4−. The hydrophobicity of the Au surface was tailored using specific peptides, blocking agents and diluents. The combination of blocking agents (ethanolamine or n-butylamine) and diluents (hexanethiol or 2-mercaptoethanol) was used to prepare various peptide-modified Au surfaces. Protein adsorption onto t...

  2. Unravelling Thiol’s Role in Directing Asymmetric Growth of Au Nanorod–Au Nanoparticle Dimers

    KAUST Repository

    Huang, Jianfeng

    2015-12-15

    Asymmetric nanocrystals have practical significance in nanotechnologies but present fundamental synthetic challenges. Thiol ligands have proven effective in breaking the symmetric growth of metallic nanocrystals but their exact roles in the synthesis remain elusive. Here, we synthesized an unprecedented Au nanorod-Au nanoparticle (AuNR-AuNP) dimer structure with the assistance of a thiol ligand. On the basis of our experimental observations, we unraveled for the first time that the thiol could cause an inhomogeneous distribution of surface strains on the seed crystals as well as a modulated reduction rate of metal precursors, which jointly induced the asymmetric growth of monometallic dimers. © 2015 American Chemical Society.

  3. Apprentissages techniques : L'apprentissage au CERN

    CERN Multimedia

    2004-01-01

    APPRENTISSAGES TECHNIQUES GESTION ET DEVELOPPEMENT DU PERSONNEL HR/PMD L'APPRENTISSAGE AU CERN pour les professions d'électronicien(ne) et de laborantin(e) en physique L'apprentissage au CERN est régi par les lois, règlements et contrats en vigueur dans le Canton de Genève. En cas de réussite à l'examen de fin d'apprentissage, les apprentis obtiennent le Certificat Fédéral de Capacité Suisse (CFC). 7 places au total sont ouvertes au recrutement pour les deux professions. L'apprentissage dure 4 ans. Minima requis pour faire acte de candidature : • avoir au moins 15 ans et moins de 21 ans à la date de début de l'apprentissage • avoir terminé la scolarité obligatoire, au minimum 9ème du Cycle d'orientation genevois (3ème en France) • être ressortissant d'un pays membre du CERN (Allemagne, Autriche, Belgiqu...

  4. Evidence of final-state suppression of high-p{_ T} hadrons in Au + Au collisions using d + Au measurements at RHIC

    Science.gov (United States)

    Back, B. B.; Baker, M. D.; Ballintijn, M.; Barton, D. S.; Becker, B.; Betts, R. R.; Bickley, A. A.; Bindel, R.; Busza, W.; Carroll, A.; Decowski, M. P.; García, E.; Gburek, T.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Harrington, A. S.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Hołyński, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Khan, N.; Kulinich, P.; Kuo, C. M.; Lee, J. W.; Lin, W. T.; Manly, S.; Mignerey, A. C.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Roland, C.; Roland, G.; Sagerer, J.; Sarin, P.; Sedykh, I.; Skulski, W.; Smith, C. E.; Steinberg, P.; Stephans, G. S. F.; Sukhanov, A.; Tonjes, M. B.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Verdier, R.; Veres, G. I.; Wolfs, F. L. H.; Wosiek, B.; Woźniak, K.; Wysłouch, B.; Zhang, J.

    Transverse momentum spectra of charged hadrons with pT 2 GeV/c). In contrast, the d + Au nuclear modification factor exhibits no suppression of the high-pT yields. These measurements suggest a large energy loss of the high-pT particles in the highly interacting medium created in the central Au + Au collisions. The lack of suppression in d + Au collisions suggests that it is unlikely that initial state effects can explain the suppression in the central Au + Au collisions. PACS: 25.75.-q

  5. Systematic Measurements of Identified Particle Spectra in pp, d+Au and Au+Au Collisions from STAR

    Energy Technology Data Exchange (ETDEWEB)

    STAR Coll

    2009-04-11

    Identified charged particle spectra of {pi}{sup {+-}}, K{sup {+-}}, p and {bar p} at mid-rapidity (|y| < 0.1) measured by the dE/dx method in the STAR-TPC are reported for pp and d + Au collisions at {radical}s{sub NN} = 200 GeV and for Au + Au collisions at 62.4 GeV, 130 GeV, and 200 GeV. Average transverse momenta, total particle production, particle yield ratios, strangeness and baryon production rates are investigated as a function of the collision system and centrality. The transverse momentum spectra are found to be flatter for heavy particles than for light particles in all collision systems; the effect is more prominent for more central collisions. The extracted average transverse momentum of each particle species follows a trend determined by the total charged particle multiplicity density. The Bjorken energy density estimate is at least several GeV/fm{sub 3} for a formation time less than 1 fm/c. A significantly larger net-baryon density and a stronger increase of the net-baryon density with centrality are found in Au + Au collisions at 62.4 GeV than at the two higher energies. Antibaryon production relative to total particle multiplicity is found to be constant over centrality, but increases with the collision energy. Strangeness production relative to total particle multiplicity is similar at the three measured RHIC energies. Relative strangeness production increases quickly with centrality in peripheral Au + Au collisions, to a value about 50% above the pp value, and remains rather constant in more central collisions. Bulk freeze-out properties are extracted from thermal equilibrium model and hydrodynamics-motivated blast-wave model fits to the data. Resonance decays are found to have little effect on the extracted kinetic freeze-out parameters due to the transverse momentum range of our measurements. The extracted chemical freeze-out temperature is constant, independent of collision system or centrality; its value is close to the predicted phase

  6. Suppression of ϒ production in d+Au and Au+Au collisions at √(sNN)=200 GeV

    International Nuclear Information System (INIS)

    We report measurements of ϒ meson production in p+p, d+Au, and Au+Au collisions using the STAR detector at RHIC. We compare the ϒ yield to the measured cross section in p+p collisions in order to quantify any modifications of the yield in cold nuclear matter using d+Au data and in hot nuclear matter using Au+Au data separated into three centrality classes. Our p+p measurement is based on three times the statistics of our previous result. We obtain a nuclear modification factor for ϒ(1S+2S+3S) in the rapidity range |y|<1 in d+Au collisions of RdAu=0.79±0.24(stat.)±0.03(syst.)±0.10(p+p syst.). A comparison with models including shadowing and initial state parton energy loss indicates the presence of additional cold-nuclear matter suppression. Similarly, in the top 10% most-central Au+Au collisions, we measure a nuclear modification factor of RAA=0.49±0.1(stat.)±0.02(syst.)±0.06(p+psyst.), which is a larger suppression factor than that seen in cold nuclear matter. Our results are consistent with complete suppression of excited-state ϒ mesons in Au+Au collisions. The additional suppression in Au+Au is consistent with the level expected in model calculations that include the presence of a hot, deconfined Quark–Gluon Plasma. However, understanding the suppression seen in d+Au is still needed before any definitive statements about the nature of the suppression in Au+Au can be made

  7. Electrochemical Characterization of Protein Adsorption onto YNGRT-Au and VLGXE-Au Surfaces

    Directory of Open Access Journals (Sweden)

    Hanna Trzeciakiewicz

    2015-08-01

    Full Text Available The adsorption of the proteins CD13, mucin and bovine serum albumin on VLGXE-Au and YNGRT-Au interfaces was monitored by electrochemical impedance spectroscopy in the presence of [Fe(CN6]3−/4−. The hydrophobicity of the Au surface was tailored using specific peptides, blocking agents and diluents. The combination of blocking agents (ethanolamine or n-butylamine and diluents (hexanethiol or 2-mercaptoethanol was used to prepare various peptide-modified Au surfaces. Protein adsorption onto the peptide-Au surfaces modified with the combination of n-butylamine and hexanethiol produced a dramatic decrease in the charge transfer resistance, Rct, for all three proteins. In contrast, polar peptide-surfaces induced a minimal change in Rct for all three proteins. Furthermore, an increase in Rct was observed with CD13 (an aminopeptidase overexpressed in certain cancers in comparison to the other proteins when the VLGXE-Au surface was modified with n-butylamine as a blocking agent. The electrochemical data indicated that protein adsorption may be modulated by tailoring the peptide sequence on Au surfaces and that blocking agents and diluents play a key role in promoting or preventing protein adsorption. The peptide-Au platform may also be used for targeting cancer biomarkers with designer peptides.

  8. Electrochemical Characterization of Protein Adsorption onto YNGRT-Au and VLGXE-Au Surfaces.

    Science.gov (United States)

    Trzeciakiewicz, Hanna; Esteves-Villanueva, Jose; Soudy, Rania; Kaur, Kamaljit; Martic-Milne, Sanela

    2015-01-01

    The adsorption of the proteins CD13, mucin and bovine serum albumin on VLGXE-Au and YNGRT-Au interfaces was monitored by electrochemical impedance spectroscopy in the presence of [Fe(CN)6](3-/4-). The hydrophobicity of the Au surface was tailored using specific peptides, blocking agents and diluents. The combination of blocking agents (ethanolamine or n-butylamine) and diluents (hexanethiol or 2-mercaptoethanol) was used to prepare various peptide-modified Au surfaces. Protein adsorption onto the peptide-Au surfaces modified with the combination of n-butylamine and hexanethiol produced a dramatic decrease in the charge transfer resistance, Rct, for all three proteins. In contrast, polar peptide-surfaces induced a minimal change in Rct for all three proteins. Furthermore, an increase in Rct was observed with CD13 (an aminopeptidase overexpressed in certain cancers) in comparison to the other proteins when the VLGXE-Au surface was modified with n-butylamine as a blocking agent. The electrochemical data indicated that protein adsorption may be modulated by tailoring the peptide sequence on Au surfaces and that blocking agents and diluents play a key role in promoting or preventing protein adsorption. The peptide-Au platform may also be used for targeting cancer biomarkers with designer peptides. PMID:26262621

  9. Identified particles in Au+Au collisions at S=200 GeV

    Science.gov (United States)

    Phobos Collaboration; Wosiek, Barbara; Back, B. B.; Baker, M. D.; Barton, D. S.; Betts, R. R.; Ballintijn, M.; Bickley, A. A.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Decowski, M. P.; García, E.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Heintzelman, G. A.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Hołyński, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C. M.; Manly, S.; McLeod, D.; Michałowski, J.; Mignerey, A. C.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Remsberg, L. P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Skulski, W.; Steadman, S. G.; Steinberg, P.; Stephans, G. S. F.; Stodulski, M.; Sukhanov, A.; Tang, J.-L.; Teng, R.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Verdier, R.; Wadsworth, B.; Wolfs, F. L. H.; Wosiek, B.; Woźniak, K.; Wuosmaa, A. H.; Wysłouch, B.

    2003-03-01

    The yields of identified particles have been measured at RHIC for Au+Au collisions at S=200 GeV using the PHOBOS spectrometer. The ratios of antiparticle to particle yields near mid-rapidity are presented. The first measurements of the invariant yields of charged pions, kaons and protons at very low transverse momenta are also shown.

  10. Strangelet search in Au+Au collisions at VsNN=200 GeV

    NARCIS (Netherlands)

    Bai, Y.; Benedosso, F.; Botje, M.A.J.; Grebenyuk, O.; Mischke, A.; Peitzmann, T.; Russcher, M.J.; Snellings, R.J.M.; van der Kolk, N.

    2007-01-01

    We have searched for strangelets in a triggered sample of 61 million central (top 4%) Au+Au collisions at √sNN=200 GeV near beam rapidities at the STAR solenoidal tracker detector at the BNL Relativistic Heavy Ion Collider. We have sensitivity to metastable strangelets with lifetimes of order ⩾0.1 n

  11. Charged particle density distributions in Au + Au collisions at relativistic heavy-ion collider energies

    Indian Academy of Sciences (India)

    Fauad Rami

    2003-05-01

    Charged particle pseudorapidity distributions have been measured in Au + Au collisions using the BRAHMS detector at RHIC. The results are presented as a function of the collision centrality and the center of mass energy. They are compared to the predictions of different parton scattering models and the important role of hard scattering processes at RHIC energies is discussed.

  12. EVENT STRUCTURE AT RHIC FROM P-P TO AU-AU.

    Energy Technology Data Exchange (ETDEWEB)

    TRAINOR,T.A.; (FOR THE STAR COLLABORATION)

    2004-03-15

    Several correlation analysis techniques are applied to p-p and Au-Au collisions at RHIC. Strong large-momentum-scale correlations are observed which can be related to local charge and momentum conservation during hadronization and to minijet (minimum-bias parton fragment) correlations.

  13. Study of Au+Au relativistic collisions with the Fopi-Phase I detector

    International Nuclear Information System (INIS)

    Au+Au relativistic collisions, in a 100-1000 MeV energy domain per nucleon, are described. Experiments have been carried out with the SIS accelerator at GSI/Darmstadt. Data are analysed with the FOPI-phase I detector. These data are compared with IQMD model (Isospin Quantum Molecular Dynamics) Predictions. (S.G). 80 refs., 77 figs., 5 tabs

  14. Jets and dijets in Au+Au and p+p collisions at RHIC

    Energy Technology Data Exchange (ETDEWEB)

    Hardtke, D.; STAR Collaboration

    2002-12-09

    Recent data from RHIC suggest novel nuclear effects in the production of high p{sub T} hadrons. We present results from the STAR detector on high p{sub T} angular correlations in Au+Au and p+p collisions at {radical}S = 200 GeV/c. These two-particle angular correlation measurements verify the presence of a partonic hard scattering and fragmentation component at high p{sub T} in both central and peripheral Au+Au collisions. When triggering on a leading hadron with p{sub T}>4 GeV, we observe a quantitative agreement between the jet cone properties in p+p and all centralities of Au+Au collisions. This quantitative agreement indicates that nearly all hadrons with p{sub T}>4 GeV/c come from jet fragmentation and that jet fragmentation properties are not substantially modified in Au+Au collisions. STAR has also measured the strength of back-to-back high p{sub T} charged hadron correlations, and observes a small suppression of the back-to-back correlation strength in peripheral collisions, and a nearly complete disappearance o f back-to-back correlations in central Au+Au events. These phenomena, together with the observed strong suppression of inclusive yields and large value of elliptic flow at high p{sub T}, are consistent with a model where high p{sub T} hadrons come from partons created near the surface of the collision region, and where partons that originate or propagate towards the center of the collision region are substantially slowed or completely absorbed.

  15. Spectra and ratios of identified particles in Au+Au and d+Au collisions at sqrt(s_NN)=200 GeV

    CERN Document Server

    Adare, A; Aidala, C; Ajitanand, N N; Akiba, Y; Al-Bataineh, H; Alexander, J; Angerami, A; Aoki, K; Apadula, N; Aramaki, Y; Atomssa, E T; Averbeck, R; Awes, T C; Azmoun, B; Babintsev, V; Bai, M; Baksay, G; Baksay, L; Barish, K N; Bassalleck, B; Basye, A T; Bathe, S; Baublis, V; Baumann, C; Bazilevsky, A; Belikov, S; Belmont, R; Bennett, R; Berdnikov, A; Berdnikov, Y; Bhom, J H; Bickley, A A; Blau, D S; Bok, J S; Boyle, K; Brooks, M L; Buesching, H; Bumazhnov, V; Bunce, G; Butsyk, S; Camacho, C M; Campbell, S; Caringi, A; Chen, C -H; Chi, C Y; Chiu, M; Choi, I J; Choi, J B; Choudhury, R K; Christiansen, P; Chujo, T; Chung, P; Chvala, O; Cianciolo, V; Citron, Z; Cole, B A; del Valle, Z Conesa; Connors, M; Constantin, P; Csanád, M; Csörgő, T; Dahms, T; Dairaku, S; Danchev, I; Das, K; Datta, A; David, G; Dayananda, M K; Denisov, A; Deshpande, A; Desmond, E J; Dharmawardane, K V; Dietzsch, O; Dion, A; Donadelli, M; Drapier, O; Drees, A; Drees, K A; Durham, J M; Durum, A; Dutta, D; D'Orazio, L; Edwards, S; Efremenko, Y V; Ellinghaus, F; Engelmore, T; Enokizono, A; En'yo, H; Esumi, S; Fadem, B; Fields, D E; Finger, M; Jr., \\,; Fleuret, F; Fokin, S L; Fraenkel, Z; Frantz, J E; Franz, A; Frawley, A D; Fujiwara, K; Fukao, Y; Fusayasu, T; Garishvili, I; Glenn, A; Gong, H; Gonin, M; Goto, Y; de Cassagnac, R Granier; Grau, N; Greene, S V; Grim, G; Perdekamp, M Grosse; Gunji, T; Gustafsson, H -Å; Haggerty, J S; Hahn, K I; Hamagaki, H; Hamblen, J; Han, R; Hanks, J; Hartouni, E P; Haslum, E; Hayano, R; He, X; Heffner, M; Hemmick, T K; Hester, T; Hill, J C; Hohlmann, M; Holzmann, W; Homma, K; Hong, B; Horaguchi, T; Hornback, D; Huang, S; Ichihara, T; Ichimiya, R; Ide, J; Ikeda, Y; Imai, K; Inaba, M; Isenhower, D; Ishihara, M; Isobe, T; Issah, M; Isupov, A; Ivanischev, D; Iwanaga, Y; Jacak, B V; Jia, J; Jiang, X; Jin, J; Johnson, B M; Jones, T; Joo, K S; Jouan, D; Jumper, D S; Kajihara, F; Kametani, S; Kamihara, N; Kamin, J; Kang, J H; Kapustinsky, J; Karatsu, K; Kasai, M; Kawall, D; Kawashima, M; Kazantsev, A V; Kempel, T; Khanzadeev, A; Kijima, K M; Kikuchi, J; Kim, A; Kim, B I; Kim, D H; Kim, D J; Kim, E; Kim, E -J; Kim, S H; Kim, Y -J; Kim, Y J; Kinney, E; Kiriluk, K; Kiss, Á; Kistenev, E; Kleinjan, D; Kochenda, L; Komkov, B; Konno, M; Koster, J; Kotchetkov, D; Kozlov, A; Král, A; Kravitz, A; Kunde, G J; Kurita, K; Kurosawa, M; Kwon, Y; Kyle, G S; Lacey, R; Lai, Y S; Lajoie, J G; Lebedev, A; Lee, D M; Lee, J; Lee, K; Lee, K B; Lee, K S; Leitch, M J; Leite, M A L; Leitner, E; Lenzi, B; Li, X; Lichtenwalner, P; Liebing, P; Levy, L A Linden; Liška, T; Litvinenko, A; Liu, H; Liu, M X; Love, B; Luechtenborg, R; Lynch, D; Maguire, C F; Makdisi, Y I; Malakhov, A; Malik, M D; Manko, V I; Mannel, E; Mao, Y; Masui, H; Matathias, F; McCumber, M; McGaughey, P L; McGlinchey, D; Means, N; Meredith, B; Miake, Y; Mibe, T; Mignerey, A C; Mikeš, P; Miki, K; Milov, A; Mishra, M; Mitchell, J T; Mohanty, A K; Moon, H J; Morino, Y; Morreale, A; Morrison, D P; Moukhanova, T V; Murakami, T; Murata, J; Nagamiya, S; Nagle, J L; Naglis, M; Nagy, M I; Nakagawa, I; Nakamiya, Y; Nakamura, K R; Nakamura, T; Nakano, K; Nam, S; Newby, J; Nguyen, M; Nihashi, M; Nouicer, R; Nyanin, A S; Oakley, C; O'Brien, E; Oda, S X; Ogilvie, C A; Oka, M; Okada, K; Onuki, Y; Oskarsson, A; Ouchida, M; Ozawa, K; Pak, R; Pantuev, V; Papavassiliou, V; Park, I H; Park, J; Park, S K; Park, W J; Pate, S F; Pei, H; Peng, J -C; Pereira, H; Peresedov, V; Peressounko, D Yu; Petti, R; Pinkenburg, C; Pisani, R P; Proissl, M; Purschke, M L; Purwar, A K; Qu, H; Rak, J; Rakotozafindrabe, A; Ravinovich, I; Read, K F; Rembeczki, S; Reygers, K; Riabov, V; Riabov, Y; Richardson, E; Roach, D; Roche, G; Rolnick, S D; Rosati, M; Rosen, C A; Rosendahl, S S E; Rosnet, P; Rukoyatkin, P; Ružička, P; Sahlmueller, B; Saito, N; Sakaguchi, T; Sakashita, K; Samsonov, V; Sano, S; Sato, T; Sawada, S; Sedgwick, K; Seele, J; Seidl, R; Semenov, A Yu; Seto, R; Sharma, D; Shein, I; Shibata, T -A; Shigaki, K; Shimomura, M; Shoji, K; Shukla, P; Sickles, A; Silva, C L; Silvermyr, D; Silvestre, C; Sim, K S; Singh, B K; Singh, C P; Singh, V; Slunečka, M; Soltz, R A; Sondheim, W E; Sorensen, S P; Sourikova, I V; Sparks, N A; Stankus, P W; Stenlund, E; Stoll, S P; Sugitate, T; Sukhanov, A; Sziklai, J; Takagui, E M; Taketani, A; Tanabe, R; Tanaka, Y; Taneja, S; Tanida, K; Tannenbaum, M J; Tarafdar, S; Taranenko, A; Tarján, P; Themann, H; Thomas, D; Thomas, T L; Togawa, M; Toia, A; Tomášek, L; Torii, H; Towell, R S; Tserruya, I; Tsuchimoto, Y; Vale, C; Valle, H; van Hecke, H W; Vazquez-Zambrano, E; Veicht, A; Velkovska, J; Vértesi, R; Vinogradov, A A; Virius, M; Vrba, V; Vznuzdaev, E; Wang, X R; Watanabe, D; Watanabe, K; Watanabe, Y; Wei, F; Wei, R; Wessels, J; White, S N; Winter, D; Wood, J P; Woody, C L; Wright, R M; Wysocki, M; Xie, W; Yamaguchi, Y L; Yamaura, K; Yang, R; Yanovich, A; Ying, J; Yokkaichi, S

    2013-01-01

    The transverse momentum (p_T) spectra and ratios of identified charged hadrons (\\pi^+/-, K^+/-, p, p^bar) produced in sqrt(s_NN)=200 GeV Au+Au and d+Au collisions are reported in five different centrality classes for each collision species. The measurements of pions and protons are reported up to p_T=6 GeV/c (5 GeV/c), and the measurements of kaons are reported up to p_T=4 GeV/c (3.5 GeV/c) in Au+Au (d+Au) collisions. In the intermediate p_T region, between 2--5 GeV/c, a significant enhancement of baryon to meson ratios compared to those measured in p+p collisions is observed. This enhancement is present in both Au+Au and d+Au collisions, and increases as the collisions become more central. We compare a class of peripheral Au+Au collisions with a class of central d+Au collisions which have a comparable number of participating nucleons and binary nucleon-nucleon collisions. The p_T dependent particle ratios for these classes display a remarkable similarity, which is then discussed.

  16. Open Heavy Flavor Production in p+p, d+Au and Au+Au Collisions at $\\sqrt{s}$= 200$ GeV

    CERN Document Server

    Wang, X

    2006-01-01

    PHENIX results for open charm production from semi-lepton decay in p+p, d+Au and Au+Au collisions in a wide rapidity ranges at $\\sqrt{s}$= 200$ GeV are presented. Keywords: Relativistic Heavy-ion Collision, Open Charm production, Nuclear Medium Effect PACS: 25.75.-q, 25.75 Dw, 13.20.Gd

  17. Spectra and ratios of identified particles in Au+Au and d+Au collisions at sNN=200 GeV

    Science.gov (United States)

    Adare, A.; Afanasiev, S.; Aidala, C.; Ajitanand, N. N.; Akiba, Y.; Al-Bataineh, H.; Alexander, J.; Angerami, A.; Aoki, K.; Apadula, N.; Aramaki, Y.; Atomssa, E. T.; Averbeck, R.; Awes, T. C.; Azmoun, B.; Babintsev, V.; Bai, M.; Baksay, G.; Baksay, L.; Barish, K. N.; Bassalleck, B.; Basye, A. T.; Bathe, S.; Baublis, V.; Baumann, C.; Bazilevsky, A.; Belikov, S.; Belmont, R.; Bennett, R.; Berdnikov, A.; Berdnikov, Y.; Bhom, J. H.; Bickley, A. A.; Blau, D. S.; Bok, J. S.; Boyle, K.; Brooks, M. L.; Buesching, H.; Bumazhnov, V.; Bunce, G.; Butsyk, S.; Camacho, C. M.; Campbell, S.; Caringi, A.; Chen, C.-H.; Chi, C. Y.; Chiu, M.; Choi, I. J.; Choi, J. B.; Choudhury, R. K.; Christiansen, P.; Chujo, T.; Chung, P.; Chvala, O.; Cianciolo, V.; Citron, Z.; Cole, B. A.; Conesa del Valle, Z.; Connors, M.; Constantin, P.; Csanád, M.; Csörgő, T.; Dahms, T.; Dairaku, S.; Danchev, I.; Das, K.; Datta, A.; David, G.; Dayananda, M. K.; Denisov, A.; Deshpande, A.; Desmond, E. J.; Dharmawardane, K. V.; Dietzsch, O.; Dion, A.; Donadelli, M.; Drapier, O.; Drees, A.; Drees, K. A.; Durham, J. M.; Durum, A.; Dutta, D.; D'Orazio, L.; Edwards, S.; Efremenko, Y. V.; Ellinghaus, F.; Engelmore, T.; Enokizono, A.; En'yo, H.; Esumi, S.; Fadem, B.; Fields, D. E.; Finger, M.; Finger, M., Jr.; Fleuret, F.; Fokin, S. L.; Fraenkel, Z.; Frantz, J. E.; Franz, A.; Frawley, A. D.; Fujiwara, K.; Fukao, Y.; Fusayasu, T.; Garishvili, I.; Glenn, A.; Gong, H.; Gonin, M.; Goto, Y.; Granier de Cassagnac, R.; Grau, N.; Greene, S. V.; Grim, G.; Grosse Perdekamp, M.; Gunji, T.; Gustafsson, H.-Å.; Haggerty, J. S.; Hahn, K. I.; Hamagaki, H.; Hamblen, J.; Han, R.; Hanks, J.; Hartouni, E. P.; Haslum, E.; Hayano, R.; He, X.; Heffner, M.; Hemmick, T. K.; Hester, T.; Hill, J. C.; Hohlmann, M.; Holzmann, W.; Homma, K.; Hong, B.; Horaguchi, T.; Hornback, D.; Huang, S.; Ichihara, T.; Ichimiya, R.; Ide, J.; Ikeda, Y.; Imai, K.; Inaba, M.; Isenhower, D.; Ishihara, M.; Isobe, T.; Issah, M.; Isupov, A.; Ivanischev, D.; Iwanaga, Y.; Jacak, B. V.; Jia, J.; Jiang, X.; Jin, J.; Johnson, B. M.; Jones, T.; Joo, K. S.; Jouan, D.; Jumper, D. S.; Kajihara, F.; Kametani, S.; Kamihara, N.; Kamin, J.; Kang, J. H.; Kapustinsky, J.; Karatsu, K.; Kasai, M.; Kawall, D.; Kawashima, M.; Kazantsev, A. V.; Kempel, T.; Khanzadeev, A.; Kijima, K. M.; Kikuchi, J.; Kim, A.; Kim, B. I.; Kim, D. H.; Kim, D. J.; Kim, E.; Kim, E.-J.; Kim, S. H.; Kim, Y.-J.; Kinney, E.; Kiriluk, K.; Kiss, Á.; Kistenev, E.; Kleinjan, D.; Kochenda, L.; Komkov, B.; Konno, M.; Koster, J.; Kotchetkov, D.; Kozlov, A.; Král, A.; Kravitz, A.; Kunde, G. J.; Kurita, K.; Kurosawa, M.; Kwon, Y.; Kyle, G. S.; Lacey, R.; Lai, Y. S.; Lajoie, J. G.; Lebedev, A.; Lee, D. M.; Lee, J.; Lee, K.; Lee, K. B.; Lee, K. S.; Leitch, M. J.; Leite, M. A. L.; Leitner, E.; Lenzi, B.; Li, X.; Lichtenwalner, P.; Liebing, P.; Linden Levy, L. A.; Liška, T.; Litvinenko, A.; Liu, H.; Liu, M. X.; Love, B.; Luechtenborg, R.; Lynch, D.; Maguire, C. F.; Makdisi, Y. I.; Malakhov, A.; Malik, M. D.; Manko, V. I.; Mannel, E.; Mao, Y.; Masui, H.; Matathias, F.; McCumber, M.; McGaughey, P. L.; McGlinchey, D.; Means, N.; Meredith, B.; Miake, Y.; Mibe, T.; Mignerey, A. C.; Mikeš, P.; Miki, K.; Milov, A.; Mishra, M.; Mitchell, J. T.; Mohanty, A. K.; Moon, H. J.; Morino, Y.; Morreale, A.; Morrison, D. P.; Moukhanova, T. V.; Murakami, T.; Murata, J.; Nagamiya, S.; Nagle, J. L.; Naglis, M.; Nagy, M. I.; Nakagawa, I.; Nakamiya, Y.; Nakamura, K. R.; Nakamura, T.; Nakano, K.; Nam, S.; Newby, J.; Nguyen, M.; Nihashi, M.; Nouicer, R.; Nyanin, A. S.; Oakley, C.; O'Brien, E.; Oda, S. X.; Ogilvie, C. A.; Oka, M.; Okada, K.; Onuki, Y.; Oskarsson, A.; Ouchida, M.; Ozawa, K.; Pak, R.; Pantuev, V.; Papavassiliou, V.; Park, I. H.; Park, J.; Park, S. K.; Park, W. J.; Pate, S. F.; Pei, H.; Peng, J.-C.; Pereira, H.; Peresedov, V.; Peressounko, D. Yu.; Petti, R.; Pinkenburg, C.; Pisani, R. P.; Proissl, M.; Purschke, M. L.; Purwar, A. K.; Qu, H.; Rak, J.; Rakotozafindrabe, A.; Ravinovich, I.; Read, K. F.; Rembeczki, S.; Reygers, K.; Riabov, V.; Riabov, Y.; Richardson, E.; Roach, D.; Roche, G.; Rolnick, S. D.; Rosati, M.; Rosen, C. A.; Rosendahl, S. S. E.; Rosnet, P.; Rukoyatkin, P.; Ružička, P.; Sahlmueller, B.; Saito, N.; Sakaguchi, T.; Sakashita, K.; Samsonov, V.; Sano, S.; Sato, T.; Sawada, S.; Sedgwick, K.; Seele, J.; Seidl, R.; Semenov, A. Yu.; Seto, R.; Sharma, D.; Shein, I.; Shibata, T.-A.; Shigaki, K.; Shimomura, M.; Shoji, K.; Shukla, P.; Sickles, A.; Silva, C. L.; Silvermyr, D.; Silvestre, C.; Sim, K. S.; Singh, B. K.; Singh, C. P.; Singh, V.; Slunečka, M.; Soltz, R. A.; Sondheim, W. E.; Sorensen, S. P.; Sourikova, I. V.; Sparks, N. A.; Stankus, P. W.; Stenlund, E.; Stoll, S. P.; Sugitate, T.; Sukhanov, A.; Sziklai, J.; Takagui, E. M.; Taketani, A.; Tanabe, R.; Tanaka, Y.; Taneja, S.; Tanida, K.; Tannenbaum, M. J.; Tarafdar, S.; Taranenko, A.; Tarján, P.; Themann, H.; Thomas, D.; Thomas, T. L.; Togawa, M.; Toia, A.; Tomášek, L.; Torii, H.; Towell, R. S.; Tserruya, I.; Tsuchimoto, Y.; Vale, C.; Valle, H.; van Hecke, H. W.; Vazquez-Zambrano, E.; Veicht, A.; Velkovska, J.; Vértesi, R.; Vinogradov, A. A.; Virius, M.; Vrba, V.; Vznuzdaev, E.; Wang, X. R.; Watanabe, D.; Watanabe, K.; Watanabe, Y.; Wei, F.; Wei, R.; Wessels, J.; White, S. N.; Winter, D.; Wood, J. P.; Woody, C. L.; Wright, R. M.; Wysocki, M.; Xie, W.; Yamaguchi, Y. L.; Yamaura, K.; Yang, R.; Yanovich, A.; Ying, J.; Yokkaichi, S.; You, Z.; Young, G. R.; Younus, I.; Yushmanov, I. E.; Zajc, W. A.; Zhang, C.; Zhou, S.; Zolin, L.

    2013-08-01

    The transverse momentum (pT) spectra and ratios of identified charged hadrons (π±, K±, p, p¯) produced in sNN=200 GeV Au+Au and d+Au collisions are reported in five different centrality classes for each collision species. The measurements of pions and protons are reported up to pT=6 GeV/c (5 GeV/c), and the measurements of kaons are reported up to pT=4 GeV/c (3.5 GeV/c) in Au+Au (d+Au) collisions. In the intermediate pT region, between 2 and 5 GeV/c, a significant enhancement of baryon-to-meson ratios compared to those measured in p+p collisions is observed. This enhancement is present in both Au+Au and d+Au collisions and increases as the collisions become more central. We compare a class of peripheral Au+Au collisions with a class of central d+Au collisions which have a comparable number of participating nucleons and binary nucleon-nucleon collisions. The pT-dependent particle ratios for these classes display a remarkable similarity, which is then discussed.

  18. Relative Distribution of Au48+~Au52+ in Au Plasma by Ionization Dynamics

    Institute of Scientific and Technical Information of China (English)

    ZHUZhi-Yan; ZHUZheng-He; JIANGGang

    2003-01-01

    The present work proposes a theoretical method called ionization dynamics to derive the ionic charge state distribution. Using relativistic quantum mechanics to calculate the energy level lifetime and average ionic lifetime of each ion, the first-order ionization rate constant can be obtained. Based on these data, from the solution of differential equations for consecutive-irreversible ionization reactions, one will be able to derive the ionic charge state distribution.The calculated average positive charge 49.24 of Au48+ ~ Au52+ and their relative distribution are in good agreement with the results of Lawrence Livermore National Laboratory.

  19. Polymerase chain reaction of Au nanoparticle-bound primers

    Institute of Scientific and Technical Information of China (English)

    SHEN Hebai; HU Min; YANG Zhongnan; WANG Chen; ZHU Longzhang

    2005-01-01

    Polymerase chain reaction (PCR) is a useful technique for in vitro amplification of a DNA fragment. In this paper, a PCR procedure using Au nanoparticle (AuNP) -bound primers was systemically studied. The 5′-SH- (CH2)6-modified primers were covalently attached to the AuNP surface via Au-S bonds, and plasmid pBluescript SK was used as a template. The effects of the concentration of AuNP-bound primers, annealing temperature and PCR cycles were evaluated, respectively. The results indicate that PCR can proceed successfully under optimized condition, with either forward or reverse primers bound to the AuNP surface or with both the two primers bound to the AuNP surface. Development of PCR procedure based on AuNPs not only makes the isolation of PCR products very convenient, but also provides novel methods to prepare AuNP-bound ssDNA and nanostructured material.

  20. Engineering the strain in graphene layers with Au decoration

    Energy Technology Data Exchange (ETDEWEB)

    Pannu, Compesh, E-mail: compesh@gmail.com; Singh, Udai B.; Kumar, Sunil; Tripathi, A.; Kabiraj, D.; Avasthi, D.K., E-mail: dka4444@gmail.com

    2014-07-01

    Graphene sheets decorated with Au nanodots are synthesized by deposition of Au of three different thicknesses and subsequent annealing at 400 °C. Different thicknesses of Au film for the formation of Au nanodots on graphene are measured using Rutherford backscattering spectrometry and morphology is studied using scanning electron microscopy. Raman spectroscopy indicates 3–6-fold increase in I{sub D}/I{sub G} ratio depending on the content of Au deposited on graphene. The increase in disorder in Au decorated graphene layers is explained on the basis of interaction of Au atoms with Π bonds of graphene. The splitting and blueshift in G band signifies compressive strain in Au deposited graphene. X-ray diffraction studies using synchrotron radiation source confirm compressive strain in graphene, which increases with increase of Au film thickness.

  1. Synthesis and characterization in AuCu–Si nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Novelo, T.E., E-mail: tenovelo@hotmail.com [Centro de Investigación en Materiales Avanzados, S.C., Laboratorio Nacional de Nanotecnología, Av. Miguel de Cervantes 120, Complejo Industrial Chihuahua, 31109 Chihuahua, Chihuahua Mexico (Mexico); Amézaga-Madrid, P. [Centro de Investigación en Materiales Avanzados, S.C., Laboratorio Nacional de Nanotecnología, Av. Miguel de Cervantes 120, Complejo Industrial Chihuahua, 31109 Chihuahua, Chihuahua Mexico (Mexico); Maldonado, R.D. [Universidad Anáhuac-Mayab, Carretera Mérida-Progreso Km. 15.5 A.P. 96-Cordemex, CP. 97310 Mérida, Yucatán Mexico (Mexico); Oliva, A.I. [Centro de Investigación y de Estudios Avanzados el IPN Unidad Mérida, Departamento de Física Aplicada, Km 6 Antigua Carretera a Progreso, A.P. 73-Cordemex, 97310 Mérida, Yucatán Mexico (Mexico); Alonzo-Medina, G.M. [Universidad Anáhuac-Mayab, Carretera Mérida-Progreso Km. 15.5 A.P. 96-Cordemex, CP. 97310 Mérida, Yucatán Mexico (Mexico)

    2015-03-15

    Au/Cu bilayers with different Au:Cu concentrations (25:75, 50:50 and 75:25 at.%) were deposited on Si(100) substrates by thermal evaporation. The thicknesses of all Au/Cu bilayers were 150 nm. The alloys were prepared by thermal diffusion into a vacuum oven with argon atmosphere at 690 K during 1 h. X-ray diffraction analysis revealed different phases of AuCu and CuSi alloys in the samples after annealing process. CuSi alloys were mainly obtained for 25:75 at.% samples, meanwhile the AuCuII phase dominates for samples prepared with 50:50 at.%. Additionally, the Au:Cu alloys with 75:25 at.%, produce Au{sub 2}Cu{sub 3} and Au{sub 3}Cu phases. The formed alloys were characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM), transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS) to study the morphology and the elemental concentration of the formed alloys. - Highlights: • AuCu/Si alloy thin films were prepared by thermal diffusion. • Alloys prepared with 50 at.% of Au produce the AuCuII phase. • Alloys prepared with 75 at.% of Au produce Au{sub 3}Cu and Au{sub 2}Cu{sub 3} phases. • All alloys present diffusion of Si and Cu through the CuSi alloy formation.

  2. Plasmonic Au islands on polymer nanopillars

    Energy Technology Data Exchange (ETDEWEB)

    Knoben, Wout; Brongersma, Sywert H; Crego-Calama, Mercedes, E-mail: wout.knoben@imec-nl.nl [Holst Centre/IMEC, High Tech Campus 31, 5656 AE Eindhoven (Netherlands)

    2011-07-22

    The refractive index sensitivity of localized surface plasmon resonance sensors can be improved by placing the plasmonic metal particles on pillars instead of on a planar substrate. In this paper, a simple and versatile colloidal lithography method for the fabrication of plasmonic Au islands on top of polymer nanopillars is described. The pillar height is controlled by varying the thickness of the initial polymer film. An increased pillar height results in a blue shift of the absorption spectrum of the Au islands. This is explained by a decreased effective refractive index around the islands. For pillars higher than approximately 40 nm no further blue shift is observed, in agreement with the decay length of the electromagnetic field around the islands. Pillar-supported Au islands were also fabricated on a flexible foil, demonstrating the potential of the method described here for the fabrication of flexible plasmonic substrates. Benefits and limitations of the method and of using polymers as the pillar material are discussed.

  3. Au nanoparticles films used in biological sensing

    International Nuclear Information System (INIS)

    Lactobacillus para paracasei are used commonly as functional food and probiotic substances. In this work Au nanoparticles self-assembled films were used for Lactobacillus para paracasei determination at five different concentrations. Functionalized substrates were immersed in a colloidal solution for one and a half hour at room temperature and dried at room temperature during four hours. After that, drops of Lactobacillus para paracasei in aqueous solution were put into the Au nanoparticles film and let dry at room temperature for another two hours. Infrared spectroscopy in attenuated total reflectance sampling mode was used to observe generation peaks due to substrate silanization, enhancement of Si-O band intensity due to the Au colloids added to silanized substrate and also to observe the enhancement of Lactobacillus para paracasei infrared intensity of the characteristic frequencies at 1650, 1534 and 1450 cm-1 due to surface enhancement infrared absorption.

  4. Au nanoparticles films used in biological sensing

    Science.gov (United States)

    Rosales Pérez, M.; Delgado Macuil, R.; Rojas López, M.; Gayou, V. L.; Sánchez Ramírez, J. F.

    2009-05-01

    Lactobacillus para paracasei are used commonly as functional food and probiotic substances. In this work Au nanoparticles self-assembled films were used for Lactobacillus para paracasei determination at five different concentrations. Functionalized substrates were immersed in a colloidal solution for one and a half hour at room temperature and dried at room temperature during four hours. After that, drops of Lactobacillus para paracasei in aqueous solution were put into the Au nanoparticles film and let dry at room temperature for another two hours. Infrared spectroscopy in attenuated total reflectance sampling mode was used to observe generation peaks due to substrate silanization, enhancement of Si-O band intensity due to the Au colloids added to silanized substrate and also to observe the enhancement of Lactobacillus para paracasei infrared intensity of the characteristic frequencies at 1650, 1534 and 1450 cm-1 due to surface enhancement infrared absorption.

  5. Violence et ordre politique au Nigeria

    OpenAIRE

    Fourchard, Laurent

    2007-01-01

    International audience De nombreuses analyses ont associé le retour d'un régime civil au Nigeria en 1999 au développement d'organisations armées privées et au regain de conflits dits religieux, inter-ethniques ou communautaires. L'application controversée de la charia dans douze Etats du nord et les actions de guérilla dans la région pétrolière du delta ont ainsi largement focalisé l'attention des médias. Le retour de la " démocratie " témoignerait-t-il d'un déclin de l'Etat ? Ces violence...

  6. Au nanoparticles films used in biological sensing

    Energy Technology Data Exchange (ETDEWEB)

    Rosales Perez, M; Delgado Macuil, R; Rojas Lopez, M; Gayou, V L [Centro de Investigacion en BiotecnologIa Aplicada del IPN, Tepetitla Tlaxcala Mexico C.P. 90700 (Mexico); Sanchez Ramirez, J F, E-mail: mrosalespe@ipn.m [CICATA Legaria Instituto Politecnico Nacional, Mexico Distrito Federal (Mexico)

    2009-05-01

    Lactobacillus para paracasei are used commonly as functional food and probiotic substances. In this work Au nanoparticles self-assembled films were used for Lactobacillus para paracasei determination at five different concentrations. Functionalized substrates were immersed in a colloidal solution for one and a half hour at room temperature and dried at room temperature during four hours. After that, drops of Lactobacillus para paracasei in aqueous solution were put into the Au nanoparticles film and let dry at room temperature for another two hours. Infrared spectroscopy in attenuated total reflectance sampling mode was used to observe generation peaks due to substrate silanization, enhancement of Si-O band intensity due to the Au colloids added to silanized substrate and also to observe the enhancement of Lactobacillus para paracasei infrared intensity of the characteristic frequencies at 1650, 1534 and 1450 cm{sup -1} due to surface enhancement infrared absorption.

  7. A velocity map imaging study of gold-rare gas complexes: Au-Ar, Au-Kr, and Au-Xe

    Science.gov (United States)

    Hopkins, W. Scott; Woodham, Alex P.; Plowright, Richard J.; Wright, Timothy G.; Mackenzie, Stuart R.

    2010-06-01

    The ultraviolet photodissociation dynamics of the gold-rare gas atom van der Waals complexes (Au-RG, RG=Ar, Kr, and Xe) have been studied by velocity map imaging. Photofragmentation of Au-Ar and Au-Kr at several wavelengths permits extrapolation to zero of the total kinetic energy release (TKER) spectra as monitored in the Au(P23/2∘[5d106p]) fragment channel, facilitating the determination of ground state dissociation energies of D0″(Au-Ar)=149±13 cm-1 and D0″(Au-Kr)=240±19 cm-1, respectively. In the same spectral region, transitions to vibrational levels of an Ω'=1/2 state of the Au-Xe complex result in predissociation to the lower Au(P21/2∘[5d106p])+Xe(S10[5p6]) fragment channel for which TKER extrapolation yields a value of D0″(Au-Xe)=636±27 cm-1. Asymmetric line shapes for transitions to the v'=14 level of this state indicate coupling to the Au(P23/2∘[5d106p])+Xe(S10[5p6]) continuum, which allows us to refine this value to D0″(Au-Xe)=607±5 cm-1. The dissociation dynamics of this vibrational level have been studied at the level of individual isotopologues by fitting the observed excitation spectra to Fano profiles. These fits reveal a remarkable variation in the predissociation dynamics for different Au-Xe isotopologues. For Au-Ar and Au-Xe, the determined ground state dissociation energies are in good agreement with recent theoretical calculations; the agreement of the Au-Kr value with theory is less satisfactory.

  8. Plasmonic Fano resonance and dip of Au-SiO2-Au nanomatryoshka.

    Science.gov (United States)

    Liaw, Jiunn-Woei; Chen, Huang-Chih; Kuo, Mao-Kuen

    2013-01-01

    This study theoretically investigates Fano resonances and dips of an Au-SiO2-Au nanomatryoshka that is excited by a nearby electric dipole. An analytical solution of dyadic Green's functions is used to analyze the radiative and nonradiative power spectra of a radial dipole in the proximity of a nanomatryoshka. From these spectra, the plasmon modes and Fano resonances that accompany the Fano dips are identified. In addition, the scattering and absorption spectra of a nanomatryoshka that is illuminated by a plane wave are investigated to confirm these modes and Fano dips. Our results reveal that a Fano dip splits each of the dipole and quadrupole modes into bonding and anti-bonding modes. The Fano dip and resonance result from the destructive interference of the plasmon modes of the Au shell and the Au core. The Fano factors that are obtained from the nonradiative power spectra of the Au shell and the Au core of a nanomatryoshka are in accordance with those obtained from the absorption cross section spectra. Moreover, these Fano factors increase as the plasmonic coupling of the Au shell with the core increases for both dipole and quadrupole modes. PMID:24206789

  9. Ω production in p+p, Au+Au and U+U collisions at STAR

    International Nuclear Information System (INIS)

    We report STAR's high precision measurements on Ω production at mid-rapidity from √(s)=200 GeVp+p, central √(sNN)=200 GeVAu+Au, and central √(sNN)=193 GeVU+U collisions. With the significantly reduced uncertainty in p+p reference, we observe that the Ω enhancement factors at RHIC are in between SPS and LHC, while enhancement factors are systematically larger in central U+U collisions than in central Au+Au collisions. The ΩRAA is much larger than protons and pions for pT up to 4 GeV/c in central Au+Au collisions. The ratio of ΩRAA in central U+U to that in central Au+Au collisions is above unity for pT up to 6 GeV/c, which indicates coalescence/recombination to be the dominant production mechanism for Ω in these collisions for the measured pT range

  10. Variation of the Melang Glacier in Mount Kawa Karpo in the Past 40 Years,Based on Dendrochronolog%近40a来基于树轮年代学的梅里雪山明永冰川变化研究

    Institute of Scientific and Technical Information of China (English)

    蓝永如; 刘高焕; 邵雪梅

    2011-01-01

    由于冰川观测资料在时空分布上的匮乏,关于梅里雪山地区冰川进退的研究很少,限制了对该区冰川进退的时间和规模及其与气候间相关性等方面的认知.树轮年代学方法作为冰川进退历史定年的有效手段,在世界上已经被广泛采用.通过对采自冰川末端冰碛上的树轮样本进行分析,利用GIS结合地形图与野外GPS点冰川边界确定,研究和分析了明永冰川年近40a来的冰川进退变化.为进一步的树轮冰川学研究提供支持,也为预估未来变化趋势提供重要的科学基本数据.%In Mount Kawa Karpo,the variation of glaciers,as well as the correlation between glaciers and climate change,is rarely known,because there is lack of data about spatial and temporal variation of glaciers,and less research about the variation has been done.Dendrochonology is a world-famous tool to reconstruct glacier fluctuation.In this study,the tree-ring samples from the moraine by the glacier terminus are analyzed,and then variation of the Melang Glacier in the past 40 years is determined by means of topographic map and latest GPS boundaries in GIS.Using the dendrochronology,the age of Picea likiangensis living on the moraine by the glacier terminus and the forming age of the moraine are determined.It is found that the latest event about glacier variation occurred in 1987,after a topographic map being completed in 1971.Derived from the ages of spruces living inside and outside the moraine,it is believed that from 1987 to 1993 the glacier terminus had existed stably at the position where spruces begun to grew in 1998.Because the youngest tree has grown,it is inferred that the glacier retreated about 1993.There is a glacier close to the Melang Glacier,whose terminus was thought at the steady state until 1959,and in the GIS map of 1971,the glacier terminus is outside the area where trees live.

  11. Production of omega mesons in p+p, d+Au, Cu+Cu, and Au+Au collisions at sqrt(s_NN)=200 GeV

    CERN Document Server

    Adare, A; Aidala, C; Ajitanand, N N; Akiba, Y; Al-Bataineh, H; Al-Jamel, A; Alexander, J; Angerami, A; Aoki, K; Apadula, N; Aphecetche, L; Aramaki, Y; Armendariz, R; Aronson, S H; Asai, J; Atomssa, E T; Averbeck, R; Awes, T C; Azmoun, B; Babintsev, V; Bai, M; Baksay, G; Baksay, L; Baldisseri, A; Barish, K N; Barnes, P D; Bassalleck, B; Basye, A T; Bathe, S; Batsouli, S; Baublis, V; Bauer, F; Baumann, C; Bazilevsky, A; Belikov, S; Belmont, R; Bennett, R; Berdnikov, A; Berdnikov, Y; Bhom, J H; Bickley, A A; Bjorndal, M T; Blau, D S; Boissevain, J G; Bok, J S; Borel, H; Boyle, K; Brooks, M L; Brown, D S; Bucher, D; Buesching, H; Bumazhnov, V; Bunce, G; Burward-Hoy, J M; Butsyk, S; Camacho, C M; Campbell, S; Caringi, A; Chai, J -S; Chang, B S; Charvet, J -L; Chen, C -H; Chernichenko, S; Chi, C Y; Chiba, J; Chiu, M; Choi, I J; Choi, J B; Choudhury, R K; Christiansen, P; Chujo, T; Chung, P; Churyn, A; Chvala, O; Cianciolo, V; Citron, Z; Cleven, C R; Cobigo, Y; Cole, B A; Comets, M P; del Valle, Z Conesa; Connors, M; Constantin, P; Csanád, M; Csörgő, T; Dahms, T; Dairaku, S; Danchev, I; Das, K; Datta, A; David, G; Dayananda, M K; Deaton, M B; Dehmelt, K; Delagrange, H; Denisov, A; d'Enterria, D; Deshpande, A; Desmond, E J; Dharmawardane, K V; Dietzsch, O; Dion, A; Donadelli, M; Drachenberg, J L; Drapier, O; Drees, A; Drees, K A; Dubey, A K; Durham, J M; Durum, A; Dutta, D; Dzhordzhadze, V; D'Orazio, L; Edwards, S; Efremenko, Y V; Egdemir, J; Ellinghaus, F; Emam, W S; Engelmore, T; Enokizono, A; En'yo, H; Espagnon, B; Esumi, S; Eyser, K O; Fadem, B; Fields, D E; Finger, M; Finger, M; Fleuret, F; Fokin, S L; Forestier, B; Fraenkel, Z; Frantz, J E; Franz, A; Frawley, A D; Fujiwara, K; Fukao, Y; Fung, S -Y; Fusayasu, T; Gadrat, S; Garishvili, I; Gastineau, F; Germain, M; Glenn, A; Gong, H; Gonin, M; Gosset, J; Goto, Y; de Cassagnac, R Granier; Grau, N; Greene, S V; Grim, G; Perdekamp, M Grosse; Gunji, T; Gustafsson, H -Å; Hachiya, T; Henni, A Hadj; Haegemann, C; Haggerty, J S; Hagiwara, M N; Hahn, K I; Hamagaki, H; Hamblen, J; Han, R; Hanks, J; Harada, H; Hartouni, E P; Haruna, K; Harvey, M; Haslum, E; Hasuko, K; Hayano, R; He, X; Heffner, M; Hemmick, T K; Hester, T; Heuser, J M; Hiejima, H; Hill, J C; Hobbs, R; Hohlmann, M; Holmes, M; Holzmann, W; Homma, K; Hong, B; Horaguchi, T; Hornback, D; Huang, S; Hur, M G; Ichihara, T; Ichimiya, R; Ide, J; Iinuma, H; Ikeda, Y; Imai, K; Inaba, M; Inoue, Y; Isenhower, D; Isenhower, L; Ishihara, M; Isobe, T; Issah, M; Isupov, A; Ivanischev, D; Iwanaga, Y; Jacak, B V; Jia, J; Jiang, X; Jin, J; Jinnouchi, O; Johnson, B M; Jones, T; Joo, K S; Jouan, D; Jumper, D S; Kajihara, F; Kametani, S; Kamihara, N; Kamin, J; Kaneta, M; Kang, J H; Kanou, H; Kapustinsky, J; Karatsu, K; Kasai, M; Kawagishi, T; Kawall, D; Kawashima, M; Kazantsev, A V; Kelly, S; Kempel, T; Khanzadeev, A; Kijima, K M; Kikuchi, J; Kim, A; Kim, B I; Kim, D H; Kim, D J; Kim, E; Kim, E J; Kim, S H; Kim, Y -J; Kim, Y -S; Kim, Y J; Kinney, E; Kiriluk, K; Kiss, Á; Kistenev, E; Kiyomichi, A; Klay, J; Klein-Boesing, C; Kochenda, L; Kochetkov, V; Komkov, B; Konno, M; Koster, J; Kotchetkov, D; Kozlov, A; Král, A; Kravitz, A; Kroon, P J; Kubart, J; Kunde, G J; Kurihara, N; Kurita, K; Kurosawa, M; Kweon, M J; Kwon, Y; Kyle, G S; Lacey, R; Lai, Y S; Lajoie, J G; Lebedev, A; Bornec, Y Le; Leckey, S; Lee, D M; Lee, J; Lee, K; Lee, K B; Lee, K S; Lee, M K; Lee, T; Leitch, M J; Leite, M A L; Leitner, E; Lenzi, B; Li, X; Li, X H; Lichtenwalner, P; Liebing, P; Lim, H; Levy, L A Linden; Liška, T; Litvinenko, A; Liu, H; Liu, M X; Love, B; Luechtenborg, R; Lynch, D; Maguire, C F; Makdisi, Y I; Malakhov, A; Malik, M D; Manko, V I; Mannel, E; Mao, Y; Mašek, L; Masui, H; Matathias, F; McCain, M C; McCumber, M; McGaughey, P L; Means, N; Meredith, B; Miake, Y; Mibe, T; Mignerey, A C; Mikeš, P; Miki, K; Miller, T E; Milov, A; Mioduszewski, S; Mishra, G C; Mishra, M; Mitchell, J T; Mitrovski, M; Mohanty, A K; Moon, H J; Morino, Y; Morreale, A; Morrison, D P; Moss, J M; Moukhanova, T V; Mukhopadhyay, D; Murakami, T; Murata, J; Nagamiya, S; Nagata, Y; Nagle, J L; Naglis, M; Nagy, M I; Nakagawa, I; Nakamiya, Y; Nakamura, K R; Nakamura, T; Nakano, K; Nam, S; Newby, J; Nguyen, M; Nihashi, M; Norman, B E; Nouicer, R; Nyanin, A S; Nystrand, J; Oakley, C; O'Brien, E; Oda, S X; Ogilvie, C A; Ohnishi, H; Ojha, I D; Oka, M; Okada, K; Omiwade, O O; Onuki, Y; Oskarsson, A; Otterlund, I; Ouchida, M; Ozawa, K; Pak, R; Pal, D; Palounek, A P T; Pantuev, V; Papavassiliou, V; Park, I H; Park, J; Park, S K; Park, W J; Pate, S F; Pei, H; Peng, J -C; Pereira, H; Peresedov, V; Peressounko, D Yu; Petti, R; Pinkenburg, C; Pisani, R P; Proissl, M; Purschke, M L; Purwar, A K; Qu, H; Rak, J; Rakotozafindrabe, A; Ravinovich, I; Read, K F; Rembeczki, S; Reuter, M; Reygers, K; Riabov, V; Riabov, Y; Richardson, E; Roach, D; Roche, G; Rolnick, S D; Romana, A; Rosati, M

    2011-01-01

    The PHENIX experiment at the Relativistic Heavy Ion Collider (RHIC) has measured omega meson production via leptonic and hadronic decay channels in p+p, d+Au, Cu+Cu, and Au+Au collisions at sqrt(s_NN) = 200 GeV. The invariant transverse momentum spectra measured in different decay modes give consistent results. Measurements in the hadronic decay channel in Cu+Cu and Au+Au collisions show that omega production has a suppression pattern at high transverse momentum, similar to that of pi^0 and eta in central collisions, but no suppression is observed in peripheral collisions. The nuclear modification factors, R_AA, are consistent in Cu+Cu and Au+Au collisions at similar numbers of participant nucleons.

  12. Production of ω mesons in p + p, d + Au, Cu + Cu, and Au + Au collisions at sNN=200 GeV

    Science.gov (United States)

    Adare, A.; Afanasiev, S.; Aidala, C.; Ajitanand, N. N.; Akiba, Y.; Al-Bataineh, H.; Al-Jamel, A.; Alexander, J.; Angerami, A.; Aoki, K.; Apadula, N.; Aphecetche, L.; Aramaki, Y.; Armendariz, R.; Aronson, S. H.; Asai, J.; Atomssa, E. T.; Averbeck, R.; Awes, T. C.; Azmoun, B.; Babintsev, V.; Bai, M.; Baksay, G.; Baksay, L.; Baldisseri, A.; Barish, K. N.; Barnes, P. D.; Bassalleck, B.; Basye, A. T.; Bathe, S.; Batsouli, S.; Baublis, V.; Bauer, F.; Baumann, C.; Bazilevsky, A.; Belikov, S.; Belmont, R.; Bennett, R.; Berdnikov, A.; Berdnikov, Y.; Bhom, J. H.; Bickley, A. A.; Bjorndal, M. T.; Blau, D. S.; Boissevain, J. G.; Bok, J. S.; Borel, H.; Boyle, K.; Brooks, M. L.; Brown, D. S.; Bucher, D.; Buesching, H.; Bumazhnov, V.; Bunce, G.; Burward-Hoy, J. M.; Butsyk, S.; Camacho, C. M.; Campbell, S.; Caringi, A.; Chai, J.-S.; Chang, B. S.; Charvet, J.-L.; Chen, C.-H.; Chernichenko, S.; Chi, C. Y.; Chiba, J.; Chiu, M.; Choi, I. J.; Choi, J. B.; Choudhury, R. K.; Christiansen, P.; Chujo, T.; Chung, P.; Churyn, A.; Chvala, O.; Cianciolo, V.; Citron, Z.; Cleven, C. R.; Cobigo, Y.; Cole, B. A.; Comets, M. P.; Conesa Del Valle, Z.; Connors, M.; Constantin, P.; Csanád, M.; Csörgő, T.; Dahms, T.; Dairaku, S.; Danchev, I.; Das, K.; Datta, A.; David, G.; Dayananda, M. K.; Deaton, M. B.; Dehmelt, K.; Delagrange, H.; Denisov, A.; D'Enterria, D.; Deshpande, A.; Desmond, E. J.; Dharmawardane, K. V.; Dietzsch, O.; Dion, A.; Donadelli, M.; Drachenberg, J. L.; Drapier, O.; Drees, A.; Drees, K. A.; Dubey, A. K.; Durham, J. M.; Durum, A.; Dutta, D.; Dzhordzhadze, V.; D'Orazio, L.; Edwards, S.; Efremenko, Y. V.; Egdemir, J.; Ellinghaus, F.; Emam, W. S.; Engelmore, T.; Enokizono, A.; En'yo, H.; Espagnon, B.; Esumi, S.; Eyser, K. O.; Fadem, B.; Fields, D. E.; Finger, M.; Finger, M., Jr.; Fleuret, F.; Fokin, S. L.; Forestier, B.; Fraenkel, Z.; Frantz, J. E.; Franz, A.; Frawley, A. D.; Fujiwara, K.; Fukao, Y.; Fung, S.-Y.; Fusayasu, T.; Gadrat, S.; Garishvili, I.; Gastineau, F.; Germain, M.; Glenn, A.; Gong, H.; Gonin, M.; Gosset, J.; Goto, Y.; Granier de Cassagnac, R.; Grau, N.; Greene, S. V.; Grim, G.; Grosse Perdekamp, M.; Gunji, T.; Gustafsson, H.-Å.; Hachiya, T.; Hadj Henni, A.; Haegemann, C.; Haggerty, J. S.; Hagiwara, M. N.; Hahn, K. I.; Hamagaki, H.; Hamblen, J.; Han, R.; Hanks, J.; Harada, H.; Hartouni, E. P.; Haruna, K.; Harvey, M.; Haslum, E.; Hasuko, K.; Hayano, R.; He, X.; Heffner, M.; Hemmick, T. K.; Hester, T.; Heuser, J. M.; Hiejima, H.; Hill, J. C.; Hobbs, R.; Hohlmann, M.; Holmes, M.; Holzmann, W.; Homma, K.; Hong, B.; Horaguchi, T.; Hornback, D.; Huang, S.; Hur, M. G.; Ichihara, T.; Ichimiya, R.; Ide, J.; Iinuma, H.; Ikeda, Y.; Imai, K.; Inaba, M.; Inoue, Y.; Isenhower, D.; Isenhower, L.; Ishihara, M.; Isobe, T.; Issah, M.; Isupov, A.; Ivanischev, D.; Iwanaga, Y.; Jacak, B. V.; Jia, J.; Jiang, X.; Jin, J.; Jinnouchi, O.; Johnson, B. M.; Jones, T.; Joo, K. S.; Jouan, D.; Jumper, D. S.; Kajihara, F.; Kametani, S.; Kamihara, N.; Kamin, J.; Kaneta, M.; Kang, J. H.; Kanou, H.; Kapustinsky, J.; Karatsu, K.; Kasai, M.; Kawagishi, T.; Kawall, D.; Kawashima, M.; Kazantsev, A. V.; Kelly, S.; Kempel, T.; Khanzadeev, A.; Kijima, K. M.; Kikuchi, J.; Kim, A.; Kim, B. I.; Kim, D. H.; Kim, D. J.; Kim, E.; Kim, E. J.; Kim, S. H.; Kim, Y.-J.; Kim, Y.-S.; Kim, Y. J.; Kinney, E.; Kiriluk, K.; Kiss, Á.; Kistenev, E.; Kiyomichi, A.; Klay, J.; Klein-Boesing, C.; Kochenda, L.; Kochetkov, V.; Komkov, B.; Konno, M.; Koster, J.; Kotchetkov, D.; Kozlov, A.; Král, A.; Kravitz, A.; Kroon, P. J.; Kubart, J.; Kunde, G. J.; Kurihara, N.; Kurita, K.; Kurosawa, M.; Kweon, M. J.; Kwon, Y.; Kyle, G. S.; Lacey, R.; Lai, Y. S.; Lajoie, J. G.; Lebedev, A.; Le Bornec, Y.; Leckey, S.; Lee, D. M.; Lee, J.; Lee, K.; Lee, K. B.; Lee, K. S.; Lee, M. K.; Lee, T.; Leitch, M. J.; Leite, M. A. L.; Leitner, E.; Lenzi, B.; Li, X.; Li, X. H.; Lichtenwalner, P.; Liebing, P.; Lim, H.; Linden Levy, L. A.; Liška, T.; Litvinenko, A.; Liu, H.; Liu, M. X.; Love, B.; Luechtenborg, R.; Lynch, D.; Maguire, C. F.; Makdisi, Y. I.; Malakhov, A.; Malik, M. D.; Manko, V. I.; Mannel, E.; Mao, Y.; Mašek, L.; Masui, H.; Matathias, F.; McCain, M. C.; McCumber, M.; McGaughey, P. L.; Means, N.; Meredith, B.; Miake, Y.; Mibe, T.; Mignerey, A. C.; Mikeš, P.; Miki, K.; Miller, T. E.; Milov, A.; Mioduszewski, S.; Mishra, G. C.; Mishra, M.; Mitchell, J. T.; Mitrovski, M.; Mohanty, A. K.; Moon, H. J.; Morino, Y.; Morreale, A.; Morrison, D. P.; Moss, J. M.; Moukhanova, T. V.; Mukhopadhyay, D.; Murakami, T.; Murata, J.; Nagamiya, S.; Nagata, Y.; Nagle, J. L.; Naglis, M.; Nagy, M. I.; Nakagawa, I.; Nakamiya, Y.; Nakamura, K. R.; Nakamura, T.; Nakano, K.; Nam, S.; Newby, J.; Nguyen, M.; Nihashi, M.; Norman, B. E.; Nouicer, R.; Nyanin, A. S.; Nystrand, J.; Oakley, C.; O'Brien, E.; Oda, S. X.; Ogilvie, C. A.; Ohnishi, H.; Ojha, I. D.; Oka, M.; Okada, K.; Omiwade, O. O.; Onuki, Y.; Oskarsson, A.; Otterlund, I.; Ouchida, M.; Ozawa, K.; Pak, R.; Pal, D.; Palounek, A. P. T.; Pantuev, V.; Papavassiliou, V.; Park, I. H.; Park, J.; Park, S. K.; Park, W. J.; Pate, S. F.; Pei, H.; Peng, J.-C.; Pereira, H.; Peresedov, V.; Peressounko, D. Yu.; Petti, R.; Pinkenburg, C.; Pisani, R. P.; Proissl, M.; Purschke, M. L.; Purwar, A. K.; Qu, H.; Rak, J.; Rakotozafindrabe, A.; Ravinovich, I.; Read, K. F.; Rembeczki, S.; Reuter, M.; Reygers, K.; Riabov, V.; Riabov, Y.; Richardson, E.; Roach, D.; Roche, G.; Rolnick, S. D.; Romana, A.; Rosati, M.; Rosen, C. A.; Rosendahl, S. S. E.; Rosnet, P.; Rukoyatkin, P.; Ružička, P.; Rykov, V. L.; Ryu, S. S.; Sahlmueller, B.; Saito, N.; Sakaguchi, T.; Sakai, S.; Sakashita, K.; Sakata, H.; Samsonov, V.; Sano, S.; Sato, H. D.; Sato, S.; Sato, T.; Sawada, S.; Sedgwick, K.; Seele, J.; Seidl, R.; Semenov, A. Yu.; Semenov, V.; Seto, R.; Sharma, D.; Shea, T. K.; Shein, I.; Shevel, A.; Shibata, T.-A.; Shigaki, K.; Shimomura, M.; Shohjoh, T.; Shoji, K.; Shukla, P.; Sickles, A.; Silva, C. L.; Silvermyr, D.; Silvestre, C.; Sim, K. S.; Singh, B. K.; Singh, C. P.; Singh, V.; Skutnik, S.; Slunečka, M.; Smith, W. C.; Soldatov, A.; Soltz, R. A.; Sondheim, W. E.; Sorensen, S. P.; Sourikova, I. V.; Sparks, N. A.; Staley, F.; Stankus, P. W.; Stenlund, E.; Stepanov, M.; Ster, A.; Stoll, S. P.; Sugitate, T.; Suire, C.; Sukhanov, A.; Sullivan, J. P.; Sziklai, J.; Tabaru, T.; Takagi, S.; Takagui, E. M.; Taketani, A.; Tanabe, R.; Tanaka, K. H.; Tanaka, Y.; Taneja, S.; Tanida, K.; Tannenbaum, M. J.; Tarafdar, S.; Taranenko, A.; Tarján, P.; Themann, H.; Thomas, D.; Thomas, T. L.; Togawa, M.; Toia, A.; Tojo, J.; Tomášek, L.; Torii, H.; Towell, R. S.; Tram, V.-N.; Tserruya, I.; Tsuchimoto, Y.; Tuli, S. K.; Tydesjö, H.; Tyurin, N.; Vale, C.; Valle, H.; van Hecke, H. W.; Vazquez-Zambrano, E.; Veicht, A.; Velkovska, J.; Vértesi, R.; Vinogradov, A. A.; Virius, M.; Vrba, V.; Vznuzdaev, E.; Wagner, M.; Walker, D.; Wang, X. R.; Watanabe, D.; Watanabe, K.; Watanabe, Y.; Wei, F.; Wei, R.; Wessels, J.; White, S. N.; Willis, N.; Winter, D.; Wood, J. P.; Woody, C. L.; Wright, R. M.; Wysocki, M.; Xie, W.; Yamaguchi, Y. L.; Yamaura, K.; Yang, R.; Yanovich, A.; Yasin, Z.; Ying, J.; Yokkaichi, S.; You, Z.; Young, G. R.; Younus, I.; Yushmanov, I. E.; Zajc, W. A.; Zaudtke, O.; Zhang, C.; Zhou, S.; Zimányi, J.; Zolin, L.

