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Sample records for atmospheric pollution biomonitoring

  1. Epiphytic lichens as biomonitors of atmospheric pollution in Slovenian forests

    Energy Technology Data Exchange (ETDEWEB)

    Jeran, Z. [Department of Environmental Sciences, Jozef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia)]. E-mail: zvonka.jeran@ijs.si; Mrak, T. [Department of Environmental Sciences, Jozef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia); Jacimovic, R. [Department of Environmental Sciences, Jozef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia); Batic, F. [Department of Agronomy, Biotechnical Faculty, University of Ljubljana, Jamnikarjeva 101, 1000 Ljubljana (Slovenia); Kastelec, D. [Department of Agronomy, Biotechnical Faculty, University of Ljubljana, Jamnikarjeva 101, 1000 Ljubljana (Slovenia); Mavsar, R. [Slovenian Forestry Institute, Vecna pot 2, 1001 Ljubljana (Slovenia); Simoncic, P. [Slovenian Forestry Institute, Vecna pot 2, 1001 Ljubljana (Slovenia)

    2007-03-15

    Two country-wide surveys using epiphytic lichens as biomonitors of atmospheric pollution carried out during 2000 and 2001 in Slovenia were compared with surveys in 1991 and 1992. In the first survey, epiphytic lichen cover was studied in more than 500 plots of the 4 x 4 km national grid carried out within the framework of forest decline inventories. In the second survey, the epiphytic lichen Hypogymnia physodes (L.) Nyl., was collected on a 16 x 16 km bioindication grid and analysed for S, N, As, Br, Ce, Cd, Cr, K, La, Mo, Rb, Sb, Th, U and Zn contents. Only 'forested area' sampling points were included in the present study. Lichen cover was low, with about 70% of plots with less than 10% foliose lichen cover. No relationship was found between Hypogymnia trace element, N and S concentrations and foliose epiphytic lichen cover. - No relationship between Hypogymnia element concentrations and foliose epiphytic lichen cover was found.

  2. Biomonitoring of the atmospheric pollution by heavy metals in Morocco

    Science.gov (United States)

    Gaudry, A.; Senhou, A.; Chouak, A.; Cherkaoui, R.; Moutia, Z.; Lferde, M.; Elyahyaoui, A.; El Khoukhi, T.; Bounakhla, M.; Embarch, K.; Ayrault, S.; Moskura, M.

    2003-05-01

    In this study, the accumulation sensitivities of trace elements in six types of air pollution biomonitors (lichens, tree barks and a moss) are compared. Three analytical methods were used:14MeV neutron activation analysis, thermal neutron activation analysis method and X-ray fluorescence analysis. Studies of the local concentration variations versus the sizes of lichen and of their altitude of collection from grounds, revealed that a standardisation of the procedures for collecting samples was necessary.

  3. Atmospheric pollution in an urban environment by tree bark biomonitoring--part I: trace element analysis.

    Science.gov (United States)

    Guéguen, Florence; Stille, Peter; Lahd Geagea, Majdi; Boutin, René

    2012-03-01

    Tree bark has been shown to be a useful biomonitor of past air quality because it accumulates atmospheric particulate matter (PM) in its outermost structure. Trace element concentrations of tree bark of more than 73 trees allow to elucidate the impact of past atmospheric pollution on the urban environment of the cities of Strasbourg and Kehl in the Rhine Valley. Compared to the upper continental crust (UCC) tree barks are strongly enriched in Mn, Ni, Cu, Zn, Cd and Pb. To assess the degree of pollution of the different sites in the cities, a geoaccumulation index I(geo) was applied. Global pollution by V, Ni, Cr, Sb, Sn and Pb was observed in barks sampled close to traffic axes. Cr, Mo, Cd pollution principally occurred in the industrial area. A total geoaccumulation index I(GEO-tot) was defined; it is based on the total of the investigated elements and allows to evaluate the global pollution of the studied environment by assembling the I(geo) indices on a pollution map.

  4. The linear accumulation of atmospheric mercury by vegetable and grass leaves: Potential biomonitors for atmospheric mercury pollution.

    Science.gov (United States)

    Niu, Zhenchuan; Zhang, Xiaoshan; Wang, Sen; Ci, Zhijia; Kong, Xiangrui; Wang, Zhangwei

    2013-09-01

    One question in the use of plants as biomonitors for atmospheric mercury (Hg) is to confirm the linear relationships of Hg concentrations between air and leaves. To explore the origin of Hg in the vegetable and grass leaves, open top chambers (OTCs) experiment was conducted to study the relationships of Hg concentrations between air and leaves of lettuce (Lactuca sativa L.), radish (Raphanus sativus L.), alfalfa (Medicago sativa L.) and ryegrass (Lolium perenne L.). The influence of Hg in soil on Hg accumulation in leaves was studied simultaneously by soil Hg-enriched experiment. Hg concentrations in grass and vegetable leaves and roots were measured in both experiments. Results from OTCs experiment showed that Hg concentrations in leaves of the four species were significantly positively correlated with those in air during the growth time (p  0.05). Thus, Hg in grass leaves is mainly originated from the atmosphere, and grass leaves are more suitable as potential biomonitors for atmospheric Hg pollution. The effect detection limits (EDLs) for the leaves of alfalfa and ryegrass were 15.1 and 22.2 ng g(-1), respectively, and the biological detection limit (BDL) for alfalfa and ryegrass was 3.4 ng m(-3).

  5. Evaluation of Tillandsia capillaris Ruiz amd Pav. f. capillaris as biomonitor of atmospheric pollution in Argentina

    Energy Technology Data Exchange (ETDEWEB)

    Pignata, M.L. [Univ. Nacional de Cordoba, Cordoba (Argentina). Facultad de Ciencias Exactas, Fisicas y Naturales]|[Instituto Multidisciplinario de Biologia Vegetal (IMBIV-UNC), Cordoba (Argentina); Wannaz, E.D.; Martinez, M.S.; Caminotti, G. [Univ. Nacional de Cordoba, Cordoba (Argentina). Facultad de Ciencias Exactas, Fisicas y Naturales

    2002-07-01

    The behaviour of Tillandsia capillaris Ruiz and Pav. f. capillaris, when exposed to atmospheric pollutants, was assessed by measuring chemical parameters indicating foliar damage and the contents of some heavy metals. Samples were transplanted to three sites in the City of Cordoba and were collected back after 15, 30, 60 and 90 days of exposure. At the same time, samples coming from the collection site were analyzed for each of said exposure times. Chlorophylls, hydroperoxy conjugated dienes, water contents, malondialdehyde, sulfur, Cu, Pb, Ni, Co, Mn, Zn and Fe were measured in the samples. A Foliar Damage Index was calculated from some of these parameters. (orig.)

  6. Biomonitoring of atmospheric pollution by moss bags: Discriminating urban-rural structure in a fragmented landscape.

    Science.gov (United States)

    Capozzi, F; Giordano, S; Di Palma, A; Spagnuolo, V; De Nicola, F; Adamo, P

    2016-04-01

    In this paper we investigated the possibility to use moss bags to detect pollution inputs - metals, metalloids and polycyclic aromatic hydrocarbons (PAHs) - in sites chosen for their different land use (agricultural, urban/residential scenarios) and proximity to roads (sub-scenarios), in a fragmented conurbation of Campania (southern Italy). We focused on thirty-nine elements including rare earths. For most of them, moss uptake was higher in agricultural than in urban scenarios and in front road sites. Twenty PAHs were analyzed in a subset of agricultural sites; 4- and 5-ringed PAHs were the most abundant, particularly chrysene, fluoranthene and pyrene. Overall results indicated that investigated pollutants have a similar spatial distribution pattern over the entire study area, with road traffic and agricultural practices as the major diffuse pollution sources. Moss bags proved a very sensitive tool, able to discriminate between different land use scenarios and proximity to roads in a mixed rural-urban landscape.

  7. Assessment of atmospheric metallic pollution in the metropolitan region of Sao Paulo, Brazil, employing Tillandsia usneoides L. as biomonitor

    Energy Technology Data Exchange (ETDEWEB)

    Figueiredo, A.M.G. [Instituto de Pesquisas Energeticas e Nucleares, IPEN-CNEN/SP, Av. Prof. Lineu Prestes 2242, CEP 05508-000, Sao Paulo, SP (Brazil)]. E-mail: anamaria@ipen.br; Nogueira, C.A. [Instituto de Pesquisas Energeticas e Nucleares, IPEN-CNEN/SP, Av. Prof. Lineu Prestes 2242, CEP 05508-000, Sao Paulo, SP (Brazil); Saiki, M. [Instituto de Pesquisas Energeticas e Nucleares, IPEN-CNEN/SP, Av. Prof. Lineu Prestes 2242, CEP 05508-000, Sao Paulo, SP (Brazil); Milian, F.M. [Instituto de Fisica, Universidade de Sao Paulo, Rua do Matao, Travessa R, 187, Cidade Universitaria, CEP 05508-090, Sao Paulo, SP (Brazil); Domingos, M. [Instituto de Botanica, Av. Miguel Stefano No. 3687, CEP 04301-012, Sao Paulo, SP (Brazil)

    2007-01-15

    Tillandsia usneoides L. is an epiphytic bromeliad plant able to absorb water and nutrients directly from the air. For this reason this species was selected to carry out a monitoring study of air pollution in the metropolitan region of Sao Paulo, Brazil. Five consecutive transplantation experiments (8 weeks each) were performed in 10 sites of the city, submitted to different sources of air pollution (industrial, vehicular), using plants collected from an unpolluted area. After exposure, trace metals were analyzed in the plant by instrumental neutron activation analysis. Traffic-related elements such as Zn and Ba presented high concentrations in exposure sites near to heavy traffic avenues (cars, buses and trucks) and may be associated to vehicular sources. For Zn and Co the highest contents were related to industrial zones and can be associated to the presence of anthropogenic emission sources. The rare earth elements, Fe and Rb, probably have soil particles as main source. - This paper is the first work on the use of biomonitors to assess metal pollution in Sao Paulo, Brazil, the biggest city in Latin America.

  8. Atmospheric pollution biomonitoring of the Sao Paulo metropolitan region using epiphytic lichens; Uso de liquens epifiticos no biomonitoramento da poluicao atmosferica da regiao metropolitana de Sao Paulo

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    Fuga, Alessandra

    2006-07-01

    Due to the increasing problems of atmospheric pollution in the Sao Paulo metropolitan region that affect the environment and human health the application of biomonitoring methodologies using cosmopolite organisms has now become relevant. Biomonitoring is a method to evaluate the response of live organisms to pollution. This method offers advantages such as reduced costs, efficient monitoring of large geographic areas and accumulated pollutants over a large period in which low concentrations of chemicals elements in the environment can be evaluated. In the present study, neutron activation analysis method was applied to determine elements accumulated in Canoparmelia texana lichenized fungi. Samples were collected in two distinct areas: Carlos Botelho (PECB) and Intervales (PEI) State Parks that are considered as non-polluted areas and that belong to the Atlantic Forest - SP ecosystem; and Sao Paulo city metropolitan region in sites near automatic monitoring stations of the Environmental Protection Agency of the State of Sao Paulo (CETESB). The lichens collected from the bark of the trees were properly treated, and irradiated with neutrons from IEA-R1 nuclear reactor along with synthetic standards of elements. The precision and the accuracy of the results were evaluated by the analyses of IAEA-336 LICHEN and Mixed Polish Herbs (INCT -MPH-2) certified reference materials. The results obtained for these materials were in accordance with the certified values and presented good precision with variation coefficients ranging from 0.9 to 14.6%. Results obtained for lichens showed that elements As, Co, Cr, Cs, La, Mo, Sb, Sc, Se and U are present at ng g{sup -1} levels, Ba, Br, Cl, Fe, K, Mn, Na, Rb and Zn at {mu}g g{sup -1} and Ca at mg g{sup -1}. By applying cluster and discriminant analyses to the results for the lichen samples from areas with different levels of pollution, the sampling sites were grouped according to their chemical similarities and their elemental

  9. Monitoring atmospheric pollutants in the biosphere reserve Wienerwald by a combined approach of biomonitoring methods and technical measurements.

    Science.gov (United States)

    Krommer, Viktoria; Zechmeister, Harald G; Roder, Ingrid; Scharf, Sigrid; Hanus-Illnar, Andrea

    2007-05-01

    In this study a combined approach of bioindication results correlated with an extensive set of data on air pollution and climate was used to assess the pollution status of the Man and Biosphere Reserve Wienerwald (Austria). Bryophytes served as impact indicators (via the Index of Atmospheric Purity-method IAP) at 30 sites as well as accumulation monitors for airborne trace elements (Al, Pb, V, S, Zn, Fe, Cu, Cr, Ni, Co, Mo, Cd, As, Sb and 16 EPA-PAHs) at 10 sites within the reserve. The results of these bioindication methods were subsequently correlated with further pollution (NO(2), SO(2) and dust) and climate data (precipitation, temperature and humidity). The findings obtained clearly indicate the following: Bryophyte distribution is solely influenced by the status of air quality, without interference by climatic or site-related factors, which is in contrast to several previous investigations. IAP-values correlated significantly with NO(2) (0.553; P=0.004), SO(2) winter values (0.511; P=0.013) and PM10 (dust) (0.561; P=0.013). The results obtained via chemical analyses revealed a strong correlation with data derived from the IAP methodology. In terms of the overall air quality within the biosphere reserve Wienerwald, the north-eastern part appears to be the most affected one with a most likely pollution contribution emitted by the capital city Vienna, agriculture and neighbouring countries.

  10. Using the pollen viability and morphology for fluoride pollution biomonitoring.

    Science.gov (United States)

    Malayeri, Behrooz Eshghi; Noori, Mitra; Jafari, Mehrana

    2012-06-01

    The methods using plants for biomonitoring of air and soil quality are simple, cheap, and fast and can supplement the classical physicochemical methods. In this study, biological pollen characterization of some collected legume species from an aluminum smelter area in Iran (IRALCO) was carried out to determine the actual value of pollen as a bioindicator of the effects of soil and atmospheric pollution. Young buds and flowers of six legumes (Cercis siliquastrum L., Medicago sativa L., Robinia pseudoacacia L., Melilotus officinalis (L.) lam, Trifolium repens L., and Sophora alopecuroides L.) in polluted and control plants were removed and compared. Studies of light and electron microscopic preparation showed some abnormalities during pollen development in affect of fluoride pollution. The viability of pollen grains estimated by staining with acetocarmine shows sharp differences in smearing advanced pollen grains from abnormal ones. Except M. officinalis, the pollen grains of C. siliquastrum, M. sativa, R. pseudoacacia, T. repens, and S. alopecuroides in polluted areas showed light, partial, or no staining with acetocarmine, whereas almost all of the control ones clearly stained. Observation of the pollen grains by light microscopy and scanning electron microscopy showed the significant effect of fluoride on shapes and sizes of pollen grains. The stimulation and inhibition of these pollen characteristics depend on the pollen species as well as on the pollutant and its concentration. Therefore, pollen grains provide essential information on biological impact of pollutants and they are good candidates for biomonitoring the atmospheric and edaphic pollutions.

  11. Biomonitoring of nitrogen pollution. Possibilities and limitations of bioindication techniques; Biomonitoring von Stickstoffimmissionen. Moeglichkeiten und Grenzen von Bioindikationsverfahren

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    Mohr, K. [Landwirtschaftskammer Niedersachsen, Oldenburg (Germany)

    2007-10-15

    Background and aim. Air pollution caused by oxidized and reduced nitrogen is distributed over wide areas of Europe at a high level. As an alternative or complement to physical measurements and modelling calculations, biomonitoring with plants provides techniques to assess amounts and effects of pollution from oxidized and reduced nitrogen compounds (depositions and concentrations). Many of the previously implemented techniques are based on well-proven standardised methods, e.g. documented in VDI guidelines, modified more or less for a biomonitoring of atmospheric nitrogen pollution. This paper gives a review of the techniques for a biomonitoring of atmospheric nitrogen pollution, their possibilities as well as their limitations. Main features - diversity of the ground vegetation - nitrogen accumulation in vascular plants - exposure of vascular plants - mapping of epiphytic lichens, bryophytes and algae - nitrogen accumulation in lichens and bryophytes - exposure of lichens and bryophytes. Results and Discussion. Important response parameters are nitrogen concentrations in plant tissue (shoot, needle, leave) and biodiversity of plant species. These responses of vascular plants in many cases are influenced by other local varying conditions, in particular the soil. The exposure of vascular plants over a short period provides a standardised quantification of the total atmospheric nitrogen input in a model ecosystem. The enrichment of nitrogen in the plant tissue of bryophytes and lichens from the ground vegetation is closely correlated with the amount of nitrogen deposition. The diversity of epiphytic lichens and the response of exposed Hypogymnia physodes is more sensitive to ammonia than to nitrous oxide, whereas with the diversity of epiphytic bryophytes or the abundance of algae no significant correlation with atmospheric N pollution were found. Conclusions. Some bioindication techniques provide a cause-effect related, partly standardised biomonitoring of nitrogen

  12. Analysis of epiphytic lichen species for atmospheric pollutant biomonitoring use; Analise de especies de liquens epifiticos para uso na biomonitoracao de poluentes atmosfericos

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    Fuga, Alessandra; Saiki, Mitiko; Vasconcelos, Marina B.A. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil). Supervisao de Radioquimica; Honda, Neil K.; Siqueira, Onofre S. [Mato Grosso do Sul Univ., Campo Grande, MS (Brazil). Dept. de Quimica

    2002-07-01

    Lichens are recognized as potential indicators of air pollution and they have been widely studied to be used as biomonitor of heavy metals. In this work, neutron activation analysis method was applied in the analysis of epiphytic lichen species Usnea meridionalis, Parmotrema tinctorum and Parmotrema dilatatum, collected in Vila Piraputanga, MS, Brazil. Concentrations of the elements Al, Br, Ca, Cl, Fe, K, Mg, Mn, Na, Rb, V and Zn were determined at the levels of {mu}g g{sup -1} and As, Cs, Cr, Co, Hf, Mo, Sb, Sc, Se, Th and lanthanide elements at ng g{sup -1} levels. Results obtained showed that these three lichen species could be used in the environmental biomonitoring purposes. The precision and the accuracy of the results were also evaluated by analyzing certified reference materials IAEA 336 Lichen and 1547 NIST Peach Leaves. (author)

  13. Environmental lichenology: Biomonitoring trace-element air pollution

    Energy Technology Data Exchange (ETDEWEB)

    Sloof, J.E.

    1993-09-27

    Chapter 1 describes the possibilities to study trace-element air pollution in order to get insight in the character and element levels of such pollution. Chapter 2 describes two monitoring surveys using Parmelia sulcata Taylor on a national scale, in which spatial and temporal patterns of heavy metals were investigated. The surveys were carried out in 1982-1983 at 110 sampling sites and in 1986-1987 at 210 sampling sites. From these studies it was concluded that lichens are at least good qualitative biomonitors for atmospheric trace-element levels. Chapter 3 describes the response of lichens to the cesium-137 activity as a result of the Chernobyl accident, deposited by rainfall in the Netherlands. From this study it was concluded that lichens are good biomonitors for atmospheric cesium-137 activity too. Chapter 4 describes the application of factor analysis to a lichen data set from a monitoring survey on a national scale (1986-1987), for source apportionment. In Chapter 5 a field study is described on the contribution of a possible influence from the soil to element concentrations in Parmelia sulcata Taylor growing on trees in a an area with polluted soil. Chapter 6 describes a field study on the interchangeability of two tolerant lichen species (Parmelia sulcata Taylor and Lecanora conizaeoides Nyl.) in a polluted area. In Chapter 7 a field study is described in which the quantitative relationships between concentrations of cobalt, scandium and zinc in lichens and concentrations in air particulate matter and total deposition (wet and dry) were investigated. Chapter 8 describes a laboratory study on the kinetics of the uptake-and release of cadmium in a green algae species (Selenastrum capricornutum Printz), which is regarded to be representative for the algal symboint in the lichens used in this thesis. Chapter 9 presents the central conclusions of this thesis for the lichen species, elements and conditions under study. (orig./MG).

  14. Influência de poluentes atmosféricos em Belo Jardim (PE utilizando Cladonia verticillaris (líquen como biomonitor Influence of atmospheric pollutants in Belo Jardim (PE using Cladonia verticillaris (lichen as biomonitor

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    Fernando de Oliveira Mota Filho

    2007-10-01

    Full Text Available Cladonia verticillaris used in this study was collected in the cerrado vegetation of Saloá (PE, Brazil and transplanted in plastic containers on soil from the collection place to Belo Jardim (PE that possesses lead smelters and battery industries. The experiments were disposed at eleven different places for evaluating the dispersion of pollutants and their effects on the biomonitor. The exposed lichens were collected over eight months and submitted to thin layer and high performance liquid chromatographies, and scanning electron microscopy. C. verticillaris placed in the vicinity of the emission sources demonstrated alteration in its metabolism, decreasing the production of its major compound, fumarprotocetraric acid, and deterioration of its external and internal surfaces.

  15. [Air pollution biomonitoring with plants and fungi: concepts and uses].

    Science.gov (United States)

    Cuny, D

    2012-07-01

    Air pollution remains a major environmental concern of the French. Since about 30 years, due to evolution and diversification of sources, pollution became more and more complex, constituting a true "cocktail". Today, it is very important to know environmental and health effects of this cocktail. In this context air biomonitoring using plants and fungi can bring a lot of information. Biomonitoring includes four concepts: the use of biomarkers, bioindication biointegration and bioaccumulation. These four concepts are articulated according to the levels of biological organization, what links up biosurveillance on fundamental plan with ecotoxicology. It is a complementary approach of the physicochemical techniques of air pollution measurements. The main objectives of biomonitoring studies are the monitoring of the space and temporal distribution of pollutants effect; the monitoring of local sources; participation in the health risks assessment; the information of people and the help to decision in public policies. Biomonitoring of air quality is a method, which made its proof in numerous domains of application and brings fundamental information on the impacts of the quality of air. Recent evolution of low concerning biggest industries allows us to envisage the increase of air quality biomonitoring with plants and fungi applications in the field of the valuation of environmental and health risks. The recent normalization (French and European) of different methods will also allow the development of uses.

  16. Is there a future for biomonitoring of elemental air pollution? A review focused on a larger-scaled health-related (epidemiological) context

    NARCIS (Netherlands)

    Wolterbeek, B.; Sarmento, S.; Verburg, T.

    2010-01-01

    The present paper focuses on biomonitoring of elemental atmospheric pollution, which is reviewed in terms of larger-scaled biomonitoring surveys in an epidemiological context. Based on the literature information, today’s availability of solar-powered small air filter samplers and fibrous ion exchang

  17. Leaves of Phragmites australis as potential atmospheric biomonitors of Platinum Group Elements.

    Science.gov (United States)

    Bonanno, Giuseppe; Pavone, Pietro

    2015-04-01

    The increasing emissions of Platinum Group Elements (PGEs), namely Pt, Pd and Rh, may pose a significant risk to ecosystem processes and human health. A periodic assessment of PGEs distribution in the environment is thus of the utmost importance for the implementation of timely measures of mitigation. Although several studies have quantified PGEs in different life forms such as mammals, birds, fish, crustaceans, algae, mosses and even human beings, data about vascular plants need further surveys. This study aimed to test the suitability of the grass Phragmites australis (common reed) as a biomonitor of PGEs atmospheric pollution. The results showed that Pd and Pt concentrations in leaves are significantly higher in urban areas. In particular, Pd showed the highest range of values in line with current studies that consider palladium as the main element of traffic-related pollution. Overall, the leaves of Phragmites australis reflected the different gradient of PGEs emissions, and may thus be considered as potential biomonitors of atmospheric pollution.

  18. Assessment of atmospheric metallic pollution in the metropolitan region of Sao Paulo, Brazil, employing Tillandsia usneoides L. as biomonitor; Avaliacao da poluicao atmosferica por metais na regiao metropolitana de Sao Paulo, Brasil, utilizando a bromelia Tillandsia usneoides L. como biomonitor

    Energy Technology Data Exchange (ETDEWEB)

    Nogueira, Claudio Ailton

    2006-07-01

    Tillandsia usneoides L. is an epiphytic bromeliad that lives on trees or other kinds of inert substrates, absorbing water and nutrients directly from the environment without roots. Due to its morphological and physiological characteristics, this species accumulates the pollutants present in the atmosphere. In the present work, Tillandsia usneoides was used as a bio monitor of metal atmospheric pollution in Sao Paulo, Brazil, which is the biggest city in South America with a population of 18 million inhabitants and a strong industrial activity. The urban area is polluted by industrial emissions but, according to the Environmental Protection Agency of the State of Sao Paulo (CETESB), the governmental agency of air quality control, regularly occurring emissions from about 7.8 million motor vehicles provide the principal source of air pollution. The Tillandsia samples were collected from an unpolluted area and were exposed bimonthly in 10 sites of the city with different pollution levels and in a control site. After exposure, trace metals were analyzed in the plant by instrumental neutron activation analysis and ICP-MS (Pb, Cd, Co, Cu, Ni, Sb e V). The results of the investigation showed a notable concentration of Co and Ni in the plants exposed in an industrial area where there is a metal processing plant, which produces about 600 tons/year of Co and 16,000 tons/year of Ni. Copper and chromium were equally distributed in industrial regions and in sites near heavy traffic avenues, suggesting that these elements can be associated to both vehicular and industrial sources. A high accumulation of Cd in the plant exposed in industrial areas indicates industrial activities as the main source of this element. For Pb, no evident sources could be identified so far as it was spread evenly along the monitoring sites. Traffic-related elements such as Zn, Ba and Sb presented high concentrations in plants exposed in sites near to heavy traffic avenues (cars, buses and trucks) and

  19. Manila clam Venerupis philippinarum as a biomonitor to metal pollution

    Institute of Scientific and Technical Information of China (English)

    WU Huifeng; JI Chenglong; WANG Qing; LIU Xiaoli; ZHAO Jianmin; FENG Jianghua

    2013-01-01

    The Manila clam Venerupis philippinarum is a good biomonitor/bioindicator to marine metal pollution and is frequently used in aquatic toxicology.Two dominant pedigrees (white and zebra) of clam are distributed in the Bohai Sea; however,little attention has been paid to potential biological differences between these two pedigrees.In this study,we tested the sensitivity of both pedigrees to marine metal (cadmium and zinc) pollution biomonitoring and marine environmental toxicology.Results demonstrate significant biological differences in gills of white and zebra clams based on metabolic profiles and antioxidant enzyme activities.In addition,we found that hypotaurine,malonate and homarine were relatively high in white clam gills,while alanine,arginine,glutamate,succinate,4-aminobutyrate,taurine and betaine were high in zebra clam gills.Zebra clam gills were also more sensitive to a mixture of Cd and Zn,as shown by antioxidant enzyme activities and metabolic profiles,but white clam gills could accumulate more Zn.Therefore,we suggest that the white pedigree can be used as a biomonitor to marine Zn pollution,whereas the zebra pedigree can be used for toxicology studies on Cd and Zn mixed pollution.

  20. Atmospheric Deposition of Trace Elements Around Ulan-Bator City Studied by Moss and Lichen Biomonitoring Technique and INAA

    CERN Document Server

    Ganbold, G; Gundorina, S F; Frontasyeva, M V; Ostrovnaya, T M; Pavlov, S S; Tsendeekhuu, T

    2005-01-01

    For the first time the moss and lichen biomonitoring technique has been applied to air pollution in Mongolia (Ulan-Bator, the capital city). INAA at the IBR-2 reactor has made it possible to determine the content of 35 elements in moss and lichen biomonitors. Samples collected at sites located 10-15 km from the center of Ulan-Bator were analyzed by Instrumental Neutron Activation Analysis (INAA) using epithermal neutrons. The mosses (\\textit{Rhytidium rugosum}, \\textit{Thuidium abietinum}, \\textit{Entodon concinnus}) and lichens (\\textit{Cladonia stellaris}, \\textit{Parmelia separata}) were used to study the atmospheric deposition of trace elements. It was shown that the suggested types of mosses could be used as suitable biomonitors to estimate the concentration levels of heavy metals and trace elements in Ulan-Bator atmospheric deposition. The results are compared to the data of atmospheric deposition of some European countries.

  1. Active biomonitoring of heavy metal pollution using Rosa rugosa plants

    Energy Technology Data Exchange (ETDEWEB)

    Calzoni, Gian Lorenzo [Dip. Biologia, Universita di Bologna, via Irnerio 42, 40126 Bologna (Italy)], E-mail: gianlorenzo.calzoni@unibo.it; Antognoni, Fabiana [Dip. Biologia, Universita di Bologna, via Irnerio 42, 40126 Bologna (Italy)], E-mail: fabiana.antognoni@unibo.it; Pari, Elena [Gruppo CSA-SpA, via al Torrente 22, Rimini (Italy)], E-mail: epari@csaricerche.com; Fonti, Paolo [Gruppo CSA-SpA, via al Torrente 22, Rimini (Italy)], E-mail: pfonti@csaricerche.com; Gnes, Antonio [ARPA - Agenzia Regionale Protezione Ambientale, Sez. Provinciale di Ravenna, via Alberoni 17, Ravenna (Italy)], E-mail: agnes@ra.arpa.emr.it; Speranza, Anna [Dip. Biologia, Universita di Bologna, via Irnerio 42, 40126 Bologna (Italy)], E-mail: anna.speranza@unibo.it

    2007-09-15

    The purpose of this work was to evaluate the quality of a rural area near Faenza (Italy) by using an active biomonitoring approach, i.e., by placing homogeneous individuals of the perennial shrub Rosa rugosa in different sites throughout the area. Further sites, within the city or its environs, were used for comparison. Soil and leaves of R. rugosa were analyzed for their heavy metal content. The total heavy metal pattern of leaves closely paralleled the pattern registered in soil, with the highest content (both in total and assimilable forms) at the site in the urban area, which is exposed to heavy traffic. Pollen quality (abortiveness and viability) was also tested as a potential indicator of pollution. Pollen abortiveness was strictly related to Pb levels in leaves, while viability was inversely related to leaf Cr content. Our results suggest that R. rugosa has the potential to be a good biomonitoring system. - Rosa rugosa leaves and pollen are - to different extents - suitable monitoring tools for heavy metal pollution.

  2. Monitoring temporal trends of air pollution in an urban area using mosses and lichens as biomonitors.

    Science.gov (United States)

    Gerdol, Renato; Marchesini, Roberta; Iacumin, Paola; Brancaleoni, Lisa

    2014-08-01

    Monitoring air quality by using living organisms as biomonitors has received increasing attention in recent years. However, rather few studies were based on the concomitant use of passive biomonitoring (based on the different sensitivity of living organisms to air pollution) and active biomonitoring (based on their capacity to accumulate pollutants in the tissues). We carried out a repeated survey of an urban area in Northern Italy, with the objective of comparing temporal trends of different kinds of air pollutants with bioindication (passive biomonitoring) and bioaccumulation (active biomonitoring) techniques. During a five-year interval, temporal patterns of moss metal concentrations underwent significant changes probably due to intercurring variations in the importance of different pollution sources. Nitrogen (N) concentration in moss tissues also decreased and was paralleled by increasing diversity of epiphytic lichens. Increasing δ(15)N in moss tissues suggested a higher contribution of oxidized N species compared with reduced N species.

  3. Potential of Opuntia ficus-indica for air pollution biomonitoring: a lead isotopic study.

    Science.gov (United States)

    El Hayek, Eliane; El Samrani, Antoine; Lartiges, Bruno; Kazpard, Veronique; Benoit, Mathieu; Munoz, Marguerite

    2015-11-01

    Opuntia ficus-indica (Ofi) is a long-domesticated cactus that is widespread throughout arid and semiarid regions. Ofi is grown for both its fruits and edible cladodes, which are flattened photosynthetic stems. Young cladodes develop from mother cladodes, thus forming series of cladodes of different ages. Therefore, successive cladodes may hold some potential for biomonitoring over several years the local atmospheric pollution. In this study, cladodes, roots, dust deposited onto the cladodes, and soil samples were collected in the vicinity of three heavily polluted sites, i.e., a fertilizer industry, the road side of a highway, and mine tailings. The lead content was analyzed using atomic absorption spectroscopy (AAS) and inductively coupled plasma-mass spectrometry (ICP-MS). Scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (SEM-EDX) was used to characterize the cladode surfaces and the nature of dust deposit, and the lead isotopes were analyzed to identify the origin of Pb. The results show that (i) Ofi readily bioaccumulates Pb, (ii) the lead isotopic composition of cladodes evidences a foliar pathway of lead into Ofi and identifies the relative contributions of local Pb sources, and (iii) an evolution of air quality is recorded with successive cladodes, which makes Ofi a potential biomonitor to be used in environmental and health studies.

  4. Air pollution biomonitoring survey in Morocco using k0-INAA

    Science.gov (United States)

    El Khoukhi, T.; Cherkaoui, R. M.; Gaudry, A.; Ayrault, S.; Senhou, A.; Chouak, A.; Moutia, Z.; Chakir, E.

    2004-01-01

    Environmental monitoring is an essential step in any economical and social development policy. The atmospheric pollution study is a principal task due to the importance of atmospheric transfer of pollutants. Geographically, Morocco is characterized by different micro-climates influencing, on one hand, the transfer range of trace elements and, on the other hand, the availability of biological organisms that can be used in trace element air pollution biodetection study. Tree-barks, lichens and mosses were used in this study to evaluate trace elements bioavailability in different regions of Morocco. Those organisms were analyzed using the multi-elemental k0-INAA technique. The quality control of the results was performed by the analysis of reference materials. The analysis results were interpreted in the form of enrichment factors reflecting the atmospheric availability of anthropogenic pollutant elements such as Cl, V, Cr, Zn, As, Se and Sr.

  5. Is there a future for biomonitoring of elemental air pollution? A review focused on a larger-scaled health-related (epidemiological) context.

    Science.gov (United States)

    Wolterbeek, Bert; Sarmento, Susana; Verburg, Tona

    The present paper focuses on biomonitoring of elemental atmospheric pollution, which is reviewed in terms of larger-scaled biomonitoring surveys in an epidemiological context. Based on the literature information, today's availability of solar-powered small air filter samplers and fibrous ion exchange materials is regarded as adequate or an even better alternative for biomonitor transplant materials used in small-scaled set-ups, but biomonitors remain valuable in larger-scaled set-ups and in unforeseen releases and accidental situations. In the latter case, in-situ biomonitoring is seen as the only option for a retrospective study: biomoniors are there before one even knows that they are needed. For biomonitoring, nuclear analytical techniques are discussed as key techniques, especially because of the necessary multi-element assessments in both source recognition and single-element interpretation. To live up to the demands in an epidemiological context, larger-scaled in-situ biomonitoring asks for large numbers of samples, and consequently, for large total sample masses, this all to ensure representation of both local situations and survey area characteristics. Possibly, this point should direct studies into new "easy-to-sample" biomonitor organisms, of which high masses and numbers may be obtained in field work, rather than continue with biomonitors such as lichens. This also means that both sample handling and processing are of key importance in these studies. To avoid problems in comparability of analytical general procedures in milling, homogenization and digestion of samples of large masses, the paper proposes to involve only few but high-quality laboratories in the total element assessment routines. In this respect, facilities that can handle large sample masses in the assessment of element concentrations are to be preferred. This all highlights the involvement of large-sample-volume nuclear facilities, which, however, should be upgraded and automated in their

  6. Heavy Metals and Trace Elements Atmospheric Deposition Studies in Tula Region Using Moss Biomonitors Technique

    CERN Document Server

    Ermakova, E V; Steinnes, E

    2002-01-01

    For the first time the moss biomonitors technique was used in air pollution studies in Tula Region (Central Russia), applying NAA, AAS. Moss samples were collected at 83 sites in accordance with the sampling strategy adopted in European projects on biomonitoring atmospheric deposition. A wide set of trace elements in mosses was determined. The method of epithermal neutron activation at IBR-2 reactor of FLNP JINR has made it possible to identify 33 elements (Na, Mg, Al, Cl, K, Ca, Sc, V, Cr, Mn, Fe, Co, Ni, Zn, As, Br, Rb, Sr, Mo, Sb, I, Cs, Ba, La, Ce, Sm, Tb, Yb, Hf, Ta, W, Th, U) in the large-scale concentration range - from 10000 ppm for K to 0,001 ppm for Tb and Ta. Cu, Cd and Pb were determined by the flame AAS in the Norwegian Institute of Science and Technology. Using the graphical technique and principal component analysis allowed to separate plant, crustal and general pollution components in the moss. The obtained data will be used for constructing coloured maps of the distribution of elements over t...

  7. Air Pollution Studies in Central Russia (Tula Region) Using Moss Biomonitoring Technique, NAA and AAS

    CERN Document Server

    Ermakova, E V; Steinnes, E

    2002-01-01

    For the first time the moss biomonitoring technique has been applied to air pollution monitoring in Central Russia (Tula Region). Moss samples were collected from 83 sites in accordance with the sampling strategy of European projects on biomonitoring of atmospheric deposition. Neutron activation analysis (NAA) at the IBR-2 reactor has made it possible to determine the concentration of 33 elements (Na, Mg, Al, Cl, K, Ca, Sc, V, Cr, Mn, Fe, Co, Ni, Zn, As, Br, Rb, Sr, Mo, Sb, I, Cs, Ba, La, Ce, Sm, Tb, Yb, Hf, Ta, W, Th, U) over a large concentration range (from 10000 mg/kg for K to 0.001 mg/kg for Tb and Ta). In addition to NAA, flame AAS (atomic absorption spectrometry) was applied to determine the concentration of Cd, Cu and Pb. Factor analysis was applied to determine possible sources of elements detected in the investigated mosses. Eight factors were identified. The geographical distribution of factor scores is presented. The interpretation of the factor analysis findings points to natural as well as anthr...

  8. The use of moss as biomonitors of atmospherical deposition in Romania. An example from the Eastern Carpathian mountains

    Energy Technology Data Exchange (ETDEWEB)

    Lucaciu, A. [' ' Horia Hulubei' ' National Institute of Physics and Nuclear Engineering, Bucharest (Romania)

    2004-07-01

    In the last thirty years, the use of naturally growing mosses as biomonitors in the study of atmospheric deposition of the heavy metals became a common method for monitoring air pollution. Naturally growing mosses have a primitive structure with no specialization of cells within the tissue. Mosses are able to concentrate and to solubilize some chemical species of environmental pollutants. Because the contact between the moss and the soil (or rock) is very weak, it is possible that the moss can not absorb notable quantities of metal ions from the soil. (orig.)

  9. Guidelines for biomonitoring persistent organic pollutants (POPs), using lichens and aquatic mosses--a review.

    Science.gov (United States)

    Augusto, Sofia; Máguas, Cristina; Branquinho, Cristina

    2013-09-01

    During the last decades, awareness regarding persistent organic pollutants (POPs), such dioxins and furans (PCDD/Fs) and polycyclic aromatic hydrocarbons (PAHs), has become a cutting-edge topic, due to their toxicity, bioaccumulation and persistency in the environment. Monitoring of PCDD/Fs and PAHs in air and water has proven to be insufficient to capture deposition and effects of these compounds in the biota. To overcome this limitation, environmental biomonitoring using lichens and aquatic mosses, have aroused as promising tools. The main aim of this work is to provide a review of: i) factors that influence the interception and accumulation of POPs by lichens; ii) how lichens and aquatic bryophytes can be used to track different pollution sources and; iii) how can these biomonitors contribute to environmental health studies. This review will allow designing a set of guidelines to be followed when using biomonitors to assess environmental POP pollution.

  10. Hg localisation in Tillandsia usneoides L. (Bromeliaceae), an atmospheric biomonitor

    Energy Technology Data Exchange (ETDEWEB)

    Filho, G.M.A. [Instituto de Pesquisas Jardim Botanico do Rio de Janeiro (Brazil). Programa Zona Costeira; Andrade, L.R.; Farina, M. [Cidade Universitaria, Rio de Janeiro (Brazil). Instituto de Ciencias Biomedicas, Departamento de Anatomia; Malm, O. [Cidade Universitaria, Rio de Janeiro (Brazil). Instituto de Biofisica Carlos Chagas Filho, Laboratorio de Radioisotopos Eduardo Penna Franca

    2002-07-01

    The Spanish moss, Tillandsia usneoides, has been applied as an atmospheric biomonitor of Hg contamination, although the mechanism of metal plant accumulation has not been understood until now. In the present work, analytical scanning electron microscopy (SEM) was used to localize Hg in T. usneoides exposed to a Hg-air-contaminated area during 15 days. After this period, Hg was determined by the flow injection mercury system, and plants were prepared for SEM observation and energy-dispersive X-ray analysis. A concentration of 2702{+-}318{mu}g Hgg{sup -1} was determined in exposed plants. The presented microanalytical results demonstrated that Hg was partly associated with atmospheric particles deposited upon the plant surface, but it was highly absorbed by the scales, stem and leaves surfaces and less absorbed by epidermal cells of T. usneoides. No Hg was detected in mesophyll parenchyma or in vascular system cells. The great surface adsorption area provided by the scales, in addition to the characteristics of T. usneoides morphology, especially of the node region, are suggested to confer the great capability of T. usneoides in Hg holding. (author)

  11. Testing benthic foraminiferal distributions as a contemporary quantitative approach to biomonitoring estuarine heavy metal pollution.

    Science.gov (United States)

    Foster, William J; Armynot du Châtelet, Eric; Rogerson, Mike

    2012-05-01

    Biomonitoring of estuarine pollution is the subject of active research, and benthic foraminifera are an attractive group to use for these purposes due to their ubiquitous presence in saline water and wide diversity. Here, we describe a case study of biomonitoring using benthic foraminifera in the French Mediterranean lagoon, Bages-Sigean lagoon. In this case, the major pollutants of interest are heavy metals in the sediment, particularly contaminated by Cu and Cd derived from industrial and agricultural sources. The foraminiferal assemblages of the Bages-Sigean lagoon are typical of normal paralic environments, but unusually almost completely lack agglutinated forms. The density of benthic foraminifera was shown to be more influenced by the sediment characteristics rather than heavy metal pollution. However, the relative abundance of Quinqueloculina bicostata was shown to increase in the most polluted areas and we propose that this taxon may be used as an indicator of heavy metal pollution.

  12. Assessment of heavy metal pollution in Córdoba (Spain) by biomonitoring foraging honeybee.

    Science.gov (United States)

    Gutiérrez, Miriam; Molero, Rafael; Gaju, Miquel; van der Steen, Josef; Porrini, Claudio; Ruiz, José Antonio

    2015-10-01

    Due to features that make them outstanding environmental bioindicator, colonies of Apis mellifera are being used to study environmental pollution. The primary objective of this research was to use honeybee colonies to identify heavy metals and determine their utility for environmental management. Five stations each with two A. mellifera hives were strategically located in urban, industrial, agricultural and forested areas within the municipality of Córdoba (Spain), and foraging bees were collected from April to December in 2007, 2009 and 2010 to analyse spatial and temporal variation in Pb, Cr, Ni and Cd pollution. Metal concentrations, in milligram per kilogram of honeybee, were determined by inductively coupled plasma-atomic emission spectrometry and graphite furnace atomic absorption spectrophotometry. Significant differences in concentrations were found among the various locations and periods. The highest number of values exceeding the upper reference thresholds proposed for this study (Pb, 0.7 mg/kg; Cr, 0.12 mg/kg; Ni, 0.3 mg/kg; and Cd, 0.1 mg/kg) was observed for Pb and Cr (6.25% respectively), station S4 (13.22%), year 2007 (20.83%) and in months of May and July (11.90% each). Regarding the Cd, which was analysed only in 2010, the highest number of values exceeding the upper reference thresholds was 40%. Biomonitoring with colonies of A. mellifera could contribute to improved surveillance and control systems for atmospheric pollution by integrating qualitative and quantitative assessments, thus facilitating prevention and readiness in the event of environmental crises.

  13. Biomonitoring spatial and temporal impact of atmospheric dust from a cement industry

    Energy Technology Data Exchange (ETDEWEB)

    Branquinho, Cristina [Universidade de Lisboa, Faculdade de Ciencias, Centro de Ecologia e Biologia Vegetal, Campo Grande, Edificio C2, Piso 4, 1749-016 Lisbon (Portugal); Universidade Atlantica, Antiga Fabrica da Polvora de Barcarena, 2745-615 Barcarena (Portugal)], E-mail: cmbranquinho@fc.ul.pt; Gaio-Oliveira, Gisela; Augusto, Sofia; Pinho, Pedro; Maguas, Cristina; Correia, Otilia [Universidade de Lisboa, Faculdade de Ciencias, Centro de Ecologia e Biologia Vegetal, Campo Grande, Edificio C2, Piso 4, 1749-016 Lisbon (Portugal)

    2008-01-15

    The objective of this work was to evaluate the spatial and temporal impact of dust-pollution in the vicinity of a cement industry, located in an area with dry climate. The spatial impact integrated over time was evaluated from the concentrations of Ca, Fe and Mg in in-situ Xanthoria parietina. The temporal pattern was assessed through one-month transplants of the lichen Ramalina canariensis. Four potential sources of atmospheric dust were evaluated: the limestone-quarry; the unpaved roads, the deposit area and the cement mill. Calcium concentration in lichens was considered the best cement-dust indicator. Different types of dust (clinker and grinded-limestone-dust) resulted in different time-patterns of Ca accumulation, which was also related with the different influence that wet and dry periods have in the lichen accumulation process. The dust pollution was found to be deposited locally and dependent on: the nature of dust particles and the volume and frequency of precipitation. - Biomonitoring Spatial and Temporal dust emissions in dry climates.

  14. Framework for using deciduous tree leaves as biomonitors for intraurban particulate air pollution in exposure assessment.

    Science.gov (United States)

    Gillooly, Sara E; Shmool, Jessie L Carr; Michanowicz, Drew R; Bain, Daniel J; Cambal, Leah K; Shields, Kyra Naumoff; Clougherty, Jane E

    2016-08-01

    Fine particulate matter (PM2.5) air pollution, varying in concentration and composition, has been shown to cause or exacerbate adverse effects on both human and ecological health. The concept of biomonitoring using deciduous tree leaves as a proxy for intraurban PM air pollution in different areas has previously been explored using a variety of study designs (e.g., systematic coverage of an area, source-specific focus), deciduous tree species, sampling strategies (e.g., single day, multi-season), and analytical methods (e.g., chemical, magnetic) across multiple geographies and climates. Biomonitoring is a low-cost sampling method and may potentially fill an important gap in current air monitoring methods by providing low-cost, longer-term urban air pollution measures. As such, better understanding of the range of methods, and their corresponding strengths and limitations, is critical for employing the use of tree leaves as biomonitors for pollution to improve spatially resolved exposure assessments for epidemiological studies and urban planning strategies.

  15. The use of conifer needles as biomonitor candidates for the study of temporal air pollution variation in the Strasbourg region.

    Science.gov (United States)

    Al-Alam, Josephine; Fajloun, Ziad; Chbani, Asma; Millet, Maurice

    2017-02-01

    The continuous emission of polluting chemicals into the atmosphere requires the implementation of monitoring of ambient air quality. The use of vegetation for environmental monitoring can be considered as a simple monitoring technique by providing a cheap and accessible matrix. In this study, needles of two conifers (Pinus nigra and Cedrus atlantica), were used for the consecutive biomonitoring of multipollutants such as pesticides, polychlorinated biphenyls, and polyaromatic hydrocarbons (PAHs) in an urban area in Strasbourg (France). The extraction was performed by accelerated solvent extraction, solid-phase extraction, and solid-phase microextraction and was followed by gas chromatography coupled to tandem mass spectrometry and liquid chromatography coupled to tandem mass spectrometry analyses. The results obtained for conifer samples collected in 5 successive weeks (April 09-May 07, 2015) show a similar variation of the different types of pollutants. A pollution peak was observed during the second week of analysis, and the concentration of all pollutants then decreased to complete disappearance at the end of the sampling period. PAHs were the most concentrated with a total concentration of about 35.87 ng g(-1), and naphthalene was, among these pollutants, the most concentrated with a total concentration of about 15.1 ng g(-1). The analysis of meteorological data during this period suggests that the results correlated with climatic conditions that widely vary during this period of the year. The results show that the concentration peak was obtained when no precipitation was detected.

  16. Intra-urban biomonitoring: Source apportionment using tree barks to identify air pollution sources.

    Science.gov (United States)

    Moreira, Tiana Carla Lopes; de Oliveira, Regiani Carvalho; Amato, Luís Fernando Lourenço; Kang, Choong-Min; Saldiva, Paulo Hilário Nascimento; Saiki, Mitiko

    2016-05-01

    It is of great interest to evaluate if there is a relationship between possible sources and trace elements using biomonitoring techniques. In this study, tree bark samples of 171 trees were collected using a biomonitoring technique in the inner city of São Paulo. The trace elements (Al, Ba, Ca, Cl, Cu, Fe, K, Mg, Mn, Na, P, Rb, S, Sr and Zn) were determined by the energy dispersive X-ray fluorescence (EDXRF) spectrometry. The Principal Component Analysis (PCA) was applied to identify the plausible sources associated with tree bark measurements. The greatest source was vehicle-induced non-tailpipe emissions derived mainly from brakes and tires wear-out and road dust resuspension (characterized with Al, Ba, Cu, Fe, Mn and Zn), which was explained by 27.1% of the variance, followed by cement (14.8%), sea salt (11.6%) and biomass burning (10%), and fossil fuel combustion (9.8%). We also verified that the elements related to vehicular emission showed different concentrations at different sites of the same street, which might be helpful for a new street classification according to the emission source. The spatial distribution maps of element concentrations were obtained to evaluate the different levels of pollution in streets and avenues. Results indicated that biomonitoring techniques using tree bark can be applied to evaluate dispersion of air pollution and provide reliable data for the further epidemiological studies.

  17. Ecological, morphological, and histological studies on Blaps polycresta (Coleoptera: Tenebrionidae) as biomonitors of cadmium soil pollution.

    Science.gov (United States)

    Osman, Wafaa; El-Samad, Lamia M; Mokhamer, El-Hassan; El-Touhamy, Aya; Shonouda, Mourad

    2015-09-01

    Soil pollution in Egypt became far more serious than before due to either the heavy usage of different toxic pesticides or aerosol deposition of industrial pollutants. The present mentioned ground beetle, Blaps polycresta Tschinkel 1975 (Coleoptera: Tenebrionidae), showed ecological, morphological, and histological alterations in adult insects as biomonitors. Two cultivated sites (reference and polluted) were chosen for sampling the insects. The results indicated a significant increase in soil cadmium concentration of the polluted site leading to sex-specific difference in cadmium accumulation in gonads and alimentary canal of insects that being higher in males than females. The cadmium pollution leads significantly to a decrease in population density, a reduction in body weight, an increase in mortality rate, and an increase in sex ratio of the insects. The results also revealed a striking decrease in body length of the polluted insects with a marked increase in the percentage of deformed gonads and alimentary canal of both sexes. Some histopathological alterations were also recorded in testis, ovary, and midgut of the polluted insects. Our results confirmed that beetles are a good bioindicator for soil pollution, and the different studied parameters could be easily employed as sensitive monitors for cadmium soil pollution.

  18. Atmospheric Chemistry and Air Pollution

    Directory of Open Access Journals (Sweden)

    Jeffrey S. Gaffney

    2003-01-01

    Full Text Available Atmospheric chemistry is an important discipline for understanding air pollution and its impacts. This mini-review gives a brief history of air pollution and presents an overview of some of the basic photochemistry involved in the production of ozone and other oxidants in the atmosphere. Urban air quality issues are reviewed with a specific focus on ozone and other oxidants, primary and secondary aerosols, alternative fuels, and the potential for chlorine releases to amplify oxidant chemistry in industrial areas. Regional air pollution issues such as acid rain, long-range transport of aerosols and visibility loss, and the connections of aerosols to ozone and peroxyacetyl nitrate chemistry are examined. Finally, the potential impacts of air pollutants on the global-scale radiative balances of gases and aerosols are discussed briefly.

  19. Impacts of particulate matter pollution on plants: Implications for environmental biomonitoring.

    Science.gov (United States)

    Rai, Prabhat Kumar

    2016-07-01

    Air pollution is one of the serious problems world is facing in recent Anthropocene era of rapid industrialization and urbanization. Specifically particulate matter (PM) pollution represents a threat to both the environment and human health. The changed ambient environment due to the PM pollutant in urban areas has exerted a profound influence on the morphological, biochemical and physiological status of plants and its responses. Taking into account the characteristics of the vegetation (wide distribution, greater contact area etc.) it turns out to be an effective indicator of the overall impact of PM pollution and harmful effects of PM pollution on vegetation have been reviewed in the present paper, covering an extensive span of 1960 to March 2016. The present review critically describes the impact of PM pollution and its constituents (e.g. heavy metals and poly-aromatic hydrocarbons) on the morphological attributes such as leaf area, leaf number, stomata structure, flowering, growth and reproduction as well as biochemical parameters such as pigment content, enzymes, ascorbic acid, protein, sugar and physiological aspect such as pH and Relative water content. Further, the paper provides a brief overview on the impact of PM on biodiversity and climate change. Moreover, the review emphasizes the genotoxic impacts of PM on plants. Finally, on the basis of such studies tolerant plants as potent biomonitors with high Air Pollution Tolerance Index (APTI) and Air Pollution Index (API) can be screened and may be recommended for green belt development.

  20. Environmental epigenetics: A promising venue for developing next-generation pollution biomonitoring tools in marine invertebrates.

    Science.gov (United States)

    Suarez-Ulloa, Victoria; Gonzalez-Romero, Rodrigo; Eirin-Lopez, Jose M

    2015-09-15

    Environmental epigenetics investigates the cause-effect relationships between specific environmental factors and the subsequent epigenetic modifications triggering adaptive responses in the cell. Given the dynamic and potentially reversible nature of the different types of epigenetic marks, environmental epigenetics constitutes a promising venue for developing fast and sensible biomonitoring programs. Indeed, several epigenetic biomarkers have been successfully developed and applied in traditional model organisms (e.g., human and mouse). Nevertheless, the lack of epigenetic knowledge in other ecologically and environmentally relevant organisms has hampered the application of these tools in a broader range of ecosystems, most notably in the marine environment. Fortunately, that scenario is now changing thanks to the growing availability of complete reference genome sequences along with the development of high-throughput DNA sequencing and bioinformatic methods. Altogether, these resources make the epigenetic study of marine organisms (and more specifically marine invertebrates) a reality. By building on this knowledge, the present work provides a timely perspective highlighting the extraordinary potential of environmental epigenetic analyses as a promising source of rapid and sensible tools for pollution biomonitoring, using marine invertebrates as sentinel organisms. This strategy represents an innovative, groundbreaking approach, improving the conservation and management of natural resources in the oceans.

  1. AQB - air quality biomonitoring an innovative and standardized approach for the evaluation of traffic pollutant diffusion in the environment

    Energy Technology Data Exchange (ETDEWEB)

    Virano, M. [SITAF Spa, Susa (Italy); Orsi, M. [Consulagri Srl., Torino (Italy); Badino, G. [Univ. degli Studi di Torino, Torino (Italy). Dipt. di Biologia Animale e dell' Uomo; Ostacoli, G.; Zelano, V.; Gastaldi, D. [Univ. degli Studi di Torino, Torino (Italy). Dipt. di Chimica Analitica; Parodi, A. [Univ. degli Studi di Torino, Torino (Italy). Dipt. di Biologia Animale e dell' Uomo]|[Consulagri Srl., Torino (Italy)

    2002-07-01

    AQB - Air Quality Biomonitoring - is a wide scale, effective and valid biorecording system at both a scientific and an economic level. It enables a detailed evaluation of pollutant diffusion in space, as well as their accumulation over time. The data relate to the diffusion of pollutants (PAH and heavy metals) due to traffic emissions on the A32 Turin-Bardonecchia motorway. Results were obtained using aeroponic culture biostations equipped with vegetal biosensors: Brassica oleracea and Holcus lanatus. (orig.)

  2. Archives of Atmospheric Lead Pollution

    Science.gov (United States)

    Weiss, Dominik; Shotyk, William; Kempf, Oliver

    Environmental archives such as peat bogs, sediments, corals, trees, polar ice, plant material from herbarium collections, and human tissue material have greatly helped to assess both ancient and recent atmospheric lead deposition and its sources on a regional and global scale. In Europe detectable atmospheric lead pollution began as early as 6000years ago due to enhanced soil dust and agricultural activities, as studies of peat bogs reveal. Increased lead emissions during ancient Greek and Roman times have been recorded and identified in many long-term archives such as lake sediments in Sweden, ice cores in Greenland, and peat bogs in Spain, Switzerland, the United Kingdom, and the Netherlands. For the period since the Industrial Revolution, other archives such as corals, trees, and herbarium collections provide similar chronologies of atmospheric lead pollution, with periods of enhanced lead deposition occurring at the turn of the century and since 1950. The main sources have been industry, including coal burning, ferrous and nonferrous smelting, and open waste incineration until c.1950 and leaded gasoline use since 1950. The greatest lead emissions to the atmosphere all over Europe occurred between 1950 and 1980 due to traffic exhaust. A marked drop in atmospheric lead fluxes found in most archives since the 1980s has been attributed to the phasing out of leaded gasoline. The isotope ratios of lead in the various archives show qualitatively similar temporal changes, for example, the immediate response to the introduction and phasing out of leaded gasoline. Isotope studies largely confirm source assessments based on lead emission inventories and allow the contributions of various anthropogenic sources to be calculated.

  3. Biomonitoring of mercury pollution in a wetland near Ravenna, Italy by translocated bivalves (Mytilus galloprovincialis)

    Energy Technology Data Exchange (ETDEWEB)

    Cattani, O.; Fabbri, D.; Salvati, M.; Trombini, C.; Vassura, I.

    1999-08-01

    An active biomonitoring experiment using mussels (Mytilus galloprovincialis) was performed in Pialassa Baiona, a mercury-polluted coastal wetland near Ravenna, Italy. Three stations (A, B, and C) were selected along the south to north axis. Following a 52-d field exposure, organisms transplanted in the southernmost polluted area (station A) showed mean mercury concentration values of 660 ng/g (dry weight), 4.4 times the initial background level, and were still accumulating mercury. Mussels in both the central area (station B) and the northern area (station C) seemed to reach a steady state with mean mercury concentration values of 323 and 412 ng/g, respectively. This field experiment is the first study carried out in the Ravenna wetlands to evaluate mercury bioavailability in this environment. Finally, the efficiency of the population of Mytilus galloprovincialis selected for the field experiment as mercury bioaccumulators was tested in a laboratory experiment that revealed that up to 135 {micro}g/g (dry weight) could be reached after 77 d of exposure to mercury-polluted water.

  4. Small mammals as biomonitors of metal pollution: a case study in Slovenia.

    Science.gov (United States)

    Al Sayegh Petkovšek, Samar; Kopušar, Nataša; Kryštufek, Boris

    2014-07-01

    The transfer of lead, cadmium, zinc, mercury, copper and molybdenum from soil to the tissues of small mammals inhabiting differently polluted areas in Slovenia was investigated. Metals were determined in soil samples and in the livers of 139 individuals of five small mammal species, collected in 2012 in the vicinity of a former lead smelter, the largest Slovenian thermal power plant, along a main road and in a control area. The area in the vicinity of former lead smelter differs considerably from other study areas. The soil from that area is heavily polluted with Pb and Cd. The mean metal concentrations in the liver, irrespective of species, varied in the following ranges-Pb: 0.40-7.40 mg/kg fw and Cd: 0.27-135 mg/kg fw and reached effect concentrations at which toxic effects can be expected in a significant proportion of the livers of the small mammal specimens (Pb 40 %, Cd 67 %). These findings indicate that the majority of small mammals trapped in the area of the former lead smelter are at risk of toxic effects due to the very high bioaccumulation of Pb and Cd in the organism. On the contrary, Pd and Cd concentrations in the livers of small mammals sampled in the vicinity of the thermal power plant and along the main road were comparable with reference values and considerably lower than effect concentrations. Additionally, the study suggests that Apodemus flavicollis and Myodes glareolus are very suitable biomonitors of metal pollution.

  5. Biomonitoring of air pollution using antioxidative enzyme system in two genera of family Pottiaceae (Bryophyta).

    Science.gov (United States)

    Bansal, Pooja; Verma, Sonam; Srivastava, Alka

    2016-09-01

    Bryophyte particularly mosses, have been found to serve as reliable indicators of air pollution and can serve as bryometers-biological instruments for measuring air pollution. They are remarkable colonizers, as they have the ability to survive in adverse environments and are also particular in their requirement of environmental conditions, which makes them appropriate ecological indicators. The purpose of this study was to evaluate the activity of antioxidative enzymes in two mosses viz., Hyophila rosea R.S. Williams and Semibarbula orientalis (Web.) Wijk. & Marg. and assess their suitability as biomonitors. Three different locations viz., Lucknow University, Residency (contaminated sites) and Dilkusha Garden (reference site) within Lucknow city with different levels of air pollutants were used for comparison. Our results indicate that air pollution caused marked enhancement in activity of antioxidative enzymes viz., catalase, peroxidase and superoxide dismutase. All the three are capable of scavenging reactive oxygen species. In the genus S. orientalis, catalase, peroxidase and superoxide dismutase activity was minimum at the reference site Dilkusha Garden and was significantly higher at the two contaminated sites for catalase and peroxidase, whereas the difference was non significant for superoxide dismutase. In H. rosea the activity of catalase and peroxidase at the three locations was almost similar, however superoxide dismutase activity showed a significant increase in the two contaminated sites when compared to the reference site, the value being highest for Lucknow University site. It was thus observed that the two genera, from the same location, showed difference in the activity of the antioxidative enzymes. Based on our results, we recommend bryophytes as good monitors of air pollution.

  6. [Current data on atmospheric pollutions].

    Science.gov (United States)

    Festy, B; Petit-Coviaux, F; Le Moullec, Y

    1991-01-01

    Atmospheric pollutions (AP) are very important for human health and ecological equilibrium. They may be natural or anthropogenic and in this later case they can appear outdoor or indoor. Urban air pollution is the most known form of AP. Its main sources are industries, individual and collective heating and now mainly automobile traffic in most cities. Classical AP indicators are SO2, particles, NOx, CO and Pb measured in networks. Important factors of AP are amounts of pollutants emitted and local climatic and meteorological characteristics. Health effects of AP peaks and of AP background levels are not well known. But generally, mean AP levels of SO2 and particles decreased in the last years in most towns as the consequence of collective actions on the three main sources of AP and on fuels, emission and immission levels; but more is wanted about motor-cars. Progress are necessary for limitation of three major ecological risks: "acid-rain" (SO2 and NOx derivatives, ozone,...) which participates in lake and forest attacks; "green house" effects whose air CO2 concentration increase is the main responsible, and stratospheric ozone depletion mainly due to freons (CFC); the consequences of these two last phenomena are not well known but ecological and health risk exist. Besides, indoor air pollution (IAP) is very important because we live more than 20 h a day indoor. IAP may be occupational (a lot of chemical or biological agents) or not. In the later case air pollutants are very various: CO, NOx and particles from heating or cooking, formaldehyde from wood glue, plywood or urea-formol foams, radon and derivatives in some granitic countries, odd jobs products, cosmetics, aero-allergens of chemical or biological origins, microbes,... Environmental tobacco smoke (ETS) is also an important pollutant complex. Risks of IAP are real or potential: acute risk is obvious for CO, aero-allergens, formaldehyde, NOx,...); irritations are produced by ETS, formaldehyde, solvants

  7. Human hair as a potential biomonitor for assessing persistent organic pollutants.

    Science.gov (United States)

    Zhang, Hong; Chai, Zhifang; Sun, Huibin

    2007-07-01

    To explore human biomonitor of persistent organic pollutants (POP) for public health risk assessment, extractable organohalogens (EOX), extractable persistent organohalogens (EPOX) and some selected organochlorine pesticides (OCP) and polychlorinated biphenyls (PCB) in children hair from urban and rural regions of Beijing, China, were measured by instrumental neutron activation analysis (INAA) and gas chromatography-electron capture detector (GC-ECD). The results indicated that about 96% of the total halogens existed as water-soluble polar compounds; about 25 to 50% of EOX were sulfuric acid-resistant EPOX; organochlorines were the major fraction of the organohalogens; and 88 to 99.6% of extractable persistent organochlorines (EPOCl) cannot be attributed to the selected OCP and PCB. HCH, DDT and 2-5CB were the major contributors to hair OCP and PCB. Further, gamma-HCH, p,p'-DDE, p,p'-DDT and PCB-52 were the predominant individuals of HCH, DDT and 2-5CB, respectively. The concentration distributions of EPOCl, HCH, DDT and PCB in children hair were generally in the order of urban>rural and girls>boys, except for PCB congeners with random distributions between genders. Pearson positive correlations between hair lipid and the detected parameters of hair gamma-HCH (phair alpha/gamma and p,p'-DDE/p,p'-DDT suggested that fresh input of HCH and DDT might exist in Beijing area. Hair can reflect body's integral exposure to POP from endogenous and exogenous sources, which, thus, can be used as a potential biomonitor in assessing POP exposure for public health purposes.

  8. Assessment of the traffic-related elements Ba, Cr and Zn during and after the construction of a peripheral highway using Tillandsia usneoides as atmospheric biomonitor

    Energy Technology Data Exchange (ETDEWEB)

    Figueiredo, Ana M.G.; Silva, Barbara C. da, E-mail: anamaria@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Nievola, Catarina C.; Alves, Edenise S.; Domingos, Marisa, E-mail: ccnievola@uol.com.br, E-mail: ealves@ibot.sp.gov.br, E-mail: mmingos@superig.com.br [Instituto de Botanica de Sao Paulo, Sao Paulo, SP (Brazil)

    2013-07-01

    Tillandsia usneoides (L.) L. is an aerial epiphytic bromeliad that lives on trees or other kinds of inert substratum, absorbing water and nutrients directly from the environment. Due to this characteristic, this species also accumulates pollutants present in the atmosphere. In this study, T. usneoides was used as biomonitor aiming to verify if the construction of the western and southern parts of the peripheral highway Mario Covas (SP-21) in Sao Paulo city would alter the profile of atmospheric contamination by Ba, Cr and Zn in the region. These elements are often associated with traffic and can indicate contaminated urban areas. This knowledge is of great interest to the city, which has one of the biggest vehicle fleets in the world, with more than seven million circulating motor vehicles and serious environmental problems due to air pollution. Neutron Activation Analysis was employed as analytical technique. Samples of T. usneoides were irradiated at the IEA-R1 nuclear reactor at IPEN-CNEN/SP, and the induced activity was measured by high resolution gamma-ray spectrometry. Increasing concentrations of Ba, Cr and Zn were observed in the biomonitor after the inauguration of the highway, indicating that these elements originated from vehicular emissions. (author)

  9. Biomonitoring of air pollution by organic compounds in the city of Graz and the industrial area of Leoben-Donawitz

    Energy Technology Data Exchange (ETDEWEB)

    Maier, W. [TUeV Sueddeutschland, Stuttgart (Germany). Bau und Betrieb Umwelt Service; Pirker, D.; Pongratz, T.; Schopper, A. [Amt der Steiermaerkischen Landesregierung, Graz (Austria). Fachabteilung 1a; Waikinat, I. [TUeV Sueddeutschland, Muenchen (Germany). Bau und Betrieb

    2002-07-01

    The air pollution of some persistent organic compounds (PAH, PCB, PCDD/F) was measured in two regions of Styria/Austria, Graz and Leoben, by biomonitoring methods. These measurements were carried out in addition to the air quality monitoring network, the monitoring of airborne dust, contaminated with dioxines and furanes and the contamination of soil. Urban emissions (traffic, domestic heating) of air pollutants dominate the pollution level in Graz. Emissions of iron and steel industry are responsible for problems in air quality in Leoben-Donawitz. (orig.)

  10. Atmospheric pollution in Lisbon urban atmosphere

    Science.gov (United States)

    Oliveira, C.

    2009-04-01

    Lisbon is the capital city of Portugal with about 565,000 residents in 2008 and a population density of 6,600 inhabitants per square kilometre. Like several other major metropolis, the town is surrounded by satellite cities, forming together a region known as "Lisbon Metropolitan Area" with about 3 million inhabitants, a quarter of the overall Portuguese population. Besides their local residents, it is estimated that more than one million citizens come into the Lisbon area every day from the outskirts, leading to elevated traffic densities and intense traffic jams, with important consequences on air pollution levels and obvious negative impacts on human health. Airborne particulate matter limit values are frequently exceeded, making urgent the existence of consistent programs to monitor and help taking measures to control them. Within the Portuguese project PAHLIS (Polycyclic Aromatic Hydrocarbons Contamination in Lisbon Urban Atmosphere) financed by the Portuguese Science Foundation ("Fundação para a Ciência e a Tecnologia"), an aerosol and vapour phase sampling program is being implemented in the city of Lisbon at two selected contrasting zones, namely a typically busy area with intense road traffic and frequent exceedences of the particulate matter standard for the maximum allowable concentration, and a residential quieter area, thus with a cleaner atmosphere characterised as an urban background site. An one month-long sampling campaign was performed during the summer of 2008, where particulate matter was collected in two fractions (coarse 2.5µm

  11. Traffic contribution to air pollution in urban street canyons: Integrated application of the OSPM, moss biomonitoring and spectral analysis

    Science.gov (United States)

    Lazić, Lazar; Urošević, Mira Aničić; Mijić, Zoran; Vuković, Gordana; Ilić, Luka

    2016-09-01

    To investigate the air pollutant distribution within the ambient of urban street canyon, Operational Street Pollution Model (OSPM) was used to predict hourly content of NOX, NO, NO2, O3, CO, BNZ and PM10. The study was performed in five street canyons in Belgrade (Serbia) during 10-week summer period. The model receptors were located on each side of street canyons at 4 m, 8 m and 16 m height. To monitor airborne trace element content, the moss bag biomonitors were simultaneously exposed with the model receptors at two heights-4 m and 16 m. The results of both methods, modelling and biomonitoring, showed significantly decreasing trend of the air pollutants with height. The results indirectly demonstrate that biomonitoring, i.e., moss bag technique could be a valuable tool to verify model performance. In addition, spectral analysis was applied to investigate weekly variation of the daily background and modelled data set. Typical periodicities and weekend effect, caused by anthropogenic influences, have been identified.

  12. Biomonitoring of environmental pollution on the Algerian west coast using caged mussels Mytilus galloprovincialis

    Directory of Open Access Journals (Sweden)

    Jean-Claude Amiard

    2009-03-01

    Full Text Available An active biomonitoring study was carried out on the Algerian west coast using wild reference mussels (Mytilus galloprovincialis sampled from the Kristel (K site and transplanted in net cages during one month (between May and June 2007 to Oran Harbour (OH and Mostaganem Harbour (MH, areas characterised by high levels of urban and industrial pollution. The biological response of the mussels was evaluated by their condition index and the use of a general stress biomarker (evaluation of lysosomal membrane stability: the neutral red retention time (NRRT method, a genotoxic effects biomarker (determination of micronuclei (MN frequency and a neurotoxic effects biomarker (determination of the acetylcholinesterase (AChE concentration.       Compared to the K reference specimens, OH and MH caged mussels presented a significant decrease of NRRT in lysosomal haemocytes (56.45 ± 26.48 min and 67.25 ± 22.77 min, respectively (78 ± 16.97 min for K mussels, an MN frequency respectively 7.3 and 9 times higher in the haemocytes and the gill cells of the OH caged mussels, and 7.2 and 6.4 times higher in the two tissues of the MH caged mussels. Significant inhibition of AChE activity was noted in the gills (16.93 ± 3.1 nmol min-1 mg prot-1 and the digestive gland (7.69 ± 1.79 nmol min-1 mg prot-1 of the OH mussels, but only in the gills (23.21 ± 5.94 nmol min-1 mg prot-1 of the MH mussels, compared to the organs of the K control specimens (35.9 ± 6.4 nmol min-1 mg prot-1 in the gills and 11.17 ± 0.49 nmol min-1 mg prot-1 in the digestive gland.       This study reflects the interest in such in situ biomonitoring assays and the utility of these biomarkers for assessing the effects of pollution in the Algerian coastal marine environment.

  13. Magnetic biomonitoring of roadside pollution in the restricted Midagahara area of Mt. Tateyama, Toyama, Japan.

    Science.gov (United States)

    Kawasaki, Kazuo; Horikawa, Keiji; Sakai, Hideo

    2017-03-07

    Magnetic biomonitoring techniques and in situ topsoil magnetic susceptibility measurements have been shown to be rapid, cost-effective, and useful methods for investigating roadside pollution. However, combustible vegetation in samples makes it very difficult to use them in high-temperature magnetic experiments although the thermal alteration of spontaneous magnetization is a fundamental magnetic property and can be used to identify reliably the magnetic minerals. Here, we report the first magnetic biomonitoring results of dust deposited on plant leaves along the Tateyama-Kurobe Alpine route at the highly protected Midagahara wetland areas of Mt. Tateyama in Toyama, Japan. In-field magnetic susceptibility from 15 sites (161 points) shows higher susceptibilities near the roadside. Dust deposited on the leaves of Sasa kurilensis, or dwarf bamboo, has been wiped off at 12 sites (64 samples) with a commercial ethanol wipe sheet or silica wool damped in ethanol and subjected to rock magnetic analyses. Thermomagnetic remanence curves and low-temperature behaviors for samples collected near the roadside using silica wool show clearly that the main magnetic mineral in the dust is partially oxidized magnetite. Further, detailed rock magnetic analyses and elemental analyses of leaves in the study area indicate that (a) the magnetic mineralogy on leaves' surface is consistent throughout the study area and (b) higher saturation isothermal remanent magnetization intensities as well as higher concentrations of Pb, Fe, Cr, and Y are observed near the roadside, i.e., the closer to the roadside, the more anthropogenic materials, including partially oxidized magnetite, are present. Also, microscopic observations show the lack of spherical grains, indicating that dust on the roadside leaves is derived from passing vehicle rather than industrial process. Both rock magnetic and geochemical results show that S. kurilensis would be an excellent candidate for investigating air pollution

  14. Citizen participatory dioxin monitoring campaign by pine needles as biomonitor of ambient air dioxin pollution

    Energy Technology Data Exchange (ETDEWEB)

    Komichi, I.; Takatori, A. [Environmental Research Institute Inc., Tokyo (Japan); Aoyama, T. [Musashi Institute of Technology, Yokohama (Japan). Faculty of Environment and Informations; Vrzic, B. [Maxxam Analytics Inc. HRMS Laboratory, Waterloo, ON (Canada)

    2004-09-15

    The needle-type leaves of Japanese black pine trees (hereafter abbreviated as pine needles) have been used as an effective bio-monitor of ambient air pollution. Miyata Laboratory of Setsunan University has reported that the pine needles accumulate PCDDs and PCDFs (hereafter abbreviated as D/F) through photosynthesis and respiration during their lifetime. On the basis of this study, we have revealed the correlation between ambient air and pine needle concentrations to be estimated at or near 1:10 by analyzing long term continuous ambient dioxin monitoring data and that of pine needles sampled from the same area as ambient air in the Kanagawa Prefecture in 1999. Since then, the citizen groups of each local area all over Japan have started monitoring the ambient air dioxin concentration levels by using pine needles. Samples analyzed during these 5 years totaled more than 650 throughout Japan. The results of these citizen participatory environmental monitoring activities are the tremendous effects achieved in reducing the dioxin levels. This occurs through observation of the dioxin emission sources such as Municipal Solid Waste Incineration Plants as well as the Industrial Waste Incineration plants, which exist in numbers exceeding several thousands in Japan. This short paper will present the results of 56 municipalities of western Japan where ambient air dioxin levels have improved steadily against local averages during these 5 years.

  15. Comparative Use of Tree Leaves, Needles, Tree Barks and Lichens for Air Pollution Biomonitoring

    Science.gov (United States)

    El Khoukhi, T.; Cherkaoui El Moursli, R.; Chouak, A.; Moutia, Z.; Lferde, M.; Senhou, A.; Gaudry, A.; Ayrault, S.; Chakir, M.

    2005-01-01

    The aim of this work is to determine the most suitable bioaccumulators for air pollution survey in Morocco. For this, we compare in this paper heavy metals uptake efficiencies for different types of biomonitors: leaves of oak and eucalyptus trees, needles of coniferous trees, tree-barks and lichens collected at the same site. Instrumental neutron activation analysis using the k0 method (INAA-k0) was used for its adequate characteristics to analyze accurately a wide number of elements. Reference materials were analyzed to check the reliability and the accuracy of this technique. The results obtained for all these bioaccumulators lead to the following conclusions. For the major elements, leaves and needles are more accumulating than tree barks and lichens. While for the intermediate and trace elements, there is an obvious accumulation in lichens in comparison with tree barks, leaves and needles. This work shows the possibility to use these four bioaccumulators according to their availability in an area. It will be useful however to set up an inter calibration between these bioaccumulators.

