WorldWideScience

Sample records for atarashii nisanka tanso

  1. Survey report for fiscal 1998. Survey of trends of new CO{sub 2} fixation technology using bacteria and algae (II); 1998 nendo chosa hokokusho. Saikin sorui wo riyoshita atarashii nisanka tanso kotei gijutsu no doko chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The trend of technology is surveyed from a standpoint that, in the process of CO2 fixation using microbes for the production of useful substances, it is essential, in view of income/outgo balance and economy, to utilize their catalytic function. The survey centers about the feasibility of the utilization of organic wastes, cellulose wastes in particular, as an energy source. Special attention is paid to the energy of artificial light and laser beams. From a point of view that it is important to suppress cell multiplication and to effectively utilize only catalytic activity for the production of useful substances, the cell division mechanism of the Corynebacterium is analyzed, and the findings are compiled to facilitate the study as to whether the division may be controlled. A report is also prepared on the metabolic mechanism of a photosynthesizing bacterium that is judged to be the most promising species. Reference is made to aerobic and anaerobic bacteria. Shown are the organic compounds that are formed by CO2 gas fixation thanks to microbial or enzymatic reactions. To emphasize their importance as an energy source and to explain the conversion of biomass into useful substances, the technology and economy of conversion into fuel compounds are surveyed. The production of ethanol out of organic wastes is evaluated in the way of LCA (life cycle assessment). (NEDO)

  2. Survey report of FY 1997 on the trends of novel CO2 fixation technology using bacteria and microalgae; 1997 nendo chosa hokokusho (saikin sorui wo riyoshita atarashii nisanka tanso kotei gijutsu no doko chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    For this survey, the latest technology trends relating to microbial functions are summarized to recover and effectively utilize CO2, typical greenhouse effect gas, using microbial functions. Systematic survey and analysis are conducted concerning the microorganisms useful for fixing CO2, CO2 uptake mechanism during the microbial reactions, utilization methods of solar light and useful energy sources except solar light, highly efficient production of useful materials, and usage of produced useful materials. Research has concentrated on use of biological activities for this purpose through design of bioreactors using microorganisms (bacteria and microalgae) for efficient CO2 fixation. For the process to have net CO2 fixation as assessed by its life cycle and to make the process economically feasible, it is essential not only to fix CO2 merely in the form of biomass but in addition to convert it to useful materials by the catalytic activities of the organisms. Three categories were set for the survey, i.e., microorganisms with CO2 fixation ability, available energy for CO2 fixation, and target CO2 fixation products. 169 refs., 49 figs., 14 tabs.

  3. High molecule compound synthesis from carbon dioxide; Nisanka tanso karano kobunshi gosei

    Energy Technology Data Exchange (ETDEWEB)

    Mishima, K. [Fukuoka Univ., Fukuoka (Japan)

    2000-09-05

    Recently, synthesis of organic substances and high molecule compounds using carbon dioxide of liquid or supercritical state as raw material is paid attention so as the influential means to realize the green chemistry. A zinc based catalyst which could synthesize the activated copolymer from oxidized cyclohexane and carbon dioxide was developed by Coates, Beckman et al. The high-activated fluoridation zinc based catalyst which dissolved the high-pressure carbon dioxide was developed by Beckman, etc. The possibility of the manufacturing of the high molecule copolymer which is made from carbon dioxide and oxidized cyclohexane as a raw material was shown by an appearance of this catalyst. In addition, a synthesizing method of lactone from carbon dioxide and olefinic hydrocarbon is being examined by Beckman. If this method is used practically, the manufacturing of a gentle biodegradable polymer in the environment which is made from carbon dioxide as a raw material becomes also possible. However, adequate catalysts are necessary so that this reaction may progress. (NEDO)

  4. Survey of regulations accompanied with isolation technology of carbon dioxide; Nisanka tanso no kakuri gijutsu ni tomonau hokisei no chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Regulations, conventions and agreements relating to the discharging liquefied carbon dioxide (CO2) into the bathypelagic zone from a cruising ships are investigated. The ocean storage of CO2 is not specifically prohibited by law, but must be regulated on a global scale because such treatment may impact the marine environment. In principle, treatment with impact on the nature is prohibited. Laws of environmental conservation are completed in European, Asian, and Pacific countries, which join international conventions and committees with high interests. It is suggested that the engineering technique of the storage should be improved to observe regulations and that an impact assessment for the ocean storage should be carefully conducted in full understanding of the basic premise of the regulatory systems or organizations. Furthermore, it is significant to study on the possible effect of the ocean storage of CO2 on global warming and life-cycle assessment inventory analysis, namely the balance of the energy budget between the separation and the ocean storage of CO2. 23 refs., 7 figs., 6 tabs.

  5. Measurement and correlation of solubility of limonene and linalool in high pressure carbon dioxide; Limonene, linalool no koatsu nisanka tanso eno yokaido sokutei to sokan

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, J. [Japan Tabacco Inc., Tokyo (Japan); Nagahama, K. [Tokyo Metropolitan University, Tokyo (Japan)

    1996-01-20

    In order to carry out the deterpenation of orange oil using carbon dioxide extraction under high pressure, the solubilities of constituents were examined experimentally. Limonene and linalool were selected as the major component and a flavor component, respectively. Solubilities of each component in high pressure carbon dioxide were measured by use of a high pressure cell with glass windows at 313K and 333K and from 1 MPa to the near critical point. All isothermal solubilities had minima against pressure and they increased along with temperature. Solubility data have been correlated based not only on the regular solution theory but the SRK equation of state. The solubilities of limonene have been correlated well by the regular solution theory, and those of linalool have been represented fairly accurately by the SRK equation. 14 refs., 6 figs., 2 tabs.

  6. Investigational research on CO2 isolation technology in fiscal 1995; 1995 nendo nisanka tanso no kakuri gijutsu ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The paper studied present technical subjects and future study subjects of the CO2 isolation technology in order to clarify technical and social problems and the developmental subjects of the CO2 isolation technology and related technologies for separating/concentrating CO2 emitted in relation to quantity consumption of fossil fuel and storing it in ocean or underground. Main items for the study were: (1) investigational study of the technology of CO2 ocean storage, (2) investigational study of environmental effect assessment in storing CO2 in ocean, (3) investigational study of the technology of CO2 ocean storage, etc. Technologies required for the ocean isolation were arranged such as CO2 storage, injection, dispersion technique, CO2 behavior simulation, and the developmental subjects were extracted. Further, in the deep-sea bottom storage method, a simulation to calculate the range of PH effects was conducted presuming the specified amount of CO2 and applying known physical values, and evaluation of the CO2 ocean discharge/solution method was made. A method was also studied for experiments on water bacteria and benthos. 127 refs., 102 figs., 81 tabs.

  7. Investigational study of the CO2 balance in high temperature CO2 separation technology; Nisanka tanso koon bunri gijutsu ni okeru CO2 balance ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    An investigational study was conducted to clarify the adaptable environment and effectivity of technologies of high temperature separation/recovery/reutilization of CO2. In the study, data collection, arrangement and comparison were made of various separation technologies such as the membrane method, absorption method, adsorption method, and cryogenic separation method. With the LNG-fired power generation as an example, the adaptable environment and effectivity were made clear by making models by a process simulator, ASPEN PLUS. Moreover, using this simulator, effects of replacing the conventional steam reforming of hydrocarbon with the CO2 reforming were made clear with the methanol synthesis as an example. As to the rock fixation treatment of high temperature CO2, collection/arrangement were made of the data on the fixation treatment of the CO2 separated at high temperature into basic rocks such as peridotite and serpentinite in order to clarify the adaptable environment and effectivity of the treatment. Besides, a potentiality of the fixation to concrete waste was made clear. 57 refs., 57 figs., 93 tabs.

  8. Research and survey report of FY 1997 on the CO2 balance for high-temperature CO2 fixation and utilization technology; 1997 nendo chosa hokokusho (nisanka tanso koon bunri gijutsu ni okeru CO2 balance ni kansuru chosa kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The purpose of this research is to clarify the application condition and effectiveness of high-temperature CO2 fixation and utilization technology. To evaluate the present process, it was compared with others, such as separation using a polymer membrane, physico-chemical absorption process, adsorption process, hydrogen contact reduction process, and biological fixation. The development trends of absorption, membrane, adsorption, and cryogenic separation were investigated. The questionnaire was carried out about the separation technologies which are in the stage of performance test using actual gas, to arrange and compare the data and information. The current trends of chemical and biological CO2 fixation and utilization technology were also investigated for arranging the subjects. High-temperature CO2 disposal by the carbonation in concrete waste has been studied, to clarify its application conditions and effectiveness. In order to compare the separation technologies, treatment processes of CO2 in the exhaust gas from boilers of LNG power generation and coal fired power generation were simulated. These processes were simulated by ASPEN PLUS for the modeling. Trends of application of ASPEN PLUS and collection of information were surveyed by participating in the ASPEN WORLD. 103 refs., 51 figs., 55 tabs.

  9. Trend survey of the global environment adaptation type industrial technology. Chikyu kankyo tekiogata sangyo gijutsu doko chosa. ; Chikyu kankyo kanren kenkyu doko no chosa (nisanka tanso no kankyo fuka teigensaku ni kansuru chosa kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    1992-03-01

    The paper studies the measures for reduction of environmental load of CO2 from the standpoint of chemical technology. As for methanol synthesis from CO2, accelerating of the reaction using Cu base compound catalyst is reported. Also, CO2 is methanated at high speed by low temperature waste heat using Ni-La2O3-Ru catalyst. Discussions are given on the subject for development of catalyst reaction relating to hydrogen production technology by methane reforming reaction using steam or CO2. Synthesis of polymetric materials by use of CO2 is also described. The paper mentions that it is indispensable to design high-function electrode and elucidate the reaction mechanism of electrochemical CO2 reduction for electrochemical and photochemical CO2 reduction measures. Moreover, in case of using solar energy, it is required to study photovoltaic excitation process in semiconductor electrode/ electrolyte solution interface. For production of hydrogen from CO2 by photosynthetic organisms and solar energy, the problem is control of inhibiting effect of oxygen combinedly produced. Described are production of polyhydroxy butyric acid and biodegradable polymer from CO2 and hydrogen by bacteria, and CO2 fixation imitating the enzyme reaction. 267 refs., 79 figs., 32 tabs.

  10. Reaction performance of methanation of carbon monoxide and carbon dioxide over supported ruthenium catalysts. ; Mainly on effects of remaining chlorine and dechlorination. Ruthenium tanji shokubaijo no issanka tanso oyobi nisanka tanso no methane ka no hanno tokusei. ; Shutoshite zanryu enso no eikyo to datsuenso shori no koka

    Energy Technology Data Exchange (ETDEWEB)

    Kasaoka, S.; Sasaoka, E.; Okazaki, Y.; Hanaya, M. (Okayama University, Okayama (Japan). Faculty of Engineering)

    1991-07-10

    An establishment of the methanation catalytic process is desired on CO and CO {sub 2} generated in coal gasification and other various processes. In this study as one reply to this requirement, Ru catalysts supported on ZrO {sub 2}, Al {sub 2} O {sub 3} ({theta}) and SiO {sub 2} were prepared, and the relationship between the reaction condition and the catalytic reaction performance was investigated, especially from a view to the effects of remaining chlorine in catalysts and dechlorination based on raw salt of Ru. Experiments were carried out using a flow fixed-bed reactor under an atmospheric temperature at mainly 120-350 {degree}C. The results are as follows: Knowledge was obtained about the amount of remaining chlorine after a hydrogen reduction treatment or after washing with warm water at 85 {degree}C; the effect of remaining chlorine one the catalytic activity was much larger for CO {sub 2} methanation than for CO methanation; the remaining chlorine suppresses the formation of carbonaceous species on the catalyst surface and decreases the catalytic activity; and Ru/ZrO {sub 2}, dechlorinated with water washing at 85 {degree}C is most active. 10 refs., 12 figs., 1 tab.

  11. Assimilation of atmospheric methane products in the MACC-II system: from SCIAMACHY to TANSO and IASI

    Directory of Open Access Journals (Sweden)

    S. Massart

    2014-01-01

    Full Text Available The Monitoring Atmospheric Composition and Climate Interim Implementation (MACC-II delayed-mode (DM system has been producing an atmospheric methane (CH4 analysis 6 months behind real time since June 2009. This analysis used to rely on the assimilation of the CH4 product from the SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY instrument on board Envisat. Recently the \\textit{Laboratoire de Météorologie Dynamique} (LMD CH4 products from the Infrared Atmospheric Sounding Interferometer (IASI and the SRON Netherlands Institute for Space Research CH4 products from the Thermal And Near-infrared Sensor for carbon Observation (TANSO were added to the DM system. With the loss of Envisat in April 2012, the DM system has to now rely on the assimilation of methane data from TANSO and IASI. This paper documents the impact of this change in the observing system on the methane tropospheric analysis. It is based on four experiments: one free run and three analyses from respectively the assimilation of SCIAMACHY, TANSO and a combination of TANSO and IASI CH4 products in the MACC-II system. The period between December 2010 and April 2012 is studied. This corresponds to a period during which the performance of SCIAMACHY was deteriorating. The SCIAMACHY experiment globally underestimates the tropospheric methane by 35 part per billion (ppb compared to the HIAPER Pole-to-Pole Observations (HIPPO data and the methane column by 23 ppb compared the Total Carbon Column Observing Network (TCCON data, when the global bias of the free run against the same HIPPO and TCCON data is respectively −5 ppb and 4 ppb. The assimilated TANSO product changed in October 2011 from version v.1 to version v.2.0. The analysis of version v.1 globally underestimates the tropospheric methane by 18 ppb compared to the HIPPO data and the column by 11 ppb compared to the TCCON data. In contrast, the analysis of version v.2.0 globally overestimates the

  12. Satellite observation of atmospheric methane: intercomparison between AIRS and GOSAT TANSO-FTS retrievals

    Science.gov (United States)

    Zou, Mingmin; Xiong, Xiaozhen; Saitoh, Naoko; Warner, Juying; Zhang, Ying; Chen, Liangfu; Weng, Fuzhong; Fan, Meng

    2016-08-01

    Space-borne observations of atmospheric methane (CH4) have been made using the Atmospheric Infrared Sounder (AIRS) on the EOS/Aqua satellite since August 2002 and the Thermal and Near-infrared Sensor for Carbon Observation Fourier Transform Spectrometer (TANSO-FTS) on the Greenhouse Gases Observing Satellite (GOSAT) since April 2009. This study compared the GOSAT TANSO-FTS thermal infrared (TIR) version 1.0 CH4 product with the collocated AIRS version 6 CH4 product using data from 1 August 2010 to 30 June 2012, including the CH4 mixing ratios and the total column amounts. The results show that at 300-600 hPa, where both AIRS and GOSAT-TIR CH4 have peak sensitivities, they agree very well, but GOSAT-TIR retrievals tend to be higher than AIRS in layer 200-300 hPa. At 300 hPa the CH4 mixing ratio from GOSAT-TIR is, on average, 10.3 ± 31.8 ppbv higher than that from AIRS, and at 600 hPa GOSAT-TIR retrieved CH4 is -16.2 ± 25.7 ppbv lower than AIRS CH4. Comparison of the total column amount of CH4 shows that GOSAT-TIR agrees with AIRS to within 1 % in the mid-latitude regions of the Southern Hemisphere and in the tropics. In the mid to high latitudes in the Northern Hemisphere, comparison shows that GOSAT-TIR is ˜ 1-2 % lower than AIRS, and in the high-latitude regions of the Southern Hemisphere the difference of GOSAT from AIRS varies from -3 % in October to +2 % in July. The difference between AIRS and GOSAT TANSO-FTS retrievals is mainly due to the difference in retrieval algorithms and instruments themselves, and the larger difference in the high-latitude regions is associated with the low information content and small degrees of freedom of the retrieval. The degrees of freedom of GOSAT-TIR retrievals are lower than that of AIRS, which also indicates that the constraint in GOSAT-TIR retrievals may be too strong. From the good correlation between AIRS and GOSAT-TIR retrievals and the seasonal variation they observed, we are confident that the thermal infrared

  13. Update on GOSAT TANSO-FTS performance, operations, and data products after more than 6 years in space

    Science.gov (United States)

    Kuze, Akihiko; Suto, Hiroshi; Shiomi, Kei; Kawakami, Shuji; Tanaka, Makoto; Ueda, Yoko; Deguchi, Akira; Yoshida, Jun; Yamamoto, Yoshifumi; Kataoka, Fumie; Taylor, Thomas E.; Buijs, Henry L.

    2016-06-01

    A data set containing more than 6 years (February 2009 to present) of radiance spectra for carbon dioxide (CO2) and methane (CH4) observations has been acquired by the Greenhouse gases Observing SATellite (GOSAT, available at http://data.gosat.nies.go.jp/GosatUserInterfaceGateway/guig/GuigPage/open.do), nicknamed "Ibuki", Thermal And Near infrared Sensor for carbon Observation Fourier Transform Spectrometer (TANSO-FTS). This paper provides updates on the performance of the satellite and TANSO-FTS sensor and describes important changes to the data product, which has recently been made available to users. With these changes the typical accuracy of retrieved column-averaged dry air mole fractions of CO2 and CH4 (XCO2 and XCH4, respectively) are 2 ppm or 0.5 % and 13 ppb or 0.7 %, respectively. Three major anomalies of the satellite system affecting TANSO-FTS are reported: a failure of one of the two solar paddles in May 2014, a switch to the secondary pointing system in January 2015, and most recently a cryocooler shutdown and restart in August 2015. The Level 1A (L1A) (raw interferogram) and the Level 1B (L1B) (radiance spectra) of version V201 described here have long-term uniform quality and provide consistent retrieval accuracy even after the satellite system anomalies. In addition, we discuss the unique observation abilities of GOSAT made possible by an agile pointing mechanism, which allows for optimization of global sampling patterns.

  14. An advanced retrieval algorithm for greenhouse gases using polarization information measured by GOSAT TANSO-FTS SWIR I: Simulation study

    Science.gov (United States)

    Kikuchi, N.; Yoshida, Y.; Uchino, O.; Morino, I.; Yokota, T.

    2016-11-01

    We present an algorithm for retrieving column-averaged dry air mole fraction of carbon dioxide (XCO2) and methane (XCH4) from reflected spectra in the shortwave infrared (SWIR) measured by the TANSO-FTS (Thermal And Near infrared Sensor for carbon Observation Fourier Transform Spectrometer) sensor on board the Greenhouse gases Observing SATellite (GOSAT). The algorithm uses the two linear polarizations observed by TANSO-FTS to improve corrections to the interference effects of atmospheric aerosols, which degrade the accuracy in the retrieved greenhouse gas concentrations. To account for polarization by the land surface reflection in the forward model, we introduced a bidirectional reflection matrix model that has two parameters to be retrieved simultaneously with other state parameters. The accuracy in XCO2 and XCH4 values retrieved with the algorithm was evaluated by using simulated retrievals over both land and ocean, focusing on the capability of the algorithm to correct imperfect prior knowledge of aerosols. To do this, we first generated simulated TANSO-FTS spectra using a global distribution of aerosols computed by the aerosol transport model SPRINTARS. Then the simulated spectra were submitted to the algorithms as measurements both with and without polarization information, adopting a priori profiles of aerosols that differ from the true profiles. We found that the accuracy of XCO2 and XCH4, as well as profiles of aerosols, retrieved with polarization information was considerably improved over values retrieved without polarization information, for simulated observations over land with aerosol optical thickness greater than 0.1 at 1.6 μm.