    2011-10-01

    The PHENIX experiment at the Relativistic Heavy Ion Collider has measured ω meson production via leptonic and hadronic decay channels in p+p, d+Au, Cu+Cu, and Au+Au collisions at sNN = 200 GeV. The invariant transverse momentum spectra measured in different decay modes give consistent results. Measurements in the hadronic decay channel in Cu+Cu and Au+Au collisions show that ω production has a suppression pattern at high transverse momentum, similar to that of π0 and η in central collisions, but no suppression is observed in peripheral collisions. The nuclear modification factors, RAA, are consistent in Cu+Cu and Au+Au collisions at similar numbers of participant nucleons.

  13. Revisiting the S-Au(111) interaction: Static or Dynamic?

    Energy Technology Data Exchange (ETDEWEB)

    Biener, M M; Biener, J; Friend, C M

    2004-08-17

    The chemical inertness typically observed for Au does not imply a general inability to form stable bonds with non-metals but is rather a consequence of high reaction barriers. The Au-S interaction is probably the most intensively studied interaction of Au surfaces with non-metals as, for example, it plays an important role in Au ore formation, and controls the structure and dynamics of thiol-based self-assembled-monolayers (SAMs). In recent years a quite complex picture of the interaction of sulfur with Au(111) surfaces emerged, and a variety of S-induced surface structures was reported under different conditions. The majority of these structures were interpreted in terms of a static Au surface, where the positions of the Au atoms remain essentially unperturbed. Here we demonstrate that the Au(111) surface exhibits a very dynamic character upon interaction with adsorbed sulfur: low sulfur coverages modify the surface stress of the Au surface leading to lateral expansion of the surface layer; large-scale surface restructuring and incorporation of Au atoms into a growing two-dimensional AuS phase were observed with increasing sulfur coverage. These results provide new insight into the Au-S surface chemistry, and reveal the dynamic character of the Au(111) surface.

  14. First steps of ion beam mixing: study by X-ray reflectometry and neutron diffraction; Premieres etapes du melange par faisceau d`ions: etude par reflectometrie de rayons X et diffraction de neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Le Boite, M.G.

    1987-12-01

    There are several processes involved in ion beam mixing: ballistic processes, chemical driving forces and radiation enhanced diffusion. Experiments usually performed on bilayers irradiated with heavy elements and characterized by Rutherford backscattering (R.B.S.), have shown that the measured mixing rate is always higher than the calculated one, taking into account ballistic effects only. Besides classical R.B.S. experiments on NiAu and NiPt bilayers irradiated with Xe, we have used another technique of characterization: X-ray reflectometry and neutron diffraction, performed on multilayers irradiated with He. The systems are NiAu, NiPt, NiPd and NiAg, which behave similarly from the ballistic point of view, but have very different heats of mixing. In these experiments, the range of deposited energy density is very low, in contrast to heavy ions irradiation: this has allowed us to reach very low diffusion coefficent, never observed before. The dependence of the diffusion coefficient on the heat of mixing is in agreement with the one theoretically calculated. For the NiAg system, which has a positive heat of mixing, the measured diffusion coefficient is smaller than the ballistic one: a decrease of the ballistic mixing rate is seen for the first time. In this work, we have shown the interest of the reflectometry techniques (X-ray and neutrons); we have used a simple model to analyze the ion beam mixing, when elementary processes are involved.

  15. Contribution to the study of the biological properties of compounds labeled with radio-chromium {sup 51}Cr; Contribution a l'etude des proprietes biologiques des composes marques au radiochrome {sup 51}Cr

    Energy Technology Data Exchange (ETDEWEB)

    Ingrand, J. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-15

    Among the radioisotopes commonly used in biology and medicine which are controlled Individually in the Radioelement Departement of the Saclay Nuclear Research Centre before being sent to the users, the author has chosen chromium 51 incorporated in inorganic salts or in organic substrates for a study of the biological properties of the compounds. In the first part, he has compared the pathways followed by the radioactive sodium chromate and chromic chloride mixed with blood or given to the whole animal, the object being to determine whether a reduction of hexavalent chromium occurs, both in vitro and in vivo. In the second part, the author has tried to show the validity of using, various substrates labeled with chromium 51, red cells, haemoglobin, plasma proteins and cytochrome c. The results obtained have contributed to underline the interest of using such compounds for biological applications. (author) [French] Parmi les radioisotopes d'utilisation courants en biologie et en medecine qui sont l'objet d'un controle particulier dans le Departement des Radioelements du Centre d'Etudes Nucleaires de Saclay avant leur diffusion aux utilisateurs, l'auteur a choisi le chrome 51 incorpore a des sels mineraux ou a des substrats organiques, afin d'en etudier les proprietes biologiques. Dans la premiere partie, il a compare le sort du chromate de sodium et du chlorure chromique radioactifs melanges a du sang ou administres a l'animal entier en s'efforcant de mettre en evidence une reduction du chrome hexavalent aussi bien in vitro qu'in vivo. Dans la deuxieme partie, il a cherche a etablir la validite de l'emploi de differents substrats marques au chrome 51, l'hematie, l'hemoglobine, les proteines plasmatiques et le cytochrome c. Les resultats obtenus ont permis de souligner le reel interet des applications biologiques des composes marques par le radioisotope. (auteur)

  16. 2010 Port-au-Prince, Haiti Images

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — According to official estimates, 222,570 people killed, 300,000 injured, 1.3 million displaced, 97,294 houses destroyed and 188,383 damaged in the Port-au-Prince...

  17. Surface structure of AU3Cu(001)

    DEFF Research Database (Denmark)

    Eckstein, G.A.; Maupai, S.; Dakkouri, A.S.;

    1999-01-01

    The surface morphology, composition, and structure of Au3Cu(001) as determined by scanning tunneling microscopy and surface x-ray diffraction are presented. Atomic resolution STM images reveal distinctive geometric features. The analysis of the surface x-ray diffraction data provides clear evidence...... for the surface structure. [S0163-1829(99)04535-X]....

  18. Didaktik des außerschulischen Lernens

    CERN Document Server

    Sauerborn, Petra

    2012-01-01

    Kernprobleme schulischer Bildung sind die zunehmenden Verluste an Realitäts- und Praxisbezug sowie die einseitige Betonung der fachwissenschaftlichen Kenntnisse. In jüngster Zeit werden insbesondere moderne didaktisch-methodische Konzepte näher diskutiert und praktiziert. So finden sich etwa die Stichwörter Handlungsorientierter Unterricht und Offener Unterricht in der fachdidaktischen Diskussion wieder. Eine wesentlich aktuellere Form stellt das außerschulische Lernen dar. Ein modernes pädagogisches Verständnis sieht den Unterricht heute nicht mehr als ausschließliche Tätigkeit des Lehrers an, sondern als Aktivität der Lernenden. Außerschulisches Lernen beschreibt die originale Begegnung im Unterricht außerhalb des Klassenzimmers. An außerschulischen Lernorten findet eine unmittelbare AuseinanderSetzung des Lernenden mit seiner räumlichen Umgebung statt. Charakteristisch sind hierbei vor allem die aktive(Mit-)Gestaltung sowie die eigenständige Wahrnehmung mehrperspektivischer Bildungsinhalte d...

  19. Stability of gold cages (Au16 and Au17) at finite temperature

    Indian Academy of Sciences (India)

    Prachi Chandrachud; Kavita Joshi; Sailaja Krishnamurty; D G Kanhere

    2009-05-01

    We have employed ab initio molecular dynamics to investigate the stability of the smallest gold cages, namely Au16 and Au17, at finite temperatures. First, we obtain the ground state structure along with at least 50 distinct isomers for both the clusters. This is followed by the finite temperature simulations of these clusters. Each cluster is maintained at 12 different temperatures for a time period of at least 150 ps. Thus, the total simulation time is of the order of 2.4 ns for each cluster. We observe that the cages are stable at least up to 850 K. Although both clusters melt around the same temperature, i.e. around 900 K, Au17 shows a peak in the heat capacity curve in contrast to the broad peak seen for Au16.

  20. Dispersion and STM Characterization of Au-CdSe Nanohybrids on Au(111)

    Institute of Scientific and Technical Information of China (English)

    Bo Gao; Yan-min Kuang; Yuan Liao; Zhen-chao Dong

    2012-01-01

    We report the dispersion and scanning tunneling microscopy (STM) characterization of isolated Au-CdSe nanohybrids on atomically flat Au(111) through surface modifications.The top terminal groups of spacer molecules self-assembled on the surface are found critical for locking the nanohybrids into a well-separated state.The STM results indicate that both thiol and carboxylic terminals are effective in this aspect by making strong interaction with the Au portions of the nanohybrids.An argon ion sputtering technique is also proposed to clean up organic contaminants on the surface for improved STM imaging of individual Au-CdSe nanohybrids.These observations help to enrich technical approaches to dispersing individual nanostructures on the surface and provide opportunities to explore their local electroluminescent and energy transfer properties at the nanoscale.

  1. High Resolution Photoelectron Spectroscopy of Au_2^- and Au_4^- by Photoelectron Imaging

    Science.gov (United States)

    Leon, Iker; Yang, Zheng; Wang, Lai-Sheng

    2013-06-01

    We report high resolution photoelectron spectra of Au_2^- and Au_4^- obtained with a newly-built photoelectron imaging apparatus. Gold anions are produced by laser vaporization and the desired specie is mass selected and focused into the collinear velocity-map imaging (VMI) lens assembly. The design of the imaging lens has allowed us to obtain less than 0.9% energy resolution for high kinetic energy electrons ( > 1eV) while maintaining wavenumber resolution for low kinetic energy electrons. Although gold dimer and tetramer have been studied in the past, we present spectroscopic results under high resolution. For Au_2^-, we report high resolution spectra with an accurate determination of the electron affinity together with a complete vibrational assignment, for both the anion and neutral ground states, while for Au_4^-, we are able to resolve a low frequency mode and obtain accurately the adiabatic detachment energy.

  2. Forward-backward multiplicity correlation in Au+Au collisions at RHIC with transport model PACIAE

    CERN Document Server

    Yan, Yu-Liang; Dong, Bao-Guo; Li, Xiao-Mei; Ma, Hai-Liang; Sa, Ben-Hao

    2009-01-01

    We have studied the charged particle forward-backward multiplicity correlation strength in 0-10% most central Au+Au collisions at \\sqrt{s_{NN}}=200 GeV by a parton and hadron cascade model, PACIAE based on PYTHIA. The real (total), statistical, and NBD (Negative Binomial Distribution) correlation strengths are calculated, respectively, with the real events, mixed events, and NBD fitting the charged particle multiplicity distribution. The corresponding STAR data are well reproduced by the real one. If the discrepancy between real and statistical correlation strengths is identified as dynamical correlation strength, the dynamical correlation strength is then just counted few percent of the total correlation strength. In addition, we also calculated the 0-5 and 5% most central Au+Au collisions and turned out that the correlation strength increases monotonously with increasing size of the centrality bin.

  3. Simulation of energy scan of pion interferometry in central Au+Au collisions at relativistic energies

    International Nuclear Information System (INIS)

    We present a systematic analysis of two-pion interferometry for the central Au+Au collisions at √sNN = 3, 5, 7, 11, 17, 27, 39, 62, 130 and 200 GeV/c with the help of a multiphase transport (AMPT) model. Emission source-size radius parameters Rlong, Rout, Rside and the chaotic parameter λ are extracted and compared with the experimental data. Transverse momentum and azimuthal angle dependencies of the HBT radii are also discussed for central Au+Au collisions at 200 GeV/c. The results show that the HBT radii in central collisions do not change much above 7 GeV/c. For central collisions at 200 GeV/c, the radii decrease with the increasing of transverse momentum pT but are not sensitive to the azimuthal angle. These results provide a theoretical reference for the energy scan program of the RHIC-STAR experiment. (authors)

  4. Charged-particle pseudorapidity distributions in Au+Au collisions at RHIC

    Institute of Scientific and Technical Information of China (English)

    WANG Zeng-Wei; JIANG Zhi-Jin

    2009-01-01

    Using the Glauber model, we present the formulas for calculating the numbers of participants,spectators and binary nucleon-nucleon collisions. Based on this work, we get the pseudorapidity distributions of charged particles as the function of the impact parameter in nucleus-nucleus collisions. The theoretical results agree well with the experimental observations made by the BRAHMS Collaboration in Au+Au collisions at √SNN=200 GeV in different centrality bins over the whole pseudorapidity range.

  5. Baryonic Effect on XcJ Suppression in Au+Au Collisions at RHIC Energies

    Institute of Scientific and Technical Information of China (English)

    PENG Ru; XU Xiao-Ming; ZHOU Dai-Cui

    2004-01-01

    @@ We predict that xcJ mesons at low transverse momentum in the central rapidity region are almost dissociated by nucleons and antinucleons in hadronic matter produced in central Au+Au collisions at relativistic high-ion collider (RHIC) energies √SNN = 130 and 200 GeV. In the calculations the nucleon and antinucleon distributions in hadronic matter are results of evolution from their freeze-out distributions which well fit the experimental transverse momentum spectra of proton and antiproton.

  6. Flow and bose-einstein correlations in Au-Au collisions at RHIC

    Science.gov (United States)

    Phobos Collaboration; Manly, Steven; Back, B. B.; Baker, M. D.; Barton, D. S.; Betts, R. R.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Decowski, M. P.; Garcia, E.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Henderson, C.; Hofman, D.; Hollis, R. S.; Hołyinski, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C. M.; Lin, W. T.; Manly, S.; McLeod, D.; Michałowski, J.; Mignerey, A.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Remsberg, L. P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Skulski, W.; Steadman, S. G.; Steinberg, P.; Stephans, G. S. F.; Stodulski, M.; Sukhanov, A.; Tang, J.-L.; Teng, R.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Verdier, R.; Wadsworth, B.; Wolfs, F. L. H.; Wosiek, B.; Woźniak, K.; Wuosmaa, A. H.; Wysłouch, B.

    2003-03-01

    Argonne flow and Bose-Einstein correlations have been measured in Au-Au collisions at S=130 and 200 GeV using the PHOBOS detector at RHIC. The systematic dependencies of the flow signal on the transverse momentum, pseudorapidity, and centrality of the collision, as well as the beam energy are shown. In addition, results of a 3-dimensional analysis of two-pion correlations in the 200 GeV data are presented.

  7. Results from experiment E917 for Au + Au collisions at the AGS

    International Nuclear Information System (INIS)

    The effects of baryon stopping and its resulting energy deposition on the dynamics of Au + Au collisions at 6, 8 and 10.8 GeV/nucleon are explored with recent results from the AGS experiment E917. Current analyses of stopping, collective flow signals and HBT parameters are presented. Strangeness and anti-baryon production is examined using the yields of anti-lambdas and anti-protons

  8. Net baryon density in Au+Au collisions at the Relativistic Heavy Ion Collider

    CERN Document Server

    Bass, S A; Srivastava, D K; Bass, Steffen A.; Müller, Berndt; Srivastava, Dinesh K.

    2003-01-01

    We calculate the net baryon rapidity distribution in Au+Au collisions at the Relativistic Heavy Ion Collider (RHIC) in the framework of the Parton Cascade Model (PCM). Parton rescattering and fragmentation leads to a substantial increase in the net baryon density at mid-rapidity over the density produced by initial primary parton-parton scatterings. The PCM is able to describe the measured net baryon density at RHIC.

  9. Some thoughts on di-jet correlation in Au + Au collisions from PHENIX

    CERN Document Server

    Jia, J

    2006-01-01

    PHENIX has measured the two particle azimuth correlation in Au + Au at $\\sqrt{s}$ = 200 GeV. Jet shape and yield at the away side are found to be strongly modified at intermediate and low $p_T$, and the modifications vary dramatically with $p_T$ and centrality. At high $p_T$, away side jet peak reappears but the yield is suppressed. We discuss the possible physics pictures leading to these complicated modifications.

  10. Anti-flow of K$^0_s$ Mesons in 6 AGeV Au + Au Collisions

    CERN Document Server

    Chung, P; Alexander, J M; Anderson, M; Best, D; Brady, F P; Case, T; Caskey, W; Cebra, D; Chance, J L; Cole, B; Crowe, K M; Das, A; Draper, J E; Gilkes, M L; Gushue, S; Heffner, M; Hirsch, A S; Hjort, E L; Huo, L; Justice, M; Kaplan, M; Keane, D; Kintner, J C; Klay, J L; Krofcheck, D; Lacey, R A; Lauret, J; Lisa, M A; Liu, H; Liu, Y M; McGrath, R; Milosevich, Z; Odyniec, Grazyna Janina; Olson, D L; Panitkin, S Y; Pinkenburg, C H; Porile, N T; Rai, G; Ritter, H G; Romero, J L; Scharenberg, R P; Schröder, L; Srivastava, B; BStone, N T; Symons, T J M; Wienold, T; Whitfield, R W J; Wood, L; Zhang Wei Ning

    2000-01-01

    We have measured the sideward flow of neutral strange ($K^0_s$) mesons in 6 AGeV Au + Au collisions. A prominent anti-flow signal is observed for an impact parameter range (b $\\lesssim 7$ fm) which spans central and mid-central events. Since the $K^0_s$ scattering cross section is relatively small in nuclear matter, this observation suggests that the in-medium kaon vector potential plays an important role in high density nuclear matter.

  11. Critical Behavior in Peripheral Au + Au Collisions at 35 MeV/u

    CERN Document Server

    Bruno, M; Belkacem, M; Agostino, M D; Milazzo, P M; Vannini, G; Bowman, D R; Dinius, J D; Ferrero, A; Fiandri, M L; Gelbke, C K; Glasmacher, T; Gramegna, F; Handzy, D O; Horn, D; Hsi, W C; Huang, M; Iori, I; Kunde, G J; Lisa, M A; Lynch, W G; Margagliotti, G V; Montoya, C P; Moroni, A; Peaslee, G F; Rui, R; Schwarz, C; Tsang, M B; Williams, C; Latora, V; Bonasera, A

    1996-01-01

    The signals theoretically predicted for the occurrence of a critical behavior (conditional moments of charge distributions, Campi scatter plot, fluctuations of the size of the largest fragment, power law in the charge distribution, intermittency) have been found for peripheral events in the reaction Au+Au at 35 MeV/u. The same signals have been studied with a dynamical model which foresees phase transition, like the Classical Molecular Dynamics.

  12. Nuclear modification factors of phi mesons in d+Au, Cu+Cu and Au+Au collisions at sqrt(S_NN)=200 GeV

    CERN Document Server

    Adare, A; Aidala, C; Ajitanand, N N; Akiba, Y; Al-Bataineh, H; Alexander, J; Al-Jamel, A; Angerami, A; Aoki, K; Aphecetche, L; Aramaki, Y; Armendariz, R; Aronson, S H; Asai, J; Atomssa, E T; Averbeck, R; Awes, T C; Azmoun, B; Babintsev, V; Bai, M; Baksay, G; Baksay, L; Baldisseri, A; Barish, K N; Barnes, P D; Bassalleck, B; Basye, A T; Bathe, S; Batsouli, S; Baublis, V; Bauer, F; Baumann, C; Bazilevsky, A; Belikov, S; Belmont, R; Bennett, R; Berdnikov, A; Berdnikov, Y; Bhom, J H; Bickley, A A; Bjorndal, M T; Blau, D S; Boissevain, J G; Bok, J S; Borel, H; Borggren, N; Boyle, K; Brooks, M L; Brown, D S; Bucher, D; Buesching, H; Bumazhnov, V; Bunce, G; Burward-Hoy, J M; Butsyk, S; Campbell, S; Caringi, A; Cassano, N; Chai, J -S; Chang, B S; Charvet, J -L; Chen, C -H; Chernichenko, S; Chiba, J; Chi, C Y; Chiu, M; Choi, I J; Choi, J B; Choudhury, R K; Christiansen, P; Chujo, T; Chung, P; Churyn, A; Chvala, O; Cianciolo, V; Citron, Z; Cleven, C R; Cobigo, Y; Cole, B A; Comets, M P; del Valle, Z Conesa; Connors, M; Constantin, P; Csanad, M; Csorgo, T; Dahms, T; Dairaku, S; Danchev, I; Das, K; Datta, A; David, G; Dayananda, M K; Deaton, M B; Dehmelt, K; Delagrange, H; Denisov, A; d'Enterria, D; Deshpande, A; Desmond, E J; Dharmawardane, K V; Dietzsch, O; Dion, A; Donadelli, M; Orazio, L D; Drachenberg, J L; Drapier, O; Drees, A; Drees, K A; Dubey, A K; Durham, J M; Durum, A; Dutta, D; Dzhordzhadze, V; Edwards, S; Efremenko, Y V; Egdemir, J; Ellinghaus, F; Emam, W S; Engelmore, T; Enokizono, A; En'yo, H; Espagnon, B; Esumi, S; Eyser, K O; Fadem, B; Fields, D E; Finger, M; Finger, M; Fleuret, F; Fokin, S L; Forestier, B; Fraenkel, Z; Frantz, J E; Franz, A; Frawley, A D; Fujiwara, K; Fukao, Y; Fung, S -Y; Fusayasu, T; Gadrat, S; Garishvili, I; Gastineau, F; Germain, M; Glenn, A; Gong, H; Gonin, M; Gosset, J; Goto, Y; de Cassagnac, R Granier; Grau, N; Greene, S V; Grim, G; Perdekamp, M Grosse; Gunji, T; Gustafsson, H -A; Hachiya, T; Henni, A Hadj; Haegemann, C; Haggerty, J S; Hagiwara, M N; Hahn, K I; Hamagaki, H; Hamblen, J; Hanks, J; Han, R; Harada, H; Hartouni, E P; Haruna, K; Harvey, M; Haslum, E; Hasuko, K; Hayano, R; Heffner, M; Hemmick, T K; Hester, T; Heuser, J M; He, X; Hiejima, H; Hill, J C; Hobbs, R; Hohlmann, M; Holmes, M; Holzmann, W; Homma, K; Hong, B; Horaguchi, T; Hornback, D; Huang, S; Hur, M G; Ichihara, T; Ichimiya, R; Iinuma, H; Ikeda, Y; Imai, K; Inaba, M; Inoue, Y; Isenhower, D; Isenhower, L; Ishihara, M; Isobe, T; Issah, M; Isupov, A; Ivanischev, D; Iwanaga, Y; Jacak, B V; Jia, J; Jiang, X; Jin, J; Jinnouchi, O; Johnson, B M; Jones, T; Joo, K S; Jouan, D; Jumper, D S; Kajihara, F; Kametani, S; Kamihara, N; Kamin, J; Kaneta, M; Kang, J H; Kanou, H; Kapustinsky, J; Karatsu, K; Kasai, M; Kawagishi, T; Kawall, D; Kawashima, M; Kazantsev, A V; Kelly, S; Kempel, T; Khanzadeev, A; Kijima, K M; Kikuchi, J; Kim, A; Kim, B I; Kim, D H; Kim, D J; Kim, E J; Kim, E; Kim, Y -J; Kim, Y -S; Kinney, E; Kiss, A; Kistenev, E; Kiyomichi, A; Klay, J; Klein-Boesing, C; Kochenda, L; Kochetkov, V; Komkov, B; Konno, M; Koster, J; Kotchetkov, D; Kotov, D; Kozlov, A; Kral, A; Kravitz, A; Kroon, P J; Kubart, J; Kunde, G J; Kurihara, N; Kurita, K; Kurosawa, M; Kweon, M J; Kwon, Y; Kyle, G S; Lacey, R; Lai, Y S; Lajoie, J G; Lebedev, A; Le Bornec, Y; Leckey, S; Lee, D M; Lee, J; Lee, K B; Lee, K S; Lee, M K; Lee, T; Leitch, M J; Leite, M A L; Lenzi, B; Lichtenwalner, P; Liebing, P; Lim, H; Levy, L A Linden; Liska, T; Litvinenko, A; Liu, H; Liu, M X; Li, X; Li, X H; Love, B; Lynch, D; Maguire, C F; Makdisi, Y I; Malakhov, A; Malik, M D; Manko, V I; Mannel, E; Mao, Y; Masek, L; Masui, H; Matathias, F; McCain, M C; McCumber, M; McGaughey, P L; Means, N; Meredith, B; Miake, Y; Mibe, T; Mignerey, A C; Mikes, P; Miki, K; Miller, T E; Milov, A; Mioduszewski, S; Mishra, G C; Mishra, M; Mitchell, J T; Mitrovski, M; Mohanty, A K; Moon, H J; Morino, Y; Morreale, A; Morrison, D P; Moss, J M; Moukhanova, T V; Mukhopadhyay, D; Murakami, T; Murata, J; Nagamiya, S; Nagata, Y; Nagle, J L; Naglis, M; Nagy, M I; Nakagawa, I; Nakamiya, Y; Nakamura, K R; Nakamura, T; Nakano, K; Nam, S; Newby, J; Nguyen, M; Nihashi, M; Norman, B E; Nouicer, R; Nyanin, A S; Nystrand, J; Oakley, C; O'Brien, E; Oda, S X; Ogilvie, C A; Ohnishi, H; Ojha, I D; Okada, K; Oka, M; Omiwade, O O; Onuki, Y; Oskarsson, A; Otterlund, I; Ouchida, M; Ozawa, K; Pak, R; Pal, D; Palounek, A P T; Pantuev, V; Papavassiliou, V; Park, I H; Park, J; Park, S K; Park, W J; Pate, S F; Pei, H; Peng, J -C; Pereira, H; Peresedov, V; Peressounko, D Yu; Petti, R; Pinkenburg, C; Pisani, R P; Proissl, M; Purschke, M L; Purwar, A K; Qu, H; Rak, J; Rakotozafindrabe, A; Ravinovich, I; Read, K F; Rembeczki, S; Reuter, M; Reygers, K; Riabov, V; Riabov, Y; Richardson, E; Roach, D; Roche, G; Rolnick, S D; Romana, A; Rosati, M; Rosen, C A; Rosendahl, S S E; Rosnet, P; Rukoyatkin, P; Ruzicka, P; Rykov, V L

    2010-01-01

    The PHENIX experiment at the Relativistic Heavy Ion Collider (RHIC) has performed systematic measurements of phi meson production in the K+K- decay channel at midrapidity in p+p, d+Au, Cu+Cu and Au+Au collisions at sqrt(S_NN)=200 GeV. Results are presented on the phi invariant yield and the nuclear modification factor R_AA for Au+Au and Cu+Cu, and R_dA for d+Au collisions, studied as a function of transverse momentum (1Au+Au collisions, the R_AA of phi exhibits a suppression relative to expectations from binary scaled p+p results. The amount of suppression is smaller than that of the neutral pion and the eta meson in the intermediate p_T range (2--5 GeV/c); whereas at higher p_T the phi, pi^0, and eta show similar suppression. The baryon (protons and anti-protons) excess observed in central Au+Au collisions at intermediate p_T is not observed for the phi meson despite the similar mass of the proton and the phi. This suggests that the excess is lin...

  13. Suppression of Upsilon Production in d+Au and Au+Au Collisions at sqrt(s_NN) = 200 GeV

    CERN Document Server

    Adamczyk, L; Agakishiev, G; Aggarwal, M M; Ahammed, Z; Alekseev, I; Alford, J; Anson, C D; Aparin, A; Arkhipkin, D; Aschenauer, E C; Averichev, G S; Banerjee, A; Beavis, D R; Bellwied, R; Bhasin, A; Bhati, A K; Bhattarai, P; Bichsel, H; Bielcik, J; Bielcikova, J; Bland, L C; Bordyuzhin, I G; Borowski, W; Bouchet, J; Brandin, A V; Brovko, S G; Bültmann, S; Bunzarov, I; Burton, T P; Butterworth, J; Caines, H; Sánchez, M Calderón de la Barca; Cebra, D; Cendejas, R; Cervantes, M C; Chaloupka, P; Chang, Z; Chattopadhyay, S; Chen, H F; Chen, J H; Chen, L; Cheng, J; Cherney, M; Chikanian, A; Christie, W; Chwastowski, J; Codrington, M J M; Contin, G; Cramer, J G; Crawford, H J; Cui, X; Das, S; Leyva, A Davila; De Silva, L C; Debbe, R R; Dedovich, T G; Deng, J; Derevschikov, A A; de Souza, R Derradi; Dhamija, S; di Ruzza, B; Didenko, L; Dilks, C; Ding, F; Djawotho, P; Dong, X; Drachenberg, J L; Draper, J E; Du, C M; Dunkelberger, L E; Dunlop, J C; Efimov, L G; Engelage, J; Engle, K S; Eppley, G; Eun, L; Evdokimov, O; Fatemi, R; Fazio, S; Fedorisin, J; Filip, P; Finch, E; Fisyak, Y; Flores, C E; Gagliardi, C A; Gangadharan, D R; Garand, D; Geurts, F; Gibson, A; Girard, M; Gliske, S; Greiner, L; Grosnick, D; Guo, Y; Gupta, A; Gupta, S; Guryn, W; Haag, B; Hajkova, O; Hamed, A; Han, L-X; Haque, R; Harris, J W; Heppelmann, S; Hill, K; Hirsch, A; Hoffmann, G W; Hofman, D J; Horvat, S; Huang, B; Huang, H Z; Huang, X; Huck, P; Humanic, T J; Igo, G; Jacobs, W W; Jang, H; Judd, E G; Kabana, S; Kalinkin, D; Kang, K; Kauder, K; Ke, H W; Keane, D; Kechechyan, A; Kesich, A; Khan, Z H; Kikola, D P; Kisel, I; Kisiel, A; Koetke, D D; Kollegger, T; Konzer, J; Koralt, I; Kotchenda, L; Kravtsov, P; Krueger, K; Kulakov, I; Kumar, L; Kycia, R A; Lamont, M A C; Landgraf, J M; Landry, K D; Lauret, J; Lebedev, A; Lednicky, R; Lee, J H; LeVine, M J; Li, C; Li, W; Li, X; Li, Y; Li, Z M; Lima, L M; Lisa, M A; Liu, F; Ljubicic, T; Llope, W J; Lomnitz, M; Longacre, R S; Luo, X; Ma, G L; Ma, Y G; Don, D M M D Madagodagettige; Mahapatra, D P; Majka, R; Margetis, S; Markert, C; Masui, H; Matis, H S; McDonald, D; McShane, T S; Minaev, N G; Mioduszewski, S; Mohanty, B; Mondal, M M; Morozov, D A; Munhoz, M G; Mustafa, M K; Nandi, B K; Nasim, Md; Nayak, T K; Nelson, J M; Nigmatkulov, G; Nogach, L V; Noh, S Y; Novak, J; Nurushev, S B; Odyniec, G; Ogawa, A; Oh, K; Ohlson, A; Okorokov, V; Oldag, E W; Oliveira, R A N; Pachr, M; Page, B S; Pal, S K; Pan, Y X; Pandit, Y; Panebratsev, Y; Pawlak, T; Pawlik, B; Pei, H; Perkins, C; Peryt, W; Peterson, A; Pile, P; Planinic, M; Pluta, J; Poljak, N; Porter, J; Poskanzer, A M; Pruthi, N K; Przybycien, M; Pujahari, P R; Putschke, J; Qiu, H; Quintero, A; Ramachandran, S; Raniwala, R; Raniwala, S; Ray, R L; Riley, C K; Ritter, H G; Roberts, J B; Rogachevskiy, O V; Romero, J L; Ross, J F; Roy, A; Ruan, L; Rusnak, J; Sahoo, N R; Sahu, P K; Sakrejda, I; Salur, S; Sandweiss, J; Sangaline, E; Sarkar, A; Schambach, J; Scharenberg, R P; Schmah, A M; Schmidke, W B; Schmitz, N; Seger, J; Seyboth, P; Shah, N; Shahaliev, E; Shanmuganathan, P V; Shao, M; Sharma, B; Shen, W Q; Shi, S S; Shou, Q Y; Sichtermann, E P; Singaraju, R N; Skoby, M J; Smirnov, D; Smirnov, N; Solanki, D; Sorensen, P; deSouza, U G; Spinka, H M; Srivastava, B; Stanislaus, T D S; Stevens, J R; Stock, R; Strikhanov, M; Stringfellow, B; Suaide, A A P; Sumbera, M; Sun, X; Sun, X M; Sun, Y; Sun, Z; Surrow, B; Svirida, D N; Symons, T J M; de Toledo, A Szanto; Szelezniak, M A; Takahashi, J; Tang, A H; Tang, Z; Tarnowsky, T; Thomas, J H; Timmins, A R; Tlusty, D; Tokarev, M; Trentalange, S; Tribble, R E; Tribedy, P; Trzeciak, B A; Tsai, O D; Turnau, J; Ullrich, T; Underwood, D G; Van Buren, G; van Nieuwenhuizen, G; Vanfossen,, J A; Varma, R; Vasconcelos, G M S; Vasiliev, A N; Vertesi, R; Videbæk, F; Viyogi, Y P; Vokal, S; Vossen, A; Wada, M; Wang, F; Wang, G; Wang, H; Wang, J S; Wang, X L; Wang, Y; Webb, G; Webb, J C; Westfall, G D; Wieman, H; Wimsatt, G; Wissink, S W; Witt, R; Wu, Y F; Xiao, Z; Xie, W; Xin, K; Xu, H; Xu, J; Xu, N; Xu, Q H; Xu, Y; Xu, Z; Yan, W; Yang, C; Yang, Y; Ye, Z; Yepes, P; Yi, L; Yip, K; Yoo, I-K; Yu, N; Zawisza, Y; Zbroszczyk, H; Zha, W; Zhang, J B; Zhang, J L; Zhang, S; Zhang, X P; Zhang, Y; Zhang, Z P; Zhao, F; Zhao, J; Zhong, C; Zhu, X; Zhu, Y H; Zoulkarneeva, Y; Zyzak, M

    2014-01-01

    We report measurements of Upsilon meson production in p+p, d+Au, and Au+Au collisions using the STAR detector at RHIC. We compare the Upsilon yield to the measured cross section in p+p collisions in order to quantify any modifications of the yield in cold nuclear matter using d+Au data and in hot nuclear matter using Au+Au data separated into three centrality classes. Our p+p measurement is based on three times the statistics of our previous result. We obtain a nuclear modification factor for Upsilon(1S+2S+3S) in the rapidity range |y|<1 in d+Au collisions of R_dAu = 0.67 +/- 0.12 (stat.) +/- 0.04 (sys.) +/- 0.08 (pp sys.). A comparison with models including shadowing and initial state parton energy loss indicates the presence of additional cold-nuclear matter suppression. Similarly, in the top 10% most-central Au+Au collisions, we measure a nuclear modification factor of R_AA=0.36 +/- 0.09 (stat.) +/- 0.01 (sys.) +/- 0.04 (pp sys.), which is a larger suppression factor than that seen in cold nuclear matte...

  14. The point-defect of carbon nanotubes anchoring Au nanoparticles

    DEFF Research Database (Denmark)

    Lv, Y. A.; Cui, Y. H.; Li, X. N.;

    2010-01-01

    The understanding of the interaction between Au and carbon nanotubes (CNTs) is very important since Au/CNTs composites have wide applications in many fields. In this study, we investigated the dispersion of Au nanoparticles on the CNTs by transmission electron microscopy and the bonding mechanism...

  15. Bonding, Luminescence, Metallophilicity in Linear Au3 and Au2Ag Chains Stabilized by Rigid Diphosphanyl NHC Ligands.

    Science.gov (United States)

    Ai, Pengfei; Mauro, Matteo; Gourlaouen, Christophe; Carrara, Serena; De Cola, Luisa; Tobon, Yeny; Giovanella, Umberto; Botta, Chiara; Danopoulos, Andreas A; Braunstein, Pierre

    2016-09-01

    The heterofunctional and rigid ligand N,N'-diphosphanyl-imidazol-2-ylidene (PCNHCP; P = P(t-Bu)2), through its phosphorus and two N-heterocyclic carbene (NHC) donors, stabilizes trinuclear chain complexes, with either Au3 or AgAu2 cores, and dinuclear Au2 complexes. The two oppositely situated PCNHCP (L) ligands that "sandwich" the metal chain can support linear and rigid structures, as found in the known tricationic Au(I) complex [Au3(μ3-PCNHCP,κP,κCNHC,κP)2](OTf)3 (OTf = CF3SO3; [Au3L2](OTf)3; Chem. Commun. 2014, 50, 103-105) now also obtained by transmetalation from [Ag3(μ3-PCNHCP,κP,κCNHC,κP)2](OTf)3 ([Ag3L2](OTf)3), or in the mixed-metal tricationic [Au2Ag(μ3-PCNHCP,κP,κCNHC,κP)2](OTf)3 ([Au2AgL2](OTf)3). The latter was obtained stepwise by the addition of AgOTf to the digold(I) complex [Au2(μ2-PCNHCP,κP,κCNHC)2](OTf)2 ([Au2L2](OTf)2). The latter contains two dangling P donors and displays fluxional behavior in solution, and the Au···Au separation of 2.8320(6) Å in the solid state is consistent with metallophilic interactions. In the solvento complex [Au3Cl2(tht)(μ3-PCNHCP,κP,κCNHC,κP)](OTf)·MeCN ([Au3Cl2(tht)L](OTf)·MeCN), which contains only one L and one tht ligand (tht = tetrahydrothiophene), the metal chain is bent (148.94(2)°), and the longer Au···Au separation (2.9710(4) Å) is in line with relaxation of the rigidity due to a more "open" structure. Similar features were observed in [Au3Cl2(SMe2)L](OTf)·2MeCN. A detailed study of the emission properties of [Au3L2](OTf)3, [Au3Cl2(tht)L](OTf)·MeCN, [Au2L2](OTf)2, and [Au2AgL2](OTf)3 was performed by means of steady state and time-resolved photophysical techniques. The complex [Au3L2](OTf)3 displays a bright (photoluminescence quantum yield = 80%) and narrow emission band centered at 446 nm with a relatively small Stokes' shift and long-lived excited-state lifetime on the microsecond timescale, both in solution and in the solid state. In line with the very narrow emission

  16. Charged hadron transverse momentum distributions in Au+Au collisions at √sNN=200 GeV

    Science.gov (United States)

    Back, B. B.; Baker, M. D.; Barton, D. S.; Betts, R. R.; Ballintijn, M.; Bickley, A. A.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Decowski, M. P.; García, E.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Heintzelman, G. A.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Hołyński, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C. M.; Lin, W. T.; Lee, J. W.; Manly, S.; McLeod, D.; Mignerey, A. C.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Remsberg, L. P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Skulski, W.; Steadman, S. G.; Steinberg, P.; Stephans, G. S. F.; Sukhanov, A.; Tang, J.-L.; Teng, R.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Verdier, R.; Veres, G. I.; Wadsworth, B.; Wolfs, F. L. H.; Wosiek, B.; Woźniak, K.; Wuosmaa, A. H.; Wysłouch, B.

    2004-01-01

    We present transverse momentum distributions of charged hadrons produced in Au+Au collisions at sNN=200 GeV. The spectra were measured for transverse momenta pT from 0.25 to 4.5 GeV/c in a pseudorapidity range of 0.2<η<1.4. The evolution of the spectra is studied as a function of collision centrality, from 65 to 344 participating nucleons. The results are compared to data from proton-antiproton collisions and Au+Au collisions at lower RHIC energies. We find a significant change of the spectral shape between proton-antiproton and semi-peripheral Au+Au collisions. Comparing semi-peripheral to central Au+Au collisions, we find that the yields at high pT exhibit approximate scaling with the number of participating nucleons, rather than scaling with the number of binary collisions.

  17. Enhanced strange baryon production in Au+Au collisions compared to p+p at sqrts = 200 GeV

    CERN Document Server

    Abelev, B I; Ahammed, Z; Anderson, B D; Arkhipkin, D; Averichev, G S; Bai, Y; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Baumgart, S; Bekele, S; Belaga, V V; Bellingeri-Laurikainen, A; Bellwied, R; Benedosso, F; Betts, R R; Bhardwaj, S; Bhasin, A; Bhati, A K; Bichsel, H; Bielcik, J; Bielcikova, J; Bland, L C; Blyth, S L; Bombara, M; Bonner, B E; Botje, M; Bouchet, J; Brandin, A V; Bravar, A; Burton, T P; Bystersky, M; Cadman, R V; Cai, X Z; Caines, H; Calderón de la Barca-Sanchez, M; Callner, J; Castillo, J; Catu, O; Cebra, D; Chajecki, Z; Chaloupka, P; Chattopadhyay, S; Chen, H F; Chen, J H; Cheng, J; Cherney, M; Chikanian, A; Christie, W; Chung, S U; Coffin, J P; Cormier, T M; Cosentino, M R; Cramer, J G; Crawford, H J; Das, D; Das, S; Dash, S; Daugherity, M; De Moura, M M; Dedovich, T G; De Phillips, M; Derevshchikov, A A; Didenko, L; Dietel, T; Djawotho, P; Dogra, S M; Dong, X; Drachenberg, J L; Draper, J E; Du, F; Dunin, V B; Dunlop, J C; Dutta-Majumdar, M R; Eckardt, V; Edwards, W R; Efimov, L G; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Estienne, M; Fachini, P; Fatemi, R; Fedorisin, J; Filimonov, K; Filip, P; Finch, E; Fine, V; Fisyak, Yu; Fu, J; Gagliardi, C A; Gaillard, L; Ganti, M S; García-Solis, E; Ghazikhanian, V; Ghosh, P; Gorbunov, Y G; Gos, H; Grebenyuk, O; Grosnick, D; Guertin, S M; Guimaraes, K S F F; Gupta, N; Haag, B; Hallman, T J; Hamed, A; Harris, J W; He, W; Heinz, M; Henry, T W; Hepplemann, S; Hippolyte, B; Hirsch, A; Hjort, E; Hoffman, A M; Hoffmann, G W; Hofman, D; Hollis, R; Horner, M J; Huang, H Z; Huang, S L; Hughes, E W; Humanic, T J; Igo, G; Iordanova, A; Jacobs, P; Jacobs, W W; Jakl, P; Jia, F; Jones, P G; Judd, E G; Kabana, S; Kang, K; Kapitan, J; Kaplan, M; Keane, D; Kechechyan, A; Kettler, D; Khodyrev, V Yu; Kim, B C; Kiryluk, J; Kisiel, A; Kislov, E M; Knospe, A G; Kocoloski, A; Koetke, D D; Kollegger, T; Kopytine, M; Kotchenda, L; Kouchpil, V; Kowalik, K L; Kravtsov, P; Kravtsov, V I; Krüger, K; Kuhn, C; Kulikov, A I; Kumar, A; Kurnadi, P; Kuznetsov, A A; Lamont, M A C; Landgraf, J M; Lange, S; La Pointe, S; Laue, F; Lauret, J; Lebedev, A; Lednicky, R; Lee, C H; Lehocka, S; Le Vine, M J; Li, C; Li, Q; Li, Y; Lin, G; Lin, X; Lindenbaum, S J; Lisa, M A; Liu, F; Liu, H; Liu, J; Liu, L; Liu, Z; Ljubicic, T; Llope, W J; Long, H; Longacre, R S; Love, W A; Lu, Y; Ludlam, T; Lynn, D; Ma, G L; Ma, J G; Ma, Y G; Magestro, D; Mahapatra, D P; Majka, R; Mangotra, L K; Manweiler, R; Margetis, S; Markert, C; Martin, L; Matis, H S; Matulenko, Yu A; McClain, C J; McShane, T S; Melnik, Yu M; Meschanin, A; Millane, J; Miller, M L; Minaev, N G; Mioduszewski, S; Mironov, C; Mischke, A; Mishra, D K; Mitchell, J; Mohanty, B; Molnár, L; Moore, C F; Morozov, D A; Munhoz, M G; Nandi, B K; Nattrass, C; Nayak, T K; Nelson, J M; Nepali, N S; Netrakanti, P K; Nogach, L V; Nurushev, S B; Odyniec, Grazyna Janina; Ogawa, A; Okorokov, V; Oldenburg, M; Olson, D; Pachr, M; Pal, S K; Panebratsev, Yu A; Pavlinov, A I; Pawlak, T; Peitzmann, T; Perevozchikov, V; Perkins, C; Peryt, W; Phatak, S C; Planinic, M; Pluta, J; Poljak, N; Porile, N; Porter, J; Poskanzer, A M; Potekhin, M V; Potrebenikova, E V; Potukuchi, B V K S; Prindle, D; Pruneau, C; Putschke, J; Qattan, I A; Rakness, G; Raniwala, R; Raniwala, S; Ray, R L; Razin, S V; Reinnarth, J; Relyea, D; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevski, O V; Romero, J L; Rose, A; Roy, C; Ruan, L; Russcher, M J; Sahoo, R; Sakuma, T; Salur, S; Sandweiss, J; Sarsour, M; Sazhin, P S; Schambach, J; Scharenberg, R P; Schmitz, N; Schweda, K; Seger, J; Selyuzhenkov, I; Seyboth, P; Shabetai, A; Shahaliev, E; Shao, M; Sharma, M; Shen, W Q; Shimansky, S S; Sichtermann, E P; Simon, F; Singaraju, R N; Smirnov, N; Snellings, R; Sørensen, P; Sowinski, J; Speltz, J; Spinka, H M; Srivastava, B; Stadnik, A; Stanislaus, T D S; Staszak, D; Stock, R; Stolpovsky, A; Strikhanov, M N; Stringfellow, B C; Suaide, A A P; Suarez, M C; Subba, N L; Sugarbaker, E R; Sumbera, M; Sun, Z; Surrow, B; Swanger, M; Symons, T J M; Szanto de Toledo, A; Takahashi, J; Tang, A H; Tarnowsky, T J; Thomas, J H; Timmins, A R; Timoshenko, S; Tokarev, M; Trainor, T A; Trentalange, S; Tribble, R E; Tsai, O D; Ulery, J; Ullrich, T; Underwood, D G; Van Buren, G; Van der Kolk, N; Van Leeuwen, M; Van der Molen, A M; Varma, R; Vasilevski, I M; Vasilev, A N; Vernet, R; Vigdor, S E; Viyogi, Y P; Vokal, S; Voloshin, S A; Waggoner, W T; Wang, F; Wang, G; Wang, J S; Wang, X L; Wang, Y; Watson, J W; Webb, J C; Westfall, G D; Wetzler, A; Whitten, C; Wieman, H; Wissink, S W; Witt, R; Wu, J; Xu, N; Xu, Q H; Xu, Z; Yepes, P; Yoo, I K; Yurevich, V I; Zhan, W; Zhang, H; Zhang, W M; Zhang, Y; Zhang, Z P; Zhao, Y; Zhong, C; Zhou, J; Zoulkarneev, R; Zoulkarneeva, Y; Zubarev, A N; Zuo, J X

    2007-01-01

    We report on the observed differences in production rates of strange and multi-strange baryons in Au+Au collisions at sqrts = 200 GeV compared to p+p interactions at the same energy. The yields in Au+Au collisions, when scaled by the number of participants, are larger than those measured in the p+p data. The magnitudes of the differences grow with the strangeness of the baryon and with increasing centrality. The enhancements of the Au+Au yields are close to those measured in sqrts = 17.3 GeV collisions. Further, when the binary scaled p+p pT spectra are compared to those of Au+Au the heavy-ion yields exceed binary scaling in the pT range 1 < pT< 4 GeV/c.

  18. Centrality dependence of direct photon production in (square root)S(NN) = 200 GeV Au + Au collisions.

    Science.gov (United States)

    Adler, S S; Afanasiev, S; Aidala, C; Ajitanand, N N; Akiba, Y; Alexander, J; Amirikas, R; Aphecetche, L; Aronson, S H; Averbeck, R; Awes, T C; Azmoun, R; Babintsev, V; Baldisseri, A; Barish, K N; Barnes, P D; Bassalleck, B; Bathe, S; Batsouli, S; Baublis, V; Bazilevsky, A; Belikov, S; Berdnikov, Y; Bhagavatula, S; Boissevain, J G; Borel, H; Borenstein, S; Brooks, M L; Brown, D S; Bruner, N; Bucher, D; Buesching, H; Bumazhnov, V; Bunce, G; Burward-Hoy, J M; Butsyk, S; Camard, X; Chai, J-S; Chand, P; Chang, W C; Chernichenko, S; Chi, C Y; Chiba, J; Chiu, M; Choi, I J; Choi, J; Choudhury, R K; Chujo, T; Cianciolo, V; Cobigo, Y; Cole, B A; Constantin, P; d'Enterria, D; David, G; Delagrange, H; Denisov, A; Deshpande, A; Desmond, E J; Devismes, A; Dietzsch, O; Drapier, O; Drees, A; du Rietz, R; Durum, A; Dutta, D; Efremenko, Y V; El Chenawi, K; Enokizono, A; En'yo, H; Esumi, S; Ewell, L; Fields, D E; Fleuret, F; Fokin, S L; Fox, B D; Fraenkel, Z; Frantz, J E; Franz, A; Frawley, A D; Fung, S-Y; Garpman, S; Ghosh, T K; Glenn, A; Gogiberidze, G; Gonin, M; Gosset, J; Goto, Y; Granier de Cassagnac, R; Grau, N; Greene, S V; Perdekamp, M Grosse; Guryn, W; Gustafsson, H-A; Hachiya, T; Haggerty, J S; Hamagaki, H; Hansen, A G; Hartouni, E P; Harvey, M; Hayano, R; Hayashi, N; He, X; Heffner, M; Hemmick, T K; Heuser, J M; Hibino, M; Hill, J C; Holzmann, W; Homma, K; Hong, B; Hoover, A; Ichihara, T; Ikonnikov, V V; Imai, K; Isenhower, D; Ishihara, M; Issah, M; Isupov, A; Jacak, B V; Jang, W Y; Jeong, Y; Jia, J; Jinnouchi, O; Johnson, B M; Johnson, S C; Joo, K S; Jouan, D; Kametani, S; Kamihara, N; Kang, J H; Kapoor, S S; Katou, K; Kelly, S; Khachaturov, B; Khanzadeev, A; Kikuchi, J; Kim, D H; Kim, D J; Kim, D W; Kim, E; Kim, G-B; Kim, H J; Kistenev, E; Kiyomichi, A; Kiyoyama, K; Klein-Boesing, C; Kobayashi, H; Kochenda, L; Kochetkov, V; Koehler, D; Kohama, T; Kopytine, M; Kotchetkov, D; Kozlov, A; Kroon, P J; Kuberg, C H; Kurita, K; Kuroki, Y; Kweon, M J; Kwon, Y; Kyle, G S; Lacey, R; Ladygin, V; Lajoie, J G; Lebedev, A; Leckey, S; Lee, D M; Lee, S; Leitch, M J; Li, X H; Lim, H; Litvinenko, A; Liu, M X; Liu, Y; Maguire, C F; Makdisi, Y I; Malakhov, A; Manko, V I; Mao, Y; Martinez, G; Marx, M D; Masui, H; Matathias, F; Matsumoto, T; McGaughey, P L; Melnikov, E; Messer, F; Miake, Y; Milan, J; Miller, T E; Milov, A; Mioduszewski, S; Mischke, R E; Mishra, G C; Mitchell, J T; Mohanty, A K; Morrison, D P; Moss, J M; Mühlbacher, F; Mukhopadhyay, D; Muniruzzaman, M; Murata, J; Nagamiya, S; Nagle, J L; Nakamura, T; Nandi, B K; Nara, M; Newby, J; Nilsson, P; Nyanin, A S; Nystrand, J; O'Brien, E; Ogilvie, C A; Ohnishi, H; Ojha, I D; Okada, K; Ono, M; Onuchin, V; Oskarsson, A; Otterlund, I; Oyama, K; Ozawa, K; Pal, D; Palounek, A P T; Pantuev, V; Papavassiliou, V; Park, J; Parmar, A; Pate, S F; Peitzmann, T; Peng, J-C; Peresedov, V; Pinkenburg, C; Pisani, R P; Plasil, F; Purschke, M L; Purwar, A K; Rak, J; Ravinovich, I; Read, K F; Reuter, M; Reygers, K; Riabov, V; Riabov, Y; Roche, G; Romana, A; Rosati, M; Rosnet, P; Ryu, S S; Sadler, M E; Saito, N; Sakaguchi, T; Sakai, M; Sakai, S; Samsonov, V; Sanfratello, L; Santo, R; Sato, H D; Sato, S; Sawada, S; Schutz, Y; Semenov, V; Seto, R; Shaw, M R; Shea, T K; Shibata, T-A; Shigaki, K; Shiina, T; Silva, C L; Silvermyr, D; Sim, K S; Singh, C P; Singh, V; Sivertz, M; Soldatov, A; Soltz, R A; Sondheim, W E; Sorensen, S P; Sourikova, I V; Staley, F; Stankus, P W; Stenlund, E; Stepanov, M; Ster, A; Stoll, S P; Sugitate, T; Sullivan, J P; Takagui, E M; Taketani, A; Tamai, M; Tanaka, K H; Tanaka, Y; Tanida, K; Tannenbaum, M J; Tarján, P; Tepe, J D; Thomas, T L; Tojo, J; Torii, H; Towell, R S; Tserruya, I; Tsuruoka, H; Tuli, S K; Tydesjö, H; Tyurin, N; van Hecke, H W; Velkovska, J; Velkovsky, M; Veszprémi, V; Villatte, L; Vinogradov, A A; Volkov, M A; Vznuzdaev, E; Wang, X R; Watanabe, Y; White, S N; Wohn, F K; Woody, C L; Xie, W; Yang, Y; Yanovich, A; Yokkaichi, S; Young, G R; Yushmanov, I E; Zajc, W A; Zhang, C; Zhou, S; Zhou, S J; Zolin, L

    2005-06-17

    The first measurement of direct photons in Au + Au collisions at (square root)S(NN) = 200 GeV is presented. The direct photon signal is extracted as a function of the Au + Au collision centrality and compared to next-to-leading order perturbative quantum chromodynamics calculations. The direct photon yield is shown to scale with the number of nucleon-nucleon collisions for all centralities. PMID:16090462

  19. Centrality Dependence of Direct Photon Production in √(SNN)=200 GeV Au+Au Collisions

    International Nuclear Information System (INIS)

    The first measurement of direct photons in Au+Au collisions at √(sNN)=200 GeV is presented. The direct photon signal is extracted as a function of the Au+Au collision centrality and compared to next-to-leading order perturbative quantum chromodynamics calculations. The direct photon yield is shown to scale with the number of nucleon-nucleon collisions for all centralities

  20. In-situ STM study of phosphate adsorption on Cu(111), Au(111) and Cu/Au(111) electrodes

    DEFF Research Database (Denmark)

    Schlaup, Christian; Horch, Sebastian

    2013-01-01

    The interaction of Cu(111), Au(111) and Cu-covered Au(111) electrodes with a neutral phosphate buffer solution has been studied by means of cyclic voltammetry (CV) and in situ electrochemical scanning tunneling microscopy (EC-STM). Under low potential conditions, both the Cu(111) and the Au(111...

  1. Di-hadron correlations with identified leading hadrons in 200 GeV Au+Au and d+Au collisions at STAR

    Directory of Open Access Journals (Sweden)

    L. Adamczyk

    2015-12-01

    Full Text Available The STAR Collaboration presents for the first time two-dimensional di-hadron correlations with identified leading hadrons in 200 GeV central Au+Au and minimum-bias d+Au collisions to explore hadronization mechanisms in the quark gluon plasma. The enhancement of the jet-like yield for leading pions in Au+Au data with respect to the d+Au reference and the absence of such an enhancement for leading non-pions (protons and kaons are discussed within the context of a quark recombination scenario. The correlated yield at large angles, specifically in the ridge region, is found to be significantly higher for leading non-pions than pions. The consistencies of the constituent quark scaling, azimuthal harmonic model and a mini-jet modification model description of the data are tested, providing further constraints on hadronization.

  2. Spectra and ratios of identified particles in Au+Au and d+Au collisions at sqrt(s_NN)=200 GeV

    OpenAIRE

    Adare, A.; Afanasiev, S.; Aidala, C.; Ajitanand, N. N.; Akiba, Y; Al-Bataineh, H.; Alexander, J.; Angerami, A.(Nevis Laboratory, Columbia University, Irvington, NY, U.S.A.); Aoki, K.; Apadula, N.; Aramaki, Y.; Atomssa, E. T.; Averbeck, R.; Awes, T. C.; Azmoun, B.

    2013-01-01

    The transverse momentum (p_T) spectra and ratios of identified charged hadrons (\\pi^+/-, K^+/-, p, p^bar) produced in sqrt(s_NN)=200 GeV Au+Au and d+Au collisions are reported in five different centrality classes for each collision species. The measurements of pions and protons are reported up to p_T=6 GeV/c (5 GeV/c), and the measurements of kaons are reported up to p_T=4 GeV/c (3.5 GeV/c) in Au+Au (d+Au) collisions. In the intermediate p_T region, between 2--5 GeV/c, a significant enhanceme...

  3. Di-Hadron Correlations with Identified Leading Hadrons in 200 GeV Au+Au and d+Au Collisions at STAR

    CERN Document Server

    Abdelwahab, N M; Adkins, J K; Agakishiev, G; Aggarwal, M M; Ahammed, Z; Alekseev, I; Alford, J; Anson, C D; Aparin, A; Arkhipkin, D; Aschenauer, E C; Averichev, G S; Banerjee, A; Beavis, D R; Bellwied, R; Bhasin, A; Bhati, A K; Bhattarai, P; Bielcik, J; Bielcikova, J; Bland, L C; Bordyuzhin, I G; Borowski, W; Bouchet, J; Brandin, A V; Brovko, S G; Bültmann, S; Bunzarov, I; Burton, T P; Butterworth, J; Caines, H; Sánchez, M Calderón de la Barca; Campbell, J M; Cebra, D; Cendejas, R; Cervantes, M C; Chaloupka, P; Chang, Z; Chattopadhyay, S; Chen, H F; Chen, J H; Chen, L; Cheng, J; Cherney, M; Chikanian, A; Christie, W; Chwastowski, J; Codrington, M J M; Contin, G; Cramer, J G; Crawford, H J; Cui, X; Das, S; Leyva, A Davila; De Silva, L C; Debbe, R R; Dedovich, T G; Deng, J; Derevschikov, A A; de Souza, R Derradi; di Ruzza, B; Didenko, L; Dilks, C; Ding, F; Djawotho, P; Dong, X; Drachenberg, J L; Draper, J E; Du, C M; Dunkelberger, L E; Dunlop, J C; Efimov, L G; Engelage, J; Engle, K S; Eppley, G; Esha, R; Eun, L; Evdokimov, O; Eyser, O; Fatemi, R; Fazio, S; Fedorisin, J; Filip, P; Fisyak, Y; Flores, C E; Gagliardi, C A; Gangadharan, D R; Garand, D; Geurts, F; Gibson, A; Girard, M; Gliske, S; Greiner, L; Grosnick, D; Gunarathne, D S; Guo, Y; Gupta, A; Gupta, S; Guryn, W; Haag, B; Hamad, A; Hamed, A; Han, L-X; Haque, R; Harris, J W; Heppelmann, S; Hirsch, A; Hoffmann, G W; Hofman, D J; Horvat, S; Huang, B; Huang, H Z; Huang, X; Huck, P; Humanic, T J; Igo, G; Jacobs, W W; Jang, H; Judd, E G; Kabana, S; Kalinkin, D; Kang, K; Kauder, K; Ke, H W; Keane, D; Kechechyan, A; Kesich, A; Khan, Z H; Kikola, D P; Kisel, I; Kisiel, A; Koetke, D D; Kollegger, T; Konzer, J; Koralt, I; Kosarzewski, L K; Kotchenda, L; Kraishan, A F; Kravtsov, P; Krueger, K; Kulakov, I; Kumar, L; Kycia, R A; Lamont, M A C; Landgraf, J M; Landry, K D; Lauret, J; Lebedev, A; Lednicky, R; Lee, J H; Li, C; Li, W; Li, X; Li, Y; Li, Z M; Lisa, M A; Liu, F; Ljubicic, T; Llope, W J; Lomnitz, M; Longacre, R S; Luo, X; Ma, G L; Ma, Y G; Mahapatra, D P; Majka, R; Margetis, S; Markert, C; Masui, H; Matis, H S; McDonald, D; McShane, T S; Minaev, N G; Mioduszewski, S; Mohanty, B; Mondal, M M; Morozov, D A; Mustafa, M K; Nandi, B K; Nasim, Md; Nayak, T K; Nelson, J M; Nigmatkulov, G; Nogach, L V; Noh, S Y; Novak, J; Nurushev, S B; Odyniec, G; Ogawa, A; Oh, K; Ohlson, A; Okorokov, V; Oldag, E W; Olvitt, D L; Page, B S; Pan, Y X; Pandit, Y; Panebratsev, Y; Pawlak, T; Pawlik, B; Pei, H; Perkins, C; Pile, P; Planinic, M; Pluta, J; Poljak, N; Poniatowska, K; Porter, J; Poskanzer, A M; Pruthi, N K; Przybycien, M; Putschke, J; Qiu, H; Quintero, A; Ramachandran, S; Raniwala, R; Raniwala, S; Ray, R L; Riley, C K; Ritter, H G; Roberts, J B; Rogachevskiy, O V; Romero, J L; Ross, J F; Roy, A; Ruan, L; Rusnak, J; Rusnakova, O; Sahoo, N R; Sahu, P K; Sakrejda, I; Salur, S; Sandacz, A; Sandweiss, J; Sangaline, E; Sarkar, A; Schambach, J; Scharenberg, R P; Schmah, A M; Schmidke, W B; Schmitz, N; Seger, J; Seyboth, P; Shah, N; Shahaliev, E; Shanmuganathan, P V; Shao, M; Sharma, B; Shen, W Q; Shi, S S; Shou, Q Y; Sichtermann, E P; Simko, M; Skoby, M J; Smirnov, D; Smirnov, N; Solanki, D; Sorensen, P; Spinka, H M; Srivastava, B; Stanislaus, T D S; Stevens, J R; Stock, R; Strikhanov, M; Stringfellow, B; Sumbera, M; Sun, X; Sun, X M; Sun, Y; Sun, Z; Surrow, B; Svirida, D N; Symons, T J M; Szelezniak, M A; Takahashi, J; Tang, A H; Tang, Z; Tarnowsky, T; Thomas, J H; Timmins, A R; Tlusty, D; Tokarev, M; Trentalange, S; Tribble, R E; Tribedy, P; Trzeciak, B A; Tsai, O D; Turnau, J; Ullrich, T; Underwood, D G; Van Buren, G; van Nieuwenhuizen, G; Vandenbroucke, M; Vanfossen,, J A; Varma, R; Vasconcelos, G M S; Vasiliev, A N; Vertesi, R; Videbæk, F; Viyogi, Y P; Vokal, S; Vossen, A; Wada, M; Wang, F; Wang, G; Wang, H; Wang, J S; Wang, X L; Wang, Y; Webb, G; Webb, J C; Wen, L; Westfall, G D; Wieman, H; Wissink, S W; Wu, Y F; Xiao, Z; Xie, W; Xin, K; Xu, H; Xu, J; Xu, N; Xu, Q H; Xu, Y; Xu, Z; Yan, W; Yang, C; Yang, Y; Ye, Z; Yepes, P; Yi, L; Yip, K; Yoo, I-K; Yu, N; Zbroszczyk, H; Zha, W; Zhang, J B; Zhang, J L; Zhang, S; Zhang, X P; Zhang, Y; Zhang, Z P; Zhao, F; Zhao, J; Zhong, C; Zhu, X; Zhu, Y H; Zoulkarneeva, Y; Zyzak, M

    2014-01-01

    The STAR collaboration presents new two-dimensional di-hadron correlations with leading hadrons in 200 GeV central Au+Au and minimum bias d+Au collisions to explore hadronization mechanisms in the quark gluon plasma. The enhancement of the jet-like yield for leading pions in Au+Au data with respect to the d+Au reference and the absence of enhancement for leading non-pions (protons and kaons) are discussed within the context of quark recombination. The correlated yield at large angles, specifically in the \\emph{ridge region}, is significantly higher for leading non-pions than pions. The consistencies of the constituent quark scaling, azimuthal harmonic model and a mini-jet modification model description of the data are tested, providing further constraints on hadronization.

