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Sample records for asymmetric ligand x-ray

  1. Asymmetrically cut crystal pair as x-ray magnifier for imaging at high intensity laser facilities

    International Nuclear Information System (INIS)

    The potential of an x-ray magnifier prepared from a pair of asymmetrically cut crystals is studied to explore high energy x-ray imaging capabilities at high intensity laser facilities. OMEGA-EP and NIF when irradiating mid and high Z targets can be a source of high-energy x-rays whose production mechanisms and use as backlighters are a subject of active research. This paper studies the properties and potential of existing asymmetric cut crystal pairs from the National Institute of Standards and Technology (NIST) built in a new enclosure for imaging x-ray sources. The technique of the x-ray magnifier has been described previously. This new approach is aimed to find a design that could be used at laser facilities by magnifying the x-ray source into a screen far away from the target chamber center, with fixed magnification defined by the crystals' lattice spacing and the asymmetry angles. The magnified image is monochromatic and the imaging wavelength is set by crystal asymmetry and incidence angles. First laboratory results are presented and discussed.

  2. Asymmetric masks for laboratory-based X-ray phase-contrast imaging with edge illumination

    Science.gov (United States)

    Endrizzi, Marco; Astolfo, Alberto; Vittoria, Fabio A.; Millard, Thomas P.; Olivo, Alessandro

    2016-05-01

    We report on an asymmetric mask concept that enables X-ray phase-contrast imaging without requiring any movement in the system during data acquisition. The method is compatible with laboratory equipment, namely a commercial detector and a rotating anode tube. The only motion required is that of the object under investigation which is scanned through the imaging system. Two proof-of-principle optical elements were designed, fabricated and experimentally tested. Quantitative measurements on samples of known shape and composition were compared to theory with good agreement. The method is capable of measuring the attenuation, refraction and (ultra-small-angle) X-ray scattering, does not have coherence requirements and naturally adapts to all those situations in which the X-ray image is obtained by scanning a sample through the imaging system.

  3. Synthesis, X-ray crystal structures and catecholase activity investigation of new chalcone ligands

    Science.gov (United States)

    Thabti, Salima; Djedouani, Amel; Rahmouni, Samra; Touzani, Rachid; Bendaas, Abderrahmen; Mousser, Hénia; Mousser, Abdelhamid

    2015-12-01

    The reaction of dehydroacetic acid DHA carboxaldehyde and RCHO derivatives (R = quinoleine-8-; indole-3-; pyrrol-2- and 4-(dimethylamino)phenyl - afforded four new chalcone ligands (4-hydroxy-6-methyl-3-[(2E)-3-quinolin-8-ylprop-2-enoyl]-2H-pyran-2-one) L1, (4-hydroxy-3-[(2E)-3-(1H-indol-3-yl)prop-2-enoyl]-6-methyl-2H-pyran-2-one) L2, (4-hydroxy-6-methyl-3-[(2E)-3-(1H-pyrrol-2-yl)prop-2-enoyl]-2H-pyran-2-one) L3, and (3-{(2E)-3-[4-(dimethylamino)phenyl]prop-2-enoyl}-4-hydroxy-6-methyl-2H-pyran-2-one) L4. L3 and L4 were characterized by X-ray crystallography. Molecules crystallize with four and two molecules in the asymmetric unit, respectively and adopt an E conformation about the Cdbnd C bond. Both structures are stabilized by an extended network O-H … O. Furthermore, N-H … O and C-H … O hydrogen bonds are observed in L3 and L4 structures, respectively. The in situ generated copper (II) complexes of the four compounds L1, L2, L3 and L4 were examined for their catalytic activities and were found to catalyze the oxidation reaction of catechol to o-quinone under atmospheric dioxygen. The rates of this oxidation depend on three parameters: ligand, ion salts and solvent nature and the combination L2[Cu (CH3COO)2] leads to the faster catalytic process.

  4. Tunable hard X-ray spectrometer utilizing asymmetric planes of a quartz transmission crystal

    Science.gov (United States)

    Seely, John F.; Henins, Albert; Feldman, Uri

    2016-05-01

    A Cauchois type hard x-ray spectrometer was developed that utilizes the (301) diffraction planes at an asymmetric angle of 23.51° to the normal to the surface of a cylindrically curved quartz transmission crystal. The energy coverage is tunable by rotating the crystal and the detector arm, and spectra were recorded in the 8 keV to 20 keV range with greater than 2000 resolving power. The high resolution results from low aberrations enabled by the nearly perpendicular angle of the diffracted rays with the back surface of the crystal. By using other asymmetric planes of the same crystal and rotating to selected angles, the spectrometer can operate with high resolution up to 50 keV.

  5. Design, x-ray image guidance and flow characterization of new asymmetric vascular stents

    Science.gov (United States)

    Ionita, Ciprian N.

    Recent advances of x-ray imaging techniques have made possible improvement and development of new minimally invasive image guided interventions (IGI). Capabilities such as real-time, high special resolution image guidance with down to sub-millimeter precision, enabled a large increase in the number of the new minimally invasive treatments using x-ray guidance. One such treatment is a new method we are developing to treat intracranial aneurysms (ICA) using a new device, the asymmetric vascular stent (AVS). The present work deals with the physical aspects of the development and evaluation of this new device. In general, stents are specially designed vascular prosthesis similar to a uniform porous wire cylinder. Unlike current stents, the new devices have a low porous region which creates an asymmetry, hence the name we use for the device. The treatment of an intracranial aneurysm using AVSs is done by placing the low porous part over the aneurysm neck. By doing so, the flow in the aneurysm is modified and conditions for the thrombosis are created. The research on the device consisted of three parts: (i) design and fabrication of the device, (ii) flow evaluation and (iii) accurate of localization of the device during x-ray IGI. The first part involved the process design and fabrication of the stents using laser micro-welding. The second part was dedicated to flow evaluation and flow characterization of the AVS. The characterization of the flow parameters of the stent were done based on physical aspects of the flow and the structure geometry. Theoretical or empirical models were evaluated experimentally in order to verify if they were appropriate for our device. We verified the effects that stents have on flow in aneurysms using methods such as Particle Image Velocimetry (PIV) and x-ray video-densitometric measurements. The last part involved the development of a marking technique using x-ray radio-opaque markers. We verified the accuracy of placement of the stent when

  6. Strain distribution at buried interfaces revealed by extremely asymmetric x-ray diffraction

    International Nuclear Information System (INIS)

    Surface strain of Si(1 1 1) surfaces implanted by 1.5 MeV Au2+ ion was observed by extremely asymmetric x-ray diffraction. A broad sub peak accompanied with intensity oscillation was observed at low-angle side of bulk peak in the measured rocking curves. Lattice strain due to ion implantation was evaluated by curve-fitting with calculated curve by a dynamical diffraction theory. The results showed that the lattice spacing of (1 1 1) planes was expanded by ∼500 nm under the surface. The simulation of rocking curve vs. strain parameters revealed that this technique is sensitive to strain profile within a depth of ∼80 nm. (author)

  7. Asymmetric and Stochastic Behavior in Magnetic Vortices Studied by Soft X-ray Microscopy

    Science.gov (United States)

    Im, Mi-Young

    Asymmetry and stochasticity in spin processes are not only long-standing fundamental issues but also highly relevant to technological applications of nanomagnetic structures to memory and storage nanodevices. Those nontrivial phenomena have been studied by direct imaging of spin structures in magnetic vortices utilizing magnetic transmission soft x-ray microscopy (BL6.1.2 at ALS). Magnetic vortices have attracted enormous scientific interests due to their fascinating spin structures consisting of circularity rotating clockwise (c = + 1) or counter-clockwise (c = -1) and polarity pointing either up (p = + 1) or down (p = -1). We observed a symmetry breaking in the formation process of vortex structures in circular permalloy (Ni80Fe20) disks. The generation rates of two different vortex groups with the signature of cp = + 1 and cp =-1 are completely asymmetric. The asymmetric nature was interpreted to be triggered by ``intrinsic'' Dzyaloshinskii-Moriya interaction (DMI) arising from the spin-orbit coupling due to the lack of inversion symmetry near the disk surface and ``extrinsic'' factors such as roughness and defects. We also investigated the stochastic behavior of vortex creation in the arrays of asymmetric disks. The stochasticity was found to be very sensitive to the geometry of disk arrays, particularly interdisk distance. The experimentally observed phenomenon couldn't be explained by thermal fluctuation effect, which has been considered as a main reason for the stochastic behavior in spin processes. We demonstrated for the first time that the ultrafast dynamics at the early stage of vortex creation, which has a character of classical chaos significantly affects the stochastic nature observed at the steady state in asymmetric disks. This work provided the new perspective of dynamics as a critical factor contributing to the stochasticity in spin processes and also the possibility for the control of the intrinsic stochastic nature by optimizing the design of

  8. Morphological and quantitative analyses on features of asymmetric mandible with X-ray CT images

    International Nuclear Information System (INIS)

    Biomechanical disproportion of the mandible causes morphological and quantitative changes in the bone and induces jaw deformities. The purpose of this study was to clarify the influence of the biomechanical disproportion on the structure and quality of the mandible, using spiral X-ray CT images. Subjects were 11 patients with mandibular asymmetry requiring orthognathic surgery. Lateral and vertical shift angles of the mandible against the maxilla were determined mathematically from the coordinates of structural reference points in 3-dimensional orthogonal coordinate systems as indices of the deformity degree. Several properties concerning thickness and CT value of mandibular cortical bone were measured as indices of the morphological and quantitative changes in mandibular cortical bone. Occlusal force was also measured using a pressure sensitive film as an index of biomechanical disproportion. Asymmetric indices of them were calculated from data of the left and right sides. The Pearson's correlation coefficients were obtained for these data. As a result, the mandible tended to shift laterally toward the side where the occlusal force at the second molar region was stronger and also to shift upward on that side. At the central incisor region of the laterally shifted side, CT values were relatively decreased. At the lateral incisor region, cortical bone density was relatively increased. At the first bicuspid region and the posterior tooth regions, cortical bone thickness was relatively decreased. (author)

  9. Morphological and quantitative analyses on features of asymmetric mandible with X-ray CT images

    Energy Technology Data Exchange (ETDEWEB)

    Hayashi, Masaki; Isshiki, Yasushige; Nishikawa, Keiichi [Tokyo Dental Coll., Chiba (Japan)

    2001-09-01

    Biomechanical disproportion of the mandible causes morphological and quantitative changes in the bone and induces jaw deformities. The purpose of this study was to clarify the influence of the biomechanical disproportion on the structure and quality of the mandible, using spiral X-ray CT images. Subjects were 11 patients with mandibular asymmetry requiring orthognathic surgery. Lateral and vertical shift angles of the mandible against the maxilla were determined mathematically from the coordinates of structural reference points in 3-dimensional orthogonal coordinate systems as indices of the deformity degree. Several properties concerning thickness and CT value of mandibular cortical bone were measured as indices of the morphological and quantitative changes in mandibular cortical bone. Occlusal force was also measured using a pressure sensitive film as an index of biomechanical disproportion. Asymmetric indices of them were calculated from data of the left and right sides. The Pearson's correlation coefficients were obtained for these data. As a result, the mandible tended to shift laterally toward the side where the occlusal force at the second molar region was stronger and also to shift upward on that side. At the central incisor region of the laterally shifted side, CT values were relatively decreased. At the lateral incisor region, cortical bone density was relatively increased. At the first bicuspid region and the posterior tooth regions, cortical bone thickness was relatively decreased. (author)

  10. X-ray Emission Spectroscopy to Study Ligand Valence Orbitals in Mn Coordination Complexes

    Energy Technology Data Exchange (ETDEWEB)

    Smolentsev, Grigory; Soldatov, Alexander V; Messinger, Johannes; Merz, Kathrin; Weyhermuller, Thomas; Bergmann, Uwe; Pushkar, Yulia; Yano, Junko; Yachandra, Vittal K.; Glatzel, Pieter

    2009-03-02

    We discuss a spectroscopic method to determine the character of chemical bonding and for the identification of metal ligands in coordination and bioinorganic chemistry. It is based on the analysis of satellite lines in X-ray emission spectra that arise from transitions between valence orbitals and the metal ion 1s level (valence-to-core XES). The spectra, in connection with calculations based on density functional theory (DFT), provide information that is complementary to other spectroscopic techniques, in particular X-ray absorption (XANES and EXAFS). The spectral shape is sensitive to protonation of ligands and allows ligands, which differ only slightly in atomic number (e.g., C, N, O...), to be distinguished. A theoretical discussion of the main spectral features is presented in terms of molecular orbitals for a series of Mn model systems: [Mn(H2O)6]2+, [Mn(H2O)5OH]+, [Mn(H2O)5NH2]+, and [Mn(H2O)5NH3]2+. An application of the method, with comparison between theory and experiment, is presented for the solvated Mn2+ ion in water and three Mn coordination complexes, namely [LMn(acac)N3]BPh4, [LMn(B2O3Ph2)(ClO4)], and [LMn(acac)N]BPh4, where L represents 1,4,7-trimethyl-1,4,7-triazacyclononane, acac stands for the 2,4-pentanedionate anion, and B2O3Ph2 represents the 1,3-diphenyl-1,3-dibora-2-oxapropane-1,3-diolato dianion.

  11. Asymmetric Distribution of Metals in the Xenopus Laevis Oocyte: a Synchrotron X-Ray Fluorescence Microprobe Study

    Energy Technology Data Exchange (ETDEWEB)

    Popescu, B.F.Gh.; Belak, Z.R.; Ignatyev, K.; Ovsenek, N.; Nichol, H.

    2009-06-04

    The asymmetric distribution of many components of the Xenopus oocyte, including RNA, proteins, and pigment, provides a framework for cellular specialization during development. During maturation, Xenopus oocytes also acquire metals needed for development, but apart from zinc, little is known about their distribution. Synchrotron X-ray fluorescence microprobe was used to map iron, copper, and zinc and the metalloid selenium in a whole oocyte. Iron, zinc, and copper were asymmetrically distributed in the cytoplasm, while selenium and copper were more abundant in the nucleus. A zone of high copper and zinc was seen in the animal pole cytoplasm. Iron was also concentrated in the animal pole but did not colocalize with zinc, copper, or pigment accumulations. This asymmetry of metal deposition may be important for normal development. Synchrotron X-ray fluorescence microprobe will be a useful tool to examine how metals accumulate and redistribute during fertilization and embryonic development.

  12. Asymmetric Distribution of Metals in the Xenopus Laevis Oocyte: a Synchrotron X-Ray Fluorescence Microprobe Study

    International Nuclear Information System (INIS)

    The asymmetric distribution of many components of the Xenopus oocyte, including RNA, proteins, and pigment, provides a framework for cellular specialization during development. During maturation, Xenopus oocytes also acquire metals needed for development, but apart from zinc, little is known about their distribution. Synchrotron X-ray fluorescence microprobe was used to map iron, copper, and zinc and the metalloid selenium in a whole oocyte. Iron, zinc, and copper were asymmetrically distributed in the cytoplasm, while selenium and copper were more abundant in the nucleus. A zone of high copper and zinc was seen in the animal pole cytoplasm. Iron was also concentrated in the animal pole but did not colocalize with zinc, copper, or pigment accumulations. This asymmetry of metal deposition may be important for normal development. Synchrotron X-ray fluorescence microprobe will be a useful tool to examine how metals accumulate and redistribute during fertilization and embryonic development.

  13. Asymmetric Distribution of Metals in the Xenopus laevis oocyte: a Synchrotron X-Ray Fluorescence Microprobe Study

    International Nuclear Information System (INIS)

    The asymmetric distribution of many components of the Xenopus oocyte, including RNA, proteins, and pigment, provides a framework for cellular specialization during development. During maturation, Xenopus oocytes also acquire metals needed for development, but apart from zinc, little is known about their distribution. Synchrotron X-ray fluorescence microprobe was used to map iron, copper, and zinc and the metalloid selenium in a whole oocyte. Iron, zinc, and copper were asymmetrically distributed in the cytoplasm, while selenium and copper were more abundant in the nucleus. A zone of high copper and zinc was seen in the animal pole cytoplasm. Iron was also concentrated in the animal pole but did not colocalize with zinc, copper, or pigment accumulations. This asymmetry of metal deposition may be important for normal development. Synchrotron X-ray fluorescence microprobe will be a useful tool to examine how metals accumulate and redistribute during fertilization and embryonic development.

  14. X-ray absorption spectral studies of copper (II) mixed ligand complexes

    International Nuclear Information System (INIS)

    X-ray absorption spectra at the K-edge of copper have been studied in two copper mixed ligand complexes, one having tetramethyethylenediamine (tmen) and the other having tetraethyethylenediamine (teen) as one of the ligands. The spectra have been recorded at BL-8 dispersive extended X-ray absorption fine structure (EXAFS) beamline at the 2.5 GeV INDUS- 2 synchrotron, RRCAT, Indore, India. The data obtained has been processed using the data analysis program Athena. The energy of the K-absorption edge, chemical shift, edge-width and shift of the principal absorption maximum in the complexes have been determined and discussed. The values of these parameters have been found to be approximately the same in both the complexes indicating that the two complexes possess similar chemical environment around the copper metal atom. The chemical shift has been utilized to estimate effective nuclear charge on the absorbing atom. The normalized EXAFS spectra have been Fourier transformed. The position of the first peak in the Fourier transform gives the value of first shell bond length, which is shorter than the actual bond length because of energy dependence of the phase factors in the sine function of the EXAFS equation. This distance is thus the phase- uncorrected bond length. Bond length has also been determined by Levy's, Lytle's and Lytle, Sayers and Stern's (LSS) methods. The results obtained from LSS and the Fourier transformation methods are comparable with each other, since both are phase uncorrected bond lengths.

  15. Effect of Epilayer Tilt on Dynamical X-ray Diffraction from Uniform Heterostructures with Asymmetric Dislocation Densities

    Science.gov (United States)

    Rago, P. B.; Jain, F. C.; Ayers, J. E.

    2013-11-01

    In this work we extend the dynamical theory of Bragg x-ray diffraction to account for a tilted, asymmetrically defected, uniform-composition epitaxial layer atop a (001) substrate. In a zincblende semiconductor there are eight active slip systems, within which two distinct types of dislocations exist. These two types are distinguished by their misfit segments, which are oriented along either the [110] or direction. The two threading dislocation densities can be measured by observing the variation of the x-ray rocking curve width with the incident beam azimuth. However, the tilting of the epilayer also has a measurable and potentially conflicting effect on the rocking curve as a function of azimuth. First, the peak position varies by (nominally) twice the layer's absolute tilt within a full azimuthal rotation. Second, the tilting of the layer affects the epilayer rocking curve width. Through use of the modified dynamical diffraction theory, we show that the peak width's azimuthal dependence on tilt is of only second order, so that the layer misorientation with respect to the substrate need not be considered for the purpose of determining the two dislocation populations by x-ray diffraction. Dynamical simulations were performed and compared with experimental measurements for a ZnSe/GaAs(001) structure grown by photoassisted metalorganic vapor-phase epitaxy, and in this way the two dislocation density populations were found to be D A = 1.6 × 108 cm-2 and D B = 2.0 × 108 cm-2.

  16. X-ray diffraction and absorption spectroscopic studies of copper mixed ligand complexes with aminophenol as one of the ligands

    International Nuclear Information System (INIS)

    X-ray diffraction (XRD) and X-ray absorption spectroscopic (XAS) studies have been conducted on two copper complexes, i.e., copper macrocyclic complex of succinic acid and ortho aminophenol (complex-1) and copper macrocyclic complex of pthalic acid and ortho aminophenol (complex-2). The diffraction pattern of the complexes have been recorded using Rigaku RINT-2000 X-ray diffractometer equipped with rotating anode X-ray tube operated at 40 kV and 100 mA. The X-ray absorption spectra of the complexes have been recorded at the K-edge of copper on Cauchois type bent crystal spectrograph having radius 0.4 m employing a mica crystal, oriented to reflect from (100) planes, for dispersion. The X-ray absorption near edge structure (XANES) parameters, viz., chemical shift, energy position of the principal absorption maximum and edge-width have been determined and discussed. From the extended X-ray absorption fine structure (EXAFS) data, the bond lengths have been calculated using three methods, namely, Levy's method, Lytle, Sayers and Stern's (LSS) method and Fourier transformation method. The results obtained have been compared with each other and discussed.

  17. Ligand-field symmetry effects in Fe(II) polypyridyl compounds probed by transient X-ray absorption spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Hana; Strader, Matthew L.; Hong, Kiryong; Jamula, Lindsey; Kim, Tae Kyu; Groot, Frank M. F. de; McCusker, James K.; Schoenlein, Robert W.; Huse, Nils

    2012-02-28

    Ultrafast excited-state evolution in polypyridyl FeII complexes are of fundamental interest for understanding the origins of the sub-ps spin-state changes that occur upon photoexcitation of this class of compounds as well as for the potential impact such ultrafast dynamics have on incorporation of these compounds in solar energy conversion schemes or switchable optical storage technologies. We have demonstrated that ground-state and, more importantly, ultrafast time-resolved x-ray absorption methods can offer unique insights into the interplay between electronic and geometric structure that underpin the photo-induced dynamics of this class of compounds. The present contribution examines in greater detail how the symmetry of the ligand field surrounding the metal ion can be probed using these x-ray techniques. In particular, we show that steady-state K-edge spectroscopy of the nearest-neighbour nitrogen atoms reveals the characteristic chemical environment of the respective ligands and suggests an interesting target for future charge-transfer femtosecond and attosecond spectroscopy in the x-ray water window.

  18. Flexible and Asymmetric Ligand in Constructing Coordinated Complexes: Synthesis, Crystal Structures and Fluorescent Characterization

    Directory of Open Access Journals (Sweden)

    Jianhua Lin

    2010-12-01

    Full Text Available Flexible and asymmetric ligand L [L = 1-((pyridin-3-ylmethyl-1H-benzotriazole], is used as a basic backbone to construct complicated metal-organic frameworks. Two new polymers, namely, [Ag2(L2(NO32]n (1 and [Ag(L(ClO4]n (2, were synthesized and characterized by X-ray structure analysis and fluorescent spectroscopy. The complex 1 gives an “S” type double helical conformation, whereas complex 2 exhibits a 1D zigzag configuration. Different anions affect the silver coordination geometry and crystal packing topology.

  19. Structural studies of P-type ATPase–ligand complexes using an X-ray free-electron laser

    Directory of Open Access Journals (Sweden)

    Maike Bublitz

    2015-07-01

    Full Text Available Membrane proteins are key players in biological systems, mediating signalling events and the specific transport of e.g. ions and metabolites. Consequently, membrane proteins are targeted by a large number of currently approved drugs. Understanding their functions and molecular mechanisms is greatly dependent on structural information, not least on complexes with functionally or medically important ligands. Structure determination, however, is hampered by the difficulty of obtaining well diffracting, macroscopic crystals. Here, the feasibility of X-ray free-electron-laser-based serial femtosecond crystallography (SFX for the structure determination of membrane protein–ligand complexes using microcrystals of various native-source and recombinant P-type ATPase complexes is demonstrated. The data reveal the binding sites of a variety of ligands, including lipids and inhibitors such as the hallmark P-type ATPase inhibitor orthovanadate. By analyzing the resolution dependence of ligand densities and overall model qualities, SFX data quality metrics as well as suitable refinement procedures are discussed. Even at relatively low resolution and multiplicity, the identification of ligands can be demonstrated. This makes SFX a useful tool for ligand screening and thus for unravelling the molecular mechanisms of biologically active proteins.

  20. Structural studies of P-type ATPase-ligand complexes using an X-ray free-electron laser.

    Science.gov (United States)

    Bublitz, Maike; Nass, Karol; Drachmann, Nikolaj D; Markvardsen, Anders J; Gutmann, Matthias J; Barends, Thomas R M; Mattle, Daniel; Shoeman, Robert L; Doak, R Bruce; Boutet, Sébastien; Messerschmidt, Marc; Seibert, Marvin M; Williams, Garth J; Foucar, Lutz; Reinhard, Linda; Sitsel, Oleg; Gregersen, Jonas L; Clausen, Johannes D; Boesen, Thomas; Gotfryd, Kamil; Wang, Kai-Tuo; Olesen, Claus; Møller, Jesper V; Nissen, Poul; Schlichting, Ilme

    2015-07-01

    Membrane proteins are key players in biological systems, mediating signalling events and the specific transport of e.g. ions and metabolites. Consequently, membrane proteins are targeted by a large number of currently approved drugs. Understanding their functions and molecular mechanisms is greatly dependent on structural information, not least on complexes with functionally or medically important ligands. Structure determination, however, is hampered by the difficulty of obtaining well diffracting, macroscopic crystals. Here, the feasibility of X-ray free-electron-laser-based serial femtosecond crystallography (SFX) for the structure determination of membrane protein-ligand complexes using microcrystals of various native-source and recombinant P-type ATPase complexes is demonstrated. The data reveal the binding sites of a variety of ligands, including lipids and inhibitors such as the hallmark P-type ATPase inhibitor orthovanadate. By analyzing the resolution dependence of ligand densities and overall model qualities, SFX data quality metrics as well as suitable refinement procedures are discussed. Even at relatively low resolution and multiplicity, the identification of ligands can be demonstrated. This makes SFX a useful tool for ligand screening and thus for unravelling the molecular mechanisms of biologically active proteins. PMID:26175901

  1. Near-surface density profiling of Fe ion irradiated Si (100) using extremely asymmetric x-ray diffraction by variation of the wavelength

    International Nuclear Information System (INIS)

    In this work, we report on correlations between surface density variations and ion parameters during ion beam-induced surface patterning process. The near-surface density variations of irradiated Si(100) surfaces were investigated after off-normal irradiation with 5 keV Fe ions at different fluences. In order to reduce the x-ray probing depth to a thickness below 5 nm, the extremely asymmetrical x-ray diffraction by variation of wavelength was applied, exploiting x-ray refraction at the air-sample interface. Depth profiling was achieved by measuring x-ray rocking curves as function of varying wavelengths providing incidence angles down to 0°. The density variation was extracted from the deviations from kinematical Bragg angle at grazing incidence angles due to refraction of the x-ray beam at the air-sample interface. The simulations based on the dynamical theory of x-ray diffraction revealed that while a net near-surface density decreases with increasing ion fluence which is accompanied by surface patterning, there is a certain threshold of ion fluence to surface density modulation. Our finding suggests that the surface density variation can be relevant with the mechanism of pattern formation.

  2. X-Ray Absorption Fine Structure Investigation of Copper(II) Mixed Ligand Complexes with Pyridinedicarboxylic Acid as Primary Ligand

    Science.gov (United States)

    Dar, D. Ah.; Gaur, A.; Soni, B.; Shrivastava, B. D.; Prasad, J.; Srivastava, K.; Jha, S. N.; Bhattacharyya, D.

    2015-05-01

    The X-ray absorption fine structure (XAFS) spectra at the K-edge of the copper complexes Cu(PDC)(Mim)3 H2O ( 1) and Cu(PDC)2(EA)2H2O ( 2) (where PDC - Pyridine-2,3-dicarboxylic acid, Mim - 2-methylimidazole, and EA - ethyl acetate) have been investigated. The experimental extended X-ray absorption fine structure data of complex 1 have been analyzed by fitting the theoretical model generated from its own crystallographic data. The crystallographic data for complex 2 are not available. It has been found by comparing the intensity of the pre-edge peaks and X-ray absorption near edge structure features of complexes 1 and 2 that both complexes possess square pyramidal geometry around the copper centers and thus complex 2 is analogous to complex 1. Hence, the theoretical model generated for complex 1 has been fitted to the experimental EXAFS data of complex 2 to determine the structural parameters of complex 2. The coordination geometry of both complexes has been depicted. Further, the chemical shifts have been used to determine the oxidation state as well as to estimate the effective nuclear charge on the copper atom.

  3. Wake monochromator in asymmetric and symmetric Bragg and Laue geometry for self-seeding the European X-ray FEL

    Energy Technology Data Exchange (ETDEWEB)

    Geloni, Gianluca [European XFEL GmbH, Hamburg (Germany); Kocharyan, Vitali; Saldin, Evgeni; Serkez, Svitozar; Tolkiehn, Martin [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)

    2013-01-15

    We discuss the use of self-seeding schemes with wake monochromators to produce TW power, fully coherent pulses for applications at the dedicated bio-imaging beamline at the European X-ray FEL, a concept for an upgrade of the facility beyond the baseline previously proposed by the authors. We exploit the asymmetric and symmetric Bragg and Laue reflections (sigma polarization) in diamond crystal. Optimization of the bio-imaging beamline is performed with extensive start-to-end simulations, which also take into account effects such as the spatio-temporal coupling caused by the wake monochromator. The spatial shift is maximal in the range for small Bragg angles. A geometry with Bragg angles close to {pi}/2 would be a more advantageous option from this viewpoint, albeit with decrease of the spectral tunability. We show that it will be possible to cover the photon energy range from 3 keV to 13 keV by using four different planes of the same crystal with one rotational degree of freedom.

  4. Crystallization and preliminary X-ray diffraction analysis of kanamycin-binding β-lactamase in complex with its ligand

    International Nuclear Information System (INIS)

    Recombinant BlaKr has been cocrystallized with kanamycin. A complete data set has been collected to 1.67 Å resolution using synchrotron radiation. TEM-1 β-lactamase is a highly efficient enzyme that is involved in bacterial resistance against β-lactam antibiotics such as penicillin. It is also a robust scaffold protein which can be engineered by molecular-evolution techniques to bind a variety of targets. One such β-lactamase variant (BlaKr) has been constructed to bind kanamycin (kan) and other aminoglycoside antibiotics, which are neither substrates nor ligands of native β-lactamases. In addition to recognizing kan, BlaKr activity is up-regulated by its binding via an activation mechanism which is not yet understood at the molecular level. In order to fill this gap, determination of the structure of the BlaKr–kan complex was embarked upon. A crystallization condition for BlaKr–kan was identified using high-throughput screening, and crystal growth was further optimized using streak-seeding and hanging-drop methods. The crystals belonged to the orthorhombic space group P212121, with unit-cell parameters a = 47.01, b = 72.33, c = 74.62 Å, and diffracted to 1.67 Å resolution using synchrotron radiation. The X-ray structure of BlaKr with its ligand kanamycin should provide the molecular-level details necessary for understanding the activation mechanism of the engineered enzyme

  5. Crystal structure determinations of macrocyclic ligands, monomeric, trimeric and tetrameric phosphazenes by x-ray diffraction

    International Nuclear Information System (INIS)

    In this study, the crystal structures of the following macrocyciic Schiff base iigandstogether with the monomeric, trimeric and tetrameric phosphazene derivatives are determined by the single crystal X-ray diffraction method. In structure solutions; the intensity data collected on the Enraf-Nonius CAD4 diffractometer for the specified crystals, are processed by MolEN and SHELXS97 and SHELXL97 crystal structure determination and refinement programs incorporated in the WinGX package for the personal computers. The intra-inter molecular interactions are determined by PARST97. The molecular diagrams and figures are drawn by CHEMWIND and ORTEP3 programs. I) (C30H2-8N2O5), 1,5-Di[N-2-oxyphenyl-salicylidene]-3-oxapentane II) (C20H26N202), 2/6-Dioxa-14, 18-diazatricyclo = [18,4,0,0''7'',''1''2]-tetracosa-7,9,11,20,22,24(1 )-hexaene III) (C22H26N2O3), 3,4,6,7,15,16,17,18,19,20,21,27-Dodecahydro-2,5,8-trioxa-16, 20-diazatricyclo (20.4.1''1''6'',''2''00.0''9'',''1''4)heptacosa-9,11,13,22,24,26(1)-hexaene IV) (C21H26N2O3), 3,4,6,7,15,16,17,18,19,20,21-Undecahydro-2,5,6-trioxa-16,20-diaza tricyclo (20.4.0.0''9'',''1''4) hexacosa-9,11,13,22,24,26(1)-hexaene V) (C31H55N2O13P3), 15,21-Bis(diethoxyphosphinoyl)-2,,5,8-trioxa-16,20 diaztri cyclo (20.4.0.0''9'',''1''4) hexacosa-9,11,13,22,24,26(1)-hexaene-Ethylphosphonic Acid-Water (1/1/1) VI) (C23H34N2O9P2.2H2O), 15,21-Bis{2-((hydroxy)(methoxy)phosphoryl))}-2,5,8-trioxa-16, 20-diazatricyclo (20.4.0.0''9'',''1''4) hexacosa-9,11,13,22,24,26(1)-hexaene-Water(1/2) VII) (C13H8Cl4N5O6P3), 2,4-(2,2''2-Methylenebis (4-nitrophenoxy))-2,4,6,6-tetrachlorocyclo-2λ''5, 4λ''5, 6λ''5-triphosphazatriene (ansa) VIII) (C9H11N3OP3Cl5), 2,4,4,6,6-Pentachloro-2-(2,4,6-trimethylphenoxy) cyclo-2λ''5, 4λ''5, 6λ''5 triphosphazatriene IX) (C45H55NO6P2), N-(Bis(2,4,6-trimethylphenoxy) phosphinoyl) -P,P,P-tris(2,4,6-trimethyl-phenoxy) phosphazene X) (C30H76N2P4), trans-2,6-Bis(n-propylamino)-2,4,4,6,8,8-hexa-tert-butylamino cyclo-2λ5, 4λ5, 6λ5,8λ5

  6. Near-infrared photoluminescence and ligand K-edge x-ray absorption spectroscopies of AnO2Cl42-(An:u, NP, Pu)

    Energy Technology Data Exchange (ETDEWEB)

    Wilkerson, Marianne P [Los Alamos National Laboratory; Berg, John M [Los Alamos National Laboratory; Clark, David L [Los Alamos National Laboratory; Conradson, Steven D [Los Alamos National Laboratory; Hobart, David E [Los Alamos National Laboratory; Kozimor, Stosh A [Los Alamos National Laboratory; Scott, Brian L [Los Alamos National Laboratory

    2008-01-01

    We have used photoluminescence and X-ray absorption spectroscopies to investigate electronic structures and metal-ligand bonding of a series of An02CI/ ' (An = U, Np, Pu) compounds. Specifically, we will discuss time-resolved near-infrared emission spectra of crystalline Cs2U(An)02C14 (An = Np and Pu) both at 23 K and 75 K, as well as chlorine Kedge X-ray absorption spectra ofCs2An02CI4 (An = U, Np).

  7. Extended X-ray absorption fine structure data analysis of copper (II) hydroxamic acid mixed ligand complexes

    International Nuclear Information System (INIS)

    The X-ray absorption spectra of copper mixed ligand complexes, having hydroxamic acid as one of the ligands, have been recorded at the K-edge of copper at BL-8 Dispersive EXAFS beamline at the 2.5 GeV INDUS-2 Synchrotron, RRCAT, Indore, India. For the analysis of EXAFS data, crystallographic data of the complex or of its analog is required, which is not available. Hence, for the analysis of EXAFS data, theoretical EXAFS data of the studied complexes have been generated using the EXAFS equation employing computer software program Mathcad. Firstly, the experimental data has been processed using the computer program Athena to obtain the normalized absorption versus energy data. From the experimental EXAFS data, the phase shift parameter (an energy independent constant 5) has been computed using Lytle, Sayers and Stern's (LSS) method. The backscattering amplitude has been taken from the available theoretical tabulations and other parameters have been taken from crystallographic data of the copper metal. Fourier transforms of both the experimental and theoretical data have been computed, and the two Fourier transforms are found to agree with each other for all the complexes. The position of the first peak in the Fourier transform gives the value of the first shell bond length, which is shorter than the actual bond length as a result of energy dependence of the phase factor (δ(k)) in the sine function of the EXAFS equation. Since, the Fourier transform method and LSS method both are uncorrected for phase and other parameters of the EXAFS equation, the present method gives phase uncorrected bond length of the first coordination shell.

  8. Synthesis, characterization and thermal study of some transition metal complexes of an asymmetrical tetradentate Schiff base ligand

    Directory of Open Access Journals (Sweden)

    ACHUT S. MUNDE

    2010-03-01

    Full Text Available Complexes of Cu(II, Ni(II, Co(II, Mn(II and Fe(III with an asymmetric tetradentate Schiff base ligand derived from dehydroacetic acid, 4-methyl-o-phenylenediamine and salicylic aldehyde were synthesized and characterized by elemental analysis, conductometry, magnetic susceptibility, UV–Vis, IR, 1H-NMR spectroscopy, X-ray diffraction analysis of powdered samples and thermal analysis, and screened for antimicrobial activity. The IR spectral data suggested that the ligand behaves as a dibasic tetadentate ligand towards the central metal ion with an ONNO donor atoms sequence. From the microanalytical data, the stoichiometry of the complexes 1:1 (metal:ligand was found. The physico-chemical data suggested square planar geometry for the Cu(II and Ni(II complexes and octahedral geometry for the Co(II, Mn(II and Fe(III complexes. The thermal behaviour (TGA/DTA of the complexes was studied and kinetic parameters were determined by Horowitz–Metzger and Coats–Redfern methods. The powder X-ray diffraction data suggested a monoclinic crystal system for the Co(II, Mn(II and Fe(III complexes. The ligand and their metal complexes were screened for antibacterial activity against Staphylococcus aureus and Escherichia coli and fungicidal activity against Aspergillus niger and Trichoderma viride.

  9. Solution small-angle x-ray scattering as a screening and predictive tool in the fabrication of asymmetric block copolymer membranes

    KAUST Repository

    Dorin, Rachel Mika

    2012-05-15

    Small-angle X-ray scattering (SAXS) analysis of the diblock copolymer poly(styrene-b-(4-vinyl)pyridine) in a ternary solvent system of 1,4-dioxane, tetrahydrofuran, and N,N-dimethylformamide, and the triblock terpolymer poly(isoprene-b-styrene-b-(4-vinyl)-pyridine) in a binary solvent system of 1,4-dioxane and tetrahydrofuran, reveals a concentration-dependent onset of ordered structure formation. Asymmetric membranes fabricated from casting solutions with polymer concentrations at or slightly below this ordering concentration possess selective layers with the desired nanostructure. In addition to rapidly screening possible polymer solution concentrations, solution SAXS analysis also predicts hexagonal and square pore lattices of the final membrane surface structure. These results suggest solution SAXS as a powerful tool for screening casting solution concentrations and predicting surface structure in the fabrication of asymmetric ultrafiltration membranes from self-assembled block copolymers. (Figure presented) © 2012 American Chemical Society.

  10. Characteristic Ligand-Induced Crystal Forms of HIV-1 Protease Complexes: A Novel Discovery of X-Ray Crystallography

    International Nuclear Information System (INIS)

    Mixtures of saquinavir (SQV) and ritonavir (RTV) were cocrystallized with HIV-1 protease (PR) in an attempt to compare their relative potencies using a crystallographic approach and factors responsible for the respective crystal forms obtained were examined. The mixture ratio of the SQV/RTV was in the range of 1:1 to 1:50 with increasing concentration of dimethyl sulphoxide (DMSO) used. Two crystal forms of PR complexes were obtained. At concentrations of 0.8 and 1.2 % DMSO using 1:1 and 1:15 ratios of SQV/RTV, the crystal form was monoclinic while increasing the concentration of DMSO to 3.2 and 5.0% using 1:15 and 1:50 ratios of SQV/RTV, the orthorhombic crystal form was obtained. The high resolution X-ray crystal structures of the PR/ inhibitor complexes reveal that crystal forms with respective space groups are dependent on the occupancy of either SQV or RTV in the active site of the PR. The occupancy of either of the PR inhibitors in the active site of PR has interestingly demonstrated unique cooperativity effects in crystallization of protein-ligand complexes. The crystal forms obtained were also related to the concentration of DMSO and ammonium sulphate in crystallization, and storage conditions of purified PR. Surprisingly, the relative occupancies of these inhibitors in the active site suggested a competition between the two inhibitors which were not inhibition constants related. Analysis of the structures in both crystal forms show no difference in DMSO content but at higher concentration of DMSO (3.2 - 5.0%) in the orthorhombic crystal forms, there were protein-sulphate interactions which were absent in the monoclinic forms with lower concentration (0.8 - 1.2%) of DMSO. This work has clearly demonstrated that there is cooperativity in crystallization and the conditions of crystallization influence specific intermolecular contacts in crystal packing (crystal form). (author)

  11. X-ray Crystal Structure of the Novel Enhanced-Affinity Glucocorticoid Agonist Fluticasone Furoate in the Glucocorticoid Receptor−Ligand Binding Domain

    Energy Technology Data Exchange (ETDEWEB)

    Biggadike, Keith; Bledsoe, Randy K.; Hassell, Anne M.; Kirk, Barrie E.; McLay, Iain M.; Shewchuk, Lisa M.; Stewart, Eugene L. (GSKNC); (GSK)

    2008-07-08

    An X-ray crystal structure is reported for the novel enhanced-affinity glucocorticoid agonist fluticasone furoate (FF) in the ligand binding domain of the glucocorticoid receptor. Comparison of this structure with those of dexamethasone and fluticasone propionate shows the 17{alpha} furoate ester to occupy more fully the lipophilic 17{alpha} pocket on the receptor, which may account for the enhanced glucocorticoid receptor binding of FF.

  12. Strain evolution in Si substrate due to implantation of MeV ion observed by extremely asymmetric x-ray diffraction

    International Nuclear Information System (INIS)

    We studied the strain introduced in a Si(111) substrate due to MeV ion implantation using extremely asymmetric x-ray diffraction and measured the rocking curves of asymmetrical 113 diffraction for the Si substrates implanted with a 1.5 MeV Au2+ ion at fluence values of 1x1013, 5x1013, and 1x1014/cm2. The measured curves consisted of a bulk peak and accompanying subpeak with an interference fringe. The positional relationship of the bulk peak to the subpeak and the intensity variation of those peaks with respect to the wavelengths of the x rays indicated that crystal lattices near the surface were strained; the lattice spacing of surface normal (111) planes near the surface was larger than that of the bulk. Detailed strain profiles along the depth direction were successfully estimated using a curve-fitting method based on Darwin's dynamical diffraction theory. Comparing the shapes of resultant strain profiles, we found that a strain evolution rapidly occurred within a depth of ∼300 nm at fluence values between 1x1013 and 5x1013/cm2. This indicates that formation of the complex defects progressed near the surface when the fluence value went beyond a critical value between 1x1013 and 5x1013/cm2 and the defects brought a large strain to the substrate.

  13. Modified nucleosides and oligonucleotides as ligands for asymmetric reactions

    OpenAIRE

    Nuzzolo, Marzia

    2010-01-01

    Development of chiral ligands capable of achieving high selectivity for various asymmetric catalytic reactions has been an important aim of both academia and industry. Nature is capable to selectively catalyze chemical reactions by using enzymes. An ideal catalyst would combine the selectivity of nature and the reactivity of man-made catalysts based on transition metal complexes. The two biomolecules chosen to achieve this are DNA and PNA. DNA is a chiral molecule with high binding selectivit...

  14. Note: An X-ray powder diffractometer with a wide scattering-angle range of 72° using asymmetrically positioned one-dimensional detectors

    Energy Technology Data Exchange (ETDEWEB)

    Katsuya, Yoshio; Tanaka, Masahiko [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science (NIMS), 1-1-1 Kouto, Sayo, Hyogo 679-5148 (Japan); Song, Chulho [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science (NIMS), 1-1-1 Kouto, Sayo, Hyogo 679-5148 (Japan); Global Research Center for Environment and Energy based Nanomaterials Science (GREEN), Lithium Air Battery Specially Promoted Research Team, NIMS, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Ito, Kimihiko; Kubo, Yoshimi [Global Research Center for Environment and Energy based Nanomaterials Science (GREEN), Lithium Air Battery Specially Promoted Research Team, NIMS, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Sakata, Osami, E-mail: SAKATA.Osami@nims.go.jp [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science (NIMS), 1-1-1 Kouto, Sayo, Hyogo 679-5148 (Japan); Global Research Center for Environment and Energy based Nanomaterials Science (GREEN), Lithium Air Battery Specially Promoted Research Team, NIMS, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Synchrotron X-ray Group, Quantum Beam Unit, NIMS, 1-1-1 Kouto, Sayo, Hyogo 679-5148 (Japan)

    2016-01-15

    An X-ray powder diffractometer has been developed for a time-resolved measurement without the requirement of a scattering angle (2θ) scan. Six one-dimensional detector modules are asymmetrically arranged in a vertical line at a designed distance of 286.5 mm. A detector module actually covers a diffraction angle of about 12° with an angular resolution of 0.01°. A diffracted intensity pattern is simultaneously recorded in a 2θ angular range from 1.63° to 74.37° in a “one shot” measurement. We tested the performance of the diffractometer with reference CeO{sub 2} powders and demonstrated diffraction measurements from an operating lithium-air battery.

  15. Note: An X-ray powder diffractometer with a wide scattering-angle range of 72° using asymmetrically positioned one-dimensional detectors

    Science.gov (United States)

    Katsuya, Yoshio; Song, Chulho; Tanaka, Masahiko; Ito, Kimihiko; Kubo, Yoshimi; Sakata, Osami

    2016-01-01

    An X-ray powder diffractometer has been developed for a time-resolved measurement without the requirement of a scattering angle (2θ) scan. Six one-dimensional detector modules are asymmetrically arranged in a vertical line at a designed distance of 286.5 mm. A detector module actually covers a diffraction angle of about 12° with an angular resolution of 0.01°. A diffracted intensity pattern is simultaneously recorded in a 2θ angular range from 1.63° to 74.37° in a "one shot" measurement. We tested the performance of the diffractometer with reference CeO2 powders and demonstrated diffraction measurements from an operating lithium-air battery.

  16. Note: An X-ray powder diffractometer with a wide scattering-angle range of 72° using asymmetrically positioned one-dimensional detectors

    International Nuclear Information System (INIS)

    An X-ray powder diffractometer has been developed for a time-resolved measurement without the requirement of a scattering angle (2θ) scan. Six one-dimensional detector modules are asymmetrically arranged in a vertical line at a designed distance of 286.5 mm. A detector module actually covers a diffraction angle of about 12° with an angular resolution of 0.01°. A diffracted intensity pattern is simultaneously recorded in a 2θ angular range from 1.63° to 74.37° in a “one shot” measurement. We tested the performance of the diffractometer with reference CeO2 powders and demonstrated diffraction measurements from an operating lithium-air battery

  17. Theoretical calculations of X-ray absorption spectra of a copper mixed ligand complex using computer code FEFF9

    International Nuclear Information System (INIS)

    The terms X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) refer, respectively, to the structure in the X-ray absorption spectrum at low and high energies relative to the absorption edge. Routine analysis of EXAFS experiments generally makes use of simplified models and several many-body parameters, e.g. mean free paths, many-body amplitude factors, and Debye-Waller factors, as incorporated in EXAFS analysis software packages like IFEFFIT which includes Artemis. Similar considerations apply to XANES, where the agreement between theory and experiment is often less satisfactory. The recently available computer code FEFF9 uses the real-space Green's function (RSGF) approach to calculate dielectric response over a broad spectrum including the dominant low-energy region. This code includes improved treatments of many-body effects such as inelastic losses, core-hole effects, vibrational amplitudes, and the extension to full spectrum calculations of optical constants including solid state effects. In the present work, using FEFF9, we have calculated the X-ray absorption spectrum at the K-edge of copper in a complex, viz., aqua (diethylenetriamine) (isonicotinato) copper(II), the crystal structure of which is unknown. The theoretical spectrum has been compared with the experimental spectrum, recorded by us at the XAFS beamline 11.1 at ELETTRA synchrotron source, Italy, in both XANES and EXAFS regions.

  18. Crystallization and preliminary X-ray crystallographic study of the extracellular domain of the 4-1BB ligand, a member of the TNF family

    Energy Technology Data Exchange (ETDEWEB)

    Byun, Jung-Sue; Kim, Dong-Uk [Department of Biology, Yonsei University, Seoul 120-749 (Korea, Republic of); Ahn, Byungchan; Kwon, Byoung Se [Immunomodulation Research Center, Ulsan University, Ulsan 680-749 (Korea, Republic of); Cho, Hyun-Soo, E-mail: hscho8@yonsei.ac.kr [Department of Biology, Yonsei University, Seoul 120-749 (Korea, Republic of)

    2006-01-01

    The extracellular domain of the 4-1BB ligand fused with glutathione-S-transferase was expressed in Escherichia coli (Origami) and purified by using affinity and ion-exchange column chromatographic methods. Crystals of the 4-1BB ligand were obtained at 290 K by the hanging-drop vapour-diffusion method. The 4-1BB ligand, a member of the tumour necrosis factor (TNF) family, is an important co-stimulatory molecule that plays a key role in the clonal expansion and survival of CD8+ T cells. Signalling through binding of the 4-1BB ligand and 4-1BB has been reported to enhance CD8+ T-cell expansion and protect activated CD8+ T cells from death. The 4-1BB ligand is an integral protein expressed on activated antigen-presenting cells. The extracellular domain of the 4-1BB ligand fused with glutathione-S-transferase was expressed in Escherichia coli (Origami) and purified by using affinity and ion-exchange column chromatographic methods. Crystals of the 4-1BB ligand were obtained at 290 K by the hanging-drop vapour-diffusion method. X-ray diffraction data were collected from these crystals to 2.8 Å resolution and the crystals belong to space group C2, with unit-cell parameters a = 114.6, b = 73.8, c = 118.50 Å, β = 115.5°.

