WorldWideScience

Sample records for atmospheric pressure discharges

  1. Electron heating in atmospheric pressure glow discharges

    Science.gov (United States)

    Stark, Robert H.; Schoenbach, Karl H.

    2001-04-01

    The application of nanosecond voltage pulses to weakly ionized atmospheric pressure plasmas allows heating the electrons without considerably increasing the gas temperature, provided that the duration of the pulses is less than the critical time for the development of glow-to-arc transitions. The shift in the electron energy distribution towards higher energies causes a temporary increase in the ionization rate, and consequently a strong rise in electron density. This increase in electron density is reflected in an increased decay time of the plasma after the pulse application. Experiments in atmospheric pressure air glow discharges with gas temperatures of approximately 2000 K have been performed to explore the electron heating effect. Measurements of the temporal development of the voltage across the discharge and the optical emission in the visible after applying a 10 ns high voltage pulse to a weakly ionized steady state plasma demonstrated increasing plasma decay times from tens of nanoseconds to microseconds when the pulsed electric field was raised from 10 to 40 kV/cm. Temporally resolved photographs of the discharge have shown that the plasma column expands during this process. The nonlinear electron heating effect can be used to reduce the power consumption in a repetitively operated air plasma considerably compared to a dc plasma operation. Besides allowing power reduction, pulsed electron heating also has the potential to enhance plasma processes, which require elevated electron energies, such as excimer generation for ultraviolet lamps.

  2. Structure formation of atmospheric pressure discharge

    Science.gov (United States)

    Medvedev, Alexey E.

    2016-02-01

    In this paper it is shown, by analyzing the results of experimental studies, that the outer boundary of the atmospheric pressure discharge pinch is determined by the condition of equality of plasma flows based on the thermal and electric field energy. In most cases, the number of charged particles coming from near-electrode zones is sufficient to compensate for losses in the discharge bulk. At large currents and enhanced heating, plasma is in the diffusion mode of losses, with recombination of charged particles at the pinch boundary. Contribution to the Topical Issue "Recent Breakthroughs in Microplasma Science and Technology", edited by Kurt Becker, Jose Lopez, David Staack, Klaus-Dieter Weltmann and Wei Dong Zhu.

  3. Atmospheric Pressure Glow Discharge with Liquid Electrode

    Science.gov (United States)

    Tochikubo, Fumiyoshi

    2013-09-01

    Nonthermal atmospheric pressure plasmas in contact with liquid are widely studied aiming variety of plasma applications. DC glow discharge with liquid electrode is an easy method to obtain simple and stable plasma-liquid interface. When we focus attention on liquid-phase reaction, the discharge system is considered as electrolysis with plasma electrode. The plasma electrode will supply electrons and positive ions to the liquid surface in a different way from the conventional metal electrode. However, the phenomena at plasma-liquid interface have not been understood well. In this work, we studied physical and chemical effect in liquid induced by dc atmospheric pressure glow discharge with liquid electrode. The experiment was carried out using H-shaped Hoffman electrolysis apparatus filled with electrolyte, to separate the anodic and cathodic reactions. Two nozzle electrodes made of stainless steel are set about 2 mm above the liquid surface. By applying a dc voltage between the nozzle electrodes, dc glow discharges as plasma electrodes are generated in contact with liquid. As electrolyte, we used aqueous solutions of NaCl, Na2SO4, AgNO3 and HAuCl4. AgNO3 and HAuCl4 are to discuss the reduction process of metal ions for synthesis of nanoparticles (NPs). OH radical generation yield in liquid was measured by chemical probe method using terephthalic acid. Discharge-induced liquid flow was visualized by Schlieren method. Electron irradiation to liquid surface (plasma cathode) generated OH- and OH radical in liquid while positive ion irradiation (plasma anode) generated H+ and OH radical. The generation efficiency of OH radical was better with plasma anode. Both Ag NPs in AgNO3 and Au NPs in HAuCl4 were synthesized with plasma cathode while only Au NPs were generated with plasma anode. Possible reaction process is qualitatively discussed. The discharge-induced liquid flow such as convection pattern was strongly influenced by the gas flow on the liquid surface. This work

  4. Modes of Homogeneous Barrier Discharge at Atmospheric Pressure in Helium

    Institute of Scientific and Technical Information of China (English)

    WANG Yan-Hui; WANG De-Zhen

    2004-01-01

    @@ The discharge modes of a homogeneous barrier discharge at atmospheric pressure in helium are investigated with a one-dimensional fluid model It is found that, either in single peak discharge or in multipeak discharge, there are two discharge modes: glow and Townsend modes. The structure and features of the two modes are compared.The conditions forming the two modes are discussed.

  5. Spectrochemical analysis with DC glow discharges at atmospheric pressure

    Energy Technology Data Exchange (ETDEWEB)

    Broekaert, J.A.C., E-mail: jose.broekaert@chemie.uni-hamburg.de; Reinsberg, K.-G.

    2015-04-01

    A review on recent work and developments in dc glow discharges at atmospheric pressure when used as radiation sources for optical atomic spectrometry and mass spectrometry is given. Diagnostics and analytical features of dc glow discharges at atmospheric pressure between conductive solid electrodes as well as with a liquid as the cathode and flowing afterglow sources were described. Possibilities for the introduction of analytes in solutions, in the gaseous state and direct solids sampling were discussed. - Highlights: • The state-of-the-art and trends of development of dc glow discharges at atmospheric pressure for spectrochemical analysis are discussed.

  6. Thermally induced atmospheric pressure gas discharges using pyroelectric crystals

    Science.gov (United States)

    Johnson, Michael J.; Linczer, John; Go, David B.

    2014-12-01

    Using a heated pyroelectric crystal, an atmospheric pressure gas discharge was generated through the input of heat. When put through a change in temperature, the polarization of a pyroelectric can change significantly, creating a substantial electric potential at its surface. When configured with a grounded sharp counter electrode, a large inhomogeneous electric field forms in the interstitial gas to initiate a corona-like discharge. Under constant heating conditions, gaseous ions drifting to the pyroelectric accumulate and screen the electric field, extinguishing the discharge. By thermally cycling the pyroelectric, negative and positive discharges are generated during heating and cooling, respectively, with peak currents on the order of 80 nA. Time-integrated visualization confirmed the generation of both a corona-like discharge and a surface discharge on the pyroelectric. Parametric studies identified that thermal cycling conditions significantly influence discharge formation for this new atmospheric pressure discharge approach.

  7. Simulation of low temperature atmospheric pressure corona discharge in helium

    Science.gov (United States)

    Bekasov, Vladimir; Kirsanov, Gennady; Eliseev, Stepan; Kudryavtsev, Anatoly; Sisoev, Sergey

    2015-11-01

    The main objective of this work was to construct a numerical model of corona discharge in helium at atmospheric pressure. The calculation was based on the two-dimensional hybrid model. Two different plasma-chemical models were considered. Models were built for RF corona and negative DC corona discharge. The system of equations is solved by the finite element method in the COMSOL Multiphysics. Main parameters of the discharge (the density of charged and excited particles, the electron temperature) and their dependence on the input parameters of the model (geometry, electrode voltage, power) were calculated. The calculations showed that the shape of the electron distribution near the electrode depends on the discharge power. The neutral gas heating data obtained will allow predicting the temperature of the gases at the designing of atmospheric pressure helium plasma sources.

  8. Simulation of nonstationary phenomena in atmospheric-pressure glow discharge

    Science.gov (United States)

    Korolev, Yu. D.; Frants, O. B.; Nekhoroshev, V. O.; Suslov, A. I.; Kas'yanov, V. S.; Shemyakin, I. A.; Bolotov, A. V.

    2016-06-01

    Nonstationary processes in atmospheric-pressure glow discharge manifest themselves in spontaneous transitions from the normal glow discharge into a spark. In the experiments, both so-called completed transitions in which a highly conductive constricted channel arises and incomplete transitions accompanied by the formation of a diffuse channel are observed. A model of the positive column of a discharge in air is elaborated that allows one to interpret specific features of the discharge both in the stationary stage and during its transition into a spark and makes it possible to calculate the characteristic oscillatory current waveforms for completed transitions into a spark and aperiodic ones for incomplete transitions. The calculated parameters of the positive column in the glow discharge mode agree well with experiment. Data on the densities of the most abundant species generated in the discharge (such as atomic oxygen, metastable nitrogen molecules, ozone, nitrogen oxides, and negative oxygen ions) are presented.

  9. Discharge Characteristics in Atmospheric Pressure Glow Surface Discharge in Helium Gas

    Institute of Scientific and Technical Information of China (English)

    LI Xue-Chen; WANG Long

    2005-01-01

    @@ Atmospheric pressure glow discharge is observed for the first time in a surface discharge generator in flowing helium. Electrical and optical methods are used to measure the characteristics of atmospheric pressure glow discharge for different voltages. The results show that discharge current waveforms are asymmetric for the different polarities of the applied voltage. A continuous discharge profile with a width of several microseconds appears for per half cycle of the applied voltage when the voltage is increased to a certain value. The short-pulsed discharge and the continuous current would result from the Townsend breakdown and glow discharge mechanisms respectively. The properties of surface discharge in stagnant helium are completely different from that in flowing helium.

  10. Surface modification of polycarbonate in homogeneous atmospheric pressure discharge

    Energy Technology Data Exchange (ETDEWEB)

    SIra, M; Trunec, D; St' ahel, P; BursIkova, V; Navratil, Z [Department of Physical Electronics, Faculty of Science, Masaryk University, Kotlarska 2, 611 37 Brno (Czech Republic)

    2008-01-07

    A homogeneous atmospheric pressure dielectric barrier discharge was used for the surface modification of polycarbonate (PC). The discharge was generated between two planar metal electrodes, the top electrode was covered by glass and the bottom electrode was covered by a polymer sample. The discharge burned in pure nitrogen or in a mixture of nitrogen and hydrogen. The surface properties of both treated and untreated polymers were characterized by atomic force microscopy, surface free energy (SFE) measurements and x-ray photoelectron spectroscopy. The influence of the treatment time and power input to the discharge on the surface properties of polymers was studied. The ageing of treated samples was also investigated. The treatment of polymers in the homogeneous atmospheric pressure discharge was homogeneous and the polymer surfaces showed a smaller degree of roughness in comparison with the polymer surfaces treated in a filamentary discharge. The SFE of the treated PC obtained at optimum conditions was 53 mJ m{sup -2} and the corresponding contact angle of water was 38{sup 0}. The maximum decrease in the SFE during ageing was about 13%. The analysis of the chemical composition showed an increase in the nitrogen concentration in the surface layer, but almost a zero increase in the oxygen concentration. This result was discussed concerning the measured values of the SFE measurement.

  11. Role of secondary emission on discharge dynamics in an atmospheric pressure dielectric barrier discharge

    Energy Technology Data Exchange (ETDEWEB)

    Tay, W. H.; Kausik, S. S.; Yap, S. L.; Wong, C. S., E-mail: cswong@um.edu.my [Plasma Technology Research Centre, Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia)

    2014-04-15

    The discharge dynamics in an atmospheric pressure dielectric barrier discharge (DBD) is studied in a DBD reactor consisting of a pair of stainless steel parallel plate electrodes. The DBD discharge has been generated by a 50 Hz ac high voltage power source. The high-speed intensified charge coupled device camera is used to capture the images of filaments occurring in the discharge gap. It is observed that frequent synchronous breakdown of micro discharges occurs across the discharge gap in the case of negative current pulse. The experimental results reveal that secondary emissions from the dielectric surface play a key role in the synchronous breakdown of plasma filaments.

  12. Parametric study of radiofrequency helium discharge under atmospheric pressure

    Indian Academy of Sciences (India)

    SAFDAR HUSSAIN; HAFIZ IMRAN AHMAD QAZI; SHANAWER NIAZ; MANZOOR AHMAD BADAR

    2016-12-01

    The parameters of radio frequency helium discharge under atmospheric pressure were studied by electrical and optical measurements using high voltage probe, current probe and optical emission spectroscopy. Two discharge modes $\\alpha$ and $\\gamma$ were observed within certain limits. During $\\alpha$ to $\\gamma$ mode transition, a decrease in voltage (280–168 V), current (2.05–1.61 A) and phase angle (76$^{\\rm o}-56^{\\rm o}$) occurred. The discharge parameters such as resistance, reactance, sheath thickness, electron density, excitation temperature and gas temperature were assessed by electrical measurements using equivalent circuit model and optical emission spectroscopy. In $\\alpha$ mode, the discharge current increased from 1.17 to 2.05 A, electron density increased from $0.19 \\times 10^{12} {\\rm to} 0.47 \\times 10^{12} {\\rm cm}^{−3}$ while sheath thickness decreased from 0.40 to 0.25 mm. The excitation temperatures in the $\\alpha$ and $\\gamma$ modes were 3266 and 4500 K respectively, evaluated by Boltzmann’s plot method. The estimated gas temperature increased from 335 K in the α mode to 485 K in the γ mode, suggesting that the radio frequency atmospheric pressure helium discharge can be used for surface treatment applications.

  13. Investigation of atmospheric pressure streamer discharges for methane reforming

    Science.gov (United States)

    Pachuilo, M. V.; Stefani, F.; Rosocha, L. A.; Raja, L. L.

    2015-09-01

    Hydrogen has several valuable uses in transportation: it can lower the coefficient of variation under lean burn conditions in internal combustion engines, and it is essential for the operation of fuel cells. Currently hydrogen can only be produced efficiently by reducing fossil fuels in large facilities. However, on-board production is desirable to reduce the infrastructure associated with storing and distributing hydrogen. Plasma dry reforming processes are viable candidates for onboard production. Our current work investigates the fundamental behavior of a single streamer discharge in methane. The electron temperature, and active species generation are determined through time resolved spectroscopy. This work will hopefully accelerate the development of non-thermal plasma based devices that include: dielectric barrier discharges, pulsed corona discharges, and other atmospheric-pressure plasma devices.

  14. Removal of paper microbial contamination by atmospheric pressure DBD discharge

    Science.gov (United States)

    Vrajova, J.; Chalupova, L.; Novotny, O.; Cech, J.; Krcma, F.; Stahel, P.

    2009-08-01

    In this paper the removal of the microbial contamination from paper material using the plasma treatment at atmospheric pressure is investigated. The Aspergillus niger has been chosen as a bio-indicator enabling to evaluate the effect of plasma assisted microbial inactivation. Dielectric barrier discharge (DBD) operated at atmospheric pressure was used for the paper sterilization. The working gas (nitrogen, argon and helium), plasma exposition time and the plasma power density were varied in order to see the effect of the plasma treatment on the fungi removal. After the treatment, the microbial abatement was evaluated by the standard plate count method. This proved a positive effect of the DBD plasma treatment on fungi removal. Morphological and colorimetric changes of paper substrate after plasma treatment were also investigated.

  15. Charging of aerosol and nucleation in atmospheric pressure electrical discharges

    Science.gov (United States)

    Borra, J. P.

    2008-12-01

    The paper focuses on applications of atmospheric pressure plasmas (dc corona, streamer, spark and ac dielectric barrier discharges (DBDs)) in aerosol processes for materials and environment. Since aerosol kinematics depends mainly on electric forces acting on charged particles, the two mechanisms of aerosol charging by the collection of ions are presented in corona, post-corona and DBDs. In such defined charging conditions, field and diffusion charging laws are depicted, with respect to applications of controlled kinematics of charged aerosol. Then key parameters controlling the formation by nucleation and the growth by coagulation of particles in plasmas are presented. Sources of vapor leading to nucleated nanoparticles are depicted in atmospheric pressure electrical discharges: (i) when filamentary dc streamer and spark as well as ac-DBDs interact with metal or dielectric surfaces and (ii) when discharges induce reactions with gaseous precursors in volume. In both cases, condensable gaseous species are produced, leading to nano-sized particles by physical and chemical routes of nucleation. The composition, size and structure of primary nanoparticles as well as the final size of agglomerates are related to plasma parameters (energy, number per unit surface and time and thermal gradients around each filament as well as the transit time).

  16. Diagnostics of Atmospheric Pressure Surface Discharge Plasmas in Argon

    Institute of Scientific and Technical Information of China (English)

    张锐; 詹如娟; 温晓辉

    2003-01-01

    Atmospheric pressure surface discharge is shown to have great prospects for a number of industrial applications.To acquire better results in application fields and considering that the study of the basic parameters including electron temperature and electron density is desirable,we develop an equivalent circuit model and the diagnostic techniques based on optical emission spectroscopy and electrical measurement in our laboratory.The electron temperature has been determined to be about 0.7eV by a Fermi-Dirac model.The electron density has been calculated to be near 1010 cm-3 from a time resolved electrical measurement(Ohmic heating method).

  17. Atmospheric pressure dielectric barrier discharges for sterilization and surface treatment

    Energy Technology Data Exchange (ETDEWEB)

    Chin, O. H.; Lai, C. K.; Choo, C. Y.; Wong, C. S.; Nor, R. M. [Plasma Technology Research Centre, Physics Department, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia); Thong, K. L. [Microbiology Division, Institute of Biological Sciences, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia)

    2015-04-24

    Atmospheric pressure non-thermal dielectric barrier discharges can be generated in different configurations for different applications. For sterilization, a parallel-plate electrode configuration with glass dielectric that discharges in air was used. Gram-negative bacteria (Escherichia coli and Salmonella enteritidis) and Gram-positive bacteria (Bacillus cereus) were successfully inactivated using sinusoidal high voltage of ∼15 kVp-p at 8.5 kHz. In the surface treatment, a hemisphere and disc electrode arrangement that allowed a plasma jet to be extruded under controlled nitrogen gas flow (at 9.2 kHz, 20 kVp-p) was applied to enhance the wettability of PET (Mylar) film.

  18. FAST TRACK COMMUNICATION: Small surface wave discharge at atmospheric pressure

    Science.gov (United States)

    Kiss'ovski, Zh; Kolev, M.; Ivanov, A.; Lishev, St.; Koleva, I.

    2009-09-01

    A small surface wave driven source produces plasma at atmospheric pressure. Microwave power at frequency 2.45 GHz is coupled with the source and a discharge is ignited at power levels below 10 W. The coaxial exciter of the surface waves has a length of 10 mm because its dielectric is a high permittivity discharge tube. The plasma source operates as a plasma jet in the case of plasma columns longer than the tube length. The source maintains stable plasma columns over a wide range of neutral gas flow and applied power in continuous and pulse regimes. An additional advantage of this source is the discharge self-ignition. An electron temperature of Te ~ 1.9 eV and a density of ne ~ 3.9 × 1014 cm-3 are estimated by the probe diagnostics method. The emission spectra in the wavelength range 200-1000 nm under different experimental conditions are analysed and they prove the applicability of the source for analytical spectroscopy. The dependences of column length, reflected power and plasma parameters on the gas flow and the input power are discussed.

  19. Sterilization of Turmeric by Atmospheric Pressure Dielectric Barrier Discharge Plasma

    Science.gov (United States)

    Setareh, Salarieh; Davoud, Dorranian

    2013-11-01

    In this study atmospheric pressure dielectric barrier discharge (DBD) plasma has been employed for sterilizing dry turmeric powders. A 6 kV, 6 kHz frequency generator was used to generate plasma with Ar, Ar/O2, He, and He/O2 gases between the 5 mm gap of two quartz covered electrodes. The complete sterilization time of samples due to plasma treatment was measured. The most important contaminant of turmeric is bacillus subtilis. The results show that the shortest sterilization time of 15 min is achieved by exposing the samples to Ar/O2 plasma. Survival curves of samples are exponential functions of time and the addition of oxygen to plasma leads to a significant increase of the absolute value of time constant of the curves. Magnitudes of protein and DNA in treated samples were increased to a similar value for all samples. Taste, color, and solubility of samples were not changed after the plasma treatment.

  20. Atmospheric pressure arc discharge with ablating graphite anode

    Energy Technology Data Exchange (ETDEWEB)

    Nemchinsky, V. A. [Keiser University, Fort Lauderdale Campus, FL, 33309, USA; Raitses, Y. [Princeton Plasma Physics Lab. (PPPL), Princeton, NJ (United States)

    2015-05-18

    The anodic carbon arc discharge is used to produce carbon nanoparticles. Recent experiments with the carbon arc at atmospheric pressure helium demonstrated the enhanced ablation rate for narrow graphite anodes resulting in high deposition rates of carbonaceous products on the copper cathode (Fetterman et al 2008 Carbon 46 1322–6). The proposed model explains these results with interconnected steady-state models of the cathode and the anode processes. When considering cathode functioning, the model predicts circulation of the particles in the near-cathode region: evaporation of the cathode material, ionization of evaporated atoms and molecules in the near-cathode plasma, return of the resulting ions to the cathode, surface recombination of ions and electrons followed again by cathode evaporation etc. In the case of the low anode ablation rate, the ion acceleration in the cathode sheath provides the major cathode heating mechanism. In the case of an intensive anode ablation, an additional cathode heating is due to latent fusion heat of the atomic species evaporated from the anode and depositing at the cathode. Using the experimental arc voltage as the only input discharge parameter, the model allows us to calculate the anode ablation rate. A comparison of the results of calculations with the available experimental data shows reasonable agreement.

  1. Spatiotemporally resolved characteristics of a gliding arc discharge in a turbulent air flow at atmospheric pressure

    DEFF Research Database (Denmark)

    Zhu, Jiajian; Gao, Jinlong; Ehn, Andreas

    2017-01-01

    A gliding arc discharge was generated in a turbulent air flow at atmospheric pressure driven by a 35 kHz alternating current (AC) electric power. The spatiotemporally resolved characteristics of the gliding arc discharge, including glow-type discharges, spark-type discharges, short-cutting events...

  2. Flow Reactor Studies with Nanosecond Pulsed Discharges at Atmospheric Pressure and Higher

    Science.gov (United States)

    2013-10-01

    Image of Discharge Reactor with Viewport Inlet Cap • Modular plasma discharge reactor can be interchanged with redesigned pressure shell to perform...Flow Reactor Studies with Nanosecond Pulsed Discharges at Atmospheric Pressure and Higher Nicholas Tsolas, Kuni Togai and Richard Yetter...Department of Mechanical and Nuclear Engineering The Pennsylvania State University University Park, PA, 16801 Fourth Annual Review Meeting of the

  3. Simulation of transition from Townsend mode to glow discharge mode in a helium dielectric barrier discharge at atmospheric pressure

    Institute of Scientific and Technical Information of China (English)

    Li Xue-Chen; Niu Dong-Ying; Xu Long-Fei; Jia Peng-Ying; Chang Yuan-Yuan

    2012-01-01

    The dielectric barrier discharge characteristics in helium at atmospheric pressure are simulated based on a one-dimensional fluid model.Under some discharge conditions,the results show that one discharge pulse per half voltage cycle usually appears when the amplitude of external voltage is low,while a glow-like discharge occurs at high voltage.For the one discharge pulse per half voltage cycle,the maximum of electron density appears near the anode at the beginning of the discharge,which corresponds to a Townsend discharge mode.The maxima of the electron density and the intensity of electric field appear in the vicinity of the cathode when the discharge current increases to some extent,which indicates the formation of a cathode-fall region.Therefore,the discharge has a transition from the Townsend mode to the glow discharge mode during one discharge pulse,which is consistent with previous experimental results.

  4. Research progress in the study of atmospheric pressure glow barrier discharge

    Institute of Scientific and Technical Information of China (English)

    LI Xuechen; DONG Lifang; JIA Pengying

    2007-01-01

    Atmospheric pressure glow barrier discharge (APGBD) can operate at high pressure, and so vacuum device is not necessary. Furthermore, the produced plasma by APGBD has moderate electron temperature and density besides good uniformity. Therefore,APGBD has extensive potential applications in industry and has been becoming a hot issue in the research of low temperature plasma. In this paper, the main problems in the study of atmospheric pressure glow discharge generated by dielectric barrier discharge, including the experimental setup, judging criterion, discharging conditions, physical mechanisms, and parameter diagnoses, are discussed, and further research prospects of APGBD are proposed.

  5. Statistical modelling of discharge behavior of atmospheric pressure dielectric barrier discharge

    Energy Technology Data Exchange (ETDEWEB)

    Tay, W. H.; Kausik, S. S.; Wong, C. S., E-mail: cswong@um.edu.my; Yap, S. L.; Muniandy, S. V. [Plasma Technology Research Centre, Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia)

    2014-11-15

    In this work, stochastic behavior of atmospheric pressure dielectric barrier discharge (DBD) has been investigated. The experiment is performed in a DBD reactor consisting of a pair of stainless steel parallel plate electrodes powered by a 50 Hz ac high voltage source. Current pulse amplitude distributions for different space gaps and the time separation between consecutive current pulses are studied. A probability distribution function is proposed to predict the experimental distribution function for the current pulse amplitudes and the occurrence of the transition regime of the pulse distribution. Breakdown voltage at different positions on the dielectric surface is suggested to be stochastic in nature. The simulated results based on the proposed distribution function agreed well with the experimental results and able to predict the regime of transition voltage. This model would be useful for the understanding of stochastic behaviors of DBD and the design of DBD device for effective operation and applications.

  6. Sustained diffusive alternating current gliding arc discharge in atmospheric pressure air

    DEFF Research Database (Denmark)

    Zhu, Jiajian; Gao, Jinlong; Li, Zhongshan

    2014-01-01

    Rapid transition from glow discharge to thermal arc has been a common problem in generating stable high-power non-thermal plasmas especially at ambient conditions. A sustained diffusive gliding arc discharge was generated in a large volume in atmospheric pressure air, driven by an alternating...

  7. Plasma chemistry in an atmospheric pressure Ar/NH3 dielectric barrier discharge

    DEFF Research Database (Denmark)

    Fateev, A.; Leipold, F.; Kusano, Y.

    2005-01-01

    An atmospheric pressure dielectric barrier discharge (DBD) in Ar/NH3 (0.1 - 10%) mixtures with a parallel plate electrode geometry was studied. The plasma was investigated by emission and absorption spectroscopy in the UV spectral range. Discharge current and voltage were measured as well. UV...... of an atmospheric pressure Ar/NH3 DBD are H-2, N-2 and N2H4. The hydrazine (N2H4) concentration in the plasma and in the exhaust gases at various ammonia concentrations and different discharge powers was measured. Thermal N2H4 decomposition into NH2 radicals may be used for NOx reduction processes....

  8. Characterization of a Dielectric Barrier Plasma Gun Discharging at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    ZHANG Guang-Qiu; GE Yuan-Jing; ZHANG Yue-Fei; CHEN Guang-Liang

    2004-01-01

    @@ We develop a plasma gun based on dielectric barrier discharge and working at atmospheric pressure. A theoretical model to predict the gun discharge voltage is built, which is in agreement with the experimental results. After investigating the characterization of discharging gun and utilizing it for polymerization, we find that the gun can be used as a source to generate a stable uniform plasma for different plasma-processing technologies.

  9. Modeling of asymmetric pulsed phenomena in dielectric-barrier atmospheric-pressure glow discharges

    Energy Technology Data Exchange (ETDEWEB)

    Ha Yan [College of Mathematics and Computer Science, Hebei University, Baoding 071002 (China); Wang Huijuan [School of Mathematics and Physics, North China Electric Power University, Baoding 071003 (China); Wang Xiaofei [College of Physics Science and Technology, Hebei University, Baoding 071002 (China)

    2012-01-15

    Asymmetric current pulses in dielectric-barrier atmospheric-pressure glow discharges are investigated by a self-consistent, one-dimensional fluid model. It is found that the glow mode and Townsend mode can coexist in the asymmetric discharge even though the gas gap is rather large. The reason for this phenomenon is that the residual space charge plays the role of anode and reduces the gap width, resulting in the formation of a Townsend discharge.

  10. Formation of an Apokampic Discharge Under Atmospheric Pressure Conditions

    Science.gov (United States)

    Skakun, V. S.; Panarin, V. A.; Pechenitsyn, D. S.; Sosnin, É. A.; Tarasenko, V. F.

    2016-09-01

    A new phenomenon is observed in a spark discharge developing under normal conditions in air in a discharge circuit with a capacitive decoupling. It consists in the current channel bending becoming a source of a 4-6 cm long plasma jet directed across the channel. The phenomenon is termed an apokampic discharge or an apokamp. Its emission spectrum contains the bands of electron-vibration transitions from the second positive group of molecular nitrogen. The conditions of formation of an apokamp are experimentally determined. A conclusion is drawn that in order construct a physical model of an apokamp, one has to take into account: 1) the presence of a local gas overheating in the site of the current channel bending, 2) the similarity of the current and voltage time dependences in the corona discharge and in the current channel (becoming a source of an apokamp), and 3) the length of the apokamp plasma jet.

  11. Specific interaction between negative atmospheric ions and organic compounds in atmospheric pressure corona discharge ionization mass spectrometry.

    Science.gov (United States)

    Sekimoto, Kanako; Sakai, Mami; Takayama, Mitsuo

    2012-06-01

    The interaction between negative atmospheric ions and various types of organic compounds were investigated using atmospheric pressure corona discharge ionization (APCDI) mass spectrometry. Atmospheric negative ions such as O(2)(-), HCO(3)(-), COO(-)(COOH), NO(2)(-), NO(3)(-), and NO(3)(-)(HNO(3)) having different proton affinities served as the reactant ions for analyte ionization in APCDI in negative-ion mode. The individual atmospheric ions specifically ionized aliphatic and aromatic compounds with various functional groups as atmospheric ion adducts and deprotonated analytes. The formation of the atmospheric ion adducts under certain discharge conditions is most likely attributable to the affinity between the analyte and atmospheric ion and the concentration of the atmospheric ion produced under these conditions. The deprotonated analytes, in contrast, were generated from the adducts of the atmospheric ions with higher proton affinity attributable to efficient proton abstraction from the analyte by the atmospheric ion.

  12. An Experimental Study on Atmospheric Pressure Glow Discharge in Different Gases

    Institute of Scientific and Technical Information of China (English)

    刘鹏; 詹如娟; 等

    2002-01-01

    Usually,the electrical breakdown of dielectric barrier discharge(DBD) at atmospheric pressure leads to a filamentary non-homogeneous discharge,However,it is also possible to obtain a diffuse DBD in homogeneous form,called atmospheric pressure glow discharge(APGD).We obtained a uniform APGD in helium and in the mixture of argon with alcohol,and studied the electrical characteristics of helium APGD.It if found that the relationship between discharge current and source frequency is different depending on the difference in gas gap when the applied voltage is kept constant.The discharge current shows an increasing trend with the increased frequency when gas gap is 0.8cm ,but the discharge current tends to decrease with the increased frequency when the gas gap increases.The discharge current always increases with the increased applied voltage when the source frequency is kept constant.We also observed a glow-like discharge in nitrogen at atmospheric pressure.

  13. Characteristics of radio-frequency atmospheric pressure dielectric-barrier discharge with dielectric electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Hussain, S., E-mail: shussain@uos.edu.pk, E-mail: shussainuos@yahoo.com; Qazi, H. I. A.; Badar, M. A. [Department of Physics, University of Sargodha, 40100 Sargodha (Pakistan)

    2014-03-15

    An experimental investigation to characterize the properties and highlight the benefits of atmospheric pressure radio-frequency dielectric-barrier discharge (rf DBD) with dielectric electrodes fabricated by anodizing aluminium substrate is presented. The current-voltage characteristics and millisecond images are used to distinguish the α and γ modes. This atmospheric rf DBD is observed to retain the discharge volume without constriction in γ mode. Optical emission spectroscopy demonstrates that the large discharge current leads to more abundant reactive species in this plasma source.

  14. Means of introducing an analyte into liquid sampling atmospheric pressure glow discharge

    Energy Technology Data Exchange (ETDEWEB)

    Marcus, R. Kenneth; Quarles, Jr., Charles Derrick; Russo, Richard E.; Koppenaal, David W.; Barinaga, Charles J.; Carado, Anthony J.

    2017-01-03

    A liquid sampling, atmospheric pressure, glow discharge (LS-APGD) device as well as systems that incorporate the device and methods for using the device and systems are described. The LS-APGD includes a hollow capillary for delivering an electrolyte solution to a glow discharge space. The device also includes a counter electrode in the form of a second hollow capillary that can deliver the analyte into the glow discharge space. A voltage across the electrolyte solution and the counter electrode creates the microplasma within the glow discharge space that interacts with the analyte to move it to a higher energy state (vaporization, excitation, and/or ionization of the analyte).

  15. A study of the glow discharge characteristics of contact electrodes at atmospheric pressure in air

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Wenzheng, E-mail: wzhliu@bjtu.edu.cn; Sun, Guangliang, E-mail: 11121659@bjtu.edu.cn; Li, Chuanhui; Zhang, Rongrong [School of Electrical Engineering, Beijing Jiaotong University, Beijing 100044 (China)

    2014-04-15

    Electric field distributions and discharge properties of rod-rod contact electrodes were studied under the condition of DBD for the steady generation of atmospheric pressure glow discharge plasma (APGD) in air. We found that under the effect of the initial electrons generated in a nanometer-scale gap, the rod-rod cross-contact electrodes yielded APGD plasma in air. Regarding the rod-rod cross-contact electrodes, increasing the working voltage expanded the strong electric field area of the gas gap so that both discharge area and discharge power increased, and the increase in the number of contact points kept the initial discharge voltage unchanged and caused an increase in the plasma discharge area and discharge power. A mesh-like structure of cross-contact electrodes was designed and used to generate more APGD plasma, suggesting high applicability.

  16. Discharge processes and an electrical model of atmospheric pressure plasma jets in argon

    Science.gov (United States)

    Fang, Zhi; Shao, Tao; Yang, Jing; Zhang, Cheng

    2016-01-01

    In this paper, an atmospheric pressure plasma discharge in argon was generated using a needle-to-ring electrode configuration driven by a sinusoidal excitation voltage. The electric discharge processes and discharge characteristics were investigated by inspecting the voltage-current waveforms, Lissajous curves and lighting emission images. The change in discharge mode with applied voltage amplitude was studied and characterised, and three modes of corona discharge, dielectric barrier discharge (DBD) and jet discharge were identified, which appeared in turn with increasing applied voltage and can be distinguished clearly from the measured voltage-current waveforms, light-emission images and the changing gradient of discharge power with applied voltage. Based on the experimental results and discharge mechanism analysis, an equivalent electrical model and the corresponding equivalent circuit for characterising the whole discharge processes accurately was proposed, and the three discharge stages were characterised separately. A voltage-controlled current source (VCCS) associated with a resistance and a capacitance were used to represent the DBD stage, and the plasma plume and corona discharge were modelled by a variable capacitor in series with a variable resistor. Other factors that can influence the discharge, such as lead and stray capacitance values of the circuit, were also considered in the proposed model. Contribution to the Topical Issue "Recent Breakthroughs in Microplasma Science and Technology", edited by Kurt Becker, Jose Lopez, David Staack, Klaus-Dieter Weltmann and Wei Dong Zhu.

  17. Surface-initiated graft polymerization on multiwalled carbon nanotubes pretreated by corona discharge at atmospheric pressure.

    Science.gov (United States)

    Xu, Lihua; Fang, Zhengping; Song, Ping'an; Peng, Mao

    2010-03-01

    Surface-initiated graft polymerization on multi-walled carbon nanotubes pretreated with a corona discharge at atmospheric pressure was explored. The mechanism of the corona-discharge-induced graft polymerization is discussed. The results indicate that MWCNTs were encapsulated by poly(glycidyl methacrylate) (PGMA), demonstrating the formation of PGMA-grafted MWCNTs (PGMA-g-MWCNTs), with a grafting ratio of about 22 wt%. The solubility of PGMA-g-MWCNTs in ethanol was dramatically improved compared to pristine MWCNTs, which could contribute to fabricating high-performance polymer/MWCNTs nanocomposites in the future. Compared with most plasma processes, which operate at low pressures, corona discharge has the merit of working at atmospheric pressure.

  18. Concentric-ring structures in an atmospheric pressure helium dielectric barrier discharge

    Institute of Scientific and Technical Information of China (English)

    Shang Wan-Li; Zhang Yuan-Tao; Wang De-Zhen; Sang Chao-Feng; Jiang shao-En; Yang Jia-Min; Liu shen-Ye; M.G.Kong

    2011-01-01

    This paper performs a numerical simulation of concentric-ring discharge structures within the scope of a two-dimensional diffusion-drift model at atmospheric pressure between two parallel circular electrodes covered with thin dielectric layers. With a relative high frequency the discharge structures present different appearances of ring structures within different radii in time due to the evolvement of the filaments. The spontaneous electron density distributions help understanding the formation and development of seff-organized discharge structures. During a cycle the electron avalanches are triggered by the electric field strengthened by the feeding voltage and the residual charged particles on the barrier surface deposited in the previous discharges. The accumulation of charges is shown to play a dominant role in the generation and annihilation of the discharge structures. Besides, the rings split and unify to bring and annihilate rings which form a new discharge structure.

  19. Preliminary Investigation of a Dielectric Barrier Discharge Lamp in Open Air at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    LIU Feng; WANG Wei-Wei; CHANG Xi-Jiang; LIANG Rong-Qing

    2011-01-01

    @@ A dielectric barrier discharge (DBD) lamp is investigated by using sinusoidal power with a 10 kHz frequency in open air at atmospheric pressure.With increasing applied voltages, the different discharge phenomena appear.At relatively low voltages, the discharge states are general stochastic filamentary discharges with weak light.However, at relatively high voltages, the walls of quartz tubes are heated sharply by plasma, and then the dazzling light is emitted very quickly to form the DBD Lamp, corresponding to the low maintaining voltage that is lower than the ignited voltage.The discharge state or mode of the DBD lamp that corresponds to the glow discharge is deduced according to the wave form of the circuit current, which is evidently different from the filamentary discharges.Under these conditions, the spectrum of the DBD lamp is continuous in the range 400-932nm, which is scanned in the range 300-932nm.It is also shown that there is another discharge state or mode that is different from the traditional filamentary discharges.Therefore, it is concluded that the discharge state or mode of the DBD lamp is a glow discharge.

  20. Surface modification of polyester film by glow discharge tunnel at atmospheric pressure

    Institute of Scientific and Technical Information of China (English)

    XU Xiang-yu; WANG Shou-guo; YE Tian-chun; JING Guang-yin; YU Da-peng

    2004-01-01

    A large-area improved dielectric barrier glow discharge tunnel has been developed for modifying the surface of polyester film at atmospheric pressure with argon and oxygen gas mixtures. The electrical properties of the glow discharge tunnel were studied by simultaneous measurement of the voltage and current. In addition, the effect of the glow discharge tunnel treatment on the surface of polyester film were studied. The resultant modifications of the surface properties of the treated samples were investigated through scanning probe microscopy and contact angle measurement.

  1. Simulation of radio-frequency atmospheric pressure glow discharge in γ mode

    Institute of Scientific and Technical Information of China (English)

    Shang Wan-Li; Wang De-Zhen; Michael G. Kong

    2007-01-01

    The existence of two different discharge modes has been verified in an rf (radio-frequency) atmospheric pressure glow discharge (APGD) by Shi [J. Appl. Phys. 97, 023306 (2005)]. In the first mode, referred to as α mode, the discharge current density is relatively low and the bulk plasma electrons acquire the energy due to the sheath expansion.In the second mode, termed γ mode, the discharge current density is relatively high, the secondary electrons emitted by cathode under ion bombardment in the cathode sheath region play an important role in sustaining the discharge. In this paper, a one-dimensional self-consistent fluid model for rf APGDs is used to simulate the discharge mechanisms in the γmode in helium discharge between two parallel metallic planar electrodes. The results show that as the applied voltage increases, the discharge current becomes greater and the plasma density correspondingly increases, consequentially the discharge transits from the c mode into the γ mode. The high collisionality of the APGD plasma results in significant drop of discharge potential across the sheath region, and the electron Joule heating and the electron collisional energy loss reach their maxima in the region. The validity of the simulation is checked with the available experimental and numerical data.

  2. Characteristics of a Normal Glow Discharge Excited by DC Voltage in Atmospheric Pressure Air

    Science.gov (United States)

    Li, Xuechen; Zhao, Huanhuan; Jia, Pengying

    2013-11-01

    Atmospheric pressure glow discharges were generated in an air gap between a needle cathode and a water anode. Through changing the ballast resistor and gas gap width between the electrodes, it has been found that the discharges are in normal glow regime judged from the current-voltage characteristics and visualization of the discharges. Results indicate that the diameter of the positive column increases with increasing discharge current or increasing gap width. Optical emission spectroscopy is used to calculate the electron temperature and vibrational temperature. Both the electron temperature and the vibrational temperature increases with increasing discharge current or increasing gap width. Spatially resolved measurements show that the maxima of electron temperature and vibrational temperature appeared in the vicinity of the needle cathode.

  3. High frequency glow discharges at atmospheric pressure with micro-structured electrode arrays

    Science.gov (United States)

    Baars-Hibbe, L.; Sichler, P.; Schrader, C.; Lucas, N.; Gericke, K.-H.; Büttgenbach, S.

    2005-02-01

    Micro-structured electrode (MSE) arrays allow the generation of large-area uniform glow discharges over a wide pressure range up to atmospheric pressure. The electrode widths, thicknesses and distances in the micrometre range are realized by means of modern micro-machining and galvanic techniques. The electrode distance, the gap width d, is small enough to generate sufficiently high electric field strengths to ignite gas discharges by applying only moderate radio frequency (RF, 13.56 MHz) voltages (80-390 V in Ne, He, Ar, N2 and air). The non-thermal plasma system is characterized by a special probe measuring the electric parameters. We tested MSE arrays with d = 70, 25 and 15 µm. The MSE driven plasmas show a different behaviour from conventional RF discharge plasmas. Due to the very small electrode gap width we can describe the behaviour of the charged particles in the RF field of our system with the dc Townsend breakdown theory, depending on the pressure range and gas. With decreasing pressure, the gas discharges, especially in Ne and He, are increasingly dominated by field electron emission. With the MSE arrays as plasma sources several applications were developed and successfully tested, e.g. decomposition of waste gases and sterilization of food packaging materials at atmospheric pressure.

  4. Translational, rotational and vibrational temperatures of a gliding arc discharge at atmospheric pressure air

    DEFF Research Database (Denmark)

    Zhu, Jiajian; Gao, Jinlong; Ehn, Andreas

    2014-01-01

    Gliding arc discharges have generally been used to generate non-equilibrium plasma at atmospheric pressure. Temperature distributions of a gliding arc are of great interest both for fundamental plasma research and for practical applications. In the presented studies, translational, rotational...... and vibrational temperatures of a gliding arc generated at atmospheric pressure air are investigated. Translational temperatures (about 1100 K) were measured by laser-induced Rayleigh scattering, and two-dimensional temperature imaging was performed. Rotational and vibrational temperatures (about 3600 K and 6700...

  5. Simulation of the propagation and reignition of atmospheric pressure air discharges behind a dielectric plane obstacle

    Science.gov (United States)

    Pechereau, Francois; Jansky, Jaroslav; Bourdon, Anne

    2012-10-01

    In recent years, experimental studies on flue gas treatment have demonstrated the efficiency of plasma assisted catalysis for the treatment of a wide range of pollutants at a low energetic cost. In plasma reactors, usual catalyst supports are pellets, monoliths or porous media, and then atmospheric pressure discharges have to interact with many obstacles and to propagate in microcavities and pores. As a first step to better understand atmospheric pressure discharge dynamics in these complex geometries, in this work, we have carried out numerical simulations using a 2D-axisymmetric fluid model for a point-to-plane discharge with a dielectric plane obstacle placed in the path of the discharge. First, we have simulated the discharge ignition at the point electrode, its propagation in the gap and its impact and expansion on the dielectric plane. Depending on the applied voltage, the dielectric plane geometry and permittivity, we have identified conditions for the reignition of a second discharge behind the plane obstacle. These conditions will be discussed and compared with recent experimental results on the same configuration.

  6. [Spatial distribution of electrons with high energy in atmospheric pressure glow discharge excited by DC voltage].

    Science.gov (United States)

    Liu, Zhi-qiang; Jia, Peng-ying; Liu, Tie

    2013-09-01

    Atmospheric pressure glow discharge excited by a DC voltage was realized in a 6 mm air gap by using a needle-water electrode discharge device. The atompheric pressure glow discharge has characteristic regions such as a cathode fall, a negative glow, a Faraday dark space, a positive column and an anode glow. The discharge is a normal glow through analyzing its voltage-current curve. The emission intensity of 337.1 nm spectral line from the second positive system of N2 was investigated because it can indicate the electron density with high energy. Results show that the maxima of high energy electrons appears in the vicinity of the needle tip, and it almost remains constant at other locations. The density of high energy electrons decreases with increasing the voltage. Similarly, it decreases with increasing the value of the ballast resistor. Oxygen atom is important for the sterilization and disinfection. The distribution of oxygen atom was also investigated by optical emission spectroscopy. It was found that the oxygen distribution is similar with the distribution of high energy electrons. These results are important for the application of atmospheric pressure glow discharge in environmental protection and biological treatment.

  7. 2D fluid simulations of discharges at atmospheric pressure in reactive gas mixtures

    Science.gov (United States)

    Bourdon, Anne

    2015-09-01

    Since a few years, low-temperature atmospheric pressure discharges have received a considerable interest as they efficiently produce many reactive chemical species at a low energy cost. This potential is of great interest for a wide range of applications as plasma assisted combustion or biomedical applications. Then, in current simulations of atmospheric pressure discharges, there is the need to take into account detailed kinetic schemes. It is interesting to note that in some conditions, the kinetics of the discharge may play a role on the discharge dynamics itself. To illustrate this, we consider the case of the propagation of He-N2 discharges in long capillary tubes, studied for the development of medical devices for endoscopic applications. Simulation results put forward that the discharge dynamics and structure depend on the amount of N2 in the He-N2 mixture. In particular, as the amount of N2 admixture increases, the discharge propagation velocity in the tube increases, reaches a maximum for about 0 . 1 % of N2 and then decreases, in agreement with experiments. For applications as plasma assisted combustion with nanosecond repetitively pulsed discharges, there is the need to handle the very different timescales of the nanosecond discharge with the much longer (micro to millisecond) timescales of combustion processes. This is challenging from a computational point of view. It is also important to better understand the coupling of the plasma induced chemistry and the gas heating. To illustrate this, we present the simulation of the flame ignition in lean mixtures by a nanosecond pulsed discharge between two point electrodes. In particular, among the different discharge regimes of nanosecond repetitively pulsed discharges, a ``spark'' regime has been put forward in the experiments, with an ultra-fast local heating of the gas. For other discharge regimes, the gas heating is much weaker. We have simulated the nanosecond spark regime and have observed shock waves

  8. Spatiotemporally resolved characteristics of a gliding arc discharge in a turbulent air flow at atmospheric pressure

    Science.gov (United States)

    Zhu, Jiajian; Gao, Jinlong; Ehn, Andreas; Aldén, Marcus; Larsson, Anders; Kusano, Yukihiro; Li, Zhongshan

    2017-01-01

    A gliding arc discharge was generated in a turbulent air flow at atmospheric pressure driven by a 35 kHz alternating current (AC) electric power. The spatiotemporally resolved characteristics of the gliding arc discharge, including glow-type discharges, spark-type discharges, short-cutting events and transitions among the different types of discharges, were investigated using simultaneously optical and electrical diagnostics. The glow-type discharge shows sinusoidal-like voltage and current waveforms with a peak current of hundreds of milliamperes. The frequency of the emission intensity variation of the glow-type discharge is the same as that of the electronic power dissipated in the plasma column. The glow-type discharge can transfer into a spark discharge characterized by a sharp peak current of several amperes and a sudden increase of the brightness in the plasma column. Transitions can also be found to take place from spark-type discharges to glow-type discharges. Short-cutting events were often observed as the intermediate states formed during the spark-glow transition. Three different types of short-cutting events have been observed to generate new current paths between two plasma channel segments, and between two electrodes, as well as between the channel segment and the electrodes, respectively. The short-cut upper part of the plasma column that was found to have no current passing through can be detected several hundreds of microseconds after the short-cutting event. The voltage recovery rate, the period of AC voltage-driving signal, the flow rates and the rated input powers were found to play an important role in affecting the transitions among the different types of discharges.

  9. Plasma sterilization of polyethylene terephthalate bottles by pulsed corona discharge at atmospheric pressure.

    Science.gov (United States)

    Masaoka, Satoshi

    2007-06-01

    A pulsed power supply was used to generate a corona discharge on a polyethylene terephthalate bottle, to conduct plasma sterilization at atmospheric pressure. Before generating such a discharge, minute quantities of water were attached to the inner surface of the bottle and to the surface of a high voltage (HV) electrode inserted into the bottle. Next, high-voltage pulses of electricity were discharged between electrodes for 6.0s, while rotating the bottle. The resulting spore log reduction values of Bacillus subtilis and Aspergillus niger on the inner surface of the bottle were 5.5 and 6 or higher, respectively, and those on the HV electrode surface were each 6 or higher for both strains. The presence of the by-products gaseous ozone, hydrogen peroxide, and nitric ions resulting from the electrical discharge was confirmed.

  10. Interplay of discharge and gas flow in atmospheric pressure plasma jets

    Science.gov (United States)

    Jiang, Nan; Yang, JingLong; He, Feng; Cao, Zexian

    2011-05-01

    Interplay of discharge and gas flow in the atmospheric pressure plasma jets generated with three different discharge modes [N. Jiang, A. L. Ji, and Z. X. Cao, J. Appl. Phys. 106, 013308 (2009); N. Jiang, A. L. Ji, and Z. X. Cao, J. Appl. Phys. 108, 033302 (2010)] has been investigated by simultaneous photographing of both plasma plumes and gas flows in the ambient, with the former being visualized by using an optical schlieren system. Gas flow gains a forward momentum from discharge except for the case of overflow jets at smaller applied voltages. Larger applied voltage implies an elongated plasma jet only for single-electrode mode; for dielectric barrier discharge jet the plume length maximizes at a properly applied voltage. These findings can help understand the underlying processes, and are useful particularly for the economic operation of tiny helium plasma jets and jet arrays.

  11. Generation of uniform atmospheric pressure argon glow plasma by dielectric barrier discharge

    Indian Academy of Sciences (India)

    Raju Bhai Tyata; Deepak Prasad Subedi; Rajendra Shrestha; Chiow San Wong

    2013-03-01

    In this paper, atmospheric pressure glow discharges (APGD) in argon generated in parallel plate dielectric barrier discharge system is investigated by means of electrical and optical measurements. Using a high voltage (0–20 kV) power supply operating at 10–30 kHz, homogeneous and steady APGD has been observed between the electrodes with gap spacing from 0.5 mm to 2 mm and with a dielectric barrier of thickness 2 mm while argon gas is fed at a controlled flow rate of 11/min. The electron temperature and electron density of the plasma are determined by means of optical emission spectroscopy. Our results show that the electron density of the discharge obtained is of the order of 1016 cm-3 while the electron temperature is estimated to be 0.65 eV. The important result is that electron density determined from the line intensity ratio method and stark broadening method are in very good agreement. The Lissajous figure is used to estimate the energy deposited to the glow discharge. It is found that the energy deposited to the discharge is in the range of 20 to 25 $\\$J with a discharge voltage of 1.85 kV. The energy deposited to the discharge is observed to be higher at smaller gas spacing. The glow discharge plasma is tested to be effective in reducing the hydrophobicity of polyethylene film significantly.

  12. Characteristics of liquid flow induced by atmospheric-pressure DC glow discharge in contact with liquid

    Science.gov (United States)

    Tochikubo, Fumiyoshi; Aoki, Takuya; Shirai, Naoki; Uchida, Satoshi

    2017-04-01

    In this work, we investigated the characteristics of liquid flow induced by atmospheric-pressure dc glow discharge in contact with a liquid. The spatiotemporal development of liquid flow was visualized by the schlieren method, and the temperature distribution was measured using microencapsulated thermotropic liquid crystal particles dispersed in a liquid. We confirmed the appearance of specific downward liquid flow immediately below the dc glow discharge. The characteristics of downward liquid flow were reproduced by fluid simulation considering a downward driving force at the plasma–liquid interface. Our results suggest that the probable driving force for the downward liquid flow was the momentum transfer of charged species at the liquid surface.

  13. Radial Evolution of the Atmospheric Pressure Glow Discharge in Helium Controlled by Dielectric Barrier

    Institute of Scientific and Technical Information of China (English)

    ZHANG Yuan-Tao; WANG De-Zhen; WANG Yan-Hui; LIU Cheng-Sen

    2005-01-01

    @@ The radial evolution of atmospheric pressure glow discharge in helium is presented by numerical simulation. The calculations reveal the mechanism of two current peaks per half cycle. The first breakdown occurs firstly in the central region of the electrode, and then spreads to the edge, while the second breakdown ignites at the periphery firstly, and then propagates toward the discharge central region. The simulations indicate that radial electric fields and radial sheath play an important role in the evolution of the second peak. These results agree fundamentally with the experimental observations.

  14. Energy distribution of runaway electrons generated by a nanosecond discharge in atmospheric-pressure air

    Science.gov (United States)

    Tarasenko, V. F.; Baksht, E. Kh.; Burachenko, A. G.; Kostyrya, I. D.; Lomaev, M. I.; Petin, V. K.; Rybka, D. V.; Shlyakhtun, S. V.

    2008-12-01

    The spectra of an ultrashort avalanche electron beam generated by a nanosecond discharge in atmospheric-pressure air were investigated. The temporal characteristics of the beam current pulses, gap voltage, and discharge current in a gas diode were measured with a time resolution of ˜0.1 ns. A simple technique was developed for recovering electron spectra from the curves of beam attenuation by aluminum foils. The effect of the cathode design, electrode gap length, and generator parameters on the electron spectra were studied using seven setups. It is shown that generation of electrons with anomalously high energies requires the use of cathodes with increased curvature radius.

  15. Characteristics of meter-scale surface electrical discharge propagating along water surface at atmospheric pressure

    Science.gov (United States)

    Hoffer, Petr; Sugiyama, Yuki; Hosseini, S. Hamid R.; Akiyama, Hidenori; Lukes, Petr; Akiyama, Masahiro

    2016-10-01

    This paper reports physical characteristics of water surface discharges. Discharges were produced by metal needle-to-water surface geometry, with the needle electrode driven by 47 kV (FWHM) positive voltage pulses of 2 µs duration. Propagation of discharges along the water surface was confined between glass plates with 2 mm separation. This allowed generation of highly reproducible 634 mm-long plasma filaments. Experiments were performed using different atmospheres: air, N2, and O2, each at atmospheric pressure. Time- and spatially-resolved spectroscopic measurements revealed that early spectra of discharges in air and nitrogen atmospheres were dominated by N2 2nd positive system. N2 radiation disappeared after approx. 150 ns, replaced by emissions from atomic hydrogen. Spectra of discharges in O2 atmosphere were dominated by emissions from atomic oxygen. Time- and spatially-resolved emission spectra were used to determine temperatures in plasma. Atomic hydrogen emissions showed excitation temperature of discharges in air to be about 2  ×  104 K. Electron number densities determined by Stark broadening of the hydrogen H β line reached a maximum value of ~1018 cm-3 just after plasma initiation. Electron number densities and temperatures depended only slightly on distance from needle electrode, indicating formation of high conductivity leader channels. Direct observation of discharges by high speed camera showed that the average leader head propagation speed was 412 km · s-1, which is substantially higher value than that observed in experiments with shorter streamers driven by lower voltages.

  16. Effect of Atmospheric Pressure Glow Discharge Treatment on Polymerization of Acrylic Fabric and Its Printing Behavior

    Directory of Open Access Journals (Sweden)

    D M El-Zeer

    2014-03-01

    Full Text Available Acrylic fibers have been treated by atmospheric pressure glow discharge (APGD plasma in open air to enhance surface antistatic properties. The treated surfaces are investigated by scanning electron microscopy (SEM, Fourier-Transition Infrared Spectroscopy (FTIR and Atomic Force Microscope (AFM. Plasma treatment of acrylic fabric has been found to increase the surface roughness, modify the nature and density of surface functionalities, and drastically improve the wettability and antistatic ability of acrylic fibers.

  17. Ionic wind generation by a wire-cylinder-plate corona discharge in air at atmospheric pressure

    OpenAIRE

    Colas, Dorian,; Ferret, Antoine; Pai, David,; Lacoste, Deanna,; Laux, C.

    2010-01-01

    International audience; A wire-cylinder-plate electrode configuration is presented to generate ionic wind with a dc corona discharge in air at atmospheric pressure. The objective of the work is to maximize the power supplied to the flow in order to increase acceleration while avoiding breakdown. Thus, the proposed experimental setup addresses the problem of decoupling the mechanism of ion generation from that of ion acceleration. Using a wire-plate configuration as a reference, we have focuse...

  18. Self-Organized Filaments in Dielectric Barrier Discharge in Air at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    DONG Li-Fang; LI Xue-Chen; YINZeng-Qian; QIAN Sheng-Fa; OUYANG Ji-Ting; WANG Long

    2001-01-01

    The self-organized filament pattern created by dielectric barrier discharges in air at atmospheric pressure is investigated experimentally. The density and dimension of filament are analysed quantitatively. The experimental results show that the distance between neighbouring filaments decreases with the increased applied voltage or with the decreased width of the gas gap. Also, the diameter of the filament decreases with the increased applied voltages or with the decreased width of the gas gap.

  19. Concentric-Ring Patterns in a Helium Dielectric Barrier Discharge at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    SHANG Wan-Li; WANG De-Zhen

    2007-01-01

    We perform the theoretical simulation of the concentric-ring patterns between two parallel electrodes covered with thin dielectric layers within the scope of a two-dimensional diffusion-drift model at atmospheric pressure. The time evolution of the discharge patterns is studied and the concentric-ring patterns with different radii shift alternately. The spatial-temporal evolution of electron density in a cycle at different time scales is performed.

  20. Non-Thermal Equilibrium Atmospheric Pressure Glow-Like Discharge Plasma Jet

    Science.gov (United States)

    Chang, Zhengshi; Yao, Congwei; Zhang, Guanjun

    2016-01-01

    Non-thermal equilibrium atmospheric pressure plasma jet (APPJ) is a cold plasma source that promises various innovative applications, and the uniform APPJ is more favored. Glow discharge is one of the most effective methods to obtain the uniform discharge. Compared with the glow dielectric barrier discharge (DBD) in atmospheric pressure, pure helium APPJ shows partial characteristics of both the glow discharge and the streamer. In this paper, considering the influence of the Penning effect, the electrical and optical properties of He APPJ and Ar/NH3 APPJ were researched. A word “Glow-like APPJ” is used to characterize the uniformity of APPJ, and it was obtained that the basic characteristics of the glow-like APPJ are driven by the kHz AC high voltage. The results can provide a support for generating uniform APPJ, and lay a foundation for its applications. supported by National Natural Science Foundation of China (Nos. 51307133, 51125029, 51221005) and the Fundamental Research Funds for the Central Universities of China (Nos. xjj2012132, xkjc2013004)

  1. Ionization instability induced striations in atmospheric pressure He/H2O RF and DC discharges

    Science.gov (United States)

    Kawamura, E.; Lieberman, M. A.; Lichtenberg, A. J.

    2017-04-01

    One-dimensional particle-in-cell (PIC) simulations of a 1 mm gap atmospheric pressure He/2%{{\\text{H}}2}\\text{O} rf capacitive discharge showed standing striations in the bulk (Kawamura et al 2016 Plasma Sources Sci. Technol. 25 054009). We found that these striations were consistent with an ionization instability induced by non-local electron kinetics. We developed a theoretical instability criterion in good agreement with the numerical results which showed that discharges with larger bulk recombination rates tend to be more unstable. We also determined a critical wavelength such that shorter wavelengths are suppressed by diffusion while longer wavelengths may be restricted by the gap width. In this paper, we extend the gap size of the atmospheric pressure He/2%{{\\text{H}}2}\\text{O} discharges in the PIC simulations to 2 and 4 mm and drive them by either dc or rf current sources. We compare the results to the 1 mm gap rf simulations and theoretical model in Kawamura et al (2016 Plasma Sources Sci. Technol. 25 054009). We find that wider gap discharges tend to be more unstable as they can accommodate a wider range of wavelengths. Furthermore, the mixture of the various excited modes in the wider gaps can lead to distinctly non-sinusoidal spatial oscillations.

  2. Surface Treatment of Polyethylene Terephthalate Film Using Atmospheric Pressure Glow Discharge in Air

    Institute of Scientific and Technical Information of China (English)

    方志; 邱毓昌; 王辉

    2004-01-01

    Non-thermal plasmas under atmospheric pressure are of great interest in polymer surface processing because of their convenience, effectiveness and low cost. In this paper, the treatment of Polyethylene terephthalate (PET) film surface for improving hydrophilicity using the non-thermal plasma generated by atmospheric pressure glow discharge (APGD) in air is conducted.The discharge characteristics of APGD are shown by measurement of their electrical discharge parameters and observation of light-emission phenomena, and the surface properties of PET before and after the APGD treatment are studied using contact angle measurement, x-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). It is found that the APGD is homogeneous and stable in the whole gas gap, which differs from the commonly filamentary dielectric barrier discharge (DBD). A short time (several seconds) APGD treatment can modify the surface characteristics of PET film markedly and uniformly. After 10 s APGD treatment, the surface oxygen content of PET surface increases to 39%, and the water contact angle decreases to 19°, respectively.

  3. Atmospheric pressure air direct current glow discharge ionization source for ion mobility spectrometry.

    Science.gov (United States)

    Dong, Can; Wang, Weiguo; Li, Haiyang

    2008-05-15

    A new atmospheric pressure air direct current glow discharge (DCGD) ionization source has been developed for ion mobility spectrometry (IMS) to overcome the regularity problems associated with the conventional (63)Ni source and the instability of the negative corona discharge. Its general electrical characteristics were experimentally investigated. By equipping it to IMS, a higher sensitivity was obtained compared to that of a (63)Ni source and corona discharge, and a linear dynamic range from 20 ppb to 20 ppm was obtained for m-xylene. Primary investigations showed that alkanes, such as pentane, which are nondetectable or insensitively detectable with (63)Ni-IMS, can be efficiently detected by DCGD-IMS and the detection limit of 10 ppb can be reached. The preliminary results have shown that the new DCGD ionization source has great potential applications in IMS, such as online monitoring of environment pollutants and halogenated compounds.

  4. Apparatus for atmospheric pressure pin-to-hole spark discharge and uses thereof

    Energy Technology Data Exchange (ETDEWEB)

    Dobrynin, Danil V.; Fridman, Alexander; Cho, Young I.; Fridman, Gregory; Friedman, Gennady

    2016-12-06

    Disclosed herein are atmospheric pressure pin-to-hole pulsed spark discharge devices and methods for creating plasma. The devices include a conduit for fluidically communicating a gas, a plasma, or both, therethrough, portion of the conduit capable of being connected to a gas supply, and a second portion of the conduit capable of emitting a plasma; a positive electrode comprising a sharp tip; and a ground plate electrode. Disclosed are methods for treating a skin ulcer using non-thermal plasma include flowing a gas through a cold spark discharge zone simultaneously with the creation of a pulsed spark discharge to give rise to a non-thermal plasma emitted from a conduit, the non-thermal plasma comprising NO; and contacting a skin ulcer with said non-thermal plasma for sufficient time and intensity to give rise to treatment of the skin ulcer.

  5. Characteristics of atmospheric-pressure, radio-frequency glow discharges operated with argon added ethanol

    Science.gov (United States)

    Sun, Wen-Ting; Li, Guo; Li, He-Ping; Bao, Cheng-Yu; Wang, Hua-Bo; Zeng, Shi; Gao, Xing; Luo, Hui-Ying

    2007-06-01

    Rf, atmospheric-pressure glow discharge (APGD) plasmas with bare metal electrodes have promising prospects in the fields of plasma-aided etching, thin film deposition, disinfection and sterilization, etc. In this paper, the discharge characteristics are presented for the rf APGD plasmas generated with pure argon or argon-ethanol mixture as the plasma-forming gas and using water-cooled, bare copper electrodes. The experimental results show that the breakdown voltage can be reduced significantly when a small amount of ethanol is added into argon, probably due to the fact that the Penning ionization process is involved, and a pure α-mode discharge can be produced more easily with the help of ethanol. The uniformity of the rf APGDs of pure argon or argon-ethanol mixtures using bare metallic electrodes is identified with the aid of the intensified charge coupled device images.

  6. Argon metastable dynamics in a filamentary jet micro-discharge at atmospheric pressure

    CERN Document Server

    Niermann, B; Kuschel, T; Benedikt, J; Böke, M; Winter, J

    2011-01-01

    Space and time resolved concentrations of Ar ($^{3}P_2$) metastable atoms at the exit of an atmospheric pressure radio-frequency micro-plasma jet were measured using tunable diode laser absorption spectroscopy. The discharge features a coaxial geometry with a hollow capillary as an inner electrode and a ceramic tube with metal ring as outer electrode. Absorption profiles of metastable atoms as well as optical emission measurements reveal the dynamics and the filamentary structure of the discharge. The average spatial distribution of Ar metastables is characterized with and without a target in front of the jet, showing that the target potential and therewith the electric field distribution substantially changes the filaments' expansion. Together with the detailed analysis of the ignition phase and the discharge's behavior under pulsed operation, the results give an insight into the excitation and de-excitation mechanisms.

  7. An experimental study of atmospheric pressure dielectric barrier discharge (DBD) in argon

    Energy Technology Data Exchange (ETDEWEB)

    Subedi, D. P. [Department of Natural Sciences, School of Science, Kathmandu University, Dhulikhel (Nepal); Tyata, R. B. [Department of Natural Sciences, School of Science, Kathmandu University, Dhulikhel, Nepal and Department of Electrical, Khwopa College of Engineering, Libali-2, Bhaktapur (Nepal); Shrestha, R. [Department of Natural Sciences, School of Science, Kathmandu University, Dhulikhel, Nepal and Department of Physics, Basu College, Kalighat, Byasi, Bhaktapur (Nepal); Wong, C. S. [Plasma Technology Research Centre, Physics Department, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia)

    2014-03-05

    In this paper, experimental results on atmospheric pressure argon dielectric barrier discharge (DBD) have been presented. The discharge was generated using a high voltage (0 to 20 kV) power supply operating at frequency of 10 to 30 kHz and was studied by means of electrical and optical measurements. A homogeneous and steady discharge was observed between the electrodes with gap spacing from 1 mm to 3 mm and with a dielectric barrier of thickness 1.5 mm while argon gas is fed at a controlled flow rate of 2liter per min. The electron temperature (T{sub e}) and electron density (n{sub e}) of the plasma have been determined by means of optical emission spectroscopy. Our results show that the electron density is of the order of 10{sup 16} cm{sup −3} while the electron temperature is estimated to be ∼ 1 eV. The homogeneity and non-thermal nature of the discharge were utilized in the investigation of the change in wettabilty of a polymer sample subjected to the treatment by the discharge. Contact angle analysis showed that the discharge was effective in improving the wettability of low density Polyethylene (LDPE) polymer sample after the treatment.

  8. A tomographic visualization of electric discharge sound fields in atmospheric pressure plasma using laser diffraction

    Science.gov (United States)

    Nakamiya, Toshiyuki; Mitsugi, Fumiaki; Iwasaki, Yoichiro; Ikegami, Tomoaki; Tsuda, Ryoichi; Sonoda, Yoshito; Danuta Stryczewska, Henryka

    2013-02-01

    The phase modulation of transparent gas can be detected using Fraunhofer diffraction technique, which we call optical wave microphone (OWM). The OWM is suitable for the detection of sonic wave from audible sound to ultrasonic wave. Because this technique has no influence on sound field or electric field during the measurement, we have applied it to the sound detection for the electric discharges. There is almost no research paper that uses the discharge sound to examine the electrical discharge phenomenon. Two-dimensional visualization of the sound field using the OWM is also possible when the computerized tomography (CT) is combined. In this work, coplanar dielectric barrier discharge sin different gases of Ar, N2, He were characterized via the OWM as well as applied voltage and discharge current. This is the first report to investigate the influence of the type of the atmospheric gas on the two-dimensional sound field distribution for the coplanar dielectric barrier discharge using the OWM with CT. Contribution to the Topical Issue "13th International Symposium on High Pressure Low Temperature Plasma Chemistry (Hakone XIII)", Edited by Nicolas Gherardi, Henryca Danuta Stryczewska and Yvan Ségui.

  9. Methane Conversion to C2 Hydrocarbons by Abnormal Glow Discharge at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    Dai Wei; Yu Hui; Chen Qi; Yin Yongxiang; Dai Xiaoyan

    2005-01-01

    Methane conversion to C2 hydrocarbons has been investigated with the addition of hydrogen in a plasma reactor of abnormal glow discharge at atmospheric pressure. The aim of this experiment is to minimize coke formation and improve discharge stability. The typical conditions in the experiment are 300 ml of total feed flux and 400 W of discharge power. The experimental results show that methane conversion is from 91.6% to 35.2% in mol, acetylene selectivity is from 90.2% to 57.6%, and ethylene selectivity is approximately from 7.8% to 3.6%,where the coke increases gradually along with the increase of CH4/H2 from 2: 8 to 9: 1. A stable discharge for a considerable running time can be obtained only at a lower ratio of CH4/H2= 2:8 or 3: 7. These phenomena indicate that the coke deposition during methane conversion is obviously reduced by adding a large amount of hydrogen during an abnormal glow discharge.A qualitative interpretation is presented, namely, with abundant hydrogen, the possibility that hydrogen molecules are activated to hydrogen radicals is increased with the help of the abnormal glow discharge. These hydrogen radicals react with carbon radicals to form C2 hydrocarbon products. Therefore, the deposition of coke is restrained.

  10. Plasma polymerization of ethylene in an atmospheric pressure-pulsed discharge

    Science.gov (United States)

    Donohoe, K.; Wydeven, T.

    1979-01-01

    The polymerization of ethylene in an atmospheric pressure-pulsed discharge has been studied. Partial pressures of ethylene up to 4 kN/sq m were used with helium as a diluent. Deposition rates (on glass slides) were the same throughout the discharge volume over a wide range of operating conditions. These rates were in the 1-2 A/sec range. The films were clear, soft, and showed good adhesion to the glass substrates. Oligomers large enough to visibly scatter 637.8-nm light were observed in the gas phase under all conditions in which film deposition occurred. The experimental results suggest that Brownian diffusion of these oligomers was the rate-limiting step in the film deposition process.

  11. Two-Dimensional Electron Density Measurement of Positive Streamer Discharge in Atmospheric-Pressure Air

    Science.gov (United States)

    Inada, Yuki; Ono, Ryo; Kumada, Akiko; Hidaka, Kunihiko; Maeyama, Mitsuaki

    2016-09-01

    The electron density of streamer discharges propagating in atmospheric-pressure air is crucially important for systematic understanding of the production mechanisms of reactive species utilized in wide ranging applications such as medical treatment, plasma-assisted ignition and combustion, ozone production and environmental pollutant processing. However, electron density measurement during the propagation of the atmospheric-pressure streamers is extremely difficult by using the conventional localized type measurement systems due to the streamer initiation jitters and the irreproducibility in the discharge paths. In order to overcome the difficulties, single-shot two-dimensional electron density measurement was conducted by using a Shack-Hartmann type laser wavefront sensor. The Shack-Hartmann sensor with a temporal resolution of 2 ns was applied to pulsed positive streamer discharges generated in an air gap between pin-to-plate electrodes. The electron density a few ns after the streamer initiation was 7*1021m-3 and uniformly distributed along the streamer channel. The electron density and its distribution profile were compared with a previous study simulating similar streamers, demonstrating good agreement. This work was supported in part by JKA and its promotion funds from KEIRIN RACE. The authors like to thank Mr. Kazuaki Ogura and Mr. Kaiho Aono of The University of Tokyo for their support during this work.