  4. "Dealloying" Phase Separation during Growth of Au on Ni(110)

    DEFF Research Database (Denmark)

    Nielsen, L. Pleth; Besenbacher, Flemming; Stensgaard, I.;

    1995-01-01

    Combined scanning tunneling microscopy and ion-scattering studies have revealed a new "dealloying" phase transition during the growth of Au on Ni(110). The Au atoms, which initially alloy into the Ni(110) surface, phase separate into a vacancy-stabilized Au dimer-trimer chain structure at Au...... coverages larger than 0.4 monolayer. Using the effective-medium theory, we show that the resulting structure as well as the physical mechanism responsible for the phase transition are closely related to the surface stress induced by the substituted Au....

  5. First results on d+Au collisions from PHOBOS

    Science.gov (United States)

    Back, B. B.; Baker, M. D.; Ballintijn, M.; Barton, D. S.; Becker, B.; Betts, R. R.; Bickley, A. A.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Decowski, M. P.; García, E.; Gburek, T.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Harrington, A. S.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Hołyński, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Khan, N.; Kulinich, P.; Kuo, C. M.; Lee, J. W.; Lin, W. T.; Manly, S.; Mignerey, A. C.; Noell, A.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Remsberg, L. P.; Roland, C.; Roland, G.; Sagerer, J.; Sarin, P.; Sawicki, P.; Sedykh, I.; Skulski, W.; Smith, C. E.; Steinberg, P.; Stephans, G. S. F.; Sukhanov, A.; Teng, R.; Tonjes, M. B.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Verdier, R.; Veres, G. I.; Wadsworth, B.; Wolfs, F. L. H.; Wosiek, B.; Woźniak, K.; Wuosmaa, A. H.; Wysłouch, B.; Zhang, J.

    2004-02-01

    We have measured transverse momentum distributions of charged hadrons produced in d+Au collisions at √SNN = 200 GeV, in the range 0.25 < pT < 6.0 GeV/c. With increasing collision centrality, the yield at high transverse momenta increases more rapidly than the overall particle density, leading to a strong modification of the spectral shape. This change in spectral shape is qualitatively different from observations in Au+Au collisions at the same energy. The results provide important information for discriminating between different models for the suppression of high-pT hadrons observed in Au+Au collisions.

  6. Thermal desorption of Au from W(001) surface

    CERN Document Server

    Blaszczyszyn, R; Godowski, P J

    2002-01-01

    Adsorption of Au on W(001) at 450 K up to multilayer structures was investigated. Temperature programmed desorption technique was used in determination of coverage dependent desorption energy (region up to one monolayer). Results were discussed in terms of competitive interactions of Au-Au and Au-W atoms. Simple procedure for prediction of faceting behavior on the interface, basing on the desorption data, was postulated. It was deduced that the Au/W(001) interface should not show faceting tendency after thermal treatment. (author)

  7. Thermal Desorption of Au from W(001) Surface

    Science.gov (United States)

    Błaszczyszyn, R.; Chrzanowski, J.; Godowski, P. J.

    2000-12-01

    Adsorption of Au on W(001) at 450 K up to multilayer structures was investigated. Temperature programmed desorption technique was used in determination of coverage dependent desorption energy (region up to one monolayer). Results were discussed in terms of competitive interactions of Au--Au and Au--W atoms. Simple procedure for prediction of faceting behavior on the interface, basing on the desorption data, was postulated. It was deduced that the Au/W(001) interface should not show faceting tendency after thermal treatment.

  8. Photoswitchable Faraday effect in EuS-Au nanosystems

    Energy Technology Data Exchange (ETDEWEB)

    Kawashima, Akira; Nakanishi, Takayuki; Kitagawa, Yuichi; Fushimi, Koji; Hasegawa, Yasuchika [Division of Applied Chemistry, Faculty of Engineering, Hokkaido University, North-13 West-8, Kita-ku, 060-8628, Sapporo (Japan)

    2016-01-15

    Effective photoswitchable europium sulfide nanocrystals with gold nanoparticles using dithiol (DDT: 1,10-decanedithiol) joint molecules, EuS-Au nanosystems, are demonstrated. The TEM image indicates the formation of EuS-Au nanosystems composed of cube-shaped EuS nanocrystals and spherical Au nanoparticles. Under visible-light irradiation, a drastic change of absorption band of EuS-Au nanosystems at around 600 nm was observed. The Faraday effects of EuS-Au nanosystems were estimated using magnetic circular dichroism (MCD) measurements. The effective change of the MCD spectra of EuS-Au nanosystems under visible-light irradiation was successfully observed at around 670 nm for the first time. The effective reversible changes in MCD spectra with the alternative irradiation cycles of visible light (>440 nm) and dark are also presented. The decrease rate of rotation angle at 670 nm of EuS-Au nanosystems is larger than that of absorbance. These results indicate that the effective change of MCD spectra of EuS-Au nanosystems would be dominated not only by a drastic change of absorption band related to enhanced LSPR of Au nanoparticles but also by specific interaction between EuS and Au in nanosystem under irradiation. Illustration of photoswitch and TEM image of EuS-Au nanosystems. (copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  9. Au-nanoparticles grafted on plasma treated PE

    Energy Technology Data Exchange (ETDEWEB)

    Svorcik, V., E-mail: vaclav.svorcik@vscht.c [Department of Solid State Engineering, Institute of Chemical Technology, 166 28 Prague (Czech Republic); Chaloupka, A. [Department of Solid State Engineering, Institute of Chemical Technology, 166 28 Prague (Czech Republic); Rezanka, P. [Department of Analytical Chemistry, Institute of Chemical Technology, Prague (Czech Republic); Slepicka, P. [Department of Solid State Engineering, Institute of Chemical Technology, 166 28 Prague (Czech Republic); Kolska, Z. [Department of Chemistry, J.E. Purkyne University, 400 96 Usti nad Labem (Czech Republic); Kasalkova, N.; Hubacek, T.; Siegel, J. [Department of Solid State Engineering, Institute of Chemical Technology, 166 28 Prague (Czech Republic)

    2010-03-15

    Polyethylene (PE) surface was treated with Ar plasma. Activated surface was grafted from methanol solution of 1,2-ethanedithiol. Then the sample was immersed into freshly prepared colloid solution of Au-nanoparticles. Finally Au layer was sputtered on the samples. Properties of the modified PE were studied using various methods: AFM, EPR, RBS and nanoindentation. It was shown that the plasma treatment results in degradation of polymer chain (AFM) and creation of free radicals by EPR. After grafting with dithiol, the concentration of free radicals declines. The presence of Au and S in the surface layer after the coating with Au-nanoparticles was proved by RBS. Plasma treatment changes PE surface morphology and increases surface roughness, too. Another significant change in surface morphology and roughness was observed after deposition of Au-nanoparticles. Nanoindentation measurements show that the grafting with Au-nanoparticles increases adhesion of subsequently sputtered Au layer.

  10. Au-nanoparticles grafted on plasma treated PE

    Science.gov (United States)

    Švorčík, V.; Chaloupka, A.; Řezanka, P.; Slepička, P.; Kolská, Z.; Kasálková, N.; Hubáček, T.; Siegel, J.

    2010-03-01

    Polyethylene (PE) surface was treated with Ar plasma. Activated surface was grafted from methanol solution of 1,2-ethanedithiol. Then the sample was immersed into freshly prepared colloid solution of Au-nanoparticles. Finally Au layer was sputtered on the samples. Properties of the modified PE were studied using various methods: AFM, EPR, RBS and nanoindentation. It was shown that the plasma treatment results in degradation of polymer chain (AFM) and creation of free radicals by EPR. After grafting with dithiol, the concentration of free radicals declines. The presence of Au and S in the surface layer after the coating with Au-nanoparticles was proved by RBS. Plasma treatment changes PE surface morphology and increases surface roughness, too. Another significant change in surface morphology and roughness was observed after deposition of Au-nanoparticles. Nanoindentation measurements show that the grafting with Au-nanoparticles increases adhesion of subsequently sputtered Au layer.

  11. 2D chemistry on Au(111) surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Rauls, Eva; Blankenburg, Stephan; Schmidt, Wolf Gero [Theoretische Physik, Universitaet Paderborn (Germany)

    2009-07-01

    The design of functional two-dimensional molecular networks has become an area of intense research. The constraint to 2 in contrast to the availability of 3 dimensions has a large impact on many chemical reactions. Chemical reactions between surface adsorbed molecules may lead to products very different from those obtained in solutions or the gas phase. The imide formation between a diaminoterphenyl (DATP) and a PTCDA molecule is one very interesting example in this respect. In scanning tunneling microscopy (STM) experiments, it has been observed that the Au surface changes both the reaction path and the reaction product compared to 3D. In order to understand these experimental observations, we have studied the chemical reactions both in solution and on the Au(111) surface by density-functional theory calculations in the generalized-gradient approximation.

  12. Tunable VO2/Au hyperbolic metamaterial

    Science.gov (United States)

    Prayakarao, S.; Mendoza, B.; Devine, A.; Kyaw, C.; van Dover, R. B.; Liberman, V.; Noginov, M. A.

    2016-08-01

    Vanadium dioxide (VO2) is known to have a semiconductor-to-metal phase transition at ˜68 °C. Therefore, it can be used as a tunable component of an active metamaterial. The lamellar metamaterial studied in this work is composed of subwavelength VO2 and Au layers and is designed to undergo a temperature controlled transition from the optical hyperbolic phase to the metallic phase. VO2 films and VO2/Au lamellar metamaterial stacks have been fabricated and studied in electrical conductivity and optical (transmission and reflection) experiments. The observed temperature-dependent changes in the reflection and transmission spectra of the metamaterials and VO2 thin films are in a good qualitative agreement with theoretical predictions. The demonstrated optical hyperbolic-to-metallic phase transition is a unique physical phenomenon with the potential to enable advanced control of light-matter interactions.

  13. De l’individu postcommuniste au citoyen

    OpenAIRE

    Anna Krasteva

    2013-01-01

    L’article analyse le paradoxe de la conception communiste du citoyen engagé : au niveau idéologique, citoyenneté et engagement sont intrinsèquement liés, au niveau politique ils sont souvent radicalement dissociés. Le citoyen communiste est plus engagé que citoyen. La citoyenneté était dépourvue de plusieurs de ses attributs : de la jouissance de la loi qui établit « l’égalité arithmétique » et minorise les maîtres ; de la citoyenneté active – civile et politique – pour ne jouir que la protec...

  14. Collision-spike Sputtering of Au Nanoparticles.

    Science.gov (United States)

    Sandoval, Luis; Urbassek, Herbert M

    2015-12-01

    Ion irradiation of nanoparticles leads to enhanced sputter yields if the nanoparticle size is of the order of the ion penetration depth. While this feature is reasonably well understood for collision-cascade sputtering, we explore it in the regime of collision-spike sputtering using molecular-dynamics simulation. For the particular case of 200-keV Xe bombardment of Au particles, we show that collision spikes lead to abundant sputtering with an average yield of 397 ± 121 atoms compared to only 116 ± 48 atoms for a bulk Au target. Only around 31 % of the impact energy remains in the nanoparticles after impact; the remainder is transported away by the transmitted projectile and the ejecta. The sputter yield of supported nanoparticles is estimated to be around 80 % of that of free nanoparticles due to the suppression of forward sputtering.

  15. Transition probability studies in 175Au

    OpenAIRE

    Grahn, Tuomas; Watkins, H.; Joss, David; Page, Robert; Carroll, R. J.; Dewald, A.; Greenlees, Paul; Hackstein, M.; Herzberg, Rolf-Dietmar; Jakobsson, Ulrika; Jones, Peter; Julin, Rauno; Juutinen, Sakari; Ketelhut, Steffen; Kröll, Th

    2013-01-01

    Transition probabilities have been measured between the low-lying yrast states in 175Au by employing the recoil distance Doppler-shift method combined with the selective recoil-decay tagging technique. Reduced transition probabilities and magnitudes of transition quadrupole moments have been extracted from measured lifetimes allowing dramatic changes in nuclear structure within a low excitation-energy range to probed. The transition quadrupole moment data are discussed in terms...

  16. Jet structure of baryon excess in Au+Au collisions at √(sNN)=200 GeV

    International Nuclear Information System (INIS)

    Two particle correlations between identified meson and baryon trigger particles with 2.5TT charged hadrons have been measured at midrapidity by the PHENIX experiment at RHIC in p+p,d+Au, and Au+Au collisions at √(sNN)=200 GeV. In noncentral Au+Au collisions, the probability of finding a hadron near in azimuthal angle to the trigger particles is almost identical for mesons and baryons and significantly higher than in p+p collisions. The associated yields for trigger baryons decrease in the most central collisions, consistent with some baryon production by thermal recombination in addition to hard scattering

  17. Mammalian sensitivity to elemental gold (Au?)

    Science.gov (United States)

    Eisler, R.

    2004-01-01

    There is increasing documentation of allergic contact dermatitis and other effects from gold jewelry, gold dental restorations, and gold implants. These effects were especially pronounced among females wearing body-piercing gold objects. One estimate of the prevalence of gold allergy worldwide is 13%, as judged by patch tests with monovalent organogold salts. Eczema of the head and neck was the most common response of individuals hypersensitive to gold, and sensitivity can last for at least several years. Ingestion of beverages containing flake gold can result in allergic-type reactions similar to those seen in gold-allergic individuals exposed to gold through dermal contact and other routes. Studies with small laboratory mammals and injected doses of colloidal gold showed increased body temperatures, accumulations in reticular cells, and dose enhancement in tumor therapy; gold implants were associated with tissue injuries. It is proposed that Au? toxicity to mammals is associated, in part, with formation of the more reactive Au+ and Au3+ species.

  18. Electric Field Induced Surface Modification of Au

    Energy Technology Data Exchange (ETDEWEB)

    Erchak, A.A.; Franklin, G.F.; Houston, J.E.; Mayer, T.M.; Michalske, T.A.

    1999-02-15

    We discuss the role of localized high electric fields in the modification of Au surfaces with a W probe using the Interfacial Force Microscope. Upon bringing a probe close to a Au surface, we measure both the interfacial force and the field emission current as a function of separation with a constant potential of 100 V between tip and sample. The current initially increases exponentially as the separation decreases. However, at a distance of less than {approximately} 500{angstrom} the current rises sharply as the surface begins to distort and rapidly close the gap. Retraction of the tip before contact is made reveals the formation of a mound on the surface. We propose a simple model, in which the localized high electric field under the tip assists the production of mobile Au adatoms by detachment from surface steps, and a radial field gradient causes a net flux of atoms toward the tip by surface diffusion. These processes give rise to an unstable surface deformation which, if left unchecked, results in a destructive mechanical contact. We discuss our findings with respect to earlier work using voltage pulses in the STM as a means of nanofabrication.

  19. Suppression of high transverse momentum π0 spectra in Au + Au collisions at RHIC

    Science.gov (United States)

    Kahana, D. E.; Kahana, S. H.

    2008-02-01

    Au + Au, s1/2 = 200 GeV measurements at RHIC, obtained with the PHENIX, STAR, PHOBOS and BRAHMS detectors, have all indicated a suppression of high p⊥ particle production, relative to an appropriately normalized NN level. For central collisions and vanishing pseudo-rapidity these experiments exhibit suppression in charged meson production, especially at medium-to-large transverse momenta. In the PHENIX experiment similar behaviour has been reported for π0 spectra. In a recent work [1] on the simpler D + Au interaction, to be considered perhaps as a tune-up for Au + Au, we reported on a pre-hadronic cascade mechanism which can explain the mixed observation of moderately reduced p⊥ suppression at higher pseudo-rapidity as well as the Cronin enhancement at mid-rapidity. Here, we present the extension of this work to the more massive ion-ion collisions. Our major thesis is that much of the suppression is generated in a late stage cascade of colourless pre-hadrons produced after an initial short-lived coloured phase. We present a pQCD argument to justify this approach and to estimate the time duration τp of this initial phase. Of essential importance is the brevity in time of the coloured phase existence relative to that of the strongly interacting pre-hadron phase, the latter essentially an interactive cascade. These distinctions in phase are of course not strict, but adequate for treating the suppression of moderate and high p⊥ mesons.

  20. Modelling of global crop production and resulting N2O emissions

    OpenAIRE

    Stehfest, Elke

    2005-01-01

    Landwirtschaft spielt eine zentrale Rolle im Erdsystem. Sie trägt durch die Emission von CO2, CH4 und N2O zum Treibhauseffekt bei, kann Bodendegradation und Eutrophierung verursachen, regionale Wasserkreisläufe verändern und wird außerdem stark vom Klimawandel betroffen sein. Da all diese Prozesse durch die zugrunde liegenden Nährstoff- und Wasserflüsse eng miteinander verknüpft sind, sollten sie in einem konsistenten Modellansatz betrachtet werden. Dennoch haben Datenmangel und ungenügendes ...

  1. Charge transport through O-deficient Au-MgO-Au junctions

    KAUST Repository

    Fadlallah, M. M.

    2009-12-29

    Metal-oxide heterostructures have been attracting considerable attention in recent years due to various technological applications. We present results of electronic structure and transport calculations for the Au-MgO-Au (metal-insulator-metal) heterostructure based on density-functional theory and the nonequilibrium Green’s functions method. The dependence of the conductance of the heterostructure on the thickness of the MgO interlayer and the interface spacing is studied. In addition, we address the effects of O vacancies. We observe deviations from an exponentially suppressed conductance with growing interlayer thickness caused by Au-O chemical bonds. Electronic states tracing back to O vacancies can increase the conductance. Furthermore, this effect can be enhanced by enlarging the interface spacing as the vacancy induced Mg states are shifted toward the Fermi energy.

  2. 40 CFR 98.278 - Definitions.

    Science.gov (United States)

    2010-07-01

    ... Lime Kiln and Calciner Emissions Factors for Fossil Fuel-Based CO2, CH4, and N2O Fuel Fossil fuel-based emissions factors (kg/mmBtu HHV) Kraft lime kilns CO2 CH4 N2O Kraft calciners CO2 CH4 N2O Residual Oil...

  3. Synthesis and characterization of Au@Pt nanoparticles

    Institute of Scientific and Technical Information of China (English)

    ZHAO Dan; WU Gang; XU Boqing

    2005-01-01

    Aucore-Ptshell (Au@Pt) nanoparticles were synthesized at room temperature by reducing K2PtCl6 with hydrogen in the solution containing Au colloids and polyvinylpyrrolidone (PVP). The particles obtained were characterized with UV-Vis, TEM and XPS techniques. UV-Vis spectra show that the surface plasmon absorption feature of Au colloids is significantly reduced with increasing the amount of reduced Pt. TEM images that the metals are found always appear as spherical nanoparticles and their sizes grow apparently due to the reduction of PtCl62- ions, indicating that Pt is deposited from solution onto Au particle surface and forms a Pt-layer with uniform thickness. In the XPS spectra, the signals of Au metal decrease due to the reductive deposition of Pt on the surface of the Au colloids. UV-Vis and XPS data are consistent in showing that when the amount of Pt in the AuPt colloids is increased to reach an overall atomic ratio of Pt/Au=2, the Pt deposits form a shell covering completely the surface of Au particles, demonstrating the core-shell structure of the synthesized AuPt particles.

  4. Enrichment of the Superheavy Element Rg in Natural Au

    CERN Document Server

    Marinov, A; Kolb, D; Halicz, L; Segal, I; Tepliakov, N; Kashiv, Y; Brandt, R

    2010-01-01

    Based on the observation of the long-lived isotopes 261Rg and 265Rg (Z = 111, t(1/2) >= 10^(8) y) in natural Au, an experiment was performed to enrich Rg in 99.999% Au. 16 mg of Au were heated in vacuum for two weeks at a temperature of 1127 deg. C (63 deg. C above the melting point of Au). The content of 197Au and 261Rg in the residue was studied with high resolution inductively coupled plasma-sector field mass spectrometry (ICP-SFMS). The residue of Au was 3x10^(-6) of its original quantity. The recovery of Rg was a few percent. The abundance of Rg compared to Au in the enriched solution was about 2x10^(-6), which is a three to four orders of magnitude enrichment. It is concluded that the evaporation rate of Rg from an Au matrix in vacuum at 63 deg. C above the Au melting point is lower than that of Au. This experiment reinforces our first observation of Rg in a terrestrial material. As before it is concluded that a long-lived isomeric state exists in 261Rg and that it probably belongs to a new class of iso...

  5. Strangelet search in Au+Au collisions at VsNN=200 GeV

    OpenAIRE

    Bai, Y.(Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, China); Benedosso, F.; Botje, M.A.J.; Grebenyuk, O.; Mischke, A.; Peitzmann, T.; Russcher, M.J.; Snellings, R.J.M.; van der Kolk, N.

    2007-01-01

    We have searched for strangelets in a triggered sample of 61 million central (top 4%) Au+Au collisions at √sNN=200 GeV near beam rapidities at the STAR solenoidal tracker detector at the BNL Relativistic Heavy Ion Collider. We have sensitivity to metastable strangelets with lifetimes of order ⩾0.1 ns, in contrast to limits over ten times longer in BNL Alternating Gradient Synchrotron (AGS) studies and longer still at the CERN Super Proton Synchrotron (SPS). Upper limits of a few 10-6 to 10-7 ...

  6. Relativistic multireference many-body perturbation theory calculations on Au64+ - Au69+ ions

    Energy Technology Data Exchange (ETDEWEB)

    Vilkas, M J; Ishikawa, Y; Trabert, E

    2006-03-31

    Many-body perturbation theory (MBPT) calculations are an adequate tool for the description of the structure of highly charged multi-electron ions and for the analysis of their spectra. They demonstrate this by way of a re-investigation of n=3, {Delta}n=0 transitions in the EUV spectra of Na-, Mg-, Al-like, and Si-like ions of Au that have been obtained previously by heavy-ion accelerator based beam-foil spectroscopy. They discuss the evidence and propose several revisions on the basis of the multi-reference many-body perturbation theory calculations of Ne- through P-like ions of Au.

  7. PARTON STRUCTURE THROUGH TWO PARTICLE CORRELATIONS IN AU-AU AT RHIC.

    Energy Technology Data Exchange (ETDEWEB)

    LONGACRE,R.S.

    1999-10-23

    A method for determining the presence of partonic scattering through two-particle correlations is developed and applied to models which have jets and mini-jets in them. We only consider the correlation of mid-rapidity particles because they will be easily measured in large numbers at RHIC. The level of two-particle correlations will be a direct measure of how dense a system is made in Au-Au collisions at RHIC. The STAR TPC will be ideal for making these measurements in the first year of running.

  8. Elliptic flow in Au+Au collisions at $\\sqrt{S_{NN}}$=130 GeV

    CERN Document Server

    Ackermann, K H; Adler, C; Ahammed, Z; Ahmad, S; Allgower, C; Amsbaugh, J; Anderson, M; Anderssen, E; Arnesen, H; Arnold, L; Averichev, G S; Baldwin, A R; Balewski, J T; Barannikova, O Yu; Barnby, L S; Baudot, J; Beddo, M E; Bekele, S; Belaga, V V; Bellwied, R; Bennett, S; Bercovitz, J; Berger, J; Betts, W; Bichsel, H; Bieser, F; Bland, L C; Bloomer, M A; Blyth, C O; Böhm, J; Bonner, B E; Bonnet, D; Bossingham, R R; Botlo, M; Boucham, A; Bouillo, N; Bouvier, S; Bradley, K; Brady, F P; Braithwaite, E S; Braithwaite, W; Brandin, A B; Brown, R L; Brugalette, G; Byrd, C; Caines, H; Calderón de la Barca-Sanchez, M; Cardenas, A; Carr, L; Carroll, J; Castillo, J; Caylor, B; Cebra, D; Chathopadhyay, S; Chen, M L; Chen, W; Chen, Y; Chernenko, S P; Cherney, M; Chikanian, A; Choi, B; Chrin, J; Christie, W; Coffin, J P; Conin, L; Consiglio, C; Cormier, T M; Cramer, J G; Crawford, H J; Danilov, V I; Dayton, D; De Mello, M; Deng, W S; Derevshchikov, A A; Dialinas, M; Díaz, H; De Young, P A; Didenko, L; Dimassimo, D; Dioguardi, J; Dominik, Wojciech; Drancourt, C; Draper, J E; Dunin, V B; Dunlop, J C; Eckardt, V; Edwards, W R; Efimov, L G; Eggert, T; Emelyanov, V I; Engelage, J; Eppley, G; Erazmus, B; Etkin, A; Fachini, P; Feliciano, C; Ferenc, D; Ferguson, M I; Fessler, H; Finch, E; Fine, V; Fisyak, Yu; Flierl, D; Flores, I; Foley, Kenneth J; Fritz, D; Gagunashvili, N D; Gans, J; Gazdzicki, M; Germain, M; Geurts, F J M; Ghazikhanian, V; Gojak, C; Grabski, J; Grachov, O A; Grau, M; Greiner, D E; Greiner, L; Grigoriev, V; Grosnick, D P; Gross, J; Guilloux, G; Gushin, E M; Hall, J; Hallman, T J; Hardtke, D; Harper, G; Harris, J W; He, P; Heffner, M; Heppelmann, S; Herston, T; Hill, D; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Horsley, M; Howe, M; Huang, H Z; Humanic, T J; Hümmler, H; Hunt, W; Hunter, J; Igo, G; Ishihara, A; Ivanshin, Yu I; Jacobs, P; Jacobs, W W; Jacobson, S; Jared, R; Jensen, P; Johnson, I; Jones, P G; Judd, E; Kaneta, M; Kaplan, M; Keane, D; Kenney, V P; Khodinov, A; Klay, J L; Klein, S R; Klyachko, A A; Koehler, G; Konstantinov, A S; Kormilitsyne, V; Kotchenda, L; Kotov, I V; Kovalenko, A D; Krämer, M; Kravtsov, P; Krüger, K; Krupien, T; Kuczewski, P; Kühn, C E; Kunde, G J; Kunz, C L; Kutuev, R K; Kuznetsov, A A; Lakehal-Ayat, L; Lamont, M A C; Landgraf, J M; Lange, S; Lansdell, C P; Lasiuk, B; Laue, F; Lebedev, A; LeCompte, T J; Leonhardt, W; Leontiev, V M; Leszczynski, P; Le Vine, M J; Li, Q; Li, Z; Liaw, C J; Lin, J; Lindenbaum, S J; Lindenstruth, V; Lindstrom, P J; Lisa, M A; Liu, H; Ljubicic, T; Llope, W J; Lo Curto, G; Long, H; Longacre, R S; López-Noriega, M; Lopiano, D; Love, W A; Lutz, Jean Robert; Lynn, D; Madansky, L; Maier, R S; Majka, R; Maliszewski, A; Margetis, S; Marks, K; Marstaller, R; Martin, L; Marx, J; Matis, H S; Matulenko, Yu A; Matyushevsky, E A; McParland, C P; McShane, T S; Meier, J; Melnik, Yu M; Meshchanin, A P; Middlekamp, P; Mikhalin, N; Miller, B; Milosevich, Z; Minaev, N G; Minor, B; Mitchell, J; Mogavero, E; Moiseenko, V A; Moltz, D M; Moore, C F; Morozov, V; Morse, R; De Moura, M M; Munhoz, M G; Mutchler, G S; Nelson, J M; Nevski, P; Ngo, T; Nguyen, M; Nguyen, T; Nikitin, V A; Nogach, L V; Noggle, T; Norman, B; Nurushev, S B; Nussbaum, T; Nystrand, J; Odyniec, Grazyna Janina; Ogawa, A; Ogilvie, C A; Olchanski, K; Oldenburg, M; Olson, D; Ososkov, G A; Ott, G; Padrazo, D; Paic, G; Pandey, S U; Panebratsev, Yu A; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Pentia, M; Perevozchikov, V; Peryt, W; Petrov, V; Pinganaud, W; Pirogov, S; Platner, E D; Pluta, J; Polk, I; Porile, N T; Porter, J; Poskanzer, A M; Potrebenikova, E V; Prindle, D J; Pruneau, C A; Puskar-Pasewicz, J; Rai, G; Rasson, J E; Ravel, O; Ray, R L; Razin, S V; Reichhold, D M; Reid, J; Renfordt, R E; Retière, F; Ridiger, A; Riso, J; Ritter, H G; Roberts, J B; Röhrich, D; Rogachevski, O V; Romero, J L; Roy, C; Russ, D; Rykov, V L; Sakrejda, I; Sánchez, R; Sandler, Z; Sandweiss, J; Sappenfield, P; Saulys, A C; Savin, I A; Schambach, J; Scharenberg, R P; Scheblien, J; Scheetz, R; Schlüter, R; Schmitz, N; Schröder, L S; Schulz, M; Schüttauf, A; Sedlmeir, J; Seger, J E; Seliverstov, D M; Seyboth, J; Seyboth, P; Seymour, R; Shakaliev, E I; Shestermanov, K E; Shi, Y; Shimansky, S S; Shuman, D B; Shvetcov, V S; Skoro, G P; Smirnov, N; Smykov, L P; Snellings, R; Solberg, K; Sowinski, J; Spinka, H M; Srivastava, B; Stephenson, E J; Stock, Reinhard; Stolpovsky, A; Stone, N; Stone, R; Strikhanov, M N; Stringfellow, B C; Ströbele, H; Struck, C; Suaide, A A P; Sugarbaker, E R; Suire, C; Symons, T J M; Takahashi, J; Tang, A H; Tarchini, A; Tarzian, J; Thomas, J H; Tikhomirov, V; Szanto de Toledo, A; Tonse, S R; Trainor, T; Trentalange, S; Tokarev, M; Tonjes, M B; Trofimov, V N; Tsai, O; Turner, K; Ullrich, T S; Underwood, D G; Vakula, I; Van Buren, G; Van der Molen, A; Vanyashin, A V; Vasilevskii, I M; Vasilev, A N; Vigdor, S E; Visser, G; Voloshin, S A; Vu, C; Wang, F; Ward, H; Weerasundara, D D; Weidenbach, R; Wells, R; Wenaus, T J; Westfall, G D; Whitfield, J P; Whitten, C; Wieman, H H; Willson, R; Wilson, K; Wirth, J; Wisdom, J; Wissink, S W; Witt, R; Wolf, J; Wood, L; Xu, N; Xu, Z; Yakutin, A E; Yamamoto, E; Yang, J; Yepes, P; Yokosawa, A; Yurevich, V I; Zanevsky, Yu V; Zhang, J; Zhang, W M; Zhu, J; Zimmerman, D; Zoulkarneev, R; Zubarev, A N

    2001-01-01

    Elliptic flow from nuclear collisions is a hadronic observable sensitive to the early stages of system evolution. We report first results on elliptic flow of charged particles at midrapidity in Au+Au collisions at sqrt(s_NN)=130 GeV using the STAR TPC at RHIC. The elliptic flow signal, v_2, averaged over transverse momentum, reaches values of about 6% for relatively peripheral collisions and decreases for the more central collisions. This can be interpreted as the observation of a higher degree of thermalization than at lower collision energies. Pseudorapidity and transverse momentum dependence of elliptic flow are also presented.

  9. Spectator matter fragmentation in Au+Au reactions: Phase space analysis

    CERN Document Server

    Vermani, Yogesh K

    2011-01-01

    Clusterization in phase space has been analyzed for peripheral Au+Au reactions at 1000 AMeV using simulated annealing clusterization algorithm (SACA). We investigate how these fragments are correlated in phase space and compare our model calculations with minimum spanning tree (MST) method. Our theoretical study highlights the importance of binding energy criterion in recognizing the fragment structure. MST method however, fails to break-up the spectator matter effectively and thus under-estimates the multiplicity of intermediate mass fragments (IMFs).

  10. Energy Dependence of Particle Multiplicities in Central Au+Au Collisions

    Science.gov (United States)

    Back, B. B.; Baker, M. D.; Barton, D. S.; Betts, R. R.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Corbo, J.; Decowski, M. P.; Garcia, E.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Henderson, C.; Hicks, D.; Hofman, D.; Hollis, R. S.; Hołyński, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C. M.; Lin, W. T.; Manly, S.; McLeod, D.; Michałowski, J.; Mignerey, A.; Mülmenstädt, J.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Rafelski, M.; Rbeiz, M.; Reed, C.; Remsberg, L. P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Skulski, W.; Steadman, S. G.; Steinberg, P.; Stephans, G. S.; Stodulski, M.; Sukhanov, A.; Tang, J.-L.; Teng, R.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Verdier, R.; Wadsworth, B.; Wolfs, F. L.; Wosiek, B.; Woźniak, K.; Wuosmaa, A. H.; Wysłouch, B.

    2002-01-01

    We present the first measurement of the pseudorapidity density of primary charged particles in Au+Au collisions at (sNN) = 200 GeV. For the 6% most central collisions, we obtain dNch/dη\\|\\|η\\|<1 = 650+/-35(syst). Compared to collisions at (sNN) = 130 GeV, the highest energy studied previously, an increase by a factor of 1.14+/-0.05 at 90% confidence level, is found. The energy dependence of the pseudorapidity density is discussed in comparison with data from proton-induced collisions and theoretical predictions.

  11. Gold nanoparticle (AuNPs) and gold nanopore (AuNPore) catalysts in organic synthesis.

    Science.gov (United States)

    Takale, Balaram S; Bao, Ming; Yamamoto, Yoshinori

    2014-04-01

    Organic synthesis using gold has gained tremendous attention in last few years, especially heterogeneous gold catalysis based on gold nanoparticles has made its place in almost all organic reactions, because of the robust and green nature of gold catalysts. In this context, gold nanopore (AuNPore) with a 3D metal framework is giving a new dimension to heterogeneous gold catalysts. Interestingly, AuNPore chemistry is proving better than gold nanoparticles based chemistry. In this review, along with recent advances, major discoveries in heterogeneous gold catalysis are discussed.

  12. Observation of anisotropic event shapes and transverse flow in ultrarelativistic Au+Au collisions

    International Nuclear Information System (INIS)

    Event shapes for Au + Au collisions at 11.4 GeV/c per nucleon were studied over nearly the full solid angle with the E877 apparatus. The analysis was performed by Fourier expansion of azimuthal distributions of the transverse energy (ET) measured in different pseudorapidity intervals. For semicentral collisions a pronounced event anisotropy is identified with a clear forward-backward anticorrelation. In the forward pseudorapidity interval up to 9% of the ET is in a directed component. The signal decreases for peripheral and very central collisions

  13. Net charge fluctuations in Au + Au interactions at sqrt[s(NN)]=130 GeV.

    Science.gov (United States)

    Adcox, K; Adler, S S; Ajitanand, N N; Akiba, Y; Alexander, J; Aphecetche, L; Arai, Y; Aronson, S H; Averbeck, R; Awes, T C; Barish, K N; Barnes, P D; Barrette, J; Bassalleck, B; Bathe, S; Baublis, V; Bazilevsky, A; Belikov, S; Bellaiche, F G; Belyaev, S T; Bennett, M J; Berdnikov, Y; Botelho, S; Brooks, M L; Brown, D S; Bruner, N; Bucher, D; Buesching, H; Bumazhnov, V; Bunce, G; Burward-Hoy, J; Butsyk, S; Carey, T A; Chand, P; Chang, J; Chang, W C; Chavez, L L; Chernichenko, S; Chi, C Y; Chiba, J; Chiu, M; Choudhury, R K; Christ, T; Chujo, T; Chung, M S; Chung, P; Cianciolo, V; Cole, B A; D'Enterria, D G; David, G; Delagrange, H; Denisov, A; Deshpande, A; Desmond, E J; Dietzsch, O; Dinesh, B V; Drees, A; Durum, A; Dutta, D; Ebisu, K; Efremenko, Y V; El Chenawi, K; En'yo, H; Esumi, S; Ewell, L; Ferdousi, T; Fields, D E; Fokin, S L; Fraenkel, Z; Franz, A; Frawley, A D; Fung, S-Y; Garpman, S; Ghosh, T K; Glenn, A; Godoi, A L; Goto, Y; Greene, S V; Grosse Perdekamp, M; Gupta, S K; Guryn, W; Gustafsson, H-A; Haggerty, J S; Hamagaki, H; Hansen, A G; Hara, H; Hartouni, E P; Hayano, R; Hayashi, N; He, X; Hemmick, T K; Heuser, J M; Hibino, M; Hill, J C; Ho, D S; Homma, K; Hong, B; Hoover, A; Ichihara, T; Imai, K; Ippolitov, M S; Ishihara, M; Jacak, B V; Jang, W Y; Jia, J; Johnson, B M; Johnson, S C; Joo, K S; Kametani, S; Kang, J H; Kann, M; Kapoor, S S; Kelly, S; Khachaturov, B; Khanzadeev, A; Kikuchi, J; Kim, D J; Kim, H J; Kim, S Y; Kim, Y G; Kinnison, W W; Kistenev, E; Kiyomichi, A; Klein-Boesing, C; Klinksiek, S; Kochenda, L; Kochetkov, V; Koehler, D; Kohama, T; Kotchetkov, D; Kozlov, A; Kroon, P J; Kurita, K; Kweon, M J; Kwon, Y; Kyle, G S; Lacey, R; Lajoie, J G; Lauret, J; Lebedev, A; Lee, D M; Leitch, M J; Li, X H; Li, Z; Lim, D J; Liu, M X; Liu, X; Liu, Z; Maguire, C F; Mahon, J; Makdisi, Y I; Manko, V I; Mao, Y; Mark, S K; Markacs, S; Martinez, G; Marx, M D; Masaike, A; Matathias, F; Matsumoto, T; McGaughey, P L; Melnikov, E; Merschmeyer, M; Messer, F; Messer, M; Miake, Y; Miller, T E; Milov, A; Mioduszewski, S; Mischke, R E; Mishra, G C; Mitchell, J T; Mohanty, A K; Morrison, D P; Moss, J M; Mühlbacher, F; Muniruzzaman, M; Murata, J; Nagamiya, S; Nagasaka, Y; Nagle, J L; Nakada, Y; Nandi, B K; Newby, J; Nikkinen, L; Nilsson, P; Nishimura, S; Nyanin, A S; Nystrand, J; O'Brien, E; Ogilvie, C A; Ohnishi, H; Ojha, I D; Ono, M; Onuchin, V; Oskarsson, A; Osterman, L; Otterlund, I; Oyama, K; Paffrath, L; Palounek, A P T; Pantuev, V S; Papavassiliou, V; Pate, S F; Peitzmann, T; Petridis, A N; Pinkenburg, C; Pisani, R P; Pitukhin, P; Plasil, F; Pollack, M; Pope, K; Purschke, M L; Ravinovich, I; Read, K F; Reygers, K; Riabov, V; Riabov, Y; Rosati, M; Rose, A A; Ryu, S S; Saito, N; Sakaguchi, A; Sakaguchi, T; Sako, H; Sakuma, T; Samsonov, V; Sangster, T C; Santo, R; Sato, H D; Sato, S; Sawada, S; Schlei, B R; Schutz, Y; Semenov, V; Seto, R; Shea, T K; Shein, I; Shibata, T-A; Shigaki, K; Shiina, T; Shin, Y H; Sibiriak, I G; Silvermyr, D; Sim, K S; Simon-Gillo, J; Singh, C P; Singh, V; Sivertz, M; Soldatov, A; Soltz, R A; Sorensen, S; Stankus, P W; Starinsky, N; Steinberg, P; Stenlund, E; Ster, A; Stoll, S P; Sugioka, M; Sugitate, T; Sullivan, J P; Sumi, Y; Sun, Z; Suzuki, M; Takagui, E M; Taketani, A; Tamai, M; Tanaka, K H; Tanaka, Y; Taniguchi, E; Tannenbaum, M J; Thomas, J; Thomas, J H; Thomas, T L; Tian, W; Tojo, J; Torii, H; Towell, R S; Tserruya, I; Tsuruoka, H; Tsvetkov, A A; Tuli, S K; Tydesjö, H; Tyurin, N; Ushiroda, T; van Hecke, H W; Velissaris, C; Velkovska, J; Velkovsky, M; Vinogradov, A A; Volkov, M A; Vorobyov, A; Vznuzdaev, E; Wang, H; Watanabe, Y; White, S N; Witzig, C; Wohn, F K; Woody, C L; Xie, W; Yagi, K; Yokkaichi, S; Young, G R; Yushmanov, I E; Zajc, W A; Zhang, Z; Zhou, S

    2002-08-19

    Data from Au + Au interactions at sqrt[s(NN)]=130 GeV, obtained with the PHENIX detector at the Relativistic Heavy-Ion Collider, are used to investigate local net charge fluctuations among particles produced near midrapidity. According to recent suggestions, such fluctuations may carry information from the quark-gluon plasma. This analysis shows that the fluctuations are dominated by a stochastic distribution of particles, but are also sensitive to other effects, like global charge conservation and resonance decays. PMID:12190459

  14. Light Fragment Production and Power Law Behavior in Au + Au Collisions

    International Nuclear Information System (INIS)

    Using charged-particle-exclusive measurements of Au+Au collisions in the LBL Bevalac's EOS time projection chamber, we investigate momentum-space densities of fragments up to 4He as a function of fragment transverse momentum, azimuth relative to the reaction plane, rapidity, multiplicity, and beam energy. Most features of these densities above a transverse momentum threshold are consistent with momentum-space coalescence, and, in particular, the increase in sideward flow with fragment mass is generally well described by a momentum-space power law

  15. On direct photon production in Pb+Pb and Au+Au collisions

    CERN Document Server

    Guptaroy, P

    2003-01-01

    Some aspects of the direct photon production phenomenon are discussed, mainly in the Pb+Pb and Au+Au collisions on the basis of a model for production of the same particle species in PP collisions. The results have, thereafter, been converted to those for a few AB/AA interactions through an appropriate mechanism. Comparison of the theoretical results obtained on the basis of model-based calculations with measured data on the relevant observables leads to a fair agreement between them. This reflects modestly the fair achievements attained by the models that are made use of in the present work. (author)

  16. On direct photon production in Pb+Pb and Au+Au collisions

    International Nuclear Information System (INIS)

    Some aspects of the direct photon production phenomenon are discussed, mainly in the Pb+Pb and Au+Au collisions on the basis of a model for production of the same particle species in PP collisions. The results have, thereafter, been converted to those for a few AB/AA interactions through an appropriate mechanism. Comparison of the theoretical results obtained on the basis of model-based calculations with measured data on the relevant observables leads to a fair agreement between them. This reflects modestly the fair achievements attained by the models that are made use of in the present work. (author)

  17. Sideward Flow in Au + Au Collisions Between 2 AGeV and 8 AGeV

    CERN Document Server

    Liu, H; Alexander, J; Anderson, M; Best, D; Brady, F P; Case, T; Caskey, W; Cebra, D; Chance, J; Chung, P; Cole, B; Crowe, K M; Das, A; Draper, J E; Gilkes, M L; Gushue, S; Heffner, M; Hirsch, A; Hjort, E; Huo, L; Justice, M; Kaplan, M; Keane, D; Kintner, J; Klay, J L; Krofcheck, D; Lacey, R A; Lisa, M A; Liu, Y M; McGrath, R; Milosevich, Z; Odyniec, Grazyna Janina; Olson, D; Panitkin, S Y; Pinkenburg, C H; Porile, N T; Rai, G; Ritter, H G; Romero, J; Scharenberg, R P; Schröder, L S; Srivastava, B; Stone, N T B; Symons, T J M; Wang, S; Whitfield, J; Wienold, T; Witt, R; Wood, L; Yang, X; Zhang Wei Ning; Zhang, Y

    2000-01-01

    Using the large acceptance Time Projection Chamber of experiment E895 at Brookhaven, measurements of collective sideward flow in Au + Au collisions at beam energies of 2, 4, 6 and 8A GeV are presented in the form of in-plane transverse momentum and the first Fourier coefficient of azimuthal anisotropy v_1. These measurements indicate a smooth variation of sideward flow as a function of beam energy. The data are compared with four nuclear transport models which have an orientation towards this energy range. All four exhibit some qualitative trends similar to those found in the data, although none shows a consistent pattern of agreement within experimental uncertainties.

  18. Charged Pion Production in 2 to 8 AGeV Central Au+Au Collisions

    CERN Document Server

    Klay, J L; Alexander, J M; Anderson, M G; Best, D; Brady, F P; Case, T; Caskey, W; Cebra, D; Chance, J L; Chung, P; Cole, B; Crowe, K; Das, A C; Draper, J E; Gilkes, M L; Gushue, S; Heffner, M; Hirsch, A S; Hjort, E L; Huo, L; Justice, M; Kaplan, M; Keane, D; Kintner, J C; Krofcheck, D; Lacey, R A; Lauret, J; Law, C; Lisa, M A; Liu, H; Liu, Y M; McGrath, R; Milosevich, Z; Odyniec, Grazyna Janina; Olson, D L; Panitkin, S Y; Pinkenburg, C H; Porile, N T; Rai, G; Ritter, H G; Romero, J L; Scharenberg, R P; Srivastava, B; Stone, N T B; Symons, T J M; Wang, S; Wells, R; Whitfield, J; Wienold, T; Witt, R; Wood, L; Zhang Wei Ning

    2003-01-01

    Momentum spectra of charged pions over nearly full rapidity coverage from target to beam rapidity have been measured in the 0-5% most central Au+Au collisions in the beam energy range from 2 to 8 AGeV by the E895 Experiment. Using a thermal parameterization to fit the transverse mass spectra, rapidity density distributions are extracted. The observed spectra are compared with predictions from the RQMD v2.3 cascade model and also to a thermal model including longitudinal flow. The total 4$pi$ yields of the charged pions are used to infer an initial state entropy produced in the collisions.

  19. Beam-Energy Dependence of Charge Balance Functions from Au+Au Collisions at RHIC

    OpenAIRE

    STAR Collaboration

    2015-01-01

    Balance functions have been measured in terms of relative pseudorapidity ($\\Delta \\eta$) for charged particle pairs at the Relativistic Heavy-Ion Collider (RHIC) from Au+Au collisions at $\\sqrt{s_{\\rm NN}}$ = 7.7 GeV to 200 GeV using the STAR detector. These results are compared with balance functions measured at the Large Hadron Collider (LHC) from Pb+Pb collisions at $\\sqrt{s_{\\rm NN}}$ = 2.76 TeV by the ALICE Collaboration. The width of the balance function decreases as the collisions beco...

  20. Beam Energy Scan a Case for the Chiral Magnetic Effect in Au-Au Collisions

    Energy Technology Data Exchange (ETDEWEB)

    Longacre, R. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2014-01-05

    The Chiral Magnetic Effect (CME) is predicted for Au-Au collisions at RHIC. However, many backgrounds can give signals that make the measurement hard to interpret. The STAR experiment has made measurements at different collisions energy ranging from √(sNN)=7.7 GeV to 62.4 GeV. In the analysis that is presented we show that the CME turns on with energy and is not present in central collisions where the induced magnetic is small.

  1. Azimuthal Anisotropy of Identified Hadrons in 200 GeV Au+Au Collisions

    CERN Document Server

    Oldenburg, M

    2006-01-01

    The azimuthal anisotropy parameter v2 has been measured with high statistics for identified hadrons in sqrt(s_NN) = 200 GeV Au+Au collisions with the STAR experiment. At high transverse momentum (pT) a strong v2 for pi+ + pi- and p + pbar is observed. In the intermediate pT region, number-of-constituent-quark scaling was tested to high precision. A detailed comparison of v2 for the multi-strange hadrons phi, Xi + anti-Xi, and Omega + anti-Omega with other particle species substantiates the development of collectivity among partons in the early phase of the collisions at RHIC.

  2. Au/Pd core-shell nanoparticles with varied hollow Au cores for enhanced formic acid oxidation

    Science.gov (United States)

    Hsu, Chiajen; Huang, Chienwen; Hao, Yaowu; Liu, Fuqiang

    2013-03-01

    A facile method has been developed to synthesize Au/Pd core-shell nanoparticles via galvanic replacement of Cu by Pd on hollow Au nanospheres. The unique nanoparticles were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, ultraviolet-visible spectroscopy, and electrochemical measurements. When the concentration of the Au solution was decreased, grain size of the polycrystalline hollow Au nanospheres was reduced, and the structures became highly porous. After the Pd shell formed on these Au nanospheres, the morphology and structure of the Au/Pd nanoparticles varied and hence significantly affected the catalytic properties. The Au/Pd nanoparticles synthesized with reduced Au concentrations showed higher formic acid oxidation activity (0.93 mA cm-2 at 0.3 V) than the commercial Pd black (0.85 mA cm-2 at 0.3 V), suggesting a promising candidate as fuel cell catalysts. In addition, the Au/Pd nanoparticles displayed lower CO-stripping potential, improved stability, and higher durability compared to the Pd black due to their unique core-shell structures tuned by Au core morphologies.

  3. Thermal stability of Mo/Au bilayers for TES applications

    International Nuclear Information System (INIS)

    Mo/Au bilayers are among the most suitable materials to be used as transition-edge sensors (TES) in cryogenic microcalorimeters and bolometers, developed, among other fields, for space missions. For this purpose the thermal stability of TES at temperatures below 150 °C is a critical issue. We report on the dependence of functional properties (superconducting critical temperature, residual resistance and α) as well as on microstructure, chemical composition and interface quality for optimized high quality Mo/Au bilayers on annealing temperature and time. Data show that the functional properties of the bilayers remain stable at T C at T ≥ 200 °C are mainly due to an increase in the average Au grain size and to Au migration along the Mo grain boundaries at the Au/Mo interface. A way to stabilize the functional properties of the Mo/Au bilayers against temperature enhancements is proposed. (paper)

  4. Anomalous magnetic moment at Ba in Au

    Science.gov (United States)

    Bhati, A. K.; Kaur, J.; Bansal, N.; Negi, D.; Kumar, R.; Bhowmik, R. K.; Kumar, V.; Dey, C. C.

    2015-04-01

    The Time differential perturbed angular distribution (TDPAD) technique is employed to measure the local susceptibility at the recoil implanted Ba ions in Au following the nuclear reaction 120Sn(12C, 3nγ)129Ba. We have observed first time the local paramagnetic susceptibility of 5.26(18) at Ba ions comparable to 4f-ions in any non-ferromagnetic metal at room temperature which seems to be related to the electronic s-d and s-f transfer at positive lattice pressure.

  5. Le risque alimentaire face au consommateur

    OpenAIRE

    Didier Torny

    2005-01-01

    Dans le contexte contemporain de multiplication des crises sanitaires, de nombreux travaux en sciences économiques et sociales ont cherché à décrire et analyser le comportement des consommateurs face au risque alimentaire. Ces travaux partagent globalement deux prémisses : ils considèrent l'acte de consommation comme un comportement individuel et attribuent aux consommateurs des "perceptions du risque" qui orientent leurs choix. Une critique de ces deux axiomes amène à soulever la question de...

  6. Les produits de terroir au Niger

    OpenAIRE

    Luxereau, Anne

    2013-01-01

    Les productions agricoles localisées, bénéficiant de ce fait d’une notoriété particulière, existent depuis longtemps en Afrique. Au Niger, elles sont nombreuses et leur statut est diversifié, entre des produits « patrimoines » et d’autres qui constituent des opportunités économiques récentes. Longtemps ignorés des projets de développement, ils connaissent actuellement des évolutions disparates mais la plupart du temps endogènes, « informelles » et innovantes. Tous commercialisés, ils particip...

  7. Que faisons-nous au CERN ?

    CERN Multimedia

    1999-01-01

    Le CERN a pour vocation la science pure, l'étude des questions les plus fondamentales de la nature:Qu'est-ce que la matière ?D'ou vient-elle ? Comment s'agglomère-t-elle en formes complexes comme les étoiles, les planètes et les êtres humains ? Au CERN, les collisions de particules servent à sonder le coeur de la matière et les chercheurs du Laboratoire étudient ces millions de collisions de particules afin de trouver des réponses à ces questions.

  8. Phase behavior of Au and Pt surfaces

    DEFF Research Database (Denmark)

    Grübel, G.; Gibbs, D.; Zehner, D.M.;

    1993-01-01

    We summarize the results of X-ray scattering studies of the Au(001) and Pt(001) surfaces between 300 K and their respective bulk melting temperatures (T(m)). Both surfaces exhibit three distinct structural phases. At high temperatures (0.88T(m) < T < T(m)) both surfaces are disordered. The Pt(001......) surface is rough. At a temperature of T/T(m) almost-equal-to 0.88 there are reversible phase transformations to incommensurate, corrugated-hexagonal phases. Below T/T(m) almost-equal-to 0.8 hexagonal domains rotate with respect to the substrate orientation. In Pt, the rotational transformation is...

  9. Les frameworks au coeur des applications web

    OpenAIRE

    Moro, Arielle; Daehne, Peter

    2010-01-01

    Depuis quelques années, Internet est vraiment entré dans les mœurs : tant dans les entreprises qu’au sein de chaque foyer. En effet, Internet permet de communiquer à travers le monde en quelques secondes, de vendre toute sorte de produits en déployant des solutions e-commerce facilement et bien d’autres choses. Internet est donc un véritable vecteur de communication, de commerce et à présent, avec le Web 2.0, un vrai berceau d’informations (tant des informations personnelles que des informati...

  10. Transition probability studies in 175Au

    International Nuclear Information System (INIS)

    Transition probabilities have been measured between the low-lying yrast states in 175Au by employing the recoil distance Doppler-shift method combined with the selective recoil-decay tagging technique. Reduced transition probabilities and magnitudes of transition quadrupole moments have been extracted from measured lifetimes allowing dramatic changes in nuclear structure within a low excitation-energy range to probed. The transition quadrupole moment data are discussed in terms of available systematics as a function of atomic number and aligned angular momentum.

  11. Compressive mechanical behavior of Au nanowires

    Energy Technology Data Exchange (ETDEWEB)

    Wen Yuhua, E-mail: yhwen@xmu.edu.c [Department of Physics, and Institute of Theoretical Physics and Astrophysics, Xiamen University, Xiamen 361005 (China); Department of Mechanical and Manufacturing Engineering, University of Manitoba, Winnipeg, Manitoba, R3T 5V6 (Canada); Wang Quan, E-mail: q_wang@umanitoba.c [Department of Mechanical and Manufacturing Engineering, University of Manitoba, Winnipeg, Manitoba, R3T 5V6 (Canada); Liew, Kim Meow [Department of Building and Construction, City University of Hong Kong (Hong Kong); Zhu Zizhong [Department of Physics, and Institute of Theoretical Physics and Astrophysics, Xiamen University, Xiamen 361005 (China)

    2010-06-28

    The structural evolution, deformation mechanism, and failure behavior of Au [001] nanowires with various sizes and slenderness ratios under uniaxial compression have been investigated using molecular dynamics. The results show that the elastic modulus, yield stress, and strain all are dependent on the diameters and slenderness ratios of the nanowires. Buckling behavior is observed in a long nanowire, followed by slips in the {l_brace}111{r_brace} planes. Differences are identified in the failure behavior of a short nanowire and a medium nanowire, although the plastic deformation of both types of nanowire originates from the slips in the {l_brace}111{r_brace} planes.

  12. Compressive mechanical behavior of Au nanowires

    International Nuclear Information System (INIS)

    The structural evolution, deformation mechanism, and failure behavior of Au [001] nanowires with various sizes and slenderness ratios under uniaxial compression have been investigated using molecular dynamics. The results show that the elastic modulus, yield stress, and strain all are dependent on the diameters and slenderness ratios of the nanowires. Buckling behavior is observed in a long nanowire, followed by slips in the {111} planes. Differences are identified in the failure behavior of a short nanowire and a medium nanowire, although the plastic deformation of both types of nanowire originates from the slips in the {111} planes.

  13. Photosynthetic electron transport system promotes synthesis of Au-nanoparticles.

    Science.gov (United States)

    Shabnam, Nisha; Pardha-Saradhi, P

    2013-01-01

    In this communication, a novel, green, efficient and economically viable light mediated protocol for generation of Au-nanoparticles using most vital organelle, chloroplasts, of the plant system is portrayed. Thylakoids/chloroplasts isolated from Potamogeton nodosus (an aquatic plant) and Spinacia oleracea (a terrestrial plant) turned Au³⁺ solutions purple in presence of light of 600 µmol m⁻² s⁻¹ photon flux density (PFD) and the purple coloration intensified with time. UV-Vis spectra of these purple colored solutions showed absorption peak at ∼545 nm which is known to arise due to surface plasmon oscillations specific to Au-nanoparticles. However, thylakoids/chloroplasts did not alter color of Au³⁺ solutions in dark. These results clearly demonstrated that photosynthetic electron transport can reduce Au³⁺ to Au⁰ which nucleate to form Au-nanoparticles in presence of light. Transmission electron microscopic studies revealed that Au-nanoparticles generated by light driven photosynthetic electron transport system of thylakoids/chloroplasts were in range of 5-20 nm. Selected area electron diffraction and powder X-ray diffraction indicated crystalline nature of these nanoparticles. Energy dispersive X-ray confirmed that these nanoparticles were composed of Au. To confirm the potential of light driven photosynthetic electron transport in generation of Au-nanoparticles, thylakoids/chloroplasts were tested for their efficacy to generate Au-nanoparticles in presence of light of PFD ranging from 60 to 600 µmol m⁻² s⁻¹. The capacity of thylakoids/chloroplasts to generate Au-nanoparticles increased remarkably with increase in PFD, which further clearly demonstrated potential of light driven photosynthetic electron transport in reduction of Au³⁺ to Au⁰ to form nanoparticles. The light driven donation of electrons to metal ions by thylakoids/chloroplasts can be exploited for large scale production of nanoparticles. PMID:23976990

  14. Photosynthetic electron transport system promotes synthesis of Au-nanoparticles.

    Directory of Open Access Journals (Sweden)

    Nisha Shabnam

    Full Text Available In this communication, a novel, green, efficient and economically viable light mediated protocol for generation of Au-nanoparticles using most vital organelle, chloroplasts, of the plant system is portrayed. Thylakoids/chloroplasts isolated from Potamogeton nodosus (an aquatic plant and Spinacia oleracea (a terrestrial plant turned Au³⁺ solutions purple in presence of light of 600 µmol m⁻² s⁻¹ photon flux density (PFD and the purple coloration intensified with time. UV-Vis spectra of these purple colored solutions showed absorption peak at ∼545 nm which is known to arise due to surface plasmon oscillations specific to Au-nanoparticles. However, thylakoids/chloroplasts did not alter color of Au³⁺ solutions in dark. These results clearly demonstrated that photosynthetic electron transport can reduce Au³⁺ to Au⁰ which nucleate to form Au-nanoparticles in presence of light. Transmission electron microscopic studies revealed that Au-nanoparticles generated by light driven photosynthetic electron transport system of thylakoids/chloroplasts were in range of 5-20 nm. Selected area electron diffraction and powder X-ray diffraction indicated crystalline nature of these nanoparticles. Energy dispersive X-ray confirmed that these nanoparticles were composed of Au. To confirm the potential of light driven photosynthetic electron transport in generation of Au-nanoparticles, thylakoids/chloroplasts were tested for their efficacy to generate Au-nanoparticles in presence of light of PFD ranging from 60 to 600 µmol m⁻² s⁻¹. The capacity of thylakoids/chloroplasts to generate Au-nanoparticles increased remarkably with increase in PFD, which further clearly demonstrated potential of light driven photosynthetic electron transport in reduction of Au³⁺ to Au⁰ to form nanoparticles. The light driven donation of electrons to metal ions by thylakoids/chloroplasts can be exploited for large scale production of nanoparticles.

  15. Energy level alignment in Au/pentacene/PTCDA trilayer stacks

    OpenAIRE

    Sehati, Parisa; Braun, Slawomir; Fahlman, Mats

    2013-01-01

    Ultraviolet photoelectron spectroscopy is used to investigate the energy level alignment and molecular orientation at the interfaces in Au/pentacene/PTCDA trilayer stacks. We deduced a standing orientation for pentacene grown on Au while we conclude a flat lying geometry for PTCDA grown onto pentacene. We propose that the rough surface of polycrystalline Au induces the standing geometry in pentacene. It is further shown that in situ deposition of PTCDA on pentacene can influence the orientati...

  16. Evaluation of the Olympus AU 400 clinical chemistry analyzer.

    Science.gov (United States)

    Bilić, A; Alpeza, I; Rukavina, A S

    2000-01-01

    The performance of the Olympus AU 400 clinical chemistry analyzer was evaluated according to the guidelines of the European Committee for Clinical Laboratory Standards. The following analytes were tested: glucose, urea, creatinine, calcium, AST, ALT, CK, LDH, ALP and amylase. The Olympus AU 400 was compared with the Olympus AU 800. Coefficients of correlation showed high correlation between the compared analyzers. Other performances (intra- and inter-assay variation, carry-over and interferences) of the analyzer were satisfactory.

  17. Nonlinear optical properties of Au/PVP composite thin films

    Institute of Scientific and Technical Information of China (English)

    Shen Hong; Cheng Bo-Lin; Lu Guo-Wei; Wang Wei-Tian; Guan Dong-Yi; Chen Zheng-Hao; Yang Guo-Zhen

    2005-01-01

    Colloidal Au and poly(vinylpyrrolidone) (PVP) composite thin films are fabricated by spin-coating method. Linear optical absorption measurements of the Au/PVP composite films indicate an absorption peak around 530 nm due to the surface plasmon resonance of gold nanoparticles. Nonlinear optical properties are studied using standard Z-scan technique, and experimental results show large optical nonlinearities of the Au/PVP composite films. A large value of films.

  18. Charged-particle rapidity density in Au+Au collisions in a quark combination model

    Science.gov (United States)

    Shao, Feng-Lan; Yao, Tao; Xie, Qu-Bing

    2007-03-01

    Rapidity/pseudorapidity densities for charged particles and their centrality, rapidity, and energy dependence in Au+Au collisions at the Relativistic Heavy Ion Collider are studied in a quark combination model. Using a Gaussian-type rapidity distribution for constituent quarks as a result of Landau hydrodynamic evolution, the data at sNN=130,200 GeV at various centralities in full pseudorapidity range are well described, and the charged-particle multiplicities are reproduced as functions of the number of participants. The energy dependence of the shape of the dNch/dη distribution is also described at various collision energies sNN=200,130,62.4 GeV in central collisions with same value of parameters except 19.6 GeV. The calculated rapidity distributions and yields for the charged pions and kaons in central Au+Au collisions at sNN=200 GeV are compared with experimental data of the BRAHMS Collaboration.

  19. Degree of chemical nonequilibrium in central Au-Au collisions at RHIC energies

    Science.gov (United States)

    Tawfik, Abdel Nasser; El-Bakry, M. Y.; Habashy, D. M.; Mohamed, M. T.; Abbas, Ehab

    2015-08-01

    In this paper, we investigate the difference between hadron resonance gas (HRG) calculations for chemical freeze-out parameters at fully and partly chemical equilibria. To this end, the results are compared with the particle ratios measured in central Au-Au collisions at a wide range of nucleon-nucleon center-of-mass energies, √ {s{ NN}} = 7.7 - 200 GeV as offered by the STAR experiment. We restrict the discussion to STAR, because of large statistics and overall homogeneity of STAR measurements (one detector) against previous experiments. We find that the matter produced at these energies is likely in fully chemical equilibria, which is consistent with recent lattice quantum chromodynamics (QCD) results. The possible improvements by partial chemical equilibria (γS ≠ 1) are very limited. We also discuss these results with the ones deduced from ϕ/π- and Ω-/π- ratios. These hadron ratios are sensitive to the degree of chemical equilibrium. Accordingly, the conclusion that the matter produced reaches fully chemical equilibria in central Au-Au at relativistic heavy-ion collider (RHIC) energies is confirmed.