  15. Characterization and correction of non-linearity effect on oxygen spectra of TANSO-FTS onboard GOSAT

    Science.gov (United States)

    Suto, H.; Frankenberg, C.; Crisp, D.; kuze, A.

    2011-12-01

    The Thermal and Near Infrared Sensor for carbon Observations Fourier Transform Spectrometer (TANSO-FTS) onboard the Greenhouse gases Observing SATellite (GOSAT) collects high spectral resolution spectra of reflected sunlight in the molecular oxygen (O2) A-band near 760 nm, the carbon dioxide (CO2) bands near 1600 and 2060 nm, and the methane (CH4) band near 1660 nm. The O2 measurements are used to estimate the surface pressure and the dry air column, which are used to define the column-averaged CO2 and CH4 dry air mole fractions, XCO2 and XCH4. O2 measurements are ideal for this application because the O2 dry air mole fraction is almost constant and well known. However, systematic errors in the O2 measurements can introduce biases in the XCO2 and XCH4 retrievals from TANSO-FTS. For example, 1% overestimate of the O2 column retrievals introduced a 10 hPa high bias in surface pressure and a 4 hPa low bias in XCO2 in early retrievals. This near-global bias has been traced to uncertainties in the O2 A-band absorption cross sections. Other spatially-varying O2 errors have been traced to uncertainties in the calibration of the TANSO-FTS A-band channel. For example, non-linearity in the A-band channel response introduces errors in the depths of both O2 lines and solar Fraunhofer lines. There are three possible sources of non-linearity: detector, analogue circuit (amplifier and electric filters), and analogue to digital converter (ADC). Observations acquired with the flight instrument and laboratory experiments with TANSO-FTS engineering model (EM) is being used to discriminate and correct these errors. The EM tests have largely vindicated the silicon photo-diode detector, but show that the non-linearity of the analogue circuit and ADC is almost identical to that seen in data acquired by the on-orbit flight model. We have developed and applied a correction to the measured interferograms from the flight instrument and confirmed it validity by showing that the Fraunhofer

  16. Methane cross-validation between three Fourier transform spectrometers: SCISAT ACE-FTS, GOSAT TANSO-FTS, and ground-based FTS measurements in the Canadian high Arctic

    Science.gov (United States)

    Holl, Gerrit; Walker, Kaley A.; Conway, Stephanie; Saitoh, Naoko; Boone, Chris D.; Strong, Kimberly; Drummond, James R.

    2016-05-01

    We present cross-validation of remote sensing measurements of methane profiles in the Canadian high Arctic. Accurate and precise measurements of methane are essential to understand quantitatively its role in the climate system and in global change. Here, we show a cross-validation between three data sets: two from spaceborne instruments and one from a ground-based instrument. All are Fourier transform spectrometers (FTSs). We consider the Canadian SCISAT Atmospheric Chemistry Experiment (ACE)-FTS, a solar occultation infrared spectrometer operating since 2004, and the thermal infrared band of the Japanese Greenhouse Gases Observing Satellite (GOSAT) Thermal And Near infrared Sensor for carbon Observation (TANSO)-FTS, a nadir/off-nadir scanning FTS instrument operating at solar and terrestrial infrared wavelengths, since 2009. The ground-based instrument is a Bruker 125HR Fourier transform infrared (FTIR) spectrometer, measuring mid-infrared solar absorption spectra at the Polar Environment Atmospheric Research Laboratory (PEARL) Ridge Laboratory at Eureka, Nunavut (80° N, 86° W) since 2006. For each pair of instruments, measurements are collocated within 500 km and 24 h. An additional collocation criterion based on potential vorticity values was found not to significantly affect differences between measurements. Profiles are regridded to a common vertical grid for each comparison set. To account for differing vertical resolutions, ACE-FTS measurements are smoothed to the resolution of either PEARL-FTS or TANSO-FTS, and PEARL-FTS measurements are smoothed to the TANSO-FTS resolution. Differences for each pair are examined in terms of profile and partial columns. During the period considered, the number of collocations for each pair is large enough to obtain a good sample size (from several hundred to tens of thousands depending on pair and configuration). Considering full profiles, the degrees of freedom for signal (DOFS) are between 0.2 and 0.7 for TANSO-FTS and

  17. Validation of GOSAT/TANSO-FTS TIR UTLS CO2 data (Version 1.0 using CONTRAIL measurements

    Directory of Open Access Journals (Sweden)

    N. Saitoh

    2015-12-01

    Full Text Available The thermal infrared (TIR band of the Thermal and Near Infrared Sensor for Carbon Observation (TANSO–Fourier Transform Spectrometer (FTS on board the Greenhouse Gases Observing Satellite (GOSAT has been observing carbon dioxide (CO2 concentrations in several atmospheric layers since its launch. This study compared TANSO-FTS TIR V1.0 CO2 data and CO2 data obtained in the Comprehensive Observation Network for TRace gases by AIrLiner (CONTRAIL project in the upper troposphere and lower stratosphere (UTLS, where the TIR band of TANSO-FTS is most sensitive to CO2 concentrations, to validate the quality of the TIR V1.0 UTLS CO2 data from 287 to 162 hPa. From a comparison made during flights between Tokyo and Sydney, the averages of the TIR upper atmospheric CO2 data agreed well with the averages of the data obtained by the CONTRAIL Continuous CO2 Measuring Experiment (CME within 0.1 % for all of the seasons in the Southern Hemisphere. The results of a comparison for all of the eight airline routes showed that the agreement between the TIR and CONTRAIL CO2 data was within 0.5 % on average in the Northern Hemisphere, which was better than the agreement between a priori and CONTRAIL CO2 data. The quality of TIR lower stratospheric CO2 data depends largely on the information content, and therefore has a seasonal dependence. In high latitudes, TIR V1.0 lower stratospheric CO2 data are only valid in the summer. The magnitude of bias in the TIR upper atmospheric CO2 data did not have a clear longitudinal dependence. The comparison results for flights in northern low and middle latitudes showed that the agreement between TIR and CONTRAIL CO2 data in the upper troposphere was worse in the spring and summer than in the fall and winter. This could be attributed to a larger negative bias in the upper atmospheric a priori CO2 data in the spring and summer and a seasonal dependence of spectral bias in TANSO-FTS TIR Level 1B (L1B radiance data. The negative bias

  18. Global Analysis of Carbon Sources and Sinks with a Comprehensive Model Optimized with GOSAT/Tanso Observations

    Science.gov (United States)

    Denning, A.; Lokupitiya, R. S.; Zupanski, D.; Kawa, S. R.; Baker, D. F.; Doney, S. C.; Gurney, K. R.

    2009-12-01

    We present a system to analyze GOSAT/Tanso data using a combination of existing models of CO2 exchanges due to hourly photosynthesis and respiration, daily air-sea gas exchange, biomass burning, Fossil Fuel Emissions, and atmospheric transport. This comprehensive system allows direct comparison to the observed record of both in-situ and remotely sensed atmospheric CO2 at hourly timescales. We have previously demonstrated that a lower-resolution version of the system has good skill at replicating diurnal, synoptic, and seasonal variations over vegetated land surfaces. The system is driven by meteorological output from the NASA Goddard EOS Data Assimilation System, version 5. Surface weather from the system drives calculations of terrestrial ecosystem metabolism (radiation, precipitation, humidity, temperature) and air-sea gas exchange (wind), with other input data coming from satellite data products (e.g., fPAR and LAI from MODIS, and ocean color from SeaWiFS and MODIS). The analysis system is evaluated using synthetic data on a 2 x 2.5 degree (lat x lon) global grid. Synthetic data are sampled in cloud-free columns along the GOSAT orbital ephemeris and used to estimate multiplicative biases to component fluxes by Ensemble Data Assimilation. The system is quite successful at retrieving mechanistic estimates of spatial patterns of surface carbon fluxes on monthly and annual timescales over land, but is less skillful over the oceans.

  19. Industrial technology research and development project for global environment in fiscal 1998. Report on achievements in research and development of technologies for fixation and effective utilization of carbon dioxide by utilizing bacteria and algae; 1998 nendo saikin sorui nado riyo nisanka tanso koteika yuko riyo gijutsu kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Microorganisms are cultivated industrially in a great quantity to fix CO2 at efficiency higher than that of photosynthesis in natural world to develop technologies to re-utilize them as resources. This paper describes achievements in fiscal 1998. Existing strain samples of photosynthesized bacteria and micro-algae were screened to continue discussions on optimal culture conditions, and evaluation on properties. Genes that provide Chlorella with antibiotic resistance were introduced to have performed evaluation on function manifestation, and acquired enzymatic genes of unsaturated {omega} 3. Using green algae as the object, reduction in the processing time has resulted in acquiring a large number of fused cell colonies. Discussions were given on conditions to breed photosynthesized bacteria and fix CO2. Structural analyses were performed on CA protein as an enzyme related to take CO2 into living organisms, and on genes. Developments were carried out on a photosynthesizing bio-reactor and useful substance producing technologies on a continual basis. A 200-liter scale light collection type bio-reactor improved the fixing capacity by 30% in Chlorellas by changing the culture medium. The direct light receiving panel type bio-reactor can utilize even scattered light, with its fixing capacity per installation area exceeding the target. Fundamental data were acquired with Chlorellas on utilizing feeds, fertilizers and building materials. (NEDO)

  20. Fiscal 1996 report on the results of the R and D under a consignment from NEDO of the technology to fix and effectively use carbon dioxide using bacteria and microalgae (for public); 1996 nendo chikyu kankyo sangyo gijutsu kenkyu kaihatsu jigyo Shin Energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku (saikin sorui nado riyo nisanka tanso koteika yuko riyo gijutsu kenkyu kaihatsu seika hokokusho (kokaiyo))

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    For the purpose of contributing to the solution to the global environmental problem, a technology is developed in which by searching for/breeding/developing bacteria, etc. which conduct photosynthesis highly effectively, CO2 is fixed and recycled. The fiscal 1996 R and D is outlined as the utilization of bacteria, microalgae, etc. Obtained were microalgae exceeding the conventional strains in CO2 fixation ability, and bacteria/microalgae excellent in production of polysaccharides, hydrocarbon, lipid, biological active substances, etc. The fundamental study was continued of CO2 integrated enzyme function/reaction system as molecular biological breeding. In the cell fusion, a set-up of conditions for green algae was started. For the confirmation of performance of high dense/quantity culture technology using solar light, further improvement of performance and systematization, 200L scale testing equipment was manufactured. It is a collective reactor and enabled study of ventilation/agitation and control of light strength. A reactor analysis model was constructed. Also including the conversion into useful substances, energy/material balance was systematically studied. Collection of technical literature and information exchanges were made in Japan and overseas. 276 refs., 475 figs., 156 tabs.

  1. Industrial science and technology research and development business for fiscal 1998. Research and development achievement report on glycoconjugate production and utilization technologies (Development of technologies of glycoconjugate-aided CO{sub 2} fixation and utilization); 1998 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo. Fukugo toshitsu seisan riyo gijutsu no kenkyu kaihatsu seika hokokusho (fukugo toshitsu oyo nisanka tanso koteika yuko riyo gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Enzymatic and chemical methods were combined and methods were developed for synthesizing mucin type sugar chains and glycopeptides. The influence of sugar chain positions and structures on glycoconjugate stereo structures and physiological activities was analyzed, and glycopeptide structural activities and glycoconjugate remodelling were studied. To create an industrial advantage in a glycoprotein production system by use of zooblasts, sugar chain structure control through sugar transfase occurrence control was studied. For the production of man-adaptive sugar chains using yeast, new yeast variations were subjected to molecular breeding, and tested for the resultant improvement on productivity. Sugar chain marking and refining techniques and various responding mechanisms on the solid surface were elucidated, which enabled structure analyses using sugar chain recognition molecules such as lectins and antibodies. A database on interactions between sugar chains and sugar chain recognition molecules was constructed using the said findings. An analyzing program was also formulated tentatively. This paper also covers general surveys and studies on technologies of producing and utilizing glycoconjugates. (NEDO)

  2. Survey report for fiscal 1998. Survey of the current state and tasks of research and development of technologies for effectively utilizing CO{sub 2} fixation by higher vegetation; 1998 nendo chosa hokokusho. Koto shokubutsu ni okeru nisanka tanso koteika yuko riyo gijutsu no kenkyu kaihatsu no genjo to kadai ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Investigations and studies are conducted seeking for a CO2 fixation method improved by utilizing the photosynthesizing function of higher vegetation. Details of higher vegetation genes are being disclosed thanks to the rapid progress of studies making use of molecular biological techniques, and the application of the genetic mechanism to scientific and technological fields is becoming increasingly feasible. In particular, the role of the CO2 fixation enzyme RuBisCO has been elucidated almost completely. It has been learned that, in terms of photosynthesizing capability, the C{sub 4} plants (corn etc.) are 2-3 times higher than the C{sub 3} plants (rice, wheat, etc.), and 5-10 times higher than the CAM plants (cactuses etc.). Studies are also under way about the rice genome so that a photosynthesizing capability so high as that of the C{sub 4} plants may be endowed the rice plant. The metabolism and control of useful substances produced in the CO2 fixation process etc. in the higher vegetation are being investigated, and it is now expected that some day such useful substances will be produced and utilized efficiently. Researches are under way into the relationship between the green leaf that is the organ that performs photosynthesis and the organ (sink) that stores and utilizes starch and sugar is in progress, and now a new field is going to open where vegetables will be fully utilized. (NEDO)

  3. Trend survey of the global environment adaptation type industrial technology. Trend survey of global environment related studies (researches on measureds for reduction of environmental load of CO2); Chikyu kankyo tekiogata sangyo gijutsu doko chosa. Chikyu kankyo kanren kenkyu doko no chosa (nisanka tanso no kankyo fuka teigensaku ni kansuru chosa kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    1992-03-01

    The paper studies the measures for reduction of environmental load of CO2 from the standpoint of chemical technology. As for methanol synthesis from CO2, accelerating of the reaction using Cu base compound catalyst is reported. Also, CO2 is methanated at high speed by low temperature waste heat using Ni-La2O3-Ru catalyst. Discussions are given on the subject for development of catalyst reaction relating to hydrogen production technology by methane reforming reaction using steam or CO2. Synthesis of polymetric materials by use of CO2 is also described. The paper mentions that it is indispensable to design high-function electrode and elucidate the reaction mechanism of electrochemical CO2 reduction for electrochemical and photochemical CO2 reduction measures. Moreover, in case of using solar energy, it is required to study photovoltaic excitation process in semiconductor electrode/ electrolyte solution interface. For production of hydrogen from CO2 by photosynthetic organisms and solar energy, the problem is control of inhibiting effect of oxygen combinedly produced. Described are production of polyhydroxy butyric acid and biodegradable polymer from CO2 and hydrogen by bacteria, and CO2 fixation imitating the enzyme reaction. 267 refs., 79 figs., 32 tabs.

  4. Report on the research and development under a consignment from NEDO of high temperature carbon dioxide fixation and utilization technology for fiscal 1996; 1996 nendo Shin Energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku gyomu seika hokokusho. Nisanka tanso koon bunri kaishu sairiyo gijutsu kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    For the prevention of global warming, this R and D is aimed at separating/recovering high temperature CO2 from high temperature gas at 300degC or above and developing technology for effective use of the recovered CO2 as measures taken for reduction in CO2 emissions from the fixed emission sources. In this fiscal year, the following were proceeded with: heightening of separation performance evaluation technology, promotion of technical development of ceramic separation membranes and supports, and development of element technology of modular integration. In the examinational research on separation technology and system optimization, the following were conducted: survey of trends of the technical development, conceptual design of plant and prediction of process behavior, assessment of applicability of the process, and study of effects of utilization/spread of the developmental technology. In the former R and D, borosilicate glass powder rich in alkali is formed on the ring by joining the trially manufactured hollow fiber type membrane and the same form alumina cylinder, and sealing property and strength which stand measurement of permeability were confirmed. In the latter, an innovative process applied with CO2 high temperature separation technology was studied to examine effects of the spread of high temperature gas separation technology. 403 refs., 478 figs., 134 tabs.

  5. Fiscal 1996 global environmental industry technology research related project. Report on the results of the consignment project of research and development of technology for reducing carbon dioxide emissions; 1996 nendo chikyu kankyo sangyo gijutsu kenkyu kaihatsu kanren jigyo. Nisanka tanso nado haishutsu teigen gijutsu kenkyu kaihatsu itaku gyomu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    For the purpose of reducing emissions of carbon dioxide, freon, etc., a research project was carried out of `Research and development of technology for reducing carbon dioxide emissions` which consists of 8 projects. The paper reported the results of the projects. The projects are: (1) Development of waste water treatment of submerged combustion system, (2) Development of thermoelectric generating devices, (3) Development of high performance heat insulation materials, (4) Development of methanol reformer for transportable fuel cell, (5) Development of large pressure reducing valves, (6) Development of large-scale turbo heat pump for district heating and cooling plants, (7) Development of heat pumps for transportation equipment, and (8) Development of thermoelectric cooling devices. In (1), the waste water treatment test was conducted and reached the target. In (2), the thermoelectric device using powder sintering element obtained performance twice the performance level of the existing device. In (3), (4), (5) and (6), the target was all reached. In (7), the results well agreed in a comparison between structural analysis and experiment. The cooling unit by the SPS sintering method using Bi-Te system sintered material element obtained the cooling efficiency almost the same as that by the freon compressor method. 8 refs., 161 figs., 63 tabs.

  6. Correction of Spectral Distortion on Oxygen a-Band Due to Non-Linear Phase Delay Onboard Tanso-FTS/Gosat

    Science.gov (United States)

    Suto, H.; Butz, A.; Kuze, A.

    2014-12-01

    To observe the global column concentration of carbon dioxide (CO2) and methane (CH4) from space, the Greenhouse gases Observing SATellite (GOSAT) was launched on January 23, 2009, and has started the operational observation. Thermal and Near Infrared Sensor for Carbon Observation - Fourier Transform Spectrometer (TANSO-FTS) has been continuously measuring CO2 and CH4 distributions globally, and the retrieved column CO2 and CH4 data have been distributed to the public. To make a successful retrieval of XCO2 and XCH4, the spectral quality of Oxygen A-band is the most importance. Over five years in-orbit operation of TANSO-FTS, the spectral distortion related with input radiance on Oxygen A-band have been observed and reduced the retrieval accuracy and precision of XCO2 and XCH4. It suggests that the Oxygen A-band signal chain has non-linear response against input radiance. To characterize the non-linear response of signal chain against input signal levels, the test procedure is newly developed coupled with the modulated laser light, simultaneous signal acquisition system and on-ground TANSO-FTS, which called engineering model. The results present clearly that the analogue signal chain of Oxygen A-band excites the non-linear response both of amplitude and phase delay against input signal levels. Also, the non-linear interferogram drives both of the artificial spectra on the out-band region and the spectral distortion linked with absorption spectral lines. To improve the spectral quality of Oxygen A-band, these artificial and distorted spectra have to correct with properly. The newly correction algorithm for level-1 processing was developed and the corrected spectra were retrieved and validated by applying RemoTeC algorithm. Comparing with the previous version of level-1 products, the agreement between observation and theoretical calculation is well improved and the biases of biases of XCO2 and XCH4 against ground validation site are reduced.

