WorldWideScience

Sample records for atomic ions

  1. Atomic negative-ion resonances

    International Nuclear Information System (INIS)

    The authors attempt to give a comprehensive discussion of observations of atomic negative-ion resonances throughout the periodic table. A review of experimental and theoretical approaches to the study of negative-ion resonances is given together with a consideration of the various schemes that are used for their classification. In addition to providing, where possible, tabulated data for the energies, widths, and symmetries of these states, the authors also attempt to highlight regularities in their behavior both within groups of the periodic table and along isoionic sequences

  2. From heavy ions to exotic atoms

    OpenAIRE

    Indelicato, Paul; Trassinelli, Martino

    2005-01-01

    We review a number of experiments and theoretical calculations on heavy ions and exotic atoms, which aim at providing informations on fundamental interactions. Among those are propositions of experiments for parity violation measurements in heavy ions and high-precision mesurements of He-like transition energies in highly charged ions. We also describe recent experiments on pionic atoms, that make use of highly-charged ion transitions to obtain accurate measurements of strong interaction shif...

  3. Cold heteronuclear atom-ion collisions

    CERN Document Server

    Zipkes, Christoph; Ratschbacher, Lothar; Sias, Carlo; Köhl, Michael

    2010-01-01

    We study cold heteronuclear atom ion collisions by immersing a trapped single ion into an ultracold atomic cloud. Using ultracold atoms as reaction targets, our measurement is sensitive to elastic collisions with extremely small energy transfer. The observed energy-dependent elastic atom-ion scattering rate deviates significantly from the prediction of Langevin but is in full agreement with the quantum mechanical cross section. Additionally, we characterize inelastic collisions leading to chemical reactions at the single particle level and measure the energy-dependent reaction rate constants. The reaction products are identified by in-trap mass spectrometry, revealing the branching ratio between radiative and non-radiative charge exchange processes.

  4. Sources of polarized ions and atoms

    International Nuclear Information System (INIS)

    In this presentation we discuss methods of producing large quantities of polarized atoms and ions (Stern-Gerlach separation, optical pumping, and spin-exchange) as well as experimental methods of measuring the degree of polarization of atomic systems. The usefulness of polarized atoms in probing the microscopic magnetic surface properties of materials will also be discussed. 39 refs., 5 figs., 2 tabs

  5. The mean excitation energy of atomic ions

    DEFF Research Database (Denmark)

    Sauer, Stephan P. A.; Oddershede, Jens; Sabin, John R.

    2015-01-01

    A method for calculation of the mean excitation energies of atomic ions is presented, making the calculation of the energy deposition of fast ions to plasmas, warm, dense matter, and complex biological systems possible. Results are reported to all ions of helium, lithium, carbon, neon, aluminum...

  6. Combined ion and atom trap for low temperature ion-atom physics

    OpenAIRE

    Ravi, K.; LEE, Seunghyun; Sharma, Arijit; Werth, G.; Rangwala, S. A.

    2010-01-01

    We report an experimental apparatus and technique which simultaneously traps ions and cold atoms with spatial overlap. Such an apparatus is motivated by the study of ion-atom processes at temperatures ranging from hot to ultra-cold. This area is a largely unexplored domain of physics with cold trapped atoms. In this article we discuss the general design considerations for combining these two traps and present our experimental setup. The ion trap and atom traps are characterized independently ...

  7. Single atom devices by ion implantation

    International Nuclear Information System (INIS)

    To expand the capabilities of semiconductor devices for new functions exploiting the quantum states of single donors or other impurity atoms requires a deterministic fabrication method. Ion implantation is a standard tool of the semiconductor industry and we have developed pathways to deterministic ion implantation to address this challenge. Although ion straggling limits the precision with which atoms can be positioned, for single atom devices it is possible to use post-implantation techniques to locate favourably placed atoms in devices for control and readout. However, large-scale devices will require improved precision. We examine here how the method of ion beam induced charge, already demonstrated for the deterministic ion implantation of 14 keV P donor atoms in silicon, can be used to implant a non-Poisson distribution of ions in silicon. Further, we demonstrate the method can be developed to higher precision by the incorporation of new deterministic ion implantation strategies that employ on-chip detectors with internal charge gain. In a silicon device we show a pulse height spectrum for 14 keV P ion impact that shows an internal gain of 3 that has the potential of allowing deterministic implantation of sub-14 keV P ions with reduced straggling. (paper)

  8. Atomic collisions in fusion plasmas involving multiply charged ions

    International Nuclear Information System (INIS)

    A short survey is given on atomic collisions involving multiply charged ions. The basic features of charge transfer processes in ion-ion and ion-atom collisions relevant to fusion plasmas are discussed. (author)

  9. The dressed mobile atoms and ions

    CERN Document Server

    Amour, B; Guillot, L

    2005-01-01

    We consider free atoms and ions in $\\R^3$ interacting with the quantized electromagnetic field. Because of the translation invariance we consider the reduced hamiltonian associated with the total momentum. After introducing an ultraviolet cutoff we prove that the reduced hamiltonian for atoms has a ground state if the coupling constant and the total momentum are sufficiently small. In the case of ions an extra infrared regularization is needed. We also consider the case of the hydrogen atom in a constant magnetic field. Finally we determine the absolutely continuous spectrum of the reduced hamiltonian. \\end{abstract}

  10. Hybrid quantum systems of atoms and ions

    CERN Document Server

    Zipkes, Christoph; Palzer, Stefan; Sias, Carlo; Köhl, Michael

    2010-01-01

    In recent years, ultracold atoms have emerged as an exceptionally controllable experimental system to investigate fundamental physics, ranging from quantum information science to simulations of condensed matter models. Here we go one step further and explore how cold atoms can be combined with other quantum systems to create new quantum hybrids with tailored properties. Coupling atomic quantum many-body states to an independently controllable single-particle gives access to a wealth of novel physics and to completely new detection and manipulation techniques. We report on recent experiments in which we have for the first time deterministically placed a single ion into an atomic Bose Einstein condensate. A trapped ion, which currently constitutes the most pristine single particle quantum system, can be observed and manipulated at the single particle level. In this single-particle/many-body composite quantum system we show sympathetic cooling of the ion and observe chemical reactions of single particles in situ...

  11. Atomic physics with highly charged ions

    International Nuclear Information System (INIS)

    This report discusses: One electron outer shell processes in fast ion-atom collisions; role of electron-electron interaction in two-electron processes; multi-electron processes at low energy; multi-electron processes at high energy; inner shell processes; molecular fragmentation studies; theory; and, JRM laboratory operations

  12. Atomic physics with highly charged ions

    Energy Technology Data Exchange (ETDEWEB)

    Richard, P.

    1991-08-01

    This report discusses: One electron outer shell processes in fast ion-atom collisions; role of electron-electron interaction in two-electron processes; multi-electron processes at low energy; multi-electron processes at high energy; inner shell processes; molecular fragmentation studies; theory; and, JRM laboratory operations.

  13. Multiple ionization of atoms by ion impact

    International Nuclear Information System (INIS)

    In order to model the energy deposition of fast ions as they slow down in gaseous media, information about the ionization occurring in collisions between ions and target atoms/molecules is required. Our measurements of doubly differential electron emission cross sections provide detailed information about the ionization process but do not provide any information about the final states of the target. They also do not distinguish between the emission of one or more target electrons in a single collision. It is important to know the relative importance of multiple-, with respect to single-, target ionization in order to accurately model the energy deposition. To date, multiple ionization of He, Ne, Ar, Kr, and Xe targets has been studied. Primarily, H and He ions were used, although some data for heavier ions (C,N and O) have also been obtained

  14. Cold atom-ion experiments in hybrid traps

    OpenAIRE

    Härter, Arne; Denschlag, Johannes Hecker

    2013-01-01

    In the last 5 years, a novel field of physics and chemistry has developed in which cold trapped ions and ultracold atomic gases are brought into contact with each other. Combining ion traps with traps for neutral atoms yields a variety of new possibilities for research and experiments. These range from studies of cold atom-ion collisions and atom-ion chemistry to applications in quantum information science and condensed matter related research. In this article we give a brief introduction int...

  15. Ion-atom cold collision: Formation of cold molecular ion by radiative processes

    OpenAIRE

    Rakshit, Arpita; Deb, Bimalendu

    2010-01-01

    We discuss theoretically ion-atom collisions at low energy and predict the possibility of formation of cold molecular ion by photoassociation. We present results on radiative homo- and hetero-nuclear atom-ion cold collisions that reveal threshold behaviour of atom-ion systems.

  16. Laser Spectroscopy of Muonic Atoms and Ions

    CERN Document Server

    Pohl, Randolf; Fernandes, Luis M P; Ahmed, Marwan Abdou; Amaro, Fernando D; Amaro, Pedro; Biraben, François; Cardoso, João M R; Covita, Daniel S; Dax, Andreas; Dhawan, Satish; Diepold, Marc; Franke, Beatrice; Galtier, Sandrine; Giesen, Adolf; Gouvea, Andrea L; Götzfried, Johannes; Graf, Thomas; Hänsch, Theodor W; Hildebrandt, Malte; Indelicato, Paul; Julien, Lucile; Kirch, Klaus; Knecht, Andreas; Knowles, Paul; Kottmann, Franz; Krauth, Julian J; Bigot, Eric-Olivier Le; Liu, Yi-Wei; Lopes, José A M; Ludhova, Livia; Machado, Jorge; Monteiro, Cristina M B; Mulhauser, Françoise; Nebel, Tobias; Rabinowitz, Paul; Santos, Joaquim M F dos; Santos, José Paulo; Schaller, Lukas A; Schuhmann, Karsten; Schwob, Catherine; Szabo, Csilla I; Taqqu, David; Veloso, João F C A; Voss, Andreas; Weichelt, Birgit; Antognini, Aldo

    2016-01-01

    Laser spectroscopy of the Lamb shift (2S-2P energy difference) in light muonic atoms or ions, in which one negative muon $\\mu^-$ is bound to a nucleus, has been performed. The measurements yield significantly improved values of the root-mean-square charge radii of the nuclei, owing to the large muon mass, which results in a vastly increased muon wave function overlap with the nucleus. The values of the proton and deuteron radii are 10 and 3 times more accurate than the respective CODATA values, but 7 standard deviations smaller. Data on muonic helium-3 and -4 ions is being analyzed and will give new insights. In future, the (magnetic) Zemach radii of the proton and the helium-3 nuclei will be determined from laser spectroscopy of the 1S hyperfine splittings, and the Lamb shifts of muonic Li, Be and B can be used to improve the respective charge radii.

  17. Ion-atom collisions for materials study

    International Nuclear Information System (INIS)

    The diffusion process of silver in aluminium was studied in thin films as a function of temperature, the most important characteristics of dispersor atoms that technique permits us to study are the atomic mass and depth into the solid. This is possible because when a sample is bombarded with ions of a given energy, the ions are dispersed with different energies for different masses and depths, hence this technique is a useful instrument for research into the physical processes which ocurr in thin films up to depths of several microns, one of the results obtained after the bombardment of the target with protons having an energy of 650 KeV was that when the target reached a temperature of approximately 400C, 800C, 1100C and 1600C during 15 minutes and the spectra of heated and unheated targets were compared it was found that the aluminium peak, the valley, the silver peak and the peak over the silver peak change with the increase of temperature and tend to get mixed, that is to say that silver and the aluminium are diffusing themselves. The analysis is essentially qualitative with this technique we ca also measure the thickness of thin films, the silver thickness was measured (3320A). (author)

  18. Fast ion-atom and ion-molecule collisions

    CERN Document Server

    2013-01-01

    The principal goal of this book is to provide state-of-the art coverage of the non-relativistic three- and four-body theories at intermediate and high energy ion-atom and ion-molecule collisions. The focus is on the most frequently studied processes: electron capture, ionization, transfer excitation and transfer ionization. The content is suitable both for graduate students and experienced researchers. For these collisions, the literature has seen enormous renewal of activity in the development and applications of quantum-mechanical theories. This subject is of relevance in several branches of science and technology, like accelerator-based physics, the search for new sources of energy and high temperature fusion of light ions. Other important applications are in life sciences via medicine, where high-energy ion beams are used in radiotherapy for which a number of storage ring accelerators are in full operation, under construction or planned to be built worldwide. Therefore, it is necessary to review this fiel...

  19. Problems with Accurate Atomic Lfetime Measurements of Multiply Charged Ions

    Energy Technology Data Exchange (ETDEWEB)

    Trabert, E

    2009-02-19

    A number of recent atomic lifetime measurements on multiply charged ions have reported uncertainties lower than 1%. Such a level of accuracy challenges theory, which is a good thing. However, a few lessons learned from earlier precision lifetime measurements on atoms and singly charged ions suggest to remain cautious about the systematic errors of experimental techniques.

  20. Investigations in atomic physics by heavy ion projectiles

    International Nuclear Information System (INIS)

    Investigations in atomic physics by high-energy heavy ions are discussed. The main attention is paid to collision mechanisms (direct Coulomb interaction, quasi-molecular collision mechanism and other models) and the structure of highly ionized and excited atoms. Some problems of fundamental issues (Lamb shift of H-like heavy ions, the superheavy quasi-atoms and the position production in supercritical fields) are conside-- red in detail

  1. Controlled long-range interactions between Rydberg atoms and ions

    Science.gov (United States)

    Secker, T.; Gerritsma, R.; Glaetzle, A. W.; Negretti, A.

    2016-07-01

    We theoretically investigate trapped ions interacting with atoms that are coupled to Rydberg states. The strong polarizabilities of the Rydberg levels increase the interaction strength between atoms and ions by many orders of magnitude, as compared to the case of ground-state atoms, and may be mediated over micrometers. We calculate that such interactions can be used to generate entanglement between an atom and the motion or internal state of an ion. Furthermore, the ion could be used as a bus for mediating spin-spin interactions between atomic spins in analogy to much employed techniques in ion-trap quantum simulation. The proposed scheme comes with attractive features as it maps the benefits of the trapped-ion quantum system onto the atomic one without obviously impeding its intrinsic scalability. No ground-state cooling of the ion or atom is required and the setup allows for full dynamical control. Moreover, the scheme is to a large extent immune to the micromotion of the ion. Our findings are of interest for developing hybrid quantum information platforms and for implementing quantum simulations of solid-state physics.

  2. Controlled long-range interactions between Rydberg atoms and ions

    CERN Document Server

    Secker, Thomas; Glaetzle, Alexander W; Negretti, Antonio

    2016-01-01

    We theoretically investigate trapped ions interacting with atoms that are coupled to Rydberg states. The strong polarizabilities of the Rydberg levels increases the interaction strength between atoms and ions by many orders of magnitude, as compared to the case of ground state atoms, and may be mediated over micrometers. We calculate that such interactions can be used to generate entanglement between an atom and the motion or internal state of an ion. Furthermore, the ion could be used as a bus for mediating spin-spin interactions between atomic spins in analogy to much employed techniques in ion trap quantum simulation. The proposed scheme comes with attractive features as it maps the benefits of the trapped ion quantum system onto the atomic one without obviously impeding its intrinsic scalability. No ground state cooling of the ion or atom is required and the setup allows for full dynamical control. Moreover, the scheme is to a large extent immune to the micromotion of the ion. Our findings are of interest...

  3. Positron Interactions with Atoms and Ions

    Science.gov (United States)

    Bhatia, Anand K.

    2012-01-01

    Dirac, in 1928, combining the ideas of quantum mechanics and the ideas of relativity invented the well-known relativistic wave equation. In his formulation, he predicted an antiparticle of the electron of spin n-bar/2. He thought that this particle must be a proton. Dirac published his interpretation in a paper 'A theory of electrons and protons.' It was shown later by the mathematician Hermann Weyl that the Dirac theory was completely symmetric between negative and positive particles and the positive particle must have the same mass as that of the electron. In his J. Robert Oppenheimer Memorial Prize Acceptance Speech, Dirac notes that 'Blackett was really the first person to obtain hard evidence for the existence of a positron but he was afraid to publish it. He wanted confirmation, he was really over cautious.' Positron, produced by the collision of cosmic rays in a cloud chamber, was detected experimentally by Anderson in 1932. His paper was published in Physical Review in 1933. The concept of the positron and its detection were the important discoveries of the 20th century. I have tried to discuss various processes involving interactions of positrons with atoms and ions. This includes scattering, bound states and resonances. It has not been possible to include the enormous work which has been carried out during the last 40 or 50 years in theory and measurements.

  4. Confinement-induced resonances in ultracold atom-ion systems

    Science.gov (United States)

    Melezhik, V. S.; Negretti, A.

    2016-08-01

    We investigate confinement-induced resonances in a system composed of a tightly trapped ion and a moving atom in a waveguide. We determine the conditions for the appearance of such resonances in a broad region—from the "long-wavelength" limit to the opposite case when the typical length scale of the atom-ion polarization potential essentially exceeds the transverse waveguide width. We find considerable dependence of the resonance position on the atomic mass which, however, disappears in the "long-wavelength and zero-energy" limit, where the known result for the confined atom-atom scattering is reproduced. We also derive an analytic and a semianalytic formula for the resonance position in the long-wavelength and zero-energy limit and we investigate numerically the dependence of the resonance condition on the finite atomic colliding energy. Our results, which can be investigated experimentally in the near future, could be used to determine the atom-ion scattering length, to determine the temperature of the atomic ensemble in the presence of an ion impurity, and to control the atom-phonon coupling in a linear ion crystal in interaction with a quasi-one-dimensional atomic quantum gas.

  5. Confinement-Induced Resonances in Ultracold Atom-Ion Systems

    CERN Document Server

    Melezhik, Vladimir S

    2016-01-01

    We investigate confinement-induced resonances in a system composed by a tightly trapped ion and a moving atom in a waveguide. We determine the conditions for the appearance of such resonances in a broad region -- from the "long-wavelength" limit to the opposite case when the typical length scale of the atom-ion interaction essentially exceeds the transverse waveguide width. We find considerable dependence of the resonance position on the atomic mass which, however, disappears in the "long-wavelength" limit, where the result for the confined atom-atom scattering is reproduced. We also derive an analytic formula for the resonance position in the "long-wavelength zero-energy" limit. Our results, which can be investigated in current experiments, indicate a strategy to determine the atom-ion scattering length, the temperature of the atomic ensemble in the presence of an ion impurity, and a pathway to control the atom-phonon coupling in a one dimensional ion crystal in interaction with an atomic quantum gas.

  6. Study of Cold Potassium Atom - Calcium Ion Reactions

    Science.gov (United States)

    Egodapitiya, Kisra; Gang, Shu; Clark, Robert; Brown, Kenneth

    2016-05-01

    We report on our progress towards constructing a hybrid system for studying reactions between cold Potassium (K) atoms and cold Calcium (Ca+) ions. Ca+ ions will be trapped and Doppler-cooled inside a linear quadrupole ion trap. Cold K atoms will be created inside a magneto optical trap, such that the ion and the atoms are in an overlapping volume. Trapping and re-pumping beams for the Potassium MOT are derived from the same laser with wavelength 766 nm using two acousto optic modulators. The reaction products will be detected using a time-of- flight mass spectrometer that is designed to detect radially ejected ions. The main objective of this experiment is to study the rate coefficients, and identification of reaction channels between cold K atoms and Ca+ ions. Subsequently this setup will be used to study reactions between cold K atoms and sympathetically cooled molecular ions such as CaO+, and to study internal state quenching of molecular ions.

  7. Electron-impact ionization of heavy atomic ions

    International Nuclear Information System (INIS)

    General theoretical methods for the calculation of direct and indirect processes in the electron-impact ionization of heavy atomic ions are reviewed. Cross section results for Xe8+ and U89+ are presented. 12 refs., 4 figs

  8. Next Generation JPL Ultra-Stable Trapped Ion Atomic Clocks

    Science.gov (United States)

    Burt, Eric; Tucker, Blake; Larsen, Kameron; Hamell, Robert; Tjoelker, Robert

    2013-01-01

    Over the past decade, trapped ion atomic clock development at the Jet Propulsion Laboratory (JPL) has focused on two directions: 1) new atomic clock technology for space flight applications that require strict adherence to size, weight, and power requirements, and 2) ultra-stable atomic clocks, usually for terrestrial applications emphasizing ultimate performance. In this paper we present a new ultra-stable trapped ion clock designed, built, and tested in the second category. The first new standard, L10, will be delivered to the Naval Research Laboratory for use in characterizing DoD space clocks.

  9. Landau quantization effects in ultracold atom-ion collisions

    Science.gov (United States)

    Simoni, Andrea; Launay, Jean-Michel

    2011-12-01

    We study ultracold atom-ion collisions in the presence of an external magnetic field. At low collision energy the field can drastically modify the translational motion of the ion, which follows quantized cyclotron orbits. We present a rigorous theoretical approach for the calculation of quantum scattering amplitudes in these conditions. Collisions in different magnetic field regimes, identified by the size of the cyclotron radius with respect to the range of the interaction potential, are investigated. Our results are important in cases where use of a magnetic field to control the atom-ion collision dynamics is envisioned.

  10. Landau quantization effects in ultracold atom-ion collisions

    International Nuclear Information System (INIS)

    We study ultracold atom-ion collisions in the presence of an external magnetic field. At low collision energy the field can drastically modify the translational motion of the ion, which follows quantized cyclotron orbits. We present a rigorous theoretical approach for the calculation of quantum scattering amplitudes in these conditions. Collisions in different magnetic field regimes, identified by the size of the cyclotron radius with respect to the range of the interaction potential, are investigated. Our results are important in cases where use of a magnetic field to control the atom-ion collision dynamics is envisioned.

  11. Hydrogen negative ions and collisions of atomic particles

    International Nuclear Information System (INIS)

    This paper will be an overview presenting some of the basic atomic collisions processes (gas phase) which are fundamental to production and destruction of H-(D-). More detailed discussions of the most important processes will be left to other papers at this Symposium, and primarily new results since the 1977 Symposium will be discussed. Recent results provide insight into mechanisms responsible for the high H-(D-) ion fractions in hydrogen gas discharges, and the ion-atom collision processes important for double capture negative ion sources are better understood than in 1977

  12. Charge exchange between hydrogen atoms and fully stripped heavy ions

    International Nuclear Information System (INIS)

    Charge exchange between multicharged ions and background atomic and molecular gases represents one of the limitations to the attainment of high charge states in heavy ion sources, particularly containment sources. An attempt is made to study systematically a particularly simple but in many respects representative class of such reactions, namely charge transfer between atomic hydrogen and fully stripped heavy ions. Approximate cross sections for these processes in the low keV range of collision energies were obtained using a multistate Landau--Zener method. The energy and Z dependences of the cross sections are discussed

  13. An Atomic Abacus: Trapped ion quantum computing experiments at NIST

    Science.gov (United States)

    Demarco, Brian

    2003-03-01

    Trapped atomic ions are an ideal system for exploring quantum information science because deterministic state preparation and efficient state detection are possible and coherent manipulation of atomic systems is relatively advanced. In our experiment, a few singly charged Be ions are confined by static and radio-frequency electric fields in a micro-machined linear Paul trap. The internal and motional states of the ions are coherently manipulated using applied laser light. Our current work focuses on demonstrating the necessary ingredients to produce a scalable quantum computing scheme and on simplifying and improving quantum logic gates. I will speak about a new set of experiments that was made possible by recent improvements in trap technology. A novel trap with multiple trapping regions was used to demonstrate the first steps towards a fully scalable quantum computing scheme. Single ions were ``shuttled" between trapping regions without disturbing the ion's motional and internal state, and two ions were separated from a single to two different trapping zones. Improvements in the trap manufacturing process has led to a reduction of nearly two orders of magnitude in the ion's motional heating rate, making possible two new improved logic gates. The first gate utilizes the wave-packet nature of the ions to tune the laser-atom interaction and achieve a controlled-NOT gate between a single ion's spin and motional states. The second, a two-ion phase gate, uses phase-space dynamics to produce a state-sensitive geometric phase. I will end with a quick look at experiments using a Mg ion to sympathetically cool a simultaneously trapped Be ion and a glimpse of the next generation of ions traps currently under construction.

  14. Enabling Nanotechnology with Focused Ion Beams from Laser Cooled Atoms

    Science.gov (United States)

    Steele, A. V.; Knuffman, B.; Orloff, J.; Maazouz, M.; McClelland, J. J.

    2011-05-01

    The Magneto-Optical Trap Ion Source (MOTIS) being developed at NIST has the potential to enable numerous advances in nanoscale science. In a MOTIS, atoms are captured into a MOT, photoionized, and accelerated to an energy of a few hundred eV to a few tens of kV. A beam formed in this way can be brought to a tight focus, competitive with the commercial focused ion beam machines deployed widely today. Additionally, the unique characteristics of this source, coupled with the user's choice of ion from the long and growing list of laser-coolable atomic species suggest that the MOTIS has the potential to advance the state of the art in applications such as imaging, nanofabrication, secondary ion mass spectrometry, and others. I will present high-resolution images from our lithium and chromium MOTIS-based focused ion beams and discuss applications which we will pursue with these new tools.

  15. Production of heavy ion beams for atomic physics studies

    International Nuclear Information System (INIS)

    A laboratory for research in atomic physics of ions has been set up around a 2 MV tandem Van de Graaff accelerator designed and built indegenously. Mass analysed negatively charged heavy ion beams from a directly extracted duoplasmatron ion source are injected through various ion-optical elements into the accelerating tube. A gas stripper at the high voltage dome changes the negative ions into positive ions which are subsequently accelerated. The high energy end of the accelerator consists of quadrupole focussing magnets and an analysing magnet. A pair of insulated tantalum slits provide corona feedback and stabilize the energy of the accelerator. A beam resolution of 5 keV at 1 MeV proton energy has been measured. A number of experiments are presently being planned to utilize the accelerator in the field of basic research in atomic physics. These include beam-foil spectroscopic measurements involving detection of decay photon/electrons, ion-induced X-ray emission, analytical applications and radiation damage studies. Electron spectrometers which are in the stage of testing include cylindrical mirror analyser and parallel plate analyser. On the accelerator front, efforts are underway to develop a new sputter ion source and computer automation for improving stability and reliability. The salient features of the accelerator and the instrumentation developed for carrying out experiments in atomic physics are reported. (author). 14 refs., 17 figs

  16. MULTIPLY CHARGED IONS COLLISIONS WITH ATOMS INTO EXCITED STATES

    Institute of Scientific and Technical Information of China (English)

    PanGuangyan

    1990-01-01

    The emission spectra in collisions between Ions and Atoms have been measured by an Optical Multichannel Analysis System (OMA).The experimental results demonstrate that there are two channels of excitation in collision between single charged ions and atoms and three channels of excitation in collision between double charged ions and atoms.Emission cross cestions and excitation cross sections have been obtained.K.Kadota et al and R.Shingal et al suggested that,under the appropriate conditions,the H42+-Li and He2++Na collision systems can be used efficiently to produce a laser of Lyman-α(30,4nm) and Lyman-β(25.6nm)lines via cascade to He+(2P)state.

  17. Bremsstrahlung spectra from atoms and ions at low relativistic energies

    International Nuclear Information System (INIS)

    Analytic expressions for bremsstrahlung spectra from neutral atoms and ions, including the polarizational bremsstrahlung contribution in a stripped atom approximation, are developed for electron scattering at energies of 10-2000 keV. A modified Elwert factor and a simple higher Born correction are used for the Coulomb spectrum, with ordinary bremsstrahlung screening effects in ions and atoms adequately characterized in the non-relativistic Born approximation. In parallel with the development of this analytic description, new numerical results are obtained for ordinary bremsstrahlung from ions and from bare nuclei, appreciably extending the available data set which can be used to study dependences on element, ionicity, energy and the fraction of incident energy radiated. The accuracy of predictions with the analytic expressions is then determined by comparison with the full numerical relativistic partial-wave results for ordinary bremsstrahlung and with non-relativistic numerical results in the Born approximation or in partial waves for the polarizational amplitude. (author)

  18. Energy Scaling of Cold Atom-Atom-Ion Three-Body Recombination

    Science.gov (United States)

    Krükow, Artjom; Mohammadi, Amir; Härter, Arne; Denschlag, Johannes Hecker; Pérez-Ríos, Jesús; Greene, Chris H.

    2016-05-01

    We study three-body recombination of Ba++Rb +Rb in the mK regime where a single 138Ba+ ion in a Paul trap is immersed into a cloud of ultracold 87Rb atoms. We measure the energy dependence of the three-body rate coefficient k3 and compare the results to the theoretical prediction, k3∝Ecol-3 /4, where Ecol is the collision energy. We find agreement if we assume that the nonthermal ion energy distribution is determined by at least two different micromotion induced energy scales. Furthermore, using classical trajectory calculations we predict how the median binding energy of the formed molecules scales with the collision energy. Our studies give new insights into the kinetics of an ion immersed in an ultracold atom cloud and yield important prospects for atom-ion experiments targeting the s -wave regime.

  19. Energy scaling of cold atom-atom-ion three-body recombination

    CERN Document Server

    Krükow, Artjom; Härter, Arne; Denschlag, Johannes Hecker; Pérez-Ríos, Jesús; Greene, Chris H

    2015-01-01

    We study three-body recombination of Ba$^+$ + Rb + Rb in the mK regime where a single $^{138}$Ba$^{+}$ ion in a Paul trap is immersed into a cloud of ultracold $^{87}$Rb atoms. We measure the energy dependence of the three-body rate coefficient $k_3$ and compare the results to the theoretical prediction, $k_3 \\propto E_{\\textrm{col}}^{-3/4}$ where $E_{\\textrm{col}}$ is the collision energy. We find agreement if we assume that the non-thermal ion energy distribution is determined by at least two different micro-motion induced energy scales. Furthermore, using classical trajectory calculations we predict how the median binding energy of the formed molecules scales with the collision energy. Our studies give new insights into the kinetics of an ion immersed into an ultracold atom cloud and yield important prospects for atom-ion experiments targeting the s-wave regime.

  20. Atomic physics with highly charged ions

    International Nuclear Information System (INIS)

    The past year has been a busy one for all three accelerators, the LINAC, EBIS and the tandem. The EBIS continues to deliver beams of highly charged ions around the clock for the study of low energy collisions with gases and surfaces. The electron beam energy has been upgraded to 10 keV, and intensities of highly charged species such as Xe44+ have been greatly increased. The tandem, the traditional source of highly charged Binary encounter electron production at zero degrees were studied for medium Z (Si,Cl,Cu) projectiles. Recoil momentum spectroscopy has been used to separate the contributions to collisional ionization of one-electron ions (C5+, O7+, F8+) from the nucleus and the electrons of a He target. Marked structure in the binary encounter electron spectra for Cuq+ on H2 targets has been measured for moderate velocity projectiles. Electron capture by slow multiply charged (EBIS) projectiles from laser excited targets has been carried out. Cross sections for capture from Na(3s) and Na*(3p) have been measured for velocities between 0.1 and 1 au. The extension of these experiments to laser excited Rydberg targets is proceeding. Electron capture cross sections and average Q values for Ar16+ on He at velocities between 0.23 and 1.67 au have been measured. The charge state distribution of the He recoils following large angle scattering of C4+ and C6+ ions at 7.5 keV/u has been measured. Cross sections have been measured for up to sextuple capture from C60 (buckminsterfullerene) by highly charged slow projectiles. Coupled channel calculations for double capture from He by slow multicharge ions have been carried out

  1. Atom probe field ion microscopy characterizations of VVER steels

    International Nuclear Information System (INIS)

    An atom probe field ion microscopy (APFIM) characterization of Soviet types 15Kh2MFA Cr-Mo-V (VVER 440) and 15Kh2NMFA Ni-Cr-Mo-V (VVER 1000) pressure vessel steels has been performed. Field ion microscopy has revealed that the lath boundaries in unirradiated VVER 440 and VVER 1000 steels are decorated with a thin film of brightly-imaging molybdenum carbonitride precipitates and some coarser vanadium carbides. Atom probe analysis has revealed significant enrichments of phosphorous at the lath boundaries

  2. A high density target of ultracold atoms and momentum resolved measurements of ion-atom collisions

    OpenAIRE

    Götz, Simone Andrea

    2012-01-01

    In this thesis an ultracold high density target with high loading flux in combination with a recoil ion momentum spectrometer (RIMS) is presented. Trapped rubidium atoms serve as a high density target (up to 10¹¹ atoms/cm³) at a temperature of only 200 µK. The target is loaded from a two-dimensional magneto-optical trap (2D MOT), which delivers an atom beam with a brilliance of 8 x 10¹² atoms/(s*rad) and a longitudinal momentum spread of 0.25 a.u.. The great advantage of this source is that t...

  3. Landau quantization effects in ultracold atom-ion collisions

    OpenAIRE

    Simoni, Andrea; Launay, Jean-Michel

    2011-01-01

    We study ultracold atom-ion collisions in the presence of an external magnetic field. At low collision energy the field can drastically modify the translational motion of the ion, which follows quantized cyclotron orbits. We present a rigorous theoretical approach for the calculation of quantum scattering amplitudes in these conditions. Collisions in different magnetic field regimes, identified by the size of the cyclotron radius with respect to the range of the interaction potential, are inv...

  4. Atomic physics experiments with trapped and cooled highly charged ions

    OpenAIRE

    Kluge, H.-J.; Quint, W; Winters, D. F. A

    2007-01-01

    Trapping and cooling techniques have become very important for many fundamental experiments in atomic physics. When applied to highly charged ions confined in Penning traps, these procedures are very effective for testing quantum electrodynamics in extreme electromagnetic fields produced by heavy highly charged ions such as uranium U$^{91+}$. In addition, fundamental constants or nuclear ground state properties can be determined with high accuracy in these simple systems. Finally, by studying...

  5. The Helium Atom and Isoelectronic Ions in Two Dimensions

    Science.gov (United States)

    Patil, S. H.

    2008-01-01

    The energy levels of the helium atom and isoelectronic ions in two dimensions are considered. The difficulties encountered in the analytical evaluation of the perturbative and variational expressions for the ground state, promote an interesting factorization of the inter-electronic interaction, leading to simple expressions for the energy. This…

  6. State selective electron capture by highly stripped ions from atoms

    International Nuclear Information System (INIS)

    An experimental study on final-state distribution in one-electron capture from slow fully-stripped and hydrogen-like projectile ions from H and He atoms is discussed. After a short review of the available results, state-selectiveness of the process is interpreted using the Landau-Zener model

  7. Energetic ion-atom collisions: early beginnings and recent advances

    International Nuclear Information System (INIS)

    From the discovery of canal rays and radioactivity to the invention of accelerators and the first applications of the Born approximation, some developments which were seminal for the development of ion-atom collisions are described. Collision theory is shown to have played a key role in the evolution of the early quantum theory and of quantum mechanics and its probability interpretation

  8. Total Born approximation cross sections for single electron loss by atoms and ions colliding with atoms

    Science.gov (United States)

    Rule, D. W.

    1977-01-01

    The first born approximation (FBA) is applied to the calculation of single electron loss cross sections for various ions and atoms containing from one to seven electrons. Screened hydrogenic wave functions were used for the states of the electron ejected from the projectile, and Hartree-Fock elastic and incoherent scattering factors were used to describe the target. The effect of the target atom on the scaling of projectile ionization cross sections with respect to the projectile nuclear charge was explored in the case of hydrogen-like ions. Scaling of the cross section with respect to the target nuclear charge for electron loss by Fe (+25) in collision with neutral atoms ranging from H to Fe is also examined. These results were compared to those of the binary encounter approximation and to the FBA for the case of ionization by completely stripped target ions.

  9. Tuning friction atom-by-atom in an ion-crystal simulator

    CERN Document Server

    Bylinskii, Alexei; Vuletic, Vladan

    2014-01-01

    Friction between ordered, atomically smooth surfaces at the nanoscale (nanofriction) is often governed by stick-slip processes. To test long-standing atomistic models of such processes, we implement a synthetic nanofriction interface between a laser-cooled Coulomb crystal of ions as the moving object, and a periodic light-field potential as the substrate, enabling us to directly observe and control individual atoms at a frictional interface. We show that stick-slip friction can be tuned from maximal to nearly frictionless via arrangement of the ions relative to the substrate. By varying the ion number, we also show that this strong dependence of friction on the structural mismatch, as predicted by many-particle models, already emerges at the level of two or three atoms. This model system enables a microscopic and systematic investigation of friction, potentially even into the quantum many-body regime.

  10. Atomic physics experiments with trapped and cooled highly charged ions

    CERN Document Server

    Kluge, H -J; Winters, D F A

    2007-01-01

    Trapping and cooling techniques have become very important for many fundamental experiments in atomic physics. When applied to highly charged ions confined in Penning traps, these procedures are very effective for testing quantum electrodynamics in extreme electromagnetic fields produced by heavy highly charged ions such as uranium U$^{91+}$. In addition, fundamental constants or nuclear ground state properties can be determined with high accuracy in these simple systems. Finally, by studying a single trapped radioactive ion, its nuclear decay can be studied in detail by observing the disappearance of the signal of the mother and the appearance of that of the daughter isotope. Such experiments on highly charged ions at extremely low energy will become possible by the HITRAP facility which is currently being built up at GSI. Also the future Facility for Antiproton and Ion Research (FAIR) will be briefly described which is expected to be operational by 2014.

  11. Bibliography on electron transfer processes in ion-ion/atom/molecule collisions (updated 1993)

    International Nuclear Information System (INIS)

    Following our previous compilations [IPPJ-AM-45 (1986), NIFS-DATA-7 (1990)], bibliographic information on experimental and theoretical studies on electron transfer processes in ion-ion/atom/molecule collisions is up-dated. The references published through 1980-1992 are included. For easy finding references for particular combination of collision partners, a simple list is also provided. (author) 1542 refs

  12. A new ion sensing deep atomic force microscope

    Science.gov (United States)

    Drake, Barney; Randall, Connor; Bridges, Daniel; Hansma, Paul K.

    2014-08-01

    Here we describe a new deep atomic force microscope (AFM) capable of ion sensing. A novel probe assembly incorporates a micropipette that can be used both for sensing ion currents and as the tip for AFM imaging. The key advance of this instrument over previous ion sensing AFMs is that it uses conventional micropipettes in a novel suspension system. This paper focuses on sensing the ion current passively while using force feedback for the operation of the AFM in contact mode. Two images are obtained simultaneously: (1) an AFM topography image and (2) an ion current image. As an example, two images of a MEMS device with a microchannel show peaks in the ion current as the pipette tip goes over the edges of the channel. This ion sensing AFM can also be used in other modes including tapping mode with force feedback as well as in non-contact mode by utilizing the ion current for feedback, as in scanning ion conductance microscopy. The instrument is gentle enough to be used on some biological samples such as plant leaves.

  13. A new ion sensing deep atomic force microscope

    Energy Technology Data Exchange (ETDEWEB)

    Drake, Barney; Randall, Connor; Bridges, Daniel; Hansma, Paul K. [Department of Physics, University of California, Santa Barbara, California 93106 (United States)

    2014-08-15

    Here we describe a new deep atomic force microscope (AFM) capable of ion sensing. A novel probe assembly incorporates a micropipette that can be used both for sensing ion currents and as the tip for AFM imaging. The key advance of this instrument over previous ion sensing AFMs is that it uses conventional micropipettes in a novel suspension system. This paper focuses on sensing the ion current passively while using force feedback for the operation of the AFM in contact mode. Two images are obtained simultaneously: (1) an AFM topography image and (2) an ion current image. As an example, two images of a MEMS device with a microchannel show peaks in the ion current as the pipette tip goes over the edges of the channel. This ion sensing AFM can also be used in other modes including tapping mode with force feedback as well as in non-contact mode by utilizing the ion current for feedback, as in scanning ion conductance microscopy. The instrument is gentle enough to be used on some biological samples such as plant leaves.

  14. Scaling of Cross Sections for Ion-atom Impact Ionization

    CERN Document Server

    Kaganovich, I D; Startsev, E

    2003-01-01

    The values of ion-atom ionization cross sections are frequently needed for many applications that utilize the propagation of fast ions through matter. When experimental data and theoretical calculations are not available, approximate formulas are frequently used. This paper briefly summarizes the most important theoretical results and approaches to cross section calculations in order to place the discussion in historical perspective and offer a concise introduction to the topic. Based on experimental data and theoretical predictions, a new fit for ionization cross sections is proposed. The range of validity and accuracy of several frequently used approximations (classical trajectory, the Born approximation, and so forth) are discussed using, as examples, the ionization cross sections of hydrogen and helium atoms by various fully stripped ions.

  15. Scaling Cross Sections for Ion-atom Impact Ionization

    Energy Technology Data Exchange (ETDEWEB)

    Igor D. Kaganovich; Edward Startsev; Ronald C. Davidson

    2003-06-06

    The values of ion-atom ionization cross sections are frequently needed for many applications that utilize the propagation of fast ions through matter. When experimental data and theoretical calculations are not available, approximate formulas are frequently used. This paper briefly summarizes the most important theoretical results and approaches to cross section calculations in order to place the discussion in historical perspective and offer a concise introduction to the topic. Based on experimental data and theoretical predictions, a new fit for ionization cross sections is proposed. The range of validity and accuracy of several frequently used approximations (classical trajectory, the Born approximation, and so forth) are discussed using, as examples, the ionization cross sections of hydrogen and helium atoms by various fully stripped ions.

  16. Scaling of Cross Sections for Ion-atom Impact Ionization

    International Nuclear Information System (INIS)

    The values of ion-atom ionization cross sections are frequently needed for many applications that utilize the propagation of fast ions through matter. When experimental data and theoretical calculations are not available, approximate formulas are frequently used. This paper briefly summarizes the most important theoretical results and approaches to cross section calculations in order to place the discussion in historical perspective and offer a concise introduction to the topic. Based on experimental data and theoretical predictions, a new fit for ionization cross sections is proposed. The range of validity and accuracy of several frequently used approximations (classical trajectory, the Born approximation, and so forth) are discussed using, as examples, the ionization cross sections of hydrogen and helium atoms by various fully stripped ions

  17. Formation of molecular ions by radiative association of cold trapped atoms and ions

    OpenAIRE

    Silva Jr, Humberto Da; Raoult, Maurice; Aymar, Mireille; Dulieu, Olivier

    2015-01-01

    Radiative emission during cold collisions between trapped laser-cooled Rb atoms and alkaline-earth ions (Ca$^+$, Sr$^+$, Ba$^+$) and Yb$^+$, and between Li and Yb$^+$, are studied theoretically, using accurate effective-core-potential based quantum chemistry calculations of potential energy curves and transition dipole moments of the related molecular ions. Radiative association of molecular ions is predicted to occur for all systems with a cross section two to ten times larger than the radia...

  18. Collisional cooling of light ions by co-trapped heavy atoms

    CERN Document Server

    Dutta, Sourav; Rangwala, S A

    2015-01-01

    The most generic cooling and thermalization pathway at the lowest temperatures is via elastic collisions. In hybrid ion-atom traps, ion cooling to temperatures where low partial wave collisions dominate require the collisional cooling mechanism to be well understood and controlled. There exists great uncertainty on whether cooling of light ions by heavier neutral atoms is possible. Here we experimentally demonstrate the cooling of light ions by co-trapped heavy atoms for the first time. We show that trapped 39K+ ions are cooled by localized ultracold neutral 85Rb atoms for an ion-atom mass ratio where most theoretical models predict ion heating. We demonstrate, based on detailed numerical simulation of our ion-cooling model, which is in excellent agreement with experiments, that cooling of ions by localized cold atoms is possible for any mass ratio. Our result opens up the possibility of studying quantum collisions and chemistry in trapped atom-ion systems.

  19. Correlated charge-changing ion-atom collisions

    International Nuclear Information System (INIS)

    This report summarizes the progress and accomplishments in accelerator atomic physics research supported by DOE grant DE-FG02-87ER13778 from February 16, 1990 through February 15, 1993. This work involves the experimental investigation of atomic interactions in collisions of charged projectiles with neutral targets or electrons, with particular emphasis on two-electron interactions and electron-correlation effects. The processes studied are of interest both from fundamental and applied points of view. In the latter case, results are obtained which are relevant to the understanding of laboratory and astrophysical plasmas, highly-excited (Rydberg) and continuum states of atoms and ions, atomic structure effects, the interaction of ions with surfaces, and the development of heavy-ion storage-rings. The results obtained have provided the basis for several M.A. thesis projects at Western Michigan and several Ph.D. dissertation projects are currently underway. Summaries of work completed and work in progress are given below in Section II. This research has resulted in 26 papers (in print and in press), 12 invited presentations at national and international meetings, and 28 contributed presentations as detailed in Section III

  20. Data compilation for depth distribution of ion-induced damage and ion-implanted atoms

    International Nuclear Information System (INIS)

    In the recent progress of utilizing ion bombardment technique to ion implantation and neutron irradiation simulation, the experimental data have accumulated concerning the depth distribution of deposited atoms and induced damage along ion incident direction. In the ion-induced damage experiments, the density of point defects or void swelling has been investigated as a function of depth. In this study, the data available until the present time are compiled and compared with theoretical prediction represented by E-DEP-1 computer code. It is recognized in general that the experimentally observed damage peak is deeper than that E-DEP-1 calculated using the LSS electronic stopping parameter, k sub(LSS). Agreement between the observation and calculation can be obtained using a modified electronic stopping parameter k = 0.8 - 0.9 k sub(LSS). With regard to the deposited atoms by ion bombardment, the peak of the observed distribution is deeper in some cases and shallower in other cases than that calculated by E-DEP-1, indicating that the modified electronic stopping parameter k is oscillating relative to k sub(LSS). This oscillatory behavior is not recognized in the damage distribution. It is suggested that future work should be made to determine the distribution of ion-induced damage in relation to that of the deposited atoms, since the defect evolution may directly be related to the implanted atoms. (author)

  1. Energy distributions for ionization in ion-atom collisions

    CERN Document Server

    Amaya-Tapia, A

    2016-01-01

    In this paper we discuss how through the process of applying the Fourier transform to solutions of the Schr\\"odinger equation in the Close Coupling approach, good results for the ionization differential cross section in energy for electrons ejected in ion-atom collisions are obtained. The differential distributions are time dependent and through their time average, the comparison with experimental and theoretical data reported in the literature can be made. The procedure is illustrated with reasonable success in two systems, $p+H$ and $p+He$, and is expected to be extended without inherent difficulties to more complex systems. This allows advancing in the understanding of the calculation of ionization processes in ion-atom collisions.

  2. Quantum theory of ultracold atom-ion collisions

    CERN Document Server

    Idziaszek, Zbigniew; Julienne, Paul S; Simoni, Andrea

    2008-01-01

    We study atom-ion scattering in the ultracold regime. To this aim, an analytical model based on the multichannel quantum defect formalism is developed and compared to close-coupled numerical calculations. We investigate the occurrence of magnetic Feshbach resonances focusing on the specific 40Ca+ - Na system. The presence of several resonances at experimentally accessible magnetic fields should allow the atom-ion interaction to be precisely tuned. A fully quantum-mechanical study of charge exchange processes shows that charge-exchange rates should remain small even in the presence of resonance effects. Most of our results can be cast in a system-independent form and are important for the realization of the charge-neutral ultracold systems.

  3. Negative ion formation in lanthanide atoms: Many-body effects

    CERN Document Server

    Felfli, Z; Sokolovski, D

    2016-01-01

    Investigations of low-energy electron-scattering of the lanthanide atoms Eu, Nd, Tb, Tm demonstrate that electron-correlation effects and core polarization are the dominant fundamental many-body effects responsible for the formation of metastable states of negative ions. Ramsauer Townsend minima, shape resonances and binding energies of the resultant anions are identified and extracted from the elastic total cross sections calculated using the complex angular momentum method. The large discrepancy between the recently measured electron affinity of 0.116 and the previously measured value of 1.053 eV for Eu is resolved. Also, the previously measured electron affinities for Nd, Tb and Tm are reconciled and new values are extracted from the calculated total cross sections. The large electron affinities found here for these atoms, should be useful in negative ion nanocatalysis, including methane conversion to methanol without CO2 emission, with significant environmental impact.. The powerful complex angular moment...

  4. K-shell ionization in relativistic ion-atom collisions

    Energy Technology Data Exchange (ETDEWEB)

    Mehler, G.; Soff, G.; Rumrich, K.; Greiner, W.

    1989-08-01

    We present calculations of K-shell ionization probabilities in asymmetric ion-atom collisions at relativistic velocities of the projectile. The time-dependent Dirac equation is represented as a system of coupled differential equations. The transition probabilities are determined using the coordinate space method. This necessitates an extension of the angular momentum coupling compared with nonrelativistic collision systems. Effects of the relativistic projectile motion on the coupling matrix elements and their consequences on K-shell ionization are discussed. (orig.).

  5. K-shell ionization in relativistic ion-atom collisions

    Energy Technology Data Exchange (ETDEWEB)

    Mehler, G.; Rumrich, K.; Greiner, W.; Soff, G.

    1989-02-01

    We present calculations of K-shell ionization probabilities in asymmetric ion-atom collisions at relativistic velocities of the projectile. The time-dependent Dirac equation is represented as a system of coupled differential equations. The transition probabilities are determined using the coordinate space method. This necessitates an extension of the angular momentum coupling compared with nonrelativistic collision systems. Effects of the relativistic projectile motion on the coupling matrix elements and their consequences on K-shell ionization are discussed.

  6. Measurements of scattering processes in negative ion-atom collisions

    Energy Technology Data Exchange (ETDEWEB)

    Kvale, T.J.

    1992-01-01

    This Technical Progress Report describes the progress made on the research objectives during the past twelve months. This research project is designed to provide measurements of various scattering processes which occur in H{sup {minus}} collisions with atomic (specifically, noble gas and atomic hydrogen) targets at intermediate energies. These processes include: elastic scattering,single- and double-electron detachment, and target excitation/ionization. For the elastic and target inelastic processes where H{sup {minus}} is scattered intact, the experimental technique of Ion Energy-Loss Spectroscopy (IELS) will be employed to identify the final target state(s). In most of the above processes, cross sections are unknown both experimentally and theoretically. The measurements in progress will provide either experimentally-determined cross sections or set upper limits to those cross sections. In either case, these measurements will be stringent tests of our understanding in energetic negative ion-atom collisions. This series of experiments required the construction of a new facility and the initial ion beam was accelerated through the apparatus in April 1991.

  7. Highly charged ions in exotic atoms research at PSI

    Energy Technology Data Exchange (ETDEWEB)

    Anagnostopoulos, D.F.; Biri, S.; Boisbourdain, V.; Demeter, M.; Borchert, G.; Egger, J.P.; Fuhrmann, H.; Gotta, D.; Gruber, A.; Hennebach, M.; Indelicato, P.; Liu, Y.W.; Manil, B.; Markushin, V.E.; Marton, H.; Nelms, N.; Rusi El Hassani, A.J.; Simons, L.M. E-mail: leopold.simons@psi.ch; Stingelin, L.; Wasser, A.; Wells, A.; Zmeskal, J

    2003-05-01

    During their de-excitation, exotic atoms formed in low pressure gases reach a state of high or even complete ionization. X-rays emitted from higher n-states of electron-free atoms have well defined energies with the error originating only from the error in the mass values of the constituent particles. They served as a basis for a new determination of the pion mass as well as for a high precision measurement of the pionic hydrogen ground state shift. The response function of the Bragg spectrometer has been determined with X-rays from completely ionized pionic carbon and with a dedicated electron cyclotron resonance ion trap (ECRIT). A further extension of the ECRIT method implemented in the experiment allows a direct calibration of exotic atom transitions as well as a precise determination of the energy of fluorescence lines.

  8. Bibliography on electron transfer processes in ion-ion/atom/molecule collisions. Updated 1997

    International Nuclear Information System (INIS)

    Following our previous compilations (IPPJ-AM-45 (1986), NIFS-DATA-7 (1990), NIFS-DATA-20 (1993)), bibliographic information on experimental and theoretical studies on electron transfer processes in ion-ion/atom/molecule collisions is up-dated. The references published through 1954-1996 are listed in the order of the publication year. For easy finding of the references for a combination of collision partners, a simple list is provided. (author)

  9. Effects of ion-atom collisions on the propagation and damping of ion-acoustic waves

    DEFF Research Database (Denmark)

    Andersen, H.K.; D'Angelo, N.; Jensen, Vagn Orla;

    1968-01-01

    Experiments are described on ion-acoustic wave propagation and damping in alkali plasmas of various degrees of ionization. An increase of the ratio Te/Ti from 1 to approximately 3-4, caused by ion-atom collisions, results in a decrease of the (Landau) damping of the waves. At high gas pressure and....../or low wave frequency a "fluid" picture adequately describes the experimental results....

  10. Bibliography on electron transfer processes in ion-ion/atom/molecule collisions, updated 1990

    International Nuclear Information System (INIS)

    Following a previous compilation, new bibliographic information on experimental and theoretical studies on electron transfer processes in ion-ion/atom/molecule collisions is up-dated. The references published through 1989 are surveyed. For easy finding references for particular combination of collision partners, a simple list is also provided. Furthermore, for convenience, a copy of the previous compilation (IPPJ-AM-45 (1986)) is included. (author) 1363 refs

  11. Bibliography on electron transfer processes in ion-ion/atom/molecule collisions. Updated 1997

    Energy Technology Data Exchange (ETDEWEB)

    Tawara, H.

    1997-04-01

    Following our previous compilations (IPPJ-AM-45 (1986), NIFS-DATA-7 (1990), NIFS-DATA-20 (1993)), bibliographic information on experimental and theoretical studies on electron transfer processes in ion-ion/atom/molecule collisions is up-dated. The references published through 1954-1996 are listed in the order of the publication year. For easy finding of the references for a combination of collision partners, a simple list is provided. (author)

  12. Dispersion coefficients for the interaction of inert gas atoms with alkali and alkaline earth ions and alkali atoms with their singly ionized ions

    CERN Document Server

    Singh, Sukhjit; Sahoo, B K; Arora, Bindiya

    2016-01-01

    We report the dispersion coefficients for the interacting inert gas atoms with the alkali ions, alkaline earth ions and alkali atoms with their singly charged ions. We use our relativistic coupled-cluster method to determine dynamic dipole and quadrupole polarizabilities of the alkali atoms and singly ionized alkaline earth atoms, whereas a relativistic random phase approximation approach has been adopted to evaluate these quantities for the closed-shell configured inert gas atoms and the singly and doubly ionized alkali and alkaline earth atoms, respectively. Accuracies of these results are adjudged from the comparison of their static polarizability values with their respective experimental results. These polarizabilities are further compared with the other theoretical results. Reason for the improvement in the accuracies of our estimated dispersion coefficients than the data listed in [At. Data and Nucl. Data Tables 101, 58 (2015)] are discussed. Results for some of the atom-ion interacting systems were not...

  13. Formation of molecular ions by radiative association of cold trapped atoms and ions

    Science.gov (United States)

    Dulieu, Olivier; da Silva, Humberto, Jr.; Aymar, Mireille; Raoult, Maurice

    2015-05-01

    Radiative emission during cold collisions between trapped laser-cooled Rb atoms and alkaline-earth ions (Ca+ , Sr+ , Ba+) and Yb+ are studied theoretically, using accurate effective-core-potential based quantum chemistry calculations of potential energy curves and transition dipole moments of the related molecular ions. Radiative association of molecular ions is predicted to occur for all systems with a cross section two to ten times larger than the radiative charge transfer one. Partial and total rate constants are also calculated and compared to available experiments. Narrow shape resonances are expected, which could be detectable at low temperature with an experimental resolution at the limit of the present standards. Vibrational distributions show that the final molecular ions are not created in their ground state level. Supported by the Marie-Curie ITN ``COMIQ: Cold Molecular Ions at the Quantum limit'' of the EU (#607491).

  14. Regularized perturbative series for the ionization potential of atomic ions

    CERN Document Server

    Gil, G

    2013-01-01

    We study N-electron atoms with nuclear charge Z. It is well known that, in the cationic (Z > N) high-Z region, the atom behaves as a weakly interacting system. The anionic (Z < N) regime, on the other hand, is characterized by an instability threshold at $Z \\lesssim N-1$ below which the atom spontaneously emits an electron. We construct a regularized perturbative series (RPS) for the ionization potential of ions in an isoelectronic sequence that exactly reproduces both, the large Z and the Z near $Z_c$ limits. The large-Z expansion coefficients are analytically computed from perturbation theory, whereas the slope of the energy curve at Z=N-1 is computed from a kind of zero-range forces theory that uses as input the electron affinity and the covalent radius of the neutral atom with N-1 electrons. Relativistic effects at the level of first-order perturbation theory in the one-particle Hamiltonian are considered. Our RPS results are compared with numbers from the NIST database.

  15. Reflections on the projection of ions in atom probe tomography

    CERN Document Server

    De Geuser, Frédéric

    2016-01-01

    There are two main projections used to transform, and reconstruct, field ion micrographs or atom probe tomography data into atomic coordinates at the specimen surface and, subsequently, in three-dimensions. In this article, we present a perspective on the strength of the azimuthal equidistant projection in comparison to the more widely used and well-established point-projection, which underpins data reconstruction in the only commercial software package available currently. After an overview of the reconstruction methodology, we demonstrate that the azimuthal equidistant is not only more accurate, but also more robust with regards to errors on the parameters used to perform the reconstruction and is therefore more likely to yield more accurate tomographic reconstructions.

  16. Theory of ion-atom collisions at high energy, I

    International Nuclear Information System (INIS)

    Electron capture process by an ion from a neutral atom is one of the fundamental problems in the theory of atomic collision physics. Here a brief review is given mainly on the processes of non-radiative and radiative electron capture (charge transfer and REC). The main mechanism which govern the charge transfer process is introduced and the characteristic feature which is predicted by the theory is explained. As for the radiative electron capture process, after introducting the present theories, the full-quantum mechanical theoretical treatment is introduced. The theory leads a result which includes some inconsistency with formulae obtained by guage transformation. The relativistic quantum mechanical treatment is being tried in order to remove this inconsistency. The some results including mass and velocity dependence are reported and discussed. (author)

  17. Analysis of the Pauli potential of atoms and ions

    International Nuclear Information System (INIS)

    The square root of the electron density satisfies a Schroedinger equation that contains a correction term called Pauli potential in addition to the usual one-body potential of the density functional theory. Earlier exact one-body potential was determined from the electron density for two- and three-level systems. The Pauli potential and the kinetic energy density corresponding to the Pauli potential are determined for several atoms and ions with several electrons. Properties of the Pauli potential are discussed. (author) 16 refs.; 10 figs

  18. Metallic atoms and ions in comets: Comet Halley 1986 3

    Science.gov (United States)

    Ibadov, S.

    1992-01-01

    The origin of metallic atoms and ions in the cometary comae is investigated theoretically. Two effects are revealed in the comas of bright comets: (1) the Na anomalous type effect is possible within the gas-dust jets of comet P/Halley 1986 3 due to cooling cometary dust by cryogenic gas flow from the nucleus; and (2) the production of ions of refractory elements (Fe(+), Si(+), etc.) at large heliocentric distances is possible in the comas of the Halley type dusty comets due to high-velocity impacts between cometary and zodiacal dust particles. Spectral observations of comets with high sensitivity and spatial resolution are important for studying both comets and interplanetary dust.

  19. Charge Exchange Collisions between Ultracold Fermionic Lithium Atoms and Calcium Ions

    CERN Document Server

    Haze, Shinsuke; Saito, Ryoichi; Mukaiyama, Takashi

    2014-01-01

    An observation of charge exchange collisions between ultracold fermionic 6Li atoms and 40Ca+ ions is reported. The reaction product of the charge exchange collision is dentified via mass spectrometry where the motion of the ions is excited parametrically. We measure the cross section of the charge exchange collisions between the 6Li atoms in the ground state and the 40Ca+ ions in the ground and metastable excited states. Investigation of the inelastic collision characteristics in the atom-ion mixture is an important step toward ultracold chemistry based on ultracold atoms and ions.

  20. Precise measurement of millisecond atomic lifetimes with heavy-ion storage ring and EBIT

    Energy Technology Data Exchange (ETDEWEB)

    Traebert, E. [I.P.N.E., Univ. de Liege, Liege (Belgium)]|[Bochum Univ. (Germany). Fakultaet fuer Physik und Astronomie]|[Lawrence Livermore National Lab., Livermore, CA (United States)

    2001-07-01

    Atomic lifetime measurements in the millisecond range have provided transition rates of intercombination and forbidden transitions in a number of ions. However, at the often claimed high level of precision, discrepancies appear between the results from different devices (Kingdon-type electrostatic ion trap, radiofrequency ion trap, electron beam ion trap and heavy-ion storage ring) measuring the same or comparable atomic systems. This calls for an assessment of the quality of typical measurements. (orig.)

