WorldWideScience

Sample records for atmospheric temperature

  1. Regularization for Atmospheric Temperature Retrieval Problems

    Science.gov (United States)

    Velez-Reyes, Miguel; Galarza-Galarza, Ruben

    1997-01-01

    Passive remote sensing of the atmosphere is used to determine the atmospheric state. A radiometer measures microwave emissions from earth's atmosphere and surface. The radiance measured by the radiometer is proportional to the brightness temperature. This brightness temperature can be used to estimate atmospheric parameters such as temperature and water vapor content. These quantities are of primary importance for different applications in meteorology, oceanography, and geophysical sciences. Depending on the range in the electromagnetic spectrum being measured by the radiometer and the atmospheric quantities to be estimated, the retrieval or inverse problem of determining atmospheric parameters from brightness temperature might be linear or nonlinear. In most applications, the retrieval problem requires the inversion of a Fredholm integral equation of the first kind making this an ill-posed problem. The numerical solution of the retrieval problem requires the transformation of the continuous problem into a discrete problem. The ill-posedness of the continuous problem translates into ill-conditioning or ill-posedness of the discrete problem. Regularization methods are used to convert the ill-posed problem into a well-posed one. In this paper, we present some results of our work in applying different regularization techniques to atmospheric temperature retrievals using brightness temperatures measured with the SSM/T-1 sensor. Simulation results are presented which show the potential of these techniques to improve temperature retrievals. In particular, no statistical assumptions are needed and the algorithms were capable of correctly estimating the temperature profile corner at the tropopause independent of the initial guess.

  2. Temperature Swings in a Hot Jupiter's Atmosphere

    Science.gov (United States)

    Kohler, Susanna

    2016-04-01

    Weather variations in the atmosphere of a planet on a highly eccentric orbit are naturally expected to be extreme. Now, a study has directly measured the wild changes in the atmosphere of a highly eccentric hot Jupiter as it passes close to its host star.Diagram of the HD 80606 system. The inset images labeled AH show the temperature distribution of the planet at different stages as it swings around its star. [de Wit et al. 2016]Eccentric OpportunityFor a hot Jupiter a gas giant that orbits close to its host star the exoplanet HD 80606 b exhibits a fairly unusual path. Rather than having a circularized orbit, HD 80606 b travels on an extremely elliptic 111-day orbit, with an eccentricity of e ~ 0.93. Since the amount of flux HD 80606 b receives from its host varies by a factor of ~850 over the course of its orbit, it stands to reason that this planet must have extreme weather swings!Now a team of scientists led by Julien de Wit (Massachusetts Institute of Technology) has reanalyzed old observations of HD 80606 and obtained new ones using the Spitzer Space Telescope. The longer observing time and new data analysis techniques allowed the team to gain new insights into how the exoplanets atmosphere responds to changes in the stellar flux it receives during its orbit.Extreme VariationsBy measuring the infrared light coming from HD 80606, de Wit and collaborators modeled the planets temperature during 80 hours of its closest approach to its host star. This period of time included the ~20 hours in which most of the planets temperature change is expected to occur, as it approaches to a distance a mere 6 stellar radii from its host.The authors find that the layer of the atmosphere probed by Spitzer heats rapidly from 500K to 1400K (thats ~440F to a scalding 2000+F!) as the planet approaches periastron.The atmosphere then cools similarly quickly as the planet heads away from the star once more.Relative infrared brightness of HD 80606 b at 4.5 and 8 m. The dip marks where

  3. Reconciling atmospheric temperatures in the early Archean

    DEFF Research Database (Denmark)

    Pope, Emily Catherine; Bird, Dennis K.; Rosing, Minik Thorleif

    the oxygen isotope record of chemical sediments and ancient ocean crust, chemical equilibria amongst primary phases in banded iron formations (BIFs), sedimentary features indicative of temperate or glacial environments, and paleosol indicators of atmospheric CO2. Further, we explore the extent to which......Average surface temperatures of Earth in the Archean remain unresolved despite decades of diverse approaches to the problem. As in the present, early Earth climates were complex systems dependent on many variables. With few constraints on such variables, climate models must be relatively simplistic...... hydrogen isotopes contribute to the geologic record as a signal for glaciations, continental growth and atmospheric methane levels. Oceanic serpentinites and subduction-related volcanic and hydrothermal environments obtain their hydrogen isotope signature from seawater, and thus may be used to calculate...

  4. Distributed Temperature Sensing in the Atmosphere

    Science.gov (United States)

    van de Giesen, Nicolaas; Selker, John; Sayde, Chadi; Thomas, Christoph K.; Higgins, Chad; Schilperoort, Bart; Coenders-Gerrits, Miriam; Luxemburg, Wim; Hilgersom, Koen; van Emmerik, Tim; Solcerova, Anna; Berghuijs, Wouter

    2016-04-01

    Over the past ten years, Distributed Temperature Sensing (DTS) has been applied for monitoring many different environmental processes, from groundwater movement, to seepage into streams and canals, to soil moisture, and internal waves in lakes. DTS uses optical fibres, along which temperatures are determined by measuring Raman shifts in light that scatters back after a laser pulse has been sent into the fiber. Over the past decade, performance of DTS equipment has dramatically improved. It is now possible to determine fiber temperatures with 0.05 K accuracy, for each 25 cm along a fiber optic cable. With typical spatial resolutions of 1 m, cable lengths can run up to 5 km. Accuracy improves with integration over longer sampling intervals, but measurements over 60 s can give 0.1 K accuracy with proper in-field calibration. DTS can also be used for atmospheric properties such as air temperature, vapor pressure, and wind speed. This presentation provides a complete overview of recent advances in atmospheric DTS observations. Air temperature is the simplest, as one simply has to suspend a fiber optic cable along the profile of interest. This can be from a balloon or along poles. Care has to be taken to correct for radiative heating of the cable. Using a thin white cable minimalizes radiative effects and normally brings the measured temperature to within 1 K of actual air temperature, sufficient for studies on effects of shading in natural and urban landscapes. It is also possible to correct for radiative heating by modeling in some detail the cable's thermal behavior or by using two cables of different diameters. Supporting structures may also have an effect on cable temperatures, which should be minimized or corrected for. Water vapor can be measured by comparing the temperatures of wet and dry cables. These wet and dry bulb temperatures allow derivation of humidity profiles, which, in turn, allows for Bowen-ratio type of calculations of latent and sensible heat

  5. Reconciling atmospheric temperatures in the early Archean

    Science.gov (United States)

    Pope, E. C.; Rosing, M.; Bird, D. K.; Albarede, F.

    2012-12-01

    Average surface temperatures of Earth in the Archean remain unresolved despite decades of diverse approaches to the problem. As in the present, early Earth climates were complex systems dependent on many variables. With few constraints on such variables, climate models must be relatively simplistic, and consider only one or two factors that drive Archean climate (e.g. a fainter young sun, a low albedo, the extent and effect of cloud cover, or the presence and abundance of a wide array of greenhouse and icehouse gasses). Compounded on the limitations of modeling is the sparse and often ambiguous Archean rock record. The goal of this study is to compile and reconcile Archean geologic and geochemical features that are in some way controlled by surface temperature and/or atmospheric composition, so that at the very least paleoclimate models can be checked by physical limits. Data used to this end include the oxygen isotope record of chemical sediments and ancient ocean crust, chemical equilibria amongst primary phases in banded iron formations (BIFs), sedimentary features indicative of temperate or glacial environments, and paleosol indicators of atmospheric CO2. Further, we explore the extent to which hydrogen isotopes contribute to the geologic record as a signal for glaciations, continental growth and atmospheric methane levels. Oceanic serpentinites and subduction-related volcanic and hydrothermal environments obtain their hydrogen isotope signature from seawater, and thus may be used to calculate secular variation in δDSEAWATER which may fluctuate significantly due to hydrogen escape, continental growth and large-scale glaciation events. Further, ancient records of low-δD meteoric fluids signal both cooler temperatures and the emergence of large continents (increasing the effects of continental weathering on climate). Selective alteration of δD in Isua rocks to values of -130 to -100‰ post-dates ca. 3.55Ga Ameralik dikes, but may be associated with a poorly

  6. Identifying human influences on atmospheric temperature.

    Science.gov (United States)

    Santer, Benjamin D; Painter, Jeffrey F; Mears, Carl A; Doutriaux, Charles; Caldwell, Peter; Arblaster, Julie M; Cameron-Smith, Philip J; Gillett, Nathan P; Gleckler, Peter J; Lanzante, John; Perlwitz, Judith; Solomon, Susan; Stott, Peter A; Taylor, Karl E; Terray, Laurent; Thorne, Peter W; Wehner, Michael F; Wentz, Frank J; Wigley, Tom M L; Wilcox, Laura J; Zou, Cheng-Zhi

    2013-01-02

    We perform a multimodel detection and attribution study with climate model simulation output and satellite-based measurements of tropospheric and stratospheric temperature change. We use simulation output from 20 climate models participating in phase 5 of the Coupled Model Intercomparison Project. This multimodel archive provides estimates of the signal pattern in response to combined anthropogenic and natural external forcing (the fingerprint) and the noise of internally generated variability. Using these estimates, we calculate signal-to-noise (S/N) ratios to quantify the strength of the fingerprint in the observations relative to fingerprint strength in natural climate noise. For changes in lower stratospheric temperature between 1979 and 2011, S/N ratios vary from 26 to 36, depending on the choice of observational dataset. In the lower troposphere, the fingerprint strength in observations is smaller, but S/N ratios are still significant at the 1% level or better, and range from three to eight. We find no evidence that these ratios are spuriously inflated by model variability errors. After removing all global mean signals, model fingerprints remain identifiable in 70% of the tests involving tropospheric temperature changes. Despite such agreement in the large-scale features of model and observed geographical patterns of atmospheric temperature change, most models do not replicate the size of the observed changes. On average, the models analyzed underestimate the observed cooling of the lower stratosphere and overestimate the warming of the troposphere. Although the precise causes of such differences are unclear, model biases in lower stratospheric temperature trends are likely to be reduced by more realistic treatment of stratospheric ozone depletion and volcanic aerosol forcing.

  7. TES/Aura L2 Atmospheric Temperatures Limb V006

    Data.gov (United States)

    National Aeronautics and Space Administration — Atmospheric vertical profile estimates and associated errors (diagonals and covariance matrices), along with retrieved surface temperature, cloud effective optical...

  8. TES/Aura L2 Atmospheric Temperatures Nadir V005

    Data.gov (United States)

    National Aeronautics and Space Administration — Atmospheric vertical profile estimates and associated errors (diagonals and covariance matrices), along with retrieved surface temperature, cloud effective optical...

  9. TES/Aura L2 Atmospheric Temperatures Nadir V006

    Data.gov (United States)

    National Aeronautics and Space Administration — Atmospheric vertical profile estimates and associated errors (diagonals and covariance matrices), along with retrieved surface temperature, cloud effective optical...

  10. TES/Aura L2 Atmospheric Temperatures Nadir V004

    Data.gov (United States)

    National Aeronautics and Space Administration — Atmospheric vertical profile estimates and associated errors (diagonals and covariance matrices), along with retrieved surface temperature, cloud effective optical...

  11. TES/Aura L2 Atmospheric Temperatures Nadir V003

    Data.gov (United States)

    National Aeronautics and Space Administration — Atmospheric vertical profile estimates and associated errors (diagonals and covariance matrices), along with retrieved surface temperature, cloud effective optical...

  12. TES/Aura L2 Atmospheric Temperatures Limb V003

    Data.gov (United States)

    National Aeronautics and Space Administration — Atmospheric vertical profile estimates and associated errors (diagonals and covariance matrices), along with retrieved surface temperature, cloud effective optical...

  13. TES/Aura L2 Atmospheric Temperatures Limb V004

    Data.gov (United States)

    National Aeronautics and Space Administration — Atmospheric vertical profile estimates and associated errors (diagonals and covariance matrices), along with retrieved surface temperature, cloud effective optical...

  14. TES/Aura L2 Atmospheric Temperatures Limb V005

    Data.gov (United States)

    National Aeronautics and Space Administration — Atmospheric vertical profile estimates and associated errors (diagonals and covariance matrices), along with retrieved surface temperature, cloud effective optical...

  15. Atmospheric Circulation of Hot Jupiters: Dayside-Nightside Temperature Differences

    CERN Document Server

    Komacek, Thaddeus D

    2016-01-01

    The full-phase infrared light curves of low-eccentricity hot Jupiters show a trend of increasing dayside-to-nightside brightness temperature difference with increasing equilibrium temperature. Here we present a three-dimensional model that explains this relationship, in order to shed insight on the processes that control heat redistribution in tidally-locked planetary atmospheres. This three-dimensional model combines predictive analytic theory for the atmospheric circulation and dayside-nightside temperature differences over a range of equilibrium temperature, atmospheric composition, and potential frictional drag strengths with numerical solutions of the circulation that verify this analytic theory. This analytic theory shows that the longitudinal propagation of waves mediates dayside-nightside temperature differences in hot Jupiter atmospheres, analogous to the wave adjustment mechanism that regulates the thermal structure in Earth's tropics. These waves can be damped in hot Jupiter atmospheres by either r...

  16. Fast Temperature Sensor for use in Atmospheric Sciences Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Southwest Sciences proposes a novel sensor to measure atmospheric temperature at high frequency (10 Hz) and with high precision and accuracy (0.1 degrees C)....

  17. ATMOSPHERIC CIRCULATION OF HOT JUPITERS: DAYSIDE–NIGHTSIDE TEMPERATURE DIFFERENCES

    Energy Technology Data Exchange (ETDEWEB)

    Komacek, Thaddeus D.; Showman, Adam P., E-mail: tkomacek@lpl.arizona.edu [Department of Planetary Sciences, University of Arizona, Tucson, AZ 85721 (United States)

    2016-04-10

    The full-phase infrared light curves of low-eccentricity hot Jupiters show a trend of increasing dayside-to-nightside brightness temperature difference with increasing equilibrium temperature. Here, we present a three-dimensional model that explains this relationship, in order to provide insight into the processes that control heat redistribution in tidally locked planetary atmospheres. This three-dimensional model combines predictive analytic theory for the atmospheric circulation and dayside–nightside temperature differences over a range of equilibrium temperatures, atmospheric compositions, and potential frictional drag strengths with numerical solutions of the circulation that verify this analytic theory. The theory shows that the longitudinal propagation of waves mediates dayside–nightside temperature differences in hot Jupiter atmospheres, analogous to the wave adjustment mechanism that regulates the thermal structure in Earth’s tropics. These waves can be damped in hot Jupiter atmospheres by either radiative cooling or potential frictional drag. This frictional drag would likely be caused by Lorentz forces in a partially ionized atmosphere threaded by a background magnetic field, and would increase in strength with increasing temperature. Additionally, the amplitude of radiative heating and cooling increases with increasing temperature, and hence both radiative heating/cooling and frictional drag damp waves more efficiently with increasing equilibrium temperature. Radiative heating and cooling play the largest role in controlling dayside–nightside temperature differences in both our analytic theory and numerical simulations, with frictional drag only being important if it is stronger than the Coriolis force. As a result, dayside–nightside temperature differences in hot Jupiter atmospheres increase with increasing stellar irradiation and decrease with increasing pressure.

  18. Temperature field simulation of gob influenced by atmospheric pressure

    Institute of Scientific and Technical Information of China (English)

    王刚; 罗海珠; 梁运涛; 王继仁

    2015-01-01

    The current temperature field model of mine gob does not take the boundary conditions of the atmospheric pressure into account, while the actual atmospheric pressure is influenced by weather, so as to produce differences between ventilation negative pressure of the working face and the negative pressure of gas drainage in gob, thus interfering the calculated results of gob temperature field. According to the characteristics of the actual air flow and temperature change in gob, a two-dimensional temperature field model of the gob was built, and the relational model between the air pressure of intake and outlet of the gob and the atmospheric pressure was established, which was introduced into the boundary conditions of temperature field to conduct calculation. By means of analysis on the simulation example, and comparison with the traditional model, the results indicate that atmospheric pressure change had notable impact on the distribution of gob temperature field. The laboratory test system of gob temperature field was constructed, and the relative error between simulated and measured value was no greater than 9.6%, which verified the effectiveness of the proposed model. This work offers theoretical basis for accurate calculation of temperature and prediction of ignition source in mine gob, and has important implications on preventing spontaneous combustion of coal.

  19. Simulation of atmospheric temperature effects on cosmic ray muon flux

    Energy Technology Data Exchange (ETDEWEB)

    Tognini, Stefano Castro; Gomes, Ricardo Avelino [Instituto de Física, Universidade Federal de Goiás, CP 131, 74001-970, Goiânia, GO (Brazil)

    2015-05-15

    The collision between a cosmic ray and an atmosphere nucleus produces a set of secondary particles, which will decay or interact with other atmosphere elements. This set of events produced a primary particle is known as an extensive air shower (EAS) and is composed by a muonic, a hadronic and an electromagnetic component. The muonic flux, produced mainly by pions and kaons decays, has a dependency with the atmosphere’s effective temperature: an increase in the effective temperature results in a lower density profile, which decreases the probability of pions and kaons to interact with the atmosphere and, consequently, resulting in a major number of meson decays. Such correlation between the muon flux and the atmosphere’s effective temperature was measured by a set of experiments, such as AMANDA, Borexino, MACRO and MINOS. This phenomena can be investigated by simulating the final muon flux produced by two different parameterizations of the isothermal atmospheric model in CORSIKA, where each parameterization is described by a depth function which can be related to the muon flux in the same way that the muon flux is related to the temperature. This research checks the agreement among different high energy hadronic interactions models and the physical expected behavior of the atmosphere temperature effect by analyzing a set of variables, such as the height of the primary interaction and the difference in the muon flux.

  20. Ocean versus atmosphere control on western European wintertime temperature variability

    Science.gov (United States)

    Yamamoto, Ayako; Palter, Jaime B.; Lozier, M. Susan; Bourqui, Michel S.; Leadbetter, Susan J.

    2015-12-01

    Using a novel Lagrangian approach, we assess the relative roles of the atmosphere and ocean in setting interannual variability in western European wintertime temperatures. We compute sensible and latent heat fluxes along atmospheric particle trajectories backtracked in time from four western European cities, using a Lagrangian atmospheric dispersion model driven with meteorological reanalysis data. The material time rate of change in potential temperature and the surface turbulent fluxes computed along the trajectory show a high degree of correlation, revealing a dominant control of ocean-atmosphere heat and moisture exchange in setting heat flux variability for atmospheric particles en route to western Europe. We conduct six idealised simulations in which one or more aspects of the climate system is held constant at climatological values and these idealised simulations are compared with a control simulation, in which all components of the climate system vary realistically. The results from these idealised simulations suggest that knowledge of atmospheric pathways is essential for reconstructing the interannual variability in heat flux and western European wintertime temperature, and that variability in these trajectories alone is sufficient to explain at least half of the internannual flux variability. Our idealised simulations also expose an important role for sea surface temperature in setting decadal scale variability of air-sea heat fluxes along the Lagrangian pathways. These results are consistent with previous studies showing that air-sea heat flux variability is driven by the atmosphere on interannual time scales over much of the North Atlantic, whereas the SST plays a leading role on longer time scales. Of particular interest is that the atmospheric control holds for the integrated fluxes along 10-day back trajectories from western Europe on an interannual time scale, despite that many of these trajectories pass over the Gulf Stream and its North Atlantic

  1. Assessing atmospheric temperature data sets for climate studies

    Directory of Open Access Journals (Sweden)

    Magnus Cederlöf

    2016-07-01

    Full Text Available Observed near-surface temperature trends during the period 1979–2014 show large differences between land and ocean, with positive values over land (0.25–0.27 °C/decade that are significantly larger than over the ocean (0.06–0.12 °C/decade. Temperature trends in the mid-troposphere of 0.08-0.11 °C/decade, on the other hand, are similar for both land and ocean and agree closely with the ocean surface temperature trend. The lapse rate is consequently systematically larger over land than over the ocean and also shows a positive trend in most land areas. This is puzzling as a response to external warming, such as from increasing greenhouse gases, is broadly the same throughout the troposphere. The reduced tropospheric warming trend over land suggests a weaker vertical temperature coupling indicating that some of the processes in the planetary boundary layer such as inversions have a limited influence on the temperature of the free atmosphere. Alternatively, the temperature of the free atmosphere is influenced by advection of colder tropospheric air from the oceans. It is therefore suggested to use either the more robust tropospheric temperature or ocean surface temperature in studies of climate sensitivity. We also conclude that the European Centre for Medium-Range Weather Forecasts Reanalysis Interim can be used to obtain consistent temperature trends through the depth of the atmosphere, as they are consistent both with near-surface temperature trends and atmospheric temperature trends obtained from microwave sounding sensors.

  2. Engineering a laser remote sensor for atmospheric pressure and temperature

    Science.gov (United States)

    Kalshoven, J. E., Jr.; Korb, C. L.

    1978-01-01

    A system for the remote sensing of atmospheric pressure and temperature is described. Resonant lines in the 7600 Angstrom oxygen A band region are used and an organic dye laser beam is tuned to measure line absorption changes with temperature or pressure. A reference beam outside this band is also transmitted for calibration. Using lidar techniques, profiling of these parameters with altitude can be accomplished.

  3. High temperature condensate clouds in super-hot Jupiter atmospheres

    CERN Document Server

    Wakeford, Hannah R; Lewis, Nikole K; Kataria, Tiffany; Marley, Mark S; Fortney, Jonathan J; Mandell, Avi M

    2016-01-01

    Deciphering the role of clouds is central to our understanding of exoplanet atmospheres, as they have a direct impact on the temperature and pressure structure, and observational properties of the planet. Super-hot Jupiters occupy a temperature regime similar to low mass M-dwarfs, where minimal cloud condensation is expected. However, observations of exoplanets such as WASP-12b (Teq ~ 2500 K) result in a transmission spectrum indicative of a cloudy atmosphere. We re-examine the temperature and pressure space occupied by these super-hot Jupiter atmospheres, to explore the role of the initial Al- and Ti-bearing condensates as the main source of cloud material. Due to the high temperatures a majority of the more common refractory material is not depleted into deeper layers and would remain in the vapor phase. The lack of depletion into deeper layers means that these materials with relatively low cloud masses can become significant absorbers in the upper atmosphere. We provide condensation curves for the initial ...

  4. Phase relation between global temperature and atmospheric carbon dioxide

    CERN Document Server

    Stallinga, Peter

    2013-01-01

    The primary ingredient of Anthropogenic Global Warming hypothesis is the assumption that atmospheric carbon dioxide variations are the cause for temperature variations. In this paper we discuss this assumption and analyze it on basis of bi-centenary measurements and using a relaxation model which causes phase shifts and delays.

  5. Temperature extremes in Western Europe and associated atmospheric anomalies

    Science.gov (United States)

    Carvalho, V. A.; Santos, J. A.

    2009-09-01

    This worḱs focal point is the analysis of temperature extremes over Western Europe in the period 1957-2007 and their relationship to large-scale anomalies in the atmospheric circulation patterns. The study is based on temperature daily time series recorded at a set of meteorological stations covering the target area. The large-scale anomalies are analyzed using data from the National Centers for Environmental Prediction reanalysis project. Firstly, a preliminary statistical analysis was undertaken in order to identify data gaps and erroneous values and to check the homogeneity of the time series, using not only elementary statistical approaches (e.g., chronograms, box-plots, scatter-plots), but also a set of non-parametric statistical tests particularly suitable for the analysis of monthly and seasonal mean temperature time series (e.g., Wald-Wolfowitz serial correlation test, Spearman and Mann-Kendall trend tests). Secondly, based on previous results, a selection of the highest quality time series was carried out. Aiming at identifying temperature extremes, we then proceed to the isolation of months with temperature values above or below pre-selected thresholds based on the empirical distribution of each time series. In particular, thresholds are based on percentiles specifically computed for each individual temperature record (data adaptive) and not on fixed values. As a result, a calendar of extremely high and extremely low monthly mean temperatures is obtained and the large-scale atmospheric conditions during each extreme are analyzed. Several atmospheric fields are considered in this study (e.g., 2-m maximum and minimum air temperature, sea level pressure, geopotential height, zonal and meridional wind components, vorticity, relative humidity) at different isobaric levels. Results show remarkably different synoptic conditions for temperature extremes in different parts of Western Europe, highlighting the different dynamical mechanisms underlying their

  6. Improved controlled atmosphere high temperature scanning probe microscope

    DEFF Research Database (Denmark)

    Hansen, Karin Vels; Wu, Yuehua; Jacobsen, Torben

    2013-01-01

    fuel cells and electrolyzer cells. Here, we report on advanced improvements of our original controlled atmosphere high temperature scanning probe microscope, CAHT-SPM. The new microscope can employ a broad range of the scanning probe techniques including tapping mode, scanning tunneling microscopy......, scanning tunneling spectroscopy, conductive atomic force microscopy, and Kelvin probe force microscopy. The temperature of the sample can be as high as 850 °C. Both reducing and oxidizing gases such as oxygen, hydrogen, and nitrogen can be added in the sample chamber and the oxygen partial pressure (pO2......To locally access electrochemical active surfaces and interfaces in operando at the sub-micron scale at high temperatures in a reactive gas atmosphere is of great importance to understand the basic mechanisms in new functional materials, for instance, for energy technologies, such as solid oxide...

  7. Glacial ocean circulation and stratification explained by reduced atmospheric temperature

    Science.gov (United States)

    Jansen, Malte F.

    2017-01-01

    Earth’s climate has undergone dramatic shifts between glacial and interglacial time periods, with high-latitude temperature changes on the order of 5–10 °C. These climatic shifts have been associated with major rearrangements in the deep ocean circulation and stratification, which have likely played an important role in the observed atmospheric carbon dioxide swings by affecting the partitioning of carbon between the atmosphere and the ocean. The mechanisms by which the deep ocean circulation changed, however, are still unclear and represent a major challenge to our understanding of glacial climates. This study shows that various inferred changes in the deep ocean circulation and stratification between glacial and interglacial climates can be interpreted as a direct consequence of atmospheric temperature differences. Colder atmospheric temperatures lead to increased sea ice cover and formation rate around Antarctica. The associated enhanced brine rejection leads to a strongly increased deep ocean stratification, consistent with high abyssal salinities inferred for the last glacial maximum. The increased stratification goes together with a weakening and shoaling of the interhemispheric overturning circulation, again consistent with proxy evidence for the last glacial. The shallower interhemispheric overturning circulation makes room for slowly moving water of Antarctic origin, which explains the observed middepth radiocarbon age maximum and may play an important role in ocean carbon storage.

  8. Atmospheric Refraction Predictions Based on Actual Atmospheric Pressure and Temperature Data

    Science.gov (United States)

    Nauenberg, Michael

    2017-04-01

    Calculations of atmospheric refraction are generally based on a simplified model of atmospheric density in the troposphere that assumes the temperature decreases at a constant lapse rate L from sea level up to a height {h}t≈ 11 {km}, and that afterward it remains constant. In this model, the ratio T o /L, where T o is the temperature at the observer’s location, determines the length scale in the calculations for altitudes h≤slant {h}t. But daily balloon measurements across the USA show that in some cases there is an inversion so that the air temperature actually increases from sea level up to a height {h}p≈ 1 {km}, and only after reaching a plateau with temperature {T}o\\prime at this height, it decreases at an approximately constant lapse rate. Hence, in such cases the relevant length scale for atmospheric refraction calculations in the range {h}p≤slant hatmospheric refraction based on this actual atmospheric data are compared with the results of current simplified models.

  9. Simulation of low temperature atmospheric pressure corona discharge in helium

    Science.gov (United States)

    Bekasov, Vladimir; Kirsanov, Gennady; Eliseev, Stepan; Kudryavtsev, Anatoly; Sisoev, Sergey

    2015-11-01

    The main objective of this work was to construct a numerical model of corona discharge in helium at atmospheric pressure. The calculation was based on the two-dimensional hybrid model. Two different plasma-chemical models were considered. Models were built for RF corona and negative DC corona discharge. The system of equations is solved by the finite element method in the COMSOL Multiphysics. Main parameters of the discharge (the density of charged and excited particles, the electron temperature) and their dependence on the input parameters of the model (geometry, electrode voltage, power) were calculated. The calculations showed that the shape of the electron distribution near the electrode depends on the discharge power. The neutral gas heating data obtained will allow predicting the temperature of the gases at the designing of atmospheric pressure helium plasma sources.

  10. Low Temperature and Modified Atmosphere: Hurdles for Antibiotic Resistance Transfer?

    Science.gov (United States)

    Van Meervenne, Eva; Van Coillie, Els; Van Weyenberg, Stephanie; Boon, Nico; Herman, Lieve; Devlieghere, Frank

    2015-12-01

    Food is an important dissemination route for antibiotic-resistant bacteria. Factors used during food production and preservation may contribute to the transfer of antibiotic resistance genes, but research on this subject is scarce. In this study, the effect of temperature (7 to 37°C) and modified atmosphere packaging (air, 50% CO2-50% N2, and 100% N2) on antibiotic resistance transfer from Lactobacillus sakei subsp. sakei to Listeria monocytogenes was evaluated. Filter mating was performed on nonselective agar plates with high-density inocula. A more realistic setup was created by performing modified atmosphere experiments on cooked ham using high-density and low-density inocula. Plasmid transfer was observed between 10 and 37°C, with plasmid transfer also observed at 7°C during a prolonged incubation period. When high-density inocula were used, transconjugants were detected, both on agar plates and cooked ham, under the three atmospheres (air, 50% CO2-50% N2, and 100% N2) at 7°C. This yielded a median transfer ratio (number of transconjugants/number of recipients) with an order of magnitude of 10(-4) to 10(-6). With low-density inocula, transfer was only detected under the 100% N2 atmosphere after 10-day incubation at 7°C, yielding a transfer ratio of 10(-5). Under this condition, the highest bacterial density was obtained. The results indicate that low temperature and modified atmosphere packaging, two important hurdles in the food industry, do not necessarily prevent plasmid transfer from Lactobacillus sakei subsp. sakei to Listeria monocytogenes.

  11. The atmospheric temperatures over Olympus Mons on Mars: An atmospheric hot ring

    Science.gov (United States)

    Wolkenberg, P.; Formisano, V.; Rinaldi, G.; Geminale, A.

    2010-05-01

    We study the thermal fields over Olympus Mons separating seasons (northern spring and summer against southern spring and summer) and local time observations (day side versus night side). Temperature vertical profiles retrieved from Planetary Fourier Spectrometer on board Mars Express (PFS-MEX) data have been used. In many orbits (running north to south along a meridian) passing over the top of the volcano there is evidence of a hot air on top of the volcano, of two enhancement of the air temperature both north and south of it and in between a collar of air that is colder than nearby at low altitudes, and warmer than nearby at high altitudes. Mapping together many orbits passing over or near the volcano we find that the hot air has the tendency to form an hot ring around it. This hot structure occurs mostly between LT = 10.00 and 15.00 and during the northern summer. Distance of the hot structure from the top of the volcano is about 600 km (10° of latitude). The hot atmospheric region is 300-420 km (5-7°) wide. Hot ring temperature contrasts of about 40 K occur at 2 km above the surface and decrease to 20 K at 5 km and to 10 K at 10 km. The atmospheric circulation over an area of 40° × 40° (latitudes and longitudes) is affected by the topography and the presence of Olympus Mons (-133°W, 18°N). We discuss also the thermal stability of the atmosphere over the selected area using the potential temperatures. The temperature field over the top of the volcano shows unstable atmosphere within 10 km from the surface. Finally, we interpret the hot temperatures around volcano as an adiabatic compression of down-welling branch coming from over the top of volcano. Different air temperature profiles are observed in the same seasons during the night, or in different seasons. In northern spring-summer during the night the isothermal contours do not show the presence of the volcano until we reach close to the surface very much, where a thermal inversion is observed. The

  12. NOAA Climate Data Record (CDR) of Upper Atmospheric Temperature 4 Layer Microwave, Version 3.3

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The 4 Layer Upper Atmosphere Temperature (UAT) Climate Data Record (CDR) dataset is a monthly analysis of the tropospheric and stratospheric data using temperature...

  13. A lidar system for measuring atmospheric pressure and temperature profiles

    Science.gov (United States)

    Schwemmer, Geary K.; Dombrowski, Mark; Korb, C. Laurence; Milrod, Jeffry; Walden, Harvey

    1987-01-01

    The design and operation of a differential absorption lidar system capable of remotely measuring the vertical structure of tropospheric pressure and temperature are described. The measurements are based on the absorption by atmospheric oxygen of the spectrally narrowband output of two pulsed alexandrite lasers. Detailed laser output spectral characteristics, which are critical to successful lidar measurements, are presented. Spectral linewidths of 0.026 and 0.018 per cm for the lasers were measured with over 99.99 percent of the energy contained in three longitudinal modes.

  14. Atmospheric Temperature Profile Measurements Using Mobile High Spectral Resolution Lidar

    Science.gov (United States)

    Razenkov, Ilya I.; Eloranta, Edwin W.

    2016-06-01

    The High Spectral Resolution Lidar (HSRL) designed at the University of Wisconsin-Madison discriminates between Mie and Rayleigh backscattering [1]. It exploits the Doppler effect caused by thermal motion of molecules, which broadens the spectrum of the transmitted laser light. That allows for absolute calibration of the lidar and measurements of the aerosol volume backscatter coefficient. Two iodine absorption filters with different absorption line widths (a regular iodine vapor filter and Argon buffered iodine filter) allow for atmospheric temperature profile measurements. The sensitivity of the measured signal-to-air temperature ratio is around 0.14%/K. The instrument uses a shared telescope transmitter-receiver design and operates in eyesafe mode (the product of laser average power and telescope aperture equals 0.1 Wm2 at 532 nm).

  15. Atmospheric Temperature Profile Measurements Using Mobile High Spectral Resolution Lidar

    Directory of Open Access Journals (Sweden)

    Razenkov Ilya I.

    2016-01-01

    Full Text Available The High Spectral Resolution Lidar (HSRL designed at the University of Wisconsin-Madison discriminates between Mie and Rayleigh backscattering [1]. It exploits the Doppler effect caused by thermal motion of molecules, which broadens the spectrum of the transmitted laser light. That allows for absolute calibration of the lidar and measurements of the aerosol volume backscatter coefficient. Two iodine absorption filters with different absorption line widths (a regular iodine vapor filter and Argon buffered iodine filter allow for atmospheric temperature profile measurements. The sensitivity of the measured signal-to-air temperature ratio is around 0.14%/K. The instrument uses a shared telescope transmitter-receiver design and operates in eyesafe mode (the product of laser average power and telescope aperture equals 0.1 Wm2 at 532 nm.

  16. The THS experiment: probing Titan's atmospheric chemistry at low temperature

    Science.gov (United States)

    Sciamma-O'Brien, Ella; Upton, Kathleen; Beauchamp, Jack L; Salama, Farid

    2014-06-01

    In Titan’s atmosphere, a complex chemistry between N2 and CH4 occurs at temperatures lower than 200K and leads to the production of heavy molecules and subsequently solid aerosols that form the haze surrounding Titan. The Titan Haze Simulation (THS) experiment has been developed at the NASA Ames COSmIC facility to study Titan’s atmospheric chemistry at low temperature in order to help interpret Cassini’s observational data. In the THS, the chemistry is simulated by plasma in the stream of a supersonic expansion. With this unique design, the gas is jet-cooled to Titan-like temperature 150K) before inducing the chemistry by plasma, and remains at low temperature in the plasma discharge 200K). Different N2-CH4-based gas mixtures can be injected in the plasma, with or without the addition of heavier precursors present as trace elements on Titan. Both the gas phase and solid phase products resulting from the plasma-induced chemistry can be monitored and analyzed using a combination of complementary in situ and ex situ diagnostics.Here we present the complementary results of two studies of the gas and solid phase. A Mass spectrometry analysis of the gas phase has demonstrated that the THS experiment is a unique tool to probe the first and intermediate steps as well as specific chemical pathways of Titan’s atmospheric chemistry at Titan-like temperature. The more complex chemistry, observed in the gas phase when adding trace elements to the initial N2-CH4 mixture, has also been confirmed by an extensive study of the solid phase products: Scanning Electron Microscopy images have shown that aggregates produced in N2-CH4-C2H2-C6H6 mixtures (up to 5 μm in diameter) are much larger than those produced in N2-CH4 mixtures (0.1-0.5 μm), and Nuclear Magnetic Resonance results support a growth evolution of the chemistry when adding acetylene to the N2-CH4 mixture, resulting in the production of more complex hydrogen bonds than with a simple N2-CH4 mixture

  17. Temperature retrieval at the southern pole of the Venusian atmosphere

    Science.gov (United States)

    Garate-Lopez, Itziar; Garcia-Munoz, A.; Hueso, R.; Sanchez-Lavega, A.

    2013-10-01

    Venus’ thermal radiation spectrum is punctuated by CO2 bands of various strengths probing into different atmospheric depths. It is thus possible to invert measured spectra of thermal radiation to infer atmospheric temperature profiles. VIRTIS-M observations of Venus in the 3-5 µm range allow us to study the night time thermal structure of the planet’s upper troposphere and lower mesosphere from 50 to 105 km [1, 2]. Building a forward radiative transfer model that solves the radiative transfer equation for the atmosphere on a line-by-line basis, we confirmed that aerosol scattering must be taken into account and we studied the impact of factors such as cloud opacity, and the size, composition and vertical distribution of aerosols [3]. The cloud top altitude and aerosol scale height have a notable impact on the spectrum. However, their weighting function matrices have similar structures contributing to the degeneracy of the temperature retrieval algorithm [2]. Our retrieval code is focused on the strong 4.3µm CO2 band, which enables the determination of the thermal profile above the cloud top, and based on the algorithm proposed by Grassi et al. (2008) in their equation (2). We present temperature maps for the south pole of Venus, where a highly variable vortex is observed. We aim to combine these maps with our previously measured velocity fields from the same VIRTIS-M infrared images [4], in order to infer the potential vorticity distribution for different vortex configurations and to improve the understanding of its unpredictable character and its role in the general atmospheric circulation. Acknowledgements This work was supported by the Spanish MICIIN projects AYA2009-10701 and AYA2012-36666 with FEDER funds, by Grupos Gobierno Vasco IT-765-13 and by Universidad País Vasco UPV/EHU through program UFI11/55. IGL and AGM gratefully acknowledge ESA/RSSD for hospitality and access to ‘The Grid’ computing resources. References [1] Roos-Serote, M., et al

  18. Lifted Temperature Minimum during the atmospheric evening transition

    Directory of Open Access Journals (Sweden)

    E. Blay-Carreras

    2014-11-01

    Full Text Available Observations of Lifted Temperature Minimum (LTM profiles in the nocturnal boundary layer were first reported by Ramdas and Atmanathan (1932. It was defined by the existence of a temperature minimum some centimeters above the ground. During the following decades, several research studies analyzed this phenomenon verifying its existence and postulating different hypothesis about its origin. The aim of this work is to study the existence and characteristics of LTM during the evening transition by using observations obtained during the Boundary Layer Late Afternoon and Sunset Turbulence (BLLAST campaign. Data obtained from two masts instrumented with thermocouples and wind sensors at different heights close to the ground, and a mast with radiometers are used to study the role of mechanical turbulence and radiation in LTM development. The study shows that LTM profiles can be detected under calm conditions during the day–night transition, several hours earlier than reported in previous work. These conditions are fulfilled under weak synoptic forcing during local flow shifts associated with a mountain–plain circulation in relatively complex orography. Under these special conditions, turbulence becomes a crucial parameter in determining the ideal conditions for observing LTM profiles. Additionally, LTM observed profiles are also related to a change in the atmospheric radiative characteristics under calm conditions.

  19. High Temperature Decomposition of Almandine and Pyrope in Reducing Atmosphere

    Science.gov (United States)

    Aparicio, C.; Filip, J.; Mashlan, M.

    2010-07-01

    Thermal decomposition of two garnets of near end-member composition—almandine (Fe2.85Mg0.15)(Al1.99)Si2.99O12 and pyrope (Mg2.22Fe0.47Ca0.33)(Cr0.11Fe0.06Al1.81)Si2.98O12—has been carried out in reducing atmosphere (forming gas: 10% of H2 in N2). High-temperature behavior of both samples was monitored using simultaneous thermogravimetry and differential scanning calorimetry. The decomposition of almandine and pyrope turned out to proceed at slightly different temperatures above 1000 °C. Therefore, two series of samples were prepared based on the results of thermal analysis: almandine heated up to 950 °C, 1070 °C and 1200 °C, and pyrope heated up to 1000 °C, 1100 °C, 1125 °C and 1200 °C. The identification of the decomposition products was performed by X-ray powder diffraction and Mössbauer spectroscopy. The common feature of the decomposition of both garnets is the presence of metallic iron and spinel phase, while the other products include fayalite, cristobalite, and cordierite for almandine; and enstatite and anorthite for pyrope. The formation of this last component was enabled due to Ca content in pyrope.

  20. TES/Aura L3 Atmospheric Temperatures Daily Gridded V001

    Data.gov (United States)

    National Aeronautics and Space Administration — Daily atmospheric temperature and VMR for the atmospheric species are provided at 2 deg. lat. X 4 deg. long. spatial grids and at a subset of TES standard pressure...

  1. TES/Aura L3 Atmospheric Temperatures Monthly Gridded V003

    Data.gov (United States)

    National Aeronautics and Space Administration — Monthly averages of atmospheric temperature and VMR for atmospheric species are provided at 2 deg. lat. X 4 deg. long. spatial grids and at a subset of TES standard...

  2. TES/Aura L3 Atmospheric Temperatures Monthly Gridded V002

    Data.gov (United States)

    National Aeronautics and Space Administration — Monthly averages of atmospheric temperature and VMR for atmospheric species are provided at 2 deg. lat. X 4 deg. long. spatial grids and at a subset of TES standard...

  3. TES/Aura L3 Atmospheric Temperatures Monthly Gridded V001

    Data.gov (United States)

    National Aeronautics and Space Administration — Monthly averages of atmospheric temperature and VMR for atmospheric species are provided at 2 deg. lat. X 4 deg. long. spatial grids and at a subset of TES standard...

  4. TES/Aura L3 Atmospheric Temperatures Daily Gridded V003

    Data.gov (United States)

    National Aeronautics and Space Administration — Daily atmospheric temperature and VMR for the atmospheric species are provided at 2 deg. lat. X 4 deg. long. spatial grids and at a subset of TES standard pressure...

  5. TES/Aura L2 Atmospheric Temperatures Nadir Special Observation V004

    Data.gov (United States)

    National Aeronautics and Space Administration — Atmospheric vertical profile estimates and associated errors (diagonals and covariance matrices), along with retrieved surface temperature, cloud effective optical...

  6. TES/Aura L2 Atmospheric Temperatures Limb Special Observation V005

    Data.gov (United States)

    National Aeronautics and Space Administration — Atmospheric vertical profile estimates and associated errors (diagonals and covariance matrices), along with retrieved surface temperature, cloud effective optical...

  7. TES/Aura L2 Atmospheric Temperatures Nadir Special Observation V005

    Data.gov (United States)

    National Aeronautics and Space Administration — Atmospheric vertical profile estimates and associated errors (diagonals and covariance matrices), along with retrieved surface temperature, cloud effective optical...

  8. TES/Aura L2 Atmospheric Temperatures Limb Special Observation V004

    Data.gov (United States)

    National Aeronautics and Space Administration — Atmospheric vertical profile estimates and associated errors (diagonals and covariance matrices), along with retrieved surface temperature, cloud effective optical...

  9. TES/Aura L2 Atmospheric Temperatures Limb Special Observation V003

    Data.gov (United States)

    National Aeronautics and Space Administration — Atmospheric vertical profile estimates and associated errors (diagonals and covariance matrices), along with retrieved surface temperature, cloud effective optical...

  10. TES/Aura L2 Atmospheric Temperatures Nadir Special Observation V006

    Data.gov (United States)

    National Aeronautics and Space Administration — Atmospheric vertical profile estimates and associated errors (diagonals and covariance matrices), along with retrieved surface temperature, cloud effective optical...

  11. TES/Aura L2 Atmospheric Temperatures Limb Special Observation V006

    Data.gov (United States)

    National Aeronautics and Space Administration — Atmospheric vertical profile estimates and associated errors (diagonals and covariance matrices), along with retrieved surface temperature, cloud effective optical...

  12. TES/Aura L2 Atmospheric Temperatures Nadir Special Observation V003

    Data.gov (United States)

    National Aeronautics and Space Administration — Atmospheric vertical profile estimates and associated errors (diagonals and covariance matrices), along with retrieved surface temperature, cloud effective optical...

  13. Effect of O3 on the atmospheric temperature structure of early Mars

    CERN Document Server

    von Paris, P; Godolt, M; Grenfell, J L; Stracke, B; Rauer, H

    2015-01-01

    Ozone is an important radiative trace gas in the Earth's atmosphere. The presence of ozone can significantly influence the thermal structure of an atmosphere, and by this e.g. cloud formation. Photochemical studies suggest that ozone can form in carbon dioxide-rich atmospheres. We investigate the effect of ozone on the temperature structure of simulated early Martian atmospheres. With a 1D radiative-convective model, we calculate temperature-pressure profiles for a 1 bar carbon dioxide atmosphere. Ozone profiles are fixed, parameterized profiles. We vary the location of the ozone layer maximum and the concentration at this maximum. The maximum is placed at different pressure levels in the upper and middle atmosphere (1-10 mbar). Results suggest that the impact of ozone on surface temperatures is relatively small. However, the planetary albedo significantly decreases at large ozone concentrations. Throughout the middle and upper atmospheres, temperatures increase upon introducing ozone due to strong UV absorpt...

  14. VUV-absorption cross section of CO2 at high temperatures and impact on exoplanet atmospheres

    CERN Document Server

    Venot, Olivia; Bénilan, Yves; Gazeau, Marie-Claire; Hébrard, Eric; Larcher, Gwenaelle; Schwell, Martin; Dobrijevic, Michel; Selsis, Franck

    2015-01-01

    Ultraviolet (UV) absorption cross sections are an essential ingredient of photochemical atmosphere models. Exoplanet searches have unveiled a large population of short-period objects with hot atmospheres, very different from what we find in our solar system. Transiting exoplanets whose atmospheres can now be studied by transit spectroscopy receive extremely strong UV fluxes and have typical temperatures ranging from 400 to 2500 K. At these temperatures, UV photolysis cross section data are severely lacking. Our goal is to provide high-temperature absorption cross sections and their temperature dependency for important atmospheric compounds. This study is dedicated to CO2, which is observed and photodissociated in exoplanet atmospheres. We performed these measurements for the 115 - 200 nm range at 300, 410, 480, and 550 K. In the 195 - 230 nm range, we worked at seven temperatures between 465 and 800 K. We found that the absorption cross section of CO2 is very sensitive to temperature, especially above 160 nm....

  15. Observations of Atmospheric Temperature Structure from an Airborne Microwave Temperature Profiler

    Science.gov (United States)

    Haggerty, J. A.; Schick, K. E.; Young, K.; Lim, B.; Ahijevych, D.

    2014-12-01

    A newly-designed Microwave Temperature Profiler (MTP) was developed at JPL for the NSF-NCAR Gulfstream-V aircraft. The MTP is a scanning microwave radiometer that measures thermal emission in the 50-60 GHz oxygen complex. It scans from near-zenith to near-nadir, measuring brightness temperatures forward, above, and below the aircraft at 17 s intervals. A statistical retrieval method derives temperature profiles from the measurements, using proximate radiosonde profiles as a priori information. MTP data examples from recent experiments, comparisons with simultaneous temperature profiles from the Airborne Vertical Atmospheric Profiling System (AVAPS), and a method for blending MTP and AVAPS temperature profiles will be presented. The Mesoscale Predictability Experiment (MPEX; May-June, 2013) investigated the utility of sub-synoptic observations to extend convective-scale predictability and otherwise enhance skill in regional numerical weather prediction over short forecast periods. This project relied on MTP and AVAPS profiles to characterize atmospheric structure on fine spatial scales. Comparison of MTP profiles with AVAPS profiles confirms uncertainty specifications of MTP. A profile blending process takes advantage of the high resolution of AVAPS profiles below the aircraft while utilizing MTP profiles above the aircraft. Ongoing research with these data sets examines double tropopause structure in association with the sub-tropical jet, mountain lee waves, and fluxes at the tropopause. The attached figure shows a mountain lee wave signature in the MTP-derived isentrope field along the flight track during an east-west segment over the Rocky Mountains. A vertically propagating wave with westward tilt is evident on the leeward side of the mountains at around 38 ksec. The Deep Propagating Gravity Wave Experiment over New Zealand (DEEPWAVE; June-July, 2014) investigated the dynamics of gravity waves from the surface to the lower thermosphere. MTP and AVAPS

  16. The effect of atmospheric temperature and pressure on the occurrence of acute myocardial infarction in Kaunas.

    Science.gov (United States)

    Radišauskas, Ričardas; Vaičiulis, Vidmantas; Ustinavičienė, Rūta; Bernotienė, Gailutė

    2013-01-01

    OBJECTIVE. The aim of the study was to evaluate the impact of meteorological variables (atmospheric temperature and pressure) on the daily occurrence of acute myocardial infarction (AMI). MATERIAL AND METHODS. The study used the daily values of atmospheric temperature and pressure in 2000-2007. The meteorological data were obtained from the Lithuanian Hydrometeorological Service for Kaunas. The relative risks of event occurrence were computed for 5°C atmospheric temperature and for 10-hPa atmospheric pressure variations by means of the Poisson regression model. RESULTS. The occurrence of AMI and atmospheric temperature showed an inverse linear relationship, while the occurrence of AMI and atmospheric pressure, a positive linear relationship. Among the youngest subjects (25-44 years old), no relationships were detected. Contrary, among the subjects aged 45-64 years and those aged 65 years and older, the occurrence of AMI significantly decreased with higher temperature (P=0.001 and P=0.002, respectively). A decrease in atmospheric temperature by 10ºC reduced the risk of AMI by 8.7% in the age groups of 45-64 and 65 years and older and by 19% in the age group of 25 years and older. Among the first AMI cases, the risk increased by 7.5% in the age group of 45-64-year olds and by 6.4% in the age group of 25-64-year olds. The relationship between atmospheric temperature and pressure, and AMI occurrence was found to be linear but inverse. An increase in atmospheric pressure by 10 hPa resulted in an increase in risk by 4% among the subjects aged 65 years and more and by 3% among the subjects aged 25 years and more. CONCLUSIONS. Atmospheric temperature and pressure variations had the greatest effect on middle-aged and aging subjects (starting from 45 years). At younger age, the effect of such factors on the AMI risk was considerably lower.

  17. Translational, rotational and vibrational temperatures of a gliding arc discharge at atmospheric pressure air

    DEFF Research Database (Denmark)

    Zhu, Jiajian; Gao, Jinlong; Ehn, Andreas

    2014-01-01

    Gliding arc discharges have generally been used to generate non-equilibrium plasma at atmospheric pressure. Temperature distributions of a gliding arc are of great interest both for fundamental plasma research and for practical applications. In the presented studies, translational, rotational...... and vibrational temperatures of a gliding arc generated at atmospheric pressure air are investigated. Translational temperatures (about 1100 K) were measured by laser-induced Rayleigh scattering, and two-dimensional temperature imaging was performed. Rotational and vibrational temperatures (about 3600 K and 6700...

  18. Vertical thermal structure of the Venus atmosphere from temperature and pressure measurements

    Energy Technology Data Exchange (ETDEWEB)

    Linkin, V.M.; Blamon, Z.; Lipatov, A.P.; Devyatkin, S.I.; Dyachkov, A.V.; Ignatova, S.I.; Kerzhanovich, V.V.; Malyk, K.; Stadny, V.I.; Sanotskiy, Y.V.

    1986-05-01

    Accurate temperature and pressure measurements were made on the Vega-2 lander during its entire descent. The temperature and pressure at the surface were 733 K and 89.3 bar, respectively. A strong temperature inversion was found in the upper troposphere. Several layers with differing static stability were visible in the atmospheric structure.

  19. Vertical thermal structure of the Venus atmosphere from temperature and pressure measurements

    Science.gov (United States)

    Linkin, V. M.; Blamon, Z.; Lipatov, A. P.; Devyatkin, S. I.; Dyachkov, A. V.; Ignatova, S. I.; Kerzhanovich, V. V.; Malyk, K.; Stadny, V. I.; Sanotskiy, Y. V.

    1986-01-01

    Accurate temperature and pressure measurements were made on the Vega-2 lander during its entire descent. The temperature and pressure at the surface were 733 K and 89.3 bar, respectively. A strong temperature inversion was found in the upper troposphere. Several layers with differing static stability were visible in the atmospheric structure.

  20. Temperature Structure and Atmospheric Circulation of Dry, Tidally Locked Rocky Exoplanets

    CERN Document Server

    Koll, Daniel D B

    2016-01-01

    Next-generation space telescopes will observe the atmospheres of rocky planets orbiting nearby M-dwarfs. Understanding these observations will require well-developed theory in addition to numerical simulations. Here we present theoretical models for the temperature structure and atmospheric circulation of dry, tidally locked rocky exoplanets with grey radiative transfer and test them using a general circulation model (GCM). First, we develop a radiative-convective model that captures surface temperatures of slowly rotating and cool atmospheres. Second, we show that the atmospheric circulation acts as a global heat engine, which places strong constraints on large-scale wind speeds. Third, we develop a radiative-convective-subsiding model which extends our radiative-convective model to hot and thin atmospheres. We find that rocky planets develop large day-night temperature gradients at a ratio of wave-to-radiative timescales up to two orders of magnitude smaller than the value suggested by work on hot Jupiters....

  1. Ultraviolet Rayleigh Scatter Imaging for Spatial Temperature Profiles in Atmospheric Microdischarges

    Science.gov (United States)

    2014-09-01

    and rotational temperatures of an atmospheric plasma jet with dimensions on the order of several millimeters were measured with 50 µm resolution...A.D. Carbone, P.J. Bruggeman and J.J.A.M. van der Mullen, "Laser Scattering on an Atmospheric Pressure Plasma Jet : Disentangling Rayleigh, Raman and...distribution unlimited. 2 INTRODUCTION A great interest has emerged over the past decade in atmospheric pressure plasma discharges due to the lower costs

  2. Atmospheric response to the North Pacific enabled by daily sea surface temperature variability

    Science.gov (United States)

    Zhou, Guidi; Latif, Mojib; Greatbatch, Richard J.; Park, Wonsun

    2015-09-01

    Ocean-atmosphere interactions play a key role in climate variability on a wide range of timescales from seasonal to decadal and longer. The extratropical oceans are thought to exert noticeable feedbacks on the atmosphere especially on decadal and longer timescales, yet the large-scale atmospheric response to anomalous extratropical sea surface temperature (SST) is still under debate. Here we show, by means of dedicated high-resolution atmospheric model experiments, that sufficient daily variability in the extratropical background SST needs to be resolved to force a statistically significant large-scale atmospheric response to decadal North Pacific SST anomalies associated with the Pacific Decadal Oscillation, which is consistent with observations. The large-scale response is mediated by atmospheric eddies. This implies that daily extratropical SST fluctuations must be simulated by the ocean components and resolved by the atmospheric components of global climate models to enable realistic simulation of decadal North Pacific sector climate variability.

  3. Infrared photometry and spectrophotometry of Titan. [for atmospheric brightness temperature model

    Science.gov (United States)

    Morrison, D.

    1974-01-01

    The wide variation in infrared brightness temperature of Titan is explained in terms of a greenhouse effect. Radiometric observations in the infrared and microwave frequencies indicate an alternate hot atmospheric model. Methane, ammonia, hydrogen atoms, and nitrogen atoms are suggested as main constituents for the Titan atmosphere.

  4. Prediction of Chinese coal ash fusion temperatures in Ar and H{sub 2} atmospheres

    Energy Technology Data Exchange (ETDEWEB)

    Wen J. Song; Li H. Tang; Xue D. Zhu; Yong Q. Wu; Zi B. Zhu; Shuntarou Koyama [East China University of Science and Technology, Shanghai (China)

    2009-04-15

    The ash fusion temperatures (AFTs) of 21 typical Chinese coal ash samples and 60 synthetic ash samples were measured in Ar and H{sub 2} atmospheres. The computer software package FactSage was used to calculate the temperatures corresponding to different proportions of the liquid phase and predict the phase equilibria of synthetic ash samples. Empirical liquidus models were derived to correlate the AFTs under both Ar and H{sub 2} atmospheres of 60 synthetic ash samples, with their liquidus temperatures calculated by FactSage. These models were used to predict the AFTs of 21 Chinese coal ash samples in Ar and H{sub 2} atmospheres, and then the AFT differences between the atmospheres were analyzed. The results show that, for both atmospheres, there was an apparently linear correlation and good agreement between the AFTs of synthetic ash samples and the liquidus temperatures calculated by FactSage (R > 0.89, and {sigma} < 30{sup o}C). These models predict the AFTs of coal ash samples with a high level of accuracy (SE < 30{sup o}C). Because the iron oxides in coal ash samples fused under a H{sub 2} atmosphere are reduced to metallic iron and lead to changes of mineral species and micromorphology, the AFTs in a H{sub 2} atmosphere are always higher than those with an Ar atmosphere. 34 refs., 9 figs., 7 tabs.

  5. STRATOSPHERIC TEMPERATURES AND WATER LOSS FROM MOIST GREENHOUSE ATMOSPHERES OF EARTH-LIKE PLANETS

    Energy Technology Data Exchange (ETDEWEB)

    Kasting, James F.; Kopparapu, Ravi K. [Department of Geosciences, The Pennsylvania State University, State College, PA 16801 (United States); Chen, Howard, E-mail: jfk4@psu.edu, E-mail: hwchen@bu.edu [Department of Astronomy, Boston University, 725 Commonwealth Ave., Boston, MA 02215 (United States)

    2015-11-01

    A radiative-convective climate model is used to calculate stratospheric temperatures and water vapor concentrations for ozone-free atmospheres warmer than that of modern Earth. Cold, dry stratospheres are predicted at low surface temperatures, in agreement with recent 3D calculations. However, at surface temperatures above 350 K, the stratosphere warms and water vapor becomes a major upper atmospheric constituent, allowing water to be lost by photodissociation and hydrogen escape. Hence, a moist greenhouse explanation for loss of water from Venus, or some exoplanet receiving a comparable amount of stellar radiation, remains a viable hypothesis. Temperatures in the upper parts of such atmospheres are well below those estimated for a gray atmosphere, and this factor should be taken into account when performing inverse climate calculations to determine habitable zone boundaries using 1D models.

  6. Stratospheric Temperatures and Water Loss from Moist Greenhouse Atmospheres of Earth-like Planets

    CERN Document Server

    Kasting, James F; Kopparapu, Ravi Kumar

    2015-01-01

    A radiative-convective climate model is used to calculate stratospheric temperatures and water vapor concentrations for ozone-free atmospheres warmer than that of modern Earth. Cold, dry stratospheres are predicted at low surface temperatures, in agreement with recent 3-D calculations. However, at surface temperatures above 350 K, the stratosphere warms and water vapor becomes a major upper atmospheric constituent, allowing water to be lost by photodissociation and hydrogen escape. Hence, a 'moist greenhouse' explanation for loss of water from Venus, or some exoplanet receiving a comparable amount of stellar radiation, remains a viable hypothesis. Temperatures in the upper parts of such atmospheres are well below those estimated for a gray atmosphere, and this factor should be taken into account when performing 'inverse' climate calculations to determine habitable zone boundaries using 1-D models.

  7. Analysis of 31.4GHz Atmospheric Noise Temperature Measurements at Madrid Deep Space Communications Complex

    Science.gov (United States)

    Shambayati, S.; Keihm, S.

    1998-01-01

    The atmospheric noise temperature at 31.4GHz was measured at NASA's Deep Space Communications Complex at Madrid from September 1990 to December 1996 excluding February 1991 and May 1992 using a Water Vapor Radiometer.

  8. Source of temperature and pressure pulsations during sessile droplet evaporation into multicomponent atmospheres.

    Science.gov (United States)

    Persad, Aaron H; Sefiane, Khellil; Ward, Charles A

    2013-10-29

    During sessile droplet evaporation, studies with IR thermography and shadowgraphs have indicated temperature pulsations. We confirm those observations with microthermocouples, but microthermocouples also indicate temperature pulsations in the atmosphere of the droplet. The pressure in this atmosphere pulsated as well and was correlated with the temperature pulsations in the droplet. Also, we find that if a droplet evaporates into its own vapor, there are no temperature or pressure pulsations. The pulsations occur only if the droplet evaporates into an atmosphere with a component having a heat of solution with the droplet when it adsorbs-absorbs. None of the currently proposed mechanisms for the temperature pulsations provide an explanation for the coupling between the temperature pulsations in the droplet and the vapor-phase pressure pulsations, and for the absence of the pulsations when the system is single-component. As a mechanism for the pulsations, we propose that when a droplet is exposed to an atmosphere containing a component that has a heat of solution with the droplet, energy will be released from adsorption-absorption. This energy will cause pulsations in the evaporation flux, and these pulsations could cause the observed temperature and pressure pulsations. We examine this mechanism by showing that, if the measured temperature pulsations in a water droplet exposed to a methanol atmosphere are used as the input to a theory of evaporation kinetics (statistical rate theory), the pressure pulsations of the water vapor in the methanol atmosphere are predicted and agree with those measured with a quadrupole mass analyzer. When the inputs and outputs are reversed in the theory, we find that the temperature pulsations in the droplet are correctly predicted from the measured water vapor pulsations in the atmosphere.

  9. Temperature of the thermosphere. [Titan atmospheric model with energy transfer

    Science.gov (United States)

    Strobel, D. L.

    1974-01-01

    The vertical temperature contrast for the thermosphere of Titan is estimated considering heating by absorption of solar energy, energy loss through infrared radiation by polyatomic molecules, and energy transfer by thermal conduction between the regions of energy deposition and loss. Current observational data suggest a CH4/H2 mixing ratio of approximately greater than 1, and a vertical temperature contrast smaller than 10 K. However, it is highly probable that H2 and CH4 are not in equilibrium in the thermosphere if there are large H2 escape rates.

  10. Altitude dependence of atmospheric temperature trends: Climate models versus observation

    CERN Document Server

    Douglass, D H; Singer, F

    2004-01-01

    As a consequence of greenhouse forcing, all state of the art general circulation models predict a positive temperature trend that is greater for the troposphere than the surface. This predicted positive trend increases in value with altitude until it reaches a maximum ratio with respect to the surface of as much as 1.5 to 2.0 at about 200 to 400 hPa. However, the temperature trends from several independent observational data sets show decreasing as well as mostly negative values. This disparity indicates that the three models examined here fail to account for the effects of greenhouse forcings.

  11. Destruction mechanisms for formaldehyde in atmospheric pressure low temperature plasmas

    Science.gov (United States)

    Storch, Daniel G.; Kushner, Mark J.

    1993-01-01

    Formaldehyde (CH2O) is a common pollutant of indoor air in residences and commercial buildings. The removal of CH2O from atmospheric pressure gas streams (N2/O2/H2O/CH2O) using plasmas generated by a dielectric barrier discharge has been theoretically investigated with the goal of cleansing indoor air. The model consists of a full accounting of the electron, ion, and neutral chemical kinetics in contaminated humid air. We find that the destruction of CH2O results dominantly from chemical attack by OH and O radicals, with the primary end products being CO and H2O. The predicted destruction rates for CH2O are typically 2-8 ppm/(mJ cm-3) (parts per million of CH2O in air/energy deposition). The elimination of the unwanted byproducts, CO and NO, using a platinum catalyst is discussed.

  12. Dynamic responses of atmospheric carbon dioxide concentration to global temperature changes between 1850 and 2010

    Science.gov (United States)

    Wang, Weile; Nemani, Ramakrishna

    2016-02-01

    Changes in Earth's temperature have significant impacts on the global carbon cycle that vary at different time scales, yet to quantify such impacts with a simple scheme is traditionally deemed difficult. Here, we show that, by incorporating a temperature sensitivity parameter (1.64 ppm yr-1 °C-1) into a simple linear carbon-cycle model, we can accurately characterize the dynamic responses of atmospheric carbon dioxide (CO2) concentration to anthropogenic carbon emissions and global temperature changes between 1850 and 2010 ( r 2 > 0.96 and the root-mean-square error reservoir (~12 year) approximates the long-term temperature sensitivity of global atmospheric CO2 concentration (~15 ppm °C-1), generally consistent with previous estimates based on reconstructed CO2 and climate records over the Little Ice Age. Our results suggest that recent increases in global surface temperatures, which accelerate the release of carbon from the surface reservoirs into the atmosphere, have partially offset surface carbon uptakes enhanced by the elevated atmospheric CO2 concentration and slowed the net rate of atmospheric CO2 sequestration by global land and oceans by ~30% since the 1960s. The linear modeling framework outlined in this paper thus provides a useful tool to diagnose the observed atmospheric CO2 dynamics and monitor their future changes.

  13. Simultaneous wind and temperature measurements in the middle atmosphere with a twin Doppler lidar

    Science.gov (United States)

    Hildebrand, Jens; Baumgarten, Gerd; Fiedler, Jens; Lübken, Franz-Josef

    2016-04-01

    Winds play an important role for the filtering of gravity waves traveling from the ground to higher altitudes. They control the propagation of gravity waves and the amount of transported energy and momentum. The thermal structure of the atmosphere determines its stability, hence the buoyancy frequency. Therefore, knowing winds and temperatures in the middle atmosphere is crucial to study and interpret atmospheric dynamics comprehensively. Both temperature and wind affect the propagation of infrasound waves through the middle atmosphere. Observing winds and temperatures in the middle atmosphere on routine basis is challenging since a large part of this altitude range is not accessible by radars or satellites. Using the Doppler Rayleigh Iodine Spectrometer DoRIS, our Rayleigh/Mie/Raman lidar at the Arctic station ALOMAR in Northern Norway (69°N, 16°E) is capable to measure winds and temperatures simultaneously in the middle atmosphere between about 20 and 80 km altitude. Since two independently steerable telescopes are used, we can derive two wind components at once. Winds and temperatures are measured even under daylight conditions, yielding observations spanning multiple days, which is essential for, e.g., gravity-wave studies. We will present results from case studies and a larger data set covering winter situations between 2012 and 2015, including stratospheric warmings and periods of enhanced gravity wave activity.

  14. Atmospheric Pressure Low Temperature Plasma System for Additive Manufacturing

    Science.gov (United States)

    Burnette, Matthew; Staack, David

    2016-09-01

    There is growing interest in using plasmas for additive manufacturing, however these methods use high temperature plasmas to melt the material. We have developed a novel technique of additive manufacturing using a low temperature dielectric barrier discharge (DBD) jet. The jet is attached to the head of a 3D printer to allow for precise control of the plasma's location. Various methods are employed to deposit the material, including using a vaporized precursor or depositing a liquid precursor directly onto the substrate or into the plasma via a nebulizer. Various materials can be deposited including metals (copper using copper (II) acetylacetonate), polymers (PMMA using the liquid monomer), and various hydrocarbon compounds (using alcohols or a 100% methane DBD jet). The rastering pattern for the 3D printer was modified for plasma deposition, since it was originally designed for thermoplastic extrusion. The design constraints for fill pattern selection for the plasma printer are influenced by substrate heating, deposition area, and precursor consumption. Depositions onto pressure and/or temperature sensitive substrates can be easily achieved. Deposition rates range up to 0.08 cm3/hr using tris(2-methoxyethoxy)(vinyl)silane, however optimization can still be done on the system to improve the deposition rate. For example higher concentration of precursor can be combined with faster motion and higher discharge powers to increase the deposition rate without overheating the substrate.

  15. Atmospheric Abundances in Post-AGB candidates of Intermediate Temperature

    CERN Document Server

    Ferro, A A; Mathias, P; Giridhar, Sunetra

    2001-01-01

    Detailed atmospheric abundances have been calculated for a sample of A-G supergiant stars with IR fluxes and/or high galactic latitudes. HD 172481 and HD 158616 show clear indications of being post-AGB stars that have experienced third dredge-up. HD 158616 is carbon-rich while the abundance pattern of HD 172481 and its large Li enhancement gives support to the hot bottom burning scenario that explains paucity of carbon-rich stars among AGB stars. HD 172324 is very likely a hot post-AGB star that shows a strong carbon deficiency. HD 725, HD 218753 and HD 331319 also appear to be evolved objects between the red giant and the AGB. HD 9167, HD 173638 with a few exceptions, reflect solar abundances and no signs of post red giant evolution. They are most likely young massive disk supergiants. Further analysis of proto-Planetary Nebula HDE 341617 reveals that He lines show signs of velocity stratification. The emission lines have weakened considerably since 1993. The envelope expands at 19 km s$^{-1}$ relative to th...

  16. Fiber optic distributed temperature sensing for the determination of the nocturnal atmospheric boundary layer height

    Directory of Open Access Journals (Sweden)

    C. A. Keller

    2010-06-01

    Full Text Available A new method for measuring air temperature profiles in the atmospheric boundary layer at high spatial and temporal resolution is presented. The measurements are based on Raman scattering distributed temperature sensing (DTS with a fiber optic cable attached to a tethered balloon. These data were used to estimate the height of the stable nocturnal boundary layer. The experiment was successfully deployed during a two-day campaign in September 2009, providing evidence that DTS is well suited for this atmospheric application. Observed stable temperature profiles exhibit an exponential shape confirming similarity concepts of the temperature inversion close to the surface. The atmospheric mixing height (MH was estimated to vary between 5 m and 50 m as a result of the nocturnal boundary layer evolution. This value is in good agreement to the MH derived from concurrent Radon-222 (222Rn measurements and in previous studies.

  17. Fiber optic distributed temperature sensing for the determination of the nocturnal atmospheric boundary layer height

    Directory of Open Access Journals (Sweden)

    C. A. Keller

    2011-02-01

    Full Text Available A new method for measuring air temperature profiles in the atmospheric boundary layer at high spatial and temporal resolution is presented. The measurements are based on Raman scattering distributed temperature sensing (DTS with a fiber optic cable attached to a tethered balloon. These data were used to estimate the height of the stable nocturnal boundary layer. The experiment was successfully deployed during a two-day campaign in September 2009, providing evidence that DTS is well suited for this atmospheric application. Observed stable temperature profiles exhibit an exponential shape confirming similarity concepts of the temperature inversion close to the surface. The atmospheric mixing height (MH was estimated to vary between 5 m and 50 m as a result of the nocturnal boundary layer evolution. This value is in good agreement with the MH derived from concurrent Radon-222 (222Rn measurements and in previous studies.

  18. Low-temperature sintering process for UO2 pellets in partially-oxidative atmosphere

    Institute of Scientific and Technical Information of China (English)

    YANG Xiao-dong; GAO Jia-cheng; WANG Yong; CHANG Xin

    2008-01-01

    Low-temperature sintering(LTS) experiments of UO2 pellets and their results were reported. Moreover, a routine process of LTS for UO2 pellets was primarily established. Being sintered at 1 400 ℃ for 3 h in a partially-oxidative atmosphere, the relative density of the pellet can be up to around 94%. Pellets with such a high density are of benefit for following-up reduction-sintering processes. Orthogonal test indicates that the importance of factors affecting the density decreases in the sequence of partial-oxidative sintering temperature and time, reduction-sintering time and temperature, and sintering atmosphere. It is found that it is helpful to introducing a small amount of water vapor into the sintering atmosphere during the latter stage. It is believed that it is the key factor to raise the O/U ratio of original powder in order to improve the properties of the low-temperature sintered pellets.

  19. VUV-absorption cross section of CO2 at high temperatures and impact on exoplanet atmospheres

    Directory of Open Access Journals (Sweden)

    Venot Olivia

    2014-02-01

    Full Text Available Ultraviolet (UV absorption cross sections are an essential ingredient of photochemical atmosphere models. Exoplanet searches have unveiled a large population of short-period objects with hot atmospheres, very different from what we find in our solar system. Transiting exoplanets whose atmospheres can now be studied by transit spectroscopy receive extremely strong UV fluxes and have typical temperatures ranging from 400 to 2500 K. At these temperatures, UV photolysis cross section data are severely lacking. Our goal is to provide high-temperature absorption cross sections and their temperature dependency for important atmospheric compounds. This study is dedicated to CO2, which is observed and photodissociated in exoplanet atmospheres. We performed these measurements for the 115 - 200 nm range at 300, 410, 480, and 550 K. In the 195 - 230 nm range, we worked at seven temperatures between 465 and 800 K. We found that the absorption cross section of CO2 is very sensitive to temperature, especially above 160 nm. Within the studied range of temperature, the CO2 cross section can vary by more than two orders of magnitude. This, in particular, makes the absorption of CO2 significant up to wavelengths as high as 230 nm, while it is negligible above 200 nm at 300 K. To investigate the influence of these new data on the photochemistry of exoplanets, we implemented the measured cross section into a 1D photochemical model. The model predicts that accounting for this temperature dependency of CO2 cross section can affect the computed abundances of NH3, CO2, and CO by one order of magnitude in the atmospheres of hot Jupiter and hot Neptune.

  20. Seasonal emanation of radon at Ghuttu, northwest Himalaya: Differentiation of atmospheric temperature and pressure influences.

    Science.gov (United States)

    Kamra, Leena

    2015-11-01

    Continuous monitoring of radon along with meteorological parameters has been carried out in a seismically active area of Garhwal region, northwest Himalaya, within the frame work of earthquake precursory research. Radon measurements are carried out by using a gamma ray detector installed in the air column at a depth of 10m in a 68m deep borehole. The analysis of long time series for 2006-2012 shows strong seasonal variability masked by diurnal and multi-day variations. Isolation of a seasonal cycle by minimising short-time by 31 day running average shows a strong seasonal variation with unambiguous dependence on atmospheric temperature and pressure. The seasonal characteristics of radon concentrations are positively correlated to atmospheric temperature (R=0.95) and negatively correlated to atmospheric pressure (R=-0.82). The temperature and pressure variation in their annual progressions are negatively correlated. The calculations of partial correlation coefficient permit us to conclude that atmospheric temperature plays a dominant role in controlling the variability of radon in borehole, 71% of the variability in radon arises from the variation in atmospheric temperature and about 6% of the variability is contributed by atmospheric pressure. The influence of pressure variations in an annual cycle appears to be a pseudo-effect, resulting from the negative correlation between temperature and pressure variations. Incorporation of these results explains the varying and even contradictory claims regarding the influence of the pressure variability on radon changes in the published literature. Temperature dependence, facilitated by the temperature gradient in the borehole, controls the transportation of radon from the deep interior to the surface.

  1. Seasonal variability of diurnal temperature range in Egypt with links to atmospheric circulations and sea surface temperature

    Science.gov (United States)

    El Kenawy, A.; Lopez Moreno, J. I.; Vicente-Serrano, S.

