WorldWideScience

Sample records for aspect-ratio polymer microstructures

  1. Fabrication of high-aspect-ratio polymer microstructures and hierarchical textures using carbon nanotube composite master molds.

    Science.gov (United States)

    Copic, Davor; Park, Sei Jin; Tawfick, Sameh; De Volder, Michael F L; Hart, A John

    2011-05-21

    Scalable and cost effective patterning of polymer structures and their surface textures is essential to engineer material properties such as liquid wetting and dry adhesion, and to design artificial biological interfaces. Further, fabrication of high-aspect-ratio microstructures often requires controlled deep-etching methods or high-intensity exposure. We demonstrate that carbon nanotube (CNT) composites can be used as master molds for fabrication of high-aspect-ratio polymer microstructures having anisotropic nanoscale textures. The master molds are made by growth of vertically aligned CNT patterns, capillary densification of the CNTs using organic solvents, and capillary-driven infiltration of the CNT structures with SU-8. The composite master structures are then replicated in SU-8 using standard PDMS transfer molding methods. By this process, we fabricated a library of replicas including vertical micro-pillars, honeycomb lattices with sub-micron wall thickness and aspect ratios exceeding 50:1, and microwells with sloped sidewalls. This process enables batch manufacturing of polymer features that capture complex nanoscale shapes and textures, while requiring only optical lithography and conventional thermal processing.

  2. High-aspect ratio magnetic nanocomposite polymer cilium

    Science.gov (United States)

    Rahbar, M.; Tseng, H. Y.; Gray, B. L.

    2014-03-01

    This paper presents a new fabrication technique to achieve ultra high-aspect ratio artificial cilia micro-patterned from flexible highly magnetic rare earth nanoparticle-doped polymers. We have developed a simple, inexpensive and scalable fabrication method to create cilia structures that can be actuated by miniature electromagnets, that are suitable to be used for lab-on-a chip (LOC) and micro-total-analysis-system (μ-TAS) applications such as mixers and flow-control elements. The magnetic cilia are fabricated and magnetically polarized directly in microfluidic channels or reaction chambers, allowing for easy integration with complex microfluidic systems. These cilia structures can be combined on a single chip with other microfluidic components employing the same permanently magnetic nano-composite polymer (MNCP), such as valves or pumps. Rare earth permanent magnetic powder, (Nd0.7Ce0.3)10.5Fe83.9B5.6, is used to dope polydimethylsiloxane (PDMS), resulting in a highly flexible M-NCP of much higher magnetization and remanence [1] than ferromagnetic polymers typically employed in magnetic microfluidics. Sacrificial poly(ethylene-glycol) (PEG) is used to mold the highly magnetic polymer into ultra high-aspect ratio artificial cilia. Cilia structures with aspect ratio exceeding 8:0.13 can be easily fabricated using this technique and are actuated using miniature electromagnets to achieve a high range of motion/vibration.

  3. Fabrication of Ni stamp with high aspect ratio, two-leveled, cylindrical microstructures using dry etching and electroplating

    DEFF Research Database (Denmark)

    Petersen, Ritika Singh; Keller, Stephan Sylvest; Hansen, Ole;

    2015-01-01

    We describe a process for the fabrication of a Ni stamp that is applied to the microstructuring of polymers by hot embossing. The target devices are microcontainers that have a potential application in oral drug delivery. Each container is a 3D, cylindrical, high aspect ratio microstructure...

  4. Hot punching of high-aspect-ratio 3D polymeric microstructures for drug delivery

    DEFF Research Database (Denmark)

    Petersen, Ritika Singh; Keller, Stephan Sylvest; Boisen, Anja

    2015-01-01

    Hot punching: a highly versatile method of fabricating high-aspect-ratio 3D microstructures for drug delivery with good replication fidelity and yield.......Hot punching: a highly versatile method of fabricating high-aspect-ratio 3D microstructures for drug delivery with good replication fidelity and yield....

  5. High aspect ratio micro tool manufacturing for polymer replication using mu EDM of silicon, selective etching and electroforming

    DEFF Research Database (Denmark)

    Tosello, Guido; Bissacco, Giuliano; Tang, Peter Torben

    2008-01-01

    Mass fabrication of polymer micro components with high aspect ratio micro-structures requires high performance micro tools allowing the use of low cost replication processes such as micro injection moulding. In this regard an innovative process chain, based on a combination of micro electrical di...

  6. Proton beam writing and electroplating for the fabrication of high aspect ratio Au microstructures

    Energy Technology Data Exchange (ETDEWEB)

    Yue Weisheng [Centre for Ion Beam Applications, Department of Physics, National University of Singapore, Singapore 117542 (Singapore); Ren Yaping [Singapore Synchrotron Light Source, National University of Singapore, 5 Research Link, Singapore 117603 (Singapore); Kan, Jeroen Anton van; Chiam, S.-Y. [Centre for Ion Beam Applications, Department of Physics, National University of Singapore, Singapore 117542 (Singapore); Jian, Linke; Moser, Herbert O. [Singapore Synchrotron Light Source, National University of Singapore, 5 Research Link, Singapore 117603 (Singapore); Osipowicz, Thomas [Centre for Ion Beam Applications, Department of Physics, National University of Singapore, Singapore 117542 (Singapore)], E-mail: phyto@nus.edu.sg; Watt, Frank [Centre for Ion Beam Applications, Department of Physics, National University of Singapore, Singapore 117542 (Singapore)

    2009-07-01

    We present an approach to fabricate tall high aspect ratio Au microstructures by means of proton beam direct writing. Combining proton beam direct writing and electroplating, we successfully produced gold structures with sub-micrometer lateral dimensions, structure heights in excess of 11 {mu}m, and aspect ratios over 28. Sidewall quality of the Au structures was improved by lowering the process temperature to 20 deg. C when developing PMMA patterns with GG developer. The application of such structures as X-ray masks for deep X-ray lithography with synchrotron radiation was demonstrated.

  7. High-speed microprobe for roughness measurements in high-aspect-ratio microstructures

    Science.gov (United States)

    Doering, Lutz; Brand, Uwe; Bütefisch, Sebastian; Ahbe, Thomas; Weimann, Thomas; Peiner, Erwin; Frank, Thomas

    2017-03-01

    Cantilever-type silicon microprobes with an integrated tip and a piezoresistive signal read out have successfully proven to bridge the gap between scanning force microscopy and stylus profilometry. Roughness measurements in high-aspect-ratio microstructures (HARMS) with depths down to 5 mm and widths down to 50 µm have been demonstrated. To improve the scanning speed up to 15 mm s‑1, the wear of the tip has to be reduced. The atomic layer deposition (ALD) technique with alumina (Al2O3) has been tested for this purpose. Repeated wear measurements with coated and uncoated microprobe cantilevers have been carried out on a roughness standard at a speed of 15 mm s‑1. The tip shape and the wear have been measured using a new probing tip reference standard containing rectangular silicon grooves with widths from 0.3 µm to 3 µm. The penetration depth of the microprobe allows one to measure the wear of the tip as well as the tip width and the opening angle of the tip. The roughness parameters obtained on the roughness standard during wear experiments agree well with the reference values measured with a calibrated stylus instrument, nevertheless a small amount of wear still is observable. Further research is necessary in order to obtain wear resistant microprobe tips for non-destructive inspection of microstructures in industry and microform measurements, for example in injection nozzles.

  8. Dynamics of polymer nanoparticles through a single artificial nanopore with a high-aspect-ratio.

    Science.gov (United States)

    Cabello-Aguilar, Simon; Chaaya, Adib Abou; Bechelany, Mikhael; Pochat-Bohatier, Céline; Balanzat, Emmanuel; Janot, Jean-Marc; Miele, Philippe; Balme, Sébastien

    2014-11-14

    The development of nanometric Coulter counters for nanoparticle detection is an attractive and promising field of research. In this work, we have studied the influence of the nanopore surface state on charged polymer nanoparticle translocations. To make this, the translocation of carboxylate modified polystyrene microspheres (diameter 40, 70 and 100 nm) has been investigated through two kinds of high aspect ratio nanopores (negative and uncharged). The latter were tailored by a single track-etched and atomic layer deposition technique. It was shown that the mobility and the energy barrier are strongly dependent on nanopore surface charge. Typically if the latter exhibits negative surface charge, the microsphere mobility increases and the global energy barrier of entrance inside the nanopore decreases with its diameter, converse to the uncharged nanopore.

  9. Wet Etched High Aspect Ratio Microstructures on Quartz for MEMS Applications

    Science.gov (United States)

    Liang, Jinxing; Kohsaka, Fusao; Matsuo, Takahiro; Ueda, Toshitsugu

    Z cut α-quartz wafers were etched in saturated ammonium bifluoride solution at 87 degrees C. The side wall profiles were observed using the scanning electron microscopy (SEM) and plotted dependent on the polar direction. This research focused on investigating high aspect ratio trench and through-hole, which were dependent on the polar direction to the crystal axis. Aspect ratio in dependence on polar direction was also plotted and microchannels with aspect ratio > 3 could be achieved at the polar angle between 30° to 60°. The possibility of application for microcapillary was discussed, and the trench at 45° was considered best. Double-sided etching technique was used for manufacturing through-hole structures. Through-hole at 0° was demonstrated effective for fabrication of capacitive MEMS tilt sensor. Through-holes at 15° and 105° were proposed for fabrication of 90°-arranged two axis capactive tilt sensor, taking advantage of the twofold symmetry property around X axis and threefold symmetry property around Z axis.

  10. Gas-Assisted Heating Technology for High Aspect Ratio Microstructure Injection Molding

    Directory of Open Access Journals (Sweden)

    Shia-Chung Chen

    2013-01-01

    Full Text Available A hot gas is used for heating the cavity surface of a mold. Different mold gap sizes were designed. The mold surface temperature was heated to above the glass transition temperature of the plastic material, and the mold then closed for melt filling. The cavity surface can be heated to 130°C to assist the melt filling of the microfeatures. Results show that hot gas heating can improve the filling process and achieve 91% of the high aspect ratio microgrooves (about 640.38 μm of the maximum of 700 μm. The mold gap size strongly affects the heating speed and heating uniformity. Without surface preheating, the center rib is the highest. When the heating target temperature is 90°C or 100°C, the three microribs have a good uniformity of height. However, when the target temperature exceeds 100°C, the left side rib is higher than the other ribs.

  11. Hot embossing of photonic crystal polymer structures with a high aspect ratio

    DEFF Research Database (Denmark)

    Schelb, Mauno; Vannahme, Christoph; Kolew, Alexander;

    2011-01-01

    Hot embossing is a promising approach for mass production of photonic crystal structures. This paper describes the fabrication of a replication tool for two-dimensional photonic crystal patterns and its replication in substrates of poly(methylmethacrylate) (PMMA) and cyclic olefin copolymer (COC......). A nickel tool for the replication of structures with lateral dimensions of 110 nm and heights of approximately 370 nm is fabricated via electroplating of a nanostructured sample resulting in an aspect ratio of approximately 3.5. The structures are subsequently hot embossed into PMMA and COC substrates....

  12. Characterization of the optical parameters of high aspect ratio polymer micro-optical components

    Science.gov (United States)

    Krajewski, Rafal; Van Erps, Jurgen; Wissmann, Markus; Kujawinska, Malgorzata; Parriaux, Olivier; Tonchev, S.; Mohr, Jurgen; Thienpont, Hugo

    2008-04-01

    Over the last decades the significant grow of interest of photonics devices is observed in various fields of applications. Due to the market demands, the current research studies are focused on the technologies providing miniaturized, reliable low-cost micro-optical systems, particularly the ones featuring the fabrication of high aspect ratio structures. A high potential of these technologies comes from the fact that fabrication process is not limited to single optical components, but entire systems integrating sets of elements could be fabricated. This could in turn result in a significant saving on the assembly and packaging costs. We present a brief overview of the most common high aspect ratio fabrication technologies for micro-optical components followed by some characterization studies of these techniques. The sidewall quality and internal homogeneity will be considered as the most crucial parameters, having an impact on the wavefront propagation in the fabricated components. We show the characterization procedure and measurement results for components prototyped with Deep Proton Writing and glass micromachining technology replicated with Hot Embossing and Elastomeric Mould Vacuum Casting technology. We discuss the pros and cons for using these technologies for the production of miniaturized interferometers blocks. In this paper we present the status of our research on the new technology chain and we show the concept of microinterferometers to be fabricated within presented technology chain.

  13. Optimization of laser energy deposition for single-shot high aspect-ratio microstructuring of thick BK7 glass

    Science.gov (United States)

    Garzillo, Valerio; Jukna, Vytautas; Couairon, Arnaud; Grigutis, Robertas; Di Trapani, Paolo; Jedrkiewicz, Ottavia

    2016-07-01

    We investigate the generation of high aspect ratio microstructures across 0.7 mm thick glass by means of single shot Bessel beam laser direct writing. We study the effect on the photoinscription of the cone angle, as well as of the energy and duration of the ultrashort laser pulse. The aim of the study is to optimize the parameters for the writing of a regular microstructure due to index modification along the whole sample thickness. By using a spectrally resolved single pulse transmission diagnostics at the output surface of the glass, we correlate the single shot material modification with observations of the absorption in different portions of the retrieved spectra, and with the absence or presence of spectral modulation. Numerical simulations of the evolution of the Bessel pulse intensity and of the energy deposition inside the sample help us interpret the experimental results that suggest to use picosecond pulses for an efficient and more regular energy deposition. Picosecond pulses take advantage of nonlinear plasma absorption and avoid temporal dynamics effects which can compromise the stationarity of the Bessel beam propagation.

  14. High aspect ratio microstructuring of transparent dielectrics using femtosecond laser pulses: method for optimization of the machining throughput

    Science.gov (United States)

    Hendricks, F.; der Au, J. Aus; Matylitsky, V. V.

    2014-10-01

    High average power, high repetition rate femtosecond lasers with μJ pulse energies are increasingly used for material processing applications. The unique advantage of material processing with sub-picosecond lasers is efficient, fast and localized energy deposition, which leads to high ablation efficiency and accuracy in nearly all kinds of solid materials. This work focuses on the machining of high aspect ratio structures in transparent dielectrics, in particular chemically strengthened Xensation™ glass from Schott using multi-pass ablative material removal. For machining of high aspect ratio structures, among others needed for cutting applications, a novel method to determine the best relation between kerf width and number of overscans is presented. The importance of this relation for optimization of the machining throughput will be demonstrated.

  15. Simple and cost-effective fabrication of solid biodegradable polymer microneedle arrays with adjustable aspect ratio for transdermal drug delivery using acupuncture microneedles

    Science.gov (United States)

    Cha, Kyoung Je; Kim, Taewan; Jea Park, Sung; Kim, Dong Sung

    2014-11-01

    Polymer microneedle arrays (MNAs) have received much attention for their use in transdermal drug delivery and microneedle therapy systems due to the advantages they offer, such as low cost, good mechanical properties, and a versatile choice of materials. Here, we present a simple and cost-effective method for the fabrication of a biodegradable polymer MNA in which the aspect ratio of each microneedle is adjustable using commercially available acupuncture microneedles. In our process, a master template with acupuncture microneedles, whose shape will be the final MNA, was carefully prepared by fixing them onto a plastic substrate with selectively drilled holes which, in turn, determine the aspect ratios of the microneedles. A polylactic acid (PLA; a biodegradable polymer) MNA was fabricated by a micromolding process with a polydimethylsiloxane (PDMS) mold containing the cavity of the microneedles, which was obtained by the PDMS replica molding against the master template. The mechanical force and degradation behavior of the replicated PLA MNA were characterized with the help of a compression test and an accelerated degradation test, respectively. Finally, the transdermal drug delivery performance of the PLA MNA was successfully simulated by two different methods of penetration and staining, using the skin of a pig cadaver. These results indicated that the proposed method can be effectively used for the fabrication of polymer MNAs which can be used in various microneedle applications.

  16. Development of a prediction equation for depth, aspect ratio, and trench roughness pertaining to excimer laser ablation of polymer materials

    Science.gov (United States)

    McGinty, Sean; O'Connor, Gerard M.; Glynn, Thomas J.

    2005-06-01

    Excimer based laser ablation of micro-fluidic circuits for micro-total analysis systems (μTAS) is an alternative to more expensive techniques of LIGA or micro-moulding. In the interests of developing a rapid prototyping method for direct writing of micro-fluidic circuits in polymer materials the ablation process was characterised using Design of Experiment techniques and a robust full factorial model was developed. Input factors of pulse energy, repetition rate, scan speed and number of passes were considered. Output responses of trench bottom width, sidewall angle, trench depth and trench roughness were measured. From this a prediction equation was created to forecast the output responses prior to machining and to allow the development of a process prior to machining. The accuracy of the prediction equation is discussed for four materials; Polystyrene, Polycarbonate, Non-CQ grade PMMA and CQ grade PMMA. For the four materials studied the response of Polystyrene and Polycarbonate were similar while the two grades of PMMA behave differently.

  17. A microstructured Polymer Optical Fiber Biosensor

    DEFF Research Database (Denmark)

    Emiliyanov, Grigoriy Andreev; Jensen, Jesper Bo; Hoiby, Poul E.

    2006-01-01

    We demonstrate selective detection of fluorophore labeled antibodies from minute samples probed by a sensor layer of the complementary biomolecules immobilized inside the air holes of microstructured Polymer Optical Fibers....

  18. Fabrication of biodegradable polymer (PLGA) microstructures and applications in controlled drug delivery

    Science.gov (United States)

    Yang, Ren; Chen, Tianning; Chen, Hualing; Wang, Wanjun

    2004-01-01

    Using biodegradable polymers for implantable drug delivery purposes has been a very important research area and industry for many years. Polymers, such as PLGA, have been the most attractive one because it does not require removal after the drug has been released. We report a research effort to microfabricate high aspect ratio microstructures of PLGA and its potential applications in implantable drug delivery. The prototypes of packaged cells with dyes have also been made and currently under test for linear release of sample dyes.

  19. Dielectrophoretically structured piezoelectric composites with high aspect ratio piezoelectric particles inclusions

    NARCIS (Netherlands)

    Ende, D.A. van den; Kempen, S.E. van; Wu, X.; Groen, W.A.; Randall, C.A.; Zwaag, S. van der

    2012-01-01

    Piezoelectric composites were prepared by dielectrophoretic alignment of high aspect ratio piezoelectric particles in a thermosetting polymer matrix. A high level of alignment was achieved in the cured composite from a resin containing randomly oriented high aspect ratio particles. Upon application

  20. Transcription and the aspect ratio of DNA

    DEFF Research Database (Denmark)

    Olsen, Kasper Wibeck; Bohr, Jakob

    2013-01-01

    analysis of transcription. It is shown that under certain reasonable assumptions transcription is only possible if the aspect ratio is in the regime corresponding to further twisting. We find this constraint to be in agreement with long-established crystallographic studies of DNA....

  1. Template-mediated Synthesis of Hollow Microporous Organic Nanorods with Tunable Aspect Ratio

    Science.gov (United States)

    Li, Qingyin; Jin, Shangbin; Tan, Bien

    2016-08-01

    Hollow microporous organic nanorods (HMORs) with hypercrosslinked polymer (HCPs) shells were synthesized through emulsion polymerization followed by hypercrosslinking. The HMORs have tunable aspect ratios, high BET surface areas and monodispersed morphologies, showing good performance in gas adsorpion.

  2. Noise of Embedded High Aspect Ratio Nozzles

    Science.gov (United States)

    Bridges, James E.

    2011-01-01

    A family of high aspect ratio nozzles were designed to provide a parametric database of canonical embedded propulsion concepts. Nozzle throat geometries with aspect ratios of 2:1, 4:1, and 8:1 were chosen, all with convergent nozzle areas. The transition from the typical round duct to the rectangular nozzle was designed very carefully to produce a flow at the nozzle exit that was uniform and free from swirl. Once the basic rectangular nozzles were designed, external features common to embedded propulsion systems were added: extended lower lip (a.k.a. bevel, aft deck), differing sidewalls, and chevrons. For the latter detailed Reynolds-averaged Navier-Stokes (RANS) computational fluid dynamics (CFD) simulations were made to predict the thrust performance and to optimize parameters such as bevel length, and chevron penetration and azimuthal curvature. Seventeen of these nozzles were fabricated at a scale providing a 2.13 inch diameter equivalent area throat." ! The seventeen nozzles were tested for far-field noise and a few data were presented here on the effect of aspect ratio, bevel length, and chevron count and penetration. The sound field of the 2:1 aspect ratio rectangular jet was very nearly axisymmetric, but the 4:1 and 8:1 were not, the noise on their minor axes being louder than the major axes. Adding bevel length increased the noise of these nozzles, especially on their minor axes, both toward the long and short sides of the beveled nozzle. Chevrons were only added to the 2:1 rectangular jet. Adding 4 chevrons per wide side produced some decrease at aft angles, but increased the high frequency noise at right angles to the jet flow. This trend increased with increasing chevron penetration. Doubling the number of chevrons while maintaining their penetration decreased these effects. Empirical models of the parametric effect of these nozzles were constructed and quantify the trends stated above." Because it is the objective of the Supersonics Project that

  3. Cyclic voltammetric investigations of microstructured and platinum-covered glassy carbon electrodes in contact with a polymer electrolyte membrane

    Energy Technology Data Exchange (ETDEWEB)

    Scherer, G.G.; Veziridis, Z.; Staub, M. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Freimuth, H. [Inst. fuer Mikrotechnik Mainz IMM, Mainz (Germany)

    1997-06-01

    Model gas diffusion electrodes were prepared by microstructuring glassy carbon surfaces with high aspect ratios and subsequent deposition of platinum. These electrodes were characterized by hydrogen under-potential deposition (H-upd) in contact with a polymer electrolyte membrane employing cyclic voltametry. H-upd was found on platinum areas not in direct contact to the solid electrolyte, as long as a continuous platinum-path existed. A carbon surface between platinum acts as barrier for H-upd. (author) 4 figs., 5 refs.