  1. Cluster ions from keV-energy ion and atom bombardment of frozen gases

    Science.gov (United States)

    David, Donald E.; Magnera, Thomas F.; Tian, Rujiang; Stulik, Dusan; Michl, Josef

    1986-04-01

    A brief survey is given of the mass spectra obtained from frozen gases by bombardment with keV-energy ions and atoms. The internal chemical constitution of the observed secondary cluster ions, which bears no simple relation to the molecular structure of the solid, has been established by observations of collision-induced dissociation, laser-induced dissociation and metastable decay. It has been correlated with the chemical composition of the residual bombarded solid, deduced from spectroscopic observations. These results, as well as preliminary results on sputtering yields for impact of 1-4 keV rare gas ions on solid argon, are compatible with the previously proposed mechanistic model for the formation of the cluster ions based on the flow of supercritical gas from the elastic collision spike region.

  2. Formation of molecular ions by radiative association of cold trapped atoms and ions

    CERN Document Server

    Silva, Humberto Da; Aymar, Mireille; Dulieu, Olivier

    2015-01-01

    Radiative emission during cold collisions between trapped laser-cooled Rb atoms and alkaline-earth ions (Ca + , Sr + , Ba +) and Yb + are studied theoretically, using accurate effective-core-potential based quantum chemistry calculations of potential energy curves and transition dipole moments of the related molecular ions. Radiative association of molecular ions is predicted to occur for all systems with a cross section two to ten times larger than the radiative charge transfer one. Partial and total rate constants are also calculated and compared to available experiments. Narrow shape resonances are expected, which could be detectable at low temperature with an experimental resolution at the limit of the present standards. Vibrational distributions are also calculated, showing that the final molecular ions are not created in their ground state level.

  3. Atomic excitations in heavy ion collisions with nuclear contact

    International Nuclear Information System (INIS)

    The dynamical semiclassical theory of atomic excitations, especially of positron creation, in heavy ion scattering is presented and extended to collisions with nuclear contact. The characteristic dependence of inner shell vacancy formation on nuclear reaction times as well as the emergence of interference patterns in the energy spectra of emitted delta-electrons and positrons in delayed collisions is discussed in terms of a simplified, schematic model for the nuclear reaction dynamics. In addition, the spontaneous decay mechanism in giant nuclear systems with Z> or approx.173 leads, for sufficiently long reaction times, to a characteristic line in the positron spectra at the position of the 1ssigma-resonance. The position and width of the positron line is calculated in dependence on the nuclear configuration taking into account the influence of the electron-electron interaction. Furthermore, a quantum mechanical extension of our semiclassical treatment of the atomic scattering process and its effect on atomic positron spectra are discussed. In addition, the influence of E0-transitions in the giant nuclear system on positron emission is treated qualitatively in a semiclassical approximation, indicating that nuclear collective modes can be revealed by the measurement of Stokes and anti-Stokes lines in the positron spectra. (orig./HSI)

  4. Cycle Time Reduction in Trapped Mercury Ion Atomic Frequency Standards

    Science.gov (United States)

    Burt, Eric A.; Tjoelker, Robert L.; Taghavi, Shervin

    2011-01-01

    The use of the mercury ion isotope (201)Hg(+) was examined for an atomic clock. Taking advantage of the faster optical pumping time in (201)Hg(+) reduces both the state preparation and the state readout times, thereby decreasing the overall cycle time of the clock and reducing the impact of medium-term LO noise on the performance of the frequency standard. The spectral overlap between the plasma discharge lamp used for (201)Hg(+) state preparation and readout is much larger than that of the lamp used for the more conventional (199)Hg(+). There has been little study of (201)Hg(+) for clock applications (in fact, all trapped ion clock work in mercury has been with (199)Hg(+); however, recently the optical pumping time in (201)Hg(+) has been measured and found to be 0.45 second, or about three times faster than in (199)Hg(+) due largely to the better spectral overlap. This can be used to reduce the overall clock cycle time by over 2 seconds, or up to a factor of 2 improvement. The use of the (201)Hg(+) for an atomic clock is totally new. Most attempts to reduce the impact of LO noise have focused on reducing the interrogation time. In the trapped ion frequency standards built so far at JPL, the optical pumping time is already at its minimum so that no enhancement can be had by shortening it. However, by using (201)Hg(+), this is no longer the case. Furthermore, integrity monitoring, the mechanism that determines whether the clock is functioning normally, cannot happen faster than the clock cycle time. Therefore, a shorter cycle time will enable quicker detection of failure modes and recovery from them.

  5. An Analytical Model for Adsorption and Diffusion of Atoms/Ions on Graphene Surface

    Directory of Open Access Journals (Sweden)

    Yan-Zi Yu

    2015-01-01

    Full Text Available Theoretical investigations are made on adsorption and diffusion of atoms/ions on graphene surface based on an analytical continuous model. An atom/ion interacts with every carbon atom of graphene through a pairwise potential which can be approximated by the Lennard-Jones (L-J potential. Using the Fourier expansion of the interaction potential, the total interaction energy between the adsorption atom/ion and a monolayer graphene is derived. The energy-distance relationships in the normal and lateral directions for varied atoms/ions, including gold atom (Au, platinum atom (Pt, manganese ion (Mn2+, sodium ion (Na1+, and lithium-ion (Li1+, on monolayer graphene surface are analyzed. The equilibrium position and binding energy of the atoms/ions at three particular adsorption sites (hollow, bridge, and top are calculated, and the adsorption stability is discussed. The results show that H-site is the most stable adsorption site, which is in agreement with the results of other literatures. What is more, the periodic interaction energy and interaction forces of lithium-ion diffusing along specific paths on graphene surface are also obtained and analyzed. The minimum energy barrier for diffusion is calculated. The possible applications of present study include drug delivery system (DDS, atomic scale friction, rechargeable lithium-ion graphene battery, and energy storage in carbon materials.

  6. Foil dissociation of fast molecular ions into atomic excited states

    International Nuclear Information System (INIS)

    The intensity and polarizations of light emitted from atomic excited states of dissociated molecular ions were measured. The dissociations are induced when fast molecular ions (50 to 500 keV/amu) are transmitted through thin carbon foils. A calculation of multiple scattering and the Coulomb explosion gives the average internuclear separation of the projectile at the foil surface. Experimentally, the foil thickness is varied to give varying internuclear separations at the foil surface and observe the consequent variation in light yield and optical polarization. Using HeH+ projectiles, factors of 1 to 5 enhancements of the light yields from n = 3, 13P,D states of He I and some He II and H I emissions were observed. The results can be explained in terms of molecular level crossings which provide mixings of the various final states during dissociation of the molecular ions at the exit surface. They suggest a short range surface interaction of the electron pick-up followed by a slow molecular dissociation. Alignment measurements confirm the essential features of the model. Observations of Lyman α emission after dissociation of H2+ amd H3+ show rapid variations in light yield for small internuclear separations at the foil surface

  7. Emulating solid-state physics with a hybrid system of ultracold ions and atoms

    OpenAIRE

    Bissbort U.; Cocks D.; Negretti A.; Idziaszek Z.; Calarco T.; Schmidt-Kaler F.; Hofstetter W.; Gerritsma R.

    2013-01-01

    We propose and theoretically investigate a hybrid system composed of a crystal of trapped ions coupled to a cloud of ultracold fermions. The ions form a periodic lattice and induce a band structure in the atoms. This system combines the advantages of scalability and tunability of ultracold atomic systems with the high fidelity operations and detection offered by trapped ion systems. It also features close analogies to natural solid-state systems, as the atomic degrees of freedom couple to pho...

  8. Atomic physics with highly charged ions. Progress report, 15 February 1985-14 February 1986

    International Nuclear Information System (INIS)

    The experimental program has three directions: the study of collisions of very low velocity, highly-charged secondary recoil ions with stationary gas atoms, the study of collisions of high velocity, highly-charged ions with stationary targets, and the study of the theoretical descriptions of atomic collisions and atomic structure properties of highly-charged ions. Brief reports of the progress in these areas are given

  9. Methane Oxidation to Methanol without CO2 Emission: Catalysis by Atomic Negative Ions

    OpenAIRE

    Tesfamichael, Aron; Suggs, Kelvin; Felfli, Zineb; Msezane, Alfred Z

    2014-01-01

    The catalytic activities of the atomic Y-, Ru-, At-, In-, Pd-, Ag-, Pt-, and Os- ions have been investigated theoretically using the atomic Au- ion as the benchmark for the selective partial oxidation of methane to methanol without CO2 emission. Dispersion-corrected density-functional theory has been used for the investigation. From the energy barrier calculations and the thermodynamics of the reactions, we conclude that the catalytic effect of the atomic Ag-, At-, Ru-, and Os- ions is higher...

  10. Symmetric eikonal model for projectile-electron excitation and loss in relativistic ion-atom collisions

    OpenAIRE

    Voitkiv, A. B.; Najjari, B.; Shevelko, S. P.

    2010-01-01

    At impact energies $ \\stackrel{>}{\\sim}1$ GeV/u the projectile-electron excitation and loss occurring in collisions between highly charged ions and neutral atoms is already strongly influenced by the presence of atomic electrons. In order to treat these processes in collisions with heavy atoms we generalize the symmetric eikonal model, used earlier for considerations of electron transitions in ion-atom collisions within the scope of a three-body Coulomb problem. We show that at asymptotically...

  11. Atom probe field ion microscopy and related topics: A bibliography 1991

    International Nuclear Information System (INIS)

    This report contains a bibliography for 1991 on the following topics: Atom probe field ion microscopy; field desorption mass spectrometry; field emission; field ion microscopy; and field emission theory

  12. Atom probe field ion microscopy and related topics: A bibliography 1991

    Energy Technology Data Exchange (ETDEWEB)

    Russell, K.F.; Miller, M.K.

    1993-01-01

    This report contains a bibliography for 1991 on the following topics: Atom probe field ion microscopy; field desorption mass spectrometry; field emission; field ion microscopy; and field emission theory.

  13. Design of ion-atom channel of the T-15 tokamak injector

    International Nuclear Information System (INIS)

    Calculation parameters of ion-atom channel elements are given and the design of T-15 tokamak injectors meant for input of atom beam of 10 MW power at 80 keV energy and pulse duration 1,5 sec. into the tokamak chamber for plasma heating as described. Injection system is based on simultaneous operation of three autonomous injectors. In each injector two modules of ion sources are mounted. The ion-atom channel of the injector consists of two ion sources neutralizer of ions beam into fast atoms beam magnetic flit shield, diaphragms ion and atom receptors deflecting electromagnet, cryopanels of 15 cm2 general area, rectangular vacuum chamber manufactured of sheet steel 12Kh18N10T of 16 mm thickness. The vacuum chamber weight constitutes 25 tons volume 24,5 m3. Ion sources are situated one above another by vertical order. In neutralizers ion beams formed are converted into fast atom beams on gas base. Behind the neutralizer situated is magnetic flit shield along the length of which gas pumping out occurs. Separation of atoms and non recharged ions is realized by the deflecting electromagnet. The deflected ions get to the receptor and fast atoms by atomguide into the tokamak. The injector diaphragm protects the electromagnet construction from overheating

  14. Rearrangement reactions in ion-ion and ion-atom collisions: results and problems

    Energy Technology Data Exchange (ETDEWEB)

    Presnyakov, L.P. [Lebedev Physical Institute, Moscow (Russian Federation); Tawara, H.

    1997-01-01

    Recent experimental and theoretical results are discussed for ionic collisions with large cross sections at intermediate and small energies of the relative motion. Single- and double-electron removal from H{sup -} ions in slow collisions with other ions is considered in more details. The theoretical methods are discussed from the viewpoint of general requirements of scattering theory. (author)

  15. Calculation of electron scattering on atoms and ions

    Energy Technology Data Exchange (ETDEWEB)

    Bray, I.

    1995-02-01

    This paper reviews the applications of the convergent close-coupling (CCC) method to electron scattering on light atoms and ions. Particular emphasis is given to those areas where other theories have difficulty, e g. total ionization cross sections and the associated spin asymmetries. It begins with the simplest application to the Temkin-Poet model problem of electron-hydrogen scattering, which is used to validate the CCC approach. Subsequently, results are given for electron impact ionization of various initial states of the targets H(1s,2s), He(1{sup 1}S,2{sup 3.1}S), He{sup +}(1s), Li(2s), O{sup 5+}(2s) and Na(3s). 50 refs., 10 figs.

  16. A New ECR Ion Source for Atomic Physics Research at IMP

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A new Electron Cyclotron Resonance (ECR) ion source (LECR3-Lanzhou Electron Cyclotron Resonance ion source No.3) was constructed this year. The main purpose of this source is to provide highly charged ion beams for atomic physics and surface physics research. The design of this ion source is based on the IMP 14.5 GHz ECR ion source (LECR2-Lanzhou Electron Cyclotron Resonance ion source No.2) with double RF heating

  17. QED corrections to atomic wavefunctions in highly charged ions

    International Nuclear Information System (INIS)

    Bound electron states in highly charged ions are strongly influenced by the effects of relativity and quantum electrodynamics (QED). These effects induce shifts of the binding energies as well as corrections to observables related to atomic processes. In this work a numerical procedure is described and implemented in which the QED effects are treated as corrections to relativistic bound-state wavefunctions. This approach, which is based on the recently developed covariant evolution-operator formalism, allows for a merging of QED with the standard methods of many-body perturbation theory. In particular, it enables an evaluation of the combined effect of QED and electron correlation in few-electron systems. Numerical results for this effect are presented for the ground state energy of helium-like ions. A detailed analysis of the contribution from the electron self-energy is carried out in both the Feynman and Coulomb gauge. It is found that the Feynman gauge suffers from large numerical cancellations and acquires significant contributions from terms involving multiple interactions with the nuclear potential (the so-called many-potential terms), while the Coulomb gauge is well suited for an approximate treatment based on terms involving only freely propagating electrons (the zero-potential terms). With the help of QED-corrected wavefunctions it is also possible to compute corrections to observables in basic atomic processes. In this work some of the one-loop QED corrections (those derivable from perturbed wavefunctions and energies) to the differential cross section and distribution of polarization in radiative recombination of initially bare uranium nuclei are evaluated, as well as the corresponding corrections to the ratio τE1/τM2 of the electric dipole and magnetic quadrupole transition amplitudes in the 2p3/2→1s radiative decay of hydrogenlike uranium. The results from these calculations are all of the expected magnitude, namely on the order of the fine

  18. QED corrections to atomic wavefunctions in highly charged ions

    Energy Technology Data Exchange (ETDEWEB)

    Holmberg, Johan

    2015-11-18

    Bound electron states in highly charged ions are strongly influenced by the effects of relativity and quantum electrodynamics (QED). These effects induce shifts of the binding energies as well as corrections to observables related to atomic processes. In this work a numerical procedure is described and implemented in which the QED effects are treated as corrections to relativistic bound-state wavefunctions. This approach, which is based on the recently developed covariant evolution-operator formalism, allows for a merging of QED with the standard methods of many-body perturbation theory. In particular, it enables an evaluation of the combined effect of QED and electron correlation in few-electron systems. Numerical results for this effect are presented for the ground state energy of helium-like ions. A detailed analysis of the contribution from the electron self-energy is carried out in both the Feynman and Coulomb gauge. It is found that the Feynman gauge suffers from large numerical cancellations and acquires significant contributions from terms involving multiple interactions with the nuclear potential (the so-called many-potential terms), while the Coulomb gauge is well suited for an approximate treatment based on terms involving only freely propagating electrons (the zero-potential terms). With the help of QED-corrected wavefunctions it is also possible to compute corrections to observables in basic atomic processes. In this work some of the one-loop QED corrections (those derivable from perturbed wavefunctions and energies) to the differential cross section and distribution of polarization in radiative recombination of initially bare uranium nuclei are evaluated, as well as the corresponding corrections to the ratio τ{sub E1}/τ{sub M2} of the electric dipole and magnetic quadrupole transition amplitudes in the 2p{sub 3/2}→1s radiative decay of hydrogenlike uranium. The results from these calculations are all of the expected magnitude, namely on the order

  19. Non-destructive detection of ions using atom-cavity collective strong coupling

    CERN Document Server

    Dutta, Sourav

    2016-01-01

    We present a technique, based on atoms coupled to an optical cavity, for non-destructive detection of trapped ions. We demonstrate the vacuum-Rabi splitting (VRS), arising due to the collective strong coupling of ultracold Rb atoms to a cavity, to change in presence of trapped Rb+ ions. The Rb+ ions are optically dark and the Rb atoms are prepared in a dark magneto-optical trap (MOT). The VRS is measured on an optically open transition of the initially dark Rb atoms. The measurement itself is fast, non-destructive and has sufficient fidelity to permit the measurement of atomic-state selective ion-atom collision rate. This demonstration illustrates a method based on atom-cavity coupling to measure two particle interactions generically and non-destructively.

  20. Finite size dependent dispersion potentials between atoms and ions dissolved in water

    CERN Document Server

    Thiyam, P; Persson, C; Parsons, D F; Brevik, I; Sernelius, Bo E

    2014-01-01

    A non-expanded theory is used for dispersion potentials between atoms and ions dissolved in a medium. The first-order dispersion interaction between two atoms in an excited state must account for the fact that the two atoms are coupled via the electromagnetic field and must include effects from background media, retardation and finite size. We show that finite-size corrections when two particles are close change the dispersion interactions in water by several orders of magnitude. We consider as four illustrative examples helium atoms, krypton atoms, phosphate ions, and iodide ions. We demonstrate that, due to large cancellation effects, retardation dominates the interaction for helium atom pairs in an isotropic excited state down to the very small atom-atom separations where finite-size corrections are also important

  1. Ion-neutral chemistry at ultralow energies: Dynamics of reactive collisions between laser-cooled Ca^+ ions and Rb atoms in an ion-atom hybrid trap

    CERN Document Server

    Hall, Felix H J; Hegi, Gregor; Raoult, Maurice; Aymar, Mireille; Dulieu, Olivier; Willitsch, Stefan

    2013-01-01

    Cold chemical reactions between laser-cooled Ca^+ ions and Rb atoms were studied in an ion-atom hybrid trap. Reaction rate constants were determined in the range of collision energies /k_B = 20 mK-20 K. The lowest energies were achieved in experiments using single localized Ca^+ ions. Product branching ratios were studied using resonant-excitation mass spectrometry. The dynamics of the reactive processes in this system (non-radiative and radiative charge transfer as well as radiative association leading to the formation of CaRb^+ molecular ions) have been analyzed using high-level quantum-chemical calculations of the potential energy curves of CaRb^+ and quantum-scattering calculations for the radiative channels. For the present low-energy scattering experiments, it is shown that the energy dependence of the reaction rate constants is governed by long-range interactions in line with the classical Langevin model, but their magnitude is determined by short-range non-adiabatic and radiative couplings which only ...

  2. Treatment of Ion-Atom Collisions Using a Partial-Wave Expansion of the Projectile Wavefunction

    Science.gov (United States)

    Wong, T. G.; Foster, M.; Colgan, J.; Madison, D. H.

    2009-01-01

    We present calculations of ion-atom collisions using a partial-wave expansion of the projectile wavefunction. Most calculations of ion-atom collisions have typically used classical or plane-wave approximations for the projectile wavefunction, since partial-wave expansions are expected to require prohibitively large numbers of terms to converge…

  3. Contribution of nitrogen atoms and ions to the luminescence emission during femotosecond filamentation in air

    Science.gov (United States)

    Li, Su-Yu; Li, Shu-Chang; Sui, Lai-Zhi; Jiang, Yuan-Fei; Chen, An-Min; Jin, Ming-Xing

    2016-01-01

    During femtosecond filamentation in air, nitrogen molecules and corresponding molecular ions undergo dissociation due to the high intensity of laser pulses, generating nitrogen atoms and atomic ions. The generated atoms and atomic ions emit luminescence in the UV range, which superposes on those emissions for the neutral and ionic nitrogen molecules. Here we report on a significant difference between the emission behavior of the 391-nm line and the other spectral lines under different pump laser polarizations. We attribute this difference to the contribution of the atomic ions to the luminescence emission around 391 nm. The difference becomes more evident in tightly focusing cases, providing an indirect but effective evidence for the dissociation of nitrogen molecular ions.

  4. Magneto optical trap recoil ion momentum spectroscopy: application to ion-atom collisions

    International Nuclear Information System (INIS)

    87Rb atoms have been cooled, trapped and prepared as targets for collision studies with 2 and 5 keV Na+ projectiles. The physics studied deals with charge exchange processes. The active electron, which is generally the most peripheral electron of the atomic target, is transferred from the target onto the ionic projectile. The ionized target is called recoil ion. The technique used to study this physics is the MOTRIMS (Magneto Optical Trap Recoil Ion Momentum Spectroscopy) technique, which combines a magneto optical trap and a recoil ion momentum spectrometer. The spectrometer is used for the measurement of the recoil ions momentum, which gives access to all the information of the collision: the Q-value (which is the potential energy difference of the active electron on each particle) and the scattering angle of the projectile. The trap provides extremely cold targets to optimize the measurement of the momentum, and to release the latter from thermal motion. Through cinematically complete experiments, the MOTRIMS technique gives access to better resolutions on momentum measurements. Measurements of differential cross sections in initial and final capture states and in scattering angle have been done. Results obtained for differential cross sections in initial and final states show globally a good agreement with theory and an other experiment. Nevertheless, discrepancies with theory and this other experiment are shown for the measurements of doubly differential cross sections. These discrepancies are not understood yet. The particularity of the experimental setup designed and tested in this work, namely a low background noise, allows a great sensitivity to weak capture channels, and brings a technical and scientific gain compared with previous works. (author)

  5. Investigation of Linear Tetra-Atomic Negative Ion by Photodetached-Electron Spectra

    Institute of Scientific and Technical Information of China (English)

    A.Rahman; Iftikhar Ahmad; A.Afaq; M.Haneef; H.J.Zhao

    2011-01-01

    @@ Photodetachment spectra from a linear tetra-atomic negative ion is investigated by treating the detached-electron wave function quantum mechanically.A plane polarized laser light, perpendicular to the axis of the ion, is used to detach the electron from the ion.Analytical expressions for the electron flux and total photodetachment cross section are derived.The electron flux on screen shows strong-energy-dependent oscillations with different frequencies.The total cross section of the tetra-atomic negative ion reduces the cross section of mono-atomic,diatomic and triatomic negative ions for high energy photons, while for low energy photons it becomes four times the cross section of mono-atomic negative ions.

  6. Simultaneous K plus L shell ionized atoms during heavy-ion collision process

    Indian Academy of Sciences (India)

    G A V Ramana Murty; G J Naga Raju; V Vijayan; T Ranjan Rautray; B Seetharami Reddy; S Lakshminarayana; K L Narasimham; S Bhuloka Reddy

    2004-06-01

    The fraction of simultaneous K plus L shell ionized atoms is estimated in Fe, Co and Cu elements using carbon ions at different projectile energies. The present results indicate that the fraction of simultaneous K plus L shell ionization probability decreases with increase in projectile energy as well as with increase in the atomic number of the targets atoms.

  7. Multiple Electron Capture Processes in Slow Collisions of Ar9+ Ions with Na Atoms

    Institute of Scientific and Technical Information of China (English)

    ZhuXiaolong; ShaShan; LiuHuiping; WeiBaoren; MaXinwen; WangZhengling; CaoShiping; QianDongbing; YangZhihu

    2003-01-01

    Slow collisions of highly charged ions with neutral atoms and molecules are of great importance in basic atomic collision physics, Recently, we built a new research facility for atomic physics at the Institute of Modern Physics. We report here the multiple electron transfer processes in collisions of Ar9+ with Na gas target at energy of 180 keV.

  8. Learning about three particle continuum states from fast ion-atom collisions

    International Nuclear Information System (INIS)

    Preliminary results for two fast ion-atom collision experiments were presented. The double detachment of H- leads to some low energy three-particle states which offer interesting possibilities for further investigations into the three-particle Coulomb problem. Secondary electrons from fast ion-atom collisions moving in the region between the two resulting ions appear to express some special features that merit further experimental and theoretical work. 8 refs.; 2 figs

  9. Experimental studies of ions and atoms interaction with insulating surface

    International Nuclear Information System (INIS)

    Grazing collisions (+, Ne+, Ne0, Na+ on LiF (001) single crystal, an ionic insulator, are investigated by a time of flight technique. The incident beam is chopped and the scattered particles are collected on a position sensitive detector providing differential cross section while the time of flight gives the energy loss. Deflection plates allow the charge state analysis. Secondary electrons are detected in coincidence allowing direct measurements of electron emission yield, angular and energetic distribution through time of flight measurements. The target electronic structure characterized by a large band gap, governs the collisional processes: charge exchange, electronic excitations and electron emission. In particular, these studies show that the population of local target excitations surface excitons is the major contribution to the kinetic energy transfer (stopping power). Auger neutralization of Ne+ and He+ ions reveals the population of quasi-molecular excitons, an exciton bound on two holes. Referenced in the literature as trion. A direct energy balance determines the binding energy associated with these excited states of the surface. Besides these electronic energy loss processes, two nuclear energy loss mechanisms are characterized. These processes imply momentum transfer to individual target atoms during close binary collisions or, if the projectile is charged, to collective mode of optical phonons induced by the projectile coulomb field. The effect of the temperature on the scattering profile, the contribution of topological surface defects to the energy loss profile and to skipping motion on the surface are analyzed in view of classical trajectory simulations. (author)

  10. Progress in numerical calculations of ion-atom collisions

    Energy Technology Data Exchange (ETDEWEB)

    Reading, J.F.; Ford, A.L.; Becker, R.L.

    1983-01-01

    An ion-atom collision produces a time dependent perturbation of a many fermion system. In this collision, excitation, ionization and charge transfer can occur. The driving mechanism for these processes may be thought of as the potentials seen by individual electrons at any given separation of the projectile and target nuclei. If we think of these potentials as belonging to the target (a nucleus and electrons) and the projectile (another nucleus and electrons) then as detected by an electron the potentials change because: (a) the target and projectile change position, and (b) electrons on the target and projectile change states. Most work in the past fifty years has concentrated on solving the independent particle model (IPM). Cracks are beginning to appear in this model which only allows for type (a) changes in the potential. But in a short review we shall have quite enough to do in understanding the progress made in the last decade on the IPM. This paper is divided into three parts. The first deals with how to reduce the IPM to the single electron model (SEM). The second is on a new method where charge transfer is important. The third confronts some standard models with modern calculations.

  11. Progress in numerical calculations of ion-atom collisions

    International Nuclear Information System (INIS)

    An ion-atom collision produces a time dependent perturbation of a many fermion system. In this collision, excitation, ionization and charge transfer can occur. The driving mechanism for these processes may be thought of as the potentials seen by individual electrons at any given separation of the projectile and target nuclei. If we think of these potentials as belonging to the target (a nucleus and electrons) and the projectile (another nucleus and electrons) then as detected by an electron the potentials change because: (a) the target and projectile change position, and (b) electrons on the target and projectile change states. Most work in the past fifty years has concentrated on solving the independent particle model (IPM). Cracks are beginning to appear in this model which only allows for type (a) changes in the potential. But in a short review we shall have quite enough to do in understanding the progress made in the last decade on the IPM. This paper is divided into three parts. The first deals with how to reduce the IPM to the single electron model (SEM). The second is on a new method where charge transfer is important. The third confronts some standard models with modern calculations

  12. Calculation of the ionization differential effective cross sections in fast ion-atom collisions

    CERN Document Server

    Kaminskij, A K

    2002-01-01

    The method of the calculations of the ionization effective cross sections d sigma/d OMEGA differential in the incident ion scattering angle is described in fast collisions of light ions and atoms. The calculated values of angular distributions of the ions Al, Mg (for the different values of charge and energy of ions) after their collisions with the Ne, Mg atoms being ionized are reported. The dependence of such angular distributions on the incident ion charge and energy and the initial state of ejected electron is investigated

  13. Emulating solid-state physics with a hybrid system of ultracold ions and atoms.

    Science.gov (United States)

    Bissbort, U; Cocks, D; Negretti, A; Idziaszek, Z; Calarco, T; Schmidt-Kaler, F; Hofstetter, W; Gerritsma, R

    2013-08-23

    We propose and theoretically investigate a hybrid system composed of a crystal of trapped ions coupled to a cloud of ultracold fermions. The ions form a periodic lattice and induce a band structure in the atoms. This system combines the advantages of high fidelity operations and detection offered by trapped ion systems with ultracold atomic systems. It also features close analogies to natural solid-state systems, as the atomic degrees of freedom couple to phonons of the ion lattice, thereby emulating a solid-state system. Starting from the microscopic many-body Hamiltonian, we derive the low energy Hamiltonian, including the atomic band structure, and give an expression for the atom-phonon coupling. We discuss possible experimental implementations such as a Peierls-like transition into a period-doubled dimerized state. PMID:24010420

  14. Emulating solid-state physics with a hybrid system of ultracold ions and atoms.

    Science.gov (United States)

    Bissbort, U; Cocks, D; Negretti, A; Idziaszek, Z; Calarco, T; Schmidt-Kaler, F; Hofstetter, W; Gerritsma, R

    2013-08-23

    We propose and theoretically investigate a hybrid system composed of a crystal of trapped ions coupled to a cloud of ultracold fermions. The ions form a periodic lattice and induce a band structure in the atoms. This system combines the advantages of high fidelity operations and detection offered by trapped ion systems with ultracold atomic systems. It also features close analogies to natural solid-state systems, as the atomic degrees of freedom couple to phonons of the ion lattice, thereby emulating a solid-state system. Starting from the microscopic many-body Hamiltonian, we derive the low energy Hamiltonian, including the atomic band structure, and give an expression for the atom-phonon coupling. We discuss possible experimental implementations such as a Peierls-like transition into a period-doubled dimerized state.

  15. Methane Oxidation to Methanol without CO2 Emission: Catalysis by Atomic Negative Ions

    CERN Document Server

    Tesfamichael, Aron; Felfli, Zineb; Msezane, Alfred Z

    2014-01-01

    The catalytic activities of the atomic Y-, Ru-, At-, In-, Pd-, Ag-, Pt-, and Os- ions have been investigated theoretically using the atomic Au- ion as the benchmark for the selective partial oxidation of methane to methanol without CO2 emission. Dispersion-corrected density-functional theory has been used for the investigation. From the energy barrier calculations and the thermodynamics of the reactions, we conclude that the catalytic effect of the atomic Ag-, At-, Ru-, and Os- ions is higher than that of the atomic Au- ion catalysis of CH4 conversion to methanol. By controlling the temperature around 290K (Os-), 300K (Ag-), 310K (At-), 320K (Ru-) and 325K (Au-) methane can be completely oxidized to methanol without the emission of CO2. We conclude by recommending the investigation of the catalytic activities of combinations of the above negative ions for significant enhancement of the selective partial oxidation of methane to methanol.

  16. Structure of the Alkali-metal-atom-Strontium molecular ions: towards photoassociation and formation of cold molecular ions

    OpenAIRE

    Aymar, Mireille; Guérout, Romain; Dulieu, Olivier

    2011-01-01

    The potential energy curves, permanent and transition dipole moments, and the static dipolar polarizability, of molecular ions composed of one alkali-metal atom and a Strontium ion are determined with a quantum chemistry approach. The molecular ions are treated as effective two-electron systems and are treated using effective core potentials including core polarization, large gaussian basis sets, and full configuration interaction. In the perspective of upcoming experiments aiming at merging ...

  17. Atom-by-atom engineering of voltage-gated ion channels: Magnified insights into function and pharmacology

    DEFF Research Database (Denmark)

    Pless, Stephan Alexander; Kim, Robin Y; Ahern, Christopher A;

    2015-01-01

    Unnatural amino acid incorporation into ion channels has proven to be a valuable approach to interrogate detailed hypotheses arising from atomic resolution structures. In this short review, we provide a brief overview of some of the basic principles and methods for incorporation of unnatural amin...... acids into proteins. We also review insights into the function and pharmacology of voltage-gated ion channels that have emerged from unnatural amino acid mutagenesis approaches....

  18. Energy losses of fast heavy multiply charged structural ions in collisions with complex atoms

    Science.gov (United States)

    Matveev, V. I.; Sidorov, D. B.

    2007-07-01

    A nonperturbatve theory of energy losses of fast heavy multiply charged structural ions in collisions with neutral complex atoms is elaborated with allowance for simultaneous excitations of ionic and atomic electron shells. Formulas for the effective deceleration that are similar to the well-known Bethe-Bloch formulas are derived. By way of example, the energy lost by partially stripped U q+ ions (10 ≤ q ≤ 70) colliding with argon atoms and also the energy lost by Au, Pb, and Bi ions colliding with various targets are calculated. The results of calculation are compared with experimental data.

  19. Level-energy-dependent mean velocities of excited tungsten atoms sputtered by krypton-ion bombardment

    Energy Technology Data Exchange (ETDEWEB)

    Nogami, Keisuke; Sakai, Yasuhiro; Mineta, Shota [Department of Physics, Toho University, Miyama, Funabashi, Chiba 274-8510 (Japan); Kato, Daiji; Murakami, Izumi [National Institute for Fusion Science, Toki, Gifu 509-5292, Japan and Department of Fusion Science, School of Physical Sciences, SOKENDAI (The Graduate University for Advanced Studies), Toki, Gifu 509-5292 (Japan); Sakaue, Hiroyuki A. [National Institute for Fusion Science, Toki, Gifu 509-5292 (Japan); Kenmotsu, Takahiro [Department of Biomedical Engineering, Faculty of Life and Medical Sciences, Doshisha University, Tatara-Miyakodani, Kyotanabe, Kyoto 610-0394 (Japan); Furuya, Kenji [Faculty of Arts and Science, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395 (Japan); Motohashi, Kenji, E-mail: motohashi@toyo.jp [Department of Biomedical Engineering, Faculty of Science and Engineering, Toyo University, 2100 Kujirai, Kawagoe, Saitama 350-8585, Japan and Bio-Nano Electronics Research Centre, Toyo University, 2100 Kujirai, Kawagoe, Saitama 350-8585 (Japan)

    2015-11-15

    Visible emission spectra were acquired from neutral atoms sputtered by 35–60 keV Kr{sup +} ions from a polycrystalline tungsten surface. Mean velocities of excited tungsten atoms in seven different 6p states were also obtained via the dependence of photon intensities on the distance from the surface. The average velocities parallel to the surface normal varied by factors of 2–4 for atoms in the different 6p energy levels. However, they were almost independent of the incident ion kinetic energy. The 6p-level energy dependence indicated that the velocities of the excited atoms were determined by inelastic processes that involve resonant charge exchange.

  20. Ion-metal and ion-atom collisions instant replays and mean-field theories

    International Nuclear Information System (INIS)

    In this paper, we describe the results of our general long-term programmatic goal of investigating the strengths and weaknesses of time-dependent mean-field theories for collisions. We have made some progress in: (a) obtaining a better formulation of the theory, which has the exact full Schroedinger equation as one limit and permits appropriate classical treatment of heavy particles correctly coupled to the quantally treated electrons; (b) restructuring our numerical treatment to make it fully three-dimensional, improve accuracy and decrease cycle time, so that larger problems more in keeping with the mean-field concept can be treated; and (c) incorporating the electrons in the conduction band of a metal into our quantal treatment, making possible the description of collisions of atoms and ions with solids. Numerical results for protons tranversing a thin metallic foil, among other examples, are presented and discussed

  1. Investigation of accelerated neutral atom beams created from gas cluster ion beams

    Energy Technology Data Exchange (ETDEWEB)

    Kirkpatrick, A., E-mail: akirkpatrick@exogenesis.us [Exogenesis Corporation, 20 Fortune Drive, Billerica, MA 01821 (United States); Kirkpatrick, S.; Walsh, M.; Chau, S.; Mack, M.; Harrison, S.; Svrluga, R.; Khoury, J. [Exogenesis Corporation, 20 Fortune Drive, Billerica, MA 01821 (United States)

    2013-07-15

    A new concept for ultra-shallow processing of surfaces known as accelerated neutral atom beam (ANAB) technique employs conversion of energetic gas cluster ions produced by the gas cluster ion beam (GCIB) method into intense collimated beams of coincident neutral gas atoms having controllable average energies from less than 10 eV per atom to beyond 100 eV per atom. A beam of accelerated gas cluster ions is first produced as is usual in GCIB, but conditions within the source ionizer and extraction regions are adjusted such that immediately after ionization and acceleration the clusters undergo collisions with non-ionized gas atoms. Energy transfer during these collisions causes the energetic cluster ions to release many of their constituent atoms. An electrostatic deflector is then used to eliminate charged species, leaving the released neutral atoms to still travel collectively at the same velocities they had as bonded components of their parent clusters. Upon target impact, the accelerated neutral atom beams produce effects similar to those normally associated with GCIB, but to shallower depths, with less surface damage and with superior subsurface interfaces. The paper discusses generation and characterization of the accelerated neutral atom beams, describes interactions of the beams with target surfaces, and presents examples of ongoing work on applications for biomedical devices.

  2. Low-Energy Ions from Laser-Cooled Atoms

    Science.gov (United States)

    Shayeganrad, G.; Fioretti, A.; Guerri, I.; Tantussi, F.; Ciampini, D.; Allegrini, M.; Viteau, M.; Fuso, F.

    2016-05-01

    We report the features of an ion source based on two-color photoionization of a laser-cooled cesium beam outsourced from a pyramidal magneto-optical trap. The ion source operates in continuous or pulsed mode. At acceleration voltages below 300 V, it delivers some ten ions per bunch with a relative energy spread Δ Urms/U ≃0.032 , as measured through the retarding field-energy-analyzer approach. Space-charge effects are negligible thanks to the low ion density attained in the interaction volume. The performances of the ion beam in a configuration using focused laser beams are extrapolated on the basis of the experimental results. Calculations demonstrate that our low-energy and low-current ion beam can be attractive for the development of emerging technologies requiring the delivery of a small amount of charge, down to the single-ion level and its eventual focusing in the 10-nm range.

  3. Electron impact ionization data for atoms and ions. Up-dated in 1998

    Energy Technology Data Exchange (ETDEWEB)

    Tawara, Hiro; Kato, Masa [National Inst. for Fusion Science, Toki, Gifu (Japan)

    1999-02-01

    Ionization cross section data for neutral atoms and (positive and negative) ions have been compiled and shown in a series of figures. The present survey has included those published up to mid-1998. (author)

  4. Spatial decomposition of molecular ions within 3D atom probe reconstructions.

    Science.gov (United States)

    Breen, Andrew; Moody, Michael P; Gault, Baptiste; Ceguerra, Anna V; Xie, Kelvin Y; Du, Sichao; Ringer, Simon P

    2013-09-01

    Two methods for separating the constituent atoms of molecular ions within atom probe tomography reconstructions are presented. The Gaussian Separation Method efficiently deconvolutes molecular ions containing two constituent atoms and is tested on simulated data before being applied to an experimental HSLA steel dataset containing NbN. The Delaunay Separation Method extends separation to larger complex ions and is also tested on simulated data before being applied to an experimental GaAs dataset containing many large (>3 atoms) complex ions. First nearest neighbour (1NN) distributions and images of the reconstruction before and after the separations are used to show the effect of the algorithms and their validity and practicality are also discussed. PMID:23522847

  5. The role of electronic excitation in cold atom-ion chemistry

    OpenAIRE

    Sullivan, Scott T.; Rellergert, Wade G.; Kotochigova, Svetlana; Hudson, Eric R.

    2012-01-01

    The role of electronic excitation in charge exchange chemical reactions between ultracold Ca atoms and Ba$^+$ ions, confined in a hybrid trap, is studied. This prototypical system is energetically precluded from reacting in its ground state, allowing a particularly simple interpretation of the influence of electronic excitation. It is found that while electronic excitation of the ion can critically influence the chemical reaction rate, electronic excitation of the neutral atom is less importa...

  6. Measurements of Scattering Processes in Negative Ion- Atom Collisions

    Energy Technology Data Exchange (ETDEWEB)

    Kvale, T. J.

    2000-12-22

    The main research activity is to study various scattering processes which occur in H{sup -} collisions with atomic (specifically, noble gas and atomic hydrogen) targets in the intermediate energy region. These processes include: elastic scattering, single- and double-electron detachment, and target excitation/ionization.

  7. Radium ion: A possible candidate for measuring atomic parity violation

    CERN Document Server

    Mandal, P; Mukherjee, M

    2009-01-01

    Single trapped and laser cooled Radium ion as a possible candidate for measuring the parity violation induced frequency shift has been discussed here. Even though the technique to be used is similar to that proposed by Fortson [1], Radium has its own advantages and disadvantages. The most attractive part of Radium ion as compared to that of Barium ion is its mass which comes along with added complexity of instability as well as other issues which are discussed here

  8. Spatial decomposition of molecular ions within 3D atom probe reconstructions

    Energy Technology Data Exchange (ETDEWEB)

    Breen, Andrew [School of Aerospace, Mechanical and Mechatronic Engineering, The University of Sydney, NSW 2006 (Australia); Australian Centre for Microscopy and Microanalysis, Madsen Building F09, The University of Sydney, NSW 2006 (Australia); Moody, Michael P. [Department of Materials, University of Oxford, Parks Road, OX13PH, Oxford (United Kingdom); Gault, Baptiste [Department of Materials Science and Engineering, McMaster University, 1280 Main Street West, Hamilton, Ont. L8S4L8 (Canada); Ceguerra, Anna V. [School of Aerospace, Mechanical and Mechatronic Engineering, The University of Sydney, NSW 2006 (Australia); Australian Centre for Microscopy and Microanalysis, Madsen Building F09, The University of Sydney, NSW 2006 (Australia); Xie, Kelvin Y. [Johns Hopkins University, Department of Mechanical Engineering, Baltimore, MD 21218 (United States); Du, Sichao [Australian Centre for Microscopy and Microanalysis, Madsen Building F09, The University of Sydney, NSW 2006 (Australia); School of Physics, The University of Sydney, NSW 2006 (Australia); Ringer, Simon P., E-mail: simon.ringer@sydney.edu.au [School of Aerospace, Mechanical and Mechatronic Engineering, The University of Sydney, NSW 2006 (Australia); Australian Centre for Microscopy and Microanalysis, Madsen Building F09, The University of Sydney, NSW 2006 (Australia)

    2013-09-15

    Two methods for separating the constituent atoms of molecular ions within atom probe tomography reconstructions are presented. The Gaussian Separation Method efficiently deconvolutes molecular ions containing two constituent atoms and is tested on simulated data before being applied to an experimental HSLA steel dataset containing NbN. The Delaunay Separation Method extends separation to larger complex ions and is also tested on simulated data before being applied to an experimental GaAs dataset containing many large (>3 atoms) complex ions. First nearest neighbour (1NN) distributions and images of the reconstruction before and after the separations are used to show the effect of the algorithms and their validity and practicality are also discussed. - Highlights: ► The need to deconvolute molecular ions within atom probe data is discussed. ► Two algorithms to separate the constituent atoms of molecular ions are proposed. ► The algorithms developed are tested on simulated and experimental data. ► Nearest neighbour distributions are used to highlight the improvements.

  9. Spatial decomposition of molecular ions within 3D atom probe reconstructions

    International Nuclear Information System (INIS)

    Two methods for separating the constituent atoms of molecular ions within atom probe tomography reconstructions are presented. The Gaussian Separation Method efficiently deconvolutes molecular ions containing two constituent atoms and is tested on simulated data before being applied to an experimental HSLA steel dataset containing NbN. The Delaunay Separation Method extends separation to larger complex ions and is also tested on simulated data before being applied to an experimental GaAs dataset containing many large (>3 atoms) complex ions. First nearest neighbour (1NN) distributions and images of the reconstruction before and after the separations are used to show the effect of the algorithms and their validity and practicality are also discussed. - Highlights: ► The need to deconvolute molecular ions within atom probe data is discussed. ► Two algorithms to separate the constituent atoms of molecular ions are proposed. ► The algorithms developed are tested on simulated and experimental data. ► Nearest neighbour distributions are used to highlight the improvements

  10. Proceedings of the workshop on opportunities for atomic physics using slow, highly-charged ions

    Energy Technology Data Exchange (ETDEWEB)

    1987-01-01

    The study of atomic physics with highly-charged ions is an area of intense activity at the present time because of a convergence of theoretical interest and advances in experimental techniques. The purpose of the Argonne ''Workshop on Opportunities for Atomic Physics Using Slow, Highly-Charged Ions'' was to bring together atomic, nuclear, and accelerator physicists in order to identify what new facilities would be most useful for the atomic physics community. The program included discussion of existing once-through machines, advanced ion sources, recoil ion techniques, ion traps, and cooler rings. One of the topics of the Workshop was to discuss possible improvement to the ANL Tandem-Linac facility (ATLAS) to enhance the capability for slowing down ions after they are stripped to a high-charge state (the Accel/Decel technique). Another topic was the opportunity for atomic physics provided by the ECR ion source which is being built for the Uranium Upgrade of ATLAS. 18 analytics were prepared for the individual papers in this volume.

  11. Database for inelastic collisions of lithium atoms with electrons, protons, and multiply charged ions

    NARCIS (Netherlands)

    Schweinzer, J; Brandenburg, R; Bray, [No Value; Hoekstra, R; Aumayr, F; Janev, RK; Winter, HP

    1999-01-01

    New experimental and theoretical cross-section data for inelastic collision processes of Li atoms in the ground state and excited states (up to n = 4) with electrons, protons, and multiply charged ions have been reported since the database assembled by Wutte et al. [ATOMIC DATA AND NUCLEAR DATA TABL

  12. Theoretical Calculation of Absolute Radii of Atoms and Ions. Part 1. The Atomic Radii

    Directory of Open Access Journals (Sweden)

    Raka Biswas

    2002-02-01

    Full Text Available Abstract. A set of theoretical atomic radii corresponding to the principal maximum in the radial distribution function, 4πr2R2 for the outermost orbital has been calculated for the ground state of 103 elements of the periodic table using Slater orbitals. The set of theoretical radii are found to reproduce the periodic law and the Lother Meyer’s atomic volume curve and reproduce the expected vertical and horizontal trend of variation in atomic size in the periodic table. The d-block and f-block contractions are distinct in the calculated sizes. The computed sizes qualitatively correlate with the absolute size dependent properties like ionization potentials and electronegativity of elements. The radii are used to calculate a number of size dependent periodic physical properties of isolated atoms viz., the diamagnetic part of the atomic susceptibility, atomic polarizability and the chemical hardness. The calculated global hardness and atomic polarizability of a number of atoms are found to be close to the available experimental values and the profiles of the physical properties computed in terms of the theoretical atomic radii exhibit their inherent periodicity. A simple method of computing the absolute size of atoms has been explored and a large body of known material has been brought together to reveal how many different properties correlate with atomic size.

  13. Complex decay patterns in atomic core photoionization disentangled by ion-recoil measurements

    Energy Technology Data Exchange (ETDEWEB)

    Guillemin, Renaud; Bomme, Cedric; Marin, Thierry; Journel, Loic; Marchenko, Tatiana; Kushawaha, Rajesh K.; Piancastelli, Maria Novella; Simon, Marc [Universite Pierre et Marie Curie, Universite Paris 06, Laboratoire de Chimie Physique Matiere et Rayonement, 11 rue Pierre et Marie Curie, FR-75231 Paris Cedex 05 (France); Centre National de la Recherche Scientifique, Laboratoire de Chimie Physique Matiere et Rayonement (UMR7614), 11 rue Pierre et Marie Curie, FR-75231 Paris Cedex 05 (France); Trcera, Nicolas [Synchrotron SOLEIL, l' Orme des Merisiers, Saint-Aubin, BP 48, FR-91192 Gif-sur-Yvette Cedex (France)

    2011-12-15

    Following core 1s ionization and resonant excitation of argon atoms, we measure the recoil energy of the ions due to momentum conservation during the emission of Auger electrons. We show that such ion momentum spectroscopy can be used to disentangle to some degree complex decay patterns, involving both radiative and nonradiative decays.

  14. Calculation Of Change-Changing Cross Sections Of IONS Or Atoms Colliding With Fast IONS Using The Classical Trajectory Method

    Energy Technology Data Exchange (ETDEWEB)

    Kaganovich, I. D., Shnidman, Ariel, Mebane, Harrison, Davidson, R.C.

    2008-10-10

    Evaluation of ion-atom charge-changing cross sections is needed for many accelerator applications. A classical trajectory Monte Carlo (CTMC) simulation has been used to calculate ionization and charge exchange cross sections. For benchmarking purposes, an extensive study has been performed for the simple case of hydrogen and helium targets in collisions with various ions. Despite the fact that the simulation only accounts for classical mechanics, the calculations are comparable to experimental results for projectile velocities in the region corresponding to the vicinity of the maximum cross section. Shortcomings of the CTMC method for multielectron target atoms are discussed.

  15. Calculation Of Change-Changing Cross Sections Of IONS Or Atoms Colliding With Fast IONS Using The Classical Trajectory Method

    International Nuclear Information System (INIS)

    Evaluation of ion-atom charge-changing cross sections is needed for many accelerator applications. A classical trajectory Monte Carlo (CTMC) simulation has been used to calculate ionization and charge exchange cross sections. For benchmarking purposes, an extensive study has been performed for the simple case of hydrogen and helium targets in collisions with various ions. Despite the fact that the simulation only accounts for classical mechanics, the calculations are comparable to experimental results for projectile velocities in the region corresponding to the vicinity of the maximum cross section. Shortcomings of the CTMC method for multielectron target atoms are discussed

  16. Atom capture and loss in ion molecule collisions

    International Nuclear Information System (INIS)

    Progress is reported in measuring the energy and angular distribution of protons emerging with velocity close to the beam velocity from the target region when Ar+ beams collide with a CH4 target and ArH+ beams collide with a He target at asymptotically high speeds. The protons result from the transfer of a target constituent to the projectile (atom capture) or from the dissociation of the projectile molecule in the collision (atom loss). For atom capture processes the Thomas peak is clearly observed. 10 refs., 3 figs

  17. Projectile X-ray emission in relativistic ion-atom collisions

    OpenAIRE

    Salem, Shadi

    2010-01-01

    This work reports on the study of the projectile x-ray emission in relativistic ion-atom collisions. Excitation of K-shell in He-like uranium ions, electron capture into H-like uranium ions and Simultaneous ionization and excitation of initially He-like uranium ions have been studied using the experimental storage ring at GSI. Information about the population of the excited states for the H- and He-like uranium ions, can be obtained by measuring the angular distribution of the decay radiation...

  18. Excitation of atoms and molecules in collisions with fast, highly charged ions

    International Nuclear Information System (INIS)

    This paper discusses the following topics: charge distributions for Ar recoil-ions produced in one- and two-electron capture collisions by Oq+ projectiles; charge distributions of He, Ne, and Ar recoil-ions produced in collisions with 10 to 30 MeV/u N7+ ions; studies of recoil ions produced in collisions of 40 MeV Ar13+ with atomic and molecular targets; two-fragment coincidence studies of molecular dissociation induced by heavy ion collisions; resonant electron transfer to double K-vacancy states in oxygen compounds; quenching of metastable states in fast Mg projectiles; and design and construction of an atomic physics beamline for the ECR ion source

  19. PREFACE: Heavy-Ion Spectroscopy and QED Effects in Atomic Systems

    Science.gov (United States)

    Lindgren, Ingvar; Martinson, Indrek; Schuch, Reinhold

    1993-01-01

    Experimental studies of heavy and highly charged ions have made remarkable progress in recent years. Today it is possible to produce virtually any ion up to hydrogen-like uranium; to study collisions of those ions with atoms, electrons, and solid surfaces; to excite such an ion and accurately measure the radiation emitted. This progress is largely due to the development of new experimental methods, for instance, the high-energy ion accelerators, laser-produced plasmas, advanced ion sources and ion traps (such as EBIS, EBIT, ECR, etc.), high temperature magnetically confined plasmas and heavy-ion storage rings. The motivations for studies of collisions with highly charged ions and for the understanding of the structure of heavy atomic systems are multi-faceted. Besides of the basic scientific aspects which are mainly the subject of this symposium, much incentive is experienced by applications, e.g., the interpretation of spectra from space (solar corona, solar flares and hot stars), the modelling of stellar atmospheres, the diagnostics of fusion plasma impurities, and the development of X-ray lasers. Since quite some time highly charged ions play a key role for high-precision metrology of atomic structure. These studies have been benchmarks for tests of advanced theories, including many-body theories of interelectronic correlations, relativistic and quantum-electrodynamic (QED) effects, effects due to the finite size of the nucleus and to parity non-conservation (PNC). The interest in QED effects in heavy ions has increased drastically in the last few years. The remarkable experiment on Li-like uranium, recently reported from Berkeley, has stimulated several groups to perform very accurate Lamb-shift calculations on such systems, and reports from three groups were given about such work. The agreement between the calculations as well as with experiment was generally very good, which implies that the problem of evaluating the first-order Lamb shift for any element is

  20. Proceedings of the workshop on atomic physics with fast heavy-ion beams

    International Nuclear Information System (INIS)

    The Workshop on Atomic Physics with Fast Heavy-Ion Beams was held in the Physics Division, Argonne National Laboratory on January 20 and 21, 1983. The meeting brought together approx. 50 practitioners in the field of accelerator-based atomic physics. The workshop was held to focus attention on possible areas of atomic physics research which would benefit from use of the newest generation of accelerators designed to produce intense high-quality beams of fast heavy ions. Abstracts of individual paper were prepared separately for the data base

  1. The fine structure of niobium condensates deposited from ion-atomic fluxes in helium atmosphere

    International Nuclear Information System (INIS)

    Helium gas influence on the structural characteristics of niobium coatings deposited by low-energy metallic Nb ion-stoic fluxes in He atmosphere is investigated. It is shown that He implantation in Nb films during condensation is accompanied with the decreasing of the mean size of condensate grains. At the same time, He atoms modify no physical processes of the fine structure formation. Using thermodesorption spectroscopy we have determined that He atoms mainly belong to vacancy/vacancy-solute complexes in Nb coatings. Our conclusion is that such complexes play a dominant role in formation of the fine structure of vacuum coatings deposited from ion-atomic fluxes

  2. Atom probe field ion microscopy and related topics: A bibliography 1989

    Energy Technology Data Exchange (ETDEWEB)

    Miller, M.K.; Hawkins, A.R.; Russell, K.F.

    1990-12-01

    This bibliography includes references related to the following topics: atom probe field ion microscopy (APFIM), field ion spectroscopy (FIM), field emission microscopy (FEM), liquid metal ion sources (LMIS), scanning tunneling microscopy (STM), and theory. Technique-orientated studies and applications are included. This bibliography covers the period 1989. The references contained in this document were compiled from a variety of sources including computer searches and personal lists of publications.

  3. Atom probe field-ion microscopy and related topics: A bibliography, 1988

    Energy Technology Data Exchange (ETDEWEB)

    Miller, M.K.; Hawkins, A.R.

    1989-10-01

    This bibliography includes references related to the following topics: field-ion microscopy (FIM), field emission microscopy (FEM), atom probe field-ion microscopy (APFIM), and liquid metal ion sources (LMIS). Technique-orientated studies and applications are included. The references contained in this document were compiled from a variety of sources including computer searches and personal lists of publications. To reduce the length of this document, the references have been reduced to the minimum necessary to locate the articles.

  4. Simulation of Collisions of Ions with Atoms by the PIC-MC Method. Comparative Estimates

    Science.gov (United States)

    Sysun, V. I.; Sysun, A. V.; Ignakhin, V. S.; Titov, V. O.

    2015-11-01

    Monte Carlo models which simulate ion-atom collisions are considered. Efficient models for calculating the time between collisions are proposed which take into account the velocity dependence of the cross sections and also the probability distribution of the velocities of the ions and the probability distribution of the angles after a collision. The simulation results are compared with theoretical values of the drift velocity of the ions.

  5. Atom probe field-ion microscopy and related topics: A bibliography, 1988

    International Nuclear Information System (INIS)

    This bibliography includes references related to the following topics: field-ion microscopy (FIM), field emission microscopy (FEM), atom probe field-ion microscopy (APFIM), and liquid metal ion sources (LMIS). Technique-orientated studies and applications are included. The references contained in this document were compiled from a variety of sources including computer searches and personal lists of publications. To reduce the length of this document, the references have been reduced to the minimum necessary to locate the articles

  6. Total Born-approximation cross sections for single-electron loss by atoms and ions colliding with atoms

    Science.gov (United States)

    Rule, D. W.

    1977-01-01

    The first Born approximation (FBA) is applied to the calculation of single-electron-loss cross sections for various ions and atoms containing from one to seven electrons. Screened hydrogenic wave functions are used for the states of the electron ejected from the projectile, and Hartree-Fock elastic and incoherent scattering factors are used to describe the target. The effect of the target atom on the scaling of projectile ionization cross sections with respect to the projectile nuclear charge is explored in the case of hydrogenlike ions. Also examined is the scaling of the cross section with respect to the target nuclear charge for electron loss by Fe(25+) in collision with neutral atoms ranging from H to Fe. These results are compared with those of the binary-encounter approximation (BEA) and with the FBA for the case of ionization by completely stripped target ions. Electron-loss cross sections are also calculated for the ions O(i+) (i = 3-7) and N(i+) (i = 0-6) in collision with He targets in the energy range of approximately 0.1 to 100 MeV/nucleon. These results are found to be in excellent agreement with the available data near the peak of the ionization cross section.

  7. Recrystallization and reactivation of dopant atoms in ion-implanted silicon nanowires.

    Science.gov (United States)

    Fukata, Naoki; Takiguchi, Ryo; Ishida, Shinya; Yokono, Shigeki; Hishita, Shunichi; Murakami, Kouichi

    2012-04-24

    Recrystallization of silicon nanowires (SiNWs) after ion implantation strongly depends on the ion doses and species. Full amorphization by high-dose implantation induces polycrystal structures in SiNWs even after high-temperature annealing, with this tendency more pronounced for heavy ions. Hot-implantation techniques dramatically suppress polycrystallization in SiNWs, resulting in reversion to the original single-crystal structures and consequently high reactivation rate of dopant atoms. In this study, the chemical bonding states and electrical activities of implanted boron and phosphorus atoms were evaluated by Raman scattering and electron spin resonance, demonstrating the formation of p- and n-type SiNWs.

  8. Dynamics of a ground-state cooled ion colliding with ultra-cold atoms

    OpenAIRE

    Meir, Ziv; Sikorsky, Tomas; Ben-shlomi, Ruti; Akerman, Nitzan; Dallal, Yehonatan; Ozeri, Roee

    2016-01-01

    Ultra-cold atom-ion mixtures are gaining increasing interest due to their potential applications in quantum chemistry, quantum computing and many-body physics. Here, we studied the dynamics of a single ground-state cooled ion during few, to many, Langevin (spiraling) collisions with ultra-cold atoms. We measured the ion's energy distribution and observed a clear deviation from Maxwell-Boltzmann to a Tsallis characterized by a power-law tail of high energies. Unlike previous experiments, the e...

  9. Correlated ion analysis and the interpretation of atom probe mass spectra

    International Nuclear Information System (INIS)

    Several techniques are presented for extracting information from atom probe mass spectra by investigating correlations within multiple-ion detector events. Analyses of this kind can provide insights into the origins of noise, the shape of mass peaks, or unexpected anomalies within the spectrum. Data can often be recovered from within the spectrum noise by considering the time-of-flight differences between ions within a multiple event. Correlated ion detection, particularly when associated with shifts in ion energies, may be used to probe the phenomenon of molecular ion dissociation, including the questions of data loss due to ion pile-up or the generation of neutrals in the dissociation process. -- Research Highlights: → Multiple-ion detection events may contain information not seen in the mass spectrum. → Analysis of multiple events can yield information on molecular ion dissociation. → Neutral species may be generated by dissociation subsequent to field evaporation.

  10. New source of MeV negative ion and neutral atom beams

    Energy Technology Data Exchange (ETDEWEB)

    Ter-Avetisyan, S., E-mail: sargis@gist.ac.kr [Center for Relativistic Laser Science, Institute for Basic Science (IBS), Gwangju 500-712 (Korea, Republic of); Department of Physics and Photon Science, GIST, Gwangju 500-712 (Korea, Republic of); Braenzel, J.; Schnürer, M. [Max Born Institute for Nonlinear Optics and Short Pulse Spectroscopy, Berlin 12489 (Germany); Prasad, R. [Institute for Laser and Plasma Physics, Heinrich Heine University, Duesseldorf 40225 (Germany); Borghesi, M. [School of Mathematics and Physics, The Queen’s University of Belfast, Belfast BT7-1NN (United Kingdom); Jequier, S.; Tikhonchuk, V. [Centre Lasers Intenses et Applications, CEA, CNRS, University of Bordeaux, 33405 Talence (France)

    2016-02-15

    The scenario of “electron-capture and -loss” was recently proposed for the formation of negative ion and neutral atom beams with MeV kinetic energies. However, it does not explain why the formation of negative ions in a liquid spray is much more efficient than with an isolated atom. The role of atomic excited states in the charge-exchange processes is considered, and it is shown that it cannot account for the observed phenomena. The processes are more complex than the single electron-capture and -loss approach. It is suggested that the shell effects in the electronic structure of the projectile ion and/or target atoms may influence the capture/loss probabilities.