    2010-09-01

    The diurnal temperature range (DTR) is an important climate-change variable. Seasonal and annual variability of DTR in Egypt was investigated based on a monthly dataset of 40 observatories distributing across the country. The trends were calculated using the Rho spearman rank test at the 95 % level of significance. The trends at the independent individual scale were compared with a regional series created for the whole country following the Thiessen polygon approach. A cross-tabulation analysis was performed between the trends of the DTR and the trends of maximum and minimum temperatures to account for directional causes of variability of the DTR at seasonal and annual scales. The physical processes controlling the DTR variability were also assessed in terms of large atmospheric circulations representing in the indices of the North Atlantic Oscillation (NAO), the East Atlantic (EA) pattern, El Niño Southern Oscillation (ENSO) index and the EAWR (East Atlantic/West Russia) Pattern. Also, the variability of the DTR was linked with anomaly of Sea Surface Temperature (SST). A cooling trend was observed in Egypt with strong behavior in winter and summer rather than fall and spring. The upwarding trend of the mean minimum temperature was mainly responsible for variability of the DTR rather than the mean maximum temperature. Also, the EA and the EAWR indices were the main indices accounted for most of variation in the DTR in Egypt, particularly in summer. Key words: trend analysis, temperature variability, Diurnal temperature range, atmospheric circulation, sea surface temperature, Egypt.

  2. Note: atmospheric point discharge current measurements using a temperature-compensated logarithmic current amplifier.

    Science.gov (United States)

    Marlton, G J; Harrison, R G; Nicoll, K A

    2013-06-01

    Measurements of atmospheric corona currents have been made for over 100 years to indicate the atmospheric electric field. Corona currents vary substantially, in polarity and in magnitude. The instrument described here uses a sharp point sensor connected to a temperature compensated bi-polar logarithmic current amplifier. Calibrations over a range of currents from ±10 fA to ±3 μA and across ±20 °C show it has an excellent logarithmic response over six orders of magnitude from 1 pA to 1 μA in both polarities for the range of atmospheric temperatures likely to be encountered in the southern UK. Comparison with atmospheric electric field measurements during disturbed weather confirms that bipolar electric fields induce corona currents of corresponding sign, with magnitudes ~0.5 μA.

  3. Note: Atmospheric point discharge current measurements using a temperature-compensated logarithmic current amplifier

    Science.gov (United States)

    Marlton, G. J.; Harrison, R. G.; Nicoll, K. A.

    2013-06-01

    Measurements of atmospheric corona currents have been made for over 100 years to indicate the atmospheric electric field. Corona currents vary substantially, in polarity and in magnitude. The instrument described here uses a sharp point sensor connected to a temperature compensated bi-polar logarithmic current amplifier. Calibrations over a range of currents from ±10 fA to ±3 μA and across ±20 °C show it has an excellent logarithmic response over six orders of magnitude from 1 pA to 1 μA in both polarities for the range of atmospheric temperatures likely to be encountered in the southern UK. Comparison with atmospheric electric field measurements during disturbed weather confirms that bipolar electric fields induce corona currents of corresponding sign, with magnitudes ˜0.5 μA.

  4. Temperature Structure and Atmospheric Circulation of Dry Tidally Locked Rocky Exoplanets

    Science.gov (United States)

    Koll, Daniel D. B.; Abbot, Dorian S.

    2016-07-01

    Next-generation space telescopes will observe the atmospheres of rocky planets orbiting nearby M-dwarfs. Understanding these observations will require well-developed theory in addition to numerical simulations. Here we present theoretical models for the temperature structure and atmospheric circulation of dry, tidally locked rocky exoplanets with gray radiative transfer and test them using a general circulation model (GCM). First, we develop a radiative-convective (RC) model that captures surface temperatures of slowly rotating and cool atmospheres. Second, we show that the atmospheric circulation acts as a global heat engine, which places strong constraints on large-scale wind speeds. Third, we develop an RC-subsiding model which extends our RC model to hot and thin atmospheres. We find that rocky planets develop large day-night temperature gradients at a ratio of wave-to-radiative timescales up to two orders of magnitude smaller than the value suggested by work on hot Jupiters. The small ratio is due to the heat engine inefficiency and asymmetry between updrafts and subsidence in convecting atmospheres. Fourth, we show, using GCM simulations, that rotation only has a strong effect on temperature structure if the atmosphere is hot or thin. Our models let us map out atmospheric scenarios for planets such as GJ 1132b, and show how thermal phase curves could constrain them. Measuring phase curves of short-period planets will require similar amounts of time on the James Webb Space Telescope as detecting molecules via transit spectroscopy, so future observations should pursue both techniques.

  5. Temperature variations in Titan's upper atmosphere: Impact on Cassini/Huygens

    Directory of Open Access Journals (Sweden)

    B. Kazeminejad

    2005-06-01

    Full Text Available Temperature variations of Titan's upper atmosphere due to the plasma interaction of the satellite with Saturn's magnetosphere and Titan's high altitude monomer haze particles can imply an offset of up to ±30K from currently estimated model profiles. We incorporated these temperature uncertainties as an offset into the recently published Vervack et al. (2004 (Icarus, Vol. 170, 91-112 engineering model and derive extreme case (i.e. minimum and maximum profiles temperature, pressure, and density profiles. We simulated the Huygens probe hypersonic entry trajectory and obtain, as expected, deviations of the probe trajectory for the extreme atmosphere models compared to the simulation based on the nominal one. These deviations are very similar to the ones obtained with the standard Yelle et al. (1997 (ESA SP-1177 profiles. We could confirm that the difference in aerodynamic drag is of an order of magnitude that can be measured by the probe science accelerometer. They represent an important means for the reconstruction of Titan's upper atmospheric properties. Furthermore, we simulated a Cassini low Titan flyby trajectory. No major trajectory deviations were found. The atmospheric torques due to aerodynamic drag, however, are twice as high for our high temperature profile as the ones obtained with the Yelle maximum profile and more than 5 times higher than the worst case estimations from the Cassini project. We propose to use the Cassini atmospheric torque measurements during its low flybys to derive the atmospheric drag and to reconstruct Titan's upper atmosphere density, pressure, and temperature. The results could then be compared to the reconstructed profiles obtained from Huygens probe measurements. This would help to validate the probe measurements and decrease the error bars.

  6. A Useful Tool for Atmospheric Correction and Surface Temperature Estimation of Landsat Infrared Thermal Data

    Science.gov (United States)

    Rivalland, Vincent; Tardy, Benjamin; Huc, Mireille; Hagolle, Olivier; Marcq, Sébastien; Boulet, Gilles

    2016-04-01

    Land Surface temperature (LST) is a critical variable for studying the energy and water budgets at the Earth surface, and is a key component of many aspects of climate research and services. The Landsat program jointly carried out by NASA and USGS has been providing thermal infrared data for 40 years, but no associated LST product has been yet routinely proposed to community. To derive LST values, radiances measured at sensor-level need to be corrected for the atmospheric absorption, the atmospheric emission and the surface emissivity effect. Until now, existing LST products have been generated with multi channel methods such as the Temperature/Emissivity Separation (TES) adapted to ASTER data or the generalized split-window algorithm adapted to MODIS multispectral data. Those approaches are ill-adapted to the Landsat mono-window data specificity. The atmospheric correction methodology usually used for Landsat data requires detailed information about the state of the atmosphere. This information may be obtained from radio-sounding or model atmospheric reanalysis and is supplied to a radiative transfer model in order to estimate atmospheric parameters for a given coordinate. In this work, we present a new automatic tool dedicated to Landsat thermal data correction which improves the common atmospheric correction methodology by introducing the spatial dimension in the process. The python tool developed during this study, named LANDARTs for LANDsat Automatic Retrieval of surface Temperature, is fully automatic and provides atmospheric corrections for a whole Landsat tile. Vertical atmospheric conditions are downloaded from the ERA Interim dataset from ECMWF meteorological organization which provides them at 0.125 degrees resolution, at a global scale and with a 6-hour-time step. The atmospheric correction parameters are estimated on the atmospheric grid using the commercial software MODTRAN, then interpolated to 30m resolution. We detail the processing steps

  7. Trends in atmospheric patterns conducive to seasonal precipitation and temperature extremes in California.

    Science.gov (United States)

    Swain, Daniel L; Horton, Daniel E; Singh, Deepti; Diffenbaugh, Noah S

    2016-04-01

    Recent evidence suggests that changes in atmospheric circulation have altered the probability of extreme climate events in the Northern Hemisphere. We investigate northeastern Pacific atmospheric circulation patterns that have historically (1949-2015) been associated with cool-season (October-May) precipitation and temperature extremes in California. We identify changes in occurrence of atmospheric circulation patterns by measuring the similarity of the cool-season atmospheric configuration that occurred in each year of the 1949-2015 period with the configuration that occurred during each of the five driest, wettest, warmest, and coolest years. Our analysis detects statistically significant changes in the occurrence of atmospheric patterns associated with seasonal precipitation and temperature extremes. We also find a robust increase in the magnitude and subseasonal persistence of the cool-season West Coast ridge, resulting in an amplification of the background state. Changes in both seasonal mean and extreme event configurations appear to be caused by a combination of spatially nonuniform thermal expansion of the atmosphere and reinforcing trends in the pattern of sea level pressure. In particular, both thermal expansion and sea level pressure trends contribute to a notable increase in anomalous northeastern Pacific ridging patterns similar to that observed during the 2012-2015 California drought. Collectively, our empirical findings suggest that the frequency of atmospheric conditions like those during California's most severely dry and hot years has increased in recent decades, but not necessarily at the expense of patterns associated with extremely wet years.

  8. Sea ice edge position impact on the atmospheric boundary layer temperature structure

    Science.gov (United States)

    Khavina, Elena; Repina, Irina

    2016-04-01

    Processes happening in the Arctic region nowadays strongly influence global climate system; the polar amplification effect can be considered one of the main indicators of ongoing changes. Dramatic increase in amount of ice-free areas in the Arctic Ocean, which took place in 2000s, is one of the most significant examples of climate system dynamic in polar region. High amplitude of changes in Arctic climate, both observed and predicted, and existing inaccuracies of climate and weather forecasting models, enforce the development of a more accurate one. It is essential to understand the physics of the interaction between atmosphere and ocean in the Northern Polar area (particularly in boundary layer of the atmosphere) to improve the models. Ice conditions have a great influence on the atmospheric boundary layer in the Arctic. Sea ice inhibits the heat exchange between atmosphere and ocean water during the polar winter, while the heat exchange above the ice-free areas increases rapidly. Due to those significant temperature fluctuations, turbulence of heat fluxes grows greatly. The most intensive interaction takes place at marginal ice zones, especially in case of the cold outbreak - intrusion of cooled air mass from the ice to free water area. Still, thermal structure and dynamic of the atmosphere boundary layer are not researched and described thoroughly enough. Single radio sounding observations from the planes being done, bur they do not provide high-resolution data which is necessary for study. This research is based on continuous atmosphere boundary layer temperature and sea ice observation collected in the Arctic Ocean during the two NABOS expeditions in August and September in 2013 and 2015, as well as on ice conditions satellite data (NASA TEAM 2 and VASIA 2 data processing). Atmosphere temperature data has been obtained with Meteorological Temperature Profiler MTP-5 (ATTEX, Russia). It is a passive radiometer, which provides continuous data of atmospheric

  9. An analysis of the errors associated with the determination of atmospheric temperature from atmospheric pressure and density data

    Science.gov (United States)

    Minzner, R. A.

    1976-01-01

    A graph was developed for relating delta T/T, the relative uncertainty in atmospheric temperature T, to delta p/p, the relative uncertainty in the atmospheric pressure p, for situations, when T is derived from the slope of the pressure-height profile. A similar graph relates delta T/T to delta roh/rho, the relative uncertainty in the atmospheric density rho, for those cases when T is derived from the downward integration of the density-height profile. A comparison of these two graphs shows that for equal uncertainties in the respective basic parameters, p or rho, smaller uncertainties in the derived temperatures are associated with density-height rather than with pressure-height data. The value of delta T/T is seen to depend not only upon delta p or delta rho, and to a small extent upon the value of T or the related scale height H, but also upon the inverse of delta h, the height increment between successive observations of p or rho. In the case of pressure-height data, delta T/T is dominated by 1/delta h for all values of delta h; for density-height data, delta T/T is dominated by delta rho/rho for delta h smaller than about 5 km. In the case of T derived from density-height data, this inverse relationship between delta T/T and delta h applies only for large values of delta h, that is, for delta h 35 km. No limit exists in the fineness of usable height resolution of T which may be derived from densities, while a fine height resolution in pressure-height data leads to temperature with unacceptably large uncertainties.

  10. [Investigation on the gas temperature of a plasma jet at atmospheric pressure by emission spectrum].

    Science.gov (United States)

    Li, Xue-chen; Yuan, Ning; Jia, Peng-ying; Niu, Dong-ying

    2010-11-01

    A plasma jet of a dielectric barrier discharge in coaxial electrode was used to produce plasma plume in atmospheric pressure argon. Spatially and temporally resolved measurement was carried out by photomultiplier tubes. The light emission signals both from the dielectric barrier discharge and from the plasma plume were analyzed. Furthermore, emission spectrum from the plasma plume was collected by high-resolution optical spectrometer. The emission spectra of OH (A 2sigma + --> X2 II, 307.7-308.9 nm) and the first negative band of N2+ (B2 sigma u+ --> X2 IIg+, 390-391.6 nm) were used to estimate the rotational temperature of the plasma plume by fitting the experimental spectra to the simulated spectra. The rotational temperature obtained is about 443 K by fitting the emission spectrum from the OH, and that from the first negative band of N2+ is about 450 K. The rotational temperatures obtained by the two method are consistent within 5% error band. The gas temperature of the plasma plume at atmospheric pressure was obtained because rotational temperature equals to gas temperature approximately in gas discharge at atmospheric pressure. Results show that gas temperature increases with increasing the applied voltage.

  11. Marketability of ready-to-eat cactus pear as affected by temperature and modified atmosphere.

    Science.gov (United States)

    Cefola, Maria; Renna, Massimiliano; Pace, Bernardo

    2014-01-01

    In order to increase the diffusion of cactus pear fruits, in this study, the proper maturity index for peeling and processing them as ready-to-eat product was evaluated and characterized. Thereafter, the effects of different storage temperatures and modified atmosphere conditions on the marketability of ready-to-eat cactus pear were studied. The storage of ready-to-eat fruits at 4 °C in both passive (air) and semi-active (10 kPa O2 and 10 kPa CO2) modified atmosphere improved the marketability by 30%, whereas the storage at 8 °C caused a dangerous reduction in O2 partial pressure inside modified atmosphere packages, due to fruits' increased metabolic activity. A very low level of initial microbial growth was detected, while a severe increase in mesophilic and psychrophilic bacteria was shown in control samples at both temperatures during storage; an inhibitory effect of modified atmosphere on microbial growth was also observed. In conclusion, modified atmosphere improved only the marketability of fruits stored at 4 °C; whereas the storage at 8 °C resulted in deleterious effects on the ready-to-eat fruits, whether stored in air or in modified atmosphere.

  12. Estimation of the Ocean Skin Temperature using the NASA GEOS Atmospheric Data Assimilation System

    Science.gov (United States)

    Koster, Randal D.; Akella, Santha; Todling, Ricardo; Suarez, Max

    2016-01-01

    This report documents the status of the development of a sea surface temperature (SST) analysis for the Goddard Earth Observing System (GEOS) Version-5 atmospheric data assimilation system (ADAS). Its implementation is part of the steps being taken toward the development of an integrated earth system analysis. Currently, GEOS-ADAS SST is a bulk ocean temperature (from ocean boundary conditions), and is almost identical to the skin sea surface temperature. Here we describe changes to the atmosphere-ocean interface layer of the GEOS-atmospheric general circulation model (AGCM) to include near surface diurnal warming and cool-skin effects. We also added SST relevant Advanced Very High Resolution Radiometer (AVHRR) observations to the GEOS-ADAS observing system. We provide a detailed description of our analysis of these observations, along with the modifications to the interface between the GEOS atmospheric general circulation model, gridpoint statistical interpolation-based atmospheric analysis and the community radiative transfer model. Our experiments (with and without these changes) show improved assimilation of satellite radiance observations. We obtained a closer fit to withheld, in-situ buoys measuring near-surface SST. Evaluation of forecast skill scores corroborate improvements seen in the observation fits. Along with a discussion of our results, we also include directions for future work.

  13. Does vertical temperature gradient of the atmosphere matter for El Niño development?

    Science.gov (United States)

    Hu, Zeng-Zhen; Huang, Bohua; Tseng, Yu-heng; Wang, Wanqiu; Kumar, Arun; Zhu, Jieshun; Jha, Bhaskar

    2017-03-01

    In this work, we examine the connection of vertical temperature gradient of the tropospheric atmosphere along the equator with El Niño-Southern Oscillation (ENSO) and the possible impact of the long-term change of the gradient. It is suggested that when the temperature anomalies in the lower troposphere are relatively warmer (cooler) than in the upper troposphere, the atmosphere is less (more) stable and favors an El Niño (a La Niña) event to develop. ENSO evolutions in 1997-1998 and 2014-2015 events are good examples of this relationship. They started from similar ocean anomaly states in the springs of 1997 and 2014, but developed into an extreme El Niño in 1997-1998 and a borderline El Niño in 2014-2015. That may be partially due to differences in the evolutions of the vertical temperature anomaly gradient in troposphere. Thus, in addition to the significant atmospheric response to ENSO, the preconditioning of vertical gradient of the tropospheric temperature due to internal atmospheric processes to some extent may play an active role in affecting ENSO evolution. The long-term trend with more pronounced warming in the upper troposphere than in the lower troposphere causes a reduction in the vertical temperature gradient in the troposphere. Moreover, unlike almost homogenous warm anomalies in the upper troposphere, the lower troposphere shows remarkable regional features along the equator during 1979-2014, with cold anomaly trends over the central and eastern Pacific Ocean associated with the so-called hiatus and some warm anomalies on its two sides in the east and west. This vertical and zonal distribution of the air temperature trends in the troposphere over the Pacific Ocean is consistent with the convection suppression over the central Pacific since 2000, implying a weakening of atmosphere and ocean coupling.

  14. Low-temperature Kinetic Studies of OH Radical Reactions Relevant to Planetary Atmospheres

    Science.gov (United States)

    Townsend, T. M.; Antiñolo, M.; Ballesteros, B.; Jimenez, E.; Canosa, A.

    2011-05-01

    In the solar system, the temperature (T) of the atmosphere of giant planets or their satellites is only several tens of Kelvin (K). The temperature of the tropopause of Titan (satellite of Saturn) and the surface of Mars is 70 K and 210 K, respectively. In the Earth's atmosphere, T decreases from 298 K (surface) to 210 K close to the T-inversion region (tropopause). The principal oxidants in the Earth's lower atmosphere are ozone, the hydroxyl (OH) radical and hydrogen peroxide. A number of critical atmospheric chemical problems depend on the Earth's oxidising capacity, which is essentially the global burden of these oxidants. In the interstellar clouds and circumstellar envelopes, OH radicals have also been detected. As the chemistry of atmospheres is highly influenced by temperature, the knowledge of the T-dependence of the rate coefficients for OH-reactions (k) is the key to understanding the underlying molecular mechanisms. In general, these reactions take place on a short temporal scale. Therefore, a detection technique with high temporal resolution is required. Measurements of k at low temperatures can be achieved by maintaining a thermalised environment using either cryogenic cooling (T>200 K) or supersonic gas expansion with a Laval nozzle (several tens of K). The pulsed laser photolysis technique coupled with laser induced fluorescence detection has been widely used in our laboratory to determine the rate coefficients of OH-reactions with different volatile organic compounds, such as alcohols (1), saturated and unsaturated aliphatic aldehydes (2), linear ketones (3), as a function of temperature (260 350 K). An experimental system based on the CRESU (Cinetique de Reaction en Ecoulement Supersonique Uniforme or Reaction Kinetics in a Uniform Supersonic Flow) technique is currently under construction. This technique will allow the performance of kinetic studies of OH-reactions of astrophysical interest at temperatures lower than 200 K.

  15. Neural Network Based Retrieval of Atmospheric Temperature Profile Using AMSU-A Observations

    Directory of Open Access Journals (Sweden)

    R. K. Gangwar

    2014-01-01

    Full Text Available The present study describes artificial neural network (ANN based approach for the retrieval of atmospheric temperature profiles from AMSU-A microwave temperature sounder. The nonlinear relationship between the temperature profiles and satellite brightness temperatures dictates the use of ANN, which is inherently nonlinear in nature. Since latitudinal variation of temperature is dominant one in the Earth’s atmosphere, separate network configurations have been established for different latitudinal belts, namely, tropics, mid-latitudes, and polar regions. Moreover, as surface emissivity in the microwave region of electromagnetic spectrum significantly influences the radiance (or equivalently the brightness temperature at the satellite altitude, separate algorithms have been developed for land and ocean for training the networks. Temperature profiles from National Center for Environmental Prediction (NCEP analysis and brightness temperature observations of AMSU-A onboard NOAA-19 for the year 2010 have been used for training of the networks. Further, the algorithm has been tested on the independent dataset comprising several months of 2012 AMSU-A observations. Finally, an error analysis has been performed by comparing retrieved profiles with collocated temperature profiles from NCEP. Errors in the tropical region are found to be less than those in the mid-latitude and polar regions. Also, in each region the errors over ocean are less than the corresponding ones over land.

  16. Implications of atmospheric conditions for analysis of surface temperature variability derived from landscape-scale thermography

    Science.gov (United States)

    Hammerle, Albin; Meier, Fred; Heinl, Michael; Egger, Angelika; Leitinger, Georg

    2016-08-01

    Thermal infrared (TIR) cameras perfectly bridge the gap between (i) on-site measurements of land surface temperature (LST) providing high temporal resolution at the cost of low spatial coverage and (ii) remotely sensed data from satellites that provide high spatial coverage at relatively low spatio-temporal resolution. While LST data from satellite (LSTsat) and airborne platforms are routinely corrected for atmospheric effects, such corrections are barely applied for LST from ground-based TIR imagery (using TIR cameras; LSTcam). We show the consequences of neglecting atmospheric effects on LSTcam of different vegetated surfaces at landscape scale. We compare LST measured from different platforms, focusing on the comparison of LST data from on-site radiometry (LSTosr) and LSTcam using a commercially available TIR camera in the region of Bozen/Bolzano (Italy). Given a digital elevation model and measured vertical air temperature profiles, we developed a multiple linear regression model to correct LSTcam data for atmospheric influences. We could show the distinct effect of atmospheric conditions and related radiative processes along the measurement path on LSTcam, proving the necessity to correct LSTcam data on landscape scale, despite their relatively low measurement distances compared to remotely sensed data. Corrected LSTcam data revealed the dampening effect of the atmosphere, especially at high temperature differences between the atmosphere and the vegetated surface. Not correcting for these effects leads to erroneous LST estimates, in particular to an underestimation of the heterogeneity in LST, both in time and space. In the most pronounced case, we found a temperature range extension of almost 10 K.

  17. Implications of atmospheric conditions for analysis of surface temperature variability derived from landscape-scale thermography.

    Science.gov (United States)

    Hammerle, Albin; Meier, Fred; Heinl, Michael; Egger, Angelika; Leitinger, Georg

    2017-04-01

    Thermal infrared (TIR) cameras perfectly bridge the gap between (i) on-site measurements of land surface temperature (LST) providing high temporal resolution at the cost of low spatial coverage and (ii) remotely sensed data from satellites that provide high spatial coverage at relatively low spatio-temporal resolution. While LST data from satellite (LSTsat) and airborne platforms are routinely corrected for atmospheric effects, such corrections are barely applied for LST from ground-based TIR imagery (using TIR cameras; LSTcam). We show the consequences of neglecting atmospheric effects on LSTcam of different vegetated surfaces at landscape scale. We compare LST measured from different platforms, focusing on the comparison of LST data from on-site radiometry (LSTosr) and LSTcam using a commercially available TIR camera in the region of Bozen/Bolzano (Italy). Given a digital elevation model and measured vertical air temperature profiles, we developed a multiple linear regression model to correct LSTcam data for atmospheric influences. We could show the distinct effect of atmospheric conditions and related radiative processes along the measurement path on LSTcam, proving the necessity to correct LSTcam data on landscape scale, despite their relatively low measurement distances compared to remotely sensed data. Corrected LSTcam data revealed the dampening effect of the atmosphere, especially at high temperature differences between the atmosphere and the vegetated surface. Not correcting for these effects leads to erroneous LST estimates, in particular to an underestimation of the heterogeneity in LST, both in time and space. In the most pronounced case, we found a temperature range extension of almost 10 K.

  18. Impedance measurements on Au microelectrodes using controlled atmosphere high temperature scanning probe microscope

    DEFF Research Database (Denmark)

    Wu, Yuehua; Hansen, Karin Vels; Jacobsen, Torben

    2011-01-01

    High temperature impedance measurements on Au microelectrodes deposited on polished yttria stabilized zirconia (YSZ) pellets were demonstrated using a newly designed controlled atmosphere high temperature scanning probe microscope (CAHT-SPM). Probes based on Pt0.8Ir0.2 were fabricated and employed...... in all the investigations. The electrical properties of the Au microelectrodes were investigated using CAHT-SPM at various temperatures in air. The influences of the tip-sample force and of the size of the microelectrode on the electrical properties of the Au microelectrodes were also studied....... The impedance spectra of circular Au microelectrodes down to 8μm in diameter at different temperatures were successfully obtained. The CAHT-SPM presented in this paper is capable of obtaining topography images, conductivity images and impedance spectra in-situ in a temperature range from room temperature...

  19. Long-term air temperature variation in the Karkonosze mountains according to atmospheric circulation

    Science.gov (United States)

    Migała, Krzysztof; Urban, Grzegorz; Tomczyński, Karol

    2016-07-01

    The results of meteorological measurements carried out continuously on Mt Śnieżka in Karkonosze mountains since 1880 well document the warming observed on a global scale. Data analysis indicates warming expressed by an increase in the mean annual air temperature of 0.8 °C/100 years. A much higher temperature increase was recorded in the last two decades at the turn of the twenty-first century. Mean decade air temperatures increased from -0.1 to 1.5 °C. It has been shown that there are relationships between air temperature at Mt Śnieżka and global mechanisms of atmospheric and oceanic circulation. Thermal conditions of the Karkonosze (Mt Śnieżka) accurately reflect global climate trends and impact of the North Atlantic Oscillation (NAO) index, macrotypes of atmospheric circulation in Europe (GWL) and Atlantic Multidecadal Oscillation (AMO). The increase in air temperature during the 1989-2012 solar magnetic cycle may reveal a synergy effect to which astrophysical effects and atmospheric and oceanic circulation effects contribute, modified by constantly increasing anthropogenic factors.

  20. The Titan Haze Simulation experiment on COSmIC: Probing Titan's atmospheric chemistry at low temperature

    Science.gov (United States)

    Sciamma-O'Brien, Ella; Ricketts, Claire L.; Salama, Farid

    2014-11-01

    The aim of the Titan Haze Simulation (THS) experiment is to contribute to a better understanding of aerosol formation in Titan's atmosphere through the study of the chemical formation pathways that link the simpler gas phase molecules resulting from the first steps of the N2-CH4 chemistry, to the more complex gas phase precursors of aerosols; and more specifically, to investigate the role of polycyclic aromatic hydrocarbons (PAHs) and nitrogenated polycyclic aromatic hydrocarbons (PANHs), among other hydrocarbons, in this process. In the THS experiment developed at the NASA Ames Cosmic simulation facility (COSmIC), Titan's atmospheric chemistry is simulated by a pulsed plasma jet expansion at temperature conditions (∼150 K) close to those found in Titan's atmosphere in regions where aerosols are formed. In addition, because of the very short residence time of the gas in the plasma discharge, only the initial steps of the chemistry occur, making the COSmIC/THS a unique tool to study the first and intermediate (when adding heavier precursors to the initial N2-CH4 mixture) steps of Titan's atmospheric chemistry at low temperature as shown in the study presented here. We further illustrate the potential of COSmIC/THS for the simulation of Titan's atmospheric chemistry by presenting very promising results from a preliminary comparison of the laboratory data to data from the Cassini Plasma Spectrometer-Ion Beam Spectrometer (CAPS-IBS) instrument.

  1. Atmospheric response to orbital forcing and 20th century sea surface temperatures

    Science.gov (United States)

    Mantsis, Damianos F.

    This study investigates modes of atmospheric variability in response to changes in Earth's orbit and changes in 20th century sea surface temperatures (SST). The orbital forcing is manifested by a change in obliquity and precession, and changes the distribution of the top-of-atmosphere insolation. A smaller obliquity reduces the annual insolation that the poles receive and increases the annual insolation in the tropics. As the meridional insolation gradient increases, the zonal mean atmospheric-ocean circulation increases. The resulting climate also has a reduced global mean temperature due to the effect of climate feedbacks. This cooling can be attributed to a reduced lapse rate, increased cloud fraction, reduced water vapor in the atmosphere, and an increase in the surface albedo. A change in the precession, as the perihelion shifts from the winter to the summer solstice, causes a strengthening as well as an expansion of the N. Pacific summer subtropical anticyclone. This anticyclonic anomaly can be attributed to the weakening of the baroclinic activity, but also represents the circulation response to remote and local diabatic heating. The remote diabatic heating is associated with monsoonal activity in the SE Asia and North Africa. Regarding the 20th century SST forcing, it is represented by a multidecadal variability in the inter-hemispheric SST difference. This change in the SST causes a latitudinal shift in the ascending branch of the Hadley cell and precipitation in the tropics, as well as an increase in the atmospheric meridional heat transport from the warmer to the colder hemisphere.

  2. Rotational and Vibrational Temperatures of Atmospheric Double Arc Argon-Nitrogen Plasma

    Institute of Scientific and Technical Information of China (English)

    YAN Jian-Hua; TU Xin; MA Zeng-Yi; CEN Ke-Fa; B.G.Chéron

    2007-01-01

    The spectroscopic technique is employed to study the emission of atmospheric argon-nitrogen plasma jet generated by an original dc double anode plasma torch. The molecular bands of the N(+2) first negative system are observed at the torch exit and chosen to evaluate the rotational and vibrational temperatures in comparison with the simulated spectra. The excitation temperature (Texc≈9600 K) is determined from the Boltzmann plot method. The results show that the rotational, vibrational, electron and kinetic temperatures are in good agreement with one another, which indicates that the core region of atmospheric double arc argon-nitrogen plasma jet at the torch exit is close to the local thermodynamic equilibrium state under our experimental conditions.

  3. Ocean and atmosphere coupling, connection between sub-polar Atlantic air temperature, Icelandic minimum and temperature in Serbia

    Directory of Open Access Journals (Sweden)

    Milovanović Boško

    2009-01-01

    Full Text Available In the presented paper correlation between the northern part of the Atlantic ocean (belt between 50-65°N and the atmospheric pressure is examined. Connection between the ocean temperature and atmospheric pressure is the most obvious in the El Nino southern oscillation mechanism. Thus, so far it is not known that such a mechanism exist in the Atlantic ocean. The main accent in the presented paper is focused on the connection between Iceland low and the sea surface temperature (SST in the subpolar part of the Atlantic ocean (used data are in grid 5x5°. By hierarchical cluster analysis five relatively unified clusters of sea surface temperatures grid cells are defined. By multiple linear regression, we examined the correlation between each of the depicted clusters with position and intensity of Iceland low, and identified the most important grid cells inside every cluster. The analysis of the relation between Iceland low and air temperature in Serbia and Belgrade has shown the strongest correlation for the longitude of this centre of action. .

  4. High Temperature Corrosion of Water Wall Materials T23 and T24 in Simulated Furnace Atmospheres

    Institute of Scientific and Technical Information of China (English)

    赵钦新; 张知翔; 成丁南; 王云刚; 邓翔

    2012-01-01

    Candidate materials for water wall of supercritical and ultra-supercritical utility boilers,T23 and T24,were chosen as the experimental samples and exposed to oxidizing atmosphere,reducing atmosphere and oxidizing/reducing alternating atmosphere separately.The corrosion temperature was 450-550?C.The effects of oxygen con-tent and temperature on the corrosion in reducing atmosphere and alternating atmosphere were investigated.The scanning electron microscope(SEM) and energy dispersive spectrometer(EDS) were used to examine the corroded samples.The results show that the corrosion kinetics of T23 and T24 can be described by the double logarithmic equation and parabolic equation respectively.To describe the corrosion of materials accurately it is not sufficient to analyze the macro-mass gain and the macro-thickness of the corroded layer only,but the EDS should be applied to examine the migration depth of corrosive elements O and S.It is revealed that the corrosion becomes more severe when H2S is present in the corrosive gas.S is more active than O,and Cr can reduce the migration of oxygen but not S.The combination corrosion of S and O and pure [S] has a stronger corrodibility than pure H2S.T24 suffers the most severe corrosion at oxygen content of 0.8%.Corrosion is aggravated when the corrosion temperature is above 450 ℃ in the alternating atmosphere.T23 has better corrosion resistance than T24 and W contributes a lot to the corrosion resistance of T23.

  5. Temporal Evolution of the Size and Temperature of Betelgeuse's Extended Atmosphere

    CERN Document Server

    O'Gorman, Eamon; Brown, Alexander; Guinan, Edward F; Richards, Anita M S; Vlemmings, Wouter; Wasatonic, Richard

    2015-01-01

    We use the Very Large Array (VLA) in the A configuration with the Pie Town (PT) Very Long Baseline Array (VLBA) antenna to spatially resolve the extended atmosphere of Betelgeuse over multiple epochs at 0.7, 1.3, 2.0, 3.5, and 6.1 cm. The extended atmosphere deviates from circular symmetry at all wavelengths while at some epochs we find possible evidence for small pockets of gas significantly cooler than the mean global temperature. We find no evidence for the recently reported e-MERLIN radio hotspots in any of our multi-epoch VLA/PT data, despite having sufficient spatial resolution and sensitivity at short wavelengths, and conclude that these radio hotspots are most likely interferometric artefacts. The mean gas temperature of the extended atmosphere has a typical value of 3000 K at 2 $R_{\\star}$ and decreases to 1800 K at 6 $R_{\\star}$, in broad agreement with the findings of the single epoch study from Lim et al. (1998). The overall temperature profile of the extended atmosphere between $2 R_{\\star} \\less...

  6. Effect of tissue and atmosphere's parameters on human eye temperature distribution.

    Science.gov (United States)

    Firoozan, Mohammad Sadegh; Porkhial, Soheil; Nejad, Ali Salmani

    2015-01-01

    A three dimensional finite element method analysis was employed to investigate the effect of tissue and atmosphere parameters namely, ambient temperature, ambient convection coefficient, local blood temperature, and blood convection coefficient upon temperature distribution of human eyes. As a matter of simplification, only eye ball and skull bone are considered as the system of eye modeling. Decreasing the local blood temperature and keeping it cool is one of the most important ways to control bleeding during surgeries. By lower temperature of body organs such as the eye, the need for oxygenated blood is reduced, allowing for an extension in time for surgery. With this in mind, this study is done to see which one of parameters, such as ambient temperature, ambient convection coefficient, local blood temperature, and blood convection coefficient, has an effective role in decreasing the temperature of the eye. To this end, 3 different paths were employed to find out about the temperature distribution through the eye. The analysis of the three paths demonstrates the interaction of ambient and blood temperature in modeling temperature changes in specific locations of the eye. These data will be important in applications such as eye surgery, relaxation, and sleep therapy.

  7. Atmosphere-only GCM (ACCESS1.0) simulations with prescribed land surface temperatures

    Science.gov (United States)

    Ackerley, Duncan; Dommenget, Dietmar

    2016-06-01

    General circulation models (GCMs) are valuable tools for understanding how the global ocean-atmosphere-land surface system interacts and are routinely evaluated relative to observational data sets. Conversely, observational data sets can also be used to constrain GCMs in order to identify systematic errors in their simulated climates. One such example is to prescribe sea surface temperatures (SSTs) such that 70 % of the Earth's surface temperature field is observationally constrained (known as an Atmospheric Model Intercomparison Project, AMIP, simulation). Nevertheless, in such simulations, land surface temperatures are typically allowed to vary freely, and therefore any errors that develop over the land may affect the global circulation. In this study therefore, a method for prescribing the land surface temperatures within a GCM (the Australian Community Climate and Earth System Simulator, ACCESS) is presented. Simulations with this prescribed land surface temperature model produce a mean climate state that is comparable to a simulation with freely varying land temperatures; for example, the diurnal cycle of tropical convection is maintained. The model is then developed further to incorporate a selection of "proof of concept" sensitivity experiments where the land surface temperatures are changed globally and regionally. The resulting changes to the global circulation in these sensitivity experiments are found to be consistent with other idealized model experiments described in the wider scientific literature. Finally, a list of other potential applications is described at the end of the study to highlight the usefulness of such a model to the scientific community.

  8. Atmospheric point discharge current measurements using a\\ud temperature-compensated logarithmic current amplifier

    OpenAIRE

    Marlton, Graeme; Harrison, R. Giles; Nicoll, Keri A.

    2013-01-01

    Measurements of atmospheric corona currents have been made for over 100 years to indicate the atmospheric electric field. Corona currents vary substantially, in polarity and in magnitude. The instrument described here uses a sharp point sensor connected to a temperature compensated bi-polar\\ud logarithmic current amplifier. Calibrations over a range of currents from ±10 fA to ±3 μA and across ±20 ◦C show it has an excellent logarithmic response over six orders of magnitude from 1 pA to 1 μA i...

  9. Atmospheric depression-mediated water temperature changes affect the vertical movement of chum salmon Oncorhynchus keta.

    Science.gov (United States)

    Kitagawa, Takashi; Hyodo, Susumu; Sato, Katsufumi

    2016-08-01

    The Sanriku coastal area, Japan, is one of the southern-most natural spawning regions of chum salmon Oncorhynchus keta. Here, we report their behavioral response to changes in ambient temperature after the passage of an atmospheric depression during the early spawning season. Before the passage, all electrically tagged fish moved vertically for several hours to depths below the shallow thermocline at >100 m. However, during the atmospheric depression, the salmon shortened the duration of their vertical movements and spent most time at the surface. The water column was homogenous at energy cost during migration.

  10. High-temperature condensate clouds in super-hot Jupiter atmospheres

    Science.gov (United States)

    Wakeford, H. R.; Visscher, C.; Lewis, N. K.; Kataria, T.; Marley, M. S.; Fortney, J. J.; Mandell, A. M.

    2017-02-01

    Deciphering the role of clouds is central to our understanding of exoplanet atmospheres, as they have a direct impact on the temperature and pressure structure, and observational properties of the planet. Super-hot Jupiters occupy a temperature regime similar to low-mass M-dwarfs, where minimal cloud condensation is expected. However, observations of exoplanets such as WASP-12b (Teq ˜ 2500 K) result in a transmission spectrum indicative of a cloudy atmosphere. We re-examine the temperature and pressure space occupied by these super-hot Jupiter atmospheres, to explore the role of the initial Al- and Ti-bearing condensates as the main source of cloud material. Due to the high temperatures, a majority of the more common refractory material is not depleted into deeper layers and would remain in the vapour phase. The lack of depletion into deeper layers means that these materials with relatively low cloud masses can become significant absorbers in the upper atmosphere. We provide condensation curves for the initial Al- and Ti-bearing condensates which may be used to provide quantitative estimates of the effect of metallicity on cloud masses, as planets with metal-rich hosts potentially form more opaque clouds because more mass is available for condensation. Increased metallicity also pushes the point of condensation to hotter, deeper layers in the planetary atmosphere further increasing the density of the cloud. We suggest that planets around metal-rich hosts are more likely to have thick refractory clouds, and discuss the implication on the observed spectra of WASP-12b.

  11. Atmospheric pressure chemical vapor deposition (APCVD) grown bi-layer graphene transistor characteristics at high temperature

    KAUST Repository

    Qaisi, Ramy M.

    2014-05-15

    We report the characteristics of atmospheric chemical vapor deposition grown bilayer graphene transistors fabricated on ultra-scaled (10 nm) high-κ dielectric aluminum oxide (Al2O3) at elevated temperatures. We observed that the drive current increased by >400% as temperature increased from room temperature to 250 °C. Low gate leakage was maintained for prolonged exposure at 100 °C but increased significantly at temperatures >200 °C. These results provide important insights for considering chemical vapor deposition graphene on aluminum oxide for high temperature applications where low power and high frequency operation are required. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Venus High Temperature Atmospheric Dropsonde and Extreme-Environment Seismometer (HADES)

    Science.gov (United States)

    Boll, Nathan J.; Salazar, Denise; Stelter, Christopher J.; Landis, Geoffrey A.; Colozza, Anthony J.

    2014-01-01

    The atmospheric composition and geologic structure of Venus have been identified by the US National Research Council's Decadal Survey for Planetary Science as priority targets for scientific exploration, however the high temperature and pressure at the surface, along with the highly corrosive chemistry of the Venus atmosphere, present significant obstacles to spacecraft design that have severely limited past and proposed landed missions. Following the methodology of the NASA Innovative Advanced Concepts (NIAC) proposal regime and the Collaborative Modeling and Parametric Assessment of Space Systems (COMPASS) design protocol, this paper presents a conceptual study and initial feasibility analysis for a Discovery-class Venus lander capable of an extended-duration mission at ambient temperature and pressure, incorporating emerging technologies within the field of high temperature electronics in combination with novel configurations of proven, high Technology Readiness Level (TRL) systems. Radioisotope Thermal Power (RTG) systems and silicon carbide (SiC) communications and data handling are examined in detail, and various high-temperature instruments are proposed, including a seismometer and an advanced photodiode imager. The study combines this technological analysis with proposals for a descent instrument package and a relay orbiter to demonstrate the viability of an integrated atmospheric and in-situ geologic exploratory mission that differs from previous proposals by greatly reducing the mass, power requirements, and cost, while achieving important scientific goals.

  13. Sensitivity of the atmospheric temperature profile to the aerosol absorption in the presence of dust

    Science.gov (United States)

    Gómez-Amo, J. L.; di Sarra, A.; Meloni, D.

    2014-12-01

    Radiative transfer simulations in the shortwave (SW) and longwave (LW) spectral regions have been carried out to investigate the time evolution of the atmospheric heating/cooling rates and their influence on the temperature profiles under different vertical distributions of the aerosol absorption. The case study is based on measurements made at Rome, Italy, on 20 June 2007, when a dust layer was present above the urban boundary layer (BL) and the column aerosol optical depth at 550 nm was about 0.37. Column-integrated aerosol optical depth and single scattering albedo, as well as vertical profiles of aerosol extinction and meteorological variables have been derived from observations and used in the simulations. Different profiles of the aerosol absorption are considered by varying the absorption of the BL aerosols and of the desert dust, without changing the overall columnar properties. Three scenarios have been considered, with absorbing (ABL) or scattering (SBL) particles in the BL, and with a vertically homogeneous case (HL), which is taken as the reference. Calculations show that, for the selected case, about 25% of the SW heating is offset by the LW cooling within the dust layer. Different longwave/all-wave contributions are observed in the BL, depending on the BL aerosol absorption. Changes of atmospheric temperature induced by aerosol-radiation interactions only, have been investigated, while interactions with the surface through changes of the latent and sensible heat flux have been neglected. The evolution of temperature is similar for the three scenarios within the dust layer, with a daytime increase and a smaller nighttime decrease. After 24 h, the increase of the atmospheric temperature due to the aerosol radiative processes is about 1 K. In the BL, the increase of temperature is strongly dependent on the aerosol absorption capability. The oscillatory behaviour of the temperature with time in the dust layer, and the different evolution in the BL are

  14. Morphological features and variations of temperature in the upper thermosphere simulated by a whole atmosphere GCM

    Directory of Open Access Journals (Sweden)

    H. Fujiwara

    2010-02-01

    Full Text Available In order to illustrate morphological features and variations of temperature in the upper thermosphere, we performed numerical simulations with a whole atmosphere general circulation model (GCM for the solar minimum and geomagnetically quiet conditions in March, June, September, and December. In previous GCMs, tidal effects were imposed at the lower boundaries assuming dominant diurnal and semi-diurnal tidal modes. Since the GCM used in the present study covers all the atmospheric regions, the atmospheric tides with various modes are generated within the GCM. The global temperature distributions obtained from the GCM are in agreement with ones obtained from NRLMSISE-00. In addition, the GCM also represents localised temperature structures which are superimposed on the global day-night distributions. These localised structures, which vary from hour to hour, would be observed as variations with periods of about 2–3 h at a single site. The amplitudes of the 2–3 h variations are significant at high-latitude, while the amplitudes are small at low-latitude. The diurnal temperature variation is more clearly identified at low-latitude than at high-latitude. When we assume the same high-latitude convection electric field in each month, the temperature calculated in the polar cap region shows diurnal variation more clearly in winter than in summer. The midnight temperature maximum (MTM, which is one of the typical low-latitude temperature structures, is also seen in the GCM results. The MTMs in the GCM results show significant day-to-day variation with amplitudes of several 10s to about 150 K. The wind convergence and stream of warm air are found around the MTM. The GCM also represent the meridional wind reversals and/or abatements which are caused due to local time variations of airflow pattern in the low-latitude region.

  15. Measurements of Rotational Temperatures in Atmospheric-Pressure Capillary Plasma Electrode (CPE) Discharge

    Science.gov (United States)

    Figus, Margaret; Abramzon, Nina; Becker, Kurt

    2003-10-01

    We report the results of rotational temperature measurements in atmospheric-pressure capillary plasma electrode (CPE) discharges in ambient air using the unresolved N2 second positive band. Assuming that the emitting N2 molecules can be described by a Maxwell-Boltzmann distribution characterized by a single rotational temperature, this temperature is determined from a fit of the measured emission spectrum to a calculated spectrum. If the emitting species are in equilibrium with the bulk gas in the plasma, then this temperature can be interpreted as the gas kinetic temperature in the plasma. We determined rotational temperatures for three different plasma regions: inside the capillary by analyzing radiation emitted along the axis of the capillary, between the capillaries, and perpendicular to the axis of the capillary. Each region has a different plasma density and, therefore, a different gas temperature with the plasma inside the capillary being the hottest. We also measured the rotational temperatures in each region as a function of the plasma power. As expected, the rotational temperatures increase with increasing discharge power. Work supported by the NSF and by ARO through a DURIP award.

  16. Effect of temperature and atmospheric environment on the photodegradation of some Disperse Red 1-type polymers.

    Science.gov (United States)

    Galvan-Gonzalez, A; Canva, M; Stegeman, G I; Twieg, R; Kowalczyk, T C; Lackritz, H S

    1999-12-01

    The photodegradation of the azobenzene chromophore DR1 {4-[N-ethyl-N-(2-hydroxyethyl)amino]-4(?)-nitroazobenzene]} incorporated as a side chain or as a guest in a poly(methyl) methacrylate host has been evaluated as a function of wavelength, temperature, and the atmospheric environment. The effects of these variables on the lifetime of DR1-based electro-optic devices is quantified.

  17. The THS experiment: Simulating Titan's atmospheric chemistry at low temperature (200 K)

    Science.gov (United States)

    Sciamma-O'Brien, Ella; Upton, Kathleen T.; Beauchamp, Jack L.; Salama, Farid

    2016-10-01

    In the Titan Haze Simulation (THS) experiment, Titan's atmospheric chemistry is simulated by plasma discharge in the stream of a supersonic expansion, i.e. at low Titan-like temperature (150 K). Here, we present complementary gas and solid phase analyses of four N2-CH4-based gas mixtures that demonstrate the unique capability of the THS to monitor the chemical growth evolution in order to better understand Titan's chemistry and the origin of aerosol formation.

  18. Atmospheric pressure and temperature profiling using near IR differential absorption lidar

    Science.gov (United States)

    Korb, C. L.; Schwemmer, G. K.; Dombrowski, M.; Weng, C. Y.

    1983-01-01

    The present investigation is concerned with differential absorption lidar techniques for remotely measuring the atmospheric temperature and pressure profile, surface pressure, and cloud top pressure-height. The procedure used in determining the pressure is based on the conduction of high-resolution measurements of absorption in the wings of lines in the oxygen A band. Absorption with respect to these areas is highly pressure sensitive in connection with the mechanism of collisional line broadening. The method of temperature measurement utilizes a determination of the absorption at the center of a selected line in the oxygen A band which originates from a quantum state with high ground state energy.

  19. Comment on "Scaling of atmosphere and ocean temperature correlations in observations and climate models"

    CERN Document Server

    Bunde, A; Havlin, S; Koscielny-Bunde, E; Schellnhuber, H J; Vjushin, D; Bunde, Armin; Eichner, Jan F.; Havlin, Shlomo; Koscielny-Bunde, Eva; Schellnhuber, Hans J.; Vjushin, Dmitry

    2003-01-01

    In a recent letter [K. Fraedrich and R. Blender, Phys. Rev. Lett. 90, 108501 (2003)], Fraedrich and Blender studied the scaling of atmosphere and ocean temperature. They analyzed monthly temperature records by using the detrended fluctuation analysis and claim that the scaling exponent alpha over the inner continents is equal to 0.5, being characteristic of uncorrelated random sequences. Here we show that also for the inner continents, the exponent is between 0.6 and 0.7, similar as for the coastline-stations.

  20. SPECTROSCOPIC EVIDENCE FOR A TEMPERATURE INVERSION IN THE DAYSIDE ATMOSPHERE OF HOT JUPITER WASP-33b

    Energy Technology Data Exchange (ETDEWEB)

    Haynes, Korey; Mandell, Avi M. [Solar System Exploration Division, NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Madhusudhan, Nikku [Institute of Astronomy, University of Cambridge, Cambridge CB3 0HA (United Kingdom); Deming, Drake [Department of Astronomy, University of Maryland, College Park, MD 20742 (United States); Knutson, Heather, E-mail: khaynes0112@gmail.com [Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125 (United States)

    2015-06-20

    We present observations of two occultations of the extrasolar planet WASP-33b using the Wide Field Camera 3 (WFC3) on the Hubble Space Telescope, which allow us to constrain the temperature structure and composition of its dayside atmosphere. WASP-33b is the most highly irradiated hot Jupiter discovered to date, and the only exoplanet known to orbit a δ-Scuti star. We observed in spatial scan mode to decrease instrument systematic effects in the data, and removed fluctuations in the data due to stellar pulsations. The rms for our final, binned spectrum is 1.05 times the photon noise. We compare our final spectrum, along with previously published photometric data, to atmospheric models of WASP-33b spanning a wide range in temperature profiles and chemical compositions. We find that the data require models with an oxygen-rich chemical composition and a temperature profile that increases at high altitude. We find that our measured spectrum displays an excess in the measured flux toward short wavelengths that is best explained as emission from TiO. If confirmed by additional measurements at shorter wavelengths, this planet would become the first hot Jupiter with a thermal inversion that can be definitively attributed to the presence of TiO in its dayside atmosphere.

  1. NF3: UV Absorption Spectrum Temperature Dependence and the Atmospheric and Climate Forcing Implications

    Science.gov (United States)

    Papadimitriou, Vassileios C.; McGillen, Max R.; Fleming, Eric L.; Jackman, Charles H.; Burkholder, James B.

    2013-01-01

    Nitrogen trifluoride (NF3) is an atmospherically persistent greenhouse gas that is primarily removed by UV photolysis and reaction with O((sup 1)D) atoms. In this work, the NF3 gas-phase UV absorption spectrum, sigma(delta,T), was measured at 16 wavelengths between 184.95 and 250 nm at temperatures between 212 and 296 K. A significant spectrum temperature dependence was observed in the wavelength region most relevant to atmospheric photolysis (200-220 nm) with a decrease in sigma(210 nm,T) of approximately 45 percent between 296 and 212 K. Atmospheric photolysis rates and global annually averaged lifetimes of NF3 were calculated using the Goddard Space Flight Center 2-D model and the sigma(delta,T) parameterization developed in this work. Including the UV absorption spectrum temperature dependence increased the stratospheric photolysis lifetime from 610 to 762 years and the total global lifetime from 484 to 585 years; the NF3 global warming potentials on the 20-, 100-, and 500-year time horizons increased less than 0.3, 1.1, and 6.5 percent to 13,300, 17,700, and 19,700, respectively.

  2. The relationship between ozone formation and air temperature in the atmospheric surface layer

    Science.gov (United States)

    Belan, Boris D.; Savkin, Denis; Tolmachev, Gennadii

    2016-04-01

    Studying the formation and dynamics of ozone in the atmosphere is important due to several reasons. First, the contribution of tropospheric ozone to the global greenhouse effect is only slightly less than that of water vapor, carbon dioxide, and methane. Second, tropospheric ozone acts as a strong poison that has negative effects on human health, animals, and vegetation. Third, being a potent oxidizer, ozone destroys almost all materials, including platinum group metals and compounds. Fourthly, ozone is formed in situ from precursors as a result of photochemical processes, but not emitted into the atmosphere by any industrial enterprises directly. In this work, we present some results of the study aimed at the revealing relationship between ozone formation rate and surface air temperature in the background atmosphere. It has been found that this relationship is nonlinear. Analysis of the possible reasons showed that the nonlinear character of this relationship may be due to a nonlinear increase in the reaction constants versus air temperature and a quadratic increase in the concentration of hydrocarbons with increasing temperature. This work was supported by the Ministry of Education and Science contract no.14.613.21.0013 (ID: RFMEFI61314X0013).

  3. [Effects of temperature and heating time on armco iron spectral emissivity in atmospheric environment].

    Science.gov (United States)

    Yu, Kun; Wang, Wen-Bao; Zhang, Kai-Hua; Liu, Yu-Fang

    2014-09-01

    The spectral emissivity of pure iron at 1.55 μm was investigated systematically by using our self-designed reflective experimental apparatus based on the Kirchhoff's law, and the influences of temperature and heating time on the spectral emissivity of pure iron were also discussed. The experimental data showed that the spectral emissivity of pure iron increased with temperature rising and its peak value and valley value appeared at certain temperatures. By analyzing the emissivity model of metal with oxidation layer, the variation of the spectral emissivity of pure iron was illustrated. The influence of heating time on the spectral emissivity was different at different temperature. The research results will further enrich pure iron spectral emissivity data, and provide the experimental basis for its application in atmospheric environment.

  4. A Software Tool for Atmospheric Correction and Surface Temperature Estimation of Landsat Infrared Thermal Data

    Directory of Open Access Journals (Sweden)

    Benjamin Tardy

    2016-08-01

    Full Text Available Land surface temperature (LST is an important variable involved in the Earth’s surface energy and water budgets and a key component in many aspects of environmental research. The Landsat program, jointly carried out by NASA and the USGS, has been recording thermal infrared data for the past 40 years. Nevertheless, LST data products for Landsat remain unavailable. The atmospheric correction (AC method commonly used for mono-window Landsat thermal data requires detailed information concerning the vertical structure (temperature, pressure and the composition (water vapor, ozone of the atmosphere. For a given coordinate, this information is generally obtained through either radio-sounding or atmospheric model simulations and is passed to the radiative transfer model (RTM to estimate the local atmospheric correction parameters. Although this approach yields accurate LST data, results are relevant only near this given coordinate. To meet the scientific community’s demand for high-resolution LST maps, we developed a new software tool dedicated to processing Landsat thermal data. The proposed tool improves on the commonly-used AC algorithm by incorporating spatial variations occurring in the Earth’s atmosphere composition. The ERA-Interim dataset (ECMWFmeteorological organization was used to retrieve vertical atmospheric conditions, which are available at a global scale with a resolution of 0.125 degrees and a temporal resolution of 6 h. A temporal and spatial linear interpolation of meteorological variables was performed to match the acquisition dates and coordinates of the Landsat images. The atmospheric correction parameters were then estimated on the basis of this reconstructed atmospheric grid using the commercial RTMsoftware MODTRAN. The needed surface emissivity was derived from the common vegetation index NDVI, obtained from the red and near-infrared (NIR bands of the same Landsat image. This permitted an estimation of LST for the entire

  5. Ground-based microwave measuring of middle atmosphere ozone and temperature profiles during sudden stratospheric warming

    Science.gov (United States)

    Feigin, A. M.; Shvetsov, A. A.; Krasilnikov, A. A.; Kulikov, M. Y.; Karashtin, D. A.; Mukhin, D.; Bolshakov, O. S.; Fedoseev, L. I.; Ryskin, V. G.; Belikovich, M. V.; Kukin, L. M.

    2012-12-01

    We carried out the experimental campaign aimed to study the response of middle atmosphere on a sudden stratospheric warming in winter 2011-2012 above Nizhny Novgorod, Russia (56N, 44E). We employed the ground-based microwave complex for remote sensing of middle atmosphere developed in the Institute of Applied Physics of the Russian Academy of Science. The complex combines two room-temperature radiometers, i.e. microwave ozonometer and the stratospheric thermometer. Ozonometer is a heterodyne spectroradiometer, operating in a range of frequencies that include the rotation transition of ozone molecules with resonance frequency 110.8 GHz. Operating frequency range of the stratospheric thermometer is 52.5-5.4 GHz and includes lower frequency edge of 5 mm molecular oxygen absorption bands and among them two relatively weak lines of O2 emission. Digital fast Fourier transform spectrometers developed by "Acqiris" are employed for signal spectral analysis. The spectrometers have frequency range 0.05-1 GHz and realizes the effective resolution about 61 KHz. For retrieval vertical profiles of ozone and temperature from radiometric data we applied novel method based on Bayesian approach to inverse problem solution, which assumed a construction of probability distribution of the characteristics of retrieved profiles with taking into account measurement noise and available a priori information about possible distributions of ozone and temperature in the middle atmosphere. Here we introduce the results of the campaign in comparison with Aura MLS data. Presented data includes one sudden stratospheric warming event which took place in January 13-14 and was accompanied by temperature increasing up to 310 K at 45 km height. During measurement period, ozone and temperature variations were (almost) anti-correlated, and total ozone abundance achieved a local maxima during the stratosphere cooling phase. In general, results of ground-based measurements are in good agreement with

  6. Investigating Titan's Atmospheric Chemistry at Low Temperature in Support of the NASA Cassini Mission

    Science.gov (United States)

    Sciamma-O'Brien, Ella; Salama, Farid

    2013-01-01

    Titan's atmosphere, composed mainly of N2 and CH4, is the siege of a complex chemistry induced by solar UV radiation and electron bombardment from Saturn's magnetosphere. This organic chemistry occurs at temperatures lower than 200 K and leads to the production of heavy molecules and subsequently solid aerosols that form the orange haze surrounding Titan. The Titan Haze Simulation (THS) experiment has been developed on the COSMIC simulation chamber at NASA Ames in order to study the different steps of Titan's atmospheric chemistry at low temperature and to provide laboratory data in support for Cassini data analysis. The chemistry is simulated by plasma in the stream of a supersonic expansion. With this unique design, the gas mixture is adiabatically cooled to Titan-like temperature (approx. 150 K) before inducing the chemistry by plasma discharge. Different gas mixtures containing N2, CH4, and the first products of the N2,-CH4 chemistry (C2H2, C2H4, C6H6...) but also heavier molecules such as PAHs or nitrogen containing PAHs can be injected. Both the gas phase and solid phase products resulting from the plasma-induced chemistry can be monitored and analyzed. Here we present the results of recent gas phase and solid phase studies that highlight the chemical growth evolution when injecting heavier hydrocarbon trace elements in the initial N2-CH4 mixture. Due to the short residence time of the gas in the plasma discharge, only the first steps of the chemistry have time to occur in a N2-CH4 discharge. However by adding acetylene and benzene to the initial N2-CH4 mixture, we can study the intermediate steps of Titan's atmospheric chemistry as well as specific chemical pathways. These results show the uniqueness of the THS experiment to help understand the first and intermediate steps of Titan fs atmospheric chemistry as well as specific chemical pathways leading to Titan fs haze formation.

  7. Low-temperature and low atmospheric pressure infrared reflectance spectroscopy of Mars soil analog materials

    Science.gov (United States)

    Bishop, Janice L.; Pieters, Carle M.

    1995-01-01

    Infrared reflectance spectra of carefully selected Mars soil analog materials have been measured under low atmospheric pressures and temperatures. Chemically altered montmorillonites containing ferrihydrite and hydrated ferric sulfate complexes are examined, as well as synthetic ferrihydrite and a palagonitic soil from Haleakala, Maui. Reflectance spectra of these analog materials exhibit subtle visible to near-infrared features, which are indicative of nanophase ferric oxides or oxyhydroxides and are similar to features observed in the spectra of the bright regions of Mars. Infrared reflectance spectra of these analogs include hydration features due to structural OH, bound H2O, and adsorbed H2O. The spectral character of these hydration features is highly dependent on the sample environment and on the nature of the H2O/OH in the analogs. The behavior of the hydration features near 1.9 micron, 2.2 micron, 2.7 micron, 3 micron, and 6 microns are reported here in spectra measured under a Marslike atmospheric environment. In spectra of these analogs measured under dry Earth atmospheric conditions the 1.9-micron band depth is 8-17%; this band is much stronger under moist conditions. Under Marslike atmospheric conditions the 1.9-micron feature is broad and barely discernible (1-3% band depth) in spectra of the ferrihydrite and palagonitic soil samples. In comparable spectra of the ferric sulfate-bearing montmorillonite the 1.9-micron feature is also broad, but stronger (6% band depth). In the low atmospheric pressure and temperature spectra of the ferrihydrite-bearing montmorillonite this feature is sharper than the other analogs and relatively stronger (6% band depth). Although the intensity of the 3-micron band is weaker in spectra of each of the analogs when measured under Marslike conditions, the 3-micron band remains a dominant feature and is especially broad in spectra of the ferrihydrite and palagonitic soil. The structural OH features observed in these materials

  8. Direct measurements of the effect of biomass burning over the Amazon on the atmospheric temperature profile

    Directory of Open Access Journals (Sweden)

    L. Remer

    2009-11-01

    Full Text Available Aerosols suspended in the atmosphere interact with solar radiation and clouds, thus change the radiation energy fluxes in the atmospheric column. In this paper we measure changes in the atmospheric temperature profile as a function of the smoke loading and the cloudiness, over the Amazon basin, during the dry seasons (August and September of 2005–2008. We show that as the aerosol optical depth (AOD increases from 0.02 to a value of ~0.6, there is a decrease of ~4°C at 1000 hPa, and an increase of ~1.5°C at 850 hPa. The warming of the aerosol layer at 850 hPa is likely due to aerosol absorption when the particles are exposed to direct illumination by the sun. The large values of cooling in the lower layers could be explained by a combination of aerosol extinction of the solar flux in the layers aloft together with an aerosol-induced increase of cloud cover which shade the lower atmosphere. We estimate that the increase in cloud fraction due to aerosol contributes about half of the observed cooling in the lower layers.

  9. Convective organization in the super-parameterized community atmosphere model with constant surface temperature

    Science.gov (United States)

    Kuang, Z.

    2015-12-01

    Organization in a moist convecting atmosphere is investigated using the super-parameterized community atmosphere model (SPCAM) in aquaplanet setting with constant surface temperature, with and without planetary rotation. Without radiative and surface feedbacks, convective organization is dominated by convectively coupled gravity waves without planetary rotation and convectively coupled equatorial waves when there is planetary rotation. This behavior is well captured when the cloud resolving model (CRM) in SPCAM is replaced by its linear response function, computed following Kuang (2010), for the state of radiative convective equilibrium (RCE). With radiative feedback, however, convection self-aggregates, and with planetary rotation, the tropical zonal wavenumber-frequency spectrum features a red noise background. These behaviors in the presence of the radiative feedback are not captured when the CRM is replaced by its linear response function around the RCE state with radiative feedback included in the construction. Implications to organization in a moist convecting atmosphere will be discussed. Kuang, Z., Linear response functions of a cumulus ensemble to temperature and moisture perturbations and implication to the dynamics of convectively coupled waves, J. Atmos. Sci., 67, 941-962, (2010)

  10. Temperature-dependent Henry's law constants of atmospheric organics of biogenic origin.

    Science.gov (United States)

    Leng, Chunbo; Kish, J Duncan; Kelley, Judas; Mach, Mindy; Hiltner, Joseph; Zhang, Yunhong; Liu, Yong

    2013-10-10

    There have been growing interests in modeling studies to understand oxidation of volatile organic compounds in the gas phase and their mass transfer to the aqueous phase for their potential roles in cloud chemistry, formation of secondary organic aerosols, and fate of atmospheric organics. Temperature-dependent Henry's law constants, key parameters in the atmospheric models to account for mass transfer, are often unavailable. In the present work, we investigated gas-liquid equilibriums of isoprene, limonene, α-pinene, and linalool using a bubble column technique. These compounds, originating from biogenic sources, were selected for their implications in atmospheric cloud chemistry and secondary organic aerosol formation. We reported Henry's law constants (K(H)), first order loss rates (k), and gas phase diffusion coefficients over a range of temperatures relevant to the lower atmosphere (278-298 K) for the first time. The measurement results of K(H) values for isoprene, limonene, α-pinene, and linalool at 298 K were 0.036 ± 0.003; 0.048 ± 0.004; 0.029 ± 0.004; and 21.20 ± 0.30 mol L(-1) atm(-1), respectively. The fraction for these compounds in stratocumulus and cumulonimbus clouds at 278 K were also estimated in this work (isoprene, 1.0 × 10(-6), 6.8 × 10(-6); limonene, 1.5 × 10(-6), 1.0 × 10(-5); α-pinene, 4.5 × 10(-7), 3.1 × 10(-6); and linalool, 6.2 × 10(-4), 4.2 × 10(-3)). Our measurements in combination with literature results indicated that noncyclic alkenes could have smaller K(H) values than those of cyclic terpenes and that K(H) values may increase with an increasing number of double bonds. It was also shown that estimated Henry's law constants and their temperature dependence based on model prediction can differ from experimental results considerably and that direct measurements of temperature-dependent Henry's law constants of atmospheric organics are necessary for future work.

  11. Torrefaction and low temperature carbonization of oil palm fiber and Eucalyptus in nitrogen and air atmospheres.

    Science.gov (United States)

    Lu, Ke-Miao; Lee, Wen-Jhy; Chen, Wei-Hsin; Liu, Shih-Hsien; Lin, Ta-Chang

    2012-11-01

    Torrefaction is a pretreatment method for upgrading biomass as solid fuels. To provide flexible operations for effectively upgrading biomass at lower costs, the aim of this study was to investigate the properties of oil palm fiber and eucalyptus pretreated in nitrogen and air atmospheres at temperatures of 250-350°C for 1h. Based on energy and solid yield and introducing an energy-mass co-benefit index (EMCI), oil palm fiber pretreatment under nitrogen at 300°C provided the solid fuel with higher energy density and less volume compared to other temperatures. Pretreatment of oil palm fiber in air resulted in the fuel with low solid and energy yields and is therefore not recommended. For eucalyptus, nitrogen and air can be employed to upgrade the biomass, and the suggested temperatures are 325 and 275°C, respectively.

  12. A Three-Dimensional Satellite Retrieval Method for Atmospheric Temperature and Moisture Profiles

    Institute of Scientific and Technical Information of China (English)

    ZHANG Lei; QIU Chongjian; HUANG Jianping

    2008-01-01

    A three-dimensional variational method iS proposed to simultaneously retrieve the 3-D atmospheric temperature and moisture profiles from satellite radiance measurements.To include both vertical structure and the horizontal patterns of the atmospheric temperature and moisture.an EOF technique iS used to decompose the temperature and moisture field in a 3-D space.A number of numerical simulations are conducted and they demonstrate that the 3-D method iS less sensitive to the observation errors compared to the 1-D method.When the observation error iS more than 2.0 K.to get the best results.the truncation number for the EOF'S expansion have to be restricted to 2 in the 1-D method.while it can be set as large as 40 in a 3-D method.This results in the truncation error being reduced and the retrieval accuracy being improved in the 3-D method.Compared to the 1-D method.the rlTLS errors of the 3-D method are reduced by 48%and 36%for the temperature and moisture retrievals,respectively.Using the real satellite measured brightness temperatures at 0557 UTC 31 July 2002,the temperature and moisture profiles are retrieved over a region(20°-45°N,100°-125°E)and compared with 37 collocated radiosonde observations.The results show that the retrieval accuracy with a 3-D method iS significantly higher than those with the 1-D method.

  13. Efficiencies of Rotational Raman, and Rayleigh Techniques for Laser Remote Sensing of the Atmospheric Temperature

    Science.gov (United States)

    Ivanova, I. D.; Gurdev, L. L.; Mitev, V. M.

    1992-01-01

    Various lidar methods have been developed for measuring the atmospheric temperature, making use of the temperature dependant characteristics of rotational Raman scattering (RRS) from nitrogen and oxygen, and Rayleigh or Rayleigh-Brillowin scattering (RS or RBS). These methods have various advantages and disadvantages as compared to each other but their potential accuracies are principal characteristics of their efficiency. No systematic attempt has been undertaken so far to compare the efficiences, in the above meaning, of different temperature lidar methods. Two RRS techniques have been compared. Here, we do such a comparison using two methods based on the detection and analysis of RS (RBS) spectra. Four methods are considered here for measuring the atmospheric temperature. One of them (Schwiesow and Lading, 1981) is based on an analysis of the RS linewidth with two Michelson interferometers (MI) in parallel. The second method (Shimisu et al., 1986) employs a high-resolution analysis of the RBS line shape. The third method (Cooney, 1972) employs the temperature dependance of the RRS spectrum envelope. The fourth method (Armstrong, 1974) makes use of a scanning Fabry-Perot interferometer (FPI) as a comb filter for processing the periodic RRS spectrum of the nitrogen. Let us denote the corresponding errors in measuring the temperature by sigma(sub MI), sigma(sub HR), sigma(sub ENV), and sigma(sub FPI). Let us also define the ratios chi(sub 1) = sigma(sub MI)/sigma(sub ENV), chi(sub 2) = sigma(sub HR)/sigma(sub ENV), and chi(sub 3) = sigma(sub FPI)/sigma(sub ENV) interpreted as relative errors with respect to sigma(sub ENV).

  14. Behavior of UO2 and fissium in sodium vapor atmosphere at temperatures up to 2800 C

    Science.gov (United States)

    Feuerstein, H.; Oschinski, J.

    1986-11-01

    An experimental technique was developed to study the behavior of fuel and fission products in out-of-pile tests in a sodium vapor atmosphere. Evaporation rates of UO2 were measured up to 2800 C. The evaporation is found to depend on temperature and the active surface. Evaporation restructures the surface of the samples, however no new active surface is formed; UO2 can form well shaped crystals and curious erosion products. The efficiency of the used condenser/filter lines is 99.99%. In an HCDA, all the evaporated substances condense in the sodium pool. Thermal reduction of the UO2 reduces the oxygen potential of the system. The final composition at 2500 C is UO1.95. The only influence of the sodium vapor is found for the diffusion of UO2 into the thoria of the crucible. Compared with experiments in an atmosphere of pure argon, the diffusion rate is reduced.

  15. Rapid coupling of Antarctic temperature and atmospheric CO2 during deglaciation

    Directory of Open Access Journals (Sweden)

    T. D. van Ommen

    2012-02-01

    Full Text Available Antarctic ice cores provide clear evidence of a close coupling between variations in Antarctic temperature and the atmospheric concentration of CO2 during the glacial/interglacial cycles of the past 800 thousand years. Precise information on the relative timing of the temperature and CO2 changes can assist in refining our understanding of the physical processes involved in this coupling. Here, we focus on the last deglaciation, 19 000 to 11 000 years before present, during which CO2 concentrations increased by ~80 parts per million by volume and Antarctic temperature increased by ~10 °C. Utilising a recently developed proxy for regional Antarctic temperature, derived from five near-coastal ice cores, and two ice core CO2 records with high dating precision, we show that the increase in CO2 lagged the increase in regional Antarctic temperature by only 0–400 years. This new value for the lag, consistent for both CO2 records, implies a faster feedback between temperature and CO2 than the centennial to millennial-scale lags suggested by previous studies.

  16. Qualitative gas temperature distribution in positive DC glow corona using spectral image processing in atmospheric air

    Science.gov (United States)

    Matsumoto, Takao; Inada, Yoichi; Shimizu, Daisuke; Izawa, Yasuji; Nishijima, Kiyoto

    2015-01-01

    An experimental method of determining a qualitative two-dimensional image of the gas temperature in stationary atmospheric nonthermal plasma by spectral image processing was presented. In the experiment, a steady-state glow corona discharge was generated by applying a positive DC voltage to a rod-plane electrode in synthetic air. The changes in the gas temperature distribution due to the amplitude of applied voltage and the ambient gas pressure were investigated. Spectral images of a positive DC glow corona were taken using a gated ICCD camera with ultranarrow band-pass filters, corresponding to the head and tail of a N2 second positive system band (0-2). The qualitative gas temperature was obtained from the emission intensity ratio between the head and tail of the N2 second positive system band (0-2). From the results, we confirmed that the gas temperature and its distribution of a positive DC glow corona increased with increasing applied voltage. In particular, just before the sparkover voltage, a distinctly high temperature region was formed in the positive DC glow at the tip of the rod electrode. In addition, the gas temperature decreased and its distribution spread diffusely with decreasing ambient gas pressure.

  17. Rotational Raman lidar to measure the atmospheric temperature from the ground to 30 km

    Energy Technology Data Exchange (ETDEWEB)

    Nedeljkovic, D.; Hauchecorne, A.; Chanin, M.L. (CNRS, Verrieres le Buisson (France))

    1993-01-01

    The authors describe in this paper a lidar method using the anti-Stokes rotational lines of N[sub 2] and O[sub 2] Raman spectrum to determine the temperature of the atmosphere up to 30 km. The method uses the variation with the temperature of the envelop of the intensities of the backscattered rotational Raman spectrum, or more precisely the variations of the ratio of the intensities at two close-by wavelengths. For each temperature of the gas, the ratio of the fluxes through two narrow and close-by filters takes a definite value directly related to the temperature. The difficulty of eliminating the near-by contribution of the Mie backscattering was solved by doubling the filters to produce a rejection factor of 10[sub +8] at the central wavelength. The validity of the method was illustrated by comparing a number of temperature profiles obtained simultaneously with radiosonde and by this new Raman lidar. The theoretical calculation of the method led to an analytic calibration function which, once adjusted with a radiosonde, can provide the temperature on successive days of measurement in the height range 50 to 25 km.

  18. [Comparative study on the gas temperature of a plasma jet at atmospheric pressure].