  12. Numerical simulation of a direct current glow discharge in atmospheric pressure helium

    Science.gov (United States)

    Yin, Zeng-Qian; Wang, Yan; Zhang, Pan-Pan; Zhang, Qi; Li, Xue-Chen

    2016-12-01

    Characteristics of a direct current (DC) discharge in atmospheric pressure helium are numerically investigated based on a one-dimensional fluid model. The results indicate that the discharge does not reach its steady state till it takes a period of time. Moreover, the required time increases and the current density of the steady state decreases with increasing the gap width. Through analyzing the spatial distributions of the electron density, the ion density and the electric field at different discharge moments, it is found that the DC discharge starts with a Townsend regime, then transits to a glow regime. In addition, the discharge operates in a normal glow mode or an abnormal glow one under different parameters, such as the gap width, the ballast resistors, and the secondary electron emission coefficients, judged by its voltage-current characteristics. Project supported by the National Natural Science Foundation of China (Grant Nos. 11575050 and 10805013), the Midwest Universities Comprehensive Strength Promotion Project, the Natural Science Foundation of Hebei Province, China (Grant Nos. A2016201042 and A2015201092), and the Research Foundation of Education Bureau of Hebei Province, China (Grant No. LJRC011).

  13. Numerical simulation and experimental validation of a direct current air corona discharge under atmospheric pressure

    Institute of Scientific and Technical Information of China (English)

    Liu Xing-Hua; He Wei; Yang Fan; Wang Hong-Yu; Liao Rui-Jin; Xiao Han-Guang

    2012-01-01

    Air corona discharge is one of the critical problems associated with high-voltage equipment.Investigating the corona mechanism plays a key role in enhancing the electrical insulation performance.An improved self-consistent multi-component two-dimensional plasma hybrid model is presented for the simulation of a direct current atmospheric pressure corona discharge in air.The model is based on plasma hydrodynamic and chemical models,and includes 12 species and 26 reactions.In addition,the photoionization effect is introduced into the model.The simulation on a bar-plate electrode configuration with an inter-electrode gap of 5.0 mm is carried out.The discharge voltage-current characteristics and the current density distribution predicted by the hybrid model agree with the experimental measurements.In addition,the dynamics of volume charged species generation,discharge current waveform,current density distribution at an electrode,charge density,electron temperature,and electric field variations are investigated in detail based on the model.The results indicate that the model can contribute valuable insights into the physics of an air plasma discharge.

  14. Space Charge Transient Kinetic Characteristics in DC Air Corona Discharge at Atmospheric Pressure

    Science.gov (United States)

    Liu, Xinghua; Xian, Richang; Sun, Xuefeng; Wang, Tao; Lv, Xuebin; Chen, Suhong; Yang, Fan

    2014-08-01

    Investigating the corona mechanism plays a key role in enhancing the performance of electrical insulation systems. Numerical simulation offers a better understanding of the physical characteristics of air corona discharges. Using a two-dimensional axisymmetrical kinetics model, into which the photoionization effect is incorporated, the DC air corona discharge at atmosphere pressure is studied. The plasma model is based on a self-consistent, multi-component, and continuum description of the air discharge, which is comprised of 12 species and 22 reactions. The discharge voltage-current characteristic predicted by the model is found to be in quite good agreement with experimental measurements. The behavior of the electronic avalanche progress is also described. O2+ and N2+ are the dominant positive ions, and the values of O- and O2- densities are much smaller than that of the electron. The electron and positive ion have a low-density thin layer near the anode, which is a result of the surface reaction and absorption effect of the electrode. As time progresses, the electric field increases and extends along the cathode surface, whereas the cathode fall shrinks after the corona discharge hits the cathode; thus, in the cathode sheath, the electron temperature increases and the position of its peak approaches to the cathode. The present computational model contributes to the understanding of this physical mechanism, and suggests ways to improve the electrical insulation system.

  15. Atmospheric pressure chemical ionization of explosives using alternating current corona discharge ion source.

    Science.gov (United States)

    Usmanov, D T; Chen, L C; Yu, Z; Yamabe, S; Sakaki, S; Hiraoka, K

    2015-04-01

    The high-sensitive detection of explosives is of great importance for social security and safety. In this work, the ion source for atmospheric pressure chemical ionization/mass spectrometry using alternating current corona discharge was newly designed for the analysis of explosives. An electromolded fine capillary with 115 µm inner diameter and 12 mm long was used for the inlet of the mass spectrometer. The flow rate of air through this capillary was 41 ml/min. Stable corona discharge could be maintained with the position of the discharge needle tip as close as 1 mm to the inlet capillary without causing the arc discharge. Explosives dissolved in 0.5 µl methanol were injected to the ion source. The limits of detection for five explosives with 50 pg or lower were achieved. In the ion/molecule reactions of trinitrotoluene (TNT), the discharge products of NOx (-) (x = 2,3), O3 and HNO3 originating from plasma-excited air were suggested to contribute to the formation of [TNT - H](-) (m/z 226), [TNT - NO](-) (m/z 197) and [TNT - NO + HNO3 ](-) (m/z 260), respectively. Formation processes of these ions were traced by density functional theory calculations. Copyright © 2015 John Wiley & Sons, Ltd.

  16. Formation and characteristics of patterns in atmospheric-pressure radio-frequency dielectric barrier discharge plasma

    Science.gov (United States)

    Yang, Lizhen; Liu, Zhongwei; Mao, Zhiguo; Li, Sen; Chen, Qiang

    2017-01-01

    The patterns in radio-frequency dielectric barrier discharge (RF DBD) are studied at atmospheric pressure of argon (Ar) or helium (He) mixed with nitrogen (N2) gas. When a small amount of N2 is mixed with He or Ar gas, discharge patterns are formed. In a N2/He gas mixture, besides the filament discharge that forms patterns, a glow background discharge is also observed, whereas only the filament discharge forms patterns in a N2/Ar gas mixture. The resolution of the hexagonal pattern as a function of applied power and gas flow rate is then explored. On the basis of spatial-temporal images taken using an intensified charge-coupled device (ICCD), we find that there is no interleaving of two transient hexagon sublattices in N2/Ar or N2/He plasma in RF DBD patterns, which are totally different from those in which surface charges dominated in the mid-frequency DBD plasma. This supports our hypothesis that the bulk charges dominate the pattern formation in RF DBD.

  17. Influence of discharge and jet flow coupling on atmospheric pressure plasma homogeneity

    Science.gov (United States)

    Nizard, H.; Gaudy, T.; Toutant, A.; Iacono, J.; Descamps, P.; Leempoel, P.; Massines, F.

    2015-10-01

    The effect of flow dynamics on the discharge mode is studied in order to design a technical solution for thin film coating on large surfaces. The configuration consists in two atmospheric pressure helium plasma jets impacting a surface and confined in a tube. This system operates in open air. It has been studied by short exposure time pictures, current and voltage measurements, optical emission spectroscopy, schlieren flow visualization and computational fluid dynamics. Two discharge regimes directly connected to the gas flow dynamic have been pointed out. One is localized from the point electrodes to the surface; the other one entirely fills the confinement tube. A correlation between air intake inside the confinement tube and the discharge mode has been highlighted. Indeed, the discharge only develops in helium and the air intake confines the helium jets in volumes smaller than the confinement tube. The air intake is determined by the gas flow rate and the distance from the tube bottom to the substrate surface, parameters which have been linked to the change from laminar to turbulent flow. Finally, the understanding of flow dynamics and discharge plasma coupling allowed the design of a technical solution favoring plasma homogeneity for large surface treatment.

  18. Synthesis of Crystalline Carbon Nitride Thin Films by Pulsed Arc Discharge at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    SHI Changyong; MA Zhibin

    2007-01-01

    The preparation of crystalline C3N4 films was investigated using pulsed arc discharge from mixed methanol and ammonia water at atmospheric pressure.The X-ray diffraction(XRD)patterns of the films prepared at a substrate temperature of 450℃ suggested that the film was composed of α-C3N4 and β-C3N4 crystallites.Raman spectra exhibited distinct peaks which are in good agreement with those predicted theoretically for C3N4 crystallites.

  19. Spatial and temporal evolutions of ozone in a nanosecond pulse corona discharge at atmospheric pressure

    Energy Technology Data Exchange (ETDEWEB)

    Duten, X; Redolfi, M; Aggadi, N; Vega, A; Hassouni, K, E-mail: duten@lspm.cnrs.fr [LSPM-CNRS UPR 3407, Universite Paris Nord, 90 Avenue J.B. Clement, 93430 Villetaneuse (France)

    2011-10-19

    This paper deals with the experimental determination of the spatial and temporal evolutions of the ozone concentration in an atmospheric pressure pulsed plasma, working in the nanosecond regime. We observed that ozone was produced in the localized region of the streamer. The ozone transport requires a characteristic time well above the millisecond. The numerical modelling of the streamer expansion confirms that the hydrodynamic expansion of the filamentary discharge region during the streamer propagation does not lead to a significant transport of atomic oxygen and ozone. It appears therefore that only diffusional transport can take place, which requires a characteristic time of the order of 50 ms.

  20. Genetic effects of radio-frequency, atmospheric-pressure glow discharges with helium

    Science.gov (United States)

    Li, Guo; Li, He-Ping; Wang, Li-Yan; Wang, Sen; Zhao, Hong-Xin; Sun, Wen-Ting; Xing, Xin-Hui; Bao, Cheng-Yu

    2008-06-01

    Due to low gas temperatures and high densities of active species, atmospheric-pressure glow discharges (APGDs) would have potential applications in the fields of plasma-based sterilization, gene mutation, etc. In this letter, the genetic effects of helium radio-frequency APGD plasmas with the plasmid DNA and oligonucleotide as the treated biomaterials are presented. The experimental results show that it is the chemically active species, instead of heat, ultraviolet radiation, intense electric field, and/or charged particles, that break the double chains of the plasmid DNA. The genetic effects depend on the plasma operating parameters, e.g., power input, helium flow rate, processing distance, time, etc.

  1. Spatial and temporal evolutions of ozone in a nanosecond pulse corona discharge at atmospheric pressure

    Science.gov (United States)

    Duten, X.; Redolfi, M.; Aggadi, N.; Vega, A.; Hassouni, K.

    2011-10-01

    This paper deals with the experimental determination of the spatial and temporal evolutions of the ozone concentration in an atmospheric pressure pulsed plasma, working in the nanosecond regime. We observed that ozone was produced in the localized region of the streamer. The ozone transport requires a characteristic time well above the millisecond. The numerical modelling of the streamer expansion confirms that the hydrodynamic expansion of the filamentary discharge region during the streamer propagation does not lead to a significant transport of atomic oxygen and ozone. It appears therefore that only diffusional transport can take place, which requires a characteristic time of the order of 50 ms.

  2. Treatment of polycarbonate by dielectric barrier discharge (DBD) at atmospheric pressure

    Science.gov (United States)

    Kostov, K. G.; Hamia, Y. A. A.; Mota, R. P.; dos Santos, A. L. R.; Nascente, P. A. P.

    2014-05-01

    Generally most plastic materials are intrinsically hydrophobic, low surface energy materials, and thus do not adhere well to other substances. Surface treatment of polymers by discharge plasmas is of great and increasing industrial application because it can uniformly modify the surface of sample without changing the material bulk properties and is environmentally friendly. The plasma processes that can be conducted under ambient pressure and temperature conditions have attracted special attention because of their easy implementation in industrial processing. Present work deals with surface modification of polycarbonate (PC) by a dielectric barrier discharge (DBD) at atmospheric pressure. The treatment was performed in a parallel plate reactor driven by a 60Hz power supply. The DBD plasmas at atmospheric pressure were generated in air and nitrogen. Material characterization was carried out by contact angle measurements, and X-ray photoelectron spectroscopy (XPS). The surface energy of the polymer surface was calculated from contact angle data by Owens-Wendt method using distilled water and diiodomethane as test liquids. The plasma-induced chemical modifications are associated with incorporation of polar oxygen and nitrogen containing groups on the polymer surface. Due to these surface modifications the DBD-treated polymers become more hydrophilic. Aging behavior of the treated samples revealed that the polymer surfaces were prone to hydrophobic recovery although they did not completely recover their original wetting properties.

  3. Investigation of Nanosecond Pulsed Discharge and Its Audio Characteristics in Atmospheric-pressure Air

    Institute of Scientific and Technical Information of China (English)

    REN Chengyan; RAN Huijuan; WANG Jue; WANG Tao; YAN Ping

    2013-01-01

    There was no well-resolved mechanism of audible noise caused by corona discharge on UHV transmission lines.Hence we measured the sound pressure of pulsed discharges between needle-plane electrodes under different discharge conditions in air,for revealing the intrinsic relationship between discharge and its audible noise(AN).The relationship between discharge parameters and audio characteristics was drawn from the analysis of the electric and sound signals obtained in experiments.Experiment results showed that nanosecond pulsed discharges produce the sound pressure with a microsecond pulse lagging behind the discharge pulse in their waveforms.The peak value of the sound pulse decreases and its high frequency component gradually attenuates,when the measuring distance from discharges increases.The sound pulses correlate with the discharge current and voltage significantly,especially the current.The audible noise produced by repetitive pulsed discharge increases with the strength,duration,and pulse repetition rate of discharge.

  4. Electron dynamics and plasma jet formation in a helium atmospheric pressure dielectric barrier discharge jet

    Energy Technology Data Exchange (ETDEWEB)

    Algwari, Q. Th. [Centre for Plasma Physics, School of Maths and Physics, Queen' s University Belfast, University Road, Belfast, Northern Ireland BT7 1NN (United Kingdom); Electronic Department, College of Electronics Engineering, Mosul University, Mosul 41002 (Iraq); O' Connell, D. [Centre for Plasma Physics, School of Maths and Physics, Queen' s University Belfast, University Road, Belfast, Northern Ireland BT7 1NN (United Kingdom); York Plasma Institute, Department of Physics, University of York, York YO10 5DD (United Kingdom)

    2011-09-19

    The excitation dynamics within the main plasma production region and the plasma jets of a kHz atmospheric pressure dielectric barrier discharge (DBD) jet operated in helium was investigated. Within the dielectric tube, the plasma ignites as a streamer-type discharge. Plasma jets are emitted from both the powered and grounded electrode end; their dynamics are compared and contrasted. Ignition of these jets are quite different; the jet emitted from the powered electrode is ignited with a slight time delay to plasma ignition inside the dielectric tube, while breakdown of the jet at the grounded electrode end is from charging of the dielectric and is therefore dependent on plasma production and transport within the dielectric tube. Present streamer theories can explain these dynamics.

  5. A sensitive gas chromatography detector based on atmospheric pressure chemical ionization by a dielectric barrier discharge.

    Science.gov (United States)

    Kirk, Ansgar T; Last, Torben; Zimmermann, Stefan

    2017-02-03

    In this work, we present a novel concept for a gas chromatography detector utilizing an atmospheric pressure chemical ionization which is initialized by a dielectric barrier discharge. In general, such a detector can be simple and low-cost, while achieving extremely good limits of detection. However, it is non-selective apart from the use of chemical dopants. Here, a demonstrator manufactured entirely from fused silica capillaries and printed circuit boards is shown. It has a size of 75×60×25mm(3) and utilizes only 2W of power in total. Unlike other known discharge detectors, which require high-purity helium, this detector can theoretically be operated using any gas able to form stable ion species. Here, purified air is used. With this setup, limits of detection in the low parts-per-billion range have been obtained for acetone.

  6. FAST TRACK COMMUNICATION: Contrasting characteristics of sub-microsecond pulsed atmospheric air and atmospheric pressure helium-oxygen glow discharges

    Science.gov (United States)

    Walsh, J. L.; Liu, D. X.; Iza, F.; Rong, M. Z.; Kong, M. G.

    2010-01-01

    Glow discharges in air are often considered to be the ultimate low-temperature atmospheric pressure plasmas for numerous chamber-free applications. This is due to the ubiquitous presence of air and the perceived abundance of reactive oxygen and nitrogen species in air plasmas. In this paper, sub-microsecond pulsed atmospheric air plasmas are shown to produce a low concentration of excited oxygen atoms but an abundance of excited nitrogen species, UV photons and ozone molecules. This contrasts sharply with the efficient production of excited oxygen atoms in comparable helium-oxygen discharges. Relevant reaction chemistry analysed with a global model suggests that collisional excitation of O2 by helium metastables is significantly more efficient than electron dissociative excitation of O2, electron excitation of O and ion-ion recombination. These results suggest different practical uses of the two oxygen-containing atmospheric discharges, with air plasmas being well suited for nitrogen and UV based chemistry and He-O2 plasmas for excited atomic oxygen based chemistry.

  7. Array of surface-confined glow discharges in atmospheric pressure helium: Modes and dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Li, D.; Liu, D. X., E-mail: liudingxin@gmail.com, E-mail: mglin5g@gmail.com [Center for Plasma Biomedicine, State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Shaanxi (China); Nie, Q. Y.; Li, H. P. [Department of Engineering Physics, Tsinghua University, Beijing 100084 (China); Chen, H. L. [Frank Reidy Center for Bioelectrics, Old Dominion University, Norfolk, Virginia 23508 (United States); Kong, M. G., E-mail: liudingxin@gmail.com, E-mail: mglin5g@gmail.com [Center for Plasma Biomedicine, State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Shaanxi (China); Frank Reidy Center for Bioelectrics, Old Dominion University, Norfolk, Virginia 23508 (United States); Department of Electrical and Computer Engineering, Old Dominion University, Norfolk, Virginia 23529 (United States)

    2014-05-19

    Array of atmospheric pressure surface discharges confined by a two-dimensional hexagon electrode mesh is studied for its discharge modes and temporal evolution so as to a theoretical underpinning to their growing applications in medicine, aerodynamic control, and environmental remediation. Helium plasma surface-confined by one hexagon-shaped rim electrode is shown to evolve from a Townsend mode to a normal and abnormal glow mode, and its evolution develops from the rim electrodes as six individual microdischarges merging in the middle of the hexagon mesh element. Within one hexagon element, microdischarges remain largely static with the mesh electrode being the instantaneous cathode, but move towards the hexagon center when the electrode is the instantaneous anode. On the entire array electrode surface, plasma ignition is found to beat an unspecific hexagon element and then spreads to ignite surrounding hexagon elements. The spreading of microdischarges is in the form of an expanding circle at a speed of about 3 × 10{sup 4} m/s, and their quenching starts in the location of the initial plasma ignition. Plasma modes influence how input electrical power is used to generate and accelerate electrons and as such the reaction chemistry, whereas plasma dynamics are central to understand and control plasma instabilities. The present study provides an important aspect of plasma physics of the atmospheric surface-confined discharge array and a theoretical underpinning to its future technological innovation.

  8. Nanosecond Repetitively Pulsed Discharges in Air at Atmospheric Pressure -- Experiment and Theory of Regime Transitions

    Science.gov (United States)

    Pai, David; Lacoste, Deanna; Laux, Christophe

    2009-10-01

    In atmospheric pressure air preheated from 300 to 1000 K, the Nanosecond Repetitively Pulsed (NRP) method has been used to generate corona, glow, and spark discharges. Experiments have been performed to determine the parameter space (applied voltage, pulse repetition frequency, ambient gas temperature, and inter-electrode gap distance) of each discharge regime. Notably, there is a minimum gap distance for the existence of the glow regime that increases with decreasing gas temperature. A theory is developed to describe the Corona-to-Glow (C-G) and Glow-to-Spark (G-S) transitions for NRP discharges. The C-G transition is shown to depend on the Avalanche-to-Streamer Transition (AST) as well as the electric field strength in the positive column. The G-S transition is due to the thermal ionization instability. The minimum gap distance for the existence of the glow regime can be understood by considering that the applied voltage of the AST must be lower than that of the thermal ionization instability. This is a previously unknown criterion for generating glow discharges, as it does not correspond to the Paschen minimum or to the Meek-Raether criterion.

  9. Effects of oxygen concentration on atmospheric pressure dielectric barrier discharge in Argon-Oxygen Mixture

    Science.gov (United States)

    Li, Xuechun; Li, Dian; Wang, Younian

    2016-09-01

    A dielectric barrier discharge (DBD) can generate a low-temperature plasma easily at atmospheric pressure and has been investigated for applications in trials in cancer therapy, sterilization, air pollution control, etc. It has been confirmed that reactive oxygen species (ROS) play a key role in the processes. In this work, we use a fluid model to simulate the plasma characteristics for DBD in argon-oxygen mixture. The effects of oxygen concentration on the plasma characteristics have been discussed. The evolution mechanism of ROS has been systematically analyzed. It was found that the ground state oxygen atoms and oxygen molecular ions are the dominated oxygen species under the considered oxygen concentrations. With the oxygen concentration increasing, the densities of electrons, argon atomic ions, resonance state argon atoms, metastable state argon atoms and excited state argon atoms all show a trend of decline. The oxygen molecular ions density is high and little influenced by the oxygen concentration. Ground state oxygen atoms density tends to increase before falling. The ozone density increases significantly. Increasing the oxygen concentration, the discharge mode begins to change gradually from the glow discharge mode to Townsend discharge mode. Project supported by the National Natural Science Foundation of China (Grant No. 11175034).

  10. Comparative study of non-thermal atmospheric pressure discharge plasmas for life science applications

    Science.gov (United States)

    Koga, Kazunori; Katayama, Ryu; Sarinont, Thapanut; Seo, Hyunwoong; Itagaki, Naho; Attri, Pankaj; Leal-Quiros, Edbertho; Tanaka, Akiyo; Shiratani, Masaharu

    2016-09-01

    We are comparing several non-thermal atmospheric pressure discharge plasmas for life science applications. Here we measured discharge period dependence of pH value and 750 nm absorbance of KI-starch solution of deionized water after plasma irradiation with two discharge devices; a dielectric barrier discharge (DBD) jet device and a scalable DBD device. The pH and the absorbance of KI-starch solution are useful indicator of their oxidizability. We have obtained a map of the absorbance and proton concentration [H+] which is deduced from pH value. For the scalable DBD, the range of the absorbance is between 0.7 and 1.3 and that of [H+] is between 10-7 and 10-5 mol/L. For the DBD jet, the range of the absorbance and [H+] are 2.0-3.2 and 10-4-10-3 mol/L, respectively. Measured data for both devices shows same tendency in the map, while the range of values for the scalable DBD is smaller than that for the DBD jet. The results indicate the oxidazability for the scalable DBD is much weaker than that for the DBD jet.

  11. Decomposition of toluene in a steady-state atmospheric-pressure glow discharge

    Science.gov (United States)

    Trushkin, A. N.; Grushin, M. E.; Kochetov, I. V.; Trushkin, N. I.; Akishev, Yu. S.

    2013-02-01

    Results are presented from experimental studies of decomposition of toluene (C6H5CH3) in a polluted air flow by means of a steady-state atmospheric pressure glow discharge at different water vapor contents in the working gas. The experimental results on the degree of C6H5CH3 removal are compared with the results of computer simulations conducted in the framework of the developed kinetic model of plasma chemical decomposition of toluene in the N2: O2: H2O gas mixture. A substantial influence of the gas flow humidity on toluene decomposition in the atmospheric pressure glow discharge is demonstrated. The main mechanisms of the influence of humidity on C6H5CH3 decomposition are determined. The existence of two stages in the process of toluene removal, which differ in their duration and the intensity of plasma chemical decomposition of C6H5CH3 is established. Based on the results of computer simulations, the composition of the products of plasma chemical reactions at the output of the reactor is analyzed as a function of the specific energy deposition and gas flow humidity. The existence of a catalytic cycle in which hydroxyl radical OH acts a catalyst and which substantially accelerates the recombination of oxygen atoms and suppression of ozone generation when the plasma-forming gas contains water vapor is established.

  12. Ion kinetics and self pulsing in DC microplasma discharges at atmospheric and higher pressure

    Science.gov (United States)

    Mahamud, Rajib; Farouk, Tanvir I.

    2016-04-01

    Atmospheric pressure microplasma devices have been the subject of considerable interest and research during the last decade. Most of the operation regime of the plasma discharges studied fall in the ‘abnormal’, ‘normal’ and ‘corona’ modes—increasing and a ‘flat’ voltage current characteristics. However, the negative differential resistance regime at atmospheric and high pressures has been less studied and possesses unique characteristics that can be employed for novel applications. In this work, the role of ion kinetics especially associated with trace impurities; on the self pulsing behavior has been investigated. Detailed numerical simulations have been conducted with a validated model for a helium-nitrogen feed gas mixture. Different oscillatory modes were observed where the discharge was found to undergo complete or partial relaxation. Trace amount of nitrogen was found to significantly alter the pulsing characteristics. External parameters influencing these self oscillations are also studied and aspects of the ion kinetics on the oscillatory behavior are discussed.

  13. On the increase in the limiting current of an atmospheric-pressure glow discharge in an argon flow

    Science.gov (United States)

    Baldanov, B. B.; Ranzhurov, Ts. V.

    2014-04-01

    The initiation of an atmospheric-pressure glow discharge (APGD) is studied in the multitip cathode-planar anode electrode system through which an argon flow passes. It is shown that sectioning of the cathode and ballast resistances present at corona tips make it possible to substantially expand the current region of the discharge and considerably raise the limiting current of the APGD. The shape of the coronafree electrode is found to influence the limiting discharge current.

  14. Transitions between corona, glow, and spark regimes of nanosecond repetitively pulsed discharges in air at atmospheric pressure

    OpenAIRE

    Pai, David,; Lacoste, Deanna,; Laux, C.

    2010-01-01

    International audience; In atmospheric pressure air preheated from 300 to 1000 K, the nanosecond repetitively pulsed (NRP) method has been used to generate corona, glow, and spark discharges. Experiments have been performed to determine the parameter space (applied voltage, pulse repetition frequency, ambient gas temperature, and interelectrode gap distance) of each discharge regime. In particular, the experimental conditions necessary for the glow regime of NRP discharges have been determine...

  15. Particle Densities of the Atmospheric-Pressure Argon Plasmas Generated by the Pulsed Dielectric Barrier Discharges

    Science.gov (United States)

    Pan, Jie; Li, Li; Wang, Yunuan; Xiu, Xianwu; Wang, Chao; Song, Yuzhi

    2016-11-01

    Atmospheric-pressure argon plasmas have received increasing attention due to their high potential in many industrial and biomedical applications. In this paper, a 1-D fluid model is used for studying the particle density characteristics of the argon plasmas generated by the pulsed dielectric barrier discharges. The temporal evolutions of the axial particle density distributions are illustrated, and the influences of changing the main discharge conditions on the averaged particle densities are researched by independently varying the various discharge conditions. The calculation results show that the electron density and the ion density reach two peaks near the momentary cathodes during the rising and the falling edges of the pulsed voltage. Compared with the charged particle densities, the densities of the resonance state atom Arr and the metastable state atom Arm have more uniform axial distributions, reach higher maximums and decay more slowly. During the platform of the pulsed voltage and the time interval between the pulses, the densities of the excited state atom Ar* are far lower than those of the Arr or the Arm. The averaged particle densities of the different considered particles increase with the increases of the amplitude and the frequency of the pulsed voltage. Narrowing the discharge gap and increasing the relative dielectric constant of the dielectric also contribute to the increase of the averaged particle densities. The effects of reducing the discharge gap distance on the neutral particle densities are more significant than the influences on the charged particle densities. supported by Natural Science Foundation of Shandong Province, China (No. ZR2015AQ008), and Project of Shandong Province Higher Educational Science and Technology Program of China (No. J15LJ04)

  16. Shock Formation by Plasma Filaments of Microwave Discharge under Atmospheric Pressure

    Science.gov (United States)

    Takahashi, Masayuki; Ohnishi, Naofumi

    2016-03-01

    A one-dimensional compressible fluid calculation was coupled with a finite- difference time-domain code and a particle-in-cell code with collision to reproduce propagation of electromagnetic wave, ionization process of plasma, and shock wave formation in atmospheric microwave discharge. Plasma filaments are driven toward the microwave source at 1 atm, and the distance between each filament is one-fifth of the wavelength of the incident microwave. The strong shock wave is generated due to the high plasma density at the atmospheric pressure. A simple analysis of the microwave propagation into the plasma shows that cut-off density of the microwave becomes smaller with the pressure decrease in a collisional plasma. At the lower pressure, the smaller density plasma is obtained with a diffusive pattern because of the smaller cut-off density and the larger diffusion effect. In contrast with the 1-atm case, the weak shock wave is generated at a rarefied condition, which lowers performance of microwave thruster.

  17. Simulation Tool for Dielectric Barrier Discharge Plasma Actuators at Atmospheric and Sub-Atmospheric Pressures Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Traditional approaches for active flow separation control using dielectric barrier discharge (DBD) plasma actuators are limited to relatively low-speed flows and...

  18. TOPICAL REVIEW: Nucleation and aerosol processing in atmospheric pressure electrical discharges: powders production, coatings and filtration

    Science.gov (United States)

    Borra, Jean-Pascal

    2006-01-01

    This review addresses the production of nano-particles and the processing of particles injected in atmospheric pressure electrical discharges (APED). The mechanisms of formation and the evolution of particles suspended in gases are first presented, with numerical and experimental facilities. Different APED and related properties are then introduced for dc corona, streamer and spark filamentary discharges (FD), as well as for ac filamentary and homogeneous dielectric barrier discharges (DBD). Two mechanisms of particle production are depicted in APED: when FD interact with the surface of electrodes or dielectrics and when filamentary and homogeneous DBD induce reactions with gaseous precursors in volume. In both cases, condensable gaseous species are produced, leading to nano-sized particles by physical and chemical routes of nucleation. The evolution of the so-formed nano-particles, i.e. the growth by coagulation/condensation, the charging and the collection are detailed for each APED, with respect to fine powders production and thin films deposition. Finally, when particles are injected in APED, they undergo interfacial processes. Non-thermal plasmas charge particles for electro-collection and trigger heterogeneous chemical reactions for organic and inorganic films deposition. Heat exchanges in thermal plasmas enable powder purification, shaping, melting for hard coatings and fine powders production by reactive evaporation.

  19. Study of a Filamentary Dielectric Barrier Discharge in Air at Atmospheric Pressure

    Science.gov (United States)

    Celestin, Sebastien; Zeghondy, Barbar; Guaitella, Olivier; Bourdon, Anne; Rousseau, Antoine

    2006-10-01

    Dielectric Barrier Discharges (DBD) at atmospheric pressure have many applications, for instance ozone production, surface treatment, and waste gas treatment. Generally, such a discharge is filamentary but it can be diffuse under particular conditions. Understanding the formation of the filament, which is an ionization wave or so-called ``streamer'', is very hard theoretically, numerically, and experimentally. This is due, first, to the non-linearity of the equations concerned, and second, because of the scaling in space and time of this phenomenon: a streamer has a radius on the order of a few microns, and propagates through distances of several centimeters in a few nanoseconds. In this study we will present the results obtained in experiments and in simulations for a plane-to-plane DBD. We electrically characterized this device and have observed collective effects that are still poorly understood. A point-to-plane DBD has also been studied for producing a much more localized discharge. In parallel with the experimental study we have developed a numerical model based on the Immersed Boundary Method (IBM) to introduce an electrode having a complex geometry into a structured Cartesian mesh. The first results of the code will be discussed.

  20. Laser-Ionization TOF Mass Spectrometer Characterization of Benzene Destruction in Atmospheric Pressure Pulsed Discharge

    Institute of Scientific and Technical Information of China (English)

    LIU Jiahong; XIAO Qingmei; WANG Liping; YAO Zhi; DING Hongbin

    2009-01-01

    Benzene is.a major industrial air pollutant and can cause serious human health disorders. In this paper an investigation on benzene destruction, in an atmospheric-pressure fast-flow pulsed DC-discharge by means of laser ionization combined with time-of-flight (TOF) mass spectrometry, is reported. Most by-products including transient reactive species from the benzene discharge were characterized by molecular beam sampling combined with TOF mass spectrometry.It is showed that, with a gas mixture of 0.5% C6H6 in Ar, benzene can be effectively destroyed by discharge plasma. The intermediate species consisted of small fragments of CNHm (n=3~5,m =1~11), cycle-chain species of CNHm (n=6~9, m = 7~10) and polycyclic species CNHm (n ≥9,m = 8~12). The alternation of mass peaks (intensity) with even/odd electrons was observed in the measured mass spectra. The results indicated that the alternation is mainly due to the different ionization potentials of the open shell and close shell species. Based on the examination of the features of the species' composition, the primary reaction pathways are proposed and discussed.

  1. Study of a new direct current atmospheric pressure glow discharge in helium

    Energy Technology Data Exchange (ETDEWEB)

    Gielniak, B. [University of Hamburg, Institute for Inorganic and Applied Chemistry, Martin-Luther-King-Platz 6, 20146 Hamburg (Germany); Fiedler, T. [Johannes Gutenberg-University Mainz, Institute for Inorganic and Analytical Chemistry, Duesbergweg 10-14, 55128 Mainz (Germany); Broekaert, J.A.C., E-mail: jose.broekaert@chemie.uni-hamburg.de [University of Hamburg, Institute for Inorganic and Applied Chemistry, Martin-Luther-King-Platz 6, 20146 Hamburg (Germany)

    2011-01-15

    In this study a new DC-APGD operated in He was developed and characterized. The discharge is operated at 0.9 kV and about 25-35 mA and at a gas flow of 100 ml/min. The source was spectroscopically studied and parameters such as the rotational temperature (T{sub rot}), the excitation temperature (T{sub exc}), the ionization temperature (T{sub ion}) and the electron number density (n{sub e}) were determined. The current-voltage characteristic of the source was studied as well. At optimized conditions the discharge operates in the normal region of the current-voltage characteristic. Rotational and excitation temperatures determined with the use of OH band and Fe I lines as thermometric species were of the order of about 900-1200 and 4500-5500 K, respectively. This indicates that despite of the atmospheric pressure, the discharge is not in LTE. Spatially resolved temperature measurements were performed with axial as well as radial resolution and showed relatively flat profiles. Axially resolved emission intensity profiles for several species such as H, N{sub 2}, N{sub 2}{sup +}, OH, He and Hg were determined. It also was found that H{sub 2} introduced into the He by electrolysis of acid solutions such as in ECHG considerably increases the spectroscopically measured gas temperatures but decreases the analyte line intensities, as shown for Hg.

  2. Restraint Effect of Filaments on Applied Voltage in Atmospheric Pressure Glow Discharge%Restraint Effect of Filaments on Applied Voltage in Atmospheric Pressure Glow Discharge

    Institute of Scientific and Technical Information of China (English)

    李森; 陈强; 刘忠伟

    2012-01-01

    In this study, argon and nitrogen were used as the discharge gases in radio-frequency (RF: 13.56 MHz) powered dielectric barrier atmospheric plasma. It was noticed that in single dielectric barrier discharge (DBD) with nitrogen as the discharge gas, or in argon plasma with a high applied power, micro-filament channels were easily formed. The channels in these two kinds of discharge were both constrictive on the bare metallic electrode and expansive on the opposite electrode covered with a quartz layer. The number of micro-channels was increased along with the input power, which caused the change in the I-V curve shape, i.e., the current kept increasing and the voltage fluctuated within a confined range. With double dielectric layers, however, no micro-channels appeared in the ICCD images, and the I-V curve demonstrated a totally different shape. It was assumed that micro-filaments exhibited a restraining effect on the discharge voltage. The mechanism of this restraining effect was explored in this work.

  3. Characterization of direct-current atmospheric-pressure discharges useful for ambient desorption/ionization mass spectrometry.

    Science.gov (United States)

    Shelley, Jacob T; Wiley, Joshua S; Chan, George C Y; Schilling, Gregory D; Ray, Steven J; Hieftje, Gary M

    2009-05-01

    Two relatively new ambient ionization sources, direct analysis in real time (DART) and the flowing atmospheric-pressure afterglow (FAPA), use direct current, atmospheric-pressure discharges to produce reagent ions for the direct ionization of a sample. Although at a first glance these two sources appear similar, a fundamental study reveals otherwise. Specifically, DART was found to operate with a corona-to-glow transition (C-G) discharge whereas the FAPA was found to operate with a glow-to-arc transition (G-A) discharge. The characteristics of both discharges were evaluated on the basis of four factors: reagent-ion production, response to a model analyte (ferrocene), infrared (IR) thermography of the gas used for desorption and ionization, and spatial emission characteristics. The G-A discharge produced a greater abundance and a wider variety of reagent ions than the C-G discharge. In addition, the discharges yielded different adducts and signal strengths for ferrocene. It was also found that the gas exiting the discharge chamber reached a maximum of 235 degrees C and 55 degrees C for the G-A and C-G discharges, respectively. Finally, spatially resolved emission maps of both discharges showed clear differences for N(2)(+) and O(I). These findings demonstrate that the discharges used by FAPA and DART are fundamentally different and should have different optimal applications for ambient desorption/ionization mass spectrometry (ADI-MS).

  4. Surface Modification of Polyethylene (PE) Films Using Dielectric Barrier Discharge Plasma at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    WANG Kun; LI Jian; REN Chunsheng; WANG Dezhen; WANG Younian

    2008-01-01

    Modification of the surface properties of polyethylene (PE) films is studied using air dielectric barrier discharge at atmospheric pressure. The treated samples are examined by water contact angle measurements, Fourier transform infrared attenuated total reflection spectroscopy (FTIR-ATR), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). With the increase in treating time, the water contact angle changes from 93.2° before treatment to a minimum of 53.3° after a treatment for 50 s. Both ATR and XPS results show some oxidized" species are introduced into the sample surface by the plasma treatment and the tendency of the water contact angle with the treating time is the same as that of oxygen concentration on the treated sample surface. SEM result shows the surface roughness of PE samples increases with the treatment time increasing.

  5. Surface Modification of Polyimide Film by Dielectric Barrier Discharge at Atmospheric Pressure

    Science.gov (United States)

    Peng, Shi; Li, Lingjun; Li, Wei; Wang, Chaoliang; Guo, Ying; Shi, Jianjun; Zhang, Jing

    2016-04-01

    In this paper, polyimide (PI) films are modified using an atmospheric pressure plasma generated by a dielectric barrier discharge (DBD) in argon. Surface performance of PI film and its dependence on exposure time from 0 s to 300 s are investigated by dynamic water contact angle (WCA), field emission scanning electron microscopy (FESEM), and Fourier transform infrared spectroscopy in attenuated total multiple reflection mode (FTIR-ATR). The study demonstrates that dynamic WCA exhibits a minimum with 40 s plasma treatment, and evenly distributed nano-dots and shadow concaves appeared for 40 s and 12 s Ar plasma treatment individually. A short period of plasma modification can contribute to the scission of the imide ring and the introduction of C-O and C=O (-COOH) by detailed analysis of FTIR-ATR.

  6. Harmonic hexagonal superlattice pattern in a dielectric barrier discharge at atmospheric pressure

    Institute of Scientific and Technical Information of China (English)

    DONG LiFang; XIE WeiXia; ZHAO HaiTao; FAN WeiLi

    2009-01-01

    We report a harmonic hexagonal superlattice pattern in a dielectric barrier discharge in air/argon mixture at atmospheric pressure.The bifurcation scenario of harmonic hexagonal superlattice pattern with the applied voltage increasing is given.The phase diagram of the pattern types as a function of the applied voltage and the air-concentration is obtained.The hysteresis of pattern transitions at the upward and downward stage of the applied voltage is observed.The correlation measurements indicate that harmonic hexagonal superlattice pattern is an interleaving of two different transient sublattices.The spatial power spectrum demonstrates that harmonic hexagonal superlattice pattern has two separate wave vectors.Both small wave vector qh and big wave vector Kh,belong to the harmonic mode,and they obey a triad resonant interaction q1h + q2h,=Kh.

  7. Electrical and optical characterization of an atmospheric pressure, uniform, large-area processing, dielectric barrier discharge

    Science.gov (United States)

    Zeniou, A.; Puač, N.; Škoro, N.; Selaković, N.; Dimitrakellis, P.; Gogolides, E.; Petrović, Z. Lj

    2017-04-01

    A printed-circuit-board (PCB) based atmospheric pressure dielectric barrier discharge (DBD) capable of uniform processing over a large area was constructed consisting of two parallel plates. The first perforated plate is comprised of four layers: a RF powered metal layer, a polymeric dielectric layer, a floating metal grid and another dielectric layer. The second, grounded, plate was fluorine doped tin oxide (FTO) glass plate with surface of 100  ×  100 mm2 and thickness of 2 mm. The PCB based atmospheric pressure DBD was characterized by (a) measuring electrical characteristics of the device using derivative I–V probes, (b) ICCD imaging and (c) optical emission spectroscopy (OES). Optical and electrical characteristics, as well as plasma uniformity were measured by changing He flow rate and input power, while keeping the gap between the PCB and the FTO glass plate ground electrode constant at 2 mm. The plasma uniformity strongly depends on the applied power and on the flow rate of the buffer gas. When increasing the flow rate, the intensity of the nitrogen-dominated emission drops, while emission of helium and oxygen lines increases. The source allows low temperature, uniform plasma operation over a wide area of 100  ×  100 mm2, which could be essential for numerous applications. Examples of etching rate and hydrophilization are demonstrated.

  8. Collision-induced dissociation analysis of negative atmospheric ion adducts in atmospheric pressure corona discharge ionization mass spectrometry.

    Science.gov (United States)

    Sekimoto, Kanako; Takayama, Mitsuo

    2013-05-01

    Collision-induced dissociation (CID) experiments were performed on atmospheric ion adducts [M + R](-) formed between various types of organic compounds M and atmospheric negative ions R(-) [such as O2(-), HCO3(-), COO(-)(COOH), NO2(-), NO3(-), and NO3(-)(HNO3)] in negative-ion mode atmospheric pressure corona discharge ionization (APCDI) mass spectrometry. All of the [M + R](-) adducts were fragmented to form deprotonated analytes [M - H](-) and/or atmospheric ions R(-), whose intensities in the CID spectra were dependent on the proton affinities of the [M - H](-) and R(-) fragments. Precursor ions [M + R](-) for which R(-) have higher proton affinities than [M - H](-) formed [M - H](-) as the dominant product. Furthermore, the CID of the adducts with HCO3(-) and NO3(-)(HNO3) led to other product ions such as [M + HO](-) and NO3(-), respectively. The fragmentation behavior of [M + R](-) for each R(-) observed was independent of analyte type (e.g., whether the analyte was aliphatic or aromatic, or possessed certain functional groups).

  9. Simulation study of one-dimensional self-organized pattern in an atmospheric-pressure dielectric barrier discharge

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Jiao; Wang, Yanhui, E-mail: wangyh@dlut.edu.cn; Wang, Dezhen, E-mail: wangdez@dlut.edu.cn [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2015-04-15

    A two-dimensional fluid model is developed to simulate the one-dimensional self-organized patterns in an atmospheric-pressure dielectric barrier discharge (DBD) driven by sinusoidal voltage in argon. Under certain conditions, by changing applied voltage amplitude, the transversely uniform discharge can evolve into the patterned discharge and the varied self-organized patterned discharges with different numbers and arrangements of discharge channels can be observed. Similar to the uniform atmospheric-pressure DBD, the patterned discharge mode is found to undergo a transition from Townsend regime, sub-glow regime to glow regime with increasing applied voltage amplitude. In the different regimes, charged particles and electric field display different dynamical behaviors. If the voltage amplitude is increased over a certain value, the discharge enters an asymmetric patterned discharge mode, and then transforms into the spatially chaotic state with out-of-order discharge channels. The reason for forming the one-dimensional self-organized pattern is mainly due to the so-called activation-inhibition effect resulting from the local high electron density region appearing in discharge space. Electrode arrangement is the reason that induces local high electron density.

  10. Characteristics of a micro-gap argon barrier discharge excited by a saw-tooth voltage at atmospheric pressure

    Science.gov (United States)

    Li, Xuechen; Zhang, Qi; Jia, Pengying; Chu, Jingdi; Zhang, Panpan; Dong, Lifang

    2017-03-01

    Using two water electrodes, a micro-gap dielectric barrier discharge excited by a saw-tooth voltage is investigated in atmospheric pressure argon. Through electrical and optical measurements, it is found that, at a lower driving frequency, a stepped discharge mode is obtained per half voltage cycle. Moreover, the duration and amplitude of the current plateau increase with the increase in the applied peak voltage. With the increase in the driving frequency, the stepped discharge mode transits into a pulsed one after a multi-peak mode. During this process, a diffuse discharge at a lower frequency transits into a filamentary one at a higher frequency. Temporal evolutions of the discharges are investigated axially based on fast photography. It is found that the stepped mode is in atmospheric pressure Townsend discharge (APTD) regime. However, there is a transition from APTD to atmospheric pressure glow discharge for the pulsed mode. Spectral intensity ratio of 391.4 nm to 337.1 nm is used to determine the averaged electron energy, which decreases with increasing peak voltage or driving frequency.

  11. Measurements of Rotational Temperatures in Atmospheric-Pressure Capillary Plasma Electrode (CPE) Discharge

    Science.gov (United States)

    Figus, Margaret; Abramzon, Nina; Becker, Kurt

    2003-10-01

    We report the results of rotational temperature measurements in atmospheric-pressure capillary plasma electrode (CPE) discharges in ambient air using the unresolved N2 second positive band. Assuming that the emitting N2 molecules can be described by a Maxwell-Boltzmann distribution characterized by a single rotational temperature, this temperature is determined from a fit of the measured emission spectrum to a calculated spectrum. If the emitting species are in equilibrium with the bulk gas in the plasma, then this temperature can be interpreted as the gas kinetic temperature in the plasma. We determined rotational temperatures for three different plasma regions: inside the capillary by analyzing radiation emitted along the axis of the capillary, between the capillaries, and perpendicular to the axis of the capillary. Each region has a different plasma density and, therefore, a different gas temperature with the plasma inside the capillary being the hottest. We also measured the rotational temperatures in each region as a function of the plasma power. As expected, the rotational temperatures increase with increasing discharge power. Work supported by the NSF and by ARO through a DURIP award.

  12. Discoloration of Congo Red by Rod-Plate Dielectric Barrier Discharge Processes at Atmospheric Pressure

    Science.gov (United States)

    Wu, Haixia; Fang, Zhi; Zhou, Tong; Lu, Chen; Xu, Yanhua

    2016-05-01

    A dielectric barrier discharge (DBD) reactor with a rod-plate electrode configuration was used for the oxidative decomposition of Congo red dye in an aqueous solution. Plasma was generated in the gas space above the water interface under atmospheric pressure. Discharge characteristics were analyzed by voltage-current waveforms. Effects of applied voltage, initial conductivity, and initial concentration were also analyzed. Congo red discoloration increased with increased applied voltage and decreased conductivity. The initial conductivity significantly influenced the Congo red discoloration. Under the same conditions, the highest discoloration rate was obtained at 25 mg/L. The presence of ferrous ions in the solutions had a substantial positive effect on Fenton dye degradation and flocculation. At an applied voltage of 20 kV, about 100% of dye was degraded after 4 min of Fe2+/DBD treatment. Results showed that adding a certain dosage of hydrogen peroxide to the wastewater could enhance the discoloration rate. Possible pathways of Congo red discoloration by DBD plasma were proposed based on GC/MS, FTIR, and UV-vis spectroscopy analyses. supported by National Natural Science Foundation of China (No. 51377075), the Natural Science Foundation of Jiangsu Province of China (Nos. BK20131412, BK20150951)

  13. Discoloration of Congo Red by Rod-Plate Dielectric Barrier Discharge Processes at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    WU Haixia; FANG Zhi; ZHOU Tong; LU Chen; XU Yanhua

    2016-01-01

    A dielectric barrier discharge (DBD) reactor with a rod-plate electrode configuration was used for the oxidative decomposition of Congo red dye in an aqueous solution.Plasma was generated in the gas space above the water interface under atmospheric pressure.Discharge characteristics were analyzed by voltage-current waveforms.Effects of applied voltage,initial conductivity,and initial concentration were also analyzed.Congo red discoloration increased with increased applied voltage and decreased conductivity.The initial conductivity significantly influenced the Congo red discoloration.Under the same conditions,the highest discoloration rate was obtained at 25 mg/L.The presence of ferrous ions in the solutions had a substantial positive effect on Fenton dye degradation and flocculation.At an applied voltage of 20 kV,about 100%of dye was degraded after 4 min of Fe2+/DBD treatment.Results showed that adding a certain dosage of hydrogen peroxide to the wastewater could enhance the discoloration rate.Possible pathways of Congo red discoloration by DBD plasma were proposed based on GC/MS,FTIR,and UV-vis spectroscopy analyses.

  14. Glyphosate contaminated soil remediation by atmospheric pressure dielectric barrier discharge plasma and its residual toxicity evaluation.

    Science.gov (United States)

    Wang, Tiecheng; Ren, Jingyu; Qu, Guangzhou; Liang, Dongli; Hu, Shibin

    2016-12-15

    Glyphosate was one of the most widely used herbicides in the world. Remediation of glyphosate-contaminated soil was conducted using atmospheric pressure dielectric barrier discharge (DBD) plasma. The feasibility of glyphosate degradation in soil was explored, and the soil leachate toxicity after remediation was assessed via a seed germination test. The experimental results showed that approximately 93.9% of glyphosate was degraded within 45min of DBD plasma treatment with an energy yield of 0.47gkWh(-1), and the degradation process fitted the first-order kinetic model. Increasing the discharge voltage and decreasing the organic matter content of the soil were both found to facilitate glyphosate degradation. There existed appropriate soil moisture to realize high glyphosate degradation efficiency. Glyphosate mineralization was confirmed by changes of total organic carbon (TOC), chemical oxygen demand (COD), PO4(3-) and NO3(-). The degradation intermediates including glycine, aminomethylphosphonic acid, acetic acid, formic acid, PO4(3-) and NO3(-), CO2 and CO were observed. A possible pathway for glyphosate degradation in the soil using this system was proposed. Based on the soil leachate toxicity test using wheat seed germination, the soil did not exhibit any hazardous effects following high-efficiency glyphosate degradation.

  15. Plasma polymers deposited in atmospheric pressure dielectric barrier discharges: Influence of process parameters on film properties

    Energy Technology Data Exchange (ETDEWEB)

    Fricke, Katja, E-mail: k.fricke@inp-greifswald.de [Leibniz Institute for Plasma Science and Technology e.V. (INP Greifswald), Felix-Hausdorff-Str. 2, 17489 Greifswald (Germany); Girard-Lauriault, Pierre-Luc [Plasma Processing Laboratory, Department of Chemical Engineering, McGill University, 3610 rue University, Montreal, QC H3A 0C5 (Canada); Weltmann, Klaus-Dieter [Leibniz Institute for Plasma Science and Technology e.V. (INP Greifswald), Felix-Hausdorff-Str. 2, 17489 Greifswald (Germany); Wertheimer, Michael R. [Department of Engineering Physics, École Polytechnique de Montréal, Box 6079, Station Centre-Ville, Montreal, QC H3C 3A7 (Canada)

    2016-03-31

    We present results on the deposition of plasma polymer (PP) films in a dielectric barrier discharge system fed with mixtures of argon or nitrogen carrier gas plus different hydrocarbon precursors, where the latter possess different carbon-to-hydrogen ratios: CH{sub 4} < C{sub 2}H{sub 6} < C{sub 2}H{sub 4} = C{sub 3}H{sub 6} < C{sub 2}H{sub 2}. The influence of precursor gas mixture and flow rate, excitation frequency, and absorbed power on PP film compositions and properties has been investigated. The discharge was characterized by electrical measurements, while the chemical compositions and structures of coatings were analysed by X-ray photoelectron spectroscopy, Fourier-transform infrared spectroscopy, total combustion, and elastic recoil detection analyses, the latter two for determining carbon-to-hydrogen ratios. Scanning electron microscopy was used to study the coatings' morphology, and profilometry for evaluating deposition rates. - Highlights: • Atmospheric pressure DBD is used to deposit organic hydrocarbon films. • High deposition rates can be achieved by varying the power and/or gas mixture ratio. • Process parameters affect the films' surface chemical composition and morphology. • Deposited films are not soluble in aqueous environment. • No delamination of coatings produced from argon plasma.

  16. A low power miniaturized dielectric barrier discharge based atmospheric pressure plasma jet

    Science.gov (United States)

    Divya Deepak, G.; Joshi, N. K.; Pal, Dharmendra Kumar; Prakash, Ram

    2017-01-01

    In this paper, a dielectric barrier discharge plasma based atmospheric pressure plasma jet has been generated in a floating helix and floating end ring electrode configuration using argon and helium gases. This configuration is subjected to a range of supply frequencies (10-25 kHz) and supply voltages (2-6 kV) at a fixed rate of gas flow rate (i.e., 1 l/min). The electrical characterization of the plasma jet has been carried out using a high voltage probe and current transformer. The current-voltage characteristics have been analyzed, and the consumed power has been estimated at different applied combinations for optimum power consumption at maximum jet length. The obtained optimum power and jet length for argon and helium gases are 12 mW and 32 mm, and 7.7 mW and 42 mm, respectively. It is inferred that besides the electrode configurations, the discharge gas is also playing a significant role in the low power operation of the cold plasma jet at maximum jet length. The obtained results are interpreted on the basis of penning processes.

  17. A comparative summary on streamers of positive corona discharges in water and atmospheric pressure gases

    Science.gov (United States)

    Tachibana, Kunihide; Motomura, Hideki

    2015-07-01

    From an intention of summarizing present understandings of positive corona discharges in water and atmospheric pressure gases, we tried to observe streamers in those media by reproducing and complementing previously reported results under a common experimental setup. We used a point-to-plane electrode configuration with different combinations of electrode gap (7 and 19 mm length) and pulsed power sources (0.25 and 2.5 ɛs duration). The general features of streamers were similar and the streamer-to-spark transition was also observed in both the media. However, in the details large differences were observed due to inherent nature of the media. The measured propagation speed of streamers in water of 0.035 × 106 ms-1 was much smaller than the speed in gases (air, N2 and Ar) from 0.4 to 1.1 × 106 ms-1 depending on species. In He the discharge looked glow-like and no streamer was observed. The other characteristics of streamers in gases, such as inception voltage, number of branches and thickness did also depend on the species. The thickness and the length of streamers in water were smaller than those in gases. From the volumetric expansion of a streamer in water after the discharge, the molecular density within the streamer medium was estimated to be rarefied from the density of water by about an order of magnitude in the active discharge phase. We derived also the electron density from the analysis of Stark broadened spectral lines of H and O atoms on the order of 1025 m-3 at the earlier time of the streamer propagation. The analyzed background blackbody radiation, rotational temperature of OH band emission and population density of Cu atomic lines yielded a consistent temperature of the streamer medium between 7000 and 10 000 K. Using the present data with a combination of the analysis of static electric field and previously reported results, we discuss the reason for the relatively low streamer inception voltage in water as compared to the large difference in the

  18. Study of an Atmospheric Pressure Plasma Jet of Argon Generated by Column Dielectric Barrier Discharge

    Science.gov (United States)

    Nur, M.; Kinandana, A. W.; Winarto, P.; Muhlisin, Z.; Nasrudin

    2016-11-01

    An atmospheric of argon plasma jet was generated by using column dielectric barrier discharge has been investigated. In this study, argon gas was passed through the capillary column by regulating the flow rate of gas. This atmospheric pressure plasma jet (APPJ) was generated by a sinusoidal AC high voltage in the range of 0.4 kV to 10 kV and at frequencies of 15 kHz and 26 kHz. APPJ has been produced with flow rate of argon gas from 1 litter/min - 10 litters/min. The electric current has been taken with variation of voltage and each interval argon gas flow rate of 1 litter/min. The results show that electric current increase linearly and then it trends to saturation condition by the increasing of applied voltage. We found also that the length of the plasma jet increase by augmenting of applied voltage both for frequencies of 15 kHz and 26 kHz. Furthermore, our results show that length of plasma jet optimum for flow rate of argon gas of 2 litters/minute. In addition, we obtained that the larger applied voltage, the greater the temperature of the plasma jet.

  19. Polymer Surface Treatment by Atmospheric Pressure Low Temperature Surface Discharge Plasma:Its Characteristics and Comparison with Low Pressure Oxygen Plasma Treatment

    Institute of Scientific and Technical Information of China (English)

    Atsushi KUWABARA; Shin-ichi KURODA; Hitoshi KUBOTA

    2007-01-01

    The polymer treatment with a low-temperature plasma jet generated on the atmospheric pressure surface discharge (SD) plasma is performed.The change of the surface property over time,in comparison with low pressure oxygen (O2) plasma treatment,is examined.As one compares the treatment by atmospheric pressure plasma to that by the low pressure O2 plasma of PS (polystyrene) the treatment effects were almost in complete agreement.However,when the atmospheric pressure plasma was used for PP(polypropylene),it produced remarkable hydrophilic effects.

  20. DC negative corona discharge in atmospheric pressure helium: transition from the corona to the ‘normal’ glow regime

    Science.gov (United States)

    Hasan, Nusair; Antao, Dion S.; Farouk, Bakhtier

    2014-06-01

    Direct current (dc) negative corona discharges in atmospheric pressure helium are simulated via detailed numerical modeling. Simulations are conducted to characterize the discharges in atmospheric helium for a pin plate electrode configuration. A self-consistent two-dimensional hybrid model is developed to simulate the discharges and the model predictions are validated with experimental measurements. The discharge model considered consists of momentum and energy conservation equations for a multi-component (electrons, ions, excited species and neutrals) gas mixture, conservation equations for each component of the mixture and state relations. A drift-diffusion approximation for the electron and the ion fluxes is used. A model for the external circuit driving the discharge is also considered and solved along with the discharge model. Many of the key features of a negative corona discharge, namely non-linear current-voltage characteristics, spatially flat cathode current density and glow-like discharge in the high current regime are displayed in the predictions. A transition to the ‘normal’ glow discharge from the corona discharge regime is also observed. The transition is identified from the calculated current-voltage characteristic curve and is characterized by the radial growth of the negative glow and the engulfment of the cathode wire.

  1. Simulation Tool for Dielectric Barrier Discharge Plasma Actuators at Atmospheric and Sub-Atmospheric Pressures: SBIR Phase I Final Report

    Science.gov (United States)

    Likhanskii, Alexandre

    2012-01-01

    This report is the final report of a SBIR Phase I project. It is identical to the final report submitted, after some proprietary information of administrative nature has been removed. The development of a numerical simulation tool for dielectric barrier discharge (DBD) plasma actuator is reported. The objectives of the project were to analyze and predict DBD operation at wide range of ambient gas pressures. It overcomes the limitations of traditional DBD codes which are limited to low-speed applications and have weak prediction capabilities. The software tool allows DBD actuator analysis and prediction for subsonic to hypersonic flow regime. The simulation tool is based on the VORPAL code developed by Tech-X Corporation. VORPAL's capability of modeling DBD plasma actuator at low pressures (0.1 to 10 torr) using kinetic plasma modeling approach, and at moderate to atmospheric pressures (1 to 10 atm) using hydrodynamic plasma modeling approach, were demonstrated. In addition, results of experiments with pulsed+bias DBD configuration that were performed for validation purposes are reported.

  2. Structure of the quasi-steady electromagnetic field of a high frequency industrial discharge at atmospheric pressure

    Science.gov (United States)

    Kirpichnikov, A. P.

    1994-02-01

    An approximate analytical solution of the Maxwell equations is obtained; this solution satisfactorily describes the structure of the quasi-steady electromagnetic field of a high-frequency atmospheric-pressure inductional discharge close to the axis of the plasma bunch.

  3. Surface modification of acrylate intraocular lenses with dielectric barrier discharge plasma at atmospheric pressure

    Institute of Scientific and Technical Information of China (English)

    WANG Yao; LIU ZhenMei; XU ZhiKang; YAO Ke

    2009-01-01

    Surface modification with dielectric barrier discharge (DBD) plasma was carried out at atmospheric pressure (argon as the discharge gas) to improve the biocompatibility of hydrophobic acrylate intraocular lens (IOL). Changes of the plasma-treated IOL surface in chemical composition,morphology and hydrophilicity were comprehensively evaluated by X-ray photoelectron spectroscopy (XPS),field emission scanning electron microscopy (FESEM),atomic force microscopy (AFM) and water contact angle (WCA) measurements. The surface biocompatibility of the untreated and plasma-treated IOLs was compared with the adhesion behavior of platelets,macrophages and lens epithelial cells (LECs) in vitro. After DBD plasma treatment,the hydrophilicity of the IOL surface was obviously improved. The changes in WCA with treatment extension may be attributed to both the introduction of oxygen or/and nitrogen-containing polar groups and the increase of surface roughness induced by plasma etching effect. The existence of low molecular weight oxidized material (LMWOM) was proved on the plasma treated IOL which was caused by the chain scission effect of the plasma treatment. The plasma-treated lOLs resisted the adhesion of platelets and macrophages significantly. The LECs spreading and proliferation were postponed on the lOLs plasma-treated for more than 180 s,with a well maintained epithelial phenotype of LECs. The IOL biocompatibility was improved after the DBD plasma treatment. We speculate that slighter foreign-body reaction and later incidence of anterior capsule opacification (ACO) may be expected after implantation of the argon DBD plasma-treated IOL.

  4. Surface modification of acrylate intraocular lenses with dielectric barrier discharge plasma at atmospheric pressure

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Surface modification with dielectric barrier discharge(DBD) plasma was carried out at atmospheric pressure(argon as the discharge gas) to improve the biocompatibility of hydrophobic acrylate intraocular lens(IOL).Changes of the plasma-treated IOL surface in chemical composition,morphology and hydrophilicity were comprehensively evaluated by X-ray photoelectron spectroscopy(XPS),field emission scanning electron microscopy(FESEM),atomic force microscopy(AFM) and water contact angle(WCA) measurements.The surface biocompatibility of the untreated and plasma-treated IOLs was compared with the adhesion behavior of platelets,macrophages and lens epithelial cells(LECs) in vitro.After DBD plasma treatment,the hydrophilicity of the IOL surface was obviously improved.The changes in WCA with treatment extension may be attributed to both the introduction of oxygen or/and nitrogen-containing polar groups and the increase of surface roughness induced by plasma etching effect.The existence of low molecular weight oxidized material(LMWOM) was proved on the plasma-treated IOL which was caused by the chain scission effect of the plasma treatment.The plasma-treated IOLs resisted the adhesion of platelets and macrophages significantly.The LECs spreading and proliferation were postponed on the IOLs plasma-treated for more than 180 s,with a well maintained epithelial phenotype of LECs.The IOL biocompatibility was improved after the DBD plasma treatment.We speculate that slighter foreign-body reaction and later incidence of anterior capsule opacification(ACO) may be expected after implantation of the argon DBD plasma-treated IOL.

  5. Laser diagnostics on atmospheric pressure discharge plasmas, including cryoplasmas, in environments around room and cryogenic temperature

    Science.gov (United States)

    Sakakibara, Noritaka; Muneoka, Hitoshi; Urabe, Keiichiro; Yasui, Ryoma; Sakai, Osamu; Terashima, Kazuo

    2017-04-01

    Cryoplasmas, the plasma gas temperature (T g) of which can be controlled continuously below room temperature, show various unique and advantageous properties depending on T g. Recently, the T g dependence of plasma chemistry related to metastable helium (Hem) has been revealed in helium cryoplasmas. However, T g was only estimated by thermal calculation from the temperature outside the plasmas. In this study, for better evaluation of T g, near-infrared laser heterodyne interferometry (NIR-LHI) measurements were conducted in atmospheric pressure helium pulsed discharge plasmas at around room and cryogenic ambient temperatures (T a). The maximum difference between T g and T a was evaluated as 47 K at T a  =  300 K with 282 mW power consumption. To further investigate the T g dependence of plasma chemical reactions related to Hem, laser absorption spectroscopy (LAS) was performed on the same discharge plasmas to measure the Hem density and lifetime. The Hem lifetime was longer at lower T g, i.e. the lifetime at T g  =  145 K (9.6 µs) was seven times longer than that at T g  =  386 K (1.4 µs). By comparing the results with the numerically simulated rates of Hem quenching reactions taking T g into account, the mechanism of the Hem quenching reaction was revealed to vary with T g even though the main quenching reaction was a three-body collision at all T g. In this manner, the combination of NIR-LHI with LAS led directly to the T g dependence of Hem quenching reactions.

  6. Gene Transfection Method Using Atmospheric Pressure Dielectric-Barrier Discharge Plasmas

    Science.gov (United States)

    Sasaki, Shota; Kanzaki, Makoto; Kaneko, Toshiro

    2013-09-01

    Gene transfection which is the process of deliberately introducing nucleic acids into cells is expected to play an important role in medical treatment because the process is necessary for gene therapy and creation of induced pluripotent stem (iPS) cells. However, the conventional transfection methods have some problems, so we focus attention on promising transfection methods by atmospheric pressure dielectric-barrier discharge (AP-DBD) plasmas. AP-DBD He plasmas are irradiated to the living cell covered with genes. Preliminarily, we use fluorescent dye YOYO-1 instead of the genes and use LIVE/DEAD Stain for cell viability test, and we analyze the transfection efficiency and cell viability under the various conditions. It is clarified that the transfection efficiency is strongly dependence on the plasma irradiation time and cell viability rates is high rates (>90%) regardless of long plasma irradiation time. These results suggest that ROS (Reactive Oxygen Species) and electric field generated by the plasma affect the gene transfection. In addition to this (the plasma irradiation time) dependency, we now investigate the effect of the plasma irradiation under the various conditions.

  7. Liquid-phase reactions induced by atmospheric pressure glow discharge with liquid electrode

    Science.gov (United States)

    Tochikubo, Fumiyoshi; Shirai, Naoki; Uchida, Satoshi

    2014-12-01

    We experimentally investigated some of the initial reactions in a liquid induced by electron or positive-ion irradiation from an atmospheric-pressure dc glow discharge in contact with the liquid. We used an H-shaped glass reactor to observe the effects of electron irradiation and positive-ion irradiation on the liquid-phase reaction separately and simultaneously. Aqueous solutions of NaCl, AgNO3, HAuCl4, and FeCl2 are used as the electrolyte. Solutions of AgNO3 and HAuCl4 are used for the generation of Ag and Au nanoparticles, respectively. Solution of FeCl2 is used for the generation of ferromagnetic particles. Experimental results showed that electron irradiation of the liquid surface generates OH- in water and that positive-ion irradiation of the liquid surface generates H+ in water even without the dissolution of gas-phase nitrogen oxide. A possible reaction process is qualitatively discussed. We also showed that the control of reductive and oxidative environment in the liquid is possible not only by the gas composition for the plasma generation but also by the liquid composition.

  8. Surface Modification of Fluororubber Using Atmospheric Pressure Dielectric Barrier Discharge (DBD)

    Institute of Scientific and Technical Information of China (English)

    TONG Wei; LU Canhui; CAI Yongkun; HUANG Yigang

    2007-01-01

    Fluoride rubber F2311 film, an alternating copolymer of CF2-CFC1 (CTFE) and CH2-CF2 (VF2) components, was treated by atmospheric pressure dielectric barrier discharge (DBD) in air. The surface structure, topography and surface chemistry of the treated F2311 films were characterized by contact angle measurement, atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS), respectively. The experimental results showed that a short time air plasma treatment led to morphological, wettability and chemical changes in the F2311 films. The surface hydrophilicity increased greatly after the plasma treatment, the static water contact angle decreased from 98.6° to 32°, and oxygen containing groups (C=O, O-C=O, etc. ) were introduced. Atomic force microscopy revealed that plasma produced by DBD etched F2311 films obviously. The roughness of the samples increased remarkably with the formation of peaks and valleys on the treated surfaces. The increased surface wettability may be correlated with both the introduction of hydrophilic groups due to air plasma oxidation of the surface and the change in surface morphology etched by DBD.

  9. Electric field development in γ-mode radiofrequency atmospheric pressure glow discharge in helium

    Science.gov (United States)

    Navrátil, Zdeněk; Josepson, Raavo; Cvetanović, Nikola; Obradović, Bratislav; Dvořák, Pavel

    2016-06-01

    Time development of electric field strength during radio-frequency sheath formation was measured using Stark polarization spectroscopy in a helium γ-mode radio-frequency (RF, 13.56 MHz) atmospheric pressure glow discharge at high current density (3 A cm-2). A method of time-correlated single photon counting was applied to record the temporal development of spectral profile of He I 492.2 nm line with a sub-nanosecond temporal resolution. By fitting the measured profile of the line with a combination of pseudo-Voigt profiles for forbidden (2 1P-4 1F) and allowed (2 1P-4 1D) helium lines, instantaneous electric fields up to 32 kV cm-1 were measured in the RF sheath. The measured electric field is in agreement with the spatially averaged value of 40 kV cm-1 estimated from homogeneous charge density RF sheath model. The observed rectangular waveform of the electric field time development is attributed to increased sheath conductivity by the strong electron avalanches occurring in the γ-mode sheath at high current densities.

  10. Online diagnosis of electron excitation temperature in CH4+H2 discharge plasma at atmospheric pressure by optical emission spectra

    Institute of Scientific and Technical Information of China (English)

    CUI JinHua; XU ZhenFeng; ZHANG JiaLiang; NIE QiuYue; XU GenHui; REN LongLiang

    2008-01-01

    Methane coupling under low temperature plasmas at atmospheric pressure is a green process by use of renewable sources of energy.In this study,CH4+H2 dis-charge plasma was on-line diagnosed by optical emission spectra so as to char-acterize the discharge system and to do spade work for the optimization of the technical parameters for future commercial production of methane coupling under plasmas.The study was focused on a calculation method for the online diagnosis of the electron excitation temperature in CH4+H2 discharge plasma at atmospheric pressure.The diagnostic method is easy,efficient and fairly precise.A serious er-ror in a literature was corrected during the reasoning of its series of equations formerly used to calculate electron temperatures in plasmas.

  11. Application of diffuse discharges of atmospheric pressure formed by runaway electrons for modification of copper and stainless steel surface

    Energy Technology Data Exchange (ETDEWEB)

    Tarasenko, V. F., E-mail: VFT@loi.hcei.tsc.ru; Shulepov, M. A.; Erofeev, M. V. [Russian Academy of Sciences, Institute of High Current Electronics, Siberian Branch (Russian Federation)

    2015-12-15

    The results of studies devoted to the influence of a runaway electron pre-ionized diffuse discharge (REP DD) formed in air and nitrogen at atmospheric pressure on the surface of copper and stainless steel are presented. Nanosecond high-voltage pulses were used to obtain REP DD in different gases at high pressures in a chamber with a flat anode and a cathode possessing a small radius of curvature. This mode of discharge was implemented owing to the generation of runaway electrons and X-rays. The conditions under which the surface of copper and stainless steel was cleaned from carbon and oxidized are described.

  12. Online diagnosis of electron excitation temperature in CH4+H2 discharge plasma at atmospheric pressure by optical emission spectra

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Methane coupling under low temperature plasmas at atmospheric pressure is a green process by use of renewable sources of energy. In this study, CH4+H2 dis- charge plasma was on-line diagnosed by optical emission spectra so as to char- acterize the discharge system and to do spade work for the optimization of the technical parameters for future commercial production of methane coupling under plasmas. The study was focused on a calculation method for the online diagnosis of the electron excitation temperature in CH4+H2 discharge plasma at atmospheric pressure. The diagnostic method is easy, efficient and fairly precise. A serious er- ror in a literature was corrected during the reasoning of its series of equations formerly used to calculate electron temperatures in plasmas.

