WorldWideScience

Sample records for asphaltenic crude oils

  1. Investigating Asphaltenes Composition in Crude Oil Samples using ...

    African Journals Online (AJOL)

    MBI

    2015-12-22

    Dec 22, 2015 ... composition of asphaltenes by Iatroscan TLC-FID method was compared with the weight% of asphaltenes precipitated. ... SARA in the crude oil samples were determined in this work ..... Fractionation and characterization of.

  2. Effect of asphaltenes on crude oil wax crystallization

    DEFF Research Database (Denmark)

    Kriz, Pavel; Andersen, Simon Ivar

    2005-01-01

    The paper summarizes the experimental work done on asphaltene influenced wax crystallization. Three different asphaltenes (from stable oil, instable oil, and deposit) were mixed at several concentrations or dispersions into the waxy crude oil. These blends were evaluated by viscometry and yield s...

  3. Test methods for determining asphaltene stability in crude oils

    Energy Technology Data Exchange (ETDEWEB)

    Asomaning, S. [Baker Petrolite, Sugar Land, TX (United States)

    2001-07-01

    The development of test methods for the determination of the stability of asphaltenes in crude oils was rendered necessary, due to the high cost of remediating asphaltene deposition in harsh production environments, namely the underwater systems in offshore deepwater. The Oliensis Spot Test, two saturates, aromatics, resins and asphaltenes (SARA)-based screens (the Colloidal Instability Index and Asphaltene-Resin ratio), a solvent titration method with near infrared radiation (NIR) solids detection, and live oil depressurization were used for the purposes of this study, to predict the stability of asphaltenes in crude oils with different API gravity. A complete description of the test methods was provided, and the experimental data obtained as a result was presented. Correlation with data on the deposition histories of the oils was used to validate the experimental stability data. The author discussed the effectiveness of the different tests for the prediction of the stability of asphaltenes in crude oils. The prediction of a crude oil's propensity towards asphaltene precipitation was more accurate with the Colloidal Instability Index and the solvent titration method. Live oil depressurization proved to be very effective for the prediction of the stability of asphaltenes for light oils, where most stability tests fail. tabs., 31 figs.

  4. Structural Study of Asphaltenes from Iranian Heavy Crude Oil

    Directory of Open Access Journals (Sweden)

    Davarpanah L.

    2015-11-01

    Full Text Available In the present study, asphaltene precipitation from Iranian heavy crude oil (Persian Gulf off-shore was performed using n-pentane (n-C5 and n-heptane (n-C7 as light alkane precipitants. Several analytical techniques, each following different principles, were then used to structurally characterize the precipitated asphaltenes. The yield of asphaltene obtained using n-pentane precipitant was higher than asphaltene precipitated with the use of n-heptane. The asphaltene removal affected the n-C5 and n-C7 maltene fractions at temperatures below 204°C, as shown by the data obtained through the simulated distillation technique. Viscosity of heavy oil is influenced by the asphaltene content and behavior. The viscosity dependence of the test heavy oil on the shear rate applied was determined and the flow was low at y. above 25 s-1 . The reconstituted heavy oil samples were prepared by adding different amounts of asphaltenes to the maltenes (deasphalted heavy oil and asphaltene effects were more pronounced at the low temperature of 25°C as compared with those at the higher temperatures. According to the power law model used in this study the flowability of the test heavy oil exhibited a pseudoplastic character. Structural results obtained from Fourier Transform InfraRed (FTIR spectroscopy showed the presence of the different functional groups in the precipitated asphaltenes. For instance, the presence of different hydrocarbons (aliphatic, aromatic and alicyclic based on their characteristics in the FTIR spectra was confirmed. Resins are effective dispersants, and removal of this fraction from the crude oil is disturbing to the colloidal nature of heavy oil; asphaltene flocculation and precipitation eventually occur. Appearance of pores in the Scanning Electron Microscopy (SEM images was used as an indicator of the resin detachment. With the use of 1H and 13C Nuclear Magnetic Resonance (NMR spectroscopy, two important structural parameters of the

  5. Comparisons Between Asphaltenes from the Dead and Live-Oil Samples of the Same Crude Oils

    DEFF Research Database (Denmark)

    Aquino-Olivos, M.A.; Andersen, Simon Ivar; Lira-Galeana, C.

    2003-01-01

    extracted and analyzed. These pressure-driven asphaltenes found on the filter were found to make up in the range between 50 and 100 ppm of the whole crude oil. Opening of the cell did not reveal asphaltenes retained due to wall adhesion. Size exclusion chromatography tests performed on both the live......-oil-derived asphaltenes and the standard asphaltenes as precipitated by atmospheric titration on the same crude oil, revealed that the live-oil asphaltenes had apparent smaller hydrodynamic volume and narrower distributions than the standard asphaltenes for two oils. Further FTIR tests also showed large differences...

  6. Extraction and characterization of crude oil asphaltenes sub fractions

    International Nuclear Information System (INIS)

    Ferreira, Silas R.; Calado, Lucas S.; Honse, Siller O.; Mansur, Claudia R.E.; Lucas, Elizabete F.

    2011-01-01

    Asphaltenes from crude oil have been studied for a long time. However, until today their chemical structures and physical-chemical properties are not well established. Nowadays, it is accepted that asphaltenes are dispersed in the crude oil as macro structures, which are mainly constituted of some condensed aromatic rings (about 6-20), containing aliphatic or naphthenic groups. The asphaltenes are also defined as the crude oil fraction that is insoluble in low molar mass n-alkanes and soluble in aromatic solvents, like benzene and toluene In order to investigate the molecular structure, in this work the asphaltenes were separated by using a different procedure as that normally described in the literature and characterized by infrared spectrometry, nuclear magnetic resonance, x-ray fluorescence, elemental analyses and particle size and size distribution. The difference in subfractions polarity can be attributed not only to the aromaticity changes but also to the content of elements, such as N, O, Fe, V, Si e Ni. (author)

  7. Aluminum Oxide Nanoparticles for Highly Efficient Asphaltene Separation from Crude Oil Using Ceramic Membrane Technology

    Directory of Open Access Journals (Sweden)

    Rezakazemi Mashallah

    2017-11-01

    Full Text Available The effects of aluminum oxide nanoparticles on the removal of asphaltenes from an Iranian crude oil (Soroush using a ceramic membrane with pore size of 0.2 µm were investigated. In order to achieve superior asphaltene separation by ultrafiltration, it is essential to make some changes for destabilizing asphaltene in crude oil. The asphaltene destabilization was done using crude oil contact with an acid containing dissolved metal ions. Metal oxide nanoparticles adsorbed asphaltene molecules and increased their molecular size. The nanoparticle of aluminum oxide was applied to alter precipitation and peptization properties of asphaltenes. Dynamic Light Scattering (DLS was used to measurement of the asphaltene molecular size dissolved in toluene. Raman spectroscopy and the Tuinstra equation were used to determine the aromatic sheet diameter (La via the integrated intensities of the G and D1 modes. This revealed that the asphaltene particles react with nano aluminum oxide and the average molecular size of asphaltene was raised from 512.754 to 2949.557 nm and La from 5.482 to 13.787. The obtained results showed that using nano aluminum oxides, asphaltene separation increased from 60–85 wt% to 90–97 wt% based on the asphaltene content of crude oil.

  8. Influence of asphaltene aggregation and pressure on crude oil emulsion stability

    Energy Technology Data Exchange (ETDEWEB)

    Auflem, Inge Harald

    2002-07-01

    Water-in-crude oil emulsions stabilised by various surface-active components are one of the major problems in relation to petroleum production. This thesis presents results from high-pressure separation experiments on ''live'' crude oil and model oil emulsions, as well as studies of Interactions between various indigenous stabilising materials in crude oil. A high-pressure separation rig was used to study the influence of gas and gas bubbles on the separation of water-in-crude oil emulsions. The results were interpreted as a flotation effect from rising gas bubbles, which led to increased separation efficiency. The separation properties of a ''live'' crude oil were compared to crude oil samples recombined with various gases. The results showed that water-in-oil emulsions produced from the ''live'' crude oil samples, generally separated faster and more complete, than emulsions based on recombined samples of the same crude oil. Adsorption of asphaltenes and resins onto a hydrophilic surface from solutions with varying aromatic/aliphatic character was investigated by a quarts crystal microbalance. The results showed that asphaltenes adsorbed to a larger degree than the resins. The resins were unable to desorb pre-adsorbed asphaltenes from the surface, and neither did they adsorb onto the asphaltene-coated surface. In solutions of both of resins and asphaltenes the two constituents associated in bulk liquid and adsorbed to the surface in the form of mixed aggregates. Near infrared spectroscopy and pulsed field gradient spin echo nuclear magnetic resonance were used to study asphaltene aggregation and the influence of various amphiphiles on the asphaltene aggregate size. The results showed Interactions between the asphaltenes and various chemicals, which were proposed to be due to acid-base interactions. Among the chemicals used were various naphthenic acids. Synthesised monodisperse acids gave a reduction of size of the asphaltene aggregates, whereas polydisperse

  9. Influence of asphaltene aggregation and pressure on crude oil emulsion stability

    Energy Technology Data Exchange (ETDEWEB)

    Auflem, Inge Harald

    2002-07-01

    Water-in-crude oil emulsions stabilised by various surface-active components are one of the major problems in relation to petroleum production. This thesis presents results from high-pressure separation experiments on ''live'' crude oil and model oil emulsions, as well as studies of Interactions between various indigenous stabilising materials in crude oil. A high-pressure separation rig was used to study the influence of gas and gas bubbles on the separation of water-in-crude oil emulsions. The results were interpreted as a flotation effect from rising gas bubbles, which led to increased separation efficiency. The separation properties of a ''live'' crude oil were compared to crude oil samples recombined with various gases. The results showed that water-in-oil emulsions produced from the ''live'' crude oil samples, generally separated faster and more complete, than emulsions based on recombined samples of the same crude oil. Adsorption of asphaltenes and resins onto a hydrophilic surface from solutions with varying aromatic/aliphatic character was investigated by a quarts crystal microbalance. The results showed that asphaltenes adsorbed to a larger degree than the resins. The resins were unable to desorb pre-adsorbed asphaltenes from the surface, and neither did they adsorb onto the asphaltene-coated surface. In solutions of both of resins and asphaltenes the two constituents associated in bulk liquid and adsorbed to the surface in the form of mixed aggregates. Near infrared spectroscopy and pulsed field gradient spin echo nuclear magnetic resonance were used to study asphaltene aggregation and the influence of various amphiphiles on the asphaltene aggregate size. The results showed Interactions between the asphaltenes and various chemicals, which were proposed to be due to acid-base interactions. Among the chemicals used were various naphthenic acids. Synthesised monodisperse acids gave a reduction of

  10. Diagnosis of asphaltene stability in crude oil through “two parameters” SVM model

    DEFF Research Database (Denmark)

    Chamkalani, Ali; Mohammadi, Amir H.; Eslamimanesh, Ali

    2012-01-01

    Asphaltene precipitation/deposition and its imposing difficulties are drastic issues in petroleum industry. Monitoring the asphaltene stability conditions in crude oil systems is still a challenge and has been subject of many studies. In this work, the Refractive Index (RI) of several oil samples...... and previously-presented empirical correlations available in open literature. © 2012 Elsevier Ltd....

  11. Modeling of Asphaltene Precipitation from Crude Oil with the Cubic Plus Association Equation of State

    DEFF Research Database (Denmark)

    Arya, Alay; Liang, Xiaodong; von Solms, Nicolas

    2017-01-01

    In this study, different modeling approaches using the Cubic Plus Association (CPA) equation of state (EoS) are developed to calculate the asphaltene precipitation onset condition and asphaltene yield from degassed crude oil during the addition of n-paraffin. A single model parameter is fitted...

  12. Molecular Dynamics Simulation: The Behavior of Asphaltene in Crude Oil and at the Oil/Water Interface

    KAUST Repository

    Gao, Fengfeng

    2014-12-18

    Carboxyl asphaltene is commonly discussed in the petroleum industry. In most conditions, electroneutral carboxyl asphaltene molecules can be deprotonated to become carboxylate asphaltenes. Both in crude oil and at the oil/water interface, the characteristics of anionic carboxylate asphaltenes are different than those of the carboxyl asphaltenes. In this paper, molecular dynamics (MD) simulations are utilized to study the structural features of different asphaltene molecules, namely, C5 Pe and anionic C5 Pe, at the molecular level. In crude oil, the electroneutral C5 Pe molecules prefer to form a steady face-to-face stacking, while the anionic C5 Pe molecules are inclined to form face-to-face stacking and T-shaped II stacking because of the repulsion of the anionic headgroups. Anionic C5 Pe has a distinct affinity to the oil/water interface during the simulation, while the C5 Pe molecules persist in the crude oil domain. A three-stage model of anionic C5 Pe molecules adsorbed at the oil/water interface is finally developed.

  13. Characterisation of crude oil components, asphaltene aggregation and emulsion stability by means of near infrared spectroscopy and multivariate analysis

    Energy Technology Data Exchange (ETDEWEB)

    Aske, Narve

    2002-06-01

    Effective separation of water-in-crude oil emulsions is a central challenge for the oil industry on the Norwegian Continental Shelf, especially with the future increase in subsea and even down-hole processing of well fluids. The mechanisms and properties governing emulsion stability are far from fully understood but the indigenous surface active crude oil components are believed to play a major role. In this work a thorough physico-chemical characterisation of a set of crude oils originating from a variety of production fields has been performed. Crude oil properties responsible for emulsion stability were identified by use of multivariate analysis techniques like partial least squares regression (PLS) and principal component analysis (PCA). Interfacial elasticity along with both asphaltene content and asphaltene aggregation state were found to be main contributors to emulsion stability. Information on a crude oils ability to form elastic crude oil-water interfaces was found to be especially crucial when discussing emulsion stability. However, measured values of interfacial elasticity were highly dependent on asphaltene aggregation state. Several experimental techniques was utilised and partly developed for the crude oil characterisation. A high-pressure liquid chromatography (HPLC) scheme was developed for SARA-fractionation of crude oils and an oscillating pendant drop tensiometer was used for characterisation of interfacial rheological properties. For emulsion stability a cell for determining the stability as a function of applied electric fields was used. In addition, near infrared spectroscopy (NIR) was used throughout the work both for chemical and physical characterisation of crude oils and model systems. High pressure NIR was used to study the aggregation of asphaltenes by pressure depletion. A new technique for detection of asphaltene aggregation onset pressures based on NIR combined with PCA was developed. It was also found that asphaltene aggregation is

  14. Developing grey-box model to diagnose asphaltene stability in crude oils: Application of refractive index

    Directory of Open Access Journals (Sweden)

    Mahdi Zeinali Hasanvand

    2016-12-01

    Full Text Available Asphaltene precipitation can cause serious problems in petroleum industry while diagnosing the asphaltene stability conditions in crude oil system is still a challenge and has been subject of many investigations. To monitor and diagnose asphaltene stability, high performance intelligent approaches based bio-inspired science like artificial neural network which have been optimized by various optimization techniques have been carried out. The main purpose of the implemented optimization algorithms is to decide high accurate interconnected weights of proposed neural network model. The proposed intelligent approaches are examined by using extensive experimental data reported in open literature. Moreover, to highlight robustness and precision of the addressed approaches, two different regression models have been developed and results obtained from the aforementioned intelligent models and regression approaches are compared with the corresponding refractive index data measured in laboratory. Based on the results, hybrid of genetic algorithm and particle swarm optimization have high performance and average relative absolute deviation between the model outputs and the relevant experimental data was found to be less than 0.2%. Routs from this work indicate that implication of HGAPSO-ANN in monitoring refractive index can lead to more reliable estimation of addressed issue which can lead to design of more reliable phase behavior simulation and further plans of oil production.

  15. Syngas obtainment from the gasification of asphaltenes of the San Fernando crude oil

    International Nuclear Information System (INIS)

    Moreno A, Laura; Rodriguez C, Fabio; Afanador R, Luz E; Grosso V, Jorge

    2010-01-01

    In this work, we developed the first study in Colombia to obtain and evaluate syngas compositions derived from asphaltenes gasification. These asphaltenes came from the implementation of a Deasphalting process to San Fernando crude oil, with the purpose of looking for technological options for their utilization. We performed the design, installation and commissioning of facilities for the gasification of asphaltenes at laboratory scale, it following an experimental methodology, performing nine tests and considering temperature and agent gasification quantity (oxygen) as independent variables. The syngas derived from gasification was analyzed by two chromatographic techniques, which reported the presence of refinery gases and sulfur. We evidenced a growth tendency of CO, H 2 and sulfur composition and a decrease in CH 4 and CO 2 composition with temperature. The composition of the syngas was evaluated with different quantities of gasification agent (33%, 40% and 47% the amount of oxygen theoretically required for complete combustion) at each temperature levels operated. It was established that when using a 40% of gasification agent, you get greater average content of CO and H 2 , which are the interest gases in the gasification process.

  16. Syngas obtainment from the gasification of asphaltenes of the San Fernando crude oil

    International Nuclear Information System (INIS)

    Moreno Arciniegas, Laura Smith; Rodriguez Corredor, Fabio Ernesto; Afanador Rey, Luz Edelmira; Grosso Vargas, Jorge Luis

    2009-01-01

    In this work, we developed the first study in Colombia to obtain and evaluate syngas compositions derived from asphaltenes gasification. These asphaltenes came from the implementation of a Deasphalting process to San Fernando crude oil, with the purpose of looking for technological options for their utilization. We performed the design, installation and commissioning of facilities for the gasification of asphaltenes at laboratory scale, it following an experimental methodology, performing nine tests and considering temperature and agent gasification quantity (oxygen) as independent variables. The syngas derived from gasification was analyzed by two chromatographic techniques, which reported the presence of refinery gases and sulfur. We evidenced a growth tendency of CO, H 2 and sulfur composition and a decrease in CH 4 and CO 2 composition with temperature. The composition of the syngas was evaluated with different quantities of gasification agent (33%, 40% and 47% the amount of oxygen theoretically required for complete combustion) at each temperature levels operated. It was established that when using a 40% of gasification agent, you get greater average content of CO and H 2 , which are the interest gases in the gasification process.

  17. Time-resolved small angle neutron scattering measurements of asphaltene nanoparticle aggregation kinetics in incompatible crude oil mixtures

    International Nuclear Information System (INIS)

    Mason, Thomas G.; Lin, Min Y.

    2003-01-01

    We use time-resolved-small angle neutron scattering to study the kinetics of asphaltene nanoparticle aggregation in incompatible crude oil mixtures. We induce asphaltene aggregation by mixing asphaltene-rich Syrian crude oil (SACO) with a paraffinic British crude oil and observe the scattered neutron intensity, I, as a function of wave number, q, over times, t, ranging from twenty minutes to about a week. We observe a growth in I at low q as the nanoscale asphaltenes agglomerate into microscale aggregates and interpret this growth as an increase in surface scattering from the aggregates. We fit I(q,t) to an empirical model and measure the growth in the power-law exponent, α, associated with the low-q logarithmic slope of I(q). We define a time, τ α , associated with the first appearance of the aggregates when α>3; τ α increases as a function of the volume fraction, φ m , of SACO in the mixture. The surface scattering intensity initially increases and then saturates at long times when the aggregate structures no longer evolve at the length scales we probe. Based on this saturation, we define a time scale, τ I , which is larger than τ α but has essentially the same dependence on φ m . We interpret τ α (φ m ) and τ I (φ m ) in terms of a simple aggregation model based on diffusion-limited kinetics and a repulsive potential barrier that models the effective solvent quality

  18. Extraction and characterization of crude oil asphaltenes sub fractions; Extracao e caracterizacao de subfracoes de asfaltenos de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Silas R.; Calado, Lucas S.; Honse, Siller O.; Mansur, Claudia R.E.; Lucas, Elizabete F., E-mail: silas@ima.ufrj.br [Universidade Federal do Rio de Janeiro, Instituto de Macromoleculas, Laboratorio de Macromoleculas e Coloides na Industria de Petroleo, Rio de Janeiro, RJ (Brazil)

    2011-07-01

    Asphaltenes from crude oil have been studied for a long time. However, until today their chemical structures and physical-chemical properties are not well established. Nowadays, it is accepted that asphaltenes are dispersed in the crude oil as macro structures, which are mainly constituted of some condensed aromatic rings (about 6-20), containing aliphatic or naphthenic groups. The asphaltenes are also defined as the crude oil fraction that is insoluble in low molar mass n-alkanes and soluble in aromatic solvents, like benzene and toluene In order to investigate the molecular structure, in this work the asphaltenes were separated by using a different procedure as that normally described in the literature and characterized by infrared spectrometry, nuclear magnetic resonance, x-ray fluorescence, elemental analyses and particle size and size distribution. The difference in subfractions polarity can be attributed not only to the aromaticity changes but also to the content of elements, such as N, O, Fe, V, Si e Ni. (author)

  19. Rheological properties of hydrate suspensions in asphaltenic crude oils; Proprietes rheologiques de suspensions d'hydrate dans des bruts asphalteniques

    Energy Technology Data Exchange (ETDEWEB)

    Marques de Toledo Camargo, R.

    2001-03-01

    The development of offshore oil exploitation under increasing water depths has forced oil companies to increase their understanding of gas hydrate formation and transportation in multiphase flow lines in which a liquid hydrocarbon phase is present. This work deals with the flow behaviour of hydrate suspensions in which a liquid hydrocarbon is the continuous phase. Three different liquid hydrocarbons are used: an asphaltenic crude oil, a condensate completely free of asphaltenes and a mixture between the asphaltenic oil and heptane. The rheological characterisation of hydrate suspensions is the main tool employed. Two original experimental devices are used: a PVT cell adapted to operate as a Couette type rheometer and a semi-industrial flow loop. Hydrate suspensions using the asphaltenic oil showed shear-thinning behaviour and thixotropy. This behaviour is typically found in flocculated systems, in which the particles attract each other forming flocs of aggregated particles at low shear rates. The suspensions using the condensate showed Newtonian behaviour. Their relative viscosities were high, which suggests that an aggregation process between hydrate particles takes. place during hydrate formation. Finally, hydrate suspensions using the mixture asphaltenic oil-heptane showed shear-thinning behaviour, thixotropy and high relative viscosity. From these results it can be inferred that, after the achievement of the hydrate formation process, the attractive forces between hydrate particles are weak. making unlikely pipeline obstruction by an aggregation process. Nevertheless, during the hydrate formation, these attractive forces can be sufficiently high. It seems that the hydrate surface wettability is an important parameter in this phenomena. (author)

  20. Molecular Dynamics Simulation: The Behavior of Asphaltene in Crude Oil and at the Oil/Water Interface

    KAUST Repository

    Gao, Fengfeng; Xu, Zhen; Liu, Guokui; Yuan, Shiling

    2014-01-01

    of the repulsion of the anionic headgroups. Anionic C5 Pe has a distinct affinity to the oil/water interface during the simulation, while the C5 Pe molecules persist in the crude oil domain. A three-stage model of anionic C5 Pe molecules adsorbed at the oil

  1. Phase Behavior Modeling of Asphaltene Precipitation for Heavy Crudes: A Promising Tool Along with Experimental Data

    Science.gov (United States)

    Tavakkoli, M.; Kharrat, R.; Masihi, M.; Ghazanfari, M. H.; Fadaei, S.

    2012-12-01

    Thermodynamic modeling is known as a promising tool for phase behavior modeling of asphaltene precipitation under different conditions such as pressure depletion and CO2 injection. In this work, a thermodynamic approach is used for modeling the phase behavior of asphaltene precipitation. The precipitated asphaltene phase is represented by an improved solid model, while the oil and gas phases are modeled with an equation of state. The PR-EOS was used to perform flash calculations. Then, the onset point and the amount of precipitated asphaltene were predicted. A computer code based on an improved solid model has been developed and used for predicting asphaltene precipitation data for one of Iranian heavy crudes, under pressure depletion and CO2 injection conditions. A significant improvement has been observed in predicting the asphaltene precipitation data under gas injection conditions. Especially for the maximum value of asphaltene precipitation and for the trend of the curve after the peak point, good agreement was observed. For gas injection conditions, comparison of the thermodynamic micellization model and the improved solid model showed that the thermodynamic micellization model cannot predict the maximum of precipitation as well as the improved solid model. The non-isothermal improved solid model has been used for predicting asphaltene precipitation data under pressure depletion conditions. The pressure depletion tests were done at different levels of temperature and pressure, and the parameters of a non-isothermal model were tuned using three onset pressures at three different temperatures for the considered crude. The results showed that the model is highly sensitive to the amount of solid molar volume along with the interaction coefficient parameter between the asphaltene component and light hydrocarbon components. Using a non-isothermal improved solid model, the asphaltene phase envelope was developed. It has been revealed that at high temperatures, an

  2. The Asphaltenes

    Science.gov (United States)

    Mullins, Oliver C.

    2011-07-01

    Asphaltenes, the most aromatic of the heaviest components of crude oil, are critical to all aspects of petroleum utilization, including reservoir characterization, production, transportation, refining, upgrading, paving, and coating materials. The asphaltenes, which are solid, have or impart crucial and often deleterious attributes in fluids such as high viscosity, emulsion stability, low distillate yields, and inopportune phase separation. Nevertheless, fundamental uncertainties had precluded a first-principles approach to asphaltenes until now. Recently, asphaltene science has undergone a renaissance; many basic molecular and nanocolloidal properties have been resolved and codified in the modified Yen model (also known as the Yen-Mullins model), thereby enabling predictive asphaltene science. Advances in analytical chemistry, especially mass spectrometry, enable the identification of tens of thousands of distinct chemical species in crude oils and asphaltenes. These and other powerful advances in asphaltene science fall under the banner of petroleomics, which incorporates predictive petroleum science and provides a framework for future developments.

  3. The use of stability indices in predicting asphaltene problems in upstream and downstream oil operations

    Energy Technology Data Exchange (ETDEWEB)

    Asomaning, S. [Baker Petrolite, Sugar Land, TX (United States)

    2003-07-01

    A series of test methods have been developed to determine the stability of asphaltenes in crude oils. They were developed due to the high cost of remediating asphaltene deposition in offshore operations. This study described the characteristics of the Oliensis Spot Test, two saturates, aromatics, resins and asphaltenes (SARA)-based screens (the Colloidal Instability Index and Asphaltene-Resin ratio), a solvent titration method with near infrared radiation (NIR) solids detection, and live oil depressurization. Each method is used to predict the stability of asphaltenes in crude oils with different API gravity. A complete description of the test methods was provided along with experimental data. The effectiveness of the different tests in predicting the stability of asphaltenes in crude oils was also assessed. Results indicate that the prediction of a crude oil's tendency towards asphaltene precipitation was more accurate with the Colloidal Instability Index and the solvent titration method. Live oil depressurization proved to be very effective in predicting the stability of asphaltenes for light oils, where most stability tests fail. tabs., figs.

  4. Enhanced Oil Recovery (EOR by Miscible CO2 and Water Flooding of Asphaltenic and Non-Asphaltenic Oils

    Directory of Open Access Journals (Sweden)

    Edwin A. Chukwudeme

    2009-09-01

    Full Text Available An EOR study has been performed applying miscible CO2 flooding and compared with that for water flooding. Three different oils are used, reference oil (n-decane, model oil (n-C10, SA, toluene and 0.35 wt % asphaltene and crude oil (10 wt % asphaltene obtained from the Middle East. Stearic acid (SA is added representing a natural surfactant in oil. For the non-asphaltenic oil, miscible CO2 flooding is shown to be more favourable than that by water. However, it is interesting to see that for first years after the start of the injection (< 3 years it is shown that there is almost no difference between the recovered oils by water and CO2, after which (> 3 years oil recovery by gas injection showed a significant increase. This may be due to the enhanced performance at the increased reservoir pressure during the first period. Maximum oil recovery is shown by miscible CO2 flooding of asphaltenic oil at combined temperatures and pressures of 50 °C/90 bar and 70 °C/120 bar (no significant difference between the two cases, about 1% compared to 80 °C/140 bar. This may support the positive influence of the high combined temperatures and pressures for the miscible CO2 flooding; however beyond a certain limit the oil recovery declined due to increased asphaltene deposition. Another interesting finding in this work is that for single phase oil, an almost linear relationship is observed between the pressure drop and the asphaltene deposition regardless of the flowing fluid pressure.

  5. Enhanced oil recovery (EOR) by miscible CO{sub 2} and water flooding of asphaltenic and non-asphaltenic oils

    Energy Technology Data Exchange (ETDEWEB)

    Chukwudeme, E. A.; Hamouda, A. A. [Department of Petroleum Engineering, University of Stavanger, 4036 Stavanger (Norway)

    2009-07-01

    An EOR study has been performed applying miscible CO{sub 2} flooding and compared with that for water flooding. Three different oils are used, reference oil (n-decane), model oil (n-C10, SA, toluene and 0.35 wt % asphaltene) and crude oil (10 wt % asphaltene) obtained from the Middle East. Stearic acid (SA) is added representing a natural surfactant in oil. For the non-asphaltenic oil, miscible CO{sub 2} flooding is shown to be more favourable than that by water. However, it is interesting to see that for first years after the start of the injection (< 3 years) it is shown that there is almost no difference between the recovered oils by water and CO{sub 2}, after which (> 3 years) oil recovery by gas injection showed a significant increase. This may be due to the enhanced performance at the increased reservoir pressure during the first period. Maximum oil recovery is shown by miscible CO{sub 2} flooding of asphaltenic oil at combined temperatures and pressures of 50 {sup o}C/90 bar and 70 {sup o}C/120 bar (no significant difference between the two cases, about 1%) compared to 80 {sup o}C/140 bar. This may support the positive influence of the high combined temperatures and pressures for the miscible CO{sub 2} flooding; however beyond a certain limit the oil recovery declined due to increased asphaltene deposition. Another interesting finding in this work is that for single phase oil, an almost linear relationship is observed between the pressure drop and the asphaltene deposition regardless of the flowing fluid pressure. (author)

  6. Separation and characterization of resins and asphaltenes coming from Castilla crude Evaluation of their molecular interaction

    International Nuclear Information System (INIS)

    Navarro, Lina; Alvarez, Mario; Grosso, Jorge Luis; Navarro, Uriel

    2004-01-01

    The study of resins and asphaltenes, the heaviest fractions of oil, has become an area of interest due to the abundance of heavy crude oils in Colombia and Latin America. We studied the chemical composition of the heavy fractions of Castilla crude oil, evaluated some of its molecular parameters and found evidence of the interaction between the resins extracted from the crude with the asphaltenes of the original crude. With this objective, we carried out at the pilot plant level precipitation of the resin-asphaltene (R-A) aggregate by adding and mixing under controlled conditions, a paraffin solvent, from the Apiay refinery, called Apiasol. By extracting Soxhlet with the same solvent, resin 1 of aggregate R-A was separated. Resin ll defined as the soluble fraction that is part of the maltenes, was separated from the deasphalted crude by open column chromatography, using alumina as support, according to the SAR method (Saturated, Aromatics, Resins). The fractions of resins and the asphaltenes obtained, were characterized by: Nuclear Magnetic Resonance (NMR), FT-lR, DRX, elementary analysis (C, H, N, S), metal content (Ni and V), distribution of molecular weight by GPC, and average molecular weight by VPO. The results obtained show evidence that resin l which is part of the aggregate has less average molecular weight than resin ll which is present in the fraction of maltenes. In addition, some changes were found in the elementary analysis of among the resins. On the one hand, and taking into account the existing theories of molecular interactions among these fractions, it was found that the resins l separated from the R-A aggregate, when added to the crude, they stabilize their asphaltenes. This evaluation was carried out by analyzing the flocculation point of the crude and its mixtures with 1,9% and 3,8% of resin l, when they are titrated with a precipitating agent in an NIR cell that works with high pressure and temperature

  7. Comparing ignitability for in situ burning of oil spills for an asphaltenic, a waxy and a light crude oil as a function of weathering conditions under arctic conditions

    DEFF Research Database (Denmark)

    Fritt-Rasmussen, Janne; Brandvik, Per Johan; Villumsen, Arne

    2012-01-01

    (asphalthenic), Kobbe (light oil) and Norne (waxy), for ignitability as a function of ice conditions and weathering degree. The crude oils (9 L) were weathered in a laboratory basin (4.8 m3) under simulated arctic conditions (0, 50 and 90% ice cover). The laboratory burning tests show that the ignitability...... is dependent on oil composition, ice conditions and weathering degree. In open water, oil spills rapidly become “not ignitable” due to the weathering e.g. high water content and low content of residual volatile components. The slower weathering of oil spills in ice (50 and 90% ice cover) results in longer time......-windows for the oil to be ignitable. The composition of the oils is important for the window of opportunity. The asphalthenic Grane crude oil had a limited timewindow for in situ burning (9 h or less), while the light Kobbe crude oil and the waxy Norne crude oil had the longest time-windows for in situ burning (from...

  8. A MODEL FOR DIFFUSION CONTROLLED BIOAVAILABILITY OF CRUDE OIL COMPONENTS

    Science.gov (United States)

    Crude oil is a complex mixture of several different structural classes of compounds including alkanes, aromatics, heterocyclic polar compounds, and asphaltenes. The rate and extent of microbial degradation of crude oil depends on the interaction between the physical and biochemi...

  9. Compositional thermodynamic model of asphaltenes flocculation out of crudes; Modelisation thermodynamique compositionnelle de la floculation des bruts asphalteniques

    Energy Technology Data Exchange (ETDEWEB)

    Szewczyk, V

    1997-12-02

    The aim of this work is to propose to the oil industry a compositional thermodynamic model able to predict the operating conditions which induce asphaltenes flocculation out of crudes. In this study, various analytical methods (calorimetry, elemental analysis, {sup 13}C nuclear magnetic resonance, neutron diffusion,...) have been used in order to get a better description of the asphaltene fraction to infer its flocculation mechanism. The proposed model describes this flocculation as a thermodynamic transition inducing the formation of a new liquid phase with a high asphaltene content and formed by all the components initially in the crude: the asphaltene deposit. Asphaltenes are represented as a pseudo-component essentially made of carbon and hydrogen. The analytical modelling of the F11-F20 light fraction is the one proposed by Jaubert (1993). The F20+ heavy fraction is represented by four pseudo-components, their physical properties are calculated using the group contribution methods of Avaullee (1995) and of Rogalski and Neau (1990). The Peng-Robinson equation of state (1976) combined with the Abdoul and Peneloux group contribution mixing rules (1989) is used in order to restitute the gas-liquid-asphaltene deposit phase equilibria. This model not being able to compute flocculation conditions on a predictive manner, the method consists in fitting some physical properties of the pseudo-components introduced in the analytical representation of the asphaltene crudes. he obtained results show results show that the proposed flocculation model is then well adapted to the description of the thermodynamic properties (saturation pressures, relative volumes, flocculation curves) of asphaltene crudes within a relatively large range of temperature (30-150 deg C) and pressure (0.1-50 MPa), covering the majority of conditions met in oil production. (author) 109 refs.

  10. Isolation of Asphaltene-Degrading Bacteria from Sludge Oil

    Directory of Open Access Journals (Sweden)

    Pingkan Aditiawati

    2015-03-01

    Full Text Available Sludge oil contains 30%–50% hydrocarbon fractions that comprise saturated fractions, aromatics, resins, and asphaltene. Asphaltene fraction is the most persistent fraction. In this research, the indigenous bacteria that can degrade asphaltene fractions from a sludge oil sample from Balikpapan that was isolated using BHMS medium (Bushnell-Hass Mineral Salt with 0.01% (w/v yeast extract, 2% (w/v asphaltene extract, and 2% (w/v sludge oil. The ability of the four isolates to degrade asphaltene fractions was conducted by the biodegradation asphaltene fractions test using liquid cultures in a BHMS medium with 0.01% (w/v yeast extract and 2% (w/v asphaltene extract as a carbon source. The parameters measured during the process of biodegradation of asphaltene fractions include the quantification of Total Petroleum Hydrocarbon (g, log total number of bacteria (CFU/ml, and pH. There are four bacteria (isolates 1, 2, 3, and 4 that have been characterized to degrade asphaltic fraction and have been identified as Bacillus sp. Lysinibacillus fusiformes, Acinetobacter sp., and Mycobacterium sp., respectively. The results showed that the highest ability to degrade asphaltene fractions is that of Bacillus sp. (isolate 1 and Lysinibacillus fusiformes (Isolate 2, with biodegradation percentages of asphaltene fractions being 50% and 55%, respectively, and growth rate at the exponential phase is 7.17x107 CFU/mL.days and 4.21x107 CFU/mL.days, respectively.

  11. The relationship between SARA fractions and crude oil stability

    Directory of Open Access Journals (Sweden)

    Siavash Ashoori

    2017-03-01

    Full Text Available Asphaltene precipitation and deposition are drastic issues in the petroleum industry. Monitoring the asphaltene stability in crude oil is still a serious problem and has been subject of many studies. To investigate crude oil stability by saturate, aromatic, resin and asphaltene (SARA analysis seven types of crudes with different components were used. The applied methods for SARA quantification are IP-143 and ASTM D893-69 and the colloidal instability index (CII is computed from the SARA values as well. In comparison between CII results, the values of oil compositions demonstrated that the stability of asphaltenes in crude oils is a phenomenon that is related to all these components and it cannot be associated only with one of them, individually.

  12. Study of the colloidal structure of crude oils - Characterisation of asphaltene suspensions. Relationships between microscopic description and macroscopic properties under different conditions

    International Nuclear Information System (INIS)

    Guille, Veronique; Espinat, Didier; Ravey, Jean-Claude

    1994-04-01

    The authors report the use of techniques of X-ray and neutron scattering, and of rheological measurements to characterise the macrostructure of asphaltenes in solution. They confirm the relevance of a lamellar model for asphaltene particles. They also show that the addition of resin particles results in a decrease of asphaltene size, and hides solvent effects. They also performed a characterisation of the residue of a vacuum distillation. Rheological measurements showed that this residue behaves like a Newtonian liquid above 100 C. Scattering spectra reveal a structure modification between 20 and 90 C. No significant change of the scattering spectrum is then noticed, even up to 300 C. It appears that the scattering technique does not allow an observation of structure modifications to be performed on a large size range [fr

  13. Experimental investigation on the effect of ultrasonic waves on reducing asphaltene deposition and improving oil recovery under temperature control.

    Science.gov (United States)

    Rezaei Dehshibi, Reza; Mohebbi, Ali; Riazi, Masoud; Niakousari, Mehrdad

    2018-07-01

    A well-known complication in the oil reservoir during oil production is asphaltene deposition in and around the production wellbore. Deposition of asphaltene around the production wellbore may cause a significant pressure drop and in turn loss of efficiency in the production process. Various mechanical and chemical methods have been employed in order to reduce asphaltene formation or to eliminate the precipitate. A novel technique which presented a great potential for prevention or elimination of asphaltene is spreading out the high energy ultrasound wave within the oil reservoir. In this study, in a glass micro-model, asphaltene precipitation was first simulated in a transparent porous medium and its removal by application of high energy ultrasound wave was then investigated. To simulate asphaltene precipitation, the micro-model was first saturated with oil and then a normal-pentane was injected. This was followed by flooding the porous media with brine while propagating ultrasound waves (30 kHz and 100 W) to eliminate asphaltene precipitation. The experiment setup was equipped with a temperature controller. The results indicate a significant reduction in asphaltene precipitation in the oil reservoir may be achieved by application of ultrasound energy. Asphaltene particle deposition has been solved reversibly in the oil layer of porous medium and with the oil layering mechanism, the rate of oil production has been increased. In some spots, water/oil emulsion has been formed because of the ultrasonic vibration on the wall. Both the crude and synthetic oils were examined. Copyright © 2018 Elsevier B.V. All rights reserved.

  14. Determination of asphaltenes in heavy oils using an on-column method

    Energy Technology Data Exchange (ETDEWEB)

    Rogel, E.; Ovalles, C.; Moir, M. [Chevron Energy Technology Co., Richmond, CA (United States); Schabron, J.F. [Western Research Inst., Laramie, WY (United States)

    2009-07-01

    An improved analytical method for determining the asphaltene content in crude oil and petroleum samples was presented. The method used an on-column precipitation technique coupled with an evaporative light scattering detector (ELSD). The column has an inert packing material where the asphaltene was precipitated and re-dissolved using a solvent. Heavy crude oils with asphaltene contents ranging from 5 to 25 per cent w/w were tested. A blend of 90:10 dichloromethane and methanol was used to decrease the influence of hydrocarbon adsorption mechanisms from the polymeric liquid chromatographic phases. A series of laboratory experiments were conducted to compare results obtained using the method with results obtained using traditional gravimetric methods. Regression analysis was used to determine the calibration constants. The study showed that the method can be used as replacement for conventional gravimetric methods when faster results are needed or when sample sizes are small. It was concluded that the method was able to accurately quantify asphaltene contents as low as 120 ppm. 8 refs., 1 tab., 3 figs.

  15. Residency of rhenium and osmium in a heavy crude oil

    Science.gov (United States)

    DiMarzio, Jenna M.; Georgiev, Svetoslav V.; Stein, Holly J.; Hannah, Judith L.

    2018-01-01

    Rhenium-osmium (Re-Os) isotope geochemistry is an emerging tool for the study of oil formation and migration processes, and a new technology for petroleum exploration. Little is known, however, about the residency of Re and Os within asphaltene and maltene sub-fractions of crude oil. This information is crucial for understanding the 187Re-187Os radiometric clock held in petroleum systems and for interpreting geochronology for key processes such as oil formation, migration, and biodegradation. In this study, a heavy crude oil was separated into soluble (maltene, MALT) and insoluble (asphaltene, ASPH) fractions using n-heptane as the asphaltene-precipitating agent. The asphaltenes were separated sequentially into sub-fractions using two different solvent pairs (heptane-dichloromethane and acetone-toluene), and the bulk maltenes were separated into saturate, aromatic, and resin (SAR) fractions using open column chromatography. Each asphaltene and maltene sub-fraction was analyzed for Re and Os. The asphaltene sub-fractions and the bulk ASPH, MALT, and crude oil were analyzed for a suite of trace metals by ICP-MS. Our results show that Re and Os concentrations co-vary between the asphaltene sub-fractions, and that both elements are found mostly in the more polar and aromatic sub-fractions. Significant Re and Os are also present in the aromatic and resin fractions of the maltenes. However, each asphaltene and maltene sub-fraction has a distinct isotopic composition, and sub-fractions are not isochronous. This suggests that asphaltene sub-fractionation separates Re-Os complexes to the point where the isotopic integrity of the geochronometer is compromised. The mobility of individual Re and Os isotopes and the decoupling possibilities between radiogenic 187Os produced from 187Re remain elusive, but their recognition in this study is a critical first step. Re and Os correlate strongly with Mo and Cd in the asphaltene sub-fractions, suggesting that these metals occupy

  16. First crude oil from Chukotka

    Energy Technology Data Exchange (ETDEWEB)

    Arenbrister, L.P.; Demidenko, K.A.; Zhmykhova, N.M.

    1986-01-01

    The physicochemical properties of the crude taken from Neogene deposits at a depth of 1486-1443 m are analyzed. The oil is distinguished by low contents of sulfur and resinous-asphaltenic substances, a high content of wax, and a high yield of light cuts distilling below 350 degrees C. The naptha cuts have high contents of naphthenes, and the diesel fuel cuts have high cetane numbers, low sulfur contents, and high contents of straight chain paraffins. The vacuum gasoil has a low density, a low viscosity, a low carbon residue and low contents of sulfur and nitrogen. This gasoil is a good feedstock for catalytic cracking and hydrocracking. The Verkhne-Echin crude is classified as light, low-sulfur, lowresin and high-wax. It can be used to produce jet fuels and summer-grade diesel fuels with low sulfur contents, as well as high-V.I. lube base stocks and liquid and solid paraffins.

  17. Comparison of crude oil interfacial behavior

    Energy Technology Data Exchange (ETDEWEB)

    Beetge, J.H.; Panchev, N. [Champion Technologies Inc., Fresno, TX (United States)

    2008-07-01

    The bulk properties of crude oil are used to predict its behaviour with regards to treatment, transport and processing. Surface active components, such as asphaltenes, are often used to study or explain critical interfacial behaviour of crude oil. This study investigated the differences and similarities in the interfacial behaviour of the collective surface active component in various crude oils from different sources. The properties of interfaces between crude oil and water were compared using a Teclis drop shape tensiometer. A portion of a crude oil sample was diluted in toluene and contacted with water in a rising drop configuration. Dynamic surface tension and interfacial rheology was examined as a function of time from the early stages of interface formation. Sinusoidal oscillation of the drop volume allowed for the evaluation of visco-elastic behaviour of the crude oil/water interface as it developed with time. The Gibbs elastic modulus, as well as its elastic and viscose components were calculated from the drop shape. The interfacial behaviour was expressed in terms of concentration, oscillation frequency and interface age. It was concluded that knowledge of crude oil interfacial character could be of value in the treatment, transport and processing of crude oils because the its behaviour may play a significant role in crude oil production and processing.

  18. Compositional modification of crude oil during oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Yangming; Weng, Huanxin [Department of Earth Sciences, Zhejiang University, Hangzhou 310027 (China); Chen, Zulin; Chen, Qi [Petroleum Geochemistry Research Center, Jianghan Petroleum University, Jingzhou, Hubei (China)

    2003-05-01

    Ten crude oils from two recovery stages spanning 5-10-year interval of five productive wells in the Tarim Basin, northwest China were analyzed for their compositional modification during production process. Significant compositional changes in polar and nonpolar fractions between the previous oil samples and the latter ones were noted at both bulk and molecular level. The latter oil samples appear to contain more aromatic fraction and less asphaltenes and resin, and their gas chromatography (GC) data for whole oil show reduced alkanes with low molecular weight and enhanced high homologue relative to the previous oil samples. Compared with the oils collected from the previous recovery stage, the concentration of basic type of nitrogen-containing compounds and organic acids in oils from the latter recovery stage have a reducing trend, suggesting the occurrence of interaction between crude oil and reservoir rock.

  19. Study of flow properties of asphaltenic oils in a porous medium; Etude des proprietes d`ecoulement des bruts asphalteniques en milieu poreux

    Energy Technology Data Exchange (ETDEWEB)

    Petrova-Bensalem, R.

    1998-06-30

    Deposits of asphaltenes during production can adversely affect the exploitation of certain fields, that of Hassi Messaoud is a known example. The objective of this study is essentially focused on the damage aspects due to formation of this deposits. A methodology has been developed which makes it possible to determine the flow properties of asphaltenic oils in a porous medium under conditions close to those of a reservoir and to detect the formation of organic deposits in situ. Several types of rocks with different morphology were selected along with a number of asphaltenic oils having varied geographic origins. It was shown with these that it was possible to evaluate, in laboratory, the reduction in permeability to the oil resulting from an asphaltene deposit during the circulation of crude oil in the samples. It was observed that the variation in blocking the cores as a function of the volume of injected fluid is similar to the blocking kinetics ascertained for the retention of solid suspended particles in injection water. This similarity in the phenomena led to using particle damage models developed for the latter case. Several experiments involving blocking by asphaltenes could thus be satisfactory simulated, showing that this approach is worth developing despite the differences between the two types of colloidal suspension. The method using injection or `squeeze` of co- solvents was studied with the same systems (rock/crude oil) as a possible remedy for asphaltene deposition. To select suitable solvents and additives. A methodology was established based on application of Hansen`s theory for adjusting the polarity of solvent to the chemical properties of the asphaltene to be eliminated. This was combined with a series of in vitro tests with separated asphaltenes and the minerals of the reservoir rock. The efficiency of the co-solvents thus selected was verified by slug injection in to cores which has been damaged by asphaltenes. This approach may well help the

  20. Asphaltenes in Mexican fuel oils; Asfaltenos en combustoleos mexicanos

    Energy Technology Data Exchange (ETDEWEB)

    Longoria Ramirez, Rigoberto [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1996-12-31

    In this article the main aspects in which the Instituto de Investigaciones Electricas (IIE) has worked to contribute to the solution of problems due to the presence of asphaltenes in national fuel oils, are emphasized. The increment of these compounds, that concentrate harmful elements, in the last ten years has reached 22% by weight of the fuel oil. It is demonstrated that the quantification of asphaltenes depends on the type of solvent employed. [Espanol] En este articulo se subrayan los principales aspectos en los que el Instituto de Investigaciones Electricas (IIE) ha trabajado para contribuir a la solucion de problemas debidos a la presencia de asfaltenos en combustoleos nacionales. El incremento de estos compuestos, que concentran elementos nocivos, en los ultimos diez anos ha llegado hasta un 22% del peso del combustoleo. Se demuestra que la cuantificacion de los asfaltenos depende del tipo de solvente utilizado.

  1. Asphaltenes in Mexican fuel oils; Asfaltenos en combustoleos mexicanos

    Energy Technology Data Exchange (ETDEWEB)

    Longoria Ramirez, Rigoberto [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1997-12-31

    In this article the main aspects in which the Instituto de Investigaciones Electricas (IIE) has worked to contribute to the solution of problems due to the presence of asphaltenes in national fuel oils, are emphasized. The increment of these compounds, that concentrate harmful elements, in the last ten years has reached 22% by weight of the fuel oil. It is demonstrated that the quantification of asphaltenes depends on the type of solvent employed. [Espanol] En este articulo se subrayan los principales aspectos en los que el Instituto de Investigaciones Electricas (IIE) ha trabajado para contribuir a la solucion de problemas debidos a la presencia de asfaltenos en combustoleos nacionales. El incremento de estos compuestos, que concentran elementos nocivos, en los ultimos diez anos ha llegado hasta un 22% del peso del combustoleo. Se demuestra que la cuantificacion de los asfaltenos depende del tipo de solvente utilizado.

  2. Chemical composition of Pechora Sea crude oil

    Directory of Open Access Journals (Sweden)

    Derkach S. R.

    2017-03-01

    Full Text Available The physicochemical properties of the Pechora Sea shelf oil and its chemical composition have been studied using the methods of refractometry, titrimetry, viscometry, rheometry and standard methods for the analysis of oil and petroleum products. The fractionation of oil is held at atmospheric pressure, some fractions boiling at the temperature below and above 211 °C have been received. Chemical structural-group composition of oil and its components has been investigated using a Fourier infrared (IR spectroscopy method. The density of oil has been obtained, it is equal to 24.2 API. The chemical composition analysis shows that water content in the investigated oil sample is about 0.03 % (by weight. The oil sample contains hydrocarbons (including alkanes, naphthenes, arenes and asphaltenes with resins; their content is equal to 89 and 10 % (by weight respectively. Alkane content is about 66 %, including alkanes of normal structure – about 37 %. The solidification temperature of oil sample is equal to –43 °C. This low temperature testifies obliquely low content of solid alkanes (paraffin. Bearing in mind the content of asphaltenes with resins we can refer the investigated oil sample to resinous oils. On the other hand spectral coefficient values (aromaticity quotient and aliphaticity quotient show that oil sample belongs to naphthenic oils. According to the data of Fourier IR spectroscopy contents of naphthenes and arenes are 5.9 and 17.8 % respectively. Thus, the obtained data of chemical structural-group composition of crude oil and its fractions indicate that this oil belongs to the heavy resinous naphthenic oils. The rheological parameters obtained at the shear deformation conditions characterize the crude oil as a visco-plastic medium.

  3. Crude oil burning mechanisms

    DEFF Research Database (Denmark)

    van Gelderen, Laurens; Malmquist, L.M.V.; Jomaas, Grunde

    2015-01-01

    In order to improve predictions for the burning efficiency and the residue composition of in-situ burning of crude oil, the burning mechanism of crude oil was studied in relation to the composition of its hydrocarbon mixture, before, during and after the burning. The surface temperature, flame...... height, mass loss rate and residues of three hydrocarbon liquids (n-octane, dodecane and hexadecane), two crude oils (DUC and REBCO) and one hydrocarbon liquid mixture of the aforementioned hydrocarbon liquids were studied using the Crude Oil Flammability Apparatus. The experimental results were compared...... on the highest achievable oil slick temperature. Based on this mechanism, predictions can then be made depending on the hydrocarbon composition of the fuel and the measured surface temperature....

  4. Crude oil market report

    Energy Technology Data Exchange (ETDEWEB)

    1985-01-01

    Falling demand for refined products and an excess of production capacity are driving world oil prices down further. Competitive price cutting, notably by Mexico, Britain, and the Soviet Union, has left Saudi Arabia the only guardian of a costly pricing discipline in terms of crude oil sales. The current crisis is limited to the producers of crude oil. Refineries are now deciding what, where, and how to buy crude in order to meet the requirements of a slack market place. Saudi Arabia could precipitate a price collapse below $20 per barrel by increasing production volume, but that seems unlikely. 1 figure, 2 tables.

  5. Reduction of benzene and naphthalene mass transfer from crude oils by aging-induced interfacial films.

    Science.gov (United States)

    Ghoshal, Subhasis; Pasion, Catherine; Alshafie, Mohammed

    2004-04-01

    Semi-rigid films or skins form at the interface of crude oil and water as a result of the accumulation of asphaltene and resin fractions when the water-immiscible crude oil is contacted with water for a period of time or "aged". The time varying patterns of area-independent mass transfer coefficients of two compounds, benzene and naphthalene, for dissolution from crude oil and gasoline were determined. Aqueous concentrations of the compounds were measured in the eluent from flow-through reactors, where a nondispersed oil phase and constant oil-water interfacial area were maintained. For Brent Blend crude oil and for gasoline amended with asphaltenes and resins, a rapid decrease in both benzene and naphthalene mass transfer coefficients over the first few days of aging was observed. The mass transfer coefficients of the two target solutes were reduced by up to 80% over 35 d although the equilibrium partition coefficients were unchanged. Aging of gasoline, which has negligible amounts of asphaltene and resin, did not result in a change in the solute mass transfer coefficients. The study demonstrates that formation of crude oil-water interfacial films comprised of asphaltenes and resins contribute to time-dependent decreases in rates of release of environmentally relevant solutes from crude oils and may contribute to the persistence of such solutes at crude oil-contaminated sites. It is estimated that the interfacial film has an extremely low film mass transfer coefficient in the range of 10(-6) cm/min.

  6. 1999 Crude oil market outlook

    International Nuclear Information System (INIS)

    Cochener, J.

    1998-01-01

    Baseline projection handling of crude oil prices was discussed, based on actual crude oil price trends from 1992 to 1998. Attention was drawn to the lack of correlation between crude oil and natural gas prices. Predictions for crude oil production were extended to the year 2015. As far as the immediate future is concerned the crude oil price for 1999 was predicted to continue to be sluggish due to competitive pressure from refined products at burner tip. tabs., figs

  7. Stabilization of Model Crude Oil Emulsion using Different ...

    African Journals Online (AJOL)

    MBI

    2015-12-31

    Dec 31, 2015 ... interaction of asphaltene with the prepared model oils can be used as a ... techniques, microscopy, interfacial pressure, and ... conclusion that these compounds were asphaltene .... The emulsion may invert from oil in water.

  8. Methods of analyzing crude oil

    Science.gov (United States)

    Cooks, Robert Graham; Jjunju, Fred Paul Mark; Li, Anyin; Rogan, Iman S.

    2017-08-15

    The invention generally relates to methods of analyzing crude oil. In certain embodiments, methods of the invention involve obtaining a crude oil sample, and subjecting the crude oil sample to mass spectrometry analysis. In certain embodiments, the method is performed without any sample pre-purification steps.

  9. Effect of temperature on biodegradation of crude oil

    International Nuclear Information System (INIS)

    Zekri, A.; Chaalal, O.

    2005-01-01

    An active strain of anaerobic thermophilic bacteria was isolated from the environment of the United Arab Emirates. This project studied the effect of temperature, salinity and oil concentration on biodegradation of crude oil. Oil weight loss, microbial growth and the changes of the crude oil asphaltene concentration are used to evaluate the oil degradation by this strain. A series of batch experiments was performed to study the effects of bacteria on the degradation of crude oil. The effects of oil concentration, bacteria concentration, temperature and salinity on the biodegradation were investigated. The temperatures of the studied systems were varied between 35 and 75 o C and the salt concentrations were varied between 0 and 10%. Oil concentrations were ranged from 5 to 50% by volume. Experimental work showed the bacteria employed in this project were capable of surviving the harsh environment and degrading the crude oil at various conditions. Increasing the temperature increases the rate of oil degradation by bacteria. Increasing the oil concentration in general decreases the rate of bacteria oil degradation. Salinity plays a major role on the acceleration of biodegradation process of crude oil. An optimum salinity should be determined for every studied system. The finding of this project could be used in either the treatment of oil spill or in-situ stimulation of heavy oil wells. (author)

  10. Raman spectrum of asphaltene

    KAUST Repository

    Abdallah, Wael A.; Yang, Yang

    2012-01-01

    Asphaltenes extracted from seven different crude oils representing different geological formations from around the globe were analyzed using the Raman spectroscopic technique. Each spectrum is fitted with four main peaks using the Gaussian function. On the basis of D1 and G bands of the Raman spectrum, asphaltene indicated an ordered structure with the presence of boundary defected edges. The average aromatic sheet size of the asphaltene molecules is estimated within the range of 1.52-1.88 nm, which represents approximately seven to eight aromatic fused rings. This estimation is based on the integrated intensity of D1 and G bands, as proposed by Tunistra and Koenig. The results here are in perfect agreement with so many other used techniques and indicate the potential applicability of Raman measurements to determine the average aromatic ring size and its boundary. © 2012 American Chemical Society.

  11. Raman spectrum of asphaltene

    KAUST Repository

    Abdallah, Wael A.

    2012-11-05

    Asphaltenes extracted from seven different crude oils representing different geological formations from around the globe were analyzed using the Raman spectroscopic technique. Each spectrum is fitted with four main peaks using the Gaussian function. On the basis of D1 and G bands of the Raman spectrum, asphaltene indicated an ordered structure with the presence of boundary defected edges. The average aromatic sheet size of the asphaltene molecules is estimated within the range of 1.52-1.88 nm, which represents approximately seven to eight aromatic fused rings. This estimation is based on the integrated intensity of D1 and G bands, as proposed by Tunistra and Koenig. The results here are in perfect agreement with so many other used techniques and indicate the potential applicability of Raman measurements to determine the average aromatic ring size and its boundary. © 2012 American Chemical Society.

  12. Record prices [crude oil

    International Nuclear Information System (INIS)

    Anon

    2006-01-01

    Crude oil prices climbed to new record levels on fears of a future loss of supplies from Iran as Washington stepped up its efforts to persuade Tehran to abandon its programme to produce nuclear fuel. IPE's December Brent contract set a new record for the exchange by trading at $75.80/bbl on 21st April. On the same day October WTI reached an all-time high of $77.30/bbl on Nymex. US product prices gained as refiners struggled to produce sufficient middle distillate. Alarmed by the rising retail price of gasoline, the US Senate debated a reduction in the already low US tax rate on motor spirit. The House of Representatives passed a measure to prohibit overcharging for petrol, diesel and heating oil, but Democrats rejected a Republican proposal to speed-up the process for approving new refineries. President George W Bush announced a temporary easing of new gasoline and diesel specifications (see 'Focus', March 2006) to allow more fuel to be produced. He also agreed to delay the repayment of some 2.1 mn bbl of crude oil lent to companies after last year's hurricanes from the Strategic Petroleum Reserve. California announced an inquiry into alleged overcharging for fuel by oil companies operating in the state. (author)

  13. Use of adsorption and gas chromatographic techniques in estimating biodegradation of indigenous crude oils

    International Nuclear Information System (INIS)

    Kokub, D.; Allahi, A.; Shafeeq, M.; Khalid, Z.M.; Malik, K.A.; Hussain, A.

    1993-01-01

    Indigenous crude oils could be degraded and emulsified upto varying degree by locally isolated bacteria. Degradation and emulsification was found to be dependent upon the chemical composition of the crude oils. Tando Alum and Khashkheli crude oils were emulsified in 27 and 33 days of incubation respectively. While Joyamair crude oil and not emulsify even mainly due to high viscosity of this oil. Using adsorption chromatographic technique, oil from control (uninoculated) and bio degraded flasks was fractioned into the deasphaltened oil containing saturate, aromatic, NSO (nitrogen, sulphur, oxygen) containing hydrocarbons) and soluble asphaltenes. Saturate fractions from control and degraded oil were further analysed by gas liquid chromatography. From these analyses, it was observed that saturate fraction was preferentially utilized and the crude oils having greater contents of saturate fraction were better emulsified than those low in this fraction. Utilization of various fractions of crude oils was in the order saturate> aromatic> NSO. (author)

  14. Canada's crude oil resources : crude oil in our daily lives

    International Nuclear Information System (INIS)

    Bott, R.

    2001-10-01

    Created in 1975, the Petroleum Communication Foundation is a not-for-profit organization. The objective of the Foundation is to inform Canadians about the petroleum industry in Canada. It produces educational, fact-based publications and programs, employing a multi-stakeholder review process. The first section of this publication is devoted to crude oil and the benefits that are derived from it. It begins by providing a brief definition of crude oil, then moves to the many uses in our daily lives and the environmental impacts like air pollution, spills, and footprint on the land from exploration and production activities. Section 2 details the many uses of crude oil and identifies the major oil producing regions of Canada. A quick mention is made of non-conventional sources of crude oil. The search for crude oil is the topic of section 3 of the document, providing an overview of the exploration activities, the access rights that must be obtained before gaining access to the resource. The drilling of oil is discussed in section 4. Section 5 deals with issues pertaining to reservoirs within rocks, while section 6 covers the feeding of the refineries, discussing topics from the movement of oil to market to the refining of the crude oil, and the pricing issues. In section 7, the uncertain future is examined with a view of balancing the supply and demand, as crude oil is a non-renewable resource. Supplementary information is provided concerning additional publications published by various organizations and agencies. figs

  15. Wax deposition in crude oil pipelines

    Energy Technology Data Exchange (ETDEWEB)

    Assuncao, Pablo Morelato; Rodrigues, Lorennzo Marrochi Nolding [Universidade Federal do Espirito Santo, Sao Mateus, ES (Brazil). Centro Universitario Norte do Espirito Santo. Engenharia de Petroleo; Romero, Mao Ilich [University of Wyoming, Laramie, WY (United States). Enhanced Oil Recovery Institute], e-mail: mromerov@uwyo.edu

    2010-07-01

    Crude oil is a complex mixture of hydrocarbons which consists of aromatics, paraffins, naphthenics, resins asphaltenes, etc. When the temperature of crude oil is reduced, the heavy components, like paraffin, will precipitate and deposit on the pipe internal wall in the form of a wax-oil gel. The gel deposit consists of wax crystals that trap some amount of oil. As the temperature gets cooler, more wax will precipitate and the thickness of the wax gel will increase, causing gradual solidification of the crude and eventually the oil stop moving inside the offshore pipeline. Crude oil may not be able to be re-mobilized during re-startup. The effective diameter will be reduced with wax deposition, resulting in several problems, for example, higher pressure drop which means additional pumping energy costs, poor oil quality, use of chemical components like precipitation inhibitors or flowing facilitators, equipment failure, risk of leakage, clogging of the ducts and process equipment. Wax deposition problems can become so sever that the whole pipeline can be completely blocked. It would cost millions of dollars to remediate an offshore pipeline that is blocked by wax. Wax solubility decreases drastically with decreasing temperature. At low temperatures, as encountered in deep water production, is easy to wax precipitate. The highest temperature below which the paraffins begins to precipitate as wax crystals is defined as wax appearance temperature (WAT). Deposition process is a complex free surface problem involving thermodynamics, fluid dynamics, mass and heat transfer. In this work, a numerical analysis of wax deposition by molecular diffusion and shear dispersion mechanisms in crude oil pipeline is studied. Diffusion flux of wax toward the wall is estimated by Fick's law of diffusion, in similar way the shear dispersion; wax concentration gradient at the solid-liquid interface is obtained by the volume fraction conservation equation; and since the wax deposition

  16. Relations between interfacial properties and heavy crude oil emulsions stability; Relations entre les proprietes interfaciales et la stabilite des emulsions de brut lourd

    Energy Technology Data Exchange (ETDEWEB)

    Hoebler-Poteau, S.

    2006-02-15

    Oil in water emulsions are currently being investigated to facilitate the transport of viscous heavy oils. The behavior of these emulsions is largely controlled by oil / water interfaces. The surface-active components of crude oil such as asphaltenes and naphthenic acids compete among themselves at these interfaces and also with possibly added synthetic surfactant emulsifier.Here, we present a study of dynamic interfacial tension and rheology of interfaces between water and a model oil (toluene) in which asphaltenes and other surface active molecules from crude oil are dissolved. We show that different parameters such as aging of the interface, asphaltenes concentration, the pH and salinity of the aqueous phase have a strong influence on interfacial properties of asphaltenes at the oil/water interface. Several micro-pipette experiments, in which micrometric drops have been manipulated, are described as well as small angle neutron scattering measurements. The influence of lower molecular weight surface-active species, such as the natural naphthenic acids contained in maltenes (crude oil without asphaltenes) has been investigated, and an interaction between asphaltenes and maltenes which facilitates molecular arrangement at the interface was detected. The microscopic properties of the different interfaces and the stability of the corresponding emulsions are determined to be correlated.The results obtained on model emulsions and model oil/water interfaces were found to be helpful in order to explain and predict the behavior of heavy crude oil emulsions. (author)

  17. Maglev crude oil pipeline

    Science.gov (United States)

    Knolle, Ernst G.