  20. The self assembly of thymine at Au(110)/liquid interfaces

    Energy Technology Data Exchange (ETDEWEB)

    Molina Contreras, J.R. [Departamento de Ingenieria Electrica y Electronica, Instituto Tecnologico de Aguascalientes, Mexico (Mexico); Smith, C.I.; Bowfield, A.; Weightman, P. [Physics Department, University of Liverpool (United Kingdom); Tillner, F. [Fachbereich Physik, Universitaet Konstanz (Germany)

    2012-06-15

    We show that thymine self-assembles into an ordered structure when adsorbed at a Au(110)/liquid interface. Reflection anisotropy spectroscopy (RAS) shows that as found for cytosine and adenine the adsorbed thymine molecules are oriented essentially vertically on the Au(110) surface with the molecule aligned along one of the principal axes of the Au(110) surface. Simulations of the RA spectra to an empirical model indicates that as found for adsorbed cytosine and adenine, thymine is aligned along the [1 anti 10] direction on the Au(110) surface. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  1. Tailoring the FeRh magnetostructural response with Au diffusion

    OpenAIRE

    Loving, Melissa. L.; De Vries, Mark; Gimenez-Villacorta, Felix; Liu, Xuerong; Langridge, Sean; Heiman, Donald; Marrows, Christopher M.; Lewis, Laura

    2012-01-01

    Factors which contribute to magnetostructural transition control have been demonstrated by study of the effects of Au incorporation on the magnetic and structural character of CsCl-structured equiatomic FeRh thin films. Sputtered films were capped with 2 nm of Au deposited at 873 K and at 323 K and subsequently characterized with magnetometry and synchrotron-based structural probes. Diffusion of Au into the FeRh film layer at 873 K is confirmed by a reduction in the Au capping layer thickness...

  2. Preparations for p-Au run in 2015

    Energy Technology Data Exchange (ETDEWEB)

    Liu, C. [Brookhaven National Lab. (BNL), Upton, NY (United States). Collider-Accelerator Dept.

    2014-12-31

    The p-Au particle collision is a unique category of collision runs. This is resulted from the different charge mass ratio of the proton and fully stripped Au ion (1 vs.79/197). The p-Au run requires a special acceleration ramp, and movement of a number of beam components as required by the beam trajectories. The DX magnets will be moved for the first time in the history of RHIC. In this note, the planning and preparations for p-Au run will be presented.

  3. Structural and optical studies of Au doped titanium oxide films

    Energy Technology Data Exchange (ETDEWEB)

    Alves, E., E-mail: ealves@itn.pt [Instituto Tecnologico e Nuclear (ITN), 2686-953 Sacavem (Portugal); Centro de Fisica Nuclear da Universidade de Lisboa, Av. Gama Pinto, 21649-003 Lisboa (Portugal); Franco, N.; Barradas, N.P. [Instituto Tecnologico e Nuclear (ITN), 2686-953 Sacavem (Portugal); Centro de Fisica Nuclear da Universidade de Lisboa, Av. Gama Pinto, 21649-003 Lisboa (Portugal); Nunes, B. [Instituto Tecnologico e Nuclear (ITN), 2686-953 Sacavem (Portugal); Lopes, J. [Instituto Superior de Engenharia de Lisboa (Portugal); Cavaleiro, A. [SEC-CEMUC - Universidade de Coimbra, Dept. Eng. Mecanica, Polo II, 3030-788 Coimbra (Portugal); Torrell, M.; Cunha, L.; Vaz, F. [Centro de Fisica, Universidade do Minho, 4800-058 Guimaraes (Portugal)

    2012-02-01

    Thin films of TiO{sub 2} were doped with Au by ion implantation and in situ during the deposition. The films were grown by reactive magnetron sputtering and deposited in silicon and glass substrates at a temperature around 150 Degree-Sign C. The undoped films were implanted with Au fluences in the range of 5 Multiplication-Sign 10{sup 15} Au/cm{sup 2}-1 Multiplication-Sign 10{sup 17} Au/cm{sup 2} with a energy of 150 keV. At a fluence of 5 Multiplication-Sign 10{sup 16} Au/cm{sup 2} the formation of Au nanoclusters in the films is observed during the implantation at room temperature. The clustering process starts to occur during the implantation where XRD estimates the presence of 3-5 nm precipitates. After annealing in a reducing atmosphere, the small precipitates coalesce into larger ones following an Ostwald ripening mechanism. In situ XRD studies reveal that Au atoms start to coalesce at 350 Degree-Sign C, reaching the precipitates dimensions larger than 40 nm at 600 Degree-Sign C. Annealing above 700 Degree-Sign C promotes drastic changes in the Au profile of in situ doped films with the formation of two Au rich regions at the interface and surface respectively. The optical properties reveal the presence of a broad band centered at 550 nm related to the plasmon resonance of gold particles visible in AFM maps.

  4. Magnetic holes in the solar wind between 0.3 AU and 17 AU

    Directory of Open Access Journals (Sweden)

    K. Sperveslage

    2000-01-01

    Full Text Available Magnetic holes (MHs are depressions of the magnetic field magnitude. Turner et al. (1977 identified the first MHs in the solar wind and determined an occurrence rate of 1.5 MHs/d. Winterhalter et al. (1994 developed an automatic identification criterion to search for MHs in Ulysses data in the solar wind between 1 AU and 5.4 AU. We adopt their criterion to expand the search to the heliocentric distances down to 0.3 AU using data from Helios 1 and 2 and up to 17 AU using data from Voyager 2. We relate our observations to two theoretical approaches which describe the so-called linear MHs in which the magnetic vector varies in magnitude rather than direction. Therefore we focus on such linear MHs with a directional change less than 10º. With our observations of about 850 MHs we present the following results: Approximately 30% of all the identified MHs are linear. The maximum angle between the initial magnetic field vector and any vector inside the MH is 20º in average and shows a weak relation to the depth of the MHs. The angle between the initial magnetic field and the minimum variance direction of those structures is large and very probably close to 90º. The MHs are placed in a high β environment even though the average solar wind shows a smaller β. The widths decrease from about 50 proton inertial length in a region between 0.3 AU and 0.4 AU heliocentric distance to about 15 proton inertial length at distances larger than 10 AU. This quantity is correlated with the β of the MH environments with respect to the heliocentric distance. There is a clear preference for the occurrence of depressions instead of compressions. We discuss these results with regard to the main theories of MHs, the mirror instability and the alternative soliton approach. Although our observational results are more consistent with the soliton theory we favour a combination of both. MHs might be the remnants of initial mirror mode structures which can be described as

  5. Baryon Stopping in Au+Au and p+p collisions at 62 and 200 GeV

    CERN Document Server

    Dalsgaard, Hans Hjersing

    2009-01-01

    BRAHMS has measured rapidity density distributions of protons and antiprotons in both p+p and Au+Au collisions at 62 GeV and 200 GeV. From these distributions the yields of so-called "net-protons", that is the difference between the proton and antiproton yields, can be determined. The rapidity dependence of the net-proton yields from peripheral Au+Au collisions is found to have a similar behaviour to that found for the p+p results, while a quite different rapidity dependence is found for central Au+Au collisions. The net-proton distributions can be used together with model calculations to find the net-baryon yields as a function of rapidity, thus yielding information on the average rapidity loss of beam particles, the baryon transport properties of the medium, and the amount of "stopping" in these collisions.

  6. Baryon Stopping in Au+Au and p+p collisions at 62 and 200 GeV

    Science.gov (United States)

    Brahms Collaboration; Dalsgaard, Hans Hjersing; BRAHMS Collaboration

    2009-11-01

    BRAHMS has measured rapidity density distributions of protons and antiprotons in both p+p and Au+Au collisions at 62 GeV and 200 GeV. From these distributions the yields of so-called ‘net-protons’, that is the difference between the proton and antiproton yields, can be determined. The rapidity dependence of the net-proton yields from peripheral Au+Au collisions is found to have a similar behaviour to that found for the p+p results, while a quite different rapidity dependence is found for central Au+Au collisions. The net-proton distributions can be used together with model calculations to find the net-baryon yields as a function of rapidity, thus yielding information on the average rapidity loss of beam particles, the baryon transport properties of the medium, and the amount of ‘stopping’ in these collisions.

  7. Design of Au/SPIO composite nanoparticle for facile and biocompatible surface functionalization via Au-S bond

    Energy Technology Data Exchange (ETDEWEB)

    Seino, Satoshi, E-mail: seino@mit.eng.osaka-u.ac.jp; Shibata, Yujin; Yamanaka, Masayuki; Nakagawa, Takashi [Osaka University, Graduate School of Engineering (Japan); Mukai, Yohei; Nakagawa, Shinsaku [Osaka University, Graduate School of Pharmaceutical Sciences and Center for Advanced Medical Engineering and Informatics (Japan); Yamamoto, Takao A. [Osaka University, Graduate School of Engineering (Japan)

    2013-01-15

    Immobilization of Au nanoparticles on super-paramagnetic iron-oxide (SPIO) enables facile and biocompatible surface functionalization via Au-S bond. Au/SPIO composite nanoparticle is easily modified by thiol-modified polyethylene glycol (PEG-SH), and they are successfully applied on MR tumor imaging. However, its large hydrodynamic size ({approx}150 nm) still causes the accumulation to liver in vivo. In this study, we controlled the hydrodynamic size of Au/SPIO by testing different raw SPIOs and stabilizing polymers. As the best candidate, Au/Molday-ION which was synthesized from Molday-ION and polyvinyl alcohol comprised the hydrodynamic size of 56 nm. Moreover, PEGylated Au/Molday-ION showed excellent dispersibility in blood serum, with the hydrodynamic size of 65 nm. This surface functionalization strategy is effective for the constructions of magnetic nanocarriers for in vivo applications.

  8. Enhanced production of direct photons in Au+Au collisions at sqrt(s_NN)=200 GeV

    CERN Document Server

    Adare, A; Aidala, C; Ajitanand, N N; Akiba, Y; Al-Bataineh, H; Alexander, J; Al-Jamel, A; Aoki, K; Aphecetche, L; Armendariz, R; Aronson, S H; Asai, J; Atomssa, E T; Averbeck, R; Awes, T C; Azmoun, B; Babintsev, V; Baksay, G; Baksay, L; Baldisseri, Alberto; Barish, K N; Barnes, P D; Bassalleck, B; Bathe, S; Batsouli, S; Baublis, V; Bauer, F; Bazilevsky, A; Belikov, S; Bennett, R; Berdnikov, Y; Bickley, A A; Bjorndal, M T; Boissevain, J G; Borel, H; Boyle, K; Brooks, M L; Brown, D S; Bucher, D; Büsching, H; Bumazhnov, V; Bunce, G; Burward-Hoy, J M; Butsyk, S; Campbell, S; Chai, J S; Chang, B S; Charvet, J L; Chernichenko, S; Chiba, J; Chi, C Y; Chiu, M; Choi, I J; Chujo, T; Chung, P; Churyn, A; Cianciolo, V; Cleven, C R; Cobigo, Y; Cole, B A; Comets, M P; Constantin, P; Csanad, M; Csrgo, T; Dahms, T; Das, K; David, o G; Deaton, M B; Dehmelt, K; Delagrange, H; Denisov, A; d'Enterria, D; Deshpande, A; Desmond, E J; Dietzsch, O; Dion, A; Donadelli, M; Drachenberg, J L; Drapier, O; Drees, A; Dubey, A K; Durum, A; Dzhordzhadze, V; Efremenko, Yu V; Egdemir, J; Ellinghaus, F; Emam, W S; Enokizono, A; Enyo, H; Espagnon, B; Esumi, S; Eyser, K O; Fields, D E; Finger, M; Finger, M; Fleuret, F; Fokin, S L; Forestier, B; Fraenkel, Zeev; Frantz, J E; Franz, A; Frawley, A D; Fujiwara, K; Fukao, Y; Fung, S Y; Fusayasu, T; Gadrat, S; Garishvili, I; Gastineau, F; Germain, M; Glenn, A; Gong, H; Gonin, M; Gosset, J; Goto, Y; Granier de Cassagnac, R; Grau, N; Greene, S V; Grosse-Perdekamp, M; Gunji, T; Gustafsson, H; Hachiya, AT; Hadj Henni, A; Haegemann, C; Haggerty, J S; Hagiwara, M N; Hamagaki, H; Han, R; Harada, H; Hartouni, E P; Haruna, K; Harvey, M; Haslum, E; Hasuko, K; Hayano, R; Heffner, M; Hemmick, T K; Hester, T; Heuser, J M; He, X; Hiejima, H; Hill, J C; Hobbs, R; Hohlmann, M; Holmes, M; Holzmann, W; Homma, K; Hong, B; Horaguchi, T; Hornback, D; Hur, M G; Ichihara, T; Imai, K; Inaba, M; Inoue, Y; Isenhower, D; Isenhower, L; Ishihara, M; Isobe, T; Issah, M; Isupov, A; Jacak, B V; Jia, J; Jin, J; Jinnouchi, O; Johnson, B M; Joo, K S; Jouan, D; Kajihara, F; Kametani, S; Kamihara, N; Kamin, J; Kaneta, M; Kang, J H; Kanou, H; Kawagishi, T; Kawall, D; Kazantsev, A V; Kelly, S; Khanzadeev, A; Kikuchi, J; Kim, D H; Kim, D J; Kim, E; Kim, Y S; Kinney, E; Kiss, A; Kistenev, E; Kiyomichi, A; Klay, J; Klein-Bösing, C; Kochenda, L; Kochetkov, V; Komkov, B; Konno, M; Kotchetkov, D; Kozlov, A; Krl, A; Kravitz, A; Kroon, P J; Kubart, J; Kunde, G J; Kurihara, N; Kurita, K; Kweon, M J; Kwon, Y; Kyle, G S; Lacey, R; Lai, Y S; Lajoie, J G; Lebedev, A; Le Bornec, Y; Leckey, S; Lee, D M; Lee, M K; Lee, T; Leitch, M J; Leite, M A L; Lenzi, B; Lim, H; Lika, T; Litvinenko, A; Liu, M X; Li, X; Li, X H; Love, s B; Lynch, D; Maguire, C F; Makdisi, Y I; Malakhov, A; Malik, M D; Man'ko, V I; Mao, Y; Maek, L; Masui, H; Matathias, F; McCain, M C; McCumber, M; McGaughey, P L; Miake, Y; Mike, s P; Miki, K; Miller, T E; Milov, A; Mioduszewski, S; Mishra, G C; Mishra, M; Mitchell, J T; Mitrovski, s M; Morreale, A; Morrison, D P; Moss, J M; Moukhanova, T V; Mukhopadhyay, D; Murata, J; Nagamiya, S; Nagata, Y; Nagle, J L; Naglis, M; Nakagawa, I; Nakamiya, Y; Nakamura, T; Nakano, K; Newby, J; Nguyen, M; Norman, B E; Nyanin, A S; Nystrand, J; O'Brien, E; Oda, S X; Ogilvie, C A; Ohnishi, H; Ojha, I D; Okada, H; Okada, K; Oka, M; Omiwade, O O; Oskarsson, A; Otterlund, I; Ouchida, M; Ozawa, K; Pak, R; Pal, D; Palounek, A P T; Pantuev, V; Papavassiliou, V; Park, J; Park, W J; Pate, S F; Pei, H; Peng, J C; Pereira, H; Peresedov, V; Peressounko, D Yu; Pinkenburg, C; Pisani, R P; Purschke, M L; Purwar, A K; Qu, H; Rak, J; Rakotozafindrabe, A; Ravinovich, I; Read, K F; Rembeczki, S; Reuter, M; Reygers, K; Riabov, V; Riabov, Y; Roche, G; Romana, A; Rosati, M; Rosendahl, S S E; Rosnet, P; Rukoyatkin, P; Rykov, V L; Ryu, S S; Sahlmueller, B; Saitô, N; Sakaguchi, T; Sakai, S; Sakata, H; Samsonov, V; Sato, H D; Sato, S; Sawada, S; Seele, J; Seidl, R; Semenov, V; Seto, R; Sharma, D; Shea, T K; Shein, I; Shevel, A; Shibata, T A; Shigaki, K; Shimomura, M; Shohjoh, T; Shoji, K; Sickles, A; Silva, C L; Silvermyr, D; Silvestre, C; Sim, K S; Singh, C P; Singh, V; Skutnik, S; Sluneka, M; Smith, W C; Soldatov, A; Soltz, R A; Sondheim, W E; Sorensen, cS P; Sourikova, I V; Staley, F; Stankus, P W; Stenlund, E; Stepanov, M; Ster, A; Stoll, S P; Sugitate, T; Suire, C; Sullivan, J P; Sziklai, J; Tabaru, T; Takagi, S; Takagui, E M; Taketani, A; Tanaka, K H; Tanaka, Y; Tanida, K; Tannenbaum, M J; Taranenko, A; Tarjn, P; Thomas, T L; Togawa, M; Toia, A; Tojo, J; Tomaek, L; Torii, H; Towell, R S; Tram, V-N; Tserruya, Itzhak; Tsuchimoto, Y; Tuli, S K; Tydesj, H; Tyurin, N; Vale, C; Valle, H; van Hecke, H W; Velkovska, o J; Vertesi, R; Vinogradov, A A; Virius, M; Vrba, V; Vznuzdaev, E; Wagner, M; Walker, D; Wang, X R; Watanabe, Y; Wessels, J; White, S N; Willis, N; Winter, D; Woody, C L; Wysocki, M; Xie, W; Yamaguchi, Y L; Yanovich, A; Yasin, Z; Ying, J; Yokkaichi, S; Young, G R; Younus, I; Yushmanov, I E; Zajc, W A; Zaudtke, O; Zhang, C; Zhou, S; Zimányi, J; Zolin, L

    2008-01-01

    The production of low mass e+e- pairs for m_{e+e-} < 300 MeV/c^2 and 1 < p_T <5 GeV/c is measured in p+p and Au+Au collisions at sqrt(s_NN)=200 GeV. Enhanced e+e- pair yield above hadronic sources is observed in Au+Au collisions. Treating the excess as internal conversion of direct photons, the invariant yield of direct photons is deduced. In central Au+Au collisions, the excess over p+p is exponential in p_T}, with inverse slope T = 221 +/- 23 (stat) +/- 18 (syst) MeV. Hydrodynamical models with initial temperatures T_init ~ 300-600 MeV at times of 0.6 - 0.15 fm/c after the collision are in qualitative agreement with the data. Lattice QCD predicts a phase transition at ~ 170 MeV.

  9. The Modification of high-$p_{T}$ hadro-chemistry in Au+Au collisions relative to p+p

    CERN Document Server

    Timmins, Anthony R

    2009-01-01

    We present high transverse momentum, $p_{T}$, pion ($\\pi$), proton ($p$), kaon ($K$), and rho ($\\rho$) spectra measured with the STAR experiment from p+p and Au+Au collisions with \\sNN{200}. We find the $K/\\pi$ ratio to be enhanced in Au+Au \\sNN{200} collisions relative to p+p \\sNN{200} collisions at $p_{T} > 5$ GeV/c. The enhancement persists until $p_{T} \\sim 12$ GeV/c for central Au+Au 200 GeV collisions. We also show the nuclear modification factor, $R_{AA}$, measured at the same center of mass energy, and find $R_{AA}(K)$ and $R_{AA}(p)$ to be higher than $R_{AA}(\\pi)$ at $p_T > 5$ GeV/c. Implications for medium induced modifications of jet chemistry is discussed.

  10. Hollow Au@Pd and Au@Pt core-shell nanoparticles as electrocatalysts for ethanol oxidation reactions

    KAUST Repository

    Song, HyonMin

    2012-09-27

    Hybrid alloys among gold, palladium and platinum become a new category of catalysts primarily due to their enhanced catalytic effects. Enhancement means not only their effectiveness, but also their uniqueness as catalysts for the reactions that individual metals may not catalyze. Here, preparation of hollow Au@Pd and Au@Pt core-shell nanoparticles (NPs) and their use as electrocatalysts are reported. Galvanic displacement with Ag NPs is used to obtain hollow NPs, and higher reduction potential of Au compared to Ag, Pd, and Pt helps to produce hollow Au cores first, followed by Pd or Pt shell growth. Continuous and highly crystalline shell growth was observed in Au@Pd core-shell NPs, but the sporadic and porous-like structure was observed in Au@Pt core-shell NPs. Along with hollow core-shell NPs, hollow porous Pt and hollow Au NPs are also prepared from Ag seed NPs. Twin boundaries which are typically observed in large size (>20 nm) Au NPs were not observed in hollow Au NPs. This absence is believed to be due to the role of the hollows, which significantly reduce the strain energy of edges where the two lattice planes meet. In ethanol oxidation reactions in alkaline medium, hollow Au@Pd core-shell NPs show highest current density in forward scan. Hollow Au@Pt core-shell NPs maintain better catalytic activities than metallic Pt, which is thought to be due to the better crystallinity of Pt shells as well as the alloy effect of Au cores. © 2012 The Royal Society of Chemistry.

  11. Component conversion from pure Au nanorods to multiblock Ag-Au-Ag nanorods assisted by Pt nanoframe templates

    Science.gov (United States)

    Lee, Sangji; Jang, Hee-Jeong; Jang, Ho Young; Kim, Seong Kyu; Park, Sungho

    2016-06-01

    We developed a new method for synthesizing multiblock Ag-Au-Ag nanorods using Pt nanoframes that had been deposited on the edges of Au nanorod seeds. As a function of Au etching time, the length of the Au nanorod decreased symmetrically starting from the two ends, leading to the formation of empty inner space at the ends. Subsequent reduction of Ag ions could be selectively performed in the inner space confined by Pt nanoframes and the resulting Ag-Au-Ag nanorods exhibited characteristic LSPR modes originating from each block component (in a transverse direction) and SPR coupling (in a longitudinal direction). The high quality of the resulting multiblock nanorods enabled observation of the longitudinal quadrupole mode that was induced by Ag-Au SPR coupling in a long axis. The mode exhibited high sensitivity in accordance with the change in the surrounding media, demonstrating great potential for sensor applications.We developed a new method for synthesizing multiblock Ag-Au-Ag nanorods using Pt nanoframes that had been deposited on the edges of Au nanorod seeds. As a function of Au etching time, the length of the Au nanorod decreased symmetrically starting from the two ends, leading to the formation of empty inner space at the ends. Subsequent reduction of Ag ions could be selectively performed in the inner space confined by Pt nanoframes and the resulting Ag-Au-Ag nanorods exhibited characteristic LSPR modes originating from each block component (in a transverse direction) and SPR coupling (in a longitudinal direction). The high quality of the resulting multiblock nanorods enabled observation of the longitudinal quadrupole mode that was induced by Ag-Au SPR coupling in a long axis. The mode exhibited high sensitivity in accordance with the change in the surrounding media, demonstrating great potential for sensor applications. Electronic supplementary information (ESI) available. See DOI: 10.1039/c6nr03484e

  12. Microstructural evolution of Au/TiO{sub 2} nanocomposite films: The influence of Au concentration and thermal annealing

    Energy Technology Data Exchange (ETDEWEB)

    Borges, J., E-mail: joelborges@fisica.uminho.pt [Instituto Pedro Nunes, Laboratório de Ensaios, Desgaste e Materiais, Rua Pedro Nunes, 3030-199 Coimbra (Portugal); SEG-CEMUC, Mechanical Engineering Department, University of Coimbra, 3030-788 Coimbra (Portugal); Centro/Departamento de Física, Universidade do Minho, Campus de Gualtar, 4710-057 Braga (Portugal); Kubart, T.; Kumar, S.; Leifer, K. [Solid-State Electronics, Department of Engineering Sciences, Uppsala University, P.O. Box 534, Uppsala SE-751 21 (Sweden); Rodrigues, M.S. [Instituto Pedro Nunes, Laboratório de Ensaios, Desgaste e Materiais, Rua Pedro Nunes, 3030-199 Coimbra (Portugal); Centro/Departamento de Física, Universidade do Minho, Campus de Gualtar, 4710-057 Braga (Portugal); Duarte, N.; Martins, B.; Dias, J.P. [Instituto Pedro Nunes, Laboratório de Ensaios, Desgaste e Materiais, Rua Pedro Nunes, 3030-199 Coimbra (Portugal); Cavaleiro, A. [SEG-CEMUC, Mechanical Engineering Department, University of Coimbra, 3030-788 Coimbra (Portugal); Vaz, F. [SEG-CEMUC, Mechanical Engineering Department, University of Coimbra, 3030-788 Coimbra (Portugal); Centro/Departamento de Física, Universidade do Minho, Campus de Gualtar, 4710-057 Braga (Portugal)

    2015-04-01

    Nanocomposite thin films consisting of a dielectric matrix, such as titanium oxide (TiO{sub 2}), with embedded gold (Au) nanoparticles were prepared and will be analysed and discussed in detail in the present work. The evolution of morphological and structural features was studied for a wide range of Au concentrations and for annealing treatments in air, for temperatures ranging from 200 to 800 °C. Major findings revealed that for low Au atomic concentrations (at.%), there are only traces of clustering, and just for relatively high annealing temperatures, T ≥ 500 °C. Furthermore, the number of Au nanoparticles is extremely low, even for the highest annealing temperature, T = 800 °C. It is noteworthy that the TiO{sub 2} matrix also crystallizes in the anatase phase for annealing temperatures above 300 °C. For intermediate Au contents (5 at.% ≤ C{sub Au} ≤ 15 at.%), the formation of gold nanoclusters was much more evident, beginning at lower annealing temperatures (T ≥ 200 °C) with sizes ranging from 2 to 25 nm as the temperature increased. A change in the matrix crystallization from anatase to rutile was also observed in this intermediate range of compositions. For the highest Au concentrations (> 20 at.%), the films tended to form relatively larger clusters, with sizes above 20 nm (for T ≥ 400 °C). It is demonstrated that the structural and morphological characteristics of the films are strongly affected by the annealing temperature, as well as by the particular amounts, size and distribution of the Au nanoparticles dispersed in the TiO{sub 2} matrix. - Highlights: • Au:TiO{sub 2} films were produced by magnetron sputtering and post-deposition annealing. • The Au concentration in the films increases with the Au pellet area. • Annealing induced microstructural changes in the films. • The nanoparticle size evolution with temperature depends on the Au concentration.

  13. Facet selective etching of Au microcrystallites

    Institute of Scientific and Technical Information of China (English)

    Gangaiah Mettela and Giridhar U. Kulkarni

    2015-01-01

    High-symmetry crystals exhibit isotropic properties. Inducing anisotropy, e.g., by facet selective etching, is considered implausible in face-centered cubic (FCC) metals, particularly gold, which, in addition to being an FCC, is noble. We report for the first time the facet selective etching of Au microcrystals obtained in the form of cuboctahedra and pentagonal rods from the thermolysis of a gold- organic precursor. The selective etching of {111} and {100} facets was achieved using a capping method in which tetraoctylammonium cations selectively cap the {111} facets while Br- ions protect the {100} facets. The exposed facets are oxidized by O2/C1-, yielding a variety of interesting geometries. The facet selective etching of the Au microcrystallites is governed only by the nature of the facets; the geometry of the microcystallite does not appear to play a significant role. The etched surfaces appear rough, but a closer examination reveals well-defined corrugations that are indexable to high hkl values. Such surfaces exhibit enhanced Raman activity.

  14. Imaging Prominence Eruptions Out to 1 AU

    CERN Document Server

    Wood, Brian E; Linton, Mark G

    2015-01-01

    Views of two bright prominence eruptions trackable all the way to 1AU are here presented, using the heliospheric imagers on the Solar TErrestrial RElations Observatory (STEREO) spacecraft. The two events first erupted from the Sun on 2011 June 7 and 2012 August 31, respectively. Only these two examples of clear prominence eruptions observable this far from the Sun could be found in the STEREO image database, emphasizing the rarity of prominence eruptions this persistently bright. For the 2011 June event, a time-dependent 3-D reconstruction of the prominence structure is made using point-by-point triangulation. This is not possible for the August event due to a poor viewing geometry. Unlike the coronal mass ejection (CME) that accompanies it, the 2011 June prominence exhibits little deceleration from the Sun to 1 AU, as a consequence moving upwards within the CME. This demonstrates that prominences are not necessarily tied to the CME's magnetic structure far from the Sun. A mathematical framework is developed ...

  15. Apprentissage administratif : L'apprentissage au CERN

    CERN Multimedia

    2004-01-01

    APPRENTISSAGE ADMINISTRATIF FORMATION ET DEVELOPPEMENT HR/PMD/RCC L'APPRENTISSAGE AU CERN pour les professions d'employé(e) de commerce et d'assistant(e) en information documentaire L'apprentissage au CERN est régi par les lois, règlements et contrats en vigueur dans le Canton de Genève. En cas de réussite à l'examen de fin d'apprentissage, les apprentis obtiennent le Certificat Fédéral de Capacité Suisse (CFC). 1 place est offerte pour la formation d'employé(e) de commerce 2 places sont offertes pour la formation d'assistant(e) en information documentaire L'apprentissage dure 3 ans. Minima requis pour faire acte de candidature : • avoir terminé la scolarité obligatoire • être ressortissant d'un pays membre du CERN (Allemagne, Autriche, Belgique, Bulgarie, Danemark, Espagne,Finlande, France, Grèce, Hongrie, Italie, Norvège...

  16. Le fonds Gabriel Tarde au CHEVS

    Directory of Open Access Journals (Sweden)

    Louise Salmon

    2005-09-01

    Full Text Available Le fonds d’archives « Gabriel Tarde » déposé au CHEVS nous permet de mieux saisir l’érudit autodidacte que fut Gabriel Tarde. De la genèse de sa pensée à ses réseaux de sociabilité, de l’homme de sciences à l’homme de lettres, ses archives témoignent à la fois des usages et des enjeux des ressources archivistiques en histoire, mais elles permettent surtout un renouvellement du regard sur Gabriel Tarde en l’inscrivant au cœur de son temps que fut la fin du XIXème siècle.At the CHEVS in Paris, Gabriel Tarde’s archives allow us to grasp the self-taught scholar who was Gabriel Tarde. From the genesis of his intellect thought to his circles of sociability, from the scientist to the man of letters, his archives testify to the uses and the stakes of the archivistic resources in history, but they allow especially a renewal of the glance on Gabriel Tarde by inscribing him in his historical time, the end of the XIXth century.

  17. Decontamination by fractional distillation of a radioactive mixture of perchlorethylene, bitumen, and sludges from chemical co-precipitations; Decontamination par distillation fractionnee d'un melange radioactif constitue par du perchlorethylene, du bitume et des boues de coprecipitation chimique

    Energy Technology Data Exchange (ETDEWEB)

    Lefillatre, G.; Hullo, R. [Commissariat a l' Energie Atomique, Chusclan (France). Centre de Production de Plutonium de Marcoule

    1969-07-01

    It is not possible to incinerate the contaminated organic waste containing chlorine, produced at the Marcoule Centre. The only valid method for these solvents of average activity is fractional distillation. This report presents a pilot fractional distillation plant designed for decontaminating the residual solvents produced by the Centre's Waste Processing Station. These contaminated solvents come from the decontamination of a screw extrusion apparatus with perchlorethylene; this equipment is used for coating the radioactive sludges with bitumen. The pilot plant operates discontinuously and is used to decontaminate the perchlorethylene, to separate the perchlorethylene from the water, and to process the distillation residue. The electrically heated boiler is fitted with a removable base in the form of a disposable container. The installations decontamination factor is 3.4 x 10{sup 6} when solvents with a specific activity of 0.23 Ci/m{sup 3} are used. The average flow-rate for a distillation run is 10 l/hr at atmospheric pressure, and 21 l/hr at a residual pressure of 40 torr. The decontamination factor for the installation is better at atmospheric pressure than in a vacuum. (authors) [French] Les effluents organiques contamines chlores du Centre de Marcoule ne peuvent etre incineres. Le seul mode de traitement qui s'impose pour ces solvants de moyenne activite s'avere etre la distillation fractionnee. Ce rapport presente une installation pilote de distillation fractionnee qui a ete concue pour decontaminer des solvants residuaires provenant de la Station de Traitement des Effluents du Centre. Ces solvants contamines resultent de la decontamination au moyen de perchlorethylene d'une extrudeuse a vis servant a l'enrobage par le bitume des boues radioactives de cette station. L'installation pilote fonctionne en discontinu et assure a la fois la decontamination du perchlorethylene, la separation du perchlorethylene et de l'eau et le

  18. 197Au Moessbauer study of the deactivation and reactivation of a carbon-supported AuCl4- hydrochlorination catalyst

    International Nuclear Information System (INIS)

    Acetylene hydrochlorination catalysts consisting of activated carbon impregnated with a solution of HAuCl4.xH2O in aqua regia have been studied by 197Au Moessbauer spectroscopy. The relative amounts of AuCl4-, of Au(0), and of an Au(I) species formed under certain process conditions were determined quantitatively. Deactivation of the catalyst at low and high temperatures was shown to be due to different mechanisms, and the reactivation of the catalyst by Cl2 gas was studied. (orig.)

  19. Coating of a layer of Au on Al13 : The findings of icosahedral Al@Al12Au20- and Al12Au202- fullerenes using ab initio pseudopotential calculations

    Science.gov (United States)

    Kumar, Vijay

    2009-02-01

    We report results of ab initio pseudopotential calculations on the nanocoating of gold on an icosahedral Al13 cluster and the findings of icosahedrally symmetric endohedral Al@Al12Au20- and empty cage Al12Au202- compound fullerenes formed of metal atoms. Twelve Al atoms cap the pentagonal faces of a dodecahedral Au20 cage in which each Au atom has three Al atoms and three Au atoms as nearest neighbors. Mixing of Al13 and Au20 magic clusters leads to a large heat of formation of 0.55 eV/atom and high stability of the Al@Al12Au20 compound fullerene. The binding energies of Al12Au20 and Al@Al12Au20 are 3.017 and 3.007 eV/atom, respectively, which are much larger than 2.457 eV/atom for Au32 fullerene, leading to the possibility of their high abundance.

  20. Ultrafast charge carrier dynamics in Au/semiconductor nanoheterostructures

    Science.gov (United States)

    Lambright, Scott

    The charge carrier dynamics in several Au/semiconductor core/shell heterostructures were examined. Firstly, Au/CdS core/shell nanocomposites were synthesized in a four step procedure culminating in a cation exchange performed on the shell. Previous studies of the ultrafast carrier dynamics in Au/CdS nanocomposites with epitaxial boundary regions reported the suppression of plasmon character in transient absorption spectra accompanied by broadband photoinduced absorption. The coupling of electron wavefunctions with lattice defects at the boundary of the two domains has been blamed for these phenomena. In the current study, transmission electron micrographs of Au/CdS synthesized using cation exchange showed no evidence of strain on the lattice of either component, while femtosecond transient absorption data show the retention of bleach regions attributed to CdS's 1S(e)-1S3/2(h) transition and Au's plasmon resonance. Accelerated rates of bleach recovery for both excitations ( tauexiton ≈ 300 ps, tauplasmon ≈ .7 ps) indicated that the interaction of Au and CdS domains leads to faster relaxation to their respective photoexcitations when compared to relaxation times in isolated Au and CdS nanoparticles. It was believed that the Au/CdS boundary was non-epitaxial in the presented core/shell nanocomposites. Secondly, these non-epitaxial Au/CdS core/shells were subsequently used to demonstrate near-field energy transfer from 5 nm diameter Au cores to CdS-encapsulated CdSe quantum dots. To this end, Au/CdS and CdSe/CdS nanocrystals were embedded in semiconductor-matrix-encapsulated-nanocrystal-arrays (SMENA) together. The encapsulation of both domains in the high band-gap semiconductor CdS was a means to suppress charge transfer between the two nanoparticles. The fluorescence intensity in these films was enhanced 6-fold in some cases as a result of the presence of Au domains. It was also demonstrated that the fluorescence enhancement was independent of the potential

  1. Resonance production and exotic clusters in Au+Au, d+Au and p+p collisions at √(s) = 200 AGeV

    International Nuclear Information System (INIS)

    The resonance production in Au+Au, d+Au and p+p collisions at √(s) = 200 AGeV are presented. The resonances are used as a sensitive tool to examine the collision dynamics in the hadronic medium through their decay and regeneration. The modification of resonance mass, width, and shape due to phase space and dynamical effects are also discussed. The measurement of resonances provides an important tool for studying the dynamics in relativistic heavy-ion collisions by probing the time evolution of the source from chemical to kinetic freeze-out and the hadronic interactions at later stages

  2. EFFECT OF LASER INPUT ENERGY ON AuSnx INTERMETALLIC COMPOUNDS FORMATION IN SOLDER JOINTS WITH DIFFERENT THICKNESS OF Au SURFACE FINISH ON PADS

    Institute of Scientific and Technical Information of China (English)

    W.Liu; C.Q.Wang; Y.H.Tian; M.Y.Li

    2008-01-01

    Formation of AuSnx intermetallic compounds (IMCs) in laser reflowed solder joints was investigated. The results showed that few IMCs formed at the solder/0.1 μm Au interface. Needlelike AuSn4 IMCs were observed at the solder/0.5 μm Au interface.In Sn-2.0Ag-0.75Cu-3.0Bi and Sn-3.5Ag-O.75Cu solder joints, when the laser input energy was increased, AuSn4 IMCs changed from a layer to needlelike or dendritic distribution at the solder/0.9 μm Au interface. As for the solder joints with 4.0 μm thickness of Au surface finish on pads, AuSn4 , AuSn2, AuSn IMCs, and Au2 Sn phases formed at the interface. Moreover, the content of AuSnx IMCs, such as, AuSn4 and AuSn2, which contained high Sn concentration, would become larger as the laser input energy increased. In the Sn-37Pb solder joints with 0.9 μm or 4.0 μm thickness of the Au surface finish on pads, AuSn4 IMCs were in netlike distribution. The interspaces between them were filled with Pb-rich phases.

  3. Microstructural evolution of eutectic Au-Sn solder joints

    Energy Technology Data Exchange (ETDEWEB)

    Song, Ho Geon

    2002-05-31

    Current trends toward miniaturization and the use of lead(Pb)-free solder in electronic packaging present new problems in the reliability of solder joints. This study was performed in order to understand the microstructure and microstructural evolution of small volumes of nominally eutectic Au-Sn solder joints (80Au-20Sn by weight), which gives insight into properties and reliability.

  4. Thermodynamic modeling of the Au-Sb-Si ternary system

    Energy Technology Data Exchange (ETDEWEB)

    Wang, J., E-mail: jiang.wang@empa.ch [School of Materials Science and Engineering, Guilin University of Electronic Technology, Guilin, Guangxi 541004 (China); Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Joining and Interface Technology, Uberlandstrasse 129, Duebendorf, Zuerich CH-8600 (Switzerland); Liu, Y.J. [Western Transportation Institute, Montana State University, Bozeman, MT 59715 (United States); Liu, L.B. [School of Materials Science and Engineering, Central South University, Changsha, Hunan 410083 (China); Zhou, H.Y. [School of Materials Science and Engineering, Guilin University of Electronic Technology, Guilin, Guangxi 541004 (China); Jin, Z.P. [School of Materials Science and Engineering, Central South University, Changsha, Hunan 410083 (China)

    2011-02-10

    Research highlights: > Thermodynamic optimization of the Au-Sb binary system was updated. > The Si-Sb binary system was assessed from critical review of experimental information. > Thermodynamic modeling of the Au-Sb-Si ternary system was performed. > The phase relations of this ternary system are useful to design Au-based solders. - Abstract: Thermodynamic optimization of the Au-Sb binary system was updated as well as the Si-Sb binary system was assessed thermodynamically using the CALPHAD method based on the critical review of the available experimental information from the published literature. The solution phases including liquid, fcc{sub A}1(Au), diamond{sub A}4(Si) and rhombohedral{sub A}7(Sb), are modeled as substitutional solutions and their excess Gibbs energies are expressed by a Redlich-Kister polynomial. The solubility of Si in the intermetallic compound AuSb{sub 2} is not taken into account because of the lack of experimental information. Combined with previous assessment of the Au-Si binary system, thermodynamic modeling of the Au-Sb-Si ternary system was performed to reproduce well the measured phase equilibria. The liquidus projection and several vertical sections of this ternary system were calculated, which are in reasonable agreement with the reported experimental data.

  5. Magnetic order of Au nanoparticle with clean surface

    Energy Technology Data Exchange (ETDEWEB)

    Sato, Ryuju; Ishikawa, Soichiro; Sato, Hiroyuki; Sato, Tetsuya, E-mail: satoh@appi.keio.ac.jp

    2015-11-01

    Au nanoparticles, which are kept in vacuum after the preparation by gas evaporation method, show ferromagnetism even in 1.7 nm in diameter. The intrinsic magnetism is examined by detecting the disappearance of spontaneous magnetization in Au bulk prepared by heating the nanoparticles without exposure to the air. The temperature dependence of spontaneous magnetization is not monotonic and the increase in magnetization is observed after Au nanoparticles are exposed to the air. The magnetic behavior can be interpreted by the ferrimagnetic-like core–shell structure with shell thickness of 0.16±0.01 nm and magnetic moment of (1.5±0.1)×10{sup −2} μ{sub B}/Au atom, respectively. - Highlights: • Au nanoparticles with clean surface were prepared by the gas evaporation method. • The spontaneous magnetization was observed in Au nanoparticles. • Temperature dependent spontaneous magnetization of smaller Au particles was not monotonic. • The magnetic behavior was interpreted by the ferrimagnetic-like core–shell model. • The shell thickness and the magnetic moment per Au atom were estimated.

  6. Microstructural evolution of eutectic Au-Sn solder joints

    OpenAIRE

    Song, Ho Geon

    2002-01-01

    Current trends toward miniaturization and the use of lead(Pb)-free solder in electronic packaging present new problems in the reliability of solder joints. This study was performed in order to understand the microstructure and microstructural evolution of small volumes of nominally eutectic Au-Sn solder joints (80Au-20Sn by weight), which gives insight into properties and reliability.

  7. Growth and structure of Co/Au magnetic thin films; Croissance et structure des couches minces magnetiques Co/Au

    Energy Technology Data Exchange (ETDEWEB)

    Marsot, N

    1999-01-14

    We have studied the growth and the crystallographic structure of magnetic ultra thin cobalt/gold films (Co/Au), in order to investigate the correlations between their magnetic and structural properties. Room temperature (R.T.) Co growth on Au (111) proceeds in three stages. Up to 2 Co monolayers (ML), a bilayer island growth mode is observed. Between 2 and 5 ML, coalescence of the islands occurs, covering the substrate surface and a Co/Au mixing is observed resulting from the de-construction of the Herringbone reconstruction. Finally, beyond 5 ML, the CoAu mixing is buried and the Co growth continues in a 3-D growth. Annealing studies at 600 K on this system show a smoothing effect of the Co film, and at the same time, segregation of Au atoms. The quality of the Co/Au interface (sharpness) is not enhanced by the annealing. The local order was studied by SEXAFS and the long range order by GIXRD showing that the Co film has a hexagonal close packed structure, with an easy magnetization axis perpendicular to the surface. From a local order point of view, the Co grows with an incoherent epitaxy and keeps its own bulk parameters. The GIXRD analysis shows a residual strain in the Co film of 4%. The difference observed between the local order analysis and the long range order results is explained in terms of the low dimensions of the diffracting domains. The evolution of film strains, as a function of the Co coverage, shows a marked deviation from the elastic strain theory. Modification of the strain field in the Co film as a function of the Au coverage is studied by GIXRD analysis. The Au growth study, at R.T., shows no evidence of a Au/Co mixing in the case of the Au/Co interface. The Au overlayer adopts a twinned face centred cubic structure on the rough Co film surface. (author)

  8. Formation of CuxAu1−x phases by cold homogenization of Au/Cu nanocrystalline thin films

    Directory of Open Access Journals (Sweden)

    Alona Tynkova

    2014-09-01

    Full Text Available It is shown, by using depth profiling with a secondary neutral mass spectrometer and structure investigations by XRD and TEM, that at low temperatures, at which the bulk diffusion is frozen, a complete homogenization can take place in the Cu/Au thin film system, which leads to formation of intermetallic phases. Different compounds can be formed depending on the initial thickness ratio. The process starts with grain boundary interdiffusion, which is followed by a formation of reaction layers at the grain boundaries that leads to the motion of the newly formed interfaces perpendicular to the grain boundary plane. Finally, the homogenization finishes when all the pure components have been consumed. The process is asymmetric: It is faster in the Au layer. In Au(25nm/Cu(50nm samples the final state is the ordered AuCu3 phase. Decrease of the film thicknesses, as expected, results in the acceleration of the process. It is also illustrated that changing the thickness ratio either a mixture of Cu-rich AuCu and AuCu3 phases (in Au(25nm/Cu(25nm sample, or a mixture of disordered Cu- as well as Au-rich solid solutions (in Au(25nm/Cu(12nm sample can be produced. By using a simple model the interface velocity in both the Cu and Au layers were estimated from the linear increase of the average composition and its value is about two orders of magnitude larger in Au (ca. 10−11 m/s than in Cu (ca. 10−13 m/s.

  9. Viscoelastic nature of Au nanoparticle–PDMS nanocomposite gels

    Indian Academy of Sciences (India)

    Ritu Gupta; Hima K Nagamanasa; Rajesh Ganapathy; Giridhar U Kulkarni

    2015-08-01

    A stable gel of Au nanoparticles in polydimethylsiloxane (PDMS) nanocomposite is prepared by employing the curing agent of PDMS elastomer as a reducing agent for the formation of Au nanoparticles by an in-situ process. The viscoelastic nature of these gels is very sensitive to the Au nanoparticle loading and the synthetic temperature conditions. Even a very low Au content of 0.09 wt% is sufficient enough to bring in the transition from sponge state to gel state at room temperature. Higher synthetic temperature also forms sponge formation. Infrared and ultraviolet–visible spectroscopy measurements have provided insight into PDMS crosslinking and nanoparticle formation, respectively. The optimization of the gel properties can have direct influence on the processability of Au nanoparticle–PDMS nanocomposite gels, with interesting implications in electronic, optical and microfluidic devices.

  10. La Physique au LHC - Partie I

    CERN Document Server

    CERN. Geneva

    2004-01-01

    Le LHC devrait permettre l'observation du boson de Higgs et pouvoir lever le voile sur l'un des scénarios de nouvelle physique présentés dans la cours précédent. Ce cours détaillera les perspectives de physique au LHC (découvertes possibles et mesures de précision) ainsi que les méthodes et difficultés expérimentales. L'accent sera mis sur les problèmes liés à la brisure de la symétrie electrofaible. Les possibilités de développement futur à plus haute luminosité et/ou énergie seront également discutées.

  11. The AuScope Geodetic VLBI Array

    CERN Document Server

    Lovell, J E J; Reid, P B; McCulloch, P M; Baynes, B E; Dickey, J M; Shabala, S S; Watson, C S; Titov, O; Ruddick, R; Twilley, R; Reynolds, C; Tingay, S J; Shield, P; Adada, R; Ellingsen, S P; Morgan, J S; Bignall, H E; 10.1007/s00190-013-0626-3

    2013-01-01

    The AuScope geodetic Very Long Baseline Interferometry array consists of three new 12 m radio telescopes and a correlation facility in Australia. The telescopes at Hobart (Tasmania), Katherine (Northern Territory) and Yarragadee (Western Australia) are co-located with other space geodetic techniques including Global Navigation Satellite Systems (GNSS) and gravity infrastructure, and in the case of Yarragadee, Satellite Laser Ranging (SLR) and Doppler Orbitography and Radiopositioning Integrated by Satellite (DORIS) facilities. The correlation facility is based in Perth (Western Australia). This new facility will make significant contributions to improving the densification of the International Celestial Reference Frame in the Southern Hemisphere, and subsequently enhance the International Terrestrial Reference Frame through the ability to detect and mitigate systematic error. This, combined with the simultaneous densification of the GNSS network across Australia will enable the improved measurement of intrapl...

  12. De l’invisible au visible

    OpenAIRE

    Tellier, Thibault

    2009-01-01

    Si la place qu’occupent les jeunes d’origine immigrée dans le traitement médiatique des violences urbaines dans certaines cités HLM n’est plus à démontrer, on connaît en revanche beaucoup moins bien la prise en compte de la  pratique religieuse des populations d’origine immigrée durant les années 1970-1990. Cette communication a donc pour but de montrer, à partir de l’exemple des grands ensembles, comment s’est effectuée au cours des Trente Glorieuses la prise en compte spécifique de cette pr...

  13. La géographie au sommet

    OpenAIRE

    Denise Pumain

    2002-01-01

    Le Ministre de l’Environnement d’Afrique du sud annonçant le sommet de Johannesburg, saluait l’occasion ainsi donnée à l’humanité de revenir au continent de ses origines pour ouvrir une ère nouvelle de solidarité (CityPress du 11 aôut). Quelques jours avant, les géographes de l’Union Géographique Internationale réunis pour leur « conférence régionale » à Durban sur le thème de « la renaissance de la géographie à l’aube du troisième millénaire » avaient invité Nelson Mandela. A cette occasion,...

  14. Jusqu’au ciel !

    OpenAIRE

    de Coster, Xavier

    2014-01-01

    Le récit biblique de la Tour de Babel (Gn. XI : 1-9) dit que le sommet de celle-ci devait atteindre les cieux. Ce texte a inspiré de nombreux artistes, au premier rang desquels Pieter Bruegel l'Ancien. Cet article s'intéresse à la manière dont parmi eux quelques prédécesseurs de Bruegel, puis lui-même, ont représenté le ciel, lequel joue dans cette histoire un rôle fondamental : non seulement le ciel est le but que se sont assigné les constructeurs de la tour, mais c'est du ciel que vient la ...

  15. Musique ! : du phonographe au MP3

    OpenAIRE

    Tournès, Ludovic

    2011-01-01

    nouvelle édition revue et augmentée de "Du phonographe au MP3. Une histoire de la musique enregistrée, XIXe-XXIe siècle" [2008] Depuis l'invention du phonographe par Thomas Edison en 1877, jusqu'à la révolution Internet, la musique enregistrée a connu une histoire longue et riche en rebondissements que l'on trouvera retracée de manière claire, synthétique et vivante dans ce livre. A l'heure où l'industrie de la musique est engagée depuis le début des années 2000 dans une mutation historiqu...

  16. Contribution au SAR spatial distribué

    OpenAIRE

    Maréchal, Rozenn

    2006-01-01

    L'obtention d’images à partir de l'émission, de la réception et du traitement d'impulsions radar (SAR) est soumise à différentes contraintes qui limitent les performances telles que la résolution en distance, la résolution en azimut ou la largeur de la Zone imagée (fauchée). Ces limites sont en partie liées à la dimension finie de l’antenne, en particulier dans le cas du SAR spatial. Pour cette raison, on a cherché à étudier la possibilité de mettre au point des systèmes SAR spatiaux distribué...

  17. Anisotropy analysis of energy in Au/Si twist interface%Au/Si扭转界面能各向异性研究

    Institute of Scientific and Technical Information of China (English)

    辛红; 张建民

    2007-01-01

    采用改进型嵌入原子法(modified embedded atom method,MEAM),计算了(001)Au/(111)Si、(011)Au/(111)Si、(111)Au/(111)Si、(001)Au/(001)Si、(011)Au/(001)Si、(111)Au/(001)Si六个扭转界面的界面能.结果表明,不论是对于(111)Si还是(001)Si基底,相同基底的界面均按照(111)Au/Si、(001)Au/Si、(011)Au/Si顺序依次增加;从界面能的最小化考虑,Au在(111)Si或(001)Si基底上的外延生长,Au(111)面为择优晶面,择优扭转角分别为θ=2.68°和θ=2.42°.

  18. Strangeness Production in Au+Au Reactions at √ {SNN} = 62.4\\ GeV

    Science.gov (United States)

    Arsene, Ionut-Cristian

    The measurement of strangeness is a valuable tool for understanding the reaction mechanism of nuclear collisions since all the strange particles need to be created during the reaction. Also, strangeness enhancement is one of the predicted signals of the QGP. In the present work we will discuss the behaviour of the strangeness production (i.e. K/π ratio) with rapidity and baryo-chemical potential in Au+Au collisions at 62.4 A GeV. In this particular reaction, BRAHMS is able to identify particles over 3.5 rapidity units and thereby cover a wide range of bar {p}/p ratios, including the fragmentation region. We will show spectra and ratios of identified particles as a function of pT and rapidity.

  19. Degree of Chemical Non-equilibrium in Central Au-Au Collisions at RHIC energies

    CERN Document Server

    Tawfik, Abdel Nasser; Habashy, D M; Mohamed, M T; Abbas, Ehab

    2014-01-01

    We investigate the difference between hadron resonance gas (HRG) calculations for chemical freeze-out parameters at fully and partly chemical equilibria. To this end, the results are compared with the particle ratios measured in central Au-Au collisions at a wide range of nucleon-nucleon center-of-mass energies, \\hbox{$\\sqrt{s_{NN}}=7.7-200 $GeV} as offered by the STAR experiment. We restrict the discussion to STAR, because of large statistics and overall homogeneity of STAR measurements (one detector) against previous experiments. We find that the matter produced at these energies is likely in fully chemical equilibrium, which is consistent with recent lattice QCD results. The possible improvements by partial chemical equilibrium ($\\gamma_S\

  20. Dynamical approach to spectator fragmentation in Au+Au reactions at 35 MeV/A

    CERN Document Server

    Vermani, Yogesh K

    2010-01-01

    The characteristics of fragment emission in peripheral $^{197}$Au+$^{197}$Au collisions 35 MeV/A are studied using the two clusterization approaches within framework of \\emph{quantum molecular dynamics} model. Our model calculations using \\emph{minimum spanning tree} (MST) algorithm and advanced clusterization method namely \\emph{simulated annealing clusterization algorithm} (SACA) showed that fragment structure can be realized at an earlier time when spectators contribute significantly toward the fragment production even at such a low incident energy. Comparison of model predictions with experimental data reveals that SACA method can nicely reproduce the fragment charge yields and mean charge of the heaviest fragment. This reflects suitability of SACA method over conventional clusterization techniques to investigate spectator matter fragmentation in low energy domain.

  1. Azimuthal anisotropy in Au+Au collisions at √sNN = 200 GeV

    International Nuclear Information System (INIS)

    The results from the STAR Collaboration on directed flow (v1), elliptic flow (v2), and the fourth harmonic (v4) in the anisotropic azimuthal distribution of particles from Au+Au collisions at √sNN = 200 GeV are summarized and compared with results from other experiments and theoretical models. Results for identified particles are presented and fit with a Blast Wave model. For v2, scaling with the number of constituent quarks and parton coalescence is discussed. For v4, scaling with v22 and quark coalescence predictions for higher harmonic flow is discussed. The different anisotropic flow analysis methods are compared and nonflow effects are extracted from the data. For v2, scaling with the number of constituent quarks and parton coalescence are discussed. For v22 and quark coalescence are discussed

  2. Nuclear Shadowing Effect on the K Factor in Au-Au Collisions

    Institute of Scientific and Technical Information of China (English)

    侯召宇; 郑乔; 张本爱

    2002-01-01

    We investigate the nuclear shadowing effect on the K factor in the Drell-Yan process by introducing a shadowing factor into the corresponding quantum chromodynamical αs order corrections. K factors for Au-Au collisions are calculated at the centre-of-mass system energies √s = 60, 130 and 200 GeV while the nuclear shadowing factor is taken into account. The numerical results indicate that the nuclear shadowing factor obviously raises the K value in the small x region, and for the same nucleon the K value becomes smaller as the energy increases. The nuclear shadowing effect could be one reason for creating the non-constancy of the K factor.

  3. Musique populaire et musique savante au XIXe siècle. Du "peuple" au "public"

    OpenAIRE

    Leterrier, Sophie-Anne

    2008-01-01

    La production culturelle englobe des formes musicales dont les statuts sont très variés. La chanson du colporteur et la partition symphonique n'appartiennent pas au même "genre" ni par leurs conditions de production, i par leurs formes matérielles, leur circulation, leur public, leur postérité. À ce sujet, l'étude des évolutions en cours au XIXe siècle est intéressante de plusieurs points de vue. D'abord, parce que c'est alors que les institutions destinées à former des "spécialistes" de la m...

  4. Questions croisées au sujet du documentaire Droit au but

    OpenAIRE

    Bromberger, Christian; Costantini, Philippe; Accolas, Sophie

    2015-01-01

    Sophie Accolas – Comment, à votre avis, le cinéma contemporain aborde‑t‑il le sport au regard de la globalisation ? Christian Bromberger – Il y a deux façons d’envisager la question. Soit l’on englobe dans la production cinématographique les matchs filmés et diffusés à la télévision, soit on ne retient que les films documentaires et de fiction. Dans la première hypothèse, on voit bien quel rôle joue l’image sportive dans le monde contemporain et, comme vous dites, « au regard de la globalisa...

  5. DEPENDENCE OF DOMAIN STRUCTURES ON Au THICKNESS IN Co/Au MULTILAYER FILMS

    Institute of Scientific and Technical Information of China (English)

    1998-01-01

    The magnetic force images and surface topography images of sputtered Co/Au multilayer films in remnant state were measured by magnetic force microscopy. From the surface magnetic structures shown in the magnetic force images it can be seen that the domain pattern and size vary with the increase of the thickness t of the non-ferromagnetic Au layer remarkably. With the measurements of the effective perpendicular anisotropy Ku and the domain period d, it was found that there are similar trends of d and Ku as functions of t. The variations of the domain pattern and size were qualitatively interpreted in terms of magnetic domain theory, the theoretical relations of d and the domain wall energy ow vs t were calculated. As t = 8.5 AL(1AL=0.235nm), the largest ow is 11mJ/m2.

  6. Beam Energy Dependence of Dielectron Production in Au+Au Collisions from STAR at RHIC

    CERN Document Server

    Huck, Patrick

    2014-01-01

    We present the energy-dependent study of dielectron production in 0-80% minimum-bias Au+Au collisions at $\\sqrt{s_{NN}}$ energies of 19.6, 27, 39, and 62.4 GeV in STAR. Invariant mass ($M_{ee}$) and transverse momentum ($p_T$) differential measurements of dielectron yields are compared to cocktail simulations of known hadronic sources and semi-leptonic charmed decays. The enhancement (excess yield) prominent in the Low-Mass Region (LMR) over the cocktail at all energies, is further compared to calculations of $\\rho$ in-medium modifications. Within statistical and systematic uncertainties, we find that the model consistently describes this enhancement from SPS up to top RHIC energies in its $M_{ee}$- as well as $p_T$-dependence. Dielectron measurements drive the statistics for the future BES Phase-II program, which promises to improve our understanding of the LMR enhancement's trend with total baryon densities.

  7. Azimuthal anisotropy in Au+Au collisions at sqrtsNN = 200 GeV

    CERN Document Server

    Adams, J; Ahammed, Z; Amonett, J; Anderson, B D; Arkhipkin, D; Averichev, G S; Badyal, S K; Bai, Y; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Bekele, S; Belaga, V V; Bellwied, R; Berger, J; Bezverkhny, B I; Bharadwaj, S; Bhasin, A; Bhati, A K; Bhatia, V S; Bichsel, H; Billmeier, A; Bland, L C; Blyth, C O; Bonner, B E; Botje, M; Boucham, A; Brandin, A V; Bravar, A; Bystersky, M; Cadman, R V; Cai, X Z; Caines, H; Calderón de la Barca-Sanchez, M; Carroll, J; Castillo, J; Cebra, D; Chajecki, Z; Chaloupka, P; Chattopadhyay, S; Chen, H F; Chen, Y; Cheng, J; Cherney, M; Chikanian, A; Christie, W; Coffin, J P; Cormier, T M; Cramer, J G; Crawford, H J; Das, D; Das, S; De Moura, M M; Derevshchikov, A A; Didenko, L; Dietel, T; Dogra, S M; Dong, W J; Dong, X; Draper, J E; Du, F; Dubey, A K; Dunin, V B; Dunlop, J C; Dutta-Majumdar, M R; Eckardt, V; Edwards, W R; Efimov, L G; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Estienne, M; Fachini, P; Faivre, J; Fatemi, R; Fedorisin, J; Filimonov, K; Filip, P; Finch, E; Fine, V; Fisyak, Yu; Foley, K J; Fomenko, K; Fu, J; Gagliardi, C A; Gans, J; Ganti, M S; Gaudichet, L; Geurts, F J M; Ghazikhanian, V; Ghosh, P; González, J E; Grachov, O; Grebenyuk, O; Grosnick, D P; Guertin, S M; Guo, Y; Sen-Gupta, A; Gutíerrez, T D; Hallman, T J; Hamed, A; Hardtke, D; Harris, J W; Heinz, M; Henry, T W; Hepplemann, S; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Huang, H Z; Huang Sheng Li; Hughes, E W; Humanic, T J; Igo, G; Ishihara, A; Jacobs, P; Jacobs, W W; Janik, M; Jiang, H; Jones, P G; Judd, E G; Kabana, S; Kang, K; Kaplan, M; Keane, D; Khodyrev, V Yu; Kiryluk, J; Kisiel, A; Kislov, E M; Klay, J; Klein, S R; Klyachko, A; Koetke, D D; Kollegger, T; Kopytine, M; Kotchenda, L; Krämer, M; Kravtsov, P; Kravtsov, V I; Krüger, K; Kuhn, C; Kulikov, A I; Kumar, A; Kunz, C L; Kutuev, R K; Kuznetsov, A A; Lamont, M A C; Landgraf, J M; Lange, S; Laue, F; Lauret, J; Lebedev, A; Lednicky, R; Lehocka, S; Le Vine, M J; Li, C; Li, Q; Li, Y; Lindenbaum, S J; Lisa, M A; Liu, F; Liu, L; Liu, Q J; Liu, Z; Ljubicic, T; Llope, W J; Long, H; Longacre, R S; López-Noriega, M; Love, W A; Lu, Y; Ludlam, T; Lynn, D; Ma, G L; Ma, J G; Ma, Y G; Magestro, D; Mahajan, S; Mahapatra, D P; Majka, R; Mangotra, L K; Manweiler, R; Margetis, S; Markert, C; Martin, L; Marx, J N; Matis, H S; Matulenko, Yu A; McClain, C J; McShane, T S; Meissner, F; Melnik, Yu M; Meschanin, A; Miller, M L; Milosevich, Z; Minaev, N G; Mironov, C; Mischke, A; Mishra, D K; Mitchell, J; Mohanty, B; Molnár, L; Moore, C F; Morozov, D A; Munhoz, M G; Nandi, B K; Nayak, S K; Nayak, T K; Nelson, J M; Netrakanti, P K; Nikitin, V A; Nogach, L V; Nurushev, S B; Odyniec, Grazyna Janina; Ogawa, A; Okorokov, V; Oldenburg, M; Olson, D; Pal, S K; Panebratsev, Yu A; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Peitzmann, Thomas; Perevozchikov, V; Perkins, C; Peryt, W; Petrov, V A; Phatak, S C; Picha, R; Planinic, M; Pluta, J; Porile, N; Porter, J; Poskanzer, A M; Potekhin, M V; Potrebenikova, E V; Potukuchi, B V K S; Prindle, D; Pruneau, C A; Putschke, J; Rai, G; Rakness, G; Raniwala, R; Raniwala, S; Ravel, O; Ray, R L; Razin, S V; Reichhold, D M; Reid, J G; Renault, G; Retière, F; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevski, O V; Romero, J L; Rose, A; Roy, C; Ruan, L; Sahoo, R; Sakrejda, I; Salur, S; Sandweiss, J; Savin, I; Sazhin, P S; Schambach, J; Scharenberg, R P; Schmitz, N; Schröder, L S; Schweda, K; Seger, J; Seyboth, P; Shahaliev, E; Shao, M; Shao, W; Sharma, M; Shen, W Q; Shestermanov, K E; Shimansky, S S; Sichtermann, E P; Simon, F; Singaraju, R N; Skoro, G P; Smirnov, N; Snellings, R; Sood, G; Sørensen, P; Sowinski, J; Speltz, J; Spinka, H M; Srivastava, B; Stadnik, A; Stanislaus, T D S; Stock, R; Stolpovsky, A; Strikhanov, M N; Stringfellow, B C; Suaide, A A P; Sugarbaker, E R; Suire, C; Sumbera, M; Surrow, B; Symons, T J M; Szanto de Toledo, A; Szarwas, P; Tai, A; Takahashi, J; Tang, A H; Tarnowsky, T J; Thein, D; Thomas, J H; Timoshenko, S; Tokarev, M; Trainor, T A; Trentalange, S; Tribble, R E; Tsai, O D; Ulery, J; Ullrich, T; Underwood, D G; Urkinbaev, A R; Van Buren, G; Van, M; Leeuwen; Van der Molen, A M; Varma, R; Vasilevski, I M; Vasilev, A N; Vernet, R; Vigdor, S E; Viyogi, V P; Vokal, S; Voloshin, S A; Vznuzdaev, M; Waggoner, W T; Wang, F; Wang, G; Wang, G; Wang, X L; Wang, Y; Wang, Y; Wang, Z M; Ward, H; Watson, J W; Webb, J C; Wells, R; Westfall, G D; Wetzler, A; Whitten, C; Wieman, H; Wissink, S W; Witt, R; Wood, J; Wu, J; Xu, N; Xu, Z; Xu, Z Z; Yamamoto, E; Yepes, P; Yurevich, V I; Zanevsky, Yu V; Zhang, H; Zhang, W M; Zhang, Z P; Zolnierczuk, P A; Zoulkarneev, R; Zoulkarneeva, Y; Zubarev, A N

    2004-01-01

    The results from the STAR Collaboration on directed flow ($v_1$), elliptic flow ($v_2$), and the fourth harmonic ($v_4$) in the anisotropic azimuthal distribution of particles from Au+Au collisions at $\\sqrtsNN = 200$ GeV are summarized and compared with results from other experiments and theoretical models. Results for identified particles are presented and fit with a Blast Wave model. For $v_2$, scaling with the number of constituent quarks and parton coalescence is discussed. For $v_4$, scaling with $v_2^2$ and quark coalescence predictions for higher harmonic flow is discussed. The different anisotropic flow analysis methods are compared and nonflow effects are extracted from the data.