    Science.gov (United States)

    Jia, Peng-Ying; Li, Xue-Chen; Yuan, Ning

    2011-08-01

    A plasma jet of a dielectric barrier discharge in coaxial electrode was used to produce jet plasma in flowing work gas (argon mixed with trace nitrogen) at atmospheric pressure. The relation between the plasma length and the gas flow rate was obtained by taking the images of the jet plasma. A high-resolution optical spectrometer was used to collect the optical emission spectrum. The emission spectra of the first negative band of N(2+) (B2 Sigma(u+)-->Chi2 Sigma(g+), 390-391.6 nm) were used to estimate the rotational temperature of the plasma plume by fitting the experimental spectra to the simulated spectra. The gas temperature was investigated by this optical method and results show that the gas temperature increases with increasing the applied voltage. For comparison, a thermometer was used to measure the temperature of the gas emitted from the jet. The results also show that the gas temperature increases with increasing the applied voltage. The gas temperatures obtained by the two methods are consistent. The difference was analyzed.

  19. Combining Abundance/Temperature Retrieval with 3D Atmospheric Circulation Simulations of Hot Jupiters

    Science.gov (United States)

    Heng, Kevin

    2011-09-01

    The atmospheres of hot Jupiters are three-dimensional, non-linear entities and understanding them requires the construction of a hierarchy of models of varying sophistication. Since previous work has either focused on the atmospheric dynamics or implemented multi-band radiative transfer, a reasonable approach is to combine the treatment of 3D dynamics with dual-band radiative transfer, where the assumption is that the stellar irradiation and re-emitted radiation from the exoplanet are at distinct wavelengths. I report on the successful implementation of such a setup and demonstrate how it can be used to compute self-consistent temperature-pressure profiles on both the day and night sides of a hot Jupiter, as well as zonal-wind profiles, circulation cell patterns and the angular/temporal offset of the hotspot from the substellar point. In particular, the hotspot offset should aid us in distinguishing between different types of hot Jupiter atmospheres. Together with N. Madhusudhan, we combine the dual-band simulation technique with the abundance/temperature retrieval method of Madhusudhan & Seager, by empirically constraining a range of values for the broad-band opacities which are consistent with the current observations. The advantage of our novel method is that the range of opacities used improves with time as the observations get better. The ability to thoroughly, efficiently and systematically explore the interplay between atmospheric dynamics, radiation and synthetic spectra is an important step forward, as it prepares us for the theoretical interpretation of exoplanetary spectra which will be obtained by future space-based missions such as JWST and EChO. I acknowledge generous support from the Zwicky Prize Fellowship and the Star and Planet Formation Group (PI: Michael Meyer) at ETH Zurich.

  20. Controlled atmosphere and temperature treatment system to disinfest fruit moth, Carposina sasakii (Lepidoptera: Carposinidae) on apples.

    Science.gov (United States)

    Son, Yerim; Chon, Ikjo; Neven, Lisa; Kim, Yonggyun

    2012-10-01

    Carposina sasakii Matsumura (Lepidoptera: Carposinidae) is a serious pest of apples and peaches in Korea and Japan. Because of its limited distribution, C. sasakii has been identified as a quarantine pest in several countries. The Controlled Atmosphere/Temperature Treatment System (CATTS) was tested as an alternative to methyl bromide fumigation to control C. sasakii in apples. The fifth instar was the most tolerant immature stage to a heat treatment of 44 degrees C for 20 min. When the apples infested with different stages of C. sasakii were treated under CATTS conditions (heating rate of 16 degrees C/h, chamber temperature of 46 degrees C, final core temperature of 44 degrees C under 1% O2/15% CO2 atmosphere), young larvae (first-fourth instars) did not survive after 40 min exposure, but the fifth instars required an exposure of at least 60 min to attain 100% mortality. A partial heat shock protein 90 (hsp90) was cloned and showed inducible expression in response to heat shock at 44 degrees C. CATTS suppressed transcription of the hsp90 gene. Apples did not show any appreciable loss of quality in relation to fruit firmness, sweetness, and decay after a 60 min CATTS treatment. These results suggest that CATTS can be applicable to control C. sasakii in apples.

  1. Influence of a Carrington-like event on the atmospheric chemistry, temperature and dynamics

    Directory of Open Access Journals (Sweden)

    M. Calisto

    2012-06-01

    Full Text Available We have modeled the atmospheric impact of a major solar energetic particle event similar in intensity to what is thought of the Carrington Event of 1–2 September 1859. Ionization rates for the August 1972 solar proton event, which had an energy spectrum comparable to the Carrington Event, were scaled up in proportion to the fluence estimated for both events. We have assumed such an event to take place in the year 2020 in order to investigate the impact on the modern, near future atmosphere. Effects on atmospheric chemistry, temperature and dynamics were investigated using the 3-D Chemistry Climate Model SOCOL v2.0. We find significant responses of NOx, HOx, ozone, temperature and zonal wind. Ozone and NOx have in common an unusually strong and long-lived response to this solar proton event. The model suggests a 3-fold increase of NOx generated in the upper stratosphere lasting until the end of November, and an up to 10-fold increase in upper mesospheric HOx. Due to the NOx and HOx enhancements, ozone reduces by up to 60–80% in the mesosphere during the days after the event, and by up to 20–40% in the middle stratosphere lasting for several months after the event. Total ozone is reduced by up to 20 DU in the Northern Hemisphere and up to 10 DU in the Southern Hemisphere. Free tropospheric and surface air temperatures show a significant cooling of more than 3 K and zonal winds change significantly by 3–5 m s−1 in the UTLS region. In conclusion, a solar proton event, if it took place in the near future with an intensity similar to that ascribed to of the Carrington Event of 1859, must be expected to have a major impact on atmospheric composition throughout the middle atmosphere, resulting in significant and persistent decrease in total ozone.

  2. Influence of a Carrington-like event on the atmospheric chemistry, temperature and dynamics

    Directory of Open Access Journals (Sweden)

    M. Calisto

    2012-09-01

    Full Text Available We have modeled the atmospheric impact of a major solar energetic particle event similar in intensity to what is thought of the Carrington Event of 1–2 September 1859. Ionization rates for the August 1972 solar proton event, which had an energy spectrum comparable to the Carrington Event, were scaled up in proportion to the fluence estimated for both events. We have assumed such an event to take place in the year 2020 in order to investigate the impact on the modern, near future atmosphere. Effects on atmospheric chemistry, temperature and dynamics were investigated using the 3-D Chemistry Climate Model SOCOL v2.0. We find significant responses of NOx, HOx, ozone, temperature and zonal wind. Ozone and NOx have in common an unusually strong and long-lived response to this solar proton event. The model suggests a 3-fold increase of NOx generated in the upper stratosphere lasting until the end of November, and an up to 10-fold increase in upper mesospheric HOx. Due to the NOx and HOx enhancements, ozone reduces by up to 60–80% in the mesosphere during the days after the event, and by up to 20–40% in the middle stratosphere lasting for several months after the event. Total ozone is reduced by up to 20 DU in the Northern Hemisphere and up to 10 DU in the Southern Hemisphere. Free tropospheric and surface air temperatures show a significant cooling of more than 3 K and zonal winds change significantly by 3–5 m s−1 in the UTLS region. In conclusion, a solar proton event, if it took place in the near future with an intensity similar to that ascribed to of the Carrington Event of 1859, must be expected to have a major impact on atmospheric composition throughout the middle atmosphere, resulting in significant and persistent decrease in total ozone.

  3. Multitechnique characterisation of 304L surface states oxidised at high temperature in steam and air atmospheres

    Energy Technology Data Exchange (ETDEWEB)

    Mamede, Anne-Sophie, E-mail: anne-sophie.mamede@ensc-lille.fr [University Lille, CNRS, ENSCL, Centrale Lille, University Artois, UMR 8181 – UCCS – Unité de Catalyse et Chimie du Solide, F-59000 Lille (France); Nuns, Nicolas, E-mail: nicolas.nuns@univ-lille1.fr [University Lille, CNRS, ENSCL, Centrale Lille, University Artois, UMR 8181 – UCCS – Unité de Catalyse et Chimie du Solide, F-59000 Lille (France); Cristol, Anne-Lise, E-mail: anne-lise.cristol@ec-lille.fr [University Lille, CNRS, Centrale Lille, Arts et Métiers Paris Tech, FRE 3723 – LML – Laboratoire de Mécanique de Lille, F-59000 Lille (France); Cantrel, Laurent, E-mail: laurent.cantrel@irsn.fr [Institut de Radioprotection et de Sûreté Nucléaire, PSN-RES, Cadarache, Saint Paul lez Durance, 13115 (France); Laboratoire de Recherche Commun IRSN-CNRS-Lille 1: «Cinétique Chimique, Combustion, Réactivité» (C3R), Cadarache, Saint Paul lez Durance, 13115 (France); Souvi, Sidi, E-mail: sidi.souvi@irsn.fr [Institut de Radioprotection et de Sûreté Nucléaire, PSN-RES, Cadarache, Saint Paul lez Durance, 13115 (France); Laboratoire de Recherche Commun IRSN-CNRS-Lille 1: «Cinétique Chimique, Combustion, Réactivité» (C3R), Cadarache, Saint Paul lez Durance, 13115 (France); and others

    2016-04-30

    Graphical abstract: - Highlights: • Mutitechnique characterisation of oxidised 304L. • Oxidation at high temperature under steam and air conditions of 304L stainless steel. • Chromium and manganese oxides formed in the outer layer. • Oxide profiles differ in air or steam atmosphere. - Abstract: In case of a severe accident occurring in a nuclear reactor, surfaces of the reactor coolant system (RCS), made of stainless steel (304L) rich in Cr (>10%) and Ni (8–12%), are oxidised. Fission products (FPs) are released from melt fuel and flow through the RCS. A part of them is deposited onto surfaces either by vapour condensation or by aerosol deposition mechanisms. To be able to understand the nature of interactions between these FPs and the RCS surfaces, a preliminary step is to characterize the RSC surface states in steam and air atmosphere at high temperatures. Pieces of 304L stainless steel have been treated in a flow reactor at two different temperatures (750 °C and 950 °C) for two different exposition times (24 h and 72 h). After surfaces analysing by a unique combination of surface analysis techniques (XPS, ToF-SIMS and LEIS), for 304L, the results show a deep oxide scale with multi layers and the outer layer is composed of chromium and manganese oxides. Oxide profiles differ in air or steam atmosphere. Fe{sub 2}O{sub 3} oxide is observed but in minor proportion and in all cases no nickel is detected near the surface. Results obtained are discussed and compared with the literature data.

  4. Mechanical characterisation of tungsten–1 wt.% yttrium oxide as a function of temperature and atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Palacios, T.; Jiménez, A. [Materials Science Department, Technical University of Madrid, E.T.S. de Ingenieros de Caminos, Canales y Puertos, C/Profesor Aranguren s/n, 28040 Madrid (Spain); Muñóz, A.; Monge, M.A.; Ballesteros, C. [Departamento de Física, Universidad Carlos III de Madrid, Leganés (Spain); Pastor, J.Y. [Materials Science Department, Technical University of Madrid, E.T.S. de Ingenieros de Caminos, Canales y Puertos, C/Profesor Aranguren s/n, 28040 Madrid (Spain)

    2014-11-15

    This study evaluates the mechanical behaviour of an Y{sub 2}O{sub 3}-dispersed tungsten (W) alloy and compares it to a pure W reference material. Both materials were processed via mechanical alloying (MA) and subsequent hot isostatic pressing (HIP). We performed non-standard three-point bending (TPB) tests in both an oxidising atmosphere and vacuum across a temperature range from 77 K, obtained via immersion in liquid nitrogen, to 1473 K to determine the mechanical strength, yield strength and fracture toughness. This research aims to evaluate how the mechanical behaviour of the alloy is affected by oxides formed within the material at high temperatures, primarily from 873 K, when the materials undergo a massive thermal degradation. The results indicate that the alloy is brittle to a high temperature (1473 K) under both atmospheres and that the mechanical properties degrade significantly above 873 K. We also used Vickers microhardness tests and the dynamic modulus by impulse excitation technique (IET) to determine the elastic modulus at room temperature. Moreover, we performed nanoindentation tests to determine the effect of size on the hardness and elastic modulus; however, no significant differences were found. Additionally, we calculated the relative density of the samples to assess the porosity of the alloy. Finally, we analysed the microstructure and fracture surfaces of the tested materials via field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). In this way, the relationship between the macroscopic mechanical properties and micromechanisms of failure could be determined based on the temperature and oxides formed.

  5. Mechanical characterisation of tungsten-1 wt.% yttrium oxide as a function of temperature and atmosphere

    Science.gov (United States)

    Palacios, T.; Jiménez, A.; Muñóz, A.; Monge, M. A.; Ballesteros, C.; Pastor, J. Y.

    2014-11-01

    This study evaluates the mechanical behaviour of an Y2O3-dispersed tungsten (W) alloy and compares it to a pure W reference material. Both materials were processed via mechanical alloying (MA) and subsequent hot isostatic pressing (HIP). We performed non-standard three-point bending (TPB) tests in both an oxidising atmosphere and vacuum across a temperature range from 77 K, obtained via immersion in liquid nitrogen, to 1473 K to determine the mechanical strength, yield strength and fracture toughness. This research aims to evaluate how the mechanical behaviour of the alloy is affected by oxides formed within the material at high temperatures, primarily from 873 K, when the materials undergo a massive thermal degradation. The results indicate that the alloy is brittle to a high temperature (1473 K) under both atmospheres and that the mechanical properties degrade significantly above 873 K. We also used Vickers microhardness tests and the dynamic modulus by impulse excitation technique (IET) to determine the elastic modulus at room temperature. Moreover, we performed nanoindentation tests to determine the effect of size on the hardness and elastic modulus; however, no significant differences were found. Additionally, we calculated the relative density of the samples to assess the porosity of the alloy. Finally, we analysed the microstructure and fracture surfaces of the tested materials via field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). In this way, the relationship between the macroscopic mechanical properties and micromechanisms of failure could be determined based on the temperature and oxides formed.

  6. Electron Density and Temperature Measurements, and Abundance Anomalies in the Solar Atmosphere

    Indian Academy of Sciences (India)

    Anita Mohan; Bhola N. Dwivedi; Enrico Landi

    2000-09-01

    Using spectra obtained from the SUMER (Solar Ultraviolet Measurements of Emitted Radiation) spectrograph on the spacecraft SOHO (Solar and Heliospheric Observatory), we investigate the height dependence of electron density, temperature and abundance anomalies in the solar atmosphere. In particular, we present the behaviour of the solar FIP effect (the abundance enhancement of elements with first ionization potential < 10 eV in the corona with respect to photospheric values) with height above an active region observed at the solar limb, with emphasis on the so-called transition region lines.

  7. Can an Atmospherically Forced Ocean Model Accurately Simulate Sea Surface Temperature During ENSO Events?

    Science.gov (United States)

    2010-01-01

    Mateger, Herley E. Hurlburt, Alan J. Walloraft H a inleficed to offer this paper to the (Nanm of Confe ounce) (Dafe. P/ace and Classification of...temperature during ENSO events? By A. BIROL KARA.HARLEY E. HURLBURT*. CHARLIE N. BARRON. ALAN J. WALLCRAFT andE. JOSEPH METZGER, Naval Research...Quantifying SST errors from an OGCM in relation to atmospheric forcing variables. Ocean Modell. 29, 43-57. Urge. W. G., McWilliams , J. C. and Doney. S. C

  8. Temperature and precipitation extremes in century-long gridded observations, reanalyses, and atmospheric model simulations

    Science.gov (United States)

    Donat, Markus G.; Alexander, Lisa V.; Herold, Nicholas; Dittus, Andrea J.

    2016-10-01

    Knowledge about long-term changes in climate extremes is vital to better understand multidecadal climate variability and long-term changes and to place today's extreme events in a historical context. While global changes in temperature and precipitation extremes since the midtwentieth century are well studied, knowledge about century-scale changes is limited. This paper analyses a range of largely independent observations-based data sets covering 1901-2010 for long-term changes and interannual variability in daily scale temperature and precipitation extremes. We compare across data sets for consistency to ascertain our confidence in century-scale changes in extremes. We find consistent warming trends in temperature extremes globally and in most land areas over the past century. For precipitation extremes we find global tendencies toward more intense rainfall throughout much of the twentieth century; however, local changes are spatially more variable. While global time series of the different data sets agree well after about 1950, they often show different changes during the first half of the twentieth century. In regions with good observational coverage, gridded observations and reanalyses agree well throughout the entire past century. Simulations with an atmospheric model suggest that ocean temperatures and sea ice may explain up to about 50% of interannual variability in the global average of temperature extremes, and about 15% in the global average of moderate precipitation extremes, but local correlations are mostly significant only in low latitudes.

  9. Study of the Temperature Turbulences Effect upon Optical Beam in Atmospheric Optical Communication

    Directory of Open Access Journals (Sweden)

    F. Dvorak

    2011-09-01

    Full Text Available The paper deals with the study of the effect of temperature turbulences upon the optical beam. The polarization parameters of optical radiation sources and different optical beam states of polarization have been investigated. The obtained polarization parameters are projected on the Poincare sphere by means of Stokes vectors. The optical power distribution curves of optical beams are processed into diagrams. The horizontal and vertical components of linearly and circularly polarized optical beams have been studied. The turbulence flux has vertical direction and the optical beam is propagating through an atmosphere environment with three different states of turbulence. The evaluation of the obtained data was done by means of variance and correlation functions computing. Different rates of effect of temperature turbulences upon horizontal and vertical components were found. To reduce the rate of effect the advantage of an optical beam with circular polarization has been proposed.

  10. Flexible sample environment for high resolution neutron imaging at high temperatures in controlled atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Makowska, Małgorzata G., E-mail: malg@dtu.dk [Department of Energy Conversion and Storage, Technical University of Denmark, Roskilde 4000 (Denmark); European Spallation Source ESS AB, P.O. Box 176, SE-221 00 Lund (Sweden); Theil Kuhn, Luise; Cleemann, Lars N. [Department of Energy Conversion and Storage, Technical University of Denmark, Roskilde 4000 (Denmark); Lauridsen, Erik M. [Xnovo Technology ApS, Galoche Alle 15, Køge 4600 (Denmark); Bilheux, Hassina Z.; Molaison, Jamie J.; Santodonato, Louis J. [Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Tremsin, Anton S. [Space Sciences Laboratory, University of California at Berkeley, Berkeley, California 94720 (United States); Grosse, Mirco [Institute for Applied Material Research, Karlsruhe Institute of Technology, Karlsruhe DE-76021 (Germany); Morgano, Manuel [Paul Scherrer Institut, Villigen PSI CH-5232 (Switzerland); Kabra, Saurabh [ISIS, Rutherford Appleton Laboratory, Chilton OX11 0QX (United Kingdom); Strobl, Markus [European Spallation Source ESS AB, P.O. Box 176, SE-221 00 Lund (Sweden)

    2015-12-15

    High material penetration by neutrons allows for experiments using sophisticated sample environments providing complex conditions. Thus, neutron imaging holds potential for performing in situ nondestructive measurements on large samples or even full technological systems, which are not possible with any other technique. This paper presents a new sample environment for in situ high resolution neutron imaging experiments at temperatures from room temperature up to 1100 °C and/or using controllable flow of reactive atmospheres. The design also offers the possibility to directly combine imaging with diffraction measurements. Design, special features, and specification of the furnace are described. In addition, examples of experiments successfully performed at various neutron facilities with the furnace, as well as examples of possible applications are presented. This covers a broad field of research from fundamental to technological investigations of various types of materials and components.

  11. Purification of Single Wall Carbon Nanotubes as a Function of UV Wavelength, Atmosphere, and Temperature

    Energy Technology Data Exchange (ETDEWEB)

    Kurst, K. E.; Dillon, A. C.; Yang, S.; Lehman, J. H.

    2008-01-01

    We investigate the purification of as-prepared single wall carbon nanotubes (SWCNTs) by exposure to pulsed 193 and 248 nm laser light, as well as lamp wavelengths of 254 and 185 nm. Raman spectroscopy before and after laser exposure indicates the removal of non-nanotube material without modification of the distribution of tube diameter for material exposed to a 248 nm laser, while 193 nm laser light does not selectively oxidize carbon impurities. The mechanism of purification is further considered in the context of atmosphere (oxygen, ozone, nitrogen or partial vacuum) and temperature (measured average and calculated maximum). A mathematical model for pulsed laser heating is used to estimate the maximum temperature achieved during laser excitation. We attribute the purification of nanotube samples to photophysical interactions of the pulsed 248 nm photons in resonance with sp{sup 2} carbon.

  12. Procyon: Constraining Its Temperature Structure with High-Precision Interferometry and 3-D Model Atmospheres

    Science.gov (United States)

    Aufdenberg, J. P.; Ludwig, H.-G.; Kervella, P.

    2004-12-01

    We have fit synthetic visibilities from 3-D (CO5BOLD + PHOENIX) and 1-D (PHOENIX, ATLAS12) model stellar atmospheres for Procyon (F5 IV) to high-precision interferometric data from the VINCI instrument at the VLT Interferometer (K-band) and from the Mark III interferometer (500 nm, 800 nm). These data provide a test of theoretical wavelength-dependent limb-darkening predictions, and therefore Procyon's atmospheric temperature structure. Earlier work (Allende Prieto et al. 2002 ApJ 567, 544) has shown that the temperature structure from a spatially and temporally averaged 3-D hydrodynamical model produces significantly less limb darkening at 500 nm relative to the temperature structure from a 1-D MARCS model atmosphere which uses a mixing-length approximation for convective flux transport. Our direct fits to the interferometric data confirm this prediction, however we find that not all 1-D models fail to reproduce the observations. The key to matching the interferometric data is a shallower temperature gradient than provided by the standard 1-D mixing-length approximation. We find that in addition to our best fitting 3-D hydrodynamical model, a 1-D ATLAS12 model, with an additional free parameter for ``approximate overshooting'', provides the required temperature gradient. We estimate that an interferometric precision better than 0.1% will be required to distinguish between the 3-D model and the ATLAS12 model. This overshooting approximation has been shown to match Solar limb-darkening observations reasonably well (Castelli et al 1997 A&A 324, 432), however published work since using Strömgren photometry of solar-type stars has cast doubt on the importance of overshooting. We have also compared synthetic spectral energy distributions for Procyon to ultraviolet, optical and near-infrared spectrophotometry and find differences from comparisons to Strömgren photometry alone. This work was performed in part contract with the Jet Propulsion Laboratory (JPL) funded by

  13. The THS Experiment: Simulating Titans Atmospheric Chemistry at Low Temperature (200K)

    Science.gov (United States)

    Sciamma-O'Brien, Ella; Upton, Kathleen; Beauchamp, Jack L.; Salama, Farid; Contreras, Cesar Sanchez; Bejaoui, Salma; Foing, Bernard; Pascale, Ehrenfreund

    2015-01-01

    In Titan's atmosphere, composed mainly of N2 (95-98%) and CH4 (2-5%), a complex chemistry occurs at low temperature, and leads to the production of heavy organic molecules and subsequently solid aerosols. Here, we used the Titan Haze Simulation (THS) experiment, an experimental setup developed at the NASA Ames COSmIC simulation facility to study Titan's atmospheric chemistry at low temperature. In the THS, the chemistry is simulated by plasma in the stream of a supersonic expansion. With this unique design, the gas is cooled to Titan-like temperature ( approximately 150K) before inducing the chemistry by plasma, and remains at low temperature in the plasma discharge (approximately 200K). Different N2-CH4-based gas mixtures can be injected in the plasma, with or without the addition of heavier precursors present as trace elements on Titan, in order to monitor the evolution of the chemical growth. Both the gas- and solid phase products resulting from the plasma-induced chemistry can be monitored and analyzed using a combination of complementary in situ and ex situ diagnostics. A recent mass spectrometry[1] study of the gas phase has demonstrated that the THS is a unique tool to probe the first and intermediate steps of Titan's atmospheric chemistry at Titan-like temperature. In particular, the mass spectra obtained in a N2-CH4-C2H2-C6H6 mixture are relevant for comparison to Cassini's CAPS-IBS instrument. The results of a complementary study of the solid phase are consistent with the chemical growth evolution observed in the gas phase. Grains and aggregates form in the gas phase and can be jet deposited on various substrates for ex situ analysis. Scanning Electron Microscopy images show that more complex mixtures produce larger aggregates. A mass spectrometry analysis of the solid phase has detected the presence of aminoacetonitrile, a precursor of glycine, in the THS aerosols. X-ray Absorption Near Edge Structure (XANES) measurements also show the presence of imine

  14. The THS: Simulating Titan’s atmospheric chemistry at low temperature

    Science.gov (United States)

    Sciamma-O'Brien, Ella; Upton, Kathleen T.; Beauchamp, Jack L.; Salama, Farid

    2015-08-01

    In Titan’s atmosphere, composed mainly of N2 (95-98%) and CH4 (2-5%), a complex chemistry occurs at low temperature, and leads to the production of heavy organic molecules and subsequently solid aerosols. Here, we used the Titan Haze Simulation (THS) experiment, an experimental setup developed at the NASA Ames COSmIC simulation facility to study Titan’s atmospheric chemistry at low temperature. In the THS, the chemistry is simulated by plasma in the stream of a supersonic expansion. With this unique design, the gas is cooled to Titan-like temperature (~150K) before inducing the chemistry by plasma, and remains at low temperature in the plasma discharge (~200K). Different N2-CH4-based gas mixtures can be injected in the plasma, with or without the addition of heavier precursors present as trace elements on Titan, in order to monitor the evolution of the chemical growth. Both the gas- and solid phase products resulting from the plasma-induced chemistry can be monitored and analyzed using a combination of complementary in situ and ex situ diagnostics.A recent mass spectrometry study of the gas phase has demonstrated that the THS is a unique tool to probe the first and intermediate steps of Titan’s atmospheric chemistry at Titan-like temperature. In particular, the mass spectra obtained in a N2-CH4-C2H2-C6H6 mixture are relevant for comparison to Cassini’s CAPS-IBS instrument. The results of a complementary study of the solid phase are consistent with the chemical growth evolution observed in the gas phase. Grains and aggregates form in the gas phase and can be jet deposited on various substrates for ex situ analysis. Scanning Electron Microscopy images show that more complex mixtures produce larger aggregates. A DART mass spectrometry analysis of the solid phase has detected the presence of aminoacetonitrile, a precursor of glycine, in the THS aerosols. X-ray Absorption Near Edge Structure (XANES) measurements also show the presence of imine and nitrile

  15. Synergy between middle infrared and millimeter-wave limb sounding of atmospheric temperature and minor constituents

    Science.gov (United States)

    Cortesi, Ugo; Del Bianco, Samuele; Ceccherini, Simone; Gai, Marco; Dinelli, Bianca Maria; Castelli, Elisa; Oelhaf, Hermann; Woiwode, Wolfgang; Höpfner, Michael; Gerber, Daniel

    2016-05-01

    Synergistic exploitation of redundant and complementary information from independent observations of the same target remains a major issue in atmospheric remote sounding and increasing attention is devoted to investigate optimized or innovative methods for the combination of two or more measured data sets. This paper focuses on the synergy between middle infrared and millimeter-wave limb sounding measurements of atmospheric composition and temperature and reports the results of a study conducted as part of the preparatory activities of the PREMIER (Process Exploration through Measurements of Infrared and millimeter-wave Emitted Radiation) mission candidate to the Core Missions of the European Space Agency (ESA) Earth Explorer 7. The activity was based on data acquired by the MIPAS-STR (Michelson Interferometer for Passive Atmospheric Sounding - STRatospheric aircraft) and MARSCHALS (Millimetre-wave Airborne Receivers for Spectroscopic CHaracterisation in Atmospheric Limb Sounding) instruments on-board the high-altitude research aircraft M-55 Geophysica during the flight of the PremierEx (PREMIER Experiment) campaign on 10 March 2010 from Kiruna, Sweden, for observation of the Arctic upper troposphere and lower stratosphere. The cloud coverage observed along the flight provided representative test cases to evaluate the synergy in three different scenarios: low clouds in the first part, no clouds in the central part and high tropospheric clouds at the end. The calculation of synergistic profiles of four atmospheric targets (i.e., O3, HNO3, H2O and temperature) was performed using a posteriori combination of individual retrieved profiles, i.e., Level 2 (L2) data rather than simultaneous inversion of observed radiances, i.e., Level 1 (L1) data. An innovative method of data fusion, based on the Measurement Space Solution (MSS) was applied along with the standard approach of inversion of MARSCHALS spectral radiances using MIPAS-STR retrieval products as a priori

  16. Climate change scenarios of extreme temperatures and atmospheric humidity for Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Tejeda-Martinez, A. [Departamento de Ciencias Atmosfericas, Universidad Veracruzana, Xalapa, Veracruz (Mexico)]. E-mail: atejeda@uv.mx; Conde-Alvarez, C. [Centro de Ciencias de la Atmosfera, Universidad Nacional Autonoma de Mexico, Mexico, D.F. (Mexico); Valencia-Treviso, L.E. [Departamento de Ciencias Atmosfericas, Universidad Veracruzana, Xalapa, Veracruz (Mexico)

    2008-10-15

    The following study explores climatic change scenarios of extreme temperature and atmospheric humidity for the 2020 and 2050 decades. They were created for Mexico through the GFDLR30, ECHAM4 and HadCM2 general circulation models. Base scenario conditions were associated with the normal climatological conditions for the period 1961-1990, with a database of 50 surface observatories. It was necessary to empirically estimate the missing data in approximately half of the pressure measurements. For the period 1961-1990, statistical models of the monthly means of maximum and minimum temperatures and atmospheric humidity (relative and specific) were obtained from the observed data of temperature, solar radiation and precipitation. Based on the simulations of the GFDLR30, ECHAM4 and HADCM2 models, a future scenario of monthly means of maximum and minimum temperatures and humidity in climatic change conditions was created. The results shown are for the representative months of winter (January) and summer (July). [Spanish] En este articulo se presentan escenarios de cambio climatico referidos a temperaturas extremas y humedad atmosferica para las decadas de 2020 y 2050. Fueron generados para Mexico a partir de los modelos de circulacion general GFDLR30, ECHAM4 y HADCM2. El escenario base corresponde a las normales climatologicas del periodo 1961-1990 para 50 observatorios de superficie. Para la mitad de ellos fue necesario estimar empiricamente la presion atmosferica a partir de la altitud y para la totalidad se obtuvieron modelos estadisticos de los promedios mensuales de temperaturas maxima y minima asi como de humedad atmosferica (relativa y especifica). Esos modelos estadisticos, combinados con las salidas de los modelos de circulacion general mencionados, produjeron escenarios futuros de medias mensuales de temperaturas extremas y de humedad bajo condiciones de cambio climatico. Se mostraran los resultados para un mes representativo del invierno (enero) y otro del verano

  17. Multidecadal changes in the relationship between extreme temperature events in Uruguay and the general atmospheric circulation

    Energy Technology Data Exchange (ETDEWEB)

    Renom, Madeleine; Barreiro, Marcelo [Universidad de la Republica, Unidad de Ciencias de la Atmosfera, Instituto de Fisica, Facultad de Ciencias, Montevideo (Uruguay); Rusticucci, Matilde [Universidad de Buenos Aires, Departamento de Ciencias de la Atmosfera y los Oceanos, Facultad de Ciencias Exactas y Naturales, Buenos Aires (Argentina)

    2011-12-15

    We analyze changes in the relationship between extreme temperature events and the large scale atmospheric circulation before and after the 1976 climate shift. To do so we first constructed a set of two temperature indices that describe the occurrence of warm nights (TN90) and cold nights (TN10) based on a long daily observed minimum temperature database that spans the period 1946-2005, and then divided the period into two subperiods of 30 years each (1946-1975 and 1976-2005). We focus on summer (TN10) and winter (TN90) seasons. During austral summer before 1976 the interannual variability of cold nights was characterized by a negative phase of the Southern Annular Mode (SAM) with a cyclonic anomaly centered off Uruguay that favoured the entrance of cold air from the south. After 1976 cold nights are associated not with the SAM, but with an isolated vortex at upper levels over South Eastern South America. During austral winter before 1976, the El Nino phenomenon dominated the interannual variability of warm nights through an increase in the northerly warm flow into Uruguay. However, after 1976 the El Nino connection weakened and the variability of warm nights is dominated by a barotropic anticyclonic anomaly located in the South Atlantic and a low pressure center over South America. This configuration also strengthens the northward flow of warm air into Uruguay. Our results suggest that changes in El Nino evolution after 1976 may have played a role in altering the relationship between temperature extreme events in Uruguay and the atmospheric circulation. (orig.)

  18. Organic particulate material levels in the atmosphere: conditions favoring sensitivity to varying relative humidity and temperature.

    Science.gov (United States)

    Pankow, James F

    2010-04-13

    This study examines the sensitivity in predicted levels of atmospheric organic particulate matter (M(o), microg m(-3)) as those levels may potentially be affected by changes in relative humidity and temperature. In a given system, for each partitioning compound, f(g) and f(p) represent the gaseous and particulate fractions (f(g) + f(p) = 1). Sensitivity in the M(o) levels becomes dampened as the compounds contributing significantly to M(o) are increasingly found in the particle phase (f(p) --> 1). Thus, although local maxima in sensitivity can be encountered as M(o) levels increase, because as M(o) increases each f(p) --> 1, then increasing M(o) levels generally tend to reduce sensitivity in M(o) levels to changes in relative humidity and temperature. Experiments designed to elucidate the potential magnitudes of the effects of relative humidity and temperature on M(o) levels must be carried out at M(o) levels that are relevant for the ambient atmosphere: The f(p) values for the important partitioning compounds must not be elevated above ambient-relevant values. Systems in which M(o) levels are low (e.g., 1-2 microg m(-3)) and/or composed of unaged secondary organic aerosol are the ones most likely to show sensitivity to changing relative humidity and temperature. Results from two published chamber studies are examined in the above regard: [Warren B, et al. (2009) Atmos Environ 43:1789-1795] and [Prisle NL, et al. (2010) Geophys Res Lett 37:L01802].

  19. Multitechnique characterisation of 304L surface states oxidised at high temperature in steam and air atmospheres

    Science.gov (United States)

    Mamede, Anne-Sophie; Nuns, Nicolas; Cristol, Anne-Lise; Cantrel, Laurent; Souvi, Sidi; Cristol, Sylvain; Paul, Jean-François

    2016-04-01

    In case of a severe accident occurring in a nuclear reactor, surfaces of the reactor coolant system (RCS), made of stainless steel (304L) rich in Cr (>10%) and Ni (8-12%), are oxidised. Fission products (FPs) are released from melt fuel and flow through the RCS. A part of them is deposited onto surfaces either by vapour condensation or by aerosol deposition mechanisms. To be able to understand the nature of interactions between these FPs and the RCS surfaces, a preliminary step is to characterize the RSC surface states in steam and air atmosphere at high temperatures. Pieces of 304L stainless steel have been treated in a flow reactor at two different temperatures (750 °C and 950 °C) for two different exposition times (24 h and 72 h). After surfaces analysing by a unique combination of surface analysis techniques (XPS, ToF-SIMS and LEIS), for 304L, the results show a deep oxide scale with multi layers and the outer layer is composed of chromium and manganese oxides. Oxide profiles differ in air or steam atmosphere. Fe2O3 oxide is observed but in minor proportion and in all cases no nickel is detected near the surface. Results obtained are discussed and compared with the literature data.

  20. Manganese oxide phases and morphologies: A study on calcination temperature and atmospheric dependence

    Directory of Open Access Journals (Sweden)

    Matthias Augustin

    2015-01-01

    Full Text Available Manganese oxides are one of the most important groups of materials in energy storage science. In order to fully leverage their application potential, precise control of their properties such as particle size, surface area and Mnx+ oxidation state is required. Here, Mn3O4 and Mn5O8 nanoparticles as well as mesoporous α-Mn2O3 particles were synthesized by calcination of Mn(II glycolate nanoparticles obtained through an economical route based on a polyol synthesis. The preparation of the different manganese oxides via one route facilitates assigning actual structure–property relationships. The oxidation process related to the different MnOx species was observed by in situ X-ray diffraction (XRD measurements showing time- and temperature-dependent phase transformations occurring during oxidation of the Mn(II glycolate precursor to α-Mn2O3 via Mn3O4 and Mn5O8 in O2 atmosphere. Detailed structural and morphological investigations using transmission electron microscopy (TEM and powder XRD revealed the dependence of the lattice constants and particle sizes of the MnOx species on the calcination temperature and the presence of an oxidizing or neutral atmosphere. Furthermore, to demonstrate the application potential of the synthesized MnOx species, we studied their catalytic activity for the oxygen reduction reaction in aprotic media. Linear sweep voltammetry revealed the best performance for the mesoporous α-Mn2O3 species.

  1. High temperature corrosion in chloridizing atmospheres: development of material quasi-stability diagrams and coatings

    Energy Technology Data Exchange (ETDEWEB)

    Doublet, S.; Schuetze, M. [Karl-Winnacker-Institut der DECHEMA e.V., Theodor-Heuss-Allee 25, D-60486 Frankfurt am Main (Germany)

    2004-07-01

    Chlorine gas is widely encountered in chemical industries, e. g. in waste incinerators and plastic/polymer decomposition mills. The presence of chlorine may significantly reduce the life-time of the components. Although metallic materials have been widely used under such conditions there is still a need for data on the role of the different alloying elements in commercial alloys. The purpose of this work is to produce a clear picture of which alloying elements play a detrimental role and which elements are beneficial. These results can be used as a tool for general assessment of metallic alloys with regard to their performance in chloridizing high temperature environments. A previous study has already been performed in oxidizing-chloridizing atmospheres and led to the elaboration of material quasi-stability diagrams. As a follow-up the present work has been performed in reducing-chloridizing atmospheres in order to validate these diagrams at low partial pressures of oxygen. The behaviour of 9 commercial materials where the content of the major alloying elements was varied in a systematic manner was investigated in reducing-chloridizing atmospheres (in Ar containing up to 2 vol.% Cl{sub 2} and down to 1 ppm O{sub 2}) at 800 deg. C. As the thermodynamical approach to corrosion in such atmospheres could not explain all the phenomena which occur, kinetics calculations i.e. diffusion calculations were carried out. Pack cementation and High Velocity Oxy-Fuel (HVOF) coatings were also developed from the best alloying elements previously found by the calculations and the corrosion experiments. Corrosion tests on the coated materials were then performed in the same conditions as the commercial alloys. (authors)

  2. Electronic ground state OH(X) radical in a low-temperature atmospheric pressure plasma jet

    Science.gov (United States)

    Fuh, Che A.; Clark, Shane M.; Wu, Wei; Wang, Chuji

    2016-10-01

    The wide applicability of atmospheric pressure plasma jets in biomedicine stems from the presence of reactive nitrogen and oxygen species generated in these plasma jets. Knowing the absolute concentration of these reactive species is of utmost importance as it is critical, along with the particle flux obtained from the plasma feed gas flow rate to ensure that the correct dosage is applied during applications. In this study, we investigate and report the ground state OH(X) number density acquired using cavity ringdown spectroscopy, along the propagation axis (z-axis) of a cold atmospheric pressure helium plasma plume. The jet was generated by a repetitively pulsed mono-polar square wave of duration 1 μs running at a frequency of 9.9 kHz. The voltage supplied was 6.5 kV with the helium flow rate fixed at 3.6 standard liters per minute. The rotational and vibrational temperatures are simulated from the second positive system of nitrogen, N 2(C3πu-B3πg) , with the rotational temperature being spatially constant at 300 K along the propagation axis of the atmospheric pressure plasma jet while the vibrational temperature is 3620 K at the beginning of the plume and is observed to decrease downstream. The OH(A) emission intensity obtained via optical emission spectroscopy was observed to decrease downstream of the plasma jet. The OH(X) number density along the propagation axis was initially 2.2 × 1013 molecules cm-3 before increasing to a peak value of 2.4 × 1013 molecules cm-3, from which the number density was observed to decrease to 2.2 × 1013 molecules cm-3 downstream of the plasma jet. The total OH(A, X) in the plasma jet remained relatively constant along the propagation axis of the plasma jet before falling off at the tip of the jet. The increase in vibrational temperature downstream and the simultaneous measurements of both the excited state OH(A) and the ground state OH(X) reported in this study provide insights into the formation and consumption of this

  3. Assessment of Mars Atmospheric Temperature Retrievals from the Thermal Emission Spectrometer Radiances

    Science.gov (United States)

    Hoffman, Matthew J.; Eluszkiewicz, Janusz; Weisenstein, Deborah; Uymin, Gennady; Moncet, Jean-Luc

    2012-01-01

    Motivated by the needs of Mars data assimilation. particularly quantification of measurement errors and generation of averaging kernels. we have evaluated atmospheric temperature retrievals from Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES) radiances. Multiple sets of retrievals have been considered in this study; (1) retrievals available from the Planetary Data System (PDS), (2) retrievals based on variants of the retrieval algorithm used to generate the PDS retrievals, and (3) retrievals produced using the Mars 1-Dimensional Retrieval (M1R) algorithm based on the Optimal Spectral Sampling (OSS ) forward model. The retrieved temperature profiles are compared to the MGS Radio Science (RS) temperature profiles. For the samples tested, the M1R temperature profiles can be made to agree within 2 K with the RS temperature profiles, but only after tuning the prior and error statistics. Use of a global prior that does not take into account the seasonal dependence leads errors of up 6 K. In polar samples. errors relative to the RS temperature profiles are even larger. In these samples, the PDS temperature profiles also exhibit a poor fit with RS temperatures. This fit is worse than reported in previous studies, indicating that the lack of fit is due to a bias correction to TES radiances implemented after 2004. To explain the differences between the PDS and Ml R temperatures, the algorithms are compared directly, with the OSS forward model inserted into the PDS algorithm. Factors such as the filtering parameter, the use of linear versus nonlinear constrained inversion, and the choice of the forward model, are found to contribute heavily to the differences in the temperature profiles retrieved in the polar regions, resulting in uncertainties of up to 6 K. Even outside the poles, changes in the a priori statistics result in different profile shapes which all fit the radiances within the specified error. The importance of the a priori statistics prevents

  4. Time and frequency response of a resistance-wire aircraft atmospheric temperature sensor

    Science.gov (United States)

    Payne, G. A.; Friehe, C. A.; Edwards, D. K.

    1994-04-01

    The heat transfer characteristics of an aircraft-mounted resistance-wire atmospheric temperature sensor are modeled to determine the time and frequency responses. The sensor element (Rosemount 102E4AL) consists of a 25-micron-diameter platinum wire wound around a cruciform mica support with approximately 143 diameters of wire between contacts with the mica. A longitudinally distributed, radially lumped capacitance model provided for the convective heat transfer to the wire and the transient heat conduction along it. Similarly, the temperature gradient across the thin dimension of the mica support was neglected, and a radially distributed model provided for the convective heat transfer to the mica and the transient conduction within it. The two solutions are coupled by the boundary conditions at the wire-mica contact. The equations were solved to produce the temperature distribution along the wire and in the mica support as a function of the frequency of a free-stream sinusoidal temperature fluctuation. The frequency response transfer function was determined and fit to a two-time-constant transfer function by regression analysis. The two-time-constant model fits the general solution very well. The small (fast response) time constant is essentially determined by the wire itself. The larger (slow response) time constant is due to conduction into and out of the mica supports. The model predicts that the effects of the mica supports are important for frequencies greater than about 0.1 Hz. The responses to five different temperature waveform inputs (sinusoid, step, pulse, ramp, and ramp level) are derived using the two-time-constant model with Laplace transform techniques for both infinite-length wire (no mica support effects) and the finite-length wire of the 102 probe. The actual temperature signals are distorted by the larger time constant of the mica supports, especially for the pulse and ramp inputs that are typical of aircraft measurements of thermals and

  5. A novel atmospheric Temperature Sounding Unit: system design and performance analyses

    Science.gov (United States)

    Chakraborty, Prantik; Gupta, Priyanka; Dave, Dilip B.; Desai, Nilesh M.; Misra, Tapan

    2016-05-01

    This paper reports the development of a millimeter-wave space-borne atmospheric Temperature Sounding Unit (TSU) in Indian Space Research Organization (ISRO). This is ISRO's first leap towards millimeter-wave technology. The sensor has several new accomplishments to its credit which include among others, the philosophy of sounding channel selection, the new assortment of temperature sounding channels, simultaneous observation of both polarizations of all channels, compact dual-band scanning Gregorian reflector antenna, indigenously developed black-body target for in-orbit calibration, in-house developed millimeter-wave RF front-end and pre-detection automatic gain control method. The prime feature of this instrument is its unique set of channels which can profile the earth's atmosphere from surface to 40 km altitude with vertical resolution ranging from less than a km near surface to +/-2.5 km at 30km altitude. The channels are predominantly off-resonant frequencies in the 50―60 GHz O2 absorption spectrum which offer near-uniform attenuation and hence more channel-bandwidth and better temperature sensitivity and yet have adequate overlap of their weighting functions to achieve the desired vertical resolution. These channels are different and have fewer bands from what has been flown in all earlier sounding missions worldwide e.g. AMSU-A, SSMIS, ATMS etc. The TSU radiometer has been characterized thoroughly using ingenious methods such as low-power active RF energizing along with frequency sweep. This is a compact, low-mass, low-power instrument and has been configured for the ISRO mini-satellite (IMS-2) bus. The flight model with improved hardware performance is being built and a suitable opportunity of flying it is being explored.

  6. SHORT-TERM EXPOSURE TO ATMOSPHERIC AMMONIA DOES NOT AFFECT LOW-TEMPERATURE HARDENING OF WINTER-WHEAT

    NARCIS (Netherlands)

    CLEMENT, JMAM; VENEMA, JH; VANHASSELT, PR

    1995-01-01

    The effect of atmospheric NH3 on low-temperature hardening of winter wheat (Triticum aestivum L. cv. Urban) was investigated. Growth and photosynthesis were stimulated by ammonia exposure. After a 14 d exposure at moderate temperatures (day/night 18.5/16 degrees C) total nitrogen content was enhance

  7. Studying temperature and dynamical variations in the extratropical boreal atmosphere in the 2012-2013 winter

    Science.gov (United States)

    Vargin, Pavel; Medvedeva, Irina

    A major Sudden Stratospheric Warming (SSW) event in early January 2013 led to a large increase in the polar stratospheric temperature (up to 60 K at 44 km height), zonal circulation reversal, split of the stratospheric polar vortex (wavenumber 2 type of SSW), and effected temperature and dynamics of the mesosphere - lower thermosphere. We analyzed the SSW-related variations in thermo-dynamical parameters of the atmosphere within a height range from the troposphere to the lower thermosphere, using reanalysis data and data of ground-based spectrometric and satellite observations. Wave activity in the extratropical troposphere and stratosphere was studied using calculated three-day means of the three-dimensional Plumb fluxes. We revealed amplification in activity of planetary waves propagating from the troposphere to the stratosphere over Eastern Siberia - China two weeks prior to that SSW. The eastward propagating Rossby wave-trains observed in the upper troposphere one week before the SSW might have contributed to enhancement of the tropospheric anticyclone over the north-eastern Atlantic that, in turn, led to the splitting of the stratospheric polar vortex during the SSW. To investigate the SSW manifestations in the middle and upper atmosphere over Eastern Siberia, the data of ground-based spectrographic measurements of the OH (834.0 nm, band (6-2)) and O2 (864.5 nm, band (0-1)) emissions obtained at the Geophysical Observatory of the Institute of Solar-Terrestrial Physics (52N, 103E, near Irkutsk) and MLS Aura satellite data were used. An increase in the activity of planetary waves in the 2nd half of November and December 2012 was revealed. During the SSW evolution, an increase in temperature of the stratosphere ( 70 K at 10 hPa) was accompanied by mesospheric cooling which was observed in a narrow layer ( 50 K at 0.01 hPa). In late December - early January, there was significant increase of intensities of OH and O2 emissions originating at the mesosphere and low

  8. Climate change and agroecosystems: the effect of elevated atmospheric CO2 and temperature on crop growth, development, and yield

    Directory of Open Access Journals (Sweden)

    Streck Nereu Augusto

    2005-01-01

    Full Text Available The amount of carbon dioxide (CO2 of the Earths atmosphere is increasing, which has the potential of increasing greenhouse effect and air temperature in the future. Plants respond to environment CO2 and temperature. Therefore, climate change may affect agriculture. The purpose of this paper was to review the literature about the impact of a possible increase in atmospheric CO2 concentration and temperature on crop growth, development, and yield. Increasing CO2 concentration increases crop yield once the substrate for photosynthesis and the gradient of CO2 concentration between atmosphere and leaf increase. C3 plants will benefit more than C4 plants at elevated CO2. However, if global warming will take place, an increase in temperature may offset the benefits of increasing CO2 on crop yield.

  9. Inactivation of Gram-positive biofilms by low-temperature plasma jet at atmospheric pressure

    Science.gov (United States)

    Marchal, F.; Robert, H.; Merbahi, N.; Fontagné-Faucher, C.; Yousfi, M.; Romain, C. E.; Eichwald, O.; Rondel, C.; Gabriel, B.

    2012-08-01

    This work is devoted to the evaluation of the efficiency of a new low-temperature plasma jet driven in ambient air by a dc-corona discharge to inactivate adherent cells and biofilms of Gram-positive bacteria. The selected microorganisms were lactic acid bacteria, a Weissella confusa strain which has the particularity to excrete a polysaccharide polymer (dextran) when sucrose is present. Both adherent cells and biofilms were treated with the low-temperature plasma jet for different exposure times. The antimicrobial efficiency of the plasma was tested against adherent cells and 48 h-old biofilms grown with or without sucrose. Bacterial survival was estimated using both colony-forming unit counts and fluorescence-based assays for bacterial cell viability. The experiments show the ability of the low-temperature plasma jet at atmospheric pressure to inactivate the bacteria. An increased resistance of bacteria embedded within biofilms is clearly observed. The resistance is also significantly higher with biofilm in the presence of sucrose, which indicates that dextran could play a protective role.

  10. The response of Phanerozoic surface temperature to variations in atmospheric oxygen concentration

    Science.gov (United States)

    Payne, Rebecca C.; Britt, Amber V.; Chen, Howard; Kasting, James F.; Catling, David C.

    2016-09-01

    Recently, Poulsen et al. (2015) suggested that O2 has played a major role in climate forcing during the Phanerozoic. Specifically, they argued that decreased O2 levels during the Cenomanian stage of the middle Cretaceous (94-100 Ma) could help explain the extremely warm climate during that time. The postulated warming mechanism involves decreased Rayleigh scattering by a thinner atmosphere, which reduces the planetary albedo and allows greater surface warming. This warming effect is then amplified by cloud feedbacks within their 3-D climate model. This increase in shortwave surface forcing, in their calculations, exceeds any decrease in the greenhouse effect caused by decreased O2. Here we use a 1-D radiative-convective climate model (with no cloud feedback) to check their results. We also include a self-consistent calculation of the change in atmospheric ozone and its effect on climate. Our results are opposite to those of Poulsen et al.: we find that the climate warms by 1.4 K at 35% O2 concentrations as a result of increased pressure broadening of CO2 and H2O absorption lines and cools by 0.8 K at 10% O2 as a result of decreased pressure broadening. The surface temperature changes are only about 1 K either way, though, for reasonable variations in Phanerozoic O2 concentrations (10%-35% by volume). Hence, it seems unlikely that changes in atmospheric O2 account for the warm climate of the Cenomanian. Other factors, such as a higher-than-expected sensitivity of climate to increased CO2 concentrations, may be required to obtain agreement with the paleoclimate data.

  11. Ionospheric ion temperature climate and upper atmospheric long-term cooling

    Science.gov (United States)

    Zhang, Shun-Rong; Holt, John M.; Erickson, Philip J.; Goncharenko, Larisa P.; Nicolls, Michael J.; McCready, Mary; Kelly, John

    2016-09-01

    It is now recognized that Earth's upper atmosphere is experiencing a long-term cooling over the past several solar cycles. The potential impact of the cooling on societal activities is significant, but a fundamental scientific question exists regarding the drivers of the cooling. New observations and analyses provide crucial advances in our knowledge of these important processes. We investigate ionospheric ion temperature climatology and long-term trends using up-to-date large and consistent ground-based data sets as measured by multiple incoherent scatter radars (ISRs). The very comprehensive view provided by these unique observations of the upper atmospheric thermal status allows us to address drivers of strong cooling previously observed by ISRs. We use observations from two high-latitude sites at Sondrestrom (invariant latitude 73.2°N) from 1990 to 2015 and Chatanika/Poker Flat (invariant latitude 65.9°N) over the span of 1976-2015 (with a gap from 1983 to 2006). Results are compared to conditions at the midlatitude Millstone Hill site (invariant latitude 52.8°N) from 1968 to 2015. The aggregate radar observations have very comparable and consistent altitude dependence of long-term trends. In particular, the lower F region (<275 km) exhibits dayside cooling trends that are significantly higher (-3 to -1 K/yr at 250 km) than anticipated from model predictions given the anthropogenic increase of greenhouse gases. Above 275 km, cooling trends continue to increase in magnitude but values are strongly dependent on magnetic latitude, suggesting the presence of significant downward influences from nonneutral atmospheric processes.

  12. Investigating Titan's Atmospheric Chemistry at Low Temperature with the Titan Haze Simulation Experiment

    Science.gov (United States)

    Sciamma-O'Brien, E. M.; Salama, F.

    2012-12-01

    Titan, Saturn's largest satellite, possesses a dense atmosphere (1.5 bar at the surface) composed mainly of N2 and CH4. The solar radiation and electron bombardment from Saturn's magnetosphere induces a complex organic chemistry between these two constituents leading to the production of more complex molecules and subsequently to solid aerosols. These aerosols in suspension in the atmosphere form the haze layers giving Titan its characteristic orange color. Since 2004, the instruments onboard the Cassini orbiter have produced large amounts of observational data, unraveling a chemistry much more complex than what was first expected, particularly in Titan's upper atmosphere. Neutral, positively and negatively charged heavy molecules have been detected in the ionosphere of Titan, including benzene (C6H6) and toluene (C6H5CH3). The presence of these critical precursors of polycyclic aromatic hydrocarbon (PAH) compounds suggests that PAHs might play a role in the production of Titan's aerosols. The aim of the Titan Haze Simulation (THS) experiment, developed at the NASA Ames COSmIC facility, is to study the chemical pathways that link the simple molecules resulting from the first steps of the N2-CH4 chemistry to benzene, and to PAHs and nitrogen-containing PAHs (PANHs) as precursors to the production of solid aerosols. In the THS experiment, Titan's atmospheric chemistry is simulated by plasma in the stream of a supersonic expansion. With this unique design, the gas mixture is cooled to Titan-like temperature (~150K) before inducing the chemistry by plasma discharge. Due to the short residence time of the gas in the plasma discharge, the THS experiment can be used to probe the first and intermediate steps of Titan's chemistry by injecting different gas mixtures in the plasma. The products of the chemistry are detected and studied using two complementary techniques: Cavity Ring Down Spectroscopy and Time-Of-Flight Mass Spectrometry. Thin tholin deposits are also produced

  13. Atmospheric pressure, density, temperature and wind variations between 50 and 200 km

    Science.gov (United States)

    Justus, C. G.; Woodrum, A.

    1972-01-01

    Data on atmospheric pressure, density, temperature and winds between 50 and 200 km were collected from sources including Meteorological Rocket Network data, ROBIN falling sphere data, grenade release and pitot tube data, meteor winds, chemical release winds, satellite data, and others. These data were analyzed by a daily difference method and results on the distribution statistics, magnitude, and spatial structure of the irregular atmospheric variations are presented. Time structures of the irregular variations were determined by the analysis of residuals from harmonic analysis of time series data. The observed height variations of irregular winds and densities are found to be in accord with a theoretical relation between these two quantities. The latitude variations (at 50 - 60 km height) show an increasing trend with latitude. A possible explanation of the unusually large irregular wind magnitudes of the White Sands MRN data is given in terms of mountain wave generation by the Sierra Nevada range about 1000 km west of White Sands. An analytical method is developed which, based on an analogy of the irregular motion field with axisymmetric turbulence, allows measured or model correlation or structure functions to be used to evaluate the effective frequency spectra of scalar and vector quantities of a spacecraft moving at any speed and at any trajectory elevation angle.

  14. Solar Atmospheric Magnetic Energy Coupling: Broad Plasma Conditions and Temperature Scales

    CERN Document Server

    Orange, N Brice; Gendre, Bruce; Morris, David C; Oluseyi, Hakeem M

    2016-01-01

    Solar variability investigations that include its magnetic energy coupling are paramount to solving many key solar/stellar physics problems. Particularly understanding the temporal variability of magnetic energy redistribution and heating processes. Using three years of observations from the {\\it Solar Dynamics Observatory's} Atmospheric Imaging Assembly and Heliosemic Magnetic Imager, radiative and magnetic fluxes were measured from coronal hole, quiet Sun, active regions, active region cores (i.e., inter moss), and at full-disk scales, respectively. We present, and mathematically describe, their coupling of radiative fluxes, across broad temperature gradients, to the available photospheric magnetic energy. A comparison of the common linear relationship of radiative to magnetic coupling is performed against our extended broken power-law description, which reveals a potential entanglement of thermodynamic and magnetic energy contributions in existing literature. As such, our work provides an improved approach...

  15. A handheld low temperature atmospheric pressure air plasma gun for nanomaterial synthesis in liquid phase

    Science.gov (United States)

    Yu, Shuang; Wang, Kaile; Zuo, Shasha; Liu, Jiahui; Zhang, Jue; Fang, Jing

    2015-10-01

    A handheld low temperature atmospheric pressure air plasma gun based on a dielectric barrier structure with hollow electrodes was proposed. The portable plasma gun with an embedded mini air pump was driven by a 12 V direct voltage battery. The air plasma jet generated from the gun could be touched without a common shock hazard. Besides working in air, the plasma gun can also work in water. The diagnostic result of optical emission spectroscopy showed the difference in reactive species of air plasma jet between in air and in water. The plasma gun was excited in 20 ml chloroauric acid aqueous solution with a concentration of 1.214 mM. A significant amount of gold nanoparticles were synthesized after 2 min continuous discharge. The plasma gun with these unique features is applicable in plasma medicine, etching, and s-nthesis of nanomaterials.

  16. Turbulent jet flow generated downstream of a low temperature dielectric barrier atmospheric pressure plasma device

    Science.gov (United States)

    Whalley, Richard D.; Walsh, James L.

    2016-08-01

    Flowing low temperature atmospheric pressure plasma devices have been used in many technological applications ranging from energy efficient combustion through to wound healing and cancer therapy. The generation of the plasma causes a sudden onset of turbulence in the inhomogeneous axisymmetric jet flow downstream of the plasma plume. The mean turbulent velocity fields are shown to be self-similar and independent of the applied voltage used to generate the plasma. It is proposed that the production of turbulence is related to a combination of the small-amplitude plasma induced body forces and gas heating causing perturbations in the unstable shear layers at the jet exit which grow as they move downstream, creating turbulence.

  17. A handheld low temperature atmospheric pressure air plasma gun for nanomaterial synthesis in liquid phase

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Shuang; Wang, Kaile; Zuo, Shasha; Liu, Jiahui [Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871 (China); Zhang, Jue, E-mail: zhangjue@pku.edu.cn; Fang, Jing [Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871 (China); College of Engineering, Peking University, Beijing 100871 (China)

    2015-10-15

    A handheld low temperature atmospheric pressure air plasma gun based on a dielectric barrier structure with hollow electrodes was proposed. The portable plasma gun with an embedded mini air pump was driven by a 12 V direct voltage battery. The air plasma jet generated from the gun could be touched without a common shock hazard. Besides working in air, the plasma gun can also work in water. The diagnostic result of optical emission spectroscopy showed the difference in reactive species of air plasma jet between in air and in water. The plasma gun was excited in 20 ml chloroauric acid aqueous solution with a concentration of 1.214 mM. A significant amount of gold nanoparticles were synthesized after 2 min continuous discharge. The plasma gun with these unique features is applicable in plasma medicine, etching, and s-nthesis of nanomaterials.

  18. Turbulent jet flow generated downstream of a low temperature dielectric barrier atmospheric pressure plasma device.

    Science.gov (United States)

    Whalley, Richard D; Walsh, James L

    2016-08-26

    Flowing low temperature atmospheric pressure plasma devices have been used in many technological applications ranging from energy efficient combustion through to wound healing and cancer therapy. The generation of the plasma causes a sudden onset of turbulence in the inhomogeneous axisymmetric jet flow downstream of the plasma plume. The mean turbulent velocity fields are shown to be self-similar and independent of the applied voltage used to generate the plasma. It is proposed that the production of turbulence is related to a combination of the small-amplitude plasma induced body forces and gas heating causing perturbations in the unstable shear layers at the jet exit which grow as they move downstream, creating turbulence.

  19. Sensitivity of Venus surface emissivity retrieval to model variations of CO2 opacity, cloud features, and deep atmosphere temperature field

    Science.gov (United States)

    Kappel, David; Arnold, Gabriele; Haus, Rainer

    2012-07-01

    The Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) aboard ESA's Venus Express space probe has acquired a wealth of nightside emission spectra from Venus and provides the first global database for systematic atmospheric and surface studies in the IR. The infrared mapping channel (VIRTIS-M-IR) sounds the atmosphere and surface at high spatial and temporal resolution and coverage. Quantitative analyses of data call for a sophisticated radiative transfer simulation model of Venus' atmosphere to be used in atmospheric and surface parameter retrieval procedures that fit simulated spectra to the measured data. The surface emissivity can be retrieved from VIRTIS-M-IR measurements in the transparency windows around 1 μm, but it is not easy to derive, since atmospheric influences strongly interfere with surface information. There are mainly three atmospheric model parameters that may affect quantitative results of surface emissivity retrievals: CO_2 opacity, cloud features, and deep atmosphere temperature field. The CO_2 opacity with respect to allowed transitions is usually computed by utilizing a suitable line data base and certain line shape models that consider collisional line mixing. Both line data bases and shape models are not well established from measurements under the environmental conditions in the deep atmosphere of Venus. Pressure-induced additional continuum absorption introduces further opacity uncertainties. The clouds of Venus are usually modeled by a four-modal distribution of spherical droplets of about 75% sulfuric acid, where each mode is characterized by a different mean and standard deviation of droplet size distribution and a different initial altitude abundance profile. The influence of possible cloud mode variations on surface emissivity retrieval results is investigated in the paper. Future retrieval procedures will aim at a separation of cloud mode and surface emissivity variations using different atmospheric windows sounded by

  20. Photoabsorption cross sections of organic molecules in the VUV at low temperatures : application to Titan's atmosphere observations.

    Science.gov (United States)

    Benilan, Y.; Ferradaz, T.; Fray, N.; Jolly, A.; Schwell, M.; Guillemin, J.-C.

    To build photochemical models of planetary atmospheres and to interpret observations the photoabsorption cross sections of molecules are needed A critical review of the absorption coefficient available in the vacuum ultraviolet domain VUV 110-210 nm for organic molecules present or expected to be present in Titan s atmosphere showed a critical lack of data In particular many absorption cross sections have never been measured at low temperature The lack is even greater for molecules not commercially available since even at room temperature absolute absorption coefficients are not available or erroneous A new specific absorption cell has thus been designed to o measure the absorption cross sections in the VUV range at low temperature characteristic of Titan s atmosphere The first molecules that we have studied are HCN HC3N and C4H2 We used the Berlin synchrotron facility BESSY to obtained those new absorption coefficients including the first spectra in the 110 to 210 nm range at the low temperature representative of Titan s atmosphere The effect of the temperature on the spectra will be discussed A application to the determination of photodissociation rate of those molecules will be showed And an application to the interpretation of VUV observations of Titan s atmosphere obtained by the UV spectrometer UVIS on board the CASSINI spacecraft will be presented

  1. Laser schlieren deflectometry for temperature analysis of filamentary non-thermal atmospheric pressure plasma

    Energy Technology Data Exchange (ETDEWEB)

    Schaefer, J.; Foest, R.; Reuter, S.; Weltmann, K.-D. [INP Greifswald, Felix-Hausdorff-Str. 2, 17489 Greifswald (Germany); Kewitz, T. [Institute of Experimental and Applied Physics, University Kiel, 24098 Kiel (Germany); Sperka, J. [Department of Physical Electronics, Masaryk University, 61137 Brno (Czech Republic)

    2012-10-15

    The heat convection generated by micro filaments of a self-organized non-thermal atmospheric pressure plasma jet in Ar is characterized by employing laser schlieren deflectometry (LSD). It is demonstrated as a proof of principle, that the spatial and temporal changes of the refractive index n in the optical beam path related to the neutral gas temperature of the plasma jet can be monitored and evaluated simultaneously. The refraction of a laser beam in a high gradient field of n(r) with cylindrical symmetry is given for a general real refraction index profile. However, the usually applied Abel approach represents an ill-posed problem and in particular for this plasma configuration. A simple analytical model is proposed in order to minimize the statistical error. Based on that, the temperature profile, specifically the absolute temperature in the filament core, the FWHM, and the frequencies of the collective filament dynamics are obtained for non-stationary conditions. For a gas temperature of 700 K inside the filament, the presented model predicts maximum deflection angles of the laser beam of 0.3 mrad which is in accordance to the experimental results obtained with LSD. Furthermore, the experimentally obtained FWHM of the temperature profile produced by the filament at the end of capillary is (1.5 {+-} 0.2) mm, which is about 10 times wider than the visual radius of the filament. The obtained maximum temperature in the effluent is (450 {+-} 30) K and is in consistence with results of other techniques. The study demonstrates that LSD represents a useful low-cost method for monitoring the spatiotemporal behaviour of microdischarges and allows to uncover their dynamic characteristics, e.g., the temperature profile even for challenging diagnostic conditions such as moving thin discharge filaments. The method is not restricted to the miniaturized and self-organized plasma studied here. Instead, it can be readily applied to other configurations that produce measurable

  2. Laser schlieren deflectometry for temperature analysis of filamentary non-thermal atmospheric pressure plasma

    Science.gov (United States)

    Schäfer, J.; Foest, R.; Reuter, S.; Kewitz, T.; Šperka, J.; Weltmann, K.-D.

    2012-10-01

    The heat convection generated by micro filaments of a self-organized non-thermal atmospheric pressure plasma jet in Ar is characterized by employing laser schlieren deflectometry (LSD). It is demonstrated as a proof of principle, that the spatial and temporal changes of the refractive index n in the optical beam path related to the neutral gas temperature of the plasma jet can be monitored and evaluated simultaneously. The refraction of a laser beam in a high gradient field of n(r) with cylindrical symmetry is given for a general real refraction index profile. However, the usually applied Abel approach represents an ill-posed problem and in particular for this plasma configuration. A simple analytical model is proposed in order to minimize the statistical error. Based on that, the temperature profile, specifically the absolute temperature in the filament core, the FWHM, and the frequencies of the collective filament dynamics are obtained for non-stationary conditions. For a gas temperature of 700 K inside the filament, the presented model predicts maximum deflection angles of the laser beam of 0.3 mrad which is in accordance to the experimental results obtained with LSD. Furthermore, the experimentally obtained FWHM of the temperature profile produced by the filament at the end of capillary is (1.5 ± 0.2) mm, which is about 10 times wider than the visual radius of the filament. The obtained maximum temperature in the effluent is (450 ± 30) K and is in consistence with results of other techniques. The study demonstrates that LSD represents a useful low-cost method for monitoring the spatiotemporal behaviour of microdischarges and allows to uncover their dynamic characteristics, e.g., the temperature profile even for challenging diagnostic conditions such as moving thin discharge filaments. The method is not restricted to the miniaturized and self-organized plasma studied here. Instead, it can be readily applied to other configurations that produce measurable

  3. Retrieving Atmospheric Temperature Profiles from AMSU-A Data with Neural Networks

    Institute of Scientific and Technical Information of China (English)

    YAO Zhigang; CHEN Hongbin; LIN Longfu

    2005-01-01

    Back propagation neural networks are used to retrieve atmospheric temperature profiles from NOAA-16 Advanced Microwave Sounding Unit-A (AMSU-A) measurements over East Asia. The collocated radiosonde observation and AMSU-A data over land in 2002-2003 are used to train the network, and the data over land in 2004 are used to test the network. A comparison with the multi-linear regression method shows that the neural network retrieval method can significantly improve the results in all weather conditions.When an offset of 0.5 K or a noise level of +0.2 K is added to all channels simultaneously, the increase in the overall root mean square (RMS) error is less than 0.1 K. Furthermore, an experiment is conducted to investigate the effects of the window channels on the retrieval. The results indicate that the brightness temperatures of window channels can provide significantly useful information on the temperature retrieval near the surface. Additionally, the RMS errors of the profiles retrieved with the trained neural network are compared with the errors from the International Advanced TOVS (ATOVS) Processing Package (IAPP).It is shown that the network-based algorithm can provide much better results in the experiment region and comparable results in other regions. It is also noted that the network can yield remarkably better results than IAPP at the low levels and at about the 250-hPa level in summer skies over ocean. Finally,the network-based retrieval algorithm developed herein is applied in retrieving the temperature anomalies of Typhoon Rananim from AMSU-A data.

  4. Laser diagnostics on atmospheric pressure discharge plasmas, including cryoplasmas, in environments around room and cryogenic temperature

    Science.gov (United States)

    Sakakibara, Noritaka; Muneoka, Hitoshi; Urabe, Keiichiro; Yasui, Ryoma; Sakai, Osamu; Terashima, Kazuo

    2017-04-01

    Cryoplasmas, the plasma gas temperature (T g) of which can be controlled continuously below room temperature, show various unique and advantageous properties depending on T g. Recently, the T g dependence of plasma chemistry related to metastable helium (Hem) has been revealed in helium cryoplasmas. However, T g was only estimated by thermal calculation from the temperature outside the plasmas. In this study, for better evaluation of T g, near-infrared laser heterodyne interferometry (NIR-LHI) measurements were conducted in atmospheric pressure helium pulsed discharge plasmas at around room and cryogenic ambient temperatures (T a). The maximum difference between T g and T a was evaluated as 47 K at T a  =  300 K with 282 mW power consumption. To further investigate the T g dependence of plasma chemical reactions related to Hem, laser absorption spectroscopy (LAS) was performed on the same discharge plasmas to measure the Hem density and lifetime. The Hem lifetime was longer at lower T g, i.e. the lifetime at T g  =  145 K (9.6 µs) was seven times longer than that at T g  =  386 K (1.4 µs). By comparing the results with the numerically simulated rates of Hem quenching reactions taking T g into account, the mechanism of the Hem quenching reaction was revealed to vary with T g even though the main quenching reaction was a three-body collision at all T g. In this manner, the combination of NIR-LHI with LAS led directly to the T g dependence of Hem quenching reactions.

  5. On the effects of clouds and hazes in the atmospheres of hot Jupiters: semi-analytical temperature-pressure profiles

    CERN Document Server

    Heng, Kevin; Pont, Frédéric; Sing, David K

    2011-01-01

    Motivated by the work of Guillot (2010), we present a semi-analytical formalism for calculating the temperature-pressure profiles in hot Jovian atmospheres which includes the effects of clouds/hazes and collision-induced absorption. Using the dual-band approximation, we assume that stellar irradiation and thermal emission from the hot Jupiter occur at distinct wavelengths ("shortwave" versus "longwave"). For a purely absorbing cloud/haze, we demonstrate its dual effect of cooling and warming the upper and lower atmosphere, respectively, which modifies, in a non-trivial manner, the condition for whether a temperature inversion is present in the upper atmosphere. The warming effect becomes more pronounced as the cloud/haze deck resides at greater depths. If it sits below the shortwave photosphere, the warming effect becomes either more subdued or ceases altogether. If shortwave scattering is present, its dual effect is to warm and cool the upper and lower atmosphere, respectively, thus counteracting the effects...

  6. The Temperature of the Dimethylhydrazine Drops Moving in the Atmosphere after Depressurization of the Fuel Tank Rockets

    Directory of Open Access Journals (Sweden)

    Bulba Elena

    2016-01-01

    Full Text Available This work includes the results of the numerical modeling of temperature changes process of the dimethylhydrazine (DMH drops, taking into account the radial temperature gradient in the air after the depressurization of the fuel compartments rockets at high altitude. There is formulated a mathematical model describing the process of DMH drops thermal state modifying when it's moving to the Earth's surface. There is the evaluation of the influence of the characteristic size of heptyl drops on the temperature distribution. It's established that the temperatures of the small size droplets practically completely coincide with the distribution of temperature in the atmosphere at altitudes of up to 40 kilometers.

  7. On the effects of clouds and hazes in the atmospheres of hot Jupiters: semi-analytical temperature-pressure profiles

    Science.gov (United States)

    Heng, Kevin; Hayek, Wolfgang; Pont, Frédéric; Sing, David K.

    2012-02-01

    Motivated by the work of Guillot, we present a semi-analytical formalism for calculating the temperature-pressure profiles in hot Jovian atmospheres which includes the effects of clouds/hazes and collision-induced absorption. Using the dual-band approximation, we assume that stellar irradiation and thermal emission from the hot Jupiter occur at distinct wavelengths ('shortwave' versus 'longwave'). For a purely absorbing cloud/haze, we demonstrate its dual effect of cooling and warming the upper and lower atmosphere, respectively, which modifies, in a non-trivial manner, the condition for whether a temperature inversion is present in the upper atmosphere. The warming effect becomes more pronounced as the cloud/haze deck resides at greater depths. If it sits below the shortwave photosphere, the warming effect becomes either more subdued or ceases altogether. If shortwave scattering is present, its dual effect is to warm and cool the upper and lower atmospheres, respectively, thus counteracting the effects of enhanced longwave absorption by the cloud/haze. We make a tentative comparison of a four-parameter model to the temperature-pressure data points inferred from the observations of HD 189733b and estimate that its Bond albedo is approximately 10 per cent. Besides their utility in developing physical intuition, our semi-analytical models are a guide for the parameter space exploration of hot Jovian atmospheres via three-dimensional simulations of atmospheric circulation.

  8. Application of Atmospheric-Pressure Microwave Line Plasma for Low Temperature Process

    Science.gov (United States)

    Suzuki, Haruka; Nakano, Suguru; Itoh, Hitoshi; Sekine, Makoto; Hori, Masaru; Toyoda, Hirotaka

    2015-09-01

    Atmospheric pressure (AP) plasmas have been given much attention because of its high cost benefit and a variety of possibilities for industrial applications. In various kinds of plasma production technique, pulsed-microwave discharge plasma using slot antenna is attractive due to its ability of high-density and stable plasma production. In this plasma source, however, size of the plasma has been limited up to a few cm in length due to standing wave inside a waveguide. To solve this, we have proposed a newly-developed AP microwave plasma source that utilizes not standing wave but travelling wave. By using this plasma source, spatially-uniform AP line plasma with 40 cm in length was realized by pure helium discharge in 60 cm slot and with nitrogen gas additive of 1%. Furthermore, gas temperature as low as 400 K was realized in this device. In this study, as an example of low temperature processes, hydrophilic treatment of PET films was performed. Processing speed increased with pulse frequency and a water contact angle of ~20° was easily obtained within 5 s with no thermal damage to the substrate. To evaluate treatment-uniformity of long line length, PET films were treated by 90 cm slot-antenna plasma and uniform treatment performance was confirmed.