  19. Gas-phase and X-ray studies of branched ligands: Cu(II) coordination polymer formed by Nα, Nɛ, Nɛ-tris(cyanoethyl)- L-lysine

    Science.gov (United States)

    Janiszewska, Jolanta; Urbańczyk-Lipkowska, Zofia

    2006-05-01

    A small dendrimeric compound, Nα, Nɛ, Nɛ-tris(dicyanoethyl)- L-lysine—C 15H 23N 5O 2 ( 1) was synthesized and used for the construction of Cu(II) complex—[Cu(C 15H 23N 5O 2) 2(ClO 4) 2·H 2O] ( 3). In the gas-phase, the dimeric and trimeric clusters of 1, surrounding Na + core were observed. The aggregates with a complex structure were found for the mixtures of 1 and Cu(ClO 4) 2 at various ratios in ESI-MS experiments. The X-ray studies showed that a new 1D coordination polymer ( 3), connected by the Cu…N tbnd6 C coordination with the α- N-cyanoethyl group of ligand is formed in a solid-state. The structure contains penta-coordinated Cu(II) with the Cu-Cu separation 7.820(1)-7.927(1) Å. The Cu(II)-coordinated branched ligands form cavities where three perchlorate anions are encapsulated into the void space by the electrostatic and van der Waals interactions. The remaining three perchlorate anions are hydrogen-bonded to the ɛ-NH + groups. Thus, the polymeric structure shows properties postulated for dendrimers, where charged groups can be isolated by the non-polar branches from the outside environment. Both gas-phase and X-ray studies show predominance of the 2:1 aggregation pattern between ligand 1 and Cu 2+ atoms.

  20. Synthesis, characterization, single crystal X-ray determination, fluorescence and electrochemical studies of new dinuclear nickel(II) and oxovanadium(IV) complexes containing double Schiff base ligands

    Science.gov (United States)

    Shafaatian, Bita; Ozbakzaei, Zahra; Notash, Behrouz; Rezvani, S. Ahmad

    2015-04-01

    A series of new bimetallic complexes of nickel(II) and vanadium(IV) have been synthesized by the reaction of the new double bidentate Schiff base ligands with nickel acetate and vanadyl acetylacetonate in 1:1 M ratio. In nickel and also vanadyl complexes the ligands were coordinated to the metals via the imine N and enolic O atoms. The complexes have been found to possess 1:1 metals to ligands stoichiometry and the molar conductance data revealed that the metal complexes were non-electrolytes. The nickel and vanadyl complexes exhibited distorted square planar and square pyramidal coordination geometries, respectively. The emission spectra of the ligands and their complexes were studied in methanol. Electrochemical properties of the ligands and their metal complexes were also investigated in DMSO solvent at 150 mV s-1 scan rate. The ligands and metal complexes showed both quasi-reversible and irreversible processes at this scan rate. The Schiff bases and their complexes have been characterized by FT-IR, 1H NMR, UV/Vis spectroscopies, elemental analysis and conductometry. The crystal structure of the nickel complex has been determined by single crystal X-ray diffraction.

  1. Recent advances in catalytic asymmetric hydrogenation:Renaissance of the monodentate phosphorus ligands

    Institute of Scientific and Technical Information of China (English)

    GUO Hongchao; DING Kuiling; DAI Lixin

    2004-01-01

    The history for the development of chiral phosphorus ligands in catalytic asymmetric hydrogenation is briefly highlighted. This review focuses on the recent advances in the synthesis of the monodentate phosphorus ligands and their applications in catalytic asymmetric hydrogenation. The examples highlighted in this article clearly demonstrated the importance and advantages of monodentate phosphorus ligands, which had been ignored for 30 a and experienced a renaissance at the very beginning of this millennium, particularly in the area of asymmetric hydrogenation.

  2. Crystallization and preliminary X-ray analysis of the human androgen receptor ligand-binding domain with a coactivator-like peptide and selective androgen receptor modulators

    International Nuclear Information System (INIS)

    The human androgen receptor ligand-binding domain has been crystallized as a ternary complex with a coactivator-like undecapeptide and two different synthetic ligands. The ligand-binding domain of the human androgen receptor has been cloned, overproduced and crystallized in the presence of a coactivator-like 11-mer peptide and two different nonsteroidal ligands. The crystals of the two ternary complexes were isomorphous and belonged to space group P212121, with one molecule in the asymmetric unit. They diffracted to 1.7 and 1.95 Å resolution, respectively. Structure determination of these two complexes will help in understanding the mode of binding of selective nonsteroidal androgens versus endogenous steroidal ligands and possibly the origin of their tissue selectivity

  3. Severe Acute Respiratory Syndrome-Coronavirus Papain-Like Novel Protease Inhibitors: Design, Synthesis, Protein-Ligand X-ray Structure and Biological Evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Ghosh, Arun K.; Takayama, Jun; Rao, Kalapala Venkateswar; Ratia, Kiira; Chaudhuri, Rima; Mulhearn, Debbie C.; Lee, Hyun; Nichols, Daniel B.; Baliji, Surendranath; Baker, Susan C.; Johnson, Michael E.; Mesecar, Andrew D. (Purdue); (UC); (UIC)

    2012-02-21

    The design, synthesis, X-ray crystal structure, molecular modeling, and biological evaluation of a series of new generation SARS-CoV PLpro inhibitors are described. A new lead compound 3 (6577871) was identified via high-throughput screening of a diverse chemical library. Subsequently, we carried out lead optimization and structure-activity studies to provide a series of improved inhibitors that show potent PLpro inhibition and antiviral activity against SARS-CoV infected Vero E6 cells. Interestingly, the (S)-Me inhibitor 15h (enzyme IC{sub 50} = 0.56 {mu}M; antiviral EC{sub 50} = 9.1 {mu}M) and the corresponding (R)-Me 15g (IC{sub 50} = 0.32 {mu}M; antiviral EC{sub 50} = 9.1 {mu}M) are the most potent compounds in this series, with nearly equivalent enzymatic inhibition and antiviral activity. A protein-ligand X-ray structure of 15g-bound SARS-CoV PLpro and a corresponding model of 15h docked to PLpro provide intriguing molecular insight into the ligand-binding site interactions.

  4. Key role of the Lewis base position in asymmetric bifunctional catalysis: design and evaluation of a new ligand for chiral polymetallic catalysts.

    Science.gov (United States)

    Fujimori, Ikuo; Mita, Tsuyoshi; Maki, Keisuke; Shiro, Motoo; Sato, Akihiro; Furusho, Sanae; Kanai, Motomu; Shibasaki, Masakatsu

    2006-12-27

    New chiral ligands for asymmetric polymetallic catalysts were designed on the basis of the assumption that the higher-order assembly structure is stabilized by modifying the modular unit. The designed ligands 6 and 7 contained a scaffolding cyclohexane ring with a Lewis base phosphine oxide directly attached to the scaffold. A module in the polymetallic complex contains two metals per ligand, and a stable 6-, 5-, 5-membered fused chelation ring system should be generated. Synthesis of these ligands is simple and high yielding, using a catalytic dynamic kinetic resolution promoted by the Trost catalyst as a key step. Ligand function was assessed in a catalytic asymmetric ring-opening reaction of meso-aziridines with TMSCN, a useful reaction for the synthesis of optically active beta-amino acids. The Gd complex generated from Gd(OiPr)3 and the ligand was a highly active and enantioselective catalyst in this reaction. Enantioselectivity was reversed compared to the previously reported d-glucose-derived catalyst containing the same chirality of the individual module. ESI-MS analysis and X-ray crystallographic studies indicate that the assembly state of the modules in the polymetallic catalysts differs depending on the chiral ligand. The difference in the higher-order structure stems from a subtle change (one carbon) in the position of the Lewis base relative to the Gd metal. The change in the higher-order structure of the polymetallic complex led to a dramatic reversal of the enantioselectivity and increased catalyst activity. PMID:17177358

  5. A novel one-dimensional manganese(II) coordination polymer containing both dicyanamide and pyrazinamide ligands: Synthesis, spectroscopic investigations, X-ray studies and evaluation of biological activities

    Science.gov (United States)

    Tabrizi, Leila; Chiniforoshan, Hossein; McArdle, Patrick

    2015-03-01

    A novel 1D coordination polymer {[Mn(μ1,5-dca)2(PZA)2](PZA)2}n, 1, has been synthesized and characterized by single crystal X-ray crystallography. The coordination mode of dicyanamide (dca) and pyrazinamide (PZA) ligands was inferred by IR spectroscopy. The compound 1 was evaluated for in vitro antimycobacterial and antitumor activities. It demonstrated better in vitro activity against Mycobacterium tuberculosis than pyrazinamide and its MIC value was determined. Complex 1 was also screened for its in vitro antitumor activity towards LM3 and LP07 murine cancer cell lines. In addition, the antibacterial activity of complex 1 has been tested against Gram(+) and Gram(-) bacteria and it has shown promising broad range anti-bacterial activity.

  6. New chiral ligands in asymmetric catalysis. Application in stabilization of metal nanoparticles

    OpenAIRE

    Axet Martí, M. Rosa

    2006-01-01

    Thesis M. Rosa AxetThis thesis deals with the development and application of diphosphite ligands derived from carbohydrates to rhodium-catalysed asymmetric hydroformylation and hydrogenation reactions. The use of various carbohydrate derivative ligands as stabilisers of metal nanoparticles is also studied. The synthesis and the characterisation of the series of diphosphite ligands are described in Chapter 2. The results of the asymmetric hydroformylation of styrene and related vinyl arenes ar...

  7. Synthesis, X-ray, and Spectroscopic Study of Dissymmetric Tetrahedral Zinc(II) Complexes from Chiral Schiff Base Naphthaldiminate Ligands with Apparent Exception to the ECD Exciton Chirality.

    Science.gov (United States)

    Enamullah, Mohammed; Makhloufi, Gamall; Ahmed, Rifat; Joy, Baitul Alif; Islam, Mohammad Ariful; Padula, Daniele; Hunter, Howard; Pescitelli, Gennaro; Janiak, Christoph

    2016-07-01

    Bidentate enantiopure Schiff base ligands, (R or S)-N-1-(Ar)ethyl-2-oxo-1-naphthaldiminate (R- or S-N^O), diastereoselectively provide Λ- or Δ-chiral-at-metal four-coordinated Zn(R- or S-N^O)2 {Ar = C6H5; Zn-1R or Zn-1S and p-C6H4OMe; Zn-2R or Zn-2S}. Two R- or S-N^O-chelate ligands coordinate to the zinc(II) in a tetrahedral mode and induce Λ- or Δ-configuration at the zinc metal center. In the solid state, the R- or S-ligand diastereoselectively gives Λ- or Δ-Zn configuration, respectively, and forms enantiopure crystals. Single crystal structure determinations show two symmetry-independent molecules (A and B) in each asymmetric unit to give Z' = 2 structures. Electronic circular dichroism (ECD) spectra show the expected mirror image relationship resulting from diastereomeric excess toward the Λ-Zn for R-ligands and Δ-Zn for S-ligands in solution. ECD spectra are well reproduced by TDDFT calculations, while the application of the exciton chirality method, in the common point-dipole approximation, predicts the wrong sign for the long-wavelength couplet. A dynamic diastereomeric equilibrium (Λ vs Δ) prevails for both R- and S-ligand-metal complexes in solution, respectively, evidenced by (1)H NMR spectroscopy. Variable temperature (1)H NMR spectra show a temperature-dependent shift of the diastereomeric equilibrium and confirm Δ-Zn configuration (for S-ligand) to be the most stable one and favored at low temperature. DSC analyses provide quantitative diastereomeric excess in the solid state for Zn-2R and Zn-2S, which is comparable to the results of solution studies. PMID:27295327

  8. Rational design of cyclopropane-based chiral PHOX ligands for intermolecular asymmetric Heck reaction

    Directory of Open Access Journals (Sweden)

    Marina Rubina

    2014-07-01

    Full Text Available A novel class of chiral phosphanyl-oxazoline (PHOX ligands with a conformationally rigid cyclopropyl backbone was synthesized and tested in the intermolecular asymmetric Heck reaction. Mechanistic modelling and crystallographic studies were used to predict the optimal ligand structure and helped to design a very efficient and highly selective catalytic system. Employment of the optimized ligands in the asymmetric arylation of cyclic olefins allowed for achieving high enantioselectivities and significantly suppressing product isomerization. Factors affecting the selectivity and the rate of the isomerization were identified. It was shown that the nature of this isomerization is different from that demonstrated previously using chiral diphosphine ligands.

  9. Joint x-ray

    Science.gov (United States)

    X-ray - joint; Arthrography; Arthrogram ... x-ray technologist will help you position the joint to be x-rayed on the table. Once in place, pictures are taken. The joint may be moved into other positions for more ...

  10. Extended X- ray absorption fine structure study at the K-edge of copper in mixed ligand complexes having benzimidazole as one of the ligands

    Science.gov (United States)

    Hinge, V. K.; Joshi, S. K.; Nitin Nair, N.; Singh Verma, Vikram; Shrivastava, B. D.; Prasad, J.; Srivastava, K.

    2014-09-01

    Extended X-ray absorption fine structure (EXAFS) spectra have been studied at the K-edge of copper in some of its biologically important complexes, viz., [Cu(BzImH)4X2] and [Cu(BzIm)2], where X= Cl, Br, 1/2SO4, ClO4, NO3, and BzIm = Benzimidazolato anion. The spectra have been recorded using a bent crystal 0.4 m Cauchois-type transmission spectrograph. The positions of EXAFS maxima and minima have been used to determine the bond lengths in the complexes with the help of three different methods, namely, Levy's, Lytle's and Lytle, Sayers and Stern's (L.S.S.) methods. The phase uncorrected bond lengths have also been determined from Fourier transforms of the experimental spectra. The results obtained from these methods have been discussed and it has been found that the results obtained by L.S.S. method are comparable with the results obtained by Fourier transformation method and that these two methods give phase uncorrected bond lengths.

  11. Introduction to the structures determination methods using X-ray diffraction in monocrystals: application to some lanthanides and transition metals complexes with organic ligands

    International Nuclear Information System (INIS)

    The crystal structure of the complexes Ln (Cl O4)3.6[P O N H2 (C6 H5) 2] where Ln = Eu, La, Cu[N H2 (C H3)2 C C O2]2, Ni Br2.4[As O(C6 H5)3]. 8 H2 O (green), Ni Br2.4[As O (C6 H5)3]. 1,5 (C H3 C6 H5).H2 O (orange) and of the ligand P O N H2 (C6 H5)2 have been determined by X-ray diffraction. The complexes involving lanthanide ions refined to final R factors of R(Eu) = 0.125 and R(La) = 0.133 and the following main features were found: the crystal system is cubic; the cation is coordinated to six ligand oxygens in octahedral (Eu) and trigonal anti prismatic (La) configurations with the rate earths on positions of high symmetry (23 for Eu and 3-bar for La); the rest of the structures shows different degrees of disorder. In the light of the geometrical configuration, the occurrence of a strong band 5 DO-7 F2 in the fluorescence spectrum of the Eu complex, forbidden on symmetry grounds, is interpreted as a consequence of vibronic coupling. A splitting of the infrared νP=0 band in the La complex is attributed to the presence of P = 0 groups non-equivalently bonded to the rare earth due to the disorder of this atom. (author)

  12. X-Ray Emission from an Asymmetric Blast Wave and a Massive White Dwarf in the Gamma Ray Emitting Nova V407 CYG

    Science.gov (United States)

    Nelson, Thomas; Donato, Davide; Mukai, Koji; Sokoloski, Jennifer; Chomiuk, Laura

    2012-01-01

    Classical nova events in symbiotic stars, although rare, offer a unique opportunity to probe the interaction between ejecta and a dense environment in stellar explosions. In this work, we use X-ray data obtained with Swift and Suzaku during the recent classical nova outburst in V407 Cyg to explore such an interaction. We find evidence of both equilibrium and non-equilibrium ionization plasmas at the time of peak X-ray brightness, indicating a strong asymmetry in the density of the emitting region. Comparing a simple model to the data, we find that the X-ray evolution is broadly consistent with nova ejecta driving a forward shock into the dense wind of the Mira companion. We detect a highly absorbed soft X-ray component in the spectrum during the first 50 days of the outburst that is consistent with supersoft emission from the nuclear burning white dwarf. The high temperature and short turn off time of this emission component, in addition to the observed breaks in the optical and UV lightcurves, indicate that the white dwarf in the binary is extremely massive. Finally, we explore the connections between the X-ray and GeV-ray evolution, and propose that the gamma ray turn-off is due to the stalling of the forward shock as the ejecta reach the red giant surface.

  13. Chest x-ray

    Science.gov (United States)

    Chest radiography; Serial chest x-ray; X-ray - chest ... You stand in front of the x-ray machine. You will be told to hold your breath when the x-ray is taken. Two images are usually taken. You will ...

  14. X-ray Echo Spectroscopy

    Science.gov (United States)

    Shvyd'ko, Yuri

    2016-02-01

    X-ray echo spectroscopy, a counterpart of neutron spin echo, is being introduced here to overcome limitations in spectral resolution and weak signals of the traditional inelastic x-ray scattering (IXS) probes. An image of a pointlike x-ray source is defocused by a dispersing system comprised of asymmetrically cut specially arranged Bragg diffracting crystals. The defocused image is refocused into a point (echo) in a time-reversal dispersing system. If the defocused beam is inelastically scattered from a sample, the echo signal acquires a spatial distribution, which is a map of the inelastic scattering spectrum. The spectral resolution of the echo spectroscopy does not rely on the monochromaticity of the x rays, ensuring strong signals along with a very high spectral resolution. Particular schemes of x-ray echo spectrometers for 0.1-0.02 meV ultrahigh-resolution IXS applications (resolving power >108 ) with broadband ≃5 - 13 meV dispersing systems are introduced featuring more than 103 signal enhancement. The technique is general, applicable in different photon frequency domains.

  15. X-ray echo spectroscopy

    CERN Document Server

    Shvyd'ko, Yuri

    2015-01-01

    X-ray echo spectroscopy, a counterpart of neutron spin-echo, is being introduced here to overcome limitations in spectral resolution and weak signals of the traditional inelastic x-ray scattering (IXS) probes. An image of a point-like x-ray source is defocused by a dispersing system comprised of asymmetrically cut specially arranged Bragg diffracting crystals. The defocused image is refocused into a point (echo) in a time-reversal dispersing system. If the defocused beam is inelastically scattered from a sample, the echo signal acquires a spatial distribution, which is a map of the inelastic scattering spectrum. The spectral resolution of the echo spectroscopy does not rely on the monochromaticity of the x-rays, ensuring strong signals along with a very high spectral resolution. Particular schemes of x-ray echo spectrometers for 0.1--0.02-meV ultra-high-resolution IXS applications (resolving power $> 10^8$) with broadband $\\simeq$~5--13~meV dispersing systems are introduced featuring more than $10^3$ signal e...

  16. Thoracic spine x-ray

    Science.gov (United States)

    Vertebral radiography; X-ray - spine; Thoracic x-ray; Spine x-ray; Thoracic spine films; Back films ... care provider's office. You will lie on the x-ray table in different positions. If the x-ray ...

  17. A High-Resolution X-Ray and Optical Study of SN1006: Asymmetric Expansion and Small-Scale Structure in a Type Ia Supernova Remnant

    Science.gov (United States)

    Winkler, P. Frank; Williams, Brian J.; Reynolds, Stephen P.; Petre, Robert; Long, Knox S.; Katsuda, Satoru; Hwang, Una

    2014-01-01

    We introduce a deep (670 ks) X-ray survey of the entire SN 1006 remnant from the Chandra X-Ray Observatory, together with a deep Ha image of SN 1006 from the 4 m Blanco telescope at CTIO. Comparison with Chandra images from 2003 gives the first measurement of the X-ray proper motions around the entire periphery, carried out over a 9 yr baseline. We find that the expansion velocity varies significantly with azimuth. The highest velocity of approx.7400 km/s (almost 2.5 times that in the northwest (NW)) is found along the southeast (SE) periphery, where both the kinematics and the spectra indicate that most of the X-ray emission stems from ejecta that have been decelerated little, if at all. Asymmetries in the distribution of ejecta are seen on a variety of spatial scales. Si-rich ejecta are especially prominent in the SE quadrant, while O and Mg are more uniformly distributed, indicating large-scale asymmetries arising from the explosion itself. Neon emission is strongest in a sharp filament just behind the primary shock along the NWrim, where the pre-shock density is highest. Here the Ne is likely interstellar, while Ne within the shell may include a contribution from ejecta. Within the interior of the projected shell we find a few isolated "bullets" of what appear to be supernova ejecta that are immediately preceded by bowshocks seen in Ha, features that we interpret as ejecta knots that have reached relatively dense regions of the surrounding interstellar medium, but that appear in the interior in projection. Recent three-dimensional hydrodynamic models for Type Ia supernovae display small-scale features that strongly resemble the ones seen in X-rays in SN 1006; an origin in the explosion itself or from subsequent hydrodynamic instabilities both remain viable options. We have expanded the search for precursor X-ray emission ahead of a synchrotron-dominated shock front, as expected from diffusive shock acceleration theory, to numerous regions along both the

  18. Chest X-Ray

    Medline Plus

    Full Text Available ... the most commonly performed x-ray exams and use a very small dose of ionizing radiation to ... to your health. While a chest x-ray use a tiny dose of ionizing radiation, the benefit ...

  19. Dental x-rays

    Science.gov (United States)

    X-ray - teeth; Radiograph - dental; Bitewings; Periapical film; Panoramic film ... dentist's office. There are many types of dental x-rays. Some are: Bitewing Periapical Palatal (also called occlusal) ...

  20. X-ray (image)

    Science.gov (United States)

    X-rays are a form of ionizing radiation that can penetrate the body to form an image on ... will be shades of gray depending on density. X-rays can provide information about obstructions, tumors, and other ...

  1. X-ray apparatus

    International Nuclear Information System (INIS)

    A diagnostic x-ray device, readily convertible between conventional radiographic and tomographic operating modes, is described. An improved drive system interconnects and drives the x-ray source and the imaging device through coordinated movements for tomography

  2. Synthesis and Application of Chiral Spiro Cp Ligands in Rhodium-Catalyzed Asymmetric Oxidative Coupling of Biaryl Compounds with Alkenes.

    Science.gov (United States)

    Zheng, Jun; Cui, Wen-Jun; Zheng, Chao; You, Shu-Li

    2016-04-27

    The vastly increasing application of chiral Cp ligands in asymmetric catalysis results in growing demand for novel chiral Cp ligands. Herein, we report a new class of chiral Cp ligands based on 1,1'-spirobiindane, a privileged scaffold for chiral ligands and catalysts. The corresponding Rh complexes are shown to be excellent catalysts in asymmetric oxidative coupling reactions, providing axially chiral biaryls in 19-97% yields with up to 98:2 er. PMID:27070297

  3. A High-Resolution X-Ray and Optical Study of SN 1006: Asymmetric Expansion and Small-Scale Structure in a Type Ia Supernova Remnant

    CERN Document Server

    Winkler, P Frank; Petre, Stephen P Reynolds Robert; Long, Knox S; Katsuda, Satoru; Hwang, Una

    2013-01-01

    We introduce a deep (670 ks) X-ray survey of the SN1006 remnant from Chandra, plus a deep H-alpha image from the 4m telescope at CTIO. Comparison with Chandra images from 2003 gives the first measurement of X-ray proper motions around the entire rim. We find that the expansion velocity varies significantly with azimuth: the highest velocity of ~7400 km/s (almost 2.5 times that in the NW) is found along the SE rim, where both kinematics and spectra indicate that most of the X-rays stem from undecelerated ejecta. Asymmetries in the distribution of ejecta are seen on a variety of spatial scales. Si-rich ejecta are especially prominent in the SE quadrant, while O and Mg are more uniformly distributed, indicating large-scale asymmetries arising from the explosion itself. Ne emission is strongest in a sharp filament just behind the primary shock along the NW rim, where the preshock density is highest. Here the Ne is likely interstellar, while Ne within the shell may include a contribution from ejecta. Within the in...

  4. X-Rays

    Science.gov (United States)

    X-rays are a type of radiation called electromagnetic waves. X-ray imaging creates pictures of the inside of your ... different amounts of radiation. Calcium in bones absorbs x-rays the most, so bones look white. Fat and ...

  5. Chest X-Ray

    Medline Plus

    Full Text Available ... by: Image/Video Gallery Your radiologist explains chest x-ray. Transcript Welcome to Radiology Info dot org! Hello, ... you about chest radiography also known as chest x-rays. Chest x-rays are the most commonly performed ...

  6. X-Ray Imaging

    Science.gov (United States)

    ... Brain Surgery Imaging Clinical Trials Basics Patient Information X-Ray Imaging Print This Page X-ray imaging is perhaps the most familiar type of imaging. Images produced by X-rays are due to the different absorption rates of ...

  7. p-Tolylimido rhenium(v) complexes with phenolate-based ligands: synthesis, X-ray studies and catalytic activity in oxidation with tert-butylhydroperoxide.

    Science.gov (United States)

    Gryca, Izabela; Machura, Barbara; Małecki, Jan Grzegorz; Kusz, Joachim; Shul'pina, Lidia S; Ikonnikov, Nikolay S; Shul'pin, Georgiy B

    2016-01-01

    The reactions of mer-[Re(p-NTol)X3(PPh3)2] (X = Cl, Br) with chelating phenolate-based ligands (2-(2-hydroxy-5-methylphenyl)benzotriazole (HL(1)), 2-(2-hydroxyphenyl)benzothiazole (HL(2)) or 2-(2-hydroxyphenyl)benzoxazole (HL(3))) afforded a series of p-tolylimido rhenium(v) complexes cis- or trans-(X,X)-[Re(p-NTol)X2(L)(PPh3)]·yMeCN (where X = Cl, Br; L = L(1), L(2), L(3) and y = 0-2) and [Re(p-NTol)X(L)(PPh3)2]Z·pPPh3 (where X = Cl, Br; Z = ReO4, PF6; L = L(1), L(2), L(3) and p = 0 or 1). The reported compounds were characterized by elemental analysis, FT-IR, NMR ((1)H, (13)C and (31)P) and X-ray crystallography. Interestingly, the halide ions of [Re(p-NTol)Cl2(L(1))(PPh3)]·MeCN (1) and [Re(p-NTol)Cl2(L(2))(PPh3)]·2MeCN (3) are in cis relative dispositions, whereas the complexes [Re(p-NTol)Br2(L)(PPh3)] (L(1) for 2, L(2) for 4 and L(3) for 6) and [Re(p-NTol)Cl2(L(3))(PPh3)] (5) were found to be trans-(X,X) isomers. The compounds [Re(p-NTol)X(L)(PPh3)2](PF6) (X = Cl, Br; L = L(1) and L(2)) and [Re(p-NTol)X(L(3))(PPh3)2](PF6)·PPh3 (X = Cl, Br) have been tested in oxidative catalysis. A few compounds exhibited very good catalytic properties in oxidation of alcohols with tert-BuOOH (TBHP) in acetonitrile solution at moderate temperatures. Complex [Re(p-NTol)Cl(L(2))(PPh3)2]PF6 (13) is the catalyst of choice for oxidation of 1-phenylethanol to acetophenone (in 80% yield; turnover number attained 290 after 30 h) and cyclooctanol to cyclooctanone (in 88% yield). Notably lower activity has been found in the oxidation of alkanes with TBHP. Product distribution in the oxidation of methylcyclohexane indicates some steric hindrance around the reaction center. PMID:26618894

  8. X-rays from jets and lobes

    Science.gov (United States)

    Feigelson, E. D.

    1983-01-01

    The current status of X-ray detections (and non-detections) of radio jets and lobes is presented. High resolution images obtained with the Einstein Observatory reveal X-ray emission associated with jet and lobe components of Virgo A, Centaurus A, 3C273, and possibly other radio structures. The Vir A and Cen A jet emission is probably s ynchrotron in origin, requiring in situ particle acceleration to extremely high energies. Inverse Compton emission is the likely cause of asymmetrical X-ray features in the halo of Vir A, supporting the assumption of equipartition.

  9. X-rays from jets and lobes

    International Nuclear Information System (INIS)

    The current status of X-ray detections (and non-detections) of radio jets and lobes is reviewed. The author summarizes the findings and interpretation of several detections of jet and lobe X-ray emission made with the EINSTEIN observatory in Virgo A, Centaurus A, 3C273, and possibly other radio structures. The Vir A (=M27) and Cen A jet emission is probably synchrotron in origin, requiring in situ particle acceleration to extremely high energies. Inverse Compton emission is the likely cause of asymmetrical X-ray features in the halo of Vir A, supporting the assumption of equipartition. (Auth.)

  10. Rhodium-catalyzed asymmetric hydroformylation with Taddol-based IndolPhos ligands

    NARCIS (Netherlands)

    J. Wassenaar; B. de Bruin; J.N.H. Reek

    2010-01-01

    A small library of Taddol-based IndolPhos ligands 2a−g and their use in asymmetric hydroformylation (AHF) reactions are reported. Moderate to good enantioselectivities are obtained for styrene, vinyl acetate, and allyl cyanide up to 72%, 74%, and 63% ee, respectively. High b/l ratios are obtained, w

  11. X-Ray Polarimetry

    OpenAIRE

    Kaaret, Philip

    2014-01-01

    We review the basic principles of X-ray polarimetry and current detector technologies based on the photoelectric effect, Bragg reflection, and Compton scattering. Recent technological advances in high-spatial-resolution gas-filled X-ray detectors have enabled efficient polarimeters exploiting the photoelectric effect that hold great scientific promise for X-ray polarimetry in the 2-10 keV band. Advances in the fabrication of multilayer optics have made feasible the construction of broad-band ...

  12. Synthesis, characterization and crystal structure of four new asymmetric triazene ligands: An example of linear HII complex with H... secondary bonding interactions

    Indian Academy of Sciences (India)

    Mohammad Reza Melardi; Fatemeh Baber Shamsi Mogoii; Ayoob Babaii Sajirani; Jafar Attar Gharamaleki; Behrouz Notash; Mohammad Kazem Rofouei

    2015-12-01

    In this work, the asymmetric ligands [1-(phenyl)-3-(2-nitro-4-methylphenyl)]triazene (1), [1-(4-methylphenyl)-3-(2-nitro-4-methylphenyl)]triazene (2), [1-(4-ethylphenyl)-3-(2-nitro-4-methylphenyl)]triazene (3) and [1-(4-ethoxyphenyl)-3-(2-nitro-4-methylphenyl)]triazene (4), were synthesized. The reaction of the ligand (3) with HgCl2 in methanol resulted in the formation of the [HgL2] complex, (5). All compounds were characterized by means of CHN analysis, FT-IR, 1H NMR, 13C NMR spectroscopy. In addition, the crystal structures of the ligands (2) to (4) were investigated by single crystal X-ray analysis. In the solid state, all ligands exhibited trans conformation about the –N=N– double bond. The HgII complex (5) crystallized in monoclinic system with 2/ space group. The triazene ligand was found to be deprotonated prior to coordination and acts as monodentate ligand. The HgII which lies on inversion center (site symmetry $\\bar{1}$), is surrounded by two N atoms from L ligands forming a linear geometry. The other two Hg–N bonds are relatively longer and can only be regarded as weak secondary bonds. Also, Hg-3-arene -interactions are present in this compound. Hydrogen bonds, · · · and C–H· · · stacking interactions help in the stabilization of the resulted frameworks. These C–H· · · edge-to-face interactions are present with H· · · distance of 3.00 Å.

  13. Synthesis of Arylplatinum(II) Complexes with Chiral Monoanionic Aryldiamine ligands. The X-ray Crystal Structure of)[(1R)2,6bis{1(dimethylamino)propyl}phenyl]chloroplatinum,

    OpenAIRE

    van Koten, G; Donkervoort, J.G.; Vicario, J.L.; Jastrzebski, J.T.B.H.; Smeets, W.J.J.; Spek, A.L.

    1998-01-01

    The new chiral arylplatinum(II) compounds [2, 6-bis(1-(dimethylamino)ethyl)phenyl]chloroplatinum(II) (4) and (-)-[(1R,1'R)-bis(1-(dimethylamino)propyl)phenyl]chloroplatinum(II) (5) have been synthesized. The transmetallation of the corresponding aryllithium compounds does not affect either stereogenic centres of the organic ligand while the rate of the transmetallation is shown to be influenced by the size of the benzylic substituents. The X-ray crystal structure of 5 is reported from which t...

  14. X-ray interferometers

    International Nuclear Information System (INIS)

    An improved type of amplitude-division x-ray interferometer is described. The wavelength at which the interferometer can operate is variable, allowing the instrument to be used to measure x-ray wavelength, and the angle of inclination is variable for sample investigation. (U.K.)

  15. X-ray - skeleton

    Science.gov (United States)

    A skeletal x-ray is an imaging test used to look at the bones. It is used to detect fractures , tumors, or ... in the health care provider's office by an x-ray technologist. You will lie on a table or ...

  16. Extremity x-ray

    Science.gov (United States)

    An extremity x-ray is an image of the hands, wrist, feet, ankle, leg, thigh, forearm humerus or upper arm, hip, shoulder ... term "extremity" often refers to a human limb. X-rays are a form of radiation that passes through ...

  17. Dental x-rays

    Science.gov (United States)

    ... addition, many dentists are taking x-rays using digital technology. The image runs through a computer. The amount of radiation given off during the procedure is less than traditional methods. Other types of dental x-rays can create a 3-D picture ...

  18. Asymmetric transfer hydrogenation of ketones catalyzed by nickel complex with new PNO-type ligands

    Institute of Scientific and Technical Information of China (English)

    Zhen Rong Dong; Yan Yun Li; Shen Luan Yu; Guo Song Sun; Jing Xing Gao

    2012-01-01

    The new polydentate mixed-N,P,O chiral ligands have been synthesized by the condensation of bis(o-formylphenyl)-phenylphosphane and R-phenylglycinol in CHCl3,and fully characterized by IR,NMR and EIMS spectra.These ligands were employed with a simple Ni complex Ni(PPh8)2Cl2 in situ as catalytic systems for asymmetric transfer hydrogenation of ketones,and the corresponding optical alcohols were obtained with up to 84% ee under mild conditions.

  19. Synthesis of a small molecule walker and the application of mechanically interlocked ligands in asymmetric catalysis

    OpenAIRE

    Hoekman, Steven

    2016-01-01

    This thesis reports the synthesis of a novel synthetic small molecule walker, a chiral [2]rotaxane and a single-handed trefoil knot. The last two were employed as ligands for metal catalysed asymmetric reactions.Chapter 1 explains what small molecule walkers are and their resemblance to nature’s walking proteins. The motor protein myosin is discussed in more detail, followed by a section about small molecules that diffuse along a surface and recent advances in dynamic covalent walker systems....

  20. X-ray crystallography

    Science.gov (United States)

    2001-01-01

    X-rays diffracted from a well-ordered protein crystal create sharp patterns of scattered light on film. A computer can use these patterns to generate a model of a protein molecule. To analyze the selected crystal, an X-ray crystallographer shines X-rays through the crystal. Unlike a single dental X-ray, which produces a shadow image of a tooth, these X-rays have to be taken many times from different angles to produce a pattern from the scattered light, a map of the intensity of the X-rays after they diffract through the crystal. The X-rays bounce off the electron clouds that form the outer structure of each atom. A flawed crystal will yield a blurry pattern; a well-ordered protein crystal yields a series of sharp diffraction patterns. From these patterns, researchers build an electron density map. With powerful computers and a lot of calculations, scientists can use the electron density patterns to determine the structure of the protein and make a computer-generated model of the structure. The models let researchers improve their understanding of how the protein functions. They also allow scientists to look for receptor sites and active areas that control a protein's function and role in the progress of diseases. From there, pharmaceutical researchers can design molecules that fit the active site, much like a key and lock, so that the protein is locked without affecting the rest of the body. This is called structure-based drug design.

  1. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... Resources Professions Site Index A-Z X-ray (Radiography) - Bone Bone x-ray uses a very small ... X-ray (Radiography)? What is Bone X-ray (Radiography)? An x-ray (radiograph) is a noninvasive medical ...

  2. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... Professions Site Index A-Z X-ray (Radiography) - Bone Bone x-ray uses a very small dose ... limitations of Bone X-ray (Radiography)? What is Bone X-ray (Radiography)? An x-ray (radiograph) is ...

  3. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... News Physician Resources Professions Site Index A-Z X-ray (Radiography) - Bone Bone x-ray uses a very ... of Bone X-ray (Radiography)? What is Bone X-ray (Radiography)? An x-ray (radiograph) is a noninvasive ...

  4. Lumbosacral spine x-ray

    Science.gov (United States)

    X-ray - lumbosacral spine; X-ray - lower spine ... The test is done in a hospital x-ray department or your health care provider's office by an x-ray technician. You will be asked to lie on the x-ray table ...

  5. Bone X-Ray (Radiography)

    Science.gov (United States)

    ... News Physician Resources Professions Site Index A-Z X-ray (Radiography) - Bone Bone x-ray uses a very ... of Bone X-ray (Radiography)? What is Bone X-ray (Radiography)? An x-ray (radiograph) is a noninvasive ...

  6. Abdomen X-Ray (Radiography)

    Science.gov (United States)

    ... News Physician Resources Professions Site Index A-Z X-ray (Radiography) - Abdomen Abdominal x-ray uses a very ... of an abdominal x-ray? What is abdominal x-ray? An x-ray (radiograph) is a noninvasive medical ...

  7. X-ray apparatus

    International Nuclear Information System (INIS)

    A patient support system for X-ray equipment in arteriographic studies of the heart is described in detail. The support system has been designed to overcome many of the practical problems encountered in using previous types of arteriographic X-ray equipment. The support system is capable of horizontal movement and, by a series of shafts attached to the main support system, the X-ray source and image intensifier or detector may be rotated through the same angle. The system is highly flexible and details are given of several possible operational modes. (U.K.)

  8. X-ray lasers

    CERN Document Server

    Elton, Raymond C

    2012-01-01

    The first in its field, this book is both an introduction to x-ray lasers and a how-to guide for specialists. It provides new entrants and others interested in the field with a comprehensive overview and describes useful examples of analysis and experiments as background and guidance for researchers undertaking new laser designs. In one succinct volume, X-Ray Lasers collects the knowledge and experience gained in two decades of x-ray laser development and conveys the exciting challenges and possibilities still to come._Add on for longer version of blurb_M>The reader is first introduced

  9. A proposal for positive cooperation in anion-cation binding in yttrium and lutetium complexes based on o-amino-substituted phenolate ligands. On the way to coordination polymers by self-assembly. Molecular structures of [ClLu(OAr)3Na] (X-ray) and [ClY(OAr')3Y(OAr')3Na] (X-ray and 89Y-NMR)

    OpenAIRE

    van Koten, G; Hogerheide, M.P.; Ringelberg, S.N.; Grove, D.M.; Jastrzebski, J.T.B.H.; Boersma, J.; Smeets, W.J.J.; Spek, A.L.

    1996-01-01

    Unique hetero(poly)metallic complexes [ClM(OAr)3Na] (M = Lu (3a), Y (3b)) and [ClY(OAr')3Y(OAr')3Na] (4) containing the bis (OAr = OC6H2(CH2NMe2)2-2,6-Me-4) and mono (OAr' = OC6H4(CH2NMe2)-2) o-amino-substituted phenolate ligands have been synthesized and characterized by NMR (1H, 13C, and 89Y) and X-ray structure determinations (3a and 4). Crystals of 3a are triclinic, space group P, with unit cell dimensions a = 10.706(1) Å, b = 14.099(2) Å, c = 18.882(3) Å, = 93.48(1), = 99.49(1), = 108.72...

  10. The concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydes

    OpenAIRE

    Nishimura, Takahiro; Kumamoto, Hana; Nagaosa, Makoto; Hayashi, Tamio

    2009-01-01

    New C2-symmetric tetrafluorobenzobarrelene ligands were prepared and applied successfully to the rhodium-catalyzed asymmetric addition of arylboronic acids to aromatic aldehydes giving chiral diarylmethanols in high yield with high enantioselectivity.

  11. X-Ray Diffraction.

    Science.gov (United States)

    Smith, D. K.; Smith, K. L.

    1980-01-01

    Reviews applications in research and analytical characterization of compounds and materials in the field of X-ray diffraction, emphasizing new developments in applications and instrumentation in both single crystal and powder diffraction. Cites 414 references. (CS)

  12. Medical X-Rays

    Science.gov (United States)

    ... The Conference of Radiation Control Program Directors (CRCPD) publishes Suggested State Regulations for the Control of Radiation , ... eSubmitter Guidance for Industry and Food and Drug Administration Staff - Assembler's Guide to Diagnostic X-Ray Equipment ...

  13. Chest X-Ray

    Medline Plus

    Full Text Available ... also be useful to help diagnose and monitor treatment for a variety of lung conditions such as pneumonia, emphysema and cancer. A chest x-ray requires no special preparation. ...

  14. Chest X-Ray

    Medline Plus

    Full Text Available ... However, it’s important to consider the likelihood of benefit to your health. While a chest x-ray use a tiny dose of ionizing radiation, the benefit of an accurate diagnosis far outweighs any risk. ...

  15. Chest X-Ray

    Medline Plus

    Full Text Available ... chest x-ray is used to evaluate the lungs, heart and chest wall and may be used ... diagnose and monitor treatment for a variety of lung conditions such as pneumonia, emphysema and cancer. A ...

  16. Chest X-Ray

    Medline Plus

    Full Text Available ... Angioplasty & vascular stenting Video: Arthrography Video: Contrast Material Radiology and You Take our survey About this Site ... radiologist explains chest x-ray. Transcript Welcome to Radiology Info dot org! Hello, I’m Dr. Geoffrey ...

  17. Chest X-Ray

    Medline Plus

    Full Text Available ... of ionizing radiation, the benefit of an accurate diagnosis far outweighs any risk. For more information about chest x-rays, visit Radiology Info dot org. Thank you for your time! ...

  18. Chest X-Ray

    Medline Plus

    Full Text Available ... Site Index A-Z Spotlight June is Men's Health Month Recently posted: Focused Ultrasound for Uterine Fibroids ... to consider the likelihood of benefit to your health. While a chest x-ray use a tiny ...

  19. X-ray tubes

    International Nuclear Information System (INIS)

    An improved form of x-ray tube is described which consists of a rotatable anode disc and an electron beam source enclosed in an envelope. The beam of electrons strikes the edge of the anode disc at an acute angle, producing x-rays which are transmitted through a window in the envelope. To improve performance and life of the anode disc it is additionally reciprocated back and forth along its axis of rotation. Dimensions are specified. (U.K.)

  20. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... around or in bones. top of page How should I prepare? Most bone x-rays require no ... might interfere with the x-ray images. Women should always inform their physician and x-ray technologist ...

  1. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... drawer under the table holds the x-ray film or image recording plate . Sometimes the x-ray ... extended over the patient while an x-ray film holder or image recording plate is placed beneath ...

  2. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... current x-ray images for diagnosis and disease management. top of page How is the procedure performed? ... standards used by radiology professionals. Modern x-ray systems have very controlled x-ray beams and dose ...

  3. X-ray laser

    International Nuclear Information System (INIS)

    X-ray is among the most important research tools today, and has given priceless contributions to all disciplines within the natural sciences. State of the art in this field is called XFEL, X-ray Free Electron Laser, which may be 10 thousand million times stronger than the x-rays at the European Synchrotron Radiation Facility in Grenoble. In addition XFEL has properties that allow the study of processes which previously would have been impossible. Of special interest are depictions on atomic- and molecular level by the use of x-ray holographic methods, and being able to study chemical reactions in nature's own timescale, the femtosecond. Conclusion: The construction of x-ray lasers is a natural development in a scientific field which has an enormous influence on the surrounding society. While the discovery of x-ray was an important breakthrough in itself, new applications appear one after the other: Medical depiction, dissemination, diffraction, DNA and protein structures, synchrotron radiation and tomography. There is reason to believe that XFEL implies a technological leap as big as the synchrotrons some decades ago. As we are now talking about studies of femtosecond and direct depiction of chemical reactions, it is obvious that we are dealing with a revolution to come, with extensive consequences, both scientifically and culturally. (EW)

  4. PipPhos and MorfPhos : Privileged monodentate phosphoramidite ligands for rhodium-catalyzed asymmetric hydrogenation

    NARCIS (Netherlands)

    Bernsmann, Heiko; van den Berg, M; Hoen, Robert; Minnaard, AJ; Mehler, G; Reetz, MT; De Vries, JG; Feringa, BL

    2005-01-01

    A library of 20 monodentate phosphoramidite ligands has been prepared and applied in rhodium-catalyzed asymmetric hydrogenation. This resulted in the identification of two ligands, PipPhos and MorfPhos, that afford excellent and in several cases unprecedented enantioselectivities in the hydrogenatio

  5. X-ray nanotomography

    Science.gov (United States)

    Sasov, Alexander

    2004-10-01

    A compact laboratory x-ray "nano-CT" scanner has been created for 3D non-invasive imaging with 150-200 nanometers 3D spatial resolution, using advanced x-ray technologies and specific physical phenomena for signal detection. This spatial resolution in volume terms is 3 orders better than can be achieved in synchrotron tomography, 5 orders better then in existing laboratory micro-CT instruments and 10-12 orders better in comparison to clinical CT. The instrument employs an x-ray source with a 300-400nm x-ray spot size and uses small-angle scattering to attain a detail detectability of 150-200nm. An object manipulator allows positioning and rotation with an accuracy of 150nm. The x-ray detector is based on an intensified CCD with single-photon sensitivity. A typical acquisition cycle for 3D reconstruction of the full object volume takes from 10 to 60 minutes, with the collection of several hundred angular views. Subsequent volumetric reconstruction produces results as a set of cross sections with isotropic voxel size down to 140 x 140 x 140nm, or as a 3D-model, which can be virtually manipulated and measured. This unique spatial resolution in non-invasive investigations gives previously unattainable 3D images in several application areas, such as composite materials, paper and wood microstructure, biomedical applications and others.

  6. X-ray Pulsars

    CERN Document Server

    Walter, Roland

    2016-01-01

    X-ray pulsars shine thanks to the conversion of the gravitational energy of accreted material to X-ray radiation. The accretion rate is modulated by geometrical and hydrodynamical effects in the stellar wind of the pulsar companions and/or by instabilities in accretion discs. Wind driven flows are highly unstable close to neutron stars and responsible for X-ray variability by factors $10^3$ on time scale of hours. Disk driven flows feature slower state transitions and quasi periodic oscillations related to orbital motion and precession or resonance. On shorter time scales, and closer to the surface of the neutron star, X-ray variability is dominated by the interactions of the accreting flow with the spinning magnetosphere. When the pulsar magnetic field is large, the flow is confined in a relatively narrow accretion column, whose geometrical properties drive the observed X-ray emission. In low magnetized systems, an increasing accretion rate allows the ignition of powerful explosive thermonuclear burning at t...

  7. X-ray astronomy

    International Nuclear Information System (INIS)

    This book contains the lectures, and the most important seminars held at the NATO meeting on X-Ray astronomy in Erice, July 1979. The meeting was an opportune forum to discuss the results of the first 8-months of operation of the X-ray satellite, HEAO-2 (Einstein Observatory) which was launched at the end of 1978. Besides surveying these results, the meeting covered extragalactic astronomy, including the relevant observations obtained in other portions of the electromagnetic spectrum (ultra-violet, optical, infrared and radio). The discussion on galactic X-ray sources essentially covered classical binaries, globular clusters and bursters and its significance to extragalactic sources and to high energy astrophysics was borne in mind. (orig.)