  11. Atomic Physics Effects on Convergent, Child-Langmuir Ion Flow between Nearly Transparent Electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Santarius, John F. [University of Wisconsin-Madison; Emmert, Gilbert A. [University of Wisconsin-Madison

    2013-11-07

    Research during this project at the University of Wisconsin Fusion Technology Institute (UW FTI) on ion and neutral flow through an arbitrary, monotonic potential difference created by nearly transparent electrodes accomplished the following: (1) developed and implemented an integral equation approach for atomic physics effects in helium plasmas; (2) extended the analysis to coupled integral equations that treat atomic and molecular deuterium ions and neutrals; (3) implemented the key deuterium and helium atomic and molecular cross sections; (4) added negative ion production and related cross sections; and (5) benchmarked the code against experimental results. The analysis and codes treat the species D0, D20, D+, D2+, D3+, D and, separately at present, He0 and He+. Extensions enhanced the analysis and related computer codes to include He++ ions plus planar and cylindrical geometries.

  12. Determination of Optimum Conditions for Distinguishing the Pulse Height Distributions of Atomic and Polyatomic Ions

    Energy Technology Data Exchange (ETDEWEB)

    Kristo, M J

    2006-12-12

    This work explored the use of pulse height distributions (PHD) from multiplier-type detectors as a means of detecting and eliminating the effects of polyatomic interferences in secondary ion mass spectrometry (SIMS). We explored the behavior of PHD for {sup 235}U{sup +}, {sup 208}Pb{sup 27}Al{sup +} and {sup 207}Pb{sup 28}Si{sup +}, all with a nominal mass-to-charge ratio of 235. In every case, the distribution for the atomic ion ({sup 235}U{sup +}) was clearly shifted relative to the distributions for {sup 208}Pb{sup 27}Al{sup +} and {sup 207}Pb{sup 28}Si{sup +}. When the first surface of the detector is metallic in character, the polyatomic ions are shifted to larger pulse heights relative to the atomic ion. When the first surface of the detector is oxide in character, the atomic ion is shifted to larger pulse heights relative to the polyatomic ions. The relative positioning appear to be stable for a given detector over time at the same secondary ion impact energy. Consequently, it appears to be feasible to use PHD data to detect interfering polyatomic ions and eliminate their deleterious effects using peak deconvolution techniques. Consequently, the updated Ultrafast RAE detector will be designed to make the pulse height information available to the data acquisition system.

  13. Investigation of ion-atom collision dynamics through imaging techniques

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The principle and technique details of recoil ion momentum imaging are discussed and summarized. The recoil ion momentum spectroscopy built at the Institute of Modern Physics (Lanzhou) is presented. The first results obtained at the setup are analyzed. For 30 keV He2+ on He collision, it is found that the capture of single electron occurs dominantly into the first excited states, and the related scattering angle results show that the ground state capture occurs at large impact parameters, while the capture into excited states occurs at small impact parameters. The results manifest the collision dynamics for the sub-femto-second process can be studied through the techniques uniquely. Finally, the future possibilities of applications of the recoil ion momentum spectroscopy in other fields are outlined.

  14. Atomic-scale thermocapillary flow in focused ion beam milling

    Energy Technology Data Exchange (ETDEWEB)

    Das, K.; Johnson, H. T.; Freund, J. B., E-mail: jbfreund@illinois.edu [Mechanical Science and Engineering and Aerospace Engineering, University of Illinois at Urbana–Champaign, 1206 West Green Street MC-244, Urbana, Illinois 61801 (United States)

    2015-05-15

    Focused ion beams provide a means of nanometer-scale manufacturing and material processing, which is used for applications such as forming nanometer-scale pores in thin films for DNA sequencing. We investigate such a configuration with Ga{sup +} bombardment of a Si thin-film target using molecular dynamics simulation. For a range of ion intensities in a realistic configuration, a recirculating melt region develops, which is seen to flow with a symmetrical pattern, counter to how it would flow were it driven by the ion momentum flux. Such flow is potentially important for the shape and composition of the formed structures. Relevant stress scales and estimated physical properties of silicon under these extreme conditions support the importance thermocapillary effects. A flow model with Marangoni forcing, based upon the temperature gradient and geometry from the atomistic simulation, indeed reproduces the flow and thus could be used to anticipate such flows and their influence in applications.

  15. Dynamics of a ground-state cooled ion colliding with ultra-cold atoms

    CERN Document Server

    Meir, Ziv; Ben-shlomi, Ruti; Akerman, Nitzan; Dallal, Yehonatan; Ozeri, Roee

    2016-01-01

    Ultra-cold atom-ion mixtures are gaining increasing interest due to their potential applications in quantum chemistry, quantum computing and many-body physics. The polarization potential between atoms and ions scales as 1/r^4 and extends to 100's of nm. This long length-scale interaction can form macroscopic objects while exhibiting quantum features such as Feshbach and shape resonances at sufficiently low temperatures. So far, reaching the quantum regime of atom-ion interaction has been impeded by the ion's excess micromotion (EMM) which sets a scale for the steady-state energy. In this work, we studied the dynamics of a ground-state cooled ion with negligible EMM during few, to many, Langevin (spiraling) collisions with ultra-cold atoms. We measured the energy distribution of the ion using both coherent (Rabi) and non-coherent (photon scattering) spectroscopy. We observed a clear deviation from a Maxwell-Boltzmann thermal distribution to a Tsallis energy distribution characterized by a power-law tail of hig...

  16. Energetic neutral atoms emitted from ice by ion bombardment under Ganymede surface conditions

    Science.gov (United States)

    Wieser, Martin; Barabash, Stas; Futaana, Yoshifumi; Wurz, Peter

    2013-04-01

    Magnetospheric or solar wind ions directly interacting with a planetary surface result in backscattering or sputtering of energetic neutral atoms. One example is the solar wind interaction with the surface of the Moon, where the produced energetic neutral atoms were observed by the Sub-keV Atom Reflecting Analyzer instrument (SARA) on Chandrayaan-1. At Jupiter, magnetospheric plasma interacts in a similar way with the surface of the Galilean moons. However, the emission of energetic neutral atoms from "dirty" ices as found e.g. on Ganymede's surface is poorly understood. We set up an experiment to study the ion to surface interaction under Ganymede surface environment conditions using the unique capabilities of the MEFISTO test facility at University of Bern. Ions of various species and energies up to 33 keV/q were impacted on a block of ice made from a mixture of water, NaCl and dry ice. The energetic neutral atoms produced by the interaction were detected with the prototype of the Jovian Neutrals Analyzer instrument (JNA.) JNA is proposed as part of the Particle Environment Package (PEP) for ESA's JUICE mission to Jupiter and instrument is based on the Energetic Energetic Neutral Atom instrument (ENA) built for the BepiColombo Magnetospheric Orbiter. We present energy spectra for different ion beam species and energetic neutral atom species combinations. The data show high yields for energetic neutral atoms up to the upper end of the instrument energy range of 3.3 keV. The energy spectra of the neutral atom flux emitted from the ice could only partially be fitted by the Sigmund-Thompson formula. In some cases, but not all, a Maxwellian distribution provides a reasonable description of the data.

  17. Coherence effects in heavy ion-atom collisions

    International Nuclear Information System (INIS)

    A new approach to charge capture and ionization by highly stripped projectiles is described and shown to explain cross section systematics through the periodic table. Oscillations in cross section with respect to charge state observed around atomic number 70 are explained as an f-wave resonance in the target electron-projectile scattering. The ratio of H2 to H cross sections for both light and heavy projectiles is shown to fit a two center coherent scattering model; independent scattering by the two centers is not a good assumption for velocities below 4 a.u. Similar coherence effects are predicted in stripping by molecular gases even in multi-electron processes where the independent atom model might be thought valid. Recent experiments on the forward peak of electrons ejected from the projectile show interesting structure which can be partly explained without invoking interference effects. 7 references

  18. Electron quantum dynamics in atom-ion interaction

    Science.gov (United States)

    Sabzyan, H.; Jenabi, M. J.

    2016-04-01

    Electron transfer (ET) process and its dependence on the system parameters are investigated by solving two-dimensional time-dependent Schrödinger equation numerically using split operator technique. Evolution of the electron wavepacket occurs from the one-electron species hydrogen atom to another bare nucleus of charge Z > 1. This evolution is quantified by partitioning the simulation box and defining regional densities belonging to the two nuclei of the system. It is found that the functional form of the time-variations of these regional densities and the extent of ET process depend strongly on the inter-nuclear distance and relative values of the nuclear charges, which define the potential energy surface governing the electron wavepacket evolution. Also, the initial electronic state of the single-electron atom has critical effect on this evolution and its consequent (partial) electron transfer depending on its spreading extent and orientation with respect to the inter-nuclear axis.

  19. Influence and determinative factors of ion-to-atom arrival ratio in unbalanced magnetron sputtering systems

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Low pressure sputtering with a controlled ratio of ion flux to deposited atom flux at the condensing surface is one of the main directions of development of magnetron sputtering methods.Unbalanced magnetron sputtering,by producing dense secondary plasma around the substrate,provides a high ion current density.The closed-field unbalanced magnetron sputtering system (CFUBMS) has been established as a versatile technique for high-rate deposition high-quality metal,alloy,and ceramic thin films.The key factor in the CFUBMS system is the ability to transport high ion currents to the substrate,which can enhance the formation of full dense coatings at relatively low value homologous temperature.The investigation shows that the energy of ions incidenced at the substrate and the ratio of the flux of these ions to the flux of condensing atoms are the fundamental parameters in determining the structure and properties of films produced by ion-assisted deposition processes.Increasing ion bombardment during deposition combined with increasing mobility of the condensing atoms favors the formation of a dense microstructure and a smooth surface.

  20. Lattice sites of ion-implanted Cu atoms in diamond

    International Nuclear Information System (INIS)

    Radioactive 67Cu atoms were accelerated to 60 keV at the online isotope separator ISOLDE at CERN, and implanted into a type IIa natural diamond sample to a dose of 2x1012 cm-2. The channeling of β--particles and conversion electrons emitted in the decay of 67Cu and 67Zn*, respectively, were monitored about the three major axial directions with a two-dimensional position-sensitive detector. The electron emission channeling data were collected from the room-temperature-implanted sample and after annealing at 1200 K. The observed channeling patterns were fitted with simulations based on the many beam formalism of electron motion through a crystal lattice. In the as-implanted sample, 25% of the Cu atoms were located a mean, isotropic displacement of 0.25(5) A from substitutional sites, and the remainder, fR=75%, at sites that gave an isotropic emission yield. Annealing at 1200 K results in enhanced axial and planar channeling effects. The fits to the data yield either a fraction f1=45(5)% of Cu atoms located 0.24(4) A from substitutional sites and fR=57%, or a fraction f1=10(2)% at substitutional sites, a fraction f2=50(5)% at mean isotropic displacement of 0.5 A from substitutional sites, and a 'random' fraction fR=40%

  1. Preparation and Analysis of Atom Probe Tips by Xenon Focused Ion Beam Milling.

    Science.gov (United States)

    Estivill, Robert; Audoit, Guillaume; Barnes, Jean-Paul; Grenier, Adeline; Blavette, Didier

    2016-06-01

    The damage and ion distribution induced in Si by an inductively coupled plasma Xe focused ion beam was investigated by atom probe tomography. By using predefined patterns it was possible to prepare the atom probe tips with a sub 50 nm end radius in the ion beam microscope. The atom probe reconstruction shows good agreement with simulated implantation profiles and interplanar distances extracted from spatial distribution maps. The elemental profiles of O and C indicate co-implantation during the milling process. The presence of small disc-shaped Xe clusters are also found in the three-dimensional reconstruction. These are attributed to the presence of Xe nanocrystals or bubbles that open during the evaporation process. The expected accumulated dose points to a loss of >95% of the Xe during analysis, which escapes undetected.

  2. Multiple electron capture in close ion-atom collisions

    International Nuclear Information System (INIS)

    Multiple electron capture is reported for Ca17+ in Ar. Close collisions are defined by the observation of a coincident Ca K or Ar K x-ray. A large number of electrons is transferred to the projectile in a single close collision when the Ca ion projectile is of the order of the Ar L-shell electron velocity. The cross section for electron capture is reported

  3. Observation of multistep Coulomb excitation during ion-atom collisions

    International Nuclear Information System (INIS)

    Well below the Coulomb barrier energies two colliding nuclei may share the energy via electromagnetic interactions and it can lead to excite the nuclear states of one or both the participating nuclei. This long range Coulombic interaction leading to nuclear excitation is called Coulomb excitation. In the present work, we have studied heavy ion induced Coulomb excitation process in 12C nuclei at the sub-Coulomb barrier energies using x-ray spectroscopy technique in combination with the nuclear techniques.

  4. Overview on collision processes of highly charged ions with atoms present status and problems

    International Nuclear Information System (INIS)

    This paper provides a brief discussion on the present status of the collision physics of highly charged ions with atoms. The emphasis is on the main achievements in understanding and describing the most important collision processes, and as charge transfer, ionization and Auger-type processes, and even more on those open problems which, due either to their scientific or practical importance, represent challenges to current research in this field. The paper concentrates on general ideas and problems whose development and solutions have advanced or will advance our basic understanding of the collision dynamics of multiply charged ions with atoms

  5. Stimulated Raman Adiabatic Passage for Improved Performance of a Cold Atom Electron and Ion Source

    CERN Document Server

    Sparkes, B M; Taylor, R J; Spiers, R W; McCulloch, A J; Scholten, R E

    2016-01-01

    We experimentally implement high-efficiency coherent excitation to a Rydberg state using stimulated Raman adiabatic passage in a cold atom electron and ion source, leading to a peak efficiency of 85%, a 1.7 times improvement in excitation probability relative to incoherent pulsed-laser excitation. Using streak measurements and pulsed electric field ionization of the Rydberg atoms we demonstrate electron bunches with duration of 250 ps. High-efficiency excitation will increase source brightness, crucial for ultrafast electron diffraction experiments, while using coherent excitation to high-lying Rydberg states could allow for the reduction of internal bunch heating and the creation of a high-speed single ion source.

  6. Atomic physics with highly-charged ions at the future FAIR facility: A status report

    Energy Technology Data Exchange (ETDEWEB)

    Stoehlker, Th. [Gesellschaft fuer Schwerionenforschung (GSI), Darmstadt (Germany) and Institut fuer Kernphysik, University of Frankfurt (Germany)]. E-mail: t.stoehlker@gsi.de; Beyer, H.F. [Gesellschaft fuer Schwerionenforschung (GSI), Darmstadt (Germany); Braeuning, H. [Gesellschaft fuer Schwerionenforschung (GSI), Darmstadt (Germany); Braeuning-Demian, A. [Gesellschaft fuer Schwerionenforschung (GSI), Darmstadt (Germany); Brandau, C. [Gesellschaft fuer Schwerionenforschung (GSI), Darmstadt (Germany); Hagmann, S. [Institut fuer Kernphysik, University of Frankfurt (Germany); Kozhuharov, C. [Gesellschaft fuer Schwerionenforschung (GSI), Darmstadt (Germany); Kluge, H.J. [Gesellschaft fuer Schwerionenforschung (GSI), Darmstadt (Germany); Kuehl, Th. [Gesellschaft fuer Schwerionenforschung (GSI), Darmstadt (Germany); Liesen, D. [Gesellschaft fuer Schwerionenforschung (GSI), Darmstadt (Germany); Mann, R. [Gesellschaft fuer Schwerionenforschung (GSI), Darmstadt (Germany); Noertershaeuser, W. [Gesellschaft fuer Schwerionenforschung (GSI), Darmstadt (Germany); Quint, W. [Gesellschaft fuer Schwerionenforschung (GSI), Darmstadt (Germany); Schramm, U. [LMU, Munich (Germany); Schuch, R. [Stockholm University, Stockholm (Sweden)

    2007-08-15

    Key features of the future international accelerator Facility for Antiproton and Ion Research (FAIR) offer a range of new and challenging opportunities for atomic physics research in the realm of highly-charged heavy ions and exotic nuclei. Centred on use of FAIR, the Stored Particle Atomic Physics Research Collaboration (SPARC), organized in working groups, has been formed. A short report on the tasks and activities of the various SPARC working groups, devoted to the realization of experimental equipments and set-ups required to reach the physics goals is given.

  7. Atomic physics with highly-charged ions at the future FAIR facility. A status report

    Energy Technology Data Exchange (ETDEWEB)

    Stoehlker, T. [Gesellschaft fuer Schwerionenforschung, Darmstadt (Germany)]|[Frankfurt Univ. (Germany). Inst. fuer Kernphysik; Beyer, H.F.; Braeuning, H. [Gesellschaft fuer Schwerionenforschung, Darmstadt (DE)] (and others)

    2006-11-15

    The key features of the future international accelerator Facility for Antiproton and Ion Research (FAIR) offer a range of new and challenging opportunities for atomic physics research in the realm of highly-charged heavy ions and exotic nuclei. Centred on use of FAIR, the Stored Particle Atomic Physics Research Collaboration (SPARC), organized in working groups, has been formed. A short report on the tasks and activities of the various SPARC working groups, devoted to the realization of experimental equipments and setups required to reach the physics goals is given. (orig.)

  8. Formation of heavy-Rydberg ion-pair states in Rydberg atom collisions with attaching targets

    Science.gov (United States)

    Wang, Changhao; Kelley, Michael; Buathong, Sitti; Dunning, F. Barry

    2014-05-01

    Electron transfer in collisions between K(np)Rydberg atoms and electron attaching molecules can lead to formation of heavy-Rydberg ion-pair states comprising a weakly-bound positive-negative ion pair orbiting at large internuclear separations. In the present work ion-pair states are created in a small collision cell and allowed to exit into an analysis region where their binding energy and velocity distributions are determined with the aid of electric-field-induced dissociation and a position sensitive detector. Ion pair production is analyzed using a Monte Carlo collision code that models both the initial Rydberg electron capture and the subsequent behavior of the product ion pair. The data demonstrate that collisions with SF6 and CCl4 lead to formation of long-lived ion pair states with a broad distribution of binding energies whose velocity distribution is strongly peaked in the forward direction. Research supported by the Robert A. Welch Foundation.

  9. Observation of the continuous stern-gerlach effect on an electron bound in an atomic Ion

    Science.gov (United States)

    Hermanspahn; Haffner; Kluge; Quint; Stahl; Verdu; Werth

    2000-01-17

    We report on the first observation of the continuous Stern-Gerlach effect on an electron bound in an atomic ion. The measurement was performed on a single hydrogenlike ion ( 12C5+) in a Penning trap. The measured g factor of the bound electron, g = 2.001 042(2), is in excellent agreement with the theoretical value, confirming the relativistic correction at a level of 0.1%. This proves the possibility of g-factor determinations on atomic ions to high precision by using the continuous Stern-Gerlach effect. The result demonstrates the feasibility of conducting experiments on single heavy highly charged ions to test quantum electrodynamics in the strong electric field of the nucleus.

  10. Observation of the continuous stern-gerlach effect on an electron bound in an atomic Ion

    Science.gov (United States)

    Hermanspahn; Haffner; Kluge; Quint; Stahl; Verdu; Werth

    2000-01-17

    We report on the first observation of the continuous Stern-Gerlach effect on an electron bound in an atomic ion. The measurement was performed on a single hydrogenlike ion ( 12C5+) in a Penning trap. The measured g factor of the bound electron, g = 2.001 042(2), is in excellent agreement with the theoretical value, confirming the relativistic correction at a level of 0.1%. This proves the possibility of g-factor determinations on atomic ions to high precision by using the continuous Stern-Gerlach effect. The result demonstrates the feasibility of conducting experiments on single heavy highly charged ions to test quantum electrodynamics in the strong electric field of the nucleus. PMID:11015930

  11. The Spectr-W3 database on the spectroscopic properties of atoms and ions

    Science.gov (United States)

    Skobelev, I. Yu.; Loboda, P. A.; Gagarin, S. V.; Ivliev, S. V.; Kozlov, A. I.; Morozov, S. V.; Pikuz, S. A.; Pikuz, T. A.; Popova, V. V.; Faenov, A. Ya.

    2016-04-01

    The Spectr-W3 database was developed in 2001-2013 and is available online (http://spectrw3. snz.ru). The database contains information on various spectroscopic constants of atoms and ions such as the wavelengths and probabilities of radiative transitions, energy levels of atoms and ions, ionization potentials, autoionization rates, and the parameters of analytical approximation of cross sections and rates of collisional transitions in atoms and ions. Spectr-W3 presently contains around 450 thousand records and is the world's largest factual database on spectral properties of multicharged ions. A new stage of development of Spectr-W3, which involves adding a new section titled "Emission Spectrograms" to the database, commenced in 2014. In contrast to the already existing sections that contain tabulated data, this new section provides graphical data (with necessary explanatory notes) on the spectrograms of emission of atoms and ions excited in various plasma sources. The structure of sections of the Spectr-W3 database is characterized, and examples of queries and the corresponding search results are given.

  12. Scaling and Formulary cross sections for ion-atom impact ionization

    OpenAIRE

    Kaganovich, Igor D.; Startsev, Edward; Davidson, Ronald C.

    2004-01-01

    The values of ion-atom ionization cross sections are frequently needed for many applications that utilize the propagation of fast ions through matter. When experimental data and theoretical calculations are not available, approximate formulas are frequently used. This paper briefly summarizes the most important theoretical results and approaches to cross section calculations in order to place the discussion in historical perspective and offer a concise introduction to the topic. Based on expe...

  13. Ion heating during geomagnetic storms measured using energetic neutral atom imaging

    Science.gov (United States)

    Keesee, Amy; Elfritz, Justin; Katus, Roxanne; Scime, Earl

    2015-11-01

    Energy from the solar wind is deposited into the magnetosphere during geomagnetic storms. Much of this energy is deposited into the plasma sheet, driving phenomena that leads to heating. The plasma sheet ions are then injected to the inner magnetosphere, driving the ring current. While ions can undergo adiabatic heating during typical drift motion, collisional and wave-particle interactions can also lead to ion heating. A technique to measure ion temperatures using energetic neutral atom (ENA) data has been developed using ENA data from the Two Wide-angle Imaging Neutral-atom Spectrometers (TWINS) mission global maps of ion temperature during the evolution of geomagnetic storms are made. These maps exhibit the location and characteristics of regions of ion heating and during which storm phase they occur. Superposed epoch analyses of such maps have demonstrated typical characteristics of ion heating during storms driven by coronal mass ejections as compared to those driven by high speed solar wind streams. The temperatures have been used to establish boundary conditions for modeling of the inner magnetosphere. We will give an overview of recent studies using TWINS ion temperature maps. Work supported by NNX10AN08A and AGS-1113478.

  14. Lattice sites of ion implanted Cu atoms in diamond

    CERN Document Server

    Bharuth-Ram, K; Correia, J G

    2003-01-01

    Radioactive $^{67}$Cu atoms were accelerated to 60 keV at the online isotope separator ISOLDE at CERN, and implanted into a type IIa natural diamond sample to a dose of 2 $\\times 10^{12}$ cm$^{-2}$. The channeling of $\\beta^{-}$-particles and conversion electrons emitted in the decay of $^{67}$Cu and $^{67}$Zn*, respectively, were monitored about the three major axial directions with a two dimensional position-sensitive detector. The electron emission channeling data were collected from the room temperature implanted sample and after annealing at 1200$^\\circ$ K. The observed channeling patterns were fitted with simulations based on the many beam formalism of electron motion through a crystal lattice. In the as-implanted sample, 25% of the Cu atoms were located a mean, isotropic displacement of 0.25(5) from substitutional sites, and the remainder, fR=75%, at sites that gave an isotropic emission yield. Annealing at 1200$^\\circ$ K results in enhanced axial and planar channeling effects. The fits to the data yie...

  15. In Pursuit of Highly Accurate Atomic Lifetime Measurements of Multiply Charged Ions

    Energy Technology Data Exchange (ETDEWEB)

    Trabert, E

    2009-06-01

    Accurate atomic lifetime data are useful for terrestrial and astrophysical plasma diagnostics. At accuracies higher than those required for these applications, lifetime measurements test atomic structure theory in ways complementary to spectroscopic energy determinations. At the highest level of accuracy, the question arises whether such tests reach the limits of modern theory, a combination of quantum mechanics and QED, adn possibly point to physics beyond the Standard Model. If high-precision atomic lifetime measurements, especially on multiply charged ions, have not quite reached this high accuracy yet, then what is necessary to attain this goal?

  16. Near threshold photodetachment cross section of negative atomic oxygen ions

    Institute of Scientific and Technical Information of China (English)

    Wu Jian-Hua(吴建华); Yuan Jian-Min(袁建民); Vo Ky Lan

    2003-01-01

    A 40-target state close-coupling calculation for the photodetachment cross section of negative atomic oxygen near threshold is carried out with core-valence electron correlation by using the R-matrix method. It was shown that after considering the excitations of two electrons from the 2s shell, the electron affinity of O- (2s22p5 2po) agrees with the experimental result much better than that just considering the excitations of electrons only from the 2p shell as well as only one electron from the 2s shell. Total cross section as well as the main contribution of the ionization channels to the partial cross section are illustrated to show the structure near threshold clearly.

  17. Atom probe field ion microscopy and related topics: A bibliography 1990

    Energy Technology Data Exchange (ETDEWEB)

    Russell, K.F.; Miller, M.K.

    1991-12-01

    This bibliography includes references related to the following topics: atom probe field ion microscopy (APFIM), field ion microscopy (FIM), field emission (FE), ion sources, and field desorption mass microscopy (FDMM). Technique-orientated studies and applications are included. The bibliography covers the period 1990. The references contained in this document were compiled from a variety of sources including computer searches and personal lists of publications. To reduce the length of this document, the references have been reduced to the minimum necessary to locate the articles. The references, listed alphabetically by authors, are subdivided into the categories listed in paragraph one above. An Addendum of references missed in previous bibliographies is included.

  18. An ion cyclotron resonance study of reactions of some atomic and simple polyatomic ions with water

    Science.gov (United States)

    Karpas, Z.; Anicich, V. G.; Huntress, W. T., Jr.

    1978-01-01

    Reactions of various positive ions with water vapor were studied by ion cyclotron resonance mass spectrometric techniques. Rate constants and product distributions were determined for reactions of the ions: Ar(+), Co(+), N2(+), and CO2(+), CH2(+), and CH4(+), CH2Cl(+), HCO(+), H2CO(+), H2COH(+), H2S(+) and HS(+). The results obtained in this work are compared with earlier reported data where available.

  19. Crystallographic studies of inter-atomic interactions and ion migration

    DEFF Research Database (Denmark)

    Filsø, Mette Østergaard

    2016-01-01

    anvendt på kendte Li ionledere til anvendelse som elektroder i Li-ion batterier. Metoden valideres ved sammenligning med eksperiment og en række andre teoretiske metoder, og trods det simple beregningsprincip foreslår the Procrysal Analysis mange korrekte migrationsstier og estimerer den relative...... struktur, hvilket fører til en reversibel formindskelse af båndgabet og et betydeligt farveskift. For både TiS2, ZnSb og Zn4Sb3 blev der fundet faseovergange ved højt tryk: TiS2 omdannedes til et trefasesystem, som stadig er bliver undersøgt, mens ZnSb og Zn4Sb3 begge omdannedes til den samme, simple...

  20. Influence of ion/atom arrival ratio on structure and optical properties of AlN films by ion beam assisted deposition

    Energy Technology Data Exchange (ETDEWEB)

    Meng, Jian-ping [Department of Energy Material and Technology, General Research Institute for Nonferrous Metals, Beijing 100088 (China); School of Engineering and Technology, China University of Geosciences, Beijing 100083 (China); Fu, Zhi-qiang, E-mail: fuzq@cugb.edu.cn [School of Engineering and Technology, China University of Geosciences, Beijing 100083 (China); Liu, Xiao-peng [Department of Energy Material and Technology, General Research Institute for Nonferrous Metals, Beijing 100088 (China); Yue, Wen; Wang, Cheng-biao [School of Engineering and Technology, China University of Geosciences, Beijing 100083 (China)

    2014-10-30

    Highlights: • AlN films were fabricated by dual ion beam sputtering. • Chemical bond status and phase composition of the films were studied by XPS and XRD. • Optical constants were measured by spectroscopic ellipsometry. • Influence of ion/atom arrival ratio on the films was studied. - Abstract: In order to improve the optical properties of AlN films, the influence of the ion/atom arrival ratio on the structure and optical characteristics of AlN films deposited by dual ion beam sputtering was studied by using X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, spectroscopic ellipsometry and UV–vis spectroscopy. The films prepared at the ion/atom arrival ratio of 1.4 are amorphous while the crystalline quality is improved with the increase of the ion/atom arrival ratio. The films deposited at the ion/atom arrival ratio of no less than 1.8 have an approximately stoichiometric ratio and mainly consist of aluminum nitride with little aluminum oxynitride, while metallic aluminum component appears in the films deposited at the ion/atom arrival ratio of 1.4. When the ion/atom arrival ratio is not less than 1.8, films are smooth, high transmitting and dense. The films prepared with high ion/atom arrival ratio (≥1.8) display the characteristic of a dielectric. The films deposited at the ion/atom arrival ratio of 1.4 are coarse, opaque and show characteristic of cermet.

  1. Solar Wind Charge Exchange Studies Of Highly Charged Ions On Atomic Hydrogen

    International Nuclear Information System (INIS)

    Accurate studies of low-energy charge exchange (CX) are critical to understanding underlying soft X-ray radiation processes in the interaction of highly charged ions from the solar wind with the neutral atoms and molecules in the heliosphere, cometary comas, planetary atmospheres, interstellar winds, etc.. Particularly important are the CX cross sections for bare, H-like, and He-like ions of C, N, O and Ne, which are the dominant charge states for these heavier elements in the solar wind. Absolute total cross sections for single electron capture by H-like ions of C, N, O and fully-stripped O ions from atomic hydrogen have been measured in an expanded range of relative collision energies (5 eV/u-20 keV/u) and compared to previous H-oven measurements. The present measurements are performed using a merged-beams technique with intense highly charged ion beams extracted from a 14.5 GHz ECR ion source installed on a high voltage platform at the Oak Ridge National Laboratory. For the collision energy range of 0.3 keV/u-3.3 keV/u, which corresponds to typical ion velocities in the solar wind, the new measurements are in good agreement with previous H-oven measurements. The experimental results are discussed in detail and compared with theoretical calculations where available.

  2. Solar Wind Charge Exchange Studies Of Highly Charged Ions On Atomic Hydrogen

    Science.gov (United States)

    Draganić, I. N.; Seely, D. G.; McCammon, D.; Havener, C. C.

    2011-06-01

    Accurate studies of low-energy charge exchange (CX) are critical to understanding underlying soft X-ray radiation processes in the interaction of highly charged ions from the solar wind with the neutral atoms and molecules in the heliosphere, cometary comas, planetary atmospheres, interstellar winds, etc.. Particularly important are the CX cross sections for bare, H-like, and He-like ions of C, N, O and Ne, which are the dominant charge states for these heavier elements in the solar wind. Absolute total cross sections for single electron capture by H-like ions of C, N, O and fully-stripped O ions from atomic hydrogen have been measured in an expanded range of relative collision energies (5 eV/u-20 keV/u) and compared to previous H-oven measurements. The present measurements are performed using a merged-beams technique with intense highly charged ion beams extracted from a 14.5 GHz ECR ion source installed on a high voltage platform at the Oak Ridge National Laboratory. For the collision energy range of 0.3 keV/u-3.3 keV/u, which corresponds to typical ion velocities in the solar wind, the new measurements are in good agreement with previous H-oven measurements. The experimental results are discussed in detail and compared with theoretical calculations where available.

  3. Photoionization cross-sections for atoms and ions of aluminum, silicon, and argon.

    Science.gov (United States)

    Chapman, R. D.; Henry, R. J. W.

    1972-01-01

    Photoionization cross sections for all levels belonging to the configurations of atoms and ions of aluminum, silicon, and argon have been calculated using Hartree-Fock bound-electron wave functions and close-coupling approximation free-electron wave functions. The results are presented in the form of a computationally convenient interpolation formula and should find wide astrophysical application.

  4. Atomic physics with highly charged ions. Progress report, FY 1989--91

    Energy Technology Data Exchange (ETDEWEB)

    Richard, P.

    1991-08-01

    This report discusses: One electron outer shell processes in fast ion-atom collisions; role of electron-electron interaction in two-electron processes; multi-electron processes at low energy; multi-electron processes at high energy; inner shell processes; molecular fragmentation studies; theory; and, JRM laboratory operations.

  5. Preface: Photon and fast Ion induced Processes in Atoms, MOlecules and Nanostructures (PIPAMON)

    Science.gov (United States)

    Kövér, László

    2016-02-01

    This Special Issue contains selected papers of contributions presented in the International Workshop on Photon and fast Ion induced Processes in Atoms, MOlecules and Nanostructures (PIPAMON), held between March 24 and 26, 2015 in Debrecen, Hungary. The venue, the Aquaticum Thermal and Wellness Hotel provided a pleasant "all-under-one-roof" environment for the event.

  6. Towards a precise measurement of atomic parity violation in a single Ra+ ion

    NARCIS (Netherlands)

    Nunez Portela, M.; van den Berg, J. E.; Bekker, H.; Giri, G.S.; Hoekstra, S.; Jungmann, K.; Mohanty, A.; Onderwater, G.J.C.; Santra, B.; Schlesser, S.; Timmermans, R.G.E.; Versolato, O.O.; Wansbeek, L.W.; Willmann, L.; Wilschut, H.W.

    2013-01-01

    A single trapped Ra+(Z= 88) ion provides a very promising route towards a most precise measurement of Atomic Parity Violation (APV), since APV effects grow faster than Z 3. This experiment promises the best determination of the electroweak coupling constant at the lowest accessible energies. Such a

  7. ELECTRON-CAPTURE IN HIGHLY-CHARGED ION-ATOM COLLISIONS

    NARCIS (Netherlands)

    MORGENSTERN, R

    1993-01-01

    An attempt is made to identify the most important mechanisms responsible for the rearrangement of electrons during collisions between multiply charged ions and atoms at keV energies. It is discussed to which extent the influence of binding energy, angular momentum of heavy particles and electrons, a

  8. Thermochemical equilibrium in the atmospheres of cool stars. Atoms and ions

    Energy Technology Data Exchange (ETDEWEB)

    Komarov, N.S.; Tsymbal, V.V.

    1980-09-01

    A method of solving the equation of state of matter in the atmospheres of stars of late spectral classes is described. The influence of the abundances of chemical elements on the structure of stellar atmospheres and the influence of the fundamental characteristics of the atmosphere on the concentrations of atoms and ions as a function of optical depth are investigated.

  9. Relativistic effects in non-radiative electron capture in ion-atom collisions

    International Nuclear Information System (INIS)

    In this paper, a modified eikonal method (Blankenbecler-Goldberger) has been extended to perform calculations for the electron capture processes in relativistic ion-atom collisions. The results are compared with the first order Born approximation and the ordinary eikonal approximation. The relativistic effects are discussed. Some conclusions are drawn. (author)

  10. Electron and X-ray emission in collisions of multiply charged ions and atoms

    International Nuclear Information System (INIS)

    The author presents experimental results of electron and X-ray emission following slow collisions of multiply charged ions and atoms. The aim of the investigation was to study the mechanisms which are responsible for the emission. (G.T.H.)

  11. Scattering of atomic and molecular ions from single crystal surfaces of Cu, Ag and Fe

    International Nuclear Information System (INIS)

    This thesis deals with analysis of crystal surfaces of Cu, Ag and Fe with Low Energy Ion scattering Spectroscopy (LEIS). Different atomic and molecular ions with fixed energies below 7 keV are scattered by a metal single crystal (with adsorbates). The energy and direction of the scattered particles are analysed for different selected charge states. In that way information can be obtained concerning the composition and atomic and electronic structure of the single crystal surface. Energy spectra contain information on the composition of the surface, while structural atomic information is obtained by direction measurements (photograms). In Ch.1 a description is given of the experimental equipment, in Ch.2 a characterization of the LEIS method. Ch.3 deals with the neutralization of keV-ions in surface scattering. Two different ways of data interpretation are presented. First a model is treated in which the observed directional dependence of neutralization action of the first atom layer of the surface is presented by a laterally varying thickness of the neutralizing layer. Secondly it is shown that the data can be reproduced by a more realistic, physical model based on atomic transition matrix elements. In Ch.4 the low energy hydrogen scattering is described. The study of the dissociation of H2+ at an Ag surface r0230ted in a model based on electronic dissociation, initialized by electron capture into a repulsive (molecular) state. In Ch.5 finally the method is applied to the investigation of the surface structure of oxidized Fe. (Auth.)

  12. A method for atomic spectroscopy of highly charged ions in the Pm isoelectronic sequence

    International Nuclear Information System (INIS)

    The aim was to search for alkali-like spectra in the Promethium isoelectronic sequence. Pb22+ ions were produced by means of an ECR-ion source and accelerated towards a target of He gas. Colliding with He atoms the Pb22+ ions are likely to capture an electron, thus forming an excited Pm-like ion (Pb21+). A 2 m grazing-incidence spectrometer was used for recording the spectra arising as the accelerated ions impinge on the target. No lines were recorded throughout the wavelength region where the spectrometer is sensitive. Further experiments are needed to make clear if this is due to experimental errors or not. 14 refs, 8 figs

  13. Single electron capture in fast ion-atom collisions

    Science.gov (United States)

    Milojević, Nenad

    2014-12-01

    Single-electron capture cross sections in collisions between fast bare projectiles and heliumlike atomic systems are investigated by means of the four-body boundary-corrected first Born (CB1-4B) approximation. The prior and post transition amplitudes for single charge exchange encompassing symmetric and asymmetric collisions are derived in terms of twodimensional real integrals in the case of the prior form and five-dimensional quadratures for the post form. The dielectronic interaction V12 = 1/r12 = 1/|r1 - r2| explicitly appears in the complete perturbation potential Vf of the post transition probability amplitude T+if. An illustrative computation is performed involving state-selective and total single capture cross sections for the p - He (prior and post form) and He2+, Li3+Be4+B5+C6+ - He (prior form) collisions at intermediate and high impact energies. We have also studied differential cross sections in prior and post form for single electron transfer from helium by protons. The role of dynamic correlations is examined as a function of increased projectile energy. Detailed comparisons with the measurements are carried out and the obtained theoretical cross sections are in reasonable agreement with the available experimental data.

  14. Application of Ion and Electron Momentum Imaging to Atomic Collisions

    Science.gov (United States)

    Cocke, C. L.

    2000-06-01

    COLTRIMS (COLd Target Recoil Ion Momentum Spectroscopy) combines fast imaging detectors with a supersonically cooled gas target to allow the charged particles from any ionizing collision, including both recoil ions and electrons, to be collected with extremely high efficiency and with fully measured vector momenta. Since all particles are measured in event mode, the full multi-dimensional momentum space is mapped. We will review several examples of the use of this technique to study two- , three- and four-body final states created in ionizing interactions of photons and charged particles with He and D2 . The momentum spectra of electrons ejected from these targets by slow projectiles reveal the stucture of the molecular orbitals which are promoted into the continuum. Double photoionization of the same targets reveals patterns which can be interpreted in terms of collective coordinates. Two-electron removal from D2 by Xe ^26+ reveals the influence of the projectile field on the dissociation process. A recent application of the technique to ionization by high intensity laser fields will be discussed. Work performed in collaboration with M.A.Abdallah^1, I.Ali^1, Matthias Achler^2, H.Braeuning^2,3, Angela Braeuning-Deminian^2, Achim Czasch^2,3, R.Doerner^2,3, R.DuBois^6, A. Landers^1,5, V.Mergel^2, R.E.Olson^6, T.Osipov^1, M.Prior^3, H.Schmidt-Boecking^2, M.Singh^1, A.Staudte^2,3, T.Weber^2, W.Wolff^4, and H.E.Wolf^4 ^1J.R.Macdonald Laboratory, Physics Department, Kansas State University, Manhattan, KS 66506; ^2 Institut fuer Kernphysik, Univ. Frankfurt, August-Euler-Str.6,D-60486 Frankfurt, Germany ; ^3Lawrence Berkeley National Laboratory, Berkeley, CA 94720; ^4Instituto de Fisica, Universidade Federal do Rio de Janeiro Caixa Postal 68.528, 21945-970, Rio de Janeiro, Brazil; ^5Physics Dept., Western Michigan University, Kalamazoo, MI 49008; ^6Physics Dept., Univ. Missouri Rolla, Rolla, MO 65409 Work supported by the Division of Chemical Sciences, Office of Basic

  15. New possibilities in high sensitivity low energy ion scattering (LEIS) for probing the outermost atomic layer

    International Nuclear Information System (INIS)

    With a recently developed high sensitivity low energy ion scattering (LEIS) instrument, a range of new applications arises for this extremely surface sensitive analytical technique. Known capabilities of LEIS are the selective characterisation and quantification of the atomic composition of the outermost atomic layer, i. e. precisely the atoms that control properties like catalytic performance, adhesion, wetting, corrosion, etc. New possibilities such as surface imaging, sputter as well as non-destructive (static) profiling and even higher sensitivity for light elements have been added. The energy range of the primary ion source of up to 8 keV allows an improved mass resolution, thus enabling a better separation of the heaviest elements. In addition, a time-of-flight filter dramatically improves the detection limit for light elements. This filter suppresses the signal arising from sputtered ions, while scattered ions reach the detection system unhindered. In this contribution, we show the utilization of these new capabilities to a range of samples and applications. Furthermore, we will show how LEIS can benefit from the combination with the complementary technique time-of-flight secondary ion mass spectrometry (TOF-SIMS), which adds ppb-ppm sensitivity, lateral resolution of 100 nm and chemical information

  16. Atomic site sensitive processes in low energy ion-dimer collisions

    CERN Document Server

    Iskandar, W; Leredde, A; Fléchard, X; Gervais, B; Guillous, S; Hennecart, D; Méry, A; Rangama, J; Zhou, C L; Shiromaru, H; Cassimi, A

    2014-01-01

    Electron capture processes for low energy Ar9+ ions colliding on Ar2 dimer targets are investigated, focusing attention on charge sharing as a function of molecule orientation and impact parameter. A preference in charge-asymmetric dissociation channels is observed, with a strong correlation between the projectile scattering angle and the molecular ion orientation. The measurements provide here clear evidences that projectiles distinguish each atom in the target and, that electron capture from near-site atom is favored. Monte Carlo calculations based on the classical over-the-barrier model, with dimer targets represented as two independent atoms, are compared to the data. They give a new insight into the dynamics of the collision by providing, for the di erent electron capture channels, the two-dimensional probability maps p(~b), where ~b is the impact parameter vector in the molecular frame.

  17. Long-range interactions between the alkali-metal atoms and alkaline earth ions

    CERN Document Server

    Kaur, Jasmeet; Arora, Bindiya; Sahoo, B K

    2014-01-01

    Accurate knowledge of interaction potentials among the alkali atoms and alkaline earth ions is very useful in the studies of cold atom physics. Here we carry out theoretical studies of the long-range interactions among the Li, Na, K, and Rb alkali atoms with the Ca$^+$, Ba$^+$, Sr$^+$, and Ra$^+$ alkaline earth ions systematically which are largely motivated by their importance in a number of applications. These interactions are expressed as a power series in the inverse of the internuclear separation $R$. Both the dispersion and induction components of these interactions are determined accurately from the algebraic coefficients corresponding to each power combination in the series. Ultimately, these coefficients are expressed in terms of the electric multipole polarizabilities of the above mentioned systems which are calculated using the matrix elements obtained from a relativistic coupled-cluster method and core contributions to these quantities from the random phase approximation. We also compare our estim...

  18. An investigation of polarized atomic photofragments using the ion imaging technique

    Energy Technology Data Exchange (ETDEWEB)

    Bracker, A.S.

    1997-12-01

    This thesis describes measurement and analysis of the recoil angle dependence of atomic photofragment polarization (atomic v-J correlation). This property provides information on the electronic rearrangement which occurs during molecular photodissociation. Chapter 1 introduces concepts of photofragment vector correlations and reviews experimental and theoretical progress in this area. Chapter 2 described the photofragment ion imaging technique, which the author has used to study the atomic v-J correlation in chlorine and ozone dissociation. Chapter 3 outlines a method for isolating and describing the contribution to the image signal which is due exclusively to angular momentum alignment. Ion imaging results are presented and discussed in Chapter 4. Chapter 5 discusses a different set of experiments on the three-fragment dissociation of azomethane. 122 refs.

  19. Surpassing the mass restriction of buffer gas cooling: Cooling of low mass ions by localized heavier atoms

    Science.gov (United States)

    Dutta, Sourav; Sawant, Rahul; Rangwala, S. A.

    2016-05-01

    Cooling of trapped ions has resulted in fascinating science including the realization of some of the most accurate atomic clocks. It has also found widespread application, for example, in mass spectrometry and cold chemistry. Among the different methods for cooling ions, cooling by elastic collisions with ultracold neutral atoms is arguably the most generic. However, in spite of its widespread application, there is confusion with regards the collisional heating/cooling of light ions by heavier neutral atoms. We address the question experimentally and demonstrate, for the first time, cooling of light ions by co-trapped heavy atoms. We show that trapped 39 K+ ions are cooled by localized ultracold neutral 85 Rb atoms. The atom-ion mass ratio (= 2.18) is well beyond any theoretical predictions so far. We further argue that cooling of ions by localized cold atoms is possible for any mass ratio. The result opens up the possibility of reaching the elusive s-wave collision regime in atom-ion collisions. S.D. is supported by DST-INSPIRE Faculty Fellowship, India.

  20. Delta-ray production in ion-atom collisions

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, W.E.; Toburen, L.H.

    1980-07-01

    The stochastic energy concentrations randomly deposited in submicron volumes in and near the paths of charged particles is needed. Computational methods, especially Monte Carlo methods, required a comprehensive set of basic interaction cross sections for the primary and all secondary radiation products. Of particular importance for high LET radiations are the cross sections for the production of energetic secondary electrons, delta-rays, in primary ionizing events. In this paper, we review the present state of available data on the production of delta-rays by fast positive ions in collision with targets of biological interest. The systematics in the cross sections for proton ionization of molecular targets are discussed, indicating what scaling is possible and summarizing what can be concluded regarding the dependence of the mean delta-ray energies on the chemical makeup of the medium. A comparison of typical data is made with the binary-encounter approximation to illustrate the limitations of this theoretical treatment of the ionization process. A bibliography of relevant published works on this topic is included.

  1. Formation of nanostructures on HOPG surface in presence of surfactant atom during low energy ion irradiation

    Science.gov (United States)

    Ranjan, M.; Joshi, P.; Mukherjee, S.

    2016-07-01

    Low energy ions beam often develop periodic patterns on surfaces under normal or off-normal incidence. Formation of such periodic patterns depends on the substrate material, the ion beam parameters, and the processing conditions. Processing conditions introduce unwanted contaminant atoms, which also play strong role in pattern formation by changing the effective sputtering yield of the material. In this work we have analysed the effect of Cu, Fe and Al impurities introduced during low energy Ar+ ion irradiation on HOPG substrate. It is observed that by changing the species of foreign atoms the surface topography changes drastically. The observed surface topography is co-related with the modified sputtering yield of HOPG. Presence of Cu and Fe amplify the effective sputtering yield of HOPG, so that the required threshold for the pattern formation is achieved with the given fluence, whereas Al does not lead to any significant change in the effective yield and hence no pattern formation occurs.

  2. Coupling all-atom molecular dynamics simulations of ions in water with Brownian dynamics

    CERN Document Server

    Erban, Radek

    2015-01-01

    Molecular dynamics (MD) simulations of ions (K$^+$, Na$^+$, Ca$^{2+}$ and Cl$^-$) in aqueous solutions are investigated. Water is described using the SPC/E model. A stochastic coarse-grained description for ion behaviour is presented and parameterized using MD simulations. It is given as a system of coupled stochastic and ordinary differential equations, describing the ion position, velocity and acceleration. The stochastic coarse-grained model provides an intermediate description between all-atom MD simulations and Brownian dynamics (BD) models. It is used to develop a multiscale method which uses all-atom MD simulations in parts of the computational domain and (less detailed) BD simulations in the remainder of the domain.

  3. Kinetic theory and atomic physics corrections for determination of ion velocities from charge-exchange spectroscopy

    Science.gov (United States)

    Muñoz Burgos, J. M.; Burrell, K. H.; Solomon, W. M.; Grierson, B. A.; Loch, S. D.; Ballance, C. P.; Chrystal, C.

    2013-09-01

    Charge-exchange spectroscopy is a powerful diagnostic tool for determining ion temperatures, densities and rotational velocities in tokamak plasmas. This technique depends on detailed understanding of the atomic physics processes that affect the measured apparent velocities with respect to the true ion rotational velocities. These atomic effects are mainly due to energy dependence of the charge-exchange cross-sections, and in the case of poloidal velocities, due to gyro-motion of the ion during the finite lifetime of the excited states. Accurate lifetimes are necessary for correct interpretation of measured poloidal velocities, specially for high density plasma regimes on machines such as ITER, where l-mixing effects must be taken into account. In this work, a full nl-resolved atomic collisional radiative model coupled with a full kinetic calculation that includes the effects of electric and magnetic fields on the ion gyro-motion is presented for the first time. The model directly calculates from atomic physics first principles the excited state lifetimes that are necessary to evaluate the gyro-orbit effects. It is shown that even for low density plasmas where l-mixing effects are unimportant and coronal conditions can be assumed, the nl-resolved model is necessary for an accurate description of the gyro-motion effects to determine poloidal velocities. This solution shows good agreement when compared to three QH-mode shots on DIII-D, which contain a wide range of toroidal velocities and high ion temperatures where greater atomic corrections are needed. The velocities obtained from the model are compared to experimental velocities determined from co- and counter-injection of neutral beams on DIII-D.

  4. Spectr-W3 online database on atomic properties of multicharged ions

    Science.gov (United States)

    Skobelev, I. Yu; Loboda, P. A.; Faenov, A. Ya; Gagarin, S. V.; Kozlov, A. I.; Morozov, S. V.; Pikuz, S. A.; Pikuz, T. A.; Popova, V. V.

    2015-11-01

    The Spectr-W3 information-reference system was developed in 2001-2013 and realized as an online Web resource based on the factual atomic database Spectr-W3. The information accumulated in the Spectr-W3 atomic database contains about 450,000 records and includes the experimental and theoretical data on ionization potentials, energy levels, wavelengths, radiation transition probabilities, and oscillator strengths, and the parameters of analytical approximations of electron-collisional cross-sections and rates for atoms and ions. Those data were extracted from publications in physical journals, proceedings of the related conferences, special-purpose publications on atomic data, provided directly by authors. The information is supplied with references to the original sources and comments, elucidating the details of experimental measurements or calculations. To date, the Spectr-W3 atomic database is still the largest factual database in the world, containing the information on spectral properties of multicharged ions. In 2014, the new stage in the development of the Spectr-W3 atomic database started. The purpose of this stage is the creation of a new information section of the Spectr-W3 database. This section would contain the information on the x-ray emission spectrograms registered from various plasma sources.

  5. Study of defects, radiation damage and implanted gases in solids by field-ion and atom-probe microscopy

    International Nuclear Information System (INIS)

    The ability of the field-ion microscope to image individual atoms has been applied, at Cornell University, to the study of fundamental properties of point defects in irradiated or quenched metals. The capability of the atom probe field-ion microscope to determine the chemistry - that is, the mass-to-charge ratio - of a single ion has been used to investigate the behavior of different implanted species in metals. A brief review is presented of: (1) the basic physical principles of the field-ion and atom-probe microscopes; (2) the many applications of these instruments to the study of defects and radiation damage in solids; and (3) the application of the atom-probe field-ion microscope to the study of the behavior of implanted 3He and 4He atoms in tungsten. The paper is heavily referenced so that the reader can pursue his specific research interests in detail

  6. Ion Flux Measurements in Electron Beam Produced Plasmas in Atomic and Molecular Gases

    Science.gov (United States)

    Walton, S. G.; Leonhardt, D.; Blackwell, D. D.; Murphy, D. P.; Fernsler, R. F.; Meger, R. A.

    2001-10-01

    In this presentation, mass- and time-resolved measurements of ion fluxes sampled from pulsed, electron beam-generated plasmas will be discussed. Previous works have shown that energetic electron beams are efficient at producing high-density plasmas (10^10-10^12 cm-3) with low electron temperatures (Te < 1.0 eV) over the volume of the beam. Outside the beam, the plasma density and electron temperature vary due, in part, to ion-neutral and electron-ion interactions. In molecular gases, electron-ion recombination plays a significant role while in atomic gases, ion-neutral interactions are important. These interactions also determine the temporal variations in the electron temperature and plasma density when the electron beam is pulsed. Temporally resolved ion flux and energy distributions at a grounded electrode surface located adjacent to pulsed plasmas in pure Ar, N_2, O_2, and their mixtures are discussed. Measurements are presented as a function of operating pressure, mixture ratio, and electron beam-electrode separation. The differences in the results for atomic and molecular gases will also be discussed and related to their respective gas-phase kinetics.

  7. An empirical curve describing the ionization cross-sections in atomic collisions involving heavy ions

    International Nuclear Information System (INIS)

    In a recent paper, a fifth order polynomial curve was presented which fits very well to the existing experimental data on K-shell ionization cross-sections induced by protons. It is a universal curve, in the sense that it includes target atoms of any Z number at any projectile (proton) energy. In principle, it is possible to fit in the same curve the cross-sections obtained with any ion as a projectile, by means of a scaling law derived from the plane wave Born approximation (PWBA) and the binary encounter approximation (BEA) models. Experimental data with deuterons, alpha particles and 3He ions were fit into the same curve, with a good agreement. The agreement was poorer for experimental cross-sections obtained with heavier ions, like 12C, 14N and 40Ar. The discrepancies are attributable to several aspects of the ion-atom interaction, not considered in the derivation of such scaling law. The ECPSSR model has been more successful on predicting the cross-sections for heavy ions. Within the considerations in the ECPSSR and other models, arguments are given to explain the former discrepancies and suggestions are made to generalize the scaling law to fit the heavy ion data in a single curve

  8. Grazing incidence collisions of ions and atoms with surfaces: from charge exchange to atomic diffraction; Collisions rasantes d'ions ou d'atomes sur les surfaces: de l'echange de charge a la diffraction atomique

    Energy Technology Data Exchange (ETDEWEB)

    Rousseau, P

    2006-09-15

    This thesis reports two studies about the interaction with insulating surfaces of keV ions or atoms under grazing incidence. The first part presents a study of charge exchange processes occurring during the interaction of singly charged ions with the surface of NaCl. In particular, by measuring the scattered charge fraction and the energy loss in coincidence with electron emission, the neutralization mechanism is determined for S{sup +}, C{sup +}, Xe{sup +}, H{sup +}, O{sup +}, Kr{sup +}, N{sup +}, Ar{sup +}, F{sup +}, Ne{sup +} and He{sup +}. These results show the importance of the double electron capture as neutralization process for ions having too much potential energy for resonant capture and not enough for Auger neutralization. We have also studied the ionisation of the projectile and of the surface, and the different Auger-like neutralization processes resulting in electron emission, population of conduction band or excited state. For oxygen scattering, we have measured an higher electron yield in coincidence with scattered negative ion than with scattered atom suggesting the transient formation above the surface of the oxygen doubly negative ion. The second study deals with the fast atom diffraction, a new phenomenon observed for the first time during this work. Due to the large parallel velocity, the surface appears as a corrugated wall where rows interfere. Similarly to the Thermal Atom Scattering the diffraction pattern corresponds to the surface potential and is sensitive to vibrations. We have study the H-NaCl and He-LiF atom-surface potentials in the 20 meV - 1 eV range. This new method offers interesting perspectives for surface characterisation. (author)

  9. Atomic physics with highly-charged heavy ions at the GSI future facility: The scientific program of the SPARC collaboration

    Energy Technology Data Exchange (ETDEWEB)

    Stoehlker, Th. [Gesellschaft fur Schwerionenforschung mbh, 64291 GSI-Darmstadt (Germany)]. E-mail: t.stoehlker@gsi.de; Beier, T. [Gesellschaft fur Schwerionenforschung mbh, 64291 GSI-Darmstadt (Germany); Beyer, H.F. [Gesellschaft fur Schwerionenforschung mbh, 64291 GSI-Darmstadt (Germany); Bosch, F. [Gesellschaft fur Schwerionenforschung mbh, 64291 GSI-Darmstadt (Germany); Braeuning-Demian, A. [Gesellschaft fur Schwerionenforschung mbh, 64291 GSI-Darmstadt (Germany); Gumberidze, A. [Gesellschaft fur Schwerionenforschung mbh, 64291 GSI-Darmstadt (Germany); Hagmann, S. [Gesellschaft fur Schwerionenforschung mbh, 64291 GSI-Darmstadt (Germany); Kozhuharov, C. [Gesellschaft fur Schwerionenforschung mbh, 64291 GSI-Darmstadt (Germany); Kuehl, Th. [Gesellschaft fur Schwerionenforschung mbh, 64291 GSI-Darmstadt (Germany); Liesen, D. [Gesellschaft fur Schwerionenforschung mbh, 64291 GSI-Darmstadt (Germany); Mann, R. [Gesellschaft fur Schwerionenforschung mbh, 64291 GSI-Darmstadt (Germany); Mokler, P.H. [Gesellschaft fur Schwerionenforschung mbh, 64291 GSI-Darmstadt (Germany); Quint, W. [Gesellschaft fur Schwerionenforschung mbh, 64291 GSI-Darmstadt (Germany); Schuch, R. [Stockholm University, Stockholm (Sweden); Warczak, A. [Institute of Physics, Jagiellonian University, Cracow (Poland)

    2005-07-01

    In the current report a short overview about the envisioned program of the atomic physics research collaboration SPARC (Stored Particle Atomic Research Collaboration, at the new international accelerator Facility for Antiproton and Ion Research (FAIR) at GSI is given. In addition, a condensed description of the planned experimental areas devoted to atomic physics research at the new facility is presented.

  10. Time-evolution of many active electrons in slow ion-atom collisions

    Energy Technology Data Exchange (ETDEWEB)

    Runge, K.; Micha, D.A.

    1996-05-01

    The previously developed Eikonal/Time-dependent Hartree-Fock method is applied to slow ionic and atomic collisions involving many active electrons. The electronic density matrix is written in a basis of traveling atomic orbitals including s, p, and d-type atomic basis functions. One- and two-electron integrals are calculated in a static basis and transformed to the traveling basis. Electronic orbital polarization parameters are calculated during the collision to determine the degree of electonic orientation and alignment as a function of time. This method is currently being applied to slow collisions of hydrogen, alkali, alkali earth and rare gas atoms and ions, to calculate the time evolution of electronic energy and charge transfer, as well as orbital polarization.

  11. Bright focused ion beam sources based on laser-cooled atoms

    CERN Document Server

    McClelland, J J; Knuffman, B; Twedt, K A; Schwarzkopf, A; Wilson, T M

    2015-01-01

    Nanoscale focused ion beams (FIBs) represent one of the most useful tools in nanotechnology, enabling nanofabrication via milling and gas-assisted deposition, microscopy and microanalysis, and selective, spatially resolved doping of materials. Recently, a new type of FIB source has emerged, which uses ionization of laser cooled neutral atoms to produce the ion beam. The extremely cold temperatures attainable with laser cooling (in the range of 100 uK or below) result in a beam of ions with a very small transverse velocity distribution. This corresponds to a source with extremely high brightness that rivals or may even exceed the brightness of the industry standard Ga+ liquid metal ion source. In this review we discuss the context of ion beam technology in which these new ion sources can play a role, their principles of operation, and some examples of recent demonstrations. The field is relatively new, so only a few applications have been demonstrated, most notably low energy ion microscopy with Li ions. Never...

  12. Bright focused ion beam sources based on laser-cooled atoms

    Science.gov (United States)

    McClelland, J. J.; Steele, A. V.; Knuffman, B.; Twedt, K. A.; Schwarzkopf, A.; Wilson, T. M.