  8. Directed flow in Au+Au collisions at $\\sqrt{s_{_{NN}}}$ =62 GeV

    CERN Document Server

    Keane, D; Aggarwal, M M; Ahammed, Z; Amonett, J; Anderson, B D; Arkhipkin, D; Averichev, G S; Badyal, S K; Bai, Y; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Bekele, S; Belaga, V V; Bellingeri-Laurikainen, A; Bellwied, R; Berger, J; Bezverkhny, B I; Bharadwaj, S; Bhasin, A; Bhati, A K; Bhatia, V S; Bichsel, H; Bielcik, J; Bielcikova, J; Billmeier, A; Bland, L C; Blyth, C O; Blyth, S L; Bonner, B E; Botje, M; Boucham, A; Bouchet, J; Brandin, A V; Bravar, A; Bystersky, M; Cadman, R V; Cai, X Z; Caines, H; Calderón de la Barca-Sanchez, M; Castillo, J; Catu, O; Cebra, D; Chajecki, Z; Chaloupka, P; Chattopadhyay, S; Chen, H F; Chen, J H; Chen, Y; Cheng, J; Cherney, M; Chikanian, A; Choi, H A; Christie, W; Coffin, J P; Cormier, T M; Cosentino, M R; Cramer, J G; Crawford, H J; Das, D; Das, S; Daugherity, M; De Moura, M M; De Phillips, M; Dedovich, T G; Derevshchikov, A A; Didenko, L; Dietel, T; Dogra, S M; Dong, W J; Dong, X; Draper, J E; Du, F; Dubey, A K; Dunin, V B; Dunlop, J C; Dutta-Majumdar, M R; Eckardt, V; Edwards, W R; Efimov, L G; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Estienne, M; Fachini, P; Faivre, J; Fatemi, R; Fedorisin, J; Filimonov, K; Filip, P; Finch, E; Fine, V; Fisyak, Yu; Fornazier, K S F; Fu, J; Gagliardi, C A; Gaillard, L; Gans, J; Ganti, M S; Geurts, F; Ghazikhanian, V; Ghosh, P; González, J E; Gos, H; Grachov, O; Grebenyuk, O; Grosnick, D P; Guertin, S M; Guo, Y; Gupta, N; Gutíerrez, T D; Hallman, T J; Hamed, A; Hardtke, D; Harris, J W; Heinz, M; Henry, T W; Hepplemann, S; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Horner, M J; Huang, H Z; Huang, S L; Hughes, E W; Humanic, T J; Igo, G; Ishihara, A; Jacobs, P; Jacobs, W W; Jedynak, M; Jiang, H; Jones, P G; Judd, E G; Kabana, S; Kang, K; Kaplan, M; Kechechyan, A; Khodyrev, V Yu; Kim, B C; Kiryluk, J; Kisiel, A; Kislov, E M; Klay, J; Klein, S R; Koetke, D D; Kollegger, T; Kopytine, M; Kotchenda, L; Kowalik, K L; Kravtsov, P; Kravtsov, V I; Krämer, M; Krüger, K; Kuhn, C; Kulikov, A I; Kumar, A; Kutuev, R K; Kuznetsov, A A; Lamont, M A C; Landgraf, J M; Lange, S; Laue, F; Lauret, J; Le Vine, M J; Lebedev, A; Lednicky, R; Lee, C H; Lehocka, S; Li, C; Li, Q; Li, Y; Lin, G; Lindenbaum, S J; Lisa, M A; Liu, F; Liu, H; Liu, J; Liu, L; Liu, Q J; Liu, Z; Ljubicic, T; Llope, W J; Long, H; Longacre, R S; Love, W A; Lu, Y; Ludlam, T; Lynn, D; López-Noriega, M; Ma, G L; Ma, J G; Ma, Y G; Magestro, D; Mahajan, S; Mahapatra, D P; Majka, R; Mangotra, L K; Manweiler, R; Margetis, S; Markert, C; Martin, L; Marx, J N; Matis, H S; Matulenko, Yu A; McClain, C J; McShane, T S; Meissner, F; Melnik, Yu M; Meschanin, A; Miller, M L; Minaev, N G; Mironov, C; Mischke, A; Mishra, D K; Mitchell, J; Mohanty, B; Molnár, L; Moore, C F; Morozov, D A; Munhoz, M G; Nandi, B K; Nayak, S K; Nayak, T K; Nelson, J M; Netrakanti, P K; Nikitin, V A; Nogach, L V; Nurushev, S B; Odyniec, Grazyna Janina; Ogawa, A; Okorokov, V; Oldenburg, M; Olson, D; Pal, S K; Panebratsev, Yu A; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Peitzmann, T; Perevozchikov, V; Perkins, C; Peryt, W; Petrov, V A; Phatak, S C; Picha, R; Planinic, M; Pluta, J; Porile, N; Porter, J; Poskanzer, A M; Potekhin, M V; Potrebenikova, E V; Potukuchi, B V K S; Prindle, D; Pruneau, C A; Putschke, J; Rakness, G; Raniwala, R; Raniwala, S; Ravel, O; Ray, R L; Razin, S V; Reichhold, D M; Reid, J G; Reinnarth, J; Renault, G; Retière, F; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevski, O V; Romero, J L; Rose, A; Roy, C; Ruan, L; Russcher, M J; Sahoo, R; Sakrejda, I; Salur, S; Sandweiss, J; Sarsour, M; Savin, I; Sazhin, P S; Schambach, J; Scharenberg, R P; Schmitz, N; Schweda, K; Seger, J; Selyuzhenkov, I; Sen-Gupta, A; Seyboth, P; Shahaliev, E; Shao, M; Shao, W; Sharma, M; Shen, W Q; Shestermanov, K E; Shimansky, S S; Sichtermann, E P; Simon, F; Singaraju, R N; Smirnov, N; Snellings, R; Sood, G; Sowinski, J; Speltz, J; Spinka, H M; Srivastava, B; Stadnik, A; Stanislaus, T D S; Stock, R; Stolpovsky, A; Strikhanov, M N; Stringfellow, B C; Suaide, A A P; Sugarbaker, E R; Sumbera, M; Surrow, B; Swanger, M; Symons, T J M; Szanto de Toledo, A; Sørensen, P; Tai, A; Takahashi, J; Tang, A H; Tarnowsky, T J; Thein, D; Thomas, J H; Timmins, A R; Timoshenko, S; Tokarev, M; Trentalange, S; Tribble, R E; Tsai, O D; Ulery, J; Ullrich, T; Underwood, D G; Van Buren, G; Van Leeuwen, M; Van der Kolk, N; Van der Molen, A M; Varma, R; Vasilev, A N; Vasilevski, I M; Vernet, R; Vigdor, S E; Viyogi, Y P; Vokal, S; Voloshin, S A; Waggoner, W T; Wang, F; Wang, G; Wang, X L; Wang, Y; Wang, Z M; Ward, H; Watson, J W; Webb, J C; Westfall, G D; Wetzler, A; Whitten, C; Wieman, H; Wissink, S W; Witt, R; Wood, J; Wu, J; Xu, N; Xu, Z; Xu, Z Z; Yamamoto, E; Yepes, P; Yoo, I K; Yurevich, V I; Zborovský, I; Zhang, H; Zhang, W M; Zhang, Y; Zhang, Z P; Zhong, C; Zoulkarneev, R; Zoulkarneeva, Y; Zubarev, A N; Zuo, J X; Wang, Gang

    2006-01-01

    We present the directed flow ($v_1$) measured in Au+Au collisions at $\\sqrt{s_{_{NN}}}$ = 62 GeV in the mid-pseudorapidity region $|\\eta|<1.3$ and in the forward pseudorapidity region $2.5 < |\\eta| < 4.0$. The results are obtained using the three-particle cumulant method, the event plane method with mixed harmonics, and for the first time at the Relativistic Heavy Ion Collider (RHIC), the standard method with the event plane reconstructed from spectator neutrons. Results from all three methods are in good agreement. Over the pseudorapidity range studied, charged particle directed flow is in the direction opposite to that of fragmentation neutrons.

  9. Autopistas: AU-1 25 de Mayo y AU-6 Perito Moreno

    Directory of Open Access Journals (Sweden)

    Editorial, Equipo

    1981-02-01

    Full Text Available Highways AU-1 and AU-6, approximately 17 km. long, were constructed for the purpose of solving the serious traffic problems in Buenos Aires, a city of nine million inhabitants and an evergrowing number of cars. A computer program was created for the design based on the geometric shape of the highway and the position of the supports. Using this, all elements composing the structure were calculated and the framework was sized. This programme made it possible to complete a stretch of 150 metres per week. The very rapid construction was carried out through self-supporting arches made of metallic beams held in place by brackets. The brackets were fitted in specially designed grooves in the major supports of the highway.

    Las autopistas AU-1 y AU-6, con una longitud aproximada de 17 km, se realizaron con objeto de resolver el grave problema de infraestructura vial del Municipio de Buenos Aires, ciudad de nueve millones de habitantes y con un parque de vehículos en rápido crecimiento. Para el proyecto se creó un programa de ordenador con el que, partiendo de la definición geométrica de la autopista y de la posición de las pilas, se calculan todos los elementos que componen la estructura y se dimensionan las armaduras. Este programa permitió proyectar un tramo (150 m por semana. La construcción, a un ritmo muy rápido, se llevó a cabo mediante cimbras autoportantes compuestas por vigas metálicas apoyadas sobre ménsulas, las cuales a su vez apoyan en unos nichos dejados en las pilas.

  10. Differential flow of protons in Au+Au collisions at AGS energies

    Energy Technology Data Exchange (ETDEWEB)

    Sahu, P.K. E-mail: pradip@iopb.res.in; Cassing, W

    2002-12-30

    We study the proton sideward and elliptic differential flow for Au+Au collisions at AGS energies (2-8 A GeV) in a microscopic relativistic transport model that includes all baryon resonances up to a mass of 2 GeV as well as string degrees of freedom for the higher hadronic excitations. In order to explore the sensitivity of the various differential flows to the nuclear equation of state (EoS) we use three different parameterizations of the scalar and vector mean-fields, i.e., NL2 (soft), NL23 (medium) and NL3 (hard), with their momentum dependence fitted to the experimental Schroedinger equivalent potential (at normal nuclear matter density {rho}{sub 0}) up to kinetic energies of 1 GeV. We calculate the excitation function of sideward and elliptic flow within these parameter sets for Au+Au collisions and compare with the recent data from the E895 Collaboration as a function of rapidity, impact parameter and transverse momentum, respectively. We find that the best description of the differential data is provided by a rather 'stiff' EoS at 2 A GeV (NL3) while at higher bombarding energies (4-8 A GeV) a 'medium' EoS leads to the lowest {chi}{sup 2} with respect to the data. However, the differences in the transverse and elliptic flows (from the different parameter sets) become of minor significance at 4-8 A GeV. We attribute this insensitivity to a similar reduction of the vector potential in all models and to the dominance of string degrees of freedom at these bombarding energies.

  11. 超声楔键合Au/Al和Al/Au界面IMC演化%Intermetallic Compound Evolution of Ultrasonic Au/Al and Al/Au Wedge Bond

    Institute of Scientific and Technical Information of China (English)

    计红军; 李明雨; 王春青

    2007-01-01

    基于固体相变理论,研究Au丝、Al丝超声楔-楔键合接头的温度长期可靠性.200℃下,存储时间<48 h时,Au/Al接头界面并未发生明显变化;随着接头存储时间增加,界面金属间化合物(IMC)开始由焊盘向引线方向生长(垂直生长);240 h时,Al焊盘完全被消耗,接头连接界面部位生成Au5Al2,周边为Au2Al;继续增加存储时间,IMC向接头水平方向生长(水平生长),Au5Al2向更稳定的Au2Al转变,IMC与引线之间形成严重的Kirkendall孔洞.Al/Au系统相对稳定得多,界面IMC生长缓慢,然而,界面化合物AuAl2导致接头裂纹,而引线内部出现严重的空洞.对比并分析了两种楔焊系统界面演变特点和产生机制.

  12. Inclusive cross section and correlations of fully reconstructed jets in 200 GEV Au+Au and p+p collisions

    OpenAIRE

    Ploskon, Mateusz; Collaboration, for the STAR

    2009-01-01

    We present an experimental study of full jet reconstruction in the high multiplicity environment of heavy ion collisions, utilizing 200 GeV p+p and central Au+Au data measured by STAR. Inclusive differential jet production cross sections and ratios are reported, as well as high-pT hadron-jet coincidences.

  13. Gold surfaces and nanoparticles are protected by Au(0)-thiyl species and are destroyed when Au(I)-thiolates form

    DEFF Research Database (Denmark)

    Reimers, Jeffrey R.; Ford, Michael J.; Halder, Arnab;

    2016-01-01

    The synthetic chemistry and spectroscopy of sulfur-protected gold surfaces and nanoparticles is analyzed, indicating that the electronic structure of the interface is Au(0)-thiyl, with Au(I)-thiolates identified as high-energy excited surface states. Density-functional theory indicates that it is...

  14. Charged particle multiplicity fluctuations in Au+Au collisions at \\sqrt{s_{NN}} = 200\\, {\\rm GeV}

    Science.gov (United States)

    Wozniak, Krzysztof; PHOBOS Collaboration; Back, B. B.; Baker, M. D.; Ballintijn, M.; Barton, D. S.; Betts, R. R.; Bickley, A. A.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Chai, Z.; Decowski, M. P.; García, E.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Heintzelman, G. A.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Holynski, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C. M.; Lin, W. T.; Manly, S.; McLeod, D.; Mignerey, A. C.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Remsberg, L. P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Skulski, W.; Steinberg, P.; Stephans, G. S. F.; Sukhanov, A.; Tang, J. L.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Verdier, R.; Wolfs, F. L. H.; Wosiek, B.; Wuosmaa, A. H.; Wyslouch, B.

    2004-08-01

    This paper presents the first PHOBOS results on charged particle multiplicity fluctuations measured for Au+Au collisions at the highest RHIC energy within a wide pseudorapidity range of |eegr| < 3. The dependence on collision geometry is removed in the analysis by using the normalized difference between the number of particles in separate eegr bins. We compare our data to HIJING model predictions.

  15. Effect of Au nano-particle aggregation on the deactivation of the AuCl3/AC catalyst for acetylene hydrochlorination

    OpenAIRE

    Bin Dai; Qinqin Wang; Feng Yu; Mingyuan Zhu

    2015-01-01

    A detailed study of the valence state and distribution of the AuCl3/AC catalyst during the acetylene hydrochlorination deactivation process is described and discussed. Temperature-programmed reduction and X-ray photoelectron spectral analysis indicate that the active Au3+ reduction to metallic Au0 is one reason for the deactivation of AuCl3/AC catalyst. Transmission electron microscopy characterization demonstrated that the particle size of Au nano-particles increases with increasing reaction...

  16. Electronic and geometric structures of Au30 clusters: a network of 2e-superatom Au cores protected by tridentate protecting motifs with u3-S

    Science.gov (United States)

    Tian, Zhimei; Cheng, Longjiu

    2015-12-01

    Density functional theory calculations have been performed to study the experimentally synthesized Au30S(SR)18 and two related Au30(SR)18 and Au30S2(SR)18 clusters. The patterns of thiolate ligands on the gold cores for the three thiolate-protected Au30 nanoclusters are on the basis of the ``divide and protect'' concept. A novel extended protecting motif with u3-S, S(Au2(SR)2)2AuSR, is discovered, which is termed the tridentate protecting motif. The Au cores of Au30S(SR)18, Au30(SR)18 and Au30S2(SR)18 clusters are Au17, Au20 and Au14, respectively. The superatom-network (SAN) model and the superatom complex (SAC) model are used to explain the chemical bonding patterns, which are verified by chemical bonding analysis based on the adaptive natural density partitioning (AdNDP) method and aromatic analysis on the basis of the nucleus-independent chemical shift (NICS) method. The Au17 core of the Au30S(SR)18 cluster can be viewed as a SAN of one Au6 superatom and four Au4 superatoms. The shape of the Au6 core is identical to that revealed in the recently synthesized Au18(SR)14 cluster. The Au20 core of the Au30(SR)18 cluster can be viewed as a SAN of two Au6 superatoms and four Au4 superatoms. The Au14 core of Au30S2(SR)18 can be regarded as a SAN of two pairs of two vertex-sharing Au4 superatoms. Meanwhile, the Au14 core is an 8e-superatom with 1S21P6 configuration. Our work may aid understanding and give new insights into the chemical synthesis of thiolate-protected Au clusters.Density functional theory calculations have been performed to study the experimentally synthesized Au30S(SR)18 and two related Au30(SR)18 and Au30S2(SR)18 clusters. The patterns of thiolate ligands on the gold cores for the three thiolate-protected Au30 nanoclusters are on the basis of the ``divide and protect'' concept. A novel extended protecting motif with u3-S, S(Au2(SR)2)2AuSR, is discovered, which is termed the tridentate protecting motif. The Au cores of Au30S(SR)18, Au30(SR)18 and Au30S

  17. 从头计算方法比较研究B2Au4,Al2Au4和BAlAu4的几何和电子结构%A Comparative Ab initio Study of the Geometric and Electronic Structures of B2Au4, Al2Au4 and BAlAu4

    Institute of Scientific and Technical Information of China (English)

    姚文志; 卢章辉; 李思殿

    2014-01-01

    Au/H similarity is a hot topic in chemistry. Here, we report the theoretical prediction of new members of the Au/H analogy family:covalent B2Au4, ionic Al2Au4, and BAlAu4. A comparative study of the geometric and electronic structures of electron-deficient B2Au4, Al2Au4, and BAlAu4 was performed based on density and wave functional theories. Detailed orbital analyses, adaptive natural density partitioning (AdNDP), and electron localization function (ELF) analyses were performed. Ab initio theoretical evidence strongly suggests that the ground state of slightly distorted C2 B2Au4 is a covalent complex containing two B―Au―B three centers-two electrons (3c-2e) bonds. Unexpectedly, C3v Al+(AlAu4)-and C3v Al+(BAu4)-are predicted to have a salt-like composition with three X―Au―Al 3c-2e bonds (X=Al in Al2Au4, X=B in BAlAu4). Al2Au4 and BAlAu4 represent the first examples of bridging gold bonds in ionic-deficient systems. The adiabatic and vertical detachment energies of the anions were calculated to facilitate their future experimental characterization. Bridging gold addressed in this work provides an interesting bonding mode for covalent and ionic-deficient systems, and may aid in designing new materials and catalysts with highly dispersed Au atoms.%Au/H相似性的研究是现代化学中的一个热门话题.我们从理论上报道Au/H相似的新成员:共价化合物B2Au4,离子化合物Al2Au4和BAlAu4.采用密度泛函和波函数理论方法对比研究了缺电子体系B2Au4、Al2Au4和BAlAu4的几何和电子结构.详细讨论了它们基态结构的轨道、适应性自然密度划分(AdNDP)和电子局域函数(ELF)分析.计算结果表明稍微扭曲变形的C2 B2Au4是基态结构,在这个共价化合物中含有两个B―Au―B三中心二电子(3c-2e)键.然而C3v Al+(AlAu4)-和C3v Al+(BAu4)-被研究证明是含有三个X―Au―Al三中心二电子键的类盐化合物(在Al2Au4中X=Al, BAlAu4中X=B). Al2Au4和BAlAu4是至今为止首例

  18. Enantiospecific adsorption of cysteine on a chiral Au34 cluster

    Science.gov (United States)

    Pelayo, José de Jesús; Valencia, Israel; Díaz, Gabriela; López-Lozano, Xóchitl; Garzón, Ignacio L.

    2015-12-01

    The interaction of biological molecules like chiral amino acids with chiral metal clusters is becoming an interesting and active field of research because of its potential impact in, for example, chiral molecular recognition phenomena. In particular, the enantiospecific adsorption (EA) of cysteine (Cys) on a chiral Au55 cluster was theoretically predicted a few years ago. In this work, we present theoretical results, based on density functional theory, of the EA of non-zwitterionic cysteine interacting with the C3-Au34 chiral cluster, which has been experimentally detected in gas phase, using trapped ion electron diffraction. Our results show that, indeed, the adsorption energy of the amino acid depends on which enantiomers participate in the formation Cys-Au34 chiral complex. EA was obtained in the adsorption modes where both the thiol, and the thiol-amino functional groups of Cys are adsorbed on low-coordinated sites of the metal cluster surface. Similarly to what was obtained for the Cys-Au55 chiral complex, in the present work, it is found that the EA is originated from the different strength and location of the bond between the COOH functional group and surface Au atoms of the Au34 chiral cluster. Calculations of the vibrational spectrum for the different Cys-Au34 diastereomeric complexes predict the existence of a vibro-enantiospecific effect, indicating that the vibrational frequencies of the adsorbed amino acid depend on its handedness.

  19. Ge-Au eutectic bonding of Ge {100} single crystals

    Science.gov (United States)

    Knowlton, W. B.; Itoh, K. M.; Beeman, J. W.; Emes, J. H.; Loretto, D.; Haller, E. E.

    1993-11-01

    We present preliminary results on the eutectic bonding between two {100} Ge single crystal surfaces using thin films of Au ranging from 900Å/surface to 300Å/surface and Pd (10% the thickness of Au). Following bonding, plan view optical microscopy (OM) of the cleaved interface of samples with Au thicknesses ≤ 500Å/surface show a eutectic morphology more conducive to phonon transmission through the bond interface. High resolution transmission electron microscopy (HRTEM) cross sectional interface studies of a 300Å/surface Au sample show epitaxial growth of Ge. In sections of the bond, lattice continuity of the Ge is apparent through the interface. TEM studies also reveal heteroepitaxial growth of Au with a Au-Ge lattice mismatch of less than 2%. Eutectic bonds with 200Å/surface Au have been attained with characterization pending. An optical polishing technique for Ge has been optimized to insure intimate contact between the Ge surfaces prior to bonding. Interferometry analysis of the optically polished Ge surface shows that surface height fluctuations lie within ±150Å across an interval of 1mm. Characterization of phonon transmission through the interface is discussed with respect to low temperature detection of ballistic phonons.

  20. Tailoring the FeRh magnetostructural response with Au diffusion

    Science.gov (United States)

    Loving, M.; de Vries, M. A.; Jimenez-Villacorta, F.; Le Graët, C.; Liu, X.; Fan, R.; Langridge, S.; Heiman, D.; Marrows, C. H.; Lewis, L. H.

    2012-08-01

    Factors which contribute to magnetostructural transition control have been demonstrated by study of the effects of Au incorporation on the magnetic and structural character of CsCl-structured equiatomic FeRh thin films. Sputtered films were capped with 2 nm of Au deposited at 873 K and at 323 K and subsequently characterized with magnetometry and synchrotron-based structural probes. Diffusion of Au into the FeRh film layer at 873 K is confirmed by a reduction in the Au capping layer thickness relative to the film capped at 323 K. The impact of Au diffusion on the FeRh magnetostructural character is noted by a decrease in the onset of the transition temperature, a thermally broadened first-order transition and an increased sensitivity of the transition to applied magnetic field. Additionally, magnetization data indicate that Au diffusion causes retention of the ferromagnetic phase well below the normal magnetostructural transition temperature. These results are attributed to a multiphase FeRh film layer created by thermally driven Au diffusion.

  1. Structural, electronic and magnetic properties of Au-based monolayer derivatives in honeycomb structure

    Science.gov (United States)

    Kapoor, Pooja; Sharma, Munish; Kumar, Ashok; Ahluwalia, P. K.

    2016-05-01

    We present electronic properties of atomic layer of Au, Au2-N, Au2-O and Au2-F in graphene-like structure within the framework of density functional theory (DFT). The lattice constant of derived monolayers are found to be higher than the pristine Au monolayer. Au monolayer is metallic in nature with quantum ballistic conductance calculated as 4G0. Similarly, Au2-N and Au2-F monolayers show 4G0 and 2G0 quantum conductance respectively while semiconducting nature with calculated band gap of 0.28 eV has been observed for Au2-O monolayer. Most interestingly, half metalicity has been predicted for Au2-N and Au2-F monolayers. Our findings may have importance for the application of these monolayers in nanoelectronic and spintronics.

  2. Optical Behaviour of ZnO/Au Nanojunctions

    Directory of Open Access Journals (Sweden)

    Shital V. Kahane

    2011-01-01

    Full Text Available ZnO/Au nanojunctions were prepared by electrochemical method at room temperature. Nanojunction formation is vivid from appearance of ZnO and Au features in x-ray diffraction pattern. Optical absorption spectra reveal excitonic as well as surface plasmon resonance (SPR feature in case of nanojunctions. Bleaching of the excitonic feature associated with the blue shift, is a signature of charge transfer from Au to ZnO at the interface of nanojunction. An increase in intensity of band edge luminescence and quenching of green emission indicates the passivation of surface defects due to formation of nanojunctions.

  3. Energy level alignment in Au/pentacene/PTCDA trilayer stacks

    Science.gov (United States)

    Sehati, P.; Braun, S.; Fahlman, M.

    2013-09-01

    Ultraviolet photoelectron spectroscopy is used to investigate the energy level alignment and molecular orientation at the interfaces in Au/pentacene/PTCDA trilayer stacks. We deduced a standing orientation for pentacene grown on Au while we conclude a flat lying geometry for PTCDA grown onto pentacene. We propose that the rough surface of polycrystalline Au induces the standing geometry in pentacene. It is further shown that in situ deposition of PTCDA on pentacene can influence the orientation of the surface pentacene layer, flipping part of the surface pentacene molecules into a flat lying geometry, maximizing the orbital interaction across the pentacene-PTCDA heterojunction.

  4. Thermodynamic description of Au-Ag-Si ternary system

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Based on the available experimental information, the Ag-Si binary system was thermodynamically assessed using the CALPHAD method. The solution phases, including liquid, fcc-Al and diamond-A4, were modeled as substitutional solutions, of which the excess Gibbs energies were expressed by Redlich-Kister polynomial functions. Combined with previous assessment of the Ag-Au and Au-Si binary systems, thermodynamic description of the Au-Ag-Si ternary system was performed to reproduce the reported phase equilibria. Thermodynamic properties of liquid alloys, liquidus projection and several vertical and isothermal sections of this ternary system were calculated, which are in reasonable agreement with the reported experimental data.

  5. Au(111) and Pt(111) surface phase behavior

    DEFF Research Database (Denmark)

    Sandy, A.R.; Mochrie, S.G.J.; Zehner, D.M.;

    1993-01-01

    We describe our recent X-ray scattering studies of the structure and phases of the clean Au(111) and Pt(111) surfaces. Below 0.65 of their respective bulk melting temperatures, the Au(111) surface has a well-ordered chevron reconstruction and the Pt(111) surface is unreconstructed. Above these...... temperatures, both surfaces reconstruct to form layers that are isotropically compresses and have only short-range order. Throughout their reconstructed phases, the densities of the Au and Pt(111) surfaces increase with increasing temperature....

  6. AuScope VLBI Project and Hobart 26-m Antenna

    Science.gov (United States)

    Lovell, Jim; Dickey, John; Reid, Brett; McCallum, Jamie; Shabala, Stas; Watson, Christopher; Ellingsen, Simon; Memin, Anthony

    2013-01-01

    This is a report on the activities carried out at the three AuScope VLBI observatories and the Hobart 26-m antenna. In 2012 the three AuScope 12-m antennas at Hobart (Hb), Katherine (Ke), and Yarragadee (Yg) completed their first full year of operations as an array. The Hobart 26-m antenna (Ho) continued to make a contribution to IVS, providing overlap with the Hb time series. In total the AuScope antennas and the Hobart 26 m observed for 146 antenna days in 2012. In this report we also briefly highlight our research activities during 2012 and our plans for 2013.

  7. Electrochemical Capacitance DNA Sensing at Hairpin-Modified Au Electrodes

    OpenAIRE

    Joel Rivera-Gandía; Maria del Mar Maldonado; Yarimar De La Torre-Meléndez; Edwin O. Ortiz-Quiles; Vargas-Barbosa, Nella M.; Cabrera, Carlos R.

    2011-01-01

    An interfacial capacitance measurement electrochemical technique has been used for the sensing of self-assembled DNA hairpin probes (M. tuberculosis and B. anthracis) attached to Au electrodes. The double-layer capacitance (Cdl) was determined with electrochemical perturbations from 0.2 V to 0.5 V versus Ag/AgCl at a Au/M. tuberculosis DNA hairpin probe at surface coverage Au electrodes. The capacitance study was done at pH 7, which was necessary to maintain the M. tuberculosis and B. anthrac...

  8. d+Au Hadron Correlation Measurements from PHENIX

    OpenAIRE

    Sickles, Anne M.; Collaboration, for the PHENIX

    2013-01-01

    Recent observations of extended pseudorapidity correlations at the LHC in p+p and p+Pb collisions are of great interest. Here we present related re- sults from d+Au collisions at PHENIX. We present the observed v2 and discuss the possible origin in the geometry of the collision region. We also present new measurements of the pseudorapidity dependence of the ridge in d+Au collision. Future plans to clarify the role of geometry in small collision systems using 3He+Au collisions are discussed.

  9. Au plasmonics in a WS{sub 2}-Au-CuInS{sub 2} photocatalyst for significantly enhanced hydrogen generation

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, Zhongzhou [CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology, Beijing 100190 (China); School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Wang, Zhenxing, E-mail: wangzx@nanoctr.cn, E-mail: hej@nanoctr.cn; Shifa, Tofik Ahmed; Wang, Fengmei; Zhan, Xueying; Xu, Kai; He, Jun, E-mail: wangzx@nanoctr.cn, E-mail: hej@nanoctr.cn [CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology, Beijing 100190 (China); Liu, Quanlin [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China)

    2015-11-30

    Promoting the activities of photocatalysts is still the critical challenge in H{sub 2} generation area. Here, a Au plasmon enhanced photocatalyst of WS{sub 2}-Au-CuInS{sub 2} is developed by inserting Au nanoparticles between WS{sub 2} nanotubes and CuInS{sub 2} (CIS) nanoparticles. Due to the localized surface plasmonic resonance properties from Au nanoparticles, WS{sub 2}-Au-CIS shows the best performance as compared to Au-CIS, CIS, WS{sub 2}-CIS, CIS-Au, WS{sub 2}-Au, and WS{sub 2}-CIS-Au. The surface plasmonic resonance effects dramatically intensify the absorption of visible light and help to inject hot electrons into the semiconductors. Our findings open up an efficient method to optimize the type-II structures for photocatalytic water splitting.

  10. Gold surfaces and nanoparticles are protected by Au(0)-thiyl species and are destroyed when Au(I)-thiolates form.

    Science.gov (United States)

    Reimers, Jeffrey R; Ford, Michael J; Halder, Arnab; Ulstrup, Jens; Hush, Noel S

    2016-03-15

    The synthetic chemistry and spectroscopy of sulfur-protected gold surfaces and nanoparticles is analyzed, indicating that the electronic structure of the interface is Au(0)-thiyl, with Au(I)-thiolates identified as high-energy excited surface states. Density-functional theory indicates that it is the noble character of gold and nanoparticle surfaces that destabilizes Au(I)-thiolates. Bonding results from large van der Waals forces, influenced by covalent bonding induced through s-d hybridization and charge polarization effects that perturbatively mix in some Au(I)-thiolate character. A simple method for quantifying these contributions is presented, revealing that a driving force for nanoparticle growth is nobleization, minimizing Au(I)-thiolate involvement. Predictions that Brust-Schiffrin reactions involve thiolate anion intermediates are verified spectroscopically, establishing a key feature needed to understand nanoparticle growth. Mixing of preprepared Au(I) and thiolate reactants always produces Au(I)-thiolate thin films or compounds rather than monolayers. Smooth links to O, Se, Te, C, and N linker chemistry are established.

  11. Design and Preparation of Supported Au Catalyst with Enhanced Catalytic Activities by Rationally Positioning Au Nanoparticles on Anatase.

    Science.gov (United States)

    Wang, Liang; Wang, Hong; Rice, Andrew E; Zhang, Wei; Li, Xiaokun; Chen, Mingshu; Meng, Xiangju; Lewis, James P; Xiao, Feng-Shou

    2015-06-18

    A synergistic effect between individual components is crucial for increasing the activity of metal/metal oxide catalysts. The greatest challenge is how to control the synergistic effect to obtain enhanced catalytic performance. Through density functional theory calculations of model Au/TiO2 catalysts, it is suggested that there is strong interaction between Au nanoparticles and Ti species at the edge/corner sites of anatase, which is favorable for the formation of stable oxygen vacancies. Motivated by this theoretical analysis, we have rationally prepared Au nanoparticles attached to edge/corner sites of anatase support (Au/TiO2-EC), confirmed by their HR-TEM images. As expected, this strong interaction is well characterized by Raman, UV-visible, and XPS techniques. Very interestingly, compared with conventional Au catalysts, Au/TiO2-EC exhibits superior catalytic activity in the oxidations using O2. Our approach to controlling Au nanoparticle positioning on anatase to obtain enhanced catalytic activity offers an efficient strategy for developing more novel supported metal catalysts. PMID:26266615

  12. Thermodynamic assessment of Au-Pt system%Au-Pt二元合金的热力学评估

    Institute of Scientific and Technical Information of China (English)

    徐晓宁; 任玉平; 李长发; 李松; 秦高梧

    2012-01-01

    基于最近实验测得的Au-Pt二元体系相平衡数据,利用Calphad方法重新评估Au-Pt二元体系的热力学参数.采用亚正规溶体模型Redlich-Kister等式描述液相和面心立方相的Gibbs自由能.考虑热力学第三定律的限定,以再现相平衡数据和固相热力学性质,包括活度和混合焓,优化Au-Pt二元系统热力学参数.优化结果表明:Au-Pt合金系统的溶解度间隙边界向富Au侧偏移,其顶点位置在1200 °c,Au-56%Pt.%The thermodynamic re-assessment of Au-Pt binary system was carded out by using the Calphad method and based on the recent experimental data.The Gibbs energies of face-centred cubic and liquid phases were described by a sub-regular solution model with the Redlich-Kister equation.Much effort was taken to reproduce the phase equilibrium results and thermodynamic properties of the solid phase,including the activity and mixing enthalpy.The constraint of the third law of thermodynamics was also considered in the assessment.According to the presently assessed results,the miscibility gap region in the Au-Pt system slightly shifts to the Au-rich side,and the critical point of the miscibility gap is about 1200 °C and Au-56% Pt.

  13. A simple approach for facile synthesis of Ag, anisotropic Au and bimetallic (Ag/Au) nanoparticles using cruciferous vegetable extracts

    Energy Technology Data Exchange (ETDEWEB)

    Jacob, Jasmine; Mukherjee, Tulsi; Kapoor, Sudhir, E-mail: sudhirk@barc.gov.in

    2012-10-01

    We present a simple and straightforward approach for the synthesis and stabilization of relatively monodisperse Ag, Au and bimetallic (Ag/Au) nanoparticles by using cruciferous vegetable (green/red) extracts by simply adjusting the pH environment in the aqueous medium. The vegetable extracts act both as reducing and capping agents. The monometallic and bimetallic nanoparticles of Ag and Au so obtained were characterized by UV-visible spectroscopy, X-ray diffraction (XRD), dynamic light scattering (DLS) and transmission electron microscopy (TEM). It is shown that red cabbage extract can be used for the preparation of anisotropic Au nanoparticles. The formation of Au anisotropic nanoparticles was found to depend on a number of environmental factors, such as the pH of the reaction medium, reaction time, and initial reactant concentrations. Additionally, it is shown that these extract-stabilized Au and Ag nanoparticles can be used as a seed for preparation of bimetallic Au/Ag nanoparticles. For bimetallic alloy nanoparticles the absorption peak was observed between the two maxima of the corresponding metallic particles. The surface plasmon absorption maxima for bimetallic nanoparticles changed linearly with increasing Au mole ratio content in various alloy compositions. It has been shown that the formation of hollow Au spheres depends on the experimental conditions. - Graphical abstract: TEM image of gold nanoparticles at pH 3.27 formed by red cabbage extract. Highlights: Black-Right-Pointing-Pointer First report on the reactivity of the extracts toward metal ions using a spectrophotometric technique. Black-Right-Pointing-Pointer Red cabbage extract has better reducing properties than green cabbage extract. Black-Right-Pointing-Pointer Red cabbage extract can reduce metal ions at any pH. Black-Right-Pointing-Pointer Reduction of metal ions can have important consequences in the study of soil chemistry.

  14. A simple approach for facile synthesis of Ag, anisotropic Au and bimetallic (Ag/Au) nanoparticles using cruciferous vegetable extracts

    International Nuclear Information System (INIS)

    We present a simple and straightforward approach for the synthesis and stabilization of relatively monodisperse Ag, Au and bimetallic (Ag/Au) nanoparticles by using cruciferous vegetable (green/red) extracts by simply adjusting the pH environment in the aqueous medium. The vegetable extracts act both as reducing and capping agents. The monometallic and bimetallic nanoparticles of Ag and Au so obtained were characterized by UV–visible spectroscopy, X-ray diffraction (XRD), dynamic light scattering (DLS) and transmission electron microscopy (TEM). It is shown that red cabbage extract can be used for the preparation of anisotropic Au nanoparticles. The formation of Au anisotropic nanoparticles was found to depend on a number of environmental factors, such as the pH of the reaction medium, reaction time, and initial reactant concentrations. Additionally, it is shown that these extract-stabilized Au and Ag nanoparticles can be used as a seed for preparation of bimetallic Au/Ag nanoparticles. For bimetallic alloy nanoparticles the absorption peak was observed between the two maxima of the corresponding metallic particles. The surface plasmon absorption maxima for bimetallic nanoparticles changed linearly with increasing Au mole ratio content in various alloy compositions. It has been shown that the formation of hollow Au spheres depends on the experimental conditions. - Graphical abstract: TEM image of gold nanoparticles at pH 3.27 formed by red cabbage extract. Highlights: ► First report on the reactivity of the extracts toward metal ions using a spectrophotometric technique. ► Red cabbage extract has better reducing properties than green cabbage extract. ► Red cabbage extract can reduce metal ions at any pH. ► Reduction of metal ions can have important consequences in the study of soil chemistry.

  15. Evaluation of the Olympus AU-510 analyser.

    Science.gov (United States)

    Farré, C; Velasco, J; Ramón, F

    1991-01-01

    The selective multitest Olympus AU-510 analyser was evaluated according to the recommendations of the Comision de Instrumentacion de la Sociedad Española de Quimica Clinica and the European Committee for Clinical Laboratory Standards. The evaluation was carried out in two stages: an examination of the analytical units and then an evaluation in routine work conditions. The operational characteristics of the system were also studied.THE FIRST STAGE INCLUDED A PHOTOMETRIC STUDY: dependent on the absorbance, the inaccuracy varies between +0.5% to -0.6% at 405 nm and from -5.6% to 10.6% at 340 nm; the imprecision ranges between -0.22% and 0.56% at 405 nm and between 0.09% and 2.74% at 340 nm. Linearity was acceptable, apart from a very low absorbance for NADH at 340 nm; and the imprecision of the serum sample pipetter was satisfactory.TWELVE SERUM ANALYTES WERE STUDIED UNDER ROUTINE CONDITIONS: glucose, urea urate, cholesterol, triglycerides, total bilirubin, creatinine, phosphate, iron, aspartate aminotransferase, alanine aminotransferase and gamma-glutamyl transferase.The within-run imprecision (CV%) ranged from 0.67% for phosphate to 2.89% for iron and the between-run imprecision from 0.97% for total bilirubin to 7.06% for iron. There was no carryover in a study of the serum sample pipetter. Carry-over studies with the reagent and sample pipetters shows some cross contamination in the iron assay.

  16. Activated Dissociation of HCl on Au(111).

    Science.gov (United States)

    Shirhatti, Pranav R; Geweke, Jan; Steinsiek, Christoph; Bartels, Christof; Rahinov, Igor; Auerbach, Daniel J; Wodtke, Alec M

    2016-04-01

    We report zero-coverage reaction probabilities (S0) for HCl dissociative adsorption on Au(111) obtained by the seeded molecular beam hot-nozzle method. For measurements at normal incidence with mean translational energies ranging from 0.94 to 2.56 eV (nozzle temperatures 296 to 1060 K), S0 increased from 6 × 10(-6) to 2 × 10(-2). S0 also increased with increasing nozzle temperature for fixed incidence energy associated with the motion normal to the surface. Accounting for the influence of the vibrational state population and translational energy distributions in the incident beam, we are able to compare the experimental results to recent theoretical predictions. These calculations, performed employing 6-D quantum dynamics on an electronically adiabatic potential energy surface obtained using density functional theory at the level of the generalized gradient approximation and the static surface approximation, severely overestimate the reaction probabilities when compared with our experimental results. We discuss some possible reasons for this large disagreement. PMID:26990513

  17. De l’individu postcommuniste au citoyen

    Directory of Open Access Journals (Sweden)

    Anna Krasteva

    2009-11-01

    Full Text Available L’article analyse le paradoxe de la conception communiste du citoyen engagé : au niveau idéologique, citoyenneté et engagement sont intrinsèquement liés, au niveau politique ils sont souvent radicalement dissociés. Le citoyen communiste est plus engagé que citoyen. La citoyenneté était dépourvue de plusieurs de ses attributs : de la jouissance de la loi qui établit « l’égalité arithmétique » et minorise les maîtres ; de la citoyenneté active – civile et politique – pour ne jouir que la protection sociale ; de la participation au profit de l’appartenance. L’individu communiste était engagé, non pas parce qu’il l’avait choisi dans la liberté, mais parce qu’il n’avait pas la liberté de se désengager. L’article compare l’engagement communiste et postcommuniste en analysant le second au croisement de l’individualité et de la citoyenneté et en distinguant trois formes de désengagement – contestataire, « bonapartiste » et individualiste et trois formes d’engagement – mimétique, héroïque, civique.From the postcommunist individual to the citizenThe article analysis the paradox of the communist conception of the engaged citizen: at ideological level, citizenship and participation are closely linked; at political level, they are radically dissociated. The communist citizen is more engaged than citizen. The citizenship is deprived of several of its attributes: of the law which establishes "the arithmetic equality" and minimises the masters; of the active citizenship, civic and political, enjoying just the social one; of the participation for emphasizing on the belonging. The communist individual is engaged not because he has chosen freely to be such, but because he had not the freedom to disengage him/herself. The article compares the communist and the post communist participation analysing the latter at the intersection of individuality and citizenship and distinguishing three forms

  18. Shadowing effects on the nuclear suppression factor, RdAu, in d+Au interactions

    International Nuclear Information System (INIS)

    We explore how nuclear modifications to the nucleon parton distributions affect production of high transverse momentum hadrons in deuteron-nucleus collisions. We calculate the charged hadron spectra to leading order using standard fragmentation functions and shadowing parameterizations. We obtain the d+Au to pp ratio both in minimum bias collisions and as a function of centrality. The minimum bias results agree reasonably well with the BRAHMS data while the calculated centrality dependence underestimates the data and is a stronger function of pT than the data indicate

  19. Distributions of Charged Hadrons Associated with High Transverse Momentum Particles in pp and Au+Au Collisions at sqrt(s_NN)=200 GeV

    CERN Document Server

    Adams, J; Aggarwal, M M; Ahammed, Z; Amonett, J; Anderson, B D; Arkhipkin, D; Averichev, G S; Badyal, S K; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Bekele, S; Belaga, V V; Bellwied, R; Berger, J; Bezverkhny, B I; Bhardwaj, S; Bhati, A K; Bichsel, H; Billmeier, A; Bland, L C; Blyth, C O; Bonner, B E; Botje, M; Boucham, A; Brandin, A; Bravar, A; Cadman, R V; Cai, X Z; Caines, H; Calderón de la Barca-Sanchez, M; Carroll, J; Castillo, J; Cebra, D; Chaloupka, P; Chattopadhyay, S; Chen, H F; Chen, Y; Chernenko, S P; Cherney, M; Chikanian, A; Christie, W; Coffin, J P; Cormier, T M; Cramer, J G; Crawford, H J; Das, D; Das, S; Derevshchikov, A A; Didenko, L; Dietel, T; Dong, W J; Dong, X; Draper, J E; Du, F; Dubey, A K; Dunin, V B; Dunlop, J C; Dutta-Majumdar, M R; Eckardt, V; Efimov, L G; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Estienne, M; Fachini, P; Faine, V; Faivre, J; Fatemi, R; Filimonov, K; Filip, P; Finch, E; Fisyak, Yu; Flierl, D; Foley, K J; Fu, J; Gagliardi, C A; Gagunashvili, N; Gans, J; Ganti, M S; Gaudichet, L; Geurts, F J M; Ghazikhanian, V; Ghosh, P; González, J E; Grachov, O; Grebenyuk, O; Gronstal, S; Grosnick, D P; Guertin, S M; Sen-Gupta, A; Gutíerrez, T D; Hallman, T J; Hamed, A; Hardtke, D; Harris, J W; Heinz, M; Henry, T W; Heppelmann, S; Herston, T; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Horsley, M; Huang, H Z; Huang Sheng Li; Hughes, E; Humanic, T J; Igo, G; Ishihara, A; Jacobs, P; Jacobs, W W; Janik, M; Jiang, H; Johnson, I; Jones, P G; Judd, E G; Kabana, S; Kaplan, M; Keane, D; Khodyrev, V Yu; Kiryluk, J; Kisiel, A; Klay, J; Klein, S R; Klyachko, A; Koetke, D D; Kollegger, T; Kopytine, M; Kotchenda, L; Kovalenko, A D; Krämer, M; Kravtsov, P; Kravtsov, V I; Krüger, K; Kuhn, C; Kulikov, A I; Kumar, A; Kunde, G J; Kunz, C L; Kutuev, R K; Kuznetsov, A A; Lamont, M A C; Landgraf, J M; Lange, S; Lasiuk, B; Laue, F; Lauret, J; Lebedev, A; Lednicky, R; Le Vine, M J; Li, C; Li, Q; Lindenbaum, S J; Lisa, M A; Liu, F; Liu, L; Liu, Z; Liu, Q J; Ljubicic, T; Llope, W J; Long, H; Longacre, R S; López-Noriega, M; Love, W A; Ludlam, T; Lynn, D; Ma, J; Ma, Y G; Magestro, D; Mahajan, S; Mangotra, L K; Mahapatra, D P; Majka, R; Manweiler, R; Margetis, S; Markert, C; Martin, L; Marx, J; Matis, H S; Matulenko, Yu A; McClain, C J; McShane, T S; Meissner, F; Melnik, Yu M; Meschanin, A; Miller, M L; Milosevich, Z; Minaev, N G; Mironov, C; Mischke, A; Mishra, D; Mitchell, J; Mohanty, B; Molnár, L; Moore, C F; Mora-Corral, M J; Morozov, D A; Morozov, V; De Moura, M M; Munhoz, M G; Nandi, B K; Nayak, S K; Nayak, T K; Nelson, J M; Netrakanti, P K; Nikitin, V A; Nogach, L V; Norman, B; Nurushev, S B; Odyniec, Grazyna Janina; Ogawa, A; Okorokov, V; Oldenburg, M; Olson, D; Paic, G; Pal, S K; Panebratsev, Yu A; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Peitzmann, T; Perevozchikov, V; Perkins, C; Peryt, W; Petrov, V A; Phatak, S C; Picha, R; Planinic, M; Pluta, J; Porile, N; Porter, J; Poskanzer, A M; Potekhin, M V; Potrebenikova, E V; Potukuchi, B V K S; Prindle, D; Pruneau, C A; Putschke, J; Rai, G; Rakness, G; Raniwala, R; Raniwala, S; Ravel, O; Ray, R L; Razin, S V; Reichhold, D M; Reid, J G; Renault, G; Retière, F; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevski, O V; Romero, J L; Rose, A; Roy, C; Ruan, L J; Sahoo, R; Sakrejda, I; Salur, S; Sandweiss, J; Savin, I; Schambach, J; Scharenberg, R P; Schmitz, N; Schröder, L S; Schweda, K; Seger, J; Seyboth, P; Shahaliev, E; Shao, M; Shao, W; Sharma, M; Shestermanov, K E; Shimansky, S S; Singaraju, R N; Simon, F; Skoro, G P; Smirnov, N; Snellings, R; Sood, G; Sørensen, P; Sowinski, J; Speltz, J; Spinka, H M; Srivastava, B; Stanislaus, T D S; Stock, R; Stolpovsky, A; Strikhanov, M N; Stringfellow, B C; Struck, C; Suaide, A A P; Sugarbaker, E R; Suire, C; Sumbera, M; Surrow, B; Symons, T J M; Szanto de Toledo, A; Szarwas, P; Tai, A; Takahashi, J; Tang, A H; Thein, D; Thomas, J H; Timoshenko, S; Tokarev, M; Tonjes, M B; Trainor, T A; Trentalange, S; Tribble, R E; Tsai, O; Ullrich, T; Underwood, D G; Van Buren, G; Van der Molen, A M; Varma, R; Vasilevski, I; Vasilev, A N; Vernet, R; Vigdor, S E; Viyogi, Y P; Voloshin, S A; Vznuzdaev, M; Waggoner, W; Wang, F; Wang, G; Wang, X L; Wang, Y; Wang, Z M; Ward, H; Watson, J W; Webb, J C; Wells, R; Westfall, G D; Whitten, C; Wieman, H; Willson, R; Wissink, S W; Witt, R; Wood, J; Wu, J; Xu, N; Xu, Z; Xu, Z Z; Yamamoto, E; Yepes, P; Yurevich, V I; Yuting, B; Zanevsky, Yu V; Zhang, H; Zhang, W M; Zhang, Z P; Zhaomin, P; Zizong, Z P; Zolnierczuk, P A; Zoulkarneev, R; Zoulkarneeva, J; Zubarev, A N

    2005-01-01

    Charged hadrons in 0.15 4 GeV/c are reconstructed in pp and Au+Au collisions at sqrt(s_NN)=200 GeV. The associated multiplicity and pt magnitude sum are found to increase from pp to central Au+Au collisions. The associated pt distributions, while similar in shape on the near side, are significantly softened on the away side in central Au+Au relative to pp and not much harder than that of inclusive hadrons. The results, consistent with jet quenching, suggest that the away-side fragments approach equilibration with the medium traversed.

  20. Comparison of the space-time extent of the emission source in $d$$+$Au and Au$+$Au collisions at $\\sqrt{s_{{NN}}}=200$ GeV

    CERN Document Server

    Adare, A; Aidala, C; Ajitanand, N N; Akiba, Y; Akimoto, R; Al-Bataineh, H; Alexander, J; Alfred, M; Angerami, A; Aoki, K; Apadula, N; Aramaki, Y; Asano, H; Atomssa, E T; Averbeck, R; Awes, T C; Azmoun, B; Babintsev, V; Bai, M; Baksay, G; Baksay, L; Bandara, N S; Bannier, B; Barish, K N; Bassalleck, B; Basye, A T; Bathe, S; Baublis, V; Baumann, C; Bazilevsky, A; Beaumier, M; Beckman, S; Belikov, S; Belmont, R; Bennett, R; Berdnikov, A; Berdnikov, Y; Bhom, J H; Bickley, A A; Black, D; Blau, D S; Bok, J; Bok, J S; Boyle, K; Brooks, M L; Bryslawskyj, J; Buesching, H; Bumazhnov, V; Bunce, G; Butsyk, S; Camacho, C M; Campbell, S; Caringi, A; Chen, C -H; Chi, C Y; Chiu, M; Choi, I J; Choi, J B; Choudhury, R K; Christiansen, P; Chujo, T; Chung, P; Chvala, O; Cianciolo, V; Citron, Z; Cole, B A; del Valle, Z Conesa; Connors, M; Constantin, P; Csanád, M; Csörgő, T; Dahms, T; Dairaku, S; Danchev, I; Das, K; Datta, A; Daugherity, M S; David, G; Dayananda, M K; DeBlasio, K; Dehmelt, K; Denisov, A; Deshpande, A; Desmond, E J; Dharmawardane, K V; Dietzsch, O; Ding, L; Dion, A; Do, J H; Donadelli, M; Drapier, O; Drees, A; Drees, K A; Durham, J M; Durum, A; Dutta, D; D'Orazio, L; Edwards, S; Efremenko, Y V; Ellinghaus, F; Engelmore, T; Enokizono, A; En'yo, H; Esumi, S; Fadem, B; Feege, N; Fields, D E; Finger, M; Jr., \\,; Fleuret, F; Fokin, S L; Fraenkel, Z; Frantz, J E; Franz, A; Frawley, A D; Fujiwara, K; Fukao, Y; Fusayasu, T; Gal, C; Gallus, P; Garg, P; Garishvili, I; Ge, H; Giordano, F; Glenn, A; Gong, H; Gonin, M; Goto, Y; de Cassagnac, R Granier; Grau, N; Greene, S V; Grim, G; Perdekamp, M Grosse; Gu, Y; Gunji, T; Guragain, H; Gustafsson, H -Å; Hachiya, T; Haggerty, J S; Hahn, K I; Hamagaki, H; Hamblen, J; Han, R; Han, S Y; Hanks, J; Hartouni, E P; Hasegawa, S; Haslum, E; Hayano, R; He, X; Heffner, M; Hemmick, T K; Hester, T; Hill, J C; Hohlmann, M; Hollis, R S; Holzmann, W; Homma, K; Hong, B; Horaguchi, T; Hornback, D; Hoshino, T; Huang, J; Huang, S; Ichihara, T; Ichimiya, R; Ide, J; Ikeda, Y; Imai, K; Imazu, Y; Inaba, M; Iordanova, A; Isenhower, D; Ishihara, M; Isobe, T; Issah, M; Isupov, A; Ivanischev, D; Ivanishchev, D; Iwanaga, Y; Jacak, B V; Jeon, S J; Jezghani, M; Jia, J; Jiang, X; Jin, J; Johnson, B M; Jones, T; Joo, E; Joo, K S; Jouan, D; Jumper, D S; Kajihara, F; Kametani, S; Kamihara, N; Kamin, J; Kang, J H; Kang, J S; Kapustinsky, J; Karatsu, K; Kasai, M; Kawall, D; Kawashima, M; Kazantsev, A V; Kempel, T; Key, J A; Khachatryan, V; Khanzadeev, A; Kihara, K; Kijima, K M; Kikuchi, J; Kim, A; Kim, B I; Kim, C; Kim, D H; Kim, D J; Kim, E; Kim, E -J; Kim, H -J; Kim, M; Kim, S H; Kim, Y -J; Kim, Y K; Kinney, E; Kiriluk, K; Kiss, Á; Kistenev, E; Klatsky, J; Kleinjan, D; Kline, P; Koblesky, T; Kochenda, L; Kofarago, M; Komkov, B; Konno, M; Koster, J; Kotchetkov, D; Kotov, D; Kozlov, A; Král, A; Kravitz, A; Kunde, G J; Kurita, K; Kurosawa, M; Kwon, Y; Kyle, G S; Lacey, R; Lai, Y S; Lajoie, J G; Lebedev, A; Lee, D M; Lee, J; Lee, K; Lee, K B; Lee, K S; Lee, S H; Leitch, M J; Leite, M A L; Leitgab, M; Leitner, E; Lenzi, B; Li, X; Lichtenwalner, P; Liebing, P; Lim, S H; Levy, L A Linden; Liška, T; Litvinenko, A; Liu, H; Liu, M X; Love, B; Luechtenborg, R; Lynch, D; Maguire, C F; Makdisi, Y I; Makek, M; Malakhov, A; Malik, M D; Manion, A; Manko, V I; Mannel, E; Mao, Y; Masui, H; Matathias, F; McCumber, M; McGaughey, P L; McGlinchey, D; McKinney, C; Means, N; Meles, A; Mendoza, M; Meredith, B; Miake, Y; Mibe, T; Mignerey, A C; Mikeš, P; Miki, K; Miller, A J; Milov, A; Mishra, D K; Mishra, M; Mitchell, J T; Miyasaka, S; Mizuno, S; Mohanty, A K; Montuenga, P; Moon, H J; Moon, T; Morino, Y; Morreale, A; Morrison, D P; Moukhanova, T V; Murakami, T; Murata, J; Mwai, A; Nagamiya, S; Nagle, J L; Naglis, M; Nagy, M I; Nakagawa, I; Nakagomi, H; Nakamiya, Y; Nakamura, K R; Nakamura, T; Nakano, K; Nam, S; Nattrass, C; Netrakanti, P K; Newby, J; Nguyen, M; Nihashi, M; Niida, T; Nouicer, R; Novitzky, N; Nyanin, A S; Oakley, C; O'Brien, E; Oda, S X; Ogilvie, C A; Oka, M; Okada, K; Onuki, Y; Koop, J D Orjuela; Oskarsson, A; Ouchida, M; Ozaki, H; Ozawa, K; Pak, R; Pantuev, V; Papavassiliou, V; Park, I H; Park, J; Park, S; Park, S K; Park, W J; Pate, S F; Patel, L; Patel, M; Pei, H; Peng, J -C; Pereira, H; Perepelitsa, D V; Perera, G D N; Peresedov, V; Peressounko, D Yu; Perry, J; Petti, R; Pinkenburg, C; Pinson, R; Pisani, R P; Proissl, M; Purschke, M L; Purwar, A K; Qu, H; Rak, J; Rakotozafindrabe, A; Ravinovich, I; Read, K F; Rembeczki, S; Reygers, K; Reynolds, D; Riabov, V; Riabov, Y; Richardson, E; Riveli, N; Roach, D; Roche, G; Rolnick, S D; Rosati, M; Rosen, C A; Rosendahl, S S E; Rosnet, P; Rowan, Z; Rubin, J G; Rukoyatkin, P; Ružička, P; Sahlmueller, B; Saito, N; Sakaguchi, T; Sakashita, K; Sako, H; Samsonov, V; Sano, S; Sarsour, M; Sato, S; Sato, T; Sawada, S; Schaefer, B; Schmoll, B K; Sedgwick, K; Seele, J; Seidl, R; Semenov, A Yu; Sen, A; Seto, R; Sett, P; Sexton, A; Sharma, D; Shein, I; Shibata, T -A; Shigaki, K; Shimomura, M; Shoji, K; Shukla, P; Sickles, A; Silva, C L; Silvermyr, D; Silvestre, C; Sim, K S; Singh, B K; Singh, C P; Singh, V; Slunečka, M; Soltz, R A; Sondheim, W E; Sorensen, S P; Sourikova, I V; Sparks, N A; Stankus, P W; Stenlund, E; Stepanov, M; Stoll, S P; Sugitate, T; Sukhanov, A; Sumita, T; Sun, J; Sziklai, J; Takagui, E M; Takahara, A; Taketani, A; Tanabe, R; Tanaka, Y; Taneja, S; Tanida, K; Tannenbaum, M J; Tarafdar, S; Taranenko, A; Tarján, P; Themann, H; Thomas, D; Thomas, T L; Timilsina, A; Todoroki, T; Togawa, M; Toia, A; Tomášek, L; Tomášek, M; Torii, H; Towell, M; Towell, R; Towell, R S; Tserruya, I; Tsuchimoto, Y; Vale, C; Valle, H; van Hecke, H W; Vargyas, M; Vazquez-Zambrano, E; Veicht, A; Velkovska, J; Vértesi, R; Vinogradov, A A; Virius, M; Vrba, V; Vznuzdaev, E; Wang, X R; Watanabe, D; Watanabe, K; Watanabe, Y; Watanabe, Y S; Wei, F; Wei, R; Wessels, J; Whitaker, S; White, S N; Winter, D; Wolin, S; Wood, J P; Woody, C L; Wright, R M; Wysocki, M; Xia, B; Xie, W; Xue, L; Yalcin, S; Yamaguchi, Y L; Yamaura, K; Yang, R; Yanovich, A; Ying, J; Yokkaichi, S; Yoon, I; You, Z; Young, G R; Younus, I; Yushmanov, I E; Zajc, W A; Zelenski, A; Zhang, C; Zhou, S; Zolin, L

    2014-01-01

    Two-pion interferometry measurements in $d$$+$Au and Au$+$Au collisions at $\\sqrt{s_{{NN}}}=200$ GeV are used to extract and compare the Gaussian source radii R$_{{\\rm out}}$, R$_{{\\rm side}}$, and R$_{{\\rm long}}$, which characterize the space-time extent of the emission sources. The comparisons, which are performed as a function of collision centrality and the mean transverse momentum for pion pairs, indicate strikingly similar patterns for the $d$$+$Au and Au$+$Au systems. They also indicate a linear dependence of R$_{{\\rm side}}$ on the initial transverse geometric size $\\bar{R}$, as well as a smaller freeze-out size for the $d$$+$Au system. These patterns point to the important role of final-state rescattering effects in the reaction dynamics of $d$$+$Au collisions.

  1. Composition distributions in FePt(Au) nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Srivastava, C. [University of Alabama, Department of Metallurgical and Materials Engineering (United States); Nikles, D. E. [University of Alabama, Department of Chemistry (United States); Harrell, J. W. [University of Alabama, Department of Physics and Astronomy (United States); Thompson, G. B., E-mail: gthompson@eng.ua.ed [University of Alabama, Department of Metallurgical and Materials Engineering (United States)

    2010-08-15

    Ternary alloy FePt(Au) nanoparticles were prepared by the co-reduction of platinum(II) acetylacetonate and gold(III) acetate and the thermal decomposition of iron pentacarbonyl in hot phenyl ether in the presence of oleic acid and oleylamine ligands. This gave spherical particles with an average diameter of 4.4 nm with a range of diameters from approximately 1.6-9 nm. The as-synthesized particles had a solid solution, face-centered-cubic structure. Though the average composition of the particles was Fe{sub 44}Pt{sub 45}Au{sub 11}, individual particle analysis by Scanning Transmission Electron Microscopy-X-ray Energy Dispersive Spectroscopy showed a broad distribution in composition. In general, smaller-sized particles tended to have a lower amount of Au as compared to larger-sized particles. As the Au content increased, the ratio of Fe/Pt widened.

  2. Coexistence of multiple conformations in cysteamine monolayers on Au(111)

    DEFF Research Database (Denmark)

    Zhang, Jingdong; Bilic, A; Reimers, JR;

    2005-01-01

    The structural organization, catalytic function, and electronic properties of cysteamine monolayers on Au(111) have been addressed comprehensively by voltammetry, in situ scanning tunneling microscopy (STM) in anaerobic environment, and a priori molecular dynamics (MD) simulation and STM image si...

  3. Les immigrants dans les regions metropolitaines de recensement au Canada

    OpenAIRE

    Schellenberg, Grant

    2004-01-01

    Dans ce rapport, on examine les facteurs des immigrants dans les regions metropolitaines de recensement (RMR) au Canada, les repercussions sur les services publics offerts dans les regions urbaines et les caracteristiques de l'emploi des immigrants.

  4. EST Table: AU004617 [KAIKOcDNA[Archive

    Lifescience Database Archive (English)

    Full Text Available AU004617 ws20666 10/09/28 54 %/178 aa ref|XP_002430772.1| tyrosine-protein phosphatase corkscrew..., putative [Pediculus humanus corporis] gb|EEB18034.1| tyrosine-protein phosphatase corkscrew,

  5. Assembling Bare Au Nanoparticles at Positively Charged Templates

    Science.gov (United States)

    Wang, Wenjie; Zhang, Honghu; Kuzmenko, Ivan; Mallapragada, Surya; Vaknin, David

    2016-05-01

    In-situ X-ray reflectivity (XRR) and grazing incidence X-ray small-angle scattering (GISAXS) reveal that unfunctionalized (bare) gold nanoparticles (AuNP) spontaneously adsorb to a cationic lipid template formed by a Langmuir monolayer of DPTAP (1,2-dihexadecanoyl-3-trimethylammonium-propane) at vapor/aqueous interfaces. Analysis of the XRR yields the electron density profile across the charged-interfaces along the surface normal showing the AuNPs assemble with vertical thickness comparable to the particle size. The GISAXS analysis indicates that the adsorbed mono-particle layer exhibits short-range in-plane correlations. By contrast, single-stranded DNA-functionalized AuNPs, while attracted to the positively charged surface (more efficiently with the addition of salt to the solution), display less in-plane regular packing compared to bare AuNPs.

  6. Dynamic features of rod-shaped Au nanoclusters

    Science.gov (United States)

    So, Woong Young; Das, Anindita; Wang, Shuxin; Zhao, Shuo; Byun, Hee Young; Lee, Dana; Kumar, Santosh; Jin, Rongchao; Peteanu, Linda A.

    2015-08-01

    Gold nanoclusters hold many potential applications such as biosensing and optics due to their emission characteristics, small size, and non-toxicity. However, their low quantum yields remain problematic for further applications, and their fluorescence mechanism is still unclear. To increase the low quantum yields, various methods have been performed: doping, tuning structures, and changing number of gold atoms. In the past, most characterizations have been performed on spherical shaped nanoclusters; in this paper, several characterizations of various rod-shaped Au nanoclusters specifically on Au25 are shown. It has been determined that the central gold atom in Au25 nano-rod is crucial in fluorescence. Furthermore, single molecule analysis of silver doped Au25 nano-rod revealed that it has more photo-stability than conjugated polymers and quantum dots.

  7. Prolonged reorganization of thiol-capped Au nanoparticles layered structures

    Directory of Open Access Journals (Sweden)

    Sarathi Kundu

    2013-09-01

    Full Text Available Prolonged reorganization behaviour of mono-, di-, tri- and multi-layer films of Au nanoparticles prepared by Langmuir-Blodgett method on hydrophobic Si(001 substrates have been studied by using X-ray scattering techniques. Out-of-plane study shows that although at the initial stage the reorganization occurs through the compaction of the films keeping the layered structure unchanged but finally all layered structures modify to monolayer structure. Due to this reorganization the Au density increases within the nanometer thick films. In-plane study shows that inside the reorganized films Au nanoparticles are distributed randomly and the particle size modifies as the metallic core of Au nanoparticles coalesces.