  4. Winglets on low aspect ratio wings

    Science.gov (United States)

    Kuhlman, John M.; Liaw, Paul

    1987-01-01

    The drag reduction potentially available from the use of winglets at the tips of low aspect ratio (1.75-2.67) wings with pronounced (45-60 deg) leading edge sweep is assessed numerically for the case of a cruise design point at Mach of 0.8 and a lift coefficient of 0.3. Both wing-winglet and wing-alone design geometries are derived from a linear-theory, minimum induced drag design methodology. Relative performance is evaluated with a nonlinear extended small disturbance potential flow analysis code. Predicted lift coefficient/pressure drag coefficient increases at equal lift for the wing-winglet configurations over the wing-alone planform are of the order of 14.6-15.8, when boundary layer interaction is included.

  5. Zeonex Microstructured Polymer Optical Fibre Bragg Grating Sensor

    DEFF Research Database (Denmark)

    Woyessa, Getinet; Fasano, Andrea; Markos, Christos

    2016-01-01

    We fabricated an endlessly single mode and humidity insensitive Zeonex microstructured polymer optical fibre (mPOF) for fibre Bragg grating (FBG) temperature and strain sensors. We inscribed and characterise FBGs in Zeonex mPOF for the first time.......We fabricated an endlessly single mode and humidity insensitive Zeonex microstructured polymer optical fibre (mPOF) for fibre Bragg grating (FBG) temperature and strain sensors. We inscribed and characterise FBGs in Zeonex mPOF for the first time....

  6. Multi-antibody biosensing with Topas microstructured polymer optical fiber

    DEFF Research Database (Denmark)

    Emiliyanov, Grigoriy Andreev; Bang, Ole; Hoiby, Poul E.

    We present a Topas based microstructured polymer optical fiber multi-antibody biosensor. This polymer allows localized activation of sensor layers on the inner side of the air holes. This concept is used to create two different sensor sections in the same fiber. Simultaneous detection of two kinds...

  7. Exercise in Experimental Plastics Technology: Hot Embossing of Polymers with surface microstructure

    DEFF Research Database (Denmark)

    Eriksson, Torbjörn Gerhard; Rasmussen, Henrik Koblitz

    2004-01-01

    Hot Embossing of polymers with surface microstructure Polymer materials have proven to be good materials for manufacturing nano/ and microstructure. There are three major processing techniques: hot embossing, injection moulding and casting. Hot embossing provides several advantages such as relati...

  8. Aspect ratio dependence in magnetorotational instability shearing box simulations

    CERN Document Server

    Bodo, G; Cattaneo, F; Rossi, P; Ferrari, A

    2008-01-01

    Aims: We study the changes in the properties of turbulence driven by the magnetorotational instability in a shearing box, as the computational domain size in the radial direction is varied relative to the height Methods: We perform 3D simulations in the shearing box approximation, with a net magnetic flux, and we consider computational domains with different aspect ratios Results: We find that in boxes of aspect ratio unity the transport of angular momentum is strongly intermittent and dominated by channel solutions in agreement with previous work. In contrast, in boxes with larger aspect ratio, the channel solutions and the associated intermittent behavior disappear. Conclusions: There is strong evidence that, as the aspect ratio becomes larger, the characteristics of the solution become aspect ratio independent. We conclude that shearing box calculations with aspect ratio unity or near unity may introduce spurious effects.

  9. Localized biosensing with Topas microstructured polymer optical fiber.

    Science.gov (United States)

    Emiliyanov, Grigoriy; Jensen, Jesper B; Bang, Ole; Hoiby, Poul E; Pedersen, Lars H; Kjaer, Erik M; Lindvold, Lars

    2007-03-01

    We present what is believed to be the first microstructured polymer optical fiber (mPOF) fabricated from Topas cyclic olefin copolymer, which has attractive material and biochemical properties. This polymer allows for a novel type of fiber-optic biosensor, where localized sensor layers may be activated on the inner side of the air holes in a predetermined section of the mPOF. The concept is demonstrated using a fluorescence-based method for selective detection of fluorophore-labeled antibodies.

  10. Retrieval of aerosol aspect ratio from optical measurements in Vienna

    Science.gov (United States)

    Kocifaj, M.; Horvath, H.; Gangl, M.

    The phase function and extinction coefficient measured simultaneously are interpreted in terms of surface distribution function and mean effective aspect ratio of aerosol particles. All optical data were collected in the atmosphere of Vienna during field campaign in June 2005. It is shown that behavior of aspect ratio of Viennese aerosols has relation to relative humidity in such a way, that nearly spherical particles (with aspect ratio ɛ≈1) might became aspherical with ɛ≈1.3-1.6 under low relative humidity conditions. Typically, >80% of all Viennese aerosols have the aspect ratio Vienna.

  11. Modeling and characterization of dielectrophoretically structured piezoelectric composites using piezoceramic particle inclusions with high aspect ratios

    NARCIS (Netherlands)

    Ende, D.A. van den; Maier, R.A.; Neer, P.L.M.J. van; Zwaag, S. van der; Randall, C.A.; Groen, W.A.

    2013-01-01

    In this work, the piezoelectric properties at high electric fields of dielectrophoretically aligned PZT - polymer composites containing high aspect ratio particles (such as short fibers) are presented. Polarization and strain as a function of electric field are evaluated. The properties of the compo

  12. A simple method for fabrication of high-aspect-ratio all-silicon grooves

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Yuncan; Pan, An; Si, Jinhai, E-mail: jinhaisi@mail.xjtu.edu.cn; Chen, Tao; Chen, Feng; Hou, Xun

    2013-11-01

    A simple method using 800-nm femtosecond laser irradiation and chemical selective etching has been proposed for fabrication of high-aspect-ratio all-silicon grooves. Grooves with the maximum aspect ratio of 44 were produced. A scanning electronic microscopy equipped with an energy dispersive X-ray spectroscopy was employed to characterize the morphology and chemical composition of the grooves respectively. The formation mechanism of the grooves was attributed to the chemical reaction of the laser induced refractive index change microstructures and hydrofluoric acid solution. The dependences of the aspect ratio of the grooves on the laser irradiation parameters, such as: the numerical aperture of the microscope objective lens, the laser average power and the laser scanning velocity, are discussed.

  13. Sealing of polymer micro-structures by over-moulding

    DEFF Research Database (Denmark)

    Vingaard, Mathias; Christiansen, Jesper de Claville

    2012-01-01

    A concept for sealing of polymer micro-structures by over-moulding with polystyrene was devised and investigated by both experiments and simulations. The depth to which the melt filled the structure, i.e. a groove in the surface of the insert, before solidification was compared with results from ...

  14. Sensing characteristics of birefringent microstructured polymer optical fiber

    DEFF Research Database (Denmark)

    Szczurowski, Marcin K.; Frazao, Orlando; Baptista, J. M.;

    2011-01-01

    We experimentally studied several sensing characteristics of a birefringent microstructured polymer optical fiber. The fiber exhibits a birefringence of the order 2×10-5 at 1.3 μm because of two small holes adjacent to the core. In this fiber, we measured spectral dependence of phase and group mo...

  15. 3D microstructuring of biodegradable polymers

    DEFF Research Database (Denmark)

    Nagstrup, Johan; Keller, Stephan Sylvest; Almdal, Kristoffer

    2011-01-01

    Biopolymer films with a thickness of 100μm are prepared using spin coating technique with solutions consisting of 25wt.% polycaprolactone or poly-l-lactide in dichloromethane. SU-8 stamps are fabricated using three photolithography steps. The stamps are used to emboss 3D microstructures...

  16. Modeling Percolation in Polymer Nanocomposites by Stochastic Microstructuring

    Directory of Open Access Journals (Sweden)

    Matias Soto

    2015-09-01

    Full Text Available A methodology was developed for the prediction of the electrical properties of carbon nanotube-polymer nanocomposites via Monte Carlo computational simulations. A two-dimensional microstructure that takes into account waviness, fiber length and diameter distributions is used as a representative volume element. Fiber interactions in the microstructure are identified and then modeled as an equivalent electrical circuit, assuming one-third metallic and two-thirds semiconductor nanotubes. Tunneling paths in the microstructure are also modeled as electrical resistors, and crossing fibers are accounted for by assuming a contact resistance associated with them. The equivalent resistor network is then converted into a set of linear equations using nodal voltage analysis, which is then solved by means of the Gauss–Jordan elimination method. Nodal voltages are obtained for the microstructure, from which the percolation probability, equivalent resistance and conductivity are calculated. Percolation probability curves and electrical conductivity values are compared to those found in the literature.

  17. Thermo-mechanical properties of high aspect ratio silica nanofiber filled epoxy composites

    Science.gov (United States)

    Ren, Liyun

    The optimization of thermo-mechanical properties of polymer composites at low filler loadings is of great interest in both engineering and scientific fields. There have been several studies on high aspect ratio fillers as novel reinforcement phase for polymeric materials. However, facile synthesis method of high aspect ratio nanofillers is limited. In this study, a scalable synthesis method of high aspect ratio silica nanofibers is going to be presented. I will also demonstrate that the inclusion of high aspect ratio silica nanofibers in epoxy results in a significant improvement of epoxy thermo-mechanical properties at low filler loadings. With silica nanofiber concentration of 2.8% by volume, the Young's modulus, ultimate tensile strength and fracture toughness of epoxy increased ~23, ~28 and ~50%, respectively, compared to unfilled epoxy. At silica nanofiber volume concentration of 8.77%, the thermal expansion coefficient decreased by ˜40% and the thermal conductivity was improved by ˜95% at room temperature. In the current study, the influence of nano-sized silica filler aspect ratio on mechanical and thermal behavior of epoxy nanocomposites were studied by comparing silica nanofibers to spherical silica nanoparticles (with aspect ratio of one) at various filler loadings. The significant reinforcement of composite stiffness is attributed to the variation of the local stress state in epoxy due to the high aspect ratio of the silica nanofiber and the introduction of a tremendous amount of interfacial area between the nanofillers and the epoxy matrix. The fracture mechanisms of silica nanofiber filled epoxy were also investigated. The existence of high aspect ratio silica nanofiber promotes fracture energy dissipation by crack deflection, crack pinning as well as debonding with fiber pull-out leading to enhanced fracture toughness. High aspect ratio fillers also provide significant reduction of photon scattering due to formation of a continuous fiber network

  18. Localized biosensing with Topas microstructured Polymer Optical Fiber

    DEFF Research Database (Denmark)

    Emiliyanov, Grigoriy Andreev; Jensen, Jesper Bo; Bang, Ole

    2007-01-01

    We present what is believed to be the first microstructured polymer optical fiber (mPOF) fabricated from Topas cyclic olefin copolymer, which has attractive material and biochemical properties. This polymer allows for a novel type of fiber-optic biosensor, where localized sensor layers may...... be activated on the inner side of the air holes in a predetermined section of the mPOF. The concept is demonstrated using a fluorescencebased method for selective detection of fluorophore-labeled antibodies. © 2007 Optical Society of America...

  19. Quantitative microstructure analysis of polymer-modified mortars.

    Science.gov (United States)

    Jenni, A; Herwegh, M; Zurbriggen, R; Aberle, T; Holzer, L

    2003-11-01

    Digital light, fluorescence and electron microscopy in combination with wavelength-dispersive spectroscopy were used to visualize individual polymers, air voids, cement phases and filler minerals in a polymer-modified cementitious tile adhesive. In order to investigate the evolution and processes involved in formation of the mortar microstructure, quantifications of the phase distribution in the mortar were performed including phase-specific imaging and digital image analysis. The required sample preparation techniques and imaging related topics are discussed. As a form of case study, the different techniques were applied to obtain a quantitative characterization of a specific mortar mixture. The results indicate that the mortar fractionates during different stages ranging from the early fresh mortar until the final hardened mortar stage. This induces process-dependent enrichments of the phases at specific locations in the mortar. The approach presented provides important information for a comprehensive understanding of the functionality of polymer-modified mortars.

  20. High lift generation of low-aspect-ratio wings

    Science.gov (United States)

    Devoria, Adam; Mohseni, Kamran

    2016-11-01

    The time-averaged flow field in the center-span of low-aspect-ratio rectangular wings is experimentally measured. It is shown that lift stall is preceded by shedding of strong trailing-edge vorticity. The induced downwash of the tip vortices delays the growth of the attached boundary layer as well as leading-edge separation. Reattached flow occurs for sufficiently low aspect ratios and results in a smooth merging of the flow at the trailing edge thus assisting in satisfying a Kutta condition there. As a consequence, the strength of vorticity shed from the trailing edge is decreased and allows for continued lift generation at high angles of attack. When the reattachment point passes beyond the trailing edge, a strong shear layer is generated there and represents negative lift, leading to stall with a slight increase in angle of attack or aspect ratio.

  1. Scattering and extinction from high-aspect-ratio trenches

    DEFF Research Database (Denmark)

    Roberts, Alexander Sylvester; Søndergaard, Thomas; Chirumamilla, Manohar;

    2015-01-01

    We construct a semi-analytical model describing the scattering, extinction and absorption properties of a high aspect-ratio trench in a metallic film. We find that these trenches act as highly efficient scatterers of free waves. In the perfect conductor limit, which for many metals is approached...

  2. Low Aspect-Ratio Wings for Wing-Ships

    DEFF Research Database (Denmark)

    Filippone, Antonino; Selig, M.

    1998-01-01

    Flying on ground poses technical and aerodynamical challenges. The requirements for compactness, efficiency, manouverability, off-design operation,open new areas of investigations in the fieldof aerodynamic analysis and design. A review ofthe characteristics of low-aspect ratio wings, in- and out...

  3. Selective detection of antibodies in microstructured polymer optical fibers

    DEFF Research Database (Denmark)

    Jensen, Jesper Bo Damm; Hoiby, P.E.; Emiliyanov, Grigoriy Andreev

    2005-01-01

    We demonstrate selective detection of fluorophore labeled antibodies from minute samples probed by a sensor layer of complementary biomolecules immobilized inside the air holes of microstructured Polymer Optical Fiber (mPOF). The fiber core is defined by a ring of 6 air holes and a simple procedure...... was applied to selectively capture either α-streptavidin or α-CRP antibodies inside these air holes. A sensitive and easy-to-use fluorescence method was used for the optical detection. Our results show that mPOF based biosensors can provide reliable and selective antibody detection in ultra small sample...

  4. Microstructured shape memory polymer surfaces with reversible dry adhesion.

    Science.gov (United States)

    Eisenhaure, Jeffrey D; Xie, Tao; Varghese, Stephen; Kim, Seok

    2013-08-28

    We present a shape memory polymer (SMP) surface with repeatable, very strong (>18 atm), and extremely reversible (strong to weak adhesion ratio of >1 × 10(4)) dry adhesion to a glass substrate. This was achieved by exploiting bulk material properties of SMP and surface microstructuring. Its exceptional dry adhesive performance is attributed to the SMP's rigidity change in response to temperature and its capabilities of temporary shape locking and permanent shape recovery, which when combined with a microtip surface design enables time-independent control of contact area.

  5. Selective detection of antibodies in microstructured polymer optical fibers.

    Science.gov (United States)

    Jensen, Jesper; Hoiby, Poul; Emiliyanov, Grigoriy; Bang, Ole; Pedersen, Lars; Bjarklev, Anders

    2005-07-25

    We demonstrate selective detection of fluorophore labeled antibodies from minute samples probed by a sensor layer of complementary biomolecules immobilized inside the air holes of microstructured Polymer Optical Fiber (mPOF). The fiber core is defined by a ring of 6 air holes and a simple procedure was applied to selectively capture either alpha-streptavidin or alpha-CRP antibodies inside these air holes. A sensitive and easy-to-use fluorescence method was used for the optical detection. Our results show that mPOF based biosensors can provide reliable and selective antibody detection in ultra small sample volumes.

  6. Microstructure of Sheared Entangled Solutions of Semiflexible Polymers

    Directory of Open Access Journals (Sweden)

    Marc Lämmel

    2016-09-01

    Full Text Available We study the influence of finite shear deformations on the microstructure and rheology of solutions of entangled semiflexible polymers theoretically and by numerical simulations and experiments with filamentous actin. Based on the tube model of semiflexible polymers, we predict that large finite shear deformations strongly affect the average tube width and curvature, thereby exciting considerable restoring stresses. In contrast, the associated shear alignment is moderate, with little impact on the average tube parameters, and thus expected to be long-lived and detectable after cessation of shear. Similarly, topologically preserved hairpin configurations are predicted to leave a long-lived fingerprint in the shape of the distributions of tube widths and curvatures. Our numerical and experimental data support the theory.

  7. High aspect ratio channels in glass and porous silicon

    Science.gov (United States)

    Liang, H. D.; Dang, Z. Y.; Wu, J. F.; van Kan, J. A.; Qureshi, S.; Ynsa, M. D.; Torres-Costa, V.; Maira, A.; Venkatesan, T. V.; Breese, M. B. H.

    2017-03-01

    We have developed a micromachining process to produce high-aspect-ratio channels and holes in glass and porous silicon. Our process utilizes MeV proton beam irradiation of silicon using direct writing with a focused beam, followed by electrochemical etching. To increase throughput we have also developed another process for large area ion irradiation based on a radiation-resistant gold surface mask, allowing many square inches to be patterned. We present a study of the achievable channel width, depth and period and sidewall verticality for a range of channels which can be over 100 μm deep or 100 nm wide with aspect ratios up to 80. This process overcomes the difficulty of machining glass on a micro- and nanometer scale which has limited many areas of applications in different fields such as microelectronics and microfluidics.

  8. Aeroelastic stability analysis of high aspect ratio aircraft wings

    OpenAIRE

    Banerjee, J. R.; Liu, X.; Kassem, H. I.

    2014-01-01

    Free vibration and flutter analyses of two types of high aspect ratio aircraft wings are presented. The wing is idealised as an assembly of bending-torsion coupled beams using the dynamic stiffness method leading to a nonlinear eigenvalue problem. This problem is solved using the Wattrick-Williams algorithm yielding natural frequencies and mode shapes. The flutter analysis is carried out using the normal mode method in conjunction with generalised coordinates and two-dimensional unsteady aero...

  9. Controlling metamaterial resonances via dielectric and aspect ratio effects

    CERN Document Server

    Chiam, Sher-Yi; Zhang, Weili; Bettiol, Andrew A

    2010-01-01

    We study ways to enhance the sensitivity and dynamic tuning range of the fundamental inductor-capacitor (LC) resonance in split ring resonators (SRRs) by controlling the aspect ratio of the SRRs and their substrate thickness. We conclude that both factors can significantly affect the LC resonance. We show that metafilms consisting of low height SRRs on a thin substrate are most sensitive to changes in their dielectric environment and thus show excellent potential for sensing applications.

  10. Formation of High Aspect Ratio Microcoil Using Dipping Method

    Science.gov (United States)

    Noda, Daiji; Yamashita, Shuhei; Matsumoto, Yoshifumi; Setomoto, Masaru; Hattori, Tadashi

    Coils are used in many electronic devices as inductors in mobile units such as mobile phone, digital cameras, etc. Inductance and quality factor of coils are very important value of the performance. Therefore, the requests for coils are small size, high inductance, low power consumption, etc. However, coils are unsuitable for miniaturization because of its structure. Therefore, we have proposed and developed the microcoils of high aspect ratio with the dipping method and an X-ray lithography technique. In dipping method, centrifugal force and highly viscous photoresist solution were key points to evenly apply resist in the form of thick film on metal bar. The film thickness of resist on bar was achieved about 50 μm after single coating. Using these techniques, we succeeded in creating threaded groove structure with 10 μm lines and spaces on 1 mm brass bar. In this case, the aspect ratio was achieved five. It is very expected the high performance microcoil with high aspect ratio lines could be manufactured in spite of the miniature size.