    1994-01-01

    This maglev crude oil pipeline consists of two conduits guiding an endless stream of long containers. One conduit carries loaded containers and the other empty returns. The containers are levitated by permanent magnets in repulsion and propelled by stationary linear induction motors. The containers are linked to each other in a manner that allows them, while in continuous motion, to be folded into side by side position at loading and unloading points. This folding causes a speed reduction in proportion to the ratio of container diameter to container length. While in side by side position, containers are opened at their ends to be filled or emptied. Container size and speed are elected to produce a desired carrying capacity.

  18. NMR and Chemometric Characterization of Vacuum Residues and Vacuum Gas Oils from Crude Oils of Different Origin

    Directory of Open Access Journals (Sweden)

    Jelena Parlov Vuković

    2015-03-01

    Full Text Available NMR spectroscopy in combination with statistical methods was used to study vacuum residues and vacuum gas oils from 32 crude oils of different origin. Two chemometric metodes were applied. Firstly, principal component analysis on complete spectra was used to perform classification of samples and clear distinction between vacuum residues and vacuum light and heavy gas oils were obtained. To quantitatively predict the composition of asphaltenes, principal component regression models using areas of resonance signals spaned by 11 frequency bins of the 1H NMR spectra were build. The first 5 principal components accounted for more than 94 % of variations in the input data set and coefficient of determination for correlation between measured and predicted values was R2 = 0.7421. Although this value is not significant, it shows the underlying linear dependence in the data. Pseudo two-dimensional DOSY NMR experiments were used to assess the composition and structural properties of asphaltenes in a selected crude oil and its vacuum residue on the basis of their different hydrodynamic behavior and translational diffusion coefficients. DOSY spectra showed the presence of several asphaltene aggregates differing in size and interactions they formed. The obtained results have shown that NMR techniques in combination with chemometrics are very useful to analyze vacuum residues and vacuum gas oils. Furthermore, we expect that our ongoing investigation of asphaltenes from crude oils of different origin will elucidate in more details composition, structure and properties of these complex molecular systems.

  19. Asphaltene precipitation and its effects on the vapour extraction (VAPEX) heavy oil recovery process

    Energy Technology Data Exchange (ETDEWEB)

    Luo, P.; Wang, X.; Gu, Y. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[Regina Univ., SK (Canada). Petroleum Technology Research Centre; Zhang, H. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[Core Laboratories Canada Ltd., Calgary, AB (Canada); Moghadam, L. [Fekete Associates Inc., Calgary, AB (Canada)

    2008-10-15

    One of the most important physical phenomena during the solvent vapour extraction (VAPEX) of heavy oil recovery is asphaltene precipitation. After the asphaltene precipitation occurs, the produced heavy oil is deasphalted in-situ, resulting in a lower viscosity and better quality. However, precipitated asphaltenes may plug some small pores of the reservoir formation, thus reducing its permeability. This paper examined the effects of three operating factors on the asphaltene precipitation during the VAPEX process, notably solvent type; operating pressure; and sand-pack permeability. Eight VAPEX tests were conducted to recover two different Lloydminster heavy oil samples from a rectangular sand-packed physical model with a butane mixture and propane as the respective solvents. The accumulative heavy oil and solvent production from the physical model were measured in the entire VAPEX process. The paper described the materials, experimental set-up, and experimental preparation. The VAPEX test was also explained. Results were presented for sand consolidation; solvent effect; pressure effect; and permeability effect. It was concluded that when the extracting solvent is in a liquid-gas state, asphaltene precipitation occurs and leads to in-situ deasphalting. 15 refs., 3 tabs., 6 figs.

  20. Separation and characterization of asphaltenic subfractions

    Energy Technology Data Exchange (ETDEWEB)

    Honse, Siller O.; Ferreira, Silas R.; Mansur, Claudia R. E.; Lucas, Elizabete F. [Universidade Federal do Rio de Janeiro (IMA/UFRJ), RJ (Brazil). Inst. de Macromoleculas Professora Eloisa Mano; Gonzalez, Gaspar, E-mail: elucas@ima.ufrj.br [Centro de Pesquisas da PETROBRAS (CENPES), Rio de Janeiro, RJ (Brazil)

    2012-07-01

    The structure of the various asphaltenic subfractions found in crude oil was evaluated. For this purpose, C5 asphaltenes were extracted from an asphaltic residue using n-pentane as the flocculant solvent. The different subfractions were isolated from the C5 asphaltenes by the difference in solubility in different solvents. These were characterized by infrared spectroscopy, nuclear magnetic resonance, X-ray fluorescence, elementary analysis and mass spectrometry. The results confirmed that the subfractions extracted with higher alkanes had greater aromaticity and molar mass. However, small solubility variations between the subfractions were attributed mainly to the variation in the concentrations of cyclical hydrocarbon compounds and metals (author)

  1. New insights into oxidation behaviours of crude oils

    Energy Technology Data Exchange (ETDEWEB)

    Li, J.; Mehta, S.A.; Moore, R.G. [Calgary Univ., AB (Canada)

    2006-07-01

    Innovative technologies will be needed to develop many of the world's oil reservoirs in an economically sustainable manner. In recent years, air injection for light oil reservoirs has gained recognition as an Improved Oil Recovery (IOR) process. In this process, the oxygen from the injected air reacts with a small fraction of the reservoir oil at high temperature to produce a mixture of carbon dioxide and nitrogen. The produced gas generated by the reaction mobilizes the oil downstream, thereby sweeping oil towards the production wells. High pressure air injection used in light oil reservoirs differs from the process used in heavy oil reservoirs, despite the fact that various oxidation reaction schemes exist. The key challenge facing the air injection process is the complexity of the oxidation reaction for crude oil and the lack of understanding of the oxidation behavior of light oils. This study identified a range of oxidation behaviors between light oil and heavy oil. The relationship between crude oil composition and its oxidation behaviors was also examined with reference to 3 different oils and their SARA (saturates, aromatics, resins and asphaltenes) fractions. This study was carried out at various pressures and temperatures using thermogravimetry and pressurized differential scanning calorimetry (PDSC) as the thermal analysis techniques.

  2. Investigation of Asphaltene Adsorption onto Zeolite Beta Nanoparticles to Reduce Asphaltene Deposition in a Silica Sand Pack

    Directory of Open Access Journals (Sweden)

    Kashefi Sepideh

    2018-01-01

    Full Text Available Zeolite beta nanoparticles were used as a new asphaltene adsorbent for reducing asphaltene deposition during fluid injection into a silica sand pack. At first, the asphaltene adsorption efficiency and capacity of zeolite beta nanoparticles were determined by UV-Vis spectrophotometer. It was found that the proper concentration of nanoparticles for asphaltene adsorption was 10 g/L and the maximum asphaltene adsorption onto zeolite beta was 1.98 mg/m2. Second, two dynamic experiments including co-injection of crude oil and n-heptane (as an asphaltene precipitant with and without use of zeolite beta nanoparticles in the sand pack was carried out. The results showed that the use of zeolite beta nanoparticles increased the permeability ratio and outlet fluid's asphaltene content about 22% and 40% compared to without use of nanoparticles, respectively. Moreover, a model based on monolayer asphaltene adsorption onto nanoparticles and asphaltene deposition mechanisms including surface deposition, entrainment and pore throat plugging was developed to determine formation damage during co-injection of crude oil and n-heptane into the sand pack. The proposed model presented good prediction of permeability and porosity ratios with AAD% of 1.07 and 0.07, respectively.

  3. EPR and Fluorescence Spectroscopy in the Photodegradation Study of Arabian and Colombian Crude Oils

    Directory of Open Access Journals (Sweden)

    Carmen L. B. Guedes

    2006-01-01

    W/m2. The reduction in the linewidth of the free radical of 9.8% in Arabian oil and 18.5% in Colombian oil, as well as the decrease in radical numbers, indicated photochemical degradation, especially in Colombian oil. The linewidth narrowing corresponding to free radicals in the irradiated oils occurred due to the rearrangement among radicals and aromatic carbon consumption. The irradiated oils showed a reduction in the relative intensity of fluorescence of the aromatics with high molecular mass, polar aromatics, and asphaltene. The fluorescent fraction was reduced by 61% in Arabian oil and 72% in Colombian oil, corresponding to photochemical degradation of crude oil aromatic compounds.

  4. Determination of trace elements in GPC fractions of oil-sand asphaltenes by INAA

    International Nuclear Information System (INIS)

    Jacobs, F.S.; Bachelor, F.W.; Filby, R.H.

    1984-01-01

    Asphaltene samples precipitated from Athabasca and Cold Lake oil-sand bitumens were separated into 12 fractions of varying molecular weight by preparative gel permeation chromatography (GPC). Each fraction was then analyzed by analytical GPC and visible spectrometry. Concentrations of As, Ce, Co, Cr, Eu, Ga, Hf, Hg, La, Ni, Sb, Sc, Se, Sm, Tb, Th, U, V, Zn, and Zr in the fractions were determined by neutron activation analysis. Molecular weights of the Athabasca fractions are generally higher than the corresponding Cold Lake fractions. Between 58% and 90% of the metal contents occur in the high molecular weight fractions of both asphaltenes. Except for V and Cr, which show biomodel distributions, all the elements have decreasing concentrations as the molecular weight of the fraction decreases. High molecular weight fractions, constituting about 55% of the whole asphaltenes, contain nonporphyrin bound vanadium compounds. It is estimated that 27% and 31% of V present in Athabasca and Cold Lake asphaltenes respectively occur as porphyrin type compounds, including vanadyl prophyrins released from the asphaltene micelle during the separation and vanadyl porphyrins bearing high-molecular-weight substituents

  5. Exports of crude oil, 1988

    International Nuclear Information System (INIS)

    1989-06-01

    Effective June 1, 1985, licensing and charging of oil exports ended. The Board now issues export orders specifying neither volumes nor prices and covering an exportation period of up to 1 year for light crude oil and up to 2 years for heavy crude oil, available on request to both Canadian and foreign companies. The Board has assumed a monitoring role, and export prices and volumes are reported monthly by exporters. This annual report provides a review of the volumes and prices associated with the supply and disposition of Canadian crude oil during 1988. Highlights are given with detailed information on prices, both internationally, in Canada, and the Chicago posted price by light or heavy crude, and on volumes including capacity and disposition in both domestic and export markets. A short description of the import market is included. Comparisons are made with the previous year. Export volumes of light crude oil in 1988 increased by 13% to average 50,200 m 3 /d. Export volumes of heavy crude also increased by ca 13% to 62,600 m 3 /d. 15 figs., 2 tabs

  6. Interfacial rheology of asphaltenes at oil-water interfaces and interpretation of the equation of state.

    Science.gov (United States)

    Rane, Jayant P; Pauchard, Vincent; Couzis, Alexander; Banerjee, Sanjoy

    2013-04-16

    In an earlier study, oil-water interfacial tension was measured by the pendant drop technique for a range of oil-phase asphaltene concentrations and viscosities. The interfacial tension was found to be related to the relative surface coverage during droplet expansion. The relationship was independent of aging time and bulk asphaltenes concentration, suggesting that cross-linking did not occur at the interface and that only asphaltene monomers were adsorbed. The present study extends this work to measurements of interfacial rheology with the same fluids. Dilatation moduli have been measured using the pulsating droplet technique at different frequencies, different concentrations (below and above CNAC), and different aging times. Care was taken to apply the technique in conditions where viscous and inertial effects are small. The elastic modulus increases with frequency and then plateaus to an asymptotic value. The asymptotic or instantaneous elasticity has been plotted against the interfacial tension, indicating the existence of a unique relationship, between them, independent of adsorption conditions. The relationship between interfacial tension and surface coverage is analyzed with a Langmuir equation of state. The equation of state also enabled the prediction of the observed relationship between the instantaneous elasticity and interfacial tension. The fit by a simple Langmuir equation of state (EOS) suggests minimal effects of aging and of nanoaggregates or gel formation at the interface. Only one parameter is involved in the fit, which is the surface excess coverage Γ∞ = 3.2 molecules/nm(2) (31.25 Å(2)/molecule). This value appears to agree with flat-on adsorption of monomeric asphaltene structures consisting of aromatic cores composed of an average of six fused rings and supports the hypothesis that nanoaggregates do not adsorb on the interface. The observed interfacial effects of the adsorbed asphaltenes, correlated by the Langmuir EOS, are consistent with

  7. Asphaltene Aggregation and Fouling Behavior

    Science.gov (United States)

    Derakhshesh, Marzie

    This thesis explored the properties of asphaltene nano-aggregates in crude oil and toluene based solutions and fouling at process furnace temperatures, and the links between these two phenomena. The link between stability of asphaltenes at ambient conditions and fouling at the conditions of a delayed coker furnace, at over 450 °C, was examined by blending crude oil with an aliphatic diluent in different ratios. The stability of the blends were measured using a S-value analyzer, then fouling rates were measured on electrically heated stainless steel 316 wires in an autoclave reactor. The less stable the blend, the greater the rate and extent of fouling. The most severe fouling occurred with the unstable asphaltenes. SEM imaging of the foulant illustrates very different textures, with the structure becoming more porous with lower stability. Under cross-polarized light, the coke shows the presence of mesophase in the foulant layer. These data suggest a correlation between the fouling rate at high temperature furnace conditions and the stability index of the crude oil. Three organic polysulfides were introduced to the crude oil to examine their effect on fouling. The polysulfides are able to reduce coking and carbon monoxide generation in steam crackers. The fouling results demonstrated that polysulfide with more sulfur content increased the amount of corrosion-fouling of the wire. Various additives, solvents, ultrasound, and heat were employed to attempt to completely disaggregate the asphaltene nano-aggregates in solution at room temperature. The primary analytical technique used to monitor the nano-aggregation state of the asphaltenes in solution was the UV-visible spectroscopy. The results indicate that stronger solvents, such as pyridine and quinoline, combined with ionic liquids yield a slight reduction in the apparent absorbance at longer wavelengths, indicative of a decrease in the nano-aggregate size although the magnitude of the decrease is not significant

  8. 15 CFR 754.2 - Crude oil.

    Science.gov (United States)

    2010-01-01

    ... processed through a crude oil distillation tower. Included are reconstituted crude petroleum, and lease... 15 Commerce and Foreign Trade 2 2010-01-01 2010-01-01 false Crude oil. 754.2 Section 754.2....2 Crude oil. (a) License requirement. As indicated by the SS notation in the “License Requirements...

  9. Mercury in Canadian crude oil

    International Nuclear Information System (INIS)

    Hollebone, B.P.

    2005-01-01

    Estimates for average mercury concentrations in crude oil range widely from 10 ng/g of oil to 3,500 ng/g of oil. With such a broad range of estimates, it is difficult to determine the contributions of the petroleum sector to the total budget of mercury emissions. In response to concerns that the combustion of petroleum products may be a major source of air-borne mercury pollution, Environment Canada and the Canadian Petroleum Products Institute has undertaken a survey of the average total mercury concentration in crude oil processed in Canadian refineries. In order to calculate the potential upper limit of total mercury in all refined products, samples of more than 30 different types of crude oil collected from refineries were measured for their concentration of mercury as it enters into a refinery before processing. High temperature combustion, cold vapour atomic absorption and cold vapour atomic fluorescence were the techniques used to quantify mercury in the samples. The results of the study provide information on the total mass of mercury present in crude oil processed in Canada each year. Results can be used to determine the impact of vehicle exhaust emissions to the overall Canadian mercury emission budget. 17 refs., 2 tabs., 2 figs

  10. OPEC's optimal crude oil price

    International Nuclear Information System (INIS)

    Horn, Manfred

    2004-01-01

    OPEC decided to stabilise oil prices within a range of 22-28 US Dollar/barrel of crude oil. Such an oil-price-level is far beyond the short and long run marginal costs of oil production, beyond even that in regions with particularly high costs. Nevertheless, OPEC may achieve its goal if world demand for oil increases substantially in the future and oil resources outside the OPEC are not big enough to accordingly increase production. In this case OPEC, which controls about 78% of world oil reserves, has to supply a large share of that demand increase. If we assume OPEC will behave as a partial monopolist on the oil market, which takes into consideration the reaction of the other producers to its own sales strategy, it can reach its price target. Lower prices before 2020 are probable only if the OPEC cartel breaks up. Higher prices are possible if production outside OPEC is inelastic as assumed by some geologists, but they would probably stimulate the production of unconventional oil based on oil sand or coal. Crude oil prices above 30 US Dollar/barrel are therefore probably not sustainable for a long period. (Author)

  11. Effect on molecular interactions of chemical alteration of petroleum asphaltenes. I

    DEFF Research Database (Denmark)

    Juyal, Priyanka; Garcia, Daniel Merino; Andersen, Simon Ivar

    2005-01-01

    Asphaltenes are naturally occurring components of crude oil and have been the subject of many studies that have involved a variety of methods to determine their complex structure, their association in crude oil with resins, and their agglomeration phenomena. Yet, the molecular structures of aspha......Asphaltenes are naturally occurring components of crude oil and have been the subject of many studies that have involved a variety of methods to determine their complex structure, their association in crude oil with resins, and their agglomeration phenomena. Yet, the molecular structures...... of asphaltenes have not been fully elucidated. It is especially important to characterize the polar functionalities of these fractions, because they participate in the intermolecular aggregation by means of hydrogen bonds. The chemical derivatization of asphaltenes has been used, in combination with suitable...

  12. CFD modeling of fouling in crude oil pre-heaters

    International Nuclear Information System (INIS)

    Bayat, Mahmoud; Aminian, Javad; Bazmi, Mansour; Shahhosseini, Shahrokh; Sharifi, Khashayar

    2012-01-01

    Highlights: ► A conceptual CFD-based model to predict fouling in industrial crude oil pre-heaters. ► Tracing fouling formation in the induction and developing continuation periods. ► Effect of chemical components, shell-side HTC and turbulent flow on the fouling rate. - Abstract: In this study, a conceptual procedure based on the computational fluid dynamic (CFD) technique has been developed to predict fouling rate in an industrial crude oil pre-heater. According to the developed CFD concept crude oil was assumed to be composed of three pseudo-components comprising of petroleum, asphaltene and salt. The binary diffusion coefficients were appropriately categorized into five different groups. The species transport model was applied to simulate the mixing and transport of chemical species. The possibility of adherence of reaction products to the wall was taken into account by applying a high viscosity for the products in competition with the shear stress on the wall. Results showed a reasonable agreement between the model predictions and the plant data. The CFD model could be applied to new operating conditions to investigate the details of the crude oil fouling in the industrial pre-heaters.

  13. The price of crude oil

    International Nuclear Information System (INIS)

    Bakhtiari, A.M.S.

    1999-01-01

    The price of crude oil is among the most important prices quoted daily across the world - which is not surprising, since crude oil is the most widely used source of energy worldwide, as well as being a unique commodity. When petroleum burst onto the world stage in 1859, its price first went through some initial gyrations (1860-70), before settling in the $1.00 - 2.00 per barrel range (barring a few exceptions) for a full century. Then, the price underwent two 'shocks' (1973 and 1980), followed by the 'counter-shock' of 1986. Thereafter, the price entered the relative stability of the $15 - 20 /b consensus, where it lingered until recently. Some day, there is bound to be a fresh paradigm of 'insufficient oil reserves', thus ushering in a new era for oil prices. Taking into consideration available data on reserves and expert analysis, it would seem that that day may be years rather than decades away

  14. Molecular-weight distributions of coal and petroleum asphaltenes from laser desorption/ionization experiments

    Energy Technology Data Exchange (ETDEWEB)

    Ana R. Hortal; Paola Hurtado; Bruno Martinez-Haya; Oliver C. Mullins [Universidad Pablo de Olavide, Seville (Spain). Departamento de Sistemas Fisicos, Quimicos y Naturales

    2007-09-15

    Molecular-weight distributions (MWDs) of asphaltenes extracted from coal and petroleum have been measured in laser desorption/ionization (LDI) mass spectrometric experiments. The dried-droplet and solvent-free sample preparation methods are compared. The coal asphaltenes have a relatively narrow MWD (full width 150 amu) with an average molecular weight of 340 amu. The petroleum asphaltenes display a broader MWD (full width 300 amu) and are heavier on average (680 amu). The LDI spectra also provide evidence for the formation of noncovalent clusters of the two types of asphaltenes during the desorption process. Petroleum and coal asphaltenes exhibit aggregation as do large model polycyclic aromatic hydrocarbons (PAHs) with five or more fused rings also included in the study. Smaller PAHs (pyrene) exhibit less aggregation, especially when alkane-chain substituents are incorporated to the molecular structure. This indicates that asphaltenes possess large PAHs and, according to the relatively small molecular weights observed, that there is a preponderance of asphaltene molecules with only a single fused ring system. The coal asphaltenes present a significantly smaller propensity toward aggregation than their crude oil counterparts. This finding, coupled with the fact that (1) alkanes inhibit aggregation in LDI and (2) petroleum asphaltenes possess much more alkane carbon, indicates that coal asphaltenes have smaller PAHs on average than petroleum asphaltenes. This is further corroborated by the stronger ultraviolet absorbance of the coal asphaltenes at wavelengths shorter than 400 nm. 32 refs., 8 figs.

  15. Market potential for Canadian crude oil

    International Nuclear Information System (INIS)

    Heath, M.; Fisher, L.; Golosinski, D.; Luthin, A.; Gill, L.; Raggett, C.

    1997-01-01

    Future key markets for Canadian crude were evaluated, and probable flow volumes and prices were identified. Key concerns of market participants such as pricing, alternative crude sources, pipeline tariffs and crude quality, were examined. An overview of the competition faced by Canadian crude supply in global markets was presented. World crude oil supply and demand was discussed. US and Canadian crude oil supply (2000 to 2010), refinery demand for light and heavy crudes, existing future crude oil and refined product pipeline infrastructure, and pricing implications of changing crude oil flows were analyzed. The general conclusion was that the US market will continue to provide growing markets for Canadian crude oil, and that the Canadian supply to fulfill increased export requirements will be available due to the combined effects of increasing heavy crude supply, growing production from the east coast offshore, and recent and ongoing pipeline expansions and additions. 20 refs., 64 tabs., 42 figs

  16. Crude oil pipeline expansion summary

    International Nuclear Information System (INIS)

    2005-02-01

    The Canadian Association of Petroleum Producers has been working with producers to address issues associated with the development of new pipeline capacity from western Canada. This document presents an assessment of the need for additional oil pipeline capacity given the changing mix of crude oil types and forecasted supply growth. It is of particular interest to crude oil producers and contributes to current available information for market participants. While detailed, the underlying analysis does not account for all the factors that may come into play when individual market participants make choices about which expansions they may support. The key focus is on the importance of timely expansion. It was emphasized that if pipeline expansions lags the crude supply growth, then the consequences would be both significant and unacceptable. Obstacles to timely expansion are also discussed. The report reviews the production and supply forecasts, the existing crude oil pipeline infrastructure, opportunities for new market development, requirements for new pipeline capacity and tolling options for pipeline development. tabs., figs., 1 appendix

  17. Adsorption and wettability study of methyl ester sulphonate on precipitated asphaltene

    International Nuclear Information System (INIS)

    Okafor, H E; Gholami, R; Sukirman, Y

    2016-01-01

    Asphaltene precipitation from crude oil and its subsequent aggregation forms solid, which preferentially deposit on rock surfaces causing formation damage and wettability changes leading to loss of crude oil production. To resolve this problem, asphaltene inhibitor has been injected into the formation to prevent the precipitation of asphaltene. Asphaltene inhibitors that are usually employed are generally toxic and non-biodegradable. This paper presents a new environmentally friendly asphaltene inhibitor (methyl ester sulphonate), an anionic surfactant, which has excellent sorption on formation rock surfaces. Result from adsorption study validated by Langmuir and Freundlich models indicate a favourable adsorption. At low volumes injected, methyl ester sulphonate is capable of reverting oil-wet sandstone surface to water-wet surface. Biodegradability test profile shows that for concentrations of 100-5000ppm it is biodegradable by 65-80%. (paper)

  18. Effect of asphaltene and resin oils on the viscosity of bituminous petroleum materials to be used as asphalt primers

    Directory of Open Access Journals (Sweden)

    Bencomo, M. R.

    2006-03-01

    Full Text Available The bituminous crude from the Machete, Venezuela, area, which has such a fluid consistency that it falls outside the normal scope of the A5TM D-5 (1 penetration test exceeding the 3D-mm ceiling specified in that standard and can be used as an asphalt primer: Like other asphalt products, these materials are -chemically speaking- a mix of numerous naphthenic, paraffinic and aromatic hydrocarbons and heterocyclic compounds containing sulphur, nitrogen, oxygen and so on. They have a dense and a malthene oil phase which, along with the natural hydrocarbons additives used in these products acts as a volatile fluidizer. The former is described as a mix of asphaltenes: complex high molecular weight substances that are insoluble in paraffinic hydrocarbons and soluble in aromatic compounds such as benzene. The malthene oil phase, in turn, consists in a mix of resins and hydrocarbons and together the two constitute a colloidal system. The experiments discussed in the present paper were conducted to determine the effect of the proportion of asphaltenes and resin oils on the viscosity of such bituminous crude emulsions/ with a view to their use as primers. These experiments were run in a Parr batch reactor in a nitrogen atmosphere using n-heptane as a solvent. The resins were separated after the asphaltenes precipitated from the samples and subsequently from the malthene fraction obtained. The results showed that the asphaltenes account for the structural characteristics and consistency of the medium and the resin oils for its cohesive properties/,the malthene oils act as solvents.Los crudos extrapesados procedentes del área Machete (Venezuela son materiales de consistencia blanda o fluida, por lo que se salen del campo en el que normalmente se aplica el ensayo de penetración a productos asfálticos según el método ASTM D-5 (1, cuyo límite máximo es 30 mm, y pueden ser utilizados como pinturas asfálticas de imprimación. Al igual que otros productos

  19. Sizes of vanadyl petroporphyrins and asphaltene aggregates in toluene

    Energy Technology Data Exchange (ETDEWEB)

    Dechaine, Greg Paul; Gray, Murray R. [Department of Chemical and Materials Engineering, University of Alberta (Canada)], email: gpd@ualberta.ca

    2010-07-01

    This work focuses on the importance of removing vanadyl porphyrins components from crude oils and the methodology for doing it. The diffusion of asphaltene and vanadium components in diluted toluene was measured using a stirred diaphragm diffusion cell, which was equipped with a number of different cellulosic membranes of different pore size. In-situ UV/visible spectroscopy was used to observe filtrates of the process. The effective diffusivity of asphaltene structures was plotted for different pore sized membranes. It was noticed that asphaltene concentrations increased with increased pore sizes; particularly increasing at pore diameter of 5 nm. Moreover the effects of temperature and mass concentration were also investigated in this study. It was shown that increasing the temperature of the toluene causes the mobility of asphaltene to increase as well. Nevertheless, decreasing the concentration of asphaltene does not affect its mobility. It was shown that toluene samples from different sources showed different mobility.

  20. Asphaltene laboratory assessment of a heavy onshore reservoir during pressure, temperature and composition variations to predict asphaltene onset pressure

    Energy Technology Data Exchange (ETDEWEB)

    Bahrami, Peyman; Ahmadi, Yaser [Islamic Azad University, Tehran (Iran, Islamic Republic of); Kharrat, Riyaz [Petroleum University of Technology, Tehran (Iran, Islamic Republic of); Mahdavi, Sedigheh; James, Lesley [Memorial University of Newfoundland, Saint John' s (Canada)

    2015-02-15

    An Iranian heavy oil reservoir recently encountered challenges in oil production rate, and further investigation has proven that asphaltene precipitation was the root cause of this problem. In addition, CO{sub 2} gas injection could be an appropriate remedy to enhance the production of heavy crudes. In this study, high pressure-high temperature asphaltene precipitation experiments were performed at different temperatures and pressures to investigate the asphaltene phase behavior during the natural depletion process and CO{sub 2} gas injection. Compositional modeling of experimental data predicted onset points at different temperatures which determine the zone of maximum probability of asphaltene precipitation for the studied heavy oil reservoir. Also, the effect of CO{sub 2} gas injection was investigated as a function of CO{sub 2} concentration and pressure. It was found that a CO{sub 2}-oil ratio of 40% is the optimum for limiting precipitation to have the least formation damage and surface instrument contamination.

  1. Biodegradability of northern crude oil

    Energy Technology Data Exchange (ETDEWEB)

    Cook, F D; Westlake, D W.S.

    1976-01-01

    Field studies on the microbiological degradation of crude oils encompassed the placing of oil-soaked plots in two areas in the Northwest Territories and Alberta. Replicate plots received amendments of fertilizer, oil-utilizing bacteria, fertilizer plus bacteria or were untreated except for the oil. Changes in microbial numbers and chemical composition of recovered oil were determined periodically. The initial stimulatory effect on bacterial numbers brought about by the addition of fertilizers to oil-soaked plots diminished two years after the application to a point where the differences were no longer significant. Experiments carried out in the Norman Wells area to determine the effect of the amount of fertilizer applied on oil degradation have yielded inconclusive results. The data suggest that at least 2.7 kg of urea-phosphate fertilizer per kl of oil is required to maintain a reasonable oil degradation rate. Preliminary studies on the use of fertilizer coated with chemicals to increase its hydrophobic character indicate that they could be useful in treating wet-land oil spills. Soils from the McKenzie River drainage basin indicate that bacteria are present which can use oil under mesophilic conditions. However, the ability to use the same oil under psychrophilic conditions is more restricted. At least one bacterial species from each mixed population studied was capable of bringing about chemical changes in oil similar to those observed for the original mixed culture. The potential hazards and uses of the seeding of oil spills is discussed relative to the environmental conditions found in the northern part of Canada. 35 refs., 2 figs., 15 tabs.

  2. Synthesis and evaluation of copolymer based on cardanol and styrene on the stability of asphaltenes; Sintese e avaliacao de copolimero a base de cardanol e estireno sobre a estabilidade dos asfaltenos

    Energy Technology Data Exchange (ETDEWEB)

    Loureiro, Tatiana S.; Spinelli, Luciana S., E-mail: tatianaloureiro@ima.ufrj.br [Universidade Federal do Rio de Janeiro (UFRJ), Rio de Janeiro, RJ (Brazil). Instituto de Macromoleculas

    2015-07-01

    The destabilization of asphaltenes in crude oil mainly happens due to variations in pressure, temperature and oil composition, causing significant losses. Polymers containing specific groups can be used as asphaltenes stabilizers and thus, avoid your precipitation, or as asphaltenes flocculants to assist the removal of suspended particles in a particular oil. The monitoring of asphaltenes precipitation is usually evaluated by tests with variation in stability of asphaltenes in function of adding a flocculant solvent. In this work, it was evaluated the influence of a synthesized copolymer based on cardanol and styrene on the stability of asphaltenes. The stability of asphaltenes was monitored by precipitation tests induced by a flocculant agent (n-heptane), using an ultraviolet-visible (UV-Vis) spectrometer. The structural characterization of copolymer was performed by FTIR and {sup 1}H NMR. The results showed that copolymer can act as asphaltene flocculant. (author)

  3. Production of jet fuel using heavy crude oil; Producao de combustiveis de aviacao a partir de petroleos pesados

    Energy Technology Data Exchange (ETDEWEB)

    Om, Neyda [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Escola de Quimica; Cavado, Alberto; Reyes, Yordanka [Centro de Pesquisas do Petroleo, Cidade de Havana (Cuba); Dominguez, Zulema [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE)

    2004-07-01

    The production of heavy crude oils increased in the last years in the world. Crude oils with high density, viscosity, acidity and sulfur, nitrogen, metals and asphaltenes contents, by the others hand, low stability and low product quality. The challenger of many refiners is find solutions to refine the heavy crude oils, and produce fuels with certify quality, such as Jet Fuel. The principal aviation technique on the world work with gas turbines engines feted for jet fuel (JET A1). The quality specifications of this fuel are establish by International Norms: ASTM-1655, DEF STAN 91-91-3 (DERD 2494) and joint Fuelling System Check List. The world technologies to obtain jet fuel from mixtures of heavy crude oil with middle crude oils are: Atmospheric distillation, with a posterior hydrogenation and finally the additivation. Studies carried out have demonstrates that the Cubans heavy crude oils is characterized for having API less than 10, raised viscosity, high sulfur content (>6%) and asphaltenes content (more than 15%). These properties provide to its derivatives of low quality. This paper define the characteristic of Cuban heavy crude oil, the technology and operational conditions to produce jet fuel (Jet A1) and the quality of fuel produced. (author)

  4. Heavy crude oil and synthetic crude market outlook

    International Nuclear Information System (INIS)

    Crandall, G.R.

    1997-01-01

    This presentation included an outline of the international heavy crude supply and demand versus Canadian heavy crude supply and disposition, and pricing outlook for synthetic crudes. Differences among crude oils such as light sweet, light sour, heavy and bitumen were described and illustrated with respect to their gravity, API, percentage of sulphur, metals and nitrogen. Internationally, heavy and sour crude supplies are forecast to increase significantly over the next four years. Discoveries of light sour crude in offshore Gulf of Mexico will provide a major new source of sour crude to U.S. Gulf Coast refineries. Venezuela's supplies of heavy and sour crude are also expected to increase over the next few years. Mexico and Canada have plans to increase their heavy crude production. All of the crudes will be aimed at the U.S. Gulf Coast and Midwest markets. Pentanes and condensates are also expected to increase based on the growing Canadian natural gas production. Diluent demand will also grow to match Canadian heavy crude/bitumen production. U.S. midwest refiners are proposing expansions to allow them to process more Canadian heavy crude oil. At present, only a few refineries are equipped to process significant amounts of synthetic crude. It was suggested that to absorb available heavy and synthetic production, increased penetration into both Canadian and U.S. markets will be required. Some refineries may have to be modified to process heavy and synthetic oil supplies. Heavy oil and synthetic producers may need to develop relationships with refiners such as joint ventures and term supply agreements to secure markets. 2 tabs., 12 figs

  5. Model compounds for heavy crude oil components and tetrameric acids: Characterization and interfacial behaviour

    Energy Technology Data Exchange (ETDEWEB)

    Nordgaard, Erland Loeken

    2009-07-01

    The tendency during the past decades in the quality of oil reserves shows that conventional crude oil is gradually being depleted and the demand being replaced by heavy crude oils. These oils contain more of a class high-molecular weight components termed asphaltenes. This class is mainly responsible for stable water-in-crude oil emulsions. Both heavy and lighter crude oils in addition contain substantial amounts of naphthenic acids creating naphthenate deposits in topside facilities. The asphaltene class is defined by solubility and consists of several thousand different structures which may behave differently in oil-water systems. The nature of possible sub fractions of the asphaltene has been received more attention lately, but still the properties and composition of such is not completely understood. In this work, the problem has been addressed by synthesizing model compounds for the asphaltenes, on the basis that an acidic function incorporated could be crucial. Such acidic, poly aromatic surfactants turned out to be highly inter facially active as studied by the pendant drop technique. Langmuir monolayer compressions combined with fluorescence of deposited films indicated that the interfacial activity was a result of an efficient packing of the aromatic cores in the molecules, giving stabilizing interactions at the o/w interface. Droplet size distributions of emulsions studied by PFG NMR and adsorption onto hydrophilic silica particles demonstrated the high affinity to o/w interfaces and that the efficient packing gave higher emulsion stability. Comparing to a model compound lacking the acidic group, it was obvious that sub fractions of asphaltenes that contain an acidic, or maybe similar hydrogen bonding functions, could be responsible for stable w/o emulsions. Indigenous tetrameric acids are the main constituent of calcium naphthenate deposits. Several synthetic model tetra acids have been prepared and their properties have been compared to the indigenous

  6. Effect of resins of heat exchanger fouling by asphaltene-containing oils

    Energy Technology Data Exchange (ETDEWEB)

    Al-Atar, E.; Watkinson, A.P. [British Columbia Univ., Dept. of Chemical and Bio-Resource Engineering, Vancouver, BC (Canada)

    1999-07-01

    The effects of resins on the thermal fouling of asphaltene containing oils in heat exchangers was investigated as well as the nature of the deposits. Building on previous research, a sample of de-asphalted vacuum bottoms (DAO), serving as a source of natural resins, heavy oil (HO) and fuel oil was used to investigate the effects of resin concentration on the rate of thermal fouling. The conditions of the study included: fluid circulation through the UBC annular fouling test section for up to 30 hour periods, monitoring of thermal fouling by measurement, and nitrogen atmospheres at a bulk temperature of 85 degrees C, a bulk velocity of 0.85 am/s, and a pressure of 410 kPa. Physical and chemical characterization of the deposits was affected, and filtration at the bulk temperature before and after a run was used to determine the occurrence of fine solids in the fluid. The rate of fouling generally decreased tending generally towards asymptotic behavior in the limit, and after one day Rf values up to 0.3 m2K/kW occurred with severe fouling. An increase in the fouling rate occurred with increased DAO concentration in the mixture, at a fixed heavy oil concentration of 5 weight percent, and the relation between Asomaning's colloidal instability index and the trends in fouling rate was not observed, although there were some indications of reduced fouling as there was an increase in the ratio of resins to asphaltenes, however, blends of the DAO-HO-FO helped to control the concentration of asphaltenes and resins that are possible. (Abstract only).

  7. Upgrading of heavy crude oil with supported and unsupported transition metals

    Energy Technology Data Exchange (ETDEWEB)

    Nares, H.R.; Schacht-Hernandez, P.; Cabrera-Reyes, M.C.; Ramirez-Garnica, M.; Cazarez-Candia, O. [Instituto Mexicano del Petroleo, Atepehuacan (Mexico)

    2006-07-01

    Heavy crude oil presents many problems such as difficulty in transportation, low processing capacity in refineries, and low mobility through the reservoir due to high viscosity which affects the index of productivity of the wells. Because of these challenges, it is necessary to enhance heavy crude oil, both aboveground and underground. The effects of several metallic oxides used to upgrade heavy crude oil properties were examined in order to increase the mobility of reservoir oil by reducing viscosity and improving the quality of the oil. This can be accomplished by reducing the asphaltene and sulfur contents and increasing the American Petroleum Institute (API) gravity using transition metal supported in alumina and unsupported from transition metals derived from either acetylacetonate or alkylhexanoate in liquid phase homogeneously mixed with heavy crude oil as well as metal transition supported in alumina. KU-H heavy crude oil from the Golf of Mexico was studied. The results were obtained by Simulated Distillation and True Boiling Point (TBP). It was concluded that the use of crude oil thermal hydrocracking allowed the API gravity to increase and considerably reduce the viscosity. As a result, the productivity index in wells was increased. However there is a high formation of coke that could damage the conductivity of the rock and then reduce the potential of oil recovery. 27 refs., 3 tabs., 5 figs.

  8. Colloidal Structure of Heavy Crudes and Asphaltene Soltutions Structure colloïdale des bruts lourds et des suspensions d'asphaltènes

    Directory of Open Access Journals (Sweden)

    Barre L.

    2006-12-01

    concentration fluctuations. It exists in the diluted suspension regions more or less extended, where the asphaltene concentration is greater than the average asphaltene concentration. Cryo-scanning electron microscopy has confirmed the system inhomogeneity. A two phase system was clearly highlighted. The flocculation process was followed during n-heptane addition by scattering measurements and microscopy observations. Small angle X-ray scattering (SAXS appears as a powerful tool for non-fractionated systems, as crude oil or other heavy derivatives. Density fluctuations were observed for a vacuum residue. L'industrie pétrolière est souvent confrontée a des problèmes industriels importants liés, entre autre, à la présence d'une forte concentration d'asphaltènes dans les fluides traités. Une meilleure connaissance de la composition de ces molécules et de l'évolution de leur structure colloïdale en solution ou dans leur milieu naturel est d'une grande importance pour mieux comprendre les mécanismes mis en jeu, et ainsi, pouvoir agir et limiter les problèmes rencontrés. Les asphaltènes correspondent à la fraction insoluble dans le n-heptane. Les molécules solubilisées dans l'alcane sont appelées maltènes et peuvent à leur tour être fractionnées par chromatographie en phase liquide; on obtient alors trois nouvelles fractions appelées résines, aromatiques et saturées. La plupart des travaux de recherche réalisés sur ces molécules complexes concernent la détermination de la composition chimique obtenue à l'aide de diverses techniques d'analyse telles la spectroscopie infrarouge et la résonance magnétique nucléaire. En revanche, peu d'informations sur la macrostructure colloïdale des asphaltènes sont disponibles dans la littérature. La détermination de la masse moléculaire a été le premier objectif : plusieurs méthodes, comme l'osmométrie à tension de vapeur, ont été appliquées. La conclusion principale de ces déterminations est la grande

  9. Solids precipitation in crude oils, gas-to-liquids and their blends

    Science.gov (United States)

    Ramanathan, Karthik

    Gas-to-liquids (GTL) liquids are obtained from syngas by the Fischer-Tropsch synthesis. The blending of GTL liquids produced from natural gas/coal reserves and crude oils is a possibility in the near future for multiple reasons. Solids precipitation is a major problem in pipelines and refineries leading to significant additional operating costs. The effect of the addition of a paraffinic GTL liquid to crude oils on solids precipitation was investigated in this study. A Fourier transform infrared (FT-IR) spectroscopic technique was used to obtain solid-liquid equilibria (SLE) data for the various samples. The SLE of multiple systems of model oils composed of n-alkanes was investigated preliminarily. Blends of a model oil simulating a GTL liquid composition and a crude oil showed that the wax precipitation temperature (WPT) decreased upon blending. Three crude oils from different geographic regions (Alaskan North Slope, Colorado and Venezuela) and a laboratory-produced GTL liquid were used in the preparation of blends with five different concentrations of the GTL liquid. The wax precipitation temperatures of the blends were found to decrease with the increasing addition of the GTL liquid for all the oils. This effect was attributed to the solvent effect of the low molecular weight-paraffinic GTL liquid on the crude oils. The weight percent solid precipitated that was estimated as a function of temperature did not show a uniform trend for the set of crude oils. The asphaltene onset studies done on the blends with near-infrared spectroscopy indicated that the addition of GTL liquid could have a stabilizing effect on the asphaltenes in some oils. Analytical techniques such as distillation, solvent separation, HPLC, GC, and GPC were used to obtain detailed composition data on the samples. Two sets of compositional data with 49 and 86 pseudo-components were used to describe the three crude oils used in the blending work. The wax precipitation was calculated using a

  10. Study on the polarity, solubility, and stacking characteristics of asphaltenes

    KAUST Repository

    Zhang, Long-li

    2014-07-01

    The structure and transformation of fused aromatic ring system in asphaltenes play an important role in the character of asphaltenes, and in step affect the properties of heavy oils. Polarity, solubility and structural characteristics of asphaltenes derived from Tahe atmospheric residue (THAR) and Tuo-826 heavy crude oil (Tuo-826) were analyzed for study of their internal relationship. A fractionation method was used to separate the asphaltenes into four sub-fractions, based on their solubility in the mixed solvent, for the study of different structural and physical-chemical properties, such as polarity, solubility, morphology, stacking characteristics, and mean structural parameters. Transmission electron microscope (TEM) observation can present the intuitive morphology of asphaltene molecules, and shows that the structure of asphaltenes is in local order as well as long range disorder. The analysis results showed that n-heptane asphaltenes of THAR and Tuo-826 had larger dipole moment values, larger fused aromatic ring systems, larger mean number of stacking layers, and less interlayer spacing between stacking layers than the corresponding n-pentane asphaltenes. The sub-fractions that were inclined to precipitate from the mixture of n-heptane and tetrahydrofuran had larger polarity and less solubility. From the first sub-fraction to the fourth sub-fraction, polarity, mean stacking numbers, and average layer size from the TEM images follow a gradual decrease. The structural parameters derived from TEM images could reflect the largest fused aromatic ring system in asphaltene molecule, yet the parameters derived from 1H NMR data reflected the mean message of poly-aromatic ring systems. The structural parameters derived from TEM images were more consistent with the polarity variation of sub-fractions than those derived from 1H NMR data, which indicates that the largest fused aromatic ring system will play a more important role in the stacking characteristics of

  11. Classification of weathered crude oils

    International Nuclear Information System (INIS)

    Vogt, N.B.; Sjoegren, C.E.; Lichtenthaler, G.

    1987-01-01

    The NORDTEST procedure (1) for oil spill identification has been applied successfully at several occasions. The NORDTEST procedure includes analyses of sulfur (XRF), vanadium and nickel (ICP/AAS), GC, HPLC and UV-fluorescence. The NORDTEST procedure does not include GC-MS as an analytical method. As part of a joint Nordic to evaluate the NORDTEST procedure for oil identification, with participants from Denmark, Sweden, Finland and Norway, thirty artificially weathered crude oils from four geographical regions have been analyzed (2). The analytical methods evaluated include sulfur analysis, vanadium and nickel analysis, infrared analysis, UV-fluorescence, gas chromatography, high pressure liquid chromatography and high resolution GC-mass spectrometry. Figure 1 shows the distribution of variables analyzed in each analytical method. The 190 variables from GC-MS were split into 7 groups according to chemical considerations. These were steranes (25 var.), triterpanes (16 var.), di(+)aromatics (63 var.), sulf. aromatics (30 var.), monoaromatics (19 var.), cycloalkanes (15 var.) and n-alkanes (22) variables. The data from these chemical analyses have been evaluated for use in oil spill identification purposes

  12. Degradation of crude oil by marine cyanobacteria

    Digital Repository Service at National Institute of Oceanography (India)

    Raghukumar, C.; Vipparty, V.; David, J.J.; Chandramohan, D.

    The marine cyanobacteria Oscillatoria salina Biswas, Plectonema terebrans Bornet et Flanhault and Aphanocapsa sp. degraded Bombay High crude oil when grown in artificial seawater nutrients as well as in plain natural seawater. Oil removals...

  13. De-emulsifiers for water-in-crude oil-emulsions

    Energy Technology Data Exchange (ETDEWEB)

    Zaki, N. [Egyptian Petroleum Research Inst. (EPRI), Cairo (Egypt); Al-Sabagh, A. [Egyptian Petroleum Research Inst. (EPRI), Cairo (Egypt)

    1997-01-01

    The efficiency of 18 different polyalkylphenols-polyalkylene-polyamines-formaldehyde ethoxylates (PAPAFE) in the deemulsification of water-in-crude oil-emulsion were studied. In this respect, two naturally occurring Egyptian water-in-curde oil-emulsions were used to test the investigated de-emulsifiers. The effect of the variation in the molecular structure of the (PAPAFE) on their de-emulsification potency is investigated. The investigation reveals that de-emulsifiers containing nonyl phenol reduce crude oil-water interfacial tension (IFT) and are more efficient than those containing dodecyl phenol. PAPAFE containing more amino groups are found to have better emulsion breaking ability. This is attributed to their enhanced ability to solubilize asphaltenes, which are the prime motivators for crude oil-water emulsion stability. They drag asphaltenes crosslinked at the water-crude oil interface and consequently, resulting in a substantial decrease in emulsion stability. There exists an optimum hydrophilic-lipophilic balance (HLB) for the investigated PAPAFE, ranging from 12 to 13.5 at which their maximum de-emulsification ability is attained. All studied PAPAFE showed increased de-emulsification performance by increasing the temperature from 50 to 70 C. Increasing the temperature reduces the viscosity of the crude oil continuous phase and increases the rate of diffusion of both the surfactant molecules and the dispersed water droplets. This will cause an increase in the rate of coalescence of the water droplets. (orig.) [Deutsch] Es wurde die Wirkung von 18 verschiedenen Polyalkylphenolpolyalkylenpolyamine-formaldehydethoxylaten (PAPAFE) bei der Demulgierung von Wasser-in-Rohoel-Emulsionen untersucht. Zwei in Aegypten natuerlich vorkommende Wasser-in-Rohoel-Emulsionen wurden fuer die Versuche eingesetzt, dabei wurde der Einfluss der molekularen Struktur der PAPAFEs auf das Demulgiervermoegen untersucht. Es zeigte sich, dass Demulgatoren mit Nonylphenol die

  14. Prediction of compatibility of crude oils with condensate (C5+); Previsao de compatibilidade de petroleos e condensado (C5+)

    Energy Technology Data Exchange (ETDEWEB)

    Zilio, Evaldo Lopez; Santos, Maria de Fatima Pereira dos [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil); Ramos, Antonio Carlos da Silva; Rolemberg, Marlus Pinheiro [Universidade Federal do Maranhao (UFMA), Sao Luis, MA (Brazil)

    2008-07-01

    Due to the recent raise of the national natural gas demand and to the need of flowing the condensates (C5+) produced from the NGPP (Natural Gas Processing Plant) by adding them to the streams of the crude oil, there was the need to carry out the compatibility prediction of one condensate with two onshore crude oils from Espirito Santo. The model to predict the compatibility among crude oils and among crude oils and oil products is based on the use of the solubility parameter of the oils. To apply it, the solubility parameter of each crude oil or oil product is measured and the parameter of their blend is calculated. If this value is beneath the asphaltenes flocculation parameter, the blend is incompatible; if it is above, the blend is compatible. In this article, the compatibility predictions were done according to the Solubility Parameter Model to two blends: the condensate C with the crude oil X and with the crude oil Y. The model predictions are that both blends are incompatible at given proportions. To check the predictions, the same two blends were experimentally carried out. It must be emphasized that the compatibility tests were done at atmospheric pressure and at the temperature of 15 deg C. These tests consist in adding the condensate to the crude oil with a titrater and visualizing the asphaltenes precipitation at an optical microscope. The experimental results were equivalent to the values predicted by the model. It is worth mentioning that there were several practical difficulties, as the high volatility of the condensate and the fact that the temperatures to determine the parameters and to carry out the tests were very lower than the operation temperature. Therefore, a security factor was applied on the predictions (less 20%). (author)

  15. Crude oil growth impact on pipelines

    International Nuclear Information System (INIS)

    Devries, O.

    2005-01-01

    This paper provided an outline of crude oil production and supply in Canada. Details of oil sands projects in Athabasca, Cold Lake and Peace River were presented. A chart of oil sands growth by major project was provided. A list of new emerging oil sands crude types was also presented along with details of a synthetic bitumen blending synergy. Maps of Western Canadian crude oil markets were provided, along with details of refinery and market demand by crude type. Various pipeline alternatives to new markets were examined, with reference to Enbridge Pipeline's supply and capacity. Details of the Hardisty to U.S Gulf Coast Pipeline and the Edmonton to Prince Rupert Pipeline and its terminal and dock facilities were presented. It was concluded that pipeline capacity and seasonal factors will influence market demand, while linefill, crude types and the quality of the product will influence operational strategies. tabs., figs

  16. Study on the polarity, solubility, and stacking characteristics of asphaltenes

    KAUST Repository

    Zhang, Long-li; Yang, Guo-hua; Wang, Ji-Qian; Li, Yan; Li, Li; Yang, Chao-he

    2014-01-01

    The structure and transformation of fused aromatic ring system in asphaltenes play an important role in the character of asphaltenes, and in step affect the properties of heavy oils. Polarity, solubility and structural characteristics of asphaltenes

  17. The dynamics of crude oil price differentials

    International Nuclear Information System (INIS)

    Fattouh, Bassam

    2010-01-01

    Crude oil price differentials are modelled as a two-regime threshold autoregressive (TAR) process using the method proposed by Caner and Hansen [Caner, M., Hansen, B.E. Threshold autoregression with a unit root. Econometrica 2001; 69; 1555-1596.]. While standard unit root tests suggest that the prices of crude oil of different varieties move closely together such that their price differential is stationary, the TAR results indicate strong evidence of threshold effects in the adjustment process to the long-run equilibrium. These findings suggest that crude oil prices are linked and thus at the very general level, the oil market is 'one great pool' (Adelman, M.A. International oil agreements. The Energy Journal 1984; 5; 1-9.). However, differences in the dynamics of adjustment suggest that within this one pool, oil markets are not necessarily integrated in every time period and hence the dynamics of crude oil price differentials may not follow a stationary process at all times. Although the development of a liquid futures market around the crude oil benchmarks has helped make some distant markets more unified, arbitrage is not costless or risk-free and temporary breakdowns in the benchmarks can lead to decoupling of crude oil prices. (author)

  18. Bacterial consortia for crude oil spill remediation

    International Nuclear Information System (INIS)

    Chhatre, S.; Purohit, H.; Shanker, R.; Khanna, P.

    1996-01-01

    Oil spills generate enormous public concern and highlight the need for cost effective ad environmentally acceptable mitigation technologies. Physico-chemical methods are not completely effective after a spill. Hence, there is a need for improved and alternative technologies. Bioremediation is the most environmentally sound technology for clean up. This report intends to determine the potential of a bacterial consortium for degradation of Gulf and Bombay High crude oil. A four membered consortium was designed that could degrade 70% of the crude oil. A member of consortium produced a biosurfactant, rhamnolipid, that emulsified crude oil efficiently for effective degradation by the other members of consortium. The wide range of hydrocarbonoclastic capabilities of the selected members of bacterial consortium leads to the degradation of both aromatic and aliphatic fractions of crude oil in 72 hours. (Author)

  19. Effect of biosurfactants on crude oil desorption and mobilization in a soil system

    Energy Technology Data Exchange (ETDEWEB)

    Kuyukina, M.S.; Ivshina, I.B. [Ural Branch of the Russian Academy of Sciences, Perm (Russian Federation). Institute of Ecology and Genetics of Microorganisms; Makarov, S.O.; Litvinenko, L.V. [Perm State University, Perm (Russian Federation); Cunningham, C.J. [University of Edinburgh (United Kingdom). Contaminated Land Assessment and Remediation Research Centre; Philp, J.C. [Napier University, Edinburgh (United Kingdom). School of Life Sciences

    2005-02-01

    Microbially produced biosurfactants were studied to enhance crude oil desorption and mobilization in model soil column systems. The ability of biosurfactants from Rhodococcus ruber to remove the oil from the soil core was 1.4-2.3 times greater than that of a synthetic surfactant of suitable properties, Tween 60. Biosurfactant-enhanced oil mobilization was temperature-related, and it was slower at 15{sup o}C than at 22-28{sup o}C. Mathematical modelling using a one-dimensional filtration model was applied to simulate the process of oil penetration through a soil column in the presence of (bio)surfactants. A strong positive correlation (R{sup 2} = 0.99) was found between surfactant penetration through oil-contaminated soil and oil removal activity. Biosurfactant was less adsorbed to soil components than synthetic surfactant, thus rapidly penetrating through the soil column and effectively removing 65-82% of crude oil. Chemical analysis showed that crude oil removed by biosurfactant contained a lower proportion of high-molecular-weight paraffins and asphaltenes, the most nonbiodegradable compounds, compared to initial oil composition. This result suggests that oil mobilized by biosurfactants could be easily biodegraded by soil bacteria. Rhodococcus biosurfactants can be used for in situ remediation of oil-contaminated soils. (author)

  20. REVIEW OF PVT CORRELATIONS FOR CRUDE OILS

    African Journals Online (AJOL)

    win

    approaches that of the fluids used. During the last 50 years, ... applied to crude oils from other regions (Sutton and Farshad,. 1990). ... S. S. Ikiensikimama, Department of Chemistry Engineering, University of Lagos, Lagos, Nigeria. O. Ogboja ...

  1. Electrodeposition of Asphaltenes. 2. Effect of Resins and Additives

    DEFF Research Database (Denmark)

    Khvostichenko, Daria S; Andersen, Simon Ivar

    2010-01-01

    Electrodeposition of asphaltenes from oil/heptane, asphaltene/heptane, and asphaltene/heptane/additive mixtures has been investigated. Toluene, native petroleum resins, and a synthetic asphaltene dispersant, p-nonylphenol, were used as additives. The addition of these components led to partial...... dissolution of asphaltenes in heptane. The charge of asphaltenic particles was found to be negative in oil/heptane mixtures and positive in asphaltene/heptane mixtures. In asphaltene/heptane/toluene systems, the charge of the deposit varied from positive to neutral to negative, depending upon the method...

  2. Rate of biodegradation of crude oil by microorganisms isolated from ...

    African Journals Online (AJOL)

    The rate of biodegradation of crude oil by micro-organisms isolated from crude oil sludge environment in Eket, Akwa Ibom State of Nigeria was studied. Mineral salt medium supplemented with crude oil was used and three most abundant species isolated from a crude oil sludged soil - Micrococcus varians, Bacillus subtilis ...

  3. When Will Occur the Crude Oil Bubbles?

    International Nuclear Information System (INIS)

    Su, Chi-Wei; Li, Zheng-Zheng; Chang, Hsu-Ling; Lobonţ, Oana-Ramona

    2017-01-01

    In this paper, we apply a recursive unit root test to investigate whether there exist multiple bubbles in crude oil price. The method is best suited for a practical implementation of a time series and delivers a consistent date-stamping strategy for the origination and termination of multiple bubbles. The empirical result indicates that there exist six bubbles during 1986–2016 when the oil price deviate from its intrinsic value based on market fundamentals. Specifically, oil price contains the fundamentals and bubble components. The dates of the bubbles correspond to specific events in the politics and financial markets. The authorities should actively fight speculative bubbles or just observe their evolutions and speculation activities may decrease, which is favour of the stabilisation of the staple commodities including crude oil price. These findings have important economic and policy implications to recognise the cause of bubbles and take corresponding measures to reduce the impact on the real economy cause of the fluctuation of crude oil price. - Highlights: • Investigate multiple bubbles in crude oil price. • Indicate six bubbles deviate from its intrinsic value based on market fundamentals. • The bubbles correspond to specific events in the politics and financial markets. • Reduce the impact on the real economy cause of the fluctuation of crude oil price.

  4. Asphaltenes analysis arising of non conventional oils; Analise de asfaltenos oriundos de petroleos nao convencionais

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Fernanda B. da; Fiorio, Paula G.P.; Guimaraes, Maria Jose O.C.; Seidl, Peter R. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Escola de Quimica

    2012-07-01

    The need to use heavy fractions in an efficient way in the production of nobler fractions has motivated the search for ways of separating the asphaltenes, since these molecules increase the viscosity of the fractions submitted to distillation, contribute to the formation of coke and to poisoning and deactivation of catalysts used in process such as cracking, reform, etc, besides provoking cloggings and blockages caused by its deposition, generating losses on the productivity and increases of the operational costs. This paper evaluates the influence of solvent blends (EQ-NP) in the selective extraction of constituents of three samples from Brazilian heavy crude. For the extraction process was used two solvent blends (N1P1 and N1P2). The solvent blend composed of N1P1 showed a higher selectivity in the extraction of aggregates than N1P2. The extracted fraction was characterized by Hydrogen Nuclear Magnetic Resonance ({sup 1}H-NMR) and revealed that the chemical species extracted from different blends exhibit very small differences. (author)

  5. STUDY OF THE THERMAL CRACKING DURING THE VACUUM DISTILLATION OF ATMOSPHERIC RESIDUE OF CRUDE OIL

    Directory of Open Access Journals (Sweden)

    JAOUAD ELAYANE

    2017-03-01

    Full Text Available This article concerns the study of the thermal cracking as undesirable phenomenon in the vacuum distillation of atmospheric residue of crude oil. In this point, we have sought to identify and characterize the effect of the increase in the temperature of vacuum distillation on the separation and the modification of the constituents of atmospheric residue of crude oil whose origin is Arabian Light. This study has been carried out by several techniques of analysis such as the density (ASTM D4052, distillation (ASTM D1160, determination of heavy metals nickel and vanadium (IFP9422, dosing of Conradson Carbon (ASTM D189, dosing of asphaltenes (ASTM D2549 and dosage of PCI (polycyclic aromatics (ASTM D 5186. The results showed a clear idea on the decomposition of the atmospheric residue and their influence on the performance of the vacuum distillation unit.

  6. Pengaruh Penambahan Kosubstrat pada Biodegradasi Crude Oil

    Directory of Open Access Journals (Sweden)

    Any Juliani

    2016-06-01

    Full Text Available Kegiatan penambangan minyak bumi tidak hanya dilakukan oleh perusahaan-perusahaan besar, tetapi juga oleh masyarakat secara tradisional. Potensi pencemaran lingkungan yang ditimbulkan oleh kegiatan penambangan rakyat ini menjadi lebih tinggi karena pengelolaannya yang tradisional. Salah satu jenis pencemaran yang ditimbulkannya misalnya adalah tanah atau perairan yang tercemar oleh minyak bumi (crude oil pada saat berlangsungnya kegiatan penambangan. Salah satu upaya untuk dapat mengatasinya adalah dengan bioremediasi. Bioremediasi merupakan teknologi pengolahan pencemar dengan memanfaatkan aktivitas mikroba, terutama dari golongan bakteri. Bioremediasi tersebut harus melibatkan bakteri yang memiliki kapasitas metabolic untuk melakukan biodegradasi terhadap crude oil tersebut. Crude oil sendiri pada dasarnya merupakan senyawa hidrokarbon yang merupakan sumber karbon yang kaya bagi mikroba. Namun demikian, biodegradasi crude oil relative lebih sulit dilakukan karena karakteristiknya yang merupakan senyawa dengan berat molekul dan ukuran yang besar. Oleh karena itu penambahan kosubstrat yang lebih sederhana dapat dilakukan untuk membantu biodegradasi terutama pada tahap awal proses. Penelitian ini dilakukan untuk mengetahui pengaruh penambahan kosubstrat dalam hal ini glukosa terhadap biodegradasi crude oil. Penelitian dilakukan dalam media cair dengan bioaugmentasi melalui penambahan inoculum bakteri yang diisolasi dari tanah yang dikondisikan terhadap crude oil dalam beberapa variasi reactor. Indikasi terjadinya biodegradasi diperiksa melalui pengukuran terhadap parameter Total Petroleum Hydrocarbon (TPH dan Total Plate Count (TPC. Hasil penelitian menunjukkan bahwa penambahan kosubstrat glukosa memberikan pengaruh positif terhadap penurunan TPH. Penurunan TPH tertinggi setelah 28 hari adalah sebesar 25,3 % yang diberikan oleh reactor dengan penambahan kosubstrat serta konsentrasi crude oil awal sebesar 8.1 %. Sementara itu reactor tanpa

  7. Effect of the structure of commercial poly(ethylene oxide-b-propylene oxide) demulsifier bases on the demulsification of water-in-crude oil emulsions: elucidation of the demulsification mechanism

    Energy Technology Data Exchange (ETDEWEB)

    Ramalho, Joao Batista V.S. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Centro de Pesquisas; Lechuga, Fernanda C.; Lucas, Elizabete F., E-mail: elucas@ima.ufrj.b [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Inst. de Macromoleculas Profa. Eloisa Mano

    2010-07-01

    Water-in-crude oil emulsions are formed during petroleum production and asphaltenes play an important role in their stabilization. Demulsifiers are added to destabilize such emulsions,however the demulsification mechanism is not completely known. In this paper, the performances of commercial poly(ethylene oxide-b-propylene oxide) demulsifiers were studied using synthetic water-in-oil emulsions and model-systems (asphaltenes in organic solvent). No change in the asphaltene aggregate size induced by the demulsifier was observed. The demulsification performance decreased as the asphaltene aggregate size increased, so it can be suggested that the demulsification mechanism is correlated to the voids between the aggregates adsorbed on the water droplets surface. (author)

  8. Effect of the structure of commercial poly(ethylene oxide-b-propylene oxide) demulsifier bases on the demulsification of water-in-crude oil emulsions: elucidation of the demulsification mechanism

    International Nuclear Information System (INIS)

    Ramalho, Joao Batista V.S.; Lechuga, Fernanda C.; Lucas, Elizabete F.

    2010-01-01

    Water-in-crude oil emulsions are formed during petroleum production and asphaltenes play an important role in their stabilization. Demulsifiers are added to destabilize such emulsions,however the demulsification mechanism is not completely known. In this paper, the performances of commercial poly(ethylene oxide-b-propylene oxide) demulsifiers were studied using synthetic water-in-oil emulsions and model-systems (asphaltenes in organic solvent). No change in the asphaltene aggregate size induced by the demulsifier was observed. The demulsification performance decreased as the asphaltene aggregate size increased, so it can be suggested that the demulsification mechanism is correlated to the voids between the aggregates adsorbed on the water droplets surface. (author)

  9. Effect of the structure of commercial poly(ethylene oxide-b-propylene oxide demulsifier bases on the demulsification of water-in-crude oil emulsions: elucidation of the demulsification mechanism

    Directory of Open Access Journals (Sweden)

    João Batista V. S. Ramalho

    2010-01-01

    Full Text Available Water-in-crude oil emulsions are formed during petroleum production and asphaltenes play an important role in their stabilization. Demulsifiers are added to destabilize such emulsions,however the demulsification mechanism is not completely known. In this paper, the performances of commercial poly(ethylene oxide-b-propylene oxide demulsifiers were studied using synthetic water-in-oil emulsions and model-systems (asphaltenes in organic solvent. No change in the asphaltene aggregate size induced by the demulsifier was observed. The demulsification performance decreased as the asphaltene aggregate size increased, so it can be suggested that the demulsification mechanism is correlated to the voids between the aggregates adsorbed on the water droplets surface.