  13. Spatial-Temporal Patterns in a Dielectric Barrier Discharge under Narrow Boundary Conditions in Argon at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    LI Xue-Chen; JIA Peng-Ying; ZHAO Na

    2011-01-01

    @@ Pattern formation phenomena are investigated in a dielectric barrier discharge under narrow boundary conditions in argon at atmospheric pressure.The discharge shows various scenarios with the increasing applied voltage.This is the first observation of alternating single spot and pair spots pattern and of a moving striation pattern in a dielectric barrier discharge system.The spatial-temporal correlations between discharge filaments in these patterns are measured by an optical method.The results show that the zigzag pattern is an interleaving of two sub-structure patterns, which ignites once for each sub-pattern per half cycle of the applied voltage.There is a temporal sequence inversion in consecutive half-cycles for the two sub-patterns.The pattern of alternating single spot and pair spots is also an interleaving of two sub-structure patterns.However, the pair spots sub-pattern ignites twice and the single spot sub-pattern ignites once per half cycle of the applied voltage.%Pattern formation phenomena are investigated in a dielectric barrier discharge under narrow boundary conditions in argon at atmospheric pressure. The discharge shows various scenarios with the increasing applied voltage.This is the first observation of alternating single spot and pair spots pattern and of a moving striation pattern in a dielectric barrier discharge system. The spatial-temporal correlations between discharge filaments in these patterns are measured by an optical method. The results show that the zigzag pattern is an interleaving of two sub-structure patterns, which ignites once for each sub-pattern per half cycle of the applied voltage. There is a temporal sequence inversion in consecutive half-cycles for the two sub-patterns. The pattern of alternating single spot and pair spots is also an interleaving of two sub-structure patterns. However, the pair spots sub-pattern ignites twice and the single spot sub-pattern ignites once per half cycle of the applied voltage.

  14. The back-diffusion effect of air on the discharge characteristics of atmospheric-pressure radio-frequency glow discharges using bare metal electrodes

    Science.gov (United States)

    Sun, Wen-Ting; Liang, Tian-Ran; Wang, Hua-Bo; Li, He-Ping; Bao, Cheng-Yu

    2007-05-01

    Radio-frequency (RF), atmospheric-pressure glow discharge (APGD) plasmas using bare metal electrodes have promising prospects in the fields of plasma-aided etching, deposition, surface treatment, disinfection, sterilization, etc. In this paper, the discharge characteristics, including the breakdown voltage and the discharge voltage for sustaining a stable and uniform α mode discharge of the RF APGD plasmas are presented. The experiments are conducted by placing the home-made planar-type plasma generator in ambient and in a vacuum chamber, respectively, with helium as the primary plasma-forming gas. When the discharge processes occur in ambient, particularly for the lower plasma-working gas flow rates, the experimental measurements show that it is the back-diffusion effect of air in atmosphere, instead of the flow rate of the gas, that results in the obvious decrease in the breakdown voltage with increasing plasma-working gas flow rate. Further studies on the discharge characteristics, e.g. the luminous structures, the concentrations and distributions of chemically active species in plasmas, with different plasma-working gases or gas mixtures need to be conducted in future work.

  15. The back-diffusion effect of air on the discharge characteristics of atmospheric-pressure radio-frequency glow discharges using bare metal electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Sun Wenting; Liang Tianran; Wang Huabo; Li Heping; Bao Chengyu [Department of Engineering Physics, Tsinghua University, Beijing 100084 (China)

    2007-05-15

    Radio-frequency (RF), atmospheric-pressure glow discharge (APGD) plasmas using bare metal electrodes have promising prospects in the fields of plasma-aided etching, deposition, surface treatment, disinfection, sterilization, etc. In this paper, the discharge characteristics, including the breakdown voltage and the discharge voltage for sustaining a stable and uniform {alpha} mode discharge of the RF APGD plasmas are presented. The experiments are conducted by placing the home-made planar-type plasma generator in ambient and in a vacuum chamber, respectively, with helium as the primary plasma-forming gas. When the discharge processes occur in ambient, particularly for the lower plasma-working gas flow rates, the experimental measurements show that it is the back-diffusion effect of air in atmosphere, instead of the flow rate of the gas, that results in the obvious decrease in the breakdown voltage with increasing plasma-working gas flow rate. Further studies on the discharge characteristics, e.g. the luminous structures, the concentrations and distributions of chemically active species in plasmas, with different plasma-working gases or gas mixtures need to be conducted in future work.

  16. Final Report DE-FG02-00ER54583: "Physics of Atmospheric Pressure Glow Discharges" and "Nanoparticle Nucleation and Dynamics in Low-Pressure Plasmas"

    Energy Technology Data Exchange (ETDEWEB)

    Uwe Kortshagen; Joachim Heberlein; Steven L. Girshick

    2009-06-01

    This project was funded over two periods of three years each, with an additional year of no-cost extension. Research in the first funding period focused on the physics of uniform atmospheric pressure glow discharges, the second funding period was devoted to the study of the dynamics of nanometer-sized particles in plasmas.

  17. Surface modification of nanofibrillated cellulose films by atmospheric pressure dielectric barrier discharge

    DEFF Research Database (Denmark)

    Siró, Istvan; Kusano, Yukihiro; Norrman, Kion

    2013-01-01

    of atmospheric pressure plasma treatment, the water contact angle of NFC films increased and the values were comparable with those of PLA films. On the other hand, surface chemical characterization revealed inhomogeneity of the plasma treatment and limited improvement in adhesion between NFC and PLA films...

  18. Student Award Finalist - Simulation of the reignition of atmospheric pressure air discharges behind dielectric obstacles: comparison with experiments

    Science.gov (United States)

    Pechereau, Francois; Bourdon, Anne

    2013-09-01

    In recent years, experimental studies on plasma assisted catalysis for flue gas treatment have shown a significant reduction of pollutants at a low energetic cost. Catalyst supports are either random or organized two phase media such as pellets, monoliths or porous media. Then, in plasma reactors, atmospheric pressure discharges have to interact with many obstacles and to propagate in microcavities and pores. To better understand the discharge dynamics in these complex structures, experiments have been carried out at LPGP (Orsay, France) in a point-to-plane geometry with a dielectric plane obstacle placed in the discharge path. In this work, we have carried out discharge simulations in the experimental geometry. We have compared the dynamics of the discharge ignited at the point and its impact on the dielectric surface. Then, we have compared the conditions of a discharge reignition behind the dielectric obstacle. A good qualitative agreement with experiments has been obtained but to improve the quantitative comparison, we have carried out a detailed parametric numerical study. In this work, we will focus on the influence of the level of seed charges on the discharge reignition and discuss several physical processes that could have an impact on the level of seed charges. ALVEOPLAS project (Grant No. ANR-08-BLAN-0159-01).

  19. Study of nanosecond discharges in different H2 air mixtures at atmospheric pressure for plasma-assisted applications

    Science.gov (United States)

    Bourdon, Anne; Kobayashi, Sumire; Bonaventura, Zdenek; Tholin, Fabien; Popov, Nikolay

    2016-09-01

    This paper presents 2D simulations of nanosecond pulsed discharges between two point electrodes in different H2/air mixtures and in air at atmospheric pressure. A fluid model is coupled with detailed kinetic schemes for air and different H2/air mixtures to simulate the discharge dynamics. First, as the positive and negative ionization waves propagate in the interelectrode gap, it has been observed that in H2/air mixtures with equivalence ratios between 0.3 and 2, major positive ions produced by the nanosecond discharge are N2+,O2+and HN2+.The discharge dynamics is shown to vary only slightly for equivalence ratios of the H2/air mixture between 0.3 and 2. Then, as the discharge transits to a nanosecond spark discharge, we have studied the different chemical reactions that lead to fast gas heating and to the production of radicals, as O,H and OH. Both thermal and chemical effects of the nanosecond spark discharge are of interest for plasma assisted combustion applications. This work has been supported by the project DRACO (Grant No. ANR-13-IS09-0004) and the french russian LIA Kappa.

  20. A volume pulsed corona formed during nanosecond pulsed periodic discharge of negative polarity in narrow gaps with airflow at atmospheric pressure

    Science.gov (United States)

    Lepekhin, N. M.; Priseko, Yu. S.; Puresev, N. I.; Filippov, V. G.

    2014-06-01

    A volume mode of spatially homogeneous nanosecond pulsed-periodic corona discharge of negative polarity has been obtained using an edge-to-edge electrode geometry in narrow gaps with airflow at atmospheric pressure and natural humidity. The parameters of discharge are estimated, and a factor limiting the power deposited in discharge is determined.

  1. Characteristics in the jet region of helium radio-frequency atmospheric-pressure glow discharge with array generators

    Directory of Open Access Journals (Sweden)

    Zhi-Bin Wang

    2015-09-01

    Full Text Available The two-dimensional spatially extended atmospheric plasma arrays by many parallel radio-frequency glow discharge plasma jets packed densely, represent a feature option of large-scale low-temperature atmospheric plasma technologies with distinct capability of directed delivery of reactive species and good insusceptibility to sample variations. However, it is still a challenge to form plasma jet with large area of uniform active species on a downstream substrate due to the complex interactions between individual jets. This paper proposes to numerically study the strategy and mechanism of control/modulation for the array discharge to produce two-dimensional plasma uniformity in the downstream working area. In this work, a two dimensional fluid model is employed to investigate the characteristics in the jet region of helium radio-frequency atmospheric-pressure glow discharge (RF APGD with array generators. The influences of upstream discharge characteristics, gas flow and their cooperative effects on the distribution of species densities, gas temperatures and the uniformity of active species in the material treating area is studied, and the essential strategy for the modulation method is acquired. The results will be significant for deep understanding of coupling behaviors of multiple plasma plumes in the RF APGD array and applications of the technology.

  2. [Research on electron density in DC needle-plate corona discharge at atmospheric pressure].

    Science.gov (United States)

    Liu, Zhi-Qiang; Guo, Wei; Liu, Tao-Tao; Wu, Wen-Shuo; Liu, Shu-Min

    2013-11-01

    Using needle-plate discharge device, corona discharge experiment was done in the atmosphere. Through photo of spot size of light-emitting area, the relationship between the voltage and thickness of corona layer was discussed. When the distance between tip and plate is fixed, the thickness of corona layer increases with the increase in voltage; when the voltage is fixed, the thickness of corona layer decreases with the increase in the distance between tip and plate. As spectral intensity of N2 (C3pi(u)) (337.1 nm)reflects high energy electron density, it was measured with emission spectrometry. The results show that high energy electron density is the biggest near the needle tip and the relationship between high energy electron density and voltage is basically linear increasing. Fixing voltage, high energy electron density decreases with the increase in the distance between tip and plate. When the voltage and the distance between tip and plate are fixed, the high energy electron density increases with the decrease in the curvature radius of needle tip. These results are of great importance for the study of plasma parameters of corona discharge.

  3. Three distinct modes in a surface micro-discharge in atmospheric pressure He + N{sub 2} mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Li, Dong; Liu, Dingxin, E-mail: liudingxin@mail.xjtu.edu.cn; He, Tongtong; Li, Qiaosong; Wang, Xiaohua [State Key Laboratory of Electrical Insulation and Power Equipment, Center for Plasma Biomedicine, Xi' an Jiaotong University, Xi' an 710049 (China); Kong, Michael G. [State Key Laboratory of Electrical Insulation and Power Equipment, Center for Plasma Biomedicine, Xi' an Jiaotong University, Xi' an 710049 (China); Frank Reidy Center for Bioelectrics, Old Dominion University, Norfolk, Virginia 23508 (United States); Department of Electrical and Computer Engineering, Old Dominion University, Norfolk, Virginia 23529 (United States)

    2015-12-15

    A surface micro-discharge in atmospheric pressure He + N{sub 2} mixtures is studied in this paper with an emphasis on the discharge modes. With the N{sub 2} admixture increasing from 0.1% to 20%, the discharge evolves from a spatially diffuse mode to a filamentary mode during positive half-cycles of the applied voltage. However during the negative half-cycles, an additional patterned mode emerges between the diffuse and the filamentary modes, which has not been reported before to exist in surface micro-discharges. In the diffuse and patterned modes, the plasmas cover almost the entirety of the mesh area during one cycle after plasma ignition in all mesh elements, and the discharge power increases linearly with the applied voltage. In contrast, plasma coverage of the mesh area is only partial in the filamentary mode and the plasma is more unstable with the discharge power increasing exponentially with the applied voltage. As the surface micro-discharge evolves through the three modes, the density of excited species changes significantly, for instance, the density of N{sub 2}{sup +}(B) drops by ∼20-fold from [N{sub 2}] = 0.2% to 20%. The N{sub 2}{sup +}(B) is predicted to be generated mainly through successive processes of Penning ionization by helium metastables and electron-impact excitation of N{sub 2}{sup +}(X), the latter is most responsible for the density decrease of N{sub 2}{sup +}(B) because much more N{sub 2}{sup +}(X) is converted to N{sub 4}{sup +}(X) as the increase of N{sub 2} fraction. Also, the electron density and electron temperature decrease with the discharge mode transition.

  4. Influence of surface emission processes on a fast-pulsed dielectric barrier discharge in air at atmospheric pressure

    Science.gov (United States)

    Pechereau, François; Bonaventura, Zdeněk; Bourdon, Anne

    2016-08-01

    This paper presents simulations of an atmospheric pressure air discharge in a point-to-plane geometry with a dielectric layer parallel to the cathode plane. Experimentally, a discharge reignition in the air gap below the dielectrics has been observed. With a 2D fluid model, it is shown that due to the fast rise of the high voltage applied and the sharp point used, a first positive spherical discharge forms around the point. Then this discharge propagates axially and impacts the dielectrics. As the first discharge starts spreading on the upper dielectric surface, in the second air gap with a low preionization density of {{10}4}~\\text{c}{{\\text{m}}-3} , the 2D fluid model predicts a rapid reignition of a positive discharge. As in experiments, the discharge reignition is much slower, a discussion on physical processes to be considered in the model to increase the reignition delay is presented. The limit case with no initial seed charges in the second air gap has been studied. First, we have calculated the time to release an electron from the cathode surface by thermionic and field emission processes for a work function φ \\in ≤ft[3,4\\right] eV and an amplification factor β \\in ≤ft[100,220\\right] . Then a 3D Monte Carlo model has been used to follow the dynamics of formation of an avalanche starting from a single electron emitted at the cathode. Due to the high electric field in the second air gap, we have shown that in a few nanoseconds, a Gaussian cloud of seed charges is formed at a small distance from the cathode plane. This Gaussian cloud has been used as the initial condition of the 2D fluid model in the second air gap. In this case, the propagation of a double headed discharge in the second air gap has been observed and the reignition delay is in rather good agreement with experiments.

  5. An experimental study on discharge characteristics in a pulsed-dc atmospheric pressure CH3OH/Ar plasma jet

    Science.gov (United States)

    Qian, Muyang; Liu, Sanqiu; Yang, Congying; Pei, Xuekai; Lu, Xinpei; Zhang, Jialiang; Wang, Dezhen

    2016-10-01

    Recently, C/H/Ar plasma discharges found enormous potential and possibility in carbonaceous compounds conversion and production. In this work, a pulsed-dc CH3OH/Ar plasma jet generated at atmospheric pressure is investigated by means of optical and electrical diagnosis concerning the variation of its basic parameters, absolute concentration of OH radicals, and plasma temperature with different CH3OH/Ar volume ratios, in the core region of discharge with needle-to-ring electrode configuration. The voltage-current characteristics are also measured at different CH3OH/Ar ratios. Laser-induced fluorescence (LIF) results here show that only small amounts of added methanol vapor to argon plasma (about 0.05% CH3OH/Ar volume ratio) is favorable for the production of OH radicals. The optical emission lines of CH, CN, and C2 radicals have been detected in the CH3OH/Ar plasma. And, the plasma temperatures increase with successive amount of added methanol vapor to the growth plasma. Moreover, qualitative discussions are presented regarding the mechanisms for methanol dissociation and effect of the CH3OH component on the Ar plasma discharge at atmospheric pressure.

  6. Transitions between corona, glow, and spark regimes of nanosecond repetitively pulsed discharges in air at atmospheric pressure

    Science.gov (United States)

    Pai, David Z.; Lacoste, Deanna A.; Laux, Christophe O.

    2010-05-01

    In atmospheric pressure air preheated from 300 to 1000 K, the nanosecond repetitively pulsed (NRP) method has been used to generate corona, glow, and spark discharges. Experiments have been performed to determine the parameter space (applied voltage, pulse repetition frequency, ambient gas temperature, and interelectrode gap distance) of each discharge regime. In particular, the experimental conditions necessary for the glow regime of NRP discharges have been determined, with the notable result that there exists a minimum and maximum gap distance for its existence at a given ambient gas temperature. The minimum gap distance increases with decreasing gas temperature, whereas the maximum does not vary appreciably. To explain the experimental results, an analytical model is developed to explain the corona-to-glow (C-G) and glow-to-spark (G-S) transitions. The C-G transition is analyzed in terms of the avalanche-to-streamer transition and the breakdown field during the conduction phase following the establishment of a conducting channel across the discharge gap. The G-S transition is determined by the thermal ionization instability, and we show analytically that this transition occurs at a certain reduced electric field for the NRP discharges studied here. This model shows that the electrode geometry plays an important role in the existence of the NRP glow regime at a given gas temperature. We derive a criterion for the existence of the NRP glow regime as a function of the ambient gas temperature, pulse repetition frequency, electrode radius of curvature, and interelectrode gap distance.

  7. NO density and gas temperature measurements in atmospheric pressure nanosecond repetitively pulsed (NRP) discharges by Mid-IR QCLAS

    Science.gov (United States)

    Simeni Simeni, Marien; Stancu, Gabi-Daniel; Laux, Christophe

    2014-10-01

    Nitric oxide is a key species for many processes: in combustion, in human skin physiology... Recently, NO-ground state absolute density measurements produced by atmospheric pressure NRP discharges were carried out in air as a function of the discharge parameters, using Quantum Cascade Laser Absorption Spectroscopy. These measurements were space averaged and performed in the post-discharge region in a large gas volume. Here we present radial profiles of NO density and temperature measured directly in the discharge for different configurations. Small plasma volume and species densities, high temperature and EM noise environment make the absorption diagnostic challenging. For this purpose the QCLAS sensitivity was improved using a two-detector system. We conducted lateral absorbance measurements with a spatial resolution of 300 μm for two absorption features at 1900.076 and 1900.517 cm-1. The radial temperature and NO density distributions were obtained from the Abel inverted lateral measurements. Time averaged NO densities of about 1.E16 cm-3 and gas temperature of about 1000K were obtained in the center of the discharge. PLASMAFLAME Project (Grant No ANR-11-BS09-0025).

  8. Numerical Study of Pulsed Dielectric Barrier Discharge at Atmospheric Pressure Under the Needle-Plate Electrode Configuration

    Institute of Scientific and Technical Information of China (English)

    WANG Yanhui; YE Huanhuan; ZHANG Jiao; WANG Qi; ZHANG Jie; WANG Dezhen

    2016-01-01

    In this paper,we study the characteristics of atmospheric-pressure pulsed dielectric barrier discharge (DBD) under the needle-plate electrode configuration using a one-dimensional self-consistent fluid model.The results show that,the DBDs driven by positive pulse,negative pulse and bipolar pulse possess different behaviors.Moreover,the two discharges appearing at the rising and the falling phases of per voltage pulse also have different discharge regimes.For the case of the positive pulse,the breakdown field is much lower than that of the negative pulse,and its propagation characteristic is different from the negative pulse DBD.When the DBD is driven by a bipolar pulse voltage,there exists the interaction between the positive and negative pulses,resulting in the decrease of the breakdown field of the negative pulse DBD and causing the change of the discharge behaviors.In addition,the effects of the discharge parameters on the behaviors of pulsed DBD in the needle-plate electrode configuration are also studied.

  9. Enhancement of antioxidant effects of naringin after atmospheric pressure dielectric barrier discharge plasma treatment.

    Science.gov (United States)

    Kim, Tae Hoon; Jang, Soo Jeung; Chung, Hyung-Wook; Kim, Hyun-Joo; Yong, Hae In; Choe, Wonho; Jo, Cheorun

    2015-03-15

    Naringin is the natural chief bitter flavonoid found in Citrus species. Herein, bitter naringin was treated with atmospheric pressure plasma to afford two new converted flavonoids, narinplasmins A (2) and B (3), along with the known compound, 2R-naringin. The structures of the two new naringin derivatives were elucidated on the basis of spectroscopic methods. The antioxidant activity of all isolates was evaluated based on 1,1-diphenyl-2-picrylhydrazyl and peroxynitrite (ONOO(-)) scavenging assays. The new flavanone glycoside 2 containing a methoxyalkyl group exhibited significantly improved antioxidant properties in these assays relative to the parent naringin.

  10. Reactions in a Mixture of CH4 and CO2 under the Aciton of Microwave Discharge at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    YunpengXu; ZhijianTian; 等

    2002-01-01

    Reactions between CH4 and CO2 under the action of continuous microwave discharge at atmospheric pressure were studied in a special homemade reactor,The main products were CO and H2,while acetylene and ethylene were also found in the products.Experimental results show that conversions of CH4 and CO2 could be higher than 90% without the presence of any catalyst,Effects of CO2/CH4 molar ratio and total flow rate of the feed gas on the reaction were also investigated.

  11. Electron-beam-sustained discharge revisited - light emission from combined electron beam and microwave excited argon at atmospheric pressure

    CERN Document Server

    Dandl, T; Neumeier, A; Wieser, J; Ulrich, A

    2015-01-01

    A novel kind of electron beam sustained discharge is presented in which a 12keV electron beam is combined with a 2.45GHz microwave power to excite argon gas at atmospheric pressure in a continuous mode of operation. Optical emission spectroscopy is performed over a wide wavelength range from the vacuum ultraviolet (VUV) to the near infrared (NIR). Several effects which modify the emission spectra compared to sole electron beam excitation are observed and interpreted by the changing plasma parameters such as electron density, electron temperature and gas temperature.

  12. Influence of the voltage waveform during nanocomposite layer deposition by aerosol-assisted atmospheric pressure Townsend discharge

    Science.gov (United States)

    Profili, J.; Levasseur, O.; Naudé, N.; Chaneac, C.; Stafford, L.; Gherardi, N.

    2016-08-01

    This work examines the growth dynamics of TiO2-SiO2 nanocomposite coatings in plane-to-plane Dielectric Barrier Discharges (DBDs) at atmospheric pressure operated in a Townsend regime using nebulized TiO2 colloidal suspension in hexamethyldisiloxane as the growth precursors. For low-frequency (LF) sinusoidal voltages applied to the DBD cell, with voltage amplitudes lower than the one required for discharge breakdown, Scanning Electron Microscopy of silicon substrates placed on the bottom DBD electrode reveals significant deposition of TiO2 nanoparticles (NPs) close to the discharge entrance. On the other hand, at higher frequencies (HF), the number of TiO2 NPs deposited strongly decreases due to their "trapping" in the oscillating voltage and their transport along the gas flow lines. Based on these findings, a combined LF-HF voltage waveform is proposed and used to achieve significant and spatially uniform deposition of TiO2 NPs across the whole substrate surface. For higher voltage amplitudes, in the presence of hexamethyldisiloxane and nitrous oxide for plasma-enhanced chemical vapor deposition of inorganic layers, it is found that TiO2 NPs become fully embedded into a silica-like matrix. Similar Raman spectra are obtained for as-prepared TiO2 NPs and for nanocomposite TiO2-SiO2 coating, suggesting that plasma exposure does not significantly alter the crystalline structure of the TiO2 NPs injected into the discharge.

  13. Time-resolved characterization of a filamentary argon discharge at atmospheric pressure in a capillary using emission and absorption spectroscopy

    Science.gov (United States)

    Schröter, Sandra; Pothiraja, Ramasamy; Awakowicz, Peter; Bibinov, Nikita; Böke, Marc; Niermann, Benedikt; Winter, Jörg

    2013-11-01

    An argon/nitrogen (0.999/0.001) filamentary pulsed discharge operated at atmospheric pressure in a quartz tube is characterized using voltage-current measurements, microphotography, optical emission spectroscopy (OES) and absorption spectroscopy. Nitrogen is applied as a sensor gas for the purpose of OES diagnostic. The density of argon metastable atoms Ar(3P2) is determined using tunable diode laser absorption spectroscopy (TDLAS). Using a plasma chemical model the measured OES data are applied for the characterization of the plasma conditions. Between intense positive pulses the discharge current oscillates with a damped amplitude. It is established that an electric current flows in this discharge not only through a thin plasma filament that is observed in the discharge image but also through the whole cross section of the quartz tube. A diffuse plasma fills the quartz tube during a time between intense current pulses. Ionization waves are propagating in this plasma between the spike and the grounded area of the tube producing thin plasma channels. The diameter of these channels increases during the pause between the propagation of ionization waves probably because of thermal expansion and diffusion. Inside the channels electron densities of ˜2 × 1013 cm-3, argon metastable densities ˜1014 cm-3 and a reduced electric field about 10 Td are determined.

  14. A model for plasma modification of polypropylene using atmospheric pressure discharges

    CERN Document Server

    Dorai, R

    2003-01-01

    Atmospheric pressure plasmas are commonly used to improve the wetting and adhesion properties of polymers. In spite of their use, the mechanisms for achieving these properties are unclear. In this regard, we report on a computational investigation of the gas phase and surface kinetics during humid-air corona treatment of polypropylene (PP) and the resulting modification of its surface properties while varying energy deposition, relative humidity (RH), web speed, and gas temperature. Using results from a global plasma chemistry model validated against experiments, we found that increasing energy deposition increased the densities of alcohol, carbonyl, acid, and peroxy radicals on the PP surface. In doing so, significant amounts of gas phase O sub 3 and N sub x O sub y are produced. Increasing the RH increased the production of peroxy and acid groups, while decreasing those of alcohol and carbonyl groups. Production of O sub 3 decreased while that of HNO sub 3 increased. Increasing the temperature decreased the...

  15. Standing striations due to ionization instability in atmospheric pressure He/H2O radio frequency capacitive discharges

    Science.gov (United States)

    Kawamura, E.; Lieberman, M. A.; Lichtenberg, A. J.

    2016-10-01

    One-dimensional particle-in-cell (PIC) simulations of a narrow gap atmospheric pressure He/2%{{\\text{H}}2}\\text{O} radio frequency capacitive discharge showed standing striations in the bulk plasma region while previously conducted PIC simulations of a narrow gap atmospheric pressure He/0.1%{{\\text{N}}2} discharges [1] showed no such instabilities. We successively modified the base He/{{\\text{H}}2}\\text{O} chemistry to make it more similar to the He/{{\\text{N}}2} chemistry in order to determine the cause of the striations. Setting the e-{{\\text{H}}2}\\text{O} scattering, attachment, vibrational and rotational excitation rates to zero did not suppress the striations. However, a systematic reduction of the e-ion recombination cross section resulted in a transition to a stable state with no striations. The results are interpreted in terms of a model in which the balance between bulk direct ionization and bulk recombination loss determines the bulk plasma equilibrium. Perturbing the equilibrium, we find that the striations are consistent with an ionization instability induced by non-local electron kinetics that form a spatially-varying high energy tail of the electron energy distribution, causing the ionization rate coefficient to decrease with increasing electron temperature T e and root-mean-square electric field E in the instability regime.

  16. AIR ATMOSPHERIC-PRESSURE DISCHARGERS FOR OPERATION IN HIGH-FREQUENCY SWITCHING MODE.

    Directory of Open Access Journals (Sweden)

    L.S. Yevdoshenko

    2013-10-01

    Full Text Available Operation of two designs of compact multigap dischargers has been investigated in a high-frequency switching mode. It is experimentally revealed that the rational length of single discharge gaps in the designs is 0.3 mm, and the maximum switching frequency is 27000 discharges per second under long-term stable operation of the dischargers. It is shown that in pulsed corona discharge reactors, the pulse front sharpening results in increasing the operating electric field strength by 1.3 – 1.8 times.

  17. High-molecular products analysis of VOC destruction in atmospheric pressure discharge

    Science.gov (United States)

    Grossmannova, Hana; Ciganek, Miroslav; Krcma, Frantisek

    2007-04-01

    We investigate the issue of applicability of the solid phase microextraction (SPME) in the analysis of volatile organic compounds (VOCs) destruction products in the gliding arc discharge. Our research is focused on the measurements with the simple one stage gliding arc reactor, applied voltage was varied in the range of 3.5-4 kV. As a carrier gas, the dry air and its mixtures with nitrogen and oxygen, enriched by toluene, with flow rate of 1000-3500 ml/min was used. Total decomposition of toluene of 97 % was achieved at the oxygen content in carrier gas of 60 %. For measurements with air as a carrier gas, the highest efficiency was 95 %. We also tested the SPME technique suitability for the quantitative analysis of exhausts gases and if this technique can be used efficiently in the field to extract byproducts. Carbowax/divinylbenzene and Carboxen/polydimethylsiloxane/divinylbenzene fibres were chosen for sampling. Tens of various high-molecular substances were observed, especially a large number of oxygenous compounds and further several nitrogenous and CxHy compounds. The concentrations of various generated compounds strongly depend on the oxygen content in gas mixture composition. The results showed that the fiber coated by Carbowax/divinylbenzene can extract more products independently on the used VOC compound. The Carboxen/polydimethylsiloxane/divinylbenzene fiber is useful for the analysis of oxygenous compounds and its use will be recommended especially when the destruction is done in the oxygen rich atmosphere. With the higher ratio of oxygen in the carrier gas a distinctive decline of CxHy compounds amount have been observed. We also tried to describe the significant production of some compounds like benzyl alcohol, benzeneacetaldehyde, even in oxygen content is proximate 0 %. Experimental data demonstrated that it is necessary to use several SPME fibres for full-scale high-molecular products analysis.

  18. Modification of surface layers of copper under the action of the volumetric discharge initiated by an avalanche electron beam in nitrogen and CO2 at atmospheric pressure

    Science.gov (United States)

    Shulepov, M. A.; Akhmadeev, Yu. Kh.; Tarasenko, V. F.; Kolubaeva, Yu. A.; Krysina, O. V.; Kostyrya, I. D.

    2011-05-01

    The results of experimental investigations of the action of the volumetric discharge initiated by an avalanche electron beam on the surface of copper specimens are presented. The volumetric (diffuse) discharge in nitrogen and CO2 at atmospheric pressure was initiated by applying high voltage pulses of nanosecond duration to a tubular foil cathode. It has been found that the treatment of a copper surface by this type of discharge increases the hardness of the surface layer due to oxidation.

  19. A comparison between micro hollow cathode discharges and atmospheric pressure plasma jets in Ar/O2 gas mixtures

    Science.gov (United States)

    Lazzaroni, C.; Chabert, P.

    2016-12-01

    Using global models, micro hollow cathode discharges (MHCDs) are compared to radiofrequency atmospheric pressure plasma jets (APPJs) in terms of reactive oxygen species (ROS) production. Ar/O2 gas mixtures are investigated, typically with a small percentage of oxygen in argon. The same chemical reaction set, involving 17 species and 128 chemical reactions in the gas phase, is used for both devices, operated in the typical geometries previously published; the APPJ is driven by a radiofrequency voltage across a 1 mm gap, at atmospheric pressure, while the MHCD is driven by a DC voltage source, at 100 Torr and in a 400 μm hole. The MHCD may be operated either in the self-pulsing or in the normal (stationary) regime, depending on the driving voltage. The comparison shows that in both regimes, the MHCD produces larger amounts of \\text{O}2\\ast , while the APPJ produces predominantly reactive oxygen ground state species, \\text{O} and {{\\text{O}}3} . These large differences in ROS composition are mostly due to the higher plasma density produced in the MHCD. The difference in operating pressure is a second order effect.

  20. Dependence of Ozone Generation on Gas Temperature Distribution in AC Atmospheric Pressure Dielectric Barrier Discharge in Oxygen

    Science.gov (United States)

    Takahashi, Go; Akashi, Haruaki

    AC atmospheric pressure multi-filament dielectric barrier discharge in oxygen has been simulated using two dimensional fluid model. In the discharge, three kinds of streamers have been obtained. They are primary streamers, small scale streamers and secondary streamers. The primary streamers are main streamers in the discharge and the small scale streamers are formed after the ceasing of the primary streamers. And the secondary streamers are formed on the trace of the primary streamers. In these streamers, the primary and the small scale streamers are very effective to generate O(3P) oxygen atoms which are precursor of ozone. And the ozone is generated mainly in the vicinity of the dielectrics. In high gas temperature region, ozone generation decreases in general. However, increase of the O(3P) oxygen atom density in high gas temperature region compensates decrease of ozone generation rate coefficient. As a result, amount of ozone generation has not changed. But if the effect of gas temperature was neglected, amount of ozone generation increases 10%.

  1. Modification of the Steel Surface Treated by a Volume Discharge Plasma in Nitrogen at Atmospheric Pressure

    Science.gov (United States)

    Erofeev, M. V.; Shulepov, M. A.; Ivanov, Yu. F.; Oskomov, K. V.; Tarasenko, V. F.

    2016-03-01

    Effect of volume discharge plasma initiated by an avalanche electron beam on the composition, structure, and properties of the surface steel layer is investigated. Voltage pulses with incident wave amplitude up to 30 kV, full width at half maximum of about 4 ns, and wave front of about 2.5 ns were applied to the gap with an inhomogeneous electric field. Changes indicating the hardening effect of the volume discharge initiated by an avalanche electron beam are revealed in St3-grade steel specimens treated by the discharge of this type.

  2. Effect of oxygen impurities on atmospheric-pressure surface streamer discharge in argon for large gap arc breakdown

    Science.gov (United States)

    Sharma, Ashish; Levko, Dmitry; Raja, Laxminarayan L.

    2016-10-01

    We report the results of a computational study that investigates the effect of impurities (molecular oxygen) on the development of argon surface streamers at atmospheric-pressure conditions. A continuous surface streamer has been proposed as a low-voltage mechanism to generate a conductive bridge for arc breakdown of a large interelectrode gap at high pressures. The streamer discharge model is based on the self-consistent, multispecies, continuum description of the plasma. Below a threshold voltage, no streamer discharge is observed and charge is localized only in the vicinity of the anode in the form of a localized corona. Above this voltage threshold in pure argon, a continuous conductive streamer successfully bridges the gap between two electrodes indicating high probability of transition to the arc. For small oxygen impurities (less than 5%), the threshold voltage is found to decrease by a few hundred volts compared to the threshold voltage in pure argon while the streamer induction time increases. No noticeable changes in the streamer conductivity is obtained for low impurities of oxygen in the above range. An increase of the oxygen density above the 5% impurity level causes a significant decrease in the continuous streamer conductivity and leads to a decrease in the probability of transition to arc.

  3. Thin film deposition at atmospheric pressure using dielectric barrier discharges: Advances on three-dimensional porous substrates and functional coatings

    Science.gov (United States)

    Fanelli, Fiorenza; Bosso, Piera; Mastrangelo, Anna Maria; Fracassi, Francesco

    2016-07-01

    Surface processing of materials by atmospheric pressure dielectric barrier discharges (DBDs) has experienced significant growth in recent years. Considerable research efforts have been directed for instance to develop a large variety of processes which exploit different DBD electrode geometries for the direct and remote deposition of thin films from precursors in gas, vapor and aerosol form. This article briefly reviews our recent progress in thin film deposition by DBDs with particular focus on process optimization. The following examples are provided: (i) the plasma-enhanced chemical vapor deposition of thin films on an open-cell foam accomplished by igniting the DBD throughout the entire three-dimensional (3D) porous structure of the substrate, (ii) the preparation of hybrid organic/inorganic nanocomposite coatings using an aerosol-assisted process, (iii) the DBD jet deposition of coatings containing carboxylic acid groups and the improvement of their chemical and morphological stability upon immersion in water.

  4. Treatment of poly(ethylene terephthalate) foils by atmospheric pressure air dielectric barrier discharge and its influence on cell growth

    Energy Technology Data Exchange (ETDEWEB)

    Kuzminova, Anna [Department of Macromolecular Physics, Faculty of Mathematics and Physics, Charles University, V Holešovickách 2, 180 00 Praha 8 (Czech Republic); Vandrovcová, Marta [Institute of Physiology, Academy of Sciences of the Czech Republic, Vídeňská 1083, 142 20 Prague 4 (Czech Republic); Shelemin, Artem [Department of Macromolecular Physics, Faculty of Mathematics and Physics, Charles University, V Holešovickách 2, 180 00 Praha 8 (Czech Republic); Kylián, Ondřej, E-mail: ondrej.kylian@gmail.com [Department of Macromolecular Physics, Faculty of Mathematics and Physics, Charles University, V Holešovickách 2, 180 00 Praha 8 (Czech Republic); Choukourov, Andrei; Hanuš, Jan [Department of Macromolecular Physics, Faculty of Mathematics and Physics, Charles University, V Holešovickách 2, 180 00 Praha 8 (Czech Republic); Bačáková, Lucie [Institute of Physiology, Academy of Sciences of the Czech Republic, Vídeňská 1083, 142 20 Prague 4 (Czech Republic); Slavínská, Danka; Biederman, Hynek [Department of Macromolecular Physics, Faculty of Mathematics and Physics, Charles University, V Holešovickách 2, 180 00 Praha 8 (Czech Republic)

    2015-12-01

    Highlights: • Effect of atmospheric pressure DBD plasma on PET foils was investigated. • DBD treatment causes increase in surface density of O-containing functional groups. • DBD plasma causes increase of wettability, roughness and complex modulus of PET. • DBD treatment positively influences cells growth on PET. • Enhancement of cell growth on treated PET depends on the cell type. - Abstract: In this contribution an effect of dielectric barrier discharge (DBD) sustained in air at atmospheric pressure on surface properties of poly(ethylene terephthalate) (PET) foils is studied. It is found that exposure of PET to DBD plasma leads to rapid changes of surface chemical composition, wettability, surface morphology as well as mechanical properties of PET surface. In addition, based on biological tests that were performed using two cell types (Saos-2 human osteoblast-like cells and HUVEC human umbilical vein endothelial cells), it may be concluded that DBD plasma treatment positively influences cell growth on PET. This effect was found to be connected predominantly with increased surface energy and oxygen content of the surface of treated PET foils.

  5. Trace analysis of organics in air by corona discharge atmospheric pressure ionization using an electrospray ionization interface.

    Science.gov (United States)

    Nikolaev, Eugene; Riter, Leah S; Laughlin, Brian C; Handberg, Eric; Cooks, R Graham

    2004-01-01

    A corona discharge ion source operating at atmospheric pressure in the point-to-plane configuration was constructed by reconfiguring the ion source of a commercial electrospray ionization (ESI) quadrupole mass spectrometer. This new source allows direct air analysis without modification to the mass spectrometer. Detection and quantitation of semi-volatile compounds in air is demonstrated. The analytical performance of the system was established using the chemical warfare agent simulants methyl salicylate and dimethyl methylphosphonate. Limits of detection are 60 pptr in the negative-ion mode and 800 pptr in the positive-ion mode for methyl salicylate and 800 pptr in the negative-ion mode and 3.6 ppb in the positive-ion mode for dimethyl methylphosphonate. A linear response was observed from 60 pptr to 8 ppb for methyl salicylate in air in the negative-ionization mode. Cluster ion formation versus production of analyte ions was investigated and it was found that dry air or an elevated capillary interface temperature (130 degrees C) was needed to avoid extensive clustering, mostly of water. Reagent gases are not needed as proton sources, as is usually the case for atmospheric pressure chemical ionization, and this, together with the simplicity, sensitivity and speed of the technique, makes it promising for miniaturization and future field studies.

  6. Production characteristics of reactive oxygen/nitrogen species in water using atmospheric pressure discharge plasmas

    Science.gov (United States)

    Takahashi, Kazuhiro; Satoh, Kohki; Itoh, Hidenori; Kawaguchi, Hideki; Timoshkin, Igor; Given, Martin; MacGregor, Scott

    2016-07-01

    A pulsed discharge, a DC corona discharge, and a plasma jet are separately generated above a water surface, and reactive oxygen species and reactive nitrogen species (ROS/RNS) in the water are investigated. ROS/RNS in water after the sparging of the off-gas of a packed-bed dielectric barrier discharge (PB-DBD) are also investigated. H2O2, NO2 -, and NO3 - are detected after plasma exposure and only NO3 - after off-gas sparging. Short-lifetime species in plasma are found to play an important role in H2O2 and NO2 - production and long-lifetime species in NO3 - production. NO x may inhibit H2O2 production through OH consumption to produce HNO2 and HNO3. O3 does not contribute to ROS/RNS production. The pulsed plasma exposure is found to be effective for the production of H2O2 and NO2 -, and the off-gas sparging of the PB-DBD for the production of NO3 -.

  7. Changes in the electro-physical properties of MCT epitaxial films affected by a plasma volume discharge induced by an avalanche beam in atmospheric-pressure air

    Science.gov (United States)

    Grigoryev, D. V.; Voitsekhovskii, A. V.; Lozovoy, K. A.; Tarasenko, V. F.; Shulepov, M. A.

    2015-11-01

    In this paper the influence of the plasma volume discharge of nanosecond duration formed in a non-uniform electric field at atmospheric pressure on samples of epitaxial films HgCdTe (MCT) films are discussed. The experimental data show that the action of pulses of nanosecond volume discharge in air at atmospheric pressure leads to changes in the electrophysical properties of MCT epitaxial films due to formation of a near-surface high- conductivity layer of the n-type conduction. The preliminary results show that it is possible to use such actions in the development of technologies for the controlled change of the properties of MCT.

  8. Modeling of recovery mechanism of ozone zero phenomenaby adding small amount of nitrogen in atmospheric pressure oxygen dielectric barrier discharges

    Science.gov (United States)

    Akashi, Haruaki; Yoshinaga, Tomokazu

    2013-09-01

    Ozone zero phenomena in an atmospheric pressure oxygen dielectric barrier discharges have been one of the major problems during a long time operation of ozone generators. But it is also known that the adding a small amount of nitrogen makes the recover from the ozone zero phenomena. To make clear the mechanism of recovery, authors have been simulated the discharges with using the results of Ref. 3. As a result, the recovery process can be seen and ozone density increased. It is found that the most important species would be nitrogen atoms. The reaction of nitrogen atoms and oxygen molecules makes oxygen atoms which is main precursor species of ozone. This generation of oxygen atoms is effective to increase ozone. The dependence of oxygen atom density (nO) and nitrogen atom density (nN) ratio was examined in this paper. In the condition of low nN/nO ratio case, generation of nitrogen oxide is low, and the quenching of ozone by the nitrogen oxide would be low. But in the high ratio condition, the quenching of ozone by nitrogen oxide would significant. This work was supported by KAKENHI(23560352).

  9. Atmospheric pressure argon surface discharges propagated in long tubes: physical characterization and application to bio-decontamination

    Science.gov (United States)

    Kovalova, Zuzana; Leroy, Magali; Jacobs, Carolyn; Kirkpatrick, Michael J.; Machala, Zdenko; Lopes, Filipa; Laux, Christophe O.; DuBow, Michael S.; Odic, Emmanuel

    2015-11-01

    Pulsed corona discharges propagated in argon (or in argon with added water vapor) at atmospheric pressure on the interior surface of a 49 cm long quartz tube were investigated for the application of surface bio-decontamination. H2O molecule dissociation in the argon plasma generated reactive species (i.e. OH in ground and excited states) and UV emission, which both directly affected bacterial cells. In order to facilitate the evaluation of the contribution of UV radiation, a DNA damage repair defective bacterial strain, Escherichia coli DH-1, was used. Discharge characteristics, including propagation velocity and plasma temperature, were measured. Up to ~5.5 and ~5 log10 reductions were observed for E. coli DH-1 bacteria (from 106 initial load) exposed 2 cm and 44 cm away from the charged electrode, respectively, for a 20 min plasma treatment. The factors contributing to the observed bactericidal effect include desiccation, reactive oxygen species (OH) plus H2O2 accumulation in the liquid phase, and UV-B (and possibly VUV) emission in dry argon. The steady state temperature measured on the quartz tube wall did not exceeded 29 °C the contribution of heating, along with that of H2O2 accumulation, was estimated to be low. The effect of UV-B emission alone or in combination with the other stress factors of the plasma process was examined for different operating conditions.

  10. Influence of pulsed nanosecond volume discharge in atmospheric-pressure air on the electrical characteristics of MCT epitaxial films

    Science.gov (United States)

    Grigoryev, Denis V.; Voitsekhovskii, Alexandr V.; Lozovoy, Kirill A.; Nesmelov, Sergey N.; Dzyadukh, Stanislav M.; Tarasenko, Viktor F.; Shulepov, Michail A.; Dvoretskii, Sergei A.

    2015-12-01

    The purpose of this paper was investigating the effect of volume nanosecond discharge in air at atmospheric pressure on the electro-physical properties of the HgCdTe (MCT) epitaxial films grown by molecular beam epitaxy. Hall measurements of electro-physical parameters of MCT samples after irradiation have shown that there is a layer of epitaxial films exhibiting n-type conductivity that is formed in the near-surface area. After more than 600 pulses of influence parameters and thickness of the resulting n-layer is such that the measured field dependence of Hall coefficient corresponds to the material of n-type conductivity. Also it is shown that the impact of the discharge leads to significant changes in electro-physical characteristics of MIS structures. This fact is demonstrated by increase in density of positive fixed charge, change in the hysteresis type of the capacitance-voltage characteristic, an increase in density of surface states. The preliminary results show that it is possible to use such actions in the development of technologies of the controlled change in the properties of MCT.

  11. Modification of hydrophobic acrylic intraocular lens with poly(ethylene glycol) by atmospheric pressure glow discharge: A facile approach

    Energy Technology Data Exchange (ETDEWEB)

    Lin Lin; Wang Yao; Huang Xiaodan [Eye Center, Affiliated Second Hospital, College of Medicine, Zhejiang University, Hangzhou 310009 (China); Xu Zhikang [Key Laboratory of Macromolecular Synthesis and Functionalization (Ministry of Education), Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027 (China); Yao Ke, E-mail: xlren@zju.edu.cn [Eye Center, Affiliated Second Hospital, College of Medicine, Zhejiang University, Hangzhou 310009 (China)

    2010-10-01

    To improve the anterior surface biocompatibility of hydrophobic acrylic intraocular lens (IOL) in a convenient and continuous way, poly(ethylene glycol)s (PEGs) were immobilized by atmospheric pressure glow discharge (APGD) treatment using argon as the discharge gas. The hydrophilicity and chemical changes on the IOL surface were characterized by static water contact angle and X-ray photoelectron spectroscopy to confirm the covalent binding of PEG. The morphology of the IOL surface was observed under field emission scanning electron microscopy and atomic force microscopy. The surface biocompatibility was evaluated by adhesion experiments with platelets, macrophages, and lens epithelial cells (LECs) in vitro. The results revealed that the anterior surface of the PEG-grafted IOL displayed significantly and permanently improved hydrophilicity. Cell repellency was observed, especially in the PEG-modified IOL group, which resisted the attachment of platelets, macrophages and LECs. Moreover, the spread and growth of cells were suppressed, which may be attributed to the steric stabilization force and chain mobility effect of the modified PEG. All of these results indicated that hydrophobic acrylic IOLs can be hydrophilic modified by PEG through APGD treatment in a convenient and continuous manner which will provide advantages for further industrial applications.

  12. Particle-in-Cell Simulation for the Control of Electron Energy Distribution of Dielectric Barrier Discharges at Atmospheric Pressure

    Science.gov (United States)

    Bae, Hyo Won; Yel Lee, Jung; Lee, Ho-Jun; Lee, Hae June

    2011-10-01

    Recently, atmospheric pressure plasmas attract lots of interests for the useful applications such as surface modification and bio-medical treatment. In this study, a particle-in-cell Monte Carlo collision (PIC-MCC) simulation was adopted to investigate the discharge characteristics of a planar micro dielectric barrier discharge (DBD) with a driving frequency from 1 MHz to 50 MHz and with a gap distance from 60 to 500 micrometers. The variation of control parameters such as the gap distance, the driving wave form, and the applied voltage results in the change in the electron energy distribution function (EEDF). Through the relation between the ionization mean free path and the gap size, a significant change of EEDFs is achievable with the decrease of gap distance. Therefore, it is possible to categorize the operation range of DBDs for its applications by controlling the interactions between plasmas and neutral gas for the generation of preferable radicals. This work was supported by the Human Resources Development of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant funded by the Korea government Ministry of Knowledge Economy (No. 20104010100670).

  13. Atmospheric pressure plasma produced inside a closed package by a dielectric barrier discharge in Ar/CO2 for bacterial inactivation of biological samples

    DEFF Research Database (Denmark)

    Chiper, Alina Silvia; Chen, Weifeng; Mejlholm, Ole

    2011-01-01

    The generation and evaluation of a dielectric barrier discharge produced inside a closed package made of a commercially available packaging film and filled with gas mixtures of Ar/CO2 at atmospheric pressure is reported. The discharge parameters were analysed by electrical measurements and optical...... emission spectroscopy in two modes of operation: trapped gas atmosphere and flowing gas atmosphere. Gas temperature was estimated using the OH(A–X) emission spectrum and the rotational temperature reached a saturation level after a few minutes of plasma running. The rotational temperature was almost three...

  14. Influences of oxygen content on characteristics of atmospheric pressure dielectric barrier discharge in argon/oxygen mixtures

    Science.gov (United States)

    Fang, Zhi; Shao, Tao; Wang, Ruixue; Yang, Jing; Zhang, Cheng

    2016-04-01

    The dielectric barrier discharge generated in argon/oxygen mixtures at atmospheric pressure is investigated, and the effect of oxygen content on discharge characteristics at applied voltage of 4.5 kV is studied by means of electrical measurements and optical diagnostics. The results show that the filaments in the discharge regime become more densely packed with the increasing in the oxygen content, and the distribution of the filaments is more uniform in the gap. An increase in the oxygen content results in a decrease in the average power consumed and transported charges, while there exists an optimal value of oxygen content for the production of oxygen radicals. The maximal yield of oxygen radicals is obtained in mixtures of argon with 0.3% oxygen addition, and the oxygen radicals then decrease with the further increase in the oxygen content. The oxygen/argon plasma is employed to modify surface hydrophilicity of the PET films to estimate the influence of oxygen content on the surface treatment, and the static contact angles before and after the treatments are measured. The lowest contact angle is obtained at a 0.3% addition of oxygen to argon, which is in accordance with the optimum oxygen content for oxygen radicals generation. The electron density and electron temperature are estimated from the measured current and optical emission spectroscopy, respectively. The electron density is found to reduce significantly at a higher oxygen content due to the increased electron attachment, while the estimated electron temperature do not change apparently with the oxygen content. Contribution to the Topical Issue "Recent Breakthroughs in Microplasma Science and Technology", edited by Kurt Becker, Jose Lopez, David Staack, Klaus-Dieter Weltmann and Wei Dong Zhu.

  15. Kinetics and dynamics of nanosecond streamer discharge in atmospheric-pressure gas bubble suspended in distilled water under saturated vapor pressure conditions

    Science.gov (United States)

    Sharma, Ashish; Levko, Dmitry; Raja, Laxminarayan L.; Cha, Min Suk

    2016-10-01

    We perform computational studies of nanosecond streamer discharges generated in helium bubbles immersed in distilled water under atmospheric pressure conditions. The model takes into account the presence of water vapor in the gas bubble for an accurate description of the discharge kinetics. We find that the dynamic characteristics of the streamer discharge are different at low and high positive trigger voltages with the axial streamer evolution dominant for low voltages and a surface hugging mode favored for high voltages. We also find a substantial difference in initiation, transition and evolution stages of discharge for positive and negative trigger voltages with the volumetric distribution of species in the streamer channel much more uniform for negative trigger voltages on account of the presence of multiple streamers. We observe that the presence of water vapor does not affect the breakdown voltage even for oversaturated conditions but significantly influences the composition of dominant species in the trail of the streamer as well as the flux of the dominant species on the bubble surface.

  16. Kinetics and dynamics of nanosecond streamer discharge in atmospheric-pressure gas bubble suspended in distilled water under saturated vapor pressure conditions

    KAUST Repository

    Sharma, Ashish

    2016-09-08

    We perform computational studies of nanosecond streamer discharges generated in helium bubbles immersed in distilled water under atmospheric pressure conditions. The model takes into account the presence of water vapor in the gas bubble for an accurate description of the discharge kinetics. We find that the dynamic characteristics of the streamer discharge are different at low and high positive trigger voltages with the axial streamer evolution dominant for low voltages and a surface hugging mode favored for high voltages. We also find a substantial difference in initiation, transition and evolution stages of discharge for positive and negative trigger voltages with the volumetric distribution of species in the streamer channel much more uniform for negative trigger voltages on account of the presence of multiple streamers. We observe that the presence of water vapor does not affect the breakdown voltage even for oversaturated conditions but significantly influences the composition of dominant species in the trail of the streamer as well as the flux of the dominant species on the bubble surface. © 2016 IOP Publishing Ltd.

  17. Simulation of a wire-cylinder-plate positive corona discharge in nitrogen gas at atmospheric pressure

    Energy Technology Data Exchange (ETDEWEB)

    Martins, Alexandre A. [Institute for Plasmas and Nuclear Fusion and Instituto Superior Tecnico, Av. Rovisco Pais, 1049-001 Lisboa (Portugal)

    2012-06-15

    In this work, we are going to perform a simulation of a wire-cylinder-plate positive corona discharge in nitrogen gas, and compare our results with already published experimental results in air for the same structure. We have chosen to simulate this innovative geometry because it has been established experimentally that it can generate a thrust per unit electrode length transmitted to the gas of up to 0.35 N/m and is also able to induce an ion wind top velocity in the range of 8-9 m/s in air. In our model, the used ion source is a small diameter wire, which generates a positive corona discharge in nitrogen gas directed to the ground electrode, after which the generated positive ions are further accelerated in the acceleration channel between the ground and cathode. By applying the fluid dynamic and electrostatic theories, all hydrodynamic and electrostatic forces that act on the considered geometries will be computed in an attempt to theoretically confirm the generated ion wind profile and also the thrust per unit electrode length. These results are important to establish the validity of this simulation tool for the future study and development of this effect for practical purposes.

  18. Simulation of a wire-cylinder-plate positive corona discharge in nitrogen gas at atmospheric pressure

    CERN Document Server

    Martins, Alexandre A

    2012-01-01

    In this work we are going to perform a simulation of a wire-cylinder-plate positive corona discharge in nitrogen gas, and compare our results with already published experimental results in air for the same structure. We have chosen to simulate this innovative geometry because it has been established experimentally that it can generate a thrust per unit electrode length transmitted to the gas of up to 0.35 N/m and is also able to induce an ion wind top velocity in the range of 8-9 m/s in air. In our model, the used ion source is a small diameter wire, which generates a positive corona discharge in nitrogen gas directed to the ground electrode, after which the generated positive ions are further accelerated in the acceleration channel between the ground and cathode. By applying the fluid dynamic and electrostatic theories all hydrodynamic and electrostatic forces that act on the considered geometries will be computed in an attempt to theoretically confirm the generated ion wind profile and also the thrust per u...

  19. Simulations of atmospheric pressure discharge in a high-voltage nanosecond pulse using the particle-in-cell Monte Carlo collision model in noble gases

    Science.gov (United States)

    Shi, Feng; Wang, Dezhen; Ren, Chunsheng

    2008-06-01

    Atmospheric pressure discharge nonequilibrium plasmas have been applied to plasma processing with modern technology. Simulations of discharge in pure Ar and pure He gases at one atmospheric pressure by a high voltage trapezoidal nanosecond pulse have been performed using a one-dimensional particle-in-cell Monte Carlo collision (PIC-MCC) model coupled with a renormalization and weighting procedure (mapping algorithm). Numerical results show that the characteristics of discharge in both inert gases are very similar. There exist the effects of local reverse field and double-peak distributions of charged particles' density. The electron and ion energy distribution functions are also observed, and the discharge is concluded in the view of ionization avalanche in number. Furthermore, the independence of total current density is a function of time, but not of position.

  20. Improving the low temperature dyeability of polyethylene terephthalate fabric with dispersive dyes by atmospheric pressure plasma discharge

    Science.gov (United States)

    Elabid, Amel E. A.; Zhang, Jie; Shi, Jianjun; Guo, Ying; Ding, Ke; Zhang, Jing

    2016-07-01

    Polyethylene terephthalate (PET) fiber and textile is one of the largest synthetic polymer commodity in the world. The great energy consumption and pollution caused by the high temperature and pressure dyeing of PET fibers and fabrics with disperse dyes has been caused concern these years. In this study, an atmospheric pressure plasma with fine and uniform filament discharge operated at 20 kHz has been used to improve the low temperature dyeability of PET fabric at 95 °C with three cation disperse dyes: Red 73, Blue 183 and Yellow 211. The dyes uptake percentage of the treated PET fabrics was observed to increase as twice as much of untreated fabric. The color strength rate was increased more than 20%. The reducing of the water contact angle and the raising of the capillary height of treated PET fabric strip indicate its hydrophilicity improvement. Scanning electron microscope (SEM) results display nano to micro size of etching pits appeared uniformly on the fiber surface of the treated PET. Simultaneously, X-ray photoelectron spectroscopy (XPS) analysis indicates an increase of the oxygen content in the surface caused by the introduction of polar groups such as Cdbnd O and COOH. The rough surface with improved polar oxygen groups showed hydrophilicity and affinity to C.I. dispersive dyes and is believed to be caused by the strong and very fine filament discharge appearing randomly at one place at an instant but evenly at many places at a longer period. This increases the diffusion and absorption of the C.I. disperse dyes on the PET fiber surface, which improve its low temperature dyeability.

  1. Analysis of Ar plasma jets induced by single and double dielectric barrier discharges at atmospheric pressure

    Science.gov (United States)

    Judée, F.; Merbahi, N.; Wattieaux, G.; Yousfi, M.

    2016-09-01

    The aim is the comparison of different plasma parameters of single and double dielectric barrier discharge plasma jet configurations (S-DBD and D-DBD) which are potentially usable in biomedical applications. Both configurations are studied in terms of electric field distribution, electrical discharge characteristics, plasma parameters (estimated by optical emission spectroscopy analysis), and hydrodynamics of the plasma jet for electrical parameters of power supplies corresponding to an applied voltage of 10 kV, pulse duration of 1 μs, frequency of 9.69 kHz, and Ar flow of 2 l/min. We observed that the D-DBD configuration requires half the electrical power one needs to provide in the S-DBD case to generate a plasma jet with similar characteristics: excitation temperature around 4700 K, electron density around 2.5 × 1014 cm-3, gas temperature of about 320 K, a relatively high atomic oxygen concentration reaching up to 1000 ppm, the presence of reactive oxygen and nitrogen species (nitric oxide, hydroxyl radical, and atomic oxygen), and an irradiance in the UV-C range of about 20 μW cm-2. Moreover, it has been observed that D-DBD plasma jet is more sensitive to short pulse durations, probably due to the charge accumulation over the dielectric barrier around the internal electrode. This results in a significantly longer plasma length in the D-DBD configuration than in the S-DBD one up to a critical flow rate (2.25 l/min) before the occurrence of turbulence in the D-DBD case. Conversely, ionization wave velocities are significantly higher in the S-DBD setup (3.35 × 105 m/s against 1.02 × 105 m/s for D-DBD), probably due to the higher electrostatic field close to the high voltage electrode in the S-DBD plasma jet.

  2. X-ray emission from a nanosecond-pulse discharge in an inhomogeneous electric field at atmospheric pressure

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Cheng; Shao Tao; Ren Chengyan; Zhang Dongdong [Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190 (China); Key Laboratory of Power Electronics and Electric Drive, Chinese Academy of Sciences, Beijing 100190 (China); Tarasenko, Victor; Kostyrya, Igor D. [Institute of High Current Electronics, Russian Academy of Science, Tomsk 634055 (Russian Federation); Ma Hao [Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190 (China); Yan Ping [Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190 (China); Key Laboratory of Power Electronics and Electric Drive, Chinese Academy of Sciences, Beijing 100190 (China); State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China)

    2012-12-15

    This paper describes experimental studies of the dependence of the X-ray intensity on the anode material in nanosecond high-voltage discharges. The discharges were generated by two nanosecond-pulse generators in atmospheric air with a highly inhomogeneous electric field by a tube-plate gap. The output pulse of the first generator (repetitive pulse generator) has a rise time of about 15 ns and a full width at half maximum of 30-40 ns. The output of the second generator (single pulse generator) has a rise time of about 0.3 ns and a full width at half maximum of 1 ns. The electrical characteristics and the X-ray emission of nanosecond-pulse discharge in atmospheric air are studied by the measurement of voltage-current waveforms, discharge images, X-ray count and dose. Our experimental results showed that the anode material rarely affects electrical characteristics, but it can significantly affect the X-ray density. Comparing the density of X-rays, it was shown that the highest x-rays density occurred in the diffuse discharge in repetitive pulse mode, then the spark discharge with a small air gap, and then the corona discharge with a large air gap, in which the X-ray density was the lowest. Therefore, it could be confirmed that the bremsstrahlung at the anode contributes to the X-ray emission from nanosecond-pulse discharges.

  3. Effect of Duty Cycle on the Characteristics of Pulse-Modulhted Radio-Frequency Atmospheric Pressure Dielectric Barrier Discharge

    Institute of Scientific and Technical Information of China (English)

    LI Xuechun; WANG Huan; DING Zhenfeng; WANG Younian

    2012-01-01

    Using a one-dimensional fluid model, the pulse-modulated radio-frequency dielectric barrier discharge in atmospheric helium is described. The influences of the pulse duty cycle on the discharge characteristics are studied. The numerical results show that the dependence of discharge characteristics on the duty cycle is sensitive in the region of around 40% duty cycle under the given simulation parameters. In the case of a larger duty cycle, the plasma density is higher, the discharge becomes more intense, but the power consumption is higher. When the duty cycle is lower, one can get a weaker discharge, lower plasma density and higher electron temperature in the bulk plasma. In practical applications, in order to get a higher plasma density and a lower power consumption, it is more important to choose a suitable duty cycle to modulate the RF power supply.

  4. Diagnostics of atmospheric-pressure pulsed-dc discharge with metal and liquid anodes by multiple laser-aided methods

    Science.gov (United States)

    Urabe, Keiichiro; Shirai, Naoki; Tomita, Kentaro; Akiyama, Tsuyoshi; Murakami, Tomoyuki

    2016-08-01

    The density and temperature of electrons and key heavy particles were measured in an atmospheric-pressure pulsed-dc helium discharge plasma with a nitrogen molecular impurity generated using system with a liquid or metal anode and a metal cathode. To obtain these parameters, we conducted experiments using several laser-aided methods: Thomson scattering spectroscopy to obtain the spatial profiles of electron density and temperature, Raman scattering spectroscopy to obtain the neutral molecular nitrogen rotational temperature, phase-modulated dispersion interferometry to determine the temporal variation of the electron density, and time-resolved laser absorption spectroscopy to analyze the temporal variation of the helium metastable atom density. The electron density and temperature measured by Thomson scattering varied from 2.4  ×  1014 cm-3 and 1.8 eV at the center of the discharge to 0.8  ×  1014 cm-3 and 1.5 eV near the outer edge of the plasma in the case of the metal anode, respectively. The electron density obtained with the liquid anode was approximately 20% smaller than that obtained with the metal anode, while the electron temperature was not significantly affected by the anode material. The molecular nitrogen rotational temperatures were 1200 K with the metal anode and 1650 K with the liquid anode at the outer edge of the plasma column. The density of helium metastable atoms decreased by a factor of two when using the liquid anode.

  5. Effects and Mechanism of Atmospheric-Pressure Dielectric Barrier Discharge Cold Plasma on Lactate Dehydrogenase (LDH) Enzyme.

    Science.gov (United States)

    Zhang, Hao; Xu, Zimu; Shen, Jie; Li, Xu; Ding, Lili; Ma, Jie; Lan, Yan; Xia, Weidong; Cheng, Cheng; Sun, Qiang; Zhang, Zelong; Chu, Paul K

    2015-01-01

    Proteins are carriers of biological functions and the effects of atmospheric-pressure non-thermal plasmas on proteins are important to applications such as sterilization and plasma-induced apoptosis of cancer cells. Herein, we report our detailed investigation of the effects of helium-oxygen non-thermal dielectric barrier discharge (DBD) plasmas on the inactivation of lactate dehydrogenase (LDH) enzyme solutions. Circular dichroism (CD) and dynamic light scattering (DLS) indicate that the loss of activity stems from plasma-induced modification of the secondary molecular structure as well as polymerization of the peptide chains. Raising the treatment intensity leads to a reduced alpha-helix content, increase in the percentage of the beta-sheet regions and random sequence, as well as gradually decreasing LDH activity. However, the structure of the LDH plasma-treated for 300 seconds exhibits a recovery trend after storage for 24 h and its activity also increases slightly. By comparing direct and indirect plasma treatments, plasma-induced LDH inactivation can be attributed to reactive species (RS) in the plasma, especially ones with a long lifetime including hydrogen peroxide, ozone, and nitrate ion which play the major role in the alteration of the macromolecular structure and molecular diameter in lieu of heat, UV radiation, and charged particles.

  6. Synthesis of flat sticky hydrophobic carbon diamond-like films using atmospheric pressure Ar/CH4 dielectric barrier discharge

    Science.gov (United States)

    Rincón, R.; Hendaoui, A.; de Matos, J.; Chaker, M.

    2016-06-01

    An Ar/CH4 atmospheric pressure dielectric barrier discharge (AP-DBD) was used to synthesize sticky hydrophobic diamond-like carbon (DLC) films on glass surface. The film is formed with plasma treatment duration shorter than 30 s, and water contact angles larger than 90° together with contact angle hysteresis larger than 10° can be achieved. According to Fourier transform infrared spectroscopy and atomic force microscopy analysis, hydrocarbon functional groups are created on the glass substrate, producing coatings with low surface energy (˜35 mJ m-2) with no modification of the surface roughness. To infer the plasma processes leading to the formation of low energy DLC surfaces, optical emission spectroscopy was used. From the results, a direct relationship between the CH species present in the plasma and the carbon concentration in the hydrophobic layer was found, which suggests that the CH species are the precursors of DLC film growth. Additionally, the plasma gas temperature was measured to be below 350 K which highlights the suitability of using AP-DBD to treat thermo-sensitive surfaces.

  7. A corona discharge atmospheric pressure chemical ionization source with selective NO(+) formation and its application for monoaromatic VOC detection.

    Science.gov (United States)

    Sabo, Martin; Matejčík, Štefan

    2013-11-21

    We have developed a new type of corona discharge (CD) for atmospheric pressure chemical ionization (APCI) for application in ion mobility spectrometry (IMS) as well as in mass spectrometry (MS). While the other CD-APCI sources are able to generate H3O(+)·(H2O)n as the major reactant ions in N2 or in zero air, the present CD-APCI source has the ability to generate up to 84% NO(+)·(H2O)n reactant ions in zero air. The change of the working gas from zero air to N2 allows us to change the major reactant ions from NO(+)·(H2O)n to H3O(+)·(H2O)n. In this paper we present the description of the new CD-APCI and discuss the processes associated with the NO(+) formation. The selective formation of NO(+)·(H2O)n reactant ions offers chemical ionization based on these ions which can be of great advantage for some classes of chemicals. We demonstrate here a significant increase in the sensitivity of the IMS-MS instrument for monoaromatic volatile organic compound (VOC) detection upon NO(+)·(H2O)n chemical ionization.

  8. Nitric oxide-assisted atmospheric pressure corona discharge ionization for the analysis of automobile hydrocarbon emission species.

    Science.gov (United States)

    Dearth, M A; Komiski, T J

    1994-12-01

    Nitric oxide reagent gas has been found to improve the sensitivity and robustness of the atmospheric pressure corona discharge ionization (APCDI) process. Sensitivity has been increased by a factor of 20-100, depending on the compound, over APCDI without nitric oxide. The robustness (defined as the sensitivity to matrix interferences) of APCDI in the presence of water has been improved by a factor of 3 over normal APCDI. These improvements are due in part to a modification of the commercial inlet system and ionization chamber that allows the chamber and sample gases to be heated to 100 and 350°C, respectively. Nitric oxide was chosen as the reagent gas because of the variety and selectivity of its interaction with hydrocarbons with differing functional groups. Product ions of nitric oxide ionization and their subsequent tandem mass spectra are presented and discussed for selected alkanes; alkenes, alkylbenzenes, alcohols; aldehydes, and an ether. A tandem mass spectrometry (unique parent ion-daughter ion transition) method was developed to quantify compounds of specific interest in vehicle emissions. The absolute sensitivity for these compounds, under ideal conditions, was determined and ranges from 0.006 ppb for xylene (most sensitive) to 80 ppb for C8 (or larger) normal alkanes. Routine sensitivity for real-world samples was in the single parts per billion range for aromatic and olefinic species. Potential applications include the real-time, on-line monitoring of selected hydrocarbons in automobile exhaust.

  9. Treatment of Candida albicans biofilms with low-temperature plasma induced by dielectric barrier discharge and atmospheric pressure plasma jet

    Energy Technology Data Exchange (ETDEWEB)

    Koban, Ina; Welk, Alexander; Meisel, Peter; Holtfreter, Birte; Kocher, Thomas [Unit of Periodontology, Dental School, University of Greifswald, Rotgerberstr. 8, 17475 Greifswald (Germany); Matthes, Rutger; Huebner, Nils-Olaf; Kramer, Axel [Institute for Hygiene and Environmental Medicine, University of Greifswald, Walther-Rathenau-Str. 49 a, 17487 Greifswald (Germany); Sietmann, Rabea [Institute of Microbiology, University of Greifswald, Friedrich-Ludwig-Jahn-Str. 15, 17487 Greifswald (Germany); Kindel, Eckhard; Weltmann, Klaus-Dieter, E-mail: ina.koban@uni-greifswald.d [Leibniz Institute for Plasma Science and Technology (INP), Felix-Hausdorff-Str. 2, 17489 Greifswald (Germany)

    2010-07-15

    Because of some disadvantages of chemical disinfection in dental practice (especially denture cleaning), we investigated the effects of physical methods on Candida albicans biofilms. For this purpose, the antifungal efficacy of three different low-temperature plasma devices (an atmospheric pressure plasma jet and two different dielectric barrier discharges (DBDs)) on Candida albicans biofilms grown on titanium discs in vitro was investigated. As positive treatment controls, we used 0.1% chlorhexidine digluconate (CHX) and 0.6% sodium hypochlorite (NaOCl). The corresponding gas streams without plasma ignition served as negative treatment controls. The efficacy of the plasma treatment was determined evaluating the number of colony-forming units (CFU) recovered from titanium discs. The plasma treatment reduced the CFU significantly compared to chemical disinfectants. While 10 min CHX or NaOCl exposure led to a CFU log{sub 10} reduction factor of 1.5, the log{sub 10} reduction factor of DBD plasma was up to 5. In conclusion, the use of low-temperature plasma is a promising physical alternative to chemical antiseptics for dental practice.

  10. Effects and Mechanism of Atmospheric-Pressure Dielectric Barrier Discharge Cold Plasma on Lactate Dehydrogenase (LDH) Enzyme

    Science.gov (United States)

    Zhang, Hao; Xu, Zimu; Shen, Jie; Li, Xu; Ding, Lili; Ma, Jie; Lan, Yan; Xia, Weidong; Cheng, Cheng; Sun, Qiang; Zhang, Zelong; Chu, Paul K.