    2016-03-01

    Nanoscale focused ion beams (FIBs) represent one of the most useful tools in nanotechnology, enabling nanofabrication via milling and gas-assisted deposition, microscopy and microanalysis, and selective, spatially resolved doping of materials. Recently, a new type of FIB source has emerged, which uses ionization of laser cooled neutral atoms to produce the ion beam. The extremely cold temperatures attainable with laser cooling (in the range of 100 μK or below) result in a beam of ions with a very small transverse velocity distribution. This corresponds to a source with extremely high brightness that rivals or may even exceed the brightness of the industry standard Ga+ liquid metal ion source. In this review, we discuss the context of ion beam technology in which these new ion sources can play a role, their principles of operation, and some examples of recent demonstrations. The field is relatively new, so only a few applications have been demonstrated, most notably low energy ion microscopy with Li ions. Nevertheless, a number of promising new approaches have been proposed and/or demonstrated, suggesting that a rapid evolution of this type of source is likely in the near future.

  13. Experimental investigation of the formation of negative hydrogen ions in collisions between positive ions and atomic or molecular targets

    International Nuclear Information System (INIS)

    The formation of the negative hydrogen ion (H-) in collisions between a positive ion and a neutral atomic or molecular target is studied experimentally at impact energies of a few keV. The doubly-differential cross sections for H- formation are measured as a function of the kinetic energy and emission angle for the collision systems OH+ + Ar and O+ + H2O at 412 eV/a.m.u. These H- ions can be emitted at high energies (keV) in hard quasi-elastic two-body collisions involving a large momentum transfer to the H center. However, H- anions are preferentially emitted at low energy (eV) due to soft many-body (≥ 2) collisions resulting in a low momentum transfer. The formation of H- ions by electron capture follows excitation or ionization of the molecule. The molecular fragmentation dynamics is modeled to simulate the emission of H- ions. The overall good agreement between the simulation and the experiment leads to the understanding of most of the experimental observations. (author)

  14. Many-electron stripping in collisions between atoms and heavy ions

    International Nuclear Information System (INIS)

    Recent experiments suggest that a highly stripped ion can remove up to 10 electrons in a single collision with a neutral atom or molecule. It is shown that this process can take place through the coherent superposition of the heavy ion's electric field at different times, in a way analogous to multiphoton ionisation by intense radiation fields. For relatively fast ions, a simple theory is developed and results are presented for a variety of cases. The theory is in reasonable agreement with measured cross sections for 1s-vacancy production in Ne by Clsup(z+) ions at 50 MeV (2 02 for effective charges 10 7+ (1s2s2p 4P) may be as large as 0.1 πa02. The dependence of these cross sections on energy is complicated but their variation with Z at a fixed energy is usually rather gentle. (author)

  15. Anisotropy and linear polarization of radiative processes in energetic ion-atom collisions; Untersuchung zur Anisotropie und linearen Polarisation radiativer Prozesse in energiereichen Ion-Atom-Stoessen

    Energy Technology Data Exchange (ETDEWEB)

    Weber, Guenter

    2010-06-16

    In the present thesis the linear polarization of radiation emitted in energetic ion-atom collisions at the ESR storage ring was measured by applying a novel type of position, timing and energy sensitive X-ray detector as a Compton polarimeter. In contrast to previous measurements, that mainly concentrate on studies of the spectral and angular distribution, the new detectors allowed the first polarization study of the Ly-{alpha}{sub 1} radiation (2p{sub 3/2}{yields}1s{sub 1/2}) in U{sup 91+}. Owing to the high precision of the polarimeters applied here, the experimental results indicate a significant depolarization of the Ly-{alpha}{sub 1} radiation caused by the interference of the E1 and M2 transition branches. Moreover, the current investigation shows that measurements of the linear polarization in combination with angular distribution studies provide a model-independent probe for the ratio of the E1 and M2 transition amplitudes and, consequently, of the corresponding transition probabilities. In addition, a first measurement of the linear polarization as well as an angular distribution study of the electron-nucleus Bremsstrahlung arising from ion-atom collisions was performed. The experimental results obtained were compared to exact relativistic calculations and, in case of the Bremsstrahlung, to a semirelativistic treatment. In general, good agreement was found between theoretical predictions and experimental findings. (orig.)

  16. Collision of Bare Ion Si14+ with the Same Z Slow-atom Si

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    We present the collision of bare ion Si14+ with the same Z slow-atom Si. It is shown that the cold-atom collisions are sensitive to the potential. In this paper, we present the cross sectiond for the most important transition from the 3p13d1 and 3p14d1 excited states. It is seen that there are large cross sections when the angle is larger than 80 degrees. With increasing energy, the cross section becomes decresasingly flat.PACS numbers:34.70.+e, 32.80. Fb

  17. Resonant coherent ionization in grazing ion/atom-surface collisions at high velocities

    Energy Technology Data Exchange (ETDEWEB)

    Garcia de Abajo, F.J. (Dept. de Ciencias de la Computacion e Inteligencia Artificial, Facultad de Informatica, Univ. del Pais Vasco, San Sebastian (Spain)); Pitarke, J.M. (Materia Kondentsatuaren Fisika Saila, Zientzi Fakultatea, Euskal Herriko Univ., Bilbo (Spain))

    1994-05-01

    The resonant coherent interaction of a fast ion/atom with an oriented crystal surface under grazing incidence conditions is shown to contribute significantly to ionize the probe for high enough velocities and motion along a random direction. The dependence of this process on both the distance to the surface and the velocity of the projectile is studied in detail. We focus on the case of hydrogen moving with a velocity above 2 a.u. Comparison with other mechanisms of charge transfer, such as capture from inner shells of the target atoms, permits us to draw some conclusions about the charge state of the outgoing projectiles. (orig.)

  18. Interaction of slow and highly charged ions with surfaces: formation of hollow atoms

    Energy Technology Data Exchange (ETDEWEB)

    Stolterfoht, N.; Grether, M.; Spieler, A.; Niemann, D. [Hahn-Meitner Institut, Berlin (Germany). Bereich Festkoerperphysik; Arnau, A.

    1997-03-01

    The method of Auger spectroscopy was used to study the interaction of highly charged ions with Al and C surfaces. The formation of hollow Ne atoms in the first surface layers was evaluated by means of a Density Functional theory including non-linear screening effects. The time-dependent filling of the hollow atom was determined from a cascade model yielding information about the structure of the K-Auger spectra. Variation of total intensities of the L- and K-Auger peaks were interpreted by the cascade model in terms of attenuation effects on the electrons in the solid. (author)

  19. Negative ion productions in high velocity collision between small carbon clusters and Helium atom target

    International Nuclear Information System (INIS)

    We measured absolute double capture cross section of Cn+ ions (n=1,5) colliding, at 2.3 and 2.6 a.u velocities, with an Helium target atom and the branching ratios of fragmentation of the so formed electronically excited anions Cn−*. We also measured absolute cross section for the electronic attachment on neutral Cn clusters colliding at same velocities with He atom. This is to our knowledge the first measurement of neutral-neutral charge exchange in high velocity collision.

  20. K-shell ionization of atoms and ions by relativistic projectiles

    International Nuclear Information System (INIS)

    We evaluate the total cross section for the single K-shell ionization of atoms and ions by the impact of relativistic electrons. The study is performed to leading orders of the QED perturbation theory with respect to the parameters αZ and 1/Z. The results obtained are in good agreement with experimental data for different atomic targets. In the case of moderate values of the nuclear charge Z, the total cross section is described by a simple analytic formula. The K-shell ionization by relativistic heavy particles is also considered.

  1. Atomic and molecular effects on spherically convergent ion flow. II. Multiple molecular species

    Science.gov (United States)

    Emmert, Gilbert A.; Santarius, John F.

    2010-01-01

    A theoretical model for the effect of molecular interactions on the flow of molecular ions in spherically convergent geometry where the inner grid (cathode) is at a large negative potential and the outer grid (anode) is grounded has been developed. The model assumes a weakly ionized deuterium plasma composed of D+, D2+, and D3+ ions that interact with the dominant background gas (D2). The interactions included are charge exchange, ionization, and dissociative processes. The formalism developed includes the bouncing motion of the ions in the electrostatic well and sums over all generations of subsequent ions produced by atomic and molecular processes. This leads to a set of two coupled Volterra integral equations, which are solved numerically. From the solution of the Volterra equations, one can obtain quantities of interest, such as the energy spectra of the ions and fast neutral atoms and molecules, and the fusion reaction rate. To provide an experimental test, the model is applied to inertial electrostatic devices and the calculated neutron production rate is compared to previously reported measurements for one University of Wisconsin inertial electrostatic confinement device [D. C. Donovan et al., Fusion Sci. Technol. 56, 507 (2009)]. The results show general agreement with the experimental results, but significant differences remain to be resolved.

  2. Orbital-angular-momentum change in sodium Rydbery atoms induced by collisions with slow ions

    Energy Technology Data Exchange (ETDEWEB)

    Smith, D.B.

    1987-01-01

    This dissertation describes the experimental measurement of angular-momentum change in sodium Rydberg-state atoms induced by collisions with slow Na/sup +/ ions. For these measurements an existing crossed-beam apparatus was modified by the addition of two ion sources, one a thermionic emitter, the other a duoplasmatron. In the experiments, Na atoms were laser-excited to Rydberg nd-levels (principal quantum numbers n = 21 to 29) and were exposed to a Na/sup +/ ion beam (energies 29 to 590 eV from the thermionic emitter) in a crossed-beam experiment. A method was devised for a direct measurement of the ion-beam current density in the interaction region. During an interaction time of approximately 3 ..mu..sec, collisions occurred in which the initial orbital-angular-momentum l was increased by an amount ..delta..l greater than or equal to 1. The distribution of final nl states was analyzed by selective field ionization (SFI). The cross section was measured as a function of velocity in the region v = 0.2 to 0.7, where the reduced velocity v is the ratio of incident-ion and orbital-electron velocities.

  3. Influence of atomic screening on fragmentation of ultrarelativistic lead ions in LHC collimators

    DEFF Research Database (Denmark)

    Baggesen, Jan C.; Sørensen, Allan H.

    2009-01-01

    ) electromagnetic dissociation dominates the fragmentation in medium to heavy target materials. Due to the extended range of the interaction at high energies, atomic screening affects the dissociation in the LHC collimators. We determine the magnitude of the reduction in cross section relative to the unscreened......When a lead beam is collimated in the CERN LHC some of the ions fragment in the collimators causing problems downstream. For design purposes the fragmentation probability needs to be assessed. At LHC energies ( γ 3000 ; the Lorentz-factor γ is the total energy of an ion in units of its rest energy...

  4. Electron capture by impact of highly partially stripped ions on hydrogen atom in low collision energies

    International Nuclear Information System (INIS)

    Based on the reaction windows of electron capture obtained by using the two-state Landau-Zener model, the electron capture processes in collision of bare ions and highly partially stripped ions with hydrogen atoms are analysed. The capture cross sections predicted by multichannel Landau-Zener method are reliable if the cross points between the initial and final diabatic potential energy curves are located in the corresponding reaction windows. The calculations by the multichannel Landau-Zener method show that the present theoretical results are in accord with the analyses for slow C3+ + H and 5+ + H collisions

  5. Investigation of energy thresholds of atomic and cluster sputtering of some elements under ion bombardment

    CERN Document Server

    Atabaev, B G; Lifanova, L F

    2002-01-01

    Threshold energies of sputtering of negative cluster ions from the Si(111) surface were measured at bombardment by Cs sup + , Rb sup + , and Na sup + ions with energy of 0.1-3.0 keV. These results are compared with the calculations of the similar thresholds by Bohdansky etc. formulas (3) for clusters Si sub n sup - and Cu sub n sup - with n=(1-5) and also for B, C, Al, Si, Fe, Cu atoms. Threshold energies of sputtering for the above elements were also estimated using the data from (5). Satisfactory agreement between the experimental and theoretical results was obtained. (author)

  6. Atom probe field ion microscopy and related topics: A bibliography 1993

    International Nuclear Information System (INIS)

    This bibliography, covering the period 1993, includes references related to the following topics: atom probe field ion microscopy (APFIM), field emission (FE), and field ion microscopy (FIM). Technique-oriented studies and applications are included. The references contained in this document were compiled from a variety of sources including computer searches and personal lists of publications. To reduce the length of this document, the references have been reduced to the minimum necessary to locate the articles. The references are listed alphabetically by authors, an Addendum of references missed in previous bibliographies is included

  7. Spin-orbit interactions and quantum spin dynamics in cold ion-atom collisions

    CERN Document Server

    Tscherbul, Timur V; Buchachenko, Alexei A

    2015-01-01

    We present accurate ab initio and quantum scattering calculations on a prototypical hybrid ion-atom system Yb$^+$-Rb, recently suggested as a promising candidate for the experimental study of open quantum systems, quantum information processing, and quantum simulation. We identify the second-oder spin-orbit (SO) interaction as the dominant source of hyperfine relaxation and decoherence in cold Yb$^+$-Rb collisions. Our results are in good agreement with recent experimental observations [L. Ratschbacher et al., Phys. Rev. Lett. 110, 160402 (2013)] of hyperfine relaxation rates of trapped Yb$^+$ immersed in an ultracold Rb gas. The calculated rates are 4 times smaller than predicted by the Langevin capture theory and display a weak $T^{-0.3}$ temperature dependence, indicating significant deviations from statistical behavior. Our analysis underscores the deleterious nature of the SO interaction and implies that light ion-atom combinations such as Yb$^+$-Li should be used to minimize hyperfine relaxation and dec...

  8. Stimulated Raman adiabatic passage for improved performance of a cold-atom electron and ion source

    Science.gov (United States)

    Sparkes, B. M.; Murphy, D.; Taylor, R. J.; Speirs, R. W.; McCulloch, A. J.; Scholten, R. E.

    2016-08-01

    We implement high-efficiency coherent excitation to a Rydberg state using stimulated Raman adiabatic passage in a cold-atom electron and ion source. We achieve an efficiency of 60% averaged over the laser excitation volume with a peak efficiency of 82%, a 1.6 times improvement relative to incoherent pulsed-laser excitation. Using pulsed electric field ionization of the Rydberg atoms we create electron bunches with durations of 250 ps. High-efficiency excitation will increase source brightness, crucial for ultrafast electron diffraction experiments, and coherent excitation to high-lying Rydberg states could allow for the reduction of internal bunch heating and the creation of a high-speed single-ion source.

  9. QED shift calculations in relativistic many-electron atoms and ions

    CERN Document Server

    Tupitsyn, I I; Safronova, M S; Shabaev, V M; Dzuba, V A

    2016-01-01

    We incorporated quantum electrodynamics (QED) corrections into the broadly-applicable high-precision relativistic method that combines configuration interaction (CI) and linearized coupled-cluster approaches. With the addition of the QED, this CI+all-order method allows one to accurately predict properties of heavy ions of particular interest to the design of precision atomic clocks and tests of fundamental physics. To evaluate the accuracy of the QED contributions and test various QED models, we incorporated four different one-electron QED potentials. We demonstrated that all of them give consistent and reliable results. For the strongly bound electrons (i.e. inner electrons of heavy atoms, or valence electrons in highly-charged ions), the nonlocal potentials are more accurate, than the local one. Results are presented for cases of particular experimental interest.

  10. Secondary electron emission from Au by medium energy atomic and molecular ions

    CERN Document Server

    Itoh, A; Obata, F; Hamamoto, Y; Yogo, A

    2002-01-01

    Number distributions of secondary electrons emitted from a Au metal surface have been measured for atomic and molecular ions of H sup + , He sup + , C sup + , N sup + , O sup + , H sup + sub 2 , H sup + sub 3 , HeH sup + , CO sup + and O sup + sub 2 in the energy range 0.3-2.0 MeV. The emission statistics obtained are described fairly well by a Polya function. The Polya parameter b, determining the distribution shape, is found to decrease monotonously with increasing emission yield gamma, revealing a surprising relationship of b gamma approx 1 over the different projectile species and impact energies. This finding supports certainly the electron cascading model. Also we find a strong negative molecular effect for heavier molecular ions, showing a significant reduction of gamma compared to the estimated values using constituent atomic projectile data.

  11. Recommended atomic data for collisional-radiative model of Li-like ions and gain calculation for Li-like Al ions in the recombining plasma

    Energy Technology Data Exchange (ETDEWEB)

    Nishikawa, T. [Okayama Univ. (Japan). Faculty of Engineering; Kawachi, T.; Nishihara, K.; Fujimoto, T.

    1995-09-01

    We have assessed atomic data for lithium-like ions for the purpose of constructing a reliable collisional-radiative model. We show several examples of the atomic data for aluminum and oxygen ions, and comparison of data from several sources is done in detail. For ions with nuclear charge z, the scaling formulas and fitting parameters, which are based on the data of oxygen ions, are presented. By use of these data, we have constructed two collisional-radiative models: the one for aluminum ions and the one for ions according to the scaling for z. The population inversion and the amplification gain of the soft x-ray laser lines in the recombining aluminum plasma are calculated for several electron temperatures. We also examine the effects of ion collisions for {Delta}n=0 transitions on the excited level populations.

  12. Atomic physics for fusion plasma spectroscopy; a soft x-ray study of molybdenum ions

    International Nuclear Information System (INIS)

    Understanding the radiative patterns of the ions of heavy atoms (Z approx-gt 18) is crucial to fusion experiments. The present thesis applies ab initio, relativistic calculations of atomic data to modeling the emission of molybdenum (Z = 42) ions in magnetically confined fusion plasmas. The models are compared to observations made in the Alcator C-Mod tokamak (Plasma Fusion Center, Massachusetts Institute of Technology), and the Frascati Tokamak Upgrade. Experimental confirmation of these models allows confidence in calculations of the total molybdenum concentration and quantitative estimates of the total power lost from the plasmas due to molybdenum line radiation. Charge states in the plasma core (Mo33+ to Mo29+) emit strong x-ray and XUV spectra which allow benchmarking of models for the spatial distribution of highly stripped molybdenum ions; the models only achieve agreement with observations when the rates of indirect ionization and recombination processes are included in the calculation of the charge state distribution of the central molybdenum ions. The total concentration of molybdenum in the core of the plasma is found, and the total power radiated from the plasma core is computed. Observations of line emission from more highly charged molybdenum ions (Mo36+ to Mo34+) are presented. open-quotes Bulkclose quotes molybdenum charge states (Mo25+ to Mo23+) emit complicated XUV spectra from a position in the plasma near C-Mod's half radius; spatial profiles of these ions' emission are analyzed. Models for the line-emission spectra of adjacent ions (Mo28+ to Mo26+) are offered, and the accuracy and limits of ab initio energy level calculations are discussed. open-quotes Edgeclose quotes charge states (Mo22+ to Mo15) extend to the last closed magnetic flux surface of the C-Mod plasma. The strongest features from these charge states are emitted in a narrow band from ∼70 Angstrom

  13. Negative hydrogen ion conversion into atoms in a plasma hydrogen target

    International Nuclear Information System (INIS)

    To verufy the feasibility of economic hydrogen plasma target and its efficiency a hydrogen plasma target for the conversion of a beam of negative ions of hydrogen isotopes to atoms has been developed and investigated experimentally. Jet of hydrogen or deuterium plasma of 1.5 m total length and 0.8 m length of a target part had approximately 4 cm in diameter. Plasma of 1013 cm-3 density and 5-6 eV electron temperature was generated at source discharge power of tens of kW at 1.5 ms pulse duration. H- ion beam of 0.3 ms pulse duration and 500 keV energy at the Van de Graaf accelerator outlet was analyzed by a magnet and collimated with a diaphragm having 0.5-1 cm aperture installed along one axis with the plasma target solenoid. After passing the target the beam was separated in a magnetic field of a bend solenoid part into three beams: H-, H0 and H+. Each beam was passed a lavsan stripping film of 3500 A thickness and in the form of a proton beam was received by the Faradey cylinder. An experimental value of atom yield is equal to 84.5+-0.5% at 500 keV H- ion energy and for a target thickness nsub(e)L=2x1015 cm-2. It is established that the plasma jet not only well screens itself from an external flow of nonionized gas but also pumps out it ionizing and carrying out to a receiving volume. A sufficiently high value of the conversion ratio of high-energy negative hydrogen ions to atoms as well as high screening and pumping out properties of the hydrogen plasma target permits to hope for its successful application in injectors of high-energy atoms

  14. K-Vacancy Production in the Collision of Highly Charged Relativistic Ions With Heavy Atoms

    OpenAIRE

    Khabibullaev, P. K.

    2000-01-01

    A general expression for the cross section of the inelastic collision of relativistic highly charged ion with heavy (relativistic) atoms is obtained using the generalized eikonal approximation. In the ultrarelativistic limit, the obtained formula coincides with a known exact one. As an application of the obtained result, probability and cross section of the K-vacany production in the U92+ - U91+ collision are calculated.

  15. On the combination of a low energy hydrogen atom beam with a cold multipole ion trap

    International Nuclear Information System (INIS)

    The first part of the activities of this thesis was to develop a sophisticated ion storage apparatus dedicated to study chemical processes with atomic hydrogen. The integration of a differentially pumped radical beam source into an existing temperature variable 22- pole trapping machine has required major modifications. Since astrophysical questions have been in the center of our interest, the introduction first gives a short overview of astrophysics and -chemistry. The basics of ion trapping in temperature variable rf traps is well-documented in the literature; therefore, the description of the basic instrument (Chapter 2) is kept rather short. Much effort has been put into the development of an intense and stable source for hydrogen atoms the kinetic energy of which can be changed. Chapter 3 describes this module in detail with emphasis on the integration of magnetic hexapoles for guiding the atoms and special treatments of the surfaces for reducing H-H recombination. Due to the unique sensitivity of the rf ion trapping technique, this instrument allows one to study a variety of reactions of astrochemical and fundamental interest. The results of this work are summarized in Chapter 4. Reactions of CO2+ with hydrogen atoms and molecules have been established as calibration standard for in situ determination of H and H2 densities over the full temperature range of the apparatus (10 K-300 K). For the first time, reactions of H- and D-atoms with the ionic hydrocarbons CH+, CH2+, and CH4+ have been studied at temperatures of interstellar space. A very interesting, not yet fully understood collision system is the interaction of protonated methane with H. The outlook presents some ideas, how to improve the new instrument and a few reaction systems are mentioned which may be studied next. (orig.)

  16. On the combination of a low energy hydrogen atom beam with a cold multipole ion trap

    Energy Technology Data Exchange (ETDEWEB)

    Borodi, Gheorghe

    2008-12-09

    The first part of the activities of this thesis was to develop a sophisticated ion storage apparatus dedicated to study chemical processes with atomic hydrogen. The integration of a differentially pumped radical beam source into an existing temperature variable 22- pole trapping machine has required major modifications. Since astrophysical questions have been in the center of our interest, the introduction first gives a short overview of astrophysics and -chemistry. The basics of ion trapping in temperature variable rf traps is well-documented in the literature; therefore, the description of the basic instrument (Chapter 2) is kept rather short. Much effort has been put into the development of an intense and stable source for hydrogen atoms the kinetic energy of which can be changed. Chapter 3 describes this module in detail with emphasis on the integration of magnetic hexapoles for guiding the atoms and special treatments of the surfaces for reducing H-H recombination. Due to the unique sensitivity of the rf ion trapping technique, this instrument allows one to study a variety of reactions of astrochemical and fundamental interest. The results of this work are summarized in Chapter 4. Reactions of CO{sub 2}{sup +} with hydrogen atoms and molecules have been established as calibration standard for in situ determination of H and H{sub 2} densities over the full temperature range of the apparatus (10 K-300 K). For the first time, reactions of H- and D-atoms with the ionic hydrocarbons CH{sup +}, CH{sub 2}{sup +}, and CH{sub 4}{sup +} have been studied at temperatures of interstellar space. A very interesting, not yet fully understood collision system is the interaction of protonated methane with H. The outlook presents some ideas, how to improve the new instrument and a few reaction systems are mentioned which may be studied next. (orig.)

  17. Adiabatic mechanism of the multiply charged ion production by a laser field through ATI states of an atom

    CERN Document Server

    Kuchiev, M Yu

    1996-01-01

    ATI can be followed by an inelastic collision of the ionized electron with the parent atomic particle resulting in an excitation of the ion. It may be a continuum state excitation producing the doubly charged ion or a discrete state which also enhances the doubly charged ion production. Absorption of a few quanta above the atomic threshold is sufficient to make this mechanism work. As a result the two-electron processes can take place even in moderate fields. The example of two-electron excitations of He atoms in a 780 nm laser field with intensity above 10^{14}W/cm^2 is discussed

  18. Multichannel quantum-defect theory for ultracold atom-ion collisions

    Science.gov (United States)

    Idziaszek, Zbigniew; Simoni, Andrea; Calarco, Tommaso; Julienne, Paul S.

    2011-08-01

    We develop an analytical model for ultracold atom-ion collisions using the multichannel quantum-defect formalism. The model is based on analytical solutions of the r-4 long-range potential and on the application of a frame transformation between asymptotic and molecular bases. This approach allows the description of atom-ion interaction in the ultracold domain in terms of only three parameters: the singlet and triplet scattering lengths, assumed to be independent of the relative motion angular momentum, and the lead dispersion coefficient of the asymptotic potential. We also introduce corrections to the scattering lengths that improve the accuracy of our quantum-defect model for higher-order partial waves, a particularly important result for an accurate description of shape and Feshbach resonances at finite temperature. The theory is applied to the system composed of a 40Ca+ ion and a Na atom, and compared with numerical coupled-channel calculations carried out using ab initio potentials. For this particular system, we investigate the spectrum of bound states, the rate of charge-transfer processes and the collision rates in the presence of magnetic Feshbach resonances at zero and finite temperature.

  19. Multichannel quantum-defect theory for ultracold atom-ion collisions

    CERN Document Server

    Idziaszek, Zbigniew; Calarco, Tommaso; Julienne, Paul S

    2011-01-01

    We develop an analytical model for ultracold atom-ion collisions using the multichannel quantum-defect formalism. The model is based on the analytical solutions of the r^-4 long-range potential and on the application of a frame transformation between asymptotic and molecular bases. This approach allows the description of the atom-ion interaction in the ultracold domain in terms of three parameters only: the singlet and triplet scattering lengths, assumed to be independent of the relative motion angular momentum, and the lead dispersion coefficient of the asymptotic potential. We also introduce corrections to the scattering lengths that improve the accuracy of our quantum-defect model for higher order partial waves, a particularly important result for an accurate description of shape and Feshbach resonances at finite temperature. The theory is applied to the system composed of a 40Ca+ ion and a Na atom, and compared to numerical coupled-channel calculations carried out using ab initio potentials. For this part...

  20. Multichannel quantum-defect theory for ultracold atom-ion collisions

    Energy Technology Data Exchange (ETDEWEB)

    Idziaszek, Zbigniew [Faculty of Physics, University of Warsaw, 00-681 Warsaw (Poland); Simoni, Andrea [Institut de Physique de Rennes, UMR 6251 du CNRS and Universite de Rennes 1, 35042 Rennes Cedex (France); Calarco, Tommaso [Institute of Quantum Information Processing, University of Ulm, D-89069 Ulm (Germany); Julienne, Paul S, E-mail: idziaszek@fuw.edu.pl [Joint Quantum Institute, NIST and the University of Maryland, Gaithersburg, MD 20899-8423 (United States)

    2011-08-15

    We develop an analytical model for ultracold atom-ion collisions using the multichannel quantum-defect formalism. The model is based on analytical solutions of the r{sup -4} long-range potential and on the application of a frame transformation between asymptotic and molecular bases. This approach allows the description of atom-ion interaction in the ultracold domain in terms of only three parameters: the singlet and triplet scattering lengths, assumed to be independent of the relative motion angular momentum, and the lead dispersion coefficient of the asymptotic potential. We also introduce corrections to the scattering lengths that improve the accuracy of our quantum-defect model for higher-order partial waves, a particularly important result for an accurate description of shape and Feshbach resonances at finite temperature. The theory is applied to the system composed of a {sup 40}Ca{sup +} ion and a Na atom, and compared with numerical coupled-channel calculations carried out using ab initio potentials. For this particular system, we investigate the spectrum of bound states, the rate of charge-transfer processes and the collision rates in the presence of magnetic Feshbach resonances at zero and finite temperature.

  1. Photon Hall Scattering from Alkaline-earth-like atoms and Alkali-like ions

    CERN Document Server

    van Tiggelen, B A

    2016-01-01

    We investigate the possibility of observing a magneto-transverse scattering of photons from alkaline-earth-like atoms as well as alkali-like ions and provide orders of magnitude. The transverse magneto-scattering is physically induced by the interference between two possible quantum transitions of an outer electron in a S-state, one dispersive electric-dipole transition to a P-orbital state and a second resonant electric-quadrupole transition to a P-orbital state. In contrast with previous mechanisms proposed for such an atomic photonic Hall effect, no real photons are scattered by the electric-dipole allowed transition, which increases the ratio of Hall current to background photons significantly. The main experimental challenge is to overcome the small detection threshold, with only 10^{-5} photons scattered per atom per second.

  2. Solar ions in the heliosheath: a possible new source of heavy neutral atoms

    CERN Document Server

    Grzedzielski, S; Bzowski, M; Izmodenov, V

    2006-01-01

    We show that multiply ionized coronal C, N, O, Mg, Si, S ions carried by the solar wind and neutralized by consecutive electron captures from neutral interstellar atoms constitute an important new source of neutral atoms in the inner heliosheath, with energies up to ~ 1 keV/n. In the model we developed, the heavy ions are treated as test particles carried by hydrodynamic plasma flow (with a Monte-Carlo description of interstellar neutrals) and undergoing all relevant atomic processes determining the evolution of all charge-states of considered species (radiative and dielectronic recombination, charge exchange, photo-, and electron impact ionization). The total strength of the source is from ~10^6 g/s for S to ~10^8 g/s for O, deposited as neutrals below the heliopause. These atoms should provide, as they drift to supersonic wind region, important sources of PUIs and eventually ACRs, especially for species that are excluded from entering the heliosphere because of their ionization in the LISM. The expected cor...

  3. A highly miniaturized vacuum package for a trapped ion atomic clock

    Science.gov (United States)

    Schwindt, Peter D. D.; Jau, Yuan-Yu; Partner, Heather; Casias, Adrian; Wagner, Adrian R.; Moorman, Matthew; Manginell, Ronald P.; Kellogg, James R.; Prestage, John D.

    2016-05-01

    We report on the development of a highly miniaturized vacuum package for use in an atomic clock utilizing trapped ytterbium-171 ions. The vacuum package is approximately 1 cm3 in size and contains a linear quadrupole RF Paul ion trap, miniature neutral Yb sources, and a non-evaporable getter pump. We describe the fabrication process for making the Yb sources and assembling the vacuum package. To prepare the vacuum package for ion trapping, it was evacuated, baked at a high temperature, and then back filled with a helium buffer gas. Once appropriate vacuum conditions were achieved in the package, it was sealed with a copper pinch-off and was subsequently pumped only by the non-evaporable getter. We demonstrated ion trapping in this vacuum package and the operation of an atomic clock, stabilizing a local oscillator to the 12.6 GHz hyperfine transition of 171Y b+. The fractional frequency stability of the clock was measured to be 2 × 10-11/τ1/2.

  4. Quantum electrodynamics tests and X-rays standards using pionic atoms and highly charged ions

    International Nuclear Information System (INIS)

    The object of this thesis is to present a new measurement of the pion mass using pionic nitrogen X-ray spectroscopy and results on helium-like argon and sulphur spectroscopy. The new pion mass has been measured with an accuracy of 1.7 ppm, 30% better that the present world average value, and it is obtained from Bragg spectroscopy of 5 ->4 pionic nitrogen transitions using the theoretical predictions provided by quantum electrodynamics. We have got: m(π-) = (139.571042 ± 0.000210 ± 0.000110) where the first error is due to the statistics and the second is the systematic error. I present the calculation of the hyperfine structure and recoil corrections for pionic atoms using a new perturbation method for the Klein-Gordon equation. The spectrometer used for this measurement has been characterized with the relativistic M1 transitions from helium-like ions produced with a new device, the Electron-Cyclotron-Resonance Ion Trap. High statistics spectra from these ions have enabled us to measure transition energies with an accuracy of some ppm which has allowed us to compare theoretical predictions with experiment data. X-ray emission from pionic atoms and multicharged ions can be used to define new types of X-ray standards for energies of a few keV

  5. Atomic layer deposition of HfO2 on graphene through controlled ion beam treatment

    Science.gov (United States)

    Kim, Ki Seok; Oh, Il-Kwon; Jung, Hanearl; Kim, Hyungjun; Yeom, Geun Young; Kim, Kyong Nam

    2016-05-01

    The polymer residue generated during the graphene transfer process to the substrate tends to cause problems (e.g., a decrease in electron mobility, unwanted doping, and non-uniform deposition of the dielectric material). In this study, by using a controllable low-energy Ar+ ion beam, we cleaned the polymer residue without damaging the graphene network. HfO2 grown by atomic layer deposition on graphene cleaned using an Ar+ ion beam showed a dense uniform structure, whereas that grown on the transferred graphene (before Ar+ ion cleaning) showed a non-uniform structure. A graphene-HfO2-metal capacitor fabricated by growing 20-nm thick HfO2 on graphene exhibited a very low leakage current (graphene, whereas a similar capacitor grown using the transferred graphene showed high leakage current.

  6. Fabrication of ion conductive tin oxide-phosphate amorphous thin films by atomic layer deposition

    International Nuclear Information System (INIS)

    This work reports the atomic layer deposition (ALD) of tin oxide-phosphate films using tetrakis(dimethylamino)tin and trimethyl phosphate as precursors. The growth rates were 1.23–1.84 Å/cycle depending upon the deposition temperature and precursor combination. The ionic conductivity of the ALD tin oxide-phosphate films was evaluated by cross-plane impedance measurements in the temperature range of 50–300 °C under atmospheric air, with the highest conductivity measured as 1.92 × 10−5 S cm−1 at 300 °C. Furthermore, high-resolution x-ray photoelectron spectroscopy exhibited two O1s peaks that were classified as two subpeaks of hydroxyl ions and oxygen ions, revealing that the quantity of hydroxyl ions in the ALD tin oxide-phosphate films influences their ionic conductivity

  7. Pair production and annihilation via nuclear resonances in atoms and ions

    Energy Technology Data Exchange (ETDEWEB)

    Belov, Nikolay A.; Harman, Zoltan [Max Planck Institute for Nuclear Physics, Heidelberg (Germany)

    2014-07-01

    Processes connected with pair production and annihilation in atoms and ions are theoretically investigated. These include nuclear excitation by resonance positron annihilation (NERPA) and nuclear-resonant e{sup -}e{sup +} pair creation in heavy ion collisions. Possible experimental schemes are put forward for the observation of these reactions. NERPA is an alternative channel of positron-matter interaction, with potential relevance in cosmic ray studies, medical positron emission tomography research, in experimental investigations of nuclear chain reactions, and in star evolution simulations. It also constitutes a novel means for the energy-selective excitation of nuclei. In heavy ion collisions, the Coulomb-excited nucleus may decay by a creation of a free-free or bound-free e{sup -}e{sup +} pair. Thus, it is an additional, resonant channel of pair creation in nucleus-nucleus collisions, an experimental investigation of which is projected at the FAIR facility.

  8. FRACTAL PATTERN GROWTH OF METAL ATOM CLUSTERS IN ION IMPLANTED POLYMERS

    Institute of Scientific and Technical Information of China (English)

    ZHANG TONG-HE; WU YU-GUANG; SANG HAI-BO; ZHOU GU

    2001-01-01

    The fractal and multi-fractal patterns of metal atoms are observed in the surface layer and cross section of a metal ion implanted polymer using TEM and SEM for the first time. The surface structure in the metal ion implanted polyethylene terephthalane (PET) is the random fractal. Certain average quantities of the random geometric patterns contain self-similarity. Some growth origins appeared in the fractal pattern which has a dimension of 1.67. The network structure of the fractal patterns is formed in cross section, having a fractal dimension of 1.87. So it can be seen that the fractal pattern is three-dimensional space fractal. We also find the collision cascade fractal in the cross section of implanted nylon, which is similar to the collision cascade pattern in transverse view calculated by the TRIM computer program. Finally, the mechanism for the formation and growth of the fractal patterns during ion implantation is discussed.

  9. Correlated electron-ion dynamics: the excitation of atomic motion by energetic electrons

    International Nuclear Information System (INIS)

    Correlated electron-ion dynamics (CEID) is an extension of molecular dynamics that allows us to introduce in a correct manner the exchange of energy between electrons and ions. The formalism is based on a systematic approximation: small amplitude moment expansion. This formalism is extended here to include the explicit quantum spread of the ions and a generalization of the Hartree-Fock approximation for incoherent sums of Slater determinants. We demonstrate that the resultant dynamical equations reproduce analytically the selection rules for inelastic electron-phonon scattering from perturbation theory, which control the mutually driven excitations of the two interacting subsystems. We then use CEID to make direct numerical simulations of inelastic current-voltage spectroscopy in atomic wires, and to exhibit the crossover from ionic cooling to heating as a function of the relative degree of excitation of the electronic and ionic subsystems

  10. Atoms

    Institute of Scientific and Technical Information of China (English)

    刘洪毓

    2007-01-01

    Atoms(原子)are all around us.They are something like the bricks (砖块)of which everything is made. The size of an atom is very,very small.In just one grain of salt are held millions of atoms. Atoms are very important.The way one object acts depends on what

  11. Theoretical Calculation of Absolute Radii of Atoms and Ions. Part 2. The Ionic Radii

    Directory of Open Access Journals (Sweden)

    Raka Biswas

    2003-05-01

    Full Text Available Abstract: The theoretical method of determination of absolute atomic size, discussed in Int. J. Mol. Sci. 2002, 3, 87-113, is exploited to calculate absolute radii of the ions whose experimental radii are published by Shanon. The computed radii are found to reproduce the expected periodic variation of size in periods and in groups and nicely reproduce the d-block and f-block contractions in the respective series. It is pointed out that experimental radii of d and f block transition metal ions make erroneous and misleading representation of the size behaviour of the respective series. A detailed comparative study of the crystal radii vis-à-vis the theoretical radii is reported. A rationale of the double hump curve of the experimental radii of 3 d-block transition metal ions is put forward in terms of the crystal field theory and Jahn-Teller distortion. The theoretical radii are exploited to calculate the diamagnetic susceptibility, polarizability and chemical hardness of the ions and compared with available experimental data. The fact of good agreement between the experimental and computed global hardness of ions and correct demonstration of d-block and f-block contraction by the computed radii are used as benchmark to test the validity of the values of the computed theoretical radii of the ions as their representative sizes. It is concluded that the theoretically computed radii of ions are visualizable size representation of ions and can be used as their absolute radii at the respective oxidation states.

  12. Selective population of ground terms in /sup 14/N atoms after ion-beam--surface interaction at grazing incidence

    Energy Technology Data Exchange (ETDEWEB)

    Winter, H.; Langheim, M.; Schirmacher, A.; Zimny, R.; Andra, H.J.

    1984-04-02

    The orientation of angular momenta in the ground terms of /sup 14/N atoms after the interaction of 350-keV /sup 14/N/sup +/ ions with a solid surface at grazing incidence is investigated by a Zeeman quantum-beat technique. After the ion-solid interaction, a term-selective and highly polarized fast beam of nitrogen atoms is observed. The phenomenon is interpreted in terms of a Pauli-principle--induced selective population.

  13. Tunnel and multiphoton ionization of atoms and ions in a strong laser field (Keldysh theory)

    International Nuclear Information System (INIS)

    The theoretical description of the nonlinear photoionization of atoms and ions exposed to high-intensity laser radiation is underlain by the Keldysh theory proposed in 1964. The paper reviews this theory and its further development. The discussion is concerned with the energy and angular photoelectron distributions for the cases of linearly, circularly, and elliptically polarized laser radiation, with the ionization rate of atomic states exposed to a monochromatic electromagnetic wave and to ultrashort laser pulses of various shape, and with momentum and angular photoelectron spectra in these cases. The limiting cases of tunnel (γ || 1) and multiphoton (γ >> 1) ionization are discussed, where c is the adiabaticity parameter, or the Keldysh parameter. The probability of above-barrier ionization is calculated for hydrogen atoms in a low-frequency laser field. The effect of a strong magnetic field on the ionization probability is discussed. The process of Lorentz ionization occurring in the motion of atoms and ions in a constant magnetic field is considered. The properties of an exactly solvable model-the ionization of an s-level bound by zero-range forces in the field of a circularly polarized electromagnetic wave-are described. In connection with this example, the Zel'dovich regularization method in the theory of quasistationary states is discussed. Results of the Keldysh theory are compared with experiment. A brief discussion is made of the relativistic ionization theory applicable when the binding energy of the atomic level is comparable with the electron rest mass (multiply charged ions) and the sub-barrier electron motion can no longer be considered to be nonrelativistic. A similar process of electron-positron pair production from a vacuum by the field of high-power optical or X-ray lasers (the Schwinger effect) is considered. The calculations invoke the method of imaginary time, which provides a convenient and physically clear way of calculating the

  14. Status of Charge Exchange Cross Section Measurements for Highly Charged Ions on Atomic Hydrogen

    Science.gov (United States)

    Draganic, I. N.; Havener, C. C.; Schultz, D. R.; Seely, D. G.; Schultz, P. C.

    2011-05-01

    Total cross sections of charge exchange (CX) for C5+, N6+, and O7+ ions on ground state atomic hydrogen are measured in an extended collision energy range of 1 - 20,000 eV/u. Absolute CX measurements are performed using an improved merged-beams technique with intense highly charged ion beams extracted from a 14.5 GHz ECR ion source mounted on a high voltage platform. In order to improve the problematic H+ signal collection for these exoergic CX collisions at low relative energies, a new double focusing electrostatic analyzer was installed. Experimental CX data are in good agreement with all previous H-oven relative measurements at higher collision energies. We compare our results with the most recent molecular orbital close-coupling (MOCC) and atomic orbital close-coupling (AOCC) theoretical calculations. Work supported by the NASA Solar & Heliospheric Physics Program NNH07ZDA001N, the Office of Fusion Energy Sciences and the Division of Chemical Sciences, Geosciences, and Biosciences, and the Office of Basic Energy Sciences of the U.S. DoE.

  15. The development of the high intensity electron cyclotron resonance ion source at China Institute of Atomic Energy.

    Science.gov (United States)

    Tang, B; Ma, R; Ma, Y; Chen, L; Huang, Q; Liang, H; Cui, B; Jiang, W

    2014-02-01

    High-current microwave ion source has been under development over 15 years for accelerator driven sub-critical system research at China Institute of Atomic Energy, and the beam intensity higher than 140 mA proton beam is produced by this ion source with long lifetime and high reliability. The emittance of high intensity continue-wave and pulse beam is measured on a test-bench in the laboratory. Based on the good performance of this proton ion source, a new 120 mA deuterium ion source is proposed for a high intensity neutron generator. The ion source details and status will be presented. PMID:24593490

  16. Present and future directions of atomic physics research with multiply-charged ions at Brookhaven National Laboratory

    International Nuclear Information System (INIS)

    Atomic physics research with multiply-charged ions is now in progress using ion beams from the Brookhaven Double MP-Tandem van de Graaff facility. In the near future, experiments will start using ions produced by photons from the National Synchrotron Light Source (NSLS). Examples of typical experiments are discussed to illustrate the comprehensive nature of these facilities. Plans for future expansion by addition of a CRYEBIS type ion source coupled to a heavy-ion storage ring for use in crossed-beam experiments at the NSLS are discussed. 18 refs., 8 figs

  17. Collisional transfer of electrons to the continuum of atomic and molecular ions

    International Nuclear Information System (INIS)

    The aim of this study was the systematic investigation of the differences that appear in the peaks of distribution of doubly differential (in angle an energy) 'convoy' electrons, when comparing spectra obtained by bombarding thin carbon foils with atomic (H+) and molecular (H2+) projectiles of equal velocity. The measurements show that the production yield of such electrons is inversely propotional to the ion dwell time in the solid. For long times, the yield ratio fluctuates around the unity value, and the amplitude of this dispersion decreases for longer times. A higher yield is measured for (H2+), but only near the peak cusp. The double differential cross section (DDCS) for electron capture is calculated in second order Born approximation. A transition from a 1s state to the continuum of two correlated protons as a function of their internuclear distance R is considered. As R decreases from approx. 0.5 atomic units towards zero, the DDCS value increases from that corresponding to the atomic projectil (Z=1) limit to the united atom value (Z=2). It is found that, the higher the projectil velocity, the better is the DDCS value agreement with both limits. The equipment used by the author is described. (M.E.L.)

  18. Investigation of the intermediate LK molecular orbital radiation in heavy ion-atom collisions

    International Nuclear Information System (INIS)

    The continuum consisting of an intensive low-energy and a high-energy components in heavy-ion atom collision systems with atomic numbers Z1, Z2 > 28 is studied. The aim of the study is to prove that the C1 continuum cannot be caused by ridiative electron capture (REC) being molecular orbital (MO) radiation to the 2ptau level. It is shown that the comparison of the C1 yields obtained in Kr+Nb asymmetric collisions in gas and solid targets is associated with the formation of vacancies in the lower-Z collision partner and can be interpreted as quasimolecular radiation to the 2ptau orbital level. The strong suppression of the C2 component in the gas target experimets indicates that the MO radiation to the 1stau orbit is emitted preferentially in the two-collision process in symmetric and near-symmetric systems with Z1, Z2 <= 41

  19. Atomic physics studies of highly charged ions on tokamaks using x-ray spectroscopy

    International Nuclear Information System (INIS)

    An overview is given of atomic physics issues which have been studied on tokamaks with the help resolution x-ray spectroscopy. The issues include the testing of model calculations predicting the excitation of line radiation, the determination of rate coefficients, and accurate atomic structure measurements. Recent research has focussed primarily on highly charged heliumlike (22 ≤ Z ≤ 28) and neonlike (34 ≤ Z ≤ 63) ions, and results are presented from measurements on the PLT and TFTR tokamaks. Many of the measurements have been aided by improved instrumental design and new measuring techniques. Remarkable agreement has been found between measurements and theory in most cases. However, in this review those areas are stressed where agreement is worst and where further investigations are needed. 19 refs., 13 figs., 2 tabs

  20. Charge exchange transition probability for collisions between unlike ions and atoms within the adiabatic approximation

    Science.gov (United States)

    Xu, Y. J.; Khandelwal, G. S.; Wilson, John W.

    1989-01-01

    A simple formula for the transition probability for electron exchange between unlike ions and atoms is established within the adiabatic approximation by employing the Linear Combination of Atomic Orbitals (LCAO) method. The formula also involves an adiabatic parameter, introduced by Massey, and thus the difficulties arising from the internal energy defect and the adiabatic approximation are avoided. Specific reactions Li(+++) + H to Li(++) + H(+) and Be(4+) + H to Be(3+) + H(+) are considered as examples. The calculated capture cross section results of the present work are compared with the experimental data and with the calculation of other authors over the velocity range of 10(7) cm/sec to 10(8) cm/sec.

  1. Ionization and charge transfer in high-energy ion-atom collisions

    International Nuclear Information System (INIS)

    Electron capture and loss by fast highly charged ions in a gas target, and ionization of the target by passage of the fast projectile beam, are fundamental processes in atomic physics. These processes, along with excitation, can be experimentally studied separately (''singles'') or together (''coincidence''). This paper is a review of recent results on singles measurements for electron capture and loss and for target ionization, for velocities which are generally high relative to the active electron, including recent ionization measurements for a nearly relativistic projectile. 11 refs., 6 figs

  2. Electron collisions with atoms, ions, molecules, and surfaces: Fundamental science empowering advances in technology

    Science.gov (United States)

    Bartschat, Klaus; Kushner, Mark J.

    2016-06-01

    Electron collisions with atoms, ions, molecules, and surfaces are critically important to the understanding and modeling of low-temperature plasmas (LTPs), and so in the development of technologies based on LTPs. Recent progress in obtaining experimental benchmark data and the development of highly sophisticated computational methods is highlighted. With the cesium-based diode-pumped alkali laser and remote plasma etching of Si3N4 as examples, we demonstrate how accurate and comprehensive datasets for electron collisions enable complex modeling of plasma-using technologies that empower our high-technology-based society.

  3. Distorted wave theories for dressed-ion-atom collisions with GSZ projectile potentials

    Energy Technology Data Exchange (ETDEWEB)

    Monti, J M; Rivarola, R D [Instituto de Fisica Rosario (CONICET-UNR) and Facultad de Ciencias Exactas, IngenierIa y Agrimensura, Universidad Nacional de Rosario, Avenida Pellegrini 250, 2000 Rosario (Argentina); Fainstein, P D, E-mail: monti@ifir-conicet.gov.ar [Comision Nacional de EnergIa Atomica, Centro Atomico Bariloche, 8400 San Carlos de Bariloche (Argentina)

    2011-10-14

    The continuum distorted wave and the continuum distorted wave-eikonal initial state approximations for electron emission in ion-atom collisions are generalized to the case of dressed projectiles. The interaction between the dressed projectile and the active electron is represented by the analytic Green-Sellin-Zachor (GSZ) potential. Doubly differential cross sections as a function of the emitted electron energy and angle are computed. The region of the binary encounter peak is analysed in detail. Interference structures appear in agreement with the experimental data and are interpreted as arising from the coherent interference between short- and long-range scattering amplitudes.

  4. Some theoretical aspects of the group-IIIA-ion atomic clocks: Intercombination transition probabilities

    International Nuclear Information System (INIS)

    The main focus of this paper is the theoretical study of the 3P1→1S0 intercombination transition probabilities of the group-IIIA ions that are excellent candidates for high-accuracy atomic clocks. The importance of relativistic effects on the intercombination transition probabilities is made apparent by comparing their calculated values with those of the allowed 1P1→1S0 transition probabilities. In striking contrast to the allowed transition probabilities, the intercombination transition probabilities exhibit a strong Z dependence

  5. Progress towards precision measurements of beta-decay correlation parameters using atom and ion traps

    CERN Document Server

    Melconian, D; Fenker, B; Mehlman, M; Shidling, P D; Anholm, M; Ashery, D; Behr, J A; Gorelov, A; Gwinner, G; Olchankski, K; Smale, S

    2014-01-01

    The correlations of the decay products following the beta decay of nuclei have a long history of providing a low-energy probe of the fundamental symmetries of our universe. Over half a century ago, the correlation of the electrons following the decay of polarized 60Co demonstrated that parity is not conserved in weak interactions. Today, the same basic idea continues to be applied to search for physics beyond the standard model: make precision measurements of correlation parameters and look for deviations compared to their standard model predictions. Efforts to measure these parameters to the 0.1% level utilizing atom and ion trapping techniques are described.

  6. Electron collisions with atoms, ions, molecules, and surfaces: Fundamental science empowering advances in technology.

    Science.gov (United States)

    Bartschat, Klaus; Kushner, Mark J

    2016-06-28

    Electron collisions with atoms, ions, molecules, and surfaces are critically important to the understanding and modeling of low-temperature plasmas (LTPs), and so in the development of technologies based on LTPs. Recent progress in obtaining experimental benchmark data and the development of highly sophisticated computational methods is highlighted. With the cesium-based diode-pumped alkali laser and remote plasma etching of Si3N4 as examples, we demonstrate how accurate and comprehensive datasets for electron collisions enable complex modeling of plasma-using technologies that empower our high-technology-based society. PMID:27317740

  7. Electron capture and ionization for ion-Rydberg atom collisions in a magnetic field

    International Nuclear Information System (INIS)

    Within the classical trajectory Monte Carlo (CTMC) model, we calculate electron transfer and ionization cross sections for 1.3-130 eV amu-1 singly charged ions colliding with Rydberg atoms in the presence of a laboratory-strength magnetic field of 4 tesla. A new method for generating a stationary microcanonical ensemble for a quasi-integrable initial-state Hamiltonian is presented. The calculated cross sections show signatures of electron capture and ionization mechanisms for the field-free case, e.g. multiple swaps and saddle-point electrons; their structure as well as their magnitude, however, are strongly modified by the presence of the magnetic field. (Author)

  8. δ-electron spectroscopy and the atomic clock effect in heavy-ion collisions

    International Nuclear Information System (INIS)

    The properties of strongly bound electrons in superheavy quasimolecular systems with combined nuclear charge numbers Z = ZP + ZT ≥ 110 are investigated. The emission of δ-electrons may serve as an atomic clock for nuclear reactions which is associated with the large overlap of the electron probability density with the nuclear interior. Excitation and emission rates of inner-shell electrons in collisions of very heavy ions with beam energies at or above the nuclear Coulomb barrier depend explicitly on details of the nuclear dynamics. Theoretical and experimental results are reviewed. (orig.)

  9. ANALYSIS OF VARIOUS METAL IONS IN SOME MEDICINAL PLANTS USING ATOMIC ABSORPTION SPECTROPHOTOMETER

    Directory of Open Access Journals (Sweden)

    Y.L. Ramachandra*, C. Ashajyothi and Padmalatha S. Rai

    2012-07-01

    Full Text Available Metal ions such as iron , lead, copper, nickel, cadmium , chromium and zinc were investigated in medicinally important plants Alstonia scholaris, Tabernaemontana coronariae, Asparagus racemosus, Mimosa pudica, Leucas aspera and Adhatoda vasica applying atomic absorption spectrophotometer techniques. The purpose of this study was to standardize various metal ion Contamination in indigenous medicinal plants. Maximum concentration of lead was present in Leucas aspera and Adhatoda vasica followed by Alstonia scholaris, Tabernaemontana coronariae and Asparagus racemosus. The concentration of lead in Mimosa pudica was below the detectable level. The maximum concentration of zinc was detected in Adhatoda vasica followed by Leucas aspera, Asparagus racemosus, Tabernaemontana coronariae, Alstonia scholaris and Mimosa pudica. The concentration of Cadmium, nickel and chromium was below the detectable level.

  10. Collective processes in heavy-ion collisions with atomic nuclei. Dissipation of energy and angular momentum

    International Nuclear Information System (INIS)

    The collective processes in collision of heavy-ions with atomic nuclei are discussed. Measured data on the S+Ti collision at Esub(LAB)=105, 130 and 144 MeV have been analysed in terms of a ''fission-like'' processes which seem to be a special case of deep inelastic collisions whose total available kinetic energy is completely dissipated. Applying transport theory it was possible to introduce a ''clock'' for measuring the time scale of nuclear processes in collision of heavy-ions by measuring the FWHM of mass distribution of emitted reaction products. Experimental data on continuum gamma spectra from Cu+Au collision at Esub(LAB)=400 MeV are presented and the angular momentum dissipation in this reaction is discussed. (author)

  11. Formation of oxides and segregation of mobile atoms during SIMS profiling of Si with oxygen ions

    Energy Technology Data Exchange (ETDEWEB)

    Petravic, M.; Williams, J.S.; Svensson, B.G.; Conway, M. [Australian National Univ., Canberra, ACT (Australia). Research School of Physical Sciences

    1993-12-31

    An oxygen beam is commonly used in secondary ion mass spectroscopy (SIMS) analysis to enhance the ionization probability for positive secondary ions. It has been observed, however, that this technique produces in some cases a great degradation of depth resolution. The most pronounced effects have been found for impurities in silicon under oxygen bombardment at angles of incidence smaller than {approx} 30 deg from the surface normal. A new approach is described which involved broadening of SIMS profiles for some mobile atoms, such as Cu, Ni and Au, implanted into silicon. The anomalously large broadening is explained in terms of segregation at a SiO{sub 2}/Si interface formed during bombardment with oxygen at impact angles less than 30 deg. 2 refs., 1 tab., 4 figs.

  12. A fully relativistic approach for calculating atomic data for highly charged ions

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Hong Lin [Los Alamos National Laboratory; Fontes, Christopher J [Los Alamos National Laboratory; Sampson, Douglas H [PENNSYLVANIA STATE UNIV

    2009-01-01

    We present a review of our fully relativistic approach to calculating atomic data for highly charged ions, highlighting a research effort that spans twenty years. Detailed discussions of both theoretical and numerical techniques are provided. Our basic approach is expected to provide accurate results for ions that range from approximately half ionized to fully stripped. Options for improving the accuracy and range of validity of this approach are also discussed. In developing numerical methods for calculating data within this framework, considerable emphasis is placed on techniques that are robust and efficient. A variety of fundamental processes are considered including: photoexcitation, electron-impact excitation, electron-impact ionization, autoionization, electron capture, photoionization and photorecombination. Resonance contributions to a variety of these processes are also considered, including discussions of autoionization, electron capture and dielectronic recombination. Ample numerical examples are provided in order to illustrate the approach and to demonstrate its usefulness in providing data for large-scale plasma modeling.

  13. Coating and functionalization of high density ion track structures by atomic layer deposition

    Science.gov (United States)

    Mättö, Laura; Szilágyi, Imre M.; Laitinen, Mikko; Ritala, Mikko; Leskelä, Markku; Sajavaara, Timo

    2016-10-01

    In this study flexible TiO2 coated porous Kapton membranes are presented having electron multiplication properties. 800 nm crossing pores were fabricated into 50 μm thick Kapton membranes using ion track technology and chemical etching. Consecutively, 50 nm TiO2 films were deposited into the pores of the Kapton membranes by atomic layer deposition using Ti(iOPr)4 and water as precursors at 250 °C. The TiO2 films and coated membranes were studied by scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray reflectometry (XRR). Au metal electrode fabrication onto both sides of the coated foils was achieved by electron beam evaporation. The electron multipliers were obtained by joining two coated membranes separated by a conductive spacer. The results show that electron multiplication can be achieved using ALD-coated flexible ion track polymer foils.

  14. Near-threshold photoionization of hydrogenlike uranium studied in ion-atom collisions via the time-reversed process.

    Science.gov (United States)

    Stöhlker, T; Ma, X; Ludziejewski, T; Beyer, H F; Bosch, F; Brinzanescu, O; Dunford, R W; Eichler, J; Hagmann, S; Ichihara, A; Kozhuharov, C; Krämer, A; Liesen, D; Mokler, P H; Stachura, Z; Swiat, P; Warczak, A

    2001-02-01

    Radiative electron capture, the time-reversed photoionization process occurring in ion-atom collisions, provides presently the only access to photoionization studies for very highly charged ions. By applying the deceleration mode of the ESR storage ring, we studied this process in low-energy collisions of bare uranium ions with low- Z target atoms. This technique allows us to extend the current information about photoionization to much lower energies than those accessible for neutral heavy elements in the direct reaction channel. The results prove that for high- Z systems, higher-order multipole contributions and magnetic corrections persist even at energies close to the threshold.

  15. Atomic data and theoretical X-ray spectra of Ge-like through V-like W ions

    International Nuclear Information System (INIS)

    The atomic structure and spectra of ten tungsten ions have been calculated using the Flexible Atomic Code. The calculations yield energy levels, radiative lifetimes, spectral line positions, transition probability rates, and oscillator strengths for the tungsten ions isoelectronic to germanium, W42+, through vanadium, W51+. Collisional–radiative models for high-temperature, low-density plasmas have been implemented to produce line emissivities for X-ray transitions in the 1–4 keV (3–12 Å) spectral interval. The Ge-like through V-like W ions are important in nuclear fusion research where their spectra may provide diagnostic information on magnetically confined plasmas

  16. Atomic data and theoretical X-ray spectra of Ge-like through V-like W ions

    Science.gov (United States)

    Clementson, J.; Beiersdorfer, P.; Brage, T.; Gu, M. F.

    2014-03-01

    The atomic structure and spectra of ten tungsten ions have been calculated using the Flexible Atomic Code. The calculations yield energy levels, radiative lifetimes, spectral line positions, transition probability rates, and oscillator strengths for the tungsten ions isoelectronic to germanium, W42, through vanadium, W51. Collisional-radiative models for high-temperature, low-density plasmas have been implemented to produce line emissivities for X-ray transitions in the 1-4 keV (3-12 Å) spectral interval. The Ge-like through V-like W ions are important in nuclear fusion research where their spectra may provide diagnostic information on magnetically confined plasmas.