  10. Comparative toxicology of four crude oils

    Energy Technology Data Exchange (ETDEWEB)

    Clarke, L.M.; Hodson, P.V. [Queen' s Univ., Kingston, ON (Canada). Dept. of Biology; Brown, R.S. [Queen' s Univ., Kingston, ON (Canada). Dept. of Chemistry

    2003-07-01

    Fish that are chronically exposed to polycyclic aromatic hydrocarbons (PAHs) exhibit dioxin-like toxicity characterized by blue sac disease and the induction of cytochrome P4501A (CYP1A). This study compared the relative toxicity of four crude oils (Scotian Shelf, MESA, the synthetic Alberta Sweet Mixed Blend, and Alaskan North Slope Crude Oil), in causing the disease in rainbow trout embryos living in simulated spawning beds with hydrocarbon-contaminated gravel. Each oil had different chemical characteristics and PAH concentrations. The study confirmed the assumption that the Alberta Sweet Mixed Blend would be the most toxic due to its high PAH concentration. The results suggest that the main cause of toxicity in crude oil is due to the presence, concentration, and conformation of specific PAHs.

  11. Crude oil spot market pricing: Pearsonian analysis of crude oil spot market prices

    International Nuclear Information System (INIS)

    Akinnusi, Ayo

    1994-01-01

    This paper presents a brief overview of crude oil pricing before describing a study of sets of 1991 spot market prices, and examining Pearson's model. Empirical distribution characteristics for 14 crude oils are tabulated, and skewness-kurtosis relationship and implication are considered. (UK)

  12. Multi-scale simulation and experimental studies of asphaltene aggregation and deposition in capillary flow

    NARCIS (Netherlands)

    Boek, E.S.; Wilson, A.D.; Padding, J.T.; Headen, T.F.; Crawshaw, J.P.

    2010-01-01

    Asphaltenes are known as the "cholesterol" of crude oil. They form nanoaggregates, precipitate, adhere to surfaces, block rock pores, and may alter the wetting characteristics of mineral surfaces within the reservoir, hindering oil recovery efficiency. Despite a significant research effort, the

  13. Assessment of Antioxidant Indices after incorporating Crude Oil ...

    African Journals Online (AJOL)

    ADOWIE PERE

    Exposure to crude oil pollution leads to the formation ... vitamin/mineral mixture (5 %). The food ..... hepatic antioxidant enzymes against cadmium induced liver ... Interaction of crude oil with alpha-tocopherol: ... Essential oil from Monodora.

  14. Trace metals in heavy crude oils and tar sand bitumens

    Energy Technology Data Exchange (ETDEWEB)

    Reynolds, J.G.

    1990-11-28

    Fe, Ni, and V are considered trace impurities in heavy crude oils and tar sand bitumens. In order to understand the importance of these metals, we have examined several properties: (1) bulk metals levels, (2) distribution in separated fractions, (3) size behavior in feeds and during processing, (4) speciation as a function of size, and (5) correlations with rheological properties. Some of the results of these studies show: (1) V and Ni have roughly bimodal size distributions, (2) groupings were seen based on location, size distribution, and Ni/V ratio of the sample, (3) Fe profiles are distinctively different, having a unimodal distribution with a maximum at relatively large molecular size, (4) Fe concentrations in the tar sand bitumens suggest possible fines solubilization in some cases, (5) SARA separated fractions show possible correlations of metals with asphaltene properties suggesting secondary and tertiary structure interactions, and (6) ICP-MS examination for soluble ultra-trace metal impurities show the possibility of unexpected elements such as U, Th, Mo, and others at concentrations in the ppB to ppM range. 39 refs., 13 figs., 5 tabs.

  15. Biogeochemistry of anaerobic crude oil biodegradation

    Science.gov (United States)

    Head, Ian; Gray, Neil; Aitken, Caroline; Sherry, Angela; Jones, Martin; Larter, Stephen

    2010-05-01

    Anaerobic degradation of crude oil and petroleum hydrocarbons is widely recognized as a globally significant process both in the formation of the world's vast heavy oil deposits and for the dissipation of hydrocarbon pollution in anoxic contaminated environments. Comparative analysis of crude oil biodegradation under methanogenic and sulfate-reducing conditions has revealed differences not only in the patterns of compound class removal but also in the microbial communities responsible. Under methanogenic conditions syntrophic associations dominated by bacteria from the Syntropheaceae are prevalent and these are likely key players in the initial anaerobic degradation of crude oil alkanes to intermediates such as hydrogen and acetate. Syntrophic acetate oxidation plays an important role in these systems and often results in methanogenesis dominated by CO2 reduction by members of the Methanomicrobiales. By contrast the bacterial communities from sulfate-reducing crude oil-degrading systems were more diverse and no single taxon dominated the oil-degrading sulfate-reducing systems. All five proteobacterial subdivisions were represented with Delta- and Gammaproteobacteria being detected most consistently. In sediments which were pasteurized hydrocarbon degradation continued at a relatively low rate. Nevertheless, alkylsuccinates characteristic of anaerobic hydrocarbon degradation accumulated to high concentrations. This suggested that the sediments harbour heat resistant, possibly spore-forming alkane degrading sulfate-reducers. This is particularly interesting since it has been proposed recently, that spore-forming sulfate-reducing bacteria found in cold arctic sediments may have originated from seepage of geofluids from deep subsurface hydrocarbon reservoirs.

  16. Waxy crude oil flow restart ability

    Energy Technology Data Exchange (ETDEWEB)

    Sierra, Andre Gaona; Varges, Priscilla Ribeiro; Mendes, Paulo Roberto de Souza [Dept. of Mechanical Engineering. Pontificia Universidade Catolica do Rio de Janeiro, RJ (Brazil)], e-mails: prvarges@puc-rio.br, pmendes@puc-rio.br; Ziglio, Claudio [PETROBRAS S.A, R.J., Rio de Janeiro, RJ (Brazil)], e-mail: ziglio@petrobras.com.br

    2010-07-01

    Under the hot reservoir conditions, waxy crudes behave like Newtonian fluids but once they experience very cold temperatures on the sea floor, the heavy paraffin's begin to precipitate from the solution impacting non- Newtonian flow behavior to the crude (Chang 2000, Lee 2009, Davidson 2004) and begin to deposit on the pipe wall leave blocked of pipeline. This gel cannot be broken with the original steady state flow operating pressure applied before gelation (Chang 1998). Restarting waxy crude oil flows in pipelines is a difficult issue because of the complex rheological behavior of the gelled oil. Indeed, below the WAT, the gelled oil exhibits viscoplastic, thixotropic, temperature-dependent, and compressible properties due to the interlocking gel-like structure formed by the crystallized paraffin compounds and the thermal shrinkage of the oil. The main objective of this work is to determine the minimal pressure to restart the flow, and the relationship between the fluid rheology , pipe geometry and the restart pressure of the flow. Experiments will be performed to investigate the displacement of carbopol aqueous solutions (viscoplastic fluid without thixotropic effects) by Newtonian oil flowing through a strait pipe to validate the experimental apparatus. Therefore, tests will be made with different fluids, like Laponite and waxy crude oils. (author)

  17. Forecasting volatility of crude oil markets

    International Nuclear Information System (INIS)

    Kang, Sang Hoon; Kang, Sang-Mok; Yoon, Seong-Min

    2009-01-01

    This article investigates the efficacy of a volatility model for three crude oil markets - Brent, Dubai, and West Texas Intermediate (WTI) - with regard to its ability to forecast and identify volatility stylized facts, in particular volatility persistence or long memory. In this context, we assess persistence in the volatility of the three crude oil prices using conditional volatility models. The CGARCH and FIGARCH models are better equipped to capture persistence than are the GARCH and IGARCH models. The CGARCH and FIGARCH models also provide superior performance in out-of-sample volatility forecasts. We conclude that the CGARCH and FIGARCH models are useful for modeling and forecasting persistence in the volatility of crude oil prices. (author)

  18. Forecasting volatility of crude oil markets

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Sang Hoon [Department of Business Administration, Gyeongsang National University, Jinju, 660-701 (Korea); Kang, Sang-Mok; Yoon, Seong-Min [Department of Economics, Pusan National University, Busan, 609-735 (Korea)

    2009-01-15

    This article investigates the efficacy of a volatility model for three crude oil markets - Brent, Dubai, and West Texas Intermediate (WTI) - with regard to its ability to forecast and identify volatility stylized facts, in particular volatility persistence or long memory. In this context, we assess persistence in the volatility of the three crude oil prices using conditional volatility models. The CGARCH and FIGARCH models are better equipped to capture persistence than are the GARCH and IGARCH models. The CGARCH and FIGARCH models also provide superior performance in out-of-sample volatility forecasts. We conclude that the CGARCH and FIGARCH models are useful for modeling and forecasting persistence in the volatility of crude oil prices. (author)

  19. Geotechnical properties of crude oil contaminated sand

    International Nuclear Information System (INIS)

    Puri, V.K.; Das, B.M.; Cook, E.E.; Shin, E.C.

    1994-01-01

    Contamination of soil due to an oil spill influences its subsequent engineering behavior. An investigation was conducted to study the effect of crude oil contamination on compaction characteristics, shear strength, one-dimensional compression, and coefficient of permeability. Water permeability was also determined by using commercial grade motor oils as contaminants. The test results indicate that the compaction characteristics are influenced by oil contamination. The angle of internal friction of sand (based on total stress condition) decreases due to presence of oil within the pore spaces in sand. One dimensional compression characteristics of sand are significantly influenced by oil contamination resulting in a decrease in the value of constrained modulus with increase in the degree of oil contamination compared to the case of dry sand. Water permeability was observed to be a function of the initial viscosity and the degree of saturation due to the contaminating oil

  20. Crude oil hedging: benchmarking price protection strategies

    International Nuclear Information System (INIS)

    Krapels, Edward N.; Pratt, Michael

    1998-01-01

    This report presents a review of hedging (protection against a loss) strategies in the crude oil futures and options markets. The introductory section of the report gives details of hedging instruments, and the purposes of hedging crude oil. Hedging strategies including pure futures strategies, pure options strategies, options combination strategies, exotic (Asian) options strategies, and insurance instruments are described. The West Texas intermediate (WTI) market depth, liquidity and hedging effectiveness are examined, and winners and losers, and energy consumers are considered. The appendix gives tables and charts summarising the outcomes of futures and options strategies under different market conditions and expectations. (UK)

  1. The future for heavy crude oil

    International Nuclear Information System (INIS)

    Horsnell, P.

    1995-01-01

    The expectation, still held in 1993, that the light oil-heavy crude oil differential would go on increasing in favour of light oil has not been fulfilled. Current perceptions are that heavy oil will continue to be relatively strong and there is no inevitable upward trend in light-heavy crude differentials. Non-OPEC production has grown significantly lighter overall in recent years and is likely to continue so for several more years. This is due to expanded light oil production in the North Sea, Latin America and the Far East, and contractions in heavy oil production in Russia and the USA. OPEC production has also become lighter with, in particular, an expansion in light oil and contraction in heavy grades from Saudi Arabia. At the same time, the nature of the demand from refineries has changed with the introduction of new units designed to process the residium from heavy oil distillation. Thus the supply of light oil has expanded while demand for it has contracted with the reverse being true for heavy oil. (2 figures, 1 table) (UK)

  2. 10 CFR 212.78 - Tertiary incentive crude oil.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 3 2010-01-01 2010-01-01 false Tertiary incentive crude oil. 212.78 Section 212.78 Energy DEPARTMENT OF ENERGY OIL MANDATORY PETROLEUM PRICE REGULATIONS Producers of Crude Oil § 212.78 Tertiary incentive crude oil. Annual prepaid expenses report. By January 31 of each year after 1980, the project...

  3. Screening of inhibitors for remediation of asphaltene deposits: Experimental and modeling study

    Directory of Open Access Journals (Sweden)

    Mehdi Madhi

    2018-06-01

    Full Text Available One of the most severe problems during production from heavy crude oil reservoirs is the formation of asphaltene precipitation and as a result deposition in the tubing, surface facilities and near wellbore region which causes oil production and permeability reduction in addition to rock wettability alteration in the reservoir. So one of the economical ways to prevent such incidents is using the chemicals which are called asphaltene inhibitor.In this study, the influence of three commercial inhibitors, namely; Cetyl Terimethyl Ammonium Bromide (CTAB, Sodium Dodecyl Sulfate (SDS, Triton X-100 and four non-commercial (Benzene, Benzoic Acid, Salicylic Acid, Naphthalene inhibitors on two Iranian crude oils were investigated. This study extends previous works and contributes toward the better understanding of interactions between asphaltene and inhibitor. Effect of functional groups and structure of inhibitors on asphaltene precipitation were studied and it seems clear that the nature and polarity of asphaltene (structure and amount of impurities presented has a significant impact on the selection of inhibitors. asphaltene dispersant tests and Core flood tests were designed for evaluation of inhibitors in static and dynamic conditions. The results revealed distinguished mechanisms for asphaltene solubilization/dispersion (such as hydrogen bonding, π–π interaction and acid-base interaction and influence of additional side group (OH on inhibition power of inhibitor.During the experiments, it was found that increasing inhibitor concentration may lead to the self-assembly of inhibitor and declining of asphaltene stabilization. So, finding optimum concentration of inhibitor with high efficiency and available at a reasonable price is very important. The results suggest that 600 ppm of CTAB and 300 ppm of SDS were approximately optimum concentrations for the studied crude oils. One of the most important findings that differ from previous studies is the

  4. Refining crude oils and gasolines, etc

    Energy Technology Data Exchange (ETDEWEB)

    1931-11-23

    A process of refining crude oils and gasolines distilled from shale and the like is described, consisting of submitting them to a prewash with soda, an oxidation preferably with hypochlorite solution, a hydrogenation with nascent hydrogen, and finally rectification and neutralization.

  5. Relation of sulfur with hydrocarbons in Brazilian heavy and extra-heavy crude oil; Relacao do enxofre com os hidrocarbonetos em petroleos pesados e extra pesados brasileiros

    Energy Technology Data Exchange (ETDEWEB)

    Iorio, Sonia Maria Badaro Mangueira; Guimaraes, Regina Celia Lourenco; Silva, Maria do Socorro A. Justo da [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil); Costa, Alexander Vinicius Moraes da [Fundacao Gorceix, Ouro Preto, MG (Brazil)

    2008-07-01

    As the occurrence of heavy and extra-heavy oils increases sensitively, their participation in the refineries feeding also becomes greater. Heavy oils usually have lower price than a light one, because they produce lower quality derivatives and it's more difficult to meet the specifications. Crude oils are a complex mixture, mostly compounded by carbon and hydrogen and also by impurities like sulfur, nitrogen, oxygen and metals. Sulfur is the third most abundant component of crude oils, following carbon and hydrogen. In general there is a strong positive correlation between the concentrations of polar compounds (aromatics, resins and asphaltenes), and the sulfur content. This work presents graphically sulfur content and polar compounds concentrations for Brazilian and foreign heavy and extra-heavy oils (< 20 deg API). The results of the data analysis indicate that Brazilian crude oils behave differently from foreign heavy and extra-heavy oils. (author)

  6. Application of Markov Model in Crude Oil Price Forecasting

    Directory of Open Access Journals (Sweden)

    Nuhu Isah

    2017-08-01

    Full Text Available Crude oil is an important energy commodity to mankind. Several causes have made crude oil prices to be volatile. The fluctuation of crude oil prices has affected many related sectors and stock market indices. Hence, forecasting the crude oil prices is essential to avoid the future prices of the non-renewable natural resources to rise. In this study, daily crude oil prices data was obtained from WTI dated 2 January to 29 May 2015. We used Markov Model (MM approach in forecasting the crude oil prices. In this study, the analyses were done using EViews and Maple software where the potential of this software in forecasting daily crude oil prices time series data was explored. Based on the study, we concluded that MM model is able to produce accurate forecast based on a description of history patterns in crude oil prices.

  7. Characterization of CRUDE OILS and petroleum products: (i) elution ...

    African Journals Online (AJOL)

    Characterization of CRUDE OILS and petroleum products: (i) elution liquid chromatographic separation and gas chromatographic analysis of crude oils and petroleum products. E.O. Odebunmi, E.A. Ogunsakin, P.E.P. Ilukhor ...

  8. Efficient way of importing crude oil from oil producing countries - A review on diversification policy of crude oil import

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Dal Sok [Korea Energy Economics Institute, Euiwang (Korea)

    1999-03-01

    Since the second oil crisis, the government has operated the import diversification support program to reduce the risk of crude oil import from Middle-East region and to raise the ability of dealing with the risk. This study tried to seek policy trends in future through reviewing the market environment related to the crude oil import diversification policy and the goal, instrument and effect of the policy. The supply and demand of crude oil and the price are influenced by market system in the world oil market and there are various types of crude oil trading available to both sellers and buyers. There is a probability that the suspension of supply in a certain area could be led to the price issue rather than the physical use of crude oil. In addition, the advantage of price with long-term contract of crude oil was abolished since the price of crude oil imported by term contract has been linked to spot prices. As a result, it is shown that the potential benefit from crude oil import diversification policy is reduced although political and social insecurity still exists in Middle-East region. Therefore, it is desirable to maintain the existing support program until the amount of stored oil reaches the optimum level and to help private enterprises determine the import considering economical efficiency and risk. (author). 36 refs., 5 figs., 23 tabs.

  9. Heavy oils processing materials requirements crude processing

    Energy Technology Data Exchange (ETDEWEB)

    Sloley, Andrew W. [CH2M Hill, Englewood, CO (United States)

    2012-07-01

    Over time, recommended best practices for crude unit materials selection have evolved to accommodate new operating requirements, feed qualities, and product qualities. The shift to heavier oil processing is one of the major changes in crude feed quality occurring over the last 20 years. The three major types of crude unit corrosion include sulfidation attack, naphthenic acid attack, and corrosion resulting from hydrolyzable chlorides. Heavy oils processing makes all three areas worse. Heavy oils have higher sulfur content; higher naphthenic acid content; and are more difficult to desalt, leading to higher chloride corrosion rates. Materials selection involves two major criteria, meeting required safety standards, and optimizing economics of the overall plant. Proper materials selection is only one component of a plant integrity approach. Materials selection cannot eliminate all corrosion. Proper materials selection requires appropriate support from other elements of an integrity protection program. The elements of integrity preservation include: materials selection (type and corrosion allowance); management limits on operating conditions allowed; feed quality control; chemical additives for corrosion reduction; and preventive maintenance and inspection (PMI). The following discussion must be taken in the context of the application of required supporting work in all the other areas. Within that context, specific materials recommendations are made to minimize corrosion due to the most common causes in the crude unit. (author)

  10. Volatility persistence in crude oil markets

    International Nuclear Information System (INIS)

    Charles, Amélie; Darné, Olivier

    2014-01-01

    Financial market participants and policy-makers can benefit from a better understanding of how shocks can affect volatility over time. This study assesses the impact of structural changes and outliers on volatility persistence of three crude oil markets – Brent, West Texas Intermediate (WTI) and Organization of Petroleum Exporting Countries (OPEC) – between January 2, 1985 and June 17, 2011. We identify outliers using a new semi-parametric test based on conditional heteroscedasticity models. These large shocks can be associated with particular event patterns, such as the invasion of Kuwait by Iraq, the Operation Desert Storm, the Operation Desert Fox, and the Global Financial Crisis as well as OPEC announcements on production reduction or US announcements on crude inventories. We show that outliers can bias (i) the estimates of the parameters of the equation governing volatility dynamics; (ii) the regularity and non-negativity conditions of GARCH-type models (GARCH, IGARCH, FIGARCH and HYGARCH); and (iii) the detection of structural breaks in volatility, and thus the estimation of the persistence of the volatility. Therefore, taking into account the outliers on the volatility modelling process may improve the understanding of volatility in crude oil markets. - Highlights: • We study the impact of outliers on volatility persistence of crude oil markets. • We identify outliers and patches of outliers due to specific events. • We show that outliers can bias (i) the estimates of the parameters of GARCH models, (ii) the regularity and non-negativity conditions of GARCH-type models, (iii) the detection of structural breaks in volatility of crude oil markets

  11. Bioremediation of crude oil contaminated tea plantation soil using ...

    African Journals Online (AJOL)

    Crude oil contamination of soil is a major concern for tea industry in Assam, India. Crude oil is a persistent organic contaminant which alters soil physical and biochemical characteristics and makes tea plants more susceptible against crude oil contamination. Therefore, two native bacterial strains designated as AS 03 and ...

  12. The Use of Biobased Surfactant Obtained by Enzymatic Syntheses for Wax Deposition Inhibition and Drag Reduction in Crude Oil Pipelines

    Directory of Open Access Journals (Sweden)

    Zhihua Wang

    2016-04-01

    Full Text Available Crude oil plays an important role in providing the energy supply of the world, and pipelines have long been recognized as the safest and most efficient means of transporting oil and its products. However, the transportation process also faces the challenges of asphaltene-paraffin structural interactions, pipeline pressure losses and energy consumption. In order to determine the role of drag-reducing surfactant additives in the transportation of crude oils, experiments of wax deposition inhibition and drag reduction of different oil in pipelines with a biobased surfactant obtained by enzymatic syntheses were carried out. The results indicated that heavy oil transportation in the pipeline is remarkably enhanced by creating stable oil-in-water (O/W emulsion with the surfactant additive. The wax appearance temperature (WAT and pour point were modified, and the formation of a space-filling network of interlocking wax crystals was prevented at low temperature by adding a small concentration of the surfactant additive. A maximum viscosity reduction of 70% and a drag reduction of 40% for light crude oil flows in pipelines were obtained with the surfactant additive at a concentration of 100 mg/L. Furthermore, a successful field application of the drag-reducing surfactant in a light crude oil pipeline in Daqing Oilfield was demonstrated. Hence, the use of biobased surfactant obtained by enzymatic syntheses in oil transportation is a potential method to address the current challenges, which could result in a significant energy savings and a considerable reduction of the operating cost.

  13. Natural gas and crude oil

    International Nuclear Information System (INIS)

    Valais, M.R.

    1991-01-01

    Two main development could gradually modify these traditional features of natural gas markets and prices. First, environmental pressures and the tightening of emission standards and of the quality specifications for fuels should work in favor of natural gas. Second the increasing distance of resources in relation to the major consuming zones should bring about a considerable development of international natural gas trade. International expansion should mark the development of the gas industry in the coming decades. This evolution will give natural gas an importance and a role appreciably closer to those of oil on the world energy scene. But it is obvious that such a development can come about only at the cost of considerable investments for which the economic viability is and will remain dependent on the level of the prices of natural gas as the inlet to its consuming markets. This paper attempts to answer the questions: Will these markets accept a new scale of value for gas in relation to other fossil fuels, including oil, which will take into account new environmental constraints and which will be able to fulfill the formidable financial needs of the gas industry in the coming decades?

  14. Prediction of the Gas Injection Effect on the Asphaltene Phase Envelope

    Directory of Open Access Journals (Sweden)

    Bahrami Peyman

    2015-11-01

    Full Text Available Asphaltene instability may occur when pressure, temperature and compositional variations affect the reservoir oil. Permeability reduction, wettability alteration, and plugging of wells and flow lines are the consequences of this phenomenon. Therefore, it is crucial to investigate the asphaltene behavior in different thermodynamic conditions by knowing the Asphaltene Precipitation Envelope (APE in a preventive way rather than the costly clean-up procedures. The selected reservoir oil has faced a remarkable decline in production due to several years of extraction, and Enhanced Oil Recovery (EOR has been considered as a solution. Therefore, in this paper, a comprehensive study was carried out to predict the effects of different injected gases on asphaltene onset and to prevent future asphaltene precipitation based on the laboratory data. The Advanced Redlich-Kwong-Soave (RKSA equation of state was considered to develop APE using Multiflash (Infochem Co.. For the selected reservoir oil, with temperature reduction at low temperatures, asphaltene precipitation weakened and made the onset pressure decrease, so this behavior is different from the results obtained in other published reports. On the basis of this model, several sensitivity analyses were performed with different gases (i.e., methane, CO2, N2 and associated gases to compare the risk of each gas for future EOR strategies. APE tend to expand as the amount of injected gases increases, except for CO2 gas injection, that showed another unconventional behavior for this crude oil. It was observed that for CO2 gas injection below a certain temperature, asphaltene stability increased, which can be considered as a good inhibitor of asphaltene precipitation.

  15. How much crude oil can zooplankton ingest? Estimating the quantity of dispersed crude oil defecated by planktonic copepods

    DEFF Research Database (Denmark)

    Almeda, Rodrigo; Connelly, Tara L.; Buskey, Edward J.

    2016-01-01

    % of the analyzed fecal pellets from three species of copepods and a natural copepod assemblage exposed for 48 h to physically or chemically dispersed light crude oil contained crude oil droplets. Crude oil droplets inside fecal pellets were smaller (median diameter: 2.4-3.5 mu m) than droplets in the physically...

  16. Mesoscale Simulation and Machine Learning of Asphaltene Aggregation Phase Behavior and Molecular Assembly Landscapes.

    Science.gov (United States)

    Wang, Jiang; Gayatri, Mohit A; Ferguson, Andrew L

    2017-05-11

    Asphaltenes constitute the heaviest fraction of the aromatic group in crude oil. Aggregation and precipitation of asphaltenes during petroleum processing costs the petroleum industry billions of dollars each year due to downtime and production inefficiencies. Asphaltene aggregation proceeds via a hierarchical self-assembly process that is well-described by the Yen-Mullins model. Nevertheless, the microscopic details of the emergent cluster morphologies and their relative stability under different processing conditions remain poorly understood. We perform coarse-grained molecular dynamics simulations of a prototypical asphaltene molecule to establish a phase diagram mapping the self-assembled morphologies as a function of temperature, pressure, and n-heptane:toluene solvent ratio informing how to control asphaltene aggregation by regulating external processing conditions. We then combine our simulations with graph matching and nonlinear manifold learning to determine low-dimensional free energy surfaces governing asphaltene self-assembly. In doing so, we introduce a variant of diffusion maps designed to handle data sets with large local density variations, and report the first application of many-body diffusion maps to molecular self-assembly to recover a pseudo-1D free energy landscape. Increasing pressure only weakly affects the landscape, serving only to destabilize the largest aggregates. Increasing temperature and toluene solvent fraction stabilizes small cluster sizes and loose bonding arrangements. Although the underlying molecular mechanisms differ, the strikingly similar effect of these variables on the free energy landscape suggests that toluene acts upon asphaltene self-assembly as an effective temperature.

  17. Tanker spills Norwegian crude oil off Shetlands

    International Nuclear Information System (INIS)

    Anon.

    1993-01-01

    This paper reports that crude oil was spilling last week from the U.S. owned Braer tanker after the 89,000 dwt vessel ran aground on the south end of Scotland's Shetland Islands. Workers were trying to assess the extent of damage to the tanker, shoreline, and wildlife after the January 5 accident. Braer's cargo amounted to 607,000 bbl of Norwegian oil bound for Canada. Braer loaded its cargo and sailed January 3 from Den norske stats oljeselskap AS's Mongstad, Norway, terminal with crude from Gullfaks field in the Norwegian North Sea. The $11 million shipment was destined for Ultramar Canada Inc.'s 125,000 b/d refinery at St. Romuald, Que

  18. Crude oil prices: Speculation versus fundamentals

    Science.gov (United States)

    Kolodziej, Marek Krzysztof

    Beginning in 2004, the price of crude oil fluctuates rapidly over a wide range. Large and rapid price increases have recessionary consequences and dampen long-term infrastructural investment. I investigate whether price changes are driven by market fundamentals or speculation. With regard to market fundamentals, I revisit econometric evidence for the importance of demand shocks, as proxied by dry maritime cargo rates, on oil prices. When I eliminate transportation costs from both sides of the equation, disaggregate OPEC and non-OPEC production, and allow for more than one cointegrating relation, I find that previous specifications are inconsistent with arguments that demand shocks play an important role. Instead, results confirm the importance of OPEC supply shocks. I investigate two channels by which speculation may affect oil prices; the direct effect of trader behavior and changes in oil from a commodity to a financial asset. With regard to trader behavior, I find evidence that trader positions are required to explain the spread between spot and futures prices of crude oil on the New York Mercantile Exchange. The inclusion of trader positions clarifies the process of equilibrium error correction, such that there is bidirectional causality between prices and trader positions. This creates the possibility of speculative bubbles. With regard to oil as a commodity and/or financial asset, I use a Kalman Filter model to estimate the time-varying partial correlation between returns to investments in equity and oil markets. This correlation changes from negative to positive at the onset of the 2008 financial crisis. The low interest rates used to rescue the economy depress convenience yields, which reduces the benefits of holding oil as a commodity. Instead, oil becomes a financial asset (on net) as the oil market changed from contango to backwardation. Contradicting simple political narratives, my research suggests that both market fundamentals and speculation drive

  19. Characterization of the rheological behavior of heavy crude oils for the optimization of their transport; Caracterisation du comportement rheologique des bruts lourds en vue de l'optimisation de leur transport

    Energy Technology Data Exchange (ETDEWEB)

    Coustet Pierre, C.

    2003-10-01

    Despite their huge reserves, production of heavy crude oils remains weak, partially because of the high viscosity. This work aims to understand the origin of this viscosity in a view of diminishing In this context, we performed structural (SAXS) and rheological studies (under shearing and oscillatory regime) in order to link macroscopic and microscopic properties of heavy oils. investigated the effect of asphaltenes and resins which are the two most polar and the high molecular mass components of heavy oils. Most of the literature work performed measures organic solvents which are considered as model solvents in a first assumption. These media haw structure too simple compared to oils. That is why we decided to complete this work by experiments in the crude. We shed some light on asphaltenes described as colloidal particles with fractal dimension of 2. Their overlapping, due to numerous polar and hydrogen bonds, responsible for the high viscosity. The contribution of asphaltenes on viscosity is lowered by resins who are able to dissociate aggregates and to reduce the interactions, so to diminish the overlapping The kinetics of formation of bonds involved in asphaltenes overlapping are strongly slower at low temperatures, which implies a shear thinning behavior under sufficiently high shearing. This allow us to describe the crude as a transient network of fractal aggregates. (author)

  20. Pilot scale refinning of crude soybean oil | Mensah | Journal of ...

    African Journals Online (AJOL)

    Pilot scale refinning of crude soybean oil. ... Abstract. A laboratory process for refining soybean has been scaled up to a 145 tonne per annum pilot plant to refine crude soybean oil. ... The quality of the refined oil was found to be within national and codex standard specifications for edible oil from vegetable sources.

  1. Electrical desalting - preparing of the crude oil for further processing

    International Nuclear Information System (INIS)

    Asadi, Nadija; Minovski, Mino; Sokolovski, Aleksandar

    1999-01-01

    Desalting as well as dewatering of the crude oil is important preparing process, which takes place in crude units on the refinery plants. One of the most efficient ways of desalting is use of high voltage electricity. In this work attention is paid on the principals of this process, illustrated with practically gained results from the OKTA Crude Oil Refinery in Macedonia. (Original)

  2. Bioavailability of chemically-dispersed crude oil

    International Nuclear Information System (INIS)

    Harris, B.C.; Bonner, J.S.; McDonald, T.J.; Fuller, C.B.; Page, C.A.; Dimitriou-Christidis, P.; Sterling, M.C.; Autenrieth, R.L.

    2002-01-01

    Oil spills can be treated with surfactant compounds to disperse them. This method enables the hydrophobic compounds to overcome their repulsion for water, enter the water phase and be diluted. Once in the water, the biodegradation fraction of the oil biodegrades over time and the residual fraction is deposited over a large area. One major issue which is not fully understood is whether oil compounds pass through the water phase to free floating cells or directly enter oil-attached microbial cells from the oil particle. In this study, crude oil was placed in a swirling flask with Corpus Christi Bay water and was then chemically dispersed with Corexit 9500. The biodegradation was then monitored and assessed. First order rate coefficients were determined based on the disappearance of specific compounds. The rate coefficients for total target PAHs were consistent for all tests. Napthalene, phenanthrene, dibenzothiophene and their alkylated homologs were among the target compounds. The trend was also observed for total target analytes and for total target saturates. The results indicate that the biodegradation rate coefficient was not dependent on the bulk concentration of oil in the water column. It was concluded that biodegradation rates was controlled by partitioning of the compounds between the two phases, and other factors such as particle size distribution and the capability of the microbial culture, temperature and nutrients. 13 refs., 1 tab., 6 figs

  3. Subordinated Levy Processes and Applications to Crude Oil Options

    OpenAIRE

    Noureddine Krichene

    2005-01-01

    One approach to oil markets is to treat oil as an asset, besides its role as a commodity. Speculative and nonspeculative activity by investors in the derivatives markets could be responsible for a sizable increase in oil prices. This paper recognizes both the consumption and investment aspects of crude oil and proposes Levy processes for modeling uncertainty and options pricing. Calibration to crude oil futures' options shows high volatility of oil futures prices, fat-tailed, and right-skewed...

  4. DOE/DOT Crude Oil Characterization Research Study, Task 2 Test Report on Evaluating Crude Oil Sampling and Analysis Methods

    Energy Technology Data Exchange (ETDEWEB)

    Lord, David [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Allen, Ray [Allen Energy Services, Inc., Longview, TX (United States); Rudeen, David [GRAM, Inc., Albuquerque, NM (United States)

    2017-11-01

    The Crude Oil Characterization Research Study is designed to evaluate whether crude oils currently transported in North America, including those produced from "tight" formations, exhibit physical or chemical properties that are distinct from conventional crudes, and how these properties associate with combustion hazards with may be realized during transportation and handling.

  5. Improving oil biodegradability of aliphatic crude oil fraction by ...

    African Journals Online (AJOL)

    The percentage of biodegrading ability of B. subtilis and the mixture of these bacteria to n-alkanes and isoprenoids (pristine, phytane) were measured and compared with control. Crude oil is used as a sole source of energy and the incubation period was 24 days, the hydrocarbons loss are detected each 6 day interval using ...

  6. Transient leak detection in crude oil pipelines

    Energy Technology Data Exchange (ETDEWEB)

    Beushausen, R.; Tornow, S.; Borchers, H. [Nord-West Oelleitung, Wilhelmshaven (Germany); Murphy, K.; Zhang, J. [Atmos International Ltd., Manchester (United Kingdom)

    2004-07-01

    Nord-West Oelleitung (NWO) operates 2 crude oil pipelines from Wilhemshaven to Koln and Hamburg respectively. German regulations for transporting flammable substances stipulate that 2 independent continuously working procedures be used to detect leaks. Leak detection pigs are used routinely to complement the surveillance system. This paper described the specific issues of transient leak detection in crude oil pipelines. It was noted that traditional methods have failed to detect leaks that occur immediately after pumps are turned on or off because the pressure wave generated by the transient dominates the pressure wave that results from the leak. Frequent operational changes in a pipeline are often accompanied by an increased number of false alarms and failure to detect leaks due to unsteady operations. NWO therefore decided to have the Atmos statistical pipeline leak detection (SPLD) system installed on their pipelines. The key to the SPLD system is the sequential probability ratio test. Comprehensive data validation is performed following reception of pipeline data from the supervisory control and data acquisition (SCADA) system. The validated data is then used to calculate the corrected flow imbalance, which is fed into the SPRT to determine if there is an increase in the flow imbalance. Pattern recognition is then used to distinguish a leak from operational changes. The SPLD is unique because it uses 3 computational pipeline monitoring methods simultaneously, namely modified volume balance, statistical analysis, and pressure and flow monitoring. The successful installation and testing of the SPLD in 2 crude oil pipelines was described along with the main difficulties associated with transient leaks. Field results were presented for both steady-state and transient conditions. 5 refs., 2 tabs., 16 figs.

  7. Vulnerability maps for Druzba crude oil pipeline

    International Nuclear Information System (INIS)

    Hladik, P.; Hosnedl, P.; Buresova, H.; Corbet, J.

    2012-01-01

    Maps of risk for individual environmental aspects within the protection zone of the Czech part of the Druzba crude oil pipeline (505.7 km) were developed based on a modified 'H and V index' method. Risk data were added into a GIS of the Druzba pipeline so that the system could be used as conceptual material in the field of environmental protection (a base for the new SCADA system). Considered environmental aspects were assessed in terms of their vulnerability. The criteria were defined as the vulnerability of the aquatic environment (surface waters and ground waters), the vulnerability of soil environment and the vulnerability of biotic components of the environment. (authors)

  8. Comparative study of biodegradation of crude oil in soil amended ...

    African Journals Online (AJOL)

    Analysis of soil samples treated with 10% (v/w) Escravos light crude oil and amended with chicken droppings and NPK fertilizer revealed that the aerobic heterotrophic bacterial counts were depressed while the proliferation of crude oil degrading bacteria (CDB) in the soil was encouraged. The counts of CDB in oil free ...

  9. Crude oil prices: Are our oil markets too tight?

    International Nuclear Information System (INIS)

    Simmons, M.R.

    1997-01-01

    The answer to the question posed in the title is that tightness in the market will surely prevail through 1997. And as discussed herein, with worldwide demand expected to continue to grow, there will be a strong call on extra oil supply. Meeting those demands, however, will not be straightforward--as many observers wrongly believe--considering the industry's practice of maintaining crude stocks at ''Just in time'' inventory levels. Further, impact will be felt from the growing rig shortage, particularly for deepwater units, and down-stream capacity limits. While these factors indicate 1997 should be another good year for the service industry, it is difficult to get any kind of consensus view from the oil price market. With most observers' information dominated by the rarely optimistic futures price of crude, as reflected by the NYMEX, the important fact is that oil prices have remained stable for three years and increased steadily through 1996

  10. Improving fuel quality by whole crude oil hydrotreating: A kinetic model for hydrodeasphaltenization in a trickle bed reactor

    International Nuclear Information System (INIS)

    Jarullah, A.T.; Mujtaba, I.M.; Wood, A.S.

    2012-01-01

    Highlights: ► Asphaltene contaminant must be removed to a large extent from the fuel to meet the regulatory demand. ► Kinetics for hydrodeasphaltenization are estimated via experimentation and modeling. ► Using the kinetic parameters, a full process model for the trickle bed reactor (TBR) is developed. ► The model is used for simulating the behavior of the TBR to get further insight of the process. ► The influences of operating conditions in the hydrodeasphaltenization process are reported. -- Abstract: Fossil fuel is still a predominant source of the global energy requirement. Hydrotreating of whole crude oil has the ability to increase the productivity of middle distillate fractions and improve the fuel quality by simultaneously reducing contaminants such as sulfur, nitrogen, vanadium, nickel and asphaltene to the levels required by the regulatory bodies. Hydrotreating is usually carried out in a trickle bed reactor (TBR) where hydrodesulfurization (HDS), hydrodenitrogenation (HDN), hydrodemetallization (HDM) and hydrodeasphaltenization (HDAs) reactions take place simultaneously. To develop a detailed and a validated TBR process model which can be used for design and optimization of the hydrotreating process, it is essential to develop kinetic models for each of these reactions. Most recently, the authors have developed kinetic models for all of these chemical reactions except that of HDAs. In this work, a kinetic model (in terms of kinetic parameters) for the HDAs reaction in the TBR is developed. A three phase TBR process model incorporating the HDAs reactions with unknown kinetic parameters is developed. Also, a series of experiments has been conducted in an isothermal TBR under different operating conditions affecting the removal of asphaltene. The unknown kinetic parameters are then obtained by applying a parameter estimation technique based on minimization of the sum of square errors (SSEs) between the experimental and predicted concentrations of

  11. Crude oil pricing report, issue 89, December 1992

    International Nuclear Information System (INIS)

    1992-01-01

    This report is prepared by the Canadian Oil Markets and Emergency Planning Division (COMEP), Energy, Mines and Resources Canada. It provides a reference for domestic and imported crude oil prices in Canadian markets and illustrates the competitive position of Canadian crude in the U.S. market. The information in this report is in part based on the Crude Oil Pricing Survey (COPS), conducted by COMEP, of Canadian refiners' domestic crude oil purchases, refinery receipts, imports and data from trade publications as well as industry pricing bulletins. 8 tabs

  12. Systemic toxicity of dermally applied crude oils in rats

    Energy Technology Data Exchange (ETDEWEB)

    Feuston, M.H.; Mackerer, C.R.; Schreiner, C.A.; Hamilton, C.E. [Stonybrook Labs., Inc., Princeton, NJ (United States)

    1997-12-31

    Two crude oils, differing in viscosity (V) and nitrogen (N) and sulfur (S) content, were evaluated for systemic toxicity, In the Crude I (low V, low N, low S) study, the material was applied to the clipped backs of rats at dose levels of 0, 30, 125, and 500 mg/kg. In the Crude II (high V, high N, moderate S) study, the oil was applied similarly at the same dose levels. The crude oils were applied for 13 wk, 5 d/wk. Exposure sites were not occluded. Mean body weight gain (wk 1-14) was significantly reduced in male rats exposed to Crude II; body weight gain of all other animals was not adversely affected by treatment. An increase in absolute (A) and relative (R) liver weights and a decrease in A and R thymus weights were observed in male and female rats exposed to Crude II at 500 mg/kg; only liver weights (A and R) were adversely affected in male and female rats exposed to Crude I. In general, there was no consistent pattern of toxicity for serum chemistry endpoints; however, more parameters were adversely affected in Crude II-exposed female rats than in the other exposed groups. A consistent pattern of toxicity for hematology endpoints was observed among male rats exposed to Crude I and male and female rats exposed to Crude II. Parameters affected included: Crudes I and II, red blood cell count, hemoglobin, and hematocrit, Crude II, platelet count. Microscopic evaluation of tissues revealed the following treatment-related findings: Crude I, treated skin, thymus, and thyroid; Crude II, bone marrow, treated skin, thymus, and thyroid. The LOEL (lowest observable effect level) for skin irritation and systemic toxicity (based on marginal effects on the thyroid) for both crude oils was 30 mg/kg; effects were more numerous and more pronounced in animals exposed to Crude II. Systemic effects are probably related to concentrations of polycyclic aromatic compounds (PAC) found in crude oil.

  13. What about oil reserve depletion and crude oil price evolution?

    International Nuclear Information System (INIS)

    2007-01-01

    The objective of this report is to give a synthesis of different points of view with respect to the 'Peak Oil' perspective and to the crude oil price evolution. In the first part, the authors examine the evolutions and assessments of oil reserves and productions, by discussing the different types of reserve, the optimistic and pessimistic points of views. Then, in the second part, they analyse the long term price formation, the various production technical costs (conventional oils, heavy oils and asphaltic sands, coal- and gas-based synthetic hydrocarbons, bio-fuels), the external costs (notably in relationship with greenhouse emissions), the relationship between geopolitical issues and short and middle term price formation. In the third and last part, they discuss the possible evolutions and scenarios in terms of demand, production, and prices

  14. Impact of Expanded North Slope of Alaska Crude Oil Production on Crude Oil Flows in the Contiguous United States

    Energy Technology Data Exchange (ETDEWEB)

    DeRosa, Sean E. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Flanagan, Tatiana Paz [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2017-05-01

    The National Transportation Fuels Model was used to simulate a hypothetical increase in North Slope of Alaska crude oil production. The results show that the magnitude of production utilized depends in part on the ability of crude oil and refined products infrastructure in the contiguous United States to absorb and adjust to the additional supply. Decisions about expanding North Slope production can use the National Transportation Fuels Model take into account the effects on crude oil flows in the contiguous United States.

  15. Thermogravimetric assessment of thermal degradation in asphaltenes

    Energy Technology Data Exchange (ETDEWEB)

    Barneto, Agustín García, E-mail: agustin.garcia@diq.uhu.es [Department of Chemical Engineering, Physical Chemistry and Organic Chemistry, University of Huelva, Huelva (Spain); Carmona, José Ariza [Department of Chemical Engineering, Physical Chemistry and Organic Chemistry, University of Huelva, Huelva (Spain); Garrido, María José Franco [CEPSA, RDI Centre, Madrid (Spain)

    2016-03-20

    Graphical abstract: - Highlights: • Asphaltenes content of visbreaking streams in oil refinery can be measured by using TGA. • Deconvoluting TGA curves allows the thermal-based composition of asphaltenes to be elucidated. • Asphaltenes cracking involves acceleratory stages compatible with autocatalytic kinetic. • Activation energy during asphaltenes pyrolysis increased with increasing temperature. • Activation energy remained almost constant at 200–225 kJ/mol during oxidative cracking. - Abstract: Monitoring asphaltenes is very important with a view to optimizing visbreaking units in oil refineries. Current analyses based on selective dissolution in different solvents are slow, so new, more expeditious methods for measuring asphaltenes are required to facilitate fuel-oil production. In this work, we studied the thermal degradation of asphaltenes as the potential basis for a thermogravimetric method for their monitoring in visbreaking streams. The thermal degradation of asphaltenes occurs largely from 400 to 500 °C; the process is quite smooth in an inert environment but involves several fast mass loss events in the air. Kinetic parameters for characterizing the process were determined by using two model-free methods and the modified Prout–Tompkins kinetic equation to examine asphaltene thermolysis. Both types of methods showed the activation energy to increase during pyrolysis but to remain almost constant during cracking in the presence of oxygen or even diminish during char oxidation. Deconvoluting the thermogravimetric profiles revealed that asphaltene thermolysis in the air cannot be accurately described in terms of an nth order kinetic model because it involves some acceleratory phases. Also, thermogravimetric analyses of visbreaking streams revealed that char production in them is proportional to their asphaltene content. This relationship enables the thermogravimetric measurement of asphaltenes.

  16. Thermogravimetric assessment of thermal degradation in asphaltenes

    International Nuclear Information System (INIS)

    Barneto, Agustín García; Carmona, José Ariza; Garrido, María José Franco

    2016-01-01

    Graphical abstract: - Highlights: • Asphaltenes content of visbreaking streams in oil refinery can be measured by using TGA. • Deconvoluting TGA curves allows the thermal-based composition of asphaltenes to be elucidated. • Asphaltenes cracking involves acceleratory stages compatible with autocatalytic kinetic. • Activation energy during asphaltenes pyrolysis increased with increasing temperature. • Activation energy remained almost constant at 200–225 kJ/mol during oxidative cracking. - Abstract: Monitoring asphaltenes is very important with a view to optimizing visbreaking units in oil refineries. Current analyses based on selective dissolution in different solvents are slow, so new, more expeditious methods for measuring asphaltenes are required to facilitate fuel-oil production. In this work, we studied the thermal degradation of asphaltenes as the potential basis for a thermogravimetric method for their monitoring in visbreaking streams. The thermal degradation of asphaltenes occurs largely from 400 to 500 °C; the process is quite smooth in an inert environment but involves several fast mass loss events in the air. Kinetic parameters for characterizing the process were determined by using two model-free methods and the modified Prout–Tompkins kinetic equation to examine asphaltene thermolysis. Both types of methods showed the activation energy to increase during pyrolysis but to remain almost constant during cracking in the presence of oxygen or even diminish during char oxidation. Deconvoluting the thermogravimetric profiles revealed that asphaltene thermolysis in the air cannot be accurately described in terms of an nth order kinetic model because it involves some acceleratory phases. Also, thermogravimetric analyses of visbreaking streams revealed that char production in them is proportional to their asphaltene content. This relationship enables the thermogravimetric measurement of asphaltenes.

  17. A catalogue of crude oil and oil product properties, 1990

    International Nuclear Information System (INIS)

    Bobra, M.A.; Callaghan, S.

    1990-09-01

    This catalogue is a compilation of available data on crude oils and petroleum products. The emphasis of the catalogue is upon oils which could potentially impact Canada's environment. Other oils which are unlikely to be of direct Canadian concern are also included because they have been well characterized and used in relevant studies. The properties listed for each oil are those which will provide an indication of a spilled oil's environmental behaviour and effects. The properties on which data is provided include API gravity, density, viscosity, interfacial tension, pour point, flash point, vapor pressure, volatility and component distribution, emulsion formation tendency and stability, weathering, dispersability, major hydrocarbon groups, aqueous solubility, toxicity, sulfur content, fire point, and wax content. Most of the chemical-physical properties listed in this catalogue were measured using standard tests. For certain properties, data are given at different temperatures and for different degrees of oil weathering. An oil's degree of weathering is expresed as the volume or weight percent evaporated from the fresh oil. Weathered oils used for testing were artificially weathered by gas stripping following the method of Mackay and Stiver. 109 refs

  18. A catalogue of crude oil and oil product properties, 1992

    International Nuclear Information System (INIS)

    Whiticar, S.; Bobra, M.; Liuzzo, P.; Callaghan, S.; Fingas, M.; Jokuty, P.; Ackerman, F.; Cao, J.

    1993-02-01

    This catalogue is a compilation of available data on crude oils and petroleum products. The emphasis of the catalogue is upon oils which could potentially impact Canada's environment. Other oils which are unlikely to be of direct Canadian concern are also included because they have been well characterized and used in relevant studies. The properties listed for each oil are those which will provide an indication of a spilled oil's environmental behaviour and effects. The properties on which data is provided include API gravity, density, viscosity, interfacial tension, pour point, flash point, vapor pressure, volatility and component distribution, emulsion formation tendency and stability, weathering, dispersability, major hydrocarbon groups, aqueous solubility, toxicity, sulfur content, fire point, and wax content. Most of the chemical-physical properties listed in this catalogue were measured using standard tests. For certain properties, data are given at different temperatures and for different degrees of oil weathering. An oil's degree of weathering is expresed as the volume or weight percent evaporated from the fresh oil. Weathered oils used for testing were artificially weathered by gas stripping following the method of Mackay and Stiver. 140 refs

  19. Alberta oil sands crudes : upgrading and marketing

    International Nuclear Information System (INIS)

    Ashar, M.

    2008-01-01

    Open pit mining and in situ techniques, such as steam stimulation, are used to recover Alberta's bitumen and heavy oil resources, which have higher viscosities than conventional hydrocarbons. The bitumen is typically upgraded to synthetic crude oil (SCO). In the simplest processing scheme, the bitumen is blended with diluent for ease in pipeline transport and then processed at refineries with upgrading facilities. The bitumen is also upgraded to light SCO at world-scale upgraders in Alberta. The SCO is then processed at refineries in downstream markets. The 2 categories of upgrading, notably primary and secondary upgrading, were described in this article along with technology options for both categories. Slurry hydrocracking is regarded as the most interesting emerging residual fuel upgrading technology. It combines special catalyst mixes with the latest slurry reactor designs as well as innovative catalyst capture and recycle schemes to produce very high conversions and potentially superior upgrading economics. The increase in volume and rate of SCO from Alberta provides refiners in the oil sands marketing sector an unprecedented choice of opportunities to improve profitability. Key trends indicate that production will increase substantially from 2008 to 2030. 5 figs

  20. Alberta oil sands crudes : upgrading and marketing

    Energy Technology Data Exchange (ETDEWEB)

    Ashar, M. [Suncor Energy, Fort McMurray, AB (Canada)

    2008-05-15

    Open pit mining and in situ techniques, such as steam stimulation, are used to recover Alberta's bitumen and heavy oil resources, which have higher viscosities than conventional hydrocarbons. The bitumen is typically upgraded to synthetic crude oil (SCO). In the simplest processing scheme, the bitumen is blended with diluent for ease in pipeline transport and then processed at refineries with upgrading facilities. The bitumen is also upgraded to light SCO at world-scale upgraders in Alberta. The SCO is then processed at refineries in downstream markets. The 2 categories of upgrading, notably primary and secondary upgrading, were described in this article along with technology options for both categories. Slurry hydrocracking is regarded as the most interesting emerging residual fuel upgrading technology. It combines special catalyst mixes with the latest slurry reactor designs as well as innovative catalyst capture and recycle schemes to produce very high conversions and potentially superior upgrading economics. The increase in volume and rate of SCO from Alberta provides refiners in the oil sands marketing sector an unprecedented choice of opportunities to improve profitability. Key trends indicate that production will increase substantially from 2008 to 2030. 5 figs.

  1. Process for removing heavy metal compounds from heavy crude oil

    Science.gov (United States)

    Cha, Chang Y.; Boysen, John E.; Branthaver, Jan F.

    1991-01-01

    A process is provided for removing heavy metal compounds from heavy crude oil by mixing the heavy crude oil with tar sand; preheating the mixture to a temperature of about 650.degree. F.; heating said mixture to up to 800.degree. F.; and separating tar sand from the light oils formed during said heating. The heavy metals removed from the heavy oils can be recovered from the spent sand for other uses.

  2. Molecular Dynamics Simulation of Spontaneous Imbibition in Nanopores and Recovery of Asphaltenic Crude Oils Using Surfactants for EOR Applications Simulations de dynamique moléculaire d’imbibition spontanée dans des nanopores et pour la récupération d’huiles brutes asphalténiques en utilisant des agents tensioactifs pour des applications d’EOR

    Directory of Open Access Journals (Sweden)

    Stukan M.R.

    2012-12-01

    Full Text Available We present Molecular Dynamics (MD simulations of the imbibition process in nanopores in case of two different mechanisms of the wettability modification. We compare the imbibition of an aqueous surfactant solution into an oil-wet pore driven by surfactant adsorption onto the oil-wet rock surface (coating mechanism and the imbibition of an aqueous surfactants solution driven by surfactants removing the contaminant molecules from the originally water-wet surface (cleaning mechanism. Our results show qualitative difference in the imbibition dynamics in these two cases and indicate that MD simulation is a useful tool to investigate details of the imbibition mechanisms at the pore scale with direct implications for Enhanced Oil Recovery (EOR operations. Nous presentons des simulations de Dynamique Moleculaire (DM du processus d’imbibition dans des nanopores dans le cas de deux mecanismes differents de modification de mouillabilite. Nous comparons l’imbibition d’une solution aqueuse d’agent tensioactif dans un pore mouille d’huile entrainee par une adsorption d’agent tensioactif sur la surface de roche mouillee d’huile (mecanisme de revetement et l’imbibition d’une solution aqueuse d’agent tensioactif entrainee par des agents tensioactifs eliminant les molecules contaminantes de la surface originellement mouillee d’eau (mecanisme de nettoyage. Nos resultats montrent une difference qualitative en matiere de dynamique d’imbibition dans ces deux cas et indiquent que la simulation de DM constitue un outil utile pour etudier les mecanismes d’imbibition a l’echelle des pores avec des implications directes pour des operations de recuperation renforcee d’huile (EOR, Enhanced Oil Recovery.

  3. Avaliação geoquímica de biomarcadores ocluídos em estruturas asfaltênicas Geochemical evaluation of occluded biomarkers in asphaltenic structures

    Directory of Open Access Journals (Sweden)

    Débora de Almeida Azevedo

    2009-01-01

    Full Text Available Asphaltenes from two Brazilian crude oils were submitted to mild oxidation to disrupt their structure, releasing the occluded oil. The released hydrocarbons were compared with those from the original crude oil, and used to evaluate the alteration of the oils, especially as a result of biodegradation, but also thermal maturity. The crude oils used are depleted in n-alkanes, which are usually related to biodegradation. However, the released products from the corresponding asphaltenes have n-alkane distributions from nC10 to nC40, suggesting a protection effect from biodegradation. The m/z 191 mass chromatograms showed higher relative intensities for tricyclic terpanes than the hopanes in the crude in comparison with the released ones.

  4. Crude oil degradation by Bacillus and Micrococcus species isolated ...

    African Journals Online (AJOL)

    Microorganisms capable of degrading crude oil were isolated from soil compost in Kano, northwestern Nigeria. The work was carried out with the aim of determining crude-oil biodegradation potentials of Bacillus and Micrococcus species isolated from the soil compost as well as the assessment of the applicability of ...

  5. Remediation trials of crude oil contaminated soil using different ...

    African Journals Online (AJOL)

    A 3 month remediation trial of the use of detergent and sawdust in different combination forms in the restoration of a crude oil contaminated tropical soil was investigated. 8 remediation treatments labeled A – H in addition to the control (I) were used in 10 kg soil artificially polluted with 300 ml crude oil each. Remediation ...

  6. Toxicity of crude oil products and detergent on serum alkaline ...

    African Journals Online (AJOL)

    The comparative effect of exposing Clarias gariepinus juveniles (100.20 + 0.8g) to diferent concentrations of crude oil products and detergent were studied. Bonny Light Crude oil (BLCO), Premium motor spirit (PMS), Dual purpose kerosene (DPK) and Ariel Enzymax Detergent (AED) were respectively applied at three ...

  7. Manihot esculenta crantz in crude oil contaminated soil amended ...

    African Journals Online (AJOL)

    Studies on the performance of Manihot esculenta, Crantz (TMS 30572) in a crude oil polluted soil was investigated in the Botanic Garden of University of Port Harcourt. The soil samples were polluted at four different levels (0%, 2%, 4% and 6%) with crude oil and amended with organic supplement (decomposed Centrosem ...

  8. Crude oil options market found to be efficient

    International Nuclear Information System (INIS)

    Anon.

    1992-01-01

    This paper reports that the U.S. crude oil options market operates efficiently and does not overreact. The authors, with the JFK School of Government, studied the crude oil options market under a Department of Energy grant. The current market was created in November 1986 when the New York Mercantile Exchange introduced an options contract for delivery of West Texas intermediate crude futures. it has grown greatly since then

  9. Experimental Study and Mathematical Modeling of Asphaltene Deposition Mechanism in Core Samples

    Directory of Open Access Journals (Sweden)

    Jafari Behbahani T.

    2015-11-01

    Full Text Available In this work, experimental studies were conducted to determine the effect of asphaltene deposition on the permeability reduction and porosity reduction of carbonate, sandstone and dolomite rock samples using an Iranian bottom hole live oil sample which is close to reservoir conditions, whereas in the majority of previous work, a mixture of recombined oil (a mixture of dead oil and associated gas was injected into a core sample which is far from reservoir conditions. The effect of the oil injection rate on asphaltene deposition and permeability reduction was studied. The experimental results showed that an increase in the oil injection flow rate can result in an increase in asphaltene deposition and permeability reduction. Also, it can be observed that at lower injection flow rates, a monotonic decrease in permeability of the rock samples can be attained upon increasing the injection flow rate, while at higher injection rates, after a decrease in rock permeability, an increasing trend is observed before a steady-state condition can be reached. The experimental results also showed that the rock type can affect the amount of asphaltene deposition, and the asphaltene deposition has different mechanisms in sandstone and carbonate core samples. It can be seen that the adsorption and plugging mechanisms have a more important role in asphaltene deposition in carbonate core samples than sandstone core samples. From the results, it can be observed that the pore volumes of the injected crude oil are higher for sandstone cores compared with the carbonate cores. Also, it can be inferred that three depositional types may take place during the crude oil injection, i.e., continuous deposition for low-permeability cores, slow, steady plugging for high-permeability cores and steady deposition for medium-permeability cores. It can be seen from the experimental results that damage to the core samples was found to increase when the production pressures were

  10. Procedures in field systems for collecting and demulsifying crude oils

    Energy Technology Data Exchange (ETDEWEB)

    Vakhitov, G G; Graifer, V I; Tronov, V P; Zakirov, I G

    1969-01-01

    This microscopic study of crude oil emulsification and demulsification showed that the sooner an emulsion is chemically treated, the less its stability. This finding led to the practice of adding demulsifiers to the crude oil in pipelines. This method of demulsification is now used in Romashkino, Bablinsk, and Elkhovs fields. By this early addition of a chemical, the tendency of the pipeline to form stable, highly viscous emulsions is reduced. This treatment also facilitates separation of water from oil in storage tanks. Repeated tests have shown that pipeline demulsification is a highly effective and economic process. This method reduces crude oil dewatering costs by several hundred percent.

  11. Tweens demulsification effects on heavy crude oil/water emulsion

    Directory of Open Access Journals (Sweden)

    Nastaran Hayati Roodbari

    2016-09-01

    Full Text Available The demulsification role of Tweens (nonionic polymers was determined in the separation of water from heavy crude oil emulsion. According to the previous researches, these nonionic polymers, having hydrophilic and lipophilic groups, are appropriate for making oil in water emulsion. In this research their effects in certain concentrations on demulsifying of water in crude oil emulsion were proved. High molecular weight, alkenes’ chains and groups of ketone and ester in these polymers can improve their performance for the demulsification of water in crude oil emulsion. Their efficiencies are improved with electronegative groups such as oxygen. They leave no corrosion effect because they are neutral and do not leave counter ions.

  12. Crude oil prices: It's not like '86

    International Nuclear Information System (INIS)

    Simmons, M.R.

    1994-01-01

    In 1981, daily crude oil productive capacity exceeded demand by more than 25%, leading to a 4-yr price decline from near $40 per barrel levels, and a sharp drop in 1986 to near $12. But, in 1994, the fundamentals are reversed, worldwide demand is growing, conservation movements are not active, and certain geographic areas, like Asia, are set to tax the system as they modernize. Meanwhile, US and Former Soviet Union production is off, without prospects for near-term turnaround. And there is reason to believe OPEC leaders may not feel compelled to cut their output, when combined small cuts of the magnitude of 5% by the rest of the world's producers could accomplish the same objective of raising oil prices. As with any forecast, only time and hindsight will tell the real story, but 1994 could end up being one of the periodic turning points for what has always been a long-term cyclical industry. This paper summarizes the predictions and causes of predicted price changes

  13. Experimental study on yield behavior of Daqing crude oil

    Energy Technology Data Exchange (ETDEWEB)

    Hou, Lei [China University of Petroleum, College of Mechanical and Transportation Engineering, Beijing (China)

    2012-07-15

    The yield behavior of Daqing crude oil was studied by means of multi-mode controlled-stress tests with a high-precision stress controlled rheometer. Two experiments of creep and constant stress loading rate were performed. The yield stress of gelled crude oil was dependent on the test conditions such as the stress loading time and the stress loading rate, but the yield strain did not change with test conditions. The yield strain did exist objectively and it can be used as the criterion for the yielding of the structure of gelled crude oil. The yield strain of gelled oil was studied through experiments of creep, constant stress loading rate, oscillatory shear stress increase, and constant shear rate. The yield strain of gelled crude oil decreased with the increasing gel strength. The experiment of constant speed increase of stress showed the strain softening phenomena for low gel strength oil. (orig.)

  14. Beyond the crude oil and gas reserves

    International Nuclear Information System (INIS)

    Sote, K.

    1993-01-01

    Petroleum remains the greatest jewel of inestimable value in both the local and international treasure hunts for cheap energy source and viable investment options the world over. The diverse business potentials and favourable government policies in Nigeria aimed specifically at stimulating investments in the up streams, midstream and downstream industries need to be tapped by both indigenous and foreign investors alike. Beyond the crude oil and gas reserves' is therefore our modest effort to support such policies, sensitise the Nigerian petroleum industry and promote more dynamic awareness for the varied business opportunities abound in this sector of the economy. The main objective or this publication is to bring to a wider audience within and outside the oil industry a spectrum of such salient opportunities therein. The publication further presents in a lucid and consize form the hidden potentials yet to be harnessed, captures the essence of such investments, identifies the inherent problems in Nigeria peculiar circumstance and thus provides a detailed guide to address such short-coming, viz. Inadequate and poor knowledge of petroleum industry, its operation, by products and their correct applications. - Lack of understanding of the intricacies, realities and technicalities of petroleum business in general. - Poor financial resources, management style, operational and marketing strategies man power and human resources development.- Dirge of information, lack of professional advice and technical service support on the varied business opportunities for diversification. Apathy on the part of the investors themselves to seek for professional support from competent oil consultants, technocrats, institutionalised authorities on petroleum and related matters, amongst others. In summary, the book is divided into ten chapters with illustrations, graphics, drawings, sketches and incorporating figures, statistics, business reports, marketing results, feasibility studies

  15. Naphthenic acids hydrates of gases: influence of the water/oil interface on the dispersing properties of an acidic crude oil; Acides naphteniques hydrates de gaz de l'interface eau/huile sur les proprietes dispersantes d'un brut acide

    Energy Technology Data Exchange (ETDEWEB)

    Arla, D.

    2006-01-15

    Nowadays, the development of offshore oil production under increasing water depths (high pressures and low temperatures) has led oil companies to focus on gas hydrates risks. Hydrates are crystals containing gas and water molecules which can plug offshore pipelines. It has been shown that some asphaltenic crude oils stabilize water-in-oil emulsions (W/O) during several months and exhibit very good anti-agglomerant properties avoiding hydrate plugs formation. In this work, we have studied the 'anti-hydrate' properties of a West African acidic crude oil called crude AH. This oil contains naphthenic acids, RCOOH hydrocarbons which are sensitive to both the pH and the salinity of the water phase.The emulsifying properties of the crude AH have firstly been explored. It has been shown that heavy resins and asphaltenes are the main compounds of the crude AH responsible for the long term stability of the W/O emulsions whereas the napthenates RCOO{sup -} lead to less stable W/O emulsions. Dealing with hydrates, the crude AH exhibits moderate anti-agglomerant properties due to the presence of heavy resins and asphaltenes. However, the naphthenates RCOO{sup -} drastically increase the formation of hydrate plugs. Moreover, it has been pointed out that hydrate particles agglomeration accelerates the kinetics of hydrate formation and enhances the water/oil separation. In order to explain these behaviours, a mechanism of agglomeration by 'sticking' between a hydrate particle and a water droplet has been proposed. Finally, we have developed a model which describes the physico-chemical equilibria of the naphthenic acids in the binary system water/crude AH, in order to transpose the results obtained in the laboratory to the real oil field conditions. (author)

  16. Feasibility Process for Remediation of the Crude Oil Contaminated Soil

    Science.gov (United States)

    Keum, H.; Choi, H.; Heo, H.; Lee, S.; Kang, G.

