WorldWideScience

Sample records for atomic clouds

  1. Coherent Forward Broadening in Cold Atom Clouds

    CERN Document Server

    Sutherland, R T

    2015-01-01

    It is shown that homogeneous line-broadening in a diffuse cold atom cloud is proportional to the resonant optical depth of the cloud. Further, it is demonstrated how the strong directionality of the coherent interactions causes the cloud's spectra to depend strongly on its shape, even when the cloud is held at constant densities. These two numerical observations can be predicted analytically by extending the single photon wave-function model. Lastly, elongating a cloud along the line of laser propagation causes the excitation probability distribution to deviate from the exponential decay predicted by the Beer-Lambert law to the extent where the atoms in the back of the cloud are more excited than the atoms in the front. These calculations are conducted at low densities relevant to recent experiments.

  2. Optimized absorption imaging of mesoscopic atomic clouds

    Science.gov (United States)

    Muessel, Wolfgang; Strobel, Helmut; Joos, Maxime; Nicklas, Eike; Stroescu, Ion; Tomkovič, Jiří; Hume, David B.; Oberthaler, Markus K.

    2013-10-01

    We report on the optimization of high-intensity absorption imaging for small Bose-Einstein condensates. The imaging calibration exploits the linear scaling of the quantum projection noise with the mean number of atoms for a coherent spin state. After optimization for atomic clouds containing up to 300 atoms, we find an atom number resolution of atoms, mainly limited by photon shot noise and radiation pressure.

  3. Mie resonances in inhomogeneous atomic clouds

    CERN Document Server

    Bachelard, Romain; Kaiser, Robin; Piovella, Nicola

    2011-01-01

    Despite the quantum nature of the process, collective scattering by dense cold samples of two-level atoms can be interpreted classically describing the sample as a macroscopic object with a complex refractive index. We demonstrate that Mie resonances can be easily observable in the cooperative scattering by tuning the frequency of the incident laser field or the atomic number. The solution of the scattering problem is obtained for spherical atomic clouds who have the parabolic density characteristic of BECs, and the cooperative radiation pressure force calculated exhibits resonances in the cloud displacement for dense clouds. Reminescent to uniform clouds which show a complex structure of narrow peaks, these densities show resonances, yet under the form of quite regular and contrasted oscillations.

  4. Preparation of Ultracold Atom Clouds at the Shot Noise Level

    DEFF Research Database (Denmark)

    Gajdacz, M.; Hilliard, A. J.; Kristensen, Matias Ammitzbøll

    2016-01-01

    We prepare number stabilized ultracold atom clouds through the real-time analysis of nondestructive images and the application of feedback. In our experiments, the atom number N∼10^6 is determined by high precision Faraday imaging with uncertainty ΔN below the shot noise level, i.e., ΔN... on this measurement, feedback is applied to reduce the atom number to a user-defined target, whereupon a second imaging series probes the number stabilized cloud. By this method, we show that the atom number in ultracold clouds can be prepared below the shot noise level....

  5. Cooperative scattering and radiation pressure force in dense atomic clouds

    CERN Document Server

    Bachelard, Romain; Courteille, Philippe

    2011-01-01

    We consider the collective scattering by a cloud of $N$ two-level atoms driven by an uniform radiation field. Dense atomic clouds can be described by a continuous density and the problem reduces to deriving the spectrum of the atom-atom coupling operator. For clouds much larger than the optical wavelength, the spectrum is treated as a continuum, and analytical expressions for several macroscopic quantities, such as scattered radiation intensity and radiation pressure force, are derived. The analytical results are then compared to the exact $N$-body solution and with those obtained assuming a symmetric timed Dicke state. In contrast with the symmetric timed Dicke state, our calculations takes account of the back action of the atoms on the driving field leading to phase shifts due to the finite refraction of the cloud.

  6. Preparation of Ultracold Atom Clouds at the Shot Noise Level.

    Science.gov (United States)

    Gajdacz, M; Hilliard, A J; Kristensen, M A; Pedersen, P L; Klempt, C; Arlt, J J; Sherson, J F

    2016-08-12

    We prepare number stabilized ultracold atom clouds through the real-time analysis of nondestructive images and the application of feedback. In our experiments, the atom number N∼10^{6} is determined by high precision Faraday imaging with uncertainty ΔN below the shot noise level, i.e., ΔNatom number to a user-defined target, whereupon a second imaging series probes the number stabilized cloud. By this method, we show that the atom number in ultracold clouds can be prepared below the shot noise level.

  7. Preparation of ultracold atom clouds at the shot noise level

    CERN Document Server

    Gajdacz, Miroslav; Kristensen, Mick A; Pedersen, Poul L; Klempt, Carsten; Arlt, Jan J; Sherson, Jacob F

    2016-01-01

    We prepare number stabilized ultracold clouds through the real-time analysis of non-destructive images and the application of feedback. In our experiments, the atom number ${N\\sim10^6}$ is determined by high precision Faraday imaging with uncertainty $\\Delta N$ below the shot noise level, i.e., $\\Delta N <\\sqrt{N}$. Based on this measurement, feedback is applied to reduce the atom number to a user-defined target, whereupon a second imaging series probes the number stabilized cloud. By this method, we show that the atom number in ultracold clouds can be prepared below the shot noise level.

  8. Sub-atom shot noise Faraday imaging of ultracold atom clouds

    CERN Document Server

    Kristensen, Mick A; Pedersen, Poul L; Klempt, Carsten; Sherson, Jacob F; Arlt, Jan J; Hilliard, Andrew J

    2016-01-01

    We demonstrate that a dispersive imaging technique based on the Faraday effect can measure the atom number in a large, ultracold atom cloud with a precision below the atom shot noise level. The minimally destructive character of the technique allows us to take multiple images of the same cloud, which enables sub-atom shot noise measurement precision of the atom number and allows for an in situ determination of the measurement precision. We have developed a noise model that quantitatively describes the noise contributions due to photon shot noise in the detected light and the noise associated with single atom loss. This model contains no free parameters and is calculated through an analysis of the fluctuations in the acquired images. For clouds containing $N \\sim 5 \\times 10^6$ atoms, we achieve a precision more than a factor of two below the atom shot noise level.

  9. Sub-atom shot noise Faraday imaging of ultracold atom clouds

    Science.gov (United States)

    Kristensen, M. A.; Gajdacz, M.; Pedersen, P. L.; Klempt, C.; Sherson, J. F.; Arlt, J. J.; Hilliard, A. J.

    2017-02-01

    We demonstrate that a dispersive imaging technique based on the Faraday effect can measure the atom number in a large, ultracold atom cloud with a precision below the atom shot noise level. The minimally destructive character of the technique allows us to take multiple images of the same cloud, which enables sub-atom shot noise measurement precision of the atom number and allows for an in situ determination of the measurement precision. We have developed a noise model that quantitatively describes the noise contributions due to photon shot noise in the detected light and the noise associated with single atom loss. This model contains no free parameters and is calculated through an analysis of the fluctuations in the acquired images. For clouds containing N∼ 5× {10}6 atoms, we achieve a precision more than a factor of two below the atom shot noise level.

  10. Composite pulses for interferometry in a thermal cold atom cloud

    CERN Document Server

    Dunning, Alexander; Bateman, James; Cooper, Nathan; Himsworth, Matthew; Jones, Jonathan A; Freegarde, Tim

    2014-01-01

    Atom interferometric sensors and quantum information processors must maintain coherence while the evolving quantum wavefunction is split, transformed and recombined, but suffer from experimental inhomogeneities and uncertainties in the speeds and paths of these operations. Several error-correction techniques have been proposed to isolate the variable of interest. Here we apply composite pulse methods to velocity-sensitive Raman state manipulation in a freely-expanding thermal atom cloud. We compare several established pulse sequences, and follow the state evolution within them. The agreement between measurements and simple predictions shows the underlying coherence of the atom ensemble, and the inversion infidelity in an 80 micro-Kelvin atom cloud is halved. Composite pulse techniques, especially if tailored for atom interferometric applications, should allow greater interferometer areas, larger atomic samples and longer interaction times, and hence improve the sensitivity of quantum technologies from inertia...

  11. From the warm magnetized atomic medium to molecular clouds

    CERN Document Server

    Hennebelle, P; Vázquez-Semadeni, E; Klessen, R; Audit, E

    2008-01-01

    {It has recently been proposed that giant molecular complexes form at the sites where streams of diffuse warm atomic gas collide at transonic velocities.} {We study the global statistics of molecular clouds formed by large scale colliding flows of warm neutral atomic interstellar gas under ideal MHD conditions. The flows deliver material as well as kinetic energy and trigger thermal instability leading eventually to gravitational collapse.} {We perform adaptive mesh refinement MHD simulations which, for the first time in this context, treat self-consistently cooling and self-gravity.} {The clouds formed in the simulations develop a highly inhomogeneous density and temperature structure, with cold dense filaments and clumps condensing from converging flows of warm atomic gas. In the clouds, the column density probability density distribution (PDF) peaks at $\\sim 2 \\times 10^{21} \\psc$ and decays rapidly at higher values; the magnetic intensity correlates weakly with density from $n \\sim 0.1$ to $10^4 \\pcc$, an...

  12. Noise spectroscopy with large clouds of cold atoms

    CERN Document Server

    Kashanian, Samir Vartabi; Guerin, William; Lintz, Michel; Fouché, Mathilde; Kaiser, Robin

    2016-01-01

    Noise measurement is a powerful tool to investigate many phenomena from laser characterization to quantum behavior of light. In this paper, we report on intensity noise measurements obtained when a laser beam is transmitted through a large cloud of cold atoms. While this measurement could possibly investigate complex processes such as the influence of atomic motion, one is first limited by the conversion of the intrinsic laser frequency noise to intensity noise via the atomic resonance. We show that a simple model, based on a mean-field approach, which corresponds to describing the atomic cloud by a dielectric susceptibility, is sufficient to understand the main features of this conversion observed in the experimental intensity noise spectrum.

  13. Dynamic splitting and merging of an atom cloud on an atom chip

    Institute of Scientific and Technical Information of China (English)

    Ke Min; Yan Bo; Cheng Feng; Wang Yu-Zhu

    2009-01-01

    Chip-based atom interferometers bring together the advantages of atom chips and Bose-Einstein condensates. Their central prerequisite is that a condensate can be coherently split into two halves with a determined relative phase. This paper demonstrates the dynamical splitting and merging of an atom cloud with two U-wires on an atom chip. Symmetrical and asymmetrical splittings are realized by applying a bias field with different directions and magnitudes. The trajectories of the splitting are consistent with theoretical calculations. The atom chip is a good candidate for constructing an atom interferometer.

  14. Neutral atomic carbon in dense molecular clouds

    Science.gov (United States)

    Zmuidzinas, J.; Betz, A. L.; Boreiko, R. T.; Goldhaber, D. M.

    1988-01-01

    The 370 micron 3P2-3P1 fine-structure line of neutral carbon was detected in seven sources: OMC 1, NGC 2024, S140, W3, DR 21, M17, and W51. Simultaneous analysis of J = 2-1 data and available observations of the J = 1-0 line make it possible to deduce optical depths and excitation temperatures for these lines. These data indicate that both C I lines are likely to be optically thin, and that the ratio of C I to CO column densities in these clouds is typically about 0.1.

  15. Preparation of ultracold atom clouds at the shot noise level

    DEFF Research Database (Denmark)

    Gajdacz, Miroslav; Hilliard, Andrew J.; Kristensen, Mick A.;

    2016-01-01

    We prepare number stabilized ultracold clouds through the real-time analysis of non-destructive images and the application of feedback. In our experiments, the atom number ${N\\sim10^6}$ is determined by high precision Faraday imaging with uncertainty $\\Delta N$ below the shot noise level, i...

  16. Abundance of atomic carbon /C I/ in dense interstellar clouds

    Science.gov (United States)

    Phillips, T. G.; Huggins, P. J.

    1981-01-01

    The abundance of interstellar neutral atomic carbon is investigated by means of its ground state fine-structure line emission at 492 GHz using the 91.5 cm telescope of NASAs Kuiper Airborne Observatory. Atomic carbon is found to be very abundant in dense interstellar molecular clouds with column densities of about 10 to the 19th per sq cm. Because the observations have considerably greater column densities than current theories of carbon chemistry, it is suggested that the physical conditions of these clouds are not as simple as assumed in the models. Various situations are discussed which would lead to large C I abundances, including the possibility that the chemical lifetimes of the clouds are relatively short.

  17. Propagation of light through small clouds of cold interacting atoms

    CERN Document Server

    Jennewein, S; Greffet, J -J; Browaeys, A

    2015-01-01

    We demonstrate experimentally that a cloud of cold atoms with a size comparable to the wavelength of light can induce large group delays on a laser pulse when the laser is tightly focused on it and is close to an atomic resonance. Delays as large as -10 ns are observed, corresponding to "superluminal" propagation with negative group velocities as low as -300 m/s. Strikingly, this large delay is associated with a moderate extinction owing to the very small size of the cloud and to the light-induced interactions between atoms. It implies that a large phase shift is imprinted on the continuous laser beam, and opens interesting perspectives for applications to quantum technologies.

  18. Cooperative scattering and radiation pressure force in dense atomic clouds

    Energy Technology Data Exchange (ETDEWEB)

    Bachelard, R. [University of Nova Gorica, School of Applied Sciences, Vipavska 11c SI-5270 Ajdovscina (Slovenia); Piovella, N. [Dipartimento di Fisica, Universita Degli Studi di Milano, Via Celoria 16, I-20133 Milano (Italy); Courteille, Ph. W. [Instituto de Fisica de Sao Carlos, Universidade de Sao Paulo, 13560-970 Sao Carlos, SP (Brazil)

    2011-07-15

    Atomic clouds prepared in ''timed Dicke'' states, i.e. states where the phase of the oscillating atomic dipole moments linearly varies along one direction of space, are efficient sources of superradiant light emission [Scully et al., Phys. Rev. Lett. 96, 010501 (2006)]. Here, we show that, in contrast to previous assertions, timed Dicke states are not the states automatically generated by incident laser light. In reality, the atoms act back on the driving field because of the finite refraction of the cloud. This leads to nonuniform phase shifts, which, at higher optical densities, dramatically alter the cooperative scattering properties, as we show by explicit calculation of macroscopic observables, such as the radiation pressure force.

  19. Spatial instabilities in a cloud of cold atoms

    CERN Document Server

    Romain, Rudy; Verkerk, Philippe; Hennequin, Daniel

    2016-01-01

    Dense cold atomic clouds have been shown to be similar to plasmas. Previous studies showed that such clouds exhibit instabilities induced by long-range interactions. However they did not describe the spatial properties of the dynamics. In this Letter, we study experimentally the spatial nature of stochastic instabilities and find out that the dynamics is localized. Data are analyzed both in the spectral domain and in the spatial domain (principal component analysis). Both methods fail to describe the dynamics in terms of eigenmodes, showing that space and time are not separable.

  20. Rapid formation of molecular clouds from turbulent atomic gas

    Science.gov (United States)

    Glover, S. C. O.; Mac Low, M.-M.

    The characteristic lifetimes of molecular clouds remain uncertain and a topic of frequent debate, with arguments having recently been advanced both in support of short-lived clouds, with lifetimes of a few Myr or less (see e.g. Elmegreen 2000; Hartmann et al. 2001) and in support of much longer-lived clouds, with lifetimes of the order of 10 Myr or more (see e.g. Tassis & Mouschovias, 2004; Goldsmith & Li, 2005). An argument that has previously been advanced in favour of longer lived clouds is the apparent difficulty involved in converting sufficient atomic hydrogen to molecular hydrogen within the short timescale required by the rapid cloud formation scenario. However, previous estimates of the time required for this conversion to occur have not taken into account the effects of the supersonic turbulence which is inferred to be present in the atomic gas. In this contribution, we present results from a set of high resolution three-dimensional simulations of turbulence in gravitationally unstable atomic gas. These simulations were performed using a modified version of the ZEUS-MP hydrodynamical code (Norman 2000), and include a detailed treatment of the thermal balance of the gas and of the formation of molecular hydrogen. The effects of photodissociation of H2 by the Galactic UV field are also included, with a simple local approximation used to compute the effects of H2 self-shielding. The results of our simulations demonstrate that H2 formation occurs rapidly in turbulent atomic gas. Starting from purely atomic gas, large quantities of molecular gas can be produced on timescales of less than a Myr, given turbulent velocity dispersions and magnetic field strengths consistent with observations. Moreover, as our simulations underestimate the effectiveness of H2 self-shielding and dust absorption, we can be confident that the molecular fractions which we compute are strong lower limits on the true values. The formation of large quantities of molecular gas on the

  1. Propagation of light through small clouds of cold interacting atoms

    Science.gov (United States)

    Jennewein, S.; Sortais, Y. R. P.; Greffet, J.-J.; Browaeys, A.

    2016-11-01

    We demonstrate experimentally that a dense cloud of cold atoms with a size comparable to the wavelength of light can induce large group delays on a laser pulse when the laser is tightly focused on it and is close to an atomic resonance. Delays as large as -10 ns are observed, corresponding to "superluminal" propagation with negative group velocities as low as -300 m /s . Strikingly, this large delay is associated with a moderate extinction owing to the very small size of the dense cloud. It implies that a large phase shift is imprinted on the continuous laser beam. Our system may thus be useful for applications to quantum technologies, such as variable delay line for individual photons or phase imprint between two beams at the single-photon level.

  2. Noise spectroscopy with large clouds of cold atoms

    Science.gov (United States)

    Kashanian, Samir Vartabi; Eloy, Aurélien; Guerin, William; Lintz, Michel; Fouché, Mathilde; Kaiser, Robin

    2016-10-01

    Noise measurement is a powerful tool to investigate many phenomena from laser characterization to quantum behavior of light. In this paper, we report on intensity noise measurements obtained when a laser beam is transmitted through a large cloud of cold atoms. While this measurement could possibly be used to investigate complex processes such as the influence of atomic motion, one is first limited by the conversion of the intrinsic laser frequency noise to intensity noise via the atomic resonance. This conversion is studied here in detail. We show that, while experimental intensity noise spectra collapse onto the same curve at low Fourier frequencies, some differences appear at higher frequencies when the probe beam is detuned from the center of the resonance line. A simple model, based on a mean-field approach, which corresponds to describing the atomic cloud by a dielectric susceptibility, is sufficient to understand the main features. Using this model, the noise spectra allow extracting some quantitative information on the laser noise as well as on the atomic sample.

  3. AtomPy: A Cloud Atomic-data Service for Astrophysical Applications

    Science.gov (United States)

    Mendoza, Claudio; Boswell, J. S.; Bautista, M.

    2013-06-01

    Apart from our long-term commitment to the computing of accurate atomic data for astrophysical applications, we have also been interested in the problems of data access and dissemination. In this respect, one of us took part in the developments of TIPTOPbase [1, 2, 3], the astrophysical opacity server referred to as OPserver [4, 5], and, more recently, of the Virtual Atomic and Molecular Data Center [6, 7]. Our present effort is now with the establishment of a cloud atomic data web service, AtomPy, implemented by means of SOAP web services, Google Drive spreadsheets and Python modules. In the present poster we will describe the outline of this ambitious project, illustrated with some prototypes that are already operational.

  4. The atomic hydrogen cloud in the saturnian system

    Science.gov (United States)

    Tseng, W.-L.; Johnson, R. E.; Ip, W.-H.

    2013-09-01

    The importance of Titan's H torus shaped by solar radiation pressure and of hydrogen atoms flowing out of Saturn's atmosphere in forming the broad hydrogen cloud in Saturn's magnetosphere is still debated. Since the Saturnian system also contains a water product torus which originates from the Enceladus plumes, the icy ring particles, and the inner icy satellites, as well as Titan's H2 torus, we have carried out a global investigation of the atomic hydrogen cloud taking into account all sources. We show that the velocity and angle distributions of the hot H ejected from Saturn's atmosphere following electron-impact dissociation of H2 are modified by collisions with the ambient atmospheric H2 and H. This in turn affects the morphology of the escaping hydrogen from Saturn, as does the morphology of the ionospheric electron distribution. Although an exact agreement with the Cassini observations is not obtained, our simulations show that H directly escaping from Titan is the dominant contributor in the outer magnetosphere. Of the total number of H observed by Cassini from 1 to 5RS, ∼5.7×1034, our simulations suggest ∼20% is from dissociation in the Enceladus torus, ∼5-10% is from dissociation of H2 in the atmosphere of the main rings, and ∼50% is from Titan's H torus, implying that ∼20% comes from Saturn atmosphere.

  5. Dicke subradiance in a large cloud of cold atoms

    CERN Document Server

    Guerin, William; Kaiser, Robin

    2015-01-01

    More than 60 years ago, Dicke published a seminal paper on coherence in spontaneous radiation process by a collection of atoms. Superradiance has since attracted a lot of interest, from its first experimental observation in a fully inverted system in the 1970s to single photon superradiance in the 2000s. Subradiance, on the contrary, has remained elusive, mainly because subradiant states are weakly coupled to the environment and are very sensitive to non radiative decoherence processes. They are thus much harder to populate and to observe. Avoiding decoherence effects by using a dilute cloud of laser-cooled atoms containing a large number of atoms, we report on direct observation of subradiance. In our experiment, we use a far detuned laser to avoid multiple scattering and detect the temporal decay after a sudden switch-off of the laser beam. After the fast decay of most of the fluorescence, we observe a very slow decay, with time constants as long as 100 times the natural lifetime of the excited state of ind...

  6. Fluid description of the cooperative scattering of light by spherical atomic clouds

    CERN Document Server

    Piovella, N; Courteille, Ph W

    2013-01-01

    When a cold atomic gas is illuminated by a quasi-resonant laser beam, light-induced dipole-dipole correlations make the scattering of light a cooperative process. Once a fluid description is adopted for the atoms, many scattering properties are captured by the definition of a complex refractive index. The solution of the scattering problem is here presented for spherical atomic clouds of arbitrary density profiles, such as parabolic densities characteristic of ultra-cold clouds. A new solution for clouds with infinite boundaries is derived, that is particularly useful for the Gaussian densities of thermal atomic clouds. The presence of Mie resonances, a signature of the cloud acting as a cavity for the light, is discussed. These resonances leave their fingerprint in various observables such as the scattered intensity or in the radiation pressure force, and can be observed by tuning the frequency of the incident laser field or the atom number.

  7. Collective resonance fluorescence in small and dense atom clouds: Comparison between theory and experiment

    CERN Document Server

    Jenkins, S D; Javanainen, J; Jennewein, S; Bourgain, R; Pellegrino, J; Sortais, Y R P; Browaeys, A

    2016-01-01

    We study the emergence of a collective optical response of a cold and dense $^{87}$Rb atomic cloud to a near-resonant low-intensity light when the atom number is gradually increased. Experimental observations are compared with microscopic stochastic simulations of recurrent scattering processes between the atoms that incorporate the atomic multilevel structure and the optical measurement setup. We analyze the optical response of an inhomogeneously-broadened gas and find that the experimental observations of the resonance line shifts and the total collected scattered light intensity in cold atom clouds substantially deviate from those of thermal atomic ensembles, indicating strong light-induced resonant dipole-dipole interactions between the atoms. At high densities, the simulations also predict a significantly slower decay of light-induced excitations in cold than in thermal atom clouds. The role of dipole-dipole interactions is discussed in terms of resonant coupling examples and the collective radiative exc...

  8. Optimization of transfer of laser-cooled atom cloud to a quadrupole magnetic

    Indian Academy of Sciences (India)

    S P Ram; S K Tiwari; S R Mishra; H S Rawat

    2014-02-01

    We present here our experimental results on transfer of laser-cooled atom cloud to a quadrupole magnetic trap. We show that by choosing appropriately the ratio of potential energy in magnetic trap to kinetic energy of cloud in molasses, we can obtain the maximum phase-space density in the magnetic trap. These results guide us to choose the value of current to be switched in the quadrupole coils used for magnetic trapping for a given temperature of the cloud after molasses. This study is also useful to set the initial phase-space density of the cloud before evaporative cooling.

  9. An optically resolvable Schr\\"odinger's cat from Rydberg dressed cold atom clouds

    CERN Document Server

    Möbius, S; Eisfeld, A; Wüster, S; Rost, J -M

    2012-01-01

    In Rydberg dressed ultra-cold gases, ground state atoms inherit properties of a weakly admixed Rydberg state, such as sensitivity to long-range interactions. We show that through hyperfine-state dependent interactions, a pair of atom clouds can evolve into a spin and subsequently into a spatial Schr\\"odinger's cat state: The pair, containing 20 atoms in total, is in a coherent superposition of two configurations, with cloud locations separated by micrometers. The mesoscopic nature of the superposition state can be proven with absorption imaging, while the coherence can be revealed though recombination and interference of the split wave packets.

  10. Cooperative fluorescence from a strongly driven dilute cloud of atoms

    DEFF Research Database (Denmark)

    Ott, Johan Raunkjær; Wubs, Martijn; Lodahl, Peter;

    2013-01-01

    We investigate cooperative fluorescence in a dilute cloud of strongly driven two-level emitters. Starting from the Heisenberg equations of motion, we compute the first-order scattering corrections to the saturation of the excited-state population and to the resonance-fluorescence spectrum, which...... both require going beyond the state-of-the-art linear-optics approach to describe collective phenomena. A dipole blockade is observed due to long-range dipole-dipole coupling that vanishes at stronger driving fields. Furthermore, we compute the inelastic component of the light scattered by a cloud...

  11. Scale Factor Measurements for a Gyroscope Based on an Expanding Cloud of Atoms

    Science.gov (United States)

    Hoth, Gregory; Pelle, Bruno; Riedl, Stefan; Kitching, John; Donley, Elizabeth

    2016-05-01

    We present an atom interferometer that can simultaneously measure two-axis rotations and one-axis accelerations with a single cloud of atoms in an active evacuated volume of about 1 cm3. This is accomplished by extending the point-source interferometry technique (Dickerson et al. PRL, 111, 083001, 2013) to a compact regime. In this technique, the cloud of atoms is imaged after the interferometer sequence. Rotations cause spatial fringes to appear across the cloud. To realize a gyroscope with this method, it is necessary to know how the wave-vector of the spatial fringes, k, is related to the rotation rate, Ω. If the cloud is initially infinitesimally small, it can be shown that k = FΩ with a scale factor F determined by the time between interferometer pulses, the total free expansion time, and the wavelength of the interrogating laser. However, the point-source approximation is not appropriate in our case because the final size of the cloud in our experiment is between 1.4 and 5 times its initial size. We show experimentally that in this finite expansion regime the phase gradient is still well described by k = FΩ , but the scale factor F depends on the initial distribution of the atoms. We also present modeling that explains this dependence.

  12. The Transition from Atomic to Molecular Hydrogen in Interstellar Clouds: 21cm Signature of the Evolution of Cold Atomic Hydrogen in Dense Clouds

    CERN Document Server

    Goldsmith, P F; Krco, M; Goldsmith, Paul F.; Li, Di; Krco, Marko

    2006-01-01

    We have investigated the time scale for formation of molecular clouds by examining the conversion of HI to H2 using a time-dependent model. H2 formation on dust grains and cosmic ray and photo destruction are included in one-dimensional model slab clouds which incorporate time-independent density and temperature distributions. We calculate 21cm spectral line profiles seen in absorption against a background provided by general Galactic HI emission, and compare the model spectra with HI Narrow Self-Absorption, or HINSA, profiles absorbed in a number of nearby molecular clouds. The time evolution of the HI and H2 densities is dramatic, with the atomic hydrogen disappearing in a wave propagating from the central, denser regions which have a shorter H2 formation time scale, to the edges, where the density is lower and the time scale for H2 formation longer. The model 21cm spectra are characterized by very strong absorption at early times, when the HI column density through the model clouds is extremely large. The ...

  13. Spin Diffusion in Trapped Clouds of Cold Atoms with Resonant Interactions

    DEFF Research Database (Denmark)

    Bruun, Georg Morten; Pethick, C. J.

    2011-01-01

    We show that puzzling recent experimental results on spin diffusion in a strongly interacting atomic gas may be understood in terms of the predicted spin diffusion coefficient for a generic strongly interacting system. Three important features play a central role: (a) Fick’s law for diffusion mus...... be modified to allow for the trapping potential; (b) the diffusion coefficient is inhomogeneous, due to the density variations in the cloud; and (c) the diffusion approximation fails in the outer parts of the cloud, where the mean free path is long....

  14. Kibble-Zurek mechanism in the self-organization of a cold atomic cloud

    CERN Document Server

    Labeyrie, Guillaume

    2016-01-01

    When applying two counter-propagating laser beams to a cold cloud of Rubidium atoms, we observe the spontaneous formation of intensity patterns associated with a spatial structuration of the atomic spins. We study the average number of defects in these patterns as a function of the sweep time employed to cross the transition threshold. We observe a power-law decrease of the number of defects with increasing sweep time, typical of the Kibble-Zurek mechanism. The measured exponent is consistent with the prediction for a supercritical bifurcation.

  15. Reduction of interference fringes in absorption imaging of cold atom cloud using eigenface method

    Institute of Scientific and Technical Information of China (English)

    Xiaolin Li; Min Ke; Bo Yan; Yuzhu Wang

    2007-01-01

    Eigenface method used in face recognition is introduced to reduce the pattern of interference fringes appearing in the absorption image of cold rubidium atom cloud trapped by an atom chip. The standard method for processing the absorption image is proposed, and the origin of the interference fringes is analyzed. Compared with the standard processing method which uses only one reference image, we take advantage of fifty reference images and reconstruct a new reference image which is more similar to the absorption image than all of the fifty original reference images. Then obvious reduction of interference fringes can be obtained.

  16. Atomic Hydrogen Gas in Dark-Matter Minihalos and the Compact High Velocity Clouds

    CERN Document Server

    Sternberg, A; Wolfire, M G

    2002-01-01

    We calculate the coupled hydrostatic and ionization structures of pressure-supported gas clouds that are confined by gravitationally dominant dark-matter (DM) mini-halos and by an external bounding pressure provided by a hot medium. We focus on clouds that are photoionized and heated by the present-day background metagalactic field and determine the conditions for the formation of warm (WNM), and multi-phased (CNM/WNM) neutral atomic hydrogen (HI) cores in the DM-dominated clouds. We consider LCDM dark-matter halos, and we compute models for a wide range of halo masses, total cloud gas masses, and external bounding pressures. We present models for the pressure-supported HI structures observed in the Local Group dwarf galaxies Leo A and Sag DIG. We then construct minihalo models for the multi-phased (and low-metallicity) compact high-velocity HI clouds (CHVCs). If the CHVCs are drawn from the same family of halos that successfully reproduce the dwarf galaxy observations, then the CHVCs must be "circumgalactic ...

  17. Modeling the Atomic-to-Molecular Transition and Chemical Distributions of Turbulent Star-Forming Clouds

    CERN Document Server

    Offner, Stella S R; Viti, Serena; Bell, Thomas A

    2013-01-01

    We use 3D-PDR, a three-dimensional astrochemistry code for modeling photodissociation regions (PDRs), to post-process hydrodynamic simulations of turbulent, star-forming clouds. We focus on the transition from atomic to molecular gas, with specific attention to the formation and distribution of H, C+, C, H2 and CO. First, we demonstrate that the details of the cloud chemistry and our conclusions are insensitive to the simulation spatial resolution, to the resolution at the cloud edge, and to the ray angular resolution. We then investigate the effect of geometry and simulation parameters on chemical abundances and find weak dependence on cloud morphology as dictated by gravity and turbulent Mach number. For a uniform external radiation field, we find similar distributions to those derived using a one-dimensional PDR code. However, we demonstrate that a three-dimensional treatment is necessary for a spatially varying external field, and we caution against using one-dimensional treatments for non-symmetric probl...

  18. MODELING THE ATOMIC-TO-MOLECULAR TRANSITION AND CHEMICAL DISTRIBUTIONS OF TURBULENT STAR-FORMING CLOUDS

    Energy Technology Data Exchange (ETDEWEB)

    Offner, Stella S. R. [Department of Astronomy, Yale University, New Haven, CT 06511 (United States); Bisbas, Thomas G.; Viti, Serena [Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6B (United Kingdom); Bell, Tom A., E-mail: stella.offner@yale.edu [Centro de Astrobiologia (CSIC-INTA), Carretera de Ajalvir, km 4, E-28850 Madrid (Spain)

    2013-06-10

    We use 3D-PDR, a three-dimensional astrochemistry code for modeling photodissociation regions (PDRs), to post-process hydrodynamic simulations of turbulent, star-forming clouds. We focus on the transition from atomic to molecular gas, with specific attention to the formation and distribution of H, C{sup +}, C, H{sub 2}, and CO. First, we demonstrate that the details of the cloud chemistry and our conclusions are insensitive to the simulation spatial resolution, to the resolution at the cloud edge, and to the ray angular resolution. We then investigate the effect of geometry and simulation parameters on chemical abundances and find weak dependence on cloud morphology as dictated by gravity and turbulent Mach number. For a uniform external radiation field, we find similar distributions to those derived using a one-dimensional PDR code. However, we demonstrate that a three-dimensional treatment is necessary for a spatially varying external field, and we caution against using one-dimensional treatments for non-symmetric problems. We compare our results with the work of Glover et al., who self-consistently followed the time evolution of molecule formation in hydrodynamic simulations using a reduced chemical network. In general, we find good agreement with this in situ approach for C and CO abundances. However, the temperature and H{sub 2} abundances are discrepant in the boundary regions (A{sub v} {<=} 5), which is due to the different number of rays used by the two approaches.

  19. The H I Probability Distribution Function and the Atomic-to-molecular Transition in Molecular Clouds

    Science.gov (United States)

    Imara, Nia; Burkhart, Blakesley

    2016-10-01

    We characterize the column-density probability distribution functions (PDFs) of the atomic hydrogen gas, H i, associated with seven Galactic molecular clouds (MCs). We use 21 cm observations from the Leiden/Argentine/Bonn Galactic H i Survey to derive column-density maps and PDFs. We find that the peaks of the H i PDFs occur at column densities in the range ˜1-2 × 1021 {{cm}}-2 (equivalently, ˜0.5-1 mag). The PDFs are uniformly narrow, with a mean dispersion of {σ }{{H}{{I}}}≈ {10}20 {{cm}}-2 (˜0.1 mag). We also investigate the H i-to-H2 transition toward the cloud complexes and estimate H i surface densities ranging from 7 to 16 {M}⊙ {{pc}}-2 at the transition. We propose that the H i PDF is a fitting tool for identifying the H i-to-H2 transition column in Galactic MCs.

  20. The HI Probability Distribution Function and the Atomic-to-Molecular Transition in Molecular Clouds

    CERN Document Server

    Imara, Nia

    2016-01-01

    We characterize the column density probability distributions functions (PDFs) of the atomic hydrogen gas, HI, associated with seven Galactic molecular clouds (MCs). We use 21 cm observations from the Leiden/Argentine/Bonn Galactic HI Survey to derive column density maps and PDFs. We find that the peaks of the HI PDFs occur at column densities ranging from ~1-2$\\times 10^{21}$ cm$^2$ (equivalently, ~0.5-1 mag). The PDFs are uniformly narrow, with a mean dispersion of $\\sigma_{HI}\\approx 10^{20}$ cm$^2$ (~0.1 mag). We also investigate the HI-to-H$_2$ transition towards the cloud complexes and estimate HI surface densities ranging from 7-16 $M_\\odot$ pc$^{-2}$ at the transition. We propose that the HI PDF is a fitting tool for identifying the HI-to-H$_2$ transition column in Galactic MCs.

  1. Contrast enhancement via shaped Raman pulses for thermal cold atom cloud interferometry

    Science.gov (United States)

    Luo, Yukun; Yan, Shuhua; Hu, Qingqing; Jia, Aiai; Wei, Chunhua; Yang, Jun

    2016-12-01

    Interferometry with thermal cold atom clouds provides high particle flux and low quantum projection noise but is limited by the rapid reduction of fringe contrast. We propose an improved method based on temporally shaped pulses to address the issue of the off-resonance dispersion and enhance the contrast. Theoretical analysis and construction principle for shaped pulses are demonstrated. The fidelity of single π and π/2 pulses as well as a complete interferometer sequence are investigated. Comparisons are ade between the traditional pulse and several alternative shaped pulses to verify the feasibility and find an efficient choice among them. Practical implementation scheme and possible error sources are also discussed. The results show a great improvement in contrast and robust phase response for high atomic temperature up to several tens of μK.

  2. Mapping atomic and diffuse interstellar band absorption across the Magellanic Clouds and the Milky Way

    CERN Document Server

    Bailey, Mandy; Sarre, Peter J; Beckman, John E

    2015-01-01

    Diffuse interstellar bands (DIBs) trace warm neutral and weakly-ionized diffuse interstellar medium (ISM). Here we present a dedicated, high signal-to-noise spectroscopic study of two of the strongest DIBs, at 5780 and 5797 \\AA, in optical spectra of 666 early-type stars in the Small and Large Magellanic Clouds, along with measurements of the atomic Na\\,{\\sc i}\\,D and Ca\\,{\\sc ii}\\,K lines. The resulting maps show for the first time the distribution of DIB carriers across large swathes of galaxies, as well as the foreground Milky Way ISM. We confirm the association of the 5797 \\AA\\ DIB with neutral gas, and the 5780 \\AA\\ DIB with more translucent gas, generally tracing the star-forming regions within the Magellanic Clouds. Likewise, the Na\\,{\\sc i}\\,D line traces the denser ISM whereas the Ca\\,{\\sc ii}\\,K line traces the more diffuse, warmer gas. The Ca\\,{\\sc ii}\\,K line has an additional component at $\\sim200$--220 km s$^{-1}$ seen towards both Magellanic Clouds; this may be associated with a pan-Magellanic ...

  3. Molecular and Atomic Gas in the Large Magellanic Cloud - I. Conditions for CO Detection

    CERN Document Server

    Wong, T; Fukui, Y; Kawamura, A; Mizuno, N; Ott, J; Müller, E; Pineda, J L; Welty, D E; Kim, S; Mizuno, Y; Murai, M; Onishi, T

    2009-01-01

    We analyze the conditions for detection of CO(1-0) emission in the Large Magellanic Cloud (LMC), using the recently completed second NANTEN CO survey. In particular, we investigate correlations between CO integrated intensity and HI integrated intensity, peak brightness temperature, and line width at a resolution of 2.6' (~40 pc). We find that significant HI column density and peak brightness temperature are necessary but not sufficient conditions for CO detection, with many regions of strong HI emission not associated with molecular clouds. The large scatter in CO intensities for a given HI intensity persists even when averaging on scales of >200 pc, indicating that the scatter is not solely due to local conversion of HI into H_2 near GMCs. We focus on two possibilities to account for this scatter: either there exist spatial variations in the I(CO) to N(H_2) conversion factor, or a significant fraction of the atomic gas is not involved in molecular cloud formation. A weak tendency for CO emission to be suppr...

  4. Demonstration of fold and cusp catastrophes in an atomic cloud reflected from an optical barrier in the presence of gravity

    CERN Document Server

    Rosenblum, Serge; Shomroni, Itay; Kaner, Roy; Arusi-Parpar, Talya; Raz, Oren; Dayan, Barak

    2013-01-01

    We experimentally demonstrate first-order (fold) and second-order (cusp) catastrophes in the density of an atomic cloud reflected from an optical barrier in the presence of gravity, and show their corresponding universal asymptotic behavior. The cusp point enables robust, field-free refocusing of an expanding atomic cloud with a wide velocity distribution. Specifically, the density attained at the cusp point in our experiment reached 65% of the peak density of the atoms in the trap prior to their release. We thereby add caustics to the various phenomena with parallels in optics that can be harnessed for manipulation of cold atoms. The structural stability of catastrophes provides inherent robustness against variations in the system's dynamics and initial conditions, making them suitable for manipulation of atoms under imperfect conditions and limited controllability.

  5. Cloud point extraction for the determination of copper in environmental samples by flame atomic absorption spectrometry

    Directory of Open Access Journals (Sweden)

    Ardeshir Shokrollahi

    2008-01-01

    Full Text Available A simple cloud point extraction procedure is presented for the preconcentration of copper in various samples. After complexation by 4-hydroxy-2-mercapto-6-propylpyrimidine (PTU, copper ions are quantitatively extracted into the phase rich in Triton X-114 after centrifugation. Methanol acidified with 0.5 mol L-1 HNO3 was added to the surfactant-rich phase prior to its analysis by flame atomic absorption spectrometry (FAAS. Analytical parameters including concentrations for PTU, Triton X-114 and HNO3, bath temperature, centrifugation rate and time were optimized. The influences of the matrix ions on the recoveries of copper ions were investigated. The detection limits (3SDb/m, n=4 of 1.6 ng mL-1 along with enrichment factors of 30 for Cu were achieved. The proposed procedure was applied to the analysis of environmental samples.

  6. The formation of the W43 complex: constraining its atomic-to-molecular transition and searching for colliding clouds

    CERN Document Server

    Motte, F; Schneider, N; Heitsch, F; Glover, S; Carlhoff, P; Hill, T; Bontemps, S; Schilke, P; Louvet, F; Hennemann, M; Didelon, P; Beuther, H

    2014-01-01

    Numerical simulations have explored the possibility to form molecular clouds through either a quasi-static, self-gravitating mechanism or the collision of gas streams or lower-density clouds. They also quantitatively predict the distribution of matter at the transition from atomic to molecular gases. We aim to observationally test these models by studying the environment of W43, a molecular cloud complex near the tip of the Galactic long bar. Using Galaxy-wide HI and 12CO surveys we searched for gas flowing toward the W43 molecular cloud complex. We also estimated the HI and H2 mass surface densities to constrain the transition from atomic to molecular gas around and within W43. We found 3 cloud ensembles within the position-velocity diagrams of 12CO and HI gases. They are separated by 20km/s along the line of sight and extend into the 13CO velocity structure of W43. Since their velocity gradients are consistent with free-fall, they could be nearby clouds attracted by, and streaming toward, the W43 10^7Msun p...

  7. Hydrogen in diffuse molecular clouds in the Milky Way. Atomic column densities and molecular fraction along prominent lines of sight

    Science.gov (United States)

    Winkel, B.; Wiesemeyer, H.; Menten, K. M.; Sato, M.; Brunthaler, A.; Wyrowski, F.; Neufeld, D.; Gerin, M.; Indriolo, N.

    2017-03-01

    Context. Recent submillimeter and far-infrared wavelength observations of absorption in the rotational ground-state lines of various simple molecules against distant Galactic continuum sources have opened the possibility of studying the chemistry of diffuse molecular clouds throughout the Milky Way. In order to calculate abundances, the column densities of molecular and atomic hydrogen, H i, must be known. Aims: We aim at determining the atomic hydrogen column densities for diffuse clouds located on the sight lines toward a sample of prominent high-mass star-forming regions that were intensely studied with the HIFI instrument onboard Herschel. Methods: Based on Jansky Very Large Array data, we employ the 21 cm H i absorption-line technique to construct profiles of the H i opacity versus radial velocity toward our target sources. These profiles are combined with lower resolution archival data of extended H i emission to calculate the H i column densities of the individual clouds along the sight lines. We employ Bayesian inference to estimate the uncertainties of the derived quantities. Results: Our study delivers reliable estimates of the atomic hydrogen column density for a large number of diffuse molecular clouds at various Galactocentric distances. Together with column densities of molecular hydrogen derived from its surrogates observed with HIFI, the measurements can be used to characterize the clouds and investigate the dependence of their chemistry on the molecular fraction, for example. The data sets are available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/600/A2

  8. Modelling the impact of noctilucent cloud formation on atomic oxygen and other minor constituents of the summer mesosphere

    Directory of Open Access Journals (Sweden)

    B. J. Murray

    2005-01-01

    Full Text Available The formation, evolution and eventual sublimation of noctilucent clouds (NLC may have a significant effect on the odd oxygen and hydrogen chemistry of the high latitude summer mesosphere. Three mechanisms are considered here: the direct uptake of atomic oxygen on the surface of the ice particles; the redistribution of water vapour, which changes the photochemical source of odd hydrogen species; and the direct photolysis of the ice particles themselves to produce odd hydrogen species in the gas phase. A 1-D photochemical model is employed to investigate the potential importance of these mechanisms. This shows, using the recently measured uptake coefficients of O on ice, that the heterogeneous removal of O on the surface of the cloud particles is too slow by at least a factor of 5x103 to compete with gas-phase O chemistry. The second and third mechanisms involve the solar Lyman-α photolysis of H2O in the gas and solid phase, respectively. During twilight, Lyman-α radiation is severely attenuated and these mechanisms are insignificant. In contrast, when the upper mesosphere is fully illuminated there is a dramatic impact on the O profile, with depletion of O at the base of the cloud layer of close to an order of magnitude. A correspondingly large depletion in O3 is also predicted, while H, OH, HO2 and H2O2 are found to be enhanced by factors of 3-5. In fact, rocket-borne mass spectrometer measurements during summer have revealed local H2O2 enhancements in the region of the clouds. Rocket-borne measurements of atomic O and O3 profiles in the presence of mesospheric clouds in the daytime are highly desirable to test the predictions of this model and our understanding of the genesis of mesospheric clouds.

  9. Electromagnetically induced transparency of a single-photon in dipole-coupled one-dimensional atomic clouds

    CERN Document Server

    Viscor, Daniel; Lesanovsky, Igor

    2014-01-01

    We investigate the propagation of a single photon under conditions of electromagnetically induced transparency in two parallel one-dimensional atomic clouds which are coupled via Rydberg dipole-dipole interaction. Initially the system is prepared with a single delocalized Rydberg excitation shared between the two ensembles and the photon enters both of them in an arbitrary path-superposition state. By properly aligning the transition dipoles of the atoms of each cloud we show that the photon can be partially transferred from one cloud to the other via the dipole-dipole interaction. This coupling leads to the formation of dark and bright superpositions of the light which experience different absorption and dispersion. We show that this feature can be exploited to filter the incident photon in such a way that only a desired path-superposition state is transmitted transparently. Finally, we generalize the analysis to the case of N coupled one-dimensional clouds. We show that within some approximations the dynami...

  10. Efimov studies of an ultracold cloud of 39 K atoms in microgravity: Numerical modelling and experimental design

    Science.gov (United States)

    Mossman, Maren; Engels, Peter; D'Incao, Jose; Jin, Deborah; Cornell, Eric

    2016-05-01

    Ultracold atomic gases at or near quantum degeneracy provide a powerful tool for the investigation of few-body physics. A particularly intriguing few-body phenomenon is the existence of Efimov trimer states at large interatomic scattering lengths. These trimers are predicted to exhibit universal geometric scaling relations, but in practice the situation is complicated e.g. by finite-range and finite-temperature effects. While some Efimov trimers have already been experimentally observed by several groups in ground-based experiments, NASA's Cold Atom Laboratory (CAL) onboard the ISS will greatly enhance the experimentally accessible regimes by providing ultracold clouds of 39 K atoms with temperatures at or below 1 nK, low densities, and long observation times. We present results of numerical modelling and simulations that lay out Efimov experiments capitalizing on the particular strengths of CAL.

  11. Determination of cadmium in rice and water by tungsten coil electrothermal vaporization-atomic fluorescence spectrometry and tungsten coil electrothermal atomic absorption spectrometry after cloud point extraction

    Energy Technology Data Exchange (ETDEWEB)

    Wen Xiaodong [College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu, Sichuan 610064 (China); Wu Peng [Analytical and Testing Center, Sichuan University, 29 Wangjiang Road, Chengdu, Sichuan 610064 (China); Chen Li [College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu, Sichuan 610064 (China); Hou Xiandeng, E-mail: houxd@scu.edu.cn [College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu, Sichuan 610064 (China); Analytical and Testing Center, Sichuan University, 29 Wangjiang Road, Chengdu, Sichuan 610064 (China)

    2009-09-14

    In this work, the microsampling nature of tungsten coil electrothermal vaporization Ar/H{sub 2} flame atomic fluorescence spectrometry (W-coil ETV-AFS) as well as tungsten coil electrothermal atomic absorption spectrometry (W-coil ET-AAS) was used with cloud point extraction (CPE) for the ultrasensitive determination of cadmium in rice and water samples. When the temperature of the extraction system is higher than the cloud point temperature of the selected surfactant Triton X-114, the complex of cadmium with dithizone can be quantitatively extracted into the surfactant-rich phase and subsequently separated from the bulk aqueous phase by centrifugation. The main factors affecting the CPE, such as concentration of Triton X-114 and dithizone, pH, equilibration temperature and incubation time, were optimized for the best extract efficiency. Under the optimal conditions, the limits of detection for cadmium by W-coil ETV-AFS and W-coil ET-AAS were 0.01 and 0.03 {mu}g L{sup -1}, with sensitivity enhancement factors of 152 and 93, respectively. The proposed methods were applied to the determination of cadmium in certified reference rice and water samples with analytical results in good agreement with certified values.

  12. Cloud point extraction thermospray flame quartz furnace atomic absorption spectrometry for determination of ultratrace cadmium in water and urine

    Science.gov (United States)

    Wu, Peng; Zhang, Yunchang; Lv, Yi; Hou, Xiandeng

    2006-12-01

    A simple, low cost and highly sensitive method based on cloud point extraction (CPE) for separation/preconcentration and thermospray flame quartz furnace atomic absorption spectrometry was proposed for the determination of ultratrace cadmium in water and urine samples. The analytical procedure involved the formation of analyte-entrapped surfactant micelles by mixing the analyte solution with an ammonium pyrrolidinedithiocarbamate (APDC) solution and a Triton X-114 solution. When the temperature of the system was higher than the cloud point of Triton X-114, the complex of cadmium-PDC entered the surfactant-rich phase and thus separation of the analyte from the matrix was achieved. Under optimal chemical and instrumental conditions, the limit of detection was 0.04 μg/L for cadmium with a sample volume of 10 mL. The analytical results of cadmium in water and urine samples agreed well with those by ICP-MS.

  13. Cloud point extraction-thermospray flame quartz furnace atomic absorption spectrometry for determination of ultratrace cadmium in water and urine

    Energy Technology Data Exchange (ETDEWEB)

    Wu Peng [Analytical and Testing Center, Sichuan University, Chengdu, Sichuan 610064 (China); Zhang Yunchang [College of Chemistry, Sichuan University, Chengdu, Sichuan 610064 (China); Lv Yi [College of Chemistry, Sichuan University, Chengdu, Sichuan 610064 (China); Hou Xiandeng [Analytical and Testing Center, Sichuan University, Chengdu, Sichuan 610064 (China) and College of Chemistry, Sichuan University, Chengdu, Sichuan 610064 (China)]. E-mail: houxd@scu.edu.cn

    2006-12-15

    A simple, low cost and highly sensitive method based on cloud point extraction (CPE) for separation/preconcentration and thermospray flame quartz furnace atomic absorption spectrometry was proposed for the determination of ultratrace cadmium in water and urine samples. The analytical procedure involved the formation of analyte-entrapped surfactant micelles by mixing the analyte solution with an ammonium pyrrolidinedithiocarbamate (APDC) solution and a Triton X-114 solution. When the temperature of the system was higher than the cloud point of Triton X-114, the complex of cadmium-PDC entered the surfactant-rich phase and thus separation of the analyte from the matrix was achieved. Under optimal chemical and instrumental conditions, the limit of detection was 0.04 {mu}g/L for cadmium with a sample volume of 10 mL. The analytical results of cadmium in water and urine samples agreed well with those by ICP-MS.

  14. Development of a cloud point extraction and preconcentration method for Cd and Ni prior to flame atomic absorption spectrometric determination

    Energy Technology Data Exchange (ETDEWEB)

    Manzoori, Jamshid L. [Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz (Iran, Islamic Republic of)]. E-mail: manzoori@tabrizu.ac.ir; Karim-Nezhad, Ghasem [Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz (Iran, Islamic Republic of)

    2004-09-13

    In this work a new cloud point extraction (CPE) methodology was developed for the separation and preconcentration of cadmium and nickel. The analyte in the initial aqueous solution was complexed with dithizone and Triton X-114 was added as surfactant. After phase separation, based on the cloud point of the mixture, and dilution of the surfactant-rich phase with tetrahydrofuran (THF), the enriched analytes were determined by flame atomic absorption spectrometry. After optimization of the complexation and extraction conditions and preconcentration of only 10 ml of sample in the presence of 0.05% Triton X-114, the enhancement factors of 52 and 39 and the detection limits of 0.31 {mu}g l{sup -1} and 1.2 {mu}g l{sup -1} were obtained for cadmium and nickel respectively. The proposed method was applied satisfactorily to the determination of cadmium and nickel in water samples.

  15. Modelling the impact of noctilucent cloud formation on atomic oxygen and other minor constituents of the summer mesosphere

    Directory of Open Access Journals (Sweden)

    B. J. Murray

    2004-11-01

    Full Text Available The formation, evolution and eventual sublimation of noctilucent clouds (NLC could have a significant effect on the odd oxygen and hydrogen chemistry of the high latitude summer mesosphere. Three mechanisms are considered here: the direct uptake of atomic oxygen on the surface of the ice particles; the redistribution of water vapour, which changes the photochemical source of odd hydrogen species; and the direct photolysis of the ice particles themselves to produce odd hydrogen species in the gas phase. A 1-D photochemical model is employed to investigate the potential importance of these mechanisms. This shows, using the recently measured uptake coefficients of O on ice, that the heterogeneous removal of O on the surface of the cloud particles is too slow by at least a factor of 5×103 to compete with gas-phase O chemistry. The second and third mechanisms involve the solar Lyman-α photolysis of H2O in the gas and solid phase, respectively. During twilight, Lyman-α radiation is severely attenuated and these mechanisms are insignificant. In contrast, when the upper mesosphere is fully illuminated there is a dramatic impact on the O profile, with depletion of O at the base of the cloud layer of close to an order of magnitude. A correspondingly large depletion in O3 is also predicted, while H, OH, HO2 and H2O2 are found to be enhanced by factors of 3–5. In fact, rocket-borne mass spectrometer measurements during summer have revealed local H2O2 enhancements in the region of the clouds. Rocket-borne measurements of atomic O and O3 profiles in the presence of mesospheric clouds in the daytime are highly desirable to test the predictions of this model and our understanding of the genesis of mesospheric clouds.

  16. Determination of trace nickel in water samples by cloud point extraction preconcentration coupled with graphite furnace atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Sun Zhimei [Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079 (China); Department of Chemistry and Biology, Huainan Normal University, Huainan 232001 (China); Liang Pei [Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079 (China)]. E-mail: liangpei@mail.ccnu.edu.cn; Ding Qiong [Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079 (China); Cao Jing [Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079 (China)

    2006-09-21

    A new method based on the cloud point extraction (CPE) preconcentration and graphite furnace atomic absorption spectrometry (GFAAS) detection was proposed for the determination of trace nickel in water samples. When the micelle solution temperature is higher than the cloud point of surfactant p-octylpolyethyleneglycolphenyether (Triton X-100), the complex of Ni{sup 2+} with 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone (PMBP) could enter surfactant-rich phase and be concentrated, then determined by GFAAS. The main factors affecting the cloud point extraction were investigated in detail. An enrichment factor of 27 was obtained for the preconcentration of Ni{sup 2+} with 10 mL solution. Under the optimal conditions, the detection limit of Ni{sup 2+} is 0.12 ng mL{sup -1} with R.S.D. of 4.3% (n = 10, c = 100 ng mL{sup -1}). The proposed method was applied to determination of trace nickel in water samples with satisfactory results.

  17. Determination of Trace Amounts of Nickel (Ⅱ) by Graphite Furnace Atomic Absorption Spectrometry Coupled with Cloud Point Extraction

    Institute of Scientific and Technical Information of China (English)

    SHAH Syed Mazhar; WANG Hao-nan; SU Xing-guang

    2011-01-01

    A new method based on the cloud point extraction(CPE) for separation and preconcentration of nickel(Ⅱ)and its subsequent determination by graphite furnace atomic absorption spectrometry(GFAAS) was proposed,8-hydroxyquinoline and Triton X-100 were usedl as the ligand and surfactant respectively. Nickel(Ⅱ) can form a hydrophobic complex with 8-hydroxyquinoline, the complex can be extracted into the small volume surfactant rich phase at the cloud point temperature(CPT) for GFAAS determination. The factors affecting the cloud point extraction,such as pH, ligand concentration, surfactant concentration, and the incubation time were optimized. Under the optimal conditions, a detection limit of 12 ng/L and a relative standard deviation(RSD) of 2.9% were obtained for Ni(Ⅱ) determination. The enrichment factor was found to be 25. The proposed method was successfully applied to the determination of nickel(Ⅱ) in certified reference material and different types of water samples and the recovery was in a range of 95% 103%.

  18. Cloud condensation nucleus (CCN) behavior of organic aerosol particles generated by atomization of water and methanol solutions

    Science.gov (United States)

    Rissman, T. A.; Varutbangkul, V.; Surratt, J. D.; Topping, D. O.; McFiggans, G.; Flagan, R. C.; Seinfeld, J. H.

    2007-06-01

    Cloud condensation nucleus (CCN) experiments were carried out for malonic acid, succinic acid, oxalacetic acid, DL-malic acid, glutaric acid, DL-glutamic acid monohydrate, and adipic acid, using both water and methanol as atomization solvents, at three operating supersaturations (0.11%, 0.21%, and 0.32%) in the Caltech three-column CCN instrument (CCNC3). Predictions of CCN behavior for five of these compounds were made using the Aerosol Diameter Dependent Equilibrium Model (ADDEM). The experiments presented here expose important considerations associated with the laboratory measurement of the CCN behavior of organic compounds. Choice of atomization solvent results in significant differences in CCN activation for some of the compounds studied, which could result from residual solvent, particle morphology differences, and chemical reactions between the particle and gas phases. Also, significant changes in aerosol size distribution occurred after classification in a differential mobility analyzer (DMA) for malonic acid and glutaric acid, preventing confident interpretation of experimental data for these two compounds. Filter analysis of adipic acid atomized from methanol solution indicates that gas-particle phase reactions may have taken place after atomization and before methanol was removed from the sample gas stream. Careful consideration of these experimental issues is necessary for successful design and interpretation of laboratory CCN measurements.

  19. Cloud condensation nucleus (CCN behavior of organic aerosol particles generated by atomization of water and methanol solutions

    Directory of Open Access Journals (Sweden)

    T. A. Rissman

    2007-06-01

    Full Text Available Cloud condensation nucleus (CCN experiments were carried out for malonic acid, succinic acid, oxalacetic acid, DL-malic acid, glutaric acid, DL-glutamic acid monohydrate, and adipic acid, using both water and methanol as atomization solvents, at three operating supersaturations (0.11%, 0.21%, and 0.32% in the Caltech three-column CCN instrument (CCNC3. Predictions of CCN behavior for five of these compounds were made using the Aerosol Diameter Dependent Equilibrium Model (ADDEM. The experiments presented here expose important considerations associated with the laboratory measurement of the CCN behavior of organic compounds. Choice of atomization solvent results in significant differences in CCN activation for some of the compounds studied, which could result from residual solvent, particle morphology differences, and chemical reactions between the particle and gas phases. Also, significant changes in aerosol size distribution occurred after classification in a differential mobility analyzer (DMA for malonic acid and glutaric acid, preventing confident interpretation of experimental data for these two compounds. Filter analysis of adipic acid atomized from methanol solution indicates that gas-particle phase reactions may have taken place after atomization and before methanol was removed from the sample gas stream. Careful consideration of these experimental issues is necessary for successful design and interpretation of laboratory CCN measurements.

  20. Cloud condensation nucleus (CCN behavior of organic aerosol particles generated by atomization of water and methanol solutions

    Directory of Open Access Journals (Sweden)

    T. A. Rissman

    2006-12-01

    Full Text Available Cloud condensation nucleus (CCN experiments were carried out for malonic acid, succinic acid, oxalacetic acid, DL-malic acid, glutaric acid, DL-glutamic acid monohydrate, and adipic acid, using both water and methanol as atomization solvents, at three operating supersaturations (0.11% 0.21%, and 0.32% in the Caltech three-column CCN instrument (CCNC3. Predictions of CCN behavior for five of these compounds were made using the Aerosol Diameter Dependent Equilibrium Model (ADDEM. The experiments presented here expose important considerations associated with the laboratory measurement of the CCN behavior of organic compounds. Choice of atomization solvent results in significant differences in CCN activation for some of the compounds studied, which could result from residual solvent, particle morphology differences, and chemical reactions between the particle and gas phases. Also, significant changes in aerosol size distribution occurred after classification in a differential mobility analyzer (DMA for malonic acid and glutaric acid. Filter analysis of adipic acid atomized from methanol solution indicates that gas-particle phase reactions may have taken place after atomization and before the methanol was removed from the sample gas stream. Careful consideration of these experimental issues is necessary for successful design and interpretation of laboratory CCN measurements.