  7. Intercomparison of XH2O Data from the GOSAT TANSO-FTS (TIR and SWIR and Ground-Based FTS Measurements: Impact of the Spatial Variability of XH2O on the Intercomparison

    Directory of Open Access Journals (Sweden)

    Hirofumi Ohyama

    2017-01-01

    Full Text Available Spatial and temporal variability of atmospheric water vapor (H2O is extremely high, and therefore it is difficult to accurately evaluate the measurement precision of H2O data by a simple comparison between the data derived from two different instruments. We determined the measurement precisions of column-averaged dry-air mole fractions of H2O (XH2O retrieved independently from spectral radiances in the thermal infrared (TIR and the short-wavelength infrared (SWIR regions measured using a Thermal And Near-infrared Sensor for carbon Observation-Fourier Transform Spectrometer (TANSO-FTS onboard the Greenhouse gases Observing SATellite (GOSAT, by an intercomparison between the two TANSO-FTS XH2O data products and the ground-based FTS XH2O data. Furthermore, the spatial variability of XH2O was also estimated in the intercomparison process. Mutually coincident XH2O data above land for the period ranging from April 2009 to May 2014 were intercompared with different spatial coincidence criteria. We found that the precisions of the TANSO-FTS TIR and TANSO-FTS SWIR XH2O were 7.3%–7.7% and 3.5%–4.5%, respectively, and that the spatial variability of XH2O was 6.7% within a radius of 50 km and 18.5% within a radius of 200 km. These results demonstrate that, in order to accurately evaluate the measurement precision of XH2O, it is necessary to set more rigorous spatial coincidence criteria or to take into account the spatial variability of XH2O as derived in the present study.

  8. Statistical characterization of three grades of large billet-graphites: Stackpole 2020, Union Carbide TS1792, and Toyo Tanso IG11

    Energy Technology Data Exchange (ETDEWEB)

    Kennedy, C R

    1987-09-01

    Large billets of three fine-grained, isostatically molded graphites (three billets each of grade TS1792 from Union Carbide Corporation, six billets of grade IG11 from Toyo Tanso, and thirteen billets of grade 2020 from Stackpole Corporation) were evaluated by nondestructive methods, and the results were analyzed. The results of sonic testing were shown to be interrelated to both the mean and variance of strenth obtained from destructive testing. The virtue of the nondestructive evaluation is clearly illustrated by the practical ability to evaluate up to 100% of the billet volume, thus giving a more accurate description of the materials' mechanical properties. It was shown that the randomness of the mean strength in these billets makes it very unlikely that test results from small-sample volumes removed from the billet will be representative of the billet as a whole. In critical applications requiring a high level of quality assurance, a more complete nondestructive evaluation of the billet appears to be required.

  9. Fiscal 1998 R and D project on global environmental industrial technology. Research result report on DNA analysis and information processing technology for photosynthesis microorganisms (Development of CO{sub 2} fixation and effective use technology by using bacteria and algae); 1998 nendo chikyu kankyo sangyo gijutsu kenkyu kaihatsu jigyo. Kogosei biseibutsu nado DNA kaiseki joho shori gijutsu no kenkyu (saikin sorui nado riyo nisanka tanso koteika yuko riyo gijutsu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This report summarizes the fiscal 1998 research result on DNA analysis and information processing technology for photosynthesis microorganisms. On the study on DNA analysis technology by triple-strand formation method, as the comparison study result of a READ method, stable triple- strand formation method and hairpin method, a READ method showed the highest triple-strand formation efficiency for target DNA. On the study on accurate separation technology of specific genes, establishment of protocols was promoted for solid-phase probe technology, subtract technology and leveling technology. On the study on DNA microarray analysis technology by high-efficiency hybridization method, the analysis technology of genes by hybridization method using DNA chips is under investigation. In addition, the high- efficiency analysis technology of specific DNA segments by using an affinity sensor, and the high-accuracy cloning technology for DNA with altered primary structure were also studied. (NEDO)

  10. Report on a survey in fiscal 1999. Supplementary survey on research and development of carbon dioxide fixation and effective utilization technologies utilizing bacteria and algae (the survey on feasibility of bio-technologies to create economic effects, such as the biological CO2 fixation technology); 1999 nendo saikin sorui nado riyo nisanka tanso koteika yuko riyo gijutsu kenkyu kaihatsu futai chosa. Keizaiteki koka wo soshutsusuru seibutsuteki CO{sub 2} koteigijutsu nado no biotechnology no kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Bio-technologies including the biological CO2 fixation technology, or the green bio-technologies (GBT) are the technologies indispensable in realizing the change to a resource circulating and environment harmonizing society that accompanies economical growth, or in other words, the 'sustainable development'. In quantifying the feasibility of these technologies, the GBTs that contribute to creating Japan's international competitive power and employment were specified, and an approach to establish the realization target in 2010 was adopted, upon identifying the general condition of the related markets inside and outside the country. The GBT is the technology that makes the best use of Japan's independent strength created by combining the enzyme engineering and fermentation engineering with the 'genome science' (HEART). The targets are to substitute four million kiloliters of petroleum with a resource circulation type energy generated by the bio-technology; apply the bio-technology to about 30% of products and processes produced or used in Japan's chemical industries; and aim at creating markets by using environmental measurement and analysis, treatment of hard-to-decompose substances, and supports on tree planting as the three pillars. A simulation on return on investment in GBT business suggests the effect of promoting PFI. (NEDO)

  11. Fiscal 1997 R and D project on industrial science and technology under a consignment from NEDO. R and D of the synthesis and processing of advanced biomaterials (fixation and effective utilization of carbon dioxide using peptides); 1997 nendo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Senshin bio zairyo no sosei kako gijutsu no kenkyu kaihatsu (peptide oyo nisanka tanso koteika yuko riyo gijutsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In fiscal 1997, study was made on formation of peptides with a biogenic function and molecular recognition function, and peptide materials. The existing automatic design technique of peptides including non-natural amino acids was applied to design of complementary peptides of proteins with known structures to optimize a development technique of ligand. Practical function of peptides as advanced receptor ligand was verified by applying the existing conformation control technique to stable holding of peptide active conformation. Creation of bio-materials, and development of preparation technology of bio-substrates and materializing technology of functional molecular materials were carried out. To construct an electron transfer system by self- organized body of peptides formed on a substrate, a peptide molecular device was prepared and verified using linkers. To use peptides as photoelectron functional molecule, metallized peptide with main helix structure was prepared. The possibility of molecular materials with a fixation function of CO2 was examined. A high-sensitivity bio-sensor was also mentioned. 75 refs., 130 figs., 25 tabs.

  12. Report on the results of research and development under a consignment from NEDO of glycoconjugate production utilizing technologies. Development of technologies to fix and effectively utilize carbon dioxide by applying glycoconjugates; 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Fukugo toshitsu seisan riyo gijutsu no kenkyu kaihatsu (fukugo toshitsu oyo nisanka tanso koteika yuko riyo gijutsu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper reports research results in fiscal 1997 for the `research and development of glycoconjugate production utilizing technologies`. In synthesizing, utilizing and remodeling technologies for glycoconjugates by means of chemical synthesis, studies were performed on developing methods to synthesize Gal {beta}1-3Gal NA(c {alpha})1-0-Serine in preparative scale, synthesizing high mannose type sugars of natural type without protection groups, and linking GlcNA or GalNAc onto partial peptide of fibroblast growth factor (FGF). In synthesizing, utilizing and remodeling technologies for glycoconjugates by using biological methods, studies were carried out, with regard to glycoconjugate synthesizing, utilizing and remodeling technologies utilizing animal cells, on identifying sugar structures of IFN-{gamma} produced from CHO cell line, and isolating CHO cell lines introduced with genes of sugar transferred enzyme GnTIV and/or GnTV. Furthermore, studies were conducted on glycoconjugate synthesizing, utilizing and remodeling technologies utilizing microorganisms, and glycoconjugate structure analyzing technologies. In addition, overall investigation was made on glycoconjugate production utilizing technologies. 113 refs., 76 figs., 18 tabs.

  13. Characteristics of Four-years of GOSAT/TANSO-FTS TIR V1.0 CO2 and CH4 Products

    Science.gov (United States)

    Saitoh, N.; Kimoto, S.; Sugimura, R.; Imasu, R.; Shiomi, K.; Kuze, A.; Kataoka, F.; Knuteson, R. O.; Machida, T.; Sawa, Y.; Matsuda, H.

    2015-12-01

    Greenhouse Gases Observing Satellite (GOSAT) was launched on 23 January 2009, and has continued to make global observations, including both nadir and off-nadir measurements, for more than six years since its launch. The thermal infrared (TIR) band of Thermal and Near-infrared Sensor for Carbon Observation Fourier Transform Spectrometer (TANSO-FTS) on board the GOSAT has observed CO2 and CH4 profiles. We have analyzed the four-year data from 2010 through 2013 of the latest released version of the TIR Level 2 (L2) CO2 and CH4 products (V1.0). Comparisons of the TIR upper atmospheric CO2 product with CO2 data from Comprehensive Observation Network for Trace Gases by Airliner (CONTRAIL) aircraft measurements show that the growth rate estimated from the TIR CO2 data is slightly lower than that from the CONTRAIL data. Overall, the TIR V1.0 CO2 product has better quality in the upper troposphere and lower stratosphere than the a priori judging from comparisons with the collocated aircraft data. In spring and summer, however, the quality of the TIR L2 CO2 products became slightly worse than in the other seasons, especially in the low and northern-mid latitudes. This is because the corresponding a priori had a larger bias and the TIR Level 1B (L1B) radiance spectra might have a larger bias in the spring-summer seasons. Here, we have tested several types of correction methods to modify the L1B spectral bias, and then compared CO2 and CH4 concentrations retrieved after applying spectral bias correction factors with coincident CONTRAIL and HIAPER Pole-to-Pole Observation (HIPPO) aircraft data. The comparison results suggest that the L1B spectral bias correction factor should be changed depending on wavelength. In addition, it should be expressed as a function of on-board internal calibration blackbody temperatures. This is because they are weak season-dependent parameters; they were clearly lower in spring and summer.

  14. The Greenhouse Gas Climate Change Initiative (GHG-CCI: comparative validation of GHG-CCI SCIAMACHY/ENVISAT and TANSO-FTS/GOSAT CO2 and CH4 retrieval algorithm products with measurements from the TCCON network

    Directory of Open Access Journals (Sweden)

    B. Dils

    2013-10-01

    Full Text Available Column-averaged dry-air mole fractions of carbon dioxide and methane have been retrieved from spectra acquired by the TANSO-FTS and SCIAMACHY instruments on board GOSAT and ENVISAT using a range of European retrieval algorithms. These retrievals have been compared with data from ground-based high-resolution Fourier Transform Spectrometers (FTS from the Total Carbon Column Observing Network (TCCON. The participating algorithms are the Weighting Function Modified Differential Optical Absorption Spectroscopy (DOAS algorithm (WFMD, University of Bremen, the Bremen Optimal Estimation DOAS algorithm (BESD, University of Bremen, the Iterative Maximum A Posteriori DOAS (IMAP, Jet Propulsion Laboratory (JPL and Netherlands Institute for Space Research algorithm (SRON, the proxy and full-physics versions of SRON's RemoTeC algorithm (SRPR and SRFP respectively and the proxy and full-physics versions of the University of Leicester's adaptation of the OCO (Orbiting Carbon Observatory algorithm (OCPR and OCFP respectively. The goal of this algorithm inter-comparison was to identify strengths and weaknesses of the various so-called Round Robin data sets generated with the various algorithms so as to determine which of the competing algorithms would proceed to the next round of the European Space Agency's (ESA Greenhouse Gas Climate Change Initiative (GHG-CCI project, which is the generation of the so-called Climate Research Data Package (CRDP, which is the first version of the Essential Climate Variable (ECV "Greenhouse Gases" (GHG. For CO2, all algorithms reach the precision requirements for inverse modelling ( For CH4, the precision for both SCIAMACHY products (50.2 ppb for IMAP and 76.4 ppb for WFMD fail to meet the XCH4 precision ranges between 18.1 and 14.0 ppb. Looking at the SRA, all GOSAT algorithm products reach the < 10 ppm threshold (values ranging between 5.4 and 6.2 ppb. For SCIAMACHY, IMAP and WFMD have a SRA of 17.2 ppb and 10.5 ppb respectively.

  15. New trends in biotechnology. Biotechnology no atarashii choryu

    Energy Technology Data Exchange (ETDEWEB)

    Karube, I. (The University of Tokyo, Tokyo (Japan). Research Center for Advanced Science and Technology)

    1993-11-30

    This paper focuses on application of the recent biotechnology and introduces its new trends. What has triggered the boom in the application is when the technology has been applied to medicines in the 1970's. Beginning with insulin and interferon, various fibrinolytic agents including tPA and monoclonals have been put on markets one after another in 1991. Progress in humangenomic analysis has led to implementation of gene therapies and diagnoses using genes on gene diseases. Sweeteners used in a large quantity in the foodstuff field are fructoses made by isomerizing glucose produced by using enzymatic bioreactors. Needless to say about production of amino acid, organic acids, saccharides, antibiotics, steroids, and nucleic acid-based compounds by using enzymatic bioreactors, chemicals including acrylic amide from acrylonitrile, enzyme detergents, and bio-herbicides are available commercially. Progress in the technology is seen in all of the fields, including electronics industry and environmental preservation. 6 refs., 4 figs.

  16. Synthesis of new erodable polymers response to environmental stimuli; Atarashii kankyo chowagata bunkaisei plastic no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Kato, M.; Nagasaki, Y. [Science University of Tokyo, Tokyo (Japan). Faculty of Industrial Science and Technology

    1997-02-01

    This report relates to the designing of functional materials that decompose in response to various signals. A derivative of {alpha}-bromomethylstyrene is caused to act on the living anions of {alpha}-methylstyrene for the synthesis of a pyrolytic polymer having unsaturated groups at its terminals. The terminal double combinations of this polymer split under the influence of heat, acid, or base for depolymerization which is quantative, and the decomposition temperature may be controlled by replacing terminal phenylallylic groups with methyl groups or phloro-groups. Furthermore, a novel polythyramine polymer is synthesized with its principal chain constituted of NCH2CH2Si, the principal chain easy to disintegrate when exposed to an electron beam. The polymer is signal-responsive and may be patterned by use of an electron beam. As a temperature-responsive polymer with the hydrolytic feature controlled, poly(thyroxy ethylene glycol) is obtained from a derivative of diaminosiloxane and oligo-oxyethylene. This is a high-mobility, temperature-responsive material whose hydrolysis may be controlled. 3 refs., 2 figs.

  17. Polymeric foaming in the new century; Atarashii jidai no happo seikei gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Oshima, M. [Kyoto Univ., Kyoto (Japan). Dept. of Chemical Engineering

    2000-10-20

    Industrial polymeric foams were developed near the middle of the twentieth century. A chemical blowing agent or a physical blowing agent was used to liberate a gas for expanding polymers by foams. Before the 1980, CFC was used because of its high solubility, volatility and nontoxic nature. However, its stability and reactivity with ozone raised substantial concern about ozone depletion. Since the late 1980s, responding the Montreal Protocol, polymeric foam producers started researches and made big efforts to switch CFC to friendly alternative blowing agents. In mid 1980s, the microcellular foaming created by super critical CO{sub 2} was presented in the United State. The central idea of microcellular foams was to create a large number of bubbles, smaller than the pre-existing flaws in a polymer product. Since then, a large number of innovative applications have been imagined and taken people's attentions because of the unique properties of microcellular foams. This article addresses the sate of the art of the foaming and discusses what we could elucidate so far and what we should know in the future to assure more success in foaming technology in the 21 century. (author)

  18. Suppression of numerical dispersion using FD modified operators; Atarashii sabunho no enzanshi wo mochiita suchi bunsan no yokusei

    Energy Technology Data Exchange (ETDEWEB)

    Takeuchi, N.; Geller, R. [The University of Tokyo, Tokyo (Japan). Faculty of Science

    1996-05-01

    The author, et al., have developed a formal evaluation theory for errors in numerical solutions and derived on the basis of this theory the conditions that a modified error minimizing operator should satisfy. A modified operator was derived for a calculus of finite difference in the time domain making use of this error evaluation theory. In this study, a modified operator was derived for O (2, 2) in the calculus of finite difference in time, and the operator was used in the calculation for the old and new methods about 1-dimension inhomogeneous media, and the two were quantitatively compared in CPU time and calculation accuracy. The calculation used 500 space grids and 5000 time grids. With the ratio of the time grid gap and space grid gap are kept constant, both CPU time and calculation accuracy were in proportion to the square of the number of grids. It was found in view of the result that the new method, as compared with the old method, needs only approximately 1/20 of CPU time in performing calculations of the same precision and that it maintains calculation accuracy that is approximately 20 times higher in the said CPU time. 4 refs., 2 figs., 1 tab.

  19. Development of novel processes for Cu concentrates without producing sulfuric acid; Hiryusan hasseigata no atarashii doshigen shori gijutsu no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Awakura, Y.; Hirato, T. [Kyoto University, Kyoto (Japan)

    1997-02-01

    Studies are conducted to develop a new wet method for copper concentrates to replace the conventional dry smelting method for the settlement of problems involving the processing of impurities for environmental protection. A specimen of pyrites polycrystals is subjected to leaching at 80 {degree}C in a strongly acidic cupric solution. Findings are that the element sulfur generated in this process does not impede leaching and only approximately 4% of the sulfur is oxidized into sulfur ions; that the presence of more than 2g/liter of bromide ions produced during bromine-aid leaching of gold changes the structure of sulfur for the inhibition of leaching; that circulation of a bromine-containing leaching liquid is not desired since even a small amount of approximately 0.02mol/liter inhibits the leaching rate. Controlled potential electrolysis is performed for the anode in an acid solution containing CuCl, NaCl, and NaBr, for the observation of oxidation/reduction potentials predicted by Nernst`s equation. It is then disclosed that bromine is more effective than chlorine in gold leaching and that the solution potential during leaching agent regeneration enables the monitoring of solution constitution. 2 refs.

  20. Development of novel processes for Cu concentrates without producing sulfuric acid; Hiryusan hasseigata no atarashii doshigen shori gijutsu no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, T.; Noguchi, F.; Takasu, T.; Ito, H. [Kyushu Inst. of Technology, Kitakyushu (Japan). Faculty of Engineering

    1997-02-01

    In the refining process for the production of copper from pyrites, heat treatment is carried out in a neutral atmosphere so that part of the sulphur will be collected in the form of simple sulfur and that pyrites naturally low in reactivity will be made active. A basic study is also conducted of a very high speed electrolytic method. The chemical aspects of pyrites which are various in composition (mainly CuFeS2) are clarified by X-ray diffraction, and then is subjected to heat-treatment in a 773K-1073K argon atmosphere. There is a decrease in the amount of sulfur at a temperatures not lower than 973K. The X-ray main diffraction line splits for the emergence of some lower angle diffraction lines. The specimen is then subjected to a leach test in a copper chloride base liquor, to disclose that leachability grows remarkably higher in the presence of a great change in the X-ray diffraction lattice constant. An experiment follows in which an electrolyte is allowed to flow at a high speed for accelerating the rate of electrolytic refining in an effort to prevent the passivation of anode and deposition of dendrite on the cathode that is apt to occur when the current density is high. Passivation is prevented when the flow rate is 10m/min or higher in the vicinity of the anode surface for the formation of a smooth electrodeposited surface. 2 refs., 2 figs., 2 tabs.