  16. Biomonitoring of genotoxic effects and elemental accumulation derived from air pollution in community urban gardens.

    Science.gov (United States)

    Amato-Lourenco, Luís Fernando; Lobo, Debora Jã A; Guimarães, Eliane T; Moreira, Tiana Carla Lopes; Carvalho-Oliveira, Regiani; Saiki, Mitiko; Saldiva, Paulo Hilário Nascimento; Mauad, Thais

    2017-01-01

    Urban gardening is a growing global phenomenon with a positive impact on society. Despite several associated benefits, growing vegetables in urban gardens that are localized in highly polluted areas poses questions about the safety of the produced food. Therefore, the identification of risk factors that result in possible deleterious effects to human health is important for realizing all of the benefits to society. We evaluated the use of two biomonitoring methods in ten urban gardens of Sao Paulo city and one control site: the micronuclei frequencies for early tetrads of Tradescantia pallida (Rose) Hunt. cv. "Purpurea" Boom (hereafter, Trad-MCN) as a short-term indicator of genotoxic response and tree barks to quantify the accumulation of traffic-related chemical elements as a long-term biomarker of air pollution in urban gardens. Mature plants of Tradescantia pallida were exposed in each garden, and their inflorescences were sampled over three months. A random set of 300 early tetrads in 13 to 21 slides per garden were evaluated for micronuclei frequencies. Elemental concentrations in 428 tree barks samples from 107 different trees in the areas surrounding urban gardens were quantified using an energy dispersive X-ray fluorescence spectrometer. The frequency of Trad-MCN has a significant correlation with traffic variables and chemical elements related to road dust and tailpipe emissions deposited in tree barks. Negative associations between Trad-MCN and both the distance through traffic and the presence of vertical obstacles were observed in the community gardens. The Mn/Zn concentrations in tree barks were associated with increased Trad-MCN.

  17. Biomonitoring and hormone-disrupting effect biomarkers of persistent organic pollutants in vitro and ex vivo.

    Science.gov (United States)

    Bonefeld-Jørgensen, Eva C; Ghisari, Mandana; Wielsøe, Maria; Bjerregaard-Olesen, Christian; Kjeldsen, Lisbeth S; Long, Manhai

    2014-07-01

    Persistent organic pollutants (POPs) include lipophilic legacy POPs and the amphiphilic perfluorinated alkyl acids (PFAAs). They have long half-lives and bioaccumulate in the environment, animals and human beings. POPs possess toxic, carcinogenic and endocrine-disrupting potentials. Endocrine-disrupting chemicals (EDCs) are compounds that either mimic or block endogenous hormones and thus disrupt the normal hormone homeostasis. Biomonitoring assesses the internal doses of a person to provide information about chemical exposures. Effect biomarkers assess chemicals potential to affect cellular functions in vivo/ex vivo. Human beings are exposed to complex mixtures of chemicals, having individually very different biological potentials and effects. Therefore, the assessment of the combined, integrated biological effect of the actual chemical mixture in human blood is important. In vitro and ex vivo cell systems have been introduced for the assessment of the integrated level of xenobiotic cellular effects in human beings. Ex vivo studies have shown geographical differences in bioaccumulated POP serum levels, being reflected by the combined biomarker effects of the complex mixture extracted from human serum. Xenohormone receptor transactivities can be used as an ex vivo integrated biomarker of POP exposure and effects. Epidemiological and in vitro/ex vivo studies have supported the potential impact of the combined effect of serum POPs on the activity of hormone and/or dioxin receptors as a risk factor for human health. With focus on hormone disruption, this MiniReview will give an update on recent POP-related endocrine-disrupting effects in vitro/ex vivo/in vivo and some related genetic data.

  18. Delonix regia and Casuarina equisetifolia as passive biomonitors and as bioaccumulators of atmospheric trace metals.

    Science.gov (United States)

    Ukpebor, Emmanuel Ehiabhi; Ukpebor, Justina Ebehirieme; Aigbokhan, Emmanuel; Goji, Idris; Onojeghuo, Alex Okiemute; Okonkwo, Anthony Chinedum

    2010-01-01

    The suitability of two common and ubiquitously distributed and exotic ornamental plant species in Nigeria-Delonix regia and Casuarina equisetifolia as biomonitors and as effective bioaccumulators of atmospheric trace metals (Cd, Pb, Zn and Cu) has been evaluated. Bark and leaf samples from these plant species were collected in June and July 2006 at five locations in Benin City. Four of the sampling sites were in areas of high traffic density and commercial activities, the fifth site is a remote site, selected to act as a control and also to provide background information for the metals. The plant samples were collected and processed using standard procedures and trace metals were determined using atomic absorption spectrometer. The bark of the plants was able to bioaccumulate the trace metals, especially Pb which originates from anthropogenic contributions in the city. The Pb range of 20.00-70.00 microg/g measured for the bark samples of D. regia, exceeded the normal plant Pb concentration of 0.2-20.0 microg/g and most Pb data available in literature. The bark of the plants was observed to accumulate more metals compared to the leave, while D. regia was found to be slightly better than C. equisetifolia in trace metal uptake efficiency. Spatial variations in the distributions of Pb and Zn were significant (p < 0.05), and the continuous use of leaded fuel in Nigeria was identified as the predominant source of Pb in the atmosphere.

  19. Mosses as biomonitors of atmospheric heavy metal deposition: Spatial patterns and temporal trends in Europe

    Energy Technology Data Exchange (ETDEWEB)

    Harmens, H., E-mail: hh@ceh.ac.u [Centre for Ecology and Hydrology, Environment Centre Wales, Deiniol Road, Bangor, Gwynedd LL57 2UW (United Kingdom); Norris, D.A., E-mail: danor@ceh.ac.u [Centre for Ecology and Hydrology, Environment Centre Wales, Deiniol Road, Bangor, Gwynedd LL57 2UW (United Kingdom); Steinnes, E., E-mail: Eiliv.Steinnes@chem.ntnu.n [Department of Chemistry, Norwegian University of Science and Technology, 7491 Trondheim (Norway); Kubin, E., E-mail: Eero.Kubin@metla.f [Finnish Forest Research Institute, Kirkkosaarentie 7, 91500 Muhos (Finland); Piispanen, J., E-mail: Juha.Piispanen@metla.f [Finnish Forest Research Institute, Kirkkosaarentie 7, 91500 Muhos (Finland); Alber, R., E-mail: Renate.Alber@provinz.bz.i [Environmental Agency of Bolzano, 39055 Laives (Italy); Aleksiayenak, Y., E-mail: beataa@gmail.co [International Sakharov Environmental University, Minsk (Belarus); Blum, O., E-mail: blum@nbg.kiev.u [National Botanical Garden, Academy of Science of Ukraine, Timiryazevs' ka St. 1, 01014 Kyiv (Ukraine); Coskun, M., E-mail: coskunafm@yahoo.co [Canakkale Onsekiz Mart University, 17100 Canakkale (Turkey); Dam, M., E-mail: mariad@us.f [Environment Agency, Traoagota 38, FO-165 Argir (Faroe Islands); De Temmerman, L., E-mail: ludet@var.fgov.b [Veterinary and Agrochemical Research Centre, Leuvensesteenweg 17, 3080 Tervuren (Belgium); Fernandez, J.A., E-mail: jangel.fernandez@usc.e [University of Santiago de Compestela, Faculty of Biology, Department of Ecology, 15782 Santiago de Compostela (Spain); Frolova, M., E-mail: marina.frolova@lvgma.gov.l [Latvian Environment, Geology and Meteorology Agency, Maskavas Str. 165, Riga LV 1019 (Latvia); Frontasyeva, M., E-mail: marina@nf.jinr.r [Joint Institute for Nuclear Research, Str. Joliot-Curie 6, 141980 Dubna (Russian Federation); Gonzalez-Miqueo, L., E-mail: lgonzale2@alumni.unav.e [University of Navarra, Irunlarrea No 1, 31008 Pamplona (Spain)

    2010-10-15

    In recent decades, mosses have been used successfully as biomonitors of atmospheric deposition of heavy metals. Since 1990, the European moss survey has been repeated at five-yearly intervals. Although spatial patterns were metal-specific, in 2005 the lowest concentrations of metals in mosses were generally found in Scandinavia, the Baltic States and northern parts of the UK; the highest concentrations were generally found in Belgium and south-eastern Europe. The recent decline in emission and subsequent deposition of heavy metals across Europe has resulted in a decrease in the heavy metal concentration in mosses for the majority of metals. Since 1990, the concentration in mosses has declined the most for arsenic, cadmium, iron, lead and vanadium (52-72%), followed by copper, nickel and zinc (20-30%), with no significant reduction being observed for mercury (12% since 1995) and chromium (2%). However, temporal trends were country-specific with sometimes increases being found. - Since 1990, heavy metal concentrations in mosses have declined in Europe for most metals.

  20. Research of Mosses Accumulation Properties Used for Assessment of Regional and Local Atmospheric Pollution

    Directory of Open Access Journals (Sweden)

    Nadezhda K. Ryzhakova

    2014-10-01

    Full Text Available The monitoring of atmospheric heavy metal and other toxic element depositions by using widespread bryophytes as biomonitors has been widely used. Choosing most appropriate moss species in relation to their accumulation properties is the main goal of this research. The accumulation of heavy metals and other toxic elements by widespread mosses of midland have been studied. The research is focused on assessing accumulation properties of 4 species of terrestrial moss, 4 species of paludal moss and 2 species of epiphytic moss. The concentrations of 32 elements have been determined in moss samples by neutron activation analysis (NAA and atom emission spectrometry (AES. Interspecies and intraspecies comparison revealed significant differences in accumulation properties. The accumulation capacity of Dicranum polysetum was higher than other terrestrial mosses and Aulacomnium palustre had higher accumulation capacity than other paludal mosses. These moss species have been used for monitoring atmospheric pollutants in an immense territory, particularly for research of transboundary transfer of heavy metal pollution. The accumulation property of epiphytic moss was higher than others. The epiphytic moss could be found on the bark of old trees (aspens, poplars, birch that are of frequent occurrence in urban areas. Therefore, epiphytic moss can be used for monitoring atmospheric pollutants in an immense territory and for research of atmospheric pollution in industrial centers, inhabited locations as well as assessment of atmospheric contamination in local pollution source. DOI: http://dx.doi.org/10.5755/j01.erem.69.3.5566

  1. Biomonitoring of a polluted coastal area (Bay of Muggia, Northern Adriatic Sea): A five-year study using transplanted mussels.

    Science.gov (United States)

    Moschino, Vanessa; Del Negro, Paola; De Vittor, Cinzia; Da Ros, Luisa

    2016-06-01

    The subcellular effects of pollution were evaluated using two lysosomal biomarkers in mussels, Mytilus galloprovincialis, deployed periodically over a period of 5 years in a harbour area in the Bay of Muggia (Gulf of Trieste, North Adriatic Sea) that is strongly influenced by anthropogenic activities. Mussels were collected from a clean marine farm and analysed (sample T0). A sub-sample was transplanted to the harbour site (sample M) and analysed after about 12 weeks. An additional sub-sample was relocated within the farm as a control and was also tested at the end of the 12-week period (sample T1). The transplantation procedures were repeated twice yearly for 5 consecutive years, starting in 2009. Two well-established lysosomal biomarkers, i.e. lysosomal membrane stability and lipofuscin accumulation, were evaluated in hepatopancreas cells. The body condition index and mortality rate were also assessed. Moreover, various pollutants were determined in both mussel flesh, for a better comprehension of the biological response, and sediments, for a general characterization of the study area. As a whole, the applied biomarkers were found to be appropriate for determining the responses of mussels to environmental pollutant loads over time. Variations in lysosomal membrane stability and lipofuscin content were mostly related to total PAHs and metals respectively. Our results confirm the usefulness of active biomonitoring in evaluating pollution trends in marine coastal areas and in particular the value of lysosomal biomarkers as a rapid screening tool for highlighting pollutant effects at least at organism level.

  2. Native legumes from the Atlantic Rainforest and their potential for biomonitoring urban air pollution

    OpenAIRE

    Andrade, Guilherme Carvalho

    2015-01-01

    In Southeastern Brazil, the city of Ipatinga is inserted in the Steel Valley Metropolitan Region, which is characterized by the predominance of steel industry, and also by the presence of one of the largest vehicle fleets in the country. Developing standardized biomonitoring methods with native plant species may be an economically viable option for assessing air quality across extensive urban areas, which usually cannot be achieved by instrumental monitoring due to cost issues. In this sense,...

  3. Biomonitoring polluted sediments in Arctic regions - possibilities and challenges using benthic foraminifera. Case studies from northern Norway

    Science.gov (United States)

    Skirbekk, Kari; Dijkstra, Noortje; Junttila, Juho; Sternal, Beata; Pedersen, Kristine Bondo; Forwick, Matthias; Carroll, JoLynn

    2016-04-01

    Biomonitoring pollution in marine environments using benthic foraminifera assemblages have proven to be a valid method for many regions. Two important reasons for their suitability are their sensitivity to changes in the environment and their rapid response time due to short life cycles. In addition, they are preserved in the sedimentary record, allowing for baseline studies of conditions prior to introduction of contaminants. Species of benthic foraminifera that appear to tolerate polluted sediments are referred to as opportunistic species. This notion is in general used for species able to dominate environments that are too stressful for most species. The high latitude setting of the northern Norwegian coastal zone experience high seasonality and, hence, largely changing conditions throughout a year: variations in water mass domination, freshwater influence, temperature and current velocity. It is possible that an environment like this is inhibited by a higher amount of opportunistic species generally thriving under high stress conditions. This might make the use of benthic foraminifera for biomonitoring more challenging, as the faunal compositions may be a result of a complex set of processes. Consequently, large datasets are necessary in order to make reliable conclusions, which in time may be used as generalized guidelines for biomonitoring in this geographical area. Here, we present preliminary results of benthic foraminiferal assemblages from two sites in Finnmark, northern Norway, which have been exposed to pollution. The main site is Repparfjorden, where the inner parts of the fjord were used as a submarine waste deposal site for mine tailings from a local copper mine during the 1970´s. Results from four marine sediment cores (10-20 cm long) containing sediments classified to be in moderate to very bad state (according to Norwegian sediment quality criteria) are presented. The contamination is seen in intervals of elevated copper content dated to the 1970

  4. Active biomonitoring in freshwater environments: early warning signals from biomarkers in assessing biological effects of diffuse sources of pollutants

    Science.gov (United States)

    Wepener, V.; van Vuren, J. H. J.; Chatiza, F. P.; Mbizi, Z.; Slabbert, L.; Masola, B.

    Effluents are a main source of direct and continuous input of pollutants in aquatic ecosystems. Relating observed effects to specific pollutants or even classes of pollutants remains a very difficult task due to the usually unknown, complex and often highly variable composition of effluents. It is recognized that toxicants interfere with organism integrity at the biochemical level and give rise to effects at the individual level and is manifested in reduced ecologically relevant characteristics such as growth, reproduction and survival, and ultimately at the ecosystem level. By integrating multiple endpoints at different ecologically relevant levels of organization within one test organism, it should be possible to gain understanding in how different levels of organization within this organism respond to toxic exposure and how responses at these different levels are interrelated. This paper presents results from a field study in the Rietvlei Wetland system, Gauteng, South Africa using the freshwater mollusk ( Melanoides tuberculata) and freshwater fish ( Oreochromis mossambicus) as bioindicator organisms. Active biomonitoring (ABM) exposures were conducted where organisms were exposed for 28 days in an effluent dominated river during high flow conditions in April 2003. The river receives effluent from a wastewater treatment plant and an industrial complex, so that up to 75% of the total flow of the river is effluent-based. Effects of field exposure were determined using cellular biomarkers e.g. DNA damage, HSP 70, metallothionein, acetylcholine esterase, lactate dehydrogenase and ethoxyresorufin-o-deethylase activity. The results clearly indicate that although the traditional mortality-based whole effluent toxicity testing did not indicate any toxicity, the in situ exposed organisms were stressed. A multivariate statistical approach was particularly useful for integrating the biomarker responses and highlighting sites at which more detailed analysis of chemical

  5. Lichens as biomonitor of atmospheric aerosol composition in the Northwest European Russia

    Science.gov (United States)

    Shevchenko, Vladimir P.; Pokrovsky, Oleg S.; Zamber, Natalia S.; Konov, Konstantin G.; Starodymova, Dina P.

    2010-05-01

    Numerous studies have shown that aerosols are of importance for atmospheric chemistry and climate of the Arctic. At the coasts of Arctic seas and in their catchment areas delivery of chemical elements and compounds are registered in natural archives, for example in lichens. Lichens absorb substances, including trace elements, through dry and wet deposition, and have been widely used as biomonitors. We studied multi-element composition of terricolous (mostly of genera Cladonia and Cetraria) and fruticose epiphytic (mostly of genera Alectoria, Usnea and Bryoria) lichens collected in 2004-2009 in Kola Peninsula, Karelia, Arkhangelsk Region and Komi Republic of NW Russia, mostly in the frame of International Polar Year activity. About 110 samples were analyzed. The unwashed lichen samples were air dried and homogenised to a fine powder in an agate crusher. Samples were treated in a four-step chemical digestion procedure (full dissolution via acid attack) and element concentrations were determined by inductively coupled plasma-mass spectrometry (ICP-MS). Parts of dry samples were analyzed by instrumental neutron activation analysis (INAA). An enrichment factor (EF) was calculated for each element (X) relative to the composition of earth's crust: EF = ((X/Al) in lichen) / ((X/Al) in the earth's crust). Al was used as a crustal indicator. In most samples contents of Ti, V, Cr, Mn, Fe, Co, rare earth elements (REEs), Th, U are at the background level and their EFs are less than 10. These low EF values indicated that, relative to average values for crustal rocks, there was no enrichment of these elements in the lichen concerned. For some elements (Se, Cd, Zn, Sb, Pb, As, Ni, Cu) consistently higher EF values were obtained. These higher values were interpreted in terms of sources of both anthropogenic and natural sources other than crustal rock and (or) soil. These elements could be derived by long-range atmospheric transport. Highest concentrations of Cu, Ni, Pb in lichens

  6. MODA - A hybrid atmospheric pollutant dispersion model

    Energy Technology Data Exchange (ETDEWEB)

    Favaron, M.; Oliveti Selmi, O. [Servizi Territorio srl, Milan (Italy); Sozzi, R. [Agenzia Regionale Protezione Ambiente (ARPA) Lazio, Rieti (Italy)

    2004-07-01

    MODA is a Gaussian-hybrid atmospheric dispersion model, intended for regulatory applications, and designed to meet the following requirements: ability to operate in complex terrain, standard use of a refined description of turbulence, operational efficiency (in terms of both speed and ease to change simulation parameters), ease of integration in modelling interfaces, output compatibility with the widely-used ISC3. MODA can operate in two modes: a standard mode, in which the pollutant dispersion is treated as Gaussian, and an advanced mode, in which the hybrid relations are used to compute the pollutant concentrations. (orig.)

  7. Atmospheric Deposition of Heavy Metals in Serbia Studied by Moss Biomonitoring, Neutron Activation Analysis and GIS Technology

    CERN Document Server

    Frontasyeva, M V; Kumar, M; Matavuly, M; Pavlov, S S; Radnovic, D; Steinnes, E

    2002-01-01

    The results of a pilot study on atmospheric deposition of heavy metals and other trace elements using the moss biomonitoring technique in the northern part of Serbia and some areas of Bosnia are presented. Samples of Hypnum cupressiforme along with some other moss types were collected at 92 sites during the summer of 2000. A total of 44 elements were determined by instrumental neutron activation analysis using epithermal neutrons. The observed levels of Cu, Zn, As, Ag, Cd, In, Sb, etc. in the area surrounding the town of Bor (Serbia) are comparable to those reported from similar industrial areas in other countries such as the Copper Basin in Poland and the South Urals of Russia. In the same region the maximum Se and Mo concentrations are the highest ever recorded in biomonitoring studies using mosses. High median concentrations of Fe and Ni in Serbian mosses are associated with a crustal component as apparent from factor analysis of the moss data. This component could be a result of windblown soil dust (most ...

  8. Biomonitoring of lead in atmospheric environment of an urban center of the Ganga Plain, India.

    Science.gov (United States)

    Singh, Munendra; Goel, Pooja; Singh, Amit K

    2005-08-01

    Monitoring of atmospheric lead from the Dalbergia sissoo tree was undertaken at Lucknow urban centre of the Ganga Plain, India. A total of 26 leaf samples were collected in spring, monsoon and winter seasons from 16 sampling sites and was analysed by Atomic Absorption Spectrophotometry method. Lead concentrations were low in spring season, increased in monsoon to winter seasons and range from 2.1 to 28.2 microg/g (dry wt.). This accumulative response of lead in the tree leaves is directly linked with the exposure time of automobile emission that is considered to be the predominant source for it. Highway localities show higher lead concentrations by a factor of 2 as compared to urban localities. Highest concentration was recorded at Sitapur Road (National Highway No. 24) in winter season. A linear quantitative relationship between urban air-lead levels and lead-in-the Dalbergia sissoo leaves is used to infer the qualitative assessment of present day atmospheric lead pollution. Reported results suggest a drastic reduction in mean lead concentration in Lucknow urban air from 1.32 microg/m3 in 1994 to 0.19 microg/m3 in 2002. Similarly, mean lead concentration in the tree leaves during winter season also dropped from 17.9 microg/g in 1994 to 8.1 microg/g in 2004. Despite of increasing urban population, urban area, vehicle population and traffic density, the introduction of unleaded-petrol (vehicular fuel) keeps lead level in the urban environment of Lucknow much lower than the past. Like Lucknow, other urban centres of the Ganga Plain are also on way to the exponential increase in pressure of urbanization. An appropriate urban public transport planning is required to provide healthy atmospheric environment for millions of people especially future young generation.

  9. A Heavy Metal Atmospheric Deposition Study Around the Lead and Copper-Zinc Smelters in Baia Mare, Romania, Employing the Moss Biomonitoring Technique, ENAA and FAAS

    CERN Document Server

    Culicov, O A; Steinnes, E; Okina, O S; Santa, Z; Todoran, R

    2001-01-01

    The mosses Pleurozium schreberi, Pseudoscleropodium purum and Rhytidiadelphus squarrosus were used as biomonitors to study the atmospheric deposition of metals around the lead and copper-zinc smelters in Baia Mare. Samples representing the last three years' growth of moss or its green part, collected on the ground at 28 sites located 2-20 km from the source area, were analyzed by instrumental neutron activation analysis using epithermal neutrons (ENAA) and by flame atomic absorption spectrometry (FAAS). A total of 30 elements were determined, including most of the heavy metals known to be released into the air from this kind of industry. Obtained concentrations for As and Cu are comparable with those observed in Karabash, South Ural Mountains, one of the most polluted regions in Europe. Besides, these two elements correlate very well with each other. The mean values for Zn (136 ppm) and Pb (41 ppm) are substantially higher than those normally found in the literature. The highest value for Pb (175 ppm) was obs...

  10. Use of Atomic Absorption Spectrometry in Assessment of Biomonitor Plants for Lead, Cadmium and Copper Pollution

    Institute of Scientific and Technical Information of China (English)

    Gokce Kaya; Mehmet Yaman

    2012-01-01

    Eleven plant species were collected from the vicinity of lead-battery plant in the city of Gaziantep,Turkey.Lead,cadmium and copper concentrations in the soil and leaves of plants were determined by atomic absorption spectrometry.Lead,Cd and Cu concentrations in the soil samples taken from battery area were found to be in the ranges of 304~602,0.4~0.44 and 31~37 mg · kg-1,respectively.Significantly increased lead concentration up to 2 750 mg · kg-1 was found in the leaves of Eleagnus angustifolia L.plant.The lead concentrations in the other plant leaves taken from 50 m around battery factory followed the order Ailanthus altissima >Morus sp.> Juglans regia L.> Ficus carica L.>Cydonia oblonga Miller> Prunus x domestica L.The plants,Populus nigra L.,Eleagnus angustifolia L.and Salix sp.were found useful for Cd,and the plant,Eleagnus angustifolia L.for Pb,to be considered as potential biomonitor.Especially,leaves of trees and plants taken from the distance of 50 m from battery plant have relatively higher Pb concentrations.Therefore,people who and animals which live in this area and benefit from these soil and plants have vital risks.

  11. Biomonitoring of atmospheric particulate matter using magnetic properties of Salix matsudana tree ring cores.

    Science.gov (United States)

    Zhang, Chunxia; Huang, Baochun; Piper, John D A; Luo, Rensong

    2008-04-01

    Magnetic properties of atmospheric particulate matter collected by both natural and artificial dust receptors are increasingly being used as proxy parameters for environmental analyses. This study reports the first investigation of the relationship between smelting factory activity and the impact on the environment as recorded by the magnetic signature in Salix matsudana tree rings. Magnetic techniques including low-temperature experiments, successive acquisition of isothermal remanent magnetisation (IRM), hysteresis loops and measurements of saturated IRM (SIRM) indicated that magnetic particles were omnipresent in tree bark and trunk wood, and that these particles were predominantly magnetite with multidomain properties. The magnetic properties of tree trunk and branch cores sampled from different directions and heights implied that the acquisition of magnetic particles by a tree depends on both orientation and height. The differences of SIRM values of tree ring cores indicated that pollution source-facing tree trunk wood contained significantly more magnetic particles than other faces. The results indicated that magnetic particles are most likely to be intercepted and collected by tree bark and then enter into tree xylem tissues during the growing season to become finally enclosed into the tree ring by lignification. There was a significant correlation between time-dependent SIRM values of tree ring cores and the annual iron production of the smelting factory. From the dependence of magnetic properties with sampling direction and height, it is argued that magnetic particles in the xylem cannot move between tree rings. Accordingly, the SIRM of tree ring cores from the source-facing side can contribute to historic studies of atmospheric particulate matter produced by heavy metal smelting activities.

  12. Ecotoxicological assessment of diffuse pollution using biomonitoring tool for sustainable land use in Thailand.

    Science.gov (United States)

    Iwai, Chuleemas Boonthai; Noller, Barry

    2010-01-01

    As a developing country, Thailand has a significant issue with diffuse pollution of the soil ecosystem due to an indiscriminate use of agrichemicals and poorly regulated disposal of a wide variety of hazardous wastes. Practical risk assessment tools based on locally-occurring species are needed to assess the effects of diffuse pollutants on the soil ecosystem in Thailand because reliance on soil criteria developed for overseas conditions may provide inadequate protection. Native soil organisms in Thailand may be more or less sensitive to contaminants compared to overseas test species. This article described a biological indicator approach for ecological risk assessment of diffuse pollution in the soil ecosystem of Thailand from pesticide application with the aim of developing standardized protocols using native species and locally generated data to better evaluate the ecological risks of non-point source soil pollution. It was found that ecotoxicological assessment provided a better understanding of the ecological impacts that diffuse pollution induced on Thai environmental conditions. Thai soil biota species were more sensitive to soil contaminants than similar species overseas. Soil series also had an influence on the ecotoxicology of contaminants to soil biota. Collembolan, Cyphoderus sp., was demonstrated as a useful alternative test species to Folsomia candida (international test species) for terrestrial ecotoxicological testing of Thai soils. In addition, the soil biota activities such as soil respiration and earthworm avoidance including soil biodiversity and the litter bag decomposition technique are also good tools to assess the effects of diffuse pollution by pesticides on the soil ecosystem of Thailand.

  13. Guidelines for the use of biological monitors in air pollution control (plants). Pt. 1. Methodological guidance for the drawing-up of biomonitoring guidelines (plants)

    Energy Technology Data Exchange (ETDEWEB)

    Zimmermann, R.D. [Buero fuer Konzeptionelle Bioindikation, Jockgrim (Germany); Wagner, G. [Universitaet des Saarlandes, Saarbruecken (Germany). Inst. fuer Biogeographie; Finck, M.

    2000-04-01

    The main objective of this study is to encourage and promote further development of the methodological basis for a broader and more effective use of biological methods for monitoring the effects of air pollution on plants. It is not intended here to explain or discuss general criteria for the design of environmental monitoring studies and principal statistical methods for dealing with heterogeneously distributed spatial phenomena in detail. A further objective of this study is to give general guidance on how to - select suitable bioindicators, - develop, optimise and validate specific guidelines for the use of these bioindicators, - plan, design and employ biomonitoring studies for different purposes, - develop case-specific study plans determining how to apply an appropriate bioindicator (method-specific guideline) to a given task, case and area, - adapt principles of quality assurance and quality control to biomonitoring studies, - increase the importance and reliability of results obtained by bioindicators with respect to administrative measures. (orig.)

  14. Biomonitoring of Air Pollution by Magnetic Measurements of Native and Transplanted Lichens; Two Case Studies Around Cement Plants

    Science.gov (United States)

    Winkler, A.; Paoli, L.; Kodnik, D.; Candotto Carniel, F.; Guttová, A.; Loppi, S.; Sagnotti, L.; Tretiach, M.

    2015-12-01

    A cement plant is a source of dust pollution and lichens are suitable biomonitors of the impact of airborne pollutants released during cement production. We investigated the magnetic and chemical properties of lichens exposed around two cement plants, located in SW Slovakia and in NE Italy, respectively. We characterized the magnetic properties of the lichen Evernia prunastri exposed for 180 days at selected sites around a Slovak cement plant in order to define the magnetic mineralogy and test the correlations between the concentration-dependent magnetic parameters and the content of heavy metals and crustal elements in the thalli. In addition, we compared the magnetic properties of the transplants to those carried by native thalli of the lichen Xanthoria parietina and neighboring soils, barks and rocks. The data indicated a substantial homogenous magnetic mineralogy, with the exception of a sample collected from a basalt quarry. The transplants showed an excellent correlation between the saturation remanent magnetization (Mrs) and the concentration of Fe; the concentrations of the elements linked to cement production also correlated to Mrs values, apart from the basalt quarry sample. In the second context, we characterized the magnetic properties of the lichen Pseudevernia furfuracea transplanted near a cement plant in NE Italy. The transplants were exposed for 2 months in 40 sites distributed in surrounding rural, urban and industrial areas. In this case, the agreement between the magnetic and elemental datasets pointed out a modest environmental impact of the cement plant compared to the neighboring industrial activities, which resulted in significantly higher values of the concentration-dependent magnetic parameters. Magnetic analyses on lichens can expand the dataset of passive dust collectors in environmental magnetism, with the advantage, for the transplants, of precisely knowing the exposure time and the initial conditions.

  15. Forest biomonitoring of the largest Slovene thermal power plant with respect to reduction of air pollution.

    Science.gov (United States)

    Al Sayegh Petkovšek, Samar

    2013-02-01

    The condition of the forest ecosystem in the vicinity of the largest Slovene power plant [the Šoštanj Thermal Power Plant (ŠTPP)] was monitored during the period 1991-2008 by determining the total concentration of sulphur, ascorbic acid and chlorophyll in Norway spruce needles. After 1995, the introduction of cleaning devices at the ŠTPP dramatically reduced the former extremely high SO(2) and dust emissions. The most significant findings of this comprehensive, long-duration survey are as follows: (1) the chosen parameters are suitable bioindicators of stress caused by air pollution in Norway spruce needles; they reflect both spatial and temporal variations in air pollution as well as the degree of efficiency of the cleaning devices; (2) observations show that the physiological condition of Norway spruce in northern Slovenia has significantly improved since 1995, when the first desulphurization device at ŠTPP was built, together with a reduction in the area influenced by pollution from ŠTPP; (3) metabolic processes in spruce needles react to air pollution according to the severity of the pollution and the length of exposure; exposure to high SO(2) ambient levels and/or spread over a long duration can damage the antioxidant defence mechanisms of spruce trees as well as diminishing the concentration of ascorbic acid; (4) a reduction in the exposure to air pollution improves the vitality of the trees (e.g. higher concentrations of total (a + b) chlorophyll), as well as restoring their defence capabilities as shown by higher concentrations of ascorbic acid; and (5) forest monitoring should be continued and focused on integrating the effects of multiple stressors, which can additionally affect a forest ecosystem.

  16. Biomonitoring the effects of air pollution on forest ecosystems in an urban area, Helsinki, Finland

    Energy Technology Data Exchange (ETDEWEB)

    Maekinen, A.; Pihlstroem, M. [Helsinki Univ. (Finland). Dept. of Ecology and Systematics

    1995-12-31

    Single bioindicators have been used for a long time in air pollution monitoring in the Helsinki area (e.g. lichen studies since 1933). In the mid-eighties local authorities became aware of the need for regular integrated monitoring. Important objectives were: (a) to collect timeseries for the evaluation of natural variation e.g. weather in different parameters (b) to detect small, gradual, changes resulting from pollution control measures. The intensive monitoring of coniferous forests in the metropolitan area of Helsinki started in 1988. (author)

  17. Biomonitoring of persistent organic pollutants (POPs) in child populations living near contaminated sites in Mexico.

    Science.gov (United States)

    Flores-Ramírez, R; Pérez-Vázquez, F J; Rodríguez-Aguilar, M; Medellín-Garibay, S E; Van Brussel, E; Cubillas-Tejeda, A C; Carrizales-Yáñez, L; Díaz-Barriga, F

    2017-02-01

    The aim of this study was to conduct a POP biomonitoring programme for children in high-risk areas. We evaluated 247 serum samples from children between the ages of 6 and 12years old from two zones in Mexico: (1) indigenous zones, which included Cuatlamayan (CUA), Tocoy (TOC), and Santa Maria Picula (SAM); and (2) industrial zones, which included Tercera Chica (TC), Industrial San Luis (IND) and Rincon de San Jose (SJR); Mundo Nuevo (MN); and Alpuyeca (ALP). Our results showed that α-endosulfan was similar to CUA, TOC, SAM, TC and MN (178.6-306.9ng/g lipid). β-Endosulfan levels were higher in ALP (901.5ng/g lipid), followed by CUA (139.9ng/g lipid) and TOC, SAM, TC and MN, which had similar levels (55.4-64.5ng/g lipid). For endosulfan sulfate, the ALP community had the highest concentration levels (1096.4ng/g lipid), whereas CUA and TOC (212.3 and 289ng/g lipid, respectively) had concentrations similar to those found in SAM and TC (99.5 and 119.1ng/g lipid, respectively). DDE levels were found in malaria-endemic areas of SAM, CUA and TOC (1782.2, 1358.3 and 57.0ng/g lipid), followed by MN (35.1ng/g lipid). HCB concentration levels were found to be higher in MN and SJR (691.8 and 575.4ng/g lipid, respectively), followed by CUA and TC (363.9 and 269.1ng/g lipid, respectively), with levels similar to those found in TOC and SAM (191.8 and 181.9ng/g lipid, respectively). Finally, PCB 101 concentration levels were found to be the highest in ALP (1032.7ng/g lipid), followed by similar levels of SJR and IND (567.5 and 327.3ng/g lipid, respectively) and TC and MN, with 109.1 and 144.5ng/g lipid, respectively. The evidence provided by this exploratory study indicates that the evaluation of the health risks posed to children living in contaminated areas is a high priority health issue.

  18. Atmospheric element pollutant evaluation at the Sao Paulo University campus, Sao Paulo using Canoparmelia texana Lichen species

    Energy Technology Data Exchange (ETDEWEB)

    Rocha, Rosiana R.; Saiki, Mitiko, E-mail: rosianarocha@yahoo.com.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2015-07-01

    The use of lichens as biomonitors of atmospheric pollutants has been considered as a very suitable tool when compared to conventional methods of direct measurements. Lichens in particular are widely used as biomonitors due to its easy sampling, low cost and resistance to environmental stresses. In this study, neutron activation analysis (NAA) was applied for element determinations in Canoparmelia texana lichenized fungi species. The samples were collected from tree barks in different sites at the Sao Paulo University Campus and in sites of areas considered non-polluted. Comparisons were made between the element concentration obtained in lichen from the study area and those from non-polluted sites. Results indicated that lichens from study area presented higher concentrations of As, Br, Ca, Cd, Co, Cr, Cs, Fe, K, La, Rb, Sb, Se and U than clean areas. The principal components analysis (PCA) was applied to the results obtained and five principal components were found as being responsible for almost 77 % of the variance. These findings suggest that element pollutants found may be associated with vehicular emissions, construction of buildings and metallurgical activities. (author)

  19. Assessment of heavy metal pollution in Córdoba (Spain) by biomonitoring foraging honeybee

    NARCIS (Netherlands)

    Gutiérrez, Miriam; Molero, Rafael; Gaju, Miquel; Steen, van der Sjef; Porrini, Claudio; Ruiz, José Antonio

    2015-01-01

    Due to features that make them outstanding environmental bioindicator, colonies of Apis mellifera are being used to study environmental pollution. The primary objective of this research was to use honeybee colonies to identify heavy metals and determine their utility for environmental management.

  20. Relationship of atmospheric pollution characterized by gas (NO2) and particles (PM10) to microbial communities living in bryophytes at three differently polluted sites (rural, urban, and industrial).

    Science.gov (United States)

    Meyer, Caroline; Gilbert, Daniel; Gaudry, André; Franchi, Marielle; Nguyen, Hung Viet; Fabure, Juliette; Bernard, Nadine

    2010-02-01

    Atmospheric pollution has become a major problem for modern societies owing to its fatal effects on both human health and ecosystems. We studied the relationships of nitrogen dioxide atmospheric pollution and metal trace elements contained in atmospheric particles which were accumulated in bryophytes to microbial communities of bryophytes at three differently polluted sites in France (rural, urban, and industrial) over an 8-month period. The analysis of bryophytes showed an accumulation of Cr and Fe at the rural site; Cr, Fe, Zn, Cu, Al, and Pb at the urban site; and Fe, Cr, Pb, Al, Sr, Cu, and Zn at the industrial site. During this study, the structure of the microbial communities which is characterized by biomasses of microbial groups evolved differently according to the site. Microalgae, bacteria, rotifers, and testate amoebae biomasses were significantly higher in the rural site. Cyanobacteria biomass was significantly higher at the industrial site. Fungal and ciliate biomasses were significantly higher at the urban and industrial sites for the winter period and higher at the rural site for the spring period. The redundancy analysis showed that the physico-chemical variables ([NO(2)], relative humidity, temperature, and site) and the trace elements which were accumulated in bryophytes ([Cu], [Sr], [Pb]) explained 69.3% of the variance in the microbial community data. Moreover, our results suggest that microbial communities are potential biomonitors of atmospheric pollution. Further research is needed to understand the causal relationship underlined by the observed patterns.

  1. Cypress tree (Cupressus semervirens L.) bark as an indicator for heavy metal pollution in the atmosphere of Amman City, Jordan.

    Science.gov (United States)

    El-Hasan, Tayel; Al-Omari, Hamzeh; Jiries, Anwar; Al-Nasir, Farh

    2002-12-01

    Bio-monitoring of air quality in Amman City was investigated by analyzing 36 cypress tree (Cupressus semervirens L.) bark samples from three sites of different anthropogenic activities at the end of summer season 2001. Cypress barks were found to be a good bio-indicator for air pollution in arid regions. Variation in Pb, Zn, Mn, Cr, Ni, Cd, and Cu contents between sites was observed due to different types of activities. Traffic emissions were found to be the main source of heavy metal pollution in the atmosphere of Amman. Lead content was found to be the highest in highly traffic density areas. The industrial part of the city was characterized by high Zn, Mn, Cr, Ni, and Co contents. No significance variations were found in pH values of the bark between the sites. This was attributed to buffering effect of carbonate in the atmosphere originated from soil of the area.

  2. Pollution biomonitoring in the Bizerte lagoon (Tunisia), using combined chemical and biomarker analyses in grass goby, Zosterisessor ophiocephalus (Teleostei, Gobiidae).

    Science.gov (United States)

    Barhoumi, Badreddine; Clérandeau, Christelle; Gourves, Pierre-Yves; Le Menach, Karyn; El Megdiche, Yassine; Peluhet, Laurent; Budzinski, Hélène; Baudrimont, Magalie; Driss, Mohamed Ridha; Cachot, Jérôme

    2014-10-01

    In this study, biological responses and contaminant levels in biological tissues were investigated in grass goby fish specimens (Zosterisessor ophiocephalus) collected from five stations in a moderately polluted ecosystem, namely the Bizerte lagoon on the north coast of Tunisia. The following biomarkers were measured: muscular acetylcholinesterase (AChE), hepatic ethoxyresorufin-O-deethylase (EROD), glutathione-S-transferase (GST), catalase (CAT), lipoperoxidation (TBARS), condition factor (CF), and hepatosomatic index (HSI). These measurements were taken in parallel with the content of Organochlorine pesticides (OCPs), Polychlorinated biphenyls (PCBs), Polycyclic aromatic hydrocarbons (PAHs) and trace metals (As, Cr, Cu, Mn, Pb, V, Zn, Ag, Cd, Co and Ni) in muscle tissue. Total PAH concentrations ranged from 20.09 ± 0.68 to 105.77 ± 42.58 ng g(-1) dw, PCB from 33.19 ± 6.25 to 126.28 ± 7.37 ng g(-1) dw, OCP from 11.26 ± 1.62 to 19.17 ± 2.06 ng g(-1) dw, and metals from 107.83 ± 1.83 to 187.21 ± 2.00 mg/kg dw. The highest levels of pollutants and biomarkers were observed at station S1, located in the Bizerte channel. Elevated EROD, GST and CAT activities, as well as TBARS levels in liver were positively correlated with tissue contaminant levels at station S1. Significant negative correlations were also found between hexachlorobenzene (HCB) and dichlorodiphenyltrichloroethane (DDTs) body burden with AChE activity in muscle at station S2. The integration of biological responses and contaminant tissue content indicated that certain areas of the Bizerte lagoon, notably station S1, are significantly impacted by various human activities, which likely represent a threat for aquatic wildlife. On the basis of these results, and due to its ecological characteristics, the grass goby appears a suitable indicator species for pollution biomonitoring in coastal marine areas along the Mediterranean Sea.

  3. Prawn biomonitors of nutrient and trace metal pollution along Asia-Pacific coastlines.

    Science.gov (United States)

    Fry, Brian; Carter, James F; Tinggi, Ujang; Arman, Ali; Kamal, Masud; Metian, Marc; Waduge, Vajira Ariyaratna; Yaccup, Rahman Bin

    2016-12-01

    To assess coastal ecosystem status and pollution baselines, prawns were collected from the commercial catches of eight Asia-Pacific countries (Australia, Bangladesh, Indonesia, Myanmar, Philippines, Pakistan, Sri Lanka and Thailand). Samples collected from 21 sites along regional coastlines were analysed for trace metal and stable isotopic compositions of H, C, N, O and S. A combination of simple averaging and multivariate analyses was used to evaluate the data. Sites could be assigned to easily recognise polluted and unpolluted groups based on the prawn results. Some filter-feeding clams were also collected and analysed together with the benthic-feeding prawns, and the prawns generally had lower trace metal burdens. Climate change effects were not strongly evident at this time, but altered ocean circulation and watershed run-off patterns accompanying future climate change are expected to change chemical patterns recorded by prawns along these and other coastlines. Stable isotopes, especially (15)N, can help to distinguish between relatively polluted and unpolluted sites.

  4. Spatiotemporal Changes in Atmospheric Deposition Rates Across The Czech Republic Estimated in The Selected Biomonitoring Campaigns. Examples of Results Available For Landscape Ecology and Land Use Planning

    Directory of Open Access Journals (Sweden)

    Suchara Ivan

    2015-11-01

    Full Text Available Several large-scale and fine-scale biomonitoring surveys were carried out in the Czech Republic to estimate current and long-term accumulated atmospheric deposition rates using moss, spruce bark and forest floor humus as bioindicators since the end of 1980s. The results of the bioindicator analyses significantly correlated with available figures of deposition rates detected at the EMEP or Czech national measurement stations.

  5. Persistent organic pollutants (POPs) in human milk: a biomonitoring study in rural areas of Flanders (Belgium).

    Science.gov (United States)

    Croes, K; Colles, A; Koppen, G; Govarts, E; Bruckers, L; Van de Mieroop, E; Nelen, V; Covaci, A; Dirtu, A C; Thomsen, C; Haug, L S; Becher, G; Mampaey, M; Schoeters, G; Van Larebeke, N; Baeyens, W

    2012-11-01

    To collect information on the concentrations of persistent organic pollutants (POPs) in the rural areas in Flanders (Belgium), 84 breastfeeding mothers were recruited in rural communities in East and West Flanders and Flemish Brabant in 2009-2010. Polychlorinated biphenyl (PCB) congeners, organochlorine pesticides, brominated flame retardants, perfluorinated compounds, polychlorinated dibenzodioxines and dibenzofurans, and dioxin-like PCBs were measured in individual milk samples and in a pooled milk sample, while some additional pollutants were only measured in the pooled sample. For most pollutants, the concentrations in this study were lower or comparable to the concentrations measured in the pooled Belgian sample of the WHO human milk study of 2006, except for the pesticides dichlorodiphenyltrichloroethane DDT (+25% for ΣDDT and metabolites) and trans-nonachlor (+94%), and for the brominated flame retardant hexachlorocyclododecane HBCD (+153%). Perfluorinated compounds were for the first time determined in human milk samples from Belgium and the concentrations were comparable to those from other European countries. Also, interesting associations were found between the concentrations of POPs measured in human milk and personal characteristics as well as dietary habits of the study population. PFOS en PFOA concentrations were significantly higher in milk of primiparous participants compared to mothers who gave birth to their second child. Lower brominated PBDE congeners increased with increasing BMI of the mothers (p=0.01 for BDE 47, p=0.02 for BDE 99 and p=0.02 for BDE 100). Participants consuming milk or dairy products daily had significant higher concentrations of ΣDDTs (p=0.03) and oxychlordane (p=0.047) in their human milk samples.

  6. Biomonitoring of environmental pollution by thorium and uranium in selected regions of the Republic of Kazakhstan.

    Science.gov (United States)

    Zoriy, P; Ostapczuk, P; Dederichs, H; Höbig, J; Lennartz, R; Zoriy, M

    2010-05-01

    Two former uranium mines and a uranium reprocessing factory in the city of Aktau, Kazakhstan, may represent a risk of contaminating the surrounding areas by uranium and its daughter elements. One of the possible fingerprinting tools for studying the environmental contamination is using plant samples, collected in the surroundings of this city in 2007 and 2008. The distribution pattern of environmental pollution by uranium and thorium was evaluated by determining the thorium and uranium concentrations in plant samples (Artemisia austriaca) from the city of Aktau and comparing these results with those obtained for the same species of plants from an unpolluted area (town of Kurchatov). The determination of the uranium and thorium concentrations in different parts of A. austriaca plants collected from the analyzed areas demonstrated that the main contamination of the flora in areas surrounding the city of Aktau was due to dust transported by the wind from the uranium mines. The results obtained demonstrate that all the areas surrounding Aktau have a higher pollution level due to thorium and uranium than the control area (Kurchatov). A few "hot points" with high concentrations of uranium and thorium were found near the uranium reprocessing factory and the uranium mines.

  7. The use of biomarkers in biomonitoring: a 2-tier approach assessing the level of pollutant-induced stress syndrome in sentinel organisms.

    Science.gov (United States)

    Viarengo, A; Lowe, D; Bolognesi, C; Fabbri, E; Koehler, A

    2007-09-01

    The paper outlines a 2-tier approach for wide-scale biomonitoring programmes. To obtain a high level of standardization, we suggest the use of caged organisms (mussels or fish). An "early warning", highly sensitive, low-cost biomarker is employed in tier 1 (i.e. lysosomal membrane stability (LMS) and survival rate, a marker for highly polluted sites). Tier 2 is used only for animals sampled at sites in which LMS changes are evident and there is no mortality, with a complete battery of biomarkers assessing the levels of pollutant-induced stress syndrome. Possible approaches for integrating biomarker data in a synthetic index are discussed, along with our proposal to use a recently developed Expert System. The latter system allows a correct selection of biomarkers at different levels of biological organisation (molecular/cellular/tissue/organism) taking into account trends in pollutant-induced biomarker changes (increasing, decreasing, bell-shape). A selection of biomarkers of stress, genotoxicity and exposure usually employed in biomonitoring programmes is presented, together with a brief overview of new biomolecular approaches.

  8. Evaluation of the use of moss transplants (Pseudoscleropodium purum) for biomonitoring different forms of air pollutant nitrogen compounds.

    Science.gov (United States)

    Varela, Z; García-Seoane, R; Arróniz-Crespo, M; Carballeira, A; Fernández, J A; Aboal, J R

    2016-06-01

    We investigated whether three different types of moss transplants (devitalized moss bags with and without cover and auto-irrigated moss transplants) are suitable for use as biomonitors of the deposition of oxidised and/or reduced forms of N. For this purpose, we determined whether the concentration of atmospheric NO2 was related to the % N, δ(15)N and the activity of the enzyme biomarkers phosphomonoesterase (PME) and nitrate reductase (NR) in the tissues of moss transplants. We exposed the transplants in 5 different environments of Galicia (NW Spain) and Cataluña (NE Spain): industrial environments, urban and periurban environments, the surroundings of a cattle farm and in a monitoring site included in the sampling network of the European Monitoring Programme. The results showed that the moss in the auto-irrigated transplants was able of incorporating the N in its tissues because it was metabolically active, whereas in devitalized moss bags transplants, moss simply intercepts physically the N compounds that reached it in particulate or gaseous form. In addition, this devitalization could limit the capacity of moss to capture gaseous compounds (i.e. reduced N) and to reduce the oxidised compounds that reach the specimens. These findings indicate that devitalized moss transplants cannot be used to monitor either oxidised or reduced N compounds, whereas transplants of metabolically active moss can be used for this purpose. Finally, the NR and PME biomarkers should be used with caution because of the high variability in their activities and the limits of quantification should be evaluated in each case.

  9. Biomonitoring of airborne particulate matter emitted from a cement plant and comparison with dispersion modelling results

    Science.gov (United States)

    Abril, Gabriela A.; Wannaz, Eduardo D.; Mateos, Ana C.; Pignata, María L.

    2014-01-01

    The influence of a cement plant that incinerates industrial waste on the air quality of a region in the province of Córdoba, Argentina, was assessed by means of biomonitoring studies (effects of immission) and atmospheric dispersion (effects of emission) of PM10 with the application of the ISC3 model (Industrial Source Complex) developed by the USEPA (Environmental Protection Agency). For the biomonitoring studies, samples from the epiphyte plant Tillandsia capillaris Ruíz & Pav. f. capillaris were transplanted to the vicinities of the cement plant in order to determine the physiological damage and heavy metal accumulation (Ca, Mn, Fe, Co, Ni, Cu, Zn, Cd and Pb). For the application of the ISC3 model, point and area sources from the cement plant were considered to obtain average PM10 concentration results from the biomonitoring exposure period. This model permitted it to be determined that the emissions from the cement plant (point and area sources) were confined to the vicinities, without significant dispersion in the study area. This was also observed in the biomonitoring study, which identified Ca, Cd and Pb, pH and electric conductivity (EC) as biomarkers of this cement plant. Vehicular traffic emissions and soil re-suspension could be observed in the biomonitors, giving a more complete scenario. In this study, biomonitoring studies along with the application of atmospheric dispersion models, allowed the atmospheric pollution to be assessed in more detail.

  10. Biomonitoring Heavy Metal Pollution Using an Aquatic Apex Predator, the American Alligator, and Its Parasites.

    Directory of Open Access Journals (Sweden)

    Marisa Tellez

    Full Text Available Monitoring the bioaccumulation of chemical elements within various organismal tissues has become a useful tool to survey current or chronic levels of heavy metal exposure within an environment. In this study, we compared the bioaccumulations of As, Cd, Cu, Fe, Pb, Se, and Zn between the American alligator, Alligator mississippiensis, and its parasites in order to establish their use as bioindicators of heavy metal pollution. Concomitant with these results, we were interested to determine if parasites were more sensitive bioindicators of heavy metals relative to alligators. We found parasites collectively accumulated higher levels of As, Cu, Se, and Zn in comparison to their alligator hosts, whereas Fe, Cd, and Pb concentrations were higher in alligators. Interestingly, Fe levels were significantly greater in intestinal trematodes than their alligator hosts when analyzed independently from other parasitic taxa. Further analyses showed alligator intestinal trematodes concentrated As, Cu, Fe, Se, and Zn at significantly higher levels than intestinal nematodes and parasites from other organs. However, pentastomids also employed the role as a good biomagnifier of As. Interestingly, parasitic abundance decreased as levels of As increased. Stomach and intestinal nematodes were the poorest bioaccumulators of metals, yet stomach nematodes showed their ability to concentrate Pb at orders of magnitude higher in comparison to other parasites. Conclusively, we suggest that parasites, particularly intestinal trematodes, are superior biomagnifiers of As, Cu, Se, and Zn, whereas alligators are likely good biological indicators of Fe, Cd, and Pb levels within the environment.

  11. Biomonitoring Heavy Metal Pollution Using an Aquatic Apex Predator, the American Alligator, and Its Parasites.

    Science.gov (United States)

    Tellez, Marisa; Merchant, Mark

    2015-01-01

    Monitoring the bioaccumulation of chemical elements within various organismal tissues has become a useful tool to survey current or chronic levels of heavy metal exposure within an environment. In this study, we compared the bioaccumulations of As, Cd, Cu, Fe, Pb, Se, and Zn between the American alligator, Alligator mississippiensis, and its parasites in order to establish their use as bioindicators of heavy metal pollution. Concomitant with these results, we were interested to determine if parasites were more sensitive bioindicators of heavy metals relative to alligators. We found parasites collectively accumulated higher levels of As, Cu, Se, and Zn in comparison to their alligator hosts, whereas Fe, Cd, and Pb concentrations were higher in alligators. Interestingly, Fe levels were significantly greater in intestinal trematodes than their alligator hosts when analyzed independently from other parasitic taxa. Further analyses showed alligator intestinal trematodes concentrated As, Cu, Fe, Se, and Zn at significantly higher levels than intestinal nematodes and parasites from other organs. However, pentastomids also employed the role as a good biomagnifier of As. Interestingly, parasitic abundance decreased as levels of As increased. Stomach and intestinal nematodes were the poorest bioaccumulators of metals, yet stomach nematodes showed their ability to concentrate Pb at orders of magnitude higher in comparison to other parasites. Conclusively, we suggest that parasites, particularly intestinal trematodes, are superior biomagnifiers of As, Cu, Se, and Zn, whereas alligators are likely good biological indicators of Fe, Cd, and Pb levels within the environment.

  12. Comparison between atmospheric pollutants from urban and rural areas employing the transplanted Usnea amblyoclada lichen species

    Energy Technology Data Exchange (ETDEWEB)

    Mendes, Fabiana S.; Saiki, Mitiko; Genezini, Frederico A.; Alves, Edson R.; Santos, Jose O., E-mail: mitiko@ipen.br, E-mail: fredzini@ipen.br, E-mail: eralves@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Martins, Marco A.G.; Saldiva, Paulo H.N., E-mail: marcogarciam@usp.br, E-mail: pepino@usp.br [Faculdade de Medicina da Universidade de Sao Paulo (FMUSP), Sao Paulo, SP (Brazil)

    2011-07-01

    Over the last decades, lichens have been used as biomonitors in studies related to atmospheric pollution of several elements. The capability of absorbing and accumulating aerial pollutants, their longevity and resistance to environmental stresses have made lichens suitable for studies on air quality evaluation. In this study, a preliminary investigation employing Usnea amblyoclata lichen species and instrumental neutron activation analysis was performed to compare the levels of elements in the air of an urban and rural area. Samples of Usnea amblyoclada (Mull. Arg) collected in a clean area were exposed in a polluted area by vehicular emissions in Sao Paulo city and in a rural area of Caucaia do Alto Municipality, Cotia, SP. After 6 months of exposure the lichens were collected, cleaned, freeze-dried and ground for analyses. Samples and elemental standards were irradiated at the IEA-R1 nuclear research reactor and their induced activities were measured using a gamma ray spectrometer. Results indicated that lichens exposed in the polluted urban area presented higher levels of Ba, Br, Ca, Co, Cr, La, Sb, Sc, Se, Th, V and Zn than those from the rural area. Besides that ,concentrations of As, Ba, Br, Ca, Co, Cr, Fe, Hf, La, Mg, Th, Sc and V in lichens exposed in the rural and polluted urban area were higher than those that were not exposed. Quality control of analytical results was achieved by the analyses of certified reference material. Lichen species used in this study proved to be very useful for active monitoring of a polluted urban environment. (author)

  13. Atmospheric pollution and health. An introduction; Pollution atmospherique et sante une introduction

    Energy Technology Data Exchange (ETDEWEB)

    Zmirou, D. [Universite-Faculte de Medecine, 38 - Grenoble (France)

    1996-12-31

    Physiological observations and pollution measurements allowed for the study of short and long term respiratory effects of tropospheric ozone and fine particulate pollution on man, depending on age and health factors. Risk reduction policies towards air quality, and criteria issues for atmospheric pollution control and abatement measures, are discussed

  14. Ideas in Practice: Studies in Atmospheric Pollution For Science Teachers

    Science.gov (United States)

    Rowe, Donald R.

    1974-01-01

    Describes the content and structure of an enviromental course offered by the Department of Engineering Technology at Western Kentucky University. The course focuses on atmospheric pollution and is designed for science teachers currently teaching in the school system. (JR)

  15. Assessment of radionuclides (uranium and thorium) atmospheric pollution around Manjung district, Perak using moss as bio-indicator

    Science.gov (United States)

    Arshad, Nursyairah; Hamzah, Zaini; Wood, Ab. Khalik; Saat, Ahmad

    2016-01-01

    Bio-monitoring method using mosses have been widely done around the world and the effectiveness has been approved. Mosses can be used to assess the levels of atmospheric pollution as mosses pick up nutrients from the atmosphere and deposition retaining many trace elements. In this study, the deposition of two radionuclides; uranium (U) and thorium (Th) around Manjung districts have been evaluated using Leucobryum aduncum as bio-monitoring medium. The samples were collected from 24 sampling sites covering up to 40 km radius to the North, North-East and South-East directions from Teluk Rubiah. The concentrations of U and Th in moss samples were analysed using Energy Dispersive X-Ray Fluorescence (EDXRF) Spectrometer. The concentrations of Th are in the range of 0.07-2.09 mg/kg. Meanwhile, the concentrations of U in the moss are in the range of 0.03-0.18 mg/kg. The Enrichment Factor (EF) was calculated to determine the origin of the radionuclides distributions. Other than that, the distribution maps were developed to observe the distribution of the radionuclides around the study area.

  16. Assessment of radionuclides (uranium and thorium) atmospheric pollution around Manjung district, Perak using moss as bio-indicator

    Energy Technology Data Exchange (ETDEWEB)

    Arshad, Nursyairah, E-mail: nursyairah1990@gmail.com; Hamzah, Zaini; Wood, Ab. Khalik [Faculty of Applied Sciences, Universiti Teknologi MARA, 40450, Shah Alam Selangor (Malaysia); Saat, Ahmad [Faculty of Applied Sciences, Universiti Teknologi MARA, 40450, Shah Alam Selangor (Malaysia); Institute of Science, Universiti Teknologi MARA, 40450, Shah Alam Selangor (Malaysia)

    2016-01-22

    Bio-monitoring method using mosses have been widely done around the world and the effectiveness has been approved. Mosses can be used to assess the levels of atmospheric pollution as mosses pick up nutrients from the atmosphere and deposition retaining many trace elements. In this study, the deposition of two radionuclides; uranium (U) and thorium (Th) around Manjung districts have been evaluated using Leucobryum aduncum as bio-monitoring medium. The samples were collected from 24 sampling sites covering up to 40 km radius to the North, North-East and South-East directions from Teluk Rubiah. The concentrations of U and Th in moss samples were analysed using Energy Dispersive X-Ray Fluorescence (EDXRF) Spectrometer. The concentrations of Th are in the range of 0.07-2.09 mg/kg. Meanwhile, the concentrations of U in the moss are in the range of 0.03-0.18 mg/kg. The Enrichment Factor (EF) was calculated to determine the origin of the radionuclides distributions. Other than that, the distribution maps were developed to observe the distribution of the radionuclides around the study area.

  17. Human biological monitoring as demonstrated by means of a heavy-metal polluted abandoned site; Human-Biomonitoring am Beispiel einer Schwermetallaltlast

    Energy Technology Data Exchange (ETDEWEB)

    Elison, M.; Schulte-Hostede, S. [GSF-Forschungzentrum fuer Umwelt und Gesundheit Neuherberg (Germany). Inst. fuer Oekologische Chemie

    1997-12-31

    Models for estimating exposure permit to make a rough assessment of the risk emanating from a contaminated area. But it must not be overlooked that such models are fraught with considerable weaknesses.- In studies such as the one described, concerned citizens should additionally be examined in order to obtain supplementary information and to aid interpretation. Such human biological monitoring makes sense only if the persons in question actually live in the contaminated areas, so that a higher exposure may reasonably be expected. Human biological monitoring is to help assess the inner exposure of human beings to pollutants emanating from the contaminated area. (orig./SR) [Deutsch] Mit Hilfe von Modellen zur Expositionsabschaetzung ist man nach den oben dargestellten Vorgehensweisen in der Lage, eine orientierende Bewertung des von einer kontaminierten Flaeche ausgehenden Risikos vorzunehmen. Dabei ist jedoch zu beruecksichtigen, dass solche Modelle mit erheblichen Schwachstellen belastet sind. Zur Ergaenzung und Interpretationshilfe sind bei Untersuchungen wie der hier vorgestellten auch Untersuchungen an den betroffenen Buergen vorzunehmen. Dieses Human-Biomonitoring hat nur dort einen Sinn, wo sichergestellt ist, dass die Menschen dort tatsaechlich auf belasteten Flaechen leben und damit eine erhoehte Belastung der Menschen anzunehmen ist. Das Human-Biomonitoring soll eine Abschaetzung der inneren Belastung des Menschen mit Schadstoffen, die von der kontaminierten Flaeche herruehren, ermoeglichen. (orig./SR)

  18. Biomonitoring of non-dioxin-like polychlorinated biphenyls in transgenic Arabidopsis using the mammalian pregnane X receptor system: a role of pectin in pollutant uptake.

    Directory of Open Access Journals (Sweden)

    Lieming Bao

    Full Text Available Polychlorinated biphenyls (PCBs are persistent organic pollutants damaging to human health and the environment. Techniques to indicate PCB contamination in planta are of great interest to phytoremediation. Monitoring of dioxin-like PCBs in transgenic plants carrying the mammalian aryl hydrocarbon receptor (AHR has been reported previously. Herein, we report the biomonitoring of non-dioxin-like PCBs (NDL-PCBs using the mammalian pregnane X receptor (PXR. In the transgenic Arabidopsis designated NDL-PCB Reporter, the EGFP-GUS reporter gene was driven by a promoter containing 18 repeats of the xenobiotic response elements, while PXR and its binding partner retinoid X receptor (RXR were coexpressed. Results showed that, in live cells, the expression of reporter gene was insensitive to endogenous lignans, carotenoids and flavonoids, but responded to all tested NDL-PCBs in a dose- and time- dependent manner. Two types of putative PCB metabolites, hydroxy- PCBs and methoxy- PCBs, displayed different activation properties. The vascular tissues seemed unable to transport NDL-PCBs, whereas mutation in QUASIMODO1 encoding a 1,4-galacturonosyltransferase led to reduced PCB accumulation in Arabidopsis, revealing a role for pectin in the control of PCB translocation. Taken together, the reporter system may serve as a useful tool to biomonitor the uptake and metabolism of NDL-PCBs in plants.

  19. A lead isotopic assessment of tree bark as a biomonitor of contemporary atmospheric lead

    Energy Technology Data Exchange (ETDEWEB)

    Patrick, Gavin J. [School of GeoSciences, University of Edinburgh, West Mains Road, Edinburgh EH9 3JN, Scotland (United Kingdom); Farmer, John G. [School of GeoSciences, University of Edinburgh, West Mains Road, Edinburgh EH9 3JN, Scotland (United Kingdom)], E-mail: J.G.Farmer@ed.ac.uk

    2007-12-15

    The outermost bark layer of trees, predominantly Scots pine (Pinus sylvestris), was sampled at 82 non-urban locations from six arbitrarily designated areas (Northwest, Northeast, Central Highlands, Central and East, Central and Southwest, Southeast), throughout Scotland during 2002-2003 and analysed for lead concentration and stable lead isotopes by flame atomic absorption spectrometry (AAS) and inductively coupled plasma-mass spectrometry (ICP-MS), respectively. The mean lead concentration and mean {sup 206}Pb/{sup 207}Pb ratio ({+-} 1 standard deviation, SD) for bark samples from the areas were as follows: Northwest (8.0 mg kg{sup -1}, 1.121 {+-} 0.014, n = 17), Northeast (8.9 mg kg{sup -1}, 1.117 {+-} 0.012, n = 12), Central Highlands (11.3 mg kg{sup -1}, 1.130 {+-} 0.010, n = 11), Central and East (35.3 mg kg{sup -1}, 1.120 {+-} 0.007, n = 10), Central and Southwest (20.6 mg kg{sup -1}, 1.125 {+-} 0.018, n = 22) and Southeast (34.4 mg kg{sup -1}, 1.120 {+-} 0.005, n = 10), with an overall mean lead concentration of 18.5 mg kg{sup -1} (range 0.6-146 mg kg{sup -1}, median 8.4 mg kg{sup -1}) and an overall mean {sup 206}Pb/{sup 207}Pb ratio of 1.122 {+-} 0.014 (range 1.089-1.168, median 1.122). The overall mean {sup 206}Pb/{sup 207}Pb ratio for bark was therefore significantly lower (p < 0.01, t test) than the mean atmospheric {sup 206}Pb/{sup 207}Pb ratio of 1.154 {+-} 0.006 (range 1.144-1.167, n = 50) and 1.154 {+-} 0.010 (range 1.134-1.171, n = 26) as determined in rainwater collected routinely at Glensaugh, Central Highlands, during 2002 and 2003, respectively. The bark {sup 206}Pb/{sup 207}Pb values, 90% of which lay between 1.10 and 1.14, were more akin to those recorded for the atmosphere (via rainwater, atmospheric particulates, moss, etc.) at various locations throughout Scotland during the 1990s, a decade over which the use of leaded petrol (mean {sup 206}Pb/{sup 207}Pb ratio = 1.076 {+-} 0.011) declined markedly before its complete withdrawal in 2000

  20. Application of computational fluid mechanics to atmospheric pollution problems

    Science.gov (United States)

    Hung, R. J.; Liaw, G. S.; Smith, R. E.

    1986-01-01

    One of the most noticeable effects of air pollution on the properties of the atmosphere is the reduction in visibility. This paper reports the results of investigations of the fluid dynamical and microphysical processes involved in the formation of advection fog on aerosols from combustion-related pollutants, as condensation nuclei. The effects of a polydisperse aerosol distribution, on the condensation/nucleation processes which cause the reduction in visibility are studied. This study demonstrates how computational fluid mechanics and heat transfer modeling can be applied to simulate the life cycle of the atmosphereic pollution problems.

  1. Development of ion-exchange collectors for monitoring atmospheric deposition of inorganic pollutants in Alaska parklands

    Science.gov (United States)

    Brumbaugh, William G.; Arms, Jesse W.; Linder, Greg L.; Melton, Vanessa D.

    2016-09-19

    Between 2010 and 2014, the U.S. Geological Survey completed a series of laboratory and field experiments designed to develop methodology to support the National Park Service’s long-term atmospheric pollutant monitoring efforts in parklands of Arctic Alaska. The goals of this research were to develop passive sampling methods that could be used for long-term monitoring of inorganic pollutants in remote areas of arctic parklands and characterize relations between wet and dry deposition of atmospheric pollutants to that of concentrations accumulated by mosses, specifically the stair-step, splendid feather moss, Hylocomium splendens. Mosses and lichens have been used by National Park Service managers as atmospheric pollutant biomonitors since about 1990; however, additional research is needed to better characterize the dynamics of moss bioaccumulation for various classes of atmospheric pollutants. To meet these research goals, the U.S. Geological Survey investigated the use of passive ionexchange collectors (IECs) that were adapted from the design of Fenn and others (2004). Using a modified IEC configuration, mulitple experiments were completed that included the following: (a) preliminary laboratory and development testing of IECs, (b) pilot-scale validation field studies during 2012 with IECs at sites with instrumental monitoring stations, and (c) deployment of IECs in 2014 at sites in Alaska having known or suspected regional sources of atmospheric pollutants where samples of Hylocomium splendens moss also could be collected for comparison. The targeted substances primarily included ammonium, nitrate, and sulfate ions, and certain toxicologically important trace metals, including cadmium, cobalt, copper, nickel, lead, and zinc.Deposition of atmospheric pollutants is comparatively low throughout most of Alaska; consequently, modifications of the original IEC design were needed. The most notable modification was conversion from a single-stage mixed-bed column to a two

  2. Biomonitoring human exposure to environmental carcinogenic chemicals

    DEFF Research Database (Denmark)

    Farmer, P.B.; Sepai, O.; Lawrence, R.;

    1996-01-01

    A coordinated study was carried out on the development, evaluation and application of biomonitoring procedures for populations exposed to environmental genotoxic pollutants. The procedures used involved both direct measurement of DNA or protein damage (adducts) and assessment of second biological...

  3. Biomonitoring of ozone: a tool to initiate the young people into the scientific method and air pollution impacts

    Energy Technology Data Exchange (ETDEWEB)

    Castell, J.F. [INA PG /INRA - Unite Environnement et Grandes Cultures, Thiverval Grignon (France); Maronnier, D. [ALOISE, Les Mureaux (France). Site de l' Oseraie

    2002-07-01

    An operation of air quality biomonitoring is proposed collectively by an agricultural research centre (INRA) and an association of scientific leisure activities (ALOISE) in the region of Paris. The operation consists in realizing a map of ozone impacts on tobacco Bel-W3 plants using observations made by school pupils. The main objectives are to introduce the young people to the scientific method by an experimental approach, to incite them to work on the air quality problems, and to allow them to meet researchers. The first educational results are encouraging. However, the standardization of the observations should be improved to allow the realization of reliable maps. (orig.)

  4. Development of ion-exchange collectors for monitoring atmospheric deposition of inorganic pollutants in Alaska parklands

    Science.gov (United States)

    Brumbaugh, William G.; Arms, Jesse W.; Linder, Greg L.; Melton, Vanessa D.

    2016-09-19

    Between 2010 and 2014, the U.S. Geological Survey completed a series of laboratory and field experiments designed to develop methodology to support the National Park Service’s long-term atmospheric pollutant monitoring efforts in parklands of Arctic Alaska. The goals of this research were to develop passive sampling methods that could be used for long-term monitoring of inorganic pollutants in remote areas of arctic parklands and characterize relations between wet and dry deposition of atmospheric pollutants to that of concentrations accumulated by mosses, specifically the stair-step, splendid feather moss, Hylocomium splendens. Mosses and lichens have been used by National Park Service managers as atmospheric pollutant biomonitors since about 1990; however, additional research is needed to better characterize the dynamics of moss bioaccumulation for various classes of atmospheric pollutants. To meet these research goals, the U.S. Geological Survey investigated the use of passive ionexchange collectors (IECs) that were adapted from the design of Fenn and others (2004). Using a modified IEC configuration, mulitple experiments were completed that included the following: (a) preliminary laboratory and development testing of IECs, (b) pilot-scale validation field studies during 2012 with IECs at sites with instrumental monitoring stations, and (c) deployment of IECs in 2014 at sites in Alaska having known or suspected regional sources of atmospheric pollutants where samples of Hylocomium splendens moss also could be collected for comparison. The targeted substances primarily included ammonium, nitrate, and sulfate ions, and certain toxicologically important trace metals, including cadmium, cobalt, copper, nickel, lead, and zinc.Deposition of atmospheric pollutants is comparatively low throughout most of Alaska; consequently, modifications of the original IEC design were needed. The most notable modification was conversion from a single-stage mixed-bed column to a two

  5. Effects of atmospheric pollutants on somatic and germ cells of Tradescantia pallida (Rose D.R. HUNT cv. purpurea

    Directory of Open Access Journals (Sweden)

    BRUNO A. CRISPIM

    2014-12-01

    Full Text Available Anatomical alterations in leaves and DNA damage in cells caused by the accumulation of atmospheric pollutants can be measured by epidermal leaf analyses and Tradescantia micronuclei assay with early pollen tetrad cells. The present study examined the feasibility of using somatic and germ cells of Tradescantia pallida for biomonitoring purposes in the city of Dourados, state of Mato Grosso do Sul (MS, Brazil. Stomatal, micronucleus and epidermal leaf analyses were performed, using standard methodologies, on plants growing at three locations during six different time periods. Tradescantia micronuclei data were analyzed using SAS 9.2 software package and stomatal data were analyzed using SANEST software. Analyses of stomatal characteristics and micronuclei examination in T. pallida were found to be an efficient tool for monitoring atmospheric pollution. The micronucleus assay suggested that the number of micronuclei in early pollen tetrad cells was related to the intensity of vehicular traffic. Increased number of epidermal cells and stomata and increased stomatal density observed at locations with greater vehicular traffic are likely physiological responses of those plants to the increased gas exchange in highly polluted environments.

  6. Analysis of lichens for use in biomonitoring of environmental pollution; Analise de liquens para uso na biomonitoracao da poluicao ambiental

    Energy Technology Data Exchange (ETDEWEB)

    Horimoto, Lidia K.; Saiki, Mitiko; Vasconcellos, Marina B.A. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil). Supervisao de Radioquimica; Marcelli, Marcello P. [Instituto de Botanica, Sao Paulo, SP (Brazil). Secao de Micologia e Liquenologia

    2000-07-01

    This work presents the results of Al, As, Br, Ca, Cd, Cl, Co, Cs, Fe, K, Mg, Mn, Na, Rb, Se, Th, V and Zn obtained by instrumental neutron activation analysis in the analyses of epiphytic lichen samples collected in different sites of the States of Sao Paulo and Parana. These lichens were collected in the following sites: Cidade Universitaria, Campo Limpo Paulista, Sao Bernardo do Campo and Itanhaen situated in the State of Sao Paulo and one sample was from Vila Velha, Ponta Grossa of Parana State. The purpose of these analyses were to obtain preliminary information of air quality of these regions and also select a region of interest for biomonitoring studies. (author)

  7. Study on Freshwater Macroinvertebrates of Some Tanzanian Rivers as a Basis for Developing Biomonitoring Index for Assessing Pollution in Tropical African Regions

    Directory of Open Access Journals (Sweden)

    Julius D. Elias

    2014-01-01

    Full Text Available Macroinvertebrates and physicochemical parameters were assessed at 15 sites along five rivers in Kilimanjaro region, Tanzania, with the aim of understanding their ecological status and setting a base to the development of a biological index for tropical regions. Investigated rivers that occur within Pangani basin include Karanga, Rau, Lumbanga, Sere, and Umbwe. Sampling sites were categorized according to the level of water and habitat quality as follows: reference or least impacted (4 sites, moderately impacted (5 sites, and highly impacted (6 sites sites. A total of 12,527 macroinvertebrates belonging to 13 orders and 48 families were recorded. The highest total abundance of 4,110 individuals per m2 was found in Karanga river, while Umbwe river had the lowest with 1,203 individuals per m2. Chironomidae was the most abundant family (2,588 individuals per m2 and the least were Hydridae and Thiaridae, each having 5 individuals per m2. High numbers of taxa were noted among the orders: Ephemeroptera (8, Odonata (8, Diptera (7, and Trichoptera (6. In conclusion, orders with greater diversity of macroinvertebrate families offer a wide range of tolerance to pollution and, thus can potentially be used to develop a biomonitoring index for evaluating pollution in tropical African rivers.

  8. Relationship between epiphytic lichens, trace elements and gaseous atmospheric pollutants

    NARCIS (Netherlands)

    Dobben, van H.F.; Wamelink, G.W.W.; Braak, ter C.J.F.