  17. Near-threshold photoionization of hydrogenlike uranium studied in ion-atom collisions via the time-reversed process.

    Science.gov (United States)

    Stöhlker, T; Ma, X; Ludziejewski, T; Beyer, H F; Bosch, F; Brinzanescu, O; Dunford, R W; Eichler, J; Hagmann, S; Ichihara, A; Kozhuharov, C; Krämer, A; Liesen, D; Mokler, P H; Stachura, Z; Swiat, P; Warczak, A

    2001-02-01

    Radiative electron capture, the time-reversed photoionization process occurring in ion-atom collisions, provides presently the only access to photoionization studies for very highly charged ions. By applying the deceleration mode of the ESR storage ring, we studied this process in low-energy collisions of bare uranium ions with low- Z target atoms. This technique allows us to extend the current information about photoionization to much lower energies than those accessible for neutral heavy elements in the direct reaction channel. The results prove that for high- Z systems, higher-order multipole contributions and magnetic corrections persist even at energies close to the threshold. PMID:11177990

  18. Atomic spectroscopy on fusion relevant ions and studies of light impurities in the JET tokamak

    Energy Technology Data Exchange (ETDEWEB)

    Tunklev, M

    1999-03-01

    The spectrum and energy levels of C IV and the 3l-4l system of the Mg-like ions in the iron group elements have been investigated. This has led to several hundred identified transitions, many of them previously unknown. Using the Charge Exchange Diagnostic system at JET, ion temperatures, rotation velocities and densities have been derived from visible spectroscopic measurements on fully ionised light impurities, such as He, C, N and Ne. The existence of plume contribution from beam produced hydrogen-like ions has been proven beyond any doubt to affect the deduction of the active charge exchange signal of He II. In the case of C VI the plume signal was estimated to be at least a factor of five lower than the active charge exchange signal. Line integrated passive charge exchange emission between neutral background atoms and fully stripped impurity ions has been investigated and modelled. When the synthetic spectrum is fitted into the experimentally detected spectra the neutral background density can be deduced. The importance of including background atoms (H, D and T) as charge exchange donors, not only in state 2s, but also in state 1s, has shown to be crucial in high temperature shots. Transport of light impurities has been studied with gas puff injections into steady state H-mode plasmas. The results suggest that light impurities are transported as described by the neo-classical Pfirsch-Schlueter regime at the edge, whilst in the centre, sawtoothing, preferably to Banana transport, is mixing the plasma and increases the measured values on the diffusion. For the peaking of impurities in a steady state plasma an anomalous treatment was more in agreement with the experimental data. Certain confinement information, previously predicted theoretically as a part of the peaking equation, has been experimentally verified

  19. Cross sections for medium energy He ions scattered from Hf and Au atoms

    Energy Technology Data Exchange (ETDEWEB)

    Nishimura, Tomoaki, E-mail: t-nishi@hosei.ac.jp [Research Center of Ion Beam Technology and College of Engineering, Hosei University, Koganei, Tokyo 184-8584 (Japan); Mitsuhara, Kei; Visikovskiy, Anton; Kido, Yoshiaki [Department of Physics, Ritsumeikan University, Kusatsu, Shiga-ken 525-8577 (Japan)

    2012-06-01

    The elastic scattering cross sections for medium energy He ions incident on Ni, Hf and Au atoms were measured precisely using a toroidal electrostatic analyzer. We prepared the targets of Ni({approx}1 nm)/HfO{sub 2}(1.5 nm)/Si(0 0 1) and Ni({approx}1 nm)/Au({approx}0.5 nm)/Si(1 1 1) and performed in situ ion scattering measurement under ultrahigh vacuum condition. The absolute amounts of Ni, Hf and Au were determined by Rutherford backscattering using 1.5 MeV He ions at a scattering angle of 150 Degree-Sign . The scattering cross sections for Hf and Au were normalized by those for Ni to avoid the ambiguities of the number of incident particles, solid angle subtended by a detector, detection efficiency and the He{sup +} fractions for the emerging He ions from the surfaces. The results obtained are compared with the simple Lee-Hart formula and the calculated values using the Moliere and ZBL potentials and the potentials derived from the Hartree-Fock-Slater wave functions.

  20. Heavy coronal ions in the heliosphere. II. Expected fluxes of energetic neutral He atoms from the heliosheath

    CERN Document Server

    Grzedzielski, S; Bzowski, M

    2012-01-01

    Aims. A model of heliosheath density and energy spectra of alpha-particles and He+ ions carried by the solar wind is developed. Neutralization of heliosheath He+ ions, mainly by charge exchange (CX) with neutral interstellar H and He atoms, gives rise to ~0.2 - ~100 keV fluxes of energetic neutral He atoms (He ENA). Such fluxes, if observed, would give information about plasmas in the heliosheath and heliospheric tail. Methods. Helium ions crossing the termination shock (TS) constitute suprathermal (test) particles convected by (locally also diffusing through) hydrodynamically calculated background plasma flows (three versions of flows are employed). The He ions proceed from the TS towards heliopause (HP) and finally to the heliospheric tail (HT). Calculations of the evolution of alpha- and He+ particle densities and energy spectra include binary interactions with background plasma and interstellar atoms, adiabatic heating (cooling) resulting from flow compression (rarefaction), and Coulomb scattering on back...

  1. The Kansas State atomic collision physics facility dedicated to the studies of atomic interactions of highly charged, low and medium energy ions

    International Nuclear Information System (INIS)

    We discuss our facility at Kansas State University, which is perfectly suited for studies of atomic collisions involving highly charged, low and medium energy ions. It should be fully operational by next year and will be operated as a user facility. We encourage collaborations with in-house researchers, because it facilitates communications and experiments. 13 refs., 3 figs

  2. Synergistic oxygen atom transfer by ruthenium complexes with non-redox metal ions.

    Science.gov (United States)

    Lv, Zhanao; Zheng, Wenrui; Chen, Zhuqi; Tang, Zhiming; Mo, Wanling; Yin, Guochuan

    2016-07-28

    Non-redox metal ions can affect the reactivity of active redox metal ions in versatile biological and heterogeneous oxidation processes; however, the intrinsic roles of these non-redox ions still remain elusive. This work demonstrates the first example of the use of non-redox metal ions as Lewis acids to sharply improve the catalytic oxygen atom transfer efficiency of a ruthenium complex bearing the classic 2,2'-bipyridine ligand. In the absence of Lewis acid, the oxidation of ruthenium(ii) complex by PhI(OAc)2 generates the Ru(iv)[double bond, length as m-dash]O species, which is very sluggish for olefin epoxidation. When Ru(bpy)2Cl2 was tested as a catalyst alone, only 21.2% of cyclooctene was converted, and the yield of 1,2-epoxycyclooctane was only 6.7%. As evidenced by electronic absorption spectra and EPR studies, both the oxidation of Ru(ii) by PhI(OAc)2 and the reduction of Ru(iv)[double bond, length as m-dash]O by olefin are kinetically slow. However, adding non-redox metal ions such as Al(iii) can sharply improve the oxygen transfer efficiency of the catalyst to 100% conversion with 89.9% yield of epoxide under identical conditions. Through various spectroscopic characterizations, an adduct of Ru(iv)[double bond, length as m-dash]O with Al(iii), Ru(iv)[double bond, length as m-dash]O/Al(iii), was proposed to serve as the active species for epoxidation, which in turn generated a Ru(iii)-O-Ru(iii) dimer as the reduced form. In particular, both the oxygen transfer from Ru(iv)[double bond, length as m-dash]O/Al(iii) to olefin and the oxidation of Ru(iii)-O-Ru(iii) back to the active Ru(iv)[double bond, length as m-dash]O/Al(iii) species in the catalytic cycle can be remarkably accelerated by adding a non-redox metal, such as Al(iii). These results have important implications for the role played by non-redox metal ions in catalytic oxidation at redox metal centers as well as for the understanding of the redox mechanism of ruthenium catalysts in the oxygen atom

  3. A Radiative Cycle with Stimulated Emission from Atoms (Ions) in an astrophysical Plasma

    CERN Document Server

    Johansson, S

    2003-01-01

    We propose that a radiative cycle operates in atoms (ions) located in a rarefied gas in the vicinity of a hot star. Besides spontaneous transitions the cycle includes a stimulated transition in one very weak intermediate channel. This radiative "bottle neck" creates a population inversion, which for an appropriate column density results in amplification and stimulated radiation in the weak transition. The stimulated emission opens a fast decay channel leading to a fast radiative cycle in the atom (or ion). We apply this model by explaining two unusually bright Fe II lines at 250.7 and 250.9 nm in the UV spectrum of gas blobs close to h Carinae, one of the most massive and luminous stars in the Galaxy. The gas blobs are spatially resolved from the central star by the Hubble Space Telescope (HST). We also suggest that in the frame of a radiative cycle stimulated emission is a key phenomenon behind many spectral lines showing anomalous intensities in spectra of gas blobs outside eruptive stars.

  4. Ground-based Investigations of Atomic Oxygen Erosion Behaviors of Silver and Ion-implanted Silver

    Institute of Scientific and Technical Information of China (English)

    DUO Shu-wang; LI Mei-shuan; YIN Xiao-hui; LI Wen-kui; LI Ming-sheng

    2006-01-01

    Silver foils and ion-implanted silver foils exposed to atomic oxygen (AO) generated in a ground simulation facility were investigated by the quartz crystal microbalance (QCM), the scanning electron microscopy (SEM) and the X-ray photoelectron spectroscopy (XPS). The experimental results show the presence of Ag2O and AgO in an oxidation process of the silver foil having exposure to AO. As soon as silver comes under the bombardment of atomic oxygen, the oxidation process starts with a thick film forming on the silver surface. Because of the development of stresses, the oxide layer gets cracked and spalled, which leads to appearance of a new silver surface intensifying further oxidation. At last, AgO begins to form on the outer surface of the oxide film. The analytical results of the XPS and the AES attest to formation of a continuous high-quality protective oxide-based layer on the surface of ion-implanted silver films after exposure to AO. This layer can well protect materials in question from erosion.

  5. Mixing of Cr and Si atoms induced by noble gas ions irradiation of Cr/Si bilayers

    Energy Technology Data Exchange (ETDEWEB)

    Tobbeche, S., E-mail: said_tobbeche@yahoo.com [Faculte des Sciences, Universite El-Hadj Lakhdar, Batna 05000 (Algeria); Boukhari, A. [Faculte des Sciences, Universite El-Hadj Lakhdar, Batna 05000 (Algeria); Khalfaoui, R. [Faculte des Sciences, Universite M. Bougara, Boumerdes 35000 (Algeria); Amokrane, A. [Faculte de Physique, USTHB, B.P. 32 El-Alia, Bab-Ezzouar 16111 (Algeria); Ecole Nationale Preparatoire aux Etudes d' Ingeniorat, Route Nationale, Rouiba (Algeria); Benazzouz, C.; Guittoum, A. [Centre de Recherche Nucleaire d' Alger, 02, Boulevard Frantz Fanon, B.P. 399 Alger-Gare (Algeria)

    2011-12-15

    Cr/Si bilayers were irradiated at room temperature with 120 keV Ar, 140 keV Kr and 350 keV Xe ions to fluences ranging from 10{sup 15} to 2 Multiplication-Sign 10{sup 16} ions/cm{sup 2}. The thickness of Cr layer evaporated on Si substrate was about 400 A. Rutherford backscattering spectrometry (RBS) was used to investigate the atomic mixing induced at the Cr-Si interface as function of the incident ion mass and fluence. We observed that for the samples irradiated with Ar ions, RBS yields from both Cr layer and Si substrate are the same as before the irradiation. There is no mixing of Cr and Si atoms, even at the fluence of 2 Multiplication-Sign 10{sup 16} ions/cm{sup 2}. For the samples irradiated with Kr ions, a slight broadening of the Cr and Si interfacial edges was produced from the fluence of 5 Multiplication-Sign 10{sup 15} ions/cm{sup 2}. The broadening of the Cr and Si interfacial edges is more pronounced with Xe ions particularly to the fluence of 10{sup 16} ions/cm{sup 2}. The interface broadening was found to depend linearly on the ion fluence and suggests that the mixing is like a diffusion controlled process. The experimental mixing rates were determined and compared with values predicted by ballistic and thermal spike models. Our experimental data were well reproduced by the thermal spikes model.

  6. Mixing of Cr and Si atoms induced by noble gas ions irradiation of Cr/Si bilayers

    International Nuclear Information System (INIS)

    Cr/Si bilayers were irradiated at room temperature with 120 keV Ar, 140 keV Kr and 350 keV Xe ions to fluences ranging from 1015 to 2 × 1016 ions/cm2. The thickness of Cr layer evaporated on Si substrate was about 400 Å. Rutherford backscattering spectrometry (RBS) was used to investigate the atomic mixing induced at the Cr–Si interface as function of the incident ion mass and fluence. We observed that for the samples irradiated with Ar ions, RBS yields from both Cr layer and Si substrate are the same as before the irradiation. There is no mixing of Cr and Si atoms, even at the fluence of 2 × 1016 ions/cm2. For the samples irradiated with Kr ions, a slight broadening of the Cr and Si interfacial edges was produced from the fluence of 5 × 1015 ions/cm2. The broadening of the Cr and Si interfacial edges is more pronounced with Xe ions particularly to the fluence of 1016 ions/cm2. The interface broadening was found to depend linearly on the ion fluence and suggests that the mixing is like a diffusion controlled process. The experimental mixing rates were determined and compared with values predicted by ballistic and thermal spike models. Our experimental data were well reproduced by the thermal spikes model.

  7. On mechanism of low-energy heavy ions scattering on a target surface with small atomic mass

    CERN Document Server

    Umarov, F F; Kudryashova, L B; Krylov, N M

    2002-01-01

    In the present work, an experimental study of low-energy (E sub 0 =20-500 eV) heavy Cs sup + ions scattering on target surfaces with small atomic masses (Al, Si, Ni) has been performed for more accurate definition of mechanism of scattering and evaluation of an opportunity for use of heavy ions scattering as a tool of surface layer analysis. It is shown that the dependence of the relative energies of scattered ions versus the initial energy E/E sub 0 (E sub 0) for Si (E sub b =4.64 eV/atom) and Ni (E sub b =4.43 eV/atom) approximately coincide despite the fact that the mass of Ni atom is twice as large as that of the Si atom mass. At the same time their binding energies E sub b are approximately equal to each other. It is found that the scattering angles of Cs sup + ions considerably exceed a limiting scattering angle theta sub l sub i sub m in a single collision. It has been established that the scattering of low-energy heavy ions by light targets is described by a non-binary mechanism of many-particle inter...

  8. The Boundary Radii of Atoms and Ions%原子和离子的边界半径

    Institute of Scientific and Technical Information of China (English)

    杨忠志; 张明波; 赵东霞

    2001-01-01

    假设原子(离子)中一个电子所受到的作用势等于其第一电离能的负值,定义了原子(离子)的边界半径,其具有内禀性、唯一性的特点。借助于MELD从头计算程序,计算了原子(离子)中一个电子受到的作用势,给出了前四周期元素的原子和离子边界半径。这种半径与传统半径之间存在很好的相关性,具有可应用性和预测性。%The MELD program is employed to evaluate the potential v(r) acting on an electron at the point r within an atom(ion). The boundary radius of an atom(ion) is defined by the classical turning point equation v(r) = - I, where I denotes the first ionization potential of the atom(ion). The boundary radii of atoms and ions of elements from first-to third-row in the periodic table are obtained. The radii of atoms and ions defined in this way have a close correlation with other traditional sets of radii, which indicates that they are applicable and predicable.

  9. Calculation of charge-changing cross-sections of ions or atoms colliding with fast ions using the classical trajectory method

    International Nuclear Information System (INIS)

    Evaluation of ion-atom charge-changing cross-sections is needed for many accelerator applications. A Classical Trajectory Monte Carlo (CTMC) simulation has been used to calculate ionization and charge-exchange cross-sections. For benchmarking purposes, an extensive study has been performed for the simple case of hydrogen and helium targets in collisions with various ions. Despite the fact that the simulation only accounts for classical mechanics, the calculations are comparable to experimental results for projectile velocities in the region corresponding to the vicinity of the maximum cross-section. The shortcomings of the CTMC method for multielectron target atoms are discussed.

  10. Imprints from the solar cycle on the helium atom and helium pickup ion distributions

    Directory of Open Access Journals (Sweden)

    D. Rucinski

    Full Text Available Neutral interstellar helium atoms penetrate into the solar system almost unaffected by gas–plasma interactions in the heliospheric interface region, and thus can be considered as carriers of original information on the basic parameters (like density, temperature, bulk velocity of the Very Local Interstellar Medium (VLISM. Such information can nowadays be derived from analysis of data obtained from different experimental methods: in situ measurements of He atoms (Ulysses, observations of the solar backscattered He 584 A radiation (EUVE, in situ measurements of He + pickup ions (AMPTE, Ulysses, Wind, SOHO, ACE. In view of the current coordinated international ISSI campaign devoted to the study of the helium focusing cone structure and its evolution, we analyze expected variations of neutral He density, of He + pickup fluxes and of their phase space distributions at various phases of the solar activity cycle based on a realistic time-dependent modelling of the neutral helium and He + pickup ion distributions, which reflect solar cycle-induced variations of the photoionization rate. We show that the neutral helium density values are generally anticorrelated with the solar activity phase and in extreme cases (near the downwind axis the maximum-to-minimum density ratio may even exceed factors of ~ 3 at 1 AU. We also demonstrate that in the upwind hemisphere (at 1 AU and beyond the He + fluxes are correlated with the solar cycle activity, whereas on the downwind side the maximum of the expected flux up to distances of ~ 3 AU occurs around solar minimum epoch, and only further away does the correlation with solar activity become positive. Finally, we present the response of the phase space distribution spectra of He + pickup ions (in the solar wind frame for different epochs of the solar cycle and heliocentric distances from 1 to 5 AU covering the range of Ulysses, Wind and ACE observations.

    Key words. Solar physics, astrophysics and astronomy

  11. Projectile X-ray emission in relativistic ion-atom collisions

    Energy Technology Data Exchange (ETDEWEB)

    Salem, Shadi Mohammad Ibrahim

    2010-03-16

    This work reports on the study of the projectile X-ray emission in relativistic ion-atom collisions. Excitation of K-shell in He-like uranium ions, electron capture into H-like uranium ions and Simultaneous ionization and excitation of initially He-like uranium ions have been studied using the experimental storage ring at GSI. For the K{sub {alpha}}{sub 1} and K{sub {alpha}}{sub 2} transitions originating from the excitation of the He-like uranium ions, no alignment was observed. In contrast, the Ly{sub {alpha}}{sub 1} radiation from the simultaneous ionization-excitation process of the He-like uranium ions shows a clear alignment. The experimental value leads to the inclusion of a magnetic term in the interaction potential. The capture process of target electrons into the highly-charged heavy ions was studied using H-like uranium ions at an incident energy of 220 MeV/u, impinging on N{sub 2} gas-target. It was shown that, the strongly aligned electrons captured in 2p{sub 3/2} level couple with the available 1s{sub 1/2} electron which shows no initial directional preference. The magnetic sub-state population of the 2p{sub 3/2} electron is redistributed according to the coupling rules to the magnetic sub-states of the relevant two-electron states. This leads to the large anisotropy in the corresponding individual ground state transitions contributing to the K{sub {alpha}}{sub 1} emission. From the K{sub {alpha}}{sub 1}/K{sub {alpha}}{sub 2} ratio, the current results show that the incoherent addition of the E1 and M2 transition components yield to an almost isotropic emission of the total K{sub {alpha}}{sub 1}. In contrast to the radiative electron capture, the experimental results for the K-shell single excitation of He-like uranium ions indicate that only the {sup 1}P{sub 1} level contributes to the K{sub {alpha}}{sub 1} transition. For this case, the anisotropy parameter {beta}{sub 20} was found to be -0.20{+-}0.03. This work also reports on the study of a two

  12. Atomic physics with highly-charged heavy ions at the GSI future facility: The scientific program of the SPARC collaboration

    Energy Technology Data Exchange (ETDEWEB)

    Gumberidze, A. [GSI, Plankstr. 1, D-64291 Darmstadt (Germany)]. E-mail: a.gumberidze@gsi.de; Bosch, F. [GSI, Plankstr. 1, D-64291 Darmstadt (Germany); Braeuning-Demian, A. [GSI, Plankstr. 1, D-64291 Darmstadt (Germany); Hagmann, S. [GSI, Plankstr. 1, D-64291 Darmstadt (Germany); Kuehl, Th. [GSI, Plankstr. 1, D-64291 Darmstadt (Germany); Liesen, D. [GSI, Plankstr. 1, D-64291 Darmstadt (Germany); Schuch, R. [Stockholm University, Stockholm (Sweden); Stoehlker, Th. [GSI, Plankstr. 1, D-64291 Darmstadt (Germany)

    2005-05-01

    The proposed new international accelerator Facility for Antiproton and Ion Research (FAIR) will open up exciting and far-reaching perspectives for atomic physics research in the realm of highly-charged heavy ions: it will provide the highest intensities of relativistic beams of both stable and unstable heavy nuclei. In combination with the strongest possible electromagnetic fields produced by the nuclear charge of the heaviest nuclei, this will allow to extend atomic spectroscopy up to the virtual limits of atomic matter. Based on the experience and results already achieved at the experimental storage ring (ESR), a substantial progress in atomic physics research has to be expected in this domain, due to a tremendous improvement of intensity, energy and production yield of both stable and unstable nuclei.

  13. Development of the negative ion beams relevant to ITER and JT-60SA at Japan Atomic Energy Agency

    Energy Technology Data Exchange (ETDEWEB)

    Hanada, M., E-mail: hanada.masaya@jaea.go.jp; Kojima, A.; Tobari, H.; Nishikiori, R.; Hiratsuka, J.; Kashiwagi, M.; Umeda, N.; Yoshida, M.; Ichikawa, M.; Watanabe, K. [Japan Atomic Energy Agency, 801-1 Mukouyama, Naka-shi, Ibaraki-ken 319-0913 (Japan); Yamano, Y. [Saitama University, Saitama, Saitama-ken 338-8570 (Japan); Grisham, L. R. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States)

    2016-02-15

    In order to realize negative ion sources and accelerators to be applicable to International Thermonuclear Experimental Reactor and JT-60 Super Advanced, a large cesium (Cs)-seeded negative ion source and a multi-aperture and multi-stage electric acceleration have been developed at Japan Atomic Energy Agency (JAEA). Long pulse production and acceleration of the negative ion beams have been independently carried out. The long pulse production of the high current beams has achieved 100 s at the beam current of 15 A by modifying the JT-60 negative ion source. The pulse duration time is increased three times longer than that before the modification. As for the acceleration, a pulse duration time has been also extended two orders of magnitudes from 0.4 s to 60 s. The developments of the negative ion source and acceleration at JAEA are well in progress towards the realization of the negative ion sources and accelerators for fusion applications.

  14. Development of the negative ion beams relevant to ITER and JT-60SA at Japan Atomic Energy Agency.

    Science.gov (United States)

    Hanada, M; Kojima, A; Tobari, H; Nishikiori, R; Hiratsuka, J; Kashiwagi, M; Umeda, N; Yoshida, M; Ichikawa, M; Watanabe, K; Yamano, Y; Grisham, L R

    2016-02-01

    In order to realize negative ion sources and accelerators to be applicable to International Thermonuclear Experimental Reactor and JT-60 Super Advanced, a large cesium (Cs)-seeded negative ion source and a multi-aperture and multi-stage electric acceleration have been developed at Japan Atomic Energy Agency (JAEA). Long pulse production and acceleration of the negative ion beams have been independently carried out. The long pulse production of the high current beams has achieved 100 s at the beam current of 15 A by modifying the JT-60 negative ion source. The pulse duration time is increased three times longer than that before the modification. As for the acceleration, a pulse duration time has been also extended two orders of magnitudes from 0.4 s to 60 s. The developments of the negative ion source and acceleration at JAEA are well in progress towards the realization of the negative ion sources and accelerators for fusion applications.

  15. Development of the negative ion beams relevant to ITER and JT-60SA at Japan Atomic Energy Agency.

    Science.gov (United States)

    Hanada, M; Kojima, A; Tobari, H; Nishikiori, R; Hiratsuka, J; Kashiwagi, M; Umeda, N; Yoshida, M; Ichikawa, M; Watanabe, K; Yamano, Y; Grisham, L R

    2016-02-01

    In order to realize negative ion sources and accelerators to be applicable to International Thermonuclear Experimental Reactor and JT-60 Super Advanced, a large cesium (Cs)-seeded negative ion source and a multi-aperture and multi-stage electric acceleration have been developed at Japan Atomic Energy Agency (JAEA). Long pulse production and acceleration of the negative ion beams have been independently carried out. The long pulse production of the high current beams has achieved 100 s at the beam current of 15 A by modifying the JT-60 negative ion source. The pulse duration time is increased three times longer than that before the modification. As for the acceleration, a pulse duration time has been also extended two orders of magnitudes from 0.4 s to 60 s. The developments of the negative ion source and acceleration at JAEA are well in progress towards the realization of the negative ion sources and accelerators for fusion applications. PMID:26932050

  16. Characterization of charge-exchange collisions between ultracold $\\rm{^6Li}$ atoms and $\\rm{^{40}Ca^+}$ ions

    CERN Document Server

    Saito, R; Sasakawa, M; Nakai, R; Raoult, M; Silva, H Da; Dulieu, O; Mukaiyama, T

    2016-01-01

    We investigate the energy dependence and the internal-state dependence of the charge-exchange collision cross sections in a mixture of $^6$Li atoms and $^{40}$Ca$^+$ ions in the collision energy range from 0.2 mK to 1 K. Deliberately excited ion micromotion is used to control the collision energy of atoms and ions. The energy dependence of the charge-exchange collision cross section obeys the Langevin model in the temperature range of the current experiment, and the measured magnitude of the cross section is correlated to the internal state of the $^{40}$Ca$^+$ ions. Revealing the relationship between the charge-exchange collision cross sections and the interaction potentials is an important step toward the realization of the full quantum control of the chemical reactions at an ultralow temperature regime.

  17. Ultracold magnetically tunable interactions without radiative-charge-transfer losses between Ca+, Sr+, Ba+, and Yb+ ions and Cr atoms

    Science.gov (United States)

    Tomza, Michał

    2015-12-01

    The Ca+, Sr+, Ba+, and Yb+ ions immersed in an ultracold gas of the Cr atoms are proposed as experimentally feasible heteronuclear systems in which ion-atom interactions at ultralow temperatures can be controlled with magnetically tunable Feshbach resonances without charge transfer and radiative losses. Ab initio techniques are applied to investigate electronic-ground-state properties of the (CaCr)+, (SrCr)+, (BaCr)+, and (YbCr)+ molecular ions. The potential energy curves, permanent electric dipole moments, and static electric dipole polarizabilities are computed. The spin-restricted open-shell coupled-cluster method restricted to single, double, and noniterative triple excitations and the multireference configuration-interaction method restricted to single and double excitations are employed. The scalar relativistic effects are included within the small-core energy-consistent pseudopotentials. The leading long-range induction and dispersion interaction coefficients are also reported. Finally, magnetic Feshbach resonances between the Ca+, Sr+, Ba+, and Yb+ ions interacting with the Cr atoms are analyzed. The present proposal opens the way towards robust quantum simulations and computations with ultracold ion-atom systems free of radiative charge-transfer losses.

  18. Recent theoretical studies of slow collisions between plasma impurity ions and H or He atoms

    Energy Technology Data Exchange (ETDEWEB)

    Fritsch, W. [Hahn-Meitner-Institut Berlin GmbH (Germany). Bereich Theoretische Physik; Tawara, H.

    1997-01-01

    We review recent progress in theoretical studies of slow collisions between light plasma impurity ions and atomic hydrogen or helium. We start with a brief overview of theory work that has been done by various groups in the past. We then proceed to discuss work that is published in the last two years. For the systems of Be{sup 2+}-He, Be{sup 4+}-He and C{sup 5+}-He we present yet unpublished work of our own. All of this work broadens our knowledge about systems that are of interest for the fusion community. Some of the new information is found to be at variance with what is known from other sources and hence needs further analysis. (author)

  19. Simultaneous Scanning Ion Conductance Microscopy and Atomic Force Microscopy with Microchanneled Cantilevers

    Science.gov (United States)

    Ossola, Dario; Dorwling-Carter, Livie; Dermutz, Harald; Behr, Pascal; Vörös, János; Zambelli, Tomaso

    2015-12-01

    We combined scanning ion conductance microscopy (SICM) and atomic force microscopy (AFM) into a single tool using AFM cantilevers with an embedded microchannel flowing into the nanosized aperture at the apex of the hollow pyramid. An electrode was positioned in the AFM fluidic circuit connected to a second electrode in the bath. We could thus simultaneously measure the ionic current and the cantilever bending (in optical beam deflection mode). First, we quantitatively compared the SICM and AFM contact points on the approach curves. Second, we estimated where the probe in SICM mode touches the sample during scanning on a calibration grid and applied the finding to image a network of neurites on a Petri dish. Finally, we assessed the feasibility of a double controller using both the ionic current and the deflection as input signals of the piezofeedback. The experimental data were rationalized in the framework of finite elements simulations.

  20. Fast low-rank approximations of multidimensional integrals in ion-atomic collisions modelling

    CERN Document Server

    Litsarev, M S

    2015-01-01

    An efficient technique based on low-rank separated approximations is proposed for computation of three-dimensional integrals arising in the energy deposition model that describes ion-atomic collisions. Direct tensor-product quadrature requires grids of size $4000^3$ which is unacceptable. Moreover, several of such integrals have to be computed simultaneously for different values of parameters. To reduce the complexity, we use the structure of the integrand and apply numerical linear algebra techniques for the construction of low-rank approximation. The resulting algorithm is $10^3$ faster than spectral quadratures in spherical coordinates used in the original DEPOSIT code. The approach can be generalized to other multidimensional problems in physics.

  1. Charge transfer in the interactions of partially stripped ions with atoms at intermediate and high energies

    International Nuclear Information System (INIS)

    The Coulomb-Born (CB) approximation has been employed to study charge transfer cross sections in collisions of Cq+, Nq+ and Oq+ (q = 1-5) with atomic hydrogen in ground state in the energy range of 30-200 keV/amu. The interaction of the active electron with the incoming projectile ion has been approximated by a model potential containing both a long-range part and a short-range part. Variations of total capture cross sections with impact energy compare favourable well with the available experimental observations and with other theoretical findings. In addition, sub-shell distributions of total capture cross sections are given in graphical form. However, we are unable to find any oscillation in the charge-state dependence of total capture cross sections. (author)

  2. Single ionization of helium atoms by energetic fully stripped carbon ions

    Institute of Scientific and Technical Information of China (English)

    Ebrahim Ghanbari-Adivi; Sadjad Eskandari

    2015-01-01

    A four-body distorted wave approximation is presented for theoretical investigations of the single ionization of ground-state helium atoms by fully stripped carbon ions at impact energies of 2 MeV/amu and 100 MeV/amu. The nine-dimensional integrals for the partial quantum-mechanical transition amplitudes of the specified reaction are reduced to some analytical expressions or one-dimensional integrals over real variables. Fully differential cross sections (FDCSs) are calculated and compared with their experimental values as well as the results obtained from other theories. Despite the simplicity and quickness of the proposed quadrature, the comparison shows that the obtained results are in reasonable agreement with the experiment and are compatible with those of other complicated theories.

  3. Proceedings of the 2nd joint seminar on atomic collisions and heavy ion induced nuclear reactions

    International Nuclear Information System (INIS)

    The meeting of the 2nd joint seminar on atomic collisions and heavy ion induced nuclear reactions was held at the University of Tokyo, May 13 and 14, 1982. The aim of this seminar has been not only to recognize the common problems lying between above two research fields, but also to obtain an overview of the theoretical and experimental approaches to clear the current problems. In the seminar, more than 50 participants gathered and presented 16 papers. These are two general reviews and fourteen comprehensive surveys on topical subjects which have been developed very intensively in recent years. The editors would like to thank all participants for their assistance and cooperation in making possible a publication of these proceedings. (author)

  4. Coordinate space translation technique for simulation of electronic process in the ion-atom collision.

    Science.gov (United States)

    Wang, Feng; Hong, Xuhai; Wang, Jian; Kim, Kwang S

    2011-04-21

    Recently we developed a theoretical model of ion-atom collisions, which was made on the basis of a time-dependent density functional theory description of the electron dynamics and a classical treatment of the heavy particle motion. Taking advantage of the real-space grid method, we introduce a "coordinate space translation" technique to allow one to focus on a certain space of interest such as the region around the projectile or the target. Benchmark calculations are given for collisions between proton and oxygen over a wide range of impact energy. To extract the probability of charge transfer, the formulation of Lüdde and Dreizler [J. Phys. B 16, 3973 (1983)] has been generalized to ensemble-averaging application in the particular case of O((3)P). Charge transfer total cross sections are calculated, showing fairly good agreements between experimental data and present theoretical results.

  5. Selective electron capture into highly stripped Ne and N target atoms after heavy-ion impact

    International Nuclear Information System (INIS)

    Auger electron and x-ray spectra from Ne and N gas targets excited with 1.4 MeV amu-1 Ar12+, Kr15+, Xe24+, and Pb36+ ions are measured, varying the target pressure and mixing other gases into the target volume. A dramatic change of line intensities from outer-shell configurations having a KL two-electron core and a third electron in the n = 4,5,6 shell is observed, depending on the target pressure and systematically on the target ionisation potential. This effect is explained by highly selective electron capture from neutral target atoms or molecules into outer-shell orbitals of slowly (Esub(r) -14 cm2 is estimated from the experiment. (author)

  6. Charge-exchange-induced perturbations of ion and atom distribution functions in the heliospheric interface

    CERN Document Server

    Fahr, H J

    2004-01-01

    Various hydrodynamic models of the heliospheric interface have been presented meanwhile, numerically simulating the interaction of the solar wind plasma bubble with the counterstreaming partially ionized interstellar medium. In these model approaches the resulting interface flows are found by the use of hydrodynamic simulation codes trying to consistently describe the dynamic and thermodynamic coupling of the different interacting fluids of protons, H-atoms and pick-up ions. Within such approaches, the fluids are generally expected to be correctly described by the three lowest velocity moments, i.e., by shifted Maxwellians. We shall show that in these approaches the charge-exchange-induced momentum coupling is treated in an unsatisfactory representation valid only at supersonic differential flow speeds. Though this flaw can be removed by an improved coupling term, we shall further demonstrate that the assumption of shifted Maxwellians in some regions of the interface is insufficiently well fulfilled both for ...

  7. Charge breeding investigation in EBIS/T and collision study of ions with cold atoms for HITRAP

    International Nuclear Information System (INIS)

    Highly charged ions (HCI) at low velocities or at rest are interesting systems for various atomic physics experiments. For investigations on HCI of heavy stable or radioactive nuclides the HITRAP (Highly charged Ion TRAP) decelerator facility has been set up at GSI to deliver cooled beams of HCI at an energy of 5 keV/q. The HCI are produced in a stripper foil at relativistic energies and are decelerated in several steps at ESR storage ring and HITRAP before they are delivered to experimental setups. One of the experiments is the investigation of multi-electron charge exchange in collisions of heavy HCI with cold atoms using novel MOTRIMS technique. Collision experiments on light ions from an ECR ion source colliding with cold atoms in a MOT have been performed and the results are described. An electron beam ion trap (EBIT) has been tested and optimized for commissioning of the HITRAP physics experiments. The process of charge breeding in the EBIT has been successfully studied with gaseous elements and with an alkaline element injected from an external ion source. (orig.)

  8. Charge breeding investigation in EBIS/T and collision study of ions with cold atoms for HITRAP

    Energy Technology Data Exchange (ETDEWEB)

    Sokolov, Alexey

    2010-01-29

    Highly charged ions (HCI) at low velocities or at rest are interesting systems for various atomic physics experiments. For investigations on HCI of heavy stable or radioactive nuclides the HITRAP (Highly charged Ion TRAP) decelerator facility has been set up at GSI to deliver cooled beams of HCI at an energy of 5 keV/q. The HCI are produced in a stripper foil at relativistic energies and are decelerated in several steps at ESR storage ring and HITRAP before they are delivered to experimental setups. One of the experiments is the investigation of multi-electron charge exchange in collisions of heavy HCI with cold atoms using novel MOTRIMS technique. Collision experiments on light ions from an ECR ion source colliding with cold atoms in a MOT have been performed and the results are described. An electron beam ion trap (EBIT) has been tested and optimized for commissioning of the HITRAP physics experiments. The process of charge breeding in the EBIT has been successfully studied with gaseous elements and with an alkaline element injected from an external ion source. (orig.)

  9. Correlation energies beyond the random-phase approximation: ISTLS applied to spherical atoms and ions

    CERN Document Server

    Gould, Tim

    2012-01-01

    The inhomogeneous Singwi, Tosi, Land and Sjolander (ISTLS) correlation energy functional of Dobson, Wang and Gould [PRB {\\bf 66} 081108(R) (2008)] has proved to be excellent at predicting correlation energies in semi-homogeneous systems, showing promise as a robust `next step' fifth-rung functional by using dynamic correlation to go beyond the limitations of the direct random-phase approximation (dRPA), but with similar numerical scaling with system size. In this work we test the functional on fourteen spherically symmetric, neutral and charged atomic systems and find it gives excellent results (within 2mHa/$e^-$ except Be) for the absolute correlation energies of the neutral atoms tested, and good results for the ions (within 4mHa/$e^-$). In all cases it performs better than the dRPA. When combined with the previous successes, these new results point to the ISTLS functional being a prime contender for high-accuracy, benchmark DFT correlation energy calculations.

  10. Wave-packet continuum-discretization approach to ion-atom collisions: Nonrearrangement scattering

    Science.gov (United States)

    Abdurakhmanov, I. B.; Kadyrov, A. S.; Bray, I.

    2016-08-01

    A general single-center close-coupling approach based on a continuum-discretization procedure is developed to calculate excitation and ionization processes in ion-atom collisions. The continuous spectrum of the target is discretized using stationary wave packets constructed from the Coulomb wave functions, the eigenstates of the target Hamiltonian. Such continuum discretization allows one to generate pseudostates with arbitrary energies and distribution. These features are ideal for detailed differential ionization studies. The approach starts from the semiclassical three-body Schrödinger equation for the scattering wave function and leads to a set of coupled differential equations for the transition probability amplitudes. To demonstrate its utility the method is applied to calculate collisions of antiprotons with atomic hydrogen. A comprehensive set of benchmark results from integrated to fully differential cross sections for antiproton-impact ionization of hydrogen in the energy range from 1 keV to 1 MeV is provided. Contrary to previous predictions, we find that at low incident energies the singly differential cross section has a maximum away from the zero emission energy. This feature could not be seen without a fine discretization of the low-energy part of the continuum.

  11. Electron emission in collisions of fast highly charged bare ions with helium atoms

    Science.gov (United States)

    Mondal, Abhoy; Mandal, Chittranjan; Purkait, Malay

    2016-01-01

    We have studied the electron emission from ground state helium atom in collision with fast bare heavy ions at intermediate and high incident energies. In the present study, we have applied the present three-body formalism of the three Coulomb wave (3C-3B) model and the previously adopted four-body formalism of the three Coulomb wave (3C-4B). To represent the active electron in the helium atom in the 3C-3B model, the initial bound state wavefunction is chosen to be hydrogenic with an effective nuclear charge. The wavefunction for the ejected electron in the exit channel has been approximated to be a Coulomb continuum wavefunction with same effective nuclear charge. Effectively the continuum-continuum correlation effect has been considered in the present investigation. Here we have calculated the energy and angular distribution of double differential cross sections (DDCS) at low and high energy electron emission from helium atom. The large forward-backward asymmetry is observed in the angular distribution which is explained in terms of the two-center effect (TCE). Our theoretical results are compared with available experimental results as well as other theoretical calculations based on the plain wave Born approximation (PWBA), continuum-distorted wave (CDW) approximation, continuum-distorted wave eikonal-initial state (CDW-EIS) approximation, and the corresponding values obtained from the 3C-4B model [S. Jana, R. Samanta, M. Purkait, Phys. Scr. 88, 055301 (2013)] respectively. It is observed that the four-body version of the present investigation produces results which are in better agreement with experimental observations for all cases.

  12. Relativistic calculations of quasi-one-electron atoms and ions using Laguerre and Slater spinors

    CERN Document Server

    Jiang, Jun; Cheng, Yongjun; Bromley, Michael W J

    2016-01-01

    A relativistic description of the structure of heavy alkali atoms and alkali-like ions using S-spinors and L-spinors has been developed. The core wavefunction is defined by a Dirac-Fock calculation using an S-spinors basis. The S-spinor basis is then supplemented by a large set of L-spinors for the calculation of the valence wavefunction in a frozen-core model. The numerical stability of the L-spinor approach is demonstrated by computing the energies and decay rates of several low-lying hydrogen eigenstates, along with the polarizabilities of a $Z=60$ hydrogenic ion. The approach is then applied to calculate the dynamic polarizabilities of the $5s$, $4d$ and $5p$ states of Sr$^+$. The magic wavelengths at which the Stark shifts between different pairs of transitions are zero are computed. Determination of the magic wavelengths for the $5s \\to 4d_{\\frac32}$ and $5s \\to 4d_{\\frac52}$ transitions near $417$~nm (near the wavelength for the $5s \\to 5p_j$ transitions) would allow a determination of the oscillator s...

  13. Are the sungrazing comets the inner source of pickup ions and energetic neutral atoms?

    CERN Document Server

    Bzowski, M

    2004-01-01

    We show arguments that at least part of the inner source of pickup ions and energetic neutral atoms (~ 1 keV) might be the material released by sungrazing comets.Based on the monthly apparition statistics we postulate that the actual number of sungrazing comets may be even higher than observed. We point out that an overwhelming majority of the observed sungrazers belong to the Kreutz group of comets which follow tightly clumped orbits and break up at $\\sim 40 - 4$ solar radii in a well defined region. The material released from these comets should be (after ionization) at least an important portion of the inner source of pickup ions. We suggest that PUI from the cometary source should be accompanied by an increased level of ENA of similar energy. We indicate time intervals during the year when the cometary PUI should be observed from a spacecraft at Earth's orbit (basically, from the end of July till the end of the year) and show three time intervals, when they should be observable by Ulysses (since launch ti...

  14. Conversion of an atomic to a molecular argon ion and low pressure argon relaxation

    Science.gov (United States)

    M, N. Stankov; A, P. Jovanović; V, Lj Marković; S, N. Stamenković

    2016-01-01

    The dominant process in relaxation of DC glow discharge between two plane parallel electrodes in argon at pressure 200 Pa is analyzed by measuring the breakdown time delay and by analytical and numerical models. By using the approximate analytical model it is found that the relaxation in a range from 20 to 60 ms in afterglow is dominated by ions, produced by atomic-to-molecular conversion of Ar+ ions in the first several milliseconds after the cessation of the discharge. This conversion is confirmed by the presence of double-Gaussian distribution for the formative time delay, as well as conversion maxima in a set of memory curves measured in different conditions. Finally, the numerical one-dimensional (1D) model for determining the number densities of dominant particles in stationary DC glow discharge and two-dimensional (2D) model for the relaxation are used to confirm the previous assumptions and to determine the corresponding collision and transport coefficients of dominant species and processes. Project supported by the Ministry of Education, Science and Technological Development of the Republic of Serbia (Grant No. ON171025).

  15. The non-symmetric ion-atom radiative processes in the stellar atmospheres

    CERN Document Server

    Mihajlov, A A; Sreckovic, V A; Dimitrijevic, M S; Metropoulos, A; 10.1093/mnras/stt187

    2013-01-01

    The aim of this research is to show that the processes of absorption charge-exchange and photo-association in $A+B^{+}$ collisions together with the processes of $AB^{+}$ photo-dissociation in the case of strongly non-symmetric ion-atom systems, significantly influence the opacity of stellar atmospheres in ultraviolet (UV) and extreme UV (EUV) region. In this work, the significance of such processes for solar atmosphere is studied. In the case of the solar atmosphere the absorption processes with $A=$ H and $B=$ Mg and Si are treated as dominant ones, but the cases $A=$ H and $B=$ Al and $A=$ He and $B=$ H are also taken into consideration. The choice of just these species is caused by the fact that, of the species relevant for the used solar-atmosphere model, it was only for them that we could determine the necessary characteristics of the corresponding molecular ions, i.e. the molecular potential curves and dipole matrix elements. It is shown that the efficiency of the examined non-symmetric processes withi...

  16. Metal-Organic Framework Thin Films as Platforms for Atomic Layer Deposition of Cobalt Ions To Enable Electrocatalytic Water Oxidation.

    Science.gov (United States)

    Kung, Chung-Wei; Mondloch, Joseph E; Wang, Timothy C; Bury, Wojciech; Hoffeditz, William; Klahr, Benjamin M; Klet, Rachel C; Pellin, Michael J; Farha, Omar K; Hupp, Joseph T

    2015-12-30

    Thin films of the metal-organic framework (MOF) NU-1000 were grown on conducting glass substrates. The films uniformly cover the conducting glass substrates and are composed of free-standing sub-micrometer rods. Subsequently, atomic layer deposition (ALD) was utilized to deposit Co(2+) ions throughout the entire MOF film via self-limiting surface-mediated reaction chemistry. The Co ions bind at aqua and hydroxo sites lining the channels of NU-1000, resulting in three-dimensional arrays of separated Co ions in the MOF thin film. The Co-modified MOF thin films demonstrate promising electrocatalytic activity for water oxidation.

  17. SPECIATION OF SELENIUM(IV) AND SELENIUM(VI) USING COUPLED ION CHROMATOGRAPHY: HYDRIDE GENERATION ATOMIC ABSORPTION SPECTROMETRY

    Science.gov (United States)

    A simple method was developed to speciate inorganic selenium in the microgram per liter range using coupled ion chromatography-hydride generation atomic absorption spectrometry. Because of the differences in toxicity and adsorption behavior, determination of the redox states selenite, Se(IV), and s...

  18. Partial and total electronic stopping cross sections of atoms for a singly charged helium ion, Part 2

    International Nuclear Information System (INIS)

    Partial and total electronic stopping cross sections of atoms with Z (55 ≤ Z ≤ 92) for a He+ ion are tabulated as the second part of NIFS-DATA-11 (1991) on the basis of the wave-packet theory. (author)

  19. A setup for transmission measurements of low energy multiply charged ions through free-standing few atomic layer films

    Science.gov (United States)

    Smejkal, V.; Gruber, E.; Wilhelm, R. A.; Brandl, L.; Heller, R.; Facsko, S.; Aumayr, F.

    2016-09-01

    We report the design and testing of a setup for transmission measurements of multiply charged ions through free-standing films with a thickness of a few atomic layers. The investigation thereof can yield deeper insight into charge equilibration and pre-equilibrium stopping phenomena which can ultimately be used to specifically tailor and modify these materials.

  20. ANISOTROPY EFFECTS IN SINGLE-ELECTRON TRANSFER BETWEEN LASER-EXCITED ATOMS AND HIGHLY-CHARGED IONS

    NARCIS (Netherlands)

    1995-01-01

    Recent collision experiments are reviewed in which one-electron transfer between laser excited target atoms and (highly charged) keV-ions has been studied. Especially results showing a dependence of the charge exchange on the initial target orbital alignment are discussed. The question to what exten

  1. Studies on the formation of atomic and molecular ions of uranium and thorium in Inductively Coupled Plasma Mass Spectrometry (ICPMS)

    International Nuclear Information System (INIS)

    The formation of molecular and atomic ions of U and Th as a function of the plasma conditions such as nebulizer gas flow and plasma power has been studied. The experiments performed and the results of these experiments are briefly described in this paper

  2. Processes involving electron capture and multiple ionization in collisions of fast H+ and He2+ ions with lead atoms

    Science.gov (United States)

    McCartney, P. C. E.; Shah, M. B.; Geddes, J.; Gilbody, H. B.

    1999-12-01

    A crossed-beam technique incorporating time-of-flight analysis and coincidence counting of the collision products has been used to study Pbq+ formation with q up to 8 in collisions between ground-state Pb atoms and H+ and He2+ ions within the range 50-600 keV amu-1. The separate cross sections for simple charge transfer, transfer ionization, and pure ionization leading to the formation of Pbq+ ions have been obtained and the relative importance of these processes has been established. Accurate measurements and rigorous theoretical descriptions of these multielectron processes in such heavy atoms are difficult and data are still very limited. The present measurements have been designed to extend our previous studies of multiple ionization of a few selected heavy metal atoms and to provide a further check on the extent to which the main collision processes can be described quantitatively in terms of simple models based on an independent electron description. In our previous work with Fe, Cu, and Ga atoms using the same experimental approach, we were able to describe the formation of multiply charged ions through both transfer ionization and pure ionization with a high degree of success using an independent electron model. However, the present results for Pb show that the success of this simple approach is much more limited for these much heavier atoms.

  3. Precise atomic-scale investigations of material sputtering process by light gas ions in pre-threshold energy region

    CERN Document Server

    Suvorov, A L

    2002-01-01

    Foundation and prospects of the new original technique of the sputtering yield determination of electro-conducting materials and sub-atomic layers on their surface by light gas ions the pre-threshold energy region (from 10 to 500 eV) are considered. The technique allows to identify individual surface vacancies, i.e., to count individual sputtered atoms directly. A short review of the original results obtained by using the developed techniques is given. Data are presented and analyzed concerning energy thresholds of the sputtering onset and energy dependences of sputtering yield in the threshold energy region for beryllium, tungsten, tungsten oxide, alternating tungsten-carbon layers, three carbon materials as well as for sub-atomic carbon layers on surface of certain metals at their bombardment by hydrogen, deuterium and/or helium ions

  4. Ultracold magnetically tunable interactions without radiative charge transfer losses between Ca$^+$, Sr$^+$, Ba$^+$, and Yb$^+$ ions and Cr atoms

    CERN Document Server

    Tomza, Michał

    2015-01-01

    The Ca$^+$, Sr$^+$, Ba$^+$, and Yb$^+$ ions immersed in an ultracold gas of the Cr atoms are proposed as experimentally feasible heteronuclear systems in which ion-atom interactions at ultralow temperatures can be controlled with magnetically tunable Feshbach resonances without charge transfer and radiative losses. \\textit{Ab initio} techniques are applied to investigate electronic-ground-state properties of the (CaCr)$^+$, (SrCr)$^+$, (BaCr)$^+$, and (YbCr)$^+$ molecular ions. The potential energy curves, permanent electric dipole moments, and static electric dipole polarizabilities are computed. The spin restricted open-shell coupled cluster method restricted to single, double, and noniterative triple excitations, RCCSD(T), and the multireference configuration interaction method restricted to single and double excitations, MRCISD, are employed. The scalar relativistic effects are included within the small-core energy-consistent pseudopotentials. The leading long-range induction and dispersion interaction co...

  5. Atomic data and theoretical X-ray spectra of Ge-like through V-like W ions

    Energy Technology Data Exchange (ETDEWEB)

    Clementson, J., E-mail: joel.clementson@ipp.mpg.de [Lawrence Livermore National Laboratory, Livermore, CA 94550 (United States); Department of Physics, Lund University, SE-221 00 Lund (Sweden); Beiersdorfer, P. [Lawrence Livermore National Laboratory, Livermore, CA 94550 (United States); Brage, T. [Department of Physics, Lund University, SE-221 00 Lund (Sweden); Gu, M.F. [University of California at Berkeley, Berkeley, CA 94720 (United States)

    2014-03-15

    The atomic structure and spectra of ten tungsten ions have been calculated using the Flexible Atomic Code. The calculations yield energy levels, radiative lifetimes, spectral line positions, transition probability rates, and oscillator strengths for the tungsten ions isoelectronic to germanium, W{sup 42+}, through vanadium, W{sup 51+}. Collisional–radiative models for high-temperature, low-density plasmas have been implemented to produce line emissivities for X-ray transitions in the 1–4 keV (3–12 Å) spectral interval. The Ge-like through V-like W ions are important in nuclear fusion research where their spectra may provide diagnostic information on magnetically confined plasmas.

  6. On the influence of the distortion of the initial atomic state by the field of a multicharged ion on double differential cross sections

    International Nuclear Information System (INIS)

    The theoretical description of atom ionization by multicharged ions is suggested; besides interaction in the finite state at Z1/Vi1 is a charge of an incident particle, Vi is a velocity of colliding particles) the distortion of the initial state of the target atom by the field of an incident ion is correctly taken into account. It is shown that the effect of the distortion of the initial state on the angular and energy distributions of electrons increases with the charge increase and the ion velocity decrease. The results of calculations for ion collisions with the helium atom are compared with experimental data

  7. Study of the anti-hydrogen atom and ion formation in the collisions antiproton-positronium

    International Nuclear Information System (INIS)

    The future CERN experiment called GBAR intends to measure the gravitational acceleration of antimatter on Earth using cold (neV) anti-hydrogen atoms undergoing a free fall. The experiment scheme first needs to cool anti-hydrogen positive ions, obtained thanks to two consecutive reactions occurring when an antiproton beam collides with a dense positronium cloud.The present thesis studies these two reactions in order to optimise the production of the anti-ions. The total cross sections of both reactions have been computed in the framework of a perturbation theory model (Continuum Distorted Wave - Final State), in the range 0 to 30 keV antiproton kinetic energy; several excited states of positronium have been investigated. These cross sections have then been integrated to a simulation of the interaction zone where antiprotons collide with positronium; the aim is to find the optimal experimental parameters for GBAR. The results suggest that the 2P, 3D or, to a lower extend, 1S states of positronium should be used, respectively with 2, less than 1 or 6 keV antiprotons. The importance of using short pulses of antiprotons has been underlined; the positronium will have to be confined in a tube of 20 mm length and 1 mm diameter. In the prospect of exciting the 1S-3D two-photon transition in positronium at 410 nm, a pulsed laser system had already been designed. It consists in the frequency doubling of an 820 nm pulsed titanium-sapphire laser. The last part of the thesis has been dedicated to the realisation of this laser system, which delivers short pulses (9 ns) of 4 mJ energy at 820 nm. (author)

  8. Investigating Global Ion and Neutral Atom Populations with IBEX and Voyager

    Science.gov (United States)

    Florinski, Vladimir

    2016-01-01

    The main objective of this project was to investigate pickup ion (PUI) production in the solar wind and heliosheath (the region between the termination shock and the heliopause) and compute the distributed energetic neutral atom fluxes throughout the helioshpere. The simulations were constrained by comparing the model output against observations from Ulysses, New Horizons, Voyager 1 and 2, and IBEX space probes. As evidenced by the number of peer reviewed journal publications resulting from the project (13 plus three submitted) and their citation rate (156 citations over three years), the project has made a lasting contribution to the field. The outcome is a significant improvement of our understanding of the pickup ion production and distribution in the distant heliosphere. The team has accomplished the entire set of tasks A-H set forth in the proposal. Namely, the transport modeling framework has been augmented with two populations of pickup ions (PUIs), the boundary conditions for the plasma and interstellar neutral hydrogen were verified against Ulysses and New Horizons PUI and an optimal set of velocity diffusion parameters established. The multi-component fluxes of PUIs were computed and isotropic velocity distributions generated for each cell in the computer simulation that covered the heliosphere from 1.5 AU to the heliopause. The distributions were carefully compared with in situ measurements at 3 AU (Ulysses), 12 AU (New Horizons), and 80-90 AU (Voyager 1 and 2) as well as those inferred from ENA fluxes measured by Cassini and IBEX (Wu et al., 2016). Some examples of modeldata comparison are shown in Figure 1. We have used coupled MHD-plasma and kinetic-neutral code to investigate the likely range of plasma and magnetic field parameters in the local interstellar medium (LISM), based on the assumption that the shape of the IBEX ribbon could be used to determine the orientation of the interstellar magnetic field. While the magnetic field is believed to be

  9. Characteristic X-ray emission in close collisions between heavy ions and atoms

    International Nuclear Information System (INIS)

    In this paper an attempt is given to answer the question of how far the inner-shell vacancy production in very heavy ion-atom collisions is influenced by the electronic configuration of the projectile prepared prior to the collision producing the observed vacancy. The variation of this configuration has been induced by changing the primary charge state of the projectile, the target density and thickness or by inverting the collision system. It turns out from the performed analysis of the experimental data that the excitation of even most strongly bound MO's can be easily dependent on these factors which have been ignored until now, especially in discussions of the 1sσ or 2pσ vacancy production at ZUA > 130. Experiments performed for the first time with gaseous targets for such heavy systems show very convincingly the influence of the outer-shell configuration on the vacancy production in inner shells. The analysis of the data has been performed in terms of electronic transitions among MO's transiently formed during the collision. In many cases a satisfactory agreement between theoretical predictions and experiment has been achieved. (orig./HSI)

  10. Pion correlations as a function of atomic mass in heavy ion collisions

    International Nuclear Information System (INIS)

    The method of two pion interferometry was used to obtain source-size and lifetime parameters for the pions produced in heavy ion collisions. The systems used were 1.70 · A GeV 56Fe + Fe, 1.82 · A GeV 40Ar + KCl and 1.54 · A GeV 93Nb + Nb, allowing for a search for dependences on the atomic number. Two acceptances (centered, in the lab., at ∼ 0 degrees and 45 degrees) were used for each system, allowing a search for dependences on the viewing angle. The correlation functions were calculated by comparing the data samples to background (or reference) samples made using the method of event mixing, where pions from different events are combined to produce a data sample in which the Bose-Einstein correlation effect is absent. The effect of the correlation function on the background samples is calculated, and a method for weighting the events to remove the residual correlation effect is presented. The effect of the spectrometer design on the measured correlation functions is discussed, as are methods for correcting for these effects during the data analysis. 58 refs., 39 figs., 18 tabs

  11. Report on the workshop on atomic and plasma physics requirements for heavy ion fusion, Argonne National Lab., December 13-14, 1979

    International Nuclear Information System (INIS)

    Atomic, molecular, and plasma physics areas that are relevant to inertial confinement fusion by energetic heavy ions are identified. Discussions are confined to problems related to the design of heavy ion accelerators, accumulation of ions in storage rings, and the beam transport in a reactor vessel

  12. The effect of atomic oxygen for the hollow-cathode in a 20 mN class ion thruster

    OpenAIRE

    長野, 寛; 早川, 幸男; 稲永, 康隆; 尾崎, 敏之; 首藤, 和雄; NAGANO, Hiroshi; Hayakawa, Yukio; Inanaga, Yasutaka; Ozaki, Toshiyuki; Shuto, Kazuo

    2014-01-01

    The super-low earth orbits under the altitude of 250 km are very attractive for earth and atmospheric observation. JAXA plans to launch the first test satellite in super-low altitude called SLATS. Such satellites use ion thrusters to compensate for air drag and keep their altitude. However, there are a lot of atomic oxygen in super-low earth orbit. The dispenser cathodes generally show degradation by oxidation. Therefore, the effect of atomic oxygen for the hollow-cathode was evaluated here. ...

  13. Towards high-energy and durable lithium-ion batteries via atomic layer deposition: elegantly atomic-scale material design and surface modification

    International Nuclear Information System (INIS)

    Targeted at fueling future transportation and sustaining smart grids, lithium-ion batteries (LIBs) are undergoing intensive investigation for improved durability and energy density. Atomic layer deposition (ALD), enabling uniform and conformal nanofilms, has recently made possible many new advances for superior LIBs. The progress was summarized by Liu and Sun in their latest review [1], offering many insightful views, covering the design of nanostructured battery components (i.e., electrodes and solid electrolytes), and nanoscale modification of electrode/electrolyte interfaces. This work well informs peers of interesting research conducted and it will also further help boost the applications of ALD in next-generation LIBs and other advanced battery technologies. (viewpoint)

  14. Sputtering of copper atoms by keV atomic and molecular ions A comparison of experiment with analytical and computer based models

    CERN Document Server

    Gillen, D R; Goelich,

    2002-01-01

    Non-resonant multiphoton ionisation combined with quadrupole and time-of-flight analysis has been used to measure energy distributions of sputtered copper atoms. The sputtering of a polycrystalline copper target by 3.6 keV Ar sup + , N sup + and CF sub 2 sup + and 1.8 keV N sup + and CF sub 2 sup + ion bombardment at 45 deg. has been investigated. The linear collision model in the isotropic limit fails to describe the high energy tail of the energy distributions. However the TRIM.SP computer simulation has been shown to provide a good description. The results indicate that an accurate description of sputtering by low energy, molecular ions requires the use of computer simulation rather than analytical approaches. This is particularly important when considering plasma-surface interactions in plasma etching and deposition systems.

  15. Charge breeding investigation in EBIS/T and collision study of ions with cold atoms for HITRAP

    OpenAIRE

    Sokolov, Alexey

    2010-01-01

    Highly charged ions (HCI) at low velocities or at rest are interesting systems for various atomic physics experiments. For investigations on HCI of heavy stable or radioactive nuclides the HITRAP (Highly charged Ion TRAP) decelerator facility has been set up at GSI to deliver cooled beams of HCI at an energy of 5 keV/q. The HCI are produced in a stripper foil at relativistic energies and are decelerated in several steps at ESR storage ring and HITRAP before they are delivered to experimental ...