  1. Determination of Mecruy at Trace Level in Natural Water Samples by Hydride Generation Atomic Absorption Spectrophotometry after Cloud Point Extraction Preconcentration

    Institute of Scientific and Technical Information of China (English)

    Ji Ying SONG; Ming HOU; Li Xiang ZHANG

    2006-01-01

    A method for the determination of trace mercury in water samples by hydride generation atomic absorption spectrophotometry after cloud point extraction was proposed in the present work.The effects of pH, concentration of surfactant, and equilibration time on cloud point extraction were discussed. The enhancement factor of 20 and the detection limit of 0.039 μg/L were obtained for mercury with relative standard deviation of 4.8% (n = 11).

  2. Determination of Ultratrace Amounts of Copper(Ⅱ) in Water Samples by Electrothermal Atomic Absorption Spectrometry After Cloud Point Extraction

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    A novel approach was developed for the determination of ultratrace amounts of copper in water samples by using electrothermal atomic absorption spectrometry (ETAAS) after cloud point extraction (CPE). 1-( 2-Pyridylazo)-2-naphthol was used as the chelating reagent and Triton X-114 as the micellar-forming surfactant. CPE was conducted in a pH 8.0 medium at 40 ℃ for 10 min. After the separation of the phases by centrifugation, the surfactant-rich phase was diluted with 1 mL of a methanol solution of 0. 1 mol/L HNO3. Then 20 μL of the diluted surfactant-rich phase was injected into the graphite furnace for atomization in the absence of any matrix modifier. Various experimental conditions that affect the extraction and atomization processes were optimized. A detection limit of 5 ng/L was obtained after preconcentration. The linear dynamic range of the copper mass concentration was found to be 0-2.0ng/mL, and the relative standard deviation was found to be less than 3.1% for a sample containing 1.0 ng/mL Cu(Ⅱ). This developed method was successfully applied to the determination of ultratrace amounts of Cu in drinking water, tap water, and seawater samples.

  3. Coherence effects in scattering order expansion of light by atomic clouds

    CERN Document Server

    Rouabah, Mohamed-Taha; Bachelard, Romain; Courteille, Philippe W; Kaiser, Robin; Piovella, Nicola

    2014-01-01

    We interpret cooperative scattering by a collection of cold atoms as a multiple scattering process. Starting from microscopic equations describing the response of $N$ atoms to a probe light beam, we represent the total scattered field as an infinite series of multiple scattering events. As an application of the method, we obtain analytical expressions of the coherent intensity in the double scattering approximation for Gaussian density profiles. In particular, we quantify the contributions of coherent backward and forward scattering.

  4. Coherence effects in scattering order expansion of light by atomic clouds.

    Science.gov (United States)

    Rouabah, Mohamed-Taha; Samoylova, Marina; Bachelard, Romain; Courteille, Philippe W; Kaiser, Robin; Piovella, Nicola

    2014-05-01

    We interpret cooperative scattering by a collection of cold atoms as a multiple-scattering process. Starting from microscopic equations describing the response of N atoms to a probe light beam, we represent the total scattered field as an infinite series of multiple-scattering events. As an application of the method, we obtain analytical expressions of the coherent intensity in the double-scattering approximation for Gaussian density profiles. In particular, we quantify the contributions of coherent backward and forward scattering.

  5. Applying a one-dimensional PDR model to the Taurus molecular cloud and its atomic envelope

    CERN Document Server

    Heiner, J S

    2012-01-01

    In this contribution, we test our previously published one-dimensional PDR model for deriving total hydrogen volume densities from HI column density measurements in extragalactic regions by applying it to the Taurus molecular cloud, where its predictions can be compared to available data. Also, we make the first direct detailed comparison of our model to CO(1-0) and far-infrared emission. Using an incident UV flux G0 of 4.25 ({\\chi} = 5) throughout the main body of the cloud, we derive total hydrogen volume densities of \\approx 430 cm-3, consistent with the extensive literature available on Taurus. The distribution of the volume densities shows a log-normal shape with a hint of a power-law shape on the high density end. We convert our volume densities to H2 column densities assuming a cloud depth of 5 parsec and compare these column densities to observed CO emission. We find a slope equivalent to a CO conversion factor relation that is on the low end of reported values for this factor in the literature (0.9 x...

  6. Cold and warm atomic gas around the Perseus molecular cloud I: Basic Properties

    CERN Document Server

    Stanimirovic, Snezana; Lee, Min-Young; Heiles, Carl; Miller, Jesse

    2014-01-01

    (Abridged) Using the Arecibo Observatory we have obtained neutral hydrogen (HI) absorption and emission spectral pairs in the direction of 26 background radio continuum sources in the vicinity of the Perseus molecular cloud. Strong absorption lines were detected in all cases allowing us to estimate spin temperature (T_s) and optical depth for 107 individual Gaussian components along these lines of sight. Basic properties of individual HI clouds (spin temperature, optical depth, and the column density of the cold and warm neutral medium, CNM and WNM) in and around Perseus are very similar to those found for random interstellar lines of sight sampled by the Millennium HI survey. This suggests that the neutral gas found in and around molecular clouds is not atypical. However, lines of sight in the vicinity of Perseus have on average a higher total HI column density and the CNM fraction, suggesting an enhanced amount of cold HI relative to an average interstellar field. Our estimated optical depth and spin temper...

  7. Atoms

    Institute of Scientific and Technical Information of China (English)

    刘洪毓

    2007-01-01

    Atoms(原子)are all around us.They are something like the bricks (砖块)of which everything is made. The size of an atom is very,very small.In just one grain of salt are held millions of atoms. Atoms are very important.The way one object acts depends on what

  8. Cloud point extraction and flame atomic absorption spectrometric determination of cadmium and nickel in drinking and wastewater samples.

    Science.gov (United States)

    Naeemullah; Kazi, Tasneem G; Shah, Faheem; Afridi, Hassan I; Baig, Jameel Ahmed; Soomro, Abdul Sattar

    2013-01-01

    A simple method for the preconcentration of cadmium (Cd) and nickel (Ni) in drinking and wastewater samples was developed. Cloud point extraction has been used for the preconcentration of both metals, after formation of complexes with 8-hydroxyquinoline (8-HQ) and extraction with the surfactant octylphenoxypolyethoxyethanol (Triton X-114). Dilution of the surfactant-rich phase with acidified ethanol was performed after phase separation, and the Cd and Ni contents were measured by flame atomic absorption spectrometry. The experimental variables, such as pH, amounts of reagents (8-HQ and Triton X-114), temperature, incubation time, and sample volume, were optimized. After optimization of the complexation and extraction conditions, enhancement factors of 80 and 61, with LOD values of 0.22 and 0.52 microg/L, were obtained for Cd and Ni, respectively. The proposed method was applied satisfactorily for the determination of both elements in drinking and wastewater samples.

  9. Speciation determination of chromium(III) and (VI) using preconcentration cloud point extraction with flame atomic absorption spectrometry (FAAS)

    Energy Technology Data Exchange (ETDEWEB)

    Kiran, K. [Department of Environmental Sciences, S.V. University, Tirupati, 517502 A.P. (India); Kumar, K. Suresh; Prasad, B.; Suvardhan, K. [Department of Chemistry, S. V. University, Tirupati, 517502 A.P. (India); Lekkala, Ramesh Babu [Department of Environmental Sciences, S.V. University, Tirupati, 517502 A.P. (India); Janardhanam, K. [Department of Environmental Sciences, S.V. University, Tirupati, 517502 A.P. (India)], E-mail: Kandukurijanardhanam@gmail.com

    2008-02-11

    bis-[2-Hydroxy-1-naphthaldehyde] thiourea was synthesized and preconcentration cloud point extraction (CPE) for speciation determination of chromium(III) and (VI) in various environmental samples with flame atomic absorption spectrometry (FAAS) has been developed. Chromium(III) complexes with bis-[2-hydroxynaphthaldehyde] thiourea is subsequently entrapped in the surfactant micelles. After complexation of chromium(III) with reagent, the analyte was quantitatively extracted to the surfactant-rich phase in the non-ionic surfactant Triton X-100 after centrifugation. The effect of pH, concentration of chelating agent, surfactant, equilibration temperature and time on CPE was studied. The relative standard deviation was 2.13% and the limits of detection were around 0.18 {mu}g L{sup -1}.

  10. Preconcentration procedure using cloud point extraction in the presence of electrolyte for cadmium determination by flame atomic absorption spectrometry

    Science.gov (United States)

    Coelho, Luciana Melo; Arruda, Marco Aurélio Zezzi

    2005-06-01

    This paper describes a micelle-mediated phase separation in the presence of electrolyte as a preconcentration method for cadmium determination by flame atomic absorption spectrometry (FAAS). Cadmium was complexed with ammonium O,O-diethyldithiophosphate (DDTP) in an acidic medium (0.32 mol l- 1 HCl) using Triton X-114 as surfactant and quantitatively extracted into a small volume (about 20 μl) of the surfactant-rich phase after centrifugation. The chemical variables that affect the cloud point extraction, such as complexing time (0 20 min), Triton X114 concentration (0.043 0.87% w/v) and complexing agent concentration (0.01 0.1 mol l- 1), were investigated. The cloud point is formed in the presence of NaCl at room temperature (25 °C), and the electrolyte concentration (0.5 5% w/v) was also investigated. Under optimized conditions, only 8 ml of sample was used in the presence of 0.043% w/v Triton X-114 and 1% (w/v) NaCl. This method permitted limits of detection and quantification of 0.9 μg l- 1 and 2.9 μg l- 1 Cd, respectively, and a linear calibration range from 3 to 400 μg l- 1 Cd. The proposed method was applied to Cd determination in physiological solutions (containing 0.9% (w/v) of NaCl), mineral water, lake water and cigarette samples (tobacco).

  11. Cloud point extraction for the determination of copper, nickel and cobalt ions in environmental samples by flame atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Ghaedi, M. [Chemistry Department, University of Yasouj, Yasouj 75914-353 (Iran, Islamic Republic of)], E-mail: m_ghaedi@mail.yu.ac.ir; Shokrollahi, A.; Ahmadi, F.; Rajabi, H.R. [Chemistry Department, University of Yasouj, Yasouj 75914-353 (Iran, Islamic Republic of); Soylak, M. [Chemistry Department, University of Erciyes, 38039 Kayseri (Turkey)

    2008-02-11

    A cloud point extraction procedure was presented for the preconcentration of copper, nickel and cobalt ions in various samples. After complexation with methyl-2-pyridylketone oxime (MPKO) in basic medium, analyte ions are quantitatively extracted to the phase rich in Triton X-114 following centrifugation. 1.0 mol L{sup -1} HNO{sub 3} nitric acid in methanol was added to the surfactant-rich phase prior to its analysis by flame atomic absorption spectrometry (FAAS). The adopted concentrations for MPKO, Triton X-114 and HNO{sub 3}, bath temperature, centrifuge rate and time were optimized. Detection limits (3 SDb/m) of 1.6, 2.1 and 1.9 ng mL{sup -1} for Cu{sup 2+}, Co{sup 2+} and Ni{sup 2+} along with preconcentration factors of 30 and for these ions and enrichment factor of 65, 58 and 67 for Cu{sup 2+}, Ni{sup 2+} and Co{sup 2+}, respectively. The high efficiency of cloud point extraction to carry out the determination of analytes in complex matrices was demonstrated. The proposed procedure was applied to the analysis of biological, natural and wastewater, soil and blood samples.

  12. Determination of ultra-trace aluminum in human albumin by cloud point extraction and graphite furnace atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Sun Mei, E-mail: sunmei@ustc.edu.cn [Hefei National Laboratory for Physical Sciences on Microscale, University of Science and Technology of China, No. 96, Jinzhai Road, Hefei 230026 (China); Wu Qianghua [Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026 (China)

    2010-04-15

    A cloud point extraction (CPE) method for the preconcentration of ultra-trace aluminum in human albumin prior to its determination by graphite furnace atomic absorption spectrometry (GFAAS) had been developed in this paper. The CPE method was based on the complex of Al(III) with 1-(2-pyridylazo)-2-naphthol (PAN) and Triton X-114 was used as non-ionic surfactant. The main factors affecting cloud point extraction efficiency, such as pH of solution, concentration and kind of complexing agent, concentration of non-ionic surfactant, equilibration temperature and time, were investigated in detail. An enrichment factor of 34.8 was obtained for the preconcentration of Al(III) with 10 mL solution. Under the optimal conditions, the detection limit of Al(III) was 0.06 ng mL{sup -1}. The relative standard deviation (n = 7) of sample was 3.6%, values of recovery of aluminum were changed from 92.3% to 94.7% for three samples. This method is simple, accurate, sensitive and can be applied to the determination of ultra-trace aluminum in human albumin.

  13. Cloud point extraction-flame atomic absorption spectrometry method for preconcentration and determination of trace cadmium in water samples.

    Science.gov (United States)

    Ning, Jinyan; Jiao, Yang; Zhao, Jiao; Meng, Lifen; Yang, Yaling

    2014-01-01

    A method based on cloud point extraction (CPE) separation/preconcentration of trace cadmium (Cd) as a prior step to its determination by flame atomic absorption spectrometry has been developed. Cadmium reacted with 8-hydroxyquinoline to form hydrophobic chelates, which were extracted into the micelles of nonionic surfactant oligoethylene glycol monoalkyl ether (Genapol X-080) in an alkaline medium. Octanol was used to depress the cloud point of Genapol X-080 in the extraction process. The chemical variables that affect the CPE, such as pH of complexation reaction, amount of chelating agent, Genapol X-080 and octanol were evaluated and optimized. Under optimized conditions, linearity was obeyed in the range of 10-500 μg/L, with the correlation coefficient of 0.9993. For 5 mL of sample solution, the enhancement factor was about 20. The limit of detection and limit of quantification of the method were 0.21 and 0.63 μg/L, respectively. The relative standard deviations (n = 6) was 3.2% for a solution containing 100 μg/L of Cd. The accuracy of the preconcentration system was evaluated by recovery measurements on spiked water samples. Recoveries of spiked samples varied in the range of 94.1-103.8%.

  14. Cloud point extraction for the determination of copper, nickel and cobalt ions in environmental samples by flame atomic absorption spectrometry.

    Science.gov (United States)

    Ghaedi, M; Shokrollahi, A; Ahmadi, F; Rajabi, H R; Soylak, M

    2008-02-11

    A cloud point extraction procedure was presented for the preconcentration of copper, nickel and cobalt ions in various samples. After complexation with methyl-2-pyridylketone oxime (MPKO) in basic medium, analyte ions are quantitatively extracted to the phase rich in Triton X-114 following centrifugation. 1.0 mol L(-1) HNO(3) nitric acid in methanol was added to the surfactant-rich phase prior to its analysis by flame atomic absorption spectrometry (FAAS). The adopted concentrations for MPKO, Triton X-114 and HNO(3), bath temperature, centrifuge rate and time were optimized. Detection limits (3 SDb/m) of 1.6, 2.1 and 1.9 ng mL(-1) for Cu(2+), Co(2+) and Ni(2+) along with preconcentration factors of 30 and for these ions and enrichment factor of 65, 58 and 67 for Cu(2+), Ni(2+) and Co(2+), respectively. The high efficiency of cloud point extraction to carry out the determination of analytes in complex matrices was demonstrated. The proposed procedure was applied to the analysis of biological, natural and wastewater, soil and blood samples.

  15. Extracting features buried within high density atom probe point cloud data through simplicial homology.

    Science.gov (United States)

    Srinivasan, Srikant; Kaluskar, Kaustubh; Broderick, Scott; Rajan, Krishna

    2015-12-01

    Feature extraction from Atom Probe Tomography (APT) data is usually performed by repeatedly delineating iso-concentration surfaces of a chemical component of the sample material at different values of concentration threshold, until the user visually determines a satisfactory result in line with prior knowledge. However, this approach allows for important features, buried within the sample, to be visually obscured by the high density and volume (~10(7) atoms) of APT data. This work provides a data driven methodology to objectively determine the appropriate concentration threshold for classifying different phases, such as precipitates, by mapping the topology of the APT data set using a concept from algebraic topology termed persistent simplicial homology. A case study of Sc precipitates in an Al-Mg-Sc alloy is presented demonstrating the power of this technique to capture features, such as precise demarcation of Sc clusters and Al segregation at the cluster boundaries, not easily available by routine visual adjustment.

  16. Cloud point extraction for the determination of cadmium and lead in biological samples by graphite furnace atomic absorption spectrometry

    Science.gov (United States)

    Maranhão, Tatiane De A.; Borges, Daniel L. G.; da Veiga, Márcia A. M. S.; Curtius, Adilson J.

    2005-06-01

    The phase-separation phenomenon of non-ionic surfactants occurring in aqueous solution was used for the extraction of Cd and Pb from digested biological samples. After complexation with O,O-diethyldithiophosphate (DDTP) in hydrochloric acid medium, the analytes are quantitatively extracted to the phase rich in the non-ionic surfactant octylphenoxypolyethoxyethanol (Triton X-114) after centrifugation. Methanol acidified with 0.1 mol L-1 HNO3 was added to the surfactant-rich phase prior to its analysis by electrothermal atomic absorption spectrometry (ET AAS). The adopted concentrations for DDTP, Triton X-114 and hydrochloric acid were all optimized. Pyrolysis and atomization temperatures were optimized using the extracts and pyrolysis temperatures of 700 °C for both elements and atomization temperatures of 1400 and 1600 °C for cadmium and lead, respectively, were used without adding any modifier, which shows that considerable analyte stabilization is provided by the medium itself. A more detailed investigation was carried out to determine which components of the extract were responsible for the high thermal stability achieved and it revealed that the amount of DDTP added and the phosphorus content of the digested samples contributed significantly to this phenomenon. Detection limits (3σB) of 6 and 40 ng g-1, along with enrichment factors of 129 and 18 for Cd and Pb, respectively, were achieved. The proposed procedure was applied to the analysis of five certified biological reference materials after microwave-assisted acid digestion in a mixture of H2O2 and HNO3. Comparison with certified values was performed for accuracy evaluation, resulting in good agreement according to the t-test for a 95% confidence level. The high efficiency of cloud point extraction to carry out the determination of the studied analytes in complex matrices was, therefore, demonstrated.

  17. Cloud point extraction for the determination of cadmium and lead in biological samples by graphite furnace atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Maranhao, Tatiane de A. [Departamento de Quimica, Universidade Federal de Santa Catarina, 88040-900, Florianopolis, SC (Brazil); Borges, Daniel L.G. [Departamento de Quimica, Universidade Federal de Santa Catarina, 88040-900, Florianopolis, SC (Brazil)]. E-mail: daniel@qmc.ufsc.br; Veiga, Marcia A.M.S. da [Instituto de Quimica, Universidade de Sao Paulo, 05513-970, CP 26077, Sao Paulo, SP (Brazil); Curtius, Adilson J. [Departamento de Quimica, Universidade Federal de Santa Catarina, 88040-900, Florianopolis, SC (Brazil)

    2005-06-30

    The phase-separation phenomenon of non-ionic surfactants occurring in aqueous solution was used for the extraction of Cd and Pb from digested biological samples. After complexation with O,O-diethyldithiophosphate (DDTP) in hydrochloric acid medium, the analytes are quantitatively extracted to the phase rich in the non-ionic surfactant octylphenoxypolyethoxyethanol (Triton X-114) after centrifugation. Methanol acidified with 0.1 mol L{sup -1} HNO{sub 3} was added to the surfactant-rich phase prior to its analysis by electrothermal atomic absorption spectrometry (ET AAS). The adopted concentrations for DDTP, Triton X-114 and hydrochloric acid were all optimized. Pyrolysis and atomization temperatures were optimized using the extracts and pyrolysis temperatures of 700 deg. C for both elements and atomization temperatures of 1400 and 1600 deg. C for cadmium and lead, respectively, were used without adding any modifier, which shows that considerable analyte stabilization is provided by the medium itself. A more detailed investigation was carried out to determine which components of the extract were responsible for the high thermal stability achieved and it revealed that the amount of DDTP added and the phosphorus content of the digested samples contributed significantly to this phenomenon. Detection limits (3{sigma} {sub B}) of 6 and 40 ng g{sup -1}, along with enrichment factors of 129 and 18 for Cd and Pb, respectively, were achieved. The proposed procedure was applied to the analysis of five certified biological reference materials after microwave-assisted acid digestion in a mixture of H{sub 2}O{sub 2} and HNO{sub 3}. Comparison with certified values was performed for accuracy evaluation, resulting in good agreement according to the t-test for a 95% confidence level. The high efficiency of cloud point extraction to carry out the determination of the studied analytes in complex matrices was, therefore, demonstrated.

  18. Preconcentration procedure using cloud point extraction in the presence of electrolyte for cadmium determination by flame atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Melo Coelho, Luciana [Departamento de Quimica Analitica, Universidade Estadual de Campinas (Unicamp), Cidade Universitaria ' Zeferino Vaz' , 13084-971, Campinas, Sao Paulo (Brazil); Arruda, Marco Aurelio Zezzi [Departamento de Quimica Analitica, Universidade Estadual de Campinas (Unicamp), Cidade Universitaria ' Zeferino Vaz' , 13084-971, Campinas, Sao Paulo (Brazil)]. E-mail: zezzi@iqm.unicamp.br

    2005-06-30

    This paper describes a micelle-mediated phase separation in the presence of electrolyte as a preconcentration method for cadmium determination by flame atomic absorption spectrometry (FAAS). Cadmium was complexed with ammonium O,O-diethyldithiophosphate (DDTP) in an acidic medium (0.32 mol l{sup -} {sup 1} HCl) using Triton X-114 as surfactant and quantitatively extracted into a small volume (about 20 {mu}l) of the surfactant-rich phase after centrifugation. The chemical variables that affect the cloud point extraction, such as complexing time (0-20 min), Triton X114 concentration (0.043-0.87% w/v) and complexing agent concentration (0.01-0.1 mol l{sup -} {sup 1}), were investigated. The cloud point is formed in the presence of NaCl at room temperature (25 deg. C), and the electrolyte concentration (0.5-5% w/v) was also investigated. Under optimized conditions, only 8 ml of sample was used in the presence of 0.043% w/v Triton X-114 and 1% (w/v) NaCl. This method permitted limits of detection and quantification of 0.9 {mu}g l{sup -} {sup 1} and 2.9 {mu}g l{sup -} {sup 1} Cd, respectively, and a linear calibration range from 3 to 400 {mu}g l{sup -} {sup 1} Cd. The proposed method was applied to Cd determination in physiological solutions (containing 0.9% (w/v) of NaCl), mineral water, lake water and cigarette samples (tobacco)

  19. Cloud point extraction for trace inorganic arsenic speciation analysis in water samples by hydride generation atomic fluorescence spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Li, Shan, E-mail: ls_tuzi@163.com; Wang, Mei, E-mail: wmei02@163.com; Zhong, Yizhou, E-mail: yizhz@21cn.com; Zhang, Zehua, E-mail: kazuki.0101@aliyun.com; Yang, Bingyi, E-mail: e_yby@163.com

    2015-09-01

    A new cloud point extraction technique was established and used for the determination of trace inorganic arsenic species in water samples combined with hydride generation atomic fluorescence spectrometry (HGAFS). As(III) and As(V) were complexed with ammonium pyrrolidinedithiocarbamate and molybdate, respectively. The complexes were quantitatively extracted with the non-ionic surfactant (Triton X-114) by centrifugation. After addition of antifoam, the surfactant-rich phase containing As(III) was diluted with 5% HCl for HGAFS determination. For As(V) determination, 50% HCl was added to the surfactant-rich phase, and the mixture was placed in an ultrasonic bath at 70 °C for 30 min. As(V) was reduced to As(III) with thiourea–ascorbic acid solution, followed by HGAFS. Under the optimum conditions, limits of detection of 0.009 and 0.012 μg/L were obtained for As(III) and As(V), respectively. Concentration factors of 9.3 and 7.9, respectively, were obtained for a 50 mL sample. The precisions were 2.1% for As(III) and 2.3% for As(V). The proposed method was successfully used for the determination of trace As(III) and As(V) in water samples, with satisfactory recoveries. - Highlights: • Cloud point extraction was firstly established to determine trace inorganic arsenic(As) species combining with HGAFS. • Separate As(III) and As(V) determinations improve the accuracy. • Ultrasonic release of complexed As(V) enables complete As(V) reduction to As(III). • Direct HGAFS analysis can be performed.

  20. Species selective preconcentration and quantification of gold nanoparticles using cloud point extraction and electrothermal atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Hartmann, Georg, E-mail: georg.hartmann@tum.de [Department of Chemistry, Technische Universitaet Muenchen, 85748 Garching (Germany); Schuster, Michael, E-mail: michael.schuster@tum.de [Department of Chemistry, Technische Universitaet Muenchen, 85748 Garching (Germany)

    2013-01-25

    Highlights: Black-Right-Pointing-Pointer We optimized cloud point extraction and ET-AAS parameters for Au-NPs measurement. Black-Right-Pointing-Pointer A selective ligand (sodium thiosulphate) is introduced for species separation. Black-Right-Pointing-Pointer A limit of detection of 5 ng Au-NP per L is achieved for aqueous samples. Black-Right-Pointing-Pointer Measurement of samples with high natural organic mater content is possible. Black-Right-Pointing-Pointer Real water samples including wastewater treatment plant effluent were analyzed. - Abstract: The determination of metallic nanoparticles in environmental samples requires sample pretreatment that ideally combines pre-concentration and species selectivity. With cloud point extraction (CPE) using the surfactant Triton X-114 we present a simple and cost effective separation technique that meets both criteria. Effective separation of ionic gold species and Au nanoparticles (Au-NPs) is achieved by using sodium thiosulphate as a complexing agent. The extraction efficiency for Au-NP ranged from 1.01 {+-} 0.06 (particle size 2 nm) to 0.52 {+-} 0.16 (particle size 150 nm). An enrichment factor of 80 and a low limit of detection of 5 ng L{sup -1} is achieved using electrothermal atomic absorption spectrometry (ET-AAS) for quantification. TEM measurements showed that the particle size is not affected by the CPE process. Natural organic matter (NOM) is tolerated up to a concentration of 10 mg L{sup -1}. The precision of the method expressed as the standard deviation of 12 replicates at an Au-NP concentration of 100 ng L{sup -1} is 9.5%. A relation between particle concentration and the extraction efficiency was not observed. Spiking experiments showed a recovery higher than 91% for environmental water samples.

  1. Speciation of silver nanoparticles and Ag(I) species using cloud point extraction followed by electrothermal atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    López-García, Ignacio; Vicente-Martínez, Yesica; Hernández-Córdoba, Manuel, E-mail: hcordoba@um.es

    2014-11-01

    Silver nanoparticles in the presence of Triton-X114 were extracted into a micellar phase obtained after incubation at 40 °C for 10 min followed by centrifugation. After injection of an aliquot (30 μL) of the surfactant-rich phase into the electrothermal atomizer, the enrichment effect due to cloud point extraction allowed a detection limit of 2 ng L{sup −1} silver to be achieved. The preconcentration factor was 242, and the repeatability for ten measurements at a 50 ng L{sup −1} silver level was 4.6%. Ag(I) species were adsorbed onto the silver nanoparticles and were also extracted in the micellar phase. The incorporation of 0.01 mol L{sup −1} ammonium thiocyanate to the sample solution prevented the extraction of Ag(I) species. Speciation was carried out using two extractions, one in the absence and the other in the presence of thiocyanate, the concentration of Ag(I) species being obtained by difference. The procedure was applied to the determination of silver nanoparticles and Ag(I) species in waters and in lixiviates obtained from sticking plasters and cleaning cloths. - Highlights: • Silver nanoparticles and Ag(I) species are separated into a surfactant-rich phase. • The Ag(I) species are not extracted in the presence of thiocyanate. • The cloud point extraction of two aliquots allows speciation to be carried out. • Extreme sensitivity (detection limit 2 ng L{sup −1}) is achieved.

  2. Determination of platinum traces contamination by graphite furnace atomic absorption spectrometry after preconcentration by cloud point extraction

    Energy Technology Data Exchange (ETDEWEB)

    Chappuy, M. [Analytical Development Laboratory, Pharmaceutical Establishment of Paris Hospitals, 7 rue du Fer a Moulin, 75005 Paris (France); Caudron, E., E-mail: eric.caudron@eps.aphp.fr [Analytical Development Laboratory, Pharmaceutical Establishment of Paris Hospitals, 7 rue du Fer a Moulin, 75005 Paris (France); Groupe de Chimie Analytique de Paris-Sud, EA 4041, IFR 141, School of Pharmacy, Univ Paris-Sud, 92296 Chatenay-Malabry (France); Bellanger, A. [Department of Pharmacy, Pitie-Salpetriere Hospital (Paris Public Hospital Authority), 47 boulevard de l' hopital, 75013 Paris (France); Pradeau, D. [Analytical Development Laboratory, Pharmaceutical Establishment of Paris Hospitals, 7 rue du Fer a Moulin, 75005 Paris (France)

    2010-04-15

    A simple and sensitive method is described for the determination of platinum surface contamination originating from cisplatin, carboplatin and oxaliplatin. Following extraction from swabs and preconcentration with the cloud point extraction (CPE) method, detection was by graphite furnace atomic absorption spectrometry (GFAAS). After desorption of platinum compounds from the swab, CPE involved on preconcentration of platinum in aqueous solution with diethyldithiocarbamate (DDTC) as chelating agent and Triton X-114 as extraction medium. DDTC is not only a chelating agent, but may also be a good candidate for the inactivation of platinum compounds. DDTC is recommended by the Word Health Organization (WHO) for the destruction of platinum-based anticancer drugs. The main factors affecting CPE efficiency, pH of the sample solution, concentrations of DDTC and Triton X-114, equilibration temperature and incubation time, were evaluated in order to enhance sensitivity of the method. The desorption of platinum compounds from the swab was investigated in parallel. Since platinum is bound to DDTC, it must exchange with copper in order to enhance platinum atomizing by GFAAS. A preconcentration factor of 29 was obtained for 10 mL of a platinum solution at 10 {mu}g mL{sup -1}. In optimal conditions, the limit of detection was 0.2 ng mL{sup -1}, corresponding to 2.0 ng of platinum metal on the swab. Absorbance was linear between 0.7 and 15 ng mL{sup -1}. The proposed method was applied for the determination of surface contamination by platinum compounds with correct results.

  3. Cloud point extraction for the preconcentration of silver and palladium in real samples and determination by atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Tavallali, Hossein; Yazdandoust, Saeed; Yazdandoust, Mozhdeh [Department of Chemistry, Payame Noor University (PNU), Shiraz (Iran)

    2010-03-15

    A cloud point extraction procedure is presented for the preconcentration and simultaneous determination of Ag{sup +} and Pd{sup 2+} in various samples. After complexation with 2-((2-((1H-benzo[d]imidazole-2-yl)methoxy)phenoxy)methyl)-1H-benzo[d]imidazol (BIMPI), which was used as a new chelating agent, analyte ions were quantitatively extracted to a phase rich in Triton X-114 following centrifugation, and determination was carried out by flame atomic absorption spectrometry (FAAS). Under the optimum experimental conditions (i. e., pH = 7.0, 15.0.10{sup -5} mol/L BIMPI and 0.036% (w/v) Triton X-114), calibration graphs were linear in the range of 28.0-430.0 {mu}g/L and 57.0-720.0 {mu}g/L with detection limits of 10.0 and 25.0 {mu}g/L for Ag{sup +} and Pd{sup 2+}, respectively. The enrichment factors were 35.0 and 28.0 for Ag{sup +} and Pd{sup 2+}, respectively. The method has been successfully applied to evaluate these metals in some real samples, including waste water, soil and hydrogenation catalyst samples. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

  4. Cloud point extraction and flame atomic absorption spectrometry combination for copper(II) ion in environmental and biological samples

    Energy Technology Data Exchange (ETDEWEB)

    Shokrollahi, Ardeshir [Chemistry Department, Yasouj University, Yasouj 75914-353 (Iran, Islamic Republic of)], E-mail: ashokrollahi@mail.yu.ac.ir; Ghaedi, Mehrorang [Chemistry Department, Yasouj University, Yasouj 75914-353 (Iran, Islamic Republic of)], E-mail: m_ghaedi@mail.yu.ac.ir; Hossaini, Omid; Khanjari, Narges [Chemistry Department, Yasouj University, Yasouj 75914-353 (Iran, Islamic Republic of); Soylak, Mustafa [Chemistry Department, University of Erciyes, 38039 Kayseri (Turkey)

    2008-12-30

    A cloud point extraction procedure was presented for the preconcentration of copper(II) ion in various samples. After complexation by 4-(phenyl diazenyl) benzene-1,3-diamine (PDBDM) (chrysoidine), copper(II) ions were quantitatively recovered in Triton X-114 after centrifugation. 0.5 ml of methanol acidified with 1.0 mol L{sup -1} HNO{sub 3} was added to the surfactant-rich phase prior to its analysis by flame atomic absorption spectrometry (FAAS). The influence of analytical parameters including ligand, Triton X-114 and HNO{sub 3} concentrations, bath temperature, heating time, centrifuge rate and time were optimized. The effect of the matrix ions on the recovery of copper(II) ions was investigated. The detection limit (3S.D.{sub b}/m, n = 10) of 0.6 ng mL{sup -1} along with preconcentration factor of 30 and enrichment factor of 41.1 with R.S.D. of 1.0% for Cu was achieved. The proposed procedure was applied to the analysis of various environmental and biological samples.

  5. Speciation of silver nanoparticles and Ag(I) species using cloud point extraction followed by electrothermal atomic absorption spectrometry

    Science.gov (United States)

    López-García, Ignacio; Vicente-Martínez, Yesica; Hernández-Córdoba, Manuel

    2014-11-01

    Silver nanoparticles in the presence of Triton-X114 were extracted into a micellar phase obtained after incubation at 40 °C for 10 min followed by centrifugation. After injection of an aliquot (30 μL) of the surfactant-rich phase into the electrothermal atomizer, the enrichment effect due to cloud point extraction allowed a detection limit of 2 ng L- 1 silver to be achieved. The preconcentration factor was 242, and the repeatability for ten measurements at a 50 ng L- 1 silver level was 4.6%. Ag(I) species were adsorbed onto the silver nanoparticles and were also extracted in the micellar phase. The incorporation of 0.01 mol L- 1 ammonium thiocyanate to the sample solution prevented the extraction of Ag(I) species. Speciation was carried out using two extractions, one in the absence and the other in the presence of thiocyanate, the concentration of Ag(I) species being obtained by difference. The procedure was applied to the determination of silver nanoparticles and Ag(I) species in waters and in lixiviates obtained from sticking plasters and cleaning cloths.

  6. Cloud point extraction for trace inorganic arsenic speciation analysis in water samples by hydride generation atomic fluorescence spectrometry

    Science.gov (United States)

    Li, Shan; Wang, Mei; Zhong, Yizhou; Zhang, Zehua; Yang, Bingyi

    2015-09-01

    A new cloud point extraction technique was established and used for the determination of trace inorganic arsenic species in water samples combined with hydride generation atomic fluorescence spectrometry (HGAFS). As(III) and As(V) were complexed with ammonium pyrrolidinedithiocarbamate and molybdate, respectively. The complexes were quantitatively extracted with the non-ionic surfactant (Triton X-114) by centrifugation. After addition of antifoam, the surfactant-rich phase containing As(III) was diluted with 5% HCl for HGAFS determination. For As(V) determination, 50% HCl was added to the surfactant-rich phase, and the mixture was placed in an ultrasonic bath at 70 °C for 30 min. As(V) was reduced to As(III) with thiourea-ascorbic acid solution, followed by HGAFS. Under the optimum conditions, limits of detection of 0.009 and 0.012 μg/L were obtained for As(III) and As(V), respectively. Concentration factors of 9.3 and 7.9, respectively, were obtained for a 50 mL sample. The precisions were 2.1% for As(III) and 2.3% for As(V). The proposed method was successfully used for the determination of trace As(III) and As(V) in water samples, with satisfactory recoveries.

  7. Preconcentration and determination of zinc and lead ions by a combination of cloud point extraction and flame atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Tavallali, H. [Chemistry Department, Payamenore University, Shiraz (Iran); Shokrollahi, A.; Zahedi, M. [Chemistry Department, Yasouj University, Yasouj (Iran); Niknam, K. [Chemistry Department, Persian Gulf University, Bushehr (Iran); Soylak, M. [Chemistry Department, University of Erciyes, Kayseri (Turkey); Ghaedi, M.

    2009-04-15

    The phase-separation phenomenon of non-ionic surfactants occurring in aqueous solution was used for the extraction of lead(II) and zinc(II). After complexation with 3-[(4-bromophenyl) (1-H-inden-3-yl)methyl]-1 H-indene (BPIMI), the analytes were quantitatively extracted to a phase rich in Triton X-114 after centrifugation. Methanol acidified with 1 mol/L HNO{sub 3} was added to the surfactant rich phase prior to its analysis by flame atomic absorption spectrometry (FAAS). The concentration of bis((1H-benzo [d] imidazol-2yl)ethyl)sulfane, Triton X-114, pH and amount of surfactant were all optimized. Detection limits (3 SDb/m) of 2.5 and 1.6 ng/mL for Pb{sup 2+} and Zn{sup 2+} along with preconcentration factors of 30 and an enrichment factor of 32 and 48 for Pb{sup 2+}and Zn {sup 2+} ions were obtained, respectively. The proposed cloud point extraction was been successfully applied for the determination of these ions in real samples with complicated matrices such as food and soil samples, with high efficiency. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

  8. Reaction between atomic N(4S) and molecular CO at very low temperature: possible formation of HNCO in the Oort cloud

    Science.gov (United States)

    Nourry, Sendres; Zins, Emilie-Laure; Krim, Lahouari

    2015-07-01

    Beyond the Kuiper belt, the Oort cloud is characterized by particularly cold temperatures and the absence of energetic particles. Specific chemical processes involving cold radicals may occur in this reservoir of comets. A microwave-driven atomic source can be used to generate cold atomic nitrogen (N (4S)) for reactivity study of ices relevant to the Oort cloud. Without any additional source of energy, atomic nitrogen does not react with CO molecules to form NCO. This is consistent with a previous theoretical investigation carried out by Yazidi et al., who have shown that the potential energy surface for the CO (X1Σ+) + N (4S) system is purely dissociative. On the other hand, a very small amount of water is sufficient to induce a reaction between these two species. This three-body reaction leads to the formation of the HNCO monomer, the (HNCO)(H2O) complex, and the hydroxyl radical. Such reactions, leading to prebiotic molecules, may take place in the Oort cloud and in the Kuiper belt, from which most of the comets come.

  9. Determination of ultra trace arsenic species in water samples by hydride generation atomic absorption spectrometry after cloud point extraction

    Energy Technology Data Exchange (ETDEWEB)

    Ulusoy, Halil Ibrahim, E-mail: hiulusoy@yahoo.com [University of Cumhuriyet, Faculty of Science, Department of Chemistry, TR-58140, Sivas (Turkey); Akcay, Mehmet; Ulusoy, Songuel; Guerkan, Ramazan [University of Cumhuriyet, Faculty of Science, Department of Chemistry, TR-58140, Sivas (Turkey)

    2011-10-10

    Graphical abstract: The possible complex formation mechanism for ultra-trace As determination. Highlights: {yields} CPE/HGAAS system for arsenic determination and speciation in real samples has been applied first time until now. {yields} The proposed method has the lowest detection limit when compared with those of similar CPE studies present in literature. {yields} The linear range of the method is highly wide and suitable for its application to real samples. - Abstract: Cloud point extraction (CPE) methodology has successfully been employed for the preconcentration of ultra-trace arsenic species in aqueous samples prior to hydride generation atomic absorption spectrometry (HGAAS). As(III) has formed an ion-pairing complex with Pyronine B in presence of sodium dodecyl sulfate (SDS) at pH 10.0 and extracted into the non-ionic surfactant, polyethylene glycol tert-octylphenyl ether (Triton X-114). After phase separation, the surfactant-rich phase was diluted with 2 mL of 1 M HCl and 0.5 mL of 3.0% (w/v) Antifoam A. Under the optimized conditions, a preconcentration factor of 60 and a detection limit of 0.008 {mu}g L{sup -1} with a correlation coefficient of 0.9918 was obtained with a calibration curve in the range of 0.03-4.00 {mu}g L{sup -1}. The proposed preconcentration procedure was successfully applied to the determination of As(III) ions in certified standard water samples (TMDA-53.3 and NIST 1643e, a low level fortified standard for trace elements) and some real samples including natural drinking water and tap water samples.

  10. Selective cloud point extraction and graphite furnace atomic absorption spectrometric determination of molybdenum (VI) ion in seawater samples

    Energy Technology Data Exchange (ETDEWEB)

    Filik, Hayati, E-mail: filik@istanbul.edu.tr [Istanbul University, Faculty of Engineering, Department of Chemistry, Avcilar, 34320 Istanbul (Turkey); Cengel, Tayfun; Apak, Resat [Istanbul University, Faculty of Engineering, Department of Chemistry, Avcilar, 34320 Istanbul (Turkey)

    2009-09-30

    A cloud point extraction process using the nonionic surfactant Triton X-114 to extract molybdenum from aqueous solutions was investigated. The method is based on the complexation reaction of Mo(VI) with 1,2,5,8-tetrahydroxyanthracene-9,10-dione (quinalizarine: QA) and micelle-mediated extraction of the complex. The enriched analyte in the surfactant-rich phase was determined by graphite furnace atomic absorption spectrometry (GFAAS). The optimal extraction and reaction conditions (e.g. pH, reagent and surfactant concentrations, temperature, incubation and centrifugation times) were evaluated and optimized. Under the optimized experimental conditions, the limit of detection (LOD) for Mo(VI) was 7.0 ng L{sup -1} with an preconcentration factor of {approx}25 when 10 mL of sample solution was preconcentrated to 0.4 mL. The proposed method (with extraction) showed linear calibration within the range 0.03-0.6 {mu}g L{sup -1}. The relative standard deviation (RSD) was found to be 3.7% (C{sub Mo(VI)} = 0.05 {mu}g L{sup -1}, n = 5) for pure standard solutions, whereas RSD for the recoveries from real samples ranged between 2 and 8% (mean RSD = 3.9%). The method was applied to the determination of Mo(VI) in seawater and tap water samples with a recovery for the spiked samples in the range of 98-103%. The interference effect of some cations and anions was also studied. In the presence of foreign ions, no significant interference was observed. In order to verify the accuracy of the method, a certified reference water sample was analysed and the results obtained were in good agreement with the certified values.

  11. Investigation of novel rapidly synergistic cloud point extraction pattern for bismuth in water and geological samples coupling with flame atomic absorption spectrometry determination

    Science.gov (United States)

    Wen, Xiaodong; Zhao, Yu; Deng, Qingwen; Ji, Shoulian; Zhao, Xia; Guo, Jie

    2012-04-01

    Rapidly synergistic cloud point extraction (RS-CPE) greatly simplified and accelerated the procedure of traditional cloud point extraction (CPE). In order to expand the application of RS-CPE, this work was carried out after the establishment of the improved extraction technique. The new established extraction method was firstly applied for bismuth extraction and determination coupled with flame atomic absorption spectrometry (FAAS) in this work. The improved RS-CPE was accomplished in the room temperature in 1 min. Non-ionic surfactant Triton X-100 (TX-100) was used as extractant. Octanol worked as cloud point revulsant and synergic reagent. TX-100 has a relatively high cloud point temperature (CPT), which limited its application in CPE. In this work, TX-100 accomplished the RS-CPE procedure in room temperature successfully. The factors influencing RS-CPE, such as concentrations of reagents, pH, conditions of phase separation, effect of environmental temperatures, salt effect and instrumental conditions, were studied systematically. Under the optimal conditions, the limit of detection (LOD) for bismuth was 4.0 μg L-1, with sensitivity enhancement factor (EF) of 43. The proposed method greatly improved the sensitivity of FAAS for the determination of bismuth and was applied to the determination of trace bismuth in real and certified samples with satisfactory analytical results. The proposed method was rapid, simple, and sensitive.

  12. Investigation of novel rapidly synergistic cloud point extraction pattern for bismuth in water and geological samples coupling with flame atomic absorption spectrometry determination.

    Science.gov (United States)

    Wen, Xiaodong; Zhao, Yu; Deng, Qingwen; Ji, Shoulian; Zhao, Xia; Guo, Jie

    2012-04-01

    Rapidly synergistic cloud point extraction (RS-CPE) greatly simplified and accelerated the procedure of traditional cloud point extraction (CPE). In order to expand the application of RS-CPE, this work was carried out after the establishment of the improved extraction technique. The new established extraction method was firstly applied for bismuth extraction and determination coupled with flame atomic absorption spectrometry (FAAS) in this work. The improved RS-CPE was accomplished in the room temperature in 1 min. Non-ionic surfactant Triton X-100 (TX-100) was used as extractant. Octanol worked as cloud point revulsant and synergic reagent. TX-100 has a relatively high cloud point temperature (CPT), which limited its application in CPE. In this work, TX-100 accomplished the RS-CPE procedure in room temperature successfully. The factors influencing RS-CPE, such as concentrations of reagents, pH, conditions of phase separation, effect of environmental temperatures, salt effect and instrumental conditions, were studied systematically. Under the optimal conditions, the limit of detection (LOD) for bismuth was 4.0 μg L(-1), with sensitivity enhancement factor (EF) of 43. The proposed method greatly improved the sensitivity of FAAS for the determination of bismuth and was applied to the determination of trace bismuth in real and certified samples with satisfactory analytical results. The proposed method was rapid, simple, and sensitive.

  13. Selective cloud point extraction and preconcentration of trace amounts of silver as a dithizone complex prior to flame atomic absorption spectrometric determination

    Energy Technology Data Exchange (ETDEWEB)

    Manzoori, Jamshid L.; Karim-Nezhad, Ghasem

    2003-05-19

    Dithizone (diphenylthiocarbazone) was used as a complexing agent in cloud point extraction for the first time and applied for selective preconcentration of trace amounts of silver. The analyte in the initial aqueous solution was acidified with sulfuric acid (pH<1) and Triton X-114 was added as a surfactant. After phase separation, based on the cloud point separation of the mixture, the surfactant rich phase was diluted with tetrahydrofuran (THF) and the analyte determined in the enriched solution by flame atomic absorption spectrometry. After optimization of the complexation and extraction conditions, a preconcentration factor of 43 was obtained for only 10 ml of sample. The analytical curve was linear in the range of 3-200 ng ml{sup -1} and the limit of detection was 0.56 ng ml{sup -1}. The proposed method was applied to the determination of silver in water samples.

  14. Rydberg Matter clusters of alkali metal atoms: the link between meteoritic matter, polar mesosphere summer echoes (PMSE), sporadic sodium layers, polar mesospheric clouds (PMCs, NLCs), and ion chemistry

    CERN Document Server

    Olofson, Frans; Holmlid, Leif

    2010-01-01

    A material exists which links together the influx of meteoritic matter from interplanetary space, the polar mesosphere summer echoes (PMSE), the sporadic sodium layers, the polar mesospheric clouds (PMCs, NLCs), and the observed ion chemistry in the mesosphere. The evidence in these research fields is here analyzed and found to agree well with the properties of Rydberg Matter (RM). This material has been studied with numerous methods in the laboratory. Alkali atoms, mainly Na, reach the mesosphere in the form of interplanetary (meteoritic, cometary) dust. The planar RM clusters NaN usually contain N = 19, 37 or 61 atoms, and have the density of air at 90 km altitude where they float. The diameters of the clusters are 10-100 nm from laboratory high precision radio frequency spectroscopic studies. Such experiments show that RM clusters interact strongly with radar frequencies: this explains the radio frequency heating and reflection studies of PMSE layers. The clusters give the low temperature in the mesosphere...

  15. The abundances of atomic carbon and carbon monoxide compared with visual extinction in the Ophiuchus molecular cloud complex

    Science.gov (United States)

    Frerking, Margaret A.; Keene, Jocelyn; Blake, Geoffrey A.; Phillips, T. G.

    1989-01-01

    Emission from the 492 GHz lines of C I have been observed toward six positions in the Ophiuchus molecular cloud complex for which accurate visual extinctions are available. The column density of C I increases with A(V) to greater than 2 x 10 to the 17th/sq cm at 100 mag, the column-averaged fractional abundance reaches a peak of about 2.2 x 10 to the -5th for A(V) in the range 4-11 mag and the column-averaged abundance ratio of C I to CO decreases with A(V) from about 1 at 2 mag to greater that about 0.03 at 100 mag. These results imply that, while C I is not the primary reservoir of gaseous carbon even at cloud edges, its fractional abundance remains high for at least 10 mag into the cloud and may be significant at even greater depths.

  16. Determination of ultra trace amounts of bismuth in biological and water samples by electrothermal atomic absorption spectrometry (ET-AAS) after cloud point extraction

    Energy Technology Data Exchange (ETDEWEB)

    Shemirani, Farzaneh; Baghdadi, Majid; Ramezani, Majid; Jamali, Mohammad Reza

    2005-04-04

    A new approach for a cloud point extraction electrothermal atomic absorption spectrometric method was used for determining bismuth. The aqueous analyte was acidified with sulfuric acid (pH 3.0-3.5). Triton X-114 was added as a surfactant and dithizone was used as a complexing agent. After phase separation at 50 deg. C based on the cloud point separation of the mixture, the surfactant-rich phase was diluted using tetrahydrofuran (THF). Twenty microliters of the enriched solution and 10 {mu}l of 0.1% (w/v) Pd(NO{sub 3}){sub 2} as chemical modifier were dispersed into the graphite tube and the analyte determined by electrothermal atomic absorption spectrometry. After optimizing extraction conditions and instrumental parameters, a preconcentration factor of 196 was obtained for a sample of only 10 ml. The detection limit was 0.02 ng ml{sup -1} and the analytical curve was linear for the concentration range of 0.04-0.60 ng ml{sup -1}. Relative standard deviations were <5%. The method was successfully applied for the extraction and determination of bismuth in tap water and biological samples (urine and hair)

  17. Application of dual-cloud point extraction for the trace levels of copper in serum of different viral hepatitis patients by flame atomic absorption spectrometry: A multivariate study

    Science.gov (United States)

    Arain, Salma Aslam; Kazi, Tasneem G.; Afridi, Hassan Imran; Abbasi, Abdul Rasool; Panhwar, Abdul Haleem; Naeemullah; Shanker, Bhawani; Arain, Mohammad Balal

    2014-12-01

    An efficient, innovative preconcentration method, dual-cloud point extraction (d-CPE) has been developed for the extraction and preconcentration of copper (Cu2+) in serum samples of different viral hepatitis patients prior to couple with flame atomic absorption spectrometry (FAAS). The d-CPE procedure was based on forming complexes of elemental ions with complexing reagent 1-(2-pyridylazo)-2-naphthol (PAN), and subsequent entrapping the complexes in nonionic surfactant (Triton X-114). Then the surfactant rich phase containing the metal complexes was treated with aqueous nitric acid solution, and metal ions were back extracted into the aqueous phase, as second cloud point extraction stage, and finally determined by flame atomic absorption spectrometry using conventional nebulization. The multivariate strategy was applied to estimate the optimum values of experimental variables for the recovery of Cu2+ using d-CPE. In optimum experimental conditions, the limit of detection and the enrichment factor were 0.046 μg L-1 and 78, respectively. The validity and accuracy of proposed method were checked by analysis of Cu2+ in certified sample of serum (CRM) by d-CPE and conventional CPE procedure on same CRM. The proposed method was successfully applied to the determination of Cu2+ in serum samples of different viral hepatitis patients and healthy controls.

  18. Application of dual-cloud point extraction for the trace levels of copper in serum of different viral hepatitis patients by flame atomic absorption spectrometry: a multivariate study.

    Science.gov (United States)

    Arain, Salma Aslam; Kazi, Tasneem G; Afridi, Hassan Imran; Abbasi, Abdul Rasool; Panhwar, Abdul Haleem; Naeemullah; Shanker, Bhawani; Arain, Mohammad Balal

    2014-12-10

    An efficient, innovative preconcentration method, dual-cloud point extraction (d-CPE) has been developed for the extraction and preconcentration of copper (Cu(2+)) in serum samples of different viral hepatitis patients prior to couple with flame atomic absorption spectrometry (FAAS). The d-CPE procedure was based on forming complexes of elemental ions with complexing reagent 1-(2-pyridylazo)-2-naphthol (PAN), and subsequent entrapping the complexes in nonionic surfactant (Triton X-114). Then the surfactant rich phase containing the metal complexes was treated with aqueous nitric acid solution, and metal ions were back extracted into the aqueous phase, as second cloud point extraction stage, and finally determined by flame atomic absorption spectrometry using conventional nebulization. The multivariate strategy was applied to estimate the optimum values of experimental variables for the recovery of Cu(2+) using d-CPE. In optimum experimental conditions, the limit of detection and the enrichment factor were 0.046μgL(-1) and 78, respectively. The validity and accuracy of proposed method were checked by analysis of Cu(2+) in certified sample of serum (CRM) by d-CPE and conventional CPE procedure on same CRM. The proposed method was successfully applied to the determination of Cu(2+) in serum samples of different viral hepatitis patients and healthy controls.

  19. Speciation of organic and inorganic selenium in selenium-enriched rice by graphite furnace atomic absorption spectrometry after cloud point extraction.

    Science.gov (United States)

    Sun, Mei; Liu, Guijian; Wu, Qianghua

    2013-11-01

    A new method was developed for the determination of organic and inorganic selenium in selenium-enriched rice by graphite furnace atomic absorption spectrometry detection after cloud point extraction. Effective separation of organic and inorganic selenium in selenium-enriched rice was achieved by sequentially extracting with water and cyclohexane. Under the optimised conditions, the limit of detection (LOD) was 0.08 μg L(-1), the relative standard deviation (RSD) was 2.1% (c=10.0 μg L(-1), n=11), and the enrichment factor for selenium was 82. Recoveries of inorganic selenium in the selenium-enriched rice samples were between 90.3% and 106.0%. The proposed method was successfully applied for the determination of organic and inorganic selenium as well as total selenium in selenium-enriched rice.

  20. Flame atomic absorption spectrometric determination of trace quantities of cadmium in water samples after cloud point extraction in Triton X-114 without added chelating agents

    Energy Technology Data Exchange (ETDEWEB)

    Afkhami, Abbas [Department of Chemistry, Faculty of Science, Bu-Ali Sina University, Hamadan (Iran, Islamic Republic of)]. E-mail: afkhami@basu.ac.ir; Madrakian, Tayyebeh [Department of Chemistry, Faculty of Science, Bu-Ali Sina University, Hamadan (Iran, Islamic Republic of); Siampour, Hajar [Department of Chemistry, Faculty of Science, Bu-Ali Sina University, Hamadan (Iran, Islamic Republic of)

    2006-11-16

    A new micell-mediated phase separation method for preconcentration of ultra-trace quantities of cadmium as a prior step to its determination by flame atomic absorption spectrometry has been developed. The method is based on the cloud point extraction (CPE) of cadmium in iodide media with Triton X-114 in the absence of any chelating agent. The optimal extraction and reaction conditions (e.g., acid concentration, iodide concentration, effect of time) were studied, and the analytical characteristics of the method (e.g., limit of detection, linear range, preconcentration, and improvement factors) were obtained. Linearity was obeyed in the range of 3-300 ng mL{sup -1} of cadmium. The detection limit of the method is 1.0 ng mL{sup -1} of cadmium. The interference effect of some anions and cations was also tested. The method was applied to the determination of cadmium in tap water, waste water, and sea water samples.

  1. Combination of cloud point extraction and flame atomic absorption spectrometry for preconcentration and determination of nickel and manganese ions in water and food samples

    Energy Technology Data Exchange (ETDEWEB)

    Arpa Sahin, Cigdem, E-mail: carpa@hacettepe.edu.tr [Hacettepe University, Chemistry Department, 06800, Beytepe, Ankara (Turkey); Efecinar, Melis; Satiroglu, Nuray [Hacettepe University, Chemistry Department, 06800, Beytepe, Ankara (Turkey)

    2010-04-15

    A simple, rapid, inexpensive, and nonpolluting cloud point extraction (CPE) technique has been improved for the preconcentration and determination of nickel and manganese. After complexation with p-nitrophenylazoresorcinol (Magneson I), the analytes could be competitively extracted in a surfactant octylphenoxy polyethoxyethanol (Triton X-114), prior to determination by flame atomic absorption spectrometry (FAAS). The effects of experimental conditions such as pH, concentration of chelating agent and surfactant, equilibration temperature and time on CPE were studied. Under the optimum conditions, preconcentration of a 25 mL sample solution permitted the detection of 2.7 ng mL{sup -1} Ni{sup 2+} and 2.9 ng mL{sup -1} Mn{sup 2+} with enrichment factors of 17 and 19 for Ni{sup 2+} and Mn{sup 2+}, respectively. The developed method was applied to the determination of trace nickel and manganese in water and food samples with satisfactory results.

  2. Application of cloud point preconcentration and flame atomic absorption spectrometry for the determination of cadmium and zinc ions in urine, blood serum and water samples

    Directory of Open Access Journals (Sweden)

    Ardeshir Shokrollahi

    2013-01-01

    Full Text Available A simple, sensitive and selective cloud point extraction procedure is described for the preconcentration and atomic absorption spectrometric determination of Zn2+ and Cd2+ ions in water and biological samples, after complexation with 3,3',3",3'"-tetraindolyl (terephthaloyl dimethane (TTDM in basic medium, using Triton X-114 as nonionic surfactant. Detection limits of 3.0 and 2.0 µg L-1 and quantification limits 10.0 and 7.0 µg L-1were obtained for Zn2+ and Cd2+ ions, respectively. Relative standard deviation was 2.9 and 3.3, and enrichment factors 23.9 and 25.6, for Zn2+ and Cd2+ ions, respectively. The method enabled determination of low levels of Zn2+ and Cd2+ ions in urine, blood serum and water samples.

  3. The Atomic-to-Molecular Transition in Galaxies. III. A New Method for Determining the Molecular Content of Primordial and Dusty Clouds

    CERN Document Server

    McKee, Christopher F

    2009-01-01

    Understanding the molecular content of galaxies is a critical problem in star formation and galactic evolution. Here we present a new method, based on a Stromgren-type analysis, to calculate the amount of HI that surrounds a molecular cloud irradiated by an isotropic radiation field. We consider both planar and spherical clouds, and H_2 formation either in the gas phase or catalyzed by dust grains. Under the assumption that the transition from atomic to molecular gas is sharp, our method gives the solution without any reference to the photodissociation cross section. We test our results for the planar case against those of a PDR code, and find typical accuracies of about 10%. Our results are also consistent with the scaling relations found in Paper I of this series, but they apply to a wider range of physical conditions. We present simple, accurate analytic fits to our results that are suitable for comparison to observations and to implementation in numerical and semi-analytic models.

  4. Cloud point extraction of palladium in water samples and alloy mixtures using new synthesized reagent with flame atomic absorption spectrometry (FAAS)

    Energy Technology Data Exchange (ETDEWEB)

    Priya, B. Krishna [Environmental Monitoring Laboratory, Department of Chemistry, S.V. University, Tirupati 517502, AP (India); Subrahmanayam, P. [Environmental Monitoring Laboratory, Department of Chemistry, S.V. University, Tirupati 517502, AP (India); Suvardhan, K. [Environmental Monitoring Laboratory, Department of Chemistry, S.V. University, Tirupati 517502, AP (India); Kumar, K. Suresh [Environmental Monitoring Laboratory, Department of Chemistry, S.V. University, Tirupati 517502, AP (India); Rekha, D. [Environmental Monitoring Laboratory, Department of Chemistry, S.V. University, Tirupati 517502, AP (India); Rao, A. Venkata [Environmental Monitoring Laboratory, Department of Chemistry, S.V. University, Tirupati 517502, AP (India); Rao, G.C. [Environmental Monitoring Laboratory, Department of Chemistry, S.V. University, Tirupati 517502, AP (India); Chiranjeevi, P. [Environmental Monitoring Laboratory, Department of Chemistry, S.V. University, Tirupati 517502, AP (India)]. E-mail: chiranjeevipattium@gmail.com

    2007-06-01

    The present paper outlines novel, simple and sensitive method for the determination of palladium by flame atomic absorption spectrometry (FAAS) after separation and preconcentration by cloud point extraction (CPE). The cloud point methodology was successfully applied for palladium determination by using new reagent 4-(2-naphthalenyl)thiozol-2yl azo chromotropic acid (NTACA) and hydrophobic ligand Triton X-114 as chelating agent and nonionic surfactant respectively in the water samples and alloys. The following parameters such as pH, concentration of the reagent and Triton X-114, equilibrating temperature and centrifuging time were evaluated and optimized to enhance the sensitivity and extraction efficiency of the proposed method. The preconcentration factor was found to be (50-fold) for 250 ml of water sample. Under optimum condition the detection limit was found as 0.067 ng ml{sup -1} for palladium in various environmental matrices. The present method was applied for the determination of palladium in various water samples, alloys and the result shows good agreement with reported method and the recoveries are in the range of 96.7-99.4%.