  9. Interpretation of biomass gasification yields regarding temperature intervals under nitrogen-steam atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Haykiri-Acma, H.; Yaman, S. [Istanbul Technical University, Chemical and Metallurgical Engineering Faculty, Chemical Engineering Department, 34469 Maslak, Istanbul (Turkey)

    2007-04-15

    Gasification of some agricultural waste biomass samples (sunflower shell, pine cone, cotton refuse, and olive refuse) and colza seed was performed using a thermogravimetric analyzer at temperatures up to 1273 K with a constant heating rate of 20 K/min under a dynamic nitrogen-steam atmosphere. Derivative thermogravimetric analysis profiles of the samples were derived from the non-isothermal thermogravimetric analysis data. Gasification yields of the biomass samples at temperature intervals of 473-553 K, 553-653 K, 653-773 K, 773-973 K, and 973-1173 K were investigated considering the successive stages of ''evolution of carbon oxides'', ''start of hydrocarbon evolution'', ''evolution of hydrocarbons'', ''dissociation'', and ''evolution of hydrogen'', respectively. Although, there were some interactions between these stages, some evident relations were observed between the gasification yields in a given stage and the chemical properties of the parent biomass materials. (author)

  10. CFCI3 (CFC-11): UV Absorption Spectrum Temperature Dependence Measurements and the Impact on Atmospheric Lifetime and Uncertainty

    Science.gov (United States)

    Mcgillen, Max R.; Fleming, Eric L.; Jackman, Charles H.; Burkholder, James B.

    2014-01-01

    CFCl3 (CFC-11) is both an atmospheric ozone-depleting and potent greenhouse gas that is removed primarily via stratospheric UV photolysis. Uncertainty in the temperature dependence of its UV absorption spectrum is a significant contributing factor to the overall uncertainty in its global lifetime and, thus, model calculations of stratospheric ozone recovery and climate change. In this work, the CFC-11 UV absorption spectrum was measured over a range of wavelength (184.95 - 230 nm) and temperature (216 - 296 K). We report a spectrum temperature dependence that is less than currently recommended for use in atmospheric models. The impact on its atmospheric lifetime was quantified using a 2-D model and the spectrum parameterization developed in this work. The obtained global annually averaged lifetime was 58.1 +- 0.7 years (2 sigma uncertainty due solely to the spectrum uncertainty). The lifetime is slightly reduced and the uncertainty significantly reduced from that obtained using current spectrum recommendations

  11. Gaseous Mean Opacities for Giant Planet and Ultracool Dwarf Atmospheres over a Range of Metallicities and Temperatures

    CERN Document Server

    Freedman, Richard S; Fortney, Jonathan J; Lupu, Roxana E; Marley, Mark S; Lodders, Katharina

    2014-01-01

    We present new calculations of Rosseland and Planck gaseous mean opacities relevant to the atmospheres of giant planets and ultracool dwarfs. Such calculations are used in modeling the atmospheres, interiors, formation, and evolution of these objects. Our calculations are an expansion of those presented in Freedman et al. (2008) to include lower pressures, finer temperature resolution, and also the higher metallicities most relevant for giant planet atmospheres. Calculations span 1 microbar to 300 bar, and 75 K to 4000 K, in a nearly square grid. Opacities at metallicities from solar to 50 times solar abundances are calculated. We also provide an analytic fit to the Rosseland mean opacities over the grid in pressure, temperature, and metallicity. In addition to computing mean opacities at these local temperatures, we also calculate them with weighting functions up to 7000 K, to simulate the mean opacities for incident stellar intensities, rather than locally thermally emitted intensities. The chemical equilib...

  12. Outer scales of temperature turbulence and dynamic turbulence from the data of acoustic sounding of the atmosphere

    Science.gov (United States)

    Shamanaeva, L. G.; Krasnenko, N. P.; Kapegesheva, O. F.

    2014-11-01

    The outer scale of turbulence plays an important role in the theory of atmospheric turbulence. It specifies the lowfrequency boundary of the inertial subrange of fluctuation spectra of the atmospheric meteorological parameters, is used to construct models of the atmospheric turbulence and to estimate the excess turbulent attenuation of waves in the atmosphere. Outer scales of the wind velocity, temperature, humidity, and ozone concentration were previously determined, in particular, from direct airborne measurements of the spectral power density of these parameters, and their dependences on the altitude above the underlying surface, its properties, and type of the atmospheric stratification were demonstrated. For optical radiation propagating in the surface layer, the outer scale of temperature turbulence was determined from measurements of the variance of phase fluctuations of optical waves propagating along the near-ground paths. Unlike the optical waves, the acoustic wave propagation in the atmospheric boundary layer is influenced simultaneously by the temperature fluctuations caused by thermal convection and by the velocity fluctuations (dynamic turbulence caused by the wind shear). Their relative contributions depend on the ratio of the outer scales of the dynamic turbulence and temperature turbulence. In the present work, a method of simultaneous acoustic sounding of the outer scales of dynamic turbulence and temperature turbulence is suggested, and combined influence of these parameters on the acoustic wave propagation is estimated. Temporal dynamics of vertical profiles of the outer scales of dynamic turbulence and temperature turbulence is analyzed. The efficiency of the suggested method is confirmed by the results of comparison with the data of laser sensing of these parameters and their theoretical estimates, which demonstrate their good agreement.

  13. Response of leaf litter decomposition to rises in atmospheric CO2 and temperature

    Science.gov (United States)

    Hammrich, A.; Flury, S.; Gessner, M. O.

    2007-05-01

    Atmospheric concentrations of CO2 have considerably increased in the last century and are expected to rise further. Elevated CO2 concentrations not only increase global temperature but also have potential to change plant litter quality, for example by increasing lignin content, changing C:N ratios and altering tannin contents. These chemical changes may interact with increased temperature to alter litter decomposition. To test whether changes in litter quality and warming affect decomposition, we conducted a field experiment with leaf litter collected from six species of mature deciduous trees exposed to either ambient or elevated CO2 levels. We used a set of 16 enclosures installed in four blocks in a freshwater marsh in a prealpine lake to test for the effects of CO2-mediated litter quality and temperature and the interaction of both factors. We measured leaf mass loss of the twelve litter types in control and heated enclosures (4 °C above ambient) and also in the open marsh. In contrast to expectations, species decomposing at low (oak and beech) and medium (hornbeam and maple) rates showed faster mass loss when leaves were grown under elevated CO2 conditions, whereas fast-decomposing species (cherry and basswood) showed no clear response. The accelerated decomposition of CO2-enriched litter could be due to higher amounts of nonstructural carbohydrates, which may have been either leached or readily degraded. Warming had a surprisingly small influence on mass loss of the tested litter species, and interactive effects were weak. These results suggest that direct and indirect effects of elevated CO2 levels on litter decomposition may not be readily predictable from first principles.

  14. Surface and Atmospheric Contributions to Passive Microwave Brightness Temperatures for Falling Snow Events

    Science.gov (United States)

    Skofronick-Jackson, Gail; Johnson, Benjamin T.

    2011-01-01

    Physically based passive microwave precipitation retrieval algorithms require a set of relationships between satellite -observed brightness temperatures (TBs) and the physical state of the underlying atmosphere and surface. These relationships are nonlinear, such that inversions are ill ]posed especially over variable land surfaces. In order to elucidate these relationships, this work presents a theoretical analysis using TB weighting functions to quantify the percentage influence of the TB resulting from absorption, emission, and/or reflection from the surface, as well as from frozen hydrometeors in clouds, from atmospheric water vapor, and from other contributors. The percentage analysis was also compared to Jacobians. The results are presented for frequencies from 10 to 874 GHz, for individual snow profiles, and for averages over three cloud-resolving model simulations of falling snow. The bulk structure (e.g., ice water path and cloud depth) of the underlying cloud scene was found to affect the resultant TB and percentages, producing different values for blizzard, lake effect, and synoptic snow events. The slant path at a 53 viewing angle increases the hydrometeor contributions relative to nadir viewing channels. Jacobians provide the magnitude and direction of change in the TB values due to a change in the underlying scene; however, the percentage analysis provides detailed information on how that change affected contributions to the TB from the surface, hydrometeors, and water vapor. The TB percentage information presented in this paper provides information about the relative contributions to the TB and supplies key pieces of information required to develop and improve precipitation retrievals over land surfaces.

  15. Development of advanced metallic coatings resistant to corrosion in high temperature industrial atmospheres

    Energy Technology Data Exchange (ETDEWEB)

    Weber, T.; Bender, R.; Rosado, C.; Schuetze, M. [DECHEMA e.V., Frankfurt am Main (Germany)

    2004-07-01

    Following the experimental results that {gamma}-TiAl is highly resistant in reducing sulfidizing atmospheres the development of Ti-Al-co-diffusion coatings produced in a single step pack cementation process was started. The appropriate diffusion powder compositions were selected using thermodynamical calculations. Different Al-Ti-, Al-Si- and Al-Ti-Si-diffusion coatings were successfully applied on austenitic steels as well as Ni-base materials and showed excellent behaviour in reducing sulfidizing atmospheres with high carbon contents (CH{sub 4} - 1% CO - 1% CO{sub 2} - 10% H{sub 2} - 7% H{sub 2}S) up to 700 deg. C, under metal dusting conditions (H{sub 2} - 25 CO - 2% H{sub 2}O and CO - 2.4% CO{sub 2} - 1% CH{sub 4} - 9.4% N{sub 2} - 23.4% H{sub 2} - 0.2% H{sub 2}O - 1 ppm H{sub 2}S-0.3 ppm HCl) at temperatures of 620 deg. C and 700 deg. C. The application of diffusion coatings on ferritic materials has to be modified due to the specific requirements on the mechanical properties which are affected by the heat treatment during the diffusion process. TiAl was also applied by the HVOF thermal spray method on ferritic steels. Due to similarity of the thermal expansion coefficients this substrate-coating system proved to be mechanically very stable also under thermal cycling conditions. (authors)

  16. Characterizations of atmospheric pressure low temperature plasma jets and their applications

    Science.gov (United States)

    Karakas, Erdinc

    2011-12-01

    Atmospheric pressure low temperature plasma jets (APLTPJs) driven by short pulses have recently received great attention because of their potential in biomedical and environmental applications. This potential is due to their user-friendly features, such as low temperature, low risk of arcing, operation at atmospheric pressure, easy handheld operation, and low concentration of ozone generation. Recent experimental observations indicate that an ionization wave exists and propagates along the plasma jet. The plasma jet created by this ionization wave is not a continuous medium but rather consists of a bullet-like-structure known as "Plasma Bullet". More interestingly, these plasma bullets actually have a donut-shaped makeup. The nature of the plasma bullet is especially interesting because it propagates in the ambient air at supersonic velocities without any externally applied electric field. In this dissertation, experimental insights are reported regarding the physical and chemical characteristics of the APLTPJs. The dynamics of the plasma bullet are investigated by means of a high-speed ICCD camera. A plasma bullet propagation model based on the streamer theory is confirmed with adequate explanations. It is also found that a secondary discharge, ignited by the charge accumulation on the dielectric electrode surfaces at the end of the applied voltage, interrupts the plasma bullet propagation due to an opposing current along the ionization channel. The reason for this interesting phenomenon is explained in detail. The plasma bullet comes to an end when the helium mole fraction along the ionization channel, or applied voltage, or both, are less than some critical values. The presence of an inert gas channel in the surrounding air, such as helium or argon, has a critical role in plasma bullet formation and propagation. For this reason, a fluid dynamics study is employed by a commercially available simulation software, COMSOL, based on finite element method. Spatio

  17. Wind and Temperature Spectrometry of the Upper Atmosphere in Low-Earth Orbit

    Science.gov (United States)

    Herrero, Federico

    2011-01-01

    Wind and Temperature Spectrometry (WATS) is a new approach to measure the full wind vector, temperature, and relative densities of major neutral species in the Earth's thermosphere. The method uses an energy-angle spectrometer moving through the tenuous upper atmosphere to measure directly the angular and energy distributions of the air stream that enters the spectrometer. The angular distribution gives the direction of the total velocity of the air entering the spectrometer, and the energy distribution gives the magnitude of the total velocity. The wind velocity vector is uniquely determined since the measured total velocity depends on the wind vector and the orbiting velocity vector. The orbiting spectrometer moves supersonically, Mach 8 or greater, through the air and must point within a few degrees of its orbital velocity vector (the ram direction). Pointing knowledge is critical; for example, pointing errors 0.1 lead to errors of about 10 m/s in the wind. The WATS method may also be applied without modification to measure the ion-drift vector, ion temperature, and relative ion densities of major ionic species in the ionosphere. In such an application it may be called IDTS: Ion-Drift Temperature Spectrometry. A spectrometer-based coordinate system with one axis instantaneously pointing along the ram direction makes it possible to transform the Maxwellian velocity distribution of the air molecules to a Maxwellian energy-angle distribution for the molecular flux entering the spectrometer. This implementation of WATS is called the gas kinetic method (GKM) because it is applied to the case of the Maxwellian distribution. The WATS method follows from the recognition that in a supersonic platform moving at 8,000 m/s, the measurement of small wind velocities in the air on the order of a few 100 m/s and less requires precise knowledge of the angle of incidence of the neutral atoms and molecules. The same is true for the case of ion-drift measurements. WATS also

  18. Lidar measurements of the atmospheric entrainment zone and the potential temperature jump across the top of the mixed layer

    Science.gov (United States)

    Boers, R.; Eloranta, E. W.

    1986-01-01

    Lidar data of the atmospheric entrainment zone from six days of clear air convection obtained in central Illinois during July 1979 are presented. A new method to measure the potential temperature jump across the entrainment zone based on only one temperature sounding and continuous lidar measurements of the mixed layer height is developed. An almost linear dependence is found between the normalized entrainment rate and the normalized thickness of the entrainment zone.

  19. An atmospheric general circulation model for Pluto with predictions for New Horizons temperature profiles

    Science.gov (United States)

    Zalucha, Angela M.

    2016-06-01

    Results are presented from a 3D Pluto general circulation model (GCM) that includes conductive heating and cooling, non-local thermodynamic equilibrium (non-LTE) heating by methane at 2.3 and 3.3 μm, non-LTE cooling by cooling by methane at 7.6 μm, and LTE CO rotational line cooling. The GCM also includes a treatment of the subsurface temperature and surface-atmosphere mass exchange. An initially 1 m thick layer of surface nitrogen frost was assumed such that it was large enough to act as a large heat sink (compared with the solar heating term) but small enough that the water ice subsurface properties were also significant. Structure was found in all three directions of the 3D wind field (with a maximum magnitude of the order of 10 m s-1 in the horizontal directions and 10-5 microbar s-1 in the vertical direction). Prograde jets were found at several altitudes. The direction of flow over the poles was found to very with altitude. Broad regions of up-welling and down-welling were also found. Predictions of vertical temperature profiles are provided for the Alice and Radio science Experiment instruments on New Horizons, while predictions of light curves are provided for ground-based stellar occultation observations. With this model methane concentrations of 0.2 per cent and 1.0 per cent and 8 and 24 microbar surface pressures are distinguishable. For ground-based stellar occultations, a detectable difference exists between light curves with the different methane concentrations, but not for different initial global mean surface pressures.

  20. Temperature Dependence of Nitro-Quenching by Atmospheric-Pressure Plasma

    Science.gov (United States)

    Mitani, Masaki; Ichiki, Ryuta; Iwakiri, Yutaro; Akamine, Shuichi; Kanazawa, Seiji

    2015-09-01

    A lot of techniques exist as the hardening method of steels, such as nitriding, carburizing and quenching. However, low-alloy steels cannot be hardened by nitriding because hardening by nitriding requires nitride precipitates of special alloy elements such as rare metals. Recently, nitro-quenching (NQ) was developed as a new hardening process, where nitrogen invokes martensitic transformation instead of carbon. NQ is adaptable to hardening low-alloy steels because it does not require alloy elements. In industrial NQ, nitrogen diffusion into steel surface is operated in high temperature ammonia gas. As a new technology, we have developed surface hardening of low-alloy steel by NQ using an atmospheric-pressure plasma. Here the pulsed-arc plasma jet with nitrogen/hydrogen gas mixture is sprayed onto steel surface and then water quench the sample. As a result, the surface of low-alloy steel was partially hardened up to 800 Hv by producing iron-nitrogen martensite. However, the hardness profile is considerably non-uniform. We found that the non-uniform hardness profile can be controlled by changing the treatment gap, the gap between the jet nozzle and the sample surface. Eventually, we succeeded in hardening a targeted part of steel by optimizing the treatment gap. Moreover, we propose the mechanism of non-uniform hardness.

  1. Atmospheric correction for sea surface temperature retrieval from single thermal channel radiometer data onboard Kalpana satellite

    Science.gov (United States)

    Shahi, Naveen R.; Agarwal, Neeraj; Mathur, Aloke K.; Sarkar, Abhijit

    2011-06-01

    An atmospheric correction method has been applied on sea surface temperature (SST) retrieval algorithm using Very High Resolution Radiometer (VHRR) single window channel radiance data onboard Kalpana satellite (K-SAT). The technique makes use of concurrent water vapour fields available from Microwave Imager onboard Tropical Rainfall Measuring Mission (TRMM/TMI) satellite. Total water vapour content and satellite zenith angle dependent SST retrieval algorithm has been developed using Radiative Transfer Model [MODTRAN ver3.0] simulations for Kalpana 10.5-12.5 μm thermal window channel. Retrieval of Kalpana SST (K-SST) has been carried out for every half-hourly acquisition of Kalpana data for the year 2008 to cover whole annual cycle of SST over Indian Ocean (IO). Validation of the retrieved corrected SST has been carried out using near-simultaneous observations of ship and buoys datasets covering Arabian Sea, Bay of Bengal and IO regions. A significant improvement in Root Mean Square Deviation (RMSD) of K-SST with respect to buoy (1.50-1.02 K) and to ship datasets (1.41-1.19 K) is seen with the use of near real-time water vapour fields of TMI. Furthermore, comparison of the retrieved SST has also been carried out using near simultaneous observations of TRMM/TMI SST over IO regions. The analysis shows that K-SST has overall cold bias of 1.17 K and an RMSD of 1.09 K after bias correction.

  2. Observation of semiannual and annual oscillation in equatorial middle atmospheric long term temperature pattern

    Energy Technology Data Exchange (ETDEWEB)

    Guharay, A.; Pant, P. [Aryabhatta Research Institute of observational scienES (ARIES), Nainital (India); Nath, D. [National Atmospheric Research Lab. (NARL), Gadanki (India); Pande, B.; Pandey, K. [Kumaun Univ., Nainital (India). Dept. of Physics; Russell, J.M. III [Hampton Univ., Hampton, VA (United States). Center for Atmospheric Sciences

    2009-07-01

    Extensive measurement of middle atmospheric temperature with the help of lidar data of more than 10 years (1998-2008) and TIMED/SABER data of 7 years (2002-2008), has been carried out from a low latitude station, Gadanki, India (13.5 N, 79.2 E), which exhibits the presence of semiannual oscillation (SAO) and annual oscillation (AnO). The AnO component is stronger in the mesospheric region (80-90 km) and the SAO is dominant at stratospheric altitudes (30-50 km). Overall, the AnO possesses higher amplitude {proportional_to}6-7 K, and the SAO shows less amplitude {proportional_to}1-2 K. The AnO present at 90 km finds crest near summer solstice, and the same at 80 km shows peak near winter solstice with a downward progression speed {proportional_to}1.7 km/month. The SAO propagates downward with an average phase speed {proportional_to}9 km/month and phase maximizes around equinox and solstice at 50 and 30 km, respectively. The observed SAO has also shown seasonal asymmetry in peaks. (orig.)

  3. Observation of semiannual and annual oscillation in equatorial middle atmospheric long term temperature pattern

    Directory of Open Access Journals (Sweden)

    A. Guharay

    2009-11-01

    Full Text Available Extensive measurement of middle atmospheric temperature with the help of lidar data of more than 10 years (1998–2008 and TIMED/SABER data of 7 years (2002–2008, has been carried out from a low latitude station, Gadanki, India (13.5° N, 79.2° E, which exhibits the presence of semiannual oscillation (SAO and annual oscillation (AnO. The AnO component is stronger in the mesospheric region (80–90 km and the SAO is dominant at stratospheric altitudes (30–50 km. Overall, the AnO possesses higher amplitude ~6–7 K, and the SAO shows less amplitude ~1–2 K. The AnO present at 90 km finds crest near summer solstice, and the same at 80 km shows peak near winter solstice with a downward progression speed ~1.7 km/month. The SAO propagates downward with an average phase speed ~9 km/month and phase maximizes around equinox and solstice at 50 and 30 km, respectively. The observed SAO has also shown seasonal asymmetry in peaks.

  4. Effects of Scattering on the Temperature Stratification in 3D Model Atmospheres of Late-Type Stars

    Science.gov (United States)

    Collet, R.; Hayek, W.; Asplund, M.

    2011-12-01

    Three-dimensional (3D) radiative hydrodynamic model atmospheres of metal-poor late-type stars predict cooler upper photospheric stratifications than their one-dimensional (1D) counterparts. This property of 3D model atmospheres affects the determination of elemental abundances from temperature-sensitive spectral features, with important consequences for galactic chemical evolution studies. In this contribution, we investigate the impact of different approximations of scattering in the solution of the radiative transfer equation on the temperature stratification of 3D model atmospheres of metal-poor red giants. We use the BIFROST code to construct 3D model atmospheres of metal-poor red giants using three different approximations of scattering. First, we self-consistently solve the radiative transfer equation for the general case of a source function with a coherent scattering term; second, we solve the radiative transfer equation assuming a Planckian source function and neglecting altogether the contribution of continuum scattering to extinction in the optically thin layers; third, we assume a Planckian source function and treat continuum scattering as pure absorption everywhere in the simulation's domain. We find that the second approach produces very similar temperature structures with cool upper photospheric layers as when treating scattering correctly, and at a much lower computational cost. In contrast, treating scattering as pure absorption leads to significantly hotter and shallower temperature stratifications.

  5. Variability of the Structure Parameters of Temperature and Humidity Observed in the Atmospheric Surface Layer Under Unstable Conditions

    NARCIS (Netherlands)

    Braam, M.; Moene, A.F.; Beyrich, F.

    2014-01-01

    The structure parameters of temperature and humidity are important in scintillometry as they determine the structure parameter of the refractive index of air, the primary atmospheric variable obtained with scintillometers. In this study, we investigate the variability of the logarithm of the Monin-O

  6. The middle atmospheric circulation of a tidally locked Earth-like planet and the role of the sea surface temperature

    Science.gov (United States)

    Proedrou, Elisavet; Hocke, Klemens; Wurz, Peter

    2016-12-01

    We investigate the influence of the sea surface temperature (SST) changes on the middle atmosphere of a tidally locked Earth-like planet orbiting a G star using the coupled 3D chemistry-climate model CESM1(WACCM). We perform three 90 day simulations. The first simulation is a present-day Earth (PDE) simulation, the second is a simulation of a tidally locked Earth-like planet with a tidally locked aquaplanet sea surface temperature (cold TLE (CLTE)) and the third is a hybrid simulation of a tidally locked Earth-like planet with a present-day Earth sea surface temperature (warm TLE (WTLE)). Our results show that changes in the SST have an influence on the lower stratospheric temperature and the secondary ozone layer. Both atmospheres exhibit a dayside upwelling and a nightside downwelling extending from the surface to the mesosphere. They are also characterised by comparable lower and middle stratospheric horizontal winds and relatively different mesospheric horizontal winds. The temperature of the WTLE atmosphere is altered as a result of the SST changes, compared to the CTLE. Specifically, the WTLE lower tropospheric temperature is increased by 3.7 K on average, due to the absorption of the increased upwelling longwave radiation and the increased sensible and latent heat. The WTLE upper troposphere temperature is decreased by 4 K on average, is adiabatic in nature, and is generated by the increased WTLE upwelling. The WLTE lower stratospheric temperature is increased by 3.8 K on average due to the absorption of the increased upwelling longwave radiation. The lower mesospheric temperature is decreased by 1.13 K on average due to increased mesospheric wave breaking. The upper mesospheric temperature is increased by 4.3 K, and its generation mechanism is currently unknown. Furthermore, the secondary ozone volume mixing ratio is increased by 40.5 %. The occurrence of large-scale vortices and variable jet streams depends, to some extent, on the SST distribution.

  7. Mid-to-late Holocene temperature evolution and atmospheric dynamics over Europe in regional model simulations

    Science.gov (United States)

    Russo, Emmanuele; Cubasch, Ulrich

    2016-08-01

    The improvement in resolution of climate models has always been mentioned as one of the most important factors when investigating past climatic conditions, especially in order to evaluate and compare the results against proxy data. Despite this, only a few studies have tried to directly estimate the possible advantages of highly resolved simulations for the study of past climate change. Motivated by such considerations, in this paper we present a set of high-resolution simulations for different time slices of the mid-to-late Holocene performed over Europe using the state-of-the-art regional climate model COSMO-CLM. After proposing and testing a model configuration suitable for paleoclimate applications, the aforementioned mid-to-late Holocene simulations are compared against a new pollen-based climate reconstruction data set, covering almost all of Europe, with two main objectives: testing the advantages of high-resolution simulations for paleoclimatic applications, and investigating the response of temperature to variations in the seasonal cycle of insolation during the mid-to-late Holocene. With the aim of giving physically plausible interpretations of the mismatches between model and reconstructions, possible uncertainties of the pollen-based reconstructions are taken into consideration. Focusing our analysis on near-surface temperature, we can demonstrate that concrete advantages arise in the use of highly resolved data for the comparison against proxy-reconstructions and the investigation of past climate change. Additionally, our results reinforce previous findings showing that summertime temperatures during the mid-to-late Holocene were driven mainly by changes in insolation and that the model is too sensitive to such changes over Southern Europe, resulting in drier and warmer conditions. However, in winter, the model does not correctly reproduce the same amplitude of changes evident in the reconstructions, even if it captures the main pattern of the pollen

  8. All-Weather Sounding of Moisture and Temperature From Microwave Sensors Using a Coupled Surface/Atmosphere Inversion Algorithm

    Science.gov (United States)

    Boukabara, S. A.; Garrett, K.

    2014-12-01

    A one-dimensional variational retrieval system has been developed, capable of producing temperature and water vapor profiles in clear, cloudy and precipitating conditions. The algorithm, known as the Microwave Integrated Retrieval System (MiRS), is currently running operationally at the National Oceanic and Atmospheric Administration (NOAA) National Environmental Satellite Data and Information Service (NESDIS), and is applied to a variety of data from the AMSU-A/MHS sensors on board the NOAA-18, NOAA-19, and MetOp-A/B polar satellite platforms, as well as SSMI/S on board both DMSP F-16 and F18, and from the NPP ATMS sensor. MiRS inverts microwave brightness temperatures into atmospheric temperature and water vapor profiles, along with hydrometeors and surface parameters, simultaneously. This atmosphere/surface coupled inversion allows for more accurate retrievals in the lower tropospheric layers by accounting for the surface emissivity impact on the measurements. It also allows the inversion of the soundings in all-weather conditions thanks to the incorporation of the hydrometeors parameters in the inverted state vector as well as to the inclusion of the emissivity in the same state vector, which is accounted for dynamically for the highly variable surface conditions found under precipitating atmospheres. The inversion is constrained in precipitating conditions by the inclusion of covariances for hydrometeors, to take advantage of the natural correlations that exist between temperature and water vapor with liquid and ice cloud along with rain water. In this study, we present a full assessment of temperature and water vapor retrieval performances in all-weather conditions and over all surface types (ocean, sea-ice, land, and snow) using matchups with radiosonde as well as Numerical Weather Prediction and other satellite retrieval algorithms as references. An emphasis is placed on retrievals in cloudy and precipitating atmospheres, including extreme weather events

  9. The atmospheric muon flux in correlation with temperature variations in the low stratosphere (50-200 mb).

    Science.gov (United States)

    Bertaina, M.; Briatore, L.; Longhetto, A.; Navarra, G.; EAS-TOP collaboraiton

    The dependence of the muon flux from the atmospheric parameters (pressure and temperature) is a well known effect since long time ago, that is usually corrected for in cosmic ray measurements. We have correlated at EAS-TOP (LNGS) the muon flux detected by the EMD detector (29 stations, 10m2 each, E_thr>3MeV) with the atmospheric temperature (10-1000mb levels) monitored by the radio-soundings of the Aeronautica Militare at Pratica di Mare (Rome). A significant effect has been observed when the muon flux is correlated with the atmospheric temperature in the region 50-200mb (50-200gr/cm2), as expected, since this is the region where the mesons of first generation are produced. The effect becomes even larger (K_T=-9.5+/-1.1)x10-4 K-1) when the variations of the cosmic ray primary flux is taken into account (Neutron Monitor, Rome). Then, the technique has been used to monitor strong temperature variations in the low stratosphere through the muon flux in two periods, showing that the average temperature variations in the low stratosphere are reproduced with a ~2K uncertainty. The main results of this analysis will be presented.

  10. Nonzonal structure of the response of the global field of the Earth's atmospheric temperature to solar activity

    Science.gov (United States)

    Krivolutsky, A. A.; Dement'eva, A. V.

    2017-01-01

    The work describes the results of calculations obtained with the Atmospheric Research Model (ARM) general circulation model. The temperature response of the troposphere and middle atmosphere to variations in UV solar radiation were found to have a large-scale wave structure when planetary waves at the lower model boundary were taken into account. In the present paper, the results from the processing of global temperature fields with three databases (ERA-20C, NOAA-CIRES 20th Century Reanalysis, v2, and NCEP/NCAR Reanalysis I) are provided. Analysis of the differences of the mean monthly temperature global fields (January and July) between the maxima and minima of three solar activity cycles (21, 22, and 23 cycles) also demonstrated their nonzonal structure. It was shown that the amplitude of this difference in January in the stratosphere (10 hPa) can be 7-29 K in the Northern Hemisphere. In July, this effect is prominent in Southern Hemisphere. In the troposphere (500 hPa), a nonzonal temperature effect is present in both the Northern and Southern Hemispheres; the amplitude of the effects amounts to approximately 5-12 K. In conclusion, we discuss that the mechanism of solar energy impact on atmospheric temperature discovered by numerical modeling is supported after reanalysis data processing.

  11. Temperature rise in objects due to optical focused beam through atmospheric turbulence near ground and ocean surface

    Science.gov (United States)

    Stoneback, Matthew; Ishimaru, Akira; Reinhardt, Colin; Kuga, Yasuo

    2013-03-01

    We consider an optical beam propagated through the atmosphere and incident on an object causing a temperature rise. In clear air, the physical characteristics of the optical beam transmitted to the object surface are influenced primarily by the effect of atmospheric turbulence, which can be significant near the ground or ocean surface. We use a statistical model to quantify the expected power transfer through turbulent atmosphere and provide guidance toward the threshold of thermal blooming for the considered scenarios. The bulk thermal characteristics of the materials considered are used in a thermal diffusion model to determine the net temperature rise at the object surface due to the incident optical beam. These results of the study are presented in graphical form and are of particular interest to operators of high power laser systems operating over large distances through the atmosphere. Numerical examples include a CO2 laser (λ=10.6 μm) with: aperture size of 5 cm, varied pulse duration, and propagation distance of 0.5 km incident on 0.1-mm copper, 10-mm polyimide, 1-mm water, and 10-mm glass/resin composite targets. To assess the effect of near ground/ocean laser propagation, we compare turbulent (of varying degrees) and nonturbulent atmosphere.

  12. Online diagnosis of electron excitation temperature in CH4+H2 discharge plasma at atmospheric pressure by optical emission spectra

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Methane coupling under low temperature plasmas at atmospheric pressure is a green process by use of renewable sources of energy. In this study, CH4+H2 dis- charge plasma was on-line diagnosed by optical emission spectra so as to char- acterize the discharge system and to do spade work for the optimization of the technical parameters for future commercial production of methane coupling under plasmas. The study was focused on a calculation method for the online diagnosis of the electron excitation temperature in CH4+H2 discharge plasma at atmospheric pressure. The diagnostic method is easy, efficient and fairly precise. A serious er- ror in a literature was corrected during the reasoning of its series of equations formerly used to calculate electron temperatures in plasmas.

  13. Online diagnosis of electron excitation temperature in CH4+H2 discharge plasma at atmospheric pressure by optical emission spectra

    Institute of Scientific and Technical Information of China (English)

    CUI JinHua; XU ZhenFeng; ZHANG JiaLiang; NIE QiuYue; XU GenHui; REN LongLiang

    2008-01-01

    Methane coupling under low temperature plasmas at atmospheric pressure is a green process by use of renewable sources of energy.In this study,CH4+H2 dis-charge plasma was on-line diagnosed by optical emission spectra so as to char-acterize the discharge system and to do spade work for the optimization of the technical parameters for future commercial production of methane coupling under plasmas.The study was focused on a calculation method for the online diagnosis of the electron excitation temperature in CH4+H2 discharge plasma at atmospheric pressure.The diagnostic method is easy,efficient and fairly precise.A serious er-ror in a literature was corrected during the reasoning of its series of equations formerly used to calculate electron temperatures in plasmas.

  14. The Titan Haze Simulation experiment: laboratory simulation of Titan's atmospheric chemistry at low temperature

    Science.gov (United States)

    Sciamma-O'Brien, E.; Contreras, C. S.; Ricketts, C. L.; Salama, F.

    2012-04-01

    In Titan’s atmosphere, a complex organic chemistry between its two main constituents, N2 and CH4, leads to the production of heavy molecules and subsequently to solid organic aerosols. Several instruments onboard Cassini have detected neutral, positively and negatively charged particles and heavy molecules in the ionosphere of Titan[1,2]. In particular, the presence of benzene (C6H6) and toluene (C6H5CH3)[3], which are critical precursors of polycyclic aromatic hydrocarbon (PAH) compounds, suggests that PAHs might play a role in the production of Titan’s aerosols. The Titan Haze Simulation (THS) experiment has been developed at NASA Ames’ Cosmic Simulation facility (COSmIC) to study the chemical pathways that link the simple precursor molecules resulting from the first steps of the N2-CH4 chemistry (C2H2, C2H4, HCN…) to benzene, and to PAHs and nitrogen-containing PAHs (or PANHs) as precursors to the production of solid aerosols. In the THS experiment, Titan’s atmospheric chemistry is simulated by plasma in the stream of a supersonic jet expansion. With this unique design, the gas mixture is cooled to Titan-like temperature (~150K) before inducing the chemistry by plasma discharge. Different gas mixtures containing the first products of Titan’s N2-CH4 chemistry but also much heavier molecules like PAHs or PANHs can be injected to study specific chemical reactions. The products of the chemistry are detected and studied using two complementary techniques: Cavity Ring Down Spectroscopy[4] and Time-Of-Flight Mass Spectrometry[5]. Thin tholin deposits are also produced in the THS experiment and can be analyzed by Gas Chromatography-Mass Spectrometry (GC-MS) and Scanning Electron Microscopy (SEM). We will present the results of ongoing mass spectrometry studies on the THS experiment using different gas mixtures: N2-CH4, N2-C2H2, N2-C2H4, N2-C2H6, N2-C6H6, and similar mixtures with an N2-CH4 (90:10) mixture instead of pure N2, to study specific pathways

  15. Atmospheric forcing intensifies the effects of regional ocean warming on reef-scale temperature anomalies during a coral bleaching event

    Science.gov (United States)

    Zhang, Zhenlin; Falter, James; Lowe, Ryan; Ivey, Greg; McCulloch, Malcolm

    2013-09-01

    We investigate how local atmospheric conditions and hydrodynamic forcing contributed to local variations in water temperature within a fringing coral reef-lagoon system during the peak of a marine heat wave in 2010-2011 that caused mass coral bleaching across Western Australia. A three-dimensional circulation model Regional Ocean Modeling System (ROMS) with a built-in air-sea heat flux exchange module Coupled Ocean Atmosphere Experiment (COARE) was coupled with a spectral wave model Simulating Waves Nearshore (SWAN) to resolve the surface heat exchange and wave-driven reef circulation in Coral Bay, Ningaloo Reef. Using realistic oceanic and atmospheric forcing, the model predictions were in good agreement with measured time series of water temperature at various locations in the coral reef system during the bleaching event. Through a series of sensitivity analyses, we found that the difference in temperature between the reef and surrounding offshore waters (ΔT) was predominantly a function of both the daily mean net heat flux (Qnet>¯) and residence time, whereas diurnal variations in reef water temperature were dependent on the diurnal fluctuation in the net heat flux. We found that reef temperatures were substantially higher than offshore in the inner lagoon under normal weather conditions and over the entire reef domain under more extreme weather conditions (0.7°C-1.5°C). Although these temperature elevations were still less than that caused by the regional ocean warming (2°C-3°C), the arrival of peak seasonal temperatures in the summer of 2010-2011 (when net atmospheric heat fluxes were positive and abnormally high) caused substantially higher thermal stresses than would have otherwise occurred if offshore temperatures had reached their normal seasonal maxima in autumn (when net atmospheric heat fluxes were negative or cooling). Therefore, the degree heating weeks calculated based on offshore temperature substantially underestimated the thermal stresses

  16. GASEOUS MEAN OPACITIES FOR GIANT PLANET AND ULTRACOOL DWARF ATMOSPHERES OVER A RANGE OF METALLICITIES AND TEMPERATURES

    Energy Technology Data Exchange (ETDEWEB)

    Freedman, Richard S. [SETI Institute, Mountain View, CA (United States); Lustig-Yaeger, Jacob [Department of Physics, University of California, Santa Cruz, CA 95064 (United States); Fortney, Jonathan J. [Department of Astronomy and Astrophysics, University of California, Santa Cruz, CA 95064 (United States); Lupu, Roxana E.; Marley, Mark S. [Space Science and Astrobiology Division, NASA Ames Research Center, Moffett Field, CA (United States); Lodders, Katharina, E-mail: Richard.S.Freedman@nasa.gov [Planetary Chemistry Laboratory, Washington University, St. Louis, MO (United States)

    2014-10-01

    We present new calculations of Rosseland and Planck gaseous mean opacities relevant to the atmospheres of giant planets and ultracool dwarfs. Such calculations are used in modeling the atmospheres, interiors, formation, and evolution of these objects. Our calculations are an expansion of those presented in Freedman et al. to include lower pressures, finer temperature resolution, and also the higher metallicities most relevant for giant planet atmospheres. Calculations span 1 μbar to 300 bar, and 75-4000 K, in a nearly square grid. Opacities at metallicities from solar to 50 times solar abundances are calculated. We also provide an analytic fit to the Rosseland mean opacities over the grid in pressure, temperature, and metallicity. In addition to computing mean opacities at these local temperatures, we also calculate them with weighting functions up to 7000 K, to simulate the mean opacities for incident stellar intensities, rather than locally thermally emitted intensities. The chemical equilibrium calculations account for the settling of condensates in a gravitational field and are applicable to cloud-free giant planet and ultracool dwarf atmospheres, but not circumstellar disks. We provide our extensive opacity tables for public use.

  17. Atmospheric correction for sea surface temperature retrieval from single thermal channel radiometer data onboard Kalpana satellite

    Indian Academy of Sciences (India)

    Naveen R Shahi; Neeraj Agarwal; Aloke K Mathur; Abhijit Sarkar

    2011-06-01

    An atmospheric correction method has been applied on sea surface temperature (SST) retrieval algorithm using Very High Resolution Radiometer (VHRR) single window channel radiance data onboard Kalpana satellite (K-SAT). The technique makes use of concurrent water vapour fields available from Microwave Imager onboard Tropical Rainfall Measuring Mission (TRMM/TMI) satellite. Total water vapour content and satellite zenith angle dependent SST retrieval algorithm has been developed using Radiative Transfer Model [MODTRAN ver3.0] simulations for Kalpana 10.5–12.5 m thermal window channel. Retrieval of Kalpana SST (K-SST) has been carried out for every half-hourly acquisition of Kalpana data for the year 2008 to cover whole annual cycle of SST over Indian Ocean (IO). Validation of the retrieved corrected SST has been carried out using near-simultaneous observations of ship and buoys datasets covering Arabian Sea, Bay of Bengal and IO regions. A significant improvement in Root Mean Square Deviation (RMSD) of K-SST with respect to buoy (1.50–1.02 K) and to ship datasets (1.41–1.19 K) is seen with the use of near real-time water vapour fields of TMI. Furthermore, comparison of the retrieved SST has also been carried out using near simultaneous observations of TRMM/TMI SST over IO regions. The analysis shows that K-SST has overall cold bias of 1.17 K and an RMSD of 1.09 K after bias correction.

  18. On the Observed Relationships between Variability in Gulf Stream Sea Surface Temperatures and the Atmospheric Circulation in the North Atlantic

    Science.gov (United States)

    Wills, Samantha; Thompson, David; Ciasto, Laura

    2016-04-01

    The advent of increasingly high-resolution satellite observations and numerical models has led to a series of advances in our understanding of the role of midlatitude sea surface temperature (SST) in climate variability, especially near western boundary currents (WBC). Observational analyses have suggested that ocean dynamics play a central role in driving interannual SST variability over the Kuroshio-Oyashio and Gulf Stream extensions. Numerical experiments have suggested that variations in the SST field within these WBC regions may have a much more pronounced influence on the atmospheric circulation than previously thought. In this study, the authors examine the observational support for (or against) a robust atmospheric response to midlatitude SST variability in the Gulf Stream extension. To do so, lead/lag analysis based on daily-mean data is applied to assess the evidence for two-way coupling between SST anomalies and the atmospheric circulation on transient timescales, building off of previous studies that have utilized weekly data. A novel decomposition approach is employed to demonstrate that atmospheric circulation anomalies over the Gulf Stream extension can be separated into two distinct patterns of midlatitude atmosphere/ocean interaction: 1) a pattern that peaks 2-3 weeks before the largest SST anomalies in the Gulf Stream extension, which can be viewed as the "atmospheric forcing" and 2) a pattern that peaks several weeks after the largest SST anomalies, which the authors argue can be viewed as the "atmospheric response". The latter pattern is linearly independent of the former, and is interpreted as the potential response of the atmospheric circulation to SST variability in the Gulf Stream extension.

  19. Eutrophication induced CO₂-acidification of subsurface coastal waters: interactive effects of temperature, salinity, and atmospheric PCO₂.

    Science.gov (United States)

    Sunda, William G; Cai, Wei-Jun

    2012-10-02

    Increasing atmospheric carbon dioxide (CO(2)) is raising seawater CO(2) concentrations and thereby acidifying ocean water. But a second environmental problem, eutrophication, is also causing large CO(2) inputs into coastal waters. This occurs because anthropogenic inputs of nutrients have fueled massive algal blooms, which deplete bottom waters of oxygen (O(2)) and release CO(2) when the organic matter from these blooms is respired by bacteria. On the basis of a biogeochemical model, these CO(2) inputs are predicted to decrease current pH values by 0.25 to 1.1 units, effects that increased with decreasing temperature and salinity. Our model predictions agreed well with pH data from hypoxic zones in the northern Gulf of Mexico and Baltic Sea, two eutrophic coastal systems with large temperature and salinity differences. The modeled and measured decreases in pH are well within the range shown to adversely impact marine fauna. Model calculations show that the acidification from respiratory CO(2) inputs interacts in a complex fashion with that from increasing atmospheric CO(2) and that these pH effects can be more than additive in seawater at intermediate to higher temperatures. These interactions have important biological implications in a future world with increasing atmospheric CO(2), increasing anthropogenic inputs of nutrients, and rising temperatures from CO(2)-linked global warming.

  20. Validation of gas temperature measurements by OES in an atmospheric air glow discharge with water electrode using Rayleigh scattering

    Energy Technology Data Exchange (ETDEWEB)

    Verreycken, T; Van Gessel, A F H; Pageau, A; Bruggeman, P, E-mail: p.j.bruggeman@tue.n [Eindhoven University of Technology, Department of Applied Physics, PO Box 513, 5600 MB Eindhoven (Netherlands)

    2011-04-15

    Rayleigh scattering is used to determine the gas temperature of an atmospheric pressure dc excited glow discharge in air with a water electrode. The obtained temperatures are compared with calculated rotational temperatures measured by optical emission spectroscopy of OH(A-X) and N{sub 2}(C-B). At a current of 15 mA a deviation is found between T{sub rot}(OH) and the gas temperature obtained from Rayleigh scattering of about 1000 K. The gas temperatures obtained from Rayleigh scattering, N{sub 2}(C) and OH(A) in the positive column are, respectively, 2600 {+-} 100 K, 2700 {+-} 150 K and 3600 {+-} 200 K. It is shown that the rotational temperature of N{sub 2}(C) is a reliable measurement of the gas temperature while this is not the case for OH(A). The results are explained in the context of quenching processes of the excited states. Spatially resolved gas temperatures in both longitudinal and radial directions are presented. The observed strong temperature gradients near the electrodes are checked to be consistent with the power dissipation and the heat transfer in the discharge. The effect of the polarity of the water electrode and filamentation on the measured temperatures is discussed.

  1. Temperature response of the troposphere and stratosphere to changes in gas and aerosol composition of the atmosphere

    Science.gov (United States)

    Dyominov, I. G.; Zadorozhny, A. M.; Elansky, N. F.

    2003-04-01

    A numerical 2-D zonally averaged interactive model of the troposphere and stratosphere including aerosol physics is used for investigation of temperature changes caused by discharges to the atmosphere of sulphate species during the Pinatubo eruption and by anthropogenic pollution of the atmosphere by CO_2, CH_4, N_2O, CFCs, HCFCs, HFCs, CH_3CCl_3 and CCl_4. The model calculates self-consistently diabatic circulation, temperature, distributions of 45 minor gas constituents, and condensed particles of sulphuric acid hydrate with radii 6.4 nm discharges of sulphate species to the atmosphere during the Pinatubo eruption led to significant changes of sulfate aerosol layer, ozone, and temperature regime of the troposphere and stratosphere. For example, we have in tropics (20oS-20oN) a temperature increase of bout 2.5-3.5 K at altitudes of 22-24 km and decrease of about 0.8-1.0 K at altitudes of 5-8 km. Discharges of sulphate species from the Pinatubo eruption significantly increased also the aerosol optical thickness of the stratosphere, which led to an about 0.3 K decrease in monthly mean global temperature at the Earth's surface by the end of 1992. The calculations of the long-term temperature variations due to anthropogenic emission show that the greatest temperature changes are observed in the Southern Hemisphere in winter/spring periods. For example, the temperature changes at a height of 40 km at 45oS in December 2050 are about -4.85 K, 0.89 K, -2.21 K, and -4.32 K respectively for anthropogenic discharges of CO_2, CH_4, N_2O, and chlorine species. The changes in the Northern Hemisphere are smaller. They are equal to about -4.5 K, 0.68 K, -1.46 K, and -3.17 K at 45oN. The temperature changes in the stratosphere are caused by the corresponding ozone variations and temperature feedbacks. In the troposphere, the temperature changes are determined by the greenhouse effect caused by optically active pollutants. For example, temperature increases near the Earth's surface

  2. High Temperature Corrosion of Fe-C-S Cast Irons in Oxidizing and Sulfidizing Atmospheres

    Institute of Scientific and Technical Information of China (English)

    Thuan-Dinh NGUYEN; Dong-Bok LEE

    2008-01-01

    The corrosion behavior of spheroidal graphite and flake graphite cast irons was studied in oxidizing and sulfidizing atmospheres between 600 and 800℃ for 50 h. The corrosion rate in the sulfidizing atmosphere was faster than that in air above 700℃, due to the formation of the Feo.975S sulfide. The corrosion rate of the spheroidal graphite cast iron was similar to that of the flake graphite cast iron.

  3. Temperature and atmospheric pressure may be considered as predictors for the occurrence of bacillary dysentery in Guangzhou, Southern China

    Directory of Open Access Journals (Sweden)

    Tiegang Li

    2014-06-01

    Full Text Available Introduction The control of bacillary dysentery (BD remains a big challenge for China. Methods Negative binomial multivariable regression was used to study relationships between meteorological variables and the occurrence of BD during the period of 2006-2012. Results Each 1°C rise of temperature corresponded to an increase of 3.60% (95%CI, 3.03% to 4.18% in the monthly number of BD cases, whereas a 1 hPa rise in atmospheric pressure corresponded to a decrease in the number of BD cases by 2.85% (95%CI = 3.34% to 2.37% decrease. Conclusions Temperature and atmospheric pressure may be considered as predictors for the occurrence of BD in Guangzhou.

  4. Simulating Titan’s atmospheric chemistry at low temperature (200K)

    Science.gov (United States)

    Sciamma-O'Brien, Ella; Upton, Kathleen T.; Beauchamp, Jesse L.; Salama, Farid

    2016-06-01

    We present our latest results on the Titan Haze Simulation (THS) experiment developed on the COSmIC simulation chamber at NASA Ames Research Center. In Titan’s atmosphere, a complex organic chemistry induced by UV radiation and electron bombardment occurs between N2 and CH4 and leads to the production of larger molecules and solid aerosols. In the THS, the chemistry is simulated by pulsed plasma in the stream of a supersonic expansion, at Titan-like temperature (150 K). The residence time of the gas in the pulsed plasma discharge is on the order of 3 µs, hence the chemistry is truncated allowing us to probe the first and intermediate steps of the chemistry by adding heavier precursors into the initial N2-CH4 gas mixture.Two complementary studies of the gas phase and solid phase products have been performed in 4 different gas mixtures: N2-CH4, N2-CH4-C2H2, N2-CH4-C6H6 and N2-CH4-C2H2-C6H6 using a combination of in situ and ex situ diagnostics. The mass spectrometry analysis of the gas phase was the first to demonstrate that the THS is a unique tool to monitor the different steps of the N2-CH4 chemistry (Sciamma-O’Brien et al. 2014). The results of the solid phase study are consistent with the chemical growth evolution observed in the gas phase. Grains and aggregates that form in the gas phase were jet deposited on various substrates then collected for ex situ analysis. Scanning Electron Microscopy images have shown that more complex mixtures produce larger aggregates (100-500 nm in N2-CH4, up to 5 µm in N2-CH4-C2H2-C6H6). Moreover, the morphology of the grains seems to depend on the precursors, which could have a large impact for Titan’s models. We will present the latest results of the X-ray Absorption Near Edge Structure measurements, that show the different functional groups present in our samples and give the C/N ratio; as well as the Direct Analysis in Real Time Mass Spectrometry coupled with Collision Induced Dissociation analyses that have been

  5. Design and fabrication of a data logger for atmospheric pressure, temperature and relative humidity for gas-filled detector development

    CERN Document Server

    Sahu, S; Rudra, Sharmili; Biswas, S; Mohanty, B; Sahu, P K

    2015-01-01

    A novel instrument has been developed to monitor and record the ambient pa- rameters such as temperature, atmospheric pressure and relative humidity. These parameters are very essential for understanding the characteristics such as gain of gas filled detectors like Gas Electron Multiplier (GEM) and Multi Wire Propor- tional Counter (MWPC). In this article the details of the design, fabrication and operation processes of the device has been presented.

  6. Quality of fresh retail pork cuts stored in modified atmosphere under temperature conditions simulating export to distant markets.

    Science.gov (United States)

    McMullen, L M; Stiles, M E

    1994-01-01

    The effect of storage temperature on microbial and sensory quality of retail cuts of pork was determined on samples stored under temperature regimens designed to simulate conditions that could be encountered in accessing distant markets with retail-ready product. Samples were packaged in modified atmosphere with 100% CO(2) and export of retail-ready pork cuts to distant markets with a three-week time for delivery to market at -1·5°C can be achieved with one to two weeks of marketing time at retail market at 4 to 7°C.

  7. Gas temperature determination in an argon non-thermal plasma at atmospheric pressure from broadenings of atomic emission lines

    Science.gov (United States)

    Yubero, C.; Rodero, A.; Dimitrijevic, M. S.; Gamero, A.; García, M. C.

    2017-03-01

    In this work a new spectroscopic method, allowing gas temperature determination in argon non-thermal plasmas sustained at atmospheric pressure, is presented. The method is based on the measurements of selected pairs of argon atomic lines (Ar I 603.2 nm/Ar I 549.6 nm, Ar I 603.2 nm/Ar I 522.1 nm, Ar I 549.6 nm/Ar I 522.1 nm). For gas temperature determination using the proposed method, there is no need of knowing the electron density, neither making assumptions on the degree of thermodynamic equilibrium existing in the plasma. The values of the temperatures obtained using this method, have been compared with the rotational temperatures derived from the OH ro-vibrational bands, using both, the well-known Boltzmann-plot technique and the best fitting to simulated ro-vibrational bands. A very good agreement has been found.

  8. Retrievability of atmospheric water vapour, temperature and vertical windspeed profiles from proposed sub-millimetre instrument ORTIS.

    Science.gov (United States)

    Hurley, Jane; Irwin, Patrick; Teanby, Nicholas; de Kok, Remco; Calcutt, Simon; Irshad, Ranah; Ellison, Brian

    2010-05-01

    The sub-millimetre range of the spectrum has been exploited in the field of Earth observation by many instruments over the years and has provided a plethora of information on atmospheric chemistry and dynamics - however, this spectral range has not been fully explored in planetary science. To this end, a sub-millimetre instrument, the Orbiter Terahertz Infrared Spectrometer (ORTIS), is jointly proposed by the University of Oxford and the Rutherford Appleton Laboratory, to meet the requirements of the European Space Agency's Cosmic Visions Europa Jupiter System Mission (EJSM). ORTIS will consist of an infrared and a sub-millimetre component; however in this study only the sub-millimetre component will be explored. The sub-millimetre component of ORTIS is projected to measure a narrow band of frequencies centred at approximately 2.2 THz, with a spectral resolution varying between approximately 1 kHz and 1 MHz, and having an expected noise magnitude of 2 nW/cm2 sr cm-1. In this spectral region, there are strong water and methane emission lines at most altitudes on Jupiter. The sub-millimetre component of ORTIS is designed to measure the abundance of atmospheric water vapour and atmospheric temperature, as well as vertical windspeed profiles from Doppler-shifted emission lines, measured at high spectral resolution. This study will test to see if, in practice, these science objectives may be met from the planned design, as applied to Jupiter. In order to test the retrievability of atmospheric water vapour, temperature and windspeed with the proposed ORTIS design, it is necessary to have a set of "measurements' for which the input parameters (such as species' concentrations, atmospheric temperature, pressure - and windspeed) are known. This is accomplished by generating a set of radiative transfer simulations using radiative transfer model RadTrans in the spectral range sampled by ORTIS, whereby the atmospheric data pertaining to Jupiter have provided by Cassini

  9. Brominated flame retardants in the urban atmosphere of Northeast China: Concentrations, temperature dependence and gas-particle partitioning

    Energy Technology Data Exchange (ETDEWEB)

    Qi, Hong; Li, Wen-Long; Liu, Li-Yan; Song, Wei-Wei; Ma, Wan-Li, E-mail: mawanli002@163.com; Li, Yi-Fan, E-mail: ijrc_pts_paper@yahoo.com

    2014-09-01

    57 pairs of air samples (gas and particle phases) were collected using a high volume air sampler in a typical city of Northeast China. Brominated flame retardants (BFRs) including 13 polybrominated diphenyl ethers (PBDEs, including BDEs 17, 28, 47, 49, 66, 85, 99, 100, 138, 153, 154, 183, and 209) and 9 alternative BFRs (p-TBX, PBBZ, PBT, PBEB, DPTE, HBBZ, γ-HBCD, BTBPE, and DBDPE) were analyzed. The annual average total concentrations of the 13 PBDEs and the 9 alternative BFRs were 69 pg/m{sup 3} and 180 pg/m{sup 3}, respectively. BDE 209 and γ-HBCD were the dominant congeners, according to the one-year study. The partial pressure of BFRs in the gas phase was significantly correlated with the ambient temperature, except for BDE 85, γ-HBCD and DBDPE, indicating the important influence of ambient temperature on the behavior of BFRs in the atmosphere. It was found that the gas–particle partitioning coefficients (logK{sub p}) for most low molecular weight BFRs were highly temperature dependent as well. Gas–particle partitioning coefficients (logK{sub p}) also correlated with the sub-cooled liquid vapor pressure (logP{sub L}{sup o}). Our results indicated that absorption into organic matter is the main control mechanism for the gas–particle partitioning of atmospheric PBDEs. - Highlights: • Both PBDEs and alternative BFRs were analyzed in the atmosphere of Northeast China. • Partial pressure of BFRs was significantly correlated with the ambient temperature. • A strong temperature dependence of gas-particle partitioning was found. • Absorption into organic matter was the control mechanism for G-P partitioning.

  10. Enhanced Vertical Atmosphere Resolution improves Climate Model Simulation of Tropical Atlantic Sea Surface Temperature and Interannual Variability

    Science.gov (United States)

    Harlass, Jan; Latif, Mojib; Park, Wonsun

    2015-04-01

    A long-standing problem in climate modelling is the inaccurate simulation of tropical Atlantic (TA) sea surface temperature (SST), known as the TA SST bias. Basically all state-of-the-art global climate models suffer from a reversed equatorial zonal SST gradient in the Atlantic and too warm surface temperatures in the Benguela upwelling region. These biases have far-reaching consequences for climate prediction as they go along, among others, with erroneous precipitation patterns. We used the coupled atmosphere-ocean-sea ice Kiel Climate Model (KCM) to conduct experiments with varying atmosphere model resolutions, while keeping the ocean component unchanged. Atmosphere model resolution has been increased not only in the horizontal (from T42 to T159), but also in the vertical (from L31 to L62). We show that the TA SST bias can be largely reduced by increasing both the atmospheric horizontal and vertical resolution. In particular, the zonal SST gradient along the equator is simulated with the correct sign. At high horizontal resolution, enhanced vertical resolution is indispensable to substantially improve the simulation of TA SST by enhancing the surface wind stress. This also reduces biases in the upper ocean thermal structure and precipitation. A major step forward is a more northward position of the Intertropical Convergence Zone. Although enhanced horizontal resolution alone leads to some improvement in the mean climate, typical bias patterns, characterized by a reversed zonal SST gradient at the equator and too warm SST along the Benguela Coast, remain. Notable changes in the pattern of interannual SST variability occur with increased resolution. Seasonal phase locking is captured only at high vertical resolution, although a phase lag of 2 months still exists. Our study highlights the importance of sufficiently high atmospheric model resolution and, equally important, a consistent choice of horizontal and vertical model resolution.

  11. A Novel Continuously Initiated Polymerization by One-Atmosphere Low Temperature Plasma Device

    Institute of Scientific and Technical Information of China (English)

    You qingliang; Meng yuedong; Wang jianhua; Ou qiongrong; Xu xu; Zhong shaofeng

    2005-01-01

    A novel atmospheric plasma device developed in this paper, which is more effective and convenient to study the plasma-initiated polymerization (PIP) than conventional setup. The structure and mechanism of the device is introduced. Some plasma-initiated polymerization experiments are carried out on the device, and the conversion of AA (Acrylic acid) and AM (Acryl amide) atmospheric (N2) plasma polymerization are respectively 89% and 94% after 120 h post polymerization, whereby IR spectra of the product (AA, AM). Our PIP result are confirmed.

  12. Elusive anion growth in Titan's atmosphere: Low temperature kinetics of the C3N- + HC3N reaction

    Science.gov (United States)

    Bourgalais, Jérémy; Jamal-Eddine, Nour; Joalland, Baptiste; Capron, Michael; Balaganesh, Muthiah; Guillemin, Jean-Claude; Le Picard, Sébastien D.; Faure, Alexandre; Carles, Sophie; Biennier, Ludovic

    2016-06-01

    Ion chemistry appears to be deeply involved in the formation of heavy molecules in the upper atmosphere of Titan. These large species form the seeds of the organic aerosols responsible for the opaque haze surrounding the biggest satellite of Saturn. The chemical pathways involving individual anions remain however mostly unknown. The determination of the rates of the elementary reactions with ions and the identification of the products are essential to the progress in our understanding of Titan's upper atmosphere. We have taken steps in that direction through the investigation of the low temperature reactivity of C3N- , which was tentatively identified in the spectra measured by the CAPS-ELS instrument of the Cassini spacecraft during its high altitude flybys. The reaction of this anion with HC3N, one of the most abundant trace organics in the atmosphere, has been studied over the 49-294 K temperature range in uniform supersonic flows using the CRESU technique. The proton transfer is found to be the main exit channel (>91%) of the C315N- + HC3N reaction. It remains however indistinguishable with the non-isotopically labeled C314N- reactant. The T - 1 / 2 temperature dependence of this proton transfer reaction and its global rate are reasonably well reproduced theoretically using an average dipole orientation model. A minor exit channel, reactive detachment (anions in the upper atmosphere of Titan. Due to the low branching into the neutral exit channel, it cannot contribute either to the growth of neutrals even assuming a complete mass transfer.

  13. UAS and DTS: Using Drones and Fiber Optics to Measure High Resolution Temperature of the Atmospheric Boundary Layer

    Science.gov (United States)

    Predosa, R. A.; Darricau, B.; Higgins, C. W.

    2015-12-01

    The atmospheric boundary layer (ABL) is the lowest part of the atmosphere that directly interacts with the planet's surface. The development of the ABL plays a vital role, as it affects the transport of atmospheric constituents such as air pollutants, water vapor, and greenhouse gases. Measurements of the processes in the ABL have been difficult due to the limitations in the spatial and temporal resolutions of the equipment as well as the height of the traditional flux tower. Recent advances in the unmanned aerial vehicle (UAV) and distributed temperature sensing (DTS) technologies have provided us with new tools to study the complex processes in ABL. We conducted a series of pioneering experiments in Eastern Oregon using a platform that combines UAV and DTS to collect data during morning and evening transitions in the ABL. The major components of this platform consists of a quad-copter, a DTS computer unit, and a set of customized fiber optic cables. A total of 75 flights were completed to investigate: (1) the capability of a duplexed fiber optic cable to reduce noise in the high spatial and temporal temperature measurements taken during the morning transition; (2) the possibility of using fiber optic cable as "wet bulb" thermometer to calculate relative humidity in the ABL at high spatial and temporal resolution. The preliminary results showed that using a fiber optic cable in a duplexed configuration with the UAV-DTS platform can effectively reduce noise level during the morning transition data collection. The customized "wet bulb" fiber optic cable is capable of providing information for the calculation of relative humidity in the ABL at unprecedented spatial and temporal resolutions. From this study, the UAV-DTS platform demonstrated great potential in collecting temperature data in the ABL and with the development of atmospheric sensor technologies, it will have more applications in the future.

  14. Low-temperature roll-to-roll atmospheric atomic layer deposition of Al₂O₃ thin films.

    Science.gov (United States)

    Ali, Kamran; Choi, Kyung-Hyun

    2014-12-02

    The Al2O3 thin films deposition through conventional ALD systems is a well-established process. The process under low temperatures has been studied by few research groups. In this paper, we report on the detailed study of low-temperature Al2O3 thin films deposited via a unique in-house built system of roll-to-roll atmospheric atomic layer deposition (R2R-AALD) using a multiple-slit gas source head. Al2O3 thin films have been grown on polyethylene terephthalate substrates under a very low-temperature zone of room temperature to 50 °C and working pressure of 750 Torr, which is very near to atmospheric pressure (760 Torr). Al2O3 thin films with superior properties were achieved in the temperature range of the ALD window. An appreciable growth rate of 0.97 Å/cycle was observed for the films deposited at 40 °C. The films have good morphological features with a very low average arithmetic roughness (Ra) of 0.90 nm. The films also showed good chemical, electrical, and optical characteristics. It was observed that the film characteristics improve with the increase in deposition temperature to the range of the ALD window. The fabrication of Al2O3 films was confirmed by X-ray photoelectron spectroscopy (XPS) analysis with the appearance of Al 2p, Al 2s, and O 1s peaks at the binding energies of 74, 119, and 531 eV, respectively. The chemical composition was also supported by the Fourier transform infrared spectroscopy (FTIR). The fabricated Al2O3 films demonstrate good insulating properties and optical transmittance of more than 85% in the visible region. The results state that Al2O3 thin films can be effectively fabricated through the R2R-AALD system at temperatures as low as 40 °C.

  15. Atmospheric Circulation of Hot Jupiters: Dayside-Nightside Temperature Differences. II. Comparison with Observations

    CERN Document Server

    Komacek, Thaddeus D; Tan, Xianyu

    2016-01-01

    The full-phase infrared light curves of low-eccentricity hot Jupiters show a trend of increasing fractional dayside-nightside brightness temperature difference with increasing incident stellar flux, both averaged across the infrared and in each individual wavelength band. The analytic theory of Komacek & Showman (2016) shows that this trend is due to the decreasing ability with increasing incident stellar flux of waves to propagate from day to night and erase temperature differences. Here, we compare the predictions of this theory to observations, showing that it explains well the shape of the trend of increasing dayside-nightside temperature difference with increasing equilibrium temperature. Applied to individual planets, the theory matches well with observations at high equilibrium temperatures but systematically under-predicts the dayside-nightside brightness temperature differences at equilibrium temperatures less than $2000 \\ \\mathrm{K}$. We interpret this as likely due to as the effects of clouds m...

  16. Diversity in neotropical wet forests during the Cenozoic is linked more to atmospheric CO2 than temperature.

    Science.gov (United States)

    Royer, Dana L; Chernoff, Barry

    2013-08-01

    Models generally predict a response in species richness to climate, but strong climate-diversity associations are seldom observed in long-term (more than 10(6) years) fossil records. Moreover, fossil studies rarely distinguish between the effects of atmospheric CO2 and temperature, which limits their ability to identify the causal controls on biodiversity. Plants are excellent organisms for testing climate-diversity hypotheses owing to their strong sensitivity to CO2, temperature and moisture. We find that pollen morphospecies richness in an angiosperm-dominated record from the Palaeogene and early Neogene (65-20 Ma) of Colombia and Venezuela correlates positively to CO2 much more strongly than to temperature (both tropical sea surface temperatures and estimates of global mean surface temperature). The weaker sensitivity to temperature may be due to reduced variance in long-term climate relative to in higher latitudes, or to the occurrence of lethal or sub-lethal temperatures during the warmest times of the Eocene. Physiological models predict that productivity should be the most sensitive to CO2 within the angiosperms, a prediction supported by our analyses if productivity is linked to species richness; however, evaluations of non-angiosperm assemblages are needed to more completely test this idea.

  17. Neutral atmosphere temperature trends and variability at 90 km, 70 °N, 19 °E, 2003-2014

    Science.gov (United States)

    Eriksen Holmen, Silje; Hall, Chris M.; Tsutsumi, Masaki

    2016-06-01

    Neutral temperatures at 90 km height above Tromsø, Norway, have been determined using ambipolar diffusion coefficients calculated from meteor echo fading times using the Nippon/Norway Tromsø Meteor Radar (NTMR). Daily temperature averages have been calculated from November 2003 to October 2014 and calibrated against temperature measurements from the Microwave Limb Sounder (MLS) on board Aura. Large-scale periodic oscillations ranging from ˜ 9 days to a year were found in the data using Lomb-Scargle periodogram analysis, and these components were used to seasonally detrend the daily temperature values before assessing trends. Harmonic oscillations found are associated with the large-scale circulation in the middle atmosphere together with planetary and gravity wave activity. The overall temperature change from 2003 to 2014 is -2.2 K ± 1.0 K decade-1, while in summer (May-June-July) and winter (November-December-January) the change is -0.3 K ± 3.1 K decade-1 and -11.6 K ± 4.1 K decade-1, respectively. The temperature record is at this point too short for incorporating a response to solar variability in the trend. How well suited a meteor radar is for estimating neutral temperatures at 90 km using meteor trail echoes is discussed, and physical explanations behind a cooling trend are proposed.

  18. Atmospheric pressure plasma surface modification of titanium for high temperature adhesive bonding

    NARCIS (Netherlands)

    Akram, M.; Jansen, K.M.B.; Ernst, L.J.; Bhowmik, S.

    2011-01-01

    In this investigation surface treatment of titanium is carried out by plasma ion implantation under atmospheric pressure plasma in order to increase the adhesive bond strength. Prior to the plasma treatment, titanium surfaces were mechanically treated by sand blasting. It is observed that the contac

  19. The Viability with Respect to Temperature of Micro-Organisms Incident on the Earth's Atmosphere

    Science.gov (United States)

    Hoyle, F.; Wickramasinghe, N. C.; Al-Mufti, S.

    Using laboratory measurements of the resistance of E. coli to flash-heating, it is shown that a large fraction of interplanetary micro-organisms in prograde orbits could be added to the Earth without losing viability due to beating by the atmospheric gases.

  20. Which Surface Atmospheric Variable Drives the Seasonal Cycle of Sea Surface Temperature over the Global Ocean?

    Science.gov (United States)

    2009-03-03

    Hydrographic Clima - tology (PHC) to keep the evaporation-precipitation balance on track in the model. The PHC climatology is chosen for its...give similar SSTs [Kara et al, 2008]. [66] As explained in the text, some corrections are applied to the atmospheric forcing from ERA-40. A clima

  1. Method of enhanced lithiation of doped silicon carbide via high temperature annealing in an inert atmosphere

    Science.gov (United States)

    Hersam, Mark C.; Lipson, Albert L.; Bandyopadhyay, Sudeshna; Karmel, Hunter J; Bedzyk, Michael J

    2014-05-27

    A method for enhancing the lithium-ion capacity of a doped silicon carbide is disclosed. The method utilizes heat treating the silicon carbide in an inert atmosphere. Also disclosed are anodes for lithium-ion batteries prepared by the method.

  2. 3D modelling of the early Martian Climate under a denser CO2 atmosphere: Temperatures and CO2 ice clouds

    CERN Document Server

    Forget, Francois; Millour, Ehouarn; Madeleine, Jean-Baptiste; Kerber, Laura; Leconte, Jeremy; Marcq, Emmanuel; Haberle, Robert M

    2012-01-01

    On the basis of geological evidence, it is often stated that the early martian climate was warm enough for liquid water to flow on the surface thanks to the greenhouse effect of a thick atmosphere. We present 3D global climate simulations of the early martian climate performed assuming a faint young sun and a CO2 atmosphere with pressure between 0.1 and 7 bars. The model includes a detailed radiative transfer model using revised CO2 gas collision induced absorption properties, and a parameterisation of the CO2 ice cloud microphysical and radiative properties. A wide range of possible climates is explored by using various values of obliquities, orbital parameters, cloud microphysic parameters, atmospheric dust loading, and surface properties. Unlike on present day Mars, for pressures higher than a fraction of a bar, surface temperatures vary with altitude because of the adiabatic cooling and warming of the atmosphere when it moves vertically. In most simulations, CO2 ice clouds cover a major part of the planet...

  3. Seasonal oscillations of middle atmosphere temperature observed by Rayleigh lidars and their comparisons with TIMED/SABER observations

    Science.gov (United States)

    Dou, Xiankang; Li, Tao; Xu, Jiyao; Liu, Han-Li; Xue, Xianghui; Wang, Shui; Leblanc, Thierry; McDermid, I. Stuart; Hauchecorne, Alain; Keckhut, Philippe; Bencherif, Hassan; Heinselman, Craig; Steinbrecht, Wolfgang; Mlynczak, M. G.; Russell, J. M.

    2009-10-01

    The long-term temperature data sets obtained by Rayleigh lidars at six different locations from low to high latitudes within the Network for the Detection of Atmospheric Composition Change (NDACC) were used to derive the annual oscillations (AO) and semiannual oscillations (SAO) of middle atmosphere temperature: Reunion Island (21.8°S); Mauna Loa Observatory, Hawaii (19.5°N); Table Mountain Facility, California (34.4°N); Observatoire de Haute Provence, France (43.9°N); Hohenpeissenberg, Germany (47.8°N); Sondre Stromfjord, Greenland (67.0°N). The results were compared with those derived from the Sounding of the Atmosphere using Broadband Emission Radiometry (SABER) instrument onboard the Thermosphere-Ionosphere-Mesosphere Energetics and Dynamics (TIMED) satellite. The zonal mean temperatures at similar latitudes show good agreement. The observations also reveal that the AO dominates the seasonal oscillations in both the stratosphere and the mesosphere at middle and high latitudes, with the amplitudes increasing poleward. The SAO oscillations are weaker at all six sites. The oscillations in the upper mesosphere are usually stronger than those in the upper stratosphere with a local minimum near 50-65 km. The upper mesospheric signals are clearly out of phase with upper stratospheric signals. Some differences between lidar and SABER results were found in both the stratosphere and mesosphere. These could be due to: the difference in data sampling between ground-based and space-based instruments, the length of data set, the tidal aliasing owing to the temperature AO and SAO since lidar data are nighttime only, and lidar temperature analysis algorithms. The seasonal oscillations of tidal amplitudes derived from SABER observations suggests that the tidal aliasing of the lidar temperature AO and SAO in the upper mesosphere may over- or under-estimate the real temperature oscillations, depending on the tidal phases. In addition, the possibly unrealistic seasonal

  4. In-situ monitoring of etching of bovine serum albumin using low-temperature atmospheric plasma jet

    Science.gov (United States)

    Kousal, J.; Shelemin, A.; Kylián, O.; Slavínská, D.; Biederman, H.

    2017-01-01

    Bio-decontamination of surfaces by means of atmospheric pressure plasma is nowadays extensively studied as it represents promising alternative to commonly used sterilization/decontamination techniques. The non-equilibrium atmospheric pressure plasmas were already reported to be highly effective in removal of a wide range of biological residual from surfaces. Nevertheless the kinetics of removal of biological contamination from surfaces is still not well understood as the majority of performed studies were based on ex-situ evaluation of etching rates, which did not allow investigating details of plasma action on biomolecules. This study therefore presents a real-time, in-situ ellipsometric characterization of removal of bovine serum albumin (BSA) from surfaces by low-temperature atmospheric plasma jet operated in argon. Non-linear and at shorter distances between treated samples and nozzle of the plasma jet also non-monotonic dependence of the removal rate on the treatment duration was observed. According to additional measurements focused on the determination of chemical changes of treated BSA as well as temperature measurements, the observed behavior is most likely connected with two opposing effects: the formation of a thin layer on the top of BSA deposit enriched in inorganic compounds, whose presence causes a gradual decrease of removal efficiency, and slight heating of BSA that facilitates its degradation and volatilization induced by chemically active radicals produced by the plasma.