  11. Effects of rectangular microchannel aspect ratio on laminar friction constant

    Science.gov (United States)

    Papautsky, Ian; Gale, Bruce K.; Mohanty, Swomitra K.; Ameel, Timothy A.; Frazier, A. Bruno

    1999-08-01

    In this paper, the effects of rectangular microchannel aspect ratio on laminar friction constant are described. The behavior of fluids was studied using surface micromachined rectangular metallic pipette arrays. Each array consisted of 5 or 7 pipettes with widths varying from 150 micrometers to 600 micrometers and heights ranging from 22.71 micrometers to 26.35 micrometers . A downstream port for static pressure measurement was used to eliminate entrance effects. A controllable syringe pump was used to provide flow while a differential pressure transducer was used to record the pressure drop. The experimental data obtained for water for flows at Reynolds numbers below 10 showed an approximate 20% increase in the friction constant for a specified driving potential when compared to macroscale predictions from the classical Navier-Stokes theory. When the experimental data are studied as a function of aspect ratio, a 20% increase in the friction constant is evident at low aspect ratios. A similar increase is shown by the currently available experimental data for low Reynolds number (flows of water.

  12. A wearable, highly stable, strain and bending sensor based on high aspect ratio graphite nanobelts

    Science.gov (United States)

    Alaferdov, A. V.; Savu, R.; Rackauskas, T. A.; Rackauskas, S.; Canesqui, M. A.; de Lara, D. S.; Setti, G. O.; Joanni, E.; de Trindade, G. M.; Lima, U. B.; de Souza, A. S.; Moshkalev, S. A.

    2016-09-01

    A simple and scalable method was developed for the fabrication of wearable strain and bending sensors, based on high aspect ratio (length/thickness ˜103) graphite nanobelt thin films deposited by a modified Langmuir-Blodgett technique onto flexible polymer substrates. The sensing mechanism is based on the changes in contact resistance between individual nanobelts upon substrate deformation. Very high sensor response stability for more than 5000 strain-release cycles and a device power consumption as low as 1 nW were achieved. The device maximum stretchability is limited by the metal electrodes and the polymer substrate; the maximum strain that could be applied to the polymer used in this work was 40%. Bending tests carried out for various radii of curvature demonstrated distinct sensor responses for positive and negative curvatures. The graphite nanobelt thin flexible films were successfully tested for acoustic vibration and heartbeat sensing.

  13. Multigigabit short-reach communication over microstructured polymer optical fiber

    Science.gov (United States)

    Surkova, Galina; Kruglov, Roman; Lwin, Richard; Leon-Saval, Sergio G.; Argyros, Alexander; Poisel, Hans; Zadorin, Anatoly

    2017-03-01

    In contrast to conventional polymer optical fibers (POF) microstructured POF (mPOF) provide an additional opportunity to control the optical properties of the propagating signals. A particular arrangement of the air holes allows to reduce the number of waveguide modes and thus overcome the bandwidth limitation which is inherent for step-index POF. In this paper we report on the implementation of a 50 m data transmission link based on mPOF with a single ring of holes and a core diameter of 180 μm. A bit rate of 7 Gb/s was achieved at a bit-error ratio (BER) of 10-3 employing on-off keying modulation technique and an offline-processed symbol-spaced decision feedback equalizer. Discrete multitone modulation provided a bit rate of 8.07 Gb/s at BER of 10-3.

  14. Polymer microstructured fibers for guiding of THz radiation

    DEFF Research Database (Denmark)

    Nielsen, Kristian; Bang, Ole; Jepsen, Peter Uhd

    2010-01-01

    THz radiation, including low-loss transport of THz signals [1] between high-speed devices, integrated components for manipulation of THz light [2], such as power splitters, polarization management, and frequency filters, and confinement of the electric field of a THz signal in a small volume, enabling...... spectroscopic investigations of minute sample quantities [3]. In this presentation we will describe our current efforts in the development, fabrication and characterization of a class of THz waveguides and components based on microstructured polymer optical fibers (mPOF’s) [4] designed for the THz frequency...... fibers and components is carried out by THz time-domain spectroscopy, where the amplitude and phase of the transmitted signal through the sample is compared to a reference signal. In this manner we can characterize both loss and dispersion of the waveguide. In addition, near-field measurements across...

  15. High aspect ratio 3D nanopatterning using Proton Beam Writing

    Science.gov (United States)

    van Kan, Jeroen A.

    2009-03-01

    Proton beam writing (PBW) is a new direct write lithography using MeV protons, and is unique because of its ability to fabricate 3D structures of high aspect ratio structures directly in resist material like PMMA, SU-8 and HSQ. The introduction by CIBA, Singapore of a dedicated PBW facility, capable of writing at the micro- and nano- scale has facilitated high aspect ratio nanostructuring. PBW has demontrated high aspect ratio walls in HSQ down to the 20nm level. In recent experiments details down to sub 20 nm have been achieved in PMMA. Monte-Carlo calculations have shown that structuring down to the nanometer level is feasible. All this is possible because of the virtual absence of proximity effects (unwanted resist exposure by stray secondary electrons). The design and performance of this unique nanoprobe facility will be discussed. Two potential fields of application (eg nanofluidics and nanowire integration) of PBW will be discussed. Currently nanofluidics devices have typically only one critical dimension below 100 nm. Here we will introduce PBW as a powerful technique to fabricate molds for replication of PDMS nanofluidic circuits down to the sub 100 nm level in two dimensions. Initial chips with dimension down to 150 nm have successfully been used to study DNA folding in quasi-1d nanochannels in tandem with fluorescence imaging. Since the size of these PDMS nanochannels is not limited by the PDMS or PBW further miniaturization down to the sub 100 nm level is a realistic goal and initial results will be discussed. Nanowires are a potential building block for nano-electronic devices, and one critical problem is the integration of nanowires to form contacts. Porous alumina templates and high energy ion-tracks have been used for the production of nanowire templates in a random orientation. Since PBW is the only true 3D direct write nanolithographic technique it can be used to fabricate nanowire templates in a controlled manner.

  16. Improving acousto-optical interaction by high aspect ratio electrodes

    DEFF Research Database (Denmark)

    Dühring, Maria Bayard

    by conventional interdigital transducers consisting of thin electrodes deposited at the surface. In this work the finite element method is employed to investigate if the acousto-optical interaction can be enhanced by generating the SAWs by interdigital transducers consisting of high aspect ratio electrodes...... these new types of SAWs compared to using the waves generated by the conventional interdigital transducer with thin electrodes. Thus, this indicates a way to improve acousto-optical interaction for integrated modulators, which have important applications such as optical phase shifters....

  17. High aspect ratio transmission line circuits micromachined in silicon

    Science.gov (United States)

    Todd, Shane Truman

    The performance of complimentary metal-oxide-semiconductor (CMOS) monolithic microwave integrated circuits (MMICs) fabricated on silicon has improved dramatically. The scaling down of silicon transistors has increased the maximum frequency of transistors to the point where silicon MMICs have become a viable alternative to compound semiconductor MMICs in certain applications. A fundamental problem still exists in silicon MMICs however in that transmission lines fabricated on silicon can suffer from high loss due to the finite conductivity of the silicon substrate. A novel approach for creating low-loss transmission lines on silicon is presented in this work. Low-loss transmission lines are created on low resistivity silicon by using a micromachining method that combines silicon deep reactive ion etching (DRIE), thermal oxidation, electroplating, and planarization. Two types of high aspect ratio transmission lines are created with this method including high aspect ratio coplanar waveguide (hicoplanar) and semi-rectangular coaxial (semicoaxial). Transmission lines with impedances ranging from 20--80 O have been fabricated with minimum measured loss lower than 1 dB/cm at 67 GHz. Low-loss dielectrics are created for the high aspect ratio transmission lines using the mesa merging method. The mesa merging method works by creating silicon mesa arrays using DRIE and then converting and merging the mesa arrays into a solid oxide dielectric using thermal oxidation. The transmission lines are designed so that the fields penetrate the low-loss oxide dielectric and are isolated from the lossy silicon substrate. The mesa merging method has successfully created large volume oxide with depth up to 65 microm and width up to 240 microm in short oxidation times. Other advantages of the high aspect ratio transmission lines are demonstrated including low-loss over a wide impedance range, high isolation, and high coupling for coupled-line circuits. Transmission line models have been

  18. Injection molding of high aspect ratio sub-100 nm nanostructures

    DEFF Research Database (Denmark)

    Matschuk, Maria; Larsen, Niels B

    2013-01-01

    with FDTS. Reduced adhesion forces are consistent with lowered friction that reduces the risk of fracturing the nanoscopic pillars during demolding. Optimized mold surface chemistry and associated injection molding conditions permitted the fabrication of square arrays of 40 nm wide and 107 nm high (aspect......We have explored the use of mold coatings and optimized processing conditions to injection mold high aspect ratio nanostructures (height-to-width >1) in cyclic olefin copolymer (COC). Optimizing the molding parameters on uncoated nickel molds resulted in slight improvements in replication quality...

  19. Effects of finite aspect ratio on wind turbine airfoil measurements

    DEFF Research Database (Denmark)

    Kiefer, Janik; Miller, Mark A.; Hultmark, Marcus;

    2016-01-01

    Wind turbines partly operate in stalled conditions within their operational cycle. To simulate these conditions, it is also necessary to obtain 2-D airfoil data in terms of lift and drag coefficients at high angles of attack. Such data has been obtained previously, but often at low aspect ratios...... and only barely past the stall point, where strong wall boundary layer influence is expected. In this study, the influence of the wall boundary layer on 2D airfoil data, especially in the post stall domain, is investigated. Here, a wind turbine airfoil is tested at different angles of attack and with two...

  20. High Aspect-Ratio Neural Probes using Conventional Blade Dicing

    Science.gov (United States)

    Goncalves, S. B.; Ribeiro, J. F.; Silva, A. F.; Correia, J. H.

    2016-10-01

    Exploring deep neural circuits has triggered the development of long penetrating neural probes. Moreover, driven by brain displacement, the long neural probes require also a high aspect-ratio shafts design. In this paper, a simple and reproducible method of manufacturing long-shafts neural probes using blade dicing technology is presented. Results shows shafts up to 8 mm long and 200 µm wide, features competitive to the current state-of-art, being its outline simply accomplished by a single blade dicing program. Therefore, conventional blade dicing presents itself as a viable option to manufacture long neural probes.

  1. Rapid homogeneous endothelialization of high aspect ratio microvascular networks.

    Science.gov (United States)

    Naik, Nisarga; Hanjaya-Putra, Donny; Haller, Carolyn A; Allen, Mark G; Chaikof, Elliot L

    2015-08-01

    Microvascularization of an engineered tissue construct is necessary to ensure the nourishment and viability of the hosted cells. Microvascular constructs can be created by seeding the luminal surfaces of microfluidic channel arrays with endothelial cells. However, in a conventional flow-based system, the uniformity of endothelialization of such an engineered microvascular network is constrained by mass transfer of the cells through high length-to-diameter (L/D) aspect ratio microchannels. Moreover, given the inherent limitations of the initial seeding process to generate a uniform cell coating, the large surface-area-to-volume ratio of microfluidic systems demands long culture periods for the formation of confluent cellular microconduits. In this report, we describe the design of polydimethylsiloxane (PDMS) and poly(glycerol sebacate) (PGS) microvascular constructs with reentrant microchannels that facilitates rapid, spatially homogeneous endothelial cell seeding of a high L/D (2 cm/35 μm; > 550:1) aspect ratio microchannels. MEMS technology was employed for the fabrication of a monolithic, elastomeric, reentrant microvascular construct. Isotropic etching and PDMS micromolding yielded a near-cylindrical microvascular channel array. A 'stretch - seed - seal' operation was implemented for uniform incorporation of endothelial cells along the entire microvascular area of the construct yielding endothelialized microvascular networks in less than 24 h. The feasibility of this endothelialization strategy and the uniformity of cellularization were established using confocal microscope imaging.

  2. Deposition of a-C:H films on inner surface of high-aspect-ratio microchannel

    Science.gov (United States)

    Hirata, Yuki; Choi, Junho

    2016-08-01

    Hydrogenated amorphous carbon (a-C:H) films were prepared on inner surface of 100-μm-width microchannel by using a bipolar-type plasma based ion implantation and deposition. The microchannel was fabricated using a silicon plate, and two kinds of microchannels were prepared, namely, with a bottom layer (open at one end) and without a bottom layer (open at both ends). The distribution of thickness and hardness of films was evaluated by SEM and nanoindentation measurements, respectively, and the microstructures of films were evaluated by Raman spectroscopy. Furthermore, the behavior of ions and radicals was analyzed simultaneously by combining the calculation methods of Particle-In-Cell/Monte Carlo Collision and Direct Simulation Monte Carlo to investigate the coating mechanism for the microchannel. It was found that the film thickness decreased as the depth of the coating position increased in the microchannels where it is open at one end. The uniformity of the film thickness improved by increasing the negative pulse voltage because ions can arrive at the deeper part of the microchannel. In addition, the hardness increased as the depth of the coating position increased. This is because the radicals do not arrive at the deeper part of the microchannel, and the incident proportion of ions relative to that of radicals increases, resulting in a high hardness due to the amorphization of the film. The opening area of the microchannel where the aspect ratio is very small, radicals dominate the incident flux, whereas ions prevail over radicals above an aspect ratio of about 7.5. On the other hand, in the microchannels that are open at both ends, there were great improvements in uniformity of the film thickness, hardness, and the film structure. The a-C:H films were successfully deposited on the entire inner surface of a microchannel with an aspect ratio of 20.

  3. Modeling of nano-reinforced polymer composites: Microstructure effect on Young’s modulus

    DEFF Research Database (Denmark)

    Peng, R.D.; Zhou, H.W.; Wang, H.W.;

    2012-01-01

    A computational numerical-analytical model of nano-reinforced polymer composites is developed taking into account the interface and particle clustering effects. The model was employed to analyze the interrelationships between microstructures and mechanical properties of nanocomposites. An improved...

  4. Dielectric spectroscopy of high aspect ratio graphene-polyurethane nanocomposites

    Science.gov (United States)

    Jan, Rahim; Habib, Amir; Abbassi, Hina; Amir, Shahid

    2015-03-01

    High aspect ratio graphene nanosheets (GNS), prepared via liquid exfoliation, are homogeneously dispersed in thermoplastic polyurethane (TPU). Dielectric spectroscopy results are reported for these nanocomposites (up to 0.55 vol. % GNS) in the frequency range of 100 Hz to 5 MHz. The as-prepared GNS increased the AC conductivity 10-1000 times across the given frequency range. The dielectric constant is increased 5-6 times at 100 Hz for the maximum loading of GNS when compared with the pristine TPU, with subsequently high dielectric loss making them a suitable candidate for high energy dissipation applications such as EMI shielding. The temperature effects on the dielectric characteristics of 0.55 vol. % GNS/TPU nanocomposites beyond 400 K are more pronounced due to the interfacial and orientation polarization. Mechanical characteristics evaluation of GNS/TPU composites shows a marked increase in the ultimate tensile strength without compromising their ductility and stiffness. [Figure not available: see fulltext.

  5. AERODYNAMIC OPTIMIZATION DESIGN OF LOW ASPECT RATIO TRANSONIC TURBINE STAGE

    Institute of Scientific and Technical Information of China (English)

    SONG Liming; LI Jun; FENG Zhenping

    2006-01-01

    The advanced optimization method named as adaptive range differential evolution (ARDE)is developed. The optimization performance of ARDE is demonstrated using a typical mathematical test and compared with the standard genetic algorithm and differential evolution. Combined with parallel ARDE, surface modeling method and Navier-Stokes solution, a new automatic aerodynamic optimization method is presented. A low aspect ratio transonic turbine stage is optimized for the maximization of the isentropic efficiency with forty-one design variables in total. The coarse-grained parallel strategy is applied to accelerate the design process using 15 CPUs. The isentropic efficiency of the optimum design is 1.6% higher than that of the reference design. The aerodynamic performance of the optimal design is much better than that of the reference design.

  6. Vortex Interaction on Low Aspect Ratio Membrane Wings

    Science.gov (United States)

    Waldman, Rye M.; Breuer, Kenneth S.

    2013-11-01

    Inspired by the flight of bats and by recent interest in Micro Air Vehicles, we present measurements on the steady and unsteady behavior of low aspect ratio membrane wings. We conduct wind tunnel experiments with coupled force, kinematic, and flow field measurements, both on the wing and in the near wake. Membrane wings interact strongly with the vortices shed from the leading- and trailing-edges and the wing tips, and the details of the membrane support play an important role in the fluid-structure interaction. Membranes that are supported at the wing tip exhibit less membrane flutter, more coherent tip vortices, and enhanced lift. The interior wake can exhibit organized spanwise vortex shedding, and shows little influence from the tip vortex. In contrast, membranes with an unsupported wing tip show exaggerated static deformation, significant membrane fluttering and a diffuse, unsteady tip vortex. The unsteady tip vortex modifies the behavior of the interior wake, disrupting the wake coherence.

  7. Large eddy simulation of a high aspect ratio combustor

    Science.gov (United States)

    Kirtas, Mehmet

    The present research investigates the details of mixture preparation and combustion in a two-stroke, small-scale research engine with a numerical methodology based on large eddy simulation (LES) technique. A major motivation to study such small-scale engines is their potential use in applications requiring portable power sources with high power density. The investigated research engine has a rectangular planform with a thickness very close to quenching limits of typical hydrocarbon fuels. As such, the combustor has a high aspect ratio (defined as the ratio of surface area to volume) that makes it different than the conventional engines which typically have small aspect ratios to avoid intense heat losses from the combustor in the bulk flame propagation period. In most other aspects, this engine involves all the main characteristics of traditional reciprocating engines. A previous experimental work has identified some major design problems and demonstrated the feasibility of cyclic combustion in the high aspect ratio combustor. Because of the difficulty of carrying out experimental studies in such small devices, resolving all flow structures and completely characterizing the flame propagation have been an enormously challenging task. The numerical methodology developed in this work attempts to complement these previous studies by providing a complete evolution of flow variables. Results of the present study demonstrated strengths of the proposed methodology in revealing physical processes occuring in a typical operation of the high aspect ratio combustor. For example, in the scavenging phase, the dominant flow structure is a tumble vortex that forms due to the high velocity reactant jet (premixed) interacting with the walls of the combustor. Since the scavenging phase is a long process (about three quarters of the whole cycle), the impact of the vortex is substantial on mixture preparation for the next combustion phase. LES gives the complete evolution of this flow

  8. All Metal Iron Core For A Low Aspect Ratio Tokamak

    Energy Technology Data Exchange (ETDEWEB)

    D.A. Gates, C. Jun, I. Zatz, A. Zolfaghari

    2010-06-02

    A novel concept for incorporating a iron core transformer within a axisymmetric toroidal plasma containment device with a high neutron flux is described. This design enables conceptual design of low aspect ratio devices which employ standard transformer-driven plasma startup by using all-metal high resistance separators between the toroidal field windings. This design avoids the inherent problems of a multiturn air core transformer which will inevitably suffer from strong neutron bombardment and hence lose the integrity of its insulation, both through long term material degradation and short term neutron- induced conductivity.. A full 3-dimensional model of the concept has been developed within the MAXWELL program and the resultant loop voltage calculated. The utility of the result is found to be dependent on the resistivity of the high resistance separators. Useful loop voltage time histories have been obtained using achievable resistivities.

  9. Noise Measurements of High Aspect Ratio Distributed Exhaust Systems

    Science.gov (United States)

    Bridges, James E.

    2015-01-01

    This paper covers far-field acoustic measurements of a family of rectangular nozzles with aspect ratio 8, in the high subsonic flow regime. Several variations of nozzle geometry, commonly found in embedded exhaust systems, are explored, including bevels, slants, single broad chevrons and notches, and internal septae. Far-field acoustic results, presented previously for the simple rectangular nozzle, showed that increasing aspect ratio increases the high frequency noise, especially directed in the plane containing the minor axis of the nozzle. Detailed changes to the nozzle geometry generally made little difference in the noise, and the differences were greatest at low speed. Having an extended lip on one broad side (bevel) did produce up to 3 decibels more noise in all directions, while extending the lip on the narrow side (slant) produced up to 2 decibels more noise, primarily on the side with the extension. Adding a single, non-intrusive chevron, made no significant change to the noise, while inverting the chevron (notch) produced up to 2decibels increase in the noise. Having internal walls (septae) within the nozzle, such as would be required for structural support or when multiple fan ducts are aggregated, reduced the noise of the rectangular jet, but could produce a highly directional shedding tone from the septae trailing edges. Finally, a nozzle with both septae and a beveled nozzle, representative of the exhaust system envisioned for a distributed electric propulsion aircraft with a common rectangular duct, produced almost as much noise as the beveled nozzle, with the septae not contributing much reduction in noise.