    2001-01-01

    A study was conducted to determine the joint effect of gaseous atmospheric pollutants and trace elements on epiphytic lichens. We used our data to test the hypothesis that lichens are generally insensitive to toxic effects of trace elements, and can therefore be used as accumulator organisms to esti

  9. Nonlinear dynamics of the atmospheric pollutants in Mexico City

    Science.gov (United States)

    Muñoz-Diosdado, Alejandro; Barrera-Ferrer, Amilcar; Angulo-Brown, Fernando

    2014-05-01

    The atmospheric pollution in the Metropolitan Zone of Mexico City (MZMC) is a serious problem with social, economical and political consequences, in virtue that it is the region which concentrates both the greatest country population and a great part of commercial and industrial activities. According to the World Health Organization, maximum permissible concentrations of atmospheric pollutants are exceeded frequently. In the MZMC, the environmental monitoring has been limited to criteria pollutants, named in this way due to when their levels are measured in the atmosphere, they indicate in a precise way the air quality. The Automatic Atmospheric Monitoring Network monitors and registers the values of pollutants concentration in air in the MZMC. Actually, it is integrated by approximately 35 automatic-equipped remote stations, which report an every-hour register. Local and global invariant quantities have been widely used to describe the fractal properties of diverse time series. In the study of certain time series, many times it is assumed that they are monofractal, which means that they can be described only with one fractal dimension. But this hypothesis is unrealistic because a lot of time series are heterogeneous and non stationary, so their scaling properties are not the same throughout time and therefore they may require more fractal dimensions for their description. Complexity of the atmospheric pollutants dynamics suggests us to analyze its time series of hourly concentration registers with the multifractal formalism. So, in this work, air concentration time series of MZMC criteria pollutants were studied with the proposed method. The chosen pollutants to perform this analysis are ozone, sulfur dioxide, carbon monoxide, nitrogen dioxide and PM10 (particles less than 10 micrometers). We found that pollutants air concentration time series are multifractal. When we calculate the degree of multifractality for each time series we know that while more

  10. Ozone pollution and ozone biomonitoring in European cities Part II. Ozone-induced plant injury and its relationship with descriptors of ozone pollution

    DEFF Research Database (Denmark)

    Klumpp, A.; Ansel, W.; Klumpp, G.

    2006-01-01

    Within the scope of a biomonitoring study conducted in twelve urban agglomerations in eight European countries, the ozone-sensitive bioindicator plant Nicotiana tabacum cv. Bel-W3 was employed in order to assess the occurrence of phytotoxic ozone effects at urban, suburban, rural and traffic....... This is because the actual ozone flux into the leaf, which is modified by various environmental factors, rather than ambient ozone concentration determines the effects on plants. The advantage of sensitive bioindicators like tobacco Bel-W3 is that the impact of the effectively absorbed ozone dose can directly...

  11. Spectral estimation of global levels of atmospheric pollutants.

    Science.gov (United States)

    Fernández-Macho, Javier

    2011-10-01

    Underlying levels of atmospheric pollutants, assumed to be governed by smoothing mechanisms due to atmospheric dispersion, can be estimated from global emissions source databases on greenhouse gases and ozone-depleting compounds. However, spatial data may be contaminated with noise or even missing or zero-valued at many locations. Therefore, a problem that arises is how to extract the underlying smooth levels. This paper sets out a structural spatial model that assumes data evolve across a global grid constrained by second-order smoothing restrictions. The frequency-domain approach is particularly suitable for global datasets, reduces the computational burden associated with two-dimensional models and avoids cumbersome zero-inflated skewed distributions. Confidence intervals of the underlying levels are also obtained. An application to the estimation of global levels of atmospheric pollutants from anthropogenic emissions illustrates the technique which may also be useful in the analysis of other environmental datasets of similar characteristics.

  12. Plant biomonitoring of air pollution in urban areas: examples of some French cities and Beijing (P.R. China)

    Energy Technology Data Exchange (ETDEWEB)

    Garrec, J.P.; Rose, C.; Radnai, F. [INRA - Centre de Recherche Forestiere de Nancy, Champenoux (France). Lab. Pollution Atmospherique; He Shang [Chinese Academy of Forestry, Beijing, BJ (China). Research Inst. of Forest Ecology and Environmental Science

    2002-07-01

    In urban areas, gaseous and particulate vehicle emissions during periods of high traffic activity consist of primary air pollutants (NO{sub x}, SO{sub 2}, VOC, particles, etc.). But under the influence of sunlight these pollutants can also react and create a variety of secondary products including ozone. Sensitive higher plants can be used as indicators of air pollution effects for studying the occurrence and distribution of air pollutants and their consequences in space and time. We report results of an urban survey (Communaute Urbaine du Grand Nancy) of ozone concentrations, using the appearance of visible injury of the leaves of a sensitive plant species (Nicotiana tabacum cv. Bel-W3) as an indicator of the presence of the pollutant. Far from France, in P.R. China, Beijing is known for its high level of air pollution, but the town is only equipped with a small air monitoring network, and for this reason nothing is known about the location of the different polluted areas, their surface and their level of pollutants. In a first step, Beijing has been divided by a 211-grid plots system. During summer 1998, leaves were sampled from one poplar (Populus tomentosa) in each plot. Among the different elements analysed in the particles collected by the leaves of this bio-accumulator, the two elements Fe and S are particularly interesting: - Fe is a tracer of the air pollution linked to road or railway traffic, - S is a tracer of the air pollution linked to domestic or industrial use of energy from coal or fuel. From the identification of three classes of iron and sulphur levels, the first air pollution maps of Beijing have been drawn up. (orig.)

  13. Metallic corrosion in the polluted urban atmosphere of Hong Kong.

    Science.gov (United States)

    Liu, Bo; Wang, Da-Wei; Guo, Hai; Ling, Zhen-Hao; Cheung, Kalam

    2015-01-01

    This study aimed to explore the relationship between air pollutants, particularly acidic particles, and metallic material corrosion. An atmospheric corrosion test was carried out in spring-summer 2012 at a polluted urban site, i.e., Tung Chung in western Hong Kong. Nine types of metallic materials, namely iron, Q235 steel, 20# steel, 16Mn steel, copper, bronze, brass, aluminum, and aluminum alloy, were selected as specimens for corrosion tests. Ten sets of the nine materials were all exposed to ambient air, and then each set was collected individually after exposure to ambient air for consecutive 6, 13, 20, 27, 35, 42, 49, 56, 63, and 70 days, respectively. After the removal of the corrosion products on the surface of the exposed specimens, the corrosion rate of each material was determined. The surface structure of materials was observed using scanning electron microscopy (SEM) before and after the corrosion tests. Environmental factors including temperature, relative humidity, concentrations of gaseous pollutants, i.e., sulfur dioxide (SO₂), nitrogen dioxide (NO₂), carbon monoxide (CO), ozone (O₃), and particulate-phase pollutants, i.e., PM₂.₅ (FSP) and PM₁₀ (RSP), were monitored. Correlation analysis between environmental factors and corrosion rate of materials indicated that iron and carbon steel were damaged by both gaseous pollutants (SO₂ and NO₂) and particles. Copper and copper alloys were mainly corroded by gaseous pollutants (SO₂ and O₃), while corrosion of aluminum and aluminum alloy was mainly attributed to NO₂ and particles.

  14. Spatial scales of variation in lichens: implications for sampling design in biomonitoring surveys.

    Science.gov (United States)

    Giordani, Paolo; Brunialti, Giorgio; Frati, Luisa; Incerti, Guido; Ianesch, Luca; Vallone, Emanuele; Bacaro, Giovanni; Maccherini, Simona

    2013-02-01

    The variability of biological data is a main constraint affecting the quality and reliability of lichen biomonitoring surveys for estimation of the effects of atmospheric pollution. Although most epiphytic lichen bioindication surveys focus on between-site differences at the landscape level, associated with the large scale effects of atmospheric pollution, current protocols are based on multilevel sampling, thus adding further sources of variation and affecting the error budget. We test the hypothesis that assemblages of lichen communities vary at each spatial scale examined, in order to determine what scales should be included in future monitoring studies. We compared four sites in Italy, along gradients of atmospheric pollution and climate, to test the partitioning of the variance components of lichen diversity across spatial scales (from trunks to landscapes). Despite environmental heterogeneity, we observed comparable spatial variance. However, residuals often overcame between-plot variability, leading to biased estimation of atmospheric pollution effects.

  15. Measurements of pollution in the lower layers of the atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Perroud, P.; Sylvestre-Baron, M.; Pleyber, G.; Perilhon, P.; Faivre- Pierret, R.; Closson, A.; Nicotra, C.

    1973-06-01

    The measurement of the meteorological parameters and the sampling of pollutants in the lower levels of the atmosphere were made by the use of captive balloons. A 550 m/sup 3/ airship filled with hydrogen was used with apparatus distributed along the anchor cable up to a height of 1,200 m. The meteorological probes used to measure the pressure, temperature, humidity, and wind velocity and to transmit them to the ground are described. The apparatus for air sampling and the chemical analytical methods are described. The results obtained are reported. This experiment made it possible to prove the relations existing between temperature inversion regions and pollution levels. The results show that under the temperature emission layers the profiles for the diffusion of SO/sub 2/, Cl/ sub 2/, and organic pollutants are sharply different. (tr-auth)

  16. Model JC-1 Laser System for Monitoring Atmospheric Pollution,

    Science.gov (United States)

    2007-11-02

    differential absorption mode atmospheric pollution laser monitoring system, in which a phase locking technique and single board computer are used for...amplification 1 3. synchronous demodulation 2 4. phase locking amplification 2 5. single board computer 6. function logging Instrument 7. oscillator...were then fed into a DBJ-Z80 single - board computer to undergo a multiple averaging process before going through functional operation, and were logged

  17. Atmospheric pollutant outflow from southern Asia: a review

    Science.gov (United States)

    Lawrence, M. G.; Lelieveld, J.

    2010-11-01

    Southern Asia, extending from Pakistan and Afghanistan to Indonesia and Papua New Guinea, is one of the most heavily populated regions of the world. Biofuel and biomass burning play a disproportionately large role in the emissions of most key pollutant gases and aerosols there, in contrast to much of the rest of the Northern Hemisphere, where fossil fuel burning and industrial processes tend to dominate. This results in polluted air masses which are enriched in carbon-containing aerosols, carbon monoxide, and hydrocarbons. The outflow and long-distance transport of these polluted air masses is characterized by three distinct seasonal circulation patterns: the winter monsoon, the summer monsoon, and the monsoon transition periods. During winter, the near-surface flow is mostly northeasterly, and the regional pollution forms a thick haze layer in the lower troposphere which spreads out over millions of square km between southern Asia and the Intertropical Convergence Zone (ITCZ), located several degrees south of the equator over the Indian Ocean during this period. During summer, the heavy monsoon rains effectively remove soluble gases and aerosols. Less soluble species, on the other hand, are lifted to the upper troposphere in deep convective clouds, and are then transported away from the region by strong upper tropospheric winds, particularly towards northern Africa and the Mediterranean in the tropical easterly jet. Part of the pollution can reach the tropical tropopause layer, the gateway to the stratosphere. During the monsoon transition periods, the flow across the Indian Ocean is primarily zonal, and strong pollution plumes originating from both southeastern Asia and from Africa spread across the central Indian Ocean. This paper provides a review of the current state of knowledge based on the many observational and modeling studies over the last decades that have examined the southern Asian atmospheric pollutant outflow and its large scale effects. An outlook

  18. Atmospheric pollutant outflow from southern Asia: a review

    Directory of Open Access Journals (Sweden)

    M. G. Lawrence

    2010-11-01

    Full Text Available Southern Asia, extending from Pakistan and Afghanistan to Indonesia and Papua New Guinea, is one of the most heavily populated regions of the world. Biofuel and biomass burning play a disproportionately large role in the emissions of most key pollutant gases and aerosols there, in contrast to much of the rest of the Northern Hemisphere, where fossil fuel burning and industrial processes tend to dominate. This results in polluted air masses which are enriched in carbon-containing aerosols, carbon monoxide, and hydrocarbons. The outflow and long-distance transport of these polluted air masses is characterized by three distinct seasonal circulation patterns: the winter monsoon, the summer monsoon, and the monsoon transition periods. During winter, the near-surface flow is mostly northeasterly, and the regional pollution forms a thick haze layer in the lower troposphere which spreads out over millions of square km between southern Asia and the Intertropical Convergence Zone (ITCZ, located several degrees south of the equator over the Indian Ocean during this period. During summer, the heavy monsoon rains effectively remove soluble gases and aerosols. Less soluble species, on the other hand, are lifted to the upper troposphere in deep convective clouds, and are then transported away from the region by strong upper tropospheric winds, particularly towards northern Africa and the Mediterranean in the tropical easterly jet. Part of the pollution can reach the tropical tropopause layer, the gateway to the stratosphere. During the monsoon transition periods, the flow across the Indian Ocean is primarily zonal, and strong pollution plumes originating from both southeastern Asia and from Africa spread across the central Indian Ocean. This paper provides a review of the current state of knowledge based on the many observational and modeling studies over the last decades that have examined the southern Asian atmospheric pollutant outflow and its large scale

  19. Identifing Atmospheric Pollutant Sources Using Artificial Neural Networks

    Science.gov (United States)

    Paes, F. F.; Campos, H. F.; Luz, E. P.; Carvalho, A. R.

    2008-05-01

    The estimation of the area source pollutant strength is a relevant issue for atmospheric environment. This characterizes an inverse problem in the atmospheric pollution dispersion. In the inverse analysis, an area source domain is considered, where the strength of such area source term is assumed unknown. The inverse problem is solved by using a supervised artificial neural network: multi-layer perceptron. The conection weights of the neural network are computed from delta rule - learning process. The neural network inversion is compared with results from standard inverse analysis (regularized inverse solution). In the regularization method, the inverse problem is formulated as a non-linear optimization approach, whose the objective function is given by the square difference between the measured pollutant concentration and the mathematical models, associated with a regularization operator. In our numerical experiments, the forward problem is addressed by a source-receptor scheme, where a regressive Lagrangian model is applied to compute the transition matrix. The second order maximum entropy regularization is used, and the regularization parameter is calculated by the L-curve technique. The objective function is minimized employing a deterministic scheme (a quasi-Newton algorithm) [1] and a stochastic technique (PSO: particle swarm optimization) [2]. The inverse problem methodology is tested with synthetic observational data, from six measurement points in the physical domain. The best inverse solutions were obtained with neural networks. References: [1] D. R. Roberti, D. Anfossi, H. F. Campos Velho, G. A. Degrazia (2005): Estimating Emission Rate and Pollutant Source Location, Ciencia e Natura, p. 131-134. [2] E.F.P. da Luz, H.F. de Campos Velho, J.C. Becceneri, D.R. Roberti (2007): Estimating Atmospheric Area Source Strength Through Particle Swarm Optimization. Inverse Problems, Desing and Optimization Symposium IPDO-2007, April 16-18, Miami (FL), USA, vol 1, p

  20. The lacustrine sedimentary records of coal-burning atmospheric pollution

    Institute of Scientific and Technical Information of China (English)

    WANG; Yunfei; HU; Shouyun; ZHU; Yuxin; YIN; Yu; ZHOU; Wangp

    2005-01-01

    Based on the studies on diatom, ostracods and magnetism on a core acquired from lacustrine sediments, as well as correlation analysis between concentration of acid diatom and the instantaneous lowest pH value, the processes of environment evolution in Lake Yangzonghai were reconstructed. The lacustrine environment was favorable in the 1950s, and began to be polluted by a coal-burning power plant since 1960. During 1965-1980, the instantaneous lowest pH value of lake water decreased to 5-6 when heavily polluted. There was a decrease trend in the pollution from 1983 to 1999, but coal-burning atmospheric pollution was still a main problem for environmental retrieving. As acid precipitated, acid-tolerant species overspread, and shellfish disappeared, as well as ferromagnetic particulates dissolved because of the consequent change of pH-Eh values in the interface of water and soil, which results in the change of environmental proxies versus depth. Thus, the environmental evolution of Lake Yangzonghai is reconstructed in this paper based on the inferences mentioned above.

  1. The propagation of light pollution in the atmosphere

    CERN Document Server

    Cinzano, Pierantonio

    2012-01-01

    Methods to map artificial night sky brightness and stellar visibility across large territories or their distribution over the entire sky at any site are based on the computation of the propagation of light pollution with Garstang models, a simplified solution of the radiative transfer problem in the atmosphere which allows a fast computation by reducing it to a ray-tracing approach. We present here up-to-date Extended Garstang Models (EGM) which provide a more general numerical solution for the radiative transfer problem applied to the propagation of light pollution in the atmosphere. We also present the LPTRAN software package, an application of EGM to high-resolution DMSP-OLS satellite measurements of artificial light emissions and to GTOPO30 digital elevation data, which provides an up-to-date method to predict the artificial brightness distribution of the night sky at any site in the World at any visible wavelength for a broad range of atmospheric situations and the artificial radiation density in the atm...

  2. Annual Patterns of Atmospheric Pollutions and Episodes over Cairo Egypt

    Directory of Open Access Journals (Sweden)

    Y. Aboel Fetouh

    2013-01-01

    Full Text Available The Nile Delta major cities, particularly Cairo, experienced stagnant air pollution episodes, known as Black Cloud, every year over the past decade during autumn. Low-elevated thermal inversion layers play a crucial role in intensifying pollution impacts. Carbon monoxide, ozone, atmospheric temperature, water vapor, and methane measurements from the tropospheric emission spectrometer (TES on board the Aura have been used to assess the dominant component below the inversion layer. In this study, time series analysis, autocorrelations, and cross correlations are performed to gain a better understanding of the connections between those parameters and their local effect. Satellite-based data were obtained for the years 2005–2010. The parameters mentioned were investigated throughout the whole year in order to study the possible episodes that take place in addition to their change from year to year. Ozone and carbon monoxide were the two major indicators to the most basic episodes that occur over Cairo and the Delta region.

  3. PCDD/F and WHO-PCB contamination in an industrialized area in Brazil. First results of atmospheric monitoring and the use of Tillandsia usneoides (L) as biomonitor

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, M. de S. [Dept. de Geoquimica, Univ. Federal Fluminense. Niteroi, RJ (Brazil); Waller, U.; Reifenhaeuser, W.; Koerner, W. [Bavarian Environmental Protection Agency, Augsburg (Germany); Torres, J.P.; Malm, O. [Inst. de Biofisica, CCS-UFRJ. Ilha do Fundao, RJ (Brazil)

    2004-09-15

    A major issue of concern in developing countries like Brazil is to conciliate increasing industrialization rates to secure health and environmental standards already required to promote the free market among countries. This was pointed out during the United Nations Conference on Environment and Development in Rio de Janeiro in 1992 (Agenda 21). There it became clear that Brazil needs to develop better methods and techniques for environmental monitoring in order to control pollution sources and promote sustainable development. Among dozens of different kinds of persistent organic pollutants, polychlorinated dibenzodioxins and dibenzofurans (PCDD/PCDF) and polychlorinated biphenyls (PCB) are a matter of great concern due to their persistence, bioaccumulation and toxicological properties. PCDD and PCDF are unwanted by-products from the combustion of organic material containing trace amounts of chlorine set free in both stationary thermal sources and diffuse fuel burning. They can also be present as unwanted by-products of various industrial and metallurgical processes and metal recycling and smelters. PCB are ubiquitous contaminants of the environment and can be produced during thermal processes. In spite of their high environmental persistence and relevance in human health concerns, legal aspects regarding maximum emission limits and control of these contaminants are absent in Brazil at present. Moreover, the absence of adequately equipped laboratories and human resources together with the high costs associated hampers the research and monitoring of these contaminants in Brazil. The present work is a first report of the monitoring of total deposition rates of PCDD/PCDF and PCB in Volta Redonda City, a highly industrialized area in Rio de Janeiro State. Simultaneously, the use of an endemic Bromeliad species, Tillandsia usneoides (L), an epiphytic bromeliad, as a possible bio-monitor for persistent organochlorine compounds was investigated.

  4. Active biomonitoring of mussels Mytilus galloprovincialis with integrated use of micronucleus assay and physiological indices to assess harbor pollution.

    Science.gov (United States)

    Gherras Touahri, Hamida; Boutiba, Zitouni; Benguedda, Wacila; Shaposhnikov, Sergey

    2016-09-15

    The mussels Mytilus galloprovincialis collected from a noncontaminated site (Chaib Rasso) were transplanted during one, three and six months at Ghazaouet harbor (GH), areas with a strong gradient of pollution. The micronucleus test (MN) was selected to monitor the impact of contamination, along with physiological indexes (condition index CI and organo-somatic indexes RI and GSI). The results show a negative correlation of MN variation in gill cells with CI but a positive correlation with transplantation duration. However, a significant correlation was found between the indexes. Moreover, the findings indicate that MN in the hemolymph and gills of transplanted mussels for one, three and six months at GH are significantly higher than those of the reference site. However, no significant differences were noted between the three transplants at the two organs. Monitoring the physiological status of mussels, in parallel with the biomarker measurements, is useful in assessing the impact of contaminants.

  5. 水生植物对水体重金属污染的监测和生态修复%Biomonitoring and Ecological Restoring Heavy Metal Polluted Water by Aquatic Plants

    Institute of Scientific and Technical Information of China (English)

    惠峰; 王良桂

    2013-01-01

    Aquatic plants have excellent ability in biomonitoring and ecological restoring heavy metal polluted water. Bryophytes are excellent biomonitors of heavy metal pollution, so they can be used to monitor and evaluate the heavy metal contamination level of the studied water. Moreover, four life forms of aquatic plants (including emergent, free-drifting, floating-leaved and submergent) all have certain accumulation capacity on heavy metals, so they are appropriate materials for ecological restoring of heavy metal polluted water. Using aquatic plants to treat heavy metal polluted water is a simple and low cost method, and won't bring secondary pollution. This phytoremediation method can not only restore heavy metal pollution, but also prettify the environment and bring direct and indirect economic benefits.%水生植物对水体重金属污染具有良好的监测和生态修复功能.苔藓植物是重金属污染良好的生物监测器,可用于水体重金属污染状况的监测和评价.同时,4种生活型的水生植物(挺水、浮叶、漂浮和沉水植物)对重金属都有一定的富集能力,对重金属污染水体有生态修复作用.利用水生植物对水体进行生态修复具有简便易行、成本较低、不易形成二次污染的优势,在修复水体重金属污染的同时还可以美化环境,并可产生直接或间接的经济效益.

  6. The effect of atmospheric pollution on building materials

    Science.gov (United States)

    Grossi, C. M.; Brimblecombe, P.

    2002-11-01

    This chapter surveys main effects of atmospheric pollution on building materials. It summarises these effects on stone, bricks, mortar, concrete, glass, metals (iron, zinc, copper, bronze, aluminium, lead and silver), polymers, paints and timber. Special attention is paid to stone because of its extensive use as building material in the cultural heritage. In general, main damaging agent is sulfur dioxide which leads to sulfation of many materials, particularly carbonate-bearing stones. However, the decline of sulfur dioxide in cities means that the recognition of the prime role of this pollutant presents something of a dilemma. It is increasingly necessary to consider other substances that can contribute to material decay e.g. nitrogen oxides, chlorides and ozone, either acting as synergistic to the sulfation reaction or as main decay agents, such as the case of aluminium and polymers. Particulate matter often from diesel vehicles can also accelerate the oxidation of SO2 on the surface (traditionally sulfur dioxide with Fe-rich particles) and blacken the materials surface in the case of soot. These processes contribute to the formation of black-crusts when embedded in the gypsum layer resulting from the material sulfation, but again the rate in the modem atmosphere is a matter of much research.

  7. Lead Isotopes and Temporal Records of Atmospheric Aerosol and Pollutants in Lichens

    Science.gov (United States)

    Getty, S. R.; Nash, T.; Asmerom, Y.

    2001-05-01

    Lichens are useful receptors of atmospheric particulate matter (PM) and pollutants due to their retention of body parts (unlike plants), slow growth rates, fairly uniform morphologies, lack of a vascular system, and sessile character over decades to centuries. Lichen biomonitoring has been used widely to map patterns of aerosol deposition, yet few studies have tested whether lichens can preserve a temporal record of airborne PM and pollutants. We show with U-Pb data that epilithic lichens (rock as host) can retain in their porous structure an integrated, decadal-scale history of changing aerosol inputs to desert ecosystems. Three lichens resided along an 80-km transect from a copper smelter (Douglas, AZ) closed in early 1987, to the ENE into adjacent New Mexico. For the radially growing lichen (Xanthoparmelia sp.), U-Pb data were obtained along cm-scale transects in the growth direction on a single thallus. Profiles from lichen rim to interior show increasing [Pb] and [U], or net accumulation with thallus age. Total lead contents are highest near the smelter. In contrast, each lead isotope profile (206Pb/207Pb) is flat during smelter operation, showing low ratios near the smelter (1.152) and high ratios (1.175) 80 km away. This suggests comparable mixtures of crust and smelter lead per locality over decades. Since smelter closure, lichens 80 km from the smelter show a sharp upturn in lead ratio in the recently grown lichen rim, indicating that smelter lead is either dispersed by aeolian recycling, or suppressed in desert soils. The amplitude and position of the isotope signal suggests a soil recovery "half-life" of about 13 yrs, a radial growth rate of 0.57+/-0.1 mm/yr, and a total lichen age of 105+/-18 yrs. Lichens near the smelter have no upturn in isotope ratio, indicating continued aeolian recylcing of lead from soils about 11 yrs after closure. Results at a far-removed desert site (c. New Mexico) also argue that isotope profiles reflect aerosol deposition

  8. Active biomonitoring with Corbicula for USEPA priority pollutant and metal sources in the Anacostia River (DC, Maryland, USA).

    Science.gov (United States)

    Phelps, Harriette L

    2016-07-01

    The freshwater Anacostia River watershed (Maryland, DC, USA) was surveyed for the sources of bioavailable US Environmental Protection Agency (USEPA) Priority Pollutants and toxic metals by active biomontoring (ABM) using the freshwater Asiatic clam Corbicula fluminea. The Anacostia River is a 456 km(2) tributary of the tidal freshwater Potomac River that includes the city of Washington, DC where edible fish are highly contaminated with PCBs and chlordane. From 1999 to 2011, Corbicula were collected for ABM from a Potomac reference site and translocated in cages placed at 45 sites in the tidal and nontidal Anacostia watershed. Minimum clam mortality and maximum contaminant bioaccumulation was with 2-week translocation. The clam tissues (28-50) were combined at sites and analyzed by TestAmerica for 66 USEPA Priority Pollutants plus technical chlordane, benz(e) pyrene, and 6 metals (As, Cd, Cr, Cu, Fe, Pb). Tissue contaminants reflected water, not sediment, levels. To compare sites, all contaminant data above detection or reference were grouped as total metals (TMET), total polycyclic aromatic hydrocarbons (TPAH), total PCB congeners (TPCB), total pesticides (TPEST), and total technical chlordane (TCHL). Tidal Anacostia ABM found highest TPAH and TCHL upstream at Bladensburg Marina (MD) except for TCHL at site PP near the confluence. Five nontidal MD subtributaries (94% of flow) had 17 sites with bioavailable TPAH, TPCB, or TCHL 2 to 3 times higher than found at the toxic-sediment "hotspots" near Washington. The only TMET noted was Fe at 1 site. TPAH in MD subtributaries was highest near industrial parks and Metro stations. A naphthalene spill was detected in Watts Branch. TPCB (low molecular weight) originated upstream at 1 industrial park. Total technical chlordane (80% of TPEST) was 2 to 5 times the US Food and Drug Administration action in 4 nontidal tributaries where heptachlor indicated legacy chlordane dumpsites. Total technical chlordane fell to reference

  9. Atmospheric Pollutions Emissions, environmental challenges of Isfahan City

    Directory of Open Access Journals (Sweden)

    V. Ezzatian

    2013-01-01

    Full Text Available Extended abstract1-IntroductionThe recent fatal events with regard to the rise in the atmospheric pollutants levels have suggested that the reason of their occurrence be more identified. The long-term and short-term effects on the environment caused by pollutants that reached unacceptable level are apparent; existence of pollutatnts has led to short-term effects such as appearance and aggravation of cancer and respiratory‚ optic and lung diseases. The sequence of long-term effects is seen on DNA‚ intelligence and physiology. The air pollution results in water and soil pollution. Of course, aquatics and plants are under the influence of these pollutions. Men are not safe from them because they enter man’s food chain too. The statistical model represented in this research can estimate the acceptable rate of surface- ozone by measuring the climatic data of synoptic meteorology of Isfahan Station and evaluating surface pollution rate of station of the Environment Protection Agency. This research shows that equations that profited from two variables including square sunshine and square carbon monoxide concentration could explain %35 of concentration changes in surface- ozone during a day. Even though multivariable regression models can explain dramatical concentration changes in surface– ozone and protector concentration, practical use of these models is limited because of numerous entrance variables. Ozone as one of the most significant secondary pollutants not only influences general health but also has a considerable effect on agriculture. Surface – ozone is in ppm or ppb and it comprises the number of ozone molecules per million and per billion of air molecule.2- Theoretical basis As regards exceptional importance and poisonous state of ozone special in agriculture, it is essential to measure the rate of this gas for quantitative and qualitative survey of garden products and birds and livestock’s health. In general pollutants threat

  10. Concept of the Flemish human biomonitoring programme.

    Science.gov (United States)

    Schoeters, Greet; Den Hond, Elly; Colles, Ann; Loots, Ilse; Morrens, Bert; Keune, Hans; Bruckers, Liesbeth; Nawrot, Tim; Sioen, Isabelle; De Coster, Sam; Van Larebeke, Nicolas; Nelen, Vera; Van de Mieroop, Els; Vrijens, Jan; Croes, Kim; Goeyens, Karen; Baeyens, Willy

    2012-02-01

    Since 2002 a human biomonitoring network has been established in Flanders (Belgium) as part of a programme on environmental health surveillance. The human biomonitoring network should support environmental health policy by identifying priorities for further action. The first cycle of the programme (2002-2006) confirmed the hypotheses that living in areas with different environmental pressure is reflected in different loads of environmental chemicals in the residents. In the second cycle of the programme (2007-2011) the number of environmental chemicals for which human biomonitoring data were obtained was expanded substantially. The goal of the Flemish programme is to use and translate the scientific results into policy actions. Its further orientation in the second cycle to human biomonitoring in hot spots and sensitive age groups or susceptible persons with underlying complications (e.g. persons with diabetes) are linked to these goals. Interaction with stakeholders is embedded in the programme emphasizing transparency of the choices that are made and direct communication. The Flemish human biomonitoring programme is organized centrally with major involvement of research partners from different disciplines which allows engrafting environmental health research on the programme. One of the major focuses is the question whether combinations of pollutants in the general population are associated with biological effects. The objective of this paper is to review and discuss the options that were taken in the human biomonitoring programme in order to achieve its goals.

  11. Circulating metals and persistent organic pollutant concentrations in Canadian and non-Canadian born primiparous women from five Canadian centres: Results of a pilot biomonitoring study

    Energy Technology Data Exchange (ETDEWEB)

    Foster, Warren G., E-mail: fosterw@mcmaster.ca [Department of Obstetrics and Gynecology, McMaster University, Hamilton, Ontario (Canada); Cheung, Anthony P. [University of British Columbia, Vancouver, British Columbia (Canada); Davis, Karelyn [Environmental Health Science and Research Bureau, Healthy Environments and Consumer Safety Branch, Health Canada (Canada); Graves, Gillian [Dalhousie University, Halifax, Nova Scotia (Canada); Jarrell, John [University of Calgary, Calgary, Alberta (Canada); Leblanc, Alain [Institut national de sante publique, Quebec City, Quebec (Canada); Liang, Chun Lei [Environmental Health Science and Research Bureau, Healthy Environments and Consumer Safety Branch, Health Canada (Canada); Leech, Tara [Chemicals Surveillance Bureau, Healthy Environments and Consumer Safety Branch, Health Canada, Ottawa, Ontario (Canada); Walker, Mark [University of Ottawa, Ottawa, Ontario (Canada); Weber, Jean Philippe [Institut national de sante publique, Quebec City, Quebec (Canada); Van Oostdam, Jay [Chemicals Surveillance Bureau, Healthy Environments and Consumer Safety Branch, Health Canada, Ottawa, Ontario (Canada)

    2012-10-01

    The developing foetus is thought to be at increased risk from exposure to environmental contaminants; however, developmental exposure data is notably lacking for many contaminants. Moreover, potential regional differences or effect of place of birth on residue levels measured in pregnant women is also unknown. Therefore, as part of a multinational biomonitoring study, 125 primiparous pregnant Canadian women were recruited from five Canadian centres (Vancouver, Calgary, Hamilton, Ottawa, and Halifax). Metals in whole blood and persistent organic pollutants (POPs) in plasma were measured by inductively coupled plasma mass spectrometry (ICPMS) and gas chromatography-mass spectrometry (GCMS), respectively. Of the 125 women recruited to this study, complete data sets were available for 123 of which 103 were Canadian born. Data were analysed by analysis of covariance and linear mixed models using age and body mass index as covariates. The metals cadmium (Cd), cobalt (Co), lead (Pb), nickel (Ni), selenium (Se), and total mercury (Hg) were detected in more than 93% of the samples tested. {beta}-Hexachlorohexane ({beta}-HCH), oxychlordane, trans-nonachlor, 1,1-dichloro-2,2-bis(p-chlorophenyl)ethylene (p,p Prime -DDE), polybrominated diphenyl ether (PBDE) congeners (PBDE-153, PBDE-47), polychlorinated biphenyl (PCB) congeners (PCB-138, -153, and -180), and the dioxin-like PCB congener PCB-118 were quantified in greater than 70% of the samples tested. Significant differences in the concentrations of Cd, Ni, PCB-153, and p,p Prime -DDE were found between the centres studied. Furthermore, foreign-born pregnant women had significantly higher concentrations of Cd, {beta}-HCH, PBDE-47, PCB-138, -153, -180, and p,p Prime -DDE compared to Canadian born pregnant women. Taken together, the data suggest that there are potential regional differences in contaminant body burden and place of birth may also contribute to differences in maternal residue concentrations. -- Highlights: Black

  12. Geoinformation modeling system for analysis of atmosphere pollution impact on vegetable biosystems using space images

    Science.gov (United States)

    Polichtchouk, Yuri; Ryukhko, Viatcheslav; Tokareva, Olga; Alexeeva, Mary

    2002-02-01

    Geoinformation modeling system structure for assessment of the environmental impact of atmospheric pollution on forest- swamp ecosystems of West Siberia is considered. Complex approach to the assessment of man-caused impact based on the combination of sanitary-hygienic and landscape-geochemical approaches is reported. Methodical problems of analysis of atmosphere pollution impact on vegetable biosystems using geoinformation systems and remote sensing data are developed. Landscape structure of oil production territories in southern part of West Siberia are determined on base of processing of space images from spaceborn Resource-O. Particularities of atmosphere pollution zones modeling caused by gas burning in torches in territories of oil fields are considered. For instance, a pollution zones were revealed modeling of contaminants dispersal in atmosphere by standard model. Polluted landscapes areas are calculated depending on oil production volume. It is shown calculated data is well approximated by polynomial models.

  13. Importance of soil contamination in Hylocomium Splendens used as biomonitor of atmospheric trace element deposition in remote areas; Importanza della contaminazione da suolo in Hylocmium Splendens utilizzato come biomonitor della deposizione atmosferica di elementi in traccia in zone remote

    Energy Technology Data Exchange (ETDEWEB)

    Spazzano, P.; Bari, A.; Olivetta, A. [ENEA, Saluggia, VC (Italy). Dipt. Ambiente, Sez. Componente Biotica degli Ecosistemi

    1999-09-01

    In the framework of a monitoring programme in rural areas using Hylocomium Splendens as biomonitor, several mass and soil samples were collected in different sampling stations. The soil content of analysed moss samples ranged from 1.7 to 7.7% on a dry mass basis as evaluated using aluminium as an indicator of soil retention. Soil particles entrapped by mosses affect the contamination levels of trace elements contributing to the variability of element concentrations. The normalisation of mass concentrations to the element concentrations in surface soils by calculating enrichment factor (EF) does not seem to be able to discriminate between soil-derived and anthropogenic contribution of trace elements. [Italian] Nell'ambito di un progetto di monitoraggio della deposizione atmosferica di metalli pesanti in zone rurali sono stati raccolti in differenti stazioni campioni di muschio e di suolo superficiale. L'articolo analizza i risultati ottenuti: le particelle di suolo ritenute nei muschi condizionano notevolmente i livelli di metalli in traccia di interesse ambientale e contribuiscono alla variabilita' delle concentrazioni. La normalizzazione rispetto alle concetrazioni presenti nel suolo e calcolata mediante il fattore di arricchimento (FA) non sembra in grado di differenziare tra contributo di origine terrigena ed eventuale contributo antropico.

  14. An Important Supplement to NAA in Study on Atmosphere Pollution:Determination of Black Carbon

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>Light absorption in the atmosphere is dominated by elemental carbon (EC), sometimes called black carbon (BC). Black carbon is an important indication of man-made pollution in airborne particulate matter

  15. The atmospheric pollution in a few words; La pollution atmospherique en bref

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-07-01

    This paper takes stock briefly on the different pollution sources (carbon dioxide, nitrogen oxides, sulfur dioxide, VOC, methane...), the mechanisms (acidification, photochemical pollution, eutrophication, greenhouse effect, ozone...) and the effects on the health. (A.L.B.)

  16. Atmospheric transport of persistent organic pollutants to aquatic ecosystems

    Energy Technology Data Exchange (ETDEWEB)

    Agrell, Cecilia

    1999-04-01

    The load of persistent organic pollutants (POPs) is considered high in the Baltic ecosystem. The Baltic Sea spans over 12 latitudes and the regional differences in climate affect the behavior of POPs. Therefore spatial and temporal variability of the concentrations of POPs in air and precipitation within this area has been investigated at 16 (mostly rural) stations around the Baltic Sea between 1990-1993. In addition, the deposition of gaseous and particulate associated POPs to the Baltic Sea is estimated from empirical data. This atmospheric input of POPs is compared with the input from rivers. Additionally, data from Ross Island, Antarctica and Lake Kariba, Zimbabve, Africa is presented, and all results are discussed and explained using the `global fractionation hypothesis` as a framework. In the Baltic Sea, concentration of individual POPs in air were found to be influenced by their physical-chemical properties, ambient air temperature and location. A latitudinal gradient, with higher levels in the south was found for PCBs and the gradient was more pronounced for the low volatility congeners. As a result, the high volatility congeners in air increased in relative importance with latitude. Generally, PCB concentration increased with temperature, but slopes of the partial pressure in air versus reciprocal temperature were different between congeners and between stations. In general, the low volatility congeners were more temperature dependent than the high volatility PCB congeners. Steep slopes at a sampling location indicate that the concentration in air is largely determined by diffusive exchange with soils. Lack of a temperature dependence may be due to the influence of long-range transported air masses at remote sites and due to the episodic, or random nature of PCB sources at urban sites. The concentrations of individual congeners in precipitation were found to be influenced by atmospheric concentrations of PCBs, ambient temperature, precipitation volume and

  17. Fluid mechanics simulation of fog formation associated with polluted atmosphere produced by energy related fuel combustion

    Science.gov (United States)

    Hung, R. J.; Liaw, G. S.

    1980-01-01

    It is noted that large quantities of atmospheric aerosols with composition SO4(-2), NO3(-1), and NH4(+1) have been detected in highly industrialized areas. Most aerosol products come from energy-related fuel combustion. Fluid mechanics simulation of both microphysical and macrophysical processes is considered in studying the time dependent evolution of the saturation spectra of condensation nuclei associated with polluted and clean atmospheres during the time periods of advection fog formation. The results demonstrate that the condensation nuclei associated with a polluted atmosphere provide more favorable conditions than condensation nuclei associated with a clean atmosphere to produce dense advection fog, and that attaining a certain degree of supersaturation is not necessarily required for the formation of advection fog having condensation nuclei associated with a polluted atmosphere.

  18. Advection of pollutants by internal solitary waves in oceanic and atmospheric stable stratifications

    Directory of Open Access Journals (Sweden)

    G. W. Haarlemmer

    1998-01-01

    Full Text Available When a pollutant is released into the ocean or atmosphere under turbulent conditions, even a steady release is captured by large eddies resulting in localized patches of high concentration of the pollutant. If such a cloud of pollutant subsequently enters a stable stratification-either a pycnocline or thermocline-then internal waves are excited. Since large solitary internal waves have a recirculating core, pollutants may be trapped in the sclitary wave, and advected large distances through the waveguide provided by the stratification. This paper addresses the mechanisms, through computer and physical simulation, by which a localized release of a dense pollutant results in solitary waves that trap the pollutant or disperse the pollutant faster than in the absence of the waves.

  19. On the use of Arion ater to biomonitor environmental pollution by Cd, Cu, Fe, Mn and Zn, with a special insight into the population variability.

    Science.gov (United States)

    Crespo, D; Bolón, M; Aboal, J R; Fernández, J A; Carballeira, A

    2015-05-01

    The suitability of Arion ater as a biomonitor of Cd, Cu, Fe, Mn and Zn was assessed. Individual specimens were collected from 22 sampling sites. Slugs from 3 of the sites were analysed individually, whereas the slugs from the other sites were pooled to make a composite sample for each site. The tissue burdens did not differ between individuals from contaminated and uncontaminated sites, and there was no gradient of bioaccumulation of any of the elements in the surroundings of the smelter. Analysis of the individual specimens from the 3 sites revealed very high coefficients of variation for the metal concentrations. As a result of the high level of variation, large numbers of slugs are required to produce a low error in characterizing the mean concentration at each site. Furthermore, as a consequence of the similar mean concentrations and high variability, large numbers of samples are needed to detect significant differences between pairs of sites.

  20. Spatial structure and scale feature of the atmospheric pollution source impact of city agglomeration

    Institute of Scientific and Technical Information of China (English)

    XU; Xiangde; ZHOU; Xiuji; SHI; Xiaohui

    2005-01-01

    The spatial structure and multi-scale feature of the atmospheric pollution influence domain of Beijing and its peripheral areas (a rapidly developed city agglomeration) is dissected and analyzed in this paper on the basis of the atmospheric pollution dynamic-chemical process observation data of the urban building ensemble boundary layer of the Beijing City Air Pollution Observation Experiment (BECAPEX) in winter (February) and summer (August) 2003, and relevant meteorological elements and satellite retrieval aerosol optical depth (AOD), etc. comprehensive data with the dynamic-statistical integrated analysis of "point-surface" spatial structure. Results show that there existed significant difference in the contribution of winter/summer different pollution emission sources to the component character of atmospheric pollution, and the principal component analysis (PCA) results of statistical model also indicate that SO2 and NOX dominated in the component structure of winter aerosol particle; instead, CO and NOX dominated in summer. Surface layer atmospheric dynamic and thermal structures and various pollutant species at the upper boundary of building ensembles at urban different observational sites of Beijing in winter and summer showed an "in-phase" variation and its spatial scale feature of "influence domain". The power spectrum analysis (PSA) shows that the period spectrum of winter/summer particle concentration accorded with those of atmospheric wind field: the longer period was dominative in winter, but the shorter period in summer, revealing the impact of the seasonal scale feature of winter/summer atmospheric general circulation on the period of atmospheric pollution variations. It is found that from analyzing urban area thermal heterogeneity that the multiscale effect of Beijing region urban heat island (UHI) was associated with the heterogeneous expansion of tall buildings area. In urban atmospheric dynamical and thermal characteristic spatial structures, the

  1. Atmospheric chemistry and physics from air pollution to climate change

    CERN Document Server

    Seinfeld, John H

    2016-01-01

    Expanded and updated with new findings and new features Since the second edition of Seinfeld and Pandis’ classic textbook, significant progress has taken place in the field of atmospheric chemistry and physics, particularly in the areas of tropospheric chemistry, aerosols, and the science of climate change. A new edition of this comprehensive work has been developed by the renowned author team. Atmospheric Chemistry and Physics, 3rd Edition, as the previous two editions have done, provides a rigorous and comprehensive treatment of the chemistry and physics of the atmosphere – including the chemistry of the stratosphere and troposphere, aerosol physics and chemistry, atmospheric new particle formation, physical meteorology, cloud physics, global climate, statistical analysis of data, and mathematical chemical/transport models of the atmosphere. Each of these topics is covered in detail and in each area the central results are developed from first principles. In this way the reader gains a significant un...

  2. Contribution to the modeling of atmospheric pollution in cities; Contribution a la modelisation de la pollution atmospherique dans les villes

    Energy Technology Data Exchange (ETDEWEB)

    Glockmer, St.

    2000-07-01

    Pollution generated by urban traffic and by industry at its periphery is a serious problem of our cities. Once emitted in the atmosphere, pollutants undergo two types of constraints: on one side they react chemically one with another and, on the other side, they are transported by the wind. We have chosen to work on the dynamical, thermal and chemical aspects of the pollution at different scales of the phenomena: local scale (around a group of buildings) and meso-scale (a whole city). Our ambition is not to realize a complete model but to advance step by step on each aspect. We have contributed to the realization of a numerical tool that will be completed and used for concrete pollution episodes. The first chapter is a description of the atmospheric boundary layer. Chapters two and three present models and results of numerical simulations. We stress on k-{epsilon}, RNG and v{sup 2}-f turbulence models, radiative heat transfer models and dynamical and thermal wall laws that allow to take in consideration surface roughness. The last chapter is dedicated to atmospheric chemistry. We have moreover developed a general solver of any number of transport equations coupled by a stiff chemistry and simplified ozone kinetics. (author)

  3. Significant atmospheric aerosol pollution caused by world food cultivation

    Science.gov (United States)

    Bauer, Susanne E.; Tsigaridis, Kostas; Miller, Ron

    2016-05-01

    Particulate matter is a major concern for public health, causing cancer and cardiopulmonary mortality. Therefore, governments in most industrialized countries monitor and set limits for particulate matter. To assist policy makers, it is important to connect the chemical composition and severity of particulate pollution to its sources. Here we show how agricultural practices, livestock production, and the use of nitrogen fertilizers impact near-surface air quality. In many densely populated areas, aerosols formed from gases that are released by fertilizer application and animal husbandry dominate over the combined contributions from all other anthropogenic pollution. Here we test reduction scenarios of combustion-based and agricultural emissions that could lower air pollution. For a future scenario, we find opposite trends, decreasing nitrate aerosol formation near the surface while total tropospheric loads increase. This suggests that food production could be increased to match the growing global population without sacrificing air quality if combustion emission is decreased.

  4. Significant Atmospheric Aerosol Pollution Caused by World Food Cultivation

    Science.gov (United States)

    Bauer, Susanne E.; Tsigaridis, Kostas; Miller, Ron

    2016-01-01

    Particulate matter is a major concern for public health, causing cancer and cardiopulmonary mortality. Therefore, governments in most industrialized countries monitor and set limits for particulate matter. To assist policy makers, it is important to connect the chemical composition and severity of particulate pollution to its sources. Here we show how agricultural practices, livestock production, and the use of nitrogen fertilizers impact near-surface air quality. In many densely populated areas, aerosols formed from gases that are released by fertilizer application and animal husbandry dominate over the combined contributions from all other anthropogenic pollution. Here we test reduction scenarios of combustion-based and agricultural emissions that could lower air pollution. For a future scenario, we find opposite trends, decreasing nitrate aerosol formation near the surface while total tropospheric loads increase. This suggests that food production could be increased to match the growing global population without sacrificing air quality if combustion emission is decreased.

  5. The effects of atmospheric pollutants upon standstone: evidence from real time measurements and analysis of decay features on historic buildings

    Energy Technology Data Exchange (ETDEWEB)

    Halsey, D.P.; Dews, J.; Harris, F.C. [Wolverhampton Univ. (United Kingdom). School of Construction, Engineering and Technology; Mitchell, D.J. [Wolverhampton Univ. (United Kingdom). School of Applied Sciences

    1995-12-31

    Due to the urbanisation and industrialisation of the West Midlands, UK, historic sandstone buildings are exposed to atmospheric pollution. In order to assess the impact of this pollution upon their deterioration, chemical analysis of runoff water, from sandstone and control surfaces, has been carried out. The amount of stone affected by atmospheric pollution has been quantified by surveying selected sandstone buildings. (author)

  6. Low level atmospheric sulfur dioxide pollution and childhood asthma

    Energy Technology Data Exchange (ETDEWEB)

    Tseng, R.Y.; Li, C.K. (Chinese Univ. of Hong Kong (Hong Kong))

    1990-11-01

    Quarterly analysis (1983-1987) of childhood asthma in Hong Kong from 13,620 hospitalization episodes in relation to levels of pollutants (SO{sub 2}, NO{sub 2}, NO, O{sub 3}, TSP, and RSP) revealed a seasonal pattern of attack rates that correlates inversely with exposure to sulfur dioxide (r = -.52, P less than .05). The same cannot be found with other pollutants. Many factors may contribute to the seasonal variation of asthma attacks. We speculate that prolonged exposure (in terms of months) to low level SO{sub 2} is one factor that might induce airway inflammation and bronchial hyperreactivity and predispose to episodes of asthma.

  7. [Characteristics of Winter Atmospheric Mixing Layer Height in Beijing-Tianjin-Hebei Region and Their Relationship with the Atmospheric Pollution].

    Science.gov (United States)

    Li, Meng; Tang, Gui-qian; Huang, Jun; Liu, Zi-rui; An, Jun-lin; Wang, Yue-si

    2015-06-01

    Atmospheric mixing layer height (MLH) is one of the main factors affecting the atmospheric diffusion and plays an important role in air quality assessment and distribution of the pollutants. Based on the ceilometers data, this paper has made synchronous observation on MLH in Beijing-Tianjin-Hebei region (Beijing, Tianjin, Shijiazhuang and Qinhuangdao) in heavy polluted February 2014 and analyzed the respective overall change and its regional features. Results show that in February 2014,the average of mixing layer height in Qinhuangdao is the highest, up to 865 +/- 268 m, and in Shijiazhuang is the lowest (568 +/- 207 m), Beijing's and Tianjin's are in between, 818 +/- 319 m and 834 +/- 334 m respectively; Combined with the meteorological data, we find that radiation and wind speed are main factors of the mixing layer height; The relationship between the particle concentration and mixing layer height in four sites suggests that mixing layer is less than 800 m, concentration of fine particulate matter in four sites will exceed the national standard (GB 3095-2012, 75 microg x m(-3)). During the period of observation, the proportion of days that mixing layer is less than 800 m in Beijing, Tianjin, Shijiazhuang and Qinhuangdao are 50%, 43%, 80% and 50% respectively. Shijiazhuang though nearly formation contaminant concentration is high, within the atmospheric mixed layer pollutant load is not high. Unfavorable atmospheric diffusion conditions are the main causes of heavy pollution in Shijiazhuang for a long time. The results of the study are of great significance for cognitive Beijing-Tianjin-Hebei area pollution distribution, and can provide a scientific reference for reasonable distribution of regional pollution sources.

  8. ATMOSPHERE POLLUTION AT STORAGE OF SLAGS OF ALUMINIUM SECONDARY PROCESSING

    Directory of Open Access Journals (Sweden)

    A. S. Panasyugin

    2013-01-01

    Full Text Available Thermodynamic probability of the processes of the formation of compounds of aluminum (which release in the environment by hydrolysis ammonia, acetylene, propane and hydrogen sulfide is determined. In the article the economic loss from irrecoverable waste of aluminum and fines for emissions of air pollutants is estimated.

  9. A Review of the Effects of Major Atmospheric Pollutants on Pollen Grains, Pollen Content, and Allergenicity

    Directory of Open Access Journals (Sweden)

    Hélène Sénéchal

    2015-01-01

    Full Text Available This review summarizes the available data related to the effects of air pollution on pollen grains from different plant species. Several studies carried out either on in situ harvested pollen or on pollen exposed in different places more or less polluted are presented and discussed. The different experimental procedures used to monitor the impact of pollution on pollen grains and on various produced external or internal subparticles are listed. Physicochemical and biological effects of artificial pollution (gaseous and particulate on pollen from different plants, in different laboratory conditions, are considered. The effects of polluted pollen grains, subparticles, and derived aeroallergens in animal models, in in vitro cell culture, on healthy human and allergic patients are described. Combined effects of atmospheric pollutants and pollen grains-derived biological material on allergic population are specifically discussed. Within the notion of “polluen,” some methodological biases are underlined and research tracks in this field are proposed.

  10. A Review of the Effects of Major Atmospheric Pollutants on Pollen Grains, Pollen Content, and Allergenicity

    Science.gov (United States)

    Sénéchal, Hélène; Visez, Nicolas; Charpin, Denis; Shahali, Youcef; Peltre, Gabriel; Biolley, Jean-Philippe; Lhuissier, Franck; Couderc, Rémy; Yamada, Ohri; Malrat-Domenge, Audrey; Pham-Thi, Nhân; Poncet, Pascal; Sutra, Jean-Pierre

    2015-01-01

    This review summarizes the available data related to the effects of air pollution on pollen grains from different plant species. Several studies carried out either on in situ harvested pollen or on pollen exposed in different places more or less polluted are presented and discussed. The different experimental procedures used to monitor the impact of pollution on pollen grains and on various produced external or internal subparticles are listed. Physicochemical and biological effects of artificial pollution (gaseous and particulate) on pollen from different plants, in different laboratory conditions, are considered. The effects of polluted pollen grains, subparticles, and derived aeroallergens in animal models, in in vitro cell culture, on healthy human and allergic patients are described. Combined effects of atmospheric pollutants and pollen grains-derived biological material on allergic population are specifically discussed. Within the notion of “polluen,” some methodological biases are underlined and research tracks in this field are proposed. PMID:26819967

  11. Atmospheric pollution assessment with mosses in Western Rhodopes, Bulgaria

    Directory of Open Access Journals (Sweden)

    Gana Gecheva

    2016-09-01

    Full Text Available The moss analysis technique was applied to monitor 10 heavy metals and toxic elements deposition. Our study was the first attempt to assess spatial patterns in a border mountain region (area 8732 km2 with a low population density and high proportion of protected territories. The obtained results did not correlate to the results from areas with low air pollution and could be linked to the impact of old and open mines.

  12. Study of atmospheric dynamics and pollution in the coastal area of English Channel using clustering technique

    Science.gov (United States)

    Sokolov, Anton; Dmitriev, Egor; Delbarre, Hervé; Augustin, Patrick; Gengembre, Cyril; Fourmenten, Marc

    2016-04-01

    The problem of atmospheric contamination by principal air pollutants was considered in the industrialized coastal region of English Channel in Dunkirk influenced by north European metropolitan areas. MESO-NH nested models were used for the simulation of the local atmospheric dynamics and the online calculation of Lagrangian backward trajectories with 15-minute temporal resolution and the horizontal resolution down to 500 m. The one-month mesoscale numerical simulation was coupled with local pollution measurements of volatile organic components, particulate matter, ozone, sulphur dioxide and nitrogen oxides. Principal atmospheric pathways were determined by clustering technique applied to backward trajectories simulated. Six clusters were obtained which describe local atmospheric dynamics, four winds blowing through the English Channel, one coming from the south, and the biggest cluster with small wind speeds. This last cluster includes mostly sea breeze events. The analysis of meteorological data and pollution measurements allows relating the principal atmospheric pathways with local air contamination events. It was shown that contamination events are mostly connected with a channelling of pollution from local sources and low-turbulent states of the local atmosphere.

  13. Atmospheric pollutants in peri-urban forests of Quercus ilex: evidence of pollution abatement and threats for vegetation.

    Science.gov (United States)

    García-Gómez, Héctor; Aguillaume, Laura; Izquieta-Rojano, Sheila; Valiño, Fernando; Àvila, Anna; Elustondo, David; Santamaría, Jesús M; Alastuey, Andrés; Calvete-Sogo, Héctor; González-Fernández, Ignacio; Alonso, Rocío

    2016-04-01

    Peri-urban vegetation is generally accepted as a significant remover of atmospheric pollutants, but it could also be threatened by these compounds, with origin in both urban and non-urban areas. To characterize the seasonal and geographical variation of pollutant concentrations and to improve the empirical understanding of the influence of Mediterranean broadleaf evergreen forests on air quality, four forests of Quercus ilex (three peri-urban and one remote) were monitored in different areas in Spain. Concentrations of nitrogen dioxide (NO2), ammonia (NH3), nitric acid (HNO3) and ozone (O3) were measured during 2 years in open areas and inside the forests and aerosols (PM10) were monitored in open areas during 1 year. Ozone was the only air pollutant expected to have direct phytotoxic effects on vegetation according to current thresholds for the protection of vegetation. The concentrations of N compounds were not high enough to directly affect vegetation but could be contributing through atmospheric N deposition to the eutrophization of these ecosystems. Peri-urban forests of Q. ilex showed a significant below-canopy reduction of gaseous concentrations (particularly NH3, with a mean reduction of 29-38%), which indicated the feasibility of these forests to provide an ecosystem service of air quality improvement. Well-designed monitoring programs are needed to further investigate air quality improvement by peri-urban ecosystems while assessing the threat that air pollution can pose to vegetation.

  14. [Long-distance transportation of atmospheric pollutants and its effects on ecosystems].

    Science.gov (United States)

    Guardans, R; Gimeno, B S

    1994-01-01

    It was known, as far back as the nineteenth century, that rain water from industrial areas was more acid than that from rural areas. The potential risks for life in general were discussed, but no further attention was paid to the issue. At the end of the twentieth century, the ecosystems of Europe, Canada and the United States have been severely damaged by pollutants borne by atmospheric winds to places distant from their origin. The main effects of these atmospheric pollutants are due to sulfur and nitrogen oxide dilution and to photochemical reactions. International organizations have been formed and agreements pronounced and ratified by many countries for a universal study on the pollution process, on the transport of pollutants--mostly sulfur, nitrogen and ozone--and on how to collaborate in order to reduce emissions in the respective countries of origin for the worldwide profit.

  15. Air pollution forecasting by coupled atmosphere-fire model WRF and SFIRE with WRF-Chem

    CERN Document Server

    Kochanski, Adam K; Mandel, Jan; Clements, Craig B

    2013-01-01

    Atmospheric pollution regulations have emerged as a dominant obstacle to prescribed burns. Thus, forecasting the pollution caused by wildland fires has acquired high importance. WRF and SFIRE model wildland fire spread in a two-way interaction with the atmosphere. The surface heat flux from the fire causes strong updrafts, which in turn change the winds and affect the fire spread. Fire emissions, estimated from the burning organic matter, are inserted in every time step into WRF-Chem tracers at the lowest atmospheric layer. The buoyancy caused by the fire then naturally simulates plume dynamics, and the chemical transport in WRF-Chem provides a forecast of the pollution spread. We discuss the choice of wood burning models and compatible chemical transport models in WRF-Chem, and demonstrate the results on case studies.

  16. Study on the Total Amount Control of Atmospheric Pollutant Based on GIS

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    Objective To provide effective environmental management for total amount control of atmospheric pollutants. Methods An atmospheric diffusion model of sulfur dioxide on the surface of the earth was established and tested in Shantou of Guangdong Province on the basis of an overall assessment of regional natural environment, social economic state of development, pollution sources and atmospheric environmental quality. Compared with actual monitoring results in a studied region, simulation values fell within the range of two times of error and were evenly distributed in the two sides of the monitored values. Predicted with the largest emission model method, the largest emission of sulfur dioxide would be 54 279.792 tons per year in 2010. Conclusion The mathematical model established and revised on the basis of GIS is more rational and suitable for the regional characteristics of total amount control of air pollutants.

  17. Means of atmospheric air pollution reduction during drilling wells

    Science.gov (United States)

    Shkitsa, L.; Yatsyshyn, T.; Lyakh, M.; Sydorenko, O.

    2016-08-01

    The process of drilling oil and gas wells is the source of air pollution through drilling mud evaporation containing hazardous chemical substances. The constructive solution for cleaning device of downhole tool that contains elements covering tube and clean the surface from the mud in the process of rising from the well is offered. Inside the device is filled with magnetic fluid containing the substance neutralizing hazardous substances. The use of the equipment proposed will make it possible to avoid penetration of harmful substances into the environment and to escape the harmful effects of aggressive substances for staff health and increase rig's fire safety.

  18. Application of cascade lasers to detection of trace gaseous atmospheric pollutants

    Science.gov (United States)

    Miczuga, Marcin; Kopczyński, Krzysztof

    2016-12-01

    Understanding the impact of gaseous pollutants on the earth's atmosphere, as well as more and more felt by mankind negative effects of its contamination, result in increasing the level of environmental awareness and contribute to the intensification of actions aimed at reducing the emission of harmful gases into the atmosphere. At the same time, the extensive studies are conducted in order to continuously monitor the level of air contamination with harmful gases and the industry compliance with the standards limited the amount of emitted pollutants. Over recent years, there has been increasing use of cascade lasers and multi-pass cells in optical systems detecting the gaseous atmospheric pollutants and measuring the gas concentrations. The paper presents the use of a tunable quantum cascade laser as a source of the IR radiation in an advanced detection system enabling the trace gaseous atmospheric pollutants to be identified. Apart from the laser, the main elements of the system are: a multi-pass cell, an IR detector and a module for control and analysis. Operation of the system is exemplified by measuring the level of the air pollution with ammonia, carbon oxide and nitrous oxide.

  19. BIOMONITORING USING AQUATIC VEGETATION

    Science.gov (United States)

    This chapter provides an overview of the state-of-the-science as related to the phytoassessment techniques used in environmental biomonitoring and the hazard assessment process for chemicals. The emphasis is on freshwater angiosperms and bryophytes. Algal species, which are prese...

  20. An estimation of the total atmospheric pollution in Quetta (Pakistan) using solar data

    Energy Technology Data Exchange (ETDEWEB)

    Ilyas, Syed Z.; Nasir, S.M. [University of Balochistan, Group of Renewable Energy, Department of Physics, Quetta (Pakistan); Veziroglu, T.N. [University of Miami, Clean Energy Institute, Department of Mechanical Engineering, Miami, FL (United States)

    2007-11-15

    A new approach for the estimation of the total atmospheric pollution is suggested by using solar energy data. The dispersion of global solar radiation is relatively large during summer (June, July and August) and autumn (September, October, November) seasons for Quetta. A continuous relative attenuation of the order of 6-14% is due to presence of fine dust particles and pollutants throughout the year in the lower atmosphere at Quetta. Our results indicate an increased difference in the relative attenuation of global solar radiation for winter when compared with summer due to combustion of natural gas and mined coal for heating of buildings. (orig.)

  1. Environmental epidemiology applied to urban atmospheric pollution: a contribution from the Experimental Air Pollution Laboratory (LPAE

    Directory of Open Access Journals (Sweden)

    André Paulo Afonso de

    2000-01-01

    Full Text Available Systematic investigation on the effects of human exposure to environmental pollution using scientific methodology only began in the 20th century as a consequence of several environmental accidents followed by an unexpected mortality increase above expected mortality and as a result of observational epidemiological and toxicological studies conducted on animals in developed countries. This article reports the experience of the Experimental Air Pollution Laboratory at the School of Medicine, University of São Paulo, concerning the respiratory system and pathophysiological mechanisms involved in responses to exposure to pollution using toxicological and experimental procedures, complemented by observational epidemiological studies conducted in the city of São Paulo. It also describes these epidemiological studies, pointing out that air pollution is harmful to public health, not only among susceptible groups but also in the general population, even when the concentration of pollutants is below the limits set by environmental legislation. The study provides valuable information to support the political and economic decision-making processes aimed at preserving the environment and enhancing quality of life.

  2. Saving the atmosphere. International law, developing countries and air pollution

    Energy Technology Data Exchange (ETDEWEB)

    Biermann, F.

    1995-08-01

    The protection of global ecological systems which are threatened by human activities has evolved into one of the most dynamic and important areas of international law and politics. Most prominently, the chemical composition of the Earth`s atmosphere has increasingly been modified by human interference, followed by regular `holes` in the stratospheric ozone layer, possible change of the global climate and various other damages. Since the 1970s, the international community has reacted by negotiating several binding agreements on environmental policies and by establishing new rules of general customary law binding upon all States. This emerging Law of the Atmosphere is the subject of this study, thereby paying special attention to the differences in the legal status of industrialised and developing countries according to their distinct responsibilities and economic and social capabilities. (orig./KW)

  3. Use of Arius thalassinus fish in a pollution biomonitoring study, applying combined oxidative stress, hematology, biochemical and histopathological biomarkers: A baseline field study.

    Science.gov (United States)

    Saleh, Yousef S; Marie, Mohamed-Assem S

    2016-05-15

    The present field study aimed to determine the extent of pollution in the Red Sea coast of Yemen Republic using a battery of biomarkers in sea catfish, Arius thalassinus, originating from a reference site in comparison with a polluted site. We reported the concentration of heavy metals in some vital fish organs and their effects on the morphological, hematological, biochemical and oxidative stress biomarkers accompanied by the examination of histopathological alterations. The obtained results showed clear signs of stress in fish from a polluted site. Linear correlation analysis exhibited that the biomarkers response could be linked to the detected metals bioaccumulation. In addition, principal component analysis showed a clear separation of sampling sites in two different assemblages. Semi-quantitative analysis for the observed histopathological lesions revealed that gills were the most affected organs with signs of severe alterations. This field investigation provides a baseline data on pollution status in this region.

  4. Atmospheric deposition of heavy metals in Wuxi, China: estimation based on native moss analysis.

    Science.gov (United States)

    Yan, Yun; Zhang, Qiang; Wang, G Geoff; Fang, Yan-Ming

    2016-06-01

    We studied atmospheric deposition of heavy metals in Wuxi, China, using moss (Haplocladium microphyllum and H. angustifolium) as a biomonitoring agent. Moss samples were collected from 49 sites determined by a systematic sampling method. The top layer of soil on each site was also sampled. No significant correlation (P ArcGIS 9.0. A total pollution coefficient was calculated for each sampling site to identify the seriously polluted areas in the region.

  5. Persistent organic pollutants in the atmosphere - spatial and temporal variations

    Energy Technology Data Exchange (ETDEWEB)

    Backe, Cecilia

    2001-05-01

    In this thesis I have studied the spatial and temporal variations of PCBs in the atmosphere and in precipitation in southern Sweden. Further, soil-air exchange processes of PCBs were investigated. Finally, the long-range transport of PCBs and DDT was studied in the Baltic Sea region and in a tropical vs. a temporal region. On the regional scale there were significant differences in PCB concentration in the atmosphere, in precipitation and in soil between nearby sampling-areas. Differences in PCB concentrations between areas probably originated from varying geographical and meteorological conditions that affected exchange processes between air and soil/vegetation surfaces. Temporal variations in PCB concentration in atmosphere and precipitation were also found. For PCBs in the air, a systematic pattern in the deviation from the yearly median value for the region was observed. Wind direction played an important role for PCB concentration in precipitation in coastal areas, while at the inland sites this variable seemed to have a minor influence. To examine the intensity of precipitation scavenging, the total washout ratios were calculated and the highest ratios were observed at the two sites where PCB concentration in the air was high. Further, high concentrations of PCB in precipitation correlated with a composition of highly chlorinated PCB congeners, as shown by principal component analysis. For most of the sites there was a significant negative relationship between PCB concentration and rain volume. Soil type and soil organic matter content was found to be important for the variations in PCB concentration between nearby areas. Highest concentrations were found at two sites with sandy soils, one with an extremely high organic carbon content. Soils with similar soil textures (i.e. sandy silt moraine) did not show any significant differences in PCB concentrations. PCB congener composition was shown to differ between sites, with site-specific congener patterns. No

  6. A reassessment of the use of Posidonia oceanica and Mytilus galloprovincialis to biomonitor the coastal pollution of trace elements: New tools and tips.

    Science.gov (United States)

    Richir, J; Gobert, S

    2014-12-15

    The present study gives a summary using state-of-the-art technology to monitor Posidonia oceanica and Mytilus galloprovincialis as bioindicators of the pollution of the Mediterranean littoral with trace elements (TEs), and discusses their complementarity and specificities in terms of TE bioaccumulation. Furthermore, this study presents two complementary indices, the Trace Element Spatial Variation Index (TESVI) and the Trace Element Pollution Index (TEPI): these indices were shown to be relevant monitoring tools since they led to the ordering of TEs according to the overall spatial variability of their environmental levels (TESVI) and to the relevant comparison of the global TE pollution between monitored sites (TEPI). In addition, this study also discusses some underestimated aspects of P. oceanica and M. galloprovincialis bioaccumulation behaviour, with regard to their life style and ecophysiology. It finally points out the necessity of developing consensual protocols between monitoring surveys in order to publish reliable and comparable results.

  7. Effect of Atmospheric Pollutants on the Air Quality in Tunisia

    Directory of Open Access Journals (Sweden)

    Karim Bouchlaghem

    2012-01-01

    Full Text Available This paper presents the evolution of Saharan dust advection when the PM10 (particles with an aerodynamic diameter below 10 μm concentration exceeds standard limits in different Tunisian sites. Meteorological and concentration data (from 2004 to 2010 obtained from several monitoring stations and in situ measurements were used to identify African dust change in seasonal occurrence, their source origin, and their impact on surface PM10 concentrations. We pointed out that the Saharan dust contribution caused frequently the surpassing of the maximum number of days in excess of EU standard limits as well as of the maximum yearly average in the Mediterranean Tunisian coasts. The maximum daily concentration reaches 439 μg/m3 during the Saharan events. The decrease in particulate levels recorded at the end of each event is due to the injection of European air masses and rainfalls. Primary pollutants peaks were much higher in winter than in summer which can be explained on the basis of the lower ventilation and mixing.

  8. Atmospheric mercury emissions from polluted gold mining areas (Venezuela).

    Science.gov (United States)

    García-Sánchez, A; Contreras, F; Adams, M; Santos, F

    2006-12-01

    Soil, waste rock and mud from mercury-gold amalgamation mining areas of El Callao (Venezuela) are highly enriched in Hg (0.5-500 microg g(-1)) relative to natural background concentrations (mining districts (>100,000 ng m(-2) h(-1)). The results from this study also show that Hg emissions from the soil are influenced by solar radiation, soil temperature and soil Hg concentration. Our data suggest that solar radiation may be the dominant factor affecting Hg degrees emission since the major species of mercury in polluted soil is Hg degrees (85-97% of total Hg). The simple release of Hg degrees vapor is probably the dominant process occurring with incident light in the field. The apparent activation energy for mercury emission indicates that the volatilization of mercury mainly occurred as a result of the vaporization of elemental mercury in soil. The degree of Hg emission differed significantly among the soil sites studied, which may be due to variations in soil texture, organic matter content and soil compaction.

  9. Atmospheric pollution in thermal power plants; Contaminacion atmosferica en centrales termicas convencionales

    Energy Technology Data Exchange (ETDEWEB)

    Aguirre Diaz, A.

    1997-04-01

    The author presents the atmospheric pollution by fossil-fuel power plants. The state of the art is developed in 4 chapters: Legislation, Sulfur dioxide: reduction of SO{sub 2}, nitrogen oxides: reduction of emissions, particulates: reduction of particulates and new technologies. (Author)

  10. Critical Evaluation of Air-Liquid Interface Exposure Devices for In Vitro Assessment of Atmospheric Pollutants

    Science.gov (United States)

    Exposure of cells to atmospheric pollutants at the air-liquid interface (ALI) is a more realistic approach than exposures of attached cells submerged in liquid medium. However, there is still limited understanding of the ideal ALI device design features that permit reproducible a...

  11. Structuro-functional changes in the placenta as a result of exposure to atmospheric pollutants

    Energy Technology Data Exchange (ETDEWEB)

    Bonashevskaia, T.I.; Lamentova, T.G.; Shmakov, G.S.; Nikolaeva, E.G.; Suslova, V.M.

    1985-02-01

    Under the influence of atmospheric pollutions certain structural-functional changes take place in placenta: terminal villi per stipulated square unite, villi with desquamated epithelium, with dilated vessels, with deposition of fibrinoid masses, with plasmodial buds increase in number; section area occupied by epithelial layer decreases; RNA concentration and histoenzymatic activity change in the latter.

  12. Spatial structure and scale feature of the atmospheric pollution source impact of city agglomeration

    Institute of Scientific and Technical Information of China (English)

    XU Xiangde; ZHOU Xiuji; SHI Xiaohui

    2005-01-01

    The spatial structure and multi-scale feature of the atmospheric pollution influence domain of Beijing and its peripheral areas (a rapidly developed city agglomeration) is dissected and analyzed in this paper on the basis of the atmospheric pollution dynamic-chemical process observation data of the urban building ensemble boundary layer of the Beijing City Air Pollution Observation Experiment (BECAPEX) in winter (February) and summer (August) 2003, and relevant meteorological elements and satellite retrieval aerosol optical depth (AOD), etc. comprehensive data with the dynamic-statistical integrated analysis of "point-surface" spatial structure. Results show that there existed significant difference in the contribution of winter/summer different pollution emission sources to the component character of atmospheric pollution, and the principal component analysis (PCA) results of statistical model also indicate that SO2 and NOX dominated in the component structure of winter aerosol particle; instead, CO and NOX dominated in summer. Surface layer atmospheric dynamic and thermal structures and various pollutant species at the upper boundary of building ensembles at urban different observational sites of Beijing in winter and summer showed an "in-phase" variation and its spatial scale feature of "influence domain". The power spectrum analysis (PSA) shows that the period spectrum of winter/summer particle concentration accorded with those of atmospheric wind field: the longer period was dominative in winter, but the shorter period in summer, revealing the impact of the seasonal scale feature of winter/summer atmospheric general circulation on the period of atmospheric pollution variations. It is found that from analyzing urban area thermal heterogeneity that the multiscale effect of Beijing region urban heat island (UHI) was associated with the heterogeneous expansion of tall buildings area. In urban atmospheric dynamical and thermal characteristic spatial structures, the

  13. NATO Advanced Study Institute on Pollutants from Combustion Formation and Impact on Atmospheric Chemistry

    CERN Document Server

    2000-01-01

    This volume is based on the lectures presented at the NATO Advanced Study Institute: (ASI) «Pollutants Formation from Combustion. Formation Mechanisms and Impact on th th Atmospheric Chemistry» held in Maratea, Italy, from 13 to 26 september 1998. Preservation of the environment is of increasing concern in individual countries but also at continental or world scales. The structure of a NATO ASI which involve lecturers and participants of different nationalities was thought as especially well suited to address environmental issues. As combustion is known to substantially contribute to the damaging of the atmosphere, it was natural to concentrate the ASI program on reviewing the currently available knowledge of the formation mechanisms of the main pollutants liberated by combustion systems. In most situations, pollutants are present as trace components and their formation and removal is strongly conditioned by the chemical reactions initiated by fuel consumption. Therefore specific lectures were aimed at defi...

  14. Atmospheric transport of pollutants from North America to the North Atlantic Ocean

    Science.gov (United States)

    Harriss, R. C.; Browell, E. V.; Sebacher, D. I.; Gregory, G. L.; Hinton, R. R.; Beck, S. M.; Mcdougal, D. S.; Shipley, S. T.

    1984-01-01

    Ground-based measurements strongly support the hypothesis that pollutant materials of anthropogenic origin are being transported over long distances in the midtroposphere and are a significant source of acid rain, acid snow, trace metal deposition, ozone and visibility-reducing aerosols in remote oceanic and polar regions of the Norhern Hemisphere. Atmospheric sulphur budget calculations and studies of acid rain on Bermuda indicate that a large fraction of pollutant materials emitted into the atmosphere in eastern North America are advected eastwards over the North Atlantic Ocean. The first direct airborne measurements of the vertical distribution of tropospheric aerosols over the western North Atlantic is reported here. A newly developed airborne differential adsorption lidar system was used to obtain continuous, remotely sensed aerosol distributions along its flight path. The data document two episodes of long-distance transport of pollutant materials from North America over the North Atlantic Ocean.

  15. Observable Effects of Atmospheric Pollution on Outpatient and Inpatient Morbidity in Bulgaria

    Directory of Open Access Journals (Sweden)

    Мagdalena PLATIKANOVA

    2016-04-01

    Full Text Available Background: One of Europe’s most well-developed industrial regions is found in the Republic of Bulgaria. The industrialization of the region has a big impact on air pollution. Thermal power plant “Maritza East” (the largest of its kind in southeastern Europe, the army training range, machine manufacturers, household heating and high volume of automobile traffic are all major sources of pollution in the region.Methods: A five year study (2009-2013 followed yearly concentrations of principal atmospheric pollutants such as sulfur dioxide, dust, nitrogen dioxide, lead aerosols and hydrogen sulfide, and the way in which those levels had an effect on morbidity (outpatient and inpatient medical care in the area. Statistical processing of data has been completed to represent and analyze the collected data in nonparametric and alternative format.Results: Atmospheric pollution affects human health directly through pathological changes in the human organism. The registered outpatient care provided for the period 2009-2013 is highest for diseases of the cardiovascular system (11.85%, the respiratory system (17.34% and the genitourinary system (9.76%. The registered rate of hospitalization for the same period is for diseases of the digestive system (11.90%, the cardiovascular system (11.85%, respiratory system (10.86% and the genitourinary system (8.88%.Conclusion: The observed period shows a decrease in average yearly concentrations of the principal atmospheric pollutants in the industrial region (Bulgaria and reflects a decrease in morbidity based on outpatient care and an increase in morbidity by inpatient care (hospitalization. Our findings should be corroborated in future longitudinal studies. Keywords: Atmospheric pollution, Morbidity, Industrial region, Bulgaria

  16. South Fork Holston River basin 1988 biomonitoring

    Energy Technology Data Exchange (ETDEWEB)

    Saylor, C.F.; Ahlstedt, S.A.