    2015-05-01

    Proteins are carriers of biological functions and the effects of atmospheric-pressure non-thermal plasmas on proteins are important to applications such as sterilization and plasma-induced apoptosis of cancer cells. Herein, we report our detailed investigation of the effects of helium-oxygen non-thermal dielectric barrier discharge (DBD) plasmas on the inactivation of lactate dehydrogenase (LDH) enzyme solutions. Circular dichroism (CD) and dynamic light scattering (DLS) indicate that the loss of activity stems from plasma-induced modification of the secondary molecular structure as well as polymerization of the peptide chains. Raising the treatment intensity leads to a reduced alpha-helix content, increase in the percentage of the beta-sheet regions and random sequence, as well as gradually decreasing LDH activity. However, the structure of the LDH plasma-treated for 300 seconds exhibits a recovery trend after storage for 24 h and its activity also increases slightly. By comparing direct and indirect plasma treatments, plasma-induced LDH inactivation can be attributed to reactive species (RS) in the plasma, especially ones with a long lifetime including hydrogen peroxide, ozone, and nitrate ion which play the major role in the alteration of the macromolecular structure and molecular diameter in lieu of heat, UV radiation, and charged particles.

  11. Production mechanism of atomic nitrogen in atmospheric pressure pulsed corona discharge measured using two-photon absorption laser-induced fluorescence

    Energy Technology Data Exchange (ETDEWEB)

    Teramoto, Yoshiyuki; Ono, Ryo [Department of Advanced Energy, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 227-8568 (Japan); Oda, Tetsuji [Department of Electrical Engineering, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

    2012-06-01

    To study the production mechanism of atomic nitrogen, the temporal profile and spatial distribution of atomic nitrogen are measured in atmospheric pressure pulsed positive corona discharge using two-photon absorption laser-induced fluorescence. The absolute atomic nitrogen density in the streamer filaments is estimated from decay rate of atomic nitrogen in N{sub 2} discharge. The results indicate that the absolute atomic nitrogen density is approximately constant against discharge energy. When the discharge voltage is 21.5 kV, production yield of atomic nitrogen produced by an N{sub 2} discharge pulse is estimated to be 2.9 - 9.8 Multiplication-Sign 10{sup 13} atoms and the energy efficiency of atomic nitrogen production is estimated to be about 1.8 - 6.1 Multiplication-Sign 10{sup 16} atoms/J. The energy efficiency of atomic nitrogen production in N{sub 2} discharge is constant against the discharge energy, while that in N{sub 2}/O{sub 2} discharge increases with discharge energy. In the N{sub 2}/O{sub 2} discharge, two-step process of N{sub 2} dissociation plays significant role for atomic nitrogen production.

  12. Effect of discharge polarity on the propagation of atmospheric-pressure helium plasma jets and the densities of OH, NO, and O radicals.

    Science.gov (United States)

    Yonemori, Seiya; Ono, Ryo

    2015-06-01

    The atmospheric-pressure helium plasma jet is an emerging technology for plasma biomedical applications. In this paper, the authors focus on the effect of discharge polarity on propagation of the discharge and the densities of OH, NO, and O radicals. The plasma jet is applied to a glass surface placed on a grounded metal plate. Positive or negative voltage pulses with 25 μs duration, 8 kV amplitude, and 10 kpps repetition rate are used for the plasma jet. The plasma propagation is measured using a short-gated ICCD camera. The light emission intensity of the discharge generated at the rising phase of the voltage pulse is approximately equivalent for both polarities, while that generated during the falling phase is much higher for the negative discharge than the positive one. The shape of the discharge changes with the discharge polarity. The OH, NO, and O densities in the plasma jet are also measured for both polarities. It is found that the OH density is almost the same regardless the discharge polarity. Conversely, the negative discharge produces more O atoms and the positive discharge produces more NO molecules. These results indicate that the polarity of the discharge affects the densities of some reactive species produced in the plasma jet.

  13. Deactivation of Streptococcus mutans Biofilms on a Tooth Surface Using He Dielectric Barrier Discharge at Atmospheric Pressure

    Science.gov (United States)

    Imola, Molnar; Judit, Papp; Alpar, Simon; Sorin, Dan Anghel

    2013-06-01

    This paper presents a study of the effect of the low temperature atmospheric helium dielectric barrier discharge (DBD) on the Streptococcus mutans biofilms formed on tooth surface. Pig jaws were also treated by plasma to detect if there is any harmful effect on the gingiva. The plasma was characterized by using optical emission spectroscopy. Experimental data indicated that the discharge is very effective in deactivating Streptococcus mutans biofilms. It can destroy them with an average decimal reduction time (D-time) of 19 s and about 98% of them were killed after a treatment time of 30 s. According to the survival curve kinetic an overall 32 s treatment time would be necessary to perform a complete sterilization. The experimental results presented in this study indicated that the helium dielectric barrier discharge, in plan-parallel electrode configuration, could be a very effective tool for deactivation of oral bacteria and might be a promising technique in various dental clinical applications.

  14. Collision-Induced Dissociation Study of the Adduct Ions Produced in NO3 (-)-Free Area of Atmospheric Pressure Negative Corona Discharges under Ambient Air Conditions.

    Science.gov (United States)

    Sekimoto, Kanako; Matsuda, Natsuki; Takayama, Mitsuo

    2013-01-01

    Collision-induced dissociation (CID) experiments of adducts [M+R](-) with negative atmospheric ions R(-) (O2 (-), HCO3 (-) and COO(-)(COOH)) produced in NO3 (-)-free discharge area in atmospheric pressure corona discharge ionization (APCDI) method were performed using aliphatic and aromatic compounds M. The [M+R](-) adducts for individual R(-) fragmented to form deprotonated analytes [M-H](-) as well as the specific product ions which also occurred in the CID of [M-H](-), independent of analytes with several different functional groups. The results obtained suggested that the specific product ions formed in the CID of [M+R](-), as well as CID of [M-H](-), are generated due to further fragmentation of the product ions [M-H](-). It was concluded, therefore, that CID of [M+R](-) formed in NO3 (-)-free discharge area can indirectly lead to the formation of the product ions originating from [M-H](-).

  15. Experimental and modeling study of the oxidation of acetaldehyde in an atmospheric-pressure pulsed corona discharge

    Science.gov (United States)

    Klett, C.; Touchard, S.; Vega-Gonzalez, A.; Redolfi, M.; Bonnin, X.; Hassouni, K.; Duten, X.

    2012-08-01

    This paper reports the results obtained for the degradation of acetaldehyde by an atmospheric plasma corona discharge working in a pulsed regime. It was shown that a few hundred ppm of acetaldehyde diluted in a pure N2 gas flow can be removed up to 80% by a discharge fed with an electric power lower than 1 W. Under the same conditions, adding up to 5% of O2 allowed the removal of up to 95% of the initial acetaldehyde. The main identified end products were CO2, CO and methanol. A quasi-homogeneous zero-dimensional chemical model was developed to investigate the respective efficiency of the discharge and post-discharge periods in the global removal of the pollutant. The identified main pathways of acetaldehyde degradation were quenching of N2 metastable states during plasma pulses and oxidation by O and OH radicals during the post-discharge. This latter contribution increased with input power because of ozone accumulation in the gas mixture acting as an additional oxygen reservoir.

  16. A New Approach to Plasma CVD of TiO2 Photocatalyst on γ-Al2O3 Pellet Filled in Dielectric Barrier Discharges at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    朱爱民; 聂龙辉; 张秀玲; 石川; 宋志民; 徐勇

    2004-01-01

    A supported TiO2/γ-Al2O3 photocatalyst has been prepared by γ-Al2O3 pellet-filled dielectric barrier discharges induced plasma CVD at atmospheric pressure and room temperature.The TiO2/γ-Al2O3 photocatalyst exhibits higher photocatalytic activity than Degussa P25, and much higher photocatalytic activity than that prepared by thermal CVD.

  17. Dynamics of the atmospheric pressure diffuse dielectric barrier discharge between cylindrical electrodes in roll-to-roll PECVD reactor

    Science.gov (United States)

    Starostin, Sergey A.; Welzel, Stefan; Liu, Yaoge; van der Velden-Schuermans, Bernadette; Bouwstra, Jan B.; van de Sanden, Mauritius C. M.; de Vries, Hindrik W.

    2015-07-01

    The high current diffuse dielectric barrier discharge (DBD) was operated in a bi-axial cylindrical electrode configuration using nitrogen, oxygen and argon gas flow with the addition of tetraethyl orthosilicate as precursor for silica-like film deposition. The behaviour of the transient plasma was visualized by means of fast imaging from two orthogonal directions. The formation and propagation (~3 × 104 m s-1) of lateral ionization waves with the transverse light emission structure similar to the low pressure glow discharge was observed at time scales below 1 µs. Despite plasma non-uniformity at nanosecond time scale the deposition process on the web-rolled polymer results in smooth well adherent films with good film uniformity and excellent gas diffusion barrier properties. Contribution to the topical issue "The 14th International Symposium on High Pressure Low Temperature Plasma Chemistry (HAKONE XIV)", edited by Nicolas Gherardi, Ronny Brandenburg and Lars Stollenwark

  18. Run-to-run variations, asymmetric pulses, and long time-scale transient phenomena in dielectric-barrier atmospheric pressure glow discharges

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Jichul; Raja, Laxminarayan L [Department of Aerospace Engineering and Engineering Mechanics, University of Texas at Austin, Austin, TX 78712 (United States)

    2007-05-21

    The dielectric-barrier (DB) discharge is an important approach to generate uniform non-equilibrium atmospheric-pressure glow discharges. We report run-to-run variations, asymmetric pulse formation and long time-scale transient phenomena in these discharges. For similar DB discharge geometric and operating conditions, we observe significant run-to-run variations as manifested in the different voltage-current waveforms at the start of each new run. These run-to-run variations are also accompanied by asymmetric pulses at the start of each run. The variations are observed to drift to a repeatable true steady-state condition on time scales of order tens of minutes to hours. Asymmetric pulse waveforms drift to a symmetric pulse waveform at the true steady state. We explore reasons for these phenomena and rule out thermal drift during a discharge run and gas-phase impurity buildup as potential causes. The most plausible explanation appears to be variations in the surface characteristics of the DBs between two consecutive runs owing to varying inter-run environmental exposure and the conditioning of the dielectric surface during a run owing to plasma-surface interactions. We speculate that the dielectric surface state affects the secondary electron emission coefficient of the surface which in turn is manifested in the discharge properties. A zero-dimensional model of the discharge is used to explore the effect of secondary electron emission.

  19. The effect of frequency on atmospheric pressure glow discharge in a pin-to-plate gap sustained by a resonant power supply

    Science.gov (United States)

    Wang, Yong Sheng; Ding, Wei Dong; Wang, Ya Nan; Wang, Jia Chen; Li, Fang; Fan, Chuan

    2016-06-01

    More and more researchers have been attracted to the research of atmospheric pressure glow discharge (APGD) because of its great prospect in numerous industrial applications. Nevertheless, almost all of the industrial applications are based on achievement of stable, large-volume, and uniform APGD. In a previous study, stable filamentary APGD was obtained by applying a resonant power supply between pin-to-plate electrodes which could limit the peak value of discharge current to supress the glow-to-arc transition through a series-wound resonance principle. The filamentary APGD is centimeter-level in the length but only several millimeters in diameter. Therefore, in order to obtain large-volume and uniform APGD, it is significant to study how to diffuse filamentary APGD in radial direction. With the increasing resonant frequency of alternating current discharge, excited particles (mainly including energetic electrons and trapped ions left from the previous half-cycle discharge) in the electrodes gap increase, which benefits obtaining stable self-sustaining APGD. In this paper, mechanism and law of the influence of resonant frequency on the diffusion of filamentary APGD in ambient air were studied. By comparing the photos of discharge plasma and waveforms of the discharge voltage and current, it is found that the volume of the glow discharge plasma enlarges as the resonant frequency of the power supply increases. It is very significant and anticipating to study how to obtain stable, large-volume, and uniform APGD in ambient air by the resonant power supply.

  20. Plasma density enhancement in atmospheric-pressure dielectric-barrier discharges by high-voltage nanosecond pulse in the pulse-on period: a PIC simulation

    Science.gov (United States)

    Sang, Chaofeng; Sun, Jizhong; Wang, Dezhen

    2010-02-01

    A particle-in-cell (PIC) plus Monte Carlo collision simulation is employed to investigate how a sustainable atmospheric pressure single dielectric-barrier discharge responds to a high-voltage nanosecond pulse (HVNP) further applied to the metal electrode. The results show that the HVNP can significantly increase the plasma density in the pulse-on period. The ion-induced secondary electrons can give rise to avalanche ionization in the positive sheath, which widens the discharge region and enhances the plasma density drastically. However, the plasma density stops increasing as the applied pulse lasts over certain time; therefore, lengthening the pulse duration alone cannot improve the discharge efficiency further. Physical reasons for these phenomena are then discussed.

  1. Effect of water vapor on plasma morphology, OH and H2O2 production in He and Ar atmospheric pressure dielectric barrier discharges

    Science.gov (United States)

    Du, Yanjun; Nayak, Gaurav; Oinuma, Gaku; Peng, Zhimin; Bruggeman, Peter J.

    2017-04-01

    Although atmospheric pressure dielectric barrier discharges (DBDs) have a long history, the effects of water vapor on the discharge morphology and kinetics have not been studied intensively. We report a simultaneous investigation of discharge morphology, OH and H2O2 production in Ar and He DBDs operated at different water vapor concentrations and powers. The combined study allows us to assess the impact of the discharge morphology and power on the concentration dependence of the OH and H2O2 production. The morphology of the discharge is investigated by ICCD images and current–voltage waveforms. These diagnostics are complemented by broadband absorption and a colorimetric method to measure the gas temperature and the OH and H2O2 concentrations. The number of filaments in Ar DBD increases with increasing water concentration and power. The surface discharge part of the micro-discharge also reduces with increasing water concentration most likely due to a change in surface conductivity of the dielectric with changing water concentration. The OH density in the case of Ar is approximately double the OH density in He for similar power and water admixture. In contrast to the root square dependence of the OH density on the water concentration in He similar to diffuse RF discharges, the OH density in Ar increases for small water concentrations followed by a saturation and reduces for higher water concentrations. This dependence of OH density on water concentration is found to correlate with changes in discharge morphology. An analytical balance of the production and destruction mechanism of H2O2 is shown to be able to reproduce the ratio of the measured OH and H2O2 density for realistic values of electron densities.

  2. Plasma-enhanced CVD of functional coatings in Ar/maleic anhydride/C2H2 homogeneous dielectric barrier discharges at atmospheric pressure

    Science.gov (United States)

    Zajíčková, Lenka; Jelínek, Petr; Obrusník, Adam; Vodák, Jiří; Nečas, David

    2017-03-01

    In this contribution, we focus on the general problems of plasma-enhanced chemical vapor deposition in atmospheric pressure dielectric barrier discharges, i.e. deposition uniformity, film roughness and the formation of dust particles, and demonstrate them on the example of carboxyl coatings prepared by co-polymerization of acetylene and maleic anhydride. Since the transport of monomers at atmospheric pressure is advection-driven, special attention is paid to the gas dynamics simulations, gas flow patterns, velocity and residence time. By using numerical simulations, we design an optimized gas supply geometry capable of synthesizing uniform layers. The selection of the gas mixture containing acetylene was motivated by two of its characteristics: (i) suppression of filaments in dielectric barrier discharges, and (ii) improved film cross-linking, keeping the amount of functional groups high. However, acetylene discharges are prone to the formation of nanoparticles that can be incorporated into the deposited films, leading to their high roughness. Therefore, we also discuss the role of the gas composition, the spatial position of the substrate with respect to gas flow and the deposition time on the topography of the deposited films.

  3. Comparison of dielectric barrier discharge, atmospheric pressure radiofrequency-driven glow discharge and direct analysis in real time sources for ambient mass spectrometry of acetaminophen

    Energy Technology Data Exchange (ETDEWEB)

    Kratzer, Jan [Institute for National Measurement Standards, National Research Council of Canada, 1200 Montreal Road, Ottawa, Ontario, K1A 0R6 (Canada); Institute of Analytical Chemistry of the ASCR, v.v.i., Veveri 97, CZ-602 00 Brno (Czech Republic); Mester, Zoltan [Institute for National Measurement Standards, National Research Council of Canada, 1200 Montreal Road, Ottawa, Ontario, K1A 0R6 (Canada); Sturgeon, Ralph E., E-mail: Ralph.Sturgeon@nrc-cnrc.gc.ca [Institute for National Measurement Standards, National Research Council of Canada, 1200 Montreal Road, Ottawa, Ontario, K1A 0R6 (Canada)

    2011-08-15

    Three plasma-based ambient pressure ion sources were investigated; laboratory constructed dielectric barrier and rf glow discharges, as well as a commercial corona discharge (DART source). All were used to desorb and ionize a model analyte, providing sampling techniques for ambient mass spectrometry (MS). Experimental parameters were optimized to achive highest signal for acetaminophen as the analyte. Insight into the mechanisms of analyte desorption and ionization was obtained by means of emission spectrometry and ion current measurements. Desorption and ionization mechanisms for this analyte appear to be identical for all three plasma sources. Emission spectra differ only in the intensities of various lines and bands. Desorption of solid analyte requires transfer of thermal energy from the plasma source to sample surface, in the absence of which complete loss of MS response occurs. For acetaminophen, helium was the best plasma gas, providing 100- to 1000-fold higher analyte response than with argon or nitrogen. The same trend was also evident with background ions (protonated water clusters). MS analyte signal intensity correlates with the ion density (expressed as ion current) in the plasma plume and with emission intensity from excited state species in the plasma. These observations support an ionization process which occurs via proton transfer from protonated water clusters to analyte molecules.

  4. Numerical Study on Atmospheric Pressure DBD in Helium: Single-breakdown and Multi-breakdown Discharges%Numerical Study on Atmospheric Pressure DBD in Helium: Single-breakdown and Multi-breakdown Discharges

    Institute of Scientific and Technical Information of China (English)

    王小华; 杨爱军; 荣命哲; 刘定新

    2011-01-01

    A 1-D fluid model for homogeneous dielectric barrier discharge (DBD) in helium is presented, aimed at unraveling the spatial-temporal characteristics of two basic discharge regimes: single-breakdown and multi-breakdown discharges. Discharge currents, gap voltages, charge densities, electron temperature and electric field profiles of the two regimes make it clear that these two regimes are qualitatively different. It is found that the multi-breakdown discharge has a more homogeneous flux on dielectrics compared to the single-breakdown discharge.

  5. Measurement of vibrationally excited N2(v) in an atmospheric-pressure air pulsed corona discharge using coherent anti-Stokes Raman scattering

    Science.gov (United States)

    Teramoto, Yoshiyuki; Ono, Ryo

    2014-08-01

    Vibrationally excited N2(v = 1, 2) in an atmospheric-pressure air pulsed corona discharge was measured using coherent anti-Stokes Raman scattering (CARS). In a dry air discharge, the vibrational temperature determined from the ratio N2(v = 2)/N2(v = 0), Tv2, was approximately 500 K higher than that determined from N2(v = 1)/N2(v = 0), Tv1, immediately after the discharge pulse. Both vibrational temperatures reached equilibrium within 100 μs after the discharge pulse by the vibration-to-vibration (V-V) process of N2-N2. The translational temperature was also measured using CARS. The rise in the translational temperature due to vibration-to-translation (V-T) energy transfer was not observed for a postdischarge time of 5 μs-1 ms in the dry-air discharge. However, when the air was humidified, a significant V-T energy transfer was observed. It was due to an extremely rapid V-T process of H2O-H2O following the V-V process of N2-H2O. Measurements showed that the humidification of the ambient air accelerated the decrease in the N2 vibrational temperature and increased the translational temperature. N2(v) was generated mostly in the secondary streamer, not in the primary one, according to estimation from the measured N2(v) density.

  6. Characterizing uniform discharge in atmospheric helium by numerical modelling

    Institute of Scientific and Technical Information of China (English)

    Lü Bo; Wang Xin-Xin; Luo Hai-Yun; Liang Zhuo

    2009-01-01

    One-dimensional fluid model of dielectric barrier discharge (DBD) in helium at atmospheric pressure was estab-lished and the discharge was numerically simulated. It was found that not only the spatial distributions of the internal parameters such as the electric field, the electron density and ion density are similar to those in a low-pressure glow discharge, but also the visually apparent attribute (light emission) is exactly the same as the observable feature of a low-pressure glow discharge. This confirms that the uniform DBD in atmosphcric helium is a glow type discharge. The fact that the thickness of the cathode fall layer is about 0.5 ram, much longer than that of a normal glow dischargc in helium at atmospheric pressure, indicates the discharge being a sub-normal glow discharge close to normal one. The multipulse phenomenon was reproduced in the simulation and a much less complicated explanation for this phenomenon was given.

  7. High-pressure hollow cathode discharges

    Science.gov (United States)

    Schoenbach, Karl H.; El-Habachi, Ahmed; Shi, Wenhui; Ciocca, Marco

    1997-11-01

    Reducing the diameter of the cathode hole in a plane anode - hollow cathode geometry to 0963-0252/6/4/003/img1m has allowed us to generate direct current discharges in argon at atmospheric pressure. Up to pressure times cathode hole diameter (pD) values of approximately 5 Torr cm, and at sub-mA currents, glow discharges (predischarges) are observed with a shape which is determined by the vacuum electric field. In the same pD range, but at higher currents of up to approximately 4 mA, the discharges are of the hollow cathode discharge type. At pD values exceeding 5 Torr cm the predischarges turn into surface discharges along the mica spacer between the electrodes. At currents > 4 mA filamentary, pulsed discharges are observed. Qualitative information on the electron energy distribution in the microdischarges has been obtained by studying the VUV emission from ionized argon atoms and the argon excimer radiation at 130 nm. The results of the spectral measurements indicate the presence of a relatively large concentration of electrons with energies > 15 eV over the entire pressure range. The fact that the current - voltage characteristic of the microdischarges has a positive slope over much of the current range where excimer radiation is emitted indicates the possibility of forming arrays of these discharges and using them in flat panel excimer lamps.

  8. Numerical studies of independent control of electron density and gas temperature via nonlinear coupling in dual-frequency atmospheric pressure dielectric barrier discharge plasmas

    Science.gov (United States)

    Zhang, Z. L.; Nie, Q. Y.; Wang, Z. B.; Gao, X. T.; Kong, F. R.; Sun, Y. F.; Jiang, B. H.

    2016-07-01

    Dielectric barrier discharges (DBDs) provide a promising technology of generating non-equilibrium cold plasmas in atmospheric pressure gases. For both application-focused and fundamental studies, it is important to explore the strategy and the mechanism for enabling effective independent tuning of key plasma parameters in a DBD system. In this paper, we report numerical studies of effects of dual-frequency excitation on atmospheric DBDs, and modulation as well as separate tuning mechanism, with emphasis on dual-frequency coupling to the key plasma parameters and discharge evolution. With an appropriately applied low frequency to the original high frequency, the numerical calculation demonstrates that a strong nonlinear coupling between two frequencies governs the process of ionization and energy deposition into plasma, and thus raises the electron density significantly (e.g., three times in this case) in comparisons with a single frequency driven DBD system. Nevertheless, the gas temperature, which is mainly determined by the high frequency discharge, barely changes. This method then enables a possible approach of controlling both averaged electron density and gas temperature independently.

  9. Transitions of an atmospheric-pressure diffuse dielectric barrier discharge in helium for frequencies increasing from kHz to MHz

    Science.gov (United States)

    Boisvert, J.-S.; Margot, J.; Massines, F.

    2017-03-01

    Recent studies have shown that tuning a dielectric barrier discharge (DBD) in the medium-frequency range (MF: from 0.3 to 3 MHz) allows a low-power and a high-power mode to be sustained. In the present article the effect of the driving frequency on a DBD is studied from the low-frequency range (LF: from 30 to 300 kHz) to the high-frequency range (HF: from 3 to 30 MHz). This is achieved using fast imaging together with electrical and spectroscopic diagnostics. At every frequency, a diffuse discharge is sustained. It is observed that at 25 kHz the discharge is an atmospheric-pressure glow discharge (APGD) while at 15 MHz the discharge behaves as a capacitive discharge in the RF-α mode. The usual LF APGD behavior is observed up to 100 kHz. Above 200 kHz, the positive column remains during the whole cycle so that the hybrid mode is sustained. At 5 MHz, the hybrid mode finally turns into the RF-α mode. In addition to the LF APGD, RF-α and hybrid modes obtained when the applied voltage is significantly higher than the ignition value, two other modes can be reached at low applied voltage. A Townsend-like mode is achieved from 50 to 100 kHz while in the medium-frequency range, the Ω mode is sustained. Moreover, only from 1.0 to 2.7 MHz there is a large hysteresis occurring when the discharge transits back and forth from the Ω to the hybrid mode. It is also found that when the frequency increases from 25 kHz to 15 MHz, the rms current increases over two orders of magnitudes while the rms voltage decreases by about 60%. The gas temperature estimated from N2 rotational spectra is always close to room temperature but the discharge is more energy efficient (in the HF range) as a lower fraction of energy turns into gas heating.

  10. Time-resolved OES of nanosecond pulsed discharges in N$_{2}$ and N$_{2}$/H$_{2}$O mixtures]{Time-resolved optical emission spectroscopy of nanosecond pulsed discharges in atmospheric pressure N$_{2}$ and N$_{2}$/H$_{2}$O mixtures

    CERN Document Server

    van der Horst, R M; van Veldhuizen, E M; Bruggeman, P J

    2014-01-01

    In this contribution, nanosecond pulsed discharges in N$_{2}$ and N$_{2}$/0.9% H$_{2}$O at atmospheric pressure (at 300 K) are studied with time-resolved imaging, optical emission spectroscopy and Rayleigh scattering. A 170 ns high voltage pulse is applied across two pin-shaped electrodes at a frequency of 1 kHz. The discharge consists of three phases: an ignition phase, a spark phase and a recombination phase. During the ignition phase the emission is mainly caused by molecular nitrogen (N$_{2}$(C-B)). In the spark and recombination phase mainly atomic nitrogen emission is observed. The emission when H$_{2}$O is added is very similar, except the small contribution of H$_{\\alpha}$ and the intensity of the molecular N$_{2}$(C-B) emission is less.

  11. Detection of Amines and Ammonia with an Ambient Pressure Mass Spectrometer using a Corona Discharge Ion Source, in an Urban Atmosphere and in a Teflon Film Chamber

    Science.gov (United States)

    Alves, M.; Hanson, D. R.; Grieves, C.; Ortega, J. V.

    2015-12-01

    Amines and ammonia are an important group of molecules that can greatly affect atmospheric particle formation that can go on to impact cloud formation and their scattering of thermal and solar radiation, and as a result human health and ecosystems. In this study, an Ambient Pressure Mass Spectrometer (AmPMS) that is selective and sensitive to molecules with a high proton affinity, such as amines, was coupled with a newly built corona discharge ion source. AmPMS was used to monitor many different nitrogenous compound that are found in an urban atmosphere (July 2015, Minneapolis), down to the single digit pmol/mol level. Simultaneous to this, a proton transfer mass spectrometer also sampled the atmosphere through an inlet within 20 m of the AmPMS inlet. In another set of studies, a similar AmPMS was attached to a large Teflon film chamber at the Atmospheric Chemistry Division at NCAR (August 2015, Boulder). Exploratory studies are planned on the sticking of amines to the chamber walls as well as oxidizing the amine and monitoring products. Depending on the success of these studies, results will be presented on the reversability of amine partitioning and mass balance for these species in the chamber.

  12. Application of post-discharge region of atmospheric pressure argon and air plasma jet in the contamination control of Candida albicans biofilms

    Directory of Open Access Journals (Sweden)

    Anelise Cristina Osório Cesar Doria

    Full Text Available Introduction:Candida species are responsible for about 80% of hospital fungal infections. Non-thermal plasmas operated at atmospheric pressure are increasingly used as an alternative to existing antimicrobial strategy. This work investigates the action of post-discharge region of a non-thermal atmospheric plasma jet, generated by a gliding arc reactor, on biofilms of standard strain of Candida albicans grown on polyurethane substrate. Methods Samples were divided into three groups: (i non-treated; (ii treated with argon plasma, and (iii treated with argon plus air plasma. Subsequently to plasma treatment, counting of colony-forming units (CFU/ml and cell viability tests were performed. In addition, the surface morphology of the samples was evaluated by scanning electron microscopy (SEM and optical profilometry (OP. Results Reduction in CFU/ml of 85% and 88.1% were observed in groups ii and iii, respectively. Cell viability after treatment also showed reduction of 33% in group ii and 8% in group iii, in comparison with group i (100%. The SEM images allow observation of the effect of plasma chemistry on biofilm structure, and OP images showed a reduction of its surface roughness, which suggests a possible loss of biofilm mass. Conclusion The treatment in post-discharge region and the chemistries of plasma jet tested in this work were effective in controlling Candida albicans biofilm contamination. Finally, it was evidenced that argon plus air plasma was the most efficient to reduce cell viability.

  13. Control of Reactive Species Generated by Low-frequency Biased Nanosecond Pulse Discharge in Atmospheric Pressure Plasma Effluent

    Science.gov (United States)

    Takashima, Keisuke; Kaneko, Toshiro

    2016-09-01

    The control of hydroxyl radical and the other gas phase species generation in the ejected gas through air plasma (air plasma effluent) has been experimentally studied, which is a key to extend the range of plasma treatment. Nanosecond pulse discharge is known to produce high reduced electric field (E/N) discharge that leads to efficient generation of the reactive species than conventional low frequency discharge, while the charge-voltage cycle in the low frequency discharge is known to be well-controlled. In this study, the nanosecond pulse discharge biased with AC low frequency high voltage is used to take advantages of these discharges, which allows us to modulate the reactive species composition in the air plasma effluent. The utilization of the gas-liquid interface and the liquid phase chemical reactions between the modulated long-lived reactive species delivered from the air plasma effluent could realize efficient liquid phase chemical reactions leading to short-lived reactive species production far from the air plasma, which is crucial for some plasma agricultural applications.

  14. Investigation of the coplanar barrier discharge in synthetic air at atmospheric pressure by cross-correlation spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Hoder, T [Department of Physical Electronics, Masaryk University, Kotlarska 2, Brno 611 37 (Czech Republic); SIra, M [Department of Physical Electronics, Masaryk University, Kotlarska 2, Brno 611 37 (Czech Republic); Kozlov, K V [Institute of Physics, Ernst-Moritz-Arndt University, Felix-Hausdorff-Str. 6, D-17489 Greifswald (Germany); Wagner, H-E [Institute of Physics, Ernst-Moritz-Arndt University, Felix-Hausdorff-Str. 6, D-17489 Greifswald (Germany)

    2008-02-07

    The barrier discharge in the coplanar arrangement operating in a single-filament mode was studied spectroscopically. The evolution of the discharge luminosity was measured by the technique of cross-correlation spectroscopy. The 1D-spatially and temporally resolved luminosities of the first negative (at 391.5 nm) and the second positive (at 337.1 nm) system of molecular nitrogen were recorded using the above-mentioned technique. A cathode-directed ionizing wave (IW) was clearly seen on the plot for radiation intensity at 337.1 nm. In addition to this, also observed was a wave of the enhanced electric field propagating over the anode. In this paper, the propagation of these waves is described and their velocities are determined. The discharge evolution is divided into three phases-the Townsend phase, the phase of the IWs propagation and the extinction phase. Since the above-mentioned luminosity distributions could be interpreted approximately as the electric field (for 391.5 nm) and the electron density (for 337.1 nm) distribution, the qualitative description of the discharge is made accordingly. All these parameters are compared with similar measurements of the volume discharge. Apart from this, an attempt to determine the reduced electric field is made according to the kinetic model.

  15. Surface treatment of polypropylene (PP) film by 50 Hz dielectric barrier discharge produced in air and argon/air mixture at atmospheric pressure

    Science.gov (United States)

    Joshi, Ujjwal Man; Subedi, Deepak Prasad

    2015-07-01

    Thin films of polypropylene (PP) are treated for improving hydrophilicity using non-thermal plasma generated by 50 Hz line frequency dielectric barrier discharge produced in air and argon/air mixture at atmospheric pressure. PP samples before and after the treatments are studied using contact angle measurements, surface free energy calculations and scanning electron microscopy (SEM). Distilled water (H2O), glycerol (C3H8O3) and diiodomethane (CH2I2) are used as test liquids. The contact angle measurements between test liquids and PP samples are used to determine total surface free energy using sessile drop technique. PP films show a remarkable increase in surface free energy after plasma treatment. SEM analysis of the plasma-treated PP films shows that plasma treatment introduces greater roughness on the surface leading to the increased surface free energy. Furthermore, it is found that introducing a small quantity of argon can enhance the surface treatment remarkably.

  16. Surface treatment of high density polyethylene (HDPE film by 50 Hz dielectric barrier discharge produced in air and argon/air mixture at atmospheric pressure

    Directory of Open Access Journals (Sweden)

    Joshi Ujjwal Man

    2015-03-01

    Full Text Available Thin films of high density polyethylene (HDPE are treated for improving hydrophilicity using non-thermal plasma generated by 50 Hz line frequency dielectric barrier discharge produced in air and argon/air mixture at atmospheric pressure. HDPE samples before and after the treatment are studied using contact angle measurements, surface free energy calculations and atomic force microscopy (AFM. Distilled water (H2O, glycerol (C3H8O3 and diiodomethane (CH2I2 are used as test liquids. The contact angle measurements between test liquids and HDPE samples are used to determine total surface free energy using sessile drop technique. HDPE films show a remarkable increase in surface free energy after plasma treatment. AFM analysis of the plasma-treated HDPE films shows that plasma treatment introduces greater roughness on the surface leading to the increased surface free energy. Furthermore, it is found that introducing a small quantity of argon can enhance the surface treatment remarkably.

  17. Liquid sampling-atmospheric pressure glow discharge (LS-APGD) ionization source for elemental mass spectrometry: preliminary parametric evaluation and figures of merit.

    Science.gov (United States)

    Quarles, C Derrick; Carado, Anthony J; Barinaga, Charles J; Koppenaal, David W; Marcus, R Kenneth

    2012-01-01

    A new, low-power ionization source for the elemental analysis of aqueous solutions has recently been described. The liquid sampling-atmospheric pressure glow discharge (LS-APGD) source operates at relatively low currents (LS-APGD has been interfaced to what is otherwise an organic, LC-MS mass analyzer, the Thermo Scientific Exactive Orbitrap without any modifications, other than removing the electrospray ionization source supplied with that instrument. A glow discharge is initiated between the surface of the test solution exiting a glass capillary and a metallic counter electrode mounted at a 90° angle and separated by a distance of ~5 mm. As with any plasma-based ionization source, there are key discharge operation and ion sampling parameters that affect the intensity and composition of the derived mass spectra, including signal-to-background ratios. We describe here a preliminary parametric evaluation of the roles of discharge current, solution flow rate, argon sheath gas flow rate, and ion sampling distance as they apply on this mass analyzer system. A cursive evaluation of potential matrix effects due to the presence of easily ionized elements indicate that sodium concentrations of up to 50 μg mL(-1) generally cause suppressions of less than 50%, dependant upon the analyte species. Based on the results of this series of studies, preliminary limits of detection (LOD) have been established through the generation of calibration functions. While solution-based concentration LOD levels of 0.02-2 μg mL(-1) are not impressive on the surface, the fact that they are determined via discrete 5 μL injections leads to mass-based detection limits at picogram to single-nanogram levels. The overhead costs associated with source operation (10 W d.c. power, solution flow rates of LS-APGD ion source may present a practical alternative to inductively coupled plasma sources typically employed in elemental mass spectrometry.

  18. Evaluation of the operating parameters of the liquid sampling-atmospheric pressure glow discharge (LS-APGD) ionization source for elemental mass spectrometry.

    Science.gov (United States)

    Zhang, Lynn X; Manard, Benjamin T; Konegger-Kappel, Stefanie; Kappel, Stefanie Konegger; Marcus, R Kenneth

    2014-11-01

    The liquid sampling-atmospheric pressure glow discharge (LS-APGD) has been assessed as an ionization source for elemental analysis with an interdependent, parametric evaluation regarding sheath/cooling gas flow rate, discharge current, liquid flow rate, and the distance between the plasma and the sampling cone of the mass spectrometer. In order to better understand plasma processes (and different from previous reports), no form of collision/reaction processing was performed to remove molecular interferents. The evaluation was performed employing five test elements: cesium, silver, lead, lanthanum and nickel (10(-4) mol L(-1) in 1 mol L(-1) HNO3). The intensity of the atomic ions, levels of spectral background, the signal-to-background ratios, and the atomic-to-oxide/hydroxide adduct ratios were monitored in order to obtain fundamental understanding with regards to not only how each parameter effects the performance of this LS-APGD source, but also the inter-parametric effects. The results indicate that the discharge current and the liquid sampling flow rates are the key aspects that control the spectral composition. A compromise set of operating conditions was determined: sheath gas flow rate = 0.9 L min(-1), discharge current = 10 mA, solution flow rate = 10 μL min(-1), and sampling distance = 1 cm. Limits of detection (LODs) were calculated using the SBR-RSDB (signal-to-background ratio/relative standard deviation of the background) approach under the optimized condition. The LODs for the test elementals ranged from 15 to 400 ng mL(-1) for 10 μL injections, with absolute mass values from 0.2 to 4 ng.

  19. 针-板DBD微流注与微辉光交替生成的机理研究%Atmospheric pressure streamer and glow-discharge generated alternately by pin-to-plane dielectric barrier discharge in air

    Institute of Scientific and Technical Information of China (English)

    俞哲; 张芝涛; 于清旋; 许少杰; 姚京; 白敏冬; 田一平; 刘开颖

    2012-01-01

    Performance of producing a high energy electron can be improved, if the glow discharge is generated in a system of dielectric barrier discharge. In this paper, different discharge modes of pin-to-plane dielectric barrier discharge are investigated in atmospheric pressure. Different discharge modes are observed in the positive half-period and negative half-period of the discharge. When and applied voltage is 3 kV, a streamer mode appear in the positive half-period and a corona (or Trichel discharge) mode occurs in negative half-period. When the applied voltage is 6 kV, a streamer emerges in the positive half-period and a micro glow discharge is present in the negative half-period. The micro glow discharge has hierarchical structure like that typical low pressure glow discharge produces. The generation of micro glow discharge is due to, enough strong cathode electric field strength and effective secondary electron emission process around naked negative electrode. The glow discharge transforming to arc discharge is avoided due to dielectric layer.%在介质阻挡放电体系中产生辉光放电可以有效的提高放电体系产生高能电子的性能,为等离子体化学反应提供更加丰富的活性粒子.本文对针一板介质阻挡放电体系下的放电模式进行了研究,实验发现放电正负半周期表现出不同的放电模式,激励电压为3kV时放电正负半周期分别为微流注放电和电晕放电(或者Trichel脉冲放电),激励电压为6kV时放电正负半周期分别为微流注放电和微辉光放电.微辉光放电形貌具有与典型辉光放电相同的分层次放电结构,分析了激励电压6kV时的放电过程,认为足够强的阴极电场强度和裸露针状电极形成的有效的二次电子发射过程是形成微辉光放电的主要因素,绝缘介质层的存在避免了微辉光放电向弧光放电过渡.

  20. 大气压氖气介质阻挡放电研究%Investigation on Dielectric Barrier Discharge in Neon at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    冉俊霞; 罗海云; 王新新

    2011-01-01

    为了加深对大气压氖气介质阻挡放电特性的认识,使用电特性测量、高速摄影的手段研究了平板结构大气压氖气介质阻挡放电的击穿电压、放电模式及其演化过程等。实验结果表明,在2~8mm大气压氖气中可很容易地实现均匀放电,并且其放电模式为辉光放电。相比同样条件下的氦气放电,氖气放电的电流密度略小、电流脉冲的半高宽较大。同时测量并比较了气隙的首次击穿与稳态击穿的差异,发现气隙的首次击穿电压较大、击穿时刻偏迟,并基于种子电子的作用对此做出了解释。利用ICCD高速相机拍摄了时间分辨的放电图像,侧面放电图像显示了汤森放电向辉光%In order to have a deep understanding of dielectric barrier discharge(DBD) in neon at atmospheric pressure,the breakdown voltage,the discharge mode and evolution of DBD in a parallel neon gap were investigated by means of electrical measurements and fast photography.Homogenous discharges could be easily produced in 2~8mm gaps in neon and were attributed to glow discharge.Compared to that in helium,the homogenous DBD in neon had a smaller discharge current density and a wider current pulse.The differences between the first breakdown and subsequent steady breakdowns were measured,it was revealed that the first breakdown usually had a higher gap voltage and a later phase,as explained by the seed electrons and penning ionization.High-speed time-resolved photographs of the homogenous discharge in neon were taken using an ICCD camera with an exposure time of 10ns.Side-view photographs showed an evolution from Townsend discharge to glow discharge,which was similar to that observed in helium discharge,while the positive column could hardly be observed in neon at the sub-normal stage of the discharge.The end-view photographs showed a radial development in neon discharge which was also similar to that in helium.

  1. 大气压空气介质阻挡汤森放电%Townsend Dielectric Barrier Discharge in Atmospheric Pressure Air

    Institute of Scientific and Technical Information of China (English)

    罗海云; 冉俊霞; 王新新

    2012-01-01

    In order to experimentally study the possibility of homogenous dielectric barrier discharge (DBD) in atmospheric pressure air as well as its characteristics, the homogenous DBD in 3 mm air gap was obtained at atmospheric pressure, using 1-2 kHz sinusoidal high voltage and no less than 1. 5 mm thick alumina as the dielectrics. The discharge was proven as an atmospheric pressure Townsend discharge after analyzing the 10 ns exposure high-speed photographs and the current waveform. The steady breakdown voltage for 3 mm air DBD was calculated to be about 5. 7 kV, much lower than 11. 2 kV, the static breakdown voltage of 3 mm air gap; Extraordinary extinction was also observed in air just like in nitrogen. Both the two phenomena indicated the existence of the shallow traps and consequently the second-electron emissidn in the alumina surface, which were important for ignition and maintaining stage of Townsend DBD. It is found that the thickness of alumina is important for air DBD, and the thickness less than 1.5 mm can not avoid the filamentary discharge. If two 1 mm thick quartz plates are used instead of alumina, it is impossible to get homogenous DBD at 670 PaN 0. 1 MPa in air. The mechanism of Townsend DBD in 3 mm air gap is attributed to the combined effects of the unique shallow traps in the alumina surface and the current-limitation of the dielectrics.%为了实验研究大气压空气介质阻挡均匀放电的可能性,使用1.5mm以上厚度的A120s陶瓷片作为阻挡介质及1-2kHz的高压激励,在大气压3mm空气平板间隙中获得均匀放电。通过ICCD高速摄影得到的放电图像以及电流波形的分析表明这种放电是汤森放电。3mm空气间隙的稳态击穿电压仅约为5.7kV,远低于静态击穿电压11.2kv;还发现了类似氮气DBD汤森放电的“反常熄灭”现象,这两个现象表明陶瓷表面可能存在浅位阱及二次电子发射机制,这对空气汤森放电的起始和维持阶段都

  2. Electrohydrodynamic force produced by a wire-to-cylinder dc corona discharge in air at atmospheric pressure

    Science.gov (United States)

    Moreau, Eric; Benard, Nicolas; Lan-Sun-Luk, Jean-Daniel; Chabriat, Jean-Pierre

    2013-11-01

    Wire-to-cylinder corona discharges are studied to better understand the electrohydrodynamic (EHD) phenomena that govern the performances of electric propulsion systems. First, theory associated with EHD thrusters is presented in order to be compared with experimental results. Secondly, direct thrust measurements are carried out to optimize the electrical and geometrical parameters of such devices. The main results are as follows: (1) the discharge current I is proportional to the square root of the grounded electrode diameter and to 1/d2 where d is the electrode gap; (2) for d ⩽ 20 mm, the mobility of negative ions is higher than that of positive ions while the mobility of both ions is equal for higher gaps; (3) therefore, for gap ⩾30 mm, positive and negative coronas results in the same current-to-thrust conversion; (4) the current-to-thrust conversion is equal to 33 N A-1 per centimetre of gap, and it is proportional to the gap; (5) the thruster effectiveness θ increases with \\sqrt d , decreases with the square root of thrust and reaches about 15 N kW-1 for d = 40 mm (6) the force computed from experimental velocity profiles is overestimated compared with the values measured with a balance, showing that this method cannot be used for thrust determination.

  3. Experimental Study on Surface Dielectric Barrier Discharge Plasma Actuator with Different Encapsulated Electrode Widths for Airflow Control at Atmospheric Pressure

    Science.gov (United States)

    Qi, Xiaohua; Yang, Liang; Yan, Huijie; Jin, Ying; Hua, Yue; Ren, Chunsheng

    2016-10-01

    The surface dielectric barrier discharge (SDBD) plasma actuator has shown great promise as an aerodynamic flow control device. In this paper, the encapsulated electrode width of a SDBD actuator is changed to study the airflow acceleration behavior. The effects of encapsulated electrode width on the actuator performance are experimentally investigated by measuring the dielectric layer surface potential, time-averaged ionic wind velocity and thrust force. Experimental results show that the airflow velocity and thrust force increase with the encapsulated electrode width. The results can be attributed to the distinct plasma distribution at different encapsulated electrode widths. supported by National Natural Science Foundation of China (No. 11175037), National Natural Science Foundation for Young Scientists of China (No. 11305017) and Special Fund for Theoretical Physics (No. 11247239)

  4. Effects of N2O and O2 addition to nitrogen Townsend dielectric barrier discharges at atmospheric pressure on the absolute ground-state atomic nitrogen density

    KAUST Repository

    Es-sebbar, Et-touhami

    2012-11-27

    Absolute ground-state density of nitrogen atoms N (2p3 4S3/2) in non-equilibrium Townsend dielectric barrier discharges (TDBDs) at atmospheric pressure sustained in N2/N2O and N2/O2 gas mixtures has been measured using Two-photon absorption laser-induced fluorescence (TALIF) spectroscopy. The quantitative measurements have been obtained by TALIF calibration using krypton as a reference gas. We previously reported that the maximum of N (2p3 4S3/2) atom density is around 3 × 1014 cm-3 in pure nitrogen TDBD, and that this maximum depends strongly on the mean energy dissipated in the gas. In the two gas mixtures studied here, results show that the absolute N (2p3 4S3/2) density is strongly affected by the N2O and O2 addition. Indeed, the density still increases exponentially with the energy dissipated in the gas but an increase in N2O and O2 amounts (a few hundreds of ppm) leads to a decrease in nitrogen atom density. No discrepancy in the order of magnitude of N (2p3 4S3/2) density is observed when comparing results obtained in N2/N2O and N2/O2 mixtures. Compared with pure nitrogen, for an energy of ∼90 mJ cm-3, the maximum of N (2p3 4S3/2) density drops by a factor of 3 when 100 ppm of N2O and O2 are added and it reduces by a factor of 5 for 200 ppm, to reach values close to our TALIF detection sensitivity for 400 ppm (1 × 1013 cm -3 at atmospheric pressure). © 2013 IOP Publishing Ltd.

  5. Liquid Sampling-Atmospheric Pressure Glow Discharge (LS-APGD) Ionization Source for Elemental Mass Spectrometry: Preliminary Parametric Evaluation and Figures of Merit

    Energy Technology Data Exchange (ETDEWEB)

    Quarles, C. Derrick; Carado, Anthony J.; Barinaga, Charles J.; Koppenaal, David W.; Marcus, R. Kenneth

    2012-01-01

    A new, low power ionization source for the elemental analysis of aqueous solutions has recently been described. The liquid sampling-atmospheric pressure glow discharge (LS-APGD) source operates at relatively low currents (<20 mA) and solution flow rates (<50 μL min-1), yielding a relatively simple alternative for atomic mass spectrometry applications. The LS-APGD has been interfaced to what is otherwise an organic, LC-MS mass analyzer, the Thermo Scientific Exactive Orbitrap without any modifications; other than removing the electrospray ionization (ESI) source supplied with that instrument. A glow discharge is initiated between the surface of the test solution exiting a glass capillary and a metallic counter electrode mounted at a 90° angle and separated by a distance of ~5 mm. As with any plasma-based ionization source, there are key discharge operation and ion sampling parameters that affect the intensity and composition of the derived mass spectra; including signal-to-background ratios. We describe here a preliminary parametric evaluation of the roles of discharge current, solution flow rate, argon sheath gas flow rate, and ion sampling distance as they apply on this mass analyzer system. A cursive evaluation of potential matrix effects due to the presence of easily ionized elements (EIEs) indicate that sodium concentrations of up to 500 μg mL-1 generally cause suppressions of less than 50%, dependant upon the analyte species. Based on the results of this series of studies, preliminary limits of detection (LOD) have been established through the generation of calibration functions. Whilst solution-based concentrations LOD levels of 0.02 – 2 μg mL-1 3 are not impressive on the surface, the fact that they are determined via discrete 5 μL injections leads to mass-based detection limits at picogram to singlenanogram levels. The overhead costs associated with source operation (10 W d.c. power, solution flow rates of <50 μL min-1, and gas flow rates <10 mL min

  6. The effect of O2 in a humid O2/N2/NOx gas mixture on NOx and N2O remediation by an atmospheric pressure dielectric barrier discharge

    DEFF Research Database (Denmark)

    Teodoru, Steluta; Kusano, Yukihiro; Bogaerts, Annemie

    2012-01-01

    A numerical model for NxOy remediation in humid air plasma produced with a dielectric barrier discharge at atmospheric pressure is presented. Special emphasis is given to NO2 and N2O reduction with the decrease of O2 content in the feedstock gas. A detailed reaction mechanism including electronic...

  7. Ozone kinetics in low-pressure discharges

    Science.gov (United States)

    Guerra, Vasco; Marinov, Daniil; Guaitella, Olivier; Rousseau, Antoine

    2012-10-01

    Ozone kinetics is quite well established at atmospheric pressure, due to the importance of ozone in atmospheric chemistry and to the development of industrial ozone reactors. However, as the pressure is decreased and the dominant three-body reactions lose importance, the main mechanisms involved in the creation and destruction of ozone are still surrounded by important uncertainties. In this work we develop a self-consistent model for a pulsed discharge and its afterglow operating in a Pyrex reactor with inner radius 1 cm, at pressures in the range 1-5 Torr and discharge currents of 40-120 mA. The model couples the electron Boltzmann equation with a system of equations for the time evolution of the heavy particles. The calculations are compared with time-dependent measurements of ozone and atomic oxygen. Parametric studies are performed in order to clarify the role of vibrationally excited ozone in the overall kinetics and to establish the conditions where ozone production on the surface may become important. It is shown that vibrationally excited ozone does play a significant role, by increasing the time constants of ozone formation. Moreover, an upper limit for the ozone formation at the wall in these conditions is set at 10(-4).

  8. Antitumorigenic effect of atmospheric-pressure dielectric barrier discharge on human colorectal cancer cells via regulation of Sp1 transcription factor

    Science.gov (United States)

    Han, Duksun; Cho, Jin Hyoung; Lee, Ra Ham; Bang, Woong; Park, Kyungho; Kim, Minseok S.; Shim, Jung-Hyun; Chae, Jung-Il; Moon, Se Youn

    2017-02-01

    Human colorectal cancer cell lines (HT29 and HCT116) were exposed to dielectric barrier discharge (DBD) plasma at atmospheric pressure to investigate the anticancer capacity of the plasma. The dose- and time-dependent effects of DBDP on cell viability, regulation of transcription factor Sp1, cell-cycle analysis, and colony formation were investigated by means of MTS assay, DAPI staining, propidium iodide staining, annexin V–FITC staining, Western blot analysis, RT-PCR analysis, fluorescence microscopy, and anchorage-independent cell transformation assay. By increasing the duration of plasma dose times, significant reductions in the levels of both Sp1 protein and Sp1 mRNA were observed in both cell lines. Also, expression of negative regulators related to the cell cycle (such as p53, p21, and p27) was increased and of the positive regulator cyclin D1 was decreased, indicating that the plasma treatment led to apoptosis and cell-cycle arrest. In addition, the sizes and quantities of colony formation were significantly suppressed even though two cancer promoters, such as TPA and epidermal growth factor, accompanied the plasma treatment. Thus, plasma treatment inhibited cell viability and colony formation by suppressing Sp1, which induced apoptosis and cell-cycle arrest in these two human colorectal cancer cell lines.

  9. Effects of H3O+, OH-, \\text{O}_{2}^{-} , \\text{NO}_{\\text{x}}^{-} and NO x for Escherichia coli inactivation in atmospheric pressure DC corona discharges

    Science.gov (United States)

    Sekimoto, Kanako; Gonda, Rena; Takayama, Mitsuo

    2015-08-01

    The effects of ionic and neutral species such as H3O+, OH-, \\text{O}2- , \\text{NO}x- (x = 2, 3), and NO x on Escherichia coli (E. coli) inactivation in gas and liquid phases was investigated using atmospheric pressure DC corona discharges with point-to-plane electrodes. The above chemical species as well as OH and O3 were selectively irradiated onto E. coli suspensions on agar plates using a needle angle of 45° with respect to the plates, airflow, and a grid plate. Irradiation with the positive ion H3O+ did not inactivate E. coli, while the negative ions OH-/\\text{O}2- resulted in bactericidal inactivation, in both gas and liquid phases. In contrast, the negative ions \\text{NO}x- and neutral species NO x in the gas phase had quite strong bactericidal effects on E. coli compared to those species in the liquid phase. These results suggest that liquid-phase HNO3, formed primarily via the reaction of gas-phase \\text{NO}x- and NO x with H2O in agar, has only a weak inactivation effect on E. coli. Furthermore, using naphthylethylenediamine spectrophotometry, the threshold amount of gas-phase \\text{NO}x- and NO x for E. coli inactivation was determined to be  ≈1.3   ×   10-9 mol mm-1.

  10. Surface treatment of polypropylene (PP) film by 50 Hz dielectric barrier discharge produced in air and argon/air mixture at atmospheric pressure

    Energy Technology Data Exchange (ETDEWEB)

    Joshi, Ujjwal Man, E-mail: umjoshi@gmail.com; Subedi, Deepak Prasad, E-mail: deepaksubedi2001@yahoo.com [Department of Natural Sciences (Physics), School of Science, Kathmandu University P. O. Box No. 6250, Dhulikhel, Kathmandu, Nepal (India)

    2015-07-31

    Thin films of polypropylene (PP) are treated for improving hydrophilicity using non-thermal plasma generated by 50 Hz line frequency dielectric barrier discharge produced in air and argon/air mixture at atmospheric pressure. PP samples before and after the treatments are studied using contact angle measurements, surface free energy calculations and scanning electron microscopy (SEM). Distilled water (H{sub 2}O), glycerol (C{sub 3}H{sub 8}O{sub 3}) and diiodomethane (CH{sub 2}I{sub 2}) are used as test liquids. The contact angle measurements between test liquids and PP samples are used to determine total surface free energy using sessile drop technique. PP films show a remarkable increase in surface free energy after plasma treatment. SEM analysis of the plasma-treated PP films shows that plasma treatment introduces greater roughness on the surface leading to the increased surface free energy. Furthermore, it is found that introducing a small quantity of argon can enhance the surface treatment remarkably.

  11. 大气压氦气介质阻挡斑图放电与辉光放电的转换条件及其演化过程%Conversion and Evolution Process of Patterned Discharges to Glow Discharges in Atmospheric-pressure Helium Dielectric Barrier Discharge

    Institute of Scientific and Technical Information of China (English)

    郝艳摔; 郑彬; 刘耀阁

    2012-01-01

    discharge generated, a single-pulse glow discharge could be achieved when the applied voltage was adjusted to a lower voltage, a two-pulse discharge appeared at a higher voltage. At the same time, the radial size of each pattern became smaller, however, the number of the discharge channels increased. It is found that, with an increasing applied voltage, the discharge becomes uniform gradually and turns into multi-pulse glow discharges. The discharge current can not be used to diagnose the discharge mode. The conversion of a spatio-temporal patterned discharge to a glow barrier discharge with the increasing applied voltage is a progress that the discharge changed from a partial APGD {atmospheric pressure glow discharze) to a whole APGD.

  12. Discharge Characteristics of Atmosphere Pressure Plasma Jet in Ar%大气压氩等离子体射流的放电特性

    Institute of Scientific and Technical Information of China (English)

    方志; 刘源; 蔡玲玲

    2012-01-01

    为了深入地理解大气压等离子体射流放电机理和优化其放电效率,通过对大气压氩等离子体射流的电压电流波形和Lissajous图形等电气特性的测量及发射光谱和发光图像等光学特性诊断,研究了外电极距石英玻璃管口不同距离时,氩等离子体射流放电的放电特性和演变规律。计算放电功率、传输电荷量、电子激发温度、分子振动温度和分子转动温度等主要放电参量后,研究了它们随外加电压增加的变化趋势,并结合放电机理对所得实验结果进行了分析。结果表明,氩等离子体射流主要产生的粒子有OH、Nz、Ar和少量的O,随着外电极位置的不同,气体温度在317-395K之间变化,为典型的低温等离子体;外电极位置影响放电模式和放电起始电压,在氩射流阶段,电子激发温度在不同外电极位置条件下相差不大。当外电极距离管口40mm时,外加电压幅值达8kV时,放电功率和传输电荷最大,放电效果和发光强度也最强,由Penning效应产生的OH谱线强度也最强,因此,用于聚合物材料表面改性等应用时,可以采用此运行参数,以达到更好处理效果。%In order to study discharge mechanisms of atmosphere pressure plasma jet (APPJ] in Ar deeply and to optimize its discharge efficiency, the effects of outer electrode position on discharge characteristics and evolutions of APPJ in Ar were studied by means of electrical measurements of voltage and current waveforms and Lissajous figures, and by diagnosing optical properties on optical emission spectra and light-emission pictures. The main discharge parameters such as discharge power, transported charges, electronic excitation temperature, molecular vibrational temperature and molecular rotational temperature were calculated, the changing tendencies of them with applied voltage were studied, and the experimental results were explained by

  13. Preliminary Figures of Merit for Isotope Ratio Measurements: The Liquid Sampling-Atmospheric Pressure Glow Discharge Microplasma Ionization Source Coupled to an Orbitrap Mass Analyzer.

    Science.gov (United States)

    Hoegg, Edward D; Barinaga, Charles J; Hager, George J; Hart, Garret L; Koppenaal, David W; Marcus, R Kenneth

    2016-08-01

    In order to meet a growing need for fieldable mass spectrometer systems for precise elemental and isotopic analyses, the liquid sampling-atmospheric pressure glow discharge (LS-APGD) has a number of very promising characteristics. One key set of attributes that await validation deals with the performance characteristics relative to isotope ratio precision and accuracy. Owing to its availability and prior experience with this research team, the initial evaluation of isotope ratio (IR) performance was performed on a Thermo Scientific Exactive Orbitrap instrument. While the mass accuracy and resolution performance for Orbitrap analyzers are well-documented, no detailed evaluations of the IR performance have been published. Efforts described here involve two variables: the inherent IR precision and accuracy delivered by the LS-APGD microplasma and the inherent IR measurement qualities of Orbitrap analyzers. Important to the IR performance, the various operating parameters of the Orbitrap sampling interface, high-energy collisional dissociation (HCD) stage, and ion injection/data acquisition have been evaluated. The IR performance for a range of other elements, including natural, depleted, and enriched uranium isotopes was determined. In all cases, the precision and accuracy are degraded when measuring low abundance (<0.1% isotope fractions). In the best case, IR precision on the order of 0.1% RSD can be achieved, with values of 1%-3% RSD observed for low-abundance species. The results suggest that the LS-APGD is a promising candidate for field deployable MS analysis and that the high resolving powers of the Orbitrap may be complemented with a here-to-fore unknown capacity to deliver high-precision IRs. Graphical Abstract ᅟ.

  14. Preliminary Figures of Merit for Isotope Ratio Measurements: The Liquid Sampling-Atmospheric Pressure Glow Discharge Microplasma Ionization Source Coupled to an Orbitrap Mass Analyzer

    Energy Technology Data Exchange (ETDEWEB)

    Hoegg, Edward D.; Barinaga, Charles J.; Hager, George J.; Hart, Garret L.; Koppenaal, David W.; Marcus, R. Kenneth

    2016-03-01

    ABSTRACT In order to meet a growing need for fieldable mass spectrometer systems for precise elemental and isotopic analyses, the liquid sampling-atmospheric pressure glow discharge (LS-APGD) has a number of very promising characteristics. One key set of attributes that await validation deals with the performance characteristics relative to isotope ratio precision and accuracy. Due to its availability and prior experience with this research team, the initial evaluation of isotope ratio (IR) performance was performed on a Thermo Scientific Exactive Orbitrap instrument. While the mass accuracy and resolution performance for orbitrap analyzers are very well documented, no detailed evaluations of the IR performance have been published. Efforts described here involve two variables: the inherent IR precision and accuracy delivered by the LSAPGD microplasma and the inherent IR measurement qualities of orbitrap analyzers. Important to the IR performance, the various operating parameters of the orbitrap sampling interface, HCD dissociation stage, and ion injection/data acquisition have been evaluated. The IR performance for a range of other elements, including natural, depleted, and enriched uranium isotopes was determined. In all cases the precision and accuracy are degraded when measuring low abundance (<0.1% isotope fractions). In the best case, IR precision on the order of 0.1 %RSD can be achieved, with values of 1-3 %RSD observed for low-abundance species. The results suggest that the LSAPGD is a very good candidate for field deployable MS analysis and that the high resolving powers of the orbitrap may be complemented with a here-to-fore unknown capacity to deliver high-precision isotope ratios.

  15. Preliminary Figures of Merit for Isotope Ratio Measurements: The Liquid Sampling-Atmospheric Pressure Glow Discharge Microplasma Ionization Source Coupled to an Orbitrap Mass Analyzer

    Science.gov (United States)

    Hoegg, Edward D.; Barinaga, Charles J.; Hager, George J.; Hart, Garret L.; Koppenaal, David W.; Marcus, R. Kenneth

    2016-08-01

    In order to meet a growing need for fieldable mass spectrometer systems for precise elemental and isotopic analyses, the liquid sampling-atmospheric pressure glow discharge (LS-APGD) has a number of very promising characteristics. One key set of attributes that await validation deals with the performance characteristics relative to isotope ratio precision and accuracy. Owing to its availability and prior experience with this research team, the initial evaluation of isotope ratio (IR) performance was performed on a Thermo Scientific Exactive Orbitrap instrument. While the mass accuracy and resolution performance for Orbitrap analyzers are well-documented, no detailed evaluations of the IR performance have been published. Efforts described here involve two variables: the inherent IR precision and accuracy delivered by the LS-APGD microplasma and the inherent IR measurement qualities of Orbitrap analyzers. Important to the IR performance, the various operating parameters of the Orbitrap sampling interface, high-energy collisional dissociation (HCD) stage, and ion injection/data acquisition have been evaluated. The IR performance for a range of other elements, including natural, depleted, and enriched uranium isotopes was determined. In all cases, the precision and accuracy are degraded when measuring low abundance (<0.1% isotope fractions). In the best case, IR precision on the order of 0.1% RSD can be achieved, with values of 1%-3% RSD observed for low-abundance species. The results suggest that the LS-APGD is a promising candidate for field deployable MS analysis and that the high resolving powers of the Orbitrap may be complemented with a here-to-fore unknown capacity to deliver high-precision IRs.

  16. Preliminary Assessment of Potential for Metal-Ligand Speciation in Aqueous Solution via the Liquid Sampling-Atmospheric Pressure Glow Discharge (LS-APGD) Ionization Source: Uranyl Acetate.

    Science.gov (United States)

    Zhang, Lynn X; Manard, Benjamin T; Powell, Brian A; Marcus, R Kenneth

    2015-07-21

    The determination of metals, including the generation of metal-ligand speciation information, is essential across a myriad of biochemical, environmental, and industrial systems. Metal speciation is generally affected by the combination of some form of chromatographic separation (reflective of the metal-ligand chemistry) with element-specific detection for the quantification of the metal composing the chromatographic eluent. Thus, the identity of the metal-ligand is assigned by inference. Presented here, the liquid sampling-atmospheric pressure glow discharge (LS-APGD) is assessed as an ionization source for metal speciation, with the uranyl ion-acetate system used as a test system. Molecular mass spectra can be obtained from the same source by simple modification of the sustaining electrolyte solution. Specifically, chemical information pertaining to the degree of acetate complexation of uranyl ion (UO2(2+)) is assessed as a function of pH in the spectral abundance of three metallic species: inorganic (nonligated) uranyl, UO2Ac(H2O)n(MeOH)m(+), and UO2Ac2(H2O)n(MeOH)(m)H(+) (n = 1, 2, 3, ...; m = 1, 2, 3, ...). The product mass spectra are different from what are obtained from electrospray ionization sources that have been applied to this system. The resulting relationships between the speciation and pH values have been compared to calculated concentrations of the corresponding uranyl species: UO2(2+), UO2Ac(+), UO2Ac2. The capacity for the LS-APGD to affect both atomic mass spectra and structurally significant spectra for organometallic complexes is a unique and potentially powerful combination.

  17. Measurement of ion density in an atmospheric pressure argon with pin-to-plate dielectric barrier discharge by resonance of plasma radiation

    Energy Technology Data Exchange (ETDEWEB)

    Qi, Bing, E-mail: qibing@szu.edu.cn; Pan, Lizhu; Zhou, Qiujiao; Huang, Jianjun; Liu, Ying [Applied Low Temperature Plasma Laboratory, School of Physics, Shenzhen University, Shenzhen 518060 (China)

    2014-12-15

    The measurements of the ion densities in the atmospheric AC barrier corona argon discharge are carried out by receiving and analyzing the frequencies of the electromagnetic radiation emitted from the plasma. An auxiliary excitation source composed of a pin-to-pin discharge system is introduced to excite the oscillations of the main discharge. To analyze the resonance mechanism, a complemented model based on a one-dimensional description of forced vibrations is given. Calculations indicate that Ar{sub 2}{sup +} is the dominant ion (∼89% in number density). By analyzing resonance frequencies, the ion densities of Ar{sub 2}{sup +} are in the order of 10{sup 19}∼10{sup 20}m{sup −3} and increase slowly as the applied voltage increases.

  18. Measurement of ion density in an atmospheric pressure argon with pin-to-plate dielectric barrier discharge by resonance of plasma radiation

    Science.gov (United States)

    Qi, Bing; Pan, Lizhu; Zhou, Qiujiao; Huang, Jianjun; Liu, Ying

    2014-12-01

    The measurements of the ion densities in the atmospheric AC barrier corona argon discharge are carried out by receiving and analyzing the frequencies of the electromagnetic radiation emitted from the plasma. An auxiliary excitation source composed of a pin-to-pin discharge system is introduced to excite the oscillations of the main discharge. To analyze the resonance mechanism, a complemented model based on a one-dimensional description of forced vibrations is given. Calculations indicate that Ar2 + is the dominant ion ( ˜ 89 % in number density). By analyzing resonance frequencies, the ion densities of Ar2 + are in the order of 10 19 ˜ 10 20 m - 3 and increase slowly as the applied voltage increases.

  19. Modeling High Pressure Micro Hollow Cathode Discharges

    Science.gov (United States)

    2007-11-02

    cathode discharge excimer lamps , Phys. Plasmas 7, 286 (2000). [3] RH Stark and KH Schoenbach, Direct high pressure glow discharges, J. Appl. Phys...temperature profiles in argon glow discharges, J. Appl. Phys. 88, 2234 (2000) [8] M. Moselhy, W. Shi, R. Stark, A flat glow discharge excimer radiation...MHCD acts as a plasma cathode for a third electrode (anode). Some experimental results in this geometry are available for argon and for air from the

  20. A change in the electro-physical properties of narrow-band CdHgTe solid solutions acted upon by a volume discharge induced by an avalanche electron beam in the air at atmospheric pressure

    Science.gov (United States)

    Voitsekhovskii, A. V.; Grigor'ev, D. V.; Korotaev, A. G.; Kokhanenko, A. P.; Tarasenko, V. F.; Shulepov, M. A.

    2012-03-01

    The effect of a nanosecond volume discharge forming in an inhomogeneous electrical field at atmospheric pressure on the CdHgTe (MCT) epitaxial films of the p-type conduction with the hole concentration 2·1016 cm3 and mobility 500 cm2·V-1·s-1 is studied. The measurement of the electrophysical parameters of the MCT specimens upon irradiation shows that a layer exhibiting the n-type conduction is formed in the near-surface region of the epitaxial films. After 600 pulses and more, the thickness and the parameters of the layer are such that the measured field dependence of the Hall coefficient corresponds to the material of the n-type conduction. Analysis of the preliminary results reveals that the foregoing nanosecond volume discharge in the air at atmospheric pressure is promising for modification of electro-physical MCT properties.

  1. Effect of Pulse Nanosecond Volume Discharge in Air at Atmospheric Pressure on Electrical Properties of Mis Structures Based on p-HgCdTe Grown by Molecular Beam Epitaxy

    Science.gov (United States)

    Voitsekhovskii, A. V.; Nesmelov, S. N.; Dzyadukh, S. M.; Grigor'ev, D. V.; Tarasenko, V. F.; Shulepov, M. A.

    2015-11-01

    The effect of the pulse nanosecond volume discharge in air at atmospheric pressure on the admittance of MIS structures based on MBE graded-gap p-Hg0.78Cd0.22Te is studied in a wide range of frequencies and temperatures. It is shown that the impact of the discharge leads to significant changes in electrical characteristics of MIS structures (the density of positive fixed charge increases), to the changes in the nature of the hysteresis of capacitance-voltage characteristics, and to an increase in the density of surface states. A possible reason for the changes in the characteristics of MIS structures after exposure to the discharge is substantial restructuring of the defect-impurity system of the semiconductor near the interface.

  2. Atmospheric Pressure Indicator.

    Science.gov (United States)

    Salzsieder, John C.

    1995-01-01

    Discusses observable phenomena related to air pressure. Describes a simple, unobtrusive, semiquantitative device to monitor the changes in air pressure that are associated with altitude, using a soft-drink bottle and a balloon. (JRH)

  3. Atmospheric Pressure Plasma Process And Applications

    Energy Technology Data Exchange (ETDEWEB)

    Peter C. Kong; Myrtle

    2006-09-01

    This paper provides a general discussion of atmospheric-pressure plasma generation, processes, and applications. There are two distinct categories of atmospheric-pressure plasmas: thermal and nonthermal. Thermal atmospheric-pressure plasmas include those produced in high intensity arcs, plasma torches, or in high intensity, high frequency discharges. Although nonthermal plasmas are at room temperatures, they are extremely effective in producing activated species, e.g., free radicals and excited state atoms. Thus, both thermal and nonthermal atmosphericpressure plasmas are finding applications in a wide variety of industrial processes, e.g. waste destruction, material recovery, extractive metallurgy, powder synthesis, and energy conversion. A brief discussion of recent plasma technology research and development activities at the Idaho National Laboratory is included.

  4. Comparison of Cocaine Detections in Corona Discharge Ionization-Ion Mobility Spectrometry and in Atmospheric Pressure Chemical Ionization-Mass Spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Sung Seen; Kim, Yun Ki; Kim, Ok Bae [Sejong University, Seoul (Korea, Republic of); An, Seung Geon; Shin, Myung Won; Maeng, Seug Jin; Choi, Gyu Seop [Wooju Communication and Technology Co., Seoul (Korea, Republic of)

    2010-08-15

    In this study, we determined the detection limit and reproducibility of the new IMS equipped with corona discharge ionization source using cocaine. The sample was injected with liquid solution to compare the results of APCI-MS. Ion mobility spectrometry (IMS) was a technique originally applied for the detection of trace compounds. IMS has been widely used to detect chemical warfare agents, explosives, and illegal drugs since it combines both high sensitivity (detection limits down to the ng/L range to pg/L range, ppb range and ppt range) and relatively low technical expenditure with high-speed data acquisition. The time required to acquire a single spectrum is in the range of several tens ms. The working principle is based on the drift of ions at ambient pressure under the influence of an external electric field.