    2015-12-01

    More than 600 oil wells were destroyed in Kuwait by Iraqi in 1991. During the war, over 300 oil lakes with depth of up to 2m at more than 500 different locations which has been over 49km2. Therefore, approximately 22 million m3was crude oil contaminated. As exposure of more than 20 years under atmospheric conditions of Kuwait, the crude oil has volatile hydrocarbons and covered heavy oily sludge under the crude oil lake. One of crude oil contaminated soil which located Burgan Oilfield area was collected by Kuwait Oil Company and got by H-plus Company. This contaminated soil has about 42% crude oil and could not biodegraded itself due to the extremely high toxicity. This contaminated soil was separated by 2mm sieve for removal oil sludge ball. Total petroleum hydrocarbons (TPH) was analysis by GC FID and initial TPH concentration was average 48,783 mg/kg. Ten grams of the contaminated soil replaced in two micro reactors with 20mL of bio surfactant produce microorganism. Reactor 1 was added 0.1g powder hemoglobin and other reactor was not added hemoglobin at time 0 day. Those reactors shake 120 rpm on the shaker for 7 days and CO2 produced about 150mg/L per day. After 7 days under the slurry systems, the rest days operated by hemoglobin as primary carbon source for enhanced biodegradation. The crude oil contaminated soil was degraded from 48,783mg/kg to 20,234mg/kg by slurry process and final TPH concentration degraded 11,324mg/kg for 21days. Therefore, highly contaminated soil by crude oil will be combined bio slurry process and biodegradation process with hemoglobin as bio catalytic source. Keywords: crude-oil contaminated soil, bio slurry, biodegradation, hemoglobin ACKOWLEDGEMENTS This project was supported by the Korea Ministry of Environment (MOE) GAIA Program

  17. New heavy crude oil flow improver increases delivery : application scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Pierce, J.; Johnston, R.; Lauzon, P. [ConocoPhillips Specialty Products Inc., Houston, TX (United States)

    2009-07-01

    Flow improvers or drag reducing agents have been used for over 25 years as a method to increase fluid flow in hydrocarbon pipelines. The technology is effective in refined projects, light and medium crude oils. This paper presented a new development in flow improver technology that allows treatment of heavy crude oil slates. It discussed case studies of flow improver treatment of heavy oils in various pipeline system as well as factors that affect commercial success. tabs., figs.

  18. MICROWAVE HEATING AND SEPARATION OF WATER-IN-OIL EMULSION FROM MEXICAN CRUDE OIL

    OpenAIRE

    VAZQUEZ V., ADRIAN; LOPEZ M., ARTURO; ANDRADE C., LUIS J.; VAZQUEZ A., ARIANA M.

    2014-01-01

    Microwave heating and gravity sedimentation are alternatives for demulsification and layer separation into oil and water layers, this process was demonstrated in the laboratory and provides an option for reducing and oil recovering from water-in-oil Mexican oil emulsions. The combinatorial process was implemented in a test lab using Mexican crude oil samples. The Laboratory samples were 100% and 50-50%, crude and crude-water respectively, were heated. The results were encouraging show that mi...

  19. Efficiency of crude oil markets: Evidences from informational entropy analysis

    International Nuclear Information System (INIS)

    Ortiz-Cruz, Alejandro; Rodriguez, Eduardo; Ibarra-Valdez, Carlos; Alvarez-Ramirez, Jose

    2012-01-01

    The role of crude oil as the main energy source for the global economic activity has motivated the discussion about the dynamics and causes of crude oil price changes. An accurate understanding of the issue should provide important guidelines for the design of optimal policies and government budget planning. Using daily data for WTI over the period January 1986–March 2011, we analyze the evolution of the informational complexity and efficiency for the crude oil market through multiscale entropy analysis. The results indicated that the crude oil market is informationally efficient over the scrutinized period except for two periods that correspond to the early 1990s and late 2000s US recessions. Overall, the results showed that deregulation has improved the operation of the market in the sense of making returns less predictable. On the other hand, there is some evidence that the probability of having a severe US economic recession increases as the informational efficiency decreases, which indicates that returns from crude oil markets are less uncertain during economic downturns. - Highlights: ► Entropy concepts are used to characterize crude oil prices. ► An index of market efficiency is introduced. ► Except for periods of economic recession, the crude oil market is informationally efficient.

  20. Investigation on trace elements in crude oil and organic matter extracted from rocks with instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    Ding Zuguo; Chai Zhifang

    1990-01-01

    Solvent extraction, column chromatography and instrumental neutron activation analysis(INAA) have been used to investigate the trace elements in crude oil, organic matter extracted from rocks and their related fractions. With these methods, about 70 crude oil samples from eight different oil fields in China and 6 extracted asphaltene samples of the lower paleozoic from the upper Yangtze region have been analyzed, and about 40 elements of interest have been determined. Those elements include Al, As, Au, Ba, Br, Cl, Co, Cr, Cs, Cu, Fe, Hf, I, Ir, Mg, Mn, Mo, Na, Ni, Rb, Re, S, Sb, Sc, Se, Sr, Th, Zn, V and parts of REE. The experimental results show that the method possesses several advantages, i.e. non-destructive, multi-elements, sensitive, precise and accurate. Without ashing samples, the loss of volatile elements such as Cl, S, Se and Sb are avoided. The column chromatography makes it possible to study the distributions of trace elements in different fractions of crude oil and organic matter extracted. Meanwhile, the characters of trace elements in them have also been discussed

  1. How much crude oil can zooplankton ingest? Estimating the quantity of dispersed crude oil defecated by planktonic copepods

    International Nuclear Information System (INIS)

    Almeda, Rodrigo; Connelly, Tara L.; Buskey, Edward J.

    2016-01-01

    We investigated and quantified defecation rates of crude oil by 3 species of marine planktonic copepods (Temora turbinata, Acartia tonsa, and Parvocalanus crassirostris) and a natural copepod assemblage after exposure to mechanically or chemically dispersed crude oil. Between 88 and 100% of the analyzed fecal pellets from three species of copepods and a natural copepod assemblage exposed for 48 h to physically or chemically dispersed light crude oil contained crude oil droplets. Crude oil droplets inside fecal pellets were smaller (median diameter: 2.4–3.5 μm) than droplets in the physically and chemically dispersed oil emulsions (median diameter: 6.6 and 8.0 μm, respectively). This suggests that copepods can reject large crude oil droplets or that crude oil droplets are broken into smaller oil droplets before or during ingestion. Depending on the species and experimental treatments, crude oil defecation rates ranged from 5.3 to 245 ng-oil copepod"−"1 d"−"1, which represent a mean weight-specific defecation rate of 0.026 μg-oil μg-C_c_o_p_e_p_o_d"1 d"−"1. Considering a dispersed crude oil concentration commonly found in the water column after oil spills (1 μl L"−"1) and copepod abundances in high productive coastal areas, copepods may defecate ∼1.3–2.6 mg-oil m"−"3 d"−"1, which would represent ∼0.15%–0.30% of the total dispersed oil per day. Our results indicate that ingestion and subsequent defecation of crude oil by planktonic copepods has a small influence on the overall mass of oil spills in the short term, but may be quantitatively important in the flux of oil from surface water to sediments and in the transfer of low-solubility, toxic petroleum hydrocarbons into food webs after crude oil spills in the sea. - Highlights: • Copepods exposed to dispersed crude oil produced fecal pellets contained numerous small oil droplets (2.4 to 3.5 µm). • Copepods could reject large oil droplets or oil droplets are broken into

  2. Expanding U.S. markets for Canadian crude oil

    International Nuclear Information System (INIS)

    Heath, M.; Angevine, G.; Chan, K.; Renne, G.; Stariha, J.; MacKay, E.

    1993-01-01

    The quantities and types of Canadian, U.S. and competing foreign crudes flowing into U.S. market regions and the potential to retain and/or expand Canadian crude oil sales in each of those markets, was studied. The various pipeline system expansion/construction proposals were reviewed. Findings of the study with respect to prospects for crude oil sales into each of the U.S. market regions were presented. Opportunities and constraints with regard to the potential for incremental crude oil sales into each of the U.S. market regions were detailed. The study concluded that there was a substantial market in the U.S. for incremental sales of Canadian crudes. Most of the refineries in the U.S. market regions were more flexible in terms of their crude diet than they were before the rationalization and restructuring of the industry began. The market for crude oil in the U.S. was shown to be one of the most competitive in the world and the most volatile. The study also revealed that there were risks associated with large additions to the capacity to ship crude oil by pipeline from Western Canada, given the uncertainties surrounding future supply. 4 refs., figs., tabs

  3. Modeling of asphaltene and wax precipitation

    Energy Technology Data Exchange (ETDEWEB)

    Chung, F.; Sarathi, P.; Jones, R.

    1991-01-01

    This research project was designed to focus on the development of a predictive technique for organic deposition during gas injection for petroleum EOR. A thermodynamic model has been developed to describe the effects of temperature, pressure, and composition on asphaltene precipitation. The proposed model combines regular solution theory with Flory-Huggins polymer solutions theory to predict maximum volume fractions of asphaltene dissolved in oil. The model requires evaluation of vapor-liquid equilibria, first using an equation of state followed by calculations of asphaltene solubility in the liquid-phase. A state-of-the-art technique for C{sub 7+} fraction characterization was employed in developing this model. The preliminary model developed in this work was able to predict qualitatively the trends of the effects of temperature, pressure, and composition. Since the mechanism of paraffinic wax deposition is different from that of asphaltene deposition, another thermodynamic model based on the solid-liquid solution theory was developed to predict the wax formation. This model is simple and can predict the wax appearance temperature with reasonable accuracy. Accompanying the modeling work, experimental studies were conducted to investigate the solubility of asphaltene in oil land solvents and to examine the effects of oil composition, CO{sub 2}, and solvent on asphaltene precipitation and its properties. This research focused on the solubility reversibility of asphaltene in oil and the precipitation caused by CO{sub 2} injection at simulated reservoir temperature and pressure conditions. These experiments have provided many observations about the properties of asphaltenes for further improvement of the model, but more detailed information about the properties of asphaltenes in solution is needed for the development of more reliable asphaltene characterization techniques. 50 refs., 8 figs., 7 tabs.

  4. An Improved CO2-Crude Oil Minimum Miscibility Pressure Correlation

    Directory of Open Access Journals (Sweden)

    Hao Zhang

    2015-01-01

    Full Text Available Minimum miscibility pressure (MMP, which plays an important role in miscible flooding, is a key parameter in determining whether crude oil and gas are completely miscible. On the basis of 210 groups of CO2-crude oil system minimum miscibility pressure data, an improved CO2-crude oil system minimum miscibility pressure correlation was built by modified conjugate gradient method and global optimizing method. The new correlation is a uniform empirical correlation to calculate the MMP for both thin oil and heavy oil and is expressed as a function of reservoir temperature, C7+ molecular weight of crude oil, and mole fractions of volatile components (CH4 and N2 and intermediate components (CO2, H2S, and C2~C6 of crude oil. Compared to the eleven most popular and relatively high-accuracy CO2-oil system MMP correlations in the previous literature by other nine groups of CO2-oil MMP experimental data, which have not been used to develop the new correlation, it is found that the new empirical correlation provides the best reproduction of the nine groups of CO2-oil MMP experimental data with a percentage average absolute relative error (%AARE of 8% and a percentage maximum absolute relative error (%MARE of 21%, respectively.

  5. Characterization of Petroleum Hydrocarbons in Post-Burn Crude Oil ...

    African Journals Online (AJOL)

    In the Niger delta, crude oil spilled soils are burned as a means of decontaminating the impacted soils. Gas chromatography - flame ionization detector (GCFID) analyses were performed on oil residues extracted from burnt spilled oil soil samples to facilitate detailed chemical composition and characterization of petroleum ...

  6. Russian crude-oil production and export still increasing

    International Nuclear Information System (INIS)

    Purho, P.

    2001-01-01

    Russian crude-oil production is still increasing. In 2000 the annual production 6.48 mb/d was about 6% higher than a year before. In 2001 the production is expected to rise near the level 7 mb/d, so the increase in production volume is fast. However, the production is still far away from the maximum level of the former Soviet Union, 12 mb/d. At the moment Russia is the second largest oil producer right after Saudi Arabia. The increase in production is based on intensified use of old oil fields caused by improved technology. The oil export of Russia far abroad in 2000 was 2.5 mb/d and near abroad into FSU countries only about 180 000 b/d. The recent export of crude-oil has been near the maximum export capacity corresponding to 2.7 mb/d. About 61 million tons of oil products were exported in 2000, and even the export of oil products is increasing. Most of this was gas oil and heavy fuel oil, but also the export of gasoline was significant. The export of oil and oil products is mainly based on shipments, but also the share of train transport is high. Nearly all the crude oil is transported west either by ships or via pipelines. The share of railway transport is only few percents. Russia will continue its own oil pumping policy despite of the appeals of OPEC for reduction of oil production. Opinion in Russia is that if the increase of production and export serves the interests of Russia, it will also be carried out. The target value for crude oil for 2002 is 22 USD per barrel. The Russian crude oil production is estimated to grow up to 7.4 - 8.4 mb/d by the year 2010

  7. Influence of the type of crude oil to platforming effects

    International Nuclear Information System (INIS)

    Kafedzhiski, Branko; Crvenkova, Suzana; Zikovski, Toni

    1999-01-01

    Platforming in one of the most subtleties processing in refinery industry and it is permanent source for research and finding out the higher optimum degree. Optimum of the last effects of platforming directly depends on many parameters. One of more important parameters is the type of crude. The purpose of this work is presenting positive and negative effect to the platforming parameters caused by different types of crude in OCTA-Crude Oil Refinery -Skopje, Macedonia. (Original)

  8. Influence of the crude oil type to platforming effects

    International Nuclear Information System (INIS)

    Kafedzhiski, Branko; Crvenkova, Suzana; Zikovski, Toni

    1999-01-01

    Platforming is one of the most subtleties processing in refinery industry and it is permanent source for research and finding out the higher optimum degree. Optimum of the last effects of platforming directly depends on many parameters. One of the more important parameters is the type of the crude. The purpose of this work is presenting positive and negative effect to the platforming parameters caused by different types of crude in OCTA Crude Oil Refinery - Skopje (Macedonia). (Author)

  9. Modeling of well drilling heating on crude oil using microwave

    Energy Technology Data Exchange (ETDEWEB)

    Muntini, Melania Suweni, E-mail: melania@physics.its.ac.id; Pramono, Yono Hadi; Yustiana [Physics Department, Institut Teknologi Sepuluh Nopember, Surabaya Kampus ITS, Sukolilo, Surabaya 60111 (Indonesia)

    2016-03-11

    As the world’s oil reserves are dwindling, some researchers have been prompted to make a breakthrough to further improve the efficiency of exploration and production. One of the technologies used is heating the crude oil. This paper presents the modeling results of heat treatment on crude oil using microwave energy. Modeling is conducted by assuming that the diameter of the well is 11,16 cm, the heat source is applied on the surface of the well, and the cut-off frequency in the air and on crude oil are 1,56 GHz. and 0.91 GHz, respectively. The energy generated by the microwave radiation is converted into heat energy which is absorbed by the crude oil. Consequently, this energy increases the temperature of crude oil through a heat transfer mechanism. The results obtained showed that the temperature of crude oil is about 200°C at a depth of 62.5cm, and at a distance of 3 cm from the center of the well. Temperature along the well follows an exponential function, which is from the center of the well in the direction radially outward from the cylinder axis. It has been observed that the temperature decreases as measured from the well surface along the cylinder.

  10. Aggregation study of asphaltenes from colombian Castilla crude oil using molecular simulation

    Directory of Open Access Journals (Sweden)

    Jennifer de León-Barreneche

    2015-01-01

    Full Text Available Se presenta un modelo de simulación molecular para estudiar el mecanismo de agregación de asfaltenos. Se seleccionaron cuatro especies, obtenidas a partir de análisis estructurales del petróleo extraído del campo Castilla, en Colombia. Se estudiaron las contribuciones energéticas al proceso de agregación y se calculó el parámetro de solubilidad para cada especie. Finalmente, se estudió el proceso de agregación entre las diferentes especies con el fi n de determinar la tendencia de las moléculas hacia la autoasociación. Los resultados muestran que para todas las especies, el estado de agregación es energéticamente favorable, y que tanto las fuerzas de Van der Waals como las fuerzas electrostáticas contribuyen en igual magnitud al proceso de agregación. Se encontró también que la estructura molecular de las moléculas tiene una gran infl uencia en la manera cómo se agregan los asfaltenos. Para las estructuras continentales, las ramifi caciones largas ocasionan un impedimento físico para la agregación. Por otro lado, la fl exibilidad asociada a las moléculas tipo archipiélago favorece la agregación con otras especies, pero de alguna manera entorpece la autoasociación. El parámetro de solubilidad para todas las especies se encontró dentro del rango establecido por la literatura.

  11. Dynamic Relationship between Crude Oil Price, Exchange Rate and ...

    African Journals Online (AJOL)

    DrNneka

    Second, since Hamilton (1983) documented the impact of crude oil price volatility .... Hariri,2013) sourced from the U.S. Energy Information Administration (EIA). .... is explained by identifying the relative importance of a variable in generating.

  12. Evaluation of Crude Oil Biodegradation Efficiency and Peroxidase ...

    African Journals Online (AJOL)

    ADOWIE PERE

    Increase in biomass enhanced degradation efficiency above 80 % after 10 days for all concentration of crude oil studied. Peroxidase ... compounds by various bacteria and fungi (Gianfreda et al, 1999) ... into a clean plastic container. Microbial.

  13. Enhancement of Crude Oil Polluted Soil by Applying Single and ...

    African Journals Online (AJOL)

    ADOWIE PERE

    bioline.org.br/ja ... 5 kg of soil each was polluted with 200 ml of crude oil ... organic matter, phosphate, nitrate, total hydrocarbon content, potassium and microbial population were analyzed before ... arise mainly from the processing and distribution of.

  14. An isolated bacterial consortium for crude oil biodegradation

    African Journals Online (AJOL)

    GREGORY

    2011-12-16

    Dec 16, 2011 ... African Journal of Biotechnology Vol. 10(81), pp. ... The removal of crude oil by bioremediation was achieved in less time as compared to natural attenuation ... Environmental pollution, especially with hydrocarbons is a major ...

  15. Bioremediation of crude oil spills in marine and terrestrial environments

    International Nuclear Information System (INIS)

    Prince, R.C.

    1995-01-01

    Bioremediation can be a safe and effective tool for dealing with crude oil spills, as demonstrated during the cleanup following the Exxon Valdez spill in Alaska. Crude oil has also been spilled on land, and bioremediation is a promising option for land spills too. Nevertheless, there are still areas where understanding of the phenomenon is rather incomplete. Research groups around the world are addressing these problems, and this symposium provides an excellent overview of some of this work

  16. Kurdistan crude oils as feedstock for production of aromatics

    Directory of Open Access Journals (Sweden)

    Abdulsalam R. Karim

    2017-05-01

    Full Text Available Crude oils from various locations in Iraqi Kurdistan were fully evaluated, so that enables refiners to improve their operation by selecting the best crude oil that yields high naphtha content to be used as a catalytic reforming feedstock after determination of total sulfur content and then de sulfurizing them, then cyclizing or reforming these sweet naphtha cuts to produce aromatic fractions which can be split into benzene, toluene, and xylenes.

  17. Pricing and crude oil self-sufficiency. [Canada

    Energy Technology Data Exchange (ETDEWEB)

    1979-11-01

    How Canada should go about achieving crude oil self-sufficiency and who should develop Canada's petroleum resources are discussed. The degree of urgency and the level of commitment required by government, industry, and consumers are evaluated. What the price should be of Canadian crude oil and who should establish this price are also discussed. The economic aspects of investment, return, and taxation are also included. (DC)

  18. Evaluating the US government's crude oil price projections

    International Nuclear Information System (INIS)

    Williams, M.D.

    1992-01-01

    The U.S. Department of Energy's (DOE) 1991 official long run crude oil price projections are evaluated by comparing parameter averages for the forecast period (1991-2010) to parameter averages from crude oil price history (1859-1990). The parameters used in the evaluation are average price, average annual price changes, and average cycle duration (in years). All prices used in the analysis are annual prices in constant 1990 dollars per barrel. 13 figs

  19. The impact of energy derivatives on the crude oil market

    Energy Technology Data Exchange (ETDEWEB)

    Fleming, J.; Ostdiek, B. [Jones Graduate School of Management, Rice University, MS 531, P.O. Box 1892 Houston, TX (United States)

    1999-04-01

    We examine the effects of energy derivatives trading on the crude oil market. There is a common public and regulatory perception that derivative securities increase volatility and can have a destabilizing effect on the underlying market. Consistent with this view, we find an abnormal increase in volatility for three consecutive weeks following the introduction of NYMEX crude oil futures. While there is also evidence of a longer-term volatility increase, this is likely due to exogenous factors, such as the continuing deregulation of the energy markets. Subsequent introductions of crude oil options and derivatives on other energy commodities have no effect on crude oil volatility. We also examine the effects of derivatives trading on the depth and liquidity of the crude oil market. This analysis reveals a strong inverse relation between the open interest in crude oil futures and spot market volatility. Specifically, when open interest is greater, the volatility shock associated with a given unexpected increase in volume is much smaller. (Copyright (c) 1999 Elsevier Science B.V., Amsterdam. All rights reserved.)

  20. Microbial degradation of resins fractionated from Arabian light crude oil

    International Nuclear Information System (INIS)

    Venkateswaran, K.; Hoaki, T.; Kato, M.; Maruyama, T.

    1995-01-01

    Sediment samples from the Japanese coasts were screened for microorganisms able to degrade resin components of crude oil. A mixed population that could degrade 35% of 5000 ppm resin in 15 days was obtained. This population also metabolized 50% of saturates and aromatics present in crude oil (5000 ppm) in 7 days. A Pseudomonas sp., isolated from the mixed population, emulsified and degraded 30% of resins. It also degraded saturates and aromatics (30%) present in crude oil (5000 ppm). These results were obtained from Iatroscan analysis. Degradation of crude oil was also analyzed by gas chromatography (GC). The peaks corresponding to known aliphatic hydrocarbons in crude oil greatly decreased within the first two days of incubation in the cultures of the RY-mixed population and of Pseudomonas strain UN3. Aromatic compounds detected as a broad peak by GC were significantly degraded at day 7 by Pseudomonas strain UN3, and at day 15 by the RY-mixed population. Investigations are ongoing to determine the genetic basis for the ability of these organisms to grow on the resin fractions of crude oil as a sole source of carbon and energy. 28 refs., 4 figs., 1 tab

  1. The impact of energy derivatives on the crude oil market

    International Nuclear Information System (INIS)

    Fleming, J.; Ostdiek, B.

    1999-01-01

    We examine the effects of energy derivatives trading on the crude oil market. There is a common public and regulatory perception that derivative securities increase volatility and can have a destabilizing effect on the underlying market. Consistent with this view, we find an abnormal increase in volatility for three consecutive weeks following the introduction of NYMEX crude oil futures. While there is also evidence of a longer-term volatility increase, this is likely due to exogenous factors, such as the continuing deregulation of the energy markets. Subsequent introductions of crude oil options and derivatives on other energy commodities have no effect on crude oil volatility. We also examine the effects of derivatives trading on the depth and liquidity of the crude oil market. This analysis reveals a strong inverse relation between the open interest in crude oil futures and spot market volatility. Specifically, when open interest is greater, the volatility shock associated with a given unexpected increase in volume is much smaller. (Copyright (c) 1999 Elsevier Science B.V., Amsterdam. All rights reserved.)

  2. Behavior of asphaltene model compounds at w/o interfaces.

    Science.gov (United States)

    Nordgård, Erland L; Sørland, Geir; Sjöblom, Johan

    2010-02-16

    Asphaltenes, present in significant amounts in heavy crude oil, contains subfractions capable of stabilizing water-in-oil emulsions. Still, the composition of these subfractions is not known in detail, and the actual mechanism behind emulsion stability is dependent on perceived interfacial concentrations and compositions. This study aims at utilizing polyaromatic surfactants which contains an acidic moiety as model compounds for the surface-active subfraction of asphaltenes. A modified pulse-field gradient (PFG) NMR method has been used to study droplet sizes and stability of emulsions prepared with asphaltene model compounds. The method has been compared to the standard microscopy droplet counting method. Arithmetic and volumetric mean droplet sizes as a function of surfactant concentration and water content clearly showed that the interfacial area was dependent on the available surfactant at the emulsion interface. Adsorption of the model compounds onto hydrophilic silica has been investigated by UV depletion, and minor differences in the chemical structure of the model compounds caused significant differences in the affinity toward this highly polar surface. The cross-sectional areas obtained have been compared to areas from the surface-to-volume ratio found by NMR and gave similar results for one of the two model compounds. The mean molecular area for this compound suggested a tilted geometry of the aromatic core with respect to the interface, which has also been proposed for real asphaltenic samples. The film behavior was further investigated using a liquid-liquid Langmuir trough supporting the ability to form stable interfacial films. This study supports that acidic, or strong hydrogen-bonding fractions, can promote stable water-in-oil emulsion. The use of model compounds opens up for studying emulsion behavior and demulsifier efficiency based on true interfacial concentrations rather than perceived interfaces.

  3. Using the fluorescence of DBO to study the aggregation of asphaltenes

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Zixin; Bohne, Cornelia [Department of Chemistry, University of Victoria (Canada)], email: xyang@uvic.ca

    2010-07-01

    Asphaltene, operationally defined as the fraction of bitumen that is insoluble in heptane but soluble in toluene, is the least characterized component of crude oil. It can aggregate at low concentrations, causing problems in the reservoir and during transport and processing. Fluorescence techniques have been employed to characterize asphaltenes, e.g. by adding external probes. DBO (2,3-diazabicyclo [2.2.2]oct-2-ene), a fluorescence probe molecule with a long fluorescence lifetime, was made sensitive to the presence of aliphatic C-H bonds. DBO was used as an external fluorescent probe to characterize the aggregation of Athabasca asphaltene. The lifetime of DBO was measured using single photon counting. Preliminary lifetime measurements show that AA-5 quenches the emission of DBO, leading to a shortening of the DBO lifetime. The abrupt decrease in lifetime may be related to the interaction of DBO with the AA-5 aggregate; further studies are being performed to test this hypothesis. In conclusion, DBO interacts with asphaltene components and has the potential for being used as a probe to study the asphaltene aggregation.

  4. Standard guide for determining corrosivity of crude oils

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2010-01-01

    1.1 This guide presents some generally accepted laboratory methodologies that are used for determining the corrosivity of crude oil. 1.2 This guide does not cover detailed calculations and methods, but rather a range of approaches that have found application in evaluating the corrosivity of crude oil. 1.3 Only those methodologies that have found wide acceptance in crude oil corrosivity evaluation are considered in this guide. 1.4 This guide does not address the change in oil/water ratio caused by accumulation of water at low points in a pipeline system. 1.5 This guide is intended to assist in the selection of methodologies that can be used for determining the corrosivity of crude oil under conditions in which water is present in the liquid state (typically up to 100°C). These conditions normally occur during oil and gas production, storage, and transportation in the pipelines. 1.6 This guide does not cover the evaluation of corrosivity of crude oil at higher temperatures (typically above 300°C) that oc...

  5. Application of alkaline waterflooding to a high acidity crude oil

    Energy Technology Data Exchange (ETDEWEB)

    Sayyouh, M.H. (King Sand Univ., Riyadh (SA). Petroleum Engineering Dept.); Abdel-Waly, A.; Osman, A. (Cairo Univ. (EG). Petroleum Engineering Dept.); Awara, A.Z. (Geisum Oil Company, Cairo (EG))

    The enhanced recovery of a high acidity crude oil (South Geisum crude) by alkaline solutions is studied. Acidity, interfacial tension, and contact angle, were investigated. Displacement tests were carried out to study the effect of alkaline slug concentration, slug size, oil alkali type, temperature and viscosity on recovery. The interfacial tension between crude oil and formation water decreases with increasing alkaline concentration until a minimum, after which it increases again. Contact angle measurements indicated oil-wetting conditions that increase by the addition of alkaline solutions. At the early stages of displacement, oil recovery increases with increasing alkaline concentration until a maximum at 4% by weight NaOH concentration. Also, at such early stages, an excessive increase in alkaline concentration results in lower oil recovery. On the other hand, after the injection of many pore volumes of water, oil recovery is almost the same regardless of the alkaline concentration. Oil recovery increases with increasing alkaline slug size until a maximum at 15% PV. Sodium hydroxide slugs produce more oil recovery than sodium carbonate slugs. Oil recovery increases with increasing temperature (from 25 to 55{sup 0}C) and decreasing oil viscosity.

  6. Enhanced crude oil biodegradation in soil via biostimulation.

    Science.gov (United States)

    Al-Saleh, Esmaeil; Hassan, Ali

    2016-08-02

    Research on feasible methods for the enhancement of bioremediation in soil contaminated by crude oil is vital in oil-exporting countries such as Kuwait, where crude oil is a major pollutant and the environment is hostile to biodegradation. This study investigated the possibility of enhancing crude oil bioremediation by supplementing soil with cost-effective organic materials derived from two widespread locally grown trees, Conocarpus and Tamarix. Amendments in soils increased the counts of soil microbiota by up to 98% and enhanced their activity by up to 95.5%. The increase in the biodegradation of crude oil (75%) and high levels of alkB expression substantiated the efficiency of the proposed amendment technology for the bioremediation of hydrocarbon-contaminated sites. The identification of crude-oil-degrading bacteria revealed the dominance of the genus Microbacterium (39.6%), Sphingopyxis soli (19.3%), and Bordetella petrii (19.6%) in unamended, Conocarpus-amended, and Tamarix-amended contaminated soils, respectively. Although soil amendments favored the growth of Gram-negative bacteria and reduced bacterial diversity, the structures of bacterial communities were not significantly altered.

  7. Dispersed catalysts for transforming extra heavy crude oil into transportable upgraded crude: phase identification

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, S.; Canizales, E.; Machin, I. [Gerencia Depttal de Investigacion Estrategica en Refinacion PDVSA Intevep (Venezuela); Segovia, X.; Rivas, A.; Lopez, E.; Pena, J.P.; Rojas, J.D.; Sardella, R. [Gerencia Depttal de Infraestructura y Mejoramiento en Faja Petrolifera PDVSA Intevep (Venezuela)

    2011-07-01

    A new technology to convert extra heavy crude oil into transportable upgraded crude has been developed. A water/oil emulsion composed of steam and catalyst precursors is introduced in the feed which then generates unsupported dispersed catalyst in situ under thermal decomposition. The aim of this paper is to characterize the particles. The study was conducted in a laboratory and on a pilot scale on three different vacuum residues using high resolution transmission electron microscopy and a transmission electron microscope. Results showed that the particles were formed by oxides and inorganic sulphur based in transition metals and their sizes ranged between 5 and 120 nm; in addition, good dispersion was observed. This study demonstrated that the process involved in the generation of dispersed catalyst is extremely complex and showed that further work with heavy crude oils and its residua is required to understand the mechanisms involved.

  8. Release of Crude Oil from Silica and Calcium Carbonate Surfaces

    DEFF Research Database (Denmark)

    Liu, Xiaoyan; Yan, Wei; Stenby, Erling Halfdan

    2016-01-01

    Adsorption and desorption of a North Sea crude oil to silica and calcium carbonate surfaces were studied by a quartz crystal microbalance, while the bare surfaces and adsorbed oil layers were characterized by atomic force microscopy and contact angle measurements. Water contact angles were measured...

  9. Evaluation of nano emulsion containing asphaltenes dispersant additive in dehydration of oil; Avaliacao de nanoemulsoes contendo aditivo dispersante de asfaltenos na desidratacao de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Priscila F. de; Rodrigues, Jessica S.; Mansur, Claudia R.E. [Universidade Federal do Rio de Janeiro/ Instituto de Macromoleculas/ Laboratorio de Macromoleculas e Coloides na Industria de Petroleo, Rio de Janeiro, RJ (Brazil)], e-mail: prisfrias@hotmail.com

    2011-07-01

    Due to the problem of the formation of emulsions type water-oil during oil production, new alternatives of the breakdown of these emulsions have been proposed over the years. Several polymers have been used to destabilize these emulsions and among them are those based on polyphenylene ether. The aim of this study was to develop nanoemulsions type oil / water, where an asphaltenes dispersant additive was dissolved in dispersed phase in order to evaluate them as a new alternative in the breakdown of oil emulsions. The nanoemulsions were prepared in the presence of surfactant based on polyoxide using a high pressure homogenizer (HPH). We obtained stable nanoemulsions for more than 30 days in the presence or absence of additive. These nanoemulsions were effective in water /oil phase separation, and the nanoemulsion containing the dispersant additive provided a faster separation of these phases. (author)

  10. US crude oil, natural gas, and natural gas liquids reserves

    International Nuclear Information System (INIS)

    1992-01-01

    This report presents estimates of proved reserves of crude oil, natural gas, and natural gas liquids as of December 31, 1991, as well as production volumes for the United States, and selected States and State subdivisions for the year 1991. Estimates are presented for the following four categories of natural gas: total gas (wet after lease separation), its two major components (nonassociated and associated-dissolved gas), and total dry gas (wet gas adjusted for the removal of liquids at natural gas processing plants). In addition, two components of natural gas liquids, lease condensate and natural gas plant liquids, have their reserves and production data presented. Also included is information on indicated additional crude oil reserves and crude oil, natural gas, and lease condensate reserves in nonproducing reservoirs. A discussion of notable oil and gas exploration and development activities during 1991 is also presented

  11. Biodegradation of crude oil in different types of marine sediment

    International Nuclear Information System (INIS)

    Hii, Y.S.; Law, A.T.

    1999-01-01

    An active oil-oxidizing bacterium, named Nap C was isolated from the sediment sample of Port Dickson coastal area for this study. Nap C is a gram negative, rod shape marine bacterium. It forms spore when the condition is not favorable. Three different types of treated marine sediment; sand, silt and clay were used in this study. The degradation of Malaysian Tapis A crude oil in the different types of marine sediment were assessed. Silt type of marine sediment was found to sustain highest biodegradation compared to clay type and sand type. 8.6.67% of the Malaysian Tapis A crude oil was degraded in silt type of marine sediment within 10 days of incubation. Where as there were only 60% and 73% of the Malaysian Tapis A crude oil was degraded in sand and clay type of marine sediment respectively. Microbial biomass estimation in the sediment was estimated by indirect phospholipid enumeration technique. (author)

  12. Characteristics of bicyclic sesquiterpanes in crude oils and petroleum products.

    Science.gov (United States)

    Yang, Chun; Wang, Zhendi; Hollebone, Bruce P; Brown, Carl E; Landriault, Mike

    2009-05-15

    This study presents a quantitative gas chromatography-mass spectrometry analysis of bicyclic sesquiterpanes (BSs) in numerous crude oils and refined petroleum products including light and mid-range distillate fuels, residual fuels, and lubricating oils collected from various sources. Ten commonly recognized bicyclic sesquiterpanes were determined in all the studied crude oils and diesel range fuels with principal dominance of BS3 (C(15)H(28)), BS5 (C(15)H(28)) and BS10 (C(16)H(30)), while they were generally not detected or in trace in light fuel oils like gasoline and kerosene and most lubricating oils. Laboratory distillation of crude oils demonstrated that sesquiterpanes were highly enriched in the medium distillation fractions of approximately 180 to 481 degrees C and were generally absent or very low in the light distillation fraction (boiling point to approximately 180 degrees C) and the heavy residual fraction (>481 degrees C). The effect of evaporative weathering on a series of diagnostic ratios of sesquiterpanes, n-alkanes, and biomarkers was evaluated with two suites of weathered oil samples. The change of abundance of sesquiterpanes was used to determine the extent of weathering of artificially evaporated crude oils and diesel. In addition to the pentacyclic biomarker C(29) and C(30) alphabeta-hopane, C(15) and C(16) sesquiterpanes might be alternative internal marker compounds to provide a direct way to estimate the depletion of oils, particularly diesels, in oil spill investigations. These findings may offer potential applications for both oil identification and oil-source correlation in cases where the tri- to pentacyclic biomarkers are absent due to refining or environmental weathering of oils.

  13. Heavy crude oils - From Geology to Upgrading - An Overview

    International Nuclear Information System (INIS)

    Huc, A.Y.

    2010-01-01

    Heavy oils, extra-heavy oils and tar sands are major players for the future of energy. They represent a massive world resource, at least the size of conventional oils. They are found all over the world but Canada and Venezuela together account, by themselves, for more than half of world deposits. They share the same origin as the lighter conventional oils, but their geological fate drove them into thick, viscous tar-like crude oils. Most of them result from alteration processes mediated by microbial degradation. They are characterized by a low content of lighter cuts and a high content of impurities such as sulfur and nitrogen compounds and metals; so, their production is difficult and deployment of specific processes is required in order to enhance their transportability and to upgrade them into valuable products meeting market needs, and honouring environmental requirements. Although these resources are increasingly becoming commercially producible, less than 1% of total heavy crude oil deposits worldwide are under active development. The voluntarily wide scope of this volume encompasses geology, production, transportation, upgrading, economics and environmental issues of heavy oils. It does not pretend to be exhaustive, but to provide an authoritative view of this very important energy resource. Besides presenting the current status of knowledge and technology involved in exploiting heavy oils, the purpose is to provide an insight into technical, economic and environmental challenges that should be taken up in order to increase the efficiency of production and processing, and finally to give a prospective view of the emerging technologies which will contribute to releasing the immense potential reserves of heavy oil and tar deposits. Contents: Part 1. Heavy Crude Oils.1. Heavy Crude Oils in the Perspective of World Oil Demand. 2. Definitions and Specificities. 3. Geological Origin of Heavy Crude Oils. 4. Properties and composition. Part 2. Reservoir Engineering

  14. Does Portuguese economy support crude oil conservation hypothesis?

    International Nuclear Information System (INIS)

    Bashiri Behmiri, Niaz; Pires Manso, José R.

    2012-01-01

    This paper examines cointegration relationships and Granger causality nexus in a trivariate framework among oil consumption, economic growth and international oil price in Portugal. For this purpose, we employ two Granger causality approaches: the Johansen cointegration test and vector error correction model (VECM) and the Toda–Yamamoto approaches. Cointegration test proves the existence of a long run equilibrium relationship among these variables and VECM and Toda–Yamamoto Granger causality tests indicate that there is bidirectional causality between crude oil consumption and economic growth (feed back hypothesis). Therefore, the Portuguese economy does not support crude oil conservation hypothesis. Consequently, policymakers should consider that implementing oil conservation and environmental policies may negatively impact on the Portuguese economic growth. - Highlights: ► We examine Granger causality among oil consumption, GDP and oil price in Portugal. ► VECM and Toda–Yamamoto tests found bidirectional causality among oil and GDP. ► Portuguese economy does not support the crude oil conservation hypothesis.

  15. EVALUATION OF CORROSION COST OF CRUDE OIL PROCESSING INDUSTRY

    Directory of Open Access Journals (Sweden)

    ADESANYA A.O.

    2012-08-01

    Full Text Available Crude oil production industry as the hub of Nigeria Economy is not immune to the global financial meltdown being experienced world over which have resulted in a continual fall of oil price. This has necessitated the need to reduce cost of production. One of the major costs of production is corrosion cost, hence, its evaluation. This research work outlined the basic principles of corrosion prevention, monitoring and inspection and attempted to describe ways in which these measures may be adopted in the context of oil production. A wide range of facilities are used in crude oil production making it difficult to evaluate precisely the extent of corrosion and its cost implication. In this study, cost of corrosion per barrel was determined and the annualized value of corrosion cost was also determined using the principles of engineering economy and results analyzed using descriptive statistics. The results showed that among the corrosion prevention methods identified, the use of chemical treatment gave the highest cost contribution (81% of the total cost of prevention while coating added 19%. Cleaning pigging and cathodic protection gave no cost. The contribution of corrosion maintenance methods are 60% for repairs and 40% for replacement. Also among the corrosion monitoring and inspection identified, NDT gave the highest cost contribution of 41% of the total cost, followed by coating survey (34%. Cathodic protection survey and crude analysis gives the lowest cost contribution of 19% and 6% respectively. Corrosion control cost per barrel was found to be 77 cent/barrel. The significance of this cost was not much due to high price of crude oil in the international market. But the effect of corrosion in crude oil processing takes its toll on crude oil production (i.e. deferment.

  16. Isolation and identification of an ester from a crude oil

    Science.gov (United States)

    Phillips, H.F.; Breger, I.A.

    1958-01-01

    A dioctylphthalate has been isolated from a crude oil by means of adsorption column chromatography. The ester was identified by means of elemental analysis, refractive index, and its infra-red absorption spectrum. Saponification of the isolate and examination of the resultant alcohol by means of infrared absorption spectra led to the conclusion that the ester is a branched chain dioctylphthalate. This is the first reported occurrence of an ester in crude petroleum. ?? 1958.

  17. OPEC announcements and their effects on crude oil prices

    International Nuclear Information System (INIS)

    Lin, Sharon Xiaowen; Tamvakis, Michael

    2010-01-01

    We investigate evidence on the effects of OPEC announcements on world oil prices by examining announcements from both official conferences and ministerial meetings on major international crudes, including the key benchmarks and several other heavy and light grades. With data from 1982 to 2008, we use event study methodology and find differentiation in the magnitude and significance of market responses to OPEC quota decisions under different price bands. We also find some (weak) evidence of differentiation between light and heavy crude grades. (author)

  18. Identification of CYP1A inducing compounds in crude oil

    Energy Technology Data Exchange (ETDEWEB)

    Khan, C.W.; Hodson, P.V. [Queen' s Univ., Kingston, ON (Canada). Dept. of Biology; Hollebone, B.P.; Wang, Z. [Environment Canada, Ottawa, ON (Canada). Environmental Technology Advancement Directorate; Brown, R.S. [Queen' s Univ., Kingston, ON (Canada). Dept. of Chemistry

    2004-07-01

    One of the major sources of polycyclic aromatic hydrocarbons (PAHs) in aquatic ecosystems is crude oil. PAHs are responsible for developmental malformations in the early life stages of fish. The induction of CYP1A enzyme is characteristic of developmental toxicity caused by crude oil. As such, it is an effective biomarker of PAH uptake. It is not known which PAHs cause toxicity because of the complex chemical composition of crude oil. In this study, an approach called Toxicity Identification and Evaluation (TIE) was used with different crude oils to separate bioavailable PAHs into petroleum sub-fractions. The extent of CYP1A induction in rainbow trout was measured after 48 hour exposures to each fraction. Low temperature vacuum distillation was used to create white gas, kerosene, coal tar/bitumen and wax fractions. Hepatic CYP1A activity was induced by whole oil and some fractions. The highest PAH concentration was found in the coal tar/bitumen fraction which accounted for most CYP1A induction in whole oil. The wax fraction also caused moderate CYP1A induction, but the white gas fraction did not cause any CYP1A induction. The hypothesis that alkyl PAH may be the most significant source of CYP1A inducers in the coal tar/bitumen fraction was supported by chemical analysis of CYP1A induction potency. Results showed that benzo[a]pyrene accounts for nearly all of the CYP1A induction caused by the wax fraction.

  19. Global economic activity and crude oil prices. A cointegration analysis

    International Nuclear Information System (INIS)

    He, Yanan; Wang, Shouyang; Lai, Kin Keung

    2010-01-01

    This paper empirically investigates the cointegrating relationship between crude oil prices and global economic activity. The Kilian economic index is used as an indicator of global economic activity. Based on a supply-demand framework and the cointegration theory, we find that real futures prices of crude oil are cointegrated with the Kilian economic index and a trade weighted US dollar index, and crude oil prices are influenced significantly by fluctuations in the Kilian economic index through both long-run equilibrium conditions and short-run impacts. We also develop an empirically stable, data-coherent and single-equation error-correction model (ECM) which has sensible economic properties. Empirical results based on the ECM show that the adjustment implied by a permanent change in the Kilian economic index is a relatively drawn-out process. (author)

  20. In-Situ Burning of Crude Oil on Water

    DEFF Research Database (Denmark)

    van Gelderen, Laurens

    in the small scale water basin. Boilovers were also observed during the burning of a heavy crude oil with a substantial light fraction without a water layer, however, which suggests that water is not essential for boilover occurrence. Further studies are required to determine the conditions under which......The fire dynamics and fire chemistry of in-situ burning of crude oil on water was studied in order to improve predictions on the suitability of this oil spill response method. For this purpose, several operational parameters were studied to determine the factors that control the burning efficiency...... of in-situ burning, i.e. the amount of oil (in wt%) removed from the water surface by the burning process. The burning efficiency is the main parameter for expressing the oil removal effectiveness of in-situ burning as response method and is thus relevant for suitability predictions of in-situ burning...

  1. Liquid ultrasonic flow meters for crude oil measurement

    Energy Technology Data Exchange (ETDEWEB)

    Kalivoda, Raymond J.; Lunde, Per

    2005-07-01

    Liquid ultrasonic flow meters (LUFMs) are gaining popularity for the accurate measurement of petroleum products. In North America the first edition of the API standard ''Measurement of liquid hydrocarbons by ultrasonic flow meters using transit time technology'' was issued in February 2005. It addresses both refined petroleum products and crude oil applications. Its field of application is mainly custody transfer applications but it does provide general guidelines for the installation and operation of LUFM's other applications such as allocation, check meters and leak detection. As with all new technologies performance claims are at times exaggerated or misunderstood and application knowledge is limited. Since ultrasonic meters have no moving parts they appear to have fewer limitations than other liquid flow meters. Liquids ultrasonic flow meters, like turbine meters, are sensitive to fluid properties. It is increasingly more difficult to apply on high viscosity products then on lighter hydrocarbon products. Therefore application data or experience on the measurement of refined or light crude oil may not necessarily be transferred to measuring medium to heavy crude oils. Before better and more quantitative knowledge is available on how LUFMs react on different fluids, the arguments advocating reduced need for in-situ proving and increased dependency on laboratory flow calibration (e.g. using water instead of hydrocarbons) may be questionable. The present paper explores the accurate measurement of crude oil with liquid ultrasonic meters. It defines the unique characteristics of the different API grades of crude oils and how they can affect the accuracy of the liquid ultrasonic measurement. Flow testing results using a new LUFM design are discussed. The paper is intended to provide increased insight into the potentials and limitations of crude oil measurement using ultrasonic flow meters. (author) (tk)

  2. Imported resources - oil crude oil processing in the Czech Republic and its prospectives

    Energy Technology Data Exchange (ETDEWEB)

    Soucek, I.; Ottis, I. [Kaucuk, Kralupy nad Vitavou (Czechoslovakia)

    1995-12-01

    This paper examines the availability of various crude oils, addressing specifically crude oil pipelines to the Czech Republic, both existing and under construction. Secondly, the economic status of two main Czech refineries is examined in comparison to international trends, technical configurations, and product supply and demand.

  3. The influence of magnetic fields on crude oils viscosity

    Energy Technology Data Exchange (ETDEWEB)

    Goncalves, Jose L.; Bombard, Antonio J. F. [Universidade Federal de Itajuba (UNIFEI), Itajuba, MG (Brazil). Instituto de Ciencias Exatas. Lab. de Reologia

    2009-07-01

    The crystallization of paraffin causes serious problems in the process of transportation of petroleum. This phenomenon increases the crude oil viscosity and implies an organic resin accumulation on pipeline wall, resulting in a reduced flux area or totally blocked pipes. One of the most challenging tasks for pipeline maintenance is solving this problem at low cost. Therefore, a method that inhibits the crystallization of paraffin and reduces the viscosity of crude oil could have many useful applications within the petroleum industry. Recent studies showed that magnetic fields reduce the Wax Appearance Temperature (WAT) and the viscosity of paraffin-based crude oil. For better understanding of this discovery, a series of tests was performed. This paper will show the influence of a DC magnetic field on rheological proprieties of three crude oils with different paraffin concentrations: a crude oil sample with 11 % p/p of paraffin concentration (sample 1); a crude oil sample with 6 % p/p of paraffin concentration (sample 2); a mixture of paraffin plus light crude oil with a total of 11 % p/p of paraffin concentration. These samples were placed in an electromagnet that generates a magnetic field of 1.3 Tesla. The samples' temperatures were conditioned around their Wax Appearance Temperature (WAT), and they were exposed to the field. As the viscosity of crude oil is very sensitive to the changes in temperature, it was ensured that the temperature has remained constant throughout the process. The sample 1 revealed a considerable reduction of viscosity: its original viscosity was 66 cP before magnetic field exposure, after that its viscosity was reduced to 39 cP. The other samples showed the same viscosity, before and after the magnetic field exposure. Since the samples 1 and 3 have the same paraffin concentrations, the viscosity reduction is not due only to the presence of paraffin; there must be other factors responsible for the interaction of sample 1 with the

  4. Isolation of CYP1A inducing components in coal tar fraction (F3) of Alaska north slope crude oil : a preliminary study

    Energy Technology Data Exchange (ETDEWEB)

    Saravanabhavan, G.; Brown, R.S. [Queen' s Univ., Kingston, ON (Canada). Dept. of Chemistry; Khan, C.W.; Hodson, P.V. [Queen' s Univ., Kingston, ON (Canada). Dept. of Biology

    2004-07-01

    Recent concerns regarding the effects of weathered crude oil on the early life stage of aquatic organisms are related to reports that blue sac disease (BSD) has been linked to larval fish exposed to crude oil. Studies have shown that a relationship exists between the induction of CYP1A enzymes and the occurrence of BSD in fish species. However, the mechanism of BSD is not fully understood. This study contributed to the Toxicity Identification and Evaluation (TIE) approach by isolating the CYP1A enzyme. An improved separation and analysis method for characterizing crude oil was also developed. Earlier studies revealed that the highest CYP1A activity occurred in the coal tar fraction of crude oil, which is rich in polycyclic aromatic hydrocarbons (PAH) and which contains many classes of compounds such as waxes, asphaltenes and resins. The TIE method included separation of these compound classes as well as a detailed characterization of the PAH classes. A solvent extraction method was also developed to fractionate the coal tar fraction into compound classes with particular emphasis on isolating PAH components. The study showed that fractions rich in PAH were responsible for a significant CYP1A induction in juvenile trout, but fractions poor in PAH did not. The solid phase extraction method offered better PAH fractions for further analysis by liquid chromatography.

  5. Breakthrough Adsorption Study of Crude Oil Removal Using Buffing Dust

    Science.gov (United States)

    Setyaningsih, L. W. N.; Yuliansyah, A. T.; Prasetyo, A.; Arimanintan, S. K.; Putri, D. R.

    2018-05-01

    The utilization of leather industry solid waste as adsorbent to separate oil from water emulsions of surfactant flooding process is a solution that is relatively inexpensive. This study was conducted aiming to obtain a mathematical model that is appropriate for the adsorption process of crude oil by buffing dust in emulsion phase with a continuous adsorption method. Variations in the column adsorption experiments were carried out, such as: flow rate of feed of water-crude oil-surfactant, the concentration of crude oil in the feed, and mass of adsorbent used. Data were evaluated using three models: Adams Bohart, Thomas and Yan. Best results are obtained on the following conditions, the feed flow rate of 60 mL/minute, the crude oil concentration in feed is 1.5% volume and the mass of adsorbent used was 10 g. The values of kinetic constant and adsorption capacity obtained from Yan Model was 21.7774 mL/mg/minute and 220.9581 mg/g with the relative error obtained is 5.4424%.

  6. Seahorse (Hippocampus reidi) as a bioindicator of crude oil exposure.

    Science.gov (United States)

    Delunardo, Frederico Augusto Cariello; de Carvalho, Luciano Rodrigues; da Silva, Bruno Ferreira; Galão, Michel; Val, Adalberto Luís; Chippari-Gomes, Adriana R

    2015-07-01

    This study explored the suitability of the seahorse Hippocampus reidi (Ginsburg, 1933) for assessing biomarkers of genotoxic effects and its use as a sentinel organism to detect the effects of acute exposure to petroleum hydrocarbons. Fish were exposed to three concentrations of crude oil (10, 20 and 30 g/kg) for 96 h, and the activity of phase II biotransformation enzyme glutathione S-transferase (GST) was measured. In addition, we performed genotoxicity assays, such as comet assay, micronucleus (MN) test and nuclear abnormalities (NA) induction, on the erythrocytes of the fish species. Our results revealed that the inhibition of hepatic GST activity in H. reidi was dependent on increasing crude oil concentrations. In contrast, an increase in the damage index (DI) and MN frequency were observed with increased crude oil concentrations. These results indicate that the alkaline comet assay and micronucleus test were suitable and useful in the evaluation of the genotoxicity of crude oil, which could improve determinations of the impact of oil spills on fish populations. In addition, H. reidi is a promising "sentinel organism" to detect the genotoxic impact of petroleum hydrocarbons. Copyright © 2015 Elsevier Inc. All rights reserved.

  7. Canadian crude oil production and supply forecast 2006-2020

    International Nuclear Information System (INIS)

    2006-05-01

    In order to enable members to plan for pipeline capacity requirements for transporting Canadian crude oil to markets, the Canadian Association of Petroleum Producers (CAPP) 2006-2020 crude oil production and supply forecast provides a long-range outlook of Canadian crude oil production. It provides a forecast of supply and demand for both western and eastern Canada. Because offshore eastern oil production does not rely on pipeline access to reach markets, the analysis primarily focuses on western Canadian production and supply. Over the next fifteen years, Alberta's oil sands provides the main source of growth in the western Canadian production forecast. A survey of CAPP members encompassing all oil sands projects was conducted. Survey responses reflect both planned and envisioned projects over a fifteen year period, although some of the envisioned projects have been risk adjusted by modifying the potential completion schedules for projects which are deemed more uncertain. Detailed tables are provided on forecast data. Three sets of tables are included to show production, two supply scenarios and a high level assessment of the need for incremental pipeline capacity. The report also discusses delays and risk factors that could slow the pace of oil sands development and the corresponding increase in production being forecast in the base case. 16 tabs

  8. Effects of Crude Oil and Oil Products on Growth of Some Edible ...

    African Journals Online (AJOL)

    The vegetative growth response of three local edible mushrooms: Pleurotus pulmonarius (Pp), Pleurotus tuber-regium (Pt) and Lentinus squarrosulus (Ls) on different concentrations of Crude oil (COIL), Automotive Gasoline Oil (AGO), Fresh Engine Oil (ENGOIL) and Spent Engine Oil (SENGOIL) was investigated. The result ...

  9. Explaining crude oil prices using fundamental measures

    International Nuclear Information System (INIS)

    Coleman, Les

    2012-01-01

    Oil is the world's most important commodity, and improving the understanding of drivers of its price is a longstanding research objective. This article analyses real oil prices during 1984–2007 using a monthly dataset of fundamental and market parameters that cover financial markets, global economic growth, demand and supply of oil, and geopolitical measures. The innovation is to incorporate proxies for speculative and terrorist activity and dummies for major industry events, and quantify price impacts of each. New findings are positive links between oil prices and speculative activity, bond yields, an interaction term incorporating OPEC market share and OECD import dependence, and the number of US troops and frequency of terrorist attacks in the Middle East. Shocks also prove significant with a $6–18 per barrel impact on price for several months. - Highlights: ► Article introduces new variables to the study of oil prices. ► New variables are terrorist incidents and military activity, and oil futures market size. ► Shocks prove important affecting prices by $6–18 per barrel for several months. ► OPEC market influence rises with OECD import dependence.

  10. CRUDE OIL TRANSPORT FROM THE CASPIAN SEA REGION TO EUROPE

    Directory of Open Access Journals (Sweden)

    Adam Przybyłowski

    2014-07-01

    Full Text Available In the contemporary world, despite the growing importance and scale of the use of renewable energy , conventional energy resources still play a huge role. The European Union countries are dependent on the oil imports and the their main supplier of crude oil and natural gas has been the Russian Federation. After the collapse of the Soviet Union , the Caspian Sea region has become an alternative to Russian energy resources. The Unit-ed States , European Union, China and many other countries have shown their interest about this region. Despite a relatively large oil and natural gas reserves, the export of the-se commodities to the West is still problematic. Based on the available data and infor-mation, the publication explores the issue of energy resources transport directions with a particular emphasis on the crude oil from the Caspian Sea region to Europe.

  11. A novel apparatus for long term weathering of crude oils

    International Nuclear Information System (INIS)

    Berger, D.; Lun, R.; Skogen, E.; Ooijen, H. Van; Mackay, D.

    1993-01-01

    A novel apparatus is under development for exposing oil in the laboratory to prolonged weathering. The apparatus is mechanically simple and robust and involves contacting oil with water and air, and possibly with solar radiation, under controlled conditions of salinity and turbulence. The principle of operation is that the oil rests on the concave surface of water, which is held in a cylindrical glass vessel and rotated at 33 rpm. The oil is agitated by a fixed stirrer which has a variable pitch. Three oils were studied: Canadian Environmenal Protection Service standard, Kuwait crude, and Prudhoe Bay crude. Gas chromatographic analysis of the oil revealed the expected changes in composition due to evaporation, and purge and trap analysis of the water in contact with the oil determined the nature and concentration of the dissolved hydrocarbons. The apparatus also proved successful for testing the formation of water-in-oil emulsions. It is hoped that the system will contribute to an improved understanding of the mechanisms involved in the long term weathering processes which occur when oil is spilled at sea. 11 refs., 10 figs., 1 tab

  12. Performance of Diesel Engine Using Blended Crude Jatropha Oil

    Science.gov (United States)

    Kamarudin, Kamarul Azhar; Mohd Sazali, Nor Shahida Akma; Mohd Ali, Mas Fauzi; Alimin, Ahmad Jais; Khir, Saffiah Abdullah

    2010-06-01

    Vegetable oil presents a very promising alternative to diesel oil since it is renewable and has similar properties to the diesel. In view of this, crude jatropha oil is selected and its viscosity is reduced by blending it with diesel. Since jatropha oil has properties which are similar to mineral diesel, it can be used in compression ignition engines without any engine modification. This paper presents the results of investigation carried out on a four-cylinder, four strokes and indirect-injection diesel engine. The engine, operated using composition blends of crude jatropha oil and diesel, were compared with mineral diesel. An experimental investigation has been carried out to analyze the performance characteristics of a compression ignition engine from the blended fuel (5%, 10%, 20% and 30%). A naturally aspirated four-stroke indirect injection diesel engine was tested at full load conditions, speeds between 1000 and 3500 rpm with intervals of 500 rpm. Results obtained from the measures of torque, power, specific fuel consumptions, thermal efficiency and brake mean effective pressure are nearly the same between blended and diesel fuel. An overall graph shows that the performance of relevant parameters from blended fuel is most likely similar to the performance produced from diesel. The experimental results proved that the use of crude jatropha oil in compression ignition engines is a viable alternative to diesel.

  13. The dynamic linkages between crude oil and natural gas markets

    International Nuclear Information System (INIS)

    Batten, Jonathan A.; Ciner, Cetin; Lucey, Brian M.

    2017-01-01

    The time varying price spillovers between natural gas and crude oil markets for the period 1994 to 2014 are investigated. Contrary to earlier research, we show that in a large part of our sample the natural gas price leads the price of crude oil with price spillover effects lasting up to two weeks. This result is robust to a battery of tests including out-of-sample forecasting exercises. However, after 2006, we detect little price dependencies between these two energy commodities. These findings arise due to a conjunction of both demand and supply-side shocks arising from both natural and economic events, including Hurricane Katrina, the Tohoku earthquake and the Global Financial Crisis, as well as infrastructure and technological improvements. The increased use of new technologies such as hydraulic fracking for the extraction of gas and oil in particular affected supply in the latter part of the study. We conclude that the long term relation present in the early part of the sample has decoupled, such that price determination of these two energy sources is now independent. - Highlights: • Contrary to earlier research we find natural gas may lead crude oil prices over a long sample. • This finding holds in forecasting out of sample. • There may be a break in the relationship between oil and gas in 2006. • We suggest that new technologies and financial conditions have led to a decoupling of these markets. • Oil and natural gas prices may now be determined independently.

  14. Assessment of antioxidant indices after incorporating crude oil ...

    African Journals Online (AJOL)

    They were divided into six groups of five rats each as follows: group 1: control, group 2: rats fed crude petroleum oil contaminated catfish diet (CPO-CCD) only, group 3: ... Administration of MWE, MEE and MDEE to the rats fed CPO-CCD significantly (p<0.05) increased the level of blood GSH, blood GSSG, SOD, CAT and ...

  15. Acute Toxicological Effects of Crude Oil On Haematological And ...

    African Journals Online (AJOL)

    The acute toxicological effects of Brass blend of crude oil on the haemoglobin concentration, and Liver functions in the Guinea pig were studied. 25 Guinea pigs divided into five animals per group were used for the study. They were divided into 5 groups. One group served as a control group, while the others received ...

  16. Evaluation of soil microbial communities as influenced by crude oil ...

    African Journals Online (AJOL)

    Impact of petroleum pollution in a vulnerable Niger Delta ecosystem was investigated to assess interactions in a first-generation phytoremediation site of a crude oil freshly-spilled agricultural soil. Community-level approach for assessing patterns of sole carbon-source utilization by mixed microbial samples was employed to ...

  17. Crude oil metabolites in groundwater at two spill sites

    Science.gov (United States)

    Bekins, Barbara A.; Cozzarelli, Isabelle M.; Erickson, Melinda L.; Steenson, Ross; Thorn, Kevin A.

    2016-01-01

    Two groundwater plumes in north central Minnesota with residual crude oil sources have 20 to 50 mg/L of nonvolatile dissolved organic carbon (NVDOC). These values are over 10 times higher than benzene and two to three times higher than Diesel Range Organics in the same wells. On the basis of previous work, most of the NVDOC consists of partial transformation products from the crude oil. Monitoring data from 1988 to 2015 at one of the sites located near Bemidji, MN show that the plume of metabolites is expanding toward a lakeshore located 335 m from the source zone. Other mass balance studies of the site have demonstrated that the plume expansion is driven by the combined effect of continued presence of the residual crude oil source and depletion of the electron accepting capacity of solid phase iron oxide and hydroxides on the aquifer sediments. These plumes of metabolites are not covered by regulatory monitoring and reporting requirements in Minnesota and other states. Yet, a review of toxicology studies indicates that polar metabolites of crude oil may pose a risk to aquatic and mammalian species. Together the results suggest that at sites where residual sources are present, monitoring of NVDOC may be warranted to evaluate the fates of plumes of hydrocarbon transformation products.

  18. Assessment and bioremediation of heavy metals from crude oil ...

    African Journals Online (AJOL)

    The assessment of the levels of heavy metals present in crude oil contaminated soil and the application of the earthworm - Hyperiodrilus africanus with interest on the bioremediation of metals from the contaminated soil was investigated within a 90-days period under laboratory conditions. Selected heavy metals such as ...

  19. Bioremediation of a crude oil polluted tropical rain forest soil ...

    African Journals Online (AJOL)

    These results suggest that Biostimulation with tilling (nutrient enhanced in-situ bioremediation) and or the combination ofBiostimulation and Bioaugumentation with indigenous hydrocarbon utilizers would be effective in the remediation of crude oil polluted tropical soils. Key Words: Bioremediation, Bioaugumentation, ...

  20. Bioremediation potential of crude oil spilled on soil

    International Nuclear Information System (INIS)

    McMillen, S.J.; Young, G.N.; Davis, P.S.; Cook, P.D.; Kerr, J.M.; Gray, N.R.; Requejo, A.G.

    1995-01-01

    Spills sometimes occur during routine operations associated with exploration and production (E and P) of crude oil. These spills at E and P sites typically are small, less than 1 acre (0.4 ha), and the spill may be in remote locations. As a result, bioremediation often represents a cost-effective alternative to other cleanup technologies. The goal of this study was to determine the potential for biodegrading a range of crude oil types and determining the effect of process variables such as soil texture and soil salinity. Crude oils evaluated ranged in American Petroleum institute (API) gravity from 14 degree to 45 degree. The extent of biodegradation was calculated from oxygen uptake data and the total extractable material (TEM) concentration. Based on the data collected, a simple model was developed for predicting the bioremediation potential of a range of crude oil types. Biodegradation rates were significantly lower in sandy soils. Soil salinities greater than approximately 40 mmhos/cm adversely impacted soil microbial activity and biodegradation rate

  1. Bioremediation of a Crude Oil Polluted Tropical Mangrove ...

    African Journals Online (AJOL)

    A combination of bioaugumentation with hydrocarbon utilizing indigenous bacteria, biostimulation with agricultural fertilizer (NPK 15:15:15) and tilling were employed as remedial options for 20 weeks in a crude oil polluted tidal plain dominated by mangrove (Rhizophora, Laguncularia and Avicenia) vegetation. Soil ...

  2. Socio–economic and environmental impact of crude oil exploration ...

    African Journals Online (AJOL)

    Socio–economic and environmental impact of crude oil exploration and production on agricultural production: a case study of Edjeba and Kokori communities in Delta State of ... The results also showed an increase in the occurrence of health hazard, air/noise pollution and heightened deforestation in these communities.

  3. The phytoremediation of crude oil-polluted aquatic environment by ...

    African Journals Online (AJOL)

    A phytoremediation experiment was carried out in the Department of Wildlife and Fisheries Management, University of Ibadan, Nigeria to examine the ability of water hyacinth (Eichhornia crassipes) to detoxify crude oil-polluted aquatic environments. There were fifteen (15) experimental units; twelve (12) had water hyacinth ...

  4. Forecasting Value-at-Risk for Crude-Oil Exposures

    DEFF Research Database (Denmark)

    Høg, Esben; Tsiaras, Leonidas

    2009-01-01

    The purpose of this paper is to forecast and evaluate Value-At-Risk for crude-oil exposures. We examine the performance of a GARCH-type based model with lagged implied volatility entering the variance equation as explanatory variable for the predicted variance. The forecasted Values-at...