  16. Precision measurements of cross sections of inelastic processes realized in collisions of alkali metal ions with atoms of rare gases

    CERN Document Server

    Lomsadze, R A; Mosulishvili, N O; Kezerashvili, R Ya

    2015-01-01

    This work presents a multifaceted experimental study of collisions of Na$^{+}$ and K$^{+}$ ions in the energy range 0.5 -- 10 keV with He and Ar atoms. Absolute cross sections for charge-exchange, ionization, stripping and excitation were measured using a refined version of the transfer electric field method, angle- and energy-dependent collection of product ions, energy loss, and optical spectroscopy. The experimental data and the schematic correlation diagrams have been employed to analyze and determine the mechanisms for these processes.

  17. Atomic collision studies at moderate projectile velocities using highly charged, decelerated heavy ions from the GSI-UNILAC

    International Nuclear Information System (INIS)

    Beams of highly ionized, very heavy atoms at moderate velocities have been produced at the UNILAC using the acceleration-stripping-deceleration method. The available ion species range from Kr33+ to U66+ in the energy region between 2 and 5 MeV/u. A survey on first experiments at GSI using these moderate velocity, few electron, heavy ion beams is given. The effectiveness of the method is demonstrated for Xesup(q+)-Xe collision experiments with 41 <= q <= 45. Results on vacancy transfer between inner quasimolecular levels for close collisions, and on distant collision electron capture are reported. (orig.)

  18. I. Charge exchange collisions of highly stripped ions with atomic hydrogen. II. Development of a three-stage double tandem accelerator-decelerator system for low energy, highly stripped ions. Final report, March 1, 1977-May 30, 1981

    International Nuclear Information System (INIS)

    The first measurements of charge exchange (electron transfer) in kiloelectron-volt-energy highly stripped boron, carbon, nitrogen and oxygen ion collisions with atoms have been extended to additional collision energies and charge values for the ions. A first accelerator-decelerator source of very highly stripped ions has been developed, and its usefulness in charge exchange studies established

  19. Atomic Data for Permitted Resonance Lines of Atoms and Ions from H to Si, and S, Ar, Ca and Fe

    OpenAIRE

    Verner, D. A.; Verner, E. M.; G. J. Ferland

    1996-01-01

    We list vacuum wavelengths, energy levels, statistical weights, transition probabilities and oscillator strengths for permitted resonance spectral lines of all ions of 18 astrophysically important elements (H through Si, S, Ar, Ca, Fe). Using a compilation of experimental energy levels, we derived accurate wavelengths for 5599 lines of 1828 ground-term multiplets which have gf-values calculated in the Opacity Project. We recalculated the Opacity Project multiplet gf-values to oscillator stren...

  20. Production of intense beams of mass-selected water cluster ions and theoretical study of atom-water interactions

    CERN Document Server

    Wang, Z P; Reinhard, P -G; Suraud, E; Bruny, G; Montano, C; Feil, S; Eden, S; Abdoul-Carime, H; Farizon, B; Farizon, M; Ouaskit, S; Maerk, T D

    2009-01-01

    The influences of water molecules surrounding biological molecules during irradiation with heavy particles (atoms,ions) are currently a major subject in radiation science on a molecular level. In order to elucidate the underlying complex reaction mechanisms we have initiated a joint experimental and theoretical investigation with the aim to make direct comparisons between experimental and theoretical results. As a first step, studies of collisions of a water molecule with a neutral projectile (C atom) at high velocities (> 0.1 a.u.), and with a charged projectile (proton) at low velocities (< 0.1 a.u.) have been studied within the microscopic framework. In particular, time-dependent density functional theory (TDDFT) was applied to the valence electrons and coupled non-adiabatically to Molecular dynamics (MD) for ionic cores. Complementary experimental developments have been carried out to study projectile interactions with accelerated (< 10 keV) and mass-selected cluster ions. The first size distributio...

  1. Determination of metallic elements in water by the combined preconcentration techniques of ion exchange and atomic absorption spectrophotometry

    International Nuclear Information System (INIS)

    Having as an aim the utilization of atomic absorption method with flame's excitement, the limits of detection in water of six metals (Ag, Co, Cr, Cu, Ni, Zn) were determined in synthetical samples through atomic absorption spectroscopy. Techniques to optimize the data have been pointed out and presented their statistical treatment. By means of the routine and the addition methods three 'real' samples have also been analysed in order to determine the contents of Cu and Zn. Aiming a pre-concentration and by utilizing the 60Co obtained activating a sample of cobalt in the CDTN/NUCLEBRAS TRIGA MARK-I reactor, the retainement of this cobalt in ion exchange resin and the variation of the factor of elution within different concentration of HCl in water have been determined. The limits of detection are presented and so are the quantitative ones, with and without pre-concentration in an ion exchanger resin and latter elution. (Author)

  2. Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups

    Science.gov (United States)

    Gillett-Kunnath, Miriam M.; Sevov, Slavi C.

    2012-01-01

    Although the first studies of Zintl ions date between the late 1890's and early 1930's they were not structurally characterized until many years later.1,2 Their redox chemistry is even younger, just about ten years old, but despite this short history these deltahedral clusters ions E9n- (E = Si, Ge, Sn, Pb; n = 2, 3, 4) have already shown interesting and diverse reactivity and have been at the forefront of rapidly developing and exciting new chemistry.3-6 Notable milestones are the oxidative coupling of Ge94- clusters to oligomers and infinite chains,7-19 their metallation,14-16,20-25 capping by transition-metal organometallic fragments,26-34 insertion of a transition-metal atom at the center of the cluster which is sometimes combined with capping and oligomerization,35-47 addition of main-group organometallic fragments as exo-bonded substituents,48-50 and functionalization with various organic residues by reactions with organic halides and alkynes.51-58 This latter development of attaching organic fragments directly to the clusters has opened up a new field, namely organo-Zintl chemistry, that is potentially fertile for further synthetic explorations, and it is the step-by-step procedure for the synthesis of germanium-divinyl clusters described herein. The initial steps outline the synthesis of an intermetallic precursor of K4Ge9 from which the Ge94- clusters are extracted later in solution. This involves fused-silica glass blowing, arc-welding of niobium containers, and handling of highly air-sensitive materials in a glove box. The air-sensitive K4Ge9 is then dissolved in ethylenediamine in the box and then alkenylated by a reaction with Me3SiC≡CSiMe3. The reaction is followed by electrospray mass spectrometry while the resulting solution is used for obtaining single crystals containing the functionalized clusters [H2C=CH-Ge9-CH=CH2]2-. For this purpose the solution is centrifuged, filtered, and carefully layered with a toluene solution of 18-crown-6. Left

  3. Experimental study of interactions of highly charged ions with atoms at keV energies: Progress report for period May 15, 1985-February 15, 1987

    International Nuclear Information System (INIS)

    Interest in interactions of low energy highly charged ions with electrons, atoms or ions is due to their importance to controlled thermonuclear fusion research and the interesting nature of the fundamental processes involved. Studies of such interactions have long been hampered by a lack of suitable ions sources. A superconducting solenoid, cryogenic Electron Beam Ion Source, CEBIS, has been constructed at Cornell University to produce low energy very highly charged ions. At present, using a pulsed 0.5A,8.5 keV electron beam, the source is capable of producing highly charged ions of C,N,O, including bare nuclei, and ions of Ar up to charge state 11 + in 1 millisecond of confinement time. The source is being used in experiments to investigate charge transfer and accompanying processes in low energy, highly charged ion-atom collisions

  4. Quantum electrodynamics tests and X-rays standards using pionic atoms and highly charged ions; Tests d'electrodynamique quantique et etalons de rayons-X a l'aide des atomes pioniques et des ions multicharges

    Energy Technology Data Exchange (ETDEWEB)

    Martino, Trassinelli

    2005-12-15

    The object of this thesis is to present a new measurement of the pion mass using pionic nitrogen X-ray spectroscopy and results on helium-like argon and sulphur spectroscopy. The new pion mass has been measured with an accuracy of 1.7 ppm, 30% better that the present world average value, and it is obtained from Bragg spectroscopy of 5 ->4 pionic nitrogen transitions using the theoretical predictions provided by quantum electrodynamics. We have got: m({pi}{sup -}) = (139.571042 {+-} 0.000210 {+-} 0.000110) where the first error is due to the statistics and the second is the systematic error. I present the calculation of the hyperfine structure and recoil corrections for pionic atoms using a new perturbation method for the Klein-Gordon equation. The spectrometer used for this measurement has been characterized with the relativistic M1 transitions from helium-like ions produced with a new device, the Electron-Cyclotron-Resonance Ion Trap. High statistics spectra from these ions have enabled us to measure transition energies with an accuracy of some ppm which has allowed us to compare theoretical predictions with experiment data. X-ray emission from pionic atoms and multicharged ions can be used to define new types of X-ray standards for energies of a few keV.

  5. Single and double electron capture cross sections in keV-collisions between fully stripped ions with helium atom

    OpenAIRE

    Ibaaz, Aicha; Dubois, Alain

    2015-01-01

    International audience We present cross section calculations for single-, double-capture, and double capture to auto-ionizing states occurring in the course of collisions between fully stripped ions Aq+ (q≤10) and helium atom at impact energies ranging from 0.25 to 625 keV/u. These calculations were performed by applying a semiclassical nonperturbative close coupling approach, based on the expansion of the scattering wave function into asymptotic bielectronic states with proper translation...

  6. Thermodynamics of various F420 coenzyme models as sources of electrons, hydride ions, hydrogen atoms and protons in acetonitrile.

    Science.gov (United States)

    Xia, Ke; Shen, Guang-Bin; Zhu, Xiao-Qing

    2015-06-14

    32 F420 coenzyme models with alkylation of the three different N atoms (N1, N3 and N10) in the core structure (XFH(-)) were designed and synthesized and the thermodynamic driving forces (defined in terms of the molar enthalpy changes or the standard redox potentials in this work) of the 32 XFH(-) releasing hydride ions, hydrogen atoms and electrons, the thermodynamic driving forces of the 32 XFH˙ releasing protons and hydrogen atoms and the thermodynamic driving forces of XF(-)˙ releasing electrons in acetonitrile were determined using titration calorimetry and electrochemical methods. The effects of the methyl group at N1, N3 and N10 and a negative charge on N1 and N10 atoms on the six thermodynamic driving forces of the F420 coenzyme models and their related reaction intermediates were examined; the results show that seating arrangements of the methyl group and the negative charge have remarkably different effects on the thermodynamic properties of the F420 coenzyme models and their related reaction intermediates. The effects of the substituents at C7 and C8 on the six thermodynamic driving forces of the F420 coenzyme models and their related reaction intermediates were also examined; the results show that the substituents at C7 and C8 have good Hammett linear free energy relationships with the six thermodynamic parameters. Meanwhile, a reasonable determination of possible reactions between members of the F420 family and NADH family in vivo was given according to a thermodynamic analysis platform constructed using the elementary step thermodynamic parameter of F420 coenzyme model 2FH(-) and NADH model MNAH releasing hydride ions in acetonitrile. The information disclosed in this work can not only fill a gap in the chemical thermodynamics of F420 coenzyme models as a class of very important organic sources of electrons, hydride ions, hydrogen atoms and protons, but also strongly promote the fast development of the chemistry and applications of F420 coenzyme.

  7. Measurements of scattering processes in negative ion-atom collisions. Technical progress report, 1 September 1991--31 August 1992

    Energy Technology Data Exchange (ETDEWEB)

    Kvale, T.J.

    1992-04-01

    This Technical Progress Report describes the progress made on the research objectives during the past twelve months. This research project is designed to provide measurements of various scattering processes which occur in H{sup {minus}} collisions with atomic (specifically, noble gas and atomic hydrogen) targets at intermediate energies. These processes include: elastic scattering,single- and double-electron detachment, and target excitation/ionization. For the elastic and target inelastic processes where H{sup {minus}} is scattered intact, the experimental technique of Ion Energy-Loss Spectroscopy (IELS) will be employed to identify the final target state(s). In most of the above processes, cross sections are unknown both experimentally and theoretically. The measurements in progress will provide either experimentally-determined cross sections or set upper limits to those cross sections. In either case, these measurements will be stringent tests of our understanding in energetic negative ion-atom collisions. This series of experiments required the construction of a new facility and the initial ion beam was accelerated through the apparatus in April 1991.

  8. Stripping and multiple electron loss cross sections for heavy ions incident on various atomic and molecular gases

    International Nuclear Information System (INIS)

    Differential cross sections for charge change resulting from the scattering of 20-MeV 127I5+ and 20-MeV 35Cl4+ ions from thin gaseous targets of Xe, Ar, and N2 were measured and published. Total electron loss cross sections were measured for 20-MeV Fe4+ ions transmitted through a variety of atomic and molecular gaseous targets. All low-charge-state peaks were well resolved. The measured total cross sections per target atom for loss of one to eleven electrons in a single collision for 20-MeV Fe4+ ions transmitted through gases of N2, SF6, Ar, Kr, and Xe are shown as a function of the final charge state q. There is an overall rather steep decrease for increasing q, interrupted by a weaker decrease between q = 6 and q = 8. For the highest q values, the cross sections follow a nearly exponential decrease with q. The cross sections are smaller and the decrease at high q values is more pronounced, the lighter the target atoms. The cross sections are smaller for molecular targets than for the noble gases. 2 figures

  9. Atomic retention and near infrared photoluminescence from PbSe nanocrystals fabricated by sequential ion implantation and electron beam annealing

    International Nuclear Information System (INIS)

    Nanocrystals of PbSe have been fabricated in a silicon dioxide matrix by sequential low energy ion implantation followed by an electron beam annealing step. Transmission electron microscopy reveals PbSe nanocrystals with typical sizes between 3 and 10 nm in the sub-surface region. Rutherford Backscattering Spectrometry has been used to study the total atomic retention, as a function of implanted atoms, following annealing. Photoluminescence was observed in various samples, at 4 K, as a broad peak between 1.4 and 2.0 μm, with observation of a dependence of the peak wavelength on annealing temperature. Room temperature photoluminescence was observed for samples with a high retention of implanted atoms, demonstrating the importance of nanocrystal density for achieving ambient temperature emission in these systems

  10. Measurements of scattering processes in negative ion - atom collisions. Technical progress report - year 1, April 1, 1995--March 31, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Kvale, T.J.

    1995-12-01

    This Technical Progress Report describes the progress made on the research objectives during the past twelve months. The objective of this research project is to provide absolute cross section measurements of various scattering processes which occur in negative ion collisions with atomic (specifically, noble gas and atomic hydrogen) targets at intermediate energies. These processes include: elastic scattering, single- and double-electron detachment, and target-inelastic processes of excitation and ionization. Total cross sections for single- and double-electron detachment were recently published in Physical Review A from this research project. The researchers were successful this past year in acquiring the first cross section measurements of target excitation for H{sup -} impact on helium target atoms.

  11. Identification of Radiation-Induced Segregation in Ion-irradiated Stainless Steel 316 using Atom Probe Tomography

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Gyeong-Geun; Jin, Hyung-Ha; Chang, Kunok; Kwon, Junhyun [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2014-10-15

    Various kinds of defects are produced by the irradiation of energetic particles onto a structural material. The defect fluxes such as mobile vacancies and self-interstitial atoms cause the diffusion of the solute atoms in the matrix. The preferential interaction of the solute with defects induces the enrichment or depletion of the solutes at the defect sinks such as the grain boundaries, and surfaces. These phenomena are generally known as radiation-induced segregation (RIS). Transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDS) are generally used as basic analysis techniques to obtain a concentration profile of RIS arising from irradiation. However, the resolution of EDS is limited due to beam broadening, and the overlapping of the probed volume with the matrix prohibits a quantitative analysis of the concentration changes. In the current work, we introduced atom probe tomography (APT) to analyze RIS in SS 316. Various types of radiation-induced defects were identified and the compositional characteristics were quantitatively provided from a wide view point. The measured concentrations were compared with values in the literature. This work can provide a fundamental understanding of the RIS behavior in ion-irradiated SS 316. In this study, an APT analysis of RIS in ion-irradiated SS316 was performed. Various types of irradiation defects were observed. Si atoms are located at the core structures of dislocation loops and clusters.

  12. Number distribution of multiply emitted secondary electrons (MUSE) produced by atomic and molecular ion impacts on thin foils

    International Nuclear Information System (INIS)

    The number distribution of secondary electrons emitted through energetic ion impact on a thin carbon foil was measured. Projectile ions of 1-MeV/u He2+ or He+ passed through a carbon foil with thickness of 1 μ g/cm2 in a direction of 45o to its surface. Electrons emitted in the forward and backward directions were accelerated by a potential applied to the foil and detected by two solid state detectors (SSDs) in which pulses proportional to the electron number were formed. Transmitted ions were charge analyzed by an electrostatic deflector and detected by the third SSD. The measurement was performed in coincidence with transmitted He2+ ions and in the event-recording mode. For molecular ions, Coulomb explosion fragments, i.e., two He2+ ions were detected after passing an annular slit or conventional circular slit which selects incident molecules with molecular axes perpendicular to or parallel to the ion velocity. The average numbers of electrons emitted in the forward direction are about 1.5 times as large as those in the backward direction for atomic and molecular ions with both orientations. The width of the number distribution is generally wider than that of Poisson distribution with the same average number. Orientation dependence is not recognized in the backward direction but a slight enhancement is found for parallel orientation in the forward direction. The fact that the vicinage effect is observed only for the parallel orientation seems consistent with the density enhancement of the target electrons behind the leading ion. A negative correlation between numbers of electrons emitted in the forward and backward directions is found. (Author)

  13. Column system using diaion HP-2MG for determination of some metal ions by flame atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Tuzen, Mustafa; Soylak, Mustafa

    2004-02-23

    A column solid-phase extraction method for the preconcentration and determination of cadmium(II), copper(II), cobalt(II), iron(III), lead(II), nickel(II) and zinc(II) dithizone chelates by atomic absorption spectrometry has been described. Diaion HP-2MG was used as adsorbent for column studies. The influences of the various analytical parameters including pH of the aqueous solutions, amounts of ligand and resin were investigated for the retentions of the analyte ions. The recovery values are ranged from 95 to 102%. The influences of alkaline and earth alkaline ions were also discussed. The preconcentration factor was 375, when the sample volume and final volume are 750 and 2 ml, respectively. The detection limits of the analyte ions (k=3, N=21) were varying 0.08 {mu}g/l for cadmium to 0.25 {mu}g/l for lead. The relative standard deviations of the determinations at the concentration range of 1.8x10{sup -4} to 4.5x10{sup -5} mmol for the investigated elements were found to be lower than 9%. The proposed solid-phase extraction procedure were applied to the flame atomic absorption spectrometric determinations of analyte ions in natural waters (sea, tap, river), microwave digested samples (milk, red wine and rice) and two different reference standard materials (SRM1515 apple leaves and NRCC-SLRS-4 riverine water)

  14. A high resolution X-ray crystal spectrometer to study electron and heavy-ion impact atomic collisions

    Indian Academy of Sciences (India)

    Ajay Kumar; D Misra; A H Kelkar; U R Kadhane; K V Thulasiram; Lokesh C Tribedi

    2007-06-01

    We have studied fast ion–atom and electron–atom collision processes using a reconditioned high resolution X-ray spectrometer. The X-rays, generated by the collisions, are dispersed by a curved ADP crystal (Johansson geometry) and detected by a gas proportional counter. A self-written LabVIEW based program has been used to give precise and controlled movement to the crystal and for data acquisition. The performance was tested by detecting the K diagram and satellite lines of several elements. The K satellite lines of Al have been studied in collision with 3–12 keV electrons and 40 MeV C4+ ions. In ion collisions as large as four L-vacancies are created simultaneously with the K-vacancy, compared to two satellites in case of the e-impact. In addition, we have measured the X-rays from H-, He- and Li-like Si ions which arise due to the electron loss/capture process in highly charged 80 MeV Si7+ ions in collision with thin carbon foil. Approximate charge state distribution has been obtained using this new technique.

  15. Cross-sections for electron capture by multiply charged ions from hydrogen atoms and molecules and population of electronic states of created ions

    International Nuclear Information System (INIS)

    The cross-sections for single electron capture by alpha-particles and multiply charged ions Ne3+, Ne4+, Ar4+, Ar5+, Ar6+ from hydrogen atoms and molecules have been measured using registration of coincidences between incident and recoil ions after collision to separate this process. Population of different electronic states of ions with lower charges produced at single electron capture has been measured by collision spectroscopy method. Cross-sections for one electron capture by He2+, ArZ+ (Z = 6, 5, 4) and NeZ+ (Z = 3-4) have been measured in the kinetic energy range of incident multiply charged ions from 1xZ to 12xZ keV (Z is charge of multiply charged ions). Cross-sections for the population of electronic states at electron capture from H2 molecules have been measured in the velocity range from V = 1·107 cm/s to V5,5·107 cm/s (in the collision energy range 3.0xZ Kev - 21.0xZ KeV) at collisions of ArZ+ ions (Z=3-6) and NeZ+ (Z3-4). The double electron capture cross-sections at incident alpha-particles and hydrogen molecules collision have been measured in the energy range from 1 KeV up to 100 KeV (V=0, 235/2, 58·108 cm/s). Errors of measured values of cross-sections are ∼10-15% The results of the measurements are presented in Tables 1-8. (author)

  16. Soft-landing ion deposition of isolated radioactive probe atoms on surfaces : A novel method

    NARCIS (Netherlands)

    Laurens, CR; Rosu, MF; Pleiter, F; Niesen, L

    1997-01-01

    We present a method to deposit a wide range of radioactive probe atoms on surfaces, without introducing lattice damage or contaminating the surface with other elements or isotopes. In this method, the probe atoms are mass separated using an isotope separator, decelerated to 5 eV, and directly deposi

  17. Production of NaCa$^+$ molecular ions in the ground state from cold atom-ion mixtures by photoassociation via an intermediate state

    CERN Document Server

    Gacesa, Marko; Michels, H Harvey; Côté, Robin

    2016-01-01

    We present a theoretical analysis of optical pathways for formation of cold Ca($^1$S)Na$^+$($^1$S) molecular ions via an intermediate state. The formation schemes are based on ab initio potential energy curves and transition dipole moments calculated using effective-core-potential methods of quantum chemistry. In the proposed approach, starting from a mixture of cold trapped Ca$^+$ ions immersed into an ultracold gas of Na atoms, (NaCa)$^+$ molecular ions are photoassociated in the excited E$^{1}\\Sigma^+$ electronic state and allowed to spontaneously decay either to the ground electronic state or an intermediate state from which the population is transferred to the ground state via an additional optical excitation. By analyzing all possible pathways, we find that the efficiency of a two-photon scheme, via either B$^{1}\\Sigma^+$ or C$^{1}\\Sigma^+$ potential, is sufficient to produce significant quantities of ground state (NaCa)$^+$ molecular ions. A single-step process results in lower formation rates that wou...

  18. Production of NaCa+ molecular ions in the ground state from cold atom-ion mixtures by photoassociation via an intermediate state

    Science.gov (United States)

    Gacesa, Marko; Montgomery, John A.; Michels, H. Harvey; Côté, Robin

    2016-07-01

    We present a theoretical analysis of optical pathways for formation of cold ground-state (NaCa) + molecular ions via an intermediate state. The formation schemes are based on ab initio potential energy curves and transition dipole moments calculated using effective-core-potential methods of quantum chemistry. In the proposed approach, starting from a mixture of cold trapped Ca+ ions immersed into an ultracold gas of Na atoms, (NaCa) + molecular ions are photoassociated in the excited E +1Σ electronic state and allowed to spontaneously decay either to the ground electronic state or an intermediate state from which the population is transferred to the ground state via an additional optical excitation. By analyzing all possible pathways, we find that the efficiency of a two-photon scheme, via either the B +1Σ or C +1Σ potential, is sufficient to produce significant quantities of ground-state (NaCa) + molecular ions. A single-step process results in lower formation rates that would require either a high-density sample or a very intense photoassociation laser to be viable.

  19. Specimen Preparation and Atom Probe Field Ion Microscopy of BSCCO-2212 Superconductors

    OpenAIRE

    Larson, D; Camus, P.; Vargas, J.; Kelly, T.; Miller, M

    1996-01-01

    Field ion specimens of Bi2Sr2CaCu2Ox (BSCCO) high temperature superconductor (HTS) materials have been prepared using a combination of three different preparation techniques : the method of sharp shards, electropolishing and ion milling. Field ion microscopy (FIM) has demonstrated that samples which exhibit the "striped"-image contrast characteristic of HTS materials can be successfully fabricated using this combination. FIM images have been obtained which show the striped-image contrast much...

  20. Relativistic calculations of the K-K charge transfer and K-vacancy production probabilities in low-energy ion-atom collisions

    CERN Document Server

    Tupitsyn, I I; Shabaev, V M; Bondarev, A I; Deyneka, G B; Maltsev, I A; Hagmann, S; Plunien, G; Stoehlker, Th

    2011-01-01

    The previously developed technique for evaluation of charge-transfer and electron-excitation processes in low-energy heavy-ion collisions [I.I. Tupitsyn et al., Phys. Rev. A 82, 042701(2010)] is extended to collisions of ions with neutral atoms. The method employs the active electron approximation, in which only the active electron participates in the charge transfer and excitation processes while the passive electrons provide the screening DFT potential. The time-dependent Dirac wave function of the active electron is represented as a linear combination of atomic-like Dirac-Fock-Sturm orbitals, localized at the ions (atoms). The screening DFT potential is calculated using the overlapping densities of each ions (atoms), derived from the atomic orbitals of the passive electrons. The atomic orbitals are generated by solving numerically the one-center Dirac-Fock and Dirac-Fock-Sturm equations by means of a finite-difference approach with the potential taken as the sum of the exact reference ion (atom) Dirac-Fock...

  1. Lectures on ion-atom collisions from nonrelativistic to relativistic velocities

    CERN Document Server

    Eichler, Jörg

    2005-01-01

    Atomic collisions offer some unique opportunities to study atomic structure and reaction mechanisms in experiment and theory, especially for projectiles of high atomic number provided by modern accelerators. The book is meant as an introduction into the field and provides some basic theoretical understanding of the atomic processes occurring when a projectile hits another atom. It also furnishes the tools for a mathematical description, however, without going deeper into the technical details, which can be found in the literature given. With this aim, the focus is on reactions, in which only a single active electron participates. Collisional excitation, ionization and charge transfer are discussed for collision velocities ranging from slow to comparable to thespeed of light. For the highest projectile velocities, energy can be converted into mass, so that electron-positron pairs are created. In addition to the systematic treatment, a theoretical section specializes on electron-electroncorrelations and three...

  2. Measurements of scattering processes in negative ion-atom collisions. Technical progress report, 1 September 1992--31 August 1993

    Energy Technology Data Exchange (ETDEWEB)

    Kvale, T.J.

    1993-05-01

    This Technical Progress Report describes the progress made on the research objectives during the past twelve months. This research project is designed to provide measurements of various scattering processes which occur in H{sup {minus}} collisions with atomic (specifically, noble gas and atomic hydrogen) targets at intermediate energies. These processes include elastic scattering, single- and double-electron detachment, and target excitation/ionization. For the elastic and target inelastic processes where H{sup {minus}} is scattered intact, the experimental technique of Ion Energy-Loss Spectroscopy (IELS) will be employed to identify the final target state(s). In most of the above processes, cross sections are unknown both experimentally and theoretically. The measurements in progress will provide either experimentally determined cross sections or set upper limits to those cross sections. In either case, these measurements will be stringent tests of our understanding in energetic negative ion - atom collisions. In addition secondary negative particle emission yields for H{sup 0} on Cu in the 3 to 50 keV range are shown.

  3. Colorimetric and atomic absorption spectrometric determination of mucolytic drug ambroxol through ion-pair formation with iron and thiocyanate.

    Science.gov (United States)

    Levent, Abdulkadir; Sentürk, Zühre

    2010-09-01

    Colorimetric and atomic absorption spectrometric methods have been developed for the determination of mucolytic drug Ambroxol. These procedures depend upon the reaction of iron(III) metal ion with the drug in the presence of thiocyanate ion to form stable ion-pair complex which extractable chloroform. The red-coloured complex was determined either colorimetrically at 510 nm or by indirect atomic absorption spectrometry (AAS) via the determination of the iron content in the formed complex. The optimum experimental conditions for pH, concentrations of Fe(3+) and SCN(-), shaking time, phase ratio, and the number of extractions were determined. Under the proposed conditions, linearity was obeyed in the concentration ranges 4.1x10(-6) - 5.7x10(-5) M (1.7-23.6 µg mL(-1)) using both methods, with detection limits of 4.6x10(-7) M (0.19 µg mL(-1)) for colorimetry and 1.1x10(-6) M (0.46 µg mL(-1)) for AAS. The proposed methods were applied for the determination of Ambroxol in tablet dosage forms. The results obtained were statistically analyzed and compared with those obtained by applying the high-performance liquid chromatographic method with diode-array detection.

  4. Low-energy electron capture by C4+ ions from atomic hydrogen

    NARCIS (Netherlands)

    Bliek, FW; Hoekstra, R; Bannister, ME; Havener, CC

    1997-01-01

    The total-electron-capture cross section for collisions of C4+ with ground-state hydrogen (deuterium) is measured in the energy range 6-1000 eV/u using the merged-beam technique. The fraction of C4+ metastable ions present in the ion beam is measured to be 5%, which results in a correction to the cr

  5. Beam dynamics of a double-gap acceleration cell for ion implantation with multiple atomic species

    International Nuclear Information System (INIS)

    As a result of our work on ion implantation, we derived equations for the beam dynamics of a two-gap-resonator cavity for accelerating and bunching various ion species of varying energies with the cavity designed for one particular ion species of a given energy (the design-reference particle). A two gap structure is useful at low resonant frequencies where lumped circuit elements (inductors) can be used and the structure kept small. A single gap structure has the advantage that each gap can be independently phased to produce the desired beam dynamics behavior for various ion species and ion energies. However at low frequencies, single gap resonant structures can be large. We find that the two-gap structure, where the phase difference between gaps, for the design reference particle, is fixed at π radians can give acceptable performance provided that the individual two gap cells in the entire accelerator are optimized for the ion species having the largest mass to charge ratio and having the maximum required output energy. Our equations show how to adjust the cavity phases and electric fields to obtain equivalent first-order accelerator performance for various ion species and energies. These equations allow for the effective evaluation of various accelerator concepts and can facilitate the tuning of a linac when changing energies and ion species. Extensive simulations have confirmed the efficacy of our equations. copyright 1997 American Institute of Physics

  6. The effect of thermal vibrations of lattice atoms on the scattering of low energetic ions (2-10keV)

    International Nuclear Information System (INIS)

    An introduction to the study of solid state surfaces by analyzing the scattering behavior of low energetic noble gas ions is given. Attention is paid to thermal vibrations of the surface atoms. The scattering of Ar and Kr ions on a Cu monocrystal is discussed as an example

  7. Fast Atomic Charge Calculation for Implementation into a Polarizable Force Field and Application to an Ion Channel Protein

    Directory of Open Access Journals (Sweden)

    Raiker Witter

    2015-01-01

    Full Text Available Polarization of atoms plays a substantial role in molecular interactions. Class I and II force fields mostly calculate with fixed atomic charges which can cause inadequate descriptions for highly charged molecules, for example, ion channels or metalloproteins. Changes in charge distributions can be included into molecular mechanics calculations by various methods. Here, we present a very fast computational quantum mechanical method, the Bond Polarization Theory (BPT. Atomic charges are obtained via a charge calculation method that depend on the 3D structure of the system in a similar way as atomic charges of ab initio calculations. Different methods of population analysis and charge calculation methods and their dependence on the basis set were investigated. A refined parameterization yielded excellent correlation of R=0.9967. The method was implemented in the force field COSMOS-NMR and applied to the histidine-tryptophan-complex of the transmembrane domain of the M2 protein channel of influenza A virus. Our calculations show that moderate changes of side chain torsion angle χ1 and small variations of χ2 of Trp-41 are necessary to switch from the inactivated into the activated state; and a rough two-side jump model of His-37 is supported for proton gating in accordance with a flipping mechanism.

  8. Pickup Ion Production in the Global Heliosphere and Heliosheath and Their Diagnostics by Fluxes of Energetic Neutral Atoms

    Science.gov (United States)

    Wu, Y.

    2015-12-01

    An anisotropic particle transport model, based on an expansion of a focused transport equation in Legendre polynomials, is used here as a tool to analyze the distributions of pickup ions (PUIs) in the heliosphere and heliosheath. A three-dimensional, MHD-kinetic model for flows of a thermal plasma, neutral atoms and PUIs has been developed. The preliminary results from our model are in qualitative agreement with observations made by New Horizons, Ulysses, Voyager 1 and 2. All-sky maps of energetic neutral atoms (ENA) fluxes with energies of about 0.2-6 keV based on our current PUI model are qualitatively similar to IBEX-Hi distributed ENA maps. Also, simulated spectra of ENA fluxes nearly match IBEX-Hi spectra of distributed ENA fluxes. It is demonstrated that preserving some pitch-angle information of the PUI distribution is important for correctly interpreting the data.

  9. Measurements of scattering processes in negative ion: Atom collisions. Technical progress report, 1 September 1991--31 December 1994

    Energy Technology Data Exchange (ETDEWEB)

    Kvale, T.J.

    1994-09-27

    This report describes the progress made on the research objectives during the past three years of the grant. This research project is designed to study various scattering processes which occur in H{sup {minus}} collisions with atomic (specifically, noble gas and atomic hydrogen) targets in the intermediate energy region. These processes include: elastic scattering, single- and double-electron detachment, and target excitation/ionization. For the elastic and target inelastic processes where H{sup {minus}} is scattered intact, the experimental technique of Ion Energy-Loss Spectroscopy (IELS) will be employed to identify the final target state(s). In most of the above processes, cross sections are unknown both experimentally and theoretically. The measurements will provide total cross sections (TCS) initially, and once the angular positioning apparatus is installed, will provide angular differential cross sections (ADCS).

  10. Atomic data and spectral analysis of carbon, nitrogen, oxygen and silicon ions observed with the International Ultraviolet Explorer

    Science.gov (United States)

    Pradhan, Anil K.

    1992-01-01

    According to the plan presented in the original proposal we have now completed most of the atomic calculations involving collision strengths and rate coefficients for electron impact excitation of C II, N III, and O IV ions. These have been reported in the first two publications appended with this report. We have now moved into the applications phase of the project with the new data being used to analyze the International Ultraviolet Explorer (IUE) observations of a variety of objects, as described in the third publication recently submitted (also appended). The analysis and interpretation of archival data will continue well into the next year with several collaborators that the PI and Co-PI are involved with. In addition, the atomic calculations on Si II have been started.

  11. High-resolution X-ray study of the multiple ionization of Pd atoms by fast oxygen ions

    OpenAIRE

    Czarnota, M.; Banaś, D.; Berset, Michel; Chmielewska, D; Dousse, Jean-Claude; Hoszowska, Joanna; Maillard, Yves-Patrick; Mauron, Olivier; Pajek, M.; Polasik, M.; Raboud, Pierre-Alexandre; Rzadkiewicz, J.; Słabkowska, K.; Sujkowski, Z.

    2010-01-01

    The multiple ionization of the L- and M-shells of Pd by fast oxygen ions has been studied by measuring with high-resolution the satellite structures of the Lα1,2 X-ray transitions. Relativistic multi-configuration Dirac-Fock (MCDF) calculations were used to interpret the complex X-ray spectrum, allowing to derive the number of L- and M-shell spectator vacancies at the moment of the X-ray emission. After correcting these numbers for the atomic vacancy rearrangement processes that take place pr...

  12. Many-electron relativistic calculation and interpretation of atomic processes in time dependent heavy-ion scattering

    Science.gov (United States)

    Thies, B.; Sepp, W.-D.; Fricke, B.

    1989-07-01

    The time dependence of a heavy-ion-atom collision system is solved via a set of coupled channel equations using energy eigen-values and matrix elements from a self-consistent field relativistic molecular many-electron Dirac-Fock-Slater calculation. Within this independent particle model we give a full many-particle interpretation by performing a small number of single-particle calculations. First results for the P( b) curves for the Ne K-hole excitation for the systems F 8+-Ne and F 6+-Ne as examples are discussed.

  13. Atomic data for neutron-capture elements I. Photoionization and recombination properties of low-charge selenium ions

    CERN Document Server

    Sterling, N C

    2011-01-01

    We present multi-configuration Breit-Pauli AUTOSTRUCTURE calculations of distorted-wave photoionization (PI) cross sections, and total and partial final-state resolved radiative recombination (RR) and dielectronic recombination (DR) rate coefficients for the first six ions of the trans-iron element Se. These calculations were motivated by the recent detection of Se emission lines in a large number of planetary nebulae. Se is a potentially useful tracer of neutron-capture nucleosynthesis, but accurate determinations of its abundance in photoionized nebulae have been hindered by the lack of atomic data governing its ionization balance. Our calculations were carried out in intermediate coupling with semi-relativistic radial wavefunctions. PI and recombination data were determined for levels within the ground configuration of each ion, and experimental PI cross-section measurements were used to benchmark our results. For DR, we allowed dn=0 core excitations, which are important at photoionized plasma temperatures...

  14. Relevant effects of localized atomic interactions and surface density of states on charge transfer in ion-surface collisions

    Energy Technology Data Exchange (ETDEWEB)

    Bonetto, F.; Romero, M.A.; Garcia, E.A.; Vidal, R.; Ferron, J.; Goldberg, E.C. [Instituto de Desarrollo Tecnologico para la Industria Quimica, Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), Santa Fe (Argentina); Ferron, J.; Goldberg, E.C. [Universidad Nacional del Litoral, J., Dept. de Ingenieria de Materiales, Facultad de Ingenieria Quimica, Santa Fe (Argentina)

    2007-12-15

    Through a time-dependent quantum-mechanical calculation of the H{sup +} scattering by a highly oriented pyrolytic graphite (HOPG) surface, we are able to satisfactorily reproduce the interesting features we observed in ion scattering experiments in H{sup +}/HOPG system. We found that the combined effects of the semimetal character of HOPG together with the localized nature of the carbon atom states primarily determine the angular dependence and the magnitude of the ion fractions for large outgoing angles. The spin fluctuation effects (not considered in the present calculation) are discussed as one of the the main causes of the disagreement between the spinless theory results and the experiments for small exit angles. (authors)

  15. Spectral distribution of the 2 → 1 two-photon transition in atoms and few-electron ions

    Indian Academy of Sciences (India)

    Ajay Kumar; S Trotsenko; A V Volotka; D Banaś; H F Beyer; H Bräuning; S Fritzsche; A Gumberidze; S Hagmann; S Hess; C Kozhuharov; R Reuschl; U Spillmann; M Trassinelli; G Weber; Th Stöhlker

    2011-02-01

    The two-photon decay of the 2 state to the ground state in dressed atoms and oneor two-electron ions has been studied for several decades. Relativistic calculations have shown an -dependence of the spectral shape of this two-photon transition in one- or two-electron ions. We have measured the spectral distribution of the 121 0 → 12 1 0 two-photon transition in He-like tin at the ESR storage ring using a new approach for such experiments. In this method, relativistic collisions of initially Li-like projectiles with a gaseous target were used to populate exclusively the first excited state, 12, of He-like tin, which provided a clean two-photon spectrum. The measured two-photon spectral distribution was compared with fully relativistic calculations. The obtained results show very good agreement with the calculations for He-like tin

  16. Excitation of atoms and molecules in collisions with highly charged ions

    International Nuclear Information System (INIS)

    A study of the double ionization of He by high-energy N7+ ions was extended up in energy to 40 MeV/amu. Coincidence time-of-flight studies of multicharged N2, O2, and CO molecular ions produced in collisions with 97-MeV Ar14+ ions were completed. Analysis of the total kinetic energy distributions and comparison with the available data for CO2+ and CO3+ from synchrotron radiation experiments led to the conclusion that ionization by Ar-ion impact populates states having considerably higher excitation energies than those accessed by photoionization. The dissociation fractions for CO1+ and CO2+ molecular ions, and the branching ratios for the most prominent charge division channels of CO2+ through CO7+ were determined from time-of-flight singles and coincidence data. An experiment designed to investigate the orientation dependence of dissociative multielectron ionization of molecules by heavy ion impact was completed. Measurements of the cross sections for K-shell ionization of intermediate-Z elements by 30-MeV/amu H, N, Ne, and Ar ions were completed. The cross sections were determined for solid targets of Z = 13, 22, 26, 29, 32, 40, 42, 46, and 50 by recording the spectra of K x rays with a Si(Li) spectrometer

  17. Kinetics of interlayer ion migration in non-swelling clays: An atomic-scale study

    Science.gov (United States)

    Lammers, L. N.; Kolluri, K.

    2015-12-01

    Clay-rich geologic repositories serve as hosts for fossil methane reserves and as traps for contaminant radionuclides and sequestered CO2. Despite the abundance of non-swelling clay minerals in sedimentary formations, the mechanisms of ion exchange and mass transport mediated by these minerals are not well understood. Ion exchange kinetics in collapsed clays are characterized by a long tail of slow exchange, which suggests that interlayer ions can exchange with the bulk solution. Recent High-Resolution TEM evidence suggests that Cs+ ion exchange K+ in collapsed interlayers leads to interstratified structures, where entire interlayers are completely exchanged while others remain pristine [Okamura T et al., (2005) Microscopy 6365-72]. This phenomenon could be explained by kinetic feedbacks arising when a larger ion substitutes for a smaller one, although the details of this exchange mechanism are currently unknown. We investigated the kinetics and mechanisms of interlayer cation migration in illite (K0.7Al2[Al0.7Si3.3O10](OH)2) using molecular simulations. A Monte Carlo scheme was used to distribute interlayer K ions, and these ions were found to prefer sites neighboring two or more Al3+ substitutions in the tetrahedral sheets. Interlayer K+ ion migration between stable ditrigonal cavity sites was observed directly in molecular dynamics simulations performed at temperatures ranging from 500 K to 900 K and at constant volume. The Climbing Image Nudged Elastic Band method was used to determine the activation energy barrier on 660 K+ ion migration paths. Interlayer ions were observed to migrate between stable lattice sites with migration barriers of 2.35 ± 1.06 eV. Only about 20% of this variation is statistically explained by the distribution of charge deficit sites in the layer caused by Al3+ substitution for Si4+. Remarkably, we find that migration barriers decrease as we increase interlayer spacing. These results suggest that frayed edge sites - local regions with

  18. Angular distribution of sputtered atoms induced by low-energy heavy ion bombardment

    Institute of Scientific and Technical Information of China (English)

    ZHANG Lai; ZHANG Zhu-Lin

    2004-01-01

    The sputtering yield angular distributions have been calculated based on the ion energy dependence of total sputtering yields for Ni and Motargets bombarded by low-energy Hg+ ion. The calculated curves show excellent agreement with the corresponding Wehner's experimental results of sputtering yield angular distribution. The fact clearly demonstrated the intrinsic relation between the ion energy dependence of total sputtering yields and the sputtering yield angular distribution. This intrinsic relation had been ignored in Yamamura's papers (1981,1982) due to some obvious mistakes.

  19. Setup and proof of principle of SAPIS (Stored Atoms Polarized Ion Source), a novel source of polarized H-/D- ions

    International Nuclear Information System (INIS)

    The objective of this work was the setup and the proof-of-principle of a new type of negative polarized hydrogen or deuterium ion source, which is based on the charge-exchange reaction vectorH0+Cs0→vectorH-+Cs+, as for instance the Colliding-Beams-Source (CBS) at the Cooler Synchrotron COSY in Juelich. In contrast to the CBS, the use of a storage cell for the charge-exchange region promises an increase in H- current by at least an order of magnitude without considerable polarization losses. For these purposes, a new laboratory was equipped and both a polarized hydrogen/deuterium atomic beam source and an intense neutral cesium-beam source have been build-on. A Lambshift polarimeter, which allows the measurement of the nuclear polarization of the atomic as well as ionic beams, was completed with the construction of a new spin-filter. After commissioning and optimizing each of these sources, a storage cell was developed and installed in the charge-exchange region with a magnetic field. Additionally, components for the extraction, detection and analysis of the negative ion beam were installed. Following the decisive proof of principle, investigation of the properties of the storage cell, especially as to H recombination and depolarisation, was begun. Furthermore, a number of software programs was developed for the control and monitoring of different components of the sources as well as a universal measuring software for the complete installation, including the measurement and calculation of the beam polarization. At the same time, the remote control system of the Cologne source of polarized ions LASCO at the FN tandem accelerator was completely modernized. (orig.)

  20. Cloud point extraction and flame atomic absorption spectrometry combination for copper(II) ion in environmental and biological samples

    Energy Technology Data Exchange (ETDEWEB)

    Shokrollahi, Ardeshir [Chemistry Department, Yasouj University, Yasouj 75914-353 (Iran, Islamic Republic of)], E-mail: ashokrollahi@mail.yu.ac.ir; Ghaedi, Mehrorang [Chemistry Department, Yasouj University, Yasouj 75914-353 (Iran, Islamic Republic of)], E-mail: m_ghaedi@mail.yu.ac.ir; Hossaini, Omid; Khanjari, Narges [Chemistry Department, Yasouj University, Yasouj 75914-353 (Iran, Islamic Republic of); Soylak, Mustafa [Chemistry Department, University of Erciyes, 38039 Kayseri (Turkey)

    2008-12-30

    A cloud point extraction procedure was presented for the preconcentration of copper(II) ion in various samples. After complexation by 4-(phenyl diazenyl) benzene-1,3-diamine (PDBDM) (chrysoidine), copper(II) ions were quantitatively recovered in Triton X-114 after centrifugation. 0.5 ml of methanol acidified with 1.0 mol L{sup -1} HNO{sub 3} was added to the surfactant-rich phase prior to its analysis by flame atomic absorption spectrometry (FAAS). The influence of analytical parameters including ligand, Triton X-114 and HNO{sub 3} concentrations, bath temperature, heating time, centrifuge rate and time were optimized. The effect of the matrix ions on the recovery of copper(II) ions was investigated. The detection limit (3S.D.{sub b}/m, n = 10) of 0.6 ng mL{sup -1} along with preconcentration factor of 30 and enrichment factor of 41.1 with R.S.D. of 1.0% for Cu was achieved. The proposed procedure was applied to the analysis of various environmental and biological samples.

  1. Microstructural evolution of Fesbnd 22%Cr model alloy under thermal ageing and ion irradiation conditions studied by atom probe tomography

    Science.gov (United States)

    Korchuganova, Olesya A.; Thuvander, Mattias; Aleev, Andrey A.; Rogozhkin, Sergey V.; Boll, Torben; Kulevoy, Timur V.

    2016-08-01

    Nanostructure evolution during ion irradiation of two thermally aged binary Fee22Cr alloys has been investigated using atom probe tomography. Specimens aged at 500 °C for 50 and 200 h were irradiated by 5.6 MeV Fe ions at room temperature up to fluences of 0.3 × 1015 ions/cm2 and 1 × 1015 ions/cm2. The effect of irradiation on the material nanostructure was examined at a depth of 1 μm from the irradiated surface. The analysis of Cr radial concentration functions reveals that dense α‧-phase precipitates in the 200 h aged alloy become diffuse and thereby larger when subjected to irradiation. On the other hand, less Cr-enriched precipitates in the alloy aged for 50 h are less affected. The CreCr pair correlation function analysis shows that matrix inhomogeneity decreases under irradiation. Irradiation leads to a decrease in the number density of diffuse clusters, whereas in the case of well-developed precipitates it remains unchanged.

  2. Role of low-energy ion irradiation in the formation of an aluminum germanate layer on a germanium substrate by radical-enhanced atomic layer deposition

    Energy Technology Data Exchange (ETDEWEB)

    Fukuda, Yukio, E-mail: y-fukuda@rs.suwa.tus.ac.jp; Yamada, Daichi; Yokohira, Tomoya; Yanachi, Kosei [Tokyo University of Science, Suwa, 5000-1 Toyohira, Chino, Nagano 391-0292 (Japan); Yamamoto, Chiaya; Yoo, Byeonghak; Sato, Tetsuya [University of Yamanashi, 4-3-11 Takeda, Kofu, Yamanashi 400-8511 (Japan); Yamanaka, Junji [University of Yamanashi, 7-32 Miyamae, Kofu, Yamanashi 400-8511 (Japan); Takamatsu, Toshiyuki [SST Inc., 989-6 Shimadadai, Yachiyo, Chiba 276-0004 (Japan); Okamoto, Hiroshi [Hirosaki University, 3 Bunkyo, Hirosaki 036-8561 (Japan)

    2016-03-15

    Radical-enhanced atomic layer deposition uses oxygen radicals generated by a remote microwave-induced plasma as an oxidant to change the surface reactions of the alternately supplied trimethylaluminum precursor and oxygen radicals on a Ge substrate, which leads to the spontaneous formation of an aluminum germanate layer. In this paper, the effects that low-energy ions, supplied from a remote microwave plasma to the substrate along with the oxygen radicals, have on the surface reactions were studied. From a comparative study of aluminum oxide deposition under controlled ion flux irradiation on the deposition surface, it was found that the ions enhance the formation of the aluminum germanate layer. The plasma potential measured at the substrate position by the Langmuir probe method was 5.4 V. Assuming that the kinetic energy of ions arriving at the substrate surface is comparable to that gained by this plasma potential, such ions have sufficient energy to induce exchange reactions of surface-adsorbed Al atoms with the underlying Ge atoms without causing significant damage to the substrate. This ion-induced exchange reaction between Al and Ge atoms is inferred to be the background kinetics of the aluminum germanate formation by radical-enhanced atomic layer deposition.

  3. Algebraic tools for dealing with the atomic shell model. I. Wavefunctions and integrals for hydrogen-like ions

    Science.gov (United States)

    Surzhykov, Andrey; Koval, Peter; Fritzsche, Stephan

    2005-01-01

    Today, the 'hydrogen atom model' is known to play its role not only in teaching the basic elements of quantum mechanics but also for building up effective theories in atomic and molecular physics, quantum optics, plasma physics, or even in the design of semiconductor devices. Therefore, the analytical as well as numerical solutions of the hydrogen-like ions are frequently required both, for analyzing experimental data and for carrying out quite advanced theoretical studies. In order to support a fast and consistent access to these (Coulomb-field) solutions, here we present the DIRAC program which has been developed originally for studying the properties and dynamical behavior of the (hydrogen-like) ions. In the present version, a set of MAPLE procedures is provided for the Coulomb wave and Green's functions by applying the (wave) equations from both, the nonrelativistic and relativistic theory. Apart from the interactive access to these functions, moreover, a number of radial integrals are also implemented in the DIRAC program which may help the user to construct transition amplitudes and cross sections as they occur frequently in the theory of ion-atom and ion-photon collisions. Program summaryTitle of program:DIRAC Catalogue number: ADUQ Program summary URL:http://cpc.cs.qub.ac.uk/summaries/ADUQ Program obtainable from: CPC Program Library, Queen's University of Belfast, N. Ireland Licensing provisions: None Computer for which the program is designed and has been tested: All computers with a license of the computer algebra package MAPLE [1] Program language used: Maple 8 and 9 No. of lines in distributed program, including test data, etc.:2186 No. of bytes in distributed program, including test data, etc.: 162 591 Distribution format: tar gzip file CPC Program Library subprograms required: None Nature of the physical problem: Analytical solutions of the hydrogen atom are widely used in very different fields of physics [2,3]. Despite of the rather simple structure

  4. Cascade Problems in Some Atomic Lifetime Measurements at a Heavy-Ion Storage Ring

    Energy Technology Data Exchange (ETDEWEB)

    Trabert, E; Hoffmann, J; Krantz, C; Wolf, A; Ishikawa, Y; Santana, J

    2008-10-09

    Lifetimes of 3s{sup 2}3p{sup k} ground configuration levels of Al-, Si-, P-, and S-like ions of Be, Co, and Ni have been measured at a heavy-ion storage ring. Some of the observed decay curves show strong evidence of cascade repopulation from specific 3d levels that feature lifetimes in the same multi-millisecond range as the levels of the ground configuration.

  5. Preliminary measurements of doubly differential cross sections for ejection of electrons from atomic and molecular hydrogen by 70-keV helium ions

    International Nuclear Information System (INIS)

    A mixture of atomic and molecular hydrogen, generated by a Slevin hydrogen atom source, was used as the target for 70-keV He+ ions. Procedures were devised to extract the ratio of the cross sections for hydrogen atoms to hydrogen molecules. The cross sections for hydrogen molecules were then measured separately and the cross sections for hydrogen atoms obtained. The cross sections for ejection of electrons, differential in the angle and energy of ejection, were measured over the 15 degrees-160 degrees range of angles and at electron energies from 1.5 to 130 eV

  6. Preliminary measurements of doubly differential cross sections for ejection of electrons from atomic and molecular hydrogen by 70-keV helium ions

    Energy Technology Data Exchange (ETDEWEB)

    Hsu, Y.Y.; Gealy, M.W.; Kerby, G.W.; Rudd, M.E. [Univ. of Nebraska, Lincoln, NB (United States)

    1993-05-01

    A mixture of atomic and molecular hydrogen, generated by a Slevin hydrogen atom source, was used as the target for 70-keV He{sup +} ions. Procedures were devised to extract the ratio of the cross sections for hydrogen atoms to hydrogen molecules. The cross sections for hydrogen molecules were then measured separately and the cross sections for hydrogen atoms obtained. The cross sections for ejection of electrons, differential in the angle and energy of ejection, were measured over the 15{degrees}-160{degrees} range of angles and at electron energies from 1.5 to 130 eV.

  7. Influence of electron motion in target atom on stopping power for low-energetic ions

    Directory of Open Access Journals (Sweden)

    Stevanović Nenad

    2012-01-01

    Full Text Available In this paper the stopping power was calculated, representing the electrons of the target atom as an assembly of quantum oscillators. It was considered that the electrons in the atoms have some velocity before interaction with the projectile, which is the main contribution of this paper. The influence of electron velocity on stopping power for different projectiles and targets was investigated. It was found that the velocity of the electron stopping power has the greatest influence at low energies of the projectile.

  8. Preconcentration of gold ions from water samples by modified organo-nanoclay sorbent prior to flame atomic absorption spectrometry determination

    Energy Technology Data Exchange (ETDEWEB)

    Afzali, Daryoush, E-mail: daryoush_afzali@yahoo.com [Nanochemistry Department, Research Institute of Environmental Sciences, International Center for Science, High Technology and Environmental Sciences, Kerman (Iran, Islamic Republic of); Mostafavi, Ali [Chemistry Department, Shahid Bahonar University of Kerman, Kerman (Iran, Islamic Republic of); Mirzaei, Mohammad [Nanochemistry Department, Research Institute of Environmental Sciences, International Center for Science, High Technology and Environmental Sciences, Kerman (Iran, Islamic Republic of); Chemistry Department, Shahid Bahonar University of Kerman, Kerman (Iran, Islamic Republic of)

    2010-09-15

    In this work, the applicability of modified organo nanoclay as a new and easy prepared solid sorbent for the preconcentration of trace amounts of Au(III) ion from water samples is studied. The organo nanoclay was modified with 5-(4'-dimethylamino benzyliden)-rhodanine and used as a sorbent for separation of Au(III) ions. The sorption of gold ions was quantitative in the pH range of 2.0-6.0. Quantitative desorption occurred with 6.0 mL of 1.0 mol L{sup -1} Na{sub 2}S{sub 2}O{sub 3}. The amount of eluted Au(III) was measured using flame atomic absorption spectrometry. In the initial solution the linear dynamic range was in the range of 0.45 ng mL{sup -1} to 10.0 {mu}g mL{sup -1}, the detection limit was 0.1 ng mL{sup -1} and the preconcentration factor was 105. Also, the relative standard deviation was {+-}2.3% (n = 8 and C = 2.0 {mu}g mL{sup -1}) and the maximum capacity of the sorbent was 3.9 mg of Au(III) per gram of modified organo nanoclay. The influences of the experimental parameters including sample pH, eluent volume and eluent type, sample volume, and interference of some ions on the recoveries of the gold ion were investigated. The proposed method was applied for preconcentration and determination of gold in different samples.

  9. On the role of atomic metastability in the production of Balmer line radiation from ‘cold’ atomic hydrogen, deuterium and hydrogenic ion impurities in fusion edge plasmas

    Science.gov (United States)

    Hey, J. D.

    2012-03-01

    Published arguments, which assign an important role to atomic metastability in the production of ‘narrow’ Zeeman component radiation from the boundary region of fusion plasmas, are examined critically in relation to l-redistribution by proton and electron collisions, and mixing of unperturbed atomic states by the ion microfield and microfield gradient. It is concluded that these important processes indeed severely constrain the contribution from ‘metastable’ states to the generation of the hydrogen Balmer spectra, for electron concentrations above 1012 cm-3, as pointed out before by the present author (Hey et al 1999 J. Phys. B: At. Mol. Opt. Phys. 32 3555). The analysis of collision-induced l-redistribution represents an extension of that used previously (Hey et al 1996 Contrib. Plasma Phys. 36 583), applicable up to higher electron densities. For comparison purposes, we also consider the question of metastability of ionized helium in a low-temperature plasma, and that of some common hydrogenic impurities (C5+ and Ne9+) in a hydrogen (deuterium) fusion plasma. While for low nuclear charge Z the metastability of 2s1/2 levels is quenched by the plasma environment, it is much reduced in high-Z ions owing to the rapid increase with Z of the two-photon electric dipole (2E1) and magnetic dipole (M1) spontaneous transition rates to the ground state, whereas the role of the plasma in these cases is less important. The main new principle elaborated in this work is the sensitivity of atomic line strengths, and hence collision strengths, to perturbation by the plasma environment for transitions between fine-structure sublevels of the same principal quantum number. As the plasma microfield strength grows, ‘allowed’ transitions diminish in strength, while ‘forbidden’ transitions grow. However, owing to violation of the parity selection rule, there is an overall loss of collision strength available to transitions, resulting from the appearance of significant

  10. Evaluation of interaction between histidine binding Cu2+ ion and histidine by atomic force microscopy.

    Science.gov (United States)

    Kim, Jong Min; Lee, Haeng-Ja; Kim, Woo-Sik; Sano, Masato; Muramatsu, Hiroshi; Chang, Sang-Mok

    2012-07-01

    This paper presents a direct interaction force measurement between histidine molecules using AFM force-distance curve measurement. AFM force-distance curves between the histidine-modified cantilever and substrate in the different conditions with or without intercalating Cu2+ ion were measured and interpreted via Gaussian curve fitting analyses. The adhesion force between histidine molecules was shown to be 110 pN under the presence of Cu2+. The result was compareable to the measured adhesion force about 0 pN, which was measured by the removal of Cu2+ ion with the addition of EDTA. The result indicated the direct histidine-histidie interaction was difficult without the role of the bridigible ionic component. From the results, the possibility of direct measurement on chemical affinities between biomolecules was suggested by using AFM force-distance curve analyses. Especially, the current approach showed the possible affinity measurement techniques that elucidate the role of bridge ions. PMID:22966539

  11. Interaction of atomic and low-energy deuterium with tungsten pre-irradiated with self-ions

    Science.gov (United States)

    Ogorodnikova, O. V.; Markelj, S.; von Toussaint, U.

    2016-02-01

    Polycrystalline tungsten (W) specimens were pre-irradiated with self-ions to create identical samples with high density of defects up to ˜2.5 μm near the surface. Then, W specimens were exposed to either thermal atomic deuterium (D) beam with an incident energy of ˜0.2 eV or low energy D plasma with the incident energy varied between 5 and 200 eV at different sample temperatures. Each sample was exposed once at certain temperature and fluence. The D migration and accumulation in W were studied post-mortem by nuclear reaction method. It was shown that the rate of the D to occupy radiation-induced defects increases with increasing the incident energy, ion flux, and temperature. Experimental investigation was accompanied by modelling using the rate-equation model. Moreover, the analytical model was developed and benchmarked against numerical model. The calculations of the deuterium diffusion with trapping at radiation-induced defects in tungsten by analytical model are consistent with numerical calculations using rate-equation model. The data of reflection and penetration of atomic and low-energy D were taking from calculations using molecular dynamics (MD) with Juslin interatomic potentials and a binary collision code TRIM. MD calculations show an agreement with a binary collision code TRIM only in a very narrow range of deuterium energies between 1 and 20 eV. Incorporation of the data of reflection and penetration of deuterium in the macroscopic modelling has been done to verify the range of validity of calculations using MD and binary collision code TRIM by comparison of modelling results with experimental data. Modelling results are consistent with experiments using reflection and penetration data of D obtained from TRIM code for incident ion energy above 1 eV. Otherwise, the parameters obtained from MD should be incorporated in the rate-equation model to have a good agreement with the experiments.