  5. 阻抗匹配对大气压氮气介质阻挡放电的影响%Impact of Impedance Matching on Discharge of Dielectric Barrier of Atmospheric Pressure Nitrogen

    Institute of Scientific and Technical Information of China (English)

    张燕; 尚中选; 吕印定; 顾彪

    2013-01-01

    The fairly homogeneous plasma was generated by dielectric barrier discharge(BDB)in the 3 mm gap filled with atmospheric pressure nitrogen, and regulated with the impedance matching network. The impacts of the discharge conditions on plasma characteristics were evaluated.The discharge was found to be Townsend mode. The results show that at a given frequency and gas-gap width, as the amplitude of driving voltage increased, the discharge current and discharge power increased at different rates,a fairly slow increase,followed by a linear increase after the discharge area covered the entire electrode. Besides, an increase of frequency resulted in an observable resonance of the discharge current and power. However, the experimentally optimized driving frequency was found to disagree with the simulated result reported by Chen et al.%在介质阻挡放电装置中,使用阻抗匹配网络后,当气体间隙为3mm时,在大气压氮气中获得了均匀介质阻挡放电等离子体,放电模式为汤森放电.在其他放电参数不变的情况下,放电电流和放电功率随着外加电压峰峰值的增大先非常缓慢增加,然后当放电面积铺满整个电极后呈线性增加.而放电电流和放电功率随驱动频率的增加呈现出非常明显的谐振现象,实验所得到的最佳匹配频率和Chen给出的理论计算结果存在差异.

  6. Experimental investigation on the characteristics of dielectric barrier discharge with a large gap width at atmospheric pressure%大气压下较大气隙宽度介质阻挡放电的实验研究

    Institute of Scientific and Technical Information of China (English)

    李雪辰; 刘润甫; 贾鹏英; 赵欢欢; 常媛媛

    2013-01-01

    A dielectric barrier discharge with a fairly large gap width is realized in atmospheric pressure argon because the critical voltage value for gas gap breakdown is sharply lowered through using a wedged gas gap. The discharge behavior is investigated experimentally through analyzing images taken with exposure time of several milliseconds. Results indicate that a stripe pattern with a homogeneous corona around can be observed under a lower voltage, and the discharge turns quite homogeneous at a higher voltage. It has been found that the micro-discharges tend to be generated at the region with small gap width, and then move to the region with large gap width along the flowing gas. Therefore, dielectric barrier discharge with a fairly large gap width can be obtained at a rather lowered voltage. Based on the visualization of the discharge with exposure time of several microseconds, it has been found that micro-discharge filament consists of the volumetric discharge between the two electrodes and the stochastic surface discharge on the dielectric for the filamentary discharge. The stripe on the image taken with exposure time of several milliseconds results from the moving of the volumetric discharge along the gas flow, and the homogeneous corona is a superimposition of the surface discharge at different half cycles. These results are of great importance for industrial applications of the atmospheric pressure uniform discharge.%利用楔形气隙极大地降低了气隙的击穿电压,从而在流动氩气中实现了大气压下较大气隙宽度的介质阻挡放电。通过毫秒量级曝光时间拍照,对放电的动力学行为进行了研究。结果发现:外加电压较低时放电为条纹斑图,且在条纹的周围伴有均匀的晕;随外加电压升高,放电会过渡到均匀模式。研究表明微放电总是产生于窄气隙区域,然后沿着气流向大间隙方向定向移动,因此在较低电压下实现了大气隙宽度的介质

  7. Atmospheric Pressure During Landing

    Science.gov (United States)

    1997-01-01

    This figure shows the variation with time of pressure (dots) measured by the Pathfinder MET instrument during the landing period shown in image PIA00797. The two diamonds indicate the times of bridal cutting and 1st impact. The overall trend in the data is of pressure increasing with time. This is almost certainly due to the lander rolling downhill by roughly 10 m. The spacing of the horizontal dotted lines indicates the pressure change expected from 10 m changes in altitude. Bounces may also be visible in the data.

  8. Temporal modulation of plasma species in atmospheric dielectric barrier discharges

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Aijun; Wang, Xiaohua, E-mail: xhw@mail.xjtu.edu.cn, E-mail: mzrong@mail.xjtu.edu.cn; Liu, Dingxin; Rong, Mingzhe, E-mail: xhw@mail.xjtu.edu.cn, E-mail: mzrong@mail.xjtu.edu.cn [Centre for Plasma Biomedicine, State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China); Kong, Michael G. [Centre for Plasma Biomedicine, State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China); Frank Reidy Research Center for Bioelectrics, Department of Electrical and Computer Engineering, Old Dominion University, Virginia 23508 (United States); Department of Electrical and Computer Engineering, Old Dominion University, Norfolk, Virginia 23529 (United States)

    2014-07-15

    The atmospheric pressure dielectric barrier discharge in helium is a pulsed discharge in nature and the moment of maximum species densities is almost consistent with peak discharge current density. In this paper, a one-dimensional fluid model is used to investigate the temporal structure of plasma species in an atmospheric He-N{sub 2} dielectric barrier discharge (DBD). It is demonstrated that there exist microsecond delays of the moments of the maximum electron and ion densities from the peak of discharge current density. These time delays are caused by a competition between the electron impact and Penning ionizations, modulated by the N{sub 2} level in the plasma-forming gas. Besides, significant electron wall losses lead to the DBD being more positively charged and, with a distinct temporal separation in the peak electron and cation densities, the plasma is characterized with repetitive bursts of net positive charges. The temporal details of ionic and reactive plasma species may provide a new idea for some biological processes.

  9. Characterization of a dielectric barrier discharge in controlled atmosphere

    Science.gov (United States)

    Kogelheide, Friederike; Offerhaus, Björn; Bibinov, Nikita; Bracht, Vera; Smith, Ryan; Lackmann, Jan-Wilm; Awakowicz, Peter; Stapelmann, Katharina; Bimap Team; Aept Team

    2016-09-01

    Non-thermal atmospheric-pressure plasmas are advantageous for various biomedical applications as they make a contact- and painless therapy possible. Due to the potential medical relevance of such plasma sources further understanding of the chemical and physical impact on biological tissue regarding the efficacy and health-promoting effect is necessary. The knowledge of properties and effects offers the possibility to configure plasmas free of risk for humans. Therefore, tailoring the discharge chemistry in regard to resulting oxidative and nitrosative effects on biological tissue by adjusting different parameters is of growing interest. In order to ensure stable conditions for the characterization of the discharge, the used dielectric barrier discharge was mounted in a vessel. Absolutely calibrated optical emission spectroscopy was carried out to analyze the electron density and the reduced electric field. The rather oxygen-based discharge was tuned towards a more nitrogen-based discharge by adjusting several parameters as reactive nitrogen species are known to promote wound healing. Furthermore, the impact of an ozone-free discharge has to be studied. This work was funded by the German Research Foundation (DFG) with the packet grant PAK 816 `Plasma Cell Interaction in Dermatology'.

  10. Optical and electrical characteristics of a single surface DBD micro-discharge produced in atmospheric-pressure nitrogen and synthetic air

    Science.gov (United States)

    Šimek, M.; Prukner, V.; Schmidt, J.

    2011-05-01

    Basic opto-electrical characteristics of a single micro-discharge generated in a surface DBD reactor with a coplanar electrode arrangement were studied with nanosecond time resolution. The discharge electrode geometry based on machinable glass-ceramic was optimized in order to get a system free of the circulating dielectric liquids that are frequently used to insulate and cool metallic electrodes. The build-up and decay of UV-vis-NIR emission by a single micro-discharge unaffected by concurrent or preceding discharge events was inspected during the first 10 µs of the micro-discharge evolution in nitrogen and in synthetic air. Obtained emission waveforms show a great similarity between the surface and volume streamers. The streamer volume-averaged N2(A) concentrations of ~8 × 1014 cm-3 were estimated at t = 1 µs decay time and concentrations of ~(2-4) × 1015 cm-3 were estimated during the streamer propagation phase in nitrogen.

  11. Diagnosis of the ion density in two discharge modes generated in atmospheric pressure argon with pin-to-plate dielectric barrier geometry

    Energy Technology Data Exchange (ETDEWEB)

    Qi Bing; Huang Jianjun; Qiu Yunming; Liu Ying; Liu Lijun [Applied Low Temperature Plasma Laboratory, College of Physics Science and Technology, Shenzhen University, Shenzhen 518060 (China)

    2011-08-15

    In this study, the ion densities of an ac dielectric barrier discharge (DBD) (that is, a pin-to-plate DBD) as a function of the applied frequency in argon have been studied by means of the plasma radiation. The pin-to-plate DBD shows the characteristic of radiation oscillations with a low-frequency wave hidden in a high-frequency wave to form a mosaic structure, which reveals the coexistence of two discharge modes in the ac barrier discharge, i.e., the streamer mode and the corona mode. According to the oscillation frequencies, the ion densities are calculated. The results show that the ion density in streamer discharge is higher than that in corona discharge for about 1-2 magnitude orders.

  12. Characteristics of RF Cold Plasma at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    QIU Liang; MENG Yuedong; SHU Xingsheng

    2007-01-01

    The characteristics of a stable discharge at atmospheric pressure is investigated.The plasma source consisted of two closely spaced parallel-plated perforated electrodes,driven by a radio frequency power to generate a uniform cold plasma in Helium at atmospheric pressure.Both alpha and gamma modes were clearly observed.The hollow cathode effects were found in the discharge.The influence of the dielectric barrier on the discharge was also investigated by utilizing a surface-anodized aluminium electrode as the anode.

  13. Measurement of OH (X2Σ) in immediate vicinity of dielectric surface under pulsed dielectric barrier discharge at atmospheric pressure using two geometries of laser-induced fluorescence

    Science.gov (United States)

    Teramoto, Yoshiyuki; Kim, Hyun-Ha; Ogata, Atsushi; Negishi, Nobuaki

    2014-04-01

    The behavior of the ground state OH radical was studied in humid air using pulsed surface dielectric barrier discharge. The validity of OH measurement in immediate vicinity of the dielectric surface was discussed using two geometries of laser-induced fluorescence (LIF) measurement, and surface distribution and temporal profiles of OH were examined. A comparison of parallel- and perpendicular-LIF techniques for OH measurement revealed that OH was mostly produced in a region several tens of μm above the dielectric surface. The surface distribution profile of OH agreed well with that of N2(C), and in both cases, the total production generated by a discharge pulse was proportional to the discharge energy. The OH local density in surface streamer channels was estimated to be 1.3 × 1015 cm-3 according to the decay rate of OH, which was similar to that in corona discharge. Additionally, the local density of OH remained constant regardless of discharge energies. These results indicate that the yield of OH increased with the discharge energy owing to expansion of the surface streamer region, increase in streamer radius or thickness or the number of branches, whereas the local density of OH in the streamer channel remained constant regardless of discharge energy.

  14. RF impedance measurements of DC atmospheric micro-discharges

    CERN Document Server

    Overzet, Lawrence J; Mandra, Monali; Goeckner, Matthew; Dufour, Thierry; Dussart, Remi; Lefaucheux, Philippe

    2016-01-01

    The available diagnostics for atmospheric micro-plasmas remain limited and relatively complex to implement; so we present a radio-frequency technique for diagnosing a key parameter here. The technique allows one to estimate the dependencies of the electron density by measuring the RF-impedance of the micro-plasma and analyzing it with an appropriate equivalent circuit. This technique is inexpensive, can be used in real time and gives reasonable results for argon and helium DC micro-plasmas in holes over a wide pressure range. The electron density increases linearly with current in the expected range consistent with normal glow discharge behavior.

  15. Analysis on Lissajous Figures of Dielectric Barrier Glow Discharge in Atmospheric-pressure Helium%大气压下氦气介质阻挡辉光放电过程的Lissajous图形分析

    Institute of Scientific and Technical Information of China (English)

    郝艳捧; 刘耀阁; 郑彬

    2012-01-01

    In order to investigate the variation of equivalent capacitance during dielectric barrier discharge (DBD), single pulse and multi-pulse discharges were obtained using a high-frequency power supply in atmospheric-pressure helium. By measuring applied voltage and loop current, Lissajous figures were calculated and compared with those which were directly measured. The equivalent capacitance of the gas gap and dielectrics during the discharging and cutting-off phases were calculated with the corresponding relationship between the peaks and valleys of current pulse and the points on Lissajous figures. The reasons of variation of the equivalent capacitance were analyzed, and the physical process of discharge was discussed. The results show that the equivalent capacitance can be studied by using calculated Lissajous figures instead of the measured ones. The equivalent capacitance keeps unchanged during the discharge cutting-off stage, but changes with current during the discharging stage and reaches its maximum at the peak point of current pulse. And the process of discharge is mainly affected by the changing rates of applied voltage and space charges.%为研究介质阻挡放电(DBD)过程中等效电容的变化情况,利用高频高压电源,进行了大气压氦气介质阻挡单脉冲和多脉冲辉光放电试验,利用外施电压、回路电流计算得到放电Lissajous图形,并与直接测量的Lissajous图形进行了对比。确定了放电电流波峰和波谷在Lissajous图形上的对应位置,计算了放电截止和放电进行阶段气隙和介质的等效电容,分析了等效电容变化的原因,并且探讨了放电的物理过程。结果表明:计算得到的Lissajous图形与测量所得的Lissajous图形一致;介质等效电容在放电截止阶段保持不变,但在放电进行阶段随电流脉冲变化而变化,并且在电流峰值处最大;放电物理过程主要受到外施电压和介质表面电荷量的变化速率影响。

  16. Atmospheric pressure plasma enhanced spatial ALD of silver

    NARCIS (Netherlands)

    Van Den Bruele, F.J.; Smets, M.; Illiberi, A.; Creyghton, Y.; Buskens, P.; Roozeboom, F.; Poodt, P.

    2014-01-01

    The authors have investigated the growth of thin silver films using a unique combination of atmospheric process elements: spatial atomic layer deposition and an atmospheric pressure surface dielectric barrier discharge plasma source. Silver films were grown on top of Si substrates with good purity a

  17. Formation Mechanism of Atmospheric Pressure Plasma Jet

    CERN Document Server

    Jiang, Nan; Cao, Zexian

    2008-01-01

    Atmospheric pressure plasma jet can protrude some 5.0 cm into air. It holds promise for multivarious innovative applications, but its formation mechanism remains unsettled. We show that the plasma jet is essentially a streamer corona totally independent of, but obscured by, dielectric barrier discharge. Consequently, the jets can be equally successfully generated even with one single bare metal electrode attached to the tube orifice, both downstream and upstream simultaneously, and at a significantly reduced voltage. These results will help understand the underlying physics and facilitate a safer and more flexible implementation of this marvelous plasma source.

  18. 120kV下常压空气纳秒脉冲电晕放电特性%Characteristic of nanosecond-pulsed corona discharge at 120 kV in atmospheric-pressure air

    Institute of Scientific and Technical Information of China (English)

    章程; 邵涛; 许家雨; 马浩; 徐蓉; 严萍

    2012-01-01

    With an excitation of negative repetitive pulses of 15 ns rise time and 30 to 40 ns duration, corona discharge in nanosecond-pulse regime at 120 kV in atmospheric-pressure air is experimentally investigated, and the characteristic of nanosecond-pulsed corona discharge is analyzed by the measurement of electrical discharge parameters, images and X-ray emission. The results show that X-ray emission occurs in nanosecond-pulsed corona discharge, but the intensity is weak. The counts of X rays decrease with the air gap spacing but increase with the pulse repetition frequency. In addition, owing to the fact that the residual particles in the gap enhance the local electric field when the next pulse is applied, separated corona channels are easily obtained at high pulse repetition frequency.%使用上升沿15 ns、脉宽30~40 ns的重复频率纳秒脉冲电源对120 kV下大气压空气中管-板电极结构电晕放电进行了实验研究,通过电压电流测量、放电图像拍摄和X射线探测分析了纳秒脉冲电晕放电特性.结果表明:纳秒脉冲电晕放电中存在X射线辐射,但辐射强度较弱,X射线辐射计数随着气隙距离的增大而减少,随着脉冲重复频率的增大而增多;放电空间的残余电荷加强了下一个脉冲到来时的局部电场,从而导致高重复频率下易于出现分散的电晕通道.

  19. Physics of Atmospheric Electric Discharges in Gases: An Informal Introduction

    CERN Document Server

    Treumann, R A; Parrot, M

    2007-01-01

    A short account of the physics of electrical discharges in gases is given in view of its historical evolution and application to planetary atmospheres. As such it serves as an introduction to the articles on particular aspects of electric discharges contained in this book, in particular in the chapters on lightning and the violent discharges which in the recent two decades have been observed to take place in Earth's upper atmosphere. In addition of briefly reviewing the early history of gas discharge physics we discuss the main parameters affecting violent atmospheric discharges like collision frequency, mean free path and critical electric field strength. Any discharge current in the atmosphere is clearly carried only by electrons. Above the lower bound of the mesosphere the electrons must be considered magnetized with the conductivity becoming a tensor. Moreover, the collisional mean free path in the upper atmosphere becomes relatively large which lowers the critical electric field there and more easily ena...

  20. Characteristics of atmospheric pressure air uniform discharge generated by a plasma needle%大气压等离子体针产生空气均匀放电特性研究

    Institute of Scientific and Technical Information of China (English)

    李雪辰; 袁宁; 贾鹏英; 常媛媛; 嵇亚飞

    2011-01-01

    Cold plasma generated by atmospheric air discharge has wide application prospect in industry because it does not need vacuum equipment and mass production is possible.In this paper,a stable uniform discharge is generated in open air by a plasma needle.Discharge mechanism is investigated by optical method,and plasma parameters are given by the spatially resolved measurement of emission spectrum from the discharge.Results show that the discharges have two modes.One is a corona discharge mode and the other is plasma plume mode.In the stable plasma plume mode,a strong emission area and a weak emission one can be distinguished from each other.The development velocity of the weak emission area is much faster than that of the strong emission area.Furthermore,the electron energy and the plasma density in the weak emission area are also bigger than those in the strong emission area.Therefore,the discharge in the strong emission area is dominated by Townsend mechanism,while that in the weak emission area is dominated by streamer discharge.Gas temperature and vibration temperature are also studied in this paper.The experimental results are of great importance to the industrial applications of atmospheric pressure discharge.%大气压空气放电由于脱离了真空装置,易于实现流水线生产,因而在工业上具有广泛的应用.采用等离子体针装置在空气中产生了稳定的大气压均匀放电.利用光谱法对等离子体的相关参数进行了空间分辨率测量,并通过光学方法对放电机理进行了研究.结果表明,等离子体针产生的放电存在电晕放电和等离子体羽放电两种模式.在稳定的等离子体羽放电模式中,发光分为强光区和弱光区.弱光区放电的发展速度远大于强光区的发展速度,电子能量和电子密度均是弱光区比强光区大.对均匀放电的气体温度和振动温度的研究表明,强光区放电遵循汤生击穿机理而弱光区为流光放电.这些结果对

  1. Characteristics of Nanosecond Pulsed Discharges in Atmospheric Helium Microplasmas

    Science.gov (United States)

    Manish, Jugroot

    2016-10-01

    Microplasmas are very interesting due to their unique properties and achievable regimes maintained at atmospheric pressures. Due to the small scales, numerical modeling could contribute to the understanding of underlying phenomena as it provides access to local parameters—and complements experimental global characteristics. A self-consistent formalism, applied to nanosecond pulsed atmospheric non-equilibrium helium plasmas, reveals that several successive discharges can persist as a result of a combined volume and dielectric surface effects. The valuable insights provided by the spatiotemporal simulation results show the critical importance of coupled gas and plasma dynamics—namely gas heating and electric field reversals. supported by the Natural Sciences and Engineering Research Council of Canada (NSERC) — Discovery Grant (No. 342369)

  2. Observations of different core water cluster ions Y-(H2O)n (Y = O2, HOx, NOx, COx) and magic number in atmospheric pressure negative corona discharge mass spectrometry.

    Science.gov (United States)

    Sekimoto, Kanako; Takayama, Mitsuo

    2011-01-01

    Reliable mass spectrometry data from large water clusters Y(-)(H(2)O)(n) with various negative core ions Y(-) such as O(2)(-), HO(-), HO(2)(-), NO(2)(-), NO(3)(-), NO(3)(-)(HNO(3))(2), CO(3)(-) and HCO(4)(-) have been obtained using atmospheric pressure negative corona discharge mass spectrometry. All the core Y(-) ions observed were ionic species that play a central role in tropospheric ion chemistry. These mass spectra exhibited discontinuities in ion peak intensity at certain size clusters Y(-)(H(2)O)(m) indicating specific thermochemical stability. Thus, Y(-)(H(2)O)(m) may correspond to the magic number or first hydrated shell in the cluster series Y(-)(H(2)O)(n). The high intensity discontinuity at HO(-)(H(2)O)(3) observed was the first mass spectrometric evidence for the specific stability of HO(-)(H(2)O)(3) as the first hydrated shell which Eigen postulated in 1964. The negative ion water clusters Y(-)(H(2)O)(n) observed in the mass spectra are most likely to be formed via core ion formation in the ambient discharge area (760 torr) and the growth of water clusters by adiabatic expansion in the vacuum region of the mass spectrometers (≈1 torr). The detailed mechanism of the formation of the different core water cluster ions Y(-)(H(2)O)(n) is described.

  3. Martian Atmospheric Pressure Static Charge Elimination Tool

    Science.gov (United States)

    Johansen, Michael R.

    2014-01-01

    A Martian pressure static charge elimination tool is currently in development in the Electrostatics and Surface Physics Laboratory (ESPL) at NASA's Kennedy Space Center. In standard Earth atmosphere conditions, static charge can be neutralized from an insulating surface using air ionizers. These air ionizers generate ions through corona breakdown. The Martian atmosphere is 7 Torr of mostly carbon dioxide, which makes it inherently difficult to use similar methods as those used for standard atmosphere static elimination tools. An initial prototype has been developed to show feasibility of static charge elimination at low pressure, using corona discharge. A needle point and thin wire loop are used as the corona generating electrodes. A photo of the test apparatus is shown below. Positive and negative high voltage pulses are sent to the needle point. This creates positive and negative ions that can be used for static charge neutralization. In a preliminary test, a floating metal plate was charged to approximately 600 volts under Martian atmospheric conditions. The static elimination tool was enabled and the voltage on the metal plate dropped rapidly to -100 volts. This test data is displayed below. Optimization is necessary to improve the electrostatic balance of the static elimination tool.

  4. Modelling study of dielectric barrier glow discharge in Ar/NH3 mixture at atmospheric pressure%大气压Ar/NH3介质阻挡辉光放电的仿真研究

    Institute of Scientific and Technical Information of China (English)

    张增辉; 张冠军; 邵先军; 常正实; 彭兆裕; 许昊

    2012-01-01

    为了研究火气压下氩气(Ar)中掺杂氨气(NH3)的Ar/NH3介质阻挡辉光放电的放电机理,通过建立一‘个多粒子的自洽耦合流体模型,采用有限元方法进行数值计算,得到了气体间隙压降、介质表面电荷密度、放电电流密度随时间的周期变化波形,以及带电粒子、中性粒子与空间电场强度的时空分布.仿真计算结果表明:气体间隙的周期击穿过程主要由气隙电压控制,并受气隙两侧介质极板上积聚的表面电荷的影响.气隙间带电粒子密度和电场强度的时空分布表明本文的放电过程存在阴极位降区、负辉区、法拉第暗区、等离子体正柱区等辉光放电的典型区域,放电模式为大气压辉光放电.在Ar/NH3等离子体中,主要的正离子为NH+,其次为Ar2+,主要的负离子为NHi:NH3分解产生的主要的激发态分子为NH,NH2和N2H3,而最终的稳态产物主要是N2和H2.%In order to investigate the mechanism of dielectric barrier glow discharge in Ar/NH3 mixture at atmospheric pressure, a multiple particles self-consistent coupled fluid model is proposed. And the finite-element method is used in the numerical calculation model, so the periodically varying waveforms of gas voltage, dielectric surface charge density and discharge current density are investigated. The spatial and temporal distributions of charged and neutral particles density and space electrical field strength are also obtained. The simulation results show that the periodic breakdown process of the gas gap is controlled by the gas voltage, and affected by dielectric surface charges. The spatiotemporal distributions of charged particle density and electrical field strength show that the discharge under conditions considered in this model is a typical atmospheric pressure glow discharge, and that in the discharge process there exist an obvious cathode fall region, a negative glow region, a

  5. Domestic atmospheric pressure thermal deaerators

    Science.gov (United States)

    Egorov, P. V.; Gimmelberg, A. S.; Mikhailov, V. G.; Baeva, A. N.; Chuprakov, M. V.; Grigoriev, G. V.

    2016-04-01

    Based on many years of experience and proven technical solutions, modern atmospheric pressure deaerators of the capacity of 0.4 to 800 t/h were designed and developed. The construction of such deaerators is based on known and explored technical solutions. A two-stage deaeration scheme is applied where the first stage is a jet dripping level (in a column) and the second one is a bubble level (in a tank). In the design of deaeration columns, low-pressure hydraulic nozzles (Δ p tests of the new deaerator prototypes of the capacity of 800 and 500 t/h in the HPP conditions showed their sustainable, reliable, and efficient work in the designed range of hydraulic and thermal loads. The content of solved oxygen and free carbon dioxide in make-up water after deaerators meets the requirements of State Standard GOST 16860-88, the operating rules and regulations, and the customer's specifications. Based on these results, the proposals were developed on the structure and the design of deaerators of the productivity of more than 800 t/h for the use in circuits of large heating systems and the preparation of feed water to the TPP at heating and industrial-heating plants. The atmospheric pressure thermal deaerators developed at NPO TsKTI with consideration of the current requirements are recommended for the use in water preparation schemes of various power facilities.

  6. Determining Atmospheric Pressure Using a Water Barometer

    Science.gov (United States)

    Lohrengel, C. Frederick, II; Larson, Paul R.

    2012-01-01

    The atmosphere is an envelope of compressible gases that surrounds Earth. Because of its compressibility and nonuniform heating by the Sun, it is in constant motion. The atmosphere exerts pressure on Earth's surface, but that pressure is in constant flux. This experiment allows students to directly measure atmospheric pressure by measuring the…

  7. Determination of Hg(2+) by on-line separation and pre-concentration with atmospheric-pressure solution-cathode glow discharge atomic emission spectrometry.

    Science.gov (United States)

    Li, Qing; Zhang, Zhen; Wang, Zheng

    2014-10-03

    A simple and sensitive method to determine Hg(2+) was developed by combining solution-cathode glow discharge atomic emission spectrometry (SCGD-AES) with flow injection (FI) based on on-line solid-phase extraction (SPE). We synthesized l-cysteine-modified mesoporous silica and packed it in an SPE microcolumn, which was experimentally determined to possess a good mercury adsorption capacity. An enrichment factor of 42 was achieved under optimized Hg(2+) elution conditions, namely, an FI flow rate of 2.0 mL min(-1) and an eluent comprised of 10% thiourea in 0.2 mol L(-1) HNO3. The detection limit of FI-SCGD-AES was determined to be 0.75 μg L(-1), and the precision of the 11 replicate Hg(2+) measurements was 0.86% at a concentration of 100 μg L(-1). The proposed method was validated by determining Hg(2+) in certified reference materials such as human hair (GBW09101b) and stream sediment (GBW07310).

  8. Determination of Hg{sup 2+} by on-line separation and pre-concentration with atmospheric-pressure solution-cathode glow discharge atomic emission spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Li, Qing [Shanghai Institute of Ceramics, Chinese Academy of Science, Shanghai 200050 (China); Zhang, Zhen [Shanghai Institute of Ceramics, Chinese Academy of Science, Shanghai 200050 (China); School of Materials Science and Engineering, Shanghai University, Shanghai 200072 (China); Wang, Zheng, E-mail: wangzheng@mail.sic.ac.cn [Shanghai Institute of Ceramics, Chinese Academy of Science, Shanghai 200050 (China)

    2014-10-03

    Highlights: • A modified SBA-15 mesoporous silica (SH-SBA-15) was synthesized as a sorbent. • On-line SPE combined with SCGD-AES based on FIA was used to detect Hg{sup 2+} firstly. • A simple, low-cost Hg{sup 2+} analysis in a complex matrix was established. • The sensitive detection of Hg{sup 2+} was achieved with a detection limit of 0.75 μg L{sup −1}. - Abstract: A simple and sensitive method to determine Hg{sup 2+} was developed by combining solution-cathode glow discharge atomic emission spectrometry (SCGD-AES) with flow injection (FI) based on on-line solid-phase extraction (SPE). We synthesized L-cysteine-modified mesoporous silica and packed it in an SPE microcolumn, which was experimentally determined to possess a good mercury adsorption capacity. An enrichment factor of 42 was achieved under optimized Hg{sup 2+} elution conditions, namely, an FI flow rate of 2.0 mL min{sup −1} and an eluent comprised of 10% thiourea in 0.2 mol L{sup −1} HNO{sub 3}. The detection limit of FI–SCGD-AES was determined to be 0.75 μg L{sup −1}, and the precision of the 11 replicate Hg{sup 2+} measurements was 0.86% at a concentration of 100 μg L{sup −1}. The proposed method was validated by determining Hg{sup 2+} in certified reference materials such as human hair (GBW09101b) and stream sediment (GBW07310)

  9. Comparision Study of Dielectric Barrier Discharge in Inert Gases at Atmospheric Pressure%大气压不同惰性气体介质阻挡放电特性的比较

    Institute of Scientific and Technical Information of China (English)

    罗海云; 冉俊霞; 王新新

    2012-01-01

    To deeply understand dielectric barrier discharge in inert gases at atmospheric pressure, we investigated the breakdown voltage, the discharge mode, and evolution of DBD in a parallel gap by means of electrical measurements and fast photography in helium, neon, and argon at atmospheric pressure. Homogenous discharges could be easily produced in 2 - 8 mm gaps in helium and neon, and they were attributed to glow discharge. Compared to that in helium or neon, the homogenous DBD often covered only a part of the electrode in 2 mm-argon using the high frequency power. And with a small increase of the applied voltage, it would turn into a pattern mode. When the argon width was no less than 3mm, the DBD always resulted in bright filamentary streamers in which the current density could reach 7. 5 A/cm2. High-speed time-resolved photographs of the homogenous discharge in helium, neon and argon were taken using an ICCD camera. Side-view photographs showed an evolution from Townsend discharge to glow discharge. The end-view photographs exhibited a radial development. The spectroscopic diagnosis showed that the penning ionization between energetic metastabilty and impurities was the most important reason leading to a homogenous discharge. The N+ first negative system(B2∑u+ →X2∑g+ ), existing in helium discharge, could not be observed in the neon or argon, as was due to the lower energy level of metastable neon and argon states. Instead, the emission spectral lines of N2 second positive band system( C3 Пu→B3 Пg) were observed in neon and argon.%为了加深对大气压惰性气体介质阻挡放电的认识,使用电特性测量、高速摄影,发射光谱等手段研究了平板结构大气压惰性气体介质阻挡放电的放电模式、演化过程以及放电机理,并对不同气体的放电特性进行了比较。实验结果表明在2~8mm大气压氦气、氖气中可很容易的实现稳定的均匀放电,并且其放

  10. Lightning and middle atmospheric discharges in the atmosphere

    Science.gov (United States)

    Siingh, Devendraa; Singh, R. P.; Kumar, Sarvan; Dharmaraj, T.; Singh, Abhay K.; Singh, Ashok K.; Patil, M. N.; Singh, Shubha

    2015-11-01

    Recent development in lightning discharges including transient luminous events (TLEs) and global electric circuit are discussed. Role of solar activity, convective available potential energy, surface temperature and difference of land-ocean surfaces on convection process are discussed. Different processes of discharge initiation are discussed. Events like sprites and halos are caused by the upward quasi-electrostatic fields associated with intense cloud-to-ground discharges while jets (blue starter, blue jet, gigantic jet) are caused by charge imbalance in thunderstorm during lightning discharges but they are not associated with a particular discharge flash. Elves are generated by the electromagnetic pulse radiated during lightning discharges. The present understanding of global electric circuit is also reviewed. Relation between lightning activity/global electric circuit and climate is discussed.

  11. Formation of Dielectric Barrier Multi-Pulse Glow Discharges in Helium at Atmospheric Pressure%大气压氦气介质阻挡多脉冲辉光放电的形成条件

    Institute of Scientific and Technical Information of China (English)

    郝艳捧; 王晓蕾; 阳林

    2009-01-01

    Discharge currents are measured on single pulse, multi-pulse glow dielectric barrier discharges (DBDs) using high-frequency power supply in helium at atmospheric pressure. The influence of the applied voltage amplitude and frequency, as well as gas distance on multi-pulse glow DBD is discussed and analyzed. Conditions to form multi-pulse glow DBDs are proposed. The results show that the higher amplitude of the applied voltage, the lower voltage frequency can be useful to form a multi-pulse glow DBD. Moreover, the higher applied voltage is necessary to form multi-pulse glow DBDs.%利用高频高压电源,进行大气压氦气介质阻挡放电试验,测量了单脉冲和多脉冲辉光放电的放电回路电流波形,分析了外加电压峰.峰值和频率、放电间隙对多脉冲辉光放电过程的影响,探讨了大气压氦气介质阻挡多脉冲辉光放电的形成条件.研究表明:多脉冲辉光放电的形成条件是较高的外加电压峰-峰值、较低的电源频率,其中较高的外加电压峰-峰值是产生多脉冲辉光放电的必要条件.

  12. Atmospheric pressure plasma treatment of glassy carbon for adhesion improvement

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Mortensen, Henrik Junge; Stenum, Bjarne

    2007-01-01

    Glassy carbon plates were treated with an atmospheric pressure dielectric barrier discharge (DBD). He gas, gas mixtures of He and reactive gases such as O2, CO2 and NH3, Ar gas and Ar/NH3 gas mixture were used as treatment gases. The oxygen and nitrogen contents on the surface as well as defect...

  13. Spacecraft Sterilization Using Non-Equilibrium Atmospheric Pressure Plasma

    Science.gov (United States)

    Cooper, Moogega; Vaze, Nachiket; Anderson, Shawn; Fridman, Gregory; Vasilets, Victor N.; Gutsol, Alexander; Tsapin, Alexander; Fridman, Alexander

    2007-01-01

    As a solution to chemically and thermally destructive sterilization methods currently used for spacecraft, non-equilibrium atmospheric pressure plasmas are used to treat surfaces inoculated with Bacillus subtilis and Deinococcus radiodurans. Evidence of significant morphological changes and reduction in viability due to plasma exposure will be presented, including a 4-log reduction of B. subtilis after 2 minutes of dielectric barrier discharge treatment.

  14. Atmospheric pressure plasma surface modification of carbon fibres

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Løgstrup Andersen, Tom; Michelsen, Poul

    2008-01-01

    Carbon fibres are continuously treated with dielectric barrier discharge plasma at atmospheric pressure in various gas conditions for adhesion improvement in mind. An x-ray photoelectron spectroscopic analysis indicated that oxygen is effectively introduced onto the carbon fibre surfaces by He, He...

  15. Super-atmospheric pressure chemical ionization mass spectrometry.

    Science.gov (United States)

    Chen, Lee Chuin; Rahman, Md Matiur; Hiraoka, Kenzo

    2013-03-01

    Super-atmospheric pressure chemical ionization (APCI) mass spectrometry was performed using a commercial mass spectrometer by pressurizing the ion source with compressed air up to 7 atm. Similar to typical APCI source, reactant ions in the experiment were generated with corona discharge using a needle electrode. Although a higher needle potential was necessary to initiate the corona discharge, discharge current and detected ion signal were stable at all tested pressures. A Roots booster pump with variable pumping speed was installed between the evacuation port of the mass spectrometer and the original rough pumps to maintain a same pressure in the first pumping stage of the mass spectrometer regardless of ion source pressure. Measurement of gaseous methamphetamine and research department explosive showed an increase in ion intensity with the ion source pressure until an optimum pressure at around 4-5 atm. Beyond 5 atm, the ion intensity decreased with further increase of pressure, likely due to greater ion losses inside the ion transport capillary. For benzene, it was found that besides molecular ion and protonated species, ion due to [M + 2H](+) which was not so common in APCI, was also observed with high ion abundance under super-atmospheric pressure condition.

  16. Modification of various metals by volume discharge in air atmosphere

    Science.gov (United States)

    Shulepov, Mikhail A.; Erofeev, Mikhail V.; Oskomov, Konstantin V.; Tarasenko, Victor F.

    2015-12-01

    The results of the modification of stainless steel, niobium and titanium by volume discharge induced by a beam of runaway electrons in air under normal pressure are presented. Changes in the chemical composition of the surface layers of metal by the action of the discharge, structural changes and changes of hardness were studied. It has been found that the concentration of oxygen and carbon in the surface layers of the samples depend on the number of discharge pulses. The aim of this work is to find possible application of this type of discharge in science and industrial production.

  17. Corona discharge ion mobility spectrometry at reduced pressures

    Science.gov (United States)

    Tabrizchi, Mahmoud; Rouholahnejad, Fereshteh

    2004-11-01

    Ion mobility spectrometers (IMSs) normally operate at ambient pressure. In this work an IMS cell has been designed and constructed to allow the pressure to be reduced inside the IMS cell. In this cell, corona discharge was employed as the ionization source. Reducing pressure affected both the discharge and the performance of the IMS. The discharge current was observed to increase with reducing pressure while the ignition potential decreased. The ion current received at the collector plate was also increased about 50 times when the pressure was reduced from ambient pressure to 15 Torr. The higher ion current can lead to an extended dynamic range. IMS spectra were recorded at various pressures and the results show that the drift times shift perfectly linear with pressure. This suggests that unlike temperature, pressure correction for ion mobility spectra is as simple as multiplying the drift times by a factor of 760/P.

  18. Special issue: diagnostics of atmospheric pressure microplasmas

    Science.gov (United States)

    Bruggeman, Peter; Czarnetzki, Uwe; Tachibana, Kunihide

    2013-11-01

    In recent decades, a strong revival of non-equilibrium atmospheric pressure plasma studies has developed in the form of microplasmas. Microplasmas have typical scales of 1 mm or less and offer a very exciting research direction in the field of plasma science and technology as the discharge physics can be considerably different due to high collisionality and the importance of plasma-surface interaction. These high-pressure small-scale plasmas have a diverse range of physical and chemical properties. This diversity coincides with various applications including light/UV sources [1], material processing [2], chemical analysis [3], material synthesis [4], electromagnetics [5], combustion [6] and even medicine [7]. At atmospheric pressure, large scale plasmas have the tendency to become unstable due to the high collision rates leading to enhanced heating and ionization compared to their low-pressure counterparts. As low-pressure plasmas typically operate in reactors with sizes of tens of centimetres, scaling up the pressure to atmospheric pressure the size of the plasma reduces to typical sizes below 1 mm. A natural approach of stabilizing atmospheric pressure plasmas is thus the use of microelectrode geometries. Traditionally microplasmas have been produced in confined geometries which allow one to stabilize dc excited discharges. This stabilization is intrinsically connected to the large surface-to-volume ratio which enhances heat transfer and losses of charged and excited species to the walls. Currently challenging boundaries are pushed by producing microcavity geometries with dimensions of the order of 1 µm [8]. The subject of this special issue, diagnostics of microplasmas, is motivated by the many challenges in microplasma diagnostics in view of the complex chemistry and strong spatial (and even temporal) gradients of species densities and plasma properties. Atmospheric pressure plasmas have a very long history dating back more than 100 years, with early work of

  19. Pulse volume discharges in high pressure gases

    Science.gov (United States)

    Yamshchikov, V. A.

    2015-11-01

    New approach for suppression of plasma inhomogeneities and instabilities in the volume self-sustained discharge is offered. The physical model is offered and conditions of obtaining extremely homogeneous self-sustained discharge are defined (with full suppression of plasma inhomogeneity and instability). Results of calculations agree with experiments.

  20. Corona Discharge Atmospheric Pressure Ionization Mass Spectrometry for Real Time Gas Analysis%在线气体分析的电晕放电大气压电离质谱

    Institute of Scientific and Technical Information of China (English)

    梁华正; 张燮; 陈双喜; 邵昭

    2008-01-01

    研制了适合在线气体分析的电晕放电大气压电离源(corona discharge atmospheric pressure ionization source)及其与商品质谱仪(LTQ-MS)的接口,对其试剂离子的产生机理进行了研究,以H2O*+ (H2O)为试剂离子,对乙醇气体进行检测,并分析了该离子的产生机制.实验结果表明:在潮湿氮气中电晕放电产生的主要试剂离子是m/z 36、37和55;而在含丙酮的潮湿氮气中则产生m/z 59和76等离子.利用静态顶空-电晕放电大气压电离质谱对不同浓度的乙醇水溶液进行分析,结果表明:以m/z 64为检测对象,乙醇气体浓度的最低检出限可达2.4×10-7 g/L;而以m/z 47为检测对象,检出限为5.9×10-6 g/L.同时还利用动态顶空-电晕放电大气压电离质谱对栀子花香气成分进行了检测,为生物挥发性物质的在线检测提供了一种新方法.

  1. An Atmospheric Pressure Ping-Pong "Ballometer"

    Science.gov (United States)

    Kazachkov, Alexander; Kryuchkov, Dmitriy; Willis, Courtney; Moore, John C.

    2006-01-01

    Classroom experiments on atmospheric pressure focus largely on demonstrating its existence, often in a most impressive way. A series of amusing physics demonstrations is widely known and practiced by educators teaching the topic. However, measuring the value of atmospheric pressure(P[subscript atm]) is generally done in a rather mundane way,…

  2. 大气压氖气介质阻挡放电脉冲等离子射流特性%Characterization of dielectric barrier discharge pulse plasma jet in neon at atmospheric pressure

    Institute of Scientific and Technical Information of China (English)

    雷枭; 方志; 邵涛; 章程

    2012-01-01

    采用自行研制的低造价、小体积、可产生幅值0-35kV、重复频率1kHz的高压μs脉冲电源,设计了一套以大气压氖气为工作气体的介质阻挡放电(DBD)等离子体射流源,通过测量并计算放电过程中的电压-电流波形、拍摄放电图像、光谱分析等手段,对电压幅值、气体流速对氖气等离子体射流特性的影响进行了研究.结果表明:μs脉冲电源激励下大气压氖气DBD能产生锥状的等离子射流且其等离子强度适中;μs脉冲电源电压幅值的快速上升,可在放电空间瞬间施加高的过电压,能有效促进放电功率、电子密度、电子激发温度和射流长度的增加;工作气体流速的增加使得放电功率、电子激发温度和电子密度减小,而射流长度变化很小;一定条件下,能形成长距离的射流.%A dielectric barrier discharge (DBD) plasma jet source is presented, which is low-cost and small in size, fed with neon and driven by the a self-developed microsecond pulse power supply with a peak voltage of 0-35 kV and a frequency of 1 kHz. Influences of applied voltage amplitude and gas flow rate on the discharge characteristics of the plasma jet are studied by measuring the waveforms of voltage and current, taking the light emission images and measuring the optical emission spectra. Results show that, the DBD in neon at atmospheric pressure driven by a microsecond pulse voltage can generate a cone-shaped flaming plasma jet, and the intensity of plasma is moderate. The fast rise of the applied pulse voltage can apply a higher overvoltage instantly to the gas gap, and thus can promotes the increases of discharge power, electron density and excitation temperature efficiently; while the increase of gas flow rate results in the decrease of these parameters but little variation of the jet length. Under certain operating conditions, the plasma jet with long length can be generated.

  3. Comparison of atmospheric air plasmas excited by high-voltage nanosecond pulsed discharge and sinusoidal alternating current discharge

    Science.gov (United States)

    Zhang, Shuai; Wang, Wen-chun; Jiang, Peng-chao; Yang, De-zheng; Jia, Li; Wang, Sen

    2013-10-01

    In this paper, atmospheric pressure air discharge plasma in quartz tube is excited by 15 ns high-voltage nanosecond pulsed discharge (HVNPD) and sinusoidal alternating current discharge (SACD), respectively, and a comparison study of these two kinds of discharges is made through visual imaging, electrical characterization, optical detection of active species, and plasma gas temperature. The peak voltage of the power supplies is kept at 16 kV while the pulse repetition rate of nanosecond pulse power supply is 100 Hz, and the frequency of sinusoidal power supply is 10 kHz. Results show that the HVNPD is uniform while the SACD presents filamentary mode. For exciting the same cycles of discharge, the average energy consumption in HVNPD is about 1/13 of the SACD. However, the chemical active species generated by the HVNPD is about 2-9 times than that excited by the SACD. Meanwhile, the rotational and vibrational temperatures have been obtained via fitting the simulated spectrum of N2 (C3Πu → B3Πg, 0-2) with the measured one, and the results show that the plasma gas temperature in the HVNPD remains close to room temperature whereas the plasma gas temperature in the SACD is about 200 K higher than that in HVNPD in the initial phase and continually increases as discharge exposure time goes on.

  4. Effects of background gas on sulfur hexafluoride removal by atmospheric dielectric barrier discharge plasma

    Science.gov (United States)

    Zhang, Xiaoxing; Xiao, Hanyan; Hu, Xiongxiong; Gui, Yingang

    2016-11-01

    The effects of background gases (He, Ar, N2 and air) on SF6 removal in a dielectric barrier reactor were investigated at atmospheric pressure. A comparison among these background gases was performed in terms of discharge voltage, discharge power, mean electron energy, electron density, removal efficiency and energy yield for the destruction of SF6. Results showed that the discharge voltage of He and Ar was lower than that of N2 and air, but the difference of their discharge power was small. Compared with three other background gases, Ar had a relatively superior destruction and removal rate and energy yield since the mean electron energy and electron density in SF6/H2O/Ar plasma were both maintained at a high level. Complete removal of 2% SF6 could be achieved at a discharge power of 48.86 W with Ar and the corresponding energy yield can reach 4.8 g/kWh.

  5. Effects of background gas on sulfur hexafluoride removal by atmospheric dielectric barrier discharge plasma

    Directory of Open Access Journals (Sweden)

    Xiaoxing Zhang

    2016-11-01

    Full Text Available The effects of background gases (He, Ar, N2 and air on SF6 removal in a dielectric barrier reactor were investigated at atmospheric pressure. A comparison among these background gases was performed in terms of discharge voltage, discharge power, mean electron energy, electron density, removal efficiency and energy yield for the destruction of SF6. Results showed that the discharge voltage of He and Ar was lower than that of N2 and air, but the difference of their discharge power was small. Compared with three other background gases, Ar had a relatively superior destruction and removal rate and energy yield since the mean electron energy and electron density in SF6/H2O/Ar plasma were both maintained at a high level. Complete removal of 2% SF6 could be achieved at a discharge power of 48.86 W with Ar and the corresponding energy yield can reach 4.8 g/kWh.

  6. Recent studies on nanosecond-timescale pressurized gas discharges

    Science.gov (United States)

    Yatom, S.; Shlapakovski, A.; Beilin, L.; Stambulchik, E.; Tskhai, S.; Krasik, Ya E.

    2016-12-01

    The results of recent experimental and numerical studies of nanosecond high-voltage discharges in pressurized gases are reviewed. The discharges were ignited in a diode filled by different gases within a wide range of pressures by an applied pulsed voltage or by a laser pulse in the gas-filled charged resonant microwave cavity. Fast-framing imaging of light emission, optical emission spectroscopy, x-ray foil spectrometry and coherent anti-Stokes Raman scattering were used to study temporal and spatial evolution of the discharge plasma density and temperature, energy distribution function of runaway electrons and dynamics of the electric field in the plasma channel. The results obtained allow a deeper understanding of discharge dynamical properties in the nanosecond timescale, which is important for various applications of these types of discharges in pressurized gases.

  7. Surface cleaning of metal wire by atmospheric pressure plasma

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, T., E-mail: tsubasa@oshima-k.ac.jp [Electronic-Mechanical Engineering Department, Oshima National College of Maritime Technology, 1091-1 Komatsu, Suo-Oshima, Yamaguchi (Japan); Department of Electrical Engineering, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka (Japan); Buttapeng, C. [School of Electrical and Energy Engineering, University of the Thai Chamber of Commerce, 126/1, Vibhavadee-Rungsit, Dindaeng, Bangkok 10400 (Thailand); Furuya, S. [Faculty of Education, Gunma University, 4-2 Aramaki, Maebashi (Japan); Harada, N. [Department of Electrical Engineering, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka (Japan)

    2009-11-30

    In this study, the possible application of atmospheric pressure dielectric barrier discharge plasma for the annealing of metallic wire is examined and presented. The main purpose of the current study is to examine the surface cleaning effect for a cylindrical object by atmospheric pressure plasma. The experimental setup consists of a gas tank, plasma reactor, and power supply with control panel. The gas assists in the generation of plasma. Copper wire was used as an experimental cylindrical object. This copper wire was irradiated with the plasma, and the cleaning effect was confirmed. The result showed that it is possible to remove the tarnish which exists on the copper wire surface. The experiment reveals that atmospheric pressure plasma is usable for the surface cleaning of metal wire. However, it is necessary to examine the method for preventing oxidization of the copper wire.

  8. Atmospheric pressure plasmas for aerosols processes in materials and environment

    Science.gov (United States)

    Borra, J. P.; Jidenko, N.; Bourgeois, E.

    2009-08-01

    The paper highlights applications of some atmospheric pressure plasmas (dc-corona, streamer and spark and ac-Dielectric Barrier Discharges) to aerosol processes for Materials and Environment (filtration, diagnostics). The production of vapor i.e. condensable gaseous species, leads to nano-sized particles by physical and chemical routes of nucleation in these AP plasmas: (i) when dc streamer and spark filamentary discharges as well as ac filamentary dielectric barrier discharges interact with metal or dielectric surfaces, and (ii) when discharges induce reactions with gaseous precursors in volume. It is shown how composition, size and structure of primary nano-particles are related to plasma parameters (energy, number per unit surface and time and thermal gradients). Then the growth by coagulation controls the final size of agglomerates versus plasma parameters and transit time in and after the plasma. Charging and electro-thermal collection are depicted to account for the related potential applications of controlled kinematics of charged aerosol.

  9. Adhesion improvement of fibres by continuous plasma treatment at atmospheric pressure

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Løgstrup Andersen, Tom; Sørensen, Bent F.

    2013-01-01

    Carbon fibres and ultra-high-molecular-weight polyethylene (UHMWPE) fibres were continuously treated by a dielectric barrier discharge plasma at atmospheric pressure for adhesion improvement with epoxy resins. The plasma treatment improved wettability, increased the oxygen containing polar...

  10. Spectral Measurement of Atmospheric Pressure Plasma by Means of Digital Camera

    Institute of Scientific and Technical Information of China (English)

    葛袁静; 张广秋; 刘益民; 赵志发

    2002-01-01

    A digital camera measuring system has been used successfully to measure the space fluctuation behaviors of Induced Dielectric Barrier Discharge (IDBD) plasma at atmospheric pressure. The experimental results showed that: (1) The uniformity of electron temperature in space depends on discharge condition and structure of web electrode. For a certain web electrode the higher the discharge voltage is, the more uniform distribution of electron temperature in space will be. For a certain discharge the finer and denser the holes on web electrode are, the more uniform distribution of electron temperature in space will be (2). Digital camera is an available equipment to measure some behaviors of the plasma working at atmospheric pressure.

  11. High Pressure Micro-Slot Hollow Cathode Discharge

    Institute of Scientific and Technical Information of China (English)

    Wang Xinbing; Zhou Lina; Yao Xilin

    2005-01-01

    A direct current glow discharge source structure operating at high pressure based on the micro-slot hollow cathode is presented in this article. A 100 μm width slot cathode was fabricated of copper, and a stable DC glow discharge with an area of 0.5 mm2 was produced in noble gases (He, Ne) and air over a wide pressure range (kPa ~ 10 kPa). The current-voltage characteristics and the near UV radiation emission of the discharge were studied.

  12. [Investigation on the Spectral Characteristics of a Plasma Jet in Atmospheric Argon Glow Discharge].

    Science.gov (United States)

    Li, Xue-chen; Zhang, Chun-yan; Li, Ji-yuan; Bao, Wen-ting

    2015-12-01

    Plasma jet is a kind of important plasma source at atmospheric pressure. In recent years, it becomes an important hot topic in the field of low temperature plasma. In this paper, using a tungsten needle and a tungsten wire mesh, a direct-current excited jet is developed to operate in argon at atmospheric pressure. In the atmospheric pressure argon, the plasma jet can produce a stable plasma plume. By using the method of emission spectroscopy, the parameters of the plasma plume are investigated. The discharge emits dazzling white light from the area between the tungsten needle electrode and the wire mesh electrode. A plasma plume with a flame shape appears outside the tungsten wire mesh electrode. For a constant value of voltage (U = 13.5 kV), the length of the plasma plume increases with the gas flow rate. For a constant value of the gas flow rate(10 L · min⁻¹), the length of the plasma plume increases with the voltage. The voltage is inversely proportional to the current under the constant gas flow rate. In other words, the voltage decreases with the discharge current, which indicates that a glow discharge is formed in the plasma jet. Optical emission spectrum in 300 to 800 nm is collected from the direct-current excited plasma jet. By Boltzmann plot method, the excited electron temperature of the plasma plume is investigated as a function of the applied voltage or the gas flow rate. Results show that the excited electron temperature increases with decreasing applied voltage under the constant gas flow. Moreover, it increases with decreasing the gas flow under the constant voltage. Based on the discharge theory, these experimental phenomena are explained qualitatively. These results are of great importance to the development of atmospheric pressure uniform discharge plasma source and its application in industrial field.

  13. Effects of airflow on the distribution of filaments in atmospheric AC dielectric barrier discharge

    Science.gov (United States)

    Fan, Zhihui; Qi, Haicheng; Liu, Yidi; Yan, Huijie; Ren, Chunsheng

    2016-12-01

    Atmospheric-pressure dielectric barrier discharge (DBD) accompanied by airflow has attracted a significant attention for its extensive applications. In this paper, the effects of airflow on the characteristics of the atmospheric air DBD plasma are experimentally investigated using the DBD reactor excited by a 15 kHz AC power source. In order to study the discharge filaments distribution at different flow rates, transparent conductive indium tin oxide film is used as the upper electrode, and quartz glasses are used as insulated dielectrics. Experiment results prove that the breakdown voltage is decreased and more current pulses with declined amplitudes are produced when the airflow is introduced into the discharge gap. It is confirmed that although the discharge seems to be diffuse in the presence of airflow to the naked eyes, the discharge mode remains filamentary in the intensified charge-coupled device images within a single AC cycle. By acquiring the images with a different exposure time, it can be recognized that the discharge filaments move along the flow field direction with a velocity less than the corresponding flow rate. The movement of discharge filaments is attributed to the motion of the charge induced by the airflow.

  14. Atmospheric-pressure guided streamers for liposomal membrane disruption

    Science.gov (United States)

    Svarnas, P.; Matrali, S. H.; Gazeli, K.; Aleiferis, Sp.; Clément, F.; Antimisiaris, S. G.

    2012-12-01

    The potential to use liposomes (LIPs) as a cellular model in order to study interactions of cold atmospheric-pressure plasma with cells is herein investigated. Cold atmospheric-pressure plasma is formed by a dielectric-barrier discharge reactor. Large multilamellar vesicle liposomes, consisted of phosphatidylcholine and cholesterol, are prepared by the thin film hydration technique, to encapsulate a small hydrophilic dye, i.e., calcein. The plasma-induced release of calcein from liposomes is then used as a measure of liposome membrane integrity and, consequently, interaction between the cold atmospheric plasma and lipid bilayers. Physical mechanisms leading to membrane disruption are suggested, based on the plasma characterization including gas temperature calculation.

  15. Atmospheric-pressure guided streamers for liposomal membrane disruption

    Energy Technology Data Exchange (ETDEWEB)

    Svarnas, P.; Aleiferis, Sp. [High Voltage Laboratory, Department of Electrical and Computer Engineering, University of Patras, Rion 26504 (Greece); Matrali, S. H. [Pharmaceutical Technology Laboratory, Department of Pharmacy, University of Patras, Rion 26504 (Greece); Gazeli, K. [High Voltage Laboratory, Department of Electrical and Computer Engineering, University of Patras, Rion 26504 (Greece); IPREM-LCABIE, Plasmas et Applications, UPPA, 64000 Pau (France); Clement, F. [IPREM-LCABIE, Plasmas et Applications, UPPA, 64000 Pau (France); Antimisiaris, S. G. [Pharmaceutical Technology Laboratory, Department of Pharmacy, University of Patras, Rion 26504 (Greece); Institute of Chemical Engineering Sciences (ICES)-FORTH, Rion 26504 (Greece)

    2012-12-24

    The potential to use liposomes (LIPs) as a cellular model in order to study interactions of cold atmospheric-pressure plasma with cells is herein investigated. Cold atmospheric-pressure plasma is formed by a dielectric-barrier discharge reactor. Large multilamellar vesicle liposomes, consisted of phosphatidylcholine and cholesterol, are prepared by the thin film hydration technique, to encapsulate a small hydrophilic dye, i.e., calcein. The plasma-induced release of calcein from liposomes is then used as a measure of liposome membrane integrity and, consequently, interaction between the cold atmospheric plasma and lipid bilayers. Physical mechanisms leading to membrane disruption are suggested, based on the plasma characterization including gas temperature calculation.

  16. Micro-structured electrode arrays : high-frequency discharges at atmospheric pressure—characterization and new applications

    NARCIS (Netherlands)

    Baars-Hibbe, Lutz; Schrader, Christian; Sichler, Philipp; Cordes, Thorben; Gericke, Karl-Heinz; Büttgenbach, Stephanus; Draeger, Siegfried

    2004-01-01

    Micro-structured electrode (MSE) arrays allow to generate large-area uniform glow discharges over a wide pressure range up to atmospheric pressure. The electrode dimensions in the µm-range realized by means of modern micro-machining and galvanic techniques are small enough to generate sufficiently h

  17. Ultrasound enhanced plasma surface modification at atmospheric pressure

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Singh, Shailendra Vikram; Norrman, Kion

    Atmospheric pressure plasma treatment can be highly enhanced by simultaneous high-power ultrasonic irradiation onto the treating surface. It is because ultrasonic waves with a sound pressure level (SPL) above approximately 140 dB can reduce the thickness of a boundary gas layer between the plasma...... and the material surface, and thus many reactive species generated in the plasma can reach the surface before inactivated, and be efficiently utilized for surface modification. In the present work polyester plates are treated using a dielectric barrier discharge (DBD) and a gliding arc at atmospheric pressure...... irradiation, the water contact angle dropped markedly, and tended to decrease furthermore at higher power. The ultrasonic irradiation during the plasma treatment consistently improved the wettability. Oxygen containing polar functional groups were introduced at the surface by the plasma treatment...

  18. Laser Thomson scattering in a pulsed atmospheric arc discharge

    Science.gov (United States)

    Sommers, Bradley; Adams, Steven

    2015-09-01

    Laser scattering measurements, including Rayleigh, Raman, and Thomson scattering have been performed on an atmospheric pulsed arc discharge. Such laser scattering techniques offer a non-invasive diagnostic to measure gas temperature, electron temperature, and electron density in atmospheric plasma sources, particularly those with feature sizes approaching 1 mm. The pulsed discharge is ignited in a pin to pin electrode geometry using a 6 kV pulse with 10 ns duration. The electrodes are housed in a glass vacuum chamber filled with argon gas. The laser signal is produced by a Nd:Yag laser supply, repetitively pulsed at 10 Hz and frequency quadrupled to operate at 266 nm. The scattered laser signal is imaged onto a triple grating spectrometer, which is used to suppress the Rayleigh scatter signal in order to measure the low amplitude Thomson and Raman signals. Preliminary results include measurements of electron temperature and electron density in the plasma column taken during the evolution of the discharge. The laser system is also used to measure the Rayleigh scattering signal, which provides space and time resolved measurements of gas temperature in the arc discharge.

  19. Evaporation of urea at atmospheric pressure.

    Science.gov (United States)

    Bernhard, Andreas M; Czekaj, Izabela; Elsener, Martin; Wokaun, Alexander; Kröcher, Oliver

    2011-03-31

    Aqueous urea solution is widely used as reducing agent in the selective catalytic reduction of NO(x) (SCR). Because reports of urea vapor at atmospheric pressure are rare, gaseous urea is usually neglected in computational models used for designing SCR systems. In this study, urea evaporation was investigated under flow reactor conditions, and a Fourier transform infrared (FTIR) spectrum of gaseous urea was recorded at atmospheric pressure for the first time. The spectrum was compared to literature data under vacuum conditions and with theoretical spectra of monomolecular and dimeric urea in the gas phase calculated with the density functional theory (DFT) method. Comparison of the spectra indicates that urea vapor is in the monomolecular form at atmospheric pressure. The measured vapor pressure of urea agrees with the thermodynamic data obtained under vacuum reported in the literature. Our results indicate that considering gaseous urea will improve the computational modeling of urea SCR systems.

  20. Numerical investigation of the spatiotemporal distribution of chemical species in an atmospheric surface barrier-discharge

    Science.gov (United States)

    Hasan, M. I.; Walsh, J. L.

    2016-05-01

    Using a one dimensional time dependent convection-reaction-diffusion model, the temporal and spatial distributions of species propagating downstream of an atmospheric pressure air surface barrier discharge was studied. It was found that the distribution of negatively charged species is more spatially spread compared to positive ions species, which is attributed to the diffusion of electrons that cool down and attach to background gas molecules, creating different negative ions downstream of the discharge region. Given the widespread use of such discharges in applications involving the remote microbial decontamination of surfaces and liquids, the transport of plasma generated reactive species away from the discharge region was studied by implementing mechanical convection through the discharge region. It was shown that increased convection causes the spatial distribution of species density to become uniform. It was also found that many species have a lower density close to the surface of the discharge as convection prevents their accumulation. While for some species, such as NO2, convection causes a general increase in the density due to a reduced residence time close to the discharge region, where it is rapidly lost through reactions with OH. The impact of the applied power was also investigated, and it was found that the densities of most species, whether charged or neutral, are directly proportional to the applied power.

  1. THE RAMAN SCATTERING OF CARBON NANOTUBES PRODUCED IN DIFFERENT INERT GASES AND THEIR PRESSURES BY ARC DISCHARGE

    Institute of Scientific and Technical Information of China (English)

    ZHANG HAI-YAN; CHEN JIAN; LIU SONG-HAO; CHEN DI-HU; WU CHUN-YAN; HE YAN-YANG; LIANG LI-ZHENG; PENG SHAO-QI

    2000-01-01

    First- and second-order Raman spectra of carbon nanotubes produced in helium and argon atmospheres at a pressure ranging from 11 to 92 kPa by arc discharge have been measured and compared with each other. The position and bandwidth of the spectral lines depend on the kind of inert gases and their pressure. The Raman spectra of the nanotubes produced in argon gas atmosphere are much more similar to that of polycrystalline graphite than those of the nanotubes produced in helium gas atmosphere. The position and bandwidth of nanotube Raman peaks change with gas pressure in arc discharge because different diameter distribution of nanotubes is produced at different inert gas pressure. The Raman spectra of nanotubes produced at high pressure is much more like that of graphite than those produced in lower pressure

  2. Peptide fragmentation induced by radicals at atmospheric pressure.

    Science.gov (United States)

    Vilkov, Andrey N; Laiko, Victor V; Doroshenko, Vladimir M

    2009-04-01

    A novel ion dissociation technique, which is capable of providing an efficient fragmentation of peptides at essential atmospheric pressure conditions, is developed. The fragmentation patterns observed often contain c-type fragments that are specific to electron capture dissociation/electron transfer dissociation (ECD/ETD), along with the y-/b-type fragments that are specific to collision-activated dissociation (CAD). In the presented experimental setup, ion fragmentation takes place within a flow reactor located in the atmospheric pressure region between the ion source and the mass spectrometer. According to a proposed mechanism, the fragmentation results from the interaction of ESI-generated analyte ions with the gas-phase radical species produced by a corona discharge source.

  3. Graphene Membranes for Atmospheric Pressure Photoelectron Spectroscopy.

    Science.gov (United States)

    Weatherup, Robert S; Eren, Baran; Hao, Yibo; Bluhm, Hendrik; Salmeron, Miquel B

    2016-05-05

    Atmospheric pressure X-ray photoelectron spectroscopy (XPS) is demonstrated using single-layer graphene membranes as photoelectron-transparent barriers that sustain pressure differences in excess of 6 orders of magnitude. The graphene serves as a support for catalyst nanoparticles under atmospheric pressure reaction conditions (up to 1.5 bar), where XPS allows the oxidation state of Cu nanoparticles and gas phase species to be simultaneously probed. We thereby observe that the Cu(2+) oxidation state is stable in O2 (1 bar) but is spontaneously reduced under vacuum. We further demonstrate the detection of various gas-phase species (Ar, CO, CO2, N2, O2) in the pressure range 10-1500 mbar including species with low photoionization cross sections (He, H2). Pressure-dependent changes in the apparent binding energies of gas-phase species are observed, attributable to changes in work function of the metal-coated grids supporting the graphene. We expect atmospheric pressure XPS based on this graphene membrane approach to be a valuable tool for studying nanoparticle catalysis.

  4. High-pressure pulsed avalanche discharges: Formulas for required preionization density and rate for homogeneity

    Energy Technology Data Exchange (ETDEWEB)

    Brenning, N.; Axnaes, I.; Nilsson, J.O.; Eninger, J.E. [Royal Inst. of Tech., Stockholm (Sweden)

    1997-02-01

    The requirements on preionization for the formation of spatially homogeneous pulsed avalanche discharges are examined. The authors derive two formulas which apply in the case of a slowly rising electric field, one which gives the required preionization density at breakdown, and one which gives the required preionization rate. These quantities are expressed as functions of the electrochemical properties of the gas, the neutral density, and the electric field rise time. They also treat the statistical effect that the electrons tend to form groups, in contrast to being randomly distributed in space, during the prebreakdown phase. This process is found to increase the required preionization rate significantly, typically by a factor of five for a discharge at atmospheric pressure. Homogeneous high-pressure discharges have been used for laser excitation, and have also been proposed for chemical plasma processing (ozone production) because of their good scaling properties and high efficiency.

  5. Investigation of Atmospheric Plasma Discharge and Its Application to Surface Modification of Textile Materials

    Institute of Scientific and Technical Information of China (English)

    TANG Xiao-liang; QIU Gao; FENG Xian-ping; YAN Yong-hui; SHI Yun-cheng; YAN Zhi-ren; WANG Liang

    2005-01-01

    In this paper, an improved quasi-stable atmospheric pressure dielectric barrier discharge (DBD) plasma source is achieved after carefully controlled discharge voltage and current, discharge power, working gas, treatment period,and gap between the electrodes. This plasma source has been used to modify the surface of Polybutylene Terephthalate (PBT) melt-blown nonwovens and Polyester(PET) fabrics, and the various influences on surface modification and the aging effeet of treated polymeric materials have been systematically investigated. In addition, the method of spectrum analysis is also used for diagnosing plasma parameters such as electron temperature.Experimental results indicate that both the wettablity and permeation of treated PBT melt-blown nonwovens and dyeing ability of treated PET fabrics are certainly improved.

  6. Basic characteristics of an atmospheric pressure rf generated plasma jet

    Institute of Scientific and Technical Information of China (English)

    Wang Shou-Guo; Li Hai-Jiang; Ye Tian-Chun; Zhao Ling-Li

    2004-01-01

    A plasma jet has been developed which operates using radio frequency (rf) power and produces a stable homogeneous discharge at atmospheric pressure. Its discharge characteristics, especially the dependence of stable discharge operating range on the feed gas, were studied, and the electric parameters such as RMS current, RMS voltage and reflected power were obtained with different gas flows. These studies indicate that there is an optimum range of operation of the plasma jet for a filling with a gas mixture of He and O2. Two "failure" modes of the discharge are identified.One is a filamentary arc when the input power is raised above a critical level, another is that the discharge disappears gradually as the addition of O2 approaches 3.2%. Possible explanations for the two failure modes have been given. The current and voltage waveform measurements show that there is a clear phase shift between normal and failure modes.In addition, Ⅰ-Ⅴ curves as a function of pure helium and for 1% addition of oxygen have been studied.

  7. 大气压直流正电晕放电暂态空间电荷分布仿真研究%Numerical simulation of transient space charge distribution of DC positive corona discharge under atmospheric pressure air

    Institute of Scientific and Technical Information of China (English)

    廖瑞金; 伍飞飞; 刘兴华; 杨帆; 杨丽君; 周之; 翟蕾

    2012-01-01

    DC positive corona discharge under atmospheric environment. The model is based on the plasma hydrodynamics and the chemical dynamics, and it includes 12 species and 27 reactions. Besides, the photoionization effect is also considered in the proposed model. The simulation and the experiment on bar-plate electrode configuration with an inter-electrode gap of 5.0 mm at 2-5.5 kV are carried out. The discharge voltage-current characteristics and single pulse waveform are in good agreement with the experimental measurements. Based on this model, the electric field distribution, the electron temperature distribution, and the evolution of charged species distribution are investigated in detail. The results show that distributions of electron temperature and electric field have the same patterns, In the process of discharge, electron density is kept at 10^19 m-3 or so. O4+ is dominant compared with the other charged heavy species, and O+ and N+ play the key role in secondary electron emission: the unmbers of O~ and O are the largest in negative ions and neutral particle respectively, they play a negligible role in discharge process.

  8. Runaway electrons preionized diffuse discharges at high pressure

    Science.gov (United States)

    Tarasenko, Victor F.; Lomaev, Mikhail I.; Sorokin, Dmitry A.

    2010-09-01

    Breakdown of the gaps with a non-uniform electric field filled with nitrogen and air as well as with other gases under high-voltage nanosecond pulses was investigated. It is shown that conditions of obtaining a diffuse discharge without a source of additional ionization are extended at the voltage pulse duration decreasing. A volume discharge is formed due to the gap pre-ionization by runaway electrons and X-ray quanta. At a negative polarity of the electrode with a small radius of curvature, a volume (diffuse) discharge formation is determined by pre-ionization with runaway electrons which are generated due to the electric field amplification near the cathode and in the gap. At a positive polarity of the electrode with a small radius of curvature, the X-ray radiation, generated at the runaway electrons braking at the anode and in the gap, is of great importance in a volume discharge formation. A runaway electrons preionized diffuse discharge (REP DD) has two characteristic stages. In the first stage, the ionization wave overlaps the gap during a fraction of a second. The discharge current is determined by the conductivity current in the dense plasma of the ionization wave and the displacement current in the remaining part of the gap. The second stage of the discharge can be related to the anomalous glow discharge with a high specific input power. During the second stage, the gap voltage decreases and the cathode spots formed as a result of explosive electron emission can participate in the electron emission from the cathode. At the increase of the voltage pulse duration and specific input power, the REP DD transforms into a spark discharge form. A REP DD is easily realized in various gases and at different pressures; see [1] and references in [1]. At pressure decrease was obtained the anode electrons beam current to rise (up to ~2 kA/cm2 in helium). At the REP DD, the anode is influenced by the plasma of a dense nanosecond discharge with the specific input power

  9. Atmospheric pressure femtosecond laser imaging mass spectrometry

    Science.gov (United States)

    Coello, Yves; Gunaratne, Tissa C.; Dantus, Marcos

    2009-02-01

    We present a novel imaging mass spectrometry technique that uses femtosecond laser pulses to directly ionize the sample. The method offers significant advantages over current techniques by eliminating the need of a laser-absorbing sample matrix, being suitable for atmospheric pressure sampling, and by providing 10μm resolution, as demonstrated here with a chemical image of vegetable cell walls.