  5. Cloud point extraction combined with electrothermal atomic absorption spectrometry for the speciation of antimony(III) and antimony(V) in food packaging materials

    Energy Technology Data Exchange (ETDEWEB)

    Jiang Xiuming; Wen Shengping [School of Chemistry and Chemical Engineering, Henan University of Technology, South Song Shan Road No. 140, Zhengzhou City 450001 (China); Xiang Guoqiang, E-mail: xianggq@haut.edu.cn [School of Chemistry and Chemical Engineering, Henan University of Technology, South Song Shan Road No. 140, Zhengzhou City 450001 (China)

    2010-03-15

    A simple, sensitive method for the speciation of inorganic antimony by cloud point extraction combined with electrothermal atomic absorption spectrometry (ETAAS) is presented and evaluated. The method based on the fact that formation of a hydrophobic complex of antimony(III) with ammonium pyrrolidine dithiocarbamate (APDC) at pH 5.0 and subsequently the hydrophobic complex enter into surfactant-rich phase, whereas antimony(V) remained in aqueous solutions. Antimony(III) in surfactant-rich phase was analyzed by ETAAS after dilution by 0.2 mL nitric acid in methanol (0.1 M), and antimony(V) was calculated by subtracting antimony(III) from the total antimony after reducing antimony(V) to antimony(III) by L-cysteine. The main factors affecting the cloud point extraction, such as pH, concentration of APDC and Triton X-114, equilibrium temperature and incubation time, sample volume were investigated in detail. Under the optimum conditions, the detection limit (3{sigma}) of the proposed method was 0.02 ng mL{sup -1} for antimony(III), and the relative standard deviation was 7.8% (c = 1.0 ng mL{sup -1}, n = 7). The proposed method was successfully applied to speciation of inorganic antimony in the leaching solutions of different food packaging materials with satisfactory results.

  6. Molecular and Atomic Gas in the Large Magellanic Cloud II. Three-dimensional Correlation between CO and HI

    CERN Document Server

    Fukui, Y; Wong, T; Murai, M; Iritani, H; Mizuno, N; Mizuno, Y; Onishi, T; Hughes, A; Ott, J; Müller, E; Staveley-Smith, L; Kim, S

    2009-01-01

    We compare the CO J =(1-0) and HI emission in the Large Magellanic Cloud (LMC) in three dimensions, i.e. including a velocity axis in addition to the two spatial axes, with the aim of elucidating the physical connection between giant molecular clouds (GMCs) and their surrounding HI gas. The CO J =1-0 dataset is from the second NANTEN CO survey and the HI dataset is from the merged Australia Telescope Compact Array (ATCA) and Parkes Telescope surveys. The major findings of our analysis are: 1) GMCs are associated with an envelope of HI emission, 2) in GMCs [average CO intensity] is proportional to [average HI intensity]^[1.1+-0.1] and 3) the HI intensity tends to increase with the star formation activity within GMCs, from Type I to Type III. An analysis of the HI envelopes associated with GMCs shows that their average linewidth is 14 km s-1 and the mean density in the envelope is 10 cm-3. We argue that the HI envelopes are gravitationally bound by GMCs. These findings are consistent with a continual increase i...

  7. Resolving the Transition from Molecular to Atomic at 1/5 Solar Metallicity in the Small Magellanic Cloud

    Science.gov (United States)

    Jameson, Katherine E.; Bolatto, Alberto D.; Wolfire, Mark; Rubio, Monica; Camus, Rodrigo Herrera; Aff003

    At a distance of 61 kpc, the Small Magellanic Cloud (SMC) affords an absolutely unique view of the low metallicity star-forming interstellar medium, providing the nearest laboratory to study processes relevant to star formation at high redshifts. We present new ALMA 7m-array maps of CO and 12CO (2-1) for one of the four observed regions in the Southwest Bar of the SMC. These maps are the first high-resolution (~6'' ~ 1.7 pc) images of CO in a molecular cloud at 1/5 Solar metallicity. We show the structure of photodissociation regions for the first time at 1/5 Solar metallicity by combining the new ALMA data with Herschel maps of [C ii] and [O i]. We present preliminary evidence that there is extended, faint 12CO (2-1) emission near where we expect the Hi-to-H2 transition. We also compare our data to the low metallicity 3D simulations by Glover & Mac Low (2011) and Shetty et al. (2011).

  8. (Super)alkali atoms interacting with the σ electron cloud: a novel interaction mode triggers large nonlinear optical response of M@P₄ and M@C₃H₆ (M=Li, Na, K and Li₃O).

    Science.gov (United States)

    Zhao, Xingang; Yu, Guangtao; Huang, Xuri; Chen, Wei; Niu, Min

    2013-12-01

    Under high-level ab initio calculations, the geometrical structures and nonlinear optical properties of M@P₄ (M=Li, Na, K and Li₃O) and M@C₃H₆ (M=Li and Li₃O) were investigated; all were found to exhibit considerable first hyperpolarizabilities (18110, 1440, 22490, 50487, 2757 and 31776 au, respectively). The computational results revealed that when doping the (super)alkali atom M into the tetrahedral P₄ molecule, the original dual spherical aromaticity of the P₄ moiety is broken and new σ electron cloud is formed on the face of P₄ part interacting with the M atom. It was found that interaction of the (super)alkali atom with the σ electron cloud is a novel mode to produce diffuse excess electrons effectively to achieve a considerable β₀ value. Further, beyond the alkali atom, employing the superalkali unit can be a more effective approach to significantly enhance the first hyperpolarizability of the systems, due to the much lower vertical ionization potential. These results were further supported by the case of the (super)alkali atom interacting with the cyclopropane C₃H₆ molecule with its typical σ aromatic electron cloud. Moreover, the β₀ values of the M@P₄ series are nonmonotonic dependent on alkali atomic number, namely, 1440 au (M = Na) alkali atom and the interacting surface with the σ electron cloud in P4 is a crucial geometrical factor in determining their first hyperpolarizabilities. These intriguing findings will be advantageous for promoting the design of novel high-performance nonlinear optical materials.

  9. Cloud point extraction-atomic absorption spectrometry for pre-concentration and determination of cadmium in cigarette samples.

    Science.gov (United States)

    Tavallali, Hossein; Boustani, Fazlollah; Yazdandoust, Mozhdeh; Aalaei, Mehdi; Tabandeh, Mahboobeh

    2013-05-01

    A new complexing agent, 2-((2-((1H-benzo[d]imidazole-2yl)methoxy)phenoxy)methyl)-1H-benzo[d]imidazole (BIMPI), was used in cloud point extraction and applied for selective pre-concentration of trace amounts of cadmium in cigarette samples. Cadmium was complexed with BIMPI in a buffer solution (pH = 10) using Triton X-114 as surfactant and quantitatively extracted into a small volume of the surfactant-rich phase after centrifugation. Under optimized conditions (pH = 10.0, 0.8 × 10(-4) mol L(-1) BIMPI and 0.08 % (w/v) Triton X-114), calibration graph was linear in the range of 34.0-1,670.0 μg L(-1). The proposed method was applied to the determination of Cd in various cigarette (tobacco) samples which gave satisfactory results.

  10. Gamma rays from atomic and molecular gas in the large complex of clouds in Orion and Monoceros

    Science.gov (United States)

    Bloemen, J. B. G. M.; Caraveo, P. A.; Hermsen, W.; Lebrun, F.; Maddalena, R. J.; Strong, A. W.; Thaddeus, P.

    1984-01-01

    A comparison of COS-B gamma-ray observations of the large complex of interstellar clouds in Orion and Monoceros with the Columbia CO and Berkeley H I surveys of this region reveals a good correlation between gamma-ray emission and total gas distribution. The observed gamma-ray emission is explainable in terms of interactions of cosmic rays that are uniformly distributed in this region with the interstellar gas. The correlation is used as the basis of a calibration of the ratio between H2 column density and the integrated CO line intensity; the value of (2.6 + or - 1.2) X 10 to the 20th mol/sq cm K km s thereby obtained is consistent with the value derived from a similar analysis for the inner galaxy.

  11. Novel analytical reagent for the application of cloud-point preconcentration and flame atomic absorption spectrometric determination of nickel in natural water samples

    Energy Technology Data Exchange (ETDEWEB)

    Suvardhan, K. [Environmental Monitoring Laboratory, Department of Chemistry, S.V. University, AP (India); Rekha, D. [Environmental Monitoring Laboratory, Department of Chemistry, S.V. University, AP (India); Kumar, K. Suresh [Environmental Monitoring Laboratory, Department of Chemistry, S.V. University, AP (India); Prasad, P. Reddy [Environmental Monitoring Laboratory, Department of Chemistry, S.V. University, AP (India); Kumar, J. Dilip [Environmental Monitoring Laboratory, Department of Chemistry, S.V. University, AP (India); Jayaraj, B. [Department of Mathematics, S.V. University, Tirupati 517502, AP (India); Chiranjeevi, P. [Environmental Monitoring Laboratory, Department of Chemistry, S.V. University, AP (India)]. E-mail: chiranjeevipattium@gmail.com

    2007-06-01

    Cloud-point extraction was applied as a preconcentration of nickel after formation of complex with newly synthesized N-quino[8,7-b]azin-5-yl-2,3,5,6,8,9,11,12octahydrobenzo[b][1,4,7,10,13] pentaoxacyclopentadecin-15-yl-methanimine, and later determined by flame atomic absorption spectrometry (FAAS) using octyl phenoxy polyethoxy ethanol (Triton X-114) as surfactant. Nickel was complexed with N-quino[8,7-b]azin-5-yl-2,3,5,6,8,9,11,12 octahydrobenzo[b][1,4,7,10,13]pentaoxacyclopentadecin-15-yl-methanimine in an aqueous phase and was kept for 15 min in a thermo-stated bath at 40 deg. C. Separation of the two phases was accomplished by centrifugation for 15 min at 4000 rpm. The chemical variables affecting the cloud-point extraction were evaluated, optimized and successfully applied to the nickel determination in various water samples. Under the optimized conditions, the preconcentration system of 100 ml sample permitted an enhancement factor of 50-fold. The detailed study of various interferences made the method more selective. The detection limits obtained under optimal condition was 0.042 ng ml{sup -1}. The extraction efficiency was investigated at different nickel concentrations (20-80 ng ml{sup -1}) and good recoveries (99.05-99.93%) were obtained using present method. The proposed method has been applied successfully for the determination of nickel in various water samples and compared with reported method in terms of Student's t-test and variance ratio f-test which indicate the significance of present method over reported and spectrophotometric methods at 95% confidence 0011lev.

  12. Preconcentration and determination of vanadium and molybdenum in milk, vegetables and foodstuffs by ultrasonic-thermostatic-assisted cloud point extraction coupled to flame atomic absorption spectrometry.

    Science.gov (United States)

    Gürkan, Ramazan; Korkmaz, Sema; Altunay, Nail

    2016-08-01

    A new ultrasonic-thermostatic-assisted cloud point extraction procedure (UTA-CPE) was developed for preconcentration at the trace levels of vanadium (V) and molybdenum (Mo) in milk, vegetables and foodstuffs prior to determination via flame atomic absorption spectrometry (FAAS). The method is based on the ion-association of stable anionic oxalate complexes of V(V) and Mo(VI) with [9-(diethylamino)benzo[a]phenoxazin-5-ylidene]azanium; sulfate (Nile blue A) at pH 4.5, and then extraction of the formed ion-association complexes into micellar phase of polyoxyethylene(7.5)nonylphenyl ether (PONPE 7.5). The UTA-CPE is greatly simplified and accelerated compared to traditional cloud point extraction (CPE). The analytical parameters optimized are solution pH, the concentrations of complexing reagents (oxalate and Nile blue A), the PONPE 7.5 concentration, electrolyte concentration, sample volume, temperature and ultrasonic power. Under the optimum conditions, the calibration curves for Mo(VI) and V(V) are obtained in the concentration range of 3-340µgL(-1) and 5-250µgL(-1) with high sensitivity enhancement factors (EFs) of 145 and 115, respectively. The limits of detection (LODs) for Mo(VI) and V(V) are 0.86 and 1.55µgL(-1), respectively. The proposed method demonstrated good performances such as relative standard deviations (as RSD %) (≤3.5%) and spiked recoveries (95.7-102.3%). The accuracy of the method was assessed by analysis of two standard reference materials (SRMs) and recoveries of spiked solutions. The method was successfully applied into the determination of trace amounts of Mo(VI) and V(V) in milk, vegetables and foodstuffs with satisfactory results.

  13. A new protein binding pocket similarity measure based on comparison of clouds of atoms in 3D: application to ligand prediction

    Directory of Open Access Journals (Sweden)

    Zaslavskiy Mikhail

    2010-02-01

    Full Text Available Abstract Background Predicting which molecules can bind to a given binding site of a protein with known 3D structure is important to decipher the protein function, and useful in drug design. A classical assumption in structural biology is that proteins with similar 3D structures have related molecular functions, and therefore may bind similar ligands. However, proteins that do not display any overall sequence or structure similarity may also bind similar ligands if they contain similar binding sites. Quantitatively assessing the similarity between binding sites may therefore be useful to propose new ligands for a given pocket, based on those known for similar pockets. Results We propose a new method to quantify the similarity between binding pockets, and explore its relevance for ligand prediction. We represent each pocket by a cloud of atoms, and assess the similarity between two pockets by aligning their atoms in the 3D space and comparing the resulting configurations with a convolution kernel. Pocket alignment and comparison is possible even when the corresponding proteins share no sequence or overall structure similarities. In order to predict ligands for a given target pocket, we compare it to an ensemble of pockets with known ligands to identify the most similar pockets. We discuss two criteria to evaluate the performance of a binding pocket similarity measure in the context of ligand prediction, namely, area under ROC curve (AUC scores and classification based scores. We show that the latter is better suited to evaluate the methods with respect to ligand prediction, and demonstrate the relevance of our new binding site similarity compared to existing similarity measures. Conclusions This study demonstrates the relevance of the proposed method to identify ligands binding to known binding pockets. We also provide a new benchmark for future work in this field. The new method and the benchmark are available at http://cbio.ensmp.fr/paris/.

  14. Simultaneous preconcentration of cadmium and chromium(III) in water samples by cloud point extraction and their determination by flame atomic absorption spectrometry.

    Science.gov (United States)

    Meng, Lifen; Ning, Jinyan; Yang, Yaling

    2014-01-01

    A sensitive and simple method for flame atomic absorption spectrometry determination of traces of cadmium and chromium(III) species in water samples after preconcentration by cloud point extraction has been developed. A novel complex agent of alizarin complexone with cadmium (Cd) and chromium (Cr(III)) was quantitatively extracted in surface primary alcohol ethoxylate-rich phase at 33 °C. The effects of experimental conditions including pH of sample solution, concentration of chelating agent and salt, equilibration temperature and time, and foreign ions were evaluated in order to enhance sensitivity of the method. Under optimal conditions, the low limit detections were 6.7 and 3.2 μg/L, and the enrichment factors were 24 and 20 for Cd and Cr(III), respectively. The relative standard deviations were 3.8 and 2.5% for Cd and Cr(II), respectively (n = 11). The high recoveries of the spiked Cd and Cr(III) ions were obtained in the range of 90-116%. The proposed method has been successfully applied for the determination of Cd and Cr(III) in water samples.

  15. Determination of trace aluminum in biological and water samples by cloud point extraction preconcentration and graphite furnace atomic absorption spectrometry detection

    Energy Technology Data Exchange (ETDEWEB)

    Sang Hongbo [Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079 (China); Liang Pei [Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079 (China)], E-mail: liangpei@mail.ccnu.edu.cn; Du Dan [Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079 (China)

    2008-06-15

    A cloud point extraction (CPE) method for the preconcentration of trace aluminum prior to its determination by graphite furnace atomic absorption spectrometry (GFAAS) has been developed. The CPE method is based on the complex of Al(III) with 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone (PMBP), and then entrapped in non-ionic surfactant Triton X-114. PMBP was used not only as chelating reagent in CPE preconcentration, but also as chemical modifier in GFAAS determination. The main factors affecting CPE efficiency, such as pH of sample solution, concentration of PMBP and Triton X-114, equilibration temperature and time, were investigated in detail. An enrichment factor of 37 was obtained for the preconcentration of Al(III) with 10 mL solution. Under the optimal conditions, the detection limit of this method for Al(III) is 0.09 ng mL{sup -1}, and the relative standard deviation is 4.7% at 10 ng mL{sup -1} Al(III) level (n = 7). The proposed method has been applied for determination of trace amount of aluminum in biological and water samples with satisfactory results.

  16. Speciation of chromium in water samples with cloud point extraction separation and preconcentration and determination by graphite furnace atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Liang Pei [Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079 (China)], E-mail: liangpei@mail.ccnu.edu.cn; Sang Hongbo [Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079 (China)

    2008-06-15

    A novel method has been developed for the speciation of chromium in natural water samples based on cloud point extraction (CPE) separation and preconcentration, and determination by graphite furnace atomic absorption spectrometry (GFAAS). In this method, Cr(III) reacts with 1-phenyl-3-methyl-4-benzoylpyrazol-5-one (PMBP) yielding a hydrophobic complex, which then is entrapped in the surfactant-rich phase, whereas Cr(VI) remained in aqueous phase. Thus, separation of Cr(III) and Cr(VI) could be realized. Total chromium was determined after the reduction of Cr(VI) to Cr(III) by using ascorbic acid as reducing reagent. PMBP was used not only as chelating reagent in CPE procedure, but also as chemical modifier in GFAAS determination of chromium. The detection limit for Cr(III) was 21 ng L{sup -1} with an enrichment factor of 42, and the relative standard deviation was 3.5% (n = 7, c = 10 ng mL{sup -1}). The proposed method has been applied to the speciation of chromium in natural water samples with satisfactory results.

  17. An evaluation of the bioaccessibility of arsenic in corn and rice samples based on cloud point extraction and hydride generation coupled to atomic fluorescence spectrometry.

    Science.gov (United States)

    Castor, José Martín Rosas; Portugal, Lindomar; Ferrer, Laura; Hinojosa-Reyes, Laura; Guzmán-Mar, Jorge Luis; Hernández-Ramírez, Aracely; Cerdà, Víctor

    2016-08-01

    A simple, inexpensive and rapid method was proposed for the determination of bioaccessible arsenic in corn and rice samples using an in vitro bioaccessibility assay. The method was based on the preconcentration of arsenic by cloud point extraction (CPE) using o,o-diethyldithiophosphate (DDTP) complex, which was generated from an in vitro extract using polyethylene glycol tert-octylphenyl ether (Triton X-114) as a surfactant prior to its detection by atomic fluorescence spectrometry with a hydride generation system (HG-AFS). The CPE method was optimized by a multivariate approach (two-level full factorial and Doehlert designs). A photo-oxidation step of the organic species prior to HG-AFS detection was included for the accurate quantification of the total As. The limit of detection was 1.34μgkg(-1) and 1.90μgkg(-1) for rice and corn samples, respectively. The accuracy of the method was confirmed by analyzing certified reference material ERM BC-211 (rice powder). The corn and rice samples that were analyzed showed a high bioaccessible arsenic content (72-88% and 54-96%, respectively), indicating a potential human health risk.

  18. Cloud Point Extraction for the Determination of Trace Amounts of Cobalt in Water and Food Samples by Flame Atomic Absorption Spectrometry

    Directory of Open Access Journals (Sweden)

    Shangzhi Wang

    2013-01-01

    Full Text Available A cloud point extraction (CPE procedure which was developed for the separation and preconcentration of trace amounts of cobalt is combined with flame atomic absorption spectrometry (FAAS to determine trace amounts of cobalt in water and food samples. The procedure is based on the formation of the hydrophobic complex between Co(II and 4-methoxy-2-sulfo-benzenediazoaminoazo-benzene (MOSDAA followed by its extraction into a Triton X-114 surfactant-rich phase. The parameters such as pH of sample, concentrations of MOSDAA and Triton X-114, equilibrium temperature, and equilibrium time, which affect both complexation and extraction, are optimized. Under the selected optimum conditions, the preconcentration of 10.0 mL, 0.1 μg mL−1 Co(II solution results in a limit of detection of 0.47 ng mL−1 (3σ and an enrichment factor of 19. A relative standard deviation of 2.78% (,  μg mL−1 for the determination of Co(II is obtained. The proposed method was applied for the determination of trace amounts of cobalt in river water and millet samples with satisfactory results.

  19. A new cloud point extraction procedure for determination of inorganic antimony species in beverages and biological samples by flame atomic absorption spectrometry.

    Science.gov (United States)

    Altunay, Nail; Gürkan, Ramazan

    2015-05-15

    A new cloud-point extraction (CPE) for the determination of antimony species in biological and beverages samples has been established with flame atomic absorption spectrometry (FAAS). The method is based on the fact that formation of the competitive ion-pairing complex of Sb(III) and Sb(V) with Victoria Pure Blue BO (VPB(+)) at pH 10. The antimony species were individually detected by FAAS. Under the optimized conditions, the calibration range for Sb(V) is 1-250 μg L(-1) with a detection limit of 0.25 μg L(-1) and sensitive enhancement factor of 76.3 while the calibration range for Sb(III) is 10-400 μg L(-1) with a detection limit of 5.15 μg L(-1) and sensitive enhancement factor of 48.3. The precision as a relative standard deviation is in range of 0.24-2.35%. The method was successfully applied to the speciative determination of antimony species in the samples. The validation was verified by analysis of certified reference materials (CRMs).

  20. Ultra-trace determination of silver in water samples by electrothermal atomic absorption spectrometry after preconcentration with a ligand-less cloud point extraction methodology

    Energy Technology Data Exchange (ETDEWEB)

    Manzoori, Jamshid L. [Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz (Iran, Islamic Republic of)]. E-mail: manzoori@tabrizu.ac.ir; Abdolmohammad-Zadeh, Hossein [Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz (Iran, Islamic Republic of); Amjadi, Mohammad [Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz (Iran, Islamic Republic of)

    2007-06-01

    A very simple and ligand-less cloud point extraction (CPE) methodology for the preconcentration of ultra-trace amounts of silver as a prior step to its determination by electrothermal atomic absorption spectrometry (ETAAS) has been developed. The method is based on the extraction of silver at pH 9 by using non-ionic surfactant polyethyleneglycolmono-p-nonylphenylether (PONPE 7.5) without adding any chelating agent. Several important variables that affect the CPE efficiency and ETAAS signal were investigated and optimized. The preconcentration of 15 ml sample solution allowed us to achieve an enhancement factor of 60. The calibration graph using the preconcentration system was linear in the range of 5-100 ng l{sup -1} with a correlation coefficient of 0.9991. The lower limit of detection (3s) obtained in the optimal conditions was 1.2 ng l{sup -1}. The relative standard deviation (R.S.D.) for eight replicate determinations at 30 ng l{sup -1} Ag level was 4.2%. The proposed method was successfully applied to the ultra-trace determination of silver in water samples.

  1. Cloud point extraction for the determination of lead and cadmium in urine by graphite furnace atomic absorption spectrometry with multivariate optimization using Box-Behnken design

    Energy Technology Data Exchange (ETDEWEB)

    Maranhao, Tatiane de A; Martendal, Edmar; Borges, Daniel L.G.; Carasek, Eduardo [Departamento de Quimica, Universidade Federal de Santa Catarina, 88040-900, Florianopolis, SC (Brazil); Welz, Bernhard [Departamento de Quimica, Universidade Federal de Santa Catarina, 88040-900, Florianopolis, SC (Brazil); Grupo de Pesquisa em Quimica Analitica, Instituto de Quimica, Universidade Federal da Bahia, 40170-290, Salvador, BA (Brazil); Curtius, Adilson J. [Departamento de Quimica, Universidade Federal de Santa Catarina, 88040-900, Florianopolis, SC (Brazil)], E-mail: curtius@qmc.ufsc.br

    2007-09-15

    Cloud point extraction (CPE) is proposed as a pre-concentration procedure for the determination of Pb and Cd in undigested urine by graphite furnace atomic absorption spectrometry (GF AAS). Aliquots of 0.5 mL urine were acidified with HCl and the chelating agent ammonium O,O-diethyl dithiophosphate (DDTP) was added along with the non-ionic surfactant Triton X-114 at the optimized concentrations. Phase separation was achieved by heating the mixture to 50 deg. C for 15 min. The surfactant-rich phase was analyzed by GF AAS, employing the optimized pyrolysis temperatures of 900 deg. C for Pb and 800 deg. C for Cd, using a graphite tube with a platform treated with 500 {mu}g Ru as permanent modifier. The reagent concentrations for CPE (HCl, DDTP and Triton X-114) were optimized using a Box-Behnken design. The response surfaces and the optimum values were very similar for aqueous solutions and for the urine samples, demonstrating that aqueous standards submitted to CPE could be used for calibration. Detection limits of 40 and 2 ng L{sup -1} for Pb and Cd, respectively, were obtained along with an enhancement factor of 16 for both analytes. Three control urine samples were analyzed using this approach, and good agreement was obtained at a 95% statistical confidence level between the certified and determined values. Five real samples have also been analyzed before and after spiking with Pb and Cd, resulting in recoveries ranging from 97 to 118%.

  2. Preconcentration and determination of iron and copper in spice samples by cloud point extraction and flow injection flame atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Sahin, Cigdem Arpa, E-mail: carpa@hacettepe.edu.tr [Hacettepe University, Chemistry Department, 06800 Beytepe, Ankara (Turkey); Tokgoez, Ilknur; Bektas, Sema [Hacettepe University, Chemistry Department, 06800 Beytepe, Ankara (Turkey)

    2010-09-15

    A flow injection (FI) cloud point extraction (CPE) method for the determination of iron and copper by flame atomic absorption spectrometer (FAAS) has been improved. The analytes were complexed with 3-amino-7-dimethylamino-2-methylphenazine (Neutral Red, NR) and octylphenoxypolyethoxyethanol (Triton X-114) was added as a surfactant. The micellar solution was heated above 50 {sup o}C and loaded through a column packed with cotton for phase separation. Then the surfactant-rich phase was eluted using 0.05 mol L{sup -1} H{sub 2}SO{sub 4} and the analytes were determined by FAAS. Chemical and flow variables influencing the instrumental and extraction conditions were optimized. Under optimized conditions for 25 mL of preconcentrated solution, the enrichment factors were 98 and 69, the limits of detection (3s) were 0.7 and 0.3 ng mL{sup -1}, the limits of quantification (10s) were 2.2 and 1.0 ng mL{sup -1} for iron and copper, respectively. The relative standard deviation (RSD) for ten replicate measurements of 10 ng mL{sup -1} iron and copper were 2.1% and 1.8%, respectively. The proposed method was successfully applied to determination of iron and copper in spice samples.

  3. Optimization of cloud point extraction procedure with response surface methodology for quantification of iron by means of flame atomic absorption spectrometry

    Directory of Open Access Journals (Sweden)

    Abdolmohammad-Zadeh Hossein

    2013-01-01

    Full Text Available A simple micelle-mediated phase separation method has been developed for the pre-concentration of trace levels of iron as a prior step to determination by flame atomic absorption spectrometry (FAAS. The method is based on the cloud point extraction (CPE of iron using non-ionic surfactant polyethyleneglycolmono-p-nonylphenylether (PONPE 7.5 without adding any chelating agent. Several variables affecting the extraction efficiency were studied and optimized utilizing central composite design (CCD and three levels full factorial design. Under the optimum conditions, the limit of detection (LOD, limit of quantification (LOQ and pre-concentration factor were 1.5 μg L-1, 5.0 μg L-1 and 100, respectively. The relative standard deviation (RSD for six replicate determinations at 50 μg L−1 Fe(III level was 1.97%. The calibration graph was linear in the rage of 5-100 μg L-1, with a correlation coefficient of 0.9921. The developed method was validated by the analysis of two certified reference materials and applied successfully to the determination of trace amounts of Fe(III in water and rice samples.

  4. Quantification of arsenic in dialysate solution and scalp hair samples of kidney failure patients by cloud point extraction and electrothermal atomic absorption spectroscopy.

    Science.gov (United States)

    Baig, Jameel A; Kazi, Tasneem G; Arain, Mohammad Balal; Afridi, Hassan Imran; Mahar, Khalida Perveen

    2012-01-01

    A method has been developed for the determination of arsenic (As) in pharmaceutical and scalp hair samples of kidney failure patients by cloud point extraction (CPE). The scalp hair samples were subjected to microwave-assisted digestion in nitric acid-hydrogen peroxide (2 + 1, v/v). Then, dialysate and digested scalp hair solutions were preconcentrated by CPE using pyronine B as a complexing agent. The resulting complex was entrapped in nonionic surfactant (Triton X-114) prior to its determination by electrothermal atomic absorption spectroscopy. The validity of the CPE method for As was checked by analysis of a certified reference material of human hair and a standard addition method for dialysate solution. The chemical variables affecting the analytical performance of the CPE methods were studied and optimized. After optimization of the complexation and extraction conditions, a preconcentration factor of 52 was obtained for As in 10 mL of dialysate solution and acid digested samples of scalp hair. Under the optimum experimental conditions, the LOD and LOQ of As for the preconcentration of 10 mL of solution were 0.022 and 0.073 microg/L, respectively. The level of As in scalp hair samples of kidney failure patients was higher than in healthy controls.

  5. Ligandless cloud point extraction of trace amounts of palladium and rhodium in road dust samples using Span 80 prior to their determination by flame atomic absorption spectrometry

    Directory of Open Access Journals (Sweden)

    Mahmoud Roushani

    2014-01-01

    Full Text Available In this study, a procedure is developed for cloud point extraction of Pd(II and Rh(III ions in aqueous solution using Span 80 (non-ionic surfactant prior to their determination by flame atomic absorption spectroscopy. This method is based on the extraction of Pd(II and Rh(III ions at a pH of 10 using Span 80 with no chelating agent. We investigated the effect of various parameters on the recovery of the analyte ions, including pH, equilibration temperature and time, concentration of Span 80, and ionic strength. Under the best experimental conditions, the limits of detection based on 3Sb for Pd(II and Rh(III ions were 1.3 and 1.2 ng mL-1, respectively. Seven replicate determinations of a mixture of 0.5 µg mL-1 palladium and rhodium ions gave a mean absorbance of 0.058 and 0.053 with relative standard deviations of 1.8 and 1.6%, respectively. The developed method was successfully applied to the extraction and determination of the palladium and rhodium ions in road dust and standard samples and satisfactory results were obtained.

  6. Cloud point extraction and flame atomic absorption spectrometric determination of cadmium(II), lead(II), palladium(II) and silver(I) in environmental samples

    Energy Technology Data Exchange (ETDEWEB)

    Ghaedi, Mehrorang, E-mail: m_ghaedi@mail.yu.ac.ir [Chemistry Department, Yasouj University, Yasouj 75914-353 (Iran, Islamic Republic of); Shokrollahi, Ardeshir [Chemistry Department, Yasouj University, Yasouj 75914-353 (Iran, Islamic Republic of); Niknam, Khodabakhsh [Chemistry Department, Persian Gulf University, Bushehr (Iran, Islamic Republic of); Niknam, Ebrahim; Najibi, Asma [Chemistry Department, Yasouj University, Yasouj 75914-353 (Iran, Islamic Republic of); Soylak, Mustafa [Chemistry Department, University of Erciyes, 38039 Kayseri (Turkey)

    2009-09-15

    The phase-separation phenomenon of non-ionic surfactants occurring in aqueous solution was used for the extraction of cadmium(II), lead(II), palladium(II) and silver(I). The analytical procedure involved the formation of understudy metals complex with bis((1H-benzo [d] imidazol-2yl)ethyl) sulfane (BIES), and quantitatively extracted to the phase rich in octylphenoxypolyethoxyethanol (Triton X-114) after centrifugation. Methanol acidified with 1 mol L{sup -1} HNO{sub 3} was added to the surfactant-rich phase prior to its analysis by flame atomic absorption spectrometry (FAAS). The concentration of BIES, pH and amount of surfactant (Triton X-114) was optimized. At optimum conditions, the detection limits of (3 sdb/m) of 1.4, 2.8, 1.6 and 1.4 ng mL{sup -1} for Cd{sup 2+}, Pb{sup 2+}, Pd{sup 2+} and Ag{sup +} along with preconcentration factors of 30 and enrichment factors of 48, 39, 32 and 42 for Cd{sup 2+}, Pb{sup 2+}, Pd{sup 2+} and Ag{sup +}, respectively, were obtained. The proposed cloud point extraction has been successfully applied for the determination of metal ions in real samples with complicated matrix such as radiology waste, vegetable, blood and urine samples.

  7. Cloud point extraction for the determination of lead and cadmium in urine by graphite furnace atomic absorption spectrometry with multivariate optimization using Box Behnken design

    Science.gov (United States)

    Maranhão, Tatiane De A.; Martendal, Edmar; Borges, Daniel L. G.; Carasek, Eduardo; Welz, Bernhard; Curtius, Adilson J.

    2007-09-01

    Cloud point extraction (CPE) is proposed as a pre-concentration procedure for the determination of Pb and Cd in undigested urine by graphite furnace atomic absorption spectrometry (GF AAS). Aliquots of 0.5 mL urine were acidified with HCl and the chelating agent ammonium O,O-diethyl dithiophosphate (DDTP) was added along with the non-ionic surfactant Triton X-114 at the optimized concentrations. Phase separation was achieved by heating the mixture to 50 °C for 15 min. The surfactant-rich phase was analyzed by GF AAS, employing the optimized pyrolysis temperatures of 900 °C for Pb and 800 °C for Cd, using a graphite tube with a platform treated with 500 μg Ru as permanent modifier. The reagent concentrations for CPE (HCl, DDTP and Triton X-114) were optimized using a Box Behnken design. The response surfaces and the optimum values were very similar for aqueous solutions and for the urine samples, demonstrating that aqueous standards submitted to CPE could be used for calibration. Detection limits of 40 and 2 ng L- 1 for Pb and Cd, respectively, were obtained along with an enhancement factor of 16 for both analytes. Three control urine samples were analyzed using this approach, and good agreement was obtained at a 95% statistical confidence level between the certified and determined values. Five real samples have also been analyzed before and after spiking with Pb and Cd, resulting in recoveries ranging from 97 to 118%.

  8. Cloud point extraction and flame atomic absorption spectrometric determination of cadmium(II), lead(II), palladium(II) and silver(I) in environmental samples.

    Science.gov (United States)

    Ghaedi, Mehrorang; Shokrollahi, Ardeshir; Niknam, Khodabakhsh; Niknam, Ebrahim; Najibi, Asma; Soylak, Mustafa

    2009-09-15

    The phase-separation phenomenon of non-ionic surfactants occurring in aqueous solution was used for the extraction of cadmium(II), lead(II), palladium(II) and silver(I). The analytical procedure involved the formation of understudy metals complex with bis((1H-benzo [d] imidazol-2yl)ethyl) sulfane (BIES), and quantitatively extracted to the phase rich in octylphenoxypolyethoxyethanol (Triton X-114) after centrifugation. Methanol acidified with 1molL(-1) HNO(3) was added to the surfactant-rich phase prior to its analysis by flame atomic absorption spectrometry (FAAS). The concentration of BIES, pH and amount of surfactant (Triton X-114) was optimized. At optimum conditions, the detection limits of (3 sdb/m) of 1.4, 2.8, 1.6 and 1.4 ng mL(-1) for Cd(2+), Pb(2+), Pd(2+) and Ag(+) along with preconcentration factors of 30 and enrichment factors of 48, 39, 32 and 42 for Cd(2+), Pb(2+), Pd(2+) and Ag(+), respectively, were obtained. The proposed cloud point extraction has been successfully applied for the determination of metal ions in real samples with complicated matrix such as radiology waste, vegetable, blood and urine samples.

  9. Application of cloud point extraction-atomic spectrometry in the speciation analysis of metal ions%浊点萃取-原子光谱法在金属离子形态分析中的应用

    Institute of Scientific and Technical Information of China (English)

    杨利宁; 赵玲玲; 陈建荣

    2012-01-01

    Cloud point extraction, an environment friendly liquid-liquid extraction technology had been applied to trace metal determination extensively. It was reviewed the application of cloud point extraction coupled with atomic spectrometry in determination of the different forms of ions in recent years. The principle of cloud point extraction was also introduced briefly.%简要介绍了浊点萃取的原理及其与原子光谱技术的联用,综述了近十年来应用浊点萃取法分离富集、原子光谱法测定多种金属离子不同形态含量的进展,对浊点萃取与光谱法联用在测定不同形态金属离子含量方面的发展进行了展望.

  10. Cloud Point Extraction and Flame Atomic Absorption Spectrometric Determination of Lead, Cadmium and Palladium in Some Food and Biological Samples

    Directory of Open Access Journals (Sweden)

    M. Soylak

    2011-12-01

    Full Text Available The proposed method is based on the complexation of the Pb2+, Cd2+ and Pd2+ ions with 3-(1-(1-H-Indol-3-Yl-3-phenylallyl-1H-indole (IPAI at pH 8.0 in the presence of Triton X-114. The phase separation occured when micellar solution was heated at 55 ◦C. The surfactant-rich phase, diluted to 0.5 mL via 1.0 mol L−1 nitric acid in methanol was directly introduced into the nebulizer of the flame atomic absorption spectrometry (FAAS. Influence of variables such as pH, amount of ligand and Triton X-114, heating time and temperature were evaluated and optimized. The optimized enhancement factors for Pb2+, Cd2+ and Pd2+ ions were 22, 33 and 23, respectively and the detection limit (DLs was between of 1.6–2.6 µgL−1. The relative standard deviation (RSD of each ion was found to be less than 4.6% at 100 µgL−1. In addition, the calibration graphs were linear in the range of 0.01-0.22 μg mL−1 for Cd2+ ion, 0.018-0.26 μg mL−1 for Pb2+ ion and 0.02-0.27 μg mL−1 for Pd2+ ion with the correlation coefficients in the range of 0.995–0.999.

  11. Simultaneous flow injection preconcentration of lead and cadmium using cloud point extraction and determination by atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Edson Luiz [Centro de Energia Nuclear na Agricultura, Universidade de Sao Paulo, Av. Centenario, 303, CP 96, 13416-000 Piracicaba, SP (Brazil)], E-mail: edsonqmc@hotmail.com; Santos Roldan, Paulo dos [Centro de Energia Nuclear na Agricultura, Universidade de Sao Paulo, Av. Centenario, 303, CP 96, 13416-000 Piracicaba, SP (Brazil)

    2009-01-15

    A flow injection (FI) micelle-mediated separation/preconcentration procedure for the determination of lead and cadmium by flame atomic absorption spectrometry (FAAS) has been proposed. The analytes reacted with 1-(2-thiazolylazo)-2-naphthol (TAN) to form hydrophobic chelates, which were extracted into the micelles of 0.05% (w/v) Triton X-114 in a solution buffered at pH 8.4. In the preconcentration stage, the micellar solution was continuously injected into a flow system with four mini-columns packed with cotton, glass wool, or TNT compresses for phase separation. The analytes-containing micelles were eluted from the mini-columns by a stream of 3 mol L{sup -1} HCl solution and the analytes were determined by FAAS. Chemical and flow variables affecting the preconcentration of the analytes were studied. For 15 mL of preconcentrated solution, the enhancement factors varied between 15.1 and 20.3, the limits of detection were approximately 4.5 and 0.75 {mu}g L{sup -1} for lead and cadmium, respectively. For a solution containing 100 and 10 {mu}g L{sup -1} of lead and cadmium, respectively, the R.S.D. values varied from 1.6 to 3.2% (n = 7). The accuracy of the preconcentration system was evaluated by recovery measurements on spiked water samples. The method was susceptible to matrix effects, but these interferences were minimized by adding barium ions as masking agent in the sample solutions, and recoveries from spiked sample varied in the range of 95.1-107.3%.

  12. [Cloud Point extraction for determination of mercury in Chinese herbal medicine by hydride generation atomic fluorescence spectrometry with optimization using Box-Behnken design].

    Science.gov (United States)

    Wang, Mei; Li, Shan; Zhou, Jian-dong; Xu, Ying; Long, Jun-biao; Yang, Bing-yi

    2014-08-01

    Cloud point extraction (CPE) is proposed as a pre-concentration procedure for the determination of Hg in Chinese herbal medicine samples by hydride generation-atomic fluorescence spectrometry (HG-AFS). Hg2+ was reacted with dithizone to form hydrophobic chelate under the condition of pH. Using Triton X-114, as surfactant, chelate was quantitatively extracted into small volume of the surfactant-rich phase by heating the solution in a water bath for 15 min and centrifuging. Four variables including pH, dithizone concentration, Triton X-114 concentration and equilibrium temperature (T) showed the significant effect on extraction efficiency of total Hg evaluated by single-factor experiment, and Box-Behnken design and response surface method- ology were adopted to further investigate the mutual interactions between these variables and to identify their optimal values that would generate maximum extraction efficiency. The results showed that the binomial was used to fit the response to experimental levels of each variable. ALL linear, quadratic terms of four variables, and interactions between pH and Trion X-114, pH and di- thizone affected the response value(extraction efficiency) significantly at 5% level. The optimum extraction conditions were as follows: pH 5.1, Triton X-114 concentration of 1.16 g x L(-1), dithizone concentration of 4.87 mol x L(-1), and T 58.2 degrees C, the predicted value of fluorescence was 4528.74 under the optimum conditions, and the experimental value had only 2.1% difference with it. Under the conditions, fluorescence was linear to mercury concentration in the range of 1-5 microg x L(-1). The limit of detection obtained was 0.01247 microg x L(-1) with the relative standard deviations (R.S.D.) for six replicate determinations of 1.30%. The proposed method was successfully applied to determination of Hg in morindae Radix, Andrographitis and dried tangerine samples with the recoveries of 95.0%-100.0%. Apparently Box-Behnken design combined with

  13. Determination of lead, cadmium, copper, and nickel in the tonghui river of beijing, china, by cloud point extraction-high resolution continuum source graphite furnace atomic absorption spectrometry.

    Science.gov (United States)

    Ren, Ting; Zhao, Li-Jiao; Sun, Bo-Si; Zhong, Ru-Gang

    2013-11-01

    Heavy metal contamination of water has become an important problem in recent years. Most hazardous heavy metals exist in environmental water in trace or ultra-trace amounts, which requires establishing highly sensitive analytical methods. In this research, quantitative analyses were performed using high-resolution continuum source graphite furnace atomic absorption spectrometry combined with cloud point extraction (CPE) to determine Pb, Cd, Cu, and Ni levels in environmental surface water. By optimizing the CPE conditions, the enrichment factors were 29 for Pb, Cd, and Cu and 25 for Ni. The limits of detection (LOD) were 0.080, 0.010, 0.035, and 0.014 μg L for Pb, Cd, Cu, and Ni, respectively. The sensitivity of the method is comparable with those reported in previous investigations using various methods and improves outcome by 2 to 3 orders of magnitude compared with the LODs of the current national standard methods of China. Our method was used to determine Pb, Cd, Cu, and Ni in 55 water samples collected from the Tonghui River, which is the principal river in the urban area of Beijing, China. The results indicated that the distributions of the four heavy metals in the Tonghui River were related with the environments. The levels of Pb and Ni exhibit increasing trends along the river from upstream to downstream possibly due to the existence of some chemical factories in the downstream area. Lead, Cd, Cu, and Ni averaged 13.9, 0.8, 46.8, and 38.5%, respectively, of the total amount of the determined heavy metals. The levels of the four heavy metals conformed to the Environmental Quality Standards for Surface Water (Grade I) of China. This work provides a reliable quantitative method to determine trace-amount heavy metals in water, which lays a foundation for establishing standards and regulations for environmental water protection.

  14. Simultaneous determination of antimony and boron in beverage and dairy products by flame atomic absorption spectrometry after separation and pre-concentration by cloud-point extraction.

    Science.gov (United States)

    Altunay, Nail; Gürkan, Ramazan

    2016-01-01

    A new cloud-point extraction (CPE) method was developed for the pre-concentration and simultaneous determination of Sb(III) and B(III) by flame atomic absorption spectrometry (FAAS). The method was based on complexation of Sb(III) and B(III) with azomethine-H in the presence of cetylpyridinium chloride (CPC) as a signal-enhancing agent, and then extraction into the micellar phase of Triton X-114. Under optimised conditions, linear calibration was obtained for Sb(III) and B(III) in the concentration ranges of 0.5-180 and 2.5-600 μg l(-1) with LODs of 0.15 and 0.75 μg l(-1), respectively. Relative standard deviations (RSDs) (25 and 100 μg l(-1) of Sb(III) and B(III), n = 6) were in a range of 2.1-3.8% and 1.9-2.3%, respectively. Recoveries of spiked samples of Sb(III) and B(III) were in the range of 98-103% and 99-102%, respectively. Measured values for Sb and B in three standard reference materials were within the 95% confidence limit of the certified values. Also, the method was used for the speciation of inorganic antimony. Sb(III), Sb(V) and total Sb were measured in the presence of excess boron before and after pre-reduction with an acidic mixture of KI-ascorbic acid. The method was successfully applied to the simultaneous determination of total Sb and B in selected beverage and dairy products.

  15. On-line cloud point extraction combined with electrothermal vaporization inductively coupled plasma atomic emission spectrometry for the speciation of inorganic antimony in environmental and biological samples

    Energy Technology Data Exchange (ETDEWEB)

    Li Yingjie [Department of Chemistry, Wuhan University, Wuhan 430072 (China); Hu Bin [Department of Chemistry, Wuhan University, Wuhan 430072 (China)]. E-mail: binhu@whu.edu.cn; Jiang Zucheng [Department of Chemistry, Wuhan University, Wuhan 430072 (China)

    2006-08-25

    A new method for the determination of inorganic Sb species by on-line cloud point extraction combined with electrothermal vaporization inductively coupled plasma atomic emission spectrometry (ETV-ICP-AES) is presented and evaluated. The method is based on the complexation of Sb(III) with pyrrolidine dithiocarbamate (PDC) which form an hydrophobic complex at pH 5.5 and subsequently enter surfactant-rich phase at pH 5.5, whereas Sb(V) remained in aqueous solutions. The preconcentration step is mediated by micelles of the non-ionic surfactant Triton X-114 with ammonium pyrrolidine dithiocarbamate (APDC). The micellar system containing the complex was loaded into the FIA manifold at a flow rate of 2.5 mL min{sup -1}, and the surfactant-rich phase was retained in a microcolumn packed with absorbent cotton, at pH 5.5. After the surfactant-rich phase was eluted with 100 {mu}L acetonitrile, it was determined by ETV-ICP-AES. Sb(V) is reduced to Sb(III) by L-cysteine prior to determined total Sb, and its assay is based on subtracting Sb(III) from total antimony. The main factors affecting separation/preconcentration and the vaporization behavior of analyte in graphite tube were investigated in detail. Under the optimized conditions, the precision relative standard deviation (R.S.D.) for eight replicate measurements of 0.2 {mu}g mL{sup -1} Sb(III) was 4.3%. The apparent concentration factor, which is defined as the concentration ratio of the analyte in the final diluted surfactant-rich extract ready for ETV-ICP-AES detection and in the initial solution, was 872 for Sb(III). The limit of detection (LOD) for Sb(III) was 0.09 {mu}g L{sup -1}. The proposed method was successfully applied for the speciation of inorganic antimony in different water samples and urine sample with satisfactory results.

  16. Molecular Cloud Evolution

    CERN Document Server

    Vazquez-Semadeni, Enrique

    2010-01-01

    I describe the scenario of molecular cloud (MC) evolution that has emerged over the past decade or so. MCs can start out as cold atomic clouds formed by compressive motions in the warm neutral medium (WNM) of galaxies. Such motions can be driven by large-scale instabilities, or by local turbulence. The compressions induce a phase transition to the cold neutral medium (CNM) to form growing cold atomic clouds, which in their early stages may constitute thin CNM sheets. Several dynamical instabilities soon destabilize a cloud, rendering it turbulent. For solar neighborhood conditions, a cloud is coincidentally expected to become molecular, magnetically supercritical, and gravitationally dominated at roughly the same column density, $N \\sim 1.5 \\times 10^21 \\psc \\approx 10 \\Msun$ pc$^{-2}$. At this point, the cloud begins to contract gravitationally. However, before its global collapse is completed ($\\sim 10^7$ yr later), the nonlinear density fluctuations within the cloud, which have shorter local free-fall time...

  17. Search Cloud

    Science.gov (United States)

    ... of this page: https://medlineplus.gov/cloud.html Search Cloud To use the sharing features on this ... of Top 110 zoster vaccine Share the MedlinePlus search cloud with your users by embedding our search ...

  18. A green and efficient procedure for the preconcentration and determination of cadmium, nickel and zinc from freshwater, hemodialysis solutions and tuna fish samples by cloud point extraction and flame atomic absorption spectrometry.

    Science.gov (United States)

    Galbeiro, Rafaela; Garcia, Samara; Gaubeur, Ivanise

    2014-04-01

    Cloud point extraction (CPE) was used to simultaneously preconcentrate trace-level cadmium, nickel and zinc for determination by flame atomic absorption spectrometry (FAAS). 1-(2-Pyridilazo)-2-naphthol (PAN) was used as a complexing agent, and the metal complexes were extracted from the aqueous phase by the surfactant Triton X-114 ((1,1,3,3-tetramethylbutyl)phenyl-polyethylene glycol). Under optimized complexation and extraction conditions, the limits of detection were 0.37μgL(-1) (Cd), 2.6μgL(-1) (Ni) and 2.3μgL(-1) (Zn). This extraction was quantitative with a preconcentration factor of 30 and enrichment factor estimated to be 42, 40 and 43, respectively. The method was applied to different complex samples, and the accuracy was evaluated by analyzing a water standard reference material (NIST SRM 1643e), yielding results in agreement with the certified values.

  19. Determination of Trace Cadmium in Water by Atomic Absorption Spectrometry after Cloud Point Extraction%浊点萃取-原子吸收法测定水中微量的镉

    Institute of Scientific and Technical Information of China (English)

    刘晓佳; 高玉华; 乐文俊

    2011-01-01

    A new atomic absorption spectrometry after cloud point extraction method for the determination of trace cadmium was developed.The method was based on the fact of cloud-point extracted chelate engendered by 5-Br-PADAP and cadmium.The linear range for the determination of Cd2+ was cCd(Ⅱ)=0.25~4.00 μg/L and the detection limit found was LCd(Ⅱ)=6.7 μg/L and RSD(n=11) was 2.7%.The values of recovery of Cd in natural water samples were 98.5%~102.3%.%基于5-Br-PADAP与镉形成稳定的螯合物能被TritonX-114浊点萃取的事实,建立了浊点萃取-原子吸收法测定水中微量的镉的新方法。镉的浓度在0.25~4.00μg/mL内呈线性,检测限为6.7μg/L;相对标准偏差(n=11)为2.7%,加标回收率为98.5%~102.3%。

  20. Determination of Trace Lead in Water by Atomic Absorption Spectrometry after Cloud Point Extraction%浊点萃取-原子吸收法测定水中微量的铅

    Institute of Scientific and Technical Information of China (English)

    高中荣

    2012-01-01

    基于5-Br-PADAP与铅形成稳定的螯合物能被TritonX-114浊点萃取的事实,建立了浊点萃取-原子吸收法测定水中微量的铅的新方法。铅的浓度在0~30μg/mL内呈线性,检测限为1.7 ng/mL;相对标准偏差(n=11)为2.7%,加标回收率为97.5%~102.5%。%A new atomic absorption spectrometry after cloud point extraction method for the determination of trace lead was developed.The method was based on the fact of cloud-point extracted chelate engendered by 5-Br-PADAP and lead.The linear range for the determination of Pb2+ found was C(Pb(Ⅱ))=0~30 μg/mL and the detection limit found was L(Pb(Ⅱ))=1.7 ng/mL and RSD(n=11) found was 2.7 %.The values of recovery of Cd in natural water samples were ranged from 97.5 % to 102.5 %.

  1. The use of rapidly synergistic cloud point extraction for the separation and preconcentration of trace amounts of Ni (II) ions from food and water samples coupling with flame atomic absorption spectrometry determination.

    Science.gov (United States)

    Rahnama, Reyhaneh; Najafi, Marzieh

    2016-03-01

    A novel improved preconcentration method known as rapidly synergistic cloud point extraction (RS-CPE) was established for nickel preconcentration and determination prior to its determination by flame atomic absorption spectrometry. In this work, the traditional CPE pattern was changed and greatly simplified in order to be applicable in metal extraction and detection. This method was accomplished in room temperature in 1 min. Non-ionic surfactant Triton X-114 was used as extractant. Octanol worked as cloud point revulsant and synergic reagent. The various parameters affecting the extraction and preconcentration of nickel such as sample pH, 2,2'-Furildioxime concentration, amounts of octanol, amounts of Triton X-114, type of diluting solvent, extraction time, and ionic strength were investigated and optimized. Under optimal conditions, the calibration curve showed an excellent linearity in the concentration range of 2-200 μg L(-1), and the limit of detection was 0.6 μg L(-1) for nickel. The developed method was successfully applied for the determination of nickel in food and water samples. The results showed that, the proposed method can be used as a cheap, rapid, and efficient method for the extraction and preconcentration of nickel from real samples.

  2. Cloud Governance

    DEFF Research Database (Denmark)

    Berthing, Hans Henrik

    Denne præsentation beskriver fordele og værdier ved anvendelse af Cloud Computing. Endvidere inddrager resultater fra en række internationale analyser fra ISACA om Cloud Computing.......Denne præsentation beskriver fordele og værdier ved anvendelse af Cloud Computing. Endvidere inddrager resultater fra en række internationale analyser fra ISACA om Cloud Computing....

  3. Cloud optics

    CERN Document Server

    Kokhanovsky, A

    2006-01-01

    Clouds affect the climate of the Earth, and they are an important factor in the weather. Therefore, their radiative properties must be understood in great detail. This book summarizes current knowledge on cloud optical properties, for example their ability to absorb, transmit, and reflect light, which depends on the clouds' geometrical and microphysical characteristics such as sizes of droplets and crystals, their shapes, and structures. In addition, problems related to the image transfer through clouds and cloud remote sensing are addressed in this book in great detail. This book can be an im

  4. Dimensional reduction in Bose-Einstein condensed clouds of atoms confined in tight potentials of any geometry and any interaction strength

    CERN Document Server

    Sandin, P; Gulliksson, M; Smyrnakis, J; Magiropoulos, M; Kavoulakis, G M

    2016-01-01

    Motivated by numerous experiments on Bose-Einstein condensed atoms which have been performed in tight trapping potentials of various geometries (elongated and/or toroidal/annular), we develop a general method which allows us to reduce the corresponding three-dimensional Gross-Pitaevskii equation for the order parameter into an effectively one-dimensional equation, taking into account the interactions (i.e., treating the width of the transverse profile variationally) and the curvature of the trapping potential. As an application of our model we consider atoms which rotate in a toroidal trapping potential. We evaluate the state of lowest energy for a fixed value of the angular momentum within various approximations of the effectively one-dimensional model and compare our results with the full solution of the three-dimensional problem, thus getting evidence for the accuracy of our model.

  5. Dimensional reduction in Bose-Einstein condensed clouds of atoms confined in tight potentials of any geometry and any interaction strength

    Science.gov (United States)

    Sandin, P.; Ögren, M.; Gulliksson, M.; Smyrnakis, J.; Magiropoulos, M.; Kavoulakis, G. M.

    2017-01-01

    Motivated by numerous experiments on Bose-Einstein condensed atoms which have been performed in tight trapping potentials of various geometries [elongated and/or toroidal (annular)], we develop a general method which allows us to reduce the corresponding three-dimensional Gross-Pitaevskii equation for the order parameter into an effectively one-dimensional equation, taking into account the interactions (i.e., treating the width of the transverse profile variationally) and the curvature of the trapping potential. As an application of our model we consider atoms which rotate in a toroidal trapping potential. We evaluate the state of lowest energy for a fixed value of the angular momentum within various approximations of the effectively one-dimensional model and compare our results with the full solution of the three-dimensional problem, thus getting evidence for the accuracy of our model.

  6. Antarctic clouds

    OpenAIRE

    Lachlan-Cope, Tom

    2010-01-01

    Sensitivity studies with global climate models show that, by their influence on the radiation balance, Antarctic clouds play a major role in the climate system, both directly at high southern latitudes and indirectly globally, as the local circulation changes lead to global teleconnections. Unfortunately, observations of cloud distribution in the Antarctic are limited and often of low quality because of the practical difficulty in observing clouds in the harsh Antarctic environment. The best ...

  7. Determination of trace amount of thallium in water samples by electrothermal atomic absorption spectrometry with cloud point extraction%浊点萃取电热原子吸收光谱法测定水中痕量铊

    Institute of Scientific and Technical Information of China (English)

    陈海婷; 陈建国; 林力; 金献忠; 魏丹毅

    2009-01-01

    Cloud point extraction (CPE) has been used for pre-concentration of trace amount of thallium in water samples after the formation of a complex with ammonium pyrrolidine dithiocarbamate, and then analysed by electrothermal absorption spectrometry (ETAAS) using octylphenoxypolyethoxyethanol (Triton X-114) as a surfactant. The effects of experimental conditions on cloud point extraction and atomization processes were optimized carefully. Under the optimum conditions, the limit of detection was 0.07 μg/L (3a) , the relative standard deviation was found to be 3.6% for a sample containing 4.0 μg/L Tl(Ⅲ) (n=7) . The recoveries was ranged from 93% to 106% , and the preconcentra-tion factor was 31. The method has been successfully applied to the determination of trace amount of thallium in tap and river water samples, and the satisfactory recoveries have been obtained.%采用吡咯烷基二硫代氨基甲酸铵(APDC)为螯合剂, Triton X-114作为表面活性剂, 建立了浊点萃取预富集电热原子吸收光谱法测定水中痕量铊的方法. 在优化的实验条件下, 方法的检出限可达0.07 μg/L, 相对标准偏差为3.6% (4 μg/L, n=7), 加标回收率为93%~106%, 富集倍率为31. 该方法成功应用于自来水和河水中痕量铊的测定.

  8. Determination of trace copper in plastic by cloud point extraction-atomic absorption spectrometry%浊点萃取-原子吸收光谱法测定塑料中的痕量铜

    Institute of Scientific and Technical Information of China (English)

    黄海霞; 王秀峰; 吴旭宇; 肖慈燕

    2013-01-01

    A novel method of cloud point extraction-atomic absorption spectrometry based on using PAN as a complexant and Triton X-100 as an extractant, was developed for determination of copper in food preservation. The effects of the pH of solution, concentrations of complexant and surfactant, equilibrium temperature and time on the efficiency of cloud point extraction have been systematically examined. Under the optimized conditions, the linear equation was Y -0. 1049Z +0. 0016, the correlation coefficient was 0. 9988, the detection limit was 0. 7 μg/L the relative standard deviation was 2. 3% , and the enrichment factor was 15. This method was applied to the determination of trace copper in plastic products, and the recovery were 97. 5% ~101. 9%.%建立了以1-(2-吡啶偶氮)-2-萘酚(PAN)为络合剂、Triton X-100为表面活性剂的浊点萃取-原子吸收光谱法测定痕量铜的分析方法.探讨了溶液的pH、络合剂和表面活性剂用量、平衡温度和平衡时间等因素对浊点萃取的影响.最佳条件下,线性方程为Y=0.1049X +0.0016,相关系数为0.9988,检出限为0.7 μg/L,相对偏差为2.3%,富集倍数为15倍.用该方法对几种塑料制品中的痕量铜进行测定,回收率为97.5% ~ 101.9%.