  8. Synthesis and X-ray structure analysis of a new binuclear Schiff base Co(II) complex with the ligand N,N'-bis(3-methoxysalicylidene)-1,4-butanediamine

    International Nuclear Information System (INIS)

    The title binuclear complex, tris[N,N-bis(3-methoxysalicylidene)-1,4-diaminobutane] dicobalt(II), C60H70Co2N6O15, was prepared by the reaction of the tetradentate Schiff base ligand bis(3-methoxysalicylidene)-1,4-diaminobutane and Co(CH3COO)2 . 4H2O in a ethanol solution and structurally characterized by single-crystal X-ray diffraction. This complex has a dinuclear structure where two Co(II) ions are bridged by one N0,N'-bis(3-methoxysalicylidene)-1,4-diaminobutane. The two Co(II) ions, have two distorted octahedral coordination involving two O and two N atoms.

  9. CRL X-RAY TUBE

    OpenAIRE

    Kolchevsky, N. N.; Petrov, P. V.

    2015-01-01

    A novel types of X-ray tubes with refractive lenses are proposed. CRL-R X-ray tube consists of Compound Refractive Lens- CRL and Reflection X-ray tube. CRL acts as X-ray window. CRL-T X-ray consists of CRL and Transmission X-ray tube. CRL acts as target for electron beam. CRL refractive lens acts as filter, collimator, waveguide and focusing lens. Properties and construction of the CRL X-ray tube are discussed.

  10. Anionic chiral tridentate N-donor pincer ligands in asymmetric catalysis.

    Science.gov (United States)

    Deng, Qing-Hai; Melen, Rebecca L; Gade, Lutz H

    2014-10-21

    Tridentate monoanionic ligands known as "pincers" have gained a prominent place as ligands for transition metals and, more recently, for main-group metals and lanthanides. They have been widely employed as ancillary ligands for metal complexes studied inter alia in bond activation steps relevant to catalytic processes. The central formally anionic aryl or heteroaryl unit acts as an "anchor" in the coordination to the metal, which kinetically stabilizes the resulting complexes. Their stability, activity, and reactivity can be tuned by subtle modifications of substitution patterns on the pincer ligand or by modifying the donor atoms. The challenges in pincer ligand design for enantioselective catalysis have been met by their assembly from rigid heterocycles and chiral ligating units in the "wingtip" positions, which generally contain the stereochemical information. The resulting well-defined geometry and shape of the reactive sector of the molecular catalyst favor orientational control of the substrates. On the other hand, the kinetic stability allows reduced catalyst loadings. Recently, a new generation of tridentate anionic N(∧)N(∧)N pincer ligands has been developed which give rise to highly enantioselective transformations. Their applications in asymmetric catalysis have focused primarily on the asymmetric Nozaki-Hiyama-Kishi coupling of aldehydes with halogenated hydrocarbons as well as Lewis acid catalysis involving enantioselective electrophilic attack onto metal-activated β-keto esters, oxindoles, and related substrates. These include highly selective protocols for Friedel-Crafts alkylations with Michael acceptors, electrophilic fluorinations, trifluoromethylations, azidations, and alkylations and subsequent transformations. Increasingly, these stereodirecting ligands are being employed in other types of transformations, including hydrosilylations, cyclopropanations, and epoxidations. The stability and well-defined nature of the molecular catalysts have

  11. X-ray astronomical spectroscopy

    Science.gov (United States)

    Holt, Stephen S.

    1987-01-01

    The contributions of the Goddard group to the history of X-ray astronomy are numerous and varied. One role that the group has continued to play involves the pursuit of techniques for the measurement and interpretation of the X-ray spectra of cosmic sources. The latest development is the selection of the X-ray microcalorimeter for the Advanced X-ray Astrophysics Facility (AXAF) study payload. This technology is likely to revolutionize the study of cosmic X-ray spectra.

  12. X-ray apparatus

    International Nuclear Information System (INIS)

    The invention discloses an X-ray apparatus that can be used for tomography with the aid of a computer. With this apparatus plus computer, it is possible to quickly achieve the required edge values whereby the influence of the movement is diminished

  13. Chest X-Ray

    Medline Plus

    Full Text Available ... Pediatric Ultrasound Video: Angioplasty & vascular stenting Video: Arthrography Radiology and You About this Site RadiologyInfo.org is ... radiologist explains chest x-ray. Transcript Welcome to Radiology Info dot org! Hello, I’m Dr. Geoffrey ...

  14. Medical x-ray

    International Nuclear Information System (INIS)

    This book describes the fundamental subject about medical radiography. It is a multidisciplinary field that requires cross professional input from scientists, engineers and medical doctors. However, it is presented in simple language to suit different levels of readers from x-ray operators and radiographers to physists, general practitioners and radiology specialists.The book is written in accordance to the requirements of the standard syllabus approved by the Ministry of Health Malaysia for the training of medical x-ray operator and general practitioners. In general, the content is not only designed to provide relevant and essential subject for related professionals in medical radiological services such as x-ray operator, radiographer and radiologists, but also to address those in associated radiological services including nurses, medical technologists and physicists.The book is organized and arranged sequentially into 3 parts for easy reference: Radiation safety; X-ray equipment and associated facilities; Radiography practices. With proper grasping of all these parts, the radiological services could be provided with confident and the highest professional standard. Thus, medical imaging with highest quality that can provide useful diagnostic information at minimum doses and at cost effective could be assured

  15. Chest X-Ray

    Medline Plus

    Full Text Available ... this Site RadiologyInfo.org is produced by: Image/Video Gallery Your radiologist explains chest x-ray. Transcript ... Recently posted: Focused Ultrasound for Uterine Fibroids Dementia Video: General Ultrasound Video: Pediatric Nuclear Medicine Radiology and ...

  16. Chest X-Ray

    Medline Plus

    Full Text Available ... this Site RadiologyInfo.org is produced by: Image/Video Gallery Your radiologist explains chest x-ray. Transcript ... time! Spotlight Recently posted: Pediatric MRI Intravascular Ultrasound Video: Chest CT Video:Thyroid Ultrasound Video: Head CT ...

  17. Pyroelectric x-ray detectors and x-ray pyrometers

    International Nuclear Information System (INIS)

    This paper discusses pyroelectric detectors which are very promising x-ray detectors for intense pulsed x-ray/γ-ray measurements and can be used as x-ray pyrometers. They are fast, passive, and inherently flat in spectral response for low energy x-rays. The authors report tests of LiTaO3, Sr.5Ba.5Nb2O6 and LiNbO3 detectors at Nova laser with 1 ns low energy x-rays and at Zapp Z-pinch machine with 100 ns x-rays. The temporal and spectral responses are discussed

  18. Pyroelectric x-ray detectors and x-ray pyrometers

    International Nuclear Information System (INIS)

    Pyroelectric detectors are very promising x-ray detectors for intense pulsed x-ray/γ-ray measurements and can be used as x-ray pyrometers. They are fast, passive, and inherently flat in spectral response for low-energy x rays. We report our tests of LiTaO3 detectors at Nova laser with 1-ns low-energy x rays and at Zapp Z-pinch machine with 100-ns x rays. The temporal and spectral responses are discussed

  19. Synthesis, characterization, X-ray crystal structure, electrochemical evaluation and anti-cancer studies of a mixed ligand Cu(II) complex of (E)-N′-((2-hydroxynaphthalen-1-yl)methylene)acetohydrazide

    Indian Academy of Sciences (India)

    Iran Sheikhshoaie; S Yousef Ebrahimipour; Mahdieh Sheikhshoaie; Maryam Mohamadi; Mehdi Abbasnejad; Hadi Amiri Rudbari; Giuseppe Bruno

    2015-12-01

    A ternary mixed ligand Cu(II) complex, [Cu(L)(Phen)], was prepared from the reaction of (E)-N′-((2-hydroxynaphthalen-1-yl)methylene)acetohydrazide [HL], Cu(NO3)2.3H2O and 1,10-Phenanthroline in 1:1:1 molar ratio. This complex was fully characterized using spectroscopic and physicochemical methods. The structure of the complex was determined by single crystal X-ray diffraction. The Cu(II) center is coordinated by two oxygen and one nitrogen donors of L2− and nitrogen atoms of the heterocyclic group. Electrochemical studies of the Cu(II) complex showed shifts in the ligand peaks as well as the appearance of new peaks after complexation. The electrochemical behavior of the Cu(II) complex was also studied using cyclic voltammetry. According to biochemical investigation (MCF-7 cells viability), anticancer activity of [Cu(L)(Phen)] was higher than those of Cu(NO3)2.3H2O, HL and 1,10-Phenanthroline.

  20. X ray Production. Chapter 5

    International Nuclear Information System (INIS)

    The differential absorption of X rays in tissues and organs, owing to their atomic composition, is the basis for the various imaging methods used in diagnostic radiology. The principles in the production of X rays have remained the same since their discovery. However, much refinement has gone into the design of X ray tubes to achieve the performance required for today’s radiological examinations. In this chapter, an outline of the principles of X ray production and a characterization of the radiation output of X ray tubes will be given. The basic processes producing X rays are dealt with in Section 1.4

  1. Crystallization and preliminary X-ray crystallographic analysis of peptide deformylase (PDF) from Bacillus cereus in ligand-free and actinonin-bound forms

    International Nuclear Information System (INIS)

    Peptide deformylase (PDF) from B. cereus has been overexpressed, purified and crystallized in ligand-free and actinonin-bound forms. Diffraction data have been collected from these crystals to 1.7 and 2.0 Å resolution, respectively. In bacteria, protein expression initiates with an N-formyl group and this needs to be removed in order to ensure proper bacterial growth. These formylation and deformylation processes are unique to eubacteria; therefore, inhibition of these would provide a novel antibacterial therapy. Deformylation is carried out by peptide deformylase (PDF). PDF from Bacillus cereus, one of the major pathogenic bacteria, was cloned into expression plasmid pET-28a (Novagen), overexpressed in Escherichia coli BL21 (DE3) and purified to high quality. Crystals have been obtained of both ligand-free PDF and PDF to which actinonin, a highly potent naturally occurring inhibitor, is bound. Both crystals belong to space group P212121, with unit-cell parameters a = 42.72, b = 44.04, c = 85.19 Å and a = 41.31, b = 44.56, c = 84.47 Å, respectively. Diffraction data were collected to 1.7 Å resolution for the inhibitor-free crystals and to 2.0 Å resolution for the actinonin-bound crystals

  2. X-ray microtomography

    International Nuclear Information System (INIS)

    In this paper the authors describe the application of a new high-resolution X-ray tomographic microscope to the study of porous media. The microscope was designed to exploit the properties of a synchrotron X-ray source to perform three dimensional tomography on millimeter sized objects with micron resolution and has been used in materials science studies with both synchrotron and conventional and synchrotron sources will be compared. In this work the authors have applied the microscope to measure the three dimensional structure of fused bead packs and berea sandstones with micron resolution and have performed preliminary studies of flow in these media with the microscope operated in a digital subtraction radiography mode. Computer graphics techniques have been applied to the data to visually display the structure of the pore body system. Tomographic imaging after flow experiments should detect the structure of the oil-water interface in the pore network and this work is ongoing

  3. X-ray generators

    International Nuclear Information System (INIS)

    Volume 4 provides a comparative survey on generators for stationary applications as available on the German market. It provides decision-making tools, physical characteristics, suggestions for radiation protection and for safe appliance operation as well as a concept for inspections all of which have been developed jointly by physicians of various specialities, physicists, engineers, business men, hospital experts and medicotechnical X-ray staff on the basis of a well-tried working concept. The systematic representation of correlations relevant to decision-making processes is based on a profile of technico-physical characteristics (standard product information) which was established by way of interdisciplinary dialog and which will enable any hospital or clinic to easily equip its X-ray department in an economic and purposeful way. The information on device data, device descriptions and market survey furnish the data tested by the manufacturers without guarantee and subject to correction. (orig./HP)

  4. X-ray lithography

    International Nuclear Information System (INIS)

    An invention relating to the development of photo-resists used in X-ray lithography is described. A COP resist which has been exposed to X-ray radiation, is developed with methyl ethyl ketone (MEK) developer and an ethanol solvent. The resist is first developed in a strong developing solution and then with a weaker developer whose concentration is slightly above that required to obtain complete development. Preferably the resist is exposed so as to obtain about a fifty per cent developed thickness and the developing is carried out in steps, the first with a concentration of 5:1.8 (MEK to ethanol) for five seconds, the second using concentrations of 5:1.8 and 5:2.7 for ten seconds and the third with a concentration of 5:2.7 for five seconds. (author)

  5. X-ray diffraction

    International Nuclear Information System (INIS)

    We have been interested in structural elucidation by x-ray diffraction of compounds of biological interest. Understanding exactly how atoms are arranged in three-dimensional arrays as molecules can help explain the relationship between structure and functions. The species investigated may vary in size and shape; our recent studies included such diverse substances as antischistosomal drugs, a complex of cadmium with nucleic acid base, nitrate salts of adenine, and proteins

  6. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... foot. top of page What are some common uses of the procedure? A bone x-ray is ... care is taken during x-ray examinations to use the lowest radiation dose possible while producing the ...

  7. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... current x-ray images for diagnosis and disease management. top of page How is the procedure performed? ... top of page What are the benefits vs. risks? Benefits Bone x-rays are the fastest and ...

  8. Dental X-ray apparatus

    International Nuclear Information System (INIS)

    Intra-oral dental X-ray apparatus for panoramic radiography is described in detail. It comprises a tubular target carrier supporting at its distal end a target with an inclined forward face. Image definition is improved by positioning in the path of the X-rays a window of X-ray transmitting ceramic material, e.g. 90% oxide of Be, or Al, 7% Si02. The target carrier forms a probe which can be positioned in the patient's mouth. X-rays are directed forwardly and laterally of the target to an X-ray film positioned externally. The probe is provided with a detachable sleeve having V-form arms of X-ray opaque material which serve to depress the tongue out of the radiation path and also shield the roof of the mouth and other regions of the head from the X-ray pattern. A cylindrical lead shield defines the X-ray beam angle. (author)

  9. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... current x-ray images for diagnosis and disease management. top of page How is the procedure performed? ... position possible that still ensures x-ray image quality. top of page Who interprets the results and ...

  10. Soft X-ray Imaging

    Energy Technology Data Exchange (ETDEWEB)

    Seely, John

    1999-05-20

    The contents of this report cover the following: (1) design of the soft x-ray telescope; (2) fabrication and characterization of the soft x-ray telescope; and (3) experimental implementation at the OMEGA laser facility.

  11. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... and x-rays. A Word About Minimizing Radiation Exposure Special care is taken during x-ray examinations ... patient's body not being imaged receive minimal radiation exposure. top of page What are the limitations of ...

  12. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... images for evaluation. National and international radiology protection organizations continually review and update the technique standards used by radiology professionals. Modern x-ray systems have very controlled x-ray beams and dose ...

  13. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... fracture. guide orthopedic surgery, such as spine repair/fusion, joint replacement and fracture reductions. look for injury, ... and Media Arthritis X-ray, Interventional Radiology and Nuclear Medicine Radiation Safety Images related to X-ray ( ...

  14. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... As a result, bones appear white on the x-ray, soft tissue shows up in shades of gray and air appears black. Until recently, x-ray images were maintained on large film sheets (much ...

  15. Panoramic Dental X-Ray

    Science.gov (United States)

    ... Physician Resources Professions Site Index A-Z Panoramic Dental X-ray Panoramic dental x-ray uses a ... a large photographic negative). Today, most images are digital files that are stored electronically. These stored images ...

  16. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... that helps physicians diagnose and treat medical conditions. Imaging with x-rays involves exposing a part of ... oldest and most frequently used form of medical imaging. A bone x-ray makes images of any ...

  17. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... wrist, arm, elbow, shoulder, spine, pelvis, hip, thigh, knee, leg (shin), ankle or foot. top of page ... the patient standing upright, as in cases of knee x-rays. A portable x-ray machine is ...

  18. Active X-ray Optics

    Czech Academy of Sciences Publication Activity Database

    Hudec, René; Inneman, A.; Pina, L.; Černá, D.; Tichý, V.

    Bellingham: SPIE, 2013 - (Juha, L.; Bajt, S.; London, R.; Hudec, R.; Pína, L.), 877718/1-877718/7. (Proceedings of SPIE. 8777). ISBN 9780819495792. [Damage to VUV, EUV, and X-ray Optics IV; and EUV and X-ray Optics: Synergy between Laboratory and Space III. Praha (CZ), 15.04.2013-18.04.2013] Institutional support: RVO:67985815 Keywords : X-ray optics * active optics * active X-ray optics Subject RIV: BN - Astronomy, Celestial Mechanics, Astrophysics

  19. X-ray Crystallography Facility

    Science.gov (United States)

    2000-01-01

    Edward Snell, a National Research Council research fellow at NASA's Marshall Space Flight Center (MSFC), prepares a protein crystal for analysis by x-ray crystallography as part of NASA's structural biology program. The small, individual crystals are bombarded with x-rays to produce diffraction patterns, a map of the intensity of the x-rays as they reflect through the crystal.

  20. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... lies. A drawer under the table holds the x-ray film or image recording plate . Sometimes the x-ray ... that is extended over the patient while an x-ray film holder or image recording plate is placed beneath ...

  1. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... x-rays. top of page What does the equipment look like? The equipment typically used for bone x-rays consists of ... and joint abnormalities, such as arthritis. X-ray equipment is relatively inexpensive and widely available in emergency ...

  2. Tunable X-ray source

    Science.gov (United States)

    Boyce, James R.

    2011-02-08

    A method for the production of X-ray bunches tunable in both time and energy level by generating multiple photon, X-ray, beams through the use of Thomson scattering. The method of the present invention simultaneously produces two X-ray pulses that are tunable in energy and/or time.

  3. X-Ray Exam: Ankle

    Science.gov (United States)

    ... Tropical Delight: Melon Smoothie Pregnant? Your Baby's Growth X-Ray Exam: Ankle KidsHealth > For Parents > X-Ray Exam: Ankle Print A A A Text Size ... español Radiografía: tobillo What It Is An ankle X-ray is a safe and painless test that uses ...

  4. X-Ray Exam: Finger

    Science.gov (United States)

    ... Tropical Delight: Melon Smoothie Pregnant? Your Baby's Growth X-Ray Exam: Finger KidsHealth > For Parents > X-Ray Exam: Finger Print A A A Text Size ... español Radiografía: dedo What It Is A finger X-ray is a safe and painless test that uses ...

  5. X-Ray Exam: Wrist

    Science.gov (United States)

    ... Tropical Delight: Melon Smoothie Pregnant? Your Baby's Growth X-Ray Exam: Wrist KidsHealth > For Parents > X-Ray Exam: Wrist Print A A A Text Size ... español Radiografía: muñeca What It Is A wrist X-ray is a safe and painless test that uses ...

  6. X-Ray Exam: Hip

    Science.gov (United States)

    ... Tropical Delight: Melon Smoothie Pregnant? Your Baby's Growth X-Ray Exam: Hip KidsHealth > For Parents > X-Ray Exam: Hip Print A A A Text Size ... español Radiografía: cadera What It Is A hip X-ray is a safe and painless test that uses ...

  7. X-Ray Exam: Forearm

    Science.gov (United States)

    ... Tropical Delight: Melon Smoothie Pregnant? Your Baby's Growth X-Ray Exam: Forearm KidsHealth > For Parents > X-Ray Exam: Forearm Print A A A Text Size ... español Radiografía: brazo What It Is A forearm X-ray is a safe and painless test that uses ...

  8. X-Ray Exam: Pelvis

    Science.gov (United States)

    ... Tropical Delight: Melon Smoothie Pregnant? Your Baby's Growth X-Ray Exam: Pelvis KidsHealth > For Parents > X-Ray Exam: Pelvis Print A A A Text Size ... español Radiografía: pelvis What It Is A pelvis X-ray is a safe and painless test that uses ...

  9. X-Ray Exam: Foot

    Science.gov (United States)

    ... Tropical Delight: Melon Smoothie Pregnant? Your Baby's Growth X-Ray Exam: Foot KidsHealth > For Parents > X-Ray Exam: Foot Print A A A Text Size ... español Radiografía: pie What It Is A foot X-ray is a safe and painless test that uses ...

  10. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... The x-ray tube is connected to a flexible arm that is extended over the patient while an x-ray film holder or image recording plate is placed beneath the patient. top of page How does the procedure work? X-rays are a form of radiation like ...

  11. Crystallization and preliminary X-ray diffraction analysis of the wild-type haloalkane dehalogenase DhaA and its variant DhaA13 complexed with different ligands

    International Nuclear Information System (INIS)

    Crystals of the wild-type haloalkane dehalogenase DhaA derived from R. rhodochrous NCIMB 13064 and of its catalytically inactive variant DhaA13 were grown in the presence of various ligands and diffraction data were collected to high and atomic resolution. Haloalkane dehalogenases make up an important class of hydrolytic enzymes which catalyse the cleavage of carbon–halogen bonds in halogenated aliphatic compounds. There is growing interest in these enzymes owing to their potential use in environmental and industrial applications. The haloalkane dehalogenase DhaA from Rhodococcus rhodochrous NCIMB 13064 can slowly detoxify the industrial pollutant 1,2,3-trichloropropane (TCP). Structural analysis of this enzyme complexed with target ligands was conducted in order to obtain detailed information about the structural limitations of its catalytic properties. In this study, the crystallization and preliminary X-ray analysis of complexes of wild-type DhaA with 2-propanol and with TCP and of complexes of the catalytically inactive variant DhaA13 with the dye coumarin and with TCP are described. The crystals of wild-type DhaA were plate-shaped and belonged to the triclinic space group P1, while the variant DhaA13 can form prism-shaped crystals belonging to the orthorhombic space group P212121 as well as plate-shaped crystals belonging to the triclinic space group P1. Diffraction data for crystals of wild-type DhaA grown from crystallization solutions with different concentrations of 2-propanol were collected to 1.70 and 1.26 Å resolution, respectively. A prism-shaped crystal of DhaA13 complexed with TCP and a plate-shaped crystal of the same variant complexed with the dye coumarin diffracted X-rays to 1.60 and 1.33 Å resolution, respectively. A crystal of wild-type DhaA and a plate-shaped crystal of DhaA13, both complexed with TCP, diffracted to atomic resolutions of 1.04 and 0.97 Å, respectively

  12. X-ray diffraction

    International Nuclear Information System (INIS)

    The seventh edition of Philips' Review of literature on X-ray diffraction begins with a list of conference proceedings on the subject, organised by the Philips' organisation at regular intervals in various European countries. This is followed by a list of bulletins. The bibliography is divided according to the equipment (cameras, diffractometers, monochromators) and its applications. The applications are subdivided into sections for high/low temperature and pressure, effects due to the equipment, small angle scattering and a part for stress, texture and phase analyses of metals and quantitative analysis of minerals

  13. X-ray detector

    International Nuclear Information System (INIS)

    The multicell X-ray or gamma detector is used in computer tomography. To achieve good spatial resolution, the electrode plates are narrowly spaced in each cell and are designed identical over the whole length of the detector group. The uniform spacing and precise check of the angles between the electrodes and accurate control of the dimensions of the whole detector structure are achieved by depositing, in the fabrication process, a viscous, resin type material (e.g., epoxy resin) or glue at selected points between the electrodes and insulators. (ORU)

  14. A comparative Study of C2-Symmetric Bis(aziridine) Ligands in Some Transition Metal-Mediated Asymmetric Transformations

    DEFF Research Database (Denmark)

    Tanner, David Ackland; Johansson, Fredrik; Harden, Adrian;

    1998-01-01

    A comparative study has been made of the performance of differently substituted Ca-symmetric bis(aziridine) ligands in a variety of metal-mediated asymmetric reactions. The metals studied were osmium (dihydroxylation), palladium (allylic alkylation) and copper (cyclopropanation and aziridination......), the ligands being chosen so as to allow evaluation of both electronic and steric effects. The electronic effects were most pronounced for complexes of palladium, which seem to bind rather loosely to this type of ligand. For the other metals, steric effects play a more important role. (C) 1998 Elsevier...

  15. Spiro-fused carbohydrate oxazoline ligands: Synthesis and application as enantio-discrimination agents in asymmetric allylic alkylation.

    Science.gov (United States)

    Kraft, Jochen; Golkowski, Martin; Ziegler, Thomas

    2016-01-01

    In the present work, we describe a convenient synthesis of spiro-fused D-fructo- and D-psico-configurated oxazoline ligands and their application in asymmetric catalysis. The ligands were synthesized from readily available 3,4,5-tri-O-benzyl-1,2-O-isopropylidene-β-D-fructopyranose and 3,4,5-tri-O-benzyl-1,2-O-isopropylidene-β-D-psicopyranose, respectively. The latter compounds were partially deprotected under acidic conditions followed by condensation with thiocyanic acid to give an anomeric mixture of the corresponding 1,3-oxazolidine-2-thiones. The anomeric 1,3-oxazolidine-2-thiones were separated after successive benzylation, fully characterized and subjected to palladium catalyzed Suzuki-Miyaura coupling with 2-pyridineboronic acid N-phenyldiethanolamine ester to give the corresponding 2-pyridyl spiro-oxazoline (PyOx) ligands. The spiro-oxazoline ligands showed high asymmetric induction (up to 93% ee) when applied as chiral ligands in palladium-catalyzed allylic alkylation of 1,3-diphenylallyl acetate with dimethyl malonate. The D-fructo-PyOx ligand provided mainly the (R)-enantiomer while the D-psico-configurated ligand gave the (S)-enantiomer with a lower enantiomeric excess. PMID:26877819

  16. X-ray Compton line scan tomography

    Energy Technology Data Exchange (ETDEWEB)

    Kupsch, Andreas; Lange, Axel; Jaenisch, Gerd-Ruediger [Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin (Germany). Fachgruppe 8.5 - Mikro-ZfP; Hentschel, Manfred P. [Technische Univ. Berlin (Germany); Kardjilov, Nikolay; Markoetter, Henning; Hilger, Andre; Manke, Ingo [Helmholtz-Zentrum Berlin (HZB) (Germany); Toetzke, Christian [Potsdam Univ. (Germany)

    2015-07-01

    The potentials of incoherent X-ray scattering (Compton) computed tomography (CT) are investigated. The imaging of materials of very different atomic number or density at once is generally a perpetual challenge for X-ray tomography or radiography. In a basic laboratory set-up for simultaneous perpendicular Compton scattering and direct beam attenuation tomography are conducted by single channel photon counting line scans. This results in asymmetric distortions of the projection profiles of the scattering CT data set. In a first approach, corrections of Compton scattering data by taking advantage of rotational symmetry yield tomograms without major geometric artefacts. A cylindrical sample composed of PE, PA, PVC, glass and wood demonstrates similar Compton contrast for all the substances, while the conventional absorption tomogram only reveals the two high order materials. Comparison to neutron tomography reveals astonishing similarities except for the glass component (without hydrogen). Therefore, Compton CT offers the potential to replace neutron tomography, which requires much more efforts.

  17. X-ray instrumentation for SR beamlines

    CERN Document Server

    Kovalchuk, M V; Zheludeva, S I; Aleshko-Ozhevsky, O P; Arutynyan, E H; Kheiker, D M; Kreines, A Y; Lider, V V; Pashaev, E M; Shilina, N Y; Shishkov, V A

    2000-01-01

    The main possibilities and parameters of experimental X-ray stations are presented: 'Protein crystallography', 'X-ray structure analysis', 'High-precision X-ray optics', 'X-ray crystallography and material science', 'X-ray topography', 'Photoelectron X-ray standing wave' that are being installed at Kurchatov SR source by A.V. Shubnikov Institute of Crystallography.

  18. TYPING SUPERNOVA REMNANTS USING X-RAY LINE EMISSION MORPHOLOGIES

    International Nuclear Information System (INIS)

    We present a new observational method to type the explosions of young supernova remnants (SNRs). By measuring the morphology of the Chandra X-ray line emission in 17 Galactic and Large Magellanic Cloud SNRs with a multipole expansion analysis (using power ratios), we find that the core-collapse SNRs are statistically more asymmetric than the Type Ia SNRs. We show that the two classes of supernovae can be separated naturally using this technique because X-ray line morphologies reflect the distinct explosion mechanisms and structure of the circumstellar material. These findings are consistent with recent spectropolarimetry results showing that core-collapse supernovae explosions are intrinsically more asymmetric.

  19. X-ray lithography sources

    International Nuclear Information System (INIS)

    Synchrotron from dipole magnets in electron storage rings has emerged as a useful source of x-rays for lithography. To meet the need for these sources numerous groups around the world have embarked on projects to design and construct storage rings for x-ray lithography. Both conventional electromagnets as well as superconducting (SC) dipoles have been incorporated into the various designs. An overview of the worldwide effort to produce commercial x-ray sources will be presented. To better illustrate the elements involved in these sources a closer examination of the Superconducting X-ray Lithography Source Project (SXLS) at BNL will be presented. 11 refs., 1 fig., 5 tabs

  20. X-ray Absorption Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Yano, Junko; Yachandra, Vittal K.

    2009-07-09

    This review gives a brief description of the theory and application of X-ray absorption spectroscopy, both X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS), especially, pertaining to photosynthesis. The advantages and limitations of the methods are discussed. Recent advances in extended EXAFS and polarized EXAFS using oriented membranes and single crystals are explained. Developments in theory in understanding the XANES spectra are described. The application of X-ray absorption spectroscopy to the study of the Mn4Ca cluster in Photosystem II is presented.

  1. X-ray Fluorescence Sectioning

    CERN Document Server

    Cong, Wenxiang

    2012-01-01

    In this paper, we propose an x-ray fluorescence imaging system for elemental analysis. The key idea is what we call "x-ray fluorescence sectioning". Specifically, a slit collimator in front of an x-ray tube is used to shape x-rays into a fan-beam to illuminate a planar section of an object. Then, relevant elements such as gold nanoparticles on the fan-beam plane are excited to generate x-ray fluorescence signals. One or more 2D spectral detectors are placed to face the fan-beam plane and directly measure x-ray fluorescence data. Detector elements are so collimated that each element only sees a unique area element on the fan-beam plane and records the x-ray fluorescence signal accordingly. The measured 2D x-ray fluorescence data can be refined in reference to the attenuation characteristics of the object and the divergence of the beam for accurate elemental mapping. This x-ray fluorescence sectioning system promises fast fluorescence tomographic imaging without a complex inverse procedure. The design can be ad...

  2. Design of HIV-1 Protease Inhibitors with Amino-bis-tetrahydrofuran Derivatives as P2-Ligands to Enhance Backbone-Binding Interactions. Synthesis, Biological Evaluation, and Protein-Ligand X-ray Studies

    Energy Technology Data Exchange (ETDEWEB)

    Ghosh, Arun K.; Martyr, Cuthbert D.; Osswald, Heather L.; Sheri, Venkat Reddy; Kassekert, Luke A.; Chen, Shujing; Agniswamy, Johnson; Wang, Yuan-Fang; Hayashi, Hironori; Aoki, Manabu; Weber, Irene T.; Mitsuya, Hiroaki (GSU); (Kumamoto); (Purdue)

    2015-10-30

    Structure-based design, synthesis, and biological evaluation of a series of very potent HIV-1 protease inhibitors are described. In an effort to improve backbone ligand–binding site interactions, we have incorporated basic-amines at the C4 position of the bis-tetrahydrofuran (bis-THF) ring. We speculated that these substituents would make hydrogen bonding interactions in the flap region of HIV-1 protease. Synthesis of these inhibitors was performed diastereoselectively. A number of inhibitors displayed very potent enzyme inhibitory and antiviral activity. Inhibitors 25f, 25i, and 25j were evaluated against a number of highly-PI-resistant HIV-1 strains, and they exhibited improved antiviral activity over darunavir. Two high resolution X-ray structures of 25f- and 25g-bound HIV-1 protease revealed unique hydrogen bonding interactions with the backbone carbonyl group of Gly48 as well as with the backbone NH of Gly48 in the flap region of the enzyme active site. These ligand–binding site interactions are possibly responsible for their potent activity.

  3. Radioisotope x-ray analysis

    International Nuclear Information System (INIS)

    Radioisotope x-ray fluorescence and x-ray preferential absorption (XRA) techniques are used extensively for the analysis of materials, covering such diverse applications as analysis of alloys, coal, environmental samples, paper, waste materials, and metalliferous mineral ores and products. Many of these analyses are undertaken in the harsh environment of industrial plants and in the field. Some are continuous on-line analyses of material being processed in industry, where instantaneous analysis information is required for the control of rapidly changing processes. Radioisotope x-ray analysis systems are often tailored to a specific but limited range of applications. They are simpler and often considerably less expensive than analysis systems based on x-ray tubes. These systems are preferred to x-ray tube techniques when simplicity, ruggedness, reliability, and cost of equipment are important; when minimum size, weight, and power consumption are necessary; when a very constant and predictable x-ray output is required; when the use of high-energy x-rays is advantageous; and when short x-ray path lengths are required to minimize the absorption of low-energy x-rays in air. This chapter reviews radioisotope XRF, preferential absorption, and scattering techniques. Some of the basic analysis equations are given. The characteristics of radioisotope sources and x-ray detectors are described, and then the x-ray analytical techniques are presented. The choice of radioisotope technique for a specific application is discussed. This is followed by a summary of applications of these techniques, with a more detailed account given of some of the applications, particularly those of considerable industrial importance. 79 refs., 28 figs., 7 tabs

  4. Preparation of Mesoporous SBA-16 Silica-Supported Biscinchona Alkaloid Ligand for the Asymmetric Dihydroxylation of Olefins

    Directory of Open Access Journals (Sweden)

    Shaheen M. Sarkar

    2014-01-01

    Full Text Available Optically active cinchona alkaloid was anchored onto mesoporous SBA-16 silica and the as-prepared complex was used as a heterogeneous chiral ligand of osmium tetraoxide for the asymmetric dihydroxylation of olefins. The prepared catalytic system provided 90–93% yield of vicinal diol with 92–99% enantioselectivity. The ordered mesoporous SBA-16 silica was found to be a valuable support for the cinchona alkaloid liganded osmium catalyst system which is frequently used in chemical industries and research laboratories for olefin functionalization.

  5. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available Toggle navigation Test/Treatment Patient Type Screening/Wellness Disease/Condition Safety En Español More Info Images/Videos News Physician Resources Professions Site Index A-Z X-ray (Radiography) - Bone Bone x-ray uses a very small dose of ionizing ...

  6. X-ray Dynamic Defectoscopy

    Czech Academy of Sciences Publication Activity Database

    Vavřík, Daniel; Visschers, J.; Jakůbek, J.; Ponchut, C.

    Orosei : IMC S.r.l., 2001. s. 47. [International Workshop on Radiation Imaging Detectors /3./. 23.09.2001-27.09.2001, Orosei] R&D Projects: GA ČR GA106/00/D064 Institutional research plan: CEZ:MSM 210000018 Keywords : X-ray Defectoscopy * Damage * X-ray Detectors Subject RIV: JL - Materials Fatigue, Friction Mechanics

  7. X-ray diagnostic equipment

    International Nuclear Information System (INIS)

    An X-ray tube is connected to several different image processing devices in X-ray diagnostic equipment. Only a single organ selector is allocated to it, for which the picture parameters for each image processing device are selected. The choice of the correct combination of picture parameters is made by means of a selector switch. (DG)

  8. X-ray tube arrangement

    International Nuclear Information System (INIS)

    An x-ray tube is described incorporating an elongated target/ anode over which the electron beam is deflected and from which x-rays are emitted. Improved methods of monitoring and controlling the amplitude of the beam deflection are presented. (U.K.)

  9. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... frequently compared to current x-ray images for diagnosis and disease management. top of page How is the procedure performed? The technologist, an individual specially trained to perform radiology examinations, positions the patient on the x-ray ...

  10. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... clothing that might interfere with the x-ray images. Women should always inform their physician and x-ray ... small burst of radiation that passes through the body, recording an image on photographic film or a special detector. Different ...

  11. X-ray photoelectron spectroscopy

    International Nuclear Information System (INIS)

    The methods and results of X-ray photoelectron spectroscopy in the study of plasmons, alloys and gold compounds are discussed. After a comprehensive introduction, seven papers by the author, previously published elsewhere, are reprinted and these cover a wide range of the uses of X-ray photoelectron spectroscopy. (W.D.L.)

  12. Aryltitanium(IV) complexes with the h3-C,N,N'-pseudofacially coordinating ligand [C6H4(CH2N(Me)CH2Ch2NMe2)-2]- (abbreviated as CNN). The x-ray crystal structure of [TiCl2(CNN)(O-i-Pr)

    OpenAIRE

    van Koten, G; Donkervoort, J.G.; Kronenburg, C.M.P.; Deelman, B.J.; Jastrzebski, J.T.B.H.; Veldman, N; Spek, A.L.

    1997-01-01

    Reaction of [TiCl{3}(O-i-Pr)] with [Li(CNN)]{2} (CNN = monoanionic C{6}H{4}(CH{2}N(Me)CH{2}CH{2}NMe{2})-2) in 2:1 molar ratio in toluene at -78}o{C afforded [TiCl{2}(CNN)(O-i-Pr)] as a 3:2 molar mixture of two stereoisomers. The stereoisomers differ by the mutual position of the chloro and alkoxy ligands. Molecular modelling calculations and an X-ray analysis of one of the stereoisomers indicated that the alkoxy ligand exhibits a strong trans preference to the weakest @p-donating ligated atom...

  13. X-ray spectrum of a pinned charge density wave

    OpenAIRE

    Rosso, Alberto; Giamarchi, Thierry

    2004-01-01

    We calculate the x-ray diffraction spectrum produced by a pinned charge density wave (CDW). The signature of the presence of a CDW consists of two satellite peaks, asymmetric as a consequence of disorder. The shape and the intensity of these peaks are determined in the case of a collective weak pinning using the variational method. We predict divergent asymmetric peaks, revealing the presence of a Bragg glass phase. We deal also with the long range Coulomb interactions, concluding that both p...

  14. Semiconductor X-ray detectors

    CERN Document Server

    Lowe, Barrie Glyn

    2014-01-01

    Identifying and measuring the elemental x-rays released when materials are examined with particles (electrons, protons, alpha particles, etc.) or photons (x-rays and gamma rays) is still considered to be the primary analytical technique for routine and non-destructive materials analysis. The Lithium Drifted Silicon (Si(Li)) X-Ray Detector, with its good resolution and peak to background, pioneered this type of analysis on electron microscopes, x-ray fluorescence instruments, and radioactive source- and accelerator-based excitation systems. Although rapid progress in Silicon Drift Detectors (SDDs), Charge Coupled Devices (CCDs), and Compound Semiconductor Detectors, including renewed interest in alternative materials such as CdZnTe and diamond, has made the Si(Li) X-Ray Detector nearly obsolete, the device serves as a useful benchmark and still is used in special instances where its large, sensitive depth is essential. Semiconductor X-Ray Detectors focuses on the history and development of Si(Li) X-Ray Detect...

  15. X-ray quasars and the X-ray background

    International Nuclear Information System (INIS)

    The Einstein X-ray observations of a sample of 202 radio-and optically-selected quasars due to Ku, Helfand and Lucy and to Zamorani et al. are analysed. Correlations between X-ray, optical and radio luminosities are examined. The contribution of radio-loud quasars to the 2-keV X-ray background is estimated using high-frequency radio-source counts, and the contribution due to radio-quiet, optically bright quasars using optical counts. It is shown that radio-loud quasars and radio-quiet optically bright quasars together contribute approximately 15 per cent of the observed 2-keV X-ray background. The contribution of optically faint radio-quiet quasars is uncertain, but may be limited to a maximum of approximately 30 per cent if recent indications of a flattening in optical counts at faint magnitudes are correct. (author)

  16. X-ray diffraction apparatus

    International Nuclear Information System (INIS)

    The invention provides an x-ray diffraction apparatus permitting the rotation of the divergence sit in conjunction with the rotation of the x-ray irradiated specimen, whereby the dimensions of the x-ray irradiated portion of the specimen remain substantially constant during the rotation of the specimen. In a preferred embodiment, the divergence slit is connected to a structural element linked with a second structural element connected to the specimen such that the divergence slit rotates at a lower angular speed than the specimen

  17. X-ray crystal interferometers

    International Nuclear Information System (INIS)

    Various configurations of the X-ray crystal interferometer are reviewed. The interferometer applications considered include metrology, the measurement of fundamental physical constants, the study of weakly absorbing phase objects, time-resolved diagnostics, the determination of hard X-ray beam parameters, and the characterization of structural defects in the context of developing an X-ray Michelson interferometer. The three-crystal Laue interferometer (LLL-interferometer), its design, and the experimental opportunities it offers are given particular attention. (instruments and methods of investigation)

  18. X-ray crystal structure and small-angle X-ray scattering of sheep liver sorbitol dehydrogenase

    DEFF Research Database (Denmark)

    Yennawar, Hemant; Møller, Magda; Gillilan, Richard; Yennawar, Neela

    The X-ray crystal structure of sheep liver sorbitol dehydrogenase (slSDH) has been determined using the crystal structure of human sorbitol dehydrogenase (hSDH) as a molecular-replacement model. slSDH crystallized in space group I222 with one monomer in the asymmetric unit. A conserved tetramer...

  19. Crystallization and preliminary X-ray analysis of aspartate transcarbamoylase from the parasitic protist Trypanosoma cruzi

    International Nuclear Information System (INIS)

    Aspartate transcarbamoylase, the second enzyme of the de novo pyrimidine-biosynthetic pathway, from T. cruzi has been purified and crystallized for X-ray structure analysis. Aspartate transcarbamoylase (ATCase), the second enzyme of the de novo pyrimidine-biosynthetic pathway, catalyzes the production of carbamoyl aspartate from carbamoyl phosphate and l-aspartate. In contrast to Escherichia coli ATCase and eukaryotic CAD multifunctional fusion enzymes, Trypanosoma cruzi ATCase lacks regulatory subunits and is not part of the multifunctional fusion enzyme. Recombinant T. cruzi ATCase expressed in E. coli was purified and crystallized in a ligand-free form and in a complex with carbamoyl phosphate at 277 K by the sitting-drop vapour-diffusion technique using polyethylene glycol 3350 as a precipitant. Ligand-free crystals (space group P1, unit-cell parameters a = 78.42, b = 79.28, c = 92.02 Å, α = 69.56, β = 82.90, γ = 63.25°) diffracted X-rays to 2.8 Å resolution, while those cocrystallized with carbamoyl phosphate (space group P21, unit-cell parameters a = 88.41, b = 158.38, c = 89.00 Å, β = 119.66°) diffracted to 1.6 Å resolution. The presence of two homotrimers in the asymmetric unit (38 kDa × 6) gives VM values of 2.3 and 2.5 Å3 Da−1 for the P1 and P21 crystal forms, respectively

  20. Mechanochemical and solution synthesis, X-ray structure and IR and 31P solid state NMR spectroscopic studies of copper(I) thiocyanate adducts with bulky monodentate tertiary phosphine ligands.

    Science.gov (United States)

    Bowmaker, Graham A; Hanna, John V; Hart, Robert D; Healy, Peter C; King, Scott P; Marchetti, Fabio; Pettinari, Claudio; Skelton, Brian W; Tabacaru, Aurel; White, Allan H

    2012-07-01

    A number of adducts of copper(I) thiocyanate with bulky tertiary phosphine ligands, and some nitrogen-base solvates, were synthesized and structurally and spectroscopically characterised. CuSCN:PCy3 (1:2), as crystallized from pyridine, is shown by a single crystal X-ray study to be a one-dimensional polymer ...(Cy3P)2CuSCN(Cy3P)2CuSCN... (1) with the four-coordinate copper atoms linked end-on by S-SCN-N bridging thiocyanate groups. A second form (2), obtained from acetonitrile, was also identified and shown by IR and 31P CPMAS NMR spectroscopy to be mononuclear, with the magnitude of the dν(Cu) parameter measured from the 31P CPMAS and the ν(CN) value from the IR clearly establishing this compound as three-coordinate [(Cy3P)2CuNCS]. Two further CuSCN/PCy3 compounds CuSCN:PCy3 (1:1) (3), and CuSCN:PCy3:py (1:1:1) (4) were also characterized spectroscopically, with the dν(Cu) parameters indicating three- and four-coordinate copper sites, respectively. Attempts to obtain a 1:2 adduct with tri-t-butylphosphine have yielded, from pyridine, the 1:1 adduct as a dimer [(Bu(t)3P)((SCN)(NCS))Cu(PBu(t)3)] (5), while similar attempts with tri-o-tolylphosphine (from acetonitrile and pyridine (= L)) resulted in solvated 1:1:1 CuSCN:P(o-tol)3:L forms as dimeric [{(o-tol)3P}LCu((SCN)(NCS))CuL{P(o-tol)3}] (6 and 8). The solvent-free 1:1 CuSCN:P(o-tol)3 adduct (7), obtained by desolvation of 6, was characterized spectroscopically and dν(Cu) measurements from the 31P CPMAS NMR data are consistent with the decrease in coordination number of the copper atom from four (for 6) (P,N(MeCN)Cu,S,N) to three (for 7) (PCuS,N) upon loss of the acetonitrile of solvation. These results are compared with those previously reported for mononuclear and binuclear PPh3 adducts which demonstrate a clear tendency for the copper centre to remain four-coordinate. The IR spectroscopic measurements on these compounds show that bands in the far-IR spectra provide a much more definitive criterion for

  1. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... x-ray machine produces a small burst of radiation that passes through the body, recording an image on photographic film or a special detector. Different parts of the body absorb the x- ...

  2. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... an image on photographic film or a special detector. Different parts of the body absorb the x-rays in varying degrees. Dense bone absorbs much of the radiation while soft tissue, such as muscle, fat and ...

  3. Duodenal X-ray diagnostics

    International Nuclear Information System (INIS)

    The publication provides an overview of duodenal X-ray diagnostics with the aid of barium meals in 1362 patients. The introducing paragraphs deal with the topographic anatomy of the region and the methodics of X-ray investigation. The chapter entitled ''processes at the duodenum itself'' describes mainly ulcers, diverticula, congenital anomalies, tumors and inflammations. The neighbourhood processes comprise in the first place diseases having their origin at the pancreas and bile ducts. As a conclusion, endoscopic rectograde cholangio-pancreaticography and percutaneous transhepatic cholangiography are pointed out as advanced X-ray investigation methods. In the annex of X-ray images some of the described phenomena are shown in exemplary manner. (orig./MG)

  4. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... is commonly used to diagnose fractured bones or joint dislocation. Bone x-rays are the fastest and ... to view and assess bone fractures, injuries and joint abnormalities. This exam requires little to no special ...

  5. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... like a photographic negative). Today, most images are digital files that are stored electronically. These stored images ... and places the x-ray film holder or digital recording plate under the table in the area ...

  6. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... the patient lies. A drawer under the table holds the x-ray film or image recording plate . ... when feasible to protect from radiation. You must hold very still and may be asked to keep ...

  7. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... technologist, an individual specially trained to perform radiology examinations, positions the patient on the x-ray table ... bone is forming), for comparison purposes. When the examination is complete, you may be asked to wait ...

  8. Picosecond x-ray science

    International Nuclear Information System (INIS)

    The report discusses the exciting times for short pulse X-rays and the current users of the technology in the United States. Tracking nuclear motions with X-rays transcends scientific disciplines and includes Biology, Materials Science, Condensed Matter and Chemistry. 1 picosecond accesses many phenomena previously hidden at 100ps. Synchrotron advantage over laser plasma and LCLS is that it's easily tunable. There is a large and diverse user community of this technology that is growing rapidly. A working group is being formed to implement 'fast track' Phases 1 and 2 which includes tunable, polarized, monochromatic, focused X-rays; variable pulse length (1 to 100ps) and 1 kHz, 109 X-rays/s with 1% bandwidth. ERL would be a major advance for ultrafast time-resolved studies.

  9. X-ray microtomographic scanners

    Energy Technology Data Exchange (ETDEWEB)

    Syryamkin, V. I., E-mail: klestov-simon@mail.ru; Klestov, S. A., E-mail: klestov-simon@mail.ru [National Research Tomsk State University, Tomsk, 634050 (Russian Federation)

    2015-11-17

    The article studies the operating procedures of an X-ray microtomographic scanner and the module of reconstruction and analysis 3D-image of a test sample in particular. An algorithm for 3D-image reconstruction based on image shadow projections and mathematical methods of the processing are described. Chapter 1 describes the basic principles of X-ray tomography and general procedures of the device developed. Chapters 2 and 3 are devoted to the problem of resources saving by the system during the X-ray tomography procedure, which is achieved by preprocessing of the initial shadow projections. Preprocessing includes background noise removing from the images, which reduces the amount of shadow projections in general and increases the efficiency of the group shadow projections compression. In conclusion, the main applications of X-ray tomography are presented.