  10. Study of short atmospheric pressure dc glow microdischarge in air

    Science.gov (United States)

    Kudryavtsev, Anatoly; Bogdanov, Eugene; Chirtsov, Alexander; Emelin, Sergey

    2011-10-01

    The results of experiments and simulations of short (without positive column) atmospheric pressure dc glow discharge in air are presented. We used metal steel electrodes with a gap of 5-100 microns. The experimental voltage-current characteristic's (VAC) have a constant or slightly increasing form at low gap. The most stable microdischarges were burning with a flat cathode and rounded anode, when the length of the discharge is automatically established near the minimum of the Paschen curve by changing their binding on the anode. In this case microdischarge was stable and it had growing VAC. For simulations we used 2D fluid model with kinetic description of electrons. We solved the balance equations for the vibrationally- and the electronically-excited states of a nitrogen and oxygen molecules; nitrogen and oxygen atoms; ozone molecule; and different nitrogen and oxygen ions with different plasmochemical reactions between them. Simulations predicted the main regions of the dc glow discharges including cathode and anode sheath and plasma of negative glow, Faraday dark space and transition region. Gas heating plays an important role in shaping the discharge profiles. The results of experiments and simulations of short (without positive column) atmospheric pressure dc glow discharge in air are presented. We used metal steel electrodes with a gap of 5-100 microns. The experimental voltage-current characteristic's (VAC) have a constant or slightly increasing form at low gap. The most stable microdischarges were burning with a flat cathode and rounded anode, when the length of the discharge is automatically established near the minimum of the Paschen curve by changing their binding on the anode. In this case microdischarge was stable and it had growing VAC. For simulations we used 2D fluid model with kinetic description of electrons. We solved the balance equations for the vibrationally- and the electronically-excited states of a nitrogen and oxygen molecules; nitrogen

  11. Supershort avalanche electron beams and x-ray in high-pressure nanosecond discharges

    Science.gov (United States)

    Tarasenko, V. F.; Baksht, E. H.; Kostyrya, I. D.; Lomaev, M. I.; Rybka, D. V.

    2008-10-01

    The properties of a supershort avalanche electron beam (S AEB) and X-ray radiation produced using a nanosecond volume discharge are examined. An electron beam of the runaway electrons with amplitude of ~ 50 A has been obtained in air atmospheric pressure. It is reported that S AEB is formed in the angle above 2π sr. Three groups of the runaway electrons are formed in a gas diode under atmospheric air pressure, when nanosecond voltage pulses with amplitude of hundreds of kilovolts are applied. The electron beam has been generated behind a 45 μm thick AlBe foil in SF6 and Xe under the pressure of 2 arm, and in He under the pressure of about 12 atm. The paper gives the analysis of a generation mechanism of SAEB.

  12. Generation of subnanosecond electron beams in air at atmospheric pressure

    Science.gov (United States)

    Kostyrya, I. D.; Tarasenko, V. F.; Baksht, E. Kh.; Burachenko, A. G.; Lomaev, M. I.; Rybka, D. V.

    2009-11-01

    Optimum conditions for the generation of runaway electron beams with maximum current amplitudes and densities in nanosecond pulsed discharges in air at atmospheric pressure are determined. A supershort avalanche electron beam (SAEB) with a current amplitude of ˜30 A, a current density of ˜20 A/cm2, and a pulse full width at half maximum (FWHM) of ˜100 ps has been observed behind the output foil of an air-filled diode. It is shown that the position of the SAEB current maximum relative to the voltage pulse front exhibits a time shift that varies when the small-size collector is moved over the foil surface.

  13. Response of cyanobacteria to low atmospheric pressure

    Science.gov (United States)

    Qin, Lifeng; Yu, Qingni; Ai, Weidang; Tang, Yongkang; Ren, Jin; Guo, Shuangsheng

    2014-10-01

    Maintaining a low pressure environment in a controlled ecological life support system would reduce the technological complexity and resupply cost in the course of the construction of a future manned lunar base. To estimate the effect of a hypobaric environment in a lunar base on biological components, such as higher plants, microbes, and algae, cyanobacteria was used as the model by determining their response of growth, morphology, and physiology when exposed to half of standard atmospheric pressure for 16 days (brought back to standard atmospheric pressure 30 minutes every two days for sampling). The results indicated that the decrease of atmospheric pressure from 100 kPa to 50 kPa reduced the growth rates of Microcystis aeruginosa, Merismopedia sp., Anabaena sp. PCC 7120, and Anabaena flos-aquae. The ratio of carotenoid to chlorophyll a content in the four tested strains increased under low pressure conditions compared to ambient conditions, resulting from the decrease of chlorophyll a and the increase of carotenoid in the cells. Moreover, low pressure induced the reduction of the phycocyanin content in Microcystis aeruginosa, Anabaena sp. PCC 7120, and Anabaena flos-aquae. The result from the ultrastructure observed using SEM indicated that low pressure promoted the production of more extracellular polymeric substances (EPSs) compared to ambient conditions. The results implied that the low pressure environment of 50 kPa in a future lunar base would induce different effects on biological components in a CELSS, which must be considered during the course of designing a future lunar base. The results will be a reference for exploring the response of other biological components, such as plants, microbes, and animals, living in the life support system of a lunar base.

  14. "Politically-Incorrect" Electron Behavior in Low Pressure RF Discharges

    Science.gov (United States)

    Godyak, Valery; Kolobov, Vladimir

    1996-10-01

    The main interaction of plasma electrons with electromagnetic fields for bounded plasma of an rf discharge occurs in the vicinity of its boundaries (in the rf sheath of a capacitive rf discharge and in the skin layer of an inductive one). On the other hand, due to plasma inhomogeneity, a dc ambipolar field is always present in the bounded plasma. in low pressure discharges the ambipolar potential well captures low energy electrons within the discharge center while high energy electrons freely overcome the ambipolar potential and reach the plasma boundaries where heating takes place. Being segregated in space, low energy electrons are discriminated from participation in the heating process. When Coulomb interaction between low and high energy electron groups is weak, their temperatures appear to be essentially different ( a low energy peak on the EEDF). In this presentation we present theoretical and experimental evidence of such an apartheid in the low and high energy electron populations of the EEDF in rf discharge and we outline discharge conditions where such abnormal EEDF behavior is possible.

  15. EDITORIAL: Atmospheric pressure non-thermal plasmas for processing and other applications

    Science.gov (United States)

    Massines, Françoise

    2005-02-01

    Interest has grown over the past few years in applying atmospheric pressure plasmas to plasma processing for the benefits this can offer to existing and potential new processes, because they do not require expensive vacuum systems and batch processing. There have been considerable efforts to efficiently generate large volumes of homogeneous atmospheric pressure non-thermal plasmas to develop environmentally friendly alternatives for surface treatment, thin film coating, sterilization, decontamination, etc. Many interesting questions have arisen that are related to both fundamental and applied research in this field. Many concern the generation of a large volume discharge which remains stable and uniform at atmospheric pressure. At this pressure, depending on the experimental conditions, either streamer or Townsend breakdown may occur. They respectively lead to micro-discharges or to one large radius discharge, Townsend or glow. However, the complexity arises from the formation of large radius streamers due to avalanche coupling and from the constriction of the glow discharge due to too low a current. Another difficulty is to visually distinguish many micro-discharges from one large radius discharge. Other questions relate to key chemical reactions in the plasma and at the surface. Experimental characterization and modelling also need to be developed to answer these questions. This cluster collects up-to-date research results related to the understanding of different discharges working at atmospheric pressure and the application to polymer surface activation and thin film coating. It presents different solutions for generating and sustaining diffuse discharges at atmospheric pressure. DC, low-frequency and radio-frequency excitations are considered in noble gases, nitrogen or air. Two specific methods developed to understand the transition from Townsend to streamer breakdown are also presented. They are based on the cross-correlation spectroscopy and an electrical

  16. Diagnostics of atmospheric pressure capillary DBD oxygen plasma jet

    CERN Document Server

    Roy, N C; Pramanik, B K

    2015-01-01

    Atmospheric pressure capillary dielectric barrier oxygen discharge plasma jet is developed to generate non-thermal plasma using unipolar positive pulse power supply. Both optical and electrical techniques are used to investigate the characteristics of the produced plasma as function of applied voltage and gas flow rate. Analytical results obtained from the optical emission spectroscopic data reveal the gas temperature, rotational temperature, excitation temperature and electron density. Gas temperature and rotational temperature are found to decrease with increasing oxygen flow rate but increase linearly with applied voltage. It is exposed that the electron density is boosting up with enhanced applied voltage and oxygen flow rate, while the electron excitation temperature is reducing with rising oxygen flow rate. Electrical characterization demonstrates that the discharge frequency is falling with flow rate but increasing with voltage. The produced plasma is applied preliminarily to study the inactivation yie...

  17. One-step preparation of transparent superhydrophobic coatings using atmospheric arc discharge

    Science.gov (United States)

    Li, Jian; Huang, Zhengyong; Wang, Feipeng; Yan, Xinzhu; Wei, Yuan

    2015-08-01

    In this letter, we report a fast, simple, and single step approach to the preparation of transparent super-hydrophobic coatings on a copper conductor via atmosphere pressure arc discharges. The preparation procedures, hydrophobic characteristics, anti-pollution capability, and transparency of the super-hydrophobic coating are presented. A dual micro- and nano-scale hierarchical structure is observed on the super-hydrophobic coating with a water contact angle greater than 150°. The coating is, thus, capable of removing a significant amount of contaminants with a small quantity of water droplets. Attenuated total reflection Fourier transform infrared spectroscopy indicates that hydrophobic methyl groups exist on the surface of the coating. The surface roughness measurement results prove that the super-hydrophobic surface obeys the Cassie-Baxter model and its light scattering is very weak. Results demonstrate the conceptual feasibility of production of optically transparent super-hydrophobic coating by arc spraying of polymers under the atmospheric pressure.

  18. Research on Electron Density in DC Needle-Plate Corona Discharge at Atmospheric Pressure%直流大气压电晕放电电子密度的光谱研究

    Institute of Scientific and Technical Information of China (English)

    刘志强; 郭威; 刘涛涛; 武文硕; 刘淑敏

    2013-01-01

    Using needle-plate discharge device ,corona discharge experiment was done in the atmosphere .Through photo of spot size of light-emitting area ,the relationship between the voltage and thickness of corona layer was discussed .When the distance between tip and plate is fixed ,the thickness of corona layer increases with the increase in voltage ;when the voltage is fixed ,the thickness of corona layer decreases with the increase in the distance between tip and plate .As spectral intensity of N2 (C3Πu ) (337.1 nm)reflects high energy electron density ,it was measured with emission spectrometry .The results show that high ener-gy electron density is the biggest near the needle tip and the relationship between high energy electron density and voltage is basi-cally linear increasing .Fixing voltage ,high energy electron density decreases with the increase in the distance between tip and plate .When the voltage and the distance between tip and plate are fixed ,the high energy electron density increases with the de-crease in the curvature radius of needle tip .These results are of great importance for the study of plasma parameters of corona discharge .%利用自制针-板式放电装置,在大气中进行电晕放电实验。用发光区域照片光斑的大小,讨论了电晕层厚度与电源电压的关系。在相同针板间距下,电晕层厚度随着电压的升高而增大;在相同电压下,电晕层厚度随着针板间距的增大而减小。由于高能电子密度能够通过氮分子第二正带系337.1 nm的光谱强度大小反映,因此对氮分子第二正带系337.1 nm谱线的强度用发射光谱法进行了测量。实验结果发现在针尖附近高能电子密度最大,并且高能电子密度随电压的升高而增大;电压一定时,高能电子密度随针板间距的增大而减小。在针板间距和电源电压不变的情况下,高能电子密度随针尖曲率半径的减小而增大。

  19. Atmospheric pressure thermospray ionization using a heated microchip nebulizer.

    Science.gov (United States)

    Keski-Rahkonen, Pekka; Haapala, Markus; Saarela, Ville; Franssila, Sami; Kotiaho, Tapio; Kostiainen, Risto; Auriola, Seppo

    2009-10-30

    When a standard atmospheric pressure chemical ionization (APCI) or atmospheric pressure photoionization (APPI) ion source is used without applying the corona discharge or photoirradiation, atmospheric pressure thermospray ionization (APTSI) of various compounds can be achieved. Although largely ignored, this phenomenon has recently gained interest as an alternative ionization technique. In this study, this technique is performed for the first time on a miniaturized scale using a microchip nebulizer. Sample ionization with the presented microchip-APTSI (microAPTSI) is achieved by applying only heat and gas flow to a nebulizer chip, without any other methods to promote gas-phase ionization. To evaluate the performance of the described microAPTSI setup, ionization efficiency for a set of test compounds was monitored as the microchip positioning, temperature, nebulizer gas flow rate, sample solution composition, and solvent flow rate were varied. The microAPTSI mass spectra of the test compounds were also compared to those obtained with ESI and APCI. The microAPTSI produces ESI-like spectra with low background noise, favoring the formation of protonated or deprotonated molecules of compounds that are ionizable in solution. Multiple charging of peptides without in-source fragmentation was also observed. Unlike ESI, however, the microAPTSI source can tolerate the presence of mobile phase additives like trifluoroacetic acid (TFA) without significant ion suppression. The microAPTSI source can be used with standard mass spectrometer ion source hardware, being a unique alternative to the present interfacing techniques.

  20. Stimulation of wound healing by helium atmospheric pressure plasma treatment

    Energy Technology Data Exchange (ETDEWEB)

    Nastuta, Andrei Vasile; Topala, Ionut; Pohoata, Valentin; Popa, Gheorghe [Faculty of Physics, Alexandru Ioan Cuza University, Bd. Carol No. 11, 700506, Iasi (Romania); Grigoras, Constantin, E-mail: andrei.nastuta@uaic.ro [Physiopathology Department, Grigore T. Popa University of Medicine and Pharmacy, 700115, Iasi (Romania)

    2011-03-16

    New experiments using atmospheric pressure plasma have found large application in treatment of living cells or tissues, wound healing, cancerous cell apoptosis, blood coagulation on wounds, bone tissue modification, sterilization and decontamination. In this study an atmospheric pressure plasma jet generated using a cylindrical dielectric-barrier discharge was applied for treatment of burned wounds on Wistar rats' skin. The low temperature plasma jet works in helium and is driven by high voltage pulses. Oxygen and nitrogen based impurities are identified in the jet by emission spectroscopy. This paper analyses the natural epithelization of the rats' skin wounds and two methods of assisted epithelization, a classical one using polyurethane wound dressing and a new one using daily atmospheric pressure plasma treatment of wounds. Systemic and local medical data, such as haematological, biochemical and histological parameters, were monitored during entire period of study. Increased oxidative stress was observed for plasma treated wound. This result can be related to the presence in the plasma volume of active species, such as O and OH radicals. Both methods, wound dressing and plasma-assisted epithelization, provided positive medical results related to the recovery process of burned wounds. The dynamics of the skin regeneration process was modified: the epidermis re-epitelization was accelerated, while the recovery of superficial dermis was slowed down.

  1. Stimulation of wound healing by helium atmospheric pressure plasma treatment

    Science.gov (United States)

    Vasile Nastuta, Andrei; Topala, Ionut; Grigoras, Constantin; Pohoata, Valentin; Popa, Gheorghe

    2011-03-01

    New experiments using atmospheric pressure plasma have found large application in treatment of living cells or tissues, wound healing, cancerous cell apoptosis, blood coagulation on wounds, bone tissue modification, sterilization and decontamination. In this study an atmospheric pressure plasma jet generated using a cylindrical dielectric-barrier discharge was applied for treatment of burned wounds on Wistar rats' skin. The low temperature plasma jet works in helium and is driven by high voltage pulses. Oxygen and nitrogen based impurities are identified in the jet by emission spectroscopy. This paper analyses the natural epithelization of the rats' skin wounds and two methods of assisted epithelization, a classical one using polyurethane wound dressing and a new one using daily atmospheric pressure plasma treatment of wounds. Systemic and local medical data, such as haematological, biochemical and histological parameters, were monitored during entire period of study. Increased oxidative stress was observed for plasma treated wound. This result can be related to the presence in the plasma volume of active species, such as O and OH radicals. Both methods, wound dressing and plasma-assisted epithelization, provided positive medical results related to the recovery process of burned wounds. The dynamics of the skin regeneration process was modified: the epidermis re-epitelization was accelerated, while the recovery of superficial dermis was slowed down.

  2. Atmospheric pressure does not influence acute diverticular disease

    OpenAIRE

    Velayos, Benito; Pons-Renedo, Fernando; Feranández-Salazar, Luis; Muñoz, María Fe; Olmo, Lourdes del; Almaraz Gómez, Ana; Beltrán de Heredia, Juan; Hernández-González, José Manuel

    2013-01-01

    Producción Científica The article offers information on a study which examines the influence of atmospheric pressure on the development of acute diverticular disease. The value of atmospheric pressure and its daily trends in 2012 was collected to prove whether atmospheric pressure influence this disease by raising intra-diverticular pressure in days with higher atmospheric pressure. The study involved patients with acute diverticulitis who underwent computed tomography.

  3. A microwave pressure sounder. [for remote measurement of atmospheric pressure

    Science.gov (United States)

    Peckham, G. E.; Flower, D. A.

    1981-01-01

    A technique for the remote measurement of atmospheric surface pressure will be described. Such measurements could be made from a satellite in polar orbit and would cover many areas for which conventional meteorological data are not available. An active microwave instrument is used to measure the strength of return echoes from the ocean surface at a number of frequencies near the 60 GHz oxygen absorption band. Factors which affect the accuracy with which surface pressure can be deduced from these measurements will be discussed and an instrument designed to test the method by making measurements from an aircraft will be described.

  4. Bacteria Inactivation Using DBD Plasma Jet in Atmospheric Pressure Argon

    Institute of Scientific and Technical Information of China (English)

    XU Guimin; ZHANG Guanjun; SHI Xingmin; MA Yue; WANG Ning; LI Yuan

    2009-01-01

    A coaxial dielectric barrier discharge plasma jet Was designed,which can be operated in atmospheric pressure argon under an intermediate frequency sinusoidal resonant power supply,and an atmospheric pressure glow-like discharge Was achieved.Two kinds of typical bacteria,i.e.,the Staphylococcus aureus(S.aurens)and Escherichia coil(E.coil),were employed to study the bacterial inactivation mechanism by means of the non-thermal plasma.The killing log value (KLV)of S.aureus reached up to 5.38 with a treatment time of 90 s and that of E.coil up to 5.36 with 60 s,respectively.According to the argon emission spectra of the plasma jet and the scanning electron microscope (SEM) images of the two bacteria before and after the plasma treatment.it is concluded that the reactive species in the argon plasma played a major role in the bacterial inactivation,while the heat,electric field and UV photons had little effect.

  5. Atmospheric pressure plasma enhanced spatial ALD of silver

    Energy Technology Data Exchange (ETDEWEB)

    Bruele, Fieke J. van den, E-mail: Fieke.vandenBruele@tno.nl; Smets, Mireille; Illiberi, Andrea; Poodt, Paul [Holst Centre/TNO, High Tech Campus 31, 5656 AE Eindhoven (Netherlands); Creyghton, Yves [TNO, High Tech Campus 21, 5656 AE Eindhoven (Netherlands); Buskens, Pascal [TNO, Rondom 1, 5612 AP Eindhoven, The Netherlands and DWI Leibniz-Institut für Interaktive Materialien, Aachen (Germany); Roozeboom, Fred [TNO, High Tech Campus 21, 5656 AE Eindhoven, The Netherlands and Department of Applied Physics, Eindhoven University of Technology, 5600 MB Eindhoven (Netherlands)

    2015-01-15

    The authors have investigated the growth of thin silver films using a unique combination of atmospheric process elements: spatial atomic layer deposition and an atmospheric pressure surface dielectric barrier discharge plasma source. Silver films were grown on top of Si substrates with good purity as revealed by resistivity values as low as 18 μΩ cm and C- and F-levels below detection limits of energy dispersive x-ray analysis. The growth of the silver films starts through the nucleation of islands that subsequently coalesce. The authors show that the surface island morphology is dependent on surface diffusion, which can be controlled by temperature within the deposition temperature range of 100–120 °C.

  6. Modification of Composite Material Fillers by Atmospheric Plasma Discharge

    Directory of Open Access Journals (Sweden)

    David Tichy

    2013-01-01

    Full Text Available This work is focused on the observation of the influence of cold atmospheric dielectric barrier discharge (DBD on a modification of textile samples. The main objective of the experiment is to research wettability change of textiles modified by different exposure times and also the observation of the influence of a modification ageing effect. An ambient air was used as a working gas for DBD plasma. The wettability evaluation was carried out by a drop method, in which an imprint of the dropwas observed on the textile surface during various time intervals. An ageing effect of the modification was monitored within an interval of 28 days. Considerable increase of wettability of all modified samples has been proved. A fibre surface analysis was carried out by means of SEM.

  7. 大气压氦气冷等离子体射流放电-维数值模拟%One-dimensional Simulation of Helium Cold Plasma Jet Discharge at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    刘富成; 王德真

    2012-01-01

    为了明确大气压冷等离子体射流的形成机理,采用一维流体模型研究了针一板电极下大气压氦气冷等离子体射流中等离子体子弹的传播过程,得到并分析了等离子体子弹的空间结构。模拟结果表明,等离子体子弹实际上就是等离子体射流头部的电离区域,其传播过程即为该电离区域的推进过程。Penning电离可以为等离子体射流的传播提供种子电子。驱动电压的极性对等离子体射流的性质有着重要的影响,与正脉冲驱动等离子体射流不同,负脉冲驱动下的等离子体射流具有一个较窄的阴极位降区,且内部没有准中性区域。%In order to understand the formation mechanism of the atmospheric pressure cold plasma jet. Using one- dimensional simulation, we invesitgated plasma bullet propagatiofl in helium at atmospheric pressure cold plasma jet between needle-plane electrodes, and obtained a fine structure of plasma bullet. The simulation results show that the plasma bullet is treated as an ionization domain in the head of the plasma jet, and the advancement of this domain should be responsible for the propagation of the plasma bullet. Moreover, Penning ionization can provide the seed electrons ahead of the plasma jet. The polarity of applied voltage has a significant effect on the characteristics of plasma jets. In contrast to the positive plasma jet, there is a narrow cathode fall region, but no quasi neutral ionized channels exist in the plasma jet driven by a negative pulse.

  8. 大气压下横向磁场驱动的滑移弧放电中的重粒子温度测量%Measurement of heavy particle temperature in a gliding arc discharge driven by the transverse magnetic field at atmospheric pressure

    Institute of Scientific and Technical Information of China (English)

    李辉; 陶小平

    2013-01-01

    A generator of the gilding arc discharge, which is driven by the transverse magnetic field, is used to produce non-equilibrium plasma at atmospheric pressure. The spectra of N2 and OH radical are used to estimate the heavy particle temperature of the gliding arc plasma jet. Compared with the heavy particel temperature of the magnetically stabilized gliding arc discharge, the heavy particle temperature obtained from N2 spectrum is lower. Whereas, the heavy particle temperature obtained from OH radical spectrum is the same order as that of the magnetically stabilized gliding arc discharge, and is approximately in the range of 2400 K to 2700 K.%采用横向磁场驱动的滑移弧等离子体发生器产生非平衡、大气压下的等离子体.用氮分子谱和OH基谱来估算滑移弧等离子体射流中的重粒子温度.从实验数据的比较来看,从氮分子谱获得的重粒子温度相对较低,而从OH基谱获得的重粒子温度与磁稳滑移弧放电的重粒子温度比较接近,大约在2400~2700 K的范围内.

  9. Extreme ultraviolet spectroscopy of low pressure helium microwave driven discharges

    Science.gov (United States)

    Espinho, Susana; Felizardo, Edgar; Tatarova, Elena; Alves, Luis Lemos

    2016-09-01

    Surface wave driven discharges are reliable plasma sources that can produce high levels of vacuum and extreme ultraviolet radiation (VUV and EUV). The richness of the emission spectrum makes this type of discharge a possible alternative source in EUV/VUV radiation assisted applications. However, due to challenging experimental requirements, publications concerning EUV radiation emitted by microwave plasmas are scarce and a deeper understanding of the main mechanisms governing the emission of radiation in this spectral range is required. To this end, the EUV radiation emitted by helium microwave driven plasmas operating at 2.45 GHz has been studied for low pressure conditions. Spectral lines from excited helium atoms and ions were detected via emission spectroscopy in the EUV/VUV regions. Novel data concerning the spectral lines observed in the 23 - 33 nm wavelength range and their intensity behaviour with variation of the discharge operational conditions are presented. The intensity of all the spectral emissions strongly increases with the microwave power delivered to the plasma up to 400 W. Furthermore, the intensity of all the ion spectral emissions in the EUV range decreases by nearly one order of magnitude as the pressure was raised from 0.2 to 0.5 mbar. Work funded by FCT - Fundacao para a Ciencia e a Tecnologia, under Project UID/FIS/50010/2013 and grant SFRH/BD/52412/2013 (PD-F APPLAuSE).

  10. Atmospheric Pressure Plasma Processing for Polymer Adhesion: A Review

    DEFF Research Database (Denmark)

    Kusano, Yukihiro

    2014-01-01

    Atmospheric pressure plasma processing has attracted significant interests over decades due to its usefulness and a variety of applications. Adhesion improvement of polymer surfaces is among the most important applications of atmospheric pressure plasma treatment. Reflecting recent significant...... development of the atmospheric pressure plasma processing, this work presents its fundamental aspects, applications, and characterization techniques relevant to adhesion....

  11. New development of atmospheric pressure plasma polishing

    Institute of Scientific and Technical Information of China (English)

    Bo Wang; Jufan Zhang; Shen Dong

    2009-01-01

    Atmospheric pressure plasma polishing (APPP) is a precision machining technology used for manufacturing high quality optical surfaces. The changes of surface modulus and hardness after machining prove the distinct improvement of surface mechanical properties. The demonstrated decrease of surfacc residual stresses testifies the removal of the former deformation layer.And the surface topographies under atomic force microscope (AFM) and scanning electron microscope (SEM) indicate obvious amelioration of the surface status,showing that the 0.926-nm average surface roughness has been achieved.

  12. Dynamics of apokamp-type atmospheric pressure plasma jets

    Science.gov (United States)

    Sosnin, Eduard A.; Panarin, Victor A.; Skakun, Victor S.; Baksht, Evgeny Kh.; Tarasenko, Victor F.

    2017-02-01

    The paper describes a new discharge source of atmospheric pressure plasma jets (APPJs) in air with no gas supply through the discharge region. In this discharge mode, plasma jets develop from the bending point of a bright current channel between two electrodes and are therefore termed an apokamp (from Greek `off' and `bend'). The apokamp can represent single plasma jets of length up 6 cm or several jets, and the temperature of such jets can range from more than 1000 °C at their base to 100-250 °C at their tip. Apokamps are formed at maximum applied voltage of positive polarity, provided that the second electrode is capacitively decoupled with ground. According to high-speed photography with time resolution from several nanoseconds to several tens of nanoseconds, the apokamp consists of a set of plasma bullets moving with a velocity of 100-220 km/s, which excludes the convective mechanism of plasma decay. Estimates on a 100-ns scale show that the near-electrode zones and the zones from which apokamps develop are close in temperature.

  13. Atmospheric pressure ion focusing with a vortex stream.

    Science.gov (United States)

    Kolomiets, Yuri N; Pervukhin, Viktor V

    2011-09-30

    For successful operation of ionization analysis techniques an efficient sampling and sample ion transportation into an analytical path are required. This is of particular importance for atmospheric pressure ionization sources like corona discharge, electrospray, MALDI, ionization with radioactive isotopes ((3)H, (63)Ni) that produce nonuniform spatial distribution of sample ions. The available methods of sample ion focusing with electric fields are either efficient at reduced pressure (to 1 Torr) or feature high sample losses. In this paper we suggest to use a highly whirled gas stream for atmospheric pressure ion focusing. We use a (63)Ni radioactive source to produce an ionized bipolar sample at atmospheric pressure. It is shown by experiments that compared to an aspiration method a forced highly whirled vortex stream allows one to enhance the efficiency of remote ionized sample collection at distances equal to the vortex sampler diameter by an order of magnitude. With a vortex stream, a sixfold increase in the efficiency of the radial ionized sample collection has been obtained. It may be deduced that with the vortex stream remote sampling obtains a new feature which is characterized by a considerable enhancement of the efficiency of the ionized sample collection and can be called as a "gas-dynamic" ionized sample focusing. Considered is the effect of recombination losses of the ionized sample during the remote sampling thereof with the vortex sampler. Prospects for a practical implementation of the vortex sampler for solving the problems of the customs control over the smuggling of radioactive α and β sources are made based on the research results.

  14. Nanocapillary Atmospheric Pressure Plasma Jet: A Tool for Ultrafine Maskless Surface Modification at Atmospheric Pressure.

    Science.gov (United States)

    Motrescu, Iuliana; Nagatsu, Masaaki

    2016-05-18

    With respect to microsized surface functionalization techniques we proposed the use of a maskless, versatile, simple tool, represented by a nano- or microcapillary atmospheric pressure plasma jet for producing microsized controlled etching, chemical vapor deposition, and chemical modification patterns on polymeric surfaces. In this work we show the possibility of size-controlled surface amination, and we discuss it as a function of different processing parameters. Moreover, we prove the successful connection of labeled sugar chains on the functionalized microscale patterns, indicating the possibility to use ultrafine capillary atmospheric pressure plasma jets as versatile tools for biosensing, tissue engineering, and related biomedical applications.

  15. Nanosecond repetitively pulsed discharges in air at atmospheric pressure—the spark regime

    Science.gov (United States)

    Pai, David Z.; Lacoste, Deanna A.; Laux, Christophe O.

    2010-12-01

    Nanosecond repetitively pulsed (NRP) spark discharges have been studied in atmospheric pressure air preheated to 1000 K. Measurements of spark initiation and stability, plasma dynamics, gas temperature and current-voltage characteristics of the spark regime are presented. Using 10 ns pulses applied repetitively at 30 kHz, we find that 2-400 pulses are required to initiate the spark, depending on the applied voltage. Furthermore, about 30-50 pulses are required for the spark discharge to reach steady state, following initiation. Based on space- and time-resolved optical emission spectroscopy, the spark discharge in steady state is found to ignite homogeneously in the discharge gap, without evidence of an initial streamer. Using measured emission from the N2 (C-B) 0-0 band, it is found that the gas temperature rises by several thousand Kelvin in the span of about 30 ns following the application of the high-voltage pulse. Current-voltage measurements show that up to 20-40 A of conduction current is generated, which corresponds to an electron number density of up to 1015 cm-3 towards the end of the high-voltage pulse. The discharge dynamics, gas temperature and electron number density are consistent with a streamer-less spark that develops homogeneously through avalanche ionization in volume. This occurs because the pre-ionization electron number density of about 1011 cm-3 produced by the high frequency train of pulses is above the critical density for streamer-less discharge development, which is shown to be about 108 cm-3.

  16. Dielectric Barrier Discharge Air Plasma at Atmospheric Pressure Induced Oxidative Stress in Saccharomyces cerevisiae%大气压介质阻挡放电空气等离子体引起酿酒酵母氧化应激的研究

    Institute of Scientific and Technical Information of China (English)

    陈慧黠; 修志龙; 白凤武

    2013-01-01

    在产生等离子体的过程中会同时产生大量的自由基和准分子.作者研究了经大气压介质阻挡放电(dielectric barrier discharge,DBD)空气等离子体处理后酿酒酵母(Saccharomyce cerevisiae)细胞的氧化应激,发现酿酒酵母细胞在DBD空气等离子体处理后,胞内总抗氧化能力和谷胱甘肽还原酶活力都不同程度被激活,丙二醛含量也随处理时间的延长不断增加,胞内活性氧(reactive oxygen species,ROS)含量明显增加,细胞周期也出现严重的G1期阻滞,说明等离子体产生的大量自由基可引发酵母细胞的氧化应激.%Atmospheric pressure dielectric barrier discharge (DBD) air plasma is a source of reactive species,such as OH*,H*,O*,H2O2,O3,etc.The oxidative stress in Saccharomyces cerevisiae which was exposed to DBD air plasma at atmospheric pressure was studied.It was showed that the intracellular total antioxidant capability (T-AOC) and activity of glutathione reductase (GR) were activated,malondialdehyde (MDA) content increased in a treatment time-dependent manner,intracellular reactive oxygen species (ROS) content increased,and cell cycle arrested in G1 phase significantly.It was proved that oxidative stress was induced in S.cerevisiae when the cells were exposed to DBD air plasma.

  17. Potential Industrial Applications of the One Atmosphere Uniform Glow Discharge Plasma (OAUGDP) Operating in Ambient Air

    Science.gov (United States)

    Reece Roth, J.

    2004-11-01

    The majority of industrial plasma processing with glow discharges has been conducted at pressures below 10 torr. This tends to limit applications to high value workpieces as a result of the high capital cost of vacuum systems and the production constraints of batch processing. It has long been recognized that glow discharge plasmas would play a much larger industrial role if they could be generated at one atmosphere. The One Atmosphere Uniform Glow Discharge Plasma (OAUGDP), developed at the University of Tennessee's Plasma Sciences Laboratory, is a non-thermal RF plasma operating on displacement currents with the time-resolved characteristics of a classical low pressure DC normal glow discharge. As a glow discharge, the OAUGDP operates with maximum electrical efficiency at the Stoletow point, where the energy input per ion-electron pair is a minimum [1, 2]. Several interdisciplinary teams have investigated potential applications of the OAUGDP. These teams included collaborators from the UTK Textiles and Nonwovens Development Center (TANDEC), and the Departments of Electrical and Computer Engineering, Microbiology, and Food Science and Technology, as well as the NASA Langley Research Center. The potential applications of the OAUGDP have all been at one atmosphere and room temperature, using air as the working gas. These applications include sterilizing medical and dental equipment; sterilizable air filters to deal with the "sick building syndrome"; removal of soot from Diesel engine exhaust; subsonic plasma aerodynamic effects, including flow re-attachment to airfoils and boundary layer modification; electrohydrodynamic (EDH) flow control of working gases; increasing the surface energy of materials; improving the adhesion of paints and electroplated layers: improving the wettability and wickability of fabrics; stripping of photoresist; and plasma deposition and directional etching of potential microelectronic relevance. [1] J. R. Roth, Industrial Plasma Engineering

  18. Formation of the high-intensity microsecond flow of electrons in the channel of high pressure arc discharge

    CERN Document Server

    Volkolupov, Yu Ya; Kolyada, Y E; Fedun, V I; Onishchenko, I N

    2000-01-01

    The possibility of microsecond duration powerful electron flows formation in the channel of high current arc discharge at atmosphere pressure has been experimentally demonstrated. The flow of electrons is formed at applying the high voltage pulse to the plasma source after plasma ejection and the pressure decreasing. Because the acceleration by the electric field prevails over the friction force due to collisions the conditions for arising of running electrons are fulfilled.

  19. Atmospheric pressure plasma treatment of glass fibre composite for adhesion improvement

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Mortensen, H.; Stenum, Bjarne

    2007-01-01

    Glass-fibre-reinforced polyester composite plates were treated with an atmospheric pressure dielectric barrier discharge. Synthetic air was used as the treatment gas. The water contact angle dropped markedly from 84 to 22° after a 2-s treatment, and decreased to 0° when the composite plates were...

  20. High-Pressure Plasma Deposition of a-C:H Films by Dielectric-Barrier Discharge

    Institute of Scientific and Technical Information of China (English)

    刘昌俊; 李阳; 杜海燕; 艾宝都

    2003-01-01

    The fabrication of a-C:H films from methane has been performed using dielectric-barrier discharges at atmospheric pressure. The effect of combined-feed gas, such as carbon dioxide,carbon monoxide or acetylene on the formation of a-C:H films has been investigated. It hasbeen demonstrated that the addition of carbon monoxide or acetylene into methane leads to aremarkable improvement in the fabrication of a-C:H films. The characterization of carbon filmobtained has been conducted using FT-IR, Raman and SEM.

  1. Response of cyanobacteria to low atmosphere pressure

    Science.gov (United States)

    Qin, Lifeng; Ai, Weidang; Guo, Shuangsheng; Tang, Yongkang; Yu, Qingni; Shen, Yunze; Ren, Jin

    Maintaining a low pressure environment would reduce the technological complexity and constructed cost of future lunar base. To estimate the effect of hypobaric of controlled ecological life support system in lunar base on terrestrial life, cyanobacteria was used as the model to exam the response of growth, morphology, physiology to it. The decrease of atmosphere pressure from 100 KPa to 50 KPa reducing the growth rates of Microcystis aeruginosa, Merismopedia.sp, Anabaena sp. PCC 7120, Anabaena Hos-aquae, the chlorophyll a content in Microcystis aeruginosa, Merismopedia.sp, Anabaena Hos-aquae, the carotenoid content in Microcystis aeruginosa, Merismopedia.sp and Anabaena sp. PCC 7120, the phycocyanin content in Microcystis aeruginosa. This study explored the biological characteristics of the cyanobacteria under low pressure condition, which aimed at understanding the response of the earth's life to environment for the future moon base, the results enrich the research contents of the lunar biology and may be referred for the research of other terrestrial life, such as human, plant, microbe and animal living in life support system of lunar base.

  2. Synthesis of silicon nanocones using rf microplasma at atmospheric pressure

    Science.gov (United States)

    Shirai, H.; Kobayashi, T.; Hasegawa, Y.

    2005-10-01

    We report the synthesis of silicon nanocones using the rf microplasma discharge at atmospheric pressure. The products formed underneath the tube electrode on Fe-coated crystalline silicon were constituted mainly of silicon and silicon oxide despite the use of a methane-argon mixture. Carbon nanotubes and silicon nanowires were also formed around the silicon nanocones. The number density and average size of silicon nanocones increased with the plasma exposure time accompanied by the enlargement of their surface distribution. The growth mechanism of silicon nanocones is discussed in terms of the catalytic growth via diffusion of silicon with nanocrystalline Si particle through FeSix nanoclusters, and enhanced Si oxidation by the plasma heating.

  3. Polymerization of acrylic acid using atmospheric pressure DBD plasma jet

    Science.gov (United States)

    Bashir, M.; Bashir, S.

    2016-08-01

    In this paper polymerization of acrylic acid was performed using non thermal atmospheric pressure plasma jet technology. The goal of this study is to deposit organic functional coatings for biomedical applications using a low cost and rapid growth rate plasma jet technique. The monomer solution of acrylic acid was vaporized and then fed into the argon plasma for coating. The discharge was powered using a laboratory made power supply operating with sinusoidal voltage signals at a frequency of 10 kHz. The optical emission spectra were collected in order to get insight into the plasma chemistry during deposition process. The coatings were characterized using Fourier transform infrared spectroscopy, atomic force microscopy and growth rates analysis. A high retention of carboxylic functional groups of the monomer was observed at the surface deposited using this low power technique.

  4. Destruction mechanisms for formaldehyde in atmospheric pressure low temperature plasmas

    Science.gov (United States)

    Storch, Daniel G.; Kushner, Mark J.

    1993-01-01

    Formaldehyde (CH2O) is a common pollutant of indoor air in residences and commercial buildings. The removal of CH2O from atmospheric pressure gas streams (N2/O2/H2O/CH2O) using plasmas generated by a dielectric barrier discharge has been theoretically investigated with the goal of cleansing indoor air. The model consists of a full accounting of the electron, ion, and neutral chemical kinetics in contaminated humid air. We find that the destruction of CH2O results dominantly from chemical attack by OH and O radicals, with the primary end products being CO and H2O. The predicted destruction rates for CH2O are typically 2-8 ppm/(mJ cm-3) (parts per million of CH2O in air/energy deposition). The elimination of the unwanted byproducts, CO and NO, using a platinum catalyst is discussed.

  5. Ultrafast laser-collision-induced fluorescence in atmospheric pressure plasma

    Science.gov (United States)

    Barnat, E. V.; Fierro, A.

    2017-04-01

    The implementation and demonstration of laser-collision-induced fluorescence (LCIF) generated in atmospheric pressure helium environments is presented in this communication. As collision times are observed to be fast (~10 ns), ultrashort pulse laser excitation (<100 fs) of the 23S to 33P (388.9 nm) is utilized to initiate the LCIF process. Both neutral-induced and electron-induced components of the LCIF are observed in the helium afterglow plasma as the reduced electric field (E/N) is tuned from  <0.1 Td to over 5 Td. Under the discharge conditions presented in this study (640 Torr He), the lower limit of electron density detection is ~1012 e cm‑3. The spatial profiles of the 23S helium metastable and electrons are presented as functions of E/N to demonstrate the spatial resolving capabilities of the LCIF method.

  6. Plasma reactor for deposition of carbon nanowalls at atmospheric pressure

    Science.gov (United States)

    Dimitrov, Zh; Mitev, D.; Kiss'ovski, Zh

    2016-10-01

    In this study a novel plasma reactor for deposition of carbon nanowalls at atmospheric pressure is constructed and characterized. A low power microwave discharge is used as a plasma source and working gas of Ar/H2/CH4 gas mixture. The substrate is heated by plasma flame and its temperature is in the range 600-700 C. The chemical composition of the plasma and the gas mixture effect on the concentration of the various particles in the plasma is investigated by optical emission spectroscopy. The emission spectrum of the plasma jet in Ar/H2/CH4 mixture shows the presence of carbon (Swan band) and an intensive line of CH (388 nm), which are necessary species for deposition of carbon nanostructures. Additional voltage in the range from -20 V to -100 V is applied in order to ensure the vertical growth of graphene walls. Results of deposited carbon nanostructures on metal substrate are shown.

  7. [Spectral diagnosis of plasma jet at atmospheric pressure].

    Science.gov (United States)

    Li, Chi; Tang, Xiao-liang; Qiu, Gao

    2008-12-01

    A new approach to surface modification of materials using dielectric barrier discharge (DBD) plasma jet at atmospheric pressure is presented in the present paper. The emission spectral lines of argon plasma jet at atmospheric pressure were recorded by the grating spectrograph HR2000 and computer software. The argon plasma emission spectra, ranging from 300nm to 1000 nm, were measured at different applied voltage. Compared to air plasma emission spectra under the same circumstance, it is shown that all of the spectral lines are attributed to neutral argon atoms. The spectral lines 763.51 and 772.42 nm were chosen to estimate the electron excitation temperature. The purpose of the study is to research the relationship between the applied voltage and temperature to control the process of materials' surface modification promptly. The results show that electron excitation temperature is in the range of 0.1-0.5 eV and increases with increasing applied voltage. In the process of surface modification under the plasma jet, the infrared radiation thermometer was used to measure the material surface temperature under the plasma jet. The results show that the material surface temperature is in the range of 50-100 degrees C and it also increases with increasing applied voltage. Because the material surface was under the plasma jet and its temperature was decided by the plasma, and the material surface temperature increased with increasing the macro-temperature of plasma jet, the relationship between the surface temperature and applied voltage indicates the relationship between the macro-temperature of the plasma jet and the applied voltage approximately. The experimental results indicate that DBD plasma jet at atmospheric pressure is a new approach to improving the quality of materials' surface modification, and spectral diagnosis has proved to be a kind of workable method by choosing suitable applied voltage.

  8. Microwave heating systems for atmospheric pressure: Nonequilibrium plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Guest, G.E.; Dandl, R.A. (AMPC, Inc., Carlsbad, CA (USA))

    1989-03-01

    Nonequilibrium plasma-chemical processing is attracting increasing interest because of the possibility of creating mixtures of active species that would not be available in thermal equilibrium. For significant throughput of reactants it would be advantageous to create nonequilibrium plasmas in large volumes of atmospheric-pressure mixtures of gases. Techniques for accomplishing this are very limited at present. Here they describe a novel microwave approach to creating nonequilibrium plasmas in large volumes of atmospheric-pressure gases using pulses of microwave radiation with very high peak power that are focused by quasi-optical techniques at one or more points in the interior of the reaction chamber. A new type of microwave source, the Plasma Electron Microwave Source (PEMS), is able to produce the require power levels by storing cw microwave power in a mirror-confined, relativistic-electron plasma and periodically transforming a fraction of that stored energy into intense microwave pulses. This approach avoids many of the limitations inherent in resonant cavity approaches and is expected to permit ultrahigh purity discharges to be produced.

  9. A Novel Atmospheric Pressure Plasma Fluidized Bed and Its Application in Mutation of Plant Seeds

    Institute of Scientific and Technical Information of China (English)

    CHEN Guang-Liang; WANG Zhen-Quan; HAN Er-Li; FU Ya-Bo; YANG Si-Ze; FAN Song-Hua; LI Chun-Ling; GU Wei-Chao; FENG Wen-Ran; ZHANG Gu-Ling; WANG Jiu-Li; Latif K.; ZHANG Shu-Gen

    2005-01-01

    @@ An atmospheric pressure plasma fluidized bed (APPFB) is designed to generate plasma using a dielectric barrier discharge (DBD) with one liquid electrode. In the APPFB system, the physical properties of DBD discharge and its application in plant-seed mutating are studied fundamentally. The results show that the generated plasma is a typical glow discharge free from filament and arc plasma, and the macro-temperature of the plasma fluidized bed is nearly at room temperature. There are no obvious changes in the pimientos when their seeds are treated by APPFB, but great changes are found for coxcombs.

  10. Longitudinal discharge pumped low-pressure XeCl laser

    Science.gov (United States)

    Fedorov, A. I.

    2013-10-01

    We have studied output parameters of a XeCl and a N2 laser pumped by a longitudinal discharge with automatic spark UV preionisation. The output parameters of a low-pressure (30 Torr) XeCl laser operating with Ar, Ne and He as buffer gases or with no buffer gas have been optimised for the first time. The laser generated 5-ns FWHM pulses with an average power of 0.5 mW and output energy of 0.15 mJ. Under longitudinal discharge pumping, an output energy per unit volume of 1.8 J L-1 atm-1 was reached using helium as a buffer gas. With argon-containing and buffer-free mixtures, it was 1.5 J L-1 atm-1. The N2 laser generated 2.5-ns FWHM pulses with an average power of 0.35 mW and output energy of 0.05 mJ.

  11. Atmospheric Pressure non-thermal plasmas for surface treatment of polymer films

    Science.gov (United States)

    Huang, Hsiao-Feng; Wen, Chun-Hsiang; Wei, Hsiao-Kuan; Kou, Chwung-Shan

    2006-10-01

    Interest has grown over the past few years in applying atmospheric pressure non-thermal plasmas to surface treatment. In this work, we used an asymmetric glow dielectric-barrier discharge (GDBD), at atmospheric pressure in nitrogen, to improve the surface hydrophilicity of three kinds of polymer films, biaxially oriented polypropylene (BOPP), polyimide (PI), and triacetyl cellulose (TAC). This set-up consists of two asymmetric electrodes covered by dielectrics. And to prevent the filamentary discharge occur, the frequency, gas flow rate and uniformity of gas flow distribution should be carefully controlled. The discharge performance is monitored through an oscilloscope, which is connected to a high voltage probe and a current monitor. The physical and chemical properties of polymer surfaces before and after GDBD treatment were analyzed via water contact angle (CA) measurements, atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS) techniques.

  12. Electrical and optical properties of Ar/NH3 atmospheric pressure plasma jet

    Science.gov (United States)

    Chang, Zheng-Shi; Yao, Cong-Wei; Chen, Si-Le; Zhang, Guan-Jun

    2016-09-01

    Inspired by the Penning effect, we obtain a glow-like plasma jet by mixing ammonia (NH3) into argon (Ar) gas under atmospheric pressure. The basic electrical and optical properties of an atmospheric pressure plasma jet (APPJ) are investigated. It can be seen that the discharge mode transforms from filamentary to glow-like when a little ammonia is added into the pure argon. The electrical and optical analyses contribute to the explanation of this phenomenon. The discharge mode, power, and current density are analyzed to understand the electrical behavior of the APPJ. Meanwhile, the discharge images, APPJ's length, and the components of plasma are also obtained to express its optical characteristics. Finally, we diagnose several parameters, such as gas temperature, electron temperature, and density, as well as the density number of metastable argon atoms of Ar/NH3 APPJ to help judge the usability in its applications.

  13. Atmospheric pressure variations and abdominal aortic aneurysm rupture.

    LENUS (Irish Health Repository)

    Killeen, S D

    2012-02-03

    BACKGROUND: Ruptured abdominal aortic aneurysm (RAAA) presents with increased frequency in the winter and spring months. Seasonal changes in atmospheric pressure mirrors this pattern. AIM: To establish if there was a seasonal variation in the occurrence of RAAA and to determine if there was any association with atmospheric pressure changes. METHODS: A retrospective cohort-based study was performed. Daily atmospheric pressure readings for the region were obtained. RESULTS: There was a statistically significant monthly variation in RAAA presentation with 107 cases (52.5%) occurring from November to March. The monthly number of RAAA and the mean atmospheric pressure in the previous month were inversely related (r = -0.752, r (2) = 0.566, P = 0.03), and there was significantly greater daily atmospheric pressure variability on days when patients with RAAA were admitted. CONCLUSION: These findings suggest a relationship between atmospheric pressure and RAAA.

  14. Atmospheric pressure plasma assisted calcination of composite submicron fibers

    Science.gov (United States)

    Medvecká, Veronika; Kováčik, Dušan; Tučeková, Zlata; Zahoranová, Anna; Černák, Mirko

    2016-08-01

    The plasma assisted calcination of composite organic/inorganic submicron fibers for the preparation of inorganic fibers in submicron scale was studied. Aluminium butoxide/polyvinylpyrrolidone fibers prepared by electrospinning were treated using low-temperature plasma generated by special type of dielectric barrier discharge, so called diffuse coplanar surface barrier discharge (DCSBD) at atmospheric pressure in ambient air, synthetic air, oxygen and nitrogen. Effect of plasma treatment on base polymer removal was investigated by using Attenuated total reflectance - Fourier transform infrared (ATR-FTIR) spectroscopy. Influence of working gas on the base polymer reduction was studied by energy-dispersive X-ray spectroscopy (EDX) and CHNS elemental analysis. Changes in fibers morphology were observed by scanning electron microscopy (SEM). High efficiency of organic template removal without any degradation of fibers was observed after plasma treatment in ambient air. Due to the low-temperature approach and short exposure time, the plasma assisted calcination is a promising alternative to the conventional thermal calcination. Contribution to the topical issue "6th Central European Symposium on Plasma Chemistry (CESPC-6)", edited by Nicolas Gherardi, Ester Marotta and Cristina Paradisi

  15. A New Atmospheric Pressure Microwave Plasma Source (APMPS)

    Institute of Scientific and Technical Information of China (English)

    LIU Liang; ZHANG Guixin; LI Yinan; ZHU Zhijie; WANG Xinxin; LUO Chengmu

    2008-01-01

    An atmospheric pressure microwave plasma source (APMPS) that can generate a large volume of plasma at an atmospheric pressure has been developed at Tsinghua University. This paper presents the design of this APMPS, the theoretical consideration of microwave plasma ignition and the simulation results, including the distributions of the electric field and power density inside the cavity as well as the accuracy of the simulation results. In addition, a method of producing an atmospheric pressure microwave plasma and some relevant observations of the plasma are also provided. It. is expected that this research would be useful for further developing atmospheric pressure microwave plasma sources and expanding the scope of their applications.

  16. Super-Atmospheric Pressure Ion Sources: Application and Coupling to API Mass Spectrometer.

    Science.gov (United States)

    Chen, Lee Chuin; Rahman, Md Matiur; Hiraoka, Kenzo

    2014-01-01

    Pressurizing the ionization source to gas pressure greater than atmospheric pressure is a new tactic aimed at further improving the performance of atmospheric pressure ionization (API) sources. In principle, all API sources, such as ESI, APCI and AP-MALDI, can be operated at pressure higher than 1 atm if suitable vacuum interface is available. The gas pressure in the ion source can have different role for different ionization. For example, in the case of ESI, stable electrospray could be sustained for high surface tension liquid (e.g., pure water) under super-atmospheric pressure, owing to the absence of electric discharge. Even for nanoESI, which is known to work well with aqueous solution, its stability and sensitivity were found to be enhanced, particularly in the negative mode when the ion source was pressurized. For the gas phase ionization like APCI, measurement of gaseous compound also showed an increase in ion intensity with the ion source pressure until an optimum pressure at around 4-5 atm. The enhancement was due to the increased collision frequency among reactant ion and analyte that promoted the ion/molecule reaction and a higher intake rate of gas to the mass spectrometer. Because the design of vacuum interface for API instrument is based on the upstream pressure of 1 atm, some coupling aspects need to be considered when connecting the high pressure ion source to the mass spectrometer. Several coupling strategies are discussed in this paper.

  17. Improving Hydrophobicity of Glass Surface Using Dielectric Barrier Discharge Treatment in Atmospheric Air

    Institute of Scientific and Technical Information of China (English)

    FANG Zhi; QIU Yuchang; WANG Hui; E. KUFFEL

    2007-01-01

    Non-thermal plasmas under atmospheric pressure are of great interest in industrial applications, especially in material surface treatment. In this paper, the treatment of a glass surface for improving hydrophobicity using the non-thermal plasma generated by dielectric barrier discharge (DBD) at atmospheric pressure in ambient air is conducted, and the surface properties of the glass before and after the DBD treatment are studied by using contact angle measurement, surface resistance measurement and wet flashover voltage tests. The effects of the applied voltage and time duration of DBD on the surface modification are studied, and the optimal conditions for the treatment are obtained. It is found that a layer of hydrophobic coating is formed on the glass surface after spraying a thin layer of silicone oil and undergoing the DBD treatment, and the improvement of hydrophobicity depends on DBD voltage and treating time. It seems that there exists an optimum treating time for a certain applied voltage of DBD during the surface treatment. The test results of thermal aging and chemical aging show that the hydrophobic layer has quite stable characteristics. The interaction mechanism between the DBD plasma and the glass surface is discussed. It is concluded that CH3 and large molecule radicals can react with the radicals in the glass surface to replace OH, and the hydrophobicity of the glass surface is improved accordingly.

  18. Electrode Configurations in Atmospheric Pressure Plasma Jets

    Science.gov (United States)

    Lietz, Amanda M.; Kushner, Mark J.

    2016-09-01

    Atmospheric pressure plasma jets (APPJs) are being studied for emerging medical applications including cancer treatment and wound healing. APPJs typically consist of a dielectric tube through which a rare gas flows, sometimes with an O2 or H2O impurity. In this paper, we present results from a computational study of APPJs using nonPDPSIM, a 2-D plasma hydrodynamics model, with the goal of providing insights on how the placement of electrodes can influence the production of reactive species. Gas consisting of He/O2 = 99.5/0.5 is flowed through a capillary tube at 2 slpm into humid air, and a pulsed DC voltage is applied. An APPJ with two external ring electrodes will be compared with one having a powered electrode inside and a ground electrode on the outside. The consequences on ionization wave propagation and the production of reactive oxygen and nitrogen species (RONS) will be discussed. Changing the electrode configuration can concentrate the power deposition in volumes having different gas composition, resulting in different RONS production. An internal electrode can result in increased production of NOx and HNOx by increasing propagation of the ionization wave through the He dominated plume to outside of the tube where humid air is diffusing into the plume. Work supported by US DOE Office of Fusion Energy Science and the National Science Foundation.

  19. Atmospheric pressure changes and unexplained variability in INR measurements.

    Science.gov (United States)

    Ernst, Michael E; Shaw, Robert F; Ernst, Erika J; Alexander, Bruce; Kaboli, Peter J

    2009-06-01

    Changes in atmospheric pressure may influence hepatic blood flow and drug metabolism. Anecdotal experience suggests international normalized ratio (INR) variability may be temporally related to significant atmospheric pressure changes. We investigated this potential association in a large sample of patients with multiple INRs. This is a retrospective review of outpatient anticoagulation records from the Iowa City Veteran's Affairs Medical Center and affiliated outpatient clinics from October 1999 to July 2007. All patients, receiving at least one prescription for warfarin and INR at least 30 days or more from the date of the first warfarin prescription, were identified. INRs during periods of hospitalization and vitamin K use were excluded. Proximity analysis using geocoding of ZIP codes of identified patients to the nearest National Oceanic and Atmospheric Administration station was performed to assign atmospheric pressure with INR. Spearman's Rho and Pearson's correlation were used to evaluate atmospheric pressure and INR. Unique patients (1441) with 45 187 INRs were analyzed. When limited to nontherapeutic INRs following a previously therapeutic INR (1121 unique patients/5256 INRs), a small but clinically insignificant association between delta INR and delta atmospheric pressure was observed (r = -0.025; P = 0.038), but not for actual INR and atmospheric pressure (P = 0.06). Delta atmospheric pressure demonstrated greater variation during fall/winter months compared with spring/summer (0.23 vs. 0.15 inHg; P atmospheric pressure changes and INR variability. These findings refute the anecdotal experience seen in our anticoagulation clinic.

  20. Decontamination of a rotating cutting tool during operation by means of atmospheric pressure plasmas

    DEFF Research Database (Denmark)

    Leipold, Frank; Kusano, Yukihiro; Hansen, F.

    2010-01-01

    The decontamination of a rotating cutting tool used for slicing in the meat industry by means of atmospheric pressure plasmas is investigated. The target is Listeria monocytogenes, a bacterium which causes listeriosis and can be found in plants and food. The non-pathogenic species, Listeria innocua......, is used for the experiments. A rotating knife was inoculated with L. innocua. The surface of the rotating knife was partly exposed to an atmospheric pressure dielectric barrier discharge operated in air, where the knife itself served as a ground electrode. The rotation of the knife ensures a treatment...

  1. Study of the impact of photoionization on negative and positive needle-plane corona discharge in atmospheric air

    Science.gov (United States)

    Dordizadeh, Peyman; Adamiak, Kazimierz; Castle, G. S. Peter

    2016-12-01

    A 2D axisymmetric model of the atmospheric pressure needle-plane corona discharge incorporating the photoionization phenomenon is presented in this paper. The photoionization model was developed using a three-term exponential approximation based on a model suggested by Bourdon et al. The coefficients of the photoionization model were tuned by reproducing the results of a positive corona discharge and comparing them with the experimental data published previously in the literature. In fact, this photoionization model is an essential module for studying a self-sustained positive corona discharge. Incorporating the photoionization phenomenon in the numerical model for the negative corona discharge causes an average of 5% increase in both the frequency and the DC current of the discharge. The relative importance of the photoionization in both positive and negative coronas was put in a quantitative frame by introducing the ratio of the integral of the impact ionization source term (IIS) divided by the Integral of the photoionization source term (IPS). With the help of this ratio and the spatial distribution of the two source terms, the minor role played by the photoionization source term for the negative discharge is justified. In the case of the positive discharge, the vital importance of the photoionization for sustaining the discharge is explained. Moreover, for the negative corona discharge, comparison of the ratio of the secondary emitted electrons (SEE) from the cathode surface divided by the IPS, at different instants of the formation of a Trichel pulse was found to be beneficial for the purpose of evaluating the relative importance of the photoionization. It is concluded that, although SEE on the rising edge of the Trichel pulse is smaller than the IPS since the injected electrons from the cathode surface are generated in the area with the strongest electric field, they have a greater contribution to the discharge current.

  2. Super-atmospheric pressure ionization mass spectrometry and its application to ultrafast online protein digestion analysis.

    Science.gov (United States)

    Chen, Lee Chuin; Ninomiya, Satoshi; Hiraoka, Kenzo

    2016-06-01

    Ion source pressure plays a significant role in the process of ionization and the subsequent ion transmission inside a mass spectrometer. Pressurizing the ion source to a gas pressure greater than atmospheric pressure is a relatively new approach that aims to further improve the performance of atmospheric pressure ionization sources. For example, under a super-atmospheric pressure environment, a stable electrospray can be sustained for liquid with high surface tension such as pure water, because of the suppression of electric discharge. Even for nano-electrospray ionization (nano-ESI), which is known to work with aqueous solution, its stability and sensitivity can also be enhanced, particularly in the negative mode when the ion source is pressurized. A brief review on the development of super-atmospheric pressure ion sources, including high-pressure electrospray, field desorption and superheated ESI, and the strategies to interface these ion sources to a mass spectrometer will be given. Using a recent ESI prototype with an operating temperature at 220 °C under 27 atm, we also demonstrate that it is possible to achieve an online Asp-specific protein digestion analysis in which the whole processes of digestion, ionization and MS acquisition could be completed on the order of a few seconds. This method is fast, and the reaction can even be monitored on a near-real-time basis. Copyright © 2016 John Wiley & Sons, Ltd.

  3. The effect of atmospheric pressure on ventricular assist device output.

    Science.gov (United States)

    Goto, Takeshi; Sato, Masaharu; Yamazaki, Akio; Fukuda, Wakako; Watanabe, Ken-Ichi; Daitoku, Kazuyuki; Minakawa, Masahito; Fukui, Kozo; Suzuki, Yasuyuki; Fukuda, Ikuo

    2012-03-01

    The effect of cabin pressure change on the respiratory system during flight is well documented in the literature, but how the change in atmospheric pressure affects ventricular assist device (VAD) output flow has not been studied yet. The purpose of our study was to evaluate the change in VAD output using a mock circulatory system in a low-pressure chamber mimicking high altitude. Changes in output and driving pressure were measured during decompression from 1.0 to 0.7 atm and pressurization from 0.7 to 1.0 atm. Two driving systems were evaluated: the VCT system and the Mobart system. In the VCT system, output and driving pressure remained the same during decompression and pressurization. In the Mobart system, the output decreased as the atmospheric pressure dropped and recovered during pressurization. The lowest output was observed at 0.7 atm, which was 80% of the baseline driven by the Mobart system. Under a practical cabin pressure of 0.8 atm, the output driven by the Mobart system was 90% of the baseline. In the Mobart system, the output decreased as the atmospheric pressure dropped, and recovered during pressurization. However, the decrease in output was slight. In an environment where the atmospheric pressure changes, it is necessary to monitor the diaphragmatic motion of the blood pump and the driving air pressure, and to adjust the systolic:diastolic ratio as well as the positive and negative pressures in a VAD system.

  4. Measurement of Restricted Atmospheric Barrier Discharge in Nonwoven Fiber Pores

    Science.gov (United States)

    Kawabe, Masaaki

    The restricted dielectric barrier discharge in nonwoven pores has been investigated by observation of the current pulse, the Lissajous figure and light emissions. The current pulse measurement revealed that homogeneity of the discharge was relatively high and the amount of individual pulse was quite small on the order of 0.01nC. Such a small current pulse demonstrates that nonwoven fiber is effective as a dielectric barrier. Analysis of the Lissajous figure, indicates the calculated value of the gap voltage for the discharge starting point of nonwoven fiber layers is close to what was predicted using the Paschen curve. On the other hand, the measured value of the gap voltage in the Lissajous figure is larger than its calculated value, so the surface charge on the dielectrics dissipated relatively fast. The observations of light emissions also showed a high homogeneity.

  5. Atmospheric discharges from nuclear facilities during decommissioning: German experiences

    Energy Technology Data Exchange (ETDEWEB)

    Braun, H.; Goertz, R.; Weil, L.

    1997-08-01

    In Germany, a substantial amount of experience is available with planning, licensing and realization of decommissioning projects. In total, a number of 18 nuclear power plants including prototype facilities as well as 6 research reactors and 3 fuel cycle facilities have been shut down finally and are at different stages of decommissioning. Only recently the final {open_quotes}green field{close_quotes} stage of the Niederaichbach Nuclear Power Plant total dismantlement project has been achieved. From the regulatory point of view, a survey of the decommissioning experience in Germany is presented highlighting the aspects of production and retention of airborne radioactivity. Nuclear air cleaning technology, discharge limits prescribed in licences and actual discharges are presented. As compared to operation, the composition of the discharged radioactivity is different as well as the off-gas discharge rate. In practically all cases, there is no significant amount of short-lived radionuclides. The discussion further includes lessons learned, for example inadvertent discharges of radionuclides expected not to be in the plants inventory. It is demonstrated that, as for operation of nuclear power plants, the limits prescribed in the Ordinance on Radiological Protection can be met using existing air cleaning technology, Optimization of protection results in public exposures substantially below the limits. In the frame of the regulatory investigation programme a study has been conducted to assess the airborne radioactivity created during certain decommissioning activities like decontamination, segmentation and handling of contaminated or activated parts. The essential results of this study are presented, which are supposed to support planning for decommissioning, for LWRs, Co-60 and Cs-137 are expected to be the dominant radionuclides in airborne discharges. 18 refs., 2 figs., 1 tab.

  6. Sterilization of Surfaces with a Handheld Atmospheric Pressure Plasma

    Science.gov (United States)

    Hicks, Robert; Habib, Sara; Chan, Wai; Gonzalez, Eleazar; Tijerina, A.; Sloan, Mark

    2009-10-01

    Low temperature, atmospheric pressure plasmas have shown great promise for decontaminating the surfaces of materials and equipment. In this study, an atmospheric pressure, oxygen and argon plasma was investigated for the destruction of viruses, bacteria, and spores. The plasma was operated at an argon flow rate of 30 L/min, an oxygen flow rate of 20 mL/min, a power density of 101.0 W/cm^3 (beam area = 5.1 cm^2), and at a distance from the surface of 7.1 mm. An average 6log10 reduction of viable spores was obtained after only 45 seconds of exposure to the reactive gas. By contrast, it takes more than 35 minutes at 121^oC to sterilize anthrax in an autoclave. The plasma properties were investigated by numerical modeling and chemical titration with nitric oxide. The numerical model included a detailed reaction mechanism for the discharge as well as for the afterglow. It was predicted that at a delivered power density of 29.3 W/cm^3, 30 L/min argon, and 0.01 volume% O2, the plasma generated 1.9 x 10^14 cm-3 O atoms, 1.6 x 10^12 cm-3 ozone, 9.3 x 10^13 cm-3 O2(^1δg), and 2.9 x 10^12 cm-3 O2(^1σ^+g) at 1 cm downstream of the source. The O atom density measured by chemical titration with NO was 6.0 x 10^14 cm-3 at the same conditions. It is believe that the oxygen atoms and the O2(^1δg) metastables were responsible for killing the anthrax and other microorganisms.

  7. Atmospheric dc discharges with miniature gas flow as microplasma generation method

    Energy Technology Data Exchange (ETDEWEB)

    Yokoyama, Takuma; Hamada, Shuhei; Ibuka, Shinji; Yasuoka, Koichi; Ishii, Shozo [Department of Electrical and Electronic Engineering, Tokyo Institute of Technology, Tokyo 152-8552 (Japan)

    2005-06-07

    An atmospheric microplasma is generated by direct-current (dc) discharge in air with a miniature gas flow through a nozzle, which limits plasma volume. Two discharge modes appear in a nozzle-to-mesh electrode system with helium or argon. One is a repetitive pulsed discharge with a current of 10-30 mA and a short pulse width. The fast pulsed current is powered by electric charges stored in the parasitic capacitance, which depends on the spatial arrangement of the electrodes and the power leads. The pulsed discharge makes it possible to develop a discharge scheme for microplasma generation without a high-voltage pulse generator. The other is a sustained dc discharge, which develops with increasing applied voltage. In the case of helium, a glow discharge configuration is observed with a positive column and a layered structure near the cathode. The length of the positive column is affected by electrode separation and gas flow rate.

  8. Operation Mode on Pulse Modulation in Atmospheric Radio Frequency Glow Discharges

    Science.gov (United States)

    Zhang, Jie; Guo, Ying; Huang, Xiaojiang; Zhang, Jing; Shi, Jianjun

    2016-10-01

    The discharge operation regime of pulse modulated atmospheric radio frequency (RF) glow discharge in helium is investigated on the duty cycle and frequency of modulation pulses. The characteristics of radio frequency discharge burst in terms of breakdown voltage, alpha(α)-gamma(γ) mode transition voltage and current are demonstrated by the discharge current voltage characteristics. The minimum breakdown voltage of RF discharge burst was obtained at the duty cycle of 20% and frequency of 400 kHz, respectively. The α-γ mode transition of RF discharge burst occurs at higher voltage and current by reducing the duty cycle and elevating the modulation frequency before the RF discharge burst evolving into the ignition phase, in which the RF discharge burst can operate stably in the γ mode. It proposes that the intensity and stability of RF discharge burst can be improved by manipulating the duty cycle and modulation frequency in pulse modulated atmospheric RF glow discharge. supported by National Natural Science Foundation of China (Nos. 11475043 and 11375042)

  9. Non-linear macro evolution of a dc driven micro atmospheric glow discharge

    Energy Technology Data Exchange (ETDEWEB)

    Xu, S. F.; Zhong, X. X., E-mail: xxzhong@sjtu.edu.cn [The State Key Laboratory on Fiber Optic Local Area, Communication Networks and Advanced Optical Communication Systems, Key Laboratory for Laser Plasmas and Department of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai 200240 (China)

    2015-10-15

    We studied the macro evolution of the micro atmospheric glow discharge generated between a micro argon jet into ambient air and static water. The micro discharge behaves similarly to a complex ecosystem. Non-linear behaviors are found for the micro discharge when the water acts as a cathode, different from the discharge when water behaves as an anode. Groups of snapshots of the micro discharge formed at different discharge currents are captured by an intensified charge-coupled device with controlled exposure time, and each group consisted of 256 images taken in succession. Edge detection methods are used to identify the water surface and then the total brightness is defined by adding up the signal counts over the area of the micro discharge. Motions of the water surface at different discharge currents show that the water surface lowers increasingly rapidly when the water acts as a cathode. In contrast, the water surface lowers at a constant speed when the water behaves as an anode. The light curves are similar to logistic growth curves, suggesting that a self-inhibition process occurs in the micro discharge. Meanwhile, the total brightness increases linearly during the same time when the water acts as an anode. Discharge-water interactions cause the micro discharge to evolve. The charged particle bomb process is probably responsible for the different behaviors of the micro discharges when the water acts as cathode and anode.

  10. Spectroscopic Investigation of Indium Halides as Substitutes of Mercury in Low Pressure Discharges for Lighting Applications

    OpenAIRE

    Briefi, Stefan

    2012-01-01

    Low pressure discharges with indium halides as radiator are discussed as substitutes for hazardous mercury in conventional fluorescent lamps. In this work, the applicability of InBr and InCl in a low pressure discharge light source is investigated. The aim is to identify and understand the physical processes which determine the discharge characteristics and the efficiency of the generated near-UV emission of the indium halide molecule and of the indium atom which is created due to dissociatio...

  11. Influence of voltage magnitude on the dynamic behavior of a stable helium atmospheric pressure plasma jet

    Science.gov (United States)

    Ning, Wenjun; Wang, Lijun; Wu, Chen; Jia, Shenli

    2014-08-01

    Effects of voltage magnitude on the development of a stable helium atmospheric pressure plasma jet are investigated by current measurements and high temporal-resolution streak images. Generated by a coaxial dielectric barrier discharge structure, the entire discharge can be classified into three regions: discharges in the tube gap, downstream jet, and up-streamer. The discharge morphologies of each region are analyzed. In the positive discharge phase, there are two discharges in the tube gap between the electrodes; the first one is ignited as corona and then developed into streamer corona, and the second one is similar with positive glow. The downstream jet is ignited independently from the discharge in the tube gap. Referred as "plasma bullet," the dynamic behavior of the jet can be well described as a positive streamer. Under specific applied voltage, the jet is found to be composed by double bullets in which case the jet length decreases since that less charge is carried by the first bullet. The up-streamer can be captured as long as the discharge in the tube gap is activated. Propagating with velocity of ˜4 km/s, the up-streamer can be regarded as the extension of the first discharge in the tube gap. In the negative discharge phase, the discharge is confined in the tube gap with nearly symmetrical morphology with the positive one. Besides, with the rising of voltage, the negative discharge is initially intensified and then turns weaker after surpassing certain voltage, which may provide suitable condition for the occurrence of double-bullet phenomenon.