  10. Photoimageable Polyimide: A Dielectric Material For High Aspect Ratio Structures

    Science.gov (United States)

    Cech, Jay M.; Oprysko, Modest M.; Young, Peter L.; Li, Kin

    1986-07-01

    Polyimide has been identified as a useful material for microelectronic packaging because of its low dielectric constant and high temperature stability. Difficulties involved with reactive ion etching (RIE), a conventional technique for patterning thick polyimide films (thickness greater than 5 microns) with vertical walls, can be overcome by using photimageable polyimide precursors. The processing steps are similar to those used with negative photoresists. EM Chemical's HTR-3 photosensitive polyimide has been spun on up to a thickness of 12 microns. Exposure with a dose of 780 mJcm-2 of ultraviolet light, followed by spin development produces clean patterns as small as 5 microns corresponding to an aspect ratio of 2.4. When the patterned precursor is heated, an imidization reaction occurs converting the patterned film to polyimide. Baking to ca. 400 degrees C results in substantial loss in the thickness and in line width. However, shrinkage occurs reproducibly so useful rules for mask design can be formulated. Near vertical wall structures can be fabricated by taking advantage of the optical and shrinkage properties of the polyimide precursor. After development, an undercut wall profile can be produced since the bottom of the film receives less exposure and is hence more soluble in the developer. During heating, lateral shrinkage pulls the top of the film inward producing a vertical wall since the bottom is fixed to the substrate by adhesion. As a result, fully cured polyimide structures with straight walls and aspect ratios greater than one can be obtained. Dielectric properties of the fully imidized films were investigated with capacitor test structures. A relative dielectric constant of 3.3 and a loss tangent of .002 were measured at 20 kHz. It was also found that the dielectric constant increases as a linear function of relative humidity.

  11. Geometry Control of Photo-induced Microstructures in an Azobenzene Polymer Film

    Institute of Scientific and Technical Information of China (English)

    Xu Ze-Da; LI Zhen; LIANG Li-Zhen; PENG Zhuo-Lun; CAI Zhi-Gang; ZHOU Jian-Ying; NINULESCU Valerica; ZHANG Ling-Zhi

    2001-01-01

    The mechanisms of photo-induced microstructures in an azobenzene polymer film are presented. They are based on the spatial periodic modulation of optical intensity and the photoisomerization of azobenzene molecules with the movement of main chains. Experiment and theory jointly point out the possibility of photo-inducing desired spatial microstructures in an azobenzene organic polymer via adequate optical lattices and adequately polarized ‘writing' beams.

  12. Connectorization of fibre Bragg grating sensors recorded in microstructured polymer optical fibre

    DEFF Research Database (Denmark)

    Abang, A.; Saez-Rodriguez, D.; Nielsen, Kristian

    2013-01-01

    We describe te production and characterization of FC/PC connectorised fibre Bragg grating sensors in polymer fibre. Sensors were recorded in few-moded and single mode microstructured fibre composed of poly (methyl methacrylate).......We describe te production and characterization of FC/PC connectorised fibre Bragg grating sensors in polymer fibre. Sensors were recorded in few-moded and single mode microstructured fibre composed of poly (methyl methacrylate)....

  13. Direct Writing of Fiber Bragg Grating in Microstructured Polymer Optical Fiber

    DEFF Research Database (Denmark)

    Stefani, Alessio; Stecher, Matthias; Town, G. E.

    2012-01-01

    We report point-by-point laser direct writing of a 1520-nm fiber Bragg grating in a microstructured polymer optical fiber (mPOF). The mPOF is specially designed such that the microstructure does not obstruct the writing beam when properly aligned. A fourth-order grating is inscribed in the m...

  14. Photodeposition Method For Fabricating A Three-Dimensional, Patterned Polymer Microstructure

    Energy Technology Data Exchange (ETDEWEB)

    Walt, David R. (Lexington, MA); Healey, Brian G. (Sommerville, MA)

    2001-03-13

    The present invention is a photodeposition methodology for fabricating a three-dimensional patterned polymer microstructure. A variety of polymeric structures can be fabricated on solid substrates using unitary fiber optic arrays for light delivery. The methodology allows micrometer-scale photopatterning for the fabricated structures using masks substantially larger than the desired dimensions of the microstructure.

  15. Guiding mode in elliptical core microstructured polymer optical fiber

    Institute of Scientific and Technical Information of China (English)

    Yani Zhang; Liyong Ren; Kang Li; Hanyi Wang; Wei Zhao; Lili Wang; Runcai Miao; Maryanne C. J. Large; Martijn A. van Eijkelenborg

    2007-01-01

    A kind of microstructured polymer optical fiber with elliptical core has been fabricated by adopting insitu chemical polymerization technology and the secondary sleeving draw-stretching technique. Microscope photography demonstrates the clear hole-structure retained in the fiber. Though the holes distortion is visible, initial laser experiment indicates that light can be strongly confined in the elliptical core region,and the mode field is split obviously and presents the multi-mode characteristic. Numerical modeling is carried out for the real fiber with the measured parameters, including the external diameter of 150μm, the average holes diameter of 3.3μm, and the averageole spacing of .3μm by using full-vector plane wave method. The guided mode fields of the numerical simulation are consistent with the experiment result.This fiber shows the strong multi-mode and weak birefringence in the visible and near-infrared band, and has possibility for achieving the fiber mode convertors, mode selective couplers and so on.

  16. Guiding mode in elliptical core microstructured polymer optical fiber

    Science.gov (United States)

    Zhang, Yani; Ren, Liyong; Li, Kang; Wang, Hanyi; Zhao, Wei; Wang, Lili; Miao, Runcai; Large, Maryanne C. J.; van Eijkelenborg, Martijn A.

    2007-04-01

    A kind of microstructured polymer optical fiber with elliptical core has been fabricated by adopting in-situ chemical polymerization technology and the secondary sleeving draw-stretching technique. Microscope photography demonstrates the clear hole-structure retained in the fiber. Though the holes distortion is visible, initial laser experiment indicates that light can be strongly confined in the elliptical core region, and the mode field is split obviously and presents the multi-mode characteristic. Numerical modeling is carried out for the real fiber with the measured parameters, including the external diameter of 150 microns, the average holes diameter of 3.3 microns, and the average hole spacing of 6.3 microns by using full-vector plane wave method. The guided mode fields of the numerical simulation are consistent with the experiment result. This fiber shows the strong multi-mode and weak birefringence in the visible and near-infrared band, and has possibility for achieving the fiber mode convertors, mode selective couplers and so on.

  17. Microstructured polymer optical fibre sensors for opto-acoustic endoscopy

    Science.gov (United States)

    Broadway, Christian; Gallego, Daniel; Pospori, Andreas; Zubel, Michal; Webb, David J.; Sugden, Kate; Carpintero, Guillermo; Lamela, Horacio

    2016-04-01

    Opto-acoustic imaging is a growing field of research in recent years, providing functional imaging of physiological biomarkers, such as the oxygenation of haemoglobin. Piezo electric transducers are the industry standard detector for ultrasonics, but their limited bandwidth, susceptibility to electromagnetic interference and their inversely proportional sensitivity to size all affect the detector performance. Sensors based on polymer optical fibres (POF) are immune to electromagnetic interference, have lower acoustic impedance and a reduced Young's Modulus compared to silica fibres. Furthermore, POF enables the possibility of a wideband sensor and a size appropriate to endoscopy. Micro-structured POF (mPOF) used in an interferometric detector has been shown to be an order of magnitude more sensitive than silica fibre at 1 MHz and 3 times more sensitive at 10 MHz. We present the first opto-acoustic measurements obtained using a 4.7mm PMMA mPOF Bragg grating with a fibre diameter of 130 μm and present the lateral directivity pattern of a PMMA mPOF FBG ultrasound sensor over a frequency range of 1-50 MHz. We discuss the impact of the pattern with respect to the targeted application and draw conclusions on how to mitigate the problems encountered.

  18. Designing microstructured polymer optical fibers for cascaded quadratic soliton compression of femtosecond pulses

    DEFF Research Database (Denmark)

    Bache, Morten

    2009-01-01

    The dispersion of index-guiding microstructured polymer optical fibers is calculated for second-harmonic generation. The quadratic nonlinearity is assumed to come from poling of the polymer, which in this study is chosen to be the cyclic olefin copolymer Topas. We found a very large phase mismatch...

  19. Overview of the Pegasus Extremely Low-Aspect Ratio Tokamak

    Science.gov (United States)

    Fonck, R.; Garstka, G.; Intrator, T.; Lewicki, B.; Thorson, T.; Toonen, R.; Tritz, K. L.; White, B.; Winz, G.

    1996-11-01

    Pegasus is a new experiment designed to explore the potential of Extremely Low Aspect Ratio Tokamaks (ELART) at very high toroidal β. Ohmic induction for plasma startup will be followed by ohmic sustainment initially and noninductive RF current drive in the future. Plasma parameters are projected to be Ip ≈ 5-40 % or higher, A=1.1-2, R=0.2-0.4 m, and P_RF <= 2MW. Goals of the program include: demonstrate high-β spherical tokamak operation in the near term; examine the stability, n=0 stability properties at high elongation and low- A, confinement and scaling characteristics at A <= 1.25; and extend high power ST operation to the extrema of A <= 1.1. Hollow current profiles should be accessible in Pegasus using a fast current ramp during formation plus off-axis FWCD in the longer term. Recent changes to the design include: increased vacuum vessel height to allow for divertor operation with an internal X-point plus increased accessible elongations (i.,e., κ <= 3.7 at A = 1.25); additional coils for X-point control; and elimination of toroidal gaps in favor of a resistive vacuum vessel. Initial operation will emphasize ohmic access to high- β, followed by high power RF heating.

  20. Aspect Ratio Effects in the Driven, Flux-Core Spheromak

    Energy Technology Data Exchange (ETDEWEB)

    Hooper, E B; Romero-Talam?s, C A; LoDestro, L L; Wood, R D; McLean, H S

    2009-03-02

    Resistive magneto-hydrodynamic simulations are used to evaluate the effects of the aspect ratio, A (length to radius ratio) in a spheromak driven by coaxial helicity injection. The simulations are benchmarked against the Sustained Spheromak Physics Experiment (SSPX) [R. D. Wood, et al., Nucl. Nucl. Fusion 45, 1582 (2005)]. Amplification of the bias ('gun') poloidal flux is fit well by a linear dependence (insensitive to A) on the ratio of gun current and bias flux above a threshold dependent on A. For low flux amplifications in the simulations the n = 1 mode is coherent and the mean-field geometry looks like a tilted spheromak. Because the mode has relatively large amplitude the field lines are open everywhere, allowing helicity penetration. Strongly-driven helicity injection at A {le} 1.4 in simulations generates reconnection events which open the magnetic field lines; this state is characteristic of SSPX. Near the spheromak tilt-mode limit, A {approx} 1.67 for a cylindrical flux conserver, the tilt approaches 90{sup o}; reconnection events are not generated up to the strongest drives simulated. The time-sequence of these events suggests that they are representative of a chaotic process. Implications for spheromak experiments are discussed.

  1. A new multifunctional platform based on high aspect ratio interdigitated NEMS structures

    Energy Technology Data Exchange (ETDEWEB)

    Ghatnekar-Nilsson, S; Karlsson, I; Kvennefors, A; Luo, G; Zela, V; Parker, T; Litwin, A [NEMS AB, Solvegatan 16, S-223 62 Lund (Sweden); Arlelid, M [Electrical and Information Technology, Lund University, PO Box 118, S-221 00 Lund (Sweden); Montelius, L [Solid State Physics/The Nanometer Structure Consortium, Lund University, PO Box 118, S-221 00 Lund (Sweden)], E-mail: andrej.litwin@nems.se

    2009-04-29

    A multifunctional NEMS platform based on a mass-producible, surface relief grating has been developed and fabricated directly in polymer materials. The pattern consists of high aspect ratio interdigitated nanometer-sized pairs of walls and can be produced in a low-complexity one-step patterning process with nanoimprint lithography. In this paper, we demonstrate the usefulness of the platform primarily by showing an application as a high-sensitivity mass sensor in air. The sensors, which are based on the high frequency resonant response of around 200 MHz, show a mass responsivity of the order of 0.1 Hz/zg per wall at room temperature and in ambient air. Their ability to selectively adsorb airborne target molecules, such as thiols, is also demonstrated. We also show that the same device can function as a varactor for electronic circuits based on its large tunable capacitive range.

  2. A new multifunctional platform based on high aspect ratio interdigitated NEMS structures.

    Science.gov (United States)

    Ghatnekar-Nilsson, S; Karlsson, I; Kvennefors, A; Luo, G; Zela, V; Arlelid, M; Parker, T; Montelius, L; Litwin, A

    2009-04-29

    A multifunctional NEMS platform based on a mass-producible, surface relief grating has been developed and fabricated directly in polymer materials. The pattern consists of high aspect ratio interdigitated nanometer-sized pairs of walls and can be produced in a low-complexity one-step patterning process with nanoimprint lithography. In this paper, we demonstrate the usefulness of the platform primarily by showing an application as a high-sensitivity mass sensor in air. The sensors, which are based on the high frequency resonant response of around 200 MHz, show a mass responsivity of the order of 0.1 Hz/zg per wall at room temperature and in ambient air. Their ability to selectively adsorb airborne target molecules, such as thiols, is also demonstrated. We also show that the same device can function as a varactor for electronic circuits based on its large tunable capacitive range.

  3. The Aneutronic Rodless Ultra Low Aspect Ratio Tokamak

    Science.gov (United States)

    Ribeiro, Celso

    2016-10-01

    The replacement of the metal centre-post in spherical tokamaks (STs) by a plasma centre-post (PCP, the TF current carrier) is the ideal scenario for a ST reactor. A simple rodless ultra low aspect-ratio tokamak (RULART) using a screw-pinch PCP ECR-assisted with an external solenoid has been proposed in the most compact RULART [Ribeiro C, SOFE-15]. There the solenoid provided the stabilizing field for the PCP and the toroidal electrical field for the tokamak start-up, which will stabilize further the PCP, acting as stabilizing closed conducting surface. Relative low TF will be required. The compactness (high ratio of plasma-spherical vessel volume) may provide passive stabilization and easier access to L-H mode transition. It is presented here: 1) stability analysis of the PCP (initially MHD stable due to the hollow J profile); 2) tokamak equilibrium simulations, and 3) potential use for aneutronic reactions studies via pairs of proton p and boron 11B ion beams in He plasmas. The beams' line-of-sights sufficiently miss the sources of each other, thus allowing a near maximum relative velocities and reactivity. The reactions should occur close to the PCP mid-plane. Some born alphas should cross the PCP and be dragged by the ion flow (higher momentum exchange) towards the anode but escape directly to a direct electricity converter. Others will reach evenly the vessel directly or via thermal diffusion (favourable heating by the large excursion 2a), leading to the lowest power wall load possible. This might be a potential hybrid direct-steam cycle conversion reactor scheme, nearly aneutronic, and with no ash or particle retention problems, as opposed to the D-T thermal reaction proposals.

  4. Numerical Study of the Effect of the Sample Aspect Ratio on the Ductility of Bulk Metallic Glasses (BMGs) Under Compression

    Science.gov (United States)

    Jiang, Yunpeng

    2016-05-01

    In this article, a systematic numerical study was conducted to study the detailed shear banding evolution in bulk metallic glasses (BMGs) with various sample aspect ratios under uniaxial compression, and whereby the effect of the sample aspect ratio on the compressive ductility was elucidated. A finite strain viscoelastic model was employed to describe the shear banding nucleation, growth, and coalescence in BMG samples with the help of Anand and Su's theory, which was incorporated into the ABAQUS finite element method code as a user material subroutine VUMAT. The present numerical method was first verified by comparing with the corresponding experimental results, and then parameter analysis was performed to discuss the impact of microstructure parameters on the predicted results. The present modeling will shed some light on enhancing the toughness of BMG structures in the engineering applications.

  5. Photoablation characteristics of novel polyimides synthesized for high-aspect-ratio excimer laser LIGA process

    Science.gov (United States)

    Yang, Chii-Rong; Hsieh, Yu-Sheng; Hwang, Guang-Yeu; Lee, Yu-Der

    2004-04-01

    The photoablation properties of two soluble polyimides DMDB/6FDA and OT/6FDA with thicknesses of over 300 µm, synthesized by the polycondensation of a hexafluoropropyl group contained in a dianhydride with two kinds of diamines, are investigated using a 248 nm krypton fluoride (KrF) laser. The incorporation of the hexafluoropropyl group into the chemical structure gives these two polyimides higher etching rates than Kapton (a commercial polyimide film which is difficult to dissolve). The etching rates of synthesized polyimides are about 0.1-0.5 µm/pulse over a fluence range of 0.25-2.25 J cm-2. The photothermal mechanism for DMDB/6FDA contributes about 19% of etching depth at a laser fluence of 0.82 J cm-2. Moreover, the number of laser pulses seriously affects the taper angle of microstructures, especially at low fluence. Near-vertical side-wall structures can be built at high fluence (~2 J cm-2). Fresnel patterns with a thickness of 300 µm and a linewidth of 10 µm were fabricated, with an attainable aspect ratio of around 30. After photoablation, the complementary metallic microstructures were also fabricated by a sequential electroplating procedure. Then, those two new polyimides could be dissolved easily in most common solvents (such as THF, DMSO, NMP and DMF). These results indicate that these two soluble polyimides are highly suitable for use in the KrF laser LIGA process.

  6. Different methods to alter surface morphology of high aspect ratio structures

    Science.gov (United States)

    Leber, M.; Shandhi, M. M. H.; Hogan, A.; Solzbacher, F.; Bhandari, R.; Negi, S.

    2016-03-01

    In various applications such as neural prostheses or solar cells, there is a need to alter the surface morphology of high aspect ratio structures so that the real surface area is greater than geometrical area. The change in surface morphology enhances the devices functionality. One of the applications of altering the surface morphology is of neural implants such as the Utah electrode array (UEA) that communicate with single neurons by charge injection induced stimulation or by recording electrical neural signals. For high selectivity between single cells of the nervous system, the electrode surface area is required to be as small as possible, while the impedance is required to be as low as possible for good signal to noise ratios (SNR) during neural recording. For stimulation, high charge injection and charge transfer capacities of the electrodes are required, which increase with the electrode surface. Traditionally, researchers have worked with either increasing the roughness of the existing metallization (platinum grey, black) or other materials such as Iridium Oxide and PEDOT. All of these previously investigated methods lead to more complicated metal deposition processes that are difficult to control and often have a critical impact on the mechanical properties of the metal films. Therefore, a modification of the surface underneath the electrode's coating will increase its surface area while maintaining the standard and well controlled metal deposition process. In this work, the surfaces of the silicon micro-needles were engineered by creating a defined microstructure on the electrodes surface using several methods such as laser ablation, focused ion beam, sputter etching, reactive ion etching (RIE) and deep reactive ion etching (DRIE). The surface modification processes were optimized for the high aspect ratio silicon structures of the UEA. The increase in real surface area while maintaining the geometrical surface area was verified using scanning electron

  7. Downsizing of single crystalline high aspect ratio tungsten nanowires

    Energy Technology Data Exchange (ETDEWEB)

    Milenkovic, Srdjan [IMDEA Materials Institute, Eric Kandel 2, 28906, Getafe (Spain); Drensler, Stefanie [Institute for Chemical Technology of Inorganic Materials, Johannes Kepler University, Altenberger Str. 69, 4040, Linz (Austria); Hassel, Achim Walter [Institute for Chemical Technology of Inorganic Materials, Johannes Kepler University, Altenberger Str. 69, 4040, Linz (Austria); Christian Doppler Laboratory for Combinatorial Oxide Chemistry, Institute for Chemical Technology of Inorganic Materials, Johannes Kepler University Linz, Altenberger Str. 69, 4040, Linz (Austria)

    2015-06-15

    Directional solidification of eutectic NiAl-W alloys offers an intuitive method to produce tungsten nanowires. Through the use of two different methods, the well-established Bridgman method and a newer type floating zone method, the direct influence of process parameters, like the withdrawal rate and the temperature gradient, onto the sample microstructure were studied. The sharp temperature gradient, built up using a four mirror system focusing the light emitted by halogen lamps inside the optical floating zone furnace allows producing nanowires with a diameter as small as 75 nm. Differences in the solid/liquid interface morphology depending on the solidification method used are discussed. (copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  8. Fabrication of 2D protein microstructures and 3D polymer-protein hybrid microstructures by two-photon polymerization

    Energy Technology Data Exchange (ETDEWEB)

    Engelhardt, Sascha [Lehrstuhl fuer Lasertechnik, RWTH Aachen, Steinbachstrasse 15, Aachen (Germany); Hoch, Eva; Tovar, Guenter E M [Institut fuer Grenzflaechenverfahrenstechnik, Universitaet Stuttgart, Nobelstrasse 12, Stuttgart (Germany); Borchers, Kirsten [Fraunhofer-Institut fuer Grenzflaechen- und Bioverfahrenstechnik, Nobelstrasse 12, Stuttgart (Germany); Meyer, Wolfdietrich; Krueger, Hartmut [Fraunhofer-Institut fuer Angewandte Polymerforschung, Geiselbergstrasse 69, Potsdam (Germany); Gillner, Arnold, E-mail: sascha.engelhardt@ilt.fraunhofer.de [Fraunhofer-Institut fuer Lasertechnik, Steinbachstrasse 15, Aachen (Germany)

    2011-06-15

    Two-photon polymerization (TPP) offers the possibility of creating artificial cell scaffolds composed of micro- and nanostructures with spatial resolutions of less than 1 {mu}m. For use in tissue engineering, the identification of a TPP-processable polymer that provides biocompatibility, biofunctionality and appropriate mechanical properties is a difficult task. ECM proteins such as collagen or fibronectin, which could mimic native tissues best, often lack the mechanical stability. Hence, by generating polymer-protein hybrid structures, the beneficial properties of proteins can be combined with the advantageous characteristics of polymers, such as sufficient mechanical stability. This study describes three steps toward facilitated application of TPP for biomaterial generation. (1) The efficiency of a low-cost ps-laser source is compared to a fs-laser source by testing several materials. A novel photoinitiator for polymerization with a ps-laser source is synthesized and proved to enable increased fabrication throughput. (2) The fabrication of 3D-microstructures with both systems and the fabrication of polymer-protein hybrid structures are demonstrated. (3) The tissue engineering capabilities of TPP are demonstrated by creating cross-linked gelatin microstructures, which clearly forced porcine chondrocytes to adapt their cell morphology.