    1990-06-01

    There is concern over the effects of shifts in land use use practices on the aquatic fauna of streams in the South Fork Holston River basin in northwestern North Carolina and southwestern Virginia. Trout reproduction has noticeably declined in the Watauga River subbasin. The Watauga River and Elk River subbasins have been subjected to commercial and resort development. The Middle fork Holston River and the upper South Fork Holston River subbasins have been affected by agricultural and mining activities, respectively (Cox, 1986). To aid reclamation and management of the South Fork Holston basin, Tennessee Valley Authority (TVA) biologists conducted biomonitoring--including index of biotic integrity and macroinvertebrate sampling--on the Middle Fork Holston, South Fork Holston, Watauga, and Elk Rivers to assess cumulative impairment related to changes in habitat and pollutant loading in these subbasins. Biomonitoring can detect environmental degradation, help document problem areas, and assist in development of strategies for managing water quality. This report discusses the methods and materials and results of the biomonitoring of South Fork Holston River Basin. 13 refs., 5 figs., 12 tabs.

  17. Urban Climate Effects on Air Pollution and Atmospheric Chemistry

    Science.gov (United States)

    Rasoul, Tara; Bloss, William; Pope, Francis

    2016-04-01

    Tropospheric ozone, adversely affects the environment and human health. The presence of chlorine nitrate (ClNO2) in the troposphere can enhance ozone (O3) formation as it undergoes photolysis, releasing chlorine reactive atoms (Cl) and nitrogen dioxide (NO2), both of which enhance tropospheric ozone formation. The importance of new sources of tropospheric ClNO2 via heterogeneous processes has recently been highlighted. This study employed a box model, using the Master Chemical Mechanism (MCM version 3.2) to assess the effect of ClNO2 on air quality in urban areas within the UK. The model updated to include ClNO2 production, photolysis, a comprehensive parameterisation of dinitrogen pentoxide (N2O5) uptake, and ClNO2 production calculated from bulk aerosol composition. The model simulation revealed the presence of ClNO2 enhances the formation of NO2, organic peroxy radical (CH3O2), O3, and hydroxyl radicals (OH) when compared with simulations excluding ClNO2. In addition, the study examined the effect of temperature variation upon ClNO2 formation. The response of ClNO2 to temperature was analysed to identify the underlying drivers, of particular importance when assessing the response of atmospheric chemistry processes under potential future climates.

  18. Modelling of anthropogenic pollutant diffusion in the atmosphere and applications to civil protection monitoring

    CERN Document Server

    Tessarotto, Marco

    2008-01-01

    A basic feature of fluid mechanics concerns the frictionless phase-space dynamics of particles in an incompressible fluid. The issue, besides its theoretical interest in turbulence theory, is important in many applications, such as the pollutant dynamics in the atmosphere, a problem relevant for civil protection monitoring of air quality. Actually, both the numerical simulation of the ABL (atmospheric boundary layer) portion of the atmosphere and that of pollutant dynamics may generally require the correct definition of the Lagrangian dynamics which characterizes arbitrary fluid elements of incompressible thermofluids. We claim that particularly important for applications would be to consider these trajectories as phase-space trajectories. This involves, however, the unfolding of a fundamental theoretical problem up to now substantially unsolved: {\\it namely the determination of the exact frictionless dynamics of tracer particles in an incompressible fluid, treated either as a deterministic or a turbulent (i....

  19. Sanitary impact of the particulate atmospheric urban pollution; Impact sanitaire de la pollution atmospherique urbaine particulaire

    Energy Technology Data Exchange (ETDEWEB)

    Sentissi, M.

    1999-03-22

    The pollution of particulates origin is one of the principle actual problem relative to air quality. In France, the fine particulates come from industry and automobile traffic, especially, the diesel vehicles. The most worrying characteristic is their fineness, that allow them to stay in suspension during a long time and penetrate into pulmonary alveoli, with toxic elements at their surface such metals, acids, polycyclic aromatic hydrocarbons. The objective of this work is to take stock of epidemiology and toxicology studies evaluating the sanitary impact of particulates in suspension. (N.C.)

  20. Biomonitoring the human population exposed to pollution from the oil fires in Kuwait: analysis of placental tissue using (32)P-postlabeling.

    Science.gov (United States)

    Marafie, E M; Marafie, I; Emery, S J; Waters, R; Jones, N J

    2000-01-01

    The placenta is a readily available source of material for molecular epidemiological investigations. As such, DNA damage in this tissue can be indicative of maternal exposure to environmental pollutants such as polycyclic aromatic hydrocarbons (PAHs). Previous reports have demonstrated that (32)P-postlabeling (PPL) is able to detect the presence of aromatic adducts in human placenta that are associated with maternal smoking during pregnancy. Using PPL we have assayed the DNA damage in placental samples from Kuwaiti mothers who were exposed to environmental pollution during pregnancy. This pollution arose in the aftermath of the Iraqi invasion of Kuwait, which left hundreds of oil wells burning. For comparison, further Kuwaiti samples were obtained approximately 1 year after the oil well fires and, as such, are from individuals unexposed to the airborne pollution from the oil well fires during pregnancy. In addition, placental samples were obtained from subjects in the United Kingdom. Adduct levels were measured in all samples using both the nuclease P1 and butanol extraction enhancement procedures. No elevation of adduct levels was observed in the placenta of mothers exposed to the oil well fires (n = 40) with either procedure (144 +/- 30 attomol/microg DNA for nuclease P1 enrichment, 245 +/- 50 attomol/microg DNA for butanol extraction), when compared with the nonexposed Kuwaiti mothers (180 +/- 32 and 281 +/- 39 attomol/microg DNA, respectively, n = 24). Similar adduct levels were observed in UK mothers who smoked cigarettes (178 +/- 30 and 284 +/- 52 attomol/microg DNA, n = 30), which in turn were approximately twice those observed in nonsmoking mothers (90 +/- 14 and 141 +/- 15 attomol/microg DNA, n = 12), although there is no significant difference in the distribution of adduct levels when statistical analysis is performed. Comprehensive interpretation of the Kuwaiti data is difficult as precise information on PAH levels is unavailable, although the data do

  1. Lichens biomonitoring as feasible methodology to assess air pollution in natural ecosystems: combined study of quantitative PAHs analyses and lichen biodiversity in the Pyrenees Mountains.

    Science.gov (United States)

    Blasco, María; Domeño, Celia; Nerín, Cristina

    2008-06-01

    The air quality in the Aragón valley, in the central Pyrenees, has been assessed by evaluation of lichen biodiversity and mapped by elaboration of the Index of Air Purity (IAP) based on observations of the presence and abundance of eight kinds of lichen with different sensitivity to air pollution. The IAP values obtained have been compared with quantitative analytical measures of 16 PAHs in the lichen Evernia prunastri, because this species was associated with a wide range of traffic exposure and levels of urbanization. Analyses of PAHs were carried out by the DSASE method followed by an SPE clean-up step and GC-MS analysis. The concentration of total PAHs found in lichen samples from the Aragón valley ranged from 692 to 6420 ng g(-1) and the PAHs profile showed predominance of compounds with three aromatic rings. The influence of the road traffic in the area has been shown because values over the median concentration of PAHs (>1092 ng g(-1)), percentage of combustion PAHs (>50%), and equivalent toxicity (>169) were found in lichens collected at places exposed to the influence of traffic. The combination of both methods suggests IAP as a general method for evaluating the air pollution referenced to PAHs because it can be correlated with the content of combustion PAHs and poor lichen biodiversity can be partly explained by the air pollution caused by specific PAHs.

  2. Gaseous atmospheric pollution. Gas measurement; Pollution atmospherique gazeuse. Mesure des gaz

    Energy Technology Data Exchange (ETDEWEB)

    Toupance, G. [Paris-12 Univ., 94 - Creteil (France); Person, A. [Laboratoire d' Hygiene de la Ville de Paris, 75 (France); Le Moullec, Y.; Masclet, P.; Perros, P.E.

    2004-09-01

    This article deals with the majority of pollutants which are present in gaseous phase in the low layer of the troposphere, of the proximity of sources to the distant areas where are in weak traces persisting substances or sub-products induced by photochemical reactions. The compounds described in this article are of interest for various reasons: either they are source tracers, or they draw attention for their impact on health or/and ecosystem. Their follow-up can also be in other approaches such as the understanding of reactional mechanisms and the support to modeling of the phenomena. Thereby, the range of the covered concentrations is very large: if the preoccupations are in most of the cases to answer to detection limits of about the ppb, for some substances, the requirements can be harder and we have then to orient oneself to techniques able to quantify at the level of ppt, sometimes less. Some pollutants are qualified of 'semi-volatile', that is to say they are the property to be present in gaseous phase and in particles in suspension in air. (O.M.)

  3. Cluster Analysis of Atmospheric Dynamics and Pollution Transport in a Coastal Area

    Science.gov (United States)

    Sokolov, Anton; Dmitriev, Egor; Maksimovich, Elena; Delbarre, Hervé; Augustin, Patrick; Gengembre, Cyril; Fourmentin, Marc; Locoge, Nadine

    2016-06-01

    Summertime atmospheric dynamics in the coastal zone of the industrialized Dunkerque agglomeration in northern France was characterized by a cluster analysis of back trajectories in the context of pollution transport. The MESO-NH atmospheric model was used to simulate the local dynamics at multiple scales with horizontal resolution down to 500 m, and for the online calculation of the Lagrangian backward trajectories with 30-min temporal resolution. Airmass transport was performed along six principal pathways obtained by the weighted k-means clustering technique. Four of these centroids corresponded to a range of wind speeds over the English Channel: two for wind directions from the north-east and two from the south-west. Another pathway corresponded to a south-westerly continental transport. The backward trajectories of the largest and most dispersed sixth cluster contained low wind speeds, including sea-breeze circulations. Based on analyses of meteorological data and pollution measurements, the principal atmospheric pathways were related to local air-contamination events. Continuous air quality and meteorological data were collected during the Benzene-Toluene-Ethylbenzene-Xylene 2006 campaign. The sites of the pollution measurements served as the endpoints for the backward trajectories. Pollutant transport pathways corresponding to the highest air contamination were defined.

  4. Cluster Analysis of Atmospheric Dynamics and Pollution Transport in a Coastal Area

    Science.gov (United States)

    Sokolov, Anton; Dmitriev, Egor; Maksimovich, Elena; Delbarre, Hervé; Augustin, Patrick; Gengembre, Cyril; Fourmentin, Marc; Locoge, Nadine

    2016-11-01

    Summertime atmospheric dynamics in the coastal zone of the industrialized Dunkerque agglomeration in northern France was characterized by a cluster analysis of back trajectories in the context of pollution transport. The MESO-NH atmospheric model was used to simulate the local dynamics at multiple scales with horizontal resolution down to 500 m, and for the online calculation of the Lagrangian backward trajectories with 30-min temporal resolution. Airmass transport was performed along six principal pathways obtained by the weighted k-means clustering technique. Four of these centroids corresponded to a range of wind speeds over the English Channel: two for wind directions from the north-east and two from the south-west. Another pathway corresponded to a south-westerly continental transport. The backward trajectories of the largest and most dispersed sixth cluster contained low wind speeds, including sea-breeze circulations. Based on analyses of meteorological data and pollution measurements, the principal atmospheric pathways were related to local air-contamination events. Continuous air quality and meteorological data were collected during the Benzene-Toluene-Ethylbenzene-Xylene 2006 campaign. The sites of the pollution measurements served as the endpoints for the backward trajectories. Pollutant transport pathways corresponding to the highest air contamination were defined.

  5. Understanding global cycling of atmosphere-surface exchangeable pollutants and its implications

    Science.gov (United States)

    Selin, N. E.; Giang, A.; Song, S.; Pike-thackray, C.; Friedman, C. L.

    2014-12-01

    We combine modeling approaches with data analysis to provide quantitative constraints on the global biogeochemical cycling of pollutants such as mercury (Hg) and persistent organic pollutants (POPs). These pollutants, released by human activities, continue to cycle between land, ocean, and atmosphere surfaces, extending their effective lifetimes in the environment. Measurement data are limited for all of these substances, providing few constraints on the magnitude of surface-atmosphere fluxes and thus the timescales of their cycling. This limits our ability to trace emissions to impacts for these substances, particularly in the context of both ongoing policies and climate change. We present a suite of modeling and analysis tools, including uncertainty analysis, that can provide quantitative constraints on cycling for these data-limited problems, and we illustrate their applicability through examples of Hg and selected POPs. Specifically, we summarize recent insights from inverse modeling of mercury, polynomial chaos-based methods for PAHs. Finally, we assess how uncertainty in timescales affects the entire emissions-to-impacts pathway for atmosphere-surface exchangeable pollutants. We discuss the implications of this analysis for policies under the Stockholm and Minamata Conventions.

  6. Assessment of the spatial and temporal distribution of persistent organic pollutants (POPs) in the Nordic atmosphere

    Science.gov (United States)

    Anttila, Pia; Brorström-Lundén, Eva; Hansson, Katarina; Hakola, Hannele; Vestenius, Mika

    2016-09-01

    Long-term atmospheric monitoring data (1994-2011) of persistent organic pollutants (POPs) were assembled from a rural site in southern Sweden, Råö, and a remote, sub-Arctic site in Finland, Pallas. The concentration levels, congener profiles, seasonal and temporal trends, and projections were evaluated in order to assess the status of POPs in the Scandinavian atmosphere. Our data include atmospheric concentrations of polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs), altogether comprising a selection of 27 different compounds. The atmospheric POP levels were generally higher in the south, closer to the sources (primary emissions) of the pollutants. The levels of low-chlorinated PCBs and chlordanes were equal at the two sites, and one of the studied POPs, α-HCH, showed higher levels in the north than in the south. Declining temporal trends in the atmospheric concentrations for the legacy POPs - PCBs (2-4% per year), HCHs (6-7% per year), chlordanes (3-4% per year) and DTTs (2-5% per year) - were identified both along Sweden's west coast and in the sub-Arctic area of northern Finland. Most of PAHs did not show any significant long-term trends. The future projections for POP concentrations suggest that in Scandinavia, low-chlorinated PCBs and p,p‧-DDE will remain in the atmospheric compartment the longest (beyond 2030). HCH's and PCB180 will be depleted from the Nordic atmosphere first, before 2020, whereas chlordanes and rest of the PCBs will be depleted between the years 2020 and 2025. PCBs tend to deplete sooner and chlordanes later from the sub-Arctic compared to the south of Sweden. This study demonstrates that the international bans on legacy POPs have successfully reduced the concentrations of these particular substances in the Nordic atmosphere. However, the most long-lived compounds may continue in the atmospheric cycle for another couple of decades.

  7. Pollution characteristics of atmospheric fine particles and their secondary components in the atmosphere of Shenzhen in summer and in winter

    Institute of Scientific and Technical Information of China (English)

    NIU; Yuwen; HE; Lingyan; HU; Min; ZHANG; Jing; ZHAO; Yunliang

    2006-01-01

    Two field measurements for atmospheric fine particles were conducted in Baoan district of Shenzhen during the summer and winter in 2004. Totally 30 sets of 24 h samples were collected, and then the mass concentrations and chemical compositions were determined. The seasonal variations and secondary pollution characteristics of fine particles during the sampling periods were discussed with meteorological factors. The results show that seasonal variations of atmospheric particles are significant in Shenzhen. The average mass concentrations of PM2.5 and PM10 in summer were 35 μg·m-3 and 57 μg·m-3, respectively, and those in winter were 99 μg·m-3 and 135 μg·m-3, respectively. The concentrations of both PM2.5 and PM10 in winter increased 184% and 137%, respectively, compared to those in summer. PM2.5 accounted for 61% and 75% of PM10 in summer and in winter, respectively, indicating severe fine particle pollution in Shenzhen. During the summer and winter sampling periods, the mean OC/EC ratios were 3.4 and 1.6, respectively. The estimated secondary organic carbon (SOC) averagely accounted for 56% and 6% of the total OC in summer and in winter, respectively, which implies a major contribution of SOC to OC in summer. During the continuous high temperature period in summer, both the concentrations and fractions of secondary aerosol components in PM2.5 were highly elevated, suggesting severe secondary pollution again. The prevailing wind was from South China Sea in summer, and the air quality was good. The prevailing wind in winter was from Mainland China to the north, and the polluted air mass led to poor air quality.

  8. Effect of atmospheric pollution on Vitis vinifera L. pollen ultrastructure under natural conditions

    Energy Technology Data Exchange (ETDEWEB)

    Stirban, M.; Craciun, C.; Bathory, D.; Cipleu, D.

    1984-06-01

    The ultrastructural modification of pollen grains in Vitis vinifera L. variety and hybrids in areas of SO atmospheric pollution (the main polluting SO2 usually reaches 2.72 mg/m3), nitrogen oxide, and other gases derived from noniron metal processing factories have been studied. Strains 1001 and 1002, resistant varieties, do not undergo ultrastructural modifications. Neuburger and Issabelle, medium resistant ones, have a heterogeneity in ultrastructural organization from normal forms to forms having both wall covers as well as the main organelles changed.

  9. Contribution to the study of characteristics of Pelargonium resistance to an atmospheric pollutant, sulfur dioxide

    Energy Technology Data Exchange (ETDEWEB)

    Bonte, J.; Bonte, C.; de Cormis, L.; Louguet, P.

    1977-01-01

    Eleven varieties of Pelargonium, subjected simultaneously to similar conditions of sulfur dioxide pollution, are arranged in ascending order of sensitivity. There is no relation between the relative susceptibility of the varieties to SO/sub 2/, the stomatal frequency and the dimensions of the stomatal apparatus. Nevertheless, a statistical comparative study of the stomatal movements of 2 Pelargonium, one resistant, the other sensitive, has shown that the closing rate of stomata and the reduction percentage of stomatal diffusive capacity are significantly different. These characteristics might be taken into consideration in the selection of varieties resistant to atmospheric pollution.

  10. Historical biomonitoring of fluoride pollution by determining fluoride contents in roe deer (Capreolus capreolus L.) antlers and mandibles in the vicinity of the largest Slovene thermal power plant.

    Science.gov (United States)

    Jelenko, Ida; Pokorny, Boštjan

    2010-12-15

    Roe deer antlers/mandibles are a useful tool for determination of ambient fluoride pollution. Antlers have a well-defined annual cycle of growth, therefore they represent a natural standardisation of samples during winter months. On the contrary, mandibles accumulate fluorides during the whole life of an organism, thus they reflect aggregated effect of fluoride pollution trough the life-span of an organism. Both tissues are easily available; mandibles are often systematically collected with the purpose of cognitive management and control, and antlers could be gathered from private well-dated hunters' collections. Considering these benefits, fluoride contents were measured in 141 antlers (period 1960-2007) and 220 mandibles (period 1997-2009) of roe deer, shot in the vicinity of the largest Slovene Thermal Power Plant of Šoštanj (ŠTPP) as one of the major sources of fluorides in Slovenia. Fluoride contents in antlers significantly differed among age categories, and ranged from 110 to 1210 mg/kg in yearlings, 130 to 2340 mg/kg in young adults, and 250 to 2590 mg/kg in older adults, respectively. Fluoride levels in mandibles were also significantly different among age categories, and ranged from 30.0 to 227 mg/kg in fawns, 33.8 to 383 mg/kg in yearlings, and 61.5 to 1020 mg/kg in adults, respectively. Comparison of these results with previously reported fluoride contents in antlers and mandibles of roe deer from different areas of Europe revealed that the study area has never been extensively contaminated with fluorides. Moreover, trends of fluoride contents in both tissues confirmed a significant decrease of fluoride pollution in the area after the years 1995 and 2000, when flue-gas cleaning devices were constructed on the ŠTPP. Indeed, highly positive correlations between annual emissions from the ŠTPP and mean annual fluoride contents in antlers/mandibles confirmed that both tissues may be a useful tool for assessing temporal trends in ambient fluoride

  11. Atmospheric Deposition of Heavy Metals around the Lead and Copper-Zinc Smelters in Baia Mare, Romania, Studied by the Moss Biomonitoring Technique, Neutron Activation Analysis and Flame Atomic Absorption Spectrometry

    CERN Document Server

    Culicov, O A; Steinnes, E; Okina, O S; Santa, Z; Todoran, R

    2002-01-01

    The mosses Pleurozium schreberi, Pseudoscleropodium purum and Rhytidiadelphus squarrosus were used as biomonitors to study the atmospheric deposition of heavy metals around the lead and copper-zinc smelters in Baia Mare. Samples representing the last three years' growth of moss or its green part, collected on the ground at 28 sites located 2-17 km from the source area, were analyzed by instrumental neutron activation analysis using epithermal neutrons and by flame atomic absorption spectrometry. A total of 31 elements were determined, including most of the heavy metals characteristic of emissions from this kind industry. The observed data for Pb, As, Cu, and Cd are all high compared with those observed in other regions of Europe with similar industries, but the concentrations in moss approach regional background levels at a distance of about 8 km from the main source area. Factor analysis of the data distinguishes two industrial components, one characterized by Pb, Cu, As, and Sb, and another one by Zn and Cd...

  12. Towards multi-level biomonitoring of nematodes to assess risk of nitrogen and phosphorus pollution in Jinchuan Wetland of Northeast China.

    Science.gov (United States)

    Wang, Yunbiao; Qiao, Jie; He, Chunguang; Wang, Zhongqiang; Luo, Wenbo; Sheng, Lianxi

    2015-12-01

    Cultivation for agricultural production often poses threats to nearby wetlands ecosystems in fertile landscapes. In this study, nematode ecological indexes were assessed through the main soil properties of the wetlands, farmlands, and edges of wetlands and farmlands in Jinchuan Wetland by the random sampling. Behavior and reproduction in Caenorhabditis elegans (C. elegans) exposed to the sampled waters were also examined. Stress proteins Hsp70 and Hsp90 were measured both in the living field samples of C. elegans and the lab-tested C. elegans. Our results suggested that disturbance to wetland ecosystems by nitrogen and phosphorus reduced nematode richness and proportions of bacterivore nematodes. Bacterivore nematode diversity and plant-parasitic ecological index were proven to be sensitive indicators of the ecological health of wetlands. Nematode Hsp70 were useful biosensors to monitor and assess the levels of nitrogen and phosphorus pollutions in wetlands. Furthermore, multi-level soil faunal assessments by canonical correspondence analysis showed that Jinchuan Wetland is threatened with non-point source pollution from nearby farmlands.

  13. Concentrations and {delta}{sup 13}C values of atmospheric CO{sub 2} from oceanic atmosphere through time: polluted and non-polluted areas

    Energy Technology Data Exchange (ETDEWEB)

    Longinelli, Antonio; Selmo, Enrico [Univ. of Parma (Italy). Dept. of Earth Sciences; Lenaz, Renzo; Ori, Carlo [C.N.R., ISMAR, Bologna (Italy). Dept. of Marine Geology

    2005-11-01

    CO{sub 2} is one of the primary agents of global climate changes. The increase of atmospheric CO{sub 2} concentration is essentially related to human-induced emissions and, particularly, to the burning of fossil fuel whose {delta}{sup 13}C values are quite negative. Consequently, an increase of the CO{sub 2} concentration in the atmosphere should be paralleled by a decrease of its {delta}{sup 13}C. Continuous and/or spot measurements of CO{sub 2} concentrations were repeatedly carried out during the last decade and in the same period of the year along hemispheric courses from Italy to Antarctica on a vessel of the Italian National Research Program in Antarctica. During these expeditions, discrete air samples were also collected in 4-l Pyrex flasks in order to carry out precise carbon isotope analyses on atmospheric CO{sub 2} from different areas, including theoretically 'clean' open ocean areas, with the main purpose of comparing these open ocean results with the results obtained by the National Oceanic and Atmospheric Administration/World Meteorological Organization (NOAA/WMO) at land-based stations. According to the data obtained for these two variables, a relatively large atmospheric pollution is apparent in the Mediterranean area where the CO{sub 2} concentration has reached the value of 384 ppmv while quite negative {delta}{sup 13}C values have been measured only occasionally. In this area, southerly winds probably help to reduce the effect of atmospheric pollution even though, despite a large variability of CO{sub 2} concentrations, these values are consistently higher than those measured in open ocean areas by a few ppmv to about 10 ppmv. A marked, though non-continuous, pollution is apparent in the area of the Bab-el-Mandeb strait where {delta}{sup 13}C values considerably more negative than in the Central and Southern Red Sea were measured. The concentration of atmospheric CO{sub 2} over the Central Indian Ocean increased from about 361 ppmv at

  14. Concentrations and (delta){sup 13}C values of atmospheric CO{sub 2} from oceanic atmosphere through time: polluted and non-polluted areas

    Energy Technology Data Exchange (ETDEWEB)

    Longinelli, Antonio; Selmo, Enrico [Univ. of Parma (Italy). Dept. of Earth Sciences; Lenaz, Renzo; Ori, Carlo [C.N.R., ISMAR, Bologna (Italy). Dept. of Marine Geology

    2005-11-15

    CO{sub 2} is one of the primary agents of global climate changes. The increase of atmospheric CO{sub 2} concentration is essentially related to human-induced emissions and, particularly, to the burning of fossil fuel whose (delta){sup 13}C values are quite negative. Consequently, an increase of the CO{sub 2} concentration in the atmosphere should be paralleled by a decrease of its (delta){sup 13}C. Continuous and/or spot measurements of CO{sub 2} concentrations were repeatedly carried out during the last decade and in the same period of the year along hemispheric courses from Italy to Antarctica on a vessel of the Italian National Research Program in Antarctica. During these expeditions, discrete air samples were also collected in 4-l Pyrex flasks in order to carry out precise carbon isotope analyses on atmospheric CO{sub 2} from different areas, including theoretically 'clean' open ocean areas, with the main purpose of comparing these open ocean results with the results obtained by the National Oceanic and Atmospheric Administration/World Meteorological Organization (NOAA/WMO) at land-based stations. According to the data obtained for these two variables, a relatively large atmospheric pollution is apparent in the Mediterranean area where the CO{sub 2} concentration has reached the value of 384 ppmv while quite negative (delta){sup 13}C values have been measured only occasionally. In this area, southerly winds probably help to reduce the effect of atmospheric pollution even though, despite a large variability of CO{sub 2} concentrations, these values are consistently higher than those measured in open ocean areas by a few ppmv to about 10 ppmv. A marked, though non-continuous, pollution is apparent in the area of the Bab-el-Mandeb strait where (delta){sup 13}C values considerably more negative than in the Central and Southern Red Sea were measured. The concentration of atmospheric CO{sub 2} over the Central Indian Ocean increased from about 361 ppmv at

  15. Oro taršos sunkiaisiais metalais tyrimai naudojant samanas kaip bioindikatorių Research into Heavy Metals Pollution of Atmosphere Applying Moss as Bioindicator: a Literature Review

    Directory of Open Access Journals (Sweden)

    Dainius PALIULIS

    2011-01-01

    -tstyle-colband-size:0; mso-style-noshow:yes; mso-style-priority:99; mso-style-qformat:yes; mso-style-parent:""; mso-padding-alt:0cm 5.4pt 0cm 5.4pt; mso-para-margin:0cm; mso-para-margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:11.0pt; font-family:"Calibri","sans-serif"; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:"Times New Roman"; mso-fareast-theme-font:minor-fareast; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-bidi-font-family:"Times New Roman"; mso-bidi-theme-font:minor-bidi;} Atmospheric pollution causes serious damage for human health and to all natural ecosystems. Nowadays, the biggest provocative of atmospheric pollution is anthropogenic human activities and transport sector, main pollutants being heavy metals (HM. Biomonitoring of HM pollution of atmosphere by mosses is one of the most popular, perspective and cost - effective method to control, detect and evaluate changes in the air quality. The most important environmental features of mosses as a suitable tool of biomonitoring are: rootless, large surface, wide - spread population, a habit to grow in groups, long life - cycle, survival in a high - polluted environment, an ability to obtain nutrients from wet and dry deposition. This literature review presents environmental properties of mosses, what makes them to be suitable for biomonitoring, HM deposition trends in some European countries during 1990-2005/6, methodology of sampling and chemical analysis, a summary of strengths and weaknesses of the most popular HM analysis techniques in Europe.

  16. DETECTING INDUSTRIAL POLLUTION IN THE ATMOSPHERES OF EARTH-LIKE EXOPLANETS

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Henry W. [Harvard College, Cambridge, MA 02138 (United States); Abad, Gonzalo Gonzalez; Loeb, Abraham, E-mail: henrylin@college.harvard.edu, E-mail: ggonzalezabad@cfa.harvard.edu, E-mail: aloeb@cfa.harvard.edu [Harvard-Smithsonian Center for Astrophysics, 60 Garden St., Cambridge, MA 02138 (United States)

    2014-09-01

    Detecting biosignatures, such as molecular oxygen in combination with a reducing gas, in the atmospheres of transiting exoplanets has been a major focus in the search for alien life. We point out that in addition to these generic indicators, anthropogenic pollution could be used as a novel biosignature for intelligent life. To this end, we identify pollutants in the Earth's atmosphere that have significant absorption features in the spectral range covered by the James Webb Space Telescope. We focus on tetrafluoromethane (CF{sub 4}) and trichlorofluoromethane (CCl{sub 3}F), which are the easiest to detect chlorofluorocarbons (CFCs) produced by anthropogenic activity. We estimate that ∼1.2 days (∼1.7 days) of total integration time will be sufficient to detect or constrain the concentration of CCl{sub 3}F (CF{sub 4}) to ∼10 times the current terrestrial level.

  17. Ozone pollution and ozone biomonitoring in European cities. Part I: Ozone concentrations and cumulative exposure indices at urban and suburban sites

    DEFF Research Database (Denmark)

    Klumpp, A.; Ansel, W.; Klumpp, G.

    2006-01-01

    In the frame of a European research project on air quality in urban agglomerations, data on ozone concentrations from 23 automated urban and suburban monitoring stations in 11 cities from seven countries were analysed and evaluated. Daily and summer mean and maximum concentrations were computed...... based on hourly mean values, and cumulative ozone exposure indices (Accumulated exposure Over a Threshold of 40 ppb (AOT40), AOT20) were calculated. The diurnal profiles showed a characteristic pattern in most city centres, with minimum values in the early morning hours, a strong rise during the morning......, by contrast, maximum values were lower and diurnal variation was much smaller. Based on ozone concentrations as well as on cumulative exposure indices, a clear north-south gradient in ozone pollution, with increasing levels from northern and northwestern sites to central and southern European sites...

  18. Atmospheric pollution: a case study of degrading urban air quality over Punjab, India.

    Science.gov (United States)

    Sehra, Parmjit Singh

    2007-01-01

    This paper presents the results of a case study of urban air quality over a densely populated city Ludhiana situated in Punjab, India, in the form of monthly and annual average concentrations of Suspended Particulate Matter (SPM), NO2 and SO2 for the periods 1988-1989, 1994-1999 and 2001-2005 which is generally found to be increasing with time and thus requires immediate corrective measures lest the situation becomes totally uncontrollable. The present situation is as bad as in other metropolitan Indian cities, although it seems to have somewhat improved as indicated by the latest 2001-2005 data in comparison with the past 1988-1989 and 1994-1999 data, but much more still needs to be done. In addition to the industrial and vehicular pollution, the agricultural pollution due to the burning of wheat and rice straws by the farmers should also be checked because it also creates tremendous pollution in the atmosphere.

  19. Simplified Atmospheric Dispersion Model andModel Based Real Field Estimation System ofAir Pollution

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    The atmospheric dispersion model has been well developed and applied in pollution emergency and prediction. Based on thesophisticated air diffusion model, this paper proposes a simplified model and some optimization about meteorological andgeological conditions. The model is suitable for what is proposed as Real Field Monitor and Estimation system. The principle ofsimplified diffusion model and its optimization is studied. The design of Real Field Monitor system based on this model and itsfundamental implementations are introduced.

  20. Detecting industrial pollution in the atmospheres of earth-like exoplanets

    CERN Document Server

    Lin, Henry W; Loeb, Abraham

    2014-01-01

    Detecting biomarkers, such as molecular oxygen, in the atmospheres of transiting exoplanets has been a major focus in the search for alien life. We point out that in addition to these generic indicators, anthropogenic pollution could be used as a novel biomarker for intelligent life. To this end, we identify pollutants in the Earth's atmosphere that have significant absorption features in the spectral range covered by the James Webb Space Telescope (JWST). We estimate that for an Earth-mass planet in the habitable zone of a white dwarf, methane (CH4) and nitrous oxide (N2O) can be detected at earth-like concentrations with an integration time of ~1.5 hrs and 12 hrs respectively. Detecting pollutants that are produced nearly exclusively by anthropogenic activities will be significantly more challenging. Of these pollutants, we focus on tetrafluoromethane (CF4) and trichlorofluoromethane (CCl3F), which will be the easiest to detect. We estimate that ~1.5 days (~3 days) of total integration time will be sufficie...

  1. Laser system for remote sensing monitoring of air pollution and quality control of the atmosphere

    Directory of Open Access Journals (Sweden)

    Belić Ilija

    2012-01-01

    Full Text Available Monitoring of the atmosphere and determination of the types and amounts of pollutants is becoming more important issue in complex and global monitoring of the environment. On the geocomponent and geocomplex level problem of monitoring the environment is attracting the attention of the scientific experts of different profiles (chemists, physicists, geographers, biologists, meteorologists, both in the national and international projects. Because of the general characteristics of the Earth's atmosphere (Dynamically Ballanced Instability DBI and the potential contribution to climate change solutions air-pollution monitoring has become particularly important field of environmental research. Control of aerosol distribution over Europe is enabled by EARLINET systems (European Aerosol Lidar NETwork. Serbia’s inclusion into these European courses needs development of the device, the standardization of methods and direct activity in determining the type, quantity and location of aerosol. This paper is analyzing the first step in the study of air-pollution, which is consisted of the realization of a functional model of LIDAR remote sensing devices for the large particle pollutants.

  2. Atmospheric pollution in the area of Vitry-sur-Seine and Alfortville; Pollution atmospherique dans la zone de Vitry-sur-Seine et d'Alfortville

    Energy Technology Data Exchange (ETDEWEB)

    Mayet, P.

    1997-07-01

    The aim of this report, demanded by the environmental minister, is the present state and the evolution of the atmospheric pollution in the area of Vitry-sur-seine and Alfortville, near Paris. In the first part the report takes stock of the air quality to show a decrease in the pollution due to fixed sources. A special interest is given in a second part to exhaust gases from the main factory of the area: the EDF power plant. The report concludes on the decrease of the industrial air pollution, the increase of the traffic air pollution and asks for the public information. (A.L.B.)

  3. Biomonitoring of environmental pollution using growth tree rings of Tipuana tipu: Quantification by synchrotron radiation total reflection X-ray fluorescence

    Science.gov (United States)

    Geraldo, S. M.; Canteras, F. B.; Moreira, S.

    2014-02-01

    Currently, many studies use the bioindicators to qualitatively and/or quantitatively measure pollution. The analyses of tree growth rings represent one such bioindicator as changes in the environment are often recorded as impressions in the wood. The main objective of the present study is to examine the growth rings of Tipuana tipu - a member of the Leguminosae family that is native to Argentina and Bolivia and was introduced in Brazil as an ornamental plant - for potentially toxic elements. T. tipu is one of the most common trees in the urban landscape of Sao Paulo city and would provide an accurate reflection of environment changes. Tree ring samples previously dated using Synchrotron Radiation Total Reflection X-ray Fluorescence were collected from strategic locations in Sao Paulo. These locations include Piracicaba (SP) that has little access and small flow traffic and the campus of the University of São Paulo. Some trace elements present concentrations higher than considered as normal in some periods. In São Paulo city, samples collected from the campus of University of São Paulo (Butantã), showed the highest toxicity, with concentrations above the tolerable limit for the elements: Cr, Cu, and Pb. For the samples collected in Piracicaba city, one sample presented highest concentrations for the majority of the elements when compared to the other four samples collected at the same place, exceeding the toxicity limits for: Cr, Ni, Cu, and Pb.

  4. Tributyltin biomonitoring using prosobranchs as sentinel organisms

    Energy Technology Data Exchange (ETDEWEB)

    Oehlmann, J. [International Graduate School Zittau, Chair of Environmental High Technology, Markt 23, D-02763 Zittau (Germany); Stroben, E. [Institute for Special Zoology and Comparative Embryology, University of Muenster, Huefferstrasse 1, D-48149 Muenster (Germany); Schulte-Oehlmann, U. [Institute for Special Zoology and Comparative Embryology, University of Muenster, Huefferstrasse 1, D-48149 Muenster (Germany); Bauer, B. [Institute for Special Zoology and Comparative Embryology, University of Muenster, Huefferstrasse 1, D-48149 Muenster (Germany); Fioroni, P. [Institute for Special Zoology and Comparative Embryology, University of Muenster, Huefferstrasse 1, D-48149 Muenster (Germany); Markert, B. [International Graduate School Zittau, Chair of Environmental High Technology, Markt 23, D-02763 Zittau (Germany)

    1996-03-01

    Tributyltin (TBT) compounds, some of the most toxic xenobiotics, produce a variety of pathological reactions in animals. A reliable biomonitoring method to assess the degree of environmental TBT pollution has been described based on investigations of virilization phenomena in prosobranch snails (Mollusca: Gastropoda). Examples are the imposex phenomenon in marine and freshwater species, the intersex reaction in littorinids and the reduction of female sexual glands and offspring numbers in further species resulting mainly in a sterilization of females. The degree of imposex or intersex in populations is determined by different biomonitoring indices which allow to assess the TBT pollution of the environment at low costs with high precision. The effectiveness of TBT legislations is analysed by extensive surveys in France and Ireland indicating that there is still a continuing threat to sensitive marine organisms. TBT disturbs the biosynthesis of steroid hormones on the level of estrogen biosynthesis. The observed virilization phenomena seem due to an inhibition of the cytochrome P-450 dependent aromatase by this organotin compound. (orig.). With 4 figs.

  5. Evaluation of growth tree rings of Tipuana Tipu as biomonitoring of environmental pollution by synchrotron radiation total reflection X-ray fluorescence

    Energy Technology Data Exchange (ETDEWEB)

    Moreira, Silvana; Geraldo, Simoni Michetti; Canteras, Felippe Benavente, E-mail: silvana@fec.unicamp.br, E-mail: felippe.canteras@gmail.com [Universidade Estadual de Campinas (FEC/UNICAMP), Campinas, SP (Brazil). Dept. de Saneamento e Ambiente

    2013-07-01

    The bioindicators, plants or animals capable to present qualitative and/or quantitative answers, when exposed to pollutant substances. Trees record and incorporate in their log, developed year after year, the impressions of the environment, becoming possible the study of the different environmental changes, including contamination, that have occurred over the life of these trees. The selected species, Tipuana Tipu, of the Leguminosae family, is native of Argentina and Bolivia and was introduced in Brazil as an ornamental plant. It is one of the most common trees in the urban landscaping in Sao Paulo city. The present project has as main objective the determination of the content of potentially toxic elements in samples of growth the tree rings of Tipuana Tipu, previously dated, collected in strategically locations of Sao Paulo, using Synchrotron Radiation Total Reflection X-Ray Fluorescence. Samples were also collected in the Piracicaba (SP), local of little access and small flow traffic. The SR-TXRF analysis was carried out in the X-ray Fluorescence Beamline at the Brazilian Synchrotron Light Source Laboratory, located in Campinas city, Sao Paulo State, Brazil. Some trace elements present concentrations higher than considered as normal in some periods. In this paper the highest value for Pb was 123.54 μg.g{sup -1} considered as threshold value was observed for the period 1998 to 2000 for University of Sao Paulo, Butanta site. For the same period excessive level was also observed for samples collected in Piracicaba city. In Sao Paulo city, sample collected in the campus of University of Sao Paulo (Butanta), showed the highest toxicity, with concentration above the tolerable limit for Ti, Cr and Cu. For the samples collected in Piracicaba city the concentrations of Cr, Ni, Cu, and Pb exceeding the toxicity limits. (author)

  6. Atmospheric transport of persistent organic pollutants to the Arctic, today and in a future climate

    Science.gov (United States)

    Octaviani, Mega; Stemmler, Irene; Lammel, Gerhard

    2013-04-01

    Persistent organic pollutants are of great concern because of their long residence time and long-range transport potential in the environment and because they are readily bioaccumulated along food chains and toxic for wildlife and humans. A multicompartment model is used to study global-scale and long term chemodynamics of anthropogenic organic substances in the Earth system. Model components are the atmosphere (ECHAM5) and ocean general circulation models (MPIOM), which include dynamic sub-models for atmospheric aerosols and the marine biogeochemistry, two-dimensional surface compartments (topsoil, vegetation surfaces, ice, and temporal snow cover) and intercompartmental mass exchange process parameterisations [1-3]. The transports into and out of the Arctic (66° N) are characterized for 1950-2000 under one realisation of present-day climate [4-5] and for 2001-2100 under one realisation of future climate (greenhouse gas emission scenario A1B of IPCC-AR4). Despite decaying primary emissions (since decades) polychlorinated biphenyls (PCB) and dichlorodimephenyltrichloromethane (DDT) are continuing to accumulate in the Arctic, which is fed by atmospheric transports. The main regions of import (and export) are identified and the vertical distribution and seasonalities are characterized. Changes by the end of the 21st century are discussed in the context of a major teleconnection, i.e. the Arctic Oscillation. References [1] Guglielmo F, Lammel G, Maier-Reimer E: Global environmental cycling of DDT and ?-HCH in the 1980s - a study using a coupled atmosphere and ocean general circulation model. Chemosphere 76 (2009) 1509-1517 [2] Stemmler I, Lammel G: Cycling of DDT in the global oceans 1950-2002: World ocean returns the pollutant. Geophys. Res. Lett. 36 (2009) L24602 [3] Hofmann L, Stemmler I, Lammel G: The impact of organochlorines cycling in the cryosphere on their global distributions and fate - 2. Land ice and temporary snow cover. Environ. Pollut. 162 (2012) 482

  7. The influence of scales of atmospheric motion on air pollution over Portugal

    Science.gov (United States)

    Russo, Ana; Trigo, Ricardo; Mendes, Manuel; Jerez, Sonia; Gouveia, Célia Marina

    2014-05-01

    Air pollution is determined by the combination of different factors, namely, emissions, physical constrains, meteorology and chemical processes [1,2,3]. The relative importance of such factors is influenced by their interaction on diverse scales of atmospheric motion. Each scale depicts different meteorological conditions, which, when combined with the different air pollution sources and photochemistry, result in varying ambient concentrations [2]. Identifying the dominant scales of atmospheric motion over a given airshed can be of great importance for many applications such as air pollution and pollen dispersion or wind energy management [2]. Portugal has been affected by numerous air pollution episodes during the last decade. These episodes are often related to peak emissions from local industry or transport, but can also be associated to regional transport from other urban areas or to exceptional emission events, such as forest fires. This research aims to identify the scales of atmospheric motion which contribute to an increase of air pollution. A method is proposed for differentiating between the scales of atmospheric motion that can be applied on a daily basis from data collected at several wind-measuring sites in a given airshed and to reanalysis datasets. The method is based on the daily mean wind recirculation and the mean and standard deviation between sites. The determination of the thresholds between scales is performed empirically following the approach of Levy et al. [2] and also through a automatic statistical approach computed taking into account the tails of the distributions (e.g. 95% and 99% percentile) of the different wind samples. A comparison is made with two objective approaches: 1) daily synoptic classification for the same period over the region [4] and 2) a 3-D backward trajectory approach [5,6] for specific episodes. Furthermore, the outcomes are expected to support the Portuguese authorities on the implementation of strategies for a

  8. Diurnal Variations of Air Pollution and Atmospheric Boundary Layer Structure in Beijing During Winter 2000/2001

    Institute of Scientific and Technical Information of China (English)

    ZHOU Li; XU Xiangde; DING Guoan; ZHOU Mingyu; CHENG Xinghong

    2005-01-01

    The diurnal variations of gaseous pollutants and the dynamical and thermodynamic structures of the atmospheric boundary layer (ABL) in the Beijing area from January to March 2001 are analyzed in this study using data from the Beijing City Air Pollution Observation Field Experiment (BECAPEX). A heavy pollution day (22 February) and a good air quality day (24 February) are selected and individually analyzed and compared to reveal the relationships between gaseous pollutants and the diurnal variations of the ABL. The results show that gaseous pollutant concentrations exhibit a double-peak-double-valley-type diurnal variation and have similar trends but with different magnitudes at different sites in Beijing. The diurnal variation of the gaseous pollutant concentrations is closely related to (with a 1-2 hour delay of)changes in the atmospheric stability and the mean kinetic energy in the ABL.

  9. Interception of wet deposited atmospheric pollutants by herbaceous vegetation: Data review and modelling

    Energy Technology Data Exchange (ETDEWEB)

    Gonze, M.-A., E-mail: marc-andre.gonze@irsn.fr; Sy, M.M.

    2016-09-15

    Better understanding and predicting interception of wet deposited pollutants by vegetation remains a key issue in risk assessment studies of atmospheric pollution. We develop different alternative models, following either empirical or semi-mechanistic descriptions, on the basis of an exhaustive dataset consisting of 440 observations obtained in controlled experiments, from 1970 to 2014, for a wide variety of herbaceous plants, radioactive substances and rainfall conditions. The predictive performances of the models and the uncertainty/variability of the parameters are evaluated under Hierarchical Bayesian modelling framework. It is demonstrated that the variability of the interception fraction is satisfactorily explained and quite accurately modelled by a process-based alternative in which absorption of ionic substances onto the foliage surfaces is determined by their electrical valence. Under this assumption, the 95% credible interval of the predicted interception fraction encompasses 81% of the observations, including situations where either plant biomass or rainfall intensity are unknown. This novel approach is a serious candidate to challenge existing empirical relationships in radiological or chemical risk assessment tools. - Highlights: • Literature data on the interception of atmospheric pollutants by herbs were reviewed • Predictive models were developed and evaluated in the Bayesian modelling framework • Sensitivity of interception to environmental conditions was satisfactorily explained • 81% of the observations were satisfactorily predicted by a semi-mechanistic model • This model challenges empirical relationships currently used in risk assessment tools.

  10. Meteorologia e poluição atmosférica Meteorology and atmospheric pollution

    Directory of Open Access Journals (Sweden)

    Davidson Martins Moreira

    2008-06-01

    Full Text Available Neste trabalho apresentam-se os principais aspectos relacionados à meteorologia ligada ao processo de dispersão turbulenta de poluentes atmosféricos. Ressalta-se que a meteorologia desempenha um papel fundamental para o controle da qualidade do ar, pois os eventos meteorológicos guiam a dispersão de poluentes e sua deposição no solo. Discutem-se os recentes melhoramentos da descrição e previsão dos fenômenos que envolvem a poluição atmosférica considerando a melhoria da qualidade de vida da população.This work shows the main aspects related to the meteorology linked to the process of turbulent dispersion of atmospheric pollutants. It is pointed out that meteorology is fundamental to air quality control, and meteorological events guide the pollutant dispersion and its deposition on the soil. Recent improvements on the description and forecast of the phenomena that involve atmospheric pollution, considering the population quality of life, are discussed.

  11. [Magnetic Response of Dust-loaded Leaves in Parks of Shanghai to Atmospheric Heavy Metal Pollution].

    Science.gov (United States)

    Liu, Fei; Chu, Hui-min; Zheng, Xiang-min

    2015-12-01

    To reveal the magnetic response to the atmospheric heavy metal pollution in leaves along urban parks, Camphor leaf samples, widely distributed at urban parks, were collected along the year leading wind direction of Shanghai, by setting two vertical and horizontal sections, using rock magnetic properties and heavy metal contents analysis. The results showed that the magnetic minerals of samples were predominated by ferromagnetic minerals, and both the concentration and grain size of magnetite particles gradually decreased with the winter monsoon direction from the main industrial district. A rigorous cleaning of leaves using ultrasonic agitator washer could remove about 63%-90% of low-field susceptibility values of the leaves, and this strongly indicated that the intensity of magnetic signal was mainly controlled by the PMs accumulated on the leaves surfaces. Moreover, there was a significant linear relationship between heavy metals contents (Fe, Mn, Zn, Cu, Cr, V and Pb) and magnetic parameters (0.442 ≤ R ≤ 0.799, P magnetic parameters of urban park leaves could be used as a proxy for atmospheric heavy metal pollution. The results of multivariate statistical analysis showed that the content of magnetic minerals and heavy metal indust-loaded tree leaves was affected by associated pollution of industry and traffic.

  12. Comparison of PCBs and PAHs levels in European coastal waters using mussels from the Mytilus edulis complex as biomonitors

    Directory of Open Access Journals (Sweden)

    Michał Olenycz

    2015-04-01

    Full Text Available Mussels from the Mytilus edulis complex were used as biomonitors for two groups of organic pollutants: polychlorinated biphenyls (PCBs, congeners: 28, 52, 101, 118, 138, 153 and 180 and polycyclic aromatic hydrocarbons (PAHs, naphthalene, acenaphthylene, acenaphthene, fluorene, phenanthrene, anthracene, fluoranthene, pyrene, benz(aanthracene, chrysene, benzo(bfluoranthene, benzo(kfluoranthene, benzo(apyrene, indeno(1,2,3-cdpyrene, dibenz(a,hanthracene, benzo(g,h,iperylene at 17 sampling sites to assess their relative bioavailabilities in coastal waters around Europe. Because of the temporal differences in PCBs and PAHs concentrations, data were adjusted using Seasonal Variation Coefficients (SVC before making large-scale spatial comparisons. The highest concentrations of PCBs were found near estuaries of large rivers flowing through urban areas and industrial regions. Elevated bioavailabilities of PAHs occurred in the vicinity of large harbors, urban areas, and regions affected by petroleum pollution as well as in some remote locations, which indicated long-range atmospheric deposition.

  13. Impact of a future H2 transportation on atmospheric pollution in Europe

    Science.gov (United States)

    Popa, Maria Elena; Segers, Arjo; Denier van der Gon, Hugo; Schaap, Martijn; Krol, Maarten; Visschedijk, Antoon; Röckmann, Thomas

    2014-05-01

    Traditionally fuelled road traffic is a major source of greenhouse gases and pollutants. Greenhouse gases (e.g. CO2 and CH4) affect the global atmosphere and contribute to global warming. The pollutants emitted by vehicles (e.g. CO, NOx, SO2, particulate matter, volatile organic compounds) are toxic for man and environment and decrease air quality especially in highly populated areas. Burning H2 produces only water, thus H2-powered vehicles are seen as a possibility to reduce greenhouse gas emissions and improve air quality; because of this, H2 usage as a fuel is foreseen to significantly increase in the future. Large scale usage of H2 as a fuel has the potential to affect the atmospheric composition in different ways. On one hand, emissions associated to fossil fuel burning will decrease. On the other hand, large quantities of H2 used will likely lead to increased H2 emissions from leakages during production, transport and storage. Additional H2 in the atmosphere will affect the chemistry of many species, in principal by decreasing the availability of OH radicals, with the result of increasing the lifetime of greenhouse gases and pollutants. Thus the net effect of H2 vehicles on the atmospheric composition depends on the relative strength of these two contrary effects. In order to evaluate the potential influence of a future H2 road transportation on local and regional air quality, we implemented H2 in the atmospheric transport and chemistry model LOTOS-EUROS. We simulated the future (2020) using emission scenarios with different proportions of H2 vehicles and different H2 leakage rates. The reference future scenario does not include H2 vehicles, and assumes that all present and planned European regulations for emissions are fully implemented. We find that in general the air quality in 2020 will be significantly better than at present in all scenarios, with and without H2 cars. In the future scenario without H2 cars, the pollution is reduced due to the strict

  14. Investigation of chemical properties and transport phenomena associated with pollutants in the atmospheric boundary layer

    Science.gov (United States)

    Holmes, Heather A.

    Under the Clean Air Act, the U.S. Environmental Protection Agency is required to determine which air pollutants are harmful to human health, then regulate, monitor and establish criteria levels for these pollutants. To accomplish this and for scientific advancement, integration of knowledge from several disciplines is required including: engineering, atmospheric science, chemistry and public health. Recently, a shift has been made to establish interdisciplinary research groups to better understand the atmospheric processes that govern the transport of pollutants and chemical reactions of species in the atmospheric boundary layer (ABL). The primary reason for interdisciplinary collaboration is the need for atmospheric processes to be treated as a coupled system, and to design experiments that measure meteorological, chemical and physical variables simultaneously so forecasting models can be improved (i.e., meteorological and chemical process models). This dissertation focuses on integrating research disciplines to provide a more complete framework to study pollutants in the ABL. For example, chemical characterization of particulate matter (PM) and the physical processes governing PM distribution and mixing are combined to provide more comprehensive data for source apportionment. Data from three field experiments were utilized to study turbulence, meteorological and chemical parameters in the ABL. Two air quality field studies were conducted on the U.S./Mexico border. The first was located in Yuma, AZ to investigate the spatial and temporal variability of PM in an urban environment and relate chemical properties of ambient aerosols to physical findings. The second border air quality study was conducted in Nogales, Sonora, Mexico to investigate the relationship between indoor and outdoor air quality in order to better correlate cooking fuel types and home activities to elevated indoor PM concentrations. The final study was executed in southern Idaho and focused on

  15. The use of lichen (Canoparmelia texana) as biomonitor of atmospheric deposition of natural radionuclides from U-238 and Th-232 series

    Science.gov (United States)

    Leonardo, Lucio; Damatto, Sandra Regina; Mazzilli, Barbara Paci; Saiki, Mitiko

    2008-08-01

    Lichens have been used in studies of environmental pollution monitoring of various air pollutants, especially heavy metals. This paper aims to study the possibility of using this specimen for the assessment of radionuclides deposition in the vicinity of a nuclear research institute, Instituto de Pesquisas Energéticas e Nucleares (IPEN) located in São Paulo, Brazil. This Institute has as major activity to perform research in the field of the nuclear fuel cycle, and therefore deals with considerable amounts of natural radionuclides of the U and Th series. The activity of the naturally occurring radionuclides U-238, Ra-226, Ra-226 and Pb-210 was determined in samples of lichen (Canoparmelia texana) and soil collected at IPEN campus. The concentrations of Ra-228, Ra-226 and Pb-210 were determined by measuring alpha and beta gross counting in a gas flow proportional detector; U and Th were determined by neutron activation analysis. The values obtained varied from 164 Bq/kg to 864 Bq/kg, 13 Bq/kg to 50 Bq/kg, and from 287 Bq/kg to 730 Bq/kg for Ra-228, Ra-226 and Pb-210 respectively. For natural U and Th the values obtained varied from 1.2 Bq/kg to 162 Bq/kg and 1.84 Bq/kg to 5.17 Bq/kg respectively. The results obtained so far suggest that the Canoparmelia texana can be used as radionuclide monitor in the vicinity of nuclear installations.

  16. Magnetic Study on Environmental Samples from Guadalajara Mexico for Monitoring of Atmospheric Pollution

    Science.gov (United States)

    Aguilar, B.; Cejudo, R.; Bogalo, M. F.; Rosas-Elguera, J.; Quintana, P.; Bautista, F.; Gogichaishvili, A.; Morales, J.

    2013-05-01

    Guadalajara is the second bigger city in Mexico, catalogued as critical zone because of atmospheric pollution levels. The magnetic methodology has been largely used as an alternative way to evaluate the pollution levels as well as identify the critical points in a given area. In this work, results from chemical analyses and magnetic measurements are presented in order to show the correlation between magnetic signal and the pollution level. We analyzed three kinds of environmental samples: urban soils, urban dust and leaves from ficus benjamina. Samples were taken in 30 sites distributed along a main avenue and two secondary avenues, including three points with very poor traffic influence. We determined a ferromagnetic carrier in most of samples, magnetite probably, since the Tc calculated from the thermomagnetic curves is around 580 °C. The magnetic susceptibility (Xlf) as well as the Saturation Isothermal Remanent Magnetization (SIRM) correlate well with the heavy metals content, specially Pb in urban dusts. These results allowed us to identify the most affected points, by vehicular traffic and industrial emissions. Furthermore, the values obtained for these magnetic parameters are above of those found in other studies for polluted cities in Europe and Asia.

  17. The role of catchment vegetation in reducing atmospheric inputs of pollutant aerosols in Ganga river.

    Science.gov (United States)

    Shubhashish, Kumar; Pandey, Richa; Pandey, Jitendra

    2012-08-01

    The role of woody perennials in the Ganga river basin in modifying the run-off quality as influenced by atmospheric deposition of pollutant aerosols was investigated. The concentration of seven nutrients and eight metals were measured in atmospheric deposits as well as in run-off water under the influence of five woody perennials. Nutrient retention was recorded maximum for Bougainvillea spectabilis ranged from 4.30 % to 33.70 %. Metal retention was recorded highest for Ficus benghalensis ranged from 5.15 % to 36.98 %. Although some species showed nutrient enrichment, all the species considered in the study invariably contribute to reduce nutrients and metal concentration in run-off water. Reduction in run off was recorded maximum for B. spectabilis (nutrient 6.48 %-40.66 %; metal 7.86 %-22.85 %) and minimum for Ficus religiosa (nutrient 1.68 %-27.19 %; metal 6.55 %-31.55 %). The study forms the first report on the use of woody perennials in reducing input of atmospheric pollutants to Ganga river and has relevance in formulating strategies for river basin management.

  18. Widespread pollution of the South American atmosphere predates the industrial revolution by 240 y.

    Science.gov (United States)

    Uglietti, Chiara; Gabrielli, Paolo; Cooke, Colin A; Vallelonga, Paul; Thompson, Lonnie G

    2015-02-24

    In the Southern Hemisphere, evidence for preindustrial atmospheric pollution is restricted to a few geological archives of low temporal resolution that record trace element deposition originating from past mining and metallurgical operations in South America. Therefore, the timing and the spatial impact of these activities on the past atmosphere remain poorly constrained. Here we present an annually resolved ice core record (A.D. 793-1989) from the high-altitude drilling site of Quelccaya (Peru) that archives preindustrial and industrial variations in trace elements. During the precolonial period (i.e., pre-A.D. 1532), the deposition of trace elements was mainly dominated by the fallout of aeolian dust and of ash from occasional volcanic eruptions, indicating that metallurgic production during the Inca Empire (A.D. 1438-1532) had a negligible impact on the South American atmosphere. In contrast, a widespread anthropogenic signal is evident after around A.D. 1540, which corresponds with the beginning of colonial mining and metallurgy in Peru and Bolivia, ∼240 y before the Industrial Revolution. This shift was due to a major technological transition for silver extraction in South America (A.D. 1572), from lead-based smelting to mercury amalgamation, which precipitated a massive increase in mining activities. However, deposition of toxic trace metals during the Colonial era was still several factors lower than 20th century pollution that was unprecedented over the entirety of human history.

  19. Exploratory analysis of atmospheric pollution in a coastal forest ecosystem in central Italy

    Directory of Open Access Journals (Sweden)

    Rita Aromolo

    2015-02-01

    Full Text Available Exploratory analysis of atmospheric pollution in a coastal forest ecosystem in central Italy - The study of spatial and temporal distribution of heavy metals in the atmosphere through the continuous assessment of deposition is of great interest for the analysis of anthropogenic pressure on the environment and the potential toxicity to humans and other living organisms. Information based on reliable estimates of heavy metals is therefore crucial for the evaluation of environmental quality. Trends in heavy metal concentration in atmospheric depositions on a coastal forest ecosystem (Castelporziano, Rome are analyzed in the present study based on a three-year monitoring field survey over three sites representative of different woodland characteristics in the area. Our results highlight both the influence of transportation processes in the short and medium distance based on the human pressure reflecting urban expansion and infrastructure development on the fringe of Castelporziano pristine forest. Further studies investigating the latent correlation with meteorological variables at various temporal scales are needed to provide a comprehensive picture of environmental conditions in a forest ecosystem subjected to increasing human pressure. Analysis of runoff water quality and the determination of other heavy metals, such as arsenic, may identify additional sources of pollution impacting soil and forest ecosystem.

  20. Utilization of bromeliad Tillandsia Usneoides L. in biomonitoring of air pollution in the metropolitan region of Sao Paulo - SP, Brazil; Utilizacao da bromelia Tillandsia Usneoides L. no biomonitoramento da poluicao atmosferica na Regiao metropolitana de Sao Paulo - SP, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Albuquerque, Caroline R.; Figueiredo, Ana M.G.; Silva, Barbara C. da; Ticianelli, Regina B., E-mail: calbuuquerque@gmail.com, E-mail: anamaria@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Figueira, Rubens C.L., E-mail: aportellar@yahoo.com.br [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Instituto Oceanografico; Nievola, Catarina C.; Alves, Edenise S.; Domingos, Marisa, E-mail: ccnievola@uol.com.br, E-mail: ealves@ibot.sp.gov.br, E-mail: mmingos@superig.com.br [Instituto de Botanica (IBt-SMA/SP), Sao Paulo, SP (Brazil); Ribeiro, Andreza P., E-mail: andrezp@uninove.br [Universidade Nove de Julho (UNINOVE), Sao Paulo, SP (Brazil)

    2013-07-01

    In this study, it was determined the metals Cd, Cu, Fe, Mo, Ni, Pb and Sb in plant Tillandsia Usneoides L., an epiphyte species popularly known as old beard and able to absorb water and nutrients directly from air, aiming to estimate the contribution of human activities in atmospheric metal pollution in the metropolitan region of Sao Paulo. The samples were collected at five different points, located near the South West and stretches of highway Mario Covas (SP-21). The Neutron Activation Analysis (NAA) and Optical Emission Spectrometry with Inductively Coupled Plasma (ICP-OES) were the analytical techniques used in the quantification of metals of interest.

  1. Remote sensing of atmospheric urban pollutants with DOAS in Castilla-La Mancha (Spain)

    Science.gov (United States)

    Saiz, A.; Poblete, F. J.; Mucientes, A. E.; Maigler, F. J.; Notario, A.; Martínez, E.; Albaladejo, J.

    Urban air pollution is one of the main environmental problems, owing to implications for public health and physical environment. In urban areas, the sources of atmospheric pollutants are distributed very inhomogeneously. Trace gas concentrations measured by conventional air quality monitoring stations are always influenced by small sources in their direct vicinity and surface effects like dry deposition and small-scale wind systems. Differential Optical Absorption Spectroscopy (DOAS) is a field-oriented monitoring technique that allows very fast and continuous measurements of different airborne pollutants along an open light path. Remote sensing techniques like DOAS can avoid the problems of local influences and surface effects, as DOAS can use light paths with range from several hundred of meters to several kilometres, thus the measured concentrations are averaged over the light path and barely influenced by small-scale variances. The technique is based on the fact that all trace gases absorb electromagnetic radiation in some part of the spectrum. If the radiation of the appropriate frequency is transmitted through the atmosphere the features of absorption of each molecule in that spectral region allow the identification and quantification of the gas concentrations. Up to date, only a few long term DOAS measurements of urban air pollution have been reported, and to the best of our knowledge, this study is the first one in the South of Spain. We present here some results obtained in a long term study performed in Ciudad Real and Puertollano, where the daily, weekly and seasonal variation of the concentrations of minor important tropospheric constituents as ozone, nitric oxide, nitrogen dioxide and sulphur dioxide, have been continuously monitored.

  2. Source regions of some Persistent Organic Pollutants measured in the atmosphere at Birkenes, Norway

    Directory of Open Access Journals (Sweden)

    S. Eckhardt

    2009-05-01

    Full Text Available A key feature of POPs (Persistent Organic Pollutants is their potential for long-range atmospheric transport. In order to better understand and predict atmospheric source-receptor relationships of POPs, we have modified an existing Lagrangian transport model (FLEXPART to include some of the key processes that control the atmospheric fate of POPs. We also present four years (2004–2007 of new atmospheric measurement data for polychlorinated biphenyls (PCBs and hexachlorocyclohexanes (HCHs obtained at Birkenes, an EMEP (European Monitoring and Evaluation Programme site in Southern Norway. The model overestimates measured PCB-28 and γ-HCH concentrations by factors of 2 and 8, respectively, which is most likely because the emissions used as input to the model are overestimated. FLEXPART captures the temporal variability in the measurements very well and, depending on season, explains 31–67% (14–62% of the variance of measured PCB-28 (γ-HCH concentrations. FLEXPART, run in a time-reversed (adjoint mode, was used to identify the source regions responsible for the POP loading at the Birkenes station. Emissions in Central Europe and Eastern Europe contributed 32% and 24%, respectively, to PCB-28 at Birkenes, while Western Europe was found to be the dominant source (50% for γ-HCH. Intercontinental transport from North America contributed 13% γ-HCH. While FLEXPART has no treatment of the partitioning of POPs between different surface media, it was found a very useful tool for studying atmospheric source-receptor relationships for POPs and POP-like chemicals that do not sorb strongly to atmospheric particles and whose atmospheric levels are believed to be mainly controlled by primary sources.

  3. Assessment of human health risk related to metals by the use of biomonitors in the province of Cordoba, Argentina

    Energy Technology Data Exchange (ETDEWEB)

    Carreras, Hebe A. [Departamento de Quimica, Instituto Multidisciplinario de Biologia Vegetal, IMBIV/CONICET-UNC, Facultad de Ciencias Exactas, Fisicas y Naturales, Universidad Nacional de Cordoba, Av. Velez Sarsfield 1611, Ciudad Universitaria, X5016GCA Cordoba (Argentina)], E-mail: hcarreras@com.uncor.edu; Wannaz, Eduardo D.; Pignata, Maria L. [Departamento de Quimica, Instituto Multidisciplinario de Biologia Vegetal, IMBIV/CONICET-UNC, Facultad de Ciencias Exactas, Fisicas y Naturales, Universidad Nacional de Cordoba, Av. Velez Sarsfield 1611, Ciudad Universitaria, X5016GCA Cordoba (Argentina)

    2009-01-15

    The evaluation of metal contents in the environment is of vital importance for the assessment of human exposure. Thus the species Usnea amblyoclada, Ramalina celastri and Tillandsia capillaris were tested as bioaccumulators of transition metals in the urban area of Cordoba city, Argentina. The level of metals on biomonitors was compared to that of total deposition samples. All three species discriminated zones within the urban area of Cordoba city with different pollution levels; they revealed high levels of Zn in the downtown area and confirmed high levels of some transition metals in an industrial area. The correlation analysis revealed that the lichen R. celastri had the highest correlation rates with total deposition samples, suggesting it is a valuable biomonitor of atmospheric pollution. A significant relationship was also observed between respiratory diseases in children and the contents of metal accumulated in R. celastri and T. capillaris, indicating their usefulness when assessing human exposure to metals. - Metal accumulation in epiphytes is correlated with human respiratory diseases.

  4. Indices of atmospheric purity and fluoride pollution pattern in Arvida, Quebec

    Energy Technology Data Exchange (ETDEWEB)

    LeBlanc, F.; Rao, D.N.; Comeau, G.

    1972-01-01

    Indices of atmospheric purity (IAP) of 42 sites located in all directions from the aluminum factory at Arvida and spread out in about 250-km/sup 2/ area, were determined on the basis of phytosociology of epiphytes of Populus balsamifera. These index values ranging from 0 to 103 were arranged into six groups and the investigated area was accordingly delineated into six IAP zones to represent areas with different levels of fluoride pollution. A relative picture of the approximate limits of fluoride contamination in different zones is obtained by the fluoride accumulation in Parmelia sulcata thalli transplanted at various sites in the area.

  5. Chromatographic air analyser microsystem for the selective and sensitive detection of atmospheric pollutants

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez, Jean-Baptiste; Lahlou, Houda; Mohsen, Yehya; Berger, Franck [Laboratoire de Chimie Physique et Rayonnements, Alain Chambaudet, UMR CEA E4 UFR ST, Universite de Franche Comte, 25000 Besancon (France); Vilanova, Xavier; Correig, Xavier, E-mail: jbsanche@univ-fcomte.fr [Departament d' Enginyeria Electronica, Electrica i Automatica, Universitat Rovira i Virgili, Paisos Catalans 26, 43007, Tarragona (Spain)

    2011-08-17

    The development of industry and automotive trafic produces Volatile Organic Compounds (VOCs) whose toxicity can affect seriously human health and environment. The level of those contaminants in air must be as low as possible. In this context, there is a need for in situ systems that could monitor selectively the concentration of these compounds. The aim of this study is to demonstrate the efficiency of a system build with a pre-concentrator, a chromatographic micro-column and a tin oxide-based gas sensor for the selective and sensitive detection of atmospheric pollutants. In particular, this study is focused on the selective detection of benzene and 1,3 butadiene.

  6. Condition of Retrieving Vertical Column Density of Atmospheric Pollution Gases by Using Scattered Solar Radiation

    Institute of Scientific and Technical Information of China (English)

    ZUO Sao-Yi

    2009-01-01

    We present a method to monitor the vertical column density (VCD) of atmospheric pollution gases by using the scattered solar radiation. The necessary condition of capturing the useful scattered solar radiation is achieved. The condition is only dependent on the solar elevation angle, while independent of the solar azimuth angle, which could greatly simply the capturing equipment and procedure. Under the condition, the VCD of tropospheric NO2 in Chengdu, China is retrieved from the scattered solar radiation, which is dose to that from the direct solar radiation.

  7. Atmospheric air pollutants: CO in Nitrogen, 5 μmol/mol

    Science.gov (United States)

    Konopelko, L. A.; Pankratov, V. V.; Pankov, A. A.; Ivahnenko, B. V.; Efremova, O. V.; Bakovec, N. V.; Mironchik, A. M.; Aleksandrov, V. V.

    2017-01-01

    This article presents the report on the COOMET supplementary comparison "Atmospheric air pollutants: CO in Nitrogen, 5 μmol/mol". Carbon monoxide (CO) is present in atmosphere due to different natural and anthropogenic sources. CO is a toxic gas and in concentrations higher than (3-5) μmol/mol it is hazardous to human health. Main text To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database kcdb.bipm.org/. The final report has been peer-reviewed and approved for publication by the CCQM, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).

  8. Aspects of the physiology and biochemistry of some plants existing under the influence of atmosphere pollution

    Energy Technology Data Exchange (ETDEWEB)

    Ionescu, A.; Grou, E.

    1971-01-01

    The vegetation of the Copsa Mica(Romania) zone is often visibly affected by the noxious elements existing in the atmosphere, especially sulfur dioxide. Comparative investigations were undertaken to examine some physiological and biochemical processes in plants from polluted as well as control zones. Water content (total and fractions of free and bound water), stomata condition and hydrogen ion concentration in cellular sap were analyzed; the results of these analyses showed that at the level of all the studied processes, modifications occur, which are sometimes substantial. In laboratory experiments with Pelargonium plants grown in an atmosphere containing sulfur dioxide, a foliar symptomatology was obtained, as well as a chromatogram of free amino acids different to that of controls

  9. Monitoring chronic and acute PAH atmospheric pollution using transplants of the moss Hypnum cupressiforme and Robinia pseudacacia leaves

    Science.gov (United States)

    Capozzi, F.; Di Palma, A.; Adamo, P.; Spagnuolo, V.; Giordano, S.

    2017-02-01

    Few studies are focused on correlations between the concentrations of PAHs in mosses and other bioindicator plant species. This study was carried out to investigate the potential of the joint use of devitalized H. cupressiforme transplants and R. pseudoacacia leaves as cost effective biomonitors for the assessment of PAHs in the air. The test was performed in a land historically devoted to agriculture, where recurrent waste burnings randomly occur, especially in the season we chose for the investigation. The presence of 20 PAHs was assessed following EPA 3550 C 2007 and EPA 8270 D 2014 protocols. R. pseudoacacia was able to accumulate both LMW and HMW PAHs, while moss prevalently collected the latter. It is suggested that R. pseudoacacia combined chronic pyrogenic and petrogenic PAH inputs, while moss transplants reflected PAH depositions from recent pyrogenic events. Our approach revealed long and short-term pollution footprints, with R. pseudoacacia recording the chronic input of PAH compounds loaded along its vegetative growth, and moss bags reflecting acute pollution inputs occurred during the exposure duration.

  10. Size and time-resolved roadside enrichment of atmospheric particulate pollutants

    Directory of Open Access Journals (Sweden)

    F. Amato

    2011-01-01

    Full Text Available Size and time-resolved roadside enrichments of atmospheric particulate pollutants in PM10 were detected and quantified in a Mediterranean urban environment (Barcelona, Spain. Simultaneous data from one urban background (UB, one traffic (T and one heavy traffic (HT location were analysed, and roadside PM10 enrichments (RE in a number of elements arising from vehicular emissions were calculated. Tracers of primary traffic emissions (EC, Fe, Ba, Cu, Sb, Cr, Sn showed the largest REs (>70%. Other traffic tracers (Zr, Cd showed lower but still consistent REs (25–40%, similar to those obtained for mineral matter resulting from road dust resuspension (Ca, La, Ce, Ti, Ga, Sr, 30–40%. The sum of primary and secondary organic carbon showed a RE of 41%, with contributions of secondary OC (SOC to total OC ranging from 46% at the HT site, 63% at the T site, and 78% in the UB. Finally, other trace elements (As, Co, Bi showed unexpected but consistent roadside enrichments (23% up to 69%, suggesting a link to traffic emissions even though the emission process is unclear.

    Hourly-resolved PM speciation data proved to be a highly resourceful tool to determine the source origin of atmospheric pollutants in urban environments. At the HT site, up to 62% of fine Mn was attributable to industrial plumes, whereas coarse Mn levels were mainly attributed to traffic. Similarly, even though Zn showed on average no roadside enrichment and thus was classified as industrial, the hourly-resolved data proved that at least 15% of coarse Zn may be attributed to road traffic emissions. In addition, our results indicate that secondary nitrate formation occurs within the city-scale, even in the absence of long atmospheric residence times or long-range atmospheric transport processes.

  11. Earthworms and Soil Pollutants

    Directory of Open Access Journals (Sweden)

    Kazuyoshi Tamae

    2011-11-01

    Full Text Available Although the toxicity of metal contaminated soils has been assessed with various bioassays, more information is needed about the biochemical responses, which may help to elucidate the mechanisms involved in metal toxicity. We previously reported that the earthworm, Eisenia fetida, accumulates cadmium in its seminal vesicles. The bio-accumulative ability of earthworms is well known, and thus the earthworm could be a useful living organism for the bio-monitoring of soil pollution. In this short review, we describe recent studies concerning the relationship between earthworms and soil pollutants, and discuss the possibility of using the earthworm as a bio-monitoring organism for soil pollution.

  12. Biomonitoring plan for Seedskadee National Wildlife Refuge

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This proposed biomonitoring plan is for Seedskadee National Wildlife Refuge in Sweetwater county, Wyoming. Biomonitoring is needed for the refuge especially due to...

  13. Effects of atmospheric deposition of energy-related pollutants on water quality: a review and assessment

    Energy Technology Data Exchange (ETDEWEB)

    Davis, M.J.

    1981-05-01

    The effects on surface-water quality of atmospheric pollutants that are generated during energy production are reviewed and evaluated. Atmospheric inputs from such sources to the aquatic environment may include trace elements, organic compounds, radionuclides, and acids. Combustion is the largest energy-related source of trace-element emissions to the atmosphere. This report reviews the nature of these emissions from coal-fired power plants and discusses their terrestrial and aquatic effects following deposition. Several simple models for lakes and streams are developed and are applied to assess the potential for adverse effects on surface-water quality of trace-element emissions from coal combustion. The probability of acute impacts on the aquatic environment appears to be low; however, more subtle, chronic effects are possible. The character of acid precipitation is reviewed, with emphasis on aquatic effects, and the nature of existing or potential effects on water quality, aquatic biota, and water supply is considered. The response of the aquatic environment to acid precipitation depends on the type of soils and bedrock in a watershed and the chemical characteristics of the water bodies in question. Methods for identifying regions sensitive to acid inputs are reviewed. The observed impact of acid precipitation ranges from no effects to elimination of fish populations. Coal-fired power plants and various stages of the nuclear fuel cycle release radionuclides to the atmosphere. Radioactive releases to the atmosphere from these sources and the possible aquatic effects of such releases are examined. For the nuclear fuel cycle, the major releases are from reactors and reprocessing. Although aquatic effects of atmospheric releases have not been fully quantified, there seems little reason for concern for man or aquatic biota.