  8. Ordered Au Nanodisk and Nanohole Arrays: Fabrication and Applications

    KAUST Repository

    Zheng, Yue Bing

    2010-01-01

    We have utilized nanosphere lithography (NSL) to fabricate ordered Au nanodisk and nanohole arrays on substrates and have studied the localized surface plasmon resonance (LSPR) of the arrays. Through these investigations, we demonstrate that the angle- dependent behavior of the LSPR in the Au nanodisk arrays enables real-time observation of exciton-plasmon couplings. In addition, we show that the NSL-fabricated Au nanohole arrays can be applied as templates for patterning micro-/nanoparticles under capillary force. The unique structural and plasmonic characteristics of the Au nanodisk and nano- hole arrays, as well as the low-cost and high-throughput NSL-based nanofabrication technique, render these arrays excellent platforms for numerous engineering applications. © 2010 by ASME.

  9. Ethylene binding to Au/Cu alloy nanoparticles

    Science.gov (United States)

    Gammage, Michael D.; Stauffer, Shannon; Henkelman, Graeme; Becker, Michael F.; Keto, John W.; Kovar, Desiderio

    2016-11-01

    Weak chemisorption of ethylene has been shown to be an important characteristic in the use of metals for the separation of ethylene from ethane. Previously, density functional theory (DFT) has been used to predict the binding energies of various metals and alloys, with Ag having the lowest chemisorption energy amongst the metals and alloys studied. Here Au/Cu alloys are investigated by a combination of DFT calculations and experimental measurements. It is inferred from experiments that the binding energy between a Au/Cu alloy and ethylene is lower than to either of the pure metals, and DFT calculations confirm that this is the case when Au segregates to the particle surface. Implications of this work suggest that it may be possible to further tune the binding energy with ethylene by compositional and morphological control of films produced from Au-surface segregated alloys.

  10. Cent ans d'aller au cinéma

    OpenAIRE

    Arnaud, Pierre,; Augier, Agnès; Augros, Joël; Berthomé, Jean-Pierre; Bertrand, Claude-Jean; Bordat, Francis; Bosséno, Christian-Marc; Dean, John; Etcheverry, Michel; Frey, Nicole Vigouroux; Gomery, Douglas; Masson, Alain; Muraire, André

    2013-01-01

    Aux Etats-Unis plus manifestement encore qu’en Europe, « aller au cinéma » a recouvert des réalités extraordinairement diverses. « Aller au cinéma », en 1902, dans un Hale’s Tours and Scenes of the World n’a rien à voir avec « aller au cinéma » dans un nickelodeon de 1908 ou dans un picture palace de 1925. « Aller au cinéma » dans les années de la Dépression, quand se généralisent les doubles programmes, les primes de fidélité et les loteries, et quand les chômeurs viennent dormir, sinon rêve...

  11. Assembling Bare Au Nanoparticles at Positively Charged Templates

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Wenjie; Zhang, Honghu; Kuzmenko, Ivan; Mallapragada, Surya; Vaknin, David

    2016-05-26

    In-situ X-ray reflectivity (XRR) and grazing incidence X-ray small-angle scattering (GISAXS) reveal that unfunctionalized (bare) gold nanoparticles (AuNP) spontaneously adsorb to a cationic lipid template formed by a Langmuir monolayer of DPTAP (1,2-dihexadecanoyl-3-trimethylammonium-propane) at vapor/aqueous interfaces. Analysis of the XRR yields the electron density profile across the chargedinterfaces along the surface normal showing the AuNPs assemble with vertical thickness comparable to the particle size. The GISAXS analysis indicates that the adsorbed mono-particle layer exhibits shortrange in-plane correlations. By contrast, single-stranded DNA-functionalized AuNPs, while attracted to the positively charged surface (more efficiently with the addition of salt to the solution), display less in-plane regular packing compared to bare AuNPs.

  12. Electrochemical Tuning of the Dielectric Function of Au Nanoparticles

    OpenAIRE

    Brown, Ana M.; Sheldon, Matthew T.; Atwater, Harry A.

    2015-01-01

    The tunable dielectric response of Au nanoparticles under electrochemical bias can be interpreted in terms of changes in the surface charge density, surface damping, and the near-surface volume fraction of the nanoparticles that experience a modified dielectric function, as well as changes in the index of refraction of the surrounding electrolyte medium. Using experimental bias-dependent extinction measurements, we derive a potential-dependent dielectric function for Au nanoparticles that acc...

  13. Surface Crystallization in a Liquid AuSi Alloy

    OpenAIRE

    Shpyrko, Oleg G.; Streitel, Reinhard; Balagurusamy, V. S. K.; Grigoriev, Alexei Y.; Deutsch, Moshe; Ocko, Benjamin M; Meron, Mati; Lin, Binhua; Pershan, Peter S.

    2006-01-01

    X-ray measurements reveal a crystalline monolayer at the surface of the eutectic liquid Au_{82}Si_{18}, at temperatures above the alloy's melting point. Surface-induced atomic layering, the hallmark of liquid metals, is also found below the crystalline monolayer. The layering depth, however, is threefold greater than that of all liquid metals studied to date. The crystallinity of the surface monolayer is notable, considering that AuSi does not form stable bulk crystalline phases at any concen...

  14. Wetting of Au and Ag particles on monocrystalline graphite substrates

    Institute of Scientific and Technical Information of China (English)

    Joonho Lee; Toshihiro Tanaka; Kazufumi Seo; Nobumitsu Hirai; Jung-Goo Lee; Hirotaro Mori

    2006-01-01

    The wetting behavior of Au and Ag particles on a monocrystalline graphite substrate was investigated using the microscopic sessile drop method under a purified Ar atmosphere at 1300 K. The measured contact angles of the liquid Au and Ag on monocrystalline graphite substrates of (0001) face were 129° and 124°, respectively. It is believed that the interaction at the interface is dominated by the physical bonding (van der Waal's interaction).

  15. Study on antibacterial activity of chemically synthesized PANI-Ag-Au nanocomposite

    Energy Technology Data Exchange (ETDEWEB)

    Boomi, Pandi [Department of Industrial Chemistry, School of Chemical Sciences, Alagappa University, Karaikudi 630 003, Tamil Nadu (India); Prabu, Halliah Gurumallesh, E-mail: hgprabu2010@gmail.com [Department of Industrial Chemistry, School of Chemical Sciences, Alagappa University, Karaikudi 630 003, Tamil Nadu (India); Manisankar, Paramasivam [Department of Industrial Chemistry, School of Chemical Sciences, Alagappa University, Karaikudi 630 003, Tamil Nadu (India); Ravikumar, Sundaram [Department of Oceanography and Coastal Area Studies, School of Marine Sciences, Alagappa University, Thondi Campus 623 409, Tamil Nadu (India)

    2014-05-01

    Graphical abstract: - Highlights: • New method of synthesizing PANI-Ag-Au nanocomposite. • Surface Plasmon resonance and formation of composite at nano level were analyzed. • HR-TEM study revealed uniform distribution of nanoparticles. • PANI-Ag-Au nanocomposite exhibited good antibacterial activity. - Abstract: Pristine polyaniline (PANI), PANI-Ag, PANI-Au and PANI-Ag-Au nanocomposites have been successfully synthesized by chemical oxidative polymerization method using aniline as monomer, ammonium persulphate as oxidant and metal (Ag, Au and Ag-Au) colloids. UV-Vis analysis exhibited surface Plasmon resonances of Ag, Au, Ag-Au nanoparticles. FT-IR spectra revealed the shift in peak position of N-H stretching. X-ray diffraction (XRD) results confirm the presence of Ag, Au and Au-Ag nanoparticles. HR-TEM images show nanosizes of Ag, Au, Ag-Au and the incorporation of such nanoparticles into the PANI matrix. Pristine PANI, PANI-Ag, PANI-Au and PANI-Ag-Au nanocomposites were tested for antibacterial activity by agar well diffusion method. PANI-Ag-Au nanocomposite exhibited higher antibacterial activity against both gram-positive [Streptococcus sp. (MTCC 890), Staphylococcus sp. (MTCC 96)] and gram-negative bacteria [Escherichia coli (MTCC 1671) and Klebsiella sp. (MTCC 7407)] when compared with PANI-Ag nanocomposite, PANI-Au nanocomposite and pristine PANI. The novelty of this study is the polymer-bimetal synthesis and its antibacterial potential.

  16. Formation, Migration, and Reactivity of Au-CO Complexes on Gold Surfaces.

    Science.gov (United States)

    Wang, Jun; McEntee, Monica; Tang, Wenjie; Neurock, Matthew; Baddorf, Arthur P; Maksymovych, Petro; Yates, John T

    2016-02-10

    We report experimental as well as theoretical evidence that suggests Au-CO complex formation upon the exposure of CO to active sites (step edges and threading dislocations) on a Au(111) surface. Room-temperature scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy, transmission infrared spectroscopy, and density functional theory calculations point to Au-CO complex formation and migration. Room-temperature STM of the Au(111) surface at CO pressures in the range from 10(-8) to 10(-4) Torr (dosage up to 10(6) langmuir) indicates Au atom extraction from dislocation sites of the herringbone reconstruction, mobile Au-CO complex formation and diffusion, and Au adatom cluster formation on both elbows and step edges on the Au surface. The formation and mobility of the Au-CO complex result from the reduced Au-Au bonding at elbows and step edges leading to stronger Au-CO bonding and to the formation of a more positively charged CO (CO(δ+)) on Au. Our studies indicate that the mobile Au-CO complex is involved in the Au nanoparticle formation and reactivity, and that the positive charge on CO increases due to the stronger adsorption of CO at Au sites with lower coordination numbers. PMID:26754257

  17. Structural and dynamical properties of liquid Al-Au alloys

    Science.gov (United States)

    Peng, H. L.; Voigtmann, Th.; Kolland, G.; Kobatake, H.; Brillo, J.

    2015-11-01

    We investigate temperature- and composition-dependent structural and dynamical properties of Al-Au melts. Experiments are performed to obtain accurate density and viscosity data. The system shows a strong negative excess volume, similar to other Al-based binary alloys. We develop a molecular-dynamics (MD) model of the melt based on the embedded-atom method (EAM), gauged against the available experimental liquid-state data. A rescaling of previous EAM potentials for solid-state Au and Al improves the quantitative agreement with experimental data in the melt. In the MD simulation, the admixture of Au to Al can be interpreted as causing a local compression of the less dense Al system, driven by less soft Au-Au interactions. This local compression provides a microscopic mechanism explaining the strong negative excess volume of the melt. We further discuss the concentration dependence of self- and interdiffusion and viscosity in the MD model. Al atoms are more mobile than Au, and their increased mobility is linked to a lower viscosity of the melt.

  18. Surface segregation phenomena in extended and nanoparticle surfaces of Cu-Au alloys

    Science.gov (United States)

    Li, Jonathan; Wang, Guofeng; Zhou, Guangwen

    2016-07-01

    Using density functional theory (DFT) and Monte Carlo (MC) simulations, we studied the surface segregation phenomena of Au atoms in the extended and nanoparticle surfaces of Cu-Au alloys. Our MC simulations predicted significant Au enrichment in the outermost layer of (111) and (100) extended surfaces, and Au enrichment in the two outermost layers of (110) extended surfaces. The equilibrium Cu-Au nanoparticles were predicted to develop into an Au-enriched shell structure, where Au atoms preferably segregate to the (100) facets while Cu atoms are mainly located on the (111) facet of the nanoparticles. Our simulation predictions agree with experimental measurements.

  19. Rapidity dependency of (Anti)-deuteron Coalescence in Au-Au collisions

    Science.gov (United States)

    Murray, Michael

    2009-05-01

    The coalescence of protons and neutrons into deuterons is sensitive to the space-time extent of the baryon freeze-out region. The coalescence parameter and the phase space density recast the information contained in the proton and deuteron spectra into ``chemical" and ``dynamic" terms. The phase space density is sensitive to the chemical potential and the temperature of the system. The coalescence parameter B2 can be interpreted in terms of a ``volume of homogeniety" which depends upon the temperature of the system and the radial flow. The large rapidity and pT coverage with good particle identification of the BRAHMS spectrometers allow us to measure the rapidity dependence of the volume, which is proportional to 1/B2, and the phase space density of the (anti)-proton source for central Au+Au collisions. We find that B2(pT) is almost independent of rapidity and beam energy. Interpreting 1/B2 as a volume gives numbers that are very close to HBT data and a size which steadily drops with pT. We find that B2(pT) is the same for protons and antiprotons. The phase space density has a weak rapidity dependence but varies rapidily with energy. These results in conjunction with other forward rapidity data start to give us a picture of the longitudinal evolution of the source at RHIC energies. Supported by NSF CAREER award 0449913

  20. A first look at Au + Au collisions at RHIC energies using the PHOBOS detector

    Indian Academy of Sciences (India)

    Birger Back; M D Baker; D S Barton; R R Betts; R Bindel; A Budzanowski; W Busza; A Carroll; J Corbo; M P Decowski; E Garcia; N George; K Gulbrandsen; S Gushue; C Halliwell; J Hamblen; G A Heintzelman; C Henderson; D Hicks; D J Hofman; R Hollis; R Holyńiski; B Holzman; A Iordanova; E Johnson; J L Kane; J Katzy; N Khan; W Kucewicz; P Kulinich; C M Kuo; W T Lin; S Manly; D McLeod; J Michalowski; A C Mignerey; J Mülmenstädt; R Nouicer; A Olszewski; R Pak; I C Park; H Pernegger; M Rafelski; M Rbeiz; C Reed; L P Remsberg; M Reuter; C Roland; G Roland; L Rosenberg; J Sagerer; P Sarin; P Sawicki; W Skulski; S G Steadman; P Steinberg; G S F Stephans; M Stodulski; A Sukhanov; J-L Tang; R Teng; A Trzupek; C Vale; G J van Nieuwenhuizen; R Verdier; B Wadsworth; F L H Wolfs; B Wosiek; K Woźniak; A H Wuosmaa; B Wyslouch

    2003-05-01

    The PHOBOS detector has been used to study Au + Au collisions at $\\sqrt{S_{NN}}=56$, 130, and 200 GeV. Several global observables have been measured and the results are compared with theoretical models. These observables include the charged-particle multiplicity measured as a function of beam energy, pseudo-rapidity, and centrality of the collision. A unique feature of the PHOBOS detector is its almost complete angular coverage such that these quantities can be studied over a pseudo-rapidity interval of ||≤ 5.4. This allows for an almost complete integration of the total charged particle yield, which is found to be about $N^{\\text{tot}}_{\\text{ch}}=4500± 470$ at $\\sqrt{S_{NN}}=130$ GeV and $N^{\\text{tot}}_{\\text{ch}}=5300± 530$ at $\\sqrt{S_{NN}}$ GeV. The ratio of anti-particles to particles emitted in the mid-rapidity region has also been measured using the PHOBOS magnetic spectrometer. Of particular interest is the ratio of anti-protons to protons in the mid-rapidity region, which was found to be $\\overline{p}/p= 0.6± 0.04$(stat) ± 0.06(syst) at $\\sqrt{S_{NN}}=130$ GeV. This high value suggests that an almost baryon-free region has been produced in the collisions.

  1. Thermal Description of Particle Production in Au-Au Collisions at STAR Energies

    CERN Document Server

    Tawfik, A

    2013-01-01

    The hadron ratios measured in central Au-Au collisions are analysed by means of Hadron Resonance Gas (HRG) model over a wide range of nucleon-nucleon center-of-mass energies ranging from 7.7 to 200 GeV as offered by the STAR Beam Energy Scan I (BES-I). We restrict the discussion on STAR BES-I, because of large statistics and over all homogeneity of STAR measurements (one detector) against previous experiments. Over the last three decades, various heavy-ion experiments utilizing different detectors (different certainties) have been carried out. Regularities in produced particles at different energies haven been studied. The temperature and baryon chemical potential are deduced from fits of experimental ratios to thermal model calculations assuming chemical equilibrium. We find that the resulting freeze-out parameters using single hard-core value and point-like constituents of HRG are identical. This implies that the excluded-volume comes up with no effect on the extracted parameters. We compare the results wit...

  2. Azimuthal anisotropy in U+U and Au+Au collisions at RHIC

    CERN Document Server

    Adamczyk, L; Agakishiev, G; Aggarwal, M M; Ahammed, Z; Alekseev, I; Alford, J; Aparin, A; Arkhipkin, D; Aschenauer, E C; Averichev, G S; Bairathi, V; Banerjee, A; Bellwied, R; Bhasin, A; Bhati, A K; Bhattarai, P; Bielcik, J; Bielcikova, J; Bland, L C; Bordyuzhin, I G; Bouchet, J; Brandin, A V; Bunzarov, I; Butterworth, J; Caines, H; Sánchez, M Calderón de la Barca; Campbell, J M; Cebra, D; Cervantes, M C; Chakaberia, I; Chaloupka, P; Chang, Z; Chattopadhyay, S; Chen, J H; Chen, X; Cheng, J; Cherney, M; Christie, W; Contin, G; Crawford, H J; Das, S; De Silva, L C; Debbe, R R; Dedovich, T G; Deng, J; Derevschikov, A A; di Ruzza, B; Didenko, L; Dilks, C; Dong, X; Drachenberg, J L; Draper, J E; Du, C M; Dunkelberger, L E; Dunlop, J C; Efimov, L G; Engelage, J; Eppley, G; Esha, R; Evdokimov, O; Eyser, O; Fatemi, R; Fazio, S; Federic, P; Fedorisin, J; Feng, Z; Filip, P; Fisyak, Y; Flores, C E; Fulek, L; Gagliardi, C A; Garand, D; Geurts, F; Gibson, A; Girard, M; Greiner, L; Grosnick, D; Gunarathne, D S; Guo, Y; Gupta, A; Gupta, S; Guryn, W; Hamad, A; Hamed, A; Haque, R; Harris, J W; He, L; Heppelmann, S; Hirsch, A; Hoffmann, G W; Hofman, D J; Horvat, S; Huang, B; Huang, H Z; Huang, X; Huck, P; Humanic, T J; Igo, G; Jacobs, W W; Jang, H; Jiang, K; Judd, E G; Kabana, S; Kalinkin, D; Kang, K; Kauder, K; Ke, H W; Keane, D; Kechechyan, A; Khan, Z H; Kikola, D P; Kisel, I; Kisiel, A; Kochenda, L; Koetke, D D; Kollegger, T; Kosarzewski, L K; Kraishan, A F; Kravtsov, P; Krueger, K; Kulakov, I; Kumar, L; Kycia, R A; Lamont, M A C; Landgraf, J M; Landry, K D; Lauret, J; Lebedev, A; Lednicky, R; Lee, J H; Li, X; Li, Z M; Li, Y; Li, W; Li, C; Lisa, M A; Liu, F; Ljubicic, T; Llope, W J; Lomnitz, M; Longacre, R S; Luo, X; Ma, G L; Ma, R; Ma, Y G; Ma, L; Magdy, N; Majka, R; Manion, A; Margetis, S; Markert, C; Masui, H; Matis, H S; McDonald, D; Meehan, K; Minaev, N G; Mioduszewski, S; Mishra, D; Mohanty, B; Mondal, M M; Morozov, D A; Mustafa, M K; Nandi, B K; Nasim, Md; Nayak, T K; Nigmatkulov, G; Nogach, L V; Noh, S Y; Novak, J; Nurushev, S B; Odyniec, G; Ogawa, A; Oh, K; Okorokov, V; Olvitt, D; Page, B S; Pak, R; Pan, Y X; Pandit, Y; Panebratsev, Y; Pawlik, B; Pei, H; Perkins, C; Peterson, A; Pile, P; Planinic, M; Pluta, J; Poljak, N; Poniatowska, K; Porter, J; Posik, M; Poskanzer, A M; Putschke, J; Qiu, H; Quintero, A; Ramachandran, S; Raniwala, R; Raniwala, S; Ray, R L; Ritter, H G; Roberts, J B; Rogachevskiy, O V; Romero, J L; Roy, A; Ruan, L; Rusnak, J; Rusnakova, O; Sahoo, N R; Sahu, P K; Sakrejda, I; Salur, S; Sandweiss, J; Sarkar, A; Schambach, J; Scharenberg, R P; Schmah, A M; Schmidke, W B; Schmitz, N; Seger, J; Seyboth, P; Shah, N; Shahaliev, E; Shanmuganathan, P V; Shao, M; Sharma, M K; Sharma, B; Shen, W Q; Shi, S S; Shou, Q Y; Sichtermann, E P; Sikora, R; Simko, M; Skoby, M J; Smirnov, N; Smirnov, D; Song, L; Sorensen, P; Spinka, H M; Srivastava, B; Stanislaus, T D S; Stepanov, M; Stock, R; Strikhanov, M; Stringfellow, B; Sumbera, M; Summa, B; Sun, Z; Sun, X M; Sun, Y; Sun, X; Surrow, B; Svirida, N; Szelezniak, M A; Tang, Z; Tang, A H; Tarnowsky, T; Tawfik, A; Thomas, J H; Timmins, A R; Tlusty, D; Tokarev, M; Trentalange, S; Tribble, R E; Tribedy, P; Tripathy, S K; Trzeciak, B A; Tsai, O D; Ullrich, T; Underwood, D G; Upsal, I; Van Buren, G; van Nieuwenhuizen, G; Vandenbroucke, M; Varma, R; Vasiliev, A N; Vertesi, R; Videbæk, F; Viyogi, Y P; Vokal, S; Voloshin, S A; Vossen, A; Wang, G; Wang, H; Wang, J S; Wang, Y; Wang, F; Webb, J C; Webb, G; Wen, L; Westfall, G D; Wieman, H; Wissink, S W; Witt, R; Wu, Y F; Xiao, Z G; Xie, W; Xin, K; Xu, Y F; Xu, Q H; Xu, H; Xu, N; Xu, Z; Yang, Y; Yang, C; Yang, S; Yang, Q; Ye, Z; Yepes, P; Yi, L; Yip, K; Yoo, I -K; Yu, N; Zbroszczyk, H; Zha, W; Zhang, J B; Zhang, Z; Zhang, J; Zhang, S; Zhang, X P; Zhang, Y; Zhao, J; Zhong, C; Zhou, L; Zhu, X; Zoulkarneeva, Y; Zyzak, M

    2015-01-01

    Collisions between prolate uranium nuclei are used to study how particle production and azimuthal anisotropies depend on initial geometry in heavy-ion collisions. We report the two- and four-particle cumulants, $v_2\\{2\\}$ and $v_2\\{4\\}$, for charged hadrons from U+U collisions at $\\sqrt{s_{\\rm NN}}$ = 193 GeV and Au+Au collisions at $\\sqrt{s_{\\rm NN}}$ = 200 GeV. Nearly fully overlapping collisions are selected based on the amount of energy deposited by spectators in the STAR Zero Degree Calorimeters (ZDCs). Within this sample, the observed dependence of $v_2\\{2\\}$ on multiplicity demonstrates that ZDC information combined with multiplicity can preferentially select different overlap configurations in U+U collisions. An initial-state model with gluon saturation describes the slope of $v_2\\{2\\}$ as a function of multiplicity in central collisions better than one based on Glauber with a two-component multiplicity model.

  3. Bimodality in binary Au + Au collisions from 60 to 100 MeV/u

    International Nuclear Information System (INIS)

    The deexcitation of quasi-projectiles (QP) released in binary Au on Au collisions as been studied from 60 to 100 MeV/u. Bimodality between two different decay patterns has been observed for intermediate violence collisions. The main experimental result is that the system jumps from one mode to the other on a narrow range of energy deposit and/or impact parameter. The sorting of the events (according to the violence of the collision) has been provided by the perpendicular energy of the light charged particles emitted on the quasi-target side. Such a sorting prevents spurious autocorrelation effects between the sorting variable and the observed mechanism. The two modes of the QP decay correspond on the one side to residue or fission fragments production, and on the other side to the multifragmentation channel. A detailed study has been performed in order to try to establish the origin of the observed bimodality in disentangling dynamical or geometrical effects from bulk matter properties linked with a liquid-gas type phase transition. The whole set of data is coherent with a dominant role of the deposited excitation energy as it is expected from theoretical arguments.(lattice gas model) in the framework of a liquid-gas phase transition picture. (authors)

  4. Phospholipid Encapsulated AuNR@Ag/Au Nanosphere SERS Tags with Environmental Stimulus Responsive Signal Property.

    Science.gov (United States)

    Su, Xueming; Wang, Yunqing; Wang, Wenhai; Sun, Kaoxiang; Chen, Lingxin

    2016-04-27

    Surface-enhanced Raman scattering (SERS) tags draw much attention due to the ultrasensitivity and multiplex labeling capability. Recently, a new kind of SERS tags was rationally designed by encapsulating metal nanoparticles with phospholipid bilayers, showing great potential in theranostics. The lipid bilayer coating confers biocompatibility and versatility to changing surface chemistry of the tag; however, its "soft" feature may influence SERS signal stability, which is rarely investigated. Herein, we prepared phospholipid-coated AuNR@Ag/Au nanosphere SERS tags by using three different kinds of Raman reporters, i.e., thio-containing 4-nitrothiophenol (NT), nitrogen-containing hydrophobic chromophore cyanine 7 monoacid (Cy7), and alkyl chain-chromophore conjugate 1,1'-dioctadecyl-3,3,3',3'-tetramethylindodicarbocyanine (DiD). It was found that signal responses were different upon additional stimulation which the tags may encounter in theranostic applications including the presence of detergent Triton X-100, lipid membrane, and photothermal treatment. Living-cell imaging also showed signal changing distinction. The different SERS signal performances were attributed to the different Raman reporter releasing behaviors from the tags. This work revealed that Raman reporter structure determined signal stability of lipid-coated SERS tags, providing guidance for the design of stimulus responsive tags. Moreover, it also implied the potential of SERS technique for real time drug release study of lipid based nanomedicine. PMID:27052206

  5. Entropy in central Au+Au reactions between 100 and 400{ital A} MeV

    Energy Technology Data Exchange (ETDEWEB)

    Dzelalija, M.; Cindro, N.; Basrak, Z.; Caplar, R.; Hoelbling, S.; Bini, M.; Maurenzig, P.R.; Olmi, A.; Pasquali, G.; Poggi, G.; Taccetti, N.; Cerruti, C.; Coffin, J.P.; Dona, R.; Fintz, P.; Guillaume, G.; Houari, A.; Jundt, F.; Kuhn, C.; Rami, F.; Tezkratt, R.; Wagner, P.; Biegansky, J.; Kotte, R.; Moesner, J.; Neubert, W.; Wohlfarth, D.; Alard, J.P.; Amouroux, V.; Bastid, N.; Berger, L.; Belayev, I.; Boussange, S.; Buta, A.; Dupieux, P.; Eroe, J.; Fodor, Z.; Fraysse, L.; Gobbi, A.; Herrmann, N.; Hildenbrand, K.D.; Ibnouzahir, M.; Kecskemeti, J.; Koncz, P.; Korchagin, Y.; Kraemer, M.; Lebedev, A.; Legrand, I.; Manko, V.; Mgebrishvili, G.; Moisa, D.; Montarou, G.; Montbel, I.; Pelte, D.; Petrovici, M.; Pras, P.; Ramillien, V.; Reisdorf, W.; Schuell, D.; Seres, Z.; Sikora, B.; Simion, V.; Smolyankin, S.; Sodan, U.; Trzaska, M.; Vasiliev, M.A.; Wessels, J.P.; Wienold, T.; Wilhelmi, Z.; Zhilin, A.V. [Institute for Physics and Nuclear Engineering, Bucharest (Romania)]|[Central Research Institute for Physics, Budapest (Hungary)]|[Laboratoire de Physique Corpusculaire, Clermont-Ferrand (France)]|[Gesellschaft fuer Schwerionenforschung, Darmstadt (Germany)]|[I.N.F.N. and University of Florence, Florence (Italy)]|[Physikalisches Institut der Universitaet Heidelberg, Heidelberg (Germany)]|[Institute for Experimental and Theoretical Physics, Moscow (Russian Federation)]|[Kurchatov Institute for Atomic Energy, Moscow (Russian Federation)]|[Forschungzentrum, Rossendorf (Germany)]|[Department of Physics, University of Split, Split (Croatia)]|[Centre de Recherches Nucleaires, IN2P3-CNRS, Universite Louis Pasteur, Strasbourg (France)]|[Institute of Experimental Physics, Warsaw University, Warsaw (Poland)]|[Rudjer Boskovic Institute, Zagreb (Croatia)

    1995-07-01

    The ratio of the total charge bound in fragments with {ital Z} between 2 and 15 to the hydrogen yield, ({ital tsum}{sub 2}{sup 15}{ital M}{sub {ital i}{ital Z}{ital i}})/{ital M}{sub {ital H}}, has been measured, and the neutron-to-proton ratio {ital n}/{ital p} has been estimated from the data of central Au + Au reactions between 100 and 400{ital A} MeV, measured with the phase I setup of the detector system FOPI and GSI, Darmstadt, in the polar-angle range between 7{degree} and 30{degree}. These two quantities were used to determine the entropy per nucleon {ital S}/{ital A} by comparing them with the predictions of the FREESCO code. The analysis allows the simulataneous extraction of the values of the baryonic entropy, temperature, and collective flow. The extracted values are in good agreement with the values obtained in earlier FOPI studies, and, for the baryonic entropy, with recent hydrodynamic calculations.

  6. Shape of collective flow in highly central Au(150 A MeV)+Au collisions

    Energy Technology Data Exchange (ETDEWEB)

    Roy, C. [Universite Louis Pasteur, Strasbourg (France). Centre de Recherches Nucl.; Kuhn, C. [Universite Louis Pasteur, Strasbourg (France). Centre de Recherches Nucl.; Coffin, J.P. [Universite Louis Pasteur, Strasbourg (France). Centre de Recherches Nucl.; Crochet, P. [Universite Louis Pasteur, Strasbourg (France). Centre de Recherches Nucl.; Fintz, P. [Universite Louis Pasteur, Strasbourg (France). Centre de Recherches Nucl.; Guillaume, G. [Universite Louis Pasteur, Strasbourg (France). Centre de Recherches Nucl.; Jundt, F. [Universite Louis Pasteur, Strasbourg (France). Centre de Recherches Nucl.; Maazouzi, C. [Universite Louis Pasteur, Strasbourg (France). Centre de Recherches Nucl.; Rami, F. [Universite Louis Pasteur, Strasbourg (France). Centre de Recherches Nucl.; Tizniti, L. [Universite Louis Pasteur, Strasbourg (France). Centre de Recherches Nucl.; Wagner, P. [Universite Louis Pasteur, Strasbourg (France). Centre de Recherches Nucl.; Alard, J.P.; Amouroux, V.; Basrak, Z.; Bastid, N.; Belyaev, I.; Best, D.; Biegansky, J.; Buta, A.; Caplar, R.; Cindro, N.; Dona, R.; Dupieux, P.; Dzelalija, M.; Fan, Z.G.; Fodor, Z.; Fraysse, L.; Gobbi, A.; Herrmann, N.; Hildenbrand, K.D.; Hoelbling, S.; Hong, B.; Jeong, S.C.; Kecskemeti, J.; Kirejczyk, M.; Koncz, P.; Korchagin, Y.; Kotte, R.; Lebedev, A.; Legrand, I.; Leifels, Y.; Manko, V.; Mgebrishvili, G.; Moisa, D.; Moesner, J.; Neubert, W.; Pelte, D.; Petrovici, M.; Pinkenburg, C.; Pras, P.; Reisdorf, W.; Ritman, J.L.; Sadchikov, A.G.; Schuell, D.; Seres, Z.; Sikora, B.; Simion, V.; Smolyankin, V.; Sodan, U.; Trzaska, M.; Vasiliev, M.; Wang, G.S.; Wessels, J.P.; Wienold, T.; Wohlfarth, D.; Zhilin, A.; Konopka, J.; Stoecker, H.

    1997-06-01

    Using the FOPI facility at GSI, charged particles (1{<=}Z{<=}6) produced in the Au(150 A MeV)+Au reaction have been measured at laboratory angles 1.2{sup 0}<{Theta}{sub lab}<30{sup 0}. Highly central collisions have been selected with two criteria, both dealing with the longitudinal and transverse degrees of freedom of the reaction. The relevance of this selection method is supported by QMD calculations which indicate that such criteria are able to select mean impact parameters less than 2 fm. Bias effects introduced by the criteria have been evaluated. The centre-of-mass polar angle distributions of low energy clusters emitted in these central collisions, have been extracted: the intensity ratio deduced for a transverse to longitudinal emission is found to be R=1.4{sup +0.2}{sub -0.4}. Model comparisons using QMD are presented. The value of R appears to depend sensitively on the nucleon-nucleon cross section, {sigma}{sub nn}. Within this model, a value of {sigma}{sub nn}=25{+-}5 mb is derived. (orig.). With 2 figs.

  7. Thermal photon production in Au + Au collisions: Viscous corrections in two different hydrodynamic formalisms

    Energy Technology Data Exchange (ETDEWEB)

    Peralta-Ramos, J., E-mail: jperalta@ift.unesp.b [Instituto de Fisica Teorica, Universidade Estadual Paulista, Rua Doutor Bento Teobaldo Ferraz 271, Bloco II, 01140-070 Sao Paulo (Brazil); Nakwacki, M.S., E-mail: sole@iafe.uba.a [Instituto de Astronomia, Geofisica e Ciencias Atmosfericas, Universidade de Sao Paulo, Rua do Matao 1226, Cidade Universitaria, 05508-090 Sao Paulo (Brazil)

    2011-02-01

    We calculate the spectra of produced thermal photons in Au + Au collisions taking into account the nonequilibrium contribution to photon production due to finite shear viscosity. The evolution of the fireball is modeled by second-order as well as by divergence-type 2+1 dissipative hydrodynamics, both with an ideal equation of state and with one based on Lattice QCD that includes an analytical crossover. The spectrum calculated in the divergence-type theory is considerably enhanced with respect to the one calculated in the second-order theory, the difference being entirely due to differences in the viscous corrections to photon production. Our results show that the differences in hydrodynamic formalisms are an important source of uncertainty in the extraction of the value of {eta}/s from measured photon spectra. The uncertainty in the value of {eta}/s associated with different hydrodynamic models used to compute thermal photon spectra is larger than the one occurring in matching hadron elliptic flow to RHIC data.

  8. Bimodality in binary Au + Au collisions from 60 to 100 MeV/u

    Energy Technology Data Exchange (ETDEWEB)

    Pichon, M.; Tamain, B.; Bougault, R. [Caen Univ., Lab. de Physique Corpusculaire, IN2P3-CNRS, ISMRA, 14 (France)] [and others

    2003-03-01

    The deexcitation of quasi-projectiles (QP) released in binary Au on Au collisions as been studied from 60 to 100 MeV/u. Bimodality between two different decay patterns has been observed for intermediate violence collisions. The main experimental result is that the system jumps from one mode to the other on a narrow range of energy deposit and/or impact parameter. The sorting of the events (according to the violence of the collision) has been provided by the perpendicular energy of the light charged particles emitted on the quasi-target side. Such a sorting prevents spurious autocorrelation effects between the sorting variable and the observed mechanism. The two modes of the QP decay correspond on the one side to residue or fission fragments production, and on the other side to the multifragmentation channel. A detailed study has been performed in order to try to establish the origin of the observed bimodality in disentangling dynamical or geometrical effects from bulk matter properties linked with a liquid-gas type phase transition. The whole set of data is coherent with a dominant role of the deposited excitation energy as it is expected from theoretical arguments.(lattice gas model) in the framework of a liquid-gas phase transition picture. (authors)

  9. Dielectron production in Au$+$Au collisions at $\\sqrt{s_{NN}}$=200 GeV

    CERN Document Server

    Adare, A; Ajitanand, N N; Akiba, Y; Akimoto, R; Alexander, J; Alfred, M; Al-Ta'ani, H; Angerami, A; Aoki, K; Apadula, N; Aramaki, Y; Asano, H; Aschenauer, E C; Atomssa, E T; Averbeck, R; Awes, T C; Azmoun, B; Babintsev, V; Bai, M; Bandara, N S; Bannier, B; Barish, K N; Bassalleck, B; Bathe, S; Baublis, V; Baumgart, S; Bazilevsky, A; Beaumier, M; Beckman, S; Belmont, R; Berdnikov, A; Berdnikov, Y; Blau, D S; Bok, J S; Boyle, K; Brooks, M L; Bryslawskyj, J; Buesching, H; Bumazhnov, V; Butsyk, S; Campbell, S; Castera, P; Chen, C -H; Chi, C Y; Chiu, M; Choi, I J; Choi, J B; Choi, S; Choudhury, R K; Christiansen, P; Chujo, T; Chvala, O; Cianciolo, V; Citron, Z; Cole, B A; Connors, M; Csanád, M; Csörgő, T; Dairaku, S; Danley, D; Datta, A; Daugherity, M S; David, G; DeBlasio, K; Dehmelt, K; Denisov, A; Deshpande, A; Desmond, E J; Dharmawardane, K V; Dietzsch, O; Ding, L; Dion, A; Diss, P B; Do, J H; Donadelli, M; D'Orazio, L; Drapier, O; Drees, A; Drees, K A; Durham, J M; Durum, A; Edwards, S; Efremenko, Y V; Engelmore, T; Enokizono, A; Esumi, S; Eyser, K O; Fadem, B; Feege, N; Fields, D E; Finger, M; Jr., \\,; Fleuret, F; Fokin, S L; Frantz, J E; Franz, A; Frawley, A D; Fukao, Y; Fusayasu, T; Gainey, K; Gal, C; Gallus, P; Garg, P; Garishvili, A; Garishvili, I; Ge, H; Giordano, F; Glenn, A; Gong, X; Gonin, M; Goto, Y; de Cassagnac, R Granier; Grau, N; Greene, S V; Perdekamp, M Grosse; Gunji, T; Guo, L; Gustafsson, H -Å; Hachiya, T; Haggerty, J S; Hahn, K I; Hamagaki, H; Hamilton, H F; Han, S Y; Hanks, J; Hasegawa, S; Haseler, T O S; Hashimoto, K; Haslum, E; Hayano, R; He, X; Hemmick, T K; Hester, T; Hill, J C; Hollis, R S; Homma, K; Hong, B; Horaguchi, T; Hori, Y; Hoshino, T; Hotvedt, N; Huang, J; Huang, S; Ichihara, T; Iinuma, H; Ikeda, Y; Imai, K; Imrek, J; Inaba, M; Iordanova, A; Isenhower, D; Issah, M; Ivanishchev, D; Jacak, B V; Javani, M; Jezghani, M; Jia, J; Jiang, X; Johnson, B M; Joo, K S; Jouan, D; Jumper, D S; Kamin, J; Kanda, S; Kaneti, S; Kang, B H; Kang, J H; Kang, J S; Kapustinsky, J; Karatsu, K; Kasai, M; Kawall, D; Kazantsev, A V; Kempel, T; Key, J A; Khachatryan, V; Khanzadeev, A; Kijima, K M; Kim, B I; Kim, C; Kim, D J; Kim, E -J; Kim, G W; Kim, H J; Kim, K -B; Kim, M; Kim, Y -J; Kim, Y K; Kimelman, B; Kinney, E; Kiss, Á; Kistenev, E; Kitamura, R; Klatsky, J; Kleinjan, D; Kline, P; Koblesky, T; Komatsu, Y; Komkov, B; Koster, J; Kotchetkov, D; Kotov, D; Král, A; Krizek, F; Kunde, G J; Kurita, K; Kurosawa, M; Kwon, Y; Kyle, G S; Lacey, R; Lai, Y S; Lajoie, J G; Lebedev, A; Lee, B; Lee, D M; Lee, J; Lee, K B; Lee, K S; Lee, S; Lee, S H; Lee, S R; Leitch, M J; Leite, M A L; Leitgab, M; Lewis, B; Li, X; Lim, S H; Levy, L A Linden; Liu, M X; Love, B; Lynch, D; Maguire, C F; Makdisi, Y I; Makek, M; Manion, A; Manko, V I; Mannel, E; Masumoto, S; McCumber, M; McGaughey, P L; McGlinchey, D; McKinney, C; Meles, A; Mendoza, M; Meredith, B; Miake, Y; Mibe, T; Mignerey, A C; Milov, A; Mishra, D K; Mitchell, J T; Miyachi, Y; Miyasaka, S; Mizuno, S; Mohanty, A K; Mohapatra, S; Montuenga, P; Moon, H J; Moon, T; Morrison, D P; Motschwiller, S; Moukhanova, T V; Murakami, T; Murata, J; Mwai, A; Nagae, T; Nagamiya, S; Nagashima, K; Nagle, J L; Nagy, M I; Nakagawa, I; Nakagomi, H; Nakamiya, Y; Nakamura, K R; Nakamura, T; Nakano, K; Nattrass, C; Nederlof, A; Netrakanti, P K; Nihashi, M; Niida, T; Nishimura, S; Nouicer, R; Novak, T; Novitzky, N; Nyanin, A S; O'Brien, E; Ogilvie, C A; Okada, K; Koop, J D Orjuela; Osborn, J D; Oskarsson, A; Ouchida, M; Ozawa, K; Pak, R; Pantuev, V; Papavassiliou, V; Park, B H; Park, I H; Park, J S; Park, S; Park, S K; Pate, S F; Patel, L; Patel, M; Pei, H; Peng, J -C; Pereira, H; Perepelitsa, D V; Perera, G D N; Peressounko, D Yu; Perry, J; Petti, R; Pinkenburg, C; Pinson, R; Pisani, R P; Proissl, M; Purschke, M L; Qu, H; Rak, J; Ramson, B J; Ravinovich, I; Read, K F; Reynolds, D; Riabov, V; Riabov, Y; Richardson, E; Rinn, T; Roach, D; Roche, G; Rolnick, S D; Rosati, M; Rowan, Z; Rubin, J G; Sahlmueller, B; Saito, N; Sakaguchi, T; Sako, H; Samsonov, V; Sano, M; Sarsour, M; Sato, S; Sawada, S; Schaefer, B; Schmoll, B K; Sedgwick, K; Seidl, R; Sen, A; Seto, R; Sett, P; Sexton, A; Sharma, D; Shein, I; Shibata, T -A; Shigaki, K; Shimomura, M; Shoji, K; Shukla, P; Sickles, A; Silva, C L; Silvermyr, D; Sim, K S; Singh, B K; Singh, C P; Singh, V; Slunečka, M; Snowball, M; Soltz, R A; Sondheim, W E; Sorensen, S P; Sourikova, I V; Stankus, P W; Stenlund, E; Stepanov, M; Ster, A; Stoll, S P; Sugitate, T; Sukhanov, A; Sumita, T; Sun, J; Sziklai, J; Takagui, E M; Takahara, A; Taketani, A; Tanaka, Y; Taneja, S; Tanida, K; Tannenbaum, M J; Tarafdar, S; Taranenko, A; Tennant, E; Themann, H; Tieulent, R; Timilsina, A; Todoroki, T; Tomášek, L; Tomášek, M; Torii, H; Towell, C L; Towell, R; Towell, R S; Tserruya, I; Tsuchimoto, Y; Tsuji, T; Vale, C; van Hecke, H W; Vargyas, M; Vazquez-Zambrano, E; Veicht, A; Velkovska, J; Vértesi, R; Virius, M; Vossen, A; Vrba, V; Vznuzdaev, E; Wang, X R; Watanabe, D; Watanabe, K; Watanabe, Y; Watanabe, Y S; Wei, F; Wei, R; White, A S; White, S N; Winter, D; Wolin, S; Woody, C L; Wysocki, M; Xia, B; Xue, L; Yalcin, S; Yamaguchi, Y L; Yang, R; Yanovich, A; Ying, J; Yokkaichi, S; Yoo, J H; Yoon, I; You, Z; Younus, I; Yu, H; Yushmanov, I E; Zajc, W A; Zelenski, A; Zhou, S; Zou, L

    2015-01-01

    We present measurements of $e^+e^-$ production at midrapidity in Au$+$Au collisions at $\\sqrt{s_{_{NN}}}$ = 200 GeV. The invariant yield is studied within the PHENIX detector acceptance over a wide range of mass ($m_{ee} <$ 5 GeV/$c^2$) and pair transverse momentum ($p_T$ $<$ 5 GeV/$c$), for minimum bias and for five centrality classes. The \\ee yield is compared to the expectations from known sources. In the low-mass region ($m_{ee}=0.30$--0.76 GeV/$c^2$) there is an enhancement that increases with centrality and is distributed over the entire pair \\pt range measured. It is significantly smaller than previously reported by the PHENIX experiment and amounts to $2.3\\pm0.4({\\rm stat})\\pm0.4({\\rm syst})\\pm0.2^{\\rm model}$ or to $1.7\\pm0.3({\\rm stat})\\pm0.3({\\rm syst})\\pm0.2^{\\rm model}$ for minimum bias collisions when the open-heavy-flavor contribution is calculated with {\\sc pythia} or {\\sc mc@nlo}, respectively. The inclusive mass and $p_T$ distributions as well as the centrality dependence are well repr...

  10. QUELS FUTURS TRAITEMENTS POUR LA DEPENDANCE AU TABAC ET AU CANNABIS?

    Science.gov (United States)

    LE FOLL, Bernard; JUSTINOVA, Zuzana; TANDA, Gianlugi; GOLDBERG, Steven R.

    2009-01-01

    RESUME Plus de trois millions de morts sont attribués au tabagisme dans le monde par an, et l’usage de tabac est en progression dans les pays en voie de développement. L’usage de tabac est donc une des rares causes de mortalité qui augmente, avec une prévision de plus de 10 millions de morts par an dans 30–40 ans. Le cannabis ou marijuana est la drogue illicite la plus consommée dans le monde et il n’y a actuellement pas de traitement disponible. Bien que les systèmes dopaminergiques jouent un rôle central dans les effets renforçants des drogues, d’autres systèmes sont impliqués. Nous présentons ici des résultats récents obtenus avec des antagonistes des récepteurs cannabinoides CB1, des récepteurs D3 de la dopamine et des récepteurs opioïdes. Ces antagonistes qui modulent de façon directe ou indirecte la transmission dopaminergique cérébrale représentent des approches prometteuses pour le traitement du tabagisme ou de la dépendance au cannabis. Ces approches sont à valider dans des essais cliniques. PMID:18663981

  11. Controlled building of CdSe@ZnS/Au and CdSe@ZnS/ Au2S/Au nanohybrids

    Institute of Scientific and Technical Information of China (English)

    Raquel E. Galian[1; Pilar Diaz[1; Antonio Ribera[1; Alejandro Rincon-Bertolin[1; Said Agouram[2; Julia Perez-Prieto[1

    2015-01-01

    The addition of Au3. to spherical amine-capped CdSe@ZnS nanoparticles in toluene at room temperature and under darkness can lead to ternary CdSe@ZnS/Au nanohybrids. We demonstrate that this happens only when the nanoparticles possess a relatively thin ZnS shell, thus showing that thickness plays a key role in gold deposition on the CdSe@ZnS nanoparticle surface. Our hypothesis is that the amine ligand acts as the reductant of Au3+ ions into Au+ ions, whose affinity for sulfur would keep them at the CdSe@ZnS surface. This interaction stabilizes the Au+ ion, making it less prone to reduction than a non-coordinated Au+ ion. In CdSe@ZnS with a thin shell, Au+ ions at the surface of, or most probably within, the ZnS shell cause the transfer of Cd2+ ions into the solution. Subsequently, the core Se2- anion, which is a better reductant than the shell S2- reduces Au+ ions to Au(0), and large gold nanoparticles (AuNPs) are quickly deposited on the CdSe@ZnS surface in room temperature process, leading to ternary CdSe@ZnS/Au nanohybrids. In solution, these ternary nanohybrids progressively transform into quaternary CdSe@ZnS/Au2S/Au nanohybrids due to the reaction of the shell S2- anion with the remaining Au+ at the CdSe@ZnS surface, thus leading to the growth of Au2S nanoparticles on the CdSe@ZnS surface while Zn concomitantly leaches from the nanohybrid into the solution. Photoirradiation of the heterostructures with visible light enhances their emission efficiency. Comparatively, irradiation of the precursors, i.e., CdSe@ZnS nanoparticles, causes a drastic decrease in their emission accompanied by a blue shift of their emission maximum. The optical properties of these nanohybrids were analyzed by absorption and fluorescence (steady-state and time-resolved) spectroscopy, and the composition of the samples and the chemical states were determined by energy dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy

  12. Charged-Particle Pseudorapidity Density Distributions from Au+Au Collisions at (sNN) = 130 GeV

    Science.gov (United States)

    Back, B. B.; Baker, M. D.; Barton, D. S.; Betts, R. R.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Decowski, M. P.; Garcia, E.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Heintzelman, G. A.; Henderson, C.; Hofman, D. J.; Hołyński, R.; Holzman, B.; Johnson, E.; Kane, J. L.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Lin, W. T.; Manly, S.; McLeod, D.; Michałowski, J.; Mignerey, A. C.; Mülmenstädt, J.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Remsberg, L. P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sarin, P.; Sawicki, P.; Skulski, W.; Steadman, S. G.; Steinberg, P.; Stephans, G. S.; Stodulski, M.; Sukhanov, A.; Tang, J.-L.; Teng, R.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Verdier, R.; Wadsworth, B.; Wolfs, F. L.; Wosiek, B.; Woźniak, K.; Wuosmaa, A. H.; Wysłouch, B.

    2001-09-01

    The charged-particle pseudorapidity density dNch/dη has been measured for Au+Au collisions at (sNN) = 130 GeV at RHIC, using the PHOBOS apparatus. The total number of charged particles produced for the 3% most-central Au+Au collisions for \\|η\\|<=5.4 is found to be 4200+/-470. The evolution of dNch/dη with centrality is discussed, and compared to model calculations and to data from proton-induced collisions. The data show an enhancement in charged-particle production at midrapidity, while in the fragmentation regions, the results are consistent with expectations from pp and pA scattering.

  13. Fabrication of Au nanostructures in the process of amalgam formation followed by Au-Hg alloy thermal decomposition

    International Nuclear Information System (INIS)

    Au films deposited under ultra-high vacuum conditions on air-cleaved mica substrates were exposed in situ to Hg vapor (residual gas pressure ∼1x10-7 Pa, with Hg vapor pressure of 0.24 Pa). This led to transformation of continuous gold film into isolated amalgam islands of nanometer scale. The changes of Au thin film surface topography caused by amalgamation carried out within ∼40 h were studied by the atomic force microscopy method, while the phase transition in the bulk of Hg-dosed Au films was monitored by means of X-ray diffraction. The island's morphology varies from irregular, ramified structures on terraces to compact shapes along the steps on the mica substrate. After thermal decomposition of the amalgam, thin gold films consisting of isolated Au nanostructures on mica can be obtained

  14. Strangeness Enhancement in Cu+Cu and Au+Au Collisions at \\sqrt{s_{NN}} = 200 GeV

    CERN Document Server

    Agakishiev, H; Ahammed, Z; Alakhverdyants, A V; Alekseev, I; Alford, J; Anderson, B D; Anson, C D; Arkhipkin, D; Averichev, G S; Balewski, J; Barnby, L S; Beavis, D R; Behera, N K; Bellwied, R; Betancourt, M J; Betts, R R; Bhasin, A; Bhati, A K; Bichsel, H; Bielcik, J; Bielcikova, J; Biritz, B; Bland, L C; Borowski, W; Bouchet, J; Braidot, E; Brandin, A V; Bridgeman, A; Brovko, S G; Bruna, E; Bueltmann, S; Bunzarov, I; Burton, T P; Cai, X Z; Caines, H; Sánchez, M Calderón de la Barca; Cebra, D; Cendejas, R; Cervantes, M C; Chajecki, Z; Chaloupka, P; Chattopadhyay, S; Chen, H F; Chen, J H; Chen, J Y; Chen, L; Cheng, J; Cherney, M; Chikanian, A; Choi, K E; Christie, W; Chung, P; Codrington, M J M; Corliss, R; Cramer, J G; Crawford, H J; Dash, S; Leyva, A Davila; De Silva, L C; Debbe, R R; Dedovich, T G; Derevschikov, A A; de Souza, R Derradi; Didenko, L; Djawotho, P; Dogra, S M; Dong, X; Drachenberg, J L; Draper, J E; Dunlop, J C; Efimov, L G; Elnimr, M; Engelage, J; Eppley, G; Estienne, M; Eun, L; Evdokimov, O; Fatemi, R; Fedorisin, J; Fersch, R G; Filip, P; Finch, E; Fine, V; Fisyak, Y; Gagliardi, C A; Gangadharan, D R; Geromitsos, A; Geurts, F; Ghosh, P; Gorbunov, Y N; Gordon, A; Grebenyuk, O; Grosnick, D; Guertin, S M; Gupta, A; Guryn, W; Haag, B; Hajkova, O; Hamed, A; Han, L-X; Harris, J W; Hays-Wehle, J P; Heinz, M; Heppelmann, S; Hirsch, A; Hjort, E; Hoffmann, G W; Hofman, D J; Huang, B; Huang, H Z; Humanic, T J; Huo, L; Igo, G; Jacobs, P; Jacobs, W W; Jones, P G; Jena, C; Jin, F; Joseph, J; Judd, E G; Kabana, S; Kang, K; Kapitan, J; Kauder, K; Ke, H; Keane, D; Kechechyan, A; Kettler, D; Kikola, D P; Kiryluk, J; Kisiel, A; Kizka, V; Knospe, A G; Koetke, D D; Kollegger, T; Konzer, J; Koralt, I; Koroleva, L; Korsch, W; Kotchenda, L; Kouchpil, V; Kravtsov, P; Krueger, K; Krus, M; Kumar, L; Kurnadi, P; Lamont, M A C; Landgraf, J M; LaPointe, S; Lauret, J; Lebedev, A; Lednicky, R; Lee, J H; Leight, W; LeVine, M J; Li, C; Li, L; Li, N; Li, W; Li, X; Li, X; Li, Y; Li, Z M; Lisa, M A; Liu, F; Liu, H; Liu, J; Ljubicic, T; Llope, W J; Longacre, R S; Love, W A; Lu, Y; Lukashov, E V; Luo, X; Ma, G L; Ma, Y G; Mahapatra, D P; Majka, R; Mall, O I; Mangotra, L K; Manweiler, R; Margetis, S; Markert, C; Masui, H; Matis, H S; Matulenko, Yu A; McDonald, D; McShane, T S; Meschanin, A; Milner, R; Minaev, N G; Mioduszewski, S; Mischke, A; Mitrovski, M K; Mohanty, B; Mondal, M M; Morozov, B; Morozov, D A; Munhoz, M G; Naglis, M; Nandi, B K; Nayak, T K; Netrakanti, P K; Nelson, J M; Nogach, L V; Nurushev, S B; Odyniec, G; Ogawa, A; Oh, K; Ohlson, A; Okorokov, V; Oldag, E W; Olson, D; Pachr, M; Page, B S; Pal, S K; Pandit, Y; Panebratsev, Y; Pawlak, T; Pei, H; Peitzmann, T; Perkins, C; Peryt, W; Phatak, S C; Pile, P; Planinic, M; Ploskon, M A; Pluta, J; Plyku, D; Poljak, N; Poskanzer, A M; Potukuchi, B V K S; Powell, C B; Prindle, D; Pruneau, C; Pruthi, N K; Pujahari, P R; Putschke, J; Qiu, H; Raniwala, R; Raniwala, S; Ray, R L; Redwine, R; Reed, R; Ritter, H G; Roberts, J B; Rogachevskiy, O V; Romero, J L; Rose, A; Ruan, L; Rusnak, J; Sahoo, N R; Sakai, S; Sakrejda, I; Sakuma, T; Salur, S; Sandweiss, J; Sangaline, E; Sarkar, A; Schambach, J; Scharenberg, R P; Schmah, A M; Schuster, T R; Seele, J; Seger, J; Selyuzhenkov, I; Seyboth, P; Shahaliev, E; Shao, M; Sharma, M; Shi, S S; Shou, Q Y; Sichtermann, E P; Simon, F; Singaraju, R N; Skoby, M J; Smirnov, N; Spinka, H M; Srivastava, B; Stanislaus, T D S; Staszak, D; Steadman, S G; Stevens, J R; Stock, R; Strikhanov, M; Stringfellow, B; Suaide, A A P; Suarez, M C; Subba, N L; Sumbera, M; Sun, X M; Sun, Y; Sun, Z; Surrow, B; Svirida, D N; Symons, T J M; de Toledo, A Szanto; Takahashi, J; Tang, A H; Tang, Z; Tarini, L H; Tarnowsky, T; Thein, D; Thomas, J H; Tian, J; Timmins, A R; Tlusty, D; Tokarev, M; Tram, V N; Trentalange, S; Tribble, R E; Tribedy, P; Tsai, O D; Ullrich, T; Underwood, D G; Van Buren, G; van Nieuwenhuizen, G; Vanfossen, J A; Jr.,; Varma, R; Vasconcelos, G M S; Vasiliev, A N; Videbæk, F; Viyogi, Y P; Vokal, S; Wada, M; Walker, M; Wang, F; Wang, G; Wang, H; Wang, J S; Wang, Q; Wang, X L; Wang, Y; Webb, G; Webb, J C; Westfall, G D; Whitten, C; Wieman, H; Wissink, S W; Witt, R; Witzke, W; Wu, Y F; Xiao, Z; Xie, W; Xu, H; Xu, N; Xu, Q H; Xu, W; Xu, Y; Xu, Z; Xue, L; Yang, Y; Yepes, P; Yip, K; Yoo, I-K; Zawisza, M; Zbroszczyk, H; Zhan, W; Zhang, J B; Zhang, S; Zhang, W M; Zhang, X P; Zhang, Y; Zhang, Z P; Zhao, J; Zhong, C; Zhou, W; Zhu, X; Zhu, Y H; Zoulkarneev, R; Zoulkarneeva, Y

    2011-01-01

    We report new STAR measurements of mid-rapidity yields for the $\\Lambda$, $\\bar{\\Lambda}$, $K^{0}_{S}$, $\\Xi^{-}$, $\\bar{\\Xi}^{+}$, $\\Omega^{-}$, $\\bar{\\Omega}^{+}$ particles in Cu+Cu collisions at \\sNN{200}, and mid-rapidity yields for the $\\Lambda$, $\\bar{\\Lambda}$, $K^{0}_{S}$ particles in Au+Au at \\sNN{200}. We show that at a given number of participating nucleons, the production of strange hadrons is higher in Cu+Cu collisions than in Au+Au collisions at the same center-of-mass energy. We find that aspects of the enhancement factors for all particles can be described by a parameterization based on the fraction of participants that undergo multiple collisions. Such a parameterization may be relevant in the core-corona or string excitation/breaking hadron production schemes.

  15. Centrality Dependence of Direct Photons in Au+Au Collisions at sqrt(s_NN) = 200 GeV

    CERN Document Server

    Fries, R J; Srivastava, D K

    2005-01-01

    We calculate the spectra of high energy photons emitted in relativistic Au+Au collisions for various centralities and compare to data recently collected at the Relativistic Heavy Ion Collider by the PHENIX collaboration. Our results for photons from primary hard scatterings and photons from interactions of jets with the medium are consistent with the measurements of neutral pion and direct photon production in p+p collisions and give a good description of direct photon spectra measured in Au+Au collisions. The contribution of photons from jet-to-photon conversion in the medium can be as large as the photon yield from hard scatterings in the momentum range p_T = 2...6 GeV/c. We show that this novel mechanism is not ruled out by any existing data.

  16. Scaling properties of proton and antiproton production in sqrt[s(NN)]=200 GeV Au+Au collisions.

    Science.gov (United States)

    Adler, S S; Afanasiev, S; Aidala, C; Ajitanand, N N; Akiba, Y; Alexander, J; Amirikas, R; Aphecetche, L; Aronson, S H; Averbeck, R; Awes, T C; Azmoun, R; Babintsev, V; Baldisseri, A; Barish, K N; Barnes, P D; Bassalleck, B; Bathe, S; Batsouli, S; Baublis, V; Bazilevsky, A; Belikov, S; Berdnikov, Y; Bhagavatula, S; Boissevain, J G; Borel, H; Borenstein, S; Brooks, M L; Brown, D S; Bruner, N; Bucher, D; Buesching, H; Bumazhnov, V; Bunce, G; Burward-Hoy, J M; Butsyk, S; Camard, X; Chai, J-S; Chand, P; Chang, W C; Chernichenko, S; Chi, C Y; Chiba, J; Chiu, M; Choi, I J; Choi, J; Choudhury, R K; Chujo, T; Cianciolo, V; Cobigo, Y; Cole, B A; Constantin, P; d'Enterria, D G; David, G; Delagrange, H; Denisov, A; Deshpande, A; Desmond, E J; Dietzsch, O; Drapier, O; Drees, A; du Rietz, R; Durum, A; Dutta, D; Efremenko, Y V; El Chenawi, K; Enokizono, A; En'yo, H; Esumi, S; Ewell, L; Fields, D E; Fleuret, F; Fokin, S L; Fox, B D; Fraenkel, Z; Frantz, J E; Franz, A; Frawley, A D; Fung, S-Y; Garpman, S; Ghosh, T K; Glenn, A; Gogiberidze, G; Gonin, M; Gosset, J; Goto, Y; Granier de Cassagnac, R; Grau, N; Greene, S V; Grosse Perdekamp, G; Guryn, W; Gustafsson, H-A; Hachiya, T; Haggerty, J S; Hamagaki, H; Hansen, A G; Hartouni, E P; Harvey, M; Hayano, R; He, X; Heffner, M; Hemmick, T K; Heuser, J M; Hibino, M; Hill, J C; Holzmann, W; Homma, K; Hong, B; Hoover, A; Ichihara, T; Ikonnikov, V V; Imai, K; Isenhower, L D; Ishihara, M; Issah, M; Isupov, A; Jacak, B V; Jang, W Y; Jeong, Y; Jia, J; Jinnouchi, O; Johnson, B M; Johnson, S C; Joo, K S; Jouan, D; Kametani, S; Kamihara, N; Kang, J H; Kapoor, S S; Katou, K; Kelly, S; Khachaturov, B; Khanzadeev, A; Kikuchi, J; Kim, D H; Kim, D J; Kim, D W; Kim, E; Kim, G-B; Kim, H J; Kistenev, E; Kiyomichi, A; Kiyoyama, K; Klein-Boesing, C; Kobayashi, H; Kochenda, L; Kochetkov, V; Koehler, D; Kohama, T; Kopytine, M; Kotchetkov, D; Kozlov, A; Kroon, P J; Kuberg, C H; Kurita, K; Kuroki, Y; Kweon, M J; Kwon, Y; Kyle, G S; Lacey, R; Ladygin, V; Lajoie, J G; Lebedev, A; Leckey, S; Lee, D M; Lee, S; Leitch, M J; Li, X H; Lim, H; Litvinenko, A; Liu, M X; Liu, Y; Maguire, C F; Makdisi, Y I; Malakhov, A; Manko, V I; Mao, Y; Martinez, G; Marx, M D; Masui, H; Matathias, F; Matsumoto, T; McGaughey, P L; Melnikov, E; Messer, F; Miake, Y; Milan, J; Miller, T E; Milov, A; Mioduszewski, S; Mischke, R E; Mishra, G C; Mitchell, J T; Mohanty, A K; Morrison, D P; Moss, J M; Mühlbacher, F; Mukhopadhyay, D; Muniruzzaman, M; Murata, J; Nagamiya, S; Nagle, J L; Nakamura, T; Nandi, B K; Nara, M; Newby, J; Nilsson, P; Nyanin, A S; Nystrand, J; O'Brien, E; Ogilvie, C A; Ohnishi, H; Ojha, I D; Okada, K; Ono, M; Onuchin, V; Oskarsson, A; Otterlund, I; Oyama, K; Ozawa, K; Pal, D; Palounek, A P T; Pantuev, V S; Papavassiliou, V; Park, J; Parmar, A; Pate, S F; Peitzmann, T; Peng, J-C; Peresedov, V; Pinkenburg, C; Pisani, R P; Plasil, F; Purschke, M L; Purwar, A; Rak, J; Ravinovich, I; Read, K F; Reuter, M; Reygers, K; Riabov, V; Riabov, Y; Roche, G; Romana, A; Rosati, M; Rosnet, P; Ryu, S S; Sadler, M E; Saito, N; Sakaguchi, T; Sakai, M; Sakai, S; Samsonov, V; Sanfratello, L; Santo, R; Sato, H D; Sato, S; Sawada, S; Schutz, Y; Semenov, V; Seto, R; Shaw, M R; Shea, T K; Shibata, T-A; Shigaki, K; Shiina, T; Silva, C L; Silvermyr, D; Sim, K S; Singh, C P; Singh, V; Sivertz, M; Soldatov, A; Soltz, R A; Sondheim, W E; Sorensen, S P; Sourikova, I V; Staley, F; Stankus, P W; Stenlund, E; Stepanov, M; Ster, A; Stoll, S P; Sugitate, T; Sullivan, J P; Takagui, E M; Taketani, A; Tamai, M; Tanaka, K H; Tanaka, Y; Tanida, K; Tannenbaum, M J; Tarján, P; Tepe, J D; Thomas, T L; Tojo, J; Torii, H; Towell, R S; Tserruya, I; Tsuruoka, H; Tuli, S K; Tydesjö, H; Tyurin, N; Van Hecke, H W; Velkovska, J; Velkovsky, M; Villatte, L; Vinogradov, A A; Volkov, M A; Vznuzdaev, E; Wang, X R; Watanabe, Y; White, S N; Wohn, F K; Woody, C L; Xie, W; Yang, Y; Yanovich, A; Yokkaichi, S; Young, G R; Yushmanov, I E; Zajc, W A; Zhang, C; Zhou, S; Zolin, L

    2003-10-24

    We report on the yield of protons and antiprotons, as a function of centrality and transverse momentum, in Au+Au collisions at sqrt[s(NN)]=200 GeV measured at midrapidity by the PHENIX experiment at the BNL Relativistic Heavy Ion Collider. In central collisions at intermediate transverse momenta (1.5Au+Au, p+p, and e(+)e(-) collisions. This enhancement is limited to p(T)<5 GeV/c as deduced from the ratio of charged hadrons to pi(0) measured in the range 1.5

  17. Synthesis of Au/C and Au/Pani for anode electrodes in glucose microfluidic fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Guerra-Balcazar, M.; Morales-Acosta, D.; Castaneda, F.; Arriaga, L.G. [Centro de Investigacion y Desarrollo Tecnologico en Electroquimica, 76703 Queretaro (Mexico); Ledesma-Garcia, J. [Division de Investigacion y Posgrado, Facultad de Ingenieria, Universidad Autonoma de Queretaro, 76010 Queretaro (Mexico)

    2010-06-15

    Gold nanoparticles have been prepared by two methods: chemical (ex-situ, Au/C) by two phase protocol, and electrochemical (in-situ, Au/Pani) by electroreduction of gold ions on a polyaniline film and compared as anode catalysts in a glucose microfluidic fuel cell. In this paper the structural characteristics and electrocatalytic properties were investigated by X-ray diffraction and electrochemical measurements. The catalytic behavior of both anodes was tested in a microfluidic fuel cell with a reference electrode incorporated, by means of linear sweep voltammetry (LSV), showing a cathodic shift in the glucose oxidation peak for Au/Pani. Results show a higher power density (0.5 mW cm{sup -} {sup 2}) for Au/C anode compared with an already reported value, where a glucose microfluidic fuel cell was used in similar conditions. (author)

  18. Structure and Mobility of Metal Clusters in MOFs: Au, Pd, and AuPd Clusters in MOF-74

    DEFF Research Database (Denmark)

    Vilhelmsen, Lasse; Walton, Krista S.; Sholl, David S.