  9. Control of multiphoton process within diffraction limit space in polymer microstructures

    Energy Technology Data Exchange (ETDEWEB)

    Nakahama, Tatsuo [National Institute of Information and Communications Technology 588-2, Iwaoka, Nishi-ku, Kobe 651-2492 (Japan); Yokoyama, Shiyoshi [National Institute of Information and Communications Technology 588-2, Iwaoka, Nishi-ku, Kobe 651-2492 (Japan)]. E-mail: syoko@nict.go.jp; Miki, Hideki [National Institute of Information and Communications Technology 588-2, Iwaoka, Nishi-ku, Kobe 651-2492 (Japan); Mashiko, Shinro [National Institute of Information and Communications Technology 588-2, Iwaoka, Nishi-ku, Kobe 651-2492 (Japan)

    2006-03-21

    Femtosecond laser pulses were used for laser fabrication using two-photon-absorption. By imaging microstructures during laser fabrication, we precisely controlled the sizes and positions of optical functions in the microstructures. We fabricated a two-dimensional periodic array of polymer microstructures using two-photon-induced photopolymerization, and developed a technique of recording optical data with a spatial resolution of less than 1 {mu}m in three-dimensions. This optical recording was achieved by using a femtosecond laser with near-infrared wavelength to induce two-photon photodegradation of fluorescent chromophores.

  10. Microstructure-mobility correlation in self-organised, conjugated polymer field-effect transistors

    DEFF Research Database (Denmark)

    Sirringhaus, H.; Brown, P.J.; Friend, R.H.

    2000-01-01

    We have investigated the correlation between polymer microstructure and charge carrier mobility in high-mobility, self-organised field-effect transistors of poly-3-hexyl-thiophene (P3HT). Two different preferential orientations of the microcrystalline P3HT domains with respect to the substrate have...... the charge transport properties of conjugated polymer field-effect devices. (C) 2000 Elsevier Science S.A. All rights reserved....

  11. π-Donors microstructuring on surface of polymer film by their noncovalent interactions with iodine

    Energy Technology Data Exchange (ETDEWEB)

    Traven, Valerii F., E-mail: valerii.traven@gmail.com [Mendeleev University of Chemical Technology, Moscow 125047, Miusskaya sq., 9 (Russian Federation); Ivanov, Ivan V.; Dolotov, Sergei M. [Mendeleev University of Chemical Technology, Moscow 125047, Miusskaya sq., 9 (Russian Federation); Veciana, Jaume Miro; Lebedev, Victor S. [Institut de Ciencia de Materials de Barcelona–CSIC, Campus de la UAB, 08193, Bellaterra (Spain); Shulga, Yurii M.; Khasanov, Salavat S. [Institute of Problems of Chemical Physics, Russian Academy of Sciences, Acad. N.N. Semenov Prosp., 1, Chernogolovka, 142432 (Russian Federation); Medvedev, Michael G. [A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 119991, Vavilova str., 28 (Russian Federation); Laukhina, Elena E. [The Biomedical Research Networking Center in Bioengineering, Biomaterials and Nanomedicine, ICMAB-CSIC, Bellaterra, 08193 (Spain)

    2015-06-15

    Noncovalent (charge transfer) interaction between perylene and iodine in polycarbonate film provides formation of microstructured perylene layer on the polymer surface upon exposure of polymer film which contains dissolved perylene to solvent + iodine vapors. The prepared bilayer film possesses a sensing effect to iodine vapors which can be observed by both fluorescence and electrical conductivity changes. Similar bilayer films have been prepared also with anthracene and phenothiazine as π-donors with use of different polymer matrixes. Interaction of iodine with polycyclic aromatic hydrocarbons (PAH) has also been studied by the M06-2x DFT calculations for better understanding of phenomenon of π-donors microstructuring on surface of polymer film. - Highlights: • Preparation of bilayer polymer films with π-donors on surface for the first time. • π-Donor phase purity is confirmed by XRD, IR spectroscopy, SEM. • Perylene bilayer polymer films possess fluorescence. • Perylene bilayer polymer films loss fluorescence under iodine vapors. • Perylene bilayer polymer films possess electrical conductivity when treated by iodine vapors.

  12. MEMS acoustic emission transducers designed with high aspect ratio geometry

    Science.gov (United States)

    Saboonchi, H.; Ozevin, D.

    2013-09-01

    In this paper, micro-electro-mechanic systems (MEMS) acoustic emission (AE) transducers are manufactured using an electroplating technique. The transducers use a capacitance change as their transduction principle, and are tuned to the range 50-200 kHz. Through the electroplating technique, a thick metal layer (20 μm nickel + 0.5 μm gold) is used to form a freely moving microstructure layer. The presence of the gold layer reduces the potential corrosion of the nickel layer. A dielectric layer is deposited between the two electrodes, thus preventing the stiction phenomenon. The transducers have a measured quality factor in the range 15-30 at atmospheric pressure and are functional without vacuum packaging. The transducers are characterized using electrical and mechanical tests to identify the capacitance, resonance frequency and damping. Ultrasonic wave generation using a Q-switched laser shows the directivity of the transducer sensitivity. The comparison of the MEMS transducers with similar frequency piezoelectric transducers shows that the MEMS AE transducers have better response characteristics and sensitivity at the resonance frequency and well-defined waveform signatures (rise time and decay time) due to pure resonance behavior in the out-of-plane direction. The transducers are sensitive to a unique wave direction, which can be utilized to increase the accuracy of source localization by selecting the correct wave velocity at the structures.

  13. 870nm Bragg grating in single mode TOPAS microstructured polymer optical fibre

    DEFF Research Database (Denmark)

    Yuan, Wu; Webb, David J.; Kalli, Kyriacos;

    2011-01-01

    We report the fabrication and characterization of a fiber Bragg grating (FBG) with 870 nm resonance wavelength in a single-mode TOPAS microstructured polymer optical fiber (mPOF). The grating has been UV-written with the phase-mask technique using a 325 nm HeCd laser. The static tensile strain se...

  14. Label-free biosensing with high sensitivity in dual-core microstructured polymer optical fibers

    DEFF Research Database (Denmark)

    Markos, Christos; Yuan, Wu; Vlachos, Kyriakos

    2011-01-01

    We present experimentally feasible designs of a dual-core microstructured polymer optical fiber (mPOF), which can act as a highly sensitive, label-free, and selective biosensor. An immobilized antigen sensing layer on the walls of the holes in the mPOF provides the ability to selectively capture...

  15. Highly photosensitive polymethyl methacrylate microstructured polymer optical fiber with doped core

    DEFF Research Database (Denmark)

    Sáez-Rodríguez, D.; Nielsen, Kristian; Rasmussen, Henrik K.

    2013-01-01

    In this Letter, we report the fabrication of a highly photosensitive, microstructured polymer optical fiber using benzyl dimethyl ketal as a dopant, as well as the inscription of a fiber Bragg grating in the fiber. A refractive index change in the core of at least 3.2×10−4 has been achieved...

  16. Zeonex-PMMA microstructured polymer optical FBGs for simultaneous humidity and temperature sensing

    DEFF Research Database (Denmark)

    Woyessa, Getinet; Pedersen, Jens Kristian Mølgaard; Fasano, Andrea

    2017-01-01

    In this Letter, we report for the first time, to the best of our knowledge, the fabrication and characterization of a Zeonex/PMMA microstructured polymer optical fiber (mPOF) Bragg grating sensor for simultaneous monitoring of relative humidity (RH) and temperature. The sensing element (probe...

  17. A study on the microstructural parameters of 550 keV electron irradiated Lexan polymer films

    Energy Technology Data Exchange (ETDEWEB)

    Hareesh, K.; Pramod, R.; Petwal, V. C.; Dwivedi, Jishnu; Sangappa; Sanjeev, Ganesh [Microtron Centre, Department of Physics, Mangalore University, Mangalagangotri-574199 (India); PSIA Division, Raja Rammana Centre for Advanced Technology, Indore-452013 (India); Department of Physics, Mangalore University, Mangalagangotri-574199 (India); Microtron Centre, Department of Physics, Mangalore University, Mangalagangotri-574199 (India)

    2012-06-05

    Lexan polymer films irradiated with 550 keV Electron Beam (EB) were characterized using Wide Angle Xray Scattering (WAXS) data to study the microstructural parameters. The crystal imperfection parameters like crystal size , lattice strain (g in %) and enthalpy ({alpha}) have been determined by Line Profile Analysis (LPA) using Fourier method of Warren.

  18. Unified model for the electromechanical coupling factor of orthorhombic piezoelectric rectangular bar with arbitrary aspect ratio

    Directory of Open Access Journals (Sweden)

    R. Rouffaud

    2017-02-01

    Full Text Available Piezoelectric Single Crystals (PSC are increasingly used in the manufacture of ultrasonic transducers and in particular for linear arrays or single element transducers. Among these PSCs, according to their microstructure and poled direction, some exhibit a mm2 symmetry. The analytical expression of the electromechanical coupling coefficient for a vibration mode along the poling direction for piezoelectric rectangular bar resonator is established. It is based on the mode coupling theory and fundamental energy ratio definition of electromechanical coupling coefficients. This unified formula for mm2 symmetry class material is obtained as a function of an aspect ratio (G where the two extreme cases correspond to a thin plate (with a vibration mode characterized by the thickness coupling factor, kt and a thin bar (characterized by k33′. To optimize the k33′ value related to the thin bar design, a rotation of the crystallogaphic axis in the plane orthogonal to the poling direction is done to choose the highest value for PIN-PMN-PT single crystal. Finally, finite element calculations are performed to deduce resonance frequencies and coupling coefficients in a large range of G value to confirm developed analytical relations.

  19. Research in manufacturing of micro-structured injection molded polymer parts

    Science.gov (United States)

    Lucyshyn, Thomas; Struklec, Tobias; Burgsteiner, Martin; Graninger, Georg; Holzer, Clemens

    2015-12-01

    An overview of current research results is given for the topic of injection molding of micro-structured polymer parts regarding filling behavior and demolding process of micro-structures as well as the production of micro-structures on curved surfaces. In order to better understand how micro-structures are formed during the filling stage of injection molding, a study was performed on a test part with micro-channels placed parallely and perpendicularly to flow direction. Short shots with a highly fluent Polypropylene grade were injection molded with the melt front stopping in the structure fields. The melt and mold temperature, the injection rate as well as the use of a variotherm heating system were varied in a systematic Design of Experiments. The shape of the flow front was investigated with the optical measurement system Alicona InfiniteFocus. The data gained was analyzed with Matlab scripts and provided the needed distance to completely fill the structures as a reference value. The next topic covers the demolding step, which is a crucial process step in injection molding of micro-structured parts as the successfully replicated structures often get destroyed in the following demolding step. In order to evaluate the influence of the four aspects polymer, mold surface (coatings), structure (geometry and placement) and process settings on the demolding behavior, an injection mold with integrated measurement system was built, which makes it possible to measure the demolding force respectively a demolding energy under process conditions. These values can be used to quantitatively compare the impact of the above mentioned influencing factors on demolding. Finally, a concept to produce micro-structures on curved surfaces with injection molding is shown: A flat metal premaster structure is used to produce an elastomeric polymer (dimethylsiloxane) master in a casting process. This master is fixed in a conventional injection mold and a thermoplastic polymer is replicated

  20. 3D fabrication of all-polymer conductive microstructures by two photon polymerization.

    Science.gov (United States)

    Kurselis, Kestutis; Kiyan, Roman; Bagratashvili, Victor N; Popov, Vladimir K; Chichkov, Boris N

    2013-12-16

    A technique to fabricate electrically conductive all-polymer 3D microstructures is reported. Superior conductivity, high spatial resolution and three-dimensionality are achieved by successive application of two-photon polymerization and in situ oxidative polymerization to a bi-component formulation, containing a photosensitive host matrix and an intrinsically conductive polymer precursor. By using polyethylene glycol diacrylate (PEG-DA) and 3,4-ethylenedioxythiophene (EDOT), the conductivity of 0.04 S/cm is reached, which is the highest value for the two-photon polymerized all-polymer microstructures to date. The measured electrical conductivity dependency on the EDOT concentration indicates percolation phenomenon and a three-dimensional nature of the conductive pathways. Tunable conductivity, biocompatibility, and environmental stability are the characteristics offered by PEG-DA/EDOT blends which can be employed in biomedicine, MEMS, microfluidics, and sensorics.

  1. Lithographically induced self-construction of polymer microstructures for resistless patterning

    Science.gov (United States)

    Chou, Stephen Y.; Zhuang, Lei; Guo, Linjie

    1999-08-01

    We have discovered and developed a method that can directly pattern polymer microstructures of arbitrary shapes without using a resist, exposure, chemical development, and etching. A mask with protruded patterns is placed a distance above an initially flat polymer film cast on a substrate. During a heating cycle that raises the temperature above the polymer's glass transition temperature and then cooled back to the room temperature, we found that the polymer was attracted to the mask protrusions on their own, forming the mesas that have a lateral dimension identical to that of the mask protrusions, a height equal to the distance between the mask and the substrate, and a relatively steep sidewall. The method, termed lithographically induced self-construction, is important to the fabrication of polymer electronic and optoelectronic devices.

  2. Power reduction and the radial limit of stall delay in revolving wings of different aspect ratio

    NARCIS (Netherlands)

    Kruyt, J.W.; Heijst, Van G.F.; Altshuler, D.L.; Lentink, David

    2015-01-01

    Airplanes and helicopters use high aspect ratio wings to reduce the power required to fly, but must operate at low angle of attack to prevent flow separation and stall. Animals capable of slow sustained flight, such as hummingbirds, have low aspect ratio wings and flap their wings at high angle o

  3. Seasonal dependence of the urban heat island on the street canyon aspect ratio

    NARCIS (Netherlands)

    Theeuwes, N.E.; Steeneveld, G.J.; Ronda, R.J.; Heusinkveld, B.G.; Hove, van L.W.A.; Holtslag, A.A.M.

    2014-01-01

    In this paper we study the relation between the urban heat island (UHI) in the urban canyon and street geometry, in particular the aspect ratio. Model results and observations show that two counteracting processes govern the relation between the nocturnal UHI and the building aspect ratio: i.e. trap

  4. Shape matters: synthesis and biomedical applications of high aspect ratio magnetic nanomaterials

    OpenAIRE

    Raluca M Fratila; Rivera-Fernández, Sara; Fuente, Jesús M. de la

    2015-01-01

    High aspect ratio magnetic nanomaterials possess anisotropic properties that make them attractive for biological applications. Their elongated shape enables multivalent interactions with receptors through the introduction of multiple targeting units on their surface, thus enhancing cell internalization. Moreover, due to their magnetic anisotropy, high aspect ratio nanomaterials can outperform their spherical analogues as contrast agents for magnetic resonance imaging (MRI) applications. In th...

  5. Prime modes of fluid circulation in large-aspect-ratio turbulent Rayleigh-Bénard convection

    NARCIS (Netherlands)

    Verdoold, J.; Tummers, M.J.; Hanjalić, K.

    2009-01-01

    Based on a detailed experimental investigation in an aspect-ratio-4 rectangular cell in the range 3.7×107≤Ra≤3.7×109, we present evidence of possible scenarios of the long-term dynamics of large-scale circulations (LSC) in bounded large-aspect-ratio turbulent Rayleigh-Bénard convection. Karhunen-Loè

  6. Hydrodynamic chromatography and field flow fractionation in finite aspect ratio channels.

    Science.gov (United States)

    Shendruk, T N; Slater, G W

    2014-04-25

    Hydrodynamic chromatography (HC) and field-flow fractionation (FFF) separation methods are often performed in 3D rectangular channels, though ideal retention theory assumes 2D systems. Devices are commonly designed with large aspect ratios; however, it can be unavoidable or desirable to design rectangular channels with small or even near-unity aspect ratios. To assess the significance of finite-aspect ratio effects and interpret experimental retention results, an ideal, analytical retention theory is needed. We derive a series solution for the ideal retention ratio of HC and FFF rectangular channels. Rather than limiting devices' ability to resolve samples, our theory predicts that retention curves for normal-mode FFF are well approximated by the infinite plate solution and that the performance of HC is actually improved. These findings suggest that FFF devices need not be designed with large aspect ratios and that rectangular HC channels are optimal when the aspect ratio is unity.

  7. The effect of aspect ratio on the performance of an energy harvesting hydrofoil

    Science.gov (United States)

    Kim, Daegyoum; Strom, Benjamin; Su, Yunxing; Mandre, Shreyas; Breuer, Kenneth

    2014-11-01

    We investigated the effect of aspect ratio on energy harvesting performance and flow structure of an oscillating hydrofoil. Power measurement and particle image velocimetry were performed in a water flume with a hydrofoil undergoing periodic heaving and pitching motions. Aspect ratio was varied from 2.5 to 4.5, and end plates were also mounted at the hydrofoil tips in order to suppress three-dimensional effects near the tips. For each aspect ratio, energy conversion efficiency was maximum at the same kinematics determined by reduced frequency and pitch amplitude. The efficiency is increased with the aspect ratio, and it is noticeably enhanced with the installation of the end plates. Leading-edge vortex formation and wake dynamics were compared at several spanwise sections among different aspect ratios. Their correlation with the efficiency was also examined. This research was supported by DOE ARPA-E.

  8. Preparation and Properties of Nanocomposites from Pristine and Modified SWCNTs of Comparable Average Aspect Ratios

    Science.gov (United States)

    Smith, Joseph G.; Delozier, Donavon M.; Watson, Kent A.; Connell, John W.; Bekyarova, E.; Haddon, R.; Yu, A.

    2008-01-01

    Low color, flexible, space-durable polyimide films with inherent and robust electrical conductivity to dissipate electrostatic charge (ESC) have been under investigation as part of a materials development activity for future NASA space missions. The use of single-walled carbon nanotubes (SWCNTs) is one means to achieving this goal. Even though the concentration of SWCNTs needed to achieve ESC dissipation is typically low, it is dependent upon purity, size, dispersion, and functionalization. In this study, SWCNTs prepared by the electric arc discharge method were used to synthesize nanocomposites using the LaRC(TradeMark) CP2 backbone as the matrix. Pristine and functionalized SWCNTs were mixed with an alkoxysilane terminated amide acid of LaRC(TradeMark) CP2 and the soluble imide form of the polymer and the resultant nanocomposites evaluated for mechanical, thermal, and electrical properties. Due to the preparative conditions for the pristine and functionalized SWCNTs, the average aspect ratio for both was comparable. This permitted the assessment of SWCNT functionalization with respect to various interactions (e.g. van der Waals, hydrogen bonding, covalent bond formation, etc.) with the matrix and the macroscopic effects upon nanocomposite properties. The results of this study are described herein.