  14. Influence of the characteristics of atmospheric boundary layer on the vertical distribution of air pollutant in China's Yangtze River Delta

    Science.gov (United States)

    Wang, Chenggang; Cao, Le

    2016-04-01

    Air pollution occurring in the atmospheric boundary layer is a kind of weather phenomenon which decreases the visibility of the atmosphere and results in poor air quality. Recently, the occurrence of the heavy air pollution events has become more frequent all over Asia, especially in Mid-Eastern China. In December 2015, the most severe air pollution in recorded history of China occurred in the regions of Yangtze River Delta and Beijing-Tianjin-Hebei. More than 10 days of severe air pollution (Air Quality Index, AQI>200) appeared in many large cities of China such as Beijing, Tianjin, Shijiazhuang and Baoding. Thus, the research and the management of the air pollution has attracted most attentions in China. In order to investigate the formation, development and dissipation of the air pollutions in China, a field campaign has been conducted between January 1, 2015 and January 28, 2015 in Yangtze River Delta of China, aiming at a intensive observation of the vertical structure of the air pollutants in the atmospheric boundary layer during the time period with heavy pollution. In this study, the observation data obtained in the field campaign mentioned above is analyzed. The characteristics of the atmospheric boundary layer and the vertical distribution of air pollutants in the city Dongshan located in the center of Lake Taihu are shown and discussed in great detail. It is indicated that the stability of the boundary layer is the strongest during the nighttime and the early morning of Dongshan. Meanwhile, the major air pollutants, PM2.5 and PM10 in the boundary layer, reach their maximum values, 177.1μg m-3 and 285μg m-3 respectively. The convective boundary layer height in the observations ranges from approximately 700m to 1100m. It is found that the major air pollutants tend to be confined in a relatively shallow boundary layer, which represents that the boundary layer height is the dominant factor for controlling the vertical distribution of the air pollutants. In

  15. Mass identification of the neutral products generated in the plasma treatment of polluted atmospheres

    Science.gov (United States)

    Seymour, David

    2013-09-01

    Plasmas produced using Dielectric Barrier Discharge (DBD) devices are very effective in the abatement of air pollution resulting from, for example, the emission of volatile organic compounds (VCOs) by a range of industrial and agricultural processes. The development and monitoring of effective DBD systems can be investigated by advanced mass spectrometric methods specifically configured for analysis at high and atmospheric pressures The present work involves the operation of a small DBD reactor which uses either a helium or nitrogen carrier gas to sustain the plasma to which may be added reactive gases, such as oxygen, as well as samples of pollutants such as chlorinated hydrocarbons, including trichloroethylene. The mass spectrometric analysis was performed using a specially configured system manufactured by Hiden Analytical Ltd. The DBD source may also be combined with a catalyst for plasma-enhanced catalysis. The neutral products of the reactions proceeding in the plasma at atmospheric pressure are sampled through the capillary sampling system which also reduces the pressure of the gas mixture delivered to the ionisation source of the quadrupole mass spectrometer. The ions produced are subsequently mass identified. We describe typical data and comment on the advantages of this technique.

  16. Performance of sulfation and nitration plates used to monitor atmospheric pollutant deposition in a real environment

    Energy Technology Data Exchange (ETDEWEB)

    Noel, D.; Hechler, J.; Roberge, H.

    1989-01-01

    Sulfation and nitration plates were exposed outdoors for various periods of time to evaluate their performance in a real environment. These passive monitors are used to estimate the deposition of pollutants on metallic surfaces, and thus to evaluate the influence of the atmosphere on the corrosion. Single-column ion chromatography was used to determine the quantity of anions absorbed on the plates. This technique is better than other analytical procedures such as turbidimetry or colorimetry because passive monitors exposed in an atmosphere with a low degree of pollution can be analyzed without preconcentration. However, the pH of the sample to be injected on the chromatographic column must be adjusted to between 6.0 and 12.0 in order to obtain reproducible sulfate values. For sulfation plates, the additivity of the deposition process is excellent for a period of exposure up to 3 months, with a reproducibility of about 2%. For nitration plates, the deposition process is not cumulative due to a physical change of the monitor during exposure. The correlation between the amounts of sulfate found on sulfation snd nitration plates was also examined. 16 refs., 6 figs., 5 tabs.

  17. Atmospheric pollution in the Tula Industrial Corridor studied using a bio monitor and nuclear analytical techniques

    Energy Technology Data Exchange (ETDEWEB)

    Martinez C, M. A.; Solis, C.; Andrade, E. [UNAM, Instituto de Fisica, Apdo. Postal 20-364, 01000 Mexico D. F. (Mexico); Beltran H, R. I. [Universidad Autonoma del Estado de Hidalgo, Centro de Investigaciones Quimicas, Carretera Pachuca-Tulancingo Km. 4.5, 42184 Pachuca, Hidalgo (Mexico); Issac O, K. [Universidad Autonoma del Estado de Mexico, Facultad de Medicina, Paseo Tollocan s/n, esq. Jesus Carranza, 50120 Toluca, Estado de Mexico (Mexico); Lucho C, C. A. [Universidad Politecnica de Pachuca, Carretera Pachuca-Cd. Sahagun Km. 20, Hidalgo (Mexico); Lopez R, M. C.; Longoria, L. C. [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2011-02-15

    This study deals with the application of nuclear analytical techniques to analyze trace elements in the biological monitor Tillandsia usneoides. Biological monitors provides an alternative advantageous way of particulate matter sampling in air pollution studies, since there is no need of special sampling devices, accumulation time can be as long as desired. T. usneoides, which occurs naturally throughout Mexico, was used to monitor air quality of Tula-Vito-Apasco (TVA) industrial corridor at central Mexico. This area is considered one of the critical zones of the country because of atmospheric contaminants high concentration. Particulate matter is regulated by Mexican norms, but its chemical composition is not. Plants were transplanted from a clean environment to four sites at the TVA corridor, and exposed for 12 weeks from February to April 2008. Trace element accumulation of plants was determined by particle induced X-ray emission and neutron activation analysis. Results reveal differences in trace elements distribution among sites in the TVA corridor. Furthermore, anthropogenic elements (S, V) and crustal elements (Ca) in T. usneoides exhibit high levels. Highly toxic elements such as Hg, As and Cr although present at trace levels, showed un enrichment relative to the initial values, when transplanted to the TVA corridor. Results show that monitoring with T. usneoides allows a first approximation of air sources to provide insights of the atmospheric pollution in the TVA corridor. (Author)

  18. Plant volatile organic compounds (VOCs) in ozone (O3) polluted atmospheres: the ecological effects.

    Science.gov (United States)

    Pinto, Delia M; Blande, James D; Souza, Silvia R; Nerg, Anne-Marja; Holopainen, Jarmo K

    2010-01-01

    Tropospheric ozone (O3) is an important secondary air pollutant formed as a result of photochemical reactions between primary pollutants, such as nitrogen oxides (NOx), and volatile organic compounds (VOCs). O3 concentrations in the lower atmosphere (troposphere) are predicted to continue increasing as a result of anthropogenic activity, which will impact strongly on wild and cultivated plants. O3 affects photosynthesis and induces the development of visible foliar injuries, which are the result of genetically controlled programmed cell death. It also activates many plant defense responses, including the emission of phytogenic VOCs. Plant emitted VOCs play a role in many eco-physiological functions. Besides protecting the plant from abiotic stresses (high temperatures and oxidative stress) and biotic stressors (competing plants, micro- and macroorganisms), they drive multitrophic interactions between plants, herbivores and their natural enemies e.g., predators and parasitoids as well as interactions between plants (plant-to-plant communication). In addition, VOCs have an important role in atmospheric chemistry. They are O3 precursors, but at the same time are readily oxidized by O3, thus resulting in a series of new compounds that include secondary organic aerosols (SOAs). Here, we review the effects of O3 on plants and their VOC emissions. We also review the state of current knowledge on the effects of ozone on ecological interactions based on VOC signaling, and propose further research directions.

  19. Interaction of pollution plumes and discontinuous fields in atmospheric chemistry models

    Science.gov (United States)

    Santillana, Mauricio; Brenner, Michael P.; Rastigeyev, Yevgeniy; Jacob, Daniel J.

    2010-11-01

    Atmospheric pollutants originate from concentrated sources such as cities, power plants, and biomass fires. They are injected in the troposphere where eddies and convective motions of various scales act to shear and dilute the pollution plumes as they are advected downwind. Despite this shear and dilution, observations from aircraft, sondes, and satellites show that pollution plumes in the remote free troposphere can preserve their identity as well-defined layers for a week or more as they are transported on intercontinental scales. This structure cannot be reproduced in the standard Eulerian chemical transport models used for global modeling of tropospheric composition, instead, the plumes dissipate far too quickly. In this work, we study how the structure of plumes is modified when they cross discontinuities arising for example: from the moving day-night boundaries or from abrupt unresolved horizontal temperature changes (for example in horizontal ocean-land or ocean-ice transitions). Chemical reactions within the plumes depend strongly on photon availability and temperature, and thus, discontinuities in these variables lead to discontinuous changes in reaction rate constants.

  20. Dendrochemistry Application as a Tool for Biomonitoring Environmental Pollution of Mining Areas%年轮化学示踪技术及在重现矿区重金属污染历史中的应用

    Institute of Scientific and Technical Information of China (English)

    雷梅; 郭立新; 张山岭

    2011-01-01

    The trees, naturally growing in the mining areas, can uptake heavy metals from air, soil, and irrigation water. The pathways of heavy metals entering the trees might be roots, barks, and leaves. After entering the trees, heavy metals will deposit in the tree-rings during cambium development. The long-term fluctuations of element contents in tree rings can be analysed by the laser ablation system coupled to an inductively coupled plasma mass spectrometer. Therefore, the pollution processes of mining areas can be recorded by the variation of heavy metal concentrations in the tree-rings, and the influential ratios of different pollution routes can be semi-quantitatively determined. Cases of applications of dendrochemistry in biomonitofing of air, water and soil pollution were reviewed in this article. Based on the point pollution characteristics of mining areas, the possibility of applying dendrochemistry for pollution monitoring was discussed. Aiming to improve the accuracy of research of atmospheric and soil pollution in mining areas by dendrochemistry, different influential factors of heavy metal concentrations in tree rings, such as tree species, selective uptake of elements by trees, climate variation and nutrient providing, were reviewed. Geostatistics, stable isotope tracer, and synchrotron radiation X-ray fluorescence can improve the accuracy of dendrochemistry for environmental pollution recording. Atmospheric dispersion model predicting ground-level concentrations from a point source of metal emissions, such as smelters, can be calibrated on tree rings in order to reconstruet the spatial and temporal Pb-contamination pattern. Dating of the historical record has been achieved using isotopic analysis, for example 210Pb and 137Cs. With the development of analytical techniques of heavy metals in tree rings, dendrochemistry will play a more important role in pollution monitoring in mining areas. This review highlights the strong potential for dendrochemistry to

  1. Using an epiphytic moss to identify previously unknown sources of atmospheric cadmium pollution

    Energy Technology Data Exchange (ETDEWEB)

    Donovan, Geoffrey H., E-mail: gdonovan@fs.fed.us [USDA Forest Service, PNW Research Station, 620 SW Main, Suite 400, Portland, OR 97205 (United States); Jovan, Sarah E., E-mail: sjovan@fs.fed.us [USDA Forest Service, PNW Research Station, 620 SW Main, Suite 400, Portland, OR 97205 (United States); Gatziolis, Demetrios, E-mail: dgatziolis@fs.fed.us [USDA Forest Service, PNW Research Station, 620 SW Main, Suite 400, Portland, OR 97205 (United States); Burstyn, Igor, E-mail: igor.burstyn@drexel.edu [Dornsife School of Public Health, Drexel University, Nesbitt Hall, 3215 Market St, Philadelphia, PA 19104 (United States); Michael, Yvonne L., E-mail: ylm23@drexel.edu [Dornsife School of Public Health, Drexel University, Nesbitt Hall, 3215 Market St, Philadelphia, PA 19104 (United States); Amacher, Michael C., E-mail: mcamacher1@outlook.com [USDA Forest Service, Logan Forest Sciences Laboratory, 860 North 1200 East, Logan, UT 84321 (United States); Monleon, Vicente J., E-mail: vjmonleon@fs.fed.us [USDA Forest Service, PNW Research Station, 3200 SW Jefferson Way, Corvallis, OR 97331 (United States)

    2016-07-15

    Urban networks of air-quality monitors are often too widely spaced to identify sources of air pollutants, especially if they do not disperse far from emission sources. The objectives of this study were to test the use of moss bio-indicators to develop a fine-scale map of atmospherically-derived cadmium and to identify the sources of cadmium in a complex urban setting. We collected 346 samples of the moss Orthotrichum lyellii from deciduous trees in December, 2013 using a modified randomized grid-based sampling strategy across Portland, Oregon. We estimated a spatial linear model of moss cadmium levels and predicted cadmium on a 50 m grid across the city. Cadmium levels in moss were positively correlated with proximity to two stained-glass manufacturers, proximity to the Oregon–Washington border, and percent industrial land in a 500 m buffer, and negatively correlated with percent residential land in a 500 m buffer. The maps showed very high concentrations of cadmium around the two stained-glass manufacturers, neither of which were known to environmental regulators as cadmium emitters. In addition, in response to our findings, the Oregon Department of Environmental Quality placed an instrumental monitor 120 m from the larger stained-glass manufacturer in October, 2015. The monthly average atmospheric cadmium concentration was 29.4 ng/m{sup 3}, which is 49 times higher than Oregon's benchmark of 0.6 ng/m{sup 3}, and high enough to pose a health risk from even short-term exposure. Both stained-glass manufacturers voluntarily stopped using cadmium after the monitoring results were made public, and the monthly average cadmium levels precipitously dropped to 1.1 ng/m{sup 3} for stained-glass manufacturer #1 and 0.67 ng/m{sup 3} for stained-glass manufacturer #2. - Highlights: • Bio-indicators are a valid method for measuring atmospheric pollutants • We used moss to map atmospheric cadmium in Portland, Oregon • Using a spatial linear model, we identified two

  2. Atmospheric emissions and pollution from the coal-fired thermal power plants in India

    Science.gov (United States)

    Guttikunda, Sarath K.; Jawahar, Puja

    2014-08-01

    In India, of the 210 GW electricity generation capacity, 66% is derived from coal, with planned additions of 76 GW and 93 GW during the 12th and the 13th five year plans, respectively. Atmospheric emissions from the coal-fired power plants are responsible for a large burden on human health. In 2010-11, 111 plants with an installed capacity of 121 GW, consumed 503 million tons of coal, and generated an estimated 580 ktons of particulates with diameter less than 2.5 μm (PM2.5), 2100 ktons of sulfur dioxides, 2000 ktons of nitrogen oxides, 1100 ktons of carbon monoxide, 100 ktons of volatile organic compounds, and 665 million tons of carbon dioxide. These emissions resulted in an estimated 80,000 to 115,000 premature deaths and 20.0 million asthma cases from exposure to PM2.5 pollution, which cost the public and the government an estimated INR 16,000 to 23,000 crores (USD 3.2 to 4.6 billion). The emissions were estimated for the individual plants and the atmospheric modeling was conducted using CAMx chemical transport model, coupled with plume rise functions and hourly meteorology. The analysis shows that aggressive pollution control regulations such as mandating flue gas desulfurization, introduction and tightening of emission standards for all criteria pollutants, and updating procedures for environment impact assessments, are imperative for regional clean air and to reduce health impacts. For example, a mandate for installation of flue gas desulfurization systems for the operational 111 plants could reduce the PM2.5 concentrations by 30-40% by eliminating the formation of the secondary sulfates and nitrates.

  3. Distribution and sources of bioaccumulative air pollutants at Mezquital Valley, Mexico, as reflected by the atmospheric plant Tillandsia recurvata L.

    Directory of Open Access Journals (Sweden)

    L. Chang Martínez

    2009-03-01

    Full Text Available Mezquital Valley (MV, a Mexican wastewater-based agricultural and industrial region, is a ''hot spot'' of regulated air pollutants emissions, but the concurrent unregulated ones, like hazardous metals and polycyclic aromatic hydrocarbons (PAH, remain undocumented. A biomonitoring survey with the epiphytic Tillandsia recurvata was conducted there to detect spatial patterns and potential sources of 20 airborne elements and 15 PAH. The natural δ13C and δ15N ratios of this plant helped in source identification. The regional mean concentrations of most elements was two (Cr to over 40 times (Ni, Pb, V higher than reported for Tillandsia in other countries. Eleven elements, pyrene and chrysene had 18–214% higher mean concentration at the industrial south than at the agricultural north of MV. The total quantified PAH (mean, 572 ng g−1; range, 142.6–2568 were composed by medium (65%, phenanthrene to chrysene, low (28%, naphthalene to fluorene and high molecular weight compounds (7%, Benzo(bfluoranthene to indeno(1,2,3-cdpyrene. The δ13C (mean, −14.6‰; range, −5.7 to −13.7‰ was lower (<−15‰ near the major petroleum combustion sources. The δ15N (mean, −3.0‰; range, −9.9 to 3.3‰ varied from positive at agriculture/industrial areas to negative at rural sites. Factor analysis provided a five-factor solution for 74% of the data variance: (1 crustal rocks, 39.5% (Al, Ba, Cu, Fe, Sr, Ti; (2 soils, 11.3%, contrasting contributions from natural (Mg, Mn, Zn and saline agriculture soils (Na; (3 cement production and fossil fuel combustion, 9.8% (Ca, Ni, V, chrysene, pyrene; (4 probable agricultural biomass burning, 8.1% (K and benzo(g,h,iperylene, and (5 agriculture with wastewater, 5.2% (δ15N and P. These results indicated high deposition of bioaccumulative air pollutants at MV, especially at the industrial area. Since T. recurvata reflected the regional differences in exposition, it is recommended as a biomonitor for comparisons

  4. Change of the dynamics of heavy metals concentration in atmospheric precipitation in chatkal nature reservation of the republic of uzbekistan as anthropogenic index of the atmospheric pollution

    Science.gov (United States)

    Smirnova, T.; Tolkacheva, G.

    2003-04-01

    At present the investigation of the chemical composition of precipitation is a very actual task in the monitoring of environmental pollution. It is known that heavy metals can be the indices of the anthropogenic atmospheric pollution. The emissions from the mining enterprises, of non-ferrous metallurgy, of chemical industry, from heat-and-power production plants, from transport vehicles fare the sources of the heavy metals ingress into the atmosphere. Their emissions in atmosphere form fine-disperse aerosol fractions and afterwards they fall down together with precipitation onto the underlying surface. Heavy metals have the property of accumulation in environmental objects, which disturbs its ecological balance. One of the problems of the study of the influence of heavy metals pollution on the environment is their travel with the air masses of different origin on large distance. In this concern it is interesting to study the content of the heavy metals in atmospheric aerosols and precipitation in the background zones. Chatkal nature reservation on the territory of Tashkent province presents such background point. For the estimation of the level of atmospheric pollution by heavy metals and evaluation of the possible impact on the background level of air pollution of Chatkal nature reservation by anthropogenic sources (industrial cities of the capital province of Uzbekistan) the data analysis was carried out by the Administration of Environment Pollution Monitoring (AEPM) of hydrometeorological service of the Republic of Uzbekistan. It is necessary to mention that Chatkal biospheric nature reservation is situated in 100 km from Tashkent (the capital of the Republic of Uzbekistan) and in 60 km from Almalyk (the biggest centre of mining-metallurgical and chemical industry of the republic). The station of the complex background monitoring of atmospheric pollution (SCBM) is situated on the territory of this nature reservation. This area is characterized by a typical

  5. [Pollution evaluation and health risk assessment of heavy metals from atmospheric deposition in Lanzhou].

    Science.gov (United States)

    Li, Ping; Xue, Su-Yin; Wang, Sheng-Li; Nan, Zhong-Ren

    2014-03-01

    In order to evaluate the contamination and health risk of heavy metals from atmospheric deposition in Lanzhou, samples of atmospheric deposition were collected from 11 sampling sites respectively and their concentrations of heavy metals were determined. The results showed that the average contents of Cu, Pb, Cd, Cr, Ni, Zn and Mn were 82.22, 130.31, 4.34, 88.73, 40.64, 369.23 and 501.49 mg x kg(-1), respectively. There was great difference among different functional areas for all elements except Mn. According to the results, the enrichment factor score of Mn was close to 1, while the enrichment of Zn, Ni, Cu and Cr was more serious, and Pb and Cd were extremely enriched. The assessment results of geoaccumulation index of potential ecological risk indicated that the pollution of Cd in the atmospheric deposition of Lanzhou should be classified as extreme degree, and that of Cu, Ni, Zn, Pb as between slight and extreme degrees, and Cr as practically uncontaminated. Contaminations of atmospheric dust by heavy metals in October to the next March were more serious than those from April to August. Health risk assessment indicated that the heavy metals in atmospheric deposition were mainly ingested by human bodies through hand-mouth ingestion. The non-cancer risk was higher for children than for adults. The order of non-cancer hazard indexes of heavy metals was Pb > Cr > Cd > Cu > Ni > Zn. The non-cancer hazard indexes and carcinogen risks of heavy metals were both lower than their threshold values, suggesting that they will not harm the health.

  6. Chemical and isotopical characterisation of atmospheric pollution from urban and rural environments of the Rhine Valley (PCBs, trace elements and Sr-, Nd- and Pb- isotope determinations)

    Science.gov (United States)

    Guéguen, F.; Stille, P.; Millet, M.; Dietze, V.; Gieré, R.

    2010-05-01

    Atmosheric samples (gas and particulate matter (PM)) have been collected in the urban environment of the cities of Strasbourg and Kehl and in the rural environment of the Vosges mountains. For sampling of gas phase pollutants and particles two different passive sampler devices have been applied (PAS and Sigma-2, respectively). The PAS has been used for gas phase Polychlorinated Biphenyls (PCBs) sampling and is based on the passive adsorption of gas phase pollutants onto XAD-2 resin. The Sigma-2 sampler is based on the sedimentation principle (Stoke's law), collects particles in the size range 2.5-100 μm and allows the calculation of ambient air concentration. The sampler is mainly used for routine air quality measurements in German health and recreation resorts and in this field study the first time for collection of samples for subsequent trace element and isotope analysis. The collection time for the Sigma-2 and PAS are four and two weeks, respectively. Major and trace elements have been analyzed by ICP-MS and the Sr, Nd and Pb isotope ratios by a sector field MC-ICP-MS (Neptune) while PCBs were ASE extracted and analysed by GC-ECD. The aerosol data are compared with those from tree barks which have previously been used successfully as biomonitors of atmospheric pollution (Lahd Geagea et al. 2008)1. The outer 1 mm thick part of the bark has been analyzed corresponding to about 2 to 8 years of accumulation. Some of the trace elements (Cr, Ni and Mo) of the aerosol samples are strongly (up to 1000 times) enriched compared to average 'upper continental crust (UCC)'. Normalization to a « natural » sample with an atmospheric baseline composition allows to identify industrial contributions: transition metals (Cr, Mn, Fe, Co, Ni, Zn, Mo, Cd), Ba and Pb appear to be important elements in steel plant and incinerator (chemical waste) emissions. Similarly enrichment in light rare earth elements (La, Pr, Nd) is observable. The enrichments increase with decreasing distance

  7. A new conceptual model for quantifying transboundary contribution of atmospheric pollutants in the East Asian Pacific rim region.

    Science.gov (United States)

    Lai, I-Chien; Lee, Chon-Lin; Huang, Hu-Ching

    2016-03-01

    Transboundary transport of air pollution is a serious environmental concern as pollutant affects both human health and the environment. Many numerical approaches have been utilized to quantify the amounts of pollutants transported to receptor regions, based on emission inventories from possible source regions. However, sparse temporal-spatial observational data and uncertainty in emission inventories might make the transboundary transport contribution difficult to estimate. This study presents a conceptual quantitative approach that uses transport pathway classification in combination with curve fitting models to simulate an air pollutant concentration baseline for pollution background concentrations. This approach is used to investigate the transboundary transport contribution of atmospheric pollutants to a metropolitan area in the East Asian Pacific rim region. Trajectory analysis categorized pollution sources for the study area into three regions: East Asia, Southeast Asia, and Taiwan cities. The occurrence frequency and transboundary contribution results suggest the predominant source region is the East Asian continent. This study also presents an application to evaluate heavy pollution cases for health concerns. This new baseline construction model provides a useful tool for the study of the contribution of transboundary pollution delivered to receptors, especially for areas deficient in emission inventories and regulatory monitoring data for harmful air pollutants.

  8. Variational approach to direct and inverse problems of atmospheric pollution studies

    Science.gov (United States)

    Penenko, Vladimir; Tsvetova, Elena; Penenko, Alexey

    2016-04-01

    We present the development of a variational approach for solving interrelated problems of atmospheric hydrodynamics and chemistry concerning air pollution transport and transformations. The proposed approach allows us to carry out complex studies of different-scale physical and chemical processes using the methods of direct and inverse modeling [1-3]. We formulate the problems of risk/vulnerability and uncertainty assessment, sensitivity studies, variational data assimilation procedures [4], etc. A computational technology of constructing consistent mathematical models and methods of their numerical implementation is based on the variational principle in the weak constraint formulation specifically designed to account for uncertainties in models and observations. Algorithms for direct and inverse modeling are designed with the use of global and local adjoint problems. Implementing the idea of adjoint integrating factors provides unconditionally monotone and stable discrete-analytic approximations for convection-diffusion-reaction problems [5,6]. The general framework is applied to the direct and inverse problems for the models of transport and transformation of pollutants in Siberian and Arctic regions. The work has been partially supported by the RFBR grant 14-01-00125 and RAS Presidium Program I.33P. References: 1. V. Penenko, A.Baklanov, E. Tsvetova and A. Mahura . Direct and inverse problems in a variational concept of environmental modeling //Pure and Applied Geoph.(2012) v.169: 447-465. 2. V. V. Penenko, E. A. Tsvetova, and A. V. Penenko Development of variational approach for direct and inverse problems of atmospheric hydrodynamics and chemistry, Izvestiya, Atmospheric and Oceanic Physics, 2015, Vol. 51, No. 3, p. 311-319, DOI: 10.1134/S0001433815030093. 3. V.V. Penenko, E.A. Tsvetova, A.V. Penenko. Methods based on the joint use of models and observational data in the framework of variational approach to forecasting weather and atmospheric composition

  9. Causes of daily cycle variability of atmospheric pollutants in a western Mediterranean urban site (DAURE campaign)

    Science.gov (United States)

    Reche, Cristina; Moreno, Teresa; Viana, Mar; Querol, Xavier; Alastuey, Andrés.; Jimenez, Jose L.; Pandolfi, Marco; Amato, Fulvio; Pérez, Noemí; Moreno, Natalia

    2010-05-01

    The 2009 DAURE Aerosol Campaign (23-February-2009 to 27-March-2009 and 1-July to 31-July) (see Presentation: Pandolfi et al., section AS3.2) had the objective of characterising the main sources and chemical processes controlling atmospheric pollution due to particulate matter in the Mediterranean site of Barcelona (Spain). An urban and a rural background site were selected in order to describe both kinds of pollution setting. Several parameters were taken into consideration, including the variability of mass concentration in the coarse and fine fractions, particle number, amount of black carbon and the concentration of gaseous pollutants (SO2, H2S, NO, NO2, CO, O3) present. Comparisons between the chemical composition of ambient atmospheric particles during day versus night were made using twelve-hour PM samples. The data shown here are focused on results obtained for the urban site where two main atmospheric settings were distinguishable in winter, namely Atlantic advection versus local air mass recirculation. During the warmer months Saharan dust intrusions added a third important influence on PM background. The data demonstrate that superimposed upon these background influences on city air quality are important local contributions from road traffic, construction-demolition works and shipping. There is also a major local contribution of secondary aerosols, with elevated number of particles occurring at midday (and especially in summer) when nucleation processes are favoured by photochemistry. Concentrations of SO2 peak at different times to the other gaseous pollutants due to regular daytime onshore south-easterly breezes bringing harbour emissions into the city. Road traffic in Barcelona also has a great impact on air quality, as demonstrated by daily and weekly cycles of gaseous pollutants, black carbon and the finer fraction of PM, with peaks being coincident with traffic rush-hours (8-10h and 20-22h), levels of pollution increasing from Monday to Friday, and

  10. Mass flows of nitrogen-containing pollutants between atmosphere and forest ecosystem. Massenfluesse stickstoffhaltiger Schadstoffe zwischen Atmosphere und Waldoekosystem

    Energy Technology Data Exchange (ETDEWEB)

    Jaeschke, W.; Grieser, J.; Herrmann, U.; Kessel, M.; Kosiol, W.; Nietzsche, I.; Sattler, T. (Frankfurt Univ. (Germany). Zentrum fuer Umweltforschung)

    1992-01-01

    In the discussion about the possible causes of novel forest decline, nitrogen-containing components in the atmosphere have received increased interest in recent years. At the Centre for Environmental Research of the University of Frankfurt, a new approach to this problem was tried within the framework of the coordinated research project Frankfurter Stadtwald. A whole number of concentrations and flows of different pollutants were used to make up a balance for the area of investigation. Where possible, all relevant concentrations and flows were to be measured or at least realistically estimated. Therefore several measuring set-ups were realized. From the compiled data, a budget of nitrogen-containing components for the area of investigation was made up. This novel approach gives an idea of the concentrations and flows of a multitude of nitrogen compounds in an ecosystem like the Frankfurter Stadtwald. These constitute a necessary basis for impact investigations by botanists to explain novel forest decline. (orig./KW) With 90 figs., 23 tabs.

  11. An analytical model for radioactive pollutant release simulation in the atmospheric boundary layer

    Energy Technology Data Exchange (ETDEWEB)

    Weymar, Guilherme J.; Vilhena, Marco T.; Bodmann, Bardo E.J., E-mail: guicefetrs@gmail.com, E-mail: mtmbvilhena@gmail.com, E-mail: bejbodmann@gmail.com [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Programa de Pos-Graduacao em Engenharia Mecanica; Buske, Daniela; Quadros, Regis, E-mail: danielabuske@gmail.com, E-mail: quadros99@gmail.com [Universidade Federal de Pelotas (UFPel), Capao do Leao, RS (Brazil). Programa de Pos-Graduacao em Modelagem Matematica

    2013-07-01

    Simulations of emission of radioactive substances in the atmosphere from the Brazilian nuclear power plant Angra 1 are a necessary tool for control and elaboration of emergency plans as a preventive action for possible accidents. In the present work we present an analytical solution for radioactive pollutant dispersion in the atmosphere, solving the time-dependent three-dimensional advection-diffusion equation. The experiment here used as a reference in the simulations consisted of the controlled releases of radioactive tritiated water vapor from the meteorological tower close to the power plant at Itaorna Beach. The wind profile was determined using experimental meteorological data and the micrometeorological parameters were calculated from empirical equations obtained in the literature. We report on a novel analytical formulation for the concentration of products of a radioactive chain released in the atmospheric boundary layer and solve the set of coupled equations for each chain radionuclide by the GILTT solution, assuming the decay of all progenitors radionuclide for each equation as source term. Further we report on numerical simulations, as an explicit but fictitious example and consider three radionuclides in the radioactive chain of Uranium 235. (author)

  12. Modeling of urban atmospheric pollution and impact on health; Modelisation de la pollution atmospherique urbaine et impact sur la sante

    Energy Technology Data Exchange (ETDEWEB)

    Myrto, Valari

    2009-10-15

    The goal of this dissertation, is to develop a methodology that provides an improved knowledge of the associations between atmospheric contaminant concentrations and health impact. The propagation of uncertainties from input data to the output concentrations through a Chemistry Transport Model was first studied. The influence of the resolutions of meteorological parameters and emissions data were studied separately, and their relative role was compared. It was found that model results do not improve linearly with the resolution of emission input. A critical resolution was found, beyond which model error becomes higher and the model breaks down. Based on this first investigation concerning the direct down scaling, further research focused on sub grid scale modeling. Thus, a statistical down scaling approach was adopted for the modeling of sub grid-scale concentration variability due to heterogeneous surface emissions. Emission fractions released from different types of sources (industry, roads, residential, natural etc.) were calculated from a high-resolution emission inventory. Then emission fluxes were mapped on surfaces emitting source-specific species. Simulations were run independently over the defined micro-environments allowing the modeling of sub grid-scale concentration variability. Sub grid scale concentrations were therefore combined with demographic and human activity data to provide exposure estimates. The spatial distribution of human exposure was parameterized through a Monte-Carlo model. The new information concerning exposure variability was added to an existing epidemiological model to study relative health risks. A log-linear Poisson regression model was used for this purpose. The principal outcome of the investigation was that a new functionality was added to the regression model which allows the dissociation of the health risk associated with each pollutant (e.g. NO{sub 2} and PM{sub 2.5}). (author)

  13. Biomonitoring of air quality in the Cologne conurbation using pine needles as a passive sampler—Part I: magnetic properties

    Science.gov (United States)

    Urbat, M.; Lehndorff, E.; Schwark, L.

    High resolution temporal and spatial control of atmospheric pollutants is of crucial importance for environmental health monitoring. Passive sampling using natural vegetation biomonitoring allows acquisition of well-defined samples at affordable costs. We here present results from a study conducted in the conurbation of Cologne, Germany, based on airborne pollutants accumulated on pine needles. This integrated study includes (i) the microscopic analysis of pine needles and analysis of their magnetic properties, (ii) PAH, and (iii) selected trace elements (Fe, Cd, Pb, Ni, Cr, Cu). A major proportion of atmospheric pollutants is bound to particles, for which in part I of the study we present data on magnetic susceptibility, remanence measurements (IRM, ARM) and total Fe content. SEM-analysis indicates that particles accumulated on needles are mostly brake-wear and from railroad and tram traffic preferentially due to material wear. Parks, forests and agricultural areas show the lowest levels of pollution by magnetic particles, followed by residential areas. This implies that traffic emissions with short transportation distances (<1.0 km) are dominant in the Cologne conurbation, whereas the contribution from power plants is negligible.

  14. Pollution

    NARCIS (Netherlands)

    Dürr, E.; Jaffe, R.; Nonini, D.M.

    2014-01-01

    This essay points to the role of pollution in understanding the social construction of hierarchies and urban space. Conceptualizations of pollution and approaches to waste management always reflect the Zeitgeist and tend to be politically charged. We argue that an ethnographic approach to pollution

  15. Identifying the origin of atmospheric inputs of trace elements in the Prades Mountains (Catalonia) with bryophytes, lichens, and soil monitoring.

    Science.gov (United States)

    Achotegui-Castells, Ander; Sardans, Jordi; Ribas, Àngela; Peñuelas, Josep

    2013-01-01

    The biomonitors Hypnum cupressiforme and Xanthoria parietina were used to assess the deposition of trace elements and their possible origin in the Prades Mountains, a protected Mediterranean forest area of NE Spain with several pollution sources nearby. Al, As, Cd, Co, Cu, Cr, Ni, Pb, Sb, Ti, V, and Zn were determined in 16 locations within this protected area. Soil trace element concentrations were also ascertained to calculate enrichment factors (EF) and use them to distinguish airborne from soilborne trace element inputs. In addition, lichen richness was measured to further assess atmospheric pollution. EF demonstrated to be useful not only for the moss but also for the lichen. Cd, Cr, Cu, Ni, and Zn presented values higher than three in both biomonitors. These trace elements were also the main ones emitted by the potential sources of pollutants. The distance between sampling locations and potential pollution sources was correlated with the concentrations of Cu, Sb, and Zn in the moss and with Cr, Ni, and Sb in the lichen. Lichen richness was negatively correlated with lichen Cu, Pb, and V concentrations on dry weight basis. The study reflected the remarkable influence that the pollution sources have on the presence of trace elements and on lichen species community composition in this natural area. The study highlights the value of combining the use of biomonitors, enrichment factors, and lichen diversity for pollution assessment to reach a better overview of both trace elements' impact and the localization of their sources.

  16. A Review of Atmospheric Chemistry Research in China: Photochemical Smog, Haze Pollution, and Gas-Aerosol Interactions

    Institute of Scientific and Technical Information of China (English)

    MA Jianzhong; XU Xiaobin; ZHAO Chunsheng; YAN Peng

    2012-01-01

    In this paper we present a review of atmospheric chemistry research in China over the period 2006-2010,focusing on tropospheric ozone,aerosol chemistry,and the interactions between trace gases and aerosols in the polluted areas of China.Over the past decade,China has suffered severe photochemical smog and haze pollution,especially in North China,the Yangtze River Delta,and the Pearl River Delta.Much scientific work on atmospheric chemistry and physics has been done to address this large-scale,complex environmental problem.Intensive field experiments,satellite data analyses,and model simulations have shown that air pollution is significantly changing the chemical and physical characters of the natural atmosphere over these parts of China.In addition to strong emissions of primary pollutants,photochemical and heterogeneous reactions play key roles in the formation of complex pollution.More in-depth research is recommended to reveal the formation mechanism of photochemical smog and haze pollution and their climatic effects at the urban,regional,and global scales.

  17. Forecasting human exposure to atmospheric pollutants in Portugal - A modelling approach

    Science.gov (United States)

    Borrego, C.; Sá, E.; Monteiro, A.; Ferreira, J.; Miranda, A. I.

    2009-12-01

    Air pollution has become one main environmental concern because of its known impact on human health. Aiming to inform the population about the air they are breathing, several air quality modelling systems have been developed and tested allowing the assessment and forecast of air pollution ambient levels in many countries. However, every day, an individual is exposed to different concentrations of atmospheric pollutants as he/she moves from and to different outdoor and indoor places (the so-called microenvironments). Therefore, a more efficient way to prevent the population from the health risks caused by air pollution should be based on exposure rather than air concentrations estimations. The objective of the present study is to develop a methodology to forecast the human exposure of the Portuguese population based on the air quality forecasting system available and validated for Portugal since 2005. Besides that, a long-term evaluation of human exposure estimates aims to be obtained using one-year of this forecasting system application. Additionally, a hypothetical 50% emission reduction scenario has been designed and studied as a contribution to study emission reduction strategies impact on human exposure. To estimate the population exposure the forecasting results of the air quality modelling system MM5-CHIMERE have been combined with the population spatial distribution over Portugal and their time-activity patterns, i.e. the fraction of the day time spent in specific indoor and outdoor places. The population characterization concerning age, work, type of occupation and related time spent was obtained from national census and available enquiries performed by the National Institute of Statistics. A daily exposure estimation module has been developed gathering all these data and considering empirical indoor/outdoor relations from literature to calculate the indoor concentrations in each one of the microenvironments considered, namely home, office/school, and other

  18. The heavily polluted atmosphere of the DAZ white dwarf GALEX J193156.8+011745

    CERN Document Server

    Vennes, S; Nemeth, P

    2010-01-01

    We report on the discovery of a new heavily polluted white dwarf. The DAZ white dwarf GALEX J193156.8+011745 was identified in a joint GALEX/GSC survey of ultraviolet-excess objects. Optical spectra obtained at ESO NTT show strong absorption lines of magnesium and silicon and a detailed abundance analysis based on VLT-Kueyen UVES spectra reveal super-solar abundances of silicon and magnesium, and near-solar abundances of oxygen, calcium, and iron. The overall abundance pattern bears the signature of ongoing accretion onto the white dwarf atmosphere. The infrared spectral energy distribution shows an excess in the H and K bands likely associated with the accretion source.

  19. Source apportionment of atmospheric mercury pollution in China using the GEOS-Chem model.

    Science.gov (United States)

    Wang, Long; Wang, Shuxiao; Zhang, Lei; Wang, Yuxuan; Zhang, Yanxu; Nielsen, Chris; McElroy, Michael B; Hao, Jiming

    2014-07-01

    China is the largest atmospheric mercury (Hg) emitter in the world. Its Hg emissions and environmental impacts need to be evaluated. In this study, China's Hg emission inventory is updated to 2007 and applied in the GEOS-Chem model to simulate the Hg concentrations and depositions in China. Results indicate that simulations agree well with observed background Hg concentrations. The anthropogenic sources contributed 35-50% of THg concentration and 50-70% of total deposition in polluted regions. Sensitivity analysis was performed to assess the impacts of mercury emissions from power plants, non-ferrous metal smelters and cement plants. It is found that power plants are the most important emission sources in the North China, the Yangtze River Delta (YRD) and the Pearl River Delta (PRD) while the contribution of non-ferrous metal smelters is most significant in the Southwest China. The impacts of cement plants are significant in the YRD, PRD and Central China.

  20. A study of atmospheric diffusion from the LANDSAT imagery. [pollution transport over the ocean

    Science.gov (United States)

    Dejesusparada, N. (Principal Investigator); Viswanadham, Y.; Torsani, J. A.

    1981-01-01

    LANDSAT multispectral scanner data of the smoke plumes which originated in eastern Cabo Frio, Brazil and crossed over into the Atlantic Ocean, are analyzed to illustrate how high resolution LANDSAT imagery can aid meteorologists in evaluating specific air pollution events. The eleven LANDSAT images selected are for different months and years. The results show that diffusion is governed primarily by water and air temperature differences. With colder water, low level air is very stable and the vertical diffusion is minimal; but water warmer than the air induces vigorous diffusion. The applicability of three empirical methods for determining the horizontal eddy diffusivity coefficient in the Gaussian plume formula was evaluated with the estimated standard deviation of the crosswind distribution of material in the plume from the LANDSAT imagery. The vertical diffusion coefficient in stable conditions is estimated using Weinstock's formulation. These results form a data base for use in the development and validation of meso scale atmospheric diffusion models.

  1. An evaluation of atmospheric Nr pollution and deposition in North China after the Beijing Olympics

    Science.gov (United States)

    Luo, X. S.; Liu, P.; Tang, A. H.; Liu, J. Y.; Zong, X. Y.; Zhang, Q.; Kou, C. L.; Zhang, L. J.; Fowler, D.; Fangmeier, A.; Christie, P.; Zhang, F. S.; Liu, X. J.

    2013-08-01

    North China is known for its large population densities and rapid development of industry and agriculture. Air quality around Beijing improved substantially during the 2008 Summer Olympics. We measured atmospheric concentrations of various Nr compounds at three urban sites and three rural sites in North China from 2010 to 2012 and estimated N dry and wet deposition by inferential models and the rain gauge method to determine current air conditions with respect to reactive nitrogen (Nr) compounds and nitrogen (N) deposition in Beijing and the surrounding area. NH3, NO2, and HNO3 and particulate NH4+ and NO3-, and NH4+-N and NO3--N in precipitation averaged 8.2, 11.5, 1.6, 8.2 and 4.6 μg N m-3, and 2.9 and 1.9 mg N L-1, respectively, with large seasonal and spatial variability. Atmospheric Nr (especially oxidized N) concentrations were highest at urban sites. Dry deposition of Nr ranged from 35.2 to 60.0 kg N ha-1 yr-1, with wet deposition of Nr of 16.3 to 43.2 kg N ha-1 yr-1 and total deposition of 54.4-103.2 kg N ha-1 yr-1. The rates of Nr dry and wet deposition were 36.4 and 33.2% higher, respectively, at the urban sites than at the rural sites. These high levels reflect the occurrence of a wide range of Nr pollution in North China and suggest that further strict air pollution control measures are required.

  2. The automated system of detection and research of pollution in the atmosphere

    Science.gov (United States)

    Isakova, Anna I.; Smal, Oksana V.; Chistyakova, Liliya K.; Penin, Sergei T.

    2004-02-01

    In the paper, the automated system of data processing (ASDP) for a hardware complex DAN-2, assigned for registration of emission and absorption of optical and the microwave radiation initiated by gas-aerosol pollution in the atmosphere, is presented. The complex DAN-2 has been developed in the Institute of Atsmospheric Optics of the Siberian Branch of the Russian Academy of Science. In the ASDP, a problem of automation of recording processes, storage and processing of the information measured in experiment has been solved. Using in ASDP subsystems of the forecast of optical noise, the forecast of distribution of an impurity in a plume of gas-aerosol emission from industrial plants allows us to carry out the express-analysis of ecological pollution in the inspection zone. Application of a modular principle has created an opportunity to realize all subsystems ASPD independently from each other, thus, they can operate as independently, and in the general complex of programs. As a tool for creation of the system software, the object-oriented instrument of programming Delphi 5.0 has been chosen. It has a number of advantages and distinctive features such as the convenient graphic interface with displaying of calculation results as uniform scrolling tables and graphics, access to the data files, high speed of mathematical calculations, an opportunity of the further expansion and change of the calculation algorithms. Use of the ASPD has allowed us to improve quality of data recording, their processing, and visualization of the processed results. For the first time in the automated system, the complex estimation of ecological situation with use of experimental data in real time has been realized. The ASPD can be used also by other experimental equipment intended for the solution of problems of the atmospheric optics.

  3. The use of mosses in air pollution monitoring in Estonia

    Energy Technology Data Exchange (ETDEWEB)

    Liiv, S.; Eensaar, A. [Academy of Sciences of Estonia, Tallinn (Estonia). Tallinn Botanic Garden

    1995-12-31

    Mosses Pleurozium schreberi and Hylocomium splendens have been proposed as biomonitors of atmospheric heavy metals. These mosses are wide-used in biomonitoring studies in Scandinavia as well as in other Nordic countries. Some methodical problems of bryoindication, e.g. other factors than the adsorption of precipitation which influence element concentrations in mosses have been studied in Scandinavia as well. Methodical study for determining the intrasite, local variability in Estonia was started in 1991. Despite of the used uniform methodics in sampling, cleaning, digesting and chemical analysing of moss samples in the same laboratory there is high variability of the content of elements at the reference area. There are many reasons for this variability - errors from instrumental procedures (analytical steps in chemical analysing), biological deviation, etc. In this article the results of the methodical study of intrasite variability of As, Cd, Cr, Cu, Fe, Ni, Pb, Zn and V in mosses at reference areas of different deposition level in Estonia are presented. The intrasite variability of elemental content in mosses at the reference areas is taken into account in mapping the territorial distribution of the content of elements in mosses, samples of which were collected during the joint Finnish-Estonian-Russian biomonitoring project in 1992 in a more dense network compared with the 1989 and 1990 national moss surveys in Estonia in order to describe more accurately the pollution situation in highly polluted north-eastern Estonia

  4. Use of the lichen Xanthoria mandschurica in monitoring atmospheric elemental deposition in the Taihang Mountains, Hebei, China

    Science.gov (United States)

    Liu, Hua-Jie; Zhao, Liang-Cheng; Fang, Shi-Bo; Liu, Si-Wa; Hu, Jian-Sen; Wang, Lei; Liu, Xiao-Di; Wu, Qing-Feng

    2016-04-01

    Air pollution is a major concern in China. Lichens are a useful biomonitor for atmospheric elemental deposition but have rarely been used in North China. The aim of this study was to investigate the atmospheric depositions of 30 trace elements (Al, Ba, Ca, Cd, Ce, Co, Cr, Cs, Cu, Fe, K, La, Mg, Mn, Mo, Na, Ni, P, Pb, Rb, Sb, Sc, Sm, Sr, Tb, Th, Ti, Tl, V and Zn) in a region of the Taihang Mountains, Hebei Province, China using lichens as biomonitors. Epilithic foliose lichen Xanthoria mandschurica was sampled from 21 sites and analyzed using inductively coupled plasma mass spectrometry (ICP-MS). The results show that 1) eight elements (Cd, Cr, Cu, Mo, P, Pb, Sb and Zn) are of atmospheric origin and are highly influenced by the atmospheric transportation from the North China Plain, as well as local mining activities, while 2) the remaining 22 elements are primarily of crustal origin, the concentration of which has been enhanced by local mining and quarrying activities. These results clearly validate the applicability of lichens in biomonitoring of atmospheric elemental deposition and demonstrate the spatial pattern for air pollution in the region.

  5. Lead chromate detected as a source of atmospheric Pb and Cr (VI) pollution

    Science.gov (United States)

    Lee, Pyeong-Koo; Yu, Soonyoung; Chang, Hye Jung; Cho, Hye Young; Kang, Min-Ju; Chae, Byung-Gon

    2016-10-01

    Spherical black carbon aggregates were frequently observed in dust dry deposition in Daejeon, Korea. They were tens of micrometers in diameter and presented a mixture of black carbon and several mineral phases. Transmission electron microscopy (TEM) observations with energy-dispersive X-ray spectroscopy (EDS) and selected area diffraction pattern (SADP) analyses confirmed that the aggregates were compact and included significant amounts of lead chromate (PbCrO4). The compositions and morphologies of the nanosized lead chromate particles suggest that they probably originated from traffic paint used in roads and were combined as discrete minerals with black carbon. Based on Pb isotope analysis and air-mass backward trajectories, the dust in Daejeon received a considerable input of anthropogenic pollutants from heavily industrialized Chinese cities, which implies that long-range transported aerosols containing PbCrO4 were a possible source of the lead and hexavalent chromium levels in East Asia. Lead chromate should be considered to be a source of global atmospheric Pb and Cr(VI) pollution, especially given its toxicity.

  6. Long Term Atmospheric and Erosional Pollution As Recorded in Lake Sediments from Yunnan, China

    Science.gov (United States)

    Hillman, A. L.; Abbott, M. B.; Yu, J.; Bain, D.; Chiou-Peng, T.

    2014-12-01

    Human activities including agriculture, metallurgy (e.g. mining, processing, smelting), and deforestation have altered cycles of erosion and sedimentation in lake environments for thousands of years. In the Yunnan province of southwestern China, where written records are incomplete, it is unclear when, where, and how much disturbance occurred. Lake sediments offer a means to investigate a wide variety of human activities. Here, we present a lake sediment record from Erhai (25°43'N, 100°12'E) based on trace metal concentrations that reveals substantial atmospheric and erosional pollution to the lake environment over the last 4,000 years. Sediments indicate the initiation of copper-based metallurgy at 3,600 years BP, the existence of which has been debated amongst archaeologists. Beginning 2,000 years BP, sedimentation rates increase and concentrations of metals such as aluminum, titanium, lead, and zinc increase. This is likely linked to increased sediment flux to the lake associated with the initiation of terraced agriculture according to historical documents. The most prominent feature of the record is an abrupt and intense increase in lead, silver, cadmium, and zinc beginning at 700 years BP. The peak of this increase occurs at 600 years BP and is consistent with historical records that the Mongols established the first government operated silver mine in Yunnan. Notably, the concentrations of lead during this time are an order of magnitude greater than modern day levels of pollution.

  7. Extreme abundance ratios in the polluted atmosphere of the cool white dwarf NLTT19868

    CERN Document Server

    Kawka, Adela

    2016-01-01

    We present an analysis of intermediate-dispersion spectra and photometric data of the newly identified cool, polluted white dwarf NLTT19868. The spectra obtained with X-shooter on the Very Large Telescope (VLT)-Melipal show strong lines of calcium, and several lines of magnesium, aluminium and iron. We use these spectra and the optical-to-near infrared spectral energy distribution to constrain the atmospheric parameters of NLTT19868. Our analysis shows that NLTT19868 is iron poor with respect to aluminium and calcium. A comparison with other cool, polluted white dwarfs shows that the Fe to Ca abundance ratio (Fe/Ca) varies by up to approximately two orders of magnitudes over a narrow temperature range with NLTT19868 at one extremum in the Fe/Ca ratio and, in contrast, NLTT888 at the other extremum. The sample shows evidence of extreme diversity in the composition of the accreted material: In the case of NLTT888, the inferred composition of the accreted matter is akin to iron-rich planetary core composition, w...

  8. Quantifying the effects of China's pollution control on atmospheric mercury emissions

    Science.gov (United States)

    Zhong, H.

    2014-12-01

    China has conducted series of air pollution control policies to reduce the pollutant emissions. Although not specifically for mercury (Hg), those policies are believed to have co-benefits on atmospheric Hg emission control. On the basis of field-tests data and updated information of energy conservation and emission control, we have developed multiple-year inventories of anthropogenic mercury emissions in China from 2005 to 2012. Three scenarios (scenario 0(S0), scenario 1(S1), scenario 2(S2)) with different emission controls and energy path are designed for prediction of the future Hg emissions for the country. In particular, comprehensive assessments has been conducted to evaluate the evolution of emission factors, recent emission trends, effects of control measures as well as the reliability of our results. The national total emissions of anthropogenic Hg are estimated to increase from 679.0 metric tons (t) in 2005 to 749.8 t in 2012, with the peak at 770.6 t in 2011. The annual growth rate of emissions can then be calculated at 2.1% during 2005-2011, much lower than that of energy consumption or economy of the country. Coal combustion, gold metallurgy and nonferrous metal smelting are the most significant Hg sources of anthropogenic origin, accounting together for 85% of national total emissions. Tightened air pollution controls in China should be important reasons for the smooth emission trends. Compared with 2005, 299 t Hg were reduced in 2010 from power plants, iron and steel smelting, nonferrous-smelting and cement production, benefiting from the improvement of control measures for those sectors. The speciation of Hg emissions is relatively stable for recent years, with the mass fractions of around 55%, 9% and 6% for Hg0, Hg2+ and Hgp respectively. Integrating the policy commitments on energy saving, different from the most conservative case S0, S2 shares the same energy path with S1, but includes more stringent emission control. Under those scenarios, we

  9. Reproductive effects in hybrid sparrow from a polluted area in Tunisia: Oxidative damage and altered testicular histomorphology.

    Science.gov (United States)

    Amri, Nahed; Hammouda, Abdessalem; Rahmouni, Fatma; Chokri, Med Ali; Chaabane, Rim; Selmi, Slaheddine; Rebai, Tarek; Badraoui, Riadh

    2016-07-01

    Air pollution is a threat for human health and wildlife. The aim of this study is to assess the pathophysiological changes and the oxidative-antioxidative status in testicular tissues of 40 Hybrid sparrows collected from four areas in Gabès city, one of the most polluted areas in Tunisia. The testis histopathological analysis revealed alterations in birds from Ghannouche, the polluted area. The thiobarbituric acid reactive substance (TBARS) levels were higher in testis of birds from the contaminated site compared to less polluted areas indicating oxidative damage to membrane lipids. Antioxidant enzyme activities (superoxide dismutase and catalase) were lower in testis sparrows from the polluted site compared with the reference site, suggesting deficiency of the antioxidant system to compensate for oxidative stress. Overall, our results suggest that the hybrid sparrow offers a suitable model for biomonitoring programs of atmosphere pollutants and the selected biomarkers could be useful tool to evaluate pollution impacts in living organisms.

  10. Composition of thermodestruction products of biologically active compounds polluting the atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Dmitriyev, M.T.; Rastyannikov, Y.G.; Sotnikov, Y.Y.; Volkov, S.A.

    1981-01-01

    The most promising method of removal of biologically active compounds such as microorganisms, antibiotics, food and other household waste from industrial waste gases is to destroy them by thermal destruction including burning. In this case, products of thermodestruction enter into the atmosphere along with carbon dioxide and steam and can unfavorably affect the population. Thus, mass spectrometric analyses have determined in the waste gases of antibiotics production aldehydes and ketones (croton- and adipalaldehydes, acetone), alcohols (propanol and butanol), amines, unsaturated and aromatic hydrocarbons. The composition of thermodestruction products of biologically active compounds was identified by their pyrolysis at 700/sup 0/C for 2 min. in the presence of air. The main components were proteins and amino acids. The products of pyrolysis were analyzed by chromato-mass-spectrometric and gas-chromatographic methods by means of a two-flame thermionic detector. No significant difference between the thermodestruction products of proteins and amino acids was found. Many of detected substances can be not only toxic but also emit strong unpleasant odors. The studies revealed toxic substances that pollute the atmospheric air during removal of biologically-active compounds from waste gases.

  11. Atmospheric electric field measurements in urban environment and the pollutant aerosol weekly dependence

    Science.gov (United States)

    Silva, H. G.; Conceição, R.; Melgão, M.; Nicoll, K.; Mendes, P. B.; Tlemçani, M.; Reis, A. H.; Harrison, R. G.

    2014-11-01

    The weekly dependence of pollutant aerosols in the urban environment of Lisbon (Portugal) is inferred from the records of atmospheric electric field at Portela meteorological station (38°47‧N, 9°08‧W). Measurements were made with a Bendorf electrograph. The data set exists from 1955 to 1990, but due to the contaminating effect of the radioactive fallout during 1960 and 1970s, only the period between 1980 and 1990 is considered here. Using a relative difference method a weekly dependence of the atmospheric electric field is found in these records, which shows an increasing trend between 1980 and 1990. This is consistent with a growth of population in the Lisbon metropolitan area and consequently urban activity, mainly traffic. Complementarily, using a Lomb-Scargle periodogram technique the presence of a daily and weekly cycle is also found. Moreover, to follow the evolution of theses cycles, in the period considered, a simple representation in a colour surface plot representation of the annual periodograms is presented. Further, a noise analysis of the periodograms is made, which validates the results found. Two datasets were considered: all days in the period, and fair-weather days only.

  12. Atmospheric pollutants in fog and rain events at the northwestern mountains of the Iberian Peninsula

    Energy Technology Data Exchange (ETDEWEB)

    Fernández-González, Ricardo; Yebra-Pimentel, Iria; Martínez-Carballo, Elena [Nutrition and Bromatology Group, Analytical and Food Chemistry Department, Faculty of Food Science and Technology, University of Vigo, Ourense Campus, E32004 Ourense (Spain); Simal-Gándara, Jesús, E-mail: jsimal@uvigo.es [Nutrition and Bromatology Group, Analytical and Food Chemistry Department, Faculty of Food Science and Technology, University of Vigo, Ourense Campus, E32004 Ourense (Spain); Pontevedra-Pombal, Xabier, E-mail: xabier.pombal@usc.es [Soil Science and Agricultural Chemistry Department, Faculty of Biology, University of Santiago de Compostela, Santiago Campus, E15782 Santiago de Compostela (Spain)

    2014-11-01

    Atmospheric polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) are persistent organic pollutants (POPs) and exist in gas and particle phases, as well as dissolved or suspended in precipitation (fog or rain). While the hydrosphere is the main reservoir for PAHs, the atmosphere serves as the primary route for global transport of PCBs. In this study, fog and rain samples were collected during fourteen events from September 2011 to April 2012 in the Xistral Mountains, a remote range in the NW Iberian Peninsula. PAH compounds [especially of low molecular weight (LMW)] were universally found, but mainly in the fog-water samples. The total PAH concentration in fog-water ranged from non-detected to 216 ng · L{sup −1} (mean of 45 ng · L{sup −1}), and was much higher in fall than in winter. Total PAH levels in the rain and fog events varied from non-detected to 1272 and 33 ng · L{sup −1} for, respectively, LMW and high molecular weight (HMW) PAHs. Diagnostic ratio analysis (LMW PAHs/HMW PAHs) suggested that petroleum combustion was the dominant contributor to PAHs in the area. Total PCB levels in the rain and fog events varied from non-detected to 305 and 91 ng · L{sup −1} for, respectively, PCBs with 2–3 Cl atoms and 5–10 Cl atoms. PCBs, especially those with 5–10 Cl atoms, were found linked to rain events. The occurrence of the most volatile PCBs, PCBs with 2–3 Cl atoms, is related to wind transport from far away sources, whereas the occurrence of PCBs with 5–10 Cl atoms seems to be related with the increase of its deposition during rainfall at the end of summer and fall. The movement of this fraction of PCBs is facilitated by its binding to air-suspended particles, whose concentrations usually show an increase as the result of a prolonged period of drought in summer. - Highlights: • There is no work about both PAHs and PCBs in fog-rain events. • None of the existing works is about the case of the northwestern mountains

  13. Air pollution tracer studies in the lower atmosphere. (Latest citations from the NTIS bibliographic database). Published Search

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-05-01

    The bibliography contains citations concerning the use of tracers to study lower atmospheric air pollution movements. Citations discuss project descriptions and results, techniques, and tracer materials. Tracer movement from nuclear power plants, industrial stacks, and urban areas is discussed. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  14. Serum proteins behavior in the urban population from a center with a lead-polluted atmospheric environment

    Energy Technology Data Exchange (ETDEWEB)

    Casin, I.; Ghelberg, N.W.

    1974-01-01

    Serum protein behavior was determined in an urban population from a center with a lead polluted atmospheric environment. The following increased amounts of serum proteins are found in 94 adult subjects: haptoglobin 75 percent; ceruloplasmin and transferrin 55 percent; IgA (immunoglobulin A) and IgG 40 percent; Igm and beta lc proteins 25 percent.

  15. The effect of nitrogen additions on oak foliage and herbivore communities at sites with high and low atmospheric pollution

    Energy Technology Data Exchange (ETDEWEB)

    Eatough Jones, Michele [Department of Entomology, University of California Riverside, Riverside, CA 92521 (United States)], E-mail: michele.eatough@ucr.edu; Paine, Timothy D. [Department of Entomology, University of California Riverside, Riverside, CA 92521 (United States); Fenn, Mark E. [USDA, Forest Service, Pacific Southwest Research Station, Forest Fire Laboratory, 4955 Canyon Crest Drive. Riverside, CA 92507 (United States)

    2008-02-15

    To evaluate plant and herbivore responses to nitrogen we conducted a fertilization study at a low and high pollution site in the mixed conifer forests surrounding Los Angeles, California. Contrary to expectations, discriminant function analysis of oak herbivore communities showed significant response to N fertilization when atmospheric deposition was high, but not when atmospheric deposition was low. We hypothesize that longer-term fertilization treatments are needed at the low pollution site before foliar N nutrition increases sufficiently to affect herbivore communities. At the high pollution site, fertilization was also associated with increased catkin production and higher densities of a byturid beetle that feeds on the catkins of oak. Leaf nitrogen and nitrate were significantly higher at the high pollution site compared to the low pollution site. Foliar nitrate concentrations were positively correlated with abundance of sucking insects, leafrollers and plutellids in all three years of the study. - Nitrogen additions at sites impacted by air pollution were associated with altered foliar herbivore communities and increased densities of a catkin-feeding beetle on Quercus kellogii.

  16. Current and future levels of mercury atmospheric pollution on a global scale

    Science.gov (United States)

    Pacyna, Jozef M.; Travnikov, Oleg; De Simone, Francesco; Hedgecock, Ian M.; Sundseth, Kyrre; Pacyna, Elisabeth G.; Steenhuisen, Frits; Pirrone, Nicola; Munthe, John; Kindbom, Karin

    2016-10-01

    An assessment of current and future emissions, air concentrations, and atmospheric deposition of mercury worldwide is presented on the basis of results obtained during the performance of the EU GMOS (Global Mercury Observation System) project. Emission estimates for mercury were prepared with the main goal of applying them in models to assess current (2013) and future (2035) air concentrations and atmospheric deposition of this contaminant. The combustion of fossil fuels (mainly coal) for energy and heat production in power plants and in industrial and residential boilers, as well as artisanal and small-scale gold mining, is one of the major anthropogenic sources of Hg emissions to the atmosphere at present. These sources account for about 37 and 25 % of the total anthropogenic Hg emissions globally, estimated to be about 2000 t. Emissions in Asian countries, particularly in China and India, dominate the total emissions of Hg. The current estimates of mercury emissions from natural processes (primary mercury emissions and re-emissions), including mercury depletion events, were estimated to be 5207 t year-1, which represents nearly 70 % of the global mercury emission budget. Oceans are the most important sources (36 %), followed by biomass burning (9 %). A comparison of the 2035 anthropogenic emissions estimated for three different scenarios with current anthropogenic emissions indicates a reduction of these emissions in 2035 up to 85 % for the best-case scenario. Two global chemical transport models (GLEMOS and ECHMERIT) have been used for the evaluation of future mercury pollution levels considering future emission scenarios. Projections of future changes in mercury deposition on a global scale simulated by these models for three anthropogenic emissions scenarios of 2035 indicate a decrease in up to 50 % deposition in the Northern Hemisphere and up to 35 % in Southern Hemisphere for the best-case scenario. The EU GMOS project has proved to be a very important

  17. Is Distant Pollution Contaminating Local Air? Analyzing the Origins of Atmospheric Aerosols

    Directory of Open Access Journals (Sweden)

    David Geng

    2012-01-01

    Full Text Available Understanding the origin of aerosols in the atmosphere is important because of visual pollution, climate impacts, and deleterious health effects due to the inhalation of fine particles. This research analyzed aerosols characterized by their chloride, sulfate, and nitrate content as a function of size over a 3-month period. Due to wind patterns over coal-burning power plants, a higher concentration of local sulfate pollution was expected. Aerosols were harvested on the Purdue University campus using a high-volume air sampler with glass fiber filters and a five-stage impactor that separates the aerosols into five sizes. The filters were extracted in water to dissolve anions and the solution was analyzed using high-pressure liquid ion chromatography. Only trace amounts of chloride with no distinct patterns in size were detected. In total, nitrate content ranged from 0.12 to 2.10 μg/m3 and sulfate content ranged from 0.44 to 6.45 μg/m3 over a 3-month period. As for fine particles, a higher concentration of sulfate was observed. The Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT model determines air mass origin, and in this study, higher total sulfate content was observed when the air mass moved out of the southwest, and higher total nitrate content was observed when the air mass originated from the southeast. The author concluded that small particles resulted in sulfate from sulfur dioxide, typically from gas to particle conversion. High sulfur dioxide levels are directly correlated with coal-burning power plant density. Small particulate sulfate found in West Lafayette, Indiana, was determined to originate primarily from power plants in southwest Indiana. Though the results do show a significant amount of potentially harmful aerosols in West Lafayette, there is still further research to be done concerning isotopic composition of those particles in attempts to better explain the chemical pathways.

  18. 60 years of UK visibility measurements: impact of meteorology and atmospheric pollutants on visibility

    Science.gov (United States)

    Singh, Ajit; Bloss, William J.; Pope, Francis D.

    2017-02-01

    Reduced visibility is an indicator of poor air quality. Moreover, degradation in visibility can be hazardous to human safety; for example, low visibility can lead to road, rail, sea and air accidents. In this paper, we explore the combined influence of atmospheric aerosol particle and gas characteristics, and meteorology, on long-term visibility. We use visibility data from eight meteorological stations, situated in the UK, which have been running since the 1950s. The site locations include urban, rural and marine environments. Most stations show a long-term trend of increasing visibility, which is indicative of reductions in air pollution, especially in urban areas. Additionally, the visibility at all sites shows a very clear dependence on relative humidity, indicating the importance of aerosol hygroscopicity on the ability of aerosol particles to scatter radiation. The dependence of visibility on other meteorological parameters, such as wind speed and wind direction, is also investigated. Most stations show long-term increases in temperature which can be ascribed to climate change, land-use changes (e.g. urban heat island effects) or a combination of both; the observed effect is greatest in urban areas. The impact of this temperature change upon local relative humidity is discussed. To explain the long-term visibility trends and their dependence on meteorological conditions, the measured data were fitted to a newly developed light-extinction model to generate predictions of historic aerosol and gas scattering and absorbing properties. In general, an excellent fit was achieved between measured and modelled visibility for all eight sites. The model incorporates parameterizations of aerosol hygroscopicity, particle concentration, particle scattering, and particle and gas absorption. This new model should be applicable and is easily transferrable to other data sets worldwide. Hence, historical visibility data can be used to assess trends in aerosol particle

  19. Reduction of air pollutants - a tool for control of atmospheric corrosion

    Directory of Open Access Journals (Sweden)

    Kucera, V.

    2003-12-01

    Full Text Available In most urban areas in Europe and Northern America serious corrosion impacts on buildings and cultural monuments have been caused by emissions of pollutants. The rapidly increasing pollution levels in many of the developing countries also exert a serious threat to materials. Beside the very important role of SO2 also the direct or synergistic effect of NOx and O3, the particulates and rain acidity may contribute in an important way to materials degradation. Results from extensive international field exposure programs i.e. within the UN/ECE have enabled development of dose-response relations which describe the effect of dry and wet deposition of pollutants on corrosion of different material groups. In most of the industrialized countries decreasing trends of sulphur and nitrogen pollutants and of acidity of precipitation have resulted in decreased corrosion rates. The concept of acceptable levels of pollutants is a useful tool in planning of abatement strategies and for defining of conditions for a suitable development in the field of corrosion of constructions in the atmosphere.

    La contaminación de la atmósfera ha sido la principal razón del grave deterioro de las edificaciones y de los monumentos en numerosas ciudades de Europa y Norteamérica. De otro lado, el acelerado incremento de los niveles de contaminación en los países menos desarrollados está poniendo en peligro la estabilidad de los materiales utilizados. Además del importante papel que en este sentido juega el SO2, la acción directa o el efecto sinérgico de los NOx y el O3, al igual que el material particulado y las lluvias acidas contribuyen a agravar el problema. Resultados de vastos programas internacionales de investigación como, por ejemplo, el UN/ECE, han permitido desarrollar relaciones dosis-respuesta que describen el efecto de la deposición de los contaminantes sobre la corrosión de

  20. Modeling and evaluation of urban pollution events of atmospheric heavy metals from a large Cu-smelter.

    Science.gov (United States)

    Chen, Bing; Stein, Ariel F; Castell, Nuria; Gonzalez-Castanedo, Yolanda; Sanchez de la Campa, A M; de la Rosa, J D

    2016-01-01

    Metal smelting and processing are highly polluting activities that have a strong influence on the levels of heavy metals in air, soil, and crops. We employ an atmospheric transport and dispersion model to predict the pollution levels originated from the second largest Cu-smelter in Europe. The model predicts that the concentrations of copper (Cu), zinc (Zn), and arsenic (As) in an urban area close to the Cu-smelter can reach 170, 70, and 30 ng m−3, respectively. The model captures all the observed urban pollution events, but the magnitude of the elemental concentrations is predicted to be lower than that of the observed values; ~300, ~500, and ~100 ng m−3 for Cu, Zn, and As, respectively. The comparison between model and observations showed an average correlation coefficient of 0.62 ± 0.13. The simulation shows that the transport of heavy metals reaches a peak in the afternoon over the urban area. The under-prediction in the peak is explained by the simulated stronger winds compared with monitoring data. The stronger simulated winds enhance the transport and dispersion of heavy metals to the regional area, diminishing the impact of pollution events in the urban area. This model, driven by high resolution meteorology (2 km in horizontal), predicts the hourly-interval evolutions of atmospheric heavy metal pollutions in the close by urban area of industrial hotspot.

  1. Possible influence of atmospheric circulations on winter hazy pollution in Beijing-Tianjin-Hebei region, northern China

    Directory of Open Access Journals (Sweden)

    Z. Zhang

    2015-08-01

    Full Text Available Using the daily records derived from the synoptic weather stations and the NCEP/NCAR and ERA-Interim reanalysis data, the variability of the winter hazy pollutions (indicated by the mean visibility and number of hazy days in Beijing-Tianjin-Hebei (BTH region during the period 1981 to 2015 and its relationship to the atmospheric circulations in middle-high latitude were analyzed in this study. The winter hazy pollution in BTH had distinct inter-annual and inter-decadal variabilities without a significant long-term trend. According to the spatial distribution of correlation coefficients, six atmospheric circulation indices (I1 to I6 were defined from the key areas in sea level pressure (SLP, zonal and meridional winds at 850 hPa (U850, V850, geopotential height field at 500 hPa (H500, zonal wind at 200 hPa (U200, and air temperature at 200 hPa (T200, respectively. All of the six indices have significant and stable correlations with the winter visibility and number of hazy days in BTH. Both the visibility and number of hazy days can be estimated well by using the six indices and fitting and the cross-validation with leave-N-out method, respectively. The high level of the prediction statistics and the reasonable mechanism suggested that the winter hazy pollutions in BTH can be forecasted or estimated credibly based on the optimized atmospheric circulation indices. However, we also noted that the statistic estimation models would be largely influenced by the artificial control of a pollutant discharge. Thus it is helpful for government decision-making departments to take actions in advance in dealing with probably severe hazy pollutions in BTH indicated by the atmospheric circulation conditions.

  2. Possible influence of atmospheric circulations on winter haze pollution in the Beijing-Tianjin-Hebei region, northern China

    Science.gov (United States)

    Zhang, Z.; Zhang, X.; Gong, D.; Kim, S.-J.; Mao, R.; Zhao, X.

    2016-01-01

    Using the daily records derived from the synoptic weather stations and the NCEP/NCAR and ERA-Interim reanalysis data, the variability of the winter haze pollution (indicated by the mean visibility and number of hazy days) in the Beijing-Tianjin-Hebei (BTH) region during the period 1981 to 2015 and its relationship with the atmospheric circulations at middle-high latitude were analyzed in this study. The winter haze pollution in BTH had distinct inter-annual and inter-decadal variabilities without a significant long-term trend. According to the spatial distribution of correlation coefficients, six atmospheric circulation indices (I1 to I6) were defined from the key areas in sea level pressure (SLP), zonal and meridional winds at 850 hPa (U850, V850), geopotential height field at 500 hPa (H500), zonal wind at 200 hPa (U200), and air temperature at 200 hPa (T200), respectively. All of the six indices have significant and stable correlations with the winter visibility and number of hazy days in BTH. In the raw (unfiltered) correlations, the correlation coefficients between the six indices and the winter visibility (number of hazy days) varied from 0.57 (0.47) to 0.76 (0.6) with an average of 0.65 (0.54); in the high-frequency ( pollution in BTH winter, and vice versa. The high level of the prediction statistics and the reasonable mechanism suggested that the winter haze pollution in BTH can be forecasted or estimated credibly based on the optimized atmospheric circulation indices. Thus it is helpful for government decision-making departments to take action in advance in dealing with probably severe haze pollution in BTH indicated by the atmospheric circulation conditions.

  3. Global atmospheric emissions and transport of polycyclic aromatic hydrocarbons: Evaluation of modeling and transboundary pollution

    Science.gov (United States)

    Shen, Huizhong; Tao, Shu

    2014-05-01

    Global atmospheric emissions of 16 polycyclic aromatic hydrocarbons (PAHs) from 69 major sources were estimated for a period from 1960 to 2030. Regression models and a technology split method were used to estimated country and time specific emission factors, resulting in a new estimate of PAH emission factor variation among different countries and over time. PAH emissions in 2007 were spatially resolved to 0.1° × 0.1° grids based on a newly developed global high-resolution fuel combustion inventory (PKU-FUEL-2007). MOZART-4 (The Model for Ozone and Related Chemical Tracers, version 4) was applied to simulate the global tropospheric transport of Benzo(a)pyrene, one of the high molecular weight carcinogenic PAHs, at a horizontal resolution of 1.875° (longitude) × 1.8947° (latitude). The reaction with OH radical, gas/particle partitioning, wet deposition, dry deposition, and dynamic soil/ocean-air exchange of PAHs were considered. The simulation was validated by observations at both background and non-background sites, including Alert site in Canadian High Arctic, EMEP sites in Europe, and other 254 urban/rural sites reported from literatures. Key factors effecting long-range transport of BaP were addressed, and transboundary pollution was discussed.

  4. The polluted atmosphere of the white dwarf NLTT 25792 and the diversity of circumstellar environments

    CERN Document Server

    Vennes, S

    2013-01-01

    We present an analysis of X-Shooter spectra of the polluted, hydrogen-rich white dwarf NLTT 25792. The spectra show strong lines of calcium (Ca H&K, near-infrared calcium triplet, and Ca I 4226 and numerous lines of iron along with magnesium and aluminum lines from which we draw the abundance pattern. Moreover, the photospheric Ca H&K lines are possibly blended with a circumstellar component shifted by -20 km/s relative to the photosphere. A comparison with a sample of four white dwarfs with similar parameters show considerable variations in their abundance patterns, particularly in the calcium to magnesium abundance ratio that varies by a factor of five within this sample. The observed variations, even after accounting for diffusion effects, imply similar variations in the putative accretion source. Also, we find that silicon and sodium are significantly underabundant in the atmosphere of NLTT 25792, a fact that may offer some clues on the nature of the accretion source.