  5. Impact of Crude-Oil Spillage Pollution and Chemical Remediation ...

    African Journals Online (AJOL)

    Michael Horsfall

    significantly (p≤0.01) higher than the level of degradation, except in infiltration rate. Soil pH increased by 26% .... volumes of water were added into the containers on day six. As the days ... crude oil spillage reduced soil moisture availability or.

  6. World resources of crude oil and natural gas

    Energy Technology Data Exchange (ETDEWEB)

    Masters, C.D.; Root, D.H.; Attanasi, E.D. (Geological Survey, Reston, VA (United States))

    1991-01-01

    An abstract is given of a paper presented at the World Petroleum Congress 1991 on the world estimates of identified reserves and undiscovered resources for crude oil, natural gas and natural gas liquids. Data are presented for Canada, Mexico, USA, South America, Western Europe, Eastern Europe, USSR, Africa, Middle East, Asia/Oceania and Antartica. (UK).

  7. Clean technology for the crude palm oil industry in Thailand

    NARCIS (Netherlands)

    Chavalparit, O.

    2006-01-01

    The aims of this study were to assess the potential contribution of clean(er) technology to improve the environmental performance of the crude palm oil industry inThailand, to analyse implementation barriers for

  8. (maize) to a crude oil polluted agricultural soil

    African Journals Online (AJOL)

    SERVER

    2007-06-04

    Jun 4, 2007 ... aiding the activities of the large numbers of microbes ... math of crude oil pollution of agricultural soils to forestall the adverse effects induced .... International Institute of Tropical Agriculture (I.I.T.A) manual series. No. 1, Ibadan ...

  9. (A. Chev.) Stevels) Exposed to Crude Oil Contaminated Soil

    African Journals Online (AJOL)

    Six accessions of cultivated Okra (Abelmoschuscaillei (A. Chev.) Stevels) and Abelmoschusesculentus (L.) Moench) were evaluated using growth parameters in crude oil contaminated soil. Seeds were collected from collected from Nigerian Institute of Horticulture (NIHORT), Ibadan and from home gardens in Benin City.

  10. Efficacy of intervention strategies for bioremediation of crude oil in ...

    African Journals Online (AJOL)

    The search for the solution to ameliorate the seemingly unending pollution and its side effects necessitated the evaluation on the effect of bioaugmentation, biostimulation and natural attenuation of crude oil pollution in soil microcosms. The bacterial species selected for this study (Bacillus thuringensis strain LG32 and ...

  11. Distribution and geochemical application of aromatic hydrocarbons in crude oils

    International Nuclear Information System (INIS)

    Asif, M.; Tahira, F.

    2007-01-01

    Distribution of aromatic hydrocarbons was studied in a set of crude oils, five from northern Indus basin of potwar area and two from southern Indus basin. Diaromatic and triaromatic hydrocarbons were separated from highly complex mixture of sedimentary organic matter by using liquid chromatography techniques such as column chromatography, TLC and GC-FID. These classes of compounds were identified to alkylated isomers of naphthalenes and phenanthrenes by using reference chromatograms and literature data. High concentration of di-,tri- and tetra-methyl naphthalenes was observed in all crude oils except Kal. The relative increase in concentration of alkyl naphthalenes was found as moved to higher methyl substituted isomers. This suggests that they are the product of sedimentary alkylation reactions during catagensis and metagensis. The significant concentration of methyl phenanthrenes indicated source of organic matter. High levels of both 1-MP and 9-MP showed marine and terrestrial source of organic matter except Umer crude oil which is most likely to have terrestrial origin. The ratios of beta-substituted to the alpha-substituted isomers of both alkyl naphthalenes and alkyl phenanthrene were used to assess the thermal maturity of sedimentary organic matter, which revealed high maturity level of Dhurnal, Pindori, Badin and Toot crude oils. (author)

  12. Crude Oil Corrosion Fatigue of L485MB Pipeline Steel

    Czech Academy of Sciences Publication Activity Database

    Gajdoš, Lubomír; Šperl, Martin; Bystrianský, J.

    2015-01-01

    Roč. 137, č. 5 (2015), 051401 ISSN 0094-9930 R&D Projects: GA TA ČR(CZ) TE02000162 Institutional support: RVO:68378297 Keywords : corrosion fatigue * crude oil * pipeline steel * S–N curve * separated water Subject RIV: JI - Composite Materials Impact factor: 0.476, year: 2015 http://pressurevesseltech.asmedigitalcollection.asme.org/article.aspx?articleID=2107675

  13. Measuring efficiency of international crude oil markets: A multifractality approach

    Science.gov (United States)

    Niere, H. M.

    2015-01-01

    The three major international crude oil markets are treated as complex systems and their multifractal properties are explored. The study covers daily prices of Brent crude, OPEC reference basket and West Texas Intermediate (WTI) crude from January 2, 2003 to January 2, 2014. A multifractal detrended fluctuation analysis (MFDFA) is employed to extract the generalized Hurst exponents in each of the time series. The generalized Hurst exponent is used to measure the degree of multifractality which in turn is used to quantify the efficiency of the three international crude oil markets. To identify whether the source of multifractality is long-range correlations or broad fat-tail distributions, shuffled data and surrogated data corresponding to each of the time series are generated. Shuffled data are obtained by randomizing the order of the price returns data. This will destroy any long-range correlation of the time series. Surrogated data is produced using the Fourier-Detrended Fluctuation Analysis (F-DFA). This is done by randomizing the phases of the price returns data in Fourier space. This will normalize the distribution of the time series. The study found that for the three crude oil markets, there is a strong dependence of the generalized Hurst exponents with respect to the order of fluctuations. This shows that the daily price time series of the markets under study have signs of multifractality. Using the degree of multifractality as a measure of efficiency, the results show that WTI is the most efficient while OPEC is the least efficient market. This implies that OPEC has the highest likelihood to be manipulated among the three markets. This reflects the fact that Brent and WTI is a very competitive market hence, it has a higher level of complexity compared against OPEC, which has a large monopoly power. Comparing with shuffled data and surrogated data, the findings suggest that for all the three crude oil markets, the multifractality is mainly due to long

  14. Down-hole catalytic upgrading of heavy crude oil

    Energy Technology Data Exchange (ETDEWEB)

    Weissman, J.G.; Kessler, R.V.; Sawicki, R.A.; Belgrave, J.D.M.; Laureshen, C.J.; Mehta, S.A.; Moore, R.G.; Ursenbach, M.G. [University of Calgary, Calgary, AB (Canada). Dept. of Chemical and Petroleum Engineering

    1996-07-01

    Several processing options have been developed to accomplish near-well bore in-situ upgrading of heavy crude oils. These processes are designed to pass oil over a fixed bed of catalyst prior to entering the production well, the catalyst being placed by conventional gravel pack methods. The presence of brine and the need to provide heat and reactant gases in a down-hole environment provide challenges not present in conventional processing. These issues were addressed and the processes demonstrated by use of a modified combustion tube apparatus. Middle-Eastern heavy crude oil and the corresponding brine were used at the appropriate reservoir conditions. In-situ combustion was used to generate reactive gases and to drive fluids over a heated sand or catalysts bed, simulating the catalyst contacting portion of the proposed processes. The heavy crude oil was found to be amenable to in-situ combustion at anticipated reservoir conditions, with a relatively low air requirement. Forcing the oil to flow over a heated zone prior to production results in some upgrading of the oil, as compared to the original oil, due to thermal effects. Passing the oil over a hydroprocessing catalyst located in the heated zone results in a product that is significantly upgraded as compared to either the original oil or thermally processed oil. Catalytic upgrading is due to hydrogenation and the results in about a 50% sulfur removal and an 8{degree} API gravity increase. Additionally, the heated catalyst was found to be efficient at converting CO to additional H{sub 2}. While all of the technologies needed for a successful field trial of in-situ catalytic upgrading exist, a demonstration has yet to be undertaken. 27 refs., 5 figs., 5 tabs.

  15. Crude oil prices : how high, how much harm?

    International Nuclear Information System (INIS)

    Levesque, M.; Alexander, C.

    2002-01-01

    This paper discussed the issue of crude oil prices and the economy. Crude oil prices are on the rise due to the recent events in the Middle East. In early April, West Texas Intermediate crude oil climbed to nearly US$28 a barrel. Most of the increase reflects the expectation of stronger world oil demand combined with supply constraints on the part of OPEC. Although there has been some concern expressed that rising oil prices may hinder economic recovery, the authors of this report do not see evidence that rising oil prices would throw economic recovery off course, arguing that the current spike will be short-lived. They stated that even under a worse-case scenario where prices remain inflated, there is little reason to fear for the health of the Canadian economy. OPEC is expected to increase its low production quotas in June. In addition, non-OPEC nations (Russia in particular) are expected to increase oil production in the coming months. The authors also indicated that it is unlikely that conflict in the West Bank will disrupt oil supply because Israel is not an oil-exporting nation. However, oil supply could be affected if other Arab nations were drawn into the issue. It was also noted that military action against Iraq would increase oil prices, possibly as high as US$40 a barrel, but the full extent of this hike in price will probably be unsustainable. In addition, the authors emphasized that the increase in energy costs would not be enough to seriously jeopardize the economic recovery in the United States. As for Canada, it is estimated that a US$10 per barrel increase in crude oil prices would have a small, but positive impact on Canadian GDP because in contrast to the United States, Canada produces much more energy than it consumers. In 2001, Canada ran a trade surplus of $2.8 billion. The report ended by stating that although higher oil prices could add a full percentage point to headline inflation by the end of the year, core inflation is likely to remain

  16. The response of Scirpus pungens to crude oil contaminated sediments

    International Nuclear Information System (INIS)

    Longpre, D.; Jaouich, A.; Jarry, V.; Venosa, A.D.; Lee, K.; Suidan, M.T.

    1999-01-01

    An exposure study was conducted to determine the impacts of an oil spill on the plant Scirpus pungens and to determine potential recovery rates of the species in the event of an accidental spill within the St. Lawrence River. Scirpus pungens is an important wetland plant which is essential for control of coastal erosion and which provides a unique habitat for a variety of biota. Sediments contaminated with medium-light crude oil were used in this study. Transplants in oiled and unoiled sediments were maintained in greenhouses to monitor changes in plant height, growth and mortality over a 63 day period. Results showed that plants exposed to high concentrations of oiled sediment were much smaller than those exposed to lightly contaminated sediments. Elevated oil concentrations greatly decreased plant biomass. Mortality was highly correlated with oil concentration. Transplants were able to survive, grow and produce new shoots in sediments contaminated with crude oil in a range of concentrations comparable to those associated with oil spills

  17. The response of Scirpus pungens to crude oil contaminated sediments

    Energy Technology Data Exchange (ETDEWEB)

    Longpre, D; Jaouich, A [Quebec Univ., Montreal, PQ (Canada); Jarry, V [Environment Canada, Montreal, PQ (Canada); Venosa, A D [US Environmental Protection Agency, Cincinnati, OH (United States). National Risk Management Research Lab.; Lee, K [Fisheries and Oceans Canada, Mont Joli, PQ (Canada). Inst. Maurice Lamontagne; Suidan, M T [Cincinnati Univ., Cincinnati, OH (United States). Dept. of Civil and Environmental Engineering

    1999-01-01

    An exposure study was conducted to determine the impacts of an oil spill on the plant Scirpus pungens and to determine potential recovery rates of the species in the event of an accidental spill within the St. Lawrence River. Scirpus pungens is an important wetland plant which is essential for control of coastal erosion and which provides a unique habitat for a variety of biota. Sediments contaminated with medium-light crude oil were used in this study. Transplants in oiled and unoiled sediments were maintained in greenhouses to monitor changes in plant height, growth and mortality over a 63 day period. Results showed that plants exposed to high concentrations of oiled sediment were much smaller than those exposed to lightly contaminated sediments. Elevated oil concentrations greatly decreased plant biomass. Mortality was highly correlated with oil concentration. Transplants were able to survive, grow and produce new shoots in sediments contaminated with crude oil in a range of concentrations comparable to those associated with oil spills.

  18. Expediting the chemistry of hematite nanocatalyst for catalytic aquathermolysis of heavy crude oil

    Science.gov (United States)

    Khalil, Munawar

    .e. thiophene at considerably mild condition. Based on the analyses, it is suggested that the catalytic mechanism involves a cyclic phase transformation of some hematite surfaces into magnetite as thiophene was oxidatively decomposed to produce maleic acid, SO2 and CO2. However, in the presence of water as the source of active oxygen, these magnetite surfaces could be reconstructed back into hematite surfaces. In addition, it is also found that the catalytic activity of hematite can be improved by changing its surface property from hydrophilic into slightly more hydrophobic. However, further improvement on hydrophobicity reduces the activity due to the blockage of the catalytic site. Finally, when both bare and surface-modified hematite nanocatalysts were used in aquathermolysis reaction of heavy crude oil sample, the viscosity of heavy oil sample was significantly decreased by 61.52% and 74.33%, respectively. In addition, the quality of heavy oil can also be upgraded as the amount of saturated and aromatic fractions were significantly increased while asphaltene and resin fractions were reduced.

  19. Molecular processes in the biodegradation of crude oils and crude oil products in the natural reservoir and in laboratory experiments

    International Nuclear Information System (INIS)

    Schalenbach, S.S.

    1993-10-01

    Two ains were pursued in the present study; first, to find positive indicators of the onset of biodegradation of reservoir oil wherever other parameters fail to give a clear picture; second, to establish a basic understanding of the molecular processes underlying the biodegradation of hydrocarbons and thus create a starting point for finding better criteria for valuating biological restoration methods for crude oil contaminated soils. (orig./HS) [de

  20. Crude oil prices: Robust demands strengthens outlook

    International Nuclear Information System (INIS)

    Simmons, M.R.

    1996-01-01

    This paper briefly summarizes the growth in the global demand for oil products by showing the historical trends in production and demand in developing countries. It shows world incremental production growth from 1985 to 1995 and developing countries's demands from 1971 to 1989. The paper goes on to make predictions as to whether the demand growth rate can be sustained. It provides information on the status of the world offshore drilling and production facilities to determine the capacity of this resource

  1. Investigation of alkaline–crude oil reaction

    Directory of Open Access Journals (Sweden)

    James J. Sheng

    2015-03-01

    In this paper, this mechanism and related issues are discussed, analyzed or quantified. In particular, the numerical simulation approach is used. The results show that only a fraction of acid components can be converted into soap; the amount of generated soap could be low. A minimum pH (e.g. 9 is needed for the acids to be converted to soap. The literature information on the effect of amount of acid components (total acid number on oil recovery is also discussed.

  2. Modélisation de la combustion de fuels lourds prenant en compte la dispersion des asphaltènes Modeling Heavy Fuel-Oil Combustion (While Considering Or Including Asphaltene Dispersion

    Directory of Open Access Journals (Sweden)

    Audibert F.

    2006-11-01

    difficultés relevant du mode d'exploration et de la non adéquation entre les structures asphalténiques et fractales. On a finalement opté pour une détermination visuelle s'appuyant sur les clichés sur lesquels les agglomérats d'asphaltènes sont clairement visualisés tels qu'ils sont dans le fuel. Ce mode d'exploration laborieux a cependant permis de déterminer un modèle construit sur une série de 25 fuels dont 10 ont été brûlés sur une chaudière de 2 MW, et 15 sur un four de 100 kW. Ce modèle fait intervenir les teneurs en carbone Conradson et en métaux, ainsi que le taux de dispersion des asphaltènes. Le perfectionnement des moyens d'exploration aidant, on peut s'attendre à ce que soient disponibles des techniques d'évaluation de la dispersion sur les clichés. Ce paramètre pourra alors être pris en considération pour une meilleure prédiction de résultats de combustion insuffisamment expliqués avec les paramètres classiques. Various models aiming to predict the amount of unburned particles (solids during heavy fuel-oil combustion have been developed. The parameters taken into consideration are generally asphaltenes precipitated by normal heptane or pentane and Conradson carbon as well as the metals content having a known catalytic effect on cenosphere combustion in the combustion chamber. The Exxon and Shell models can be mentioned, which were developed respectively in 1979 and 1981 (Chapter II. Other models also give consideration to the fuel-oil composition, the way it is atomized and diffused in the chamber and the combustion kinetics (research done by the MIT Energy Laboratory published in 1986. However, the above parameters are not the only ones involved. For some fuel oils, experience has shown that the state of dispersion of asphaltenes may also play an important role particularly for combustion installations with mechanical injection for which the dispersion of fuel-oil droplets is not very great and does not affect the structures built

  3. Rheological Behaviour of Water-in-Light Crude Oil Emulsion

    Science.gov (United States)

    Husin, H.; Taju Ariffin, T. S.; Yahya, E.

    2018-05-01

    Basically, emulsions consist of two immiscible liquids which have different density. In petroleum industry, emulsions are undesirable due to their various costly problems in term of transportation difficulties and production loss. A study of the rheological behaviour of light crude oil and its mixture from Terengganu were carried out using Antoon Paar MCR 301 rheometer operated at pressure of 2.5 bar at temperature C. Water in oil emulsions were prepared by mixing light crude oil with different water volume fractions (20%, 30% and 40%). The objectives of present paper are to study the rheological behaviour of emulsion as a fuction of shear rate and model analysis that fitted with the experimental data. The rheological models of Ostwald-De-Waele and Herschel-Bulkley were fitted to the experimental results. All models represented well the rheological data, with high values for the correlation coefficients. The result indicated that variation of water content influenced shear rate-shear stress rheogram of the prepared emulsions. In the case of 100% light crude oil, the study demonstrated non-Newtonian shear thickening behavior. However, for emulsion with different volume water ratios, the rheological behaviour could be well described by Herschel-Bulkley models due to the present of yield stress parameter (R2 = 0.99807). As a conclusion, rheological studies showed that volume water ratio have a great impact on the shear stress and viscosity of water in oil emulsion and it is important to understand these factors to avoid various costly problems.

  4. The US gasoline situation and crude oil prices

    International Nuclear Information System (INIS)

    Anon.

    2004-01-01

    Before and during the United States' summer driving season, concern over the country's gasoline supply can potentially influence the direction of the petroleum market. There are three causes of concern: a persistent lack of gasoline-producing capacity; a patchwork of as many as 18 different kinds of gasoline specifications; and the introduction of stringent new specifications for reformulated gasoline. However, gasoline stocks should be able to meet the needs of this year's driving season, at a time of ample crude oil availability, with strong imports. But, unplanned outages in the US logistics system and refining centres, or major disruptions in external gasoline supplies, could trigger price spikes that would, in turn, lead to frequently stronger crude oil prices, especially with the observed robust oil demand growth in China. (Author)

  5. Microbial ecology of a crude oil contaminated aquifer

    Science.gov (United States)

    Bekins, B.A.; Cozzarelli, I.M.; Warren, E.; Godsy, E.M.

    2002-01-01

    Detailed microbial analyses of a glacial outwash aquifer contaminated by crude oil provide insights into the pattern of microbial succession from iron reducing to methanogenic in the anaerobic portion of the contaminant plume. We analysed sediments from this area for populations of aerobes, iron reducers, fermenters and methanogens, using the most probable number method. On the basis of the microbial data the anaerobic area can be divided into distinct physiological zones dominated by either iron-reducers or a consortium of fermenters and methanogens. Chemistry and permeability data show that methanogenic conditions develop first in areas of high hydrocarbon flux. Thus, we find methanogens both in high permeability horizons and also where separate-phase crude oil is present in either the saturated or unsaturated zone. Microbial numbers peak at the top of the separate-phase oil suggesting that growth is most rapid in locations with access to both hydrocarbons and nutrients infiltrating from the surface.

  6. Crude oil and natural gas supplies and demands for Denmark

    International Nuclear Information System (INIS)

    Mackay, R.M.; Probert, S.D.

    1995-01-01

    A novel technique for forecasting the supply and extraction life-cycle of a depleting fossil fuel resource has been developed. The supply side utilises a 'skewed-normal production-profile' model that yields a better representation than earlier approaches. A simple model for extrapolating crude oil and natural gas demands has also been devised, based on the so called 'modified logit function'. The predicted crude oil and natural gas balances for the period up to AD 2010 indicate the disparity between indigenous production and future consumption for Denmark. These forecasts depend on current estimates of remaining oil and gas reserves. It will consequently be necessary to revise periodically the present projections as more reliable reserve estimates become available. (author)

  7. Detection of genetically modified soybean in crude soybean oil.

    Science.gov (United States)

    Nikolić, Zorica; Vasiljević, Ivana; Zdjelar, Gordana; Ðorđević, Vuk; Ignjatov, Maja; Jovičić, Dušica; Milošević, Dragana

    2014-02-15

    In order to detect presence and quantity of Roundup Ready (RR) soybean in crude oil extracted from soybean seed with a different percentage of GMO seed two extraction methods were used, CTAB and DNeasy Plant Mini Kit. The amplifications of lectin gene, used to check the presence of soybean DNA, were not achieved in all CTAB extracts of DNA, while commercial kit gave satisfactory results. Comparing actual and estimated GMO content between two extraction methods, root mean square deviation for kit is 0.208 and for CTAB is 2.127, clearly demonstrated superiority of kit over CTAB extraction. The results of quantification evidently showed that if the oil samples originate from soybean seed with varying percentage of RR, it is possible to monitor the GMO content at the first stage of processing crude oil. Copyright © 2013 Elsevier Ltd. All rights reserved.

  8. On Boiling of Crude Oil under Elevated Pressure

    Science.gov (United States)

    Pimenova, Anastasiya V.; Goldobin, Denis S.

    2016-02-01

    We construct a thermodynamic model for theoretical calculation of the boiling process of multicomponent mixtures of hydrocarbons (e.g., crude oil). The model governs kinetics of the mixture composition in the course of the distillation process along with the boiling temperature increase. The model heavily relies on the theory of dilute solutions of gases in liquids. Importantly, our results are applicable for modelling the process under elevated pressure (while the empiric models for oil cracking are not scalable to the case of extreme pressure), such as in an oil field heated by lava intrusions.

  9. Radiation doses and hazards from processing of crude oil at the Tema oil refinery in Ghana

    International Nuclear Information System (INIS)

    Darko, E. O.; Kpeglo, D. O.; Akaho, E. H. K.; Schandorf, C.; Adu, P. A. S.; Faanu, A.; Abankwah, E.; Lawluvi, H.; Awudu, A. R.

    2012-01-01

    Processing of crude oil has been carried out in Ghana for more than four decades without measures to assess the hazards associated with the naturally occurring radionuclides in the raw and processed materials. This study investigates the exposure of the public to 226 Ra, 232 Th and 40 K in crude oil, petroleum products and wastes at the Tema oil refinery in Ghana using gamma-ray spectrometry. The study shows higher activity concentrations of the natural radionuclides in the wastes than the crude oil and the products with estimated hazard indices less than unity. The values obtained in the study are within recommended limits for public exposure indicating that radiation exposure from processing of the crude oil at the refinery does not pose any significant radiological hazard but may require monitoring to establish long-term effect on both public and workers. (authors)

  10. Radiation doses and hazards from processing of crude oil at the Tema oil refinery in Ghana.

    Science.gov (United States)

    Darko, E O; Kpeglo, D O; Akaho, E H K; Schandorf, C; Adu, P A S; Faanu, A; Abankwah, E; Lawluvi, H; Awudu, A R

    2012-02-01

    Processing of crude oil has been carried out in Ghana for more than four decades without measures to assess the hazards associated with the naturally occurring radionuclides in the raw and processed materials. This study investigates the exposure of the public to (226)Ra, (232)Th and (40)K in crude oil, petroleum products and wastes at the Tema oil refinery in Ghana using gamma-ray spectrometry. The study shows higher activity concentrations of the natural radionuclides in the wastes than the crude oil and the products with estimated hazard indices less than unity. The values obtained in the study are within recommended limits for public exposure indicating that radiation exposure from processing of the crude oil at the refinery does not pose any significant radiological hazard but may require monitoring to establish long-term effect on both public and workers.

  11. Separation of Asphaltenes by Polarity using Liquid-Liquid Extraction

    DEFF Research Database (Denmark)

    Andersen, Simon Ivar

    1997-01-01

    In order to investigate the nature of petroleum asphaltenes in terms of polarity a process was developed using initial liquid-liquid extraction of the oil phase followed by precipitation of the asphaltenes using n-heptane. The liquid-liquid extraction was performed using toluene-methanol mixtures...... phase. The asphaltenes were analysed using FTir, Elemental analysis, and HPLC-SEC with a diode array detector. With increasing content of toluene in the methanol the molecular weight distribution of the asphaltenes significantly move to higher molecular weights. The content of nitrogen and sulfur...

  12. Islamic versus conventional stock market and its co-movement with crude oil: a wavelet analysis

    OpenAIRE

    Kamarudin, Eka Azrin; Masih, Mansur

    2015-01-01

    Crude oil market plays an important role in economic development and its price changes give huge impact to the financial markets. In this paper, the relationships between crude oil and stock markets are examined. This study has selected Malaysian Islamic and conventional stock markets as a case study. Financialisation of crude oil and its frequent inclusion into investment portfolios warrant an analysis of the relationship between crude oil and stock market indices at various time scales or i...

  13. Can reserve additions in mature crude oil provinces attenuate supply-side peak oil?

    Energy Technology Data Exchange (ETDEWEB)

    Okullo, Samuel; Reynes, Frederic

    2010-09-15

    More often, oil supply has been modeled on the basis of resource availability and demand. The impact of strategy between oil producers has largely been ignored or overly simplified. In this paper, we formulate a model that embodies a weak and strong OPEC for varied rates of reserve additions. With this economic equilibrium model which has the capability to generate a supply side peak in oil production, we show that although reserves of conventional crude oil may seem abundant. OPEC has the ability to lead to substantial crude oil reserve depletion in non-OPEC countries by 2050 given likely depletion rates.

  14. Improving the Forecasting Accuracy of Crude Oil Prices

    Directory of Open Access Journals (Sweden)

    Xuluo Yin

    2018-02-01

    Full Text Available Currently, oil is the key element of energy sustainability, and its prices and economy have a strong mutual influence. Modeling a good method to accurately predict oil prices over long future horizons is challenging and of great interest to investors and policymakers. This paper forecasts oil prices using many predictor variables with a new time-varying weight combination approach. In doing so, we first use five single-variable time-varying parameter models to predict crude oil prices separately. Second, every special model is assigned a time-varying weight by the new combination approach. Finally, the forecasting results of oil prices are calculated. The results show that the paper’s method is robust and performs well compared to random walk.

  15. World market of crude oil - review of possible scenarios of forecasting for the crude oil price movement

    International Nuclear Information System (INIS)

    Janevski, Risto

    2003-01-01

    Throughout most of 2002, crude oil prices were solidly within the range preferred by producers in the Organization of Petroleum Exporting Countries (OPEC), $22 to $28 per barrel for the OPEC 'basket price' (Fig. 1). OPEC producers have been demonstrating disciplined adherence to announced cutbacks in production. Early in 2003, a dramatic upward turn in crude oil prices was brought about by a combination of two factors. First, a general strike against the Chavez regime resulted in a sudden drop in Venezuela's oil exports. Although other OPEC producers agreed to increase production to make up for the lost Venezuelan output, the obvious strain on worldwide spare capacity kept prices high. Second, price volatility was exacerbated by fears of war in Iraq. (Original)

  16. Organic palladium and palladium-magnesium chemical modifiers in direct determination of lead in fractions from distillation of crude oil by electrothermal atomic absorption analysis

    Science.gov (United States)

    Kowalewska, Zofia; Bulska, Ewa; Hulanicki, Adam

    1999-05-01

    Platinum reforming catalysts are easily poisoned by increased levels of lead, therefore a sensitive atomic absorption spectrometric procedure for lead determination in fractions from crude oil distillation was developed. Lead was present in organic form in the samples analysed therefore the behaviour of various lead compounds (Pb-alkylarylsulphonate, Pb-4-cyclohexanobutyrate, tetraethyllead, Pb in fuel oil) was studied. The best procedure for the determination of lead in different petroleum products, including those containing asphaltenes includes a pretreatment with iodine and methyltrioctylammonium chloride, followed by the use of an organic Pd-Mg modifier. Under these conditions an effective matrix removal is possible at a pyrolysis temperature up to approximately 1100°C and the behaviour of lead present in different forms is unified. The characteristic mass is 11-12 pg Pb, corresponding to a detection limit of 0.25 ng g -1 for 20 μl sample solution. This can be lowered by multiple injection.

  17. An empirical analysis of the risk of crude oil imports in China using improved portfolio approach

    International Nuclear Information System (INIS)

    Wu, Gang; Wei, Yi-Ming; Fan, Ying; Liu, Lan-Cui

    2007-01-01

    This paper quantifies the diversification index of China's crude oil imports during the period 1996-2004, and explores the relationship between the monthly prices and Brent crude oil cash prices. Accordingly, we calculate the systematic and specific risks using portfolio theory of China's crude oil import over the period 1996-2004. Because China's crude oil import increased rapidly since 1996, we improve upon the traditional portfolio theory and develop a risk index model of portfolio theory for crude oil imports in order to explore objectively the changes in China's crude oil import risks. The results show that China's crude oil import risk is affected extensively by the fluctuation of international oil prices. So the traditional portfolio theory is insufficient to measure China's crude oil import risk. The improved portfolio theory risks index model reflects the effect of international oil prices, diversification, imports, and geopolitics factors etc., on crude oil import risk, and changes in crude oil import risk. Therefore, the risk index model of portfolio theory provides greater theoretical and methodological robustness as an indicator of China's crude oil import security than that offered from the application of traditional measures of dependence. (author)

  18. Biological treatment: Soil impacted with crude oil

    International Nuclear Information System (INIS)

    Gilbertson, N.; Severns, J.J.

    1992-01-01

    Biological land treatment proved to be a successful way to manage contamination at a California oil and gas production property. During the project, approximately 120,000 yards of contaminated soil was treated in the treatment plots to below the cleanup goals of 1,000 milligrams per kilograms (mg/kg) total petroleum hydrocarbons. In general, remaining hydrocarbon levels in treated soil were the 200 mg/kg total petroleum hydrocarbons range or lower. Cleanup goals were achieved in less than 2 months for each lift of soil treated. The treated soil was used as fill material in the excavation. No significant odor problems occurred during the project. Groundwater monitoring confirmed that no impact to groundwater occurred due to the biological land treatment process. Design of the treatment plan and regulatory requirements are also discussed

  19. Microbial ecology of methanogenic crude oil biodegradation; from microbial consortia to heavy oil

    Energy Technology Data Exchange (ETDEWEB)

    Head, Ian M.; Maguire, Michael J.; Sherry, Angela; Grant, Russell; Gray, Neil D.; Aitken, Carolyn M.; Martin Jones, D.; Oldenburg, Thomas B.P.; Larter, Stephen R. [Petroleum Research Group, Geosciences, University of Calgary (Canada)

    2011-07-01

    This paper presents the microbial ecology of methanogenic crude oil biodegradation. Biodegraded petroleum reservoirs are one of the most dramatic indications of the deep biosphere. It is estimated that heavy oil and oil sands will account for a considerable amount of energy production in the future. Carbon, a major resource for deep subsurface microorganisms, and energy are contained in large quantities in petroleum reservoirs. The aerobic to anaerobic paradigm shift is explained. A key process for in-situ oil biodegradation in petroleum reservoirs is methanogenesis. New paradigms for in-reservoir crude oil biodegradation are discussed. Variations in anaerobic degradation of crude oil hydrocarbons are also discussed. A graph shows the different patterns of crude oil biodegradation under sulfate-reducing and methanogenic conditions. Alternative anaerobic alkane activation mechanisms are also shown. From the study, it can be concluded that methanogenic crude oil degradation is of global importance and led to the establishment of the world's enormous heavy oil deposits.

  20. Study of the gelation behaviour of Brazilian waxy crude oils

    Energy Technology Data Exchange (ETDEWEB)

    Ziglio, C.M.; Sant' Ana, D.F. [Petroleo Brasileiro S.A., Petrobras, Rio de Janeiro (Brazil)

    2008-07-01

    The precipitation of wax from crude oil results in the formation of a paraffin network which evolves into a gel structure, causing a major operating issue for the petroleum industry. A gelled oil in a pipeline may need a very high re-start pressure that is beyond the capacity of the pump. The gelation of the oil can also develop into a wax deposit on the pipeline wall that restricts the flow of crude oil. Rheometry tests were used in this study to determine the yielding process of wax gels formed by the cooling of Brazilian crude oils. The effect of selected chemical additives on the gel strength was also examined. Dynamic rheology was used to study the oil-gel transition under quiescent conditions. Two rheological methods were used to study the gel yield stress, which is related to the gel strength. In the Creep and Recovery method, a stress was applied to the sample for a short period while the resulting deformation was measured. The stress was then removed to allow the sample to recover the gel structure. The steps of creep and recovery were repeated with an increasing stress value. The yield stress was identified as the minimum stress to cause an irreversible deformation in the sample. The yield stress of the gelled oil was estimated through dynamic measurements. Gel breakdown occurred when the sample was submitted to a critical strain, which is related to the yield stress value. This study showed that the gelation temperature can be reduced considerably by adding small amounts of readily available additives. These additives have an influence on yield stress values. In a cold re-start situation, they can reduce the pump pressure.

  1. Factors affecting future crude oil production in South East Asia

    International Nuclear Information System (INIS)

    Baugh, M.A.

    1996-01-01

    In the face of booming regional demand, crude oil production in the South East Asian region will decline from a 1996 peak of 5.7 million barrels a day to 3.5 million barrels a day in 2005 unless major new exploration investments are undertaken. The current fiscal terms for such investment will not attract continued significant funds to the region given the low crude price outlook, tough competitive global environment for the upstream industry, and the emergence of more attractive fiscal terms in politically and commercially stable countries with proven prospectivity. There is evidence from the emerging trend toward fiscal terms softening and differentiation around risk in some countries, that the commercial reality is becoming accepted. It remains to be seen if the various national political, bureaucratic and industry constituencies guiding these decisions within the region can respond decisively to mitigate the growing crude import dependency. (author). 2 tabs

  2. Problems in waterflooding fields containing paraffinic crude oils

    Energy Technology Data Exchange (ETDEWEB)

    Kovalev, A G; Lyutin, L V; Perevalov, V G

    1968-11-01

    When Caspian seawater is injected into the Uzen field reservoir, the temperature of the reservoir oil can be lowered 10/sup 0/ to 20/sup 0/C below initial reservoir temperature. Because Uzen crude oil is saturated with paraffin, the cold injection water can deposit paraffin in the formation and reduce oil recovery. In a related study, it was shown that the lower temperature should not adversely affect capillary and wettability behavior of the crude oil in the reservoir. Oil recovery was found to be essentially independent of water composition. However, fresh water is easier to handle in injection systems than brines. Several studies have shown that oil recovery from Uzen field should be increased by use of hot injection water. Various methods of heating the water are discussed. To reduce corrosivity and scaling of hot brine, sodium hexametaphosphate is added in concentrations of 2 to 15 mg/liter. It is concluded that it would be practical to use hot injection water in this field.

  3. Global market trade policy analysis for petroleum oils and oils obtained from bituminous minerals, crude

    Directory of Open Access Journals (Sweden)

    Bagheri, F.

    2012-01-01

    Full Text Available This article is based on surveying the custom tariffs imposed on the world export market of Petroleum Oils and Oils Obtained from Bituminous Minerals, Crude. We obtained the data according to the most updated available data provided online by UNCTAD and World Bank. The results indicate that none of the 142 countries in the world market of this product have imposed non-tariff trade barriers on the import of Petroleum Oils and Oils Obtained from Bituminous Minerals, Crude. The developed countries and the countries with transition economies are the main world import partners. European Union, United States, China, Japan, South Korea, Canada, Singapore, Taiwan, Thailand, South Africa, Australia, Turkey, Brazil, Sweden and Belarus are the examples and have imposed low custom tariffs on Petroleum Oils and Oils Obtained from Bituminous Minerals, Crude.

  4. Histopathologic lesions in sea otters exposed to crude oil

    Energy Technology Data Exchange (ETDEWEB)

    Lipscomb, T.P.; Harris, R.K.; Moeller, R.B.; Pletcher, J.M.; Haebler, R.J.; Ballachey, B.E. (Armed Forces Institute of Pathology, Washington, DC (United States))

    1993-01-01

    Following the Exxon Valdez oil spill in Prince William Sound, Alaska, sea otters (Enhydra lutris) that appeared to be contaminated with oil, that were in danger of becoming contaminated, or that were behaving abnormally were captured and taken to rehabilitation centers. Exposure to oil was assessed by visual examination when otters arrived at the centers. Degree of oil exposure was graded according to the following criteria: oil covering greater than 60% of the body--heavily contaminated; oil covering 30-60% of the body--moderately contaminated; oil covering less than 30% of the body or light sheen on fur--lightly contaminated. If there was no oil visible, otters were considered uncontaminated. Tissues from 51 oil-contaminated sea otters (14 males, 37 females) and from six uncontaminated sea otters (three males, three females) that died in rehabilitation centers were examined histologically. Among oil-contaminated sea otters, 19/46 had interstitial pulmonary emphysema, 13/40 had gastric erosion and hemorrhage, 11/47 had centrilobular hepatic necrosis, 14/47 had periportal to diffuse hepatic lipidosis, and 10/42 had renal tubular lipidosis. Of the uncontaminated sea otters, 1/6 had gastric erosion and hemorrhage and 1/6 had diffuse hepatic lipidosis. Histologic examinations were performed on tissues from five sea otters found dead with external oil present 15 to 16 days after the spill. Periportal hepatic lipidosis and renal tubular lipidosis were found in 3/5, and interstitial pulmonary emphysema was found in 1/5. Tissues from six apparently normal sea otters collected from an area not affected by an oil spill were examined histologically, and none of these lesions were found. We conclude that interstitial pulmonary emphysema, centrilobular hepatic necrosis, and hepatic and renal lipidosis of sea otters were associated with exposure to crude oil. Gastric erosion and hemorrhage may have been associated with stress of captivity and/or oil exposure.

  5. Histopathologic lesions in sea otters exposed to crude oil

    Science.gov (United States)

    Lipscomb, T.P.; Harris, R.K.; Moeller, R.B.; Pletcher, J.M.; Haebler, R.J.; Ballachey, Brenda E.

    1993-01-01

    Following the Exxon Valdez oil spill in Prince William Sound, Alaska, sea otters (Enhydra lutris) that appeared to be contaminated with oil, that were in danger of becoming contaminated, or that were behaving abnormally were captured and taken to rehabilitation centers. Exposure to oil was assessed by visual examination when otters arrived at the centers. Degree of oil exposure was graded according to the following criteria: oil covering greater than 60% of the body - heavily contaminated; oil covering 30–60% of the body - moderately contaminated; oil covering less than 30% of the body or light sheen on fur - lightly contaminated. If there was no oil visible, otters were considered uncontaminated. Tissues from 51 oil-contaminated sea otters (14 males, 37 females) and from six uncontaminated sea otters (three males, three females) that died in rehabilitation centers were examined histologically. Among oil-contaminated sea otters, 19/46 had interstitial pulmonary emphysema, 13/40 had gastric erosion and hemorrhage, 11/47 had centrilobular hepatic necrosis, 14/47 had periportal to diffuse hepatic lipidosis, and 10/42 had renal tubular lipidosis. Of the uncontaminated sea otters, 1/6 had gastric erosion and hemorrhage and 1/6 had diffuse hepatic lipidosis. Histologic examinations were performed on tissues from five sea otters (three males, two females) found dead with external oil present 15 to 16 days after the spill. Periportal hepatic lipidosis and renal tubular lipidosis were found in 3/5, and interstitial pulmonary emphysema was found in 1/5. Tissues from six apparently normal sea otters (four males, two females) collected from an area not affected by an oil spill were examined histologically, and none of these lesions were found. We conclude that interstitial pulmonary emphysema, centrilobular hepatic necrosis, and hepatic and renal lipidosis of sea otters were associated with exposure to crude oil. Gastric erosion and hemorrhage may have been associated with

  6. New contact system in crude oil desalting process

    International Nuclear Information System (INIS)

    Forero, J; Duque; Diaz, J; Nunez, A; Guarin, F; Carvajal, F

    2001-01-01

    The effect of the ICP contactor and the mixture valve on the desalting process was evaluated as a contact system in the crude oil washing process. The evaluation was carried out in the two desalters at the Cartagena refinery (GRC) and a desalter at the Barrancabermeja refinery (GCB) of ECOPETROL. The pressure drop was measured and the efficiency of the desalting processes, dehydration and hydrocarbon crude intake in the water was calculated based on the BS and W measurement, salt content and hydrocarbon concentration in the water. Results showed that the contactor improved desalting, water in the crude oil was reduced and crude carry-over in the wastewater was reduced between 50 and 92% at the Barrancabermeja refinery, and between 40 and 95% at the Cartagena refinery, which mean savings of approximately us$ 373.000 dollars per year at both refineries, due to the fact that less water is loaded into the process. Furthermore, hydrocarbon 1055 in wastewater was reduced by about 3650 barrels per year. The pressure drop was reduced between 88 and 94 % in relation to the mixing valve

  7. Causality Relationship between Crude Oil Variables and Budget Variables in Malaysia

    OpenAIRE

    Zakaria, Zukarnain; Shamsuddin, Sofian

    2017-01-01

    As an oil and gas exporter, Malaysia profited from higher world energy prices. However, the fall in oil prices from highs in 2014 significantly affected Malaysia’s government revenue (GR), hence its expenditure since the Malaysian GR still largely depends on oil revenues. Malaysia also has problems with high spending on energy subsidy, shrinking in its net crude oil export, and narrowing the gap between its crude oil production and consumption. Given this scenario, not only shocks in crude oi...

  8. Simultaneous cleanup of soil polluted with crude oil and heavy metals

    International Nuclear Information System (INIS)

    Groudeva, V.; Doycheva, A.; Groudev, S.

    2005-01-01

    Some soils in a site located in the Northwestern part of Bulgaria were heavily polluted with crude oil and some heavy metals (copper, zinc, cadmium, lead). The oil was light, with a specific gravity of about 0.8 g/cm 3 , rich in paraffins and with a very low content of asphaltene-resinous substances. The heavy metals were present mainly as the relevant sulphide minerals but products from the oxidation of sulphides were also present. The oil and the above-mentioned heavy metals were present mainly in the upper soil layers (mainly in the horizon A). Preliminary laboratory experiments in reactors and lysimeters revealed that it was possible to remove most of the contaminants in the soil by using the activity of the indigenous soil microflora. This activity was enhanced by suitable changes in the levels of some essential environmental factors such as pH and water, oxygen and nutrient contents of the soil. It was also found that the inoculation of the soil with active oil-degrading and metal-solubilizing microorganisms caused a considerable positive effect on the soil clean up. A pilot-scale operation for a simultaneous biological removal of the oil and heavy metals from the soil was carried out using the heap technique. Some data about this pilot-scale operation are presented in this paper. At the end of the treatment, the contents of pollutants in the soil were decreased below the permissible levels for soil of such type. At the same time, the chemical composition, structure and main physical and water properties of the soil were altered to a small extent, regardless of the fact that its pH was decreased to about 3.5. The addition of lime to the treated soil increased this pH to about 5.5 and in this way prevented the further acidification of the soil and the generation of acid drainage after rainfall. It must be noted that the removal of contaminants from the control heap was negligible, even after a period of about three years

  9. Cracking of crude oil in the molten metals

    Directory of Open Access Journals (Sweden)

    Marat A. Glikin

    2014-03-01

    Full Text Available In this paper is investigated the process of crude oil and its individual fractions cracking in the molten metals medium to produce light petroleum products. Thermodynamic calculations demonstrate the possibility of using lead and tin including alloys thereof as the melt. The cracking of West Siberian crude oil is studied at temperatures 400-600 °C. It is detected that as the temperature increases there is increase of aromatic hydrocarbons and olefins content in gasoline while naphthenes, n- and i-paraffins content reduces. Optimal temperature for cracking in molten metals is ~500 °C. The use of a submerged nozzle increases the yield of light petroleum products by ~2%. The research octane number of gasoline produced is 82-87 points. It is determined that the yield of light petroleum products depending on the experimental conditions is increased from 46.9 to 55.1-61.3% wt.   

  10. Wavelet regression model in forecasting crude oil price

    Science.gov (United States)

    Hamid, Mohd Helmie; Shabri, Ani

    2017-05-01

    This study presents the performance of wavelet multiple linear regression (WMLR) technique in daily crude oil forecasting. WMLR model was developed by integrating the discrete wavelet transform (DWT) and multiple linear regression (MLR) model. The original time series was decomposed to sub-time series with different scales by wavelet theory. Correlation analysis was conducted to assist in the selection of optimal decomposed components as inputs for the WMLR model. The daily WTI crude oil price series has been used in this study to test the prediction capability of the proposed model. The forecasting performance of WMLR model were also compared with regular multiple linear regression (MLR), Autoregressive Moving Average (ARIMA) and Generalized Autoregressive Conditional Heteroscedasticity (GARCH) using root mean square errors (RMSE) and mean absolute errors (MAE). Based on the experimental results, it appears that the WMLR model performs better than the other forecasting technique tested in this study.

  11. Coalescence kinetics of dispersed crude oil in a laboratory reactor

    International Nuclear Information System (INIS)

    Sterling, M.C. Jr.; Ojo, T.; Autenrieth, R.L.; Bonner, J.S.; Page, C.A.; Ernst, A.N.S.

    2002-01-01

    A study was conducted to examine the effects of salinity and mixing energy on the resurfacing and coalescence rates of chemically dispersed crude oil droplets. This kinetic study involved the use of mean shear rates to characterize the mixing energy in a laboratory reactor. Coagulation kinetics of dispersed crude oil were determined within a range of mean shear rates of 5, 10, 15, and 20 per second, and with salinity values of 10 and 30 per cent. Observed droplet distributions were fit to a transport-reaction model to estimate collision efficiency values and their dependence on salinity and mixing energy. Dispersant efficiencies were compared with those derived from other laboratory testing methods. Experimentally determined dispersant efficiencies were found to be 10 to 50 per cent lower than predicted using a non-interacting droplet model, but dispersant efficiencies were higher than those predicted using other testing methods. 24 refs., 1 tab., 3 figs

  12. Design of crude oil storage tank for acoustic emission testing

    International Nuclear Information System (INIS)

    Shukri Mohd; Masrul Nizam Salleh; Abd Razak Hamzah; Norasiah Abd Kasim

    2005-01-01

    The integrity of crude oil storage tank needs to be well managed because they can contain a large inventory of hazardous material and because of the high cost such as cleaning and waste disposal prior to disposal and maintenance. Costs involved in cleaning and inspection can be up to several hundreds thousand Malaysian Ranting. If the floor then proves to be in good condition, these costs have been wasted. Acoustic Emission (AE) is proposed to be use for monitoring the floor of the storage tank on line without doing cleaning and waste disposal. A storage tank will be fabricated for storing the crude oil and then the corrosion process will be monitor using AE method. This paper will discuss the background, material and is technical specification, design and also the difficulties faced during design and fabrication process. (Author)

  13. Crude oil and finished fuel storage stability: An annotated review

    Energy Technology Data Exchange (ETDEWEB)

    Whisman, M.L.; Anderson, R.P.; Woodward, P.W.; Giles, H.N.

    1991-01-01

    A state-of-the-art review and assessment of storage effects on crude oil and product quality was undertaken through a literature search by computer accessing several data base sources. Pertinent citations from that literature search are tabulated for the years 1980 to the present. This 1990 revision supplements earlier reviews by Brinkman and others which covered stability publications through 1979 and an update in 1983 by Goetzinger and others that covered the period 1952--1982. For purposes of organization, citations are listed in the current revision chronologically starting with the earliest 1980 publications. The citations have also been divided according to primary subject matter. Consequently 11 sections appear including: alternate fuels, gasoline, distillate fuel, jet fuel, residual fuel, crude oil, biodegradation, analyses, reaction mechanisms, containment, and handling and storage. Each section contains a brief narrative followed by all the citations for that category.

  14. Does China factor matter? An econometric analysis of international crude oil prices

    International Nuclear Information System (INIS)

    Wu, Gang; Zhang, Yue-Jun

    2014-01-01

    Whether China’s crude oil imports are the culprit of oil price volatility these years has not been quantitatively confirmed. Therefore, this paper empirically investigates the role of China’s crude oil net imports in Brent price changes from October 2005 to November 2013 based on an econometric analysis. The results indicate that, during the sample period, China’s crude oil imports do not significantly affect Brent price changes, no matter in the long run or short run. Therefore, the blame for China’s crude oil imports to cause the dramatic fluctuations of international oil price has no solid evidence. Also, there exists significant uni-directional causality running from the Brent price to China's crude oil imports at the 5% level. Besides, the response of the Brent price to China's crude oil imports is found positive but slight, and the Brent price responds more significantly to US dollar exchange rate and OECD commercial inventory than to China’s crude oil imports in the short run. Finally, the contribution of China's crude oil imports to Brent price movement is about 10%, which is less than that of US dollar exchange rate but larger than that of Indian crude oil imports or OECD commercial inventory. - Highlights: • The paper detects the role of China’s crude oil imports in Brent oil price changes. • China’s crude imports do not matter for oil prices in the long run or short run. • The blame for China’s crude imports on oil price changes has no solid evidence. • Significant causality runs from Brent prices to China's crude oil net imports. • China's crude imports contribute less to Brent prices than US dollar exchange rate

  15. Thermal properties and burning efficiency of crude oils and refined fuel oil

    DEFF Research Database (Denmark)

    van Gelderen, Laurens; Alva, Wilson Ulises Rojas; Mindykowski, Pierrick Anthony

    2017-01-01

    The thermal properties and burning efficiencies of fresh and weathered crude oils and a refined fuel oil were studied in order to improve the available input data for field ignition systems for the in-situ burning of crude oil on water. The time to ignition, surface temperature upon ignition, heat......-cooled holder for a cone calorimeter under incident heat fluxes of 0, 5, 10, 20, 30, 40 and 50 kW/m2. The results clearly showed that the weathered oils were the hardest to ignite, with increased ignition times and critical heat fluxes of 5-10 kW/m2. Evaporation and emulsification were shown...

  16. Coals to Newcastle: Will Alberta become a crude oil importer?

    International Nuclear Information System (INIS)

    Haessel, W.; Foley, D.J.

    1991-01-01

    The security of markets for Canadian heavy crude oil (HCO) under different conditions is examined. The emphasis of the study is on the conditions under which bitumen blend from Alberta could penetrate certain markets that have generally been identified as potential prospects. A secondary question concerns the cost reductions in bitumen production and upgrading that would be needed for bitumen blend and synthetic crude oil (SCO) to penetrate these same markets if long-term oil prices settle at US$18/bbl for Saudi light delivered to the USA Gulf Coast in 2010. A brief overview is first presented of some of the world and US factors that will affect the demand for Canadian HCO, with specific reference to the demand in the northern USA in 2010. The determination of the volume of HCO that can or will be processed at a refinery or a combination of refineries in a given market is then discussed. The cost and volume numbers for 2010 as provided in the National Energy Board's latest Canadian energy supply and demand forecast are used in the analysis. It is concluded that all traditional markets outside of the Canadian prairies could be lost if world oil prices stay below US$18/bbl for extended periods. At prices below US$17/bbl, bitumen producers would have trouble competing with imported crude oils in Edmonton unless bitumen production costs decline from current levels. The potential for bitumen production costs to decline enough for diluted bitumen to compete with US$18/bbl oil is better than the prospect for SCO costs to decrease enough to compete in eastern Canada or the northern USA at those price levels. 9 figs., 8 tabs

  17. Desulfurization of AL-Ahdab Crude Oil using Oxidative Processes

    OpenAIRE

    Neran Khalel Ibrahim; Saja Mohsen Jabbar

    2015-01-01

    Two different oxidative desulfurization strategies based on oxidation/adsorption or oxidation/extraction were evaluated for the desulfurization of AL-Ahdab (AHD) sour crude oil (3.9wt% sulfur content). In the oxidation process, a homogenous oxidizing agent comprising of hydrogen peroxide and formic acid was used. Activated carbons were used as sorbent/catalyst in the oxidation/adsorption process while acetonitrile was used as an extraction solvent in the oxidation/extraction process. For the ...

  18. Fatigue behaviour of X70 steel in crude oil

    Czech Academy of Sciences Publication Activity Database

    Gajdoš, Lubomír; Šperl, Martin; Bystrianský, J.

    2015-01-01

    Roč. 49, č. 2 (2015), s. 243-246 ISSN 1580-2949 R&D Projects: GA ČR(CZ) GAP105/10/2052; GA TA ČR(CZ) TE02000162 Institutional support: RVO:68378297 Keywords : corrosion fatigue * S-N curve * X70 steel * crude oil * separated water Subject RIV: JL - Materials Fatigue, Friction Mechanics Impact factor: 0.439, year: 2015 http://mit.imt.si/Revija/izvodi/mit152/gajdos.pdf

  19. Brine crude oil interactions at the oil-water interface

    DEFF Research Database (Denmark)

    Chakravarty, Krishna Hara; Fosbøl, Philip Loldrup; Thomsen, Kaj

    2015-01-01

    The impact of brine salinity and its ionic composition on oil displacement efficiency has been investigated extensively in recent years due to the potential of enhanced oil recovery (EOR). Wettability alterations through relative interactions at the mineral surface have been the basis of proposed...... in enhancing oil emulsion formation by increasing interactions between polar acids and brine solutions. The results propose the potential use of HPO42- ions in reservoirs having inactive mineral surfaces. The relative oil affinity of different ions including K+, Na+, Mg2+, and Ca2+ (cations), and Cl-, SO42...... and thus reduces the interfacial viscoelasticity of the trapped oil. These results show significant correlation between oil emulsion formation and increased oil recovery. Copyright 2015; Society of Petroleum Engineers...

  20. Crude oil pricing in Asia and future problems; Asia no gen`yu pricing to kongo no kadai

    Energy Technology Data Exchange (ETDEWEB)

    Kato, T. [The Institute of Energy Economics, Tokyo (Japan)

    1997-01-30

    This paper describes pricing factors of crude oil for Asia and future problems. Price of the Middle East crude oil for Asia is determined by linking the spot price of Dubayy crude oil using as a marker. Factors affecting the pricing of marker crude oil include the information dispatching functions for prices of spot market and paper market of marker crude oil, the presence of competitive crude oil, and the correlation between market of oil products and price of crude oil. The paper market of Dubayy crude oil with a small scale of trading provides poor impact and transparency. In Asia, there is no strong competitive crude oil except the Middle East crude oil. There is only a weak price linking between crude oil and products. These are the background that the price of Middle East crude oil stays at the high level and the price adjusting functions are hard to work. The marker crude oil should be changed to another except Dubayy crude oil, and information should be dispatched from purchasers based on the stable standard crude oil. The real paper market should be created, and the force of speaking to oil producing countries should be enhanced by concentrating forces of major oil consuming countries in Asia. It is necessary to find out competitive crude oils. 5 figs., 6 tabs.

  1. Biosurfactant production by Mucor circinelloides on waste frying oil and possible uses in crude oil remediation.

    Science.gov (United States)

    Hasanizadeh, Parvin; Moghimi, Hamid; Hamedi, Javad

    2017-10-01

    Biosurfactants are biocompatible surface active agents which many microorganisms produce. This study investigated the production of biosurfactants by Mucor circinelloides. The effects of different factors on biosurfactant production, including carbon sources and concentrations, nitrogen sources, and iron (II) concentration, were studied and the optimum condition determined. Finally, the strain's ability to remove the crude oil and its relationship with biosurfactant production was evaluated. The results showed that M. circinelloides could reduce the surface tension of the culture medium to 26.6 mN/m and create a clear zone of 12.9 cm diameter in an oil-spreading test. The maximum surface tension reduction was recorded 3 days after incubation. The optimum condition for biosurfactant production was achieved in the presence of 8% waste frying oil as a carbon source, 2 g/L yeast extract as a nitrogen source, and 0.01 mM FeSO 4 . M. circinelloides could consume 8% waste frying oil in 5 days of incubation, and 87.6% crude oil in 12 days of incubation. A direct correlation was observed between oil degradation and surface tension reduction in the first 3 days of fungal growth. The results showed that the waste frying oil could be recommended as an inexpensive oily waste substance for biosurfactant production, and M. circinelloides could have the potential to treat waste frying oil. According to the results, the produced crude biosurfactant or fungal strain could be directly used for the mycoremediation of crude oil contamination in oil fields.

  2. Economic repercussions of OPEC's crude oil price increases

    Energy Technology Data Exchange (ETDEWEB)

    Merklein, H A

    1980-05-01

    Accusations that the Organization of Petroleum Exporting Countries (OPEC) created the world energy crisis and destroyed the economies of oil-importing nations are challenged by Dr. Merklein. He shows that the economic impact of OPEC price increases have only accelerated an already-developing energy shortage and only reflect the existing problems of inflation, unemployment, and declining currency exchange rates. The real problem is argued to be a US energy policy that is incapable of responding appropriately to what should be a manageable crude oil tax. When the arguments against OPEC policies are examined in an historical context, they are shown to be essentially neutral. 4 tables. (DCK)

  3. Deep hydrotreating of middle distillates from crude and shale oils

    Energy Technology Data Exchange (ETDEWEB)

    Landau, M.V. [The Blechner Center for Industrial Catalysis and Process Development, Ben-Gurion University of the Negev, Beer-Sheva (Israel)

    1997-06-20

    The potential scientific and technological solutions to the problems that appear as a result of shifting the hydrotreating of crude oil middle distillates and shale oils from the `normal` to the `deep` mode are considered on the basis of the reactivities and transformation routes of the least-reactive sulfur-, nitrogen-, and oxygen-containing compounds. The efficiency of selecting the optimal feedstock, increasing the process severity, improving the catalysts activity, and using alternative catalytic routes are compared, taking into account the specific issues related to deep hydrodesulfurization/hydrodenitrogenation/hydrodeoxygenation, i.e., chemical aspects, kinetics and catalysts

  4. Response surface analysis to improve dispersed crude oil biodegradation

    Energy Technology Data Exchange (ETDEWEB)

    Zahed, Mohammad A.; Aziz, Hamidi A.; Mohajeri, Leila [School of Civil Engineering, Universiti Sains Malaysia, Nibong Tebal, Penang (Malaysia); Isa, Mohamed H. [Civil Engineering Department, Universiti Teknologi PETRONAS, Tronoh, Perak (Malaysia)

    2012-03-15

    In this research, the bioremediation of dispersed crude oil, based on the amount of nitrogen and phosphorus supplementation in the closed system, was optimized by the application of response surface methodology and central composite design. Correlation analysis of the mathematical-regression model demonstrated that a quadratic polynomial model could be used to optimize the hydrocarbon bioremediation (R{sup 2} = 0.9256). Statistical significance was checked by analysis of variance and residual analysis. Natural attenuation was removed by 22.1% of crude oil in 28 days. The highest removal on un-optimized condition of 68.1% were observed by using nitrogen of 20.00 mg/L and phosphorus of 2.00 mg/L in 28 days while optimization process exhibited a crude oil removal of 69.5% via nitrogen of 16.05 mg/L and phosphorus 1.34 mg/L in 27 days therefore optimization can improve biodegradation in shorter time with less nutrient consumption. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  5. Price dynamics of crude oil and the regional ethylene markets

    International Nuclear Information System (INIS)

    Masih, Mansur; Algahtani, Ibrahim; De Mello, Lurion

    2010-01-01

    This paper is the first attempt to investigate: (1) is the crude oil (WTI) price significantly related to the regional ethylene prices in the Naphtha intensive ethylene markets of the Far East, North West Europe, and the Mediterranean? (2) What drives the regional ethylene prices? The paper is motivated by the recent and growing debate on the lead-lag relationship between crude oil and ethylene prices. Our findings, based on the long-run structural modelling approach of Pesaran and Shin, and subject to the limitations of the study, tend to suggest: (1) crude oil (WTI) price is cointegrated with the regional ethylene prices (2) our within-sample error-correction model results tend to indicate that although the ethylene prices in North West Europe and the Mediterranean were weakly endogenous, the Far East ethylene price was weakly exogenous both in the short and long term. These results are consistent, during most of the period under review (2000.1-2006.4) with the surge in demand for ethylene throughout the Far East, particularly in China and South Korea. However, during the post-sample forecast period as evidenced in our variance decompositions analysis, the emergence of WTI as a leading player as well, is consistent with the recent surge in WTI price (fuelled mainly, among others, by the strong hedging activities in the WTI futures/options and refining tightness) reflecting the growing importance of input cost in determining the dynamic interactions of input and product prices. (author)

  6. Investigation of wax precipitation in crude oil: Experimental and modeling

    Directory of Open Access Journals (Sweden)

    Taraneh Jafari Behbahani

    2015-09-01

    Full Text Available In this work, a series of experiments were carried to investigation of rheological behavior of crude oil using waxy crude oil sample in the absence/presence of flow improver such as ethylene-vinyl acetate copolymer. The rheological data covered the temperature range of 5–30 °C. The results indicated that the performance of flow improver was dependent on its molecular weight. Addition of small quantities of flow improver, can improve viscosity and pour point of crude oil. Also, an Artificial Neural Network (ANN model using Multi-Layer Perceptron (MLP topology has been developed to account wax appearance temperature and the amount of precipitated wax and the model was verified using experimental data given in this work and reported in the literature. In order to compare the performance of the proposed model based on Artificial Neural Network, the wax precipitation experimental data at different temperatures were predicted using solid solution model and multi-solid phase model. The results showed that the developed model based on Artificial Neural Network can predict more accurately the wax precipitation experimental data in comparison to the previous models such as solid solution and multi-solid phase model with AADs less than 0.5%. Furthermore, the number of parameters required for the Artificial Neural Network (ANN model is less than the studied thermodynamic models.

  7. Two-stage hydroprocessing of synthetic crude gas oil

    Energy Technology Data Exchange (ETDEWEB)

    Mahay, A.; Chmielowiec, J.; Fisher, I.P.; Monnier, J. (Petro-Canada Products, Missisauga, ON (Canada). Research and Development Centre)

    1992-02-01

    The hydrocracking of synthetic crude gas oils (SGO), which are commercially produced from Canadian oil sands, is strongly inhibited by nitrogen-containing species. To alleviate the pronounced effect of these nitrogenous compounds, SGO was hydrotreated at severe conditions prior to hydrocracking to reduce its N content from 1665 to about 390 ppm (by weight). Hydrocracking was then performed using a commercial nickel-tungsten catalyst supported on silica-alumina. Two-stage hydroprocessing of SGO was assessed in terms of product yields and quality. As expected, higher gas oil conversion were achieved mostly from an increase in naphtha yield. The middle distillate product quality was also clearly improved as the diesel fuel cetane number increased by 13%. Diesel engine tests indicated that particulate emissions in exhaust gases were lowered by 20%. Finally, pseudo first-order kinetic equations were derived for the overall conversion of the major gas oil components. 17 refs., 2 figs., 8 tabs.

  8. Method for estimating boiling temperatures of crude oils

    International Nuclear Information System (INIS)

    Jones, R.K.

    1996-01-01

    Evaporation is often the dominant mechanism for mass loss during the first few days following an oil spill. The initial boiling point of the oil and the rate at which the boiling point changes as the oil evaporates are needed to initialize some computer models used in spill response. The lack of available boiling point data often limits the usefulness of these models in actual emergency situations. A new computational method was developed to estimate the temperature at which a crude oil boils as a function of the fraction evaporated using only standard distillation data, which are commonly available. This method employs established thermodynamic rules and approximations, and was designed to be used with automated spill-response models. Comparisons with measurements show a strong correlation between results obtained with this method and measured values

  9. California demand and supply of crude oil: An econometric analysis with projections to 2000

    International Nuclear Information System (INIS)

    Ibegbulam, B.N.

    1991-01-01

    Forecast of California domestic crude oil supply requires the forecasts of California crude oil production and supply from Alaska. Future California crude oil production is forecast with an econometric model that postulates production as a function of reserves and reserves as a function of crude oil prices and exploration and development costs. Future supplies from Alaska are obtained by subtracting forecasts of Alaskan crude oil demand and shipments to the States of Hawaii, Oregon, and Washington from Alaskan North Slope crude oil production forecasts. A two-stage process was used to forecast future California crude oil demand. In the first stage, the demand for refined crude oil products was predicted with a single-equation double logarithmic rational-expectations dynamic model. In the second stage, the total demands obtained in the first stage were converted into a crude oil equivalent. It was found that the current surplus of domestic crude oil in California will end in 1994. Thereafter, California crude oil imports will sharply increase

  10. Thermal infrared remote sensing of crude oil slicks

    International Nuclear Information System (INIS)

    Salisbury, J.W.; D'Aria, D.M.

    1993-01-01

    It is important to develop a remote sensing technique for reliable detection of oil slicks for reasons of both oil exploration and environmental protection. Yet, unambiguous detection has proven an elusive goal. This article presents new thermal infrared spectra of oil slicks made from five different crude oil samples with a wide range of API gravities and compositions. After a brief outgassing phase, all oil slick spectra are quite similar and little affected by thickness, extended exposure to air or sunlight, and even by emulsification with seawater (mousse formation). Thus, oil slicks provide a remarkably unvarying spectral signature as remote sensing targets in the thermal infrared compared to other regions of the spectrum. This spectral signature in the 8-14 μm atmospheric window is flat, with an average reflectance of 4%. Seawater, on the other hand, has a spectrum that varies in reflectance with wavelength in the 8-14 μm window from 0.90 to 3.65%. In addition, the authors show that sea foam displays a reflectance spectrum quite similar to that of seawater in the 8-14 μm region, because the very high absorption coefficient of water in this wavelength region prevents volume scattering in foam bubbles. This results in a relatively uniform spectral background, against which oil slicks can be detected, based on their different spectral signature. Thus, thermal infrared multispectral remote sensing appears to offer a simple and reliable technique for aircraft or satellite detection of oil slicks

  11. Linkages between the markets for crude oil and the markets for refined products

    International Nuclear Information System (INIS)

    Didziulis, V.S.