  9. High Aspect Ratio Microstructures in Flexible Printed Circuit Boards : Process and Applications

    OpenAIRE

    Yousef, Hanna

    2008-01-01

    Flexible printed circuit boards (flex PCBs) are used in a wide range of electronic devices today due to their light weight, bendability, extensive wiring possibilities, and low-cost manufacturing techniques. The general trend in the flex PCB industry is further miniaturization alongside increasing functionality per device and reduced costs. To meet these demands, a new generation of low cost manufacturing technologies is being developed to enable structures with smaller lateral dimensions and...

  10. Flow visualization study in high aspect ratio cooling channels for rocket engines

    Science.gov (United States)

    Meyer, Michael L.; Giuliani, James E.

    1993-11-01

    The structural integrity of high pressure liquid propellant rocket engine thrust chambers is typically maintained through regenerative cooling. The coolant flows through passages formed either by constructing the chamber liner from tubes or by milling channels in a solid liner. Recently, Carlile and Quentmeyer showed life extending advantages (by lowering hot gas wall temperatures) of milling channels with larger height to width aspect ratios (AR is greater than 4) than the traditional, approximately square cross section, passages. Further, the total coolant pressure drop in the thrust chamber could also be reduced, resulting in lower turbomachinery power requirements. High aspect ratio cooling channels could offer many benefits to designers developing new high performance engines, such as the European Vulcain engine (which uses an aspect ratio up to 9). With platelet manufacturing technology, channel aspect ratios up to 15 could be formed offering potentially greater benefits. Some issues still exist with the high aspect ratio coolant channels. In a coolant passage of circular or square cross section, strong secondary vortices develop as the fluid passes through the curved throat region. These vortices mix the fluid and bring lower temperature coolant to the hot wall. Typically, the circulation enhances the heat transfer at the hot gas wall by about 40 percent over a straight channel. The effect that increasing channel aspect ratio has on the curvature heat transfer enhancement has not been sufficiently studied. If the increase in aspect ratio degrades the secondary flow, the fluid mixing will be reduced. Analysis has shown that reduced coolant mixing will result in significantly higher wall temperatures, due to thermal stratification in the coolant, thus decreasing the benefits of the high aspect ratio geometry. A better understanding of the fundamental flow phenomena in high aspect ratio channels with curvature is needed to fully evaluate the benefits of this

  11. Numerical studies of the reversed-field pinch at high aspect ratio

    Science.gov (United States)

    Sätherblom, H.-E.; Drake, J. R.

    1998-10-01

    The reversed field pinch (RFP) configuration at an aspect ratio of 8.8 is studied numerically by means of the three-dimensional magnetohydrodynamic code DEBS [D. D. Schnack et al., J. Comput. Phys. 70, 330 (1987)]. This aspect ratio is equal to that of the Extrap T1 experiment [S. Mazur et al., Nucl. Fusion 34, 427 (1994)]. A numerical study of a RFP with this level of aspect ratio requires extensive computer achievements and has hitherto not been performed. The results are compared with previous studies [Y. L. Ho et al., Phys. Plasmas 2, 3407 (1995)] of lower aspect ratio RFP configurations. In particular, an evaluation of the extrapolation to the aspect ratio of 8.8 made in this previous study shows that the extrapolation of the spectral spread, as well as most of the other findings, are confirmed. An important exception, however, is the magnetic diffusion coefficient, which is found to decrease with aspect ratio. Furthermore, an aspect ratio dependence of the magnetic energy and of the helicity of the RFP is found.

  12. New Vehicle Detection Method with Aspect Ratio Estimation for Hypothesized Windows

    Directory of Open Access Journals (Sweden)

    Jisu Kim

    2015-12-01

    Full Text Available All kinds of vehicles have different ratios of width to height, which are called the aspect ratios. Most previous works, however, use a fixed aspect ratio for vehicle detection (VD. The use of a fixed vehicle aspect ratio for VD degrades the performance. Thus, the estimation of a vehicle aspect ratio is an important part of robust VD. Taking this idea into account, a new on-road vehicle detection system is proposed in this paper. The proposed method estimates the aspect ratio of the hypothesized windows to improve the VD performance. Our proposed method uses an Aggregate Channel Feature (ACF and a support vector machine (SVM to verify the hypothesized windows with the estimated aspect ratio. The contribution of this paper is threefold. First, the estimation of vehicle aspect ratio is inserted between the HG (hypothesis generation and the HV (hypothesis verification. Second, a simple HG method named a signed horizontal edge map is proposed to speed up VD. Third, a new measure is proposed to represent the overlapping ratio between the ground truth and the detection results. This new measure is used to show that the proposed method is better than previous works in terms of robust VD. Finally, the Pittsburgh dataset is used to verify the performance of the proposed method.

  13. Selective three-dimensional hydrophilization of microstructured polymer surfaces through confined photocatalytic oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Ammosova, Lena; Jiang, Yu; Suvanto, Mika; Pakkanen, Tapani A., E-mail: tapani.pakkanen@uef.fi

    2015-02-28

    Graphical abstract: - Highlights: • Microstructured polymer surfaces with selective 3-D anisotropy were created. • Selective UV treatment was performed to alter surface wettability. • Removable meshes resembling a photomask were applied during UV treatment. • Micropatterning by viscous polymer on solid surface was performed. - Abstract: While the conventional photomask technique gives only two-dimensional anisotropies, in this study we fabricated microstructured polymer surfaces with a selective three-dimensional anisotropy. With the applied removable mesh, we were able to confine the contacting area between the surface and photoinitiator and provide three-dimensional wettability anisotropies. Different types of meshes were used depending on the desired micropatterns shape, size and substrate material. The results revealed the three-dimensional anisotropic micropits pattern with depth profiles, which would be applicable for the confinement and patterning of cells and biomolecules. In addition, the proposed method is applicable for creating selectively activated polymer surface as a substrate for further atomic layer deposition. Moreover, we demonstrate a low cost and fast mass productive method for patterning a viscous polymer liquid in a micro-sized scale.

  14. Effects of alkyl chain positioning on conjugated polymer microstructure and field-effect mobilities

    KAUST Repository

    Schroeder, Bob C.

    2015-07-02

    Solubilizing alkyl chains play a crucial role in the design of semiconducting polymers because they define the materials solubility and processability as well as both the crystallinity and solid-state microstructure. In this paper, we present a scarcely explored design approach by attaching the alkyl side chains on one side (cis-) or on both sides (trans-) of the conjugated backbone. We further investigate the effects of this structural modification on the solid-state properties of the polymers and on the charge-carrier mobilities in organic thin-film transistors. Copyright © Materials Research Society 2015

  15. Tailored Au nanorods: optimizing functionality, controlling the aspect ratio and increasing biocompatibility

    Energy Technology Data Exchange (ETDEWEB)

    Cai Xiaoqing; Wang, Cheng-Liang; Chen, Hsiang-Hsin; Chien, Chia-Chi; Lai Shengfeng; Chen Yiyun; Hua, Tzu-En; Kempson, Ivan M; Hwu, Y [Institute of Physics, Academia Sinica, Nankang, Taipei 115, Taiwan (China); Yang, C S [Center for Nanomedicine, National Health Research Institutes, Miaoli, Taiwan (China); Margaritondo, G, E-mail: phhwu@sinica.edu.tw [Ecole Polytechnique Federale de Lausanne (EPFL), CH-1015 Lausanne (Switzerland)

    2010-08-20

    Monodisperse gold nanorods with high aspect ratio were synthesized by x-ray irradiation. Irradiation was first used to stimulate the creation of seeds. Afterward, nanorod growth was stimulated either by chemical reduction or again by x-ray irradiation. In the last case, the entire process took place without reducing agents. The shape of the final products could be controlled by modulating the intensity of the x-ray irradiation during the seed synthesis. In turn, the nanorod aspect ratio determines the absorption wavelength of the nanorods that can thus be optimized for different applications. Likewise, the aspect ratio influences the uptake of the nanorods by HeLa cells.

  16. Selective Serial Multi-Antibody Biosensing with TOPAS Microstructured Polymer Optical Fibers

    DEFF Research Database (Denmark)

    Emiliyanov, Grigoriy Andreev; Høiby, Poul E.; Pedersen, Lars H.

    2013-01-01

    We have developed a fluorescence-based fiber-optical biosensor, which can selectively detect different antibodies in serial at preselected positions inside a single piece of fiber. The fiber is a microstructured polymer optical fiber fabricated from TOPAS cyclic olefin copolymer, which allows...... for UV activation of localized sensor layers inside the holes of the fiber. Serial fluorescence-based selective sensing of Cy3-labelled α-streptavidin and Cy5-labelled α-CRP antibodies is demonstrated....

  17. Selective Serial Multi-Antibody Biosensing with TOPAS Microstructured Polymer Optical Fibers

    Directory of Open Access Journals (Sweden)

    Lars H. Pedersen

    2013-03-01

    Full Text Available We have developed a fluorescence-based fiber-optical biosensor, which can selectively detect different antibodies in serial at preselected positions inside a single piece of fiber. The fiber is a microstructured polymer optical fiber fabricated from TOPAS cyclic olefin copolymer, which allows for UV activation of localized sensor layers inside the holes of the fiber. Serial fluorescence-based selective sensing of Cy3-labelled α-streptavidin and Cy5-labelled α-CRP antibodies is demonstrated.

  18. Selective serial multi-antibody biosensing with TOPAS microstructured polymer optical fibers.

    Science.gov (United States)

    Emiliyanov, Grigoriy; Høiby, Poul E; Pedersen, Lars H; Bang, Ole

    2013-03-08

    We have developed a fluorescence-based fiber-optical biosensor, which can selectively detect different antibodies in serial at preselected positions inside a single piece of fiber. The fiber is a microstructured polymer optical fiber fabricated from TOPAS cyclic olefin copolymer, which allows for UV activation of localized sensor layers inside the holes of the fiber. Serial fluorescence-based selective sensing of Cy3-labelled α-streptavidin and Cy5-labelled α-CRP antibodies is demonstrated.

  19. Aspect ratio dependent fluorescence quenching of eosin Y by gold nanorods.

    Science.gov (United States)

    Weng, Guojun; Li, Jianjun; Zhang, Li; Zhao, Junwu

    2014-06-01

    Gold nanorods of different aspect ratios had been synthesized using seed mediated growth method. The formed gold nanorods had been characterized by the absorption and transmission electron microscopy (TEM) measurements. The obtained gold nanorods were used to study the quenched effect on fluorescence of Eosin Y. Experimental results revealed that Eosin Y molecules adsorbed on the metallic surfaces, suffering strong quenching of their fluorescence and the quenching efficiency was different for different aspect ratio. Using dielectric coated gold nanorods model, the probable mechanism of aspect ratio dependent quenching efficiency was obtained by numerical calculation based on fluorescence resonance energy transfer and quasi-static theory. The calculation results showed that the non-monotonic changing of fluorescence quenching was attributed to competing effects of aspect ratio and the dielectric constant of coated shell on surface plasmon resonance.

  20. Resistive wall stabilization by toroidal rotation: effects of partial wall configurations and aspect ratio

    Energy Technology Data Exchange (ETDEWEB)

    Ward, D.J. [Ecole Polytechnique Federale, Lausanne (Switzerland). Centre de Recherche en Physique des Plasma (CRPP)

    1996-09-01

    The results of this work demonstrate that with a pair of close-fitting conducting plates, which leave a large gap at the outboard midplane, a high-{beta} equilibrium at conventional aspect ratio can be stabilized at a rotation speed reduced by a factor of over 3.5 compared to a fully surrounding, continuous and complete wall at the same separation. Results were also presented which show that low-aspect-ratio equilibria can be stabilized at significantly lower rotation speeds than at conventional aspect ratio. These two effects can perhaps be combined to enhance even further the effect of resistive wall stabilization at low aspect ratio. (author) 3 figs., 1 tab., 7 refs.

  1. Synthesis of high aspect ratio ZnO nanowires with an inexpensive handcrafted electrochemical setup

    Science.gov (United States)

    Taheri, Ali; Saramad, Shahyar; Setayeshi, Saeed

    2016-12-01

    In this work, high aspect ratio zinc oxide nanowires are synthesized using templated one-step electrodeposition technique. Electrodeposition of the nanowires is done using a handcrafted electronic system. Nuclear track-etched polycarbonate membrane is used as a template to form the high aspect ratio nanowires. The result of X-ray diffraction and scanning electron microscopy shows that nanowires with a good crystallinity and an aspect ratio of more than 30 can be achieved in a suitable condition. The height of electrodeposited nanowires reaches to about 11 μm. Based on the obtained results, high aspect ratio ZnO nanowires can be formed using inexpensive electrodeposition setup with an acceptable quality.

  2. Aspect Ratio Dependence of the Free-Fall Time for Non-Spherical Symmetries

    CERN Document Server

    Pon, Andy; Johnstone, Doug; Vázquez-Semadeni, Enrique; Heitsch, Fabian; Gómez, Gilberto C

    2012-01-01

    We investigate the collapse of non-spherical substructures, such as sheets and filaments, which are ubiquitous in molecular clouds. Such non-spherical substructures collapse homologously in their interiors but are influenced by an edge effect that causes their edges to be preferentially accelerated. We analytically compute the homologous collapse timescales of the interiors of uniform-density, self-gravitating filaments and find that the homologous collapse timescale scales linearly with the aspect ratio. The characteristic timescale for an edge driven collapse mode in a filament, however, is shown to have a square root dependence on the aspect ratio. For both filaments and circular sheets, we find that selective edge acceleration becomes more important with increasing aspect ratio. In general, we find that lower dimensional objects and objects with larger aspect ratios have longer collapse timescales. We show that estimates for star formation rates, based upon gas densities, can be overestimated by an order ...

  3. Ultra-high aspect ratio replaceable AFM tips using deformation-suppressed focused ion beam milling

    DEFF Research Database (Denmark)

    Savenko, Alexey; Yildiz, Izzet; Petersen, Dirch Hjorth;

    2013-01-01

    Fabrication of ultra-high aspect ratio exchangeable and customizable tips for atomic force microscopy (AFM) using lateral focused ion beam (FIB) milling is presented. While on-axis FIB milling does allow high aspect ratio (HAR) AFM tips to be defined, lateral milling gives far better flexibility...... FIB milling strategies for obtaining sharper tips are discussed. Finally, assembly of the HAR tips on a custom-designed probe as well as the first AFM scanning is shown....

  4. A Sense of Proportion: Aspect Ratio and the Framing of Television Space

    OpenAIRE

    Cardwell, Sarah E. F.

    2015-01-01

    ‘Aspect ratio’ is frequently overlooked or naively characterised. Yet it plays a fundamental, determining role in forming and framing television’s spaces. A balanced reappraisal of television’s varied aspect ratios and their unique dramatic and aesthetic possibilities can enhance our close analyses and our understanding of television’s ‘art history’. This paper challenges myths, misunderstandings and preconceptions about TV’s aspect ratios and their spatial properties. Countering prevailing p...

  5. A Stationary Vortex Phenomenon above a Low-Aspect-Ratio Wing

    Institute of Scientific and Technical Information of China (English)

    TANG Jian; ZHU Ke-Qin; TAN Guang-Kun

    2004-01-01

    @@ A stationary vortex phenomenon above a nondelta low-aspect-ratio wing was obtained in three-dimensional unsteady numerical simulation. Flow visualization is conducted in water channel using hydrogen bubbles. The results verify that there is a vortex trapped above the low-aspect-ratio wing and the stationary vortex consisted of two semi-balls and anti-rotation vortices which are different from the leading edge vortices on the delta wing.

  6. Thorough tuning of the aspect ratio of gold nanorods using response surface methodology

    Energy Technology Data Exchange (ETDEWEB)

    Reza Hormozi-Nezhad, M., E-mail: hormozi@sharif.edu [Department of Chemistry, Sharif University of Technology, Tehran 11155-9516 (Iran, Islamic Republic of); Institute for Nanoscience and Nanotechnology, Sharif University of Technology, Tehran (Iran, Islamic Republic of); Robatjazi, Hossein; Jalali-Heravi, Mehdi [Department of Chemistry, Sharif University of Technology, Tehran 11155-9516 (Iran, Islamic Republic of)

    2013-05-24

    Graphical abstract: -- Highlights: •We are finely controlling the aspect ratio of gold nanorods. •We study the effect of variables on aspect ratio (AR) of gold nanorods simultaneously. •We use response surface methodology to make the relation among parameters affect on AR. -- Abstract: In the present work a central composite design based on response surface methodology (RSM) is employed for fine tuning of the aspect ratios of seed-mediated synthesized gold nanorods (GNRs). The relations between the affecting parameters, including ratio of l-ascorbic acid to Au{sup 3+} ions, concentrations of silver nitrate, CTAB, and CTAB-capped gold seeds, were explored using a RSM model. It is observed that the effect of each parameter on the aspect ratio of developing nanorods highly depends on the value of the other parameters. The concentrations of silver ions, ascorbic acid and seeds are found to have a high contribution in controlling the aspect ratios of NRs. The optimized parameters led to a high yield synthesis of gold nanorods with an ideal aspect ratio ranging from 1 (spherical particle) to 4.9. In addition, corresponding tunable surface Plasmon absorption band has been extended to 880 nm. The resulted nanorods were characterized by UV–visible spectrometry and transmission electron microscopy.

  7. Fabrication of high aspect ratio nanocell lattices by ion beam irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Ishikawa, Osamu [School of Environmental Science and Technology, Kochi University of Technology, Tosayamada, Kami, Kochi 782-8502 (Japan); Nitta, Noriko, E-mail: nitta.noriko@kochi-tech.ac.jp [School of Environmental Science and Technology, Kochi University of Technology, Tosayamada, Kami, Kochi 782-8502 (Japan); Center for Nanotechnology, Research Institute, Kochi University of Technology, Tosayamada, Kami, Kochi 782-8502 (Japan); Taniwaki, Masafumi [School of Environmental Science and Technology, Kochi University of Technology, Tosayamada, Kami, Kochi 782-8502 (Japan)

    2016-11-01

    Highlights: • Nanocell lattice with a high aspect ratio on InSb semiconductor surface was fabricated by ion beam irradiation. • The fabrication technique consisting of top-down and bottom-up processes was performed in FIB. • High aspect ratio of 2 was achieved in nanocell lattice with a 100 nm interval. • The intermediate-flux irradiation is favorable for fabrication of nanocell with a high aspect ratio. - Abstract: A high aspect ratio nanocell lattice was fabricated on the InSb semiconductor surface using the migration of point defects induced by ion beam irradiation. The fabrication technique consisting of the top-down (formation of voids and holes) and bottom-up (growth of voids and holes into nanocells) processes was performed using a focused ion beam (FIB) system. A cell aspect ratio of 2 (cell height/cell diameter) was achieved for the nanocell lattice with a 100 nm dot interval The intermediate-flux ion irradiation during the bottom-up process was found to be optimal for the fabrication of a high aspect ratio nanocell.

  8. Lift-optimal aspect ratio of a revolving wing at low Reynolds number

    Science.gov (United States)

    Jardin, Thierry; Colonius, Tim

    2016-11-01

    Lentink & Dickinson (2009) showed that rotational acceleration stabilized the leading-edge vortex on revolving, low-aspect-ratio wings, and hypothesized that a Rossby number of around 3, which is achieved during each half-stroke for a variety of hovering insects, seeds, and birds, represents a convergent high-lift solution across a range of scales in nature. Subsequent work has verified that, in particular, the Coriolis acceleration is responsible for LEV stabilization. Implicit in these results is that there exists an optimal aspect ratio for wings revolving about their root, because it is otherwise unclear why, apart from possible physiological reasons, the convergent solution would not occur for an even lower Rossby number. We perform direct numerical simulations of the flow past revolving wings where we vary the aspect ratio and Rossby numbers independently by displacing the wing root from the axis of rotation. We show that the optimal lift coefficient represents a compromise between competing trends where the coefficient of lift increases monotonically with aspect ratio, holding Rossby number constant, but decreases monotonically with Rossby number, when holding aspect ratio constant. For wings revolving about their root, this favors wings of aspect ratio between 3 and 4. The authors gratefully acknowledge support from Fondation ISAE-Supaero.