  1. Travel time and ray path computation in 2D-heterogeneous structures; Fukinshitsu kozo ni okeru jishinha soji oyobi hasen no atarashii keisan hoho

    Energy Technology Data Exchange (ETDEWEB)

    Fujie, G.; Kasahara, J.; Sato, T.; Mochizuki, K. [The University of Tokyo, Tokyo (Japan). Earthquake Research Institute

    1996-05-01

    Methods were studied for determining the initial travel time and ray paths with stability when an non-linear travel time inversion is performed in an inhomogeneous structure. The travel time calculation was based on Faria and Stoffa`s method. First, the 2-dimension space was sectioned by grids, and `slowness` was assigned to all the lattice points. Starting from the vibration source, travel time at each lattice point is sequentially calculated. This method calculates travel time for any structure without breakup. In this study, an algorithm more sophisticated than the method of Faria, et al., was developed, and the improvement of travel time calculation accuracy led to the accurate determination of the direction of incidence into the lattice points during the initial motion. The calculation of ray paths was effected by tracing back from the receiving points the incidence into the lattice points or by following back the ray paths to the vibration source. This method performs stable calculation for a heavily inhomogeneous structure and, with the algorithm being simple, do the parallel programming as well. 1 ref., 6 figs., 1 tab.

  2. New style of system business and reengineering of software engineering process; Atarashii system jigyo style to software sekkei no gyomu kakushin

    Energy Technology Data Exchange (ETDEWEB)

    Minami, A.; Muto, K.; Dotemoto, A. [Toshiba Corp., Tokyo (Japan)

    1999-09-01

    Toshiba is promoting a new style of system business by business process reengineering (BPR), with the sales, engineering, and software development divisions acting in concert. Virtual task force teams are changing the styles of sales and engineering. They are supported by an intranet-based system for information management and C Solution, a new system architecture. (author)

  3. Development of the hull inspection robot (RTV-SHIP); Sentai kensayo suichu robot (RTV-SHIP) no kaihatsu (atarashii sentai kensaho no ichiteian)

    Energy Technology Data Exchange (ETDEWEB)

    Nakata, Y.; Otsuka, M.; Ozawa, H.; Konosu, M. [Mitsui Engineering and Shipbuilding Co. Ltd., Tokyo (Japan)

    1997-08-01

    A compact and lightweight underwater RTV robot (RTV-SHIP) that enables the remote sensing in the double-shell structure of a tanker and the six-freedom motion control was developed based on the technology of the conventional portable underwater robot. The motion performance test in a water tank showed that the RTV-SHIP can freely access the manhole in the double-shell structure of a tanker and completely satisfies the thrust and swing force required for movement and measurement in a tank. The in-tank function confirmation test also shows that the main measurement items such as positioning in the tank, large deflection of panels, and plate thickness have a satisfactory measurement accuracy and that the RTV-SHIP has the same tone discrimination function as for a visual check. The method of inputting the tank shape during measurement and miniaturizing the recording unit should be improved until the RTV-SHIP is put to practical use. This system can be widely used by improving the above points according to the result of a future measurement test for the actual ships. 1 ref., 9 figs.

  4. Proposal and study of a long-span composite cable-stayed bridge with new hybrid girder; Atarashii gosei kozo shuketa wo mochiita chodai fukugo shachokyo no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Yoshida, K.; Hishiki, Y.; Furuichi, K. [Kajima Corp., Tokyo (Japan)

    1999-09-30

    A hybrid or mixed structure (composite structures) are a matter of increasing concern which takes in each advantage of steel and concrete. A field of bridges is no exception, with the plan and construction carried out for the new type of composite bridge, such as a composite cable-stayed bridge and a composite extra dose bridge as a long span bridge, and a composite truss bridge and a corrugated steel plate web bridge as a medium-span bridge, with technological development becoming active in this field. In such a technological trend, a hybrid two-girder structure was devised, a structure consisting of a concrete filled steel pipe for a girder and a precast (PC) floor plate for a floor board, as the girder structure of a long-span cable-stayed bridge in the subject research; also, applicability was examined using, as an example, the composite cable-stayed bridge with hybrid girders employed for the span. This paper reports the result of the analysis of the entire system, the analysis made for the purpose of examining the characteristic and the feasibility of this hybrid girder. The analysis revealed the structural feasibility of the long-span composite cable-stayed bridge using two hybrid girders of concrete-filled steel pipes thus devised. (NEDO)

  5. Development of newly engineering technology based on computer analysis for dust diffusion; Funjin kakusan kaiseki gijutsu wo kihon to shita atarashii engineering gijutsu no tenkai

    Energy Technology Data Exchange (ETDEWEB)

    Ishii, K.; Murahashi, Y.; Kawakami, H.; Tanaka, K. [Nippon Steel Corp., Tokyo (Japan)

    1997-07-30

    Nippon Steel has made a comprehensive survey of the space environment designing technology that can precisely cope with the needs required for a space in a plant in a very wide range from the ventilation problem in steel mill to the turbulence problem in semiconductor plant, through accomplishing the development of computer analysis technology for dust diffusion that can estimate and control `air flow` and `dust movement` in an electric angstrom [furnace plant]. This paper describes the basic concept for establishing the computer analysis technology for dust diffusion and the concrete measures to solve accompanying problems, and further enters into details how the new engineering technology has innovated technical measures to solve problems, the new engineering technology which introduces a concept of both estimation and control to attain objects such as to curtail the equipment cost and so by estimating the `air flow` and `dust movement` to create both a new flow and movement depending on needs. 3 refs., 20 figs., 8 tabs.

  6. Development of new type of nonlinear optical materials with a function of ultrafast optical modulation; Chokosoku hikari reiki hencho kino wo motsu atarashii hisenkei kogaku zairyo no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Sakaguchi, H. [Shizuoka University, Shizuoka (Japan). Research Institute of Electronics

    1995-12-15

    Ultrafast modulation of second harmonies from a Langmuir-Blodgett film consisting of a ruthenium complex was demonstrated for the first time. The mechanism of the modulator of SHG intensity on laser irradiation was ascribed to the change of molecular hyperpolarizability of the ruthenium complex on going from the ground state to the excited state. 9 refs., 12 figs.

  7. Development of new finite element by source method. 2nd Report. Plate bending element; Source wo mochiita atarashii yugen yoso no kaihatsu. 2. Itamage yoso

    Energy Technology Data Exchange (ETDEWEB)

    Neki, I.; Tada, T. [Ishikawajima-Harima Heavy Industries Co. Ltd., Tokyo (Japan)

    1996-12-31

    This paper reports a method to develop a new finite element by source (FES) for a two-dimensional plane problem and a three-dimensional solid problem as a method to analyze ship body structures. The paper describes development of a plate bending element by using a similar method, and the fundamental principle thereof. The present method can prepare a finite element of an arbitrary shape by simply providing a contact point only on a boundary. It can also derive good calculation accuracy with less number of contact points and elements. These facts are shown by examples of analyses on a square plate, a triangle plate and a semi-circular plate. Particularly, since a plate bending problem has a large order of differential calculus in a governing equation, this method being a semi-analytical method derives a result with very good accuracy even with less number of contact points. A hypothetical boundary method or a hypothetical electric charge method presents not a very high accuracy even if a large number of contact points are provided. This is because the method hypothesizes only a bending moment vertical to the boundary, but does not consider a source of the moment relative to the boundary. In contrast, the present method hypothesizes both of bending and twisting as the sources, hence its accuracy is better than with the above two methods. 5 refs., 11 figs., 7 tabs.

  8. Air pollution and allergy. ; Focusing on the relationship between nitrogen dioxide and bronchial asthma. Taiki osen to allergy. ; Tokuni nisanka chisso to kikanshi zensoku no kankei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kagawa, J. (Tokyo Women' s Medical College, Tokyo (Japan))

    1993-01-10

    Recently NO2 is drawing wide attention as a factor developing or worsening bronichial asthma. This paper describes the results of a study concerning this problem based on many survey data and statistics. There have been reported cases such as Tokyo-Yokohama asthma, Yokkaichi asthma, New Orleans asthma and a number of epidemiological investigations, but no sufficient clarification has not been given on the mechanism and the causal relation with respect to this problem. In animal experiments using NO2, naturally symptom-developing prompt type allergy is clearly recognized in dogs. Strong or weak infection resistance due to exposure to NO2 is confirmed in cavies. However, there is an example where the increase of disease rate is inversely correlated with the concentration of air pollutant and there are also some facts suggesting participation of factors other than air pollutant like ticks, mold and food. In order to obtain correct evaluation on the participation of NO2, it is indispensable to carry out investigations or experiments which can detect the effects due to NO2 by appropriately controlling these other factors. It can be said that there is small possibility of developing the symptom by being exposed to NO2 alone in the present level of atmospheric NO2 concentration. 68 refs., 1 fig., 4 tabs.

  9. International Workshop on Carbon Cycling and Coral Reef Metabolism; Sangosho no tanso junkan ni kansuru kokusai workshop hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-10-16

    The paper described the International Workshop on Carbon Cycling and Coral Reef Metabolism which was held at Miyako-jima, Okinawa Pref. on October 17-24, 1995. In the workshop, researchers got together which are involved in marine chemistry, marine biology, coral ecology, and environmental science, and discussed the carbon cycling and metabolism of coral reef. Discussions were made on what the coral reef ecosystem is, and what the definition of a sink or a source for CO2 is. Also discussed were scales of how much time and space should be considered to make these issues clear. Further, it was proposed that it was necessary to investigate carbon balance of both the whole system and the components of the system and to keep track of mass transfer among neighboring components of the system. Seventeen presentations were given. The workshop obtained a definite consensus on carbon balance of the coral reef system. 123 refs., 39 figs., 9 tabs.

  10. Toray Industries, Inc. : It is strengthened to europe and U.S. in carbon fiber; Tanso seni, oubei de zokyo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-31

    Toray Industries, Inc. plans the strengthening expansion of the compound material business. Toray Industries, Inc. proceeds with the maintenance of the position in the global scale as a world top manufacturer of PAN CF. 3 position is established by will start production in addition to Japan and Buddha in the United States in the next year. Though the production ability of Toray Industries, Inc. group is an annual production 7300 tons by the operation of the United States, 1 affiliation (1800 tons) establishment has already examined reinforcement with Buddha at the demand meeting with a view to marriage in the United States more. And, position building in the high Chinese market of the potential demand is given as an applicable area in the next increasing stage. And, performance improvement sport, industry use plans cost competition power strengthening by the proper use with large tough and so on in the aircraft multiple things field which should be made good as a new demand reclamation toward the market share rise. (translated by NEDO)

  11. Transformation hardening by linear-polarized laser beam. Report 2. Development of novel laser beam shaping optics and its applications to materials processing; Chokusen henko reza wo mochiiru hentai koka. 2. Atarashii reza shaping kogakukei no kaihatsu to sono oyo

    Energy Technology Data Exchange (ETDEWEB)

    Miyamoto, I.; Maruo, H. [Osaka Univ., Osaka (Japan)

    1994-08-05

    Shape variable laser beam shaping optics for which linear polarized beam is utilized is applied to the hardening of carbon steel by CO2 laser beam to analyze the absorptivity. In addition, linear polarized beam is irradiated to inclined materials for laser hardening to analyze the depth of hardening and the distribution of temperature. The absorptivity of random polarized beam by the bare specimens is as low as 20%. It is as high as above 40% with the graphite coated specimen, but is nearly constant with no dependence on the angle of incidence. The absorptivity in p-polarization increases with the increase in the angle of incidence. When linear polarized beam is used, the total efficiency of the bare specimen becomes high by about 1.5 times that of the graphite coated specimen subjected to random polarized beam. Hardening of bear material by laser beam is quite possible when p-polarization is employed. An approximation equation is derived with which the temperature distribution and hardened depth can be obtained easily if beam distribution and absorptivity are given, and it is applied to the evaluation of laser hardening of inclined specimens using linear polarized beam. 22 refs., 11 figs., 1 tab.

  12. Application of new analytical techniques to the order-disorder transformation in Ni-Mo alloys; Ni-Mo gokin no kisoku-fukisoku hentai ni okeru atarashii kozo kaiseki no kokoromi

    Energy Technology Data Exchange (ETDEWEB)

    Oki, K.; Hata, S.; Kuwano, N. [Kyushu University, Fukuoka (Japan)

    1997-09-20

    This paper presents the analytical example of the ordering process of order-disorder transformation in Ni-Mo alloy using recent experimental techniques. Monte Carlo simulation clarified the fact that the ordering process in Ni4-Mo alloy is largely affected by short range interaction in the early stage of ordering, and forms D1a, D022 and Pt2Mo structure units with a similar atomic pair correlation. The ordering process is largely affected by long range interaction with an advance of ordering, and develops only D1a structure most stable in energy. In order to check the existence of SRO (short range order) structure obtained by Monte Carlo simulation, the analysis of high-resolution TEM images under SRO condition was carried out using the imaging plate recently developed for TEM. The analytical result showed that the observed N2M3 pattern is derived from not always the existence of N2M3 structure but superimposition of D1a, D022 and Pt2Mo structure units. 19 refs., 4 figs.

  13. New ion generation method with SF{sub 6} plasma. Direct ionization of refractory materials; SF{sub 6} purazuma wo mochiita atarashii ion seiseiho. koyuten busshitsu wo chokusetsu ion ka

    Energy Technology Data Exchange (ETDEWEB)

    Okoshi, K.; Saito, Y.; Tajima, S. [Japan Atomic Energy Research Institute, Tokyo (Japan)

    1999-11-01

    For many refractory materials, vapor pressures rise due to fluoridation. For example, a vapor pressure of B is almost zero at room temperature, whereas a vapor pressure of BF{sub 3} is 10{sup 5}Pa or greater. A SF{sub 6} plasma method is capable of directly generating a solid fluoride in an ion source and obtaining its plasma. In order to ionize refractory materials such as niobium, boron, silicon and the like, the present authors have developed a new ion generation method using a stable solid sample and SF{sub 6} gas. Further, the present method was employed to successfully and greatly extending the filament life of the ion source. The plasma method can be used widely not only for a Freeman ion source but also for an ion source using plasma such as electron cyclotron resonance (ECR) ion source. Since the refractory material ions can be stably supplied at a great intensity for a long time, they are expected to be used in corrosion-resistant materials or materials having new functions such as optical switching materials. (NEDO)

  14. Construction of the curtain wall made of carbon fiber reinforced concrete. Sangenjaya Carrot Tower; Tanso sen`i hokyo konkurito wo mochiita katen uoru no seko - sangenjaya kyarotto tawa -

    Energy Technology Data Exchange (ETDEWEB)

    Hara, H.; Sasaki, M.; Honda, Y. [Tokyu Construction Co. Ltd., Tokyo (Japan)

    1997-08-01

    The characteristics of the carbon fiber reinforced concrete (CFRC) for the construction of the above-titled curtain walled tower, its full-size property test and the result of building work are reported. In the beginning, the composition of CFRC materials and their blending are described and the relationship between the mixing time with a mixer destined for that purpose and the mortar flow and the quality control on the CFRC control specimens are explained, followed by a description on the CFRC weight, water content, the use of stainless reinforcement bars to suppress corrosion, dry shrinkage, the relationship between bending strength and Young coefficient, durability, the bonding state obtained by traction test and so forth, together with an outline of the test result, It is also clarified that an ultimate strength taken in member design is assumed to be the one at the moment of bending crack at a high-wind occurring once during 150 years, and the safety is assured by the reinforcement of deformed stainless bars. Further, the working steps from the form construction to the fluorocarbon resin painting are indicated enumerating requirements for the curtain wall properties in terms of water-tightness, windresisting, aseismicity and so on. Lastly, some improvements made through the experiments and the state of construction work are noted. 5 refs., 14 figs., 4 tabs.

  15. Asymmetric carbon-carbon bond forming reactions catalyzed by chiral titanium complexes. Efficient synthesis of optically active secondary alcohols; Kiraru na chitan shokubai ni yoru fuseitanso-tanso ketsugo keisei. Kogaku kassei dainikyu arukoru no gosei

    Energy Technology Data Exchange (ETDEWEB)

    Hayashi, M. [Yamaguchi Univ., Yamaguchi (Japan). Faculty of Science

    1996-02-01

    For asymmetric metal complex catalysts with high catalytic activity and ability for recognizing asymmetry, it is most important to choose center metals and design asymmetric organic ligands. When the authors began to study on the title reactions, combination of titanium alkoxides as center metals and chiral Schiff bases as organic ligands was unknown, although two moieties had been used independently for asymmetric reactions with excellent results. Asymmetric silylcyanation of aldehydes and enantio-selective addition of diketone to aldehydes are introduced, that have been achieved by authors using titanium complexes of the above combination. In the silylcyanation, reactivity is remarkably improved, compared with a single catalyst of titanium isopropoxide. Cyanohydrin of R from was obtained preferentially with salicyladehyde, particularly having 3-tert butyl group, in an asymmetric yield of 85 % ee. In the latter addition reaction, 5-hydroxy-3-ketoesters were obtained from benzaldehyde in an asymmetric yield as high as 91 % ee. 9 refs., 2 figs.

  16. Synthesis of trimethoxy-type silane coupling agents containing two fluorocarbon chains and surface modification of glass; Fukka tanso kusari wo nisa yusuru torimetokishigata shiran coupling zai no gosei to glass no hyomen kaishitsu

    Energy Technology Data Exchange (ETDEWEB)

    Yoshino, N.; Itagaki, T. [Science University of Tokyo, Tokyo (Japan). Faculty of Engineering; Kondo, Y. [Science University of Tokyo, Tokyo (Japan). Institute of Colloid and Interface Sciences

    1997-08-20

    This paper reports synthesis of silane coupling agents (containing two fluorocarbon chains in one molecule) and modification of glass surface. The agents were synthesized by hydrosilylation of diester maleate, RfCH2CH2OCOCH = CHCOOCH2CH2Rf[Rf=CF3(CF)n, n=3, 5, 7 or (CF3)2CF(CF2)m, m=2, 4, 6, 8] using trimethoxy-type silane. The following matters were clarified on modification of glass surface for water repellency and oil repellency by using these silane coupling agents: the optimum treatment condition is heating at 200 degC for 60 minutes after the glass has been immersed in 10 mM aqueous solution of the agents/F-113 for 240 minutes; the modified glass has sufficiently high oxidation resistance if the fluorocarbon chain in molecules of the silane coupling agents is long; however, the glass may be hydrolyzed more easily because of having ester bond, whereas its acid resistance was shown low. 40 refs., 8 figs., 9 tabs.