    1990-01-01

    To understand the crude oil price determination process it is necessary to extend the analysis beyond the markets for petroleum. Crude oil prices are determined in two closely related markets: the markets for crude oil and the markets for refined products. An econometric-linear programming model was developed to capture the linkages between the markets for crude oil and refined products. In the LP refiners maximize profits given crude oil supplies, refining capacities, and prices of refined products. The objective function is profit maximization net of crude oil prices. The shadow price on crude oil gives the netback price. Refined product prices are obtained from the econometric models. The model covers the free world divided in five regions. The model is used to analyze the impacts on the markets of policies that affect crude oil supplies, the demands for refined products, and the refining industry. For each scenario analyzed the demand for crude oil is derived from the equilibrium conditions in the markets for products. The demand curve is confronted with a supply curve which maximizes revenues providing an equilibrium solution for both crude oil and product markets. The model also captures crude oil price differentials by quality. The results show that the demands for crude oil are different across regions due to the structure of the refining industries and the characteristics of the demands for refined products. Changes in the demands for products have a larger impact on the markets than changes in the refining industry. Since markets for refined products and crude oil are interrelated they can't be analyzed individually if an accurate and complete assessment of a policy is to be made. Changes in only one product market in one region affect the other product markets and the prices of crude oil

  12. Exporting Alaskan North Slope crude oil: Benefits and costs

    Energy Technology Data Exchange (ETDEWEB)

    1994-06-01

    The Department of Energy study examines the effects of lifting the current prohibitions against the export of Alaskan North Slope (ANS) crude. The study concludes that permitting exports would benefit the US economy. First, lifting the ban would expand the markets in which ANS oil can be sold, thereby increasing its value. ANS oil producers, the States of California and Alaska, and some of their local governments all would benefit from increased revenues. Permitting exports also would generate new economic activity and employment in California and Alaska. The study concludes that these economic benefits would be achieved without increasing gasoline prices (either in California or in the nation as a whole). Lifting the export ban could have important implications for US maritime interests. The Merchant Marine Act of 1970 (known as the Jones Act) requires all inter-coastal shipments to be carried on vessels that are US-owned, US-crewed, and US-built. By limiting the shipment of ANS crude to US ports only, the export ban creates jobs for the seafarers and the builders of Jones Act vessels. Because the Jones Act does not apply to exports, however, lifting the ban without also changing US maritime law would jeopardize the jobs associated with the current fleet of Jones Act tankers. Therefore the report analyzes selected economic impacts of several maritime policy alternatives, including: Maintaining current law, which allows foreign tankers to carry oil where export is allowed; requiring exports of ANS crude to be carried on Jones Act vessels; and requiring exports of ANS crude to be carried on vessels that are US-owned and US-crewed, but not necessarily US-built. Under each of these options, lifting the export ban would generate economic benefits.

  13. Exporting Alaskan North Slope crude oil: Benefits and costs

    International Nuclear Information System (INIS)

    1994-06-01

    The Department of Energy study examines the effects of lifting the current prohibitions against the export of Alaskan North Slope (ANS) crude. The study concludes that permitting exports would benefit the US economy. First, lifting the ban would expand the markets in which ANS oil can be sold, thereby increasing its value. ANS oil producers, the States of California and Alaska, and some of their local governments all would benefit from increased revenues. Permitting exports also would generate new economic activity and employment in California and Alaska. The study concludes that these economic benefits would be achieved without increasing gasoline prices (either in California or in the nation as a whole). Lifting the export ban could have important implications for US maritime interests. The Merchant Marine Act of 1970 (known as the Jones Act) requires all inter-coastal shipments to be carried on vessels that are US-owned, US-crewed, and US-built. By limiting the shipment of ANS crude to US ports only, the export ban creates jobs for the seafarers and the builders of Jones Act vessels. Because the Jones Act does not apply to exports, however, lifting the ban without also changing US maritime law would jeopardize the jobs associated with the current fleet of Jones Act tankers. Therefore the report analyzes selected economic impacts of several maritime policy alternatives, including: Maintaining current law, which allows foreign tankers to carry oil where export is allowed; requiring exports of ANS crude to be carried on Jones Act vessels; and requiring exports of ANS crude to be carried on vessels that are US-owned and US-crewed, but not necessarily US-built. Under each of these options, lifting the export ban would generate economic benefits

  14. Fortum Oil and Gas 2000: Exceptionally high price of crude oil and strong refining margins

    International Nuclear Information System (INIS)

    Ropponen, V.-M.

    2001-01-01

    Fortum intends to be an active player in the structural reorganization of the oil business by utilizing its niche position in oil refining. Fortum produces sophisticated motor fuel components, which it uses in its reformulated gasolines and sells and exports to other oil companies, even to highly demanding markets in California. The increase in the price of crude oil considerably improved the results of Oil and Gas Upstream. Similarly, an improvement in the refining margin, as well as profitable shipping operations and a strong demand for gasoline components, boosted the results of Oil Refining and Marketing. (orig.)

  15. 15 CFR 754.3 - Petroleum products not including crude oil.

    Science.gov (United States)

    2010-01-01

    ... 15 Commerce and Foreign Trade 2 2010-01-01 2010-01-01 false Petroleum products not including crude... SUPPLY CONTROLS § 754.3 Petroleum products not including crude oil. (a) License requirement. As indicated... required to all destinations, including Canada, for the export of petroleum products, excluding crude oil...

  16. Technical Proposal for Loading 3000 Gallon Crude Oil Samples from Field Terminal to Sandia Pressurized Tanker to Support US DOE/DOT Crude Oil Characterization Research Study

    Energy Technology Data Exchange (ETDEWEB)

    Lord, David; Allen, Raymond

    2016-10-01

    Sandia National Laboratories is seeking access to crude oil samples for a research project evaluating crude oil combustion properties in large-scale tests at Sandia National Laboratories in Albuquerque, NM. Samples must be collected from a source location and transported to Albuquerque in a tanker that complies with all applicable regulations for transportation of crude oil over public roadways. Moreover, the samples must not gain or lose any components, to include dissolved gases, from the point of loading through the time of combustion at the Sandia testing facility. In order to achieve this, Sandia designed and is currently procuring a custom tanker that utilizes water displacement in order to achieve these performance requirements. The water displacement procedure is modeled after the GPA 2174 standard “Obtaining Liquid Hydrocarbons Samples for Analysis by Gas Chromatography” (GPA 2014) that is used routinely by crude oil analytical laboratories for capturing and testing condensates and “live” crude oils, though it is practiced at the liter scale in most applications. The Sandia testing requires 3,000 gallons of crude. As such, the water displacement method will be upscaled and implemented in a custom tanker. This report describes the loading process for acquiring a ~3,000 gallon crude oil sample from commercial process piping containing single phase liquid crude oil at nominally 50-100 psig. This document contains a general description of the process (Section 2), detailed loading procedure (Section 3) and associated oil testing protocols (Section 4).

  17. EVALUATING THE SHORT RUN EFFECTS OF U.S. CRUDE OIL INVENTORY LEVELS ON WTI CRUDE OIL PRICE FROM 1993 - 2013

    Directory of Open Access Journals (Sweden)

    Tobi Olasojiand

    2016-07-01

    Full Text Available The focus of this research was to investigate the short-term influence of U.S. crude oil inventories on WTI crude oil prices from 1993 to 2013. This study is important for policy makers who wish to reduce the persistent and growing price volatility of crude oil and its related products as well as businesses such as airline companies who wish to make annual budgetary sales decisions. Using OLS multiple regression, cointegration, VECM and Ex-post forecast techniques; we provide evidence of an inelastic relationship in which a 1% increase in U.S. crude oil inventories is associated with 0.46% decrease in WTI crude oil prices; however this was only valid for 22% of WTI crude oil price variation. We also find that past data on U.S. crude oil inventories could be used to predict future WTI crude oil prices movement. Contrary to literature, the results of the VECM analysis indicate there is no short-run relationship between both variables over the trajectory.

  18. Daily Crude Oil Price Forecasting Using Hybridizing Wavelet and Artificial Neural Network Model

    Directory of Open Access Journals (Sweden)

    Ani Shabri

    2014-01-01

    Full Text Available A new method based on integrating discrete wavelet transform and artificial neural networks (WANN model for daily crude oil price forecasting is proposed. The discrete Mallat wavelet transform is used to decompose the crude price series into one approximation series and some details series (DS. The new series obtained by adding the effective one approximation series and DS component is then used as input into the ANN model to forecast crude oil price. The relative performance of WANN model was compared to regular ANN model for crude oil forecasting at lead times of 1 day for two main crude oil price series, West Texas Intermediate (WTI and Brent crude oil spot prices. In both cases, WANN model was found to provide more accurate crude oil prices forecasts than individual ANN model.

  19. Effect of dispersants on the growth of indigenous bacterial population and biodegradation of crude oil

    Digital Repository Service at National Institute of Oceanography (India)

    Bhosle, N.B.; Row, A.

    Oil dispersants (5 from Castrol Ltd., Bombay and 2 from British Petroleum, London) were studied individually and in combination with Saudi Arabian crude oil for their effect on the growth of indigenous bacteria and on the biodegradation of oil. None...

  20. Combustion of crude oil sludge containing naturally occurring radioactive material

    International Nuclear Information System (INIS)

    Mohamad Puad Abu; Muhd Noor Muhd Yunus; Shamsuddin, A.H.; Sopian, K.

    2000-01-01

    The characteristics of crude oil sludge fi-om the crude oil terminal are very unique because it contains both heavy metals and also Naturally Occurring Radioactive Material (NORM). As a result, the Department of Environmental (DOE) and the Atomic Energy Licensing Board (AELB) considered it as Scheduled Wastes and Low Level Radioactive Waste (LLRW) respectively. As a Scheduled Wastes, there is no problem in dealing with the disposal of it since there already exist a National Center in Bukit Nanas to deal with this type of waste. However, the Center could not manage this waste due to the presence of NORM by which the policy regarding the disposal of this kind of waste has not been well established. This situation is unclear to certain parties, especially with respect to the relevant authorities having final jurisdiction over the issue as well as the best practical method of disposal of this kind of waste. Existing methods of treatment viewed both from literature and current practice include that of land farming, storing in plastic drum, re-injection into abandoned oil well, recovery, etc., found some problems. Due to its organic nature, very low level in radioactivity and the existence of a Scheduled Waste incineration facility in Bukit Nanas, there is a potential to treat this sludge by using thermal treatment technology. However, prior to having this suggestion to be put into practice, there are issues that need to be addressed. This paper attempts to discuss the potentials and the related issues of combusting crude oil sludge based on existing experimental data as well as mathematical modeling

  1. Application of Biosurfactants Produced by Pseudomonas putida using Crude Palm Oil (CPO) as Substrate for Crude Oil Recovery using Batch Method

    Science.gov (United States)

    Suryanti, V.; Handayani, D. S.; Masykur, A.; Septyaningsih, I.

    2018-03-01

    The application of biosurfactants which have been produced by Pseudomonas putida in nutrient broth medium supplemented with NaCl and crude palm oil (CPO) for oil recovery has been evaluated. The crude and purified biosurfactants have been examined for oil recovery from a laboratory oil-contaminated sand in agitated flask (batch method). Two synthetic surfactants and water as control was also performed for oil recovery as comparisons. Using batch method, the results showed that removing ability of crude oil from the oil-contaminated sand by purified and crude biosurfactants were 79.40±3.10 and 46.84±2.23 %, respectively. On other hand, the recoveries obtained with the SDS, Triton X-100 and water were 94.33±0.47, 74.84±7.39 and 34.42±1.21%respectively.

  2. Unit root properties of crude oil spot and futures prices

    International Nuclear Information System (INIS)

    Maslyuk, Svetlana; Smyth, Russell

    2008-01-01

    In this article, we examine whether WTI and Brent crude oil spot and futures prices (at 1, 3 and 6 months to maturity) contain a unit root with one and two structural breaks, employing weekly data over the period 1991-2004. To realise this objective we employ Lagrange multiplier (LM) unit root tests with one and two endogenous structural breaks proposed by Lee and Strazicich [2003. Minimum Lagrange multiplier unit root test with two structural breaks. Review of Economics and Statistics, 85, 1082-1089; 2004. Minimum LM unit root test with one structural break. Working Paper no. 04-17, Department of Economics, Appalachian State University]. We find that each of the oil price series can be characterised as a random walk process and that the endogenous structural breaks are significant and meaningful in terms of events that have impacted on world oil markets

  3. The predictive content of CBOE crude oil volatility index

    Science.gov (United States)

    Chen, Hongtao; Liu, Li; Li, Xiaolei

    2018-02-01

    Volatility forecasting is an important issue in the area of econophysics. The information content of implied volatility for financial return volatility has been well documented in the literature but very few studies focus on oil volatility. In this paper, we show that the CBOE crude oil volatility index (OVX) has predictive ability for spot volatility of WTI and Brent oil returns, from both in-sample and out-of-sample perspectives. Including OVX-based implied volatility in GARCH-type volatility models can improve forecasting accuracy most of time. The predictability from OVX to spot volatility is also found for longer forecasting horizons of 5 days and 20 days. The simple GARCH(1,1) and fractionally integrated GARCH with OVX performs significantly better than the other OVX models and all 6 univariate GARCH-type models without OVX. Robustness test results suggest that OVX provides different information from as short-term interest rate.

  4. Oil and Cars: The Impact of Crude Oil Prices on the Stock Returns of Automotive Companies

    Directory of Open Access Journals (Sweden)

    Bettina Lis

    2012-01-01

    Full Text Available In this paper we are testing whether the impact of oil prices is different on the overall market and automotive companies. In addition we investigate, if this relationship is nonlinear. For this we use stock return data of US, German and Japanese car companies, and returns of share indices from the same countries as control variables, and Brent crude oil price changes. We first estimate the impact of crude oil on the indices, then clean the indices from these influences, and afterwards estimate the impact on the stocks. For this we are using OLS and EGARCH (1,1. We conclude that in general the car companies‘ stocks do not react more adversely as the overall market to crude oil price increases, while Japanese companies do not show any excess sensitivity at all. German companies tend to be sensitive, and US and German companies are together more sensitive in the more recent time periods.

  5. Comparative Toxicity of Different Crude Oils on the Cardiac Function of Marine Medaka (Oryzias melastigma Embryo

    Directory of Open Access Journals (Sweden)

    Zhendong Zhang

    2014-12-01

    Full Text Available The acute toxic effect of different crude oils (heavy crude oil and bonny light crude oil on embryos of marine medaka Oryzias melastigma was measured and evaluated by exposure to the water-accommodated fraction (WAF in the present study. The cardiac function of medaka embryos was used as target organ of ecotoxicological effect induced by oil exposure. Results showed that the developing marine medaka heart was a sensitive target organ to crude oil exposure the heavy crude oil WAF was more toxic to cardiac function of medaka embryos than bonny light cured oil one. Cardiac function of medaka embryos was clearly affected by exposure to heavy crude oil WAF after 24 hours exposure and showed a dose-dependent slowing of heart rate. Furthermore, swelled and enlarged heart morphology, lowered blood circulation and accumulation of blood cells around the heart area were found. However, the toxic effect of bonny light crude oil on cardiac function of medaka embryos was comparatively low. Statistical results showed that the cardiac function was only affected by highest bonny light crude oil WAF (9.8 mg/L exposure treatment. These findings indicated that cardiac function of marine medaka embryo was a good toxicity model for oil pollution and could be used to compare and evaluate the toxicity of different crude oils. The heart rate was an appropriate endpoint in the acute toxicity test.

  6. Exploring crude oil production and export capacity of the OPEC Middle East countries

    International Nuclear Information System (INIS)

    Matsumoto, Ken'ichi; Voudouris, Vlasios; Stasinopoulos, Dimitrios; Rigby, Robert; Di Maio, Carlo

    2012-01-01

    As the world economy highly depends on crude oil, it is important to understand the dynamics of crude oil production and export capacity of major oil-exporting countries. Since crude oil resources are predominately located in the OPEC Middle East, these countries are expected to have significant leverage in the world crude oil markets by taking into account a range of uncertainties. In this study, we develop a scenario for crude oil export and production using the ACEGES model considering uncertainties in the resource limits, demand growth, production growth, and peak/decline point. The results indicate that the country-specific peak of both crude oil export and production comes in the early this century in the OPEC Middle East countries. On the other hand, they occupy most of the world export and production before and after the peak points. Consequently, these countries are expected to be the key group in the world crude oil markets. We also find that the gap between the world crude oil demand and production broadens over time, meaning that the acceleration of the development of ultra-deep-water oil, oil sands, and extra-heavy oil will be required if the world continuous to heavily rely on oil products. - Highlights: ► We simulate the future scenario of crude oil export and production using ACEGES. ► The simulated results are analyzed using the GAMLSS framework. ► The peak points of oil export and production will come early in this century. ► The OPCE Middle East will produce most of the world crude oil in the near future. ► These countries will continuously be the key players in the crude oil markets.

  7. Crude oil price analysis and forecasting based on variational mode decomposition and independent component analysis

    Science.gov (United States)

    E, Jianwei; Bao, Yanling; Ye, Jimin

    2017-10-01

    As one of the most vital energy resources in the world, crude oil plays a significant role in international economic market. The fluctuation of crude oil price has attracted academic and commercial attention. There exist many methods in forecasting the trend of crude oil price. However, traditional models failed in predicting accurately. Based on this, a hybrid method will be proposed in this paper, which combines variational mode decomposition (VMD), independent component analysis (ICA) and autoregressive integrated moving average (ARIMA), called VMD-ICA-ARIMA. The purpose of this study is to analyze the influence factors of crude oil price and predict the future crude oil price. Major steps can be concluded as follows: Firstly, applying the VMD model on the original signal (crude oil price), the modes function can be decomposed adaptively. Secondly, independent components are separated by the ICA, and how the independent components affect the crude oil price is analyzed. Finally, forecasting the price of crude oil price by the ARIMA model, the forecasting trend demonstrates that crude oil price declines periodically. Comparing with benchmark ARIMA and EEMD-ICA-ARIMA, VMD-ICA-ARIMA can forecast the crude oil price more accurately.

  8. Environmental considerations in a high desert, crude oil pipeline spill

    International Nuclear Information System (INIS)

    Lowe, M.A.; Mancini, E.R.; Chamberlain, D.W.; Albright, G.R.

    1993-01-01

    A road grader punctured a high-pressure crude oil pipeline in the California high desert resulting in the release of approximately 4,200 barrels of Alaska North Slope crude oil. Oil sprayed over a steeply sloped hillside and flowed into an adjacent, densely vegetated ephemeral stream channel which carried secondary treatment sewage discharge. Three underflow dams were constructed in the channel within 2.8 km of the site. To ensure containment at the first dam, the sewage discharge was diverted from the channel, eventually to an upland impulse sprinkler irrigation system. Channel water and phase-separated ANS crude oil, impounded behind the first dam, percolated through alluvial sands/gravels to a depth of about five meters. The oil percolated through the soils on the receding surface of the water, affecting soils to an equivalent depth and saturating a horizontally narrow band of stream-bank soils as much as two to four meters into the bank. Stream channel undergrowth and a small number of mature trees were cleared to provide access for cleanup and/or to remove oiled plants. A large number of trees experienced partial leaf-drop within 25 days of the spill while two heavily oiled trees died. New vegetative growth was evident within five weeks of the spill. Site restoration included planting cuttings of five riparian tree species and hydroseeding exposed banks. Total petroleum hydrocarbon concentrations ranged from not detectable to 203,000 parts per million and averaged approximately 25,000 ppm in affected soils as sampled in place and in stockpiles. Approximately 30,000 tons of hydrocarbon-contaminated soil was excavated from the length of the stream channel (3,600 tons) as well as the area behind the first dam and spill site (26,400 tons). All soils were staged on site for waste profiling and final disposition. After treatment, the contaminated soil was beneficially reused as daily cover at a southern California landfill at a turnkey cost of approximately $57/ton

  9. Synthesis copolymer use to reduce pour point temperature of diamond crude oil

    Science.gov (United States)

    Than, Dao Viet; Chuong, Thai Hong; Tuy, Dao Quoc

    2017-09-01

    Diamond oil field is located in Block 01&02 Offshore Vietnam. Crude oil from Diamond Well Head Platform (WHP) is evacuated to FPSO via 20km 10" subsea flexible pipeline. The lowest seabed temperature in the field is 22°C, while the pour point temperature (PPT) of Diamond crude oil is very high (36°C) due to high paraffin content (25%). So studying to research a suitable Pour Point Depressant (PPD) for the crude oil is very important. The PPD must have ability to reduce pour point temperature of crude oil from 36°C to 21°C.

  10. Performance Optimization of Centrifugal Pump for Crude Oil Delivery

    Directory of Open Access Journals (Sweden)

    S.A.I. Bellary

    2018-02-01

    Full Text Available Crude oil transport is an essential task in oil and gas industries, where centrifugal pumps are extensively used. The design of a centrifugal pump involves a number of independent parameters which affect the pump performance. Altering some of the parameters within a realistic range improves pump performance and saves a significant amount of energy. The present research investigated the pump characteristics by modifying the number of blades and the exit blade-angles. Reynolds-Averaged Navier-Stokes equations with standard k-ε two-equation turbulence closure were used for steady and incompressible flow of crude oil through the pump. The experimental set-up was installed and the pump performance calculated numerically  was compared with the experiments.   The investigations showed that the number of blades and the exit blade-angles have a significant influence on the head, shaft power, and efficiency. The vortical flow structures, recirculation and reverse flow characteristics around the impeller were investigated to explain the flow dynamics of impeller and casing. A larger number of blades on the rotor showed dominant streamlined flow without any wake phenomena. The combined effect of the number of blades and exit blade angle has led to an increase in head and efficiency through the parametric optimization.

  11. Investigation of Asphaltene Precipitation at Elevated Temperature

    DEFF Research Database (Denmark)

    Andersen, Simon Ivar; Lindeloff, Niels; Stenby, Erling Halfdan

    1998-01-01

    In order to obtain quantitative data on the asphaltene precipitation induced by the addition of n-alkane (heptane) at temperatures above the normal boiling point of the precipitant, a high temperature/high pressure filtration apparatus has been constructed. Oil and alkane are mixed...

  12. How crude oil consumption impacts on economic growth of Sub-Saharan Africa?

    International Nuclear Information System (INIS)

    Bashiri Behmiri, Niaz; Pires Manso, José R.

    2013-01-01

    This study investigates the causality relationship between crude oil consumption and economic growth in twenty three Sub-Saharan African countries. We applied a multivariate panel Granger causality framework during 1985–2011 and we included crude oil price as the control variable of the model. The results indicate that in the short-run, there is a bi-directional causality relationship between crude oil consumption and economic growth in oil importing region and there is a uni-directional causality relationship from crude oil consumption to GDP in oil exporting region. However, in the long-run there is a bi-directional causality relationship between them in both regions. Therefore, reducing crude oil consumption without employing appropriate policies adversely impacts on economic growth of Sub-Saharan Africa. Hence, in order to reduce crude oil dependency of the region policymakers should pay more attention to the issue of energy efficiency programs. - Highlights: ► We examined Granger causality among oil consumption and GDP in Sub-Saharan Africa. ► Crude oil price is the control variable of the model. ► There is short run bi-directional causality among oil and GDP (oil importing). ► There is short run uni-directional causality from oil to GDP (oil exporting). ► There is a long run bi-directional causality among oil and GDP in both regions

  13. Spectral characterization of crude oil using fluorescence (synchronous and time-resolved) and NIR (Near Infrared Spectroscopy); Caracterizacao espectral do petroleo utilizando fluorescencia (sincronizada e resolvida no tempo) e NIR (Near Infrared Spectroscopy)

    Energy Technology Data Exchange (ETDEWEB)

    Falla Sotelo, F.; Araujo Pantoja, P.; Lopez-Gejo, J.; Le Roux, G.A.C.; Nascimento, C.A.O. [Universidade de Sao Paulo (USP), SP (Brazil). Dept. de Engenharia Quimica. Lab. de Simulacao e Controle de Processos; Quina, F.H. [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Quimica. Centro de Capacitacao e Pesquisa em Meio Ambiente (CEPEMA)

    2008-07-01

    The objective of the present work is to evaluate the performance of two spectroscopic techniques employed in the crude oil characterization: NIR spectroscopy and fluorescence spectroscopy (Synchronous fluorescence - SF and Time Resolved Fluorescence - TRF) for the development of correlation models between spectral profiles of crude oil samples and both physical properties (viscosity and API density) and physico-chemical properties (SARA analysis: Saturated, Aromatic, Resins and Asphaltenes). The better results for viscosity and density were obtained using NIR whose prediction capacity was good (1.5 cP and 0.5 deg API, respectively). For SARA analysis, fluorescence spectroscopy revealed its potential in the model calibration showing good results (R2 coefficients greater than 0.85). TRF spectroscopy had better performance than SF spectroscopy. (author)

  14. The Necessity of a Graded Tariff System between Crude Oil and Oil Products

    Energy Technology Data Exchange (ETDEWEB)

    Kang, B.R. [SK Corporation, Seoul (Korea)

    2002-06-01

    Even though the graded tariff system between crude oil and oil products has been continuously insisted by oil refining companies since the export and import liberalization of 1997, and its necessity has been admitted by the government, press, and academia, the expanded implementation of the graded tariff system has not been yet realized. Some people says that the graded tariff system between crude oil and oil products is a kind of desperate plans, which oil refining companies suggests to stop the importing companies' rapid growth, so it will eventually restrict the competition of the domestic oil market due to the withering of importing companies. However, the graded tariff system between crude oil and oil products should have been enforced in 1997 as a complementary measure of the import liberalization like other industries or the advanced countries' cases. It is the basic tariff principle that the low tariff is levied on raw materials and the high tariff on final products in order to protect domestic industry. The remaining things are just to form the sympathy and to agree socially for the reorganization of tariff structure in the reasonable way. It is not desirable to make a fool mistake such as a proverb; t is too late to shut the stable door after the horse has bolted. owing to the unreasonable tariff system.

  15. Electrochemical removal of metals from crude oil samples

    Energy Technology Data Exchange (ETDEWEB)

    Welter, K.; Salazar, E.; Balladores, Y.; Marquez, O.P.; Marquez, J.; Martinez, Y. (Laboratorio de Electroquimica, Facultad de Ciencias, Universidad de Los Andes, Merida 5101-Venezuela)

    2009-02-15

    Removal of vanadium from vanadyl (IV) meso-tetra-phenylporphyrin (VO-MTPP) and vanadyl (IV) octa-ethylporphyrin (VO-OEP) and metals removal from Ayacucho Venezuelan crude oil samples were performed using electrochemical techniques. According to cyclic voltammograms, a potential of - 2.3 V vs. Ag/AgNO{sub 3} (0.1 M), LiClO{sub 4} (0.1 M) in acetonitrile, was chosen for running electrolysis at platinum (Pt), graphite (G) and glassy carbon (GC) electrodes. Qualitative analysis was done by cyclic voltammetry (CV) and atomic absorption spectroscopy (AAS) while quantification was performed by AAS and inductively coupled plasma/atomic emission spectrometry (ICP/AES). Three stages (best results) of the study are reported: (a) when using commercial porphyrins; the best conditions for electrolysis were: tetrahydrofuran (THF)/20% methanol (MeOH)/1% perchloric acid (HClO{sub 4}) on GC, producing 84% hydro-demetalation (HDM) for VO-MTPP, and 78% HDM for VO-OEP; (b) when using extracts of crude oil; demetalation percentages, after 90 min of electrolysis, on graphite, and after 120 min of electrolysis on platinum, were 66.44% and 64.10% HDM respectively, no discrimination of metals under these conditions (c) from electrolysis in whole crude oil, quantitative analysis gave: vanadium (V) 31.2 mg/kg, iron (Fe) 65, 0 mg/kg and nickel (Ni) 6, 3 mg/kg, with charge efficiencies of V (7.5%), Fe (79.6%) and Ni (8.2%). (author)

  16. A risk assessment for crude oil in residential surface soils

    International Nuclear Information System (INIS)

    Sullivan, M.J.; Miller, C.J.; Custance, S.R.

    1991-01-01

    This paper reports that the discovery of crude oil residues in residential soils is occurring with increasing frequency as property previously owned by the petroleum industry is sold and developed for housing. Many states have adopted action levels for total petroleum hydrocarbons (TPH) in soil for the purpose of discerning those sites requiring remediation and/or monitoring. Many states are known to have action levels consisting of a single concentration value which may carry from 10 to 100 ppm TPH. Other states incorporate a range of action levels for addressing site-specific needs; values range from 10 to 1000 ppm TPH for gasoline in soils

  17. Exergy analysis of a crude oil atmospheric distillation unit

    International Nuclear Information System (INIS)

    Rivero, R.; Gonzalez, G.V.; Garcia, V.H.; Pulido, R.; Escarcega, C.A.

    1989-01-01

    This paper deals with the application of an exergy analysis to an existing and operating crude oil atmospheric distillation unit. The objective of such an analysis is to fully understand where energy inefficiencies and real energy losses are located and where modifications should be implemented to improve the overall utilization of energy in the plant. First, the description of the process and the block diagram are presented. After that, the calculating procedure to obtain the exergy balance, the exergy losses, the effectiveness and the improvement potential for each plant component is described and the corresponding results are shown. Finally, the component and overall evaluations are discussed

  18. Potential of oil palm empty fruit bunch ash for remediation of crude ...

    African Journals Online (AJOL)

    The potential of oil palm empty fruit bunch ash for remediation of crude oil polluted soil was investigated. Three levels (100 g, 200 g and 300 g) of ash treatments in 2 kg of soil were set up alongside a control (nil ash) after pollution with100 ml of crude oil. Composite soil samples were collected and analyzed at intervals of ...

  19. Crude Oil Resource: A Blessing Or Curse To Nigeria – The Case Of ...

    African Journals Online (AJOL)

    Crude Oil Resource: A Blessing Or Curse To Nigeria – The Case Of The Niger Delta. S Tamuno, JM Felix. Abstract. This paper examines the question as to whether crude oil resource is a blessing or curse to Nigeria: The case of the Niger Delta Region. The paper traces the origin of oil exploration and exploitation from ...

  20. Concentration of vanadium in crude oil and water using inductively-coupled plasma spectrometry

    International Nuclear Information System (INIS)

    Amin, Y.M.; Hassan, M.A.; Junkin, K.; Mahat, R.H.; Raphie, B.

    1991-01-01

    Vanadium is a trace element that is usually associated to crude oil and its products. In this study the concentration of vanadium in a few samples of local crude oil, sea and river water were determined using inductively-coupled plasma spectrometry (ICP). It is hoped that the concentration of vanadium in water can be used to indicate the possible extent of oil contamination

  1. Natural gas hydrate formation and inhibition in gas/crude oil/aqueous systems

    DEFF Research Database (Denmark)

    Daraboina, Nagu; Pachitsas, Stylianos; von Solms, Nicolas

    2015-01-01

    Gas hydrate formation in multi phase mixtures containing an aqueous phase (with dissolved salts), reservoir fluid (crude oil) and natural gas phase was investigated by using a standard rocking cell (RC-5) apparatus. The hydrate formation temperature was reduced in the presence of crude oils...... can contribute to the safe operation of sub sea pipelines in the oil and gas industry....

  2. Speculation and volatility spillover in the crude oil and agricultural commodity markets: A Bayesian analysis

    International Nuclear Information System (INIS)

    Du Xiaodong; Yu, Cindy L.; Hayes, Dermot J.

    2011-01-01

    This paper assesses factors that potentially influence the volatility of crude oil prices and the possible linkage between this volatility and agricultural commodity markets. Stochastic volatility models are applied to weekly crude oil, corn, and wheat futures prices from November 1998 to January 2009. Model parameters are estimated using Bayesian Markov Chain Monte Carlo methods. Speculation, scalping, and petroleum inventories are found to be important in explaining the volatility of crude oil prices. Several properties of crude oil price dynamics are established, including mean-reversion, an asymmetry between returns and volatility, volatility clustering, and infrequent compound jumps. We find evidence of volatility spillover among crude oil, corn, and wheat markets after the fall of 2006. This can be largely explained by tightened interdependence between crude oil and these commodity markets induced by ethanol production.

  3. Acetylation of oil palm empty fruit bunch fiber as an adsorbent for removal of crude oil.

    Science.gov (United States)

    Asadpour, Robabeh; Sapari, Nasiman B; Isa, Mohamed Hasnain; Kakooei, Saeid

    2016-06-01

    Removal of oil spillage from the environment is a global concern. Various methods, including the use of fibers as sorbents, have been developed for oil spill control. Oil palm empty fruit bunch (OPEFB) fiber is a plant biomass that may be acetylated by acetic anhydride using N-bromosuccinimide (NBS) as a catalyst; here, the extent of acetylation may be calculated in terms of weight percent gain (WPG). The modified fiber was used to remove Tapis and Arabian crude oils. The optimum time, temperature, and catalyst concentration were 4 h, 120 °C, and 3 %, respectively, and these parameters could achieve an 11.49 % increase in WPG. The optimized parameters improved the adsorption capacity of OPEFB fibers for crude oil removal. The acetylated OPEFB fibers were characterized by using Fourier transform infrared spectroscopy and field emission scanning electron microscopy to observe the functional groups available and morphology. Kinetic and isotherm studies were conducted using different contact times and oil/water ratios. The rate of oil sorption onto the OPEFB fibers can be adequately described by the pseudo-second-order equation. Adsorption studies revealed that adsorption of crude oil on treated OPEFB fiber could be best described by the Langmuir isotherm model.

  4. Influence of chemical surfactants on the biodegradation of crude oil by a mixed bacterial culture

    International Nuclear Information System (INIS)

    Van Hamme, J.D.; Ward, O.P.

    1999-01-01

    A study was conducted in which the effects of surfactant physicochemical properties on crude oil biodegradation by a mixed-bacterial culture were examined. The effects of hydrophile-lipophile balance (HLB) and molecular structure on the biodegradation of Bow River crude oil were determined. It was shown that chemical surfactants have the potential to improve crude oil biodegradation in complex microbial systems. Surfactant selection should consider factors such as molecular structure, HLB and surfactant concentration. 26 refs., 4 tabs., 3 figs

  5. Soil water repellency at old crude oil spill sites

    International Nuclear Information System (INIS)

    Roy, J.L.

    1999-08-01

    This thesis presents the current state of knowledge regarding the cause of soil water repellency and characterizes disaggregated nonwettable surface soils found at old crude oil spill sites. Pollution-induced water repellency generally develops following prolonged exposures of soil to liquid- or vapour-phase petroleum hydrocarbons. The condition varies significantly in terms of severity and persistence. Soil water repellency retards plant growth and disturbs the hydrological balance of ecosystems. Disaggregated water-repellent soils are also very susceptible to dispersal by erosion, posing a threat to the productivity of surrounding soils. The author described the probable causes of soil water repellency under the following three main themes: (1) accumulation of hydrophobic organic material in soil, (2) redistribution and re-organisation of this material in soil, and (3) stabilisation of the hydrophobic organic material. This final process is necessary to ensure persistence of induced water repellency symptoms. Petroleum residues as water-repellent substances in weathered nonwettable oil-contaminated soils were also discussed and a hypothesis about soil water repellency was presented which deals with flexible conformation in organic matter coatings. Processes leading to the development of soil water repellency following crude oil contamination were also described. It was determined that soil water repellency is a function of the packing density and the chain conformation of amphiphilic organic molecules in the outermost layer of soil organic matter coatings. This research suggests that the fractional coverage of alkyl chains on soil particle surfaces determines the degree of water repellency that is displayed by soil. It was shown that prompt remediation of some oil-contaminated plots can effectively prevent the development of soil water repellency. 4 refs., 32 tabs., 22 figs., 5 appendices

  6. Influence of crude oil treatment to the environment

    International Nuclear Information System (INIS)

    Mammadov, F.F.; Rzayev, P.F.

    2005-01-01

    Full text : Environmental menace is linking with the unprecedented man-caused explosion and perspective global warming at the result of atmosphere pollution. If similar tendency is continued radical changing's will not happen in future which catastrophically reflects in ecology, climate of the planet, finally in the population health of the Earth. However, unfortunately one-sidedly economy increasing are chiefly directed to the oil-gas sector and from year to year amount increasing of means of transport causes man's impact to the environment. Further increasing of these processes obviously can lead to the dangerous ecological situation. In the economical and efficiency increasing process country population depend directly on the level of energy consumption. Application of nature-conservative measures and technology, promotional efficiency increasing of energy usage, its total usage decreasing, simultaneous reducing of hazardous substance lead to the considerable but cardinal results. That's why taking into consideration above mentioned circumstance, conclusion one is oil and gas saving, reducing of hazardous substance, we can greatly economize by the gradual way of natural energy replacement into renewable energy. In this connection, special interest for Azerbaijan creates high-grade potential solar radiation usage problem in several fields of national economy, especially in oil sector of the country. There is a real background for effective usage of high-grade potential solar radiation in Azerbaijan oil industry. As the process of primary crude oil treatment in the condition of oil fields for its further transportation to Oil Refining Plant the temperature is to be near 50-60 degrees to be very readily reached to various solar radiation engineering systems. On the base on the above mentioned for realizing this process we built and developed high-grade temperature solar plant with parabolic trough concentrator. Economy till 40% of national fuels (mazut, gas

  7. Jump dynamics with structural breaks for crude oil prices

    International Nuclear Information System (INIS)

    Lee, Yen-Hsien; Hu, Hsu-Ning; Chiou, Jer-Shiou

    2010-01-01

    This study investigates the joint phenomena of permanent and transitory components in conditional variance and jump intensity along with verification of structural breaks for crude oil prices. We adopt a Component-ARJI model with structural break analysis, utilizing daily data on West Texas Intermediate crude oil spot and futures contracts. The analytical results verify the existence of permanent and transitory components in conditional variance, with the permanent component of conditional variance increasing with the occurrence of a sudden major event (such as the Iraqi Invasion of Kuwait, Operation Desert Storm and the war between the US and Iraq), and a relatively greater increase in the transitory component over the same period. Notably, jump intensity fluctuates with an increase in the transitory component of conditional variance in response to abnormal events. It is the transitory component which serves as the primary influential factor for jumps in returns; therefore, speculators are willing to take large risks, particularly with respect to anticipating future price movements, or gambling, in the hopes of rapidly making substantial gains; thus, speculators prefer the temporary volatility component and engage in trade activities. However, investors prefer the permanent volatility component, because they may well be better off relocating their assets into more stable portfolios to outperform the market portfolio over the long run. (author)

  8. Desulfurization of AL-Ahdab Crude Oil using Oxidative Processes

    Directory of Open Access Journals (Sweden)

    Neran Khalel Ibrahim

    2015-07-01

    Full Text Available Two different oxidative desulfurization strategies based on oxidation/adsorption or oxidation/extraction were evaluated for the desulfurization of AL-Ahdab (AHD sour crude oil (3.9wt% sulfur content. In the oxidation process, a homogenous oxidizing agent comprising of hydrogen peroxide and formic acid was used. Activated carbons were used as sorbent/catalyst in the oxidation/adsorption process while acetonitrile was used as an extraction solvent in the oxidation/extraction process. For the oxidation/adsorption scheme, the experimental results indicated that the oxidation desulfurization efficiency was enhanced on using activated carbon as catalyst/sorbent. The effects of the operating conditions (contact time, temperature, mixing speed and sorbent dose on the desulfurization efficiency were examined. The desulfurization efficiency measured at the best operating conditions(optimum conditions: 60 , 500rpm, 60min contact time and sorbent dose of 0.7g AC/100 ml AHD crude, was 32.8% corresponding to a sulfur content of 2.6 wt%. Applying the same optimum operating conditions and at 3:1 solvent/oil ratio, the oxidation/extraction method gave comparable desulfurization efficiency of 31.5%.

  9. Jump dynamics with structural breaks for crude oil prices

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Yen-Hsien [Department of Finance, Chung Yuan Christian University (China); Hu, Hsu-Ning [Department of Money, Banking and Finance, TamKang University (China); Chiou, Jer-Shiou [Department of Finance and Banking, Shih Chien University, 70 Ta-Chih Street, Taipei 104 (China)

    2010-03-15

    This study investigates the joint phenomena of permanent and transitory components in conditional variance and jump intensity along with verification of structural breaks for crude oil prices. We adopt a Component-ARJI model with structural break analysis, utilizing daily data on West Texas Intermediate crude oil spot and futures contracts. The analytical results verify the existence of permanent and transitory components in conditional variance, with the permanent component of conditional variance increasing with the occurrence of a sudden major event (such as the Iraqi Invasion of Kuwait, Operation Desert Storm and the war between the US and Iraq), and a relatively greater increase in the transitory component over the same period. Notably, jump intensity fluctuates with an increase in the transitory component of conditional variance in response to abnormal events. It is the transitory component which serves as the primary influential factor for jumps in returns; therefore, speculators are willing to take large risks, particularly with respect to anticipating future price movements, or gambling, in the hopes of rapidly making substantial gains; thus, speculators prefer the temporary volatility component and engage in trade activities. However, investors prefer the permanent volatility component, because they may well be better off relocating their assets into more stable portfolios to outperform the market portfolio over the long run. (author)

  10. Implications of lifting the ban on the export of Alaskan crude oil

    Energy Technology Data Exchange (ETDEWEB)

    1990-03-26

    Present legislation effectively bans the export of crude oil produced in the United States. The ban has been in effect for years and is particularly stringent with respect to crude oil produced in Alaska, particularly on the North Slope. The Alaska crude export ban is specifically provided for in the Trans-Alaska Pipeline Authorization Act of 1973 and in other legislation. It was imposed for two reasons. The first was to reduce US dependence on imported crude oil. The Arab oil embargo had been imposed shortly before the Act was passed and a greater measure of energy independence was considered imperative at that time. The second reason was to assure that funds expended in building an Alaskan pipeline would benefit domestic users rather than simply employed to facilitate shipments to other countries. The main objective of this report is to estimate the potential impacts on crude oil prices that would result from lifting the export ban Alaskan crude oil. The report focuses on the Japanese market and the US West Coast market. Japan is the principal potential export market for Alaskan crude oil. Exports to that market would also affect the price of Alaskan crude oil as well as crude oil and product prices on the West Coast and the volume of petroleum imported in that area. 3 figs., 8 tabs.

  11. Comparative toxicity of four crude oils to the early life stages of rainbow trout (Oncorhynchus mykiss)

    International Nuclear Information System (INIS)

    Clarke, L.M.J.; Khan, C.W.; Akhtar, P.; Hodson, P.V.; Short, J.W.

    2004-01-01

    Crude oil is a source of polycyclic aromatic hydrocarbons (PAH) in aquatic ecosystems. Fish that are chronically exposed to alkyl PAHs show dioxin-like toxicity characterized by the presence of blue sac disease (BSD) and the induction of cytochrome P4501A (CYP1A). This study compared the relative toxicity of four crude oils (Scotian Light Crude, MESA, the synthetic Federated Crude, and Alaska North Slope Crude) to early life stages of rainbow trout (Oncorhynchus mykiss). The study examined the influence of the four crudes in causing the disease in rainbow trout embryos living in simulated spawning beds with hydrocarbon-contaminated gravel. Each oil had different chemical characteristics and PAH concentrations. Mortality in the direct exposure experiment increased as the oil concentration increased. The same trend was observed for the BSD prevalence. The study showed that Scotian Light Crude was the least toxic, with BSD increasing only at the highest concentration. 7 refs., 2 tabs., 1 fig

  12. NEB view of development potential and markets for heavy crude oil. [Canada

    Energy Technology Data Exchange (ETDEWEB)

    Scotland, W A; Gutek, A M.H.

    1977-01-01

    The phased reduction in total crude oil and equivalent exports, from 911 Mpbd in 1974 to 465 Mbpd in 1976, has no doubt had a disruptive effect on the rate of development of heavy crude oil reserves. The effect could have become more series as total exports continued to drop. However, the separate licensing of heavy crude oil for export will allow heavy crude oil to enter available markets until the early 1980s. The construction of one or several upgrading facilities by the early 1980s, combined with growing domestic requirements for heavy crude oil feedstock, could make the disposition of heavy oil largely independent of the purchasing patterns of export markets. The prospect of increased market stability combined with increasing cash flows should provide an appropriate environment to optimize the role that heavy oil resources can play in Canada's future energy balance. (12 refs.)

  13. Conversion of Crude Oil to Methane by a Microbial Consortium Enriched From Oil Reservoir Production Waters

    Directory of Open Access Journals (Sweden)

    Carolina eBerdugo-Clavijo

    2014-05-01

    Full Text Available The methanogenic biodegradation of crude oil is an important process occurring in petroleum reservoirs and other oil-containing environments such as contaminated aquifers. In this process, syntrophic bacteria degrade hydrocarbon substrates to products such as acetate, and/or H2 and CO2 that are then used by methanogens to produce methane in a thermodynamically dependent manner. We enriched a methanogenic crude oil-degrading consortium from production waters sampled from a low temperature heavy oil reservoir. Alkylsuccinates indicative of fumarate addition to C5 and C6 n-alkanes were identified in the culture (above levels found in controls, corresponding to the detection of an alkyl succinate synthase gene (assA in the culture. In addition, the enrichment culture was tested for its ability to produce methane from residual oil in a sandstone-packed column system simulating a mature field. Methane production rates of up 5.8 μmol CH4/g of oil/day were measured in the column system. Amounts of produced methane were in relatively good agreement with hydrocarbon loss showing depletion of more than 50% of saturate and aromatic hydrocarbons. Microbial community analysis revealed that the enrichment culture was dominated by members of the genus Smithella, Methanosaeta, and Methanoculleus. However, a shift in microbial community occurred following incubation of the enrichment in the sandstone columns. Here, Methanobacterium sp. were most abundant, as were bacterial members of the genus Pseudomonas and other known biofilm forming organisms. Our findings show that microorganisms enriched from petroleum reservoir waters can bioconvert crude oil components to methane both planktonically and in sandstone-packed columns as test systems. Further, the results suggest that different organisms may contribute to oil biodegradation within different phases (e.g., planktonic versus sessile within a subsurface crude oil reservoir.

  14. Crude oil and stock markets. Stability, instability, and bubbles

    International Nuclear Information System (INIS)

    Miller, J. Isaac; Ratti, Ronald A.

    2009-01-01

    We analyze the long-run relationship between the world price of crude oil and international stock markets over 1971:1-2008:3 using a cointegrated vector error correction model with additional regressors. Allowing for endogenously identified breaks in the cointegrating and error correction matrices, we find evidence for breaks after 1980:5, 1988:1, and 1999:9. There is a clear long-run relationship between these series for six OECD countries for 1971:1-1980.5 and 1988:2-1999.9, suggesting that stock market indices respond negatively to increases in the oil price in the long run. During 1980.6-1988.1, we find relationships that are not statistically significantly different from either zero or from the relationships of the previous period. The expected negative long-run relationship appears to disintegrate after 1999.9. This finding supports a conjecture of change in the relationship between real oil price and real stock prices in the last decade compared to earlier years, which may suggest the presence of several stock market bubbles and/or oil price bubbles since the turn of the century. (author)

  15. Optimization of asphaltenes decantation equipment used in deasphalting process using computational fluid dynamics; Otimizacao de um equipamento para a decantacao de asfaltenos no processo de desasfaltacao usando fluidodinamica computacional

    Energy Technology Data Exchange (ETDEWEB)

    Arenales, Carlos Gregorio Dallos [Cooperativa de Trabajadores Profesionales Ltda (CTP), Santander (Colombia); Pimiento, Carlos Eduardo Lizcano; Quintero, Lina Constanza Navarro; Bueno, Jhon Ivan Penaloza [Empresa Colombiana de Petroleos S.A. (ICP/ECOPETROL), Santander (Colombia). Instituto Colombiano del Petroleo

    2012-07-01

    Heavy crude oil is a complex mixture of compounds that include saturates, aromatics, resins and asphaltenes. In this mixture, the asphaltenes are the heaviest components and can be unstable and precipitate. This kind of components causes troubles in transportation and processing. One way to reduce this problem is through technologies that use solvents, which under adequate operating conditions, separate the heavy fraction, improving the properties and conditions for transporting and refining of heavy crude oil. One of the processes used in the petroleum industry to improve the properties of heavy and residue oil is the solvent deasphalting. These processes have the disadvantage of work at elevated pressure and temperature. The Colombian Petroleum Company, ECOPETROL S.A. has developed its own process of upgrading heavy oils, ECODESF, a process that is designed to work at moderate conditions of pressure and temperature and that by using a paraffinic solvent, significantly improves the quality of heavy oil, reducing its viscosity and increasing API gravity. The present work develops a model of computational fluid dynamics (CFD) for asphaltene settler, using microscopic balance. The response of this model allowed determine: the solids flow pattern distribution and accumulation points of heavy phase. This information is useful for understanding the fluid-dynamic behavior of the system. The model was validated using data from a pilot plant with capacity for treatment 1.25 BPD of heavy crude oil. This pilot plant is located in the Colombian Petroleum Institute of ECOPETROL (ICP), Piedecuesta city, Santander, Colombia. (author)

  16. Adsorption of petroleum resins and asphaltenes onto reservoir rock sands studied by near infrared (NIR) spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Syunyaev, R.Z.; Balabin, R.M. [Russian State Univ. of Oil and Gas, Moscow (Russian Federation). Dept. of Physics; Akhatov, I.S. [North Dakota State Univ., Fargo, ND (United States). Dept. of Mechanical Engineering and Center for Nanoscale Science and Engineering

    2008-07-01

    The presence of asphaltene and resin in crude oil is known to cause well bore plugging and pipeline deposition; stabilization of water/oil emulsions; sedimentation and plugging during crude oil storage; adsorption on refining equipment and coke formation. Kinetic and thermodynamic parameters of adsorption are also known to influence wettability and the capillary number. In this study, adsorption parameters of petroleum resins and asphaltenes were evaluated by Near Infrared (NIR) spectroscopy. Fractioned quartz, dolomite, mica and kaolinite sands were used as adsorbent. The particle size distribution was evaluated using an optical microscope. Porosity and permeability of each fraction were designed and benzene was used as the solvent. Various approaches for calibrating NIR spectra-macromolecules concentration were discussed. In this study, the partial least squares (PLS) regression method was used and the Langmuir model was chosen for experimental data fitting. Kinetic and isothermic data was used to evaluate the maximal adsorbed mass density, the equilibrium constant of adsorption, and the rate constants of adsorption and desorption. The rate constants of resins adsorption and desorption depended on the concentration. A numerical algorithm was developed to estimate the diffusion coefficient and relaxation time from the experimental data.

  17. Design challenges for large Arctic crude oil tanker

    International Nuclear Information System (INIS)

    Iyerusalimskiy, A.; Noble, P.

    2008-01-01

    The Vasily Dinkov vessel was delivered by Samsung Heavy Industries shipyard to Russian ship-owner Sovcomflot. It is the largest icebreaking tanker ever built. The vessel was designed and constructed to transport crude oil from the Varandey offshore terminal in the southeastern Barents Sea to a transshipment location near Murmansk, Russia. The vessel is under long-term charter for Naryanmarneftegas, a joint venture of Lukoil and ConocoPhillips. The new ship was constructed strictly to the requirements, specification, and concept design provided by the charterer. The Varandey oil transportation concept and the vessel operational profile resulted in some conflicting requirements, compromising technical solutions, and assumptions yet to be proven in operation. This paper described the design challenges and selected approach to solve the solution to the tanker key design elements. These included the ice transit and other Arctic environmental challenges; open water performance issues; and icebreaking hull structure design challenges associated with modern shipbuilding technology standards and cost efficiency. The principle characteristics of the Vasily Dinkov were first presented and the Varandey crude oil transportation system was also described. Several features have made the Vasily Dinkov the most advanced icebreaking tanker to date, such as the icebreaking concept which has expanded the capability of both traditional icebreaking ships fitted with the icebreaker bow and double acting ships intended to operate astern only in the ice; the largest azimuthal twin screw propulsion plant for the Arctic with highest ice torque capacity ever specified for cargo vessel; and the first customized, automated, asymmetric steering control system designed to improve open water maneuverability and steering stability of podded vessels. It was concluded that the transportation system, the overall vessel concept and many of the vessel features require validation based on operational

  18. Induction of reactive oxygen species in marine phytoplankton under crude oil exposure.

    Science.gov (United States)

    Ozhan, Koray; Zahraeifard, Sara; Smith, Aaron P; Bargu, Sibel

    2015-12-01

    Exposure of phytoplankton to the water-accommodated fraction of crude oil can elicit a number of stress responses, but the mechanisms that drive these responses are unclear. South Louisiana crude oil was selected to investigate its effects on population growth, chlorophyll a (Chl a) content, antioxidative defense, and lipid peroxidation, for the marine diatom, Ditylum brightwellii, and the dinoflagellate, Heterocapsa triquetra, in laboratory-based microcosm experiments. The transcript levels of several possible stress-responsive genes in D. brightwellii were also measured. The microalgae were exposed to crude oil for up to 96 h, and Chl a content, superoxide dismutase (SOD), the glutathione pool (GSH and GSSG), and lipid peroxidation content were analyzed. The cell growth of both phytoplankton species was inhibited with increasing crude oil concentrations. Crude oil exposure did not affect Chl a content significantly in cells. SOD activities showed similar responses in both species, being enhanced at 4- and 8-mg/L crude oil exposure. Only H. triquetra demonstrated enhanced activity in GSSG pool and lipid peroxidation at 8-mg/L crude oil exposure, suggesting that phytoplankton species have distinct physiological responses and tolerance levels to crude oil exposure. This study indicated the activation of reactive oxygen species (ROS) in phytoplankton under crude oil exposure; however, the progressive damage in cells is still unknown. Thus, ROS-related damage in nucleic acid, lipids, proteins, and DNA, due to crude oil exposure could be a worthwhile subject of study to better understand crude oil toxicity at the base of the food web.

  19. Effects of crude oil pollution on the germination of Zea mays and Capsicum frutescens

    Energy Technology Data Exchange (ETDEWEB)

    Amakiri, J.O.; Onofeghara, F.A.

    1984-01-01

    The effects of crude oil pollution on the germination of Zea mays F7 and F27 and Capsicum frutescens were investigated. Crude oil was found to inhibit the germination of all the seed types used. The rate of germination decreased signficantly with increase in the length of the period of presoaking. The germination percentage of oil-soaked seeds of Zea mays also fell significantly with time. Seeds of Capsicum frutescens are most tolerant of crude oil in their germination response. The seeds were found to retain almost 100% viability after nearly 1 year of presoaking in crude oil. The lag phase preceding the germination of such seeds, however, increased threefold. Germination inhibition is attributed primarily to the physical surface characteristics of soil, which make it function as a physical barrier to water and oxygen. However, crude oil, where it penetrates, may be toxic to the embryos.

  20. Corrosion of mild steel, copper and brass in crude oil / seawater mixture

    Digital Repository Service at National Institute of Oceanography (India)

    PrabhaDevi, S.; Sawant, S.S.; Wagh, A.B.

    Mild steel, copper and brass coupons were introduced in natural seawater containing varying amount of crude oil. Mild steel showed higher rate of corrosion in seawater containing oil and lower corrosion rate in natural as well as artificial seawater...

  1. Can reserve additions in mature crude oil provinces attenuate peak oil?

    NARCIS (Netherlands)

    Okullo, S.J.; Reynes, F.G.D.

    2011-01-01

    Following the peak in US crude oil production 30 years ago, more and more non-OPEC producers have seen their production decline as a result of resource depletion. OPEC, on the other hand has extracted a comparatively smaller proportion of its reserve base. Given that new non-OPEC discoveries are

  2. Application of microbiological methods for secondary oil recovery from the Carpathian crude oil reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Karaskiewicz, J

    1974-01-01

    The investigation made it possible to isolate from different ecologic environmental (soil, crude oil, formation water, industrial wastes) bacteria cultures of the genus Arthrobacter, Clostridium, Mycobacterium, Peptococcus, and Pseudomonas. These heterotrophic bacteria are characterized by a high metabolic and biogeochemical activity hydrocarbon transformation. Experiments on a technical scale were conducted from 1961 to 1971 in 20 wells; in this study, only the 16 most typical examples are discussed. The experiments were conducted in Carpathian crude oil reservoirs. To each well, a 500:1 mixture of the so-called bacteria vaccine (containing an active biomass of cultures obtained by a specific cultivation method and holding 6 x 10/sup 5/ bacteria cells in 1 ml of fluid, 2,000 kg of molasses, and 50 cu m of water originating from the reservoir submitted to treatment) was injected at 500 to 1,200 m. The intensification of the microbiological processes in the reservoir was observed. This phenomenon occurred not only in the wells to which the bacteria vaccine was injected, but also in the surrounding producing wells. At the same time, an increase in the crude oil production occurred on the average within the range from 20 to 200% and the surpluses of crude oil production continued for 2 to 8 yr. (92 refs.)

  3. Cross-correlations between crude oil and exchange markets for selected oil rich economies

    Science.gov (United States)

    Li, Jianfeng; Lu, Xinsheng; Zhou, Ying

    2016-07-01

    Using multifractal detrended cross-correlation analysis (MF-DCCA), this paper studies the cross-correlation behavior between crude oil market and five selected exchange rate markets. The dataset covers the period of January 1,1996-December 31,2014, and contains 4,633 observations for each of the series, including daily closing prices of crude oil, Australian Dollars, Canadian Dollars, Mexican Pesos, Russian Rubles, and South African Rand. Our empirical results obtained from cross-correlation statistic and cross-correlation coefficient have confirmed the existence of cross-correlations, and the MF-DCCA results have demonstrated a strong multifractality between cross-correlated crude oil market and exchange rate markets in both short term and long term. Using rolling window analysis, we have also found the persistent cross-correlations between the exchange rates and crude oil returns, and the cross-correlation scaling exponents exhibit volatility during some time periods due to its sensitivity to sudden events.

  4. Causes for an asymmetric relation between the price of crude oil and refined petroleum products

    International Nuclear Information System (INIS)

    Kaufmann, R.K.; Laskowski, C.

    2005-01-01

    We revisit the issue of asymmetries in the relation between the price of crude oil and refined petroleum products in the United States. An econometric analysis of monthly data indicates that the asymmetric relationship between the price of crude oil and motor gasoline is generated by refinery utilization rates and inventory behavior. The asymmetric relation between the price of crude oil and home heating oil probably is generated by contractual arrangements between retailers and consumers. Together, these results imply that price asymmetries may be generated by efficient markets. Under these conditions, there is little justification for policy interventions to reduce or eliminate price asymmetries in motor gasoline and home heating oil markets. (author)

  5. Indigenous production of biosurfactant and degradation of crude oil

    Directory of Open Access Journals (Sweden)

    Hamid Rashedi

    2015-04-01

    Full Text Available The present study investigated the isolation and identification of biosurfactant producing bacteria from Iranian oil wells. The biosurfactant production of bacteria isolates was evaluated and confirmed using hemolysis and emulsification tests. The biodegradation of crude oil was studied using GC and HPLC analysis. A total of 45 strains have been isolated. These strains showed less than a 40 mN m-1 reduction in surface tension. The effects of different pH (4.2-9.2, salinity concentrations (1%-15%, and temperatures (25-50 in biosurfactant production of isolated strains were evaluated. One of the strains (Bacillus sp. NO.4 showed a high salt tolerance and a successful production of biosurfactant in a vast pH range. Its maximum biomass production (about 3.1 g L-1 dry weight was achieved after 60 hours of growth. The surface tension of the culture broth dropped rapidly after inoculation and reached its lowest value (36 mN m-1 during the exponential phase after about 36-48 hours of growth. The study of the GC graphs showed that higher aliphatic reduction occurred in fractions with C14 to C24 hydrocarbons. The depicted results of the HPLC graphs indicated a 100% degradation of chrysene and fluorine. In this study, we demonstrated the useful capacities of the isolates in removing oil pollutants and their application in MEOR in vitro.

  6. Interactions between zooplankton and crude oil: toxic effects and bioaccumulation of polycyclic aromatic hydrocarbons.

    Directory of Open Access Journals (Sweden)

    Rodrigo Almeda

    Full Text Available We conducted ship-, shore- and laboratory-based crude oil exposure experiments to investigate (1 the effects of crude oil (Louisiana light sweet oil on survival and bioaccumulation of polycyclic aromatic hydrocarbons (PAHs in mesozooplankton communities, (2 the lethal effects of dispersant (Corexit 9500A and dispersant-treated oil on mesozooplankton, (3 the influence of UVB radiation/sunlight exposure on the toxicity of dispersed crude oil to mesozooplankton, and (4 the role of marine protozoans on the sublethal effects of crude oil and in the bioaccumulation of PAHs in the copepod Acartia tonsa. Mortality of mesozooplankton increased with increasing oil concentration following a sigmoid model with a median lethal concentration of 32.4 µl L(-1 in 16 h. At the ratio of dispersant to oil commonly used in the treatment of oil spills (i.e. 1∶20, dispersant (0.25 µl L(-1 and dispersant-treated oil were 2.3 and 3.4 times more toxic, respectively, than crude oil alone (5 µl L(-1 to mesozooplankton. UVB radiation increased the lethal effects of dispersed crude oil in mesozooplankton communities by 35%. We observed selective bioaccumulation of five PAHs, fluoranthene, phenanthrene, pyrene, chrysene and benzo[b]fluoranthene in both mesozooplankton communities and in the copepod A. tonsa. The presence of the protozoan Oxyrrhis marina reduced sublethal effects of oil on A. tonsa and was related to lower accumulations of PAHs in tissues and fecal pellets, suggesting that protozoa may be important in mitigating the harmful effects of crude oil exposure in copepods and the transfer of PAHs to higher trophic levels. Overall, our results indicate that the negative impact of oil spills on mesozooplankton may be increased by the use of chemical dispersant and UV radiation, but attenuated by crude oil-microbial food webs interactions, and that both mesozooplankton and protozoans may play an important role in fate of PAHs in marine environments.

  7. Interactions between Zooplankton and Crude Oil: Toxic Effects and Bioaccumulation of Polycyclic Aromatic Hydrocarbons

    Science.gov (United States)

    Almeda, Rodrigo; Wambaugh, Zoe; Wang, Zucheng; Hyatt, Cammie; Liu, Zhanfei; Buskey, Edward J.

    2013-01-01

    We conducted ship-, shore- and laboratory-based crude oil exposure experiments to investigate (1) the effects of crude oil (Louisiana light sweet oil) on survival and bioaccumulation of polycyclic aromatic hydrocarbons (PAHs) in mesozooplankton communities, (2) the lethal effects of dispersant (Corexit 9500A) and dispersant-treated oil on mesozooplankton, (3) the influence of UVB radiation/sunlight exposure on the toxicity of dispersed crude oil to mesozooplankton, and (4) the role of marine protozoans on the sublethal effects of crude oil and in the bioaccumulation of PAHs in the copepod Acartia tonsa. Mortality of mesozooplankton increased with increasing oil concentration following a sigmoid model with a median lethal concentration of 32.4 µl L−1 in 16 h. At the ratio of dispersant to oil commonly used in the treatment of oil spills (i.e. 1∶20), dispersant (0.25 µl L−1) and dispersant- treated oil were 2.3 and 3.4 times more toxic, respectively, than crude oil alone (5 µl L−1) to mesozooplankton. UVB radiation increased the lethal effects of dispersed crude oil in mesozooplankton communities by 35%. We observed selective bioaccumulation of five PAHs, fluoranthene, phenanthrene, pyrene, chrysene and benzo[b]fluoranthene in both mesozooplankton communities and in the copepod A. tonsa. The presence of the protozoan Oxyrrhis marina reduced sublethal effects of oil on A. tonsa and was related to lower accumulations of PAHs in tissues and fecal pellets, suggesting that protozoa may be important in mitigating the harmful effects of crude oil exposure in copepods and the transfer of PAHs to higher trophic levels. Overall, our results indicate that the negative impact of oil spills on mesozooplankton may be increased by the use of chemical dispersant and UV radiation, but attenuated by crude oil-microbial food webs interactions, and that both mesozooplankton and protozoans may play an important role in fate of PAHs in marine environments. PMID:23840628

  8. Phytoremediation of some tropical soils contaminated with petroleum crude oil

    International Nuclear Information System (INIS)

    Oyibo, Charles

    2013-12-01

    This study was undertaken in three phases to identify (phase 1), screen (phase 11) and evaluate (phase 111) plants for their phytoremediation potential. In Phase 1, 15 plant species made up of grasses and legumes namely: Paspalum. vaginatum, Cynodon.dactylon, Pueraria. phaseoloides, Centrosema. pubescens, Panicum. maximum, Schrankia. leptocarpa, Eclipta. alba (Linn.), Cyperus. haspen (Linn.), Melastromastrum. capitatum, Acreceras. zizanoides Dandy, Pteridum aquilinum (Linn), Ludwigia.decurrens Walt,Setaria longiseta P.Beauv., Physalis angulata (Linn.), and Desmodium scorpiurus Desv.were identified on sites previously polluted by crude oil spills in the Niger Delta Area of Nigeria. The first 6 species were used in phase 11 while the first four species were earmarked (rolled over) for phase 111. Responses to Questionnaire indicated that majority of residents in the selected sites/communities had lived in these areas for 10 or more years had mainly JHS/SHS education; were self employed – mainly farmers and fishers although most were unemployed in the public sector. Adverse effects of the operations of oil companies particularly oil spillage on the environment and local residents include: loss of vegetation and farmlands, soil and water body contamination, weak social and cultural institutions (disrespect by youth for elders and institutions), militancy and hostage taking among youth from the area. In phase 11, seeds of legumes among the six selected species were collected from Accra, Aburi environs and Kusi in the Eastern region of Ghana; they were scarified, cultured in growth medium and the seedlings which emerged from them were transplanted into experimental pots, each containing 2000g of either Alajo or Toje soil series. One week after transplanting, each pot was simulated with a corresponding serial crude oil concentration of 0% (control) 1 % (24ml), 3% (83ml), 5.5% (130ml) and 8% (189ml) or 10% (237ml) in three replicates. These concentrations were arrived at

  9. An analysis of price and volatility transmission in butter, palm oil and crude oil markets

    Directory of Open Access Journals (Sweden)

    Dennis Bergmann

    2016-11-01

    Full Text Available Abstract Recent changes to the common agricultural policy (CAP saw a shift to greater market orientation for the EU dairy industry. Given this reorientation, the volatility of EU dairy commodity prices has sharply increased, creating the need to develop proper risk management tools to protect farmers’ income and to ensure stable prices for processors and consumers. In addition, there is a perceived threat that these commodities may be replaced by cheaper substitutes, such as palm oil, as dairy commodity prices become more volatile. Global production of palm oil almost doubled over the last decade while butter production remained relatively flat. Palm oil also serves as a feedstock for biodiesel production, thus establishing a new link between agricultural commodities and crude oil. Price and volatility transmission effects between EU and World butter prices, as well as between butter, palm oil and crude oil prices, before and after the Luxembourg agreement, are analysed. Vector autoregression (VAR models are applied to capture price transmission effects between these markets. These are combined with a multivariate GARCH model to account for potential volatility transmission. Results indicate strong price and volatility transmission effects between EU and World butter prices. EU butter shocks further spillover to palm oil volatility. In addition, there is evidence that oil prices spillover to World butter prices and World butter volatility.