  9. Effect of tip vortices on membrane vibration of flexible wings with different aspect ratios

    Directory of Open Access Journals (Sweden)

    Genç Mustafa Serdar

    2016-01-01

    Full Text Available In this study, the effect of the aspect ratio on the aerodynamics characteristic of flexible membrane wings with different aspect ratios (AR = 1 and AR = 3 is experimentally investigated at Reynolds number of 25000. Time accurate measurements of membrane deformation using Digital Image Correlation system (DIC is carried out while normal forces of the wing will be measured by helping a load-cell system and flow on the wing was visualized by means of smoke wire technic. The characteristics of high aspect ratio wings are shown to be affected by leading edge separation bubbles at low Reynolds number. It is concluded that the camber of membrane wing excites the separated shear layer and this situation increases the lift coefficient relatively more as compared to rigid wings. In membrane wings with low aspect ratio, unsteadiness included tip vortices and vortex shedding, and the combination of tip vortices and vortex shedding causes complex unsteady deformations of these membrane wings. The characteristic of high aspect ratio wings was shown to be affected by leading edge separation bubbles at low Reynolds numbers whereas the deformations of flexible wing with low aspect ratio affected by tip vortices and leading edge separation bubbles.

  10. Aspect ratio dependence of heat transfer and large-scale flow in turbulent convection

    CERN Document Server

    Bailon-Cuba, Jorge; Schumacher, Joerg

    2010-01-01

    The heat transport and corresponding changes in the large-scale circulation (LSC) in turbulent Rayleigh-B\\'{e}nard convection are studied by means of three-dimensional direct numerical simulations as a function of the aspect ratio $\\Gamma$ of a closed cylindrical cell and the Rayleigh number $Ra$. For small and moderate aspect ratios, the global heat transfer law $Nu=A\\times Ra^{\\beta}$ shows a power law dependence of both fit coefficients $A$ and $\\beta$ on the aspect ratio. A minimum Nusselt number coincides with the point where the LSC undergoes a transition from a single-roll to a double-roll pattern. With increasing aspect ratio, we detect complex multi-roll LSC configurations. The aspect ratio dependence of the turbulent heat transfer for small and moderate $\\Gamma$ is in line with a varying amount of energy contained in the LSC, as quantified by the Proper Orthogonal Decomposition analysis. For $\\Gamma\\gtrsim 8$ the heat transfer becomes independent of the aspect ratio.

  11. Growth of high aspect ratio ZnO nanorods by solution process: Effect of polyethyleneimine

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Han-Seok; Vaseem, Mohammad; Kim, Sang Gon; Im, Yeon-Ho [School of Semiconductor and Chemical Engineering, Dept. of BIN Fusion Technology, BK 21 Centre for Future Energy Materials and Devices, and Nanomaterials Processing Research Center, Chonbuk National University, Jeonju 561-756 (Korea, Republic of); Hahn, Yoon-Bong, E-mail: ybhahn@chonbuk.ac.kr [School of Semiconductor and Chemical Engineering, Dept. of BIN Fusion Technology, BK 21 Centre for Future Energy Materials and Devices, and Nanomaterials Processing Research Center, Chonbuk National University, Jeonju 561-756 (Korea, Republic of)

    2012-05-15

    High aspect ratio ZnO nanorods were grown vertically on ZnO seed layer deposited silicon, glass and polyimide substrates by a solution process at low-temperature using zinc nitrate hexahydrate and hexamethylenetetramine. We studied the effect of polyethlyeneimine (PEI) on the growth of ZnO nanorods. It was found that PEI has a prominent effect on controlling the aspect ratio of ZnO nanorods in solution. The morphological and photoluminescence properties of the ZnO nanorods were also examined with varying the growth temperature (60-90 Degree-Sign C). - Graphical abstract: With addition of polyehyleneimine (PEI) high aspect-ratio ZnO nanorods were grown. It is believed that during ZnO nanorods growth, protonized form of linear PEI molecules inhibits the lateral growth by being adsorbed on non-polar lateral planes. Thus the vertical growth is favored. Highlights: Black-Right-Pointing-Pointer A controlled growth of high aspect ratio ZnO nanorods on different substrates. Black-Right-Pointing-Pointer A prominent effect of polyethlyeneimine (PEI) on controlling the aspect ratio of ZnO nanorods in solution. Black-Right-Pointing-Pointer Precursor concentration and growth temperature effect for various aspect ratio ZnO nanorods.

  12. Relating Film Structure/Microstructure on Device Function/Microproperties in Conjugated Polymers and Polymer/Small Molecule Blends

    Science.gov (United States)

    Cochran, Justin Enir

    Over the last twenty years conjugated organic materials, polymers and small molecules, have attracted broad interest due to their potential applications in the field of solution processed low cost electronics. Due to their semi/polycrystalline nature the spatial arrangement of crystallites and disordered regions in the film have a significant influence over charge transport properties. Structure-Function relationships are universal; consequently, the focus of my research thesis is to relate the film structure/microstructure to device performance and micro-properties, specifically in thin film transistors and bulk conductivity measurements. My initial research focus was on how modification of a semiconducting polymers backbone alters the packing structure and in turn impacts device performance. We then focused on how modification of TFT interface microstructures by altering between dielectric surfaces changes the orientaional correlation length in the semiconductors crystalline domains which in turn directly impacts the field effect mobility. The final two projects focused on doping conjugated polymers with small molecular acceptors. The purpose was to understand how bulk packing dominates conductivity in order to better understand what appears to be a universal transport behavior in these blends. These insights into the structural changes provide a platform under which to analyze the electrical measurements where significant changes in conductivity were observed at high acceptor concentrations but results showed dependence upon pre and post processing conditions. As expected, increases in film conductivity scaled with acceptor concentration but of special interest is how the conductivity showed temperature stability upon annealing, even increasing under certain conditions, near the polymer liquid crystal transition temperature and then decreasing below the as cast baseline at higher annealing temperatures. The electrical study combined with the structural analysis

  13. Photonic effects in microstructured conjugated polymer films and light emitting diodes

    CERN Document Server

    Matterson, B J

    2002-01-01

    metal layers that are used as electrodes in the LED does not adversely affect the electrical properties of the LED. It is demonstrated that grating in the LED is able to substantially increase the light emission without using extra electrical power. The emission spectra from LEDs are observed to vary with angle, and exhibit considerable polarization. This thesis reports an investigation into the photonic effects caused by wavelength scale microstructure patterned onto films of conjugated polymers. The efficiency of light emitting diodes (LEDs) made from conjugated polymers is limited in part by the trapping of light into waveguide modes caused by the high refractive index of these materials. Waveguide modes in films of poly(p,-phenylene vinylene) (PPV) and poly(2-methoxy, 5-(2'ethylhexyloxy)-p-phenylene vinylene) (MEH-PPV) are analysed and the refractive index of these materials is calculated. The photoluminescence of conjugated polymer films that have been spun onto textured substrates is analysed. It is fou...

  14. Interferometric microstructured polymer optical fiber ultrasound sensor for optoacoustic endoscopic imaging in biomedical applications

    DEFF Research Database (Denmark)

    Gallego, Daniel; Sáez-Rodríguez, David; Webb, David

    2014-01-01

    to conventional piezoelectric transducers. These kind of sensors, made of biocompatible polymers, are good candidates for the sensing element in an optoacoustic endoscope because of its high sensitivity, its shape and its non-brittle and non-electric nature. The acoustic sensitivity of the intrinsic fiber optic......We report a characterization of the acoustic sensitivity of microstructured polymer optical fiber interferometric sensors at ultrasonic frequencies from 100kHz to 10MHz. The use of wide-band ultrasonic fiber optic sensors in biomedical ultrasonic and optoacoustic applications is an open alternative...... interferometric sensors depends strongly of the material which is composed of. In this work we compare experimentally the intrinsic ultrasonic sensitivities of a PMMA mPOF with other three optical fibers: a singlemode silica optical fiber, a single-mode polymer optical fiber and a multimode graded...

  15. The impact of non-equilibrium microstructure on the mechanical response of polymer nanocomposites

    Science.gov (United States)

    Thomin, James D.

    2007-12-01

    , particle clustering is driven primarily by the polymer entropy. As a consequence, applying strain at rates corresponding to the shear-thinning regime tends to increase particle dispersion. The different modes of reinforcement which occur at different interaction strengths, combined with the inherently non-equilibrium nature of the microstructure at the extreme low or high end of the interaction strength scale explain why disagreement over the nature of reinforcement has persisted in the experimental community. These simulation results provide a qualitative "map" of the types of reinforcement and non-equilibrium behavior that one would expect to see for different ranges of the particle-polymer interaction energy.

  16. Impact of electrode preparation on the bending of asymmetric planar electro-active polymer microstructures

    Science.gov (United States)

    Weiss, Florian M.; Töpper, Tino; Osmani, Bekim; Winterhalter, Carla; Müller, Bert

    2014-03-01

    Compliant electrodes of microstructures have been a research topic for many years because of the increasing interest in consumer electronics, robotics, and medical applications. This interest includes electrically activated polymers (EAP), mainly applied in robotics, lens systems, haptics and foreseen in a variety of medical devices. Here, the electrodes consist of metals such as gold, graphite, conductive polymers or certain composites. The common metal electrodes have been magnetron sputtered, thermally evaporated or prepared using ion implantation. In order to compare the functionality of planar metal electrodes in EAP microstructures, we have investigated the mechanical properties of magnetron sputtered and thermally evaporated electrodes taking advantage of cantilever bending of the asymmetric, rectangular microstructures. We demonstrate that the deflection of the sputtered electrodes is up to 39 % larger than that of thermally evaporated nanometer-thin film on a single silicone film. This difference has even more impact on nanometer-thin, multi-stack, low-voltage EAP actuators. The stiffening effect of many metallic electrode layers is expected to be one of the greatest drawbacks in the multi-stack approaches, which will be even more pronounced if the elastomer layer thickness will be in the sub-micrometer range. Additionally, an improvement in voltage and strain resolution is presented, which is as low as 2 V or 5 × 10-5 above 10 V applied.

  17. Solar cells based on block copolymer semiconductor nanowires: effects of nanowire aspect ratio.

    Science.gov (United States)

    Ren, Guoqiang; Wu, Pei-Tzu; Jenekhe, Samson A

    2011-01-25

    The solution-phase self-assembly of nanowires (NWs) from diblock copolymer semiconductors, poly(3-butylthiophene)-block-poly(3-octylthiophene), of different block compositions gave crystalline NWs of similar width (13-16 nm) but a tunable average aspect ratio (length/width) of 50-260. The power conversion efficiency of bulk heterojunction solar cells comprising the diblock copolythiophene NWs and PC(71)BM was found to increase with increasing aspect ratio, reaching 3.4% at the highest average aspect ratio of 260. The space charge limited current mobility of holes in neat films of the copolymer NWs and in copolymer NWs/PC(71)BM films (∼1.0 × 10(-4) cm(2)/(V s)) was invariant with aspect ratio, reflecting the parallel orientation of the NWs to the substrate. The enhancement of photovoltaic efficiency with increasing aspect ratio of NWs was explained in terms of increased exciton and charge photogeneration and collection in the bulk heterojunction solar cells.

  18. Precise modulation of gold nanorods aspect ratio based on localized surface plasmon resonance

    Science.gov (United States)

    Wen, Xiaoyan; Shuai, Huang; Min, Li

    2016-10-01

    Gold nanorods (GNRs) aspect ratio is significant to GNRs-based biomedical sensors. In this paper precise modulation of GNRs aspect ratio was realized by H2O2 oxidation based on localized surface plasmon resonance (LSPR) of GNRs. The oxidation process was studied in detail. A linear relationship was revealed between H2O2 oxidation time and the longitudinal LSPR wavelength of GNR, the latter depending on GNRs aspect ratio. Using the relationship GNRs aspect ratios could be modulated by H2O2 oxidation time. Oxidation time deduced aspect ratio was verified by transmission electron microscope (TEM) characterization and the average error is 2.92%. Influences of temperature and pH value on the modulation process were investigated. Increase in temperature (from 30 °C to 60 °C) or solution acidity (pH value from 2.6 to 1.2) facilitated the oxidation process. The proposed method is characterized by its simplicity and efficiency, and would find extensive application prospects in GNRs-based biomedical sensing fields.

  19. Selecting the aspect ratio of a scatter plot based on its delaunay triangulation.

    Science.gov (United States)

    Fink, Martin; Haunert, Jan-Henrik; Spoerhase, Joachim; Wolff, Alexander

    2013-12-01

    Scatter plots are diagrams that visualize two-dimensional data as sets of points in the plane. They allow users to detect correlations and clusters in the data. Whether or not a user can accomplish these tasks highly depends on the aspect ratio selected for the plot, i.e., the ratio between the horizontal and the vertical extent of the diagram. We argue that an aspect ratio is good if the Delaunay triangulation of the scatter plot at this aspect ratio has some nice geometric property, e.g., a large minimum angle or a small total edge length. More precisely, we consider the following optimization problem. Given a set Q of points in the plane, find a scale factor s such that scaling the x-coordinates of the points in Q by s and the y-coordinates by 1=s yields a point set P(s) that optimizes a property of the Delaunay triangulation of P(s), over all choices of s. We present an algorithm that solves this problem efficiently and demonstrate its usefulness on real-world instances. Moreover, we discuss an empirical test in which we asked 64 participants to choose the aspect ratios of 18 scatter plots. We tested six different quality measures that our algorithm can optimize. In conclusion, minimizing the total edge length and minimizing what we call the 'uncompactness' of the triangles of the Delaunay triangulation yielded the aspect ratios that were most similar to those chosen by the participants in the test.

  20. Influence of grid aspect ratio on planetary boundary layer turbulence in large-eddy simulations

    Directory of Open Access Journals (Sweden)

    S. Nishizawa

    2015-10-01

    Full Text Available We examine the influence of the grid aspect ratio of horizontal to vertical grid spacing on turbulence in the planetary boundary layer (PBL in a large-eddy simulation (LES. In order to clarify and distinguish them from other artificial effects caused by numerical schemes, we used a fully compressible meteorological LES model with a fully explicit scheme of temporal integration. The influences are investigated with a series of sensitivity tests with parameter sweeps of spatial resolution and grid aspect ratio. We confirmed that the mixing length of the eddy viscosity and diffusion due to sub-grid-scale turbulence plays an essential role in reproducing the theoretical −5/3 slope of the energy spectrum. If we define the filter length in LES modeling based on consideration of the numerical scheme, and introduce a corrective factor for the grid aspect ratio into the mixing length, the theoretical slope of the energy spectrum can be obtained; otherwise, spurious energy piling appears at high wave numbers. We also found that the grid aspect ratio has influence on the turbulent statistics, especially the skewness of the vertical velocity near the top of the PBL, which becomes spuriously large with large aspect ratio, even if a reasonable spectrum is obtained.

  1. Shape matters: synthesis and biomedical applications of high aspect ratio magnetic nanomaterials.

    Science.gov (United States)

    Fratila, Raluca M; Rivera-Fernández, Sara; de la Fuente, Jesús M

    2015-05-14

    High aspect ratio magnetic nanomaterials possess anisotropic properties that make them attractive for biological applications. Their elongated shape enables multivalent interactions with receptors through the introduction of multiple targeting units on their surface, thus enhancing cell internalization. Moreover, due to their magnetic anisotropy, high aspect ratio nanomaterials can outperform their spherical analogues as contrast agents for magnetic resonance imaging (MRI) applications. In this review, we first describe the two main synthetic routes for the preparation of anisotropic magnetic nanomaterials: (i) direct synthesis (in which the anisotropic growth is directed by tuning the reaction conditions or by using templates) and (ii) assembly methods (in which the high aspect ratio is achieved by assembly from individual building blocks). We then provide an overview of the biomedical applications of anisotropic magnetic nanomaterials: magnetic separation and detection, targeted delivery and magnetic resonance imaging.

  2. Development of high-aspect-ratio microchannel heat exchanger based on multi-tool milling process

    Institute of Scientific and Technical Information of China (English)

    潘敏强; 李金恒; 汤勇

    2008-01-01

    A high-aspect-ratio microchannel heat exchanger based on multi-tool milling process was developed. Several slotting cutters were stacked together for simultaneously machining several high-aspect-ratio microchannels with manifold structures. On the basis of multi-tool milling process, the structural design of the manifold side height, microchannel length, width, number, and interval were analyzed. The heat transfer performances of high-aspect-ratio microchannel heat exchangers with two different manifolds were investigated by experiments, and the influencing factors were analyzed. The results indicate that the magnitude of heat transfer area per unit volume dominates the heat transfer performances of plate-type micro heat exchanger, while the velocity distribution between microchannels has little effects on the heat transfer performances.

  3. Inversion of spheroid particle size distribution in wider size range and aspect ratio range

    Directory of Open Access Journals (Sweden)

    Tang Hong

    2013-01-01

    Full Text Available The non-spherical particle sizing is very important in the aerosol science, and it can be determined by the light extinction measurement. This paper studies the effect of relationship of the size range and aspect ratio range on the inversion of spheroid particle size distribution by the dependent mode algorithm. The T matrix method and the geometric optics approximation method are used to calculate the extinction efficiency of the spheroids with different size range and aspect ratio range, and the inversion of spheroid particle size distribution in these different ranges is conducted. Numerical simulation indicates that a fairly reasonable representation of the spheroid particle size distribution can be obtained when the size range and aspect ratio range are suitably chosen.

  4. Controlled Aspect Ratios of Gold Nanorods in Reduction-Limited Conditions

    Directory of Open Access Journals (Sweden)

    Jong-Yeob Kim

    2011-01-01

    Full Text Available Aspect ratios of gold nanorods have been finely modified in reduction-limited conditions via two electrochemical ways: by changing the amount of a growth solution containing small gold clusters in the presence of already prepared gold nanorods as seeds or by changing electrolysis time in the presence or absence of a silver plate. While the atomic molar ratio of gold in the growth solution to gold in the seed solution is critical in the former method, the relative molar ratio of gold ions to silver ions in the electrolytic solution is important in the latter way for the control of the aspect ratios of gold nanorods. The aspect ratios of gold nanorods decrease with an increase of electrolysis time in the absence of a silver plate, but they increase with an increase of electrolysis time in the presence of a silver plate.

  5. Shape matters: synthesis and biomedical applications of high aspect ratio magnetic nanomaterials

    Science.gov (United States)

    Fratila, Raluca M.; Rivera-Fernández, Sara; de La Fuente, Jesús M.

    2015-04-01

    High aspect ratio magnetic nanomaterials possess anisotropic properties that make them attractive for biological applications. Their elongated shape enables multivalent interactions with receptors through the introduction of multiple targeting units on their surface, thus enhancing cell internalization. Moreover, due to their magnetic anisotropy, high aspect ratio nanomaterials can outperform their spherical analogues as contrast agents for magnetic resonance imaging (MRI) applications. In this review, we first describe the two main synthetic routes for the preparation of anisotropic magnetic nanomaterials: (i) direct synthesis (in which the anisotropic growth is directed by tuning the reaction conditions or by using templates) and (ii) assembly methods (in which the high aspect ratio is achieved by assembly from individual building blocks). We then provide an overview of the biomedical applications of anisotropic magnetic nanomaterials: magnetic separation and detection, targeted delivery and magnetic resonance imaging.

  6. Aspect Ratio Model for Radiation-Tolerant Dummy Gate-Assisted n-MOSFET Layout.

    Science.gov (United States)

    Lee, Min Su; Lee, Hee Chul

    2014-01-01

    In order to acquire radiation-tolerant characteristics in integrated circuits, a dummy gate-assisted n-type metal oxide semiconductor field effect transistor (DGA n-MOSFET) layout was adopted. The DGA n-MOSFET has a different channel shape compared with the standard n-MOSFET. The standard n-MOSFET has a rectangular channel shape, whereas the DGA n-MOSFET has an extended rectangular shape at the edge of the source and drain, which affects its aspect ratio. In order to increase its practical use, a new aspect ratio model is proposed for the DGA n-MOSFET and this model is evaluated through three-dimensional simulations and measurements of the fabricated devices. The proposed aspect ratio model for the DGA n-MOSFET exhibits good agreement with the simulation and measurement results.