  12. Electrical Properties for Capacitively Coupled Radio Frequency Discharges of Helium and Neon at Low Pressure

    Science.gov (United States)

    Tanisli, Murat; Sahin, Neslihan; Demir, Suleyman

    2016-10-01

    In this study, the symmetric radio frequency (RF) electrode discharge is formed between the two electrodes placing symmetric parallel. The electrical properties of symmetric capacitive RF discharge of pure neon and pure helium have been obtained from current and voltage waveforms. Calculations are done according to the homogeneous discharge model of capacitively coupled radio frequency (CCRF) using with the data in detail. Electrical properties of bulk plasma and sheath capacitance are also investigated at low pressure with this model. This study compares the electrical characteristics and sheath capacitance changes with RF power and pressure for helium and neon discharges. Also, the aim of the study is to see the differences between helium and neon discharges' current and voltage values. Their root-mean-square voltages and currents are obtained from Tektronix 3052C oscilloscope. Modified homogeneous discharge model of CCRF is used for low pressure discharges and the calculations are done using experimental results. It is seen that homogeneous discharge model of CCRF is usable with modification and then helium and neon discharge's electrical properties are investigated and presented with a comparison. Helium discharge's voltage and current characteristic have smaller values than neon's. It may be said that neon discharge is a better conductor than helium discharge. It is seen that the sheath capacitance is inversely correlation with sheath resistance.

  13. Plasma polymerization of acrylic acid onto polystyrene by cyclonic plasma at atmospheric pressure

    Science.gov (United States)

    Chang, Yi-Jan; Lin, Chin-Ho; Huang, Chun

    2016-01-01

    The cyclonic atmospheric-pressure plasma is developed for chamberless deposition of poly(acrylic acid) film from argon/acrylic acid mixtures. The photoemission plasma species in atmospheric-pressure plasma polymerization was identified by optical emission spectroscopy (OES). The OES diagnosis data and deposition results indicated that in glow discharge, the CH and C2 species resulted from low-energy electron-impact dissociation that creates deposition species, but the strong CO emission lines are related to nondeposition species. The acrylic acid flow rate is seen as the key factor affecting the film growth. The film surface analysis results indicate that a smooth, continuous, and uniform surface of poly(acrylic acid) films can be formed at a relatively low plasma power input. This study reveals the potential of chamberless film growth at atmospheric pressure for large-area deposition of poly(acrylic acid) films.

  14. Helium atmospheric pressure plasma jets touching dielectric and metal surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Norberg, Seth A., E-mail: norbergs@umich.edu; Johnsen, Eric, E-mail: ejohnsen@umich.edu [Department of Mechanical Engineering, University of Michigan, 2350 Hayward Street, Ann Arbor, Michigan 48109-2125 (United States); Kushner, Mark J., E-mail: mjkush@umich.edu [Department of Electrical Engineering and Computer Science, University of Michigan, 1301 Beal Avenue, Ann Arbor, Michigan 48109-2122 (United States)

    2015-07-07

    Atmospheric pressure plasma jets (APPJs) are being investigated in the context plasma medicine and biotechnology applications, and surface functionalization. The composition of the surface being treated ranges from plastics, liquids, and biological tissue, to metals. The dielectric constant of these materials ranges from as low as 1.5 for plastics to near 80 for liquids, and essentially infinite for metals. The electrical properties of the surface are not independent variables as the permittivity of the material being treated has an effect on the dynamics of the incident APPJ. In this paper, results are discussed from a computational investigation of the interaction of an APPJ incident onto materials of varying permittivity, and their impact on the discharge dynamics of the plasma jet. The computer model used in this investigation solves Poisson's equation, transport equations for charged and neutral species, the electron energy equation, and the Navier-Stokes equations for the neutral gas flow. The APPJ is sustained in He/O{sub 2} = 99.8/0.2 flowing into humid air, and is directed onto dielectric surfaces in contact with ground with dielectric constants ranging from 2 to 80, and a grounded metal surface. Low values of relative permittivity encourage propagation of the electric field into the treated material and formation and propagation of a surface ionization wave. High values of relative permittivity promote the restrike of the ionization wave and the formation of a conduction channel between the plasma discharge and the treated surface. The distribution of space charge surrounding the APPJ is discussed.

  15. Study on an Atmospheric Pressure Plasma Jet and its Application in Etching Photo-Resistant Materials

    Institute of Scientific and Technical Information of China (English)

    李海江; 王守国; 赵玲利; 叶甜春

    2004-01-01

    An atmospheric pressure radio-frequency plasma jet that can eject cold plasma has been developed. In this paper, the configuration of this type of plasma jet is illustrated and its discharge characteristics curves are studied with a current and a voltage probe. A thermal couple is used to measure the temperature distribution along the axis of the jet stream. The temperature distribution curve is generated for the He/O2 jet stream at the discharge power of 150W. This jet can etch the photo-resistant material at an average rate of 100nm/min on the surface of silicon wafers at a right angle.

  16. Bullet-to-streamer transition on the liquid surface of a plasma jet in atmospheric pressure

    Science.gov (United States)

    Yoon, S.-Y.; Kim, G.-H.; Kim, S.-J.; Bae, B.; Kim, N.-K.; Lee, H.; Bae, N.; Ryu, S.; Yoo, S. J.; Kim, S. B.

    2017-01-01

    This study investigated the transition of the plasma shape from a ring-shaped bullet to a pin-like streamer adjacent to the electrolyte surface in a kHz-driven helium atmospheric pressure plasma jet. The transition was observed by synchronized fast images, plasma propagation speed, time-resolved emission profile of Hβ, and spatially and temporally resolved helium metastable density. The transition height increased when electrolyte evaporation was enhanced. The plasma continued to discharge on the electrolyte surface even in the absence of metastable species, i.e., the discharge mechanism changed from Penning ionization between helium metastable and ambient nitrogen to electron collision on evaporated water.

  17. Optical diagnostics of reactive species in atmospheric-pressure nonthermal plasma

    Science.gov (United States)

    Ono, Ryo

    2016-03-01

    This paper reviews optical measurements of reactive species in atmospheric-pressure nonthermal plasmas: streamer discharge, dielectric barrier discharge (DBD), plasma jet, and plasma-assisted ignition and combustion. Measurements of OH, O, N, {{\\text{O}}3} , NO, {{\\text{N}}2} (A, B, C), {{\\text{O}}2} (a, b), {{\\text{N}}2}(v) , {{\\text{O}}2}(v) , He*, Ar*, \\text{N}2+ , CH, and CH2O by laser-induced fluorescence, absorption, optical emission spectroscopy, and coherent anti-Stokes Raman scattering methods are included. Reactive species measurement in low-frequency (\\cong 1 Hz) pulsed streamer discharge is introduced, and reactive species production and reaction processes indicated by these measurements are described in detail. Measurements in high-frequency DBD, atmospheric-pressure diffuse discharge, and dc corona discharge are described. Measurements in plasma jets are also reviewed: rf plasma jets, kHz plasma jets, and additional plasma jets. Finally, measurements in plasma-assisted ignition and combustion are described and reviewed in addition to measurements in conventional spark ignition. A comprehensive list of the reviewed measurements is provided.

  18. Piezoelectric transformers for low-voltage generation of gas discharges and ionic winds in atmospheric air

    Science.gov (United States)

    Johnson, Michael J.; Go, David B.

    2015-12-01

    To generate a gas discharge (plasma) in atmospheric air requires an electric field that exceeds the breakdown threshold of ˜30 kV/cm. Because of safety, size, or cost constraints, the large applied voltages required to generate such fields are often prohibitive for portable applications. In this work, piezoelectric transformers are used to amplify a low input applied voltage (corona-like discharges on its corners or on adjacent electrodes. In the proper configuration, these discharges can be used to generate a bulk air flow called an ionic wind. In this work, PT-driven discharges are characterized by measuring the discharge current and the velocity of the induced ionic wind with ionic winds generated using input voltages as low as 7 V. The characteristics of the discharge change as the input voltage increases; this modifies the resonance of the system and subsequent required operating parameters.

  19. Atmospheric pressure plasma for surface modification

    CERN Document Server

    Wolf, Rory A

    2012-01-01

    This Book's focus and intent is to impart an understanding of the practical application of atmospheric plasma for the advancement of a wide range of current and emerging technologies. The primary key feature of this book is the introduction of over thirteen years of practical experimental evidence of successful surface modifications by atmospheric plasma methods. It offers a handbook-based approach for leveraging and optimizing atmospheric plasma technologies which are currently in commercial use. It also offers a complete treatment of both basic plasma physics and industrial plasma process

  20. Characterization of an atmospheric pressure air plasma source for polymer surface modification

    Science.gov (United States)

    Yang, Shujun; Tang, Jiansheng

    2013-10-01

    An atmospheric pressure air plasma source was generated through dielectric barrier discharge (DBD). It was used to modify polyethyleneterephthalate (PET) surfaces with very high throughput. An equivalent circuit model was used to calculate the peak average electron density. The emission spectrum from the plasma was taken and the main peaks in the spectrum were identified. The ozone density in the down plasma region was estimated by Absorption Spectroscopy. NSF and ARC-ODU

  1. Plasma discharge in N2 + CH4 at low pressures - Experimental results and applications to Titan

    Science.gov (United States)

    Thompson, W. Reid; Henry, Todd J.; Schwartz, Joel M.; Khare, B. N.; Sagan, Carl

    1991-01-01

    Results are reported from laboratory continuous-flow plasma-discharge experiments designed to simulate the formation of hydrocarbons and nitriles from N2 and CH4 in the atmosphere of Titan. Gas-chromatography and mass-spectrometry data were obtained in experiments lasting up to 100 h at temperature 295 K and pressure 17 or 0.24 mbar, modeling (1) cosmic-ray-induced processes in the Titan troposphere and (2) processes related to stratospheric aurorae excited by energetic electrons and ions from the Saturn magnetosphere, respectively. The results are presented in extensive tables and graphs, and the 0.24-mbar yields are incorporated into an eddy-mixing model to give stratospheric column abundances and mole fractions in good agreement with Voyager IRIS observations.

  2. On the mechanism of atmospheric pressure plasma plume

    Science.gov (United States)

    Chen, Longwei; Zhao, Peng; Shu, Xingsheng; Shen, Jie; Meng, Yuedong

    2010-08-01

    For the purpose of unveiling the parameters influencing the length of atmospheric pressure plasma plume, an over 165 cm long argon plasma plume is generated in the quartz tube attached to the nozzle of the device. Dependence of plasma length on discharge parameters such as applied voltage, frequency of power supply, and argon gas flow rate was investigated. Experimental results indicated that (a) the applied voltage plays crucial roles on plasma plume length, that is, the plasma plume length exponentially increases with the applied voltage, (b) the plasma plume length increases with frequency, more obviously when the applied voltage is higher, (c) the plasma plume length increases with argon gas flow rate, reaches its maximum at critical value of the gas flow rate, and then decreases again. An evaluation of the physical phenomena involved in streamer propagation, particularly of the energy balance, was investigated. The numerical results were qualitatively consistent with previous experimental results by successfully indicating the high velocity of "plasma bullet" and providing physical mechanism of energy balance determining streamer length.

  3. Atmospheric pressure thermal dissociation of phospho- and sulfopeptides.

    Science.gov (United States)

    Eberlin, Lívia S; Xia, Yu; Chen, Hao; Cooks, R Graham

    2008-12-01

    Several phospho- and sulfopeptides were subjected to atmospheric pressure thermal dissociation (APTD), which was effected by passing peptide ions generated by electrosonic spray ionization (ESSI) through a heated coiled metal tube. Sequence informative fragment ions including a-, b-, c-, and y-types of ions were observed with increased relative intensities under APTD compared with collision-induced dissociation (CID), performed inside the ion trap. A certain degree of preservation of phosphate and sulfate ester moieties was observed for some fragments ions under APTD. The neutral fragments generated outside the mass spectrometer were further analyzed via on-line corona discharge to provide rich and complementary sequence information to that provided by the fragment ions directly obtained from APTD, although complete losses of the modification groups were noted. Improved primary sequence information for phospho- and sulfopeptides was typically obtained by analyzing both ionic and neutral fragments from APTD compared with fragment ions from CID alone. Localization of the modification sites of phospho- and sulfopeptides was achieved by combining the structural information acquired from APTD and CID.

  4. Hydrocarbon analysis using desorption atmospheric pressure chemical ionization

    KAUST Repository

    Jjunju, Fred Paul Mark

    2013-07-01

    Characterization of the various petroleum constituents (hydronaphthalenes, thiophenes, alkyl substituted benzenes, pyridines, fluorenes, and polycyclic aromatic hydrocarbons) was achieved under ambient conditions without sample preparation by desorption atmospheric pressure chemical ionization (DAPCI). Conditions were chosen for the DAPCI experiments to control whether ionization was by proton or electron transfer. The protonated molecule [M+H]+ and the hydride abstracted [MH]+ form were observed when using an inert gas, typically nitrogen, to direct a lightly ionized plasma generated by corona discharge onto the sample surface in air. The abundant water cluster ions generated in this experiment react with condensed-phase functionalized hydrocarbon model compounds and their mixtures at or near the sample surface. On the other hand, when naphthalene was doped into the DAPCI gas stream, its radical cation served as a charge exchange reagent, yielding molecular radical cations (M+) of the hydrocarbons. This mode of sample ionization provided mass spectra with better signal/noise ratios and without unwanted side-products. It also extended the applicability of DAPCI to petroleum constituents which could not be analyzed through proton transfer (e.g., higher molecular PAHs such as chrysene). The thermochemistry governing the individual ionization processes is discussed and a desorption/ionization mechanism is inferred. © 2012 Elsevier B.V.

  5. Characteristics of Atmospheric Pressure Rotating Gliding Arc Plasmas

    Institute of Scientific and Technical Information of China (English)

    ZHANG Hao; ZHU Fengsen; TU Xin; BO Zheng; CEN Kefa; LI Xiaodong

    2016-01-01

    In this work,a novel direct current (DC) atmospheric pressure rotating gliding arc (RGA) plasma reactor has been developed for plasma-assisted chemical reactions.The influence of the gas composition and the gas flow rate on the arc dynamic behaviour and the formation of reactive species in the N2 and air gliding arc plasmas has been investigated by means of electrical signals,high speed photography,and optical emission spectroscopic diagnostics.Compared to conventional gliding arc reactors with knife-shaped electrodes which generally require a high flow rate (e.g.,10-20 L/min) to maintain a long arc length and reasonable plasma discharge zone,in this RGA system,a lower gas flow rate (e.g.,2 L/min) can also generate a larger effective plasma reaction zone with a longer arc length for chemical reactions.Two different motion patterns can be clearly observed in the N2 and air RGA plasmas.The time-resolved arc voltage signals show that three different arc dynamic modes,the arc restrike mode,takeover mode,and combined modes,can be clearly identified in the RGA plasmas.The occurrence of different motion and arc dynamic modes is strongly dependent on the composition of the working gas and gas flow rate.

  6. Atmospheric Pressure Plasma Jet for Chem/Bio Warfare Decontamination

    Science.gov (United States)

    Herrmann, Hans W.; Henins, Ivars; Park, Jaeyoung; Selwyn, Gary S.

    1999-11-01

    Atmospheric Pressure Plasma Jet (APPJ) technology may provide a much needed method of CBW decontamination which, unlike traditional decon methods, is dry and nondestructive to sensitive equipment and materials. The APPJ discharge uses a high-flow feedgas consisting primarily of an inert carrier gas, such as He, and a small amount of a reactive additive, such as O2, which flows between capacitively-coupled electrodes powered at 13.56 MHz. The plasma generates highly reactive metastable and atomic species of oxygen which are then directed onto a contaminated surface. The reactive effluent of the APPJ has been shown to effectively neutralize VX nerve agent as well as simulants for anthrax and mustard blister agent. Research efforts are now being directed towards reducing He consumption and increasing the allowable stand-off distance. Recent results demonstrate that by replacing the O2 reactive additive with CO2, ozone formation is greatly reduced. This has the result of extending the lifetime of atomic oxygen by an order of magnitude or more. A recirculating APP Decon Chamber which combines heat, vacuum, forced convection and reactivity is currently being developed for enhanced decontamination of sensitive equipment. Several techniques are also being evaluated for use in an APP Decon Jet for decontamination of items which cannot be placed inside a chamber.

  7. Characteristics of Atmospheric Pressure Rotating Gliding Arc Plasmas

    Science.gov (United States)

    Zhang, Hao; Zhu, Fengsen; Tu, Xin; Bo, Zheng; Cen, Kefa; Li, Xiaodong

    2016-05-01

    In this work, a novel direct current (DC) atmospheric pressure rotating gliding arc (RGA) plasma reactor has been developed for plasma-assisted chemical reactions. The influence of the gas composition and the gas flow rate on the arc dynamic behaviour and the formation of reactive species in the N2 and air gliding arc plasmas has been investigated by means of electrical signals, high speed photography, and optical emission spectroscopic diagnostics. Compared to conventional gliding arc reactors with knife-shaped electrodes which generally require a high flow rate (e.g., 10-20 L/min) to maintain a long arc length and reasonable plasma discharge zone, in this RGA system, a lower gas flow rate (e.g., 2 L/min) can also generate a larger effective plasma reaction zone with a longer arc length for chemical reactions. Two different motion patterns can be clearly observed in the N2 and air RGA plasmas. The time-resolved arc voltage signals show that three different arc dynamic modes, the arc restrike mode, takeover mode, and combined modes, can be clearly identified in the RGA plasmas. The occurrence of different motion and arc dynamic modes is strongly dependent on the composition of the working gas and gas flow rate. supported by National Natural Science Foundation of China (No. 51576174), the Specialized Research Fund for the Doctoral Program of Higher Education of China (No. 20120101110099) and the Fundamental Research Funds for the Central Universities (No. 2015FZA4011)

  8. [Investigation on the gas temperature of a plasma jet at atmospheric pressure by emission spectrum].

    Science.gov (United States)

    Li, Xue-chen; Yuan, Ning; Jia, Peng-ying; Niu, Dong-ying

    2010-11-01

    A plasma jet of a dielectric barrier discharge in coaxial electrode was used to produce plasma plume in atmospheric pressure argon. Spatially and temporally resolved measurement was carried out by photomultiplier tubes. The light emission signals both from the dielectric barrier discharge and from the plasma plume were analyzed. Furthermore, emission spectrum from the plasma plume was collected by high-resolution optical spectrometer. The emission spectra of OH (A 2sigma + --> X2 II, 307.7-308.9 nm) and the first negative band of N2+ (B2 sigma u+ --> X2 IIg+, 390-391.6 nm) were used to estimate the rotational temperature of the plasma plume by fitting the experimental spectra to the simulated spectra. The rotational temperature obtained is about 443 K by fitting the emission spectrum from the OH, and that from the first negative band of N2+ is about 450 K. The rotational temperatures obtained by the two method are consistent within 5% error band. The gas temperature of the plasma plume at atmospheric pressure was obtained because rotational temperature equals to gas temperature approximately in gas discharge at atmospheric pressure. Results show that gas temperature increases with increasing the applied voltage.

  9. Ionisation and discharge in cloud-forming atmospheres of brown dwarfs and extrasolar planets

    CERN Document Server

    Helling, Ch; Rodriguez-Barrera, I M; Wood, Kenneth; Robertson, G B; Stark, C R

    2016-01-01

    Brown dwarfs and giant gas extrasolar planets have cold atmospheres with a rich chemical compositions from which mineral cloud particles form. Their properties, like particle sizes and material composition, vary with height, and the mineral cloud particles are charged due to triboelectric processes in such dynamic atmospheres. The dynamics of the atmospheric gas is driven by the irradiating host star and/or by the rotation of the objects that changes during its lifetime. Thermal gas ionisation in these ultra-cool but dense atmospheres allows electrostatic interactions and magnetic coupling of a substantial atmosphere volume. Combined with a strong magnetic field $\\gg B_{\\rm Earth}$, a chromosphere and aurorae might form as suggested by radio and X-ray observations of brown dwarfs. Non-equilibrium processes like cosmic ray ionisation and discharge processes in clouds will increase the local pool of free electrons in the gas. Cosmic rays and lighting discharges also alter the composition of the local atmospheri...

  10. Measuring Viscosities of Gases at Atmospheric Pressure

    Science.gov (United States)

    Singh, Jag J.; Mall, Gerald H.; Hoshang, Chegini

    1987-01-01

    Variant of general capillary method for measuring viscosities of unknown gases based on use of thermal mass-flowmeter section for direct measurement of pressure drops. In technique, flowmeter serves dual role, providing data for determining volume flow rates and serving as well-characterized capillary-tube section for measurement of differential pressures across it. New method simple, sensitive, and adaptable for absolute or relative viscosity measurements of low-pressure gases. Suited for very complex hydrocarbon mixtures where limitations of classical theory and compositional errors make theoretical calculations less reliable.

  11. Reactivity of water vapor in an atmospheric argon flowing post-discharge plasma torch

    CERN Document Server

    Collette, S; Reniers, F

    2016-01-01

    The reactivity of water vapor introduced in the flowing post-discharge of an RF atmospheric plasma torch is investigated through electrical characterization, optical emission spectroscopy and mass spectrometry measurements. Due to the technical features of the plasma torch, the post-discharge can be considered as divided into two regions: an inner region (inside the plasma torch device) where the water vapor is injected and an outer region which directly interacts with the ambient air. The main reactions induced by the injection of water vapor are identified as well as those indicative of the influence of the ambient air. Plausible pathways allowing the production of H, OH, O radicals and H2O2 are discussed as well as reactions potentially responsible for inhomogeneities and for a low DC current measured in the flowing post-discharge. Keywords: atmospheric post-discharge, H2O plasma reactivity, RF plasma torch

  12. Non-Thermal Sanitation By Atmospheric Pressure Plasma Project

    Data.gov (United States)

    National Aeronautics and Space Administration — ORBITEC proposes to develop a non-thermal technology based on atmospheric-pressure (AP) cold plasma to sanitize foods, food packaging materials, and other hardware...

  13. Non-Thermal Sanitation By Atmospheric Pressure Plasma Project

    Data.gov (United States)

    National Aeronautics and Space Administration — ORBITEC's Non-Thermal Sanitation by Atmospheric Pressure Plasma technology sanitizes fresh fruits and vegetables without the use of consumable chemicals and without...

  14. Charge Exchange Reaction in Dopant-Assisted Atmospheric Pressure Chemical Ionization and Atmospheric Pressure Photoionization.

    Science.gov (United States)

    Vaikkinen, Anu; Kauppila, Tiina J; Kostiainen, Risto

    2016-08-01

    The efficiencies of charge exchange reaction in dopant-assisted atmospheric pressure chemical ionization (DA-APCI) and dopant-assisted atmospheric pressure photoionization (DA-APPI) mass spectrometry (MS) were compared by flow injection analysis. Fourteen individual compounds and a commercial mixture of 16 polycyclic aromatic hydrocarbons were chosen as model analytes to cover a wide range of polarities, gas-phase ionization energies, and proton affinities. Chlorobenzene was used as the dopant, and methanol/water (80/20) as the solvent. In both techniques, analytes formed the same ions (radical cations, protonated molecules, and/or fragments). However, in DA-APCI, the relative efficiency of charge exchange versus proton transfer was lower than in DA-APPI. This is suggested to be because in DA-APCI both dopant and solvent clusters can be ionized, and the formed reagent ions can react with the analytes via competing charge exchange and proton transfer reactions. In DA-APPI, on the other hand, the main reagents are dopant-derived radical cations, which favor ionization of analytes via charge exchange. The efficiency of charge exchange in both DA-APPI and DA-APCI was shown to depend heavily on the solvent flow rate, with best efficiency seen at lowest flow rates studied (0.05 and 0.1 mL/min). Both DA-APCI and DA-APPI showed the radical cation of chlorobenzene at 0.05-0.1 mL/min flow rate, but at increasing flow rate, the abundance of chlorobenzene M(+.) decreased and reagent ion populations deriving from different gas-phase chemistry were recorded. The formation of these reagent ions explains the decreasing ionization efficiency and the differences in charge exchange between the techniques. Graphical Abstract ᅟ.

  15. Corona Discharges in Atmospheric Air Between a Wire and Two Plates

    OpenAIRE

    Bérard, Philippe; Lacoste, Deanna,; Laux, C.

    2011-01-01

    International audience; The corona discharge obtained in atmospheric air between a wire and two plates is presented. For the configuration studied and the voltage applied, the current is steady for the positive corona and exhibits Trichel pulses in the negative corona. The positive corona produces a homogeneous blue halo around the wire, whereas the negative discharge produces evenly spaced spots on the wire surface. We verified the analytic prediction that the ionic wind varies as the square...

  16. Laser electrospray mass spectrometry of adsorbed molecules at atmospheric pressure

    Science.gov (United States)

    Brady, John J.; Judge, Elizabeth J.; Simon, Kuriakose; Levis, Robert J.

    2010-02-01

    Atmospheric pressure mass analysis of solid phase biomolecules is performed using laser electrospray mass spectrometry (LEMS). A non-resonant femtosecond duration laser pulse vaporizes native samples at atmospheric pressure for subsequent electrospray ionization and transfer into a mass spectrometer. LEMS was used to detect a complex molecule (irinotecan HCl), a complex mixture (cold medicine formulation with active ingredients: acetaminophen, dextromethorphan HBr and doxylamine succinate), and a biological building block (deoxyguanosine) deposited on steel surfaces without a matrix molecule.

  17. Observation of hard radiations in a laboratory atmospheric high-voltage discharge

    CERN Document Server

    Agafonov, A V; Chubenko, A P; Oginov, A V; Rodionov, A A; Rusetskiy, A S; Ryabov, V A; Shepetov, A L; Shpakov, K V

    2016-01-01

    The new results concerning neutron emission detection from a laboratory high-voltage discharge in the air are presented. Data were obtained with a combination of plastic scintillation detectors and $^3$He filled counters of thermal neutrons. Strong dependence of the hard x-ray and neutron radiation appearance on the field strength near electrodes, which is determined by their form, was found. We have revealed a more sophisticated temporal structure of the neutron bursts observed during of electric discharge. This may indicate different mechanisms for generating penetrating radiation at the time formation and development of the atmospheric discharge.

  18. Initiation of extended arc discharge in ICF reactor dense atmospheres

    Energy Technology Data Exchange (ETDEWEB)

    Kislev, H.

    1986-01-01

    Reduced density plasma channels are essential for LIB transport from external diodes to an ICF pellet centered in the 2-4 MPa superheated steamfilled cavity of the Heavy Water ICF Reactor. Forming such channels by ohmic heating requires the initiation of straight arc discharges along each beamline. The goal of this thesis is to evaluate the threshold beamline preionization and applied electric field for arc initiation. The capability of several preionizers to produce a straight preionized trail is evaluated through a ten-group Boltzmann equation solver. Electron densities around 10/sup 17/ m/sup -3/ could be maintained in the trail by monojoule output external preionizers. Trail preionization through the co-application of UV and CO/sub 2/ lasers appears to be the most promising technique. UV laser preionization of NO(a/sup 4/..pi..) formed in the fireball shows also good prospective. The large divergence of soft x-ray sources reduces their attractivity. The E/N dependent electron transport properties are used to construct the first streamer model capable of evaluating the steady state streamer wave shape. The streamers-induced highly ionized filament transition into a multi-kA carrying plasma channel is simulated by a modified radiation-MHD one-dimensional code.

  19. Emission of excimer radiation from direct current, high-pressure hollow cathode discharges

    Science.gov (United States)

    El-Habachi, Ahmed; Schoenbach, Karl H.

    1998-01-01

    A novel, nonequilibrium, high-pressure, direct current discharge, the microhollow cathode discharge, has been found to be an intense source of xenon and argon excimer radiation peaking at wavelengths of 170 and 130 nm, respectively. In argon discharges with a 100 μm diam hollow cathode, the intensity of the excimer radiation increased by a factor of 5 over the pressure range from 100 to 800 mbar. In xenon discharges, the intensity at 170 nm increased by two orders of magnitude when the pressure was raised from 250 mbar to 1 bar. Sustaining voltages were 200 V for argon and 400 V for xenon discharges, at current levels on the order of mA. The resistive current-voltage characteristics of the microdischarges indicate the possibility to form arrays for direct current, flat panel excimer lamps.

  20. Black pepper powder microbiological quality improvement using DBD systems in atmospheric pressure

    Science.gov (United States)

    Grabowski, Maciej; Hołub, Marcin; Balcerak, Michał; Kalisiak, Stanisław; Dąbrowski, Waldemar

    2015-07-01

    Preliminary results are given regarding black pepper powder decontamination using dielectric barrier discharge (DBD) plasma in atmospheric pressure. Three different DBD reactor constructions were investigated, both packaged and unpackaged material was treated. Due to potential, industrial applications, in addition to microbiological results, water activity, loss of mass and the properties of packaging material, regarding barrier properties were investigated. Argon based treatment of packed pepper with DBD reactor configuration is proposed and satisfactory results are presented for treatment time of 5 min or less. Contribution to the topical issue "The 14th International Symposium on High Pressure Low Temperature Plasma Chemistry (HAKONE XIV)", edited by Nicolas Gherardi, Ronny Brandenburg and Lars Stollenwark

  1. 50-Hz plasma treatment of glass fibre reinforced polyester at atmospheric pressure enhanced by ultrasonic irradiation

    OpenAIRE

    Kusano, Yukihiro; Norrman, Kion; Singh, Shailendra Vikram; Leipold, Frank; Morgen, P.; Bardenshtein, A.; Krebs, N.

    2011-01-01

    Glass fibre reinforced polyester (GFRP) plates are treated using a 50-Hz dielectric barrier discharge at peak-to-peak voltage of 30 kV in helium at atmospheric pressure with and without ultrasonicirradiation to study adhesion improvement. The ultrasonic waves at the fundamental frequency of around 30 kHz with the sound pressure level of approximately 155 dB were introduced vertically to the GFRP surface through a cylindrical waveguide. The polar component of the surface energy was almost unch...

  2. 50-Hz plasma treatment of glass fibre reinforced polyester at atmospheric pressure enhanced by ultrasonic irradiation

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Norrman, Kion; Singh, Shailendra Vikram

    2011-01-01

    Glass fibre reinforced polyester (GFRP) plates are treated using a 50-Hz dielectric barrier discharge at peak-to-peak voltage of 30 kV in helium at atmospheric pressure with and without ultrasonic irradiation to study adhesion improvement. The ultrasonic waves at the fundamental frequency of around...... 30 kHz with the sound pressure level of approximately 155 dB were introduced vertically to the GFRP surface through a cylindrical waveguide. The polar component of the surface energy was almost unchanged after the plasma treatment without ultrasonic irradiation, but drastically increased...

  3. Ultrasound enhanced 50 Hz plasma treatment of glass-fiber-reinforced polyester at atmospheric pressure

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Norrman, Kion; Singh, Shailendra Vikram

    2013-01-01

    Glass-fiber-reinforced polyester (GFRP) plates are treated using a 50Hz dielectric barrier discharge at a peak-to-peak voltage of 30 kV in helium at atmospheric pressure with and without ultrasonic irradiation to study adhesion improvement. The ultrasonic waves at the fundamental frequency...... of around 30 kHz with the sound pressure level of approximately 155 dB were introduced vertically to the GFRP surface through a cylindrical waveguide. The polar component of the surface energy was almost unchanged after the plasma treatment without ultrasonic irradiation, but drastically increased...

  4. Ionisation in atmospheres of brown dwarfs and extrasolar planets VI: Properties of large-scale discharge events

    CERN Document Server

    Bailey, R L; Hodos, G; Bilger, C; Stark, C R

    2013-01-01

    Mineral clouds in substellar atmospheres play a special role as a catalyst for a variety of charge processes. If clouds are charged, the surrounding environment becomes electrically activated, and ensembles of charged grains are electrically discharging (e.g. by lightning), which significantly infuences the local chemistry creating conditions similar to those thought responsible for life in early planetary atmospheres. We note that such lightning discharges contribute also to the ionisation state of the atmosphere. We apply scaling laws for electrical discharge processes from laboratory measurements and numerical experiments to Drift-Phoenix model atmosphere results to model the discharge's propagation downwards (as lightning) and upwards (as sprites) through the atmospheric clouds. We evaluate the spatial extent and energetics of lightning discharges. The atmospheric volume affected (e.g. by increase of temperature or electron number) is larger in a brown dwarf atmosphere ($10^8 -~10^{10}$m$^3$) than in a gi...

  5. A Spectacular Experiment Exhibiting Atmospheric Pressure

    Science.gov (United States)

    Le Noxaïc, Armand

    2014-01-01

    The experiment described here is fairly easy to reproduce and dramatically shows the magnitude of ambient air pressure. Two circular plates of aluminum are applied one against the other. How do you make their separation very difficult? With only the help of an elastic band! You don't have to use a vacuum pump for this experiment.

  6. Saturated vapor pressure above the amalgam of alkali metals in discharge lamps

    Science.gov (United States)

    Gavrish, S. V.

    2011-12-01

    A theoretical and numerical analysis of the evaporation process of two-component compounds in vapors of alkali metals in discharge lamps is presented. Based on the developed mathematical model of calculation of saturated vapor pressure of the metal above the amalgam, dependences of mass fractions of the components in the discharge volume on design parameters and thermophysical characteristics of the lamp are obtained.

  7. Current-pressure dependencies of dc magnetron discharge in inert gases

    Science.gov (United States)

    Serov, A. O.; Mankelevich, Yu A.; Pal, A. F.; Ryabinkin, A. N.

    2016-11-01

    The current-pressure (I-P) characteristics of dc magnetron discharge in inert gases (Ar, Kr and Xe) for various constant discharge voltages were measured. Under certain conditions on I-P characteristic, the nonmonotonic region of local maximum followed by a minimum is observed. It is found that increasing mass of the working gas ions results in a shift of the local maximum to lower pressures. The spatial distribution of ions in the plasma was studied by optical emission spectroscopy. Transformation of the discharge spatial structure with pressure was observed. A qualitative model of the observed trends is presented. It takes into account the pressure dependence of the discharge spatial structure, the capturing of secondary electrons by the cathode and charge exchange effects.

  8. Ultrasound enhanced plasma surface modification at atmospheric pressure

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Singh, Shailendra Vikram; Norrman, Kion

    2012-01-01

    Efficiency of atmospheric pressure plasma treatment can be highly enhanced by simultaneous high power ultrasonic irradiation onto the treating surface. It is because ultrasonic waves with a sound pressure level (SPL) above ∼140 dB can reduce the thickness of a boundary gas layer between the plasma...... arc at atmospheric pressure to study adhesion improvement. The effect of ultrasonic irradiation with the frequency diapason between 20 and 40 kHz at the SPL of ∼150 dB was investigated. After the plasma treatment without ultrasonic irradiation, the wettability was significantly improved...

  9. Non-linear macro evolution of a dc driven micro atmospheric glow discharge

    CERN Document Server

    Xu, Shaofeng

    2015-01-01

    We studied the macro evolution of the micro atmospheric glow discharge generated between a micro argon jet into ambient air and static water. The micro discharge behaves similarly to a complex ecosystem. Non-linear behaviors are found for the micro discharge when the water acts as a cathode, different from the discharge when water behaves as an anode. Groups of snapshots of the micro discharge formed at different discharge currents are captured by an intensified charge-coupled device with controlled exposure time, and each group consisted of 256 images taken in succession. Edge detection methods are used to identify the water surface and then the total brightness is defined by adding up the signal counts over the area of the micro discharge. Motions of the water surface at different discharge currents show that the water surface lowers increasingly rapidly when the water acts as a cathode. In contrast, the water surface lowers at a constant speed when the water behaves as an anode. The light curves are simila...

  10. Study of optimal discharge pressure of compressor in CO_2 refrigerating trans-critical cycle

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    In this paper, a carbon dioxide trans-critical refrigerating system which is different from a conventional subcritical refrigerating cycle was studied. The trans-critical carbon dioxide refrigerating systems are based on the Gustav Lorntzen cycle. Emphasis was focused on how to determine the optimal discharge pressure of compressor in CO2 trans-critical cycle. The factors related with the optimal discharge pressure were analyzed. A formula was developed based on cycle simulation, which could be used to pred...

  11. Investigation of Ozone Yield of Air Fed Ozonizer by High Pressure Homogeneous Dielectric Barrier Discharge

    Science.gov (United States)

    2013-07-01

    homogeneous dielectric barrier discharge ( DBD ) in dry air by using a simple DBD device. So far, we have tried to apply the homogeneous DBD to an...specific input energy region. In this work, we investigated the effect of gas pressure (from 0.1 MPa to 0.2 MPa) on the ozone yield by homogeneous DBD . The...homogeneous DBD decreased with increasing the gas pressure. 1. Introduction The dielectric barrier discharge ( DBD ) is composed of many filamentary micro

  12. CO2 Dissociation using the Versatile Atmospheric Dielectric Barrier Discharge Experiment (VADER

    Directory of Open Access Journals (Sweden)

    Michael Allen Lindon

    2014-09-01

    Full Text Available Dissociation of CO2 is investigated in an atmospheric pressure dielectric barrier discharge (DBD with a simple, zero dimensional (0-D chemical model and through experiment. The model predicts that the primary CO2 dissociation pathway within a DBD is electron impact dissociation and electron-vibrational excitation. The relaxation kinetics following dissociation are dominated by atomic oxygen chemistry. The experiments included investigating the energy efficiencies and dissociation rates of CO2 within a planar DBD, while the gas flow rate, voltage, gas composition, driving frequency, catalyst, and pulse modes were varied. Some of the VADER results include a maximum CO2 dissociation energy efficiency of 2.5 +/- 0.5%, a maximum CO$_2$ dissociation rate of 4 +/- 0.4*10^-6 mol CO2/s (5 +/- 0.5% percent dissociation, discovering that a resonant driving frequency of ~30 kHz, dependent on both applied voltage and breakdown voltage, is best for efficient CO2 dissociation and that TiO2, a photocatalyst, improved dissociation efficiencies by an average of 18% at driving frequencies above 5 kHz.

  13. Ultrasound enhanced plasma treatment of glass-fibre-reinforced polyester in atmospheric pressure air for adhesion improvement

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Singh, Shailendra Vikram; Norrman, Kion

    2011-01-01

    A glass-fibre-reinforced polyester (GFRP) plate was treated with dielectric barrier discharge (DBD) at atmospheric pressure in air for adhesion improvement. The effects of ultrasonic irradiation using a high-power gas-jet generator during the treatment were investigated. The optical emission...

  14. The discharge of fine silica sand in a silo under different ambient air pressures

    Science.gov (United States)

    Hsiau, Shu-San; Liao, Chun-Chung; Lee, Jie-Hsien

    2012-04-01

    Silos are widely used for the industrial scale handling and transportation of powdered and granular materials. The process of discharging powder in a silo involves the flow of both solid particles and an interstitial fluid, usually air. In this study, we experimentally investigate the effects of particle size and ambient pressure on the discharge process in open- and closed-top silos. The discharge rate, pressure drop, and pressure recovery rate are measured and discussed. The results show that the particle size, the diameter of the orifice, and the ambient pressure significantly influence the process of discharge. The effect of air flow is stronger on fine-powdered flow in a closed-top silo. The results indicate that the effects of air flow could be reduced by lowering the ambient pressure. In addition, a normalized critical pressure can be defined beyond which the discharge rate increases dramatically. With reduced ambient pressure, this normalized critical pressure decreases with increasing particle size. Finally, the experimental results are compared with results calculated using the Beverloo equation and Darcy's law.

  15. Temperature field simulation of gob influenced by atmospheric pressure

    Institute of Scientific and Technical Information of China (English)

    王刚; 罗海珠; 梁运涛; 王继仁

    2015-01-01

    The current temperature field model of mine gob does not take the boundary conditions of the atmospheric pressure into account, while the actual atmospheric pressure is influenced by weather, so as to produce differences between ventilation negative pressure of the working face and the negative pressure of gas drainage in gob, thus interfering the calculated results of gob temperature field. According to the characteristics of the actual air flow and temperature change in gob, a two-dimensional temperature field model of the gob was built, and the relational model between the air pressure of intake and outlet of the gob and the atmospheric pressure was established, which was introduced into the boundary conditions of temperature field to conduct calculation. By means of analysis on the simulation example, and comparison with the traditional model, the results indicate that atmospheric pressure change had notable impact on the distribution of gob temperature field. The laboratory test system of gob temperature field was constructed, and the relative error between simulated and measured value was no greater than 9.6%, which verified the effectiveness of the proposed model. This work offers theoretical basis for accurate calculation of temperature and prediction of ignition source in mine gob, and has important implications on preventing spontaneous combustion of coal.

  16. Decomposition of Chemical Chain Molecules with Atmospheric Pressure Plasma

    Science.gov (United States)

    Tansli, Murat; Tasal, Erol

    2016-10-01

    Chemical chain molecules' decomposition is an interesting subject area for the atmospheric pressure plasma applications. The effects of the atmospheric pressure argon plasma on 4-((2-methoxyphenyl)Diazenyl)Benzene-1,3,-Diol molecule at room temperature are investigated. This molecule is one of the industrial dye molecules used widely. When considering the ecological life, this molecule will be very harmful and danger. We suggest a different, easy and useful decomposing method for such molecules. Atmospheric pressure plasma jet was principally treated for this decomposing of the molecule. Fourier transform infrared spectrometry (FT-IR) was used to characterization of the molecule after the plasma application to molecule in liquid phase with ethanol and methanol solvents. The atmospheric-pressure plasma jet of argon (Ar) as non-equilibrium has been formed by ac-power generator with frequency - 24 kHz and voltage - 12 kV. Characterizations for solutions prepared with ethanol and methanol solvents of molecule have been examined after applying (duration: 3 minutes) the atmospheric pressure plasma jet. The molecule was broken at 6C-7N =8N-9C stretching peak after the plasma treatment. The new plasma photo-products for ethanol and methanol solutions were produced as 6C-7N-8N =9C (strong, varying) and 12C =17O (strong, wide) stretching peaks.

  17. Seed disinfection effect of atmospheric pressure plasma and low pressure plasma on Rhizoctonia solani.

    Science.gov (United States)

    Nishioka, Terumi; Takai, Yuichiro; Kawaradani, Mitsuo; Okada, Kiyotsugu; Tanimoto, Hideo; Misawa, Tatsuya; Kusakari, Shinichi

    2014-01-01

    Gas plasma generated and applied under two different systems, atmospheric pressure plasma and low pressure plasma, was used to investigate the inactivation efficacy on the seedborne pathogenic fungus, Rhizoctonia solani, which had been artificially introduced to brassicaceous seeds. Treatment with atmospheric plasma for 10 min markedly reduced the R. solani survival rate from 100% to 3% but delayed seed germination. The low pressure plasma treatment reduced the fungal survival rate from 83% to 1.7% after 10 min and the inactivation effect was dependent on the treatment time. The seed germination rate after treatment with the low pressure plasma was not significantly different from that of untreated seeds. The air temperature around the seeds in the low pressure system was lower than that of the atmospheric system. These results suggested that gas plasma treatment under low pressure could be effective in disinfecting the seeds without damaging them.

  18. Plant adaptation to low atmospheric pressures: potential molecular responses

    Science.gov (United States)

    Ferl, Robert J.; Schuerger, Andrew C.; Paul, Anna-Lisa; Gurley, William B.; Corey, Kenneth; Bucklin, Ray

    2002-01-01

    There is an increasing realization that it may be impossible to attain Earth normal atmospheric pressures in orbital, lunar, or Martian greenhouses, simply because the construction materials do not exist to meet the extraordinary constraints imposed by balancing high engineering requirements against high lift costs. This equation essentially dictates that NASA have in place the capability to grow plants at reduced atmospheric pressure. Yet current understanding of plant growth at low pressures is limited to just a few experiments and relatively rudimentary assessments of plant vigor and growth. The tools now exist, however, to make rapid progress toward understanding the fundamental nature of plant responses and adaptations to low pressures, and to develop strategies for mitigating detrimental effects by engineering the growth conditions or by engineering the plants themselves. The genomes of rice and the model plant Arabidopsis thaliana have recently been sequenced in their entirety, and public sector and commercial DNA chips are becoming available such that thousands of genes can be assayed at once. A fundamental understanding of plant responses and adaptation to low pressures can now be approached and translated into procedures and engineering considerations to enhance plant growth at low atmospheric pressures. In anticipation of such studies, we present here the background arguments supporting these contentions, as well as informed speculation about the kinds of molecular physiological responses that might be expected of plants in low-pressure environments.

  19. MicroScale - Atmospheric Pressure Plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Sankaran, Mohan [Case Western Reserve University

    2012-01-25

    Low-temperature plasmas play an essential role in the manufacturing of integrated circuits which are ubiquitous in modern society. In recent years, these top-down approaches to materials processing have reached a physical limit. As a result, alternative approaches to materials processing are being developed that will allow the fabrication of nanoscale materials from the bottom up. The aim of our research is to develop a new class of plasmas, termed “microplasmas” for nanomaterials synthesis. Microplasmas are a special class of plasmas formed in geometries where at least one dimension is less than 1 mm. Plasma confinement leads to several unique properties including high-pressure stability and non-equilibrium that make microplasams suitable for nanomaterials synthesis. Vapor-phase precursors can be dissociated to homogeneously nucleate nanometer-sized metal and alloyed nanoparticles. Alternatively, metal salts dispersed in liquids or polymer films can be electrochemically reduced to form metal nanoparticles. In this talk, I will discuss these topics in detail, highlighting the advantages of microplasma-based systems for the synthesis of well-defined nanomaterials.

  20. Optical properties of the atmospheric pressure helium plasma jet generated by alternative current (a.c.) power supply

    Science.gov (United States)

    Ilik, Erkan; Akan, Tamer

    2016-05-01

    In this work, an atmospheric pressure plasma jet (APPJ) was produced to generate cold flowing post-discharge plasma of pure helium gas. The main aim of this study was to generate cold flowing APPJ of pure helium gas and to determine how their optical emission spectrum change influences varying different flow rates. Lengths of early, middle, and late post-discharge plasma (jet) regions and their fluctuations were determined, respectively. Then, ignition condition dependence of the post-discharge plasma for flow rate was specified at a constant voltage. Spectroscopic studies of an atmospheric pressure plasma jet of helium were presented via analyzing OH, N2, N2+, oxygen, and helium intensities for various flow rates.

  1. Low-pressure glow discharge in a Xenon/Chlorine mixture

    Science.gov (United States)

    Shuaibov, A. K.; Shimon, L. L.; Shevera, I. V.; Dashchenko, A. I.

    2002-12-01

    The spatial, electrical, and optical characteristics of a transverse glow discharge and a volume discharge with a spherical anode and plane cathode in low-pressure Xe/Cl2 mixtures are studied. It is shown that the transverse glow discharge in mixtures with a low chlorine content occupies most of the interelectrode gap and exists in the form of strata. As the total pressure ( P≥300 Pa) and the partial chlorine pressure ( P(Cl2)≥80 Pa) increase, a solitary plasma domain with a volume of 1-2 cm3 forms in the discharge gap. It acts as a selective source of UV radiation in the XeCl(D-X) 236-nm, Cl2 (D'-A') 257-nm, and XeCl(B-X) 308-nm bands. In certain Xe/Cl2 mixtures, plasma self-oscillations in the frequency range 1-100 kHz are observed. The current of a low-pressure volume discharge with a spherical anode and plane cathode and the emission from it have both a dc and an ac component. The pressure and composition of the working mixture, as well as the average current of the volume discharge are optimized to attain the maximum emission intensity of the XeCl(D,B-X) bands. Low-pressure volume discharges in xenon/chlorine mixtures can be used as active media in low-pressure large-aperture planar or cylindrical excimer-halogen lamps emitting modulated or repetitive pulsed UV radiation.

  2. Parameters of a supershort avalanche electron beam generated in atmospheric-pressure air

    Science.gov (United States)

    Tarasenko, V. F.

    2011-05-01

    Conditions under which the number of runaway electrons in atmospheric-pressure air reaches ˜5 × 1010 are determined. Recommendations for creating runaway electron accelerators are given. Methods for measuring the parameters of a supershort avalanche electron beam and X-ray pulses from gas-filled diodes, as well as the discharge current and gap voltage, are described. A technique for determining the instant of runaway electron generation with respect to the voltage pulse is proposed. It is shown that the reduction in the gap voltage and the decrease in the beam current coincide in time. The mechanism of intense electron beam generation in gas-filled diodes is analyzed. It is confirmed experimentally that, in optimal regimes, the number of electrons generated in atmospheric-pressure air with energies T > eU m , where U m is the maximum gap voltage, is relatively small.

  3. Atmospheric-pressure air microplasma jets in aqueous media for the inactivation of Pseudomonas fluorescens cells

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Xianhui; Yang, Si-ze [Fujian Provincial Key Laboratory of Plasma and Magnetic Resonance, School of Physics and Mechanical and Electrical Engineering, Xiamen University, Xiamen, Fujian 361005 (China); Liu, Dongping [Fujian Provincial Key Laboratory of Plasma and Magnetic Resonance, School of Physics and Mechanical and Electrical Engineering, Xiamen University, Xiamen, Fujian 361005 (China); School of Physics and Materials Engineering, Dalian Nationalities University, Dalian 116600 (China); Song, Ying [School of Physics and Materials Engineering, Dalian Nationalities University, Dalian 116600 (China); School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116023 (China); Sun, Yue [School of Physics, Changchun University of Science and Technology, Changchun 130022 (China)

    2013-05-15

    The hollow fiber-based cold air microplasma jet array running at atmospheric pressure has been designed to inactivate Pseudomonas fluorescens (P. fluorescens) cells in vitro in aqueous media. The influences of electrode configurations, air flow rate, and applied voltage on the discharge characteristics of the single microplasma jet operating in aqueous media are presented, and the bactericidal efficiency of the hollow fibers-based and large-volume microplasma jet array is reported. Optical emission spectroscopy is utilized to identify excited species during the antibacterial testing of plasma in solutions. These well-aligned and rather stable air microplasma jets containing a variety of short-lived species, such as OH and O radicals and charged particles, are in direct contact with aqueous media and are very effective in killing P. fluorescens cells in aqueous media. This design shows its potential application for atmospheric pressure air plasma inactivation of bacteria cells in aqueous media.

  4. Development of a new atmospheric pressure cold plasma jet generator and application in sterilization

    Institute of Scientific and Technical Information of China (English)

    Cheng Cheng; Liu Peng; Xu Lei; Zhang Li-Ye; Zhan Ru-Juan; Zhang Wen-Rui

    2006-01-01

    This paper reports that a new plasma generator at atmospheric pressure, which is composed of two homocentric cylindrical all-metal tubes, successfully generates a cold plasma jet. The inside tube electrode is connected to ground,the outside tube electrode is connected to a high-voltage power supply, and a dielectric layer is covered on the outside tube electrode. When the reactor is operated by low-frequency (6 kHz-20 kHz) AC supply in atmospheric pressure and argon is steadily fed as a discharge gas through inside tube electrode, a cold plasma jet is blown out into air and the plasma gas temperature is only 25-30 ℃. The electric character of the discharge is studied by using digital real-time oscilloscope (TDS 200-Series), and the discharge is capacitive. Preliminary results are presented on the decontamination of E.colis bacteria and Bacillus subtilis bacteria by this plasma jet, and an optical emission analysis of the plasma jet is presented in this paper. The ozone concentration generated by the plasma jet is 1.0 × 1016cm-3 which is acquired by using the ultraviolet absorption spectroscopy.

  5. Engineering a laser remote sensor for atmospheric pressure and temperature

    Science.gov (United States)

    Kalshoven, J. E., Jr.; Korb, C. L.

    1978-01-01

    A system for the remote sensing of atmospheric pressure and temperature is described. Resonant lines in the 7600 Angstrom oxygen A band region are used and an organic dye laser beam is tuned to measure line absorption changes with temperature or pressure. A reference beam outside this band is also transmitted for calibration. Using lidar techniques, profiling of these parameters with altitude can be accomplished.

  6. Operation Manual: Pressure Momentum Method of Discharge Measurement.

    Science.gov (United States)

    1984-05-01

    Scale Factors .... ............... ... A3 Al Table Al Manometer Conversion Factors Water Temperature Inches Deflection/psid, B OF Mercury, Hg * Meriam , Me...differential pressure (psid): psid = B- Specific gravity of Meriam = 2.95. Table A2 Water Density* Temperature Density3 OF slugs/ft3 32 1.940 40 1.940 50

  7. Influence of geomagnetic activity and atmospheric pressure in hypertensive adults.

    Science.gov (United States)

    Azcárate, T; Mendoza, B

    2017-03-30

    We performed a study of the systolic and diastolic arterial blood pressure behavior under natural variables such as the atmospheric pressure and the horizontal geomagnetic field component. We worked with a group of eight adult hypertensive volunteers, four men and four women, with ages between 18 and 27 years in Mexico City during a geomagnetic storm in 2014. The data was divided by gender, age, and day/night cycle. We studied the time series using three methods: correlations, bivariate analysis, and superposed epoch (within a window of 2 days around the day of occurrence of a geomagnetic storm) analysis, between the systolic and diastolic blood pressure and the natural variables. The correlation analysis indicated a correlation between the systolic and diastolic blood pressure and the atmospheric pressure and the horizontal geomagnetic field component, being the largest during the night. Furthermore, the correlation and bivariate analyses showed that the largest correlations are between the systolic and diastolic blood pressure and the horizontal geomagnetic field component. Finally, the superposed epoch analysis showed that the largest number of significant changes in the blood pressure under the influence of geomagnetic field occurred in the systolic blood pressure for men.

  8. Piezoelectric transformers for low-voltage generation of gas discharges and ionic winds in atmospheric air

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, Michael J. [Department of Aerospace and Mechanical Engineering, University of Notre Dame, Notre Dame, Indianapolis 46556 (United States); Go, David B., E-mail: dgo@nd.edu [Department of Aerospace and Mechanical Engineering, University of Notre Dame, Notre Dame, Indianapolis 46556 (United States); Department of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, Indianapolis 46556 (United States)

    2015-12-28

    To generate a gas discharge (plasma) in atmospheric air requires an electric field that exceeds the breakdown threshold of ∼30 kV/cm. Because of safety, size, or cost constraints, the large applied voltages required to generate such fields are often prohibitive for portable applications. In this work, piezoelectric transformers are used to amplify a low input applied voltage (<30 V) to generate breakdown in air without the need for conventional high-voltage electrical equipment. Piezoelectric transformers (PTs) use their inherent electromechanical resonance to produce a voltage amplification, such that the surface of the piezoelectric exhibits a large surface voltage that can generate corona-like discharges on its corners or on adjacent electrodes. In the proper configuration, these discharges can be used to generate a bulk air flow called an ionic wind. In this work, PT-driven discharges are characterized by measuring the discharge current and the velocity of the induced ionic wind with ionic winds generated using input voltages as low as 7 V. The characteristics of the discharge change as the input voltage increases; this modifies the resonance of the system and subsequent required operating parameters.

  9. Ionisation and discharge in cloud-forming atmospheres of brown dwarfs and extrasolar planets

    Science.gov (United States)

    Helling, Ch; Rimmer, P. B.; Rodriguez-Barrera, I. M.; Wood, Kenneth; Robertson, G. B.; Stark, C. R.

    2016-07-01

    Brown dwarfs and giant gas extrasolar planets have cold atmospheres with rich chemical compositions from which mineral cloud particles form. Their properties, like particle sizes and material composition, vary with height, and the mineral cloud particles are charged due to triboelectric processes in such dynamic atmospheres. The dynamics of the atmospheric gas is driven by the irradiating host star and/or by the rotation of the objects that changes during its lifetime. Thermal gas ionisation in these ultra-cool but dense atmospheres allows electrostatic interactions and magnetic coupling of a substantial atmosphere volume. Combined with a strong magnetic field \\gg {{B}\\text{Earth}} , a chromosphere and aurorae might form as suggested by radio and x-ray observations of brown dwarfs. Non-equilibrium processes like cosmic ray ionisation and discharge processes in clouds will increase the local pool of free electrons in the gas. Cosmic rays and lighting discharges also alter the composition of the local atmospheric gas such that tracer molecules might be identified. Cosmic rays affect the atmosphere through air showers in a certain volume which was modelled with a 3D Monte Carlo radiative transfer code to be able to visualise their spacial extent. Given a certain degree of thermal ionisation of the atmospheric gas, we suggest that electron attachment to charge mineral cloud particles is too inefficient to cause an electrostatic disruption of the cloud particles. Cloud particles will therefore not be destroyed by Coulomb explosion for the local temperature in the collisional dominated brown dwarf and giant gas planet atmospheres. However, the cloud particles are destroyed electrostatically in regions with strong gas ionisation. The potential size of such cloud holes would, however, be too small and might occur too far inside the cloud to mimic the effect of, e.g. magnetic field induced star spots.

  10. Atmospheric pressure He-air plasma jet: Breakdown process and propagation phenomenon

    Directory of Open Access Journals (Sweden)

    Asma Begum

    2013-06-01

    Full Text Available In this paper He-discharge (plasma jet/bullet in atmospheric pressure air and its progression phenomenon has been studied experimentally using ICCD camera, optical emission spectroscopy (OES and calibrated dielectric probe measurements. The repetitive nanosecond pulse has applied to a plasma pencil to generate discharge in the helium gas channel. The discharge propagation speed was measured from the ICCD images. The axial electric field distribution in the plasma jet is inferred from the optical emission spectroscopic data and from the probe measurement. The correlation between the jet velocities, jet length with the pulse duration is established. It shows that the plasma jet is not isolated from the input voltage along its propagation path. The discharge propagation speed, the electron density and the local and average electric field distribution along the plasma jet axis predicted from the experimental results are in good agreement with the data predicted by numerical simulation of the streamer propagation presented in different literatures. The ionization phenomenon of the discharge predicts the key ionization parameters, such as speed, peak electric field in the front, and electron density. The maximum local electric field measured by OES is 95 kV/cm at 1.3 cm of the jet axis, and average EF measured by probe is 24 kV/cm at the same place of the jet. The average and local electron density estimated are in the order of 1011 cm-3 and it reaches to the maximum of 1012 cm-3.

  11. On the permanent hip-stabilizing effect of atmospheric pressure.

    Science.gov (United States)

    Prietzel, Torsten; Hammer, Niels; Schleifenbaum, Stefan; Kaßebaum, Eric; Farag, Mohamed; von Salis-Soglio, Georg

    2014-08-22

    Hip joint dislocations related to total hip arthroplasty (THA) are a common complication especially in the early postoperative course. The surgical approach, the alignment of the prosthetic components, the range of motion and the muscle tone are known factors influencing the risk of dislocation. A further factor that is discussed until today is atmospheric pressure which is not taken into account in the present THA concepts. The aim of this study was to investigate the impact of atmospheric pressure on hip joint stability. Five joint models (Ø 28-44 mm), consisting of THA components were hermetically sealed with a rubber capsule, filled with a defined amount of fluid and exposed to varying ambient pressure. Displacement and pressure sensors were used to record the extent of dislocation related to intraarticular and ambient pressure. In 200 experiments spontaneous dislocations of the different sized joint models were reliably observed once the ambient pressure was lower than 6.0 kPa. Increasing the ambient pressure above 6.0 kPa immediately and persistently reduced the joint models until the ambient pressure was lowered again. Displacement always exceeded half the diameter of the joint model and was independent of gravity effects. This experimental study gives strong evidence that the hip joint is permanently stabilized by atmospheric pressure, confirming the theories of Weber and Weber (1836). On basis of these findings the use of larger prosthetic heads, capsular repair and the deployment of an intracapsular Redon drain are proposed to substantially decrease the risk of dislocation after THA.

  12. Etching of polymers, proteins and bacterial spores by atmospheric pressure DBD plasma in air

    Science.gov (United States)

    Kuzminova, A.; Kretková, T.; Kylián, O.; Hanuš, J.; Khalakhan, I.; Prukner, V.; Doležalová, E.; Šimek, M.; Biederman, H.

    2017-04-01

    Many studies proved that non-equilibrium discharges generated at atmospheric pressure are highly effective for the bio-decontamination of surfaces of various materials. One of the key processes that leads to a desired result is plasma etching and thus the evaluation of etching rates of organic materials is of high importance. However, the comparison of reported results is rather difficult if impossible as different authors use diverse sources of atmospheric plasma that are operated at significantly different operational parameters. Therefore, we report here on the systematic study of the etching of nine different common polymers that mimic the different structures of more complicated biological systems, bovine serum albumin (BSA) selected as the model protein and spores of Bacillus subtilis taken as a representative of highly resistant micro-organisms. The treatment of these materials was performed by means of atmospheric pressure dielectric barrier discharge (DBD) sustained in open air at constant conditions. All tested polymers, BSA and spores, were readily etched by DBD plasma. However, the measured etching rates were found to be dependent on the chemical structure of treated materials, namely on the presence of oxygen in the structure of polymers.

  13. Atmospheric Pressure Plasma Based Flame Control and Diagnostics

    Science.gov (United States)

    2015-01-01

    TYPE 3. DATES COVERED 00-00-2015 to 00-00-2015 4. TITLE AND SUBTITLE Atmospheric Pressure Plasma Based Flame Control and Diagnostics 5a...to 10%)  Flame speed enhancement (>20%)  Extension of lean limit (factor of two)  Distributed ignition  Development of new diagnostics

  14. Einstein's Tea Leaves and Pressure Systems in the Atmosphere

    Science.gov (United States)

    Tandon, Amit; Marshall, John

    2010-01-01

    Tea leaves gather in the center of the cup when the tea is stirred. In 1926 Einstein explained the phenomenon in terms of a secondary, rim-to-center circulation caused by the fluid rubbing against the bottom of the cup. This explanation can be connected to air movement in atmospheric pressure systems to explore, for example, why low-pressure…

  15. Atmospheric pressure and suicide attempts in Helsinki, Finland.

    Science.gov (United States)

    Hiltunen, Laura; Ruuhela, Reija; Ostamo, Aini; Lönnqvist, Jouko; Suominen, Kirsi; Partonen, Timo

    2012-11-01

    The influence of weather on mood and mental health is commonly debated. Furthermore, studies concerning weather and suicidal behavior have given inconsistent results. Our aim was to see if daily weather changes associate with the number of suicide attempts in Finland. All suicide attempts treated in the hospitals in Helsinki, Finland, during two separate periods, 8 years apart, were included. Altogether, 3,945 suicide attempts were compared with daily weather parameters and analyzed with a Poisson regression. We found that daily atmospheric pressure correlated statistically significantly with the number of suicide attempts, and for men the correlation was negative. Taking into account the seasonal normal value during the period 1971-2000, daily temperature, global solar radiation and precipitation did not associate with the number of suicide attempts on a statistically significant level in our study. We concluded that daily atmospheric pressure may have an impact on suicidal behavior, especially on suicide attempts of men by violent methods (P atmospheric pressure and women under high atmospheric pressure. We show only statistical correlations, which leaves the exact mechanisms of interaction between weather and suicidal behavior open. However, suicidal behavior should be assessed from the point of view of weather in addition to psychiatric and social aspects.

  16. Atmospheric pressure CVD of SNO2 and ZNO:AL

    NARCIS (Netherlands)

    Deelen, J. van; Kniknie, B.J.; Steijvers, H.L.A.H.; Mannie, G.; Thune, P.; Illiberi, A.

    2012-01-01

    Atmospheric pressure CVD (APCVD) is a highly cost effective method of depositing transparent conductive oxides (TCOs). In this work, insights in alcohol addition in the widely applied SnO2 process are discussed, including high resolution TEM images. Furthermore, the APCVD process of ZnO:Al was demon

  17. Atmospheric pressure photoionization using tunable VUV synchrotron radiation

    Energy Technology Data Exchange (ETDEWEB)

    Giuliani, A., E-mail: alexandre.giuliani@synchrotron-soleil.fr [Synchrotron SOLEIL, L' Orme des Merisiers, Saint Aubin, 91192 Gif-sur-Yvette (France); INRA, U1008 CEPIA, Rue de la Geraudiere, F-44316 Nantes (France); Giorgetta, J.-L.; Ricaud, J.-P. [Synchrotron SOLEIL, L' Orme des Merisiers, Saint Aubin, 91192 Gif-sur-Yvette (France); Jamme, F. [Synchrotron SOLEIL, L' Orme des Merisiers, Saint Aubin, 91192 Gif-sur-Yvette (France); INRA, U1008 CEPIA, Rue de la Geraudiere, F-44316 Nantes (France); Rouam, V.; Wien, F. [Synchrotron SOLEIL, L' Orme des Merisiers, Saint Aubin, 91192 Gif-sur-Yvette (France); Laprevote, O. [Laboratoire de Spectrometrie de Masse, ICSN-CNRS, 1 Avenue de la Terrasse, 91190 Gif-sur-Yvette (France); Laboratoire de Chimie-Toxicologie Analytique et cellulaire, IFR 71, Faculte des Sciences Pharmaceutiques et Biologiques, Universite Paris Descartes, 4 Avenue de l' Observatoire, 75006 Paris (France); Refregiers, M. [Synchrotron SOLEIL, L' Orme des Merisiers, Saint Aubin, 91192 Gif-sur-Yvette (France)

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer Coupling of an atmospheric pressure photoionization source with a vacuum ultra-violet (VUV) beamline. Black-Right-Pointing-Pointer The set up allows photoionization up to 20 eV. Black-Right-Pointing-Pointer Compared to classical atmospheric pressure photoionization (APPI), our set up offers spectral purity and tunability. Black-Right-Pointing-Pointer Allows photoionization mass spectrometry on fragile and hard to vaporize molecules. - Abstract: We report here the first coupling of an atmospheric pressure photoionization (APPI) source with a synchrotron radiation beamline in the vacuum ultra-violet (VUV). A commercial APPI source of a QStar Pulsar i from AB Sciex was modified to receive photons from the DISCO beamline at the SOLEIL synchrotron radiation facility. Photons are delivered at atmospheric pressure in the 4-20 eV range. The advantages of this new set up, termed SR-APPI, over classical APPI are spectral purity and continuous tunability. The technique may also be used to perform tunable photoionization mass spectrometry on fragile compounds difficult to vaporize by classical methods.

  18. Observation of Quartz Cathode-Luminescence in a Low Pressure Plasma Discharge

    Science.gov (United States)

    Foster, John E.

    2004-01-01

    Intense, steady-state cathode-luminescence has been observed from exposure of quartz powder to a low pressure rf-excited argon plasma discharge. The emission spectra (400 to 850 nm) associated with the powder luminescence were documented as a function of bias voltage using a spectrometer. The emission was broad-band, essentially washing out the line spectra features of the argon plasma discharge.

  19. Plasma Disinfection and the Deterioration of Surgical Tools at Atmospheric Pressure Plasma

    Science.gov (United States)

    Zaaba, Siti Khadijah; Akitsu, Tetsuya; Ohkawa, Hiroshi; Katayama-Hirayama, Keiko; Tsuji, Masao; Shimizu, Naohiro; Imanishi, Yuichirou

    The purpose of this paper is to present and compare disinfection effect of plasma by means of Atmospheric Pressure Glow plasma and streamer discharge. Geobacillus stearothermophilus was used as biological indicator for disinfection process. The effect of blades after irradiated in plasma was also studied by SEM analysis. It was found that the disinfection process was effective when the cylindrical configuration was applied. Carbon steel blade was also found to be deteriorated after immersed in plasma irradiation. Results indicate that disinfection can be achieved and at the same time deteriorations of the tools were observed.

  20. Titanium Alloy Surface Modification by a Spatio-Temporal Atmospheric Pressure DBD Afterglow

    Institute of Scientific and Technical Information of China (English)

    E.PANOUSIS; F.CLEMENT; J.F.LOISEAU; N.SPYROU; B.HELD1; J.LARRIEU; F.GUERTON

    2007-01-01

    The experimental work reported here is devoted to the study of the modifications inflicted on the surface of titanium alloy specimens by an atmospheric pressure dielectric barrier discharge(DBD) reactor in both spatial and temporal afterglow conditions.A commercially available (AcXys Technologies) modified reactor system was used for the surface treatment of the TiA6V4 titanium alloy that is widely used in the aeronautical industry.Wettability surface characterisation and XPS analyses are performed to give a macroscopic and microscopic insight to the surface modifications.Best operating conditions,at constant input energy,were obtained for a duty cycle equal to 10%.

  1. Synthesis of PPy-like Nanocrystallines by Oriented Plasma Polymerization at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    FANG Xin-sheng; GUO Ying; XU Jin-zhou; ZHANG Jing

    2006-01-01

    Polymeric polypyrrole-like (PPy-like) nanocrystallines were fast synthesized through oriented plasma polymerization at atmospheric pressure and room temperature. The effects of discharge power on the nanocrystalline morphology were investigated. Larger power tends to produce longer nanocrystallines. 3 mm long nanowires were produced at the largest power in our experiment. TEM image and the sharp electronic diffraction spots in SAD suggest that the nanoparticles have a single crystal phase. The chemical structure of the nanocrystalline has been studied through FTIR, EDX etc. This novel polymerization method could have great applications in fabricating functional polymeric nanocrystallines.

  2. Bacterial inactivation using atmospheric pressure single pin electrode microplasma jet with a ground ring

    Science.gov (United States)

    Kim, Sun Ja; Chung, T. H.; Bae, S. H.; Leem, S. H.

    2009-04-01

    Bacterial inactivation experiment was performed using atmospheric pressure microplasma jets driven by radio-frequency wave of 13.56 MHz and by low frequency wave of several kilohertz. With addition of a ground ring electrode, the discharge current, the optical emission intensities from reactive radicals, and the sterilization efficiency were enhanced significantly. When oxygen gas was added to helium at the flow rate of 5 SCCM, the sterilization efficiency was enhanced. From the survival curve of Escherichia coli, the primary role in the inactivation was played by reactive species with minor aid from heat, UV photons, charged particles, and electric fields.

  3. Atmospheric Point Discharge Currents measured with a bi-polar logarithmic current amplifier

    Science.gov (United States)

    Marlton, G.; Harrison, R. G.; Nicoll, K. A.

    2013-09-01

    Point Discharge Currents (PDC) flow in conductors exposed to the atmosphere when strong ambient electric fields cause breakdown of air. This can occur because of field intensification around a sharp point. In some cases point discharge can even become visible, known as St Elmo's fire, one of the longest recognized phenomena in atmospheric electricity. Due to the wide range of magnitudes of currents of both polarities encountered in measuring PDCs, a bipolar logarithmic current amplifier is used here for atmospheric investigations. During an installation at the Reading Atmospheric observatory, it was able to detect PDC of magnitude 0.5μA during periods of strong electric fields, in disturbed weather. Two useful attributes for planetary applications have been suggested by these experiments. Firstly, it is sufficiently compact and light-weight that it seems appropriate for planetary exploration of the electrical properties of atmospheres. Secondly its wide bi polar logarithmic range (~ pA to uA) makes it robust enough to provide useful data despite the environment in which it is deployed being poorly quantified.

  4. Quality characteristics of the radish grown under reduced atmospheric pressure

    Science.gov (United States)

    Levine, Lanfang H.; Bisbee, Patricia A.; Richards, Jeffrey T.; Birmele, Michele N.; Prior, Ronald L.; Perchonok, Michele; Dixon, Mike; Yorio, Neil C.; Stutte, Gary W.; Wheeler, Raymond M.