  10. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... or in bones. top of page How should I prepare? Most bone x-rays require no special ... to 10 minutes. top of page What will I experience during and after the procedure? A bone ...

  11. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... the body absorb the x-rays in varying degrees. Dense bone absorbs much of the radiation while ... is further reviewed by committees from the American College of Radiology (ACR) and the Radiological Society of ...

  12. Dental X-ray apparatus

    International Nuclear Information System (INIS)

    Intra-oral dental X-ray apparatus for panoramic dental radiography is described in detail. It comprises an electron gun having an elongated tubular target carrier extending into the patient's mouth. The carrier supports an inclined target for direction of an X-ray pattern towards a film positioned externally of the patient's mouth. Image definition is improved by a focusing anode which focuses the electron beam into a sharp spot (0.05 to 0.10 mm diameter) on the target. The potential on the focusing anode is adjustable to vary the size of the spot. An X-ray transmitting ceramic (oxides of Be, Al and Si) window is positioned adjacent to the front face of the target. The electron beam can be magnetically deflected to change the X-ray beam direction. (author)

  13. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... very controlled x-ray beams and dose control methods to minimize stray (scatter) radiation. This ensures that ... around joints, and in evaluating the hips of children with congenital problems. top of page This page ...

  14. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... can be taken to the patient in a hospital bed or the emergency room. The x-ray ... and international radiology protection organizations continually review and update the technique standards used by radiology professionals. Modern ...

  15. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... top of page What are the benefits vs. risks? Benefits Bone x-rays are the fastest and ... in the typical diagnostic range for this exam. Risks There is always a slight chance of cancer ...

  16. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... current x-ray images for diagnosis and disease management. top of page How is the procedure performed? ... in a known abnormality can be monitored over time. Follow-up examinations are sometimes the best way ...

  17. X-ray thickness gauge

    International Nuclear Information System (INIS)

    New design of X-ray gauge of rolled product thickness is suggested. It is supplied with self-compensation unit, removing the error, caused by changes of half-cycles of supply voltage of radiation source

  18. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... during x-ray examinations to use the lowest radiation dose possible while producing the best images for evaluation. National and international radiology protection organizations continually review and update the technique standards ...

  19. Bone X-Ray (Radiography)

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    Full Text Available ... Leave jewelry at home and wear loose, comfortable clothing. You may be asked to wear a gown. ... appliances, eye glasses and any metal objects or clothing that might interfere with the x-ray images. ...

  20. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... a large photographic negative). Today, most images are digital files that are stored electronically. These stored images ... and places the x-ray film holder or digital recording plate under the table in the area ...

  1. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... current x-ray images for diagnosis and disease management. top of page How is the procedure performed? ... examination may also be necessary so that any change in a known abnormality can be monitored over ...

  2. Bone X-Ray (Radiography)

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    Full Text Available ... replacement and fracture reductions. look for injury, infection, arthritis , abnormal bone growths and bony changes seen in ... injuries, including fractures, and joint abnormalities, such as arthritis. X-ray equipment is relatively inexpensive and widely ...

  3. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... the lowest radiation dose possible while producing the best images for evaluation. National and international radiology protection organizations continually review and update the technique standards used by radiology professionals. Modern x-ray systems ...

  4. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... pregnant. Many imaging tests are not performed during pregnancy so as not to expose the fetus to ... See the Safety page for more information about pregnancy and x-rays. top of page What does ...

  5. Bone X-Ray (Radiography)

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    Full Text Available ... the patient in a hospital bed or the emergency room. The x-ray tube is connected to ... equipment is relatively inexpensive and widely available in emergency rooms, physician offices, ambulatory care centers, nursing homes ...

  6. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... the baby. See the Safety page for more information about pregnancy and x-rays. top of page ... procedure varies. See the Safety page for more information about radiation dose. Women should always inform their ...

  7. X-Ray Assembler Data

    Data.gov (United States)

    U.S. Department of Health & Human Services — Federal regulations require that an assembler who installs one or more certified components of a diagnostic x-ray system submit a report of assembly. This database...

  8. X-ray fluorescence holography

    CERN Document Server

    Hayashi, K; Takahashi, Y

    2003-01-01

    X-ray fluorescence holography (XFH) is a new structural analysis method of determining a 3D atomic arrangement around fluorescing atoms. We developed an XFH apparatus using advanced X-ray techniques and succeeded in obtaining high-quality hologram data. Furthermore, we introduced applications to the structural analysis of a thin film and the environment around dopants and, discussed the quantitative analysis of local lattice distortion. (author)

  9. Accelerator x-ray sources

    CERN Document Server

    Talman, Richard

    2007-01-01

    This first book to cover in-depth the generation of x-rays in particle accelerators focuses on electron beams produced by means of the novel Energy Recovery Linac (ERL) technology. The resulting highly brilliant x-rays are at the centre of this monograph, which continues where other books on the market stop. Written primarily for general, high energy and radiation physicists, the systematic treatment adopted by the work makes it equally suitable as an advanced textbook for young researchers.

  10. Electromechanical x-ray generator

    Energy Technology Data Exchange (ETDEWEB)

    Watson, Scott A; Platts, David; Sorensen, Eric B

    2016-05-03

    An electro-mechanical x-ray generator configured to obtain high-energy operation with favorable energy-weight scaling. The electro-mechanical x-ray generator may include a pair of capacitor plates. The capacitor plates may be charged to a predefined voltage and may be separated to generate higher voltages on the order of hundreds of kV in the AK gap. The high voltage may be generated in a vacuum tube.

  11. X-ray laser; Roentgenlaser

    Energy Technology Data Exchange (ETDEWEB)

    Samuelsen, Emil J.; Breiby, Dag W.

    2009-07-01

    X-ray is among the most important research tools today, and has given priceless contributions to all disciplines within the natural sciences. State of the art in this field is called XFEL, X-ray Free Electron Laser, which may be 10 thousand million times stronger than the x-rays at the European Synchrotron Radiation Facility in Grenoble. In addition XFEL has properties that allow the study of processes which previously would have been impossible. Of special interest are depictions on atomic- and molecular level by the use of x-ray holographic methods, and being able to study chemical reactions in nature's own timescale, the femtosecond. Conclusion: The construction of x-ray lasers is a natural development in a scientific field which has an enormous influence on the surrounding society. While the discovery of x-ray was an important breakthrough in itself, new applications appear one after the other: Medical depiction, dissemination, diffraction, DNA and protein structures, synchrotron radiation and tomography. There is reason to believe that XFEL implies a technological leap as big as the synchrotrons some decades ago. As we are now talking about studies of femtosecond and direct depiction of chemical reactions, it is obvious that we are dealing with a revolution to come, with extensive consequences, both scientifically and culturally. (EW)

  12. X-ray diagnostic apparatus

    International Nuclear Information System (INIS)

    A falling load type X-ray diagnostic apparatus comprises a low voltage power source, AC-DC converting means connected to the low voltage power source so as to apply a rectified low DC voltage, chopping means connected to the AC-DC converting means and chopping said DC voltage into a low AC voltage, high voltage applying means for transforming said low AC voltage into a high AC voltage, said high AC voltage being applied as a tube voltage to an X-ray tube from which X-rays are irradiated toward an object to be examined, means for controlling a filament heating power of the X-ray tube, programming means for supplying a control signal to said filament heating control means so as to reduce the emission current of said X-ray tube during the irradiation, and chopper control means for controlling the chopping ratio of said chopping means by evaluating said rectified DC voltage with a preset tube voltage generated in said programming means, said programming means compensating said tube voltage by receiving said control signal in such a manner that said tube voltage is maintained substantially constant during the irradiation by varying said preset tube voltage so as to control the chopping ratio based upon the reduction of the filament heating power for the X-ray tube

  13. Low energy (soft) x rays

    International Nuclear Information System (INIS)

    Dosimetry of low-energy (soft) X rays produced by the SOFTEX Model CMBW-2 was performed using Nuclear Associates Type 30 - 330 PTW, Exradin Type A2, and Shonka-Wyckoff ionization chambers with a Keithley Model 602 electrometer. Thermoluminescent (BeO chip) dosimeters were used with a Harshaw Detector 2000-A and Picoammeter-B readout system. Beam quality measurements were made using aluminum absorbers; exposure rates were assessed by the current of the X-ray tube and by exposure times. Dose distributions were established, and the average factors for non-uniformity were calculated. The means of obtaining accurate absorbed and exposed doses using these methods are discussed. Survival of V79 cells was assessed by irradiating them with soft X rays, 200 kVp X rays, and 60Co gamma rays. The relative biological effectiveness (RBE) values for soft X rays with 0, 0.2, 0.7 mm added thicknesses of aluminum were 1.6, which were compared to 60Co. The RBE of 200 kVp X rays relative to 60Co was 1.3. Results of this study are available for reference in future RERF studies of cell survival. (author)

  14. Tokamak x ray diagnostic instrumentation

    International Nuclear Information System (INIS)

    Three classes of x-ray diagnostic instruments enable measurement of a variety of tokamak physics parameters from different features of the x-ray emission spectrum. (1) The soft x-ray (1 to 50 keV) pulse-height-analysis (PHA) diagnostic measures impurity concentrations from characteristic line intensities and the continuum enhancement, and measures the electron temperature from the continuum slope. (2) The Bragg x-ray crystal spectrometer (XCS) measures the ion temperature and neutral-beam-induced toroidal rotation velocity from the Doppler broadening and wavelength shift, respectively, of spectral lines of medium-Z impurity ions. Impurity charge state distributions, precise wavelengths, and inner-shell excitation and recombination rates can also be studied. X rays are diffracted and focused by a bent crystal onto a position-sensitive detector. The spectral resolving power E/ΔE is greater than 104 and time resolution is 10 ms. (3) The x-ray imaging system (XIS) measures the spatial structure of rapid fluctuations (0.1 to 100 kHZ) providing information on MHD phenomena, impurity transport rates, toroidal rotation velocity, plasma position, and the electron temperature profile. It uses an array of silicon surface-barrier diodes which view different chords of the plasma through a common slot aperture and operate in current (as opposed to counting) mode. The effectiveness of shields to protect detectors from fusion-neutron radiation effects has been studied both theoretically and experimentally

  15. Center for X-Ray Optics, 1992

    International Nuclear Information System (INIS)

    This report discusses the following topics: Center for X-Ray Optics; Soft X-Ray Imaging wit Zone Plate Lenses; Biological X-Ray microscopy; Extreme Ultraviolet Lithography for Nanoelectronic Pattern Transfer; Multilayer Reflective Optics; EUV/Soft X-ray Reflectometer; Photoemission Microscopy with Reflective Optics; Spectroscopy with Soft X-Rays; Hard X-Ray Microprobe; Coronary Angiography; and Atomic Scattering Factors

  16. X-ray instrumentation for SR beamlines

    Energy Technology Data Exchange (ETDEWEB)

    Kovalchuk, M.V.; Shilin, Yu.N.; Zheludeva, S.I. E-mail: zheludeva@ns.crys.ras.ru; Aleshko-Ozhevsky, O.P.; Arutynyan, E.H.; Kheiker, D.M.; Kreines, A.Ya.; Lider, V.V.; Pashaev, E.M.; Shilina, N.Yu.; Shishkov, V.A

    2000-06-21

    The main possibilities and parameters of experimental X-ray stations are presented: 'Protein crystallography', 'X-ray structure analysis', 'High-precision X-ray optics', 'X-ray crystallography and material science', 'X-ray topography', 'Photoelectron X-ray standing wave' that are being installed at Kurchatov SR source by A.V. Shubnikov Institute of Crystallography.

  17. Investigation of the interaction between a novel unnatural chiral ligand and reactant on palladium for asymmetric hydrogenation.

    Science.gov (United States)

    Jeon, Eun Hee; Yang, Sena; Kang, Sung Ho; Kim, Sehun; Lee, Hangil

    2015-07-21

    We report about the mechanistic studies of the reaction between a newly synthesized (S)-2-((R)-3H-dinaphtho[2,1-c:1',2'-e]azepin-4(5H)-yl)-2-phenylethanol based on the binaphthyl skeleton and (E)-2-methyl-5-phenylpent-2-enoic acid for the asymmetric hydrogenation of α,β-unsaturated acids with heterogeneous palladium catalysts. The specific interactions between the chiral ligand and reactant were investigated in solution with palladium nanoparticles, as well as under ultrahigh vacuum (UHV) conditions on the palladium metal surface in the absence of hydrogen. The reactions were explored using nuclear magnetic resonance (NMR) spectroscopy, scanning tunneling microscopy (STM), and high-resolution photoemission spectroscopy (HRPES) combined with density functional theory (DFT) calculations. A NMR study identified the interaction between both molecules with palladium nanoparticles in solution. In addition, STM and HRPES studies revealed the spatial distribution and configuration of both compounds on the palladium metal surface under UHV conditions. The theoretical results support the experimental results with respect to the interaction energy value. It was found that the reaction between the ligand and reactant occurs with hydrogen bonding on palladium surface, simultaneously. The present study provides mechanistic details of the asymmetric hydrogenation reaction, which bears a correlation between the ligand, reactant, and catalyst during the reaction. PMID:26084713

  18. X-rays and some applications

    International Nuclear Information System (INIS)

    This book is one of the specialized books issued by the Arab Atomic Energy Agency about the key technologies of interest to Arab researchers . The book contains 10 chapters as follows: the nature of X-ray, methods of production and measurement of X-rays, X-ray and materials, X-ray crystallography, X-ray and chemistry, X-ray and physics, biological effects of X-ray, radiography in the field of medicine and biology, X-ray in the field of industry, other applications in agriculture, imaging artifacts and paintings and geology.

  19. X-ray Astronomical Polarimetry in the XEUS Era

    CERN Document Server

    Costa, E; Persio, G D; Feroci, M; Pacciani, L; Rubini, A; Bellazzini, R; Brez, A; Baldini, L; Latronico, L; Omodei, N; Spandre, G

    2002-01-01

    X-ray Polarimetry is almost as old as X-ray Astronomy. Since the first discovery of X-ray sources theoretical analysis suggested that a high degree of linear polarization could be expected due either to the, extremely non thermal, emission mechanism or to the transfer of radiation in highly asymmetric systems. The actual implementation of this subtopic was, conversely, relatively deceiving. This is mainly due to the limitation of the conventional techniques based on the Bragg diffraction at 45deg, or on Thomson scattering around 90deg. Acually no X-ray Polarimeter has been launched since 25 years. Nevertheless the expectations from such measurement on several astrophysical targets including High and Low Mass X-Ray Binaries, isolated neutron Stars, Galactic and Extragalactic Black Holes is extremely attractive. We developed a new technique to measure the linear polarization of X-ray sources. It is based on the visualization of photoelectron tracks in a, finely subdivided, gas filled detector (micropattern). Th...

  20. The Be X-ray Binary Outburst Zoo II

    Science.gov (United States)

    Kuehnel, M.; Kretschmar, P.; Nespoli, E.; Okazaki, A. T.; Schoenherr, G.; Wilson-Hodge, C. A.; Falkner, S.; Brand, T.; Anders, F.; Schwarm, F.-W.; Kreykenbohm, I.; Mueller, S.; Pottschmidt, K.; Fuerst, F.; Grinberg, V.; Wilms, J.

    2015-03-01

    We have continued our recently started systematic study of Be X-ray binary (BeXRB) outbursts. Specifically, we are developing a catalogue of outbursts including their basic properties based on nearly all available X-ray all-sky-monitors. These properties are derived by fitting asymmetric Gaussians to the outburst lightcurves. This model describes most of the outbursts covered by our preliminary catalogue well; only 13% of all datasets show more complex outburst shapes. Analyzing the basic properties, we reveal a strong correlation between the outburst length and the reached peak flux. As an example, we discuss possible models describing the observed correlation in EXO 2030+375.

  1. Dental X-ray apparatus

    International Nuclear Information System (INIS)

    Intra-oral X-ray apparatus which reduces the number of exposures necessary to obtain panoramic dental radiographs is described in detail. It comprises an electron gun, a tubular target carrier projecting from the gun along the beam axis and carrying at its distal end a target surrounded by a shield of X-ray opaque material. This shield extends forward and laterally of the target and has surfaces which define a wedge or cone-shaped radiation pattern delimited vertically by the root tips of the patient's teeth. A film holder is located externally of the patient's mouth. A disposable member can fit on the target carrier to depress the patient's tongue out of the radiation pattern and to further shield the roof of the mouth. The electron beam can be magnetically deflected to change the X-ray beam direction. (author)

  2. Extragalactic X-ray sources

    International Nuclear Information System (INIS)

    About 40% of the X-ray sources in the third UHURU catalogue are extragalactic. One, SMC X-1 has been identified with a binary star in the lesser Magellanic Cloud, while five sources, three probably binary stars, have been found in the greater Magellanic Cloud. X-ray sources in normal galaxies (M31), radiogalaxies (NGC5128), Seyfert galaxies (NGC4151), quasars (3C273) and galaxy clusters (Virgo X-1 and Perseus X-1) are briefly discussed. The most probable explanation for the origin of X-ray emissions from galaxy clusters appears at present to be that the cluster is filled with a thin, very hot gas which emits X-radiation by thermal bremsstrahlung. The main alternative is a socalled inverse Compton effect. (JIW)

  3. Trinuclear Zinc(II) Complexes and Polymeric Cadmium(II) Complexes with the Ligand 2,5-Bis(2-pyridyl)pyrazine: Synthesis, Spectral Analysis, and Single-Crystal and Powder X-ray Analyses.

    Science.gov (United States)

    Neels, Antonia; Stoeckli-Evans, Helen

    1999-12-27

    coordination about the metal is best described as a distorted octahedral with four long distances in the basal plane, to two chlorines and to two nitrogen atoms, and two short distances in the axial direction, to two nitrogen atoms. With Cd(II) two polymeric complexes, 4 and 5 were obtained. Compound 4, C(18)H(16)N(4)O(4)Cd.5H(2)O, crystallizes in the triclinic space group P&onemacr;, a = 9.045(1) Å, b = 10.438(1) Å, c = 12.719(1) Å, alpha = 100.48(1) degrees, beta = 95.05(1) degrees, gamma = 95.86(1) degrees, and Z = 2; R1 for 3694 observed reflections [I > 2sigma(I)] was 0.029. The analogous Cd(NO(3))(2) complex with bppz, 5, could only be obtained in microcrystalline form, and its structure was solved by the use of X-ray powder diffraction methods. Compound 5, C(14)H(10)N(6)O(6)Cd, crystallizes in the monoclinic space group C2/c, with a = 11.6601(3) Å, b = 11.9870(3) Å, c = 12.1453(3) Å, beta = 103.348(2) degrees, and Z = 4. In both 4 and 5 the cadmium atoms are bridged by the ligand bppz, so forming uniform one-dimensional coordination polymers. The cadmium ions exhibit the rare coordination number of 8, with two coordinated ligand molecules and two chelating acetate (4) or nitrate (5) groups. PMID:11671328

  4. X-ray imaging: Perovskites target X-ray detection

    Science.gov (United States)

    Heiss, Wolfgang; Brabec, Christoph

    2016-05-01

    Single crystals of perovskites are currently of interest to help fathom fundamental physical parameters limiting the performance of perovskite-based polycrystalline solar cells. Now, such perovskites offer a technology platform for optoelectronic devices, such as cheap and sensitive X-ray detectors.

  5. X-ray hot plasma diagnostics

    International Nuclear Information System (INIS)

    X-ray plasma emission study is powerful diagnostic tool of hot plasmas. In this review article the main techniques of X-ray plasma emission measurement are shortly presented: X-ray spectrometry using absorbent filters, crystal and grating spectrometers, imaging techniques using pinhole cameras, X-ray microscopes and Fresnel zone plate cameras, X-ray plasma emission calorimetry. Advances in these techniques with examples for different hot plasma devices are also presentes. (author)

  6. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... exam requires little to no special preparation. Tell your doctor and the technologist if there is any possibility you are pregnant. Leave jewelry at home and wear loose, comfortable clothing. You may be asked to wear a gown. What is Bone X-ray (Radiography)? What are some ...

  7. X-ray image converters

    International Nuclear Information System (INIS)

    The invention pertains to rare earth phosphor admixtures utilizing thulium-activated lanthanum or gadolinium oxyhalide phosphor material. These materials increase the relative speed and resolution of an X-ray image compared with conventional phosphors as well as reducing the still serious crossover problem now experienced with conventional phosphors. (Auth.)

  8. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... Images related to X-ray (Radiography) - Bone About this Site RadiologyInfo.org is produced by: Please note ... you can search the ACR-accredited facilities database . This website does not provide cost information. The costs ...

  9. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... Safety En Español More Info Images/Videos News Physician Resources Professions Site Index A-Z X-ray ( ... are the fastest and easiest way for your doctor to view and assess bone fractures, injuries and ...

  10. X-Ray Diffractive Optics

    Science.gov (United States)

    Dennis, Brian; Li, Mary; Skinner, Gerald

    2013-01-01

    X-ray optics were fabricated with the capability of imaging solar x-ray sources with better than 0.1 arcsecond angular resolution, over an order of magnitude finer than is currently possible. Such images would provide a new window into the little-understood energy release and particle acceleration regions in solar flares. They constitute one of the most promising ways to probe these regions in the solar atmosphere with the sensitivity and angular resolution needed to better understand the physical processes involved. A circular slit structure with widths as fine as 0.85 micron etched in a silicon wafer 8 microns thick forms a phase zone plate version of a Fresnel lens capable of focusing approx. =.6 keV x-rays. The focal length of the 3-cm diameter lenses is 100 microns, and the angular resolution capability is better than 0.1 arcsecond. Such phase zone plates were fabricated in Goddard fs Detector Development Lab. (DDL) and tested at the Goddard 600-microns x-ray test facility. The test data verified that the desired angular resolution and throughput efficiency were achieved.

  11. X-ray diagnostic equipment

    International Nuclear Information System (INIS)

    Lateral and orbital scanning movements can be carried out with the equipment. The assessment is carried out by a computer. Differences in sensitivity of the detectors can be compensated for by displacement of the electron beam of the X-ray tube compared to the anti-cathode or by bending of the electron beam by electromagnetic coils. (RW)

  12. X-ray fluorescence spectrometry

    International Nuclear Information System (INIS)

    The seventh edition of Philips' Review of Literature on x-ray fluorescence spectrometry starts with a list of conference proceedings on the subject, organised by the Philips organisation at regular intervals in various European countries. It is followed by a list of bulletins. The bibliography is subdivided according to spectra, equipment, applications and absorption analysis

  13. X-ray film processing

    International Nuclear Information System (INIS)

    X-ray films have to be highly sensitive, for radiation protection reasons. The films used in radiology are coated on both sides with a photosensitive emulsion. This applies to all dental films. Their properties and the development of the different exposed films are explained. (DG)

  14. X-ray backscatter imaging

    Science.gov (United States)

    Dinca, Dan-Cristian; Schubert, Jeffrey R.; Callerame, J.

    2008-04-01

    In contrast to transmission X-ray imaging systems where inspected objects must pass between source and detector, Compton backscatter imaging allows both the illuminating source as well as the X-ray detector to be on the same side of the target object, enabling the inspection to occur rapidly and in a wide variety of space-constrained situations. A Compton backscatter image is similar to a photograph of the contents of a closed container, taken through the container walls, and highlights low atomic number materials such as explosives, drugs, and alcohol, which appear as especially bright objects by virtue of their scattering characteristics. Techniques for producing X-ray images based on Compton scattering will be discussed, along with examples of how these systems are used for both novel security applications and for the detection of contraband materials at ports and borders. Differences between transmission and backscatter images will also be highlighted. In addition, tradeoffs between Compton backscatter image quality and scan speed, effective penetration, and X-ray source specifications will be discussed.

  15. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available Toggle navigation Test/Treatment Patient Type Screening/Wellness Disease/Condition Safety En Español More Info Images/Videos News Physician Resources Professions Site Index A-Z X-ray (Radiography) - Bone ...

  16. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... top of page What are the benefits vs. risks? Benefits Bone x-rays are the fastest and easiest ... cancer from excessive exposure to radiation. However, the benefit of an accurate diagnosis far outweighs the risk. The effective radiation dose for this procedure varies. ...

  17. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... over time. top of page What are the benefits vs. risks? Benefits Bone x-rays are the fastest and easiest ... cancer from excessive exposure to radiation. However, the benefit of an accurate diagnosis far outweighs the risk. ...

  18. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... over time. top of page What are the benefits vs. risks? Benefits Bone x-rays are the fastest and easiest ... evaluation. National and international radiology protection organizations continually review and update the technique standards used by radiology ...

  19. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... current x-ray images for diagnosis and disease management. top of page How is the procedure performed? ... benefit of an accurate diagnosis far outweighs the risk. The effective ... more information about radiation dose. Women should always inform their ...

  20. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available Toggle navigation Test/Treatment Patient Type Screening/Wellness Disease/Condition Safety En Español More Info Images/Videos ... to current x-ray images for diagnosis and disease management. top of page How is the procedure ...

  1. Bone X-Ray (Radiography)

    Medline Plus

    Full Text Available ... for more information about pregnancy and x-rays. A Word About Minimizing Radiation Exposure Special care is ... encourage linking to this site. × Recommend RadiologyInfo to a friend Send to (friend's e-mail address): From ( ...

  2. High-Resolution X-ray Emission and X-ray Absorption Spectroscopy

    OpenAIRE

    de Groot, F. M. F.

    2001-01-01

    In this review, high-resolution X-ray emission and X-ray absorption spectroscopy will be discussed. The focus is on the 3d transition-metal systems. To understand high-resolution X-ray emission and reso-nant X-ray emission, it is first necessary to spend some time discussing the X-ray absorption process. Section II discusses 1s X-ray absorption, i.e., the K edges, and section III deals with 2p X-ray absorption, the L edges. X-ray emission is discussed in, respectively, the L edges. X-ray emis...

  3. Crystal Structure of a Nickel(Ⅱ) Complex with Asymmetric L-Histidine Ligand

    Institute of Scientific and Technical Information of China (English)

    JIN Yi; CHE Yun-Xia; ZHENG Ji-Min

    2006-01-01

    A novel nickel(Ⅱ) complex with L-histidine has been synthesized and solved by single-crystal X-ray diffraction analysis at physiological pH. The title complex (C7H16NiN4O6S, Mr= 343.01) crystallizes in monoclinic, space group P21 with a = 7.2194(7), b = 7.5968(7), c =12.2797(11) (A), β = 93.3110(10)°, V = 672.35(11) (A)3, Z = 2, Dc= 1.694 g/cm3, F(000) = 356,μ(MoKα) = 1.626 mm-1, T = 293(2) K, the final R = 0.0184 and wR = 0.0426 for 2207 observed reflections with I > 2σ(Ⅰ). The complex provides insights into a possible structural arrangement between nickel (Ⅱ) and L-histidine which may be physiologically important and abundantly present in biological systems.

  4. Fructose derived pyridyl alcohol ligands: synthesis and application in the asymmetric diethylzinc addition to aldehydes

    Institute of Scientific and Technical Information of China (English)

    ZHOU, Yong-Gui; DAI, Li-Xin; HOU, Xue-Long

    2000-01-01

    Easily available chiral ketones were employed for the synthesis of optically active pyridyl alcohols, which were applied in the asymmetric diethylzinc addition to aldehydes, up to 89.4%e.e. was obtained using D-fructose-derived pyridyl alcohol.

  5. Center for X-Ray Optics, 1986

    International Nuclear Information System (INIS)

    The Center for X-Ray Optics has made substantial progress during the past year on the development of very high resolution x-ray technologies, the generation of coherent radiation at x-ray wavelengths, and, based on these new developments, had embarked on several scientific investigations that would not otherwise have been possible. The investigations covered in this report are topics on x-ray sources, x-ray imaging and applications, soft x-ray spectroscopy, synchrotron radiation, advanced light source and magnet structures for undulators and wigglers

  6. Phonon effects in STJ X-ray detectors

    Energy Technology Data Exchange (ETDEWEB)

    Andrianov, V.A. E-mail: andrva@srdlan.npi.msu.su; Dmitriev, P.N.; Koshelets, V.P.; Kozin, M.G.; Romashkina, I.L.; Sergeev, S.A.; Shpinel, V.S

    2000-04-07

    Influence of the phonon effects on the output signal of superconducting tunnel X-ray detectors was studied for junctions of two types: the standard Nb/Al/AlO{sub x}/Nb junctions and the multilayer asymmetric Nb/Al/AlO{sub x}/Al/Nb/NbN junctions with the proximity Al trapping layer. It was shown that phonon exchange can change the shape, the amplitude and the polarity of the signal. The most pronounced effects were observed in asymmetric junctions for the signals from the electrode with higher gap.

  7. Digital x-ray imaging

    International Nuclear Information System (INIS)

    Digital radiography is progressively replacing conventional (film-based) radiographic techniques promising consistently high levels of image quality, more effective use of radiation and more efficient work practices. At the same time its introduction poses new challenges to those physical scientists who design radiological imaging systems and those who provide scientific/technical support to a clinical radiology service. In this review scientific aspects of those digital x-ray imaging systems which are proving most successful are described. Physical measurement techniques developed to evaluate the imaging performance and radiation dose efficiency of clinical digital radiography systems are outlined. Finally, directions in which digital x-ray imaging technology may evolve in the coming decade are discussed. (author)

  8. Soft x-ray tomoholography

    International Nuclear Information System (INIS)

    We demonstrate an x-ray imaging method that combines Fourier transform holography with tomography (‘tomoholography’) for three-dimensional (3D) microscopic imaging. A 3D image of a diatom shell with a spatial resolution of 140 nm is presented. The experiment is realized by using a small gold sphere as the reference wave source for holographic imaging. This setup allows us to rotate the sample and to collect a number of 2D projections for tomography. (paper)

  9. Soft x-ray tomoholography

    OpenAIRE

    Guehrs, E.; Stadler, A.M.; Flewett, S.; Frömmel, S.; Geilhufe, J.; Pfau, B; Rander, T.; Schaffert, S.; Büldt, G; Eisebitt, S.

    2012-01-01

    We demonstrate an x-ray imaging method that combines Fourier transform holography with tomography ('tomoholography') for three-dimensional (3D) microscopic imaging. A 3D image of a diatom shell with a spatial resolution of 140 nm is presented. The experiment is realized by using a small gold sphere as the reference wave source for holographic imaging. This setup allows us to rotate the sample and to collect a number of 2D projections for tomography.

  10. X-ray tube arrangements

    International Nuclear Information System (INIS)

    A technique for ensuring the rapid correction of both amplitude and offset errors in the deflectional movement of an electron beam along an X-ray emissive target is described. The movement is monitored at at least two positions during a sweep and differences, between the two movements and a desired movement, at these positions are combined in different proportions to produce a corrective servo signal. Such arrangements find application, for example, in computerised tomographic scanners. (author)

  11. Synthesis of phosphine ligands with helical chirality for applications in asymmetric catalysis

    Czech Academy of Sciences Publication Activity Database

    Andronova, Angelina; Stará, Irena G.; Starý, Ivo

    Praha : -, 2009. s. 90-90. ISBN 978-80-02-02160-5. [ESOC 2009. European Symposium on Organic Chemistry /16./. 12.07.2009-16.07.2009, Praha] R&D Projects: GA MŠk LC512; GA ČR GA203/09/1766; GA ČR GA203/07/1664 Institutional research plan: CEZ:AV0Z40550506 Keywords : helicene * asymmetric catalysis * phosphites Subject RIV: CC - Organic Chemistry

  12. X-ray-powered macronovae

    CERN Document Server

    Kisaka, Shota; Nakar, Ehud

    2015-01-01

    A macronova (or kilonova) was observed as an infrared excess several days after short gamma-ray burst, GRB 130603B. Although the $r$-process radioactivity is widely discussed as an energy source, it requires huge mass of ejecta from a neutron star (NS) binary merger. We propose that the X-ray excess simultaneously observed with the infrared excess can naturally heat the ejecta, leading to the thermal re-emission as observed in infrared. This X-ray-powered model explains both the X-ray and infrared excesses with a single energy source by the central engine like a black hole, and allows for broader parameter region, in particular smaller ejecta mass $\\sim10^{-3}-10^{-2}M_{\\odot}$ with iron mixed as suggested by general relativistic simulations for typical NS-NS mergers, than the previous models. We also discuss the other macronova candidates in GRB 060614 and GRB 080503, and implications for the search of electromagnetic counterparts to gravitational waves.

  13. X-Ray Crystallography Reagent

    Science.gov (United States)

    Morrison, Dennis R. (Inventor); Mosier, Benjamin (Inventor)

    2003-01-01

    Microcapsules prepared by encapsulating an aqueous solution of a protein, drug or other bioactive substance inside a semi-permeable membrane by are disclosed. The microcapsules are formed by interfacial coacervation under conditions where the shear forces are limited to 0-100 dynes per square centimeter at the interface. By placing the microcapsules in a high osmotic dewatering solution. the protein solution is gradually made saturated and then supersaturated. and the controlled nucleation and crystallization of the protein is achieved. The crystal-filled microcapsules prepared by this method can be conveniently harvested and stored while keeping the encapsulated crystals in essentially pristine condition due to the rugged. protective membrane. Because the membrane components themselves are x-ray transparent, large crystal-containing microcapsules can be individually selected, mounted in x-ray capillary tubes and subjected to high energy x-ray diffraction studies to determine the 3-D smucture of the protein molecules. Certain embodiments of the microcapsules of the invention have composite polymeric outer membranes which are somewhat elastic, water insoluble, permeable only to water, salts, and low molecular weight molecules and are structurally stable in fluid shear forces typically encountered in the human vascular system.

  14. X-Ray-powered Macronovae

    Science.gov (United States)

    Kisaka, Shota; Ioka, Kunihito; Nakar, Ehud

    2016-02-01

    A macronova (or kilonova) was observed as an infrared excess several days after the short gamma-ray burst GRB 130603B. Although the r-process radioactivity is widely discussed as an energy source, it requires a huge mass of ejecta from a neutron star (NS) binary merger. We propose a new model in which the X-ray excess gives rise to the simultaneously observed infrared excess via thermal re-emission, and explore what constraints this would place on the mass and velocity of the ejecta. This X-ray-powered model explains both the X-ray and infrared excesses with a single energy source such as the central engine like a black hole, and allows for a broader parameter region than the previous models, in particular a smaller ejecta mass ˜ {10}-3{--}{10}-2{M}⊙ and higher iron abundance mixed as suggested by general relativistic simulations for typical NS-NS mergers. We also discuss the other macronova candidates in GRB 060614 and GRB 080503, and the implications for the search of electromagnetic counterparts to gravitational waves.

  15. Asymmetric Transfer Hydrogenation of Prochiral Ketones in Aqueous Media with New Water-Soluble Chiral Vicinal Diamine as Ligand

    Institute of Scientific and Technical Information of China (English)

    ZHU Jin; MA Ya-Ping; LIU Hui; CHEN Li; CUI Xin; DENG Jin-Gen

    2003-01-01

    @@ As a consequence of the increasing demand for atom economy and environmental friendly methods, the water soluble ligands and their metal complexes are of great interest in catalytic synthesis because of simpler product sepa ration and the possibility of recycling. [1] Unique reactivity and selectivity are often observed in aqueous reactions. [2]Recently, we have developed a new water-soluble chiral vicinal diamine and synthesized its mono-N-tosylated derivative for the first time. The application of its mono-N-tosylated derivative in catalytic asymmetric transfer hydrogenation of prochiral ketones was examined in aqueous media. High activity (up to > 99 % conv. ) and good enatioselectivity ( up to 98% ee ) were achieved for most of prochiral aromatic ketones in organic solvent free system. [3

  16. Synthesis and crystal structures of two nickel coordination polymers generated from asymmetric malate ligand

    International Nuclear Information System (INIS)

    Two nickel coordination polymers [Ni(H2O)(C4H4O5)].H2O 1 and [Ni(H2O)(mal)(phen)] 2, have been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. Crystal data for 1: C4H8O7Ni, monoclinic Cc, a=13.156(3)A, b=7.5436(15)A, c=9.6982(19)A, β=130.96(3)o, Z=4. Crystal data for 2: C16H14N2O6Ni, orthorhombic Pna21, a=9.6113(19)A, b=19.691(4)A, c=8.0944(16)A, Z=4. Compound 1 is constructed from [Ni(H2O)(C4H4O5)] sheets pillared through β-carboxylate groups into a 3D framework, which exhibits a diamond-like network. Compound 2 exhibits a 3D supramolecular network. To our knowledge, compound 1 represents the first diamond-like topology in the system of metal-malate. Other characterizations by elemental analysis, IR and TG are also described. The magnetic behavior of compound 1 has been studied

  17. Aspergillosis - chest x-ray (image)

    Science.gov (United States)

    ... usually occurs in immunocompromised individuals. Here, a chest x-ray shows that the fungus has invaded the lung ... are usually seen as black areas on an x-ray. The cloudiness on the left side of this ...

  18. Stabilized x-ray generator power supply

    International Nuclear Information System (INIS)

    X-ray diffraction and X-ray fluorescence analysis are very much adopted in laboratories to determine the type and structure of the constituent compounds in solid materials, chemical composition of materials, stress developed on metals etc. These experiments need X-ray beam of fixed intensity and wave length. This can only be achieved by X-ray generator having highly stabilized tube voltage and tube current. This paper describes how X-ray tube high voltage and electron beam current are stabilized. This paper also highlights generation of X-rays, diffractometry and X-ray fluorescence analysis and their wide applications. Principle of operation for stabilizing the X-ray tube voltage and current, different protection circuits adopted, special features of the mains H.V. transformer and H.T. tank are described in this report. (author)

  19. Phase-sensitive X-ray imager

    Science.gov (United States)

    Baker, Kevin Louis

    2013-01-08

    X-ray phase sensitive wave-front sensor techniques are detailed that are capable of measuring the entire two-dimensional x-ray electric field, both the amplitude and phase, with a single measurement. These Hartmann sensing and 2-D Shear interferometry wave-front sensors do not require a temporally coherent source and are therefore compatible with x-ray tubes and also with laser-produced or x-pinch x-ray sources.

  20. Optical element for X-ray microscopy

    OpenAIRE

    Chadzitaskos, G.

    2008-01-01

    We present a proposal for a X-ray optical element suitable for X-ray microscopy and other X-ray-based display systems. Its principle is based on the Fresnel lenses condition and the Bragg condition for X-ray scattering on a slice of monocrystal. These conditions are fulfilled simultaneously due to a properly machined shape of the monocrystal with a stress at its ends.

  1. Helicene-Based Phosphite Ligands in Asymmetric Transition-Metal Catalysis: Exploring Rh-Catalyzed Hydroformylation and Ir-Catalyzed Allylic Amination

    Czech Academy of Sciences Publication Activity Database

    Krausová, Zuzana; Sehnal, Petr; Bondzic, B. P.; Chercheja, S.; Eilbracht, P.; Stará, Irena G.; Šaman, David; Starý, Ivo

    -, 20/21 (2011), s. 3849-3857. ISSN 1434-193X R&D Projects: GA ČR GA203/09/1766; GA MŠk LC512 Institutional research plan: CEZ:AV0Z40550506 Keywords : asymmetric catalysis * helical structures * P ligands * hydroformylation * amination Subject RIV: CC - Organic Chemistry Impact factor: 3.329, year: 2011

  2. Chiral N-1-adamantyl-N-trans-cinnamylaniline type ligands: synthesis and application to palladium-catalyzed asymmetric allylic alkylation of indoles.

    Science.gov (United States)

    Mino, Takashi; Nishikawa, Kenji; Asano, Moeko; Shima, Yamato; Ebisawa, Toshibumi; Yoshida, Yasushi; Sakamoto, Masami

    2016-08-21

    Such chiral phosphine-internal olefin hybrid type ligands as N-1-adamantyl-N-cinnamylaniline derivatives 1 with C(aryl)-N(amine) bond axial chirality were synthesized and utilized for the palladium-catalyzed asymmetric allylic alkylation of indoles to afford the desired products in high enantioselectivities (up to 98% ee). PMID:27425209

  3. Kinetic studies on the asymmetric transfer hydrogenation of acetophenone using a homogeneous ruthenium catalyst with a chiral amino-alcohol ligand

    NARCIS (Netherlands)

    Wisman, Ronald V.; Vries, Johannes G. de; Deelman, Berth-Jan; Heeres, Hero J.

    2006-01-01

    The overall kinetics of the asymmetric transfer hydrogenation of acetophenone to 1-phenyl-ethanol using a Noyori-type homogeneous Ru-catalyst with a chiral amino-alcohol ligand ((1R, 2S)-(+)- cis-1-amino-2- indanol) were determined in a batch reactor with on-line FT-IR spectroscopy. Data analysis sh

  4. Center for X-ray Optics, 1988

    Energy Technology Data Exchange (ETDEWEB)

    1989-04-01

    This report briefly reviews the following topics: soft-x-ray imaging; reflective optics for hard x-rays; coherent XUV sources; spectroscopy with x-rays; detectors for coronary artery imaging; synchrotron-radiation optics; and support for the advanced light source.

  5. X-Ray Exam: Neck (For Parents)

    Science.gov (United States)

    ... Tropical Delight: Melon Smoothie Pregnant? Your Baby's Growth X-Ray Exam: Neck KidsHealth > For Parents > X-Ray Exam: Neck Print A A A Text Size ... español Radiografía: cuello What It Is A neck X-ray is a safe and painless test that uses ...

  6. Cryotomography x-ray microscopy state

    Science.gov (United States)

    Le Gros, Mark; Larabell, Carolyn A.

    2010-10-26

    An x-ray microscope stage enables alignment of a sample about a rotation axis to enable three dimensional tomographic imaging of the sample using an x-ray microscope. A heat exchanger assembly provides cooled gas to a sample during x-ray microscopic imaging.

  7. Electron beam parallel X-ray generator

    Science.gov (United States)

    Payne, P.

    1967-01-01

    Broad X ray source produces a highly collimated beam of low energy X rays - a beam with 2 to 5 arc minutes of divergence at energies between 1 and 6 keV in less than 5 feet. The X ray beam is generated by electron bombardment of a target from a large area electron gun.

  8. Center for X-ray Optics, 1988

    International Nuclear Information System (INIS)

    This report briefly reviews the following topics: soft-x-ray imaging; reflective optics for hard x-rays; coherent XUV sources; spectroscopy with x-rays; detectors for coronary artery imaging; synchrotron-radiation optics; and support for the advanced light source

  9. X-ray tracing using Geant4

    International Nuclear Information System (INIS)

    We describe an extension to the Geant4 software package that allows it to be used as a general purpose X-ray tracing package. We demonstrate the use of our extension by building a model of the X-ray optics of the X-ray observatory XMM-Newton, calculating its effective area, and comparing the results with the published calibration curves.

  10. Chandra Discovery of a 100 kpc X-ray Jet in PKS 0637-752

    CERN Document Server

    Schwartz, D A; Lovell, J E J; Piner, B G; Tingay, S J; Birkinshaw, M; Chartas, G; Elvis, M; Feigelson, E D; Ghosh, K K; Harris, D E; Hirabayashi, H; Hooper, E J; Jauncey, D L; Lanzetta, K M; Mathur, S D; Preston, R A; Tucker, W H; Virani, S N; Wilkes, B; Worrall, D M

    2000-01-01

    The quasar PKS 0637-753, the first celestial X-ray target of the Chandra X-ray Observatory, has revealed asymmetric X-ray structure extending from 3 to 12 arcsec west of the quasar, coincident with the inner portion of the jet previously detected in a 4.8 GHz radio image (Tingay et al. 1998). At a redshift of z=0.651, the jet is the largest (~100 kpc) and most luminous (~10^{44.6} ergs/s) of the few so far detected in X-rays. This letter presents a high resolution X-ray image of the jet, from 42 ks of data when PKS 0637-753 was on-axis and ACIS-S was near the optimum focus. For the inner portion of the radio jet, the X-ray morphology closely matches that of new ATCA radio images at 4.8 and 8.6 GHz. Observations of the parsec scale core using the VSOP space VLBI mission show structure aligned with the X-ray jet, placing important constraints on the X-ray source models. HST images show that there are three small knots coincident with the peak radio and X-ray emission. Two of these are resolved, which we use to ...

  11. Heterometallic Zn6Ti2 Building Block Persistent in Metal-organic Frameworks Based on Asymmetrically Substituted Dicarboxylate Ligands

    International Nuclear Information System (INIS)

    The Zn6Ti2 SBU appears to be a persistent and preferably formed building block when asymmetrically substituted, linear dicarboxylate ligands are used. Despite the complexity of the composition and connectivity, the new SBU possesses the nodal geometry of distorted octahedron leading to a simple, 6-connected topology. Metal-organic frameworks (MOFs) are coordination-based polymeric networks often noted for their high crystallinity and high level of porosity. Although many MOFs lack the chemical stabilities under ambient conditions, the crystalline porous materials enjoy the status as promising candidates for numerous practical applications thanks to the highly versatile nature of their compositions and structures. The almost infinite variations in the structures of MOFs are governed by two factors, the geometry of secondary building units (SBUs) and organic ligands. A high level of uncertainty is almost always associated with the former, while the latter, in structure-point of view, largely remains invariant during the synthesis of MOFs. Therefore identifying a new SBU with a well-defined geometry is of a paramount importance in the targeted synthesis of new MOFs. In this context, exploiting two different metals with dissimilar coordination behavior would be highly beneficial because it can significantly deepen the structural chemistry of MOFs. It is, however, a challenging task

  12. A proposal for positive cooperation in anion-cation binding in yttrium and lutetium complexes based on o-amino-substituted phenolate ligands. On the way to coordination polymers by self-assembly. Molecular structures of [ClLu(OAr)3Na] (X-ray) and [ClY(OAr')3Y(OAr')3Na] (X-ray and 89Y-NMR)

    NARCIS (Netherlands)

    Koten, G. van; Hogerheide, M.P.; Ringelberg, S.N.; Grove, D.M.; Jastrzebski, J.T.B.H.; Boersma, J.; Smeets, W.J.J.; Spek, A.L.

    1996-01-01

    Unique hetero(poly)metallic complexes [ClM(OAr)3Na] (M = Lu (3a), Y (3b)) and [ClY(OAr')3Y(OAr')3Na] (4) containing the bis (OAr = OC6H2(CH2NMe2)2-2,6-Me-4) and mono (OAr' = OC6H4(CH2NMe2)-2) o-amino-substituted phenolate ligands have been synthesized and characterized by NMR (1H, 13C, and 89Y) and

  13. Palladium-catalyzed, asymmetric Baeyer–Villiger oxidation of prochiral cyclobutanones with PHOX ligands

    KAUST Repository

    Petersen, Kimberly S.

    2011-06-01

    Described in this report is a general method for the conversion of prochiral 3-substituted cyclobutanones to enantioenriched γ-lactones through a palladium-catalyzed Baeyer-Villiger oxidation using phosphinooxazoline ligands in up to 99% yield and 81% ee. Lactones of enantiopurity ≥93% could be obtained through a single recrystallization step. Importantly, 3,3-disubtituted cyclobutanones produced enantioenriched lactones containing a β-quaternary center. © 2011 Elsevier Ltd. All rights reserved.

  14. X-ray crystallographic characterization of an adenine-cadmium (II) complex, di-. mu. -adeninium-di-. mu. -aquo-tetrakis(nitrato-0,0')dicadmium(II) dinitrate, containing a cationic nuclei acid base as a bidentate ligand

    Energy Technology Data Exchange (ETDEWEB)

    Wei, C.H.; Jacobson, K.B.

    1981-02-01

    The reaction of the monosodium salt of adenosine-5'-monophosphoric acid with cadmium nitrate in the presence of nitric acid has resulted in the formation of a binuclear cadmium complex of adenine, ((C/sub 5/H/sub 6/N/sub 5/)Cd(NO/sub 3/)/sub 2/.H/sub 2/O)/sub 2/(NO/sub 3/)/sub 2/. The crystal structure of this complex has been characterized by single-crystal x-ray analysis based on counter data collected with an automated diffractometer. The crystals contain one centrosymmetric dimer in a reduced triclinic cell of symmetry P anti 1 and of dimensions a = 7.595 (2) A, b = 9.539 (5) A, c = 10.527 (5) A, ..cap alpha.. = 101.37 (3)/sup 0/, ..beta.. = 108.69 (3)/sup 0/, and ..gamma.. = 107.42 (3)/sup 0/.