  9. Cloud point extraction and flame atomic absorption spectrometric determination of trace lead in freshwater fish%浊点萃取-火焰原子吸收光谱法测定淡水鱼中痕量铅

    Institute of Scientific and Technical Information of China (English)

    王秀峰; 李龙; 张春丽; 林朋; 崔书亚

    2012-01-01

    采用以双硫腙为络合剂、Triton X- 100为表面活性剂的新型浊点萃取体系富集淡水鱼中的痕量铅,并用火焰原子吸收光谱法对其进行测定.探讨了溶液pH、表面活性剂浓度、络合剂用量、平衡温度、平衡时间等对浊点萃取及测定灵敏度的影响,优化了实验条件.在最佳条件下测得铅的检出限为0.090μg/L,校准曲线相关系数为0.9999.该方法已用于淡水鱼中痕量铅的测定.%A new cloud point extraction-flame atomic absorption spectrometric method has been developed to determine trace lead. Dithizone was selected as the complex reagent and Triton X - 100 as the surfactant. Effects of pH, concentrations of surfactant and complex reagent, equilibrium temperature and time on the efficiency and sensitivity of cloud point extraction were investigated. Under optimal conditions, the calibration curve was linear over the concentration range of 0. 1 - 60μg/L with correlation coefficient of 0. 9999 and detection limit of 0. 090 μg/L. The present method was applied to the determination of trace lead in freshwater fish samples with satisfactory results.

  10. Cloud Computing

    CERN Document Server

    Antonopoulos, Nick

    2010-01-01

    Cloud computing has recently emerged as a subject of substantial industrial and academic interest, though its meaning and scope is hotly debated. For some researchers, clouds are a natural evolution towards the full commercialisation of grid systems, while others dismiss the term as a mere re-branding of existing pay-per-use technologies. From either perspective, 'cloud' is now the label of choice for accountable pay-per-use access to third party applications and computational resources on a massive scale. Clouds support patterns of less predictable resource use for applications and services a

  11. Simultaneous preconcentration of copper and mercury in water samples by cloud point extraction and their determination by inductively coupled plasma atomic emission spectrometry

    Science.gov (United States)

    Shoaee, Hamta; Roshdi, Mina; Khanlarzadeh, Nasibeh; Beiraghi, Asadollah

    2012-12-01

    A cloud-point extraction process coupled to ICP-OES by using 3-nitro benzaldehyde thiosemicarbazone (3-NBT) as complexing agent was developed for the simultaneous preconcentration and determination of copper and mercury in water samples. The variables affecting the complexation and extraction steps were optimized. Under the optimum conditions (i.e. 1.5 × 10-5 mol L-1 ligand, 0.3% (v/v) Triton X-114, 55 °C equilibrium temperature, incubation time of 30 min) the calibration graphs were linear in the range of 5-120 and 10-100 ng mL-1 with enhancement factor of 82.7 and 51.3 for Cu2+ and Hg2+, respectively. The preconcentration factors were 28.6 in both cases and detection limits were obtained 0.48 for Cu and 1.1 ng mL-1 for Hg. The precisions (R.S.D.%) for five replicate determinations at 50 ng mL-1 of copper and mercury were better than 1.8% and 3.2%, respectively. The accuracy of the proposed method is validated by analyzing a certified reference material of water (RTC-QCI-049) with satisfactory results. Finally, the proposed method was utilized successfully for the determination of copper and mercury in surface water (river), tap water and bottled mineral water samples.

  12. Simultaneous preconcentration of copper and mercury in water samples by cloud point extraction and their determination by inductively coupled plasma atomic emission spectrometry.

    Science.gov (United States)

    Shoaee, Hamta; Roshdi, Mina; Khanlarzadeh, Nasibeh; Beiraghi, Asadollah

    2012-12-01

    A cloud-point extraction process coupled to ICP-OES by using 3-nitro benzaldehyde thiosemicarbazone (3-NBT) as complexing agent was developed for the simultaneous preconcentration and determination of copper and mercury in water samples. The variables affecting the complexation and extraction steps were optimized. Under the optimum conditions (i.e. 1.5×10(-5) mol L(-1) ligand, 0.3% (v/v) Triton X-114, 55 °C equilibrium temperature, incubation time of 30 min) the calibration graphs were linear in the range of 5-120 and 10-100 ng mL(-1) with enhancement factor of 82.7 and 51.3 for Cu(2+) and Hg(2+), respectively. The preconcentration factors were 28.6 in both cases and detection limits were obtained 0.48 for Cu and 1.1 ng mL(-1) for Hg. The precisions (R.S.D.%) for five replicate determinations at 50 ng mL(-1) of copper and mercury were better than 1.8% and 3.2%, respectively. The accuracy of the proposed method is validated by analyzing a certified reference material of water (RTC-QCI-049) with satisfactory results. Finally, the proposed method was utilized successfully for the determination of copper and mercury in surface water (river), tap water and bottled mineral water samples.

  13. Determination of copper after cloud point extraction by flame atomic absorption spectrometry%浊点萃取-火焰原子吸收光谱法测定痕量铜

    Institute of Scientific and Technical Information of China (English)

    王尚芝; 孟双明; 关翠林; 刘月成

    2013-01-01

    A method for the determination of trace copper by flame atomic absorption spectrometry after cloud point extraction was proposed. The analyte was complexd with 2-sulfo -4-methoxy-benzenediazoaminoazobenzene (MOSDAA) and Trition X-114 was added as a nonionic surfactant. The complex formed was extracted into the phase of surfactant, then copper in the complex was determined by flame atomic absorption spectrometry. The effects of experimental conditions such as pH, chelating agent and surfactant, equilibration temperature on cloud point extraction were studied. Under the optimum conditions, the detection limit was 1.1 ng/mL (3σ)for copper, and relative standard deviation was 1.91 % (n =6). The proposed method has been applied to the determination of trace copper in millet and water with satisfactory results.%2-磺酸基-4-甲氧基苯基重氮氨基偶氮苯(MOSDAA)和Cu (Ⅱ)反应生成疏水性络合物后,被萃取到Triton X-114非离子表面活性剂胶束相中,火焰原子吸收光谱法测定其中的铜,建立了浊点萃取预富集-火焰原子吸收光谱法测定铜的方法.反应体系的pH、MOSDAA和Triton X-114的浓度、平衡温度及时间等实验条件被优化.在选择的实验条件下,方法的检出限为1.1 ng/mL(3σ),对浓度为0.1 μg/mL的Cu (Ⅱ)溶液平行测定6次,相对标准偏差为1.9%.方法已用于小米和水样中痕量铜的测定.

  14. Managing Clouds in Cloud Platforms

    CERN Document Server

    Ahmat, Kamal A

    2010-01-01

    Managing cloud services is a fundamental challenge in todays virtualized environments. These challenges equally face both providers and consumers of cloud services. The issue becomes even more challenging in virtualized environments that support mobile clouds. Cloud computing platforms such as Amazon EC2 provide customers with flexible, on demand resources at low cost. However, they fail to provide seamless infrastructure management and monitoring capabilities that many customers may need. For instance, Amazon EC2 doesn't fully support cloud services automated discovery and it requires a private set of authentication credentials. Salesforce.com, on the other hand, do not provide monitoring access to their underlying systems. Moreover, these systems fail to provide infrastructure monitoring of heterogenous and legacy systems that don't support agents. In this work, we explore how to build a cloud management system that combines heterogeneous management of virtual resources with comprehensive management of phys...

  15. Cloud Computing

    CERN Document Server

    Mirashe, Shivaji P

    2010-01-01

    Computing as you know it is about to change, your applications and documents are going to move from the desktop into the cloud. I'm talking about cloud computing, where applications and files are hosted on a "cloud" consisting of thousands of computers and servers, all linked together and accessible via the Internet. With cloud computing, everything you do is now web based instead of being desktop based. You can access all your programs and documents from any computer that's connected to the Internet. How will cloud computing change the way you work? For one thing, you're no longer tied to a single computer. You can take your work anywhere because it's always accessible via the web. In addition, cloud computing facilitates group collaboration, as all group members can access the same programs and documents from wherever they happen to be located. Cloud computing might sound far-fetched, but chances are you're already using some cloud applications. If you're using a web-based email program, such as Gmail or Ho...

  16. Large molecules in diffuse interstellar clouds

    NARCIS (Netherlands)

    Lepp, S.; Dalgarno, A.; Dishoeck, van E.F.; Black, J.H.

    1988-01-01

    The effects of the presence of a substantial component of large molecules on the chemistry of diffuse molecular clouds are explored, and detailed models of the zeta Persei and zeta Ophiuchi clouds are constructed. The major consequence is a reduction in the abundances of singly charged atomic specie

  17. Steerable optical tweezers for ultracold atom studies

    OpenAIRE

    Roberts, Kris O.; McKellar, Thomas; Fekete, Julia; Rakonjac, Ana; Deb, Amita B.; Kjærgaard, Niels

    2013-01-01

    We report on the implementation of an optical tweezer system for controlled transport of ultracold atoms along a narrow, static confinement channel. The tweezer system is based on high-efficiency acousto-optical deflectors and offers two-dimensional control over beam position. This opens up the possibility for tracking the transport channel when shuttling atomic clouds along the guide, forestalling atom spilling. Multiple clouds can be tracked independently by time-shared tweezer beams addres...

  18. Cloud point extraction of copper, lead, cadmium, and iron using 2,6-diamino-4-phenyl-1,3,5-triazine and nonionic surfactant, and their flame atomic absorption spectrometric determination in water and canned food samples.

    Science.gov (United States)

    Citak, Demirhan; Tuzen, Mustafa

    2012-01-01

    A cloud point extraction procedure was optimized for the separation and preconcentration of lead(II), cadmium(II), copper(II), and iron(III) ions in various water and canned food samples. The metal ions formed complexes with 2,6-diamino-4-phenyl-1,3,5-triazine that were extracted by surfactant-rich phases in the nonionic surfactant Triton X-114. The surfactant-rich phase was diluted with 1 M HNO3 in methanol prior to its analysis by flame atomic absorption spectrometry. The parameters affecting the extraction efficiency of the proposed method, such as sample pH, complexing agent concentration, surfactant concentration, temperature, and incubation time, were optimized. LOD values based on three times the SD of the blank (3Sb) were 0.38, 0.48, 1.33, and 1.85 microg/L for cadmium(II), copper(II), lead(II), and iron(III) ions, respectively. The precision (RSD) of the method was in the 1.86-3.06% range (n=7). Validation of the procedure was carried out by analysis of National Institute of Standards and Technology Standard Reference Material (NIST-SRM) 1568a Rice Flour and GBW 07605 Tea. The method was applied to water and canned food samples for determination of metal ions.

  19. A new ultrasonic-assisted cloud-point-extraction procedure for pre-concentration and determination of ultra-trace levels of copper in selected beverages and foods by flame atomic absorption spectrometry.

    Science.gov (United States)

    Altunay, Nail; Gürkan, Ramazan; Orhan, Ulaş

    2015-01-01

    A new ultrasonic-assisted cloud-point-extraction (UA-CPE) method was developed for the pre-concentration of Cu(II) in selected beverage and food samples prior to flame atomic absorption spectrometric (FAAS) analysis. For this purpose, Safranin T was used as an ion-pairing reagent based on charge transfer in the presence of oxalate as the primary chelating agent at pH 10. Non-ionic surfactant, poly(ethyleneglycol-mono-p-nonylphenylether) (PONPE 7.5) was used as an extracting agent in the presence of NH4Cl as the salting out agent. The variables affecting UA-CPE efficiency were optimised in detail. The linear range for Cu(II) at pH 10 was 0.02-70 µg l(-)(1) with a very low detection limit of 6.10 ng l(-)(1), while the linear range for Cu(I) at pH 8.5 was 0.08-125 µg l(-)(1) with a detection limit of 24.4 ng l(-)(1). The relative standard deviation (RSD %) was in the range of 2.15-4.80% (n = 5). The method was successfully applied to the quantification of Cu(II), Cu(I) and total Cu in selected beverage and food samples. The accuracy of the developed method was demonstrated by the analysis of two standard reference materials (SRMs) as well as recoveries of spiked samples.

  20. Securing Cloud from Cloud Drain

    Directory of Open Access Journals (Sweden)

    Niva Das

    2014-09-01

    Full Text Available Today, in the world of communication, connected systems is growing at a rapid pace. To accommodate this growth the need for computational power and storage is also increasing at a similar rate. Companies are investing a large amount of resources in buying, maintaining and ensuring availability of the system to their customers. To mitigate these issues, cloud computing is playing a major role [1]. The underlying concept of cloud computing dates back to the ‘50s but the term entering into widespread usage can be traced to 2006 when Amazon.com announced the Elastic Compute Cloud. In this paper, we will discuss about cloud security approaches. We have used the term “CloudDrain” to define data leakage in case of security compromise.

  1. Cloud point extraction for determination of lead in blood samples of children, using different ligands prior to analysis by flame atomic absorption spectrometry: A multivariate study

    Energy Technology Data Exchange (ETDEWEB)

    Shah, Faheem, E-mail: shah_ceac@yahoo.com [National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro 76080 (Pakistan); Kazi, Tasneem Gul, E-mail: tgkazi@yahoo.com [National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro 76080 (Pakistan); Afridi, Hassan Imran, E-mail: hassanimranafridi@yahoo.com [National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro 76080 (Pakistan); Naeemullah, E-mail: khannaeemullah@ymail.com [National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro 76080 (Pakistan); Arain, Muhammad Balal, E-mail: bilal_ku2004@yahoo.com [Department of Chemistry, University of Science and Technology, Bannu, KPK (Pakistan); Baig, Jameel Ahmed, E-mail: jab_mughal@yahoo.com [National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro 76080 (Pakistan)

    2011-09-15

    Highlights: {yields} Trace levels of lead in blood samples of healthy children and with different kidney disorders {yields} Pre-concentration of Pb{sup +2} in acid digested blood samples after chelating with two complexing reagents. {yields} Multivariate technique was used for screening of significant factors that influence the CPE of Pb{sup +2} {yields} The level of Pb{sup +2} in diseased children was significantly higher than referents of same age group. - Abstract: The phase-separation phenomenon of non-ionic surfactants occurring in aqueous solution was used for the extraction of lead (Pb{sup 2+}) from digested blood samples after simultaneous complexation with ammonium pyrrolidinedithiocarbamate (APDC) and diethyldithiocarbamate (DDTC) separately. The complexed analyte was quantitatively extracted with octylphenoxypolyethoxyethanol (Triton X-114). The multivariate strategy was applied to estimate the optimum values of experimental factors. Acidic ethanol was added to the surfactant-rich phase prior to its analysis by flame atomic absorption spectrometer (FAAS). The detection limit value of Pb{sup 2+} for the preconcentration of 10 mL of acid digested blood sample was 1.14 {mu}g L{sup -1}. The accuracy of the proposed methods was assessed by analyzing certified reference material (whole blood). Under the optimized conditions of both CPE methods, 10 mL of Pb{sup 2+} standards (10 {mu}g L{sup -1}) complexed with APDC and DDTC, permitted the enhancement factors of 56 and 42, respectively. The proposed method was used for determination of Pb{sup 2+} in blood samples of children with kidney disorders and healthy controls.

  2. Determination of nickel in blood and serum samples of oropharyngeal cancer patients consumed smokeless tobacco products by cloud point extraction coupled with flame atomic absorption spectrometry.

    Science.gov (United States)

    Arain, Sadaf Sadia; Kazi, Tasneem Gul; Arain, Jamshed Bashir; Afridi, Hassan Imran; Kazi, Atif Gul; Nasreen, Syeda; Brahman, Kapil Dev

    2014-10-01

    Oropharyngeal cancer is a significant public health issue in the world. The incidence of oropharyngeal cancer has been increased among people who have habit of chewing smokeless tobacco (SLT) in Pakistan. The aim of present study was to evaluate the concentration of nickel (Ni) in biological samples (whole blood, serum) of oral (n = 95) and pharyngeal (n = 84) male cancer patients. For comparison purposes, the biological samples of healthy age-matched referents (n = 150), who consumed and did not consumed SLT products, were also analyzed for Ni levels. As the Ni level is very low in biological samples, a preconcentration procedure has been developed, prior to analysis of analyte by flame atomic absorption spectrometry (FAAS). The Ni in acid-digested biological samples was complexed with ammonium pyrrolidinedithio carbamate (APDC), and a resulted complex was extracted in a surfactant Triton X-114. Acidic ethanol was added to the surfactant-rich phase prior to its analysis by FAAS. The chemical variables, such as pH, amounts of reagents (APDC, Triton X-114), temperature, incubation time, and sample volume were optimized. The resulted data indicated that concentration of Ni was higher in blood and serum samples of cancer patients as compared to that of referents who have or have not consumed different SLT products (p = 0.012-0.001). It was also observed that healthy referents who consumed SLT products have two to threefold higher levels of Ni in both biological samples as compared to those who were not chewing SLT products (p < 0.01).

  3. Cloud migration

    CERN Document Server

    Höllwarth, Tobias

    2012-01-01

    This book is designed for managers and entrepreneurs, who are considering improving the economics and flexibility of their IT solutions and infrastructures. The book is also for readers who wish to learn more about the Cloud, but do not want to become specialists.This book discusses the technical, legal, fiscal, economic, organisational and environmental aspects of Cloud services. If you are looking for practical advice on vendor selection and certification, as well as real world Cloud project case studies, this is the book to consult.It is the result of a highly cooper

  4. Cloud Computing

    CERN Document Server

    Baun, Christian; Nimis, Jens; Tai, Stefan

    2011-01-01

    Cloud computing is a buzz-word in today's information technology (IT) that nobody can escape. But what is really behind it? There are many interpretations of this term, but no standardized or even uniform definition. Instead, as a result of the multi-faceted viewpoints and the diverse interests expressed by the various stakeholders, cloud computing is perceived as a rather fuzzy concept. With this book, the authors deliver an overview of cloud computing architecture, services, and applications. Their aim is to bring readers up to date on this technology and thus to provide a common basis for d

  5. Atomic laser-beam finder.

    Science.gov (United States)

    Viering, Kirsten; Medellin, David; Mo, Jianyong; Raizen, Mark G

    2012-11-05

    We report on an experimental method to align a laser beam to a cloud of atoms trapped in a magneto-optical trap (MOT). We show how balanced lock-in detection leads to a very sensitive method to align the laser beam to the atoms in the plane perpendicular to the propagation direction. This provides a very reliable and fast way of aligning laser beams to atoms trapped in a MOT.

  6. Cloud Formation

    Science.gov (United States)

    Graham, Mark Talmage

    2004-05-01

    Cloud formation is crucial to the heritage of modern physics, and there is a rich literature on this important topic. In 1927, Charles T.R. Wilson was awarded the Nobel Prize in physics for applications of the cloud chamber.2 Wilson was inspired to study cloud formation after working at a meteorological observatory on top of the highest mountain in Scotland, Ben Nevis, and testified near the end of his life, "The whole of my scientific work undoubtedly developed from the experiments I was led to make by what I saw during my fortnight on Ben Nevis in September 1894."3 To form clouds, Wilson used the sudden expansion of humid air.4 Any structure the cloud may have is spoiled by turbulence in the sudden expansion, but in 1912 Wilson got ion tracks to show up by using strobe photography of the chamber immediately upon expansion.5 In the interim, Millikan's study in 1909 of the formation of cloud droplets around individual ions was the first in which the electron charge was isolated. This study led to his famous oil drop experiment.6 To Millikan, as to Wilson, meteorology and physics were professionally indistinct. With his meteorological physics expertise, in WWI Millikan commanded perhaps the first meteorological observation and forecasting team essential to military operation in history.7 But even during peacetime meteorology is so much of a concern to everyone that a regular news segment is dedicated to it. Weather is the universal conversation topic, and life on land could not exist as we know it without clouds. One wonders then, why cloud formation is never covered in physics texts.

  7. Atomic population distribution in the output ports of cold-atom interferometers with optical splitting and recombination

    CERN Document Server

    Ilo-Okeke, Ebubechukwu O

    2010-01-01

    Cold-atom interferometers with optical splitting and recombination use off-resonant laser beams to split a cloud of Bose-Einstein condensate (BEC) into two clouds that travel along different paths and are then recombined again using optical beams. After the recombination, the BEC in general populates both the cloud at rest and the moving clouds. Measuring relative number of atoms in each of these clouds yields information about the relative phase shift accumulated by the atoms in the two moving clouds during the interferometric cycle. We derive the expression for the probability of finding any given number of atoms in each of the clouds, discuss features of the probability density distribution, analyze its dependence on the relative accumulated phase shift as a function of the strength of the interatomic interactions, and compare our results with experiment.

  8. Cloud point extraction and flame atomic absorption spectrometry determination fo trace lead in urine%浊点萃取-火焰原子吸收光谱法测定人尿液中的痕量铅

    Institute of Scientific and Technical Information of China (English)

    杜军良; 杨双; 胡杨; 王秀峰

    2014-01-01

    A method for the determination of Pb in urine by flame atomic absorption spectrometry with cloud point extraction was es-tablished. Dithizone-acetone was selected as the complex reagent and TritonX-100 as the surfactant. Effects of pH concentrations of surfactant and complex reagent equilibrium temperature and time on the efficiency and sensitivity for clound point extraction were investigated. Under optimal conditions the detection limit was 0. 06 μg·L-1(n=11)with linear over the concentration range of 0~1. 00 μg·mL-1 ,and values of recovery were in the range of 96. 7% ~101%. The present method was applied to the determination of trace lead in urine samples with satisfactory results.%以双硫腙作为络合剂、聚乙二醇辛基苯基醚( TritonX-100)为非离子表面活性剂,建立浊点萃取-火焰原子吸收光谱测定尿液中痕量铅的方法。探讨了络合剂用量、平衡时间、pH值、TritonX-100用量、冰浴时间等因素对萃取效率的影响。结果表明:该方法对铅的最大富集倍数约为40倍,检出限为0.06μg·L-1( n=11)。回收率在96.7%~101%,线性范围为0~1.00μg·mL-1。利用该方法测定尿液中痕量铅的含量,结果令人满意。

  9. Cloud radiative properties and aerosol - cloud interaction

    Science.gov (United States)

    Viviana Vladutescu, Daniela; Gross, Barry; Li, Clement; Han, Zaw

    2015-04-01

    The presented research discusses different techniques for improvement of cloud properties measurements and analysis. The need for these measurements and analysis arises from the high errors noticed in existing methods that are currently used in retrieving cloud properties and implicitly cloud radiative forcing. The properties investigated are cloud fraction (cf) and cloud optical thickness (COT) measured with a suite of collocated remote sensing instruments. The novel approach makes use of a ground based "poor man's camera" to detect cloud and sky radiation in red, green, and blue with a high spatial resolution of 30 mm at 1km. The surface-based high resolution photography provides a new and interesting view of clouds. As the cloud fraction cannot be uniquely defined or measured, it depends on threshold and resolution. However as resolution decreases, cloud fraction tends to increase if the threshold is below the mean, and vice versa. Additionally cloud fractal dimension also depends on threshold. Therefore these findings raise concerns over the ability to characterize clouds by cloud fraction or fractal dimension. Our analysis indicate that Principal Component analysis may lead to a robust means of quantifying cloud contribution to radiance. The cloud images are analyzed in conjunction with a collocated CIMEL sky radiometer, Microwave Radiometer and LIDAR to determine homogeneity and heterogeneity. Additionally, MFRSR measurements are used to determine the cloud radiative properties as a validation tool to the results obtained from the other instruments and methods. The cloud properties to be further studied are aerosol- cloud interaction, cloud particle radii, and vertical homogeneity.

  10. Spatial distribution of optically induced atomic excitation in a dense and cold atomic ensemble

    CERN Document Server

    Fofanov, Ya A; Sokolov, I M; Havey, M D

    2013-01-01

    On the basis of our general theoretical results developed previously in JETP 112, 246 (2011), we calculate the spatial distribution of atoms excited in a dense and cold atomic cloud by weak monochromatic light. We also study the atomic distribution over different Zeeman sublevels of the excited state in different parts of the cloud. The dependence of this distribution of atomic excitation on the density of the atomic ensemble and the frequency of external emission is investigated. We show that in the boundary regions of the cloud the orientation and alignment of atomic angular momentum takes place. Analysis of the spatial distribution of atomic excitation shows no noticeable signs of light localization effects even in those parameter regimes where the Ioffe-Regel criterium of strong localization is satisfied. However, comparative calculations performed in the framework of the scalar approximation to the dipole-dipole interaction reveals explicit manifestation of strong localization under some conditions.

  11. Atomic lighthouse effect.

    Science.gov (United States)

    Máximo, C E; Kaiser, R; Courteille, Ph W; Bachelard, R

    2014-11-01

    We investigate the deflection of light by a cold atomic cloud when the light-matter interaction is locally tuned via the Zeeman effect using magnetic field gradients. This "lighthouse" effect is strongest in the single-scattering regime, where deviation of the incident field is largest. For optically dense samples, the deviation is reduced by collective effects, as the increase in linewidth leads to a decrease in magnetic field efficiency.

  12. The Atomic Lighthouse Effect

    CERN Document Server

    Máximo, C E; Courteille, Ph W; Bachelard, R

    2014-01-01

    We investigate the deflection of light by a cold atomic cloud when the light-matter interaction is locally tuned via the Zeeman effect using magnetic field gradients. This "lighthouse" effect is strongest in the single-scattering regime, where deviation of the incident field is largest. For optically dense samples, the deviation is reduced by collective effects, as the increase in linewidth leads to a decrease of the magnetic field efficiency.

  13. Soft Clouding

    DEFF Research Database (Denmark)

    Søndergaard, Morten; Markussen, Thomas; Wetton, Barnabas;

    2012-01-01

    Soft Clouding is a blended concept, which describes the aim of a collaborative and transdisciplinary project. The concept is a metaphor implying a blend of cognitive, embodied interaction and semantic web. Furthermore, it is a metaphor describing our attempt of curating a new semantics of sound...

  14. Mobile Clouds

    DEFF Research Database (Denmark)

    Fitzek, Frank; Katz, Marcos

    examples of mobile clouds applications, based on both existing commercial initiatives as well as proof-of-concept test-beds. Visions and prospects are also discussed, paving the way for further development. As mobile networks and social networks become more and more reliant on each other, the concept...

  15. Cloud management and security

    CERN Document Server

    Abbadi, Imad M

    2014-01-01

    Written by an expert with over 15 years' experience in the field, this book establishes the foundations of Cloud computing, building an in-depth and diverse understanding of the technologies behind Cloud computing. In this book, the author begins with an introduction to Cloud computing, presenting fundamental concepts such as analyzing Cloud definitions, Cloud evolution, Cloud services, Cloud deployment types and highlighting the main challenges. Following on from the introduction, the book is divided into three parts: Cloud management, Cloud security, and practical examples. Part one presents the main components constituting the Cloud and federated Cloud infrastructure(e.g., interactions and deployment), discusses management platforms (resources and services), identifies and analyzes the main properties of the Cloud infrastructure, and presents Cloud automated management services: virtual and application resource management services. Part two analyzes the problem of establishing trustworthy Cloud, discuss...

  16. Cloud Computing

    DEFF Research Database (Denmark)

    Krogh, Simon

    2013-01-01

    The second half of the 20th century has been characterized by an explosive development in information technology (Maney, Hamm, & O'Brien, 2011). Processing power, storage capacity and network bandwidth have increased exponentially, resulting in new possibilities and shifting IT paradigms. In step...... with technological changes, the paradigmatic pendulum has swung between increased centralization on one side and a focus on distributed computing that pushes IT power out to end users on the other. With the introduction of outsourcing and cloud computing, centralization in large data centers is again dominating...... the IT scene. In line with the views presented by Nicolas Carr in 2003 (Carr, 2003), it is a popular assumption that cloud computing will be the next utility (like water, electricity and gas) (Buyya, Yeo, Venugopal, Broberg, & Brandic, 2009). However, this assumption disregards the fact that most IT production...

  17. Anchoring Magnetic Field in Turbulent Molecular Clouds

    CERN Document Server

    Li, Hua-bai; Goodman, Alyssa; Hildebrand, Roger; Novak, Giles

    2009-01-01

    One of the key problems in star formation research is to determine the role of magnetic fields. Starting from the atomic inter-cloud medium (ICM) which has density nH ~ 1 per cubic cm, gas must accumulate from a volume several hundred pc across in order to form a typical molecular cloud. Star formation usually occurs in cloud cores, which have linear sizes below 1 pc and densities nH2 > 10^5 per cubic cm. With current technologies, it is hard to probe magnetic fields at scales lying between the accumulation length and the size of cloud cores, a range corresponds to many levels of turbulent eddy cascade, and many orders of magnitude of density amplification. For field directions detected from the two extremes, however, we show here that a significant correlation is found. Comparing this result with molecular cloud simulations, only the sub-Alfvenic cases result in field orientations consistent with our observations.

  18. Cosmic ray penetration in diffuse clouds

    CERN Document Server

    Morlino, G

    2015-01-01

    Cosmic rays are a fundamental source of ionization for molecular and diffuse clouds, influencing their chemical, thermal, and dynamical evolution. The amount of cosmic rays inside a cloud also determines the $\\gamma$-ray flux produced by hadronic collisions between cosmic rays and cloud material. We study the spectrum of cosmic rays inside and outside of a diffuse cloud, by solving the stationary transport equation for cosmic rays including diffusion, advection and energy losses due to ionization of neutral hydrogen atoms. We found that the cosmic ray spectrum inside a diffuse cloud differs from the one in the interstellar medium for energies smaller than $E_{br}\\approx 100$ MeV, irrespective of the model details. Below $E_{br}$, the spectrum is harder (softer) than that in the interstellar medium if the latter is a power law $\\propto p^{-s}$ with $s$ larger (smaller) than $\\sim0.42$.

  19. Evaporative cooling of cold atoms at surfaces

    CERN Document Server

    Märkle, J; Federsel, P; Jetter, B; Günther, A; Fortágh, J; Proukakis, N P; Judd, T E

    2014-01-01

    We theoretically investigate the evaporative cooling of cold rubidium atoms that are brought close to a solid surface. The dynamics of the atom cloud are described by coupling a dissipative Gross-Pitaevskii equation for the condensate with a quantum Boltzmann description of the thermal cloud (the Zaremba-Nikuni-Griffin method). We have also performed experiments to allow for a detailed comparison with this model and find that it can capture the key physics of this system provided the full collisional dynamics of the thermal cloud are included. In addition, we suggest how to optimize surface cooling to obtain the purest and largest condensates.

  20. Cloud Interactions

    Science.gov (United States)

    2004-01-01

    [figure removed for brevity, see original site] Released 1 July 2004 The atmosphere of Mars is a dynamic system. Water-ice clouds, fog, and hazes can make imaging the surface from space difficult. Dust storms can grow from local disturbances to global sizes, through which imaging is impossible. Seasonal temperature changes are the usual drivers in cloud and dust storm development and growth. Eons of atmospheric dust storm activity has left its mark on the surface of Mars. Dust carried aloft by the wind has settled out on every available surface; sand dunes have been created and moved by centuries of wind; and the effect of continual sand-blasting has modified many regions of Mars, creating yardangs and other unusual surface forms. This image was acquired during mid-spring near the North Pole. The linear water-ice clouds are now regional in extent and often interact with neighboring cloud system, as seen in this image. The bottom of the image shows how the interaction can destroy the linear nature. While the surface is still visible through most of the clouds, there is evidence that dust is also starting to enter the atmosphere. Image information: VIS instrument. Latitude 68.4, Longitude 258.8 East (101.2 West). 38 meter/pixel resolution. Note: this THEMIS visual image has not been radiometrically nor geometrically calibrated for this preliminary release. An empirical correction has been performed to remove instrumental effects. A linear shift has been applied in the cross-track and down-track direction to approximate spacecraft and planetary motion. Fully calibrated and geometrically projected images will be released through the Planetary Data System in accordance with Project policies at a later time. NASA's Jet Propulsion Laboratory manages the 2001 Mars Odyssey mission for NASA's Office of Space Science, Washington, D.C. The Thermal Emission Imaging System (THEMIS) was developed by Arizona State University, Tempe, in collaboration with Raytheon Santa Barbara

  1. ATOMIC HYDROGEN IN A GALACTIC CENTER OUTFLOW

    Energy Technology Data Exchange (ETDEWEB)

    McClure-Griffiths, N. M.; Green, J. A.; Hill, A. S. [Australia Telescope National Facility, CSIRO Astronomy and Space Science, Marsfield, NSW 2122 (Australia); Lockman, F. J. [National Radio Astronomy Observatory, Green Bank, WV 24944 (United States); Dickey, J. M. [School of Physics and Mathematics, University of Tasmania, TAS 7001 (Australia); Gaensler, B. M.; Green, A. J., E-mail: naomi.mcclure-griffiths@csiro.au [Sydney Institute for Astronomy, School of Physics, The University of Sydney, NSW 2006 (Australia)

    2013-06-10

    We describe a population of small, high-velocity, atomic hydrogen clouds, loops, and filaments found above and below the disk near the Galactic center. The objects have a mean radius of 15 pc, velocity widths of {approx}14 km s{sup -1}, and are observed at |z| heights up to 700 pc. The velocity distribution of the clouds shows no signature of Galactic rotation. We propose a scenario where the clouds are associated with an outflow from a central star-forming region at the Galactic center. We discuss the clouds as entrained material traveling at {approx}200 km s{sup -1} in a Galactic wind.

  2. Steerable optical tweezers for ultracold atom studies.

    Science.gov (United States)

    Roberts, K O; McKellar, T; Fekete, J; Rakonjac, A; Deb, A B; Kjærgaard, N

    2014-04-01

    We report on the implementation of an optical tweezer system for controlled transport of ultracold atoms along a narrow, static confinement channel. The tweezer system is based on high-efficiency acousto-optic deflectors and offers two-dimensional control over beam position. This opens up the possibility for tracking the transport channel when shuttling atomic clouds along it, forestalling atom spilling. Multiple clouds can be tracked independently by time-shared tweezer beams addressing individual sites in the channel. The deflectors are controlled using a multichannel direct digital synthesizer, which receives instructions on a submicrosecond time scale from a field-programmable gate array. Using the tweezer system, we demonstrate sequential binary splitting of an ultracold 87Rb cloud into 2(5) clouds.

  3. Martian Clouds

    Science.gov (United States)

    2004-01-01

    [figure removed for brevity, see original site] Released 28 June 2004 The atmosphere of Mars is a dynamic system. Water-ice clouds, fog, and hazes can make imaging the surface from space difficult. Dust storms can grow from local disturbances to global sizes, through which imaging is impossible. Seasonal temperature changes are the usual drivers in cloud and dust storm development and growth. Eons of atmospheric dust storm activity has left its mark on the surface of Mars. Dust carried aloft by the wind has settled out on every available surface; sand dunes have been created and moved by centuries of wind; and the effect of continual sand-blasting has modified many regions of Mars, creating yardangs and other unusual surface forms. This image was acquired during early spring near the North Pole. The linear 'ripples' are transparent water-ice clouds. This linear form is typical for polar clouds. The black regions on the margins of this image are areas of saturation caused by the build up of scattered light from the bright polar material during the long image exposure. Image information: VIS instrument. Latitude 68.1, Longitude 147.9 East (212.1 West). 38 meter/pixel resolution. Note: this THEMIS visual image has not been radiometrically nor geometrically calibrated for this preliminary release. An empirical correction has been performed to remove instrumental effects. A linear shift has been applied in the cross-track and down-track direction to approximate spacecraft and planetary motion. Fully calibrated and geometrically projected images will be released through the Planetary Data System in accordance with Project policies at a later time. NASA's Jet Propulsion Laboratory manages the 2001 Mars Odyssey mission for NASA's Office of Space Science, Washington, D.C. The Thermal Emission Imaging System (THEMIS) was developed by Arizona State University, Tempe, in collaboration with Raytheon Santa Barbara Remote Sensing. The THEMIS investigation is led by Dr. Philip

  4. Cloud Computing (4)

    Institute of Scientific and Technical Information of China (English)

    Wang Bai; Xu Liutong

    2010-01-01

    @@ 8 Case Study Cloud computing is still a new phenomenon. Although many IT giants are developing their own cloud computing infrastructures,platforms, software, and services, few have really succeeded in becoming cloud computing providers.

  5. Blue skies for CLOUD

    CERN Multimedia

    2006-01-01

    Through the recently approved CLOUD experiment, CERN will soon be contributing to climate research. Tests are being performed on the first prototype of CLOUD, an experiment designed to assess cosmic radiation influence on cloud formation.

  6. Cloud-Top Entrainment in Stratocumulus Clouds

    Science.gov (United States)

    Mellado, Juan Pedro

    2017-01-01

    Cloud entrainment, the mixing between cloudy and clear air at the boundary of clouds, constitutes one paradigm for the relevance of small scales in the Earth system: By regulating cloud lifetimes, meter- and submeter-scale processes at cloud boundaries can influence planetary-scale properties. Understanding cloud entrainment is difficult given the complexity and diversity of the associated phenomena, which include turbulence entrainment within a stratified medium, convective instabilities driven by radiative and evaporative cooling, shear instabilities, and cloud microphysics. Obtaining accurate data at the required small scales is also challenging, for both simulations and measurements. During the past few decades, however, high-resolution simulations and measurements have greatly advanced our understanding of the main mechanisms controlling cloud entrainment. This article reviews some of these advances, focusing on stratocumulus clouds, and indicates remaining challenges.

  7. Silicon Photonics Cloud (SiCloud)

    DEFF Research Database (Denmark)

    DeVore, P. T. S.; Jiang, Y.; Lynch, M.;

    2015-01-01

    Silicon Photonics Cloud (SiCloud.org) is the first silicon photonics interactive web tool. Here we report new features of this tool including mode propagation parameters and mode distribution galleries for user specified waveguide dimensions and wavelengths.......Silicon Photonics Cloud (SiCloud.org) is the first silicon photonics interactive web tool. Here we report new features of this tool including mode propagation parameters and mode distribution galleries for user specified waveguide dimensions and wavelengths....

  8. Automatic Cloud Bursting under FermiCloud

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Hao [Fermilab; Shangping, Ren [IIT; Garzoglio, Gabriele [Fermilab; Timm, Steven [Fermilab; Bernabeu, Gerard [Fermilab; Kim, Hyun Woo; Chadwick, Keith; Jang, Haengjin [KISTI, Daejeon; Noh, Seo-Young [KISTI, Daejeon

    1900-01-01

    Cloud computing is changing the infrastructure upon which scientific computing depends from supercomputers and distributed computing clusters to a more elastic cloud-based structure. The service-oriented focus and elasticity of clouds can not only facilitate technology needs of emerging business but also shorten response time and reduce operational costs of traditional scientific applications. Fermi National Accelerator Laboratory (Fermilab) is currently in the process of building its own private cloud, FermiCloud, which allows the existing grid infrastructure to use dynamically provisioned resources on FermiCloud to accommodate increased but dynamic computation demand from scientists in the domains of High Energy Physics (HEP) and other research areas. Cloud infrastructure also allows to increase a private cloud’s resource capacity through “bursting” by borrowing or renting resources from other community or commercial clouds when needed. This paper introduces a joint project on building a cloud federation to support HEP applications between Fermi National Accelerator Laboratory and Korea Institution of Science and Technology Information, with technical contributions from the Illinois Institute of Technology. In particular, this paper presents two recent accomplishments of the joint project: (a) cloud bursting automation and (b) load balancer. Automatic cloud bursting allows computer resources to be dynamically reconfigured to meet users’ demands. The load balance algorithm which the cloud bursting depends on decides when and where new resources need to be allocated. Our preliminary prototyping and experiments have shown promising success, yet, they also have opened new challenges to be studied

  9. A magnetic guide for cold atoms

    CERN Document Server

    Richmond, J A; Cantwell, B P; Opat, G I

    1998-01-01

    We propose a novel method for guiding cold, neutral atoms using static magnetic fields. A theoretical study of the magnetic field produced by a tube consisting of two identical, interwound solenoids carrying equal but opposite currents is presented. This field is almost zero throughout the centre of the tube, but it increases with exponential rapidity as one approaches the walls formed by the current carrying wires. Hence, cold atoms passing through the tube may be reflected by magnetic mirror effects near the walls. Applying this technique to a free-falling cloud of magneto-optically cooled caesium atoms we hope to construct atomic guides to facilitate the manipulation of cold atomic beams.

  10. Cloud Computing (2)

    Institute of Scientific and Technical Information of China (English)

    Wang Bai; Xu Liutong

    2010-01-01

    @@ Editor's Desk: Cloud computing is a topic of intense interest in the Internet field. Major IT giants have launched their own cloud computing products. This four-part lecture series discusses cloud computing technology in the following aspects: The first part provided a brief description of the origin and characteristics of cloud computing from the users view of point; the other parts introduce typical applications of cloud computing, technically analyze the specific content within the cloud, its components, architecture and computational paradigm, compare cloud computing to other distributed computing technologies, and discuss its successful cases, commercial models, related technical and economic issues, and development trends.

  11. Cloud Computing (1)

    Institute of Scientific and Technical Information of China (English)

    Wang Bai; Xu Liutong

    2010-01-01

    @@ Editor's Desk: Cloud computing is a topic of intense interest in the Internet field. Major IT giants have launched their own cloud computing products. This four-part lecture series will discuss cloud computing technology in the following aspects: The first part provides a brief description of the origin and characteristics of cloud computing from the users view of point; the other parts introduce typical applications of cloud computing, technically analyze the specific content within the cloud, its components, architecture and computational paradigm, compare cloud computing to other distributed computing technologies, and discuss its successful cases, commercial models, related technical and economic issues, and development trends.

  12. Robots and sensor clouds

    CERN Document Server

    Shakshuki, Elhadi

    2016-01-01

    This book comprises four chapters that address some of the latest research in clouds robotics and sensor clouds. The first part of the book includes two chapters on cloud robotics. The first chapter introduces a novel resource allocation framework for cloud robotics and proposes a Stackelberg game model and the corresponding task oriented pricing mechanism for resource allocation. In the second chapter, the authors apply Cloud Computing for building a Cloud-Based 3D Point Cloud extractor for stereo images. Their objective is to have a dynamically scalable and applicable to near real-time scenarios.  .

  13. Cloud storage for dummies

    CERN Document Server

    Xu, Linda; Loughlin, Tanya

    2010-01-01

    Understand cloud computing and save your organization time and money! Cloud computing is taking IT by storm, but what is it and what are the benefits to your organization? Hitachi Data Systems' Cloud Storage For Dummies provides all the answers, With this book, you discover a clear explanation of cloud storage, and tips for how to choose the right type of cloud storage for your organization's needs. You also find out how cloud storage can free up valuable IT resources, saving time and money. Cloud Storage For Dummies presents useful information on setting up a

  14. Atom chips

    CERN Document Server

    Reichel, Jakob

    2010-01-01

    This book provides a stimulating and multifaceted picture of a rapidly developing field. The first part reviews fundamentals of atom chip research in tutorial style, while subsequent parts focus on the topics of atom-surface interaction, coherence on atom chips, and possible future directions of atom chip research. The articles are written by leading researchers in the field in their characteristic and individual styles.

  15. Atomic energy

    CERN Multimedia

    1996-01-01

    Interviews following the 1991 co-operation Agreement between the Department of Atomic Energy (DAE) of the Government of India and the European Organization for Nuclear Research (CERN) concerning the participation in the Large Hadron Collider Project (LHC) . With Chidambaram, R, Chairman, Atomic Energy Commission and Secretary, Department of Atomic Energy, Department of Atomic Energy (DAE) of the Government of India and Professor Llewellyn-Smith, Christopher H, Director-General, CERN.

  16. Two-component model of the interaction of an interstellar cloud with surrounding hot plasma

    OpenAIRE

    Provornikova, E. A.; Izmodenov, V. V.; Lallement, R.

    2011-01-01

    We present a two-component gasdynamic model of an interstellar cloud embedded in a hot plasma. It is assumed that the cloud consists of atomic hydrogen gas, interstellar plasma is quasineutral. Hydrogen atoms and plasma protons interact through a charge exchange process. Magnetic felds and radiative processes are ignored in the model. The influence of heat conduction within plasma on the interaction between a cloud and plasma is studied. We consider the extreme case and assume that hot plasma...

  17. The CLOUD experiment

    CERN Multimedia

    Maximilien Brice

    2006-01-01

    The Cosmics Leaving Outdoor Droplets (CLOUD) experiment as shown by Jasper Kirkby (spokesperson). Kirkby shows a sketch to illustrate the possible link between galactic cosmic rays and cloud formations. The CLOUD experiment uses beams from the PS accelerator at CERN to simulate the effect of cosmic rays on cloud formations in the Earth's atmosphere. It is thought that cosmic ray intensity is linked to the amount of low cloud cover due to the formation of aerosols, which induce condensation.

  18. Cloud Robotics Platforms

    Directory of Open Access Journals (Sweden)

    Busra Koken

    2015-01-01

    Full Text Available Cloud robotics is a rapidly evolving field that allows robots to offload computation-intensive and storage-intensive jobs into the cloud. Robots are limited in terms of computational capacity, memory and storage. Cloud provides unlimited computation power, memory, storage and especially collaboration opportunity. Cloud-enabled robots are divided into two categories as standalone and networked robots. This article surveys cloud robotic platforms, standalone and networked robotic works such as grasping, simultaneous localization and mapping (SLAM and monitoring.

  19. Cloud Computing (3)

    Institute of Scientific and Technical Information of China (English)

    Wang Bai; Xu Liutong

    2010-01-01

    @@ Editor's Desk: In the preceding two parts of this series, several aspects of cloud computing-including definition, classification, characteristics, typical applications, and service levels-were discussed. This part continues with a discussion of Cloud Computing Oopen Architecture and Market-Oriented Cloud. A comparison is made between cloud computing and other distributed computing technologies, and Google's cloud platform is analyzed to determine how distributed computing is implemented in its particular model.

  20. OH+ in Diffuse Molecular Clouds

    CERN Document Server

    Porras, A J; Welty, D E; Ritchey, A M

    2013-01-01

    Near ultraviolet observations of OH+ and OH in diffuse molecular clouds reveal a preference for different environments. The dominant absorption feature in OH+ arises from a main component seen in CH+ (that with the highest CH+/CH column density ratio), while OH follows CN absorption. This distinction provides new constraints on OH chemistry in these clouds. Since CH+ detections favor low-density gas with small fractions of molecular hydrogen, this must be true for OH+ as well, confirming OH+ and H2O+ observations with the Herschel Space Telescope. Our observed correspondence indicates that the cosmic ray ionization rate derived from these measurements pertains to mainly atomic gas. The association of OH absorption with gas rich in CN is attributed to the need for high enough density and molecular fraction before detectable amounts are seen. Thus, while OH+ leads to OH production, chemical arguments suggest that their abundances are controlled by different sets of conditions and that they coexist with differen...

  1. Cloud Databases: A Paradigm Shift in Databases

    Directory of Open Access Journals (Sweden)

    Indu Arora

    2012-07-01

    Full Text Available Relational databases ruled the Information Technology (IT industry for almost 40 years. But last few years have seen sea changes in the way IT is being used and viewed. Stand alone applications have been replaced with web-based applications, dedicated servers with multiple distributed servers and dedicated storage with network storage. Cloud computing has become a reality due to its lesser cost, scalability and pay-as-you-go model. It is one of the biggest changes in IT after the rise of World Wide Web. Cloud databases such as Big Table, Sherpa and SimpleDB are becoming popular. They address the limitations of existing relational databases related to scalability, ease of use and dynamic provisioning. Cloud databases are mainly used for data-intensive applications such as data warehousing, data mining and business intelligence. These applications are read-intensive, scalable and elastic in nature. Transactional data management applications such as banking, airline reservation, online e-commerce and supply chain management applications are write-intensive. Databases supporting such applications require ACID (Atomicity, Consistency, Isolation and Durability properties, but these databases are difficult to deploy in the cloud. The goal of this paper is to review the state of the art in the cloud databases and various architectures. It further assesses the challenges to develop cloud databases that meet the user requirements and discusses popularly used Cloud databases.

  2. Atomic polarizabilities

    Energy Technology Data Exchange (ETDEWEB)

    Safronova, M. S. [Department of Physics and Astronomy, University of Delaware, Newark, DE 19716 (United States); Mitroy, J. [School of Engineering, Charles Darwin University, Darwin NT 0909 (Australia); Clark, Charles W. [Joint Quantum Institute, National Institute of Standards and Technology and the University of Maryland, Gaithersburg, Maryland 20899-8410 (United States); Kozlov, M. G. [Petersburg Nuclear Physics Institute, Gatchina 188300 (Russian Federation)

    2015-01-22

    The atomic dipole polarizability governs the first-order response of an atom to an applied electric field. Atomic polarization phenomena impinge upon a number of areas and processes in physics and have been the subject of considerable interest and heightened importance in recent years. In this paper, we will summarize some of the recent applications of atomic polarizability studies. A summary of results for polarizabilities of noble gases, monovalent, and divalent atoms is given. The development of the CI+all-order method that combines configuration interaction and linearized coupled-cluster approaches is discussed.

  3. A dense gas of laser-cooled atoms for hybrid atom-ion trapping

    Science.gov (United States)

    Höltkemeier, Bastian; Glässel, Julian; López-Carrera, Henry; Weidemüller, Matthias

    2017-01-01

    We describe the realization of a dark spontaneous-force trap of rubidium atoms. The atoms are loaded from a beam provided by a two-dimensional magneto-optical trap yielding a capture efficiency of 75%. The dense and cold atomic sample is characterized by saturated absorption imaging. Up to 10^9 atoms are captured with a loading rate of 3× 10^9 atoms/s into a cloud at a temperature of 250 μK with the density exceeding 10^{11} atoms/cm^3. Under steady-state conditions, more than 90% of the atoms can be prepared into the absolute atomic ground state, which provides favorable conditions for the investigation of sympathetic cooling of ions in a hybrid atom-ion trap.

  4. Spontaneous decay of an atom excited in a dense and disordered atomic ensemble: quantum microscopic approach

    CERN Document Server

    Kuraptsev, A S

    2016-01-01

    On the basis of general theoretical results developed previously in [I. M. Sokolov et al., J. Exp. Theor. Phys. 112, 246 (2011)], we analyze spontaneous decay of a single atom inside cold atomic clouds under conditions when the averaged interatomic separation is less or comparable with the wavelength of quasi resonant radiation. Beyond the decay dynamics we analyze shifts of resonance as well as distortion of the spectral shape of the atomic transition.

  5. Hybrid cloud for dummies

    CERN Document Server

    Hurwitz, Judith; Halper, Fern; Kirsch, Dan

    2012-01-01

    Understand the cloud and implement a cloud strategy for your business Cloud computing enables companies to save money by leasing storage space and accessing technology services through the Internet instead of buying and maintaining equipment and support services. Because it has its own unique set of challenges, cloud computing requires careful explanation. This easy-to-follow guide shows IT managers and support staff just what cloud computing is, how to deliver and manage cloud computing services, how to choose a service provider, and how to go about implementation. It also covers security and

  6. Secure cloud computing

    CERN Document Server

    Jajodia, Sushil; Samarati, Pierangela; Singhal, Anoop; Swarup, Vipin; Wang, Cliff

    2014-01-01

    This book presents a range of cloud computing security challenges and promising solution paths. The first two chapters focus on practical considerations of cloud computing. In Chapter 1, Chandramouli, Iorga, and Chokani describe the evolution of cloud computing and the current state of practice, followed by the challenges of cryptographic key management in the cloud. In Chapter 2, Chen and Sion present a dollar cost model of cloud computing and explore the economic viability of cloud computing with and without security mechanisms involving cryptographic mechanisms. The next two chapters addres

  7. Cloud Processed CCN Affect Cloud Microphysics

    Science.gov (United States)

    Hudson, J. G.; Noble, S. R., Jr.; Tabor, S. S.

    2015-12-01

    Variations in the bimodality/monomodality of CCN spectra (Hudson et al. 2015) exert opposite effects on cloud microphysics in two aircraft field projects. The figure shows two examples, droplet concentration, Nc, and drizzle liquid water content, Ld, against classification of CCN spectral modality. Low ratings go to balanced separated bimodal spectra, high ratings go to single mode spectra, strictly monomodal 8. Intermediate ratings go merged modes, e.g., one mode a shoulder of another. Bimodality is caused by mass or hygroscopicity increases that go only to CCN that made activated cloud droplets. In the Ice in Clouds Experiment-Tropical (ICE-T) small cumuli with lower Nc, greater droplet mean diameters, MD, effective radii, re, spectral widths, σ, cloud liquid water contents, Lc, and Ld were closer to more bimodal (lower modal ratings) below cloud CCN spectra whereas clouds with higher Nc, smaller MD, re, σ, and Ld were closer to more monomodal CCN (higher modal ratings). In polluted stratus clouds of the MArine Stratus/Stratocumulus Experiment (MASE) clouds that had greater Nc, and smaller MD, re, σ, Lc, and Ld were closer to more bimodal CCN spectra whereas clouds with lower Nc, and greater MD, re, σ, Lc, and Ld were closer to more monomodal CCN. These relationships are opposite because the dominant ICE-T cloud processing was coalescence whereas chemical transformations (e.g., SO2 to SO4) were dominant in MASE. Coalescence reduces Nc and thus also CCN concentrations (NCCN) when droplets evaporate. In subsequent clouds the reduced competition increases MD and σ, which further enhance coalescence and drizzle. Chemical transformations do not change Nc but added sulfate enhances droplet and CCN solubility. Thus, lower critical supersaturation (S) CCN can produce more cloud droplets in subsequent cloud cycles, especially for the low W and effective S of stratus. The increased competition reduces MD, re, and σ, which inhibit coalescence and thus reduce drizzle

  8. Cold heteronuclear atom-ion collisions

    CERN Document Server

    Zipkes, Christoph; Ratschbacher, Lothar; Sias, Carlo; Köhl, Michael

    2010-01-01

    We study cold heteronuclear atom ion collisions by immersing a trapped single ion into an ultracold atomic cloud. Using ultracold atoms as reaction targets, our measurement is sensitive to elastic collisions with extremely small energy transfer. The observed energy-dependent elastic atom-ion scattering rate deviates significantly from the prediction of Langevin but is in full agreement with the quantum mechanical cross section. Additionally, we characterize inelastic collisions leading to chemical reactions at the single particle level and measure the energy-dependent reaction rate constants. The reaction products are identified by in-trap mass spectrometry, revealing the branching ratio between radiative and non-radiative charge exchange processes.

  9. Carbon Isotope Chemistry in Molecular Clouds

    Science.gov (United States)

    Robertson, Amy N.; Willacy, Karen

    2012-01-01

    Few details of carbon isotope chemistry are known, especially the chemical processes that occur in astronomical environments like molecular clouds. Observational evidence shows that the C-12/C-13 abundance ratios vary due to the location of the C-13 atom within the molecular structure. The different abundances are a result of the diverse formation pathways that can occur. Modeling can be used to explore the production pathways of carbon molecules in an effort to understand and explain the chemical evolution of molecular clouds.

  10. Moving towards Cloud Security

    Directory of Open Access Journals (Sweden)

    Edit Szilvia Rubóczki

    2015-01-01

    Full Text Available Cloud computing hosts and delivers many different services via Internet. There are a lot of reasons why people opt for using cloud resources. Cloud development is increasing fast while a lot of related services drop behind, for example the mass awareness of cloud security. However the new generation upload videos and pictures without reason to a cloud storage, but only few know about data privacy, data management and the proprietary of stored data in the cloud. In an enterprise environment the users have to know the rule of cloud usage, however they have little knowledge about traditional IT security. It is important to measure the level of their knowledge, and evolve the training system to develop the security awareness. The article proves the importance of suggesting new metrics and algorithms for measuring security awareness of corporate users and employees to include the requirements of emerging cloud security.

  11. Cloud Computing for radiologists.

    Science.gov (United States)

    Kharat, Amit T; Safvi, Amjad; Thind, Ss; Singh, Amarjit

    2012-07-01

    Cloud computing is a concept wherein a computer grid is created using the Internet with the sole purpose of utilizing shared resources such as computer software, hardware, on a pay-per-use model. Using Cloud computing, radiology users can efficiently manage multimodality imaging units by using the latest software and hardware without paying huge upfront costs. Cloud computing systems usually work on public, private, hybrid, or community models. Using the various components of a Cloud, such as applications, client, infrastructure, storage, services, and processing power, Cloud computing can help imaging units rapidly scale and descale operations and avoid huge spending on maintenance of costly applications and storage. Cloud computing allows flexibility in imaging. It sets free radiology from the confines of a hospital and creates a virtual mobile office. The downsides to Cloud computing involve security and privacy issues which need to be addressed to ensure the success of Cloud computing in the future.

  12. In the clouds

    NARCIS (Netherlands)

    Wassink, J.

    2012-01-01

    Clouds always used to be the least understood element of the weather system, but that is rapidly changing . Computer clouds increasingly correspond with those in the sky, which promises weather forecasts at street level and more accurate climate scenarios.

  13. Comparing Point Clouds

    Science.gov (United States)

    2004-04-01

    Point clouds are one of the most primitive and fundamental surface representations. A popular source of point clouds are three dimensional shape...acquisition devices such as laser range scanners. Another important field where point clouds are found is in the representation of high-dimensional...framework for comparing manifolds given by point clouds is presented in this paper. The underlying theory is based on Gromov-Hausdorff distances, leading

  14. Computer animation of clouds

    Energy Technology Data Exchange (ETDEWEB)

    Max, N.

    1994-01-28

    Computer animation of outdoor scenes is enhanced by realistic clouds. I will discuss several different modeling and rendering schemes for clouds, and show how they evolved in my animation work. These include transparency-textured clouds on a 2-D plane, smooth shaded or textured 3-D clouds surfaces, and 3-D volume rendering. For the volume rendering, I will present various illumination schemes, including the density emitter, single scattering, and multiple scattering models.

  15. Cloud computing strategies

    CERN Document Server

    Chorafas, Dimitris N

    2011-01-01

    A guide to managing cloud projects, Cloud Computing Strategies provides the understanding required to evaluate the technology and determine how it can be best applied to improve business and enhance your overall corporate strategy. Based on extensive research, it examines the opportunities and challenges that loom in the cloud. It explains exactly what cloud computing is, what it has to offer, and calls attention to the important issues management needs to consider before passing the point of no return regarding financial commitments.

  16. 浊点萃取技术-原子光谱法在食品中金属元素检测中的应用%Application of cloud point extraction-flame atomic absorption spectroscopy on determination of metal elements in food

    Institute of Scientific and Technical Information of China (English)

    杨艳红; 姜兆兴; 赵敏

    2014-01-01

    Heavy metal pollution has been one of the major influencing factor to food safety, which attracts more and more attention from all over the world. Hence, it is very important to establish a new detection method of metal in food. Application of an emerging, green and environment benign separation and enrichment process, cloud point extraction were introduced, combined with atomic absorption spectroscopy. Cloud point extraction is economic, safe, simple and highly efficient, which has been widely used in the sample pretreatment of metal detections in food. This paper discussed the basic principle of cloud point extraction. Several factors were elaborated, such as the species and concentration of surfactants, pH values, equilibrium temperature and time, as well as the concentration of chelating reagents, which influenced the extraction efficiency and enrichment factor. In addition, the applications of cloud point extraction combined with the flame atomic absorbance spectroscopy on the metal determination in food were reviewed. Finally, the development trend of cloud point extraction technology in modern food detection was prospected.%重金属污染已成为影响食品安全的重要因素之一,在世界范围内引起了越来越广泛的关注,因此开发建立新的食品中金属检测方法具有十分重要的意义。本文介绍了新兴的绿色环保分离富集技术-浊点萃取及其结合原子吸收光谱法在食品中金属离子检测方面的应用。浊点萃取技术具有经济、安全、高效、简便等优点,近年来已开始广泛应用于食品中金属检测的样品前处理。本文讨论了浊点萃取技术的基本原理,阐述了表面活性剂的种类、浓度、溶液pH值、平衡时间、温度以及络合物浓度等影响萃取效率、富集系数的主要因素,及其与火焰原子吸收光谱联用后,在食品重金属检测中的研究应用情况。最后对浊点萃取技术在食品金属离子检测

  17. Governmental Cloud - Part of Cloud Computing

    Directory of Open Access Journals (Sweden)

    Cristian IVANUS

    2014-01-01

    Full Text Available Large IT (Information Technology companies propose cloud government's (G-Cloud development model through investment from the private sector, which will facilitate the access of users from public sector to the new generation IT services. Through the G-Cloud private operators that operate governmental cloud infrastructure by adding specific SaaS (Software as a Service functionalities, proposed model by big companies, supports public institutions in optimizing costs and increased operational efficiency, bringing tangible benefits in relation with citizens and thus with the whole society. These optimizations are achieved by moving the initial investment to the private sector, through type subscription model cost by eliminating dependency on human factors (technical and by providing a low cost [1]. This paper aims to bring to the attention of specialists, some aspects of Governmental Cloud from the European Union (EU countries to be understood and implemented in Romania.