  17. Design of environment-friendly and next generation-type conversion system for unused carbon resources by developing highly functional materials; Kokino zairyo kaihatsu ni yoru kankyo chowagata jisedai miriyo tanso shigen tenkan system no kochiku

    Energy Technology Data Exchange (ETDEWEB)

    Wakabayashi, K.; Morooka, S.; Arai, Y. [Kyushu University, Fukuoka (Japan). Faculty of Engineering; Sakanishi, K. [Kyushu University, Fukuoka (Japan). Institute of Advanced Material Study

    1997-02-01

    Studies are conducted for the development of now-unused kinds of fossil carbon resources, such as low rank coal and heavy gravity crude oil, into higher-value liquid fuel. In the preliminary treatment process, the fossil carbon resources are dried by use of supercritical carbon dioxide, when it is found that the resources are disintegrated and water is desorbed. In a low rank coal liquefaction process using the NiMo/KB (Kefjen Black) catalyst, more than 60% is converted into oil, which rate is improved by use of the dual-temperature liquefaction process. This catalyst may be recovered by separation utilizing specific gravity difference. As a low temperature gasification catalyst, the alkaline carbonate-carried carbon catalyst is very quick at the initial stage of reaction. The perovskite-carried alkaline carbonate catalyst is high in carbon oxidizing/activating efficiency at low temperatures. The silica film deposited on an alumina-coated support tube is excellent in selectivity and speed as a hydrogen separating film, and a carbonized polyimide film as a carbon dioxide separating film. For the supercritical phase adsorption/separation of chemicals not to be distilled easily, the NaY-type zeolite functions effectively. Pd/ZrO2 serving as a carbon monoxide conversion catalyst enables the recovery of more MeOH when Pd grains are smaller in diameter.

  18. Influences of species of metals and supports on the hydrogenation activity of carbon-supported metal sulfides catalysts; Tanso biryushi tanji shokubai no suisoka kassei ni taisuru kassei kinzoku oyobi tantaishu no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Sakanishi, K.; Hasuo, H.; Taniguchi, H.; Nagamatsu, T.; Mochida, I. [Kyushu University, Fukuoka (Japan). Institute of Advanced Material Study

    1996-10-28

    In order to design catalysts suitable for primary liquefaction stage and secondary upgrading stage respectively in the multi-stage liquefaction process, various carbon-supported catalysts were prepared. Catalytic activities of them were investigated for the hydrogenation of 1-methylnaphthalene, to discuss the influences of metals and carbon species on the catalytic activity. Various water soluble and oil soluble Mo and Ni salts were used for NiMo supported catalysts. Among various carbon supports, Ketjen Black (KB) was effective for preparing the catalyst showing the most excellent hydrogenation activity. The KB and Black Pearl 2000 (BP2000) showing high hydrogenation activity were fine particles having high specific surface area more than 1000 m{sup 2}/g and primary particle diameter around 30 nm. This was inferred to contribute to the high dispersion support of active metals. Since such fine particles of carbon exhibited hydrophobic surface, they were suitable for preparing catalysts from the methanol-soluble metals. Although Ni and Mo added iron-based catalysts provided lower aromatic hydrogenation activity, they exhibited liquefaction activity competing with the NiMo/KB catalyst. 3 refs., 1 fig., 3 tabs.

  19. Influence of carbon content on superplastic behaviour in Ti and B doped Cr-Mo steels; Ti, B tenka kuromu moribudenko no chososei ni oyobosu tanso gan`yuryo no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Aramaki, M.; Nakai, O.; Onodera, R.; Higashida, K. [Kyushu University, Fukuoka (Japan). Faculty of Engineering

    1997-12-01

    Superplasticity has been investigated in various ferrous alloys and steels. However, in these materials, especially in the hypoeutectoid steel bellow A1 temperature, the relationship between the content of carbon and elongation to failure is not obvious. In the present investigation, the influence of carbon content on superplastic behaviour is studied using carbon steels based on Cr-Mo steel. In order to obtain the fine grain structure, a small amount of Ti and B were added and the content of carbon was controlled to be in the range of 0.24% to 0.83%. The largest value of elongation to failure was 644% which was obtained by the tensile test of the specimen containing 0.58% carbon. The temperature and strain rate at which the maximum value was obtained were 710degC and 5 times 10{sup -4}s{sup -1}, respectively. Of all the specimens, this. specimen had the minimum grain size. Moreover, the area fraction of carbide took the maximum value at the temperature where the largest elongation value was obtained. These results show that the addition of carbon has an effect on grain refinement by formation of carbide, but excess amounts of carbons (>0.6%) bring about premature failure because of coarse microstructure and larger carbide. 17 refs., 9 figs., 1 tab.

  20. Report of the results of the fiscal 1997 regional consortium R and D project. Regional consortium field / Development of technology to treat aquatic environment by using microorganisms fixed on carbon fabrics (abbreviation: carbon/aquatic environment project) (first fiscal year); 1997 nendo chiiki consortium kenkyu kaihatsu jigyo. Chiiki consortium bun`ya / tanso sen`i nansoshiki eno biseibutsu kochaku gensho wo riyoshita mizukankyo seibi gijutsu no kaihatsu (ryakusho: tanso mizu kankyo project) daiichi nendo seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Out of the development of technology to arrange the aquatic environment using phenomena of microorganism fixation on carbon fiber soft textures, the paper stated the fiscal 1997 result. On carbon fibers in a state of swaying in water, microorganisms in water fix in an amazingly large quantity. A catalog was compiled of 58 kinds of carbon fabrics trially woven and knitted. When carbon fiber is used as activated sludge carrier, activity of microorganism lasts more than one year. Only a little amount of surplus sludge is generated. The fixed microorganisms are more active in case of carbon fiber than in case of nylon and polyester fibers. Fiber texture models of carbon fiber fixing activated sludge groups were proposed. By pump operation, the water flow inside/outside microorganism groups is being accelerated. Several new strains of bacillus carboniphilus were isolated/identified from soil and marsh. To grasp relationships of characteristics among three elements such as the state of aquatic environment, fiber, and microorganism group, the experiment was prepared. Preliminary work is conducted to derive a simple equation for facility design, and experimental directions to obtain design conditions were proposed. 6 refs., 166 figs., 47 tabs.

  1. Analytical study on aseismic base isolation in new offshore location. For practical location for thermal power plants by soft-landing artificial ground construction method; Atarashii kaijo ricchi ni okeru menshinsei ni kansuru kaisekiteki kento. Nanchaku jinko jiban koho ni yoru karyoku hatsuden setsubi ricchi jitsuyoka ni mukete

    Energy Technology Data Exchange (ETDEWEB)

    Kawamura, T.; Sakakibara, T. [Tokyo Electric Power Co. Inc., Tokyo (Japan); Ishikawa, M. [Nikken Sekkei Ltd., Osaka (Japan)

    1996-09-05

    Assuming offshore location of thermal power plants by soft-landing artificial ground construction method, its effect on uneven settlement of facility unit group and its seismic behavior were studied. In soft-landing artificial ground, the total weight and buoyancy of a caisson body with interior space are balanced by controlling water level in a tank to reduce landing pressure. Artificial ground resists lateral seismic external force by friction with submarine bedrock. Settlement analysis and seismic behavior analysis were conducted by 2-D FEM. As a result, bottom RC honeycomb structure was sufficient to resist uneven settlement during construction even under fixed junction condition between units. In soft-landing artificial ground, the maximum acceleration was reduced to nearly 70% by aseismic base isolation as compared with conventional methods. In addition, its sliding manner in earthquake was different from that of rigid bodies, and the maximum stress acceleration transmitted to the bottom of artificial ground changed even under the same waveform. 4 refs., 13 figs., 4 tabs.

  2. Investigation of the near-field structure of jet diffusion flame by the laser sheet method. 1st Report. New seeding method of scattering particles and its application; Laser sheet ho ni yoru funryu kakusan kaen no kibu kozo no kaimei. 1. Atarashii sanran ryushi tenkaho no teian to sono oyo

    Energy Technology Data Exchange (ETDEWEB)

    Noda, S.; Onodera, K.; Kamitakahara, Y.; Onuma, Y. [Toyohashi University of Technology, Aichi (Japan)

    1997-02-25

    The new seeding method of MgO scattering particles based on a laser sheet method was developed, and the near-field structure of jet diffusion flame was studied. This method adds MgO particles (0.2-1.0{mu}m in size) produced by oxidation reaction as scattering particles through combustion of a Mg ribbon in a passage. Since this seeding method of scattering particles can add extreme-densely particles, this method is applicable to not only laser sheet visualization but also laser Doppler velocimeter and concentration measurement. In non-combustion jet formed over a contraction nozzle, coherent vortices are formed in the near field within nearly 8000 in Reynolds number, and the coherent vortices enhance mixing of fuel and air in the process of their linear and nonlinear growth. In the case over 8000 in Reynolds number, the small-scale short-lifetime coherent vortices are formed in the initial development stage of mixed layers, and the whole jet is dominated by irregular turbulent mixing after collapse of the coherent vortices. 14 refs., 8 figs., 1 tab.

  3. Investigation of the creation of functional surfaces and the recent development in related researches. 2. Investigation of the development of new isolation/refining systems in water system; Kokino hyomen no sosei to shintenkai no kenkyu doko chosa. 2. Suikei ni okeru atarashii bunri seisei system no kaihatsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    Propositions were made concerning new chromatography and membrane separation techniques wherein a command control material is used, the mobile phase is fixed upon water, and the fixed phase is caused to vary by external commands, and how to develop the said techniques into a project was discussed. New methods were also introduced, capable of separating water systems and, particularly, capable of separating and refining, without damaging their functions, bionic elements such as proteins, genes, and cells, which encouraged discussion on the future of the said project. As for command controlled materials, detailed investigations were conducted into materials responsive to physical stimulation such as light, electric field, magnetic field, or heat and materials responsive to PH and chemical or biochemical substances, and discussion was made on the structures and characters of the said materials. Concerning the manufacture of a command controlled surface, consideration centered particularly about the density and thickness of command controlled molecules to be introduced onto the surface. Furthermore, the current state and problems were discussed regarding chromatographic separation and refining of optical isomers, nucleic acids, physiologically active substances, peptides, cells, etc. 252 refs., 75 figs., 31 tabs.

  4. 43rd annual meeting of the Society of Coal Mining Engineers. Part 3. Coalbed methane activity in the U.S.A.; 1994 nendo (dai 43 kai) zenkoku tanko gijutsukai taikai koenshu. 3. Amerika no tanso gas kaihatsu genkyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Tamari, A. [Coal Mining Research Center, Tokyo (Japan)

    1994-09-20

    Hitherto, the coalbed methane gas gushing out accompanied by the coal mining is only emphasized as the obstacle on the viewpoint of safety of colliery in disregard of the fact that a part thereof has been gathered and used for a long time. However, in the overseas coal producing countries having rich coal resources, the evaluation on said coalbed methane as the clean and new energy has been raised in these years, and also from the stand of decreasing the release of methane which is one of the main reasons causing the warming of the earth the researches and the technical development are carried out for the active reclamation thereof. Especially, the coalbed methane activity in the United States shows a rapid growth as the important supplying resource of clean energy shouldering a general part of the natural gas resource in the future. In this paper, simultaneously with the description of the resource and production of coalbed methane the United States, the practical status of San Juan Basin and Black Warrior Basin as the representative coalfield is described. At last, the ventilation technique of coalbed methane in Jim Walter Resources Company are introduced. 3 refs., 12 figs., 1 tab.

  5. International seminar in fiscal 1998 on the development and promotion of global environment-related industrial technologies. Report on International Workshops on CO{sub 2} Cycling and Metabolism in Coral Reef; 1998 nendo chikyu sangyo gijutsu kaihatsu suishin jigyo. 'Sangosho ni okeru busshitsu ido to tanso junkan' kokusai workshop hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    For the study of CO{sub 2} absorption and fixation in the marine ecosystem, studies of coral reefs by RITE (Research Institute of Innovative Technology for the Earth) were subjected to discussion at the above-named workshops. It is after the elapse of a long geological time on the earth that CO2 in the atmosphere has arrived at the current level of concentration thanks to fixation and calcification by living organisms and to dissolution into the seawater. In the formation of CaCO{sub 3} that constitutes the coral skeleton, 1 mol Ca combines with 2 mol bicarbonates for the production of 1 mol CaCO{sub 3} and 1 mol CO{sub 2}. The reaction may suggests a consequential increase of CO2 in the atmosphere but such CO{sub 2} is in reality consumed by being converted into organic substances in a photosynthetic process performed by symbiotic algae. Calculation was made for the whole of Bora Bay, Miyakojima Island, and the result was that 700kg-C/day comes to be stored in the form of organic matters in the community of coral reef organisms. In a coral reef, even when it emits CO2 into the atmosphere, there is organic matter production which exceeds the lost CO{sub 2}. Coral reefs fix carbon out of the seawater at the rate of 0.42Gt-C/year, which is the aggregate of 0.3Gt organic matters and 0.12Gt CaCO{sub 3}. (NEDO)

  6. Design and qualification of the interferometer for the GOSAT-2 spectrometer

    Science.gov (United States)

    Montembault, Yan; Moreau, Louis; Roux, Michel; Buijs, Henry; Soucy, Marc-André

    2016-10-01

    GOSAT-2 is the successor of the Greenhouse gases Observing SATellite (GOSAT, "IBUKI") launched in 2009 by Japan Aerospace Exploration Agency (JAXA). GOSAT-2 will continue and enhance space borne measurements of greenhouse gases started by GOSAT and monitor the impacts of climate change and human activities on the carbon cycle. It will also contribute to climate science and climate change related policies. The GOSAT-2 spacecraft will carry two earth observation instruments: FTS-2, the second generation of the TANSO-FTS and CAI-2, a Cloud and Aerosol Imager. Mitsubishi Electric Corporation is the prime contractor of GOSAT-2. Harris is the subcontractor of the spectrometer. ABB, who successfully designed, manufactured, and delivered the interferometer for the TANSO-FTS instrument for GOSAT, is currently delivering the modulator for the FTS-2 instrument to Mitsubishi Electric Corporation. Built on the TANSO-FTS heritage, FTS-2 is a thermal and near infrared sensor for carbon observation based on a Fourier transform spectrometer featuring larger optical throughput than TANSO-FTS. This paper presents an overview of the design of the FTS-2 interferometer as well as key qualification and performance verification activities conducted on the interferometer flight model.

  7. Inverse modelling of CH4 emissions for 2010-2011 using different satellite retrieval products from GOSAT and SCIAMACHY

    NARCIS (Netherlands)

    Alexe, M.; Bergamaschi, P.; Segers, A.; Detmers, R.; Butz, A.; Hasekamp, O.; Guerlet, S.; Parker, R.; Boesch, H.; Frankenberg, C.; Scheepmaker, R.A.; Dlugokencky, E.; Sweeney, C.; Wofsy, S.C.; Kort, E.A.

    2015-01-01

    At the beginning of 2009 new space-borne observations of dry-air column-averaged mole fractions of atmospheric methane (XCH4) became available from the Thermal And Near infrared Sensor for carbon Observations-Fourier Transform Spectrometer (TANSO-FTS) instrument on board the Greenhouse Gases Observi

  8. Effect of massive transformation on formation of acicular structure in austenitic stainless steel weld metal solidified as ferritic single phase. Report 5. Study on solidification and subsequent transformation of Cr-Ni stainless steel weld metals; Feraito tanso de gyokosuru osutenaito kei sutenresu ko yosetsu kinzoku ni okeru ashikyura jo soshiki no keisei ni oyobosu masshibu hentai no eikyo.5. Cr-Ni kei sutenresu ko yosetsu kinzoku no gyoko/hentai ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, H.; Koseki, T.; Okita, S.; Fuji, M. [Nippon Steel Corp., Tokyo (Japan)

    1997-05-05

    The authors clarified that massive transformation occurs at two phase region under To temperature and there is K-S relation between the massive formation phase and base phase using {gamma} stainless steel that solidifies at F mode and forms acicular structure at room temperature structure. There is a possibility of massive transformation in weld metals because the cooling rate below the high temperature To was high even for normal welding process. Thereupon, in this report, whether the massive transformation effects the formation of acicular structure or not was studied as for {gamma} stainless steel weld metal that solidifies at F mode and room temperature structure becomes acicular form of two {delta} and {gamma} phase. As a result, it was clarified that massive transformation occurs at two phase region with temperature below To, and the room temperature structure was acicular form structure irrespective to massive transformation in case of composition with small Cr/Ni ratio even in case of stainless steel that solidifies at F mode. 20 refs., 15 figs., 1 tab.

  9. Solidification and transformation behavior of Cr-Ni stainless steel weld metals with ferritic single phase solidification mode. Report 4. Study on solidification and subsequent transformation of Cr-Ni stainless steel weld metals; Feraito tanso de gyokosuru Cr-Ni kei sutenresu ko yosetsu kinzoku no gyoko/hendo kyodo. 4. Cr-Ni kei sutenresu ko yosetsu kinzoku no gyoko/hentai ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, H.; Koseki, T.; Okita, S.; Fuji, M. [Nippon Steel Corp., Tokyo (Japan)

    1997-05-05

    The solidification modes of {gamma} stainless steel that solidifies at initial crystal {delta} are classified into FA mode where solidification at two phase of {delta}+{gamma} takes place after crystallization at {gamma} phase during solidification and F mode where solidification is completed at {delta} single phase, and solidification transformation behaviors of weld metal of FA mode are reported in the previous paper. Hereupon, in this report, solidification and transformation behaviors of stainless steel weld metal of F mode are studied. Cr-Ni stainless steel of F mode consists of two phase stainless steel with two phase base metal structure of {delta}+{gamma} besides {gamma} stainless steel. Further, two phase stainless steel with higher alloy compared to conventional one has been developed. In this report, not only the {gamma} stainless steel but also two phase stainless weld metals with varied amount of alloying metal are studied. The welding method and welding conditions are same as that of previous paper. Observation of structure was carried out by optical microscope, and crystal orientation and element distribution were measured by EBSP and CMA respectively. 11 refs., 18 figs., 1 tab.