  5. TOWARD THE FORMATION OF CARBONACEOUS REFRACTORY MATTER IN HIGH TEMPERATURE HYDROCARBON-RICH ATMOSPHERES OF EXOPLANETS UPON MICROMETEOROID IMPACT

    Energy Technology Data Exchange (ETDEWEB)

    Dangi, Beni B.; Kim, Yong S.; Krasnokutski, Serge A.; Kaiser, Ralf I. [Department of Chemistry, University of Hawai’i at Manoa, Honolulu, HI 96822 (United States); Bauschlicher Jr, Charles W. [Entry Systems and Technology Division, NASA Ames Research Center, Moffett Field, CA 94035 (United States)

    2015-05-20

    We report on laboratory simulation experiments mimicking the chemical processing of model atmospheres of exoplanets containing C3 and C4 hydrocarbons at moderate temperatures of 400 K upon interaction of catalytic surfaces of micrometeoroids. By utilizing an ultrasonic levitator device and heating singly levitated particles under simulated microgravity conditions, Raman spectroscopy is utilized as a non-invasive tool to probe on line and in situ the conversion of C3 and C4 hydrocarbons to refractory carbonaceous matter on the surfaces of levitated particles. Secondary Ion Mass Spectrometry and electron microscopic imaging were also conducted to gain further insight into the elementary composition and structures of the refractories formed. Our results provide compelling evidence that in the presence of a catalytic surface, which can be supplied in the form of micrometeoroids and atmospheric dust particles, hydrocarbon gases present in the atmospheres of exoplanets can be converted to refractory, carbon-rich carbonaceous matter of mainly graphitic structure with a carbon content of at least 90% at elevated temperatures. This finding might explain the low methane to carbon monoxide (CH{sub 4}–CO) ratio in the hot Neptune GJ 436b, where the abundant methane photochemically converts to higher order hydrocarbons and ultimately to refractory graphite-like carbon in the presence of a silicon surface.

  6. Effective temperatures, rotational velocities, microturbulent velocities and abundances in the atmospheres of the Sun,. HD1835 and HD10700

    CERN Document Server

    Pavlenko, Ya V; Jones, H R A; Ivanyuk, O; Pinfield, D J

    2012-01-01

    We describe our procedure to determine effective temperatures, rotational velocities, microturbulent velocities, and chemical abundances in the atmospheres of Sun-like stars. We use independent determinations of iron abundances using the fits to the observed Fe I and Fe II atomic absorption lines. We choose the best solution from the fits to these spectral features for the model atmosphere that provides the best confidence in the determined log N(Fe), Vt, and vsini. First, we compute the abundance of iron for a set of adopted microturbulent velocities. To determine the most self-consistent effective temperature and microturbulent velocity in any star's atmosphere, we used an additional constraint where we minimise the dependence of the derived abundances of Fe I and Fe II on the excitation potential of the corresponding lines. We analyse the spectra of the Sun and two well known solar type stars, HD1835 and HD10700 to determine their abundances, microturbulent velocity and rotational velocity. For the Sun abu...

  7. High temperature properties of ceramic fibers and insulations for thermal protection of atmospheric entry and hypersonic cruise vehicles

    Science.gov (United States)

    Kourtides, Demetrius A.; Pitts, William C.; Araujo, Myrian; Zimmerman, R. S.

    1988-01-01

    Multilayer insulations (MIs) which will operate in the 500 to 1000 C temperature range are being considered for possible applications on aerospace vehicles subject to convective and radiative heating during atmospheric entry. The insulations described consist of ceramic fibers, insulations, and metal foils quilted together with ceramic thread. As these types of insulations have highly anisotropic properties, the total heat transfer characteristics must be determined. Data are presented on the thermal diffusivity and thermal conductivity of four types of MIs and are compared to the baseline Advanced Flexible Reusable Surface Insulation currently used on the Space Shuttle Orbiter. In addition, the high temperature properties of the fibers used in these MIs are discussed. The fibers investigated included silica and three types of aluminoborosilicate (ABS). Static tension tests were performed at temperatures up to 1200 C and the ultimate strain, tensile strength, and tensile modulus of single fibers were determined.

  8. High-temperature and high-speed oxidation of 4H-SiC by atmospheric pressure thermal plasma jet

    Science.gov (United States)

    Hanafusa, Hiroaki; Ishimaru, Ryosuke; Higashi, Seiichiro

    2017-04-01

    The application of atmospheric pressure thermal plasma jet (TPJ) annealing to the high-temperature and high-speed thermal oxidation of Si-face of 4H-SiC wafer is reported. A high SiO2 film growth rate of 288 nm min‑1 was obtained at an oxidation temperature of 1640 °C without intentional dry O2 gas feeding. Ambient analysis suggested that ozone generated from oxygen in the ambient air by the plasma irradiation was supplied to the SiC surface. It is implied that a mono-oxygen decomposed from ozone was diffused into the oxide growth interface. As a result, high-speed oxidation occurred by combination of high-temperature TPJ annealing and ozone feeding.

  9. The Mathematical Representation of Wind Speed and Temperature Profiles in the Unstable Atmospheric Surface Layer

    DEFF Research Database (Denmark)

    Paulson, C.A.

    1970-01-01

    Analytical expressions which specify non-dimensionalized wind speed and potential temperature gradients as functions of stability are integrated. The integrated equations are tested against Swinhank's wind and temperature profiles measured at Kerang, Australia. It is found that a representation s...... suggested independently by Businger and by Dyer gives the best fit to temperature profiles and describes the wind profiles equally as well as a relation suggested by Panofsky et al....

  10. Thermal infrared cross-sections of C{sub 2}F{sub 6} at atmospheric temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Zou, Q.; Sun, C.; Nemtchinov, V.; Varanasi, P. E-mail: pvaranasi@notes.cc.sunysb.edu

    2004-01-15

    Spectral absorption cross-sections, k{sub {nu}} (cm{sup -1} atm{sup -1}), have been measured in the 8.0 and 8.95 {mu}m bands of C{sub 2}F{sub 6}. Temperature and total (N{sub 2}-broadening) pressure have been varied to represent the conditions specified in various models of the terrestrial atmosphere so that the absorption cross-sections can be applied directly to the optical remote-sensing of C{sub 2}F{sub 6} in the atmosphere. The measured absolute intensities of the 8.0 and the 8.95 {mu}m bands are (1.636{+-}0.003)x10{sup -16} and (0.467{+-}0.0018)x10{sup -16} cm molecule{sup -1}, respectively.

  11. Atmospheric circulation in regional climate models over Central Europe: links to surface air temperature and the influence of driving data

    Energy Technology Data Exchange (ETDEWEB)

    Plavcova, Eva [Institute of Atmospheric Physics, Academy of Sciences of the Czech Republic, Prague 4 (Czech Republic); Technical University, Department of Applied Mathematics, Liberec (Czech Republic); Charles University, Faculty of Mathematics and Physics, Prague (Czech Republic); Kysely, Jan [Institute of Atmospheric Physics, Academy of Sciences of the Czech Republic, Prague 4 (Czech Republic); Technical University, Department of Applied Mathematics, Liberec (Czech Republic)

    2012-10-15

    The study examines simulation of atmospheric circulation, represented by circulation indices (flow direction, strength and vorticity), and links between circulation and daily surface air temperatures in regional climate models (RCMs) over Central Europe. We explore control simulations of five high-resolution RCMs from the ENSEMBLES project driven by re-analysis (ERA-40) and the same global climate model (ECHAM5 GCM) plus of one RCM (RCA) driven by different GCMs. The aims are to (1) identify errors in RCM-simulated distributions of circulation indices in individual seasons, (2) identify errors in simulated temperatures under particular circulation indices, and (3) compare performance of individual RCMs with respect to the driving data. Although most of the RCMs qualitatively reflect observed distributions of the airflow indices, each produces distributions significantly different from the observations. General biases include overestimation of the frequency of strong flow days and of strong cyclonic vorticity. Some circulation biases obviously propagate from the driving data. ECHAM5 and all simulations driven by ECHAM5 underestimate frequency of easterly flow, mainly in summer. Except for HIRHAM, however, all RCMs driven by ECHAM5 improve on the driving GCM in simulating atmospheric circulation. The influence on circulation characteristics in the nested RCM differs between GCMs, as demonstrated in a set of RCA simulations with different driving data. The driving data control on circulation in RCA is particularly weak for the BCM GCM, in which case RCA substantially modifies (but does not improve) the circulation from the driving data in both winter and summer. Those RCMs with the most distorted atmospheric circulation are HIRHAM driven by ECHAM5 and RCA driven by BCM. Relatively strong relationships between circulation indices and surface air temperatures were found in the observed data for Central Europe. The links differ by season and are usually stronger for

  12. Isoepoxydon dehydrogenase (idh) gene expression in relation to patulin production by Penicillium expansum under different temperature and atmosphere.

    Science.gov (United States)

    De Clercq, N; Vlaemynck, G; Van Pamel, E; Van Weyenberg, S; Herman, L; Devlieghere, F; De Meulenaer, B; Van Coillie, E

    2016-03-02

    Penicillium expansum growth and patulin production occur mainly at post-harvest stage during the long-term storage of apples. Low temperature in combination with reduced oxygen concentrations is commonly applied as a control strategy to extend apple shelf life and supply the market throughout the year. Our in vitro study investigated the effect of temperature and atmosphere on expression of the idh gene in relation to the patulin production by P. expansum. The idh gene encodes the isoepoxydon dehydrogenase enzyme, a key enzyme in the patulin biosynthesis pathway. First, a reverse transcription real-time PCR (RT-qPCR) method was optimized to measure accurately the P. expansum idh mRNA levels relative to the mRNA levels of three reference genes (18S, β-tubulin, calmodulin), taking into account important parameters such as PCR inhibition and multiple reference gene stability. Subsequently, two P. expansum field isolates and one reference strain were grown on apple puree agar medium (APAM) under three conditions of temperature and atmosphere: 20 °C - air, 4 °C - air and 4 °C - controlled atmosphere (CA; 3% O2). When P. expansum strains reached a 0.5 and 2.0 cm colony diameter, idh expression and patulin concentrations were determined by means of the developed RT-qPCR and an HPLC-UV method, respectively. The in vitro study showed a clear reduction in patulin production and down-regulation of the idh gene expression when P. expansum was grown under 4 °C - CA. The results suggest that stress (low temperature and oxygen level) caused a delay of the fungal metabolism rather than a complete inhibition of toxin biosynthesis. A good correlation was found between the idh expression and patulin production, corroborating that temperature and atmosphere affected patulin production by acting at the transcriptional level of the idh gene. Finally, a reliable RT-qPCR can be considered as an alternative tool to investigate the effect of control strategies on the toxin formation in

  13. Interdecadal Variations of Precipitation and Temperature in China Around the Abrupt Change of Atmospheric Circulation in 1976

    Institute of Scientific and Technical Information of China (English)

    LI Chunhui; WAN Qilin; LIN Ailan; GU Dejun; ZHENG Bin

    2009-01-01

    The interdecadal characteristics of rainfall and temperature in China before and after the abrupt change of the general circulation in 1976 are analyzed using the global 2.5°×2.5° monthly mean reanalysis data from the National Centers for Environmental Prediction of US and the precipitation and temperature data at the 743 stations of China from the National Climate Center of China. The results show that after 1976, springtime precipitation and temperature were anomalously enhanced and reduced respectively in South China, while the reverse was true in the western Yangtze River basin. In summer, precipitation was anomalously less in South China, more in the Yangtze River basin, less again in North China and more again in Northeast China, showing a distribution pattern alternating with negative and positive anomalies ("-, +, -, +"). Meanwhile, temperature shows a distribution of warming in South China, cooling in the Yangtze and Huaihe River basins, and warming again in northern China. In autumn, precipitation tended to decrease and temperature tended to increase in most parts of the country. In winter, precipitation increased moderately in South China and warming was the trend across all parts of China. The interdecadal decline of mean temperature in spring and summer in China was mainly due to the daily maximum temperature variation, while the interdecadal increase was mainly the result of the minimum temperature change. The overall warming in autumn (winter) was mostly influenced by the minimum (maximum) temperature variation. These changes were closely related to the north-south shifts of the ascending and descending branches of the Hadley cell, the strengthening and north-south progression of the westerly jet stream, and the atmospheric stratification and water vapor transport conditions.

  14. Atmospheric Circulation of Hot Jupiters: Dayside–Nightside Temperature Differences. II. Comparison with Observations

    Science.gov (United States)

    Komacek, Thaddeus D.; Showman, Adam P.; Tan, Xianyu

    2017-02-01

    The full-phase infrared light curves of low-eccentricity hot Jupiters show a trend of increasing fractional dayside–nightside brightness temperature difference with increasing incident stellar flux, both averaged across the infrared and in each individual wavelength band. The analytic theory of Komacek & Showman shows that this trend is due to the decreasing ability with increasing incident stellar flux of waves to propagate from day to night and erase temperature differences. Here, we compare the predictions of this theory with observations, showing that it explains well the shape of the trend of increasing dayside–nightside temperature difference with increasing equilibrium temperature. Applied to individual planets, the theory matches well with observations at high equilibrium temperatures but, for a fixed photosphere pressure of 100 {mbar}, systematically underpredicts the dayside–nightside brightness temperature differences at equilibrium temperatures less than 2000 {{K}}. We interpret this as being due to the effects of a process that moves the infrared photospheres of these cooler hot Jupiters to lower pressures. We also utilize general circulation modeling with double-gray radiative transfer to explore how the circulation changes with equilibrium temperature and drag strengths. As expected from our theory, the dayside–nightside temperature differences from our numerical simulations increase with increasing incident stellar flux and drag strengths. We calculate model phase curves using our general circulation models, from which we compare the broadband infrared offset from the substellar point and dayside–nightside brightness temperature differences against observations, finding that strong drag or additional effects (e.g., clouds and/or supersolar metallicities) are necessary to explain many observed phase curves.

  15. Future Changes Projections of Atmospheric Circulation and Precipitation and Temperature Patterns Over South America in Austral Summer

    Science.gov (United States)

    Shimizu, M. H.; Cavalcanti, I. F.

    2012-12-01

    Atmospheric circulation is primarily driven by temperature gradients across the globe due to differential heating of Earth's surface which leads to a surplus of energy in the tropics and a deficit in the high latitudes. However, due to global warming, changes in atmospheric circulation are expected, which could result in modifications also in precipitation pattern. There are some evidences of changes in atmospheric circulation, such as the expansion of tropical belt and the poleward shift of large-scale atmospheric circulation systems, such as jet streams. These changes can be enhanced in a scenario with increasing greenhouse gases concentration. The objective of this study was to analyze future changes of atmospheric circulation and precipitation and temperature patterns in the austral summer over South America under Representative Pathway Concentration 8.5 (RCP 8.5) emission scenario. This evaluation was made according to model projections based on the coordinated climate change experiments defined by Coupled Model Intercomparison Project phase 5 (CMIP5). Historical simulations were used to evaluate model performance in reproduce main climatic features over South America in the Austral Summer. This analysis showed that some models perform better than others, with a wide range of difference between simulations and Global Precipitation Climatology Project (GPCP) and European Centre for Medium-Range Weather Forecasts (ECMWF) ERA-Interim data sets. In general, the models captured the main features of Austral Summer such as the northwest-southeast precipitation band associated with the South Atlantic Convergence Zone (SACZ) and the anticyclonic circulation at high levels related to Bolivian High. The projections from different models pointed out in general to a reduction of precipitation, however the signal was not the same over all the continent and for all models. For example, Met Office's HadGEM2-ES projection indicated a reduction of precipitation in most of

  16. Spectroscopic Evidence for a Temperature Inversion in the Dayside Atmosphere of the Hot Jupiter WASP-33b

    CERN Document Server

    Haynes, Korey; Madhusudhan, Nikku; Deming, Drake; Knutson, Heather

    2015-01-01

    We present observations of two occultations of the extrasolar planet WASP-33b using the Wide Field Camera 3 (WFC3) on the HST, which allow us to constrain the temperature structure and composition of its dayside atmosphere. WASP-33b is the most highly irradiated hot Jupiter discovered to date, and the only exoplanet known to orbit a delta-Scuti star. We observed in spatial scan mode to decrease instrument systematic effects in the data, and removed fluctuations in the data due to stellar pulsations. The RMS for our final, binned spectrum is approximately 1.05 times the photon noise. We compare our final spectrum, along with previously published photometric data, to atmospheric models of WASP-33b spanning a wide range in temperature profiles and chemical compositions. We find that the data require models with an oxygen-rich chemical composition and a temperature profile that increases at high altitude. We also find that our spectrum displays an excess in the measured flux towards short wavelengths that is best...

  17. Temperature-Pressure Profile of the hot Jupiter HD 189733b from HST Sodium Observations: Detection of Upper Atmospheric Heating

    CERN Document Server

    Huitson, Catherine M; Vidal-Madjar, Alfred; Ballester, Gilda E; Etangs, Alain Lecavelier des; Désert, Jean-Michel; Pont, Frédéric

    2012-01-01

    We present transmission spectra of the hot Jupiter HD 189733b taken with the Space Telescope Imaging Spectrograph aboard HST. The spectra cover the wavelength range 5808-6380 Ang with a resolving power of R=5000. We detect absorption from the NaI doublet within the exoplanet's atmosphere at the 9 sigma confidence level within a 5 Ang band (absorption depth 0.09 +/- 0.01%) and use the data to measure the doublet's spectral absorption profile. We detect only the narrow cores of the doublet. The narrowness of the feature could be due to an obscuring high-altitude haze of an unknown composition or a significantly sub-solar NaI abundance hiding the line wings beneath a H2 Rayleigh signature. We compare the spectral absorption profile over 5.5 scale heights with model spectral absorption profiles and constrain the temperature at different atmospheric regions, allowing us to construct a vertical temperature profile. We identify two temperature regimes; a 1280 +/- 240 K region derived from the NaI doublet line wings ...

  18. Influence of land-atmosphere feedbacks on temperature and precipitation extremes in the GLACE-CMIP5 ensemble

    Science.gov (United States)

    Lorenz, Ruth; Argüeso, Daniel; Donat, Markus G.; Pitman, Andrew J.; Hurk, Bart; Berg, Alexis; Lawrence, David M.; Chéruy, Frédérique; Ducharne, Agnès.; Hagemann, Stefan; Meier, Arndt; Milly, P. C. D.; Seneviratne, Sonia I.

    2016-01-01

    We examine how soil moisture variability and trends affect the simulation of temperature and precipitation extremes in six global climate models using the experimental protocol of the Global Land-Atmosphere Coupling Experiment of the Coupled Model Intercomparison Project, Phase 5 (GLACE-CMIP5). This protocol enables separate examinations of the influences of soil moisture variability and trends on the intensity, frequency, and duration of climate extremes by the end of the 21st century under a business-as-usual (Representative Concentration Pathway 8.5) emission scenario. Removing soil moisture variability significantly reduces temperature extremes over most continental surfaces, while wet precipitation extremes are enhanced in the tropics. Projected drying trends in soil moisture lead to increases in intensity, frequency, and duration of temperature extremes by the end of the 21st century. Wet precipitation extremes are decreased in the tropics with soil moisture trends in the simulations, while dry extremes are enhanced in some regions, in particular the Mediterranean and Australia. However, the ensemble results mask considerable differences in the soil moisture trends simulated by the six climate models. We find that the large differences between the models in soil moisture trends, which are related to an unknown combination of differences in atmospheric forcing (precipitation, net radiation), flux partitioning at the land surface, and how soil moisture is parameterized, imply considerable uncertainty in future changes in climate extremes.

  19. A Pilot Study of Ion - Molecule Reactions at Temperatures Relevant to the Atmosphere of Titan

    Science.gov (United States)

    Zymak, Illia; Žabka, Ján; Polášek, Miroslav; Španěl, Patrik; Smith, David

    2016-11-01

    Reliable theoretical models of the chemical kinetics of the ionosphere of Saturn's moon, Titan, is highly dependent on the precision of the rates of the reactions of ambient ions with hydrocarbon molecules at relevant temperatures. A Variable Temperature Selected Ions Flow Tube technique, which has been developed primarily to study these reactions at temperatures within the range of 200-330 K, is briefly described. The flow tube temperature regulation system and the thermalisation of ions are also discussed. Preliminary studies of two reactions have been carried out to check the reliability and efficacy of kinetics measurements: (i) Rate constants of the reaction of CH3 + ions with molecular oxygen were measured at different temperatures, which indicate values in agreement with previous ion cyclotron resonance measurements ostensibly made at 300 K. (ii) Formation of CH3 + ions in the reaction of N2 + ions with CH4 molecules were studied at temperatures within the range 240-310 K which showed a small but statistically significant decrease of the ratio of product CH3 + ions to reactant N2 + ions with reaction temperature.

  20. Transfer and distortion of atmospheric information in the satellite temperature retrieval problem

    Science.gov (United States)

    Thompson, O. E.

    1981-01-01

    A systematic approach to investigating the transfer of basic ambient temperature information and its distortion by satellite systems and subsequent analysis algorithms is discussed. The retrieval analysis cycle is derived, the variance spectrum of information is examined as it takes different forms in that process, and the quality and quantity of information existing at each stop is compared with the initial ambient temperature information. Temperature retrieval algorithms can smooth, add, or further distort information, depending on how stable the algorithm is, and how heavily influenced by a priori data.

  1. Absolute cross sections of ozone at atmospheric temperatures for the Wulf and the Chappuis bands

    Science.gov (United States)

    Helou, Z. El; Churassy, S.; Wannous, G.; Bacis, R.; Boursey, E.

    2005-06-01

    Ozone absorption constitutes a variable background against which measurement of pollution is observed from satellites by the solar occultation technique. The temperature-altitude gradient of ozone spans the range 180-340K. Laboratory measurements of ozone absorption at temperatures across this range are needed to calibrate spectroscopic remote sensing, but have yielded results in substantial disagreement with each other. This paper presents the first measurements of the variation of absorption cross-sections of ozone at temperatures from 144to300K over the 9250-18 500cm-1 spectral region.

  2. High-Temperature Properties of Ceramic Fibers and Insulations for Thermal Protection of Atmospheric Entry and Hypersonic Cruise Vehicles

    Science.gov (United States)

    Kourtides, Demetrius A.; Pitts, William C.; Araujo, Myrian; Zimmerman, R. S.

    1988-01-01

    Multilayer insulations which will operate in the 500C to 1000C temperature range are being considered for possible applications on aerospace vehicles subject to convective and radiative heating during atmospheric entry. The insulations described in this paper consist of ceramic fabrics, insulations, and metal foils quilted together using ceramic thread. As these types of insulations have highly anisotropic properties, the total heat transfer characteristics of these insulations must be determined. Data are presented on the thermal diffusivity and thermal conductivity of four types of multilayer insulations and are compared to the baseline Advanced Flexible Reusable Surface Insulation

  3. High Temperature Energy Storage for In Situ Planetary Atmospheric Measurement Technologies Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Development of energy storage capable of operational temperatures of 380:C and 486oC with a specific capacity 200 Wh/kg for use as a power source on the Venusian...

  4. Global atmospheric change and herbivory: Effects of elevated levels of UV-B radiation, atmospheric CO{sub 2} and temperature on boreal woody plants and their herbivores

    Energy Technology Data Exchange (ETDEWEB)

    Veteli, T.

    2003-07-01

    The aim of this study was to assess the effects of elevated ultraviolet-B radiation (UV-B, 280- 320 nm), atmospheric CO{sub 2}, temperature and soil nitrogen level on the growth and chemical quality of boreal deciduous woody plants and on performance of the herbivorous insects feeding on them. Eggs and larvae of Operophtera brumata (L.) (Lepidoptera, Geometridae) were subjected to elevated UV-B radiation in the laboratory. Two willow species, Salix phylicifolia L. (Salicaceae) and S. myrsinifolia Salisb., were grown in an UV-B irradiation field where the responses of both plants and their herbivorous insects were monitored. S. myrsinifolia, Betula pendula Ehrh. (Betulaceae) and B. pubescens Roth. were subjected to elevated CO{sub 2} and temperature and different fertilisation levels in closed-top climatic chambers. To assess the indirect effects of the different treatments, the leaves of experimental willows and birches were fed to larvae of Phratora vitellinae (L.) (Coleoptera, Chrysomelidae) and adults of Agellastica alni L. in the laboratory. Elevated UV-B radiation significantly decreased the survival and performance of eggs and larvae of O. brumata. It also increased concentrations of some flavonoids and phenolic acids in S. myrsinifolia and S. phylicifolia, while the low-UV-B- absorbing phenolics, e. g. condensed tannins, gallic acid derivatives and salicylates, either decreased or remained unaffected. Both the height growth and biomass of one S. phylicifolia clone was sensitive to elevated levels of UV-B radiation. Abundance of adults and larvae of a willow- feeding leaf beetle, P. vitellinae, was increased under elevated UV-B; but this did not lead to increased leaf damage on the host plants. There were no significant differences in performance of the larvae feeding on differentially treated willow leaves, but adult A. alni preferred UV-B-treated leaves to ambient control leaves. Elevated CO{sub 2} and temperature significantly increased the height growth

  5. NOAA Climate Data Record (CDR) of Reflectance and Brightness Temperatures from AVHRR Pathfinder Atmospheres - Extended (PATMOS-x), Version 5.3

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This NOAA Climate Data Record (CDR) of AVHRR reflectance and brightness temperatures was produced by the University of Wisconsin using the AVHRR Pathfinder...

  6. Relationships of surface air temperature anomalies over Europe to persistence of atmospheric circulation patterns conducive to heat waves

    Directory of Open Access Journals (Sweden)

    J. Kyselý

    2008-04-01

    Full Text Available Heat waves are among natural hazards with the most severe consequences for human society, including pronounced mortality impacts in mid-latitudes. Recent studies have hypothesized that the enhanced persistence of atmospheric circulation may affect surface climatic extremes, mainly the frequency and severity of heat waves. In this paper we examine relationships between the persistence of the Hess-Brezowsky circulation types conducive to summer heat waves and air temperature anomalies at stations over most of the European continent. We also evaluate differences between temperature anomalies during late and early stages of warm circulation types in all seasons. Results show that more persistent circulation patterns tend to enhance the severity of heat waves and support more pronounced temperature anomalies. Recent sharply rising trends in positive temperature extremes over Europe may be related to the greater persistence of the circulation types, and if similar changes towards enhanced persistence affect other mid-latitudinal regions, analogous consequences and implications for temperature extremes may be expected.

  7. An atmospheric pressure high-temperature laminar flow reactor for investigation of combustion and related gas phase reaction systems

    Energy Technology Data Exchange (ETDEWEB)

    Oßwald, Patrick; Köhler, Markus [Institute of Combustion Technology, German Aerospace Center (DLR), Pfaffenwaldring 38-40, D-70569 Stuttgart (Germany)

    2015-10-15

    A new high-temperature flow reactor experiment utilizing the powerful molecular beam mass spectrometry (MBMS) technique for detailed observation of gas phase kinetics in reacting flows is presented. The reactor design provides a consequent extension of the experimental portfolio of validation experiments for combustion reaction kinetics. Temperatures up to 1800 K are applicable by three individually controlled temperature zones with this atmospheric pressure flow reactor. Detailed speciation data are obtained using the sensitive MBMS technique, providing in situ access to almost all chemical species involved in the combustion process, including highly reactive species such as radicals. Strategies for quantifying the experimental data are presented alongside a careful analysis of the characterization of the experimental boundary conditions to enable precise numeric reproduction of the experimental results. The general capabilities of this new analytical tool for the investigation of reacting flows are demonstrated for a selected range of conditions, fuels, and applications. A detailed dataset for the well-known gaseous fuels, methane and ethylene, is provided and used to verify the experimental approach. Furthermore, application for liquid fuels and fuel components important for technical combustors like gas turbines and engines is demonstrated. Besides the detailed investigation of novel fuels and fuel components, the wide range of operation conditions gives access to extended combustion topics, such as super rich conditions at high temperature important for gasification processes, or the peroxy chemistry governing the low temperature oxidation regime. These demonstrations are accompanied by a first kinetic modeling approach, examining the opportunities for model validation purposes.

  8. Low Temperature Performance of Selective Catalytic Reduction of NO with NH3 under a Concentrated CO2 Atmosphere

    Directory of Open Access Journals (Sweden)

    Xiang Gou

    2015-10-01

    Full Text Available Selective catalytic reduction of NOx with NH3 (NH3-SCR has been widely investigated to reduce NOx emissions from combustion processes, which cause environmental challenges. However, most of the current work on NOx reduction has focused on using feed gas without CO2 or containing small amounts of CO2. In the future, oxy-fuel combustion will play an important role for power generation, and this process generates high concentrations of CO2 in flue gas. Therefore, studies on the SCR process under concentrated CO2 atmosphere conditions are important for future SCR deployment in oxy-fuel combustion processes. In this work, Mn- and Ce-based catalysts using activated carbon as support were used to investigate the effect of CO2 on NO conversion. A N2 atmosphere was used for comparison. Different process conditions such as temperature, SO2 concentration, H2O content in the feed gas and space velocity were studied. Under Mn-Ce/AC conditions, the results suggested that Mn metal could reduce the inhibition effect of CO2 on the NO conversion, while Ce metal increased the inhibition effect of CO2. High space velocity also resulted in a reduction of CO2 inhibition on the NO conversion, although the overall performance of SCR was greatly reduced at high space velocity. Future investigations to design novel Mn-based catalysts are suggested to enhance the SCR performance under concentrated CO2 atmosphere conditions.

  9. Sintering temperature and atmosphere modulated evolution of structure and luminescence of 2CaO-P2O5-B2O3

    DEFF Research Database (Denmark)

    Zhu, C. F.; Wang, J.; Ren, X. R.

    2014-01-01

    Europium doped 2CaO-P2O5-B2O3 phosphors prepared via high temperature solid state reactions are reported. The evolution of luminescence and structure of the phosphors induced by variation of sintering temperature and atmosphere is investigated using photoluminescence spectra and X-ray diffraction...... techniques. We found that the optical performance and structure of the phosphors are sensitive to the sintering temperature and atmosphere. The luminescence intensity due to 5D0 → 7F2 transition of Eu3+ is decreased with increasing sintering temperature. CaBPO5 and BPO4 crystals co-exist in the as...

  10. Daily changes of radon concentration in soil gas under influence of atmospheric factors: room temperature, soil surface temperature and relative humidity

    Energy Technology Data Exchange (ETDEWEB)

    Lara, Evelise G.; Oliveira, Arno Heeren de, E-mail: evelise.lara@gmail.com, E-mail: heeren@nuclear.ufmg.br [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Departamento de Engenharia Nuclear; Rocha, Zildete; Rios, Francisco Javier, E-mail: rochaz@cdtn.br, E-mail: javier@cdtn.br [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)

    2015-07-01

    This work aims at relating the daily change in the radon concentration in soil gas in a Red Yellow Acrisol (SiBCS) under influence of atmospheric factors: room temperature, soil surface temperature and relative humidity. The {sup 226}Ra, {sup 232}Th, U content and permeability were also performed. The measurements of radon soil gas were carried out by using an AlphaGUARD monitor. The {sup 226}Ra activity concentration was made by Gamma Spectrometry (HPGe); the permeability was carried out using the RADON-JOK permeameter and ICP-MS analysis to {sup 232}Th and U content. The soil permeability is 5.0 x 10{sup -12}, which is considered average. The {sup 226}Ra (22.2 ± 0.3 Bq.m{sup -3}); U content (73.4 ± 3.6 Bq.kg{sup -1}) and {sup 232}Th content (55.3 ± 4.0 Bq.kg{sup -1}) were considered above of average concentrations, according to mean values for soils typical (~ 35.0 Bq.kg{sup -1}) by UNSCEAR. The results showed a difference of 26.0% between the highest and the lowest concentration of radon in soil gas: at midnight (15.5 ± 1.0 kBq.m{sup -3}) and 3:00 pm, the highest mean radon concentration (21.0 ± 1.0 kBq.m{sup -3}). The room temperature and surface soil temperature showed equivalent behavior and the surface soil temperature slightly below room temperature during the entire monitoring time. Nevertheless, the relative humidity showed the highest cyclical behavior, showing a higher relationship with the radon concentration in soil gas. (author)

  11. Remote Sensing of lower thermospheric temperature and composition based on observations of O2 Atmospheric band emission.

    Science.gov (United States)

    Christensen, A. B.; Yee, J.; Budzien, S. A.; Bishop, R. L.; Hecht, J. H.; Stephan, A. W.; Crowley, G.

    2011-12-01

    The properties of the O2 Atmospheric bands emitted in the lower thermosphere are examined through the use of a photochemical model and compared with measurements from the RAIDS near-infrared spectrometer on the International Space Station. An updated model (Yee, 2011) has been used to establish the sensitivity of the line-of-sight (LOS) brightness of the (0,0), (1,1) and (0,1) bands to changes in neutral composition and some reaction rate and branching ratios. We found that the most sensitive region to O2 variability is near 120 km where the brightness is ~ [O2]^2. Calculations based on the MSIS-90E neutral atmospheric model corresponding to the geographical locations of the brightness measurements at 120 and 125 km for several days of observations indicate greater variability in the model results than observed by RAIDS based on our current understanding of the pointing errors. Up to about 200 km the (0,0) band lifetime is sufficiently long to allow thermalization of the upper state through collisions with the background gasses making the rotational distribution representative of the local temperature. The analysis of rocket data by Heller et al. (1991) and more recently Sheese et al. (2010) using OSIRIS observations up to an altitude of ~ 110 km illustrates the approach. Using the same measurement concept, the RAIDS data extend the range of altitudes an additional two scale heights to approximately 130 km. Comparing RAIDS and TIMED/SABER LOS measurements we have been able to validate temperatures in the region around 100 km. During moderate geomagnetic activity (Kp ~ 4) localized but greatly enhanced temperatures have been observed. J. W. Heller, A. B. Christensen, J. H. Yee and W. E. Sharp, Mesospheric temperature inferred from daytime observation of the O2 atmospheric (0,0) band system, J. Geophys. Res., 96,19,499-19,505,1991. P. E. Sheese, E. J. Llewellyn, R. L. Gattinger, A. E. Bourassa, D. A. Degenstein, N. D. Lloyd, and I. C. McDade, Temperatures in the

  12. Mean ocean temperature change over the last glacial transition based on atmospheric changes in heavy noble mixing ratios

    Science.gov (United States)

    Bereiter, Bernhard; Severinghaus, Jeff; Shackleton, Sarah; Baggenstos, Daniel; Kawamura, Kenji

    2016-04-01

    On paleo-climatic timescales heavy noble gases (Krypton and Xenon) are passively cycled through the atmosphere-ocean system without seeing any significant sink or source. Since the solubility in water of each gas species is characterized by a specific temperature dependency, mixing ratios in the atmosphere change with changing ocean temperatures. In this study, we use this fact to reconstruct mean global ocean temperatures (MOT) over the course of the last glacial transition based on measurements of trapped air in the WAIS Divide ice core. We analyzed 70 ice samples with a recently developed method which determines the isotopic ratios of N2, Ar, Kr (and in some cases also of Xe, though with less precision) and the elemental ratios of Kr/N2, Xe/N2 and Xe/Kr. We use the isotope ratios to correct the elemental ratios for gravitational enrichment in the firn column. The corrected elemental ratios are then used in a simple box model to reconstruct MOT. The three elemental ratio pairs are first interpreted as independent measures of MOT and then combined to a single "best-estimate" MOT record with an average uncertainty of 0.27°C. We find a clear link to Antarctic temperatures and a LGM-Holocene change in MOT of 2.4°C. This value is in good agreement with results from marine sediment cores (which, however, have an uncertainty of 1°C). Our record provides an unprecedented constrain on ocean heat uptake over the last glacial transition and therefore gives new insights in the mechanisms underlying long term ocean heat fluxes. To our knowledge, this is the first time that MOT has been reconstructed in such great detail.

  13. Investigation Of The Influence Of Temperature Inversions And Turbulence On Land-Atmosphere Interactions For Rolling Terrain

    Science.gov (United States)

    Osibanjo, Olabosipo O.

    The objectives of this work are to calculate surface fluxes for rolling terrain using observational data collected during one week in September 2014 from a monitoring site in Echo, Oregon and to investigate the log law in the ABL. The site is located in the Columbia Basin with rolling terrain, irrigated farmland, and over 100 wind turbines. The 10 m tower was placed in a small valley depression to isolate nighttime temperature inversions. This thesis presents observations of momentum, sensible heat, moisture, and CO2 fluxes from data collected at a sampling frequency of 10Hz at four heights. Results show a strong correlation between temperature inversions and CO 2 flux. The log layer could not be achieved as the value of the estimated von Karman constant (˜0.62) is not close to that of the accepted value of 0.41. The impact of the irrigated farmland near the measurement site was observed in the latent heat flux, where the advection of moisture was evident in the tower moisture gradient. A strong relationship was also observed between fluxes of sensible heat, latent heat, CO2, and atmospheric stability. The average nighttime CO2 concentration observed was ˜407 ppm, and daytime ˜388 ppm compared to the 2013 global average CO2 concentration of 395 ppm. The maximum CO2 concentration (˜485 ppm) was observed on the strongest temperature inversion night. There are few uncertainties in the measurements. The manufacturer for the eddy covariance instruments (EC 150) quotes uncertainty of +/- 0.1°C for temperature between -0°C-40°C. Error bars were generated on the estimated surface sensible heat flux using the standard deviation and mean values. Under the most stable atmospheric conditions, uncertainty (assumed to be the variability in the flux estimates) was close to the minimum (˜+/- 5 W m-2). (Abstract shortened by ProQuest.).

  14. Extending MGS-TES Temperature Retrievals in the Martian Atmosphere up to 90 Km: Retrieval Approach and Results

    Science.gov (United States)

    Feofilov, A. G.; Kutepov, A. A.; Rezac, L.; Smith, M. D.

    2015-01-01

    This paper describes a methodology for performing a temperature retrieval in the Martian atmosphere in the 50-90 km altitude range using spectrally integrated 15 micrometers C02 limb emissions measured by the Thermal Emission Spectrometer (TES), the thermal infrared spectrometer on board the Mars Global Surveyor (MGS). We demonstrate that temperature retrievals from limb observations in the 75-90 km altitude range require accounting for the non-local thermodynamic equilibrium (non-LTE) populations of the C02(v2) vibrational levels. Using the methodology described in the paper, we have retrieved approximately 1200 individual temperature profiles from MGS TES limb observations in the altitude range between 60 and 90 km. 0ur dataset of retrieved temperature profiles is available for download in supplemental materials of this paper. The temperature retrieval uncertainties are mainly caused by radiance noise, and are estimated to be about 2 K at 60 km and below, 4 K at 70 km, 7 K at 80 km, 10 K at 85 km, and 20 K at 90 km. We compare the retrieved profiles to Mars Climate Database temperature profiles and find good qualitative agreement. Quantitatively, our retrieved profiles are in general warmer and demonstrate strong variability with the following values for bias and standard deviations (in brackets) compared to the Martian Year 24 dataset of the Mars Climate Database: 6 (+/-20) K at 60 km, 7.5 (+/-25) K at 65 km, 9 (+/-27) K at 70 km, 9.5 (+/-27) K at 75 km, 10 (+/-28) K at 80 km, 11 (+/-29) K at 85 km, and 11.5 (+/-31) K at 90 km. Possible reasons for the positive temperature bias are discussed. carbon dioxide molecular vibrations

  15. Method of and apparatus for measuring temperature and pressure. [atmospheric sounding

    Science.gov (United States)

    Korb, C. L.; Kalshoven, J. E., Jr. (Inventor)

    1985-01-01

    Laser beams are transmitted through gas to a reflecting target, which may be either a solid surface or particulate matter in gas or the gas molecules. The return beams are measured to determine the amount of energy absorbed by the gas. For temperature measurements, the laser beam has a wavelength at which the gas exhibits a relatively temperature sensitive and pressure insensitive absorption characteristic for pressure measurements, the laser beam has a wavelength at which the gas has a relatively pressure sensitive and temperature insensitive absorption characteristic. To reduce the effects of scattering on the absorption measurements a reference laser beam with a weak absorption characteristic is transmitted colinearly with the data beam having a strong absorption characteristic. The two signals are processed as a ratio to eliminate back scattering. Embodiments of transmitters and receivers described include a sequential laser pulse transmitter and receiver, a simultaneous laser pulse transmitter and receiver.

  16. Synthesis of MIL-100(Fe at Low Temperature and Atmospheric Pressure

    Directory of Open Access Journals (Sweden)

    Jing Shi

    2013-01-01

    Full Text Available MIL-100(Fe, a mesoporous metal-organic framework (MOF, has a large BET specific surface area and pore volume with the presence of a significant amount of accessible Lewis acid metal sites upon dehydration. The structural characteristics of MIL-100(Fe make it a good candidate for potential applications in gas storage, separation, and heterogeneous catalysis. Mainly, this MOF is obtained by the hydrothermal synthesis in a Teflon-lined autoclave at high temperature (>150°C under static conditions. However, this method has several disadvantages such as high temperature, high (autogenous pressure, long time, and comparable low MOF yield. Therefore, development of a facile method for synthesis of MIL-100(Fe is vitally important for fundamental understanding and practical application. Herein, MIL-100(Fe is synthesized by a facile low-temperature (90% still could be achieved, suggesting that this simple and energy saving method has the potential to be used practically.

  17. Benzylammonium Thermometer Ions: Internal Energies of Ions Formed by Low Temperature Plasma and Atmospheric Pressure Chemical Ionization.

    Science.gov (United States)

    Stephens, Edward R; Dumlao, Morphy; Xiao, Dan; Zhang, Daming; Donald, William A

    2015-12-01

    The extent of internal energy deposition upon ion formation by low temperature plasma and atmospheric pressure chemical ionization was investigated using novel benzylammonium thermometer ions. C-N heterolytic bond dissociation enthalpies of nine 4-substituted benzylammoniums were calculated using CAM-B3LYP/6-311++G(d,p), which was significantly more accurate than B3LYP/6-311++G(d,p), MP2/6-311++G(d,p), and CBS-QB3 for calculating the enthalpies of 20 heterolytic dissociation reactions that were used to benchmark theory. All 4-substituted benzylammonium thermometer ions fragmented by a single pathway with comparable dissociation entropies, except 4-nitrobenzylammonium. Overall, the extent of energy deposition into ions formed by low temperature plasma was significantly lower than those formed by atmospheric pressure chemical ionization under these conditions. Because benzylamines are volatile, this new suite of thermometer ions should be useful for investigating the extent of internal energy deposition during ion formation for a wide range of ionization methods, including plasma, spray and laser desorption-based techniques. Graphical Abstract ᅟ.

  18. Degradation of metaflumizone in soil: impact of varying moisture, light, temperature, atmospheric CO2 level, soil type and soil sterilization.

    Science.gov (United States)

    Chatterjee, Niladri Sekhar; Gupta, Suman; Varghese, Eldho

    2013-01-01

    Soil is a major sink for the bulk of globally used pesticides. Hence, fate of pesticides in soil under the influence of various biotic and abiotic factors becomes important for evaluation of stability and safety. This paper presents the impact of varying moisture, light, temperature, atmospheric CO(2) level, soil type and soil sterilization on degradation of metaflumizone, a newly registered insecticide in India. Degradation of metaflumizone in soil followed the first order reaction kinetics and its half life values varied from ~20 to 150 d. Under anaerobic condition, degradation of metaflumizone was faster (t(½) 33.4 d) compared to aerobic condition (t(½) 50.1 d) and dry soil (t(½) 150.4 d). Under different light exposures, degradation was the fastest under UV light (t(½) 27.3 d) followed by Xenon light (t(½) 43 d) and dark condition (t(½) 50.1 d). Degradation rate of metaflumizone increased with temperature and its half life values ranged from 30.1 to 100.3d. Elevated atmospheric CO(2) level increased the degradation in soil (t(½) 20.1-50.1 d). However, overall degradation rate was the fastest at 550 ppm atmospheric CO(2) level, followed by 750 ppm and ambient level (375 ppm). Degradation of metaflumizone was faster in Oxisol (pH 5.2, Total Organic Carbon 1.2%) compared to Inceptisol (pH 8.15, TOC 0.36%). In sterile soil, only 5% dissipation of initial concentration was observed after 90 d of sampling. Under various conditions, 4-cyanobenzoic acid (0.22-1.86 mg kg(-1)) and 4-trifluoromethoxy aniline (0.21-1.23 mg kg(-1)) were detected as major degradation products.

  19. Fast low-temperature plasma reduction of monolayer graphene oxide at atmospheric pressure

    Science.gov (United States)

    Bodik, Michal; Zahoranova, Anna; Micusik, Matej; Bugarova, Nikola; Spitalsky, Zdenko; Omastova, Maria; Majkova, Eva; Jergel, Matej; Siffalovic, Peter

    2017-04-01

    We report on an ultrafast plasma-based graphene oxide reduction method superior to conventional vacuum thermal annealing and/or chemical reduction. The method is based on the effect of non-equilibrium atmospheric-pressure plasma generated by the diffuse coplanar surface barrier discharge in proximity of the graphene oxide layer. As the reduction time is in the order of seconds, the presented method is applicable to the large-scale production of reduced graphene oxide layers. The short reduction times are achieved by the high-volume power density of plasma, which is of the order of 100 W cm‑3. Monolayers of graphene oxide on silicon substrate were prepared by a modified Langmuir–Schaefer method and the efficient and rapid reduction by methane and/or hydrogen plasma was demonstrated. The best results were obtained for the graphene oxide reduction in hydrogen plasma, as verified by x-ray photoelectron spectroscopy and Raman spectroscopy.

  20. Handbook of Geophysics and Space Environments. Chapter 15, 1983 Revision. Atmospheric Temperature, Density and Pressure

    Science.gov (United States)

    1983-06-13

    D.C. 20402. 15 . , iF -w" Stevenson Screen. The shelter has a base about 1 m (1.7 to 2.0 m in Central Europe) above the ground and is mounted in an...10 through 12 August 1893, Fin- land, after Homen (Geigerl 2 ) Temperature (C) Annual Means Daily Means Swamp Sandy Granite Loam Sand Humus Land Heath

  1. Response of atmospheric ground level temperatures to changes in the total solar irradiance

    CERN Document Server

    Erlykin, Anatoly

    2015-01-01

    The attribution of part of global warming to changes in the total solar irradiance (TSI) is an important topic which is not, yet, fully understood. Here, we examine the TSI induced temperature (T) changes on a variety of time scales, from one day to centuries and beyond, using a variety of assumptions. Also considered is the latitude variation of the T-TSI correlations, where it appears that over most of the globe there is a small increase in the sensitivity of temperature to TSI in time. It is found that the mean global sensitivity (alpha)measured in K(Wm-2)-1 varies from about 0.003 for 1 day, via 0.05 for 11-years to about 0.2 for decades to centuries. We conclude that mean global temperature changes related to TSI are not significant from 1975 onwards. Before 1975, when anthropogenic gases were less important, many of the temperature changes can be attributed to TSI variations. Over much longer periods of time, from Kyear to Myear, the TSI changes are more efficient still, the sensitivity alpha increasing...

  2. Effects of Satellite Spectral Resolution and Atmospheric Water Vapor on Retrieval of Near-Ground Temperatures

    Science.gov (United States)

    1993-04-28

    alternate low-level water vapor profile was considered. This " dry " water vapor profile (dashed in Fig. I) was specified to be equal to the "basic...the dry water vapor profile for the night situation. As expected, the unresolvable perturbations of surface temperature were smaller for the dry

  3. Studies of temperature disturbances of lower and middle atmosphere during stratospheric warmings 2006-2013

    Science.gov (United States)

    Medvedev, Andrey; Medvedeva, Irina; Ratovsky, Konstantin; Tolstikov, Maxim

    This paper was devoted to study of sudden winter stratospheric warmings 2006-2013. Initial data were vertical temperature profiles obtained by the Microwave Limb Sounder (MLS) aboard the spacecraft EOS Aura. Shown that the temperature disturbances, propagated during stratospheric warmings are result of interference of at least two waves. Two-wave interference model of stratospheric warming was developed. Characteristics of planetary waves were obtained by using this model. Periods of disturbances vary from 5 to 45 days. Vertical wave numbers range is 20-150 km. Amplitudes and horizontal wave numbers obtained by the two-wave model vary smoothly in space and time, forming vorticity-like structure. We compared warmings 2006-2013 by using global amplitude. Comparison of variations of ionospheric parameters and characteristics of planetary waves in the stratosphere during warmings was done. On the basis of regular, continuous observations of the Irkutsk ionosonde DSP-4, was shown that number of traveling ionospheric disturbances (TIDs) tend to increase during stratospheric warmings. Found correlations between the amount of traveling ionospheric disturbances and the temperature at 80 km, between the daily maximum electron concentration and global amplitude of wave with upward phase velocity between the ion temperature and the amplitude of wave with downward phase velocity over Irkutsk. The work was supported by Russian Foundation for Basic Research Grant 13-05-00153 and RF President Grant of Public Support for RF Leading Scientific Schools (NSh-2942.2014.5).

  4. Screen level temperature increase due to higher atmospheric carbon dioxide in calm and windy nights revisited

    NARCIS (Netherlands)

    Steeneveld, G.J.; Holtslag, A.A.M.; McNider, R.T.; Pielke sr., R.A.

    2011-01-01

    Long-term surface observations over land have shown temperature increases during the last century, especially during nighttime. Observations analyzed by Parker [2004] show similar long-term trends for calm and windy conditions at night, and on basis of this it was suggested that the possible effect

  5. Coupling between atmospheric CO2 and temperature during the onset of the Little Ice Age

    NARCIS (Netherlands)

    Hoof, T.B. van

    2004-01-01

    Present day global warming is primarily caused by the greenhouse effect of the increased CO2 emissions since the onset of the industrial revolution. A coupling between temperature and the greenhouse gas CO2 has also been observed in several ice-core records on a glacial-interglacial timescale as we

  6. Measurements of non-equilibrium and equilibrium temperature behind a strong shock wave in simulated martian atmosphere

    Institute of Scientific and Technical Information of China (English)

    Xin Lin; Xi-Long Yu; Fei Li; Shao-Hua Zhang; Jian-Guo Xin; Xin-Yu Zhang

    2012-01-01

    Non-equilibrium radiation measurements behind strong shock wave for simulated Martian atmosphere are presented in this paper.The shock wave is established in a hydrogen oxygen combustion driven shock tube.Time-resolved spectra of the △v =0 sequence of the B2Σ+ → X2Σ+ electronic transition of CN have been observed through optical emission spectroscopy (OES).A new method,which is based on fitting high resolution spectrum for rotational and vibrational temperatures measurement,is proposed to diagnose temperature distribution behind the shock wave.It is estimated that the current scheme has the maximum deviation less than 8% (1σ) for vibrational temperature measurement through detailed analysis of the influence of the uncertainties of spectroscopic constants and spectral resolution.Radiation structure of the shock layer,including induction,relaxation and equilibrium process,and corresponding rotational and vibrational temperatures are obtained through time gating OES diagnostics with sub-microsecond temporal resolution.The present extensive results will strongly benefit the reaction rate estimation and computational fluid dynamics (CFD)code validation in high enthalpy Mars reentry chemistry.

  7. NO density and gas temperature measurements in atmospheric pressure nanosecond repetitively pulsed (NRP) discharges by Mid-IR QCLAS

    Science.gov (United States)

    Simeni Simeni, Marien; Stancu, Gabi-Daniel; Laux, Christophe

    2014-10-01

    Nitric oxide is a key species for many processes: in combustion, in human skin physiology... Recently, NO-ground state absolute density measurements produced by atmospheric pressure NRP discharges were carried out in air as a function of the discharge parameters, using Quantum Cascade Laser Absorption Spectroscopy. These measurements were space averaged and performed in the post-discharge region in a large gas volume. Here we present radial profiles of NO density and temperature measured directly in the discharge for different configurations. Small plasma volume and species densities, high temperature and EM noise environment make the absorption diagnostic challenging. For this purpose the QCLAS sensitivity was improved using a two-detector system. We conducted lateral absorbance measurements with a spatial resolution of 300 μm for two absorption features at 1900.076 and 1900.517 cm-1. The radial temperature and NO density distributions were obtained from the Abel inverted lateral measurements. Time averaged NO densities of about 1.E16 cm-3 and gas temperature of about 1000K were obtained in the center of the discharge. PLASMAFLAME Project (Grant No ANR-11-BS09-0025).

  8. Influence of the tilting reflection mirror on the temperature and wind velocity retrieved by a polarizing atmospheric Michelson interferometer.

    Science.gov (United States)

    Zhang, Chunmin; Li, Ying

    2012-09-20

    The principles of a polarizing atmospheric Michelson interferometer are outlined. The tilt of its reflection mirror results in deflection of the reflected beam and affects the intensities of the observed inteferogram. This effect is systematically analyzed. Both rectangular and circular apertures are considered. The theoretical expression of the modulation depth and phase of the interferogram are derived. These parameters vary with the inclination angle of the mirror and the distance between the deflection center and the optical axis and significantly influence the retrieved temperature and wind speed. If the wind and temperature errors are required to be less than 3 m/s and 5 K, the deflection angle must be less than 0.5°. The errors are also dependent on the shape of aperture. If the reflection mirror is deflected in one direction, the temperature error is smaller for a circular aperture (1.3 K) than for a rectangular one (2.6 K), but the wind velocity errors are almost the same (less than 3 m/s). If the deflection center and incident light beam are coincident, the temperature errors are 3 × 10(-4) K and 0.45 K for circular and rectangular apertures, respectively. The wind velocity errors are 1.2 × 10(-3) m/s and 0.06 m/s. Both are small. The result would be helpful for theoretical research and development of the static polarization wind imaging interferometer.

  9. Photodissociation in the atmosphere of Mars - Impact of high resolution, temperature-dependent CO2 cross-section measurements

    Science.gov (United States)

    Anbar, A. D.; Allen, M.; Nair, H. A.

    1993-01-01

    We have investigated the impact of high resolution, temperature-dependent CO2 cross-section measurements, reported by Lewis and Carver (1983), on calculations of photodissociation rate coefficients in the Martian atmosphere. We find that the adoption of 50 A intervals for the purpose of computational efficiency results in errors in the calculated values for photodissociation of CO2, H2O, and O2 which are generally not above 10 percent, but as large as 20 percent in some instances. These are acceptably small errors, especially considering the uncertainties introduced by the large temperature dependence of the CO2 cross section. The inclusion of temperature-dependent CO2 cross sections is shown to lead to a decrease in the diurnally averaged rate of CO2 photodissociation as large as 33 percent at some altitudes, and increases of as much as 950 percent and 80 percent in the photodissociation rate coefficients of H2O and O2, respectively. The actual magnitude of the changes depends on the assumptions used to model the CO2 absorption spectrum at temperatures lower than the available measurements, and at wavelengths longward of 1970 A.

  10. Atomic Force Microscopy Thermally-Assisted Microsampling with Atmospheric Pressure Temperature Ramped Thermal Desorption/Ionization-Mass Spectrometry Analysis.

    Science.gov (United States)

    Hoffmann, William D; Kertesz, Vilmos; Srijanto, Bernadeta R; Van Berkel, Gary J

    2017-02-20

    The use of atomic force microscopy controlled nanothermal analysis probes for reproducible spatially resolved thermally assisted sampling of micrometer-sized areas (ca. 11 × 17 μm wide × 2.4 μm deep) from relatively low number-average molecular weight (Mn mass spectrometric analysis. The procedure and mechanism for material pickup, the sampling reproducibility and sampling size are discussed, and the oligomer distribution information available from slow temperature ramps versus ballistic temperature jumps is presented. For the Mn = 970 P2VP, the Mn and polydispersity index determined from the mass spectrometric data were in line with both the label values from the sample supplier and the value calculated from the simple infusion of a solution of polymer into the commercial atmospheric pressure chemical ionization source on this mass spectrometer. With a P2VP sample of higher Mn (Mn = 2070 and 2970), intact oligomers were still observed (as high as m/z 2793 corresponding to the 26-mer), but a significant abundance of thermolysis products were also observed. In addition, the capability for confident identification of the individual oligomers by slowly ramping the probe temperature and collecting data-dependent tandem mass spectra was also demonstrated. The material type limits to the current sampling and analysis approach as well as possible improvements in nanothermal analysis probe design to enable smaller area sampling and to enable controlled temperature ramps beyond the present upper limit of about 415 °C are also discussed.

  11. Effects of Modified Atmosphere Packaging, Food Life Extenders and Temperature on the Shelf Life of Ready-Made Dishes.

    Science.gov (United States)

    Sato, Jun; Maenishi, Takuya; Saito, Yuki; Masuda, Toshiro; Kadotani, Naoki; Kozakai, Hiroshi; Ito, Masanori

    2016-01-01

    The combined effect of several microbial control factors including gas barrier of containers, modified atmosphere packaging, food life extenders and storage temperature was discussed in order to determine the possibility for improving the shelf life for hamburger steak and deepfried chicken, representative ready-made dishes sold at convenience stores in Japan. Multiple measures including cold storage were effective in improving the shelf life of ready-made dishes. It was also suggested that storage tests for ready-made dishes should be conducted at 10℃, a practical temperature, to confirm the storable period, as well as at 15℃, an adequate abuse temperature, to confirm the effects of various microbial control factors. In the present study, the test group 4 (nitrogen + barrier containers + pH modifier) performed most favorably at both temperatures, indicating the efficacy of multiple means including "cold storage" in improving the shelf life (extending the consume-by date) of ready-made dishes. All strains isolated from the tested hamburger steak and deep-fried chicken were common food contaminant bacterial species.

  12. Impact of temperature field inhomogeneities on the retrieval of atmospheric species from MIPAS IR limb emission spectra

    Directory of Open Access Journals (Sweden)

    M. Kiefer

    2010-04-01

    Full Text Available We examine volume mixing ratios (vmr retrieved from limb emission spectra recorded with the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS. In level 2 (L2 data products of three different retrieval processors, which perform one dimensional (1-D retrievals, we find significant differences between species' profiles from ascending and descending orbit parts. The relative differences vary systematically with time of the year, latitude, and altitude. In the lower stratosphere their monthly means can reach maxima of 20% for CFC-11, CFC-12, HNO3, H2O, 10% for CH4 and N2O. Relative differences between monthly means of 1-D retrieval results and of the true atmospheric state can be expected to reach half of these percentage values, while relative differences in single vmr profiles might well exceed those numbers. Often there are no physical or chemical reasons for these differences, so they are an indicator for a problem in the data processing. The differences are generally largest at locations where the meridional temperature gradient of the atmosphere is strong. On the contrary, when performing the retrieval with a tomographic two dimensional (2-D retrieval, L2 products generally do not show these differences. This implies that inhomogeneities in the temperature field, and possibly in the species' fields, which are accounted for in the 2-D algorithm and not in standard 1-D processors, may cause significant deviations in the results. Inclusion of an externally given adequate temperature gradient in the forward model of a 1-D processor helps to reduce the observed differences. However, only the full tomographic approach is suitable to resolve the horizontal inhomogeneities. Implications for the use of the 1-D data, e.g. for validation, are discussed. The dependence of the ascending/descending differences on the observation strategy suggests that this problem is to be expected to affect in

  13. Geophysical validation of temperature retrieved by the ESA processor from MIPAS/ENVISAT atmospheric limb-emission measurements

    Directory of Open Access Journals (Sweden)

    M. Ridolfi

    2007-04-01

    Full Text Available The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS has been operating since March 2002 onboard of the ENVIronmental SATellite of the European Space Agency (ESA. The high resolution (0.035 cm−1 limb-emission measurements acquired by MIPAS in the first two years of operation have very good geographical and temporal coverage and have been re-processed by ESA with the most recent versions (4.61 and 4.62 of the inversion algorithms. The products of this processing chain are geolocated profiles of temperature and of the volume mixing ratios of six key atmospheric constituents: H2O, O3, HNO3, CH4, N2O and NO2. As for all the measurements made with innovative instruments and techniques, this data set requires a thorough validation. In this paper we present a geophysical validation of the temperature profiles derived from MIPAS measurements by the ESA retrieval algorithm. The validation is carried-out by comparing MIPAS temperature with correlative measurements made by radiosondes, lidars, in-situ and remote sensors operated either from the ground or stratospheric balloons.

    The results of the intercomparison indicate that the bias of the MIPAS profiles is generally smaller than 1 or 2 K depending on altitude. Furthermore we find that, especially at the edges of the altitude range covered by the MIPAS scan, the random error estimated from the intercomparison is larger (typically by a factor of two to three than the corresponding estimate derived on the basis of error propagation.

    In this work we also characterize the discrepancies between MIPAS temperature and the temperature fields resulting from the analyses of the European Centre for Medium-range Weather Forecasts (ECMWF. The bias and the standard deviation of these discrepancies are consistent with those obtained when comparing MIPAS to correlative measurements; however, in this case the

  14. Geophysical validation of temperature retrieved by the ESA processor from MIPAS/ENVISAT atmospheric limb-emission measurements

    Directory of Open Access Journals (Sweden)

    M. Ridolfi

    2007-08-01

    Full Text Available The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS has been operating since March 2002 onboard of the ENVIronmental SATellite of the European Space Agency (ESA. The high resolution (0.035 cm−1 full width half maximum, unapodized limb-emission measurements acquired by MIPAS in the first two years of operation have very good geographical and temporal coverage and have been re-processed by ESA with the most recent versions (4.61 and 4.62 of the inversion algorithms. The products of this processing chain are pressures at the tangent points and geolocated profiles of temperature and of the volume mixing ratios of six key atmospheric constituents: H2O, O3, HNO3, CH4, N2O and NO2. As for all the measurements made with innovative instruments and techniques, this data set requires a thorough validation. In this paper we present a geophysical validation of the temperature profiles derived from MIPAS measurements by the ESA retrieval algorithm. The validation is carried-out by comparing MIPAS temperature with correlative measurements made by radiosondes, lidars, in-situ and remote sensors operated either from the ground or stratospheric balloons.

    The results of the intercomparison indicate that the bias of the MIPAS profiles is generally smaller than 1 or 2 K depending on altitude. Furthermore we find that, especially at the edges of the altitude range covered by the MIPAS scan, the random error estimated from the intercomparison is larger (typically by a factor of two to three than the corresponding estimate derived on the basis of error propagation.

    In this work we also characterize the discrepancies between MIPAS temperature and the temperature fields resulting from the analyses of the European Centre for Medium-range Weather Forecasts (ECMWF. The bias and the standard deviation of these discrepancies are consistent with those obtained when

  15. On the temperature dependence of the reaction O+NO-NO2(asterisk). [in earth atmosphere

    Science.gov (United States)

    Sharp, W. E.

    1984-01-01

    The published data on the temperature dependence of the radiative combination of atomic oxygen with nitric oxide at pressures near 1 torr is examined. Arguments are advanced to suggest that radiation near the cut-off wavelength (about 3875A) is coming from the unstabilized activated complex, NO2(asterisk). At 4000A a positive activation energy of 1 kcal/mole is deduced. Application of this temperature dependence with the rate coefficient at 5200A is made to airglow measurements in aurora. The deduced NO concentration is about 10 to the 9th per cu cm, in general agreement with that deduced from the measured NO(+)/O2(+) ratio as well as an auroral model prediction.

  16. Rheological behavior of Shengli coal-solvent slurry at low-temperatures and atmospheric pressure

    Institute of Scientific and Technical Information of China (English)

    WANG Yong-gang; YAN Yan; GUO Xiang-kun; Xu De-ping

    2009-01-01

    We report the results from systematic studies of Shengli lignite coal-solvent slurries. Solvent type, temperature, coal to solvent ratio, particle granularity, shear rate and shear time were investigated. The viscosity of the solvents is time independent. However, the slurries are thixotropic. A change from pseudo-plastic to Newtonian behavior occurs as the temperature, or as the solvent to coal ratio, increases. The solvent used in the slurry affects the point at which the theology changes from pseudo-plastic to Newtonian. The REC slurry changes at 1 : 1.2 coal to solvent ratio and at 40 ℃. The HAR slurry changes at a 1:1.5 ratio and at 60 ℃. The theology of the slurries is pseudo-plastic at low shear rates but Newtonian at high shear rates.

  17. A comparison of atmospheric temperature over China between radiosonde observations and multiple reanalysis datasets

    Science.gov (United States)

    Guo, Yanjun; Zhang, Siqi; Yan, Jinghui; Chen, Zhe; Ruan, Xin

    2016-04-01

    The quality controlled (RAW) and homogenized (ADJ) radiosonde temperatures within 850-30 hPa collected at 118 stations in China are compared, on a monthly mean basis, with the temperatures extracted from 8 reanalysis datasets (REA) including NCEP-1, NCEP-2, ERA-40 (ECMWF 45-yr Reanalysis), ERA-Interim, JRA-55 (Japanese 55-yr Reanalysis), 20CR (20th Century Reanalysis), MERRA (Modern Era Retrospective-Analysis), and CFSR (Climate Forecast System Reanalysis). Average differences, correlations, standard deviations, and linear trends among RAW, ADJ, and REA for the period 1981-2010 are analyzed. The results reveal significant inhomogeneity in the time series of RAW radiosonde temperature in China; an overall negative adjustment was thus employed to obtain the ADJ temperatures, and the effect of the negative adjustment is the most significant within 200-100 hPa. Such a homogenization process has removed the system errors in RAW, possibly caused by radiosonde instrument changes and observation system upgrades. Hence, the correlation is higher between ADJ and REA than that between RAW and REA. The mean difference between ADJ and REA is about 1℃ during 1981-2010, while REA are mostly cooler in the troposphere and warmer in the stratosphere than ADJ; nonetheless, they have a significant high and positive correlation and their annual variability is notably consistent. Furthermore, the linear trends in REA and ADJ both demonstrate warming in the lower-mid troposphere and cooling in the mid stratosphere, with large uncertainties found in the upper troposphere and lower stratosphere. In general, ERA-Interim, JRA-55, and MERRA are more consistent with ADJ than other reanalysis datasets.

  18. Coupling between atmospheric CO2 and temperature during the onset of the Little Ice Age

    OpenAIRE

    Hoof, T.B. van

    2004-01-01

    Present day global warming is primarily caused by the greenhouse effect of the increased CO2 emissions since the onset of the industrial revolution. A coupling between temperature and the greenhouse gas CO2 has also been observed in several ice-core records on a glacial-interglacial timescale as well as on a millennial timescale during the glacials. In marked contrast, no significant ice-derived CO2 fluctuations occur on centennial time scales contemporaneously with well-documented cooling ev...

  19. Measurement of atmospheric turbulence strength at high altitude with balloon-borne temperature sensors

    Science.gov (United States)

    Bufton, J. L.

    1974-01-01

    A technique to measure a vertical profile of the optical strength of turbulence employs the measurement of a root mean square temperature difference between two microthermal probes carried aloft as part of a balloon payload. Microthermal fluctuations provide a measure for the density fluctuations of turbulence. Examination of recorded profiles of refractive-index structure coefficients reveals a turbulence structure which is organized into multiple, thin groupings of strong turbulence separated by relatively quiescent intervals of variable length.

  20. Quasi-16-day period oscillations observed in middle atmospheric ozone and temperature in Antarctica

    Directory of Open Access Journals (Sweden)

    T. D. Demissie

    2013-07-01

    Full Text Available Nightly averaged mesospheric temperature derived from the hydroxyl nightglow at Rothera station (67°34' S, 68°08' W and nightly midnight measurements of ozone mixing ratio obtained from Troll station (72°01' S, 2°32' E in Antarctica have been used to investigate the presence and vertical profile of the quasi-16-day planetary wave in the stratosphere and mesosphere during the Antarctic winter of 2009. The variations caused by planetary waves on the ozone mixing ratio and temperature are discussed, and spectral and cross-correlation analyses are performed to extract the wave amplitudes and to examine the vertical structure of the wave from 34 to 80 km. The results show that while planetary-wave signatures with periods 3–12 days are strong below the stratopause, the oscillations associated with the 16-day wave are the strongest and present in both the mesosphere and stratosphere. The period of the wave is found to increase below 42 km due to the Doppler shifting by the strong eastward zonal wind. The 16-day oscillation in the temperature is found to be correlated and phase coherent with the corresponding oscillation observed in O3 volume mixing ratio at all levels, and the wave is found to have vertical phase fronts consistent with a normal mode structure.

  1. Quasi-16-day period oscillations observed in middle atmospheric ozone and temperature in Antarctica

    Energy Technology Data Exchange (ETDEWEB)

    Demissie, T.D.; Hibbins, R.E.; Espy, P.J. [Norwegian Univ. of Science and Technology (NTNU), Trondheim (Norway); Birkeland Centre for Space Science, Bergen (Norway); Kleinknecht, N.H.; Straub, C. [Norwegian Univ. of Science and Technology (NTNU), Trondheim (Norway)

    2013-09-01

    Nightly averaged mesospheric temperature derived from the hydroxyl nightglow at Rothera station (67 34' S, 68 08' W) and nightly midnight measurements of ozone mixing ratio obtained from Troll station (72 01' S, 2 32' E) in Antarctica have been used to investigate the presence and vertical profile of the quasi-16-day planetary wave in the stratosphere and mesosphere during the Antarctic winter of 2009. The variations caused by planetary waves on the ozone mixing ratio and temperature are discussed, and spectral and cross-correlation analyses are performed to extract the wave amplitudes and to examine the vertical structure of the wave from 34 to 80 km. The results show that while planetary-wave signatures with periods 3-12 days are strong below the stratopause, the oscillations associated with the 16-day wave are the strongest and present in both the mesosphere and stratosphere. The period of the wave is found to increase below 42 km due to the Doppler shifting by the strong eastward zonal wind. The 16-day oscillation in the temperature is found to be correlated and phase coherent with the corresponding oscillation observed in O{sub 3} volume mixing ratio at all levels, and the wave is found to have vertical phase fronts consistent with a normal mode structure. (orig.)

  2. Effects of temperature and other atmospheric conditions on long-term gaseous mercury observations in the Arctic

    Directory of Open Access Journals (Sweden)

    A. S. Cole

    2009-12-01

    Full Text Available Gaseous elemental mercury (GEM measurements at Alert, Canada, from 1995 to 2007 were analyzed for statistical time trends and for correlations with meteorological and climate data. A significant decreasing trend in annual GEM concentration is reported at Alert, with an estimated slope of −0.0086 ng m−3 yr−1 (−0.6% yr−1 over this 13-year period. It is shown that there has been a shift in the month of minimum mean GEM concentration from May to April due to a change in the timing of springtime atmospheric mercury depletion events (AMDEs. These AMDEs are found to decrease with increasing local temperature within each month, both at Alert and at Amderma, Russia. These results agree with the temperature dependence suggested by previous experimental results and theoretical kinetic calculations and highlight the potential for changes in Arctic mercury chemistry with climate. A correlation between total monthly AMDEs at Alert and the Polar/Eurasian Teleconnection Index was observed only in March, perhaps due to higher GEM inputs in early spring in those years with a weak polar vortex. A correlation of AMDEs at Alert with wind direction supports the origin of mercury depletion events over the Arctic Ocean, in agreement with a previous trajectory study of ozone depletion events. Interannual variability in total monthly depletion event frequency at Alert does not appear to correlate significantly with total or first-year northern hemispheric sea ice area or with other major teleconnection patterns. Nor do AMDEs at either Alert or Amderma correlate with local wind speed, as might be expected if depletion events are sustained by stable, low-turbulence atmospheric conditions. The data presented here – both the change in timing of depletion events and their relationship with temperature – can be used as additional constraints to improve the ability of global models to predict the cycling and deposition of mercury

  3. CFCl3 (CFC-11): UV Absorption Spectrum Temperature Dependence Measurements and the Impact on Atmospheric Lifetime Uncertainty

    Science.gov (United States)

    McGillen, M.; Fleming, E. L.; Jackman, C. H.; Burkholder, J. B.

    2013-12-01

    CFCl3 (CFC-11) is both a major ozone-depleting substance and a potent greenhouse gas that is removed primarily via stratospheric UV photolysis. Uncertainty in the temperature dependence of its UV absorption spectrum is a significant contributing factor to the overall uncertainty in its global lifetime and, thus, model calculations of stratospheric ozone recovery and climate change. In this work, the CFC-11 UV absorption spectrum was measured over a range of wavelength (184.95-230 nm) and temperature (216-296 K). We report a spectrum temperature dependence that is less than currently recommended for use in atmospheric models. The impact on its atmospheric lifetime was quantified using the NASA Goddard Space Flight Center 2-D coupled chemistry-radiation-dynamics model and the spectrum parameterization developed in this work. The modeled global annually averaged lifetime was 58.1 × 0.7 years (2σ uncertainty due solely to the spectrum uncertainty). The lifetime is slightly reduced and the uncertainty significantly reduced from that obtained using current UV spectrum recommendations. CFCl 3 (CFC-11) 2-D model results: Left: Global annually averaged loss rate coefficient (local lifetime) and photolysis and reaction contributions (see legend). Middle: Molecular loss rate and uncertainty limits; the slow and fast profiles were calculated using the 2σ uncertainty estimates in the CFC-11 UV absorption spectrum from this work. Right: CFC-11 concentration profile. CFC-11 loss process contribution to the overall local lifetime uncertainty (2σ) calculated using the 2-D model (see text). Left: Results obtained from this work. Right: Results obtained using model input from Sander et al. [2011] and updates in SPARC [2013].

  4. Surface treatment of a titanium implant using low temperature atmospheric pressure plasmas

    Science.gov (United States)

    Lee, Hyun-Young; Tang, Tianyu; Ok, Jung-Woo; Kim, Dong-Hyun; Lee, Ho-Jun; Lee, Hae June

    2015-09-01

    During the last two decades, atmospheric pressure plasmas(APP) are widely used in diverse fields of biomedical applications, reduction of pollutants, and surface treatment of materials. Applications of APP to titanium surface of dental implants is steadily increasing as it renders surfaces wettability and modifies the oxide layer of titanium that hinders the interaction with cells and proteins. In this study, we have treated the titanium surfaces of screw-shaped implant samples using a plasma jet which is composed of a ceramic coaxial tube of dielectrics, a stainless steel inner electrode, and a coper tube outer electrode. The plasma ignition occurred with Ar gas flow between two coaxial metal electrodes and a sinusoidal bias voltage of 3 kV with a frequency of 20 kHz. Titanium materials used in this study are screw-shaped implants of which diameter and length are 5 mm and 13 mm, respectively. Samples were mounted at a distance of 5 mm below the plasma source, and the plasma treatment time was set to 3 min. The wettability of titanium surface was measured by the moving speed of water on its surface, which is enhanced by plasma treatment. The surface roughness was also measured by atomic force microscopy. The optimal condition for wettability change is discussed.