  5. Biomonitoring of {sup 210}Po and {sup 210}Pb using lichens and mosses around coal-fired power plants in Western Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Sert, Emel, E-mail: emel.sert@mail.ege.edu.tr [Ege University, Institute of Nuclear Sciences, 35100 Bornova, Izmir (Turkey); Ugur, Aysun, E-mail: aysun.ugur@ege.edu.tr [Ege University, Institute of Nuclear Sciences, 35100 Bornova, Izmir (Turkey); Ozden, Banu, E-mail: banu.ozden@ege.edu.tr [Ege University, Institute of Nuclear Sciences, 35100 Bornova, Izmir (Turkey); Sac, Mueslim Murat, E-mail: muslum.murat.sac@ege.edu.tr [Ege University, Institute of Nuclear Sciences, 35100 Bornova, Izmir (Turkey); Camgoez, Berkay, E-mail: berkay.camgoz@ege.edu.tr [Ege University, Institute of Nuclear Sciences, 35100 Bornova, Izmir (Turkey)

    2011-06-15

    Mosses and lichens are useful biological indicators of environmental contamination for a variety of metals and radionuclides of both natural and artificial origin. These plants lack a well-developed root system and rely largely on atmospheric deposition for nourishment. Therefore in the study, different lichens (Cladonia convoluta, Cladonia foliacea) and mosses (Homalothecium sericeum, Hypnum lacunosum, Hypnum cupressiforme, Tortella tortuosa, Didymodon acutus, Syntrichia ruralis, Syntrichia intermedia, Pterogonium graciale, Isothecium alopecuroides, Pleurochatae squarrosa) were collected around the Yatagan (Mugla), Soma (Manisa), Seyitoemer - Tuncbilek (Kuetahya) coal-fired power plants and investigated for potential use as biomonitors for {sup 210}Po and {sup 210}Pb deposition. While the activity concentrations of {sup 210}Po and {sup 210}Pb in lichens are in the ranges of 151 {+-} 7-593 {+-} 21 and 97 {+-} 5-364 {+-} 13 Bq kg{sup -1}, for mosses the ranges for {sup 210}Po and {sup 210}Pb are 124 {+-} 5-1125 {+-} 38 and 113 {+-} 4-490 {+-} 17 Bq kg{sup -1}, respectively. In the study, the moss samples were observed to accumulate more {sup 210}Po and {sup 210}Pb compared to lichens. While the most suitable biomonitor was a moss species (H. lacunosum) for Yatagan (Mugla), it was another moss species (S. intermedia) for Soma (Manisa) and Seyitoemer - Tuncbilek (Kuetahya) sites. {sup 210}Po concentrations were found higher than {sup 210}Pb concentrations at the all sampling stations. - Highlights: > Lichens and mosses have been used as biomonitors of 210Po and 210Pb deposition. > The morphology of lichens and mosses does not vary with seasons. > Lichens and mosses retain and accumulate pollutants deposited from the atmosphere. > Canopy is an important factor causing differences in the concentrations of radionuclides.

  6. Biomonitoring for the photovoltaics industry

    Energy Technology Data Exchange (ETDEWEB)

    Bernholc, N.M.; Moskowitz, P.D.

    1995-07-01

    Biomonitoring often is used as a method for estimating the dose to an individual. Therefore, a parameter of measurement, or biomarkers must be identified. The purpose of this paper is to give an overview of biomonitoring protocols for metals used in the photovoltaics industry. Special attention is given to areas that often are skimmed over, to gain insights into some of the problems that may arise when these tasks are carried out. Biological monitoring can be used to determine current human exposures to chemicals, as well as to detect past exposures, and the effects that these exposures may have on human health. It is used in conjunction with environmental monitoring to describe more completely worker`s exposures to, and absorption of, chemicals in the workplace. Biological specimens (e.g., blood, hair or urine) are analyzed for chemical agents, metabolites, or for some specific effect on the person (Lowry 1994). Biomonitoring can assess a workers exposure to industrial chemicals by all routes including skin absorption and ingestion. Although the methodology still is in its infancy, in cases where the procedures have been developed, it can be an invaluable component of an ongoing program of industrial hygiene monitoring. Like any technology, there are limitations to its effectiveness because of a lack of knowledge, contamination of specimens, and the introduction of errors.

  7. ENVIRONMENTAL MONITORING USING LINDEN TREE LEAVES AS NATURAL TRAPS OF ATMOSPHERIC DEPOSITION: A PILOT STUDY IN TRANSILVANIA, ROMANIA

    Directory of Open Access Journals (Sweden)

    MIHÁLY BRAUN

    2007-12-01

    Full Text Available Atmospheric pollution caused by toxic elements is an emerging problem of concern. Tree leaves have been widely used as indicator of atmospheric pollutions and they are effective alternatives to the moreusual biomonitoring methods. Tree leaves can be used as natural traps of atmospheric deposition. Elemental composition of dust deposited onto leaf surfaces can be used to characterize the urban environment. A pilot survey including 16 Romanian settlements was carried out in order to evaluate the characteristics and sources of air pollutants. Tree leaves (Tilia tomentosa, Tilia cordata, Tilia platyphyllos were collected and used for the measurements. Elemental analyses were carried out by ICP-OES and ICP-MS. Principal component and discriminant analyses were used to characterizing and estimating the level of pollution. Settlements were grouped on the basis of discriminant function values. Multivariate comparison of chemical data ordered the settlements into 3 main groups, which showed a systematic geographic distribution.

  8. Research Progress of Atmospheric Pollution Control Measures%大气污染防治措施研究进展

    Institute of Scientific and Technical Information of China (English)

    吴刚

    2015-01-01

    Main source and harm of air pollution were discussed from natural pollution and anthropogenic pollution. The present situation of atmospheric pollution was also introduced. By improving production processes and equipment, developing recycled exhaust gas purification technology, improving combustion process and the development of new energy, strengthening environmental supervision, control vehicle exhaust pollution, strengthening urban greening we can control air pollution and improve environmental quality effectively.%从自然污染和人为污染方面论述了大气污染的主要来源和危害,介绍了大气污染的的现状。认为,通过改善生产工艺和设备、开发废气净化回收工艺、改进燃烧方法并开发新能源、加强环境监管力度、控制机动车尾气污染、加强城市绿化建设、做好大气环境宣传教育工作等一系列措施和制度,可以有效治理大气污染,改善环境质量。

  9. Complex Physiological Response of Norway Spruce to Atmospheric Pollution – Decreased Carbon Isotope Discrimination and Unchanged Tree Biomass Increment

    Science.gov (United States)

    Čada, Vojtěch; Šantrůčková, Hana; Šantrůček, Jiří; Kubištová, Lenka; Seedre, Meelis; Svoboda, Miroslav

    2016-01-01

    Atmospheric pollution critically affects forest ecosystems around the world by directly impacting the assimilation apparatus of trees and indirectly by altering soil conditions, which subsequently also leads to changes in carbon cycling. To evaluate the extent of the physiological effect of moderate level sulfate and reactive nitrogen acidic deposition, we performed a retrospective dendrochronological analysis of several physiological parameters derived from periodic measurements of carbon stable isotope composition (13C discrimination, intercellular CO2 concentration and intrinsic water use efficiency) and annual diameter increments (tree biomass increment, its inter-annual variability and correlation with temperature, cloud cover, precipitation and Palmer drought severity index). The analysis was performed in two mountain Norway spruce (Picea abies) stands of the Bohemian Forest (Czech Republic, central Europe), where moderate levels of pollution peaked in the 1970s and 1980s and no evident impact on tree growth or link to mortality has been reported. The significant influence of pollution on trees was expressed most sensitively by a 1.88‰ reduction of carbon isotope discrimination (Δ13C). The effects of atmospheric pollution interacted with increasing atmospheric CO2 concentration and temperature. As a result, we observed no change in intercellular CO2 concentrations (Ci), an abrupt increase in water use efficiency (iWUE) and no change in biomass increment, which could also partly result from changes in carbon partitioning (e.g., from below- to above-ground). The biomass increment was significantly related to Δ13C on an individual tree level, but the relationship was lost during the pollution period. We suggest that this was caused by a shift from the dominant influence of the photosynthetic rate to stomatal conductance on Δ13C during the pollution period. Using biomass increment-climate correlation analyses, we did not identify any clear pollution

  10. Inorganic nitrogenous air pollutants, atmospheric nitrogen deposition and their potential ecological impacts in remote areas of western North America (Invited)

    Science.gov (United States)

    Bytnerowicz, A.; Fenn, M. E.; Fraczek, W.; Johnson, R.; Allen, E. B.

    2013-12-01

    Dry deposition of gaseous inorganic nitrogenous (N) air pollutants plays an important role in total atmospheric N deposition and its ecological effects in the arid and semi-arid ecosystems. Passive samplers and denuder/ filter pack systems have been used for determining ambient concentrations of ammonia (NH3), nitric oxide (NO), nitrogen dioxide (NO2), and nitric acid vapor (HNO3) in the topographically complex remote areas of the western United States and Canada. Concentrations of the measured pollutants varied significantly between the monitoring areas. Highest NH3, NO2 and HNO3 levels occurred in southern California areas downwind of the Los Angeles Basin and in the western Sierra Nevada impacted by emissions from the California Central Valley and the San Francisco Bay area. Strong spatial gradients of N pollutants were also present in southeastern Alaska due to cruise ship emissions and in the Athabasca Oil Sands Region in Canada affected by oil exploitation. Distribution of these pollutants has been depicted by maps generated by several geostatistical methodologies within the ArcGIS Geostatistical Analyst (ESRI, USA). Such maps help to understand spatial and temporal changes of air pollutants caused by various anthropogenic activities and locally-generated vs. long range-transported air pollutants. Pollution distribution maps for individual N species and gaseous inorganic reactive nitrogen (Nr) have been developed for the southern portion of the Sierra Nevada, Lake Tahoe Basin, San Bernardino Mountains, Joshua Tree National Park and the Athabasca Oil Sands Region. The N air pollution data have been utilized for estimates of dry and total N deposition by a GIS-based inferential method specifically developed for understanding potential ecological impacts in arid and semi-arid areas. The method is based on spatial and temporal distribution of concentrations of major drivers of N dry deposition, their surface deposition velocities and stomatal conductance values

  11. Model assessment of atmospheric pollution control schemes for critical emission regions

    Science.gov (United States)

    Zhai, Shixian; An, Xingqin; Liu, Zhao; Sun, Zhaobin; Hou, Qing

    2016-01-01

    In recent years, the atmospheric environment in portions of China has become significantly degraded and the need for emission controls has become urgent. Because more international events are being planned, it is important to implement air quality assurance targeted at significant events held over specific periods of time. This study sets Yanqihu (YQH), Beijing, the location of the 2014 Beijing APEC (Asia-Pacific Economic Cooperation) summit, as the target region. By using the atmospheric inversion model FLEXPART, we determined the sensitive source zones that had the greatest impact on the air quality of the YQH region in November 2012. We then used the air-quality model Models-3/CMAQ and a high-resolution emissions inventory of the Beijing-Tianjian-Hebei region to establish emission reduction tests for the entire source area and for specific sensitive source zones. This was achieved by initiating emission reduction schemes at different ratios and different times. The results showed that initiating a moderate reduction of emissions days prior to a potential event is more beneficial to the air quality of Beijing than initiating a high-strength reduction campaign on the day of the event. The sensitive source zone of Beijing (BJ-Sens) accounts for 54.2% of the total source area of Beijing (BJ), but its reduction effect reaches 89%-100% of the total area, with a reduction efficiency 1.6-1.9 times greater than that of the entire area. The sensitive source zone of Huabei (HuaB-Sens.) only represents 17.6% of the total area of Huabei (HuaB), but its emission reduction effect reaches 59%-97% of the entire area, with a reduction efficiency 4.2-5.5 times greater than that of the total area. The earlier that emission reduction measures are implemented, the greater the effect they have on preventing the transmission of pollutants. In addition, expanding the controlling areas to sensitive provinces and cities around Beijing (HuaB-sens) can significantly accelerate the reduction

  12. Spatial character of the gaseous and particulate state compound correlation of urban atmospheric pollution in winter and summer

    Institute of Scientific and Technical Information of China (English)

    XU Xiangde; SHI Xiaohui; XIE Lian; DING Guoan; MIAO Qiuju; MA Jianzhong; ZHENG Xiangdong

    2005-01-01

    The spatial/temporal variation information of atmospheric dynamic-chemical processes at observation site points of the "canopy" boundary of Beijing urban building ensemble and over urban area "surface", as well as the seasonal correlation structure of the gaseous and particulate states of urban atmospheric pollution (UAP) and its seasonal conversion feature at observation points are investigated, using the comprehensive observation data of the Beijing City Air Pollution Observation Experiment (BECAPEX) in winter and summer 2003 with a "point-surface" combined research approach. By using "one dimension spatial empirical orthogonal function (EOF)" principal component analysis (PCA) mode, the seasonal change of gaseous and particulate states of atmospheric aerosols and the association feature of pollutant species under the background of the complicated structure of urban boundary layer (UBL) are analyzed. The comprehensive analyses of the principal components of particle concentrations,gaseous pollutant species, and meteorological conditions reveal the seasonal changes of the complex constituent and structure features of the gaseous and particulate states of UAP to further trace the impact feature of urban aerosol pollution surface sources and the seasonal difference of the component structure of UAP. Research results suggest that in the temporal evolution of the gaseous and particulate states of winter/summer UAP, NOx, CO, and SO2 showed an "in-phase" evolution feature, however, O3 showed an "inverse-phase" relation with other species,all possessing distinctive dependent feature. On the whole, summer concentrations of gaseous pollutants CO, SO2, and NOx were obviously lower than winter ones, especially, the reduction in CO concentration was most distinctive, and ones in SO2 and NOx were next. However, the summer O3 concentration was more than twice winter one. Winter/summer differences in PM10and PM2.5 particle concentrations were relatively not obvious, which

  13. Optimal wavelet denoising for smart biomonitor systems

    Science.gov (United States)

    Messer, Sheila R.; Agzarian, John; Abbott, Derek

    2001-03-01

    Future smart-systems promise many benefits for biomedical diagnostics. The ideal is for simple portable systems that display and interpret information from smart integrated probes or MEMS-based devices. In this paper, we will discuss a step towards this vision with a heart bio-monitor case study. An electronic stethoscope is used to record heart sounds and the problem of extracting noise from the signal is addressed via the use of wavelets and averaging. In our example of heartbeat analysis, phonocardiograms (PCGs) have many advantages in that they may be replayed and analysed for spectral and frequency information. Many sources of noise may pollute a PCG including foetal breath sounds if the subject is pregnant, lung and breath sounds, environmental noise and noise from contact between the recording device and the skin. Wavelets can be employed to denoise the PCG. The signal is decomposed by a discrete wavelet transform. Due to the efficient decomposition of heart signals, their wavelet coefficients tend to be much larger than those due to noise. Thus, coefficients below a certain level are regarded as noise and are thresholded out. The signal can then be reconstructed without significant loss of information in the signal. The questions that this study attempts to answer are which wavelet families, levels of decomposition, and thresholding techniques best remove the noise in a PCG. The use of averaging in combination with wavelet denoising is also addressed. Possible applications of the Hilbert Transform to heart sound analysis are discussed.

  14. Non-invasive matrices in human biomonitoring: a review.

    Science.gov (United States)

    Esteban, Marta; Castaño, Argelia

    2009-02-01

    Humans and other living organisms are exposed to a variety of chemical pollutants that are released into the environment as a consequence of anthropogenic activities. Environmental pollutants are incorporated into the organism by different routes and can then be stored and distributed in different tissues, which leads to an internal concentration that can induce different alterations, adverse effects and/or diseases. Control measures should be taken to avoid these effects and human biomonitoring is a very useful tool that can contribute to this aim. Human biomonitoring uses different matrices to measure the target chemicals depending on the chemical, the amount of matrix necessary for the analysis and the detection limit (LOD) of the analytical technique. Blood is the ideal matrix for most chemicals due to its contact with the whole organism and its equilibrium with organs and tissues where chemicals are stored. However, it has an important disadvantage of being an invasive matrix. The development of new methodology and modern analytical techniques has allowed the use of other matrices that are less or non-invasive, such as saliva, urine, meconium, nails, hair, and semen or breast milk. The presence of a chemical in these matrices reflects an exposure, but correlations between levels in non-invasive matrices and blood must be established to ensure that these levels are related to the total body burden. The development of new biomarkers that are measurable in these matrices will improve non-invasive biomonitoring. This paper reviews studies that measure Cd, Pb, Hg, polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), polycyclic aromatic hydrocarbons (PAHs), polybrominated diphenyl ethers (PBDEs), organochlorine pesticides and phthalates in non-invasive matrices, the most used techniques for measurements and what alternative techniques are available.

  15. Lichen (Xanthoria parietina) biomonitoring of trace element contamination and air quality assessment in Livorno Province (Tuscany, Italy)

    Energy Technology Data Exchange (ETDEWEB)

    Scerbo, R.; Barghigiani, C.; Ristori, T. [CNR Istituto di Biofisica, Via S. Lorenzo 26, 56127 Pisa (Italy); Possenti, L.; Barale, R. [Dipartimento di Scienze dell' Ambiente e del Territorio, Via Volta, Pisa (Italy); Lampugnani, L. [CNR Istituto di Chimica Analitica Strumentale, Via Risorgimento, Pisa (Italy)

    1999-10-29

    This paper deals with the biomonitoring of air in Livorno Province (Tuscany, Italy) using lichens for both quantitative monitoring of airborne metals and air quality assessment. On the basis of the possible sources of metal pollution in the study area, the following elements were analyzed: As, Cd, Cr, Ni, Pb, V, Zn and Hg. The small number of lichen species, the often stunted appearance of the specimens, and metal analysis revealed widespread atmospheric pollution in the study area. The results indicate extensive anthropic impact. The highest levels of contamination were recorded for Hg, Cd, Pb, and V concentrations. Good agreement was found between bioindication and metal concentrations in lichens. The impact of anthropic activities is particularly due to steelworks and chemical plants, combustion processes related to energy production and vehicle emissions. In addition to air pollution, some natural factors, such as climate, rocky shores or ozone, were assumed to affect lichen occurrence. Comparison with the Lake Orta area in northern Italy showed Livorno Province was more contaminated by trace elements. Similar contamination levels were found in another area of Tuscany, probably due to the geological characteristics of this region.

  16. Atmospheric mercury deposition and its contribution of the regional atmospheric transport to mercury pollution at a national forest nature reserve, southwest China.

    Science.gov (United States)

    Ma, Ming; Wang, Dingyong; Du, Hongxia; Sun, Tao; Zhao, Zheng; Wei, Shiqing

    2015-12-01

    Atmospheric mercury deposition by wet and dry processes contributes to the transformation of mercury from atmosphere to terrestrial and aquatic systems. Factors influencing the amount of mercury deposited to subtropical forests were identified in this study. Throughfall and open field precipitation samples were collected in 2012 and 2013 using precipitation collectors from forest sites located across Mt. Jinyun in southwest China. Samples were collected approximately every 2 weeks and analyzed for total (THg) and methyl mercury (MeHg). Forest canopy was the primary factor on THg and MeHg deposition. Simultaneously, continuous measurements of atmospheric gaseous elemental mercury (GEM) were carried out from March 2012 to February 2013 at the summit of Mt. Jinyun. Atmospheric GEM concentrations averaged 3.8 ± 1.5 ng m(-3), which was elevated compared with global background values. Sources identification indicated that both regional industrial emissions and long-range transport of Hg from central, northeast, and southwest China were corresponded to the elevated GEM levels. Precipitation deposition fluxes of THg and MeHg in Mt. Jinyun were slightly higher than those reported in Europe and North America, whereas total fluxes of MeHg and THg under forest canopy on Mt. Jiuyun were 3 and 2.9 times of the fluxes of THg in wet deposition in the open. Highly elevated litterfall deposition fluxes suggest that even in remote forest areas of China, deposition of atmospheric Hg(0) via uptake by vegetation leaf may be a major pathway for the deposition of atmospheric Hg. The result illustrates that areas with greater atmospheric pollution can be expected to have greater fluxes of Hg to soils via throughfall and litterfall.

  17. Mixing state of particles with secondary species by single particle aerosol mass spectrometer in an atmospheric pollution event

    Science.gov (United States)

    Xu, Lingling; Chen, Jinsheng

    2016-04-01

    Single particle aerosol mass spectrometer (SPAMS) was used to characterize size distribution, chemical composition, and mixing state of particles in an atmospheric pollution event during 20 Oct. - 5 Nov., 2015 in Xiamen, Southeast China. A total of 533,012 particle mass spectra were obtained and clustered into six groups, comprising of industry metal (4.5%), dust particles (2.6%), carbonaceous species (70.7%), K-Rich particles (20.7%), seasalt (0.6%) and other particles (0.9%). Carbonaceous species were further divided into EC (70.6%), OC (28.5%), and mixed ECOC (0.9%). There were 61.7%, 58.3%, 4.0%, and 14.6% of particles internally mixed with sulfate, nitrate, ammonium and C2H3O, respectively, indicating that these particles had undergone significant aging processing. Sulfate was preferentially mixed with carbonaceous particles, while nitrate tended to mix with metal-containing and dust particles. Compared to clear days, the fractions of EC-, metal- and dust particles remarkably increased, while the fraction of OC-containing particles decreased in pollution days. The mixing state of particles, excepted for OC-containing particles with secondary species was much stronger in pollution days than that in clear days, which revealed the significant influence of secondary particles in atmospheric pollution. The different activity of OC-containing particles might be related to their much smaller aerodynamic diameter. These results could improve our understanding of aerosol characteristics and could be helpful to further investigate the atmospheric process of particles.

  18. Measurement of DNA strand breaks as a biomarker of genotoxic pollutants

    Digital Repository Service at National Institute of Oceanography (India)

    Sarkar, A.; Patil, S.S.; Holkar, P.K.R.

    This paper deals with the development of a molecular biomarker technique by measurement of DNA integrity in marine organisms for biomonitoring of pollution due to genotoxic compounds. The marine environment is continuously being polluted...

  19. Removal of priority pollutants from water by means of dielectric barrier discharge atmospheric plasma

    Energy Technology Data Exchange (ETDEWEB)

    Hijosa-Valsero, María, E-mail: mhijv@unileon.es [Instituto de Diagnóstico Ambiental y Estudios del Agua (IDAEA), CID, CSIC, C/Jordi Girona 18-26, E-08034 Barcelona (Spain); Molina, Ricardo, E-mail: ricardo.molina@cid.csic.es [Instituto de Química Avanzada de Cataluña (IQAC), CID, CSIC, C/Jordi Girona 18-26, E-08034 Barcelona (Spain); Schikora, Hendrik, E-mail: hendrik.schikora@igb.fraunhofer.de [Fraunhofer IGB, Nobelstraße 12, 70569 Stuttgart (Germany); Müller, Michael, E-mail: michael.mueller@igb.fraunhofer.de [Fraunhofer IGB, Nobelstraße 12, 70569 Stuttgart (Germany); Bayona, Josep M., E-mail: josep.bayona@cid.csic.es [Instituto de Diagnóstico Ambiental y Estudios del Agua (IDAEA), CID, CSIC, C/Jordi Girona 18-26, E-08034 Barcelona (Spain)

    2013-11-15

    Highlights: • DBD plasma reactors were used to remove pollutants from aqueous solutions. • Atrazine, chlorfenvinfos, 2,4-dibromophenol and lindane were studied. • First-order degradation kinetics were observed for all the compounds. • Degradation by-products were identified by GC–MS. • Treatment efficiencies were lower in industrial wastewater than in pure water. -- Abstract: Two different nonthermal plasma reactors at atmospheric pressure were assessed for the removal of organic micropollutants (atrazine, chlorfenvinfos, 2,4-dibromophenol, and lindane) from aqueous solutions (1–5 mg L{sup −1}) at laboratory scale. Both devices were dielectric barrier discharge (DBD) reactors; one was a conventional batch reactor (R1) and the other a coaxial thin-falling-water-film reactor (R2). A first-order degradation kinetics was proposed for both experiments. The kinetic constants (k) were slightly faster in R1 (0.534 min{sup −1} for atrazine; 0.567 min{sup −1} for chlorfenvinfos; 0.802 min{sup −1} for 2,4-dibromophenol; 0.389 min{sup −1} for lindane) than in R2 (0.104 min{sup −1} for atrazine; 0.523 min{sup −1} for chlorfenvinfos; 0.273 min{sup −1} for 2,4-dibromophenol; 0.294 min{sup −1} for lindane). However, energy efficiencies were about one order of magnitude higher in R2 (89 mg kW{sup −1} h{sup −1} for atrazine; 447 mg kW{sup −1} h{sup −1} for chlorfenvinfos; 47 mg kW{sup −1} h{sup −1} for 2,4-dibromophenol; 50 mg kW{sup −1} h{sup −1} for lindane) than in R1. Degradation by-products of all four compounds were identified in R1. As expected, when the plasma treatment (R1) was applied to industrial wastewater spiked with atrazine or lindane, micropollutant removal was also achieved, although at a lower rate than with aqueous solutions (k = 0.117 min{sup −1} for atrazine; k = 0.061 min{sup −1} for lindane)

  20. Bioindication of atmospheric trace metals - With special references to megacities

    Energy Technology Data Exchange (ETDEWEB)

    Markert, Bernd, E-mail: markert@schlundmail.de [Fliederweg 17, D-49733 Haren/Erika (Germany); Wuenschmann, Simone [Fliederweg 17, D-49733 Haren/Erika (Germany); Fraenzle, Stefan [International Graduate School Zittau, D-02763 Zittau (Germany); Graciana Figueiredo, Ana Maria; Ribeiro, Andreza P. [Instituto de Pesquisas Energeticas e Nucleares, IPEN-CNEN/SP, Av. Prof. Linea Prestes 2242, CEP 05508-090, Sao Paulo (Brazil); Wang Meie [State Key Laboratory of Urban and Regional Ecology, Research Centre for Eco-environmental Sciences, Beijing 110016 (China)

    2011-08-15

    After considering the particular problems of atmospheric pollution in megacities, i.e. agglomerations larger than 5 mio. inhabitants, with urbanization of World's population going on steadily, possibilities of active biomonitoring by means of green plants are discussed. Based on specific definitions of active and passive bioindication the chances of monitoring heavy metals in Sao Paulo megacity were demonstrated (first results published before). This is to show that there is need for increased use of bioindication to tackle the particular problems of megacities concerning environmental 'health', the data to be processed according to the Multi-Markered-Bioindication-Concept (MMBC). Comparison to other work shows this approach to be reasonable. - Highlights: > Chemical Pollution. > Bioindication. > Multi-Markered-Bioindication-Concept (MMBC). > Mega cities. - Bioindication is a relevant technique for observing the atmospheric deposition of chemical elements of the environment in megacities.

  1. Retrospective environmental biomonitoring - Mussel Watch expanded

    Science.gov (United States)

    Schöne, Bernd R.; Krause, Richard A.

    2016-09-01

    Monitoring bioavailable contaminants and determining baseline conditions in aquatic environments has become an important aspect of ecology and ecotoxicology. Since the mid-1970s and the initiation of the Mussel Watch program, this has been successfully accomplished with bivalve mollusks. These (mostly) sessile organisms reliably and proportionately record changes of a range of organic and inorganic pollutants occurring in the water, food or sediment. The great majority of studies have measured the concentration of pollutants in soft tissues and, to a much lesser extent, in whole shells or fractions thereof. Both approaches come with several drawbacks. Neither soft tissues nor whole shells can resolve temporal changes of the pollution history, except through the analysis of multiple specimens collected at different times. Soft tissues and shell fractions provide time-averaged data spanning months or years, and whole shells time-averaged data over the entire lifespan of the animal. Even with regular sampling of multiple specimens over long intervals of time, the resulting chronology may not faithfully resolve short-term changes of water quality. Compounding the problem, whole shell averages tend to be non-arithmetic and non-linear, because shell growth rate varies through seasons and lifetime, and different shell layers often vary ultrastructurally and can thus be chemically different from each other. Mussel Watch could greatly benefit from the potential of bivalve shells in providing high-resolution, temporally aligned archives of environmental variability. So far, only circa a dozen studies have demonstrated that the sclerochronological approach - i.e., combined growth pattern and high-resolution chemical analyses - can provide sub-seasonally to annually resolved time-series documenting the history of pollution over centuries and even millennia. On the other hand, the sclerochronological community has failed to fully appreciate that the formation of the shell and

  2. Composition and effects of inhalable size fractions of atmospheric aerosols in the polluted atmosphere: part I. PAHs, PCBs and OCPs and the matrix chemical composition.

    Science.gov (United States)

    Landlová, Linda; Cupr, Pavel; Franců, Juraj; Klánová, Jana; Lammel, Gerhard

    2014-05-01

    Atmospheric particulate matter (PM) abundance, mass size distribution (MSD) and chemical composition are parameters relevant for human health effects. The MSD and phase state of semivolatile organic pollutants were determined at various polluted sites in addition to the PM composition and MSD. The distribution pattern of pollutants varied from side to side in correspondence to main particle sources and PM composition. Levels of particle-associated polycyclic aromatic hydrocarbons (PAHs) were 1-30 ng m(-3) (corresponding to 15-35 % of the total, i.e., gas and particulate phase concentrations), of polychlorinated biphenyls (PCBs) were 2-11 pg m(-3) (4-26 % of the total) and of DDT compounds were 2-12 pg m(-3) (4-23 % of the total). The PM associated amounts of other organochlorine pesticides were too low for quantification. The organics were preferentially found associated with particles matrix composition, amount of contaminants and toxicological effects occur. Legislative regulation based on gravimetric determination of PM mass can clearly be insufficient for assessment.

  3. Assessment of the variability of atmospheric pollution in National Parks of mainland Spain

    Science.gov (United States)

    Escudero, M.; Lozano, A.; Hierro, J.; Tapia, O.; del Valle, J.; Alastuey, A.; Moreno, T.; Anzano, J.; Querol, Xavier

    2016-05-01

    Air quality in nine National Parks in mainland Spain was assessed analysing SO2, NOx, O3, PM10 and PM2.5 data from background stations. As emissions in and around parks are limited, the levels of primary pollutants are low. Concentrations of secondary pollutants are high especially in summer due to photochemical production. The geographical variability of pollutants responds to regional emission patterns and the dominant circulation regimes in different regions resulting in west-east gradients for O3 and PM. Seasonal variability of pollutants was also interpreted in virtue of transport scenarios, changes in photochemical activity and emissions variability. NOx and SO2, maximize in winter due to higher emissions while O3 and PM do it in summer due to photochemical production, lower precipitation and, in the case of PM, the occurrence of African dust outbreaks. The diurnal evolution was interpreted in virtue of variability in emissions and changes in the Planetary Boundar Layer height.

  4. Impacts of Mercury Pollution Controls on Atmospheric Mercury Concentration and Occupational Mercury Exposure in a Hospital.

    Science.gov (United States)

    Li, Ping; Yang, Yan; Xiong, Wuyan

    2015-12-01

    Mercury (Hg) and Hg-containing products are used in a wide range of settings in hospitals. Hg pollution control measures were carried out in the pediatric ward of a hospital to decrease the possibility of Hg pollution occurring and to decrease occupational Hg exposure. Total gaseous Hg (TGM) concentrations in the pediatric ward and hair and urine Hg concentrations for the pediatric staff were determined before and after the Hg pollution control measures had been implemented. A questionnaire survey performed indicated that the pediatric staff had little understanding of Hg pollution and that appropriate disposal techniques were not always used after Hg leakage. TGM concentrations in the pediatric ward and urine Hg (UHg) concentrations for the pediatric staff were 25.7 and 22.2% lower, respectively, after the Hg pollution control measures had been implemented than before, which indicated that the control measures were effective. However, TGM concentrations in the pediatric ward remained significantly higher than background concentrations and UHg concentrations for the pediatric staff were remained significantly higher than the concentrations in control group, indicating continued existence of certain Hg pollution.

  5. Remote sensing applications for diagnostics of the radioactive pollution of the ground surface and in the atmosphere

    Science.gov (United States)

    Pulinets, Sergey; Ouzounov, Dimitar; Boyarchuk, Kirill; Laverov, Nikolay

    2013-04-01

    Radioactive pollution due to its air ionization activity can drastically change the atmospheric boundary layer conductivity (what was experimentally proved during period of nuclear tests in atmosphere) and through the global electric circuit produce anomalous variations in atmosphere. As additional effect the ions created due to air ionization serve as centers of water vapor condensation and nucleation of aerosol-size particles. This process is accompanied by latent heat release. Both anomalies (ionospheric and thermal) can be controlled by remote sensing technique both from satellites (IR sensors and ionospheric probes) and from ground (GPS receivers, ground based ionosondes, VLF propagation sounding, ground measurements of the air temperature and humidity). We monitored the majority of transient events (Three-Mile Island and Chernobyl nuclear power plant emergencies) and stationary sources such as Gabon natural nuclear reactor, sites of underground nuclear tests, etc. and were able to detect thermal anomalies and for majority of cases - the ionospheric anomalies as well. Immediately after the March 11, 2011 earthquake and tsunami in Japan we started to continuously survey the long-wavelength energy flux (10-13 microns) measurable at top of the atmosphere from POES/NOAA/AVHRR polar orbit satellites. Our preliminary results show the presence of hot spots on the top of the atmosphere over the Fukushima Daiichi Nuclear Power Plant (FDNPP) and due to their persistence over the same region they are most likely not of meteorological origin. On March 14 and 21 we detected a significant increase in radiation at the top of the atmosphere which also coincides with a reported radioactivity gas leaks from the FDNPP. After March 21 the intensity of energy flux in atmosphere started to decline, which has been confirmed by ground radiometer network. We were able to detect with ground based ionosonde the ionospheric anomaly associated with the largest radioactive release on March

  6. Atmospheric pollution in the mediterranean area: geochemical studies of aerosols and rain waters

    Energy Technology Data Exchange (ETDEWEB)

    Caboi, R. [Cagliari Univ. (Italy). Dipt. di Scienze della Terra; Chester, R. [Oceanography Lab., Liverpool Univ. (United Kingdom). Dept. of Earth Sciences

    1998-12-31

    It is now recognised that the atmosphere is a major pathway for the transport of material to the oceans. The material in the atmosphere is present as gaseous and particulate (aerosol) phases. Aerosols may be removed from the atmosphere by a combination of `dry` (i.e. not involving an atmospheric aqueous phase) and `wet` (precipitation scavenging) processes. Thus, aerosols are intimately related to rain waters, and interactions between the two are discusses below in relation to the input of material to the Mediterranean Sea.

  7. Atmospheric concentrations of persistent organic pollutants over the Pacific Ocean near southern Taiwan and the northern Philippines.

    Science.gov (United States)

    Chao, How-Ran; Lin, Ding-Yan; Chen, Kuang-Yu; Gou, Yan-Yu; Chiou, Tsyr-Huei; Lee, Wen-Jhy; Chen, Shui-Jen; Wang, Lin-Chi

    2014-09-01

    This study investigates the atmospheric occurrence of persistent organic pollutants (POPs) over the Pacific Ocean near southern Taiwan and the northern Philippines. We determined sixty-six compounds, including polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), dioxin-like polychlorinated biphenyls (DLPCBs), polybrominated diphenyl ethers (PBDEs), as well as polychlorinated diphenyl ethers (PCDEs), polybrominated dibenzo-p-dioxins and dibenzofurans (PBDD/Fs), and polybrominated biphenyls (PBBs), in air samples simultaneously collected from the offshore oceanic atmosphere (n=6) and over a rural area (n=2). We calculated the atmospheric World Health Organization 2005 toxic equivalency levels (WHO2005-TEQ), for the total dioxin-like POPs, including PCDD/Fs, DLPCBs, and PBDD/Fs, being 0.00612 pg WHO2005-TEQ/m(3) and 0.0138 pg WHO2005-TEQ/m(3) over the ocean and land, respectively. We found unexpected lower averaged atmospheric PBDE concentrations in the rural area (15.9 pg/m(3)) than over the ocean (31.1 pg/m(3)) due to higher levels of the BDE209 congener, although the difference was not statistically significant. We have compared and reported our field results with previously published datasets over the global oceans, which suggest PCBs and PBDEs are the dominant chemical contaminants in the global oceanic atmosphere among these halogenated POPs (e.g. PCBs and Σdi-hepta PBDEs could be found in the range of 0.09-48.7 and 8.07-94.0 pg/m(3), respectively, including our dataset). However, there are still very few investigations on the global atmospheric levels of PBDD/Fs, PCDEs and PBBs and our data sums to these earlier studies. Finally, we point out that the halogenated POPs originated from Taiwan or the continental East Asia which could easily reach remote ocean sites via atmospheric transport.

  8. Modelling atmospheric circulations for the study of Alpine valleys pollution; Modelisation des circulations atmospheriques pour l'etude de la pollution des vallees alpines

    Energy Technology Data Exchange (ETDEWEB)

    Brulfert, G.

    2004-11-15

    Local weather phenomena observed in alpine valleys frequently lead to the accumulation of emitted anthropogenic airborne species in the low layers of the atmosphere. The development of a numerical model allows reproducing the chemical evolution of air mass during POVA intensive period of observations. In Chamonix and Maurienne valley, computations of photochemical indicators (NO{sub y}, O{sub 3}/NO{sub z}, H{sub 2}O{sub 2}/HNO{sub 3}) prove the ozone regime to be control by volatile organic compounds. Moreover simulation highlighted that the major part of this secondary pollutant is regionally produced. The development of an indicator who localised ozone production sites can help to define abatement scenarios. The chemical mechanism RACM allows describing the evolution of many species. It is possible to conclude that in winter road traffic and heating are the main sources of volatile organic compounds. (author)

  9. Foliar Uptake of Atmospheric Reactive Nitrogen Pollution Along an Urban-Rural Gradient in New York State

    Science.gov (United States)

    Vallano, D.; Sparks, J. P.

    2008-12-01

    Vegetation is an important sink for atmospheric reactive nitrogen (N) pollution in terrestrial ecosystems, and when soil N is limiting, foliar N uptake can be a source of plant-available N. A proxy for pollution derived N, and in particular foliar assimilated N, would be useful to quantify the impact of the foliar uptake pathway on plant metabolism. Nitrogen stable isotope ratios (15N/14N) are practical for this purpose because forms of plant-available N often have varying isotopic compositions. However, the mechanisms driving differences in foliar N isotopic composition (δ15N) are still unresolved. Current understanding of foliar δ 15N suggests these values primarily represent the integration of the soil water solution δ15N, direct foliar uptake of atmospheric reactive N, within-plant fractionations, and fractionation due to the fungus to root transfer in mycorrhizae. In this study, we investigated the influence of direct foliar uptake, soil solution δ 15N, and mycorrhizae on foliar δ15N in seedlings of two dominant Northeastern tree species, red maple (Acer rubrum) and red oak (Quercus rubra), along an N deposition gradient in New York State. Using a potted plant mesocosm system, we compared foliar δ15N values directly to soil solution δ15N values while controlling for mycorrhizal associations. Both species showed higher foliar δ15N when exposed to fractionation by mycorrhizal associations. Overall, A. rubrum showed higher foliar δ15N than Q. rubra across all sites. In both species, patterns of foliar δ15N values were coupled with soil solution δ15N values across the N deposition gradient. Additionally, increasing atmospheric N deposition was correlated with higher foliar δ15N values in Q. rubra, but not in A. rubrum. Using a mixing model, we estimated that Q. rubra seedlings incorporated up to 7% of their assimilated N via direct foliar uptake of atmospheric N pollution. However, foliar uptake was not detectable in A. rubrum seedlings. Results

  10. Atmospheric Chemistry Research in New EU Countries. A survey on atmospheric chemistry research and monitoring of air pollution in some new EU Member States and Candidate Countries

    Energy Technology Data Exchange (ETDEWEB)

    Batchvarova, E.; Spassova, T.; Valkov, N.; Iordanova, L. [Department of Composition of the Atmosphere and Hydrosphere, National IInstitute of Meteorology and Hydrology, Bulgarian Academy of Sciences, Sofia (Bulgaria); Hjorth, J. (ed.) [Institute for Environment and Sustainability, Joint Research Centre JRC, Ispra (Italy)

    2005-07-01

    Historically some of the new EU Member States and the Candidate countries experienced high levels of pollution in the past. Enhanced management measures were and are needed to improve the air quality. The present survey on the ongoing air chemistry research is in support to such measures and the incorporation of the EU environmental legislation in the air quality management of these countries. The aim of the survey is to list the current research activities on atmospheric chemistry in these countries, as well as groups and institutions involved in it. The air chemistry plays essential part of air quality and climate change modelling, energy industry planning and health risk assessments. In addition, the air quality monitoring networks and management are briefly discussed, as well as some information on the air pollution modelling research. The ongoing research (field, laboratory and modelling) in the field of chemical transformation of trace compounds in the atmosphere is discussed here and parallels are drown among 10 of the new EU Member States and Candidate Countries, namely Bulgaria, the Czech Republic, Estonia, Hungary, Latvia, Lithuania, Poland, Romania, the Slovak Republic and Slovenia. Laboratory studies traditionally emphasize on rate and equilibrium processes. Field studies are based on aircraft and surface measurements of reaction chemistry, advective influences on the chemical composition of the atmosphere, and air-surface exchange processes. Both types experimental studies on atmospheric chemistry are demanding concerning equipment and resources. Therefore, most of the studies in the field are coming from international projects, EU, ESF or NATO funded. Modelling efforts address both chemistry and dynamics on regional and global scales. The analysis of research activities in those fields is made with regards of the current EU practice in the field and the historical frames in the ten countries of interest. The unique traditions and achievements in

  11. Evolution of atmospheric pollutants in the city of Sfax (Tunisia) (October 1996-June 1997)

    Energy Technology Data Exchange (ETDEWEB)

    Azri, C. [Faculte des Sciences de Sfax, Departement des Sciences de la Terre, Sfax (Tunisia)]. E-mail: chafai_azri@yahoo.fr; Maalej, A. [Faculte des Sciences de Sfax, Departement de Physique, Sfax (Tunisia); Medhioub, K. [Institut Preparatoire aux Etudes d' Ingenieurs de Sfax (IPEIS), Sfax (Tunisia); Rosset, R. [Laboratoire d' Aerologie UMR CNRS/UPS 5560, Toulouse (France)

    2007-07-15

    The descriptive study related to the evolution of O{sub 3}, NO, NO{sub 2}, CO, SO{sub 2}, CH{sub 4}, NMHC and PM10 concentrations in downtown Sfax showed, during the period October 1996-June 1997, that the city is significantly influenced by many sources and meteorological factors. The diurnal average concentrations of these species let appear at times some peculiarities due to the population local customs and also to particular meteorological conditions associated with predominant strong cyclonic situations (cut-off lows). Based on NO and CH{sub 4}, two species selected respectively as local and synoptic tracers, this descriptive study which is refined by a principal component analysis showed, out from these particular meteorological conditions, three components of the atmospheric pollution: a first component formed by CH{sub 4} and in less degree NMHC showing the impact of synoptic sources, a second component containing NO, NO{sub 2}, CO, SO{sub 2} and in less degree PM10 and NMHC displaying the impact of local sources (vehicle and industrial sources), and finally a third component constituted by O{sub 3} and in less degree PM10 presenting the impact of regional sources. Under the above quoted cyclonic situations, the distribution of such components was shown considerably modified. [Spanish] El estudio descriptivo con relacion a la evolucion de las concentraciones de los compuestos O{sub 3}, NO, NO{sub 2}, CO, SO{sub 2}, CH{sub 4}, NMHC y de los PM10 en la ciudad de Sfax senalo, durante el periodo de octubre 1996 hasta junio 1997, que la ciudad esta fuertemente influenciada por varias fuentes y factores meteorologicos. Las concentraciones diurnas medias de dichas especies mostraron algunas particularidades debidas a las costumbres locales de los habitantes y tambien a las particulares condiciones meteorologicas asociadas a las fuertes situaciones ciclonicas (bajas segregadas). Con base en NO y CH{sub 4}, dos especies seleccionadas como trazadores local y

  12. Atmospheric pollution problems and control proposals associated with solid waste management in China: a review.

    Science.gov (United States)

    Tian, Hezhong; Gao, Jiajia; Hao, Jiming; Lu, Long; Zhu, Chuanyong; Qiu, Peipei

    2013-05-15

    Along with population growth, rapid urbanization and industrialization process, the volume of municipal solid waste (MSW) generation in China has been increasing sharply in the past 30 years and the total amount of MSW yields will continue to increase. Nowadays, due to global warming warrants particular attention throughout the world, a series of air pollutants (including greenhouse gases, odorous gases, PCDD/Fs, heavy metals, PM, etc.) discharged from waste disposal and treatment processes have become one of the new significant emerging air pollution sources, which arousing great concerns about their adverse effects on surrounding ambient air quality and public health. At present, the overall safely disposed ratio of the collected MSW in China is reported at approximately 78% in 2010, and there are mainly three types of MSW disposal methods practiced in China, including landfill, composting and incineration. The characteristics of air pollutants and greenhouse gases discharge vary substantially among different MSW disposal methods. By presenting a thorough review of MSW generation in China and providing a summarization of the current status of MSW disposal methods practices, this review article makes an integrated overview analysis of existing air pollution problems associated with MSW collection, separation, and disposal processes. Furthermore, some comprehensive control proposals to prevent air pollution for improving MSW management of China in the future are put forward.

  13. The horizontal transport of pollutants from a slope wind layer into the valley core as a function of atmospheric stability

    Science.gov (United States)

    Leukauf, Daniel; Gohm, Alexander; Rotach, Mathias W.; Posch, Christian

    2016-04-01

    Slope winds provide a mechanism for the vertical exchange of air between the valley and the free atmosphere aloft. By this means, heat, moisture and pollutants are exported or imported. However, it the static stability of the valley atmosphere is strong, one part of the up-slope flow is redirected towards the valley center and pollutants are recirculated within the valley. This may limit the venting potential of slope winds severely. The main objective of this study is to quantify the horizontal transport of pollutants from the slope wind layer into the stable valley core and to determine the dependency of this flux as a function of the initial stability of the atmosphere. For this purpose, we conducted large eddy simulations with the Weather Research and Forecasting (WRF) model for a quasi-two-dimensional valley. The valley geometry consists of two slopes with constant slope angle rising to a crest height of 1500 m and a 4 km wide flat valley floor in between. The valley is 20 km long and homogeneous in along-valley direction. Hence, only slope winds but no valley winds can evolve. The surface sensible heat flux is prescribed by a sine function with an amplitude of 125 W m-2. The initial sounding characterized by an atmosphere at rest and by a constant Brunt-Väisälä frequency which is varied between 0.006 s-1 and 0.02 s-1. A passive tracer is released with an arbitrary but constant rate at the valley floor. As expected, the atmospheric stability has a strong impact on the vertical and horizontal transport of tracer mass. A horizontal intrusion forms at the top of the mixed layer due to outflow from the slope wind layer. Tracer mass is transported from the slope towards the center of the valley. The efficiency of this mechanism increases with increasing stability N. For the lowest value of N, about 70% of the tracer mass released at the valley bottom is exported out of the valley. This value drops to about 12% in the case of the strongest stability. Hence, most

  14. Impacts of atmospheric pollution on the plant communities of British acid grasslands.

    Science.gov (United States)

    Payne, Richard J; Stevens, Carly J; Dise, Nancy B; Gowing, David J; Pilkington, Michael G; Phoenix, Gareth K; Emmett, Bridget A; Ashmore, Michael R

    2011-10-01

    Air pollutants are recognised as important agents of ecosystem change but few studies consider the effects of multiple pollutants and their interactions. Here we use ordination, constrained cluster analysis and indicator value analyses to identify potential environmental controls on species composition, ecological groupings and indicator species in a gradient study of UK acid grasslands. The community composition of these grasslands is related to climate, grazing, ozone exposure and nitrogen deposition, with evidence for an interaction between the ecological impacts of base cation and nitrogen deposition. Ozone is a key agent in species compositional change but is not associated with a reduction in species richness or diversity indices, showing the subtly different drivers on these two aspects of ecosystem degradation. Our results demonstrate the effects of multiple interacting pollutants, which may collectively have a greater impact than any individual agent.

  15. The polluted atmospheres of cool white dwarfs and the magnetic field connection

    CERN Document Server

    Kawka, A

    2014-01-01

    We present an analysis of X-Shooter spectra of the polluted hydrogen-rich white dwarfs (DAZ) NLTT 888 and NLTT 53908. The spectra of NLTT 53908 show strong, Zeeman-split calcium lines (CaII H&K and Ca I $\\lambda 4226$) and the star appears to be a close relative of the polluted magnetic white dwarf (DAZH) NLTT 10480, while the spectra of NLTT 888 show narrow lines of calcium and iron. A comparison of the DAZ NLTT 888 and the DAZH NLTT 53908 with other class members illustrates the diversity of environment and formation circumstances surrounding these objects. In particular, we find that the incidence of magnetism in old, polluted white dwarfs significantly exceeds that found in the general white dwarf population which suggests an hypothetical link between a crowded planetary system and magnetic field generation.

  16. Contribution of atmospheric nitrogen deposition to diffuse pollution in a typical hilly red soil catchment in southern China.

    Science.gov (United States)

    Shen, Jianlin; Liu, Jieyun; Li, Yong; Li, Yuyuan; Wang, Yi; Liu, Xuejun; Wu, Jinshui

    2014-09-01

    Atmospheric nitrogen (N) deposition is currently high and meanwhile diffuse N pollution is also serious in China. The correlation between N deposition and riverine N export and the contribution of N deposition to riverine N export were investigated in a typical hilly red soil catchment in southern China over a two-year period. N deposition was as high as 26.1 to 55.8kgN/(ha·yr) across different land uses in the studied catchment, while the riverine N exports ranged from 7.2 to 9.6kgN/(ha·yr) in the forest sub-catchment and 27.4 to 30.3kgN/(ha·yr) in the agricultural sub-catchment. The correlations between both wet N deposition and riverine N export and precipitation were highly positive, and so were the correlations between NH4(+)-N or NO3(-)-N wet deposition and riverine NH4(+)-N or NO3(-)-N exports except for NH4(+)-N in the agricultural sub-catchment, indicating that N deposition contributed to riverine N export. The monthly export coefficients of atmospheric deposited N from land to river in the forest sub-catchment (with a mean of 14%) presented a significant positive correlation with precipitation, while the monthly contributions of atmospheric deposition to riverine N export (with a mean of 18.7% in the agricultural sub-catchment and a mean of 21.0% in the whole catchment) were significantly and negatively correlated with precipitation. The relatively high contribution of N deposition to diffuse N pollution in the catchment suggests that efforts should be done to control anthropogenic reactive N emissions to the atmosphere in hilly red soil regions in southern China.

  17. The model SIRANE for atmospheric urban pollutant dispersion; part I, presentation of the model

    Science.gov (United States)

    Soulhac, Lionel; Salizzoni, Pietro; Cierco, F.-X.; Perkins, Richard

    2011-12-01

    In order to control and manage urban air quality, public authorities require an integrated approach that incorporates direct measurements and modelling of mean pollutant concentrations. These have to be performed by means of operational modelling tools, that simulate the transport of pollutants within and above the urban canopy over a large number of streets. The operational models must be able to assess rapidly a large variety of situations and with limited computing resources. SIRANE is an operational urban dispersion model based on a simplified description of the urban geometry that adopts parametric relations for the pollutant transfer phenomena within and out of the urban canopy. The streets in a city district are modelled as a network of connected street segments. The flow within each street is driven by the component of the external wind parallel to the street, and the pollutant is assumed to be uniformly mixed within the street. The model contains three main mechanisms for transport in and out of a street: advection along the street axis, diffusion across the interface between the street and the overlying air flow and exchanges with other streets at street intersections. The dispersion of pollutants advected or diffused out of the streets is taken into account using a Gaussian plume model, with the standard deviations σ y and σ z parameterised by the similarity theory. The input data for the final model are the urban geometry, the meteorological parameters, the background concentration of pollutants advected into the model domain by the wind and the emissions within each street in the network.

  18. Atmospheric pollution problems and control proposals associated with solid waste management in China: A review

    Energy Technology Data Exchange (ETDEWEB)

    Tian, Hezhong, E-mail: hztian@bnu.edu.cn [State Key Joint Laboratory of Environmental Simulation and Pollution Control, School of Environment, Beijing Normal University, Beijing 100875 (China); Gao, Jiajia [State Key Joint Laboratory of Environmental Simulation and Pollution Control, School of Environment, Beijing Normal University, Beijing 100875 (China); Hao, Jiming [School of Environment, Tsinghua University, Beijing 100084 (China); Lu, Long; Zhu, Chuanyong; Qiu, Peipei [State Key Joint Laboratory of Environmental Simulation and Pollution Control, School of Environment, Beijing Normal University, Beijing 100875 (China)

    2013-05-15

    Highlights: ► Air pollution problems generated in MSW management processes in China are presented. ► Both quantity and composition of MSW generation in China are identified. ► The status of different methods for MSW treatment and disposal are reviewed. ► Some comprehensive control proposals for improving MSW management are proposed. -- Abstract: Along with population growth, rapid urbanization and industrialization process, the volume of municipal solid waste (MSW) generation in China has been increasing sharply in the past 30 years and the total amount of MSW yields will continue to increase. Nowadays, due to global warming warrants particular attention throughout the world, a series of air pollutants (including greenhouse gases, odorous gases, PCDD/Fs, heavy metals, PM, etc.) discharged from waste disposal and treatment processes have become one of the new significant emerging air pollution sources, which arousing great concerns about their adverse effects on surrounding ambient air quality and public health. At present, the overall safely disposed ratio of the collected MSW in China is reported at approximately 78% in 2010, and there are mainly three types of MSW disposal methods practiced in China, including landfill, composting and incineration. The characteristics of air pollutants and greenhouse gases discharge vary substantially among different MSW disposal methods. By presenting a thorough review of MSW generation in China and providing a summarization of the current status of MSW disposal methods practices, this review article makes an integrated overview analysis of existing air pollution problems associated with MSW collection, separation, and disposal processes. Furthermore, some comprehensive control proposals to prevent air pollution for improving MSW management of China in the future are put forward.

  19. Atmospheric processes of organic pollutants over a remote lake on the central Tibetan Plateau: implications for regional cycling

    Science.gov (United States)

    Ren, Jiao; Wang, Xiaoping; Wang, Chuanfei; Gong, Ping; Yao, Tandong

    2017-01-01

    Atmospheric processes (air-surface exchange, and atmospheric deposition and degradation) are crucial for understanding the global cycling and fate of organic pollutants (OPs). However, such assessments over the Tibetan Plateau (TP) remain uncertain. More than 50 % of Chinese lakes are located on the TP, which exerts a remarkable influence on the regional water, energy, and chemical cycling. In this study, air and water samples were simultaneously collected in Nam Co, a large lake on the TP, to test whether the lake is a secondary source or sink of OPs. Lower concentrations of organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) were observed in the atmosphere and lake water of Nam Co, while the levels of polycyclic aromatic hydrocarbons (PAHs) were relatively higher. Results of fugacity ratios and chiral signatures both suggest that the lake acted as the net sink of atmospheric hexachlorocyclohexanes (HCHs), following their long-range transport driven by the Indian monsoon. Different behaviours were observed in the PAHs, which primarily originated from local biomass burning. Acenaphthylene, acenaphthene, and fluorene showed volatilization from the lake to the atmosphere, while other PAHs were deposited into the lake due to the integrated deposition process (wet/dry and air-water gas deposition) and limited atmospheric degradation. As the dominant PAH compound, phenanthrene exhibited a seasonal reversal of air-water gas exchange, which was likely related to the melting of the lake ice in May. The annual input of HCHs from the air to the entire lake area (2015 km2) was estimated as 1.9 kg yr-1, while input estimated for ∑ 15PAHs can potentially reach up to 550 kg yr-1. This study highlights the significance of PAH deposition on the regional carbon cycling in the oligotrophic lakes of the TP.

  20. Biomonitoring and speciation of road dust for heavy metals using Calotropis procera and Delbergia sissoo

    Directory of Open Access Journals (Sweden)

    Santosh Kumar Prajapati

    2012-12-01

    Full Text Available The present study was conducted for identifying the important heavy metals present in the road dust and at the same time biomonitor them using Calotropis procera and Delbergia sissoo leaves. The study clearly indicated that both the plants can be used as biomonitor for As, Pb, Fe, V, Cd, Cr, Zn and Cu. The heavy metals were estimated using AAS-7000 (Shimadzu. Reason for selecting the plants were their abundance in the area and high air pollution indices. Presence of these heavy metals in the road dust can be attributed to the red soil and more importantly thermal power plants operating in the study area. Since plants are able to capture the road dust, they can also prevent the particulate pollution which is having adverse health impacts for humans.

  1. Biomonitoring of air quality in the metropolitan region of Recife, PE, Brazil; Biomonitoracao da qualidade do ar na Regiao Metropolitana do Recife, PE

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Thiago Oliveira dos

    2016-08-01

    The interest on questions related to environmental conservation has increased in recent decades, being air pollution one of the main public health problems in huge urban centers. Major part of this atmospheric contamination is caused by gaseous pollutants and inhalable particulate matter. One of the main sources is the burning of fossil fuels mainly emitted by motor vehicles. Some organisms, like lichen and atmospheric bromeliad, are able to accumulate chemical elements in their tissues, thereby becoming excellent tools for air quality studies of monitoring. The present work evaluated the air quality in the Metropolitan Region of Recife (RMR) using the lichen Cladonia verticillaris and the bromeliad Tillandsia recurvata, through the quantification of chemical elements associated to vehicles traffic. The biomonitors were transferred to 40 points distributed in the RMR with different intensities of the vehicle traffic. After the exposition period of six months, Al, Ba, Ca, Cd, Cl, Fe, Mg, Mn, P, Pb, Sb, Sr, Th, V and Zn were quantified by Energy Dispersive X-Ray Fluorescence (EDXRF) and Inductively Coupled Plasma Mass Spectrometry (ICP-MS). The organisms were complementary, being appropriated tools for monitoring the air quality. The vehicle traffic was considered one of the major contributor for increasing chemical elements in the RMR urban atmosphere. (author)

  2. Assessment of trace metal air pollution in Paris using slurry-TXRF analysis on cemetery mosses.

    Science.gov (United States)

    Natali, Marco; Zanella, Augusto; Rankovic, Aleksandar; Banas, Damien; Cantaluppi, Chiara; Abbadie, Luc; Lata, Jean -Christophe

    2016-12-01

    Mosses are useful, ubiquitous accumulation biomonitors and as such can be used for biomonitoring surveys. However, the biomonitoring of atmospheric pollution can be compromised in urban contexts if the targeted biomonitors are regularly disturbed, irregularly distributed, or are difficult to access. Here, we test the hypothesis that cemeteries are appropriate moss sampling sites for the evaluation of air pollution in urban areas. We sampled mosses growing on gravestones in 21 urban and peri-urban cemeteries in the Paris metropolitan area. We focused on Grimmia pulvinata (Hedwig) Smith, a species abundantly found in all studied cemeteries and very common in Europe. The concentration of Al, As, Br, Ca, Ce, Cl, Cr, Cu, Fe, K, Mn, Ni, V, P, Pb, Rb, S, Sr, Ti, and Zn was determined by a total reflection X-ray fluorescence technique coupled with a slurry sampling method (slurry-TXRF). This method avoids a digestion step, reduces the risk of sample contamination, and works even at low sample quantities. Elemental markers of road traffic indicated that the highest polluted cemeteries were located near the highly frequented Parisian ring road and under the influence of prevailing winds. The sites with the lowest pollution were found not only in the peri-urban cemeteries, adjoining forest or farming landscapes, but also in the large and relatively wooded cemeteries located in the center of Paris. Our results suggest that (1) slurry-TXRF might be successfully used with moss material, (2) G. pulvinata might be a good biomonitor of trace metals air pollution in urban context, and (3) cemetery moss sampling could be a useful complement for monitoring urban areas. Graphical abstract We tested the hypothesis that cemeteries are appropriate moss sampling sites for the evaluation of air pollution in urban areas. We sampled 110 moss cushions (Grimmia pulvinata) growing on gravestones in 21 urban and peri-urban cemeteries in the Paris metropolitan area. The concentration of 20

  3. Laser technology to monitor atmospheric pollution. Tecnologia laser para medicion de la contaminacion atmosferica

    Energy Technology Data Exchange (ETDEWEB)

    Guerao, A.; Caceci, M.

    1993-01-01

    Air quality and pollution can be monitored in a reliable way using LIDAR. Light detection and measurement by using a Laser beam can identify gases, particles, smoke, water vapor and other contaminants. Radiance and directionality of the laser beam are useful for this application. Activities of CISE in this field are presented.

  4. Automobile air pollution: Atmospheric motion. (Latest citations from the NTIS bibliographic database). Published Search

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-05-01

    The bibliography contains citations concerning the modeling, diffusion, and motion of motor vehicle exhaust. The citations cover the prediction of pollution from motor vehicles at specific locations and its impact at locations removed from the source. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  5. Impacts of atmospheric pollution on the plant communities of British acid grasslands

    Energy Technology Data Exchange (ETDEWEB)

    Payne, Richard J., E-mail: r.payne@mmu.ac.uk [School of Science and the Environment, Manchester Metropolitan University, Chester St., Manchester M1 5GD (United Kingdom); Geography, School of Environment and Development, University of Manchester, Oxford Road, Manchester M13 9PL (United Kingdom); Stevens, Carly J. [Faculty of Science, Open University, Walton Hall, Milton Keynes MK7 6AA (United Kingdom); Lancaster Environment Centre, Lancaster University, Bailrigg, Lancaster LA1 4YQ (United Kingdom); Dise, Nancy B. [School of Science and the Environment, Manchester Metropolitan University, Chester St., Manchester M1 5GD (United Kingdom); Gowing, David J. [Faculty of Science, Open University, Walton Hall, Milton Keynes MK7 6AA (United Kingdom); Pilkington, Michael G.; Phoenix, Gareth K. [Department of Animal and Plant Sciences, Alfred Denny Building, University of Sheffield, Sheffield S10 2TN (United Kingdom); Emmett, Bridget A. [Centre for Ecology and Hydrology, Environment Centre Wales, Deiniol Road, Bangor, Gwynedd LL57 2UW (United Kingdom); Ashmore, Michael R. [Environment Department, University of York, Heslington, York YO10 5DD (United Kingdom)

    2011-10-15

    Air pollutants are recognised as important agents of ecosystem change but few studies consider the effects of multiple pollutants and their interactions. Here we use ordination, constrained cluster analysis and indicator value analyses to identify potential environmental controls on species composition, ecological groupings and indicator species in a gradient study of UK acid grasslands. The community composition of these grasslands is related to climate, grazing, ozone exposure and nitrogen deposition, with evidence for an interaction between the ecological impacts of base cation and nitrogen deposition. Ozone is a key agent in species compositional change but is not associated with a reduction in species richness or diversity indices, showing the subtly different drivers on these two aspects of ecosystem degradation. Our results demonstrate the effects of multiple interacting pollutants, which may collectively have a greater impact than any individual agent. - Highlights: > Ozone exposure, N and base cation deposition modify UK acid grassland composition. > Ozone influences community composition without reducing species richness. > Nitrogen and base cation deposition have interacting impacts. > Distinct species responses to pollutants suggest potential for bioindication. - Ozone exposure and nitrogen deposition have distinct but additive impacts on the plant communities of British acid grasslands.

  6. Lateral Dispersion of Pollutants in a Very Stable Atmosphere - The Effect of Meandering

    DEFF Research Database (Denmark)

    Kristensen, Leif; Jensen, Niels Otto; Lundtang Petersen, Erik

    1981-01-01

    A model based on single particle diffusion is introduced to account for the effect of “meandering” on lateral plume dispersion in a very stable atmosphere. It is assumed that small scale atmospheric turbulence is absent, so that only large horizontal eddies are effective. A formula for the lateral...... standard deviation σy as function of observation time, distance from source, mean wind speed, lateral turbulence intensity, and scale of the atmospheric motion is derived. Climatological time series of temperature lapse rates, wind speeds, and wind directions can be used as input to calculate σy....... Meteorological data from Risø and the small island Sprogø have been analysed in order to identify all situations in which the atmosphere is so stable that small scale turbulence cannot exist. The purpose is to see in how many of these situations meandering is also absent. The results show that, as a rule...

  7. 欧洲大气颗粒物污染治理%Atmospheric Particulates Pollution Control in Europe

    Institute of Scientific and Technical Information of China (English)

    尹盛鑫; 尹军

    2013-01-01

    欧洲历史上曾长期遭受大气颗粒物污染问题的困扰,比如,发生过1930年比利时马斯河谷事件及1952年伦敦烟雾事件。但最近几十年来,经过长期努力,欧洲对大气颗粒物的治理工作取得了显著成绩。目前,我国大气颗粒物来源情况与欧洲存在较大的差异,但欧洲通过在交通和能源等方面对污染源的治理有效减少大气颗粒物排放的经验,对我国治理“雾霾”具有重要的借鉴意义。%Europe has suffered from the air pollution caused by atmospheric particulates for decades, for instance, Smog Incident in Meuse Valley in 1930, and the Great Smog of London in 1952. However, due to its long-term commitment, Europe has made great achievements on control of this pollution in recent decades. This paper analyzed measures taken by Europe to control the emission of particulate matter via its energy use and transport management, which has great signiifcance to the treatment of particulate matter pollution emerging in China.

  8. Resonance Raman imaging as a tool to assess the atmospheric pollution level: carotenoids in Lecanoraceae lichens as bioindicators.

    Science.gov (United States)

    Ibarrondo, I; Prieto-Taboada, N; Martínez-Arkarazo, I; Madariaga, J M

    2016-04-01

    Raman spectroscopy differentiation of carotenoids has traditionally been based on the ν 1 position (C = C stretching vibrations in the polyene chain) in the 1500-1600 cm(-1) range, using a 785 nm excitation laser. However, when the number of conjugated double bonds is similar, as in the cases of zeaxanthin and β-carotene, this distinction is still ambiguous due to the closeness of the Raman bands. This work shows the Raman results, obtained in resonance conditions using a 514 mm laser, on Lecanora campestris and Lecanora atra species, which can be used to differentiate and consequently characterize carotenoids. The presence of the carotenoid found in Lecanoraceae lichens has been demonstrated to depend on the atmospheric pollution level of the environment they inhabit. Astaxanthin, a superb antioxidant, appears as the principal xanthophyll in highly polluted sites, usually together with the UV screening pigment scytonemin; zeaxanthin is the major carotenoid in medium polluted environments, while β-carotene is the major carotenoid in cleaner environments. Based on these observations, an indirect classification of the stress suffered in a given environment can be assessed by simply analysing the carotenoid content in the Lecanoraceae lichens by using resonance Raman imaging.

  9. Potential sensitivity of photosynthesis and isoprene emission to direct radiative effects of atmospheric aerosol pollution

    Science.gov (United States)

    Strada, Susanna; Unger, Nadine

    2016-04-01

    A global Earth system model is applied to quantify the impacts of direct anthropogenic aerosol effective radiative forcing on gross primary productivity (GPP) and isoprene emission. The impacts of different pollution aerosol sources (anthropogenic, biomass burning, and non-biomass burning) are investigated by performing sensitivity experiments. The model framework includes all known light and meteorological responses of photosynthesis, but uses fixed canopy structures and phenology. On a global scale, our results show that global land carbon fluxes (GPP and isoprene emission) are not sensitive to pollution aerosols, even under a global decline in surface solar radiation (direct + diffuse) by ˜ 9 %. At a regional scale, GPP and isoprene emission show a robust but opposite sensitivity to pollution aerosols in regions where forested canopies dominate. In eastern North America and Eurasia, anthropogenic pollution aerosols (mainly from non-biomass burning sources) enhance GPP by +5-8 % on an annual average. In the northwestern Amazon Basin and central Africa, biomass burning aerosols increase GPP by +2-5 % on an annual average, with a peak in the northwestern Amazon Basin during the dry-fire season (+5-8 %). The prevailing mechanism varies across regions: light scattering dominates in eastern North America, while a reduction in direct radiation dominates in Europe and China. Aerosol-induced GPP productivity increases in the Amazon and central Africa include an additional positive feedback from reduced canopy temperatures in response to increases in canopy conductance. In Eurasia and northeastern China, anthropogenic pollution aerosols drive a decrease in isoprene emission of -2 to -12 % on an annual average. Future research needs to incorporate the indirect effects of aerosols and possible feedbacks from dynamic carbon allocation and phenology.

  10. Nanoparticle exposure biomonitoring: exposure/effect indicator development approaches

    Science.gov (United States)

    Marie-Desvergne, C.; Dubosson, M.; Lacombe, M.; Brun, V.; Mossuz, V.

    2015-05-01

    The use of engineered nanoparticles (NP) is more and more widespread in various industrial sectors. The inhalation route of exposure is a matter of concern (adverse effects of air pollution by ultrafine particles and asbestos). No NP biomonitoring recommendations or standards are available so far. The LBM laboratory is currently studying several approaches to develop bioindicators for occupational health applications. As regards exposure indicators, new tools are being implemented to assess potentially inhaled NP in non-invasive respiratory sampling (nasal sampling and exhaled breath condensates (EBC)). Diverse NP analytical characterization methods are used (ICP-MS, dynamic light scattering and electron microscopy coupled to energy-dispersive X-ray analysis). As regards effect indicators, a methodology has been developed to assess a range of 29 cytokines in EBCs (potential respiratory inflammation due to NP exposure). Secondly, collaboration between the LBM laboratory and the EDyp team has allowed the EBC proteome to be characterized by means of an LC-MS/MS process. These projects are expected to facilitate the development of individual NP exposure biomonitoring tools and the analysis of early potential impacts on health. Innovative techniques such as field-flow fractionation combined with ICP-MS and single particle-ICPMS are currently being explored. These tools are directly intended to assist occupational physicians in the identification of exposure situations.

  11. Tillandsia usneoides L, a biomonitor in the determination of Ce, La and Sm by neutron activation analysis in an industrial corridor in Central Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Isaac-Olive, K. [Facultad de Medicina. Universidad Autonoma del Estado de Mexico, Paseo Tollocan s/n, esq. Jesus Carranza, Toluca, 50120 Estado de Mexico (Mexico); Solis, C., E-mail: corina@fisica.unam.mx [Instituto de Fisica, Universidad Nacional Autonoma de Mexico, 04510 Mexico DF (Mexico); Martinez-Carrillo, M.A; Andrade, E. [Instituto de Fisica, Universidad Nacional Autonoma de Mexico, 04510 Mexico DF (Mexico); Lopez, C.; Longoria, L.C. [Instituto Nacional de Investigaciones Nucleares (ININ), Salazar, 50045 Estado de Mexico (Mexico); Lucho-Constantino, C.A. [Universidad Politecnica de Pachuca, Carretera Pachuca-Cd. Sahagun, Km. 20., Hidalgo, Mexico (Mexico); Beltran-Hernandez, R.I. [Centro de Investigaciones Quimicas, Universidad Autonoma del Estado de Hidalgo. Carretera Pachuca-Tulancingo km. 4.5, 42184, Pachuca, Hidalgo (Mexico)

    2012-04-15

    The atmosphere of the Tula Industrial Corridor in Central Mexico is contaminated due to several industries including oil refining while station monitoring in this area are limited. Lanthanides are considered fingerprint of oil refinery activities, and La, Ce and Sm have been previously detected in this area using filters. The suitability of T. usneoides as a biomonitor assessing the La, Ce and Sm concentrations in Particulate Matter is evaluated by NAA. Results of both biomonitor and filters are highly correlated.

  12. Human semen as an early, sensitive biomarker of highly polluted living environment in healthy men: A pilot biomonitoring study on trace elements in blood and semen and their relationship with sperm quality and RedOx status.

    Science.gov (United States)

    Bergamo, Paolo; Volpe, Maria Grazia; Lorenzetti, Stefano; Mantovani, Alberto; Notari, Tiziana; Cocca, Ennio; Cerullo, Stefano; Di Stasio, Michele; Cerino, Pellegrino; Montano, Luigi

    2016-12-01

    The Campania region in Italy is facing an environmental crisis due to the illegal disposal of toxic waste. Herein, a pilot study (EcoFoodFertility initiative) was conducted to investigate the use of human semen as an early biomarker of pollution on 110 healthy males living in various areas of Campania with either high or low environmental impact. The semen from the "high impact" group showed higher zinc, copper, chromium and reduced iron levels, as well as reduced sperm motility and higher sperm DNA Fragmentation Index (DFI). Redox biomarkers (total antioxidant capacity, TAC, and glutathione, GSH) and the activity of antioxidant enzymes in semen were lower in the "high impact" group. The percentage of immotile spermatozoa showed a significant inverse correlation with TAC and GSH. Overall, several semen parameters (reduced sperm quality and antioxidant defenses, altered chemical element pattern), which were associated with residence in a high polluted environment, could be used in a further larger scale study, as early biomarkers of environmental pollution.

  13. Foote Brook Macroinvertebrate Biomonitoring-Phase I in Johnson, Vermont

    Data.gov (United States)

    Vermont Center for Geographic Information — The Foote Brook Biomonitoring Project, Phase I geospatial dataset consists of data from the biomonitoring of benthic macroinvertebrates at three sites located along...

  14. Evaluating the effects of China's pollution control on inter-annual trends and uncertainties of atmospheric mercury emissions

    Science.gov (United States)

    Zhao, Y.; Zhong, H.; Zhang, J.; Nielsen, C. P.

    2014-10-01

    China's atmospheric mercury (Hg) emissions of anthropogenic origin have been effectively restrained through the national policy of air pollution control. Improved methods based on available field measurements are developed to quantify the benefits of Hg abatement through various emission control measures. Those measures include increased use of flue gas desulfurization (FGD) and selective catalyst reduction (SCR) systems for power sector, precalciners with fabric filter (FF) for cement production, machinery coking with electrostatic precipitator (ESP) for iron and steel production, and advanced manufacturing technologies for nonferrous metal smelting. Declining trends in emissions factors for those sources are revealed, leading to a much slower growth of national total Hg emissions than that of energy and economy, from 679 in 2005 to 750 metric tons (t) in 2012. In particular, nearly half of emissions from the above-mentioned four types of sources are expected to be reduced in 2012, attributed to expansion of technologies with high energy efficiencies and air pollutant removal rates after 2005. The speciation of Hg emissions keeps stable for recent years, with the mass fractions of around 55, 39 and 6% for Hg0, Hg2+ and Hgp, respectively. The lower estimate of Hg emissions than previous inventories is supported by limited chemistry simulation work, but middle-to-long term observation on ambient Hg levels is further needed to justify the inter-annual trends of estimated Hg emissions. With improved implementation of emission controls and energy saving, 23% reduction in annual Hg emissions for the most optimistic case in 2030 is expected compared to 2012, with total emissions below 600 t. While Hg emissions are evaluated to be gradually constrained, increased uncertainties are quantified with Monte-Carlo simulation for recent years, particularly for power and certain industrial sources. The uncertainty of Hg emissions from coal-fired power plants, as an example

  15. Evaluating the effects of China's pollution control on inter-annual trends and uncertainties of atmospheric mercury emissions

    Directory of Open Access Journals (Sweden)

    Y. Zhao

    2014-10-01

    Full Text Available China's atmospheric mercury (Hg emissions of anthropogenic origin have been effectively restrained through the national policy of air pollution control. Improved methods based on available field measurements are developed to quantify the benefits of Hg abatement through various emission control measures. Those measures include increased use of flue gas desulfurization (FGD and selective catalyst reduction (SCR systems for power sector, precalciners with fabric filter (FF for cement production, machinery coking with electrostatic precipitator (ESP for iron and steel production, and advanced manufacturing technologies for nonferrous metal smelting. Declining trends in emissions factors for those sources are revealed, leading to a much slower growth of national total Hg emissions than that of energy and economy, from 679 in 2005 to 750 metric tons (t in 2012. In particular, nearly half of emissions from the above-mentioned four types of sources are expected to be reduced in 2012, attributed to expansion of technologies with high energy efficiencies and air pollutant removal rates after 2005. The speciation of Hg emissions keeps stable for recent years, with the mass fractions of around 55, 39 and 6% for Hg0, Hg2+ and Hgp, respectively. The lower estimate of Hg emissions than previous inventories is supported by limited chemistry simulation work, but middle-to-long term observation on ambient Hg levels is further needed to justify the inter-annual trends of estimated Hg emissions. With improved implementation of emission controls and energy saving, 23% reduction in annual Hg emissions for the most optimistic case in 2030 is expected compared to 2012, with total emissions below 600 t. While Hg emissions are evaluated to be gradually constrained, increased uncertainties are quantified with Monte-Carlo simulation for recent years, particularly for power and certain industrial sources. The uncertainty of Hg emissions from coal-fired power plants, as an

  16. The bioindicative potential evaluation of Tabebuia alba (Cham. Sandwith, Bignoniaceae, in urban atmospheric pollution

    Directory of Open Access Journals (Sweden)

    César Vinícius Carvalheiro

    2013-08-01

    Full Text Available This study aimed to evaluate the existence of leaf anatomic characteristics in Tabebuia alba changed by air pollutants, which could be used as tool for a bioindication program. The quantification of mutagenic events on pollen grains also were measured. For this, median leaves and pre-anthesis flowers were collected from the adult plants from three places of Curitiba and one place in Araucaria, all nearby to the air monitoring stations. The comparison of the four study sites showed a reduction in leaf area, an increasing of stomatal density, subepidermic layer, epidermis in both faces and the amount of micronucleus. Also, there was reduction of chlorophyllian parenchymas at the site where there was the higher average for the ozone level. It was concluded that these modifications might be a consequence of the effect of troposferic pollution on T. alba plants. However, further studies with this species would be necessary to confirm its potential for bioindication.