  15. Zernike x-ray ptychography.

    Science.gov (United States)

    Vartiainen, Ismo; Mohacsi, Istvan; Stachnik, Karolina; Guizar-Sicairos, Manuel; David, Christian; Meents, Alke

    2016-02-15

    We present an imaging technique combining Zernike phase-contrast imaging and ptychography. The contrast formation is explained by following the theory of Zernike phase-contrast imaging. The method is demonstrated with x-rays at a photon energy of 6.2 keV, showing how ptychographic reconstruction of a phase sample leads to a Zernike phase-contrast image appearing in the amplitude reconstruction. In addition, the results presented in this Letter indicate an improvement of the resolution of the reconstructed object in the case of Zernike ptychography compared with the conventional one. PMID:26872172

  16. Protonium X-ray spectroscopy

    CERN Document Server

    Gotta, D

    1999-01-01

    The Lyman and Balmer transitions from antiprotonic hydrogen and deuterium were studied extensively at the low-energy-antiproton ring LEAR at CERN in order to determine the strong interaction effects. A first series of experiments $9 was performed with semiconductor and gaseous X-ray detectors. In the last years of LEAR operation using a Bragg crystal spectrometer, strong interaction parameters in the 2p states of antiprotonic hydrogen and deuterium were measured $9 directly. The results of the measurements support the meson-exchange models describing the medium and long range part of the nucleon-antinucleon interaction. (39 refs).

  17. X-ray tomographic apparatus

    International Nuclear Information System (INIS)

    An x-ray tomographic system consists of a radiation source such as gamma or x radiation which produces a fan-shaped beam. The fan is wide enough to encompass the patient circle. The system further includes means for rotating the radiation source about the patient for less than a full rotation, and detectors for detecting the radiation at positions that surround the patient by 1800 plus the angle of the fan beam plus the angle between adjacent fan detectors. Attenuation data from the detectors is sorted into detector fans of attenuation data, then processed. The convolved data is back-projected into an image memory and displayed on a video monitor

  18. Use of X-ray techniques to demonstrate electively increased damage to certain muscles in patients sufferring from muscular diseases

    International Nuclear Information System (INIS)

    In X-ray examinations on 38 patients suffering from muscular diseases the authors demonstrated electively pronounced damage to certain muscles in 18 cases. The decay of muscle fibres within a single muscle is not always uniform and is often bilaterally asymmetrical. Before biopsy or EMG examinations it is advisable to take an X-ray of the damaged musculature. (orig.)

  19. X-ray Pulsations in the Supersoft X-ray Binary CAL 83

    OpenAIRE

    Schmidtke, P. C.; Cowley, A. P.

    2005-01-01

    X-ray data reveal that the supersoft X-ray binary CAL 83 exhibits 38.4 minute pulsations at some epochs. These X-ray variations are similar to those found in some novae and are likely to be caused by nonradial pulsations the white dwarf. This is the first detection of pulsations in a classical supersoft X-ray binary.

  20. Comets: mechanisms of x-ray activity

    Science.gov (United States)

    Ibadov, Subhon

    2016-07-01

    Basic mechanisms of X-ray activity of comets are considered, including D-D mechanism corresponding to generation of X-rays due to production of hot short-living plasma clumps at high-velocity collisions between cometary and interplanetary dust particles as well as M-M one corresponding to production of X-rays due to recombination of multicharge ions of solar wind plasma via charge exchange process at their collisions with molecules/atoms of the cometary atmospheres. Peculiarities of the variation of the comet X-ray spectrum and X-ray luminosity with variation of its heliocentric distance are revealed.

  1. Swift Observations of X-ray supernovae

    OpenAIRE

    Li, K. L.; Pun, Chun. S. J.

    2011-01-01

    We present a result of X-ray supernovae (SNe) survey using the Swift satellite public archive. An automatic searching program was designed to search X-ray SNe among all of the Swift archival observations between November 2004 and February 2011. Using the C++ program, 24 X-ray detectable supernovae have been found in the archive and 3 of them were newly-discovered in X-rays which are SN 1986L, SN 2003lx, and SN 2007od. In addition, SN 2003lx is a Type Ia supernova which may be the second X-ray...

  2. X-ray Spectroscopy of Cooling Cluster

    Energy Technology Data Exchange (ETDEWEB)

    Peterson, J.R.; /SLAC; Fabian, A.C.; /Cambridge U., Inst. of Astron.

    2006-01-17

    We review the X-ray spectra of the cores of clusters of galaxies. Recent high resolution X-ray spectroscopic observations have demonstrated a severe deficit of emission at the lowest X-ray temperatures as compared to that expected from simple radiative cooling models. The same observations have provided compelling evidence that the gas in the cores is cooling below half the maximum temperature. We review these results, discuss physical models of cooling clusters, and describe the X-ray instrumentation and analysis techniques used to make these observations. We discuss several viable mechanisms designed to cancel or distort the expected process of X-ray cluster cooling.

  3. Symbiotic stars in X-rays

    OpenAIRE

    Luna, G. J. M.; Sokoloski, J. L.; Mukai, K; Nelson, T.

    2012-01-01

    Until recently, symbiotic binary systems in which a white dwarf accretes from a red giant were thought to be mainly a soft X-ray population. Here we describe the detection with the X-ray Telescope (XRT) on the Swift satellite of nine white dwarf symbiotics that were not previously known to be X-ray sources and one that had previously been detected as a supersoft X-ray source. The nine new X-ray detections were the result of a survey of 41 symbiotic stars, and they increase the number of symbi...

  4. Miniature x-ray point source for alignment and calibration of x-ray optics

    International Nuclear Information System (INIS)

    A miniature x-ray point source of high brightness similar to that of Rovinsky, et al. is described. One version of the x-ray source is used to align the x-ray optics on the Argus and Shiva laser systems. A second version is used to determine the spatial and spectral transmission functions of the x-ray optics. The spatial and spectral characteristics of the x-ray emission from the x-ray point source are described. The physical constraints including size, intensity and thermal limitations, and useful lifetime are discussed. The alignment and calibration techniques for various x-ray optics and detector combinations are described

  5. An X-Ray Tomographic Microscope with Submicron Resolution

    International Nuclear Information System (INIS)

    X-ray tomographic microscopy (XTM) is a powerful non-destructive investigation method, that has been applied in many fields of modern research (material science, micro electronics, medicine, biology , archaeology). So far the major limitations were imposed by low detection efficiency and low spatial resolution. With the advent of third generation synchrotron facilities excellent high intensity X-ray sources became available that by far counterbalanced low efficiency. On the other hand the resolution of presently used detector systems is restricted by scintillator properties, optical light transfer, and CCD granularity. They impose a practical limit of about one micrometer, while the progressing research demands urgently an advance in the submicron region. A break-through in this respect is being achieved by a novel detector type. It uses the properties of asymmetric Bragg reflection to increase the cross section of the reflected X-ray beam. A suitable combination of correspondingly cut Bragg crystals yields an image magnification that even at higher energies may surpass a factor of 1000. In this way the influence of the detector resolution can be scaled down accordingly. Such a device is being constructed and installed at the SLS which delivers an optimal X-ray beam of about 23 keV. The special properties of this experiment will be presented. (author)

  6. Phase contrast imaging with coherent high energy X-rays

    Energy Technology Data Exchange (ETDEWEB)

    Snigireva, I. [ESRF, Grenoble (France)

    1997-02-01

    X-ray imaging concern high energy domain (>6 keV) like a contact radiography, projection microscopy and tomography is used for many years to discern the features of the internal structure non destructively in material science, medicine and biology. In so doing the main contrast formation is absorption that makes some limitations for imaging of the light density materials and what is more the resolution of these techniques is not better than 10-100 {mu}m. It was turned out that there is now way in which to overcome 1{mu}m or even sub-{mu}m resolution limit except phase contrast imaging. It is well known in optics that the phase contrast is realised when interference between reference wave front and transmitted through the sample take place. Examples of this imaging are: phase contrast microscopy suggested by Zernike and Gabor (in-line) holography. Both of this techniques: phase contrast x-ray microscopy and holography are successfully progressing now in soft x-ray region. For imaging in the hard X-rays to enhance the contrast and to be able to resolve phase variations across the beam the high degree of the time and more importantly spatial coherence is needed. Because of this it was reasonable that the perfect crystal optics was involved like Bonse-Hart interferometry, double-crystal and even triple-crystal set-up using Laue and Bragg geometry with asymmetrically cut crystals.

  7. Management of dental x-ray exposure

    International Nuclear Information System (INIS)

    The effects of dental x-ray exposure and how they might be minimized were reviewed. The frequency of dental x-ray exposures in Japan was presented for each year, sex, age group and site of x-ray photography separately. The doses of exposure at various parts of the body per x-ray examination were also presented, and the probabilities of genetic damage, and of development of leukemia or cancer were calculated. The allowable dose of exposure for radiation workers was discussed. It is important to take account of radiation quality, area of irradiation field, and posture of patients to minimize the radiation effect. The actual statistics on the x-ray exposure at the dentists, distribution of the dispersed radiation in the x-ray room, methods of protection against exposure, and plans and designs of the x-ray room were discussed. (Kaihara, S.)

  8. X ray imaging microscope for cancer research

    Science.gov (United States)

    Hoover, Richard B.; Shealy, David L.; Brinkley, B. R.; Baker, Phillip C.; Barbee, Troy W., Jr.; Walker, Arthur B. C., Jr.

    1991-01-01

    The NASA technology employed during the Stanford MSFC LLNL Rocket X Ray Spectroheliograph flight established that doubly reflecting, normal incidence multilayer optics can be designed, fabricated, and used for high resolution x ray imaging of the Sun. Technology developed as part of the MSFC X Ray Microscope program, showed that high quality, high resolution multilayer x ray imaging microscopes are feasible. Using technology developed at Stanford University and at the DOE Lawrence Livermore National Laboratory (LLNL), Troy W. Barbee, Jr. has fabricated multilayer coatings with near theoretical reflectivities and perfect bandpass matching for a new rocket borne solar observatory, the Multi-Spectral Solar Telescope Array (MSSTA). Advanced Flow Polishing has provided multilayer mirror substrates with sub-angstrom (rms) smoothnesss for the astronomical x ray telescopes and x ray microscopes. The combination of these important technological advancements has paved the way for the development of a Water Window Imaging X Ray Microscope for cancer research.

  9. Expanded beam x-ray optics calibration facility at the Daresbury Synchrotron

    DEFF Research Database (Denmark)

    Christensen, Finn Erland; Hornstrup, Allan; FREDERIKSEN, P; ABDALI, S; Grundsøe, Peter; SCHNOPPER, HW; LEWIS, R; HALL, CH; BOROZDIN, K

    1994-01-01

    interval from 6 kev to 12 kev, the facility features a 1D sheet of X-rays, approximately 200 mm wide, obtained from an extremely asymmetric reflection in large perfect crystals of Si. The beam is collimated to < 20 arcsec. Data from tests using large (approximately 250 mm long) beam expander crystals in...... the energy range from 6 - 12 kev are presented. The planned calibration of the two X-ray telescopes (XSPECT/SODART and JET-X) will be described....

  10. Crystal optics for hard-X-ray spectroscopy of highly charged ions

    OpenAIRE

    Beyer, H.F.; Attia, D.; Banas, D.; Bigot, E. -O. Le; Bosch, F.; Dousse, Jean-Claude; Förster, E; Gumberidze, A.; Hagmann, S; Heß, S.; Hoszowska, J.; Indelicato, P.; Jagodzinski, P.; Kozhuharov, Chr.; Krings, Th.

    2009-01-01

    A twin crystal-spectrometer assembly, operated in the focusing compensated asymmetric Laue geometry has been developed for accurate spectroscopy of fast highly charged heavy ions in the hard-X-ray region. Coupled to the focusing crystal optics is a specially developed two-dimensional position-sensitive X-ray detector which is necessary for retaining spectral resolution also for fast moving sources. We summarize the crystal optics and demonstrate the usefulness of the instrument for spectrosco...

  11. Parametric X-Ray Radiation

    Science.gov (United States)

    Shchagin, Alexander

    1997-10-01

    The main PXR properties [1,2] are considered in the paper: energy, width, smooth tuning of monochromatic PXR spectral line; fine structure and absolute differential yields of PXR in the vicinity of and at angular distances from Brag directions; angular spread of the PXR beam; the influence of incident electron energy and of the density effect on the PXR properties; linear polarization of PXR; background in PXR spectra. Experimental setups for linacs and the results of measurements are discussed. Experimental data are compared to theoretical calculations at PXR energies between 5 and 400 keV for incident electron energies ranging from 15 to 1200 MeV. Possible applications of PXR as a new source of a bright, tunable X-ray beam in science and industry are discussed. [1] A.V. Shchagin and N.A. Khizhnyak, NIM B119, 115-122 (1996). [2] A.V. Shchagin and X.K. Maruyama, "Parametric X-rays", a chapter in the book "Accelerator-based Atomic Physics Techniques and Applications", edited by S.M. Shafroth and J.C. Austin, AIP Press, 1997, pp 279-307.

  12. Full-field transmission x-ray imaging with confocal polycapillary x-ray optics

    OpenAIRE

    Sun, Tianxi; MacDonald, C. A.

    2013-01-01

    A transmission x-ray imaging setup based on a confocal combination of a polycapillary focusing x-ray optic followed by a polycapillary collimating x-ray optic was designed and demonstrated to have good resolution, better than the unmagnified pixel size and unlimited by the x-ray tube spot size. This imaging setup has potential application in x-ray imaging for small samples, for example, for histology specimens.

  13. X-ray crystal structure and small-angle X-ray scattering of sheep liver sorbitol dehydrogenase

    Energy Technology Data Exchange (ETDEWEB)

    Yennawar, Hemant [Pennsylvania State University, 8 Althouse Laboratory, University Park, PA 16802 (United States); Møller, Magda [Cornell High Energy Synchrotron Source, Ithaca, NY 14853 (United States); University of Copenhagen, DK-2100 Copenhagen (Denmark); Gillilan, Richard [Cornell High Energy Synchrotron Source, Ithaca, NY 14853 (United States); Yennawar, Neela, E-mail: nhy1@psu.edu [Pennsylvania State University, 8 Althouse Laboratory, University Park, PA 16802 (United States)

    2011-05-01

    The X-ray crystal structure and a small-angle X-ray scattering solution structure of sheep liver sorbitol dehydrogenase have been determined. The details of the interactions that enable the tetramer scaffold to be the functional biological unit have been analyzed. The X-ray crystal structure of sheep liver sorbitol dehydrogenase (slSDH) has been determined using the crystal structure of human sorbitol dehydrogenase (hSDH) as a molecular-replacement model. slSDH crystallized in space group I222 with one monomer in the asymmetric unit. A conserved tetramer that superposes well with that seen in hSDH (despite belonging to a different space group) and obeying the 222 crystal symmetry is seen in slSDH. An acetate molecule is bound in the active site, coordinating to the active-site zinc through a water molecule. Glycerol, a substrate of slSDH, also occupies the substrate-binding pocket together with the acetate designed by nature to fit large polyol substrates. The substrate-binding pocket is seen to be in close proximity to the tetramer interface, which explains the need for the structural integrity of the tetramer for enzyme activity. Small-angle X-ray scattering was also used to identify the quaternary structure of the tetramer of slSDH in solution.

  14. Observation of π backbonding features appearing in Fe 2p X-ray absorption spectra and Fe 1s-4p-1s resonant X-ray emission spectra of RbMn[Fe(CN)6

    International Nuclear Information System (INIS)

    Satellite features by p backbonding (metal-to-ligand charge transfer) were observed in both Fe 2p (L3,2-edge) X-ray absorption spectra and 1s-4p-1s resonant X-ray emission spectra for RbMn[Fe(CN)6], which can be theoretically explained using common parameters. Fe L3,2-edge and Mn L3,2-edge X-ray absorption spectra for low temperature phase are also presented.

  15. X-ray microtomography: applications and developments

    International Nuclear Information System (INIS)

    Full text: X-ray microtomography has followed a classical development path being originally available only to those with the expertise to piece together the often cumbersome components to required to make a practical x-ray microtomography system. Subsequent technological and scientific advances have meant that x-ray microtomography instruments are now off-the-shelf items with a cost well within the equipment budgets of research institutions and industry. The technological advances that have contributed to the development of x-ray microtomography include commercially available x-ray micro-sources, high-resolution CCD cameras and highspeed, low-cost computers. The scientific developments have been predominantly in image reconstruction. Some of these scientific developments are, with the advantage of hindsight, very simple while others, such as resolution enhancement using the Fresnel fringes in x-ray projection images, are not so intuitive. As a consequence of the availability of 'black-box' instruments, x-ray microtomography is spreading to a wide range of applications. The materials most suited to examination by x-ray microtomography are those with a medium level of x-ray absorption such as bone, teeth, rocks, porous metals, composite materials and plant materials. For these materials, 3D information can be obtained at resolutions comparable to the resolution of a high-quality optical microscope. A few of these applications will be demonstrated in the presentation. Technological advances that aid x-ray microtomography will continue with x-ray sources becoming smaller, computers becoming faster and CCD cameras having increased numbers of pixels. It will be interesting to see if nano x-ray microtomography is achieved. Developments in x-ray microtomography are required in areas such as contrast enhancement particularly for problematic materials such as soft tissue and low-density polymers. For low-density polymers x-ray absorption is very low while for soft tissue

  16. Cloning, purification, crystallization and X-ray crystallographic analysis of Ignicoccus hospitalis neelaredoxin

    International Nuclear Information System (INIS)

    Diffraction-quality crystals of I. hospitalis neelaredoxin have been produced. The cloning, expression, purification, crystallization and X-ray crystallographic analysis are reported. Superoxide reductases (SORs) are metalloproteins which constitute the most recently identified oxygen-detoxification system in anaerobic and microaerobic bacteria and archaea. SORs are involved in scavenging superoxide radicals from the cell by catalyzing the reduction of superoxide to hydrogen peroxide and are characterized by a catalytic nonhaem iron centre coordinated by four histidine ligands and one cysteine ligand. Ignicoccus hospitalis, a hyperthermophilic crenarchaeon, is known to have a neelaredoxin-type SOR that keeps toxic oxygen species levels under control. Blue crystals of recombinant I. hospitalis oxidized neelaredoxin (14.1 kDa, 124 residues) were obtained. These crystals diffracted to 2.4 Å resolution in-house at room temperature and belonged to the hexagonal space group P6222 or P6422, with unit-cell parameters a = b = 108, c = 64 Å. Cell-content analysis indicated the presence of one monomer in the asymmetric unit

  17. A beam expander facility for studying x-ray optics

    DEFF Research Database (Denmark)

    Christensen, Finn Erland; Hornstrup, Allan; Frederiksen, P.; Nilsson, C.; Grundsøe, Peter; Ørup, P.; Jacobsen, E.; Schnopper, H. W.; Lewis, R.; Hall, C.

    1992-01-01

    The detailed study of the performance of full scale x-ray optics often requires the illumination of large areas. This paper describes a beam expander facility at the Daresbury Synchrotron Radiation Facility. It combines monochromatization and beam expansion in one dimension. The beam expansion is...... obtained from an extremely asymmetric reflection in a large single crystal of Si. An expansion of a factor of 50 was obtained in one dimension. The expanded beam of ~85 mm is limited only by the crystal size. The facility is installed in a 12-m-long hutch. A specific application, in which a high throughput...... x-ray telescope will be studied, is described in detail. Review of Scientific Instruments is copyrighted by The American Institute of Physics....

  18. Anomalous x-ray scattering

    International Nuclear Information System (INIS)

    The availability of tunable synchrotron radiation has made it possible systematically to perform x-ray diffraction studies in regions of anomalous scattering near absorption edges, e.g. in order to derive phase information for crystal structure determination. An overview is given of recent experimental and theoretical work and discuss the properties of the anomalous atomic scattering factor, with emphasis on threshold resonances and damping effects. The results are applied to a discussion of the very strong anomalous dispersion recently observed near the L3 edge in a cesium complex. Also given is an overview of elements and levels where similar behavior can be expected. Finally, the influence of solid state and chemical effects on the absorption edge structure is discussed. 64 references

  19. Submicron X-ray diffraction

    International Nuclear Information System (INIS)

    At the Advanced Light Source in Berkeley the authors have instrumented a beam line that is devoted exclusively to x-ray micro diffraction problems. By micro diffraction they mean those classes of problems in Physics and Materials Science that require x-ray beam sizes in the sub-micron range. The beam line has a unity magnification toroidal mirror that produces a 50 by 200 micron focus just inside an x-ray hutch at the position of an x-y slit. The beam path in the hutch consists of source defining slits, a four bounce Ge or Si monochromator, followed by elliptically bent Kirkpatrick-Baez mirror pair which focuses the beam from the slits to sub micron dimensions (0.8 x 0.8 microns). An important feature of this arrangement is the ability to switch between white and monochromatic beams that are essential for characterizing crystals or crystal grains in the sub-micron range. Since sample rotation is fixed they have facilities for precision translation of the specimen to allow them to scan different crystal regions or grains. The sample stage rests on a state of the art six-circle diffractometer equipped with encoders in the main rotation stages calibrated to a second of arc. The detector is a 4K x 4K CCD (Bruker) with a 9 x 9 cm view area mounted on a detector arm that can be positioned around the sample. The detector itself can also be positioned to better than 1 micron along the detector arm. Using this facility they have been able to measure the orientation structure of single grains of passivated or buried Al interconnect test structures. Such structures or their equivalents are important in connecting individual components on integrated circuits. Their sub-micron dimensions result in very high current densities that can result in interconnect failures. The variation in sub-grain structure in a single grain is rich in detail. They have obtained detailed maps of misorientations in single grains using white beam Laue diffraction patterns From these they have been

  20. X-ray intensifying screens

    International Nuclear Information System (INIS)

    An x-ray intensifying screen comprises a support which has a luminescent composition comprising an isotropic phosphor and a polymer having an index of refraction within 0.02 of that of the phosphor over at least 80 percent of its emission spectrum. The support has an index of refraction up to or equal to 0.05 units higher than that of the phosphor and has a reflection optical density of at least 1.7 to light emitted by the phosphor. A preferred luminescent composition comprises Kl:Tl, Rbl:Tl at BaSrFCl:Eu mixed with two monomers such as 1-naphthylmethylmethacrylate, S(1-naphthylmethyl) thioacrylate, 1-bromo-2-naphthylacrylate, and benzyl methacrylate, coated on black anodised Al and polymerised in situ. The ratio of monomers is adjusted to give the desired refractive index. Other phosphors, polymers and supports are specified together with the preparation of the monomers and polymers. (author)

  1. X-ray flat panel detectors and X-ray tubes contributing to development of X-ray diagnostic systems

    International Nuclear Information System (INIS)

    X-ray flat panel detectors (FPDs) and X-ray tubes are key devices allowing X-ray diagnostic systems to support more sophisticated medical care. FPDs provide valuable information for the diagnosis of various diseases through the conversion of X-ray images of the human body into electronic signals, while X-ray tubes are used in a wide range of applications such as computed tomography (CT), angiography, fluoroscopy, mammography, and dental systems. Toshiba Electron Tubes and Devices Co., Ltd. has developed and commercialized FPDs providing high-quality diagnostic X-ray images with low dose exposure through the development of cutting-edge technologies including a fine crystal formation technology for cesium iodide (CsI) scintillators, thin-film transistor (TFT) arrays with photodiodes, and so on. In the field of X-ray tubes that can generate a high output of X-rays, we have developed a liquid metal hydrodynamic bearing (LM bearing) technology for various diagnostic systems including medical CT systems with a long lifetime and high rotation speed, and cardiovascular imaging systems with quiet operation. Furthermore, LM bearing technology reduces the burden on the environment by replacing insulating oil with water coolant for the cooling system and making the X-ray tubes more compact. (author)

  2. Imaging properties and its improvements of scanning/imaging x-ray microscope

    Energy Technology Data Exchange (ETDEWEB)

    Takeuchi, Akihisa, E-mail: take@spring8.or.jp; Uesugi, Kentaro; Suzuki, Yoshio [Japan Synchrotron Radiation Research Institute (JASRI / SPring-8), Sayo, Hyogo 679-5198 (Japan)

    2016-01-28

    A scanning / imaging X-ray microscope (SIXM) system has been developed at SPring-8. The SIXM consists of a scanning X-ray microscope with a one-dimensional (1D) X-ray focusing device and an imaging (full-field) X-ray microscope with a 1D X-ray objective. The motivation of the SIXM system is to realize a quantitative and highly-sensitive multimodal 3D X-ray tomography by taking advantages of both the scanning X-ray microscope using multi-pixel detector and the imaging X-ray microscope. Data acquisition process of a 2D image is completely different between in the horizontal direction and in the vertical direction; a 1D signal is obtained with the linear-scanning while the other dimensional signal is obtained with the imaging optics. Such condition have caused a serious problem on the imaging properties that the imaging quality in the vertical direction has been much worse than that in the horizontal direction. In this paper, two approaches to solve this problem will be presented. One is introducing a Fourier transform method for phase retrieval from one phase derivative image, and the other to develop and employ a 1D diffuser to produce an asymmetrical coherent illumination.

  3. Imaging properties and its improvements of scanning/imaging x-ray microscope

    International Nuclear Information System (INIS)

    A scanning / imaging X-ray microscope (SIXM) system has been developed at SPring-8. The SIXM consists of a scanning X-ray microscope with a one-dimensional (1D) X-ray focusing device and an imaging (full-field) X-ray microscope with a 1D X-ray objective. The motivation of the SIXM system is to realize a quantitative and highly-sensitive multimodal 3D X-ray tomography by taking advantages of both the scanning X-ray microscope using multi-pixel detector and the imaging X-ray microscope. Data acquisition process of a 2D image is completely different between in the horizontal direction and in the vertical direction; a 1D signal is obtained with the linear-scanning while the other dimensional signal is obtained with the imaging optics. Such condition have caused a serious problem on the imaging properties that the imaging quality in the vertical direction has been much worse than that in the horizontal direction. In this paper, two approaches to solve this problem will be presented. One is introducing a Fourier transform method for phase retrieval from one phase derivative image, and the other to develop and employ a 1D diffuser to produce an asymmetrical coherent illumination

  4. Development of confocal micro X-ray fluorescence instrument using two X-ray beams

    International Nuclear Information System (INIS)

    A new confocal micro X-ray fluorescence instrument was developed. This instrument has two independent micro X-ray tubes with Mo targets. A full polycapillary X-ray lens was attached to each X-ray tube. Another half polycapillary lens was attached to a silicon drift X-ray detector (SDD). The focal spots of the three lenses were adjusted to a common position. The effects of the excitation of two X-ray beams were investigated. The instrument enabled highly sensitive three-dimensional X-ray fluorescence analysis. We confirmed that the X-ray fluorescence intensity from the sample increased by applying the two independent X-ray tubes in confocal configuration. Elemental depth profiling of black wheat was demonstrated with the result that each element in the surface coat of a wheat grain showed unique distribution

  5. Acoustooptics of x-rays

    Energy Technology Data Exchange (ETDEWEB)

    Balakhanov, M.V.; Pustovoyt, V.I.; Radzhabov, R.U.; Khabibullayev, P.K.

    Scattering of x-rays by acoustic phonons in crystals during excitation of a noise phonon flux thermodynamically at equilibrium is analyzed from the standpoint of the dynamic diffraction theory, emphasis being put on the differences with the conventional acoustooptic effect attributable to lower frequencies and smaller amplitudes. The structural peak and the diffusional peak are calculated from known relations for the intensity of scattering in each mode, assuming that the Laue condition is satisfied. Interaction of x-rays and an acoustic wave is considered, the conditions for a diffraction peak being determined by the relations between location of that peak and angular dimensions of the structural peak. Experiments were performed in crystals of photosensitive piezoelectric semiconductors with phonon generation. Rectangular or variable-shape voltage pulses with amplitudes up to 800 V were applied to 6-60 ..mu..m thick CdS crystals at repetition rates up to 800 Hz. The electron concentration was (1.3-4.5) x 10/sup 14/ cm/sup -3/ and the electron mobility, according to saturation of the current-voltage characteristics, was differentially in time. The results reveal sharp anisotropy of scattering, evident in the dependence of scattering intensity on the angle of crystal rotation and the resulting lobar scattering pattern. Structural scattering varies exponentially and diffusional scattering varies linearly with increasing amplitude of the applied voltage. According to the dependence of the spectral density of phonon generation on the concentration of charge carriers, the phase of the scattering effect changes upon transition from the structural range to the diffusional range. 8 references, 3 figures.

  6. Soft x-ray interferometry

    International Nuclear Information System (INIS)

    The purpose of the soft x-ray interferometry workshop held at Lawrence Berkeley Laboratory was to discuss with the scientific community the proposed technical design of the soft x-ray Fourier-transform spectrometer being developed at the ALS. Different design strategies for the instrument's components were discussed, as well as detection methods, signal processing issues, and how to meet the manufacturing tolerances that are necessary for the instrument to achieve the desired levels of performance. Workshop participants were encouraged to report on their experiences in the field of Fourier transform spectroscopy. The ALS is developing a Fourier transform spectrometer that is intended to operate up to 100 eV. The motivation is solely improved resolution and not the throughput (Jaquinot) or multiplex (Fellgett) advantage, neither of which apply for the sources and detectors used in this spectral range. The proposed implementation of this is via a Mach-Zehnder geometry that has been (1) distorted from a square to a rhombus to get grazing incidence of a suitable angle for 100 eV and (2) provided with a mirror-motion system to make the path difference between the interfering beams tunable. The experiment consists of measuring the emergent light intensity (I(x)) as a function of the path difference (x). The resolving power of the system is limited by the amount of path difference obtainable that is 1 cm (one million half-waves at 200 angstrom wavelength) in the design thus allowing a resolving power of one million. The free spectral range of the system is limited by the closeness with which the function I(x) is sampled. It is proposed to illuminate a helium absorption cell with roughly 1%-band-width light from a monochromator thus allowing one hundred aliases without spectral overlap even for sampling of I(x) at one hundredth of the Nyquist frequency

  7. Trans-influence and axial interactions in low spin, tetragonal cobalt(II) complexes containing macrocyclic and/or cyano ligands. Pulse radiolytic studies in fluid solution, electron paramagnetic resonance spectra at 77 k, and single-crystal x-ray structures

    International Nuclear Information System (INIS)

    Investigations of the weak interactions between low spin cobalt(II) species and their axial ligands have been performed. X-ray structural studies of six-coordinate Co(N4)(OH2)22+ and Co(N4)(ClO4)2 complexes, where (N4) is an equatorially coordinated tetradentate macrocyclic ligand, reveal that the axial Co--ligand bond lengths are 0.3 to 0.5 A longer per bond than are the equatorial Co--ligand bond lengths. By means of the pulse radiolytic reductions of the corresponding cobalt(III) complexes, low spin cobalt(II) species of the types Co/sup II/(N4)L2 (L = NH3, NO2-, CN-) and Co/sup II/(CN)5X (X = Cl, CN) have been generated, and the rates of ligand exchange with water in the reduced species have been determined by a kinetic conductivity method. All the cobalt(II) species have been found to be very labile in two (axial) coordination positions, with an appreciable range of rate constants (k greater than or equal to 103 s-1) which depend on both the equatorial and the axial ligands. Electron paramagnetic resonance spectra have provided evidence for interactions with either one or two axial ligands (at 77 K) but on the whole have not provided definitive criteria regarding the coordination number of low spin cobalt(II) species in fluid solution. Comparison of the results of this and other studies suggests a strong trans influence in the axial ligand interactions of low spin cobalt(II) complexes. A simple three-center bonding model has been used to describe the weak axial interactions. This model also provides a convenient basis for interpreting the absorption spectrum of a Co/sup II/(N4)CN transient generated in the pulse radiolysis studies. It is inferred that the synergistic trans-influence deduced for low spin cobalt(II) species may be a significant factor in inner sphere electron transfer reactions

  8. Soft x-ray polarimeter laboratory tests

    Science.gov (United States)

    Murphy, Kendrah D.; Marshall, Herman L.; Schulz, Norbert S.; Jenks, Kevin; Sommer, Sophie J. B.; Marshall, Eric A.

    2010-07-01

    Multilayer-coated optics can strongly polarize X-rays and are central to a new design of a broad-band, soft X-ray polarimeter. We have begun laboratory work to verify the performance of components that could be used in future soft X-ray polarimetric instrumentation. We have reconfigured a 17 meter beamline facility, originally developed for testing transmission gratings for Chandra, to include a polarized X-ray source, an X-ray-dispersing transmission grating, and a multilayer-coated optic that illuminates a CCD detector. The X-rays produced from a Manson Model 5, multi-anode source are polarized by a multilayer-coated flat mirror. The current configuration allows for a 180 degree rotation of the source in order to rotate the direction of polarization. We will present progress in source characterization and system modulation measurements as well as null and robustness tests.

  9. X-rays for medical use

    Science.gov (United States)

    Hessenbruch, A.

    1995-11-01

    1995 is the centenary of the discovery of X-rays by the German physicist Wilhelm C Rontgen. In the past hundred years, the new rays have developed from being unknown to finding application in many walks of life, not least in medicine. This is so much so that in common speech the word `x-ray` refers not to a form of radiation but to an X-ray photograph taken for the purposes of diagnosis (as in: `I had an X-ray done to see if my leg was broken`). X-rays are now used routinely, and they are used both for diagnosis and for therapy. This paper will give an outline of the use of X-rays in medicine throughout our present century.

  10. Handbook of X-Ray Data

    CERN Document Server

    Zschornack, Günter

    2007-01-01

    This sourcebook is intended as an X-ray data reference for scientists and engineers working in the field of energy or wavelength dispersive X-ray spectrometry and related fields of basic and applied research, technology, or process and quality controlling. In a concise and informative manner, the most important data connected with the emission of characteristic X-ray lines are tabulated for all elements up to Z = 95 (Americium). This includes X-ray energies, emission rates and widths as well as level characteristics such as binding energies, fluorescence yields, level widths and absorption edges. The tabulated data are characterized and, in most cases, evaluated. Furthermore, all important processes and phenomena connected with the production, emission and detection of characteristic X-rays are discussed. This reference book addresses all researchers and practitioners working with X-ray radiation and fills a gap in the available literature.

  11. Clinical X-ray diagnostics. v. 1

    International Nuclear Information System (INIS)

    After introductory remarks on historical aspects of the development of X-ray diagnostics, the physical and technological fundamentals of the generation and recording of radiographs are elaborated. In a comprehensive chapter such topics as X-rays, X-ray tubes, X-ray generators, contrast media, interrelations between X-rays and patients as well as classical and recent methods of recording with regard to geometrical conditions, and of picture quality are outlined. Brief notes on analysis, documentation and filing of radiographs are added. Physico-technological fundamentals of radiation protection, remarks concerning radiation protection in the GDR, and special problems of radiation protection as to X-ray diagnostics are discussed

  12. Radiation safety in X-ray facilities

    International Nuclear Information System (INIS)

    The guide specifies the radiation safety requirements for structural shielding and other safety arrangements used in X-ray facilities in medical and veterinary X-ray activities and in industry, research and education. The guide is also applicable to premises in which X-ray equipment intended for radiation therapy and operating at a voltage of less than 25 kV is used. The guide applies to new X-ray facilities in which X-ray equipment that has been used elsewhere is transferred. The radiation safety requirements for radiation therapy X-ray devices operating at a voltage exceeding 25 kV, and for the premices in which such devices are used, are set out in Guide ST 2.2

  13. Radiation safety in X-ray facilities

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-09-01

    The guide specifies the radiation safety requirements for structural shielding and other safety arrangements used in X-ray facilities in medical and veterinary X-ray activities and in industry, research and education. The guide is also applicable to premises in which X-ray equipment intended for radiation therapy and operating at a voltage of less than 25 kV is used. The guide applies to new X-ray facilities in which X-ray equipment that has been used elsewhere is transferred. The radiation safety requirements for radiation therapy X-ray devices operating at a voltage exceeding 25 kV, and for the premices in which such devices are used, are set out in Guide ST 2.2.

  14. Ligand placement based on prior structures: the guided ligand-replacement method

    Energy Technology Data Exchange (ETDEWEB)

    Klei, Herbert E. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Bristol-Myers Squibb, Princeton, NJ 08543-4000 (United States); Moriarty, Nigel W., E-mail: nwmoriarty@lbl.gov; Echols, Nathaniel [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Terwilliger, Thomas C. [Los Alamos National Laboratory, Los Alamos, NM 87545-0001 (United States); Baldwin, Eric T. [Bristol-Myers Squibb, Princeton, NJ 08543-4000 (United States); Natural Discovery LLC, Princeton, NJ 08542-0096 (United States); Pokross, Matt; Posy, Shana [Bristol-Myers Squibb, Princeton, NJ 08543-4000 (United States); Adams, Paul D. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); University of California at Berkeley, Berkeley, CA 94720-1762 (United States)

    2014-01-01

    A new module, Guided Ligand Replacement (GLR), has been developed in Phenix to increase the ease and success rate of ligand placement when prior protein-ligand complexes are available. The process of iterative structure-based drug design involves the X-ray crystal structure determination of upwards of 100 ligands with the same general scaffold (i.e. chemotype) complexed with very similar, if not identical, protein targets. In conjunction with insights from computational models and assays, this collection of crystal structures is analyzed to improve potency, to achieve better selectivity and to reduce liabilities such as absorption, distribution, metabolism, excretion and toxicology. Current methods for modeling ligands into electron-density maps typically do not utilize information on how similar ligands bound in related structures. Even if the electron density is of sufficient quality and resolution to allow de novo placement, the process can take considerable time as the size, complexity and torsional degrees of freedom of the ligands increase. A new module, Guided Ligand Replacement (GLR), was developed in Phenix to increase the ease and success rate of ligand placement when prior protein–ligand complexes are available. At the heart of GLR is an algorithm based on graph theory that associates atoms in the target ligand with analogous atoms in the reference ligand. Based on this correspondence, a set of coordinates is generated for the target ligand. GLR is especially useful in two situations: (i) modeling a series of large, flexible, complicated or macrocyclic ligands in successive structures and (ii) modeling ligands as part of a refinement pipeline that can automatically select a reference structure. Even in those cases for which no reference structure is available, if there are multiple copies of the bound ligand per asymmetric unit GLR offers an efficient way to complete the model after the first ligand has been placed. In all of these applications, GLR

  15. X-ray microlaminography with polycapillary optics

    International Nuclear Information System (INIS)

    We demonstrate layer-by-layer x-ray microimaging using polycapillary optics. The depth resolution is achieved without sample or source rotation and in a way similar to classical tomography or laminography. The method takes advantage from large angular apertures of polycapillary optics and from their specific microstructure, which is treated as a coded aperture. The imaging geometry is compatible with polychromatic x-ray sources and with scanning and confocal x-ray fluorescence setups.

  16. X-ray microlaminography with polycapillary optics

    Science.gov (United States)

    Dąbrowski, K. M.; Dul, D. T.; Wróbel, A.; Korecki, P.

    2013-06-01

    We demonstrate layer-by-layer x-ray microimaging using polycapillary optics. The depth resolution is achieved without sample or source rotation and in a way similar to classical tomography or laminography. The method takes advantage from large angular apertures of polycapillary optics and from their specific microstructure, which is treated as a coded aperture. The imaging geometry is compatible with polychromatic x-ray sources and with scanning and confocal x-ray fluorescence setups.

  17. X-ray spot film device

    International Nuclear Information System (INIS)

    Improvements are described in an X-ray spot film device which is used in conjunction with an X-ray table to make a selected number of radiographic exposures on a single film and to perform fluoroscopic examinations. To date, the spot film devices consist of two X-ray field defining masks, one of which is moved manually. The present device is more convenient to use and speeds up the procedure. (U.K.)

  18. X-ray microlaminography with polycapillary optics

    Energy Technology Data Exchange (ETDEWEB)

    Dabrowski, K. M.; Dul, D. T.; Wrobel, A.; Korecki, P. [Institute of Physics, Jagiellonian University, Reymonta 4, 30-059 Krakow (Poland)

    2013-06-03

    We demonstrate layer-by-layer x-ray microimaging using polycapillary optics. The depth resolution is achieved without sample or source rotation and in a way similar to classical tomography or laminography. The method takes advantage from large angular apertures of polycapillary optics and from their specific microstructure, which is treated as a coded aperture. The imaging geometry is compatible with polychromatic x-ray sources and with scanning and confocal x-ray fluorescence setups.

  19. Applications of soft x-ray lasers

    Energy Technology Data Exchange (ETDEWEB)

    Skinner, C.H.

    1993-08-01

    The high brightness and short pulse duration of soft x-ray lasers provide unique advantages for novel applications. Imaging of biological specimens using x-ray lasers has been demonstrated by several groups. Other applications to fields such as chemistry, material science, plasma diagnostics, and lithography are beginning to emerge. We review the current status of soft x-ray lasers from the perspective of applications, and present an overview of the applications currently being developed.

  20. X-ray data booklet. Revision

    International Nuclear Information System (INIS)

    A compilation of data is presented. Included are properties of the elements, electron binding energies, characteristic x-ray energies, fluorescence yields for K and L shells, Auger energies, energy levels for hydrogen-, helium-, and neonlike ions, scattering factors and mass absorption coefficients, and transmission bands of selected filters. Also included are selected reprints on scattering processes, x-ray sources, optics, x-ray detectors, and synchrotron radiation facilities

  1. X-ray data booklet. Revision

    Energy Technology Data Exchange (ETDEWEB)

    Vaughan, D. (ed.)

    1986-04-01

    A compilation of data is presented. Included are properties of the elements, electron binding energies, characteristic x-ray energies, fluorescence yields for K and L shells, Auger energies, energy levels for hydrogen-, helium-, and neonlike ions, scattering factors and mass absorption coefficients, and transmission bands of selected filters. Also included are selected reprints on scattering processes, x-ray sources, optics, x-ray detectors, and synchrotron radiation facilities. (WRF)

  2. Novel optics for X-ray telescopes

    Czech Academy of Sciences Publication Activity Database

    Hudec, René; Pína, L.; Semencová, V.; Inneman, A.; Skulinová, Michaela; Nekola, Martin

    Berlin : Springer, 2009 - (Brandl, B.), s. 1-8 ISBN 978-90-481-2232-5. [400 Years of Astronomical Telescopes. Leiden (NL), 29.09.2008-02.10.2008] R&D Projects: GA AV ČR IAAX01220701; GA ČR GP202/07/P510 Institutional research plan: CEZ:AV0Z10030501 Keywords : X-ray telescopes * X-ray optics * X-ray astronomy Subject RIV: BN - Astronomy, Celestial Mechanics, Astrophysics

  3. X-ray transient AGN and galaxies

    OpenAIRE

    Grupe, D.

    2001-01-01

    X-ray transience is the most extreme form of variability observed in AGN or normal in-active galaxies. While factors of 2-3 on timescales of days to years are quite commen among AGN, X-ray transients appear only once and vanish from the X-ray sky years later. The ROSAT All-Sky Survey was the tool to discover these sources. X-ray transience in AGN or galaxies can be caused by dramatic changes in the accretion rate of the central black hole or by changes of the properties of the accretion disk.

  4. Microfabrication of hard x-ray lenses

    DEFF Research Database (Denmark)

    Stöhr, Frederik

    characterization details that cannot be obtained by other means. The respective x-ray techniques largely benefit from continuously improved x-ray sources, x-ray detectors and x-ray optics. For instance, some techniques aiming for structural investigation of poly-crystalline materials directly benefit from more...... by their potential for compact integration, which makes them cost-effective, easy to handle and stable on-axis optics. A Si-CRL comprises multiple bi-parabolic cylindrical cavities. The bi-parabolic patterns are defined lithographically and vertically transferred into the Si substrate using deep reactive ion etching...

  5. Advanced X-ray diffractive optics

    OpenAIRE

    Vila-Comamala, J.; Jefimovs, K.; Pilvi, T.; Ritala, M; Sarkar, S S; Solak, H H; Guzenko, V.A.; Stampanoni, M.; Marone, F.; J. Raabe; G. Tzvetkov; Fink, R H; Grolimund, D.; Borca, C.N.; Kaulich, B

    2009-01-01

    X-ray microscopy greatly bene�ts from the advances in x-ray optics. At the Paul Scherrer Institut, developments in x-ray di�ractive optics include the manufacture and optimization of Fresnel zone plates (FZPs) and di�ractive optical elements for both soft and hard x-ray regimes. In particular, we demonstrate here a novel method for the production of ultra-high resolution FZPs. This technique is based on the deposition of a zone plate material (iridium) onto the sidewalls of a p...

  6. Microscopic x-ray luminescence computed tomography

    Science.gov (United States)

    Zhang, Wei; Zhu, Dianwen; Zhang, Kun; Li, Changqing

    2015-03-01

    X-ray luminescence computed tomography (XLCT) was emerged as a new hybrid imaging modality, in which the x-rays are used to excite phosphors emitting optical photons to be measured for imaging. In this paper, we reported a microscopic x-ray luminescence computed tomography (microXLCT) with a spatial resolution up to hundreds of micrometers for deep targets. We use a superfine x-ray pencil beam to scan the phosphor targets. The superfine x-ray pencil beam is generated by a small collimator mounted in front of a powerful x-ray tube (93212, Oxford Instrument). A CT detector is used to image the x-ray beam. We have generated an x-ray beam with a diameter of 192 micrometers with a collimator of 100 micrometers in diameter. The emitted optical photons on the top surface of phantom are reflected by a mirror and acquired by an electron multiplier charge-coupled device (EMCCD) camera (C9100-13, Hamamatsu Photonics). The microXLCT imaging system is built inside an x-ray shielding and light tight cabinet. The EMCCD camera is placed in a lead box. All the imaging components are controlled by a VC++ program. The optical photon propagation is modeled with the diffusion equation solved by the finite element method. We have applied different regularization methods including L2 and L1 in the microXLCT reconstruction algorithms. Numerical simulations and phantom experiments are used to validate the microXLCT imaging system.

  7. Imaging with x-ray lasers

    Energy Technology Data Exchange (ETDEWEB)

    Da Silva, L.B.; Cauble, B.; Frieders, G.; Koch, J.A.; MacGowan, B.J.; Matthews, D.L.; Mrowka, S.; Ress, D.; Trebes, J.E.; Weiland, T.L.

    1993-11-01

    Collisionally pumped soft x-ray lasers now operate over a wavelength range extending from 35--300 {Angstrom}. These sources have high peak brightness and are now being utilized for x-ray imaging and plasma interferometry. In this paper we will describe our efforts to probe long scalelength plasmas using Moire deflectrometry and soft x-ray imaging. The progress in the development of short pulse x-ray lasers using a double pulse irradiation technique which incorporates a travelling wave pump will also be presented.

  8. X-ray Emission from Elliptical Galaxies

    OpenAIRE

    Sarazin, Craig L.

    1996-01-01

    Elliptical galaxies are generally luminous sources of X-ray radiation, and contain large amounts of hot, interstellar gas. In the brighter X-ray galaxies, the inferred masses of hot gas are consistent with those expected given the present rates of stellar mass loss. The required rates of heating of the gas are also roughly consistent with those expected from the motions of gas losing stars. X-ray observations, particularly X-ray spectra, require a low rate of Type Ia supernova heating and che...

  9. X-ray Observations of Planetary Nebulae

    OpenAIRE

    Guerrero, M. A.; Chu, Y.-H.; Gruendl, R A

    2003-01-01

    Planetary nebulae (PNe) are an exciting addition to the zoo of X-ray sources. Recent Chandra and XMM-Newton observations have detected diffuse X-ray emission from shocked fast winds in PN interiors as well as bow-shocks of fast collimated outflows impinging on the nebular envelope. Point X-ray sources associated with PN central stars are also detected, with the soft X-ray (>0.5 keV) emission from instability shocks in the fast stellar wind itself or from a low-mass companion's coronal activit...

  10. Hard X-ray Modulation Telescope

    Institute of Scientific and Technical Information of China (English)

    LU Fangjun

    2011-01-01

    The Hard X-ray Modulation Telescope (HXMT) will be China's first astronomical satellite. On board HXMT there are three kinds of slat-collimated telescopes, the High Energy X-ray Telescope (HE, 20-250 keV, 5000 cm^2), the Medium Energy X-ray Telescope (ME, 5-30 keV, 952 cm^2), and the Low Energy X-ray Telescope (LE, 1-15 keV, 384 cm^2).