  5. Retrieval of temperature profiles from CHAMP for climate monitoring: intercomparison with Envisat MIPAS and GOMOS and different atmospheric analyses

    Directory of Open Access Journals (Sweden)

    A. Gobiet

    2007-02-01

    Full Text Available This study describes and evaluates a Global Navigation Satellite System (GNSS radio occultation (RO retrieval scheme particularly aimed at delivering bias-free atmospheric parameters for climate monitoring and research. The focus of the retrieval is on the sensible use of a priori information for careful high-altitude initialisation in order to maximise the usable altitude range. The RO retrieval scheme has been meanwhile applied to more than five years of data (September 2001 to November 2006 from the German CHAllenging Minisatellite Payload for geoscientific research (CHAMP satellite. In this study it was validated against various correlative datasets including the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS and the Global Ozone Monitoring for Occultation of Stars (GOMOS sensors on Envisat, five different atmospheric analyses, and the operational CHAMP retrieval product from GeoForschungsZentrum (GFZ Potsdam. In the global mean within 10 to 30 km altitude we find that the present validation observationally constrains the potential RO temperature bias to be <0.2 K. Latitudinally resolved analyses show biases to be observationally constrained to <0.2–0.5 K up to 35 km in most cases, and up to 30 km in any case, even if severely biased (about 10 K or more a priori information is used in the high altitude initialisation of the retrieval. No evidence is found for the 10–35 km altitude range of RO bias sources other than those potentially propagated downward from initialisation, indicating that the widely quoted RO promise of "unbiasedness and long-term stability due to intrinsic self-calibration" can indeed be realized given care in the data processing to strictly limit structural uncertainty. The results demonstrate that an adequate high-altitude initialisation technique is crucial for accurate stratospheric RO retrievals and that still common methods of initialising the involved hydrostatic integral with an upper boundary

  6. Laser Measurements of the H Atom + Ozone Rate Constant at Atmospheric Temperatures

    Science.gov (United States)

    Liu, Y.; Smith, G. P.; Peng, J.; Reppert, K. J.; Callahan, S. L.

    2015-12-01

    The exothermic H + O3 reaction produces OH(v) Meinel band emissions, used to derive mesospheric H concentrations and chemical heating rates. We have remeasured its rate constant to reduce resulting uncertainties and the measurement extend to lower mesospheric temperatures using modern laser techniques. H atoms are produced by pulsed ultraviolet laser trace photolysis of O3, followed by reaction of O(D) with added H2. A second, delayed, frequency-mixed dye laser measures the reaction decay rate with the remaining ozone by laser induced fluorescence. We monitor either the H atom decay by 2 photon excitation at 205 nm and detection of red fluorescence, or the OH(v=9) product time evolution with excitation of the B-X (0,9) band at 237 nm and emission in blue B-A bands. By cooling the enclosed low pressure flow cell we obtained measurements from 146-305 K. Small kinetic modeling corrections are made for secondary regeneration of H atoms. The results fully confirm the current NASA JPL recommendation for this rate constant, and establish its extrapolation down to the lower temperatures of the mesosphere. This work was supported by the NSF Aeronomy Program and an NSF Physics summer REU student grant.

  7. Dependence of Ozone Generation on Gas Temperature Distribution in AC Atmospheric Pressure Dielectric Barrier Discharge in Oxygen

    Science.gov (United States)

    Takahashi, Go; Akashi, Haruaki

    AC atmospheric pressure multi-filament dielectric barrier discharge in oxygen has been simulated using two dimensional fluid model. In the discharge, three kinds of streamers have been obtained. They are primary streamers, small scale streamers and secondary streamers. The primary streamers are main streamers in the discharge and the small scale streamers are formed after the ceasing of the primary streamers. And the secondary streamers are formed on the trace of the primary streamers. In these streamers, the primary and the small scale streamers are very effective to generate O(3P) oxygen atoms which are precursor of ozone. And the ozone is generated mainly in the vicinity of the dielectrics. In high gas temperature region, ozone generation decreases in general. However, increase of the O(3P) oxygen atom density in high gas temperature region compensates decrease of ozone generation rate coefficient. As a result, amount of ozone generation has not changed. But if the effect of gas temperature was neglected, amount of ozone generation increases 10%.

  8. Hyperbaric storage of melon juice at and above room temperature and comparison with storage at atmospheric pressure and refrigeration.

    Science.gov (United States)

    Queirós, Rui P; Santos, Mauro D; Fidalgo, Liliana G; Mota, Maria J; Lopes, Rita P; Inácio, Rita S; Delgadillo, Ivonne; Saraiva, Jorge A

    2014-03-15

    Hyperbaric storage (8h) of melon juice (a highly perishable food) at 25, 30 and 37°C, under pressure at 25-150 MPa was compared with atmospheric pressure storage (0.1 MPa) at the same temperatures and under refrigeration (4°C). Comparatively to the refrigerated condition, hyperbaric storage at 50/75 MPa resulted in similar or lower microbial counts (total aerobic mesophiles, enterobacteriaceae, and yeasts/moulds) while at 100/150 MPa, the counts were lower for all the tested temperatures, indicating in the latter case, in addition to microbial growth inhibition, a microbial inactivation effect. At 25 MPa no microbial inhibition was observed. Physicochemical parameters of all samples stored under pressure (pH, titratable acidity, total soluble solids, browning degree and cloudiness) did not show a clear variation trend with pressure, being the results globally similar to refrigeration storage. These results show the potential of hyperbaric storage, at and above room temperature and with potential energy savings, comparatively to refrigeration.

  9. Temperature and atmospheric CO2 concentration estimates through the PETM using triple oxygen isotope analysis of mammalian bioapatite

    Science.gov (United States)

    Gehler, Alexander; Gingerich, Philip D.; Pack, Andreas

    2016-07-01

    The Paleocene-Eocene Thermal Maximum (PETM) is a remarkable climatic and environmental event that occurred 56 Ma ago and has importance for understanding possible future climate change. The Paleocene-Eocene transition is marked by a rapid temperature rise contemporaneous with a large negative carbon isotope excursion (CIE). Both the temperature and the isotopic excursion are well-documented by terrestrial and marine proxies. The CIE was the result of a massive release of carbon into the atmosphere. However, the carbon source and quantities of CO2 and CH4 greenhouse gases that contributed to global warming are poorly constrained and highly debated. Here we combine an established oxygen isotope paleothermometer with a newly developed triple oxygen isotope paleo-CO2 barometer. We attempt to quantify the source of greenhouse gases released during the Paleocene-Eocene transition by analyzing bioapatite of terrestrial mammals. Our results are consistent with previous estimates of PETM temperature change and suggest that not only CO2 but also massive release of seabed methane was the driver for CIE and PETM.

  10. Percentage Contributions from Atmospheric and Surface Features to Computed Brightness Temperatures

    Science.gov (United States)

    Jackson, G. S.

    2006-12-01

    Over the past few years, there has become an increasing interest in the use of millimeter-wave (mm-wave) and sub-millimeter-wave (submm-wave) radiometer observations to investigate the properties of ice particles in clouds. Passive radiometric channels respond to both the integrated particle mass throughout the volume and field of view, and to the amount, location, and size distribution of the frozen (and liquid) particles with the sensitivity varying for different frequencies and hydrometeor types. One methodology used since the 1960's to discern the relationship between the physical state observed and the brightness temperature (TB) is through the temperature weighting function profile. In this research, the temperature weighting function concept is exploited to analyze the sensitivity of various characteristics of the cloud profile, such as relative humidity, ice water path, liquid water path, and surface emissivity. In our numerical analysis, we compute the contribution (in Kelvin) from each of these cloud and surface characteristics, so that the sum of these various parts equals the computed TB. Furthermore, the percentage contribution from each of these characteristics is assessed. There is some intermingling/contamination of the contributions from various components due to the integrated nature of passive observations and the absorption and scattering between the vertical layers, but all in all the knowledge gained is useful. This investigation probes the sensitivity over several cloud classifications, such as cirrus, blizzards, light snow, anvil clouds, and heavy rain. The focus is on mm-wave and submm-wave frequencies, however discussions of the effects of cloud variations to frequencies as low as 10 GHz and up to 874 GHz will also be presented. The results show that nearly 60% of the TB value at 89 GHz comes from the earth's surface for even the heaviest blizzard snow rates. On the other hand, a significant percentage of the TB value comes from the snow

  11. Atmospheric density, temperature and wind measurement techniques during the 1980 Energy Budget Campaign

    Science.gov (United States)

    Schmidlin, F. J.; Philbrick, C. R.; Offermann, D.

    1981-01-01

    Super Loki rocketsonde systems are described. The datasonde telemeters data to a ground station where ambient temperatures are calculated between 20 and 70 km. The sphere is a passive, radar tracked system which allows density to be calculated between 30 and 90 km. When flown simultaneously the systems give redundant data in the altitudes between 30 and 70 km. The datasonde has a balloon parachute that descends more slowly than a conventional parachute and is more stable. Because of launch constraints the datasondes reached very high apogees, leading to very fast descent velocities. Aerodynamic heating reduced thermistor sensitivity. Anomalous parachute behavior influenced wind sensing until a denser layer was reached. The spheres collapsed above 60 km altitude, but their data, combined with dropsonde data give significant results for 21 flights. These show that the stratosphere is colder than Cospar 72 model predictions and the mesosphere is warmer.

  12. Mutation breeding of lycopene-producing strain Blakeslea trispora by a novel atmospheric and room temperature plasma (ARTP).

    Science.gov (United States)

    Qiang, Wang; Ling-ran, Feng; Luo, Wei; Han-guang, Li; Lin, Wang; Ya, Zhou; Xiao-bin, Yu

    2014-09-01

    To improve the fermentation efficiency of lycopene, a plasma jet, driven by an active helium atom supplied with atmospheric and room temperature plasma (ARTP) biological breeding system, was used as a new method to generate mutations in Blakeslea trispora (-). After several rounds of screening, a mutant A5 with high concentration of lycopene and dry biomass was isolated, which showed a maximum lycopene concentration (26.4 ± 0.2 mg/g dry biomass) which was 55 % higher than the parent strain (16.9 ± 0.3 mg/g dry biomass) in the production of lycopene. Compared with parent strain, B. trispora A5 required less dissolved oxygen (10 % less than that of parent strain) to reach maximum concentration in a 5-L stirred tank reactor batch fermentation.

  13. The Healing Effect of Low-Temperature Atmospheric-Pressure Plasma in Pressure Ulcer: A Randomized Controlled Trial.

    Science.gov (United States)

    Chuangsuwanich, Apirag; Assadamongkol, Tananchai; Boonyawan, Dheerawan

    2016-08-31

    Pressure ulcers are difficult to treat. Recent reports of low-temperature atmospheric-pressure plasma (LTAPP) indicated its safe and effectiveness in chronic wound care management. It has been shown both in vitro and vivo studies that LTAPP not only helps facilitate wound healing but also has antimicrobial efficacy due to its composition of ion and electron, free radicals, and ultraviolet ray. We studied the beneficial effect of LTAPP specifically on pressure ulcers. In a prospective randomized study, 50 patients with pressure ulcers were divided into 2 groups: Control group received standard wound care and the study group was treated with LTAPP once every week for 8 consecutive weeks in addition to standard wound care. We found that the group treated with LTAPP had significantly better PUSH (Pressure Ulcer Scale for Healing) scores and exudate amount after 1 week of treatment. There was also a reduction in bacterial load after 1 treatment regardless of the species of bacteria identified.

  14. Winter to winter recurrence of atmospheric circulation anomalies over East Asia and its impact on winter surface air temperature anomalies

    Science.gov (United States)

    2017-01-01

    The persistence of atmospheric circulation anomalies over East Asia shows a winter to winter recurrence (WTWR) phenomenon. Seasonal variations in sea level pressure anomalies and surface wind anomalies display significantly different characteristics between WTWR and non-WTWR years. The WTWR years are characterized by the recurrence of both a strong (weak) anomalous Siberian High and an East Asian winter monsoon over two successive winters without persistence through the intervening summer. However, anomalies during the non-WTWR years have the opposite sign between the current and ensuing winters. The WTWR of circulation anomalies contributes to that of surface air temperature anomalies (SATAs), which is useful information for improving seasonal and interannual climate predictions over East Asia and China. In the positive (negative) WTWR years, SATAs are cooler (warmer) over East Asia in two successive winters, but the signs of the SATAs are opposite in the preceding and subsequent winters during the non-WTWR years. PMID:28178351

  15. Improving climate model simulation of tropical Atlantic sea surface temperature: The importance of enhanced vertical atmosphere model resolution

    Science.gov (United States)

    Harlaß, Jan; Latif, Mojib; Park, Wonsun

    2015-04-01

    A long-standing problem in climate modeling is the inaccurate simulation of tropical Atlantic (TA) sea surface temperature (SST), known as the TA SST bias. It has far-reaching consequences for climate prediction in that area as it goes along, among others, with erroneous precipitation patterns. We show that the TA SST bias can be largely reduced by increasing both the atmospheric horizontal and vertical resolutions in a climate model. At high horizontal resolution, enhanced vertical resolution is indispensable to substantially improve the simulation of TA SST by enhancing surface wind stress. This also reduces biases in the upper ocean thermal structure and precipitation patterns. Although, enhanced horizontal resolution alone leads to some improvement in the mean climate, typical bias patterns characterized by a reversed zonal SST gradient at the equator and too warm SST in the Benguela upwelling region are mostly unchanged at a coarser vertical resolution.

  16. Degradation of Kresoxim-Methyl in Water: Impact of Varying pH, Temperature, Light and Atmospheric CO2 Level.

    Science.gov (United States)

    Khandelwal, Ashish; Gupta, Suman; Gajbhiye, Vijay T; Varghese, Eldho

    2016-01-01

    In the present investigation, persistence of kresoxim-methyl (a broad spectrum strobilurin fungicide) was studied in water. Results revealed that kresoxim-methyl readily form acid metabolite. Therefore, residues of kresoxim-methyl were quantified on the basis of parent molecule alone and sum total of kresoxim-methyl and its acid metabolite. In water, influence of various abiotic factors like pH, temperature, light and atmospheric carbon dioxide level on dissipation of kresoxim-methyl was studied. The half life value for kresoxim-methyl and total residue varied from 1 to 26.1 and 6.1 to 94.0 days under different conditions. Statistical analysis revealed the significant effect of abiotic factors on the dissipation of kresoxim-methyl from water.

  17. Titan's atmosphere from ISO observations: Temperature, composition and detection of water vapor

    Science.gov (United States)

    Coustenis, A.; Salama, A.; Lellouch, E.; Encrenaz, Th.; de Graauw, Th.; Bjoraker, G. L.; Samuelson, R. E.; Gautier, D.; Feuchtgruber, H.; Kessler, M. F.; Orton, G. S.

    1998-09-01

    Observations of Titan in the thermal infrared (2.36-45.2 mu m) were performed by ISO, in Jan. and Dec. 1997, with resolving powers between 1500 and 3000 in the Grating mode and up to 30000 in the Fabry-Perot mode. Two pure rotational water lines were observed using the ISO/SWS/Grating (R=2000) at 39.4 and 43.9 mu m, with fluxes of about 2 Jy over a continuum of 60 Jy [1], with S/N ~ 8. The flux observed can be reproduced with a constant abundance of ~ 4 x 10(-10) , or with a recent photochemical profile [2] multiplied by a factor of 0.4. This yields a H_2O vapor mole fraction of about 10(-8) at the 400 km altitude level (column density of 2.5 x 10(14) mol cm(-2) ). The inferred water influx at Titan at 700 km of altitude is : (0.8-2.8) x 10(6) mol cm(-2) s(-1) , compatible with the CO2 observed abundance and similar to that found at Saturn [3]. This suggests that infalling material from Saturn rings may not be the dominant source of Saturn's water. The analysis of the 233-1500 cm(-1) spectrum of ISO/SWS has provided the thermal and compositional structure of Titan on a disk-average [4]. In particular, observations of the CH_3D band at 1150 cm(-1) significantly improved the determination of the D/H ratio in Titan's stratosphere. The new value of 7.5 x 10(-5) , is four times lower than in comets and suggests that Titan's atmosphere is not of cometary origin, but rather formed by outgassing from the interior. We have also tested available vertical profiles and inferred upper limits for a few likely candidates in Titan's stratosphere (such as benzene and allene) [4]. References [1] COUSTENIS, A., et al. 1998a. Astron. Astrophys. 336, L85. [2] LARA, L. M., et al. 1996. J. Geophys. Res.-Planets 101, 23261-23283. [3] FEUCHTGRUBER, H., et al. 1997. Nature 389, 159-162. [4] COUSTENIS, A., et al. 1998b. Submitted for publication.

  18. HC3N and C4H2 low temperature VUV photoabsorption cross sections: application to their observation in Titan's atmosphere by UVIS

    Science.gov (United States)

    Benilan, Y.; Ferradaz, T.; Fray, N.; Jolly, A.; Schwell, M.; Guillemin, J.-C.

    To interpret observations of Titan's high atmosphere obtained by the UV spectrometer UVIS on board the CASSINI spacecraft, the photoabsorption cross sections of molecules are needed. A critical review of the absorption coefficient available in the vacuum ultraviolet domain (VUV: 110-210 nm) for organic molecules present or expected to be present in Titan's atmosphere, showed a critical lack of data. In particular, many absorption cross sections have never been measured at low temperature. The lack is even greater for molecules not commercially available since, even at room temperature, absolute absorption coefficients are not available or erroneous. A new specific absorption cell has thus been designed to measure the absorption cross sections in the VUV range at low temperature characteristic of Titan's atmosphere. We have measured HC3N and C4H2 spectra using the Berlin synchrotron facility (BESSY) to obtain new absorption coefficients in the 110 to 190 nm range, at the low temperature representative of Titan's atmosphere. The effect of the temperature on the spectra will be discussed. And, an application to the interpretation of VUV observations of Titan's atmosphere obtained by UVIS will be presented.

  19. Effects of the annealing temperature and atmosphere on the microstructures and dielectric properties of ZnO/Al{sub 2}O{sub 3} composite coatings

    Energy Technology Data Exchange (ETDEWEB)

    Wei, Ping, E-mail: pingwei0202@126.com; Zhu, Dongmei; Huang, Shanshan; Zhou, Wancheng; Luo, Fa

    2013-11-15

    ZnO/Al{sub 2}O{sub 3} composite coatings were fabricated by atmospheric plasma spraying technology (APS). The effects of annealing temperature and atmospheres (in air or vacuum) on the microstructure and phase transformation of the sprayed coatings were studied by scanning electron microscope (SEM) and X-ray diffraction spectroscopy (XRD). The microwave dielectric properties of these coatings after annealing treatment were also discussed in the frequency range of 8.2–12.4 GHz. Both the real part and the imaginary part of the permittivity decreased significantly with increased annealing temperature when the annealing process is carried out in air atmosphere, while the complex permittivity of the coating annealed in vacuum atmosphere was obviously increased compared to the initial sprayed coating. The mechanism for the variation of dielectric properties of sprayed ZnO/Al{sub 2}O{sub 3} composite coating caused by annealing treatment was discussed in this study.

  20. The statistical inhomogeneity of surface air temperature in global atmospheric reanalyses

    Science.gov (United States)

    Ferguson, C. R.; Lee, M. H.

    2015-12-01

    Recently, a new generation of so-called climate reanalyses has emerged, including the 161-year NOAA—Cooperative Institute for Research in Environmental Sciences (NOAA-CIRES) Twentieth Century Reanalysis Version 2c (20CR V2c), the 111-year ECMWF pilot reanalysis of the twentieth century (ERA-20C), and the 55-year JMA conventional reanalysis (JRA-55C). These reanalyses were explicitly designed to achieve improved homogeneity through assimilation of a fixed subset of (mostly surface) observations. We apply structural breakpoint analysis to evaluate inhomogeneity of the surface air temperature in these reanalyses (1851-2011). For the modern satellite era (1979-2013), we intercompare their inhomogeneity to that of all eleven available satellite reanalyses. Where possible, we distinguish between breakpoints that are likely linked to climate variability and those that are likely due to an artificial observational network shift. ERA-20C is found to be the most homogenous reanalysis, with 40% fewer artificial breaks than 20CR V2c. Despite its gains in homogeneity, continued improvements to ERA-20C are needed. In this presentation, we highlight the most spatially extensive artificial break events in ERA-20C.

  1. Exploiting the atmosphere's memory for monthly, seasonal and interannual temperature forecasting using Scaling LInear Macroweather Model (SLIMM)

    Science.gov (United States)

    Del Rio Amador, Lenin; Lovejoy, Shaun

    2016-04-01

    Traditionally, most of the models for prediction of the atmosphere behavior in the macroweather and climate regimes follow a deterministic approach. However, modern ensemble forecasting systems using stochastic parameterizations are in fact deterministic/ stochastic hybrids that combine both elements to yield a statistical distribution of future atmospheric states. Nevertheless, the result is both highly complex (both numerically and theoretically) as well as being theoretically eclectic. In principle, it should be advantageous to exploit higher level turbulence type scaling laws. Concretely, in the case for the Global Circulation Models (GCM's), due to sensitive dependence on initial conditions, there is a deterministic predictability limit of the order of 10 days. When these models are coupled with ocean, cryosphere and other process models to make long range, climate forecasts, the high frequency "weather" is treated as a driving noise in the integration of the modelling equations. Following Hasselman, 1976, this has led to stochastic models that directly generate the noise, and model the low frequencies using systems of integer ordered linear ordinary differential equations, the most well-known are the Linear Inverse Models (LIM). For annual global scale forecasts, they are somewhat superior to the GCM's and have been presented as a benchmark for surface temperature forecasts with horizons up to decades. A key limitation for the LIM approach is that it assumes that the temperature has only short range (exponential) decorrelations. In contrast, an increasing body of evidence shows that - as with the models - the atmosphere respects a scale invariance symmetry leading to power laws with potentially enormous memories so that LIM greatly underestimates the memory of the system. In this talk we show that, due to the relatively low macroweather intermittency, the simplest scaling models - fractional Gaussian noise - can be used for making greatly improved forecasts

  2. Rlationship between the aerosol scattering ratio and temperature of atmosphere and the sensitivity of a Doppler wind lidar with iodine filter

    Institute of Scientific and Technical Information of China (English)

    Jinshan Zhu; Yubao Chen; Zhaoai Yan; Songhua Wu; Zhishen Liu

    2008-01-01

    The sensitivity of Doppler wind lidar is an important parameter which affects the performance of Doppler wind lidar. Aerosol scattering ratio, atmospheric temperature, and wind speed obviously affect the mea- surement of Doppler wind lidar with iodine filter. We discuss about the relationship between the measurement sensitivity and the above atmospheric parameters. The numerical relationship between them is given through the theoretical simulation and calculation.

  3. Design, Analysis and Implementation of an Experimental System to Harvest Energy From Atmospheric Temperature Variations Using Ethyl Chloride Filled Bellows

    Science.gov (United States)

    Ali, Gibran

    The increase in global warming and the dwindling supplies of fossil fuels have shifted the focus from traditional to alternate sources of energy. This has resulted in a concerted effort towards finding new energy sources as well as better understanding traditional renewable energy sources such as wind and solar power. In addition to the shift in focus towards alternate energy, the last two decades have offered a dramatic rise in the use of digital technologies such as wireless sensor networks that require small but isolated power supplies. Energy harvesting, a method to gather energy from ambient sources including sunlight, vibrations, heat, etc., has provided some success in powering these systems. One of the unexplored areas of energy harvesting is the use of atmospheric temperature variations to obtain usable energy. This thesis investigates an innovative mechanism to extract energy from atmospheric variations using ethyl chloride filled mechanical bellows. The energy harvesting process was divided into two parts. The first part consisted of extracting energy from the temperature variations and converting it into the potential energy stored in a linear coil spring. This was achieved by designing and fabricating an apparatus that consisted of an ethyl chloride filled bellows working against a mechanical spring in a closed and controlled environment. The bellows expanded/contracted depending upon the ambient temperature and the energy harvested was calculated as a function of the bellows' length. The experiments showed that 6 J of potential energy may be harvested for a 23°C change in temperature. The numerical results closely correlated to the experimental data with an error magnitude of 1%. In regions with high diurnal temperature variation, such an apparatus may yield approximately 250 microwatts depending on the diurnal temperature range. The second part of the energy harvesting process consisted of transforming linear expansion of the bellows into electric

  4. Polymer Surface Treatment by Atmospheric Pressure Low Temperature Surface Discharge Plasma:Its Characteristics and Comparison with Low Pressure Oxygen Plasma Treatment

    Institute of Scientific and Technical Information of China (English)

    Atsushi KUWABARA; Shin-ichi KURODA; Hitoshi KUBOTA

    2007-01-01

    The polymer treatment with a low-temperature plasma jet generated on the atmospheric pressure surface discharge (SD) plasma is performed.The change of the surface property over time,in comparison with low pressure oxygen (O2) plasma treatment,is examined.As one compares the treatment by atmospheric pressure plasma to that by the low pressure O2 plasma of PS (polystyrene) the treatment effects were almost in complete agreement.However,when the atmospheric pressure plasma was used for PP(polypropylene),it produced remarkable hydrophilic effects.

  5. Temperature dependence of evaporation coeffcient of water in air and nitrogen under atmospheric pressure; study in water droplets

    CERN Document Server

    Zientara, M; Kolwas, K; Kolwas, M

    2008-01-01

    The evaporation coefficients of water in air and nitrogen were found as a function of temperature, by studying the evaporation of pure water droplet. The droplet was levitated in an electrodynamic trap placed in a climatic chamber maintaining atmospheric pressure. Droplet radius evolution and evaporation dynamics were studied with high precision by analyzing the angle-resolved light scattering Mie interference patterns. A model of quasi-stationary droplet evolution, accounting for the kinetic effects near the droplet surface was applied. In particular, the effect of thermal effusion (a short range analogue of thermal diffusion) was discussed and accounted for. The evaporation coefficient \\alpha in air and in nitrogen were found equal. \\alpha was found to decrease from ~ 0.18 to ~ 0.13 for the temperature range from 273.1 K to 293.1 K and follow the trend given by Arrhenius formula. The agreement with condensation coefficient values obtained with essentially different method by Li et al.[1] was found excellent...

  6. Treatment of Candida albicans biofilms with low-temperature plasma induced by dielectric barrier discharge and atmospheric pressure plasma jet

    Energy Technology Data Exchange (ETDEWEB)

    Koban, Ina; Welk, Alexander; Meisel, Peter; Holtfreter, Birte; Kocher, Thomas [Unit of Periodontology, Dental School, University of Greifswald, Rotgerberstr. 8, 17475 Greifswald (Germany); Matthes, Rutger; Huebner, Nils-Olaf; Kramer, Axel [Institute for Hygiene and Environmental Medicine, University of Greifswald, Walther-Rathenau-Str. 49 a, 17487 Greifswald (Germany); Sietmann, Rabea [Institute of Microbiology, University of Greifswald, Friedrich-Ludwig-Jahn-Str. 15, 17487 Greifswald (Germany); Kindel, Eckhard; Weltmann, Klaus-Dieter, E-mail: ina.koban@uni-greifswald.d [Leibniz Institute for Plasma Science and Technology (INP), Felix-Hausdorff-Str. 2, 17489 Greifswald (Germany)

    2010-07-15

    Because of some disadvantages of chemical disinfection in dental practice (especially denture cleaning), we investigated the effects of physical methods on Candida albicans biofilms. For this purpose, the antifungal efficacy of three different low-temperature plasma devices (an atmospheric pressure plasma jet and two different dielectric barrier discharges (DBDs)) on Candida albicans biofilms grown on titanium discs in vitro was investigated. As positive treatment controls, we used 0.1% chlorhexidine digluconate (CHX) and 0.6% sodium hypochlorite (NaOCl). The corresponding gas streams without plasma ignition served as negative treatment controls. The efficacy of the plasma treatment was determined evaluating the number of colony-forming units (CFU) recovered from titanium discs. The plasma treatment reduced the CFU significantly compared to chemical disinfectants. While 10 min CHX or NaOCl exposure led to a CFU log{sub 10} reduction factor of 1.5, the log{sub 10} reduction factor of DBD plasma was up to 5. In conclusion, the use of low-temperature plasma is a promising physical alternative to chemical antiseptics for dental practice.

  7. Evaluation of dust cake filtration at high temperature with effluence from an atmospheric fluidized-bed combustor

    Energy Technology Data Exchange (ETDEWEB)

    Dennis, R.A.

    1990-08-01

    In the spring of 1989, two separate test series were simultaneously conducted at the US Department of Energy's (DOE's) Morgantown Energy Technology Center (METC) to examine applied and fundamental behavior of dust cake filtration under high temperature and high pressure (HTHP) conditions. The purpose was to provide information on dust-cake filtration properties to gas stream cleanup researchers associated with the Tidd 70 megawatt (MW) pressurized fluidized-bed combustor (PFBC). The two test facilities included (1) a high-pressure natural-gas combustor with injected particulate, which was fed to two full-size candle filters; and (2) an atmospheric fluidized-bed combustor (AFBC) with coal and limestone sorbent to generate a particulate-laden combustion exhaust gas, which was sent to a single full-size candle filter and a small-scale disc filter. Several major conclusions from these studies are noted below. On average reducing the mean particulate size by 33% and the associated loading carried in the filtrate will increase the dust cake specific flow resistance (K{sub 2}) by 498%. High-temperature and high-pressure filtration can be successfully performed with ceramic candle filters at moderate filtration face velocities and reasonable system pressure drops. Off-line filter cleaning can produce a filter system with a higher apparent permeability than that produced from on-line filter cleaning at the same face velocity. 19 refs., 89 figs., 13 tabs.

  8. Trends in long-term gaseous mercury observations in the Arctic and effects of temperature and other atmospheric conditions

    Directory of Open Access Journals (Sweden)

    A. S. Cole

    2010-05-01

    Full Text Available Gaseous elemental mercury (GEM measurements at Alert, Canada, from 1995 to 2007 were analyzed for statistical time trends and for correlations with meteorological and climate data. A significant decreasing trend in annual GEM concentration is reported at Alert, with an estimated slope of −0.0086 ng m−3 yr−1 (−0.6% yr−1 over this 13-year period. It is shown that there has been a shift in the month of minimum mean GEM concentration from May to April due to a change in the timing of springtime atmospheric mercury depletion events (AMDEs. These AMDEs are found to decrease with increasing local temperature within each month, both at Alert and at Amderma, Russia. These results support the temperature dependence suggested by previous experimental results and theoretical kinetic calculations on both bromine generation and mercury oxidation and highlight the potential for changes in Arctic mercury chemistry with climate. A correlation between total monthly AMDEs at Alert and the Polar/Eurasian Teleconnection Index was observed only in March, perhaps due to higher GEM inputs in early spring in those years with a weak polar vortex. A correlation of AMDEs at Alert with wind direction supports the origin of mercury depletion events over the Arctic Ocean, in agreement with a previous trajectory study of ozone depletion events. Interannual variability in total monthly depletion event frequency at Alert does not appear to correlate significantly with total or first-year northern hemispheric sea ice area or with other major teleconnection patterns. Nor do AMDEs at either Alert or Amderma correlate with local wind speed, as might be expected if depletion events are sustained by stable, low-turbulence atmospheric conditions. The data presented here – both the change in timing of depletion events and their relationship with temperature – can be used as additional constraints to improve the ability of models to predict

  9. Improving the low temperature dyeability of polyethylene terephthalate fabric with dispersive dyes by atmospheric pressure plasma discharge

    Science.gov (United States)

    Elabid, Amel E. A.; Zhang, Jie; Shi, Jianjun; Guo, Ying; Ding, Ke; Zhang, Jing

    2016-07-01

    Polyethylene terephthalate (PET) fiber and textile is one of the largest synthetic polymer commodity in the world. The great energy consumption and pollution caused by the high temperature and pressure dyeing of PET fibers and fabrics with disperse dyes has been caused concern these years. In this study, an atmospheric pressure plasma with fine and uniform filament discharge operated at 20 kHz has been used to improve the low temperature dyeability of PET fabric at 95 °C with three cation disperse dyes: Red 73, Blue 183 and Yellow 211. The dyes uptake percentage of the treated PET fabrics was observed to increase as twice as much of untreated fabric. The color strength rate was increased more than 20%. The reducing of the water contact angle and the raising of the capillary height of treated PET fabric strip indicate its hydrophilicity improvement. Scanning electron microscope (SEM) results display nano to micro size of etching pits appeared uniformly on the fiber surface of the treated PET. Simultaneously, X-ray photoelectron spectroscopy (XPS) analysis indicates an increase of the oxygen content in the surface caused by the introduction of polar groups such as Cdbnd O and COOH. The rough surface with improved polar oxygen groups showed hydrophilicity and affinity to C.I. dispersive dyes and is believed to be caused by the strong and very fine filament discharge appearing randomly at one place at an instant but evenly at many places at a longer period. This increases the diffusion and absorption of the C.I. disperse dyes on the PET fiber surface, which improve its low temperature dyeability.

  10. Ice nucleation by surrogates for atmospheric mineral dust and mineral dust/sulfate particles at cirrus temperatures

    Directory of Open Access Journals (Sweden)

    C. M. Archuleta

    2005-01-01

    Full Text Available This study examines the potential role of some types of mineral dust and mineral dust with sulfuric acid coatings as heterogeneous ice nuclei at cirrus temperatures. Commercially-available nanoscale powder samples of aluminum oxide, alumina-silicate and iron oxide were used as surrogates for atmospheric mineral dust particles, with and without multilayer coverage of sulfuric acid. A sample of Asian dust aerosol particles was also studied. Measurements of ice nucleation were made using a continuous-flow ice-thermal diffusion chamber (CFDC operated to expose size-selected aerosol particles to temperatures between -45 and -60°C and a range of relative humidity above ice-saturated conditions. Pure metal oxide particles supported heterogeneous ice nucleation at lower relative humidities than those required to homogeneously freeze sulfuric acid solution particles at sizes larger than about 50 nm. The ice nucleation behavior of the same metal oxides coated with sulfuric acid indicate heterogeneous freezing at lower relative humidities than those calculated for homogeneous freezing of the diluted particle coatings. The effect of soluble coatings on the ice activation relative humidity varied with the respective uncoated core particle types, but for all types the heterogeneous freezing rates increased with particle size for the same thermodynamic conditions. For a selected size of 200 nm, the natural mineral dust particles were the most effective ice nuclei tested, supporting heterogeneous ice formation at an ice relative humidity of approximately 135%, irrespective of temperature. Modified homogeneous freezing parameterizations and theoretical formulations are shown to have application to the description of heterogeneous freezing of mineral dust-like particles with soluble coatings.

  11. Atmospheric variables, nutrients, pH, salinity, and temperature collected by bottle and from meteorological stations in the Sea of Japan and the Yellow Sea from 01 July 1952 to 31 December 1998 (NODC Accession 0000032)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Atmospheric variables, nutrients, pH, salinity, and temperature data were collected using bottle casts in the Sea of Japan from 01 July 1952 to 31 December 1998....

  12. Stratospheric and mesospheric pressure-temperature profiles from rotational analysis of CO2 lines in atmospheric trace molecule spectroscopy/ATLAS 1 infrared solar occultation spectra

    Science.gov (United States)

    Stiller, G. P.; Gunson, M. R.; Lowes, L. L.; Abrams, M. C.; Raper, O. F.; Farmer, C. B.; Zander, R.; Rinsland, C. P.

    1995-01-01

    A simple, classical, and expedient method for the retrieval of atmospheric pressure-temperature profiles has been applied to the high-resolution infrared solar absorption spectra obtained with the atmospheric trace molecule spectroscopy (ATMOS) instrument. The basis for this method is a rotational analysis of retrieved apparent abundances from CO2 rovibrational absorption lines, employing existing constituent concentration retrieval software used in the analysis of data returned by ATMOS. Pressure-temperature profiles derived from spectra acquired during the ATLAS 1 space shuttle mission of March-April 1992 are quantitatively evaluated and compared with climatological and meteorological data as a means of assessing the validity of this approach.

  13. Low temperature carrier transport study of monolayer MoS{sub 2} field effect transistors prepared by chemical vapor deposition under an atmospheric pressure

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Xinke, E-mail: xkliu@szu.edu.cn, E-mail: wujing026@gmail.com; He, Jiazhu; Tang, Dan; Lu, Youming; Zhu, Deliang; Liu, Wenjun; Cao, Peijiang; Han, Sun [College of Materials Science and Engineering, Shenzhen Engineering Laboratory for Advanced Technology of Ceramics, Nanshan District Key Lab for Biopolymer and Safety Evaluation, Shenzhen University, 3688 Nanhai Ave, Shenzhen 518060 (China); Liu, Qiang; Wen, Jiao; Yu, Wenjie [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, CAS, 865 Chang Ning Road, Shanghai 200050 (China); Liu, Wenjun [State Key Laboratory of ASIC and System, Department of Microelectronics, Fudan University, 220 Handan Road, Shanghai 200433 (China); Wu, Jing, E-mail: xkliu@szu.edu.cn, E-mail: wujing026@gmail.com [Department of Physics, National University of Singapore, 21 Lower Kent Ridge Road, 117576 Singapore (Singapore); He, Zhubing [Department of Materials Science and Engineering, South University of Science and Technology of China, 1088 Xueyuan Road, Shenzhen 518055 (China); Ang, Kah-Wee [Department of Electrical and Computer Engineering, National University of Singapore, 4 Engineering Drive 3, 117583 Singapore (Singapore)

    2015-09-28

    Large size monolayer Molybdenum disulphide (MoS{sub 2}) was successfully grown by chemical vapor deposition method under an atmospheric pressure. The electrical transport properties of the fabricated back-gate monolayer MoS{sub 2} field effect transistors (FETs) were investigated under low temperatures; a peak field effect mobility of 59 cm{sup 2}V{sup −1}s{sup −1} was achieved. With the assist of Raman measurement under low temperature, this work identified the mobility limiting factor for the monolayer MoS{sub 2} FETs: homopolar phonon scattering under low temperature and electron-polar optical phonon scattering at room temperature.

  14. The influence of winter and summer atmospheric circulation on the variability of temperature and sea ice around Greenland

    Directory of Open Access Journals (Sweden)

    Masayo Ogi

    2016-10-01

    Full Text Available Most peripheral seas of the Arctic Ocean have seen a pronounced rise in sea surface temperatures in the past century, and this signature of Arctic amplification in proximity to the land suggests that the observed marine and terrestrial changes might be connected to each other. Using in situ observations of temperature from nine coastal meteorological stations around Greenland (GrSTs and remotely sensed fields of sea ice extent (SIE, we examine the interannual variations of surface air temperature (T2m and sea level pressure (SLP anomalies associated with the GrSTs and SIEs surrounding Greenland, specifically within Baffin Bay, the Greenland Sea and Kara-Barents Seas. During winter, the interannual variation in T2m and SLP of the west and south coasts of GrSTs and the Baffin Bay SIE are different from that of the east coast of GrSTs and the SIEs in the Greenland Sea and Kara-Barents Seas. The GrSTs on the west and south coasts of Greenland and the Baffin Bay SIE are associated with the T2m anomalies over Baffin Bay and Davis Strait. The winter SLP patterns associated with these GrSTs and SIEs show positive anomalies over the Arctic and negative anomalies over the North Atlantic with a large-scale atmospheric circulation such as the winter NAO. On the contrary, the east coast of GrSTs and the SIEs in the Greenland Sea and Kara-Barents Seas are correlated with the T2m anomalies over the Greenland Sea and Barents Sea. The surface wind pattern associated with the SIEs in the Greenland Sea and Kara-Barents Seas has a cyclonic circulation in the Greenland Sea and Barents Sea. At the local scale the cyclonic circulation could induce negative SIE anomalies and contribute to increasing open water in the Greenland Sea and Barents Sea. The effect of the loss of sea ice and the heat from the open ocean warming to the atmosphere may influence the GrSTs in the east coast of Greenland. As a result, the T2m pattern associated with the GrSTs in the east coast of

  15. Local flux-profile relationships of wind speed and temperature in a canopy layer in atmospheric stable conditions

    Science.gov (United States)

    Zhang, G.; Leclerc, M. Y.; Karipot, A.

    2010-11-01

    The particularities of the physics of the canopy layer pose challenges to the determination and use of traditional universal functions so helpful in the atmospheric surface layer. Progress toward "universal-like functions" such as those provided by Monin-Obukhov similarity theory for the canopy layer has been modest. One of the challenges lies in that the assumptions underlying Monin-Obukhov similarity theory do not hold within a canopy layer. This paper thus examines the local flux-profile relations for wind (Φm) and for temperature (Φh). It uses three different stability parameters, i.e., h/L(h) at tree top, local z/L(z), and the local bulk Richardson number (Ri), within a tall forest canopy in nighttime stable (indicated by h/L(h) > 0) conditions. Results suggest that the in-canopy Φm can be described using the local Richardson number Ri. Furthermore, Φm is found to increase linearly with Ri in the upper canopy layer for |Ri| 1, |Φm| decreases with |Ri| in a power function, a result consistent for all levels of measurements within the canopy. When both local Φh and local Ri are positive, i.e., the local downward turbulent heat flux is consistent with the local temperature gradient, the local Φh increases with the local Ri when Ri 1. The relationship between local Φh and Ri disappears when counter-gradient heat transfer occurs in strongly stable conditions. A self-correlation analysis is used to examine the influence of self-correlation and the physical meaning of these relationships.

  16. A radiance-based method for estimating uncertainties in the Atmospheric Infrared Sounder (AIRS) land surface temperature product

    Science.gov (United States)

    Hulley, Glynn C.; Hook, Simon J.

    2012-10-01

    Land Surface Temperature (LST) has been identified by NASA and other international organizations as an important Earth System Data Record (ESDR). An ESDR is defined as a long-term, well calibrated and validated data set. Identifying uncertainties in LST products with coarse spatial resolutions (>10 km) such as those from hyperspectral infrared sounders is notoriously difficult due to the challenges of making reliable in situ measurements representative of the spatial scales of the output products. In this study we utilize a Radiance-based (R-based) LST method for estimating uncertainties in the Atmospheric Infrared Sounder (AIRS) v5 LST product. The R-based method provides estimates of the true LST using a radiative closure simulation without the need for in situ measurements, and requires input air temperature, relative humidity profiles and emissivity data. The R-based method was employed at three validation sites over the Namib Desert, Gran Desierto, and Redwood National Park for all AIRS observations from 2002 to 2010. Results showed daytime LST root-mean square errors (RMSE) of 2-3 K at the Namib and Desierto sites, and 1.5 K at the Redwood site. Nighttime LST RMSEs at the two desert sites were a factor of two less when compared to daytime results. Positive daytime LST biases were found at each site due to an underestimation of the daytime AIRS v5 longwave spectral emissivity, while the reverse occurred at nighttime. In the AIRS v6 product (release 2012), LST biases and RMSEs will be reduced significantly due to improved methodologies for the surface retrieval and emissivity first guess.

  17. Direct radiative effect of the Russian wildfires and their impact on air temperature and atmospheric dynamics during August 2010

    Directory of Open Access Journals (Sweden)

    J. C. Péré

    2013-06-01

    Full Text Available The present study aims at investigating the shortwave aerosol direct radiative forcing (ADRF and its feedback on air temperature and atmospheric dynamics during a major fire event that occurred in Russia during August 2010. The methodology is based on an off-line coupling between the CHIMERE chemistry-transport and the Weather Research and Forecasting (WRF models. First, simulations for the period 5–12 August 2010 have been evaluated by using AERONET and satellite measurements of the POLarization and Directionality of the Earth's Reflectance (POLDER and the Cloud-Aerosol LIdar with Orthogonal Polarization (CALIOP sensors. During this period, elevated POLDER AOT are found over a large part of Eastern Europe with values above 2 (at 550 nm in the aerosol plume. According to CALIOP observations, particles remain confined within the first five kilometres of the atmospheric layer. Comparisons with satellite measurements show the ability of CHIMERE to reproduce the regional and vertical distribution of aerosols during their transport from the source region. Over Moscow, AERONET measurements indicate an important increase of AOT (340 nm from 0.7 on 5 August to 2–4 between 6 and 10 August when the aerosol plume is advected over the city. Particles are mainly observed in the fine size mode (radius in the range 0.2–0.4 μm and are characterized by elevated SSA (0.95–0.96 between 440 and 1020 nm. Also, comparisons of simulations with AERONET measurements show that aerosol physical-optical properties (size distribution, AOT, SSA have been well simulated over Moscow in term of intensity and/or spectral dependence. Secondly, modelled aerosol optical properties have been used as input in the radiative transfer code of WRF to evaluate their direct radiative impact. Simulations indicate a significant reduction of solar radiation at the ground (up to 80–150 W m−2 in diurnal-averaged over a large part of Eastern Europe due to the presence of the aerosol

  18. Changes in flavonoids of sliced and fried yellow onions (allium cepa L. var. zittauer) during storage at different atmospheric, temperature and light conditions

    DEFF Research Database (Denmark)

    Islek, Merve; Nilufer-Erdil, Dilara; Knuthsen, Pia

    2015-01-01

    Flavonoid changes in sliced and fried onions which were packed and stored at different atmospheric conditions (air, nitrogen and vacuum), temperatures (ambient, +5 and -18C) and light (dark or light) were investigated. Flavonoids were extracted using accelerated solvent extraction and analyzed...... using ultra performance liquid chromatography coupled with photodiode array detector. Total flavonoid content, quercetin-3,4'-O-diglucoside and quercetin-4'-O-monoglucoside contents in sliced reference onion samples were found as 1,570±176, 926±105 and 564±64μg q.e./g d.w., respectively. Frying did...... not result in significant losses of flavonoids. At room temperature, total flavonoid losses were significant, besides conversion of quercetin glycosides into aglycons. Dark conditions better retained flavonoids of sliced onions at all atmospheric conditions. For sliced onions; +5C, air or vacuum atmosphere...

  19. Effects of elevated atmospheric CO2, prolonged summer drought and temperature increase on N2O and CH4 fluxes in a temperate heathland

    DEFF Research Database (Denmark)

    Carter, Mette Sustmann; Ambus, Per; Albert, Kristian Rost;

    2011-01-01

    In temperate regions, climate change is predicted to increase annual mean temperature and intensify the duration and frequency of summer droughts, which together with elevated atmospheric carbon dioxide (CO2) concentrations, may affect the exchange of nitrous oxide (N2O) and methane (CH4) between...... terrestrial ecosystems and the atmosphere. We report results from the CLIMAITE experiment, where the effects of these three climate change parameters were investigated solely and in all combinations in a temperate heathland. Field measurements of N2O and CH4 fluxes took place 1–2 years after the climate...... change manipulations were initiated. The soil was generally a net sink for atmospheric CH4. Elevated temperature (T) increased the CH4 uptake by on average 10 μg C m−2 h−1, corresponding to a rise in the uptake rate of about 20%. However, during winter elevated CO2 (CO2) reduced the CH4 uptake, which...

  20. Two fast temperature sensors for probing of the atmospheric boundary layer using small remotely piloted aircraft (RPA

    Directory of Open Access Journals (Sweden)

    N. Wildmann

    2013-08-01

    Full Text Available Two types of temperature sensors are designed and tested: a thermocouple and a fine wire resistance thermometer. The intention of this study is to figure out which kind of measurement principle is in general more suited for atmospheric boundary layer meteorology with small remotely piloted aircraft (RPA. The sensors are calibrated in a NIST traceable climate chamber and validated in flight against tower measurements, radiosondes and remote sensing. The sensors have a measurement range of at least −10–50 °C, an absolute RMS error of less than ±0.2 K which is stable over the lifetime of the sensors, and a resolution of about 0.01 K. Both devices are tested for typical errors like radiation error and adiabatic heating, as well as for their dynamic response. Spectral resolutions of up to approximately 10 Hz can be obtained with both sensors, which makes them suitable for turbulence measurement. Their low cost of less than 100 EUR in pure hardware is a major advantage for research with small RPA.

  1. Two fast temperature sensors for probing of the Atmospheric Boundary Layer using small Remotely Piloted Aircraft (RPA

    Directory of Open Access Journals (Sweden)

    N. Wildmann

    2013-03-01

    Full Text Available Two types of temperature sensors are designed and tested, a thermocouple and a fine wire resistance thermometer. The intention of this study is to figure out which kind of measurement principle is in general more suited for atmospheric boundary layer meteorology with small RPA. The sensors are calibrated in a NIST traceable climate chamber and validated in flight against tower measurements, radiosondes and remote sensing. The sensors have a measurement range of at least −10...50° C, an absolute RMS error of less than ±0.2 K which is stable over the lifetime of the sensors, and a resolution of about 0.01 K. Both devices are tested for typical errors like radiation error and adiabatic heating, as well as for their dynamic response. Spectral resolutions of up to approximately 10 Hz can be obtained with both sensors, which makes them suitable for turbulence measurements. Their low cost of less than 100 EUR in pure hardware is a major advantage for research with small RPA.

  2. Proliferation assay of mouse embryonic stem (ES) cells exposed to atmospheric-pressure plasmas at room temperature

    Science.gov (United States)

    Miura, Taichi; Ando, Ayumi; Hirano, Kazumi; Ogura, Chika; Kanazawa, Tatsuya; Ikeguchi, Masamichi; Seki, Atsushi; Nishihara, Shoko; Hamaguchi, Satoshi

    2014-11-01

    Proliferation assays of mouse embryonic stem (ES) cells have been performed with cell culture media exposed to atmospheric-pressure plasmas (APPs), which generate reactive species in the media at room temperature. It is found that serum in cell culture media functions as a scavenger of highly reactive species and tends to protect cells in the media against cellular damage. On the other hand, if serum is not present in a cell culture medium when it is exposed to APP, the medium becomes cytotoxic and cannot be detoxified by serum added afterwards. Plasma-induced cytotoxic media hinder proliferation of mouse ES cells and may even cause cell death. It is also shown by nuclear magnetic resonance spectroscopy that organic compounds in cell culture media are in general not significantly modified by plasma exposure. These results indicate that if there is no serum in media when they are exposed to APPs, highly reactive species (such as OH radicals) generated in the media by the APP exposure are immediately converted to less reactive species (such as H2O2), which can no longer readily react with serum that is added to the medium after plasma exposure. This study has clearly shown that it is these less reactive species, rather than highly reactive species, that make the medium cytotoxic to mouse ES cells.

  3. Silver nanoparticles sintering at low temperature on a copper substrate: In situ characterization under inert atmosphere and air

    Directory of Open Access Journals (Sweden)

    Sopousek J.

    2012-01-01

    Full Text Available Silver nanoparticles (Ag-NPs were prepared by wet synthesis. The Ag-NPs suspension and the copper substrate plate were used for a preparation of substrate-nanoparticle-substrate samples. The sandwich like samples Cu/Ag/Cu were prepared and investigated in-situ at the isothermal external conditions (IEC and inside apparatus for simultaneous thermal analysis STA409 (DSC. The in-situ results of the electrical resistance were recorded during the Cu/Ag/Cu (IEC sample preparation and heat treatment. Thermal effects of the Ag-NPs sintering between copper substrates were measured by differential scanning calorimetry (DSC under different atmospheres. The prepared Cu/Ag/Cu sandwich samples were characterised by means of both optical and electron microscopy. The process of the low temperature sintering inside calorimeter of the Ag-NPs was monitored using both thermogravimetry (TG and DSC technique under inert gas and under synthetic air. The exothermic heat effect of nanosilver sintering was evaluated.

  4. Analysis and Validation of a Predictive Model for Growth and Death of Aeromonas hydrophila under Modified Atmospheres at Refrigeration Temperatures

    Science.gov (United States)

    Pin, Carmen; Velasco de Diego, Raquel; George, Susan; García de Fernando, Gonzalo D.; Baranyi, József

    2004-01-01

    Specific growth and death rates of Aeromonas hydrophila were measured in laboratory media under various combinations of temperature, pH, and percent CO2 and O2 in the atmosphere. Predictive models were developed from the data and validated by means of observations obtained from (i) seafood experiments set up for this purpose and (ii) the ComBase database (http://www.combase.cc; http://wyndmoor.arserrc.gov/combase/).Two main reasons were identified for the differences between the predicted and observed growth in food: they were the variability of the growth rates in food and the bias of the model predictions when applied to food environments. A statistical method is presented to quantitatively analyze these differences. The method was also used to extend the interpolation region of the model. In this extension, the concept of generalized Z values (C. Pin, G. García de Fernando, J. A. Ordóñez, and J. Baranyi, Food Microbiol. 18:539-545, 2001) played an important role. The extension depended partly on the density of the model-generating observations and partly on the accuracy of extrapolated predictions close to the boundary of the interpolation region. The boundary of the growth region of the organism was also estimated by means of experimental results for growth and death rates. PMID:15240265

  5. Mutation breeding of extracellular polysaccharide-producing microalga Crypthecodinium cohnii by a novel mutagenesis with atmospheric and room temperature plasma.

    Science.gov (United States)

    Liu, Bin; Sun, Zheng; Ma, Xiaonian; Yang, Bo; Jiang, Yue; Wei, Dong; Chen, Feng

    2015-04-13

    Extracellular polysaccharides (EPS) produced by marine microalgae have the potential to be used as antioxidants, antiviral agents, immunomodulators, and anti-inflammatory agents. Although the marine microalga Crypthecodinium cohnii releases EPS during the process of docosahexaenoic acid (DHA) production, the yield of EPS remains relatively low. To improve the EPS production, a novel mutagenesis of C. cohnii was conducted by atmospheric and room temperature plasma (ARTP). Of the 12 mutants obtained, 10 mutants exhibited significantly enhanced EPS yield on biomass as compared with the wild type strain. Among them, mutant M7 was the best as it could produce an EPS volumetric yield of 1.02 g/L, EPS yield on biomass of 0.39 g/g and EPS yield on glucose of 94 mg/g, which were 33.85%, 85.35% and 57.17% higher than that of the wild type strain, respectively. Results of the present study indicated that mutagenesis of the marine microalga C. cohnii by ARTP was highly effective leading to the high-yield production of EPS.

  6. Conductivity of SrTiO3 based oxides in the reducing atmosphere at high temperature

    DEFF Research Database (Denmark)

    Hashimoto, Shin-Ichi; Poulsen, Finn Willy; Mogensen, Mogens Bjerg

    2007-01-01

    The conductivities of several donor-doped SrTiO3 based oxides, which were prepared in air, were studied in a reducing atmosphere at high temperature. The conductivities of all specimens increased slowly with time at 1000 degrees C in 9% H-2/N-2, even after 100 h. Nb-doped SrTiO3 showed relatively...... fast reduction and high conductivity compared with the other SrTiO3 based oxides. The conductivity of Nb-doped SrTiO3 was ca. 50 S cm(-1) at 500 degrees C after reduction at 1200 degrees C. After strong reduction, the conductivity of Nb-doped SrTiO3 was almost independent of the oxygen partial pressure...... at 500-800 degrees C, while that of La-doped SrTiO3 dropped immediately on exposure to air. The conduction behavior of Nb-doped SrTiO3 was explained by reduction of Ti4+ and/or Nb5+ and the relatively slow oxygen diffusibility. (c) 2006 Elsevier B.V. All rights reserved....

  7. On the synthesis atmosphere influence in the technology of complex composite materials in the wide temperature range

    Science.gov (United States)

    Uspensky, A. A.; Yavshits, S.; Lipin, V.; Zhigalov, P.; Slobodov, A.

    2017-02-01

    Heterogeneous and homogeneous processes of synthesis for complex functional materials are studied by the methods of thermodynamic modeling and calculation, based on minimization of the Gibbs energy of the researched system. The conditions and products of gasification in the field of 0-2000 °C are determined for the synthesis conditions of a ceramic tile with complex composition (10-component system). All main products of interaction of components of ceramic mass (the system SiO2 – K2O – Na2O – Al2O3 – Fe2O3 – CaO – MgO – TiO2 – P2O5 – SO3) and main components of air (the system N2 – O2 – CO2 – H2O) are found for the synthesis of material in the conditions of the air atmosphere at various temperatures. The character of physico-chemical influence of each components on the occurring processes is revealed, that determines a theoretical and calculation base of management and optimization of the synthesis engineering process for various functional materials.

  8. Breeding L-arginine-producing strains by a novel mutagenesis method: Atmospheric and room temperature plasma (ARTP).

    Science.gov (United States)

    Cheng, Gong; Xu, Jianzhong; Xia, Xiuhua; Guo, Yanfeng; Xu, Kai; Su, Cunsheng; Zhang, Weiguo

    2016-07-03

    A plasma jet, driven by an active helium atom supplied with an atmospheric and room temperature plasma (ARTP) biological breeding system, was used as a novel method to breed L-arginine high-yielding strains. A mutant with resistance to L-homoarginine and 8-azaguaine, ARG 3-15 (L-HA(r), 8-AG(r), L-His(-)), was screened after several rounds of screening. The L-arginine production of these mutants was more than that of the original strain, increased by 43.79% for ARG 3-15. Moreover, N-acetyl-L-glutamate synthase activity of these mutants was also increased. After a series of passages, the hereditary properties of these mutants were found to be stable. Interestingly, beet molasses was utilized in a co-feeding fermentation and benefited to increase the productivity by 5.88%. Moreover, the fermentation with 1.0 g/L betaine could produce 9.33% more L-arginine than without betaine. In fed-batch fermentation, C. glutamicum ARG 3-15 began to produce L-arginine at the initial of logarithmic phase, and continuously increased over 24 hr to a final titer of 45.36 ± 0.42 g/L. The L-arginine productivity was 0.571 g/L/hr and the conversion of glucose (α) was 32.4% after 96 hr. These results indicated that C. glutamicum ARG 3-15 is a promising industrial producer.

  9. Exoplanet Atmospheres

    CERN Document Server

    Seager, S

    2010-01-01

    At the dawn of the first discovery of exoplanets orbiting sun-like stars in the mid-1990s, few believed that observations of exoplanet atmospheres would ever be possible. After the 2002 Hubble Space Telescope detection of a transiting exoplanet atmosphere, many skeptics discounted it as a one-object, one-method success. Nevertheless, the field is now firmly established, with over two dozen exoplanet atmospheres observed today. Hot Jupiters are the type of exoplanet currently most amenable to study. Highlights include: detection of molecular spectral features; observation of day-night temperature gradients; and constraints on vertical atmospheric structure. Atmospheres of giant planets far from their host stars are also being studied with direct imaging. The ultimate exoplanet goal is to answer the enigmatic and ancient question, "Are we alone?" via detection of atmospheric biosignatures. Two exciting prospects are the immediate focus on transiting super Earths orbiting in the habitable zone of M-dwarfs, and u...

  10. Validation of HITEMP-2010 for carbon dioxide and water vapour at high temperatures and atmospheric pressures in 450-7600cm-1 spectral range

    DEFF Research Database (Denmark)

    Alberti, Michael; Weber, Roman; Mancini, Marco

    2015-01-01

    The objective of the work is validation of HITEMP-2010 at atmospheric pressures and temperatures reaching 1770K. To this end, spectral transmissivities at 1cm-1 resolution and excellent signal-to-noise-ratio have been measured for 22 CO2/H2O/N2 mixtures. In this paper we consider the 450cm-1-7600cm...

  11. Gas chromatography interfaced with atmospheric pressure ionization-quadrupole time-of-flight-mass spectrometry by low-temperature plasma ionization

    DEFF Research Database (Denmark)

    Norgaard, Asger W.; Kofoed-Sorensen, Vivi; Svensmark, Bo

    2013-01-01

    A low temperature plasma (LTP) ionization interface between a gas chromatograph (GC) and an atmospheric pressure inlet mass spectrometer, was constructed. This enabled time-of-flight mass spectrometric detection of GC-eluting compounds. The performance of the setup was evaluated by injection...

  12. Modeling the impact of vapor thymol concentration, temperature and modified atmosphere condition on growth behavior of Salmonella spp. on raw shrimp

    Science.gov (United States)

    Salmonella spp. is a microorganism of concern, on a global basis, for raw shrimp. This research modeled the impact of vapor thymol concentration (0, 0.8 and 1.6 mg/l), storage temperature (8, 12 and 16 degree C) and modified atmosphere packaging (0.04 and 59.5 percent CO2) against the growth behavio...

  13. The role of large-scale atmospheric circulation in the formation of temperature anomalies in surface waters as illustrated by the northern part of the Pacific Ocean

    Science.gov (United States)

    Sorkina, A. I.

    1975-01-01

    One important reason for thermal anomalies in the ocean is the dynamic action of anomalous wind systems that set masses of surface water in motion; predominant longitudinal transport of water and air leads to a significant redistribution of cold and warm waters. Heat exchange between the ocean and atmosphere plays an additional role in the formation of water temperature anomalies.

  14. Interactive effects of soil temperature, atmospheric carbon dioxide and soil N on root development, biomass and nutrient uptake of winter wheat during vegetative growth.

    Science.gov (United States)

    Gavito, M E; Curtis, P S; Mikkelsen, T N; Jakobsen, I

    2001-09-01

    Nutrient requirements for plant growth are expected to rise in response to the predicted changes in CO(2) and temperature. In this context, little attention has been paid to the effects of soil temperature, which limits plant growth at early stages in temperate regions. A factorial growth-room experiment was conducted with winter wheat, varying soil temperature (10 degrees C and 15 degrees C), atmospheric CO(2) concentration (360 and 700 ppm), and N supply (low and high). The hypothesis was that soil temperature would modify root development, biomass allocation and nutrient uptake during vegetative growth and that its effects would interact with atmospheric CO(2) and N availability. Soil temperature effects were confirmed for most of the variables measured and 3-factor interactions were observed for root development, plant biomass components, N-use efficiency, and shoot P content. Importantly, the soil temperature effects were manifest in the absence of any change in air temperature. Changes in root development, nutrient uptake and nutrient-use efficiencies were interpreted as counterbalancing mechanisms for meeting nutrient requirements for plant growth in each situation. Most variables responded to an increase in resource availability in the order: N supply >soil temperature >CO(2).

  15. Remote measurement of atmospheric temperature profiles in clouds with rotational Raman lidar; Fernmessung atmosphaerischer Temperaturprofile in Wolken mit Rotations-Raman-Lidar

    Energy Technology Data Exchange (ETDEWEB)

    Behrendt, A. [GKSS-Forschungszentrum Geesthacht GmbH (Germany). Inst. fuer Physikalische und Chemische Analytik

    2000-07-01

    The development of a lidar receiver for remote measurements of atmospheric temperature profiles with the rotational Raman method is described. By a new receiver concept, this instrument allowed for the first time remote temperature measurements without any perturbation by the presence of clouds up to a backscatter ratio of 45. In addition, high efficiency of the spectral separation of atmospheric backscatter signals leads to improved measurement resolution: the minimum integration time needed for a statistical uncertainty < {+-}1 K at, e.g., 10 km height and 960 m height resolution is only 5 minutes. The measurement range extends to over 45 km altitude. Results of field campaigns obtained with the instrument are presented and discussed. In winter 1997/98, the instrument was transferred with the GKSS Raman lidar to Esrange (67.9 N, 21.1 E) in northern Sweden, where pioneering remote measurements of local temperatures in orographically induced polar stratospheric clouds could be carried out. (orig.)

  16. GHRSST Level 2P Global skin Sea Surface Temperature from the Infrared Atmospheric Sounding Interferometer (IASI) on the Metop-A satellite (GDS V2) produced by OSI SAF (GDS version 2)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A global 1 km Group for High Resolution Sea Surface Temperature (GHRSST) Level 2P dataset based on multi-channel sea surface temperature (SST) retrievals generated...

  17. GHRSST Level 2P Global skin Sea Surface Temperature from the Infrared Atmospheric Sounding Interferometer (IASI) on the Metop-B satellite (GDS V2) produced by OSI SAF (GDS version 2)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A Group for High Resolution Sea Surface Temperature (GHRSST) Level 2P dataset based on multi-channel sea surface temperature (SST) retrievals generated in real-time...

  18. Local flux-profile relationships of wind speed and temperature in a canopy layer in atmospheric stable conditions

    Directory of Open Access Journals (Sweden)

    G. Zhang

    2010-11-01

    Full Text Available The particularities of the physics of the canopy layer pose challenges to the determination and use of traditional universal functions so helpful in the atmospheric surface layer. Progress toward "universal-like functions" such as those provided by Monin-Obukhov similarity theory for the canopy layer has been modest. One of the challenges lies in that the assumptions underlying Monin-Obukhov similarity theory do not hold within a canopy layer. This paper thus examines the local flux-profile relations for wind (Φm and for temperature (Φh. It uses three different stability parameters, i.e., h/L(h at tree top, local z/L(z, and the local bulk Richardson number (Ri, within a tall forest canopy in nighttime stable (indicated by h/L(h > 0 conditions. Results suggest that the in-canopy Φm can be described using the local Richardson number Ri. Furthermore, Φm is found to increase linearly with Ri in the upper canopy layer for |Ri| < 1. When local |Ri| > 1, |Φm| decreases with |Ri| in a power function, a result consistent for all levels of measurements within the canopy. When both local Φh and local Ri are positive, i.e., the local downward turbulent heat flux is consistent with the local temperature gradient, the local Φh increases with the local Ri when Ri < 1. However, Φh does not change with Ri (or much more scattered when Ri > 1. The relationship between local Φh and Ri disappears when counter-gradient heat transfer occurs in strongly stable conditions. A self-correlation analysis is used to examine the influence of self-correlation and the physical meaning of these relationships.

  19. Atmospheric temperature profiling in the presence of clouds with a pure rotational Raman lidar by use of an interference-filter-based polychromator.

    Science.gov (United States)

    Behrendt, A; Reichardt, J

    2000-03-20

    A lidar polychromator design for the measurement of atmospheric temperature profiles in the presence of clouds with the rotational Raman method is presented. The design utilizes multicavity interference filters mounted sequentially at small angles of incidence. Characteristics of this design are high signal efficiency and adjustable center wavelengths of the filters combined with a stable and relatively simple experimental setup. High suppression of the elastic backscatter signal in the rotational Raman detection channels allows temperature measurements independent of the presence of thin clouds or aerosol layers; no influence of particle scattering on the lidar temperature profile was observed in clouds with a backscatter ratio of at least 45. The minimum integration time needed for temperature profiling with a statistical temperature error of +/-1 K at, e.g., 20-km height and 960-m height resolution is 1.5 h.

  20. An All-Solid-State, Room-Temperature, Heterodyne Receiver for Atmospheric Spectroscopy at 1.2 THz

    Science.gov (United States)

    Siles, Jose V.; Mehdi, Imran; Schlecht, Erich T.; Gulkis, Samuel; Chattopadhyay, Goutam; Lin, Robert H.; Lee, Choonsup; Gill, John J.; Thomas, Bertrand; Maestrini, Alain E.

    2013-01-01

    been specifically optimized to maximize the mixer performance beyond 1 THz. The measured DSB noise temperatures and conversion losses of the receiver are 2,000 to 3,500 K and 12 to 14 dB, respectively, at 120 K, and 4,000 to 6,000 K and 13 to 15 dB, respectively, at 300 K. These results establish the state-of-the-art for all-solid-state, all-planar heterodyne receivers at 1.2 THz operating at either room temperature or using passive cooling only. Since no cryogenic cooling is needed, the receiver is eminently suited to atmospheric heterodyne spectroscopy of the outer planets and their moons.

  1. Improved Determination of Surface and Atmospheric Temperatures Using Only Shortwave AIRS Channels: The AIRS Version 6 Retrieval Algorithm

    Science.gov (United States)

    Susskind, Joel; Blaisdell, John; Iredell, Lena

    2010-01-01

    AIRS was launched on EOS Aqua on May 4, 2002 together with ASMU-A and HSB to form a next generation polar orbiting infrared and microwave atmosphere sounding system (Pagano et al 2003). The theoretical approach used to analyze AIRS/AMSU/HSB data in the presence of clouds in the AIRS Science Team Version 3 at-launch algorithm, and that used in the Version 4 post-launch algorithm, have been published previously. Significant theoretical and practical improvements have been made in the analysis of AIRS/AMSU data since the Version 4 algorithm. Most of these have already been incorporated in the AIRS Science Team Version 5 algorithm (Susskind et al 2010), now being used operationally at the Goddard DISC. The AIRS Version 5 retrieval algorithm contains three significant improvements over Version 4. Improved physics in Version 5 allowed for use of AIRS clear column radiances (R(sub i)) in the entire 4.3 micron CO2 absorption band in the retrieval of temperature profiles T(p) during both day and night. Tropospheric sounding 15 micron CO2 observations were used primarily in the generation of clear column radiances (R(sub i)) for all channels. This new approach allowed for the generation of accurate Quality Controlled values of R(sub i) and T(p) under more stressing cloud conditions. Secondly, Version 5 contained a new methodology to provide accurate case-by-case error estimates for retrieved geophysical parameters and for channel-by-channel clear column radiances. Thresholds of these error estimates are used in a new approach for Quality Control. Finally, Version 5 contained for the first time an approach to provide AIRS soundings in partially cloudy conditions that does not require use of any microwave data. This new AIRS Only sounding methodology was developed as a backup to AIRS Version 5 should the AMSU-A instrument fail. Susskind et al 2010 shows that Version 5 AIRS Only sounding are only slightly degraded from the AIRS/AMSU soundings, even at large fractional cloud

  2. A Microwave Radiometric Method to Obtain the Average Path Profile of Atmospheric Temperature and Humidity Structure Parameters and Its Application to Optical Propagation System Assessment

    Science.gov (United States)

    Manning, Robert M.; Vyhnalek, Brian E.

    2015-01-01

    The values of the key atmospheric propagation parameters Ct2, Cq2, and Ctq are highly dependent upon the vertical height within the atmosphere thus making it necessary to specify profiles of these values along the atmospheric propagation path. The remote sensing method suggested and described in this work makes use of a rapidly integrating microwave profiling radiometer to capture profiles of temperature and humidity through the atmosphere. The integration times of currently available profiling radiometers are such that they are approaching the temporal intervals over which one can possibly make meaningful assessments of these key atmospheric parameters. Since these parameters are fundamental to all propagation conditions, they can be used to obtain Cn2 profiles for any frequency, including those for an optical propagation path. In this case the important performance parameters of the prevailing isoplanatic angle and Greenwood frequency can be obtained. The integration times are such that Kolmogorov turbulence theory and the Taylor frozen-flow hypothesis must be transcended. Appropriate modifications to these classical approaches are derived from first principles and an expression for the structure functions are obtained. The theory is then applied to an experimental scenario and shows very good results.

  3. High throughput measurement of high temperature strength of ceramics in controlled atmosphere and its use on solid oxide fuel cell anode supports

    DEFF Research Database (Denmark)

    Frandsen, Henrik Lund; Curran, Declan; Rasmussen, Steffen;

    2014-01-01

    In the development of structural and functional ceramics for high temperature electrochemical conversion devices such as solid oxide fuel cells, their mechanical properties must be tested at operational conditions, i.e. at high temperature and controlled atmospheres. Furthermore, characterization...... of the strength of ceramic components requires testing of a high number of samples due to stochastic failures. Successive heating and testing a single sample is very time consuming and consequently this hinders thorough studies with sufficient samples at operational conditions. This work presents a methodology...

  4. Monitoring middle-atmospheric dynamics using independent ground-based wind and temperature measurements at Reunion Island

    Science.gov (United States)

    Le Pichon, Alexis; Hauchecorne, Alain; Keckhut, Philippe; Khaykin, Sergey; Camas, Jean Pierre; Payen, Guillaume; Kämpfer, Niklaus; Rüfenacht, Rolf; Ceranna, Lars

    2016-04-01

    There are very few multi-instrumented sites in the tropics and particularly in the Southern Hemisphere. In these regions, developing atmospheric sounding methods in the middle and high-atmosphere provides valuable means to improve the physical representation of deep convection in atmospheric models (breaking of gravity waves, coupling between layers) and to better characterize large-scale atmospheric perturbations (cyclones, storms, tropical convection). The Maïdo observatory at Reunion Island (21°S, 55°E) offers trans-national access to host experiments or measurement campaigns for high resolution measurements of dynamic atmospheric processes in a wide range of altitude such as Rayleigh lidar, Doppler lidar, Modem radiosonde, or microwave Doppler spectro-radiometer (WIRA, operated by Institute of Applied Physics, University of Bern). Collocated to the existing instruments, a small aperture infrasound array (CEA) has been operating continuously since 2014. In the 0.1-1 Hz band, the coherent energy is dominated by microbarom signals resulting from the non-linear interaction of large swells systems which circulate along the Antarctic Circumpolar Current (ACC). The seasonal transition in the bearings along with the stratospheric general circulation between summer and winter is clearly noted. Interestingly, the semiannual oscillation (SAO) of the zonal stratospheric wind is well captured by infrasound measurements. It manifests by opposite ducts between 30 and 60 km that persist for several weeks during the equinox period. For the ARISE project (http://arise-project.eu/), this multi-technology site opens new perspectives to study the climatology of SAO as well as poorly resolved atmospheric disturbances of the tropical middle atmosphere where data coverage is sparse.

  5. The impact of temperature dependent CO2 cross section measurements: A role for heterogeneous chemistry in the atmosphere of Mars?

    Science.gov (United States)

    Anbar, A. D.; Allen, M.; Nair, H.; Leu, M-T.; Yung, Y. L.

    1992-01-01

    Carbon dioxide comprises over 95 percent of the Mars atmosphere, despite continuous photolysis of CO2 by solar ultraviolet (UV) radiation. Since the direct recombination of CO and O is spinforbidden, the chemical stability of CO2 in the Martian atmosphere is thought to be the result of a HO(x)-catalyzed recombination scheme. Thus the rate of CO oxidation is sensitive to the abundance and altitude distribution of OH, H, and HO2. Most Martian atmospheric models assume that HO(x) abundances are governed purely by gas phase chemistry. However, it is well established that reactive HO(x) radical are adsorbed by a wide variety of surfaces. The authors have combined laboratory studies of H, OH, and HO2 adsorption on inorganic surfaces, observational data of aerosol distributions, and an updated photochemical model to demonstrate that adsorption on either dust or ice aerosols is capable of reducing HO(x) abundances significantly, thereby retarding the rate of CO oxidation.

  6. A forward model for calculating the AMSR brightness temperatures of sea-ice and ocean as seen through the atmosphere

    DEFF Research Database (Denmark)

    Pedersen, Leif Toudal; Hofmann-Bang, Dorthe

    This report describes a forward model for open water and the atmosphere, and how the contribution from sea ice can be included in these. In addition the report describes a retrieval algorithm that allows validation of the forward model. The model and the algorithm are verified by comparison...... with SSM/I retrievals, with ocean and atmosphere retrievals by Remote Sensing Systems, with SST data from the Ocean and Sea Ice SAF and with sea ice concentrations and MY-fractions of the NASA Team and Comiso Bootstrap sea ice algorithms. The forward model is the level 0 emissivity and radiative transfer...

  7. ESA STSE Project “Sea Surface Temperature Diurnal Variability: Regional Extend – Implications in Atmospheric Modelling”

    DEFF Research Database (Denmark)

    Karagali, Ioanna

    , atmospheric and oceanic modelling, bio-chemical processes and oceanic CO2 studies. The diurnal variability of SST, driven by the coincident occurrence of low enough wind and solar heating, is currently not properly understood. Atmospheric, oceanic and climate models are currently not adequately resolving...... present the final project findings regarding the analysis of hourly SEVIRI SSTs from SEVIRI over the Atlantic Ocean and the European Seas, revealing the regional extend of diurnal warming. As satellite SSTs are representative of the upper centimetre of the water column, they do not provide information...