  12. Interaction of atomic and low-energy deuterium with tungsten pre-irradiated with self-ions

    Energy Technology Data Exchange (ETDEWEB)

    Ogorodnikova, O. V., E-mail: igra32@rambler.ru [National Research Nuclear University “MEPHI,” Kashirskoe sh. 31, Moscow (Russian Federation); Markelj, S. [Jožef Stefan Institute, Jamova cesta 39, 1000 Ljubljana (Slovenia); Toussaint, U. von [Max-Planck-Institut für Plasmaphysik, Boltzmannstr. 2, D-85748 Garching (Germany)

    2016-02-07

    Polycrystalline tungsten (W) specimens were pre-irradiated with self-ions to create identical samples with high density of defects up to ∼2.5 μm near the surface. Then, W specimens were exposed to either thermal atomic deuterium (D) beam with an incident energy of ∼0.2 eV or low energy D plasma with the incident energy varied between 5 and 200 eV at different sample temperatures. Each sample was exposed once at certain temperature and fluence. The D migration and accumulation in W were studied post-mortem by nuclear reaction method. It was shown that the rate of the D to occupy radiation-induced defects increases with increasing the incident energy, ion flux, and temperature. Experimental investigation was accompanied by modelling using the rate-equation model. Moreover, the analytical model was developed and benchmarked against numerical model. The calculations of the deuterium diffusion with trapping at radiation-induced defects in tungsten by analytical model are consistent with numerical calculations using rate-equation model. The data of reflection and penetration of atomic and low-energy D were taking from calculations using molecular dynamics (MD) with Juslin interatomic potentials and a binary collision code TRIM. MD calculations show an agreement with a binary collision code TRIM only in a very narrow range of deuterium energies between 1 and 20 eV. Incorporation of the data of reflection and penetration of deuterium in the macroscopic modelling has been done to verify the range of validity of calculations using MD and binary collision code TRIM by comparison of modelling results with experimental data. Modelling results are consistent with experiments using reflection and penetration data of D obtained from TRIM code for incident ion energy above 1 eV. Otherwise, the parameters obtained from MD should be incorporated in the rate-equation model to have a good agreement with the experiments.

  13. Multi-element coprecipitation for separation and enrichment of heavy metal ions for their flame atomic absorption spectrometric determinations

    International Nuclear Information System (INIS)

    A preconcentration-separation technique for lead(II), cadmium(II), chromium(III), nickel(II) and manganese(II) ions has been established. The procedure is based on coprecipitation of these ions by the aid of Cu(II)-dibenzyldithiocarbamate precipitate. The precipitate was dissolved in 0.5 mL of concentrated HNO3, and made up to 5 mL with distilled water. The heavy metals were determined by flame atomic absorption spectrometer. The effects of analytical parameters like pH, amounts of reagents, sample volume, etc. on the recoveries of heavy metals were investigated. The influences of matrix ions were also examined. The detection limits for the heavy metals based on 3 sigma (N = 21) were found in the range of 0.34-0.87 μg L-1. In order to validate the proposed method, two certified reference materials of NIST SRM 2711 Montana soil and NIST SRM 1515 Apple leaves were analyzed with satisfactory results. The proposed method was applied for the determination of lead, cadmium, chromium, nickel and manganese in environmental samples

  14. Cloud point extraction for the determination of copper, nickel and cobalt ions in environmental samples by flame atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Ghaedi, M. [Chemistry Department, University of Yasouj, Yasouj 75914-353 (Iran, Islamic Republic of)], E-mail: m_ghaedi@mail.yu.ac.ir; Shokrollahi, A.; Ahmadi, F.; Rajabi, H.R. [Chemistry Department, University of Yasouj, Yasouj 75914-353 (Iran, Islamic Republic of); Soylak, M. [Chemistry Department, University of Erciyes, 38039 Kayseri (Turkey)

    2008-02-11

    A cloud point extraction procedure was presented for the preconcentration of copper, nickel and cobalt ions in various samples. After complexation with methyl-2-pyridylketone oxime (MPKO) in basic medium, analyte ions are quantitatively extracted to the phase rich in Triton X-114 following centrifugation. 1.0 mol L{sup -1} HNO{sub 3} nitric acid in methanol was added to the surfactant-rich phase prior to its analysis by flame atomic absorption spectrometry (FAAS). The adopted concentrations for MPKO, Triton X-114 and HNO{sub 3}, bath temperature, centrifuge rate and time were optimized. Detection limits (3 SDb/m) of 1.6, 2.1 and 1.9 ng mL{sup -1} for Cu{sup 2+}, Co{sup 2+} and Ni{sup 2+} along with preconcentration factors of 30 and for these ions and enrichment factor of 65, 58 and 67 for Cu{sup 2+}, Ni{sup 2+} and Co{sup 2+}, respectively. The high efficiency of cloud point extraction to carry out the determination of analytes in complex matrices was demonstrated. The proposed procedure was applied to the analysis of biological, natural and wastewater, soil and blood samples.

  15. Hybrid compounds of Keggin polyoxotungstate with transition metal ion as the central atom. Synthesis, structure and properties

    Science.gov (United States)

    Li, Xiao-Min; Chen, Ya-Guang; Shi, Tian

    2016-02-01

    The compounds (Hbipy)2[Co(bipy)2(H2O)4]2(CoW12O40)·2bipy·7H2O (1) and [Ni2(Hbipy)2(bipy)(H2O)4(H2W12O40)]·5H2O (2) (bipy = 4,4-bipyridine) were synthesized hydrothermally and characterized by elemental analysis, IR spectroscopy, TG analyses, solid ultraviolet diffuse spectroscopy and single crystal X-ray diffraction method. In 1 the complex ions, [Co(bipy)2(H2O)4]2+, construct a supramolecular layer through π-π stacking interaction. The heteropolyanions with central Co atom and supramolecular layers are linked by hydrogen bonds. In 2 a 2D structure is formed from metatungstate anions and binuclear Ni-bipy complexes through the coordination of metatungstate anions and bipy to Ni ions. Between the layers and bipyridine molecules are the hydrogen bond interactions. The formation of 1 and 2 shows that the solution acidity and metal ions influence greatly the structure of the compounds. Solid ultraviolet diffusion results indicate that the compounds 1 and 2 are potential semiconductor materials. In 1 and 2 there exists a weak antiferromagnetic interaction.

  16. Absolute Transition Probabilities of Lines in the Spectra of Astrophysical Atoms, Molecules, and Ions

    Science.gov (United States)

    Parkinson, W. H.; Smith, P. L.; Yoshino, K.

    1984-01-01

    Progress in the investigation of absolute transition probabilities (A-values or F values) for ultraviolet lines is reported. A radio frequency ion trap was used for measurement of transition probabilities for intersystem lines seen in astronomical spectra. The intersystem line at 2670 A in Al II, which is seen in pre-main sequence stars and symbiotic stars, was studied.

  17. Photoassociative ionization of cold Na atoms: repulsive levels effects on the ion production rate

    Science.gov (United States)

    Paiva, R. R.; Muhammad, R.; Shiozaki, R. F.; de Oliveira, A. L.; Magalhães, D. V.; Ramirez-Serrano, J.; Bagnato, V. S.; Magalhães, K. M. F.

    2009-02-01

    We have revisited photoassociative ionization (PAI) in a cold sample of Na atoms. A two-color experiment was performed in a magneto-optical trap through the addition of a probe laser. The observation of a marked change in the PAI rate for a definite frequency range can be attributed to the influence of repulsive levels and a possible avoided crossing between long-range molecular levels.

  18. Ionization cross sections of state selective atomic hydrogen by impact of multiply charged ions

    International Nuclear Information System (INIS)

    Ionization cross sections of atomic hydrogen in ground state and in metastable 2s state in collision with bare projectiles over a wide energy range have been calculated. The final state wave function considers the distortion due to Coulomb fields of both the projectile and the target nucleus. The present calculated total ionization cross-section values show good accord with the measurements for He2+, Li3- and C6+ impact at intermediate and high energy region. (author)

  19. VizieR Online Data Catalog: N-like ions atomic data (Radziute+, 2015)

    Science.gov (United States)

    Radziute, L.; Ekman, J.; Jonsson, P.; Gaigalas, G.

    2015-08-01

    Table 5. Excitation energy in cm-1 for the active sets n=8 (E{cal,n=8}) and n=9 (E{cal,n=9}) in LSJ-coupling for FeXX compared with Gu (2005, Cat. J/ApJS/156/105) (E_{CI+MBPT} ) and observed energies Eobs from NIST Atomic Spectra Database (Kramida et al., 2013, NIST Atomic Spectra Database (version 5.1) (Gaithersburg, MD: US NIST)). Tables 6, 8, 10, 12. Excitation energy E (in cm-1), hyperfine magnetic dipole constants AJ(I/μI) (in MHz per units of μ_N), electric quadrupole constants BJ/Q (MHz/barn), Lande gJ-factors, normal mass shift {widetilde}K_{NMS} (GHzu) parameters, specific mass shift {widetilde}K_{SMS} (GHzu), field shift {widetilde}F (GHz/fm2) parameters for levels of FeXX, CrXVIII, NiXXII and ZnXXIV respectively. Tables 7, 9, 11 and 13. Excitation energy E (in cm-1) and composition of atomic state function in LSJ-coupling FeXX, CrXVIII, NiXXII and ZnXXIV respectively. Tables 18 - 21. Excitation energy E (in cm-1) and lifetimes in s for FeXX, CrXVIII, NiXXII and ZnXXIV respectively in length ({tau}_l) and velocity ({tau}_v) forms. (17 data files).

  20. Nondestructive atomic compositional analysis of BeMgZnO quaternary alloys using ion beam analytical techniques

    Energy Technology Data Exchange (ETDEWEB)

    Zolnai, Z., E-mail: zolnai.zsolt@ttk.mta.hu [Research Centre for Natural Sciences, Institute of Technical Physics and Materials Science (MFA), Konkoly-Thege M. út 29-33, H-1121 Budapest (Hungary); Toporkov, M. [Department of Electrical and Computer Engineering, Virginia Commonwealth University, 601W Main St, Richmond, VA 23284 (United States); Volk, J. [Research Centre for Natural Sciences, Institute of Technical Physics and Materials Science (MFA), Konkoly-Thege M. út 29-33, H-1121 Budapest (Hungary); Department of Electrical and Computer Engineering, Virginia Commonwealth University, 601W Main St, Richmond, VA 23284 (United States); Demchenko, D.O. [Department of Physics, Virginia Commonwealth University, 701W. Grace St., Richmond, VA 23284 (United States); Okur, S. [Department of Electrical and Computer Engineering, Virginia Commonwealth University, 601W Main St, Richmond, VA 23284 (United States); Szabó, Z. [Research Centre for Natural Sciences, Institute of Technical Physics and Materials Science (MFA), Konkoly-Thege M. út 29-33, H-1121 Budapest (Hungary); Özgür, Ü.; Morkoç, H.; Avrutin, V. [Department of Electrical and Computer Engineering, Virginia Commonwealth University, 601W Main St, Richmond, VA 23284 (United States); Kótai, E. [Wigner Research Centre for Physics, Institute for Particle and Nuclear Physics, Konkoly-Thege M. út 29-33, H-1121 Budapest (Hungary)

    2015-02-01

    Highlights: • BeMgZnO thin layers were grown with plasma-assisted molecular beam epitaxy (MBE). • The Be contents were accurately measured with RBS and proton elastic backscattering. • The Tauc bandgap was measured from optical transmittance experiments. • The bandgap has been varied between 3.26 eV and 4.62 eV via the Be and Mg content. • Experimental and density functional theory calculated bandgaps were in good agreement. - Abstract: The atomic composition with less than 1–2 atom% uncertainty was measured in ternary BeZnO and quaternary BeMgZnO alloys using a combination of nondestructive Rutherford backscattering spectrometry with 1 MeV He{sup +} analyzing ion beam and non-Rutherford elastic backscattering experiments with 2.53 MeV energy protons. An enhancement factor of 60 in the cross-section of Be for protons has been achieved to monitor Be atomic concentrations. Usually the quantitative analysis of BeZnO and BeMgZnO systems is challenging due to difficulties with appropriate experimental tools for the detection of the light Be element with satisfactory accuracy. As it is shown, our applied ion beam technique, supported with the detailed simulation of ion stopping, backscattering, and detection processes allows of quantitative depth profiling and compositional analysis of wurtzite BeZnO/ZnO/sapphire and BeMgZnO/ZnO/sapphire layer structures with low uncertainty for both Be and Mg. In addition, the excitonic bandgaps of the layers were deduced from optical transmittance measurements. To augment the measured compositions and bandgaps of BeO and MgO co-alloyed ZnO layers, hybrid density functional bandgap calculations were performed with varying the Be and Mg contents. The theoretical vs. experimental bandgaps show linear correlation in the entire bandgap range studied from 3.26 eV to 4.62 eV. The analytical method employed should help facilitate bandgap engineering for potential applications, such as solar blind UV photodetectors and

  1. Experimental studies of ions and atoms interaction with insulating surface; Etude experimentale de l'interaction rasante d'atomes et d'ions sur des surfaces isolantes

    Energy Technology Data Exchange (ETDEWEB)

    Villette, J

    2000-10-15

    Grazing collisions (<3 deg.) of keV ions and atoms: H{sup +}, Ne{sup +}, Ne{sup 0}, Na{sup +} on LiF (001) single crystal, an ionic insulator, are investigated by a time of flight technique. The incident beam is chopped and the scattered particles are collected on a position sensitive detector providing differential cross section while the time of flight gives the energy loss. Deflection plates allow the charge state analysis. Secondary electrons are detected in coincidence allowing direct measurements of electron emission yield, angular and energetic distribution through time of flight measurements. The target electronic structure characterized by a large band gap, governs the collisional processes: charge exchange, electronic excitations and electron emission. In particular, these studies show that the population of local target excitations surface excitons is the major contribution to the kinetic energy transfer (stopping power). Auger neutralization of Ne{sup +} and He{sup +} ions reveals the population of quasi-molecular excitons, an exciton bound on two holes. Referenced in the literature as trion. A direct energy balance determines the binding energy associated with these excited states of the surface. Besides these electronic energy loss processes, two nuclear energy loss mechanisms are characterized. These processes imply momentum transfer to individual target atoms during close binary collisions or, if the projectile is charged, to collective mode of optical phonons induced by the projectile coulomb field. The effect of the temperature on the scattering profile, the contribution of topological surface defects to the energy loss profile and to skipping motion on the surface are analyzed in view of classical trajectory simulations. (author)

  2. Atomic Data for Neutron-capture Elements I. Photoionization and Recombination Properties of Low-charge Selenium Ions

    Science.gov (United States)

    Sterling, N. C.; Witthoeft, Michael

    2011-01-01

    We present multi-configuration Breit-Pauli AUTOSTRUCTURE calculations of distorted-wave photoionization (PI) cross sections. and total and partial final-state resolved radiative recombination (RR) and dielectronic recombination (DR) rate coefficients for the first six ions of the trans-iron element Se. These calculations were motivated by the recent detection of Se emission lines in a large number of planetary nebulae. Se is a potentially useful tracer of neutron-capture nucleosynthesis. but accurate determinations of its abundance in photoionized nebulae have been hindered by the lack of atomic data governing its ionization balance. Our calculations were carried out in intermediate coupling with semi re1ativistic radial wavefunctions. PI and recombination data were determined for levels within the ground configuration of each ion, and experimental PI cross-section measurements were used to benchmark our results. For DR, we allowed (Delta)n = 0 core excitations, which are important at photoionized plasma temperatures. We find that DR is the dominant recombination process for each of these Se ions at temperatures representative of photoionized nebulae (approx.10(exp 4) K). In order to estimate the uncertainties of these data, we compared results from three different configuration-interaction expansions for each ion, and also tested the sensitivity of the results to the radial scaling factors in the structure calculations. We find that the internal uncertainties are typically 30-50% for the direct PI cross sections and approx.10% for the computed RR rate coefficients, while those for low-temperature DR can be considerably larger (from 15-30% up to two orders of magnitude) due to the unknown energies of near-threshold autoionization resonances. These data are available at the CDS, and fitting coefficients to the total RR and DR rate coefficients are presented. The results are suitable for incorporation into photoionization codes used to numerically simulate

  3. Comparison of quantum mechanical and classical trajectory calculations of cross sections for ion-atom impact ionization of negative - and positive -ions for heavy ion fusion applications

    OpenAIRE

    Kaganovich, Igor D.; Startsev, Edward A.; Davidson, Ronald C.

    2003-01-01

    Stripping cross sections in nitrogen have been calculated using the classical trajectory approximation and the Born approximation of quantum mechanics for the outer shell electrons of 3.2GeV I$^{-}$ and Cs$^{+}$ ions. A large difference in cross section, up to a factor of six, calculated in quantum mechanics and classical mechanics, has been obtained. Because at such high velocities the Born approximation is well validated, the classical trajectory approach fails to correctly predict the stri...

  4. Atomic Structure Calculations and Study of Plasma Parameters of Al-Like Ions

    Directory of Open Access Journals (Sweden)

    Arun Goyal

    2016-07-01

    Full Text Available In the present paper, the spectroscopic properties and plasma characteristics of Al-like ions are investigated in an extensive and detailed manner by adopting the GRASP2K package based on fully relativistic Multi-Configuration Dirac–Hartree–Fock (MCDHF wave-functions in the active space approximation. We have presented energy levels for Al-like ions for Valence-Valence (VV and Core-Valence (CV correlations under the scheme of active space. We have also provided radiative data for E1 transitions for Al-like ions and studied the variation of the transition wavelength and transition probability for electric dipole (E1 Extreme Ultraviolet (EUV transitions with nuclear charge. Our calculated energy levels and transition wavelengths match well with available theoretical and experimental results. The discrepancies of the GRASP2K code results with CIV3 and RMPBT (Relativistic Many Body Perturbation Theory results are also discussed. The variations of the line intensity ratio, electron density, plasma frequency and plasma skin depth with plasma temperature and nuclear charge are discussed graphically in detail for optically thin plasma in Local Thermodynamic Equilibrium (LTE. We believe that our obtained results may be beneficial for comparisons and in fusion and astrophysical plasma research.

  5. Single-Ion Atomic Clock with $3\\times10^{-18}$ Systematic Uncertainty

    CERN Document Server

    Huntemann, N; Lipphardt, B; Tamm, Chr; Peik, E

    2016-01-01

    We experimentally investigate an optical frequency standard based on the $^2S_{1/2} (F=0)\\to {}^2F_{7/2} (F=3)$ electric octupole (\\textit{E}3) transition of a single trapped $^{171}$Yb$^+$ ion. For the spectroscopy of this strongly forbidden transition, we utilize a Ramsey-type excitation scheme that provides immunity to probe-induced frequency shifts. The cancellation of these shifts is controlled by interleaved single-pulse Rabi spectroscopy which reduces the related relative frequency uncertainty to $1.1\\times 10^{-18}$. To determine the frequency shift due to thermal radiation emitted by the ion's environment, we measure the static scalar differential polarizability of the \\textit{E}3 transition as $0.888(16)\\times 10^{-40}$ J m$^2$/V$^2$ and a dynamic correction $\\eta(300~\\text{K})=-0.0015(7)$. This reduces the uncertainty due to thermal radiation to $1.8\\times 10^{-18}$. The residual motion of the ion yields the largest contribution $(2.1\\times 10^{-18})$ to the total systematic relative uncertainty of...

  6. Damage effects of {ion}/{atom} beam milling on MNOS (Al/Si 3N 4/SiO 2/Si) capacitors

    Science.gov (United States)

    Bangert, U.; Belson, J.; Wilson, I. H.

    1984-02-01

    Low energy argon ion and atom beams produced by saddle field sources have been used to study changes in CVD Si 3N 4/SiO 2/Si structures after bombardment of the bare nitride at a particle energy of 2.9 keV. Interface state densities Nst and flatband voltages VFB were extracted from high frequency (1.3 MHz) and quasi-static C- V curves. Bombardment was found to induce an increase in Nst and positive and negative charge storage associated with the nitride (or the nitride/oxide interface). The effect was more pronounced under ion bombardment. On the supposition that displacement damage is similar for ion and atom bombardments the differences in charge storage are interpreted in terms of enhanced trapping under the field associated with ion bombardment.

  7. Sum rules and other properties involving resonance projection operators. [for optical potential description of electron scattering from atoms and ions

    Science.gov (United States)

    Berk, A.; Temkin, A.

    1985-01-01

    A sum rule is derived for the auxiliary eigenvalues of an equation whose eigenspectrum pertains to projection operators which describe electron scattering from multielectron atoms and ions. The sum rule's right-hand side depends on an integral involving the target system eigenfunctions. The sum rule is checked for several approximations of the two-electron target. It is shown that target functions which have a unit eigenvalue in their auxiliary eigenspectrum do not give rise to well-defined projection operators except through a limiting process. For Hylleraas target approximations, the auxiliary equations are shown to contain an infinite spectrum. However, using a Rayleigh-Ritz variational principle, it is shown that a comparatively simple aproximation can exhaust the sum rule to better than five significant figures. The auxiliary Hylleraas equation is greatly simplified by conversion to a square root equation containing the same eigenfunction spectrum and from which the required eigenvalues are trivially recovered by squaring.

  8. The elastic scattering of electrons from atoms and ions containing core holes

    Energy Technology Data Exchange (ETDEWEB)

    Al-Mulla, S Y Yousif [College of Engineering, University of Boras, S-50190 Boras (Sweden)

    2004-01-28

    Differential cross sections for the elastic scattering of electrons from the ground states of the closed shell atomic systems Ne, Ar and Na{sup +}, and the excited states of the open shell systems containing a highly localized core hole obtained by removing a single electron from any one of the occupied shells of these closed shell systems, have been calculated. Local density approximations to the exchange and correlation potentials have been used in these calculations. A comparison of the calculated results with other experimental and theoretical data is shown and discussed.

  9. Molecular ions in ultracold atomic gases: computed electronic interactions for \\MgHion with Rb

    CERN Document Server

    Tacconi, Mario

    2007-01-01

    The electronic structures of the manifold of potential energy surfaces generated in the lower energy range by the interaction of the MgH$^+$(X$^1\\Sigma^+$) cationic molecule with Rb($^2$S), neutral atom are obtained over a broad range of Jacobi coordinates from strongly correlated \\emph{ab initio} calculations which use a Multireference (MR) wavefunction within a Complete Active Space (CAS) approach. The relative features of the lowest five surfaces are analyzed in terms of possible collisional outcomes when employed to model the ultracold dynamics of ionic molecular partners.

  10. Atomic physics

    International Nuclear Information System (INIS)

    Research activities in atomic physics at Lawrence Berkeley Laboratory during 1976 are described. Topics covered include: experiments on stored ions; test for parity violation in neutral weak currents; energy conservation and astrophysics; atomic absorption spectroscopy, atomic and molecular detectors; theoretical studies of quantum electrodynamics and high-z ions; atomic beam magnetic resonance; radiative decay from the 23Po,2 levels of helium-like argon; quenching of the metastable 2S/sub 1/2/ state of hydrogen-like argon in an external electric field; and lifetime of the 23Po level of helium-like krypton

  11. Measurements of ionization balance parameters in atomic ions. Progress report, January 1-December 31, 1983

    International Nuclear Information System (INIS)

    We have made significant progress toward the measurement of the cross section for dielectronic recombination of C3+ and a free electron. The instrumentation required to disperse and detect recombined ions was added to the apparatus, and initial measurements indicate that the present background C2+ detecting rate is within a factor of 5 of being acceptable. We are presently attempting to reduce the background by improving the vacuum in the beam transport system. A pressure of 5x10-9 torr in this region would provide a real to accidental coincidence ratio of 0.074 and a meaningful measurement of dielectronic recombination in 4.5 hours

  12. Comparison of quantum mechanical and classical trajectory calculations of cross sections for ion-atom impact ionization of negative - and positive -ions for heavy ion fusion applications

    CERN Document Server

    Kaganovich, I D; Davidson, R C; Kaganovich, Igor D.; Startsev, Edward A.; Davidson, Ronald C.

    2003-01-01

    Stripping cross sections in nitrogen have been calculated using the classical trajectory approximation and the Born approximation of quantum mechanics for the outer shell electrons of 3.2GeV I$^{-}$ and Cs$^{+}$ ions. A large difference in cross section, up to a factor of six, calculated in quantum mechanics and classical mechanics, has been obtained. Because at such high velocities the Born approximation is well validated, the classical trajectory approach fails to correctly predict the stripping cross sections at high energies for electron orbitals with low ionization potential.

  13. MULTIPHOTON IONIZATION OF ATOMS

    OpenAIRE

    Mainfray, G.

    1985-01-01

    Multiphoton ionization of one-electron atoms, such as atomic hydrogen and alkaline atoms, is well understood and correctly described by rigorous theoretical models. The present paper will be devoted to collisionless multiphoton ionization of many-electron atoms as rare gases. It induces removal of several electrons and the production of multiply charged ions. Up to Xe5+ ions are produced in Xe atoms. Doubly charged ions can be produced, either by simultaneous excitation of two electrons, or b...

  14. Correlated charge changing ion-atom collisions: Progress report for the period February 15, 1987-March 14, 1988

    International Nuclear Information System (INIS)

    This report summarizes the progress and accomplishments in accelerator atomic physics research supported by DOE grant DE-FG02-87ER13778 for a period of 13 months from February 15, 1987 through March 14, 1988. The general scope of this work involves the experimental investigation of fundamental atomic interactions in collisions of highly charged projectiles with neutral targets, with a particular emphasis on two-electron interactions. Inner-shell processes involving excitation, ionization, and charge transfer are investigated using coincidence techniques in which projectile charge-changing events are associated with x-ray emission, target recoil ions, or electron emission. New measurements were conducted using accelerators at the Lawrence Berkeley Laboratory, Argonne National Laboratory, Hahn-Meitner-Institut (Berlin), and Western Michigan University. The work at Hahn-Meitner resulted from a collaboration initiated while J. A. T. was on research leave from Western Michigan University during the 1986-1987 academic year. The principal new results obtained during the past year using each of the three coincidence techniques are summarized below. A major emphasis of all these investigations is to determine the role of electron correlation in two- (and multiple-) electron interactions

  15. Two-color above threshold ionization of atoms and ions in XUV Bessel beams and combined with intense laser light

    CERN Document Server

    Seipt, D; Surzhykov, A; Fritzsche, S

    2016-01-01

    The two-color above-threshold ionization (ATI) of atoms and ions is investigated for a vortex Bessel beam in the presence of a strong near-infrared (NIR) light field. While the photoionization is caused by the photons from the weak but extreme ultra-violet (XUV) vortex Bessel beam, the energy and angular distribution of the photoelectrons and their sideband structure are affected by the plane-wave NIR field. We here explore the energy spectra and angular emission of the photoelectrons in such two-color fields as a function of the size and location of the target (atoms) with regard to the beam axis. In addition, analogue to the circular dichroism in typical two-color ATI experiments with circularly polarized light, we define and discuss seven different dichroism signals for such vortex Bessel beams that arise from the various combinations of the orbital and spin angular momenta of the two light fields. For localized targets, it is found that these dichroism signals strongly depend on the size and position of t...

  16. Atomic collision experiments utilizing low-velocity, highly-charged ion beams

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, B.M.; Jones, K.W.; Meron, M.

    1982-01-01

    Intense beams of highly-stripped ions are now routinely produced at low velocities using the Brookhaven dual MP-tandens in a unique four-stage accel/decel mode. This mode of operation combines three stages of acceleration, stripping at high energy, and one stage of deceleration to near-zero velocity. To date, experiments have used 10-100 nA beams of bare and few-electron heavy ions at energies as low as 0.2 MeV/amu, and upgrades of the facility should push the lower limit below 0.1 MeV/amu. Recent experiments, such as measurements of charge transfer and x-ray production for S/sup 6-16+/ on He and Ar at 6 to 20 MeV and P(b) measurements for MO x-rays produced in Cl/sup 16 +/ + Ar collisions at 20, 10, and 5 MeV have demonstrated the usefulness of highly-stripped, low-velocity projectiles. These experiments and a few possibilities for future experiments are discussed.

  17. On the chemistry of hydrides of N atoms and O$^+$ ions

    CERN Document Server

    Awad, Zainab; Williams, David A

    2016-01-01

    Previous work by various authors has suggested that the detection by Herschel/HIFI of nitrogen hydrides along the low density lines of sight towards G10.6-0.4 (W31C) cannot be accounted for by gas-phase chemical models. In this paper we investigate the role of surface reactions on dust grains in diffuse regions, and we find that formation of the hydrides by surface reactions on dust grains with efficiency comparable to that for H$_2$ formation reconciles models with observations of nitrogen hydrides. However, similar surface reactions do not contribute significantly to the hydrides of O$^+$ ions detected by Herschel/HIFI present along many sight lines in the Galaxy. The O$^+$ hydrides can be accounted for by conventional gas-phase chemistry either in diffuse clouds of very low density with normal cosmic ray fluxes or in somewhat denser diffuse clouds with high cosmic ray fluxes. Hydride chemistry in dense dark clouds appears to be dominated by gas-phase ion-molecule reactions.

  18. HISTRAP: Proposal for a Heavy Ion Storage Ring for Atomic Physics

    International Nuclear Information System (INIS)

    This paper presents an overview of the physics capabilities of HISTRAP together with a brief description of the facility and a sampling of the beams which will be available for experimentation, and surveys some of the lines of investigation in the physics of multicharged ions, molecular ion spectroscopy, condensed beams, and nuclear physics that will become possible with the advent of HISTRAP. Details of the accelerator design are discussed, including computer studies of beam tracking in the HISTRAP lattice, a discussion of the HHIRF tandem and ECR/RFQ injectors, and a description of the electron beam cooling system. In the past three years, HISTRAP has received substantial support from Oak Ridge National Laboratory management and staff. The project has used discretionary funds to develop hardware prototypes and carry out design studies. Construction has been completed on a vacuum test stand which models 1/16 of the storage ring and has attained a pressure of 4 x 10-12 Torr; a prototype rf cavity capable of accelerating beams up to 90 MeV/nucleon and decelerating to 20 keV/nucleon; and a prototype dipole magnet, one of the eight required for the HISTRAP lattice. This paper also contains a summary of the work on electron cooling carried out by one of our staff members at CERN. Building structures and services are described. Details of cost and schedule are also discussed. 77 refs

  19. Atomic collision experiments utilizing low-velocity, highly-charged ion beams

    International Nuclear Information System (INIS)

    Intense beams of highly-stripped ions are now routinely produced at low velocities using the Brookhaven dual MP-tandems in a unique four-stage accel/decel mode. This mode of operation combines three stages of acceleration, stripping at high energy, and one stage of deceleration to near-zero velocity. To date, experiments have used 10-100 nA beams of bare and few-electron heavy ions at energies as low as 0.2 MeV/amu, and upgrades of the facility should push the lower limit below 0.1 MeV/amu. Recent experiments, such as measurements of charge transfer and x-ray production for S6-16+ on He and Ar at 6-20 MeV and P(b) measurements for MO x-rays produced in Cl16+ + Ar collisions at 20, 10 and 5 MeV have demonstrated the usefulness of highly-stripped, low-velocity projectiles. These experiments and a few possibilities for future experiments are discussed

  20. HISTRAP: Proposal for a Heavy Ion Storage Ring for Atomic Physics

    Energy Technology Data Exchange (ETDEWEB)

    1988-11-01

    This paper presents an overview of the physics capabilities of HISTRAP together with a brief description of the facility and a sampling of the beams which will be available for experimentation, and surveys some of the lines of investigation in the physics of multicharged ions, molecular ion spectroscopy, condensed beams, and nuclear physics that will become possible with the advent of HISTRAP. Details of the accelerator design are discussed, including computer studies of beam tracking in the HISTRAP lattice, a discussion of the HHIRF tandem and ECR/RFQ injectors, and a description of the electron beam cooling system. In the past three years, HISTRAP has received substantial support from Oak Ridge National Laboratory management and staff. The project has used discretionary funds to develop hardware prototypes and carry out design studies. Construction has been completed on a vacuum test stand which models 1/16 of the storage ring and has attained a pressure of 4 x 10/sup -12/ Torr; a prototype rf cavity capable of accelerating beams up to 90 MeV/nucleon and decelerating to 20 keV/nucleon; and a prototype dipole magnet, one of the eight required for the HISTRAP lattice. This paper also contains a summary of the work on electron cooling carried out by one of our staff members at CERN. Building structures and services are described. Details of cost and schedule are also discussed. 77 refs.

  1. Atomic layer deposition of amorphous iron phosphates on carbon nanotubes as cathode materials for lithium-ion batteries

    International Nuclear Information System (INIS)

    A non-aqueous approach was developed to synthesize iron phosphate cathode materials by the atomic layer deposition (ALD) technique. Deposition of iron phosphate thin films was achieved on nitrogen-doped carbon nanotubes (NCNTs) by combining ALD subcycles of Fe2O3 (ferrocene-ozone) and POx (trimethyl phosphate-water) at 200 – 350 °C. The thickness of iron phosphate thin films depends linearly on the ALD cycle, indicating their self-limiting growth behavior. The growth per cycle of iron phosphate thin films was determined to be ∼ 0.2, 0.4, 0.6, and 0.5 Å, at 200, 250, 300, and 350 °C, respectively. Characterization by SEM, TEM, and HRTEM techniques revealed uniform and conformal coating of amorphous iron phosphates on the surface of NCNTs. XANES analysis confirmed Fe−O−P bonding in the iron phosphates prepared by ALD. Furthermore, electrochemical measurement verified the high electrochemical activity of the amorphous iron phosphate as a cathode material in lithium-ion batteries. It is expected that the amorphous iron phosphate prepared by this facile and cost-effective ALD approach will find applications in the next generation of lithium-ion batteries and thin film batteries as either cathode materials or surface coating materials

  2. Preconcentration and determination of zinc and lead ions by a combination of cloud point extraction and flame atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Tavallali, H. [Chemistry Department, Payamenore University, Shiraz (Iran); Shokrollahi, A.; Zahedi, M. [Chemistry Department, Yasouj University, Yasouj (Iran); Niknam, K. [Chemistry Department, Persian Gulf University, Bushehr (Iran); Soylak, M. [Chemistry Department, University of Erciyes, Kayseri (Turkey); Ghaedi, M.

    2009-04-15

    The phase-separation phenomenon of non-ionic surfactants occurring in aqueous solution was used for the extraction of lead(II) and zinc(II). After complexation with 3-[(4-bromophenyl) (1-H-inden-3-yl)methyl]-1 H-indene (BPIMI), the analytes were quantitatively extracted to a phase rich in Triton X-114 after centrifugation. Methanol acidified with 1 mol/L HNO{sub 3} was added to the surfactant rich phase prior to its analysis by flame atomic absorption spectrometry (FAAS). The concentration of bis((1H-benzo [d] imidazol-2yl)ethyl)sulfane, Triton X-114, pH and amount of surfactant were all optimized. Detection limits (3 SDb/m) of 2.5 and 1.6 ng/mL for Pb{sup 2+} and Zn{sup 2+} along with preconcentration factors of 30 and an enrichment factor of 32 and 48 for Pb{sup 2+}and Zn {sup 2+} ions were obtained, respectively. The proposed cloud point extraction was been successfully applied for the determination of these ions in real samples with complicated matrices such as food and soil samples, with high efficiency. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

  3. Flame Atomic Absorption Determination of Gold Ion in Aqueous Samples after Preconcentration Using 9-Acridinylamine Functionalized γ-Alumina Nanoparticles

    Directory of Open Access Journals (Sweden)

    Mohammad Karimi

    2013-01-01

    Full Text Available A simple and sensitive solid phase extraction utilizing 9-acridinylamine functionalized alumina nanoparticles was developed, and their potential use for preconcentration and subsequent determination of gold by flame atomic absorption spectrometry (FAAS was investigated. A number of parameters, namely, type, concentration, and volume of eluent, pH of the sample solution, flow rate of extraction, and volume of the sample, were evaluated. The effect of a variety of ions on preconcentration and recovery was also investigated. Gold ions were found to be recovered quantitatively at pH 3.0, with 0.1 mol L−1 thiourea in 2 mol L−1 H2SO4 as eluent. The limit of detection (LOD, defined as five times the standard deviation of the blank, was determined to be lower than 13.0 ppb. Under optimum conditions, the accuracy and precision (RSD% of the method were >98.0 and <1.5%, respectively. To gauge its ability in terms of application to real samples, the proposed method was successfully applied for determination of gold concentration in waste water samples and one soil standard material, and satisfactory results were obtained.

  4. Relative level excitation in ion-atom collisions as a function of the orbital angular momentum quantum number

    International Nuclear Information System (INIS)

    In a previous study of projectile Rydberg state excitations in the collisions Be+, Mg+-He at 10-75 keV it was found, for a fixed value of the principal quantum number n, that the ratio of the s, p, and d level cross sections was close to 1:3:5, whereas the f and g level cross sections drop to approximately the same value as for s levels. Blaney and Berry (1976) found essentially the same increase in cross section for electron transfer into excited Li I states in the Li+-H2 collision. In contrast to this behavior, beam-foil excitations oscillate as a function of the orbital angular momentum quantum number with maxima at odd values of l (p, f,...) and minima at even l (s, d, g,...). Since no model is available to describe these features, the measurements have been extended to other systems to test their general validity. A large conjugated molecule (benzene) was chosen as target gas in one experiment to bridge the gap between ion-atom and ion-foil excitations. The data presented here have all been obtained by optical spectrometry. A quasi molecular approach is used to explain the results. (Auth.)

  5. Atomic force microscopy imaging reveals the formation of ASIC/ENaC cross-clade ion channels

    Energy Technology Data Exchange (ETDEWEB)

    Jeggle, Pia; Smith, Ewan St. J.; Stewart, Andrew P. [Department of Pharmacology, University of Cambridge, Tennis Court Road, Cambridge CB2 1PD (United Kingdom); Haerteis, Silke; Korbmacher, Christoph [Institut für Zelluläre und Molekulare Physiologie, Friedrich-Alexander-Universität Erlangen-Nürnberg, Waldstrasse 6, 91054 Erlangen (Germany); Edwardson, J. Michael, E-mail: jme1000@cam.ac.uk [Department of Pharmacology, University of Cambridge, Tennis Court Road, Cambridge CB2 1PD (United Kingdom)

    2015-08-14

    ASIC and ENaC are co-expressed in various cell types, and there is evidence for a close association between them. Here, we used atomic force microscopy (AFM) to determine whether ASIC1a and ENaC subunits are able to form cross-clade hybrid ion channels. ASIC1a and ENaC could be co-isolated from detergent extracts of tsA 201 cells co-expressing the two subunits. Isolated proteins were incubated with antibodies against ENaC and Fab fragments against ASIC1a. AFM imaging revealed proteins that were decorated by both an antibody and a Fab fragment with an angle of ∼120° between them, indicating the formation of ASIC1a/ENaC heterotrimers. - Highlights: • There is evidence for a close association between ASIC and ENaC. • We used AFM to test whether ASIC1a and ENaC subunits form cross-clade ion channels. • Isolated proteins were incubated with subunit-specific antibodies and Fab fragments. • Some proteins were doubly decorated at ∼120° by an antibody and a Fab fragment. • Our results indicate the formation of ASIC1a/ENaC heterotrimers.

  6. Measurements of transition probabilities for spin-changing lines of atomic ions used in diagnostics of astrophysical plasmas

    Science.gov (United States)

    Smith, P. L.; Johnson, B. C.; Kwong, H. S.; Parkinson, W. H.; Knight, R. D.

    1984-01-01

    The intensities of ultraviolet, spin-changing, 'intersystem' lines of low-Z atomic ions are frequently used in determinations of electron densities and temperatures in astrophysical plasmas as well as in measurements of element abundances in the interstellar gas. The transition probabilities (A-values) of these lines, which are about five orders of magnitude weaker than allowed lines, have not been measured heretofore and various calculations produce A-values for these lines that differ by as much as 50 percent A radio-frequency ion trap has been used for the first measurements of transition probabilities for intersystem lines seen in astronomical spectra. The measurement procedure is discussed and results for Si III, O III, N II, and C III are reviewed and compared to calculated values. Discrepancies exist; these indicate that some of the calculated A-values may be less reliable than has been beleived and that revisions to the electron densities determined for some astrophysical plasmas may be required.

  7. Relativistic theory for radiative forward electron emission in heavy ion-atom encounters

    Science.gov (United States)

    Jakubaßa-Amundsen, Doris; Müller, Robert; Surzhykov, Andrey; Yerokhin, Vladimir

    2014-12-01

    The forward electron emission with simultaneous photon production during the scattering of relativistic, highly stripped projectiles from light target atoms is calculated within the Dirac theory. The method of calculation is a simplification of the impulse approximation and is based on the relation of the cross section for radiative capture to continuum of loosely bound electrons to the frame-transformed electron bremsstrahlung cross section. It is demonstrated that such an approximation is well justified in a large region of energies and photon emission angles, with the exception of the extreme forward and backward emission and the soft-photon energy limit. The cusp spectrum and the corresponding angular distribution are compared to recent experimental data for the collision system 90.38 MeV/amu U88+ + N2.

  8. Atomic physics with highly ionized ions. Progress report, 1 June 1980-31 May 1981

    International Nuclear Information System (INIS)

    The research accomplishments for the period 1 June 1980 to 31 May 1981 are summarized. The research program that was proposed for this period consisted of the study of the processes: K-ionization, K-shell to K-shell electron transfer and double K-shell to K-shell electron transfer for systems of varying charge asymmetry in high energy high charge (HEHQ) collisions, the capture of loosely bound electrons to Rydberg states of highly ionized spectra, the excitation of, ionization and capture to well-defined states of few electron ions, the calculation of the structure and formation of the highly ionized states that are observed through deexcitation processes, and single and multiple electron transfer, ionization and transfer ionization in low energy high charge (LEHQ) collisions

  9. Dynamics of electron-capture-to-continuum (ECC) formation in slow ion-atom collisions

    Energy Technology Data Exchange (ETDEWEB)

    Afaneh, F [Physics Department, The Hashemite University, PO Box 150459, Zarqa 13115 (Jordan); Schmidt, L Ph H [Institut fuer Kernphysik, Max-von-Laue-Str. 1, 60438 Frankfurt (Germany); Schoeffler, M [Institut fuer Kernphysik, Max-von-Laue-Str. 1, 60438 Frankfurt (Germany); Stiebing, K E [Institut fuer Kernphysik, Max-von-Laue-Str. 1, 60438 Frankfurt (Germany); Al-Jundi, J [Physics Department, The Hashemite University, PO Box 150459, Zarqa 13115 (Jordan); Schmidt-Boecking, H [Institut fuer Kernphysik, Max-von-Laue-Str. 1, 60438 Frankfurt (Germany); Doerner, R [Institut fuer Kernphysik, Max-von-Laue-Str. 1, 60438 Frankfurt (Germany)

    2007-05-28

    The zero-degree ejected-electron spectrum for protons incident on He at 25 keV is examined experimentally using the COLTRIMS technique. The momentum distribution of the emitted electrons for the transfer ionization (TI) reaction channel is measured in coincidence with the momentum vectors of the recoil ion and the scattered projectile. The momentum distribution of the electrons emitted around zero degree in the forward direction for the TI reaction channel shows two prominent structures: the electron-capture-to-the-continuum (ECC) peak and the saddle-point peak. From the measured fully differential electron emission cross sections with respect to the scattering plane we can deduce that the main ECC formation mechanism is electron promotion via quasimolecular orbitals.

  10. Photodetachment Studies Of Atomic Negative Ions Through Velocity-Map Imaging Spectroscopy

    Science.gov (United States)

    Chartkunchand, Kiattichart

    The technique of velocity-map imaging (VMI) spectroscopy as been adapted to a keV-level negative ion beamline for studies of photon-negative ion collisions. The design and operation of the VMI spectrometer takes into consideration the use of continuous, fast-moving (5 keV to 10 keV) ion beams, as well as a continuous wave (CW) laser as the source of photons. The VMI spectrometer has been used in photodetachment studies of the Group 14 negative ions Ge--, Sn--, and Pb-- at a photon wavelength of 532 nm. Measurements of the photoelectron angular distributions and asymmetry parameters for Ge-- and Sn-- were benchmarked against those measured previously [W. W. Williams, D. L. Carpenter, A. M. Covington, and J. S. Thompson, Phys. Rev. A 59, 4368 (1999), V. T. Davis, J. Ashokkumar, and J. S. Thompson, Phys. Rev. A 65, 024702 (2002)], while fine-structure-resolved asymmetry parameters for Pb-- were measured for the first time. Definitive evidence of a "forbidden" 4S 3/2→1D2 transition was observed in both the Ge-- and Sn-- photoelectron kinetic energy spectra. This transition is explained in terms of the inadequacy of the single-configuration description for the 1D2 excited state in the corresponding neutral. Near-threshold photodetachment studies of S-- were carried out in order to measure the spectral dependence of the photoelectron angular distribution. The resulting asymmetry parameters were measured at several photon wavelengths in the range of 575 nm (2.156 eV photon energy) to 615 nm (2.016 eV photon energy). Comparison of the measurements to a qualitative model of p-electron photodetachment [D. Hanstorp, C. Bengtsson, and D. J. Larson, Phys. Rev. A 40, 670 (1989)] were made. Deviations of the measured asymmetry parameters from the Hanstorp model near photodetachment thresholds suggests a reduced degree of suppression of d partial-waves than predicted by models. Measurement of the electron affinity of terbium was performed along with a determination of the

  11. Sympathetic cooling of the Ba$^+$ ion by collisions with ultracold Rb atoms: theoretical prospects

    CERN Document Server

    Krych, Michał; Moszynski, Filip Pawłowski Robert; Idziaszek, Zbigniew

    2010-01-01

    State-of-the-art {\\em ab initio} techniques have been applied to compute the potential energy curves of the (BaRb)$^+$ molecular ion in the Born-Oppenheimer approximation. The long-range coefficients describing the electrostatic, induction, and dispersion interactions at large interatomic distances are also reported. The electric transition dipole moments governing the X$^1\\Sigma\\; \\rightarrow\\; ^1\\Sigma, \\; ^1\\Pi$ have been obtained as the first residue of the polarization propagator computed with the linear response coupled-cluster method restricted to single and double excitations. Nonadiabatic radial and angular coupling matrix elements, as well as the spin-orbit coupling matrix elements have been evaluated using the multireference configuration interaction method restricted to single and double excitations with a large active space. With these couplings, the spin-orbit coupled (relativistic) potential energy curves for the 0$^+$ and 1 states relevant for the running experiments have been obtained. Finall...

  12. Measurement of Atomic Oxygen in Diffuse Aurora and Ion Density in the E-Region

    Science.gov (United States)

    Sharp, William E.

    1997-01-01

    An ion mass spectrometer (IMS) was refurbished, calibrated and supplied to the University of Colorado payload (Dr. Charles Barth, P.I.) which was launched from White Sands in September of 1993 as NASA 33.062. The nose cone failed to deploy and their were problems with the ACS so the mission was declared a failure. However, the door covering the IMS deployed and the instrument obtained data. The launch occurred shortly after a payload carrying solar x-ray detectors was launched. Thus a small portion of the Colorado payload science was salvaged; namely, the NO(+)/O2(+) ratio to compare with the measured x-ray flux. Figure I shows the NO(+) to O2(+) ratio vs. altitude. The behavior is typical of the E-region.

  13. Radiative electron capture studied in relativistic heavy-ion atom collisions

    International Nuclear Information System (INIS)

    The process of Radiative Electron Capture (REC) in relativistic collisions of high-Z ions with low-Z gaseous and solid targets is studied experimentally and theoretically. The observed X-ray spectra are analysed with respect to photon angular distributions as well as to total K-REC cross sections. The experimental results for angle-differential cross sections are well-reproduced by exact relativistic calculations which yield significant deviations from standard sin2θ distributions. Total cross sections for K-REC are shown to follow a simple scaling rule obtained from exact relativistic calculations as well as from a non-relativistic dipole approximation. The agreement between these different theoretical approaches must be regarded as fortuitous, but it lends support to the use of the non-relativistic approach for practical purposes. (orig.)

  14. Change of Cr atoms distribution in Fe85Cr15 alloy caused by 250 keV He+ ion irradiation to different doses

    International Nuclear Information System (INIS)

    Highlights: • Effect of He-ion irradiation dose on Fe85Cr15 alloy. • Irradiation-induced clustering of Cr atoms. • Irradiation-caused reorientation of the surface magnetization vector. • Irradiation-caused increase of Fe-site spin-density. - Abstract: Redistribution of Cr atoms in a Fe85Cr15 alloy caused by its irradiation with 250 keV He+ ions to different doses, D = 8 ⋅ 1016, 16 ⋅ 1016 and 48 ⋅ 1016 ions/cm2 was investigated by means of conversion electrons Mössbauer spectroscopy. The redistribution was expressed in terms of the Warren–Cowley short-range order parameters α1, α2 and α12 pertaining to the first (1NN), second (2NN) and both i.e. 1NN + 2NN shells, respectively. Clear evidence was found, both for non-irradiated and irradiated samples that the actual distribution of Cr atoms is characteristic of the shell, and for a given shell it depends on the irradiation dose. In particular, α1 is positive, hence indicates an under population of Cr atoms in 1NN with respect to the random case, α2 is negative, giving evidence thereby that 2NN is overpopulated by Cr atoms, and α12 is weakly positive. Under the applied irradiation the number of Cr atoms in both neighbor shells decreased signifying thereby a clustering of Cr atoms. The underlying decrease of Cr concentration within the 1NN–2NN volume around the probe Fe atoms was estimated at 1.5 at.% ranging between 2.1 for the lowest and 0.8 at.% for the highest dose

  15. Effects of autoionization in electron loss from helium-like highly charged ions in collisions with photons and fast atomic particles

    CERN Document Server

    Lyashchenko, K N; Voitkiv, A B

    2016-01-01

    We study theoretically single electron loss from helium-like highly charged ions involving excitation and decay of autoionizing states of the ion. Electron loss is caused by either photo absorption or the interaction with a fast atomic particle (a bare nucleus, a neutral atom, an electron). The interactions with the photon field and the fast particles are taken into account in the first order of perturbation theory. Two initial states of the ion are considered: $1s^2$ and $(1s2s)_{J=0}$. We analyze in detail how the shape of the emission pattern depends on the atomic number $Z_{I}$ of the ion discussing, in particular, the inter-relation between electron loss via photo absorption and due to the impact of atomic particles in collisions at modest relativistic and extreme relativistic energies. According to our results, in electron loss from the $1s^2$ state autoionization may substantially influence the shape of the emission spectra only up to $Z_{I} \\approx 35-40$. A much more prominent role is played by autoi...

  16. The Effects of the Pauli Exclusion Principle in Determining the Ionization Energies of the Helium Atom and Helium-Like Ions

    Science.gov (United States)

    Deeney, F. A.; O'Leary, J. P.

    2012-01-01

    For helium and helium-like ions, we have examined the differences between the values of the ionization energies as calculated from the Bohr theory and those measured in experiments. We find that these differences vary linearly with the atomic number of the system. Using this result, we show how the Bohr model for single-electron systems may be…

  17. Speciation of arsenic(III)/arsenic(V) and selenium(IV)/ selenium(VI) using coupled ion chromatography - hydride generation atomic absorption spectrometry

    Science.gov (United States)

    Simple analytical methods have been developed to speciate inorganic arsenic and selenium in the ppb range using coupled ion chromatography-hydride generation atomic absorption spectrometry. Because of the differences in toxicity and adsorption behavior, determinations of the redox states arsenite A...

  18. Doubly Differential Cross Sections for Ejection of Electrons from Atomic and Molecular Hydrogen by 30-120 KEV HELIUM(+) Ion Impact

    Science.gov (United States)

    Hsu, Ying-Yuan

    Electrons ejected from atomic and molecular hydrogen in He^+ ion impacts were observed with projectile energies ranging from 30 to 120 keV. The ejection angles observed were 15^circ, 30^circ, 50^circ, 70^ circ, 90^circ, 110^circ, 130^circ and 160^circ with electron energies ranging from 1.5 to 130 eV. Ejected electrons were energy analyzed by an electrostatic analyzer with 5% resolution and were detected by a channel electron multiplier. A Slevin-type RF hydrogen atom source was used to generate a mixed target of atomic and molecular hydrogen. The dissociation fraction of the target was determined from the measurement of 9-eV H^+ ions coming from the break-up of the 2psigma_ {u} state of the H_2 ^+ molecular ion. Methods were devised to extract the electron ejection cross section ratio between hydrogen atoms and molecules. Cross sections for the hydrogen atom were then calculated from additional measurements on pure H_2.. The results are compared to plane-wave-Born approximation (PWBA) calculations, classical-trajectory-Monte-Carlo (CTMC) calculations, and continuum-distorted-wave-eikonal-initial -state (CDW-EIS) calculations for proton impact. Electron loss cross sections are calculated with PWBA and used as a correction to the above calculations.

  19. Atomic Physics

    CERN Document Server

    Foot, Christopher J

    2007-01-01

    This text will thoroughly update the existing literature on atomic physics. Intended to accompany an advanced undergraduate course in atomic physics, the book will lead the students up to the latest advances and the applications to Bose-Einstein Condensation of atoms, matter-wave inter-ferometry and quantum computing with trapped ions. The elementary atomic physics covered in the early chapters should be accessible to undergraduates when they are first introduced to the subject. To complement. the usual quantum mechanical treatment of atomic structure the book strongly emphasizes the experimen

  20. Electron correlation in fast ion-impact single ionization of helium atoms

    International Nuclear Information System (INIS)

    A four-body distorted-wave approximation is applied for theoretical analysis of the fully differential cross sections (FDCS) for proton-impact single ionization of helium atoms in their ground states. The nine-dimensional integrals for the partial amplitudes are analytically reduced to closed-form expressions or some one-dimensional integrals which can be easily calculated numerically. Calculations are performed in the scattering and perpendicular planes. The influence of the target static electron correlations on the process is investigated using a number of different bound-state wave functions for the ground state of the helium targets. An illustrative computation is performed for 75-keV proton-helium collisions and the obtained results are compared with experimental data and other theoretical predictions. Although for small momentum transfers, the comparison shows a reasonable agreement with experiments in the scattering and perpendicular planes, some significant discrepancies are still present at large momentum transfers in these planes. However, our results are compatible and for some cases, better than those of the other sophisticated calculations. (paper)

  1. The direct ionization processes in the collisions of partially stripped carbon and oxygen ions with helium atoms at low-to-intermediate energies

    International Nuclear Information System (INIS)

    The values of direct double-to-single ionization ratio R of helium atoms induced by Cq+, Oq++ (q = 1–4) ions at incident energies from 0.2 to 8.5MeV are measured. Based on the existing model (Shao J X, Chen X M and Ding B W 2007 Phys. Rev. A 75 012701) the effective charge of the projectile is introduced to theoretically estimate the value of R for the partially stripped ions impacting on helium atoms. The results calculated from our 'effective charge' model are in good agreement with the experimental data, and the dependence of the effective charge on the ionization energy of the projectile is also discussed qualitatively. (atomic and molecular physics)

  2. Dispersion coefficients for the interactions of the alkali and alkaline-earth ions and inert gas atoms with a graphene layer

    CERN Document Server

    Kaur, Kiranpreet; Sahoo, B K

    2015-01-01

    Largely motivated by a number of applications, the van der Waals dispersion coefficients ($C_3$s) of the alkali ions (Li$^+$, Na$^+$, K$^+$ and Rb$^+$), the alkaline-earth ions (Ca$^+$, Sr$^+$, Ba$^+$ and Ra$^+$) and the inert gas atoms (He, Ne, Ar and Kr) with a graphene layer are determined precisely within the framework of Dirac model. For these calculations, we have evaluated the dynamic polarizabilities of the above atomic systems very accurately by evaluating the transition matrix elements employing relativistic many-body methods and using the experimental values of the excitation energies. The dispersion coefficients are, finally, given as functions of the separation distance of an atomic system from the graphene layer and the ambiance temperature during the interactions. For easy extraction of these coefficients, we give a logistic fit to the functional forms of the dispersion coefficients in terms of the separation distances at the room temperature.

  3. Dispersion coefficients for the interactions of the alkali-metal and alkaline-earth-metal ions and inert-gas atoms with a graphene layer

    Science.gov (United States)

    Kaur, Kiranpreet; Arora, Bindiya; Sahoo, B. K.

    2015-09-01

    Largely motivated by a number of applications, the van der Waals dispersion coefficients C3 of the alkali-metal ions Li+,Na+,K+, and Rb+, the alkaline-earth-metal ions Ca+,Sr+,Ba+, and Ra+, and the inert-gas atoms He, Ne, Ar, and Kr with a graphene layer are determined precisely within the framework of the Dirac model. For these calculations, we evaluate the dynamic polarizabilities of the above atomic systems very accurately by evaluating the transition matrix elements employing relativistic many-body methods and using the experimental values of the excitation energies. The dispersion coefficients are given as functions of the separation distance of an atomic system from the graphene layer and the ambiance temperature during the interactions. For easy extraction of these coefficients, we give a logistic fit to the functional forms of the dispersion coefficients in terms of the separation distances at room temperature.

  4. An atom probe field ion microscope investigation of the role of boron in precipitates and at grain boundaries in NiAl

    International Nuclear Information System (INIS)

    This paper reports that the high resolution analytical technique of Atom Probe Field Ion Microscopy (APFIM) has been used to characterize grain boundaries and the matrix of a stoichiometric NiAl alloy doped with 0.04 (100 wppm) and 0.12 at. % (300 wppm) boron. Field ion images revealed boron segregation to the grain boundaries. Atom probe elemental analysis of the grain boundaries measured a boron coverage of up to 30% of a monolayer. Extensive atom probe analyses also revealed a fine dispersion of nanoscale boride precipitates in the matrix. The boron segregation to the grain boundaries was found to correlate with the observed suppression of intergranular fracture. However, the decrease in ductility of boron-doped NiAl is attributed in part to the precipitation hardening effect of the boride phases

  5. Resolving a discrepancy between experimental and theoretical lifetimes in atomic negative ions

    CERN Document Server

    Brage, Tomas

    2016-01-01

    Recently the lifetime of the excited $^{2}P_{1/2}$-state of S$^-$ was measured to be $503\\pm 54$ s (B\\"ackstr\\"om \\textit{et al.} Phys. Rev. Lett. 114, 143003 (2015)). The earlier theoretical lifetime of $436$ s was clearly outside the experimental error bars. To investigate this discrepancy we have performed systematic and large-scale Multi-configuration Dirac-Hartree-Fock calculations for this system. After including a careful treatment of correlation and relativistic effects, we predict a well-converged value of $492$ s for this lifetime, with an uncertainty considerably less than 1 \\%, thereby removing the apparent conflict between theory and experiment. We also show that this result corresponds to the non-relativistic limit in the $LS$-approximation for the M1-transition within this $^2P$-term. This approach for the M1-transition yields lifetimes for several $^2P$ fine-structure transitions in negative ions, which only depends on the transition energy and shows excellent agreement with recent lifetime me...

  6. Production, formation, and transport of high-brightness atomic hydrogen beam studies for the relativistic heavy ion collider polarized source upgrade

    Science.gov (United States)

    Kolmogorov, A.; Atoian, G.; Davydenko, V.; Ivanov, A.; Ritter, J.; Stupishin, N.; Zelenski, A.

    2014-02-01

    The RHIC polarized H- ion source had been successfully upgraded to higher intensity and polarization by using a very high brightness fast atomic beam source developed at BINP, Novosibirsk. In this source the proton beam is extracted by a four-grid multi-aperture ion optical system and neutralized in the H2 gas cell downstream from the grids. The proton beam is extracted from plasma emitter with a low transverse ion temperature of ˜0.2 eV which is formed by plasma jet expansion from the arc plasma generator. The multi-hole grids are spherically shaped to produce "geometrical" beam focusing. Proton beam formation and transport of atomic beam were experimentally studied at test bench.