  11. X-ray pulsar rush in 1998

    International Nuclear Information System (INIS)

    We present recent remarkable topics about discoveries of X-ray pulsars. 1. Pulsations from two Soft Gamma-ray Repeaters: These pulsars have enormously strong magnetic field (B ∼ 1015 G), thus these are called as 'magnetar', new type of X-ray pulsars. 2. New Crab-like pulsars: These discoveries lead to suggesting universality of Crab-like pulsars. 3. An X-ray bursting millisecond pulsar: This is strong evidence for the recycle theory of generating radio millisecond pulsars. 4. X-ray pulsar rush in the SMC: This indicates the younger star formation history in the SMC. (author)

  12. The Lunar X-ray Observatory (LXO)

    Science.gov (United States)

    Porter, F. Scott

    2008-01-01

    X-ray emission from charge exchange recombination between the highly ionized solar wind and neutral material i n Earth's magnetosheath has complicated x-ray observations of celestial objects with x-ray observatories including ROSAT, Chandra, XMM-Newton, and Suzaku. However, the charge-exchange emission can also be used as an important diagnostic of the solar-wind interacting with the magnetosheath. Soft x-ray observations from low-earth orbit or even the highly eccentric orbits of Chandra and XMM-Newton are likely superpositions of the celestial object of interest, the true extra-solar soft x-ray background, geospheric charge exchange, and heliospheric charge exchange. We show that with a small x-ray telescope placed either on the moon, in a similar vein as the Apollo ALSOP instruments, or at a stable orbit near L1, we can begin t o disentangle the complicated emission structure in the soft x-ray band. Here we present initial results of a feasibility study recently funded by NASA t o place a small x-ray telescope on the lunar surface. The telescope operates during lunar night to observe charge exchange interactions between the solar wind and magnetospheric neutrals, between the solar wind and the lunar atmosphere, and an unobstructed view of the soft x-ray background without the geospheric component.

  13. Ultrashort X-ray pulse science

    Energy Technology Data Exchange (ETDEWEB)

    Chin, Alan Hap [Univ. of California, Berkeley, CA (US). Dept. of Physics; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    1998-05-01

    A variety of phenomena involves atomic motion on the femtosecond time-scale. These phenomena have been studied using ultrashort optical pulses, which indirectly probe atomic positions through changes in optical properties. Because x-rays can more directly probe atomic positions, ultrashort x-ray pulses are better suited for the study of ultrafast structural dynamics. One approach towards generating ultrashort x-ray pulses is by 90{sup o} Thomson scattering between terawatt laser pulses and relativistic electrons. Using this technique, the author generated {approx} 300 fs, 30 keV (0.4 {angstrom}) x-ray pulses. These x-ray pulses are absolutely synchronized with ultrashort laser pulses, allowing femtosecond optical pump/x-ray probe experiments to be performed. Using the right-angle Thomson scattering x-ray source, the author performed time-resolved x-ray diffraction studies of laser-perturbated InSb. These experiments revealed a delayed onset of lattice expansion. This delay is due to the energy relaxation from a dense electron-hole plasma to the lattice. The dense electron-hole plasma first undergoes Auger recombination, which reduces the carrier concentration while maintaining energy content. Longitudinal-optic (LO) phonon emission then couples energy to the lattice. LO phonon decay into acoustic phonons, and acoustic phonon propagation then causes the growth of a thermally expanded layer. Source characterization is instrumental in utilizing ultrashort x-ray pulses in time-resolved x-ray spectroscopies. By measurement of the electron beam diameter at the generation point, the pulse duration of the Thomson scattered x-rays is determined. Analysis of the Thomson scattered x-ray beam properties also provides a novel means of electron bunch characterization. Although the pulse duration is inferred for the Thomson scattering x-ray source, direct measurement is required for other x-ray pulse sources. A method based on the laser-assisted photoelectric effect (LAPE) has

  14. X-ray pulsars: a review

    CERN Document Server

    Caballero, I

    2012-01-01

    Accreting X-ray pulsars are among the most luminous objects in the X-ray sky. In highly magnetized neutron stars (B~10^12 G), the flow of matter is dominated by the strong magnetic field. The general properties of accreting X-ray binaries are presented, focusing on the spectral characteristics of the systems. The use of cyclotron lines as a tool to directly measure a neutron star's magnetic field and to test the theory of accretion are discussed. We conclude with the current and future prospects for accreting X-ray binary studies.

  15. Ultrashort X-ray pulse science

    International Nuclear Information System (INIS)

    A variety of phenomena involves atomic motion on the femtosecond time-scale. These phenomena have been studied using ultrashort optical pulses, which indirectly probe atomic positions through changes in optical properties. Because x-rays can more directly probe atomic positions, ultrashort x-ray pulses are better suited for the study of ultrafast structural dynamics. One approach towards generating ultrashort x-ray pulses is by 90o Thomson scattering between terawatt laser pulses and relativistic electrons. Using this technique, the author generated ∼ 300 fs, 30 keV (0.4 (angstrom)) x-ray pulses. These x-ray pulses are absolutely synchronized with ultrashort laser pulses, allowing femtosecond optical pump/x-ray probe experiments to be performed. Using the right-angle Thomson scattering x-ray source, the author performed time-resolved x-ray diffraction studies of laser-perturbated InSb. These experiments revealed a delayed onset of lattice expansion. This delay is due to the energy relaxation from a dense electron-hole plasma to the lattice. The dense electron-hole plasma first undergoes Auger recombination, which reduces the carrier concentration while maintaining energy content. Longitudinal-optic (LO) phonon emission then couples energy to the lattice. LO phonon decay into acoustic phonons, and acoustic phonon propagation then causes the growth of a thermally expanded layer. Source characterization is instrumental in utilizing ultrashort x-ray pulses in time-resolved x-ray spectroscopies. By measurement of the electron beam diameter at the generation point, the pulse duration of the Thomson scattered x-rays is determined. Analysis of the Thomson scattered x-ray beam properties also provides a novel means of electron bunch characterization. Although the pulse duration is inferred for the Thomson scattering x-ray source, direct measurement is required for other x-ray pulse sources. A method based on the laser-assisted photoelectric effect (LAPE) has been

  16. X-rays pinpoint tumour targets

    International Nuclear Information System (INIS)

    When a surgeon in Birmingham used an X-ray photograph to guide the removal of a needle buried in a woman's hand in January 1896, it became the first X-ray guided operation in medical history. Since then X-rays have been widely used for medical imaging, and 'computed tomography' now provides us with exquisite 2D cross-sectional images of the human body. The technique creates images by passing X-rays along a plane through the body and recording the transmitted signals from various angles. A 'CT scan' lets us locate and visualize tumours with a resolution of 1 mm. But there is more to X-rays than imaging - they can also treat patients by killing cancerous tumours. When X-rays interact with tissue, they release highly reactive radicals that break the double strands in DNA molecules and cause the rapidly dividing cancerous cells to die. But because X-rays kill both healthy and diseased tissue in equal measure, it is vital to minimize the radiation received by healthy organs and tissue surrounding the tumour. The goal of radiotherapy is to find the precise location of a tumour using a CT scan - or other imaging technique - and then concentrate the X-rays on it to destroy the diseased tissue. In the August issue of Physics World Matin Durrani describes how intensity-modulated radiation therapy can deliver precise doses of X-rays to tumours while leaving surrounding, healthy tissue relatively unscathed. (U.K.)

  17. Linkage Isomerism in Transition-Metal Complexes of Mixed (Arylcarboxamido)(arylimino)pyridine Ligands

    OpenAIRE

    Boyce, David W.; Salmon, Debra J.; Tolman, William B.

    2014-01-01

    The synthesis of a series of asymmetric mixed 2,6-disubstituted (arylcarboxamido)(arylimino)pyridine ligands and their coordination chemistry toward a series of divalent first-row transition metals (Cu, Co, and Zn) have been explored. Complexes featuring both anionic N,N′,N″-carboxamido and neutral O,N,N′-carboxamide coordination have been prepared and characterized by X-ray crystallography, cyclic voltammetry, and UV–visible and EPR spectroscopy. Specifically, RLM(X) (M = Cu; X = Cl–, OAc–) ...

  18. X-ray imaging using a tunable coherent X-ray source based on parametric X-ray radiation

    International Nuclear Information System (INIS)

    A novel X-ray source based on parametric X-ray radiation (PXR) has been employed for X-ray imaging at the Laboratory for Electron Beam Research and Application (LEBRA), Nihon University. Notable features of PXR are tunable energy, monochromaticity with spatial chirp, narrow local bandwidth and spatial coherence. Since the X-ray beam from the PXR system has a large irradiation area with uniform flux density, the PXR-based source is suited for X-ray imaging, especially for application to phase-contrast imaging. Despite the cone-like X-ray beam, diffraction-enhanced imaging (DEI) can be employed as a phase contrast imaging technique. DEI experiments were performed using 14- to 34-keV X-rays and the phase-gradient images were obtained. The results demonstrated the capability of PXR as an X-ray source for phase-contrast imaging with a large irradiation field attributed to the cone-beam effect. Given the significant properties of the LEBRA-PXR source, the result suggests the possible construction of a compact linac-driven PXR-Imaging instrument and its application to medical diagnoses

  19. X-ray studies of polymer/gold nanocomposites

    International Nuclear Information System (INIS)

    We demonstrate that x-ray reflection standing wave fluorescence spectroscopy is a highly sensitive technique for the determination of the distribution of metal nanoparticles inside polymer thin films. We investigate both the depth profile and the in-plane spatial correlation of gold nanoparticles in an asymmetric polystyrene-b-poly(2-vinylpyridine) block copolymer film. These copolymer films self-assemble into alternating, nanometer-sized domains that are, upon annealing, selectively decorated by thermally evaporated metal nanoparticles to form metal/polymer composites. copyright 1999 American Institute of Physics

  20. On the universal X-ray luminosity function of binary X-ray sources in galaxies

    OpenAIRE

    Postnov, K. A.

    2002-01-01

    The empirically determined universal power-law shape of X-ray luminosity function of high mass X-ray binaries in galaxies is explained by fundamental mass-luminosity and mass-radius relations for massive stars.

  1. Wide field x-ray telescopes: Detecting x-ray transients/afterglows related to GRBs

    International Nuclear Information System (INIS)

    The recent discovery of X-ray afterglows of GRBs opens the possibility of analyses of GRBs by their X-ray detections. However, imaging X-ray telescopes in current use mostly have limited fields of view. Alternative X-ray optics geometries achieving very large fields of view have been theoretically suggested in the 70's but not constructed and used so far. We review the geometries and basic properties of the wide-field X-ray optical systems based on one- and two-dimensional lobster-eye geometry and suggest technologies for their development and construction. First results of the development of double replicated X-ray reflecting flats for use in one-dimensional X-ray optics of lobster-eye type are presented and discussed. The optimum strategy for locating GRBs upon their X-ray counterparts is also presented and discussed

  2. A structural basis for Staphylococcal complement subversion: X-ray structure of the complement-binding domain of Staphylococcus aureus protein Sbi in complex with ligand C3d

    OpenAIRE

    Clark, E. A.; Crennell, S.; Upadhyay, A.; Zozulya, A. V.; Mackay, J. D.; Svergun, D.I.; Bagby, S; van den Elsen, J. M.

    2011-01-01

    The structure of the complement-binding domain of Staphylococcus aureus protein Sbi (Sbi-IV) in complex with ligand C3d is presented. The 1.7 Å resolution structure reveals the molecular details of the recognition of thioester-containing fragment C3d of the central complement component C3, involving interactions between residues of Sbi-IV helix α2 and the acidic concave surface of C3d. The complex provides a structural basis for the binding preference of Sbi for native C3 over C3b and explain...

  3. Multicell X-ray detector

    International Nuclear Information System (INIS)

    A detector for X-radiation or other ionizing radiation is described comprising a pair of curved metal bars lying in spaced apart parallel planes. Ceramic members are bonded to the respective bars in facing relationship. Each ceramic member has a plurality of radially extending circumferentially spaced grooves facing similar grooves in the other member. A plurality of electrode plates are held in juxtaposed and circumferentially spaced apart relationship by disposing their respective upper and lower edges in the grooves of opposed ceramic members. The faces of adjacent electrode plates define gas-filled gaps in which photoelectron-ion pairs are produced when radiation enters from the front edges of the plates. The above described assembly is disposed within a pressurized gas-filled chamber having an X-ray transmissive window adjacent the front edges of the plates. A cover encloses the chamber. It has insulator feed-throughs for connecting the electrode plates with external electric circuits. Photoelectrons and/or ions, created by the ionizing radiation, are collected on the electrode plates and thereby generate an electrical signal which corresponds to the incident ionizing radiation. (Auth.)

  4. X-ray radiography facility

    International Nuclear Information System (INIS)

    The paper described a radiographic apparatus containing a radiation source, a diaphragm with collimating windows and a cassette holder with a cassette for the X-ray film. In order to increase the efficiency and quality of monitoring, the diaphragm and the cassette are made in the form of cylindrical shells, the centre of curvature of which coincides with the position of the radiation source focus. Each collimating window of the diaphragm is made in the form of two coaxially connected truncated cones, joined at the large bases in such a way that the angle at the vertex of the cone nearer the source is not less than the central angle with the vertex at the focus of the radiation source supported by the larger base, and 15-300 less than the angle at the vertex of the cone further from the source. By this means monitoring efficiency is increased by a factor of 1.5-2 and the quality of the radiographs improved. The apparatus is used for flaw detection in cylindrical objects. (author)

  5. Diffraction leveraged modulation of X-ray pulses using MEMS-based X-ray optics

    Energy Technology Data Exchange (ETDEWEB)

    Lopez, Daniel; Shenoy, Gopal; Wang, Jin; Walko, Donald A.; Jung, Il-Woong; Mukhopadhyay, Deepkishore

    2016-08-09

    A method and apparatus are provided for implementing Bragg-diffraction leveraged modulation of X-ray pulses using MicroElectroMechanical systems (MEMS) based diffractive optics. An oscillating crystalline MEMS device generates a controllable time-window for diffraction of the incident X-ray radiation. The Bragg-diffraction leveraged modulation of X-ray pulses includes isolating a particular pulse, spatially separating individual pulses, and spreading a single pulse from an X-ray pulse-train.

  6. Lenses for Soft X-Rays and X-ray Microscopy Experiments

    International Nuclear Information System (INIS)

    This paper discusses the development of zone plates as x-ray lenses by the use of a uv-holographic lithography technique. Condenser zone plates as well as scanning x-ray microscopes are described. In addition, results of x-ray microscopy experiments are presented, which have been performed with an imaging x-ray microscope installed at the BESSY electron storage ring in Berlin

  7. Crystallization and X-ray diffraction studies of arginine kinase from the white Pacific shrimp Litopenaeus vannamei

    International Nuclear Information System (INIS)

    The crystallization and preliminary X-ray diffraction analysis at 1.25 Å resolution of free-ligand arginine kinase from the Pacific whiteleg shrimp Litopenaeus vannamei are reported. Crystals belong to space group P212121, phases were determined by molecular replacement and refinement was performed with Phenix. Crystals of an unligated monomeric arginine kinase from the Pacific whiteleg shrimp Litopenaeus vannamei (LvAK) were successfully obtained using the microbatch method. Crystallization conditions and preliminary X-ray diffraction analysis to 1.25 Å resolution are reported. Data were collected at 100 K on NSLS beamline X6A. The crystals belonged to space group P212121, with unit-cell parameters a = 56.5, b = 70.2, c = 81.7 Å. One monomer per asymmetric unit was found, with a Matthews coefficient (VM) of 2.05 Å3 Da−1 and 40% solvent content. Initial phases were determined by molecular replacement using a homology model of LvAK as the search model. Refinement was performed with PHENIX, with final Rwork and Rfree values of 0.15 and 0.19, respectively. Biological analysis of the structure is currently in progress

  8. X-ray structure of W(CO)3(PPri3)2(H2O)·THF. Isotopic exchange between H2O and η2-D2 ligands and their competitive binding to tungsten

    International Nuclear Information System (INIS)

    Reactions of water with M(CO)3(PR3)2 and M(CO)3(PR3)2(η2-H2) [M = Mo, W; R = Cy (cyclohexyl), i-Pr] have been studied in various organic solvents. Infrared studied of the products showed v(OH) modes at widely varying positions, but no clear evidence for oxidative addition of water was found. The aquo complex W(CO)3(P-i-Pr3)2(H2O)·THF was isolated from THF and structurally characterized. A long W-O distance of 2.32 angstrom was observed for the reversibly bound H2O ligand, which also undergoes hydrogen bonding interactions with both lattice THF and a CO on an adjacent molecule. Water was found to instantaneously displace the dihydrogen ligand in M(CO)3(PR3)2(η2-H2) in THF solution to give aquo complexes, but in hexane H2 remained bound under H2 atmosphere. NMR spectra of the aquo complexes showed rapid exchange between free and coordinated water at 298 K. Isotopic exchange of W(CO)3(P-i-Pr3)2(η2-D2) with H2O under D2 atmosphere took place in THF or toluene giving W(CO)3(P-i-Pr3)2(D2O)

  9. X-ray topography and multiple diffraction

    International Nuclear Information System (INIS)

    A short summary on X-ray topography, which is based on the dynamical theory of X-ray diffraction, is made. The applications and properties related to the use of the multiple diffraction technique are analized and discussed. (L.C.)

  10. Proton induced X-ray emission analysis

    International Nuclear Information System (INIS)

    The developments in proton induced X-ray emission analysis are reviewed. Techniques for analyzing thick and thin samples of different origin are described. Discussions on the application of proton induced X-ray emission analysis in different fields, comparison of the sensitivity of this method with other analytical techniques, its limitations and possible improvements are presented

  11. Rotatable target for x-ray tubes

    International Nuclear Information System (INIS)

    Distorsion of the focal trace results in reduction of X-ray intensity, which may stop the desired use of the X-ray tube early. This distorsion can be avoided almost by use of molybdenum alloys for base body and substrate. Different alloys together with belonging measured values are described. (J.K.)

  12. X-ray diagnosis in birds

    International Nuclear Information System (INIS)

    The author describes techniques of X- ray examination in birds and the advantages of using contrast medium. He gives the medical indications of such examinations and lists the main anatomical features to be well known in birds for a better interpretation of X-ray pictures

  13. X-ray spectroscopy of magnetic CVs

    Science.gov (United States)

    Matt, Giorgio

    I discuss two topics in X-ray spectroscopy of magnetic CVs: reflection from the white dwarf surface, and opacity effects in the post shock plasma. I also briefly mention future observational perspectives, with particular emphasis on the Constellation X-ray mission.

  14. Tracing the X-Ray Trail

    Science.gov (United States)

    What you need to know about… Tracing the X-ray Trail If you’ve just completed an x-ray, computed tomography (CT), magnetic resonance (MR) Start here! or other diagnostic imaging procedure, you probably want to know when you will ... los rayos X Si acaba de hacerse una radiografía, tomografía ¡Empezar ...

  15. Coccidioidomycosis - chest x-ray (image)

    Science.gov (United States)

    This chest x-ray shows the affects of a fungal infection, coccidioidomycosis. In the middle of the left lung (seen on the ... defined borders. Other diseases that may explain these x-ray findings include lung abscesses, chronic pulmonary tuberculosis, chronic ...

  16. X-ray diagnosis of retropatellar diseases

    International Nuclear Information System (INIS)

    The article reports on a comprehensive, stepwise diagnosis in diseases of the knee joints. This includes a description of the indication, the technique of taking X-ray films, and X-ray findings, as well as arthrography of the femoropatellar joint in retropatellar diseases such as chondropathia patellae, osteochondrosis dissecans, traumas of the knee joints and arthrosis deformans. (orig.)

  17. Adenocarcinoma - chest x-ray (image)

    Science.gov (United States)

    This chest x-ray shows adenocarcinoma of the lung. There is a rounded light spot in the right upper lung (left side ... density. Diseases that may cause this type of x-ray result would be tuberculous or fungal granuloma, and ...

  18. X-Ray Detection Visits the Classroom

    Science.gov (United States)

    Peralta, Luis; Farinha, Ana; Pinto, Ana

    2008-01-01

    Film has been used to detect x-rays since the early days of their discovery by Rontgen. Although nowadays superseded by other techniques, film still provides a cheap means of x-ray detection, making it attractive in high-school or undergraduate university courses. If some sort of quantitative result is required, the film's optical absorbance or…

  19. Soft x rays for radiobiological studies

    International Nuclear Information System (INIS)

    Lethal effects and chromosome aberrations induced in cells exposed to low energy (soft) X rays demonstrated that these relatively low energy X rays are just as effective as those of higher energy for radiobiological studies, and even more effective for irradiating cultured mammalian cells than laboratory animals. (author)

  20. X-Ray Exam: Scoliosis (For Parents)

    Science.gov (United States)

    ... Your Child All About Food Allergies X-Ray Exam: Scoliosis KidsHealth > For Parents > X-Ray Exam: Scoliosis Print A A A Text Size What's ... routinely check kids for scoliosis during regular physical exams, and some schools also test for scoliosis. If ...

  1. Large X-ray optics: lobster alternative

    Czech Academy of Sciences Publication Activity Database

    Hudec, René; Pína, L.; Inneman, A.

    Garching : MaxPlanck Institute for Extraterrestrial Physics, 2003 - (Hasinger, G.; Boller, T.; Parmer, A.), s. 271-277 [XEUS - studying the evolution of the hot Universe. Garching (DE), 11.03.2002-13.03.2002] Institutional research plan: CEZ:AV0Z1003909 Keywords : XEUS X-ray telescope * lobster eye X-ray optics Subject RIV: BN - Astronomy, Celestial Mechanics, Astrophysics

  2. Accelerator-driven X-ray Sources

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Dinh Cong [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-11-09

    After an introduction which mentions x-ray tubes and storage rings and gives a brief review of special relativity, the subject is treated under the following topics and subtopics: synchrotron radiation (bending magnet radiation, wiggler radiation, undulator radiation, brightness and brilliance definition, synchrotron radiation facilities), x-ray free-electron lasers (linac-driven X-ray FEL, FEL interactions, self-amplified spontaneous emission (SASE), SASE self-seeding, fourth-generation light source facilities), and other X-ray sources (energy recovery linacs, Inverse Compton scattering, laser wakefield accelerator driven X-ray sources. In summary, accelerator-based light sources cover the entire electromagnetic spectrum. Synchrotron radiation (bending magnet, wiggler and undulator radiation) has unique properties that can be tailored to the users’ needs: bending magnet and wiggler radiation is broadband, undulator radiation has narrow spectral lines. X-ray FELs are the brightest coherent X-ray sources with high photon flux, femtosecond pulses, full transverse coherence, partial temporal coherence (SASE), and narrow spectral lines with seeding techniques. New developments in electron accelerators and radiation production can potentially lead to more compact sources of coherent X-rays.

  3. X-ray scattering measurements from thin-foil x-ray mirrors

    DEFF Research Database (Denmark)

    Christensen, Finn Erland; BYRNAK, BP; Hornstrup, Allan;

    1992-01-01

    Thin foil X-ray mirrors are to be used as the reflecting elements in the telescopes of the X-ray satellites Spectrum-X-Gamma (SRG) and ASTRO-D. High resolution X-ray scattering measurements from the Au coated and dip-lacquered Al foils are presented. These were obtained from SRG mirrors positioned...

  4. Soft X-Ray Spectra of AGN Discovered Via Their Hard X-Ray

    Science.gov (United States)

    Schwartz, Daniel

    1998-01-01

    This final report is a study of the Active Galactic Nuclei (AGN). Investigation of the soft x-ray spectra of AGN were performed by using their hard x-ray emission. ROSAT observations of AGN was also performed, which allowed for the study of these x-ray spectra and the structures of 7 clusters of galaxies.

  5. X-ray devices contributing to sophistication of X-ray diagnostic systems

    International Nuclear Information System (INIS)

    X-ray tubes to generate X-rays, as well as X-ray image intensifiers (I.I.s) and X-ray flat panel detectors (FPDs) to convert X-ray images into electronic signals, are key devices in X-ray diagnostic systems, which are playing a major role in the advancement of diagnosis and treatment. Toshiba Electron Tubes and Devices Co., Ltd. has been offering optimal products incorporating the most advanced technologies to customers through continuous technological innovations. These include a high-sensitivity technology for X-ray I.I.s and X-ray FPDs to suppress patient exposure doses, a focal spot design technology for X-ray tubes and high-resolution technologies for X-ray I.I.s and X-ray FPDs that enhance image quality and make it possible to detect smaller lesion areas, and a noise reduction technology for X-ray tubes to realize a comfortable medical environment with reduced stress on both patients and medical staff. (author)

  6. High Energy Vision: Processing X-rays

    CERN Document Server

    DePasquale, Joseph; Edmonds, Peter

    2015-01-01

    Astronomy is by nature a visual science. The high quality imagery produced by the world's observatories can be a key to effectively engaging with the public and helping to inspire the next generation of scientists. Creating compelling astronomical imagery can, however, be particularly challenging in the non-optical wavelength regimes. In the case of X-ray astronomy, where the amount of light available to create an image is severely limited, it is necessary to employ sophisticated image processing algorithms to translate light beyond human vision into imagery that is aesthetically pleasing while still being scientifically accurate. This paper provides a brief overview of the history of X-ray astronomy leading to the deployment of NASA's Chandra X-ray Observatory, followed by an examination of the specific challenges posed by processing X-ray imagery. The authors then explore image processing techniques used to mitigate such processing challenges in order to create effective public imagery for X-ray astronomy. ...

  7. Requirements for industrial x-ray equipment

    International Nuclear Information System (INIS)

    This safety code is concerned with the protection of all individuals who may be exposed to radiation emitted by X-ray equipment operating at energies up to 1 MeV as used in industrial radiography. This code presents basic radiation safety information for the protection of personnel operating and servicing X-ray equipment and other workers and the general public in the vicinity of areas where X-ray equipment is in operation. It specifies general safety features of design, construction and functioning of X-ray equipment and facilities; describes the responsibilities of the user, operator and maintenance personnel; contains recommendations to ensure that the X-ray equipment is used and maintained in accordance with the ALARA principle; and describes a program of personnel monitoring and radiation safety surveys. ( 6 refs., 5 tabs., 4 figs.)

  8. Development of coherent x-ray lasers

    International Nuclear Information System (INIS)

    Proposed x-ray laser applications such as interferometry and holography require coherent radiation. The fact that x-ray laser media are short-lived high-temperature plasmas leads to very different coherence properties from those of ordinary lasers. Research aimed at developing theoretical models and experimentally characterizing and improving x-ray laser coherence is discussed. Longitudinal coherence is already sufficient for several applications due to the narrow linewidths. However, transverse coherence is estimated to be poor for most current x-ray lasers. To quantify these estimates and to design better lasers, both wave and geometric optics propagation and coherence theories have been developed. These theories and resulting predictions of the coherence length are presented and compared. Measurements of x-ray laser beam patterns and coherence lengths are presented and compared to detailed theoretical simulations. Designs for more coherent lasers are given

  9. Perspectives of medical X-ray imaging

    Science.gov (United States)

    Freudenberger, J.; Hell, E.; Knüpfer, W.

    2001-06-01

    While X-ray image intensifiers (XII), storage phosphor screens and film-screen systems are still the work horses of medical imaging, large flat panel solid state detectors using either scintillators and amorphous silicon photo diode arrays (FD-Si), or direct X-ray conversion in amorphous selenium are reaching maturity. The main advantage with respect to image quality and low patient dose of the XII and FD-Si systems is caused by the rise of the Detector Quantum Efficiency originating from the application of thick needle-structured phosphor X-ray absorbers. With the detectors getting closer to an optimal state, further progress in medical X-ray imaging requires an improvement of the usable source characteristics. The development of clinical monochromatic X-ray sources of high power would not only allow an improved contrast-to-dose ratio by allowing smaller average photon energies in applications but would also lead to new imaging techniques.

  10. Perspectives of medical X-ray imaging

    International Nuclear Information System (INIS)

    While X-ray image intensifiers (XII), storage phosphor screens and film-screen systems are still the work horses of medical imaging, large flat panel solid state detectors using either scintillators and amorphous silicon photo diode arrays (FD-Si), or direct X-ray conversion in amorphous selenium are reaching maturity. The main advantage with respect to image quality and low patient dose of the XII and FD-Si systems is caused by the rise of the Detector Quantum Efficiency originating from the application of thick needle-structured phosphor X-ray absorbers. With the detectors getting closer to an optimal state, further progress in medical X-ray imaging requires an improvement of the usable source characteristics. The development of clinical monochromatic X-ray sources of high power would not only allow an improved contrast-to-dose ratio by allowing smaller average photon energies in applications but would also lead to new imaging techniques

  11. Perspectives of medical X-ray imaging

    Energy Technology Data Exchange (ETDEWEB)

    Freudenberger, J. E-mail: joerg.freudenberger@med.siemens.de; Hell, E.; Knuepfer, W

    2001-06-21

    While X-ray image intensifiers (XII), storage phosphor screens and film-screen systems are still the work horses of medical imaging, large flat panel solid state detectors using either scintillators and amorphous silicon photo diode arrays (FD-Si), or direct X-ray conversion in amorphous selenium are reaching maturity. The main advantage with respect to image quality and low patient dose of the XII and FD-Si systems is caused by the rise of the Detector Quantum Efficiency originating from the application of thick needle-structured phosphor X-ray absorbers. With the detectors getting closer to an optimal state, further progress in medical X-ray imaging requires an improvement of the usable source characteristics. The development of clinical monochromatic X-ray sources of high power would not only allow an improved contrast-to-dose ratio by allowing smaller average photon energies in applications but would also lead to new imaging techniques.

  12. XIPE: the X-ray Imaging Polarimetry Explorer

    CERN Document Server

    Soffitta, Paolo; Bellazzini, Ronaldo; Braga, João; Costa, Enrico; Fraser, George W; Gburek, Szymon; Huovelin, Juhani; Matt, Giorgio; Pearce, Mark; Poutanen, Juri; Reglero, Victor; Santangelo, Andrea; Sunyaev, Rashid A; Tagliaferri, Gianpiero; Weisskopf, Martin; Aloisio, Roberto; Amato, Elena; Attiná, Primo; Axelsson, Magnus; Baldini, Luca; Basso, Stefano; Bianchi, Stefano; Blasi, Pasquale; Bregeon, Johan; Brez, Alessandro; Bucciantini, Niccoló; Burderi, Luciano; Burwitz, Vadim; Casella, Piergiorgio; Churazov, Eugene; Civitani, Marta; Covino, Stefano; da Silva, Rui Miguel Curado; Cusumano, Giancarlo; Dadina, Mauro; D'Amico, Flavio; De Rosa, Alessandra; Di Cosimo, Sergio; Di Persio, Giuseppe; Di Salvo, Tiziana; Dovciak, Michal; Elsner, Ronald; Eyles, Chris J; Fabian, Andrew C; Fabiani, Sergio; Feng, Hua; Giarrusso, Salvatore; Goosmann, René W; Grandi, Paola; Grosso, Nicolas; Israel, Gianluca; Jackson, Miranda; Kaaret, Philip; Karas, Vladimir; Kuss, Michael; Lai, Dong; La Rosa, Giovanni; Larsson, Josefin; Larsson, Stefan; Latronico, Luca; Maggio, Antonio; Maia, Jorge; Marin, Frédéric; Massai, Marco Maria; Mineo, Teresa; Minuti, Massimo; Moretti, Elena; Muleri, Fabio; O'Dell, Stephen L; Pareschi, Giovanni; Peres, Giovanni; Pesce, Melissa; Petrucci, Pierre-Olivier; Pinchera, Michele; Porquet, Delphine; Ramsey, Brian; Rea, Nanda; Reale, Fabio; Rodrigo, Juana Maria; Różańska, Agata; Rubini, Alda; Rudawy, Pawel; Ryde, Felix; Salvati, Marco; Júnior, Valdivino Alexandre de Santiago; Sazonov, Sergey; Sgró, Carmelo; Silver, Eric; Spandre, Gloria; Spiga, Daniele; Stella, Luigi; Tamagawa, Toru; Tamborra, Francesco; Tavecchio, Fabrizio; Dias, Teresa Teixeira; van Adelsberg, Matthew; Wu, Kinwah; Zane, Silvia

    2013-01-01

    X-ray polarimetry, sometimes alone, and sometimes coupled to spectral and temporal variability measurements and to imaging, allows a wealth of physical phenomena in astrophysics to be studied. X-ray polarimetry investigates the acceleration process, for example, including those typical of magnetic reconnection in solar flares, but also emission in the strong magnetic fields of neutron stars and white dwarfs. It detects scattering in asymmetric structures such as accretion disks and columns, and in the so-called molecular torus and ionization cones. In addition, it allows fundamental physics in regimes of gravity and of magnetic field intensity not accessible to experiments on the Earth to be probed. Finally, models that describe fundamental interactions (e.g. quantum gravity and the extension of the Standard Model) can be tested. We describe in this paper the X-ray Imaging Polarimetry Explorer (XIPE), proposed in June 2012 to the first ESA call for a small mission with a launch in 2017 but not selected. XIPE ...

  13. Moving the Frontier of Quantum Control into the Soft X-Ray Spectrum

    Directory of Open Access Journals (Sweden)

    A. Aquila

    2011-01-01

    Full Text Available The femtosecond nature of X-ray free electron laser (FEL pulses opens up exciting research possibilities in time-resolved studies including femtosecond photoemission and diffraction. The recent developments of seeding X-ray FELs extend their capabilities by creating stable, temporally coherent, and repeatable pulses. This in turn opens the possibility of spectral engineering soft X-ray pulses to use as a probe for the control of quantum dynamics. We propose a method for extending coherent control pulse-shaping techniques to the soft X-ray spectral range by using a reflective geometry 4f pulse shaper. This method is based on recent developments in asymmetrically cut multilayer optic technology and piezoelectric substrates.

  14. High-resolution x-ray studies of an AXAF high-energy transmission grating

    DEFF Research Database (Denmark)

    Abdali, S.; Christensen, Finn Erland; Schnopper, H. W.;

    1993-01-01

    A triple axis X-ray diffractometer, designed and built at the Danish Space Research Institute, was used to make a high resolution study of the performance of a 2000 angstroms period, high energy X-ray transmission grating developed at MIT for one of the grating spectrometers on the Advanced X......-ray Astrophysics Facility. Data was obtained at CuK(alpha )1 (8.048 keV) and, using single reflection asymmetric Si(044) crystals for both the monochromator and analyzer, an angular resolution of 1.5 arcsec FWHM was achieved. The efficiency of the grating in all orders up to the 15th was measured using a 12 k......W rotating anode X-ray generator. These data provided the basis for a modelling of the grating structure....

  15. Time-resolved X-ray diffraction at monocrystalline indium antimonide

    International Nuclear Information System (INIS)

    The present work deals with the experimental study of the structural change of the semiconductor indium antimonide (InSb) after excitation by an ultrashort laser pulse (60 fs). The investigation is carried out by ultra-short X-ray pulses (around 100 fs). As a source for ultrashort X-ray pulses serves a laser plasma X-ray source. With this source, a more intense ultrashort optical laser pulse is focused onto a metal foil (intensity to 8.1016 W/cm2), and by the resulting plasma, there is an emission of X-rays. To characterize the X-ray source a novel Timepix detector was used, which made it possible to detect Bremsstrahlung up to photon energies of 700 keV. The penetration depth of X-rays is usually several micrometers and is thus much greater than the penetration depth of 100 nm of the laser pulse used for excitation. By the use of a highly asymmetric Bragg reflex the penetration depth of X-rays could be adapted to the penetration depth of the excitation pulse. Due to the low penetration depth of 2 ps after excitation an expansion of 4% of a 4 nm thin layer at the surface can already be measured. The excitation of the semiconductor will be described with different models theoretically, the temporal evolution of the deformation obtained therefrom is compared with the performed measurements.

  16. MEASURING OF X-RAY SOURCE SIZE BY USING COMPOUND REFRACTIVE X-RAY LENS

    Directory of Open Access Journals (Sweden)

    Yu. V. Dudchik

    2015-04-01

    Full Text Available Compound refractive lens was used for measuring size of 2-3 beamline Standford synchrotron radiation source and a size of microfocus X-ray tube. X-ray beam from the source was focused by the lens and parameters of the beam at image plane were measured. Scanning diaphragm and X-ray CCD-camera were used for measuring X-ray beam. It was found that the vertical size of synchrotron source is equal to 0,6 mm and the size of the X-ray tube focal spot is equal to 60 micrometers. 

  17. Large area soft x-ray collimator to facilitate x-ray optics testing

    Science.gov (United States)

    Espy, Samuel L.

    1994-01-01

    The first objective of this program is to design a nested conical foil x-ray optic which will collimate x-rays diverging from a point source. The collimator could then be employed in a small, inexpensive x-ray test stand which would be used to test various x-ray optics and detector systems. The second objective is to demonstrate the fabrication of the x-ray reflectors for this optic using lacquer-smoothing and zero-stress electroforming techniques.

  18. First X-ray fluorescence CT experimental results at the SSRF X-ray imaging beamline

    Institute of Scientific and Technical Information of China (English)

    DENG Biao; YANG Qun; XIE Hong-Lan; DU Guo-Hao; XIAO Wi-Qiao

    2011-01-01

    X-ray fluorescence CT is a non-destructive technique for detecting elemental composition and distribution inside a specimen. In this paper, the first experimental results of X-ray fluorescence CT obtained at the SSRF X-ray imaging beamline (BL13W1) are described. The test samples were investigated and the 2D elemental image was reconstructed using a filtered back-projection algorithm. In the sample the element Cd was observed. Up to now, the X-ray fluorescence CT could be carried out at the SSRF X-ray imaging beamline.

  19. Laser plasma x-ray source for ultrafast time-resolved x-ray absorption spectroscopy

    OpenAIRE

    Miaja-Avila, L.; G. C. O'Neil; Uhlig, J.; C. L. Cromer; Dowell, M. L.; Jimenez, R.; Hoover, A. S.; Silverman, K. L.; Ullom, J. N.

    2015-01-01

    We describe a laser-driven x-ray plasma source designed for ultrafast x-ray absorption spectroscopy. The source is comprised of a 1 kHz, 20 W, femtosecond pulsed infrared laser and a water target. We present the x-ray spectra as a function of laser energy and pulse duration. Additionally, we investigate the plasma temperature and photon flux as we vary the laser energy. We obtain a 75 μm FWHM x-ray spot size, containing ∼106 photons/s, by focusing the produced x-rays with a polycapillary opti...

  20. X-ray Spectral Variation of Eta Carinae through the 2003 X-ray Minimum

    OpenAIRE

    Hamaguchi, Kenji; Corcoran, Michael F.; Gull, Theodore; Ishibashi, Kazunori; Pittard, Julian M.; Hillier, D. John; Damineli, Augusto; Davidson, Kris; Nielsen, Krister E.; Kober, Gladys Vieira

    2007-01-01

    We report the results of an X-ray observing campaign on the massive, evolved star Eta Carinae, concentrating on the 2003 X-ray minimum as seen by the XMM-Newton observatory. These are the first spatially-resolved X-ray monitoring observations of the stellar X-ray spectrum during the minimum. The hard X-ray emission, believed to be associated with the collision of Eta Carinae's wind with the wind from a massive companion star, varied strongly in flux on timescales of days, but not significantl...

  1. X-ray diffraction from the ripple structures created by femtosecond laser pulses

    International Nuclear Information System (INIS)

    In this paper, we present the investigation and characterization of the laser-induced surface structure on an asymmetrically cut InSb crystal. We describe diffraction from the ripple surface and present a theoretical model that can be used to simulate X-ray energy scans. The asymmetrically cut InSb sample was irradiated with short-pulse radiation centred at 800 nm, with fluences ranging from 10 to 80 mJ/cm2. The irradiated sample surface profile was investigated using optical and atomic force microscopy. We have investigated how laser-induced ripples influence the possibility of studying repetitive melting of solids using X-ray diffraction. The main effects arise from variations in local asymmetry angles, which reduce the attenuation length and increase the X-ray diffraction efficiency. (orig.)

  2. Characteristics of Transmission-type Microfocus X-ray Tube based-on Carbon Nanotube Field Emitter

    International Nuclear Information System (INIS)

    A high resolution microfocus x-ray source is widely applied to noninvasive detection for industrial demands, material science and engineering, and to diagnostic study of microbiology and micro-tomography. Carbon nanotube (CNT) is regarded as an excellent electron emitter, which outperforms conventional electron sources in point of brightness. It has been suggested that CNT is used as an electron source of a high resolution x-ray tube according to their low threshold field with atomically sharp geometry, chemically robust structure, and electric conductivity. Several researchers have reported miniaturized x-ray tube based on diode structure and micro x-ray radiography and computed tomography systems using triode types with precise emission control and electrostatic focusing. Especially, a microfocus x-ray source of 30 μm resolution has been demonstrated recently using an elliptical CNT cathode and asymmetrical Eingel lens. However, to increase the spatial resolution of x-ray source, a smaller CNT emitter is desired. Electron focusing optics must be corrected to reduce aberrations. A thin wire tip end can provide a micro-area of CNT substrate, and a magnetic lens and transmission x-ray target are proper to reduce the lens aberration and a focal length. Until now, CNT based microfocus x-ray source with less than 10 um resolution has not been shown. Here we report a microfocus x-ray source with 4.7 μm x-ray focal spot consisted of a conical CNT tip, a single solenoid lens, and a transmission type x-ray target. A magnified x-ray image larger than 230 times was resolved with advantage of microfocused focal spot and transmission x-ray target

  3. Dual-energy X-ray CT and the extension to polychromatic X-ray CT

    International Nuclear Information System (INIS)

    We have developed dual energy X-ray CT using monochromatic X-ray beams. From the dual-energy X-ray CT, we can obtain distributions of an electron density and an effective atomic number in a human body. Especially, the electron density is very important for the heavy ion radiotherapy. Now, we adopted new array-detector to know the energy of incident photons as well as detect the position and the number of photons. We carry out the experiment of the dual-energy X-ray CT at the beamline of KEK and SPring-8 as a fundamental study for the polychromatic X-ray CT. We will show the preliminary result of this experiments and the feasibility of a quantitative polychromatic X-ray CT as an advanced method of monochromatic X-ray CT in this study. (author)

  4. Toward Adaptive X-Ray Telescopes

    Science.gov (United States)

    O'Dell, Stephen L.; Atkins, Carolyn; Button, Tim W.; Cotroneo, Vincenzo; Davis, William N.; Doel, Peer; Feldman, Charlotte H.; Freeman, Mark D.; Gubarev, Mikhail V.; Kolodziejczak, Jeffrey J.; Michette, Alan G.; Ramsey, Brian D.; Reid, Paul B.; Rodriguez Sanmartin, Daniel; Saha, Timo T.; Schwartz, Daniel A.; Trolier-McKinstry, Susan; Wilke, Rudeger H. T.; Willingale, Richard; Zhang, William W.

    2011-01-01

    Future x-ray observatories will require high-resolution (less than 1 inch) optics with very-large-aperture (greater than 25 square meter) areas. Even with the next generation of heavy-lift launch vehicles, launch-mass constraints and aperture-area requirements will limit the surface areal density of the grazing-incidence mirrors to about 1 kilogram per square meter or less. Achieving sub-arcsecond x-ray imaging with such lightweight mirrors will require excellent mirror surfaces, precise and stable alignment, and exceptional stiffness or deformation compensation. Attaining and maintaining alignment and figure control will likely involve adaptive (in-space adjustable) x-ray optics. In contrast with infrared and visible astronomy, adaptive optics for x-ray astronomy is in its infancy. In the middle of the past decade, two efforts began to advance technologies for adaptive x-ray telescopes: The Generation-X (Gen-X) concept studies in the United States, and the Smart X-ray Optics (SXO) Basic Technology project in the United Kingdom. This paper discusses relevant technological issues and summarizes progress toward adaptive x-ray telescopes.

  5. Toward active x-ray telescopes

    Science.gov (United States)

    O'Dell, Stephen L.; Atkins, Carolyn; Button, Timothy W.; Cotroneo, Vincenzo; Davis, William N.; Doel, Peter; Feldman, Charlotte H.; Freeman, Mark D.; Gubarev, Mikhail V.; Kolodziejczak, Jeffery J.; Michette, Alan G.; Ramsey, Brian D.; Reid, Paul B.; Rodriguez Sanmartin, Daniel; Saha, Timo T.; Schwartz, Daniel A.; Trolier-McKinstry, Susan; Wilke, Rudeger H. T.; Willingale, Richard; Zhang, William W.

    2011-09-01

    Future x-ray observatories will require high-resolution ( 25 m2) areas. Even with the next generation of heavy-lift launch vehicles, launch-mass constraints and aperture-area requirements will limit the areal density of the grazing-incidence mirrors to about 1 kg/m2 or less. Achieving sub-arcsecond x-ray imaging with such lightweight mirrors will require excellent mirror surfaces, precise and stable alignment, and exceptional stiffness or deformation compensation. Attaining and maintaining alignment and figure control will likely involve active (in-space adjustable) x-ray optics. In contrast with infrared and visible astronomy, active optics for x-ray astronomy is in its infancy. In the middle of the past decade, two efforts began to advance technologies for adaptive x-ray telescopes: The Smart X-ray Optics (SXO) Basic Technology project in the United Kingdom (UK) and the Generation-X (Gen-X) concept studies in the United States (US). This paper discusses relevant technological issues and summarizes progress toward active x-ray telescopes.

  6. Stellar coronas, X-rays, and Einstein

    International Nuclear Information System (INIS)

    Observations of the sun at ultraviolet and X-ray wavelengths reveal a structure connected with the configuration of the solar magnetic field. The Einstein Observatory (HEAO 2), the first satellite to use an imaging X-ray telescope, searched for faint coronas on the basis of visual brightness and their proximity to the sun. Observed temperatures of transition regions between the chromosphere and the corona exceed 1,000,000 K. A possible correlation between X-ray luminosity and rotation rate has been observed and Einstein observations also indicated that stellar coronas showed changes in X-ray brightness during the most stable period of a star's life. Solar flares and transients, which generate substantial amounts of X-rays, radio waves and charged particles, are believed to be other properties of stellar coronas which change with age. Future missions such as NASA's Extreme Ultraviolet Explorer, the Advanced X-ray Astrophysics Facility and Space Telescope will enable astronomers to greatly increase their sampling of stellar coronas available for study. Observations also suggest the early development of a strong stellar dynamo due to X-ray activity in pre-main-sequence objects. It is hoped that the study of activity cycles in other stars will yield a greater understanding of the dynamo theory

  7. Cell survival studies using ultrasoft x rays

    International Nuclear Information System (INIS)

    Cell survival was studied for V79 hamster, 10T1/2 mouse, and human skin fibroblast cell lines, using carbon K (0.28 keV), copper K (8.0 keV), and 250 kVp x rays. Because of the rapid attenuation of the carbon x rays, cellular dimensions at the time of exposure were measured using optical and electron microscopy, and frequency distributions of mean dose absorbed by the cell nucleus were obtained. The results indicate that the differences in cell killing between ultra-soft and hard x rays may depend on the nuclear thickness of the cells. Studies of the effects of hypoxia on V79 and 10T1/2 cells using carbon K, aluminum K (1.5 keV), and copper K x rays show decreasing OER values with decreasing x-ray energy and no difference between the two cell lines. Age response studies with V79 cells show similar cell-cycle variation of survival for carbon K and aluminum K x rays as for hard x rays

  8. Beam position measurements of Indus-2 using X-Ray beam position monitor

    International Nuclear Information System (INIS)

    A staggered pair metal blade X-ray beam position monitor (XBPM) is designed, fabricated and commissioned on Indus-2 bending magnet front end. Calibration of XBPM is done by scanning the metal blades in the path of synchrotron radiation and by giving controlled electron asymmetric bump. The vertical beam position stability of the source measured during various injections and storages are reported.