  10. Optimization of China Crude Oil Transportation Network with Genetic Ant Colony Algorithm

    Directory of Open Access Journals (Sweden)

    Yao Wang

    2015-08-01

    Full Text Available Taking into consideration both shipping and pipeline transport, this paper first analysed the risk factors for different modes of crude oil import transportation. Then, based on the minimum of both transportation cost and overall risk, a multi-objective programming model was established to optimize the transportation network of crude oil import, and the genetic algorithm and ant colony algorithm were employed to solve the problem. The optimized result shows that VLCC (Very Large Crude Carrier is superior in long distance sea transportation, whereas pipeline transport is more secure than sea transport. Finally, this paper provides related safeguard suggestions on crude oil import transportation.

  11. Learning Crude Oil by Using Scientific Literacy Comics

    Science.gov (United States)

    Aisyah, R.; Zakiyah, I. A.; Farida, I.; Ramdhani, M. A.

    2017-09-01

    A research has been conducted to create a crude oil learning media in the form of scientific literacy-oriented comic. The research included some phases, namely: concept analysis, material transformation to concept map, indicator identification and science literacy aspect. The product was made based on flowcharts and storyboards that have been validated by expert validators. The product has characteristics namely; 1) Develops indicators and aspects of science literacy, 2) presents the materials in form of story of science fiction genre, 3) has characters adopting levels of scientific literacy, 4) has optional stories, because it depends on questions asked to develop scientific literacy in terms of content, context, process and attitude. Based on feasibility test, the product is feasible to be used as learning media. It is suggested to do an expanded experiment to examine its affectivity in improving scientific literacy and growing students’ awareness about the issues of energy crisis and the impacts of fossil fuel use on the environment.

  12. Enhancing crude oil degradation in a sandy soil: Effects of addition ...

    African Journals Online (AJOL)

    This study investigated the effects of the addition of poultry manure alone and in combination with surfactant (Goldcrew or Corexit) and/or alternate carbon substrate (glucose or starch) on crude oil degradation in a sandy soil. With poultry manure alone, optimal crude oil degradation was obtained at a concentration of 4.0% ...

  13. Bioremediation Potential of Native Hydrocarbons Degrading Bacteria in Crude Oil Polluted Soil

    Directory of Open Access Journals (Sweden)

    Mariana MARINESCU

    2017-05-01

    Full Text Available Bioremediation of crude oil contaminated soil is an effective process to clean petroleum pollutants from the environment. Crude oil bioremediation of soils is limited by the bacteria activity in degrading the spills hydrocarbons. Native crude oil degrading bacteria were isolated from different crude oil polluted soils. The isolated bacteria belong to the genera Pseudomonas, Mycobacterium, Arthrobacter and Bacillus. A natural biodegradable product and bacterial inoculum were used for total petroleum hydrocarbon (TPH removal from an artificial polluted soil. For soil polluted with 5% crude oil, the bacterial top, including those placed in the soil by inoculation was 30 days after impact, respectively 7 days after inoculum application, while in soil polluted with 10% crude oil,  multiplication top of bacteria was observed in the determination made at 45 days after impact and 21 days after inoculum application, showing once again how necessary is for microorganisms habituation and adaptation to environment being a function of pollutant concentration. The microorganisms inoculated showed a slight adaptability in soil polluted with 5% crude oil, but complete inhibition in the first 30 days of experiment at 10% crude oil.

  14. Impact of the discovery of crude oil on inter-group relations between ...

    African Journals Online (AJOL)

    Impact of the discovery of crude oil on inter-group relations between Isoko and her immediate neighbours in the western Niger Delta of Nigeria. ... The article shows that the discovery of crude oil petroleum in the western Niger Delta marked a watershed in the history of intergroup relations in the area. Keywords: Discovery ...

  15. A Formula for the Coefficient of Thermal Expansion of Crude Oils ...

    African Journals Online (AJOL)

    A new formula for the calculation of the coefficient of world crude oils has been developed. The formula is semi theoretical. The empirical part was obtained by regression calculation of the Formation Volume Factor of the gas free crude oil at reservoir temperature. Comparison of the calculated values of the Formation ...

  16. Reduction of Sulphur Content of Urals Crude Oil Prior to Processing ...

    African Journals Online (AJOL)

    The presence of sulphur in crude oil poses enormous challenges as regards its negative environmental and economic impacts. As such, the safety of the personnel and the equipment is at high risk during the processing of Urals crude oil in Kaduna Refining and Petrochemical Company (KRPC) because of its sour nature.

  17. Price elasticity of demand for crude oil: estimates for 23 countries

    International Nuclear Information System (INIS)

    Cooper, J.C.B.

    2003-01-01

    This paper uses a multiple regression model derived from an adaptation of Nerlove's partial adjustment model to estimate both the short-run and long-run elasticities of demand for crude oil in 23 countries. The estimates so obtained confirm that the demand for crude oil internationally is highly insensitive to changes in price. (author)

  18. Studies on sludge from waxy crude oil storage tank. II. Solvent fractionation

    Energy Technology Data Exchange (ETDEWEB)

    Fazal, S.A.; Zarapkar, S.S.; Joshi, G.C. [D.G. Ruparel College, Bombay (India). Dept. of Chemistry

    1995-12-31

    The sludge formed from crude oil (Bombay Hindu Crude oil) dump storage has been analysed by solvent extraction with a series of solvents of increasing polarity. The extract fractions so obtained have been analysed extensively. The nature of the sludge is compared with the similar sludges reported by other workers. 9 refs., 4 figs., 2 tabs.

  19. Density and viscosity behavior of a North Sea crude oil, natural gas liquid, and their mixtures

    DEFF Research Database (Denmark)

    Schmidt, KAG; Cisneros, Sergio; Kvamme, B

    2005-01-01

    to accurately model the saturation pressures, densities, and viscosities of petroleum systems ranging from natural gases to heavy crude oils. The applicability of this overall modeling technique to reproduce measured bubble points, densities, and viscosities of a North Sea crude oil, a natural gas liquid...

  20. Comparison of the effects of crude and spent oils on Tilapia ...

    African Journals Online (AJOL)

    Toxic effects of bonnylight crude and spent oils on Oreochromis niloticus fingerlings were conducted under laboratory conditions at the University of Port Harcourt, Nigeria for two months. Five concentrations (5 ml/L, 10 ml/L, 20 m1/L, 50 m1/L and l00 ml/L) of water soluble fraction (WSF) of crude and spent oils were ...

  1. 75 FR 11841 - Proposed Information Collection; Comment Request; Short Supply Regulations, Petroleum (Crude Oil)

    Science.gov (United States)

    2010-03-12

    ... DEPARTMENT OF COMMERCE Bureau of Industry and Security Proposed Information Collection; Comment Request; Short Supply Regulations, Petroleum (Crude Oil) AGENCY: Bureau of Industry and Security. ACTION... supporting documentation for license applications to export petroleum (crude oil) and is used by licensing...

  2. An estimation of crude oil import demand in Turkey: Evidence from time-varying parameters approach

    International Nuclear Information System (INIS)

    Ozturk, Ilhan; Arisoy, Ibrahim

    2016-01-01

    The aim of this study is to model crude oil import demand and estimate the price and income elasticities of imported crude oil in Turkey based on a time-varying parameters (TVP) approach with the aim of obtaining accurate and more robust estimates of price and income elasticities. This study employs annual time series data of domestic oil consumption, real GDP, and oil price for the period 1966–2012. The empirical results indicate that both the income and price elasticities are in line with the theoretical expectations. However, the income elasticity is statistically significant while the price elasticity is statistically insignificant. The relatively high value of income elasticity (1.182) from this study suggests that crude oil import in Turkey is more responsive to changes in income level. This result indicates that imported crude oil is a normal good and rising income levels will foster higher consumption of oil based equipments, vehicles and services by economic agents. The estimated income elasticity of 1.182 suggests that imported crude oil consumption grows at a higher rate than income. This in turn reduces oil intensity over time. Therefore, crude oil import during the estimation period is substantially driven by income. - Highlights: • We estimated the price and income elasticities of imported crude oil in Turkey. • Income elasticity is statistically significant and it is 1.182. • The price elasticity is statistically insignificant. • Crude oil import in Turkey is more responsive to changes in income level. • Crude oil import during the estimation period is substantially driven by income.

  3. A laboratory study of particulate and gaseous emissions from crude oil and crude oil-dispersant contaminated seawater due to breaking waves

    Science.gov (United States)

    Afshar-Mohajer, Nima; Li, Cheng; Rule, Ana M.; Katz, Joseph; Koehler, Kirsten

    2018-04-01

    Crude oil spill incidents occur frequently causing a verity of occupational, ecological and environmental problems. Dispersants are applied to enhance the dispersion rate of crude oil slicks into the water column. In this study, the aerosol size distribution from 10 nm to 20 μm, total particle-bound aromatic hydrocarbons (pPAH) and volatile organic compounds (VOCs) are measured in a 6 x 0.3 x 0.6 m tank as plunging breaking waves entrain oil slicks. The experiments are performed for seawater with slicks of crude oil, crude oil-dispersant mixture and dispersant only. The measurements investigate the effects of wave energy and slick properties on the temporal evolution of the emissions. The total number concentrations of particles originating from the oil-dispersant mixture are 1-2 orders of magnitude higher than those of crude oil across the entire nano-scale range, reaching 100x for 20 nm particles. Conversely, the differences in concentration are small in the micron range. The average concentrations of pPAH are variable but similar (150-270 ng/m3). The VOC concentrations for crude oil-dispersant mixtures are 2-3 times lower than those of crude oil, presumably due to the surfactant effect on mass diffusion. The drastic increase in ultrafine particle concentrations may raise concerns about effects of inhalation by cleanup workers and downstream communities though VOC emissions reduce. Findings through this study provide insight into how the spray of dispersant may change the ratio of airborne particulate matter and VOC emissions from seawater due to natural processes.

  4. The Effect Of Additional Detergent In Crude Palm Oil In The Process Of Separation Stearin

    Science.gov (United States)

    Rezekyah Hasibuan, Vina; aini, Nur; Febriyanti; Ayubi Pane, Salahudin Al

    2018-03-01

    This study aims to find out how much stearin is formed from the addition of detergent and to understand the process of separation of crude olein with crude stearin from raw material of crude palm oil (CPO). Using a detergent fractionation system, detergent fractionation is a continuous crystallization of oil with controlled cooling and the separation of fractions by weight or centrifuge after supplementing surfactant.

  5. Sequential enrichment of microbial population exhibiting enhanced biodegradation of crude oil

    International Nuclear Information System (INIS)

    Venkateswaran, Kasthuri; Harayama, Shigeaki.

    1995-01-01

    The distribution of oil-degrading bacteria in the coastal waters and sediments of Hokkaido, Japan, was surveyed. It was found that the potential of mixed microbial populations to degrade weathered crude oil was not confined to any ecological components (water or sediment) nor to the sampling stations. One microbial culture that was stable during repeated subculturing degraded 45% of the saturates and 20% of the aromatics present in crude oil in 10 days during the initial screening. The residual hydrocarbons in this culture were extracted by chloroform and dispersed in a fresh seawater-based medium and subsequently inoculated with microorganisms from the first culture. After full growth of the second culture, the residual hydrocarbons were extracted and dispersed in a fresh medium in which microorganisms from the second culture had been inoculated. This sequential process was carried out six times to enrich those microorganisms that grew on the recalcitrant components of crude oil. After repeated exposure of the residual crude oil to the enriched microorganisms, about 80% of the initially added crude oil was degraded. The cultures obtained after each enrichment cycle were kept, and the degradation of fresh crude oil by the enriched microorganisms was monitored. The degrading activity of the enriched cultures increased as the number of enrichment cycles increased. A microbial population that had been selected six times on the residual crude oil could degrade 70% of the saturates and 30% of the aromatics of crude oil, indicating that growth of a microbial population on residual crude oil improved its ability to biodegrade crude oil. 21 refs., 2 tabs., 7 figs

  6. Downhole Upgrading of Orinoco Basin Extra-Heavy Crude Oil Using Hydrogen Donors under Steam Injection Conditions. Effect of the Presence of Iron Nanocatalysts

    Directory of Open Access Journals (Sweden)

    Cesar Ovalles

    2015-03-01

    Full Text Available An extra-heavy crude oil underground upgrading concept and laboratory experiments are presented which involve the addition of a hydrogen donor (tetralin to an Orinoco Basin extra-heavy crude oil under steam injection conditions (280–315 °C and residence times of at least 24-h. Three iron-containing nanocatalysts (20 nm, 60 nm and 90 nm were used and the results showed increases of up to 8° in API gravity, 26% desulfurization and 27% reduction in the asphaltene content of the upgraded product in comparison to the control reaction using inert sand. The iron nanocatalysts were characterized by SEM, XPS, EDAX, and Mössbauer spectroscopy before and after the upgrading reactions. The results indicated the presence of hematite (Fe2O3 as the predominant iron phase. The data showed that the catalysts were deactivating by particle sintering (~20% increase in particle size and also by carbon deposition. Probable mechanisms of reactions are proposed.

  7. Rheological Investigation on the Effect of Shear and Time Dependent Behavior of Waxy Crude Oil

    Directory of Open Access Journals (Sweden)

    Japper-Jaafar A.

    2014-07-01

    Full Text Available Rheological measurements are essential in transporting crude oil, especially for waxy crude oil. Several rheological measurements have been conducted to determine various rheological properties of waxy crude oil including the viscosity, yield strength, wax appearance temperature (WAT, wax disappearance temperature (WDT, storage modulus and loss modulus, amongst others, by using controlled stress rheometers. However, a procedure to determine the correct parameters for rheological measurements is still unavailable in the literature. The paper aims to investigate the effect of shear and time dependent behaviours of waxy crude oil during rheological measurements. It is expected that the preliminary work could lead toward a proper rheological measurement guideline for reliable rheological measurement of waxy crude oil.

  8. Multifractal detrended cross-correlations between crude oil market and Chinese ten sector stock markets

    Science.gov (United States)

    Yang, Liansheng; Zhu, Yingming; Wang, Yudong; Wang, Yiqi

    2016-11-01

    Based on the daily price data of spot prices of West Texas Intermediate (WTI) crude oil and ten CSI300 sector indices in China, we apply multifractal detrended cross-correlation analysis (MF-DCCA) method to investigate the cross-correlations between crude oil and Chinese sector stock markets. We find that the strength of multifractality between WTI crude oil and energy sector stock market is the highest, followed by the strength of multifractality between WTI crude oil and financial sector market, which reflects a close connection between energy and financial market. Then we do vector autoregression (VAR) analysis to capture the interdependencies among the multiple time series. By comparing the strength of multifractality for original data and residual errors of VAR model, we get a conclusion that vector auto-regression (VAR) model could not be used to describe the dynamics of the cross-correlations between WTI crude oil and the ten sector stock markets.

  9. Some technological aspects for functioning of crude oil pipeline Solun-OKTA

    International Nuclear Information System (INIS)

    Zikovski, Toni

    2005-01-01

    Crude oil pipeline Solun-Okta was built according to international technical, ecological and safety standards and enables quick, optimal and continuity supply of OKTA Refinery with crude oil. The building of the pipeline began in 1999 and finished in 2002 with official start-up operation by pumping of first quantity crude oil. After the activation, human environment protection has an important place. A lot of instructions and procedures are prepared specially for this purpose. With a total length about 212 km, pipeline enables transport of crude oil from ECO Refinery to OKTA with a capacity of 2.5 million tons per year. The pipeline is designed for transport of few types crude oil and their mixtures. The pipeline system has been equipped with sophisticated and modern equipment, which will enable quality of the work by controlling and monitoring of the system. (Author)

  10. Some technological aspects for functioning of crude oil pipeline Solun-Okta

    International Nuclear Information System (INIS)

    Zikovski, Toni

    2005-01-01

    Crude oil pipeline Solun-Okta was built according to international technical, ecological and safety standards and enables quick, optimal and continuity supply of OKTA Refinery with crude oil. The building of the pipeline began in 1999 and finished in 2002 with official start-up operation by pumping of first quantity crude oil. After the activation, human environment protection has an important place. A lot of instructions and procedures are prepared specially for this purpose. With a total length about 212 km, pipeline enables transport of crude oil from ECO Refinery to OKTA with a capacity of 2.5 million tons per year. The pipeline is designed for transport of few types crude oil and their mixtures. The pipeline system has been equipped with sophisticated and modern equipment, which will enable quality of the work by controlling and monitoring of the system. (Author)

  11. Does Climate Change Mitigation Activity Affect Crude Oil Prices? Evidence from Dynamic Panel Model

    Directory of Open Access Journals (Sweden)

    Jude C. Dike

    2014-01-01

    Full Text Available This paper empirically investigates how climate change mitigation affects crude oil prices while using carbon intensity as the indicator for climate change mitigation. The relationship between crude oil prices and carbon intensity is estimated using an Arellano and Bond GMM dynamic panel model. This study undertakes a regional-level analysis because of the geographical similarities among the countries in a region. Regions considered for the study are Africa, Asia and Oceania, Central and South America, the EU, the Middle East, and North America. Results show that there is a positive relationship between crude oil prices and carbon intensity, and a 1% change in carbon intensity is expected to cause about 1.6% change in crude oil prices in the short run and 8.4% change in crude oil prices in the long run while the speed of adjustment is 19%.

  12. Price and income elasticities of crude oil import demand in South Africa. A cointegration analysis

    Energy Technology Data Exchange (ETDEWEB)

    Ziramba, Emmanuel [Department of Economics, University of South Africa, P.O Box 392, Unisa 0003 (South Africa)

    2010-12-15

    This paper examines the demand for imported crude oil in South Africa as a function of real income and the price of crude oil over the period 1980-2006. We carried out the Johansen co integration multivariate analysis to determine the long-run income and price elasticities. A unique long-run cointegration relationship exists between crude oil imports and the explanatory variables. The short-run dynamics are estimated by specifying a general error correction model. The estimated long-run price and income elasticities of -0.147 and 0.429 suggest that import demand for crude oil is price and income inelastic. There is also evidence of unidirectional long-run causality running from real GDP to crude oil imports. (author)

  13. Probing the Carbonyl Functionality of a Petroleum Resin and Asphaltene through Oximation and Schiff Base Formation in Conjunction with N-15 NMR.

    Directory of Open Access Journals (Sweden)

    Kevin A Thorn

    Full Text Available Despite recent advances in spectroscopic techniques, there is uncertainty regarding the nature of the carbonyl groups in the asphaltene and resin fractions of crude oil, information necessary for an understanding of the physical properties and environmental fate of these materials. Carbonyl and hydroxyl group functionalities are not observed in natural abundance 13C nuclear magnetic resonance (NMR spectra of asphaltenes and resins and therefore require spin labeling techniques for detection. In this study, the carbonyl functionalities of the resin and asphaltene fractions from a light aliphatic crude oil that is the source of groundwater contamination at the long term USGS study site near Bemidji, Minnesota, have been examined through reaction with 15N-labeled hydroxylamine and aniline in conjunction with analysis by solid and liquid state 15N NMR. Ketone groups were revealed through 15N NMR detection of their oxime and Schiff base derivatives, and esters through their hydroxamic acid derivatives. Anilinohydroquinone adducts provided evidence for quinones. Some possible configurations of the ketone groups in the resin and asphaltene fractions can be inferred from a consideration of the likely reactions that lead to heterocyclic condensation products with aniline and to the Beckmann reaction products from the initially formed oximes. These include aromatic ketones and ketones adjacent to quaternary carbon centers, β-hydroxyketones, β-diketones, and β-ketoesters. In a solid state cross polarization/magic angle spinning (CP/MAS 15N NMR spectrum recorded on the underivatized asphaltene as a control, carbazole and pyrrole-like nitrogens were the major naturally abundant nitrogens detected.

  14. Probing the carbonyl functionality of a petroleum resin and asphaltene through oximation and schiff base formation in conjunction with N-15 NMR

    Science.gov (United States)

    Thorn, Kevin A.; Cox, Larry G.

    2015-01-01

    Despite recent advances in spectroscopic techniques, there is uncertainty regarding the nature of the carbonyl groups in the asphaltene and resin fractions of crude oil, information necessary for an understanding of the physical properties and environmental fate of these materials. Carbonyl and hydroxyl group functionalities are not observed in natural abundance 13C nuclear magnetic resonance (NMR) spectra of asphaltenes and resins and therefore require spin labeling techniques for detection. In this study, the carbonyl functionalities of the resin and asphaltene fractions from a light aliphatic crude oil that is the source of groundwater contamination at the long term USGS study site near Bemidji, Minnesota, have been examined through reaction with 15N-labeled hydroxylamine and aniline in conjunction with analysis by solid and liquid state 15N NMR. Ketone groups were revealed through 15N NMR detection of their oxime and Schiff base derivatives, and esters through their hydroxamic acid derivatives. Anilinohydroquinone adducts provided evidence for quinones. Some possible configurations of the ketone groups in the resin and asphaltene fractions can be inferred from a consideration of the likely reactions that lead to heterocyclic condensation products with aniline and to the Beckmann reaction products from the initially formed oximes. These include aromatic ketones and ketones adjacent to quaternary carbon centers, β-hydroxyketones, β-diketones, and β-ketoesters. In a solid state cross polarization/magic angle spinning (CP/MAS) 15N NMR spectrum recorded on the underivatized asphaltene as a control, carbazole and pyrrole-like nitrogens were the major naturally abundant nitrogens detected.

  15. Effects of selected thermophilic microorganisms on crude oils at elevated temperatures and pressures. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Premuzic, E.T.; Lin, M.S.

    1995-07-01

    During the past several years, a considerable amount of work has been carried out showing that microbially enhanced oil recovery (MEOR) is promising and the resulting biotechnology may be deliverable. At the Brookhaven National Laboratory (BNL), systematic studies have been conducted which dealt with the effects of thermophilic and thermoadapted bacteria on the chemical and physical properties of selected types of crude oils at elevated temperatures and pressures. Particular attention was paid to heavy crude oils from Venezuela, California, Alabama, Arkansas, Wyoming, Alaska, and other oil producing areas. Current studies indicate that during the biotreatment several chemical and physical properties of crude oils are affected. The oils are (1) emulsified; (2) acidified; (3) there is a qualitative and quantitative change in light and heavy fractions of the crudes; (4) there are chemical changes in fractions containing sulfur compounds; (5) there is an apparent reduction in the concentration of trace metals; (6) the qualitative and quantitative changes appear to be microbial species dependent; and (7) there is a distinction between {open_quotes}biodegraded{close_quotes} and {open_quotes}biotreated{close_quotes} oils. Preliminary results indicate the introduced microorganisms may become the dominant species in the bioconversion of oils. These studies also indicate the biochemical interactions between crude oils and microorganisms follow distinct trends, characterized by a group of chemical markers. Core-flooding experiments have shown significant additional crude oil recoveries are achievable with thermophilic microorganisms at elevated temperatures similar to those found in oil reservoirs. In addition, the biochemical treatment of crude oils has technological applications in downstream processing of crude oils such as in upgrading of low grade oils and the production of hydrocarbon based detergents.

  16. effect of crude oil extracts on early stages of african catfish

    African Journals Online (AJOL)

    Admin

    Nigerian Bonny light crude oil and Exxon Mobil Oso off-shore condensate during a ... of Oso condensate extract when larval integument was damaged. It is ... Spills of oil condensate from Oso Exxon Mobil Oil rig readily enter the .... compounds are extracted from oil films in natural .... Resources and Fishing Rome, 9-13 Dec.

  17. Effect of crude oil and palm bunch ash on maize growth

    Institute of Scientific and Technical Information of China (English)

    Emmanue Ogboma Dania; Temitayo Fayehun; Osemhengbe Ruth Akhabue

    2016-01-01

    Objective:To investigate the effect of different crude oil fractions (whole crude and water soluble fraction) at 2% contamination (98% distilled water) and the effect of 2 g of palm bunch ash (PBA) on the phytotoxicity of crude oil fraction on growth parameters such as percentage of seedling emergence, plant height, number of leaves, length of root, length of radical and leaf area in maize (Zea mays). Methods: A total of 180 bags containing 500 g of loamy soil each were used for this study, of which 30 bags containing loamy soil each served as control, 60 bags of soil were added each 2% crude oil fraction and 60 bags of soil were added each 2% crude oil fraction and 2 gPBA each, while 30 bags of soil contained each 2 g ofPBA only. The maize grown on the soil was harvested after 7, 14 and 21 days of seedling emergence and assessed for growth parameters. Results: The growth parameters (plant height, length of root, length of radicle, number of leaves, and leaf area) in maize were significantly reduced in the crude oil fraction treatment (P≤0.05). The treatment containingPBA was found to have significant improvement compared to the crude oil fraction contaminated treatment. Conclusions: The study has revealed the deleterious effect of crude oil at 2% on maize and its effect was ameliorated usingPBA.

  18. Hedging strategy for crude oil trading and the factors influencing hedging effectiveness

    International Nuclear Information System (INIS)

    Yun, Won-Cheol; Jae Kim, Hyun

    2010-01-01

    This study analyzes the hedging effectiveness of different hedge type and period by Korean oil traders. Both crude oil price and exchange rate risks are considered. Theoretical models are formulated to estimate the hedge ratios by separate and complex hedge types. The hedging period covers 1-12 months. This study also performs some statistical works to investigate the relationship between the hedging effectiveness and the crude oil price sensitivity to exchange rate. In addition, the relationship between the hedging effectiveness and the volatilities of crude oil price and exchange rate is analyzed. (author)

  19. Toxicological evaluation of a lake ecosystem contaminated with crude oil

    International Nuclear Information System (INIS)

    Twigg, D.; Ramey, B.

    1995-01-01

    Winona Lake on the Daniel Boone National Forest in Powell County, Kentucky, was used from the mid 1950's to 1987 as a water source for water-injection oil drilling and as a brine disposal site. The lake was contaminated with excessive amounts of crude oil. A multi phase investigation was conducted, including chemical analysis of water and sediment, water toxicity tests using a cladoceran, Ceriodaphnia dubia, sediment toxicity tests using an amphipod, Hyalella azteca, and a faunal survey of the communities of the lake and stream both above and below the lake. The sediment was laden with petroleum hydrocarbons (4.1 parts per thousand), while the water showed no contamination. The C dubia test results showed no significant water toxicity. The contaminated sediment adjacent to the dam produced 75% mortality in H. azteca. The faunal survey indicated little or no impact on the upstream and downstream communities but the lake community was highly impacted, especially the benthos. Pollution tolerant Chaoborus sp. were the only organisms collected from sediment samples dredged from the lake. Contamination was limited to the sediment within the lake but the impact on the entire lake community was severe

  20. Bioremediation of soil contaminated crude oil by Agaricomycetes.

    Science.gov (United States)

    Mohammadi-Sichani, M Maryam; Assadi, M Mazaheri; Farazmand, A; Kianirad, M; Ahadi, A M; Ghahderijani, H Hadian

    2017-01-01

    One of the most important environmental problems is the decontamination of petroleum hydrocarbons polluted soil, particularly in the oil-rich country. Bioremediation is the most effective way to remove these pollutants in the soil. Spent mushroom compost has great ability to decompose lignin-like pollution. The purpose of this study was the bioremediation of soil contaminated with crude oil by an Agaricomycetes . Soil sample amended with spent mushroom compost into 3%, 5% and 10% (w/w) with or without fertilizer. Ecotoxicity germination test was conducted with Lipidium sativa . The amplified fragment (18 s rDNA) sequence of this mushroom confirmed that the strain belonged to Pleurotus ostreatus species with complete homology (100% identity). All tests experiment sets were effective at supporting the degradation of petroleum hydrocarbons contaminated soil after three months. Petroleum contaminated soil amended with Spent mushroom compost 10% and fertilizer removed 64.7% of total petroleum hydrocarbons compared control. The germination index (%) in ecotoxicity tests ranged from 60.4 to 93.8%. This showed that the petroleum hydrocarbons contaminated soil amended with 10% Spent mushroom compost had higher bioremediation ability and reduced soil toxicity in less than three months.

  1. Effect of Bombay high crude oil and its water-soluble fraction on growth and metabolism of diatom Thalassiosira sp.

    Digital Repository Service at National Institute of Oceanography (India)

    Parab, S.R.; Pandit, R.A.; Kadam, A.N.; Indap, M.M.

    Effect of Bombay high crude oil (BHC) and its water-soluble fraction (WSF) on growth and metabolism of the phytoplankton, Thalassiosira sp. was assessed. The study revealed the signs of acute toxicity at higher concentrations of crude oil (0...

  2. Workshop Papers: Directions and Marketing of Synthetic Crude Oil and Heavy Oil

    International Nuclear Information System (INIS)

    1997-01-01

    This workshop was organized by the National Centre for Upgrading Technology in an effort to bring together experts from the various sectors of the petroleum industry to outline their views of the directions that the synthetic crude oil market will pursue over the next decade and into the 21. century. The motivation for the Workshop came from the many announcements during 1996 and 1997 by several Canadian oil companies about plans to initiate or expand their heavy oil and synthetic crude production. During the same period, at least one US refiner also announced plans to revamp an existing refinery to allow it to process Canadian heavy oil and synthetic crude. The workshop was organized to review these plans and to discuss such questions as (1) Would the selected technologies be the familiar carbon rejection or hydrogen addition methods, or would there be radical advanced technologies? (2) Would the products be fully or partially upgraded? (3) How would they be processed in the refinery? (4) Would there be a market? This collection of papers or viewgraphs comprise all the formal presentations given at the workshop. The final section also contains the edited notes recorded during the question and answer periods. refs., tabs., figs

  3. Acute toxicities of crude oils and oil-dispersant mixtures to Red sea fishes and invertebrates

    Energy Technology Data Exchange (ETDEWEB)

    Eisler, R.

    1975-11-01

    Crude oil from fields in the Persian Gulf and in the Sinai plus a chemical oil dispersant were tested, using static bioassay procedures, for toxicity to adults or juveniles of ten marine species: Heteroxenia fuscescens, a soft coral; Nerita forskali and Drupa granulata, gastropod molluscs; Mytilus variabilis, a mussel; Acanthopleura haddoni, a chiton (mollusc); Echinometra mathaei, sea urchin; Calcinus latens, a hermit crab; Palaemon pacificus, a shrimp; Parupeneus barberinus, goatfish; and Siganus rivulatus, rabbitfish. Concentrations fatal to 50 percent of individual test species in 168 hours, LC-50 (168 h), ranged from 0.74 to more than 30.0 ml/liter for Persian Gulf crude, from 14.5 to more than 30.0 ml/liter for Sinai crude, and from 0.006 to 0.064 ml/liter for the dispersant. In general, fishes and crustaceans were the most sensitive groups assayed and molluscs the most resistant. LC-50 (168 h) values for oil-dispersant mixtures of 10 parts oil to 1 part dispersant (v/v) for selected species ranged from 0.047 to 0.152 ml/liter which appears to reflect the biocidal properties of the dispersant. Some individuals that survived immersion in high concentrations of the test compounds for 168 h were adversely affected during treatment and afterwards.

  4. Crude oil import policy of Turkey: Historical analysis of determinants and implications since 1968

    Energy Technology Data Exchange (ETDEWEB)

    Ediger, Volkan S., E-mail: volkanediger@gmail.co [Izmir University of Economics, Sakarya Caddesi, No. 156, 35330 Izmir (Turkey); Berk, Istemi [Izmir University of Economics, Sakarya Caddesi, No. 156, 35330 Izmir (Turkey)

    2011-04-15

    Turkey is one of the most energy import dependent countries in the world, suffering deeply from the economic and strategic burdens of oil importation. Our purpose is to determine the factors behind the crude oil import policy of Turkey and to measure their contribution to a well-organized import strategy. We implemented a principle component analysis to construct an Oil Import Vulnerability Index (OIVI) based on four factors, which are crude oil import dependency of primary energy consumption, crude oil import bill as a share of Gross Domestic Product (GDP), non-diversification of import sources, and share of oil in total energy import. The contribution of these factors to the OIVI is found to be approximately equal. While an overall deterioration in the OIVI has been observed during periods of increasing oil prices, better diversification of oil import sources has lead to significant improvements. We suggest Turkish policy-makers implement sound policies, emphasizing diversification of crude oil import sources and reduction of the share of crude oil in primary energy imports to increase energy supply security. This study has also demonstrated that it is possible to construct an index representing crude oil vulnerability caused by import dependency. - Research highlights: {yields}We examine the factors lying behind the crude oil import policy of Turkey. {yields} We measure the contribution of each factor to a well-organized import strategy. {yields} We constrtuct an Oil Import Vulnerability Index using principle component analysis. {yields} We suggest that four factors affect oil import policies with almost equal weights. {yields} Source diversification is found to be the core issue in oil import policies.

  5. Crude oil import policy of Turkey: Historical analysis of determinants and implications since 1968

    International Nuclear Information System (INIS)

    Ediger, Volkan S.; Berk, Istemi

    2011-01-01

    Turkey is one of the most energy import dependent countries in the world, suffering deeply from the economic and strategic burdens of oil importation. Our purpose is to determine the factors behind the crude oil import policy of Turkey and to measure their contribution to a well-organized import strategy. We implemented a principle component analysis to construct an Oil Import Vulnerability Index (OIVI) based on four factors, which are crude oil import dependency of primary energy consumption, crude oil import bill as a share of Gross Domestic Product (GDP), non-diversification of import sources, and share of oil in total energy import. The contribution of these factors to the OIVI is found to be approximately equal. While an overall deterioration in the OIVI has been observed during periods of increasing oil prices, better diversification of oil import sources has lead to significant improvements. We suggest Turkish policy-makers implement sound policies, emphasizing diversification of crude oil import sources and reduction of the share of crude oil in primary energy imports to increase energy supply security. This study has also demonstrated that it is possible to construct an index representing crude oil vulnerability caused by import dependency. - Research highlights: →We examine the factors lying behind the crude oil import policy of Turkey. → We measure the contribution of each factor to a well-organized import strategy. → We constrtuct an Oil Import Vulnerability Index using principle component analysis. → We suggest that four factors affect oil import policies with almost equal weights. → Source diversification is found to be the core issue in oil import policies.

  6. Sulfur transfer in the distillate fractions of Arabian crude oils under gamma-irradiation

    International Nuclear Information System (INIS)

    Basfar, Ahmed A.; Soliman, Yasser S.; Alkhuraiji, Turki S.

    2017-01-01

    Desulfurization of light distillation fractions including gasoline, kerosene and diesel obtained from the four Arabian crude oils (heavy, medium, light and extra light) upon γ-rays irradiation to different doses was investigated. In addition, yields vol%, FTIR analysis, kinematic viscosity and density of all distillation fractions of irradiated crude oils were evaluated. Limited radiation-induced desulfurization of those fractions was observed up to an irradiation dose of 200 kGy. FTIR analysis of those fractions indicates the absence of oxidized sulfur compounds, represented by S=O of sulfone group, indicating that γ-irradiation of the Arabian crude oils at normal conditions does not induce an oxidative desulfurization in those distillation fractions. Radiation-induced sulfur transfer decreases by 28.56% and increases in total sulfur by 16.8% in Arabian extra light oil and Arabian medium crude oil respectively. - Highlights: • Limited desulfurization in the light distillate fraction of Arabian crude oils using γ-rays was observed. • FTIR analysis confirms limited unchanged in density, viscosity and yields of Arabian crude oils. • In absence of oxidizer, radiation-induced sulfur transfer was observed in gasoline and diesel fractions of Arabian crude oils. • Radiation-induced oxidative desulfuration of the light distillate fractions depends on its characteristics.

  7. Eastern Canadian crude oil supply and its implications for regional energy security

    International Nuclear Information System (INIS)

    Hughes, Larry

    2010-01-01

    Canada has been blessed with immense energy resources; however, their distribution is not uniform. One such example is crude oil, which is found primarily in western Canada. Eastern Canada, consisting of the six eastern-most provinces (Newfoundland and Labrador, New Brunswick, Nova Scotia, Ontario, Prince Edward Island, and Quebec), produce limited quantities of crude oil, most of which is exported to the United States. Ideally, western Canadian crude oil would meet the demands of eastern Canada; however, the North American Free Trade Agreement (NAFTA) and the absence of oil pipelines means that eastern Canada increasingly relies on supplies of crude oil from a small number of oil exporting countries, many with declining production. This paper examines crude oil production, supply, and its refining in eastern Canada. It shows that crude production in the region has reached its peak and that increasing global competition for crude oil will affect energy security in eastern Canada, either through price increases or supply shortages, or both. (author)

  8. Analysis of metals in asphaltenes of KU-46 by PIXE analysis

    International Nuclear Information System (INIS)

    Navidad G, P.; Pina L, L.I.; Lopez M, J.; Ramirez T, J.J.; Aspiazu F, J.A.; Romero G, E.T.

    2002-01-01

    The content of metals of the asphaltenes obtained from the KU-46 mexican crude with n-heptane was evaluated. The found metals in higher concentration are transition metals as well as the vanadium, nickel, copper and zinc. Moreover the sulfur in high concentrations was quantified. The metallic content of the asphaltenes revealed that the crude contains a lower quantity of metals unlike the vacuum residue previously analysed. (Author)

  9. Microbial enhanced heavy crude oil recovery through biodegradation using bacterial isolates from an Omani oil field.

    Science.gov (United States)

    Al-Sayegh, Abdullah; Al-Wahaibi, Yahya; Al-Bahry, Saif; Elshafie, Abdulkadir; Al-Bemani, Ali; Joshi, Sanket

    2015-09-16

    Biodegradation is a cheap and environmentally friendly process that could breakdown and utilizes heavy crude oil (HCO) resources. Numerous bacteria are able to grow using hydrocarbons as a carbon source; however, bacteria that are able to grow using HCO hydrocarbons are limited. In this study, HCO degrading bacteria were isolated from an Omani heavy crude oil field. They were then identified and assessed for their biodegradation and biotransformation abilities under aerobic and anaerobic conditions. Bacteria were grown in five different minimum salts media. The isolates were identified by MALDI biotyper and 16S rRNA sequencing. The nucleotide sequences were submitted to GenBank (NCBI) database. The bacteria were identified as Bacillus subtilis and B. licheniformis. To assess microbial growth and biodegradation of HCO by well-assay on agar plates, samples were collected at different intervals. The HCO biodegradation and biotransformation were determined using GC-FID, which showed direct correlation of microbial growth with an increased biotransformation of light hydrocarbons (C12 and C14). Among the isolates, B. licheniformis AS5 was the most efficient isolate in biodegradation and biotransformation of the HCO. Therefore, isolate AS5 was used for heavy crude oil recovery experiments, in core flooding experiments using Berea core plugs, where an additional 16 % of oil initially in place was recovered. This is the first report from Oman for bacteria isolated from an oil field that were able to degrade and transform HCO to lighter components, illustrating the potential use in HCO recovery. The data suggested that biodegradation and biotransformation processes may lead to additional oil recovery from heavy oil fields, if bacteria are grown in suitable medium under optimum growth conditions.

  10. Lifting the US crude oil export ban: A numerical partial equilibrium analysis

    International Nuclear Information System (INIS)

    Langer, Lissy; Huppmann, Daniel; Holz, Franziska

    2016-01-01

    The upheaval in global crude oil markets and the boom in shale oil production in North America brought scrutiny on the US export ban for crude oil from 1975. The ban was eventually lifted in early 2016. This paper examines the shifts of global trade flows and strategic refinery investments in a spatial, game-theoretic partial equilibrium model. We consider detailed oil supply chain infrastructure with multiple crude oil types, distinct oil products, as well as specific refinery configurations and modes of transport. Prices, quantities produced and consumed, as well as infrastructure and refining capacity investments are endogenous to the model. We compare two scenarios: an insulated US crude oil market, and a counter-factual with lifted export restrictions. We find a significant expansion of US sweet crude exports with the lift of the export ban. In the US refinery sector, more (imported) heavy sour crude is transformed. Countries importing US sweet crude gain from higher product output, while avoiding costly refinery investments. Producers of heavy sour crude (e.g. the Middle East) are incentivised to climb up the value chain to defend their market share and maintain their dominant position. - Highlights: • We study the impacts of lifting the US crude ban on global oil flows and investments. • We find massive expansion of US sweet crude oil exports. • We analyze the resulting welfare effects for US producers, refiners and consumers. • We indicate the changes on global trade patterns. • We conclude that lifting the ban is the right policy for the US and the global economy.

  11. Effects of silica-based nanostructures with raspberry-like morphology and surfactant on the interfacial behavior of light, medium, and heavy crude oils at oil-aqueous interfaces

    Science.gov (United States)

    Bai, Lingyun; Li, Chunyan; Korte, Caroline; Huibers, Britta M. J.; Pales, Ashley R.; Liang, Wei-zhen; Ladner, David; Daigle, Hugh; Darnault, Christophe J. G.

    2017-11-01

    were ranked as follows: (1) Prudhoe Bay > (2) Lloydminster > and (3) West Texas Intermediate. The level of asphaltenes and resins in these crude oil samples reflected these rankings. A decrease in the IFT also indicated the potential of the SiO2 NPs to decrease capillary pressure and induce the movement and recovery of oil in original water-wet reservoirs. Conversely, an increase in IFT indicated the potential of SiO2 NPs to increase capillary pressure and oil recovery in reservoirs subject to wettability reversal under water-wet conditions. Raspberry-like morphology particles were discovered in 5 wt% brine-surfactant-SiO2 nanofluid-oil systems. The development of raspberry-like particles material with high surface area, high salt stability, and high capability of interfaces alteration and therefore wettability changes offers a wide range of applications in the fields of applied nanoscience, environmental engineering, and petroleum engineering.

  12. A new approach to model strain change of gelled waxy crude oil under constant stress

    DEFF Research Database (Denmark)

    Hou, Lei; Song, Changyu; Yan, Wei

    2014-01-01

    Deformation of gelled waxy crude oil with loaded stress is worthy of research for the flow assurance of pipelining system. A dispersion parameter was introduced to characterize the disruption degree of wax crystal structure in crude oil with shear action. Based on fractional calculus theory, a rh...... monotonously with test temperature. Multiple creep curves of gelled waxy crude oil at a certain temperature can be described with this model......., a rheological model incorporating dispersion parameter was proposed to describe creep of gelled waxy crude. A discrete and numerical algorithm was proposed to solve the model. Combining with the experimental results of five kinds of waxy crude oil, the model parameters were regressed and found to change...

  13. The Effect of the Operating Conditions on the Apparent Viscosity of Crude Palm Oil During Oil Clarification

    OpenAIRE

    Sulaiman Al-Zuhair, Mirghani I. Ahmed and Yousif A. Abakr

    2012-01-01

    This paper discusses the apparent viscosity of crude palm oil, using rotary viscometer, under different boundary conditions. It was experimentally shown that the apparent viscosity of palm oil drops with increasing of the shear rate and the temperature.  However, the effect of temperature on the viscosity tends to fade at temperatures beyond 80 oC.  A correlation between the apparent viscosity of crude palm oil and the operating conditions was developed. This correlation can be used...

  14. Experiment on the Influence Factors of Steam Distillation Rate of Crude Oil in Porous Media

    Directory of Open Access Journals (Sweden)

    Tian Guoqing

    2017-01-01

    Full Text Available To explore the influence of complexity of reservoir properties in porous media and the diversity of operating conditions on the steam distillation rate of crude oil in the process of heavy oil exploitation with steam injection, steam distillation simulation devices are used to study steam distillation rate of crude oil in porous media. Then steam distillation ratio is obtained under the condition of different core permeability, oil saturation, steam temperatures, system pressure, steam injection rates and steam distillation rates with different viscosities of crude oil. The results show that the steam distillation rate of crude oil in porous media depends mainly on the nature of the crude oil itself, for temperature and pressure are the key factors compared with the pore structure, the initial oil saturation and steam injection rate. The experimental results help estimate the amount of crude oil and the required steam in the reservoir in the steam drive process, aiming to facilitate the optimization design and operation of steam drive.

  15. Price and income elasticities of crude oil import demand in South Africa: A cointegration analysis

    Energy Technology Data Exchange (ETDEWEB)

    Ziramba, Emmanuel, E-mail: zirame@unisa.ac.z [Department of Economics, University of South Africa, P.O Box 392, Unisa 0003 (South Africa)

    2010-12-15

    This paper examines the demand for imported crude oil in South Africa as a function of real income and the price of crude oil over the period 1980-2006. We carried out the Johansen co integration multivariate analysis to determine the long-run income and price elasticities. A unique long-run cointegration relationship exists between crude oil imports and the explanatory variables. The short-run dynamics are estimated by specifying a general error correction model. The estimated long-run price and income elasticities of -0.147 and 0.429 suggest that import demand for crude oil is price and income inelastic. There is also evidence of unidirectional long-run causality running from real GDP to crude oil imports. - Research Highlights: {yields}The paper examines the demand for imported crude oil in South Africa over the period 1980-2006. {yields} The estimated long-run price and income elasticities are -0.147 and 0.429, respectively. {yields} There is evidence of unidirectional long-run causality running from real GDP to crude oil imports.

  16. Price and income elasticities of crude oil import demand in South Africa: A cointegration analysis

    International Nuclear Information System (INIS)

    Ziramba, Emmanuel

    2010-01-01

    This paper examines the demand for imported crude oil in South Africa as a function of real income and the price of crude oil over the period 1980-2006. We carried out the Johansen co integration multivariate analysis to determine the long-run income and price elasticities. A unique long-run cointegration relationship exists between crude oil imports and the explanatory variables. The short-run dynamics are estimated by specifying a general error correction model. The estimated long-run price and income elasticities of -0.147 and 0.429 suggest that import demand for crude oil is price and income inelastic. There is also evidence of unidirectional long-run causality running from real GDP to crude oil imports. - Research Highlights: →The paper examines the demand for imported crude oil in South Africa over the period 1980-2006. → The estimated long-run price and income elasticities are -0.147 and 0.429, respectively. → There is evidence of unidirectional long-run causality running from real GDP to crude oil imports.

  17. Volatility spillovers in China’s crude oil, corn and fuel ethanol markets

    International Nuclear Information System (INIS)

    Haixia, Wu; Shiping, Li

    2013-01-01

    Price volatility spillovers among China’s crude oil, corn and fuel ethanol markets are analyzed based on weekly price data from September 5, 2003 to August 31, 2012, employing the univariate EGARCH model and the BEKK-MVGARCH model, respectively. The empirical results indicate a higher interaction among crude oil, corn and fuel ethanol markets after September, 2008. In the overall sample period, the results simultaneously provide strong evidence that there exist unidirectional spillover effects from the crude oil market to the corn and fuel ethanol markets, and double-directional spillovers between the corn market and the fuel ethanol market. However, the spillover effects from the corn and fuel ethanol markets to the crude oil market are not significant. -- Highlights: •Employing univariate EGARCH model and BEKK-MVGARCH model, respectively. Unidirectional spillover effects from crude oil market to corn and fuel ethanol markets. •Double-directional spillovers between corn market and fuel ethanol market. •The spillover effects from corn and fuel ethanol markets to crude oil market are not significant. •The empirical results indicate a higher interaction among crude oil, corn and fuel ethanol markets after September, 2008

  18. Leadership Strategies for Maintaining Profitability in a Volatile Crude Oil Market

    Science.gov (United States)

    Braimoh, Lucky Anderson

    Volatile crude oil prices significantly affect the profitability of crude oil firms. The purpose of this single case study was to explore strategies some crude oil and gas business leaders used to remain profitable during periods of crude oil price volatility. The target population comprised 8 crude oil and gas business leaders located in Calgary, Canada, whose company remained profitable despite crude oil price volatility. The transformational leadership theory formed the conceptual framework for the study. Data were collected through the use of semistructured face-to-face interviews, company reports, and field notes. Data analysis involved a modified Van Kamm method, which included descriptive coding, a sequential review of the interview transcripts, and member checking. Based on methodological triangulation and thematic analysis, 5 themes emerged from the study, including communication and engagement; motivation and empowerment; measurement, monitoring, and control; self-awareness and humility; and efficiency and optimization. The implications for social change include the potential for crude oil and gas companies in Calgary, Canada to manage production costs, ensure earnings and profitability, and thus improve the socioeconomic well-being of Calgary indigenes through improved employment opportunities.

  19. Characteristics of gas-liquid dynamics in operation of oil fields producing non-Newtonian crude oils

    Energy Technology Data Exchange (ETDEWEB)

    Mirzadzhanzade, A Kh; Khasaev, A M; Gurbanov, R S; Akhmedov, Z M

    1968-08-01

    Experimental studies have shown that crude oils from Azerbaidzhan, Uzbekistan, Tataria, Kazakhstan and other areas have anomalous properties under reservoir conditions. Such crude oils are non-Newtonian and (1) obey Darcys Law at low velocities; (2) obey an exponential law at higher velocities; and (3) obey a modified Darcys Law at most velocities. A discussion is given of (1) flow of non-Newtonian crude oils together with gas or water; (2) flow of non-Newtonian crude oils in well tubing; (3) behavior of wells producing non-Newtonian crude oils; and (4) pumping of non-Newtonian oils in wells. Experiments have shown that a visco-plastic liquid does not fill pump inlets completely; as the diameter of the pump inlet decreases so also does the degree of liquid filling. A statistical analysis of production data from 160 fields with Newtonian oil and 129 fields with non- Newtonian oil has shown that much higher production is obtained from fields with Newtonian crude oils.

  20. Energetic dependency on the oil reserve- resources of crude oil in the world

    Directory of Open Access Journals (Sweden)

    Marína Sidorová

    2006-10-01

    Full Text Available Crude oil belongs to the most important energy resources nowadays., However its reserves are the smallest in comparison with other energy resources as coal, gas or uranium. The world oil consumption continuously increases and within 20-year period there could be about one third. So, the consumption of combustibles will probably increase and the reserves will decrease. Promising are new resources or a better utilization of primary sources. It´s a question of a short time when world scientists should think about this indisputably worldwide problem and would provide an equivalent substitution with an available ecological solution.

  1. Geochemistry of crude oils, seepage oils and source rocks from Belize and Guatemala

    DEFF Research Database (Denmark)

    Petersen, H.I.; Holland, B.; Nytoft, H.P.

    2012-01-01

    This study reviews the stratigraphy and the poorly documented petroleum geology of the Belize-Guatemala area in northern Central America. Guatemala is divided by the east-west trending La Libertad arch into the North and South Petén Basins. The arch is the westward continuation of the Maya...... generated from source rocks with similar thermal maturities. The crude oils were generated from marine carbonate source rocks and could be divided into three groups: Group 1 oils come from the North Petén Basin (Guatemala) and the western part of the Corozal Basin (Belize), and have a typical carbonate...

  2. Use of compound-specific stable carbon isotope ratio measurements of asphaltene-bound polycyclic aromatic hydrocarbons (PAHs) as a novel aid to source apportionment of environmental PAHs

    Energy Technology Data Exchange (ETDEWEB)

    C. Sun; C. Snape; M. Cooper; W. Ivwurie [University of Nottingham, Nottingham (United Kingdom). Nottingham Energy & Fuel Centre

    2005-07-01

    In this study, the PAHs from hydropyrolysis of asphaltenes from different primary sources (e.g. crude oil, low and high temperature coal tars) were characterized by their molecular distributions and {sup 13}C/{sup 12}C isotope ratios. It was found that for all oil samples, the molecular and isotopic profiles for their asphaltene-derived PAHs are both similar to those observed for their contained free aromatics, with {sup 13}C-isotopic values varying from -25 to -27{per_thousand} for the Nigerian and -27 to -30{per_thousand} for North Sea oil samples. For low and high temperature coal tar samples, however, similar molecular but different isotopic profiles were observed for their asphaltene-bound PAHs. The free aromatics are significantly isotopically lighter (by nearly -3{per_thousand}) than their asphaltene-derived counterparts having isotopic values typically between -22 and -23{per_thousand} for all coal tar samples examined, and this leads to a larger isotopic difference of up to 7{per_thousand} between the two sources of PAHs than that already observed between their free aromatics (3{per_thousand}). Applying these results to samples previously examined in an area where unambiguous source apportionment could not be conducted for the PAHs due to likely biodegradation, it was found that the bound PAHs released from the asphaltenes recovered from the soil samples in this area are extremely similar to low temperature tar as the source, in terms of their both molecular (highly alkylated) and isotopic profiles. The free PAHs are much less alkyl substituted confirming that the aromatics detected in this area have been subjected to intensiveenvironmental degradation with alkylated aromatic constituents being preferentially removed from their initial matrix.

  3. The Parameters Controlling the Burning Efficiency of In-Situ Burning of Crude Oil on Water

    DEFF Research Database (Denmark)

    van Gelderen, Laurens; Jomaas, Grunde

    2017-01-01

    Parameters that control the burning efficiency of in-situ burning of crude oil on water were identified by studying the influence of the initial slick thickness, vaporization order, oil slick diameter, weathering state of the oil, heat losses to the water layer and heat flux to the fuel surface...... on the burning efficiency for light and heavy crude oils. These parameters were studied in several small scale and intermediate scale experimental setups. The results showed that the heat losses to the water layer increase with increasing burning time because the components in a crude oil evaporate from volatile...... to non-volatile. Due to the relatively low heat feedback (reradiation and convection, in kW/m2) to the fuel surface of small scale pool fires, as compared to large scale pool fires, these heat losses were shown to limit the burning efficiency in small scale experiments. By subjecting small scale crude...

  4. Sulfur transfer in the distillate fractions of Arabian crude oils under gamma-irradiation

    Science.gov (United States)

    Basfar, Ahmed A.; Soliman, Yasser S.; Alkhuraiji, Turki S.

    2017-05-01

    Desulfurization of light distillation fractions including gasoline, kerosene and diesel obtained from the four Arabian crude oils (heavy, medium, light and extra light) upon γ-rays irradiation to different doses was investigated. In addition, yields vol%, FTIR analysis, kinematic viscosity and density of all distillation fractions of irradiated crude oils were evaluated. Limited radiation-induced desulfurization of those fractions was observed up to an irradiation dose of 200 kGy. FTIR analysis of those fractions indicates the absence of oxidized sulfur compounds, represented by S=O of sulfone group, indicating that γ-irradiation of the Arabian crude oils at normal conditions does not induce an oxidative desulfurization in those distillation fractions. Radiation-induced sulfur transfer decreases by 28.56% and increases in total sulfur by 16.8% in Arabian extra light oil and Arabian medium crude oil respectively.

  5. The Effect of the Operating Conditions on the Apparent Viscosity of Crude Palm Oil During Oil Clarification

    Directory of Open Access Journals (Sweden)

    Sulaiman Al-Zuhair, Mirghani I. Ahmed and Yousif A. Abakr

    2012-10-01

    Full Text Available This paper discusses the apparent viscosity of crude palm oil, using rotary viscometer, under different boundary conditions. It was experimentally shown that the apparent viscosity of palm oil drops with increasing of the shear rate and the temperature.  However, the effect of temperature on the viscosity tends to fade at temperatures beyond 80 oC.  A correlation between the apparent viscosity of crude palm oil and the operating conditions was developed. This correlation can be used in design of crude palm oil settlers and in determining the optimum operating conditions.Key Words:  Crude palm oil, apparent viscosity, shear rate, modelling, separation 

  6. Corrosion of API 5L B and X52 in crude oil/water/gas mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Perdomo, J J; Gonzalez, J J; Viloria, A; De Veer, H; De Abreu, Y

    2000-02-01

    Laboratory and field tests were conducted to evaluate the corrosion behavior of API 5L grade B and X52 steels using Furrial's crude oil in the presence of water and gas containing carbon dioxide (CO{sub 2}) and hydrogen sulfide (H{sub 2}S). The results suggest that the corrosiveness of this crude oil/water/gas mixture is not detrimental to either steel. However, pitting corrosion was observed. The low general corrosion rates measured were attributed to the natural inhibiting properties of the crude oil.

  7. Multivariate EMD-Based Modeling and Forecasting of Crude Oil Price

    Directory of Open Access Journals (Sweden)

    Kaijian He

    2016-04-01

    Full Text Available Recent empirical studies reveal evidence of the co-existence of heterogeneous data characteristics distinguishable by time scale in the movement crude oil prices. In this paper we propose a new multivariate Empirical Mode Decomposition (EMD-based model to take advantage of these heterogeneous characteristics of the price movement and model them in the crude oil markets. Empirical studies in benchmark crude oil markets confirm that more diverse heterogeneous data characteristics can be revealed and modeled in the projected time delayed domain. The proposed model demonstrates the superior performance compared to the benchmark models.

  8. Plasma corticosterone and thyroxine concentrations during chronic ingestion of crude oil in mallard ducks (Anas platyrhynchos)

    Science.gov (United States)

    Rattner, B.A.; Eastin, W.C.

    1981-01-01

    1. Blood samples were collected from mallard ducks after 6, 12, and 18 weeks of dietary exposure to mash containing 0.015%, 0.150%, and 1.500% crude oil.2. Plasma corticosterone concentrations in ducks fed mash containing 0.150% or 1.500% Alaskan Prudhoe Bay crude oil were uniformly depressed when compared to values in untreated control birds.3. Plasma thyroxine concentration was not altered in ducks chronically exposed to crude oil.4. The observed alteration in corticosterone concentration could reduce tolerance to temperature and dietary fluctuations in the environment.

  9. Corrosion of API 5L B and X52 in crude oil/water/gas mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Perdomo, J.J.; Gonzalez, J.J.; Viloria, A.; De Veer, H.; De Abreu, Y.

    2000-02-01

    Laboratory and field tests were conducted to evaluate the corrosion behavior of API 5L grade B and X52 steels using Furrial's crude oil in the presence of water and gas containing carbon dioxide (CO{sub 2}) and hydrogen sulfide (H{sub 2}S). The results suggest that the corrosiveness of this crude oil/water/gas mixture is not detrimental to either steel. However, pitting corrosion was observed. The low general corrosion rates measured were attributed to the natural inhibiting properties of the crude oil.

  10. Price Relationships in the Petroleum Market: An Analysis of Crude Oil and Refined Product Prices

    International Nuclear Information System (INIS)

    Asche, Frank; Gjoelberg, Ole; Voelker, Teresa

    2001-08-01

    In this paper the relationships between crude oil and refined product prices are investigated in a multivariate framework. This allows us to test several (partly competing) assumptions of earlier studies. In particular, we find that the crude oil price is weakly exogenous and that the spread is constant in some but not all relationships. Moreover, the multivariate analysis shows that the link between crude oil prices and several refined product prices implies market integration for these refined products. This is an example of supply driven market integration and producers will change the output mix in response to price changes. (author)

  11. Price relationships in the petroleum market. An analysis of crude oil and refined product prices

    International Nuclear Information System (INIS)

    Asche, Frank; Gjoelberg, Ole; Volker, Teresa

    2003-01-01

    In this paper the relationships between crude oil and refined product prices are investigated in a multivariate framework. This allows us to test several (partly competing) assumptions of earlier studies. In particular, we find that the crude oil price is weakly exogenous and that the spread is constant in some but not all relationships. Moreover, the multivariate analysis shows that the link between crude oil prices and several refined product prices implies market integration for these refined products. This is an example of supply driven market integration and producers will change the output mix in response to price changes

  12. Price relationships in the petroleum market: an analysis of crude oil and refined product prices

    International Nuclear Information System (INIS)

    Asche, F.; Gjoelberg, O.; Voelker, T.

    2003-01-01

    In this paper the relationships between crude oil and refined product prices are investigated in a multivariate framework. This allows us to test several (partly competing) assumptions of earlier studies. In particular, we find that the crude oil price is weakly exogenous and that the spread is constant in some but not all relationships. Moreover, the multivariate analysis shows that the link between crude oil prices and several refined product prices implies market integration for these refined products. This is an example of supply driven market integration and producers will change the output mix in response to price changes. (author)

  13. Literature Survey of Crude Oil Properties Relevant to Handling and Fire Safety in Transport.

    Energy Technology Data Exchange (ETDEWEB)

    Lord, David [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Luketa, Anay [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Wocken, Chad [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Schlasner, Steve [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Aulich, Ted [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Allen, Ray [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Rudeen, David Keith [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-03-01

    Several fiery rail accidents in 2013-2015 in the U.S. and Canada carrying crude oil produced from the Bakken region of North Dakota have raised questions at many levels on the safety of transporting this, and other types of crude oil, by rail. Sandia National Laboratories was commissioned by the U.S. Department of Energy to investigate the material properties of crude oils, and in particular the so-called "tight oils" like Bakken that comprise the majority of crude oil rail shipments in the U.S. at the current time. The current report is a literature survey of public sources of information on crude oil properties that have some bearing on the likelihood or severity of combustion events that may occur around spills associated with rail transport. The report also contains background information including a review of the notional "tight oil" field operating environment, as well a basic description of crude oils and potential combustion events in rail transport. This page intentionally blank

  14. Artificial Intelligence for Inferential Control of Crude Oil Stripping Process

    Directory of Open Access Journals (Sweden)

    Mehdi Ebnali

    2018-01-01

    Full Text Available Stripper columns are used for sweetening crude oil, and they must hold product hydrogen sulfide content as near the set points as possible in the faces of upsets. Since product    quality cannot be measured easily and economically online, the control of product quality is often achieved by maintaining a suitable tray temperature near its set point. Tray temperature control method, however, is not a proper option for a multi-component stripping column because the tray temperature does not correspond exactly to the product composition. To overcome this problem, secondary measurements can be used to infer the product quality and adjust the values of the manipulated variables. In this paper, we have used a novel inferential control approach base on adaptive network fuzzy inference system (ANFIS for stripping process. ANFIS with different learning algorithms is used for modeling the process and building a composition estimator to estimate the composition of the bottom product. The developed estimator is tested, and the results show that the predictions made by ANFIS structure are in good agreement with the results of simulation by ASPEN HYSYS process simulation package. In addition, inferential control by the implementation of ANFIS-based online composition estimator in a cascade control scheme is superior to traditional tray temperature control method based on less integral time absolute error and low duty consumption in reboiler.

  15. Modelling demand for crude oil products in Spain

    International Nuclear Information System (INIS)

    Pedregal, D.J.; Dejuan, O.; Gomez, N.; Tobarra, M.A.