  8. Atmospheric Refraction

    CERN Document Server

    Nauenberg, Michael

    2016-01-01

    Calculations of atmospheric refraction are generally based on a simplified model of atmospheric density in the troposphere which assumes that the temperature decreases at a constant lapse rate from sea level up to a height equal to eleven km, and that afterwards it remains constant. In this model, the temperature divided by the lapse rate determines the length scale in the calculations for altitudes less than this height. But daily balloon measurements across the U.S.A. reveal that in some cases the air temperature actually increases from sea level up to a height of about one km, and only after reaching a plateau, it decreases at an approximately constant lapse rate. Moreover, in three examples considered here, the temperature does not remain constant at eleven km , but continues to decreases to a minimum at about sixteen kilometers , and then increases at higher altitudes at a lower rate. Calculations of atmospheric refraction based on this atmospheric data is compared with the results of simplified models.

  9. Design and construction of an irradiation apparatus with controlled atmosphere and temperature for radiation damage evaluation of nuclear materials in the IEA-R1 research reactor

    Energy Technology Data Exchange (ETDEWEB)

    Lucki, Georgi; Silva, Jose Eduardo Rosa da; Castanheira, Myrthes; Terremoto, Luis Antonio Albiac; Teodoro, Celso Antonio; Silva, Antonio Teixeira e; Damy, Margaret de Almeida [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)]. E-mail: glucki@ipen.br

    2005-07-01

    A material irradiation apparatus CIMAT (Capsula de Irradiacao de Materiais) with controlled temperature and atmosphere is described. The device was specifically designed to perform experiments inside the core of the IEA-R1 swimming pool reactor and allows fast neutron (E=1 MeV) irradiations of multiple miniature metallic samples at temperature between 100 deg C and 500 deg C, in Argon or Helium atmosphere to inhibit corrosion. The aim of CIMAT is to make a comparative assessment of Radiation Embrittlement (RE) on the AS 508 cl.3 steel, of different origins (ELETROMETAL-Brazil and VITCOVICE-Chekia) used in Pressure Vessels (PV) of PWR, for fluence of 10 exp 19 nvt at 300 C, by means of mechanical post irradiation evaluation. Previous characterization of non-irradiated samples of these materials is presented. In situ electrical and magnetic measurements, at high temperatures, are foreseen to be made with this apparatus. Extensive temperature stability and leak-tightness tests performed in the reactor swimming pool have proven the CIMAT to be intrinsically safe and operational. (author)

  10. The upper atmosphere of the exoplanet HD209458b revealed by the sodium D lines: Temperature-pressure profile, ionization layer, and thermosphere

    CERN Document Server

    Vidal-Madjar, A; Etangs, A Lecavelier des; Ferlet, R; Desert, J -M; Hebrard, G; Boisse, I; Ehrenreich, D; Moutou, C

    2010-01-01

    A complete reassessment of the HST observations of the transits of the extrasolar planet HD209458b has provided a transmission spectrum of the atmosphere over a wide range of wavelengths. Analysis of the NaI absorption line profile has already shown that the sodium abundance has to drop by at least a factor of ten above a critical altitude. Here we analyze the profile in the deep core of the NaI doublet line from HST and high-resolution ground-based spectra to further constrain the vertical structure of the HD209458b atmosphere. With a wavelength-dependent cross section that spans more than 5 orders of magnitude, we use the absorption signature of the NaI doublet as an atmospheric probe. The NaI transmission features are shown to sample the atmosphere of HD209458b over an altitude range of more than 6500km, corresponding to a pressure range of 14 scale heights spanning 1 millibar to 1e-9 bar pressures. By comparing the observations with a multi-layer model in which temperature is a free parameter at the resol...

  11. Tight coupling between atmospheric ρCO2 and temperature change during the Late Triassic: observational evidence for enhanced climate sensitivity in a hothouse state

    Science.gov (United States)

    Knobbe, T.; Schaller, M. F.

    2015-12-01

    Climate sensitivity is the change in global equilibrium surface temperature per doubling of atmospheric ρCO2. Modern climate sensitivity, based on paleoclimate data and fast-feedback processes (Charney sensitivity), is observed to be ~3°C per doubling of CO2. However, Charney sensitivity may not be representative of ice-free hothouse states that have dominated most of Earth history where sensitivity may be higher. Few opportunities exist to empirically determine climate sensitivity during a hothouse state based on contemporaneous observations of ρCO2 and temperature. Here we present evidence for tight coupling between ρCO2 and temperature during the Late Triassic (end-Norian through Rhaetian) from the Newark basin and Lagonegro/Sicani basins, respectively. Detailed magnetostratigraphy and biostratigraphy allows for correlation between the Lagonegro and Sicani basins (Italy), which are magnetostratigraphically correlated to the Newark basin. Temperature is calculated from δ18O values of conodont apatite published from the Lagonegro and Sicani basins, while ρCO2 estimates are from pedogenic carbonates in the Newark basin. We find a distinct rise and subsequent fall in atmospheric ρCO2 that is precisely mirrored by a contemporaneous rise and fall in temperature. Between 212-209 Ma, we observe a concomitant increase in ρCO2 (1900 to 4800 ppm) and temperature (20 to 27°C), followed by a more protracted concomitant decrease in atmospheric ρCO2 (4800 to 2200 ppm) and temperature (27 to 21°C) from 209-202 Ma. We use simple numerical methods to calculate climate sensitivity for the Late Triassic from these complementary data sets and find that sensitivity through both a doubling and subsequent halving of pCO2 are on the order of 5°C, in close agreement with empirically based model assessments from younger sections. We note sensitivities as high as 7°C/doubling are observed when using the lowest pCO2 estimate allowed by the formal error window assigned to the

  12. Effects of Milling Atmosphere and Increasing Sintering Temperature on the Magnetic Properties of Nanocrystalline Ni0.36Zn0.64Fe2O4

    Directory of Open Access Journals (Sweden)

    Abdollah Hajalilou

    2015-01-01

    Full Text Available Nanocrystalline Ni0.36Zn0.64Fe2O4 was synthesized by milling a powder mixture of Zn, NiO, and Fe2O3 in a high-energy ball mill for 30 h under three different atmospheres of air, argon, and oxygen. After sintering the 30 h milled samples at 500°C, the XRD patterns suggested the formation of a single phase of Ni-Zn ferrite. The XRD results indicated the average crystallite sizes to be 15, 14, and 16 nm, respectively, for the 30 h milled samples in air, argon, and oxygen atmospheres sintered at 500°C. From the FeSEM micrographs, the average grain sizes of the mentioned samples were 83, 75, and 105 nm, respectively, which grew to 284, 243, and 302 nm after sintering to 900°C. A density of all the samples increased while a porosity decreased by elevating sintering temperature. The parallel evolution of changes in magnetic properties, due to microstructural variations with changes in the milling atmosphere and sintering temperature in the rage of 500–900°C with 100°C increments, is also studied in this work.

  13. Correlations of the first and second derivatives of atmospheric CO2 with global surface temperature and the El Nino-Southern Oscillation respectively

    CERN Document Server

    Leggett, L M W

    2014-01-01

    Understanding current global climate requires an understanding of trends both in Earth's atmospheric temperature and the El Nino-Southern Oscillation (ENSO), a characteristic large-scale distribution of warm water in the tropical Pacific Ocean and the dominant mode of year-to-year climate variability (Holbrook et al. 2009. However, despite much effort, the average projection of current climate models has become statistically significantly different from the observed 21st century global surface temperature trend (Fyfe 2013)and has failed to reflect the statistically significant evidence that annual-mean global temperature has not risen in the 21st century (Fyfe 2013, Kosaka 2013). Modelling also provides a wide range of predictions for future ENSO variability, some showing an increase, others a decrease and some no change (Guilyardi, et al. 2012; Bellenger, 2013). Here we present correlations which include the current era and do not have these drawbacks. The correlations arise as follows. First it has been sho...

  14. Impact of Rain Snow Threshold Temperature on Snow Depth Simulation in Land Surface and Regional Atmospheric Models

    Institute of Scientific and Technical Information of China (English)

    WEN Lijuan; Nidhi NAGABHATLA; L(U) Shihua; Shih-Yu WANG

    2013-01-01

    This study investigates the impact of rain snow threshold (RST) temperatures on snow depth simulation using the Community Land Model (CLM) and the Weather Research and Forecasting model (WRF coupled with the CLM and hereafter referred to as WRF_CLM),and the difference in impacts.Simulations were performed from 17 December 1994 to 30 May 1995 in the French Alps.Results showed that both the CLM and the WRF_CLM were able to represent a fair simulation of snow depth with actual terrain height and 2.5℃ RST temperature.When six RST methods were applied to the simulation using WRF_CLM,the simulated snow depth was the closest to observations using 2.5℃ RST temperature,followed by that with Pipes',USACE,Kienzle's,Dai's,and 0℃ RST temperature methods.In the case of using CLM,simulated snow depth was the closest to the observation with Dai's method,followed by with USACE,Pipes',2.5℃ RST temperature,Kienzle's,and 0℃ RST temperature method.The snow depth simulation using the WRF_CLM was comparatively sensitive to changes in RST temperatures,because the RST temperature was not only the factor to partition snow and rainfall.In addition,the simulated snow related to RST temperature could induce a significant feedback by influencing the meteorological variables forcing the land surface model in WRF_CLM.In comparison,the above variables did not change with changes in RST in CLM.Impacts of RST temperatures on snow depth simulation could also be influenced by the patterns of temperature and precipitation,spatial resolution,and input terrain heights.

  15. Long-term ground-based microwave radiometric measurements of atmospheric brightness temperature in SKYNET Hefei (31.90N, 117.17E) site

    Science.gov (United States)

    Wang, Zhenzhu; Liu, Dong; Xie, Chenbo; Wang, Bangxin; Zhong, Zhiqing; Wang, Yingjian; Chen, Bin

    2017-02-01

    A dual-frequency, ground-based microwave radiometer (WVR-1100) is used to investigate the behavior of the atmosphere in terms of zenith brightness temperature (TB) at 23.8 and 31.4 GHz respectively. Some experimental findings in SKYNET Hefei site from September 2002 to August 2012 are presented. The cumulative distributions of TB at both frequencies for all sky conditions show four different regions, while only two regions can be identified for clear, lightly cloudy and cloudy condition. Annual cycle of TB at 23.8 GHz is apparently remarkable, indicating the large annual cycle of atmospheric water vapor. Regular seasonal variations of TB are observed with the strongest value in summer and the weakest in winter.

  16. Research on the changes of the tidal force and the air temperature in the atmosphere of Lushan (China Ms7.0 earthquake

    Directory of Open Access Journals (Sweden)

    Ma Weiyu

    2015-01-01

    Full Text Available The cycle process of the tidal force of celestial body for Lushan M7.0 earthquake, occurred in Lushan county of Sichuan, China on April 20, 2013 was calculated. The earthquake occurred at the lowest point phase. It indicated that the type of seismogenic fault that the tide force acted on belonged to the thrust fault. According to the tidal cycle, the abnormal air temperature change was analyzed based on NCEP satellite data around the whole China before and after the earthquake. The result showed that the air temperature changed evidently with the tide force changing. In temporal, the change went through: initial air temperature rise → strength→ reaching abnormal peak→ gradually decline; in spatial, the abnormal area winded its way along the margin of the southern Qinghai-Tibet Plateau and went through: scattered→ conversion→ scattered procession. The procession was similar to the change procession of a rock breaking under the stress loading. This shows that the stress change of rock may cause the air temperature change in the atmosphere before and after earthquake. It indicated that the tidal force of celestial body could trigger the earthquake, when the tectonic stress reaches its critical broken point and the air temperature anomaly was proportional to the seismic tectonic stress change. It was useful to combine air temperature and tidal force in earthquake precursory.

  17. Estimation of the Total Atmospheric Water Vapor Content and Land Surface Temperature Based on AATSR Thermal Data

    Directory of Open Access Journals (Sweden)

    Rong Liu

    2008-03-01

    Full Text Available The total atmospheric water vapor content (TAWV and land surfacetemperature (LST play important roles in meteorology, hydrology, ecology and some otherdisciplines. In this paper, the ENVISAT/AATSR (The Advanced Along-Track ScanningRadiometer thermal data are used to estimate the TAWV and LST over the Loess Plateauin China by using a practical split window algorithm. The distribution of the TAWV isaccord with that of the MODIS TAWV products, which indicates that the estimation of thetotal atmospheric water vapor content is reliable. Validations of the LST by comparingwith the ground measurements indicate that the maximum absolute derivation, themaximum relative error and the average relative error is 4.0K, 11.8% and 5.0%respectively, which shows that the retrievals are believable; this algorithm can provide anew way to estimate the LST from AATSR data.

  18. The Effect of Scattering on the Temperature Stratification of 3D Model Atmospheres of Metal-Poor Red Giants

    Science.gov (United States)

    Collet, Remo; Hayek, Wolfgang; Asplund, Martin

    2011-08-01

    We study the effects of different approximations of scattering in 3D radiation-hydrodynamics simulations on the photospheric temperature stratification of metal-poor red giant stars. We find that assuming a Planckian source function and neglecting the contribution of scattering to extinction in optically thin layers provides a good approximation of the effects of coherent scattering on the photospheric temperature balance.

  19. Lead-lag relationships between global mean temperature and the atmospheric CO2 content in dependence of the type and time scale of the forcing

    Science.gov (United States)

    Muryshev, Kirill E.; Eliseev, Alexey V.; Mokhov, Igor I.; Timazhev, Alexandr V.

    2017-01-01

    By employing an Earth system model of intermediate complexity (EMIC) developed at the A.M. Obukhov Institute of Atmospheric Physics, Russian Academy of Sciences (IAP RAS CM), mutual lags between global mean surface air temperature, T and the atmospheric CO2 content, q, in dependence of the type and time scale of the external forcing are explored. In the simulation, which follows the protocol of the Coupled Models Intercomparison Project, phase 5, T leads q for volcanically-induced climate variations. In contrast, T lags behind q for changes caused by anthropogenic CO2 emissions into the atmosphere. In additional idealized numerical experiments, driven by periodic external emissions of carbon dioxide into the atmosphere, T always lags behind q as expected. In contrast, if the model is driven by the periodic non-greenhouse radiative forcing, T leads q for the external forcing time scale ≤4 ×102 yr, while q leads T at longer scales. The latter is an example that lagged correlations do not necessarily represent causal relationships in a system. This apparently counter-intuitive result, however, is a direct consequence of i) temperature sensitivity of the soil carbon stock (which decreases if climate is warmed and increases if climate is cooled), ii) conservation of total mass of carbon in the system in the absence of external carbon emissions, iii) increased importance of the oceanic branch of the carbon cycle at longer time scales. The results obtained with an EMIC are further interpreted with a conceptual Earth system model consisting of an energy balance climate model and a globally averaged carbon cycle model. The obtained results have implications to the empirical studies attempting to understand the origins of the contemporary climate change by applying lead-lag relationships to empirical data.

  20. Semi-classical H2-broadening coefficients of 12CH3D rovibrational lines and their temperature dependence for planetary atmosphere modeling

    Science.gov (United States)

    Sinyakova, T.; Buldyreva, J.

    2017-01-01

    Theoretical hydrogen-broadening coefficients and associated temperature exponents for 12CH3D (J, K) lines in parallel (ΔK = 0) bands are calculated by a semi-classical approach based on a rigorous consideration of the active molecule as a symmetric top, a model intermolecular potential comprising both short- and long-range interactions, and exact classical trajectories. The leading potential terms are shown to provide a realistic description of line broadening in comparison with scarce measurements available in the literature. The calculations performed for 296, 240 and 190 K are used to extract the line-width temperature-dependence exponents for the typical temperature range of atmospheric interest ∼200-300 K. Detailed P-Q-R-line lists are provided for large intervals of quantum numbers (0 ≤ J ≤ 20, 0 ≤ K ≤ J) requested for remote sensing of planetary atmospheres, in particular those of outer planets and their moons. With negligible vibrational dependence of CH3D line-widths and estimated as negligible their sub-branch dependence, these data can be also employed for perpendicular bands.

  1. A Critical Review of Published Data on the Gas Temperature and the Electron Density in the Electrolyte Cathode Atmospheric Glow Discharges

    Directory of Open Access Journals (Sweden)

    Tamás Cserfalvi

    2012-05-01

    Full Text Available Electrolyte Cathode Discharge (ELCAD spectrometry, a novel sensitive multielement direct analytical method for metal traces in aqueous solutions, was introduced in 1993 as a new sensing principle. Since then several works have tried to develop an operational mechanism for this exotic atmospheric glow plasma technique, however these attempts cannot be combined into a valid model description. In this review we summarize the conceptual and technical problems we found in this upcoming research field of direct sensors. The TG gas temperature and the ne electron density values published up to now for ELCAD are very confusing. These data were evaluated by three conditions. The first is the gas composition of the ELCAD plasma, since TG was determined from the emitted intensity of the N2 and OH bands. Secondly, since the ELCAD is an atmospheric glow discharge, thus, the obtained TG has to be close to the Te electron temperature. This can be used for the mutual validation of the received temperature data. Thirdly, as a consequence of the second condition, the values of TG and ne have to agree with the Engel-Brown approximation of the Saha-equation related to weakly ionized glow discharge plasmas. Application of non-adequate experimental methods and theoretical treatment leads to unreliable descriptions which cannot be used to optimize the detector performance.

  2. 2012/13 abnormal cold winter in Japan associated with Large-scale Atmospheric Circulation and Local Sea Surface Temperature over the Sea of Japan

    Science.gov (United States)

    Ando, Y.; Ogi, M.; Tachibana, Y.

    2013-12-01

    On Japan, wintertime cold wave has social, economic, psychological and political impacts because of the lack of atomic power stations in the era of post Fukushima world. The colder winter is the more electricity is needed. Wintertime weather of Japan and its prediction has come under the world spotlight. The winter of 2012/13 in Japan was abnormally cold, and such a cold winter has persisted for 3 years. Wintertime climate of Japan is governed by some dominant modes of the large-scale atmospheric circulations. Yasunaka and Hanawa (2008) demonstrated that the two dominant modes - Arctic Oscillation (AO) and Western Pacific (WP) pattern - account for about 65% of the interannual variation of the wintertime mean surface air temperature of Japan. A negative AO brings about cold winter in Japan. In addition, a negative WP also brings about cold winter in Japan. Looking back to the winter of 2012/13, both the negative AO and negative WP continued from October through December. If the previous studies were correct, it would have been extremely very cold from October through December. In fact, in December, in accordance with previous studies, it was colder than normal. Contrary to the expectation, in October and November, it was, however, warmer than normal. This discrepancy signifies that an additional hidden circumstance that heats Japan overwhelms these large-scale atmospheric circulations that cool Japan. In this study, we therefore seek an additional cause of wintertime climate of Japan particularly focusing 2012 as well as the AO and WP. We found that anomalously warm oceanic temperature surrounding Japan overwhelmed influences of the AO or WP. Unlike the inland climate, the island climate can be strongly influenced by surrounding ocean temperature, suggesting that large-scale atmospheric patterns alone do not determine the climate of islands. (a) Time series of a 5-day running mean AO index (blue) as defined by Ogi et al., (2004), who called it the SVNAM index. For

  3. New Discoveries Resulted from Lidar Investigation of Middle and Upper Atmosphere Temperature, Composition, Chemistry and Dynamics at McMurdo, Antarctica

    Science.gov (United States)

    Chu, X.; Yu, Z.; Fong, W.; Chen, C.; Huang, W.; Lu, X.; Gardner, C. S.; McDonald, A.; Fuller-Rowell, T. J.; Vadas, S.

    2013-12-01

    The scientific motivation to explore the neutral properties of the polar middle and upper atmosphere is compelling. Human-induced changes in the Earth's climate system are one of the most challenging social and scientific issues in this century. Besides monitoring climate change, to fully explore neutral-ion coupling in the critical region between 100 and 200 km is an objective of highest priority for the upper atmosphere science community. Meteorological sources of wave energy from the lower atmosphere are responsible for producing significant variability in the upper atmosphere. Energetic particles and fields originating from the magnetosphere regularly alter the state of the ionosphere. These influences converge through the tight coupling between the ionosphere plasma and neutral thermosphere gas in the space-atmosphere interaction region (SAIR). Unfortunately measurements of the neutral thermosphere are woefully incomplete and in critical need to advance our understanding of and ability to predict the SAIR. Lidar measurements of neutral thermospheric winds, temperatures and species can enable these explorations. To help address these issues, in December 2010 we deployed an Fe Boltzmann temperature lidar to McMurdo (77.8S, 166.7E), Antarctica via collaboration between the United States Antarctic Program and Antarctica New Zealand. Since then an extensive dataset (~3000 h) has been collected by this lidar during its first 32 months of operation, leading to several important new discoveries. The McMurdo lidar campaign will continue for another five years to acquiring long-term datasets for polar geospace research. In this paper we provide a comprehensive overview of the lidar campaign and scientific results, emphasizing several new discoveries in the polar middle and upper atmosphere research. In particular, the lidar has detected neutral Fe layers reaching 170 km in altitude, and derived neutral temperature from 30 to 170 km for the first time in the world. Such

  4. Data in support of comparative analysis of strawberry proteome in response to controlled atmosphere and low temperature storage using a label-free quantification

    Directory of Open Access Journals (Sweden)

    Li Li

    2015-06-01

    Full Text Available To elucidate the mechanisms contributing to fruit responses to senescence and stressful environmental stimuli under low temperature (LT and controlled atmosphere (CA storage, a label-free quantitative proteomic investigation was conducted in strawberry (Fragaria ananassa, Duch. cv. ‘Akihime’. Postharvest volatile compounds were characterized following storage under different conditions. The observed post-storage protein expression profiles may be associated with delayed senescence features in strawberry [2]. A total of 454 proteins were identified in differentially treated strawberry fruits. Quantitative analysis, using normalized spectral counts, revealed 73 proteins common to all treatments, which formed three clusters in a hierarchical clustering analysis.

  5. Grid-pattern formation of extracellular matrix on silicon by low-temperature atmospheric-pressure plasma jets for neural network biochip fabrication

    Energy Technology Data Exchange (ETDEWEB)

    Ando, Ayumi, E-mail: ando@ppl.eng.osaka-u.ac.jp [Center for Atomic and Molecular Technologies, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871 (Japan); Uno, Hidetaka; Urisu, Tsuneo [FIRST Research Center for Innovative Nanobiodevice, Nagoya University, Furo-cho, Chikusa, Nagoya, Aichi, 464-8603 (Japan); Hamaguchi, Satoshi [Center for Atomic and Molecular Technologies, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871 (Japan)

    2013-07-01

    Grid patterns of extracellular matrices (ECMs) have been formed on silicon (Si) substrates with the use of low-temperature atmospheric-pressure plasma (APP) jets with metal stencil masks and neuron model cells have been successfully cultured on the patterned ECMs. Arrangement of living neuron cells on a microelectronics chip in a desired pattern is one of the major challenges for the fabrication of neuron-cell biochips. The APP-based technique presented in this study offers a cost-effective solution to this problem by providing a simple patterning method of ECMs, which act as biological interfaces between living cells and non-biological materials such as Si.

  6. Long-term temperature variations in the stratosphere and troposphere caused by changes in gas and aerosol composition of the atmosphere

    Science.gov (United States)

    Dyominov, I.; Zadorozhny, A.

    A numerical 2-D zonally averaged interactive dynamical radiative-photochemical model of the troposphere and stratosphere including aerosol physics is used for investigation of long-term temperature changes caused by anthropogenic pollution of the atmosphere by CO2 , CH4, N2O, CFCs, HCFCs, HFCs, CH 3CCl 3 and CCl4 as well as by discharges to the atmosphere of sulphate species during the Pinatubo eruption. The model allows calculating self-consistently diabatic circulation, temperature, gaseous composition of the troposphere and stratosphere at latitudes from the South to North Poles, as well as distribution of sulphate aerosol particles and polar stratospheric clouds (PSCs) of types I and II. The scenarios of expected changes of the anthropogenic pollutants for the period from 1990 through 2050 are taken from Climate Change 1995. The calculations of the long-term temperature variations due to anthropogenic emission s show that the greatest temperature changes are observed in the Southern Hemisphere in winter/spring periods. For example, the temperature changes at a height of 40 km at 45°S in December 2050 are about -4.85 K, 0.89 K, -2.21 K, and -4.32 K respectively for anthropogenic discharges of CO2, CH4, N2O, and chlorine species. The changes in the Northern Hemisphere are smaller. They are equal to about -4.5 K, 0.68 K, -1.46 K, and -3.17 K at 45°N. The temperature changes in the stratosphere are caused by the corresponding ozone variations and temperature feedbacks. In the troposphere, the temperature changes are determined by the greenhouse effect caused by optically active pollutants. For example, temperature increases near the Earth's surface at 45 °N in December of 2050 due to anthropogenic discharges of CO2, CH4, N2O, and chlorine species are about 0.87 K, 0.19 K, 0.14 K, and 0.32 K, respectively. The calculations show that short -term megaton discharges of sulphate species to the atmosphere during the Pinatubo eruption led to significant long

  7. Multi-temperature model derived from state-to-state kinetics for hypersonic entry in Jupiter atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Colonna, G.; Pietanza, L. D. [Istituto di Metodologie Inorganiche e Plasmi, CNR, Via Amendola 144/D, 70126 Bari (Italy); D' Ambrosio, D. [Dipartimento di Ingegneria Meccanica e Aerospaziale, Politecnico di Torino, Corso Duca degli Abruzzi 24, I-10129 Torino (Italy); D' Ammando, G.; Capitelli, M. [Istituto di Metodologie Inorganiche e Plasmi, CNR, Via Amendola 144/D, 70126 Bari, Italy and Dipartimento di Chimica, Universitá degli studi di Bari, Via Orabona 4, 70125 Bari (Italy)

    2014-12-09

    A state-to-state model of H{sub 2}/He plasmas coupling the master equations for internal distributions of heavy species with the transport equation for the free electrons has been used as a basis for implementing a multi-temperature kinetic model. In the multi-temperature model internal distributions of heavy particles are Boltzmann, the electron energy distribution function is Maxwell, and the rate coefficients of the elementary processes become a function of local temperatures associated to the relevant equilibrium distributions. The state-to-state and multi-temperature models have been compared in the case of a homogenous recombining plasma, reproducing the conditions met during supersonic expansion though converging-diverging nozzles.

  8. Temperature profile from NOAA Ship RESEARCHER and other platforms as part of the ARP (Global Atmospheric Research Program) Atlantic Tropical Experiment from 1974-08-28 to 1974-09-20 (NCEI Accession 7800314)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Temperature profile data were collected using BT and XBT from NOAA Ship RESEARCHER and other platforms in the TOGA area - Atlantic from 28 August 1974 to 20...

  9. Temperature, current meter, and other data from moored buoy from the HUMBOLDT as part of the GARP (Global Atmospheric Research Program) Atlantic Tropical Experiment (GATE) project, 28 July 1974 - 18 August 1974 (NODC Accession 7601676)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Temperature, current meter, and other data were collected using moored buoy from the HUMBOLDT from July 28, 1974 to August 18, 1974. Data were submitted by US Coast...

  10. Underway pressure, temperature, and salinity data from the MOANA WAVE from the Pacific warm pool in support of the Coupled Ocean-Atmosphere Response Experiment (COARE) from 02 February 1993 to 21 February 1993 (NODC Accession 9600090)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Pressure, temperature, and salinity data were collected while underway from the MOANA WAVE from the Pacific warm pool. Data were collected in support of the Coupled...

  11. Temperature, current meter, and other data from moored buoy as part of the GARP (Global Atmospheric Research Program) Atlantic Tropical Experiment (GATE) project, 30 July 1974 - 14 August 1974 (NODC Accession 7601675)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Temperature, current meter, and other data were collected using moored buoy from the CAPRICORNE from July 30, 1974 to August 14, 1974. Data were collected as part of...

  12. Electronic quenching of OH(A) by water in atmospheric pressure plasmas and its influence on the gas temperature determination by OH(A-X) emission

    Energy Technology Data Exchange (ETDEWEB)

    Bruggeman, Peter; Schram, Daan C [Department of Applied Physics, Technische Universiteit Eindhoven, PO Box 513, 5600 MB Eindhoven (Netherlands); Iza, Felipe; Kong, Michael G [Department of Electronic and Electrical Engineering, Loughborough University, Loughborough, Leicestershire LE11 3TU (United Kingdom); Guns, Peter; Lauwers, Daniel; Leys, Christophe [Department of Applied Physics, Ghent University, Jozef Plateaustraat 22, B-9000 Ghent (Belgium); Gonzalvo, Yolanda Aranda [Plasma and Surface Analysis Division, Hiden Analytical Ltd, 420 Europa Boulevard, Warrington WA5 7UN (United Kingdom)], E-mail: p.j.bruggeman@tue.nl

    2010-02-15

    In this paper it is shown that electronic quenching of OH(A) by water prevents thermalization of the rotational population distribution of OH(A). This means that the observed ro-vibrational OH(A-X) emission band is (at least partially) an image of the formation process and is determined not only by the gas temperature. The formation of negative ions and clusters for larger water concentrations can contribute to the non-equilibrium. The above is demonstrated in RF excited atmospheric pressure glow discharges in He-water mixtures in a parallel metal plate reactor by optical emission spectroscopy. For this particular case a significant overpopulation of high rotational states appears around 1000 ppm H{sub 2}O in He. The smallest temperature parameter of a non-Boltzmann (two-temperature) distribution fitted to the experimental spectrum of OH(A-X) gives a good representation of the gas temperature. Only the rotational states with the smallest rotational numbers (J {<=} 7) are thermalized and representative for the gas temperature.

  13. Heat engines and heat pumps in a hydrostatic atmosphere: How surface pressure and temperature control wind power output and circulation cell size

    CERN Document Server

    Makarieva, A M; Nefiodov, A V; Sheil, D; Nobre, A D; Shearman, P L; Li, B -L

    2015-01-01

    The gross spatial features of the atmospheric kinetic energy budget are analytically investigated. Kinetic energy generation is evaluated in a hydrostatic atmosphere where the axisymmetric circulation cells are represented by Carnot cycles. The condition that kinetic energy generation is positive in the lower atmosphere is shown to limit the poleward cell extension via a relationship between the meridional differences in surface pressure and temperature $\\Delta p_s$ and $\\Delta T_s$: an upper limit to cell size exists when $\\Delta p_s$ increases sublinearly with $\\Delta T_s$. This is the case for the Hadley cells as demonstrated here using data from MERRA re-analysis. The limited cell size necessitates the appearance of heat pumps -- circulation cells with negative work output where the low-level air moves towards colder areas. These cells consume the positive work output of heat engines -- cells where the low-level air moves towards the warmer areas -- and can in principle drive the global efficiency of atmo...

  14. Sm1.5Sr0.5MO4 (M=Ni,Co,Fe) Cathode Catalysts for Ammonia Synthesis at Atmospheric Pressure and Low Temperature

    Institute of Scientific and Technical Information of China (English)

    XU,Gaochao; LIU,Ruiquan

    2009-01-01

    Sm1.5Sr0.5MO4 (M=Ni,Co,Fe) (SSM) catalysts were prepared by a sol-gel method and characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM).Ammonia was synthesized from wet hydrogen and dry nitrogen at atmospheric pressure and low temperature (25-100 ℃) with applied voltage,using SSM as a cathode,Ni-Ce0.5Sm0.2O2-δ(Ni-SDC) as an anode,and silver-platinum film as a current collector,Nation proton exchange membrane as a proton permeating membrane.Several important factors on ammonia synthesis were investigated and the optimal synthetic temperature was found,at which the highest rate of evolution of ammonia was up to 1.05×10-8 mol·cm- 2·S-1.

  15. Influence of temperature on flammability limits of heat treating atmosphere%温度对热处理气氛可燃极限的影响

    Institute of Scientific and Technical Information of China (English)

    Dwyer John; Hansel James G.; Philips Tom; Chen Wayne; 侯学涛

    2011-01-01

    讨论了热处理气氛中常用气体成分的可燃极限,分析了上下可燃极限与温度的关系。提出了一个应用CAFT理论推断气氛可燃极限的方法,同时解释了温度对热处理炉安全操作的影响。%The flammability limits of gas constituents commonly used in heat treating atmospheres were discussed.The upper and lower flammability limits,with respect to temperature,were analyzed.A method was described for determining these limits using CAFT theory.This temperature factor and its impact on safe furnace practices were addressed.

  16. Effect of oxygen on the electrical conductivity of some metal oxides in inert and reducing atmospheres at high temperature

    Energy Technology Data Exchange (ETDEWEB)

    Jones, T.A.; Firth, J.G.; Mann, B.

    1985-12-01

    An investigation has been carried out on the electrical behaviour at 900/sup 0/C of some ceramic oxides as a function of oxygen pressure. Measurements have been made in an inert (N/sub 2/) atmosphere and in an inert atmosphere containing reducing gases (CO, H/sub 2/ and CH/sub 4/). The oxides for which data are presented are Cr/sub 2/O/sub 3/, Nb/sub 2/O/sub 5/, CeO/sub 2/, ThO/sub 2/ and Ga/sub 2/O/sub 3/. The factors affecting the electrical conductivities of these materials are briefly reviewed. The conductivities of Cr/sub 2/O/sub 3/, Nb/sub 2/O/sub 5/ and CeO/sub 2/ showed a switch-like behaviour at the stoichiometric mixture of oxygen and reducing gas. Ga/sub 2/O/sub 3/ and ThO/sub 2/ do not exhibit this type of behaviour, the conductivities changing monotonically with increasing oxygen pressure. The possible reasons for this difference in behaviour are discussed. Data are also presented showing the behaviour of a sensor based on Ga/sub 2/O/sub 3/ in a vehicle exhaust. This shows its potential as a means of monitoring exhaust emissions with a view to controlling the air/fuel ratios at around the stoichiometric mixture.

  17. Effects of aging temperature on electrical conductivity and hardness of Cu-3 at. pct Ti alloy aged in a hydrogen atmosphere

    KAUST Repository

    Semboshi, S.

    2011-08-01

    To improve the balance of the electrical conductivity and mechanical strength for dilute Cu-Ti alloys by aging in a hydrogen atmosphere, the influence of aging temperature ranging from 673 K to 773 K (400 °C to 500 °C) on the properties of Cu-3 at. pct Ti alloy was studied. The Vickers hardness increases steadily with aging time and starts to fall at 3 hours at 773 K (500 °C), 10 hours at 723 K (450 °C), or over 620 hours at 673 K (400 °C), which is the same as the case of conventional aging in vacuum. The maximum hardness increases from 220 to 236 with the decrease of aging temperature, which is slightly lower than aging at the same temperature in vacuum. The electrical conductivity at the maximum hardness also increases from 18 to 32 pct of pure copper with the decrease of the temperature, which is enhanced by a factor of 1.3 to 1.5 in comparison to aging in vacuum. Thus, aging at 673 K (400 °C) in a hydrogen atmosphere renders fairly good balance of strength and conductivity, although it takes nearly a month to achieve. The microstructural changes during aging were examined by transmission electron microscopy (TEM) and atom-probe tomography (APT), it was confirmed that precipitation of the Cu4Ti phase occurs first and then particles of TiH2 form as the third phase, thereby efficiently removing the Ti solutes in the matrix.

  18. Accurate measurements and temperature dependence of the water vapor self-continuum absorption in the 2.1 μm atmospheric window

    Energy Technology Data Exchange (ETDEWEB)

    Ventrillard, I.; Romanini, D.; Mondelain, D.; Campargue, A., E-mail: Alain.Campargue@ujf-grenoble.fr [LIPhy, Université Grenoble Alpes, F-38000 Grenoble (France); LIPhy, CNRS, F-38000 Grenoble (France)

    2015-10-07

    In spite of its importance for the evaluation of the Earth radiative budget, thus for climate change, very few measurements of the water vapor continuum are available in the near infrared atmospheric windows especially at temperature conditions relevant for our atmosphere. In addition, as a result of the difficulty to measure weak broadband absorption signals, the few available measurements show large disagreements. We report here accurate measurements of the water vapor self-continuum absorption in the 2.1 μm window by Optical Feedback Cavity Enhanced Absorption Spectroscopy (OF-CEAS) for two spectral points located at the low energy edge and at the center of the 2.1 μm transparency window, at 4302 and 4723 cm{sup −1}, respectively. Self-continuum cross sections, C{sub S}, were retrieved with a few % relative uncertainty, from the quadratic dependence of the spectrum base line level measured as a function of water vapor pressure, between 0 and 16 Torr. At 296 K, the C{sub S} value at 4302 cm{sup −1} is found 40% higher than predicted by the MT-CKD V2.5 model, while at 4723 cm{sup −1}, our value is 5 times larger than the MT-CKD value. On the other hand, these OF-CEAS C{sub S} values are significantly smaller than recent measurements by Fourier transform spectroscopy at room temperature. The temperature dependence of the self-continuum cross sections was also investigated for temperatures between 296 K and 323 K (23-50 °C). The derived temperature variation is found to be similar to that derived from previous Fourier transform spectrometer (FTS) measurements performed at higher temperatures, between 350 K and 472 K. The whole set of measurements spanning the 296-472 K temperature range follows a simple exponential law in 1/T with a slope close to the dissociation energy of the water dimer, D{sub 0} ≈ 1100 cm{sup −1}.

  19. Numerical studies of independent control of electron density and gas temperature via nonlinear coupling in dual-frequency atmospheric pressure dielectric barrier discharge plasmas

    Science.gov (United States)

    Zhang, Z. L.; Nie, Q. Y.; Wang, Z. B.; Gao, X. T.; Kong, F. R.; Sun, Y. F.; Jiang, B. H.

    2016-07-01

    Dielectric barrier discharges (DBDs) provide a promising technology of generating non-equilibrium cold plasmas in atmospheric pressure gases. For both application-focused and fundamental studies, it is important to explore the strategy and the mechanism for enabling effective independent tuning of key plasma parameters in a DBD system. In this paper, we report numerical studies of effects of dual-frequency excitation on atmospheric DBDs, and modulation as well as separate tuning mechanism, with emphasis on dual-frequency coupling to the key plasma parameters and discharge evolution. With an appropriately applied low frequency to the original high frequency, the numerical calculation demonstrates that a strong nonlinear coupling between two frequencies governs the process of ionization and energy deposition into plasma, and thus raises the electron density significantly (e.g., three times in this case) in comparisons with a single frequency driven DBD system. Nevertheless, the gas temperature, which is mainly determined by the high frequency discharge, barely changes. This method then enables a possible approach of controlling both averaged electron density and gas temperature independently.

  20. Electrocatalytic Synthesis of Ammonia at Room Temperature and Atmospheric Pressure from Water and Nitrogen on a Carbon-Nanotube-Based Electrocatalyst.

    Science.gov (United States)

    Chen, Shiming; Perathoner, Siglinda; Ampelli, Claudio; Mebrahtu, Chalachew; Su, Dangsheng; Centi, Gabriele

    2017-03-01

    Ammonia is synthesized directly from water and N2 at room temperature and atmospheric pressure in a flow electrochemical cell operating in gas phase (half-cell for the NH3 synthesis). Iron supported on carbon nanotubes (CNTs) was used as the electrocatalyst in this half-cell. A rate of ammonia formation of 2.2×10(-3)  gNH3  m(-2)  h(-1) was obtained at room temperature and atmospheric pressure in a flow of N2 , with stable behavior for at least 60 h of reaction, under an applied potential of -2.0 V. This value is higher than the rate of ammonia formation obtained using noble metals (Ru/C) under comparable reaction conditions. Furthermore, hydrogen gas with a total Faraday efficiency as high as 95.1 % was obtained. Data also indicate that the active sites in NH3 electrocatalytic synthesis may be associated to specific carbon sites formed at the interface between iron particles and CNT and able to activate N2 , making it more reactive towards hydrogenation.

  1. Influences of guide-tube and bluff-body on advanced atmospheric pressure plasma source for single-crystalline polymer nanoparticle synthesis at low temperature

    Science.gov (United States)

    Kim, Dong Ha; Park, Choon-Sang; Kim, Won Hyun; Shin, Bhum Jae; Hong, Jung Goo; Park, Tae Seon; Seo, Jeong Hyun; Tae, Heung-Sik

    2017-02-01

    The use of a guide-tube and bluff-body with an advanced atmospheric pressure plasma source is investigated for the low-temperature synthesis of single-crystalline high-density plasma polymerized pyrrole (pPPy) nano-materials on glass and flexible substrates. Three process parameters, including the position of the bluff-body, Ar gas flow rate, and remoteness of the substrate from the intense and broadened plasma, are varied and examined in detail. Plus, for an in-depth understanding of the flow structure development with the guide-tube and bluff-body, various numerical simulations are also conducted using the same geometric conditions as the experiments. As a result, depending on both the position of the bluff-body and the Ar gas flow rate, an intense and broadened plasma as a glow-like discharge was produced in a large area. The production of the glow-like discharge played a significant role in increasing the plasma energy required for full cracking of the monomers in the nucleation region. Furthermore, a remote growth condition was another critical process parameter for minimizing the etching and thermal damage during the plasma polymerization, resulting in single- and poly-crystalline pPPy nanoparticles at a low temperature with the proposed atmospheric pressure plasma jet device.

  2. Influence of temperature and atmosphere on polychlorinated dibenzo-p-dioxins and dibenzofurans desorption from waste incineration fly ash.

    Science.gov (United States)

    Yang, Jie; Yan, Mi; Li, Xiaodong; Chen, Tong; Lu, Shengyong; Yan, Jianhua; Buekens, Alfons

    2015-01-01

    A fly ash sample was heated for 1 h to 200°C, 300°C and 400°C, in order to study the influence of temperature and gas phase composition on the removal of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) from fly ash derived from municipal solid waste incineration. The tests were conducted by treating a fixed bed of fly ash both in an inert (nitrogen) and in a reducing (nitrogen+hydrogen) gas flow in a horizontal bench-scale quartz tubular reactor, heated by a surrounding tubular furnace. The results indicate that most of the PCDD/Fs in fly ash were removed by thermal treatment, especially when the temperature was higher than 300°C: the PCDD/Fs' removal efficiency attained up to 96%. PCDD/Fs dechlorination and destruction were much more important than PCDD/Fs desorption, under either inert or reducing atmosphere. At 200°C and 300°C, the experiments with reducing atmosphere yielded slightly better results than those in nitrogen; yet, this tendency was reversed at 400°C. In general, both treatment modes can fully meet the requirements regarding the concentration of dioxins in fly ash to be sent for landfill in China.

  3. New low-temperature preparations of some simple and mixed co and ni dispersed sulfides and their chemical behavior in reducing atmosphere.

    Science.gov (United States)

    Bezverkhyy, I; Danot, M; Afanasiev, P

    2003-03-10

    A series of simple (CoS(2), Co(9)S(8), NiS(2), NiS, Ni(3)S(2)) and mixed sulfides (NiCo(2)S(4), Ni(0.33)Co(0.67)S(2), Ni(3)Co(6)S(8), CuCo(2)S(4), Cu(0.33)Co(0.67)S(2)) was prepared using low-temperature procedures. To obtain the mixed sulfides, the mixtures of the solutions of the corresponding salts were precipitated by Na(2)S and then heated in a sulfiding atmosphere at 300 degrees C. It has been found that the product phase composition depends on the sulfiding atmosphere. Using a H(2)S/Ar mixture leads to pyrite type sulfides, whereas treatment in H(2)S/H(2) flow allowed the preparation of Ni-Co and Cu-Co thiospinels. The as prepared highly dispersed single-phase materials were characterized by X-ray powder diffraction, scanning electron microscopy, temperature-programmed reduction (TPR), elemental analysis, and BET surface area measurements.

  4. Influence of small-scale North Atlantic sea surface temperature patterns on the marine boundary layer and free troposphere: a study using the atmospheric ARPEGE model

    Science.gov (United States)

    Piazza, Marie; Terray, Laurent; Boé, Julien; Maisonnave, Eric; Sanchez-Gomez, Emilia

    2016-03-01

    A high-resolution global atmospheric model is used to investigate the influence of the representation of small-scale North Atlantic sea surface temperature (SST) patterns on the atmosphere during boreal winter. Two ensembles of forced simulations are performed and compared. In the first ensemble (HRES), the full spatial resolution of the SST is maintained while small-scale features are smoothed out in the Gulf Stream region for the second ensemble (SMTH). The model shows a reasonable climatology in term of large-scale circulation and air-sea interaction coefficient when compared to reanalyses and satellite observations, respectively. The impact of small-scale SST patterns as depicted by differences between HRES and SMTH shows a strong meso-scale local mean response in terms of surface heat fluxes, convective precipitation, and to a lesser extent cloudiness. The main mechanism behind these statistical differences is that of a simple hydrostatic pressure adjustment related to increased SST and marine atmospheric boundary layer temperature gradient along the North Atlantic SST front. The model response to small-scale SST patterns also includes remote large-scale effects: upper tropospheric winds show a decrease downstream of the eddy-driven jet maxima over the central North Atlantic, while the subtropical jet exhibits a significant northward shift in particular over the eastern Mediterranean region. Significant changes are simulated in regard to the North Atlantic storm track, such as a southward shift of the storm density off the coast of North America towards the maximum SST gradient. A storm density decrease is also depicted over Greenland and the Nordic seas while a significant increase is seen over the northern part of the Mediterranean basin. Changes in Rossby wave breaking frequencies and weather regimes spatial patterns are shown to be associated to the jets and storm track changes.

  5. Electron Density and Temperature Measurement by Stark Broadening in a Cold Argon Arc-Plasma Jet at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    ZHOU Qiuping; CHENG Cheng; MENG Yuedong

    2009-01-01

    Determination of both the electron density and temperature simultaneously in a cold argon arc-plasma jet by analyzing the Stark broadening of two different emission lines is presented.This method is based on the fact that the Stark broadening of different lines has a different dependence on the electron density and temperature.Therefore,a comparison of two or more line broadenings allows us to diagnose the electron density and temperature simultaneously.In this study we used the first two Balmer series hydrogen lines H_α and H_β for their large broadening width.For this purpose,a small amount of hydrogen was introduced into the discharge gas.The results of the Gigosos-Cardenoso computational model,considering more relevant processes for the hydrogen Balmer lines,is used to process the experimental data.With this method,we obtained reliable electron density and temperature,1.88 ×10 ~(15) cm~(-3 )and 13000 K,respectively.Possible sources of error were also analyzed.

  6. Temperature and seeding effects on the precipitation of scorodite from sulfate solutions under atmospheric-pressure conditions

    Science.gov (United States)

    Singhania, Shalabh; Wang, Qiankun; Filippou, Dimitrios; Demopoulos, George P.

    2005-06-01

    Arsenic is a major contaminant in the nonferrous extractive metallurgy. In the past 20 years, many studies have shown that it can be precipitated as relatively stable crystalline scorodite (FeAsO4·2H2O) by precipitation under ambient or elevated pressures. In the present study, an extensive program of scorodite precipitation tests under ambient pressure has shown that the rate of scorodite formation increases dramatically by a small increase in temperature from 85 °C to 100 °C. The beneficial effects of temperature are attributed to the higher thermodynamic stability of scorodite at elevated temperatures, but also to higher rates of secondary nuclei formation and crystal growth. In any case, irrespective of the precipitation temperature, the leachability of all scorodite precipitates observed in toxicity characterization leaching procedure (TCLP) tests is below 5 mg/L As. Another parameter examined in this study was seeding. It was observed that the higher the initial concentration of seed, the faster the precipitation. Precipitation of well-crystallized scorodite can be effected equally well on heterogeneous seed such as hematite (Fe2O3) or gypsum (CaSO4·2H2O) added externally or formed in situ.

  7. Use of SSU/MSU Satellite Observations to Validate Upper Atmospheric Temperature Trends in CMIP5 Simulations

    Directory of Open Access Journals (Sweden)

    Lilong Zhao

    2015-12-01

    Full Text Available The tropospheric and stratospheric temperature trends and uncertainties in the fifth Coupled Model Intercomparison Project (CMIP5 model simulations in the period of 1979–2005 have been compared with satellite observations. The satellite data include those from the Stratospheric Sounding Units (SSU, Microwave Sounding Units (MSU, and the Advanced Microwave Sounding Unit-A (AMSU. The results show that the CMIP5 model simulations reproduced the common stratospheric cooling (−0.46–−0.95 K/decade and tropospheric warming (0.05–0.19 K/decade features although a significant discrepancy was found among the individual models being selected. The changes of global mean temperature in CMIP5 simulations are highly consistent with the SSU measurements in the stratosphere, and the temporal correlation coefficients between observation and model simulations vary from 0.6–0.99 at the 99% confidence level. At the same time, the spread of temperature mean in CMIP5 simulations increased from stratosphere to troposphere. Multiple linear regression analysis indicates that the temperature variability in the stratosphere is dominated by radioactive gases, volcanic events and solar forcing. Generally, the high-top models show better agreement with observations than the low-top model, especially in the lower stratosphere. The CMIP5 simulations underestimated the stratospheric cooling in the tropics and overestimated the cooling over the Antarctic compared to the satellite observations. The largest spread of temperature trends in CMIP5 simulations is seen in both the Arctic and Antarctic areas, especially in the stratospheric Antarctic.

  8. Stratospheric Horizontal Wavenumber Spectra of Winds, Potential Temperature, and Atmospheric Tracers Observed by High-Altitude Aircraft

    Science.gov (United States)

    Bacmeister, Julio T.; Eckermann, Stephen D.; Newman, Paul A.; Lait, Leslie; Chan, K. R.; Loewenstein, Max; Proffitt, Michael H.; Gary, Bruce L.

    1996-01-01

    Horizontal wavenumber power spectra of vertical and horizontal wind velocities, potential temperatures, and ozone and N(2)O mixing ratios, as measured in the mid-stratosphere during 73 ER-2 flights (altitude approx. 20km) are presented. The velocity and potential temperature spectra in the 100 to 1-km wavelength range deviate significantly from the uniform -5/3 power law expected for the inverse energy-cascade regime of two-dimensional turbulence and also for inertial-range, three-dimensional turbulence. Instead, steeper spectra approximately consistent with a -3 power law are observed at horizontal scales smaller than 3 km for all velocity components as well as potential temperature. Shallower spectra are observed at scales longer than 6 km. For horizontal velocity and potential temperature the spectral indices at longer scales are between -1.5 and -2.0. For vertical velocity the spectrum at longer scales become flat. It is argued that the observed velocity and potential temperature spectra are consistent with gravity waves. At smaller scales, the shapes are also superficially consistent with a Lumley-Shur-Weinstock buoyant subrange of turbulence and/or nonlinear gravity waves. Contemporaneous spectra of ozone and N(sub 2)O mixing ratio in the 100 to 1-km wavelength range do conform to an approximately uniform -5/3 power law. It is argued that this may reflect interactions between gravity wave air-parcel displacements and laminar or filamentary structures in the trace gas mixing ratio field produced by enstropy-cascading two-dimensional turbulence.

  9. Experimental study of the density and viscosity of polyethylene glycols and their mixtures at temperatures from 293 K to 473 K and at atmospheric pressure

    Energy Technology Data Exchange (ETDEWEB)

    Sagdeev, D.I.; Fomina, M.G.; Mukhamedzyanov, G.Kh. [Kazan State Technological University, Kazan (Russian Federation); Abdulagatov, I.M., E-mail: ilmutdin@boulder.nist.gov [Geothermal Research Institute of the Dagestan Scientific Center of the Russian Academy of Sciences, Makhachkala, Dagestan (Russian Federation)

    2011-12-15

    Highlights: > Viscosity and density of polyethylene glycols. > Combined experimental apparatus for density and viscosity measurements. > Vogel-Tamman-Fulcher model for viscosity. - Abstract: A new apparatus to measure simultaneously the density and viscosity of liquids has been designed and constructed based on the hydrostatic weighing and falling-body principles. The density and viscosity of monoethylene glycol (MEG), diethylene glycol (DEG), and triethylene glycol (TEG) and their binary, (50%MEG + 50%DEG), (50%MEG + 50%TEG), (50%DEG + 50%TEG), and ternary (33.33%MEG + 33.33%DEG + 33.34%TEG) mixtures have been measured over the temperature range from 293 K to 473 K and at atmospheric pressure. The expanded uncertainty of the density, pressure, temperature, and viscosity measurements at the 95% confidence level with a coverage factor of k = 2 is estimated to be 0.15% to 0.30%, 0.05%, 0.06 K, and 1.5% to 2.0% (depending on temperature and pressure ranges), respectively. The theoretically based Arrhenius-Andrade and Vogel-Tamman-Fulcher type equations were used to describe the temperature dependence of measured viscosities for pure polyethylene glycols and their mixtures.

  10. High temperature corrosion studies. A. Iron: based superalloy in SO/sub 2//O/sub 2/ atmospheres. B. Gas: solid reaction with formation of volatile species

    Energy Technology Data Exchange (ETDEWEB)

    Liu, T.K.

    1980-03-01

    The thermogravimetric method was used to study high temperature corrosion under SO/sub 2//O/sub 2/ atmosphere applied to Armco 18SR alloys with different heat treatment histories, Armco T310 and pure chromium between 750 and 1100/sup 0/C. The weight gain follows the parabolic rate law. The volatilization of the protective Cr/sub 2/O/sub 3/ layer via formation of CrO/sub 3/ was taken into account above 900/sup 0/C for long time runs. The parabolic rate and the volatilization rate, derived from fitting the experimental data to the modified Tedmon's non-linear model, were correlated using the Arrhenius equation. Armco 18SR-C has the best corrosion resistance of the Armco 18SR alloys. Armco T310 is not protective at high temperatures. The available rate data on the oxidation of chromium oxide, chlorination of chromium, oxidation-chlorination of chromium oxide, chlorination of nickel and chlorination of iron were found to be predictable. The calculation of high temperature volatilization rate was performed using the available fluid correlation equations and the Lennard-Jones parameters derived from the molecule with similar structure and from the low temperature viscosity measurement. The lower predicted volatilization rate is due to the use of the Chapman-Enskog equation with the Lennard-Jones parameters mostly derived from the low temperature viscosity measurement. This was substantiated by comparing the reliable high temperature diffusion rate in the literature with the above mentioned calculational method. The experimental volatilization rates of this study are compared with the other related studies and the mass transfer predictions.

  11. Effects of cathodic current density and temperature on morphology and microstructure of iridium coating prepared by electrodeposition in molten salt under the air atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Zhu Li' an, E-mail: mr_zla@163.com [Department of Materials Engineering and Applied Chemistry, College of Aerospace and Materials Engineering, National University of Defence Technology, Changsha 410073 (China); Bai Shuxin; Zhang Hong; Ye Yicong [Department of Materials Engineering and Applied Chemistry, College of Aerospace and Materials Engineering, National University of Defence Technology, Changsha 410073 (China)

    2013-01-15

    Highlights: Black-Right-Pointing-Pointer The 'salt passivation' occurs on the anode surface at low temperatures. Black-Right-Pointing-Pointer The index of preferred growth crystal plane increases as increasing current density. Black-Right-Pointing-Pointer The <1 1 1> oriented coating is smoother and denser than <2 2 0>/<3 1 1> oriented coating. Black-Right-Pointing-Pointer The coating compactness improves as increasing current density/decreasing temperature. - Abstract: Iridium coating was prepared on a Re/C substrate (graphite substrate coated with rhenium coating by CVD) using electrodeposition in molten salt of chlorides in the air atmosphere. The effects of cathodic current density and temperature on both the morphology and microstructure of the coating were studied, respectively. The morphology and orientation of the coating were determined by scanning electron microscope and X-ray diffraction, respectively. The results showed that the cathodic current density and temperature both affected the surface morphology, roughness, grain size and compactness of the iridium coating. With increasing of current density from 5 to 50 mA/cm{sup 2}, the surface roughness of the coating increased from Ra 0.98 to Ra 6.29 {mu}m, while the grain size decreased. With temperature increasing from 520 to 640 Degree-Sign C, the surface roughness of the coating decreased from Ra 4.41 to Ra 1.16 {mu}m, while the grain size increased. The preferred orientations of the coatings changed in the row <111>-<220>-<311> with current density increasing. With the increase of temperature, the preferred orientation of the coating changed from <1 1 1> to <2 2 0>, and again to <1 1 1>. The coating with <1 1 1> orientation was smoother and denser than that with <2 2 0> orientation regardless of the grain size.

  12. Water-soluble organic carbon (WSOC) and its temperature-resolved carbon fractions in atmospheric aerosols in Beijing

    Science.gov (United States)

    Tang, Xiong; Zhang, Xiaoshan; Wang, Zhangwei; Ci, Zhijia

    2016-11-01

    Investigation of temperature-resolved carbon fractions of water-soluble organic carbon (WSOC) can improve our understanding of the chemical properties, formation processes and sources of WSOC in aerosols. We developed a method that can examine different temperature-resolved carbon fractions of WSOC and used this method to characterize aerosol samples (n = 102) collected from an urban site in Beijing in 2010-2011. The aerosol composition data including inorganic ions, elements and temperature-resolved carbon fractions of WSOC were used as input of positive matrix factorization (PMF) model to investigate the sources of WSOC. The results showed that the mean concentrations of WSOC were 10.2 μg m- 3 with increased values in winter and decreased values in summer, while WSOC/OC ratios (mean: 51.7%) were higher in spring and summer than in fall and winter. The sampling artifacts of WSOC (18.2%) were higher than those of OC (13.4%). Though WSOC was significantly influenced by biomass burning in spring and winter, the strong correlations between WSOC and other secondary components suggested that WSOC was secondary in nature. Results of temperature-resolved carbon fractions of OC and WSOC showed that WSOC/OC ratios for different carbon fractions had the highest value of 0.92 and lowest value of 0.30. PMF analysis identified four factors, three of which were associated with three organic polar compounds groups (low, medium, and high molecular weight compounds) based on their thermal evolution features, and one of which was attributed to inorganic secondary formation processes. Annually, the contributions of four factors were 20.5%, 46.2%, 12.4% and 20.9%, respectively.

  13. Turbulent Transfer Coefficients and Calculation of Air Temperature inside Tall Grass Canopies in Land Atmosphere Schemes for Environmental Modeling.

    Science.gov (United States)

    Mihailovic, D. T.; Alapaty, K.; Lalic, B.; Arsenic, I.; Rajkovic, B.; Malinovic, S.

    2004-10-01

    A method for estimating profiles of turbulent transfer coefficients inside a vegetation canopy and their use in calculating the air temperature inside tall grass canopies in land surface schemes for environmental modeling is presented. The proposed method, based on K theory, is assessed using data measured in a maize canopy. The air temperature inside the canopy is determined diagnostically by a method based on detailed consideration of 1) calculations of turbulent fluxes, 2) the shape of the wind and turbulent transfer coefficient profiles, and 3) calculation of the aerodynamic resistances inside tall grass canopies. An expression for calculating the turbulent transfer coefficient inside sparse tall grass canopies is also suggested, including modification of the corresponding equation for the wind profile inside the canopy. The proposed calculations of K-theory parameters are tested using the Land Air Parameterization Scheme (LAPS). Model outputs of air temperature inside the canopy for 8 17 July 2002 are compared with micrometeorological measurements inside a sunflower field at the Rimski Sancevi experimental site (Serbia). To demonstrate how changes in the specification of canopy density affect the simulation of air temperature inside tall grass canopies and, thus, alter the growth of PBL height, numerical experiments are performed with LAPS coupled with a one-dimensional PBL model over a sunflower field. To examine how the turbulent transfer coefficient inside tall grass canopies over a large domain represents the influence of the underlying surface on the air layer above, sensitivity tests are performed using a coupled system consisting of the NCEP Nonhydrostatic Mesoscale Model and LAPS.

  14. On the multiscale nature of soil moisture-temperature couplings: the role of seasonality, causation and non-linear feedbacks in land-atmosphere interactions (Invited)

    Science.gov (United States)

    Molini, A.; Casagrande, E.; Mueller, B.

    2013-12-01

    Land-Atmosphere (L-A) interactions, their strength and directionality, are one of the main sources of uncertainty in current climate modeling, with strong implications on the accurate assessment of future climate variability and climate change impacts. Beside from the scarcity of direct observations, major uncertainties derive from the inherent complexity and nonlinearity of these interactions, and from their multi-scale character. Statistical analysis of L-A couplings is traditionally based on linear correlation methods and metrics. However, these approaches are not designed to detect causal connections or non-linear couplings and they poorly perform in presence of non-stationarities. Additionally these methods assess L-A couplings essentially in the time domain, despite the fact that L-A dynamical drivers can act simultaneously over a wide range of different space and time scales. This talk explores the multi-scale nature of L-A interactions, through the example of soil moisture-temperature couplings and soil-moisture memory effects. In several regions of the world, soil moisture can have a dampening effect on temperature due to evaporative cooling. By using spectral decomposition techniques and both newly developed satellite based products and re-analysis, we analyze the contribution of different time scales to the build-up of global soil moisture-temperature coupling hot spots, addressing at the same time the role of seasonality, causation and non-linear feedbacks in land-atmosphere interactions. Finally we focus on the role of fine (sub-monthly) time scales and their interplay with the seasonal scales.

  15. Atmospheric reaction of Cl + methacrolein: a theoretical study on the mechanism, and pressure- and temperature-dependent rate constants.

    Science.gov (United States)

    Sun, Cuihong; Xu, Baoen; Zhang, Shaowen

    2014-05-22

    Methacrolein is a major degradation product of isoprene, the reaction of methacrolein with Cl atoms may play some roles in the degradation of isoprene where these species are relatively abundant. However, the energetics and kinetics of this reaction, which govern the reaction branching, are still not well understood so far. In the present study, two-dimensional potential energy surfaces were constructed to analyze the minimum energy path of the barrierless addition process between Cl and the C═C double bond of methacrolein, which reveals that the terminal addition intermediate is directly formed from the addition reaction. The terminal addition intermediate can further yield different products among which the reaction paths abstracting the aldehyde hydrogen atom and the methyl hydrogen atom are dominant reaction exits. The minimum reaction path for the direct aldehydic hydrogen atom abstraction is also obtained. The reaction kinetics was calculated by the variational transition state theory in conjunction with the master equation method. From the theoretical model we predicted that the overall rate constant of the Cl + methacrolein reaction at 297 K and atmospheric pressure is koverall = 2.3× 10(-10) cm(3) molecule(-1) s(-1), and the branching ratio of the aldehydic hydrogen abstraction is about 12%. The reaction is pressure dependent at P pressure limit at about 100 Torr. The calculated results could well account for the experimental observations.

  16. 大气压空气等离子体羽的振动温度研究%Vibrational Temperature of Plasma Plume in Atmospheric Pressure Air

    Institute of Scientific and Technical Information of China (English)

    李雪辰; 常媛媛; 贾鹏英; 赵欢欢; 鲍文婷

    2013-01-01

    A tri-electrode discharge device was designed in a dielectric barrier discharge configurations to generate a fairly large volume plasma plume in atmospheric pressure air.The discharge characteristics of the plasma plume were investigated by an optical method.The discharge emission from the plasma plume was collected by a photomultiplier tube.It was found that the number of discharge pulse per cycle of the applied voltage increased with increasing the peak value of the applied voltage.The emission spectra of the plasma plume were collected by a spectrometer.The vibrational temperature was calculated by fitting the experimental data to the theoretical one.Results showed that the vibrational temperature of the plasma plume decreases with increasing the Up.Spatially resolved measurement of the vibrational temperature was also conducted on the plasma plume with the same method.Results showed that the vibrational temperature increases firstly and then decreases with increasing distance from the nozzle.The vibrational temperature reachs its maximum when the distance is 5.4 mm from the nozzle.These experimental phenomena were analyzed qualitatively based on the discharge theory.These results have important significance for the industrial applications of the plasma plume in atmospheric pressure air.%利用三电极介质阻挡放电装置,在大气压空气中产生了较大体积的等离子体羽.采用光学方法对该等离子体羽的特性进行了研究.发现随着外加电压峰值增加,每个外加电压周期的放电脉冲个数增加.通过采集等离子体羽的发射光谱,空间分辨地研究了放电等离子体羽的振动温度.结果表明等离子体羽的振动温度随着外加电压峰值的增加而减小;随着远离喷嘴的距离的增加,等离子体振动温度先增加后减小,当距离喷嘴5.4mm时振动温度达到最高值.对上述现象进行了定性分析.研究结果对大气压空气等离子体羽在杀菌消毒等领域的应用具有重要意义.

  17. High temperature erosion wear of flame and plasma-sprayed nickel-chromium coatings under simulated coal-fired boiler atmospheres

    Energy Technology Data Exchange (ETDEWEB)

    Hidalgo, V.H.; Varela, J.B.; Menendez, A.C.; Martinez, S.P. [Universidad de Oviedo, Gijon (Spain). Departamento Energia

    2001-02-01

    Erosive high temperature wear of heat exchanger tubes and other structural materials in coal-fired boilers are recognised as being the main cause of downtime at power generation plants. This study concerns the behaviour of plasma and flame sprayed modified nickel-chromium alloy (with small aluminium and titanium additions) subjected to the action of simulated post-combustion gases from a coal-fired boiler combustor. The study first evaluates the effects of thermal exposure at high temperature on the adherence between the substrate (austenitic stainless steel) and coatings. Then, the oxidation rates of these coatings in atmospheres with 3-3.5% of free oxygen at 500 and 800{degree}C (773 and 1073 K) were evaluated. The low velocity corrosion-erosion behaviour produced by the impact of fly ashes in the gas stream at high temperatures (773 and 1073 K) was also evaluated under impact angles of 30 and 90{degree}C. Finally, the eroded surfaces were analysed using scanning electron microscopy to characterise the ash embedment phenomena and the operating erosive micromechanisms. 24 refs., 13 figs., 9 tabs.

  18. Temperature and modified atmosphere affect the quality of okra Temperatura e atmosfera modificada influenciam a qualidade do quiabo

    Directory of Open Access Journals (Sweden)

    Fernando Luiz Finger

    2008-01-01

    Full Text Available Little information is available on the influence of temperature on plastic films wrapped okra (Albelmoschus esculentus for their postharvested conservation. This works investigated the influence of the temperature and PVC film on the development of chilling injury and storability from one of the most popular Brazilian cultivar of okra cv. Amarelinho in fruits stored at 5, 10ºC and at 25ºC. Fruits were harvest at commercial maturity stage with length ranging from 8 to 12 cm, and immediately wrapped in PVC over a polystyrene tray and than stored until visible deterioration or wilting symptoms. Lowering the temperature of storage room from 25 to 10 or 5ºC decreased the weight loss in both PVC wrapped and control fruits, with a lower rate at 5ºC. By reducing the temperature to 5 or 10ºC and wrapping the fruits in PVC film, the relative water content of the fruit pericarp was maintained throughout the storage, while at 25ºC the high weight loss was associated with significant reduction of the water content. The development of chilling symptoms was delayed by the presence of PVC film in fruits stored at 5ºC. However, at 10ºC symptoms of pitting were not developed in PVC wrapped or control fruits up to tenth day of storage. The rate of chlorophyll degradation was diminished by reducing the temperature and by wrapping the fruits with PVC film. The appearance of severe chilling symptoms at 5ºC was associated to less chlorophyll in the fruit pericarp on the control as compared to their content in the PVC wrapped fruits.Para o armazenamento do quiabo (Albelmoschus esculentus há poucas informações disponíveis sobre a influência da temperatura e filmes plásticos na conservação pós-colheita desta hortaliça. Para investigar a influência da temperatura e do filme de PVC na qualidade e desenvolvimento de sintomas de injúria por frio de uma das mais populares cultivares brasileira de quiabo cv. Amarelinho, os frutos foram armazenados a 5, 10

  19. Scaling properties of velocity and temperature spectra above the surface friction layer in a convective atmospheric boundary layer

    Directory of Open Access Journals (Sweden)

    K. G. McNaughton

    2007-06-01

    Full Text Available We report velocity and temperature spectra measured at nine levels from 1.42 meters up to 25.7 m over a smooth playa in Western Utah. Data are from highly convective conditions when the magnitude of the Obukhov length (our proxy for the depth of the surface friction layer was less than 2 m. Our results are somewhat similar to the results reported from the Minnesota experiment of Kaimal et al. (1976, but show significant differences in detail. Our velocity spectra show no evidence of buoyant production of kinetic energy at at the scale of the thermal structures. We interpret our velocity spectra to be the result of outer eddies interacting with the ground, not "local free convection".

    We observe that velocity spectra represent the spectral distribution of the kinetic energy of the turbulence, so we use energy scales based on total turbulence energy in the convective boundary layer (CBL to collapse our spectra. For the horizontal velocity spectra this scale is (zi εo2/3, where zi is inversion height and εo is the dissipation rate in the bulk CBL. This scale functionally replaces the Deardorff convective velocity scale. Vertical motions are blocked by the ground, so the outer eddies most effective in creating vertical motions come from the inertial subrange of the outer turbulence. We deduce that the appropriate scale for the peak region of the vertical velocity spectra is (z εo2/3 where z is height above ground. Deviations from perfect spectral collapse under these scalings at large and small wavenumbers are explained in terms of the energy transport and the eddy structures of the flow.

    We find that the peaks of the temperature spectra collapse when wavenumbers are scaled using (z1/2 zi1/2. That is, the lengths of the thermal structures depend on both the lengths of the

  20. Industrial-age changes in atmospheric [CO2] and temperature differentially alter responses of faster- and slower-growing Eucalyptus seedlings to short-term drought.

    Science.gov (United States)

    Lewis, James D; Smith, Renee A; Ghannoum, Oula; Logan, Barry A; Phillips, Nathan G; Tissue, David T

    2013-05-01

    Climate change may alter forest composition by differentially affecting the responses of faster- and slower-growing tree species to drought. However, the combined effects of rising atmospheric CO2 concentration ([CO2]) and temperature on drought responses of trees are poorly understood. Here, we examined interactive effects of temperature (ambient, ambient + °C) and [CO2] (290, 400 and 650mu;l l(-1)) on drought responses of Eucalyptus saligna Sm. (faster-growing) and E. sideroxylon A. Cunn. ex Woolls (slower-growing) seedlings. Drought was imposed via a controlled reduction in soil water over 1-2 weeks, re-watering seedlings when leaves visibly wilted. In ambient temperature, the effect of drought on the light-saturated net photosynthetic rate (Asat) in E. saligna decreased as [CO2] increased from pre-industrial to future concentrations, but rising [CO2] did not affect the response in Eucalyptus sideroxylon. In contrast, elevated temperature exacerbated the effect of drought in reducing Asat in both species. The drought response of Asat reflected changes in stomatal conductance (gs) associated with species and treatment differences in (i) utilization of soil moisture and (ii) leaf area ratio (leaf area per unit plant dry mass). Across [CO2] and temperature treatments, E. saligna wilted at higher soil water potentials compared with E. sideroxylon. Photosynthetic recovery from drought was 90% complete 2 days following re-watering across all species and treatments. Our results suggest that E. saligna (faster-growing) seedlings are more susceptible to drought than E. sideroxylon (slower-growing) seedlings. The greater susceptibility to drought of E. saligna reflected faster drawdown of soil moisture, associated with more leaf area and leaf area ratio, and the ability of E. sideroxylon to maintain higher gs at a given soil moisture. Inclusion of a pre-industrial [CO2] treatment allowed us to conclude that susceptibility of these species to short-term drought

  1. Degradation of cationic red GTL by catalytic wet air oxidation over Mo-Zn-Al-O catalyst under room temperature and atmospheric pressure.

    Science.gov (United States)

    Xu, Yin; Li, Xiaoyi; Cheng, Xiang; Sun, Dezhi; Wang, Xueye

    2012-03-06

    To overcome the drawback of catalytic wet air oxidation (CWAO) with high temperature and high pressure, the catalytic activity of Mo-Zn-Al-O catalyst for degradation of cationic red GTL under room temperature and atmospheric pressure was investigated. Mo-Zn-Al-O catalyst was prepared by coprecipitation and impregnation. XRD, TG-DTG, and XPS were used to characterize the resulting sample. Central composition design using response surface methodology was employed to optimize correlation of factors on the decolorization of cationic red GTL. The results show that the optimal conditions of pH value, initial concentration of dye and catalyst dosage were found to be 4.0, 85 mg/L and 2.72 g/L, respectively, for maximum decolorization of 80.1% and TOC removal of 50.9%. Furthermore, the reaction on the Mo-Zn-Al-O catalyst and degradation mechanism of cationic red GTL was studied by Electron spin resonance (ESR) and GC-MS technique. The possible reaction mechanism was that the Mo-Zn-Al-O catalyst can efficiently react with adsorbed oxygen/H(2)O to produce ·OH and (1)O(2) and finally induce the degradation of cationic red GTL. GC-MS analysis of the degradation products indicates that cationic red GTL was initiated by the cleavage of -N ═ N- and the intermediates were further oxidized by ·OH or (1)O(2).

  2. Possibility to sound the atmospheric ozone by a radiosonde equipped with two temperature sensors, sensitive and non-sensitive to the long wave radiation

    Science.gov (United States)

    Kitaoka, T.; Sumi, T.

    1994-01-01

    The sensitiveness of white coated thermistor sensors and non-sensitiveness of the gold coated over white thermistor sensors (which have been manufactured by a vacuum evaporation process) to long wave radiation were ascertained by some simple experiments in-room and also by analyses of some results of experimental soundings. From results of analyses on the temperature discrepancies caused by long wave radiation, the possibility to sound the atmospheric ozone partial pressure by a radiosonde equipped with two kinds of sensors, sensitive and non-sensitive to the long wave radiation was suggested, and the test results of the newly developed software for the deduction of ozone partial pressure in upper layers was also shown. However, it was found that the following is the necessary condition to realize the purpose. The sounding should be made by a radiosonde equipped with three sensors, instead of two, one being non-sensitive to the long wave radiation perfectly, and the other two also non-sensitive partially to the downward one, with two different angles of exposure upward. It is essential for the realization of the purpose to get two different values of temperature discrepancies simultaneously observed by the three sensors mentioned above and to avoid the troublesome effects of the upward long wave radiation.

  3. Confined-space synthesis of single crystal TiO2 nanowires in atmospheric vessel at low temperature: a generalized approach

    Science.gov (United States)

    Wang, Xiaoyue; Wang, Hai; Zhou, Yu; Liu, Yong; Li, Baojun; Zhou, Xiang; Shen, Hui

    2015-01-01

    Extensive efforts have been devoted to develop innovative synthesis strategies for nanomaterials in order to exploit the true potential of nanotechnology. However, most approaches require high temperature or high pressure to favor crystallization. Here we highlight an unconventional approach for the confined-space synthesis of the single crystal TiO2 nanowires in the atmospheric vessel at low temperature by cleverly manipulating the unique physical properties of straight-chain saturated fatty acids. Our method also applys to icosane due to its straight-chain saturated hydrocarbon structure and similar physical properties to the saturated fatty acids. Interestingly, we also found that the unsaturated fatty acids can facilitate the crystal growth, but their bent chains lead to the formation of TiO2 particle aggregates. In addition, we demonstrate the growth of TiO2 nanowires on arbitrary substrates, which are of great importance for their wider applications. We thus anticipate our presented method to be a possible starting point for non-classical crystallization strategies and be easily adapted for the fabrication of all other inorganic materials.