    2012-01-01

    Understanding the adsorption and mobility of metal–organic framework (MOF)-supported metal nanoclusters is critical to the development of these catalytic materials. We present the first theoretical investigation of Au-, Pd-, and AuPd-supported clusters in a MOF, namely MOF-74. We combine density...... functional theory (DFT) calculations with a genetic algorithm (GA) to reliably predict the structure of the adsorbed clusters. This approach allows comparison of hundreds of adsorbed configurations for each cluster. From the investigation of Au8, Pd8, and Au4Pd4 we find that the organic part of the MOF...... is just as important for nanocluster adsorption as open Zn or Mg metal sites. Using the large number of clusters generated by the GA, we developed a systematic method for predicting the mobility of adsorbed clusters. Through the investigation of diffusion paths a relationship between the cluster...

  19. Excitonic luminescence of ZnSe single crystals doped with Au

    International Nuclear Information System (INIS)

    Photoluminescence spectra of ZnSe single crystals doped with Au during a long high-temperature treatment of as-grown crystals in Zn+Au or Se+Au melts are investigated in the temperature range from 83 to 300 K. The Au-doping from Zn+Au melt leads to the formation of both simple defects (Aui donors and AuZn acceptors) and acceptor associates (AuZn-Aui). The edge luminescence is attributed to radiative annihilation of Aui and VSe donor-bound excitons. The edge spectra of the crystals doped with Au from Se+Au melt contain the band ascribed to radiative annihilation of AuZn acceptor-bound excitons

  20. Pion Interferometry of $\\sqrt{s_{NN}} = 130$ GeV Au+Au Collisions at RHIC

    OpenAIRE

    STAR Collaboration; Adler, C.

    2001-01-01

    Two-pion correlation functions in Au+Au collisions at $\\sqrt{s_{NN}} = 130$ GeV have been measured by the STAR (Solenoidal Tracker at RHIC) detector. The source size extracted by fitting the correlations grows with event multiplicity and decreases with transverse momentum. Anomalously large sizes or emission durations, which have been suggested as signals of quark-gluon plasma formation and rehadronization, are not observed. The HBT parameters display a weak energy dependence over a broad ran...

  1. NUCLEAR AND HEAVY ION PHYSICS: Charged-particle pseudorapidity distributions in Au+Au collisions at RHIC

    Science.gov (United States)

    Wang, Zeng-Wei; Jiang, Zhi-Jin

    2009-04-01

    Using the Glauber model, we present the formulas for calculating the numbers of participants, spectators and binary nucleon-nucleon collisions. Based on this work, we get the pseudorapidity distributions of charged particles as the function of the impact parameter in nucleus-nucleus collisions. The theoretical results agree well with the experimental observations made by the BRAHMS Collaboration in Au + Au collisions at GeV in different centrality bins over the whole pseudorapidity range.

  2. Azimuthally sensitive hanbury brown-twiss interferometry in Au + Au collisions sqrt S sub NN = 200 GeV

    Energy Technology Data Exchange (ETDEWEB)

    Adams, J.; Adler, C.; Aggarwal, M.M.; Ahammed, Z.; Amonett, J.; Anderson, B.D.; Arkhipkin, D.; Averichev, G.S.; Badyal, S.K.; Balewski, J.; Barannikova, O.; Barnby, L.S.; Baudot, J.; Bekele, S.; Belaga, V.V.; Bellwied, R.; Berger, J.; Bezverkhny, B.I.; Bhardwaj, S.; Bhati, A.K.; Bichsel, H.; Billmeier, A.; Bland, L.C.; Blyth, C.O.; Bonner, B.E.; Botje, M.; Boucham, A.; Brandin, A.; Bravar, A.; Cadman, R.V.; Cai, X.Z.; Caines, H.; Calderon de la Barca Sanchez, M.; Carroll, J.; Castillo, J.; Cebra, D.; Chaloupka, P.; Chattopadhyay, S.; Chen, H.F.; Chen, Y.; Chernenko, S.P.; Cherney, M.; Chikanian, A.; Christie, W.; Coffin, J.P.; Cormier, T.M.; Cramer, J.G.; Crawford, H.J.; Das, D.; Das, S.; Derevschikov, A.A.; Didenko, L.; Dietel, T.; Dong, W.J.; Dong, X.; Draper, J.E.; Du, F.; Dubey, A.K.; Dunin, V.B.; Dunlop, J.C.; Dutta Majumdar, M.R.; Eckardt, V.; Efimov, L.G.; Emelianov, V.; Engelage, J.; Eppley, G.; Erazmus, B.; Estienne, M.; Fachini, P.; Faine, V.; Faivre, J.; Fatemi, R.; Filimonov, K.; Filip, P.; Finch, E.; Fisyak, Y.; Flierl, D.; Foley, K.J.; Fu, J.; Gagliardi, C.A.; Gagunashvili, N.; Gans, J.; Gaudichet, L.; Geurts, F.; Ghazikhanian, V.; Ghosh, P.; Gonzalez, J.E.; Grachov, O.; Grebenyuk, O.; Gronstal, S.; Grosnick, D.; Guertin, S.M.; Gupta, A.; Gutierrez, T.D.; Hallman, T.J.; Hamed, A.; Hardtke, D.; Harris, J.W.; Heinz, M.; Henry, T.W.; Heppelmann, S.; Hippolyte, B.; Hirsch, A.; Hjort, E.; Hoffmann, G.W.; Horsley, M.; Huang, H.Z.; Huang, L.S.; Hughes, E.; Humanic, T.J.; Igo, G.; Ishihara, A.; Jacobs, P.; Jacobs, W.W.; Janik, M.; Jiang, H.; Johnson, I.; Jones, P.G.; Judd, E.G.; Kabana, S.; Kaplan, M.; Keane, D.; Khodyrev, V.Yu.; Kiryluk, J.; Kisiel, A.; Klay, J.; Klein, S.R.; Klyachko, A.; Koetke, D.D.; Kollegger, T.; Kopytine, M.; Kotchenda, L.; Kovalenko, A.D.; Kramer, M.; Kravtsov, V.I.; Kravtsov, P.; Krueger, K.; Kuhn, C.; Kulikov, A.I.; Kumar, A.; Kunde, G.J.; Kunz, C.L.; Kutuev, R.Kh.; Kuznetsov, A.A.; Lamont, M.A.C.; et al.

    2004-06-30

    We present the results of a systematic study of the shape of the pion distribution in coordinate space at freeze-out in Au+Au collisions at RHIC using two-pion Hanbury Brown-Twiss (HBT) interferometry. Oscillations of the extracted HBT radii vs. emission angle indicate sources elongated perpendicular to the reaction plane. The results indicate that the pressure and expansion time of the collision system are not sufficient to completely quench its initial shape.

  3. Elliptic flow of identified hadrons in Au+Au collisions at √(sNN)=200 GeV

    International Nuclear Information System (INIS)

    The anisotropy parameter (v2), the second harmonic of the azimuthal particle distribution, has been measured with the PHENIX detector in Au+Au collisions at √(sNN)=200 GeV for identified and inclusive charged particle production at central rapidities (|η|2 of mesons falls below that of (anti)baryons for pT>2 GeV/c, in marked contrast to the predictions of a hydrodynamical model. A quark-coalescence model is also investigated

  4. Elliptic flow of identified hadrons in Au+Au collisions at sqrt sNN =200 GeV.

    Science.gov (United States)

    Adler, S S; Afanasiev, S; Aidala, C; Ajitanand, N N; Akiba, Y; Alexander, J; Amirikas, R; Aphecetche, L; Aronson, S H; Averbeck, R; Awes, T C; Azmoun, R; Babintsev, V; Baldisseri, A; Barish, K N; Barnes, P D; Bassalleck, B; Bathe, S; Batsouli, S; Baublis, V; Bazilevsky, A; Belikov, S; Berdnikov, Y; Bhagavatula, S; Boissevain, J G; Borel, H; Borenstein, S; Brooks, M L; Brown, D S; Bruner, N; Bucher, D; Buesching, H; Bumazhnov, V; Bunce, G; Burward-Hoy, J M; Butsyk, S; Camard, X; Chai, J-S; Chand, P; Chang, W C; Chernichenko, S; Chi, C Y; Chiba, J; Chiu, M; Choi, I J; Choi, J; Choudhury, R K; Chujo, T; Cianciolo, V; Cobigo, Y; Cole, B A; Constantin, P; D'Enterria, D G; David, G; Delagrange, H; Denisov, A; Deshpande, A; Desmond, E J; Dietzsch, O; Drapier, O; Drees, A; du Rietz, R; Durum, A; Dutta, D; Efremenko, Y V; El Chenawi, K; Enokizono, A; En'yo, H; Esumi, S; Ewell, L; Fields, D E; Fleuret, F; Fokin, S L; Fox, B D; Fraenkel, Z; Frantz, J E; Franz, A; Frawley, A D; Fung, S-Y; Garpman, S; Ghosh, T K; Glenn, A; Gogiberidze, G; Gonin, M; Gosset, J; Goto, Y; Granier de Cassagnac, R; Grau, N; Greene, S V; Grosse Perdekamp, M; Guryn, W; Gustafsson, H-A; Hachiya, T; Haggerty, J S; Hamagaki, H; Hansen, A G; Hartouni, E P; Harvey, M; Hayano, R; He, X; Heffner, M; Hemmick, T K; Heuser, J M; Hibino, M; Hill, J C; Holzmann, W; Homma, K; Hong, B; Hoover, A; Ichihara, T; Ikonnikov, V V; Imai, K; Isenhower, L D; Ishihara, M; Issah, M; Isupov, A; Jacak, B V; Jang, W Y; Jeong, Y; Jia, J; Jinnouchi, O; Johnson, B M; Johnson, S C; Joo, K S; Jouan, D; Kametani, S; Kamihara, N; Kang, J H; Kapoor, S S; Katou, K; Kelly, S; Khachaturov, B; Khanzadeev, A; Kikuchi, J; Kim, D H; Kim, D J; Kim, D W; Kim, E; Kim, G-B; Kim, H J; Kistenev, E; Kiyomichi, A; Kiyoyama, K; Klein-Boesing, C; Kobayashi, H; Kochenda, L; Kochetkov, V; Koehler, D; Kohama, T; Kopytine, M; Kotchetkov, D; Kozlov, A; Kroon, P J; Kuberg, C H; Kurita, K; Kuroki, Y; Kweon, M J; Kwon, Y; Kyle, G S; Lacey, R; Ladygin, V; Lajoie, J G; Lebedev, A; Leckey, S; Lee, D M; Lee, S; Leitch, M J; Li, X H; Lim, H; Litvinenko, A; Liu, M X; Liu, Y; Maguire, C F; Makdisi, Y I; Malakhov, A; Manko, V I; Mao, Y; Martinez, G; Marx, M D; Masui, H; Matathias, F; Matsumoto, T; McGaughey, P L; Melnikov, E; Messer, F; Miake, Y; Milan, J; Miller, T E; Milov, A; Mioduszewski, S; Mischke, R E; Mishra, G C; Mitchell, J T; Mohanty, A K; Morrison, D P; Moss, J M; Mühlbacher, F; Mukhopadhyay, D; Muniruzzaman, M; Murata, J; Nagamiya, S; Nagle, J L; Nakamura, T; Nandi, B K; Nara, M; Newby, J; Nilsson, P; Nyanin, A S; Nystrand, J; O'Brien, E; Ogilvie, C A; Ohnishi, H; Ojha, I D; Okada, K; Ono, M; Onuchin, V; Oskarsson, A; Otterlund, I; Oyama, K; Ozawa, K; Pal, D; Palounek, A P T; Pantuev, V S; Papavassiliou, V; Park, J; Parmar, A; Pate, S F; Peitzmann, T; Peng, J-C; Peresedov, V; Pinkenburg, C; Pisani, R P; Plasil, F; Purschke, M L; Purwar, A; Rak, J; Ravinovich, I; Read, K F; Reuter, M; Reygers, K; Riabov, V; Riabov, Y; Roche, G; Romana, A; Rosati, M; Rosnet, P; Ryu, S S; Sadler, M E; Saito, N; Sakaguchi, T; Sakai, M; Sakai, S; Samsonov, V; Sanfratello, L; Santo, R; Sato, H D; Sato, S; Sawada, S; Schutz, Y; Semenov, V; Seto, R; Shaw, M R; Shea, T K; Shibata, T-A; Shigaki, K; Shiina, T; Silva, C L; Silvermyr, D; Sim, K S; Singh, C P; Singh, V; Sivertz, M; Soldatov, A; Soltz, R A; Sondheim, W E; Sorensen, S P; Sourikova, I V; Staley, F; Stankus, P W; Stenlund, E; Stepanov, M; Ster, A; Stoll, S P; Sugitate, T; Sullivan, J P; Takagui, E M; Taketani, A; Tamai, M; Tanaka, K H; Tanaka, Y; Tanida, K; Tannenbaum, M J; Tarján, P; Tepe, J D; Thomas, T L; Tojo, J; Torii, H; Towell, R S; Tserruya, I; Tsuruoka, H; Tuli, S K; Tydesjö, H; Tyurin, N; van Hecke, H W; Velkovska, J; Velkovsky, M; Villatte, L; Vinogradov, A A; Volkov, M A; Vznuzdaev, E; Wang, X R; Watanabe, Y; White, S N; Wohn, F K; Woody, C L; Xie, W; Yang, Y; Yanovich, A; Yokkaichi, S; Young, G R; Yushmanov, I E; Zajc, W A; Zhang, C; Zhou, S; Zolin, L

    2003-10-31

    The anisotropy parameter (v(2)), the second harmonic of the azimuthal particle distribution, has been measured with the PHENIX detector in Au+Au collisions at sqrt[s(NN)]=200 GeV for identified and inclusive charged particle production at central rapidities (|eta|2 GeV/c, in marked contrast to the predictions of a hydrodynamical model. A quark-coalescence model is also investigated. PMID:14611277

  5. Au - Be/Ru/Au multilayer metallization as a stable ohmic contact scheme to p-type InP

    Science.gov (United States)

    Malina, V.; Moro, L.; Micheli, V.; Mojzes, I.

    1996-07-01

    An attempt has been made to improve the electrical and metallurgical stability of Au - Be alloyed contacts to moderately doped p-type InP by minimizing the thickness of the Au - Be contact layer and using an Ru layer as a new, more effective diffusion barrier between the Au - Be and a thick Au top layer. It was found that the Au - Be contact layer only 40 - 50 nm thick is sufficient to give excellent ohmic contacts with specific contact resistance values as low as 0268-1242/11/7/025/img6 and 0268-1242/11/7/025/img7 (for 0268-1242/11/7/025/img8 and 0268-1242/11/7/025/img9 respectively). When subjected to an aging test at 0268-1242/11/7/025/img10 for 50 h in 0268-1242/11/7/025/img11 gas, the 50 nm Au - Be/50 nm Ru/300 nm Au contacts alloyed at an optimum temperature of about 0268-1242/11/7/025/img12 exhibit good thermal stability and no substantial increase in the specific contact resistance. The remarkable metallurgical stability of such contacts was confirmed by secondary neutral mass spectroscopy (SNMS) in-depth profile measurements. A comparison with the previously investigated diffusion barrier metals (such as Cr, Ti, Pt, etc) shows that the Ru layer is a much better barrier against the migration of Au into the InP substrate and, at the same time, it suppresses the out-diffusion of In and P from the semiconductor.

  6. Production and collective behavior of strange particles in Au + Au collisions at 2-8 AGeV

    CERN Document Server

    Pinkenburg, C H; Alexander, J M; Anderson, M; Best, D; Brady, F P; Case, T; Caskey, W; Cebra, D; Chance, J L; Chung, P; Cole, B; Crowe, K M; Das, A C; Draper, J E; Gilkes, M L; Gushue, S; Heffner, M; Hirsch, A S; Hjort, E L; Huo, L; Justice, M; Kaplan, M; Keane, D; Kintner, J C; Klay, J L; Krofcheck, D; Lacey, R A; Law, C; Lauret, J; Lisa, M A; Liu, H; Liu, Y M; McGrath, R L; Milosevich, Z; Odyniec, Grazyna Janina; Olson, D L; Panitkin, S Y; Porile, N T; Rai, G; Ritter, H G; Romero, J L; Scharenberg, R P; Schröder, L S; Srivastava, B; Stone, N T B; Symons, T J M; Wang, S; Whitfield, J; Witt, R; Wood, L; Zhang Wei Ning

    2002-01-01

    The E895 experiment at the AGS measured strange particle production and collective behavior in Au+Au collisions between 2--8 AGeV. The production of $\\Lambda$ Baryons and K$^0$ Mesons as function of energy rises smoothly and exhibits a nonlinear impact parameter dependence. Neutral and positively charged Kaons exhibit a strong anti-flow behavior. $\\Lambda$ Baryons show a smaller flow signal than protons.

  7. Identified hadron transverse momentum spectra in Au+Au collisions at sNN=62.4 GeV

    Science.gov (United States)

    Back, B. B.; Baker, M. D.; Ballintijn, M.; Barton, D. S.; Betts, R. R.; Bickley, A. A.; Bindel, R.; Busza, W.; Carroll, A.; Chai, Z.; Decowski, M. P.; García, E.; Gburek, T.; George, N.; Gulbrandsen, K.; Halliwell, C.; Hamblen, J.; Hauer, M.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Hołyński, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Khan, N.; Kulinich, P.; Kuo, C. M.; Lin, W. T.; Manly, S.; Mignerey, A. C.; Nouicer, R.; Olszewski, A.; Pak, R.; Reed, C.; Roland, C.; Roland, G.; Sagerer, J.; Seals, H.; Sedykh, I.; Smith, C. E.; Stankiewicz, M. A.; Steinberg, P.; Stephans, G. S. F.; Sukhanov, A.; Tonjes, M. B.; Trzupek, A.; Vale, C.; Nieuwenhuizen, G. J. Van; Vaurynovich, S. S.; Verdier, R.; Veres, G. I.; Wenger, E.; Wolfs, F. L. H.; Wosiek, B.; Woźniak, K.; Wysłouch, B.

    2007-02-01

    Transverse momentum spectra of pions, kaons, protons, and antiprotons from Au+Au collisions at sNN = 62.4 GeV have been measured by the PHOBOS experiment at the Relativistic Heavy Ion Collider at Brookhaven National Laboratory. The identification of particles relies on three different methods: low momentum particles stopping in the first detector layers; the specific energy loss (dE/dx) in the silicon spectrometer, and time-of-flight measurement. These methods cover the transverse momentum ranges 0.03 0.2, 0.2 1.0, and 0.5 3.0 GeV/c, respectively. Baryons are found to have substantially harder transverse momentum spectra than mesons. The pT region in which the proton to pion ratio reaches unity in central Au+Au collisions at sNN = 62.4 GeV fits into a smooth trend as a function of collision energy. At low transverse mass, the spectra of various species exhibit a significant deviation from transverse mass scaling. The observed particle yields at very low pT are comparable to extrapolations from higher pT for kaons, protons and antiprotons. By comparing our results to Au+Au collisions at sNN = 200 GeV, we conclude that the net proton yield at midrapidity is proportional to the number of participant nucleons in the collision.

  8. Amperometric Immunosensor for Carbofuran Detection Based on MWCNTs/GS-PEI-Au and AuNPs-Antibody Conjugate

    Directory of Open Access Journals (Sweden)

    Xiangyou Wang

    2013-04-01

    Full Text Available In this paper, an amperometric immunosensor for the detection of carbofuran was developed. Firstly, multiwall carbon nanotubes (MWCNTs and graphene sheets-ethyleneimine polymer-Au (GS-PEI-Au nanocomposites were modified onto the surface of a glass carbon electrode (GCE via self-assembly. The nanocomposites can increase the surface area of the GCE to capture a large amount of antibody, as well as produce a synergistic effect in the electrochemical performance. Then the modified electrode was coated with gold nanoparticles-antibody conjugate (AuNPs-Ab and blocked with BSA. The monoclonal antibody against carbofuran was covalently immobilized on the AuNPs with glutathione as a spacer arm. The morphologies of the GS-PEI-Au nanocomposites and the fabrication process of the immunosensor were characterized by X-ray diffraction (XRD, ultraviolet and visible absorption spectroscopy (UV-vis and scanning electron microscopy (SEM, respectively. Under optimal conditions, the immunosensor showed a wide linear range, from 0.5 to 500 ng/mL, with a detection limit of 0.03 ng/mL (S/N = 3. The as-constructed immunosensor exhibited notable performance features such as high specificity, good reproducibility, acceptable stability and regeneration performance. The results are mainly due to the excellent properties of MWCNTs, GS-PEI-Au nanocomposites and the covalent immobilization of Ab with free hapten binding sites for further immunoreaction. It provides a new avenue for amperometric immunosensor fabrication.

  9. Amperometric immunosensor for carbofuran detection based on MWCNTs/GS-PEI-Au and AuNPs-antibody conjugate.

    Science.gov (United States)

    Zhu, Ying; Cao, Yaoyao; Sun, Xia; Wang, Xiangyou

    2013-04-19

    In this paper, an amperometric immunosensor for the detection of carbofuran was developed. Firstly, multiwall carbon nanotubes (MWCNTs) and graphene sheets-ethyleneimine polymer-Au (GS-PEI-Au) nanocomposites were modified onto the surface of a glass carbon electrode (GCE) via self-assembly. The nanocomposites can increase the surface area of the GCE to capture a large amount of antibody, as well as produce a synergistic effect in the electrochemical performance. Then the modified electrode was coated with gold nanoparticles-antibody conjugate (AuNPs-Ab) and blocked with BSA. The monoclonal antibody against carbofuran was covalently immobilized on the AuNPs with glutathione as a spacer arm. The morphologies of the GS-PEI-Au nanocomposites and the fabrication process of the immunosensor were characterized by X-ray diffraction (XRD), ultraviolet and visible absorption spectroscopy (UV-vis) and scanning electron microscopy (SEM), respectively. Under optimal conditions, the immunosensor showed a wide linear range, from 0.5 to 500 ng/mL, with a detection limit of 0.03 ng/mL (S/N = 3). The as-constructed immunosensor exhibited notable performance features such as high specificity, good reproducibility, acceptable stability and regeneration performance. The results are mainly due to the excellent properties of MWCNTs, GS-PEI-Au nanocomposites and the covalent immobilization of Ab with free hapten binding sites for further immunoreaction. It provides a new avenue for amperometric immunosensor fabrication.

  10. Heterojunction metal-oxide-metal Au-Fe{sub 3}O{sub 4}-Au single nanowire device for spintronics

    Energy Technology Data Exchange (ETDEWEB)

    Reddy, K. M., E-mail: mrkongara@boisestate.edu; Punnoose, Alex; Hanna, Charles [Department of Physics, Boise State University, Boise, Idaho 83725 (United States); Padture, Nitin P. [School of Engineering, Brown University, Providence, Rhode Island 02912 (United States)

    2015-05-07

    In this report, we present the synthesis of heterojunction magnetite nanowires in alumina template and describe magnetic and electrical properties from a single nanowire device for spintronics applications. Heterojunction Au-Fe-Au nanowire arrays were electrodeposited in porous aluminum oxide templates, and an extensive and controlled heat treatment process converted Fe segment to nanocrystalline cubic magnetite phase with well-defined Au-Fe{sub 3}O{sub 4} interfaces as confirmed by the transmission electron microscopy. Magnetic measurements revealed Verwey transition shoulder around 120 K and a room temperature coercive field of 90 Oe. Current–voltage (I-V) characteristics of a single Au-Fe{sub 3}O{sub 4}-Au nanowire have exhibited Ohmic behavior. Anomalous positive magnetoresistance of about 0.5% is observed on a single nanowire, which is attributed to the high spin polarization in nanowire device with pure Fe{sub 3}O{sub 4} phase and nanocontact barrier. This work demonstrates the ability to preserve the pristine Fe{sub 3}O{sub 4} and well defined electrode contact metal (Au)–magnetite interface, which helps in attaining high spin polarized current.

  11. Effect of Au nano-particle aggregation on the deactivation of the AuCl3/AC catalyst for acetylene hydrochlorination.

    Science.gov (United States)

    Dai, Bin; Wang, Qinqin; Yu, Feng; Zhu, Mingyuan

    2015-01-01

    A detailed study of the valence state and distribution of the AuCl3/AC catalyst during the acetylene hydrochlorination deactivation process is described and discussed. Temperature-programmed reduction and X-ray photoelectron spectral analysis indicate that the active Au(3+) reduction to metallic Au(0) is one reason for the deactivation of AuCl3/AC catalyst. Transmission electron microscopy characterization demonstrated that the particle size of Au nano-particles increases with increasing reaction time. The results indicated that metallic Au(0) exhibits considerable catalytic activity and that Au nano-particle aggregation may be another reason for the AuCl3/AC catalytic activity in acetylene hydrochlorination. PMID:25994222

  12. Jet-Hadron Correlations in sqrt{s_{NN}} = 200 GeV Au+Au and p+p Collisions

    CERN Document Server

    Adamczyk, L; Agakishiev, G; Aggarwal, M M; Ahammed, Z; Alekseev, I; Alford, J; Anson, C D; Aparin, A; Arkhipkin, D; Aschenauer, E; Averichev, G S; Balewski, J; Banerjee, A; Barnovska, Z; Beavis, D R; Bellwied, R; Betancourt, M J; Betts, R R; Bhasin, A; Bhati, A K; Bhattarai,; Bichsel, H; Bielcik, J; Bielcikova, J; Bland, L C; Bordyuzhin, I G; Borowski, W; Bouchet, J; Brandin, A V; Brovko, S G; Bruna, E; Bültmann, S; Bunzarov, I; Burton, T P; Butterworth, J; Caines, H; Sánchez, M Calderón de la Barca; Cebra, D; Cendejas, R; Cervantes, M C; Chaloupka, P; Chang, Z; Chattopadhyay, S; Chen, H F; Chen, J H; Chen, J Y; Chen, L; Cheng, J; Cherney, M; Chikanian, A; Christie, W; Chung, P; Chwastowski, J; Codrington, M J M; Corliss, R; Cramer, J G; Crawford, H J; Cui, X; Das, S; Leyva, A Davila; De Silva, L C; Debbe, R R; Dedovich, T G; Deng, J; de Souza, R Derradi; Dhamija, S; di Ruzza, B; Didenko, L; Dilks,; Ding, F; Dion, A; Djawotho, P; Dong, X; Drachenberg, J L; Draper, J E; Du, C M; Dunkelberger, L E; Dunlop, J C; Efimov, L G; Elnimr, M; Engelage, J; Engle, K S; Eppley, G; Eun, L; Evdokimov, O; Fatemi, R; Fazio, S; Fedorisin, J; Fersch, R G; Filip, P; Finch, E; Fisyak, Y; Flores, C E; Gagliardi, C A; Gangadharan, D R; Garand, D; Geurts, F; Gibson, A; Gliske, S; Grebenyuk, O G; Grosnick, D; Guo, Y; Gupta, A; Gupta, S; Guryn, W; Haag, B; Hajkova, O; Hamed, A; Han, L-X; Haque, R; Harris, J W; Hays-Wehle, J P; Heppelmann, S; Hirsch, A; Hoffmann, G W; Hofman, D J; Horvat, S; Huang, B; Huang, H Z; Huck, P; Humanic, T J; Igo, G; Jacobs, W W; Jena, C; Judd, E G; Kabana, S; Kang, K; Kauder, K; Ke, H W; Keane, D; Kechechyan, A; Kesich, A; Kikola, D P; Kiryluk, J; Kisel, I; Kisiel, A; Koetke, D D; Kollegger, T; Konzer, J; Koralt, I; Korsch, W; Kotchenda, L; Kravtsov, P; Krueger, K; Kulakov, I; Kumar, L; Kycia, R A; Lamont, M A C; Landgraf, J M; Landry, K D; LaPointe, S; Lauret, J; Lebedev, A; Lednicky, R; Lee, J H; Leight, W; LeVine, M J; Li, C; Li, W; Li, X; Li, Y; Li, Z M; Lima, L M; Lisa, M A; Liu, F; Ljubicic, T; Llope, W J; Longacre, R S; Luo, X; Ma, G L; Ma, Y G; Don, D M M D Madagodagettige; Mahapatra, D P; Majka, R; Margetis, S; Markert, C; Masui, H; Matis, H S; McDonald, D; McShane, T S; Mioduszewski, S; Mitrovski, M K; Mohammed, Y; Mohanty, B; Mondal, M M; Munhoz, M G; Mustafa, M K; Naglis, M; Nandi, B K; Nasim, Md; Nayak, T K; Nelson, J M; Nogach, L V; Novak, J; Odyniec, G; Ogawa, A; Oh, K; Ohlson, A; Okorokov, V; Oldag, E W; Oliveira, R A N; Olson, D; Pachr, M; Page, B S; Pal, S K; Pan, Y X; Pandit, Y; Panebratsev, Y; Pawlak, T; Pawlik, B; Pei, H; Perkins, C; Peryt, W; Pile, P; Planinic, M; Pluta, J; Plyku, D; Poljak, N; Porter, J; Poskanzer, A M; Powell, C B; Pruneau, C; Pruthi, N K; Przybycien, M; Pujahari, P R; Putschke, J; Qiu, H; Ramachandran, S; Raniwala, R; Raniwala, S; Ray, R L; Riley, C K; Ritter, H G; Roberts, J B; Rogachevskiy, O V; Romero, J L; Ross, J F; Roy, A; Ruan, L; Rusnak, J; Sahoo, N R; Sahu, P K; Sakrejda, I; Salur, S; Sandacz, A; Sandweiss, J; Sangaline, E; Sarkar, A; Schambach, J; Scharenberg, R P; Schmah, A M; Schmidke, B; Schmitz, N; Schuster, T R; Seger, J; Seyboth, P; Shah, N; Shahaliev, E; Shao, M; Sharma, B; Sharma, M; Shen, W Q; Shi, S S; Shou, Q Y; Sichtermann, E P; Singaraju, R N; Skoby, M J; Smirnov, D; Smirnov, N; Solanki, D; Sorensen, P; deSouza, U G; Spinka, H M; Srivastava, B; Stanislaus, T D S; Stevens, J R; Stock, R; Strikhanov, M; Stringfellow, B; Suaide, A A P; Suarez, M C; Sumbera, M; Sun, X M; Sun, Y; Sun, Z; Surrow, B; Svirida, D N; Symons, T J M; de Toledo, A Szanto; Takahashi, J; Tang, A H; Tang, Z; Tarini, L H; Tarnowsky, T; Thomas, J H; Timmins, A R; Tlusty, D; Tokarev, M; Trentalange, S; Tribble, R E; Tribedy, P; Trzeciak, B A; Tsai, O D; Turnau, J; Ullrich, T; Underwood, D G; Van Buren, G; van Nieuwenhuizen, G; Vanfossen,, J A; Varma, R; Vasconcelos, G M S; Vertesi, R; Videbæk, F; Viyogi, Y P; Vokal, S; Voloshin, S A; Vossen, A; Wada, M; Walker, M; Wang, F; Wang, G; Wang, H; Wang, J S; Wang, Q; Wang, X L; Wang, Y; Webb, G; Webb, J C; Westfall, G D; Wieman, H; Wissink, S W; Witt, R; Wu, Y F; Xiao, Z; Xie, W; Xin, K; Xu, H; Xu, N; Xu, Q H; Xu, W; Xu, Y; Xu, Z; Yan,; Yang, C; Yang, Y; Yepes, P; Yi, L; Yip, K; Yoo, I-K; Zawisza, Y; Zbroszczyk, H; Zha, W; Zhang, J B; Zhang, S; Zhang, X P; Zhang, Y; Zhang, Z P; Zhao, F; Zhao, J; Zhong, C; Zhu, X; Zhu, Y H; Zoulkarneeva, Y; Zyzak, M

    2013-01-01

    Azimuthal angular correlations of charged hadrons with respect to the axis of a reconstructed (trigger) jet in Au+Au and p+p collisions at $\\sqrt{s_{NN}} = 200$ GeV in STAR are presented. The trigger jet population in Au+Au collisions is biased towards jets that have not interacted with the medium, allowing easier matching of jet energies between Au+Au and p+p collisions while enhancing medium effects on the recoil jet. The associated hadron yield of the recoil jet is significantly suppressed at high transverse momentum ($p_{T}^{assoc}$) and enhanced at low $p_{T}^{assoc}$ in Au+Au collisions, which is indicative of medium-induced parton energy loss in ultrarelativistic heavy-ion collisions.

  13. Transverse-energy distributions at midrapidity in $p$$+$$p$, $d$$+$Au, and Au$+$Au collisions at $\\sqrt{s_{_{NN}}}=62.4$--200~GeV and implications for particle-production models

    OpenAIRE

    Adler, S. S.; Afanasiev, S.; Aidala, C.; Ajitanand, N. N.; Akiba, Y; Al-Jamel, A.; Alexander, J.; Aoki, K.; Aphecetche, L.; Armendariz, R.; Aronson, S. H.; Averbeck, R.; Awes, T. C.; Azmoun, B.; Babintsev, V.

    2013-01-01

    Measurements of the midrapidity transverse energy distribution, $d\\Et/d\\eta$, are presented for $p$$+$$p$, $d$$+$Au, and Au$+$Au collisions at $\\sqrt{s_{_{NN}}}=200$ GeV and additionally for Au$+$Au collisions at $\\sqrt{s_{_{NN}}}=62.4$ and 130 GeV. The $d\\Et/d\\eta$ distributions are first compared with the number of nucleon participants $N_{\\rm part}$, number of binary collisions $N_{\\rm coll}$, and number of constituent-quark participants $N_{qp}$ calculated from a Glauber model based on th...

  14. Enantiospecific adsorption of cysteine on a chiral Au34 cluster

    Science.gov (United States)

    de Jesús Pelayo, José; Valencia, Israel; Díaz, Gabriela; López-Lozano, Xóchitl; Garzón, Ignacio L.

    2015-12-01

    The interaction of biological molecules like chiral amino acids with chiral metal clusters is becoming an interesting and active field of research because of its potential impact in, for example, chiral molecular recognition phenomena. In particular, the enantiospecific adsorption (EA) of cysteine (Cys) on a chiral Au55 cluster was theoretically predicted a few years ago. In this work, we present theoretical results, based on density functional theory, of the EA of non-zwitterionic cysteine interacting with the C3-Au34 chiral cluster, which has been experimentally detected in gas phase, using trapped ion electron diffraction. Our results show that, indeed, the adsorption energy of the amino acid depends on which enantiomers participate in the formation Cys-Au34 chiral complex. EA was obtained in the adsorption modes where both the thiol, and the thiol-amino functional groups of Cys are adsorbed on low-coordinated sites of the metal cluster surface. Similarly to what was obtained for the Cys-Au55 chiral complex, in the present work, it is found that the EA is originated from the different strength and location of the bond between the COOH functional group and surface Au atoms of the Au34 chiral cluster. Calculations of the vibrational spectrum for the different Cys-Au34 diastereomeric complexes predict the existence of a vibro-enantiospecific effect, indicating that the vibrational frequencies of the adsorbed amino acid depend on its handedness. Contribution to the Topical Issue "Atomic Cluster Collisions (7th International Symposium)", edited by G. Delgado Barrio, A. Solov'Yov, P. Villarreal, R. Prosmiti.

  15. A simple electrochemical biosensor based on AuNPs/MPS/Au electrode sensing layer for monitoring carbamate pesticides in real samples.

    Science.gov (United States)

    Song, Yonghai; Chen, Jingyi; Sun, Min; Gong, Coucong; Shen, Yuan; Song, Yonggui; Wang, Li

    2016-03-01

    A simple electrochemical biosensor for quantitative determination of carbamate pesticide was developed based on a sensing interface of citrate-capped gold nanoparticles (AuNPs)/(3-mercaptopropyl)-trimethoxysilane (MPS)/gold electrode (Au). The biosensor was fabricated by firstly assembling three-dimensional (3D) MPS networks on Au electrode and subsequently assembling citrate-capped AuNPs on 3D MPS network via AuS bond. The interface of AuNPs/MPS/Au was negatively charged originating from the citrate coated on AuNPs that would repulse the negatively charged ferricyanide ([Fe(CN)6](3-/4-)) to produce a negative response. In the presence of acetylcholinesterase (AChE) and acetylthiocholine (ATCl), the AChE catalyzes the hydrolysis of ATCl into positively charged thiocholine which would replace the citrate on AuNPs through the strong AuS bond and convert the negative charged surface to be positively charged. The resulted positively charged AuNPs/MPS/Au then attracted the [Fe(CN)6](3-/4-) to produce a positive response. Based on the inhibition of carbamate pesticides on the activity of AChE, the pesticide could be quantitatively determined at a very low potential. The linear range was from 0.003 to 2.00 μM. The sensing platform was also proved to be suitable for carbamate pesticides detection in practical sample.

  16. Efficient H2 production over Au/graphene/TiO2 induced by surface plasmon resonance of Au and band-gap excitation of TiO2

    International Nuclear Information System (INIS)

    Highlights: • Both surface plasmon resonance and band-gap excitation were used for H2 production. • Au/Gr/TiO2 composite photocatalyst was synthesized. • Au/Gr/TiO2 exhibited enhancement of light absorption and charge separation. • H2 production rate of Au/Gr/TiO2 was about 2 times as high as that of Au/TiO2. - Abstract: H2 production over Au/Gr/TiO2 composite photocatalyst induced by surface plasmon resonance of Au and band-gap excitation of TiO2 using graphene (Gr) as an electron acceptor has been investigated. Electron paramagnetic resonance study indicated that, in this composite, Gr collected electrons not only from Au with surface plasmon resonance but also from TiO2 with band-gap excitation. Surface photovoltage and UV–vis absorption measurements revealed that compared with Au/TiO2, Au/Gr/TiO2 displayed more effective photogenerated charge separation and higher optical absorption. Benefiting from these advantages, the H2 production rate of Au/Gr/TiO2 composite with Gr content of 1.0 wt% and Au content of 2.0 wt% was about 2 times as high as that of Au/TiO2. This work represents an important step toward the efficient application of both surface plasmon resonance and band-gap excitation on the way to converting solar light into chemical energy

  17. Chapitre 5. Robots au Japon : le futur se conjugue au présent

    OpenAIRE

    Barral, Étienne

    2016-01-01

    2015... Les analystes japonais aiment bien projeter leurs lecteurs dans le futur. En 2015 donc, selon le Rapport intérimaire du comité stratégique en robotique du ministère japonais de l’Économie, du Commerce et de l’Industrie, le marché de la robotique au Japon représentera 1,1 billion de yens (7,8 milliards d’euros). Une somme, déjà astronomique, à rapprocher de la production japonaise des ordinateurs personnels en 2005 : 1,6 billion de yens (10,8 milliards d’euros). Dans moins d’une décenn...

  18. Structure investigation of organic molecules on Au(111) surfaces; Strukturuntersuchung organischer Molekuele auf Au(111)-Oberflaechen

    Energy Technology Data Exchange (ETDEWEB)

    Kazempoor, Michel

    2009-02-02

    The present work covers two topics namely the coadsorption of formic acid and water on Au(111) and the structure of biphenylalkanthiole SAMs on Au(111) surfaces. The coadsorption of formic acid and water on Au(111) surfaces has been investigated by means of vibrational and photoelectron spectroscopy (HREELS, XPS). Formic acid adsorbs at 90 K molecularly with vibrational modes characteristic for flat lying zig-zag chains in the mono- and multilayer regime, like in solid formic acid. The structure of the flat lying formic acid chains was determined by low energy electron diffraction (LEED) as a (2r3 x r19) unit cell. Annealing results in a complete desorption at 190 K. Sequential adsorption of formic acid and water at 90 K shows no significant chemical interaction. Upon annealing the coadsorbed layer to 140 K a hydrogenbonded cyclic complex of formic acid with one water molecule could be identified using isotopically labelled adsorbates. Upon further annealing this complex decomposes leaving molecularly adsorbed formic acid on the surface at 160 K, accompanied by a proton exchange between formic acid and water. The influence of the alkane spacer chain length on the structure of biphenylalkanethiols on Au(111) surfaces was investigated as well. A systematic study was done on BPn-SAMs deposited from the gas phase. For every chain length a structure was found by LEED. Furthermore the influence of temperature on the structure was investigated in the range from room temperature up to about 400 K. To obviate influences from different preparation methods BP3 and BP4 was deposited from gas phase and from solution. No LEED spots were observed on BP4 SAMs deposited from solution. For BP3 an influence of the preparation could be excluded. For all BPn-SAMs a good agreement between LEED and STM data's was found. Nevertheless different unit cells were determined by LEED and STM consistent structures could be suggested considering the unit cell size given by LEED and the

  19. Massignon face au sionisme Massignon and Zionism

    Directory of Open Access Journals (Sweden)

    Agathe Mayeres

    2010-03-01

    Full Text Available En 1916, Louis Massignon participe aux négociations franco-britanniques qui envisagent, dans la perspective de la capitulation probable des empires centraux, le futur partage de l’Empire ottoman. Dans ce contexte, Massignon cherche à se situer face la question sioniste qui, pour lui, est avant tout un problème de politique orientale.Sous l’influence d'Aaron Aaronsohn, l’islamologue éprouve d’abord pour les pionniers d’Eretz Israel, au regard de leurs réalisations agricoles, une sympathie enthousiaste qui lui fait souhaiter la réussite de l’établissement du Foyer national juif en Palestine. Son engagement l’incite notamment à rédiger, conjointement avec Maritain, un « rapport sur le sionisme », adressé à Pie XI en 1925, dans le but d’obtenir du Saint-Siège un soutien pour les Juifs convertis au catholicisme qui souhaiteraient participer à l’œuvre commune de la résurrection d’Israël. Cependant, les procédés « colonisateurs » et l’athéisme affiché de nombreux dirigeants sionistes, allant à l’encontre des convictions religieuses des Arabes autochtones chrétiens et musulmans, provoquent peu à peu chez Massignon un revirement total qui lui dicte à l’égard des Juifs des « propos excessifs ». Massignon considère qu’en Terre Sainte, il est impossible de séparer le temporel du spirituel et que les faits doivent être lus à la lumière des événements de l’histoire religieuse qui s’y sont déroulés depuis Abraham, « premier héros de l’hospitalité ».La prise de conscience de la pureté de Marie lui paraît la condition nécessaire à une reconnaissance juive dans l’esprit du Patriarche, bien plus, un préalable à toute paix. Massignon voit dans l’Immaculée Conception le « signe marial » de ralliement des diverses confessions de la famille abrahamique.In 1916, facing the probable capitulation of the Central Powers, Louis Massignon participates in French

  20. Relégation au village

    Directory of Open Access Journals (Sweden)

    Nicolas Renahy

    2010-12-01

    Full Text Available Les thèses de l’individualisation des sociétés occidentales, ou de l’exclusion de ceux qui resteraient en marge d’une vaste classe moyenne aux modes de vie homogénéisés, ont sans doute permis de sortir d’une grille de lecture rigide héritée du marxisme. Mais elles résistent aujourd’hui mal aux faits et sont vivement contredites par le renouvellement des études sur les inégalités sociales pensées en termes de stratification. Enquêtant la population ouvrière d’un village industriel de Bourgogne au cours des années 1990, l’auteur a pu mesurer tout autant la force socialisatrice continue du groupe ouvrier sur sa jeunesse que le lent processus de délitement de ses cadres de références, longtemps stabilisés autour d’une mono-industrie métallurgique, provoquant une crise dans la reproduction de ce monde ouvrier. C’est cette crise de reproduction qui est évoquée ici. Dans un premier temps sont explicitées les formes passées de la présence industrielle au village, qui n’a jamais été celle d’un bastion de la grande industrie – la population locale n’est pas structurellement différenciée de celle de son environnement rural immédiat. L’exemple d’une lignée familiale d’artisans montre pour finir l’étroit maillage entre usine et structures sociales plus classiquement rurales, favorisant la constitution d’un capital d’autochtonie, déclinaison populaire du capital social.Relegation to the villageArguments demonstrating the individualisation of western societies, or the exclusion of those who stay on the margins of a vast middle class homogeneous life style, have no doubt allowed the move away from the rigid interpretations inherited from Marxism. However, these arguments resist today in spite of the facts and they are even keenly contradicted by the renewal of stratification studies on social inequalities. Analyzing the working population of an industrial village in Bourgogne during the

  1. Study of electrodepositing Au on hollow polystyrene microspheres

    Energy Technology Data Exchange (ETDEWEB)

    Jin Rong [Research Center of Laser Fusion, China Academy of Engineering Physics, P.O. Box 919-987, Mianyang 621900 (China); School of Material Science and Engineering, Xihua University, Chengdu 610039 (China); Zhang Yunwang [Research Center of Laser Fusion, China Academy of Engineering Physics, P.O. Box 919-987, Mianyang 621900 (China); Zhang Lin, E-mail: zhlmy@sina.com [Research Center of Laser Fusion, China Academy of Engineering Physics, P.O. Box 919-987, Mianyang 621900 (China); Wei Chengfu, E-mail: wcf@mail.xhu.edu.cn [School of Material Science and Engineering, Xihua University, Chengdu 610039 (China); Guo Jianjun [School of Material Science and Engineering, Xihua University, Chengdu 610039 (China)

    2013-01-15

    Highlights: Black-Right-Pointing-Pointer The gold is electrodeposited on hollow polystyrene microspheres by self-designed setup in this paper. Black-Right-Pointing-Pointer The Au electrodeposit is finer and more uniform on account of the microspheres freely move on the cathode. Black-Right-Pointing-Pointer The morphology, thickness and roughness of Au electrodeposits were analyzed using Scanning Electron Microscopy, X-ray diffraction and Atomic Force Microscope, respectively. - Abstract: The electrodeposited Au film on hollow polystyrene microspheres is successfully prepared by a set of self-designed device. The film is more compact and uniform on account of the microspheres freely moving on the cathode. These experiments mainly focus on the analysis of spherical symmetry, thickness and roughness of electrodeposited Au film. Under conditions of current density 1.5-3 mA cm{sup -2}, the temperature 25 Degree-Sign C, and the stirring rate 150 rpm, the electrodeposited microsphere is coated with a considerably orbicular film. The morphology, thickness and roughness of Au electrodeposits are studied by Scanning Electron Microscopy (SEM), X-ray diffraction (XRD) and Atomic Force Microscope (AFM), respectively.

  2. Observations of high spin states in {sup 179}Au

    Energy Technology Data Exchange (ETDEWEB)

    Carpenter, M.P.; Ahmad, I.; Blumenthal, D.J. [and others

    1995-08-01

    As part of a current study on the properties of the {pi} i{sub 13/2} intruder state in the A = 175-190 region, we conducted an experiment at ATLAS to observe high spin states in {sup 179}Au utilizing the reaction {sup 144}Sm({sup 40}Ar,p4n) at beam energies of 207 MeV and 215 MeV. To aid in the identification of {sup 179}Au, and to filter out the large amount of events from fission by-products, the Fragment Mass Analyzer was utilized in conjunction with ten Compton-suppression germanium detectors. In total, 11 x 10{sup 6} {gamma}-{gamma} and 4 x 10{sup 5} {gamma}-recoil events were collected. By comparing {gamma}-rays in coincidence with an A = 179 recoil mass gate and {gamma}-rays in coincidence with Au K{alpha} and K{beta} X-rays, ten {gamma}-rays were identified as belonging to {sup 179}Au. Based on {gamma}-ray coincidence relationships and on comparisons with neighboring odd-A Au nuclei, we constructed a tentative level scheme and assigned a rotational-like sequence to the {pi} i{sub 13/2} proton configuration.

  3. Collisional modelling of the AU Microscopii debris disc

    CERN Document Server

    Schüppler, Ch; Krivov, A V; Ertel, S; Marshall, J P; Wolf, S; Wyatt, M C; Augereau, J -C; Metchev, S A

    2015-01-01

    The spatially resolved AU Mic debris disc is among the most famous and best-studied debris discs. We aim at a comprehensive understanding of the dust production and the dynamics of the disc objects with in depth collisional modelling including stellar radiative and corpuscular forces. Our models are compared to a suite of observational data for thermal and scattered light emission, ranging from the ALMA radial surface brightness profile at 1.3mm to polarisation measurements in the visible. Most of the data can be reproduced with a planetesimal belt having an outer edge at around 40au and subsequent inward transport of dust by stellar winds. A low dynamical excitation of the planetesimals with eccentricities up to 0.03 is preferred. The radial width of the planetesimal belt cannot be constrained tightly. Belts that are 5au and 17au wide, as well as a broad 44au-wide belt are consistent with observations. All models show surface density profiles increasing with distance from the star as inferred from observatio...

  4. Exotic high activity surface patterns in PtAu nanoclusters

    KAUST Repository

    Mokkath, Junais Habeeb

    2013-05-09

    The structure and chemical ordering of PtAu nanoclusters of 79, 135, and 201 atoms are studied via a combination of a basin hopping atom-exchange technique (to locate the lowest energy homotops at fixed composition), a symmetry orbit technique (to find the high symmetry isomers), and density functional theory local reoptimization (for determining the most stable homotop). The interatomic interactions between Pt and Au are derived from the empirical Gupta potential. The lowest energy structures show a marked tendency toward PtcoreAushell chemical ordering by enrichment of the more cohesive Pt in the core region and of Au in the shell region. We observe a preferential segregation of Pt atoms to (111) facets and Au atoms to (100) facets of the truncated octahedron cluster motif. Exotic surface patterns are obtained particularly for Pt-rich compositions, where Pt atoms are being surrounded by Au atoms. These surface arrangements boost the catalytic activity by creating a large number of active sites. © 2013 American Chemical Society.

  5. L'APPRENTISSAGE AU CERN - French version only

    CERN Multimedia

    2003-01-01

    APPRENTISSAGES TECHNIQUES FORMATION ET DEVELOPPEMENT HR/TD/AP L'APPRENTISSAGE AU CERN pour les professions d'électronicien(ne) et de laborantin(e) en physique L'apprentissage au CERN est régi par les lois, règlements et contrats en vigueur dans le Canton de Genève. En cas de réussite à l'examen de fin d'apprentissage, les apprentis obtiennent le Certificat Fédéral de Capacité Suisse (CFC). 7 places au total sont ouvertes au recrutement pour les deux professions. L'apprentissage dure 4 ans. Minima requis pour faire acte de candidature : - avoir terminé la scolarité obligatoire - être ressortissant d'un pays membre du CERN (Allemagne, Autriche, Belgique, Bulgarie, Danemark, Espagne, Finlande, France, Grèce, Hongrie, Italie, Norvège, Pays-Bas, Pologne, Portugal, République slovaque, République tchèque, Royaume-Uni, Suède, Suisse) - avoir au moins 15 ans et moins de 21 ans à la date de début de l'apprentissage - avoir un niveau scolaire correspondant à la 9ème générale ou moderne...

  6. Interaction Kinetics between Sn-Pb Solder Droplet and Au/Ni/Cu Pad

    Institute of Scientific and Technical Information of China (English)

    Fuquan LI; Chunqing WANG; Yanhong TIAN

    2006-01-01

    The interfacial phenomena of the Sn-Pb solder droplet on Au/Ni/Cu pad are investigated. A continuous AuSn2and needle-like AuSn4 are formed at the interface after the liquid state reaction (soldering). The interfacial reaction between the solder and Au layer continues during solid state aging with AuSn4 breaking off from the interface and felling into the solder. The kinetics of Au layer dissolution and diffusion into the solder during soldering and aging is analyzed to elucidate intermetallic formation mechanism at the solder/Au pad interface.The concentration of Au near the solder/pad interface is identified to increase and reach the solubility limit during the period of liquid state reaction. During solid state reaction, the thickening of Au-Sn compound is mainly controlled by element diffusion.

  7. Ordered phase formation and diffusion composition path in Cu3Au/Pd couple

    International Nuclear Information System (INIS)

    EDX-TEM technique, IKL-ALCHEMI and Monte Carlo simulation were employed to reveal the relation between diffusion composition path and the ordered structures in Cu3Au/Pd diffusion couple annealed at 573 K. A Cu3Au layer including Pd, a CuAu layer including Pd, a CuPd layer and a Pd layer including Cu existed in sequence between Cu3Au and Pd. The Au concentration increased by up-hill diffusion from the Cu3Au layer to the CuAu layer, whereas Au scarcely diffused from the CuAu into the CuPd layer. The diffusion composition path deviated from the Cu3Au-Pd line in the Cu-Au-Pd Gibbs triangle and exhibited an 'S-shaped' curve through the CuAu and CuPd existence regions. The atomic configurations in the L10-type phase were highly ordered and consistent with the equilibrium state. In the Monte Carlo simulation, diffusion couples were virtually produced. The diffusion composition paths, Fourier power spectra and Warren-Cowley parameters were estimated in this way. The strong ordering interactions of the Cu-Au pair and Cu-Pd pair in the first nearest neighbor and the high activation barrier for migration of Au reproduced experimental results

  8. Atomic and electronic structures of Si(1 1 1)-(√3 x √3)R30°-Au and (6 × 6)-Au surfaces.

    Science.gov (United States)

    Patterson, C H

    2015-12-01

    Si(1 1 1)-Au surfaces with around one monolayer of Au exhibit many ordered structures and structures containing disordered domain walls. Hybrid density functional theory (DFT) calculations presented here reveal the origin of these complex structures and tendency to form domain walls. The conjugate honeycomb chain trimer (CHCT) structure of the [Formula: see text]-Au phase contains Si atoms with non-bonding surface states which can bind Au atoms in pairs in interstices of the CHCT structure and make this surface metallic. Si adatoms adsorbed on the [Formula: see text]-Au surface induce a gapped surface through interaction with the non-bonding states. Adsorption of extra Au atoms in interstitial sites of the [Formula: see text]-Au surface is stabilized by interaction with the non-bonding orbitals and leads to higher coverage ordered structures including the [Formula: see text]-Au phase. Extra Au atoms bound in interstitial sites of the [Formula: see text]-Au surface result in top layer Si atoms with an SiAu4 butterfly wing configuration. The structure of a [Formula: see text]-Au phase, whose in-plane top atomic layer positions were previously determined by an electron holography technique (Grozea et al 1998 Surf. Sci. 418 32), is calculated using total energy minimization. The Patterson function for this structure is calculated and is in good agreement with data from an in-plane x-ray diffraction study (Dornisch et al 1991 Phys. Rev. B 44 11221). Filled and empty state scanning tunneling microscopy (STM) images are calculated for domain walls and the [Formula: see text]-Au structure. The [Formula: see text]-Au phase is 2D chiral and this is evident in computed and actual STM images. [Formula: see text]-Au and domain wall structures contain the SiAu4 motif with a butterfly wing shape. Chemical bonding within the Si-Au top layers of the [Formula: see text]-Au and [Formula: see text]-Au surfaces is analyzed and an explanation for the SiAu4 motif structure is given. PMID

  9. Transverse momentum and centrality dependence of high-pt non-photonic electron suppression in Au+Au collisions at $\\sqrt{s_{NN}}$ = 200 GeV

    CERN Document Server

    Abelev, B I; Aggarwal, M M; Ahammed, Z; Amonett, J; Anderson, B D; Anderson, M; Arkhipkin, D; Averichev, G S; Bai, Y; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Bekele, S; Belaga, V V; Bellingeri-Laurikainen, A; Bellwied, R; Benedosso, F; Bhardwaj, S; Bhasin, A; Bhati, A K; Bichsel, H; Bielcik, J; Bielcikova, J; Bland, L C; Blyth, S L; Bonner, B E; Botje, M; Bouchet, J; Brandin, A V; Bravar, A; Bystersky, M; Cadman, R V; Cai, X Z; Caines, H; Calderón de la Barca-Sanchez, M; Castillo, J; Catu, O; Cebra, D; Chajecki, Z; Chaloupka, P; Chattopadhyay, S; Chen, H F; Chen, J H; Cheng, J; Cherney, M; Chikanian, A; Christie, W; Coffin, J P; Cormier, T M; Cosentino, M R; Cramer, J G; Crawford, H J; Das, D; Das, S; Daugherity, M; De Moura, M M; Dedovich, T G; De Phillips, M; Derevshchikov, A A; Didenko, L; Dietel, T; Djawotho, P; Dogra, S M; Dong, W J; Dong, X; Draper, J E; Du, F; Dunin, V B; Dunlop, J C; Dutta-Majumdar, M R; Eckardt, V; Edwards, W R; Efimov, L G; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Estienne, M; Fachini, P; Fatemi, R; Fedorisin, J; Filimonov, K; Filip, P; Finch, E; Fine, V; Fisyak, Yu; Fu, J; Gagliardi, C A; Gaillard, L; Ganti, M S; Ghazikhanian, V; Ghosh, P; González, J E; Gorbunov, Y G; Gos, H; Grebenyuk, O; Grosnick, D P; Guertin, S M; Guimaraes, K S F F; Guo, Y; Gupta, N; Gutíerrez, T D; Haag, B; Hallman, T J; Hamed, A; Harris, J W; He, W; Heinz, M; Henry, T W; Hepplemann, S; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Horner, M J; Huang, H Z; Huang, S L; Hughes, E W; Humanic, T J; Igo, G; Jacobs, P; Jacobs, W W; Jakl, P; Jia, F; Jiang, H; Jones, P G; Judd, E G; Kabana, S; Kang, K; Kapitan, J; Kaplan, M; Keane, D; Kechechyan, A; Khodyrev, V Yu; Kim, B C; Kiryluk, J; Kisiel, A; Kislov, E M; Klein, S R; Koetke, D D; Kollegger, T; Kopytine, M; Kotchenda, L; Kouchpil, V; Kowalik, K L; Krämer, M; Kravtsov, P; Kravtsov, V I; Krüger, K; Kuhn, C; Kulikov, A I; Kumar, A; Kuznetsov, A A; Lamont, M A C; Landgraf, J M; Lange, S; La Pointe, S; Laue, F; Lauret, J; Lebedev, A; Lednicky, R; Lee, C H; Lehocka, S; Le Vine, M J; Li, C; Li, Q; Li, Y; Lin, G; Lin, X; Lindenbaum, S J; Lisa, M A; Liu, F; Liu, H; Liu, J; Liu, L; Liu, Z; Ljubicic, T; Llope, W J; Long, H; Longacre, R S; López-Noriega, M; Love, W A; Lu, Y; Ludlam, T; Lynn, D; Ma, G L; Ma, J G; Ma, Y G; Magestro, D; Mahapatra, D P; Majka, R; Mangotra, L K; Manweiler, R; Margetis, S; Markert, C; Martin, L; Matis, H S; Matulenko, Yu A; McClain, C J; McShane, T S; Melnik, Yu M; Meschanin, A; Miller, M L; Minaev, N G; Mioduszewski, S; Mironov, C; Mischke, A; Mishra, D K; Mitchell, J; Mohanty, B; Molnár, L; Moore, C F; Morozov, D A; Munhoz, M G; Nandi, B K; Nattrass, C; Nayak, T K; Nelson, J M; Netrakanti, P K; Nikitin, V A; Nogach, L V; Nurushev, S B; Odyniec, Grazyna Janina; Ogawa, A; Okorokov, V; Oldenburg, M; Olson, D; Pachr, M; Pal, S K; Panebratsev, Yu A; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Peitzmann, T; Perevozchikov, V; Perkins, C; Peryt, W; Petrov, V A; Phatak, S C; Picha, R; Planinic, M; Pluta, J; Poljak, N; Porile, N; Porter, J; Poskanzer, A M; Potekhin, M V; Potrebenikova, E V; Potukuchi, B V K S; Prindle, D; Pruneau, C; Putschke, J; Rakness, G; Raniwala, R; Raniwala, S; Ray, R L; Razin, S V; Reinnarth, J; Relyea, D; Retière, F; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevski, O V; Romero, J L; Rose, A; Roy, C; Ruan, L; Russcher, M J; Sahoo, R; Salur, S; Sandweiss, J; Sarsour, M; Sazhin, P S; Schambach, J; Scharenberg, R P; Schmitz, N; Schweda, K; Seger, J; Selyuzhenkov, I; Seyboth, P; Shabetai, A; Shahaliev, E; Shao, M; Sharma, M; Shen, W Q; Shimansky, S S; Sichtermann, E P; Simon, F; Singaraju, R N; Smirnov, N; Snellings, R; Sood, G; Sørensen, P; Sowinski, J; Speltz, J; Spinka, H M; Srivastava, B; Stadnik, A; Stanislaus, T D S; Stock, R; Stolpovsky, A; Strikhanov, M N; Stringfellow, B C; Suaide, A A P; Sugarbaker, E R; Sumbera, M; Sun, Z; Surrow, B; Swanger, M; Symons, T J M; Szanto de Toledo, A; Tai, A; Takahashi, J; Tang, A H; Tarnowsky, T J; Thein, D; Thomas, J H; Timmins, A R; Timoshenko, S; Tokarev, M; Trainor, T A; Trentalange, S; Tribble, R E; Tsai, O D; Ulery, J; Ullrich, T; Underwood, D G; Van Buren, G; Van der Kolk, N; Van Leeuwen, M; Van der Molen, A M; Varma, R; Vasilevski, I M; Vasilev, A N; Vernet, R; Vigdor, S E; Viyogi, Y P; Vokal, S; Voloshin, S A; Waggoner, W T; Wang, F; Wang, G; Wang, J S; Wang, X L; Wang, Y; Watson, J W; Webb, J C; Westfall, G D; Wetzler, A; Whitten, C; Wieman, H; Wissink, S W; Witt, R; Wood, J; Wu, J; Xu, N; Xu, Q H; Xu, Z; Yepes, P; Yoo, I K; Yurevich, V I; Zhan, W; Zhang, H; Zhang, W M; Zhang, Y; Zhang, Z P; Zhao, Y; Zhong, C; Zoulkarneev, R; Zoulkarneeva, Y; Zubarev, A N; Zuo, J X; al, et

    2006-01-01

    The STAR collaboration at RHIC reports measurements of the inclusive yield of non-photonic electrons, which arise dominantly from semi-leptonic decays of heavy flavor mesons, over a broad range of transverse momenta ($1.2 < \\pt < 10$ \\gevc) in \\pp, \\dAu, and \\AuAu collisions at \\sqrtsNN = 200 GeV. The non-photonic electron yield exhibits unexpectedly large suppression in central \\AuAu collisions at high \\pt, suggesting substantial heavy quark energy loss in hot QCD matter. The centrality and \\pt dependences of the suppression provide stringent constraints on theoretical models of suppression.

  10. Characterization of freeze dried egg melange long stored after irradiation

    Science.gov (United States)

    Bakalivanov, Stefan; Tsvetkova, Eli; Bakalivanova, Todorka; Tsvetkov, Tsvetan; Kaloyanov, Nikolay; Grigorova, Stoyanka; Alexieva, Vanja

    2008-01-01

    During the 4-year period of storage at room temperature of the freeze-dried (control group) and the freeze-dried and gamma-irradiated (2.0 and 3.5 kGy) whole hen's egg mélange, no significant changes were found into the sensory and functional characteristics till the 28th month. The change in the number of SH groups was not unidirectional up to the 28th month and then it started to decrease in all investigated samples. During the entire period of investigation the amount of malondialdehyde in all three groups of egg mélange was considerably below the allowed limit for foodstuffs. The most significant fractions of the protein spectra showed a general tendency of decrease during the storage.

  11. Preparation and evaluation of Au nanoparticle–silica aerogel nanocomposite

    Directory of Open Access Journals (Sweden)

    Naruhito Katagiri

    2015-06-01

    Full Text Available A Au nanoparticle–silica aerogel nanocomposite was prepared by the gelling of a tetramethyl orthosilicate (TMOS/ethanol solution together with Au nanoparticles and drying the wet gel in supercritical carbon dioxide. The aerogel nanocomposite contained Au nanoparticles at a concentration of 0.268 ppm. The bulk density, porosity, and specific surface area of the obtained nanocomposite were 0.126 g/cm3, 94%, and 890 m2/g, respectively. The nanocomposite was reddish-violet in color and transparent, and had a relative permittivity of approximately 6 with a dielectric loss of ca. 1 × 10−3 in the range of 10 MHz to 1 GHz.