  10. The results of the critical design of the mission instruments of GOSAT-2

    Science.gov (United States)

    Yajima, Yukie; Suto, Hiroshi; Yotsumoto, Kazuhiko; Miyakawa, Takehiro; Hashimoto, Makiko; Shiomi, Kei; Nakajima, Masakatsu; Hirabayashi, Takeshi

    2016-04-01

    The GOSAT-2 is the successor satellite to the GOSAT which is the satellite dedicated to the measurements of the greenhouse gases such as carbon dioxide and methane. GOSAT was launched in January of 2009 and has been operated for about seven years. The development of the GOSAT-2 has been continued for two years, and through the preliminary and critical design phase the detail of the design of the mission instruments were fixed as well as the bus system design. The mission instruments of the GOSAT-2 are TANSO-FTS-2 and TANSO-CAI-2. TANSO-FTS-2 is the Fourier Transform Spectrometer observing greenhouse gases such as Carbon Dioxide and Methane and TANSO-CAI-2 is the imager observing the aerosols and clouds to compensate the TANSO-FTS-2 data and to grasp the movements of the aerosols such as PM2.5. The mission instruments will adopt the same kinds of instruments as GOSAT. But some improvements will be carried. Based on the results of the preliminary design, the design had been refined in the critical design phase and the results of the design meets all of the requirements on the mission instruments derived from the mission requirements to understand CO2 and CH4 sources and sinks and carbon cycle precisely. To improve the measurement accuracy, the signal to noise ratio will be increased by the extension of the aperture size from 64mm to 73mm and cooling the after optics as well as the thermal detectors. And to increase the number of the useful data, GOSAT-2 will equip the function to avoid the clouds during the observation using the images obtained by the monitor camera in FTS. To observe the carbon monoxide, the 2.3μm observation channel will be added. This function will be realized by the extension of the 2.0μm observation band to 2.3μm. The pointing angle in the along track direction will be extend from 20 degrees of GOSAT to 40 degrees to expand the observation area over the ocean where the sun glint is observed. This will make it possible to increase the number

  11. The Greenhouse Gas Climate Change Initiative (GHG-CCI): comparison and quality assessment of near-surface-sensitive satellite-derived CO2 and CH4 global data sets

    Science.gov (United States)

    Buchwitz, Michael

    2013-04-01

    The GHG-CCI project is one of several projects of the European Space Agency's (ESA) Climate Change Initiative (CCI). The goal of the CCI is to generate and deliver data sets of various satellite-derived Essential Climate Variables (ECVs) in line with GCOS (Global Climate Observing System) requirements. The "ECV Greenhouse Gases" (ECV GHG) is the global distribution of important climate relevant gases - atmospheric CO2 and CH4 - with a quality sufficient to obtain information on regional CO2 and CH4 sources and sinks. Two satellite instruments deliver the main input data for GHG-CCI: SCIAMACHY/ENVISAT and TANSO-FTS/GOSAT. The first order priority goal of GHG-CCI is the further development of retrieval algorithms for near-surface-sensitive column-averaged dry air mole fractions of CO2 and CH4, denoted XCO2 and XCH4, to meet the demanding user requirements. GHG-CCI focusses on four core data products: XCO2 from SCIAMACHY and TANSO and XCH4 from the same two sensors. For each of the four core data products at least two candidate retrieval algorithms have been independently further developed and the corresponding data products have been quality assessed and inter-compared. This activity is referred to as "Round Robin" (RR) activity within the CCI. The main goal of the RR was to identify for each of the four core products which algorithm to be used to generate the Climate Research Data Package (CRDP), which will essentially be the first version of the ECV GHG. This manuscript gives an overview about the GHG-CCI RR and related activities. This comprises the establishment of the user requirements, the improvement of the candidate retrieval algorithms and comparisons with ground-based observations and models. The manuscript summarizes the final RR algorithm selection decision and its justification. Comparison with ground-based Total Carbon Column Observing Network (TCCON) data indicates that the "breakthrough" single measurement precision requirement has been met for

  12. The total column of CO2 and CH4 measured with a compact Fourier transform spectrometer at NASA Armstrong Flight Research Center and Railroad Valley, Nevada, USA

    Science.gov (United States)

    Kawakami, S.; Shiomi, K.; Suto, H.; Kuze, A.; Hillyard, P. W.; Tanaka, T.; Podolske, J. R.; Iraci, L. T.; Albertson, R. T.

    2014-12-01

    The total columns of carbon dioxide (XCO2) and methane (XCH4) were measured with a compact Fourier transform spectrometer (FTS) at NASA Armstrong Flight Research Center (AFRC) and Railroad Valley, Nevada, USA (RRV) during a vicarious calibration campaign in June 2014. The campaign was performed to estimate changes in the radiometric response of the Thermal and Near Infrared Sensor for carbon Observations Fourier Transform Spectrometer (TANSO-FTS) and the Cloud and Aerosol Imager (TANSO-CAI) aboard Greenhouse gases Observing SATellite (GOSAT). TANSO-FTS measures spectra of radiance scattered by the Earth surface with high- and medium-gain depending on the surface reflectance. At high reflectance areas, such as deserts over north Africa and Australia, TANSO-FTS collects spectra with medium-gain. There was differences on atmospheric pressure and XCO2 retrieved from spectra obtained between high-gain and medium-gain. Because the retrieved products are useful for evaluating the difference of spectral qualities between high- and medium-gain, this work is an attempt to collect validation data for spectra with medium-gain of TANSO-FTS at remote and desert area with a compact and medium-spectral resolution instrument. As a compact FTS, EM27/SUN was used. It was manufactured and newly released on April 1, 2014 by Bruker. It is robust and operable in a high temperature environment. It was housed in a steel box to protect from dust and rain and powered by Solar panels. It can be operated by such a remote and desert area, like a RRV. Over AFRC and RRV, vertical profiles of CO2 and CH4 were measured using the Alpha Jet research aircraft as part of the Alpha Jet Atmospheric eXperiment (AJAX) of ARC, NASA. The values were calibrated to standard gases. To make the results comparable to WMO (World Meteorological Organization) standards, the retrieved XCO2 and XCH4 values are divided by a calibration factor. This values were determined by comparisons with in situ profiles measured by

  13. Comparison of XH2O Retrieved from GOSAT Short-Wavelength Infrared Spectra with Observations from the TCCON Network

    Directory of Open Access Journals (Sweden)

    Eric Dupuy

    2016-05-01

    Full Text Available Understanding the atmospheric distribution of water (H 2 O is crucial for global warming studies and climate change mitigation. In this context, reliable satellite data are extremely valuable for their global and continuous coverage, once their quality has been assessed. Short-wavelength infrared spectra are acquired by the Thermal And Near-infrared Sensor for carbon Observation-Fourier Transform Spectrometer (TANSO-FTS aboard the Greenhouse gases Observing Satellite (GOSAT. From these, column-averaged dry-air mole fractions of carbon dioxide, methane and water vapor (XH 2 O have been retrieved at the National Institute for Environmental Studies (NIES, Japan and are available as a Level 2 research product. We compare the NIES XH 2 O data, Version 02.21, with retrievals from the ground-based Total Carbon Column Observing Network (TCCON, Version GGG2014. The datasets are in good overall agreement, with GOSAT data showing a slight global low bias of −3.1% ± 24.0%, good consistency over different locations (station bias of −1.53% ± 10.35% and reasonable correlation with TCCON (R = 0.89. We identified two potential sources of discrepancy between the NIES and TCCON retrievals over land. While the TCCON XH 2 O amounts can reach 6000–7000 ppm when the atmospheric water content is high, the correlated NIES values do not exceed 5500 ppm. This could be due to a dry bias of TANSO-FTS in situations of high humidity and aerosol content. We also determined that the GOSAT-TCCON differences directly depend on the altitude difference between the TANSO-FTS footprint and the TCCON site. Further analysis will account for these biases, but the NIES V02.21 XH 2 O product, after public release, can already be useful for water cycle studies.

  14. Global and regional methane budget and its inter-annual variability

    Science.gov (United States)

    Bourakkadi, Zakia; Payan, Sébastien; Locatelli, Robin; Chevallier, Frederic; Saunois, Marielle; Bousquet, Philippe

    2016-04-01

    Methane global concentration has more than doubled since the pre-industrial times. This increase is generally caused by the anthropogenic activities like the massive use and extraction of fossil fuel, rice paddies agriculture and emissions from landfills. Space observations are very useful to monitor and quantify methane concentration in the atmosphere, in order to improve our knowledge of its sources, sinks, transport and trends. Since 2002 global methane total-columns mixing ratois from the SCanning Imaging Absorption spectroMeter for Atmospheric ChartographY (SCIAMACHY) on board ENVISAT was the first space-borne sensitive to methane in the boundary layer. However the communication with the instrument was lost in April 2012. Since January 2009 methane columns retrievals have been available also from the Thermal And Near Infrared Sensor for carbon Observations-Fourier Transform Spectrometer (TANSO-FTS), on-board the GOSAT satellite. In this study, we used measurements in the short wave infrared radiation (SWIR) from TANSO-FTS covering 5 years, from January 2010 to December 2014 to estimate global methane fluxes by inverse modeling, using the PYVAR-LMDZ model. We present here the results of global and regional methane budget, and its inter-annual variability during this period.

  15. Optimization of the GOSAT global observation from space with region-by-region target-mode operations

    Science.gov (United States)

    kuze, A.; Suto, H.; Shiomi, K.; Kawakami, S.; Nakajima, M.

    2013-12-01

    Since its launch in 2009, the Thermal And Near infrared Sensor for carbon Observation Fourier-Transform Spectrometer (TANSO-FTS) onboard the Greenhouse gases Observing SATellite (GOSAT) has continued its grid observation and acquired about 20,000 samples per day. Now that more than 10 programs are planned or proposed to monitor greenhouse gases from space. TANSO-FTS is the only instrument that uses a Fourier transfer spectrometer. It is not an imaging spectrometer but has a symmetrical instrument line shape function (ILSF) that can be expressed to high precision for all wavelengths with a simple analytical function and can reduce fitting errors for atmosphere remote sensing. Therefore, other future instruments can cross-calibrate their data with accurate and precise GOSAT spectra. Since August 2010, TANSO-FTS has selected 3-point cross-track scan mode, which has the current best pointing stability and observes a single point three times in 14 sec. Column-averaged dry air mole fractions of CO2 (XCO2) and CH4 (XCH4) have been well validated at the TCCON sites, where surface albedo is not high and aerosol optical thickness is small. Long term GOSAT data show seasonal and latitudinal variation and annual increase accurately and precisely. JAXA has been processing and providing all the Level 1B spectra data that were acquired on-orbit. Thus the distribution of the Level 1B is spatially equal. The Level 2 users are retrieving XCO2 and XCH4 from the Level 1 by filtering cloud contaminated, aerosol thick, and low signal-to-noise ratio scenes. As a result, the yield rate at cloudy area such as Amazon, south-east Asia, and Central America, low surface albedo area such as snow and ice, bay and channels is very low. Aerosol thick area such as Sahara also has larger errors. Now that GOSAT demonstrated accurate XCO2 and XCH4 remote sensing, demand for emission source measurements of mega cities, power plants, gas fields, and volcanos has increased. In addition to grid

  16. GOSAT TIR radiometric validation toward simultaneous GHG column and profile observation

    Science.gov (United States)

    Kataoka, F.; Knuteson, R. O.; Kuze, A.; Shiomi, K.; Suto, H.; Saitoh, N.

    2015-12-01

    The Greenhouse gases Observing SATellite (GOSAT) was launched on January 2009 and continues its operation for more than six years. The thermal and near infrared sensor for carbon observation Fourier-Transform Spectrometer (TANSO-FTS) onboard GOSAT measures greenhouse gases (GHG), such as CO2 and CH4, with wide and high resolution spectra from shortwave infrared (SWIR) to thermal infrared (TIR). This instrument has the advantage of being able to measure simultaneously the same field of view in different spectral ranges. The combination of column-GHG form SWIR band and vertical profile-GHG from TIR band provide better understanding and distribution of GHG, especially in troposphere. This work describes the radiometric validation and sensitivity analysis of TANSO-FTS TIR spectra, especially CO2, atmospheric window and CH4 channels with forward calculation. In this evaluation, we used accurate in-situ dataset of the HIPPO (HIAPER Pole-to-Pole Observation) airplane observation data and GOSAT vicarious calibration and validation campaign data in Railroad Valley, NV. The HIPPO aircraft campaign had taken accurate atmospheric vertical profile dataset (T, RH, O3, CO2, CH4, N2O, CO) approximately pole-to-pole from the surface to the tropopause over the ocean. We implemented these dataset for forward calculation and made the spectral correction model with respect to wavenumber and internal calibration blackbody temperature The GOSAT vicarious calibration campaign have conducted every year since 2009 near summer solstice in Railroad Valley, where high-temperature desert site. In this campaign, we have measured temperature and humidity by a radiosonde and CO2, CH4 and O3 profile by the AJAX airplane at the time of the GOSAT overpass. Sometimes, the GHG profiles over the Railroad Valley show the air mass advection in mid-troposphere depending on upper wind. These advections bring the different concentration of GHG in lower and upper troposphere. Using these cases, we made

  17. Characterization and correction of spectral distortions induced by microvibrations onboard the GOSAT Fourier transform spectrometer.

    Science.gov (United States)

    Suto, Hiroshi; Yoshida, Jun; Desbiens, Raphael; Kawashima, Takahiro; Kuze, Akihiko

    2013-07-10

    Microvibrations onboard greenhouse gases observing satellite (GOSAT) cause scan speed variations in the TANSO Fourier transform spectrometer. The associated periodic sampling errors generate ghost features in O2 A-band spectra, where surface pressure and aerosol properties are retrieved to determine the optical path through the atmosphere. A correction algorithm has been developed to re-compute the interferograms at equally spaced sampling intervals. The key is to determine iteratively the amplitude and phase of sinusoidal perturbations with predetermined frequencies to minimize the magnitude of the out-of-band ghosts artifacts after correction of the sampling grid. This correction algorithm drastically reduces errors in retrieved surface pressure and improves agreement with ground-based observations.

  18. A General Introduction to Greenhouse Gases Observing Satellite (GOSAT) and Its Products%温室气体观测卫星GOSAT及产品

    Institute of Scientific and Technical Information of China (English)

    侯姗姗; 雷莉萍; 关贤华

    2013-01-01

    为了深入了解国际上新一代温室气体观测卫星及其产品,详细介绍了GOSAT卫星发射背景、卫星平台、传感器设置、地面系统及数据产品特点.GOSAT卫星采用干涉分光技术,结合多种观测方式,可以获得高精度、高时空分辨率的温室气体浓度及廓线资料,其卫星设计及数据应用思路,为我国发展温室气体探测卫星提供了重要参考价值.%Remote sensing plays an important role in monitoring greenhouse gases emissions and the source and sink of greenhouse gases at regional and global scales. GOSAT (Greenhouse gases Observing SATellite) is the first satellite for space borne measurement of the main greenhouse gases CO2 and CH4. An Introduction is made about the emission background, satellite platform, instrument characteristics, and the ground systems of GOSAT,in order to thoroughly understand the advances of satellite greenhouse gases observation in the world. This paper also presents an overview of GOS-AT data products,calibration and validation strategies. Thermal And Near infrared Sensor for carbon Observation Fourier-Transform Spectrometer (TANSO-FTS) is based on the Michelson interferometer, and combine with several observation modes which provides atmospheric greenhouse gases concentration and profile data with high precision. While TANSO-CAI (Cloud and Aerosol Imager) is a radiometer with Ultra Violet (UV), visible, and short wave infrared (SWIR) bands to reduce the interference of cloud and aerosol on greenhouse gases measurements. The satellite design and data applications of GOSAT provide important references for developing greenhouse gas monitor satellites in China.

  19. Progress of Validation of GOSAT Standard Products

    Science.gov (United States)

    Uchino, Osamu

    2010-05-01

    Isamu Morino, Tomoaki Tanaka, Yuki Miyamoto, Yukio Yoshida, Tatsuya Yokota, Toshinobu Machida National Institute for Environmental Studies, Tsukuba, Ibaraki, Japan Debra Wunch, Paul Wennberg Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California, USA Geoffrey Toon Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USA Thorsten Warneke, Justus Notholt Institute of Environmental Physics, University of Bremen, Bremen, Germany David Griffith, Nicholas Deutscher Department of Chemistry, University of Wollongong, Wollongong New South Wales, Australia Vanessa Sherlock National Institute of Water and Atmospheric Research, Lauder, Central Otago, New Zealand Hidekazu Matsueda, Yousuke Sawa Meteorological Research Institute, 1-1 Nagamine, Tsukuba, Ibaraki 305-0052, Japan Colm Sweeney, Pieter Tans Earth System Research Laboratory, NOAA, Boulder, USA The Greenhouse gases Observing SATellite (GOSAT), launched on 23 January 2009, is the world's first satellite dedicated to measuring the concentrations of the two major greenhouse gases, carbon dioxide (CO2) and methane (CH4), from space. The data measured with the Thermal And Near-infrared Sensor for carbon Observation Fourier Transform Spectrometer (TANSO-FTS) and the Cloud and Aerosol Imager (TANSO-CAI) are processed into several types of data products. Column abundances of CO2 and CH4 (TANSO-FTS SWIR L2 data product) are retrieved from the FTS L1B spectral data. Validation of the FTS Level 2 data product is critical since the data is used for generating the FTS Level 3 (global distributions of column-averaged mixing ratio data of XCO2 and XCH4) and the FTS Level 4 (regional CO2 fluxes and three dimensional distribution of CO2 calculated from the estimated fluxes) products. The reference data to be used for validating abundances are required to have uncertainties of less than 1.0 % (0.3 % or 1 ppm is desirable) for CO2 and 2.0 % for CH4. Ground

  20. Retrieval algorithm for CO2 and CH4 column abundances from short-wavelength infrared spectral observations by the Greenhouse gases observing satellite

    Directory of Open Access Journals (Sweden)

    I. Morino

    2011-04-01

    Full Text Available The Greenhouse gases Observing SATellite (GOSAT was launched on 23 January 2009 to monitor the global distributions of carbon dioxide and methane from space. It has operated continuously since then. Here, we describe a retrieval algorithm for column abundances of these gases from the short-wavelength infrared spectra obtained by the Thermal And Near infrared Sensor for carbon Observation-Fourier Transform Spectrometer (TANSO-FTS. The algorithm consists of three steps. First, cloud-free observational scenes are selected by several cloud-detection methods. Then, column abundances of carbon dioxide and methane are retrieved based on the optimal estimation method. Finally, the retrieval quality is examined to exclude low-quality and/or aerosol-contaminated results. Most of the retrieval random errors come from instrumental noise. The interferences due to auxiliary parameters retrieved simultaneously with gas abundances are small. The evaluated precisions of the retrieved column abundances for single observations are less than 1% in most cases. The interhemispherical differences and temporal variation patterns of the retrieved column abundances show features similar to those of an atmospheric transport model.

  1. The GHG-CCI Project of ESA's Climate Change Initiative: Data Products and Applications

    Science.gov (United States)

    Buchwitz, M.; Reuter, M.; Schneising, O.; Boesch, H.; Aben, I.; Alexe, M.; Bergamaschi, P.; Bovensmann, H.; Brunner, D.; Buchmann, B.; Burrows, J. P.; Butz, A.; Chevallier, F.; Crevoisier, C. D.; De Maziere, M.; De Wachter, E.; Detmers, R.; Dils, B.; Feng, L.; Frankenberg, C.; Hasekamp, O. P.; Hewson, W.; Heymann, J.; Houweling, S.; Kaminski, T.; Laeng, A.; Leeuwen, T. T. v.; Lichtenberg, G.; Marshall, J.; Noel, S.; Notholt, J.; Palmer, P. I.; Parker, R.; Sundstrom, A.-M.; Scholze, M.; Stiller, G.; Warneke, T.; Zehner, C.

    2016-08-01

    The goal of the GHG-CCI project (http://www.esa-ghg- cci.org/) of ESA's Climate Change Initiative (CCI) is to generate global atmospheric satellite-derived carbon dioxide (CO2) and methane (CH4) data sets as needed to improve our understanding of the regional sources and sinks of these important greenhouse gases (GHG). Here we present an overview about the latest data set called Climate Research Data Package No. 3 (CRDP3). We focus on the GHG-CCI project core data products, which are near-surface-sensitive column-averaged dry air mole fractions of CO2 and CH4, denoted XCO2 (in ppm) and XCH4 (in ppb) retrieved from SCIAMACHY/ENVISAT (2002-2012) and TANSO-FTS/GOSAT (2009-today) nadir mode radiance observations in the near- infrared/shortwave-infrared spectral region. The GHG- CCI products are primarily individual sensor Level 2 products. However, we also generate merged Level 2 products ("EMMA products"). Here we also present a first GHG-CCI Level 3 product, namely XCO2 and XCH4 in Obs4MIPs format (monthly, 5°x5°).