  9. X-ray diffraction study of surface-layer structure in parallel grazing rays

    International Nuclear Information System (INIS)

    An x-ray diffraction method is described for study of thin polycrystalline and amorphous films and surface layers in an extremely asymmetrical diffraction system in parallel grazing rays using a DRON-3.0 diffractometer. The minimum grazing angles correspond to diffraction under conditions of total external reflection and a layer depth of ∼ 2.5-8 nm

  10. Synthesis of trinuclear MFe2-clusters with bridge sigma,π-phenylethynyl ligand and X-ray diffraction study of delta connection μ-[1-(dicarbonyl-eta-cyclopentadienyltungsten)-2-(phenyl)-ethyne]-bis(tricarbonyliron)(WFe2)

    International Nuclear Information System (INIS)

    Trinuclear clusters CpMFe2(CO)8 (σ, π-C2Ph)(2a-2b) are synthesized by Fe2(CO)9 interaction with σ-acetylenide complexes CpM(CO)3C identity sign CPh(1a-1b) (M=Cr, Mo, W) in the benzene media. IR spectra 2a-2b and 13C-('H)NMR spectra of 1a-1b, 2b, are investigated. Roentgenostructural investigation of 2b with M=W (monoclinic crystals, a=8.656, b=14.261, c=37.355 A, β=92.17 deg, sp. group P21/c, Z=8, lambda Cu 4654 reflections, R=12%) is carried out. Bridge σ, π-C identity sign C Ph-ligand is bended, acetylene C atoms build up Fe2W triangle (Fe-Fesub(medium) 2.474, Fe-W 2.827-2.887 A) to a trigonal bipyromide Fe2WC2. Two independent molecules in 2b crystal differ in the angle of Ph-cycle rotation relatively to heteronuclear cluster fragment

  11. X-ray diffraction imaging and analysis

    International Nuclear Information System (INIS)

    The first papers dealing with the very important application of x-ray diffraction to crystal structure analysis were also published in 1912 by W.L. Bragg, while a student at Cambridge. Bragg performed an analysis of the Laue diffraction pattern of zinc blend and determined the correct structure of the crystal lattice. There have been many practical applications for x-ray diffraction techniques. Historically conventional x-ray machines were used as generators and film used as the recording medium. Prior to 1966, all attempts to directly image x-ray diffraction patterns used a large format x-ray image intensifier tube of the same type as conventionally used for medical and industrial fluoroscopy. Since the 1960's numerous electro-optical systems have been developed which are far better suited for real-time viewing and recording of x-ray diffraction patterns. Modern x-ray diffraction imaging systems incorporating rotating anode and pulsed x-ray generators, synchrotron x-ray sources, and optimized electro-optical systems have been used to orient single crystals, to study crystal lattice rotation accompanying plastic deformation, to measure the rate of grain boundary migration during recrystallization annealing of cold-worked metals, to determine the physical state of exploding metals, to rapidly measure residual stress (strain), to study the dynamics of structural phase transitions in ferroelectric crystals, to monitor the amorphous to crystalline phase transformation of rapidly solidified metals, and to record topographic images of lattice defects in quartz, gallium arsenide and nickel alloy turbine blade crystals

  12. Picosecond X-ray absorption spectroscopy: application to coordination chemistry compounds in solution

    OpenAIRE

    Saes, Melanie

    2004-01-01

    The photocycle of aqueous ruthenium-(trisbipyridine) [Ru(bpy)3]2+ was studied under high laser excitation intensities and high sample concentrations with picosecond resolved x-ray absorption spectroscopy. In a pump-probe scheme a femtosecond laser pulse promotes a 4d electron from the ruthenium to the ligand orbitals, thus creating a metal-to-ligand-charge-transfer (MLCT) complex. A hard x-ray pulse from a synchrotron source probes the ruthenium L3 and L2 edges, monitoring the electronic and ...

  13. Picosecond X-ray absorption spectroscopy: application to coordination chemistry compounds in solution

    OpenAIRE

    Saes, Melanie; Chergui, Majed

    2005-01-01

    The photocycle of aqueous ruthenium-(trisbipyridine) [Ru(bpy)3]2+ was studied under high laser excitation intensities and high sample concentrations with picosecond resolved x-ray absorption spectroscopy. In a pump-probe scheme a femtosecond laser pulse promotes a 4d electron from the ruthenium to the ligand orbitals, thus creating a metal-to-ligand-charge-transfer (MLCT) complex. A hard x-ray pulse from a synchrotron source probes the ruthenium L3 and L2 edges, monitoring the electronic and ...

  14. X-ray hazards - diagnostic and therapeutic

    International Nuclear Information System (INIS)

    The subject is covered in sections, entitled: introduction; nature of X-rays; X-rays - effect on biological materials; X-ray measurement; radiation dosages to exposed groups; organizational structure of radiological protection; duties of the Radiological Safety Officer; general measures for radiological protection; protection of staff; protection of patients; safety measures in radiotherapy work - sealed sources laboratory -general safety rules; radiotherapy - duties of the Radiological Safety Officer (Radiotherapy); the custodian of sealed sources -duties and relevant radiological protection information; external beam therapy - radionuclide source unit - emergency procedure in the event of technical failure; safety aspects of brachytherapy in the patient's vicinity; diagnostic radiology; conclusion. (U.K.)

  15. X-ray microscopy using synchrotron radiation

    International Nuclear Information System (INIS)

    The system for x-ray microscopy now being developed at the X-26 beam line of the Brookhaven National Synchrotron Light Source (NSLS) is described here. Examples of the use of x-ray microscopy for trace element geochemistry, biology and medicine, and materials investigations are given to emphasize the scientific applications of the technique. Future directions for the improvement and further development of the X-26 microscope and of the x-ray microscopy field in general are discussed. 11 refs., 7 figs

  16. Two-dimensional x-ray diffraction

    CERN Document Server

    He, Bob B

    2009-01-01

    Written by one of the pioneers of 2D X-Ray Diffraction, this useful guide covers the fundamentals, experimental methods and applications of two-dimensional x-ray diffraction, including geometry convention, x-ray source and optics, two-dimensional detectors, diffraction data interpretation, and configurations for various applications, such as phase identification, texture, stress, microstructure analysis, crystallinity, thin film analysis and combinatorial screening. Experimental examples in materials research, pharmaceuticals, and forensics are also given. This presents a key resource to resea

  17. X-ray Variability of Blazars

    OpenAIRE

    Pian, Elena

    2002-01-01

    Critical progress in our understanding of high energy emission from AGN has been determined in the last 10 years by X-ray monitoring campaigns with many space missions, notably ROSAT, ASCA, RXTE, BeppoSAX, and XMM, often in conjunction with observations at other frequencies. The emphasis of the present review is on recent findings about X-ray variability of blazars. Among AGN, these exhibit the largest amplitude variations of the X-ray emission, often well correlated with variations at higher...

  18. Imaging Cellular Architecture with X-rays

    OpenAIRE

    Larabell, Carolyn A.; Nugent, Keith A.

    2010-01-01

    X-ray imaging of biological samples is progressing rapidly. In this paper we review the progress to date in high resolution imaging of cellular architecture. In particular we survey the progress in soft X-ray tomography and argue that the field is coming of age and that important biological insights are starting to emerge. We then review the new ideas based on coherent diffraction. These methods are at a much earlier stage of development but, as they eliminate the need for X-ray optics, have ...

  19. Large Area X-Ray Spectroscopy Mission

    Science.gov (United States)

    Tananbaum, H.

    1997-01-01

    The Large Area X-ray Spectroscopy (LAXS) mission concept study continues to evolve strongly following the merging of the LAXS mission with the Next Generation X-ray Observatory (NGXO, PI: Nick White) into the re-named High Throughput X-ray Spectroscopy (HTXS) Mission. HTXS retains key elements of the LAXS proposal, including the use of multiple satellites for risk-reduction and cost savings. A key achievement of the program has been the recommendation by the Structure and Evolution of the Universe (SEUS) (April 1997) for a new start for the HTXS mission in the 2000-2004 timeframe.

  20. The Future of X-Ray Optics

    Science.gov (United States)

    Weisskopf, Martin C.

    2013-01-01

    The most important next step is the development of X-ray optics comparable to (or better than) Chandra in angular resolution that far exceed Chandra s effective area. Use the long delay to establish an adequately funded, competitive technology program along the lines I have recommended. Don't be diverted from this objective, except for Explorer-class missions. Progress in X-ray optics, with emphasis on the angular resolution, is central to the paradigm-shifting discoveries and the contributions of X-ray astronomy to multiwavelength astrophysics over the past 51 years.

  1. X-ray emission from Centaurus A

    Energy Technology Data Exchange (ETDEWEB)

    Terrell, N.J.

    1981-01-01

    Observations of 3 to 12 keV x-ray emission from NGC 5128 (Cen A) were made by Vela spacecraft over the period 1969 to 1979. These data are in good agreement with previously reported data, but are much more complete. Numerous peaks of x-ray intensity occurred during the period 1973 to 1975, characterized by rapid increases and equally rapid decreases (in less than 10 days). Thus it seems probable that most of the x-ray flux from the nucleus of Cen A came from a single source of small size.

  2. Nonlinear X-ray Compton Scattering

    OpenAIRE

    Fuchs, Matthias; Trigo, Mariano; Chen, Jian; Ghimire, Shambhu; Shwartz, Sharon; Kozina, Michael; Jiang, Mason; Henighan, Thomas; Bray, Crystal; Ndabashimiye, Georges; Bucksbaum, P. H.; Feng, Yiping; Herrmann, Sven; Carini, Gabriella; Pines, Jack

    2015-01-01

    X-ray scattering is a weak linear probe of matter. It is primarily sensitive to the position of electrons and their momentum distribution. Elastic X-ray scattering forms the basis of atomic structural determination while inelastic Compton scattering is often used as a spectroscopic probe of both single-particle excitations and collective modes. X-ray free-electron lasers (XFELs) are unique tools for studying matter on its natural time and length scales due to their bright and coherent ultrash...

  3. Advances in x-ray analysis

    International Nuclear Information System (INIS)

    This book presents papers given at the 1982 Denver Conference on the Applications of X-ray Analysis. Focus is on recent developments in measurement accuracy of two-theta and intensity. Topics include accuracy in x-ray powder diffraction (the theme of the conference); search/match procedures (Powder Diffraction File); quantitative XRD analysis; XRD application and automation; x-ray stress determination (position sensitive detectors, fatigue and fracture characterization); new XRF instrumentation and techniques; XRF computer systems and mathematical corrections; and XRF general applications

  4. Streaked, x-ray-transmission-grating spectrometer

    International Nuclear Information System (INIS)

    A free standing x-ray transmission grating has been coupled with a soft x-ray streak camera to produce a time resolved x-ray spectrometer. The instrument has a temporal resolution of approx. 20 psec, is capable of covering a broad spectral range, 2 to 120 A, has high sensitivity, and is simple to use requiring no complex alignment procedure. In recent laser fusion experiments the spectrometer successfully recorded time resolved spectra over the range 10 to 120 A with a spectral resolving power, lambda/Δlambda of 4 to 50, limited primarily by source size and collimation effects

  5. X-ray lenses with large aperture

    International Nuclear Information System (INIS)

    Up to now, most X-ray imaging setups are based on absorption contrast imaging. There is a demand for focused X-rays in many X-ray analysis applications, either to increase the resolution of an imaging system, or, to reduce the time effort of an experiment through higher photon flux. For photon energies higher than 15 keV refractive X-ray optics are more efficient in comparison to non-refractive X-ray optics. The aim of this work was to develop X-ray lenses with large apertures and high transparency. By increasing the number of refracting surfaces while removing unnecessary lens material such lenses have been developed. Utilizing this approach the overall beam deflection angle is large with respect to the lens material it propagates through and so the transparency of the lens is increased. Within this work, X-ray lenses consisting of several thousands of prisms with an edge length in the range of micrometers have been developed and fabricated by deep X-ray lithography. Deep X-ray lithography enables high precision microstrucures with smooth sidewalls and large aspect ratios. The aperture of high-transparency X-ray lenses made this way is greater than 1 mm. They are suitable for photon energies in the range of 8 keV to 24 keV and offer a focal width of smaller than 10 μm at a transparency of around 40%. Furthermore, rolled X-ray lenses have been developed, that are made out of a microstructured polyimide film, which is cut according to the requirements regarding focal length and photon energy. The microstructured film is fabricated by molding, using an anisotropically etched silicon wafer as molding tool. Its mean roughness is in the range of nanometers. The film features prismatic structures, its surface topology is similar to an asparagus field. The measured diameter of the point focus was 18 μm to 31 μm, the calculated opticla efficiency was 37%. Future work will concentrate on increasing the aspect ratio of Prism Lenses and on increasing the rolling accuracy

  6. Ten years of X-ray interferometry

    International Nuclear Information System (INIS)

    X-ray interferometers were the first optical instruments which utilized many Bragg reflecting components in monolithic blocks of perfect crystal. They have made important contributions to our knowledge of fundamental constants, of Bragg reflection x-ray optics, of strains and defects in crystals and of the optical constants of materials in the x-ray region of the electromagnetic spectrum. Based on an oversimplified optical analogue, their mode of operation is described in detail. Current applications of crystal interferometers and future work is briefly reviewed. (author)

  7. Ray-tracing simulations of spherical Johann diffraction spectrometer for in-beam X-ray experiments

    International Nuclear Information System (INIS)

    The results of the Monte-Carlo ray-tracing simulations for a Johann-type Bragg spectrometer with spherically curved-crystal designed to detect the X-rays from a fast-moving source are reported. These calculations were performed to optimize the X-ray spectrometer to be used at the gas-target installed at ion storage ring for high-resolution X-ray experiments. In particular, the two-dimensional distributions of detected photons were studied using the Monte-Carlo method both for the stationary and moving X-ray sources, taking into account a detailed description of X-ray source and X-ray diffraction on the crystal as well as a role of the Doppler effect for in-beam experiments. The origin of the asymmetry of observed X-ray profiles was discussed in detail and the procedure to derive a precise (sub-eV) X-ray transition energy for such asymmetric profiles was proposed. The results are important for the investigations of 1s2p3P2→1s2s3S1 intrashell transition in excited He-like uranium ions in in-beam X-ray experiments

  8. Laser plasma x-ray source for ultrafast time-resolved x-ray absorption spectroscopy

    Directory of Open Access Journals (Sweden)

    L. Miaja-Avila

    2015-03-01

    Full Text Available We describe a laser-driven x-ray plasma source designed for ultrafast x-ray absorption spectroscopy. The source is comprised of a 1 kHz, 20 W, femtosecond pulsed infrared laser and a water target. We present the x-ray spectra as a function of laser energy and pulse duration. Additionally, we investigate the plasma temperature and photon flux as we vary the laser energy. We obtain a 75 μm FWHM x-ray spot size, containing ∼106 photons/s, by focusing the produced x-rays with a polycapillary optic. Since the acquisition of x-ray absorption spectra requires the averaging of measurements from >107 laser pulses, we also present data on the source stability, including single pulse measurements of the x-ray yield and the x-ray spectral shape. In single pulse measurements, the x-ray flux has a measured standard deviation of 8%, where the laser pointing is the main cause of variability. Further, we show that the variability in x-ray spectral shape from single pulses is low, thus justifying the combining of x-rays obtained from different laser pulses into a single spectrum. Finally, we show a static x-ray absorption spectrum of a ferrioxalate solution as detected by a microcalorimeter array. Altogether, our results demonstrate that this water-jet based plasma source is a suitable candidate for laboratory-based time-resolved x-ray absorption spectroscopy experiments.

  9. X-ray diffraction contrast tomography (DCT) system, and an X-ray diffraction contrast tomography (DCT) method

    DEFF Research Database (Denmark)

    2012-01-01

    Source: US2012008736A An X-ray diffraction contrast tomography system (DCT) comprising a laboratory X-ray source (2), a staging device (5) rotating a polycrystalline material sample in the direct path of the X-ray beam, a first X-ray detector (6) detecting the direct X-ray beam being transmitted...

  10. Panoramic dental X-ray machine

    International Nuclear Information System (INIS)

    A panoramic dental X-ray machine is described possessing mechanical and electronic simplicity for providing both continuous and discontinuous radiographs of a dental arch area. The machine includes an excursion mechanism which causes a tubehead-camera assembly to uninterruptedly circularly orbit the patient's head at a constant speed. A drive mechanism is employed which controls the shifting or transport of the patient along an X-axis only, when either continuous or discontinuous images are desired. The kVp and milliamperes remain constant during the entire exposure of the patient to the X-rays as well as the rotational speed of the tubehead-camera assembly, and no attenuating members are required in the X-ray path for varying intensity of the X-ray beam. (Auth.)

  11. Future X-ray timing missions

    CERN Document Server

    Barret, D; Staubert, R; Stella, L

    2000-01-01

    Thanks to the Rossi X-ray Timing Explorer (RXTE), it is now widely recognized that fast X-ray timing can be used to probe strong gravity fields around collapsed objects and constrain the equation of state of dense matter in neutron stars. We first discuss some of the outstanding issues which could be solved with an X-ray timing mission building on the great successes of RXTE and providing an order of magnitude better sensitivity. Then we briefly describe the 'Experiment for X-ray timing and Relativistic Astrophysics' (EXTRA) recently proposed to the European Space Agency as a follow-up to RXTE and the related US mission 'Relativistic Astrophysics Explorer' (RAE).

  12. Future X-Ray Timing Missions

    Science.gov (United States)

    Barret, Didier; van der Klis, Michiel; Skinner, Gerry K.; Staubert, Rüdiger; Stella, Luigi

    Thanks to the Rossi X-ray Timing Explorer (RXTE), it is now widely recognized that fast X-ray timing can be used to probe strong gravity fields around collapsed objects and constrain the equation of state of dense matter in neutron stars. We first discuss some of the outstanding issues which could be solved with an X-ray timing mission building on the great successes of RXTE and providing an order of magnitude better sensitivity. Then we briefly describe the `Experiment for X-ray timing and Relativistic Astrophysics' (EXTRA) recently proposed to the European Space Agency as a follow-up to RXTE and the related US mission `Relativistic Astrophysics Explorer' (RAE).

  13. X-ray reprocessing in local AGN

    Science.gov (United States)

    Turner, J.

    2015-09-01

    Feature-rich X-ray spectra of local AGN reveal signatures from circumnuclear reprocessing gas spanning a wide range of column density and ionization state; this gas is likely dominant in shaping X-ray spectra and variability in AGN. Combining spectral information with X-ray time lag signatures indicates that the nuclear regions have a high covering fraction outflow of absorbing, Compton-scattering gas existing on scales of light- hours. We have applied a Monte Carlo Radiative Transfer model to the local AGN population and found the X-ray properties can be explained simply by changing the observer's sightline through a Compton-thick cloud ensemble, although other important cloud dependences, such as column denisty or ionization state are not ruled out.

  14. Nonrelativistic quantum X-ray physics

    CERN Document Server

    Hau-Riege, Stefan P

    2015-01-01

    Providing a solid theoretical background in photon-matter interaction, Nonrelativistic Quantum X-Ray Physics enables readers to understand experiments performed at XFEL-facilities and x-ray synchrotrons. As a result, after reading this book, scientists and students will be able to outline and perform calculations of some important x-ray-matter interaction processes. Key features of the contents are that the scope reaches beyond the dipole approximation when necessary and that it includes short-pulse interactions. To aid the reader in this transition, some relevant examples are discussed in detail, while non-relativistic quantum electrodynamics help readers to obtain an in-depth understanding of the formalisms and processes. The text presupposes a basic (undergraduate-level) understanding of mechanics, electrodynamics, and quantum mechanics. However, more specialized concepts in these fields are introduced and the reader is directed to appropriate references. While primarily benefiting users of x-ray light-sou...

  15. X-ray Emission from Solar Flares

    Indian Academy of Sciences (India)

    Rajmal Jain; Malini Aggarwal; Raghunandan Sharma

    2008-03-01

    Solar X-ray Spectrometer (SOXS), the first space-borne solar astronomy experiment of India was designed to improve our current understanding of X-ray emission from the Sun in general and solar flares in particular. SOXS mission is composed of two solid state detectors, viz., Si and CZT semiconductors capable of observing the full disk Sun in X-ray energy range of 4–56 keV. The X-ray spectra of solar flares obtained by the Si detector in the 4–25 keV range show evidence of Fe and Fe/Ni line emission and multi-thermal plasma. The evolution of the break energy point that separates the thermal and non-thermal processes reveals increase with increasing flare plasma temperature. Small scale flare activities observed by both the detectors are found to be suitable to heat the active region corona; however their location appears to be in the transition region.

  16. (EXAFS) X-ray absorption spectroscopy

    International Nuclear Information System (INIS)

    The technique EXAFS (Extended X-Ray Absorption Fine Structure) is presented and its applications using the synchrotron radiation as an incidente beam in Science of Materials and Biophysics are shown. (L.C.)

  17. X-Ray Detector Simulations - Oral Presentation

    International Nuclear Information System (INIS)

    The free-electron laser at LCLS produces X-Rays that are used in several facilities. This light source is so bright and quick that we are capable of producing movies of objects like proteins. But making these movies would not be possible without a device that can detect the X-Rays and produce images. We need X-Ray cameras. The challenges LCLS faces include the X-Rays' high repetition rate of 120 Hz, short pulses that can reach 200 femto-seconds, and extreme peak brightness. We need detectors that are compatible with this light source, but before they can be used in the facilities, they must first be characterized. My project was to do just that, by making a computer simulation program. My presentation discusses the individual detectors I simulated, the details of my program, and how my project will help determine which detector is most useful for a specific experiment.

  18. Silicon Wafer X-ray Mirror Project

    Data.gov (United States)

    National Aeronautics and Space Administration — In this one year research project, we propose to do the following four tasks; (1) Design the silicon wafer X-ray mirror demo unit and develop a ray-tracing code to...

  19. Demonstration of X-ray talbot interferometry

    CERN Document Server

    Momose, A; Kawamoto, S; Hamaishi, Y; Takai, K; Suzuki, Y

    2003-01-01

    First Talbot interferometry in the hard X-ray region was demonstrated using a pair of transmission gratings made by forming gold stripes on glass plates. By aligning the gratings on the optical axis of X-rays with a separation that caused the Talbot effect by the first grating, moire fringes were produced inclining one grating slightly against the other around the optical axis. A phase object placed in front of the first grating was detected by moire-fringe bending. Using the technique of phase-shifting interferometry, the differential phase corresponding to the phase object could also be measured. This result suggests that X-ray Talbot interferometry is a novel and simple method for phase-sensitive X-ray radiography. (author)

  20. X-Ray Technologist Listing In California

    Data.gov (United States)

    U.S. Department of Health & Human Services — This table represents a current listing of X-Ray Technologists who are licensed by Radiologic Health Branch (RHB) of the California Department of Public Health. RHB...

  1. X-ray source for mammography

    Science.gov (United States)

    Logan, Clinton M.

    1994-01-01

    An x-ray source utilizing anode material which shifts the output spectrum to higher energy and thereby obtains higher penetrating ability for screening mammography application, than the currently utilized anode material. The currently used anode material (molybdenum) produces an energy x-ray spectrum of 17.5/19.6 keV, which using the anode material of this invention (e.g. silver, rhodium, and tungsten) the x-ray spectrum would be in the 20-35 keV region. Thus, the anode material of this invention provides for imaging of breasts with higher than average x-ray opacity without increase of the radiation dose, and thus reduces the risk of induced breast cancer due to the radiation dose administered for mammograms.

  2. Dental x-ray diagnostic installation

    International Nuclear Information System (INIS)

    An exemplary embodiment comprises an exposure unit including an X-ray tube and a cassette holder rotatable about vertical axes and between which the head of the patient is disposed. A radiation detector is disposed at the cassette holder for supplying an electrical signal corresponding to the dose rate when it is struck by X-rays and being interconnected with an X-ray tube voltage controller and a dose rate regulator in such manner that the X-ray tube voltage is influenced by the output of the radiation detector to control the dose rate to a value producing an optimum film blackening. A function generator determining the speed of the exposure unit is provided in which a speed curve is stored given which the radiation dose influencing the film is approximately constant

  3. Chest X-Ray (Chest Radiography)

    Science.gov (United States)

    ... Lung tissue absorbs little radiation and will appear dark on the image. Until recently, x-ray images ... understanding of the possible charges you will incur. Web page review process: This Web page is reviewed ...

  4. Center for X-ray Optics (CXRO)

    Data.gov (United States)

    Federal Laboratory Consortium — The Center for X-Ray Optics at Lawrence Berkeley National Laboratory works to further science and technology using short wavelength optical systems and techniques....

  5. The Need for X-Ray Spectroscopy

    Science.gov (United States)

    Winebarger, Amy R.; Cirtain, Jonathan; Kobayashi, Ken

    2011-01-01

    For over four decades, X-ray, EUV, and UV spectral observations have been used to measure physical properties of the solar atmosphere. During this time, there has been substantial improvement in the spectral, spatial, and temporal resolution of the observations for the EUV and UV wavelength ranges. At wavelengths below 100 Angstroms, however, observations of the solar corona with simultaneous spatial and spectral resolution are limited, and not since the late 1970's have spatially resolved solar X-ray spectra been measured. The soft-X-ray wavelength range is dominated by emission lines formed at high temperatures and provides diagnostics unavailable in any other wavelength range. In this presentation, we will discuss the important science questions that can be answered using spatially and spectrally resolved X-ray spectra.

  6. Time-resolved suprathermal x-rays

    International Nuclear Information System (INIS)

    Temporally resolved x-ray spectra in the range of 1 to 20 keV have been obtained from gold disk targets irradiated by 1.06 μm laser pulses from the Argus facility. The x-ray streak camera used for the measurement has been calibrated for streak speed and dynamic range by using an air-gap Fabry-Perot etalon, and the instrument response has been calibrated using a multi-range monoenergetic x-ray source. The experimental results indicate that we are able to observe the ''hot'' x-ray temperature evolve in time and that the experimentally observed values can be qualitatively predicted by LASNEX code computations when the inhibited transport model is used

  7. X-ray imaging: Status and trends

    International Nuclear Information System (INIS)

    There is a veritable renaissance occurring in x-ray imaging. X-ray imaging by radiography has been a highly developed technology in medicine and industry for many years. However, high resolution imaging has not generally been practical because sources have been relatively dim and diffuse, optical elements have been nonexistent for most applications, and detectors have been slow and of low resolution. Materials analysis needs have therefore gone unmet. Rapid progress is now taking place because we are able to exploit developments in microelectronics and related material fabrication techniques, and because of the availability of intense x-ray sources. This report describes the methods and uses of x-ray imaging along with a discussion of technology advances in these areas

  8. X-ray microtomography in biology

    CERN Document Server

    Mizutani, Ryuta

    2016-01-01

    Progress in high-resolution x-ray microtomography has provided us with a practical approach to determining three-dimensional (3D) structures of opaque samples at micrometer to submicrometer resolution. In this review, we give an introduction to hard x-ray microtomography and its application to the visualization of 3D structures of biological soft tissues. Practical aspects of sample preparation, handling, data collection, 3D reconstruction, and structure analysis are described. Furthermore, different sample contrasting methods are approached in detail. Examples of microtomographic studies are overviewed to present an outline of biological applications of x-ray microtomography. We also provide perspectives of biological microtomography as the convergence of sciences in x-ray optics, biology, and structural analysis.

  9. Dentistry 4. X-ray diagnostics

    International Nuclear Information System (INIS)

    DIN pocketbook 267/4 gives an overview of the normative requirements of the new X-Ray and Radiation Protection Ordinance, which has been in effect since 1 November 2011. This DIN pocketbook is intended for anyone charged with professional responsibility for the use of ionizing radiation in dentistry, operators and users of x-ray devices, radiation protection officers, accredited experts, manufacturers as well as for anyone with an interest in radiation protection or optimal radiological diagnostics. It contains standards relating to the following areas: acceptance and constancy testing; devices for evaluating findings (monitors, film viewing devices), films, printers; archiving, designating, labelling. Adherence to the standards makes it possible to avoid distractive artefacts in x-ray images and optimise the quality of x-ray diagnostics in dentistry.

  10. Inelastic magnetic X-ray scattering

    Science.gov (United States)

    Platzman, P. M.; Tzoar, N.

    1985-04-01

    The theory of magnetic X-ray scattering is used to discuss the possibilities for employing inelastic scattering to probe the magnetic properties of condensed matter systems. In particular, it is shown how the interference between the nonmagnetic (Compton) and magnetic scattering arising from the use of circularly polarized X-rays is absolutely essential in such experiments. The very beautiful preliminary experiments by Sakai and Ono (1976) on Fe which use circularly polarized Moessbauer gamma-rays will be discussed. They already show the sensitivity of the technique to the 'magnetic form factor'. In addition, the physics of a unique quarter wave plate employed in obtaining circularly polarized X-rays is considered, and the implications of this advance for doing such experiments on existing synchrotron X-ray sources are discussed.

  11. 5.8 X-ray Calorimeters

    Science.gov (United States)

    Porter, F. Scott

    2008-01-01

    X-ray calorimeter instruments for astrophysics have seen rapid development since they were invented in 1984. The prime instrument on all currently planned X-ray spectroscopic observatories is based on calorimeter technology. This relatively simple detection concept that senses the energy of an incident photon by measuring the temperature rise of an absorber material at very low temperatures, can form the basis of a very high performance, non-dispersive spectrometer. State-of-the-art calorimeter instruments have resolving powers of over 3000, large simultaneous band-passes, and near unit efficiency. This coupled with the intrinsic imaging capability of a pixilated x-ray calorimeter array, allows true spectral-spatial instruments to be constructed. In this chapter I briefly review the detection scheme, the state-of-the-art in X-ray calorimeter instruments and the future outlook for this technology.

  12. Why Do I Need X-Rays?

    Science.gov (United States)

    ... information you need from the Academy of General Dentistry Wednesday, August 24, 2016 About | Contact InfoBites Quick ... Related Articles: X-Rays The Academy of General Dentistry (AGD) Sets the Record Straight on Dental X- ...

  13. Demonstration of X-ray talbot interferometry

    International Nuclear Information System (INIS)

    First Talbot interferometry in the hard X-ray region was demonstrated using a pair of transmission gratings made by forming gold stripes on glass plates. By aligning the gratings on the optical axis of X-rays with a separation that caused the Talbot effect by the first grating, moire fringes were produced inclining one grating slightly against the other around the optical axis. A phase object placed in front of the first grating was detected by moire-fringe bending. Using the technique of phase-shifting interferometry, the differential phase corresponding to the phase object could also be measured. This result suggests that X-ray Talbot interferometry is a novel and simple method for phase-sensitive X-ray radiography. (author)

  14. Silicon Wafer X-ray Mirror Project

    Data.gov (United States)

    National Aeronautics and Space Administration — In this one year research project, we propose to do the following four tasks;(1) Design the silicon wafer X-ray mirror demo unit and develop a ray-tracing code to...

  15. Experimental x-ray ghost imaging

    CERN Document Server

    Pelliccia, Daniele; Scheel, Mario; Cantelli, Valentina; Paganin, David M

    2016-01-01

    We report an experimental proof of principle for ghost imaging in the hard x-ray energy range. We used a synchrotron x-ray beam that was split using a thin crystal in Laue diffraction geometry. With an ultra-fast imaging camera, we were able to image x-rays generated by isolated electron bunches. At this time scale, the shot noise of the synchrotron emission process is measurable as speckles, leading to speckle correlation between the two beams. The integrated transmitted intensity from a sample located in the first beam was correlated with the spatially resolved intensity measured on the second, empty, beam to retrieve the shadow of the sample. The demonstration of ghost imaging with hard x-rays may open the way to protocols to reduce radiation damage in medical imaging and in non-destructive structural characterization using Free Electron Lasers.

  16. Tuberculosis, advanced - chest x-rays (image)

    Science.gov (United States)

    Tuberculosis is an infectious disease that causes inflammation, the formation of tubercules and other growths within tissue, ... death. These chest x-rays show advanced pulmonary tuberculosis. There are multiple light areas (opacities) of varying ...

  17. Linking Jet Emission, X-Ray States, and Hard X-Ray Tails in the Neutron Star X-Ray Binary GX 17+2

    NARCIS (Netherlands)

    S. Migliari; J.C.A. Miller-Jones; R.P. Fender; J. Homan; T. di Salvo; R.E. Rothschild; M.P. Rupen; J.A. Tomsick; R. Wijnands; M. van der Klis

    2007-01-01

    We present the results of simultaneous radio (VLA) and X-ray (RXTE) observations of the Z-type neutron star X-ray binary GX 17+2. The aim is to assess the coupling between X-ray and radio properties throughout its three rapidly variable X-ray states and during the time-resolved transitions. These ob

  18. Advanced detectors for X-ray microscopy

    International Nuclear Information System (INIS)

    Over the last decade the advances in x-ray microscopy have mainly been due to the development of x-ray source technology and to the micro-fabrication of x-ray optics. These advances have spurred the development of x-ray microscopes that are approaching the best resolution possible in the presence of radiation damage in the specimen. In addition, the development of specimen preparation techniques that reduce tile effects of radiation damage on the specimen are underway. In contrast, tile development or x-ray detectors for x-ray microscopy has been a low priority. The objective of the work was to develop a new detector for x-ray microscopy. This involved the modification of a Thorn EMI electron tube in order to sensitise the multiplier for soil x-rays In the energy range of interest (0.2-6 keV). The electron multiplier was then tested on a repetitive laser plasma source, which has been shown to be eminently suitable for a laboratory scale x-ray microscope, and the Scanning Transmission X-ray Microscope (STXM) at the National Synchrotron Light Source (NSLS), which is the most successful STXM presently in operation. The processed data from tile electron multiplier was used to characterise its response and assess its potential as all alternative to existing detectors. In addition, ID21, the microscopy beamline at the European Synchrotron Radiation Source (ESRF) was studied to assess the need for a beam position monitor close to the exit slit of the monochromator. This involved the ray tracing of the beamline. It was proposed that in the case of a crystal monochromator a beam position monitor based oil the total signal from a photo-emitting blade containing a number of different diameter pinholes was sufficient. However, for a grating monochromator tile beamline design relied upon feedback from a beam position monitor capable of detecting the height of the beam at tile entrance to the microscope. A number of conceptual designs for a monitor that could fulfil this

  19. Principles of X-ray Navigation

    Energy Technology Data Exchange (ETDEWEB)

    Hanson, John Eric; /SLAC

    2006-03-17

    X-ray navigation is a new concept in satellite navigation in which orientation, position and time are measured by observing stellar emissions in x-ray wavelengths. X-ray navigation offers the opportunity for a single instrument to be used to measure these parameters autonomously. Furthermore, this concept is not limited to missions in close proximity to the earth. X-ray navigation can be used on a variety of missions from satellites in low earth orbit to spacecraft on interplanetary missions. In 1997 the Unconventional Stellar Aspect Experiment (USA) will be launched as part of the Advanced Research and Global Observation Satellite (ARGOS). USA will provide the first platform for real-time experimentation in the field of x-ray navigation and also serves as an excellent case study for the design and manufacturing of space qualified systems in small, autonomous groups. Current techniques for determining the orientation of a satellite rely on observations of the earth, sun and stars in infrared, visible or ultraviolet wavelengths. It is possible to use x-ray imaging devices to provide arcsecond level measurement of attitude based on star patterns in the x-ray sky. This technique is explored with a simple simulation. Collimated x-ray detectors can be used on spinning satellites to provide a cheap and reliable measure of orientation. This is demonstrated using observations of the Crab Pulsar taken by the high Energy Astronomy Observatory (HEAO-1) in 1977. A single instrument concept is shown to be effective, but dependent on an a priori estimate of the guide star intensity and thus susceptible to errors in that estimate. A star scanner based on a differential measurement from two x-ray detectors eliminates the need for an a priori estimate of the guide star intensity. A first order model and a second order model of the two star scanner concepts are considered. Many of the stars that emit in the x-ray regime are also x-ray pulsars with frequency stability approaching a

  20. Allelic Mutations of KITLG, Encoding KIT Ligand, Cause Asymmetric and Unilateral Hearing Loss and Waardenburg Syndrome Type 2.

    Science.gov (United States)

    Zazo Seco, Celia; Serrão de Castro, Luciana; van Nierop, Josephine W; Morín, Matías; Jhangiani, Shalini; Verver, Eva J J; Schraders, Margit; Maiwald, Nadine; Wesdorp, Mieke; Venselaar, Hanka; Spruijt, Liesbeth; Oostrik, Jaap; Schoots, Jeroen; van Reeuwijk, Jeroen; Lelieveld, Stefan H; Huygen, Patrick L M; Insenser, María; Admiraal, Ronald J C; Pennings, Ronald J E; Hoefsloot, Lies H; Arias-Vásquez, Alejandro; de Ligt, Joep; Yntema, Helger G; Jansen, Joop H; Muzny, Donna M; Huls, Gerwin; van Rossum, Michelle M; Lupski, James R; Moreno-Pelayo, Miguel Angel; Kunst, Henricus P M; Kremer, Hannie

    2015-11-01

    Linkage analysis combined with whole-exome sequencing in a large family with congenital and stable non-syndromic unilateral and asymmetric hearing loss (NS-UHL/AHL) revealed a heterozygous truncating mutation, c.286_303delinsT (p.Ser96Ter), in KITLG. This mutation co-segregated with NS-UHL/AHL as a dominant trait with reduced penetrance. By screening a panel of probands with NS-UHL/AHL, we found an additional mutation, c.200_202del (p.His67_Cys68delinsArg). In vitro studies revealed that the p.His67_Cys68delinsArg transmembrane isoform of KITLG is not detectable at the cell membrane, supporting pathogenicity. KITLG encodes a ligand for the KIT receptor. Also, KITLG-KIT signaling and MITF are suggested to mutually interact in melanocyte development. Because mutations in MITF are causative of Waardenburg syndrome type 2 (WS2), we screened KITLG in suspected WS2-affected probands. A heterozygous missense mutation, c.310C>G (p.Leu104Val), that segregated with WS2 was identified in a small family. In vitro studies revealed that the p.Leu104Val transmembrane isoform of KITLG is located at the cell membrane, as is wild-type KITLG. However, in culture media of transfected cells, the p.Leu104Val soluble isoform of KITLG was reduced, and no soluble p.His67_Cys68delinsArg and p.Ser96Ter KITLG could be detected. These data suggest that mutations in KITLG associated with NS-UHL/AHL have a loss-of-function effect. We speculate that the mechanism of the mutation underlying WS2 and leading to membrane incorporation and reduced secretion of KITLG occurs via a dominant-negative or gain-of-function effect. Our study unveils different phenotypes associated with KITLG, previously associated with pigmentation abnormalities, and will thereby improve the genetic counseling given to individuals with KITLG variants. PMID:26522471

  1. Capacitor discharges, magnetohydrodynamics, X-rays, ultrasonics

    CERN Document Server

    Früngel, Frank B A

    1965-01-01

    High Speed Pulse Technology, Volume 1: Capacitor Discharges - Magnetohydrodynamics - X-Rays - Ultrasonics deals with the theoretical and engineering problems that arise in the capacitor discharge technique.This book discusses the characteristics of dielectric material, symmetrical switch tubes with mercury filling, and compensation conductor forms. The transformed discharge for highest current peaks, ignition transformer for internal combustion engines, and X-ray irradiation of subjects in mechanical motion are also elaborated. This text likewise covers the transformed capacitor discharge in w

  2. X-ray observations of stellar coronae

    International Nuclear Information System (INIS)

    The Einstein X-Ray Observatory (HEAO-2) has been used to search for X-ray emission from a wide variety of stars in our galaxy. A significant fraction of the data was obtained via the 8.5 magnitude stellar survey, which is reported here. This survey searches for X-ray emission from all stars brighter than visual magnitude 8.5 that serendipitously fell into the Imaging Proportional Counter field-of-view of the Einstein Observatory. The survey includes 227 separate fields that contain a total of 276 stars with V < 8.5. A wide range of spectral types and luminosity classes are represented. X-Ray emission in excess of 3-sigma above local background was discovered from 33 stars; 3-sigma upper limits have been determined for the remaining 243 stars. Comparison of X-ray source detection statistics with the expected frequency of stars brighter than V = 8.5 as a function of spectral type and luminosity class shows that the present visual magnitude limited survey can define the X-ray luminosity for dwarf F stars and provides constraints for the high luminosity tails of the X-ray luminosity functions for other types of stars constructed from other Einstein observations. The results of the 8.5 and Gliese survey have been integrated with those of four othe Einstein surveys. In total, X-ray emission has been detected from 156 stars, with most of these representing initial discoveries. Most of the observations can be explained by the presence of hot coronae around stars of nearly every spectral type. The consequences of these observations in terms of the presence of stellar outer convection zones, surface magnetic fields, and rotation rates are discussed

  3. Supernova remnants: the X-ray perspective

    OpenAIRE

    Vink, Jacco

    2011-01-01

    Supernova remnants are beautiful astronomical objects that are also of high scientific interest, because they provide insights into supernova explosion mechanisms, and because they are the likely sources of Galactic cosmic rays. X-ray observations are an important means to study these objects.And in particular the advances made in X-ray imaging spectroscopy over the last two decades has greatly increased our knowledge about supernova remnants. It has made it possible to map the products of fr...

  4. Scattered X-ray beam nondestructive testing

    Science.gov (United States)

    Harding, G.; Kosanetzky, J.

    1989-08-01

    X-ray scatter interactions generally dominate the linear attenuation coefficient at the photon energies typical of medical and industrial radiography. Specific advantages of X-ray scatter imaging, including a flexible choice of measurement geometry, direct 3D-imaging capability (tomography) and improved information for material characterization, are illustrated with results from Compton and coherent scatter devices. Applications of a Compton backscatter scanner (ComScan) in the aerospace industry and coherent scatter imaging in security screening are briefly considered.

  5. High speed gated x-ray imagers

    International Nuclear Information System (INIS)

    Single and multi-frame gated x-ray images with time-resolution as fast as 150 psec are described. These systems are based on the gating of microchannel plates in a stripline configuration. The gating voltage comes from the avalanche breakdown of reverse biased p-n junction producing high power voltage pulses as short as 70 psec. Results from single and four frame x-ray cameras used on Nova are described. 8 refs., 9 figs

  6. Multi-layer X-ray screens

    International Nuclear Information System (INIS)

    Rare earth (La or Gd) oxyhalide phosphors activated with thulium ion are employed in x-ray intensifying screens having modified ultraviolet emission characteristics which reduce crossover effects without significant reduction in brightness or film speed. Relatively low concentration levels of the thulium activator ion have been found to shift the ultraviolet emission of said phosphor when excited by x-rays to lower wavelengths in both the ultraviolet and near-ultraviolet spectral regions. (author)

  7. X-ray laser program at MBI

    Science.gov (United States)

    Nickles, P. V.; Janulewicz, K. A.; Lucianetti, A.; Priebe, G.; Zigler, A.; Rocca, J. J.; Sandner, W.

    2002-11-01

    A survey of the Max Born Institute (MBI) activities in the field of X-ray lasers (XRLs) is presented. The main interest is focused on the transient soft X-ray lasers. Additionally, much work is put to look for new, efficient, compact (table-top) pumping schemes with a prospect to be applied in practice. The current state of the research and the plans for the future are described as well.

  8. Refractive lens for hard x-rays

    International Nuclear Information System (INIS)

    The refractive lens for hard X-rays on the base of glass capillary is presented. The fabrication techniques for lens production are described. The model of refractive lens for hard X-ray is proposed. The model assume that the compound lens work similar one thin lens the complex refraction index of which is following: n=1-δ N + i β N. On the base of this model the parameters of focussed beam are calculated and the images of object are constructed

  9. Parametric X-rays at FAST

    Energy Technology Data Exchange (ETDEWEB)

    Sen, Tanaji [Fermilab

    2016-06-01

    We discuss the generation of parametric X-rays (PXR) in the photoinjector at the new FAST facility at Fermilab. Detailed calculations of the intensity spectrum, energy and angular widths and spectral brilliance with a diamond crystal are presented. We also report on expected results with PXR generated while the beam is channeling. The low emittance electron beam makes this facility a promising source for creating brilliant X-rays.

  10. Detection limits in x-ray fluorescence analysis

    International Nuclear Information System (INIS)

    X-ray fluorescence spectrometry is a well established analytical technique for elemental analysis of solids, powders, or liquids. This extended abstract briefly discusses the detection limits or sensitivity of x-ray spectrometers in x-ray fluorescence analysis

  11. The ROSAT X-ray Background Dipole

    CERN Document Server

    Plionis, M

    1998-01-01

    We estimate the dipole of the diffuse 1.5 keV X-ray background from the ROSAT all-sky survey map of Snowden et al (1995). We first subtract the diffuse Galactic emission by fitting to the data an exponential scale height, finite radius, disk model. We further exclude regions of low galactic latitudes, of local X-ray emission (eg the North Polar Spur) and model them using two different methods. We find that the ROSAT X-ray background (XRB) dipole points towards $(l,b) ~ (288, 25) \\pm 19 degrees within 30 degrees of the CMB dipole. Its direction is also in good agreement with the HEAO1 X-ray dipole at harder energies. The normalised amplitude of the ROSAT XRB dipole is about 1.7 per cent. Subtracting from the ROSAT map the expected X-ray background dipole due to the reflex motion of the observer with respect to the cosmic rest frame (Compton-Geting effect) we find the large-scale dipole of the X-ray emitting extragalactic sources having an amplitude 90% of the total XRB, in general agreement with the prediction...

  12. Portable fluid X-ray diagnostic system

    International Nuclear Information System (INIS)

    A portable X-ray image system is described comprising: (a) a base assembly including panels and hinges joining the panels together along edges, and compression stops for biasing the hinges to compensate for the weight of payload when mounted on the base assembly, the compression stops being located for interaction with the hinges for biasing the panels to exhibit upward bowing when laid upon a flat surface prior to loading, and to provide resiliency for facilitating the base assembly assuming a substantially flat configuration when a predetermined payload is placed upon the base assembly; (b) an X-ray member; (c) apparatus for detachably mounting a table member to the base assembly to hold the table member at a location above the base; (d) an X-ray source; (e) means for sensing X-rays to form an image; (f) means for mounting the X-ray source and the X-ray sensing means on opposite sides relative to the table member and supported by the base assembly; (g) releasable clamping apparatus associated with the hinges for rendering the joints of the base assembly substantially rigid; (h) means for adjustably leveling the base assembly, and (i) means for indicating the attitude of the base assembly with respect to the horizontal

  13. X-ray Emission of Hollow Atoms

    Institute of Scientific and Technical Information of China (English)

    ZhaoYongtao; XiaoGuoqing; ZhangXiaoan; YangZhihu; ChenXimeng; ZhangYanping

    2003-01-01

    We have systematically investigated the X-rays emission of hollow atoms (HA) which formed in the interaction of highly charged ions with a variety of solid surfaces at the atomic physics experimental setup of IMP. The X-ray spectra were measured by Si(Li) detectors with effective energy ranging from 1 keV to 60 keV. The results show that, the X-ray emission from the formed HA is closely correlated with the charge state of the projectile ions, and weakly correlated with the velocity of the projectile ions. For example, it was found that when Ar18+ ions interact with Be-target, the yield of K X-ray with character energy of 3.0 keV is 7.2×10-3 per ion, which is two times and 5 order of magnitude higher than those in the interactions of Ar17+ and Ar16+ ions respectively. When Ar15+ ions interact with the same targets, the Argon K X-ray would be too feeble to be detected. The X-ray yield with single ion in this experiment can be represented by the following equation,

  14. X-ray refraction-contrast imaging

    International Nuclear Information System (INIS)

    The conventional x-ray imaging for soft tissue often produced some adverse effects because of contrast medium and high-dose radiation. This report outlines the recently developed a very sensitive x-ray imaging method called as refraction contrast method or x-ray Schlieren method, which allows to detect density difference and irregularity in the soft tissue. In the apparatus (SPring-8 BL47XU), a light emitted from undulator was monochromatized by two-crystal x-ray spectroscope and x-ray passed through a sample was caught by imaging detector equipped with a combination of relay lens and CCD. When a glass capillary (outer diameter: 660 μm, inner diameter: 220 μm) was used as a measuring sample, it was confirmed that the image through geometrical refraction was obtained. When x-ray images of a dragonfly wing obtained by the Schlieren method (sample-detector distance: 5 m) and the conventional contact method were compared, it was demonstrated that reticulate structure of the wing was clearly observed by the former method but not at all by the latter one. At present, the study on efficacy of the refraction contrast imaging is under way using rodents. (M.N.)

  15. Years of Magnetic X-Ray Dichroism

    Science.gov (United States)

    van der Laan, Gerrit

    A historical overview of magnetic x-ray dichroism is presented. I describe the first theoretical and experimental results that have led to the development of this powerful technique for element-specific magnetometry. The theoretical progress of the sum rules is also described, starting with the spinorbit sum rule for the isotropic spectrum which led on to the spin and orbital moment sum rules for x-ray magnetic circular dichroism. The latter has been particularly useful to understand the magnetic anisotropy in thin films and multilayers. Further developments of circular dichroism in (resonant) photoemission and Auger, as well as x-ray detected optical activity, also are summarized. Currently, magnetic x-ray dichroism finds a wide application in x-ray spectroscopy and imaging for the study of magnetic materials and it is considered to be one of the most important discoveries in the field of magnetism in the last few decennia. It is hard to imagine modern research into magnetism without the aid of polarized x-rays.