  12. Neutral atom transport from the termination shock to 1 AU

    CERN Document Server

    Bzowski, M; Bzowski, Maciej; Tarnopolski, Slawomir

    2006-01-01

    Dynamics of H, D, and heavy Energetic Neutral Atoms (ENA) between the termination shock and 1 AU is discussed in the context of the forthcoming NASA SMEX mission IBEX. In particular, effects of the velocity-dependent radiation pressure on atomic trajectories are considered and ionization losses between TS and 1 AU are studied. It is shown, among others, that most of the dynamical effects and ionization losses are induced within a few AU from the Sun, which translates to the time domain into $\\sim 1 - 3$ solar rotations before detection. This loosens considerably time requirements for tracking the ionization and radiation pressure history to just prior 3 months. ENA seem excellent tracers of the processes within the heliospheric interface, with the transport effects between the termination shock and detector relatively mild and easy to account for.

  13. Enhancing the reactivity of gold: Nanostructured Au(111) adsorbs CO

    Science.gov (United States)

    Hoffmann, F. M.; Hrbek, J.; Ma, S.; Park, J. B.; Rodriguez, J. A.; Stacchiola, D. J.; Senanayake, S. D.

    2016-08-01

    Low-coordinated sites are surface defects whose presence can transform a surface of inert or noble metal such as Au into an active catalyst. Starting with a well-ordered Au(111) surface we prepared by ion sputtering gold surfaces modified by pits, used microscopy (STM) for their structural characterization and CO spectroscopy (IRAS and NEXAFS) for probing reactivity of surface defects. In contrast to the Au(111) surface CO adsorbs readily on the pitted surfaces bonding to low-coordinated sites identified as step atoms forming {111} and {100} microfacets. Pitted nanostructured surfaces can serve as interesting and easily prepared models of catalytic surfaces with defined defects that offer an attractive alternative to vicinal surfaces or nanoparticles commonly employed in catalysis science.

  14. Hydrogen evolution on Au(111) covered with submonolayers of Pd

    DEFF Research Database (Denmark)

    Björketun, Mårten; Karlberg, Gustav; Rossmeisl, Jan;

    2011-01-01

    . The energetics of adsorption and desorption of hydrogen on/from different types of sites on the Pd-Au(111) surface are assessed by means of density functional theory calculations combined with thermodynamic modeling. Based on the density functional and Monte Carlo data, the hydrogen evolution activity......A theoretical investigation of electrochemical hydrogen evolution on Au(111) covered with submonolayers of Pd is presented. The size and shape of monoatomically high Pd islands formed on the Au(111) surface are determined using Monte Carlo simulations, for Pd coverages varying from 0.02 to 0.95 ML...... line defects for Pd island formation and hydrogen evolution are discussed. It is argued, with support from theoretical data, that this kind of defects is likely to be responsible for a dramatic increase in activity observed experimentally [ChemPhysChem 7, 985 (2006); Electrochim. Acta 52, 5548 (2007...

  15. The Adsorption of Nitromethane on the Au (111 Surface

    Directory of Open Access Journals (Sweden)

    F. Illas

    2001-11-01

    Full Text Available The density functional theory (DFT based hybrid-method B3LYP has been used to study the interaction of the nitromethane molecule (CH3NO2 with the Au(111 surface. The perfect Au(111 surface has been represented by a rather large cluster model, Au22, that was in turn used to extract information about the preferred adsorption geometry of the CH3NO2 species. In order to extract energetic information about the stability of adsorbed nitromethane, calculations were also performed for the gas-phase CH3NO2 molecule. The results obtained here are used to interpret experimental data. The computed geometry for adsorbed CH3NO2 agrees with the structure proposed from a previous experimental work.

  16. Controlled electrodeposition of Au monolayer film on ionic liquid

    Science.gov (United States)

    Ma, Qiang; Pang, Liuqing; Li, Man; Zhang, Yunxia; Ren, Xianpei; Liu, Shengzhong Frank

    2016-05-01

    Gold (Au) nanoparticles have been attractive for centuries for their vibrant appearance enhanced by their interaction with sunlight. Nowadays, there have been tremendous research efforts to develop them for high-tech applications including therapeutic agents, sensors, organic photovoltaics, medical applications, electronics and catalysis. However, there remains to be a challenge to fabricate a monolayer Au coating with complete coverage in controlled fashion. Here we present a facile method to deposit a uniform Au monolayer (ML) film on the [BMIM][PF6] ionic liquid substrate using an electrochemical deposition process. It demonstrates that it is feasible to prepare a solid phase coating on the liquid-based substrate. Moreover, the thickness of the monolayer coating can be controlled to a layer-by-layer accuracy.

  17. Fermi surfaces of surface states on Si(111)-Ag, Au

    Science.gov (United States)

    Crain, J. N.; Altmann, K. N.; Bromberger, C.; Himpsel, F. J.

    2002-11-01

    Metallic surface states on semiconducting substrates provide an opportunity to study low-dimensional electrons decoupled from the bulk. Angle resolved photoemission is used to determine the Fermi surface, group velocity, and effective mass for surface states on Si(111)(3)×(3)-Ag, Si(111)(3)×(3)-Au, and Si(111)(21)×(21)-(Ag+Au). For Si(111)(3)×(3)-Ag the Fermi surface consists of small electron pockets populated by electrons from a few % excess Ag. For Si(111)(21)×(21)-(Ag+Au) the pockets increase their size corresponding to a filling by three electrons per unit cell. The (21)×(21) superlattice leads to an intricate surface umklapp pattern and to minigaps of 110 meV, giving an interaction potential of 55 meV for the (21)×(21) superlattice.

  18. Plasmonic Fano resonances in compositional heterogenous Al- Au nanorod dimers

    Science.gov (United States)

    Wu, Botao; Xue, Yingxian; Ma, Qiang; Ding, Chengjie; Rong, Youying; Liu, Yan; Chen, Lingxiao; Wu, E.; Zeng, Heping

    2016-01-01

    We have investigated theoretically the plasmon resonance coupling in compositional heterogenous Al-Au nanorod dimers organized in a close proximity by end-to-end. It has been proved that the destructive interference between the bright dipole mode from Al nanorod and the dark quadrupole mode from Au nanorod nearby results in the appearance of apparent Fano resonance in the extinction spectra. The Fano resonance response on the structural dimension modifications in the proposed nanorod dimers have been estimated and determined. The Al-Au heterogeneous nanorod dimer shows a high sensitivity to the surrounding environment with a local surface plasmon resonance figure of merit of 7.6, which enables its promising applications in plasmonic sensing and detection.

  19. Final Technical Report: First Principles Investigations for the Ensemble Effects of PdAu and PtAu Bimetallic Nanocatalysts

    Energy Technology Data Exchange (ETDEWEB)

    Ruqian Wu

    2012-05-18

    Bimetallic surfaces with tunable chemical properties have attracted broad attention in recent years due to their ample potential for heterogeneous catalysis applications. The local chemical properties of constituents are strongly altered from their parent metals by 'ligand effect', a term encompassing the influences of charge transfer, orbital rehybridization and lattice strain. In comparison to the aforementioned, the 'ensemble effect' associated with particular arrangements of the active constituents have received much less attention, despite their notable importance towards the determination of reactivity and selectivity of bimetallic catalysts. We performed theoretical studies for understanding the ensemble effects on bimetallic catalysis: (i) simulations for the formation of different ensembles on PdAu and PtAu nanoclusters; (ii) studies of the size, shape, and substrate dependence of their electronic properties; and (iii) simulations for model reactions such as CO oxidation, methanol, ethylene and water dehydrogenation on PdAu and PtAu nanoclusters. In close collaboration with leading experimental groups, our theoretical research elucidated the fundamentals of Au based bimetallic nanocatalysts.

  20. Measurement of direct photons in Au+Au collisions at √(s(NN))=200 GeV.

    Science.gov (United States)

    Afanasiev, S; Aidala, C; Ajitanand, N N; Akiba, Y; Al-Jamel, A; Alexander, J; Aoki, K; Aphecetche, L; Armendariz, R; Aronson, S H; Averbeck, R; Awes, T C; Azmoun, B; Babintsev, V; Baldisseri, A; Barish, K N; Barnes, P D; Bassalleck, B; Bathe, S; Batsouli, S; Baublis, V; Bauer, F; Bazilevsky, A; Belikov, S; Bennett, R; Berdnikov, Y; Bjorndal, M T; Boissevain, J G; Borel, H; Boyle, K; Brooks, M L; Brown, D S; Bucher, D; Buesching, H; Bumazhnov, V; Bunce, G; Burward-Hoy, J M; Butsyk, S; Campbell, S; Chai, J-S; Chernichenko, S; Chi, C Y; Chiba, J; Chiu, M; Choi, I J; Chujo, T; Cianciolo, V; Cleven, C R; Cobigo, Y; Cole, B A; Comets, M P; Connors, M; Constantin, P; Csanád, M; Csörgő, T; Dahms, T; Das, K; David, G; Delagrange, H; Denisov, A; d'Enterria, D; Deshpande, A; Desmond, E J; Dietzsch, O; Dion, A; Drachenberg, J L; Drapier, O; Drees, A; Dubey, A K; Durum, A; Dzhordzhadze, V; Efremenko, Y V; Egdemir, J; Enokizono, A; En'yo, H; Espagnon, B; Esumi, S; Fields, D E; Fleuret, F; Fokin, S L; Forestier, B; Fraenkel, Z; Frantz, J E; Franz, A; Frawley, A D; Fukao, Y; Fung, S-Y; Gadrat, S; Gastineau, F; Germain, M; Glenn, A; Gonin, M; Gosset, J; Goto, Y; Granier de Cassagnac, R; Grau, N; Greene, S V; Grosse Perdekamp, M; Gunji, T; Gustafsson, H-Å; Hachiya, T; Hadj Henni, A; Haggerty, J S; Hagiwara, M N; Hamagaki, H; Harada, H; Hartouni, E P; Haruna, K; Harvey, M; Haslum, E; Hasuko, K; Hayano, R; He, X; Heffner, M; Hemmick, T K; Heuser, J M; Hiejima, H; Hill, J C; Hobbs, R; Holmes, M; Holzmann, W; Homma, K; Hong, B; Horaguchi, T; Hur, M G; Ichihara, T; Iinuma, H; Imai, K; Imrek, J; Inaba, M; Isenhower, D; Isenhower, L; Ishihara, M; Isobe, T; Issah, M; Isupov, A; Jacak, B V; Jia, J; Jin, J; Jinnouchi, O; Johnson, B M; Joo, K S; Jouan, D; Kajihara, F; Kametani, S; Kamihara, N; Kaneta, M; Kang, J H; Kawagishi, T; Kazantsev, A V; Kelly, S; Khanzadeev, A; Kim, D J; Kim, E; Kim, Y-S; Kinney, E; Kiss, A; Kistenev, E; Kiyomichi, A; Klein-Boesing, C; Kochenda, L; Kochetkov, V; Komkov, B; Konno, M; Kotchetkov, D; Kozlov, A; Kroon, P J; Kunde, G J; Kurihara, N; Kurita, K; Kweon, M J; Kwon, Y; Kyle, G S; Lacey, R; Lajoie, J G; Lebedev, A; Le Bornec, Y; Leckey, S; Lee, D M; Lee, M K; Leitch, M J; Leite, M A L; Li, X H; Lim, H; Litvinenko, A; Liu, M X; Maguire, C F; Makdisi, Y I; Malakhov, A; Malik, M D; Manko, V I; Masui, H; Matathias, F; McCain, M C; McGaughey, P L; Miake, Y; Miller, T E; Milov, A; Mioduszewski, S; Mishra, G C; Mitchell, J T; Morrison, D P; Moss, J M; Moukhanova, T V; Mukhopadhyay, D; Murata, J; Nagamiya, S; Nagata, Y; Nagle, J L; Naglis, M; Nakamura, T; Newby, J; Nguyen, M; Norman, B E; Nyanin, A S; Nystrand, J; O'Brien, E; Ogilvie, C A; Ohnishi, H; Ojha, I D; Okada, K; Omiwade, O O; Oskarsson, A; Otterlund, I; Ozawa, K; Pak, R; Pal, D; Palounek, A P T; Pantuev, V; Papavassiliou, V; Park, J; Park, W J; Pate, S F; Pei, H; Peng, J-C; Pereira, H; Peresedov, V; Peressounko, D Yu; Pinkenburg, C; Pisani, R P; Purschke, M L; Purwar, A K; Qu, H; Rak, J; Ravinovich, I; Read, K F; Reuter, M; Reygers, K; Riabov, V; Riabov, Y; Roche, G; Romana, A; Rosati, M; Rosendahl, S S E; Rosnet, P; Rukoyatkin, P; Rykov, V L; Ryu, S S; Sahlmueller, B; Saito, N; Sakaguchi, T; Sakai, S; Samsonov, V; Sato, H D; Sato, S; Sawada, S; Semenov, V; Seto, R; Sharma, D; Shea, T K; Shein, I; Shibata, T-A; Shigaki, K; Shimomura, M; Shohjoh, T; Shoji, K; Sickles, A; Silva, C L; Silvermyr, D; Sim, K S; Singh, C P; Singh, V; Skutnik, S; Smith, W C; Soldatov, A; Soltz, R A; Sondheim, W E; Sorensen, S P; Sourikova, I V; Staley, F; Stankus, P W; Stenlund, E; Stepanov, M; Ster, A; Stoll, S P; Sugitate, T; Suire, C; Sullivan, J P; Sziklai, J; Tabaru, T; Takagi, S; Takagui, E M; Taketani, A; Tanaka, K H; Tanaka, Y; Tanida, K; Tannenbaum, M J; Taranenko, A; Tarján, P; Thomas, T L; Togawa, M; Tojo, J; Torii, H; Towell, R S; Tram, V-N; Tserruya, I; Tsuchimoto, Y; Tuli, S K; Tydesjö, H; Tyurin, N; Vale, C; Valle, H; van Hecke, H W; Velkovska, J; Vértesi, R; Vinogradov, A A; Vznuzdaev, E; Wagner, M; Wang, X R; Watanabe, Y; Wessels, J; White, S N; Willis, N; Winter, D; Woody, C L; Wysocki, M; Xie, W; Yanovich, A; Yokkaichi, S; Young, G R; Younus, I; Yushmanov, I E; Zajc, W A; Zaudtke, O; Zhang, C; Zimányi, J; Zolin, L

    2012-10-12

    We report the measurement of direct photons at midrapidity in Au+Au collisions at √(s(NN))=200 GeV. The direct photon signal was extracted for the transverse momentum range of 4 GeV/cAu+Au collision centralities using the measured p+p direct photon spectrum and compared to theoretical predictions. R(AA) was found to be consistent with unity for all centralities over the entire measured p(T) range. Theoretical models that account for modifications of initial direct photon production due to modified parton distribution functions in Au and the different isospin composition of the nuclei predict a modest change of R(AA) from unity. They are consistent with the data. Models with compensating effects of the quark-gluon plasma on high-energy photons, such as suppression of jet-fragmentation photons and induced-photon bremsstrahlung from partons traversing the medium, are also consistent with this measurement. PMID:23102300

  1. Template-directed synthesis, characterization and electrical properties of Au-TiO2-Au heterojunction nanowires

    International Nuclear Information System (INIS)

    The feasibility of synthesizing metal-oxide-metal (MOM) heterojunction nanowires in the Au-TiO2-Au system is demonstrated. The synthesis method presented here entails sequential electroplating of Au and electro-deposition of amorphous titanium oxide (TiOx) inside nanoholes of anodic aluminium oxide (AAO) templates. This is followed by dissolving the template, and heat-treating the released nanowires, which results in the crystallization of the amorphous TiOx segment into nanocrystalline TiO2. Detailed transmission electron microscopy (TEM) investigation has revealed that the nanocrystalline TiO2 is orthorhombic (columbite) phase primarily. This synthesis method has the potential to provide better control over the characteristics and architectures of the resulting MOM nanowires. The Au-TiO2-Au nanowires were incorporated into single-nanowire devices, fabricated using a direct-write method. Nonlinear current-voltage (I-V) responses were obtained for individual MOM nanowires. The heterojunctions in such MOM nanowires are likely to offer certain advantages over all-oxide nanowires, making the MOM nanowires potentially useful as one-dimensional building blocks in the multifunctional nanoelectronics of the future

  2. Measurement of Direct Photons in Au+Au Collisions at sqrt(s_NN) = 200 GeV

    CERN Document Server

    Afanasiev, S; Ajitanand, N N; Akiba, Y; Al-Jamel, A; Alexander, J; Aoki, K; Aphecetche, L; Armendariz, R; Aronson, S H; Averbeck, R; Awes, T C; Azmoun, B; Babintsev, V; Baldisseri, A; Barish, K N; Barnes, P D; Bassalleck, B; Bathe, S; Batsouli, S; Baublis, V; Bauer, F; Bazilevsky, A; Belikov, S; Bennett, R; Berdnikov, Y; Bjorndal, M T; Boissevain, J G; Borel, H; Boyle, K; Brooks, M L; Brown, D S; Bucher, D; Buesching, H; Bumazhnov, V; Bunce, G; Burward-Hoy, J M; Butsyk, S; Campbell, S; Chai, J -S; Chernichenko, S; Chi, C Y; Chiba, J; Chiu, M; Choi, I J; Chujo, T; Cianciolo, V; Cleven, C R; Cobigo, Y; Cole, B A; Comets, M P; Connors, M; Constantin, P; Csanád, M; Csörgő, T; Dahms, T; Das, K; David, G; Delagrange, H; Denisov, A; d'Enterria, D; Deshpande, A; Desmond, E J; Dietzsch, O; Dion, A; Drachenberg, J L; Drapier, O; Drees, A; Dubey, A K; Durum, A; Dzhordzhadze, V; Efremenko, Y V; Egdemir, J; Enokizono, A; En'yo, H; Espagnon, B; Esumi, S; Fields, D E; Fleuret, F; Fokin, S L; Forestier, B; Fraenkel, Z; Frantz, J E; Franz, A; Frawley, A D; Fukao, Y; Fung, S -Y; Gadrat, S; Gastineau, F; Germain, M; Glenn, A; Gonin, M; Gosset, J; Goto, Y; de Cassagnac, R Granier; Grau, N; Greene, S V; Perdekamp, M Grosse; Gunji, T; Gustafsson, H -Å; Hachiya, T; Henni, A Hadj; Haggerty, J S; Hagiwara, M N; Hamagaki, H; Harada, H; Hartouni, E P; Haruna, K; Harvey, M; Haslum, E; Hasuko, K; Hayano, R; He, X; Heffner, M; Hemmick, T K; Heuser, J M; Hiejima, H; Hill, J C; Hobbs, R; Holmes, M; Holzmann, W; Homma, K; Hong, B; Horaguchi, T; Hur, M G; Ichihara, T; Iinuma, H; Imai, K; Imrek, J; Inaba, M; Isenhower, D; Isenhower, L; Ishihara, M; Isobe, T; Issah, M; Isupov, A; Jacak, B V; Jia, J; Jin, J; Jinnouchi, O; Johnson, B M; Joo, K S; Jouan, D; Kajihara, F; Kametani, S; Kamihara, N; Kaneta, M; Kang, J H; Kawagishi, T; Kazantsev, A V; Kelly, S; Khanzadeev, A; Kim, D J; Kim, E; Kim, Y -S; Kinney, E; Kiss, Á; Kistenev, E; Kiyomichi, A; Klein-Boesing, C; Kochenda, L; Kochetkov, V; Komkov, B; Konno, M; Kotchetkov, D; Kozlov, A; Kroon, P J; Kunde, G J; Kurihara, N; Kurita, K; Kweon, M J; Kwon, Y; Kyle, G S; Lacey, R; Lajoie, J G; Lebedev, A; Bornec, Y Le; Leckey, S; Lee, D M; Lee, M K; Leitch, M J; Leite, M A L; Li, X H; Lim, H; Litvinenko, A; Liu, M X; Maguire, C F; Makdisi, Y I; Malakhov, A; Malik, M D; Manko, V I; Masui, H; Matathias, F; McCain, M C; McGaughey, P L; Miake, Y; Miller, T E; Milov, A; Mioduszewski, S; Mishra, G C; Mitchell, J T; Morrison, D P; Moss, J M; Moukhanova, T V; Mukhopadhyay, D; Murata, J; Nagamiya, S; Nagata, Y; Nagle, J L; Naglis, M; Nakamura, T; Newby, J; Nguyen, M; Norman, B E; Nyanin, A S; Nystrand, J; O'Brien, E; Ogilvie, C A; Ohnishi, H; Ojha, I D; Okada, K; Omiwade, O O; Oskarsson, A; Otterlund, I; Ozawa, K; Pal, D; Palounek, A P T; Pantuev, V; Papavassiliou, V; Park, J; Park, W J; Pate, S F; Pei, H; Peng, J -C; Pereira, H; Peresedov, V; Peressounko, D Yu; Pinkenburg, C; Pisani, R P; Purschke, M L; Purwar, A K; Qu, H; Rak, J; Ravinovich, I; Read, K F; Reuter, M; Reygers, K; Riabov, V; Riabov, Y; Roche, G; Romana, A; Rosati, M; Rosendahl, S S E; Rosnet, P; Rukoyatkin, P; Rykov, V L; Ryu, S S; Sahlmueller, B; Saito, N; Sakaguchi, T; Sakai, S; Samsonov, V; Sato, H D; Sato, S; Sawada, S; Semenov, V; Seto, R; Sharma, D; Shea, T K; Shein, I; Shibata, T -A; Shigaki, K; Shimomura, M; Shohjoh, T; Shoji, K; Sickles, A; Silva, C L; Silvermyr, D; Sim, K S; Singh, C P; Singh, V; Skutnik, S; Smith, W C; Soldatov, A; Soltz, R A; Sondheim, W E; Sorensen, S P; Sourikova, I V; Staley, F; Stankus, P W; Stenlund, E; Stepanov, M; Ster, A; Stoll, S P; Sugitate, T; Suire, C; Sullivan, J P; Sziklai, J; Tabaru, T; Takagi, S; Takagui, E M; Taketani, A; Tanaka, K H; Tanaka, Y; Tanida, K; Tannenbaum, M J; Taranenko, A; Tarján, P; Thomas, T L; Togawa, M; Tojo, J; Torii, H; Towell, R S; Tram, V-N; Tserruya, I; Tsuchimoto, Y; Tuli, S K; Tydesjö, H; Tyurin, N; Vale, C; Valle, H; van Hecke, H W; Velkovska, J; Vértesi, R; Vinogradov, A A; Vznuzdaev, E; Wagner, M; Wang, X R; Watanabe, Y; Wessels, J; White, S N; Willis, N; Winter, D; Woody, C L; Wysocki, M; Xie, W; Yanovich, A; Yokkaichi, S; Young, G R; Younus, I; Yushmanov, I E; Zajc, W A; Zaudtke, O; Zhang, C; Zimányi, J; Zolin, L

    2012-01-01

    We report the measurement of direct photons at midrapidity in Au+Au collisions at sqrt{s_NN} = 200 GeV. The direct photon signal was extracted for the transverse-momentum range of 4 GeV/c < p_T < 22 GeV/c, using a statistical method to subtract decay photons from the inclusive-photon sample. The direct-photon nuclear-modification factor R_AA was calculated as a function of p_T for different Au+Au collision centralities using the measured p+p direct-photon spectrum and compared to theoretical predictions. R_AA was found to be consistent with unity for all centralities over the entire measured p_T range. Theoretical models that account for modifications of initial-direct-photon production due to modified-parton-distribution functions in Au and the different isospin composition of the nuclei, predict a modest change of R_AA from unity and are consistent with the data. Models with compensating effects of the quark-gluon plasma on high-energy photons, such as suppression of jet-fragmentation photons and indu...

  3. Potential energies of characteristic atoms on basis of experimental heats of formation of AuCu and AuCu_3 compounds (Ⅰ)

    Institute of Scientific and Technical Information of China (English)

    XIE You-qing; LIU Xin-bi; LI Xiao-bo; PENG Hong-jian; NIE Yao-zhuang

    2009-01-01

    The systematic science of alloys(SSA) is a framework of the total energy and total volume able to be separated. The potential energy sequences of characteristic atoms at the central sites of the basic clusters in the fcc-based lattice Au-Cu system are separated out from smaller experimental heats of formation of L10-AuCu and L1_2-AuCu_3 compounds only, by nine potential energy E-functions and through the use of structural unit inversion method. From these potential energy sequences, the potential energies and heats of formation of the disordered Au1-xCux alloys at 0 K are calculated. The potential energies, heats of formation and Tc-temperatures of order-disorder transitions of the L1_0-AuCu, L1_2-Au_3Cu and L1_2-AuCu_3 compounds, as well as the Au_3Cu-, AuCu- and AuCu_3~- type ordered alloys with maximal ordering degrees are calculated too. The results show that the 5th E-function may be chosen for developing it into the free energy-, enthalpy-, vibrational energy- and vibrational entropy-functions for describing thermodynamic properties of the compounds, ordered and disordered phases and for establishing the phase diagram of the Au-Cu system in the future.

  4. Common Suppression Pattern of eta and pi^0 Mesons at High Transverse Momentum in Au+Au Collisions at sqrt(s_NN) = 200 GeV

    CERN Document Server

    Adler, S S; Aidala, C; Ajitanand, N N; Akiba, Y; Alexander, J; Amirikas, R; Aphecetche, L; Aronson, S H; Averbeck, R; Awes, T C; Azmoun, R; Babintsev, V; Baldisseri, Alberto; Barish, K N; Barnes, P D; Bassalleck, B; Bathe, S; Batsouli, S; Baublis, V; Bazilevsky, A; Belikov, S; Berdnikov, Y; Bhagavatula, S; Boissevain, J G; Borel, H; Borenstein, S R; Brooks, M L; Brown, D S; Bruner, N; Bucher, D; Büsching, H; Bumazhnov, V; Bunce, G; Burward-Hoy, J M; Butsyk, S; Camard, X; Chai, J S; Chand, P; Chang, W C; Chernichenko, S; Chi, C Y; Chiba, J; Chiu, M; Choi, I J; Choi, J; Choudhury, R K; Chujo, T; Cianciolo, V; Cobigo, Y; Cole, B A; Constantin, P; D'Enterria, D G; Dávid, G; Delagrange, H; Denisov, A; Deshpande, Abhay A; Desmond, E J; Devismes, A; Dietzsch, O; Drapier, O; Drees, A; Du Rietz, R; Durum, A; Dutta, D; Efremenko, Yu V; El-Chenawi, K F; Enokizono, A; Enyo, H; Esumi, S; Ewell, L; Fields, D E; Fleuret, F; Fokin, S L; Fox, B D; Fraenkel, Zeev; Frantz, J E; Franz, A; Frawley, A D; Fung, S Y; Garpman, S; Ghosh, frontmatter@1T K; Glenn, A; Gogiberidze, G; Gonin, M; Gosset, J; Goto, Y; Granier de Cassagnac, R; Grau, N; Greene, S V; Grosse-Perdekamp, M; Guryn, W; Gustafsson, Hans Åke; Hachiya, T; Haggerty, J S; Hamagaki, H; Hansen, A G; Hartouni, E P; Harvey, M; Hayano, R; Hayashi, N; He, X; Heffner, M; Hemmick, T K; Heuser, J M; Hibino, M; Hiejima, H; Hill, J C; Holzmann, W; Homma, K; Hong, B; Hoover, A; Ichihara, T; Ikonnikov, V V; Imai, K; Isenhower, D; Ishihara, M; Issah, M; Isupov, A; Jacak, B V; Jang, W Y; Jeong, Y; Jia, J; Jinnouchi, O; Johnson, B M; Johnson, S C; Joo, K S; Jouan, D; Kametani, S; Kamihara, N; Kang, J H; Kapoor, S S; Katou, K; Kelly, S; Khachaturov, B; Khanzadeev, A; Kikuchi, J; Kim, D H; Kim, D J; Kim, D W; Kim, E; Kim, G B; Kim, H J; Kistenev, E P; Kiyomichi, A; Kiyoyama, K; Klein-Bösing, C; Kobayashi, H; Kochenda, L; Kochetkov, V; Koehler, D; Kohama, T; Kopytine, M; Kotchetkov, D; Kozlov, A; Kroon, P J; Kuberg, C H; Kurita, K; Kuroki, Y; Kweon, M J; Kwon, Y; Kyle, G S; Lacey, R; Ladygin, V; Lajoie, J G; Lebedev, A; Leckey, S; Lee, D M; Lee, S; Leitch, M J; Li, X H; Lim, H; Litvinenko, A; Liu, M X; Liu, Y; Maguire, C F; Makdisi, Y I; Malakhov, A; Man'ko, V I; Mao, Y; Martínez, G; Marx, M D; Masui, H; Matathias, F; Matsumoto, T; McGaughey, P L; Melnikov, E A; Messer, F; Miake, Y; Milan, J; Miller, T E; Milov, A; Mioduszewski, S; Mischke, R E; Mishra, G C; Mitchell, J T; Mohanty, A K; Morrison, D P; Moss, J M; Muhlbacher, F; Mukhopadhyay, D; Muniruzzaman, M; Murata, J; Nagamiya, S; Nagle, J L; Nakamura, T; Nandi, B K; Nara, M; Newby, J; Nilsson, P; Nyanin, A S; Nystrand, J; O'Brien, E; Ogilvie, C A; Ohnishi, H; Ojha, I D; Okada, K; Ono, M; Onuchin, V; Oskarsson, A; Otterlund, I; Oyama, K; Ozawa, K; Pal, D; Palounek, A P T; Pantuev, V S; Papavassiliou, V; Park, J; Parmar, A; Pate, S F; Peitzmann, T; Peng, J C; Peresedov, V; Pinkenburg, C; Pisani, R P; Plasil, F; Purschke, M L; Purwar, A K; Rak, J; Ravinovich, I; Read, K F; Reuter, M; Reygers, K; Riabov, V; Riabov, Y; Roche, G; Romana, A; Rosati, M; Rosnet, P; Ryu, S S; Sadler, M E; Sahlmueller, B; Saitô, N; Sakaguchi, T; Sakai, M; Sakai, S; Samsonov, V; Sanfratello, L; Santo, R; Sato, H D; Sato, S; Sawada, S; Schutz, Y; Semenov, V; Seto, R; Shaw, M R; Shea, T K; Shibata, T A; Shigaki, K; Shiina, T; Silva, C L; Silvermyr, D; Sim, K S; Singh, C P; Singh, V; Sivertz, M; Soldatov, A; Soltz, R A; Sondheim, W E; Sørensen, S P; Sourikova, I V; Staley, F; Stankus, P W; Stenlund, E; Stepanov, M; Ster, A; Stoll, S P; Sugitate, T; Sullivan, J P; Takagui, E M; Taketani, A; Tamai, M; Tanaka, K H; Tanaka, Y; Tanida, K; Tannenbaum, M J; Tarjan, P; Tepe, J D; Thomas, T L; Tojo, J; Torii, H; Towell, R S; Tserruya, Itzhak; Tsuruoka, H; Tuli, S K; Tydesjo, H; Tyurin, N; van Hecke, H W; Velkovska, J; Velkovsky, M; Veszpremi, V; Villatte, L; Vinogradov, A A; Volkov, M A; Vznuzdaev, E; Wang, X R; Watanabe, Y; White, S N; Wohn, F K; Woody, C L; Xie, W; Yang, Y; Yanovich, A A; Yokkaichi, S; Young, G R; Yushmanov, I E; Zajc, W A; Zhang, C; Zhou, S; Zhou, S J; Zolin, L

    2006-01-01

    Inclusive transverse momentum spectra of eta mesons have been measured within p_T = 2-10 GeV/c at mid-rapidity by the PHENIX experiment in Au+Au collisions at sqrt(s_NN) = 200 GeV. In central Au+Au the eta yields are significantly suppressed compared to peripheral Au+Au, d+Au and p+p yields scaled by the corresponding number of nucleon-nucleon collisions. The magnitude, centrality and p_T dependence of the suppression is common, within errors, for eta and pi^0. The ratio of eta to pi^0 spectra at high p_T amounts to 0.40 < R_eta/pi^0 < 0.48 for the three systems in agreement with the world average measured in hadronic and nuclear reactions and, at large scaled momentum, in e^+e^- collisions.

  5. Common suppression pattern of eta and pi0 mesons at high transverse momentum in Au + Au collisions at square root S(NN) = 200 GeV.

    Science.gov (United States)

    Adler, S S; Afanasiev, S; Aidala, C; Ajitanand, N N; Akiba, Y; Alexander, J; Amirikas, R; Aphecetche, L; Aronson, S H; Averbeck, R; Awes, T C; Azmoun, R; Babintsev, V; Baldisseri, A; Barish, K N; Barnes, P D; Bassalleck, B; Bathe, S; Batsouli, S; Baublis, V; Bazilevsky, A; Belikov, S; Berdnikov, Y; Bhagavatula, S; Boissevain, J G; Borel, H; Borenstein, S; Brooks, M L; Brown, D S; Bruner, N; Bucher, D; Buesching, H; Bumazhnov, V; Bunce, G; Burward-Hoy, J M; Butsyk, S; Camard, X; Chai, J-S; Chand, P; Chang, W C; Chernichenko, S; Chi, C Y; Chiba, J; Chiu, M; Choi, I J; Choi, J; Choudhury, R K; Chujo, T; Cianciolo, V; Cobigo, Y; Cole, B A; Constantin, P; d'Enterria, D; David, G; Delagrange, H; Denisov, A; Deshpande, A; Desmond, E J; Devismes, A; Dietzsch, O; Drapier, O; Drees, A; du Rietz, R; Durum, A; Dutta, D; Efremenko, Y V; Chenawi, K El; Enokizono, A; En'yo, H; Esumi, S; Ewell, L; Fields, D E; Fleuret, F; Fokin, S L; Fox, B D; Fraenkel, Z; Frantz, J E; Franz, A; Frawley, A D; Fung, S-Y; Garpman, S; Ghosh, T K; Glenn, A; Gogiberidze, G; Gonin, M; Gosset, J; Goto, Y; de Cassagnac, R Granier; Grau, N; Greene, S V; Perdekamp, M Grosse; Guryn, W; Gustafsson, H-A; Hachiya, T; Haggerty, J S; Hamagaki, H; Hansen, A G; Hartouni, E P; Harvey, M; Hayano, R; Hayashi, N; He, X; Heffner, M; Hemmick, T K; Heuser, J M; Hibino, M; Hiejima, H; Hill, J C; Holzmann, W; Homma, K; Hong, B; Hoover, A; Ichihara, T; Ikonnikov, V V; Imai, K; Isenhower, D; Ishihara, M; Issah, M; Isupov, A; Jacak, B V; Jang, W Y; Jeong, Y; Jia, J; Jinnouchi, O; Johnson, B M; Johnson, S C; Joo, K S; Jouan, D; Kametani, S; Kamihara, N; Kang, J H; Kapoor, S S; Katou, K; Kelly, S; Khachaturov, B; Khanzadeev, A; Kikuchi, J; Kim, D H; Kim, D J; Kim, D W; Kim, E; Kim, G-B; Kim, H J; Kistenev, E; Kiyomichi, A; Kiyoyama, K; Klein-Boesing, C; Kobayashi, H; Kochenda, L; Kochetkov, V; Koehler, D; Kohama, T; Kopytine, M; Kotchetkov, D; Kozlov, A; Kroon, P J; Kuberg, C H; Kurita, K; Kuroki, Y; Kweon, M J; Kwon, Y; Kyle, G S; Lacey, R; Ladygin, V; Lajoie, J G; Lebedev, A; Leckey, S; Lee, D M; Lee, S; Leitch, M J; Li, X H; Lim, H; Litvinenko, A; Liu, M X; Liu, Y; Maguire, C F; Makdisi, Y I; Malakhov, A; Manko, V I; Mao, Y; Martinez, G; Marx, M D; Masui, H; Matathias, F; Matsumoto, T; McGaughey, P L; Melnikov, E; Messer, F; Miake, Y; Milan, J; Miller, T E; Milov, A; Mioduszewski, S; Mischke, R E; Mishra, G C; Mitchell, J T; Mohanty, A K; Morrison, D P; Moss, J M; Mühlbacher, F; Mukhopadhyay, D; Muniruzzaman, M; Murata, J; Nagamiya, S; Nagle, J L; Nakamura, T; Nandi, B K; Nara, M; Newby, J; Nilsson, P; Nyanin, A S; Nystrand, J; O'Brien, E; Ogilvie, C A; Ohnishi, H; Ojha, I D; Okada, K; Ono, M; Onuchin, V; Oskarsson, A; Otterlund, I; Oyama, K; Ozawa, K; Pal, D; Palounek, A P T; Pantuev, V; Papavassiliou, V; Park, J; Parmar, A; Pate, S F; Peitzmann, T; Peng, J-C; Peresedov, V; Pinkenburg, C; Pisani, R P; Plasil, F; Purschke, M L; Purwar, A K; Rak, J; Ravinovich, I; Read, K F; Reuter, M; Reygers, K; Riabov, V; Riabov, Y; Roche, G; Romana, A; Rosati, M; Rosnet, P; Ryu, S S; Sadler, M E; Sahlmueller, B; Saito, N; Sakaguchi, T; Sakai, M; Sakai, S; Samsonov, V; Sanfratello, L; Santo, R; Sato, H D; Sato, S; Sawada, S; Schutz, Y; Semenov, V; Seto, R; Shaw, M R; Shea, T K; Shibata, T-A; Shigaki, K; Shiina, T; Silva, C L; Silvermyr, D; Sim, K S; Singh, C P; Singh, V; Sivertz, M; Soldatov, A; Soltz, R A; Sondheim, W E; Sorensen, S P; Sourikova, I V; Staley, F; Stankus, P W; Stenlund, E; Stepanov, M; Ster, A; Stoll, S P; Sugitate, T; Sullivan, J P; Takagui, E M; Taketani, A; Tamai, M; Tanaka, K H; Tanaka, Y; Tanida, K; Tannenbaum, M J; Tarján, P; Tepe, J D; Thomas, T L; Tojo, J; Torii, H; Towell, R S; Tserruya, I; Tsuruoka, H; Tuli, S K; Tydesjö, H; Tyurin, N; van Hecke, H W; Velkovska, J; Velkovsky, M; Veszprémi, V; Villatte, L; Vinogradov, A A; Volkov, M A; Vznuzdaev, E; Wang, X R; Watanabe, Y; White, S N; Wohn, F K; Woody, C L; Xie, W; Yang, Y; Yanovich, A; Yokkaichi, S; Young, G R; Yushmanov, I E; Zajc, W A; Zhang, C; Zhou, S; Zhou, S J; Zolin, L

    2006-05-26

    Inclusive transverse momentum spectra of eta mesons have been measured within p(T) = 2-10 GeV/c at midrapidity by the PHENIX experiment in Au + Au collisions at square root S(NN) = 200 GeV. In central Au+Au the eta yields are significantly suppressed compared to peripheral Au + Au, d + Au, and p + p yields scaled by the corresponding number of nucleon-nucleon collisions. The magnitude, centrality, and p(T) dependence of the suppression is common, within errors, for eta and pi0. The ratio of eta to pi0 spectra at high p(T) amounts to 0.40 < R(eta/pi)0 < 0.48 for the three systems, in agreement with the world average measured in hadronic and nuclear reactions and, at large scaled momentum, in e+e- collisions. PMID:16803168

  6. Enhanced electrochromic coloration of poly(3-hexylthiophene) films by electrodeposited Au nanoparticles.

    Science.gov (United States)

    Nah, Yoon-Chae

    2013-05-01

    Au nanoparticles and poly(3-hexylthiophene) (P3HT) composite films were prepared by electrodeposition of Au nanoparticles using pulse-current electrodeposition followed by the spin coating of P3HT and their enhanced electrochromic coloration was investigated. A relatively uniformed Au nanoparticle was obtained by the controlled electrodeposition on indium tin oxide (ITO) substrate and plasmon absorption band of Au nanoparticles were observed. Optical and electrochemical properties of Au/P3HT composite films were compared with the pure P3HT films. The enhanced electrochromic absorption of the composite films was observed due to the surface plasmon resonance of the Au nanoparticles. PMID:23858881

  7. Tuning the chemical activity through PtAu nanoalloying: a first principles study

    KAUST Repository

    Mokkath, Junais Habeeb

    2013-06-21

    The electronic structure and adsorption properties of 1.5 nm sized Pt, Au, and PtAu nanoclusters are studied by density functional theory. We explain the recent experimental finding that 20% Au content in PtAu nanoparticles is optimal to induce a dramatically different catalytic behavior. Our results show that the d-band center together with the density of states at the Fermi energy can be used as an indicator of the chemical activity of PtAu nanoclusters. The most favorable adsorption sites on the cluster surfaces as a function of the Pt/Au ratio are identified using atomic H as a probe.

  8. Nuclear Shadowing and Select d+Au Observables

    Science.gov (United States)

    Adeluyi, Adeola; Fai, George

    2007-04-01

    Much of the complexity of the description of d+Au collisions in the framework of perturbative Quantum Chromodynamics (pQCD) derives from effects of the nuclear environment. Here we investigate the effects of the most recent available nuclear shadowing parametrization, the Hirai-Kumano-Nagai (HKN) nuclear parton distribution functions (nPDFs) and the updated Albino-Kniehl-Kramer (AKK) fragmentation functions on three select d+Au collision observables. We compare our results to available experimental data from the STAR and BRAHMS collaborations.

  9. Towards Ultra-Low-NoiseMoAu Transition Edge Sensors

    OpenAIRE

    Goldie, D. J.; Velichko, A. V.; Glowacka, D. M.; Withington, S.

    2014-01-01

    We report initial measurements on our firstMoAu Transition Edge Sensors (TESs). The TESs formed from a bilayer of 40 nm of Mo and 106 nm of Au showed transition temperatures of about 320 mK, higher than identical TESs with a MoCu bilayer which is consistent with a reduced electron transmission coefficient between the bilayer films. We report measurements of thermal conductance in the 200 nm thick silicon nitride SiNx support structures at this temperature, TES dynamic behaviour and current no...

  10. Towards Ultra-Low-NoiseMoAu Transition Edge Sensors

    CERN Document Server

    Goldie, D J; Glowacka, D M; Withington, S

    2014-01-01

    We report initial measurements on our firstMoAu Transition Edge Sensors (TESs). The TESs formed from a bilayer of 40 nm of Mo and 106 nm of Au showed transition temperatures of about 320 mK, higher than identical TESs with a MoCu bilayer which is consistent with a reduced electron transmission coefficient between the bilayer films. We report measurements of thermal conductance in the 200 nm thick silicon nitride SiNx support structures at this temperature, TES dynamic behaviour and current noise measurements.

  11. NEUROMARKETING ET NEUROSCIENCES AU SERVICE DES PUBLICITAIRES : QUESTIONNEMENTS ETHIQUES

    OpenAIRE

    Courbet, Didier

    2010-01-01

    Le neuromarketing et les neurosciences au service des publicitaires soulèvent immanquablement des questions éthiques relatives aux finalités de cette nouvelle discipline mais également aux moyens utilisés. L'objectif de ce papier est donc de discuter certaines de ces questions. La première partie s'intéressera aux principaux débats éthiques entre les personnes adeptes du neuromarketing (les "pro-neuromarketing") et les "anti-neuromarketing". La deuxième partie expliquera qu'au stade actuel de...

  12. Self-assembly of flagellin on Au(111) surfaces.

    Science.gov (United States)

    González Orive, Alejandro; Pissinis, Diego E; Diaz, Carolina; Miñán, Alejandro; Benítez, Guillermo A; Rubert, Aldo; Daza Millone, Antonieta; Rumbo, Martin; Hernández Creus, Alberto; Salvarezza, Roberto C; Schilardi, Patricia L

    2014-11-01

    The adsorption of flagellin monomers from Pseudomonas fluorescens on Au(111) has been studied by Atomic Force Microscopy (AFM), Scanning Tunneling Microscopy (STM), X-ray Photoelectron Spectroscopy (XPS), Surface Plasmon Resonance (SPR), and electrochemical techniques. Results show that flagellin monomers spontaneously self-assemble forming a monolayer thick protein film bounded to the Au surface by the more hydrophobic subunit and exposed to the environment the hydrophilic subunit. The films are conductive and allow allocation of electrochemically active cytochrome C. The self-assembled films could be used as biological platforms to build 3D complex molecular structures on planar metal surfaces and to functionalize metal nanoparticles.

  13. Femtosecond laser ablation of Au film around single pulse threshold

    Institute of Scientific and Technical Information of China (English)

    Xiaochang Ni; Ching-Yue Wang; Yinzhong Wu; Li Yang; Wei Jia; Lu Chai

    2006-01-01

    @@ Ablation process of 1-kHz femtosecond lasers (pulse duration of 148 fs, wavelength of 775 nm) of Au film on silica substrates is studied. The thresholds for single and multi pulses can be obtained directly from the relation between the squared diameter D2 of the ablated craters and the laser fluence φo. From the plot of the accumulated laser fluence Nφth(N) and the number of laser pulses N, incubation coefficient of Au film is obtained to be 0.765. Some experimental data obtained around the single pulse threshold are in good agreement with the theoretical calculation.

  14. Rational design and synthesis of excavated trioctahedral Au nanocrystals

    Science.gov (United States)

    Chen, Qiaoli; Jia, Yanyan; Shen, Wei; Xie, Shuifen; Yang, Yanan; Cao, Zhenming; Xie, Zhaoxiong; Zheng, Lansun

    2015-06-01

    Excavated polyhedral nanostructures, possessing the features of high surface area and well-defined surface structure with a specific crystal facet and avoidance of aggregation, could be one of the best choices for the purpose of reducing consumption and improving performance of noble metals in many application fields. However, the formation of the excavated structures is thermodynamically unfavourable and its rational synthesis is far beyond our knowledge. In this work, taking overgrowth of Pd onto trioctahedral Au nanocrystals as a model, we present a deep insight study for synthesizing an excavated structure relying on the protection role of surfactants under suitable crystal growth kinetics. Based on the abovementioned understanding, we designed a simple and effective strategy to synthesize Au nanocrystals with excavated trioctahedral structure in one step. Due to the novel feature of the excavated structure and exposed high energy {110} facets, excavated trioctahedral Au NCs exhibited optical extinction at the near-infrared region and showed high catalytic activity towards the reduction of p-nitrophenol. Moreover, the synthetic strategy can be extended to the synthesis of excavated Au-Pd alloys.Excavated polyhedral nanostructures, possessing the features of high surface area and well-defined surface structure with a specific crystal facet and avoidance of aggregation, could be one of the best choices for the purpose of reducing consumption and improving performance of noble metals in many application fields. However, the formation of the excavated structures is thermodynamically unfavourable and its rational synthesis is far beyond our knowledge. In this work, taking overgrowth of Pd onto trioctahedral Au nanocrystals as a model, we present a deep insight study for synthesizing an excavated structure relying on the protection role of surfactants under suitable crystal growth kinetics. Based on the abovementioned understanding, we designed a simple and effective

  15. Catalytically favorable surface patterns in Pt-Au nanoclusters

    KAUST Repository

    Mokkath, Junais Habeeb

    2013-01-01

    Motivated by recent experimental demonstrations of novel PtAu nanoparticles with highly enhanced catalytic properties, we present a systematic theoretical study that explores principal catalytic indicators as a function of the particle size and composition. We find that Pt electronic states in the vicinity of the Fermi level combined with a modified electron distribution in the nanoparticle due to Pt-to-Au charge transfer are the origin of the outstanding catalytic properties. From our model we deduce the catalytically favorable surface patterns that induce ensemble and ligand effects. © The Royal Society of Chemistry 2013.

  16. Fermi Surfaces of Surface States on Si(111) + Ag, Au

    OpenAIRE

    Crain, J. N.; Altmann, K. N.; Bromberger, Ch.; Himpsel, F. J.

    2002-01-01

    Metallic surface states on semiconducting substrates provide an opportunity to study low-dimensional electrons decoupled from the bulk. Angle resolved photoemission is used to determine the Fermi surface, group velocity, and effective mass for surface states on Si(111)sqrt3xsqrt3-Ag, Si(111)sqrt3x sqrt3-Au, and Si(111)sqrt21xsqrt21-(Ag+Au). For Si(111)sqrt3xsqrt3-Ag the Fermi surface consists of small electron pockets populated by electrons from a few percent excess Ag. For Si(111)sqrt21xsqrt...

  17. Beyond 3 AU from the Sun: "Hypervolatiles" in Distant Comets

    Science.gov (United States)

    Bonev, Boncho P.; Villanueva, Geronimo Luis; Mumma, Michael J.; DiSanti, Michael A.; Paganini, Lucas; Boehnhardt, Hermann; Lippi, Manuela; Gibb, Erika L.; Bockelee-Morvan, Dominique; de Val-Borro, Miguel; Kawakita, Hideyo; Altwegg, Kathrin

    2016-10-01

    Our understanding of inner coma composition in comets has long been biased towards heliocentric distances (Rh) smaller than 2-3 AU. However, observations far from the Sun are also of high value for better understanding the nucleus structure and outgassing of volatiles. Substantial and very important evidence for the activity of distant comets has been accumulated from photometry and analyses of light curves, but direct detections of primary (parent) volatiles are still rare. For example, comet C/2006 W3 (Christensen) remained outside 3.1 AU throughout its apparition, yet it presented the best opportunity since Hale-Bopp (1997) for detailed spectroscopic studies in a distant comet. C/2006 W3 was observed from several space- and ground-based facilities using both infrared and radio techniques. CO, CH4, and C2H6 were measured via infrared spectroscopy at ESO-VLT at Rh = 3.25 AU. Production rates were found to exceed those measured for each of these species in most other comets, despite those comets being observed much closer to the Sun. With its relatively high CO/CO2 ratio, C/2006 W3 also appears as an outlier in the AKARI comet survey of 18 comets. The detections of H2O (Herschel Space Observatory) and CO (ESO-VLT) allow for constraining the coma abundance ratio H2O/CO at Rh = 5 AU.We will compare the C2H6/CH4/CO ratios in C/2006 W3 with those in other comets spanning a large range in Rh: from D/2012 S1 ISON (~0.7 AU) to 29P/Schwassmann-Wachmann 1 (~ 6.3 AU). Notably in situ measurements by the Rosetta mission were performed in the coma of 67P/Churyumov-Gerasimenko, at a very similar heliocentric distance to C/2006 W3 (3.15 AU). While comparisons of column-integrated remote sensing measurements and abundances from in-situ mass spectrometry (as performed by the ROSINA instrument) are not straightforward, both types of measurement are of high value for constraining models of nucleus outgassing beyond 3 AU from the Sun, where the inferred nucleus structure and

  18. Organisation and Control of Nanoscale Structures on Au(111)

    DEFF Research Database (Denmark)

    Zhang, Jingdong; Chi, Qijin; Andersen, Jens Enevold Thaulov;

    2001-01-01

    We address the formation and characterisation of three different nanoscale systems on single-crystal Au(lll) electrode surfaces in aqueous electrolyte solutions. The systems are investigated particularly by single-crystal electrochernistry and in situ scanning tunnelling rnicroscopy (STM). The [mt...... constitutes a new case for the lise of in situ STM as a tool for manufacturing nanoscale pit structures on IDe Au(lll) surface at small bias voltage. Individually and in combination these data hold perspectives for preparation of atornically planar electrochernical surfaces willi controlled functionalisation......, orientation of functional biological macromolecules, nanoscale biological sensing, and controlled adsorption sites for enzymes and otter reactive molecules....

  19. Graphene nanoribbons synthesized from molecular precursor polymerization on Au(110)

    Energy Technology Data Exchange (ETDEWEB)

    Massimi, Lorenzo; Ourdjini, Oualid; Della Pia, Ada; Mariani, Carlo; Betti, Maria Grazia [Dipartimento di Fisica, Università di Roma La Sapienza, Piazzale Aldo Moro 2, I - 00185 Roma (Italy); Cavaliere, Emanuele; Gavioli, Luca [i-LAMP & Dipartimento di Matematica e Fisica, Università Cattolica, 25121 Brescia (Italy)

    2015-06-23

    A spectroscopic study of 10,10-dibromo-9,9 bianthracene (DBBA) molecules deposited on the Au(110) surface is presented, by means of ultraviolet and X-ray photoemission, and X-ray absorption spectroscopy. Through a thermally activated procedure, these molecular precursors polymerize and eventually form graphene nanoribbons (GNRs) with atomically controlled shape and width, very important building blocks for several technological applications. The GNRs observed by scanning tunneling microscopy (STM) appear as short segments on top of the gold surface reconstruction, pointing out the delicate balance among surface diffusion and surface corrugation in their synthesis on the Au(110) surface.

  20. Site-specific growth of Au-Pd alloy horns on Au nanorods: A platform for highly sensitive monitoring of catalytic reactions by surface enhancement raman spectroscopy

    KAUST Repository

    Huang, Jianfeng

    2013-06-12

    Surface-enhanced Raman scattering (SERS) is a highly sensitive probe for molecular detection. The aim of this study was to develop an efficient platform for investigating the kinetics of catalytic reactions with SERS. To achieve this, we synthesized a novel Au-Pd bimetallic nanostructure (HIF-AuNR@AuPd) through site-specific epitaxial growth of Au-Pd alloy horns as catalytic sites at the ends of Au nanorods. Using high-resolution electron microscopy and tomography, we successfully reconstructed the complex three-dimensional morphology of HIF-AuNR@AuPd and identified that the horns are bound with high-index {11l} (0.25 < l < 0.43) facets. With an electron beam probe, we visualized the distribution of surface plasmon over the HIF-AuNR@AuPd nanorods, finding that strong longitudinal surface plasmon resonance concentrated at the rod ends. This unique crystal morphology led to the coupling of high catalytic activity with a strong SERS effect at the rod ends, making HIF-AuNR@AuPd an excellent bifunctional platform for in situ monitoring of surface catalytic reactions. Using the hydrogenation of 4-nitrothiophenol as a model reaction, we demonstrated that its first-order reaction kinetics could be accurately determined from this platform. Moreover, we clearly identified the superior catalytic activity of the rod ends relative to that of the rod bodies, owing to the different SERS activities at the two positions. In comparison with other reported Au-Pd bimetallic nanostructures, HIF-AuNR@AuPd offered both higher catalytic activity and greater detection sensitivity. © 2013 American Chemical Society.

  1. Gold chloride clusters with Au(III) and Au(I) probed by FT-ICR mass spectrometry and MP2 theory.

    Science.gov (United States)

    Lemke, Kono H

    2014-05-01

    Microsolvated clusters of gold chloride are probed by electrospray ionization mass spectrometry (ESI-MS) and scalar relativistic electronic structure calculations. Electrospray ionization of aqueous AuCl3 leads to mononuclear clusters of types [AuCl2](+)(H2O)n (n = 0-4), [AuOHCl](+)(H2O)n (n = 0-1) and [AuCl2](+)(HCl)2(H2O)n (n = 0-4). In addition, strong ion signals due to dinuclear [Au2Cl5-xOHx](+)(H2O)n (x = 0-1) are present in ESI mass spectra of aqueous AuCl3, with the abundance of individual dinuclear species controlled by the concentration-dependent variation of the precursor complexes [AuCl2-xOHx](+)(H2O)n and AuCl3. Equilibrium structures, energies and thermodynamic properties of mono- and dinuclear gold clusters have been predicted using MP2 and CCSD(T) theory, and these data have been applied to examine the influence of microsolvation on cluster stability. Specifically, results from CCSD(T) calculations indicate that non-covalently bound ion-neutral complexes Au(+)(Cl2)(H2O)n, with formal Au(I), are the dominant forms of mononuclear gold with n = 0-2, while higher hydrates (n > 2) are covalently bound [AuCl2](+)(H2O)n complexes in which gold exists as Au(III). MP2 calculations show that the lowest energy structure of dinuclear gold is an ion-molecule cluster [Au2Cl(Cl2)2](+) consisting of a single-bridged digold-chloronium ion bound end-on to two dichlorine ligands, with two higher energy isomers, single-bridged [Au2Cl3(Cl2)](+) and double-bridged [Au2Cl5](+) clusters. Finally, AuAu interactions in the singly-bridged clusters [Au2Cl(Cl2)2](+)(H2O)n and [Au2Cl3(Cl2)](+)(H2O)n are examined employing a wide range of computational tools, including natural bond order (NBO) analysis and localized orbital locator (LOL) profiles. PMID:24643288

  2. Interfacial electronic properties of the heterojunctions C{sub 60}/rubrene/Au and rubrene/C{sub 60}/Au

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, Chiu-Ping; Chan, Yi-Wei; Hsueh, Chih-Feng [Department of Electrophysics, National Chiayi University, 300 University Road, Chiayi 60004, Taiwan (China); Pi, Tun-Wen [National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan (China)

    2012-07-15

    Using synchrotron-radiation photoemission, we have studied the electronic structures of rubrene:C{sub 60} heterojunctions on Au substrates. The photoelectron spectra show that the interfacial properties at the C{sub 60}/rubrene/Au and rubrene/C{sub 60}/Au interfaces are asymmetric and do not follow the commutation rule. In the C{sub 60}/rubrene case, a gap state appearing in the initial deposition stage results from negative charges transferred from rubrene to C{sub 60}, while in the inverse deposition process, no strong chemical reaction could be found. A significant shift of the vacuum level induced by alignment of the charge neutrality levels of the two materials was observed in both cases. Furthermore, the charge transfer strongly enhances the dipole potential of the C{sub 60}/rubrene interface. The energy level diagrams show that the C{sub 60}-on-rubrene process has a superior number of advantages in the photovoltaic applications.

  3. Competing mechanisms for ordering tendencies in BCC CuAuZn{sub 2} and FCC AuFe alloys

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, D.D.; Althoff, J.D. [Sandia National Labs., Livermore, CA (United States); Staunton, J.B.; Ling, M.F. [Warwick Univ., Coventry (United Kingdom). Dept. of Physics; Pinski, F.J. [Cincinnati Univ, OH (United States). Dept. of Physics

    1995-07-01

    We have briefly discussed the ASRO (atomic short-range order) in AuFe and CuAuZn{sub 2}. General points are that (1) we have implemented a first-principles theory of ASRO in N-component alloys which allows determination of the electronic origins of said ASRO; (2) such calculations can provide much information on the high- and (sometimes) low-temperature alloys; and (3) this approach has identified the origin for the novel special-point ASRO in AuFe. Displacement effects, i.e., non-rigid lattice effects, as well as the other contributions beyond band-energy, are being incorporated into the multicomponent alloy calculations. Such improvements will allow us to investigate other alloys, where charge effects may play a role, to ``design`, for example, higher temperature intermetallics through alloying.

  4. (-Λ)-Hyperon Global Polarization in Au+Au Collisions at RHIC%(-Λ)-超子在RHIC的Au+Au碰撞中的整体极化

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    We present the (-Λ)-hyperon global polarization in Au+Au collisions at (√SNN)=62GeV and 200GeV measured with the STAR detector at RHIC. The observed (-Λ)-hyperon global polarization is consistent with zero,what is in agreement with recent measurements of A global polarization, as well as φ(1020) and K*0(892) vector mesons spin alignment with respect to the reaction plane. The possible dependence of the global polarization on relative azimuthal angle between the orbital momentum of the system and the hyperon 3-momentum is discussed. The corresponding systematic uncertainty due to detector acceptance is found to be less than 20%.

  5. Study on the optical and electrical properties of Au@Graphene@Au%Au@Graphene@Au复合结构的光电性质研究

    Institute of Scientific and Technical Information of China (English)

    岑超; 蔡绍洪

    2015-01-01

    在密度泛函理论的基础上,采用了广义梯度近似的方法研究了Au@Graphene@Au复合纳米结构的光电性质.经过对Au@Graphene@Au的电子结构计算,发现由于Graphene与Au表面功函数的差异,在Graphene与Au纳米薄膜的界面处产生电荷聚集,从而形成增强的电场,使得光与物质的相互作用增强,光吸收系数得到明显改善.

  6. Synthesis and electrocatalytic activity of Au/Pt bimetallic nanodendrites for ethanol oxidation in alkaline medium.

    Science.gov (United States)

    Han, Xinyi; Wang, Dawei; Liu, Dong; Huang, Jianshe; You, Tianyan

    2012-02-01

    Gold/Platinum (Au/Pt) bimetallic nanodendrites were successfully synthesized through seeded growth method using preformed Au nanodendrites as seeds and ascorbic acid as reductant. Cyclic voltammograms (CVs) of a series of Au/Pt nanodendrites modified electrodes in 1M KOH solution containing 1M ethanol showed that the electrocatalyst with a molar ratio (Au:Pt) of 3 exhibited the highest peak current density and the lowest onset potential. The peak current density of ethanol electro-oxidation on the Au(3)Pt(1) nanodendrites modified glassy carbon electrode (Au(3)Pt(1) electrode) is about 16, 12.5, and 4.5 times higher than those on the polycrystalline Pt electrode, polycrystalline Au electrode, and Au nanodendrites modified glassy carbon electrode (Au dendrites electrode), respectively. The oxidation peak potential of ethanol electro-oxidation on the Au(3)Pt(1) electrode is about 299 and 276 mV lower than those on the polycrystalline Au electrode and Au dendrites electrode, respectively. These results demonstrated that the Au/Pt bimetallic nanodendrites may find potential application in alkaline direct ethanol fuel cells (ADEFCs). PMID:22071516

  7. Controlled shape modification of embedded Au nanoparticles by 3 MeV Au{sup 2+}-ion irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Datta, D.P., E-mail: debi@iopb.res.in [Institute of Physics, Sachivalaya Marg, Bhubaneswar 751005, Odisha (India); Quantum Beam Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0003 (Japan); Takeda, Y.; Amekura, H. [Quantum Beam Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0003 (Japan); Sasase, M. [Wakasa wan Energy Research Center, Nagatani, Tsuruga, Fukui 914-0192 (Japan); Kishimoto, N. [National Institute for Materials Science, Sengen, Tsukuba, Ibaraki 305-0047 (Japan)

    2014-08-15

    Highlights: • By irradiation of 3 MeV Au{sup 2+} ions on spherical Au nanoparticles (NPs), shallowly-embedded in SiO{sub 2}, we have demonstrated the well-controlled fabrication of ellipsoidal Au NPs. • The observed nanostructural evolution can be qualitatively understood in terms of formation of a supersaturated solid solution and preferential growth of particles from the solution with a contribution from electronic energy loss induced elongation. • Our results indicate that inverse Ostwald ripening can be triggered after a certain amount of growth of the ellipsoids. • Our study thus provides a modification method for a shallow layer of embedded metal nanoparticles by MeV ion irradiation. - Abstract: Shape modification of embedded Au nanoparticles by 3 MeV Au{sup 2+}-ion irradiation has been studied by cross-sectional transmission electron microscopy (XTEM). The ion irradiation on spherical Au nanoparticles shallowly-embedded in SiO{sub 2} caused a well-controlled transformation of shape to ellipsoidal. Satellite nanoparticles of smaller sizes were found to nucleate around the ellipsoids. Rapid growth of the ellipsoidal nanoparticles was observed as the applied fluence increased from 3 × 10{sup 15} to 7 × 10{sup 15} ions cm{sup −2}. The XTEM study also revealed the crystallinity of the ellipsoids formed by MeV ion irradiation. Reduction in the surface plasmon resonance (SPR) peak intensity in the optical absorption spectrum indicates partial dissolution of the spherical nanoparticles by ion irradiation. We have thus obtained a unique near-surface structure of ellipsoidal nanoparticles. The results are discussed in terms of effects of ion energy deposition and inverse Ostwald ripening.

  8. Pion Interferometry of $\\sqrt{s_{NN}} = 130$ GeV Au+Au Collisions at RHIC

    CERN Document Server

    Adler, C

    2001-01-01

    Two-pion correlation functions in Au+Au collisions at $\\sqrt{s_{NN}} = 130$ GeV have been measured by the STAR (Solenoidal Tracker at RHIC) detector. The source size extracted by fitting the correlations grows with event multiplicity and decreases with transverse momentum. Anomalously large sizes or emission durations, which have been suggested as signals of quark-gluon plasma formation and rehadronization, are not observed. The HBT parameters display a weak energy dependence over a broad range in $\\sqrt{s_{NN}}$.

  9. Pseudorapidity distribution of multiplicity in Au+Au collisions at √sNN = 200 GeV

    Science.gov (United States)

    Dong, Ya-Fei; Jiang, Zhi-Jin; Wang, Zeng-Wei

    2008-04-01

    Using the Glauber model, we discuss the number of binary nucleon-nucleon collisions in heavy-ion collisions. Based on the latter, after considering the effect of energy loss of the nucleons in multiple collisions, we derive the pseudorapidity distribution of the multiplicity as a function of the impact parameter in nucleus-nucleus collisions. Using this, we analyze the experimental measurements carried out by the BRAHMS Collaboration in Au + Au collisions at √sNN = 200 GeV. The results are in good agreement with the experimental observations. Supported by Key Foundation of Shanghai (06JC14075)

  10. Pseudorapidity distribution of multiplicity in Au+Au collisions at √SNN=200 GeV

    Institute of Scientific and Technical Information of China (English)

    DONG Ya-Fei; JIANG Zhi-Jin; WANG ZengWei

    2008-01-01

    Using the Glauber model,we discuss the number of binary nucleon-nucleon collisions in heavy-ion collisions.Based on the latter,after considering the effect of energy loss of the nucleons in multiple collisions,we derive the pseudorapidity distribution of the multiplicity as a function of the impact parameter in nucleus-nucleus collisions.Using this,we analyze the experimental measurements carried out by the BRAHMS Collaboration in Au+Au collisions at √SNN=200 GeV.The results are in good agreement with the experimental observations.