    2009-01-01

    This paper develops an econometric model for the five most important crude oil products demand in Spain. The aim is the estimation of a range of elasticities of such demands that would serve as the basis for an applied general equilibrium model used for forecasting energy demand in a broader framework. The main distinctive features of the system with respect to previous literature are (1) it takes advantage of monthly information coming from very different information sources and (2) multivariate unobserved components (UC) models are implemented allowing for a separate analysis of long- and short-run relations. UC models decompose time series into a number of unobserved though economic meaningful components mainly trend, seasonal and irregular. A module is added to such structure to take into account the influence of exogenous variables necessary to compute price, cross and income elasticities. Since all models implemented are multivariate in nature, the demand components are allowed to interact among them through the system noises (similar to a seemingly unrelated equations model). The results show unambiguously that the main factor driving demand is real income with prices having little impact on energy consumption. (author)

  16. Crude palm oil as fuel extender for diesel engines

    International Nuclear Information System (INIS)

    Mohamed M El-Awad; Fuad Abas; Mak Kian Sin

    2000-01-01

    In this work an investigation has been conducted into the use of Crude Palm Oil (CPO) as an extender fuel for diesel engines. Mixtures of CPO with normal diesel fuel (with a percentage of 25%, 50% and 75% CPO by volume) were used to fuel a stationary diesel engine and the engine performance variables, i.e., power output, fuel consumption, and exhaust-gas emission, were compared to those of normal diesel fuel. The results obtained, for a fixed throttle opening and variable speed, indicate that at high engine speeds, the engine performance with CP0/diesel mixtures with up to 50% CPO is comparable to that of diesel fuel. However, the results of the 75% CPO mixture showed a higher temperature and emission of CO and NO compared to the diesel fuel. At low engine speeds, the engine performance with CPO mixtures gave higher power output and lower emission of NO compared to that with diesel fuel, but showed higher specific fuel consumption and higher emission of CO. Based on these results, the study recommends that CPO can be used to extend diesel fuel in a mixture of up to 50% CPO by volume for an unmodified engine. (Author)

  17. Modelling demand for crude oil products in Spain

    Energy Technology Data Exchange (ETDEWEB)

    Pedregal, D.J. [Escuela Tecnica Superior de Ingenieros Industriales and Instituto de Matematica Aplicada a la Ciencia y la Ingenieria (IMACI), Universidad de Castilla-La Mancha (UCLM), Avenida Camilo Jose Cela s/n, 13071 Ciudad Real (Spain); Dejuan, O.; Gomez, N.; Tobarra, M.A. [Facultad de Ciencias Economicas y Empresariales, Universidad de Castilla-La Mancha (UCLM) (Spain)

    2009-11-15

    This paper develops an econometric model for the five most important crude oil products demand in Spain. The aim is the estimation of a range of elasticities of such demands that would serve as the basis for an applied general equilibrium model used for forecasting energy demand in a broader framework. The main distinctive features of the system with respect to previous literature are (1) it takes advantage of monthly information coming from very different information sources and (2) multivariate unobserved components (UC) models are implemented allowing for a separate analysis of long- and short-run relations. UC models decompose time series into a number of unobserved though economic meaningful components mainly trend, seasonal and irregular. A module is added to such structure to take into account the influence of exogenous variables necessary to compute price, cross and income elasticities. Since all models implemented are multivariate in nature, the demand components are allowed to interact among them through the system noises (similar to a seemingly unrelated equations model). The results show unambiguously that the main factor driving demand is real income with prices having little impact on energy consumption. (author)

  18. Review of Alberta Crown Crude Oil Marketing Program

    International Nuclear Information System (INIS)

    Crandall, G. R.; Kromm, R. B.

    1999-01-01

    This report contains an independent evaluation of the operations of the private marketing agents that are currently marketing the Alberta Crown's share of royalty crude oil. The evaluation includes a review of pricing performance, working relationship, current issues and the overall performance of the marketing arrangements during the fiscal years of 1997 and 1998. Overall, the outsourcing of sales of Crown production to agents is judged to be successful. For example, it has been noted that agents are becoming more aggressive in maintaining and increasing their margins. On the other hand, the increased level of aggressiveness in marketing, while tending to maximize Crown revenues, is also creating a potential conflict on how margins should be shared between the Crown and its agents. Also, there has been evidence of some management issues between the agents and the Crown concerning the extent to which the Crown should share in any increased value which the agent generates by increased third party marketing activities. These differences need to be addressed in order to maintain the strong performance of the marketing program. The consultants also recommend additional guidelines on risk management issues that more clearly define the Crown's risk tolerance. 2 tabs., 4 figs

  19. Exergy analysis of a distillation tower for crude oil fractionation

    International Nuclear Information System (INIS)

    Rivero, R.

    1990-01-01

    In this paper the application of the exergy method to a crude oil atmospheric distillation tower is presented. The fundamentals and procedures are presented as well as the main parameters used to describe the thermodynamic performance of the system, such as Exergy Losses, Effectiveness and Improvement Potential. A parametric analysis of the influence on the effectiveness of the tower is then performed as a function of the number of trays, the amount of stripping steam, the use of reboilers and the operation pressure. The results obtained are discussed. As expected, the effectiveness of the tower increases with the overall number of trays in the tower and in the stripping columns for a constant operation pressure and a constant amount of stripping steam but there is a limit at which the pressure drop across the trays and the stripping steam requirements make the effectiveness decrease. The use of reboilers in the stripping columns adjacent to the main tower allows an increase in the effectiveness basically due to a greater heat integration. Finally, the increase in the operation pressure of the tower produces an increase of the effectiveness but also an increase in the stripping steam requirements

  20. Kinetic modeling and half life study on bioremediation of crude oil dispersed by Corexit 9500

    International Nuclear Information System (INIS)

    Zahed, Mohammad Ali; Aziz, Hamidi Abdul; Isa, Mohamed Hasnain; Mohajeri, Leila; Mohajeri, Soraya; Kutty, Shamsul Rahman Mohamed

    2011-01-01

    Hydrocarbon pollution in marine ecosystems occurs mainly by accidental oil spills, deliberate discharge of ballast waters from oil tankers and bilge waste discharges; causing site pollution and serious adverse effects on aquatic environments as well as human health. A large number of petroleum hydrocarbons are biodegradable, thus bioremediation has become an important method for the restoration of oil polluted areas. In this research, a series of natural attenuation, crude oil (CO) and dispersed crude oil (DCO) bioremediation experiments of artificially crude oil contaminated seawater was carried out. Bacterial consortiums were identified as Acinetobacter, Alcaligenes, Bacillus, Pseudomonas and Vibrio. First order kinetics described the biodegradation of crude oil. Under abiotic conditions, oil removal was 19.9% while a maximum of 31.8% total petroleum hydrocarbons (TPH) removal was obtained in natural attenuation experiment. All DCO bioreactors demonstrated higher and faster removal than CO bioreactors. Half life times were 28, 32, 38 and 58 days for DCO and 31, 40, 50 and 75 days for CO with oil concentrations of 100, 500, 1000 and 2000 mg/L, respectively. The effectiveness of Corexit 9500 dispersant was monitored in the 45 day study; the results indicated that it improved the crude oil biodegradation rate.

  1. Short-term outlook for Canadian crude oil to 2006 : an energy market assessment

    International Nuclear Information System (INIS)

    2005-09-01

    The National Energy Board monitors the supply of all energy commodities in Canada along with the demand for Canadian energy commodities in domestic and export markets. This report is intended to expand the effectiveness of the Board's monitoring activities by providing an assessment of the current state of the petroleum industry and the potential for growth. It provides an 18-month outlook on international and domestic crude oil prices; drilling and exploration activity; supply projections for Canadian crude oil and petroleum products; Canada's crude oil trade balance and markets for Canadian crude; existing export pipeline networks and project expansion plans; and, the Canadian petroleum products industry and the impact of higher prices. It also identifies the major issues and challenges associated with the development of Canada's crude oil. The 2 major oil producing areas in Canada are the Western Canada Sedimentary Basin (WCSB) including the oil sands, and offshore eastern Canada. While conventional production in the WCSB is declining, development focus has shifted to Alberta's oil sands as well as Hibernia, Terra Nova and White Rose, the 3 major oil fields offshore Newfoundland and Labrador. High energy prices have resulted in record profits for the Canadian oil and gas industry, and has stimulated billions of dollars in investment, with Alberta's oil sands being the main beneficiary. The 19 refineries in Canada have been operating at about 90 per cent capacity for the last several years due to strong demand for transportation fuels. 10 tabs., 37 figs., 2 appendices

  2. Life cycle water demand coefficients for crude oil production from five North American locations.

    Science.gov (United States)

    Ali, Babkir; Kumar, Amit

    2017-10-15

    The production of liquid fuels from crude oil requires water. There has been limited focus on the assessment of life cycle water demand footprints for crude oil production and refining. The overall aim of this paper is address this gap. The objective of this research is to develop water demand coefficients over the life cycle of fuels produced from crude oil pathways. Five crude oil fields were selected in the three North American countries to reflect the impact of different spatial locations and technologies on water demand. These include the Alaska North Slope, California's Kern County heavy oil, and Mars in the U.S.; Maya in Mexico; and Bow River heavy oil in Alberta, Canada. A boundary for an assessment of the life cycle water footprint was set to cover the unit operations related to exploration, drilling, extraction, and refining. The recovery technology used to extract crude oil is one of the key determining factors for water demand. The amount of produced water that is re-injected to recover the oil is essential in determining the amount of fresh water that will be required. During the complete life cycle of one barrel of conventional crude oil, 1.71-8.25 barrels of fresh water are consumed and 2.4-9.51 barrels of fresh water are withdrawn. The lowest coefficients are for Bow River heavy oil and the highest coefficients are for Maya crude oil. Of all the unit operations, exploration and drilling require the least fresh water (less than 0.015 barrel of water per barrel of oil produced). A sensitivity analysis was conducted and uncertainty in the estimates was determined. Copyright © 2017 Elsevier Ltd. All rights reserved.

  3. Investigating the influence of pressure and temperature on malaysian crude oil density and viscosity for improved recovery

    International Nuclear Information System (INIS)

    Zahoor, M.K.; Derahman, M.N.

    2012-01-01

    Malaysia has great potential as a crude oil or fossil fuel producing country. To increase oil production, behavior of Malaysian Crude Oil has been analyzed with reference to temperature and pressure variations. The effect of these parameters on crude oil density and viscosity has been observed, to select the methodology to be adopted for increases recovery by implementing enhanced oil recovery (EOR) project. Based on this study it has been decided to further explore the feasibility of increasing reservoir pressure. (author)

  4. Process technology for refining crude soybean oil – a product from ...

    African Journals Online (AJOL)

    Process technology for refining crude soybean oil – a product from soycake meal production in Ghana. ... yield of 83.3 per cent was recorded. Results of quality assessment of the final laboratory refined oil compared favourably with Ghana Standards Board's specification for edible soybean oil. Ghana Journal of Science Vol.

  5. A Microfluidic Method to Assess Emulsion Stability in Crude-Oil/Water Separators

    NARCIS (Netherlands)

    Krebs, T.; Schroën, C.G.P.H.; Boom, R.M.

    2011-01-01

    The control of emulsion stability and droplet size is of crucial importance for oil production, especially for the processes of crude/oil water separation and cleanup of produced water. To recover pure oil and water, coalescence between droplets needs to take place, the extent of which will depend

  6. Multivariate Time Series Forecasting of Crude Palm Oil Price Using Machine Learning Techniques

    Science.gov (United States)

    Kanchymalay, Kasturi; Salim, N.; Sukprasert, Anupong; Krishnan, Ramesh; Raba'ah Hashim, Ummi

    2017-08-01

    The aim of this paper was to study the correlation between crude palm oil (CPO) price, selected vegetable oil prices (such as soybean oil, coconut oil, and olive oil, rapeseed oil and sunflower oil), crude oil and the monthly exchange rate. Comparative analysis was then performed on CPO price forecasting results using the machine learning techniques. Monthly CPO prices, selected vegetable oil prices, crude oil prices and monthly exchange rate data from January 1987 to February 2017 were utilized. Preliminary analysis showed a positive and high correlation between the CPO price and soy bean oil price and also between CPO price and crude oil price. Experiments were conducted using multi-layer perception, support vector regression and Holt Winter exponential smoothing techniques. The results were assessed by using criteria of root mean square error (RMSE), means absolute error (MAE), means absolute percentage error (MAPE) and Direction of accuracy (DA). Among these three techniques, support vector regression(SVR) with Sequential minimal optimization (SMO) algorithm showed relatively better results compared to multi-layer perceptron and Holt Winters exponential smoothing method.

  7. Changes in cardiac activity, oxygen uptake and perfusion indices in Carcinus maenas (L. ) exposed to crude oil and dispersant

    Energy Technology Data Exchange (ETDEWEB)

    Depledge, M.H.

    1984-01-01

    Cardiac activity and oxygen consumption increased when C. maenas were exposed to a 20% solution of the water-soluble fraction of Fortes crude oil, a 10% solution of the dispersant BP1100WD or a combination of both. Normal feeding behaviour was disrupted. Perfusion indices (Q/VO2) decreased as locomotor activity increased following exposure to crude oil. However, exposure to dispersant or dispersant + crude oil resulted in elevation of perfusion index despite crabs becoming active. All test animals survived for at least 6 weeks following exposure to the pollutants. The acute, sublethal effects of dispersant and dispersant + crude oil were more severe than the effects of crude oil alone.

  8. Import demand of crude oil and economic growth. Evidence from India

    International Nuclear Information System (INIS)

    Ghosh, Sajal

    2009-01-01

    This study establishes a long-run equilibrium relationship among quantity of crude oil import, income and price of the imported crude in India for the time span 1970-1971 to 2005-2006 using autoregressive distributed lag (ARDL) bounds testing approach of cointegration. Empirical results show that the long-term income elasticity of imported crude in India is 1.97 and there exists a unidirectional long-run causality running from economic growth to crude oil import. So reduction of crude oil import will not affect the future economic growth in India in the long-run. India should take various energy efficiency and demand side management measures in transport sector along with other measures like expanding and strengthening indigenous resource-base, substituting imported fuels by domestic fuels and de-controlling the price of petroleum products to reduce its import dependence. (author)

  9. Efisiensi Perusahaan Crude Palm Oil (CPO di Indonesia

    Directory of Open Access Journals (Sweden)

    Amzul Rifin

    2017-07-01

    Full Text Available Crude Palm Oil (CPO is an important Indonesian agricultural product as a raw material for cooking oil and an export commodity. In order to achieve maximum profit, the companies producing the CPO need to produce it efficiently. This study used the data from the 2013 Annual Manufacturing Survey conducted by the Statistics Indonesia. In this survey, there were 547 factories producing CPO. The efficiency measurement utilized the Data Envelopment Analysis (DEA approach using value of production as the output and two inputs, namely the number of workers and raw material value. The results showed that there are 17 factories out of 547 factories which are efficient indicated by the efficiency value of one. Factories owned by the private national companies have the highest average of efficiency followed by the foreign and government-owned companies. In regards to location, factories located in Kalimantan Island have higher average efficiency compared to those located in Sumatra Island and other islands. Meanwhile, factories with local market orientation have a higher efficiency compared to those with export market orientation.Keywords: CPO, efficiency, data envelopment analysis (DEAABSTRAKCrude Palm Oil (CPO merupakan salah satu andalan produk pertanian Indonesia baik sebagai bahan baku minyak goreng maupun komoditas ekspor. Untuk mencapai keuntungan maksimum, maka perusahaan penghasil CPO perlu berproduksi secara efisien. Penelitian ini menggunakan data-data perusahaan sawit yang berasal dari Survei Perusahaan Industri Manufaktur 2013 yang dilakukan oleh Badan Pusat Statistik. Pada survei ini terdapat 547 pabrik yang merupakan penghasil CPO. Pengukuran efisiensi menggunakan analisis Data Envelopment Analysis (DEA dengan satu output, yaitu nilai produksi serta dua input, yaitu jumlah pekerja dan nilai bahan baku. Hasil yang diperoleh menunjukkan dari 547 perusahaan terdapat 17 perusahaan yang efisien yang ditunjukkan oleh nilai efisiensi sebesar satu

  10. Salt marsh recovery from a crude oil spill: Vegetation, oil weathering, and response

    International Nuclear Information System (INIS)

    Hoff, R.Z.; Shigenaka, G.; Henry, C.B. Jr.

    1993-01-01

    When a spill of Prudhoe Bay crude oil covered a fringing Salicornia virginica marsh in Fidalgo Bay, Washington (northern Puget Sound) in February 1991, response personnel used several low-impact techniques to remove oil from the marsh, and minimized access by cleanup workers. Following the response, a monitoring program was established to track marsh recovery, and to document the effectiveness of the response techniques used and their impacts on the marsh. Through monthly sampling over a 16-month period, vegetative growth was monitored and chemical degradation of remaining oil was tracked. Sampling was conducted along transects located in four areas affected in different ways by the spill, including an oiled, trampled section; an oiled, vacuumed section; and an oiled, washed, and vacuumed section. In addition, a control transect was established in an unoiled adjacent marsh. The study included both biological and chemical components. Biological measurements included percent cover of live vegetation (sampled monthly) and below-ground plant biomass (sampled at the beginning of each growing season in April 1991 and April 1992). Sediment samples included surface sediment (monthly) and core samples collected at the beginning and end of the growing seasons. Sediment samples were analyzed using gas chromatography/mass spectroscopy, and indicator compounds were tracked to determine rates of oil degradation. Results from 16 months of post-spill monitoring show that foot trampling was most detrimental to marsh plants, while washing with vacuuming removed the most oil and minimized adverse impacts to vegetation. Dense clay substrate helped prevent oil from penetrating the sediment, thus minimizing acute toxic effects from oil exposure to marsh plant rootstock. By the second growing season post-spill, Salicornia and other marsh plants were growing in all areas except one heavily oiled patch

  11. Hydrothermal Liquefaction Biocrude Compositions Compared to Petroleum Crude and Shale Oil

    Energy Technology Data Exchange (ETDEWEB)

    Jarvis, Jacqueline M.; Billing, Justin M.; Hallen, Richard T.; Schmidt, Andrew J.; Schaub, Tanner M.

    2017-02-17

    We provide a direct and detailed comparison of the chemical composition of petroleum crude oil (from the Gulf of Mexico), shale oil, and three biocrudes (i.e., clean pine, microalgae Chlorella sp., and sewage sludge feedstocks) generated by hydrothermal liquefaction (HTL). Ultrahigh resolution Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) reveals that HTL biocrudes are compositionally more similar to shale oil than petroleum crude oil and that only a few heteroatom classes (e.g., N1, N2, N1O1, and O1) are common to organic sediment- and biomass-derived oils. All HTL biocrudes contain a diverse range of oxygen-containing compounds when compared to either petroleum crude or shale oil. Overall, petroleum crude and shale oil are compositionally dissimilar to HTL oils, and >85% of the elemental compositions identified within the positive-ion electrospray (ESI) mass spectra of the HTL biocrudes were not present in either the petroleum crude or shale oil (>43% for negative-ion ESI). Direct comparison of the heteroatom classes that are common to both organic sedimentand biomass-derived oils shows that HTL biocrudes generally contain species with both smaller core structures and a lower degree of alkylation relative to either the petroleum crude or the shale oil. Three-dimensional plots of carbon number versus molecular double bond equivalents (with observed abundance as the third dimension) for abundant molecular classes reveal the specific relationship of the composition of HTL biocrudes to petroleum and shale oils to inform the possible incorporation of these oils into refinery operations as a partial amendment to conventional petroleum feeds.

  12. Superoleophillic electrospun polystrene/exofoliated graphite fibre for selective removal of crude oil from water

    Science.gov (United States)

    Alayande, S. Oluwagbemiga; Dare, Enock O.; Olorundare, F. O. Grace; Nkosi, D.; Msagati, Titus A. M.; Mamba, B. B.

    2016-04-01

    During oil spills, the aquatic environment is greatly endangered because oil floats on water making the penetration of sunlight difficult therefore primary productivity is compromised, birds and aquatic organisms are totally eliminated within a short period. It is therefore essential to remove the oil from the water bodies after the spillage. This work reports on the fabrication of oil loving electrospun polystyrene-exofoliated graphite fibre with hydrophobic and oleophillic surface properties. The fibre was applied for the selective adsorption of crude oil from simulated crude oil spillage on water. The maximum oil adsorption capacity of the EPS/EG was 1.15 kg/g in 20 min while the lowest oil adsorption capacity was 0.81 kg/g in 10 min. Cheap oil adsorbent was developed with superoleophillic and superhydrophobic properties.

  13. The impacts of the export ban on Alaskan crude oil trade

    International Nuclear Information System (INIS)

    Farah, P.G.; Bausell, C.W.; Vogelsang, A.

    1990-01-01

    The authors investigated the petroleum markets impacts of lifting the ban on Alaska North Slope (ANS) crude oil exports. This paper reports on some aspects of this investigation. The economic analysis relied heavily on the modeling of the ANS crude trade conducted on behalf of GAO by the Energy Information Administration (EIA) using the Transportation and Refining of International Petroleum model (TRIP). In contrast to previous studies, this one suggests that transportation costs may not be the only major factor in the realignment of ANS crude trade in response to lifting the ban. The differences in the yields of ANS crude and various crudes used by refiners in Pacific Rim countries on the one hand, and the product demand slates of the US West Coast and the potential buyers of ANS crude in Pacific Rim may also figure prominently in determining the reallocation of ANS crude if exports are permitted

  14. Fuzzy logic controller for crude oil levels at Escravos Tank Farm ...

    African Journals Online (AJOL)

    Fuzzy logic controller (FLC) for crude oil flow rates and tank levels was designed for monitoring flow and tank level management at Escravos Tank Farm in Nigeria. The fuzzy control system incorporated essence of expert knowledge required to handle the tasks. Proportional Integral Derivative (PID) control of crude flow ...

  15. Draft Genome Sequence of Sphingopyxis sp. Strain MWB1, a Crude-Oil-Degrading Marine Bacterium

    Science.gov (United States)

    Kim, Jonghyun; Kim, Soo Jung; Kim, Seon Hee; Kim, Seung Il; Moon, Yoon-Jung; Park, Sung-Joon

    2014-01-01

    Sphingopyxis sp. strain MWB1, which is capable of degrading crude oil, diesel, and kerosene, was isolated from crude oil–contaminated seashore in Tae-an, South Korea. Here, we report the draft genome sequence of this strain, which comprises 3,118,428 bp with a G+C content of 62.85 mol%. PMID:25477411

  16. Spectral signatures of fluorescence and light absorption to identify crude oils found in the marine environment

    Science.gov (United States)

    Baszanowska, E.; Otremba, Z.

    2014-08-01

    To protect the natural marine ecosystem, it is necessary to continuously enhance knowledge of environmental contamination, including oil pollution. Therefore, to properly track the qualitative and quantitative changes in the natural components of seawater, a description of the essential spectral features describing petroleum products is necessary. This study characterises two optically-different types of crude oils (Petrobaltic and Romashkino) - substances belonging to multi-fluorophoric systems. To obtain the spectral features of crude oils, the excitation-emission spectroscopy technique was applied. The fluorescence and light absorption properties for various concentrations of oils at a stabilised temperature are described. Both excitation-emission spectra (EEMs) and absorption spectra of crude oils are discussed. Based on the EEM spectra, both excitation end emission peaks for the wavelengthindependent fluorescence maximum (Exmax/ Emmax) - characteristic points for each type of oil - were identified and compared with the literature data concerning typical marine chemical structures.

  17. A reexamination of the crude oil price-unemployment relationship in the United States

    International Nuclear Information System (INIS)

    Uri, N.D.; Boyd, R.

    1996-01-01

    This study begins by asking whether fluctuations in the price of crude oil have affected employment and the rate of unemployment in the US. After reviewing previous assessments of the issue, the existence of an empirical relationship between the rate of unemployment and crude oil price volatility is established using Granger causality. Subsequently, the nature of the relationship is estimated with the results suggesting that at least three full years are required before the measurable impact of a percentage change in the real price of crude oil on the change in unemployment is exhausted. Finally, the structural stability of the functional relationship between the change in unemployment and the volatility of the price of crude oil and the percentage change in gross national product is examined

  18. Vaporization order and burning efficiency of crude oils during in-situ burning on water

    DEFF Research Database (Denmark)

    van Gelderen, Laurens; Malmquist, Linus M.V.; Jomaas, Grunde

    2017-01-01

    furthermore showed that the vaporization was diffusion-limited. Analysis of the heat transfer balance for the crude oils indicated that the energy available for evaporation decreased over time due to increasing heat losses, which were caused by the volatility controlled vaporization order. Presumably, larger......In order to improve the understanding of the burning efficiency and its observed size dependency of in-situ burning of crude oil on water, the vaporization order of the components in crude oils was studied. The vaporization order of such multicomponent fuels was assessed by studying the surface...... these results. The crude oils did not show any steady state behavior, but instead had an increasing surface temperature and decreasing burning rate and flame height, indicating a volatility controlled vaporization order. An increasing concentration gradient from the medium to heavy fraction in the burn residues...

  19. Is there co-movement of agricultural commodities futures prices and crude oil?

    International Nuclear Information System (INIS)

    Natanelov, Valeri; Alam, Mohammad J.; McKenzie, Andrew M.; Van Huylenbroeck, Guido

    2011-01-01

    Even though significant attempts have appeared in literature, the current perception of co-movement of commodity prices appear inadequate and static. In particular we focus on price movements between crude oil futures and a series of agricultural commodities and gold futures. A comparative framework is applied to identify changes in relationships through time and various cointegration methodologies and causality tests are employed. Our results indicate that co-movement is a dynamic concept and that some economic and policy development may change the relationship between commodities. Furthermore we show that biofuel policy buffers the co-movement of crude oil and corn futures until the crude oil prices surpass a certain threshold. - Highlights: → We show that co-movement of commodity futures is a temporal concept. → A variation in parallel movement between 2 large periods occurs. → Biofuel policy buffers parallel movement of corn and crude oil futures

  20. Is there co-movement of agricultural commodities futures prices and crude oil?

    Energy Technology Data Exchange (ETDEWEB)

    Natanelov, Valeri, E-mail: valeri.natanelov@ugent.be [Department of Agricultural Economics, Ghent University, Coupure links 653, 9000 Ghent (Belgium); Alam, Mohammad J. [Department of Agricultural Economics, Ghent University, Coupure links 653, 9000 Ghent (Belgium); Department of Agribusiness and Marketing, Bangladesh Agricultural University (Bangladesh); McKenzie, Andrew M. [Department of Agricultural Economics and Agribusiness, University of Arkansas, AR (United States); Van Huylenbroeck, Guido [Department of Agricultural Economics, Ghent University, Coupure links 653, 9000 Ghent (Belgium)

    2011-09-15

    Even though significant attempts have appeared in literature, the current perception of co-movement of commodity prices appear inadequate and static. In particular we focus on price movements between crude oil futures and a series of agricultural commodities and gold futures. A comparative framework is applied to identify changes in relationships through time and various cointegration methodologies and causality tests are employed. Our results indicate that co-movement is a dynamic concept and that some economic and policy development may change the relationship between commodities. Furthermore we show that biofuel policy buffers the co-movement of crude oil and corn futures until the crude oil prices surpass a certain threshold. - Highlights: > We show that co-movement of commodity futures is a temporal concept. > A variation in parallel movement between 2 large periods occurs. > Biofuel policy buffers parallel movement of corn and crude oil futures

  1. Dose-Time Effect of Crude Oil and Hydro-test Effluent on Freshwater ...

    African Journals Online (AJOL)

    ) and a brackish water shrimp, Palaemonetes africanus. Test results indicated that the brackish water juvenile shrimps were more sensitive to the mixture of the hydro-test effluent and crude oil than the freshwater habitat. This could be ...

  2. Detection of simulated pitting corrosion and noises in crude oil storage tank by acoustic emission

    International Nuclear Information System (INIS)

    Shukri Mohd; Latif, N.A.; Azhar Mohd Sinin; Mohamad Daud; Abd Nasir Ibrahim

    2008-01-01

    The damage mechanisms associated with crude oil storage tanks can be complex and varied and include pitting corrosion due to presence of species such as sulphate reducing bacteria. Acoustic Emission (AE) could be used to characterise the pitting corrosion signal in crude oil storage tanks but it is extremely difficult to simulate the pitting corrosion in the laboratory using crude oil as electrolyte because crude oil is considered as non corrosive medium. In this study, induced current have been introduced onto a surface ASTM 516 steel as an electrical source to simulate the electrical noise produced during pitting corrosion process and AE sensor have been used to detect this current. It is found that AE system could detect AE signal release during current induction this current and is expected that if the exact simulation of the current magnitude produced during pitting corrosion process is made available, AE characterisation of pitting corrosion in such tank could be made possible. (Author)

  3. Effects of bonny light crude oil on anti-oxidative enzymes and total ...

    African Journals Online (AJOL)

    Effects of bonny light crude oil on anti-oxidative enzymes and total proteins in Wistar rats. Christian E Odo, Okwesili FC Nwodo, Parker E Joshua, Chibuike S Ubani, Okon E Etim, Okechukwu PC Ugwu ...

  4. Effect of crude oil pollution on maize growth and soil properties in ...

    African Journals Online (AJOL)

    Effect of crude oil pollution on maize growth and soil properties in Ihiagwa, Imo State, Nigeria. ... PROMOTING ACCESS TO AFRICAN RESEARCH. AFRICAN JOURNALS ONLINE ... International Journal of Agriculture and Rural Development.

  5. Forecasting short-run crude oil price using high- and low-inventory variables

    International Nuclear Information System (INIS)

    Ye, Michael; Zyren, John; Shore, Joanne

    2006-01-01

    Since inventories have a lower bound or a minimum operating level, economic literature suggests a nonlinear relationship between inventory level and commodity prices. This was found to be the case in the short-run crude oil market. In order to explore this inventory-price relationship, two nonlinear inventory variables are defined and derived from the monthly normal level and relative level of OECD crude oil inventories from post 1991 Gulf War to October 2003: one for the low inventory state and another for the high inventory state of the crude oil market. Incorporation of low- and high-inventory variables in a single equation model to forecast short-run WTI crude oil prices enhances the model fit and forecast ability

  6. Effect of Crude Oil Price on Agricultural Productivity in Nigeria (1981 ...

    African Journals Online (AJOL)

    SH

    Faculty of Agricultural Sciences, LAUTECH, Ogbomoso, Nigeria, 2013. Effect of Crude Oil ... foreign exchange earnings since early. 1970s. ..... has been an improvement in the devaluation of the currency in .... IMF papers, Vol. 27:637 – 677.

  7. The role of Canadian heavy crude oil in the North American market

    Energy Technology Data Exchange (ETDEWEB)

    Mink, F J; Antonia, H A

    1977-01-01

    Canadian reserves of heavy gravity crude oil are vast and the potential producibility from those reserves is expected to be surplus to Canadian requirements into the 1990s. This study focuses on the impact that market constraints may have on the future supply of heavy gravity crude oils from the W. Canadian basin. It observes that severe export restrictions will not only limit the orderly development of available reserves in the area but also will impair the prospects of additional enhanced recovery of conventional heavy crude reserves and restrict future experimental applications of oil sands recovery in the Cold Lake deposit of Alberta. Since it is expected that export restrictions for heavy gravity crude oil will be lifted in the future, the outlook for expanded development of indigenous reserves is promising.

  8. Nonlinear joint dynamics between prices of crude oil and refined products

    Science.gov (United States)

    Zhang, Tao; Ma, Guofeng; Liu, Guangsheng

    2015-02-01

    In this paper, we investigate the relationships between crude oil and refined product prices. We find that nonlinear correlations are stronger in the long-term than in the short-term. Crude oil and product prices are cointegrated and financial crisis in 2007-2008 caused a structural break of the cointegrating relationship. Moreover, different from the findings in most studies, we reveal that the relationships are almost symmetric based on a threshold error correction model. The so-called 'asymmetric relationships' are caused by some outliers and financial crisis. Most of the time, crude oil prices play the major role in the adjustment process of the long-term equilibrium. However, refined product prices dominated crude oil prices during the period of financial crisis. Important policy and risk management implications can be learned from the empirical findings.

  9. The impact of crude oil price volatility on agricultural employment in the United States

    International Nuclear Information System (INIS)

    Uri, N.D.

    1996-01-01

    This study addresses the question of whether fluctuations in the price of crude oil have affected agricultural employment in the United States. After reviewing previous assessments of the issue, the existence of an empirical relationship between agricultural employment and crude oil price volatility is established using cointegration tests. Subsequently, the nature of the relationship is estimated with the results suggesting that at least three full years are required before the measurable impacts of a percentage change in the real price of crude oil on the change in agricultural employment are exhausted. Finally, the structural stability of the functional relationship between the change in agricultural employment and the volatility of the price of crude oil, the percentage changes in expected net farm income, realized technological innovation, and the wage rate is examined. (author)

  10. Level shift two-components autoregressive conditional heteroscedasticity modelling for WTI crude oil market

    Science.gov (United States)

    Sin, Kuek Jia; Cheong, Chin Wen; Hooi, Tan Siow

    2017-04-01

    This study aims to investigate the crude oil volatility using a two components autoregressive conditional heteroscedasticity (ARCH) model with the inclusion of abrupt jump feature. The model is able to capture abrupt jumps, news impact, clustering volatility, long persistence volatility and heavy-tailed distributed error which are commonly observed in the crude oil time series. For the empirical study, we have selected the WTI crude oil index from year 2000 to 2016. The results found that by including the multiple-abrupt jumps in ARCH model, there are significant improvements of estimation evaluations as compared with the standard ARCH models. The outcomes of this study can provide useful information for risk management and portfolio analysis in the crude oil markets.

  11. Enhancing the Effectiveness of Carbon Dioxide Flooding by Managing Asphaltene Precipitation; FINAL

    International Nuclear Information System (INIS)

    Deo, Milind D.

    2002-01-01

    This project was undertaken to understand fundamental aspects of carbon dioxide (CO2) induced asphaltene precipitation. Oil and asphaltene samples from the Rangely field in Colorado were used for most of the project. The project consisted of pure component and high-pressure, thermodynamic experiments, thermodynamic modeling, kinetic experiments and modeling, targeted corefloods and compositional modeling

  12. Study of asphaltene precipitation by Calorimetry

    DEFF Research Database (Denmark)

    Verdier, Sylvain Charles Roland; Plantier, Frédéric; Bessières, David

    2007-01-01

    Can calorimetry bring new input to the Current understanding of asphaltene precipitation? In this work, two types of precipitation were studied by means of calorimetry: addition of n-heptane into asphaltene solutions and temperature/pressure variations on a recombined live oil. The first series...... of experiments showed that weak forces determine precipitation. Indeed, isothermal titration calorimetry could not detect any clear signal although this technique can detect low-energy transitions such as liquid-liquid equilibrium and rnicellization. The second series of tests proved that precipitation caused...... by T and P variations is exothermic for this system. Furthermore, the temperature-induced precipitation is accompanied by an increase in the apparent thermal expansivity. Therefore, it seems that these two phase transitions exhibit different calorimetric behaviours and they may not be as similar...

  13. Formulation of best-fit hydrophile/lipophile balance-dielectric permittivity demulsifiers for treatment of crude oil emulsions

    Directory of Open Access Journals (Sweden)

    C.M. Ojinnaka

    2016-12-01

    Full Text Available The commerce of crude oil depends heavily on its water and salt contents usually referred to as Basic Sediments and Water (BS&W, which is co-produced with the crude oil in the form of emulsion. The lower the BS&W, the higher the market value of the crude. The presence of water in crude oil causes corrosion, lowers capacity utilization of production and processing plant parts and pipelines, reduces oil recovery and increases the oil content of the effluent water. The stabilizing factors of crude oil emulsions vary from one oil field to the other and with time in the same well as co-produced water increases, or after a well treatment and Enhanced Oil Recovery Operations (EOR. Periodical assessment and possible change of demulsifiers employed is therefore necessary at certain stages of crude oil productions, but this is not encouraged due to lack of general formulation procedures and the rigorous nature of bottle test method that is currently being used for assessment and selection. In this paper, the factors that affect the stability of crude oil emulsions are presented. Efforts of researchers in formulating demulsifiers based on these factors and their screening methods were reviewed. The context sets the stage for further exploration of possible relationship(s between the physical parameters of the crude oil and the demulsifiers, and exploiting same in the formulation of new demulsifiers capable of resolving crude oil emulsions using chemicals with improved surface activity and crude extracts of indigenous plants.

  14. Influence of UVB radiation on the lethal and sublethal toxicity of dispersed crude oil to planktonic copepod nauplii.

    Science.gov (United States)

    Almeda, Rodrigo; Harvey, Tracy E; Connelly, Tara L; Baca, Sarah; Buskey, Edward J

    2016-06-01

    Toxic effects of petroleum to marine zooplankton have been generally investigated using dissolved petroleum hydrocarbons and in the absence of sunlight. In this study, we determined the influence of natural ultraviolet B (UVB) radiation on the lethal and sublethal toxicity of dispersed crude oil to naupliar stages of the planktonic copepods Acartia tonsa, Temora turbinata and Pseudodiaptomus pelagicus. Low concentrations of dispersed crude oil (1 μL L(-1)) caused a significant reduction in survival, growth and swimming activity of copepod nauplii after 48 h of exposure. UVB radiation increased toxicity of dispersed crude oil by 1.3-3.8 times, depending on the experiment and measured variables. Ingestion of crude oil droplets may increase photoenhanced toxicity of crude oil to copepod nauplii by enhancing photosensitization. Photoenhanced sublethal toxicity was significantly higher when T. turbinata nauplii were exposed to dispersant-treated oil than crude oil alone, suggesting that chemical dispersion of crude oil may promote photoenhanced toxicity to marine zooplankton. Our results demonstrate that acute exposure to concentrations of dispersed crude oil and dispersant (Corexit 9500) commonly found in the sea after oil spills are highly toxic to copepod nauplii and that natural levels of UVB radiation substantially increase the toxicity of crude oil to these planktonic organisms. Overall, this study emphasizes the importance of considering sunlight in petroleum toxicological studies and models to better estimate the impact of crude oil spills on marine zooplankton. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.

  15. An Approximation Solution to Refinery Crude Oil Scheduling Problem with Demand Uncertainty Using Joint Constrained Programming

    OpenAIRE

    Duan, Qianqian; Yang, Genke; Xu, Guanglin; Pan, Changchun

    2014-01-01

    This paper is devoted to develop an approximation method for scheduling refinery crude oil operations by taking into consideration the demand uncertainty. In the stochastic model the demand uncertainty is modeled as random variables which follow a joint multivariate distribution with a specific correlation structure. Compared to deterministic models in existing works, the stochastic model can be more practical for optimizing crude oil operations. Using joint chance constraints, the demand unc...

  16. Unbiasedness and time varying risk premia in the crude oil futures market

    International Nuclear Information System (INIS)

    Moosa, I.A.; Al-Loughani, N.E.

    1994-01-01

    This paper presents some empirical evidence on market efficiency and unbiasedness in the crude oil futures market and some related issues. On the basis of monthly observations on spot and futures prices of the West Texas Intermediate (WTI) crude oil, several tests are carried out on the relevant hypotheses. The evidence suggests that futures prices are neither unbiased nor efficient forecasters of spot prices. Furthermore, a GARCH-M(1,1) model reveals the existence of a time varying risk premium. (author)

  17. Biodegradation of crude oil by Pseudomonas aeruginosa in the presence of rhamnolipids*

    OpenAIRE

    Zhang, Guo-liang; Wu, Yue-ting; Qian, Xin-ping; Meng, Qin

    2005-01-01

    The potential biodegradation of crude oil was assessed based on the development of a fermentative process with a strain of Pseudomonas aeruginosa which produced 15.4 g/L rhamnolipids when cultured in a basal mineral medium using glycerol as a sole carbon source. However, neither cell growth nor rhamnolipid production was observed in the comparative culture system using crude oil as the sole carbon source instead. As rhamnolipid, an effective biosurfactant, has been reported to stimulate the b...

  18. The effect of crude oil on growth of the weed (Paspalum ...

    African Journals Online (AJOL)

    The use of grasses for phytoremediation of crude oil polluted soils especially in the tropics is a new area of study with a lot of potentials. The effect of different levels (0.00, 2.50, 5.00, 7.50, 10.00, 12.50 and 15.00%) of crude oil contamination on the growth of Paspalum scrobiculatum, a common weed in Nigeria was ...

  19. Does Climate Change Mitigation Activity Affect Crude Oil Prices? Evidence from Dynamic Panel Model

    OpenAIRE

    Dike, Jude C.

    2014-01-01

    This paper empirically investigates how climate change mitigation affects crude oil prices while using carbon intensity as the indicator for climate change mitigation. The relationship between crude oil prices and carbon intensity is estimated using an Arellano and Bond GMM dynamic panel model. This study undertakes a regional-level analysis because of the geographical similarities among the countries in a region. Regions considered for the study are Africa, Asia and Oceania, Central and Sout...

  20. Microbial Population Dynamics Associated with Crude-Oil Biodegradation in Diverse Soils

    OpenAIRE

    Hamamura, Natsuko; Olson, Sarah H.; Ward, David M.; Inskeep, William P.

    2006-01-01

    Soil bacterial population dynamics were examined in several crude-oil-contaminated soils to identify those organisms associated with alkane degradation and to assess patterns in microbial response across disparate soils. Seven soil types obtained from six geographically distinct areas of the United States (Arizona, Oregon, Indiana, Virginia, Oklahoma, and Montana) were used in controlled contamination experiments containing 2% (wt/wt) crude oil spiked with [1-14C]hexadecane. Microbial populat...

  1. Physical aspects of crude oil spills on northern terrain. Task Force on Northern Oil Development, Report No. 74-25

    Energy Technology Data Exchange (ETDEWEB)

    Mackay, D; Charles, M E; Phillips, C R

    1974-01-01

    The physical aspects of crude oil spills on the terrain of the Mackenzie Valley were investigated. The aqueous solubility of Norman Wells crude oil has been determined and it has been established that about half of the dissolved hydrocarbon is aromatic. The distribution of hydrocarbons between the oil and aqueous phases is in good agreement with predicted values. The permeability of the surface terrain to oil at Norman Wells was found to decrease very rapidly with depth below the surface. A simple, in-situ method for determination of the profile was developed. The implication of the results is that flow will occur more readily near the surface than near the basement. The spreading rates of two crude oils on water were studied on two lakes near Inuvik. Pembina crude oil showed only one spreading front, whereas Norman Wells crude oil showed a bulk front preceded by a surface-slick. Once the initial separation occurred, wind drove both fronts across the water at about 6 percent of the wind speed. The area of surface-active contamination was several times the area of the bulk oil film. The isothermal spreading of five crude oils on ice under gravity-viscous conditions was examined. The radius of the slick was found to increase linearly with the ratio (time/viscosity)/sup /sup 1///sub 5//. Surface roughness effects were negligible. An attempt has been made to predict the behavior of a 50,000 barrel oil spill in the taiga region of the Mackenzie Valley, under both summer and winter conditions. The areas affected and the amounts of hydrocarbon evaporated were predicted. These predictions are valuable in providing a scenario of an oil spill incident which will assist in assessing the environmental impact of oil spills in the Mackenzie Valley and in preparing for clean-up measures. Burning as a clean-up procedure considered in some detail. Other methods specifically designed for Arctic conditions will probably prove more satisfactory.

  2. Natural resource injury assessment of a crude oil spill

    International Nuclear Information System (INIS)

    Fischel, M.; Mancini, E.R.

    1995-01-01

    In January 1994, a 6.7 magnitude earthquake in southern California ruptured a pipeline releasing approximately 4,200 barrels of blended San Joaquin Valley crude oil. A smaller volume entered the Santa Clara River and flowed 25 km downstream to an emergency containment dam. Ruptured water mains and chlorinated discharges from a damaged sewage treatment plant also affected water quality in the river. Quantitative injury assessment studies were initiated within days of the spill and included water/sediment chemistry, benthic macroinvertebrate community analyses and aquatic toxicity tests. Water quality values for TPH, BTEX, and chlorine ranged from nondetectable to 78 mg/l (TPH), nondetectable to 5.4 microg/l (total BTEX constituents) and nondetectable to 600 microg/l (residual chlorine) within 72 hours of the spill. Ammonia concentrations ranged from nondetectable to 12.1 mg/l within 10 days of the spill. Hydrocarbon concentrations in sediments ranged from nondetectable to 3,900 mg/kg within 8 to 12 weeks post-spill. Both the density and diversity of benthic macroinvertebrates were reduced immediately after the spill but were not significantly different from reference areas four months later. River water collected from numerous locations within 72 hrs of the earthquake was transferred to the laboratory for static renewal acute toxicity tests using rainbow trout (Oncorhynchus mykiss) and threespine stickleback (Gasterosteus aculeatus). TPH concentrations in test containers ranged from nondetectable to 23 mg/l, BTEX constituents were nondetectable, and chlorine, measured at 600 microg/l in one sample, was titrated with sodium thiosulfate prior to testing. No acute toxicity was observed in either species

  3. Mild Hydroprocessing with Dispersed Catalyst of Highly Asphaltenic Pitch

    Science.gov (United States)

    Isquierdo, Fernanda

    Asphaltene are known to have diverse negative impacts on heavy oil extraction and hydroprocessing. This research then, explores the optimal conditions to convert asphaltenes into lighter material using mild conditions of pressure and temperature, and investigates changes in asphaltene structure during hydroprocessing. Feedstock and products were characterized by Simulated Distillation, Microdeasphalting, Sulfur content, X-ray diffraction, X-ray photoelectron spectroscopy, and Nuclear magnetic resonance spectroscopy. Solid catalysts were analyzed by Themogravimetric analysis, X-ray diffraction, and Dynamic light scattering. Based on the results obtained from X-ray diffraction and Nuclear magnetic resonance spectroscopy analysis a mechanism for the asphaltene hydroprocessing at mild conditions is proposed in which the alky peripheric portion from the original asphaltenes is partially removed during the reaction. The consequence of that process being an increase in the stacking of the aromatics sheets in the remaining asphaltenes. Also, this study investigates different for ultradispersed catalyst compositions, where CoWS, CoMoS, NiWS, FeWS, NiMo/NaHFeSi 2O6 and NaHFeSi2O6 showed a high asphaltene conversion as determined by asphaltene microdeasphalting, FeMoS and NaHFeSi 2O6 presented a high Vacuum Residue as determined by distillation (SIMDIST) analysis conversion, and in terms of sulfur removal CoMoS gave the higher conversion. In addition, all the catalyst tested showed a coke production lower than 1%. Finally, a kinetic study for the pitch hydroprocessing using CoMoS as catalysts gave a global activation energy of 97.3 kJ/mol.

  4. Combustion of drops of Mexican fuel oils with high asphaltenes content; Combustion de gotas de combustoleos mexicanos con alto contenido de asfaltenos

    Energy Technology Data Exchange (ETDEWEB)

    Garcia Rodriguez, Jose Francisco [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1998-09-01

    In this work the combustion of fuel drops with a content of 18% of asphaltenes has been studied . The results obtained for this fuel were compared with the ones obtained for another with a content of 12% asphaltenes. The drops were suspended in a platinum filament and burned in an spherical radiant furnace. The drop size varied between 600 and 800 microns. The fuel drops with 12% asphaltenes showed shorter combustion times, a smaller diameter increment of the smaller diameter during the combustion stages and also a shorter burning time of the carbonaceous residue than the fuel drops with a content of 18% asphaltenes. [Espanol] En el presente trabajo se ha estudiado la combustion de gotas de combustible con 18% de contenido de asfaltenos. Los resultados obtenidos para este combustible se compararon con los obtenidos para otro con 12% de contenido de asfaltenos. Las gotas fueron suspendidas en un filamento de platino y quemadas en un horno radiante esferico. El tamano de las gotas vario entre 600 y 800 micras. Las gotas de combustible con 12% de asfaltenos mostraron tiempos de combustion mas cortos, un incremento del diametro menor durante las etapas de combustion y un tiempo de quemado del residuo carbonoso tambien mas corto que las gotas del combustible con 18% de contenido de asfaltenos.

  5. Characterization of crude and purified pumpkin seed oil.

    Directory of Open Access Journals (Sweden)

    Tsaknis, John

    1997-10-01

    Full Text Available Oil from hulled pumpkin seeds (Cucurbita pepo and Cucurbita Maxima was extracted with hot petroleum ether, and then it was degummed, neutralized and bleached, consecutively Physical and chemical characteristics of crude and purified oils were determined. Density, refractive index, viscosity and peroxide value were not affected by purification, while decreases in acidity, colour, unsaponifiable, E1%1cm 232, and oxidative stability, and increases in smoke point and E1%1cm 270 were observed. Purification did not affect the fatty acid and sterol profiles. GLC analysis for the fatty acid composition of the seed oil showed that the predominant unsaturates were linoleic (42% and oleic (38%, while the major saturates were palmitic (12,7% and stearic (6%. Only α-tocopherol was detected at a level of 126 mg/kg, which reduced to 78 mg/kg after purification. The main sterols of pumpkin seed oil unsaponifiable were Δ7.22,25 -stigmastatrien-3β-ol, α-spinasterol, Δ7,25_stigmastadienol and Δ7-avenasterol, followed by stigmasterol, 24-methylcholest-7-enol and Δ7-stigmastenol, and also trace to minor amounts of cholesterol, brassicasterol, campesterol, sitostanol, Δ5-avenasterol, erythrodiol and uvaol were found.

    Aceite de semillas de calabaza descascarada (Cucurbita pepo YCucurbita maxima fue extraído con éter de petróleo caliente, y luego desgomado, neutralizado y decolorado consecutivamente. Las características físicas y químicas de aceites crudo y purificado fueron determinadas. La densidad, el índice de refracción, la viscosidad y el índice de peróxido no se afectaron por la purificación, mientras que se observó una disminución en la acidez, color, insaponificable, E1%1cm 232, y estabilidad oxidativa, y un aumento en el punto de humo y de E1%1cm270. La purificaci

  6. Forecasting Crude Oil Price Using EEMD and RVM with Adaptive PSO-Based Kernels

    Directory of Open Access Journals (Sweden)

    Taiyong Li

    2016-12-01

    Full Text Available Crude oil, as one of the most important energy sources in the world, plays a crucial role in global economic events. An accurate prediction for crude oil price is an interesting and challenging task for enterprises, governments, investors, and researchers. To cope with this issue, in this paper, we proposed a method integrating ensemble empirical mode decomposition (EEMD, adaptive particle swarm optimization (APSO, and relevance vector machine (RVM—namely, EEMD-APSO-RVM—to predict crude oil price based on the “decomposition and ensemble” framework. Specifically, the raw time series of crude oil price were firstly decomposed into several intrinsic mode functions (IMFs and one residue by EEMD. Then, RVM with combined kernels was applied to predict target value for the residue and each IMF individually. To improve the prediction performance of each component, an extended particle swarm optimization (PSO was utilized to simultaneously optimize the weights and parameters of single kernels for the combined kernel of RVM. Finally, simple addition was used to aggregate all the predicted results of components into an ensemble result as the final result. Extensive experiments were conducted on the crude oil spot price of the West Texas Intermediate (WTI to illustrate and evaluate the proposed method. The experimental results are superior to those by several state-of-the-art benchmark methods in terms of root mean squared error (RMSE, mean absolute percent error (MAPE, and directional statistic (Dstat, showing that the proposed EEMD-APSO-RVM is promising for forecasting crude oil price.

  7. Naphthenic acid characterization and distribution in crude oils; Caracterizacao e distribuicao de acidos naftenicos em petroleos

    Energy Technology Data Exchange (ETDEWEB)

    Guimaraes, Regina C.L.; Gomes, Alexandre de O. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

    2008-07-01

    Naphthenic acid corrosion was observed for the first time during the distillation process of some kind of crude oils in 1920. Recent reports about naphthenic acid corrosion have been found in China, India, Venezuela, Eastern Europe, Russia and the USA. In Brazil, heavy and acid crude oil processing is rising. Some brazilian crude oils have TAN around 3,0 mg KOH/g. The presence of relatively high levels of naphthenic acids in crude oils is a bane of petroleum refiners; and more recently, of producers as well, who have reported problems during production with calcium and sodium naphthenate . Essentially, these acids which are found to greater or lesser extent in virtually all crude oils are corrosive and tend to cause equipment failures, lead to high maintenance costs and may pose environmental disposal problems. In order to give these information to PETROBRAS, The Research and Development Center of PETROBRAS (CENPES) has been working in house and with brazilian universities developing analytical technicians to know better molecular structures and distribution of these acids compounds in crude oils. This work presents the actual methods and some results from these developments. (author)

  8. Forecasting crude oil price with an EMD-based neural network ensemble learning paradigm

    International Nuclear Information System (INIS)

    Yu, Lean; Wang, Shouyang; Lai, Kin Keung

    2008-01-01

    In this study, an empirical mode decomposition (EMD) based neural network ensemble learning paradigm is proposed for world crude oil spot price forecasting. For this purpose, the original crude oil spot price series were first decomposed into a finite, and often small, number of intrinsic mode functions (IMFs). Then a three-layer feed-forward neural network (FNN) model was used to model each of the extracted IMFs, so that the tendencies of these IMFs could be accurately predicted. Finally, the prediction results of all IMFs are combined with an adaptive linear neural network (ALNN), to formulate an ensemble output for the original crude oil price series. For verification and testing, two main crude oil price series, West Texas Intermediate (WTI) crude oil spot price and Brent crude oil spot price, are used to test the effectiveness of the proposed EMD-based neural network ensemble learning methodology. Empirical results obtained demonstrate attractiveness of the proposed EMD-based neural network ensemble learning paradigm. (author)

  9. Experimental Study on Characteristics of Oil Particle Distribution in Water-Gelled Crude Oil Two-Phase Flow System

    Directory of Open Access Journals (Sweden)

    Liu Xiaoyan

    2014-06-01

    Full Text Available The conventional gathering and transportation mode of heating the produced fluid of oil wells with hot water or steam may result in excessive energy consumption. In order to perform the unheated transportation, the idea of hydraulic suspension transport of the gelled crude oil is proposed based on the actual production of Daqing Oilfield, and the experimental system is established to test characteristics of oil particle distribution which have an important effect on the hydraulic suspension transportation. In the experiment, the image of gelled crude oil particle distribution was obtained in a horizontal pipe with inner diameter of 0.053 m, and then the law of particle distribution was investigated by the theoretical model. The results showed that the gelled crude oil hydraulic suspension transport could be achieved without any chemical reagent when the gelled crude oil was transformed into particles and dispersedly suspended in water. The results also showed that the gelled oil particles of 0–4 mm in size accounted for 92% or more of all particles, and the percentage of gelled crude oil particles of a size of 4 mm gradually increased with the increasing mixed flow rate.

  10. The influence of asphaltenes of the petroleum on the rheology of O/W (Oil/Water) emulsions; Influencia de asfaltenos do petroleo sobre a reologia de emulsoes O/A (Oleo/Agua)

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Ronaldo Goncalves dos; Mohamed, Rahoma Sadeg; Loh, Watson; Bannwart, Antonio Carlos [Universidade Estadual de Campinas (UNICAMP), Campinas, SP (Brazil)

    2004-07-01

    Heavy oils represent a large fraction of the Brazilian petroleum reserves and display a great potential for application as substitute to the conventional oils, provided a suitable technology for their transportation is available. The high viscosity of these heavy oils leads to high flow resistance and increase in the recovery and transportation costs. Methodologies employed to reduce these problems involve application of heat of addition of diluents or lighter oils, but are associated with high costs. Formation of low viscosity oil-in-water emulsions has been proposed as an alternative for the transportation of heavy oils, as investigated in this work. Preliminary results indicate significant viscosity decreases upon emulsification of heavy oils (viscosities greater than 1,000 cP) forming o/w emulsions with high oil content (between 50-65 vol. %), which display viscosities within 4-25 cP. Additionally, the effect of different surfactants, methodology of preparation and oil asphaltene content on the emulsion stability was also evaluated. These results confirm the potential of emulsification as a viable methodology for heavy oil transportation. (author)

  11. Finding the multipath propagation of multivariable crude oil prices using a wavelet-based network approach

    Science.gov (United States)

    Jia, Xiaoliang; An, Haizhong; Sun, Xiaoqi; Huang, Xuan; Gao, Xiangyun

    2016-04-01

    The globalization and regionalization of crude oil trade inevitably give rise to the difference of crude oil prices. The understanding of the pattern of the crude oil prices' mutual propagation is essential for analyzing the development of global oil trade. Previous research has focused mainly on the fuzzy long- or short-term one-to-one propagation of bivariate oil prices, generally ignoring various patterns of periodical multivariate propagation. This study presents a wavelet-based network approach to help uncover the multipath propagation of multivariable crude oil prices in a joint time-frequency period. The weekly oil spot prices of the OPEC member states from June 1999 to March 2011 are adopted as the sample data. First, we used wavelet analysis to find different subseries based on an optimal decomposing scale to describe the periodical feature of the original oil price time series. Second, a complex network model was constructed based on an optimal threshold selection to describe the structural feature of multivariable oil prices. Third, Bayesian network analysis (BNA) was conducted to find the probability causal relationship based on periodical structural features to describe the various patterns of periodical multivariable propagation. Finally, the significance of the leading and intermediary oil prices is discussed. These findings are beneficial for the implementation of periodical target-oriented pricing policies and investment strategies.

  12. Forecasting and evaluations of crude oil processing and oil derivatives consumption in Republic of Macedonia up to 2000 year

    International Nuclear Information System (INIS)

    Janevski, Risto

    1998-01-01

    Elaboration of various analysis in an energetic field is a quite usual, but inevitable action, procedure and investigation. Also, in a field of crude oil processing and oil derivatives consumption these analyses are a base for making a various range of forecasting and evaluations. How many of these forecasting and evaluations will be credible it depends mostly of diligent, precise and accurate data and experiences in the previous years. This part refers to forecasting and evaluations of crude oil processing and oil derivatives consumption in a short period up to 2000 year in Republic of Macedonia. (Author)

  13. Three essays in corporate finance: Examining the influence of government ownership and evaluating crude oil arbitrage

    Science.gov (United States)

    Holland, Kateryna

    The aim of this dissertation is twofold: first, to evaluate how governments influence firms in which they invest (chapters one and two), and second, to examine arbitrage in the crude oil market by investigating the relationship between crude oil inventories, physical prices, and financial prices (chapter three). In the first chapter (The Wealth Effects of Government Investment in Publicly Traded Firms), I study how government share ownership affects shareholder wealth. I find that government investments with higher likelihood of political interference have a negative influence on shareholder wealth, while the opposite is true for government investments with economic objectives. In the second chapter (Government Ownership and the Cost of Debt: Evidence form Government Investment in Publicly Traded Firms), I investigate how government share ownership affects the cost of debt of publicly traded firms. I find that government ownership generally leads to a higher cost of debt, except for times of economic and firm distress, when the value of the implicit government guarantee is associated with a reduction in the cost of debt. In the third chapter (Financial Trading, Spot Oil Prices, and Inventory: Evidence from the U.S. Crude Oil Market), I confirm the existence of an active cash and carry market in crude oil in Cushing, OK, the main U.S. crude oil futures settlement location. In other words, crude oil inventories in Cushing, but not in any other U.S. crude oil storage locations, are explained by the spread between the financial and the physical price of oil in addition to operational factors.

  14. Successful phytoremediation of crude-oil contaminated soil at an oil exploration and production company by plants-bacterial synergism.

    Science.gov (United States)

    Fatima, Kaneez; Imran, Asma; Amin, Imran; Khan, Qaiser M; Afzal, Muhammad

    2018-06-07

    Phytoremediation is a promising approach for the cleanup of soil contaminated with petroleum hydrocarbons. This study aimed to develop plant-bacterial synergism for the successful remediation of crude oil-contaminated soil. A consortia of three endophytic bacteria was augmented to two grasses, Leptochloa fusca and Brachiaria mutica, grown in oil-contaminated soil (46.8 g oil kg -1 soil) in the vicinity of an oil exploration and production company. Endophytes augmentation improved plant growth, crude oil degradation, and soil health. Maximum oil degradation (80%) was achieved with B. mutica plants augmented with the endophytes and it was significantly (P oil reduction indicates that catabolic gene expression is important for hydrocarbon mineralization. This investigation showed that the use of endophytes with appropriate plant is an effective strategy for the cleanup of oil-contaminated soil under field conditions.

  15. Comparative study on adsorption of crude oil and spent engine oil from seawater and freshwater using algal biomass.

    Science.gov (United States)

    Boleydei, Hamid; Mirghaffari, Nourollah; Farhadian, Omidvar

    2018-05-15

    Efficiency of a biosorbent prepared from the green macroalga Enteromorpha intestinalis biomass for decontamination of seawater and freshwater polluted by crude oil and engine spent oil was compared. The effect of different experimental conditions including contact time, pH, particle size, initial oil concentration, and biosorbent dose on the oil biosorption was studied in the batch method. The biosorbent was characterized by CHNOS, FTIR, and SEM analysis. The experimental data were well fitted to the pseudo-second-order kinetic model and the Langmuir adsorption isotherm model. Based on the obtained results, the adsorption of spent oil with higher viscosity was better than crude oil. The biosorption of oil hydrocarbons from seawater was more efficient than freshwater. The algal biomasses which are abundantly available could be effectively used as a low-cost and environmentally friendly adsorbent for remediation of oil spill in the marine environments or in the water and wastewater treatment.

  16. Phototoxic potential of undispersed and dispersed fresh and weathered Macondo crude oils to Gulf of Mexico Marine Organisms.

    Science.gov (United States)

    Finch, Bryson E; Marzooghi, Solmaz; Di Toro, Dominic M; Stubblefield, William A

    2017-10-01

    Crude oils contain a mixture of hydrocarbons, including phototoxic polycyclic aromatic hydrocarbons (PAHs) that have the ability to absorb ultraviolet (UV) light. Absorption of UV light by PAHs can substantially increase their toxicity to marine organisms. The objective of the present study was to examine the potential for phototoxicity of fresh and naturally weathered Macondo crude oils alone and in combination with the dispersant Corexit 9500 to mysid shrimp (Americamysis bahia), inland silverside (Menidia beryllina), sheepshead minnow (Cyprinodon variegatus), and Gulf killifish (Fundulus grandis). Acute toxicity tests were conducted using combinations of natural or artificial sunlight and low-energy water-accommodated fractions (WAFs) of fresh and weathered Macondo crude oils collected from the Gulf of Mexico. Studies were also conducted to compare the phototoxicity resulting from natural and artificial sunlight. Fresh Macondo crude oil was more phototoxic than weathered crude oils, both in the presence and in the absence of UV light. Differences in toxicity between fresh and weathered crude oils were likely attributed to lighter-ringed PAHs in fresh crude oils. Phototoxic PAHs were relatively resistant to weathering compared with lighter-ringed PAHs. The addition of Corexit 9500 to crude oil increased toxicity compared with tests with crude oil alone, by increasing phototoxic PAH concentrations in WAFs. Macondo crude oils had the potential to be phototoxic to Gulf of Mexico marine organisms if specific light conditions and PAH concentrations were present during the Deepwater Horizon oil spill. Environ Toxicol Chem 2017;36:2640-2650. © 2017 SETAC. © 2017 SETAC.

  17. The Effects of Crude Oil on Stock Markets with use of Markov Switching Models

    OpenAIRE

    Wiese, Thor August Mediaas

    2016-01-01

    In this thesis, a two regime Markov switching (MS) model is implemented to examine the relationship between crude oil, both brent oil and WTI, and stock markets. In particular, the model is applied to stock markets in both oil importing and exporting countries which include Canada, China, Japan, Germany, Netherlands, Norway, the United Kingdom and the United States. This paper first evaluates the significance of oil parameters in the detected regimes, where the two regimes respond to low mean...

  18. The empirical role of the exchange rate on the crude-oil price formation

    International Nuclear Information System (INIS)

    Yousefi, A.; Wirjanto, T.S.; University of Waterloo, Ont.

    2004-01-01

    This paper adopts a novel empirical approach to the crude-oil price formation for the purpose of understanding the price reactions of OPEC member countries to changes in the exchange rate of the US dollar against other major currencies and prices of other members. The results are broadly consistent with the view of the absence of a unified OPEC determined price in the international crude market literature. In addition, the results also highlight a cross regional dimension of the crude oil market. (author)

  19. Effects of surfactants on bacteria and the bacterial degradation of alkanes in crude oil

    Energy Technology Data Exchange (ETDEWEB)

    Bruheim, Per

    1998-12-31

    This thesis investigates the effects of surfactants on the bacterial degradation of alkanes in crude oil. Several alkane oxidising Gram positive and Gram negative were tested for their abilities to oxidise alkanes in crude oil emulsified with surfactants. The surfactants used to make the oil in water emulsions were either of microbial or chemical origin. Oxidation rates of resting bacteria oxidising various crude oil in water emulsions were measured by Warburg respirometry. The emulsions were compared with non-emulsified oil to see which was the preferred substrate. The bacteria were pregrown to both the exponential and stationary phase of growth before harvesting and preparation for the Warburg experiments. 123 refs., 4 figs., 14 tabs.

  20. Ultrasound aided in situ transesterification of crude palm oil adsorbed on spent bleaching clay

    International Nuclear Information System (INIS)

    Boey, Peng-Lim; Ganesan, Shangeetha; Maniam, Gaanty Pragas; Ali, Dafaalla Mohamed Hag

    2011-01-01

    Research highlights: → Crude palm oil adsorbed on spent bleaching clay converted to biodiesel. → Ultrasound dislodges adsorbed oil from spent bleaching clay into reaction mixture. → Co-solvents promotes miscibility of the reactants. -- Abstract: Adsorbed crude palm oil on spent bleaching clay (SBC) was in situ transesterified to methyl esters (biodiesel) by the aid of ultrasound and organic co-solvents (petroleum ether (PE) or ethyl methyl ketone (EMK)). The SBC under study was found to contain 24.2-27.0% of crude oil with free fatty acids (FFA) of 3.01% and moisture content of 0.29%. The optimized reaction conditions were as follows: methanol to oil molar ratio of 150:1; catalyst (KOH), 20%; reaction temperature, 60 ± 2 o C; reaction time, 2 h. Using PE as a co-solvent, highest conversion of 75.2% was achieved while 60% was recorded with EMK.