    This study addresses whether reduced atmospheric pressure (hypobaria) affects the quality traits of radish grown under such environments. Radish (Raphanus sativus L. cv. Cherry Bomb Hybrid II) plants were grown hydroponically in specially designed hypobaric plant growth chambers at three atmospheric pressures; 33, 66, and 96 kPa (control). Oxygen and carbon dioxide partial pressures were maintained constant at 21 and 0.12 kPa, respectively. Plants were harvested at 21 days after planting, with aerial shoots and swollen hypocotyls (edible portion of the radish referred to as the “root” hereafter) separated immediately upon removal from the chambers. Samples were subsequently evaluated for their sensory characteristics (color, taste, overall appearance, and texture), taste-determining factors (glucosinolate and soluble carbohydrate content and myrosinase activity), proximate nutrients (protein, dietary fiber, and carbohydrate) and potential health benefit attributes (antioxidant capacity). In roots of control plants, concentrations of glucosinolate, total soluble sugar, and nitrate, as well as myrosinase activity and total antioxidant capacity (measured as ORACFL), were 2.9, 20, 5.1, 9.4, and 1.9 times greater than the amount in leaves, respectively. There was no significant difference in total antioxidant capacity, sensory characteristics, carbohydrate composition, or proximate nutrient content among the three pressure treatments. However, glucosinolate content in the root and nitrate concentration in the leaf declined as the atmospheric pressure decreased, suggesting perturbation to some nitrogen-related metabolism.

  5. An expression for the h l factor in low-pressure electronegative plasma discharges

    Science.gov (United States)

    Chabert, P.

    2016-04-01

    The positive ion flux exiting a low-pressure plasma discharge is a crucial quantity in global (volume-averaged) models. In discharges containing only electrons and positive ions (electropositive discharges), it is common to write this flux {Γ\\text{wall}}={{h}\\text{l}}{{n}\\text{i0}}{{u}\\text{B}} , where {{n}\\text{i0}} is the central positive ion density, {{u}\\text{B}} is the positive ion fluid speed at the sheath edge (the Bohm speed), and {{h}\\text{l}} is the positive ion edge-to-centre density ratio. There are well established formulae for {{h}\\text{l}} in electropositive discharges, but for discharges containing negative ions (electronegative discharges), the analysis is more complicated. The purpose of this paper is to propose a formula for the {{h}\\text{l}} factor in low-pressure electronegative discharges. We use the numerical solution of fluid equations with Boltzmann negative ions, including Poisson’s equation, as a guide to derive an analytical expression that can easily be incorporated in global models. The parameter space in which the derived expression is valid is discussed at the end of the paper.

  6. Simulation of atmospheric pressure microplasma in Ar on the basis of heat transfer

    Science.gov (United States)

    Yamasaki, Masanori; Yagisawa, Takashi; Tatsumi, Tetsuya; Makabe, Toshiaki

    2011-10-01

    In a decade, atmospheric pressure microplasmas have been applied to wide range of fields based on the characteristics of high plasma density. The underlying mechanism for sustaining a stable glow discharge, however, is not well understood. In this study, the microplasma characteristics at atmospheric pressure are numerically investigated, particularly focusing on a heat transfer in the whole system. We consider a capacitively coupled plasma with the characteristic size of several hundred micrometers, driven by radio frequency (13.56 MHz) in a cylindrical reactor under atmospheric pressure of pure Ar. A plasma fluid model is coupled with a neutral gas dynamics model including the temperature and flow in gas phase. A wall heating caused by energetic ions and metastables coming from the plasma is also incorporated in the model. Under a constant gas pressure, the local depletion of a neutral gas density occurs due to a gas heating, simply shown by ideal gas law. The influence of the local gas density on the structure of the microplasma will be mainly discussed in a periodic steady state.

  7. Study of optimal discharge pressure of compressor in CO2 refrigerating trans-critical cycle

    Institute of Scientific and Technical Information of China (English)

    Fu Liehu; Wang Ruixiang; Li Qingdong; Wu Yezheng

    2008-01-01

    In this paper, a carbon dioxide trans-critical refrigerating system which is different from a conventional subcritical refrigerating cycle was studied. The trans-critical carbon dioxide refrigerating systems are based on the Gustav Lorntzen cycle. Emphasis was focused on how to determine the optimal discharge pressure of compressor in CO2 trans-critical cycle. The factors related with the optimal discharge pressure were analyzed. A formula was developed based on cycle simulation, which could be used to predict the optimal discharge pressure of a basic CO2 trans-critical cycle. After further studies on CO2 trans-critical cycles with a regenerator or expander, two more formulas were also developed. These formulas could provide an access to improve the COP of CO2 trans-critical cycle.

  8. Plasma treatment of carbon fibres and glass-fibre-reinforced polyesters at atmospheric pressure for adhesion improvement

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Løgstrup Andersen, Tom; Toftegaard, Helmuth Langmaack

    2014-01-01

    Atmospheric pressure plasma treatment is useful for adhesion improvement, because cleaning, roughening and addition of polar functional groups can be expected at the surfaces. Its possible applications in the wind energy industry include plasma treatment of fibres and fibre-reinforced polymer...... composites before assembling them to build wind turbine blades. In the present work, unsized carbon fibres are continuously treated using a dielectric barrier discharge plasma in helium at atmospheric pressure, and carbon fibre reinforced epoxy composite plates are manufactured for the mechanical test...

  9. Electron heating in low pressure capacitive discharges revisited

    Science.gov (United States)

    Kawamura, E.; Lieberman, M. A.; Lichtenberg, A. J.

    2014-12-01

    The electrons in capacitively coupled plasmas (CCPs) absorb energy via ohmic heating due to electron-neutral collisions and stochastic heating due to momentum transfer from high voltage moving sheaths. We use Particle-in-Cell (PIC) simulations to explore these heating mechanisms and to compare the PIC results with available theories on ohmic and stochastic heating. The PIC results for ohmic heating show good agreement with the ohmic heating calculation of Lafleur et al. [Phys. Plasmas 20, 124503 (2013)]. The PIC results for stochastic heating in low pressure CCPs with collisionless sheaths show good agreement with the stochastic heating model of Kaganovich et al. [IEEE Trans. Plasma Sci. 34, 696 (2006)], which revises the hard wall asymptotic model of Lieberman [IEEE Trans. Plasma Sci. 16, 638 (1988)] by taking current continuity and bulk oscillation into account.

  10. Study on the transition from filamentary discharge to diffuse discharge by using a dielectric barrier surface discharge device

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Discharge characteristics have been investigated in different gases under different pressures using a dielectric barrier surface discharge device. Electrical measurements and optical emission spectroscopy are used to study the discharge,and the results obtained show that the discharges in atmospheric pressure helium and in low-pressure air are diffuse,while that in high-pressure air is filamentary. With decreasing pressure, the discharge in air can transit from filamentary to diffuse one. The results also indicate that corona discharge around the stripe electrode is important for the diffuse discharge. The spectral intensity of N2+ (391.4 nm) relative to N2 (337.1 nm) is measured during the transition from diffuse to filamentary discharge. It is shown that relative spectral intensity increases during the discharge transition. This phenomenon implies that the averaged electron energy in diffuse discharge is higher than that in the filamentary discharge.

  11. Atmospheric-pressure glow plasma synthesis of plasmonic and photoluminescent zinc oxide nanocrystals

    Science.gov (United States)

    Bilik, N.; Greenberg, B. L.; Yang, J.; Aydil, E. S.; Kortshagen, U. R.

    2016-06-01

    In this paper, we present a large-volume (non-micro) atmospheric pressure glow plasma capable of rapid, large-scale zinc oxide nanocrystal synthesis and deposition (up to 400 μg/min), whereas in the majority of the literature, nanoparticles are synthesized using micro-scale or filamentary plasmas. The reactor is an RF dielectric barrier discharge with a non-uniform gap spacing. This design encourages pre-ionization during the plasma breakdown, making the discharge uniform over a large volume. The produced zinc oxide nanocrystals typically have diameters ranging from 4 to 15 nm and exhibit photoluminescence at ≈550 nm and localized surface plasmon resonance at ≈1900 cm-1 due to oxygen vacancies. The particle size can be tuned to a degree by varying the gas temperature and the precursor mixing ratio.

  12. Apparatus and method for atmospheric pressure reactive atom plasma processing for shaping of damage free surfaces

    Science.gov (United States)

    Carr; Jeffrey W.

    2009-03-31

    Fabrication apparatus and methods are disclosed for shaping and finishing difficult materials with no subsurface damage. The apparatus and methods use an atmospheric pressure mixed gas plasma discharge as a sub-aperture polisher of, for example, fused silica and single crystal silicon, silicon carbide and other materials. In one example, workpiece material is removed at the atomic level through reaction with fluorine atoms. In this example, these reactive species are produced by a noble gas plasma from trace constituent fluorocarbons or other fluorine containing gases added to the host argon matrix. The products of the reaction are gas phase compounds that flow from the surface of the workpiece, exposing fresh material to the etchant without condensation and redeposition on the newly created surface. The discharge provides a stable and predictable distribution of reactive species permitting the generation of a predetermined surface by translating the plasma across the workpiece along a calculated path.

  13. Atmospheric pressure loading parameters from very long baseline interferometry observations

    Science.gov (United States)

    Macmillan, D. S.; Gipson, John M.

    1994-01-01

    Atmospheric mass loading produces a primarily vertical displacement of the Earth's crust. This displacement is correlated with surface pressure and is large enough to be detected by very long baseline interferometry (VLBI) measurements. Using the measured surface pressure at VLBI stations, we have estimated the atmospheric loading term for each station location directly from VLBI data acquired from 1979 to 1992. Our estimates of the vertical sensitivity to change in pressure range from 0 to -0.6 mm/mbar depending on the station. These estimates agree with inverted barometer model calculations (Manabe et al., 1991; vanDam and Herring, 1994) of the vertical displacement sensitivity computed by convolving actual pressure distributions with loading Green's functions. The pressure sensitivity tends to be smaller for stations near the coast, which is consistent with the inverted barometer hypothesis. Applying this estimated pressure loading correction in standard VLBI geodetic analysis improves the repeatability of estimated lengths of 25 out of 37 baselines that were measured at least 50 times. In a root-sum-square (rss) sense, the improvement generally increases with baseline length at a rate of about 0.3 to 0.6 ppb depending on whether the baseline stations are close to the coast. For the 5998-km baseline from Westford, Massachusetts, to Wettzell, Germany, the rss improvement is about 3.6 mm out of 11.0 mm. The average rss reduction of the vertical scatter for inland stations ranges from 2.7 to 5.4 mm.

  14. CFD investigation of thermal and pressurization performance in LH2 tank during discharge

    Science.gov (United States)

    Wang, Lei; Li, Yanzhong; Li, Cui; Zhao, Zhixiang

    2013-10-01

    Predictions of thermal and pressurization performance in a liquid hydrogen (LH2) tank during liquid discharge is of significance to the design and optimization of a rocket pressurization system. In this paper, a computational fluid dynamic (CFD) model is introduced to simulate the pressurized discharge event of LH2 tank. The wall region together with the fluid region is simultaneously considered as the computational domain, and low-Re k-ε model is applied to account for the fluid-wall heat exchange effect. Liquid-vapor phase change effect is also involved in the model. Comparison of the numerical results with existing experimental data suggests that the CFD model has a good adaptability in pressurization computation. Detailed characteristics, such as pressurant gas requirement, pressure altering history, and temperature distribution inside the tank, can be obtained by the model. The difference of pressurant gas, selecting helium or vapor H2, may result in the variations in pressure and temperature histories. Pressurization by vapor H2 supplies a higher pressure and also a temperature rise, which is significant to consider the selection of pressurant gas. The influences of phase change effect and injector structure on pressurization behaviors are also analyzed. The computational results show that liquid-vapor phase change has a slight influence on the pressurization behaviors. Significant pressure decay at the beginning stage of process may occur in the case of no-diffuser injector application since the incoming gas is excessively cooled by cold LH2. The results show that the present CFD model has a good adaptability in the prediction of pressurization behaviors and is a useful tool for the design and optimization of a pressurization system.

  15. BWR suppression pool pressures during safety relief valve discharge. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Hwang, G.; Gay, R.R.

    1985-04-01

    An analytical understanding of the pool pressures measured during safety relief valve (SRV) discharge in BWRs equipped with x-quenchers has been developed and compared to experimental data. The local conditions inside the SRV discharge lines and inside of the x-quencher were modeled successfully with RELAP5. The measured pressure surges inside the quencher are successfully predicted by the code. In addition, the analytical predictions allow one to associate the peak pressure inside the quencher arm with the onset of air discharge into the suppression pool. A Rayleigh model of bubble dynamics successfully explained both the higher-frequency and the ensuing lower-frequency pressure oscillations that have been measured in suppression pools during SRV discharge tests. The higher-frequency oscillations are characteristic of an air bubble emanating from a single row of quencher holes. The lower-frequency pressure oscillations are characteristic of a large air bubble containing all the air expelled from one side of an x-quencher arm.

  16. Super-atmospheric pressure ionization mass spectrometry and its application to ultrafast online protein digestion analysis.

    Science.gov (United States)

    Chen, L C; Ninomiya, S; Hiraoka, K

    2016-06-01

    Pressure is a key parameter for an ionization source. In this Special Feature article, Lee Chuin Chen and colleagues review super-atmospheric pressure ionization MS with electrospray, corona-discharge-based chemical ionization, and field desorption. They routinely run their mass spectrometer with ion source pressures ranging from several to several tens of atmospheres. A number of strategies have been used to preserve the high vacuum of the instrument while working with a high-pressure (HP) ion source. A recent prototype uses a booster pump with variable pumping speed added to the first pumping stage of the mass spectrometer to regulate a constant vacuum pressure. Further, a new HP-ESI source allowing rapid (a few seconds) online protein digestion MS is also reported. Dr. Lee Chuin Chen is Associate Professor in the Department of Interdisciplinary Research at the University of Yamanashi (Yamanashi, Japan). His main research interest is the development of novel mass spectrometric methods for in-situ medical diagnosis.

  17. Impacts of air pressure on the evolution of nanosecond pulse discharge products

    Institute of Scientific and Technical Information of China (English)

    Yu Jin-Lu; He Li-Ming; Ding Wei; Wang Yu-Qian; Du Chun

    2013-01-01

    Based on the nonequilibrium plasma dynamics of air discharge,a dynamic model of zero-dimensional plasma is established by combining the component density equation,the Boltzmann equation,and the energy transfer equation.The evolution properties of nanosecond pulse discharge (NPD) plasma under different air pressures are calculated.The results show that the air pressure has significant impacts on the NPD products and the peak values of particle number density for particles such as O atoms,O3 molecules,N2(A3) molecules in excited states,and NO molecules.It increases at first and then decreases with the increase of air pressure.On the other hand,the peak values of particle number density for N2(B3)and N2(C3) molecules in excited states are only slightly affected by the air pressure.

  18. Velocity and pressure distributions in discharge tunnel of rotary-obstruction composite inner energy dissipation

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    On the basis of model test and theoretical analysis of velocity and pressure distributions,an hypothesis is presented that the distribution of tangential velocity in radial direction seems to be a combinational distribution of a quasi-free vortex and a quasi-forced vortex for the discharge tunnel of rotary-obstruction composite inner energy dissipation.The variations of corresponding parameters about the hypothesis are obtained under test conditions in this paper.The formula of pressure distribution in radial direction is deduced theoretically,and the theoretical values of pressure distribution computed by the formula are well consistent with the measured ones,showing that the formula is correct and can be applied to the computation and analysis of pressure distribution of this discharge tunnel.

  19. Radiative heat transfer in plasma of pulsed high pressure caesium discharge

    Science.gov (United States)

    Lapshin, V. F.

    2016-01-01

    Two-temperature many component gas dynamic model is used for the analysis of features of radiative heat transfer in pulsed high pressure caesium discharge plasma. It is shown that at a sufficiently high pressure the radial optical thickness of arc column is close to unit (τR (λ) ∼ 1) in most part of spectrum. In this case radiative heat transfer has not local character. In these conditions the photons which are emitted in any point of plasma volume are absorbed in other point remote from an emission point on considerable distance. As a result, the most part of the electric energy put in the discharge mainly near its axis is almost instantly redistributed on all volume of discharge column. In such discharge radial profiles of temperature are smooth. In case of low pressure, when discharge plasma is optically transparent for own radiation in the most part of a spectrum (τR(λ) << 1), the emission of radiation without reabsorption takes place. Radiative heat transfer in plasma has local character and profiles of temperature have considerable gradient.

  20. Intracellular effects of atmospheric-pressure plasmas on melanoma cancer cells

    Science.gov (United States)

    Ishaq, M.; Bazaka, K.; Ostrikov, K.

    2015-12-01

    Gas discharge plasmas formed at atmospheric pressure and near room temperature have recently been shown as a promising tool for cancer treatment. The mechanism of the plasma action is attributed to generation of reactive oxygen and nitrogen species, electric fields, charges, and photons. The relative importance of different modes of action of atmospheric-pressure plasmas depends on the process parameters and specific treatment objects. Hence, an in-depth understanding of biological mechanisms that underpin plasma-induced death in cancer cells is required to optimise plasma processing conditions. Here, the intracellular factors involved in the observed anti-cancer activity in melanoma Mel007 cells are studied, focusing on the effect of the plasma treatment dose on the expression of tumour suppressor protein TP73. Over-expression of TP73 causes cell growth arrest and/or apoptosis, and hence can potentially be targeted to enhance killing efficacy and selectivity of the plasma treatment. It is shown that the plasma treatment induces dose-dependent up-regulation of TP73 gene expression, resulting in significantly elevated levels of TP73 RNA and protein in plasma-treated melanoma cells. Silencing of TP73 expression by means of RNA interference inhibited the anticancer effects of the plasma, similar to the effect of caspase inhibitor z-VAD or ROS scavenger N-acetyl cysteine. These results confirm the role of TP73 protein in dose-dependent regulation of anticancer activity of atmospheric-pressure plasmas.

  1. Intracellular effects of atmospheric-pressure plasmas on melanoma cancer cells

    Energy Technology Data Exchange (ETDEWEB)

    Ishaq, M., E-mail: ishaqmusarat@gmail.com [Peter MacCallum Cancer Centre, East Melbourne, VIC 3002 (Australia); Comonwealth Scientific and Industrial Research Organization, Sydney, New South Wales (Australia); Bazaka, K. [Institute for Health and Biomedical Innovation, School of Chemistry, Physics and Mechanical Engineering, Queensland University of Technology, Brisbane, QLD 4000 (Australia); Ostrikov, K. [Comonwealth Scientific and Industrial Research Organization, Sydney, New South Wales (Australia); Institute for Health and Biomedical Innovation, School of Chemistry, Physics and Mechanical Engineering, Queensland University of Technology, Brisbane, QLD 4000 (Australia)

    2015-12-15

    Gas discharge plasmas formed at atmospheric pressure and near room temperature have recently been shown as a promising tool for cancer treatment. The mechanism of the plasma action is attributed to generation of reactive oxygen and nitrogen species, electric fields, charges, and photons. The relative importance of different modes of action of atmospheric-pressure plasmas depends on the process parameters and specific treatment objects. Hence, an in-depth understanding of biological mechanisms that underpin plasma-induced death in cancer cells is required to optimise plasma processing conditions. Here, the intracellular factors involved in the observed anti-cancer activity in melanoma Mel007 cells are studied, focusing on the effect of the plasma treatment dose on the expression of tumour suppressor protein TP73. Over-expression of TP73 causes cell growth arrest and/or apoptosis, and hence can potentially be targeted to enhance killing efficacy and selectivity of the plasma treatment. It is shown that the plasma treatment induces dose-dependent up-regulation of TP73 gene expression, resulting in significantly elevated levels of TP73 RNA and protein in plasma-treated melanoma cells. Silencing of TP73 expression by means of RNA interference inhibited the anticancer effects of the plasma, similar to the effect of caspase inhibitor z-VAD or ROS scavenger N-acetyl cysteine. These results confirm the role of TP73 protein in dose-dependent regulation of anticancer activity of atmospheric-pressure plasmas.

  2. Power dissipated in a non-thermal atmospheric pressure plasma jet measured by miniaturized electrical probes

    Science.gov (United States)

    Golda, Judith; Schulz-von der Gathen, Volker

    2016-09-01

    Non-thermal atmospheric pressure plasma jets are used in bio-medicine, because they generate reactive species at a low gas temperature. Knowledge and control of plasma parameters is required for stable and reliable operation. Therefore, measuring dissipated power in these plasmas is necessary. However, this is challenging because the delivered sender power is often orders of magnitudes higher than the power dissipated in the discharge itself. To measure this dissipated power, we built miniaturized electrical probes directly attached to the jet device. We observed that the dissipated power is a more comprehensive parameter than the common parameter voltage: For example, gas temperature and emission line intensities rose exponentially with increasing voltage but linearly with increasing power. Our analyses further revealed that a substantial proportion of the dissipated power is transformed into heat. In conclusion, miniaturized electrical probes give a fundamental insight into the energy balance of atmospheric pressure plasmas. In the future, these probes can also be adapted to different types of atmospheric pressure plasmas. This work was supported by DFG within the frameworks of the Package Project PAK 816.

  3. Atmospheric pressure plasma jet with high-voltage power supply based on piezoelectric transformer.

    Science.gov (United States)

    Babij, Michał; Kowalski, Zbigniew W; Nitsch, Karol; Silberring, Jerzy; Gotszalk, Teodor

    2014-05-01

    The dielectric barrier discharge plasma jet, an example of the nonthermal atmospheric pressure plasma jet (APPJ), generates low-temperature plasmas that are suitable for the atomization of volatile species and can also be served as an ionization source for ambient mass and ion mobility spectrometry. A new design of APPJ for mass spectrometry has been built in our group. In these plasma sources magnetic transformers (MTs) and inductors are typically used in power supplies but they present several drawbacks that are even more evident when dealing with high-voltage normally used in APPJs. To overcome these disadvantages, high frequency generators with the absence of MT are proposed in the literature. However, in the case of miniaturized APPJs these conventional power converters, built of ferromagnetic cores and inductors or by means of LC resonant tank circuits, are not so useful as piezoelectric transformer (PT) based power converters due to bulky components and small efficiency. We made and examined a novel atmospheric pressure plasma jet with PT supplier served as ionization source for ambient mass spectrometry, and especially mobile spectrometry where miniaturization, integration of components, and clean plasma are required. The objective of this paper is to describe the concept, design, and implementation of this miniaturized piezoelectric transformer-based atmospheric pressure plasma jet.

  4. Transfer of a cold atmospheric pressure plasma jet through a long flexible plastic tube

    Science.gov (United States)

    Kostov, Konstantin G.; Machida, Munemasa; Prysiazhnyi, Vadym; Honda, Roberto Y.

    2015-04-01

    This work proposes an experimental configuration for the generation of a cold atmospheric pressure plasma jet at the downstream end of a long flexible plastic tube. The device consists of a cylindrical dielectric chamber where an insulated metal rod that serves as high-voltage electrode is inserted. The chamber is connected to a long (up to 4 m) commercial flexible plastic tube, equipped with a thin floating Cu wire. The wire penetrates a few mm inside the discharge chamber, passes freely (with no special support) along the plastic tube and terminates a few millimeters before the tube end. The system is flushed with Ar and the dielectric barrier discharge (DBD) is ignited inside the dielectric chamber by a low frequency ac power supply. The gas flow is guided by the plastic tube while the metal wire, when in contact with the plasma inside the DBD reactor, acquires plasma potential. There is no discharge inside the plastic tube, however an Ar plasma jet can be extracted from the downstream tube end. The jet obtained by this method is cold enough to be put in direct contact with human skin without an electric shock. Therefore, by using this approach an Ar plasma jet can be generated at the tip of a long plastic tube far from the high-voltage discharge region, which provides the safe operation conditions and device flexibility required for medical treatment.

  5. 100% N2 atmospheric-pressure microwave-line-plasma production with a modified waveguide structure

    Science.gov (United States)

    Suzuki, Haruka; Tamura, Yuto; Itoh, Hitoshi; Sekine, Makoto; Hori, Masaru; Toyoda, Hirotaka

    2016-09-01

    Large-scale atmospheric pressure (AP) plasmas have been given much attention because of its high cost benefit and a variety of possibilities for industrial applications. Microwave discharge plasma using slot antenna is attractive due to its ability of high-density and stable plasma production, and we have developed a long-scale AP microwave plasma (AP microwave line plasma: AP-MLP) source using loop-structured waveguide and travelling wave and have reported spatially-uniform AP-MLP of 40 cm in length using Ar or He gas discharge. However, rare gas discharge is not always suitable for industrial applications because usage of large volume rare gas degrades the AP cost benefit. Furthermore, many industrial applications require chemically-reactive species and the AP-MLP using molecular gas will drastically increase the applications of the AP-MLP. In this study, we demonstrate 100% N2 discharge of the AP-MLP with a modified waveguide structure. Cross-sectional structure of the waveguide is improved to enhance the microwave electric field in the slot. 100% N2 plasma of 15 cm-long is successfully produced using CW microwave power of 2 kW. Low gas temperature of 1000 K is confirmed by optical emission spectroscopy, suggesting applications of the AP-MLP to low temperature processes. Part of this work is supported by JSPS KAKENHI Grant Number 25286079.

  6. [Investigation on the electron density of a micro-plasma jet operated at atmospheric pressure].

    Science.gov (United States)

    Li, Xue-chen; Zhao, Na; Liu, Wei-yuan; Liu, Zhi-qiang

    2010-07-01

    In the present paper, a micro-hollow cathode discharge setup was used to generate micro-plasma jet in flowing mixture of Ar and N2 at atmospheric pressure. The characteristics of the micro-plasma jet were investigated by means of optical method and electrical one. It has been found that breakdown occurs in the gas between the two electrodes when the input power of electric source is increased to a certain value. Plasma appears along the gas flow direction when the mixed gas flows from the aperture of the micro-hollow cathode, and the length of plasma reaches 4 mm. The discharge current is quasi-continuous, and the duration of discharge pulse is about 0.1 micros. Electron density was studied by using Einstein equation and Stark broadening of spectral lines from the emission spectrum respectively. It was found that the results of electron density calculated by the two methods are consistent with the order of 10(15) x cm(-3). It was also found that the electron density is almost independent of power. A qualitative explanation to the phenomenon is given based on the gas discharge theory.

  7. Cellular membrane collapse by atmospheric-pressure plasma jet

    Science.gov (United States)

    Kim, Kangil; Jun Ahn, Hak; Lee, Jae-Hyeok; Kim, Jae-Ho; Sik Yang, Sang; Lee, Jong-Soo

    2014-01-01

    Cellular membrane dysfunction caused by air plasma in cancer cells has been studied to exploit atmospheric-pressure plasma jets for cancer therapy. Here, we report that plasma jet treatment of cervical cancer HeLa cells increased electrical conductivity across the cellular lipid membrane and caused simultaneous lipid oxidation and cellular membrane collapse. We made this finding by employing a self-manufactured microelectrode chip. Furthermore, increased roughness of the cellular lipid membrane and sequential collapse of the membrane were observed by atomic force microscopy following plasma jet treatment. These results suggest that the cellular membrane catastrophe occurs via coincident altered electrical conductivity, lipid oxidation, and membrane roughening caused by an atmospheric-pressure plasma jet, possibly resulting in cellular vulnerability to reactive species generated from the plasma as well as cytotoxicity to cancer cells.

  8. Cellular membrane collapse by atmospheric-pressure plasma jet

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Kangil; Sik Yang, Sang, E-mail: jsjlee@ajou.ac.kr, E-mail: ssyang@ajou.ac.kr [Department of Electrical and Computer Engineering, Ajou University, Suwon 443-749 (Korea, Republic of); Jun Ahn, Hak; Lee, Jong-Soo, E-mail: jsjlee@ajou.ac.kr, E-mail: ssyang@ajou.ac.kr [Department of Biological Sciences, Ajou University, Suwon 443-749 (Korea, Republic of); Lee, Jae-Hyeok; Kim, Jae-Ho [Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea, Republic of)

    2014-01-06

    Cellular membrane dysfunction caused by air plasma in cancer cells has been studied to exploit atmospheric-pressure plasma jets for cancer therapy. Here, we report that plasma jet treatment of cervical cancer HeLa cells increased electrical conductivity across the cellular lipid membrane and caused simultaneous lipid oxidation and cellular membrane collapse. We made this finding by employing a self-manufactured microelectrode chip. Furthermore, increased roughness of the cellular lipid membrane and sequential collapse of the membrane were observed by atomic force microscopy following plasma jet treatment. These results suggest that the cellular membrane catastrophe occurs via coincident altered electrical conductivity, lipid oxidation, and membrane roughening caused by an atmospheric-pressure plasma jet, possibly resulting in cellular vulnerability to reactive species generated from the plasma as well as cytotoxicity to cancer cells.

  9. Decontamination of Chemical/Biological Warfare (CBW) Agents Using an Atmospheric Pressure Plasma Jet (APPJ)

    Science.gov (United States)

    Herrmann, Hans W.

    1998-11-01

    The atmospheric pressure plasma jet (APPJ) is a non-thermal, high pressure, uniform glow discharge that produces a high velocity effluent stream of highly reactive chemical species. The discharge operates on a feedstock gas (e.g. He/O_2/H_2O) which flows between an outer, grounded, cylindrical electrode and an inner, coaxial electrode powered at 13.56 MHz RF. While passing through the plasma, the feedgas becomes excited, dissociated or ionized by electron impact. Once the gas exits the discharge volume, ions and electrons are rapidly lost by recombination, but the fast-flowing effluent still contains metastables (e.g. O2*, He*) and radicals (e.g. O, OH). These reactive species have been shown to be effective neutralizers of surrogates for anthrax spores, mustard blister agent and VX nerve gas. Unlike conventional, wet decontamination methods, the plasma effluent does not cause corrosion of most surfaces and does not damage wiring, electronics, nor most plastics. This makes it highly suitable for decontamination of high value sensitive equipment such as is found in vehicle interiors (i.e. tanks, planes...) for which there is currently no good decontamination technique. Furthermore, the reactive species rapidly degrade into harmless products leaving no lingering residue or harmful byproducts. Physics of the APPJ will be discussed and results of surface decontamination experiments using simulant and actual CBW agents will be presented.

  10. Partial Discharge Measurements in HV Rotating Machines in Dependence on Pressure of Coolant

    Directory of Open Access Journals (Sweden)

    I. Kršňák

    2002-01-01

    Full Text Available The influence of the pressure of the coolant used in high voltage rotating machines on partial discharges occurring in stator insulation is discussed in this paper. The first part deals with a theoretical analysis of the topic. The second part deals with the results obtained on a real generator in industrial conditions. Finally, theoretical assumptions and obtained results are compared.

  11. LIF diagnostics of hydroxyl radical in a methanol containing atmospheric-pressure plasma jet

    Science.gov (United States)

    Qian, Mu-Yang; Liu, San-Qiu; Pei, Xue-Kai; Lu, Xin-Pei; Zhang, Jia-Liang; Wang, De-Zhen

    2016-10-01

    In this paper, a pulsed-dc CH3OH/Ar plasma jet generated at atmospheric pressure is studied by laser-induced fluorescence (LIF) and optical emission spectroscopy (OES). A gas-liquid bubbler system is proposed to introduce the methanol vapor into the argon gas, and the CH3OH/Ar volume ratio is kept constant at about 0.1%. Discharge occurs in a 6-mm needle-to-ring gap in an atmospheric-pressure CH3OH/Ar mixture. The space-resolved distributions of OH LIF inside and outside the nozzle exhibit distinctly different behaviors. And, different production mechanisms of OH radicals in the needle-to-ring discharge gap and afterglow of plasma jet are discussed. Besides, the optical emission lines of carbonaceous species, such as CH, CN, and C2 radicals, are identified in the CH3OH/Ar plasma jet. Finally, the influences of operating parameters (applied voltage magnitude, pulse frequency, pulsewidth) on the OH radical density are also presented and analyzed. Project supported by the National Natural Science Foundation of China (Grant Nos. 11465013 and 11375041), the Natural Science Foundation of Jiangxi Province, China (Grant Nos. 20151BAB212012 and 20161BAB201013), and the International Science and Technology Cooperation Program of China (Grant No. 2015DFA61800).

  12. Synthesis and Characterization of Nanofibrous Polyaniline Thin Film Prepared by Novel Atmospheric Pressure Plasma Polymerization Technique

    Directory of Open Access Journals (Sweden)

    Choon-Sang Park

    2016-01-01

    Full Text Available This work presents a study on the preparation of plasma-polymerized aniline (pPANI nanofibers and nanoparticles by an intense plasma cloud type atmospheric pressure plasma jets (iPC-APPJ device with a single bundle of three glass tubes. The nano size polymer was obtained at a sinusoidal wave with a peak value of 8 kV and a frequency of 26 kHz under ambient air. Discharge currents, photo-sensor amplifier, and optical emission spectrometer (OES techniques were used to analyze the plasma produced from the iPC-APPJ device. Field emission scanning electron microscopy (FE-SEM, transmission electron microscopy (TEM, Fourier transform infrared spectroscopy (FT-IR, gas chromatography-mass spectrometry (GC-MS, and gel permeation chromatography (GPC techniques were used to analyze the pPANI. FE-SEM and TEM results show that pPANI has nanofibers, nanoparticles morphology, and polycrystalline characteristics. The FT-IR and GC-MS analysis show the characteristic polyaniline peaks with evidence that some quinone and benzene rings are broken by the discharge energy. GPC results show that pPANI has high molecular weight (Mw, about 533 kDa with 1.9 polydispersity index (PDI. This study contributes to a better understanding on the novel growth process and synthesis of uniform polyaniline nanofibers and nanoparticles with high molecular weights using the simple atmospheric pressure plasma polymerization technique.

  13. Diffuse plasma treatment of polyamide 66 fabric in atmospheric pressure air

    Science.gov (United States)

    Li, Lee; Peng, Ming-yang; Teng, Yun; Gao, Guozhen

    2016-01-01

    The polyamide 66 (PA66) fabrics are hard to be colored or glued in industrial production due to the poor hydrophily. Diffuse plasma is a kind of non-thermal plasma generated at atmospheric pressure in air. This paper proposes that large-scale diffuse plasma generated between wire electrodes can be employed for improving the hydrophily of PA66 fabrics. A repetitive nanosecond-pulse diffuse-discharge reactor using a cylindrical wire electrode configuration is presented, which can generate large-scale non-thermal plasmas steadily at atmospheric pressure without any barrier dielectric. Then the reactor is used to treat PA66 fabrics in different discharge conditions. The hydrophilicity property of modified PA66 is measured by wicking test method. The modified PA66 is also analyzed by atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS) to prove the surface changes in physical microstructure and chemical functional groups, respectively. What's more, the effects of treatment time and treatment frequency on surface modification are investigated and discussed.

  14. Atmospheric sugar alcohols: evaporation rates and saturation vapor pressures

    DEFF Research Database (Denmark)

    Bilde, Merete; Zardini, Alessandro Alessio; Hong, Juan

    volatile organic molecules. Saturation vapor pressure and the associated temperature dependence (dH) are key parameters for improving predictive atmospheric models. In this work we combine experiments and thermodynamic modeling to investigate these parameters for a series of polyols, so-called sugar......The atmospheric partitioning between gas and condensed phase of organic molecules is poorly understood, and discrepancies exist between predicted and observed concentrations of secondary organic aerosols. A key problem is the lack of information about thermodynamic properties of semi- and low...... alcohols. These polyols are common in the water soluble fraction of atmospheric aerosols. In our experimental system sub-micron particles are generated by nebulization from aqueous solution, and a mono disperse fraction of the aerosol is selected using a differential mobility analyzer. The particles...

  15. Atmospheric oxygenation caused by a change in volcanic degassing pressure.

    Science.gov (United States)

    Gaillard, Fabrice; Scaillet, Bruno; Arndt, Nicholas T

    2011-10-12

    The Precambrian history of our planet is marked by two major events: a pulse of continental crust formation at the end of the Archaean eon and a weak oxygenation of the atmosphere (the Great Oxidation Event) that followed, at 2.45 billion years ago. This oxygenation has been linked to the emergence of oxygenic cyanobacteria and to changes in the compositions of volcanic gases, but not to the composition of erupting lavas--geochemical constraints indicate that the oxidation state of basalts and their mantle sources has remained constant since 3.5 billion years ago. Here we propose that a decrease in the average pressure of volcanic degassing changed the oxidation state of sulphur in volcanic gases, initiating the modern biogeochemical sulphur cycle and triggering atmospheric oxygenation. Using thermodynamic calculations simulating gas-melt equilibria in erupting magmas, we suggest that mostly submarine Archaean volcanoes produced gases with SO(2)/H(2)S atmosphere.

  16. Glow and pseudo-glow discharges in a surface discharge generator

    Institute of Scientific and Technical Information of China (English)

    Li Xue-Chen; Dong Li-Fang; Wang Long

    2005-01-01

    The glow discharge in flowing argon at one atmospheric pressure is realized in a surface discharge generator. The discharge current presents one peak per half-cycle of the applied voltage. The duration of the discharge pulse is more than 1μs when the frequency of the applied voltage is 60kHz. For the glow discharge in argon, the power consumption increases with the increase of voltage or the decrease of gas pressure.This relation is explained qualitatively based on the theory of the Townsend breakdown mechanism. In contrast, the discharge current in one atmospheric pressure air gives many spikes in each half-cycle, and correspondingly this kind of discharge is called pseudo-glow discharge. Every current spike oscillates with high-frequency damping. The pseudo-glow discharge in one atmospheric pressure air might result from the streamer breakdown mechanism.

  17. Transmission geometry laserspray ionization vacuum using an atmospheric pressure inlet.

    Science.gov (United States)

    Lutomski, Corinne A; El-Baba, Tarick J; Inutan, Ellen D; Manly, Cory D; Wager-Miller, James; Mackie, Ken; Trimpin, Sarah

    2014-07-01

    This represents the first report of laserspray ionization vacuum (LSIV) with operation directly from atmospheric pressure for use in mass spectrometry. Two different types of electrospray ionization source inlets were converted to LSIV sources by equipping the entrance of the atmospheric pressure inlet aperture with a customized cone that is sealed with a removable glass plate holding the matrix/analyte sample. A laser aligned in transmission geometry (at 180° relative to the inlet) ablates the matrix/analyte sample deposited on the vacuum side of the glass slide. Laser ablation from vacuum requires lower inlet temperature relative to laser ablation at atmospheric pressure. However, higher inlet temperature is required for high-mass analytes, for example, α-chymotrypsinogen (25.6 kDa). Labile compounds such as gangliosides and cardiolipins are detected in the negative ion mode directly from mouse brain tissue as intact doubly deprotonated ions. Multiple charging enhances the ion mobility spectrometry separation of ions derived from complex tissue samples.

  18. Atmospheric pressure plasma jet treatment of Salmonella Enteritidis inoculated eggshells.

    Science.gov (United States)

    Moritz, Maike; Wiacek, Claudia; Koethe, Martin; Braun, Peggy G

    2017-03-20

    Contamination of eggshells with Salmonella Enteritidis remains a food safety concern. In many cases human salmonellosis within the EU can be traced back to raw or undercooked eggs and egg products. Atmospheric pressure plasma is a novel decontamination method that can reduce a wide range of pathogens. The aim of this work was to evaluate the possibility of using an effective short time cold plasma treatment to inactivate Salmonella Enteritidis on the eggshell. Therefore, artificially contaminated eggshells were treated with an atmospheric pressure plasma jet under different experimental settings with various exposure times (15-300s), distances from the plasma jet nozzle to the eggshell surface (5, 8 or 12mm), feed gas compositions (Ar, Ar with 0.2, 0.5 or 1.0% O2), gas flow rates (5 and 7slm) and different inoculations of Salmonella Enteritidis (10(1)-10(6)CFU/cm(2)). Atmospheric pressure plasma could reduce Salmonella Enteritidis on eggshells significantly. Reduction factors ranged between 0.22 and 2.27 log CFU (colony-forming units). Exposure time and, particularly at 10(4)CFU/cm(2) inoculation, feed gas had a major impact on Salmonella reduction. Precisely, longer exposure times led to higher reductions and Ar as feed gas was more effective than ArO2 mixtures.

  19. Atmospheric pressure loading effects on Global Positioning System coordinate determinations

    Science.gov (United States)

    Vandam, Tonie M.; Blewitt, Geoffrey; Heflin, Michael B.

    1994-01-01

    Earth deformation signals caused by atmospheric pressure loading are detected in vertical position estimates at Global Positioning System (GPS) stations. Surface displacements due to changes in atmospheric pressure account for up to 24% of the total variance in the GPS height estimates. The detected loading signals are larger at higher latitudes where pressure variations are greatest; the largest effect is observed at Fairbanks, Alaska (latitude 65 deg), with a signal root mean square (RMS) of 5 mm. Out of 19 continuously operating GPS sites (with a mean of 281 daily solutions per site), 18 show a positive correlation between the GPS vertical estimates and the modeled loading displacements. Accounting for loading reduces the variance of the vertical station positions on 12 of the 19 sites investigated. Removing the modeled pressure loading from GPS determinations of baseline length for baselines longer than 6000 km reduces the variance on 73 of the 117 baselines investigated. The slight increase in variance for some of the sites and baselines is consistent with expected statistical fluctuations. The results from most stations are consistent with approximately 65% of the modeled pressure load being found in the GPS vertical position measurements. Removing an annual signal from both the measured heights and the modeled load time series leaves this value unchanged. The source of the remaining discrepancy between the modeled and observed loading signal may be the result of (1) anisotropic effects in the Earth's loading response, (2) errors in GPS estimates of tropospheric delay, (3) errors in the surface pressure data, or (4) annual signals in the time series of loading and station heights. In addition, we find that using site dependent coefficients, determined by fitting local pressure to the modeled radial displacements, reduces the variance of the measured station heights as well as or better than using the global convolution sum.

  20. Atmospheric sugar alcohols: evaporation rates and saturation vapor pressures

    Science.gov (United States)

    Bilde, M.; Zardini, A. A.; Hong, J.; Tschiskale, M.; Emanuelsson, E.

    2014-12-01

    The atmospheric partitioning between gas and condensed phase of organic molecules is poorly understood, and discrepancies exist between predicted and observed concentrations of secondary organic aerosols. A key problem is the lack of information about thermodynamic properties of semi- and low volatile organic molecules. Saturation vapor pressure and the associated temperature dependence (dH) are key parameters for improving predictive atmospheric models. In this work we combine experiments and thermodynamic modeling to investigate these parameters for a series of polyols, so-called sugar alcohols. These polyols are common in the water soluble fraction of atmospheric aerosols. In our experimental system sub-micron particles are generated by nebulization from aqueous solution, and a mono disperse fraction of the aerosol is selected using a differential mobility analyzer. The particles are allowed to evaporate in a laminar flow reactor, and changes in particle size as function of evaporation time are determined using a scanning mobility particle sizer system. In this work saturation vapor pressures of sugar alcohols at several temperatures have been inferred from such measurements using thermodynamic modeling. Results are presented and discussed in context of atmospheric gas to particle partitioning.

  1. Emission and absorption spectroscopy study of Ar excited states in 13.56 MHz argon plasma operating at sub-atmospheric to atmospheric pressure

    Energy Technology Data Exchange (ETDEWEB)

    Li, L. [Department of Applied Physics, Research Unit Plasma Technology, Ghent University, Jozef Plateaustraat 22, Ghent B-9000 (Belgium); Nikiforov, A., E-mail: anton.nikiforov@ugent.be [Department of Applied Physics, Research Unit Plasma Technology, Ghent University, Jozef Plateaustraat 22, Ghent B-9000 (Belgium); Institute of Solution Chemistry of the Russian Academy of Science, Academicheskaya St., 1, Ivanovo, 153045 (Russian Federation); Britun, N. [Chimie des Interactions Plasma-Surface (ChIPS), CIRMAP, Universite de Mons, 23 Place du Parc, B-7000 Mons (Belgium); Snyders, R. [Chimie des Interactions Plasma-Surface (ChIPS), CIRMAP, Universite de Mons, 23 Place du Parc, B-7000 Mons (Belgium); Materia Nova Research Centre, Parc Initialis, B-7000 Mons (Belgium); Leys, C. [Department of Applied Physics, Research Unit Plasma Technology, Ghent University, Jozef Plateaustraat 22, Ghent B-9000 (Belgium)

    2015-05-01

    The densities of metastable and resonant states of Ar atoms are measured in high pressure Ar radio frequency discharge. Resonant absorption spectroscopy for the case of a low pressure spectral lamp and high-pressure plasma absorption lines is implemented for this purpose. The necessary generalizations for the high-pressure resonant absorption method are given. Absolute density of Ar 1s levels obtained at different RF input power and operating pressures are of the order of 10{sup 11} cm{sup −3}, which is in a good agreement with those reported in the literature. The population distribution on the Ar 2p (excited) levels, obtained from the optical emission spectroscopy, reveals strong deviation from thermal equilibrium for these levels in the high-pressure case. The generation of the Ar excited states in the studied discharges is compared to the previously reported results. - Highlights: • Strong non-equilibrium distribution of Ar 2p levels is observed. • The absolute number density of non-radiative Ar 1s states is determined by the easier and low cost spectral-lamp absorption method. • The modified absorption theory of Mitchell and Zemanski was used to obtain the absolute number density of Ar 1s states at high pressure. • The developed RF source with 5 cm long gap can be a possible alternative to micro-plasma working in Ar at atmospheric pressure.

  2. Study on the Microsecond Pulse Homogeneous Dielectric Barrier Discharges in Atmospheric Air and Its Influencing Factors%Study on the Microsecond Pulse Homogeneous Dielectric Barrier Discharges in Atmospheric Air and Its Influencing Factors

    Institute of Scientific and Technical Information of China (English)

    方志; 雷枭; 蔡玲玲; 邱毓昌; Edmund KUFFEL

    2011-01-01

    The homogeneous dielectric barrier discharge (DBD) in atmospheric air between two symmetric-columnar copper electrodes with epoxy plates as the dielectric barriers is generated using a us pulse high voltage power supply. The discharge characteristics are studied by measurement of its electrical discharge parameters and observation of its light emission phenom- ena, and the main discharge parameters of the homogenous DBD, such as discharge current and average discharge power, are calculated. Results show that the discharge generated is a homogeneous one with one larger single current pulse of about 2 #s duration appearing in each voltage pulse, and its light emission is radially homogeneous and covers the entire surface of the two elec- trodes. The influences of applied voltage amplitude, air gap distance and barrier thickness on the transition of discharge modes are studied. With the increase of air gap distance, the discharge will transit from homogeneous mode to filamentary mode. The higher the thickness of dielectric barriers, the larger the air gap distance for generating the homogeneous discharge mode. The average discharge power increases non-linearly with increasing applied voltage amplitude, and decreases non-linearly with the increase of air gap distance and barrier thickness. In order to generate stable and homogeneous DBD with high discharge power, thin barriers distance should be used, and higher applied voltage amplitude should be applied to small air gap.

  3. Simulation of ion motion at atmospheric pressure: particle tracing versus electrokinetic flow.

    Science.gov (United States)

    Wissdorf, Walter; Pohler, Larissa; Klee, Sonja; Müller, David; Benter, Thorsten

    2012-02-01

    Results obtained with two computational approaches for the simulation of ion motion at elevated pressure are compared with experimentally derived ion current data. The computational approaches used are charged particle tracings with the software package SIMION ver. 8 and finite element based calculations using the software package Comsol Multiphysics ver. 4.0/4.0a. The experimental setup consisted of a tubular corona discharge ion source coupled to a cylindrical measurement chamber held at atmospheric pressure. Generated ions are flown into the chamber at essentially subsonic laminar isothermal conditions. In the simulations, strictly stationary conditions were assumed. The results show very good agreement between the SIMION/SDS model and experimental data. For the Comsol model, only qualitative agreement is observed.

  4. Time and space variability of spectral estimates of atmospheric pressure

    Science.gov (United States)

    Canavero, Flavio G.; Einaudi, Franco

    1987-01-01

    The temporal and spatial behaviors of atmospheric pressure spectra over the northern Italy and the Alpine massif were analyzed using data on surface pressure measurements carried out at two microbarograph stations in the Po Valley, one 50 km south of the Alps, the other in the foothills of the Dolomites. The first 15 days of the study overlapped with the Alpex Intensive Observation Period. The pressure records were found to be intrinsically nonstationary and were found to display substantial time variability, implying that the statistical moments depend on time. The shape and the energy content of spectra depended on different time segments. In addition, important differences existed between spectra obtained at the two stations, indicating a substantial effect of topography, particularly for periods less than 40 min.

  5. Removal of priority pollutants from water by means of dielectric barrier discharge atmospheric plasma

    Energy Technology Data Exchange (ETDEWEB)

    Hijosa-Valsero, María, E-mail: mhijv@unileon.es [Instituto de Diagnóstico Ambiental y Estudios del Agua (IDAEA), CID, CSIC, C/Jordi Girona 18-26, E-08034 Barcelona (Spain); Molina, Ricardo, E-mail: ricardo.molina@cid.csic.es [Instituto de Química Avanzada de Cataluña (IQAC), CID, CSIC, C/Jordi Girona 18-26, E-08034 Barcelona (Spain); Schikora, Hendrik, E-mail: hendrik.schikora@igb.fraunhofer.de [Fraunhofer IGB, Nobelstraße 12, 70569 Stuttgart (Germany); Müller, Michael, E-mail: michael.mueller@igb.fraunhofer.de [Fraunhofer IGB, Nobelstraße 12, 70569 Stuttgart (Germany); Bayona, Josep M., E-mail: josep.bayona@cid.csic.es [Instituto de Diagnóstico Ambiental y Estudios del Agua (IDAEA), CID, CSIC, C/Jordi Girona 18-26, E-08034 Barcelona (Spain)

    2013-11-15

    Highlights: • DBD plasma reactors were used to remove pollutants from aqueous solutions. • Atrazine, chlorfenvinfos, 2,4-dibromophenol and lindane were studied. • First-order degradation kinetics were observed for all the compounds. • Degradation by-products were identified by GC–MS. • Treatment efficiencies were lower in industrial wastewater than in pure water. -- Abstract: Two different nonthermal plasma reactors at atmospheric pressure were assessed for the removal of organic micropollutants (atrazine, chlorfenvinfos, 2,4-dibromophenol, and lindane) from aqueous solutions (1–5 mg L{sup −1}) at laboratory scale. Both devices were dielectric barrier discharge (DBD) reactors; one was a conventional batch reactor (R1) and the other a coaxial thin-falling-water-film reactor (R2). A first-order degradation kinetics was proposed for both experiments. The kinetic constants (k) were slightly faster in R1 (0.534 min{sup −1} for atrazine; 0.567 min{sup −1} for chlorfenvinfos; 0.802 min{sup −1} for 2,4-dibromophenol; 0.389 min{sup −1} for lindane) than in R2 (0.104 min{sup −1} for atrazine; 0.523 min{sup −1} for chlorfenvinfos; 0.273 min{sup −1} for 2,4-dibromophenol; 0.294 min{sup −1} for lindane). However, energy efficiencies were about one order of magnitude higher in R2 (89 mg kW{sup −1} h{sup −1} for atrazine; 447 mg kW{sup −1} h{sup −1} for chlorfenvinfos; 47 mg kW{sup −1} h{sup −1} for 2,4-dibromophenol; 50 mg kW{sup −1} h{sup −1} for lindane) than in R1. Degradation by-products of all four compounds were identified in R1. As expected, when the plasma treatment (R1) was applied to industrial wastewater spiked with atrazine or lindane, micropollutant removal was also achieved, although at a lower rate than with aqueous solutions (k = 0.117 min{sup −1} for atrazine; k = 0.061 min{sup −1} for lindane)

  6. Self-consistent Kinetic Description of the Low-Pressure Solenoidal Inductively Coupled Argon Discharge

    Institute of Scientific and Technical Information of China (English)

    毛明; 王友年

    2005-01-01

    Using an one-dimensional slab model, we have studied the electron energy distribution, the anomalous skin effect, and power absorption in the solenoidal-inductively-coupled argon discharge under low pressures (≤1.33 Pa). The electron energy distribution function and rf electromagnetic field in the plasma are determined self-consistently by the linearized Bolztmann equation incorporating with the Maxwell equations. The numerical results show that, at low pressures, the electron energy distribution function exhibits a non-Maxwellian distribution with a long high-energy tail. The anomalous skin effect is greatly enhanced under low pressures and the negative power absorption is also obtained.

  7. Growth of Fluorocarbon Films by Low-Pressure Dielectric Barrier Discharge

    Institute of Scientific and Technical Information of China (English)

    LI Wei; TAN Xiaodong; LIU Dongping; LIU Yanhong; FENG Zhiqing; CHEN Baoxiang

    2008-01-01

    Plasma polymerized fluorocarbon (FC) films have been deposited on silicon sub-strates from dielectric barrier discharge (DBD) plasma of C4Fs at room temperature under a pressure of 25~125 Pa. The effects of the discharge pressure and frequency of power supply on the films have been systematically investigated. FC films with a less cross linked structure may be formed at a relatively high pressure. Increase in the frequency of power supply leads to a signifi-cant increase in the deposition rate. Static contact angle measurements show that deposited FC films have a stable, hydrophobic surface property. All deposited films show smooth surfaces with an atomic surface roughness. The relationship between plasma parameters and the properties of the deposited FC films are discussed.

  8. Modelling the Dynamic Interaction Power System Lamp - Application to High Pressure Mercury Gas Discharge Lamps

    Directory of Open Access Journals (Sweden)

    ZIANE, M.

    2007-11-01

    Full Text Available The aim of this paper is to study the dynamic behaviour of a plant constituted by an electrical power system and a gas discharge lamp, this latter, increasingly used in street lighting, remains a nonlinear load element. Various approaches are used to represent it, one is the approximation of the discharge represented by a hot "channel", which verifies the assumption of local thermodynamic equilibrium [LTE] or the polynomial form of the conductance variation. A calculation procedure, based on "channel" approximation of the high pressure mercury (HPM gas-discharge lamp, is developed to determine the physical and electric magnitudes, which characterize the dynamic behavior of the couple "lamp-electrical power system". The evolution of the lamp properties when principal parameters of the discharge (pressure of mercury, voltage supply, frequency are varying were studied and analyzed. We show the concordance between simulation, calculations and measurements for electric, energetic or irradiative characteristics. The model reproduces well the evolution of properties of the supply when principal parameters of the discharge vary.

  9. Nanosecond-timescale high-pressure gas discharge in a microwave pulse compressor

    Science.gov (United States)

    Shlapakovski, Anatoli; Beilin, Leonid; Krasik, Yakov

    2016-09-01

    The results of experimental and numerical studies of the microwave plasma discharge initiated by a nanosecond laser pulse are presented. The discharge is ignited in the pressurized gas filling the switch, which opens the charged resonant cavity, so that the accumulated microwave energy is rapidly released into a load. Fast-framing optical imaging showed that the plasma in the switch appears as filaments expanding along the RF electric field. The temporal evolution of the plasma density was derived from time-resolved spectroscopic measurements. With increasing microwave energy in the cavity, the plasma appears earlier in time after the laser beam enters the switch and its density rises more steeply reaching values which exceed 1016 cm-3 at a gas pressure of 2 .105 Pa. Numerical simulations were conducted using the gas conductivity model of plasma and representation of discharge origin by setting initial population of seed electrons treated by PIC algorithm. The results showed good agreement with the experiments and explained how the self-consistent dynamics of the plasma and RF fields determines the quality of microwave output pulses. In addition, the dynamics of the microwave energy absorption in the discharge plasma was studied. It was shown that at a high pressure, even with an unlimited rate of ionization, a significant portion of the stored energy, 20%, is lost. This work was partially supported by the BSF Grant No. 2012038.

  10. Ignition during hydrogen release from high pressure into the atmosphere

    Science.gov (United States)

    Oleszczak, P.; Wolanski, P.

    2010-12-01

    The first investigations concerned with a problem of hydrogen jet ignition, during outflow from a high-pressure vessel were carried out nearly 40 years ago by Wolanski and Wojcicki. The research resulted from a dramatic accident in the Chorzow Chemical Plant Azoty, where the explosion of a synthesis gas made up of a mixture composed of three moles of hydrogen per mole of nitrogen, at 300°C and 30 MPa killed four people. Initial investigation had excluded potential external ignition sources and the main aim of the research was to determine the cause of ignition. Hydrogen is currently considered as a potential fuel for various vehicles such as cars, trucks, buses, etc. Crucial safety issues are of potential concern, associated with the storage of hydrogen at a very high pressure. Indeed, the evidence obtained nearly 40 years ago shows that sudden rupture of a high-pressure hydrogen storage tank or other component can result in ignition and potentially explosion. The aim of the present research is identification of the conditions under which hydrogen ignition occurs as a result of compression and heating of the air by the shock wave generated by discharge of high-pressure hydrogen. Experiments have been conducted using a facility constructed in the Combustion Laboratory of the Institute of Heat Engineering, Warsaw University of Technology. Tests under various configurations have been performed to determine critical conditions for occurrence of high-pressure hydrogen ignition. The results show that a critical pressure exists, leading to ignition, which depends mainly on the geometric configuration of the outflow system, such as tube diameter, and on the presence of obstacles.

  11. Low pressure water vapour discharge as a light source: I. Spectroscopic characteristics and efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Artamonova, E; Artamonova, T; Beliaeva, A; Gorbov, D; Khodorkovskii, M; Melnikov, A; Milenin, V; Murashov, S; Rakcheeva, L; Timofeev, N [Saint-Petersburg State University, Ulyanovskaya 3, 198504 (Russian Federation); Michael, D [General Electric Global Research Center, One Research Circle (Bldg K1 Rm 4B31), Niskayuna, NY, 12309 (United States)], E-mail: timofeev@pobox.spbu.ru, E-mail: michael@crd.ge.com

    2008-08-07

    Spectral and electrical characteristics of a low pressure dc discharge formed from a mixture of one of the rare gases Ne, Ar or Kr plus water vapour are studied. Water vapour is only a minor additive to the rare gas. It has been shown that enhanced emission of the OH 306.4 nm band is registered from the discharge of Ar mixed with water vapour. Plasmas from the other investigated rare gases yielded considerably less OH 306.4 nm emission. Data about consumed electric power, spectra and relative efficiencies are presente000.

  12. Validation of gas temperature measurements by OES in an atmospheric air glow discharge with water electrode using Rayleigh scattering

    Energy Technology Data Exchange (ETDEWEB)

    Verreycken, T; Van Gessel, A F H; Pageau, A; Bruggeman, P, E-mail: p.j.bruggeman@tue.n [Eindhoven University of Technology, Department of Applied Physics, PO Box 513, 5600 MB Eindhoven (Netherlands)

    2011-04-15

    Rayleigh scattering is used to determine the gas temperature of an atmospheric pressure dc excited glow discharge in air with a water electrode. The obtained temperatures are compared with calculated rotational temperatures measured by optical emission spectroscopy of OH(A-X) and N{sub 2}(C-B). At a current of 15 mA a deviation is found between T{sub rot}(OH) and the gas temperature obtained from Rayleigh scattering of about 1000 K. The gas temperatures obtained from Rayleigh scattering, N{sub 2}(C) and OH(A) in the positive column are, respectively, 2600 {+-} 100 K, 2700 {+-} 150 K and 3600 {+-} 200 K. It is shown that the rotational temperature of N{sub 2}(C) is a reliable measurement of the gas temperature while this is not the case for OH(A). The results are explained in the context of quenching processes of the excited states. Spatially resolved gas temperatures in both longitudinal and radial directions are presented. The observed strong temperature gradients near the electrodes are checked to be consistent with the power dissipation and the heat transfer in the discharge. The effect of the polarity of the water electrode and filamentation on the measured temperatures is discussed.

  13. A procedure for estimating site specific derived limits for the discharge of radioactive material to the atmosphere

    CERN Document Server

    Hallam, J; Jones, J A

    1983-01-01

    Generalised Derived Limits (GDLs) for the discharge of radioactive material to the atmosphere are evaluated using parameter values to ensure that the exposure of the critical group is unlikely to be underestimated significantly. Where the discharge is greater than about 5% of the GDL, a more rigorous estimate of the derived limit may be warranted. This report describes a procedure for estimating site specific derived limits for discharges of radioactivity to the atmosphere taking into account the conditions of the release and the location and habits of the exposed population. A worksheet is provided to assist in carrying out the required calculations.

  14. Collisional Excitation and De-Excitation of N2 and N2+ in High-Pressure Discharge Plasmas

    Science.gov (United States)

    Kurunczi, P.; Abramzon, N.; Figus, M.; Becker, K.

    2003-05-01

    Emission spectroscopy using the 2nd positive system of N2 and the 1st negative system of N2+ can be used to determine important plasma parameters such the translational, vibrational, and rotational temperatures of the plasma species. The rotational temperature is perhaps the most frequently determined quantity as its determination may reflect the gas temperature in the plasma and/or provide insight into the reaction kinetics of important plasma species. If the emitting species are in equilibrium with the bulk gas in the plasma, then this temperature can be interpreted as the gas kinetic temperature in the plasma. We determined rotational temperatures for N2 and N2+ in high-pressure (400 Torr) discharges in mixtures in Ne with a trace admixture of N2. Significantly different values were obtained for respectively N2 and N2+. The relation of these rotational temperatures to the gas kinetic temperature and to the reaction kinetics leading to the formation and the decay of the emitting species will be discussed. We also carried out a rotational analysis of the unresolved N2 second positive system emitted by an atmospheric-pressure capillary plasma electrode (CPE) discharge in ambient air. Work supported by the US National Science Foundation.

  15. Determination of the elemental composition of micrometric and submicrometric particles levitating in a low pressure Radio-Frequency plasma discharge using Laser-Induced Breakdown Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Dutouquet, C., E-mail: Christophe.dutouquet@ineris.fr [Institut National de l' Environnement Industriel et des Risques (INERIS/DRC/CARA/NOVA), Parc Technologique Alata, BP 2, 60550 Verneuil-En-Halatte (France); Wattieaux, G. [Groupe de Recherches sur l' Énergétique des Milieux Ionisés (GREMI) UMR 6606, CNRS/Université d' Orléans, 14 rue d' Issoudun, BP 6744, 45067 Orléans Cedex 2 (France); Compagnie Industrielle des Lasers (CILAS), 8, avenue Buffon B.P. 6319 Z.I. La Source, 45063 Orleans (France); Meyer, L. [Groupe de Recherches sur l' Énergétique des Milieux Ionisés (GREMI) UMR 6606, CNRS/Université d' Orléans, 14 rue d' Issoudun, BP 6744, 45067 Orléans Cedex 2 (France); Frejafon, E. [Institut National de l' Environnement Industriel et des Risques (INERIS/DRC/CARA/NOVA), Parc Technologique Alata, BP 2, 60550 Verneuil-En-Halatte (France); Boufendi, L. [Groupe de Recherches sur l' Énergétique des Milieux Ionisés (GREMI) UMR 6606, CNRS/Université d' Orléans, 14 rue d' Issoudun, BP 6744, 45067 Orléans Cedex 2 (France)

    2013-05-01

    The LIBS (Laser-Induced Breakdown Spectroscopy) technique has shown its potential in many fields of applications including that of aerosol analysis. The latter is usually carried out on the particle flow, thereby allowing quantitative detection in various experimental conditions such as ambient air analysis or exhaust stack monitoring, to name but a few. A possible alternative method for particle analysis has been experimented combining a low pressure RF (Radio-Frequency) plasma discharge with the LIBS technique. Such approach has two peculiar features in comparison to the usual LIBS analysis. First, the particles injected in the RF plasma discharge are trapped in levitation. Second, the analysis is performed at a reduced pressure of around 1 mbar. LIBS detection at such low pressure has this peculiarity that particle vaporization is assumed to be achieved through direct laser particle interaction whereas it is caused by laser-induced plasma ignited in the gas at atmospheric pressure. The use of such particle trap could allow improving particle sampling, making organic particle analysis possible (by using an inert gas for RF plasma ignition) and even (depending on the pressure) obtaining a better signal to noise ratio. Detection of the elements of nanoparticle agglomerates made following their injection in the RF discharge has demonstrated the feasibility of such approach. Future experiments are intended to explore its potentialities when tackling issues such as process control or ambient air monitoring. - Highlights: ► Agglomerated composite nanoparticles are maintained in levitation within a trap. ► The trap consists in a low pressure Radio-Frequency (RF) plasma discharge. ► Particles are analyzed using Laser-Induced Breakdown Spectroscopy (LIBS). ► The analysis is done at RF discharge reduced pressure, namely 0.25 mbar.

  16. When API Mass Spectrometry Meets Super Atmospheric Pressure Ion Sources.

    Science.gov (United States)

    Chen, Lee Chuin

    2015-01-01

    In a tutorial paper on the application of free-jet technique for API-MS, John Fenn mentioned that "…for a number of years and a number of reasons, it has been found advantageous in many situations to carry out the ionization process in gas at pressures up to 1000 Torr or more" (Int. J. Mass Spectrom. 200: 459-478, 2000). In fact, the first ESI mass spectrometer constructed by Yamashita and Fenn had a counter-flow curtain gas source at 1050 Torr (ca. 1.4 atm) to sweep away the neutral (J. Phys. Chem. 88: 4451-4459, 1984). For gaseous ionization using electrospray plume, theoretical analysis also shows that "super-atmospheric operation would be more preferable in space-charge-limited situations."(Int. J. Mass Spectrom. 300: 182-193, 2011). However, electrospray and the corona-based chemical ion source (APCI) in most commercial instrument are basically operated under an atmospheric pressure ambient, perhaps out of the concern of safety, convenience and simplicity in maintenance. Running the ion source at pressure much higher than 1 atm is not so common, but had been done by a number of groups as well as in our laboratory. A brief review on these ion sources will be given in this paper.

  17. Simulation of polyatomic discharges for thin film deposition processes in low-pressure plasma reactors

    Science.gov (United States)

    Bera, Kallol

    Comprehensive multi-dimensional self-consistent numerical fluid models for radio-frequency capacitively and inductively coupled methane discharges were developed to predict diamond-like-carbon thin film deposition/etching rate on the wafer. A numerical model of glow discharge provides insight on the physical phenomena in the discharge leading to better understanding and design of the reactor. The developed discharge models included detailed discharge physics, gas-phase chemistry and surface chemistry modeling. To understand the basic discharge phenomena, one- dimensional radio frequency capacitively coupled Ar plasma was simulated using a fluid model. The model was modified for methane plasma to predict the profiles of the plasma variables. The model was then extended to two- dimensional cylindrical coordinates to capture the effects of asymmetry of the reactor on the plasma variables. The necessary dc bias for the discharge was predicted such that the cycle-averaged current to the powered electrode was zero. A discharge chemistry model was also developed to predict various radical and neutral densities in the plasma, and their fluxes to the cathode. The species fluxes are used to predict film deposition rate and the properties of the deposited film. The model predictions of plasma density, self-generated de bias, cathode current and plasma potential compared well with the experimental results. A high density plasma with inductive coupling at low pressure was also considered. Separate rf bias and dc bias are applied to the substrate holder to modulate the ion energy. The present model simulates electron, ion and neutral transport, including detailed discharge and surface chemistry. The model has been implemented for methane discharge to obtain deposition/etching of thin carbon film on the wafer. To the author's knowledge, this is the first attempt to simulate capacitively and inductively coupled plasmas self-consistently for a depositing gas under the operating

  18. Atmospheric pressure He-air plasma jet: Breakdown process and propagation phenomenon

    Energy Technology Data Exchange (ETDEWEB)

    Begum, Asma [Independent University, Bangladesh, School of Engineering and Computer Science, Bashundhara, Dhaka (Bangladesh); Laroussi, Mounir [Old Dominion University, Department of Electrical and Computer Engineering, Norfolk, Virginia (United States); Pervez, Mohammad Rasel [Master Mind College, Department of Physics, Dhanmondi, Dhaka (Bangladesh)

    2013-06-15

    In this paper He-discharge (plasma jet/bullet) in atmospheric pressure air and its progression phenomenon has been studied experimentally using ICCD camera, optical emission spectroscopy (OES) and calibrated dielectric probe measurements. The repetitive nanosecond pulse has applied to a plasma pencil to generate discharge in the helium gas channel. The discharge propagation speed was measured from the ICCD images. The axial electric field distribution in the plasma jet is inferred from the optical emission spectroscopic data and from the probe measurement. The correlation between the jet velocities, jet length with the pulse duration is established. It shows that the plasma jet is not isolated from the input voltage along its propagation path. The discharge propagation speed, the electron density and the local and average electric field distribution along the plasma jet axis predicted from the experimental results are in good agreement with the data predicted by numerical simulation of the streamer propagation presented in different literatures. The ionization phenomenon of the discharge predicts the key ionization parameters, such as speed, peak electric field in the front, and electron density. The maximum local electric field measured by OES is 95 kV/cm at 1.3 cm of the jet axis, and average EF measured by probe is 24 kV/cm at the same place of the jet. The average and local electron density estimated are in the order of 10{sup 11} cm{sup -3} and it reaches to the maximum of 10{sup 12} cm{sup -3}.

  19. Rice (Oryza sativa L.) Seed Sterilization and Germination Enhancement via Atmospheric Hybrid Nonthermal Discharge Plasma.

    Science.gov (United States)

    Khamsen, Natthaporn; Onwimol, Damrongvudhi; Teerakawanich, Nithiphat; Dechanupaprittha, Sanchai; Kanokbannakorn, Weerawoot; Hongesombut, Komsan; Srisonphan, Siwapon

    2016-08-01

    We designed a system to produce atmospheric hybrid cold-discharge plasma (HCP) based on microcorona discharge on a single dielectric barrier and applied it to inactivate microorganisms that commonly attach the rice seed husk. The cold-plasma treatment modified the surface of the rice seeds, resulting in accelerated germination and enhanced water imbibition. The treatment can operate under air-based ambient conditions without the need for a vacuum. The cold-plasma treatment completely inactivated pathogenic fungi and other microorganisms, enhancing the germination percentage and seedling quality. The final germination percentage of the treated rice seeds was ∼98%, whereas that of the nontreated seeds was ∼90%. Microcorona discharge on a single dielectric barrier provides a nonaggressive cold plasma that can be applied to organic materials without causing thermal and electrical damage. The hybrid nonthermal plasma is cost effective and consumes relatively little power, making it suitable for the surface sterilization and disinfection of organic and biological materials with large-scale compatibility.

  20. Pulsed positive discharges in air at moderate pressures near a dielectric rod

    Science.gov (United States)

    Dubinova, A.; Trienekens, D.; Ebert, U.; Nijdam, S.; Christen, T.

    2016-10-01

    We study pulsed positive discharges in air in a cylindrically symmetric setup with an electrode needle close (about 1 mm) above the top of a dielectric cylindrical rod of 4 mm in diameter mounted at its bottom on a grounded plate electrode. We present ICCD (intensified charge-coupled device) pictures and evaluations of experiments as well as simulations with a fluid discharge model; the simulations use cylindrical symmetry. In the experiments, there is an initial inception cloud phase, where the cylindrical symmetry is maintained, and later a streamer phase, where it is broken spontaneously. At 75-150 mbar, discharges with cylindrical symmetry are not attracted to the dielectric rod, but move away from it. The dielectric rod plays the sole role of an obstacle that shades (in the context of photoionization) a cone-shaped part of the inception cloud; the cone size is determined by the geometry of the setup. The material properties of the dielectric rod, such as its dielectric permittivity and the efficiency of the photon induced secondary electron emission do not have a noticeable effect. This is due to the abundance of photoionization in air, which supplies a positive discharge with free electrons and allows it to propagate along the electric field lines. Using some simple field calculations, we show that field enhancement due to dielectric polarization does not play a significant role in our geometry as long as the discharge maintains its cylindrical symmetry. The field component towards the rod is insufficiently enhanced to cause the discharge to move towards the rod. Any additional electrons produced by the dielectric surface do not influence this discharge morphology. This interpretation is supported by both experiments and simulations. At higher pressures (400-600 mbar) or for large