  18. OH+ in Diffuse Molecular Clouds

    Science.gov (United States)

    Porras, A. J.; Federman, S. R.; Welty, D. E.; Ritchey, A. M.

    2014-01-01

    Near ultraviolet observations of OH+ and OH in diffuse molecular clouds reveal a preference for different environments. The dominant absorption feature in OH+ arises from a main component seen in CH+ (that with the highest CH+/CH column density ratio), while OH follows CN absorption. This distinction provides new constraints on OH chemistry in these clouds. Since CH+ detections favor low-density gas with small fractions of molecular hydrogen, this must be true for OH+ as well, confirming OH+ and H2O+ observations with the Herschel Space Telescope. Our observed correspondence indicates that the cosmic ray ionization rate derived from these measurements pertains to mainly atomic gas. The association of OH absorption with gas rich in CN is attributed to the need for a high enough density and molecular fraction before detectable amounts are seen. Thus, while OH+ leads to OH production, chemical arguments suggest that their abundances are controlled by different sets of conditions and that they coexist with different sets of observed species. Of particular note is that non-thermal chemistry appears to play a limited role in the synthesis of OH in diffuse molecular clouds.

  19. Cloud Computing Explained

    Science.gov (United States)

    Metz, Rosalyn

    2010-01-01

    While many talk about the cloud, few actually understand it. Three organizations' definitions come to the forefront when defining the cloud: Gartner, Forrester, and the National Institutes of Standards and Technology (NIST). Although both Gartner and Forrester provide definitions of cloud computing, the NIST definition is concise and uses…

  20. On clocks and clouds

    Directory of Open Access Journals (Sweden)

    M. K. Witte

    2013-09-01

    Full Text Available Cumulus clouds exhibit a life cycle that consists of: (a the growth phase (increasing size, most notably in the vertical direction; (b the mature phase (growth ceases; any precipitation that develops is strongest during this period; and (c the dissipation phase (cloud dissipates because of precipitation and/or entrainment; no more dynamical support. Although radar can track clouds over time and give some sense of the age of a cloud, most aircraft in situ measurements lack temporal context. We use large eddy simulations of trade wind cumulus cloud fields from cases during the Barbados Oceanographic and Meteorological Experiment (BOMEX and Rain In Cumulus over the Ocean (RICO campaigns to demonstrate a potential cumulus cloud "clock". We find that the volume-averaged total water mixing ratio rt is a useful cloud clock for the 12 clouds studied. A cloud's initial rt is set by the subcloud mixed-layer mean rt and decreases monotonically from the initial value due primarily to entrainment. The clock is insensitive to aerosol loading, environmental sounding and extrinsic cloud properties such as lifetime and volume. In some cases (more commonly for larger clouds, multiple pulses of buoyancy occur, which complicate the cumulus clock by replenishing rt. The clock is most effectively used to classify clouds by life phase.

  1. Security in the cloud.

    Science.gov (United States)

    Degaspari, John

    2011-08-01

    As more provider organizations look to the cloud computing model, they face a host of security-related questions. What are the appropriate applications for the cloud, what is the best cloud model, and what do they need to know to choose the best vendor? Hospital CIOs and security experts weigh in.

  2. On CLOUD nine

    CERN Multimedia

    2009-01-01

    The team from the CLOUD experiment - the world’s first experiment using a high-energy particle accelerator to study the climate - were on cloud nine after the arrival of their new three-metre diameter cloud chamber. This marks the end of three years’ R&D and design, and the start of preparations for data taking later this year.

  3. Atomic physics

    CERN Document Server

    Born, Max

    1989-01-01

    The Nobel Laureate's brilliant exposition of the kinetic theory of gases, elementary particles, the nuclear atom, wave-corpuscles, atomic structure and spectral lines, electron spin and Pauli's principle, quantum statistics, molecular structure and nuclear physics. Over 40 appendices, a bibliography, numerous figures and graphs.

  4. Cloud Computing Bible

    CERN Document Server

    Sosinsky, Barrie

    2010-01-01

    The complete reference guide to the hot technology of cloud computingIts potential for lowering IT costs makes cloud computing a major force for both IT vendors and users; it is expected to gain momentum rapidly with the launch of Office Web Apps later this year. Because cloud computing involves various technologies, protocols, platforms, and infrastructure elements, this comprehensive reference is just what you need if you'll be using or implementing cloud computing.Cloud computing offers significant cost savings by eliminating upfront expenses for hardware and software; its growing popularit

  5. Cloud Computing Quality

    Directory of Open Access Journals (Sweden)

    Anamaria Şiclovan

    2013-02-01

    Full Text Available Cloud computing was and it will be a new way of providing Internet services and computers. This calculation approach is based on many existing services, such as the Internet, grid computing, Web services. Cloud computing as a system aims to provide on demand services more acceptable as price and infrastructure. It is exactly the transition from computer to a service offered to the consumers as a product delivered online. This paper is meant to describe the quality of cloud computing services, analyzing the advantages and characteristics offered by it. It is a theoretical paper.Keywords: Cloud computing, QoS, quality of cloud computing

  6. Intergalactic HI Clouds

    CERN Document Server

    Briggs, F H

    2005-01-01

    Neutral intergalactic clouds are so greatly out numbered by galaxies that their integral HI content is negligible in comparison to that contained in optically luminous galaxies. In fact, no HI cloud that is not associated with a galaxy or grouping of galaxies has yet been identified. This points to a causal relationship that relies on gravitational potentials that bind galaxies also being responsible for confining HI clouds to sufficient density that they can become self-shielding to the ionizing background radiation. Unconfined clouds of low density become ionized, but confined clouds find themselves vulnerable to instability and collapse, leading to star formation.

  7. Cloud Computing Technologies

    Directory of Open Access Journals (Sweden)

    Sean Carlin

    2012-06-01

    Full Text Available This paper outlines the key characteristics that cloud computing technologies possess and illustrates the cloud computing stack containing the three essential services (SaaS, PaaS and IaaS that have come to define the technology and its delivery model. The underlying virtualization technologies that make cloud computing possible are also identified and explained. The various challenges that face cloud computing technologies today are investigated and discussed. The future of cloud computing technologies along with its various applications and trends are also explored, giving a brief outlook of where and how the technology will progress into the future.

  8. CLOUD COMPUTING SECURITY

    Directory of Open Access Journals (Sweden)

    Ştefan IOVAN

    2016-05-01

    Full Text Available Cloud computing reprentes the software applications offered as a service online, but also the software and hardware components from the data center.In the case of wide offerd services for any type of client, we are dealing with a public cloud. In the other case, in wich a cloud is exclusively available for an organization and is not available to the open public, this is consider a private cloud [1]. There is also a third type, called hibrid in which case an user or an organization might use both services available in the public and private cloud. One of the main challenges of cloud computing are to build the trust and ofer information privacy in every aspect of service offerd by cloud computingle. The variety of existing standards, just like the lack of clarity in sustenability certificationis not a real help in building trust. Also appear some questions marks regarding the efficiency of traditionsecurity means that are applied in the cloud domain. Beside the economic and technology advantages offered by cloud, also are some advantages in security area if the information is migrated to cloud. Shared resources available in cloud includes the survey, use of the "best practices" and technology for advance security level, above all the solutions offered by the majority of medium and small businesses, big companies and even some guvermental organizations [2].

  9. Community Cloud Computing

    CERN Document Server

    Marinos, Alexandros

    2009-01-01

    Cloud Computing is rising fast, with its data centres growing at an unprecedented rate. However, this has come with concerns over privacy, efficiency at the expense of resilience, and environmental sustainability, because of the dependence on Cloud vendors such as Google, Amazon and Microsoft. Our response is an alternative model for the Cloud conceptualisation, providing a paradigm for Clouds in the community, utilising networked personal computers for liberation from the centralised vendor model. Community Cloud Computing (C3) offers an alternative architecture, created by combing the Cloud with paradigms from Grid Computing, principles from Digital Ecosystems, and sustainability from Green Computing, while remaining true to the original vision of the Internet. It is more technically challenging than Cloud Computing, having to deal with distributed computing issues, including heterogeneous nodes, varying quality of service, and additional security constraints. However, these are not insurmountable challenge...

  10. Security Problems in Cloud Computing

    OpenAIRE

    Rola Motawie; Mahmoud M. El-Khouly; Samir Abou El-Seoud

    2016-01-01

    Cloud is a pool of computing resources which are distributed among cloud users. Cloud computing has many benefits like scalability, flexibility, cost savings, reliability, maintenance and mobile accessibility. Since cloud-computing technology is growing day by day, it comes with many security problems. Securing the data in the cloud environment is most critical challenges which act as a barrier when implementing the cloud. There are many new concepts that cloud introduces, such as resource sh...

  11. Cross-Cloud Testing Strategies Over Cloud Computing

    Directory of Open Access Journals (Sweden)

    Mr. Nageswararao,

    2014-06-01

    Full Text Available Cloud computing is the new paradigm to deliver all the hosted services over internet on demand. The ultimate goal of cloud computing paradigm is to realize computing as a utility. The cloud is rapidly maturing towards its goal to support a wide variety of enterprise and consumer services and real-world applications. Recently a movement towards cross cloud also called as multi-clouds or inters clouds or cloud-of-clouds has emerged which take advantage of multiple independent cloud provider offers for cloud resilience and dependability. This cross cloud represents the next logical wave in computing, enabling complex hybrid applications, cost and performance optimization, enhanced reliability, customer flexibility and lock-in avoidance. Providing testing as a service (TaaS in cross clouds become hot topics in industry. Testing heterogeneous e-commerce sites, Software as a Service solutions, and Cloud based applications is extremely challenging.

  12. Properties of Diffuse Molecular Gas in the Magellanic Clouds

    Science.gov (United States)

    Welty, Daniel

    2012-10-01

    Studies of the interstellar medium in the lower-metallicity Magellanic Clouds explore somewhat different environmental conditions from those typically probed in our own Galactic ISM. Recent studies based on optical/UV spectra of SMC and LMC targets, for example, have revealed unexpected differences in gas-phase abundance patterns {for various atomic and molecular species} and have begun to explore the effects of differences in metallicity on the atomic-to-molecular transition and resulting molecular fraction f{H_2} - a key aspect in the formation of molecular clouds. We propose a more detailed study of the abundances, depletions, and local physical conditions characterizing diffuse molecular material in the Magellanic Clouds, using STIS E140H and E230M spectra of two sight lines with N{H_2} > 10^20 cm^-2 {both probing the outskirts of molecular clouds seen in CO emission}. The two STIS settings will include lines from various neutral and ionized species {with a range in depletion behavior}, several C I multiplets, and several bands of CO and C_2. By probing and characterizing the atomic-to-molecular transition in the Magellanic Clouds, we will address key issues regarding the effects of differences in metallicity on the relationship between the atomic and molecular gas in galaxies; on cloud structure, physical conditions, and diffuse cloud chemistry; and on the composition and properties of interstellar dust. The results of this project should thus aid in the interpretation of observations of atomic and molecular material in more distant low-metallicity systems.

  13. Secure Cloud Architecture

    Directory of Open Access Journals (Sweden)

    Kashif Munir

    2013-02-01

    Full Text Available Cloud computing is set of resources and services offered through the Internet. Cloud services are delivered from data centers located throughout the world. Cloud computing facilitates its consumers by providing virtual resources via internet. The biggest challenge in cloud computing is the security and privacy problems caused by its multi-tenancy nature and the outsourcing of infrastructure, sensitive data and critical applications. Enterprises are rapidly adopting cloud services for their businesses, measures need to be developed so that organizations can be assured of security in their businesses and can choose a suitable vendor for their computing needs. Cloud computing depends on the internet as a medium for users to access the required services at any time on pay-per-use pattern. However this technology is still in its initial stages of development, as it suffers from threats and vulnerabilities that prevent the users from trusting it. Various malicious activitiesfrom illegal users have threatened this technology such as data misuse, inflexible access control and limited monitoring. The occurrence of these threats may result into damaging or illegal access of critical and confidential data of users. In this paper we identify the most vulnerable security threats/attacks in cloud computing, which will enable both end users and vendors to know a bout the k ey security threats associated with cloud computing and propose relevant solution directives to strengthen security in the Cloud environment. We also propose secure cloud architecture for organizations to strengthen the security.

  14. Determination of micro Pd ( Ⅱ )in catalyst by cloud point extraction separation-flame atomic absorption spectrometry%浊点萃取-火焰原子吸收光谱法测定乙醛触媒微量钯含量

    Institute of Scientific and Technical Information of China (English)

    宋唯; 屈海峰; 陈寿华; 王绍东

    2012-01-01

    建立了以1-(2-吡啶偶氮)-2-萘酚(PAN)为络合剂,以非离子表面活性剂Triton X-100为萃取剂的浊点萃取分离富集-火焰原子吸收光谱法测定痕量钯的新方法.研究了溶液的酸度、络合剂和表面活性剂浓度、平衡温度和时间、离子强度等条件对浊点萃取效果的影响.该方法对钯的检出限为35.3 ng/mL,相对标准偏差(RSD)为3.1%(n=8),回收率97.6%~106.7%.可用于乙醛催化剂中微量Pd(Ⅱ)的测定.%Deter mination of micro Pd ( Ⅱ) in aldehyde catalyst was established by cloud point extraction separation-flame atomic absorption spectrometry using l-(2-pyridylazo)-2-naphthol(PAN) com-plexing agent( Ⅰ ) , non-ionic surfactant Triton X -100 as extracting agent (Id). The influences of acidity of solution,concentration of I and Ⅲ temperature and time of equilibrium,and ionic strength on the effect of cloud point extraction separation were investigated. The detection limit of new determinating method is 35. 3 ng/mL, the RSD is 3. l%(n = 8),the recovery is 97. 6%~106. 7%. New methd can be used in aldehyde production.

  15. The application of cloud point extraction in atomic absorption spectrometry%浊点萃取在原子吸收光谱分析中的应用进展

    Institute of Scientific and Technical Information of China (English)

    邓勃

    2010-01-01

    浊点萃取(Cloud Point Extraction,CPE),是基于非离子型表面活性剂溶液的浊点现象和胶束增溶效应而建立的一种萃取技术.大部分金属螯合物具有微溶于水的特性,与表面活性剂的疏水基团结合,富集于小体积的富胶束相内,亲水性物质仍留在水相中.再经两相分离,即可实现样品中的目标化合物的分离和富集.浊点萃取法的优点:避免使用对人体有害的挥发性有机溶剂,不污染环境,安全;试剂消耗少,经济;减少萃取时间,快速高效;操作比较简便;对各种分析物具有高的萃取效率,富集倍数大;易于与仪器分析方法联用等.浊点萃取是分离和富集痕量金属离子的有效方法,是一种有发展前途的环境友好的分离富集技术.

  16. Cold and Warm Atomic Gas around the Perseus Molecular Cloud. II. The Impact of High Optical Depth on the HI Column Density Distribution and Its Implication for the HI-to-H2 Transition

    CERN Document Server

    Lee, Min-Young; Murray, Claire E; Heiles, Carl; Miller, Jesse

    2015-01-01

    We investigate the impact of high optical depth on the HI surface density (Sigma_HI) saturation observed in the Perseus molecular cloud. We use Arecibo HI emission and absorption measurements obtained toward 26 radio continuum sources to derive the spin temperature and optical depth of individual HI components along each line of sight. The derived properties are used to estimate the correction for high optical depth. We examine two different methods for the correction, Gaussian decomposition and isothermal approximation methods, and find that they are consistent as having the maximum correction factor of ~1.2 likely due to the relatively low optical depth and insignificant contribution from the diffuse radio continuum emission for Perseus. We apply the correction to the HI column density image derived in the optically thin approximation on a pixel-by-pixel basis, and find that the total HI mass increases by only ~10%. Using the corrected HI column density image and far-infrared data from the Improved Reproces...

  17. Molecular Cloud Formation Behind Shock Waves

    CERN Document Server

    Bergin, E A; Raymond, J C; Ballesteros-Paredes, J

    2004-01-01

    We examine the formation of molecular gas behind shocks in atomic gas using a chemical/dynamical model, particular emphasis is given to constraints the chemistry places on the dynamical evolution. The most important result of this study is to stress the importance of shielding the molecular gas from the destructive effects of UV radiation. For shock ram pressures comparable to or exceeding typical local ISM pressures, self-shielding controls the formation time of H2 but CO formation requires shielding of the interstellar radiation field by dust grains. We find that the molecular hydrogen fractional abundance can become significant well before CO forms. The timescale for (CO) molecular cloud formation is not set by H2 formation, but rather by the timescale for accumulating a sufficient column density or extinction, A_V > 0.7. The local ratio of atomic to molecular gas (4:1), coupled with short estimates for cloud lifetimes (3-5 Myr), suggests that the timescales for accumulating molecular clouds from atomic ma...

  18. Atom as a "Dressed" Nucleus

    CERN Document Server

    Kalitvianski, V

    2008-01-01

    It is shown that electrostatic potential of atomic nucleus seen by a fast charged projectile at short distances is quite smeared due to nucleus motion around the atomic center of inertia. For example, the size of positive charge cloud in the Hydrogen ground state is much larger than the proper proton size. It is even bigger for the target atom in an excited state. Therefore the elastic scattering at large angles is generally weaker than the Rutherford one. In other words, the resulting elastic interaction with an atom at short distances is softer than the Colombian one due to a natural cutoff. In addition, the large angle scattering leads to the target atom excitations due to hitting the nucleus (inelastic processes). It is also shown that the Rutherford cross section is in fact the inclusive rather than the elastic one. These results are analogous to the QED ones. The difference and the value of the presented below non relativistic atomic calculations is in non perturbatively (exact) dressing that immediatel...

  19. NASA Glenn Icing Research Tunnel: Upgrade and Cloud Calibration

    Science.gov (United States)

    VanZante, Judith Foss; Ide, Robert F.; Steen, Laura E.

    2012-01-01

    In 2011, NASA Glenn s Icing Research Tunnel underwent a major modification to it s refrigeration plant and heat exchanger. This paper presents the results of the subsequent full cloud calibration. Details of the calibration procedure and results are presented herein. The steps include developing a nozzle transfer map, establishing a uniform cloud, conducting a drop sizing calibration and finally a liquid water content calibration. The goal of the calibration is to develop a uniform cloud, and to build a transfer map from the inputs of air speed, spray bar atomizing air pressure and water pressure to the output of median volumetric droplet diameter and liquid water content.

  20. Cloud Robotics Model

    Directory of Open Access Journals (Sweden)

    Gyula Mester

    2015-01-01

    Full Text Available Cloud Robotics was born from the merger of service robotics and cloud technologies. It allows robots to benefit from the powerful computational, storage, and communications resources of modern data centres. Cloud robotics allows robots to take advantage of the rapid increase in data transfer rates to offload tasks without hard real time requirements. Cloud Robotics has rapidly gained momentum with initiatives by companies such as Google, Willow Garage and Gostai as well as more than a dozen active research projects around the world. The presentation summarizes the main idea, the definition, the cloud model composed of essential characteristics, service models and deployment models, planning task execution and beyond. Finally some cloud robotics projects are discussed.

  1. Encyclopedia of cloud computing

    CERN Document Server

    Bojanova, Irena

    2016-01-01

    The Encyclopedia of Cloud Computing provides IT professionals, educators, researchers and students with a compendium of cloud computing knowledge. Authored by a spectrum of subject matter experts in industry and academia, this unique publication, in a single volume, covers a wide range of cloud computing topics, including technological trends and developments, research opportunities, best practices, standards, and cloud adoption. Providing multiple perspectives, it also addresses questions that stakeholders might have in the context of development, operation, management, and use of clouds. Furthermore, it examines cloud computing's impact now and in the future. The encyclopedia presents 56 chapters logically organized into 10 sections. Each chapter covers a major topic/area with cross-references to other chapters and contains tables, illustrations, side-bars as appropriate. Furthermore, each chapter presents its summary at the beginning and backend material, references and additional resources for further i...

  2. Entangled Cloud Storage

    DEFF Research Database (Denmark)

    Ateniese, Giuseppe; Dagdelen, Özgür; Damgård, Ivan Bjerre

    2012-01-01

    Entangled cloud storage enables a set of clients {P_i} to “entangle” their files {f_i} into a single clew c to be stored by a (potentially malicious) cloud provider S. The entanglement makes it impossible to modify or delete significant part of the clew without affecting all files in c. A clew...... recover their files. We provide theoretical foundations for entangled cloud storage, introducing the notion of an entangled encoding scheme that guarantees strong security requirements capturing the properties above. We also give a concrete construction based on privacy-preserving polynomial interpolation......, along with protocols for using the encoding scheme in practice. Protocols for cloud storage find application in the cloud setting, where clients store their files on a remote server and need to be ensured that the cloud provider will not delete their data illegitimately. Current solutions, e.g., based...

  3. Cosmic ray penetration in diffuse clouds

    CERN Document Server

    Morlino, G; Krause, J

    2015-01-01

    Cosmic rays are a fundamental source of ionization for molecular and diffuse clouds, influencing their chemical, thermal, and dynamical evolution. The amount of cosmic rays inside a cloud also determines the $\\gamma$-ray flux produced by hadronic collisions between cosmic rays and cloud material. We study the spectrum of cosmic rays inside and outside of a diffuse cloud, by solving the stationary transport equation for cosmic rays including diffusion, advection and energy losses due to ionization of neutral hydrogen atoms. We found that the cosmic ray spectrum inside a diffuse cloud differs from the one in the interstellar medium (ISM) for energies smaller than $E_{br}\\approx 100$ MeV, irrespective of the model details. Below $E_{br}$, the spectrum is harder (softer) than that in the ISM if the latter is a power law $\\propto p^{-s}$ with $s$ larger (smaller) than $\\sim0.42$. As a consequence also the ionization rate due to CRs is strongly affected. Assuming an average Galactic spectrum similar to the one infe...

  4. CLOUD Experiment - How it works -

    CERN Multimedia

    Jasper Kirkby

    2016-01-01

    A brief tour of the CLOUD experiment at CERN, and its scientific aims. CLOUD uses a special cloud chamber to study the possible link between galactic cosmic rays and cloud formation. The results should contribute much to our fundamental understanding of aerosols and clouds, and their affect on climate.

  5. Considerations for Cloud Security Operations

    OpenAIRE

    Cusick, James

    2016-01-01

    Information Security in Cloud Computing environments is explored. Cloud Computing is presented, security needs are discussed, and mitigation approaches are listed. Topics covered include Information Security, Cloud Computing, Private Cloud, Public Cloud, SaaS, PaaS, IaaS, ISO 27001, OWASP, Secure SDLC.

  6. Laser-Free Cold-Atom Gymnastics

    Science.gov (United States)

    Gould, Harvey; Feinberg, Benedict; Munger, Charles T., Jr.; Nishimura, Hiroshi

    2017-01-01

    We have performed beam transport simulations on ultra cold (2 μK) and cold (130 μK) neutral Cs atoms in the F = M = + 4 (magnetic weak-field seeking) ground state. We use inhomogeneous magnetic fields to focus and accelerate the atoms. Acceleration of neutral atoms by an inhomogeneous magnetic field was demonstrated by Stern and Gerlach in 1922. In the simulations, a two mm diameter cloud of atoms is released to fall under gravity. A magnetic coil focuses the falling atoms. After falling 41 cm, the atoms are reflected in the magnetic fringe field of a solenoid. They return to their starting height, about 0.7 s later, having passed a second time through the focusing coil. The simulations show that > 98 % of ultra cold Cs atoms and > 70 % of cold Cs atoms will survive at least 15 round trips (assuming perfect vacuum). More than 100 simulations were run to optimize coil currents and focusing coil diameter and height. Simulations also show that atoms can be launched into a fountain. An experimental apparatus to test the simulations, is being constructed. This technique may find application in atomic fountain clocks, interferometers, and gravitometers, and may be adaptable for use in microgravity. It may also work with Bose-Einstein condensates of paramagnetic atoms.

  7. Geodesics on Point Clouds

    OpenAIRE

    Hongchuan Yu; Zhang, Jian J.; Zheng Jiao

    2014-01-01

    We present a novel framework to compute geodesics on implicit surfaces and point clouds. Our framework consists of three parts, particle based approximate geodesics on implicit surfaces, Cartesian grid based approximate geodesics on point clouds, and geodesic correction. The first two parts can effectively generate approximate geodesics on implicit surfaces and point clouds, respectively. By introducing the geodesic curvature flow, the third part produces smooth and accurate geodesic solution...

  8. Cryptographic Cloud Storage

    Science.gov (United States)

    Kamara, Seny; Lauter, Kristin

    We consider the problem of building a secure cloud storage service on top of a public cloud infrastructure where the service provider is not completely trusted by the customer. We describe, at a high level, several architectures that combine recent and non-standard cryptographic primitives in order to achieve our goal. We survey the benefits such an architecture would provide to both customers and service providers and give an overview of recent advances in cryptography motivated specifically by cloud storage.

  9. CLOUD COMPUTING SECURITY

    Directory of Open Access Journals (Sweden)

    DANISH JAMIL,

    2011-04-01

    Full Text Available It is no secret that cloud computing is becoming more and more popular today and is ever increasing inpopularity with large companies as they share valuable resources in a cost effective way. Due to this increasingdemand for more clouds there is an ever growing threat of security becoming a major issue. This paper shalllook at ways in which security threats can be a danger to cloud computing and how they can be avoided.

  10. Cloud Detection with MATLAB

    OpenAIRE

    P. Shrivastava

    2013-01-01

    The accurate detection of clouds in satellite imagery is important in research and operational applications. Cloud cover influences the distribution of solar radiation reaching the ground where it is absorbed. Resulting fluxes of sensible and latent heat are critical to the accurate characterization of boundary layer behavior and mesoscale circulations that often lead to convective development. Therefore the spatial and temporal variation in cloud cover can greatly affect regional an...

  11. Collisional Decoherence in Trapped-Atom Interferometers that use Nondegenerate Sources

    Science.gov (United States)

    2009-01-22

    atomic cloud experiences a nonuniform potential during the interferometer cycle, the density echoes will be shifted relative to the initial modula- tion...verify the analytic model. 15. SUBJECT TERMS Topside ionosphere Electron density Ionospheric model Altitude profile 16. SECURITY CLASSIFICATION OF: a...sensitive free space atom in- terferometers, the atomic clouds travel up to 10 meters [21. The large scale of free space interferometers limits their

  12. Refractive Index Enhancement in Atomic Media

    Science.gov (United States)

    Proite, Nicholas; Sikes, Daniel; Yavuz, Deniz

    2010-03-01

    We experimentally demonstrate a scheme where a laser beam experiences refractive index enhancement with vanishing absorption. The essential idea is to excite two Raman resonances with appropriately chosen strong laser beams in a far-off resonant atomic system. We have performed our experiments both in vapor cells and in ultracold atomic clouds. Additionally, we discuss a new scheme that achieves giant Kerr nonlinearities using refractive index enhancement. This scheme does not require an intense coupling laser and has the potential to produce all-optical switches and distributed Bragg reflectors at a total energy requirement of tens of photons per atomic cross section.

  13. An Atom Trap Relying on Optical Pumping

    CERN Document Server

    Bouyer, P; Dahan, M B; Michaud, A; Salomon, C; Dalibard, J

    1994-01-01

    We have investigated a new radiation pressure trap which relies on optical pumping and does not require any magnetic field. It employs six circularly polarized divergent beams and works on the red of a $J_{g} \\longrightarrow J_{e} = J_{g} + 1$ atomic transition with $J_{g} \\geq 1/2$. We have demonstrated this trap with cesium atoms from a vapour cell using the 852 nm $J_{g} = 4 \\longrightarrow J_{e} = 5$ resonance transition. The trap contained up to $3 \\cdot 10^{7}$ atoms in a cloud of $1/\\sqrt{e}$ radius of 330 $\\mu$m.

  14. Imaging of microwave fields using ultracold atoms

    CERN Document Server

    Boehi, Pascal; Haensch, Theodor W; Treutlein, Philipp; 10.1063/1.3470591

    2010-01-01

    We report a technique that uses clouds of ultracold atoms as sensitive, tunable, and non-invasive probes for microwave field imaging with micrometer spatial resolution. The microwave magnetic field components drive Rabi oscillations on atomic hyperfine transitions whose frequency can be tuned with a static magnetic field. Readout is accomplished using state-selective absorption imaging. Quantitative data extraction is simple and it is possible to reconstruct the distribution of microwave magnetic field amplitudes and phases. While we demonstrate 2d imaging, an extension to 3d imaging is straightforward. We use the method to determine the microwave near-field distribution around a coplanar waveguide integrated on an atom chip.

  15. Nanoscale atomic waveguides with suspended carbon nanotubes

    CERN Document Server

    Peano, V; Kasper, A; Egger, R

    2005-01-01

    We propose an experimentally viable setup for the realization of one-dimensional ultracold atom gases in a nanoscale magnetic waveguide formed by single doubly-clamped suspended carbon nanotubes. We show that all common decoherence and atom loss mechanisms are small guaranteeing a stable operation of the trap. Since the extremely large current densities in carbon nanotubes are spatially homogeneous, our proposed architecture allows to overcome the problem of fragmentation of the atom cloud. Adding a second nanowire allows to create a double-well potential with a moderate tunneling barrier which is desired for tunneling and interference experiments with the advantage of tunneling distances being in the nanometer regime.

  16. Cloud Computing: An Overview

    Science.gov (United States)

    Qian, Ling; Luo, Zhiguo; Du, Yujian; Guo, Leitao

    In order to support the maximum number of user and elastic service with the minimum resource, the Internet service provider invented the cloud computing. within a few years, emerging cloud computing has became the hottest technology. From the publication of core papers by Google since 2003 to the commercialization of Amazon EC2 in 2006, and to the service offering of AT&T Synaptic Hosting, the cloud computing has been evolved from internal IT system to public service, from cost-saving tools to revenue generator, and from ISP to telecom. This paper introduces the concept, history, pros and cons of cloud computing as well as the value chain and standardization effort.

  17. CLOUD TECHNOLOGY IN EDUCATION

    Directory of Open Access Journals (Sweden)

    Alexander N. Dukkardt

    2014-01-01

    Full Text Available This article is devoted to the review of main features of cloud computing that can be used in education. Particular attention is paid to those learning and supportive tasks, that can be greatly improved in the case of the using of cloud services. Several ways to implement this approach are proposed, based on widely accepted models of providing cloud services. Nevertheless, the authors have not ignored currently existing problems of cloud technologies , identifying the most dangerous risks and their impact on the core business processes of the university. 

  18. JINR cloud infrastructure evolution

    Science.gov (United States)

    Baranov, A. V.; Balashov, N. A.; Kutovskiy, N. A.; Semenov, R. N.

    2016-09-01

    To fulfil JINR commitments in different national and international projects related to the use of modern information technologies such as cloud and grid computing as well as to provide a modern tool for JINR users for their scientific research a cloud infrastructure was deployed at Laboratory of Information Technologies of Joint Institute for Nuclear Research. OpenNebula software was chosen as a cloud platform. Initially it was set up in simple configuration with single front-end host and a few cloud nodes. Some custom development was done to tune JINR cloud installation to fit local needs: web form in the cloud web-interface for resources request, a menu item with cloud utilization statistics, user authentication via Kerberos, custom driver for OpenVZ containers. Because of high demand in that cloud service and its resources over-utilization it was re-designed to cover increasing users' needs in capacity, availability and reliability. Recently a new cloud instance has been deployed in high-availability configuration with distributed network file system and additional computing power.

  19. A cloud storage overlay to aggregate heterogeneous cloud services

    OpenAIRE

    Machado, Guilherme Sperb; Bocek, Thomas; Ammann, Michael; Stiller, Burkhard

    2013-01-01

    Many Cloud services provide generic (e.g., Amazon S3 or Dropbox) or data-specific Cloud storage (e.g., Google Picasa or SoundCloud). Although both Cloud storage service types have the data storage in common, they present heterogeneous characteristics: different interfaces, accounting and charging schemes, privacy and security levels, functionality and, among the data-specific Cloud storage services, different data type restrictions. This paper proposes PiCsMu (Platform-independent Cloud Stora...

  20. Classification of Clouds in Satellite Imagery Using Adaptive Fuzzy Sparse Representation.

    Science.gov (United States)

    Jin, Wei; Gong, Fei; Zeng, Xingbin; Fu, Randi

    2016-12-16

    Automatic cloud detection and classification using satellite cloud imagery have various meteorological applications such as weather forecasting and climate monitoring. Cloud pattern analysis is one of the research hotspots recently. Since satellites sense the clouds remotely from space, and different cloud types often overlap and convert into each other, there must be some fuzziness and uncertainty in satellite cloud imagery. Satellite observation is susceptible to noises, while traditional cloud classification methods are sensitive to noises and outliers; it is hard for traditional cloud classification methods to achieve reliable results. To deal with these problems, a satellite cloud classification method using adaptive fuzzy sparse representation-based classification (AFSRC) is proposed. Firstly, by defining adaptive parameters related to attenuation rate and critical membership, an improved fuzzy membership is introduced to accommodate the fuzziness and uncertainty of satellite cloud imagery; secondly, by effective combination of the improved fuzzy membership function and sparse representation-based classification (SRC), atoms in training dictionary are optimized; finally, an adaptive fuzzy sparse representation classifier for cloud classification is proposed. Experiment results on FY-2G satellite cloud image show that, the proposed method not only improves the accuracy of cloud classification, but also has strong stability and adaptability with high computational efficiency.

  1. Atomic theories

    CERN Document Server

    Loring, FH

    2014-01-01

    Summarising the most novel facts and theories which were coming into prominence at the time, particularly those which had not yet been incorporated into standard textbooks, this important work was first published in 1921. The subjects treated cover a wide range of research that was being conducted into the atom, and include Quantum Theory, the Bohr Theory, the Sommerfield extension of Bohr's work, the Octet Theory and Isotopes, as well as Ionisation Potentials and Solar Phenomena. Because much of the material of Atomic Theories lies on the boundary between experimentally verified fact and spec

  2. Software for Hydrogenic Atoms and Orbitals Visualization

    Directory of Open Access Journals (Sweden)

    Kowit KITTIWUTTHISAKDI

    2005-06-01

    Full Text Available A program was developed in java for hydrogenic atoms and orbitals visualization. The first 18 atoms in the periodic table were approximated with a hydrogenic wave-function. This simple hydrogenic wave-function allowed quick calculation for real-time interactive visualization. Electron cloud based models were employed and displayed by a ray-tracing technique. One or more orbitals that defined an atom could be selected and displayed. A user could zoom in, zoom out, and rotate the displayed cloud in real time. The approximation method for probability integrals was summation. The intensity of color at each point on the screen directly related to the integrated probability in finding the electron across the viewer%s eye path.

  3. VMware vCloud security

    CERN Document Server

    Sarkar, Prasenjit

    2013-01-01

    VMware vCloud Security provides the reader with in depth knowledge and practical exercises sufficient to implement a secured private cloud using VMware vCloud Director and vCloud Networking and Security.This book is primarily for technical professionals with system administration and security administration skills with significant VMware vCloud experience who want to learn about advanced concepts of vCloud security and compliance.

  4. Cloud point extraction of iron(III) and vanadium(V) using 8-quinolinol derivatives and Triton X-100 and determination of 10(-7)moldm(-3) level iron(III) in riverine water reference by a graphite furnace atomic absorption spectroscopy.

    Science.gov (United States)

    Ohashi, Akira; Ito, Hiromi; Kanai, Chikako; Imura, Hisanori; Ohashi, Kousaburo

    2005-01-30

    The cloud point extraction behavior of iron(III) and vanadium(V) using 8-quinolinol derivatives (HA) such as 8-quinolinol (HQ), 2-methyl-8-quinolinol (HMQ), 5-butyloxymethyl-8-quinolinol (HO(4)Q), 5-hexyloxymethyl-8-quinolinol (HO(6)Q), and 2-methyl-5-octyloxymethyl-8-quinolinol (HMO(8)Q) and Triton X-100 solution was investigated. Iron(III) was extracted with HA and 4% (v/v) Triton X-100 in the pH range of 1.70-5.44. Above pH 4.0, more than 95% of iron(III) was extracted with HQ, HMQ, and HMO(8)Q. Vanadium(V) was also extracted with HA and 4% (v/v) Triton X-100 in the pH range of 2.07-5.00, and the extractability increased in the following order of HMQ atomic absorption spectroscopy. When 1.25 x 10(-3)M HMQ and 1% (v/v) Triton X-100 were used, the found values showed a good agreement with the certified ones within the 2% of the R.S.D. Moreover, the effect of an alkyl group on the solubility of 5-alkyloxymethyl-8-quinolinol and 2-methyl-5-alkyloxymethyl-8-quinolinol in 4% (v/v) Triton X-100 at 25 degrees C was also investigated.

  5. Cloud speed sensor

    Directory of Open Access Journals (Sweden)

    V. Fung

    2013-10-01

    Full Text Available Changing cloud cover is a major source of solar radiation variability and poses challenges for the integration of solar energy. A compact and economical system that measures cloud motion vectors to estimate power plant ramp rates and provide short term solar irradiance forecasts is presented. The Cloud Speed Sensor (CSS is constructed using an array of luminance sensors and high-speed data acquisition to resolve the progression of cloud passages across the sensor footprint. An embedded microcontroller acquires the sensor data and uses a cross-correlation algorithm to determine cloud motion vectors. The CSS was validated against an artificial shading test apparatus, an alternative method of cloud motion detection from ground measured irradiance (Linear Cloud Edge, LCE, and a UC San Diego Sky Imager (USI. The CSS detected artificial shadow directions and speeds to within 15 and 6% accuracy, respectively. The CSS detected (real cloud directions and speeds without average bias and with average weighted root mean square difference of 22° and 1.9 m s−1 when compared to USI and 33° and 1.5 m s−1 when compared to LCE results.

  6. The California Molecular Cloud

    CERN Document Server

    Lada, Charles J; Alves, Joao F

    2009-01-01

    We present an analysis of wide-field infrared extinction maps of a region in Perseus just north of the Taurus-Auriga dark cloud complex. From this analysis we have identified a massive, nearby, but previously unrecognized, giant molecular cloud (GMC). From comparison of foreground star counts with Galactic models we derive a distance of 450 +/- 23 parsecs to the cloud. At this distance the cloud extends over roughly 80 pc and has a mass of approximately 10^5 solar masses, rivaling the Orion (A) Molecular Cloud as the largest and most massive GMC in the solar neighborhood. Although surprisingly similar in mass and size to the more famous Orion Molecular Cloud (OMC) the newly recognized cloud displays significantly less star formation activity with more than an order of magnitude fewer young stellar objects than found in the OMC, suggesting that both the level of star formation and perhaps the star formation rate in this cloud are an order of magnitude or more lower than in the OMC. Analysis of extinction maps ...

  7. Clouds in Planetary Atmospheres

    Science.gov (United States)

    West, R.; Murdin, P.

    2000-11-01

    What are clouds? The answer to that question is both obvious and subtle. In the terrestrial atmosphere clouds are familiar as vast collections of small water drops or ice crystals suspended in the air. In the atmospheres of Venus, Mars, Jupiter, Saturn, Saturn's moon Titan, Uranus, Neptune, and possibly Pluto, they are composed of several other substances including sulfuric acid, ammonia, hydroge...

  8. Absorption imaging of a single atom

    Science.gov (United States)

    Streed, Erik W.; Jechow, Andreas; Norton, Benjamin G.; Kielpinski, David

    2012-07-01

    Absorption imaging has played a key role in the advancement of science from van Leeuwenhoek's discovery of red blood cells to modern observations of dust clouds in stellar nebulas and Bose-Einstein condensates. Here we show the first absorption imaging of a single atom isolated in a vacuum. The optical properties of atoms are thoroughly understood, so a single atom is an ideal system for testing the limits of absorption imaging. A single atomic ion was confined in an RF Paul trap and the absorption imaged at near wavelength resolution with a phase Fresnel lens. The observed image contrast of 3.1 (3)% is the maximum theoretically allowed for the imaging resolution of our set-up. The absorption of photons by single atoms is of immediate interest for quantum information processing. Our results also point out new opportunities in imaging of light-sensitive samples both in the optical and X-ray regimes.

  9. Cloud Computing Quality

    Directory of Open Access Journals (Sweden)

    Anamaria Şiclovan

    2013-02-01

    Full Text Available

    Cloud computing was and it will be a new way of providing Internet services and computers. This calculation approach is based on many existing services, such as the Internet, grid computing, Web services. Cloud computing as a system aims to provide on demand services more acceptable as price and infrastructure. It is exactly the transition from computer to a service offered to the consumers as a product delivered online. This paper is meant to describe the quality of cloud computing services, analyzing the advantages and characteristics offered by it. It is a theoretical paper.

    Keywords: Cloud computing, QoS, quality of cloud computing

  10. Cloud computing security.

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Dongwan; Claycomb, William R.; Urias, Vincent E.

    2010-10-01

    Cloud computing is a paradigm rapidly being embraced by government and industry as a solution for cost-savings, scalability, and collaboration. While a multitude of applications and services are available commercially for cloud-based solutions, research in this area has yet to fully embrace the full spectrum of potential challenges facing cloud computing. This tutorial aims to provide researchers with a fundamental understanding of cloud computing, with the goals of identifying a broad range of potential research topics, and inspiring a new surge in research to address current issues. We will also discuss real implementations of research-oriented cloud computing systems for both academia and government, including configuration options, hardware issues, challenges, and solutions.

  11. Prebiotic chemistry in clouds

    Science.gov (United States)

    Oberbeck, Verne R.; Marshall, John; Shen, Thomas

    1991-01-01

    The chemical evolution hypothesis of Woese (1979), according to which prebiotic reactions occurred rapidly in droplets in giant atmospheric reflux columns was criticized by Scherer (1985). This paper proposes a mechanism for prebiotic chemistry in clouds that answers Scherer's concerns and supports Woese's hypothesis. According to this mechanism, rapid prebiotic chemical evolution was facilitated on the primordial earth by cycles of condensation and evaporation of cloud drops containing clay condensation nuclei and nonvolatile monomers. For example, amino acids supplied by, or synthesized during entry of meteorites, comets, and interplanetary dust, would have been scavenged by cloud drops containing clay condensation nuclei and would be polymerized within cloud systems during cycles of condensation, freezing, melting, and evaporation of cloud drops.

  12. Cloud computing basics

    CERN Document Server

    Srinivasan, S

    2014-01-01

    Cloud Computing Basics covers the main aspects of this fast moving technology so that both practitioners and students will be able to understand cloud computing. The author highlights the key aspects of this technology that a potential user might want to investigate before deciding to adopt this service. This book explains how cloud services can be used to augment existing services such as storage, backup and recovery. Addressing the details on how cloud security works and what the users must be prepared for when they move their data to the cloud. Also this book discusses how businesses could prepare for compliance with the laws as well as industry standards such as the Payment Card Industry.

  13. CLOUD COMPUTING AND SECURITY

    Directory of Open Access Journals (Sweden)

    Asharani Shinde

    2015-10-01

    Full Text Available This document gives an insight into Cloud Computing giving an overview of key features as well as the detail study of exact working of Cloud computing. Cloud Computing lets you access all your application and documents from anywhere in the world, freeing you from the confines of the desktop thus making it easier for group members in different locations to collaborate. Certainly cloud computing can bring about strategic, transformational and even revolutionary benefits fundamental to future enterprise computing but it also offers immediate and pragmatic opportunities to improve efficiencies today while cost effectively and systematically setting the stage for the strategic change. As this technology makes the computing, sharing, networking easy and interesting, we should think about the security and privacy of information too. Thus the key points we are going to be discussed are what is cloud, what are its key features, current applications, future status and the security issues and the possible solutions.

  14. Solar variability and clouds

    CERN Document Server

    Kirkby, Jasper

    2000-01-01

    Satellite observations have revealed a surprising imprint of the 11- year solar cycle on global low cloud cover. The cloud data suggest a correlation with the intensity of Galactic cosmic rays. If this apparent connection between cosmic rays and clouds is real, variations of the cosmic ray flux caused by long-term changes in the solar wind could have a significant influence on the global energy radiation budget and the climate. However a direct link between cosmic rays and clouds has not been unambiguously established and, moreover, the microphysical mechanism is poorly understood. New experiments are being planned to find out whether cosmic rays can affect cloud formation, and if so how. (37 refs).

  15. Measurement of the temperature of atomic ensembles via \\emph{which-way} information

    CERN Document Server

    León-Montiel, R de J

    2011-01-01

    We unveil the relationship existing between the temperature of an atomic ensemble of three-level atoms in a $\\Lambda$-configuration, and the width of the emission cone of Stokes photons that are spontaneously emitted when atoms are excited by an optical beam. This relationship, which is based on the amount of \\emph{which-way} information available about where the Stokes photon originated during the interaction, allow us to put forward a new scheme to determine the temperature of atomic clouds by measuring the width of the emission cone. Unlike the commonly used time-of-flight measurements, with this new technique, the atomic cloud is not destroyed during each measurement.

  16. Gold volatile species atomization and preconcentration in quartz devices for atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Arslan, Yasin [Institute of Analytical Chemistry of the ASCR, v. v. i., Veveří 97, 602 00 Brno (Czech Republic); Mehmet Akif Ersoy University, Faculty of Arts & Sciences, Chemistry Department, 15030 Burdur (Turkey); Musil, Stanislav; Matoušek, Tomáš; Kratzer, Jan [Institute of Analytical Chemistry of the ASCR, v. v. i., Veveří 97, 602 00 Brno (Czech Republic); Dědina, Jiří, E-mail: dedina@biomed.cas.cz [Institute of Analytical Chemistry of the ASCR, v. v. i., Veveří 97, 602 00 Brno (Czech Republic)

    2015-01-01

    The on-line atomization of gold volatile species was studied and the results were compared with thermodynamic calculations in several quartz atomizers, namely: diffusion flame, flame-in-gas-shield, flame-in-plain-tube, externally heated T-tube and externally heated flame-in-T-tube. Atomization mechanism in the explored devices is proposed, where volatile species are converted to thermodynamically stable AuH at elevated temperature over 500 °C and then atomized by an interaction with a cloud of hydrogen radicals. Because of its inherent simplicity and robustness, diffusion flame was employed as a reference atomizer. It yielded atomization efficiency of 70 to 100% and a very good long time reproducibility of peak area sensitivity: 1.6 to 1.8 s μg{sup −1}. Six and eleven times higher sensitivity, respectively, was provided by atomizers with longer light paths in the observation volume, i.e. externally heated T-tube and externally heated flame-in-T-tube. The latter one, offering limit of detection below 0.01 μg ml{sup −1}, appeared as the most prospective for on-line atomization. Insight into the mechanism of atomization of gold volatile species, into the fate of free atoms and into subsequent analyte transfer allowed to assess possibilities of in-atomizer preconcentration of gold volatile species: it is unfeasible with quartz atomizers but a sapphire tube atomizer could be useful in this respect. - Highlights: • On-line atomization of gold volatile species for AAS in quartz devices was studied. • Atomization mechanism was proposed and atomization efficiency was estimated. • Possibilities of in-atomizer preconcentration of gold volatile species were assessed.

  17. Sub-Doppler temperature measurements of laser-cooled atoms using optical nanofibres

    Science.gov (United States)

    Russell, Laura; Deasy, Kieran; Daly, Mark J.; Morrissey, Michael J.; Chormaic, Síle Nic

    2012-01-01

    We present a method for measuring the average temperature of a cloud of cold 85Rb atoms in a magneto-optical trap using an optical nanofibre. A periodic spatial variation is applied to the magnetic fields generated by the trapping coils and this causes the trap centre to oscillate, which, in turn, causes the cloud of cold atoms to oscillate. The optical nanofibre is used to collect the fluorescence emitted by the cold atoms, and the frequency response between the motion of the centre of the oscillating trap and the cloud of atoms is determined. This allows us to make measurements of cloud temperature both above and below the Doppler limit, thereby paving the way for nanofibres to be integrated with ultracold atoms for hybrid quantum devices.

  18. Optical dipole mirror for cold atoms based on a metallic diffraction grating

    DEFF Research Database (Denmark)

    Kawalec, Tomasz; Bartoszek-Bober, Dobroslawa; Panas, Roman

    2014-01-01

    and numerically determined mirror efficiencies are close to 100%. The intensity of SPPs above a real grating coupler and the atomic trajectories, as well as the momentum dispersion of the atom cloud being reflected, are computed. A suggestion is given as to how the plasmonic mirror might serve as an optical atom...

  19. Turbulence in high latitude molecular clouds

    Science.gov (United States)

    Shore, S. N.; Larosa, T. N.; Magnani, L.; Chastain, R. J.; Costagliola, F.

    We summarize a continuing investigation of turbulence in high-latitude translucent molecular clouds. These low mass (~ 50 M(solar), nearby (~ 100 pc), non-star forming clouds appear to be condensing out of the atomic cirrus and must be forced by external dynamical processes, since they lack internal sources, for which we can distinguish the injection scale for the turbulence. We have now mapped three clouds -- MBM 3, MBM 16, and MBM 40 -- with high spatial (0.03 pc) and velocity resolution (<0.08 km/s) in 12CO(1-0) 13CO(1-0) (NRAO 12m and FCRAO). All three clouds show evidence for large-shear flows and we propose that the turbulent motions are powered by shear-flow instability. The densest gas is structured into filaments but the velocity profiles do not change in going across a filament indicating that shocks are not compressing the gas. The density field is more likely the result of thermal instability. The velocity-size relationship, a commonly used diagnostic of ISM turbulence, does not hold in these clouds: the linewidth does not increase with region size. The centroid velocity probability distribution function (PDF) is a more precise measure of turbulence. In these clouds the PDFs exhibit broad wings, consistent with a Lorentzian distribution and showing evidence non-Gaussian correlated processes. This is a clear signature of intermittency. We have also begun a mapping survey of CS (1-0), CS (2-1), H2CO, and HCO+ at Arecibo and OSO and willdiscuss results for the Polaris flare and L1512. We will also discusssome implications of these studies for the turbulent dissipation in these systems.

  20. Dark Gas in the Translucent Cloud MBM 12

    Science.gov (United States)

    Abrahams, Ryan; Paglione, T.

    2013-01-01

    Gamma-ray studies of nearby molecular clouds show some residual emission after removing emission derived from spatial maps of HI and CO. This residual emission is called “dark gas” and it represents molecular hydrogen not traced by CO. We study the gamma-ray emission from MBM 12, a nearby translucent cloud. These clouds have very low column density which allows UV radiation from the interstellar radiation field to penetrate through the entire cloud. The UV irradiation creates large photodissociation regions in the cloud, where a significant amount of CO is dissociated into atomic carbon. The neutral and ionized atomic carbon should trace the molecular hydrogen in these regions. MBM 12 is free of known sources of high energy cosmic rays, such as OB associations or supernova remnants, and it is both close and extended enough that we expect it to be resolvable in gamma-rays with the Fermi LAT. This makes it an ideal laboratory to identify whether other molecular tracers, such as atomic carbon, can trace the dark gas. We compare the gamma-ray emission with spatial maps of HI, CO, dust, CI, and CII to try to identify the source of the dark gas.

  1. Atomic physics

    Energy Technology Data Exchange (ETDEWEB)

    Livingston, A.E.; Kukla, K.; Cheng, S. [Univ. of Toledo, OH (United States)] [and others

    1995-08-01

    In a collaboration with the Atomic Physics group at Argonne and the University of Toledo, the Atomic Physics group at the University of Notre Dame is measuring the fine structure transition energies in highly-charged lithium-like and helium-like ions using beam-foil spectroscopy. Precise measurements of 2s-2p transition energies in simple (few-electron) atomic systems provide stringent tests of several classes of current atomic- structure calculations. Analyses of measurements in helium-like Ar{sup 16+} have been completed, and the results submitted for publication. A current goal is to measure the 1s2s{sup 3}S{sub 1} - 1s2p{sup 3}P{sub 0} transition wavelength in helium-like Ni{sup 26+}. Measurements of the 1s2s{sup 2}S{sub 1/2} - 1s2p{sup 2}P{sub 1/2,3/2} transition wavelengths in lithium-like Kr{sup 33+} is planned. Wavelength and lifetime measurements in copper-like U{sup 63+} are also expected to be initiated. The group is also participating in measurements of forbidden transitions in helium-like ions. A measurement of the lifetime of the 1s2s{sup 3}S{sub 1} state in Kr{sup 34+} was published recently. In a collaboration including P. Mokler of GSI, Darmstadt, measurements have been made of the spectral distribution of the 2E1 decay continuum in helium-like Kr{sup 34+}. Initial results have been reported and further measurements are planned.

  2. Cloud Scheduler: a resource manager for distributed compute clouds

    CERN Document Server

    Armstrong, P; Bishop, A; Charbonneau, A; Desmarais, R; Fransham, K; Hill, N; Gable, I; Gaudet, S; Goliath, S; Impey, R; Leavett-Brown, C; Ouellete, J; Paterson, M; Pritchet, C; Penfold-Brown, D; Podaima, W; Schade, D; Sobie, R J

    2010-01-01

    The availability of Infrastructure-as-a-Service (IaaS) computing clouds gives researchers access to a large set of new resources for running complex scientific applications. However, exploiting cloud resources for large numbers of jobs requires significant effort and expertise. In order to make it simple and transparent for researchers to deploy their applications, we have developed a virtual machine resource manager (Cloud Scheduler) for distributed compute clouds. Cloud Scheduler boots and manages the user-customized virtual machines in response to a user's job submission. We describe the motivation and design of the Cloud Scheduler and present results on its use on both science and commercial clouds.

  3. Interstellar molecular clouds

    Science.gov (United States)

    Bally, J.

    1986-04-01

    The physical properties of the molecular phase of the interstellar medium are studied with regard to star formation and the structure of the Galaxy. Most observations of molecular clouds are made with single-dish, high-surface precision radio telescopes, with the best resolution attainable at 0.2 to 1 arcmin; the smallest structures that can be resolved are of order 10 to the 17th cm in diameter. It is now believed that: (1) most of the mass of the Galaxy is in the form of giant molecular clouds; (2) the largest clouds and those responsible for most massive star formation are concentrated in spiral arms; (3) the molecular clouds are the sites of perpetual star formation, and are significant in the chemical evolution of the Galaxy; (4) giant molecular clouds determine the evolution of the kinematic properties of galactic disk stars; (5) the total gas content is diminishing with time; and (6) most clouds have supersonic internal motions and do not form stars on a free-fall time scale. It is concluded that though progress has been made, more advanced instruments are needed to inspect the processes operating within stellar nurseries and to study the distribution of the molecular clouds in more distant galaxies. Instruments presently under construction which are designed to meet these ends are presented.

  4. Cloud Computing Law

    CERN Document Server

    Millard, Christopher

    2013-01-01

    This book is about the legal implications of cloud computing. In essence, ‘the cloud’ is a way of delivering computing resources as a utility service via the internet. It is evolving very rapidly with substantial investments being made in infrastructure, platforms and applications, all delivered ‘as a service’. The demand for cloud resources is enormous, driven by such developments as the deployment on a vast scale of mobile apps and the rapid emergence of ‘Big Data’. Part I of this book explains what cloud computing is and how it works. Part II analyses contractual relationships between cloud service providers and their customers, as well as the complex roles of intermediaries. Drawing on primary research conducted by the Cloud Legal Project at Queen Mary University of London, cloud contracts are analysed in detail, including the appropriateness and enforceability of ‘take it or leave it’ terms of service, as well as the scope for negotiating cloud deals. Specific arrangements for public sect...

  5. Cloud Computing: A study of cloud architecture and its patterns

    Directory of Open Access Journals (Sweden)

    Mandeep Handa,

    2015-05-01

    Full Text Available Cloud computing is a general term for anything that involves delivering hosted services over the Internet. Cloud computing is a paradigm shift following the shift from mainframe to client–server in the early 1980s. Cloud computing can be defined as accessing third party software and services on web and paying as per usage. It facilitates scalability and virtualized resources over Internet as a service providing cost effective and scalable solution to customers. Cloud computing has evolved as a disruptive technology and picked up speed with the presence of many vendors in cloud computing space. The evolution of cloud computing from numerous technological approaches and business models such as SaaS, cluster computing, high performance computing, etc., signifies that the cloud IDM can be considered as a superset of all the corresponding issues from these paradigms and many more. In this paper we will discuss Life cycle management, Cloud architecture, Pattern in Cloud IDM, Volatility of Cloud relations.

  6. DETERMINATION OF CHROMIUM(VI) IN DRUG CAPSULES BY GRAPHITE FURNACE ATOMIC ABSORPTION SPECTROMETRY AFTER CLOUD POINT EXTRACTION%浊点萃取-石墨炉原子吸收光谱法测定药物胶囊中的痕量铬(VI)

    Institute of Scientific and Technical Information of China (English)

    杨平; 陈为键; 陈婷; 温茂云; 陈春凤

    2013-01-01

    采用硝基苯胲铵盐(铜铁试剂)、吡咯烷基二硫代甲酸铵(APDC)为络合剂,Triton X-114为表面活性剂的浊点萃取体系分别富集药物胶囊中的痕量Cr(Ⅲ)和总铬,富集后的Cr(Ⅲ)和总铬用石墨炉原子吸收光谱法进行测定。讨论了溶液pH值、表面活性剂浓度、络合剂浓度、平衡温度、平衡时间等对浊点萃取效率的影响。在优化的实验条件下,Cr(Ⅵ)测定的检出限为0.031μg/L,相对标准偏差为1.2%,加标回收率为98.4%~102.1%。应用本法测定药物胶囊中的痕量Cr(Ⅵ),结果令人满意。%A method was developed for determining trace Cr(VI) and total chromium in drug capsules by graphite furnace atomic absorption spectrometry after cloud point extraction with Cupferron and ammonium pyrrolidine dithiocarbamate(APDC) as complexing agent, triton X-114 as surfactant. The main factors affecting the cloud point extraction, such as pH, concentrations of APDC, Cupferron and Triton X-114, equilibrium temperature and time were studied. Under the optimal conditions, the detection limit of Cr(VI) is 0.031μg/L (S/N=3) with RSD of 1.2% and recovery rate of 98.4% to 102.1%. It is satisfactory to apply the method to the determine trace Chromium in drug capsules samples.

  7. Cloud Computing Services Accounting

    Directory of Open Access Journals (Sweden)

    Igor Ruiz-Agundez

    2012-06-01

    Full Text Available Cloud computing provides a new promising parading to offer services. It brings the opportunity to develop new business models in the Internet. Classic accounting solutions fail to full fill the new requirements of these services due to their structural design. To understand these new constrains, we study the different actors and processes that interact in the Internet Economics. Specifically, we focus on cloud computing introducing a methodology that allows the deployment of cloud services. Further, we present an Infrastructure as a Service (IaaS use case that applies the proposed system.

  8. Trusted cloud computing

    CERN Document Server

    Krcmar, Helmut; Rumpe, Bernhard

    2014-01-01

    This book documents the scientific results of the projects related to the Trusted Cloud Program, covering fundamental aspects of trust, security, and quality of service for cloud-based services and applications. These results aim to allow trustworthy IT applications in the cloud by providing a reliable and secure technical and legal framework. In this domain, business models, legislative circumstances, technical possibilities, and realizable security are closely interwoven and thus are addressed jointly. The book is organized in four parts on "Security and Privacy", "Software Engineering and

  9. Precision Control of Cold Rubidium Atoms

    Science.gov (United States)

    Nic Chormaic, Síle; Deasy, Kieran; Morrissey, Michael; Shortt, Brian; Yarovitskiy, Alexander

    2005-10-01

    Research interest in designing sources of cold atoms has significantly increased during the past 10 years with the development of suitable laser sources for magneto-optical trapping and the further mastering of evaporative cooling in order to achieve Bose-Einstein condensation. The magneto-optical trap is now viewed as a standard research facility worldwide and has opened up many exciting research directions in atomic physics. One area of interest is that of combining spherical microcavities with cold atomic sources in order to achieve efficient photon exchange between the cavity and atom for further understandings of cavity quantum electrodynamics. This could eventually lead to atom entanglement via photon exchange, which would have implications for quantum logic design. However, initial attempts to achieve such interactions have been hindered by inadequate control and manipulation of the cold atom source. Here, we present work on designing and building an ultra-stable source of magneto-optically cooled rubidium atoms with a temperature in the tens of μK range. We present a suitable experimental arrangement including details on the ultra-high vacuum chamber, the laser systems being used, and the source of rubidium vapor. We discuss some future directions for the research, including diffraction of atoms from gratings and micron-sized objects and parameter control of the atom cloud.