  4. An 80-year summer temperature history from the Xiao Dongkemadi ice core in the central Tibetan Plateau and its association with atmospheric circulation

    Science.gov (United States)

    Li, Xiangying; Ding, Yongjian; Yu, Zhongbo; Mika, Sillanpää; Liu, Shiyin; Shangguan, Donghui; Lu, Chengyang

    2015-02-01

    The climate significance of oxygen isotopes from the central Tibetan Plateau (cTP) ice cores is a debated issue because of large scale atmospheric circulation. A high-resolution δ18O record was recovered from the Xiao Dongkemadi (XD) ice core, which expanded the spatial coverage of δ18O data in this region. Annual average δ18O correlated significantly with nearby MJJAS air temperatures, suggesting the δ18O can be used as a proxy to reconstruct regional climate change. The reconstructed temperature anomaly is related to the regional and global warming trends, and the greater warming amplitude since 1970s is related to the elevation dependency of the warming signal. The close relationship of the warming to variations in glacier mass balances and discharge reveal that recent warming has led to obvious glacier shrinkage and runoff increase. Correlation analysis suggests that monsoon and westerly moisture substantially influence the cTP ice core records, along with an increase in their level of contribution to the XD core accumulation in recent decades, and confirms a teleconnection of regional climate of the cTP ice cores with climate parameters in the Indian and North Atlantic Oceans.

  5. Three years of increased soil temperature and atmospheric N deposition have no effect on the N status and growth of a mature balsam fir forest

    Directory of Open Access Journals (Sweden)

    L. D'Orangeville

    2013-01-01

    Full Text Available Nitrogen (N is a major growth-limiting factor in boreal forest ecosystems. Increases of temperature and atmospheric N deposition are expected to affect forest growth directly and indirectly, by increasing N availability due to higher rates of N mineralization. In order to understand the potential impacts of these changes, a mature balsam fir stand in Québec, Canada, was subjected to (i experimentally increased soil temperature (4 °C and earlier snowmelt (2–3 weeks as well as (ii increased inorganic N concentration in artificial precipitation (3 × current N concentrations using 15NH415NO3. Soil inorganic N was measured using buried ion exchange membranes (PRS™-probes and standard soil extractions. Dendrometers were used to monitor the variations in diameter growth and needles were analyzed annually for N to assess the nutritional response of trees.

    After three years of treatment, there was no significant increase in soil nitrate (NO3 or ammonium (NH4 availability either in the organic or in the mineral soil as measured with standard soil extractions. Similar results were obtained with ion exchange membranes, except for an average 54% increase in the forest floor available NH4. No effect of treatments were observed on needle N or diameter growth, but an eight-day earlier peak in diameter growth was measured in heated plots in 2010.

    We attributed the limited effects of our treatments to the acute soil competition for available N at the site. As a result, the projected modifications of the forest N cycle and concomitant increased forest growth due to an earlier snowmelt, increased soil temperature and N deposition should be considered with caution in similar cold N-poor ecosystems.

  6. Increased soil temperature and atmospheric N deposition have no effect on the N status and growth of a mature balsam fir forest

    Directory of Open Access Journals (Sweden)

    L. D'Orangeville

    2013-07-01

    Full Text Available Nitrogen (N is a major growth-limiting factor in boreal forest ecosystems. Increases of temperature and atmospheric N deposition are expected to affect forest growth directly and indirectly by increasing N availability due to higher rates of N mineralization. In order to understand the potential impacts of these changes, a mature balsam fir stand in Québec, Canada, was subjected during three consecutive growing seasons (2009–2011 to (i experimentally increased soil temperature (4 °C and earlier snowmelt (2–3 weeks as well as (ii increased inorganic N concentration in artificial precipitation (3 × current N concentrations using 15NH4-15NO3. Soil inorganic N was measured using buried ion-exchange membranes (PRS™ probes and standard soil extractions. Dendrometers were used to monitor the variations in diameter growth and needles were analyzed annually for N to assess the nutritional response of trees. Results from the second (2010 and third (2011 year of treatment are reported. After three years of treatment, there was no significant increase in soil nitrate (NO3 or ammonium (NH4 availability either in the organic or in the mineral soil as measured with standard soil extractions. Similar results were obtained with ion-exchange membranes, except for NH4 in the forest floor, which increased by an average of 54% over the two years. No effect of treatments were observed on needle N or diameter growth, but an 8-day earlier peak in diameter growth was measured in heated plots in 2010. We attributed the limited effects of our treatments to the acute soil competition for available N at the site. As a result, the projected modifications of the forest N cycle and concomitant increased forest growth due to an earlier snowmelt, increased soil temperature and N deposition should be considered with caution in similar cold N-poor ecosystems.

  7. Are microbial N transformation rates in a permanent grassland soil after 17 years of elevated atmospheric CO2 sensitive to soil temperature?

    Science.gov (United States)

    Moser, Gerald; Gorenflo, André; Brenzinger, Kristof; Clough, Tim; Braker, Gesche; Müller, Christoph

    2016-04-01

    Long-term observations (17 years) within the Giessen Free Air Carbon dioxide Enrichment (Giessen FACE) study on permanent grassland showed that the carbon fertilization caused significant changes in the ecosystem nitrogen cycle. These changes are responsible for a doubling of annual N2O emissions under elevated atmospheric CO2 (eCO2) caused by increased emissions during the plant growing season. The goal of this lab study was to understand how soil temperature influences the long-term effects of eCO2 and plant carbon input on microbial N transformations in the Giessen FACE. Therefore, a pulse labelling study with 15N tracing of 15NH4+ and 15NO3- was carried out with incubated soil samples from elevated and ambient CO2 FACE rings in climate chambers at two different temperatures (10°C and 19°C), while water filled pore space of the samples was adjusted to the same level. The various N pools in the soil (NH4+, NO3-, NO2-, soil organic matter), N2O emissions and simultaneous gross N transformation rates were quantified. The quantification of the gross N transformations are based on the turnover of 15NH4+, 15NO3-, 15NO2- and shall illuminate the interaction between carbon fertilization, temperature and changes in nitrogen cycle in this grassland soil. While the soil respiration after labelling was significantly increased at 19°C compared to 10°C, N2O emissions showed no significant differences. There were also no significant differences of N2O emissions between soil samples from control and elevated CO2 rings within each temperature level. As the soil temperature (within the range of 10-19°C) had no significant effects on N transformations responsible for the observed doubling of N2O emissions under eCO2, it seems most likely that other factors like direct carbon input by plants and/or soil moisture differences between ambient and elevated rings in the field are responsible for the observed increase in N2O emissions under eCO2.

  8. Drought increases heat tolerance of leaf respiration in Eucalyptus globulus saplings grown under both ambient and elevated atmospheric [CO2] and temperature

    Science.gov (United States)

    Gauthier, Paul P. G.; Crous, Kristine Y.; Ayub, Gohar; Duan, Honglang; Weerasinghe, Lasantha K.; Ellsworth, David S.; Tjoelker, Mark G.; Evans, John R.; Tissue, David T.; Atkin, Owen K.

    2014-01-01

    Climate change is resulting in increasing atmospheric [CO2], rising growth temperature (T), and greater frequency/severity of drought, with each factor having the potential to alter the respiratory metabolism of leaves. Here, the effects of elevated atmospheric [CO2], sustained warming, and drought on leaf dark respiration (R dark), and the short-term T response of R dark were examined in Eucalyptus globulus. Comparisons were made using seedlings grown under different [CO2], T, and drought treatments. Using high resolution T–response curves of R dark measured over the 15–65 °C range, it was found that elevated [CO2], elevated growth T, and drought had little effect on rates of R dark measured at T drought increased R dark at high leaf T typical of heatwave events (35–45 °C), and increased the measuring T at which maximal rates of R dark occurred (T max) by 8 °C (from 52 °C in well-watered plants to 60 °C in drought-treated plants). Leaf starch and soluble sugars decreased under drought and elevated growth T, respectively, but no effect was found under elevated [CO2]. Elevated [CO2] increased the Q 10 of R dark (i.e. proportional rise in R dark per 10 °C) over the 15–35 °C range, while drought increased Q 10 values between 35 °C and 45 °C. Collectively, the study highlights the dynamic nature of the T dependence of R dark in plants experiencing future climate change scenarios, particularly with respect to drought and elevated [CO2]. PMID:25205579

  9. Spatial and temporal variation of phthalic acid esters (PAEs) in atmospheric PM10 and PM2.5 and the influence of ambient temperature in Tianjin, China

    Science.gov (United States)

    Kong, Shaofei; Ji, Yaqin; Liu, Lingling; Chen, Li; Zhao, Xueyan; Wang, Jiajun; Bai, Zhipeng; Sun, Zengrong

    2013-08-01

    Phthalic acid esters (PAEs) are produced in large amounts throughout the world and are excessively used in various industries, which have posed a serious threat to human health and the environment. An investigation of six major PAEs congeners in atmospheric PM10 and PM2.5 was synchronously conducted at seven sites belonging to different functional zones in spring, summer and winter in Tianjin, China in 2010. Results showed that the average concentrations of DMP, DEP, DBP, BBP, DEHP and DOP in PM10 were 0.88, 0.73, 12.90, 0.15, 98.29 and 0.83 ng m-3, respectively, and in PM2.5, they were 0.54, 0.30, 8.72, 0.08, 75.68 and 0.33 ng m-3, respectively. DEHP and DBP were the predominant species. The industrial site exhibited highest PAEs values as 135.9 ± 202.8 ng m-3. In winter, the detected percentages for DOP were low. The other five PAEs concentrations were higher in winter than those in spring and summer, which may be related to the influence of emission sources, meteorological parameters and the chemical-physical characteristic of themselves. Except for DOP, other PAEs were negatively correlated with ambient temperature and the relationships were the best fitted as exponential forms. Significant positive correlations were found for PAEs in PM2.5 and PM10, indicating common sources. The PM2.5/PM10 ratios (0.53-0.70) for the six PAEs concentrations suggested that they were preferentially concentrated in finer particles. Principal component analysis indicated the emission from cosmetics and personal care products, plasticizers and sewage and industrial wastewater may be important sources for PAEs in atmospheric particulate matter in Tianjin.

  10. Adjoint Sensitivity Analysis of Radiative Transfer Equation: Temperature and Gas Mixing Ratio Weighting Functions for Remote Sensing of Scattering Atmospheres in Thermal IR

    Science.gov (United States)

    Ustinov, E.

    1999-01-01

    Sensitivity analysis based on using of the adjoint equation of radiative transfer is applied to the case of atmospheric remote sensing in the thermal spectral region with non-negligeable atmospheric scattering.

  11. Chemical characterisation of atmospheric aerosols during a 2007 summer field campaign at Brasschaat, Belgium: sources and source processes, time series, diel variations, and temperature dependencies

    Directory of Open Access Journals (Sweden)

    Y. Gómez-González

    2011-08-01

    Full Text Available Measurements of organic marker compounds and inorganic species were performed on PM2.5 aerosols from a Belgian forest site that is severely impacted by urban pollution ("De Inslag", Brasschaat, Belgium during a 2007 summer period within the framework of the "Formation mechanisms, marker compounds, and source apportionment for biogenic atmospheric aerosols (BIOSOL" project. The objectives of this study were to determine sources, source processes, time series, and diel variations of the organic species, and to explore the relationships between their concentrations and those of trace gases (O3, NO2, SO2, and CO2 or meteorological parameters (temperature, relative humidity, wind speed, and rain fall. The measured organic species included (i low-molecular weight (MW dicarboxylic acids (LMW DCAs, (ii methanesulfonate (MSA, and (iii terpenoic acids originating from the oxidation of α-pinene, β-pinene, d-limonene and Δ3-carene, and (iv organosulfates related to secondary organic aerosol (SOA from the oxidation of isoprene and α-pinene. The measurements of MSA, the LMW DCAs and selected inorganic species were done with ion chromatography (IC, while those of the terpenoic acids and organosulfates were performed using liquid chromatography with negative ion electrospray ionisation mass spectrometry [LC/(−ESI-MS]. The organic tracers explained, on average, 5.3 % of the organic carbon (OC, of which 0.7 % was due to MSA, 3.4 % to LMW DCAs, and 1.2 % to organosulfates and terpenoic acids. The highest atmospheric concentrations of most species were observed during the first five days of the campaign, which were characterised by maximum day-time temperatures >22 °C. Most of the terpenoic acids and the organosulfates peaked during day-time, consistent with their photochemical origin, except the MW 295 α-pinene-related nitrooxy organosulfates and the terpenoic acids,

  12. A study of different‑scale relationship between changes of the surface air temperature and the СО2 concentration in the atmosphere

    Directory of Open Access Journals (Sweden)

    N. V. Vakulenko

    2016-01-01

    Full Text Available A concept of the anthropogenic origin of the current global climate warming assumes that growth of concentration of the atmospheric carbon dioxide and other greenhouse gases is of great concern in this process. However, all earlier performed analyses of the Antarctic ice cores, covering the time interval of several glacial cycles for about 1 000 000 years, have demonstrated that the carbon dioxide concentration changes had a certain lag relative to the air temperature changes by several hundred years during every beginning of the glacial terminations as well as at endings of interglacials. In contrast to these findings, a recently published careful analysis of Antarctic ice cores (Parrenin et al., 2013 had shown that both, the carbon dioxide concentration and global temperature, varied almost synchronously during the transition from the last glacial maximum to the Holocene. To resolve this dilemma, a special technique for analysis of the paleoclimatic time series, based on the wavelets, had been developed and applied to the same carbon dioxide concentration and temperature time series which were used in the above paper of Parrenin et al., 2013. Specifically, a stack of the Antarctic δ18O time series (designated as ATS and the deuterium Dome C – EPICA ones (dD were compared to one another in order to: firstly, to quantitatively estimate differences between time scales of these series; and, secondly, to clear up the lead–lag relationships between different scales variations within these time series. It was found that accuracy of the mutual ATS and dD time series dating lay within the range of 80–160 years. Perhaps, the mutual dating of the temperature and carbon dioxide concentration series was even worse due to the assumed displacement of air bubbles within the ice. It made us to limit our analysis by the time scales of approximately from 800 to 6000 years. But it should be taken into account that any air bubble movement

  13. Low temperature rate coefficients for the reactions of 1CH2 with reactive and non-reactive species, and the implications for Titan's atmosphere

    Science.gov (United States)

    Douglas, Kevin; Slater, Eloise; Blitz, Mark; Plane, John; Heard, Dwayne; Seakins, Paul

    2016-04-01

    The Cassini-Huygens mission to Titan revealed unexpectedly large amounts of benzene in the troposphere, and confirmed the absence of a global ethane ocean as predicted by photochemical models of methane conversion over the lifetime of the solar system. An important chemical intermediate in both the production and loss of benzene and ethane is the first electronically excited state of methylene, 1CH2. For example, at room temperature an important reaction of 1CH2 is with acetylene (R1a), leading to the formation of propargyl (C3H3)[1]. The subsequent recombination of propargyl radicals is the major suggested route to benzene in Titan's atmosphere (R2)[2]. In addition to reaction of 1CH2 leading to products, there is also competition between inelastic electronic relaxation to form the ground triplet state 3CH2 (R1b). This ground state 3CH2 has a markedly different reactivity to the singlet, reacting primarily with methyl radicals (CH3) to form ethene (R3). As methyl radical recombination is the primary route to ethane (R4)[3], reactions of 1CH2 will also heavily influence the ethane budget on Titan. 1CH2 + C2H2 → C3H3 + H (R1a) 1CH2 + C2H2 → 3CH2 + C2H2 (R1b) C3H3 + C3H3 → C6H6 (R2) 3CH2 + CH3 → C2H4 + H (R3) CH3 + CH3 (+ M) → C2H6 (R4) Thus this competition between chemical reaction and electronic relaxation in the reactions of 1CH2 with H2, CH4, C2H4, and C2H6 will play an important role in determining the benzene and ethane budgets on Titan. Despite this there are no measurements of any rate constants for 1CH2 at temperatures relevant to Titan's atmosphere (60 - 170 K). Using a pulsed Laval nozzle apparatus coupled with pulsed laser photolysis laser-induced fluorescence, the low temperature reaction kinetics for the removal of 1CH2 with nitrogen, hydrogen, methane, ethane, ethene, acetylene, and oxygen, have been studied. The results revealed an increase in the removal rate of 1CH2 at temperatures below 200 K, with a sharp increase of around a factor of

  14. The roles of atmospheric wind and entrained water temperature (Te) in the second-year cooling of the 2010-12 La Niña event

    Science.gov (United States)

    Gao, Chuan; Zhang, Rong-Hua

    2017-01-01

    An intermediate coupled model (ICM) yields a successful real-time prediction of the sea surface temperature (SST) evolution in the tropical Pacific during the 2010-12 La Niña event, whereas many other coupled models fail. It was previously identified that the thermocline effect on the SST (including vertical advection and mixing), as represented by water temperature entrained into the mixed layer (Te) and its relationship with the thermocline fluctuation, is an important factor that affects the second-year cooling in mid-late 2011. Because atmospheric wind forcing is also important to ENSO processes, its role is investigated in this study within the context of real-time prediction of the 2010-12 La Niña event using the ICM in which wind stress anomalies are calculated using an empirical model as a response to SST anomalies. An easterly wind anomaly is observed to persist over the western-central Pacific during 2010-11, which acts to sustain a horse shoe-like Te pattern connecting large negative subsurface thermal anomalies in the central-eastern regions off and on the equator. Sensitivity experiments are conducted using the ICM to demonstrate how its SST predictions are directly affected by the intensity of wind forcing. The second-year cooling in 2011 is not predicted to occur in the ICM if the easterly wind anomaly intensity is weakly represented below certain levels; instead, a surface warming can emerge in 2011, with weak SST variability. The results of the current study indicate that the intensity of interannual wind forcing is equally important to SST evolution during 2010-11 compared with that of the thermocline effect. To correctly predict the observed La Niña conditions in the fall of 2011, the ICM needs to adequately represent the intensity of both the wind forcing and the thermocline effects.

  15. Temperature- and pH-dependent aqueous-phase kinetics of the reactions of glyoxal and methylglyoxal with atmospheric amines and ammonium sulfate

    Science.gov (United States)

    Sedehi, Nahzaneen; Takano, Hiromi; Blasic, Vanessa A.; Sullivan, Kristin A.; De Haan, David O.

    2013-10-01

    Reactions of glyoxal (Glx) and methylglyoxal (MG) with primary amines and ammonium salts may produce brown carbon and N-containing oligomers in aqueous aerosol. 1H NMR monitoring of reactant losses and product appearance in bulk aqueous reactions were used to derive rate constants and quantify competing reaction pathways as a function of pH and temperature. Glx + ammonium sulfate (AS) and amine reactions generate products containing C-N bonds, with rates depending directly on pH: rate = (70 ± 60) M-1 s-1fAld [Glx]totfAm [Am]tot, where fAld is the fraction of aldehyde with a dehydrated aldehyde functional group, and fAm is the fraction of amine or ammonia that is deprotonated at a given pH. MG + amine reactions generate mostly aldol condensation products and exhibit less pH dependence: rate = 10[(0.36 ± 0.06) × pH - (3.6 ± 0.3)] M-1 s-1fAld [MG]tot [Am]tot. Aldehyde + AS reactions are less temperature-dependent (Ea = 18 ± 8 kJ mol-1) than corresponding amine reactions (Ea = 50 ± 11 kJ mol-1). Using aerosol concentrations of [OH] = 10-12 M, [amine]tot = [AS] = 0.1 M, fGlx = 0.046 and fMG = 0.09, we estimate that OH radical reactions are normally the major aerosol-phase sink for both dicarbonyl compounds. However, reactions with AS and amines together can account for up to 12 and 45% of daytime aerosol-phase glyoxal and methylglyoxal reactivity, respectively, in marine aerosol at pH 5.5. Reactions with AS and amines become less important in acidic or non-marine aerosol, but may still be significant atmospheric sources of brown carbon, imidazoles, and nitrogen-containing oligomers.

  16. Effect of modified atmosphere and temperature abuse on the growth from spores and cereulide production of Bacillus weihenstephanensis in a cooked chilled meat sausage.

    Science.gov (United States)

    Thorsen, Line; Budde, Birgitte Bjørn; Koch, Anette Granly; Klingberg, Trine Danø

    2009-04-15

    The effect of modified atmosphere packaging (MAP) on the germination and growth of toxin producing psychrotolerant Bacillus spp is not well described. A model agar system mimicking a cooked meat product was used in initial experiments. Incubation at refrigeration temperature of 8 degrees C for 5 weeks of 26 Bacillus weihenstephanensis including two emetic toxin (cereulide) producing strains showed that B. weihenstephanensis is sensitive to MAP containing CO2. The sensitivity to 20% CO2 was dependent on strain and oxygen level, being increased when oxygen was excluded from the MAP. Growth from spores was observed at the earliest within 2 weeks when 20% CO2 was combined with 2% O2 and in 3 weeks when combined with "0"% O2 (the remaining atmosphere was made up from N2). Results were validated in a cooked meat sausage model for two non-emetic and one emetic B. weihenstephanensis strain. The packaging film oxygen transfer rates (OTR) were 1.3 and 40 ml/m(2)/24 h and the atmospheres were 2% O2/20% CO2 and "0"% O2/20% CO2. Oxygen availability had a large impact on the growth from spores in the MAP meat sausage, only the most oxygen restricted condition (OTR of 1.3 ml/m(2)/24 h and "0"% O2/20 % CO2 inhibited growth of the three strains during 4 weeks storage at 8 degrees C. Cereulide production was undetectable during storage at 8 degrees C irrespective of choice of the MAP (quantified by liquid chromatography mass spectrometry/mass spectrometry). MAP storage at 8 degrees C for 1 and 3 weeks followed by opening of packages and temperature abuse for 1.5 h daily at 20 degrees C during 1 week resulted in increased cell counts and variable cereulide production in the meat sausage. A pre-history at 8 degrees C for 1 week in MAP with OTR of 1.3 or 40 ml/m(2)/24 h and 2% O2 resulted in cereulide concentrations of 0.816-1.353 microg/g meat sausage, while a pre-history under the most oxygen restricted condition (OTR of 1.3 ml/m(2)/24 h, "0"% O2/20 % CO2 resulted in minimal

  17. 2D modeling and simulation of the flow dynamics, electric field and reactions in a low-temperature, atmospheric-pressure nitrogen plasma sharp-end plate-to-plane configuration and CVD reactor

    Science.gov (United States)

    De Wilde, Juray; Lorant, Christophe; Descamps, Pierre

    2017-04-01

    In atmospheric-pressure plasma reactors, the flow dynamics can be complex, determine the reactor performance and complicate scale-up. Coupling computational fluid dynamics to the calculation of the electric field and plasma chemistry is challenging because of the numerical stiffness introduced by the difference in time scale of the different phenomena involved. Focusing on low-temperature, atmospheric-pressure pure nitrogen plasma, a model and model reduction based solution strategy to deal with the numerical stiffness are presented and evaluated. The influence of the electric field on the flow dynamics and species concentration fields is first qualitatively studied by means of 2D simulations of a sharp-end plate-to-plane configuration. Next, a specific reactor prototype for low-temperature, atmospheric-pressure plasma-enhanced chemical vapor deposition for in-line surface treatments is simulated to illustrate the importance of accounting for the detailed flow dynamics.

  18. Reduction of methanol in brewed wine by the use of atmospheric and room-temperature plasma method and the combination optimization of malt with different adjuncts.

    Science.gov (United States)

    Liang, Ming-Hua; Liang, Ying-Jie; Chai, Jiang-Yan; Zhou, Shi-Shui; Jiang, Jian-Guo

    2014-11-01

    Methanol, often generated in brewed wine, is highly toxic for human health. To decrease the methanol content of the brewed wine, atmospheric and room-temperature plasma (ARTP) was used as a new mutagenesis tool to generate a mutant of Saccharomyces cerevisiae with lower methanol content. Headspace gas chromatography was used to determine the identity and concentration of methanol with butyl acetate as internal standard in brewed wine. With 47.4% higher and 26.3% positive mutation rates were obtained, the ARTP jet exhibited a strong effect on mutation breeding of S. cerevisiae. The mutant S. cerevisiae S12 exhibited the lowest methanol content, which was decreased by 72.54% compared with that of the wild-type strain. Subsequently, the mutant S. cerevisiae S12 was used to ferment different combinations of malt and adjuncts for lower methanol content and higher alcoholic content. It was shown that the culture 6#, which was 60% malt, 20% wheat, and 20% corn, was the best combinations of malt and adjuncts, with the lowest methanol content (104.8 mg/L), and a relatively higher alcoholic content (15.3%, v/v). The optimal malt-adjunct culture 6#, treated with the glucoamylase dose of 0.04 U/mg of grain released the highest reducing sugars (201.6 mg/mL). It was indicated that the variation in reducing sugars among the combinations of malt and different adjuncts could be due to the dose of exogenous enzymes.

  19. From the Cover: Growth of Carnobacterium spp. from permafrost under low pressure, temperature, and anoxic atmosphere has implications for Earth microbes on Mars

    Science.gov (United States)

    Nicholson, Wayne L.; Krivushin, Kirill; Gilichinsky, David; Schuerger, Andrew C.

    2013-01-01

    The ability of terrestrial microorganisms to grow in the near-surface environment of Mars is of importance to the search for life and protection of that planet from forward contamination by human and robotic exploration. Because most water on present-day Mars is frozen in the regolith, permafrosts are considered to be terrestrial analogs of the martian subsurface environment. Six bacterial isolates were obtained from a permafrost borehole in northeastern Siberia capable of growth under conditions of low temperature (0 °C), low pressure (7 mbar), and a CO2-enriched anoxic atmosphere. By 16S ribosomal DNA analysis, all six permafrost isolates were identified as species of the genus Carnobacterium, most closely related to C. inhibens (five isolates) and C. viridans (one isolate). Quantitative growth assays demonstrated that the six permafrost isolates, as well as nine type species of Carnobacterium (C. alterfunditum, C. divergens, C. funditum, C. gallinarum, C. inhibens, C. maltaromaticum, C. mobile, C. pleistocenium, and C. viridans) were all capable of growth under cold, low-pressure, anoxic conditions, thus extending the low-pressure extreme at which life can function.

  20. Direct fermentation of gelatinized cassava starch to acetone, butanol, and ethanol using Clostridium acetobutylicum mutant obtained by atmospheric and room temperature plasma.

    Science.gov (United States)

    Li, Han-guang; Luo, Wei; Wang, Qiang; Yu, Xiao-bin

    2014-04-01

    The mutant strain designated as ART18, obtained from the wild-type strain Clostridium acetobutylicum PW12 treated by atmospheric and room temperature plasma, showed higher solvent tolerance and butanol production than that of the wild-type strain. The production of butanol was 11.3 ± 0.5 g/L, 31 % higher than that of the wild-type strain when it was used for acetone, butanol, and ethanol fermentation in P2 medium. Furthermore, the effects of cassava flour concentration, pH regulators, and vitamins on the ABE production were also investigated. The highest butanol production of 15.8 ± 0.8 g/L and butanol yield (0.31 g/g) were achieved after the above factors were optimized. When acetone, butanol, and ethanol fermentation by ART18 was carried out in a 15-L bioreactor, the butanol production, the productivity of butanol, and the total solvent were 16.3 ± 0.9, 0.19, and 0.28 g/L(/)h, respectively. These results indicate that ART18 is a promising industrial producer in ABE fermentation.

  1. Delafossite-CuAlO{sub 2} films prepared by annealing of amorphous Cu-Al-O films at high temperature under controlled atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Hong-Ying, E-mail: hychen@cc.kuas.edu.tw; Tsai, Ming-Wei

    2011-07-01

    In this study, amorphous Cu-Al-O films were deposited onto a (100) p-type silicon substrate by a magnetron sputtering system. The films were then annealed at 700 deg. C and 800 deg. C for 2 h in N{sub 2}, air and O{sub 2}. X-ray diffraction patterns showed that the as-deposited films were amorphous. When the films were annealed at 700 deg. C, the monoclinic-CuO and spinel-CuAl{sub 2}O{sub 4} phases were detected in all atmospheres. As the annealing temperature increased to 800 deg. C, delafossite-CuAlO{sub 2} (R3-bar m and P6{sub 3}/mmc phases) appeared in N{sub 2} whereas monoclinic-CuO and spinel-CuAl{sub 2}O{sub 4} phases were detected in air and O{sub 2}. Thermodynamic calculations can explain the formation of delafossite-CuAlO{sub 2} films. The optical bandgap and conductivity of delafossite-CuAlO{sub 2} films were 3.30 eV and 6.8 x 10{sup -3} S/cm, respectively, which are compatible with other data in the literature. The p-type characteristic in delafossite-CuAlO{sub 2} films was verified by a hot-probe method.

  2. Laser-induced Fluorescence and Optical Emission Spectroscopy for the Determination of Reactive Species in the Effluent of Atmospheric Pressure Low Temperature Plasma Jets

    Science.gov (United States)

    Pei, Xuekai; Razavi, Hamid; Lu, Xinpei; Laroussi, Mounir

    2014-10-01

    OH radicals and O atoms are important active species in various applications of room temperature atmospheric pressure plasma jet (RT-APPJ). So the determination of absolute density of OH radicals and O atoms in RT-APPJs is necessary. In this work, the time and spatially resolved OH radicals density of a RT-APPJ are measured using the laser-induced fluorescence (LIF) technology. In addition, the spatial distribution of the emitting species along the axial direction of the jet is of interest and is measured using optical emission spectroscopy. The absolute OH density of the RT-APPJ is about 2.0 × 1013 cm-3 at 5 mm away from the plasma jet nozzle and 1 μs after the discharge. The OH density reaches a maximum when H2O concentration in helium gas flow is about 130ppm. In order to control the OH density, the effect of voltage polarity, applied voltage magnitude, pulse frequency, pulse width on the OH density are also investigated and discussed. O atoms are investigated by TA-LIF. It is demonstrated that the O atoms density reaches a maximum when O2 percent is about 0.3% in pure He and the lifetime of O atoms in RT-APPJ is much longer (up to dozens of ms) than OH radicals.

  3. High temperature X-ray diffraction and thermo-gravimetrical analysis of the cubic perovskite Ba0.5Sr0.5Co0.8Fe0.2O3-δ under different atmospheres.

    Science.gov (United States)

    Sahini, M G; Tolchard, J R; Wiik, K; Grande, T

    2015-06-21

    Ba(0.5)Sr(0.5)Co(0.8)Fe(0.2)O(3-δ) (BSCF) with the cubic perovskite structure is known to be metastable at low temperature under an oxidizing atmosphere. Here, the thermal and chemical expansion of BSCF were studied by in situ high temperature powder X-ray diffraction and thermo-gravimetrical analysis (TGA) in partial pressure of oxygen ranging from an inert atmosphere (∼10(-4) bar) to 10 bar O(2). The BSCF powder, heat treated at 1000 °C and quenched to ambient temperature prior to the analysis, was shown to oxidize under an oxidizing atmosphere before thermal reduction took place. With decreasing partial pressure of oxygen the initial oxidation was suppressed and only reduction of Co/Fe and loss of oxygen were observed under an inert atmosphere. The thermal expansion of BSCF under different atmospheres was determined from the thermal evolution of the cubic unit cell parameter, demonstrating that the thermal expansion of BSCF depends on the atmosphere. Chemical expansion of BSCF was also estimated based on the diffraction data and thermo-gravimetrical analysis. A hexagonal perovskite phase, coexisting with the cubic BSCF polymorph, was observed to be formed above 600 °C during heating. The phase separation leading to the formation of the hexagonal polymorph was driven by oxidation, and the unit cell of the cubic BSCF was shown to decrease with increasing amounts of the hexagonal phase. The hexagonal phase disappeared upon further heating, accompanied with an expansion of the unit cell of the cubic BSCF.

  4. Changes in flavor precursors, pungency, and sugar content in short-day onion bulbs during 5-month storage at various temperatures or in controlled atmosphere.

    Science.gov (United States)

    Yoo, Kil S; Lee, Eun J; Patil, Bhimanagouda S

    2012-02-01

    Short-day onion bulbs (cv. TG 1015Y) were stored in 1% O(2,) 99% N(2) air at 5 °C (controlled atmosphere [CA]), or in ambient air at 5, 24, or 30 °C, for 5 mo. Changes in flavor precursors, pungency, and sugar content were investigated. After 5 mo of storage, 1-propenyl-L-cysteine sulfoxide concentrations increased continuously at 5 °C, gradually decreased in CA, slightly increased for 3 mo, and returned to initial levels at 24 °C and decreased below initial levels at 34 °C. Methyl-L-cysteine sulfoxide concentrations remained unchanged in all storage conditions. Onion pungency levels significantly increased at 5 °C, and decreased at 30 °C. Storage in CA and at 24 °C resulted in some fluctuations in pungency but the levels remained similar to initial levels. The calculated pyruvic acid concentrations were approximately 1.0 μmole/mL higher than the measured concentrations, and showed an increase at 5 °C and a slight reduction at 30 °C, consistent with the pungency results. Storage at 5 °C and in CA resulted in slight increases in fructose and glucose concentrations for 3 to 4 mo with subsequent rapid decreases, while sucrose concentrations remained unchanged. However, at 24 and 30 °C, fructose and glucose concentrations continuously decreased, accompanied by a continuous increase in sucrose concentrations. Storage in CA maintained the quality of onions best, as evidenced by the smallest changes in flavor precursors, pungency, and sugar concentrations, while storage at 5 °C resulted in increased pungency. Storage at 24 and 30 °C was tested for the purpose of comparison only; these temperatures are not recommended for commercial storage.

  5. Occurrence of gaseous and particulate polycyclic aromatic hydrocarbons in the urban atmosphere: study of sources and ambient temperature effect on the gas/particle concentration and distribution

    Energy Technology Data Exchange (ETDEWEB)

    Tsapakis, Manolis [Environmental Chemical Processes Laboratory (ECPL), Department of Chemistry, University of Crete, EL-71409 Heraklion (Greece); Stephanou, Euripides G. [Environmental Chemical Processes Laboratory (ECPL), Department of Chemistry, University of Crete, EL-71409 Heraklion (Greece)]. E-mail: stephanou@chemistry.uoc.gr

    2005-01-01

    The presence of polycyclic aromatic hydrocarbons (PAHs) in an urban region (Heraklion, Greece) and processes that govern their atmospheric fate were studied from November 2000 until February 2002. Sixteen samples were collected, by using an artifact-free sampling device, on a monthly basis and the concentration of PAHs in gas and particulate phase was determined. The most abundant members (gas + particles) were phenanthrene (20.0 {+-} 7.0 ng m{sup -3}), fluoranthene (6.5 {+-} 1.7 ng m{sup -3}), pyrene (6.6 {+-} 2.4 ng m{sup -3}), and chrysene (3.1 {+-} 1.5 ng m{sup -3}). Total concentration (gas + particulate) of PAH ranged from 44.3 to 129.2 ng m{sup -3}, with a mean concentration of 79.3 ng m{sup -3}. Total concentration of PAHs in gas phase ranged from 31.4 to 84.7 ng m{sup -3} with non-observable seasonal variation. Conversely, maximum PAH concentrations in the particulate phase occurred during winter months. Particulate concentration varied from 11.4 to 44.9 ng m{sup -3}, with an average of 25.2 ng m{sup -3}. PAH distribution between gas and particulate phase was in agreement with the sub-cooled vapor pressure. Shift in gas/particle distribution due to difference in ambient temperature elucidated to some extent the seasonal variation of the concentration of PAHs in particles. - Capsule: Ambient PAH partitioning between gas and particle phases vary between compounds and with environmental conditions.

  6. Impact of storm-induced cooling of sea surface temperature on large turbulent eddies and vertical turbulent transport in the atmospheric boundary layer of Hurricane Isaac

    Science.gov (United States)

    Zhu, Ping; Wang, Yuting; Chen, Shuyi S.; Curcic, Milan; Gao, Cen

    2016-01-01

    Roll vortices in the atmospheric boundary layer (ABL) are important to oil operation and oil spill transport. This study investigates the impact of storm-induced sea surface temperature (SST) cooling on the roll vortices generated by the convective and dynamic instability in the ABL of Hurricane Isaac (2012) and the roll induced transport using hindcasting large eddy simulations (LESs) configured from the multiply nested Weather Research & Forecasting model. Two experiments are performed: one forced by the Unified Wave INterface - Coupled Model and the other with the SST replaced by the NCEP FNL analysis that does not include the storm-induced SST cooling. The simulations show that the roll vortices are the prevalent eddy circulations in the ABL of Isaac. The storm-induced SST cooling causes the ABL stability falls in a range that satisfies the empirical criterion of roll generation by dynamic instability, whereas the ABL stability without considering the storm-induced SST cooling meets the criterion of roll generation by convective instability. The ABL roll is skewed and the increase of convective instability enhances the skewness. Large convective instability leads to large vertical transport of heat and moisture; whereas the dominant dynamic instability results in large turbulent kinetic energy but relatively weak heat and moisture transport. This study suggests that failure to consider roll vortices or incorrect initiation of dynamic and convective instability of rolls in simulations may substantially affect the transport of momentum, energy, and pollutants in the ABL and the dispersion/advection of oil spill fume at the ocean surface.

  7. Synergy of CuO and CeO2 combination for mercury oxidation under low-temperature selective catalytic reduction atmosphere

    KAUST Repository

    Li, Hailong

    2016-07-19

    Synergy for low temperature Hg0 oxidation under selective catalytic reduction (SCR) atmosphere was achieved when copper oxides and cerium oxides were combined in a CuO-CeO2/TiO2 (CuCeTi) catalyst. Hg0 oxidation efficiency as high as 99.0% was observed on the CuCeTi catalyst at 200 °C, even the gas hourly space velocity was extremely high. To analyze the synergistic effect, comparisons of catalyst performance in the presence of different SCR reaction gases were systematically conducted over CuO/TiO2 (CuTi), CeO2/TiO2 (CeTi) and CuCeTi catalysts prepared by sol-gel method. The interactions between copper oxides and cerium oxides in CuCeTi catalyst yielded more surface chemisorbed oxygen, and facilitated the conversion of gas-phase O2 to surface oxygen, which are favorable for Hg0 oxidation. Copper oxides in the combination interacted with NO forming more chemisorbed oxygen for Hg0 oxidation in the absence of gas-phase O2. Cerium oxides in the combination promoted Hg0 oxidation through enhancing the transformations of NO to NO2. In the absence of NO, NH3 exhibited no inhibitive effect on Hg0 oxidation, because enough Lewis acid sites due to the combination of copper oxides and cerium oxides scavenged the competitive adsorption between NH3 and Hg0. In the presence of NO, although NH3 lowered Hg0 oxidation rate through inducing reduction of oxidized mercury, complete recovery of Hg0 oxidation activity over the CuCeTi catalyst was quickly achieved after cutting off NH3. This study revealed the synergistic effect of the combination of copper oxides and cerium oxides on Hg0 oxidation, and explored the involved mechanisms. Such knowledge would help obtaining maximum Hg0 oxidation co-benefit from SCR units in coal-fired power plants.

  8. Qualidade de ameixas 'Laetitia' em função da temperatura e da atmosfera de armazenamento Quality of 'Laetitia' plums as affected by temperature and storage atmosphere

    Directory of Open Access Journals (Sweden)

    Erlani de Oliveira Alves

    2010-12-01

    Full Text Available O objetivo deste trabalho foi avaliar o efeito da temperatura e de atmosferas de armazenamento sobre a manutenção da qualidade de ameixas 'Laetitia'. Os tratamentos avaliados constituíram-se na combinação de duas temperaturas (-0,5ºC e 0,5ºC, com três atmosferas de armazenamento: armazenamento refrigerado (AR, com 21,0 kPa de O2 + 0,03 kPa de CO2; atmosfera controlada (AC, com 1,0 kPa de O2 + 3,0 kPa de CO2; e AC, com 2,0 kPa de O2 + 5,0 kPa de CO2. Após 60 dias de armazenamento, foram avaliadas: taxas respiratória e de produção de etileno, acidez titulável (AT, firmeza de polpa, atributos de textura, índice de cor vermelha e ângulo 'hue' (hº da casca, e incidência de rachaduras, podridões e degenerescência da polpa. O armazenamento refrigerado a -0,5ºC resultou em menores valores para o índice de cor vermelha, taxa respiratória e de produção de etileno e incidência de frutos rachados. Em ambas as condições de AC, a temperatura de 0,5ºC resultou em menor índice de cor vermelha, cor da epiderme mais verde, maior firmeza de polpa e menor taxa de produção de etileno, tanto na abertura da câmara como após quatro dias em condição ambiente. As condições de AC retardaram o amadurecimento dos frutos e reduziram a incidência de degenerescência de polpa. O armazenamento em AC, com 2,0 kPa de O2 + 5,0 kPa de CO2, a 0,5ºC, proporcionou menor taxa respiratória e menor incidência de podridões na saída da câmara, mas maior AT e força para penetração da polpa, após quatro dias em condição ambiente. No entanto, o armazenamento da ameixa 'Laetitia', nas condições de AC avaliadas, por um período de 60 dias, não reduziu a incidência de degenerescência da polpa.The aim of this work was to evaluate the effect of temperature and storage atmospheres on the quality of 'Laetitia' plums. The treatments were obtained from the combination of two temperatures (-0.5ºC and 0.5ºC with three storage atmospheres: cold

  9. Atmospheric Habitable Zones in Y Dwarf Atmospheres

    Science.gov (United States)

    Yates, Jack S.; Palmer, Paul I.; Biller, Beth; Cockell, Charles S.

    2017-02-01

    We use a simple organism lifecycle model to explore the viability of an atmospheric habitable zone (AHZ), with temperatures that could support Earth-centric life, which sits above an environment that does not support life. To illustrate our model, we use a cool Y dwarf atmosphere, such as WISE J085510.83–0714442.5, whose 4.5–5.2 μm spectrum shows absorption features consistent with water vapor and clouds. We allow organisms to adapt to their atmospheric environment (described by temperature, convection, and gravity) by adopting different growth strategies that maximize their chance of survival and proliferation. We assume a constant upward vertical velocity through the AHZ. We found that the organism growth strategy is most sensitive to the magnitude of the atmospheric convection. Stronger convection supports the evolution of more massive organisms. For a purely radiative environment, we find that evolved organisms have a mass that is an order of magnitude smaller than terrestrial microbes, thereby defining a dynamical constraint on the dimensions of life that an AHZ can support. Based on a previously defined statistical approach, we infer that there are of the order of 109 cool Y brown dwarfs in the Milky Way, and likely a few tens of these objects are within 10 pc from Earth. Our work also has implications for exploring life in the atmospheres of temperate gas giants. Consideration of the habitable volumes in planetary atmospheres significantly increases the volume of habitable space in the galaxy.

  10. Measurement of the Temperature Dependence of Line Mixing and Pressure Broadening Parameters between 296 and 90 K in the v3 band of 12CH4 and their Influence on Atmospheric Methane Retrievals

    Science.gov (United States)

    Mondelain, Didier; Payan, Sebastien; Deng, Wenping; Camy-Peyret, Claude; Hurtmans, Daniel; Mantz, Arlan W.

    2007-01-01

    We measured the temperature dependence of the nitrogen broadening, narrowing and line-mixing coefficients of four lines of the P9 manifold in the v3 band of 12CH4 for atmospheric purposes. The data were collected using our tunable diode laser (TDL) spectrometer with active wavenumber control coupled to a newly developed cold Herriott cell with a path length of 5.37 m and a temperature uniformity of better than 0.01 K along the cell. We recorded and analyzed spectra recorded at sample temperature between 90 K and room temperature. We have investigate the influence of our new results in the inversion model used to retrieve methane profiles from atmospheric spectra; our new results make it possible to retrieve significantly more precise methane profiles. The atmospheric spectra we utilized were obtained by several of us with a balloon-born Fourier Transform infrared experiment in a limb configuration. Differences up to 7% on the retrieved volume mixing ratio were found compared to an inversion model using only HITRAN04 spectroscopic parameters.

  11. Atmospheric Habitable Zones in Y Dwarf Atmospheres

    CERN Document Server

    Yates, Jack S; Biller, Beth; Cockell, Charles S

    2016-01-01

    We use a simple organism lifecycle model to explore the viability of an atmospheric habitable zone (AHZ), with temperatures that could support Earth-centric life, which sits above an environment that does not support life. We illustrate this idea using the object WISE J085510.83-0714442.5, which is a cool, free-floating brown dwarf. We allow organisms to adapt to their atmospheric environment (described by temperature, convection, and gravity) by adopting different growth strategies that maximize their chance of survival and proliferation. We assume a constant upward vertical velocity through the AHZ. We found that the organism growth strategy is most sensitive to the magnitude of the atmospheric convection. Stronger convection supports the evolution of more massive organisms. For a purely radiative environment we find that evolved organisms have a mass that is an order of magnitude smaller than terrestrial microbes, thereby defining a dynamical constraint on the dimensions of life that an AHZ can support. Ba...

  12. Temperature Dependence of Carbon Kinetic Isotope Effect for the Oxidation Reaction of Ethane by Hydroxyl Radicals Under Atmospherically Relevant Conditions: Experimental and Theoretical Studies

    OpenAIRE

    Piansawan, Tammarat

    2016-01-01

           Ethane is the second most abundant hydrocarbon in the atmosphere, after methane, impacting on air quality, human health and climate. A quantification of its effects requires accurate knowledge of sources, processes along transport, and sinks. Carbon stable isotopic ratio investigations, complementarily to concentration measurements, were demonstrated to give more insight in source apportionment and atmospheric processing of organic compounds.        Yet, apportionment of atmospher...

  13. Effective mie-scattering and CO2 absorption in the dust-laden Martian atmosphere and its impact on radiative-convective temperature changes in the lower scale heights

    Science.gov (United States)

    Pallmann, A. J.

    1976-01-01

    A time dependent computer model of radiative-convective-conductive heat transfer in the Martian ground-atmosphere system was refined by incorporating an intermediate line strength CO2 band absorption which together with the strong-and weak-line approximation closely simulated the radiative transmission through a vertically inhomogeneous stratification. About 33,000 CO2 lines were processed to cover the spectral range of solar and planetary radiation. Absorption by silicate dust particulates, was taken into consideration to study its impact on the ground-atmosphere temperature field as a function of time. This model was subsequently attuned to IRIS, IR-radiometric and S-band occultation data. Satisfactory simulations of the measured IRIS spectra were accomplished for the dust-free condition. In the case of variable dust loads, the simulations were sufficiently fair so that some inferences into the effect of dust on temperature were justified.

  14. The atmospheric chemistry of the warm Neptune GJ 3470b: influence of metallicity and temperature on the CH4/CO ratio

    CERN Document Server

    Venot, Olivia; Selsis, Franck; Tessenyi, Marcell; Iro, Nicolas

    2013-01-01

    Current observation techniques are able to probe the atmosphere of some giant exoplanets and get some clues about their atmospheric composition. However, the chemical compositions derived from observations are not fully understood, as for instance in the case of the CH4/CO abundance ratio, which is often inferred different from what has been predicted by chemical models. Recently, the warm Neptune GJ3470b has been discovered and because of its close distance from us and high transit depth, it is a very promising candidate for follow up characterisation of its atmosphere. We study the atmospheric composition of GJ3470b in order to compare with the current observations of this planet, to prepare the future ones, but also as a typical case study to understand the chemical composition of warm (sub-)Neptunes. The metallicity of such atmospheres is totally uncertain, and vary probably to values up to 100x solar. We explore the space of unknown parameters to predict the range of possible atmospheric compositions. Wi...

  15. Mathematical Analysis of High-Temperature Co-electrolysis of CO2 and O2 Production in a Closed-Loop Atmosphere Revitalization System

    Energy Technology Data Exchange (ETDEWEB)

    Michael G. McKellar; Manohar S. Sohal; Lila Mulloth; Bernadette Luna; Morgan B. Abney

    2010-03-01

    NASA has been evaluating two closed-loop atmosphere revitalization architectures based on Sabatier and Bosch carbon dioxide, CO2, reduction technologies. The CO2 and steam, H2O, co-electrolysis process is another option that NASA has investigated. Utilizing recent advances in the fuel cell technology sector, the Idaho National Laboratory, INL, has developed a CO2 and H2O co-electrolysis process to produce oxygen and syngas (carbon monoxide, CO and hydrogen, H2 mixture) for terrestrial (energy production) application. The technology is a combined process that involves steam electrolysis, CO2 electrolysis, and the reverse water gas shift (RWGS) reaction. A number of process models have been developed and analyzed to determine the theoretical power required to recover oxygen, O2, in each case. These models include the current Sabatier and Bosch technologies and combinations of those processes with high-temperature co-electrolysis. The cases of constant CO2 supply and constant O2 production were evaluated. In addition, a process model of the hydrogenation process with co-electrolysis was developed and compared. Sabatier processes require the least amount of energy input per kg of oxygen produced. If co-electrolysis replaces solid polymer electrolyte (SPE) electrolysis within the Sabatier architecture, the power requirement is reduced by over 10%, but only if heat recuperation is used. Sabatier processes, however, require external water to achieve the lower power results. Under conditions of constant incoming carbon dioxide flow, the Sabatier architectures require more power than the other architectures. The Bosch, Boudouard with co-electrolysis, and the hydrogenation with co-electrolysis processes require little or no external water. The Bosch and hydrogenation processes produce water within their reactors, which aids in reducing the power requirement for electrolysis. The Boudouard with co-electrolysis process has a higher electrolysis power requirement because carbon

  16. Experiment on influence of ice-temperature controlled atmosphere storage on Pinggu peach quality%冰温气调贮藏对平谷大桃品质影响的实验研究

    Institute of Scientific and Technical Information of China (English)

    申江; 刘丽; 宋烨; 胡开永

    2013-01-01

    将冰温贮藏和气调贮藏相结合,开展了冰温气调贮藏对平谷大桃品质影响的实验研究.实验在冰温条件下从调节气体组分入手,研究不同气体指标对平谷大桃贮藏期间品质变化的影响.得出以下结论:冰温环境结合气调贮藏,能够更加有效地降低大桃的代谢作用.与-1.2℃普通冰温贮藏相比较,大桃在冰温结合氧气浓度为3%和5%环境下贮藏的品质要优于普通冰温贮藏,贮藏期间糖类和维生素C都保持较高的含量,并最后得出了平谷大桃保鲜的有效方法.%Ice-temperature storage and controlled atmosphere storage had been combined to carry out the experimental study of ice - temperature controlled atmosphere storage to the effect of Pinggu peach quality.Experimental in ice-temperature condition from regulating gas components start to research the impact of different gas indicators of Pinggu peach quality change during storage.The results showed that the ice - temperature environment combined with controlled atmosphere storage was able to be more effectively to reduce peach' s metabolism.Compared with of -1.2℃ ordinary ice temperature storage,the peach ice-temperature combined with the atmosphere concentration of 3% and 5% of the storage environment quality was better than ordinary ice temperature storage.During storage carbohydrates and vitamin C had been to maintain a higher content,and come to the Pinggu peach preservation effective method.

  17. Carbon dioxide, temperature, salinity, wind speed, air temperature, and atmospheric pressure collected via surface underway survey from R/V Aegaeo in Aegean Sea from February 8, 2006 to February 13, 2006 (NODC Accession 0084543)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0084543 includes chemical, meteorological, and physical underway data collected aboard the AEGAEO in Aegean Sea, and Mediterranean Sea from 8 February...

  18. Staging atmospheres

    DEFF Research Database (Denmark)

    Bille, Mikkel; Bjerregaard, Peter; Sørensen, Tim Flohr

    2015-01-01

    The article introduces the special issue on staging atmospheres by surveying the philosophical, political and anthropological literature on atmosphere, and explores the relationship between atmosphere, material culture, subjectivity and affect. Atmosphere seems to occupy one of the classic...... localities of tensions between matter and the immaterial, the practical and the ideal, and subject and object. In the colloquial language there can, moreover, often seem to be something authentic or genuine about atmosphere, juxtaposing it to staging, which is implied to be something simulated or artificial....... This introduction seeks to outline how a number of scholars have addressed the relationship between staged atmospheres and experience, and thus highlight both the philosophical, social and political aspects of atmospheres...

  19. Effect of flue gas composition on deposit induced high temperature corrosion under laboratory conditions mimicking biomass firing. Part I: Exposures in oxidizing and chlorinating atmospheres

    DEFF Research Database (Denmark)

    Okoro, Sunday Chukwudi; Kiamehr, Saeed; Montgomery, Melanie;

    2016-01-01

    bothoxidizing and oxidizing-chlorinating atmospheres, and the resulting corrosionproducts were comprehensively studied with scanning electron microscopy(SEM), energy dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD)techniques. The results show that deposit-free samples suffer grain boundaryattack...... only in an oxidizing-chlorinating atmosphere, otherwise corrosionresults in formation of a duplex oxide. Corrosion attack on deposit-coatedsamples was higher than on deposit-free samples irrespective of the gaseousatmosphere. Specifically, severe volatilization of alloying elements occurred ondeposit...

  20. Comment on "The phase relation between atmospheric carbon dioxide and global temperature" Humlum et al. [Glob. Planet. Change 100: 51-69.]: Isotopes ignored

    Science.gov (United States)

    Kern, Zoltán; Leuenberger, Markus

    2013-10-01

    A recent study relying purely on statistical analysis of relatively short time series suggested substantial re-thinking of the traditional view about causality explaining the detected rising trend of atmospheric CO2 (atmCO2) concentrations. If these results are well-justified then they should surely compel a fundamental scientific shift in paradigms regarding both atmospheric greenhouse warming mechanism and global carbon cycle. However, the presented work suffers from serious logical deficiencies such as, 1) what could be the sink for fossil fuel CO2 emissions, if neither the atmosphere nor the ocean - as suggested by the authors - plays a role? 2) What is the alternative explanation for ocean acidification if the ocean is a net source of CO2 to the atmosphere? Probably the most provocative point of the commented study is that anthropogenic emissions have little influence on atmCO2 concentrations. The authors have obviously ignored the reconstructed and directly measured carbon isotopic trends of atmCO2 (both δ13C, and radiocarbon dilution) and the declining O2/N2 ratio, although these parameters provide solid evidence that fossil fuel combustion is the major source of atmCO2 increase throughout the Industrial Era.

  1. Fine-Structure Measurements of Oxygen A Band Absorbance for Estimating the Thermodynamic Average Temperature of the Earth's Atmosphere: An Experiment in Physical and Environmental Chemistry

    Science.gov (United States)

    Myrick, M. L.; Greer, A. E.; Nieuwland, A.; Priore, R. J.; Scaffidi, J.; Andreatta, Daniele; Colavita, Paula

    2006-01-01

    The experiment describe the measures of the A band transitions of atmospheric oxygen, a rich series of rotation-electronic absorption lines falling in the deep red portion of the optical spectrum and clearly visible owing to attenuation of solar radiation. It combines pure physical chemistry with analytical and environmental science and provides a…

  2. Low-Temperature DC Carrier Transport in (Fe0.45Co0.45Zr0.10x(Al2O31−x Nanocomposites Manufactured by Sputtering in Pure Ar Gas Atmosphere

    Directory of Open Access Journals (Sweden)

    Ivan A. Svito

    2015-01-01

    Full Text Available This presented work investigates the structure and temperature relationship/dependence of the DC conductivity σ(T in the (Fe0.45Co0.45Zr0.10x(Al2O31−x nanocomposites deposited in Ar atmosphere with composition (30temperature (2temperatures of 100–120 K. It is also noted that the observed shift of the percolation threshold to higher concentrations of metallic fraction can be attributed to the disordering of the metallic nanoparticles due to the incorporation of the residual oxygen in the vacuum chamber during the deposition procedure.

  3. Atmospheric Neutrinos

    OpenAIRE

    Takaaki Kajita

    1994-01-01

    Atmospheric neutrinos are produced as decay products in hadronic showers resulting from collisions of cosmic rays with nuclei in the atmosphere. Electron-neutrinos and muon-neutrinos are produced mainly by the decay chain of charged pions to muons to electrons. Atmospheric neutrino experiments observed zenith angle and energy-dependent deficit of muon-neutrino events. It was found that neutrino oscillations between muon-neutrinos and tau-neutrinos explain these data well. This paper discusses...

  4. Articulating Atmospheres

    DEFF Research Database (Denmark)

    Kinch, Sofie

    2011-01-01

    This paper presents an architectural approach to designing computational interfaces by articulating the notion of atmosphere in the field of interaction design. It draws upon the concept of kinesthetic interaction and a philosophical notion on atmosphere emphasizing the importance of bodily...... experience in space, presented as middle ground experience. In the field of HCI, middle ground experiences complete the unarticulated spectrum between designing for foreground of attention or background awareness. When “Articulating Atmospheres through Middle Ground Experiences in Interaction Design...

  5. Exact results in modeling planetary atmospheres-I. Gray atmospheres

    Energy Technology Data Exchange (ETDEWEB)

    Chevallier, L. [Observatoire de Paris-Meudon, Laboratoire LUTH, 5 Place Jules Janssen, 92195 Meudon cedex (France)]. E-mail: loic.chevallier@obspm.fr; Pelkowski, J. [Institut fuer Meteorologie und Geophysik, J.W. Goethe Universitaet Frankfurt, Robert Mayer Strasse 1, D-60325 Frankfurt (Germany); Rutily, B. [Universite de Lyon, Lyon, F-69000 (France) and Universite Lyon 1, Villeurbanne, F-69622 (France) and Centre de Recherche Astronomique de Lyon, Observatoire de Lyon, 9 avenue Charles Andre, Saint-Genis Laval cedex, F-69561 (France) and CNRS, UMR 5574; Ecole Normale Superieure de Lyon, Lyon (France)

    2007-04-15

    An exact model is proposed for a gray, isotropically scattering planetary atmosphere in radiative equilibrium. The slab is illuminated on one side by a collimated beam and is bounded on the other side by an emitting and partially reflecting ground. We provide expressions for the incident and reflected fluxes on both boundary surfaces, as well as the temperature of the ground and the temperature distribution in the atmosphere, assuming the latter to be in local thermodynamic equilibrium. Tables and curves of the temperature distribution are included for various values of the optical thickness. Finally, semi-infinite atmospheres illuminated from the outside or by sources at infinity is dealt with.

  6. Atmospheric Neutrinos

    Directory of Open Access Journals (Sweden)

    Takaaki Kajita

    2012-01-01

    Full Text Available Atmospheric neutrinos are produced as decay products in hadronic showers resulting from collisions of cosmic rays with nuclei in the atmosphere. Electron-neutrinos and muon-neutrinos are produced mainly by the decay chain of charged pions to muons to electrons. Atmospheric neutrino experiments observed zenith angle and energy-dependent deficit of muon-neutrino events. It was found that neutrino oscillations between muon-neutrinos and tau-neutrinos explain these data well. This paper discusses atmospheric neutrino experiments and the neutrino oscillation studies with these neutrinos.

  7. Atmospheric electricity

    CERN Document Server

    Chalmers, J Alan

    1957-01-01

    Atmospheric Electricity brings together numerous studies on various aspects of atmospheric electricity. This book is composed of 13 chapters that cover the main problems in the field, including the maintenance of the negative charge on the earth and the origin of the charges in thunderstorms. After a brief overview of the historical developments of atmospheric electricity, this book goes on dealing with the general principles, results, methods, and the MKS system of the field. The succeeding chapters are devoted to some aspects of electricity in the atmosphere, such as the occurrence and d

  8. Possible combined influences of absorbing aerosols and anomalous atmospheric circulation on summertime diurnal temperature range variation over the middle and lower reaches of the Yangtze River

    Science.gov (United States)

    Cai, Jiaxi; Guan, Zhaoyong; Ma, Fenhua

    2016-12-01

    Based on the temperature data from the China Meteorological Administration, NCEP-NCAR reanalysis data, and the TOMS Aerosol Index (AI), we analyze the variations in the summertime diurnal temperature range (DTR) and temperature maxima in the middle and lower reaches of the Yangtze River (MLRYR) in China. The possible relationships between the direct warming effect of the absorbing aerosol and temperature variations are further investigated, although with some uncertainties. It is found that the summertime DTR exhibits a decreasing trend over the most recent 50 years, along with a slight increasing tendency since the 1980s. The trend of the maximum temperature is in agreement with those of the DTR and the absorbing aerosols. To investigate the causes of the large anomalies in the temperature maxima, composite analyses of the circulation anomalies are performed. When anomalous AI and anomalous maximum temperature over the MLRYR have the same sign, an anomalous circulation with a quasi-barotropic structure occurs there. This anomalous circulation is modulated by the Rossby wave energy propagations from the regions northwest of the MLRYR and influences the northwestern Pacific subtropical high over the MLRYR. In combination with aerosols, the anomalous circulation may increase the maximum temperature in this region. Conversely, when the anomalous AI and anomalous maximum temperature in the MLRYR have opposite signs, the anomalous circulation is not equivalently barotropic, which possibly offsets the warming effect of aerosols on the maximum temperature changes in this region. These results are helpful for a better understanding of the DTR changes and the occurrences of temperature extremes in the MLRYR region during boreal summer.

  9. Elevated atmospheric carbon dioxide and temperature effects on seed composition, mineral nutrition, and 15N and 13C dynamics in soybean genotypes under controlled environments

    Science.gov (United States)

    Seed nutrition of crops can be affected by global climate changes due to elevated CO2 and elevated temperatures. Information on the effects of elevated CO2 and temperature on seed nutrition is very limited in spite of its importance to seed quality and food security. Therefore, the objective of this...

  10. Survival of lactic acid and chlorine dioxide treated Campylobacter jejuni under suboptimal conditions of pH, temperature and modified atmosphere

    DEFF Research Database (Denmark)

    Smigic, Nada; Rajkovic, Andreja; Nielsen, Dennis Sandris;

    2010-01-01

    Campylobacter jejuni cells treated with lactic acid (LA, 3% lactic acid, pH 4.0, 2 min) or chlorine dioxide (ClO(2), 20 ppm, 2 min) were inoculated in Bolton broth (pH 6.0) and incubated under 80% O(2)/20% N(2), 80% CO(2)/20% N(2), air or micro-aerophilic (10% CO(2)/85% N(2)/5% O(2)) atmosphere, at 4 degrees C...

  11. Atmospheres of Brown Dwarfs

    CERN Document Server

    Helling, Christiane

    2014-01-01

    Brown Dwarfs are the coolest class of stellar objects known to date. Our present perception is that Brown Dwarfs follow the principles of star formation, and that Brown Dwarfs share many characteristics with planets. Being the darkest and lowest mass stars known makes Brown Dwarfs also the coolest stars known. This has profound implication for their spectral fingerprints. Brown Dwarfs cover a range of effective temperatures which cause brown dwarfs atmospheres to be a sequence that gradually changes from a M-dwarf-like spectrum into a planet-like spectrum. This further implies that below an effective temperature of < 2800K, clouds form already in atmospheres of objects marking the boundary between M-Dwarfs and brown dwarfs. Recent developments have sparked the interest in plasma processes in such very cool atmospheres: sporadic and quiescent radio emission has been observed in combination with decaying Xray-activity indicators across the fully convective boundary.

  12. Sintering temperature and atmosphere modulated evolution of structure and luminescence of 2CaO–P{sub 2}O{sub 5}–B{sub 2}O{sub 3}: Eu phosphors

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Chaofeng, E-mail: chaofengzhu@gmail.com [Key Laboratory of Processing and Testing Technology of Glass and Functional Ceramics of Shandong Province, Shandong Polytechnic University, Jinan 250353 (China); Key Laboratory of Amorphous and Polycrystalline Materials in Universities of Shandong, Shandong Polytechnic University, Jinan 250353 (China); Wang, Jia [Key Laboratory of Processing and Testing Technology of Glass and Functional Ceramics of Shandong Province, Shandong Polytechnic University, Jinan 250353 (China); Ren, Xiaorong [Instrumental Analysis Center, Shandong Polytechnic University, Jinan 250353 (China); Zhang, Yanfei; Liu, Shujiang; Shen, Jianxing [Key Laboratory of Processing and Testing Technology of Glass and Functional Ceramics of Shandong Province, Shandong Polytechnic University, Jinan 250353 (China); Yue, Yuanzheng, E-mail: yy@bio.aau.dk [Key Laboratory of Processing and Testing Technology of Glass and Functional Ceramics of Shandong Province, Shandong Polytechnic University, Jinan 250353 (China); Section of Chemistry, Aalborg University, Aalborg DK-9000 (Denmark)

    2014-01-15

    Europium doped 2CaO–P{sub 2}O{sub 5}–B{sub 2}O{sub 3} phosphors prepared via high temperature solid state reactions are reported. The evolution of luminescence and structure of the phosphors induced by variation of sintering temperature and atmosphere is investigated using photoluminescence spectra and X-ray diffraction techniques. We found that the optical performance and structure of the phosphors are sensitive to the sintering temperature and atmosphere. The luminescence intensity due to {sup 5}D{sub 0}→{sup 7}F{sub 2} transition of Eu{sup 3+} is decreased with increasing sintering temperature. CaBPO{sub 5} and BPO{sub 4} crystals co-exist in the as-prepared phosphors and the relative content of these two phases is dependent on sintering temperature. CaBPO{sub 5} crystal favors the transition of {sup 5}D{sub 0}→{sup 7}F{sub 1} of Eu{sup 3+} ions, while BPO{sub 4} enhances the emission of 612 nm. This study gives insight into the correlation between optical properties and structure of the as-prepared phosphors. The phosphors reported here are good candidates for light emitting diode applications. -- Highlights: • Eu doped 2CaO–P{sub 2}O{sub 5}–B{sub 2}O{sub 3} phosphors for LED applications are studied. • Effect of sintering conditions on optical property and structure is examined. • CaBPO{sub 5} favors the transition of {sup 5}D{sub 0}→{sup 7}F{sub 1} of Eu{sup 3+} in the investigated phosphors. • BPO{sub 4} enhances the emission of 612 nm of the phosphor.

  13. Photoacoustic study of the influence of the cooling temperature on the CO2 emission rate by Carica papaya L. in modified atmosphere

    Science.gov (United States)

    Schramm, D. U.; Sthel, M. S.; da Silva, M. G.; Carneiro, L. O.; Silva, H. R. F.; Martins, M. L. L.; Resende, E. D.; Vitorazi, L.; Vargas, H.

    2005-06-01

    The monitoring of trace gas emitted by papaya fruits and assessments of its mass loss can contribute to improve the conditions for their storage and transport. The C02 emission rate by the papaya fruits, monitored by a commercial infrared-based gas analyzer, was influenced by the temperature and storage time. The fruits stored at temperature of 13 °C accumulated more CO2 inside the PEBD bags than those fruits stored at 6 °C. The loss of mass of the fruits progressively increased with storage time for both temperatures until the saturation of the moisture inside the PEBD bag, been more pronounced at 13 ºC.

  14. Ocean Surface Temperature Response to Atmosphere-Ocean Interaction of the MJO. A Component of Coupled Air-Wave-Sea Processes in the Subtropics Departmental Research Initiative

    Science.gov (United States)

    2013-09-30

    Airborne IR imagery will provide high spatial resolution calibrated SST variability. The image scale will be roughly 500 m to 1000 m (depending on...array performance will allow for the determination of temperature variability of less than 50 mK. 3 Additionally, we will deploy a JADE LWIR 570...that are calibrated to better than 0.05ºC. The upward- looking instrumentation will be used to discriminate real from apparent ice surface temperature

  15. Effects of soil temperature and elevated atmospheric CO{sub 2} concentration on gas exchange, in vivo carboxylation and chlorophyll fluorescence in jack pine and white birch seedlings

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, S.; Dang, Q-L. [Lakehead University, Faculty of Forestry and the Forest Environment, Thunder Bay, ON (Canada)

    2005-05-01

    The interactive effects of soil temperature and elevated carbon dioxide on the photosynthetic functions of white birch and jack pine were investigated. Elevated carbon dioxide was found to significantly decrease the allocation of electron transport to photorespiration in both species by increasing electron allocation to Rubisco carboxylation. Photosynthetic down-regulation occurred in both species after four months in elevated carbon dioxide as evidenced by decreases in maximal carboxylation rate which were unaffected by soil temperature. 50 refs., 5 figs.

  16. On the use of the double floating probe method to infer the difference between the electron and the heavy particles temperatures in an atmospheric pressure, vortex-stabilized nitrogen plasma jet

    Energy Technology Data Exchange (ETDEWEB)

    Prevosto, L., E-mail: prevosto@waycom.com.ar; Mancinelli, B. R. [Grupo de Descargas Eléctricas, Departamento Ingeniería Electromecánica, Facultad Regional Venado Tuerto (UTN), Laprida 651, 2600 Venado Tuerto, Santa Fe (Argentina); Kelly, H. [Grupo de Descargas Eléctricas, Departamento Ingeniería Electromecánica, Facultad Regional Venado Tuerto (UTN), Laprida 651, 2600 Venado Tuerto, Santa Fe (Argentina); Instituto de Física del Plasma (CONICET), Departamento de Física, Facultad de Ciencias Exactas y Naturales (UBA) Ciudad Universitaria Pab. I, 1428 Buenos Aires (Argentina)

    2014-05-15

    Sweeping double probe measurements in an atmospheric pressure direct current vortex-stabilized plasma jet are reported (plasma conditions: 100 A discharge current, N{sub 2} gas flow rate of 25 Nl/min, thoriated tungsten rod-type cathode, copper anode with 5 mm inner diameter). The interpretation of the double probe characteristic was based on a generalization of the standard double floating probe formulae for non-uniform plasmas coupled to a non-equilibrium plasma composition model. Perturbations caused by the current to the probe together with collisional and thermal processes inside the probe perturbed region were taken into account. Radial values of the average electron and heavy particle temperatures as well as the electron density were obtained. The calculation of the temperature values did not require any specific assumption about a temperature relationship between different particle species. An electron temperature of 10 900 ± 900 K, a heavy particle temperature of 9300 ± 900 K, and an electron density of about 3.5 × 10{sup 22} m{sup −3} were found at the jet centre at 3.5 mm downstream from the torch exit. Large deviations from kinetic equilibrium were found toward the outer border of the plasma jet. These results showed good agreement with those previously reported by the authors by using a single probe technique. The calculations have shown that this method is particularly useful for studying spraying-type plasma torches operated at power levels of about 15 kW.

  17. On the use of the double floating probe method to infer the difference between the electron and the heavy particles temperatures in an atmospheric pressure, vortex-stabilized nitrogen plasma jet.

    Science.gov (United States)

    Prevosto, L; Kelly, H; Mancinelli, B R

    2014-05-01

    Sweeping double probe measurements in an atmospheric pressure direct current vortex-stabilized plasma jet are reported (plasma conditions: 100 A discharge current, N2 gas flow rate of 25 Nl/min, thoriated tungsten rod-type cathode, copper anode with 5 mm inner diameter). The interpretation of the double probe characteristic was based on a generalization of the standard double floating probe formulae for non-uniform plasmas coupled to a non-equilibrium plasma composition model. Perturbations caused by the current to the probe together with collisional and thermal processes inside the probe perturbed region were taken into account. Radial values of the average electron and heavy particle temperatures as well as the electron density were obtained. The calculation of the temperature values did not require any specific assumption about a temperature relationship between different particle species. An electron temperature of 10,900 ± 900 K, a heavy particle temperature of 9300 ± 900 K, and an electron density of about 3.5 × 10(22) m(-3) were found at the jet centre at 3.5 mm downstream from the torch exit. Large deviations from kinetic equilibrium were found toward the outer border of the plasma jet. These results showed good agreement with those previously reported by the authors by using a single probe technique. The calculations have shown that this method is particularly useful for studying spraying-type plasma torches operated at power levels of about 15 kW.

  18. 氦气流量和加工时间对大气等离子体温度的影响%Research on Influence of Plasma Gas He and process Time upon Temperature of Atmospheric Pressure Plasma Jet

    Institute of Scientific and Technical Information of China (English)

    赵玺; 金会良; 李娜; 金江; 王波

    2012-01-01

    Through Temperature analysis of the infrared camera at the atmospheric pressure plasma processing of fused silica upon the flow of helium and processing time,the relationship was got between the flow of Helium and processing time and the plasma temperature. With the increase of the flow of helium flow, it was found that the Plasma temperature increase to the peak followed by decreases. With the increase of the process time, stability is remained after the temperature increases to a certain temperature range.%通过红外热像仪对大气压下等离子体加工熔石英中的氦气流量和加工时间进行温度分析,分别得到氦气流量与加工时间对等离子体温度的联系.实验得出随着氦气流量的增加,等离子体温度先增加到峰值随后减小:随着加工时间的增加,温度增加至一定温度范围后基本保持稳定.

  19. Atmospheric materiality

    DEFF Research Database (Denmark)

    Wieczorek, Izabela

    2016-01-01

    experience and, consequently, to the conceptual and methodological shifts in the production of space, and hence in the way we think about materiality. In this context, architectural space is understood as a contingent construction – a space of engagement that appears to us as a result of continuous...... characteristics of atmosphere as a spatial phenomenon, the aim of this text is to illustrate these associations and draw out design protocols, focusing on ways in which atmosphere can be conditioned architecturally. In other words, the objective is to trace the conceptual contours of ‘atmospheric materiality’....

  20. High temperature corrosion of 9Cr-1Mo ferritic steel P91 modified, in oxidizing-carburizing atmospheres; Corrosion a temperatura alta del acero ferritico 9Cr-1Mo modificado P91, en atmosferas simuladas oxidantes-carburantes

    Energy Technology Data Exchange (ETDEWEB)

    Pena-Ballesteros, D. Y.; Vazquez-Quintero, C.; Laverde-Catano, D.; Serna, G.

    2012-11-01

    High temperature corrosion in processing units of the chemical, petrochemical, and thermoelectric carbochemical is of high interest, due to the costs generated by sudden failures caused by deterioration in the mechanical properties of metals, being the carburization of the metallic matrix the most important corrosion mechanism resulting in loss of ductility and creep resistance. In this research a 9Cr-1Mo modified steel P91 was exposed to simulated atmospheres oxidant-fuel gas mixtures simultaneous in equilibrium of CO, CO{sub 2}, CH{sub 4}, H{sub 2}O and H{sub 2}, similar to those produced in the refining industry, at temperatures between 550 and 750 degree centigrade. The microstructural evolution of the metal matrix was analyzed, also the growth, evolution and behavior of oxide layers and carburized, establishing the mechanism of deterioration of the material and the extent of damage for times exceeding 700 h of exposure. (Author) 21 refs.