  2. Influence of aerosols and thin cirrus clouds on the GOSAT-observed CO2: a case study over Tsukuba

    Directory of Open Access Journals (Sweden)

    A. Bril

    2011-11-01

    Full Text Available Lidar observations of vertical profiles of aerosols and thin cirrus clouds were made at Tsukuba (36.1° N, 140.1° E, Japan, to investigate the influence of aerosols and thin cirrus clouds on the column-averaged dry-air mole fraction of carbon dioxide (XCO2 retrieved from observation data of the Thermal And Near-infrared Sensor for carbon Observation Fourier Transform Spectrometer, measured in the Short-Wavelength InfraRed band (TANSO-FTS SWIR, onboard the Greenhouse gases Observing SATellite (GOSAT. The lidar system measured the backscattering ratio, depolarization ratio, and/or the wavelength exponent of atmospheric particles. The lidar observations and ground-based high-resolution FTS measurements at the Tsukuba Total Carbon Column Observing Network (Tsukuba TCCON site were recorded simultaneously during passages of GOSAT over Tsukuba. GOSAT SWIR XCO2 data (version 01.xx released in August 2010 were compared with the lidar and Tsukuba TCCON data. High-altitude aerosols and thin cirrus clouds had a large impact on the GOSAT SWIR XCO2 results. By taking into account the observed aerosol/cirrus vertical profiles and using a more adequate solar irradiance database in the GOSAT SWIR retrieval, the difference between the GOSAT SWIR XCO2 data and the Tsukuba TCCON data was greatly reduced.

  3. Long-term analysis of carbon dioxide and methane column-averaged mole fractions retrieved from SCIAMACHY

    Science.gov (United States)

    Schneising, Oliver; Buchwitz, Michael; Reuter, Maximilian; Heymann, Jens; Bovensmann, Heinrich; Burrows, John P.

    2010-05-01

    Carbon dioxide (CO2) and methane (CH4) are the two most important anthropogenic greenhouse gases contributing to climate change. Despite their importance our knowledge about their variable natural and anthropogenic sources and sinks has significant gaps. Satellite observations can add important global scale information on greenhouse gas sources and sinks provided the data are accurate and precise enough and are sensitive to the lowest atmospheric layers where the variability is largest. High sensitivity to near-surface greenhouse gas concentration changes can be achieved using reflected solar radiation in the near-infrared/shortwave-infrared (NIR/SWIR) spectral region. SCIAMACHY onboard ENVISAT (launch 2002) was the first and is now besides TANSO onboard GOSAT (launch 2009) the only satellite instrument currently in space covering important absorption bands of both gases in this spectral range. Global SCIAMACHY nadir observations from the time period 2003-2009 have been used to retrieve carbon dioxide and methane column-averaged mole fractions (which are the quantities needed for inverse modelling to get information on the sources and sinks) constituting seven years of greenhouse gas information derived from European EO data and offering temporal overlap with GOSAT. These new improved WFM-DOAS multi-year global data sets extending afore existing retrievals will be presented and discussed including an analysis of the long-term characteristics and comparison of the retrieved mole fractions with independent data, e.g., a first analysis of how the SCIAMACHY results compare with GOSAT retrievals for the overlapping time period.

  4. Retrieval algorithm for CO2 and CH4 column abundances from short-wavelength infrared spectral observations by the Greenhouse Gases Observing Satellite

    Directory of Open Access Journals (Sweden)

    I. Morino

    2010-11-01

    Full Text Available The Greenhouse gases Observing SATellite (GOSAT was launched on 23 January 2009 to monitor the global distributions of carbon dioxide and methane from space. It has operated continuously since then. Here we describe a retrieval algorithm for column abundances of these gases from the short-wavelength infrared spectra obtained by the Thermal And Near infrared Sensor for carbon Observation-Fourier Transform Spectrometer (TANSO-FTS. The algorithm consists of three steps. First, cloud-free observational scenes are selected by several cloud-detection methods. Then, column abundances of carbon dioxide and methane are retrieved based on the optimal estimation method. Finally, the retrieval quality is examined to exclude low-quality and/or aerosol-contaminated results. Most of the retrieval random errors come from the instrumental noise. The interferences by auxiliary parameters retrieved simultaneously with gas abundances are small. The evaluated precisions of the retrieved column abundances for single observations are less than 1% in most cases. The interhemispherical differences and the temporal variation patterns of the retrieved column abundances agree well with the current state of knowledge.

  5. Analyzing six-year-long GOSAT Observational Data

    Science.gov (United States)

    Yokota, T.; Yoshida, Y.; Noda, H.; Morino, I.; Uchino, O.; Takagi, H.; Kim, H. S.; Saito, M.; Maksyutov, S. S.; Fujita, T.; Kawazoe, F.; Ajiro, M.

    2015-12-01

    The Greenhouse gases Observing SATellite (GOSAT) has been operating for more than six-and-a-half years since January 2009. In 2014, GOSAT went through some technical difficulties in the functioning of its solar paddle and sensor pointing mechanism. These problems were overcome later, and the GOSAT observation is still continued without major flaws. GOSAT TANSO-FTS SWIR Level 2 data products, the column-averaged concentrations of carbon dioxide (XCO2) and methane (XCH4) calculated over the past measurement period, have been validated and disseminated to registered researchers and the general public by the NIES GOSAT Project. Also, monthly regional fluxes of CO2 and CH4 (Level 4A data products) over a few year period have been estimated from the FTS SWIR Level 2 data and ground-based GHG monitoring data. Although the above-mentioned technical problems caused a data discontinuity, we accumulated FTS SWIR Level 2 data for more than six years. It is expected that more data will be collected for a few more years while the satellite remains operational. Anomalies in the time series of regional-mean column-averaged concentrations and fluxes are being investigated. In this presentation, we will show the results of the investigation, particularly the ones for some tropical and sub-tropical regions where only few retrievals were obtained due to the influence of frequent cloudiness. Also, we will touch changes in the number of retrievals found over these regions after modifying the satellite's observational pattern. The GOSAT Research Announcement (RA) activities by selected researchers are still continued. In analyzing long-term GOSAT data, events of concentration anomalies (e.g. in 2010 in Europe and in the US, and similar ones in 2013) were found by some of the RA studies. We will summarize the characteristics of GOSAT data products generated over the past several years, and some of the important research outcomes brought by the GOSAT RA researchers.

  6. CARBONGASES: Retrieval and Analysis of Carbon Dioxide and Methane Greenhouse Gases from SCIAMACHY on Envisat

    Science.gov (United States)

    Schneising, O.; Buchwitz, M.; Reuter, M.; Bovensmann, H.; Burrows, J. P.

    2010-12-01

    Carbon dioxide (CO2) and methane (CH4) are the two most important anthropogenic greenhouse gases contributing to global climate change. Despite their importance our knowledge about their variable natural and anthropogenic sources and sinks has significant gaps. Satellite observations can add important global scale information on greenhouse gas sources and sinks provided the data are accurate and precise enough and are sensitive to the lowest atmospheric layers where the variability due to regional greenhouse gas sources and sinks are largest. SCIAMACHY onboard ENVISAT was the first and is now besides TANSO onboard GOSAT the only satellite instrument which covers important absorption bands of both gases in the near-infrared/shortwave- infrared (NIR/SWIR) spectral region. In nadir mode SCIAMACHY observes reflected and backscattered solar radiation. The daytime measurements are therefore very sensitive to near-surface greenhouse gas concentration changes except in case of significant cloud cover. The atmospheric greenhouse gas information is extracted from the SCIAMACHY spectra using the Weighting Function Modified Differential Optical Absorption Spectroscopy (WFM-DOAS or WFMD) algorithm developed at the Institute of Environmental Physics (IUP) of the University of Bremen, Germany. In the framework of the CARBONGASES project, which is part of the Changing Earth Science Network, the afore existing data set focussing on the first three full years of the ENVISAT mission (2003-2005) is improved and extended up to end of 2009 constituting seven years of greenhouse gas information derived from European Earth observation data and closing the gap to GOSAT. The status of this retrieval activity and first results are presented.

  7. Using ocean-glint scattered sunlight as a diagnostic tool for satellite remote sensing of greenhouse gases

    Directory of Open Access Journals (Sweden)

    A. Butz

    2013-09-01

    Full Text Available Spectroscopic measurements of sunlight backscattered by the Earth's surface is a technique widely used for remote sensing of atmospheric constituent concentrations from space. Thereby, remote sensing of greenhouse gases poses particularly challenging accuracy requirements for instrumentation and retrieval algorithms which, in general, suffer from various error sources. Here, we investigate a method that helps disentangle sources of error for observations of sunlight backscattered from the glint spot on the ocean surface. The method exploits the backscattering characteristics of the ocean surface, which is bright for glint geometry but dark for off-glint angles. This property allows for identifying a set of clean scenes where light scattering due to particles in the atmosphere is negligible such that uncertain knowledge of the lightpath can be excluded as a source of error. We apply the method to more than 3 yr of ocean-glint measurements by the Thermal And Near infrared Sensor for carbon Observation (TANSO Fourier Transform Spectrometer (FTS onboard the Greenhouse Gases Observing Satellite (GOSAT, which aims at measuring carbon dioxide (CO2 and methane (CH4 concentrations. The proposed method is able to clearly monitor recent improvements in the instrument calibration of the oxygen (O2 A-band channel and suggests some residual uncertainty in our knowledge about the instrument. We further assess the consistency of CO2 retrievals from several absorption bands between 6400 cm−1 (1565 nm and 4800 cm−1 (2100 nm and find that the absorption bands commonly used for monitoring of CO2 dry air mole fractions from GOSAT allow for consistency better than 1.5 ppm. Usage of other bands reveals significant inconsistency among retrieved CO2 concentrations pointing at inconsistency of spectroscopic parameters.

  8. Using ocean-glint scattered sunlight as a diagnostic tool for satellite remote sensing of greenhouse gases

    Directory of Open Access Journals (Sweden)

    A. Butz

    2013-05-01

    Full Text Available Spectroscopic measurements of sunlight backscattered by the Earth's surface is a technique widely used for remote sensing of atmospheric constituent concentrations from space. Thereby, remote sensing of greenhouse gases poses particularly challenging accuracy requirements for instrumentation and retrieval algorithms which, in general, suffer from various error sources. Here, we investigate a method that helps disentangle sources of error for observations of sunlight backscattered from the glint spot on the ocean surface. The method exploits the backscattering characteristics of the ocean surface which is bright for glint geometry but dark for off-glint angles. This property allows for identifying a set of clean scenes where light scattering due to particles in the atmosphere is negligible such that uncertain knowledge of the lightpath can be excluded as a source of error. We apply the method to more than 3 yr of ocean-glint measurements by the Thermal And Near infrared Sensor for carbon Observation (TANSO – Fourier Transform Spectrometer (FTS onboard the Greenhouse Gases Observing Satellite (GOSAT which aims at measuring carbon dioxide (CO2 and methane (CH4 concentrations. The proposed method is able to clearly monitor recent improvements in the instrument calibration of the oxygen (O2 A-band channel and suggests some residual uncertainty in our knowledge about the instrument. We further assess the consistency of CO2 retrievals from several absorption bands between 6400 cm−1 (1565 nm and 4800 cm−1 (2100 nm and find that the absorption bands commonly used for monitoring of CO2 dry air mole fractions from GOSAT allow for consistency better than 1.5 ppm. Usage of other bands reveals significant inconsistency among retrieved CO2 concentrations pointing at inconsistency of spectroscopic parameters.

  9. Variability of tropospheric methane above the Mediterranean Basin inferred from satellite and model data

    Directory of Open Access Journals (Sweden)

    P. Ricaud

    2014-04-01

    Full Text Available The space and time variabilities of methane (CH4 total column and upper tropospheric mixing ratios are analyzed above the Mediterranean Basin (MB as part of the Chemical and Aerosol Mediterranean Experiment (ChArMEx programme. Spaceborne measurements from the Thermal And Near infrared Sensor for carbon Observations-Fourier Transform Spectrometer (TANSO-FTS instrument on the Greenhouse gases Observing SATellite (GOSAT satellite, the Atmospheric InfraRed Spectrometer (AIRS on the AURA platform and the Infrared Atmospheric Sounder Interferometer (IASI instrument aboard the MetOp-A platform are used in conjunction with model results from the Chemical Transport Model (CTM MOCAGE, and the Chemical Climate Models (CCMs CNRM-AOCCM and LMDz-OR-INCA (according to different emission scenarios. In order to minimize systematic errors in the spaceborne measurements, we have only considered maritime pixels over the MB. The period under interest spans from 2008 to 2011 considering satellite and MOCAGE data and, regarding the CCMs, from 2001 to 2010. An East-West gradient in CH4 is observed and modelled whatever the season considered. In winter, air masses mainly originating from Atlantic Ocean and Europe tend to favour an elevated amount of mid-to-upper tropospheric CH4 in the West vs. the East of the MB, with a general upward transport above the MB. In summer, the meteorological state of the MB is changed, favouring air from Northern Africa and Middle East together with Atlantic Ocean and Europe, with a general downward motion above the MB. The Asian Monsoon traps and uplifts high amounts of CH4 that are transported towards North Africa and Middle East by the Asian Monsoon Anticyclone to finally reach and descent in the East of the MB. Consequently, the mid-to-upper tropospheric CH4 is much greater in the East than in the West of the MB. The seasonal variation of the difference in CH4 between the East and the West MB does show a maximum in summer for pressures

  10. INITIAL COMPARISON OF BASELINE PHYSICAL AND MECHANICAL PROPERTIES FOR THE VHTR CANDIDATE GRAPHITE GRADES

    Energy Technology Data Exchange (ETDEWEB)

    Carroll, Mark C

    2014-09-01

    High-purity graphite is the core structural material of choice in the Very High Temperature Reactor (VHTR) design, a graphite-moderated, helium-cooled configuration that is capable of producing thermal energy for power generation as well as process heat for industrial applications that require temperatures higher than the outlet temperatures of present nuclear reactors. The Baseline Graphite Characterization Program is endeavoring to minimize the conservative estimates of as-manufactured mechanical and physical properties in nuclear-grade graphites by providing comprehensive data that captures the level of variation in measured values. In addition to providing a thorough comparison between these values in different graphite grades, the program is also carefully tracking individual specimen source, position, and orientation information in order to provide comparisons both in specific properties and in the associated variability between different lots, different billets, and different positions from within a single billet. This report is a preliminary comparison between each of the grades of graphite that are considered “candidate” grades from four major international graphite producers. These particular grades (NBG-18, NBG-17, PCEA, IG-110, and 2114) are the major focus of the evaluations presently underway on irradiated graphite properties through the series of Advanced Graphite Creep (AGC) experiments. NBG-18, a medium-grain pitch coke graphite from SGL from which billets are formed via vibration molding, was the favored structural material in the pebble-bed configuration. NBG-17 graphite from SGL is essentially NBG-18 with the grain size reduced by a factor of two. PCEA, petroleum coke graphite from GrafTech with a similar grain size to NBG-17, is formed via an extrusion process and was initially considered the favored grade for the prismatic layout. IG-110 and 2114, from Toyo Tanso and Mersen (formerly Carbone Lorraine), respectively, are fine-grain grades

  11. Small Specimen Data from a High Temperature HFIR Irradiation Experiment

    Energy Technology Data Exchange (ETDEWEB)

    Burchell, Timothy D [ORNL; McDuffee, Joel Lee [ORNL; Thoms, Kenneth R [ORNL

    2014-01-01

    The HTV capsule is a High Flux Isotope Reactor (HFIR) target-rod capsule designed to operate at very high temperatures. The graphite containing section of the capsule (in core) is approximately 18 inches (457.2 mm) long and is separated into eight temperature zones. The specimen diameters within each zone are set to achieve the desired gas gap and hence design temperature (900 C, 1200 C or 1500 C). The capsule has five zones containing 0.400 inch (10.16 mm) diameter specimens, two zones containing 0.350 inch (8.89 mm) diameter specimens and one zone containing 0.300 inch (7.62 mm) diameter specimens. The zones have been distributed within the experiment to optimize the gamma heating from the HFIR core as well as minimize the axial heat flow in the capsule. Consequently, there are two 900 C zones, three 1200 C zones, and three 1500 C zones within the HTV capsule. Each zone contains nine specimens 0.210 0.002 inches (5.334 mm) in length. The capsule will be irradiated to a peak dose of 3.17 displacements per atom. The HTV specimens include samples of the following graphite grades: SGL Carbon s NBG-17 and NBG-18, GrafTech s PCEA, Toyo Tanso s IG-110, Mersen s 2114 and the reference grade H-451 (SGL Carbon). As part of the pre-irradiation program the specimens were characterized using ASTM Standards C559 for bulk density, and ASTM C769 for approximate Young s modulus from the sonic velocity. The probe frequency used for the determination of time of flight of the ultrasonic signal was 2.25 MHz. Marked volume (specimen diameter) effects were noted for both bulk density (increased with increasing specimen volume or diameter) and Dynamic Young s modulus (decreased with increasing specimen volume or diameter). These trends are extended by adding the property vs. diameter data for unirradiated AGC-1 creep specimens (nominally 12.5 mm-diameter x 25.4 mm-length). The relatively large reduction in Dynamic Young s Modulus was surprising given the trend for increasing density

  12. Seasonal variation of the O3-CO correlation derived from remote sensing measurements over western Japan

    Science.gov (United States)

    Ohyama, Hirofumi; Kawakami, Shuji; Uchino, Osamu; Sakai, Tetsu; Morino, Isamu; Nagai, Tomohiro; Shiomi, Kei; Sakashita, Masanori; Akaho, Taiga; Okumura, Hiroshi; Arai, Kohei

    2016-12-01

    We used a lower tropospheric ozone column (LTOC) and column-averaged dry-air mole fraction of carbon monoxide (XCO) data observed in the area around Saga, which is located in western Japan and is close to the Asian continent, with an aim to investigate whether these data can characterize the seasonal variation of the photochemical ozone (O3) formation in the northeast Asian Pacific rim region. The LTOC data after April 2009 were retrieved from thermal infrared spectra measured by the Thermal and Near Infrared Sensor for Carbon Observation-Fourier Transform Spectrometer (TANSO-FTS) onboard the Greenhouse Gases Observing Satellite (GOSAT). The XCO data after July 2011 were obtained from ground-based high-resolution FTS measurements at Saga. The retrieved LTOCs were validated with those derived from a differential absorption lidar for O3 at Saga. The LTOCs showed a distinct seasonal variation that reached a maximum in late spring (May or June) and a local minimum in winter. In addition to the general seasonal pattern, we observed pronounced minimums in July or August. The XCO concentrations showed a maximum in spring and a minimum in summer. These seasonal patterns are consistent with those observed from mountainous sites in Japan. The origins of the air masses reaching Saga were characterized for each season according to backward trajectories, and the factors causing the temporal variations of the LTOCs and the XCO were identified based on the transport paths of the air masses. The enhancement of the LTOC relative to the XCO (ΔO3/ΔCO ratio) reveals significant positive correlations in the spring and summer seasons with slopes of 0.21 and 0.45 ppb/ppb, respectively. The effects of stratospheric air intrusion on the observed ΔO3/ΔCO ratio in spring were investigated using meteorological data (backward trajectory and potential vorticity) and column-averaged hydrogen fluoride data derived from the ground-based FTS measurements. It was found that there was little

  13. Greenhouse gas observations from space: The GHG-CCI project of ESA's Climate Change Initiative

    Science.gov (United States)

    Buchwitz, Michael; Noël, Stefan; Bergamaschi, Peter; Boesch, Hartmut; Bovensmann, Heinrich; Notholt, Justus; Schneising, Oliver; Hasekamp, Otto; Reuter, Maximilian; Parker, Robert; Dils, Bart; Chevallier, Frederic; Zehner, Claus; Burrows, John

    2012-07-01

    The GHG-CCI project (http://www.esa-ghg-cci.org) is one of several projects of ESA's Climate Change Initiative (CCI), which will deliver various Essential Climate Variables (ECVs). The goal of GHG-CCI is to deliver global satellite-derived data sets of the two most important anthropogenic greenhouse gases (GHGs) carbon dioxide (CO2) and methane (CH4) suitable to obtain information on regional CO2 and CH4 surface sources and sinks as needed for better climate prediction. The GHG-CCI core ECV data products are column-averaged mole fractions of CO2 and CH4, XCO2 and XCH4, retrieved from SCIAMACHY on ENVISAT and TANSO on GOSAT. Other satellite instruments will be used to provide constraints in upper layers such as IASI, MIPAS, and ACE-FTS. Which of the advanced algorithms, which are under development, will be the best for a given data product still needs to be determined. For each of the 4 GHG-CCI core data products - XCO2 and XCH4 from SCIAMACHY and GOSAT - several algorithms are being further developed and the corresponding data products are inter-compared to identify which data product is the most appropriate. This includes comparisons with corresponding data products generated elsewhere, most notably with the operational data products of GOSAT generated at NIES and the NASA/ACOS GOSAT XCO2 product. This activity, the so-called "Round Robin exercise", will be performed in the first two years of this project. At the end of the 2 year Round Robin phase (end of August 2012) a decision will be made which of the algorithms performs best. The selected algorithms will be used to generate the first version of the ECV GHG. In the last six months of this 3 year project the resulting data products will be validated and made available to all interested users. In the presentation and overview about this project will be given focussing on the latest results.