  17. Lidar Monitoring of Mexico City's Atmosphere During High Air Pollution Episodes

    Science.gov (United States)

    Quick, C. R., Jr.; Archuleta, F. L.; Hof, D. E.; Karl, R. R., Jr.; Tiee, J. J., Jr.; Eichinger, W. E.; Holtkamp, D. B.; Tellier, L.

    1992-01-01

    Over the last two decades, Mexico City, like many large industrial and populous urban areas, has developed a serious air pollution problem, especially during the winter months when there are frequent temperature inversions and weak winds. The deteriorating air quality is the result of several factors. The basin within which Mexico City lies in Mexico's center of political, administrative and economic activity, generating 34 percent of the gross domestic product and 42 percent of the industrial revenue, and supporting a population which is rapidly approaching the 20 million mark. The basin is surrounded by mountains on three sides which end up preventing rapid dispersal of pollutants. Emissions from the transportation fleet (more than 3 million vehicles) are one of the primary pollution sources, and most are uncontrolled. Catalytic converters are just now working their way into the fleet. The Mexico City Air Quality Research Initiative in an international collaboration project between the Los Alamos National Laboratory and the Mexican Petroleum Institute are dedicated to the investigation of the air quality problem in Mexico City. The main objective of the project is to identify and assess the cost and benefits of major options being proposed to improve the air quality. The project is organized into three main activity areas: (1) modeling and simulation; (2) characterization and measurements; and (3) strategic evaluation.

  18. Bioindication of atmospheric trace metals--with special references to megacities.

    Science.gov (United States)

    Markert, Bernd; Wuenschmann, Simone; Fraenzle, Stefan; Graciana Figueiredo, Ana Maria; Ribeiro, Andreza P; Wang, Meie

    2011-01-01

    After considering the particular problems of atmospheric pollution in megacities, i.e. agglomerations larger than 5 mio. inhabitants, with urbanization of World's population going on steadily, possibilities of active biomonitoring by means of green plants are discussed. Based on specific definitions of active and passive bioindication the chances of monitoring heavy metals in Sao Paulo megacity were demonstrated (first results published before). This is to show that there is need for increased use of bioindication to tackle the particular problems of megacities concerning environmental "health", the data to be processed according to the Multi-Markered-Bioindication-Concept (MMBC). Comparison to other work shows this approach to be reasonable.

  19. L'IIASA and the integrated simulation of the trans-border atmospheric pollution assessment and evaluation; L'IIASA et la modelisation integree de la pollution atmospherique transfrontiere. Bilan et evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Soleille, S.; Brignon, J.M.; Farret, R.; Landrieu, G.; Le Gall, A.C.; Rouil, L

    2003-09-15

    The RAINS model is an integrated evaluation model for many pollutants and many effects, developed by he IIASA. This model studies the emissions of 4 atmospheric pollutants (nitrogen oxides, sulfur oxides, ammonium and volatile organic compounds) and the necessary costs to reduce them and the dispersion of these pollutants and their effects (tropospheric ozone formation, acidification and eutrophication). The model can be used in activities scenario mode (energy, agriculture, transports...) to calculate the emissions and their effects or in optimization mode to calculate strategies of emissions control from environmental constraints. (A.L.B.)

  20. Current and future levels of mercury atmospheric pollution on a global scale

    NARCIS (Netherlands)

    Steenhuisen, Frits

    2016-01-01

    An assessment of current and future emissions, air concentrations, and atmospheric deposition of mercury worldwide is presented on the basis of results obtained during the performance of the EU GMOS (Global Mercury Observation System) project. Emission estimates for mercury were prepared with the ma

  1. Current and future levels of mercury atmospheric pollution on global scale

    NARCIS (Netherlands)

    Pacyna, Jozef M.; Travnikov, Oleg; De Simone, Francesco; Hedgecock, Ian M.; Sundseth, Kyrre; Pacyna, Elisabeth G.; Steenhuisen, Frits; Pirrone, Nicola; Munthe, John; Kindbom, Karin

    2016-01-01

    An assessment of current and future emissions, air concentrations and atmospheric deposition of mercury world-wide are presented on the basis of results obtained during the performance of the EU GMOS (Global Mercury Observation System) project. Emission estimates for mercury were prepared with the m

  2. Air Pollution.

    Science.gov (United States)

    Barker, K.; And Others

    Pollution of the general environment, which exposes an entire population group for an indeterminate period of time, certainly constitutes a problem in public health. Serious aid pollution episodes have resulted in increased mortality and a possible relationship between chronic exposure to a polluted atmosphere and certain diseases has been…

  3. Early atmospheric metal pollution provides evidence for Chalcolithic/Bronze Age mining and metallurgy in Southwestern Europe.

    Science.gov (United States)

    Martínez Cortizas, Antonio; López-Merino, Lourdes; Bindler, Richard; Mighall, Tim; Kylander, Malin E

    2016-03-01

    Although archaeological research suggests that mining/metallurgy already started in the Chalcolithic (3rd millennium BC), the earliest atmospheric metal pollution in SW Europe has thus far been dated to ~3500-3200 cal.yr. BP in paleo-environmental archives. A low intensity, non-extensive mining/metallurgy and the lack of appropriately located archives may be responsible for this mismatch. We have analysed the older section (>2100 cal.yr. BP) of a peat record from La Molina (Asturias, Spain), a mire located in the proximity (35-100 km) of mines which were exploited in the Chalcolithic/Bronze Age, with the aim of assessing evidence of this early mining/metallurgy. Analyses included the determination of C as a proxy for organic matter content, lithogenic elements (Si, Al, Ti) as markers of mineral matter, and trace metals (Cr, Cu, Zn, Pb) and stable Pb isotopes as tracers of atmospheric metal pollution. From ~8000 to ~4980 cal.yr. BP the Pb composition is similar to that of the underlying sediments (Pb 15 ± 4 μg g(-1); (206)Pb/(207)Pb 1.204 ± 0.002). A sustained period of low (206)Pb/(207)Pb ratios occurred from ~4980 to ~2470 cal.yr. BP, which can be divided into four phases: Chalcolithic (~4980-3700 cal.yr. BP), (206)Pb/(207)Pb ratios decline to 1.175 and Pb/Al ratios increase; Early Bronze Age (~3700-3500 cal.yr. BP), (206)Pb/(207)Pb increase to 1.192 and metal/Al ratios remain stable; Late Bronze Age (~3500-2800 cal.yr. BP), (206)Pb/(207)Pb decline to their lowest values (1.167) while Pb/Al and Zn/Al increase; and Early Iron Age (~2800-2470 cal.yr. BP), (206)Pb/(207)Pb increase to 1.186, most metal/Al ratios decrease but Zn/Al shows a peak. At the beginning of the Late Iron Age, (206)Pb/(207)Pb ratios and metal enrichments show a rapid return to pre-anthropogenic values. These results provide evidence of regional/local atmospheric metal pollution triggered by the earliest phases of mining/metallurgy in the area, and reconcile paleo-environmental and

  4. Detection Method of Atmospheric Pollution and Pollution Control Measures%大气污染源的检测方法及污染物控制措施

    Institute of Scientific and Technical Information of China (English)

    罗鹏

    2014-01-01

    Industry is developing rapidly in our country, the air polution geting worse, seriously affects the safety of peo- ple’s health. The main measures to control the air pollution is to accurately find sources of polution, and effective control polutant, its the only way to fundamentaly reduce the air polution degree. Thus, in this paper, the atmospheric polution source detection method and polutant control measures were analyzed, for reference.%我国工业迅速发展,空气污染不断加重,严重影响了人们的健康安全。治理空气污染的主要措施是,准确找到污染源,并对污染物进行有效控制,只有这样才能从根本上降低空气污染程度。以此,本文就大气污染源的检测方法及污染物控制措施进行分析,以供参考。

  5. Biomonitoring of bees. Upgrading of electronic monitoring of thermal power plants

    Energy Technology Data Exchange (ETDEWEB)

    Cuhalev, I.; Rajh-Alatic, Z. [Electroinstitute Ljubljana (Slovakia)

    1995-12-31

    Environmental monitoring of the air quality associates procedures whose task is to acquire data about the measurement of the polluted air in the real time and on-line mode. Air quality measurements are made at the point of the measurement site which is the most exposed to pollution. Apart from the point measurements, there are also line measurements carried out. They are made in a particular area where they provide better results about the environmental pollution. Data that are obtained in this way provide the basis for adequate procedures for the air protection. The effect of noxious substances from the air on living organisms under laboratory conditions is known to a certain degree. The real extent of the effect of the air pollution under existing conditions in a particular area and time can only be established with biomonitoring. One of its most frequent forms is observation of a particular plant specimen which is sensitive to some noxious components from the air. Biomonitoring of plants provides data about the complex pollution stress to which an observed plant is exposed. It covers a certain time period and gives point results of an area. To get a complete insight into the effect of the pollution stress in an area biomonotoring was expanded onto bees

  6. Investigating Incursion of Transboundary Pollution into the Atmosphere of Dhaka, Bangladesh

    Directory of Open Access Journals (Sweden)

    Md. Masud Rana

    2016-01-01

    Full Text Available Concentrations of particulate matter (PM in Dhaka, Bangladesh, during November 2013 to April 2014 were found 7-8 times higher than the World Health Organization (WHO guideline value. Probability of contribution of transboundary sources to this PM pollution was investigated through different approaches. Ninety-six-hour backward trajectories with every 3-hour interval were computed and clustered into 06 groups based on angle distance matrix. Probabilities of individual cluster to be associated with different ranges of coarse and fine particles were studied. Gazipur station near Dhaka city was found to have 68% probability of receiving PM10 concentration higher than 150 μg/m3 when air masses followed the route of Middle East through the Himalayan valley to the station. This channel was identified as the main route of PM transport to Bangladesh during dry season. Transboundary source-regions were spotted by concentration weighted trajectory (CWT method and also by the monthly average aerosol optical depths (AOD over South Asia. North-western Indian regions, Nepal and its neighboring areas, and Indian state of West Bengal were identified as the most probable zones that might have contributed to PM pollution in Gazipur, Dhaka. November to January was the high time the station had experienced fine particles from those transboundary regions.

  7. Modelling pollutants dispersion and plume rise from large hydrocarbon tank fires in neutrally stratified atmosphere

    Science.gov (United States)

    Argyropoulos, C. D.; Sideris, G. M.; Christolis, M. N.; Nivolianitou, Z.; Markatos, N. C.

    2010-02-01

    Petrochemical industries normally use storage tanks containing large amounts of flammable and hazardous substances. Therefore, the occurrence of a tank fire, such as the large industrial accident on 11th December 2005 at Buncefield Oil Storage Depots, is possible and usually leads to fire and explosions. Experience has shown that the continuous production of black smoke from these fires due to the toxic gases from the combustion process, presents a potential environmental and health problem that is difficult to assess. The goals of the present effort are to estimate the height of the smoke plume, the ground-level concentrations of the toxic pollutants (smoke, SO 2, CO, PAHs, VOCs) and to characterize risk zones by comparing the ground-level concentrations with existing safety limits. For the application of the numerical procedure developed, an external floating-roof tank has been selected with dimensions of 85 m diameter and 20 m height. Results are presented and discussed. It is concluded that for all scenarios considered, the ground-level concentrations of smoke, SO 2, CO, PAHs and VOCs do not exceed the safety limit of IDLH and there are no "death zones" due to the pollutant concentrations.

  8. Measurements and modelling of atmospheric pollution over the Paris area: an overview of the ESQUIF project

    Energy Technology Data Exchange (ETDEWEB)

    Menut, L.; Vautard, R.; Flamant, P.H. [Centre National de Recherche Scientifique (CNRS), 75 - Paris (France). Lab. de Meteorologie Dynamique; Flamant, C.; Beekmann, M.; Megie, G.; Sicard, M. [Centre National de la Recherche Scientifique (CNRS), 91 - Verrieres-le-Buisson (France). Service d' Aeronomie; Abonnel, C.; Lefebvre, M.P.; Lossec, B. [Meteo-France, 75 - Paris (France); Chazette, P.; Martin, D. [CNRS (France). Lab. des Sciences du Climat et de l' Environnement; Gombert, D. [AIRPARIF, Paris (France); Guedalia, D. [CNRS-Universite Paul Sabatier (France). Lab. d' Aerologie; Kley, D. [Forschungszentrum Juelich GmbH (Germany); Perros, P.; Toupance, G. [CNRS (France). Lab. Interuniversitaire des Systemes Atmospheriques

    2000-11-01

    The ''etude et simulation de la qualite de l'air en ile de France'' (ESQUIF) project is the first integrated project dedicated to the study of the processes leading to air pollution events over the Paris area. The project was carried out over two years (summer 1998 to winter 2000) to document all types of meteorological conditions favourable to air quality degradation, and in particular to photo oxydant formation. The goals of ESQUIF are (1) to improve our understanding of the relevant chemical and dynamical processes and, in turn, improve their parametrizations in numerical models, and (2) to improve and validate existing models dedicated to pollution analysis, scenarios and/or forecasting, by establishing a comprehensive and thorough database. We present the rationale of the ESQUIF project and we describe the experimental set-up. We also report on the first experiments which took place during the summer of 1998 involving surface networks, and remote sensing instruments as well as several aircraft. Focusing on three days of August 1998, the relative contributions of long-range transported and locally-produced ozone to the elevated ozone concentrations observed during this period are discussed and chemistry-transport model preliminary results on this period are compared to measurements. (orig.)

  9. Total reflection X-ray fluorescence analysis of pollen as an indicator for atmospheric pollution*1

    Science.gov (United States)

    Pepponi, G.; Lazzeri, P.; Coghe, N.; Bersani, M.; Gottardini, E.; Cristofolini, F.; Clauser, G.; Torboli, A.

    2004-08-01

    The viability of pollen is affected by environmental pollution and its use as a bio-indicator is proposed. Such effects can be observed and quantified by biological tests. However, a more accurate identification of the agents affecting the viability is required in order to validate the biological assay for environmental monitoring. The chemical analysis of pollen is meant to ascertain the existence of a correlation between its reduced biological functions and the presence of pollutants. Moreover, such biological systems act as accumulators and allow the detection and quantification of species present in the environment at low concentrations. Total reflection X-ray fluorescence analysis (TXRF) has been chosen for the investigation due to its high sensitivity, multielement capability and wide dynamic range. Corylus avellana L. (hazel) pollen has been collected in areas with different anthropic impact in the province of Trento, Italy. For the TXRF measurements, a liquid sample is needed, especially if a quantitative analysis is required. In the present work, the analysis after a microwave digestion has been compared with the analysis of a suspension of the pollen samples. In both cases, an internal standard has been used for the quantification. The concentrations of 17 elements ranging from Al to Pb have been determined in 13 samples. Analysis of the suspensions showed to be comparable to that of digested samples in terms of spectral quality, but the latter preparation method gave better reproducibility. Sub-ppm lowest limits of detection were obtained for iron and heavier elements detected.

  10. An advanced open-path atmospheric pollution monitor for large areas

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, L. [Westinghouse Science & Technology Center, Pittsburgh, PA (United States)

    1995-10-01

    Large amounts of toxic waste materials, generated in manufacturing fuel for nuclear reactors, are stored in tanks buried over large areas at DOE sites. Flammable and hazardous gases are continually generated by chemical reactions in the waste materials. To prevent explosive concentrations of these gases, the gases are automatically vented to the atmosphere when the pressure exceeds a preset value. Real-time monitoring of the atmosphere above the tanks with automatic alarming is needed to prevent exposing workers to unsafe conditions when venting occurs. This report describes the development of a monitor which can measure concentrations of hazardous gases over ranges as long as 4km. The system consists of a carbon dioxide laser combined with an acousto-optic tunable filter.

  11. Causes of change in nitrophytic and oligotrophic lichen species in a Mediterranean climate: Impact of land cover and atmospheric pollutants

    Energy Technology Data Exchange (ETDEWEB)

    Pinho, P.; Augusto, S.; Martins-Loucao, M.A. [Faculdade de Ciencias, Centro de Ecologia e Biologia Vegetal, Universidade de Lisboa, edificio C4, 1749-016 Lisbon (Portugal); Pereira, M.J.; Soares, A. [Instituto Superior Tecnico, Universidade Tecnica de Lisboa, Cerena, Av. Rovisco Pais, 1049-001 Lisbon (Portugal); Maguas, C. [Faculdade de Ciencias, Centro de Ecologia e Biologia Vegetal, Universidade de Lisboa, edificio C4, 1749-016 Lisbon (Portugal); Branquinho, C. [Faculdade de Ciencias, Centro de Ecologia e Biologia Vegetal, Universidade de Lisboa, edificio C4, 1749-016 Lisbon (Portugal); Antiga Fabrica da Polvora de Barcarena, Universidade Atlantica, 2745-615 Barcarena (Portugal)], E-mail: cmbranquinho@fc.ul.pt

    2008-08-15

    With the aim of determining the main drivers of changes in nitrophytic and oligotrophic macro-lichen communities in an industrial region with a Mediterranean climate, we considered both land-cover types and atmospheric pollutants. We determined the relation between the abundance of nitrophytic and oligotrophic species with environmental factors considering the distance of influence of land-cover types. The results showed that oligotrophic species decreased in the proximity of artificial areas, barren land and agricultural areas, associated with higher concentrations of NO{sub 2} and Zn, and Ti, probably dust of industrial and agricultural origin. Nitrophytic species were positively related to all the mentioned land-cover types, and with higher concentrations of Fe and N. Magnesium, probably from ocean aerosols, was negatively related to oligotrophic species and positively to nitrophytic. - Causes of change in nitrophytic and oligotrophic lichen species.

  12. EFFECT OF CHLORIDE ON THE ATMOSPHERIC CORROSION OF SIMULATED ARTIFACT IRON IN NO3-BEARING POLLUTANT ENVIRONMENT

    Institute of Scientific and Technical Information of China (English)

    X. Cao; C.C. Xu

    2006-01-01

    The effect of chloride in nitrogen-bearing pollutant on the atmospheric corrosion of cast iron was investigated by using periodic wet-dry test, electrochemical experiment and surface tension test.Scanning electron microscopy (SEM) with energy disperse atomic X-ray (EDAX) was used to identify the corrosion processes and products. The results of the weight loss measurement showed that the whole corrosion kinetics can be approximately described by: AW=AtB. With the addition of NaC1, B increases. The result presented that Cl- accelerated the corrosion rate obviously during the whole corrosion process. The initial corrosion process was investigated from the viewpoint of surface tension. At the initial corrosion period, the corrosion rate was proportion to the adsorption of anions contained the solutions. And as corrosion went on, the penetration effect of anions and different characteristics of the corrosion products began to dominant the corrosion process, which led to the accelerated effect.

  13. 60 years of UK visibility measurements: impact of meteorology and atmospheric pollutants on visibility

    OpenAIRE

    Singh, Ajit; Bloss, William J.; Pope, Francis D.

    2016-01-01

    Reduced visibility is an indicator of poor air quality. Moreover, degradation in visibility can be hazardous to human safety; for example, low visibility can lead to road, rail, sea and air accidents. In this paper, we explore the combined influence of atmospheric aerosol particle and gas characteristics, and meteorology, on long-term visibility. We use visibility data from eight meteorological stations, situated in the UK, which have been running since the 1950s. The site locations include u...

  14. Numerical Approach to the Evaluation of Atmospheric Pollution by Combustion Products of Solid Fuels

    Directory of Open Access Journals (Sweden)

    Gvozdyakov Dmitry

    2016-01-01

    Full Text Available This research presents the results of mathematical modeling of acid rain formation and its fallout in the areas adjacent to the site of the energy complex. Four thermal periods that are typical for regions of sharply continental climate has been considered. The influence of convective parameters on the formation mechanism of atmospheric precipitation has been estimated. The contribution of solar energy flux to the research process has been analyzed.

  15. Atmospheric phenanthrene pollution modulates carbon allocation in red clover (Trifolium pratense L.)

    Energy Technology Data Exchange (ETDEWEB)

    Desalme, Dorine, E-mail: dorine.desalme@univ-fcomte.fr [Universite de Franche-Comte, CNRS, UMR 6249, Chrono-environnement, BP 71427, F-25211 Montbeliard Cedex (France); Binet, Philippe [Universite de Franche-Comte, CNRS, UMR 6249, Chrono-environnement, BP 71427, F-25211 Montbeliard Cedex (France); Epron, Daniel [Nancy Universite, UMR 1137, Ecologie et Ecophysiologie Forestieres, Faculte des Sciences, BP 70239, F- 54506 Vandoeuvre-les-Nancy Cedex (France); INRA, UMR 1137, Ecologie et Ecophysiologie Forestieres, Centre INRA de Nancy, F- 54280 Champenoux (France); Bernard, Nadine; Gilbert, Daniel; Toussaint, Marie-Laure [Universite de Franche-Comte, CNRS, UMR 6249, Chrono-environnement, BP 71427, F-25211 Montbeliard Cedex (France); Plain, Caroline [Nancy Universite, UMR 1137, Ecologie et Ecophysiologie Forestieres, Faculte des Sciences, BP 70239, F- 54506 Vandoeuvre-les-Nancy Cedex (France); INRA, UMR 1137, Ecologie et Ecophysiologie Forestieres, Centre INRA de Nancy, F- 54280 Champenoux (France); Chiapusio, Genevieve, E-mail: genevieve.chiapusio@univ-fcomte.fr [Universite de Franche-Comte, CNRS, UMR 6249, Chrono-environnement, BP 71427, F-25211 Montbeliard Cedex (France)

    2011-10-15

    The influence of atmospheric phenanthrene (PHE) exposure (160 {mu}g m{sup -3}) during one month on carbon allocation in clover was investigated by integrative (plant growth analysis) and instantaneous {sup 13}CO{sub 2} pulse-labelling approaches. PHE exposure diminished plant growth parameters (relative growth rate and net assimilation rate) and disturbed photosynthesis (carbon assimilation rate and chlorophyll content), leading to a 25% decrease in clover biomass. The root-shoot ratio was significantly enhanced (from 0.32 to 0.44). Photosynthates were identically allocated to leaves while less allocated to stems and roots. PHE exposure had a significant overall effect on the {sup 13}C partitioning among clover organs as more carbon was retained in leaves at the expense of roots and stems. The findings indicate that PHE decreases root exudation or transfer to symbionts and in leaves, retains carbon in a non-structural form diverting photosynthates away from growth and respiration (emergence of an additional C loss process). - Highlights: > Atmospheric PHE decreased growth, biomass partitioning and C allocation in clover. > C allocation was modified in favor of leaves but at the expense of roots and stems. > In roots, a decreased carbon exudation or allocation to symbionts was proposed. > In leaves, carbon was retained in a non-structural form as secondary metabolites. > BVOC emission was suggested as another loss process than respiration and exudation. - Exposure of clover to atmospheric PHE affected not only its growth, but also biomass partitioning and C allocation among its organs.

  16. Atmospheric pollutant and other data from the TRIDENT and tower as part of the International Decade of Ocean Exploration (IDOE) from 01 February 1972 to 01 September 1972 (NODC Accession 7300574)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Atmospheric pollutant and other data were collected from the TRIDENT and tower from 01 February 1972 to 01 September 1972. Data include trace metals in the...

  17. Progress report for the project: Comparison of the response of mature branches and seedlings of Pinus ponderosa to atmospheric pollution

    Energy Technology Data Exchange (ETDEWEB)

    Houpis, J.L.J.; Anderson, P.D.; Benes, S.E.; Phelps, S.P.; Loeffler, A.T.

    1990-09-01

    This progress report details Lawrence Livermore National Laboratory's (LLNL) performance regarding the projects Comparison of the Response of Mature Branches and Seedlings of Pinus ponderosa to Atmospheric Pollution'' and Effects of Ozone, acid Precipitation, and Their Interactions on Mature Branches and Seedlings of Ponderosa Pine'' for the months of November 1989 to June 1990. During the last eight months, we have initiated ozone and acid precipitation exposures, and we began intensive growth, morphological, and physiological measurements. During these major physiological measurement periods, we measured photosynthesis, transpiration, stomatal conductance, respiration, antioxidant activity, pigmentation, and foliar nutrient concentration. We have also concluded the analysis of our branch autonomy experiment, which we conducted in the fall. We determined that virtually no carbon is exported among branches in close proximity to one another. This conclusion assists in validating the approach of using branches and branch exposure chambers as a means of assessing the effects of air pollution on mature trees of Ponderosa pine. 6 refs., 4 figs., 3 tabs.

  18. Development of a Passive Doas System to Retrieve Atmospheric Pollution Columns in the 200 to 355 nm Region

    Directory of Open Access Journals (Sweden)

    Rubén Galicia Mejía

    2013-01-01

    Full Text Available In recent years several techniques have been developed to measure and monitor the pollution of the air. Among these techniques, remote sensing using optical methods stands out due to several advantages for air quality control applications. A Passive Differential Optical Absorption Spectroscopy system that uses the ultraviolet region from 200 to 355 nm of the solar radiation is presented. The developed system is portable; therefore it is practical for real time and in situ measurements. The enhanced wavelength range of the system is intended to detect the ultraviolet light penetration in the Mexican Valley considering the solar zenith angle and the altitude. The system was applied to retrieve atmospheric SO2 columns emitted either by anthropogenic (power plant or natural sources (volcano, reaching a detection limit of about 1 ppm. The measurement of the penetrating solar radiation on the earth surface at the UVC range is presented and the possibility to measure pollution traces of some contaminants as O3, NO2 and aromatic compounds in real time and in situ in the ultraviolet region is discussed.

  19. Development of a passive doas system to retrieve atmospheric pollution columns in the 200 to 355 nm region

    Directory of Open Access Journals (Sweden)

    Mejía Rubén Galicia

    2013-01-01

    Full Text Available Abstract In recent years several techniques have been developed to measure and monitor the pollution of the air. Among these techniques, remote sensing using optical methods stands out due to several advantages for air quality control applications. A Passive Differential Optical Absorption Spectroscopy system that uses the ultraviolet region from 200 to 355 nm of the solar radiation is presented. The developed system is portable; therefore it is practical for real time and in situ measurements. The enhanced wavelength range of the system is intended to detect the ultraviolet light penetration in the Mexican Valley considering the solar zenith angle and the altitude. The system was applied to retrieve atmospheric SO2 columns emitted either by anthropogenic (power plant or natural sources (volcano, reaching a detection limit of about 1 ppm. The measurement of the penetrating solar radiation on the earth surface at the UVC range is presented and the possibility to measure pollution traces of some contaminants as O3, NO2 and aromatic compounds in real time and in situ in the ultraviolet region is discussed.

  20. [Analysis and assessment of atmospheric pollution based on accumulation characterization of heavy metals in Platanus acerifolia leaves].

    Science.gov (United States)

    Liu, Ling; Fang, Yan-Ming; Wang, Shun-Chang; Xie, Ying; Wang, Cheng-Run

    2014-03-01

    The present work was aimed to evaluate the heavy metal pollution in the atmosphere of Huainan City. We measured and clustered the accumulation of six heavy metals in Platanus acerifolia leaves in 20 sampling fields with six types of environmental conditions, and analyzed the EF value of heavy metal enrichment in the leaves. The results showed that the accumulations in Platanus acerifolia leaves varied according to different types of metals, following the order of Zn > Cu > Cr > Ni > Pb > Cd. Environmental conditions also had great influence on the accumulation of heavy metals. Cd and Cu were mostly found in cement plant and mine, respectively, and Cr, Ni, Pb and Zn were significant higher in main road, compared with other environmental conditions. The average values of EF for all the metals expect Cr in scenic and village area were over 1. The average values of EF for all the metals in mine, power plant, main road and cement plant were above 3. The overall pollution condition of heavy metals in Huainan City followed the order of Cd > Cu > Zn > Ni > Pb > Cr.

  1. Estimating the influence of different urban canopy cover types on atmospheric particulate matter (PM10) pollution abatement in London UK.

    Science.gov (United States)

    Tallis, Matthew; Freer-Smith, Peter; Sinnett, Danielle; Aylott, Matthew; Taylor, Gail

    2010-05-01

    In the urban environment atmospheric pollution by PM10 (particulate matter with a diameter less than 10 x 10-6 m) is a problem that can have adverse effects on human health, particularly increasing rates of respiratory disease. The main contributors to atmospheric PM10 in the urban environment are road traffic, industry and power production. The urban tree canopy is a receptor for removing PM10s from the atmosphere due to the large surface areas generated by leaves and air turbulence created by the structure of the urban forest. In this context urban greening has long been known as a mechanism to contribute towards PM10 removal from the air, furthermore, tree canopy cover has a role in contributing towards a more sustainable urban environment. The work reported here has been carried out within the BRIDGE project (SustainaBle uRban plannIng Decision support accountinG for urban mEtabolism). The aim of this project is to assess the fluxes of energy, water, carbon dioxide and particulates within the urban environment and develope a DSS (Decision Support System) to aid urban planners in sustainable development. A combination of published urban canopy cover data from ground, airborne and satellite based surveys was used. For each of the 33 London boroughs the urban canopy was classified to three groups, urban woodland, street trees and garden trees and each group quantified in terms of ground cover. The total [PM10] for each borough was taken from the LAEI (London Atmospheric Emissions Inventory 2006) and the contribution to reducing [PM10] was assessed for each canopy type. Deposition to the urban canopy was assessed using the UFORE (Urban Forest Effects Model) approach. Deposition to the canopy, boundary layer height and percentage reduction of the [PM10] in the atmosphere was assessed using both hourly meterological data and [PM10] and seasonal data derived from annual models. Results from hourly and annual data were compared with measured values. The model was then

  2. Chemical characteristics of atmospheric PM2.5 loads during air pollution episodes in Giza, Egypt

    Science.gov (United States)

    Hassan, Salwa K.; Khoder, Mamdouh I.

    2017-02-01

    Several types of pollution episodes, including dust storm (DSs), haze dust (HDs), straw rice combustions (SRCs) are common phenomena and represent severe environmental hazard in Egypt. This study provides the first comprehensive analysis of the chemical characteristics of aerosol during air pollution episodes at an urban area in Giza, Egypt. PM2.5 samples during various PM episodes during 2013-2014 were collected and analyzed. Results indicate that the highest PM2.5 mass concentrations were found during DSs (250 μg/m3), followed by HDs (130 μg/m3) and SRCs (103 μg/m3). Average PM2.5 mass concentrations were 1.91, 3.68 and 1.68 times higher than on normal days (NDs) during HDs, DSs and SRCs, respectively. The highest total water-soluble ions concentration was 61.1 μg/m3 during HDs, followed by SRCs (41.9 μg/m3) and DSs (35.2 μg/m3). SO42- is the most abundant chemical components on the three PM episodes. Secondary inorganic ions (NO3-, SO42-, and NH4+) were enriched during HDs. The total secondary inorganic ions concentrations were 3.17, 1.39 and 1.75 times higher than NDs during HDs days, DSs days and SRCs days, respectively. PM from SRCs showed high K+ and Cl-. SO42-/K+, NO3-/SO42- and Cl-/K+ ratios proved effective as indicators for different pollution episodes. A Ca2+/Al ratio indicates that soil dust was dominant during DSs. Ion balance calculations indicated that PM2.5 from HDs was acidic, while the DSs and SRCs particles were alkaline and the NDs particle's was nearly neutral. The total crustal and anthropogenic metals concentrations were higher in DSs than other PM episodes and normal days. The enrichment factors values in PM episodes and normal days indicate that Fe and Mn in NDs, HDs, DSs and SRCs as well as Cr and Ni in DSs come mainly from crustal sources, whereas Cr, Ni, Co, Cu, Zn, Pb and Cd in PM episodes and NDs are anthropogenic.

  3. A Global Modeling View on Long-range Transport of Atmospheric Pollutants

    Science.gov (United States)

    Schultz, M. G.; Bauer, H.; Brasseur, G. P.; Diehl, T.; Granier, C.

    2002-12-01

    The NASA-GTE TRACE-P intensive field campaign in spring 2001 aimed at the quantification of the export of pollutants from East Asia and an improved understanding of the chemical evolution of Asian outflow. Scientists from MPI-Met have participated in TRACE-P with global model forecasts of carbon monoxide tracer concentrations and tagged tracers, which allow the identification of source regions affecting the North Pacific ocean. We have since developed a new version of the global general circulation model ECHAM, and we performed multi-year simulations with the MOZART-2 chemistry transport model. In our presentation, we will compare results from both models with TRACE-P observations, and we will compare the spring 2001 period with those of other years in the 1990s. Effects of model resolution and specification of emission sources will be considered.

  4. [Atmospheric pollution and chronic respiratory diseases in the blast-furnace areas of iron-works].

    Science.gov (United States)

    Zannini, D; Valente, T; Rotunno, R; Giusto, R

    1977-01-01

    An epidemiologic research together with a study on the environmental pollution were carried out in order to evaluate the risk of chronic respiratory diseases of blast furnace workers. The environment study was performed mainly using personal samplers given to workers with different jobs. Observations on 222 work shifts have shown that the total dust concentration to which cast workmen, maintenance men and blast furnace service men were exposed, marginally exceed the TLV values. Furthermore the level of respirable dusts for blast furnace service men was found slightly excessive. The average SO2 concentration was largely below the TLV values. However this gas could be found in excess for very short periods during the work. The epidemiologic study, conducted on a cohort of blast furnace area workers against a control group cohort, indicated a moderate prevalence of pneumoconiosis and chronic bronchitis amongst blast furnaces workers. The clinic and radiological pictures do not seem to go beyond the initial stages.

  5. Breath acidification in adolescent runners exposed to atmospheric pollution: A prospective, repeated measures observational study

    Directory of Open Access Journals (Sweden)

    Van Sickle David

    2008-03-01

    Full Text Available Abstract Background Vigorous outdoors exercise during an episode of air pollution might cause airway inflammation. The purpose of this study was to examine the effects of vigorous outdoor exercise during peak smog season on breath pH, a biomarker of airway inflammation, in adolescent athletes. Methods We measured breath pH both pre- and post-exercise on ten days during peak smog season in 16 high school athletes engaged in daily long-distance running in a downwind suburb of Atlanta. The association of post-exercise breath pH with ambient ozone and particulate matter concentrations was tested with linear regression. Results We collected 144 pre-exercise and 146 post-exercise breath samples from 16 runners (mean age 14.9 years, 56% male. Median pre-exercise breath pH was 7.58 (interquartile range: 6.90 to 7.86 and did not change significantly after exercise. We observed no significant association between ambient ozone or particulate matter and post-exercise breath pH. However both pre- and post-exercise breath pH were strikingly low in these athletes when compared to a control sample of 14 relatively sedentary healthy adults and to published values of breath pH in healthy subjects. Conclusion Although we did not observe an acute effect of air pollution exposure during exercise on breath pH, breath pH was surprisingly low in this sample of otherwise healthy long-distance runners. We speculate that repetitive vigorous exercise may induce airway acidification.

  6. The study of atmospheric correction of satellite remotely sensed images intended for air pollution using sun-photometers (AERONET) and lidar system in Lemesos, Cyprus

    Science.gov (United States)

    Hadjimitsis, Diofantos G.; Themistocleous, Kyriacos; Nisantzi, Argyro; Matsas, Alexandros

    2010-10-01

    Solar radiation reflected by the Earth's surface to satellite sensors is modified by its interaction with the atmosphere. The objective of atmospheric correction is to determine true surface reflectance values by removing atmospheric effects from satellite images. Atmospheric correction is arguably the most important part of the pre-processing of satellite remotely sensed data. The most important parameter in applying any atmospheric correction is the aerosol optical thickness which is also used for assessing air pollution. This paper explores how the AOT is extracted from atmospheric corrected satellite imagery acquired from Landsat ETM + and how then AOT values are used to assess air pollution. The atmospheric correction algorihm developed by Hadjimitsis and Clayton (2009) is applied to short wavelengths like Landsat TM band 1 and 2 (0.45-0.52μm, 0.52-0.60 μm). The results are also assessed using Lidar system and Cimel Sunphotometer located in the premises of the Cyprus University of Technology in Limassol. The authors run the atmospheric correction developed by Hadjimitsis and Clayton (2009) in MATLAB and sample AOT results for the Landsat ETM+ images acquired on the 15/01/2010, 20/4/2010, 09/06/2010 are shown. For the Landsat ETM+ image acquired on 20/4/2010, the AOT was found 1.4 after the application of the atmospheric correction. Such value complies with the AOT value measured by the Cimel Sun-photometer (AERONET) during the satellite overpass. An example of how Lidar is used to assess the existing atmospheric conditions which is useful for assessing air pollution is also presented.

  7. A model employing integral transform method to simulate pollutant dispersion in atmosphere

    Directory of Open Access Journals (Sweden)

    Davidson Martins Moreira

    2013-12-01

    Full Text Available An updated version of the semi-analytical model for describing the steady-state concentration in the atmospheric boundary layer is presented here. Two inversion methods of the Laplace transform are tested: the Gaussian Quadrature scheme and the Fixed-Talbot method. The model takes into account settling velocity, removal (wet and dry deposition, and first order chemical reactions. The capability of the model to accurately predict the ground-level concentration is demonstrated qualitative and quantitatively. The results are in good agreement with experimental data.

  8. Role of sectoral and multi-pollutant emission control strategies in improving atmospheric visibility in the Yangtze River Delta, China.

    Science.gov (United States)

    Huang, Kan; Fu, Joshua S; Gao, Yang; Dong, Xinyi; Zhuang, Guoshun; Lin, Yanfen

    2014-01-01

    The Community Multi-scale Air Quality modeling system is used to investigate the response of atmospheric visibility to the emission reduction from different sectors (i.e. industries, traffic and power plants) in the Yangtze River Delta, China. Visibility improvement from exclusive reduction of NOx or VOC emission was most inefficient. Sulfate and organic aerosol would rebound if NOx emission was exclusively reduced from any emission sector. The most efficient way to improve the atmospheric visibility was proven to be the multi-pollutant control strategies. Simultaneous emission reductions (20-50%) on NOx, VOC and PM from the industrial and mobile sectors could result in 0.3-1.0 km visibility improvement. And the emission controls on both NOx (85%) and SO2 (90%) from power plants gained the largest visibility improvement of up to 4.0 km among all the scenarios. The seasonal visibility improvement subject to emission controls was higher in summer while lower in the other seasons.

  9. Spheroidal carbonaceous particles (SCPs) as indicators of atmospherically deposited pollutants in North African wetlands of conservation importance

    Science.gov (United States)

    Rose, N. L.; Flower, R. J.; Appleby, P. G.

    Wetlands and lowland lakes in the coastal region of North Africa are being lost at an alarming rate as a result of increasing human demands for water and land. Those remaining wetlands, which have not been severely degraded, support high value ecosystems that not only contribute to regional biodiversity but also provide important resources for local human populations. However, information on the current status of these sites and the rates and directions of trends in environmental change over recent decades is generally lacking. In particular, regional data on the inputs of atmospheric pollutants to these important sites are absent. As part of the EU (INCO-MED) funded CASSARINA project, sediment cores were taken from eight coastal lakes in Morocco, Tunisia and Egypt. Chronologies for these cores were produced primarily using radionuclides and all were analysed for spheroidal carbonaceous particles (SCPs). SCPs are produced only from high temperature fossil-fuel combustion and are thus unambiguous indicators of atmospheric deposition from industrial sources. SCP contamination trends appear to show a combination of influences from European and, more recently (post-1980), local North African sources. Contemporary data indicate contamination equivalent to that found in heavily impacted European mountain lakes or moderately impacted lowland lakes in the UK. Such levels of impact raise particular concerns over the future of Moroccan wetland lakes downwind of a recently expanded major coal-fired power station at Jorf Lasar.

  10. The application of magnetic measurements for the characterization of atmospheric particulate pollution within the airport environment.

    Science.gov (United States)

    Jones, S; Richardson, N; Bennett, M; Hoon, S R

    2015-01-01

    The significant increase in global air travel which has occurred during the last fifty years has generated growing concern regarding the potential impacts associated with increasing emissions of atmospheric particulate matter (PM) on health and the environment. PM within the airport environment may be derived from a range of sources. To date, however, the identification of individual sources of airport derived PM has remained elusive but constitutes a research priority for the aviation industry.The aim of this research was to identify distinctive and characteristic fingerprints of atmospheric PM derived from various sources in an airport environment through the use of environmental magnetic measurements. PM samples from aircraft engine emissions, brake wear and tire wear residues have been obtained from a range of different aircraft and engine types. Samples have been analyzed utilizing a range of magnetic mineral properties indicative of magnetic mineralogy and grain size. Results indicate that the dusts from the three 'aircraft' sources, (i.e. engines, brakes and tires) display distinctive magnetic mineral characteristics which may serve as 'magnetic fingerprints' for these sources. Magnetic measurements of runway dusts collected at different locations on the runway surface also show contrasting magnetic characteristics which, when compared with those of the aircraft-derived samples, suggest that they may relate to different sources characteristic of aircraft emissions at various stages of the take-off/landing cycle. The findings suggest that magnetic measurements could have wider applicability for the differentiation and identification of PM within the airport environment.

  11. Lichens as biomonitors around a coal-fired power station in Israel.

    Science.gov (United States)

    Garty, Jacob; Tomer, Sharon; Levin, Tal; Lehr, Haya

    2003-03-01

    In the present study epiphytic lichens were applied as biomonitors of air pollution to determine the environmental impact of a coal-fired power station. Thalli of the lichen Ramalina lacera (With.) J.R. Laund. growing on carob twigs (Ceratonia siliqua L.) were collected with their substrate in July 2000 in a relatively unpolluted forest near HaZorea, Ramoth Menashe, Northeast Israel, and transplanted to 10 biomonitoring sites in the vicinity of the coal-fired power station Oroth Rabin near the town of Hadera. The lichens were retrieved in January 2001. We examined the following parameters of lichen vitality: (a) potential quantum yield of photosynthesis expressed as fluorescence ratio F(v)/F(m), (b) stress-ethylene production, and (c) electric conductivity expressing integrity of cell membranes. Following an exposure of 7 months, the lichens were retrieved and physiological parameters and data of elemental content were analyzed comparatively. Electric conductivity values correlated positively with B, Fe, Mg, Mn, Na, Pb, S, Sn, and Ti content. Concentrations of stress-ethylene correlated positively with Al, Ba, Pb, S, and V content and negatively with Cu and Sn. F(v)/F(m) ratios correlated negatively with S content. Some of the heavy metals reached lower levels than those reported in the relevant literature despite a wind regime that should have blown pollutants toward the biomonitoring sites.

  12. Highlights of recent studies and future plans for the French human biomonitoring (HBM) programme.

    Science.gov (United States)

    Fréry, Nadine; Vandentorren, Stéphanie; Etchevers, Anne; Fillol, Clémence

    2012-02-01

    This manuscript presents highlights of recent studies and perspectives from the French human biomonitoring (HBM) programme. Until recently, HBM studies focused on specific populations or pollutants to gain a better understanding of exposure to environmental chemicals, to help regulators reduce environmental exposure and to monitor existing policies on specific concerns. Highlights of recent multicentre biomonitoring studies with specific population or pollutant focus are given. These French HBM studies have been implemented to know: (1) the influence of living near an incinerator on serum dioxin and polychlorinated biphenyl (PCB) levels, (2) the influence of consuming river fish contaminated by PCBs on serum PCBs of fishermen, and (3) the evolution of blood lead levels in children from 1 to 6 years old since 1995. Special emphasis is placed on the use of an integrated (HBM coupled with nutrition and health studies), multipollutant approach. This approach has been initiated in France with a recent national population-based biomonitoring survey, the Etude Nationale Nutrition Santé (ENNS; French Nutrition and Health Survey). This survey will provide the first reference distribution for 42 biomarkers in the French population. The current national HBM strategy will build upon the ENNS and include a national survey of people aged between 6 and 74 years complemented for the neonatal period and childhood by the Etude Longitudinale Française depuis l'Enfance (ELFE; French longitudinal study of children). France also contributes to the harmonization of HBM activities in Europe through participation in European HBM projects.

  13. Lichens as biomonitors around a coal-fired power station in Israel

    Energy Technology Data Exchange (ETDEWEB)

    Garty, J.; Tomer, S.; Levin, T.; Lehr, H. [Tel Aviv University, Tel Aviv (Israel). Dept. of Plant Science

    2003-03-01

    In the present study epiphytic lichens were applied as biomonitors of air pollution to determine the environmental impact of a coal-fired power station. Thalli of the lichen Ramalina lacera (With.) J.R. Laund. growing on carob twigs (Ceratonia siliqua L.) were collected with their substrate in July 2000 in a relatively unpolluted forest near HaZorea, Ramoth Menashe, Northeast Israel, and transplanted to 10 biomonitoring sites in the vicinity of the coal-fired power station Oroth Rabin near the town of Hadera. The lichens were retrieved in January 2001. The following parameters of lichen vitality were examined: (a) potential quantum yield of photosynthesis expressed as fluorescence ratio F{sub v}/F{sub m}, (b) stress-ethylene production, and (c) electric conductivity expressing integrity of cell membranes. Following an exposure of 7 months, the lichens were retrieved and physiological parameters and data of elemental content were analyzed comparatively. Electric conductivity values correlated positively with B, Fe, Mg, Mn, Na, Pb, S, Sn, and Ti content. Concentrations of stress-ethylene correlated positively with Al, Ba, Pb, S, and V content and negatively with Cu and Sn. F{sub v}/F{sub m} ratios correlated negatively with S content. Some of the heavy metals reached lower levels than those reported in the relevant literature despite a wind regime that should have blown pollutants toward the biomonitoring sites.

  14. Urban atmospheric pollution in the Eastern Mediterranean : lessons from the TRANSEMED initiative

    Science.gov (United States)

    Borbon, Agnes; Salameh, Therese; Gaimoz, Cecile; Sauvage, Stephane; Locoge, Nadine; Oztürk, Fatma; Cetin, Banu; Keles, Melek; Afif, Charbel

    2016-04-01

    The East Mediterranean Basin (EMB) is a highly sensitive environment under considerable pressures. Future decadal projections point to the EMB as a possible hot spot of poor air quality and predict a continual and gradual warming in the region, much stronger than other regions. The increase and accumulation of anthropogenic emissions of gaseous and particulate pollutants from surrounding urban areas, are suspected as one of the key compounding factors of those environmental impacts. The quantification of emission distribution is a challenge, and even more in cities of the EMB where local emission data are sparse. While some highly resolved inventories have been developed at the regional scale in the EMB area for Beirut and Istanbul, their uncertainties are unknown. The paucity of observations in this region, especially for VOCs and PM composition, is a strong limitation to the achievement of evaluated and accurate emission inventories. As part of the TRANSEMED initiative (https://charmex.lsce.ipsl.fr/index.php/sister-projects/transemed.html), one of our objectives is to develop a systematic source-receptor methodology for emission inventory evaluation. We combine existing and newly collected observations and complementary source-receptor approaches (ie., urban enhancement emission ratios, multivariate models like PMF) in representative areas of the EMB: Beirut (Lebanon), Istanbul (Turkey), Cairo (Egypt) and, more recently, Athens (Greece). Over the past five years a very detailed database of ambient and near-source observations has been built-up especially regarding the composition of gaseous organic carbon. Results show (i) the extremely high levels of pollution for organics, (ii) the dominance of traffic emissions on VOC concentration levels, (iii) the relative poor spatial variability of speciated hydrocarbon traffic emissions regardless of the region, and (iv) the high uncertainty on global emission inventories when compared to observations. For the latter, and

  15. Levels and Seasonal Variability of Persistent Organic Pollutants in Rural and Urban Atmosphere of Southern Ghana

    Science.gov (United States)

    Adu-Kumi, Sam; Klanova, Jana; Holoubek, Ivan

    2010-05-01

    Concentrations of persistent organic pollutants (POPs) in air are reported from the first full year of the RECETOX-Africa Air Monitoring (MONET_AFRICA) Project. Passive air samplers composed of polyurethane foam disks (PUF-disk samplers) were deployed for sampling background air concentrations from January-December 2008 at two urban sites in Ghana, namely, Ghana Atomic Energy Commission (Biotechnology and Nuclear Agricultural Research Institute, Kwabenya); and Ghana Meteorological Agency (East Legon). Another set of PUF-disk samplers were deployed at a rural/agricultural location (Lake Bosumtwi) from July-November 2008. For the purposes of this study, 28 days was the sampling period for polyaromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs); and 3 months for OCPs (Drins) and dioxins/furans (PCDD/Fs) respectively. MONET_AFRICA constituted part of the activities under the Global Monitoring Plan (GMP) for the effectiveness evaluation (Article 16) of the Stockholm Convention on POPs and the air sampling survey was conducted at 26 sites across the African continent with the aim to establish baseline information on contamination of ambient air with persistent organic pollutants (POPs) as a reference for future monitoring programmes in the region. For the pesticides, endosulfans constituted the highest contaminants measured followed by HCHs and DDTs in that order. The large temporal variability in the pesticide concentrations suggested seasonal application of endosulfans and γ-HCH. Levels of endosulfans were initially found to be below detection limit during the first sampling period (January - March 2008) but recorded the highest concentration than any other pesticide from all 16 sites in the African region during the second sampling period (April - June 2008). Concentrations of DDTs and HCHs were generally low throughout the sampling periods. p,p'-DDE/p,p'-DDT ratio in ambient air showed that the metabolite DDE was the

  16. Monitoring of atmospheric pollutants passive sampling for the protection of historic buildings and monuments

    Energy Technology Data Exchange (ETDEWEB)

    De Santis, F.; Fino, A.; Vazzana, C.; Allegrini, I. [Consiglio Nazionale delle Ricerche, Istituto Inquinamento Atmosferico, Rome (Italy)

    2001-12-01

    When considering the various possibilities to assess the effects of SO{sub 2} and NO{sub 2} on historic buildings and monuments, a distinction can be made according to the completeness of the scope of the assessment itself. A first approach can be limited to gathering data as they become available through the official bodies established under air quality legislation. This approach is based on a single point measurement where a general purpose monitoring station is located, often quite far from the monument to protect and often without investigating local and temporal variations. A more comprehensive assessment should include a generalisation that covers the territory. This can be made on the basis of the knowledge of the spatial distribution of concentrations and the knowledge of the causes of air pollution. Passive samplers allow the measurement of air quality in numerous sites and to assess the pollutant spatial distribution over a large area with a high resolution. As an application of the method, the spatial distribution of SO{sub 2} and NO{sub 2} in the city of Siracusa, Sicily, Italy, has been studied to identify areas of high deposition fluxes in relation to the protection of buildings and monuments of the historic centre. [Italian] E' noto che gli inquinanti presenti in aria, tra questi in particolare l'SO{sub 2} e l'NO{sub 2}, sono causa di danno sui monumenti e sulle opere d'arte. La valutazione dell'impatto di questi due inquinanti viene solitamente effettuata sulla base del monitoraggio eseguito secondo la legislazione vigente ma spesso lontano dal monumento da proteggere. Cio', evidentemente, non consente di valutare correttamente il grado di rischio al quale un monumento e' esposto poiche' non fornisce informazioni sulle variazioni spaziali e temporali dei due inquinanti in prossimita' del monumento stesso. Allo scopo di raccogliere quindi informazioni complete sulla distribuzione degli inquinanti, e

  17. The spatial-temporal distribution of the atmospheric polluting agents during the period 2000-2005 in the Urban Area of Guadalajara, Jalisco, Mexico.

    Science.gov (United States)

    Sánchez, Hermes U Ramírez; García, María D Andrade; Bejaran, Rubén; Guadalupe, Mario E García; Vázquez, Antonio Wallo; Toledano, Ana C Pompa; Villasenor, Odila de la Torre

    2009-06-15

    In the large cities, the disordered urban development, the industrial activities, and the transport, have caused elevated concentrations of polluting agents and possible risks to the health of the population. The metropolises located in valleys with little ventilation (such as the Urban Area of Guadalajara: UAG) present low dispersion of polluting agents can cause high risk of respiratory and cardiovascular diseases. The objective of this work was to describe the spatial-temporal distribution of the atmospheric polluting agents: carbon monoxide (CO), nitrogen dioxide (NO(2)), sulfur dioxide (SO(2)), particles smaller than 10 microns (microm) (PM(10)) and ozone (O(3)) in the UAG during the period 2000-2005. A spatial-temporal distribution analysis was made by means of graphic interpolation (Kriging method) of the statistical parameters of CO, NO(2), SO(2), PM(10) and O(3) with the collected data from eight stations of atmospheric monitoring in the UAG. The results show that the distributions of the atmospheric polluting agents are variable during the analyzed years. The polluting agent with highest concentration is PM(10) (265.42 microg/m(3)), followed by O(3) (0.11 ppm), NO(2) (0.11 ppm), CO (9.17 ppm) and SO(2) (0.05 ppm). The most affected zone is the southeast of the UAG. The results showed that an important percentage of days exceed the Mexican norms of air quality (93-199 days/year).

  18. Assessment of air pollution genotoxicity by RAPD in Evernia prunastri L. Ach. from around iron-steel factory in Karabük, Turkey.

    Science.gov (United States)

    Cansaran-Duman, Demet; Atakol, Orhan; Aras, Sümer

    2011-01-01

    Lichens are widely used in biomonitoring studies of air pollution, either as bioindicators of air quality or as bioaccumulators of atmospheric deposition. Over the past decade, several molecular techniques have been developed to provide information on diversity, genotoxicology, genetic relationships, etc. The heavy metal contents of Evernia prunastri samples were determined by atomic absorption spectrometry. The Random Amplified Polymorphic DNA Polymerase Chain Reaction (RAPD-PCR) method was used to describe the pattern of DNA band variation in the samples influenced by the environmental pollution. The study was designed to describe the level of pollution in an area contaminated with smoke and waste from an iron-steel factory, and to reveal the level of potential genotoxic agents around this source of pollution. The study also examined the suitability of the lichen samples for the detection of genotoxicity.

  19. Combining environment and health information systems for the assessment of atmospheric pollution on human health.

    Science.gov (United States)

    Skouloudis, Andreas N; Kassomenos, Pavlos

    2014-08-01

    The use of emerging technologies for environmental monitoring with satellite and in-situ sensors have become essential instruments for assessing the impact of environmental pollution on human health, especially in areas that require high spatial and temporal resolution. This was until recently a rather difficult problem. Regrettably, with classical approaches the spatial resolution is frequently inadequate in reporting environmental causes and health effects in the same time scale. This work examines with new tools different levels of air-quality with sensor monitoring with the aim to associate those with severe health effects. The process established here facilitates the precise representation of human exposure with the population attributed in a fine spatial grid and taking into account environmental stressors of human exposure. These stressors can be monitored with innovative sensor units with a temporal resolution that accurately describes chronic and acute environmental burdens. The current understanding of the situation in densely populated areas can be properly analyzed, before commitments are made for reductions in total emissions as well as for assessing the effects of reduced trans-boundary fluxes. In addition, the data processed here with in-situ sensors can assist in establishing more effective regulatory policies for the protection of vulnerable population groups and the satellite monitoring instruments permit abatement strategies that are close to real-time over large geographical areas.

  20. The Link between Knowledge, Attitudes and Practices in Relation to Atmospheric Haze Pollution in Peninsular Malaysia.

    Science.gov (United States)

    De Pretto, Laura; Acreman, Stephen; Ashfold, Matthew J; Mohankumar, Suresh K; Campos-Arceiz, Ahimsa

    2015-01-01

    Transboundary haze episodes caused by seasonal forest fires have become a recurrent phenomenon in Southeast Asia, with serious environmental, economic, and public health implications. Here we present a cross-sectional survey conducted among people in Kuala Lumpur and surrounds to assess the links between knowledge, attitudes, and practices in relation to the transboundary haze episodes. Of 305 respondents, 125 were amateur athletes participating in a duathlon event and the remainder were surveyed in an inner-city shopping mall. Across the whole sample, people who possessed more factual information about the haze phenomenon showed significantly higher levels of concern. Duathletes were more knowledgeable than non-duathletes and also more concerned about the negative effects of haze, especially on health. For all people who regularly practice outdoor sports (including people interviewed at the shopping mall), higher levels of knowledge and concerned attitudes translated into a greater likelihood of engaging in protective practices, such as cancelling their outdoor training sessions, while those with greater knowledge were more likely to check the relevant air pollution index on a daily basis. Our results indicate that the provision of accurate and timely information about air quality to residents will translate into beneficial practices, at least among particularly exposed individuals, such as amateur athletes who regularly practice outdoor sports.

  1. The Link between Knowledge, Attitudes and Practices in Relation to Atmospheric Haze Pollution in Peninsular Malaysia.

    Directory of Open Access Journals (Sweden)

    Laura De Pretto

    Full Text Available Transboundary haze episodes caused by seasonal forest fires have become a recurrent phenomenon in Southeast Asia, with serious environmental, economic, and public health implications. Here we present a cross-sectional survey conducted among people in Kuala Lumpur and surrounds to assess the links between knowledge, attitudes, and practices in relation to the transboundary haze episodes. Of 305 respondents, 125 were amateur athletes participating in a duathlon event and the remainder were surveyed in an inner-city shopping mall. Across the whole sample, people who possessed more factual information about the haze phenomenon showed significantly higher levels of concern. Duathletes were more knowledgeable than non-duathletes and also more concerned about the negative effects of haze, especially on health. For all people who regularly practice outdoor sports (including people interviewed at the shopping mall, higher levels of knowledge and concerned attitudes translated into a greater likelihood of engaging in protective practices, such as cancelling their outdoor training sessions, while those with greater knowledge were more likely to check the relevant air pollution index on a daily basis. Our results indicate that the provision of accurate and timely information about air quality to residents will translate into beneficial practices, at least among particularly exposed individuals, such as amateur athletes who regularly practice outdoor sports.

  2. Modelling atmospheric chemistry and long-range transport of emerging Asian pollutants

    CERN Document Server

    Wang, Kuo-Ying

    2008-01-01

    Modeling is a very important tool for scientific processes, requiring long-term dedication, desire, and continuous reflection. In this work, we discuss several aspects of modeling, and the reasons for doing it. We discuss two major modeling systems that have been built by us over the last 10 years. It is a long and arduous process but the reward of understanding can be enormous, as demonstrated in the examples shown in this work. We found that long-range transport of emerging Asian pollutants can be interpreted using a Lagrangian framework for wind analysis. More detailed processes still need to be modeled but an accurate representation of the wind structure is the most important thing above all others. Our long-term chemistry integrations reveal the capability of the IMS model in simulating tropospheric chemistry on a climate scale. These long-term integrations also show ways for further model development. Modeling is a quantitative process, and the understanding can be sustained only when theories are vigor...

  3. Anthropogenic emissions in Nigeria and implications for atmospheric ozone pollution: A view from space

    Science.gov (United States)

    Marais, E. A.; Jacob, D. J.; Wecht, K.; Lerot, C.; Zhang, L.; Yu, K.; Kurosu, T. P.; Chance, K.; Sauvage, B.

    2014-12-01

    Nigeria has a high population density and large fossil fuel resources but very poorly managed energy infrastructure. Satellite observations of formaldehyde (HCHO) and glyoxal (CHOCHO) reveal very large sources of anthropogenic nonmethane volatile organic compounds (NMVOCs) from the Lagos megacity and oil/gas operations in the Niger Delta. This is supported by aircraft observations over Lagos and satellite observations of methane in the Niger Delta. Satellite observations of carbon monoxide (CO) and nitrogen dioxide (NO2) show large seasonal emissions from open fires in December-February (DJF). Ventilation of central Nigeria is severely restricted at that time of year, leading to very poor ozone air quality as observed from aircraft (MOZAIC) and satellite (TES). Simulations with the GEOS-Chem chemical transport model (CTM) suggest that maximum daily 8-h average (MDA8) ozone exceeds 70 ppbv over the region on a seasonal mean basis, with significant contributions from both open fires (15-20 ppbv) and fuel/industrial emissions (7-9 ppbv). The already severe ozone pollution in Nigeria could worsen in the future as a result of demographic and economic growth, although this would be offset by a decrease in open fires.

  4. DEVELOPMENT OF MATHEMATICAL MEANS FOR ESTIMATION OF ECOLOGICAL AND ECONOMICAL LOSSES FROM POLLUTION OF ATMOSPHERIC AIR IN ZONES OF TECHNOGENIC OBJECTS IMPACT

    Directory of Open Access Journals (Sweden)

    O. POPOV

    2015-10-01

    Full Text Available The article describes the solution of one of the most important problems of rational use of natural resources. Modern mathematical tools for damage estimation, which are caused by atmospheric pollution to natural objects, and also methods for calculation of the cost for their renewal were developed. The solution of problem was divided into 3 stages. At the first stage it was defined basic anthropogenic sources of pollution, was illustrated conceptual behavior of pollutants in the atmosphere emitted by technological stationary point source. Choice of mathematical model that allows to determine the distribution of pollutants concentration in the air in zones of pollution by point stationary sources in the short-term discharges was proved. At the second stage it was developed mathematical tools to determine the level of objects damage, which were in the zone of pollution, depending on the intensity and duration of exposure of technogenic sources. At the third stage it was developed mathematical models to determine the recoverable amount of natural objects depending on their level of damage. Model example of developed means usage was described. Advantages of developed means over existed analogs were noticed.

  5. Toxic ignorance and right-to-know in biomonitoring results communication: a survey of scientists and study participants

    Directory of Open Access Journals (Sweden)

    Altman Rebecca

    2009-02-01

    Full Text Available Abstract Background Exposure assessment has shifted from pollutant monitoring in air, soil, and water toward personal exposure measurements and biomonitoring. This trend along with the paucity of health effect data for many of the pollutants studied raise ethical and scientific challenges for reporting results to study participants. Methods We interviewed 26 individuals involved in biomonitoring studies, including academic scientists, scientists from environmental advocacy organizations, IRB officials, and study participants; observed meetings where stakeholders discussed these issues; and reviewed the relevant literature to assess emerging ethical, scientific, and policy debates about personal exposure assessment and biomonitoring, including public demand for information on the human health effects of chemical body burdens. Results We identify three frameworks for report-back in personal exposure studies: clinical ethics; community-based participatory research; and citizen science 'data judo.' The first approach emphasizes reporting results only when the health significance of exposures is known, while the latter two represent new communication strategies where study participants play a role in interpreting, disseminating, and leveraging results to promote community health. We identify five critical areas to consider in planning future biomonitoring studies. Conclusion Public deliberation about communication in personal exposure assessment research suggests that new forms of community-based research ethics and participatory scientific practice are emerging.

  6. Applying bioethical principles to human biomonitoring

    Directory of Open Access Journals (Sweden)

    Harrison Myron

    2008-06-01

    Full Text Available Abstract Bioethical principles are widely used as a normative framework in areas of human research and medical care. In recent years there has been increasing formalization of their use in public health decisions. The "traditional bioethical principles" are applied in this discussion to the important issue human biomonitoring for environmental exposures. They are: (1 Autonomy – Also known as the "respect for humans" principle, people understand their own best interests; (2 Beneficence – "do good" for people; (3 Nonmaleficence – "do no harm"; (4 Justice – fair distribution of benefits and costs (including risks to health across stakeholders. Some of the points made are: (1 There is not a single generic bioethical analysis applicable to the use of human biomonitoring data, each specific use requires a separate deliberation; (2 Using unidentified, population-based biomonitoring information for risk assessment or population surveillance raises fewer bioethical concerns than personally identified biomonitoring information such as employed in health screening; (3 Companies should proactively apply normative bioethical principles when considering the disposition of products and by-products in the environment and humans; (4 There is a need for more engagement by scholars on the bioethical issues raised by the use of biomarkers of exposure; (5 Though our scientific knowledge of biology will continue to increase, there will always be a role for methods or frameworks to resolve substantive disagreements in the meaning of this data that are matters of belief rather than knowledge.

  7. Human biomonitoring activities--programmes by industry.

    Science.gov (United States)

    Boogaard, Peter J

    2007-05-01

    Biomonitoring of exposure to chemicals has been practiced for over half a century on a regular basis. During the last decade, however, the focus changed from occupational to environmental settings, requiring a different interpretative framework. Under the auspices of the European Centre for Ecology and Ecotoxicology (ECETOC) a framework was developed that allows to assess the relevance of any biomonitoring result to be interpreted reliably. If biomonitoring data is to be used for the evaluation of health risks of a substance, information is required on the analytical integrity of the data, the toxicokinetics of this substance, and its health effects in relation to (low) exposures. In addition, a weight-of-evidence needs to be used. The framework also identifies a number of data-gaps, several of which are addressed through the Long-range Research Initiative (LRI), an initiative of the global chemical industries (EU, USA, and Japan), which aims to help answering important questions in the application of biomonitoring data in human health risk assessment.

  8. Applying bioethical principles to human biomonitoring

    Directory of Open Access Journals (Sweden)

    Harrison Myron

    2008-01-01

    Full Text Available Abstract Bioethical principles are widely used as a normative framework in areas of human research and medical care. In recent years there has been increasing formalization of their use in public health decisions. The "traditional bioethical principles" are applied in this discussion to the important issue human biomonitoring for environmental exposures. They are: (1 Autonomy – Also known as the "respect for humans" principle, people understand their own best interests; (2 Beneficence – "do good" for people; (3 Nonmaleficence – "do no harm"; (4 Justice – fair distribution of benefits and costs (including risks to health across stakeholders. Some of the points made are: (1 There is not a single generic bioethical analysis applicable to the use of human biomonitoring data, each specific use requires a separate deliberation; (2 Using unidentified, population-based biomonitoring information for risk assessment or population surveillance raises fewer bioethical concerns than personally identified biomonitoring information such as employed in health screening; (3 Companies should proactively apply normative bioethical principles when considering the disposition of products and by-products in the environment and humans; (4 There is a need for more engagement by scholars on the bioethical issues raised by the use of biomarkers of exposure; (5 Though our scientific knowledge of biology will continue to increase, there will always be a role for methods or frameworks to resolve substantive disagreements in the meaning of this data that are matters of belief rather than knowledge.

  9. Quantifying the uncertainties of a bottom-up emission inventory of anthropogenic atmospheric pollutants in China

    Science.gov (United States)

    Zhao, Y.; Nielsen, C. P.; Lei, Y.; McElroy, M. B.; Hao, J.

    2011-03-01

    studies, the results are not always consistent with those derived from satellite observations. The results thus represent an incremental research advance; while the analysis provides current estimates of uncertainty to researchers investigating Chinese and global atmospheric transport and chemistry, it also identifies specific needs in data collection and analysis to improve on them. Strengthened quantification of emissions of the included species and other, closely associated ones - notably CO2, generated largely by the same processes and thus subject to many of the same parameter uncertainties - is essential not only for science but for the design of policies to redress critical atmospheric environmental hazards at local, regional, and global scales.

  10. Air pollution characteristics associated with mesoscale atmospheric patterns in northwest continental Europe

    Science.gov (United States)

    Buchholz, Saskia; Junk, Jürgen; Krein, Andreas; Heinemann, Günther; Hoffmann, Lucien

    2010-12-01

    An impact related daily air quality index (DAQx), calculated for 15 air quality monitoring stations (traffic, background, and industry) in Belgium, France, Germany and Luxembourg, was compared to mesoscale atmospheric patterns between 2001 and 2007. Meteorological conditions were described by the Hess and Brezowsky synoptic weather classification system and gridded data of the EU FP6 ENSEMBLES project of total precipitation and mean surface temperature. DAQx values indicate sufficient to poor air quality in the urban area of Brussels and at urban traffic stations, as well as satisfactory air quality at the background stations. The air quality index refers to more than 90% to the presence of high PM 10, O 3 and NO 2 concentrations. SO 2 and CO play only a minor role. The investigation of weather regimes indicates that zonal and mixed cyclonic circulation regimes are associated with better air quality than meridional and anticyclonic weather regimes. In general, weather regimes with high daily precipitation lead to better air quality than dryer air masses because of lower contribution of PM 10 to the air quality index. A trend analysis of weather regimes from 1978 to 2007 shows significant ( α = 0.05) positive trends for weather classes associated with lower PM 10 concentrations. The results of a case study at a German station examining the relationship between PM 10 concentrations and local meteorological quantities (wind speed and precipitation) confirm the results of the regional analysis.

  11. Urban light pollution - The effect of atmospheric aerosols on astronomical observations at night

    Science.gov (United States)

    Joseph, Joachim H.; Mekler, Yuri; Kaufman, Yoram J.

    1991-01-01

    The transfer of diffuse city light from a localized source through a dust-laden atmosphere with optical depth less than 0.5 has been analyzed in the source-observer plane on the basis of an approximate treatment. The effect on several types of astronomical observation at night has been studied, considering different size distributions and amounts as well as particle shapes of the aerosols. The analysis is made in terms of the signal-to-noise ratios for a given amount of aerosol. The model is applied to conditions at the Wise Astronomical Observatory in the Negev desert, and limiting backgrounds for spectroscopy, photometry, and photography of stars and extended objects have been calculated for a variety of signal-to-noise ratios. Applications to observations with different equipment at various distances from an urban area of any size are possible. Due to the use of signal-to-noise ratios, the conclusions are different for the different experimental techniques used in astronomy.

  12. Fire risk and air pollution assessment during the 2007 wildfire events in Greece using the COSMO-ART atmospheric model

    Science.gov (United States)

    Athanasopoulou, E.; Giannakopoulos, C.; Vogel, H.; Rieger, D.; Knote, C.; Hatzaki, M.; Vogel, B.; Karali, A.

    2012-04-01

    During 2007, Greece experienced an extreme summer and the worst natural hazard in its modern history. Soil dehydration, following a prolonged dry period in combination with hot temperatures and strong winds, yielded favorable conditions for the ignition and spread of wild fires that burnt approximately 200,000 ha of vegetated land (Founda and Gianakopoulos, 2009; Sifakis et al., 2011). The relationship between meteorology and fire potential can be provided by the Canadian Fire Weather Index (FWI), which is already found applicable in the fire activity of the Mediterranean region (Carvalho et al., 2008). However, lack of meteorological data or remote fire spots can be sources of uncertainties for fire risk estimation. In addition to the direct fire damage, these fires produced large quantities of gaseous air pollutants and particles (PM10) dispersed over the area of Greece. Indeed, PM10 concentration measurements showed two pollution episodes over Athens during late August and early September, 2007 (Liu et al., 2009). Nevertheless, these measurements neither show the large spatial extent of fire effects nor reveal its important role on atmospheric chemistry. In the current study, the application of the atmospheric model COSMO-ART is used to investigate the issues addressed above. COSMO-ART (Vogel et al. 2009) is a regional chemistry transport model (ART stands for Aerosols and Reactive Trace gases) online-coupled to the COSMO regional numerical weather prediction and climate model (Baldauf et al. 2011). The current simulations are performed between August 15 and September 15 over Greece with a horizontal resolution of 2.8 km and a vertical extend up to 20 km. The initial and boundary meteorological conditions are derived from a coarser COSMO simulation performed by the German Weather Service. Fire emissions are retrieved from the Global Fire Emissions Database version 3 (van der Werf et al., 2010). The anthropogenic emission database used is the TNO/MACC (Kuenen et

  13. Effective degradation of organic water pollutants by atmospheric non-thermal plasma torch and analysis of degradation process.

    Science.gov (United States)

    Bansode, Avinash S; More, Supriya E; Siddiqui, Ejaz Ahmad; Satpute, Shruti; Ahmad, Absar; Bhoraskar, Sudha V; Mathe, Vikas L

    2017-01-01

    The paper reports the use of atmospheric non-thermal plasma torch as a catalyst for degradation of various organic pollutants dissolved in water. A flow of He mixed with air was used to produce the dielectric barrier discharge (DBD), at the tip of the torch, using pulsed electric excitation at 12 kV. The torch, operated at a power of 750 mW/mm(2), was seen to completely degrade the aqueous solutions of the pollutants namely methylene blue (MB), methyl orange (MO) and rhodamine-B (RB), at around 10(-4) M concentrations, the concentration of polluants is one order higher than of routinely used heterogeneous photocatalytic reactions, within 10 min of irradiation time at room temperature. UV Visible spectra of the organic dye molecules, monitored after different intervals of plasma-irradiation, ranging between 1 and 10 min, have been used as tools to quantify their sequential degradation. Further, instead of using He, only air was used to form plasma plume and used for degradation of organic dye which follow similar trend as that of He plasma. Further, Liquid Chromatography Mass Spectroscopy (LCMS) technique has been used to understand degradation pathway of methylene blue (MB) as a representative case. Total organic carbon (TOC) measurements indicates significant decrease in its content as a function of duration of plasma exposure onto methylene blue as a representative case. Toxicity studies were carried out onto Gram negative Escherichia coli. This indicated that methylene blue, without plasma treatment, shows growth inhibition, whereas with plasma treatment no inhibition was observed.

  14. Fundamental understanding of the thermal degradation mechanisms of waste tires and their air pollutant generation in a N2 atmosphere.

    Science.gov (United States)

    Kwon, Eilhann; Castaldi, Marco J

    2009-08-01

    The thermal decomposition of waste tires has been characterized via thermo-gravimetric analysis (TGA) tests, and significant mass loss has been observed between 300 and 500 degrees C. A series of gas chromatography-mass spectrometer (GC-MS) measurements, in which the instrument was coupled to a TGA unit, have been carried out to investigate the thermal degradation mechanisms as well as the air pollutant generation including volatile organic carbons (VOCs) and polycyclic aromatic hydrocarbons (PAHs) in a nitrogen atmosphere. In order to understand fundamental information on the thermal degradation mechanisms of waste tires, the main constituents of tires, poly-isoprene rubber (IR) and styrene butadiene rubber (SBR), have been studied under the same conditions. All of the experimental work indicated that the bond scission on each monomer of the main constituents of tires was followed by hydrogenation and gas phase reactions. This helped to clarify the independent pathways and species attributable to IR and SBR during the pyrolysis process. To extend that understanding to a more practical level, a flow-through reactor was used to test waste tire, SBR and IR samples in the temperature range of 500-800 degrees C at a heating rate of approximately 200 degrees C. Lastly, the formation of VOCs (approximately 1-50 PPMV/10 mg of sample) and PAHs (approximately 0.2-7 PPMV/10 mg of sample) was observed at relatively low temperatures compared to conventional fuels, and its quantified concentration was significantly high due to the chemical structure of SBR and IR. The measurement of chemicals released during pyrolysis suggests not only a methodology for reducing the air pollutants but also the feasibility of petrochemical recovery during thermal treatment.

  15. Evaluation of the pollution and human health risks posed by heavy metals in the atmospheric dust in Ebinur Basin in Northwest China.

    Science.gov (United States)

    Abuduwailil, Jilili; Zhaoyong, Zhang; Fengqing, Jiang

    2015-09-01

    Recently, a large amount of research assessing pollution levels and the related health risks posed by atmosphere dust has been undertaken worldwide. However, little work has been done in the oases of the arid regions of Northwest China. In this paper, we studied the pollution and health risks over a year of seven heavy metals in the atmospheric dust of Ebinur Basin, a typical oasis in Northwest China. The results showed the following: (1) The annual amount of atmospheric deposition in Ebinur Basin was 298.23 g m(-2) and the average monthly atmospheric deposition was 25.06 g m(-2). The average and maximum values of the seven heavy metals measured were all below the National Soil Environmental Quality Standards (2nd). (2) Heavy metals of Cu, Cr, and As in the atmospheric deposition mainly originated from the natural geological background, while Zn came from human activity. This study also showed that among the seven measured heavy metals, the ratios of the no-pollution status of Pb, Cd, and Hg were higher than those of others with moderate degrees of pollution also accounting for a certain ratio. (3) The carcinogenic risks from As, Cd, and Cr were all lower than the corresponding standard limit values, and these metals are considered not harmful to the health of the basin. However, there is a relatively high risk of exposure for children from hand-to-mouth intake, which is worthy of attention. This research showed that both human activity and natural factors, such as wind and altitude, influenced the heavy metal contents in the atmospheric dust of the study area. Furthermore, recent human activity in the study area had the most negative influence on the accumulation of the heavy metals and the corresponding health risks, especially for Hg, Pb, and Cd, which is worthy of attention.