  10. Cloud computing basics for librarians.

    Science.gov (United States)

    Hoy, Matthew B

    2012-01-01

    "Cloud computing" is the name for the recent trend of moving software and computing resources to an online, shared-service model. This article briefly defines cloud computing, discusses different models, explores the advantages and disadvantages, and describes some of the ways cloud computing can be used in libraries. Examples of cloud services are included at the end of the article.

  11. Taxonomy of cloud computing services

    NARCIS (Netherlands)

    Hoefer, C.N.; Karagiannis, G.

    2010-01-01

    Cloud computing is a highly discussed topic, and many big players of the software industry are entering the development of cloud services. Several companies want to explore the possibilities and benefits of cloud computing, but with the amount of cloud computing services increasing quickly, the need

  12. The Atomic orbitals of the topological atom

    OpenAIRE

    Ramos-Cordoba, Eloy; Salvador Sedano, Pedro

    2013-01-01

    The effective atomic orbitals have been realized in the framework of Bader's atoms in molecules theory for a general wavefunction. This formalism can be used to retrieve from any type of calculation a proper set of orthonormalized numerical atomic orbitals, with occupation numbers that sum up to the respective Quantum Theory of Atoms in Molecules (QTAIM) atomic populations. Experience shows that only a limited number of effective atomic orbitals exhibit significant occupation numbers. These c...

  13. IBM SmartCloud essentials

    CERN Document Server

    Schouten, Edwin

    2013-01-01

    A practical, user-friendly guide that provides an introduction to cloud computing using IBM SmartCloud, along with a thorough understanding of resource management in a cloud environment.This book is great for anyone who wants to get a grasp of what cloud computing is and what IBM SmartCloud has to offer. If you are an IT specialist, IT architect, system administrator, or a developer who wants to thoroughly understand the cloud computing resource model, this book is ideal for you. No prior knowledge of cloud computing is expected.

  14. Cloud Computing (2/2)

    CERN Document Server

    CERN. Geneva

    2012-01-01

    Cloud computing, the recent years buzzword for distributed computing, continues to attract and keep the interest of both the computing and business world. These lectures aim at explaining "What is Cloud Computing?" identifying and analyzing it's characteristics, models, and applications. The lectures will explore different "Cloud definitions" given by different authors and use them to introduce the particular concepts. The main cloud models (SaaS, PaaS, IaaS), cloud types (public, private, hybrid), cloud standards and security concerns will be presented. The borders between Cloud Computing and Grid Computing, Server Virtualization, Utility Computing will be discussed and analyzed.

  15. Cloud Computing (1/2)

    CERN Document Server

    CERN. Geneva

    2012-01-01

    Cloud computing, the recent years buzzword for distributed computing, continues to attract and keep the interest of both the computing and business world. These lectures aim at explaining "What is Cloud Computing?" identifying and analyzing it's characteristics, models, and applications. The lectures will explore different "Cloud definitions" given by different authors and use them to introduce the particular concepts. The main cloud models (SaaS, PaaS, IaaS), cloud types (public, private, hybrid), cloud standards and security concerns will be presented. The borders between Cloud Computing and Grid Computing, Server Virtualization, Utility Computing will be discussed and analyzed.

  16. Security Architecture of Cloud Computing

    Directory of Open Access Journals (Sweden)

    V.KRISHNA REDDY

    2011-09-01

    Full Text Available The Cloud Computing offers service over internet with dynamically scalable resources. Cloud Computing services provides benefits to the users in terms of cost and ease of use. Cloud Computing services need to address the security during the transmission of sensitive data and critical applications to shared and public cloud environments. The cloud environments are scaling large for data processing and storage needs. Cloud computing environment have various advantages as well as disadvantages on the data security of service consumers. This paper aims to emphasize the main security issues existing in cloud computing environments. The security issues at various levels of cloud computing environment is identified in this paper and categorized based on cloud computing architecture. This paper focuses on the usage of Cloud services and security issues to build these cross-domain Internet-connected collaborations.

  17. The formation of molecular clouds in spiral galaxies

    CERN Document Server

    Dobbs, C L

    2006-01-01

    We present Smoothed Particle Hydrodynamics (SPH) simulations of molecular cloud formation in spiral galaxies. These simulations model the response of a non-self-gravitating gaseous disk to a galactic potential. The formation of molecular gas occurs when cold ($T \\le 100$ K) gas is compressed during the passage of a spiral arm. The spiral arms display considerable structure and the molecular gas accumulates into dense clouds. We identify the formation of these structures as due to the dynamics of clumpy shocks, which perturb the orbits of particles passing through the spiral arm. In addition, the spiral shocks induce a large velocity dispersion in the spiral arms, comparable with the magnitude of the velocity dispersion observed in molecular clouds. The molecular clouds are largely confined to the spiral arms, since most molecular gas is photodissociated to atomic hydrogen upon leaving the arms. However a low photodissociation rate increases the amount of interarm molecular gas, and the possibility of molecula...

  18. NASA Glenn Icing Research Tunnel: 2014 Cloud Calibration

    Science.gov (United States)

    VanZante, Judith Foss; Ide, Robert F.; Steen, Laura; Acosta, Waldo J.

    2014-01-01

    The results of the December 2013 to February 2014 Icing Research Tunnel full icing cloud calibration are being presented to the SAE AC-9C committee, as represented in the 2014 cloud calibration report. The calibration steps included establishing a uniform cloud and conducting drop size and liquid water content calibrations. The goal of the calibration was to develop a uniform cloud, and to generate a transfer function from the inputs of air speed, spray bar atomizing air pressure and water pressure to the outputs of median volumetric drop diameter and liquid water content. This was done for both 14 CFR Parts 25 and 29, Appendix C (typical icing) and soon-to-be released Appendix O (supercooled large drop) conditions.

  19. Hyperfine-induced quadrupole moments of alkali-metal atom ground states and their implications for atomic clocks

    CERN Document Server

    Derevianko, Andrei

    2016-01-01

    Spherically-symmetric ground states of alkali-metal atoms do not posses electric quadrupole moments. However, the hyperfine interaction between nuclear moments and atomic electrons distorts the spherical symmetry of electronic clouds and leads to non-vanishing atomic quadrupole moments. We evaluate these hyperfine-induced quadrupole moments using techniques of relativistic many-body theory and compile results for Li, Na, K, Rb, and Cs atoms. For heavy atoms we find that the hyperfine-induced quadrupole moments are strongly (two orders of magnitude) enhanced by correlation effects. We further apply the results of the calculation to microwave atomic clocks where the coupling of atomic quadrupole moments to gradients of electric fields leads to clock frequency uncertainties. We show that for $^{133}$Cs atomic clocks, the spatial gradients of electric fields must be smaller than $30 \\, \\mathrm{V}/\\mathrm{cm}^2$ to guarantee fractional inaccuracies below $10^{-16}$.

  20. Cloud Computing For Microfinances

    CERN Document Server

    V, Suma; M, Vaidehi; Nair, T R Gopalakrishnan

    2012-01-01

    Evolution of Science and Engineering has led to the growth of several commercial applications. The wide spread implementation of commercial based applications has in turn directed the emergence of advanced technologies such as cloud computing. India has well proven itself as a potential hub for advanced technologies including cloud based industrial market. Microfinance system has emerged out as a panacea to Indian economy since the population encompasses of people who come under poverty and below poverty index. However, one of the key challenges in successful operation of microfinance system in India has given rise to integration of financial services using sophisticated cloud computing model. This paper, therefore propose a fundamental cloud-based microfinance model in order to reduce high transaction risks involved during microfinance operations in an inexpensive and efficient manner.

  1. Reconfigurable Martian Data Cloud

    Science.gov (United States)

    Sheldon, D. J.; Moeller, R. C.; Pingree, P.; Lay, N.; Reeves, G.

    2012-06-01

    The objective is to develop a constellation of small satellites in orbit around Mars that would provide a highly scalable and dynamically allocatable high performance computing resource. Key is use of Field Programmable Gate Arrays for the cloud.

  2. Green symbiotic cloud communications

    CERN Document Server

    Mustafa, H D; Desai, Uday B; Baveja, Brij Mohan

    2017-01-01

    This book intends to change the perception of modern day telecommunications. Communication systems, usually perceived as “dumb pipes”, carrying information / data from one point to another, are evolved into intelligently communicating smart systems. The book introduces a new field of cloud communications. The concept, theory, and architecture of this new field of cloud communications are discussed. The book lays down nine design postulates that form the basis of the development of a first of its kind cloud communication paradigm entitled Green Symbiotic Cloud Communications or GSCC. The proposed design postulates are formulated in a generic way to form the backbone for development of systems and technologies of the future. The book can be used to develop courses that serve as an essential part of graduate curriculum in computer science and electrical engineering. Such courses can be independent or part of high-level research courses. The book will also be of interest to a wide range of readers including b...

  3. Energy scaling of cold atom-atom-ion three-body recombination

    CERN Document Server

    Krükow, Artjom; Härter, Arne; Denschlag, Johannes Hecker; Pérez-Ríos, Jesús; Greene, Chris H

    2015-01-01

    We study three-body recombination of Ba$^+$ + Rb + Rb in the mK regime where a single $^{138}$Ba$^{+}$ ion in a Paul trap is immersed into a cloud of ultracold $^{87}$Rb atoms. We measure the energy dependence of the three-body rate coefficient $k_3$ and compare the results to the theoretical prediction, $k_3 \\propto E_{\\textrm{col}}^{-3/4}$ where $E_{\\textrm{col}}$ is the collision energy. We find agreement if we assume that the non-thermal ion energy distribution is determined by at least two different micro-motion induced energy scales. Furthermore, using classical trajectory calculations we predict how the median binding energy of the formed molecules scales with the collision energy. Our studies give new insights into the kinetics of an ion immersed into an ultracold atom cloud and yield important prospects for atom-ion experiments targeting the s-wave regime.

  4. Underestimation of Oceanic Warm Cloud Occurrences by the Cloud Profiling Radar Aboard CloudSat

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    The Cloud Profi ling Radar (CPR) onboard CloudSat is an active sensor specifi cally dedicated to cloud detection. Compared to passive remote sensors, CPR plays a unique role in investigating the occurrence of multi-layer clouds and depicting the internal vertical structure of clouds. However, owing to contamination from ground clutter, CPR refl ectivity signals are invalid in the lowest 1 km above the surface, leading to numerous missed detections of warm clouds. In this study, by using 1-yr CPR and MODIS (Moderate Resolution Imaging Spectroradiometer) synchronous data, those CPR-missed oceanic warm clouds that are identifi ed as cloudy by MODIS are examined. It is demonstrated that CPR severely underestimates the occurrence of oceanic warm clouds, with a global-average miss rate of about 0.43. Over the tropical and subtropical oceans, the CPR-missed clouds tend to occur in regions with relatively low sea surface temperature. CPR misses almost all warm clouds with cloud tops lower than 1 km, and the miss rate reduces with increasing cloud top. As for clouds with cloud tops higher than 2 km, the negative bias of CPR-captured warm cloud occurrence falls below 3%. The cloud top height of CPR-missed warm clouds ranges from 0.6 to 1.2 km, and these clouds mostly have evidently small optical depths and droplet eff ective radii. The vertically integrated cloud liquid water content of CPR-missed warm clouds is smaller than 50 g m−2 . It is also revealed that CPR misses some warm clouds that have small optical depths or small droplet sizes, besides those limited in the boundary layer below about 1 km due to ground clutter.

  5. Heteronuclear diatomics in diffuse and translucent clouds

    CERN Document Server

    Weselak, T

    2013-01-01

    Diffuse and translucent molecular clouds fill a vast majority of the interstellar space in the galactic disk being thus the most typical objects of the Interstellar Medium (ISM). Recent advances in observational techniques of modern optical and ultraviolet spectroscopy led to detection of many features of atomic and molecular origin in spectra of such clouds. Molecular spectra of heteronuclear diatomic molecules, ie. OH, OH+, CH CH+, CN, NH, CO play an important role in understanding chemistry and physical conditions in environments they do populate. A historical review of astronomical observations of interstellar molecules is presented. Recent results based on visual and ultraviolet observations of molecular features in spectra of reddened, early type OB-stars are presented and discussed. Appearance of vibrational-rotational spectra with observed transitions based on high-quality spectra, are also presented. Relations between column densities of heteronuclear diatomics (based on the recommended oscillator st...

  6. Toward Cloud Computing Evolution

    OpenAIRE

    Susanto, Heru; Almunawar, Mohammad Nabil; Kang, Chen Chin

    2012-01-01

    -Information Technology (IT) shaped the success of organizations, giving them a solid foundation that increases both their level of efficiency as well as productivity. The computing industry is witnessing a paradigm shift in the way computing is performed worldwide. There is a growing awareness among consumers and enterprises to access their IT resources extensively through a "utility" model known as "cloud computing." Cloud computing was initially rooted in distributed grid-based computing. ...

  7. Marine Cloud Brightening

    Energy Technology Data Exchange (ETDEWEB)

    Latham, John; Bower, Keith; Choularton, Tom; Coe, H.; Connolly, P.; Cooper, Gary; Craft, Tim; Foster, Jack; Gadian, Alan; Galbraith, Lee; Iacovides, Hector; Johnston, David; Launder, Brian; Leslie, Brian; Meyer, John; Neukermans, Armand; Ormond, Bob; Parkes, Ben; Rasch, Philip J.; Rush, John; Salter, Stephen; Stevenson, Tom; Wang, Hailong; Wang, Qin; Wood, Robert

    2012-09-07

    The idea behind the marine cloud-brightening (MCB) geoengineering technique is that seeding marine stratocumulus clouds with copious quantities of roughly monodisperse sub-micrometre sea water particles might significantly enhance the cloud droplet number concentration, and thereby the cloud albedo and possibly longevity. This would produce a cooling, which general circulation model (GCM) computations suggest could - subject to satisfactory resolution of technical and scientific problems identified herein - have the capacity to balance global warming up to the carbon dioxide-doubling point. We describe herein an account of our recent research on a number of critical issues associated with MCB. This involves (i) GCM studies, which are our primary tools for evaluating globally the effectiveness of MCB, and assessing its climate impacts on rainfall amounts and distribution, and also polar sea-ice cover and thickness; (ii) high-resolution modelling of the effects of seeding on marine stratocumulus, which are required to understand the complex array of interacting processes involved in cloud brightening; (iii) microphysical modelling sensitivity studies, examining the influence of seeding amount, seedparticle salt-mass, air-mass characteristics, updraught speed and other parameters on cloud-albedo change; (iv) sea water spray-production techniques; (v) computational fluid dynamics studies of possible large-scale periodicities in Flettner rotors; and (vi) the planning of a three-stage limited-area field research experiment, with the primary objectives of technology testing and determining to what extent, if any, cloud albedo might be enhanced by seeding marine stratocumulus clouds on a spatial scale of around 100 km. We stress that there would be no justification for deployment of MCB unless it was clearly established that no significant adverse consequences would result. There would also need to be an international agreement firmly in favour of such action.

  8. Cloud Forensics Issues

    Science.gov (United States)

    2014-07-01

    Cloud Computing , Forensics , IT Security, Standards, Monitoring, Virtualization. I. INTRODUCTION LOUD computing has come to mean many different...an efficient re-allocation of resources. VI. ACCOUNTABILITY, MONITORING AND FORENSICS The goal of computer forensics is to perform a structured...away from the concept of cloud computing [12 - 14]. We believe, however, that a precise statement of the high assurance and forensics requirements

  9. Adolescent Interstellar Cloud Poised to Make Star-forming Debut

    Science.gov (United States)

    2001-06-01

    Astronomers using the National Science Foundation's (NSF) 140-foot radio telescope at the National Radio Astronomy Observatory (NRAO) in Green Bank, W.Va., have discovered a highly unusual, massive interstellar cloud that appears poised to begin a burst of star formation. The cloud may be the first ever to be detected in the transition between atomic and molecular states. NRAO scientists Felix J. Lockman and Anthony H. Minter presented their findings at the American Astronomical Society meeting in Pasadena, Calif. Radio Image of G28.17+0.05 The scientists discovered the cloud, identified as G28.17+0.05, lying along the inner plane of the Milky Way Galaxy, approximately 16,300 light-years from Earth. Observations of the cloud indicate that it is near one of the Galaxy's sweeping spiral arms, which are outlined by young stars and the massive clouds that form them. Lockman and Minter speculate that as the interstellar cloud slams into the Galactic arm, the resulting shock wave may be precipitating the conversion of the neutral hydrogen atoms into heavier molecules, which could herald the onset of star formation. "These may be the first observations of a cloud that is in the transition between the neutral atomic hydrogen and molecular phases," said Lockman. "This provides astronomers a unique opportunity to study the chemistry of very young interstellar clouds, which could give us significant insights into the early stages of star formation and the structure of the Galaxy." Interstellar clouds that contain neutral atomic hydrogen, called HI (H-one) clouds, are thought of as giant, cold blobs of gas. Researchers study these objects because they offer intriguing glimpses of the composition of our Galaxy and the cosmos, and reveal much about how stars and planets are born. Hydrogen atoms in these clouds give off natural signals (at the 21-cm wavelength), which can be detected only by radio telescopes. The scientists discovered that this HI cloud was unusual in many

  10. The diffuse interstellar cloud toward HD 179406 (20 Aquilae)

    Science.gov (United States)

    Hanson, Margaret M.; Snow, Theodore P.; Black, John H.

    1992-01-01

    An analysis of the diffuse interstellar cloud complex in front of HD 179406 (20 Aql) is presented. Along this sight line, multispectral absortion- and emission-line studies have uncovered at least three distinct velocity components due to individual clouds. A dominant velocity component is seen in both the absorption and emission-line data sets at 3 +/- 1 km/s. It is argued that the cloud associated with this velocity component is responsible for most of the atomic and all of the molecular gas in front of 20 Aql. The present chemical and physical analysis of the cloud combines the diagnostic tools of radio emission-line data with those of UV and optical absorption data. Using non-LTE models to synthesize the observed absorption profiles, (C-12)O and (C-13)O column densities along this line of sight are determined. The (C-12)O/(C-13)O abundance ratio was found to be 50 +/- 15, similar to that found by Wannier et al. toward Zeta Oph. The physical conditions of the cloud have been investigated using ultraviolet absorption lines. Measurements indicate that the dominant absorption cloud has a gas pressure similar to that found in the local diffuse molecular cloud in Ophiuchus with nT = 20,000/cu cm K.

  11. CLOUD COMPUTING TECHNOLOGY TRENDS

    Directory of Open Access Journals (Sweden)

    Cristian IVANUS

    2014-05-01

    Full Text Available Cloud computing has been a tremendous innovation, through which applications became available online, accessible through an Internet connection and using any computing device (computer, smartphone or tablet. According to one of the most recent studies conducted in 2012 by Everest Group and Cloud Connect, 57% of companies said they already use SaaS application (Software as a Service, and 38% reported using standard tools PaaS (Platform as a Service. However, in the most cases, the users of these solutions highlighted the fact that one of the main obstacles in the development of this technology is the fact that, in cloud, the application is not available without an Internet connection. The new challenge of the cloud system has become now the offline, specifically accessing SaaS applications without being connected to the Internet. This topic is directly related to user productivity within companies as productivity growth is one of the key promises of cloud computing system applications transformation. The aim of this paper is the presentation of some important aspects related to the offline cloud system and regulatory trends in the European Union (EU.

  12. 环境水样中痕量铜的浊点萃取-火焰原子吸收光谱测定法%Determination of trace copper in environmental water sample by flame atomic absorption spectrometry with cloud point extraction

    Institute of Scientific and Technical Information of China (English)

    钟怡洲; 王梅; 张泽华; 杨冰仪; 黄林玉

    2016-01-01

    目的 建立环境水样中痕量铜的浊点萃取(cloud point extraction,CPE)-火焰原子吸收光谱(flame atomic absorption spectrometry,FAAS)测定法.方法 样品在pH 9.5的条件下,加入0.4 ml的1 mmol/L 2-(5-溴-2-吡啶偶氮)-5-二乙氨基酚(5-Br-PADAP)溶液,0.1%氯化钙溶液0.1 ml,5%(W/V)Triton X-114溶液0.8 ml,40℃加热15 min后离心,采用火焰原子吸收光谱法进行检测.结果 在2~240 μg/L的线性范围内,所得回归方程为A=0.0027c+0.0246,r=0.9958.以3倍信噪比计算,方法的检出限为0.62 μg/L,富集倍数为36.58倍,平均加标回收率为96.28%~98.08%,RSD为1.67%~3.13%.结论 该方法简单、灵敏,具有良好的重现性,适用于环境水样中痕量铜的测定.

  13. Atom Skimmers and Atom Lasers Utilizing Them

    Science.gov (United States)

    Hulet, Randall; Tollett, Jeff; Franke, Kurt; Moss, Steve; Sackett, Charles; Gerton, Jordan; Ghaffari, Bita; McAlexander, W.; Strecker, K.; Homan, D.

    2005-01-01

    Atom skimmers are devices that act as low-pass velocity filters for atoms in thermal atomic beams. An atom skimmer operating in conjunction with a suitable thermal atomic-beam source (e.g., an oven in which cesium is heated) can serve as a source of slow atoms for a magneto-optical trap or other apparatus in an atomic-physics experiment. Phenomena that are studied in such apparatuses include Bose-Einstein condensation of atomic gases, spectra of trapped atoms, and collisions of slowly moving atoms. An atom skimmer includes a curved, low-thermal-conduction tube that leads from the outlet of a thermal atomic-beam source to the inlet of a magneto-optical trap or other device in which the selected low-velocity atoms are to be used. Permanent rare-earth magnets are placed around the tube in a yoke of high-magnetic-permeability material to establish a quadrupole or octupole magnetic field leading from the source to the trap. The atoms are attracted to the locus of minimum magnetic-field intensity in the middle of the tube, and the gradient of the magnetic field provides centripetal force that guides the atoms around the curve along the axis of the tube. The threshold velocity for guiding is dictated by the gradient of the magnetic field and the radius of curvature of the tube. Atoms moving at lesser velocities are successfully guided; faster atoms strike the tube wall and are lost from the beam.

  14. An approach to identify the optimal cloud in cloud federation

    Directory of Open Access Journals (Sweden)

    Saumitra Baleshwar Govil

    2012-01-01

    Full Text Available Enterprises are migrating towards cloud computing for their ability to provide agility, robustness and feasibility in operations. To increase the reliability and availability of services, clouds have grown into federated clouds i.e., union of clouds. There are still major issues in federated clouds, which when solved could lead to increased satisfaction to both service providers and clients alike. One such issue is to select the optimal foreign cloud amongst the federation, which provides services according to the client requirements. In this paper, we propose a model to select the optimal cloud service provider based on the capability and performance of the available clouds in the federation. We use two matrix models to obtain the capability and performance parametric values. They are matched with the client requirements and the optimal foreign cloud service provider is selected.

  15. Bayesian Exploration of Cloud Microphysical Sensitivities in Mesoscale Cloud Systems

    Science.gov (United States)

    Posselt, D. J.

    2015-12-01

    It is well known that changes in cloud microphysical processes can have a significant effect on the structure and evolution of cloud systems. In particular, changes in water phase and the associated energy sources and sinks have a direct influence on cloud mass and precipitation, and an indirect effect on cloud system thermodynamic properties and dynamics. The details of cloud particle nucleation and growth, as well as the interactions among vapor, liquid, and ice phases, occur on scales too small to be explicitly simulated in the vast majority of numerical models. These processes are represented by approximations that introduce uncertainty into the simulation of cloud mass and spatial distribution and by extension the simulation of the cloud system itself. This presentation demonstrates how Bayesian methodologies can be used to explore the relationships between cloud microphysics and cloud content, precipitation, dynamics, and radiative transfer. Specifically, a Markov chain Monte Carlo algorithm is used to compute the probability distribution of cloud microphysical parameters consistent with particular mesoscale environments. Two different physical systems are considered. The first example explores the multivariate functional relationships between precipitation, cloud microphysics, and the environment in a deep convective cloud system. The second examines how changes in cloud microphysical parameters may affect orographic cloud structure, precipitation, and dynamics. In each case, the Bayesian framework can be shown to provide unique information on the inter-dependencies present in the physical system.

  16. A cold 87Rb atomic beam

    Institute of Scientific and Technical Information of China (English)

    Wang Xiao-Jia; Feng Yan-Ying; Xue Hong-Bo; Zhou Zhao-Ying; Zhang Wen-Dong

    2011-01-01

    We demonstrate an experimental setup for the production of a beam source of cold 87Rb atoms.The atoms are extracted from a trapped cold atomic cloud in an unbalanced three-dimensional magneto-optical trap.Via a radiation pressure difference generated by a specially designed leak tunnel along one trapping laser beam,the atoms are pushed out continuously with low velocities and a high flux.The most-probable velocity in the beam is varied from 9 m/s to 19 m/s by varying the detuning of the trapping laser beams in the magneto-optical trap and the flux can be tuned up to 4× 109 s-1 by increasing the intensity of the trapping beams.We also present a simple model for describing the dependence of the beam performance on the magneto-optical trap trapping laser intensity and the detuning.

  17. Cloud networking understanding cloud-based data center networks

    CERN Document Server

    Lee, Gary

    2014-01-01

    Cloud Networking: Understanding Cloud-Based Data Center Networks explains the evolution of established networking technologies into distributed, cloud-based networks. Starting with an overview of cloud technologies, the book explains how cloud data center networks leverage distributed systems for network virtualization, storage networking, and software-defined networking. The author offers insider perspective to key components that make a cloud network possible such as switch fabric technology and data center networking standards. The final chapters look ahead to developments in architectures

  18. Security Problems in Cloud Computing

    Directory of Open Access Journals (Sweden)

    Rola Motawie

    2016-12-01

    Full Text Available Cloud is a pool of computing resources which are distributed among cloud users. Cloud computing has many benefits like scalability, flexibility, cost savings, reliability, maintenance and mobile accessibility. Since cloud-computing technology is growing day by day, it comes with many security problems. Securing the data in the cloud environment is most critical challenges which act as a barrier when implementing the cloud. There are many new concepts that cloud introduces, such as resource sharing, multi-tenancy, and outsourcing, create new challenges for the security community. In this work, we provide a comparable study of cloud computing privacy and security concerns. We identify and classify known security threats, cloud vulnerabilities, and attacks.

  19. Superposition and alignment of labeled point clouds.

    Science.gov (United States)

    Fober, Thomas; Glinca, Serghei; Klebe, Gerhard; Hüllermeier, Eyke

    2011-01-01

    Geometric objects are often represented approximately in terms of a finite set of points in three-dimensional euclidean space. In this paper, we extend this representation to what we call labeled point clouds. A labeled point cloud is a finite set of points, where each point is not only associated with a position in three-dimensional space, but also with a discrete class label that represents a specific property. This type of model is especially suitable for modeling biomolecules such as proteins and protein binding sites, where a label may represent an atom type or a physico-chemical property. Proceeding from this representation, we address the question of how to compare two labeled points clouds in terms of their similarity. Using fuzzy modeling techniques, we develop a suitable similarity measure as well as an efficient evolutionary algorithm to compute it. Moreover, we consider the problem of establishing an alignment of the structures in the sense of a one-to-one correspondence between their basic constituents. From a biological point of view, alignments of this kind are of great interest, since mutually corresponding molecular constituents offer important information about evolution and heredity, and can also serve as a means to explain a degree of similarity. In this paper, we therefore develop a method for computing pairwise or multiple alignments of labeled point clouds. To this end, we proceed from an optimal superposition of the corresponding point clouds and construct an alignment which is as much as possible in agreement with the neighborhood structure established by this superposition. We apply our methods to the structural analysis of protein binding sites.

  20. Interaction between atoms and slow light: a design study

    CERN Document Server

    Zang, Xiaorun; Faggiani, Rémi; Gill, Christopher; Petrov, Plamen G; Hugonin, Jean-Paul; Bernon, Simon; Bouyer, Philippe; Boyer, Vincent; Lalanne, Philippe

    2015-01-01

    The emerging field of on-chip integration of nanophotonic devices and cold atoms offers extremely-strong and pure light-matter interaction schemes, which may have profound impact on quantum information science. In this context, a longstanding obstacle is to achieve strong interaction between single atoms and single photons, while at the same time trap atoms in vacuum at large separation distances from dielectric surfaces. In this letter, we study new waveguide geometries that challenge these conflicting objectives. The designed photonic crystal waveguide is expected to offer a good compromise, which additionally allow for easy manipulation of atomic clouds around the structure.

  1. Immersing carbon nano-tubes in cold atomic gases

    OpenAIRE

    2013-01-01

    We investigate the sympathetic relaxation of a free-standing, vibrating carbon nano-tube that is mounted on an atom chip and is immersed in a cloud of ultra-cold atoms. Gas atoms colliding with the nano-tube excite phonons via a Casimir-Polder potential. We use Fermi's Golden Rule to estimate the relaxation rates for relevant experimental parameters and develop a fully dynamic theory of relaxation for the multi-mode phononic field embedded in a thermal atomic reservoir. Based on currently ava...

  2. Atomic magnetometer

    Science.gov (United States)

    Schwindt, Peter [Albuquerque, NM; Johnson, Cort N [Albuquerque, NM

    2012-07-03

    An atomic magnetometer is disclosed which uses a pump light beam at a D1 or D2 transition of an alkali metal vapor to magnetically polarize the vapor in a heated cell, and a probe light beam at a different D2 or D1 transition to sense the magnetic field via a polarization rotation of the probe light beam. The pump and probe light beams are both directed along substantially the same optical path through an optical waveplate and through the heated cell to an optical filter which blocks the pump light beam while transmitting the probe light beam to one or more photodetectors which generate electrical signals to sense the magnetic field. The optical waveplate functions as a quarter waveplate to circularly polarize the pump light beam, and as a half waveplate to maintain the probe light beam linearly polarized.

  3. Non-destructive Faraday imaging of dynamically controlled ultracold atoms

    DEFF Research Database (Denmark)

    Gajdacz, Miroslav; Pedersen, Poul Lindholm; Mørch, Troels

    2013-01-01

    We describe an easily implementable method for non-destructive measurements of ultracold atomic clouds based on dark field imaging of spatially resolved Faraday rotation. The signal-to-noise ratio is analyzed theoretically and, in the absence of experimental imperfections, the sensitivity limit...... is found to be identical to other conventional dispersive imaging techniques. The dependence on laser detuning, atomic density, and temperature is characterized in a detailed comparison with theory. Due to low destructiveness, spatially resolved images of the same cloud can be acquired up to 2000 times...

  4. High Atom Number in Microsized Atom Traps

    Science.gov (United States)

    2015-12-14

    Final Performance Report on ONR Grant N00014-12-1-0608 High atom number in microsized atom traps for the period 15 May 2012 through 14 September...TYPE Final Technical Report 3. DATES COVERED (From - To) 05/15/2012-09/14/2012 4. TITLE AND SUBTITLE High atom number in microsized atom traps...forces for implementing a small-footprint, large-number atom -chip instrument. Bichromatic forces rely on absorption and stimulated emission to produce

  5. Trust management in cloud services

    CERN Document Server

    Noor, Talal H; Bouguettaya, Athman

    2014-01-01

    This book describes the design and implementation of Cloud Armor, a novel approach for credibility-based trust management and automatic discovery of cloud services in distributed and highly dynamic environments. This book also helps cloud users to understand the difficulties of establishing trust in cloud computing and the best criteria for selecting a service cloud. The techniques have been validated by a prototype system implementation and experimental studies using a collection of real world trust feedbacks on cloud services.The authors present the design and implementation of a novel pro

  6. The Serpens Molecular Cloud

    CERN Document Server

    Eiroa, C; Casali, M M

    2008-01-01

    The Serpens cloud has received considerable attention in the last years, in particular the small region known as the Serpens cloud core where a plethora of star formation related phenomena are found. This review summarizes our current observational knowledge of the cloud, with emphasis on the core. Recent results are converging to a distance for the cloud of ~ 230 +- 20 pc, an issue which has been controversial over the years. We present the gas and dust properties of the cloud core and describe its structure and appearance at different wavelengths. The core contains a dense, very young, low mass stellar cluster with more than 300 objects in all evolutionary phases, from collapsing gaseous condensations to pre-main sequence stars. We describe the behaviour and spatial distribution of the different stellar populations (mm cores, Classes 0, I and II sources). The spatial concentration and the fraction number of Class 0/Class I/Class II sources is considerably larger in the Serpens core than in any other low mas...

  7. Microphysics of Pyrocumulonimbus Clouds

    Science.gov (United States)

    Jensen, Eric; Ackerman, Andrew S.; Fridlind, Ann

    2004-01-01

    The intense heat from forest fires can generate explosive deep convective cloud systems that inject pollutants to high altitudes. Both satellite and high-altitude aircraft measurements have documented cases in which these pyrocumulonimbus clouds inject large amounts of smoke well into the stratosphere (Fromm and Servranckx 2003; Jost et al. 2004). This smoke can remain in the stratosphere, be transported large distances, and affect lower stratospheric chemistry. In addition recent in situ measurements in pyrocumulus updrafts have shown that the high concentrations of smoke particles have significant impacts on cloud microphysical properties. Very high droplet number densities result in delayed precipitation and may enhance lightning (Andrew et al. 2004). Presumably, the smoke particles will also lead to changes in the properties of anvil cirrus produces by the deep convection, with resulting influences on cloud radiative forcing. In situ sampling near the tops of mature pyrocumulonimbus is difficult due to the high altitude and violence of the storms. In this study, we use large eddy simulations (LES) with size-resolved microphysics to elucidate physical processes in pyrocumulonimbus clouds.

  8. Moving HammerCloud to CERN's private cloud

    CERN Document Server

    Barrand, Quentin

    2013-01-01

    HammerCloud is a testing framework for the Worldwide LHC Computing Grid. Currently deployed on about 20 hand-managed machines, it was desirable to move it to the Agile Infrastructure, CERN's OpenStack-based private cloud.

  9. Cloud processing of soluble gases

    Science.gov (United States)

    Laj, P.; Fuzzi, S.; Facchini, M. C.; Lind, J. A.; Orsi, G.; Preiss, M.; Maser, R.; Jaeschke, W.; Seyffer, E.; Helas, G.; Acker, K.; Wieprecht, W.; Möller, D.; Arends, B. G.; Mols, J. J.; Colvile, R. N.; Gallagher, M. W.; Beswick, K. M.; Hargreaves, K. J.; Storeton-West, R. L.; Sutton, M. A.

    Experimental data from the Great Dun Fell Cloud Experiment 1993 were used to investigate interactions between soluble gases and cloud droplets. Concentrations of H 2O 2, SO 2, CH 3COOOH, HCOOH, and HCHO were monitored at different sites within and downwind of a hill cap cloud and their temporal and spatial evolution during several cloud events was investigated. Significant differences were found between in-cloud and out-of-cloud concentrations, most of which could not be explained by simple dissolution into cloud droplets. Concentration patterns were analysed in relation to the chemistry of cloud droplets and the gas/liquid equilibrium. Soluble gases do not undergo similar behaviour: CH 3COOH simply dissolves in the aqueous phase and is outgassed upon cloud dissipation; instead, SO 2 is consumed by its reaction with H 2O 2. The behaviour of HCOOH is more complex because there is evidence for in-cloud chemical production. The formation of HCOOH interferes with the odd hydrogen cycle by enhancing the liquid-phase production of H 2O 2. The H 2O 2 concentration in cloud therefore results from the balance of consumption by oxidation of SO 2 in-cloud production, and the rate by which it is supplied to the system by entrainment of new air into the clouds.

  10. Reconstruction of cloud geometry using a scanning cloud radar

    Science.gov (United States)

    Ewald, F.; Winkler, C.; Zinner, T.

    2015-06-01

    Clouds are one of the main reasons of uncertainties in the forecasts of weather and climate. In part, this is due to limitations of remote sensing of cloud microphysics. Present approaches often use passive spectral measurements for the remote sensing of cloud microphysical parameters. Large uncertainties are introduced by three-dimensional (3-D) radiative transfer effects and cloud inhomogeneities. Such effects are largely caused by unknown orientation of cloud sides or by shadowed areas on the cloud. Passive ground-based remote sensing of cloud properties at high spatial resolution could be crucially improved with this kind of additional knowledge of cloud geometry. To this end, a method for the accurate reconstruction of 3-D cloud geometry from cloud radar measurements is developed in this work. Using a radar simulator and simulated passive measurements of model clouds based on a large eddy simulation (LES), the effects of different radar scan resolutions and varying interpolation methods are evaluated. In reality, a trade-off between scan resolution and scan duration has to be found as clouds change quickly. A reasonable choice is a scan resolution of 1 to 2°. The most suitable interpolation procedure identified is the barycentric interpolation method. The 3-D reconstruction method is demonstrated using radar scans of convective cloud cases with the Munich miraMACS, a 35 GHz scanning cloud radar. As a successful proof of concept, camera imagery collected at the radar location is reproduced for the observed cloud cases via 3-D volume reconstruction and 3-D radiative transfer simulation. Data sets provided by the presented reconstruction method will aid passive spectral ground-based measurements of cloud sides to retrieve microphysical parameters.

  11. Cloud Based Applications and Platforms (Presentation)

    Energy Technology Data Exchange (ETDEWEB)

    Brodt-Giles, D.

    2014-05-15

    Presentation to the Cloud Computing East 2014 Conference, where we are highlighting our cloud computing strategy, describing the platforms on the cloud (including Smartgrid.gov), and defining our process for implementing cloud based applications.

  12. Ash cloud aviation advisories

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, T.J.; Ellis, J.S. [Lawrence Livermore National Lab., CA (United States); Schalk, W.W.; Nasstrom, J.S. [EG and G, Inc., Pleasanton, CA (United States)

    1992-06-25

    During the recent (12--22 June 1991) Mount Pinatubo volcano eruptions, the US Air Force Global Weather Central (AFGWC) requested assistance of the US Department of Energy`s Atmospheric Release Advisory Capability (ARAC) in creating volcanic ash cloud aviation advisories for the region of the Philippine Islands. Through application of its three-dimensional material transport and diffusion models using AFGWC meteorological analysis and forecast wind fields ARAC developed extensive analysis and 12-hourly forecast ash cloud position advisories extending to 48 hours for a period of five days. The advisories consisted of ``relative`` ash cloud concentrations in ten layers (surface-5,000 feet, 5,000--10,000 feet and every 10,000 feet to 90,000 feet). The ash was represented as a log-normal size distribution of 10--200 {mu}m diameter solid particles. Size-dependent ``ashfall`` was simulated over time as the eruption clouds dispersed. Except for an internal experimental attempt to model one of the Mount Redoubt, Alaska, eruptions (12/89), ARAC had no prior experience in modeling volcanic eruption ash hazards. For the cataclysmic eruption of 15--16 June, the complex three-dimensional atmospheric structure of the region produced dramatically divergent ash cloud patterns. The large eruptions (> 7--10 km) produced ash plume clouds with strong westward transport over the South China Sea, Southeast Asia, India and beyond. The low-level eruptions (< 7 km) and quasi-steady-state venting produced a plume which generally dispersed to the north and east throughout the support period. Modeling the sequence of eruptions presented a unique challenge. Although the initial approach proved viable, further refinement is necessary and possible. A distinct need exists to quantify eruptions consistently such that ``relative`` ash concentrations relate to specific aviation hazard categories.

  13. Multi-Cloud Application Design through Cloud Service Composition

    OpenAIRE

    Kyriakos Kritikos; Dimitris Plexousakis

    2015-01-01

    A paper that proposes a cloud service composition approach able to optimally compose different types of cloud services by simultaneously satisfying various types of user requirements. Its novel approach in handling these types, which are not concurrently supported by any cloud design tool, include quality, deployment, security, placement and cost requirements.

  14. Modeling the Cloud: Methodology for Cloud Computing Strategy and Design

    Science.gov (United States)

    2011-05-17

    Opportunities 4How can you determine which, if any, cloud computing technologies and services are suitable for the company? 4How does cloud technology differ...with existing service types, in terms of functions and characteristics? 4How can cloud technology support current and new service or application

  15. Cloud Computing Strategy

    Science.gov (United States)

    2012-07-01

    delivery and integrated  DevOps .  This test and development cloud  environment will enable applications and services to run in a distributed environment...reducing  time to deliver content to clients.        This cloud development and test environment will:  " DevOps " is an emerging set of principles

  16. Storm and cloud dynamics

    CERN Document Server

    Cotton, William R

    1992-01-01

    This book focuses on the dynamics of clouds and of precipitating mesoscale meteorological systems. Clouds and precipitating mesoscale systems represent some of the most important and scientifically exciting weather systems in the world. These are the systems that produce torrential rains, severe winds including downburst and tornadoes, hail, thunder and lightning, and major snow storms. Forecasting such storms represents a major challenge since they are too small to be adequately resolved by conventional observing networks and numerical prediction models.Key Features* Key Highlight

  17. Transition to the Cloud

    DEFF Research Database (Denmark)

    Hedman, Jonas; Xiao, Xiao

    2016-01-01

    companies operate. In this paper, we present a case study of an ERP vendor for SMB (small and mediumsize business) in making a transition towards a cloud-based business model. Through the theoretical lens of ecosystem, we are able to analyze the evolution of the vendor and its business network as a whole......The rising of cloud computing has dramatically changed the way software companies provide and distribute their IT product and related services over the last decades. Today, most software is bought offthe-shelf and distributed over the Internet. This transition is greatly influencing how software...

  18. 浊点萃取-热喷雾火焰炉原子吸收光谱法测定荔枝和桂圆肉中痕量Pb和Cd%Determination of Lead and Cadmium in Litchi and Longan Samples by Cloud Point Extraction Coupled with Thermospray Flame Furnace Atomic Absorption Spectrometry

    Institute of Scientific and Technical Information of China (English)

    杨方文; 曾楚杰; 罗济文; 周能

    2011-01-01

    为测定荔枝和桂圆肉中的Pb和Cd。采用浊点萃取-热喷雾火焰炉原子吸收光谱法对该样品进行分析,考查二乙基二硫代氨基甲酸钠(DDTC)浓度、溶液pH值、TritonX-100浓度、加热时间、水浴温度、干扰离子等实验条件对浊点萃取效率的影响。在最优试验条件下,即pH5.0、温度100℃、萃取时间15min、TritonX-100体积分数0.3%、DDTC质量浓度0.02g/100mL、进样速率0.3mL/min,该方法对Pb和Cd的富集倍数分别为30倍和26倍;方法的检出限对Pb和Cd分别为2ng/mL和0.1ng/mL,相对标准偏差分别为5.2%和3.6%。利用该方法对荔枝和桂圆中的铅和镉进行测定,结果令人满意。%A sensitive method based on cloud point extraction(CPE) coupled with thermospray flame furnace atomic absorption spectrometry(TS-FF-AAS) was proposed for the determination of trace lead and cadmium in litchi and longan samples.Factors affecting the cloud point extraction of lead and cadmium,such as sodium diethyldithiocarbamate(DDTC) concentration,pH,TritonX-100 concentration,extraction time and interference ions were investigated.Results indicated that the optimal extraction parameters were pH 5.0,extraction temperature of 100 ℃,extraction time of 15 min,Triton X-100 concentration of 0.3%,DDTC concentration of 0.02 g/100 mL and sample flow rate of 0.3 mL/min.Under the optimal conditions,Pb and Cd were enriched by 30 folds and 26 folds,respectively.The limits of detection of Pb and Cd were 2 ng/mL and 0.1 ng/mL,and the relative standard deviations(RSDs) were 5.2% and 3.6%,respectively.The proposed method was successfully applied to the determination of lead and cadmium in litchi and longan samples.

  19. Agent-Based Cloud Computing

    OpenAIRE

    Sim, Kwang Mong

    2012-01-01

    Agent-based cloud computing is concerned with the design and development of software agents for bolstering cloud service\\ud discovery, service negotiation, and service composition. The significance of this work is introducing an agent-based paradigm for\\ud constructing software tools and testbeds for cloud resource management. The novel contributions of this work include: 1) developing\\ud Cloudle: an agent-based search engine for cloud service discovery, 2) showing that agent-based negotiatio...

  20. Security Dynamics of Cloud Computing

    OpenAIRE

    Khaled M. Khan

    2009-01-01

    This paper explores various dimensions of cloud computing security. It argues that security concerns of cloud computing need to be addressed from the perspective of individual stakeholder. Security focuses of cloud computing are essentially different in terms of its characteristics and business model. Conventional way of viewing as well as addressing security such as ‘bolting-in’ on the top of cloud computing may not work well. The paper attempts to portray the security spectrum necessary for...

  1. Cloud services, networking, and management

    CERN Document Server

    da Fonseca, Nelson L S

    2015-01-01

    Cloud Services, Networking and Management provides a comprehensive overview of the cloud infrastructure and services, as well as their underlying management mechanisms, including data center virtualization and networking, cloud security and reliability, big data analytics, scientific and commercial applications. Special features of the book include: State-of-the-art content. Self-contained chapters for readers with specific interests. Includes commercial applications on Cloud (video services and games).

  2. The atomic orbitals of the topological atom.

    Science.gov (United States)

    Ramos-Cordoba, Eloy; Salvador, Pedro; Mayer, István

    2013-06-07

    The effective atomic orbitals have been realized in the framework of Bader's atoms in molecules theory for a general wavefunction. This formalism can be used to retrieve from any type of calculation a proper set of orthonormalized numerical atomic orbitals, with occupation numbers that sum up to the respective Quantum Theory of Atoms in Molecules (QTAIM) atomic populations. Experience shows that only a limited number of effective atomic orbitals exhibit significant occupation numbers. These correspond to atomic hybrids that closely resemble the core and valence shells of the atom. The occupation numbers of the remaining effective orbitals are almost negligible, except for atoms with hypervalent character. In addition, the molecular orbitals of a calculation can be exactly expressed as a linear combination of this orthonormalized set of numerical atomic orbitals, and the Mulliken population analysis carried out on this basis set exactly reproduces the original QTAIM atomic populations of the atoms. Approximate expansion of the molecular orbitals over a much reduced set of orthogonal atomic basis functions can also be accomplished to a very good accuracy with a singular value decomposition procedure.

  3. "Bohr's Atomic Model."

    Science.gov (United States)

    Willden, Jeff

    2001-01-01

    "Bohr's Atomic Model" is a small interactive multimedia program that introduces the viewer to a simplified model of the atom. This interactive simulation lets students build an atom using an atomic construction set. The underlying design methodology for "Bohr's Atomic Model" is model-centered instruction, which means the central model of the…

  4. OH{sup +} IN DIFFUSE MOLECULAR CLOUDS

    Energy Technology Data Exchange (ETDEWEB)

    Porras, A. J.; Federman, S. R. [Department of Physics and Astronomy, University of Toledo, Toledo, OH 43606 (United States); Welty, D. E. [Department of Astronomy and Astrophysics, University of Chicago, 5640 South Ellis Avenue, Chicago, IL 60637 (United States); Ritchey, A. M., E-mail: steven.federman@utoledo.edu, E-mail: aporras@live.unc.edu, E-mail: dwelty@oddjob.uchicago.edu, E-mail: aritchey@astro.washington.edu [Department of Astronomy, University of Washington, Seattle, WA 98195 (United States)

    2014-01-20

    Near ultraviolet observations of OH{sup +} and OH in diffuse molecular clouds reveal a preference for different environments. The dominant absorption feature in OH{sup +} arises from a main component seen in CH{sup +} (that with the highest CH{sup +}/CH column density ratio), while OH follows CN absorption. This distinction provides new constraints on OH chemistry in these clouds. Since CH{sup +} detections favor low-density gas with small fractions of molecular hydrogen, this must be true for OH{sup +} as well, confirming OH{sup +} and H{sub 2}O{sup +} observations with the Herschel Space Telescope. Our observed correspondence indicates that the cosmic ray ionization rate derived from these measurements pertains to mainly atomic gas. The association of OH absorption with gas rich in CN is attributed to the need for a high enough density and molecular fraction before detectable amounts are seen. Thus, while OH{sup +} leads to OH production, chemical arguments suggest that their abundances are controlled by different sets of conditions and that they coexist with different sets of observed species. Of particular note is that non-thermal chemistry appears to play a limited role in the synthesis of OH in diffuse molecular clouds.

  5. Research on cloud computing solutions

    Directory of Open Access Journals (Sweden)

    Liudvikas Kaklauskas

    2015-07-01

    Full Text Available Cloud computing can be defined as a new style of computing in which dynamically scala-ble and often virtualized resources are provided as a services over the Internet. Advantages of the cloud computing technology include cost savings, high availability, and easy scalability. Voas and Zhang adapted six phases of computing paradigms, from dummy termi-nals/mainframes, to PCs, networking computing, to grid and cloud computing. There are four types of cloud computing: public cloud, private cloud, hybrid cloud and community. The most common and well-known deployment model is Public Cloud. A Private Cloud is suited for sensitive data, where the customer is dependent on a certain degree of security.According to the different types of services offered, cloud computing can be considered to consist of three layers (services models: IaaS (infrastructure as a service, PaaS (platform as a service, SaaS (software as a service. Main cloud computing solutions: web applications, data hosting, virtualization, database clusters and terminal services. The advantage of cloud com-puting is the ability to virtualize and share resources among different applications with the objective for better server utilization and without a clustering solution, a service may fail at the moment the server crashes.DOI: 10.15181/csat.v2i2.914

  6. The Basics of Cloud Computing

    Science.gov (United States)

    Kaestner, Rich

    2012-01-01

    Most school business officials have heard the term "cloud computing" bandied about and may have some idea of what the term means. In fact, they likely already leverage a cloud-computing solution somewhere within their district. But what does cloud computing really mean? This brief article puts a bit of definition behind the term and helps one…

  7. Trusting Privacy in the Cloud

    NARCIS (Netherlands)

    Prüfer, J.O.

    2014-01-01

    Cloud computing technologies have the potential to increase innovation and economic growth considerably. But many users worry that data in the cloud can be accessed by others, thereby damaging the data owner. Consequently, they do not use cloud technologies up to the efficient level. I design an ins

  8. A View from the Clouds

    Science.gov (United States)

    Chudnov, Daniel

    2010-01-01

    Cloud computing is definitely a thing now, but it's not new and it's not even novel. Back when people were first learning about the Internet in the 1990s, every diagram that one saw showing how the Internet worked had a big cloud in the middle. That cloud represented the diverse links, routers, gateways, and protocols that passed traffic around in…

  9. Understanding and monitoring cloud services

    NARCIS (Netherlands)

    Drago, Idilio

    2013-01-01

    Cloud services have changed the way computing power is delivered to customers. The advantages of the cloud model have fast resulted in powerful providers. However, this success has not come without problems. Cloud providers have been related to major failures, including outages and performance degra

  10. iCloud standard guide

    CERN Document Server

    Alfi, Fauzan

    2013-01-01

    An easy-to-use guide, filled with tutorials that will teach you how to set up and use iCloud, and profit from all of its marvellous features.This book is for anyone with basic knowledge of computers and mobile operations. Prior knowledge of cloud computing or iCloud is not expected.

  11. Cloud water chemistry and the production of sulfates in clouds

    Science.gov (United States)

    Hegg, D. A.; Hobbs, P. V.

    1981-01-01

    Measurements are presented of the pH and ionic content of water collected in clouds over western Washington and the Los Angeles Basin. Evidence for sulfate production in some of the clouds is presented. Not all of the sulfur in the cloud water was in the form of sulfate. However, the measurements indicate that the production of sulfate in clouds is of considerable significance in the atmosphere. Comparison of field measurements with model results show reasonable agreement and suggest that the production of sulfate in cloud water is a consequence of more than one conversion mechanism.

  12. Securing the Cloud Cloud Computer Security Techniques and Tactics

    CERN Document Server

    Winkler, Vic (JR)

    2011-01-01

    As companies turn to cloud computing technology to streamline and save money, security is a fundamental concern. Loss of certain control and lack of trust make this transition difficult unless you know how to handle it. Securing the Cloud discusses making the move to the cloud while securing your peice of it! The cloud offers felxibility, adaptability, scalability, and in the case of security-resilience. This book details the strengths and weaknesses of securing your company's information with different cloud approaches. Attacks can focus on your infrastructure, communications network, data, o

  13. VMware private cloud computing with vCloud director

    CERN Document Server

    Gallagher, Simon

    2013-01-01

    It's All About Delivering Service with vCloud Director Empowered by virtualization, companies are not just moving into the cloud, they're moving into private clouds for greater security, flexibility, and cost savings. However, this move involves more than just infrastructure. It also represents a different business model and a new way to provide services. In this detailed book, VMware vExpert Simon Gallagher makes sense of private cloud computing for IT administrators. From basic cloud theory and strategies for adoption to practical implementation, he covers all the issues. You'll lea

  14. AIRS-CloudSat cloud mask, radar reflectivities, and cloud classification matchups V3.2

    Data.gov (United States)

    National Aeronautics and Space Administration — This is AIRS-CloudSat collocated subset, in NetCDF 4 format. These data contain collocated: AIRS Level 1b radiances spectra, CloudSat radar reflectivities, and MODIS...

  15. Determination of Trace Lead in 4Carbonated Drinks by Cloud Point Extraction ﹣ Flame Atomic Absorption Spectrometry(CPE ﹣ AFFS)%浊点萃取﹣火焰原子吸收法(CPE ﹣ AFFS)测定碳酸饮料中痕量铅

    Institute of Scientific and Technical Information of China (English)

    杨葵华; 朱瑶

    2015-01-01

    The cloud Point extraction was used for Preconcentration of the trace lead in carbonated drinks after the formation of a comPlex with 8 ﹣ hydroxyquinoline ethanol in the Presence of surfactant TritonX ﹣ 100,and then the flame atomic absorPtion sPectrometry was aPPlied to determine the content of lead. The affecting condition,in-cluding extraction temPerature and time,PH,dosage of extraction agent and comPlex agent,the amount of satu-rated sodium chloride and ionic strength were oPtimized. The results show that the lead detection limit was 4. 39 ng / mL and the RSD was 7. 4% ,while the recovery was between 98. 7% ~ 99. 7% ,the linear range was 200 ~500 ng / mL at the oPtimum conditions. Ⅰt was revealed that the method is simPle,safe,efficient,agile,and effi-cient.%以8﹣羟基喹啉﹣非离子表面活性剂 TritonX ﹣100为萃取体系测定碳酸饮料中痕量铅的含量.考察了温度、时间、PH 值、8﹣羟基喹啉用量、TritonX ﹣100用量、饱和氯化钠用量、离子强度等因素对萃取效果的影响.结果表明:在最佳条件下测定方法的检测限为4.39 ng/ mL,RSD 为7.4%,回收率在98.7%~99.7%,线性范围为200~500 ng/ mL,结果可靠,为碳酸饮料的质量控制提供参考.

  16. Password authentication in cloud

    Directory of Open Access Journals (Sweden)

    Indal Singh

    2015-09-01

    Full Text Available Cloud computing is an Internet-based computing, whereby shared resources, software, and information are provided to computers and other devices on demand. However, adopting a cloud computing paradigm may have positive as well as negative effects on the data security of service consumers [1]. Cloud Computing is a term used to describe both a platform and type of application. As a platform it supplies, configures and reconfigures servers, while the servers can be physical machines or virtual machines. On the other hand, Cloud Computing describes applications that are extended to be accessible through the internet and for this purpose large data centers and powerful servers are used to host the web applications and web services. Authentication is one the most important security primitive [6]. Password authentication is most widely used authentication mechanism. Password provides security mechanism for authentication and protection services against unwanted access to resource. In this paper, we applied a technique to preserve our password using graphical authentication.

  17. CLOUD COMPUTING SECURITY ISSUES

    Directory of Open Access Journals (Sweden)

    Florin OGIGAU-NEAMTIU

    2012-01-01

    Full Text Available The term “cloud computing” has been in the spotlights of IT specialists the last years because of its potential to transform this industry. The promised benefits have determined companies to invest great sums of money in researching and developing this domain and great steps have been made towards implementing this technology. Managers have traditionally viewed IT as difficult and expensive and the promise of cloud computing leads many to think that IT will now be easy and cheap. The reality is that cloud computing has simplified some technical aspects of building computer systems, but the myriad challenges facing IT environment still remain. Organizations which consider adopting cloud based services must also understand the many major problems of information policy, including issues of privacy, security, reliability, access, and regulation. The goal of this article is to identify the main security issues and to draw the attention of both decision makers and users to the potential risks of moving data into “the cloud”.

  18. CloudETL

    DEFF Research Database (Denmark)

    Liu, Xiufeng; Thomsen, Christian; Pedersen, Torben Bach

    2014-01-01

    the powerful Pig platform for data processing on MapReduce does not support such dimensional ETL processing. To remedy this, we present the ETL framework CloudETL which uses Hadoop to parallelize ETL execution and to process data into Hive. The user defines the ETL process by means of high-level constructs...

  19. Computing in the Clouds

    Science.gov (United States)

    Johnson, Doug

    2010-01-01

    Web-based applications offer teachers, students, and school districts a convenient way to accomplish a wide range of tasks, from accounting to word processing, for free. Cloud computing has the potential to offer staff and students better services at a lower cost than the technology deployment models they're using now. Saving money and improving…

  20. Multiscale Cloud System Modeling

    Science.gov (United States)

    Tao, Wei-Kuo; Moncrieff, Mitchell W.

    2009-01-01

    The central theme of this paper is to describe how cloud system resolving models (CRMs) of grid spacing approximately 1 km have been applied to various important problems in atmospheric science across a wide range of spatial and temporal scales and how these applications relate to other modeling approaches. A long-standing problem concerns the representation of organized precipitating convective cloud systems in weather and climate models. Since CRMs resolve the mesoscale to large scales of motion (i.e., 10 km to global) they explicitly address the cloud system problem. By explicitly representing organized convection, CRMs bypass restrictive assumptions associated with convective parameterization such as the scale gap between cumulus and large-scale motion. Dynamical models provide insight into the physical mechanisms involved with scale interaction and convective organization. Multiscale CRMs simulate convective cloud systems in computational domains up to global and have been applied in place of contemporary convective parameterizations in global models. Multiscale CRMs pose a new challenge for model validation, which is met in an integrated approach involving CRMs, operational prediction systems, observational measurements, and dynamical models in a new international project: the Year of Tropical Convection, which has an emphasis on organized tropical convection and its global effects.

  1. Benchmarking personal cloud storage

    NARCIS (Netherlands)

    Drago, Idilio; Bocchi, Enrico; Mellia, Marco; Slatman, Herman; Pras, Aiko

    2013-01-01

    Personal cloud storage services are data-intensive applications already producing a significant share of Internet traffic. Several solutions offered by different companies attract more and more people. However, little is known about each service capabilities, architecture and - most of all - perform

  2. Seeding the Cloud

    Science.gov (United States)

    Schaffhauser, Dian

    2013-01-01

    For any institution looking to shift enterprise resource planning (ERP) systems to the cloud, big savings can be achieved--but only if the school has properly prepped "before" negotiations begin. These three steps can help: (1) Mop up the mess first; (2) Understand the true costs for services; and (3) Calculate the cost of transition.

  3. Towards autonomous vehicular clouds

    Directory of Open Access Journals (Sweden)

    Stephan Olariu

    2011-09-01

    Full Text Available The dawn of the 21st century has seen a growing interest in vehicular networking and its myriad potential applications. The initial view of practitioners and researchers was that radio-equipped vehicles could keep the drivers informed about potential safety risks and increase their awareness of road conditions. The view then expanded to include access to the Internet and associated services. This position paper proposes and promotes a novel and more comprehensive vision namely, that advances in vehicular networks, embedded devices and cloud computing will enable the formation of autonomous clouds of vehicular computing, communication, sensing, power and physical resources. Hence, we coin the term, autonomous vehicular clouds (AVCs. A key feature distinguishing AVCs from conventional cloud computing is that mobile AVC resources can be pooled dynamically to serve authorized users and to enable autonomy in real-time service sharing and management on terrestrial, aerial, or aquatic pathways or theaters of operations. In addition to general-purpose AVCs, we also envision the emergence of specialized AVCs such as mobile analytics laboratories. Furthermore, we envision that the integration of AVCs with ubiquitous smart infrastructures including intelligent transportation systems, smart cities and smart electric power grids will have an enormous societal impact enabling ubiquitous utility cyber-physical services at the right place, right time and with right-sized resources.