  16. Technological challenges to X-ray FELs

    CERN Document Server

    Nuhn, H D

    2000-01-01

    There is strong interest in the development of X-ray Free Electron Lasers (X-ray FELs). The interest is driven by the scientific opportunities provided by intense, coherent X-rays. An X-ray FEL has all the characteristics of a fourth-generation source: brightness several orders of magnitude greater than presently achieved in third-generation sources, full transverse coherence, and sub-picosecond long pulses. The SLAC and DESY laboratories have presented detailed design studies for X-ray FEL user-facilities around the 0.1 nm wavelength regime (LCLS at SLAC, TESLA X-ray FEL at DESY). Both laboratories are engaged in proof-of-principle experiments at longer wavelengths (TTF FEL Phase I at 71 nm, VISA at 600-800 nm) with results expected in 1999. The technologies needed to achieve the proposed performances are those of bright electron sources, of acceleration systems capable of preserving the brightness of the source, and of undulators capable of meeting the magnetic and mechanical tolerances that are required fo...

  17. X-ray nanotomography in a SEM

    Science.gov (United States)

    Pauwels, Bart; Liu, Xuan; Sasov, Alexander

    2010-09-01

    We have developed an x-ray computer tomography (CT) add-on to perform X-ray micro- and nanotomography in any scanning electron microscope (SEM). The electron beam inside the SEM is focused on a metal target to generate x-rays. Part of the X-rays pass through the object that is installed on a rotation stage. Shadow X-ray images are collected by a CCD camera with direct photon detection mounted on the external wall of the SEM specimen chamber. An extensive description on the working principles of this micro/nano-CT add-on together with some examples of CT-scans will be given in this paper. The resolution that can be obtained with this set-up and the influence of the shape of the electron beam are discussed. Furthermore, possible improvements on this SEM-CT set-up will be discussed: replacing the backilluminated CCD with a fully depleted CCD with improved quantum efficiency (QE) for higher energies, reduces the exposure time by 6 when using metal targets with x-ray characteristic lines around 10 keV.

  18. A million X-ray detections

    Science.gov (United States)

    Webb, N.; XMM-Newton Survey Science Centre (SSC)

    2016-06-01

    Part of the XMM-Newton Survey Science Centre responsibilities include producing an X-ray catalogue of all X-ray sources detected with XMM-Newton. The latest version, 3XMM, takes advantage of improvements made to the source characterisation, reducing the number of spurious detections, but providing better astrometric precision, greater net sensitivity, as well as spectra and timeseries for a quarter of all catalogue detections. The data release 5 (3XMM-DR5, April 2015) is derived from the first 13 years of observations with XMM-Newton. 3XMM-DR5 includes 565962 X-ray detections and 396910 unique sources, detected as many as 48 times. 3XMM-DR5 is therefore the largest X-ray source catalogue. 3XMM-DR6 will be made available during 2016 and will augment the catalogue with 70000 X-ray detections. Over the next decade the catalogue will reach 1 million X-ray detections, including galaxy clusters, galaxies, tidal disruption events, gamma-ray bursts, stars, stellar mass compact objects, supernovae, planets, comets and many other systems. Thanks to the wide range of data products for each catalogue detection, the catalogue is an excellent resource for finding populations of sources as well as new and extreme objects. Here we present results achieved from searching the catalogue and discuss improvements that will be provided in future versions.

  19. The SAS-3 X-ray observatory

    Science.gov (United States)

    Mayer, W. F.

    1975-01-01

    The experiment section of the Small Astronomy Satellite-3 (SAS-3) launched in May 1975 is an X-ray observatory intended to determine the location of bright X-ray sources to an accuracy of 15 arc-seconds; to study a selected set of sources over a wide energy range, from 0.1 to 55 keV, while performing very specific measurements of the spectra and time variability of known X-ray sources; and to monitor the sky continuously for X-ray novae, flares, and unexpected phenomena. The improvements in SAS-3 spacecraft include a clock accurate to 1 part in 10 billion, rotatable solar panels, a programmable data format, and improved nutation damper, a delayed command system, improved magnetic trim and azimuth control systems. These improvements enable SAS-3 to perform three-axis stabilized observations of any point on the celestial sphere at any time of the year. The description of the experiment section and the SAS-3 operation is followed by a synopsis of scientific results obtained from the observations of X-ray sources, such as Vela X-1 (supposed to be an accreting neutron star), a transient source of hard X-ray (less than 36 min in duration) detected by SAS-3, the Crab Nebula pulsar, the Perseus cluster of galaxies, and the Vela supernova remnant.

  20. Optics Developments for X-Ray Astronomy

    Science.gov (United States)

    Ramsey, Brian

    2014-01-01

    X-ray optics has revolutionized x-ray astronomy. The degree of background suppression that these afford, have led to a tremendous increase in sensitivity. The current Chandra observatory has the same collecting area (approx. 10(exp 3)sq cm) as the non-imaging UHURU observatory, the first x-ray observatory which launched in 1970, but has 5 orders of magnitude more sensitivity due to its focusing optics. In addition, its 0.5 arcsec angular resolution has revealed a wealth of structure in many cosmic x-ray sources. The Chandra observatory achieved its resolution by using relatively thick pieces of Zerodur glass, which were meticulously figured and polished to form the four-shell nested array. The resulting optical assembly weighed around 1600 kg, and cost approximately $0.5B. The challenge for future x-ray astronomy missions is to greatly increase the collecting area (by one or more orders of magnitude) while maintaining high angular resolution, and all within realistic mass and budget constraints. A review of the current status of US optics for x-ray astronomy will be provided along with the challenges for future developments.

  1. The Constellation X-ray mission

    International Nuclear Information System (INIS)

    The Constellation-X mission is a large collecting area X-ray facility, emphasizing observations at high spectral resolution (E/ΔE∼300-3000) while covering a broad energy band (0.25-40 keV). By increasing the telescope aperture and utilizing efficient spectrometers the mission will achieve a factor of 100 increased sensitivity over current high-resolution X-ray spectroscopy missions. The use of focussing optics across the 10-40 keV band will provide a similar factor of 100 increased sensitivity in this band. Key technologies under development for the mission include lightweight high throughput X-ray optics, multilayer coatings to enhance the hard X-ray performance of X-ray optics, micro-calorimeter spectrometer arrays with 2 eV resolution, low-power and low-weight CCD arrays, lightweight gratings and hard X-ray detectors. When observations commence towards the end of the next decade, Constellation-X will address many pressing questions concerning the extremes of gravity and the evolution of the Universe

  2. Low exposure x-ray transmission measurements for contrast media detection with filtered x-rays

    International Nuclear Information System (INIS)

    A feasibility study of X-ray transmission measurements for contrast media with less exposure using filtered X-rays and their energy information is described. Based on measurements of the energy spectra of La-filtered X-rays, sensitivity to the contrast media and the relative quantity of dose exposure of filtered X-rays as the ratio to white X-rays are shown. The dose exposure for the measurement of iodine contrast media is reduced by more than 50% with a 400 μm thick La filter. By using a filter with atomic number close to that of iodine such as Cs and Ba, a greater reduction in dose exposure with a smaller increase in the current of the X-ray tube is expected. (author)

  3. Development of x-ray laminography under an x-ray microscopic condition

    Science.gov (United States)

    Hoshino, Masato; Uesugi, Kentaro; Takeuchi, Akihisa; Suzuki, Yoshio; Yagi, Naoto

    2011-07-01

    An x-ray laminography system under an x-ray microscopic condition was developed to obtain a three-dimensional structure of laterally-extended planar objects which were difficult to observe by x-ray tomography. An x-ray laminography technique was introduced to an x-ray transmission microscope with zone plate optics. Three prototype sample holders were evaluated for x-ray imaging laminography. Layered copper grid sheets were imaged as a laminated sample. Diatomite powder on a silicon nitride membrane was measured to confirm the applicability of this method to non-planar micro-specimens placed on the membrane. The three-dimensional information of diatom shells on the membrane was obtained at a spatial resolution of sub-micron. Images of biological cells on the membrane were also obtained by using a Zernike phase contrast technique.

  4. Development of x-ray laminography under an x-ray microscopic condition

    Energy Technology Data Exchange (ETDEWEB)

    Hoshino, Masato; Uesugi, Kentaro; Takeuchi, Akihisa; Suzuki, Yoshio; Yagi, Naoto [Japan Synchrotron Radiation Research Institute JASRI/SPring-8, 1-1-1 Kouto, Sayo, Hyogo 679-5198 (Japan)

    2011-07-15

    An x-ray laminography system under an x-ray microscopic condition was developed to obtain a three-dimensional structure of laterally-extended planar objects which were difficult to observe by x-ray tomography. An x-ray laminography technique was introduced to an x-ray transmission microscope with zone plate optics. Three prototype sample holders were evaluated for x-ray imaging laminography. Layered copper grid sheets were imaged as a laminated sample. Diatomite powder on a silicon nitride membrane was measured to confirm the applicability of this method to non-planar micro-specimens placed on the membrane. The three-dimensional information of diatom shells on the membrane was obtained at a spatial resolution of sub-micron. Images of biological cells on the membrane were also obtained by using a Zernike phase contrast technique.

  5. Development of x-ray laminography under an x-ray microscopic condition

    International Nuclear Information System (INIS)

    An x-ray laminography system under an x-ray microscopic condition was developed to obtain a three-dimensional structure of laterally-extended planar objects which were difficult to observe by x-ray tomography. An x-ray laminography technique was introduced to an x-ray transmission microscope with zone plate optics. Three prototype sample holders were evaluated for x-ray imaging laminography. Layered copper grid sheets were imaged as a laminated sample. Diatomite powder on a silicon nitride membrane was measured to confirm the applicability of this method to non-planar micro-specimens placed on the membrane. The three-dimensional information of diatom shells on the membrane was obtained at a spatial resolution of sub-micron. Images of biological cells on the membrane were also obtained by using a Zernike phase contrast technique.

  6. Geometrical Effect of Target Crystal on Pxr Generation as a Coherent X-Ray Source

    Science.gov (United States)

    Hayakawa, Y.; Hayakawa, K.; Inagaki, M.; Kuwada, T.; Nakao, K.; Nogami, K.; Sakai, T.; Sato, I.; Takahashi, Y.; Tanaka, T.

    2010-04-01

    The experiments of the PXR performance carried out for the target crystals with different cutting planes have shown significant difference in the PXR property, which suggests another way to increase the PXR intensity than by increasing the electron beam current. In order to investigate the effect of the geometrical condition of the crystal surface on the PXR property, the experiments have been carried out for the target crystal with a knife-edge-shaped cut surface. For the case with symmetric Bragg geometry on the front surface and asymmetric condition on the rear surface, the rather low intensity X-ray beam has shown considerably good spatial coherence. The X-ray beam with narrow line width has made it possible to obtain X-ray absorption spectra with a high resolution. In contrast, relatively high intensity, which enabled taking an absorption image with the exposure for several tens of seconds, has been obtained for the geometry with asymmetric front surface and symmetric rear surface. This configuration, however, has raised a problem of degradation in the spatial coherence of the X-rays due to the superposition of two different X-ray beams.

  7. A damage-free structural determination of the highly X-ray irradiation-sensitive active site of bovine heart cytochrome c oxidase by the femtosecond X-ray laser crystallography using SACLA

    International Nuclear Information System (INIS)

    A peroxide-like ligand in the O2 reduction site of the fully oxidized bovine heart cytochrome c oxidase (CcO) as isolated blocks the proton pump activity of CcO. High resolution structural determination of the ligand-bound O2 reduction site was essentially impossible because of the high sensitivity of the bound ligand to X-ray irradiation. The present high resolution and damage-free determination of the site by the femtosecond X-ray crystallographic analysis using SACLA, an X-ray free electron laser facility, has provided various insights for the mechanism of proton pump. Furthermore, the successful determination by femtosecond level X-ray irradiation assures that X-ray structural changes during the physiological processes driven by proteins are able to be followed with the time resolution sufficiently high for following any physiologically relevant process in the protein. The concept of Picobiology, for which the present newly developed time-resolved X-ray structural technique together with a recently established time-resolved infrared spectroscopy are prerequisite, is introduced for showing the importance of the femtosecond X-ray laser crystallography for understanding of Life Process. (author)

  8. Measurements of transient electron density distributions by femtosecond X-ray diffraction

    International Nuclear Information System (INIS)

    This thesis concerns measurements of transient charge density maps by femtosecond X-ray diffraction. Different X-ray diffraction methods will be considered, particularly with regard to their application in femtosecond X-ray diffraction. The rotation method is commonly used in stationary X-ray diffraction. In the work in hand an X-ray diffraction experiment is demonstrated, which combines the method with ultrafast X-ray pulses. This experiment is the first implementation which makes use of the rotation method to map transient intensities of a multitude of Bragg reflections. As a prototype material Bismuth is used, which previously was studied frequently by femtosecond X-ray diffraction by measuring Bragg reflections successively. The experimental results of the present work are compared with the literature data. In the second part a powder-diffraction experiment will be presented, which is used to study the dynamics of the electron-density distribution on ultrafast time scales. The experiment investigates a transition metal complex after photoexcitation of the metal to ligand charge transfer state. Besides expected results, i. e. the change of the bond length between the metal and the ligand and the transfer of electronic charge from the metal to the ligand, a strong contribution of the anion to the charge transfer was found. Furthermore, the charge transfer has predominantly a cooperative character. That is, the excitation of a single complex causes an alteration of the charge density of several neighboring units. The results show that more than 30 transition-metal complexes and 60 anions contribute to the charge transfer. This collective response is a consequence of the strong coulomb interactions of the densely packed ions.

  9. Effects of x-ray does on rhizosphere studies using x-ray computed tomography

    OpenAIRE

    Susan Zappala; Jonathan R Helliwell; Tracy, Saoirse R.; Stefan Mairhofer; Sturrock, Craig J.; Tony Pridmore; Malcolm Bennett; Sacha J. Mooney

    2013-01-01

    X-ray Computed Tomography (CT) is a non-destructive imaging technique originally designed for diagnostic medicine, which was adopted for rhizosphere and soil science applications in the early 1980s. X-ray CT enables researchers to simultaneously visualise and quantify the heterogeneous soil matrix of mineral grains, organic matter, air-filled pores and water-filled pores. Additionally, X-ray CT allows visualisation of plant roots in situ without the need for traditional invasive methods such ...

  10. Simulation of transmitted X-rays in a polycapillary X-ray lens

    Energy Technology Data Exchange (ETDEWEB)

    Peng, Shiqi [The Key Laboratory of Beam Technology and Material Modification of the Ministry of Education, Beijing Normal University, Beijing 100875 (China); College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China); Beijing Radiation Center, Beijing 100875 (China); Liu, Zhiguo, E-mail: liuzhiguo512@126.com [The Key Laboratory of Beam Technology and Material Modification of the Ministry of Education, Beijing Normal University, Beijing 100875 (China); College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China); Beijing Radiation Center, Beijing 100875 (China); Sun, Tianxi; Wang, Kai; Yi, Longtao; Yang, Kui; Chen, Man; Wang, Jinbang [The Key Laboratory of Beam Technology and Material Modification of the Ministry of Education, Beijing Normal University, Beijing 100875 (China); College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China); Beijing Radiation Center, Beijing 100875 (China)

    2015-09-21

    The geometrical description of capillary systems adjusted for the controlled guiding of X-rays and the basic theory of the transmission of X-rays are presented. A method of numerical calculation, based on Ray-Tracing theory, is developed to simulate the transmission efficiency of an X-ray parallel lens and the shape and size of the light spot gain from it. The simulation results for two half-lenses are in good agreement with the experimental results.

  11. Simulation of transmitted X-rays in a polycapillary X-ray lens

    International Nuclear Information System (INIS)

    The geometrical description of capillary systems adjusted for the controlled guiding of X-rays and the basic theory of the transmission of X-rays are presented. A method of numerical calculation, based on Ray-Tracing theory, is developed to simulate the transmission efficiency of an X-ray parallel lens and the shape and size of the light spot gain from it. The simulation results for two half-lenses are in good agreement with the experimental results

  12. X-ray photoemission spectroscopy study of hexavalent uranium compounds

    International Nuclear Information System (INIS)

    The electronic structure of the outer occupied levels of a series of hexavalent uranium (predominately uranyl) compounds was studied using x-ray photoemission spectroscopy (XPS). The changes in the spectral features of the outer occupied levels with the variation of the uranium-oxygen bond lengths (1.7--2.1 A) are systematically investigated. Previously unexplained spectral structure has been found to result from ligand-field splitting of the occupied U 6p3/2 levels. The XPS results are compared with predictions of a relativistic molecular-cluster calculation and with the results of a simple point-charge crystal-field model. When the crystalline electric fields generated by both the primary and secondary ligands are taken into consideration, excellent quantitative agreement is obtained between the XPS data and the molecular-cluster results with no parameter adjustment

  13. Cloning, expression, purification, crystallization and preliminary X-ray diffraction analysis of Rv2827c from Mycobacterium tuberculosis

    International Nuclear Information System (INIS)

    M. tuberculosis hypothetical protein Rv2827c was cloned, expressed, purified and crystallized. Preliminary X-ray diffraction data were collected to a resolution of 1.93 Å. The hypothetical protein Rv2827c from Mycobacterium tuberculosis was cloned and heterologously expressed in Escherichia coli. It was purified using affinity and size-exclusion chromatographic techniques and then crystallized. Preliminary X-ray diffraction data analysis suggests the presence of two translationally related molecules in the asymmetric unit of the orthorhombic crystals

  14. Laser-based X-ray and electron source for X-ray fluorescence studies

    Science.gov (United States)

    Valle Brozas, F.; Crego, A.; Roso, L.; Peralta Conde, A.

    2016-08-01

    In this work, we present a modification to conventional X-rays fluorescence using electrons as excitation source and compare it with the traditional X-ray excitation for the study of pigments. For this purpose, we have constructed a laser-based source capable to produce X-rays as well as electrons. Because of the large penetration depth of X-rays, the collected fluorescence signal is a combination of several material layers of the artwork under study. However, electrons are stopped in the first layers, allowing a more superficial analysis. We show that the combination of both excitation sources can provide extremely valuable information about the structure of the artwork.

  15. Comparison of x-ray output of inverter-type x-ray equipment

    International Nuclear Information System (INIS)

    The x-ray output of 54 inverter-type x-ray apparatuses used at 18 institutions was investigated. The reproducibility and linearity of x-ray output and variations among the x-ray equipment were evaluated using the same fluorescence meter. In addition, the x-ray apparatuses were re-measured using the same non-invasive instrument to check for variations in tube voltage, tube current, and irradiation time. The non-invasive instrument was calibrated by simultaneously obtaining measurements with an invasive instrument, employing the tube voltage and current used for the invasive instrument, and the difference was calculated. Reproducibility of x-ray output was satisfactory for all x-ray apparatuses. The coefficient of variation was 0.04 or less for irradiation times of 5 ms or longer. In 84.3% of all x-ray equipment, variation in the linearity of x-ray output was 15% or less for an irradiation time of 5 ms. However, for all the apparatuses, the figure was 50% when irradiation time was the shortest (1 to 3 ms). Variation in x-ray output increased as irradiation time decreased. Variation in x-ray output ranged between 1.8 and 2.5 compared with the maximum and minimum values, excluding those obtained at the shortest irradiation time. The relative standard deviation ranged from ±15.5% to ±21.0%. The largest variation in x-ray output was confirmed in regions irradiated for the shortest time, with smaller variations observed for longer irradiation times. The major factor responsible for variation in x-ray output in regions irradiated for 10 ms or longer, which is a relatively long irradiation time, was variation in tube current. Variation in tube current was slightly greater than 30% at maximum, with an average value of 7% compared with the preset tube current. Variations in x-ray output in regions irradiated for the shortest time were due to photographic effects related to the rise and fall times of the tube voltage waveform. Accordingly, in order to obtain constant x-ray

  16. Fabrication of large area X-ray diffraction grating for X-ray phase imaging

    International Nuclear Information System (INIS)

    X-ray lithography, which uses highly directional synchrotron radiation, is one of the technologies that can be used for fabricating micrometer-sized structures. In X-ray lithography, the accuracy of the fabricated structure depends largely on the accuracy of the X-ray mask. Since X-ray radiation is highly directional, a micro-fabrication technology that produces un-tapered and high aspect ratio highly absorbent structures on a low absorbent membrane is required. Conventionally, a resin material is used as the support membrane for large area X-ray masks. However, resin membranes have the disadvantage that they can sag after several cycles of X-ray exposure due to the heat generated by the X-rays. Therefore, we proposed and used thin carbon wafers for the membrane material because carbon has an extremely small thermal expansion coefficient. We fabricated new carbon membrane X-ray masks, and these results of X-ray lithography demonstrate the superior performance.

  17. X-ray-induced photo-chemistry and X-ray absorption spectroscopy of biological samples

    OpenAIRE

    George, Graham N.; Pickering, Ingrid J.; Pushie, M. Jake; Nienaber, Kurt; Hackett, Mark J.; Ascone, Isabella; Hedman, Britt; Hodgson, Keith O.; Aitken, Jade B.; Levina, Aviva; Glover, Christopher; Lay, Peter A.

    2012-01-01

    X-ray-induced photo-chemistry of metal sites within biological molecules is a concern for X-ray absorption spectroscopy, X-ray crystallography and other techniques in which samples are illuminated with X-rays. The effects of X-ray-induced photo-chemistry are reviewed and the methods used to mitigate these in X-ray absorption spectroscopy are outlined.

  18. Handbook of X-Ray Astronomy

    Science.gov (United States)

    Arnaud, Keith A. (Editor); Smith, Randall K.; Siemiginowska, Aneta

    2011-01-01

    X-ray astronomy was born in the aftermath of World War II as military rockets were repurposed to lift radiation detectors above the atmosphere for a few minutes at a time. These early flights detected and studied X-ray emission from the Solar corona. The first sources beyond the Solar System were detected during a rocket flight in 1962 by a team headed by Riccardo Giaccom at American Science and Engineering, a company founded by physicists from MIT. The rocket used Geiger counters with a system designed to reduce non-X-ray backgrounds and collimators limiting the region of sky seen by the counters. As the rocket spun, the field of view (FOV) happened to pass over what was later found to be the brightest non-Solar X-ray source; later designated See X-1. It also detected a uniform background glow which could not be resolved into individual sources. A follow-up campaign using X-ray detectors with better spatial resolution and optical telescopes identified See X-1 as an interacting binary with a compact (neutron star) primary. This success led to further suborbital rocket flights by a number of groups. More X-ray binaries were discovered, as well as X-ray emission from supernova remnants, the radio galaxies M87 and Cygnus-A, and the Coma cluster. Detectors were improved and Geiger counters were replaced by proportional counters, which provided information about energy spectra of the sources. A constant challenge was determining precise positions of sources as only collimators were available.

  19. Ray-tracing simulation and Au-girds experimental test on spatial resolution of KBA X-ray microscope

    International Nuclear Information System (INIS)

    The spatial resolution of KBA X-ray microscope is studied with ray-tracing simulation and experimental test. In the experiment, the imaging object is Au grid, backlit by X-rays produced by the 9th laser interaction with Cu target on Shenguang II laser facility. The spatial resolution of KBA X-ray microscope is found to be asymmetric about the center of its field of view. Moreover, the experimental data show that, the variation of resolution in the reducing direction of grazing incidence angle is smaller than that in the increasing direction, and the resolution asymmetry is about 30% relative to the field center. (authors)

  20. Superoxide reductase from Nanoarchaeum equitans: expression, purification, crystallization and preliminary X-ray crystallographic analysis

    International Nuclear Information System (INIS)

    Diffraction-quality crystals of N. equitans neelaredoxin have been produced. The expression, purification and crystallization of the protein and preliminary X-ray crystallographic analysis of the crystals are reported. Superoxide reductases (SORs) are the most recent oxygen-detoxification system to be identified in anaerobic and microaerobic bacteria and archaea. SORs are metalloproteins that are characterized by their possession of a catalytic nonhaem iron centre in the ferrous form coordinated by four histidine ligands and one cysteine ligand. Ignicoccus hospitalis, a hyperthermophilic crenarchaeon, is the only organism known to date to serve as a host for Nanoarchaeum equitans, a nanosized hyperthermophilic archaeon isolated from a submarine hot vent which completely depends on the presence of and contact with I. hospitalis cells for growth to occur. Similarly to I. hospitalis, N. equitans has a neelaredoxin (a 1Fe-type SOR) that keeps toxic oxygen species under control, catalysing the one-electron reduction of superoxide to hydrogen peroxide. Blue crystals of recombinant N. equitans SOR in the oxidized form (12.7 kDa, 109 residues) were obtained using polyethylene glycol (PEG 2000 MME) as precipitant. These crystals diffracted to 1.9 Å resolution at 100 K and belonged to the orthorhombic space group P212121, with unit-cell parameters a = 51.88, b = 82.01, c = 91.30 Å. Cell-content analysis suggested the presence of four monomers in the asymmetric unit. The Matthews coefficient (VM) was determined to be 1.9 Å3 Da−1, corresponding to an estimated solvent content of 36%. Self-rotation function and native Patterson calculations suggested a tetramer with 222 point-group symmetry, similar to other 1Fe-SORs. The three-dimensional structure will be determined by the molecular-replacement method

  1. X-raying with low dose irradiation

    International Nuclear Information System (INIS)

    With the purpose of the improvement of diagnostics quality and reduction of beam load on a patient in modern x-ray devices pulse x-raying is applied. It is based on the using of radiation pulses with various frequencies of intervals between them instead of continuous radiation. At pulse x-raying with the net control the principle of filling of an interval is used, when the information about the image, received with the last pulse, get into memory and is displayed before occurrence of other pulse. It creates impression of the continuous image even at low frequency of pulses. Due to the unique concept of the simultaneous (double) control, all of 3 parameters, which define the quality of the image (pressure(voltage), force of a current and length of a pulse), are adjusted automatically at each pulse, thus optimum adaptation to varied thickness of object during dynamic researches occurs. At x-raying pulse the presence of a free interval from x-ray radiation between two pulses results in the decrease of a radiation dose. Pulsing occurs some times per one second with equal intervals between pulses. Thus, the degree of decrease irradiation dose depends on duration of a pause between pulses. On the screen the image of last pulse before occurrence of the following is kept and repeats. The principle of x-raying pulse was realized in system Grid Controlled Fluoroscopy by the firm 'Philips Medi zin Systeme'. In the x-ray tube of this system inclusion and de energizing of radiation occurs directly on a source. Electron cloud is broken off by the special grid, which is located between the cathode and the anode and operates as a barrier. Thus the tube continues to be energized. In usual devices for pulses formation is used generator pulsation system, which at increase and attenuation of a x-ray pulse results in occurrence of the increasing and fading radiation which are not participating in the formation of the image, but creating beam load on the patient and the personnel. Thus

  2. Moessbauer meets Fano at X-ray energies: Controlled line shapes in cooperative emission from nuclei

    Energy Technology Data Exchange (ETDEWEB)

    Heeg, Kilian P.; Ott, Christian; Pfeifer, Thomas; Evers, Joerg [Max-Planck-Institut fuer Kernphysik, Heidelberg (Germany); Schumacher, Daniel; Wille, Hans-Christian; Roehlsberger, Ralf [Deutsches Elektronen-Synchrotron DESY, Hamburg (Germany)

    2014-07-01

    Control of spectroscopic line shapes at hard X-ray energies is demonstrated in the reflectance of a thin film cavity with embedded Moessbauer nuclei. Tunable Fano interference between a spectrally broad cavity response and a narrow bound state nuclear contribution enables us to switch between Lorentz- and Fano-profiles. Spectroscopic signatures such as the cooperative Lamb shift and superradiant line broadening are extracted from the recorded asymmetric line shapes with high precision and agree excellently with our theoretical model. Our results advance spectroscopy and precision metrology in the hard X-ray domain, and provide access to a multitude of applications linked to Fano interference.

  3. Toward atomic resolution diffractive imaging of isolated molecules with x-ray free-electron lasers

    DEFF Research Database (Denmark)

    Stern, Stephan; Holmegaard, Lotte; Filsinger, Frank;

    2014-01-01

    We give a detailed account of the theoretical analysis and the experimental results of an x-ray-diffraction experiment on quantum-state selected and strongly laser-aligned gas-phase ensembles of the prototypical large asymmetric rotor molecule 2,5-diiodobenzonitrile, performed at the Linac Coherent...... Light Source [Phys. Rev. Lett. 112, 083002 (2014)]. This experiment is the first step toward coherent diffractive imaging of structures and structural dynamics of isolated molecules at atomic resolution, i. e., picometers and femtoseconds, using x-ray free-electron lasers....

  4. Toward atomic resolution diffractive imaging of isolated molecules with x-ray free-electron lasers

    CERN Document Server

    Stern, Stephan; Filsinger, Frank; Rouzée, Arnaud; Rudenko, Artem; Johnsson, Per; Martin, Andrew V; Barty, Anton; Bostedt, Christoph; Bozek, John D; Coffee, Ryan N; Epp, Sascha; Erk, Benjamin; Foucar, Lutz; Hartmann, Robert; Kimmel, Nils; Kühnel, Kai-Uwe; Maurer, Jochen; Messerschmidt, Marc; Rudek, Benedikt; Starodub, Dmitri G; Thøgersen, Jan; Weidenspointner, Georg; White, Thomas A; Stapelfeldt, Henrik; Rolles, Daniel; Chapman, Henry N; Küpper, Jochen

    2014-01-01

    We give a detailed account of the theoretical analysis and the experimental results of an x-ray-diffraction experiment on quantum-state selected and strongly laser-aligned gas-phase ensembles of the prototypical large asymmetric rotor molecule 2,5-diiodobenzonitrile, performed at the Linac Coherent Light Source [Phys. Rev. Lett. 112, 083002 (2014)]. This experiment is the first step toward coherent diffractive imaging of structures and structural dynamics of isolated molecules at atomic resolution, i. e., picometers and femtoseconds, using x-ray free-electron lasers.

  5. Moessbauer meets Fano at X-ray energies: Controlled line shapes in cooperative emission from nuclei

    International Nuclear Information System (INIS)

    Control of spectroscopic line shapes at hard X-ray energies is demonstrated in the reflectance of a thin film cavity with embedded Moessbauer nuclei. Tunable Fano interference between a spectrally broad cavity response and a narrow bound state nuclear contribution enables us to switch between Lorentz- and Fano-profiles. Spectroscopic signatures such as the cooperative Lamb shift and superradiant line broadening are extracted from the recorded asymmetric line shapes with high precision and agree excellently with our theoretical model. Our results advance spectroscopy and precision metrology in the hard X-ray domain, and provide access to a multitude of applications linked to Fano interference.

  6. New achievements in X-ray optics——the X-ray lens and its applications

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    An X-ray lens consists of a large number of X-ray capillaries. It can collect divergent X-rays emitted from an X-ray source and form a focused or parallel beam of high intensity. So it is an effective tool for adjusting and controlling wide bandwidth X-ray beams. In this paper, the X-ray lens made by the X-ray Optics Laboratory of Institute of Low Energy Nuclear Physics at Beijing Normal University and its applications in the field of X-ray analysis are presented.

  7. Coordination symmetry determination of some lanthanide complexes by x-ray diffraction

    International Nuclear Information System (INIS)

    The x-ray determination of the crystal and molecular structures of three lanthanide complexes is described. The work is a contribution to the study of the coordination chemistry of lanthanide ions with organic ligands and in particular, it aims to compare the observed point symmetry of the ion environment with spectroscopic predictions. (author)

  8. Synthesis of novel chiral phosphine-triazine ligand derived from α-phenylethylamine for Pd-catalyzed asymmetric allylic alkylation

    Institute of Scientific and Technical Information of China (English)

    Jia Di Huang; Xiang Ping Hu; Zhuo Zheng

    2008-01-01

    A novel chiral phosphine-triazine ligand was synthesized from chiral model reaction of Pd-catalyzed allylic alkylation of rac-l,3-diphenylprop-2-en-l-yl pivalate with dimethyl malonate, good enantioselectivity (90% e.e.) was obtained by using this ligand.

  9. X-Ray Calorimeter Arrays for Astrophysics

    Science.gov (United States)

    Kilbourne, Caroline A.

    2009-01-01

    High-resolution x-ray spectroscopy is a powerful tool for studying the evolving universe. The grating spectrometers on the XMM and Chandra satellites started a new era in x-ray astronomy, but there remains a need for instrumentation that can provide higher spectral resolution with high throughput in the Fe-K band (around 6 keV) and can enable imaging spectroscopy of extended sources, such as supernova remnants and galaxy clusters. The instrumentation needed is a broad-band imaging spectrometer - basically an x-ray camera that can distinguish tens of thousands of x-ray colors. The potential benefits to astrophysics of using a low-temperature calorimeter to determine the energy of an incident x-ray photon via measurement of a small change in temperature was first articulated by S. H. Moseley over two decades ago. In the time since, technological progress has been steady, though full realization in an orbiting x-ray telescope is still awaited. A low-temperature calorimeter can be characterized by the type of thermometer it uses, and three types presently dominate the field. The first two types are temperature-sensitive resistors - semiconductors in the metal-insulator transition and superconductors operated in the superconducting-normal transition. The third type uses a paramagnetic thermometer. These types can be considered the three generations of x-ray calorimeters; by now each has demonstrated a resolving power of 2000 at 6 keV, but only a semiconductor calorimeter system has been developed to spaceflight readiness. The Soft X-ray Spectrometer on Astro-H, expected to launch in 2013, will use an array of silicon thermistors with I-IgTe x-ray absorbers that will operate at 50 mK. Both the semiconductor and superconductor calorimeters have been implemented in small arrays, kilo-pixel arrays of the superconducting calorimeters are just now being produced, and it is anticipated that much larger arrays will require the non-dissipative advantage of magnetic thermometers.

  10. X-ray spectroscopy an introduction

    CERN Document Server

    Agarwal, Bipin K

    1979-01-01

    Rontgen's discovery of X-rays in 1895 launched a subject which became central to the development of modern physics. The verification of many of the predic­ tions of quantum theory by X-ray spectroscopy in the early part of the twen­ tieth century stimulated great interest in thi's area, which has subsequently influenced fields as diverse as chemical physics, nuclear physics, and the study of the electronic properties of solids, and led to the development of techniques such as Auger, Raman, and X-ray photoelectron spectroscopy. The improvement of the theoretical understanding of the physics underlying X-ray spectroscopy has been accompanied by advances in experimental techniques, and the subject provides an instructive example of how progress on both these fronts can be mutually beneficial. This book strikes a balance between his­ torical description, which illustrates this symbiosis, and the discussion of new developments. The application of X-ray spectroscopic methods to the in­ vestigation of chemical b...

  11. Polarisation modulation in X-ray binaries

    Science.gov (United States)

    Ingram, Adam; Maccarone, Thomas

    2016-07-01

    X-ray polarimetry promises to provide a powerful new lever arm for studying accretion onto black holes with the next generation of X-ray telescopes. I will discuss how polarisation can be used to help constrain the physical origin of quasi-periodic oscillations (QPOs) observed in the X-ray light curves of accreting black holes. QPOs may be signatures of the frame dragging effect: in General Relativity, a spinning black hole twists up the surrounding space-time, causing vertical precession of nearby orbits. In the truncated disc / precessing inner flow model, the entire inner accretion flow precesses as a solid body causing a modulation in the X-ray flux through solid angle and Doppler effects. This model also predicts the observed polarisation of the X-ray signal to vary quasi-periodically. I will summarise our work to model the polarisation signal from a precessing accretion flow, starting with simple assumptions about the emission mechanism but taking General Relativity fully into account. We find that it should be possible to measure the predicted modulation in polarisation degree for a reasonable region of parameter space with a polarimeter capable of detecting ~60 counts per second from a bright black hole binary. I will also show that sensitivity can be greatly improved by correlating the signal with a high count rate reference band signal.

  12. Optics for coherent X-ray applications.

    Science.gov (United States)

    Yabashi, Makina; Tono, Kensuke; Mimura, Hidekazu; Matsuyama, Satoshi; Yamauchi, Kazuto; Tanaka, Takashi; Tanaka, Hitoshi; Tamasaku, Kenji; Ohashi, Haruhiko; Goto, Shunji; Ishikawa, Tetsuya

    2014-09-01

    Developments of X-ray optics for full utilization of diffraction-limited storage rings (DLSRs) are presented. The expected performance of DLSRs is introduced using the design parameters of SPring-8 II. To develop optical elements applicable to manipulation of coherent X-rays, advanced technologies on precise processing and metrology were invented. With propagation-based coherent X-rays at the 1 km beamline of SPring-8, a beryllium window fabricated with the physical-vapour-deposition method was found to have ideal speckle-free properties. The elastic emission machining method was utilized for developing reflective mirrors without distortion of the wavefronts. The method was further applied to production of diffraction-limited focusing mirrors generating the smallest spot size in the sub-10 nm regime. To enable production of ultra-intense nanobeams at DLSRs, a low-vibration cooling system for a high-heat-load monochromator and advanced diagnostic systems to characterize X-ray beam properties precisely were developed. Finally, new experimental schemes for combinative nano-analysis and spectroscopy realised with novel X-ray optics are discussed. PMID:25177986

  13. Nonlinear X-ray Compton Scattering

    CERN Document Server

    Fuchs, Matthias; Chen, Jian; Ghimire, Shambhu; Shwartz, Sharon; Kozina, Michael; Jiang, Mason; Henighan, Thomas; Bray, Crystal; Ndabashimiye, Georges; Bucksbaum, P H; Feng, Yiping; Herrmann, Sven; Carini, Gabriella; Pines, Jack; Hart, Philip; Kenney, Christopher; Guillet, Serge; Boutet, Sebastien; Williams, Garth; Messerschmidt, Marc; Seibert, Marvin; Moeller, Stefan; Hastings, Jerome B; Reis, David A

    2015-01-01

    X-ray scattering is a weak linear probe of matter. It is primarily sensitive to the position of electrons and their momentum distribution. Elastic X-ray scattering forms the basis of atomic structural determination while inelastic Compton scattering is often used as a spectroscopic probe of both single-particle excitations and collective modes. X-ray free-electron lasers (XFELs) are unique tools for studying matter on its natural time and length scales due to their bright and coherent ultrashort pulses. However, in the focus of an XFEL the assumption of a weak linear probe breaks down, and nonlinear light-matter interactions can become ubiquitous. The field can be sufficiently high that even non-resonant multiphoton interactions at hard X-rays wavelengths become relevant. Here we report the observation of one of the most fundamental nonlinear X-ray-matter interactions, the simultaneous Compton scattering of two identical photons producing a single photon at nearly twice the photon energy. We measure scattered...

  14. X-Ray Surveyor Mission Concept

    Science.gov (United States)

    Gaskin, Jessica

    2015-10-01

    An initial concept study for the X-ray Surveyor mission was carried-out by the Advanced Concept Office at Marshall Space Flight Center (MSFC), with a strawman payload and related requirements that were provided by an Informal Mission Concept Team, comprised of MSFC and Smithsonian Astrophysics Observatory (SAO) scientists plus a diverse cross-section of the X-ray community. The study included a detailed assessment of the requirements, a preliminary design, a mission analysis, and a preliminary cost estimate. The X-ray Surveyor strawman payload is comprised of a high-resolution mirror assembly and an instrument set, which may include an X-ray microcalorimeter, a high-definition imager, and a dispersive grating spectrometer and its readout. The mirror assembly will consist of highly nested, thin, grazing-incidence mirrors, for which a number of technical approaches are currently under development—including adjustable X-ray optics, differential deposition, and new polishing techniques applied to a variety of substrates. This study benefits from previous studies of large missions carried out over the past two decades, such as Con-X, AXSIO and IXO, and in most areas, points to mission requirements no more stringent than those of Chandra.

  15. Advanced X-ray diffractive optics

    Energy Technology Data Exchange (ETDEWEB)

    Vila-Comamala, J; Jefimovs, K; Sarkar, S S; Solak, H H; Guzenko, V A; Stampanoni, M; Marone, F; Raabe, J; Tzvetkov, G; Grolimund, D; Borca, C N; David, C [Paul Scherrer Institut, CH-5232 Villigen PSI (Switzerland); Pilvi, T; Ritala, M [Department of Chemistry, FIN-00014 University of Helsinki (Finland); Fink, R H [Friedrich-Alexander Universitaet, D-91058 Erlangen (Germany); Kaulich, B, E-mail: joan.vila@psi.c [ELETTRA Sincrotrone, I-34012 Basovizza (Italy)

    2009-09-01

    X-ray microscopy greatly benefits from the advances in x-ray optics. At the Paul Scherrer Institut, developments in x-ray diffractive optics include the manufacture and optimization of Fresnel zone plates (FZPs) and diffractive optical elements for both soft and hard x-ray regimes. In particular, we demonstrate here a novel method for the production of ultra-high resolution FZPs. This technique is based on the deposition of a zone plate material (iridium) onto the sidewalls of a prepatterned template structure (silicon) by atomic layer deposition. This approach overcomes the limitations due to electron-beam writing of dense patterns in FZP fabrication and provides a clear route to push the resolution into sub-10 nm regime. A FZP fabricated by this method was used to resolve test structures with 12 nm lines and spaces at the scanning transmission x-ray microscope of the PolLux beamline of the Swiss Light Source at 1.2 keV photon energy.

  16. Thin Shell, Segmented X-Ray Mirrors

    Science.gov (United States)

    Petre, Robert

    2010-01-01

    Thin foil mirrors were introduced as a means of achieving high throughput in an X-ray astronomical imaging system in applications for which high angular resolution were not necessary. Since their introduction, their high filling factor, modest mass, relative ease of construction, and modest cost have led to their use in numerous X-ray observatories, including the Broad Band X-ray Telescope, ASCA, and Suzaku. The introduction of key innovations, including epoxy replicated surfaces, multilayer coatings, and glass mirror substrates, has led to performance improvements, and in their becoming widely used for X-ray astronomical imaging at energies above 10 keV. The use of glass substrates has also led to substantial improvement in angular resolution, and thus their incorporation into the NASA concept for the International X-ray Observatory with a planned 3 in diameter aperture. This paper traces the development of foil mirrors from their inception in the 1970's through their current and anticipated future applications.

  17. X-ray spectra for mamography

    International Nuclear Information System (INIS)

    By means of Monte Carlo methods the X-ray spectra that produce Mammography equipment have been obtained. The mammographs are widely used with the purpose of diagnosing the cancer of the mammary glands. Different makers and mammographs models are distinguished by the voltage capacity and the current, exist as well as in the target type and filter. The targets that are used are Mo, Rh and W and the filters are Mo, Rh, Al and Be. In this work the results obtained by means of the MCNP code of the X-ray spectra take place when an electron beam of 28 keV is made impact on Mo, Rh and W targets, as well as the spectra that result of filtering these X rays using different types of filters. The resulting spectra contain the continuous spectrum of the stopping radiation, as well as the X rays characteristic of the used target. The utility of estimating the spectra of X rays by means of Monte Carlo is that it can use to estimate the absorbed dose by the gland, as well as the absorbed dose by other organs. It also allows to calculate the detector response. (Author)

  18. Diorganotin Complexes of a Thiosemicarbazone, Synthesis: Properties, X-Ray Crystal Structure, and Antiproliferative Activity of Diorganotin Complexes

    Directory of Open Access Journals (Sweden)

    Joanna Wiecek

    2010-01-01

    Full Text Available The synthesis and spectral characterization of novel diorganotin complexes with 3-hydroxypyridine-2-carbaldehyde thiosemicarbazone, HL(1, [SnMe2(L] (2, [SnBu2(L] (3, and [SnPh2(L] (4 are reported. The single-crystal X-ray structure of complex [SnPh2(L(DMSO] (5 shows that the ligand is doubly deprotonated and is coordinated as tridentate ligand. The six coordination number is completed by two carbon atoms of phenyl groups. There are two similar monomers 5a (Sn1 and 5b (Sn51 in the asymmetric unit. The monomers 5a and 5b are linked through intermolecular hydrogen bonds of N–H–O and C–H–S type. C-H→, intermolecular interactions, intra- and intermolecular hydrogen bonds stabilize this structure and leads to aggregation and a supramolecular assembly. The IR and NMR (1H, 13C and 119Sn spectroscopic data of the complexes are reported. The in vitro cytotoxic activity has been evaluated against the cells of three human cancer cell lines: MCF-7 (human breast cancer cell line, T-24 (bladder cancer cell line, A-549 (nonsmall cell lung carcinoma and a mouse L-929 (a fibroblast-like cell line cloned from strain L. Compounds 1, 3, and 4 were found active against all four cell lines. Selectivity was observed for complexes 3 and 4 which were found especially active against MCF-7 and T-24 cancer cell lines.

  19. Diorganotin Complexes of a Thiosemicarbazone, Synthesis: Properties, X-Ray Crystal Structure, and Antiproliferative Activity of Diorganotin Complexes

    Science.gov (United States)

    Wiecek, Joanna; Kovala-Demertzi, Dimitra; Ciunik, Zbigniew; Zervou, Maria; Demertzis, Mavroudis A.

    2010-01-01

    The synthesis and spectral characterization of novel diorganotin complexes with 3-hydroxypyridine-2-carbaldehyde thiosemicarbazone, H2L(1), [SnMe2(L)] (2), [SnBu2(L)] (3), and [SnPh2(L)] (4) are reported. The single-crystal X-ray structure of complex [SnPh2(L)(DMSO)] (5) shows that the ligand is doubly deprotonated and is coordinated as tridentate ligand. The six coordination number is completed by two carbon atoms of phenyl groups. There are two similar monomers 5a (Sn1) and 5b (Sn51) in the asymmetric unit. The monomers 5a and 5b are linked through intermolecular hydrogen bonds of N–H–O and C–H–S type. C–H → π, intermolecular interactions, intra- and intermolecular hydrogen bonds stabilize this structure and leads to aggregation and a supramolecular assembly. The IR and NMR (1H, 13C and 119Sn) spectroscopic data of the complexes are reported. The in vitro cytotoxic activity has been evaluated against the cells of three human cancer cell lines: MCF-7 (human breast cancer cell line), T-24 (bladder cancer cell line), A-549 (nonsmall cell lung carcinoma) and a mouse L-929 (a fibroblast-like cell line cloned from strain L). Compounds 1, 3, and 4 were found active against all four cell lines. Selectivity was observed for complexes 3 and 4 which were found especially active against MCF-7 and T-24 cancer cell lines. PMID:20689713

  20. Energy-dispersive X-ray emission spectroscopy using an X-ray free-electron laser in a shot-by-shot mode

    Science.gov (United States)

    Alonso-Mori, Roberto; Kern, Jan; Gildea, Richard J.; Sokaras, Dimosthenis; Weng, Tsu-Chien; Lassalle-Kaiser, Benedikt; Tran, Rosalie; Hattne, Johan; Laksmono, Hartawan; Hellmich, Julia; Glöckner, Carina; Echols, Nathaniel; Sierra, Raymond G.; Schafer, Donald W.; Sellberg, Jonas; Kenney, Christopher; Herbst, Ryan; Pines, Jack; Hart, Philip; Herrmann, Sven; Grosse-Kunstleve, Ralf W.; Latimer, Matthew J.; Fry, Alan R.; Messerschmidt, Marc M.; Miahnahri, Alan; Seibert, M. Marvin; Zwart, Petrus H.; White, William E.; Adams, Paul D.; Bogan, Michael J.; Boutet, Sébastien; Williams, Garth J.; Zouni, Athina; Messinger, Johannes; Glatzel, Pieter; Sauter, Nicholas K.; Yachandra, Vittal K.; Yano, Junko; Bergmann, Uwe

    2012-01-01

    The ultrabright femtosecond X-ray pulses provided by X-ray free-electron lasers open capabilities for studying the structure and dynamics of a wide variety of systems beyond what is possible with synchrotron sources. Recently, this “probe-before-destroy” approach has been demonstrated for atomic structure determination by serial X-ray diffraction of microcrystals. There has been the question whether a similar approach can be extended to probe the local electronic structure by X-ray spectroscopy. To address this, we have carried out femtosecond X-ray emission spectroscopy (XES) at the Linac Coherent Light Source using redox-active Mn complexes. XES probes the charge and spin states as well as the ligand environment, critical for understanding the functional role of redox-active metal sites. Kβ1,3 XES spectra of MnII and Mn2III,IV complexes at room temperature were collected using a wavelength dispersive spectrometer and femtosecond X-ray pulses with an individual dose of up to >100 MGy. The spectra were found in agreement with undamaged spectra collected at low dose using synchrotron radiation. Our results demonstrate that the intact electronic structure of redox active transition metal compounds in different oxidation states can be characterized with this shot-by-shot method. This opens the door for studying the chemical dynamics of metal catalytic sites by following reactions under functional conditions. The technique can be combined with X-ray diffraction to simultaneously obtain the geometric structure of the overall protein and the local chemistry of active metal sites and is expected to prove valuable for understanding the mechanism of important metalloproteins, such as photosystem II. PMID:23129631