  16. Use of native mosses as biomonitors of heavy metals and nitrogen deposition in the surroundings of two steel works.

    Science.gov (United States)

    González-Miqueo, L; Elustondo, D; Lasheras, E; Santamaría, J M

    2010-02-01

    A biomonitoring survey using the moss species Hypnum cupressiforme Hedw. was conducted in the surroundings of two steel plants located in the North of Spain. Levels of V, Cr, Ni, Cu, Zn, As, Cd, Hg, Pb and N were determined. Very high concentrations in the areas of study were detected when compared to nearby unaffected regions. Similar trends were observed for all the elements in the differently orientated transects, showing an appreciable influence of the NW prevailing winds of the region in the dispersion of pollutants, as well as a clear decreasing gradient in the concentrations of metals in mosses within a distance of 1500 meters from the facilities. A differentiation between the elements emitted by the chimney as result of the industrial activity (V, Cr, Ni, Cu and As) and those with a high presence in steel slag deposits (Zn, Cd, Hg and Pb) was observed. The range of contamination was also established by means of the Contamination Factor, indicating a category 4 out of 6 categories, which shows the high levels reported in the areas of study. A different dynamic was registered for nitrogen regarding the rest of the heavy metals analysed except for Hg, probably due to the elevated volatility and mobility of both elements, as well as their high persistence in the atmosphere.

  17. Opinions of the French on the atmospheric pollution, the wastes management and the eco-products; Opinions des francais sur la pollution atmospherique, la gestion des dechets et les eco-produits

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-06-01

    Five main opinions can be presented from the answers analysis to the inquiry realized in 1999 by the ADEME on the French way of life and aspirations. The French think that the atmospheric pollution is dangerous for the health and that they are badly informed about the air quality of their town. 87% of the motorists are ready to leave their vehicles the days of high urban pollution level. In less of two years the green products credibility is worsening. Nevertheless the consumer believes sensitive to the ecological arguments. Finally the French are very favorable to the domestic wastes control. (A.L.B.)

  18. Atmospheric pollution, eco-products, wastes management: some opinions and attitudes at the beginning of 2002; Pollution atmospherique, eco-produits, gestion des dechets: quelques opinions et attitudes au debut 2002

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-07-01

    This document presents the results (statistical data) to the questions asked by the ADEME in the inquiry of the CREDOC concerning the ''French way of life and aspirations'' and realized in the beginning of the year 2002. The questions dealt with the following five topics: the french attitude facing the atmospheric pollution; the renouncing of the vehicle during the days of high urban pollution; the French and the remote-working; the consumption and the environment control. (A.L.B.)

  19. Quantifying the uncertainties of a bottom-up emission inventory of anthropogenic atmospheric pollutants in China

    Directory of Open Access Journals (Sweden)

    Y. Zhao

    2010-11-01

    Carlo simulation yields narrowed estimates of uncertainties compared to previous bottom-up emission studies, the results are not always consistent with those derived from satellite observations. The results thus represent an incremental research advance; while the analysis provides current estimates of uncertainty to researchers investigating Chinese and global atmospheric transport and chemistry, it also identifies specific needs in data collection and analysis to improve on them. Strengthened quantification of emissions of the included species and other, closely associated ones – notably CO2, generated largely by the same processes and thus subject to many of the same parameter uncertainties – is essential not only for science but for the design of policies to redress critical atmospheric environmental hazards at local, regional, and global scales.

  20. Application of a Lagrangian modeling to the atmospheric pollution; Aplicacion de una modelizacion Lagrangiana a la contaminacion atmosferica transfronteriza

    Energy Technology Data Exchange (ETDEWEB)

    Rua, A.; Hernandez, E. [Departamento de Fisica del Aire, Universidad Complutense de Madrid, Facultad de Ciencias Fisicas, Madrid (Spain); Gimeno, L. [Centro de Formacion del Instituto Nacional de Meteorologia (INM), Madrid (Spain)

    1998-04-01

    In this article, a physical modeling of the atmospheric pollution was considered. The objective was to determine the concentrations of pollutants in a receptor station reproducing the way followed by the air mass and simulating the physical and chemical processes involved during this way. To do that we used a Lagrangian model. To estimate the quality of the model a comparison between the theoretical concentration from the model and the observed concentrations is done. The model uses the air mass trajectories arriving at the receptor station calculated from the Limited Area Model (LAM). These trajectories let us know the air mass position each 6 hours. Once the initial model had been run, several parameters were modified with the aim of reproducing letter the conditions of The Iberian Peninsula. The considered pollutants were the SO{sub 2} and SO{sub 4}{sup 2}- and the chosen station was Logrono (Spain). [Spanish] En este articulo se planteo una modelizacion de la contaminacion atmosferica transfronteriza desde un punto de vista fisico. Asi, reproduciendo el camino seguido por las masas de aire que transportan los contaminantes y simulando lo mejor posible los procesos fisico-quimicos existentes durante ese camino, pretendimos determinar cual fue la concentracion final registrada de tales contaminantes en una estacion receptora. Un modelo fisico de tipo Lagrangiano se uso en este trabajo. Para estimar la bondad de tal modelizacion se realizo una comparacion entre la concentracion final estimada mediante la modelizacion y la observada. Se partio de las trayectorias de las masas de aire que llegan hasta esa estacion receptora, calculadas a partir del Modelo de Area Limitada (LAM), y que permite conocer la posicion de la masa de aire cada 6 horas. Fueron modificados algunos parametros del modelo fisico inicialmente propuestos, adecuandolos mas a la realidad fisica de la Peninsula Iberica, lograndose una mejora en los resultados obtenidos en un primer momento. Los

  1. Biomonitoring of 1,3-butadiene and related compounds.

    Science.gov (United States)

    Osterman-Golkar, S; Bond, J A

    1996-10-01

    The 1990 Clean Air Act Amendments list several volatile organic chemicals as hazardous air pollutants, including ethylene oxide, butadiene, styrene, and acrylonitrile. The toxicology of many of these compounds shares several common elements such as carcinogenicity in laboratory animals, genotoxicity of the epoxide intermediates, involvement of cytochrome P450 for metabolic activation (except ethylene oxide), and involvement of at least two enzymes for detoxication of the epoxides (e.g., hydrolysis or conjugation with glutathione). These similarities facilitate research strategies for identifying and developing biomarkers of exposure. This article reviews the current knowledge about biomarkers of butadiene. Butadiene is carcinogenic in mice and rats, which raises concern for potential carcinogenicity in humans. Butadiene is metabolized to DNA-reactive metabolites, including 1,2-epoxy-3-butene and diepoxybutane. These epoxides are thought to play a critical role in butadiene carcinogenicity. Butadiene and some of its metabolites (e.g., epoxybutene) are volatile. Exhalation of unchanged butadiene and excretion of butadiene metabolites in urine represent major routes of elimination. Therefore, biomonitoring of butadiene exposure could be based on chemical analysis of butadiene in exhaled breath, blood levels of butadiene epoxides, excretion of butadiene metabolites in urine, or adducts of butadiene epoxides with DNA or blood proteins. Mutation induction in specific genes (e.g., HPRT) following butadiene exposure can be potentially used as a biomarker. Excretion of 1,2-dihydroxy-4-(N-acetylcysteinyl-S)butane or the product of epoxybutene with N-7 in guanine in urine, epoxybutene-hemoglobin adducts, and HPRT mutation have been used as biomarkers in recent studies of occupational exposure to butadiene. Data in laboratory animals suggest that diepoxybutane may be a more important genotoxic metabolite than epoxybutene. Biomonitoring methods need to be developed for

  2. Effect of Pollution Controls on Atmospheric PM2.5 Composition during Universiade in Shenzhen, China

    Directory of Open Access Journals (Sweden)

    Nitika Dewan

    2016-04-01

    Full Text Available The 16th Universiade, an international multi-sport event, was hosted in Shenzhen, China from 12 to 23 August 2011. During this time, officials instituted the Pearl River Delta action plan in order to enhance the air quality of Shenzhen. To determine the effect of these controls, the current study examined the trace elements, water-soluble ions, and stable lead isotopic ratios in atmospheric particulate matter (PM collected during the controlled (when the restrictions were in place and uncontrolled periods. Fine particles (PM2.5 were collected at two sampling sites in Shenzhen: “LG”—a residential building in the Longgang District, with significant point sources around it and “PU”—Peking University Shenzhen Graduate School in the Nanshan District, with no significant point sources. Results from this study showed a significant increase in the concentrations of elements during the uncontrolled periods. For instance, samples at the LG site showed (controlled to uncontrolled periods concentrations (in ng·m−3 of: Fe (152 to 290, As (3.65 to 8.38, Pb (9.52 to 70.8, and Zn (98.6 to 286. Similarly, samples at the PU site showed elemental concentrations (in ng·m−3 of: Fe (114 to 301, As (0.634 to 8.36, Pb (4.86 to 58.1, and Zn (29.5 to 259. Soluble Fe ranged from 7%–15% for the total measured Fe, indicating an urban source of Fe. Ambient PM2.5 collected at the PU site has an average 206Pb/204Pb ratio of 18.257 and 18.260 during controlled and uncontrolled periods, respectively. The LG site has an average 206Pb/204Pb ratio of 18.183 and 18.030 during controlled and uncontrolled periods, respectively. The 206Pb/204Pb ratios at the PU and the LG sites during the controlled and uncontrolled periods were similar, indicating a common Pb source. To characterize the sources of trace elements, principal component analysis was applied to the elements and ions. Although the relative importance of each component varied, the major sources for both

  3. Atmospheric aerosol and gaseous pollutant concentrations in Bucharest area using first datasets from the city AQ monitoring network

    Science.gov (United States)

    Balaceanu, Cristina; Iorga, Gabriela

    2010-05-01

    City of Bucharest is the largest and most populated (about 2.8 million inhabitants) city in the Romanian Plain and encounters environmental problems and meteorology typical for several cities in southeastern Europe. City environment includes intense emissions arising from traffic (about 1 million cars per day), five thermo-electrical power-generation stations, that use both natural gas and oil derivatives for power generation and domestic heating, and from industrial sources (more than 800 small and medium plants). In the present work we performed an extensive analysis of the air pollution state for the Bucharest area (inside and outside the city) using filter measurement aerosol data PM10 and PM2.5. Data spanning over first year of continuous sampling (2005) were taken from the city Air Quality Monitoring Network, which consists of eight sampling stations: three industrial and two traffic, one EPA urban background, one suburban and one regional station located outside of Bucharest. The objective was to assess the PM10 recorded levels and their degree of compliance with the EU-legislated air quality standards and to provide a statistical investigation of the factors controlling seasonal and spatial variations of PM levels. PM10 relationships with other measured air pollutants (SO2, CO, NOx) and meteorological parameters (temperature, relative humidity, atmospheric pressure, wind velocity and direction) were investigated by statistical analysis. Back trajectory modeling and wind direction frequency distributions were used to identify the origin of the polluted air masses. Contribution of combustion (slopes) and non-combustion (intercepts) sources to PM10 recorded levels was quantified by linear analysis, for two seasonal periods: cold (15 October-14 April) and warm (15 April-14 October). PM10 and PM2.5 concentrations were compared with corresponding values in other European urban areas. Main conclusions are as follows: Traffic and industrial sites contribute to the

  4. Evaluation of hydrophobic treatments applied to stones used in andalusian cathedrals. III.-Accelerated weathering test with polluted atmosphere

    Directory of Open Access Journals (Sweden)

    Villegas Sánchez, R.

    1993-12-01

    Full Text Available SUMMARY In this work we study the weathering resistance of samples of five types of stone used in Andalusian Cathedrals, treated with six water repellent products, by subjecting the samples to a SO2 polluted atmosphere. To evaluate the alteration of the samples, besides visual observation of macroscopic aspect, changes in weight and the quantity of sulfate that remains on the surface have been measured. Also properties related with water have been measured after the test to determine if there have been any changes in the hydrophobic characteristics.

    En el presente artículo se estudia el comportamiento de muestras de cinco tipos de piedra utilizados en catedrales andaluzas, tratadas con seis productos hidrófugos, sometiéndolas a un ensayo acelerado de alteración en atmósfera contaminada con SO2 . Para evaluar la alteración, además de la observación visual de las manifestaciones macroscópicas, se ha medido la variación de peso de las muestras expuestas y la cantidad de sulfato que permanece en la superficie tras el ensayo. Así mismo, se han detectado los cambios experimentados en las propiedades hidrófugas conferidas por los tratamientos, mediante la medida de propiedades relacionadas con el movimiento del agua.

  5. Levels, sources and chemical fate of persistent organic pollutants in the atmosphere and snow along the western Antarctic Peninsula.

    Science.gov (United States)

    Khairy, Mohammed A; Luek, Jenna L; Dickhut, Rebecca; Lohmann, Rainer

    2016-09-01

    The Antarctic continent is among the most pristine regions; yet various organic contaminants have been measured there routinely. Air and snow samples were collected during the austral spring (October-November, 2010) along the western Antarctic Peninsula and analyzed for organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs) to assess the relative importance of long-range transport versus local primary or secondary emissions. Highest concentrations of PCBs, PBDEs and DDTs were observed in the glacier's snow sample, highlighting the importance of melting glaciers as a possible secondary source of legacy pollutants to the Antarctic. In the atmosphere, contaminants were mainly found in the vapor phase (>65%). Hexachlorobenzene (33.6 pg/m(3)), PCBs (11.6 pg/m(3)), heptachlor (5.64 pg/m(3)), PBDEs (4.22 pg/m(3)) and cis-chlordane (2.43 pg/m(3)) were the most abundant contaminants. In contrast to other compounds, PBDEs seem to have originated from local sources, possibly the research station itself. Gas-particle partitioning for analytes were better predicted using the adsorption partitioning model than an octanol-based absorption approach. Diffusive flux calculations indicated that net deposition is the dominant pathway for PBDEs and chlordanes, whereas re-volatilization from snow (during melting or metamorphosis) was observed for PCBs and some OCPs.

  6. Atmospheric dry deposition in the vicinity of the Salton Sea, California - I: Air pollution and deposition in a desert environment

    Science.gov (United States)

    Alonso, R.; Bytnerowicz, A.; Boarman, W.I.

    2005-01-01

    Air pollutant concentrations and atmospheric dry deposition were monitored seasonally at the Salton Sea, southern California. Measurements of ozone (O 3), nitric acid vapor (HNO3), ammonia (NH3), nitric oxide (NO), nitrogen dioxide (NO2) and sulfur dioxide (SO 2) were performed using passive samplers. Deposition rates of NO 3-, NH4+, Cl-, SO 42-, Na+, K+ and Ca2+ to creosote bush branches and nylon filters as surrogate surfaces were determined for one-week long exposure periods. Maximum O3 values were recorded in spring with 24-h average values of 108.8 ??g m-3. Concentrations of NO and NO2 were low and within ranges of the non-urban areas in California (0.4-5.6 and 3.3-16.2 ??g m-3 ranges, respectively). Concentrations of HNO3 (2.0-6.7 ??g m-3) and NH 3 (6.4-15.7 ??g m-3) were elevated and above the levels typical for remote locations in California. Deposition rates of Cl-, SO42-, Na+, K+ and Ca2+ were related to the influence of sea spray or to suspended soil particles, and no strong enrichments caused by ions originated by human activities were detected. Dry deposition rates of NO3- and NH4+ were similar to values registered in areas where symptoms of nitrogen saturation and changes in species composition have been described. Deposition of nitrogenous compounds might be contributing to eutrophication processes at the Salton Sea. ?? 2005 Elsevier Ltd. All rights reserved.

  7. Multistate atmospheric power production pollution study - MAP3S. Progress report for FY 1977 and FY 1978

    Energy Technology Data Exchange (ETDEWEB)

    MacCracken, Michael C.; Ballantine, David S.

    1979-07-01

    Research progress on the transport, transformation, and fate of pollutants released by energy-related activities is summarized. Information is reported under the following section headings: power production emissions; non-power production emissions; measuring pollutants and their properties; regional pollutant distribution; transport; pollutant transformation; surface removal processes; wet removal processes; weather and climate modification; numerical modeling and analysis; special activities; and, MAP3S research directions. (JGB)

  8. Human biomonitoring in civil defense; Humanbiomonitoring im Bevoelkerungsschutz

    Energy Technology Data Exchange (ETDEWEB)

    Mueller, Michael; Schmiechen, Katharina [Universitaetsmedizin Goettingen (Germany). Arbeits-, Sozial- und Umweltmedizin

    2012-07-01

    The booklet on human biomonitoring (HBM) in civil defense covers the following issues within two sections: (1) general part: definition and importance of human biomonitoring; application in civil defense; practice in a CBRN (chemical, biological, radiation, nuclear) scenario; sampling following a CBRN assignment; HBM for antidote administration; peculiarities of sampling in case of biological agents; microbiological detection procedure; human biomonitoring of radioactive metal isotopes. (2) Special part: substance profiles; list of HBM laboratories; list of poison information centers; questionnaire for exposure assessment in case of dangerous substance accidents; agreement for human biomonitoring examination.

  9. Declining trends of PCDD/Fs in lichens over a decade in a Mediterranean area with multiple pollution sources.

    Science.gov (United States)

    Augusto, Sofia; Pinho, Pedro; Santos, Artur; Botelho, Maria João; Palma-Oliveira, José; Branquinho, Cristina

    2015-03-01

    Lichens are one of the most useful environmental biomonitors, due to their ability to clearly reflect atmospheric deposition of pollutants. Dioxin and furan (PCDD/F) emissions have been reported to be decreasing in North European countries as a consequence of European regulations. This reduction has been perceptible across several environmental matrices, but it hasn't yet been shown in lichens as typical biomonitors of atmospheric pollution. In this work we compared concentrations of PCDD/Fs in two lichen species collected in a Mediterranean area with mixed land-uses, encompassing urban, industrial and natural areas, in 2009 and 2011 with the ones obtained in the same species collected in the same region in 2000. We found that PCDD/F concentrations in both lichen species have decreased approximately 70% since 2000 whereas industrial emissions have only decreased 25% for the same period. This substantial greater reduction observed in lichens may be due to several causes; after excluding fires as a possible explanation, we point out that possible causes could not only be the overall decrease in industrial emissions but also other causes such as traffic reduction and/or increase efficiency in the use of fuels. Capsule: PCDD/F concentrations in lichens have decreased 70% over the last decade, whereas industrial emissions have only decreased 25%.

  10. Enviormental Pollution

    OpenAIRE

    Kanika Saini; Dr. Sona Malhotra

    2016-01-01

    Environment Pollution is one of the greatest problems today which is increasing with every passing year and causing crucial and severe damage to the earth. It has become a real problem since the beginning of the industrial revolution. It is the contamination of physical and biological components of the Earth / atmosphere system to such an extent that normal environmental processes are harmed. Pollution of the environment consists of five main types of pollution, namely air, water,...

  11. Toxic metal levels in children residing in a smelting craft village in Vietnam: a pilot biomonitoring study

    OpenAIRE

    Sanders, Alison P.; Miller, Sloane K.; Nguyen, Viet; Kotch, Jonathan B; Fry, Rebecca C.

    2014-01-01

    Background In Vietnam, environmental pollution caused by small-scale domestic smelting of automobile batteries into lead ingot is a growing concern. The village of Nghia Lo is a smelting craft village located roughly 25 km southeast of Hanoi in the Red River Delta. Despite the concern of toxic metal exposure in the village, biomonitoring among susceptible populations, such as children, has not been previously conducted. The aim of this study was to determine the body burden of toxic metals in...

  12. The biomonitoring and bioremediation of toxic water resulting from municipal waste storage of Somârd, Sibiu county

    OpenAIRE

    2013-01-01

    This paper presents information from the specialty literature and laboratory experimental results on biomonitoring, phytoextraction, biodegradation, and biotransformation of toxic water pollutants at the biotechnology laboratory of the Faculty of Environmental Science and Engineering. The study was conducted in laboratory micro tanks with contaminated water from the municipal landfill water storage pit with toxic bund of Somârd/Medias, Sibiu County, in order to research and develo...

  13. Determination of the atmospheric optical depth due to the El Chichon stratospheric aerosol cloud in the polluted atmosphere of Mexico City

    Energy Technology Data Exchange (ETDEWEB)

    Galindo, Ignacio [Centro Universitario de Investigaciones en Ciencia del Ambiente, Universidad de Colima, Colima, Colima, (Mexico); Kondratyev, Kirill Ya. [Academician, Counsellor Center for Ecological Safety, Russian Academy of Sciences, St. Petersburg (Russian Federation); Zenteno, Gerardo [Instituto de Geofisica, UNAM, Mexico, D.F. (Mexico)

    1996-01-01

    Direct solar radiation measurements were used to determine the aerosol optical depth (AOD) increase associated with the presence of aerosol and large particles (ash) originating from the 28 March to 4 April 1982 El Chichon eruptions (17.5 degrees N, 93.3 degrees W; Mexico) on Mexico City's polluted atmospheric aerosol layer. The results are compared with those obtained at Vancouver, British Columbia, revealing that a first AOD increase occurred in both locations during May, June, and July 1982, the Mexico City AOD decay is more extended, not reaching normal climatological values until February 1983. Meanwhile, Vancouver's AOD reached minimum values in September 1982, which subsequently increased over a period from October 1982 to September 1983. This secondary maximum was recorded in Mexico City from March to August 1983. Results suggest that the first AOD increases in May, June and July 1982, both at Vancouver and Mexico City, are due chiefly to short life-time volcanic ash particles being located near the surface. However, the second AOD increases, associated with anomalously colored twilights, corresponds to stratospheric volcanic aerosols. [Spanish] Se utilizaron mediciones de radiacion solar directa para determinar el incremento de la profundidad optica del aerosol (AOD) asociada a la presencia de aerosoles y particulas grandes (cenizas) organizadas por las erupciones de El Chichon (17.5 grados N, 93.3 grados W; Mexico) del 28 de marzo al 4 de abril de 1982 sobre la capa atmosferica contaminada de la Ciudad de Mexico. Los resultados se comparan con los obtenidos en Vancouver, Colombia Britanica, relevando que un primer aumento de AOD ocurrio en ambos lugares durante mayo, junio y julio de 1982. Sin embargo, la AOD decayo en Ciudad de Mexico mas lentamente, alcanzando los valores climatologicos normales hasta febrero de 1983. Mientras tanto la AOD para Vancouver alcanzo valores minimos en septiembre de 1982; estos subsecuentemente se incrementaron en

  14. The lichen Parmelia physodes (L. Ach. as indicator for determination of the degree of atmospheric air pollution in the area contaminated by flourine and sulphur dioxide emission

    Directory of Open Access Journals (Sweden)

    M. Świeboda

    2015-01-01

    Full Text Available On the area involved in the influence of conteminations emitted by the aluminium works and electric power plant, the degree of atmospheric air pollution was evaluated on the basis of the behaviour of healthy thallus of the lichen Parmelia physodes, analysis of fluorine and sulphur content in this thallus and in the bark substrate and the F and SO2 concentrations in the air.

  15. Modelling impact of climate change on atmospheric transport and fate of persistent organic pollutants in the Arctic

    Directory of Open Access Journals (Sweden)

    K. M. Hansen

    2015-03-01

    Full Text Available The Danish Eulerian Hemispheric Model (DEHM was applied to investigate how projected climate changes will affect the atmospheric transport of 13 persistent organic pollutants (POPs to the Artic and their environmental fate within the Arctic. Two sets of simulations were performed, one with initial environmental concentrations from a 20 year spin-up simulation and one with initial environmental concentrations set to zero. Each set of simulations consisted of two ten-year time slices representing the present (1990–2000 and future (2090–2100 climate conditions. The same POP emissions were applied in all simulations to ensure that the difference in predicted concentrations for each set of simulations only arises from the difference in climate input. DEHM was driven using meteorological input from the global circulation model, ECHAM/MPI-OM, simulating the SRES A1B climate scenario. Under the applied climate and emission scenarios, the total mass of all compounds was predicted to be up to 20% higher across the Northern Hemisphere. The mass of HCHs within the Arctic was predicted to be up to 39% higher, whereas the change in mass of the PCBs was predicted to range from 14% lower to 17% higher depending on the congener and the applied initial environmental concentrations. The results of this study also indicate that contaminants with no or a short emission history will be more rapidly transported to and build up in the arctic environment in a future warmer climate. The process that dominates the environmental behaviour of POPs in the Arctic under a future warmer climate scenario is the shift in mass of POPs from the surface media to the atmosphere induced by the higher mean temperature. This is to some degree counteracted by higher degradation rates also following the higher mean temperature. The more dominant of these two processes depend on the physical-chemical properties of the compounds. Previous model studies have predicted that the effect of

  16. Modelling impact of climate change on atmospheric transport and fate of persistent organic pollutants in the Arctic

    Science.gov (United States)

    Hansen, K. M.; Christensen, J. H.; Geels, C.; Silver, J. D.; Brandt, J.

    2015-03-01

    The Danish Eulerian Hemispheric Model (DEHM) was applied to investigate how projected climate changes will affect the atmospheric transport of 13 persistent organic pollutants (POPs) to the Artic and their environmental fate within the Arctic. Two sets of simulations were performed, one with initial environmental concentrations from a 20 year spin-up simulation and one with initial environmental concentrations set to zero. Each set of simulations consisted of two ten-year time slices representing the present (1990-2000) and future (2090-2100) climate conditions. The same POP emissions were applied in all simulations to ensure that the difference in predicted concentrations for each set of simulations only arises from the difference in climate input. DEHM was driven using meteorological input from the global circulation model, ECHAM/MPI-OM, simulating the SRES A1B climate scenario. Under the applied climate and emission scenarios, the total mass of all compounds was predicted to be up to 20% higher across the Northern Hemisphere. The mass of HCHs within the Arctic was predicted to be up to 39% higher, whereas the change in mass of the PCBs was predicted to range from 14% lower to 17% higher depending on the congener and the applied initial environmental concentrations. The results of this study also indicate that contaminants with no or a short emission history will be more rapidly transported to and build up in the arctic environment in a future warmer climate. The process that dominates the environmental behaviour of POPs in the Arctic under a future warmer climate scenario is the shift in mass of POPs from the surface media to the atmosphere induced by the higher mean temperature. This is to some degree counteracted by higher degradation rates also following the higher mean temperature. The more dominant of these two processes depend on the physical-chemical properties of the compounds. Previous model studies have predicted that the effect of a changed climate on

  17. The prominent role of urban confluences in the local and regional transport of atmospheric pollutants in the Valley of Mexico

    Science.gov (United States)

    Jazcilevich, A. D.; Díaz, E. N.; Tatarko, J.; Garcia, A. R.

    2010-12-01

    The meteorological phenomenon known as confluences is especially vigorous in city environments due to the daytime urban heat island effect. Through the analysis of episodes obtained using computational modeling, it is shown not only that confluences strongly influence the local transport of pollution affecting the potential exposure of local population, but also that they enhance the interaction of anthropogenic pollutants generated in Mexico City with natural pollutants emitted in surrounding forests and how confluences provide the necessary convective energy so pollutants are transported on a regional scale

  18. Dynamics of the health status of children in an area with atmospheric pollution, as compared with a control group

    Energy Technology Data Exchange (ETDEWEB)

    Antal, A.; Coasan, A.; Vicas, T.; Balasoiu, I.; Horvath, V.; Sabau, S.

    1974-01-01

    The effect of air pollution on children was studied in two areas of Romania. Development, psychometric aspects, and morphological aspects were studied. Vital capacity, maximum expiratory volume, and muscular strength were examined. Adaptability and learning performance were studied in children from 7 to 14 years old. In polluted areas containing high concentrations of nitrogen oxides, sulfur dioxide, lead, and carbon black, the health of the children was impaired. Respiratory diseases were frequent, and pleurobronchopulmonary diseases, anemia, and rachitis also occurred. Scholarly performance was poorer in polluted areas than in control areas. Children in polluted areas were also shorted than in control areas.

  19. 哈尔滨市区内大气污染现状分析%The analysis of the status of Harbin atmospheric pollution

    Institute of Scientific and Technical Information of China (English)

    白爱飞; 孟庆庆

    2011-01-01

    以哈尔滨市区近年的大气监测为依据,剖析了市区大气污染物的分布特征,并探讨了市区内产生大气污染的主要原因。哈尔滨市大气污染特征表现为“煤烟型污染”。针对哈尔滨市大气污染现状,依据环境监测数据,制定出了相应的防治措施。%The city of Harbin in recent years the monitoring as the basis, analyzes the distribution characteristics of the urban air pollutants, and discusses the urban atmospheric pollution produced inside the main reason.Harbin city air pollution characteristic feature is the "MeiYanXing pollution. " In Harbin city, according to the present situation of air pollution environment monitoring data, work out the corresponding prevention measures.

  20. Public policies, atmospheric pollution and health: follow the risk decrease; Politiques publiques, pollution atmospherique et sante: poursuivre la reduction des risques

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-07-01

    This book takes stock of the air pollution effects knowledge and prevention and proposes ways of improvement of this knowledge. More specifically, advices are provided in order to promote a coordinated research program and improve the public information on the air quality. (A.L.B.)

  1. The effects of short- and long-term air pollutants on plant phenology and leaf characteristics.

    Science.gov (United States)

    Jochner, Susanne; Markevych, Iana; Beck, Isabelle; Traidl-Hoffmann, Claudia; Heinrich, Joachim; Menzel, Annette

    2015-11-01

    Pollution adversely affects vegetation; however, its impact on phenology and leaf morphology is not satisfactorily understood yet. We analyzed associations between pollutants and phenological data of birch, hazel and horse chestnut in Munich (2010) along with the suitability of leaf morphological parameters of birch for monitoring air pollution using two datasets: cumulated atmospheric concentrations of nitrogen dioxide and ozone derived from passive sampling (short-term exposure) and pollutant information derived from Land Use Regression models (long-term exposure). Partial correlations and stepwise regressions revealed that increased ozone (birch, horse chestnut), NO2, NOx and PM levels (hazel) were significantly related to delays in phenology. Correlations were especially high when rural sites were excluded suggesting a better estimation of long-term within-city pollution. In situ measurements of foliar characteristics of birch were not suitable for bio-monitoring pollution. Inconsistencies between long- and short-term exposure effects suggest some caution when interpreting short-term data collected within field studies.

  2. Assessment of population exposure to air pollution by benzene.

    Science.gov (United States)

    Tchepel, Oxana; Penedo, Ana; Gomes, Madalena

    2007-05-01

    Biomonitoring is one of the methods that allow to identify population groups that have significantly higher exposures to a particular chemical than the general population. However, use of biomonitoring is particularly useful when applied in combination with other methods of pollution exposure assessment. The current study is focused on the developing of the modelling approach to estimate population exposure to benzene through inhalation. The model is based on a microenvironment approach and is adapted to be applied in urban areas where the pattern of exposure is complex. The results provided by the model may be used in combination with human biomonitoring in order to select who and where should monitoring be done, as well as for interpretation and extrapolation of biomonitoring results.

  3. Modeling of atmospheric pollution at the regional scale: application to the Esquif campaign; Modelisation a l'echelle regionale de la pollution atmospherique: application a la campagne Esquif

    Energy Technology Data Exchange (ETDEWEB)

    Sarrat, C.

    2003-06-01

    The Esquif experimental campaign (study and simulation of air quality in Ile-de-France (Paris region, France)) took place between 1998 and 2000 with the aim of better understanding the dynamical and chemical processes leading to atmospheric pollution peaks in Paris. The construction of a rich and diversified database (12 periods of intensive monitoring (PIM)) has been implemented with the aim of improving the existing chemical-transport models in general and air quality forecasting models in particular. In the framework of this study, the data collected during PIM 2 and 6 were used for the validation and analysis of situations of intensive pollution, simulated with the meso-scale numerical meteorological and chemical model Meso-NHC. The validation of both the dynamic fields (temperature and potential temperature, wind, height of the boundary layer) and the chemical fields (mainly O{sub 3}, NO{sub x}, NO{sub y}, PAN, isoprene) of the model allows to discuss some of the parameters of the model such as the initialization, the boundary forcing and the resolution. Then, a study of the dynamical processes allows to analyze the formation and reinforcement of the pollution conditions. Stress is put on the interaction of the regional scale processes with the photochemical pollution events. In this framework, the dynamical-chemical interaction processes are analyzed in detail, in particular when pollution levels are reinforced by the intrusion of residual ozone inside the convective boundary layer, dragged by the turbulence. Also, the impact of the urban hot island and of the urban wind on the redistribution of primary and secondary pollutants are considered. An analysis of the impact of hydrocarbons of biogenic origin on the ozone concentrations with respect to the temperature and to the presence of primary compounds has been performed for the PIM 2 and 6 of the Esquif campaign. (J.S.)

  4. Risk communication and human biomonitoring: which practical lessons from the Belgian experience are of use for the EU perspective?

    Directory of Open Access Journals (Sweden)

    Loots Ilse

    2008-01-01

    Full Text Available Abstract Background In order to investigate and monitor environmental health in Flanders (the Dutch speaking part of Belgium, the Flemish government funded the Centre of Expertise for Environment and Health, which started a human biomonitoring campaign in 2001. In addition to environmental health experts measuring environmental pollutants and health effects in human beings, social scientific experts at the Centre focus on risk communication associated with the human biomonitoring campaign. Methods In the literature about risk communication an evolution can be traced from traditional, one-way communication, restricted to the dissemination of information from experts to the public, to more modern, two-way risk communication, with a focus on participation and cooperation between scientists, policy-makers and the public. Within the Centre of Expertise for Environment and Health this discourse was first translated into some general principles and guidelines for external communication, at a 'Ten Commandments level'. These principles needed to be incorporated in the day-to-day practice of human biomonitoring research. Results The social scientific experts at the Centre developed a combined risk communication strategy. On the one hand the strategy consists of traditional risk communication for external communication purposes, for example information meetings and digital newsletters. On the other hand it consists of a step by step approach of incorporating more modern risk communication, for example a risk perception questionnaire, dialogical experiments for involving local stakeholders, and an action-plan for interpreting results for policy making. Conclusion With a parallel strategy of traditional and modern communication, of external and internal reflection, and through different social scientific projects, the Flemish Centre of Expertise of Environment and Health incorporates risk communication in the day-to-day practice of human biomonitoring

  5. Synthesis report: program ecosystems, transport, pollutions, 1998 - 2001; Rapport de synthese: programme ecosystemes, transport, pollutions, 1998 - 2001

    Energy Technology Data Exchange (ETDEWEB)

    Etchelecou, A.; Deletraz, G.; Elichegaray, Ch

    2001-04-01

    The ''Ecosystems, Transports, Pollution Program'' ETP Program, has been elaborated to evaluate the road pollution impacts on the mountain ecosystems. Four mountains valleys have been chosen: two in Alps (Chamonix and Maurienne) and two in Pyrenees (Biriatou and Vallee d'Aspe). This Program presents six objectives: the road traffic characterization, the pollutants emission estimation, the pollutants concentrations in the air, the pollutants dispersion according to relief, the relationships between pollutants emissions and bio-monitoring, the road pollution effects on nearby ecosystems. (A.L.B.)

  6. The First Nations Biomonitoring Initiative-FNBI.

    Science.gov (United States)

    La Corte, Elsa; Wuttke, Stuart

    2012-02-01

    The First Nations Biomonitoring Initiative (FNBI) pilot study was implemented in the winter 2010/2011, sampling 252 First Nations people on reserve in Canada for a suite of chemical contaminants following Cycle 1 of the Canadian Health Measures Survey (CHMS). Results will be sent confidentially to participants and a community report will be presented after the analysis of results, expected to be completed by fall of 2011. The national scale of the study will take place during the summer 2011/2012 and aims to sample thirteen communities with a participation of 42 First Nations people per community. Results are expected for spring 2012/2013.

  7. AICE Survey of USSR Air Pollution Literature, Volume 15: A Third Compilation of Technical Reports on the Biological Effects and the Public Health Aspects of Atmospheric Pollutants.

    Science.gov (United States)

    Nuttonson, M. Y.

    Ten papers were translated: Maximum permissible concentrations of noxious substances in the atmospheric air of populated areas; Some aspects of the biological effect of microconcentrations of two chloroisocyanates; The toxicology of low concentrations of aromatic hydrocarbons; Chronic action of low concentrations of acrolein in air on the…

  8. Critical Evaluation of Air-Liquid Interface Cell Exposure Systems for in Vitro Assessment of Atmospheric Pollutants

    Science.gov (United States)

    We compared various in vitro exposure systems for their ability to expose cells to particles and gases. The systems tested use different mechanisms to deliver multi-pollutants to the cells: diffusion, sedimentation, thermophoresis (THP) and electrostatic precipitation (ESP). Vari...

  9. Influence of synoptic and local atmospheric patterns on PM10 air pollution levels: a model application to Naples (Italy)

    CERN Document Server

    Fortelli, Alberto; Mazzarella, Adriano

    2016-01-01

    We investigate the relationship between synoptic/local meteorological patterns and PM10 air pollution levels in the metropolitan area of Naples, Italy. We found that severe air pollution crises occurred when the 850 and 500 hpa geopotential heights and their relative temperatures present maximum values above the city. The most relevant synoptic parameter was the 850 hPa geopotential height, which is located about 1500 m of altitude. We compared local meteorological conditions (specifically wind stress, rain amount and thermal inversion) against the urban air pollution levels from 2009 to 2013. We found several empirical criteria for forecasting high daily PM10 air pollution levels in Naples. Pollution crises occurred when (a) the wind stress was between 1 and 2 m/s, (b) the thermal inversion between two strategic locations was at least 3{\\deg}C/200m and (c) it did not significantly rain for at least 7 days. Beside these meteorological conditions, severe pollution crises occurred also during festivals when fir...

  10. GLANCE - calculatinG heaLth impActs of atmospheric pollutioN in a Changing climatE

    Science.gov (United States)

    Vogel, Leif; Faria, Sérgio; Markandya, Anil

    2016-04-01

    Current annual global estimates of premature deaths from poor air quality are estimated in the range of 2.6-4.4 million, and 2050 projections are expected to double against 2010 levels. In Europe, annual economic burdens are estimated at around 750 bn €. Climate change will further exacerbate air pollution burdens; therefore, a better understanding of the economic impacts on human societies has become an area of intense investigation. European research efforts are being carried out within the MACC project series, which started in 2005. The outcome of this work has been integrated into a European capacity for Earth Observation, the Copernicus Atmospheric Monitoring Service (CAMS). In MACC/CAMS, key pollutant concentrations are computed at the European scale and globally by employing chemically-driven advanced transport models. The project GLANCE (calculatinG heaLth impActs of atmospheric pollutioN in a Changing climatE) aims at developing an integrated assessment model for calculating the health impacts and damage costs of air pollution at different physical scales. It combines MACC/CAMS (assimilated Earth Observations, an ensemble of chemical transport models and state of the art ECWMF weather forecasting) with downscaling based on in-situ network measurements. The strengthening of modelled projections through integration with empirical evidence reduces errors and uncertainties in the health impact projections and subsequent economic cost assessment. In addition, GLANCE will yield improved data accuracy at different time resolutions. This project is a multidisciplinary approach which brings together expertise from natural sciences and socio economic fields. Here, its general approach will be presented together with first results for the years 2007 - 2012 on the European scale. The results on health impacts and economic burdens are compared to existing assessments.

  11. Marine Pollution Prevention Act

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Marine Pollution Prevention Act of 2008 implements the International Convention for the Prevention of Pollution from Ships, including related Protocols (MARPOL)...

  12. Influence of synoptic and local atmospheric patterns on PM10 air pollution levels: a model application to Naples (Italy)

    Science.gov (United States)

    Fortelli, Alberto; Scafetta, Nicola; Mazzarella, Adriano

    2016-10-01

    We investigate the relationship between synoptic/local meteorological patterns and PM10 air pollution levels in the metropolitan area of Naples, Italy. We found that severe air pollution crises occurred when the 850 and 500 hpa geopotential heights and their relative temperatures present maximum values above the city. The most relevant synoptic parameter was the 850 hPa geopotential height, which is located about 1500 m of altitude. We compared local meteorological conditions (specifically wind stress, rain amount and thermal inversion) against the urban air pollution levels from 2009 to 2013. We found several empirical criteria for forecasting high daily PM10 air pollution levels in Naples. Pollution crises occurred when (a) the wind stress was between 1 and 2 m/s, (b) the thermal inversion between two strategic locations was at least 3°C/200 m and (c) it did not significantly rain for at least 7 days. Beside these meteorological conditions, severe pollution crises occurred also during festivals when fireworks and bonfires are lighted, and during anomalous breeze conditions and severe fire accidents. Finally, we propose a basic model to predict PM10 concentration levels from local meteorological conditions that can be easily forecast a few days in advance. The synthetic PM10 record predicted by the model was found to correlate with the PM10 observations with a correlation coefficient close to 0.80 with a confidence level greater than 99%. The proposed model is expected to provide reliable information to city officials to carry out practical strategies to mitigate air pollution effects. Although the proposed model equation is calibrated on the topographical and meteorological conditions of Naples, it should be easily adaptable to alternative locations.

  13. Biomonitoring of selected freshwater macrophytes to assess lake trace element contamination: a case study of Nal Sarovar Bird Sanctuary, Gujarat, India

    Directory of Open Access Journals (Sweden)

    Rita N. KUMAR

    2006-02-01

    Full Text Available A biomonitoring study was carried out at Nal Sarovar Bird Sanctuary, a proposed Ramsar site, Gujarat State, India, to ascertain the degree of trace element contamination. The study focused on assessment of trace element contamination in certain aquatic macrophytes to be used as biomonitors, in comparison with the sediments (abiotic monitor for heavy metal pollution. Good information was provided by analyzing roots, stems and leaves of native aquatic plants (biomonitors represented by eight species: Bergia odorata, Hydrilla verticillata, Ipomoea aquatica, Najas graminea, Nelumbo nucifera, Phragmites karka, Typha angustata and Vellisnaria spiralis, alongwith surface sediments and water, were analyzed for Cd, Co, Cu, Cu, Ni, Pb and Zn contamination. The highest concentrations of the trace elements were measured in Ipomoea aquatica and the lowest in Bergia odorata. Based on the concentration and toxicity status observed in the lake's vegetation, the six metals are arranged in the following decreasing order: Zn > Cu > Ni > Co > Pb > Cd. Compared with the standard, normal and critical toxicity range in plants, the detected values of Cd and Pb falls within normal range, while that of Co, Ni and Cu were within the critical range. However, Zn showed the highest concentration and alarming toxicity levels, which is considered as one of the most hazardous pollutants in Nal Sarovar Bird Sanctuary. Certain aquatic macrophytes species are also proposed as biomonitors for the investigated heavy metal pollutants. Such result was significant in the plant species such as Ipomoea aquatica and Phragmites karka, which are the two most useful species in biomonitoring studies due to their ability to accumulate elements in high concentration in the roots and their availability throughout the year. The results showed the significant difference in accumulation rate of some metals like Zn, Cu and Ni in different plant organs, which showed more accumulation in root than

  14. Assessment of atmospheric pollution of chemical elements by epiphytic lichen analysis at the Campus of the Sao Paulo University; Avaliacao da poluicao atmosferica de elementos quimicos pela analise de liquen epifitico no Campus da Cidade Universitaria de Sao Paulo

    Energy Technology Data Exchange (ETDEWEB)

    Rocha, Rosiana Rocho

    2015-07-01

    Air pollution has been a frequent topic of research, due to the effects that it can cause on the health of living organisms, environment and climate. In order to identify pollution sources and their effects, biomonitoring has been studied due to its low cost and possibility of sampling in wide geographic areas. In this study for passive biomonitoring of air pollution levels at the Cidade Universitaria Armando Salles de Oliveira (CUASO), University of Sao Paulo campus, epiphytic lichens of Canoparmelia texana species were used. The lichens collected from tree barks at different sampling sites in the CUASO were cleaned, freeze-dried and ground for analyses. Lichen samples were analyzed by X - ray fluorescence spectrometry (XRFS) and neutron activation analysis (NAA). For XRFS, cylindrical pellets of samples were prepared to determine As, Br, Ca, Cl, Cr, Cu, Fe, K, Mn, Rb, S, Sr and Zn. For NAA, lichen sample aliquots along with synthetic elemental standards were irradiated both for short and long periods at the IEA-R1 nuclear research reactor. The induced activities were measured by a gamma ray spectrometer to determine As, Br, Ca Cd, Cl, Co, Cr, Cs, Cu, Fe, K, La, Mg, Mn, Rb, Sb, Sc, Se, U, V and Zn. The precision and accuracy of the results were evaluated by the analysis of certified reference materials (MRCs). Their results of relative errors and standard deviations were below 15% for most of the elements. The standardized difference or En score values were lower than |1| indicating satisfactory results. Replicate analyses of a lichen sample by XRFS and NAA, indicated good homogeneity of the sample for the elements determined. The lichen results showed that the mean concentrations of As, Br, Ca, Cd, Co, Cr, Cs, Rb, Sb, Se and U were higher in samples from CUASO than those from regions considered unpolluted. For Fe, K, La, S, V and Zn, they were of the same order of magnitude. The correlation study between the elements showed high correlation (r > 0.7) for elements

  15. Epiphytic Moss as a Biomonitor for Nitrogen Deposition

    Science.gov (United States)

    Rolfe, T.; Deakova, T.; Shortlidge, E.; Rao, M.; Rosenstiel, T. N.; Rice, A. L.; George, L. A.

    2014-12-01

    Tracking nitrogen (N) deposition patterns is important for understanding how anthropogenic sources of nitrogen affect natural habitats, human health, and for evaluating computer models of future N deposition. It can also aid in tracking and modeling anthropogenic fossil fuel emissions. This pilot study investigated the use of Orthotrichum lyellii, a common urban epiphytic moss, as a possible bioindicator for N deposition through the analysis of total moss N content and N isotopic fractionation ( δ15N) for evaluating N sources. In the spring/summer of 2013 we collected 168 O. lyellii samples from the trunks of deciduous trees in 53 locations in the Portland metropolitan area. In the winter of 2013-14, we resampled the same locations to investigate the effect of seasonality. The averaged summer moss N content were plotted against a land use regression model (LUR) developed by taking NOx samples from 144 sites in the Portland area within the Urban Growth Boundary. The correlation between moss N and modeled NO2 was found to be significant at p moss samples N content ranged between 0.71% and 3.36% (mean of 1.87%), the δ15N ranged -8.97‰ and 11.78‰ (mean of -0.91‰). Moss winter N content ranged between .77% and 3.12% (mean of 1.71%), and the δ15N ranged -10.40‰ and 10.27‰ (mean of -3.73‰). The average values for %N and δ15N fall within the range of previous studies in other moss samples, however the maximum values are higher than what other studies have typically found for both %N and δ15N. A significant correlation between δ15N and %N was found (r = 0.67). The moss samples showed a similar pattern of higher N content and δ15N near the urban center decreasing with distance from major roadways and other significant sources of fossil fuel derived NOx. These results indicated the sensitivity of O.lyellii to N and the potential for its use as a biomonitor. With sufficient sampling density, using O. lyellii as an inexpensive biomonitor to evaluate local

  16. 被动DOAS/CT在大气污染气体监测中的应用%Detection of the atmospheric pollutant by using passive DOAS

    Institute of Scientific and Technical Information of China (English)

    韦民红; 童敏明; 魏明生; 李素文

    2013-01-01

    为了对大气污染气体的空间分布进行实时监测,有效防治大气环境污染,设计了被动差分吸收光谱层析系统,通过差分吸收光谱技术(DOAS)获取大气污染气体的积分体积分数,再采用联合迭代重构算法(SIRT)得到其空间分布信息,通过数值模拟的方式加以验证.数值模拟结果表明,实践与理论相符,满足预期指标,且投影误差基本不影响重构图像的质量.试验结果表明,系统可以实现大气污染气体的二维空间分布监测.%This paper is aimed to present our method for finding the atmospheric pollutant by using passive DOAS.For this purpose,we have introduced an optical tomography system based on the passive difference optical absorption spectrum (DOAS),that is,how to do real-time monitoring activities with the spatial distribution of pollution gases in the atmosphere so as to prevent the atmosphere from being polluted effectively.The goal of the system is to employ the concentration profiles,rather than just a point value,of the pollutant gases concentrations.However,the reconstruction area (20 × 20 pixels) of the concentration of the pollutant gases are to be scanned while doing on-line monitoring activities by using two sets of passive difference optical absorption spectrum (DOAS) rather than one.In addition,36 light paths are needed to be adopted in the form of the fan projection scheme to scan the area of the polluted gases.At the same time,it is to apply a novel image reconstruction algorithm,known as the simultaneous iterative reconstruction technique (SIRT),to extract the data and information from the two passive DOAS systems.The disadvantage of the SIRT is slow in speed though some improvements have already been made by adding different relax factors to reduce the relative errors.The new system of ours can work out the integrated concentration of the gases with the difference optical absorption spectrum (DOAS) algorithm.Besides,we have also introduced the

  17. Indoor and outdoor biomonitoring using lichens at urban and rural primary schools.

    Science.gov (United States)

    Canha, N; Almeida, S M; Freitas, M C; Wolterbeek, H T

    2014-01-01

    Monitoring particulate matter (PM) and its chemical constituents in classrooms is a subject of special concern within the scientific community in order to control and minimize child exposure. Regulatory sampling methods have presented several limitations in their application to larger number of classrooms due to operational and financial constraints. Consequently, passive sampling methodologies using filters were developed for indoor sampling. However, such methodologies could not provide parallel information for outdoors, which is important to identify pollution sources and assess outdoor contribution to the indoors. Therefore, biomonitoring with transplanted lichens, a technique usually applied for outdoor studies, was used both indoor and outdoor of classrooms. Three main objectives were proposed, to (i) characterize simultaneously indoor and outdoor of classrooms regarding inorganic air pollutants, (ii) investigate spatial patterns of lichen conductivity, and (iii) assess pollution sources that contribute to a poor indoor air quality in schools. Lichens Flavoparmelia caperata were transplanted to indoor and outdoor of classrooms for 59 d. After exposure, electric conductivity of lichens leachate was measured to evaluate lichen vitality and cell damage. Outdoors lichen conductivity was higher near the main highways, and indoors there was great variability in levels, which indicates different emissions sources and different ventilation patterns. Chemical content of lichens was assessed by instrumental neutron activation analysis (INAA), and As, Br, Ca, Ce, Co, Cr, Cs, Eu, Fe, Hf, K, La, Na, Rb, Sb, Sc, Sm, Sr, Ta, Th, Yb, and Zn were determined. Element accumulation, crustal enrichment factors, and spatial variability of elements were analyzed and contaminants from anthropogenic sources, such as traffic (As, Sb, and Zn) and indoor chalk (Ca) found. Classrooms with potential indoor air quality problems were identified by presenting higher accumulations of

  18. Biomonitoring program for the Rocky Mountain Arsenal National Wildlife Area

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This document provides information on historical and present biomonitoring at the Rocky Mountain Arsenal National Wildlife Refuge, and discusses the creation of the...

  19. A proposed framework for the interpretation of biomonitoring data.

    Science.gov (United States)

    Boogaard, Peter J; Money, Chris D

    2008-06-05

    Biomonitoring, the determination of chemical substances in human body fluids or tissues, is more and more frequently applied. At the same time detection limits are decreasing steadily. As a consequence, many data with potential relevance for public health are generated although they need not necessarily allow interpretation in term of health relevance. The European Centre of Ecotoxicology and Toxicology of Chemicals (ECETOC) formed a dedicated task force to build a framework for the interpretation of biomonitoring data. The framework that was developed evaluates biomonitoring data based on their analytical integrity, their ability to describe dose (toxicokinetics), their ability to relate to effects, and an overall evaluation and weight of evidence analysis. This framework was subsequently evaluated with a number of case studies and was shown to provide a rational basis to advance discussions on human biomonitoring allowing better use and application of this type of data in human health risk assessment.

  20. A proposed framework for the interpretation of biomonitoring data

    Directory of Open Access Journals (Sweden)

    Boogaard Peter

    2008-01-01

    Full Text Available Abstract Biomonitoring, the determination of chemical substances in human body fluids or tissues, is more and more frequently applied. At the same time detection limits are decreasing steadily. As a consequence, many data with potential relevance for public health are generated although they need not necessarily allow interpretation in term of health relevance. The European Centre of Ecotoxicology and Toxicology of Chemicals (ECETOC formed a dedicated task force to build a framework for the interpretation of biomonitoring data. The framework that was developed evaluates biomonitoring data based on their analytical integrity, their ability to describe dose (toxicokinetics, their ability to relate to effects, and an overall evaluation and weight of evidence analysis. This framework was subsequently evaluated with a number of case studies and was shown to provide a rational basis to advance discussions on human biomonitoring allowing better use and application of this type of data in human health risk assessment.

  1. Epiphytic lichen Flavoparmelia caperata as a sentinel for trace metal pollution

    Directory of Open Access Journals (Sweden)

    Mitrović Tatjana

    2012-01-01

    Full Text Available Widely spread lichen specie Flavoparmelia caperata is used in a biomonitoring study for atmospheric trace metal pollution in natural ecosystems in Southeastern Serbia. The concentration and distribution pattern of 21 metals in lichens were determined by inductively coupled plasma atomic emission spectrometry. The difference observed between metal deposition in peripheral and central parts of lichen thalli reflected air quality changes in the last and previous years. These findings were confirmed with principal component analysis. Our study demonstrated the accumulation of Ba, K, Mg, Na, Tl and Zn in peripheral parts of thalli, while As, B, Cd, Cr, Cu, Fe, Ga, In, Li, Ni, Pb and Se were concentrated in central parts of thalli.

  2. Atmospheric deposition, operational report for air pollution 2003. NOVA 2003; Atmosfaerisk deposition, driftsrapport for Luftforurening i 2003 NOVA 2003

    Energy Technology Data Exchange (ETDEWEB)

    Ellermann, T.; Hertel, O.; Ambelas Skjoeth, C.; Kemp, K.; Monies, C.

    2004-12-01

    This report presents measurements and calculations from the atmospheric part of NOVA 2003 and covers results for 2003. It summarises the main results concerning concentrations and depositions of nitrogen, phosphorous and sulphur compounds related to eutrofication and acidification and selected heavy metals. Depositions of atmospheric compounds to Danish marine waters as well as land surface are presented. The measurements in the monitoring programme are supplemented with model calculations of concentrations and depositions of nitrogen and sulphur compounds to Danish land surfaces as well as marine waters, fjords and bays using the ACDEP model (Atmospheric Chemistry and Deposition). The model is a so-called trajectory model and simulates the physical and chemical processes in the atmosphere using meteorological and emission data input. (BA)

  3. Design and application of a mobile ground-based observatory for continuous measurements of atmospheric trace gas and criteria pollutant species

    Science.gov (United States)

    Bush, S. E.; Hopkins, F. M.; Randerson, J. T.; Lai, C.-T.; Ehleringer, J. R.

    2015-08-01

    Ground-based measurements of atmospheric trace gas species and criteria pollutants are essential for understanding emissions dynamics across space and time. Gas composition in the lower 50 m of the atmosphere has the greatest direct impacts on human health as well as ecosystem processes; hence data at this level are necessary for addressing carbon-cycle- and public-health-related questions. However, such surface data are generally associated with stationary measurement towers, where spatial representation is limited due to the high cost of establishing and maintaining an extensive network of measurement stations. We describe here a compact mobile laboratory equipped to provide high-precision, high-frequency, continuous, on-road synchronous measurements of CO2, CO, CH4, H2O, NOx, O3, aerosol, meteorological, and geospatial position data. The mobile laboratory has been deployed across the western USA. In addition to describing the vehicle and its capacity, we present data that illustrate the use of the laboratory as a powerful tool for investigating the spatial structure of urban trace gas emissions and criteria pollutants at spatial scales ranging from single streets to whole ecosystem and regional scales. We assess the magnitude of known point sources of CH4 and also identify fugitive urban CH4 emissions. We illustrate how such a mobile laboratory can be used to better understand emissions dynamics and quantify emissions ratios associated with trace gas emissions from wildfire incidents. Lastly, we discuss additional mobile laboratory applications in health and urban metabolism.

  4. Air ion and pollution index variation for indoor and outdoor atmosphere at rural station Ramanandnagar (17° 4′N, 74° 25′) India

    Indian Academy of Sciences (India)

    S D Pawar

    2013-02-01

    In the present study, the observation of indoor air ion concentration at a rural site has been carried out for the first time. These indoor observations are compared with outdoor air ion concentration. Net charge can be introduced into the atmosphere by processes such as combustion, rainfall and ultraviolet radiation. As compared to indoors, average air ions of both the polarities at outdoors are higher. Moreover, the air ion concentrations, experience large fluctuations during daytime, as compared to nighttime values. Positive and negative air ion concentrations are lower and uniform throughout the night both for indoor and outdoor conditions. Pollution index is more or less unity for outdoors in all-the-time period, which is good for human health. Due to limited sources of air ions indoors, it is observed that pollution index decreases from 00:00–02:00 hours and minimum is reached during 12:00–14:00 hours for indoors. During 00:00–02:00 hours, the indoor pollution index is 1.55, which is very harmful to human health.

  5. Atmospheric deposition of beryllium in Central Europe: comparison of soluble and insoluble fractions in rime and snow across a pollution gradient.

    Science.gov (United States)

    Bohdalkova, Leona; Novak, Martin; Voldrichova, Petra; Prechova, Eva; Veselovsky, Frantisek; Erbanova, Lucie; Krachler, Michael; Komarek, Arnost; Mikova, Jitka

    2012-11-15

    Little is known about atmospheric input of beryllium (Be) into ecosystems, despite its highly toxic behavior. For three consecutive winters (2009-2011), we measured Be concentrations in horizontal deposition (rime) and vertical deposition (snow) at 10 remote mountain-top locations in the Czech Republic, Central Europe. Beryllium was determined both in filtered waters, and in HF digests of insoluble particles. Across the sites, soluble Be concentrations in rime were 7 times higher, compared to snow (6.1 vs. 0.9ng·L(-1)). Rime scavenged the pollution-rich lower segments of clouds. The lowest Be concentrations were detected in the soluble fraction of snow. Across the sites, 34% of total Be deposition occurred in the form of soluble (bioavailable) Be, the rest were insoluble particles. Beryllium fluxes decreased in the order: vertical dry deposition insoluble>vertical dry deposition soluble>horizontal deposition soluble>vertical wet deposition insoluble>vertical wet deposition soluble>horizontal deposition insoluble. The average contributions of these Be forms to total deposition were 56, 21, 8, 7, 5 and 3%, respectively. Sites in the northeast were more Be-polluted than the rest of the country with sources of pollution in industrial Silesia.

  6. Integration of biomonitoring and instrumental techniques to assess the air quality in an industrial area located in the coastal of central Asturias, Spain.

    Science.gov (United States)

    Almeida, Susana Marta; Lage, Joana; Freitas, Maria do Carmo; Pedro, Ana Isabel; Ribeiro, Tiago; Silva, Alexandra Viana; Canha, Nuno; Almeida-Silva, Marina; Sitoe, Timóteo; Dionisio, Isabel; Garcia, Sílvia; Domingues, Gonçalo; de Faria, Julia Perim; Fernández, Beatriz González; Ciaparra, Diane; Wolterbeek, Hubert T

    2012-01-01

    Throughout the world, epidemiological studies were established to examine the relationship between air pollution and mortality rates and adverse respiratory health effects. However, despite the years of discussion the correlation between adverse health effects and atmospheric pollution remains controversial, partly because these studies are frequently restricted to small and well-monitored areas. Monitoring air pollution is complex due to the large spatial and temporal variations of pollution phenomena, the high costs of recording instruments, and the low sampling density of a purely instrumental approach. Therefore, together with the traditional instrumental monitoring, bioindication techniques allow for the mapping of pollution effects over wide areas with a high sampling density. In this study, instrumental and biomonitoring techniques were integrated to support an epidemiological study that will be developed in an industrial area located in Gijon in the coastal of central Asturias, Spain. Three main objectives were proposed to (i) analyze temporal patterns of PM₁₀ concentrations in order to apportion emissions sources, (ii) investigate spatial patterns of lichen conductivity to identify the impact of the studied industrial area in air quality, and (iii) establish relationships amongst lichen conductivity with some site-specific characteristics. Samples of the epiphytic lichen Parmelia sulcata were transplanted in a grid of 18 by 20 km with an industrial area in the center. Lichens were exposed for a 5-mo period starting in April 2010. After exposure, lichen samples were soaked in 18-MΩ water aimed at determination of water electrical conductivity and, consequently, lichen vitality and cell damage. A marked decreasing gradient of lichens conductivity relative to distance from the emitting sources was observed. Transplants from a sampling site proximal to the industrial area reached values 10-fold higher than levels far from it. This finding showed that

  7. Atmospheric impacts of the 2010 Russian wildfires: integrating modelling and measurements of the extreme air pollution episode in the Moscow megacity region

    Directory of Open Access Journals (Sweden)

    I. B. Konovalov

    2011-04-01

    Full Text Available Numerous wildfires provoked by an unprecedented intensive heat wave caused continuous episodes of extreme air pollution in several Russian cities and densely pullulated regions, including the Moscow megacity region. This paper analyzes the chemical evolution of the atmosphere over the Moscow region during the 2010 heat wave by integrating available ground based and satellite measurements with results of meso-scale modeling. The state-of-the-art CHIMERE CTM is used, which is modified to take into account air pollutant emissions from wildfires and the shielding effect of smoke aerosols. The wild fire emissions are derived from satellite measurements of the fire radiative power and are optimized by assimilating data of ground measurements of carbon monoxide (CO and particulate matter (PM10 into the model. It is demonstrated that the optimized simulations reproduce independent observations, which were withheld during the optimisation procedure, quite adequately (specifically, the correlation coefficient of daily time series of CO and PM10 exceeds 0.8 and that inclusion of the fire emissions into the model significantly improves its performance. The results of the analysis show that wildfires were a principal factor causing the observed air pollution episodes associated with the extremely high level of daily mean CO and PM10 concentrations (up to 10 mg m−3 and 700 μg m−3 in the averages over available monitoring sites, respectively in the Moscow region, although accumulation of anthropogenic pollution was also favoured by a stagnant meteorological situation. In contrast, diagnostic model runs indicate that ozone concentrations could reach very high values even without fire emissions which provide "fuel" for ozone formation, but, at the same time, inhibit it as a result of absorption and scattering of solar radiation by smoke aerosols. The analysis of MOPITT CO measurements and of

  8. Source apportionment of atmospheric pollutants based on the online data by using PMF and ME2 models at a megacity, China

    Science.gov (United States)

    Liu, Baoshuang; Yang, Jiamei; Yuan, Jie; Wang, Jiao; Dai, Qili; Li, Tingkun; Bi, Xiaohui; Feng, Yinchang; Xiao, Zhimei; Zhang, Yufen; Xu, Hong

    2017-03-01

    From 1st June to 31st August 2015, the online datasets (the water soluble inorganic ions (WSIIs), OC and EC in PM2.5, and SO2, NO2, NO) were measured continuously at Tianjin. Source apportionment of atmospheric pollutants was carried out by using PMF and ME2 models based on the online datasets. During summer in Tianjin, the ammonium sulfate/ammonium hydrogen sulfate might be major forms of sulfate in the atmospheric aerosol, while the ammonium nitrate might be major forms of nitrate. The poor correlation between OC and EC might be caused by the changes of emission sources and the production of secondary organic carbon (SOC). Five source-categories that contributed to atmospheric pollutants were extracted by PMF and ME2 models, respectively. The profiles calculated by PMF and ME2 models were consistent, and the source contributions estimated by the two models were also similar. The correlations (R2 = 0.84-0.94) were better on the time series of the contributed concentrations for the same source-category calculated from PMF and ME2 models. The source-categories were identified as secondary sources (the contribution of 25.4-26.1%), vehicle exhaust (23.3-25.4%), coal combustion (16.5-18.2%), crustal dust (13.2-14.0%) and biomass burning (9.1-10.2%). For the same source-category identified from PMF and ME2 models, the differences of profiles might be attributed to the differences of calculated methods from the two models and the uncertainties of the online datasets.

  9. Atmospheric Pb-pollution by pre-medieval mining detected in the sediments of the brackish karst lake An Loch Mor, western Ireland

    Energy Technology Data Exchange (ETDEWEB)

    Schettler, G. [GeoForschungsZentrum Potsdam, Telegrafenberg, D-14473 Potsdam (Germany)]. E-mail: schet@gfz-potsdam.de; Romer, R.L. [GeoForschungsZentrum Potsdam, Telegrafenberg, D-14473 Potsdam (Germany)

    2006-01-15

    This paper presents results of geochemical investigations of lake sediments from the karst lake An Loch Mor, Aran Islands, including the first highly resolved record of atmospheric Roman Pb pollution for Ireland. The natural Pb influx into the lake is largely contributed by 3 Pb components, which differ in their isotopic composition: detrital influx of Pb from the siliciclastic input, dissolved influx of Pb released by weathering of the local limestone, and dissolved influx of seawater Pb. The balance between the 3 Pb components varies in concert with the hydrological evolution of the lake. The influx of Pb in dissolved form is estimated by geochemical mass balance assuming that the siliciclastic influx is characterised by the Pb/Al-ratio of the Late Glacial clastic sediments. It typically accounts for 50-80% of total Pb input in the Holocene sediments of An Loch Mor. The natural dissolved influxes of Pb, Sc, and Y reach a similar order of magnitude. Normalisation with Sc and Y is applied to quantify contributions from anthropogenic Pb. Based on continuous sampling of 1 cm sample slices, variations in the influx of Roman Pb could be reconstructed at a time resolution of c. 5 a. Combined geochemical and Pb isotope mass balance is used to characterise the isotopic composition of anthropogenic Pb. Distinctly enhanced influx of anthropogenic Pb occurs in the 1st and 2nd century AD and shows high variability on decadal scale. This is in contrast to central European Pb records, which document a gradual increase and decrease in ancient atmospheric pollution by Roman Pb. The reconstructed high variability in the influx of Roman Pb in An Loch Mor documents variations in the wind regime of western Europe, temporarily favouring the transport of atmospheric Pb to western Ireland.

  10. Terrestrial gastropods (Helix spp) as sentinels of primary DNA damage for biomonitoring purposes: a validation study.

    Science.gov (United States)

    Angeletti, Dario; Sebbio, Claudia; Carere, Claudio; Cimmaruta, Roberta; Nascetti, Giuseppe; Pepe, Gaetano; Mosesso, Pasquale

    2013-04-01

    We validated the alkaline comet assay in two species of land snail (Helix aspersa and Helix vermiculata) to test their suitability as sentinels for primary DNA damage in polluted environments. The study was conducted under the framework of a biomonitoring program for a power station in Central Italy that had recently been converted from oil to coal-fired plant. After optimizing test conditions, the comet assay was used to measure the % Tail DNA induced by in vitro exposure of hemocytes to different concentrations of a reactive oxygen species (H2 O2 ). The treatment induced significant increases in this parameter with a concentration effect, indicating the effectiveness of the assay in snail hemocytes. After evaluating possible differences between the two species, we sampled them in three field sites at different distances from the power station, and in two reference sites assumed to have low or no levels of pollution. No species differences emerged. Percent Tail DNA values in snails from the sites near the power station were higher than those from control sites. An inverse correlation emerged between % Tail DNA and distance from the power station, suggesting that the primary DNA damage decreased as distance increased away from the pollution source. Detection of a gradient of heavy metal concentration in snail tissues suggests that these pollutants are a potential cause of the observed pattern. The comet assay appears to be a suitable assay and Helix spp. populations suitable sentinels to detect the genotoxic impact of pollutants.

  11. A preliminary attempt to identify atmospherically-derived pollution particles in English topsoils from magnetic susceptibility measurements

    Science.gov (United States)

    Hay, K. L.; Dearing, J. A.; Baban, S. M. J.; Loveland, P.

    This study identifies topsoils in England having increased magnetic susceptibility (xlf) values attributable to the presence of anthropogenically produced pollution particles, such as fly-ash. The database consists of 1176 topsoils taken at 10 km intervals across the whole of England, and tested for magnetic susceptibility at low and high frequencies. Soils containing significant concentrations of pollution particles were identified using two criteria; xlf (values > 0.38 10-6m3kg-1) and xfd% (values < 3%). The ‘polluted’ topsoils are located in the south-east around London, the Midlands, the north around the conurbations of Manchester, Merseyside and West Yorkshire, and in the north-east around Newcastle and Teeside. The heavy metal concentration of the soils are elevated above background levels, and have strong positive relationships with magnetic susceptibility and other magnetic parameters.

  12. The effects of recent control policies on trends in emissions of anthropogenic atmospheric pollutants and CO2 in China

    OpenAIRE

    Zhao, Y.; Zhang, Junying; Nielsen, Chris

    2013-01-01

    To examine the effects of China's national policies of energy conservation and emission control during 2005–2010, inter-annual emission trends of gaseous pollutants, primary aerosols, and CO2 are estimated with a bottom-up framework. The control measures led to improved energy efficiency and/or increased penetration of emission control devices at power plants and other important industrial sources, yielding reduced emission factors for all evaluated species except NOx. The national emissions ...

  13. The atmospheric pollution in the area of the Goczałkowice Reservoir changes based on wet and dry deposition

    Directory of Open Access Journals (Sweden)

    Mieczysław LEŚNIOK

    2014-11-01

    Full Text Available The Goczałkowice Reservoir was formed as a result of the accumulation of waters from the Vistula River caused by the construction of the earth dam of 2980 m in length between the town of Goczałkowice-Zdrój and Zabrzeg. It is located in Subcaprathia, near the Silesian Beskids mountain range (Outer Western Carpathians. Discussed reservoir was investigated in several environmental aspects. One of those researched elements was wet and dry pollution deposition in Integrated System Supporting Management and Protection of Water Reservoir (ZiZOZap.The research on wet and dry pollution deposition was carried out at two measurement points situated on the opposite sides of the Goczałkowice Reservoir. From the east side it was a station in Goczałkowice and from the west side a station in Frelichów (fig. 1.  The location of points allowed to assess influence of air masses from different directions and define sources of the pollutants.

  14. Translating biomonitoring data into risk management and policy implementation options for a European Network on Human Biomonitoring

    Directory of Open Access Journals (Sweden)

    Schoeters G

    2008-01-01

    Full Text Available Abstract Background The "European Environment & Health Action Plan 2004–2010" originates from the concern of the European Commission on the well-being of individuals and the general population. Through this plan, the Commission has set the objectives to improve the information chain for a better understanding of the link between sources of pollution and health effects, to better identify existing knowledge gaps, and improve policy making and communication strategies. Human biomonitoring (HBM has been included as one of the tools to achieve these objectives. As HBM directly measures the amount of a chemical substance in a person's body, taking into account often poorly understood processes such as bioaccumulation, excretion, metabolism and the integrative uptake variability through different exposure pathways, HBM data are much more relevant for risk assessment than extrapolations from chemical concentrations in soil, air, and water alone. However, HBM primarily is a stepping stone between environmental and health data, and the final aim should be an integrated and holistic systematic risk assessment paradigm where HBM serves as a pivotal point between environment and health, on the one hand leaning on environmental data to provide detailed information on the sources and pathways of pollutants that enter the human body, and on the other hand clarifying new and existing hypotheses on the relationship between environmental pollutants and the prevalence of diseases. With the large amount of data that is being gathered in the different national survey projects, and which is expected to become available in Europe in the near future through the expected European Pilot Project on HBM, a framework to optimize data interpretation from such survey projects may greatly enhance the usefulness of HBM data for risk managers and policy makers. Results This paper outlines an hierarchic approach, based on the stepwise formulation of 4 subsequent steps, that

  15. Assessment of Anodonta cygnea as a Biomonitor Agent for Copper and Zinc in Anzali Wetland, Iran

    Directory of Open Access Journals (Sweden)

    Saeed Ganjali

    2014-06-01

    Full Text Available Background: Anzali wetland has been subjected to high levels of pollution due to contamination from several industrial sites in addition to agricultural chemicals. Mussels have been widely used for monitoring pollution in aquatic ecosystems, because they, as filter feeders, bioaccumulate pollutants. Therefore we decided to evaluate Anodonta cygnea for its application as a bio-monitor for copper (Cu and zinc (Zn. Methods: A. cygnea specimens and their surface sediments were gathered from three locations in Anzali wetland. Afterwards, the collected samples (the soft tissues and shells of A. cygnea as well as surface sediments were analyzed for Cu and Zn by a flame atomic absorption spectrophotometer (Model 670G. Results: The Cu and Zn concentrations in the sediments obtained from Anzali wetland were in the range of 21.05 to 25.53 for copper and 37.84 to 82.26 μg g-1 dw for zinc. The Cu and Zn levels in the soft tissue were 1.09-1.5 times and 5-7.3 times, respectively, higher than those of the shells. The CV values (% in the soft tissues and shells were 36 and 53 for Cu, and 53.5 and 150.3 for Zn respectively. Conclusions: The lower Zn variability (CV in the soft tissues of A. cygnea and significant correlation between Zn levels in the soft tissues of A. cygnea and the surface sediments indicated that the soft tissues of A. cygnea are more appropriate for bio-monitoring of Zn. Cu concentration in the sediment and Zn levels in the soft tissues were found to be comparatively higher than some of the international standards of reference.

  16. Feasibility of poplar foliages as bio-monitors for organochlorine pesticides in air

    Institute of Scientific and Technical Information of China (English)

    DAI TianYou; ZHU XiaoHua; WANG Wei; MENG Wei; YU YunJiang; LI FaSheng; YANG YongLiang; LIU Feng

    2009-01-01

    The feasibility of poplar (P. tomentosa) foliages as passive biomonitors for organochlorine pesticides In air was explored. The accumulation patterns of poplar foliages for HCHs, DDTs and HCB were similar, the amount of HCHs, DDTs and HCB increased with foliage growth in spring, and decreased thereafter. There was no obvious distinction in the accumulation styles between the adult leaf and the leaf-litter. This accumulation pattern is likely related to the growing process of the poplar foliage, and was ob-served for the first time in our work, giving an evidence for the "bud burst effect" in plants. The tech-nical HCH and DDT were used largely in history and not used in recent years, but there was a little usage of lindane and new input of o,p'DDT in recent years, and dicofol usage may be the main source of o,p'-DDT. Concentrations of HCHs, DDTs and HCB in poplar foliages were similar to those in pine needles at the corresponding period, and there is a positive strong correlation between OCP concen-tration data of two kinds of trees. It presents no difference in the accumulation style between two kinds of trees. The level of OCPs in the poplar foliage reflected the pollution status of OCPs in air. The result of this work showed that the poplar foliage can be used as the bio-monitor of OCPs in air.

  17. Bivalve Omics: State of the Art and Potential Applications for the Biomonitoring of Harmful Marine Compounds

    Directory of Open Access Journals (Sweden)

    Paola Venier

    2013-11-01

    Full Text Available The extraordinary progress experienced by sequencing technologies and bioinformatics has made the development of omic studies virtually ubiquitous in all fields of life sciences nowadays. However, scientific attention has been quite unevenly distributed throughout the different branches of the tree of life, leaving molluscs, one of the most diverse animal groups, relatively unexplored and without representation within the narrow collection of well established model organisms. Within this Phylum, bivalve molluscs play a fundamental role in the functioning of the marine ecosystem, constitute very valuable commercial resources in aquaculture, and have been widely used as sentinel organisms in the biomonitoring of marine pollution. Yet, it has only been very recently that this complex group of organisms became a preferential subject for omic studies, posing new challenges for their integrative characterization. The present contribution aims to give a detailed insight into the state of the art of the omic studies and functional information analysis of bivalve molluscs, providing a timely perspective on the available data resources and on the current and prospective applications for the biomonitoring of harmful marine compounds.

  18. Wild rodents (Dipodomys merriami) used as biomonitors in contaminated mining sites.

    Science.gov (United States)

    Espinosa-Reyes, Guillermo; Torres-Dosal, Arturo; Ilizaliturri, Cesar; Gonzalez-Mille, Donaji; Diaz-Barriga, Fernando; Mejia-Saavedra, Jesus

    2010-01-01

    Mining is one of the most important industrial activities globally; however, mining processes have critical environmental impacts, as mining is a major source of metals and metalloids that contribute significantly to the pollution of soil, sediment, water and air. Heavy metals can impact the health of exposed human populations and nonhuman receptors. This study focused on arsenic because its genotoxicity is well-known. Previously, we proposed a methodology to evaluate and integrate risk from a single source affecting different biologic receptors. Here, we propose an alternative approach estimating arsenic exposure in children and kangaroo rats using probabilistic simulation with Monte Carlo modeling. The estimates are then associated to measured DNA damage and compared to both populations of children and rodents living in contaminated and in reference areas. Finally, based on the integrated analysis of the generated information, we evaluate the potential use of wild rodents (