  4. Two-component model of the interaction of an interstellar cloud with surrounding hot plasma

    CERN Document Server

    Provornikova, E A; Lallement, R

    2011-01-01

    We present a two-component gasdynamic model of an interstellar cloud embedded in a hot plasma. It is assumed that the cloud consists of atomic hydrogen gas, interstellar plasma is quasineutral. Hydrogen atoms and plasma protons interact through a charge exchange process. Magnetic felds and radiative processes are ignored in the model. The influence of heat conduction within plasma on the interaction between a cloud and plasma is studied. We consider the extreme case and assume that hot plasma electrons instantly heat the plasma in the interaction region and that plasma flow can be described as isothermal. Using the two-component model of the interaction of cold neutral cloud and hot plasma, we estimate the lifetime of interstellar clouds. We focus on the clouds typical for the cluster of local interstellar clouds embedded in the hot Local Bubble and give an estimate of the lifetime of the Local interstellar cloud where the Sun currently travels. The charge transfer between highly charged plasma ions and neutr...

  5. Equilibrium vortex lattices of a binary rotating atomic Bose-Einstein condensate with unequal atomic masses

    Science.gov (United States)

    Dong, Biao; Wang, Lin-Xue; Chen, Guang-Ping; Han, Wei; Zhang, Shou-Gang; Zhang, Xiao-Fei

    2016-10-01

    We perform a detailed numerical study of the equilibrium ground-state structures of a binary rotating Bose-Einstein condensate with unequal atomic masses. Our results show that the ground-state distribution and its related vortex configurations are complex events that differ markedly depending strongly on the strength of rotation frequency, as well as on the ratio of atomic masses. We also discuss the structures and radii of the clouds, the number and the size of the core region of the vortices, as a function of the rotation frequency, and of the ratio of atomic masses, and the analytical results agree well with our numerical simulations. This work may open an alternate way in the quantum control of the binary rotating quantum gases with unequal atomic masses.

  6. Security for cloud storage systems

    CERN Document Server

    Yang, Kan

    2014-01-01

    Cloud storage is an important service of cloud computing, which offers service for data owners to host their data in the cloud. This new paradigm of data hosting and data access services introduces two major security concerns. The first is the protection of data integrity. Data owners may not fully trust the cloud server and worry that data stored in the cloud could be corrupted or even removed. The second is data access control. Data owners may worry that some dishonest servers provide data access to users that are not permitted for profit gain and thus they can no longer rely on the servers

  7. Cloud database development and management

    CERN Document Server

    Chao, Lee

    2013-01-01

    Nowadays, cloud computing is almost everywhere. However, one can hardly find a textbook that utilizes cloud computing for teaching database and application development. This cloud-based database development book teaches both the theory and practice with step-by-step instructions and examples. This book helps readers to set up a cloud computing environment for teaching and learning database systems. The book will cover adequate conceptual content for students and IT professionals to gain necessary knowledge and hands-on skills to set up cloud based database systems.

  8. Controllable Magnetic Focusing of Cold Atoms on a Chip

    Institute of Scientific and Technical Information of China (English)

    LIU Yang; YUN Min; YIN Jian-Ping

    2006-01-01

    @@ We propose a new lens scheme to focus cold atoms by using a controllable inhomogeneous magnetic field from a square current-carrying wire fabricated on a chip. The spatial distributions of the magnetic field are calculated, and the results show that the generated magnetic field is a two-dimensional (2D) quadrupole one and can be used to focus cold atoms or a cold atomic beam. The dynamic processes of cold atoms passing through our square wire layout and its focusing properties are studied by using Monte Carlo simulations. Our study shows that the atomic clouds can be focused effectively by our magnetic lens scheme, and the focal lengthof the atomic lens and its radius of focused spot can be continuously changed by adjusting the current in the wires.

  9. Realization of Green MOT for Ytterbium Atoms

    Institute of Scientific and Technical Information of China (English)

    ZHAO Peng-Yi; XIONG Zhuan-Xian; LONG Yun; HE Ling-Xiang; L(U) Bao-Long

    2009-01-01

    We report the experimental realization of a magneto-optical trap (MOT) of 174Yb atoms operating on the 1S0-3p1 intercombination transition at 555.8 nm.The green MOT is loaded by a Zeeman-slowed atomic beam.In order to increase the capture velocity of the MOT,we use the trapping laser beams consisting of five discrete frequency components obtained by modulating the laser light through an electro-optic modulator.The trapped atomic number of the 174 Yb isotope is about 6.2×105,and the temperature of the cold atowic cloud is estimated to be about 100 μK.The success of the green MOT is an important step towards the goad of an ytterbium optical dock.

  10. Distributed Feedback Lasing with Cold Atoms

    CERN Document Server

    Schilke, Alexander; Courteille, Philippe W; Guerin, William

    2011-01-01

    There is currently a strong interest in mirrorless lasing. In these systems, the electromagnetic feedback is provided either by disorder, i.e., multiple scattering in the gain medium itself, or by order, i.e., multiple Bragg reflection. This corresponds, respectively, to "random lasers" and "photonic crystal lasers". The crossover regime, between order and disorder, or correlated disorder, starts also to be fruitfully investigated. Here, we report one-dimensional photonic crystal lasing, i.e., distributed feedback lasing, with a cold atom cloud that provides simultaneously both gain and feedback. The atoms are trapped in a 1D lattice, giving a density modulation that creates a strong Bragg reflection under a small angle of incidence. Pumping the atoms with auxiliary beams induces four wave mixing that provides gain. The combination of both ingredients generates a mirrorless laser with a conical output emission, whose apex angle is tunable with the lattice periodicity through the Bragg condition.

  11. Atomic phase diagram

    Institute of Scientific and Technical Information of China (English)

    LI Shichun

    2004-01-01

    Based on the Thomas-Fermi-Dirac-Cheng model, atomic phase diagram or electron density versus atomic radius diagram describing the interaction properties of atoms of different kinds in equilibrium state is developed. Atomic phase diagram is established based on the two-atoms model. Besides atomic radius, electron density and continuity condition for electron density on interfaces between atoms, the lever law of atomic phase diagram involving other physical parameters is taken into account, such as the binding energy, for the sake of simplicity.

  12. Two-way conversations between cold atoms and semiconductors

    Energy Technology Data Exchange (ETDEWEB)

    Judd, Thomas [University of Tuebingen (Germany); University of Nottingham (United Kingdom); Scott, Robin; Sinuco, German; Montgomery, Tom; Krueger, Peter; Fromhold, Mark [University of Nottingham (United Kingdom); Martin, Andrew [University of Melbourne (Australia)

    2010-07-01

    There has been significant work in the past few years on hybrid devices which combine cold atoms with solid state structures. The hope is to create devices which combine the key advantages of both systems - the purity of a quantum coherent atom cloud, and the versatility of microchips - to study fundamental physics and further quantum technologies. To date there has been much success in manipulating cold atoms with microchips and semiconductors to create a measurable signal in the atom cloud. However, it has not been possible to perform the reverse procedure of using cold atoms to create a measurable signal in a solid state device. If this two-way coupling can be achieved, a range of possibilities open up such as long-term quantum memory chips. Here we use simulations to show that Fresnel zone plates could assist these efforts by strongly and coherently focusing ultracold atoms onto a semiconductor chip with a two-dimensional electron gas (2DEG). The atoms are shown to deplete the 2DEG, thereby strongly increasing its resistivity to measurable levels. The technique provides a solution to the long standing problem of short-range atom focusing while at the same time opening the door to a new form of non-destructive lithography which can create electronic components on a 50nm scale.

  13. LOAD MANAGEMENT IN CLOUD ENVIRONMENT

    Directory of Open Access Journals (Sweden)

    Esha Sarkar

    2014-09-01

    Full Text Available Cloud computing is an on demand service in which shared resources, information, software and other devices are provided to the end user as per their requirement at a specific time. A cloud consists of several elements such as clients, datacenters and distributed servers. There are n number of clients and end users involved in cloud environment. These clients may make requests to the cloud system simultaneously, making it difficult for the cloud to manage the entire load at a time. The load can be CPU load, memory load, delay or network load. This might cause inconvenience to the clients as there may be delay in the response time or it might affect the performance and efficiency of the cloud environment. So, the concept of load balancing is very important in cloud computing to improve the efficiency of the cloud. Good load balancing makes cloud computing more efficient and improves user satisfaction. This paper gives an approach to balance the incoming load in cloud environment by making partitions of the public cloud

  14. Cloud Computing Utility and Applications

    Directory of Open Access Journals (Sweden)

    Pradeep Kumar Tiwari

    2011-12-01

    Full Text Available Cloud Architecture provides services on demand basis via internet (WWW services. Application design in cloud computing environment or the applications which support cloud paradigm are on demand on the basis of user requirement. Those applications provide the support on various hardware, software and other resource requirement on demand. API used in the cloud computing provide the greater advantage to provide industrial strength, where the complex reliability and scalability logic of the underlying services remains implemented and hidden in the cloud environment. Cloud Computing provide the highest utilization in terms of utilization, resource sharing, requirement gathering and utility to the other needful resources. In this paper we discuss several utility and their applications. We provide a broad discussion which is useful for cloud computing research.

  15. Research Agenda in Cloud Technologies

    CERN Document Server

    Sriram, Ilango

    2010-01-01

    Cloud computing is the latest effort in delivering computing resources as a service. It represents a shift away from computing as a product that is purchased, to computing as a service that is delivered to consumers over the internet from large-scale data centres - or "clouds". Whilst cloud computing is gaining growing popularity in the IT industry, academia appeared to be lagging behind the rapid developments in this field. This paper is the first systematic review of peer-reviewed academic research published in this field, and aims to provide an overview of the swiftly developing advances in the technical foundations of cloud computing and their research efforts. Structured along the technical aspects on the cloud agenda, we discuss lessons from related technologies; advances in the introduction of protocols, interfaces, and standards; techniques for modelling and building clouds; and new use-cases arising through cloud computing.

  16. Aircraft measurements of wave cloud

    Directory of Open Access Journals (Sweden)

    Z. Cui

    2012-05-01

    Full Text Available In this paper, aircraft measurements are presented of liquid phase (ice-free wave clouds made at temperatures greater than −5 °C that formed over Scotland, UK. The horizontal variations of the vertical velocity across wave clouds display a distinct pattern. The maximum updraughts occur at the upshear flanks of the clouds and the strong downdraughts at the downshear flanks. The cloud droplet concentrations were a couple of hundreds per cubic centimetres, and the drops generally had a mean diameter between 15–45 μm. A small proportion of the drops were drizzle. A new definition of a mountain-wave cloud is given, based on the measurements presented here and previous studies. The results in this paper provide a case for future numerical simulation of wave cloud and the interaction between wave and clouds.

  17. Lean computing for the cloud

    CERN Document Server

    Bauer, Eric

    2016-01-01

    Applies lean manufacturing principles across the cloud service delivery chain to enable application and infrastructure service providers to sustainably achieve the shortest lead time, best quality, and value This book focuses on lean in the context of cloud computing capacity management of applications and the physical and virtual cloud resources that support them. Lean Computing for the Cloud considers business, architectural and operational aspects of efficiently delivering valuable services to end users via cloud-based applications hosted on shared cloud infrastructure. The work also focuses on overall optimization of the service delivery chain to enable both application service and infrastructure service providers to adopt leaner, demand driven operations to serve end users more efficiently. The book’s early chapters analyze how capacity management morphs with cloud computing into interlocked physical infrastructure capacity management, virtual resou ce capacity management, and application capacity ma...

  18. The Atomic to Molecular Transition in the Interstellar Medium

    Science.gov (United States)

    Goldsmith, Paul F.

    2012-01-01

    Study of H2 in UV and IR continues to surprise us with complexity of excitation state, OPR, and role in astrochemistry. Atomic H in molecular clouds is a very powerful tool suggesting that they are not "young" but that it takes millions of years to convert primarily atomic hydrogen clouds to 99.9% molecular form. Laboratory data suggests that H2 formation is efficient over broader range of temperatures than thought to be the case a few years ago, but range is still limited. Issues of complex grain morphology and surface structure make this a very difficult field in which to obtain definitively meaningful results. Ongoing and future observations of CI and CII will improve our understanding of the structure of clouds, their total mass, and how they have evolved and will continue to do so.

  19. A direct probe of cloud holes at the L/T transition

    Science.gov (United States)

    Buenzli, Esther

    2014-10-01

    Understanding cloud formation, evolution and dispersal is one of the biggest challenges in the field of substellar atmospheres. At the transition from L to T type brown dwarfs, thick silicate and iron clouds disappear below the visible photosphere and the spectra are altered dramatically despite little change in effective temperature. Observed strengthening of the FeH band through the transition has indicated an opening of cloud holes rather than gradual sinking of the clouds. This view has been supported by the discovery of brown dwarfs with photometric variability attributed to patchy cloud cover. However, our recent spectral variability observations have complicated the picture because patchy cloud models with cloud holes currently cannot reproduce the color variations and spectral variability signatures. Whether this implies an absence of cloud holes (in contradiction to the interpretation of the observed strengthening of FeH) or is because models neglect other mechanisms that can affect the colors (eg temperature anomalies) remains unclear. Here, we propose WFC3/G102 spectral variability observations of the very nearby L/T transition benchmark binary Luhman 16AB, the only known variable brown dwarfs in a binary system. These observations target the FeH band. As the FeH molecule contains the cloud forming atom Fe, it is a direct tracer of the cloud holes. By comparing the variability amplitude in the FeH band with the surrounding continuum, as well as between the L and T component at different stages of cloud evolution, we will obtain direct evidence whether the formation of cloud holes is indeed the driving mechanism behind cloud dispersal at the L/T transition.

  20. X-Ray Shadowing Experiments Toward Infrared Dark Clouds

    Science.gov (United States)

    Anderson, L. E.; Snowden, S.; Bania, T. M.

    2009-01-01

    We searched for X-ray shadowing toward two infrared dark clouds (IRDCs) using the MOS detectors on XMM-Newton to learn about the Galactic distribution of X-ray emitting plasma. IRDCs make ideal X-ray shadowing targets of 3/4 keY photons due to their high column densities, relatively large angular sizes, and known kinematic distances. Here we focus on two clouds near 30 deg Galactic longitude at distances of 2 and 5 kpc from the Sun. We derive the foreground and background column densities of molecular and atomic gas in the direction of the clouds. We find that the 3/4 ke V emission must be distributed throughout the Galactic disk. It is therefore linked to the structure of the cooler material of the ISM, and to the birth of stars.

  1. Cold Matter Assembled Atom-by-Atom

    CERN Document Server

    Endres, Manuel; Keesling, Alexander; Levine, Harry; Anschuetz, Eric R; Krajenbrink, Alexandre; Senko, Crystal; Vuletic, Vladan; Greiner, Markus; Lukin, Mikhail D

    2016-01-01

    The realization of large-scale fully controllable quantum systems is an exciting frontier in modern physical science. We use atom-by-atom assembly to implement a novel platform for the deterministic preparation of regular arrays of individually controlled cold atoms. In our approach, a measurement and feedback procedure eliminates the entropy associated with probabilistic trap occupation and results in defect-free arrays of over 50 atoms in less than 400 ms. The technique is based on fast, real-time control of 100 optical tweezers, which we use to arrange atoms in desired geometric patterns and to maintain these configurations by replacing lost atoms with surplus atoms from a reservoir. This bottom-up approach enables controlled engineering of scalable many-body systems for quantum information processing, quantum simulations, and precision measurements.

  2. Jupiter Clouds in Depth

    Science.gov (United States)

    2000-01-01

    [figure removed for brevity, see original site] 619 nm [figure removed for brevity, see original site] 727 nm [figure removed for brevity, see original site] 890 nmImages from NASA's Cassini spacecraft using three different filters reveal cloud structures and movements at different depths in the atmosphere around Jupiter's south pole.Cassini's cameras come equipped with filters that sample three wavelengths where methane gas absorbs light. These are in the red at 619 nanometer (nm) wavelength and in the near-infrared at 727 nm and 890 nm. Absorption in the 619 nm filter is weak. It is stronger in the 727 nm band and very strong in the 890 nm band where 90 percent of the light is absorbed by methane gas. Light in the weakest band can penetrate the deepest into Jupiter's atmosphere. It is sensitive to the amount of cloud and haze down to the pressure of the water cloud, which lies at a depth where pressure is about 6 times the atmospheric pressure at sea level on the Earth). Light in the strongest methane band is absorbed at high altitude and is sensitive only to the ammonia cloud level and higher (pressures less than about one-half of Earth's atmospheric pressure) and the middle methane band is sensitive to the ammonia and ammonium hydrosulfide cloud layers as deep as two times Earth's atmospheric pressure.The images shown here demonstrate the power of these filters in studies of cloud stratigraphy. The images cover latitudes from about 15 degrees north at the top down to the southern polar region at the bottom. The left and middle images are ratios, the image in the methane filter divided by the image at a nearby wavelength outside the methane band. Using ratios emphasizes where contrast is due to methane absorption and not to other factors, such as the absorptive properties of the cloud particles, which influence contrast at all wavelengths.The most prominent feature seen in all three filters is the polar stratospheric haze that makes Jupiter bright near the pole

  3. Cloud and Cloud Shadow Masking Using Multi-Temporal Cloud Masking Algorithm in Tropical Environmental

    Science.gov (United States)

    Candra, D. S.; Phinn, S.; Scarth, P.

    2016-06-01

    A cloud masking approach based on multi-temporal satellite images is proposed. The basic idea of this approach is to detect cloud and cloud shadow by using the difference reflectance values between clear pixels and cloud and cloud shadow contaminated pixels. Several bands of satellite image which have big difference values are selected for developing Multi-temporal Cloud Masking (MCM) algorithm. Some experimental analyses are conducted by using Landsat-8 images. Band 3 and band 4 are selected because they can distinguish between cloud and non cloud. Afterwards, band 5 and band 6 are used to distinguish between cloud shadow and clear. The results show that the MCM algorithm can detect cloud and cloud shadow appropriately. Moreover, qualitative and quantitative assessments are conducted using visual inspections and confusion matrix, respectively, to evaluate the reliability of this algorithm. Comparison between this algorithm and QA band are conducted to prove the reliability of the approach. The results show that MCM better than QA band and the accuracy of the results are very high.

  4. IBM Cloud Computing Powering a Smarter Planet

    Science.gov (United States)

    Zhu, Jinzy; Fang, Xing; Guo, Zhe; Niu, Meng Hua; Cao, Fan; Yue, Shuang; Liu, Qin Yu

    With increasing need for intelligent systems supporting the world's businesses, Cloud Computing has emerged as a dominant trend to provide a dynamic infrastructure to make such intelligence possible. The article introduced how to build a smarter planet with cloud computing technology. First, it introduced why we need cloud, and the evolution of cloud technology. Secondly, it analyzed the value of cloud computing and how to apply cloud technology. Finally, it predicted the future of cloud in the smarter planet.

  5. Point clouds in BIM

    Science.gov (United States)

    Antova, Gergana; Kunchev, Ivan; Mickrenska-Cherneva, Christina

    2016-10-01

    The representation of physical buildings in Building Information Models (BIM) has been a subject of research since four decades in the fields of Construction Informatics and GeoInformatics. The early digital representations of buildings mainly appeared as 3D drawings constructed by CAD software, and the 3D representation of the buildings was only geometric, while semantics and topology were out of modelling focus. On the other hand, less detailed building representations, with often focus on ‘outside’ representations were also found in form of 2D /2,5D GeoInformation models. Point clouds from 3D laser scanning data give a full and exact representation of the building geometry. The article presents different aspects and the benefits of using point clouds in BIM in the different stages of a lifecycle of a building.

  6. Proceedings of the Bonn/Bochum-Graduiertenkolleg Workshop 'The Magellanic Clouds and Other Dwarf Galaxies'

    OpenAIRE

    Richtler, Tom; Braun, Jochen M.

    1998-01-01

    The Workshop 'The Magellanic Clouds and Other Dwarf Galaxies' was held at the Physikzentrum Bad Honnef in January 1998. The proceedings comprise 79 contributions. About 1/3 of the 352 pages contain the following Reviews: The Violent Interstellar Medium in Dwarf Galaxies: Atomic Gas (Elias Brinks and Fabian Walter), Hot Gas in the Large Magellanic Cloud (You-Hua Chu), Astrophysics of Dwarf Galaxies: Structures and Stellar Populations (John S. Gallagher), Star-forming regions and ionized gas in...

  7. Ion Cloud Modeling

    Science.gov (United States)

    1977-11-11

    detailed examination of the photographic image of the Spruce neutral cloud at 20 seconds after release. Technology International Corporation kindly...seconds after release as recorded on film record #71715. (Original densitometer tracing courtesy of W. Boquist, Technology International Corporation.) 29...C., and R. N. Bybee , "Secede H Chemical Payloads," RADC-TR-71-232, pp. 1-21, Thiokol Chemical Corporation, Ogden, Utah, 84402, June 1971. 6. Boquist

  8. Icebergs in the Clouds: the Other Risks of Cloud Computing

    CERN Document Server

    Ford, Bryan

    2012-01-01

    Cloud computing is appealing from management and efficiency perspectives, but brings risks both known and unknown. Well-known and hotly-debated information security risks, due to software vulnerabilities, insider attacks, and side-channels for example, may be only the "tip of the iceberg." As diverse, independently developed cloud services share ever more fluidly and aggressively multiplexed hardware resource pools, unpredictable interactions between load-balancing and other reactive mechanisms could lead to dynamic instabilities or "meltdowns." Non-transparent layering structures, where alternative cloud services may appear independent but share deep, hidden resource dependencies, may create unexpected and potentially catastrophic failure correlations, reminiscent of financial industry crashes. Finally, cloud computing exacerbates already-difficult digital preservation challenges, because only the provider of a cloud-based application or service has the ability to archive a "live," functional copy of a cloud...

  9. ATLAS Cloud R&D

    Science.gov (United States)

    Panitkin, Sergey; Barreiro Megino, Fernando; Caballero Bejar, Jose; Benjamin, Doug; Di Girolamo, Alessandro; Gable, Ian; Hendrix, Val; Hover, John; Kucharczyk, Katarzyna; Medrano Llamas, Ramon; Love, Peter; Ohman, Henrik; Paterson, Michael; Sobie, Randall; Taylor, Ryan; Walker, Rodney; Zaytsev, Alexander; Atlas Collaboration

    2014-06-01

    The computing model of the ATLAS experiment was designed around the concept of grid computing and, since the start of data taking, this model has proven very successful. However, new cloud computing technologies bring attractive features to improve the operations and elasticity of scientific distributed computing. ATLAS sees grid and cloud computing as complementary technologies that will coexist at different levels of resource abstraction, and two years ago created an R&D working group to investigate the different integration scenarios. The ATLAS Cloud Computing R&D has been able to demonstrate the feasibility of offloading work from grid to cloud sites and, as of today, is able to integrate transparently various cloud resources into the PanDA workload management system. The ATLAS Cloud Computing R&D is operating various PanDA queues on private and public resources and has provided several hundred thousand CPU days to the experiment. As a result, the ATLAS Cloud Computing R&D group has gained a significant insight into the cloud computing landscape and has identified points that still need to be addressed in order to fully utilize this technology. This contribution will explain the cloud integration models that are being evaluated and will discuss ATLAS' learning during the collaboration with leading commercial and academic cloud providers.

  10. Cloud Computing Security: A Survey

    Directory of Open Access Journals (Sweden)

    Issa M. Khalil

    2014-02-01

    Full Text Available Cloud computing is an emerging technology paradigm that migrates current technological and computing concepts into utility-like solutions similar to electricity and water systems. Clouds bring out a wide range of benefits including configurable computing resources, economic savings, and service flexibility. However, security and privacy concerns are shown to be the primary obstacles to a wide adoption of clouds. The new concepts that clouds introduce, such as multi-tenancy, resource sharing and outsourcing, create new challenges to the security community. Addressing these challenges requires, in addition to the ability to cultivate and tune the security measures developed for traditional computing systems, proposing new security policies, models, and protocols to address the unique cloud security challenges. In this work, we provide a comprehensive study of cloud computing security and privacy concerns. We identify cloud vulnerabilities, classify known security threats and attacks, and present the state-of-the-art practices to control the vulnerabilities, neutralize the threats, and calibrate the attacks. Additionally, we investigate and identify the limitations of the current solutions and provide insights of the future security perspectives. Finally, we provide a cloud security framework in which we present the various lines of defense and identify the dependency levels among them. We identify 28 cloud security threats which we classify into five categories. We also present nine general cloud attacks along with various attack incidents, and provide effectiveness analysis of the proposed countermeasures.

  11. An Improved Technique for Measurement of Cold HI in Molecular Cloud Cores

    CERN Document Server

    Krco, Marko; Brown, Robert L; Li, Di

    2008-01-01

    The presence of atomic gas mixed with molecular species in a "molecular" cloud may significantly affect its chemistry, the excitation of some species, and can serve as probe of the cloud's evolution. Cold neutral atomic hydrogen (HI) in molecular clouds is revealed by its self absorption of background galactic HI 21-cm emission. The properties of this gas can be investigated quantitatively through observation of HI Narrow Self-Absorption (HINSA). In this paper, we present a new technique for measuring atomic gas physical parameters from HINSA observations that utilizes molecular tracers to guide the HINSA extraction. This technique offers a significant improvement in the precision with which HI column densities can be determined over previous methods, and it opens several new avenues of study of relevance to the field of star formation.

  12. Observation of individual tracer atoms in an ultracold dilute gas

    CERN Document Server

    Hohmann, Michael; Lausch, Tobias; Mayer, Daniel; Schmidt, Felix; Lutz, Eric; Widera, Artur

    2016-01-01

    Understanding the motion of a tracer particle in a rarefied gas is of fundamental and practical importance. We report the experimental investigation of individual Cs atoms impinging on a dilute cloud of ultracold Rb atoms with variable density. We study the nonequilibrium relaxation of the initial nonthermal state and detect the effect of single collisions which has eluded observation so far. We show that after few collisions, the measured spatial distribution of the light tracer atoms is correctly described by a generalized Langevin equation with a velocity-dependent friction coefficient, over a large range of Knudsen numbers.

  13. Positron clouds within thunderstorms

    CERN Document Server

    Dwyer, Joseph R; Hazelton, Bryna J; Grefenstette, Brian W; Kelley, Nicole A; Lowell, Alexander W; Schaal, Meagan M; Rassoul, Hamid K

    2015-01-01

    We report the observation of two isolated clouds of positrons inside an active thunderstorm. These observations were made by the Airborne Detector for Energetic Lightning Emissions (ADELE), an array of six gamma-ray detectors, which flew on a Gulfstream V jet aircraft through the top of an active thunderstorm in August 2009. ADELE recorded two 511 keV gamma-ray count rate enhancements, 35 seconds apart, each lasting approximately 0.2 seconds. The enhancements, which were about a factor of 12 above background, were both accompanied by electrical activity as measured by a flat-plate antenna on the underside of the aircraft. The energy spectra were consistent with a source mostly composed of positron annihilation gamma rays, with a prominent 511 keV line clearly visible in the data. Model fits to the data suggest that the aircraft was briefly immersed in clouds of positrons, more than a kilometer across. It is not clear how the positron clouds were created within the thunderstorm, but it is possible they were ca...

  14. Clouds over Mars!

    Science.gov (United States)

    1997-01-01

    This is the first color image ever taken from the surface of Mars of an overcast sky. Featured are pink stratus clouds coming from the northeast at about 15 miles per hour (6.7 meters/second) at an approximate height of ten miles (16 kilometers) above the surface. The clouds consist of water ice condensed on reddish dust particles suspended in the atmosphere. Clouds on Mars are sometimes localized and can sometimes cover entire regions, but have not yet been observed to cover the entire planet. The image was taken about an hour and forty minutes before sunrise by the Imager for Mars Pathfinder (IMP) on Sol 16 at about ten degrees up from the eastern Martian horizon.Mars Pathfinder is the second in NASA's Discovery program of low-cost spacecraft with highly focused science goals. The Jet Propulsion Laboratory, Pasadena, CA, developed and manages and Mars Pathfinder mission for NASA's Office of Space Science, Washington, D.C. JPL is an operating division of the California Institute of Technology (Caltech). The Imager for Mars Pathfinder (IMP) was developed by the University of Arizona Lunar and Planetary Laboratory under contract to JPL. Peter Smith is the Principal Investigator.

  15. Controlling Rydberg atom excitations in dense background gases

    CERN Document Server

    Liebisch, Tara Cubel; Engel, Felix; Nguyen, Huan; Balewski, Jonathan; Lochead, Graham; Böttcher, Fabian; Westphal, Karl M; Kleinbach, Kathrin S; Schmid, Thomas; Gaj, Anita; Löw, Robert; Hofferberth, Sebastian; Pfau, Tilman; Pérez-Ríos, Jesús; Greene, Chris H

    2016-01-01

    We discuss the density shift and broadening of Rydberg spectra measured in cold, dense atom clouds in the context of Rydberg atom spectroscopy done at room temperature, dating back to the experiments of Amaldi and Segr\\`e in 1934. We discuss the theory first developed in 1934 by Fermi to model the mean-field density shift and subsequent developments of the theoretical understanding since then. In particular, we present a model whereby the density shift is calculated using a microscopic model in which the configurations of the perturber atoms within the Rydberg orbit are considered. We present spectroscopic measurements of a Rydberg atom, taken in a Bose-Einstein condensate (BEC) and thermal clouds with densities varying from $5\\times10^{14}\\textrm{cm}^{-3}$ to $9\\times10^{12}\\textrm{cm}^{-3}$. The density shift measured via the spectrum's center of gravity is compared with the mean-field energy shift expected for the effective atom cloud density determined via a time of flight image. Lastly, we present calcul...

  16. A Catalog of HI Clouds in the Large Magellanic Cloud

    CERN Document Server

    Kim, S; Lee, Y; Kim, Y; Jung, Y C; Dopita, M A; Elmegreen, B G; Freeman, K C; Sault, R J; Kesteven, M J; McConnell, D; Chu, Y -H

    2007-01-01

    A 21 cm neutral hydrogen interferometric survey of the Large Magellanic Cloud (LMC) combined with the Parkes multi-beam HI single-dish survey clearly shows that the HI gas is distributed in the form of clumps or clouds. The HI clouds and clumps have been identified using a thresholding method with three three separate brightness temperature thresholds ($T_b$). Each catalog of HI cloud candidates shows a power law relationship between the sizes and the velocity dispersions of the clouds roughly following the Larson Law scaling $\\sigma_v \\propto R^{0.5}$, with steeper indices associated with dynamically hot regions. The clouds in each catalog have roughly constant virial parameters as a function mass suggesting that that the clouds are all in roughly the same dynamical state, but the values of the virial parameter are significantly larger than unity showing that turbulent motions dominate gravity in these clouds. The mass distribution of the clouds is a power law with differential indices between -1.6 and -2.0 ...

  17. CLOUD PARAMETERIZATIONS, CLOUD PHYSICS, AND THEIR CONNECTIONS: AN OVERVIEW.

    Energy Technology Data Exchange (ETDEWEB)

    LIU,Y.; DAUM,P.H.; CHAI,S.K.; LIU,F.

    2002-02-12

    This paper consists of three parts. The first part is concerned with the parameterization of cloud microphysics in climate models. We demonstrate the crucial importance of spectral dispersion of the cloud droplet size distribution in determining radiative properties of clouds (e.g., effective radius), and underline the necessity of specifying spectral dispersion in the parameterization of cloud microphysics. It is argued that the inclusion of spectral dispersion makes the issue of cloud parameterization essentially equivalent to that of the droplet size distribution function, bringing cloud parameterization to the forefront of cloud physics. The second part is concerned with theoretical investigations into the spectral shape of droplet size distributions in cloud physics. After briefly reviewing the mainstream theories (including entrainment and mixing theories, and stochastic theories), we discuss their deficiencies and the need for a paradigm shift from reductionist approaches to systems approaches. A systems theory that has recently been formulated by utilizing ideas from statistical physics and information theory is discussed, along with the major results derived from it. It is shown that the systems formalism not only easily explains many puzzles that have been frustrating the mainstream theories, but also reveals such new phenomena as scale-dependence of cloud droplet size distributions. The third part is concerned with the potential applications of the systems theory to the specification of spectral dispersion in terms of predictable variables and scale-dependence under different fluctuating environments.

  18. Security prospects through cloud computing by adopting multiple clouds

    DEFF Research Database (Denmark)

    Jensen, Meiko; Schwenk, Jörg; Bohli, Jens Matthias

    2011-01-01

    Clouds impose new security challenges, which are amongst the biggest obstacles when considering the usage of cloud services. This triggered a lot of research activities in this direction, resulting in a quantity of proposals targeting the various security threats. Besides the security issues coming...... with the cloud paradigm, it can also provide a new set of unique features which open the path towards novel security approaches, techniques and architectures. This paper initiates this discussion by contributing a concept which achieves security merits by making use of multiple distinct clouds at the same time...

  19. Clouds and Dust Storms

    Science.gov (United States)

    2004-01-01

    [figure removed for brevity, see original site] Released 2 July 2004 The atmosphere of Mars is a dynamic system. Water-ice clouds, fog, and hazes can make imaging the surface from space difficult. Dust storms can grow from local disturbances to global sizes, through which imaging is impossible. Seasonal temperature changes are the usual drivers in cloud and dust storm development and growth. Eons of atmospheric dust storm activity has left its mark on the surface of Mars. Dust carried aloft by the wind has settled out on every available surface; sand dunes have been created and moved by centuries of wind; and the effect of continual sand-blasting has modified many regions of Mars, creating yardangs and other unusual surface forms. This image was acquired during mid-spring near the North Pole. The linear water-ice clouds are now regional in extent and often interact with neighboring cloud system, as seen in this image. The bottom of the image shows how the interaction can destroy the linear nature. While the surface is still visible through most of the clouds, there is evidence that dust is also starting to enter the atmosphere. Image information: VIS instrument. Latitude 68.4, Longitude 180 East (180 West). 38 meter/pixel resolution. Note: this THEMIS visual image has not been radiometrically nor geometrically calibrated for this preliminary release. An empirical correction has been performed to remove instrumental effects. A linear shift has been applied in the cross-track and down-track direction to approximate spacecraft and planetary motion. Fully calibrated and geometrically projected images will be released through the Planetary Data System in accordance with Project policies at a later time. NASA's Jet Propulsion Laboratory manages the 2001 Mars Odyssey mission for NASA's Office of Space Science, Washington, D.C. The Thermal Emission Imaging System (THEMIS) was developed by Arizona State University, Tempe, in collaboration with Raytheon Santa Barbara Remote

  20. Future of Cloud Computing in India

    OpenAIRE

    Pradeep Kumar Tiwari

    2012-01-01

    This paper shows the future of cloud computing in India. This paper also help to understand of future of cloud computing in Indian market .This paper also show the benefits of cloud computing .Cloud computing is not very buzz in India. This paper give the new idea to understand cloud computing and cloud computing future in India. This paper also show the importance of cloud computing. Ito show the growth rate of cloud computing. This paper not only show the cloud computing market it also show...

  1. NASA Glenn Icing Research Tunnel: 2014 Cloud Calibration Procedure and Results

    Science.gov (United States)

    Van Zante, Judith F.; Ide, Robert F.; Steen, Laura E.; Acosta, Waldo J.

    2014-01-01

    The results of the December 2013 to February 2014 Icing Research Tunnel full icing cloud calibration are presented. The calibration steps included establishing a uniform cloud and conducting drop size and liquid water content calibrations. The goal of the calibration was to develop a uniform cloud, and to generate a transfer function from the inputs of air speed, spray bar atomizing air pressure and water pressure to the outputs of median volumetric drop diameter and liquid water content. This was done for both 14 CFR Parts 25 and 29, Appendix C ('typical' icing) and soon-to-be released Appendix O (supercooled large drop) conditions.

  2. NASA Glenn Icing Research Tunnel: 2012 Cloud Calibration Procedure and Results

    Science.gov (United States)

    VanZante, Judith Foss; Ide, Robert F.; Steen, Laura E.

    2012-01-01

    In 2011, NASA Glenn s Icing Research Tunnel underwent a major modification to it s refrigeration plant and heat exchanger. This paper presents the results of the subsequent full cloud calibration. Details of the calibration procedure and results are presented herein. The steps include developing a nozzle transfer map, establishing a uniform cloud, conducting a drop sizing calibration and finally a liquid water content calibration. The goal of the calibration is to develop a uniform cloud, and to build a transfer map from the inputs of air speed, spray bar atomizing air pressure and water pressure to the output of median volumetric droplet diameter and liquid water content.

  3. STELLAR 'EGGS' EMERGE FROM MOLECULAR CLOUD (Star-Birth Clouds in M16)

    Science.gov (United States)

    2002-01-01

    This eerie, dark structure, resembling an imaginary sea serpent's head, is a column of cool molecular hydrogen gas (two atoms of hydrogen in each molecule) and dust that is an incubator for new stars. The stars are embedded inside finger-like protrusions extending from the top of the nebula. Each 'fingertip' is somewhat larger than our own solar system. The pillar is slowly eroding away by the ultraviolet light from nearby hot stars, a process called 'photoevaporation'. As it does, small globules of especially dense gas buried within the cloud is uncovered. These globules have been dubbed 'EGGs' -- an acronym for 'Evaporating Gaseous Globules'. The shadows of the EGGs protect gas behind them, resulting in the finger-like structures at the top of the cloud. Forming inside at least some of the EGGs are embryonic stars -- stars that abruptly stop growing when the EGGs are uncovered and they are separated from the larger reservoir of gas from which they were drawing mass. Eventually the stars emerge, as the EGGs themselves succumb to photoevaporation. The stellar EGGS are found, appropriately enough, in the 'Eagle Nebula' (also called M16 -- the 16th object in Charles Messier's 18th century catalog of 'fuzzy' permanent objects in the sky), a nearby star-forming region 6,500 light-years away in the constellation Serpens. The picture was taken on April 1, 1995 with the Hubble Space Telescope Wide Field and Planetary Camera 2. The color image is constructed from three separate images taken in the light of emission from different types of atoms. Red shows emission from singly-ionized sulfur atoms. Green shows emission from hydrogen. Blue shows light emitted by doubly- ionized oxygen atoms. Credit: Jeff Hester and Paul Scowen (Arizona State University), and NASA Image files in GIF and JPEG format and captions may be accessed on Internet via anonymous ftp from oposite.stsci.edu in /pubinfo:

  4. Do atoms and anti-atoms obey the same laws of physics?

    CERN Multimedia

    Jeffrey Hangst

    2010-01-01

    ALPHA physicists have recently succeeded in trapping anti-atoms for the first time. Being able to hold on to the simplest atoms of antimatter is an important step towards the collaboration’s ultimate goal: precision spectroscopic comparison of hydrogen and antihydrogen. The question they are seeking to answer: do atoms and anti-atoms obey the same laws of physics? The Standard Model says that they must.   The ALPHA Collaboration celebrates the successful results. The ALPHA collaboration has taken it up a gear and trapped 38 atoms of antihydrogen for the first time. Antihydrogen atoms have been mass-produced at the Antiproton Decelerator (AD) since 2002, when ATHENA (ALPHA’s predecessor) and ATRAP learned how to mix clouds of antiprotons and positrons at cryogenic temperatures. However, these anti-atoms were not confined, and flew off in a few microseconds to meet their fate: annihilation with matter in the walls of the experiment. ALPHA uses antiprotons produced at...

  5. Studi Perbandingan Layanan Cloud Computing

    Directory of Open Access Journals (Sweden)

    Afdhal Afdhal

    2014-03-01

    Full Text Available In the past few years, cloud computing has became a dominant topic in the IT area. Cloud computing offers hardware, infrastructure, platform and applications without requiring end-users knowledge of the physical location and the configuration of providers who deliver the services. It has been a good solution to increase reliability, reduce computing cost, and make opportunities to IT industries to get more advantages. The purpose of this article is to present a better understanding of cloud delivery service, correlation and inter-dependency. This article compares and contrasts the different levels of delivery services and the development models, identify issues, and future directions on cloud computing. The end-users comprehension of cloud computing delivery service classification will equip them with knowledge to determine and decide which business model that will be chosen and adopted securely and comfortably. The last part of this article provides several recommendations for cloud computing service providers and end-users.

  6. Shock-cloud interaction and particle acceleration in SN 1006

    CERN Document Server

    Miceli, M; Dubner, G; Decourchelle, A; Orlando, S; Bocchino, F

    2014-01-01

    The supernova remnant SN 1006 is a powerful source of high-energy particles and evolves in a relatively tenuous and uniform environment, though interacting with an atomic cloud in its northwestern limb. The X-ray image of SN 1006 reveals an indentation in the southwestern part of the shock front and the HI maps show an isolated cloud (southwestern cloud) having the same velocity as the northwestern cloud and whose morphology fits perfectly in the indentation. We performed spatially resolved spectral analysis of a set of small regions in the southwestern nonthermal limb and studied the deep X-ray spectra obtained within the XMM-Newton SN 1006 Large Program. We also analyzed archive HI data, obtained combining single dish and interferometric observations. We found that the best-fit value of the N_H derived from the X-ray spectra significantly increases in regions corresponding to the southwestern cloud, while the cutoff energy of the synchrotron emission decreases. The amount of the N_H variations corresponds p...

  7. Atom Lithography with a Chromium Atomic Beam

    Institute of Scientific and Technical Information of China (English)

    ZHANG Wen-Tao; LI Tong-Bao

    2006-01-01

    @@ Direct write atom lithography is a new technique in which resonant light is used to pattern an atomic beam and the nanostructures are formed when the atoms deposit on the substrate. We design an experiment setup to fabricate chromium nanolines by depositing an atomic beam of 52 Cr through an off-resonant laser standing wave with the wavelength of 425.55 nm onto a silicon substrate. The resulting nanolines exhibit a period of 215 ± 3 nm with height of 1 nm.

  8. Clouds in Super-Earth Atmospheres: Chemical Equilibrium Calculations

    Science.gov (United States)

    Mbarek, Rostom; Kempton, Eliza M.-R.

    2016-08-01

    Recent studies have unequivocally proven the existence of clouds in super-Earth atmospheres. Here we provide a theoretical context for the formation of super-Earth clouds by determining which condensates are likely to form under the assumption of chemical equilibrium. We study super-Earth atmospheres of diverse bulk composition, which are assumed to form by outgassing from a solid core of chondritic material, following Schaefer & Fegley. The super-Earth atmospheres that we study arise from planetary cores made up of individual types of chondritic meteorites. They range from highly reducing to oxidizing and have carbon to oxygen (C:O) ratios that are both sub-solar and super-solar, thereby spanning a range of atmospheric composition that is appropriate for low-mass exoplanets. Given the atomic makeup of these atmospheres, we minimize the global Gibbs free energy of formation for over 550 gases and condensates to obtain the molecular composition of the atmospheres over a temperature range of 350-3000 K. Clouds should form along the temperature-pressure boundaries where the condensed species appear in our calculation. We find that the composition of condensate clouds depends strongly on both the H:O and C:O ratios. For the super-Earth archetype GJ 1214b, KCl and ZnS are the primary cloud-forming condensates at solar composition, in agreement with previous work. However, for oxidizing atmospheres, K2SO4 and ZnO condensates are favored instead, and for carbon-rich atmospheres with super-solar C:O ratios, graphite clouds appear. For even hotter planets, clouds form from a wide variety of rock-forming and metallic species.

  9. Shock Waves in Cloud Cavitation

    OpenAIRE

    Brennen, C. E.; Reisman, G. E.; Wang, Y.-C.

    1997-01-01

    Thie paper described experimental and computational investigations of the dynamics of clouds of cavitation bubbles. Recent studies have confirmed that the interactions between bubbles as they are manifest in the dynamics of bubble clouds lead to generation of very large impulsive pressures which, in turn, cause substantial enhancement of the radiated noise and the material damage which results from this form of cavitation. The experimental program focuses on cloud cavitation formed on th...

  10. Cavity-aided magnetic-resonance microscopy of atoms in optical lattices

    CERN Document Server

    Purdy, Tom P; Brooks, Daniel W C; Botter, Thierry; Stamper-Kurn, Dan M

    2010-01-01

    Magnetic resonance imaging (MRI) is a powerful technique for investigating the microscopic properties and dynamics of physical systems. In this work we demonstrate state-sensitive MRI of ultracold atoms in an optical lattice. Single-shot spatial resolution is 120 nm, well below the lattice spacing, and number sensitivity is +/-2.4 for 150 atoms on a single site, well below Poissonian atom-number fluctuations. We achieve this by combining high-spatial-resolution control over the atomic spin using an atom chip, together with nearly quantum-limited spin measurement, obtained by dispersively coupling the atoms to light in a high-finesse optical cavity. The MRI is minimally disruptive of the atoms' internal state, preserving the magnetisation of the gas for subsequent experiments. Using this technique, we observe the nonequilibrium transport dynamics of the atoms among individual lattice sites. We see the atom cloud initially expand ballistically, followed by the onset of interaction-inhibited transport.

  11. Cooperativity in light scattering by cold atoms

    CERN Document Server

    Bienaime, Tom; Piovella, Nicola; Kaiser, Robin

    2012-01-01

    A cloud of cold N two-level atoms driven by a resonant laser beam shows cooperative effects both in the scattered radiation field and in the radiation pressure force acting on the cloud center-of-mass. The induced dipoles synchronize and the scattered light presents superradiant and/or subradiant features. We present a quantum description of the process in terms of a master equation for the atomic density matrix in the scalar, Born-Markov approximations, reduced to the single-excitation limit. From a perturbative approach for weak incident field, we derive from the master equation the effective Hamiltonian, valid in the linear regime. We discuss the validity of the driven timed Dicke ansatz and of a partial wave expansion for different optical thicknesses and we give analytical expressions for the scattered intensity and the radiation pressure force on the center of mass. We also derive an expression for collective suppression of the atomic excitation and the scattered light by these correlated dipoles.

  12. Cloud computing theory and practice

    CERN Document Server

    Marinescu, Dan C

    2013-01-01

    Cloud Computing: Theory and Practice provides students and IT professionals with an in-depth analysis of the cloud from the ground up. Beginning with a discussion of parallel computing and architectures and distributed systems, the book turns to contemporary cloud infrastructures, how they are being deployed at leading companies such as Amazon, Google and Apple, and how they can be applied in fields such as healthcare, banking and science. The volume also examines how to successfully deploy a cloud application across the enterprise using virtualization, resource management and the ri

  13. The Ethics of Cloud Computing.

    Science.gov (United States)

    de Bruin, Boudewijn; Floridi, Luciano

    2017-02-01

    Cloud computing is rapidly gaining traction in business. It offers businesses online services on demand (such as Gmail, iCloud and Salesforce) and allows them to cut costs on hardware and IT support. This is the first paper in business ethics dealing with this new technology. It analyzes the informational duties of hosting companies that own and operate cloud computing datacentres (e.g., Amazon). It considers the cloud services providers leasing 'space in the cloud' from hosting companies (e.g., Dropbox, Salesforce). And it examines the business and private 'clouders' using these services. The first part of the paper argues that hosting companies, services providers and clouders have mutual informational (epistemic) obligations to provide and seek information about relevant issues such as consumer privacy, reliability of services, data mining and data ownership. The concept of interlucency is developed as an epistemic virtue governing ethically effective communication. The second part considers potential forms of government restrictions on or proscriptions against the development and use of cloud computing technology. Referring to the concept of technology neutrality, it argues that interference with hosting companies and cloud services providers is hardly ever necessary or justified. It is argued, too, however, that businesses using cloud services (e.g., banks, law firms, hospitals etc. storing client data in the cloud) will have to follow rather more stringent regulations.

  14. Cosmic rays, clouds, and climate

    DEFF Research Database (Denmark)

    Marsh, N.; Svensmark, Henrik

    2000-01-01

    in the Earth's radiation budget through trapping outgoing radiation and reflecting incoming radiation. If a physical link between these two features can be established, it would provide a mechanism linking solar activity and Earth's climate. Recent satellite observations have further revealed a correlation...... between cosmic ray flux and low cloud top temperature. The temperature of a cloud depends on the radiation properties determined by its droplet distribution. Low clouds are warm (> 273 K) and therefore consist of liquid water droplets. At typical atmospheric supersaturations (similar to1%) a liquid cloud...

  15. Design and fabrication of diffractive atom chips for laser cooling and trapping

    CERN Document Server

    Cotter, J P; Griffin, P F; Rabey, I M; Docherty, K; Riis, E; Arnold, A S; Hinds, E A

    2016-01-01

    It has recently been shown that optical reflection gratings fabricated directly into an atom chip provide a simple and effective way to trap and cool substantial clouds of atoms [1,2]. In this article we describe how the gratings are designed and micro-fabricated and we characterise their optical properties, which determine their effectiveness as a cold atom source. We use simple scalar diffraction theory to understand how the morphology of the gratings determines the power in the diffracted beams.

  16. Atomic References for Measuring Small Accelerations

    Science.gov (United States)

    Maleki, Lute; Yu, Nan

    2009-01-01

    Accelerometer systems that would combine the best features of both conventional (e.g., mechanical) accelerometers and atom interferometer accelerometers (AIAs) have been proposed. These systems are intended mainly for use in scientific research aboard spacecraft but may also be useful on Earth in special military, geological, and civil-engineering applications. Conventional accelerometers can be sensitive, can have high dynamic range, and can have high frequency response, but they lack accuracy and long-term stability. AIAs have low frequency response, but they offer high sensitivity, and high accuracy for measuring small accelerations. In a system according to the proposal, a conventional accelerometer would be used to perform short-term measurements of higher-frequency components of acceleration, while an AIA would be used to provide consistent calibration of, and correction of errors in, the measurements of the conventional accelerometer in the lower-frequency range over the long term. A brief description of an AIA is prerequisite to a meaningful description of a system according to the proposal. An AIA includes a retroreflector next to one end of a cell that contains a cold cloud of atoms in an ultrahigh vacuum. The atoms in the cloud are in free fall. The retroreflector is mounted on the object, the acceleration of which is to be measured. Raman laser beams are directed through the cell from the end opposite the retroreflector, then pass back through the cell after striking the retroreflector. The Raman laser beams together with the cold atoms measure the relative acceleration, through the readout of the AIA, between the cold atoms and the retroreflector.

  17. Advances in atomic spectroscopy

    CERN Document Server

    Sneddon, J

    2000-01-01

    This fifth volume of the successful series Advances in Atomic Spectroscopy continues to discuss and investigate the area of atomic spectroscopy.It begins with a description of the use of various atomic spectroscopic methods and applications of speciation studies in atomic spectroscopy. The emphasis is on combining atomic spectroscopy with gas and liquid chromatography. In chapter two the authors describe new developments in tunable lasers and the impact they will have on atomic spectroscopy. The traditional methods of detection, such as photography and the photomultiplier, and how they are being replaced by new detectors is discussed in chapter three. The very active area of glow discharge atomic spectrometry is presented in chapter four where, after a brief introduction and historical review, the use of glow discharge lamps for atomic spectroscopy and mass spectrometry are discussed. Included in this discussion is geometry and radiofrequency power. The future of this source in atomic spectroscopy is also dis...

  18. Atomic and molecular manipulation

    CERN Document Server

    Mayne, Andrew J

    2011-01-01

    Work with individual atoms and molecules aims to demonstrate that miniaturized electronic, optical, magnetic, and mechanical devices can operate ultimately even at the level of a single atom or molecule. As such, atomic and molecular manipulation has played an emblematic role in the development of the field of nanoscience. New methods based on the use of the scanning tunnelling microscope (STM) have been developed to characterize and manipulate all the degrees of freedom of individual atoms and molecules with an unprecedented precision. In the meantime, new concepts have emerged to design molecules and substrates having specific optical, mechanical and electronic functions, thus opening the way to the fabrication of real nano-machines. Manipulation of individual atoms and molecules has also opened up completely new areas of research and knowledge, raising fundamental questions of "Optics at the atomic scale", "Mechanics at the atomic scale", Electronics at the atomic scale", "Quantum physics at the atomic sca...

  19. Using cloud computing infrastructure with CloudBioLinux, CloudMan, and Galaxy.

    Science.gov (United States)

    Afgan, Enis; Chapman, Brad; Jadan, Margita; Franke, Vedran; Taylor, James

    2012-06-01

    Cloud computing has revolutionized availability and access to computing and storage resources, making it possible to provision a large computational infrastructure with only a few clicks in a Web browser. However, those resources are typically provided in the form of low-level infrastructure components that need to be procured and configured before use. In this unit, we demonstrate how to utilize cloud computing resources to perform open-ended bioinformatic analyses, with fully automated management of the underlying cloud infrastructure. By combining three projects, CloudBioLinux, CloudMan, and Galaxy, into a cohesive unit, we have enabled researchers to gain access to more than 100 preconfigured bioinformatics tools and gigabytes of reference genomes on top of the flexible cloud computing infrastructure. The protocol demonstrates how to set up the available infrastructure and how to use the tools via a graphical desktop interface, a parallel command-line interface, and the Web-based Galaxy interface.

  20. Sensitive Detection of Individual Neutral Atoms in a Strong Coupling Cavity QED System

    Institute of Scientific and Technical Information of China (English)

    ZHANG Peng-Fei; ZHANG Yu-Chi; LI Gang; DU Jin-Jin; ZHANG Yan-Feng; GUO Yan-Qiang; WANG Jun-Min; ZHANG Tian-Cai; LI Wei-Dong

    2011-01-01

    We experimentally demonstrate real-time detection of individual cesium atoms by using a high-finesse optical micro-cavity in a strong coupling regime.A cloud of cesium atoms is trapped in a magneto-optical trap positioned at 5 mm above the micro-cavity center.The atoms fall down freely in gravitation after shutting off the magnetooptical trap and pass through the cavity.The cavity transmission is strongly affected by the atoms in the cavity, which enables the micro-cavity to sense the atoms individually.We detect the single atom transits either in the resonance or various detunings.The single atom vacuum-Rabi splitting is directly measured to be Ω = 2π × 23.9 MHz.The average duration of atom-cavity coupling of about 110μs is obtained according to the probability distribution of the atom transits.%@@ We experimentally demonstrate real-time detection of individual cesium atoms by using a high-finesse optical micro-cavity in a strong coupling regime.A cloud of cesium atoms is trapped in a magneto-optical trap positioned at 5mm above the micro-cavity center.The atoms fall down freely in gravitation after shutting off the magnetooptical trap and pass through the cavity.The cavity transmission is strongly affected by the atoms in the cavity, which enables the micro-cavity to sense the atoms individually.We detect the single atom transits either in the resonance or various detunings.The single atom vacuum-Rabi splitting is directly measured to be Ω=2π×23.9 MHz.The average duration of atom-cavity coupling of about 110μs is obtained according to the probability distribution of the atom transits.

  1. MAGIA - using atom interferometry to determine the Newtonian gravitational constant

    Energy Technology Data Exchange (ETDEWEB)

    Stuhler, J; Fattori, M; Petelski, T; Tino, G M [Dipartimento di Fisica and LENS, Universita di Firenze, INFN - Sezione di Firenze, Via Sansone 1, I-50019 Sesto Fiorentino (Finland), Italy

    2003-04-01

    We describe our experiment MAGIA (misura accurata di G mediante interferometria atomica), in which we will use atom interferometry to perform a high precision measurement of the Newtonian gravitational constant G. Free-falling laser-cooled atoms in a vertical atomic fountain will be accelerated due to the gravitational potential of nearby source masses (SMs). Detecting this acceleration with techniques of Raman atom interferometry will enable us to assign a value to G. To suppress systematic effects we will implement a double-differential measurement. This includes launching two atom clouds in a gradiometer configuration and moving the SMs to different vertical positions. We briefly summarize the general idea of the MAGIA experiment and put it in the context of other high precision G-measurements. We present the current status of the experiment and report on analyses of the expected measurement accuracy.

  2. Defining the cloud battlefield - supporting security assessments by cloud customers

    NARCIS (Netherlands)

    Bleikertz, Sören; Mastelic, Toni; Pape, Sebastian; Pieters, Wolter; Dimkov, Trajce

    2013-01-01

    Cloud computing is becoming more and more popular, but security concerns overshadow its technical and economic benefits. In particular, insider attacks and malicious insiders are considered as one of the major threats and risks in cloud computing. As physical boundaries disappear and a variety of pa

  3. Mapping in the cloud

    CERN Document Server

    Peterson, Michael P

    2014-01-01

    This engaging text provides a solid introduction to mapmaking in the era of cloud computing. It takes students through both the concepts and technology of modern cartography, geographic information systems (GIS), and Web-based mapping. Conceptual chapters delve into the meaning of maps and how they are developed, covering such topics as map layers, GIS tools, mobile mapping, and map animation. Methods chapters take a learn-by-doing approach to help students master application programming interfaces and build other technical skills for creating maps and making them available on the Internet. Th

  4. Heroku cloud application development

    CERN Document Server

    Hanjura, Anubhav

    2014-01-01

    An easy-to-follow, hands-on guide that clearly explains the various components of the Heroku platform and provides step-by-step guidance as well as numerous examples on how to build and troubleshoot robust and scalable production-ready web applications on the Heroku platform.This book is intended for those who want to learn Heroku the right way. Perhaps you are new to Heroku or are someone who has heard about Heroku but have not built anything significant with it. You should have knowledge or familiarity with cloud computing and basic knowledge of database and network deployment.

  5. Grids, Clouds and Virtualization

    CERN Document Server

    Cafaro, Massimo

    2011-01-01

    Research into grid computing has been driven by the need to solve large-scale, increasingly complex problems for scientific applications. Yet the applications of grid computing for business and casual users did not begin to emerge until the development of the concept of cloud computing, fueled by advances in virtualization techniques, coupled with the increased availability of ever-greater Internet bandwidth. The appeal of this new paradigm is mainly based on its simplicity, and the affordable price for seamless access to both computational and storage resources. This timely text/reference int

  6. Towards a random laser with cold atoms

    CERN Document Server

    Guerin, William; Michaud, Franck; Brivio, Davide; Froufe-Pérez, Luis S; Carminati, Rémi; Eremeev, Vitalie; Goetschy, Arthur; Skipetrov, Sergey S; Kaiser, Robin

    2009-01-01

    Atoms can scatter light and they can also amplify it by stimulated emission. From this simple starting point, we examine the possibility of realizing a random laser in a cloud of laser-cooled atoms. The answer is not obvious as both processes (elastic scattering and stimulated emission) seem to exclude one another: pumping atoms to make them behave as amplifier reduces drastically their scattering cross-section. However, we show that even the simplest atom model allows the efficient combination of gain and scattering. Moreover, supplementary degrees of freedom that atoms offer allow the use of several gain mechanisms, depending on the pumping scheme. We thus first study these different gain mechanisms and show experimentally that they can induce (standard) lasing. We then present how the constraint of combining scattering and gain can be quantified, which leads to an evaluation of the random laser threshold. The results are promising and we draw some prospects for a practical realization of a random laser wit...

  7. Storing Quantum Information via Atomic Dark Resonances

    CERN Document Server

    Caruso, Filippo

    2010-01-01

    In this thesis, after a brief review of some concepts of Quantum Optics, we analyze a three-level atomic system in the conditions of electromagnetically induced transparency (EIT), and we investigate the propagation of a gaussian pulse along a cigar-shaped cloud of both cold and hot atoms in EIT regime. In particular, we show that it is possible to amplify a slow propagating pulse without population inversion. We also analyze the regime of anomalous light propagation showing that it is possible to observe superluminal energy propagation. In these conditions, it is possible to imprint reversibly ('write') the information carried by the photons onto the atoms, specifically as a coherent pattern of atomic spins, and later the information stored in the atomic spins can be transferred back ('read') to the light field, implementing in this way a quantum memory. Besides, we analyze the propagation of a quantum field in an EIT medium sustaining dark state polaritons (DSP) in a quasi-particle picture. Here, the decohe...