  7. The role of phase separation for self-organized surface pattern formation by ion beam erosion and metal atom co-deposition

    Energy Technology Data Exchange (ETDEWEB)

    Hofsaess, H.; Zhang, K.; Pape, A.; Bobes, O.; Broetzmann, M. [Georg-August University Goettingen, II. Institute of Physics, Goettingen (Germany)

    2013-05-15

    We investigate the ripple pattern formation on Si surfaces at room temperature during normal incidence ion beam erosion under simultaneous deposition of different metallic co-deposited surfactant atoms. The co-deposition of small amounts of metallic atoms, in particular Fe and Mo, is known to have a tremendous impact on the evolution of nanoscale surface patterns on Si. In previous work on ion erosion of Si during co-deposition of Fe atoms, we proposed that chemical interactions between Fe and Si atoms of the steady-state mixed Fe{sub x} Si surface layer formed during ion beam erosion is a dominant driving force for self-organized pattern formation. In particular, we provided experimental evidence for the formation of amorphous iron disilicide. To confirm and generalize such chemical effects on the pattern formation, in particular the tendency for phase separation, we have now irradiated Si surfaces with normal incidence 5 keV Xe ions under simultaneous gracing incidence co-deposition of Fe, Ni, Cu, Mo, W, Pt, and Au surfactant atoms. The selected metals in the two groups (Fe, Ni, Cu) and (W, Pt, Au) are very similar regarding their collision cascade behavior, but strongly differ regarding their tendency to silicide formation. We find pronounced ripple pattern formation only for those co deposited metals (Fe, Mo, Ni, W, and Pt), which are prone to the formation of mono and disilicides. In contrast, for Cu and Au co-deposition the surface remains very flat, even after irradiation at high ion fluence. Because of the very different behavior of Cu compared to Fe, Ni and Au compared to W, Pt, phase separation toward amorphous metal silicide phases is seen as the relevant process for the pattern formation on Si in the case of Fe, Mo, Ni, W, and Pt co-deposition. (orig.)

  8. Surface Passivation of MoO3 Nanorods by Atomic Layer Deposition Towards High Rate Durable Li Ion Battery Anodes

    KAUST Repository

    Ahmed, Bilal

    2015-06-03

    We demonstrate an effective strategy to overcome the degradation of MoO3 nanorod anodes in Lithium (Li) ion batteries at high rate cycling. This is achieved by conformal nanoscale surface passivation of the MoO3 nanorods by HfO2 using atomic layer deposition (ALD). At high current density such as 1500 mA/g, the specific capacity of HfO2 coated MoO3 electrodes is 68% higher than bare MoO3 electrodes after 50 charge/discharge cycles. After 50 charge/discharge cycles, HfO2 coated MoO3 electrodes exhibited specific capacity of 657 mAh/g, on the other hand, bare MoO3 showed only 460 mAh/g. Furthermore, we observed that HfO2 coated MoO3 electrodes tend to stabilize faster than bare MoO3 electrodes because nanoscale HfO2 layer prevents structural degradation of MoO3 nanorods. Additionally, the growth temperature of MoO3 nanorods and the effect of HfO2 layer thickness was studied and found to be important parameters for optimum battery performance. The growth temperature defines the microstructural features and HfO2 layer thickness defines the diffusion coefficient of Li–ions through the passivation layer to the active material. Furthermore, ex–situ HRTEM, X–ray photoelectron spectroscopy (XPS), Raman spectroscopy and X–ray diffraction was carried out to explain the capacity retention mechanism after HfO2 coating.

  9. Surface Passivation of MoO₃ Nanorods by Atomic Layer Deposition toward High Rate Durable Li Ion Battery Anodes.

    Science.gov (United States)

    Ahmed, B; Shahid, Muhammad; Nagaraju, D H; Anjum, D H; Hedhili, Mohamed N; Alshareef, H N

    2015-06-24

    We demonstrate an effective strategy to overcome the degradation of MoO3 nanorod anodes in lithium (Li) ion batteries at high-rate cycling. This is achieved by conformal nanoscale surface passivation of the MoO3 nanorods by HfO2 using atomic layer deposition (ALD). At high current density such as 1500 mA/g, the specific capacity of HfO2-coated MoO3 electrodes is 68% higher than that of bare MoO3 electrodes after 50 charge/discharge cycles. After 50 charge/discharge cycles, HfO2-coated MoO3 electrodes exhibited specific capacity of 657 mAh/g; on the other hand, bare MoO3 showed only 460 mAh/g. Furthermore, we observed that HfO2-coated MoO3 electrodes tend to stabilize faster than bare MoO3 electrodes because nanoscale HfO2 layer prevents structural degradation of MoO3 nanorods. Additionally, the growth temperature of MoO3 nanorods and the effect of HfO2 layer thickness was studied and found to be important parameters for optimum battery performance. The growth temperature defines the microstructural features and HfO2 layer thickness defines the diffusion coefficient of Li-ions through the passivation layer to the active material. Furthermore, ex situ high resolution transmission electron microscopy, X-ray photoelectron spectroscopy, Raman spectroscopy, and X-ray diffraction were carried out to explain the capacity retention mechanism after HfO2 coating.

  10. Determination of arsenic speciation in sulfidic waters by Ion Chromatography Hydride-Generation Atomic Fluorescence Spectrometry (IC-HG-AFS).

    Science.gov (United States)

    Keller, Nicole S; Stefánsson, Andri; Sigfússon, Bergur

    2014-10-01

    A method for the analysis of arsenic species in aqueous sulfide samples is presented. The method uses an ion chromatography system connected with a Hydride-Generation Atomic Fluorescence Spectrometer (IC-HG-AFS). With this method inorganic As(III) and As(V) species in water samples can be analyzed, including arsenite (HnAs(III)O3(n-3)), thioarsenite (HnAs(III)S3(n-3)), arsenate (HnAs(V)O4(n-3)), monothioarsenate (HnAs(V)SO3(n-3)), dithioarsenate (HnAs(V)S2O2(n-3)), trithioarsenate (HnAs(V)S3O(n-3)) and tetrathioarsenate (HnAs(V)S4(n-3)). The peak identification and retention times were determined based on standard analysis of the various arsenic compounds. The analytical detection limit was ~1-3 µg L(-1) (LOD), depending on the quality of the baseline. This low detection limit makes this method also applicable to discriminate between waters meeting the drinking water standard of max. 10 µg L(-1) As, and waters that do not meet this standard. The new method was successfully applied for on-site determination of arsenic species in natural sulfidic waters, in which seven species were unambiguously identified.

  11. Metal atom and ion layers observed by a frequency-tunable resonance scattering lidar in the midlatitude

    Science.gov (United States)

    Ejiri, Mitsumu K.; Nakamura, Takuji; Kawahara, Takuya D.; Tsuno, Katsuhiko; Abo, Makoto; Nishiyama, Takanori; Tsuda, Takuo; Wada, Satoshi; Ogawa, Takayo

    2016-07-01

    The National Institute of Polar Research (NIPR) is leading a six year prioritized project of the Antarctic research observations since 2010. One of the sub-project is entitled the global environmental change revealed through the Antarctic middle and upper atmosphere. Profiling dynamical parameters such as temperature and wind, as well as minor constituents is the key component of observations in this project, together with a long term observations using existent various instruments in Syowa, the Antarctica (69S). As a part of the sub-project, we are developing a new resonance lidar system with multiple wavelengths and plan to install and operate it at Syowa, Antarctica. The lidar will observe temperature profiles and variations of minor constituents such as Fe, K, Ca+, and aurorally excited N2+. The lidar system is being developed with trial and error in test observations of the metal atom and ion density and the MLT temperature profiles. The lidar will be installed at Syowa in Antarctica by the 58th Japan Antarctic Research Expedition (JARE 58). In this presentation, we will report current status of the system developments and discuss results of the test observations.

  12. Atomic absorption spectroscopic, conductometric and colorimetric methods for determination of fluoroquinolone antibiotics using ammonium reineckate ion-pair complex formation

    Science.gov (United States)

    Ragab, Gamal H.; Amin, Alaa S.

    2004-03-01

    Three accurate, rapid and simple atomic absorption spectrometric, conductometric and colorimetric methods were developed for the determination of norfloxacin (NRF), ciprofloxacin (CIP), ofloxacin (OFL) and enrofloxacin (ENF). The proposed methods depend upon the reaction of ammonium reineckate with the studied drugs to form stable precipitate of ion-pair complexes, which was dissolved in acetone. The pink coloured complexes were determined either by AAS or colorimetrically at λmax 525 nm directly using the dissolved complex. Using conductometric titration, the studied drugs could be evaluated in 50% (v/v) acetone in the range 5.0-65, 4.0-48, 5.0-56 and 6.0-72 μg ml -1 of NRF, CPF, OFL and ENF, respectively. The optimizations of various experimental conditions were described. The results obtained showed good recoveries of 99.15±1.15, 99.30±1.40, 99.60±1.50, and 99.00±1.25% with relative standard deviations of 0.81, 1.06, 0.97, and 0.69% for NRF, CPF, OFL, and ENF, respectively. Applications of the proposed methods to representative pharmaceutical formulations are successfully presented.

  13. Dimensional comparison between amplitude-modulation atomic force microscopy and scanning ion conductance microscopy of biological samples

    Science.gov (United States)

    Kim, Joonhui; Choi, MyungHoon; Jung, Goo-Eun; Rahim Ferhan, Abdul; Cho, Nam-Joon; Cho, Sang-Joon

    2016-08-01

    The range of scanning probe microscopy (SPM) applications for atomic force microscopy (AFM) is expanding in the biological sciences field, reflecting an increasing demand for tools that can improve our fundamental understanding of the physics behind biological systems. However, the complexity associated with applying SPM techniques in biomedical research hampers the full exploitation of its capabilities. Recently, the development of scanning ion conductance microscopy (SICM) has overcome these limitations and enabled contact-free, high resolution imaging of live biological specimens. In this work, we demonstrate the limitation of AFM for imaging biological samples in liquid due to artifacts arising from AFM tip-sample interaction, and how SICM imaging is able to overcome those limitations with contact-free scanning. We also demonstrate that SICM measurements, when compared to AFM, show better fit to the actual dimensions of the biological samples. Our results highlight the superiority of SICM imaging, enabling it to be widely adopted as a general and versatile research tool for biological studies in the nanoscale.

  14. Modification of SnO2 Anodes by Atomic Layer Deposition for High Performance Lithium Ion Batteries

    KAUST Repository

    Yesibolati, Nulati

    2013-05-01

    Tin dioxide (SnO2) is considered one of the most promising anode materials for Lithium ion batteries (LIBs), due to its large theoretical capacity and natural abundance. However, its low electronic/ionic conductivities, large volume change during lithiation/delithiation and agglomeration prevent it from further commercial applications. In this thesis, we investigate modified SnO2 as a high energy density anode material for LIBs. Specifically two approaches are presented to improve battery performances. Firstly, SnO2 electrochemical performances were improved by surface modification using Atomic Layer Deposition (ALD). Ultrathin Al2O3 or HfO2 were coated on SnO2 electrodes. It was found that electrochemical performances had been enhanced after ALD deposition. In a second approach, we implemented a layer-by-layer (LBL) assembled graphene/carbon-coated hollow SnO2 spheres as anode material for LIBs. Our results indicated that the LBL assembled electrodes had high reversible lithium storage capacities even at high current densities. These superior electrochemical performances are attributed to the enhanced electronic conductivity and effective lithium diffusion, because of the interconnected graphene/carbon networks among nanoparticles of the hollow SnO2 spheres.

  15. Dimensional comparison between amplitude-modulation atomic force microscopy and scanning ion conductance microscopy of biological samples

    Science.gov (United States)

    Kim, Joonhui; Choi, MyungHoon; Jung, Goo-Eun; Rahim Ferhan, Abdul; Cho, Nam-Joon; Cho, Sang-Joon

    2016-08-01

    The range of scanning probe microscopy (SPM) applications for atomic force microscopy (AFM) is expanding in the biological sciences field, reflecting an increasing demand for tools that can improve our fundamental understanding of the physics behind biological systems. However, the complexity associated with applying SPM techniques in biomedical research hampers the full exploitation of its capabilities. Recently, the development of scanning ion conductance microscopy (SICM) has overcome these limitations and enabled contact-free, high resolution imaging of live biological specimens. In this work, we demonstrate the limitation of AFM for imaging biological samples in liquid due to artifacts arising from AFM tip–sample interaction, and how SICM imaging is able to overcome those limitations with contact-free scanning. We also demonstrate that SICM measurements, when compared to AFM, show better fit to the actual dimensions of the biological samples. Our results highlight the superiority of SICM imaging, enabling it to be widely adopted as a general and versatile research tool for biological studies in the nanoscale.

  16. Elegant design of electrode and electrode/electrolyte interface in lithium-ion batteries by atomic layer deposition

    International Nuclear Information System (INIS)

    Lithium-ion batteries (LIBs) are very promising power supply systems for a variety of applications, such as electric vehicles, plug-in hybrid electric vehicles, grid energy storage, and microelectronics. However, to realize these practical applications, many challenges need to be addressed in LIBs, such as power and energy density, cycling lifetime, safety, and cost. Atomic layer deposition (ALD) is emerging as a powerful technique for solving these problems due to its exclusive advantages over other film deposition counterparts. In this review, we summarize the state-of-the-art progresses of employing ALD to design novel nanostructured electrode materials and solid-state electrolytes and to tailor electrode/electrolyte interface by surface coatings in order to prevent unfavorable side reactions and achieve optimal performance of the electrode. Insights into the future research and development of the ALD technique for LIB applications are also discussed. We expect that this review article will provide resourceful information to researchers in both fields of LIBs and ALD and also will stimulate more insightful studies of using ALD for the development of next-generation LIBs. (review)

  17. Core-shell Si@TiO2 nanosphere anode by atomic layer deposition for Li-ion batteries

    Science.gov (United States)

    Bai, Ying; Yan, Dong; Yu, Caiyan; Cao, Lina; Wang, Chunlei; Zhang, Jinshui; Zhu, Huiyuan; Hu, Yong-Sheng; Dai, Sheng; Lu, Junling; Zhang, Weifeng

    2016-03-01

    Silicon (Si) has been regarded as next-generation anode for high-energy lithium-ion batteries (LIBs) due to its high Li storage capacity (4200 mA h g-1). However, the mechanical degradation and resultant capacity fade critically hinder its practical application. In this regard, we demonstrate that nanocoating of Si spheres with a 3 nm titanium dioxide (TiO2) layer via atomic layer deposition (ALD) can utmostly balance the high conductivity and the good structural stability to improve the cycling stability of Si core material. The resultant sample, Si@TiO2-3 nm core-shell nanospheres, exhibits the best electrochemical performance of all with a highest initial Coulombic efficiency and specific charge capacity retention after 50 cycles at 0.1C (82.39% and 1580.3 mA h g-1). In addition to making full advantage of the ALD technique, we believe that our strategy and comprehension in coating the electrode and the active material could provide a useful pathway towards enhancing Si anode material itself and community of LIBs.

  18. Application of cloud point preconcentration and flame atomic absorption spectrometry for the determination of cadmium and zinc ions in urine, blood serum and water samples

    Directory of Open Access Journals (Sweden)

    Ardeshir Shokrollahi

    2013-01-01

    Full Text Available A simple, sensitive and selective cloud point extraction procedure is described for the preconcentration and atomic absorption spectrometric determination of Zn2+ and Cd2+ ions in water and biological samples, after complexation with 3,3',3",3'"-tetraindolyl (terephthaloyl dimethane (TTDM in basic medium, using Triton X-114 as nonionic surfactant. Detection limits of 3.0 and 2.0 µg L-1 and quantification limits 10.0 and 7.0 µg L-1were obtained for Zn2+ and Cd2+ ions, respectively. Relative standard deviation was 2.9 and 3.3, and enrichment factors 23.9 and 25.6, for Zn2+ and Cd2+ ions, respectively. The method enabled determination of low levels of Zn2+ and Cd2+ ions in urine, blood serum and water samples.

  19. Negative ions, energy loss, and electron emission during grazing scattering of fast H and He atoms from a clean and oxidized NiAl(1 1 0) surface

    Energy Technology Data Exchange (ETDEWEB)

    Blauth, D. [Institut fuer Physik der Humboldt, Universitaet zu Berlin, Newtonstr. 15, D-12489 Berlin-Adlershof (Germany); Winter, H., E-mail: winter@physik.hu-berlin.de [Institut fuer Physik der Humboldt, Universitaet zu Berlin, Newtonstr. 15, D-12489 Berlin-Adlershof (Germany)

    2011-06-01

    Negative ion fractions, projectile energy loss, and the emission of electrons is studied for grazing scattering of hydrogen and helium atoms/ions from a clean and oxidized NiAl(1 1 0) surface. Making use of translation energy spectroscopy and the coincident detection of the number of emitted electrons we have studied the electronic interaction mechanisms for the change from a clean metal target to an insulator surface via the preparation of a well defined ultrathin alumina film on top of the metal substrate. We find that already for a monolayer thick oxide film the characteristic different features of electronic processes for the surface of an insulator crystal are present.

  20. Velocity dependence of ionization probability of Be, Cu, Ag, W, Pb and Sn atoms sputtered by 5.5 keV Ar+ ions

    International Nuclear Information System (INIS)

    The energy distributions of both ions and neutral atoms sputtered during ion bombardment of a few polycrystalline metals have been measured. The absolute values of the ionization probability P+ as a function of the emitted particle velocity ν were obtained. The ionization probability for Be, Cu, Ag and W targets is found to depend exponentially on the particle velocity in accordance with the electron tunneling model. In the case of Pb and Sn the ionization probability shows strong deviation from an exponential dependence at high emission energies. (author)

  1. A novel approach for site-specific atom probe specimen preparation by focused ion beam and transmission electron backscatter diffraction

    International Nuclear Information System (INIS)

    Atom probe tomography (APT) is a suitable technique for chemical analyses with almost atomic resolution. However, the time-consuming site-specific specimen preparation can be improved. Recently, transmission electron backscatter diffraction (t-EBSD) has been established for high resolution crystallographic analyses of thin foils. In this paper we present the first successful application of a combined focused ion beam (FIB)/t-EBSD preparation of site-specific APT specimens using the example of grain boundary segregation in technically pure molybdenum. It will be shown that the preparation of a grain boundary can be substantially accelerated by t-EBSD analyses in-between the annular milling FIB procedure in the same microscope. With this combined method, a grain boundary can easily be recognized and positioned in the first 220 nm of an APT sample much faster than e.g. with complementary investigations in a transmission electron microscope. Even more, the high resolution technique of t-EBSD gives the opportunity to get crystallographic information of the mapped area and, therefore, an analysis of the grain boundary character to support the interpretation of the APT data files. To optimize this newly developed technique for the application on needle-shaped APT specimens, a parameter study on enhanced background correction, acceleration voltage, and tilt angle was carried out. An acceleration voltage of 30 kV at specimen surface tilt angles between −45° and −35° from horizontal plane leads to the best results. Even for molybdenum the observation of crystal orientation data up to about 200 nm specimen thickness is possible. - Highlights: • We developed a new site-specific APT specimen preparation method by FIB and t-EBSD. • A grain boundary was positioned in the first 220 nm of the APT tip by the FIB/t-EBSD method. • Crystallographic information of the mapped area can be quickly obtained. • An acceleration voltage of 30 kV at specimen surface tilt angles

  2. The direct ionization processes in the collisions of partially stripped carbon and oxygen ions with helium atoms at low-to-intermediate energies

    Institute of Scientific and Technical Information of China (English)

    Zhou Chun-Lin; Shao Jian-Xiong; Chen Xi-Meng; Sun Guang-Zhi; Zou Xian-Rong

    2008-01-01

    The values of direct double- to-single ionization ratio R of helium atoms induced by Cq+,Oq+ (q=1-4) ions at incident energies from 0.2 to 8.5MeV are measured.Based on the existing model (Shao J X,Chen X M and Ding B W 2007 Phys.Rev.A 75 012701) the effective charge of the projectile is introduced to theoretically estimate the value of R for the partially stripped ions impacting on helium atoms.The results calculated from our "effective charge" model are in good agreement with the experimental data,and the dependence of the effective charge on the ionization energy of the projectile is also discussed qualitatively.

  3. Solar wind He pickup ions as source of tens-of-keV/n neutral He atoms observed by the HSTOF/SOHO detector

    CERN Document Server

    Grzedzielski, S; Czechowski, A; Hilchenbach, M

    2013-01-01

    Context. The HSTOF instrument on board SOHO satellite measures since 1996, during periods of low solar activity, weak fluxes of He atoms of 28-58 keV/n (helium energetic neutral atoms - He ENA). The probable source region is the inner heliosheath. Aims. Understand the emission mechanism of He ENA based on knowledge of heliosheath spatial extent and plasma content resulting from Voyager 1 & 2 measurements in the period posterior to termination shock crossings. Methods. He ENA are generated by charge-exchange neutralization of energetic helium ions on interstellar neutral H and He. Energy spectra of helium ions in the heliosheath are calculated by following the evolution of their velocity distribution functions when carried by, and undergoing binary interactions with, plasma constituents of a background flow whose particle populations are modeled to approximately render post-termination shock Voyager data. Results. The observed HSTOF He ENA form a higher energy part of general heliospheric He ENA fluxes and...

  4. Ground States of the Lithium Atom and its Ions up to Z = 10 in the Presence of Magnetic Field using Variational Monte Carlo Technique

    CERN Document Server

    Doma, S B; Farag, A M; El-Gammal, F N

    2016-01-01

    The variational Monte Carlo method is applied to investigate the ground state energy of the lithium atom and its ions up to Z=10 in the presence of an external magnetic field regime. Our calculations are based on using three forms of compact and accurate trial wave functions, which were put forward in calculating energies in the absence of magnetic field. The obtained results are in good agreement with the most recent accurate values and also with the exact values.

  5. Analisa Kadar Ion Besi, Kadmium Dan Kalsium Dalam Air Minum Kemasan Galon Dan Air Minum Kemasan Galon Isi Ulang Dengan Metode Spektrofotometri Serapan Atom

    OpenAIRE

    Susanti, Widia

    2010-01-01

    The analysis of iron, cadmium and calcium ion in drinking water has been carried out. The samples analyzed are drinking water packaging gallons from official agencies and drinking water packaging refill gallons. The water was distributed with tank from the mountains and the wells drilled. Samples were analyzed every week for a month. Water samples was added with HNO3 (c) and analyzed by using atomic absorption spectrophotometer. The concentration of iron, cadmium and calcium was determined wi...

  6. Selective cloud point extraction and graphite furnace atomic absorption spectrometric determination of molybdenum (VI) ion in seawater samples

    Energy Technology Data Exchange (ETDEWEB)

    Filik, Hayati, E-mail: filik@istanbul.edu.tr [Istanbul University, Faculty of Engineering, Department of Chemistry, Avcilar, 34320 Istanbul (Turkey); Cengel, Tayfun; Apak, Resat [Istanbul University, Faculty of Engineering, Department of Chemistry, Avcilar, 34320 Istanbul (Turkey)

    2009-09-30

    A cloud point extraction process using the nonionic surfactant Triton X-114 to extract molybdenum from aqueous solutions was investigated. The method is based on the complexation reaction of Mo(VI) with 1,2,5,8-tetrahydroxyanthracene-9,10-dione (quinalizarine: QA) and micelle-mediated extraction of the complex. The enriched analyte in the surfactant-rich phase was determined by graphite furnace atomic absorption spectrometry (GFAAS). The optimal extraction and reaction conditions (e.g. pH, reagent and surfactant concentrations, temperature, incubation and centrifugation times) were evaluated and optimized. Under the optimized experimental conditions, the limit of detection (LOD) for Mo(VI) was 7.0 ng L{sup -1} with an preconcentration factor of {approx}25 when 10 mL of sample solution was preconcentrated to 0.4 mL. The proposed method (with extraction) showed linear calibration within the range 0.03-0.6 {mu}g L{sup -1}. The relative standard deviation (RSD) was found to be 3.7% (C{sub Mo(VI)} = 0.05 {mu}g L{sup -1}, n = 5) for pure standard solutions, whereas RSD for the recoveries from real samples ranged between 2 and 8% (mean RSD = 3.9%). The method was applied to the determination of Mo(VI) in seawater and tap water samples with a recovery for the spiked samples in the range of 98-103%. The interference effect of some cations and anions was also studied. In the presence of foreign ions, no significant interference was observed. In order to verify the accuracy of the method, a certified reference water sample was analysed and the results obtained were in good agreement with the certified values.

  7. The use of ion chromatography-dc plasma atomic emission spectrometry for the speciation of trace metals

    Energy Technology Data Exchange (ETDEWEB)

    Urasa, I.T.

    1991-09-20

    The original objects of this research program were: to interface d.c. plasma atomic emission spectrometer with an ion chromatograph; to characterize and optimize the combined systems for application in the speciation of metals in aqueous solutions; to use this system in the study of the solution chemistry of various metals; and to find ways in which the measurement sensitivity of the method can be enhanced, thereby allowing the detection of metal species at low ppb concentration levels. This approach has been used to study the chemistry of and speciate several elements in solution including: arsenic, chromium, iron, manganese, nickel phosphorus, platinum, selenium, and vanadium. During the course of this research, we have found that the solution chemistry of the elements studied and the speciation data obtained can vary considerably depending on the solution, and the chromatographic conditions employed. The speciation of chromium, iron, and vanadium was found to be highly influenced by the acidity of the sample. The element selective nature of the d.c. plasma detector allows these changes to be monitored, thereby providing quantitative information on the new moieties formed. New approaches are being developed including the use of chelating ligands as preconcentration agents for purposes of reducing further the detection limits of the elements of interest and to improve the overall element speciation scheme. New thrusts are being directed towards the employment of post-column derivatization method coupled with colorimetric measurements to detect and quantify metal species eluting from the chromatographic column. The influence of sample acidity on these investigations will be carefully evaluated. These new thrusts are described in the accompanying Project Renewal Proposal.

  8. Multidimensional characterisation of biomechanical structures by combining Atomic Force Microscopy and Focused Ion Beam: A study of the rat whisker.

    Science.gov (United States)

    Adineh, Vahid Reza; Liu, Boyin; Rajan, Ramesh; Yan, Wenyi; Fu, Jing

    2015-07-01

    Understanding the heterogeneity of biological structures, particularly at the micro/nano scale can offer insights valuable for multidisciplinary research in tissue engineering and biomimicry designs. Here we propose to combine nanocharacterisation tools, particularly Focused Ion Beam (FIB) and Atomic Force Microscopy (AFM) for three dimensional mapping of mechanical modulus and chemical signatures. The prototype platform is applied to image and investigate the fundamental mechanics of the rat face whiskers, a high-acuity sensor used to gain detailed information about the world. Grazing angle FIB milling was first applied to expose the interior cross section of the rat whisker sample, followed by a "lift-out" method to retrieve and position the target sample for further analyses. AFM force spectroscopy measurements revealed a non-uniform pattern of elastic modulus across the cross section, with a range from 0.8GPa to 13.5GPa. The highest elastic modulus was found at the outer cuticle region of the whisker, and values gradually decreased towards the interior cortex and medulla regions. Elemental mapping with EDS confirmed that the interior of the rat whisker is dominated by C, O, N, S, Cl and K, with a significant change of elemental distribution close to the exterior cuticle region. Based on these data, a novel comprehensive three dimensional (3D) elastic modulus model was constructed, and stress distributions under realistic conditions were investigated with Finite Element Analysis (FEA). The simulations could well account for the passive whisker deflections, with calculated resonant frequency as well as force-deflection for the whiskers being in good agreement with reported experimental data. Limitations and further applications are discussed for the proposed FIB/AFM approach, which holds good promise as a unique platform to gain insights on various heterogeneous biomaterials and biomechanical systems. PMID:25839121

  9. The effects of correlation, relativity, exchange, channels coupling and polarization in scattering of electrons by alkali-metal atoms and alkali-like ions

    International Nuclear Information System (INIS)

    The present review briefly presents the growing experimental as well as theoretical interest in recent years in the effects of correlation, relativity, exchange, channels coupling and polarization on the high precision scattering of electron by alkali-metal atoms and alkali-like ions. Many high precision experiments have been performed which need very high accurate theoretical prediction for correct interpretation and identification of different physical effects involved. Several sophisticated theoretical techniques have been developed for inclusion of the above mentioned effects which play an extremely important role in order to obtain results of high accuracy for understanding experimental observation of high precision. At present, we do not have a comprehensive and practical atomic scattering theory which accounts for all these effects on an equal footing. Future challenges and directions, in reliable electron-atom scattering calculations, have been discussed and suggested. (author). 136 refs, 16 figs

  10. Atomic absorption spectrometric determination of some metal ions after preconcentration by solid phase extraction using amberlite XAD 16 resin loaded with thenoyltrifluoroacetone

    International Nuclear Information System (INIS)

    Complete text of publication follows. The direct determination of extremely low concentrations of trace elements by modern atomic spectroscopic methods, such as atomic absorption spectrometry and inductively coupled plasma atomic emission spectrometry is often difficult because of insufficient sensitivity and selectivity of the methods used. For this reason, the preliminary separation and preconcentration of trace elements from the matrix are often required. Solid phase extraction shows several major advantages such as simplicity, rapidity and high enrichment factor, the ability of combination with different detection techniques in the form of on-line or off-line mode and finally cost saving (Tokalioglu et al., Microchim Acta 164 (2009) 471-477.). A new solid phase extraction method for the separation and preconcentration of Cu(II), Pb(II), Ni(II), Co(II), Mn(II) and Fe(III) ions was developed. As solid phase material, Amberlite XAD-16 resin loaded with thenoyltrifluoroacetone (TTA) was used. For this purpose, 0.5 g of the resin was saturated with 10 mL of 0.5% (w/v) TTA solution. After preconcentrating, the metals retained on the resin were eluted with 10 mL of 2 mol L-1 HCl and then determined by flame atomic absorption spectrometry. The effect of some parameters for the preconcentration of the metal ions was investigated. The optimum pH was found as 6. Eluent for quantitative elution was 10 mL of 2 mol L-1 HCl.

  11. Excitation of atoms and molecules in collisions with fast, highly charged ions: Progress report for the period January 1, 1988 to February 28, 1989

    International Nuclear Information System (INIS)

    This report summarizes progress in research supported by DOE Grant FG05-84ER13262 during the period January 1, 1988 to February 29, 1989. The research program continues to emphasize the investigation of multielectron ionization and capture processes in fast heavy-ion collisions. Several major projects were completed this year and a number of new ones begun. Among the completed projects were an investigation of resonant multielectron transfer to double K-vacancy states in solid oxygen compounds, and a study of collisional quenching of 23P and 24P states in 33 MeV two- and three-electron Mg ions. New projects include a systematic investigation of the projectile charge dependence of cross sections for Ar recoil-ion production in 1 MeV/amu oxygen ion collisions production, and a design study for an atomic physics beam line to be connected to an electron-cyclotron-resonance (ECR) ion source. Work on molecular fragmentation in heavy-ion collisions continued

  12. Experimental study of interactions of highly charged ions with atoms at keV energies. Progress report, May 15, 1981-May 14, 1982

    International Nuclear Information System (INIS)

    An electron beam ion source, EBIS, to be used in experimental investigations of interactions of highly charged ions with atoms at keV energies has been constructed. The EBIS generates low energy, multiply charged ions by successive electron impact ionization of ions trapped in an intense, magnetically confined electron beam. A 2 keV, approx. 10 A/cm2 electron beam has been successfully launched from an external, high convergence electron gun into a 4 kG, 50 cm long solenoidal magnetic field and propagated through sixteen tubes fabricated from stainless steel mesh and concentric with the beam. An innovative feature of the source is the use of a distributed sputter-ion pump to create the necessary ultra-high vacuum environment in the ionization region. A microprocessor based sixteen channel power supply which generates the potential distribution applied to the drift tubes for axial trapping of the ions has been designed and constructed. A study of source properties is in progress

  13. Changes of the electronic structure of the atoms of nitrogen in nitrogen-doped multiwalled carbon nanotubes under the influence of pulsed ion radiation

    Energy Technology Data Exchange (ETDEWEB)

    Korusenko, P.M., E-mail: korusenko@obisp.oscsbras.ru [Omsk Scientific Centre, Siberian Branch, Russian Academy of Sciences, Karl Marx Avenue, 15, Omsk 644024 (Russian Federation); Bolotov, V.V.; Nesov, S.N.; Povoroznyuk, S.N. [Omsk Scientific Centre, Siberian Branch, Russian Academy of Sciences, Karl Marx Avenue, 15, Omsk 644024 (Russian Federation); Khailov, I.P. [Tomsk Polytechnic University, Lenin Ave. 2a, Tomsk 634028 (Russian Federation)

    2015-09-01

    With the use of X-ray photoelectron spectroscopy (XPS) there have been investigated the changes of the chemical state of nitrogen atoms in the structure of nitrogen-doped multiwalled carbon nanotubes (CN{sub x}-MWCNTs) resulting from the impact of pulsed ion beam at various parameters of the beam (energy density, number of pulses). It has been established that irradiation with the pulsed ion beam leads to a reduction of the total amount of nitrogen in CN{sub x} nanotubes. It has been shown that a single pulse irradiation of ion beam at the energy densities of 0.5, 1, 1.5 J/cm{sup 2} leads to restructuring of the nitrogen from pyridinic and pyrrolic configuration to graphitic state. Complete removal of nitrogen (pyridinic, pyrrolic, graphitic) embedded in the structure of the walls of CN{sub x} nanotubes occurs at ten pulses and 1.5 J/cm{sup 2}.

  14. Atomic Oxygen (ATOX) simulation of Teflon FEP and Kapton H surfaces using a high intensity, low energy, mass selected, ion beam facility

    Science.gov (United States)

    Vered, R.; Grossman, E.; Lempert, G. D.; Lifshitz, Y.

    1994-01-01

    A high intensity (greater than 10(exp 15) ions/sq cm) low energy (down to 5 eV) mass selected ion beam (MSIB) facility was used to study the effects of ATOX on two polymers commonly used for space applications (Kapton H and Teflon FEP). The polymers were exposed to O(+) and Ne(+) fluences on 10(exp 15) - 10(exp 19) ions/sq cm, using 30eV ions. A variety of analytical methods were used to analyze the eroded surfaces including: (1) atomic force microscopy (AFM) for morphology measurements; (2) total mass loss measurements using a microbalance; (3) surface chemical composition using x-ray photoelectron spectroscopy (XPS), and (4) residual gas analysis (RGA) of the released gases during bombardment. The relative significance of the collisional and chemical degradation processes was evaluated by comparing the effects of Ne(+) and O(+) bombardment. For 30 eV ions it was found that the Kapton is eroded via chemical mechanisms while Teflon FEP is eroded via collisional mechanisms. AFM analysis was found very powerful in revealing the evolution of the damage from its initial atomic scale (roughness of approx. 1 nm) to its final microscopic scale (roughness greater than 1 micron). Both the surface morphology and the average roughness of the bombarded surfaces (averaged over 1 micron x 1 micron images by the system's computer) were determined for each sample. For 30 eV a non linear increase of the Kapton roughness with the O(+) fluence was discovered (a slow increase rate for fluences phi less than 5 x 10(exp 17) O(+)/sq cm, and a rapid increase rate for phi greater than 5 x 10(exp 17) O(+)/sq cm). Comparative studies on the same materials exposed to RF and DC oxygen plasmas indicate that the specific details of the erosion depend on the simulation facility emphasizing the advantages of the ion beam facility.

  15. Experimental study of interactions of highly charged ions with atoms at keV energies. Progress report, May 15, 1983-May 14, 1984

    International Nuclear Information System (INIS)

    The interest, both theoretical and experimental, in interactions of low energy highly charged ions with electrons, atoms or ions is partly due to the importance of such interactions to controlled thermonuclear fusion research and partly to the intrinsically interesting nature of the fundamental processes involved. This program centers around two main lines of activity. One involves atomic physics experiments and source studies and development using a small EBIS, called CEBIS I, which was constructed and tested under DOE contract. The other, initiated in August 1983, involves the design, construction and development of a larger superconducting solenoid version, called CEBIS II, capable of competing with existing and under construction European sources. CEBIS I is used to investigate low energy charge transfer to multiply charged ions, in particular to measure partial cross sections for population of specific states of the projectile as a function of its energy for C/sup q+/, N/sub q+/ and O/sup q+/ (q greater than or equal to 3) colliding with molecular hydrogen and helium in the 0.05 qkeV to 5 qkeV range. Specific states of the projectile populated in the collision are selected by high resolution energy gain spectroscopy. The immediate goal of CEBIS II will be to generate a usable, approx. 3 qkeV beam of Ar18+. Longer range goals include optimization of the source and gradually upgrading it to handle a 25 kV, 1A electron beam which could be used to produce He-like xenon. Both sources will be used in atomic physics experiments involving low energy highly charged ions and studies of the behavior and properties of EBIS sources in general

  16. Setup and proof of principle of SAPIS (Stored Atoms Polarized Ion Source), a novel source of polarized H{sup -}/D{sup -} ions; Aufbau und Funktionsnachweis von SAPIS (Stored Atoms Polarized Ion Source), einer neuartigen Quelle polarisierter H{sup -}/D{sup -}-Ionen

    Energy Technology Data Exchange (ETDEWEB)

    Emmerich, R.

    2007-02-14

    The objective of this work was the setup and the proof-of-principle of a new type of negative polarized hydrogen or deuterium ion source, which is based on the charge-exchange reaction (vector)H{sup 0}+Cs{sup 0}{yields}(vector)H{sup -}+Cs{sup +}, as for instance the Colliding-Beams-Source (CBS) at the Cooler Synchrotron COSY in Juelich. In contrast to the CBS, the use of a storage cell for the charge-exchange region promises an increase in H{sup -} current by at least an order of magnitude without considerable polarization losses. For these purposes, a new laboratory was equipped and both a polarized hydrogen/deuterium atomic beam source and an intense neutral cesium-beam source have been build-on. A Lambshift polarimeter, which allows the measurement of the nuclear polarization of the atomic as well as ionic beams, was completed with the construction of a new spin-filter. After commissioning and optimizing each of these sources, a storage cell was developed and installed in the charge-exchange region with a magnetic field. Additionally, components for the extraction, detection and analysis of the negative ion beam were installed. Following the decisive proof of principle, investigation of the properties of the storage cell, especially as to H recombination and depolarisation, was begun. Furthermore, a number of software programs was developed for the control and monitoring of different components of the sources as well as a universal measuring software for the complete installation, including the measurement and calculation of the beam polarization. At the same time, the remote control system of the Cologne source of polarized ions LASCO at the FN tandem accelerator was completely modernized. (orig.)

  17. High-energy collision-induced dissociation of [M+Na]+ ions desorbed by fast atom bombardment of ceramides isolated from the starfish Distolasterias nipon.

    Science.gov (United States)

    Yoo, Ji Sun; Park, Taeseong; Bang, Geul; Lee, Chulhyun; Rho, Jung-Rae; Kim, Young Hwan

    2013-02-01

    Ten ceramides and four cerebrosides were extracted from the starfish Distolasterias nipon by solvent extraction, silica gel column chromatography and reversed-phase high-performance liquid chromatography. Structural identification was conducted using tandem mass spectrometry of monosodiated ions desorbed by fast atom bombardment. The complete structures of four cerebrosides were determined by a previously reported method. The high-energy collision-induced dissociation (CID) spectral characteristics of ceramides with various structures depend on the number and positions of double bonds on both the N-acyl and sphingoid chains, the presence of a hydroxyl group or a double bond at the C-4 position of the sphingoid chain and the presence of an α-hydroxy group on the N-acyl chain. The high-energy CID of the monosodiated ion, [M+Na](+), of each ceramide molecular species generated abundant ions, providing information on the composition of the fatty acyl chains and sphingoid long-chain bases. Each homologous ion series along the fatty acyl group and aliphatic chain of the sphingoid base was used for locating the double-bond positions of both chains and hydroxyl groups on the sphingoid base chain. The double-bond positions were also confirmed by the m/z values of abundant allylic even- and odd-electron ions, and the intensity ratio of the T ion peak relative to the O ion peak. This technique could determine the complete structures of ceramides and cerebrosides in an extract mixture and has great potential for determining other sphingolipids isolated from various biological sources. PMID:23378088

  18. Change in magnetic and structural properties of FeRh thin films by gold cluster ion beam irradiation with the energy of 1.67 MeV/atom

    Science.gov (United States)

    Koide, T.; Saitoh, Y.; Sakamaki, M.; Amemiya, K.; Iwase, A.; Matsui, T.

    2014-05-01

    The effect of energetic cluster ion beam irradiation on magnetic and structural properties of FeRh thin films have been investigated. The cluster ions used in the present studies consist of a few gold atoms with the energy of 1.67 MeV/gold atom. Saturation magnetization of the sample irradiated with Au3 cluster ion beam (280 emu/cc) is larger than that for the irradiated sample with Au1 ion beam (240 emu/cc) for the same irradiation ion fluence. These results can also be confirmed by the X-ray magnetic circular dichroism (XMCD) measurement; the XMCD signal for Au3 cluster ion irradiation is larger than that for Au1 ion irradiation. Since the ion beam irradiation induced magnetization of FeRh is significantly correlated with the amount of the lattice defects in the samples, cluster ion beam irradiation can be considered to effectively introduce the lattice defects in B2-type FeRh rather than the single ion beam. Consequently, cluster ion irradiation is better than single ion irradiation for the viewpoint of saturation magnetization, even if the same irradiation energy is deposited in the samples.

  19. Change in magnetic and structural properties of FeRh thin films by gold cluster ion beam irradiation with the energy of 1.67 MeV/atom

    Energy Technology Data Exchange (ETDEWEB)

    Koide, T.; Iwase, A. [Department of Materials Science, Osaka Prefecture University, Sakai, Osaka 599-8531 (Japan); Saitoh, Y. [Japan Atomic Energy Agency, Takasaki, Gunma 370-1292 (Japan); Sakamaki, M.; Amemiya, K. [High Energy Accelerator Research Organization, Tsukuba, Ibaraki 305-0801 (Japan); Matsui, T., E-mail: t-matsui@21c.osakafu-u.ac.jp [Research Organization for the 21st Century, Osaka Prefecture University Sakai, Osaka 599-8531 (Japan)

    2014-05-07

    The effect of energetic cluster ion beam irradiation on magnetic and structural properties of FeRh thin films have been investigated. The cluster ions used in the present studies consist of a few gold atoms with the energy of 1.67 MeV/gold atom. Saturation magnetization of the sample irradiated with Au3 cluster ion beam (280 emu/cc) is larger than that for the irradiated sample with Au1 ion beam (240 emu/cc) for the same irradiation ion fluence. These results can also be confirmed by the X-ray magnetic circular dichroism (XMCD) measurement; the XMCD signal for Au3 cluster ion irradiation is larger than that for Au1 ion irradiation. Since the ion beam irradiation induced magnetization of FeRh is significantly correlated with the amount of the lattice defects in the samples, cluster ion beam irradiation can be considered to effectively introduce the lattice defects in B2-type FeRh rather than the single ion beam. Consequently, cluster ion irradiation is better than single ion irradiation for the viewpoint of saturation magnetization, even if the same irradiation energy is deposited in the samples.

  20. Hydrated electron production by reaction of hydrogen atoms with hydroxide ions: A first-principles molecular dynamics study

    International Nuclear Information System (INIS)

    The solvated electron production by reaction between the H atom and the hydroxide anion was studied using Density Functional Theory based first-principles molecular dynamics. The simulation reveals a complex mechanism, controlled by proton transfers in the coordination sphere of the hydroxide and by the diffusion of the H atom in its solvent cavity. We formulate the hypothesis, based on a coupling between classical and first-principles molecular dynamics, that these two processes give rise to a lag time for the reaction that would explain the H atom extremely small reactivity compared to other radical species. Furthermore, the reaction observed gives an original insight in excess electron solvation. (authors)

  1. An application of the refined born approximation to the solution of coupled equations involved in electron-ion and electron-atom scattering problems

    International Nuclear Information System (INIS)

    A new approach to the solution of coupled equations involved in electron-ion and electron-atom scattering problems is proposed. This method is a combination of iteration and variation procedures. The main advantage of this method is that exchange terms can be calculated in a direct and straightforward manner. The method is based on the Lippmann-Schwinger equation and does not require trial functions satisfying appropriate boundary conditions. Using the Volterra formulation one can find the solution on an interval determined by the range of the exchange potential and the long-range potential terms can be taken into account by a projection procedure giving the asymptotic value of the reactance matrix. The method is tested on the case of electron-hydrogen atom scattering in the 1s-2s and 1s-2s-2p approximation. (orig.)

  2. Simultaneous study of non equilibrated charge and excitation states of MeV/amu light atomic and molecular ions emerging from thin solid targets

    International Nuclear Information System (INIS)

    The evolution of the relative population of a given excited state of atoms H0 or ions (He+) emerging from thin carbon foils bombarded with MeV/a.m.u. atomic H0, He+ and molecular (H2+, H3+) beams has been observed in equilibrium and non-equilibrium situations which are known to occur in charge exchange processes. The comparison between charge state and photon yield (transition n = 4 - 3) variations for He+ gives new informations about capture and excitation processes in the target. Strong enhancement of the relative population of the low excited state n = 2 in the He0 emerging beam is observed in non-equilibrium regime for H0 incident beam as for hydrogen molecular incident beams. In addition, specific molecular effects occur in the equilibrium regime

  3. SHIP, the Separator for Heavy Ion Reaction Products, and the making of the heaviest atomic nuclei. Roentgenium - a new chemical element

    International Nuclear Information System (INIS)

    Ever since the foundation of the GSI, the Darmstadt-based Gesellschaft fuer Schwerionenforschung, in the 1970s, physicists of the Justus-Liebig-University of Giessen have been at the frontiers of research work examining the behaviour of nuclear matter under critical stability conditions. The article in this edition of ''Spiegel der Forschung'', the scientific journal of the university, highlights the results of the last twenty years of research activities with the velocity separator named SHIP, Separator for Heavy Ion Reaction Products. With this instrument, developed by members of the university's II. Institute of Physics and built and operated by members of the GSI in Darmstadt, the scientists were able to generate the six heaviest of the currently known chemical elements, with atomic numbers ranging from 107 to 112. The element with the atomic number 111 will be named ''Roentgenium'', in honour of the famous physicist and Nobel prize winner Wilhelm Conrad Roentgen

  4. Rydberg Matter clusters of alkali metal atoms: the link between meteoritic matter, polar mesosphere summer echoes (PMSE), sporadic sodium layers, polar mesospheric clouds (PMCs, NLCs), and ion chemistry

    CERN Document Server

    Olofson, Frans; Holmlid, Leif

    2010-01-01

    A material exists which links together the influx of meteoritic matter from interplanetary space, the polar mesosphere summer echoes (PMSE), the sporadic sodium layers, the polar mesospheric clouds (PMCs, NLCs), and the observed ion chemistry in the mesosphere. The evidence in these research fields is here analyzed and found to agree well with the properties of Rydberg Matter (RM). This material has been studied with numerous methods in the laboratory. Alkali atoms, mainly Na, reach the mesosphere in the form of interplanetary (meteoritic, cometary) dust. The planar RM clusters NaN usually contain N = 19, 37 or 61 atoms, and have the density of air at 90 km altitude where they float. The diameters of the clusters are 10-100 nm from laboratory high precision radio frequency spectroscopic studies. Such experiments show that RM clusters interact strongly with radar frequencies: this explains the radio frequency heating and reflection studies of PMSE layers. The clusters give the low temperature in the mesosphere...

  5. 稀土原子与离子的自然辐射寿命测量%Natural radiative lifetime measurements of rare-earth atoms and ions

    Institute of Scientific and Technical Information of China (English)

    蒋红玫; 杨博思; 李贺龙; 徐淮良

    2013-01-01

    Advances in the techniques available for natural radiative lifetime measurement of excited states of free atoms and ions are presented.The disadvantages and advantages of several often-used methods for radia-tive lifetime measurements of free atoms and ions of rare-earth elements are reviewed by taking La Ⅰ and PrⅡas examples.Then, the techniques of the laser ablation to produce free atoms and ions are introduced by taking SmⅡas an example, and the time-resolved laser induced fluorescence (LIF) spectroscopy for the radi-ative lifetime measurements is discussed in detail .The limitation of this method of LIF combined with laser ab-lation is summarized and a possibly useful solution is suggested , which may be helpful to further improve the precision of radiative lifetime measurements.%概述了当前自由原子和离子的激发态自然辐射寿命测量技术的进展。以LaⅠ和Pr Ⅱ为例,系统介绍了几种稀土元素自由原子和离子激发态寿命测量技术并分析了它们的优缺点;以Sm Ⅱ为例,详细介绍了激光烧蚀产生自由原子(离子)技术及结合激光诱导荧光时间分辨光谱技术进行激发态寿命测量的优缺点。最后,探讨了改进上述技术局限性的解决思路,以期进一步提高辐射寿命测量的精确度。

  6. Molecular theory of K-vacancy production in heavy-ion-atom collisions at small impact parameters

    International Nuclear Information System (INIS)

    1 s sigma vacancy production is calculated by approximating the 1 s sigma molecular wave function with an atomic 1s wave function for a charge Z(R) centered at a distance h(R) from the heavier nucleus. h(R) and Z(R) are determined by minimizing the 1 s sigma electronic energy. Previous calculations with the atomic semi-classsical approximation (h = 0, Z(R) = Z2, the target atomic number) showed that the probability of making Cu K vacancies in 0.5- to 2-MeV/a.m.u. H+, D+, and He+ + Cu collisions can be written as P(theta) = A(1 + B cos theta), where theta is the scattering angle and A and B are constants for theta approx. > 100. Although the recoil and dipole excitation contributions to P(theta) (which interfere destructively in the atomic theory) are independently smaller in the molecular calculations, similar B values are obtained. (orig.)

  7. An {\\it ab initio} relativistic coupled-cluster theory of dipole and quadrupole polarizabilities: Applications to a few alkali atoms and alkaline earth ions

    CERN Document Server

    Sahoo, B K

    2006-01-01

    We present a general approach within the relativistic coupled-cluster theory framework to calculate exactly the first order wave functions due to any rank perturbation operators. Using this method, we calculate the static dipole and quadrupole polarizabilities in some alkali atoms and alkaline earth-metal ions. This may be a good test of the present theory for different rank and parity interaction operators. This shows a wide range of applications including precise calculations of both parity and CP violating amplitudes due to rank zero and rank one weak interaction Hamiltonians. We also give contributions from correlation effects and discuss them in terms of lower order many-body perturbation theory.

  8. Efficient focusing of 8 keV X-rays with multilayer Fresnel zone plates fabricated by atomic layer deposition and focused ion beam milling

    OpenAIRE

    Mayer, Marcel; Keskinbora, Kahraman; Grévent, Corinne; Szeghalmi, Adriana; Knez, Mato; Weigand, Markus; Snigirev, Anatoly; Snigireva, Irina; Schütz, Gisela

    2013-01-01

    Fresnel zone plates (FZPs) recently showed significant improvement by focusing soft X-rays down to ∼10 nm. In contrast to soft X-rays, generally a very high aspect ratio FZP is needed for efficient focusing of hard X-rays. Therefore, FZPs had limited success in the hard X-ray range owing to difficulties of manufacturing high-aspect-ratio zone plates using conventional techniques. Here, employing a method of fabrication based on atomic layer deposition (ALD) and focused ion beam (FIB) milling,...

  9. Characterization of duplex stainless steels by TEM [transmission electron microscopy], SANS [small-angle neutron scattering], and APFIM [atom-probe field ion microscopy] techniques

    International Nuclear Information System (INIS)

    Results are presented of complementary characterization of aged duplex stainless steels by advanced metallographic techniques, including transmission and high-voltage electron microscopies; small-angle neutron scattering; and atom-probe field ion microscopy. On the basis of the characterization, the mechanisms of aging embrittlement have been shown to be associated with the precipitation of Ni- and Si-rich G phase and Cr-rich α' in the ferrite, and M23C6 carbides on the austenite-ferrite phase boundaries. 19 refs., 19 figs., 1 tab

  10. Anomalous elastic scattering of linearly polarized X-ray radiation by multicharged atomic ions in the range of the ionization threshold of the 1s-shell

    Energy Technology Data Exchange (ETDEWEB)

    Hopersky, A.N. E-mail: phys@rgups.ru; Novikov, S.A.; Chuvenkov, V.V

    2002-04-01

    The absolute values and shape of differential cross-section of the process of the anomalous elastic scattering for non-zero angle are investigated within non-relativistic approximation for linearly polarized X-ray radiation scattered by multicharged atomic ions Ne{sup 6+} in the range of the ionization threshold of 1s-shell. The many-particle effects of radial rearrangement of electron shells in the field of an inner 1s-vacancy and the effect of vacancy stabilization are taken into account. The results of the work are predictions.

  11. Metallic Glass Formation by Ion Mixing and Calculation of Glass-Forming-Ability from Inter-Atomic Potential in the Binary Metal Systems

    Institute of Scientific and Technical Information of China (English)

    LI Zhengcao; LAI Wensheng; LIU Baixin

    2001-01-01

    In this article,a brief summary of the up-to-date progress of metallic glass formation by ion mixing of metallic multilayers in the binary metal systems is first presented.Secondly,thermodynamic modeling of metallic glass formation is developed with special consideration of the interfacial free energy of the multilayers.Thirdly,results of molecular dynamics simulations for some representative systems are presented to show the calculation of the glass-forming ability directly from the inter-atomic potential of the binary metal systems.

  12. Iterative inversion of global magnetospheric ion distributions using energetic neutral atom (ENA images recorded by the NUADU/TC2 instrument

    Directory of Open Access Journals (Sweden)

    L. Lu

    2008-06-01

    Full Text Available A method has been developed for extracting magnetospheric ion distributions from Energetic Neutral Atom (ENA measurements made by the NUADU instrument on the TC-2 spacecraft. Based on a constrained linear inversion, this iterative technique is suitable for use in the case of an ENA image measurement, featuring a sharply peaked spatial distribution. The method allows for magnetospheric ion distributions to be extracted from a low-count ENA image recorded over a short integration time (5 min. The technique is demonstrated through its application to a set of representative ENA images recorded in energy Channel~2 (hydrogen: 50–81 keV, oxygen: 138–185 keV of the NUADU instrument during a geomagnetic storm. It is demonstrated that this inversion method provides a useful tool for extracting ion distribution information from ENA data that are characterized by high temporal and spatial resolution. The recovered ENA images obtained from inverted ion fluxes match most effectively the measurements made at maximum ENA intensity.

  13. Relativistic Configuration Interaction calculations of the atomic properties of selected transition metal positive ions; Ni II, V II and W II

    Science.gov (United States)

    Abdalmoneam, Marwa Hefny

    -quantitative agreement with experiment for the oscillator strength and branching fractions. However the calculated lifetimes and Lande g-values are in very good agreement with the available measured quantities. We found the sums of lifetimes and the sums of Lande g-values of the nearby levels were almost independent of the calculation stage. The calculated atomic properties for Ni II, V II, and W II fill in many gaps in the available atomic data for these three ions. Also, they are expected to facilitate the fundamental understanding of electric and magnetic behaviors of most of the transition metal ions and atoms with similar electronic configurations.

  14. Formation of nitrate and ammonium ions in titanium dioxide mediated photocatalytic degradation of organic compounds containing nitrogen atoms

    Energy Technology Data Exchange (ETDEWEB)

    Low, G.K.-C.; McEvoy, S.R.; Matthews, R.W. (CSIRO Division of Coal and Energy Technology, Menai (Australia))

    1991-03-01

    The photocatalytic oxidation of a related series of primary, secondary, and tertiary amines and other nitrogen- and sulfur-containing organic compounds over a UV-illuminated film of TiO{sub 2} has been studied. The compounds were as follows: n-pentylamine, piperidine, pyridine, phenylalanine, desipramine, thioridazine, penicillamine, isosorbide dinitrate, 4-nitrocatechol, 2,4-dinitrophenol, cyclophosphamide, 5-fluorouracil, atrazine, ethylenediaminetetracetic acid, and tetrabutylammonium phosphate. Both ammonium and nitrate ions were formed. The relative concentration of the two ions depended on the nature of the nitrogen in a compound, but was also influenced by the illumination time and concentration of the solute. It was found that for n-pentylamine, piperidine and pyridine, the rate of formation of ammonium ions was n-pentylamine {much gt} pyridine > piperidine. The order of rates of nitrate formation was pyridine = piperidine {much gt} pentylamine. For n-pentylamine the rate of formation of ammonium ions was {approximately}100 times that of nitrate.

  15. Order within disorder: The atomic structure of ion-beam sputtered amorphous tantala (a-Ta2O5)

    Science.gov (United States)

    Bassiri, Riccardo; Liou, Franklin; Abernathy, Matthew R.; Lin, Angie C.; Kim, Namjun; Mehta, Apurva; Shyam, Badri; Byer, Robert L.; Gustafson, Eric K.; Hart, Martin; MacLaren, Ian; Martin, Iain W.; Route, Roger K.; Rowan, Sheila; Stebbins, Jonathan F.; Fejer, Martin M.

    2015-03-01

    Amorphous tantala (a-Ta2O5) is a technologically important material often used in high-performance coatings. Understanding this material at the atomic level provides a way to further improve performance. This work details extended X-ray absorption fine structure measurements of a-Ta2O5 coatings, where high-quality experimental data and theoretical fits have allowed a detailed interpretation of the nearest-neighbor distributions. It was found that the tantalum atom is surrounded by four shells of atoms in sequence; oxygen, tantalum, oxygen, and tantalum. A discussion is also included on how these models can be interpreted within the context of published crystalline Ta2O5 and other a-T2O5 studies.

  16. Order within disorder: The atomic structure of ion-beam sputtered amorphous tantala (a-Ta2O5

    Directory of Open Access Journals (Sweden)

    Riccardo Bassiri

    2015-03-01

    Full Text Available Amorphous tantala (a-Ta2O5 is a technologically important material often used in high-performance coatings. Understanding this material at the atomic level provides a way to further improve performance. This work details extended X-ray absorption fine structure measurements of a-Ta2O5 coatings, where high-quality experimental data and theoretical fits have allowed a detailed interpretation of the nearest-neighbor distributions. It was found that the tantalum atom is surrounded by four shells of atoms in sequence; oxygen, tantalum, oxygen, and tantalum. A discussion is also included on how these models can be interpreted within the context of published crystalline Ta2O5 and other a-T2O5 studies.

  17. C6 Coefficients and Dipole Polarizabilities for All Atoms and Many Ions in Rows 1-6 of the Periodic Table.

    Science.gov (United States)

    Gould, Tim; Bučko, Tomáš

    2016-08-01

    Using time-dependent density functional theory (TDDFT) with exchange kernels, we calculate and test imaginary frequency-dependent dipole polarizabilities for all atoms and many ions in rows 1-6 of the periodic table. These are then integrated over frequency to produce C6 coefficients. Results are presented under different models: straight TDDFT calculations using two different kernels; "benchmark" TDDFT calculations corrected by more accurate quantum chemical and experimental data; and "benchmark" TDDFT with frozen orbital anions. Parametrizations are presented for 411+ atoms and ions, allowing results to be easily used by other researchers. A curious relationship, C6,XY ∝ [αX(0)αY(0)](0.73), is found between C6 coefficients and static polarizabilities α(0). The relationship C6,XY = 2C6,XC6,Y/[(αX/αY)C6,Y + (αY/αX)C6,X] is tested and found to work well (30% errors) in a small fraction of cases. PMID:27304856

  18. A simplified numerical model for atomic processes of the low and medium Z-ions in the laser-produced plasmas

    International Nuclear Information System (INIS)

    To calculate the ion fractional abundance of every charge state with the short computation time, we tried to build a suitable model for describing atomic processes. In 1982, Busquet proposed a mixed model, where he introduced two superlevels. They are related to a ground state and a ionized state, respectively, and the local-thermodynamic equilibrium (LET) is assumed over the excited states with the ionized state. In order to treat the atomic processes more accurately, we introduce the three superlevels which are the ground state, the first excited state and ionized state. The transition rates between them are evaluated by using Burguess formula which is used in the rate equations. The present model (Extended Mixed Model; EMM) gives results closer to the collisional-radiative model (CRM) than the original mixed model. The emissivity calculated by average-ion model (AIM) is compared with the one by EMM. The x-ray spectra are also obtained by using the EMM together with the hydrodynamic implosion code HIMICO. (author)

  19. Sixteenth International Conference on the physics of electronic and atomic collisions

    International Nuclear Information System (INIS)

    This report contains abstracts of papers on the following topics: photons, electron-atom collisions; electron-molecule collisions; electron-ion collisions; collisions involving exotic species; ion- atom collisions, ion-molecule or atom-molecule collisions; atom-atom collisions; ion-ion collisions; collisions involving rydberg atoms; field assisted collisions; collisions involving clusters and collisions involving condensed matter

  20. Sixteenth International Conference on the physics of electronic and atomic collisions

    Energy Technology Data Exchange (ETDEWEB)

    Dalgarno, A.; Freund, R.S.; Lubell, M.S.; Lucatorto, T.B. (eds.)

    1989-01-01

    This report contains abstracts of papers on the following topics: photons, electron-atom collisions; electron-molecule collisions; electron-ion collisions; collisions involving exotic species; ion- atom collisions, ion-molecule or atom-molecule collisions; atom-atom collisions; ion-ion collisions; collisions involving rydberg atoms; field assisted collisions; collisions involving clusters and collisions involving condensed matter.