  14. Methane Footprint Measurements with IASI and GOSAT - Identification of Source Regions from Space

    Science.gov (United States)

    Malina, E.; Muller, J. P.; Walton, D.; Potts, D.

    2015-12-01

    To date, satellite instruments such as SCIAMACHY and GOSAT-TANSO-FTS have largely focused on regional scale methane output (Kort, A. E., et al. 2014), in order to gain insight into significant methane source regions (such as the Four Corners). However, such an approach does not tackle the root of the issue; the individual sources of methane that account for the total global methane budget, e.g. oil wells and marshland. In this study we aim to use existing satellite sensors onboard Metop and GOSAT to locate point sources of methane from space. We use nine years of global methane measurements from Metop-IASI A/B in order to exploit the exceptionally high global coverage of the instruments (total coverage of the Earth twice a day), and its relatively small spatial footprint in order to accurately identify these methane source regions. Using these data we show which regions have persistent sources (such as the Four Corners), and which are fugitive (methane bubbles in the Arctic), changing from one month to the next. Following the identification of significant source regions using IASI, we increase the resolution by cross-referencing with the higher spatial resolution (but patchy) GOSAT data, in order to answer the question of whether individual gas sources can be identified from space. This study partially follows the method proposed by Kort, who used SCIAMACHY to identify general areas of high methane release in the USA, focusing on the oilrigs in the Four Corners region. This study takes Kort's work further and attempts to identify individual sources (both natural and anthropogenic) using the GOSAT/IASI combination, backed up with ground-based knowledge of sources, such as the FrackTracker database and known natural sources such as the "Door to Hell" in Turkmenistan. Finally we show validation by comparing the individual footprints against methane measurements from the TCCON (Wunch, D., et al. 2010), thus providing confidence in the use of individual satellites

  15. The Canadian Arctic ACE/OSIRIS Validation Project at PEARL: Validating Satellite Observations Over the High Arctic

    Science.gov (United States)

    Walker, Kaley A.; Strong, Kimberly; Fogal, Pierre F.; Drummond, James R.

    2016-04-01

    , the CANDAC Bruker 125HR Fourier transform spectrometer, a Systeme d'Analyse par Observations Zenithales (SAOZ) instrument, and several Brewer spectrophotometers. In the past several years, these results have been used to validate the measurements by the ACE-FTS, ACE-MAESTRO, and OSIRIS instruments as well as the TANSO-FTS instrument on the Japanese Greenhouse Gases Observing Satellite (GOSAT). This presentation will focus on an overview of the measurements made by the ground-based, balloon-borne and satellite-borne instruments during the recent ACE/OSIRIS Arctic Validation campaigns and highlight how these have been used for satellite validation.

  16. ESA's atmospheric composition and dynamics mission

    Science.gov (United States)

    Fehr, Thorsten; Laur, Henri; Hoersch, Bianca; Ingmann, Paul; Wehr, Tobias; Langen, Joerg; Veihelmann, Ben

    Party Missions is improving. Currently, data from CSA's SCISAT (ACE-FTS, MAESTRO), SSC's ODIN (OSIRIS, SMR), JAXA/NIES' GOSAT (TANSO-FTS, -CAI) missions are available; NASA/KNMI OMI/AURA data is foreseen. ESA, with its mission and instruments, is committed to support the science community in their investigations of fundamental processes related to atmospheric composition, chemistry-dynamics coupling and dynamics in the troposphere, stratosphere and upper atmosphere. The presentation will provide a consolidated status the ESA atmospheric mission, in particular with respect development, instruments, algorithm development and data distribution status.

  17. The Carbon in Arctic Reservoirs Vulnerability Experiment (CARVE) FTS: Results From the 2012/13 Alaska Campaigns

    Science.gov (United States)

    kurosu, T. P.; Miller, C. E.; Dinardo, S.

    2013-12-01

    from TANSO/GOSAT as well as results from CARVE in situ measurements. CARVE Science Team: L. Bruhwiler, NOAA ESRL I. Fung, UC Berkeley C. Koven, Lawrence Berkeley Laboratory I. Leifer, UC Santa Barbara K. McDonald, CCNY J. Miller, NOAA ESRL W. Oechel, San Diego State University E. Podest, JPL J. Randerson, UC Irvine P. Rayner, Melbourne University D. Rider, JPL C. Sweeney, NOAA ESRL P. Wennberg, Caltech S. Wofsy, Harvard University R. Chang, Harvard University A. Karion, NOAA ESRL T. P. Kurosu, JPL N. Steiner, CCNY J. Henderson, AER J. Fisher, JPL

  18. Can satellite-based monitoring techniques be used to quantify volcanic CO2 emissions?

    Science.gov (United States)

    Schwandner, Florian M.; Carn, Simon A.; Kuze, Akihiko; Kataoka, Fumie; Shiomi, Kei; Goto, Naoki; Popp, Christoph; Ajiro, Masataka; Suto, Hiroshi; Takeda, Toru; Kanekon, Sayaka; Sealing, Christine; Flower, Verity

    2014-05-01

    Since 2010, we investigate and improve possible methods to regularly target volcanic centers from space in order to detect volcanic carbon dioxide (CO2) point source anomalies, using the Japanese Greenhouse gas Observing SATellite (GOSAT). Our long-term goals are: (a) better spatial and temporal coverage of volcano monitoring techniques; (b) improvement of the currently highly uncertain global CO2 emission inventory for volcanoes, and (c) use of volcanic CO2 emissions for high altitude, strong point source emission and dispersion studies in atmospheric science. The difficulties posed by strong relief, orogenic clouds, and aerosols are minimized by a small field of view, enhanced spectral resolving power, by employing repeat target mode observation strategies, and by comparison to continuous ground based sensor network validation data. GOSAT is a single-instrument Earth observing greenhouse gas mission aboard JAXA's IBUKI satellite in sun-synchronous polar orbit. GOSAT's Fourier-Transform Spectrometer (TANSO-FTS) has been producing total column XCO2 data since January 2009, at a repeat cycle of 3 days, offering great opportunities for temporal monitoring of point sources. GOSAT's 10 km field of view can spatially integrate entire volcanic edifices within one 'shot' in precise target mode. While it doesn't have any spatial scanning or mapping capability, it does have strong spectral resolving power and agile pointing capability to focus on several targets of interest per orbit. Sufficient uncertainty reduction is achieved through comprehensive in-flight vicarious calibration, in close collaboration between NASA and JAXA. Challenges with the on-board pointing mirror system have been compensated for employing custom observation planning strategies, including repeat sacrificial upstream reference points to control pointing mirror motion, empirical individualized target offset compensation, observation pattern simulations to minimize view angle azimuth. Since summer 2010

  19. Ten Years of Near-Surface-Sensitive Satellite Observations of Carbon Dioxide and Methane: Selected Results Related to Natural and Anthropogenic Sources and Sinks

    Science.gov (United States)

    Buchwitz, M. A.; Reuter, M.; Schneising, O.; Bovensmann, H.; Burrows, J. P.

    2014-12-01

    Prior to the recently successfully launched OCO-2 mission, global near-surface-sensitive satellite observations of carbon dioxide (CO2) have been made with SCIAMACHY/ENVISAT during 2002-2012 and are still being made since 2009 with TANSO-FTS/GOSAT, which also deliver atmospheric methane (CH4). The SCIAMACHY and GOSAT overlapping time series of atmospheric column-averaged mole fractions, i.e., XCO2 and XCH4, now cover more than 10 years. During the last years significant progress has been made in improving the quality of the XCO2 and XCH4 data products retrieved from SCIAMACHY and GOSAT and in extending the time series so that more and more applications can be addressed. In this presentation we present some recent results related to CO2 and CH4 sources and sinks. The SCIAMACHY products have been generated using retrieval algorithms developed at University of Bremen. For XCO2 we use an ensemble of data products generated using GOSAT retrieval algorithms developed in Japan (at NIES), in the US (at NASA/JPL and collaborating institutes) and at European institutions (University of Leicester, UK, and SRON, Netherlands, in collaboration with KIT, Germany). Focus will be on three applications: (i) An assessment of the strength of the European terrestrial carbon sink during 2003-2010 based on an ensemble of SCIAMACHY (2003-2010) and GOSAT (2010) XCO2 data products, (ii) an assessment of CO2 and NO2 anthropogenic emission and emission ratio trends using co-located SCIAMACHY XCO2 and NO2 observations over Europe, North America and East Asia, and (iii) an analysis of SCIAMACHY XCH4 retrievals during 2006-2011 over North America focusing on fugitive methane emissions from oil and gas production using tight geological formations ("fracking"). It will be shown that (i) the European terrestrial carbon sink appears to be stronger than expected, (ii) that recent Chinese CO2 and NO2 emissions are increasing but with a trend towards reduced NO2-to-CO2 emission ratios pointing to

  20. Long-term analysis of carbon dioxide and methane column-averaged mole fractions retrieved from SCIAMACHY

    Directory of Open Access Journals (Sweden)

    O. Schneising

    2011-03-01

    Full Text Available Carbon dioxide (CO2 and methane (CH4 are the two most important anthropogenic greenhouse gases contributing to global climate change. SCIAMACHY onboard ENVISAT (launch 2002 was the first and is now with TANSO onboard GOSAT (launch 2009 one of only two satellite instruments currently in space whose measurements are sensitive to CO2 and CH4 concentration changes in the lowest atmospheric layers where the variability due to sources and sinks is largest.

    We present long-term SCIAMACHY retrievals (2003–2009 of column-averaged dry air mole fractions of both gases (denoted XCO2 and XCH4 derived from absorption bands in the near-infrared/shortwave-infrared (NIR/SWIR spectral region focusing on large-scale features. The results are obtained using an upgraded version (v2 of the retrieval algorithm WFM-DOAS including several improvements, while simultaneously maintaining its high processing speed. The retrieved mole fractions are compared to global model simulations (CarbonTracker XCO2 and TM5 XCH4 being optimised by assimilating highly accurate surface measurements from the NOAA/ESRL network and taking the SCIAMACHY averaging kernels into account. The comparisons address seasonal variations and long-term characteristics.

    The steady increase of atmospheric carbon dioxide primarily caused by the burning of fossil fuels can be clearly observed with SCIAMACHY globally. The retrieved global annual mean XCO2 increase agrees with CarbonTracker within the error bars (1.80±0.13 ppm yr−1 compared to 1.81±0.09 ppm yr−1. The amplitude of the XCO2 seasonal cycle as retrieved by SCIAMACHY, which is 4.3±0.2 ppm for the Northern Hemisphere and 1.4±0.2 ppm for the Southern Hemisphere, is on average about 1 ppm larger than for CarbonTracker.

    An investigation of the boreal forest carbon uptake during the

  1. Spatial and Temporal Distribution Characteristics of CO2 Column Concentration in China from 2009 to 2010%中国区域近地面CO2时空分布特征研究

    Institute of Scientific and Technical Information of China (English)

    赵静; 崔伟宏

    2014-01-01

    本文利用2009年6月至2010年5月日本宇宙航空研究开发机构(JAXA)、日本环境署(MOE)与日本环境研究(NIES)所等联合开发的全球首颗专用温室气体观测卫星“呼吸号”(GOSAT)上的被动红外探测器(TANSO)官方反演的近地面975hPa左右的CO2浓度L4B数据产品,采用ArcGIS地统计分析方法,对比瓦里关全球大气本底站地面观测数据进行真实性检验,分析中国区域近地面CO2浓度分布的时空变化特征。结果表明:中国区域近地面CO2浓度空间分布集中,东高西低,差异显著;CO2浓度具有明显的季节变化特征,月平均浓度4月份(春季)升至最高,7月份(夏季)降至最低。结合“中国统计年鉴2012”中的2009年人口密度、能源消费总量(煤)和GDP等辅助数据对比发现:导致中国近地面CO2浓度空间分布规律的原因多种多样,不可轻易定论是人为或自然使然,需进一步深入研究。%Data adopted was the official near the ground surface (975hPa) CO2 concentration L4B retrieval data products of GOSAT-the world’s first Greenhouse Gases Observing Satellite“Breathing No.”-with a passive infrared detector (TANSO) from June 2009 to May 2010, which was jointly developed by Japan Aerospace Ex-ploration Agency (JAXA), Japanese Environment Agency (MOE) and the Japan Institute for Environmental Stud-ies (NIES). Based on the ArcGIS Geostatistical Analytical Method, authenticity inspection was processed by comparing the data mentioned above with the ground observation data of the Global Atmospheric Background Station (Waliguan), in order to analyze Chinese CO2 concentration spatial and temporal variations near the ground surface. The results show that:(i) Chinese CO2 concentration near the ground surface is concentrated and has a high value in the East, a low value in the West;(ii) Chinese CO2 concentration has an obviously seasonal variation characteristic that

  2. Retrieving CO2 from Orbiting Carbon Observatory-2 (OCO-2) Spectra

    Science.gov (United States)

    Crisp, David

    2014-06-01

    reflected sunlight in near infrared CO2 and O2 bands. However, this is among the most challenging space-based remote sensing applications because even the largest CO2 sources and sinks produce changes in the background XCO2 distribution no larger than 1%, and most are smaller 0.25% (˜1 ppm). This approach was pioneered by the European Space Agency's EnviSat SCIAMACHY and Japanese GOSAT TANSO-FTS instruments. These sensors have provided valuable insights into space based XCO2 measurement techniques, but still do not have the sensitivity, resolution, and coverage needed to quantify CO2 sources and sinks on regional scales. The Orbiting Carbon Observatory-2 (OCO-2) is the first NASA spacecraft designed to exploit this measurement approach. This spacecraft carries and points a 3channel, imaging, grating spectrometer that collects high resolution spectra of reflected sunlight in the 765 nm O2 A-band and in the 1610 and 2060 nm CO2 bands. Coincident O2 and CO2 spectra are combined into "soundings" that are analyzed with a full-physics retrieval algorithm to yield estimates of XCO2. Each spectrometer channel will collect 24 spectra per second, yielding up to a million soundings per day over the sunlit hemisphere. Between 10 and 30% of these soundings are expected to be sufficiently cloud free to yield full-column estimates of XCO2. OCO-2 is currently scheduled for launch from Space Launch Complex 2 at Vandenberg Air Force Base in California on a United Launch Alliance Delta-II 7320-10 Launch Vehicle at 02:56:44 AM PDT (12:56:44 GMT) on 1 July 2014. The nominal spacecraft checkout and orbit raising plan will take about 37 days to insert the observatory into the 705-km Afternoon Constellation (A-Train). This 98.8-minute, sun-synchronous orbit has a 98.2-degree inclination, a 1:36:30 PM mean ascending equator crossing time time, and a 16-day (233 orbit) ground track repeat cycle. Once in the A-Train, the instrument's optical bench and detectors will be cooled to their operating

  3. Atmospheric CH4 and CO2 enhancements and biomass burning emission ratios derived from satellite observations of the 2015 Indonesian fire plumes

    Science.gov (United States)

    Parker, Robert J.; Boesch, Hartmut; Wooster, Martin J.; Moore, David P.; Webb, Alex J.; Gaveau, David; Murdiyarso, Daniel

    2016-08-01

    increases in regional greenhouse gas concentrations. CH4 is particularly enhanced, due to the dominance of smouldering combustion in peatland fires, with CH4 total column values typically exceeding 35 ppb above those of background "clean air" soundings. By examining the CH4 and CO2 excess concentrations in the fire-affected GOSAT observations, we determine the CH4 to CO2 (CH4 / CO2) fire emission ratio for the entire 2-month period of the most extreme burning (September-October 2015), and also for individual shorter periods where the fire activity temporarily peaks. We demonstrate that the overall CH4 to CO2 emission ratio (ER) for fires occurring in Indonesia over this time is 6.2 ppb ppm-1. This is higher than that found over both the Amazon (5.1 ppb ppm-1) and southern Africa (4.4 ppb ppm-1), consistent with the Indonesian fires being characterised by an increased amount of smouldering combustion due to the large amount of organic soil (peat) burning involved. We find the range of our satellite-derived Indonesian ERs (6.18-13.6 ppb ppm-1) to be relatively closely matched to that of a series of close-to-source, ground-based sampling measurements made on Kalimantan at the height of the fire event (7.53-19.67 ppb ppm-1), although typically the satellite-derived quantities are slightly lower on average. This seems likely because our field sampling mostly intersected smaller-scale peat-burning plumes, whereas the large-scale plumes intersected by the GOSAT Thermal And Near infrared Sensor for carbon Observation - Fourier Transform Spectrometer (TANSO-FTS) footprints would very likely come from burning that was occurring in a mixture of fuels that included peat, tropical forest and already-cleared areas of forest characterised by more fire-prone vegetation types than the natural rainforest biome (e.g. post-fire areas of ferns and scrubland, along with agricultural vegetation).The ability to determine large-scale ERs from satellite data allows the combustion behaviour of very