  8. Alterations of Cloud Microphysics Due to Cloud Processed CCN

    Science.gov (United States)

    Hudson, J. G.; Tabor, S. S.; Noble, S. R., Jr.

    2015-12-01

    High-resolution CCN spectra have revealed bimodality (Hudson et al. 2015) similar to aerosol size spectra (e.g., Hoppel et al. 1985). Bimodality is caused by chemical and physical cloud processes that increase mass or hygroscopicity of only CCN that produced activated cloud droplets. Bimodality is categorized by relative CCN concentrations (NCCN) within the two modes, Nu-Np; i.e., NCCN within the higher critical supersaturation, Sc, mode that did not undergo cloud processing minus NCCN within the lower Sc mode that was cloud processed. Lower, especially negative, Nu-Np designates greater processing. The table shows regressions between Nu-Np and characteristics of clouds nearest the CCN measurements. ICE-T MASE parameter R SL R SL Nc 0.17 93.24 -0.26 98.65 MD -0.31 99.69 0.33 99.78 σ -0.27 99.04 0.48 100.00 Ld -0.31 99.61 0.38 99.96 Table. Correlation coefficients, R, and one-tailed significance levels in percent, SL, for Nu-Np with microphysics of the clouds closest to each CCN measurement, 75 ICE-T and 74 MASE cases. Nc is cloud droplet concentration, MD is cloud droplet mean diameter, σ is standard deviation of cloud droplet spectra, Ldis drizzle drop LWC. Two aircraft field campaigns, Ice in Clouds Experiment-Tropical (ICE-T) and Marine Stratus/Stratocumulus Experiment (MASE) show opposite R signs because coalescence dominated cloud processing in low altitude ICE-T cumuli whereas chemical transformations predominated in MASE low altitude polluted stratus. Coalescence reduces Nc and NCCN, which thus increases MD, and σ, which promote Ld. Chemical transformations, e.g., SO2 to SO4, increase CCN hygroscopicity, thus reducing Sc, but not affecting Nc or NCCN. Lower Sc CCN are capable of producing greater Nc in subsequent cloud cycles, which leads to lower MD and σ which reduce Ld (figure). These observations are consistent with cloud droplet growth models for the higher vertical wind (W) of cumuli and lower W of stratus. Coalescence thus reduces the indirect

  9. Statistical properties of cloud lifecycles in cloud-resolving models

    Directory of Open Access Journals (Sweden)

    R. S. Plant

    2008-12-01

    Full Text Available A new technique is described for the analysis of cloud-resolving model simulations, which allows one to investigate the statistics of the lifecycles of cumulus clouds. Clouds are tracked from timestep-to-timestep within the model run. This allows for a very simple method of tracking, but one which is both comprehensive and robust. An approach for handling cloud splits and mergers is described which allows clouds with simple and complicated time histories to be compared within a single framework. This is found to be important for the analysis of an idealized simulation of radiative-convective equilibrium, in which the moist, buoyant, updrafts (i.e., the convective cores were tracked. Around half of all such cores were subject to splits and mergers during their lifecycles. For cores without any such events, the average lifetime is 30 min, but events can lengthen the typical lifetime considerably.

  10. CloudGenius: Decision Support for Web Server Cloud Migration

    CERN Document Server

    Menzel, Michael

    2012-01-01

    Cloud computing is the latest computing paradigm that delivers hardware and software resources as virtualized services in which users are free from the burden of worrying about the low-level system administration details. Migrating Web applications to Cloud services and integrating Cloud services into existing computing infrastructures is non-trivial. It leads to new challenges that often require innovation of paradigms and practices at all levels: technical, cultural, legal, regulatory, and social. The key problem in mapping Web applications to virtualized Cloud services is selecting the best and compatible mix of software images (e.g., Web server image) and infrastructure services to ensure that Quality of Service (QoS) targets of an application are achieved. The fact that, when selecting Cloud services, engineers must consider heterogeneous sets of criteria and complex dependencies between infrastructure services and software images, which are impossible to resolve manually, is a critical issue. To overcom...

  11. Cloud ERP and Cloud Accounting Software in Romania

    Directory of Open Access Journals (Sweden)

    Gianina MIHAI

    2015-05-01

    Full Text Available Nowadays, Cloud Computing becomes a more and more fashionable concept in the IT environment. There is no unanimous opinion on the definition of this concept, as it covers several versions of the newly emerged stage in the IT. But in fact, Cloud Computing should not suggest anything else than simplicity. Thus, in short, simple terms, Cloud Computing can be defined as a solution to use external IT resources (servers, storage media, applications and services, via Internet. Cloud computing is nothing more than the promise of an easy accessible technology. If the promise will eventually turn into something certain yet remains to be seen. In our opinion it is too early to make an assertion. In this article, our purpose is to find out what is the Romanian offer of ERP and Accounting software applications in Cloud and / or as services in SaaS version. Thus, we conducted an extensive study whose results we’ll present in the following.

  12. Performance Evaluation of the CloudStack Private Cloud

    Directory of Open Access Journals (Sweden)

    Mumtaz M.Ali AL-Mukhtar

    2014-02-01

    Full Text Available The number of open source cloud platforms is increasing day by day.The features of these platforms vary significantly and this creates a difficulty for cloud consumers to choose the platforms based on their requirments.In this paper we build a private cloud using Cloudstack , a popular open source platform used to built Infrastructure as a Service(IaaS cloud.We presents its architecure and analyze performance of virtual machines initiated and managed by the Cloudstack in terms of CPU usage,memory bandwidth,disk I/O speed and networking performance using suitable benchmarks.Different vitual machine management operations such as add ,delete and live migration are also evaluated .The performance evaluation of Cloudstack can help to determine its suability to be adopted as on premise cloud solution.

  13. Daytime Land Cloud Detection Enhancements For The VIIRS Cloud Mask

    Science.gov (United States)

    Frey, R. A.; Heidinger, A. K.; Hutchinson, K. D.; Iisager, B.

    2005-12-01

    The first in a new series of polar-orbiting satellites, National Polar-Orbiting Operational Satellite System (NPOESS), is scheduled to be launched in 2008. The Visible/Infrared Imager/Radiometer Suite (VIIRS) is a major component of the series and will replace the AVHRR instrument on operational polar orbiters. A crucial piece of the VIIRS data processing chain is the VIIRS Cloud Mask (VCM). A high quality cloud detection system is necessary as a first step for most if not all of the algorithms which produce the 18 EDRs (Environmental Data Records) from VIIRS. A cloud detection scheme similar to the one developed for MODIS data (MOD35) will be implemented for VIIRS, but several enhancements have been investigated for daytime land scenes. During daylight hours over vegetated surfaces and in the absence of snow cover, use of the high contrast between clouds and surface in visible wavelengths offers the most sensitive clear/cloud discrimination. However, visible surface reflectances vary from about 10% over tropical rain forests to as high as 50% in arid regions, making the use of a single cloud test threshold very difficult. A set of reflectance thresholds based on NDVI and scattering angle has been developed from historical AVHRR data. Clear-sky NDVIs were accumulated as a function of scattering angle over a multi-year period and from morning and afternoon satellites, from which cloud test thresholds were developed. The thresholds were then tested on several AVHRR scenes. For extremely arid scenes, where visible reflectances from clouds and surface are similar, a cloud test using 0.4 μm data has been devised. This poster describes the development of both new cloud tests and associated thresholds, from initial tests using MODIS data to the calculation and implementation of the thresholds.

  14. Study to perform preliminary experiments to evaluate particle generation and characterization techniques for zero-gravity cloud physics experiments

    Science.gov (United States)

    Katz, U.

    1982-01-01

    Methods of particle generation and characterization with regard to their applicability for experiments requiring cloud condensation nuclei (CCN) of specified properties were investigated. Since aerosol characterization is a prerequisite to assessing performance of particle generation equipment, techniques for characterizing aerosol were evaluated. Aerosol generation is discussed, and atomizer and photolytic generators including preparation of hydrosols (used with atomizers) and the evaluation of a flight version of an atomizer are studied.

  15. High Velocity Cloud Edges and Mini-HVCs

    CERN Document Server

    Hoffman, G L; Salpeter, E E

    2002-01-01

    Arecibo mapping is reported of the neutral hydrogen distribution along selected directions out from the centers of two small High Velocity Clouds (HVC), W486 and W491. Both HVCs have a small inner region where the neutral hydrogen column density N_HI decreases slowly and a larger outer region where N_HI declines more rapidly, smoothly and exponentially from ~ 2 X 10^19 atoms cm^-2 down to < 10^18 atoms cm^-2. Line widths, and presumably temperature and turbulence, do not increase in the outermost regions. Therefore pressure decreases smoothly, making confinement by dark matter gravity more likely than confinement by external pressure. The more extended HVC, W491, has a superimposed small cloud (which we dub a ``mini-HVC''), offset by 66 km s^-1 in velocity along the line of sight with peak column density about 5 X 10^18 atoms cm^-2. Preliminary data toward future mapping of two more HVCs reveals two more mini-HVCs of similarly small size and central column density a bit less than 1 X 10^19 atoms cm^-2. We ...

  16. Local Atomic Structure Deviation from Average Structure of Na0.5Bi0.5TiO3: Combined X-ray and Neutron Total Scattering Study

    Science.gov (United States)

    2013-03-27

    model into a single unit cell produced “ point clouds ” of approximately a thousand atoms at each crystallographic site. These are plotted as a function...In order to determine the origin of the two distinct A- O bonding environments, the Na+ and Bi3+ point clouds from Fig. 8 are further investigated...bonding arrangement is the effect on the possible ferroelectric domain FIG. 8. (Color online) Folded RMC models produce “ point clouds ” of atoms at each

  17. Growing Cloud Computing Efficiency

    Directory of Open Access Journals (Sweden)

    Dr. Mohamed F. AlAjmi, Dr. Arun Sharma, Shakir Khan

    2012-05-01

    Full Text Available Cloud computing is basically altering the expectation for how and when computing, storage and networking assets should be allocated, managed and devoted. End-users are progressively more sensitive in response time of services they ingest. Service Developers wish for the Service Providers to make sure or give the ability for dynamically assigning and managing resources in respond to alter the demand patterns in real-time. Ultimately, Service Providers are under anxiety to build their infrastructure to facilitate real-time end-to-end visibility and energetic resource management with well grained control to decrease total cost of tenure for improving quickness. What is required to rethink of the underlying operating system and management infrastructure to put up the on-going renovation of data centre from the traditional server-centric architecture model to a cloud or network centric model? This paper projects and describes a indication model for a network centric data centre infrastructure management heap that make use of it and validates key ideas that have enabled dynamism, the quality of being scalable, reliability and security in the telecommunication industry to the computing engineering. Finally, the paper will explain a proof of concept classification that was implemented to show how dynamic resource management can be enforced to enable real-time service guarantee for network centric data centre architecture.

  18. Cloud Native Java

    CERN Document Server

    CERN. Geneva

    2017-01-01

    “It is not necessary to change. Survival is not mandatory.” -W. Edwards Deming Work takes time to flow through an organization and ultimately be deployed to production where it captures value. It’s critical to reduce time-to-production. Software – for many organizations and industries – is a competitive advantage. Organizations break their larger software ambitions into smaller, independently deployable, feature -centric batches of work – microservices. In order to reduce the round-trip between stations of work, organizations collapse or consolidate as much of them as possible and automate the rest; developers and operations beget “devops,” cloud-based services and platforms (like Cloud Foundry) automate operations work and break down the need for ITIL tickets and change management boards. But velocity, for velocity’s sake, is dangerous. Microservices invite architectural complexity that few are prepared to address. In this talk, we’ll look at how high performance organizations like Tic...

  19. Constraining the Properties of Cold Interstellar Clouds

    Science.gov (United States)

    Spraggs, Mary Elizabeth; Gibson, Steven J.

    2016-01-01

    Since the interstellar medium (ISM) plays an integral role in star formation and galactic structure, it is important to understand the evolution of clouds over time, including the processes of cooling and condensation that lead to the formation of new stars. This work aims to constrain and better understand the physical properties of the cold ISM by utilizing large surveys of neutral atomic hydrogen (HI) 21cm spectral line emission and absorption, carbon monoxide (CO) 2.6mm line emission, and multi-band infrared dust thermal continuum emission. We identify areas where the gas may be cooling and forming molecules using HI self-absorption (HISA), in which cold foreground HI absorbs radiation from warmer background HI emission.We are developing an algorithm that uses total gas column densities inferred from Planck and other FIR/sub-mm data in parallel with CO and HISA spectral line data to determine the gas temperature, density, molecular abundance, and other properties as functions of position. We can then map these properties to study their variation throughout an individual cloud as well as any dependencies on location or environment within the Galaxy.Funding for this work was provided by the National Science Foundation, the NASA Kentucky Space Grant Consortium, the WKU Ogden College of Science and Engineering, and the Carol Martin Gatton Academy for Mathematics and Science in Kentucky.

  20. Cloud computing assessing the risks

    CERN Document Server

    Carstensen, Jared; Golden, Bernard

    2012-01-01

    Cloud Computing: Assessing the risks answers these questions and many more. Using jargon-free language and relevant examples, analogies and diagrams, it is an up-to-date, clear and comprehensive guide the security, governance, risk, and compliance elements of Cloud Computing.

  1. Big Data in der Cloud

    DEFF Research Database (Denmark)

    Leimbach, Timo; Bachlechner, Daniel

    2014-01-01

    Technology assessment of big data, in particular cloud based big data services, for the Office for Technology Assessment at the German federal parliament (Bundestag)......Technology assessment of big data, in particular cloud based big data services, for the Office for Technology Assessment at the German federal parliament (Bundestag)...

  2. Cloud computing and services science

    NARCIS (Netherlands)

    Ivanov, Ivan; Sinderen, van Marten; Shishkov, Boris

    2012-01-01

    This book is essentially a collection of the best papers of the International Conference on Cloud Computing and Services Science (CLOSER), which was held in Noordwijkerhout, The Netherlands on May 7–9, 2011. The conference addressed technology trends in the domain of cloud computing in relation to a

  3. How to govern the cloud?

    NARCIS (Netherlands)

    Prüfer, J.; Diamond, S.; Wainwright, N.

    2013-01-01

    This paper applies economic governance theory to the cloud computing industry. We analyze which governance institution may be best suited to solve the problems stemming from asymmetric information about the true level of data protection, security, and accountability offered by cloud service provider

  4. Enhancing accountability in the cloud

    NARCIS (Netherlands)

    Jaatun, M.; Pearson, S.; Gittler, F.; Leenes, Ronald; van der Zwet, Maartje

    2016-01-01

    This article focuses on the role of accountability within information management, particularly in cloud computing contexts. Key to this notion is that an accountable Cloud Provider must demonstrate both willingness and capacity for being a responsible steward of other people's data. More generally,

  5. Cloud $_{Micro}$Atlas$^{∗}$

    Indian Academy of Sciences (India)

    Rama Govindarajan; S Ravichandran

    2017-03-01

    We begin by outlining the life cycle of a tall cloud, and thenbriefly discuss cloud systems. We choose one aspect of thislife cycle, namely, the rapid growth of water droplets in ice freeclouds, to then discuss in greater detail. Taking a singlevortex to be a building block of turbulence, we demonstrateone mechanism by which we believe droplets grow rapidly.

  6. The ethics of cloud computing

    NARCIS (Netherlands)

    de Bruin, Boudewijn; Floridi, Luciano

    2016-01-01

    Cloud computing is rapidly gaining traction in business. It offers businesses online services on demand (such as Gmail, iCloud and Salesforce) and allows them to cut costs on hardware and IT support. This is the first paper in business ethics dealing with this new technology. It analyzes the informa

  7. International Satellite Cloud Climatology Project (ISCCP)

    Data.gov (United States)

    National Aeronautics and Space Administration — International Satellite Cloud Climatology Project (ISCCP) focuses on the distribution and variation of cloud radiative properties to improve the understanding of the...

  8. Presenting the Bohr Atom.

    Science.gov (United States)

    Haendler, Blanca L.

    1982-01-01

    Discusses the importance of teaching the Bohr atom at both freshman and advanced levels. Focuses on the development of Bohr's ideas, derivation of the energies of the stationary states, and the Bohr atom in the chemistry curriculum. (SK)

  9. Climate Effects of Cloud Modified CCN-Cloud Interactions

    Science.gov (United States)

    Noble, S. R., Jr.; Hudson, J. G.

    2015-12-01

    Cloud condensation nuclei (CCN) play an important role in the climate system through the indirect aerosol effect (IAE). IAE is one of the least understood aspects of the climate system as many cloud processes are complicated. Many studies of aerosol-cloud interaction involve CCN interaction with cloud droplet concentrations (Nc), cloud microphysics, and radiative properties. However, fewer studies investigate how cloud processes modify CCN. Upon evaporation from non-precipitating clouds, CCN distributions develop bimodal shaped distributions (Hoppel et al. 1986). Activated CCN participate in cloud processing that is either chemical: aqueous oxidation; or physical: Brownian scavenging, collision and coalescence. Chemical processing does not change CCN concentration (NCCN) but reduces critical supersaturations (Sc; larger size) (Feingold and Kreidenweis, 2000) while physical processing reduces NCCN and Sc. These processes create the minima in the bimodal CCN distributions (Hudson et al., 2015). Updraft velocity (W) and NCCN are major factors on how these modified CCN distributions affect clouds. Panel a shows two nearby CCN distributions in the MArine Stratus/stratocumulus Experiment (MASE), which have similar concentrations, but the bimodal one (red) has been modified by cloud processing. In a simplified cloud droplet model, the modified CCN then produces higher Nc (panel b) and smaller droplet mean diameters (MD; panel c) when compared to the unmodified CCN (black) for W lower than 50 cm/s. The better CCN (lower Sc) increase competition among droplets reducing MD and droplet distribution spread (σ) which acts to reduce drizzle. Competition is created by limited available condensate due to lower S created by the low W (50 cm/s) typical of cumuli, Ncis reduced and MD is increased from the modified CCN distribution (panels b & c). Here, CCN cloud processing increases MD and σ leading to increased drizzle. Improved climate prediction requires a better understanding

  10. The Future of Cloud Computing

    Directory of Open Access Journals (Sweden)

    Anamaroa SIclovan

    2011-12-01

    Full Text Available

    Cloud computing was and it will be a new way of providing Internet services and computers. This calculation approach is based on many existing services, such as the Internet, grid computing, Web services. Cloud computing as a system aims to provide on demand services more acceptable as price and infrastructure. It is exactly the transition from computer to a service offered
    to the consumers as a product delivered online. This represents an advantage for the organization both regarding the cost and the opportunity for the new business. This paper presents the future perspectives in cloud computing. The paper presents some issues of the cloud computing paradigm. It is a theoretical paper.

    Keywords: Cloud Computing, Pay-per-use

  11. Cloud Database Management System (CDBMS

    Directory of Open Access Journals (Sweden)

    Snehal B. Shende

    2015-10-01

    Full Text Available Cloud database management system is a distributed database that delivers computing as a service. It is sharing of web infrastructure for resources, software and information over a network. The cloud is used as a storage location and database can be accessed and computed from anywhere. The large number of web application makes the use of distributed storage solution in order to scale up. It enables user to outsource the resource and services to the third party server. This paper include, the recent trend in cloud service based on database management system and offering it as one of the services in cloud. The advantages and disadvantages of database as a service will let you to decide either to use database as a service or not. This paper also will highlight the architecture of cloud based on database management system.

  12. Trusted computing strengthens cloud authentication.

    Science.gov (United States)

    Ghazizadeh, Eghbal; Zamani, Mazdak; Ab Manan, Jamalul-lail; Alizadeh, Mojtaba

    2014-01-01

    Cloud computing is a new generation of technology which is designed to provide the commercial necessities, solve the IT management issues, and run the appropriate applications. Another entry on the list of cloud functions which has been handled internally is Identity Access Management (IAM). Companies encounter IAM as security challenges while adopting more technologies became apparent. Trust Multi-tenancy and trusted computing based on a Trusted Platform Module (TPM) are great technologies for solving the trust and security concerns in the cloud identity environment. Single sign-on (SSO) and OpenID have been released to solve security and privacy problems for cloud identity. This paper proposes the use of trusted computing, Federated Identity Management, and OpenID Web SSO to solve identity theft in the cloud. Besides, this proposed model has been simulated in .Net environment. Security analyzing, simulation, and BLP confidential model are three ways to evaluate and analyze our proposed model.

  13. Cloud Computing: Exploring the scope

    CERN Document Server

    Pandey, Abhinav; Tandon, Ankit; Maurya, Brajesh Kr; Kushwaha, Upendra

    2010-01-01

    Cloud computing refers a paradigm shift to overall IT solutions while raising the accessibility, scalability and effectiveness through its enabling technologies. However, migrated cloud platforms and services cost benefits as well as performances are neither clear nor summarized. Globalization and the recessionary economic times have not only raised the bar of a better IT delivery models but also have given access to technology enabled services via internet. Cloud computing has vast potential in terms of lean Retail methodologies that can minimize the operational cost by using the third party based IT capabilities, as a service. It will not only increase the ROI but will also help in lowering the total cost of ownership. In this paper we have tried to compare the cloud computing cost benefits with the actual premise cost which an organization incurs normally. However, in spite of the cost benefits, many IT professional believe that the latest model i.e. "cloud computing" has risks and security concerns. This ...

  14. Trusted Computing Strengthens Cloud Authentication

    Directory of Open Access Journals (Sweden)

    Eghbal Ghazizadeh

    2014-01-01

    Full Text Available Cloud computing is a new generation of technology which is designed to provide the commercial necessities, solve the IT management issues, and run the appropriate applications. Another entry on the list of cloud functions which has been handled internally is Identity Access Management (IAM. Companies encounter IAM as security challenges while adopting more technologies became apparent. Trust Multi-tenancy and trusted computing based on a Trusted Platform Module (TPM are great technologies for solving the trust and security concerns in the cloud identity environment. Single sign-on (SSO and OpenID have been released to solve security and privacy problems for cloud identity. This paper proposes the use of trusted computing, Federated Identity Management, and OpenID Web SSO to solve identity theft in the cloud. Besides, this proposed model has been simulated in .Net environment. Security analyzing, simulation, and BLP confidential model are three ways to evaluate and analyze our proposed model.

  15. AtomPy: An Open Atomic Data Curation Environment for Astrophysical Applications

    Directory of Open Access Journals (Sweden)

    Claudio Mendoza

    2014-05-01

    Full Text Available We present a cloud-computing environment, referred to as AtomPy, based on Google-Drive Sheets and Pandas (Python Data Analysis Library DataFrames to promote community-driven curation of atomic data for astrophysical applications, a stage beyond database development. The atomic model for each ionic species is contained in a multi-sheet workbook, tabulating representative sets of energy levels, A-values and electron impact effective collision strengths from different sources. The relevant issues that AtomPy intends to address are: (i data quality by allowing open access to both data producers and users; (ii comparisons of different datasets to facilitate accuracy assessments; (iii downloading to local data structures (i.e., Pandas DataFrames for further manipulation and analysis by prospective users; and (iv data preservation by avoiding the discard of outdated sets. Data processing workflows are implemented by means of IPython Notebooks, and collaborative software developments are encouraged and managed within the GitHub social network. The facilities of AtomPy are illustrated with the critical assessment of the transition probabilities for ions in the hydrogen and helium isoelectronic sequences with atomic number Z ≤ 10.

  16. Atomic Storage States

    Institute of Scientific and Technical Information of China (English)

    汪凯戈; 朱诗尧

    2002-01-01

    We present a complete description of atomic storage states which may appear in the electromagnetically induced transparency (EIT). The result shows that the spatial coherence has been included in the atomic collective operators and the atomic storage states. In some limits, a set of multimode atomic storage states has been established in correspondence with the multimode Fock states of the electromagnetic field. This gives a better understanding of the fact that, in BIT, the optical coherent information can be preserved and recovered.

  17. Atoms Talking to SQUIDs

    CERN Document Server

    Hoffman, J E; Kim, Z; Wood, A K; Anderson, J R; Dragt, A J; Hafezi, M; Lobb, C J; Orozco, L A; Rolston, S L; Taylor, J M; Vlahacos, C P; Wellstood, F C

    2011-01-01

    We present a scheme to couple trapped $^{87}$Rb atoms to a superconducting flux qubit through a magnetic dipole transition. We plan to trap atoms on the evanescent wave outside an ultrathin fiber to bring the atoms to less than 10 $\\mu$m above the surface of the superconductor. This hybrid setup lends itself to probing sources of decoherence in superconducting qubits. Our current plan has the intermediate goal of coupling the atoms to a superconducting LC resonator.

  18. Single Atom Plasmonic Switch

    OpenAIRE

    Emboras, Alexandros; Niegemann, Jens; Ma, Ping; Haffner, Christian; Luisier, Mathieu; Hafner, Christian; Schimmel, Thomas; Leuthold, Juerg

    2015-01-01

    The atom sets an ultimate scaling limit to Moores law in the electronics industry. And while electronics research already explores atomic scales devices, photonics research still deals with devices at the micrometer scale. Here we demonstrate that photonic scaling-similar to electronics-is only limited by the atom. More precisely, we introduce an electrically controlled single atom plasmonic switch. The switch allows for fast and reproducible switching by means of the relocation of an individ...

  19. Atomic Scale Plasmonic Switch

    OpenAIRE

    Emboras, A.; Niegemann, J.; Ma, P.; Haffner, C; Pedersen, A.; Luisier, M.; Hafner, C.; Schimmel, T.; Leuthold, J.

    2016-01-01

    The atom sets an ultimate scaling limit to Moore’s law in the electronics industry. While electronics research already explores atomic scales devices, photonics research still deals with devices at the micrometer scale. Here we demonstrate that photonic scaling, similar to electronics, is only limited by the atom. More precisely, we introduce an electrically controlled plasmonic switch operating at the atomic scale. The switch allows for fast and reproducible switching by means of the relocat...

  20. Atomic Spectra Database (ASD)

    Science.gov (United States)

    SRD 78 NIST Atomic Spectra Database (ASD) (Web, free access)   This database provides access and search capability for NIST critically evaluated data on atomic energy levels, wavelengths, and transition probabilities that are reasonably up-to-date. The NIST Atomic Spectroscopy Data Center has carried out these critical compilations.

  1. Observational Approach to Molecular Cloud Evolution with the Submillimeter CI Lines

    Science.gov (United States)

    Oka, T.; Yamamoto, S.; Mt. Fuji Submillimeter-Wave Telescope Group

    Neutral carbon atoms (CI) play important role both in chemistry and cooling processes of interstellar molecular clouds. It is thus crucial to explore its large area distribution to investigate formation processes and thermal balance of molecular clouds. We have constructed a 1.2 m submillimeter-wave telescope at the summit of Mt.Fuji. The telescope was designed for the exclusive use of surveying molecular clouds in two submillimeter CI lines, 3P1--3P0 (492 GHz) and 3P2--3P1 (809 GHz), of atomic carbon. It has been operated successfully during 4 observing seasons since July 1998 in a remote way from the Hongo campus of the University of Tokyo. We have already revealed large-scale CI 492 GHz distributions of many giant molecular clouds, including Orion MC, Taurus MC, DR15, DR21, NGC2264, M17, W3, W44, W51, Rosette MC, covering more than 40 square degrees of the sky. The distribution of CI 492 GHz emission is found to be different from those of the 13CO or C18O emission in some clouds. We found the spatial order of C+/CO/C from UV sources. This is the general property of the cloud illuminated by intense UV radiation, whereas it is apparently inconsistent with the standard photodissociation region (PDR) picture. We also found CI-rich areas (C/CO˜1) in several dark clouds without strong UV sources. These results are discussed in relation to formation processes of molecular clouds and dense cloud cores.

  2. Absorption imaging of a single atom

    CERN Document Server

    Streed, E W; Norton, B G; Kielpinski, D

    2012-01-01

    Absorption imaging has played a key role in the advancement of science from van Leeuwenhoek's discovery of red blood cells to modern observations of dust clouds in stellar nebula. Here we show the first absorption imaging of a single atom isolated in vacuum. The simplicity of this system lets us compare our results directly to quantum theory, unlike recent work on absorption imaging of single molecules. The observed image contrast of 3.1(3)% achieved the maximum allowed by quantum theory for our setup, while the imaging resolution was on the order of the 370 nm illumination wavelength. The absorption of photons by single atoms is of immediate interest for quantum information processing (QIP). Our results also point out new opportunities in imaging of light-sensitive samples both in the optical and x-ray regimes. In particular, the dynamics of chromatin in living cells could be imaged without delivering a lethal UV dose.

  3. EDITORIAL: Focus on Cloud Physics FOCUS ON CLOUD PHYSICS

    Science.gov (United States)

    Falkovich, Gregory; Malinowski, Szymon P.

    2008-07-01

    Cloud physics has for a long time been an important segment of atmospheric science. It is common knowledge that clouds are crucial for our understanding of weather and climate. Clouds are also interesting by themselves (not to mention that they are beautiful). Complexity is hidden behind the common picture of these beautiful and interesting objects. The typical school textbook definition that a cloud is 'a set of droplets or particles suspended in the atmosphere' is not adequate. Clouds are complicated phenomena in which dynamics, turbulence, microphysics, thermodynamics and radiative transfer interact on a wide range of scales, from sub-micron to kilometres. Some of these interactions are subtle and others are more straightforward. Large and small-scale motions lead to activation of cloud condensation nuclei, condensational growth and collisions; small changes in composition and concentration of atmospheric aerosol lead to significant differences in radiative properties of the clouds and influence rainfall formation. It is justified to look at a cloud as a composite, nonlinear system which involves many interactions and feedback. This system is actively linked into a web of atmospheric, oceanic and even cosmic interactions. Due to the complexity of the cloud system, present-day descriptions of clouds suffer from simplifications, inadequate parameterizations, and omissions. Sometimes the most fundamental physics hidden behind these simplifications and parameterizations is not known, and a wide scope of view can sometimes prevent a 'microscopic', deep insight into the detail. Only the expertise offered by scientists focused on particular elementary processes involved in this complicated pattern of interactions allows us to shape elements of the puzzle from which a general picture of clouds can be created. To be useful, every element of the puzzle must be shaped precisely. This often creates problems in communication between the sciences responsible for shaping

  4. Dynamics of atom trapping in an rf-dressed potential

    CERN Document Server

    Chakraborty, A; Ram, S P; Tiwari, S K; Rawat, H S

    2016-01-01

    The dynamics of atom trapping in a radio-frequency-dressed-state potential formed by static and radio frequency (rf) fields has been studied using the Direct Simulation Monte Carlo (DSMC) technique. Using the simulations, a case of formation of a toroidal trap for cold $^{87}Rb$ atoms is investigated for atoms trapped in a static quadrupole magnetic trap and exposed to an rf-field with temporally increasing amplitude and decreasing frequency. We first calculate the adiabatic rf-dressed potential for an atom interacting with these fields and then apply DSMC algorithm to simulate the motion of the atom in this time dependent adiabatic potential. In the simulations the Landau-Zener (LZ) transition probability is calculated to know if the atom is in the trappable or untrappable dressed state. The results show that, initially at lower rf-field strength, the rf-field ejects atoms from the trap and leads to evaporative cooling of the atom cloud. However at higher rf-field strength, the atoms make LZ transition to th...

  5. Cloud-Ground Interaction

    Science.gov (United States)

    2004-01-01

    [figure removed for brevity, see original site] Released 30 June 2004 The atmosphere of Mars is a dynamic system. Water-ice clouds, fog, and hazes can make imaging the surface from space difficult. Dust storms can grow from local disturbances to global sizes, through which imaging is impossible. Seasonal temperature changes are the usual drivers in cloud and dust storm development and growth. Eons of atmospheric dust storm activity has left its mark on the surface of Mars. Dust carried aloft by the wind has settled out on every available surface; sand dunes have been created and moved by centuries of wind; and the effect of continual sand-blasting has modified many regions of Mars, creating yardangs and other unusual surface forms. This image of the North Polar water-ice clouds shows how surface topography can affect the linear form. Notice that the crater at the bottom of the image is causing a deflection in the linear form. Image information: VIS instrument. Latitude 68.4, Longitude 100.7 East (259.3 West). 38 meter/pixel resolution. Note: this THEMIS visual image has not been radiometrically nor geometrically calibrated for this preliminary release. An empirical correction has been performed to remove instrumental effects. A linear shift has been applied in the cross-track and down-track direction to approximate spacecraft and planetary motion. Fully calibrated and geometrically projected images will be released through the Planetary Data System in accordance with Project policies at a later time. NASA's Jet Propulsion Laboratory manages the 2001 Mars Odyssey mission for NASA's Office of Space Science, Washington, D.C. The Thermal Emission Imaging System (THEMIS) was developed by Arizona State University, Tempe, in collaboration with Raytheon Santa Barbara Remote Sensing. The THEMIS investigation is led by Dr. Philip Christensen at Arizona State University. Lockheed Martin Astronautics, Denver, is the prime contractor for the Odyssey project, and developed and

  6. Cloud and Star Formation in Spiral Arms

    CERN Document Server

    Dobbs, Clare

    2014-01-01

    We present the results from simulations of GMC formation in spiral galaxies. First we discuss cloud formation by cloud-cloud collisions, and gravitational instabilities, arguing that the former is prevalent at lower galactic surface densities and the latter at higher. Cloud masses are also limited by stellar feedback, which can be effective before clouds reach their maximum mass. We show other properties of clouds in simulations with different levels of feedback. With a moderate level of feedback, properties such as cloud rotations and virial parameters agree with observations. Without feedback, an unrealistic population of overly bound clouds develops. Spiral arms are not found to trigger star formation, they merely gather gas into more massive GMCs. We discuss in more detail interactions of clouds in the ISM, and argue that these are more complex than early ideas of cloud-cloud collisions. Finally we show ongoing work to determine whether the Milky Way is a flocculent or grand design spiral.

  7. Cloud Security A Comprehensive Guide to Secure Cloud Computing

    CERN Document Server

    Krutz, Ronald L

    2010-01-01

    Well-known security experts decipher the most challenging aspect of cloud computing-security. Cloud computing allows for both large and small organizations to have the opportunity to use Internet-based services so that they can reduce start-up costs, lower capital expenditures, use services on a pay-as-you-use basis, access applications only as needed, and quickly reduce or increase capacities. However, these benefits are accompanied by a myriad of security issues, and this valuable book tackles the most common security challenges that cloud computing faces. The authors offer you years of unpa

  8. Evolution of Cloud Storage as Cloud Computing Infrastructure Service

    OpenAIRE

    Rajan, Arokia Paul; Shanmugapriyaa

    2013-01-01

    Enterprises are driving towards less cost, more availability, agility, managed risk - all of which is accelerated towards Cloud Computing. Cloud is not a particular product, but a way of delivering IT services that are consumable on demand, elastic to scale up and down as needed, and follow a pay-for-usage model. Out of the three common types of cloud computing service models, Infrastructure as a Service (IaaS) is a service model that provides servers, computing power, network bandwidth and S...

  9. L1599B: Cloud Envelope and C+ Emission in a Region of Moderately Enhanced Radiation Field

    CERN Document Server

    Goldsmith, Paul F; Langer, William D; Liu, Tie; Requena-Torres, Miguel; Ricken, Oliver; Riquelme, Denise

    2016-01-01

    We study the effects of an asymmetric radiation field on the properties of a molecular cloud envelope. We employ observations of carbon monoxide (12CO and 13CO), atomic carbon, ionized carbon, and atomic hydrogen to analyze the chemical and physical properties of the core and envelope of L1599B, a molecular cloud forming a portion of the ring at approximately 27 pc from the star Lambda Ori. The O III star provides an asymmetric radiation field that produces a moderate enhancement of the external radiation field. Observations of the [CII] fine structure line with the GREAT instrument on SOFIA indicate a significant enhanced emission on the side of the cloud facing the star, while the [Ci], 12CO and 13CO J = 1-0 and 2-1, and 12CO J = 3-2 data from the PMO and APEX telescopes suggest a relatively typical cloud interior. The atomic, ionic, and molecular line centroid velocities track each other very closely, and indicate that the cloud may be undergoing differential radial motion. The HI data from the Arecibo GAL...

  10. Experimental Demonstration of Synthetic Lorentz Force on Cold Atoms by Using Radiation Pressure

    Science.gov (United States)

    Ban, Ticijana; Santic, Neven; Dubcek, Tena; Aumiler, Damir; Buljan, Hrvoje

    2015-05-01

    The quest for synthetic magnetism in quantum degenerate atomic gases is motivated by producing controllable quantum emulators, which could mimic complex quantum systems such as interacting electrons in magnetic fields. Experiments on synthetic magnetic fields for neutral atoms have enabled realization of the Hall effect, Harper and Haldane Hamiltonians, and other intriguing topological effects. Here we present the first demonstration of a synthetic Lorentz force, based on the radiation pressure and the Doppler effect, in cold atomic gases captured in a Magneto-Optical Trap (MOT). Synthetic Lorentz force on cold atomic cloud is measured by recording the cloud trajectory. The observed force is perpendicular to the cloud velocity, and it is zero for the atomic cloud at rest. The proposed concept is straightforward to implement in a large volume and different geometries, it is applicable for a broad range of velocities, and it can be realized for different atomic species. The experiment is based on the theoretical proposal introduced in. This work was supported by the UKF Grant No. 5/13 and Croatian MZOS.

  11. Single Atom Plasmonic Switch

    CERN Document Server

    Emboras, Alexandros; Ma, Ping; Haffner, Christian; Luisier, Mathieu; Hafner, Christian; Schimmel, Thomas; Leuthold, Juerg

    2015-01-01

    The atom sets an ultimate scaling limit to Moores law in the electronics industry. And while electronics research already explores atomic scales devices, photonics research still deals with devices at the micrometer scale. Here we demonstrate that photonic scaling-similar to electronics-is only limited by the atom. More precisely, we introduce an electrically controlled single atom plasmonic switch. The switch allows for fast and reproducible switching by means of the relocation of an individual or at most - a few atoms in a plasmonic cavity. Depending on the location of the atom either of two distinct plasmonic cavity resonance states are supported. Experimental results show reversible digital optical switching with an extinction ration of 10 dB and operation at room temperature with femtojoule (fJ) power consumption for a single switch operation. This demonstration of a CMOS compatible, integrated quantum device allowing to control photons at the single-atom level opens intriguing perspectives for a fully i...

  12. ATLAS Cloud R&D

    CERN Document Server

    Panitkin, S; The ATLAS collaboration; Caballero Bejar, J; Benjamin, D; DiGirolamo, A; Gable, I; Hendrix, V; Hover, J; Kucharczuk, K; Medrano LLamas, R; Love, P; Ohman, H; Paterson, M; Sobie, R; Taylor, R; Walker, R; Zaytsev, A

    2014-01-01

    The computing model of the ATLAS experiment was designed around the concept of grid computing and, since the start of data taking, this model has proven very successful. However, new cloud computing technologies bring attractive features to improve the operations and elasticity of scientific distributed computing. ATLAS sees grid and cloud computing as complementary technologies that will coexist at different levels of resource abstraction, and two years ago created an R&D working group to investigate the different integration scenarios. The ATLAS Cloud Computing R&D has been able to demonstrate the feasibility of offloading work from grid to cloud sites and, as of today, is able to integrate transparently various cloud resources into the PanDA workload management system. The ATLAS Cloud Computing R&D is operating various PanDA queues on private and public resources and has provided several hundred thousand CPU days to the experiment. As a result, the ATLAS Cloud Computing R&D group has gained...

  13. Data mining in Cloud Computing

    Directory of Open Access Journals (Sweden)

    Ruxandra-Ştefania PETRE

    2012-10-01

    Full Text Available This paper describes how data mining is used in cloud computing. Data Mining is used for extracting potentially useful information from raw data. The integration of data mining techniques into normal day-to-day activities has become common place. Every day people are confronted with targeted advertising, and data mining techniques help businesses to become more efficient by reducing costs.Data mining techniques and applications are very much needed in the cloud computing paradigm. The implementation of data mining techniques through Cloud computing will allow the users to retrieve meaningful information from virtually integrated data warehouse that reduces the costs of infrastructure and storage.

  14. Cloud computing for enterprise architectures

    CERN Document Server

    Mahmood, Zaigham

    2011-01-01

    This important text provides a single point of reference for state-of-the-art cloud computing design and implementation techniques. The book examines cloud computing from the perspective of enterprise architecture, asking the question; how do we realize new business potential with our existing enterprises? Its topics and features are: with a Foreword by Thomas Erl; contains contributions from an international selection of preeminent experts; presents the state-of-the-art in enterprise architecture approaches with respect to cloud computing models, frameworks, technologies, and applications; di

  15. Mobile Cloud Computing and Applications

    Institute of Scientific and Technical Information of China (English)

    Chengzhong Xu

    2011-01-01

    @@ In 2010, cloud computing gained momentum.Cloud computing is a model for real-time, on-demand, pay-for-use network access to a shared pool of configurable computing and storage resources.It has matured from a promising business concept to a working reality in both the private and public IT sectors.The U.S.government, for example, has requested all its agencies to evaluate cloud computing alternatives as part of their budget submissions for new IT investment.

  16. Aerosol-Cloud-Drizzle-Turbulence Interactions in Boundary Layer Clouds

    Science.gov (United States)

    2013-09-30

    prevent sticking. They were dispersed using a mechanism that auger fed particles into fluidized bed of grit before emitting them to the outside in a...objectives are to: 1) document the structure and characteristics of entrainment circulations in marine stratocumulus and fair-weather-cumuli, 2...characterize the vertical distribution of drizzle and how it relates to cloud and mesoscale circulations ; 3) investigate the relative role of cloud

  17. CALIPSO Observations of Near-Cloud Aerosol Properties as a Function of Cloud Fraction

    Science.gov (United States)

    Yang, Weidong; Marshak, Alexander; Varnai, Tamas; Wood, Robert

    2015-01-01

    This paper uses spaceborne lidar data to study how near-cloud aerosol statistics of attenuated backscatter depend on cloud fraction. The results for a large region around the Azores show that: (1) far-from-cloud aerosol statistics are dominated by samples from scenes with lower cloud fractions, while near-cloud aerosol statistics are dominated by samples from scenes with higher cloud fractions; (2) near-cloud enhancements of attenuated backscatter occur for any cloud fraction but are most pronounced for higher cloud fractions; (3) the difference in the enhancements for different cloud fractions is most significant within 5km from clouds; (4) near-cloud enhancements can be well approximated by logarithmic functions of cloud fraction and distance to clouds. These findings demonstrate that if variability in cloud fraction across the scenes used to composite aerosol statistics are not considered, a sampling artifact will affect these statistics calculated as a function of distance to clouds. For the Azores-region dataset examined here, this artifact occurs mostly within 5 km from clouds, and exaggerates the near-cloud enhancements of lidar backscatter and color ratio by about 30. This shows that for accurate characterization of the changes in aerosol properties with distance to clouds, it is important to account for the impact of changes in cloud fraction.

  18. Secure Data Sharing in Cloud Computing using Hybrid cloud

    Directory of Open Access Journals (Sweden)

    Er. Inderdeep Singh

    2015-06-01

    Full Text Available Cloud computing is fast growing technology that enables the users to store and access their data remotely. Using cloud services users can enjoy the benefits of on-demand cloud applications and data with limited local infrastructure available with them. While accessing the data from cloud, different users may have relationship among them depending on some attributes, and thus sharing of data along with user privacy and data security becomes important to get effective results. Most of the research has been done to secure the data authentication so that user’s don’t lose their private data stored on public cloud. But still data sharing is a significant hurdle to overcome by researchers. Research is going on to provide secure data sharing with enhanced user privacy and data access security. In this paper various research and challenges in this area are discussed in detail. It will definitely help the cloud users to understand the topic and researchers to develop a method to overcome these challenges.

  19. Hidden in the Clouds: New Ideas in Cloud Computing

    CERN Document Server

    CERN. Geneva

    2013-01-01

    Abstract: Cloud computing has become a hot topic. But 'cloud' is no newer in 2013 than MapReduce was in 2005: We've been doing both for years. So why is cloud more relevant today than it ever has been? In this presentation, we will introduce the (current) central thesis of cloud computing, and explore how and why (or even whether) the concept has evolved. While we will cover a little light background, our primary focus will be on the consequences, corollaries and techniques introduced by some of the leading cloud developers and organizations. We each have a different deployment model, different applications and workloads, and many of us are still learning to efficiently exploit the platform services offered by a modern implementation. The discussion will offer the opportunity to share these experiences and help us all to realize the benefits of cloud computing to the fullest degree. Please bring questions and opinions, and be ready to share both!   Bio: S...

  20. The design of cloud workflow systems

    CERN Document Server

    Liu, Xiao; Zhang, Gaofeng

    2011-01-01

    Cloud computing is the latest market-oriented computing paradigm which brings software design and development into a new era characterized by ""XaaS"", i.e. everything as a service. Cloud workflows, as typical software applications in the cloud, are composed of a set of partially ordered cloud software services to achieve specific goals. However, due to the low QoS (quality of service) nature of the cloud environment, the design of workflow systems in the cloud becomes a challenging issue for the delivery of high quality cloud workflow applications. To address such an issue, this book presents

  1. Long range intermolecular forces in triatomic systems: connecting the atom-diatom and atom-atom-atom representations

    OpenAIRE

    2005-01-01

    The long-range forces that act between three atoms are analysed in both atom-diatom and atom-atom-atom representations. Expressions for atom-diatom dispersion coefficients are obtained in terms of 3-body nonadditive coefficients. The anisotropy of atom-diatom C_6 dispersion coefficients arises primarily from nonadditive triple-dipole and quadruple-dipole forces, while pairwise-additive forces and nonadditive triple-dipole and dipole-dipole-quadrupole forces contribute significantly to atom-di...

  2. Research computing in a distributed cloud environment

    Energy Technology Data Exchange (ETDEWEB)

    Fransham, K; Agarwal, A; Armstrong, P; Bishop, A; Charbonneau, A; Desmarais, R; Hill, N; Gable, I; Gaudet, S; Goliath, S; Impey, R; Leavett-Brown, C; Ouellete, J; Paterson, M; Pritchet, C; Penfold-Brown, D; Podaima, W; Schade, D; Sobie, R J, E-mail: fransham@uvic.ca

    2010-11-01

    The recent increase in availability of Infrastructure-as-a-Service (IaaS) computing clouds provides a new way for researchers to run complex scientific applications. However, using cloud resources for a large number of research jobs requires significant effort and expertise. Furthermore, running jobs on many different clouds presents even more difficulty. In order to make it easy for researchers to deploy scientific applications across many cloud resources, we have developed a virtual machine resource manager (Cloud Scheduler) for distributed compute clouds. In response to a user's job submission to a batch system, the Cloud Scheduler manages the distribution and deployment of user-customized virtual machines across multiple clouds. We describe the motivation for and implementation of a distributed cloud using the Cloud Scheduler that is spread across both commercial and dedicated private sites, and present some early results of scientific data analysis using the system.

  3. Trust level of Clouds by Scheduling

    Directory of Open Access Journals (Sweden)

    Deva Sinha K.

    2015-11-01

    Full Text Available Cloud computing is a virtual storage which is used to store the data and information in secure manner. This project which gives a trustworthy to the cloud user from Admin without knowing the infrastructure and its properties of cloud. Cloud scheduled safety-critical data processing needs are beginning to push back strongly against using cloud computing, users will find that cloud scheduling will be maintained by the user to store their data on the cloud to create trust them . We have overcome this problem; a trusted cloud computing platform (TCCP proposed design. TCCP guarantees the implementation of the guest virtual machines to provide a closed box execution environment as a Service (IaaS providers such as Amazon EC2 allowing infrastructure. To protect a data in a secured way, while cloud user uploading a data it will get encrypted which means non readable format and when cloud user downloading a data it will get decrypted.

  4. Trust level of Clouds by Scheduling

    Directory of Open Access Journals (Sweden)

    Deva Sinha K

    2014-03-01

    Full Text Available Cloud computing is a virtual storage which is used to store the data and information in secure manner. This project which gives a trustworthy to the cloud user from Admin without knowing the infrastructure and its properties of cloud. Cloud scheduled safety-critical data processing needs are beginning to push back strongly against using cloud computing, users will find that cloud scheduling will be maintained by the user to store their data on the cloud to create trust them . We have overcome this problem; a trusted cloud computing platform (TCCP proposed design. TCCP guarantees the implementation of the guest virtual machines to provide a closed box execution environment as a Service (IaaS providers such as Amazon EC2 allowing infrastructure. To protect a data in a secured way, while cloud user uploading a data it will get encrypted which means non readable format and when cloud user downloading a data it will get decrypted.

  5. Research computing in a distributed cloud environment

    Science.gov (United States)

    Fransham, K.; Agarwal, A.; Armstrong, P.; Bishop, A.; Charbonneau, A.; Desmarais, R.; Hill, N.; Gable, I.; Gaudet, S.; Goliath, S.; Impey, R.; Leavett-Brown, C.; Ouellete, J.; Paterson, M.; Pritchet, C.; Penfold-Brown, D.; Podaima, W.; Schade, D.; Sobie, R. J.

    2010-11-01

    The recent increase in availability of Infrastructure-as-a-Service (IaaS) computing clouds provides a new way for researchers to run complex scientific applications. However, using cloud resources for a large number of research jobs requires significant effort and expertise. Furthermore, running jobs on many different clouds presents even more difficulty. In order to make it easy for researchers to deploy scientific applications across many cloud resources, we have developed a virtual machine resource manager (Cloud Scheduler) for distributed compute clouds. In response to a user's job submission to a batch system, the Cloud Scheduler manages the distribution and deployment of user-customized virtual machines across multiple clouds. We describe the motivation for and implementation of a distributed cloud using the Cloud Scheduler that is spread across both commercial and dedicated private sites, and present some early results of scientific data analysis using the system.

  6. Cloud Infrastructure Service Management - A Review

    Directory of Open Access Journals (Sweden)

    A. Anasuya Threse Innocent

    2012-03-01

    Full Text Available The new era of computing called Cloud Computing allows the user to access the cloud services dynamically over the Internet wherever and whenever needed. Cloud consists of data and resources; and the cloud services include the delivery of software, infrastructure, applications, and storage over the Internet based on user demand through Internet. In short, cloud computing is a business and economic model allowing the users to utilize high-end computing and storage virtually with minimal infrastructure on their end. Cloud has three service models namely, Cloud Software-as-a-Service (SaaS, Cloud Platform-as-a-Service (PaaS, and Cloud Infrastructure-as-a-Service (IaaS. This paper talks in depth of cloud infrastructure service management.

  7. Cloud computing in medical imaging.

    Science.gov (United States)

    Kagadis, George C; Kloukinas, Christos; Moore, Kevin; Philbin, Jim; Papadimitroulas, Panagiotis; Alexakos, Christos; Nagy, Paul G; Visvikis, Dimitris; Hendee, William R

    2013-07-01

    Over the past century technology has played a decisive role in defining, driving, and reinventing procedures, devices, and pharmaceuticals in healthcare. Cloud computing has been introduced only recently but is already one of the major topics of discussion in research and clinical settings. The provision of extensive, easily accessible, and reconfigurable resources such as virtual systems, platforms, and applications with low service cost has caught the attention of many researchers and clinicians. Healthcare researchers are moving their efforts to the cloud, because they need adequate resources to process, store, exchange, and use large quantities of medical data. This Vision 20/20 paper addresses major questions related to the applicability of advanced cloud computing in medical imaging. The paper also considers security and ethical issues that accompany cloud computing.

  8. Graph kernels between point clouds

    CERN Document Server

    Bach, Francis

    2007-01-01

    Point clouds are sets of points in two or three dimensions. Most kernel methods for learning on sets of points have not yet dealt with the specific geometrical invariances and practical constraints associated with point clouds in computer vision and graphics. In this paper, we present extensions of graph kernels for point clouds, which allow to use kernel methods for such ob jects as shapes, line drawings, or any three-dimensional point clouds. In order to design rich and numerically efficient kernels with as few free parameters as possible, we use kernels between covariance matrices and their factorizations on graphical models. We derive polynomial time dynamic programming recursions and present applications to recognition of handwritten digits and Chinese characters from few training examples.

  9. Cloud computing methods and practical approaches

    CERN Document Server

    Mahmood, Zaigham

    2013-01-01

    This book presents both state-of-the-art research developments and practical guidance on approaches, technologies and frameworks for the emerging cloud paradigm. Topics and features: presents the state of the art in cloud technologies, infrastructures, and service delivery and deployment models; discusses relevant theoretical frameworks, practical approaches and suggested methodologies; offers guidance and best practices for the development of cloud-based services and infrastructures, and examines management aspects of cloud computing; reviews consumer perspectives on mobile cloud computing an

  10. VMware vCloud director cookbook

    CERN Document Server

    Langenhan, Daniel

    2013-01-01

    VMware vCloud Director Cookbook will adopt a Cookbook-based approach. Packed with illustrations and programming examples, this book explains the simple as well as the complex recipes in an easy-to-understand language.""VMware vCloud Director Cookbook"" is aimed at system administrators and technical architects moving from a virtualized environment to cloud environments. Familiarity with cloud computing platforms and some knowledge of virtualization and managing cloud environments is expected.

  11. Cloud Security: Issues and Research Directions

    Science.gov (United States)

    2014-11-18

    al. present two storage isolation schemes that enable cloud users with high security requirements to verify that their disk storage is isolated from...Proof of Isolation for Cloud Storage Zhan Wang, Kun Sun, Sushil Jajodia, and Jiwu Jing 6. Selective and Fine-Grained Access to Data in the Cloud ... Cloud Security: Issues and Research Directions We organized an invitational workshop at George Mason University on Cloud Security: Issues and Research

  12. Cloud Top Scanning radiometer (CTS)

    Science.gov (United States)

    1978-01-01

    A scanning radiometer to be used for measuring cloud radiances in each of three spectral regions is described. Significant features incorporated in the Cloud Top Scanner design are: (1) flexibility and growth potential through use of easily replaceable modular detectors and filters; (2) full aperture, multilevel inflight calibration; (3) inherent channel registration through employment of a single shared field stop; and (4) radiometric sensitivity margin in a compact optical design through use of Honeywell developed (Hg,Cd)Te detectors and preamplifiers.

  13. Trapping of ultra cold atoms in a 3He/4He dilution refrigerator

    CERN Document Server

    Jessen, F; Bell, S C; Vergien, P; Hattermann, H; Weiss, P; Rudolph, M; Reinschmidt, M; Meyer, K; Gaber, T; Cano, D; Guenther, A; Bernon, S; Koelle, D; Kleiner, R; Fortagh, J

    2013-01-01

    We describe the preparation of ultra cold atomic clouds in a dilution refrigerator. The closed cycle 3He/4He cryostat was custom made to provide optical access for laser cooling, optical manipulation and detection of atoms. We show that the cryostat meets the requirements for cold atom experiments, specifically in terms of operating a magneto-optical trap, magnetic traps and magnetic transport under ultra high vacuum conditions. The presented system is a step towards the creation of a quantum hybrid system combining ultra cold atoms and solid state quantum devices.

  14. The chemistry of interstellar argonium and other probes of the molecular fraction in diffuse clouds

    CERN Document Server

    Neufeld, David A

    2016-01-01

    We present a general parameter study, in which the abundance of interstellar argonium (ArH$^+$) is predicted using a model for the physics and chemistry of diffuse interstellar gas clouds. Results have been obtained as a function of UV radiation field, cosmic-ray ionization rate, and cloud extinction. No single set of cloud parameters provides an acceptable fit to the typical ArH$^+$, OH$^+$ and $\\rm H_2O^+$ abundances observed in diffuse clouds within the Galactic disk. Instead, the observed abundances suggest that ArH$^+$ resides primarily in a separate population of small clouds of total visual extinction of at most 0.02 mag per cloud, within which the column-averaged molecular fraction is in the range $10^{-5} - 10^{-2}$, while OH$^+$ and $\\rm H_2O^+$ reside primarily in somewhat larger clouds with a column-averaged molecular fraction $\\sim 0.2$. This analysis confirms our previous suggestion that the argonium molecular ion is a unique tracer of almost purely atomic gas.

  15. Compression and ablation of the photo-irradiated molecular cloud the Orion Bar

    Science.gov (United States)

    Goicoechea, Javier R.; Pety, Jérôme; Cuadrado, Sara; Cernicharo, José; Chapillon, Edwige; Fuente, Asunción; Gerin, Maryvonne; Joblin, Christine; Marcelino, Nuria; Pilleri, Paolo

    2016-09-01

    The Orion Bar is the archetypal edge-on molecular cloud surface illuminated by strong ultraviolet radiation from nearby massive stars. Our relative closeness to the Orion nebula (about 1,350 light years away from Earth) means that we can study the effects of stellar feedback on the parental cloud in detail. Visible-light observations of the Orion Bar show that the transition between the hot ionized gas and the warm neutral atomic gas (the ionization front) is spatially well separated from the transition between atomic and molecular gas (the dissociation front), by about 15 arcseconds or 6,200 astronomical units (one astronomical unit is the Earth-Sun distance). Static equilibrium models used to interpret previous far-infrared and radio observations of the neutral gas in the Orion Bar (typically at 10-20 arcsecond resolution) predict an inhomogeneous cloud structure comprised of dense clumps embedded in a lower-density extended gas component. Here we report one-arcsecond-resolution millimetre-wave images that allow us to resolve the molecular cloud surface. In contrast to stationary model predictions, there is no appreciable offset between the peak of the H2 vibrational emission (delineating the H/H2 transition) and the edge of the observed CO and HCO+ emission. This implies that the H/H2 and C+/C/CO transition zones are very close. We find a fragmented ridge of high-density substructures, photoablative gas flows and instabilities at the molecular cloud surface. The results suggest that the cloud edge has been compressed by a high-pressure wave that is moving into the molecular cloud, demonstrating that dynamical and non-equilibrium effects are important for the cloud evolution.

  16. Atomic homodyne detection of weak atomic transitions.

    Science.gov (United States)

    Gunawardena, Mevan; Elliott, D S

    2007-01-26

    We have developed a two-color, two-pathway coherent control technique to detect and measure weak optical transitions in atoms by coherently beating the transition amplitude for the weak transition with that of a much stronger transition. We demonstrate the technique in atomic cesium, exciting the 6s(2)S(1/2) --> 8s(2)S(1/2) transition via a strong two-photon transition and a weak controllable Stark-induced transition. We discuss the enhancement in the signal-to-noise ratio for this measurement technique over that of direct detection of the weak transition rate, and project future refinements that may further improve its sensitivity and application to the measurement of other weak atomic interactions.

  17. The Software Atom

    CERN Document Server

    Javanainen, Juha

    2016-01-01

    By putting together an abstract view on quantum mechanics and a quantum-optics picture of the interactions of an atom with light, we develop a corresponding set of C++ classes that set up the numerical analysis of an atom with an arbitrary set of angular-momentum degenerate energy levels, arbitrary light fields, and an applied magnetic field. As an example, we develop and implement perturbation theory to compute the polarizability of an atom in an experimentally relevant situation.

  18. The Software Atom

    Science.gov (United States)

    Javanainen, Juha

    2017-03-01

    By putting together an abstract view on quantum mechanics and a quantum-optics picture of the interactions of an atom with light, we develop a corresponding set of C++ classes that set up the numerical analysis of an atom with an arbitrary set of angular-momentum degenerate energy levels, arbitrary light fields, and an applied magnetic field. As an example, we develop and implement perturbation theory to compute the polarizability of an atom in an experimentally relevant situation.

  19. Advances in atomic spectroscopy

    CERN Document Server

    Sneddon, J

    1997-01-01

    This series describes selected advances in the area of atomic spectroscopy. It is primarily intended for the reader who has a background in atmoic spectroscopy; suitable to the novice and expert. Although a widely used and accepted method for metal and non-metal analysis in a variety of complex samples, Advances in Atomic Spectroscopy covers a wide range of materials. Each Chapter will completely cover an area of atomic spectroscopy where rapid development has occurred.

  20. Advances in atomic spectroscopy

    CERN Document Server

    Sneddon, J

    1995-01-01

    This series describes selected advances in the area of atomic spectroscopy. It is promarily intended for the reader who has a background in atmoic spectroscopy; suitable to the novice and expert. Although a widely used and accepted method for metal and non-metal analysis in a variety of complex samples, Advances in Atomic Spectroscopy covers a wide range of materials. Each Chapter will completely cover an area of atomic spectroscopy where rapid development has occurred.