  7. Fabrication of high aspect ratio nanogrid transparent electrodes via capillary assembly of Ag nanoparticles

    Science.gov (United States)

    Kang, Juhoon; Park, Chang-Goo; Lee, Su-Han; Cho, Changsoon; Choi, Dae-Geun; Lee, Jung-Yong

    2016-05-01

    In this report, we describe the fabrication of periodic Ag nanogrid electrodes by capillary assembly of silver nanoparticles (AgNPs) along patterned nanogrid templates. By assembling the AgNPs into these high-aspect-ratio nanogrid patterns, we can obtain high-aspect-ratio nanogratings, which can overcome the inherent trade-off between the optical transmittance and the sheet resistance of transparent electrodes. The junction resistance between the AgNPs is effectively reduced by photochemical welding and post-annealing. The fabricated high-aspect-ratio nanogrid structure with a line width of 150 nm and a height of 450 nm has a sheet resistance of 15.2 Ω sq-1 and an optical transmittance of 85.4%.In this report, we describe the fabrication of periodic Ag nanogrid electrodes by capillary assembly of silver nanoparticles (AgNPs) along patterned nanogrid templates. By assembling the AgNPs into these high-aspect-ratio nanogrid patterns, we can obtain high-aspect-ratio nanogratings, which can overcome the inherent trade-off between the optical transmittance and the sheet resistance of transparent electrodes. The junction resistance between the AgNPs is effectively reduced by photochemical welding and post-annealing. The fabricated high-aspect-ratio nanogrid structure with a line width of 150 nm and a height of 450 nm has a sheet resistance of 15.2 Ω sq-1 and an optical transmittance of 85.4%. Electronic supplementary information (ESI) available. See DOI: 10.1039/c6nr01896c

  8. Improving surface acousto-optical interaction by high aspect ratio electrodes

    DEFF Research Database (Denmark)

    Dühring, Maria Bayard; Laude, Vincent; Khelif, Abdelkrim

    2009-01-01

    The acousto-optical interaction of an optical wave confined inside a waveguide and a surface acoustic wave launched by an interdigital transducer (IDT) at the surface of a piezoelectric material is considered. The IDT with high aspect ratio electrodes supports several acoustic modes that are stro......The acousto-optical interaction of an optical wave confined inside a waveguide and a surface acoustic wave launched by an interdigital transducer (IDT) at the surface of a piezoelectric material is considered. The IDT with high aspect ratio electrodes supports several acoustic modes...

  9. Fabrication of High Aspect Ratio SU-8 Structures for Integrated Spectrometers

    DEFF Research Database (Denmark)

    Anhøj, Thomas Aarøe

    2007-01-01

    of photolithography. Successful fabrication of re ection gratings requires a high degree of precision in the photolithographic process. The fabrication process has thus been optimized by optimizing the photolithographic process for fabrication of high aspect ratio structures, i.e. structures with details...... that are small compared to the height of the structure. A decisive factor is the ability of the process to separate closely- spaced structures. The primary measure of quality is thus the aspect ratio of the narrowest trench which it is possible to resolve in the lithographic process. The optimization...

  10. Simple Systematic Synthesis of Periodic Mesoporous Organosilica Nanoparticles with Adjustable Aspect Ratios

    Directory of Open Access Journals (Sweden)

    Mohanty Paritosh

    2009-01-01

    Full Text Available Abstract One-dimensional periodic mesoporous organosilica (PMO nanoparticles with tunable aspect ratios are obtained from a chain-type molecular precursor octaethoxy-1,3,5-trisilapentane. The aspect ratio can be tuned from 2:1 to >20:1 simply by variation in the precursor concentration in acidic aqueous solutions containing constant amounts of triblock copolymer Pluronic P123. The mesochannels are highly ordered and are oriented parallel to the longitudinal axis of the PMO particles. No significant Si–C bond cleavage occurs during the synthesis according to29Si MAS NMR. The materials exhibit surface areas between 181 and 936 m2 g−1.

  11. Monte Carlo simulation with aspect-ratio optimization: anomalous anisotropic scaling in dimerized antiferromagnets.

    Science.gov (United States)

    Yasuda, Shinya; Todo, Synge

    2013-12-01

    We present a method that optimizes the aspect ratio of a spatially anisotropic quantum lattice model during the quantum Monte Carlo simulation, and realizes the virtually isotropic lattice automatically. The anisotropy is removed by using the Robbins-Monro algorithm based on the correlation length in each direction. The method allows for comparing directly the value of the critical amplitude among different anisotropic models, and identifying the universality more precisely. We apply our method to the staggered dimer antiferromagnetic Heisenberg model and demonstrate that the apparent nonuniversal behavior is attributed mainly to the strong size correction of the effective aspect ratio due to the existence of the cubic interaction.

  12. Bragg grating writing in PMMA microstructured polymer optical fibers in less than 7 minutes

    DEFF Research Database (Denmark)

    Bundalo, Ivan-Lazar; Nielsen, Kristian; Markos, Christos;

    2014-01-01

    We demonstrate fiber Bragg grating (FBG) writing in PMMA microstructured Polymer Optical Fibers (mPOFs) using UV Phase Mask technique with writing times shorter than 10 min. The shortest writing time was 6 minutes and 50 seconds and the longest writing time was 8 min and 50 sec. The FBGs were...... written in a 125 x00B5;m PMMA mPOF having 3-rings of holes, the reflection peaks were centred at 632.6 nm and have a reflectivity as high as 26 dB. We also demonstrate how the writing dynamics depends on the intensity of the writing beam....

  13. Dispersion-engineered and highly-nonlinear microstructured polymer optical fibres

    DEFF Research Database (Denmark)

    Frosz, Michael Henoch; Nielsen, Kristian; Hlubina, Petr;

    2009-01-01

    We demonstrate dispersion-engineering of microstructured polymer optical fibres (mPOFs) made of poly(methyl methacrylate) (PMMA). A significant shift of the total dispersion from the material dispersion is confirmed through measurement of the mPOF dispersion using white-light spectral....... To increase the nonlinearity of the mPOFs we investigated doping of PMMA with the highly-nonlinear dye Disperse Red 1. Both doping of a PMMA cane and direct doping of a PMMA mPOF was performed....

  14. Impact of Nanoparticles on the Microstructure and Properties of Immiscible Polymer Blends: Preliminary Investigations

    Science.gov (United States)

    Filippone, G.; Acierno, D.

    2010-06-01

    The control of the morphology represents one of the most important aspects in designing polymer blends. A particular arrangement of the phases known as co-continuity can be promoted within a narrow range of compositions and using appropriate expedients during the mixing process. The distinguishing feature of co-continuous morphologies is the mutual interpenetration of the phases, which is often desirable as it may result in a remarkable combination of functional and structural properties of the blend constituents. Besides acting on the composition and processing conditions, adding nanoparticles in polymer systems with an existing phase-separated morphology such as polymer blends represents an innovative way to promote co-continuity in blends with low amounts of either phase. In the present work we focus on this topic, investigating the ability of nanoparticles to affect the morphology and properties of different kinds of immiscible polymer blends. In addition, the implications of the microstructural changes promoted by the filler on the high-temperature mechanical behavior of the blends are discussed.

  15. A Close Look at Charge Generation in Polymer:Fullerene Blends with Microstructure Control

    KAUST Repository

    Scarongella, Mariateresa

    2015-03-04

    © 2015 American Chemical Society. We reveal some of the key mechanisms during charge generation in polymer:fullerene blends exploiting our well-defined understanding of the microstructures obtained in pBTTT:PCBM systems via processing with fatty acid methyl ester additives. Based on ultrafast transient absorption, electro-absorption, and fluorescence up-conversion spectroscopy, we find that exciton diffusion through relatively phase-pure polymer or fullerene domains limits the rate of electron and hole transfer, while prompt charge separation occurs in regions where the polymer and fullerene are molecularly intermixed (such as the co-crystal phase where fullerenes intercalate between polymer chains in pBTTT:PCBM). We moreover confirm the importance of neat domains, which are essential to prevent geminate recombination of bound electron-hole pairs. Most interestingly, using an electro-absorption (Stark effect) signature, we directly visualize the migration of holes from intermixed to neat regions, which occurs on the subpicosecond time scale. This ultrafast transport is likely sustained by high local mobility (possibly along chains extending from the co-crystal phase to neat regions) and by an energy cascade driving the holes toward the neat domains.

  16. A review on non-linear aeroelasticity of high aspect-ratio wings

    Science.gov (United States)

    Afonso, Frederico; Vale, José; Oliveira, Éder; Lau, Fernando; Suleman, Afzal

    2017-02-01

    Current economic constraints and environmental regulations call for design of more efficient aircraft configurations. An observed trend in aircraft design to reduce the lift induced drag and improve fuel consumption and emissions is to increase the wing aspect-ratio. However, a slender wing is more flexible and subject to higher deflections under the same operating conditions. This effect may lead to changes in dynamic behaviour and in aeroelastic response, potentially resulting in instabilities. Therefore, it is important to take into account geometric non-linearities in the design of high aspect-ratio wings, as well as having accurate computational codes that couple the aerodynamic and structural models in the presence of non-linearities. Here, a review on the state-of-the-art on non-linear aeroelasticity of high aspect-ratio wings is presented. The methodologies employed to analyse high aspect-ratio wings are presented and their applications discussed. Important observations from the state-of-the-art studies are drawn and the current challenges in the field are identified.

  17. Dense high-aspect ratio 3D carbon pillars on interdigitated microelectrode arrays

    DEFF Research Database (Denmark)

    Amato, Letizia; Heiskanen, Arto; Hansen, Rasmus

    2015-01-01

    In this work we present high-aspect ratio carbon pillars (1.4 μm in diameter and ∼11 μm in height) on top of interdigitated electrode arrays to be used for electrochemical applications. For this purpose, different types of 2D and 3D pyrolysed carbon structures were fabricated and characterised...

  18. Hummingbird wing efficacy depends on aspect ratio and compares with helicopter rotors

    NARCIS (Netherlands)

    Kruyt, J.W.; Quicazan Rubio, E.M.; Heijst, van G.J.F.; Altshuler, D.L.; Lentink, D.

    2014-01-01

    Hummingbirds are the only birds that can sustain hovering. This unique flight behaviour comes, however, at high energetic cost. Based on helicopter and aeroplane design theory, we expect that hummingbird wing aspect ratio (AR), which ranges from about 3.0 to 4.5, determines aerodynamic efficacy. Pre

  19. Patterning of periodic high-aspect-ratio nanopores in anatase titanium dioxide from titanium fluoride hydrolysis.

    Science.gov (United States)

    Tevis, Ian D; Stupp, Samuel I

    2011-05-01

    We report straight pores in titanium dioxide produced by a pattern transfer method with titanium fluoride hydrolysis. The resulting films on fluorine-doped tin oxide had pores with diameters of 30 nm and depths of 500 nm, corresponding to aspect ratios of 1:17.

  20. Effects of Confinement on Microstructure and Charge Transport in High Performance Semicrystalline Polymer Semiconductors

    KAUST Repository

    Himmelberger, Scott

    2012-11-23

    The film thickness of one of the most crystalline and highest performing polymer semiconductors, poly(2,5-bis(3-tetradecylthiophen-2-yl)thieno[3,2-b] thiophene) (PBTTT), is varied in order to determine the effects of interfaces and confinement on the microstructure and performance in organic field effect transistors (OFETs). Crystalline texture and overall film crystallinity are found to depend strongly on film thickness and thermal processing. The angular distribution of crystallites narrows upon both a decrease in film thickness and thermal annealing. These changes in the film microstructure are paired with thin-film transistor characterization and shown to be directly correlated with variations in charge carrier mobility. Charge transport is shown to be governed by film crystallinity in films below 20 nm and by crystalline orientation for thicker films. An optimal thickness is found for PBTTT at which the mobility is maximized in unannealed films and where mobility reaches a plateau at its highest value for annealed films. The effects of confinement on the morphology and charge transport properties of poly(2,5-bis(3-tetradecylthiophen-2-yl) thieno[3,2-b]thiophene) (PBTTT) are studied using quantitative X-ray diffraction and field-effect transistor measurements. Polymer crystallinity is found to limit charge transport in the thinnest films while crystalline texture and intergrain connectivity modulate carrier mobility in thicker films. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Surface and Microstructural Failures of PET-Coated ECCS Plates by Salmon-Polymer Interaction

    Directory of Open Access Journals (Sweden)

    Ernesto Zumelzu

    2016-03-01

    Full Text Available The new types of knowledge-intensive, multilayer containers consist of steel plates protected against corrosion by nanometric electrolytic chromium (Cr0 and chromium oxide (Cr2O3 layers chemically bonded to polyethylene terephthalate (PET polymer coating to preserve food. It was observed that after emptying the cans, the salmon adhered to the polymer coating, changing its color, and that this adhesion increased with longer storage times. This work was aimed at determining the product-container interactions and their characterization by X-ray diffraction (XRD, confocal Raman and micro-Raman imaging and scanning electron microscopy (SEM analysis. The zones of adhesion showed surface changes, variations in crystallinity and microstructural degradation of the PET coating. In addition, localized damages altering the functional properties of the multilayer system were observed as microcracking in the chromium layers that protect the steel. The degradation undergone was evaluated and characterized at a surface and microstructural level to establish the failure mechanisms, which were mainly associated with the activity of the adhered muscle and its biochemical components. Finally, a recommendation is done to preserve the useful life and functionality of cans for the preservation and efficient use of resources with an impact on recycling and environmental conservancy.

  2. Localized magnetization reversal processes in cobalt nanorods with different aspect ratios

    Institute of Scientific and Technical Information of China (English)

    Marc Pousthomis[1; Evangelia Anagnostopoulou[1; Ioannis Panagiotopoulos[2,3; Rym Boubekri[1; Weiqing Fang[2; Frederic Ott[2; Kahina Ait Atmane[4; Jean-Yves Piquemal[4; Lise-Marie Lacroix[1; Guillaume Viau[1

    2015-01-01

    We present results of the synthesis of cobalt nanorods using the polyol process and the mechanism of magnetization reversal. We show that the nucleation step is significantly dependent on the nature of the ruthenium chloride used as the nucleating agent. This allows varying the diameter and aspect ratio of the cobalt nanorods independently. Co nanorods with aspect ratio, mean diameter, and mean length in the ranges ARm =3-16, Din= 7-25 nm, and Lm=30-300 nm, respectively, were produced using this method. X-ray diffraction and electron microscopy showed that a strong discrepancy between the structural coherence and morphological aspect ratio can exist because of stacking faults. The coercivity of assemblies of different nanorods was systematically measured, and the highest values were obtained for the smallest diameter and the largest structural coherence length. Micromagnetic simulations were performed to account for the dependence of the coercive field on the diameter. An important observation is that simple coherent magnetization rotation models do not apply to these magnetic nano-objects. Even for very small diameters (Dm = 5-10 nm) well below the theoretical coherent diameter Dcoh(CO)= 24 nm, we observed inhomogeneous reversal modes dominated by nucleation at the rod edges or at structural defects such as stacking faults. We conclude that, in order to produce high-coercivity materials based on nanowires, moderate aspect ratios of 5-10 are sufficient for providing a structural coherence similar to the morphological aspect ratio. Thus, the first priority should be to avoid the formation of stacking faults within the Co nanowires.

  3. A 3-dimensional in vitro model of epithelioid granulomas induced by high aspect ratio nanomaterials

    Directory of Open Access Journals (Sweden)

    Hurt Robert H

    2011-05-01

    Full Text Available Abstract Background The most common causes of granulomatous inflammation are persistent pathogens and poorly-degradable irritating materials. A characteristic pathological reaction to intratracheal instillation, pharyngeal aspiration, or inhalation of carbon nanotubes is formation of epithelioid granulomas accompanied by interstitial fibrosis in the lungs. In the mesothelium, a similar response is induced by high aspect ratio nanomaterials, including asbestos fibers, following intraperitoneal injection. This asbestos-like behaviour of some engineered nanomaterials is a concern for their potential adverse health effects in the lungs and mesothelium. We hypothesize that high aspect ratio nanomaterials will induce epithelioid granulomas in nonadherent macrophages in 3D cultures. Results Carbon black particles (Printex 90 and crocidolite asbestos fibers were used as well-characterized reference materials and compared with three commercial samples of multiwalled carbon nanotubes (MWCNTs. Doses were identified in 2D and 3D cultures in order to minimize acute toxicity and to reflect realistic occupational exposures in humans and in previous inhalation studies in rodents. Under serum-free conditions, exposure of nonadherent primary murine bone marrow-derived macrophages to 0.5 μg/ml (0.38 μg/cm2 of crocidolite asbestos fibers or MWCNTs, but not carbon black, induced macrophage differentiation into epithelioid cells and formation of stable aggregates with the characteristic morphology of granulomas. Formation of multinucleated giant cells was also induced by asbestos fibers or MWCNTs in this 3D in vitro model. After 7-14 days, macrophages exposed to high aspect ratio nanomaterials co-expressed proinflammatory (M1 as well as profibrotic (M2 phenotypic markers. Conclusions Induction of epithelioid granulomas appears to correlate with high aspect ratio and complex 3D structure of carbon nanotubes, not with their iron content or surface area. This model

  4. Rapid transfer of hierarchical microstructures onto biomimetic polymer surfaces with gradually tunable water adhesion from slippery to sticky superhydrophobicity

    Science.gov (United States)

    Chen, An-Fu; Huang, Han-Xiong

    2016-02-01

    Biomimetic superhydrophobic surfaces are generally limited to extremely high or quite low water droplet adhesion. The present work proposes flexible template replication methods for bio-inspired polypropylene (PP) surfaces with microtopographies and gradually tunable water droplet adhesion in one step using microinjection compression molding (μ-ICM). A dual-level microstructure appears on PP surfaces prepared using a flexible template. The microstructures obtained under low and high mold temperatures exhibit low-aspect-ratio (AR) micropillars with semi-spherical top and high-AR ones with conical top, resulting in the surfaces with high-adhesive hydrophobicity and low-adhesive superhydrophobicity, respectively. Further, silica nanoparticles (SNPs) coated on templates are transferred to viscous state-dominated melt during its filling in μ-ICM, and firmly adhered to the skin of the replicas, forming hierarchical microstructures on PP surfaces. The hydrophilic and hydrophobic SNPs on high-AR micropillared surfaces help achieve extremely high (petal effect) and extremely low (lotus effect) adhesion on superhydrophobic surfaces, respectively. The hybrid SNPs on low-AR micropillars change the Wenzel state-dominated surface to Cassie-Baxter state-dominated surface and preserves medium adhesion with superhydrophobicity. The proposed methods for fast and mass replication of superhydrophobic surfaces with the dual-level or hierarchical microtopography can be excellent candidates for the development of microfluidics, sensors, and labs on chip.

  5. Thermal stability of mesoporous silica-coated gold nanorods with different aspect ratios

    Energy Technology Data Exchange (ETDEWEB)

    Gergely-Fülöp, Eszter, E-mail: fulop.eszter@ttk.mta.hu; Zámbó, Dániel, E-mail: zambo.daniel@ttk.mta.hu; Deák, András, E-mail: deak.andras@ttk.mta.hu

    2014-12-15

    The effect of different temperatures (up to 900 °C) on the morphology of mesoporous silica-coated gold nanorods was systematically investigated. Gold nanorods with different aspect ratios (AR ranging from 2.5 to 4.3) were coated with a 15 nm thick mesoporous silica shell. Silicon supported monolayers of the particles were annealed in the temperature range of 300–900 °C. The resulting changes in particle morphology were investigated using scanning electron microscopy and visible wavelength extinction spectroscopy. The silica coating generally improved the stability of the nanorods from ca. 250 °C by several hundreds degree Celsius. For nanorods with AR < 3 the shape and the aspect ratio change is only moderate up to 700 °C. At 900 °C these nanorods became spherical. For nanorods with AR>3, lower stability was found as the aspect ratio decrease was more significant and they transformed into spherical particles already at 700 °C. It was confirmed by investigating empty silica shells that the observed conformal change of the shell material when annealing core/shell particles is dictated by the deformation of the core particle. This also implies that a significant mechanical stress is exerted on the shell upon core deformation. In accordance with this, for the highest aspect ratio (AR ∼ 4) nanorod the shell breaks up at 900 °C and the gold cores were partially released and coalesced into large spherical particles. - Highlights: • Deformation of mesoporous silica-coated gold nanorods upon annealing up to 900 °C. • The silica shell protects the gold cores from turning into spheres up to 500 °C. • Decreasing thermal stability with increasing aspect ratio. • Deformation of the silica shell dictated by the shape change of the gold core. • Core induced break-up of the shell for high aspect ratio nanorods.

  6. Effect of Aspect Ratio and Boundary Conditions in Modeling Shape Memory Alloy Nanostructures with 3D Coupled Dynamic Phase-Field Theories

    Directory of Open Access Journals (Sweden)

    R. Dhote

    2016-01-01

    Full Text Available The behavior of shape memory alloy (SMA nanostructures is influenced by strain rate and temperature evolution during dynamic loading. The coupling between temperature, strain, and strain rate is essential to capture inherent thermomechanical behavior in SMAs. In this paper, we propose a new 3D phase-field model that accounts for two-way coupling between mechanical and thermal physics. We use the strain-based Ginzburg-Landau potential for cubic-to-tetragonal phase transformations. The variational formulation of the developed model is implemented in the isogeometric analysis framework to overcome numerical challenges. We have observed a complete disappearance of the out-of-plane martensitic variant in a very high aspect ratio SMA domain as well as the presence of three variants in equal portions in a low aspect ratio SMA domain. The dependence of different boundary conditions on the microstructure morphology has been examined energetically. The tensile tests on rectangular prism nanowires, using the displacement based loading, demonstrate the shape memory effect and pseudoelastic behavior. We have also observed that higher strain rates, as well as the lower aspect ratio domains, resulting in high yield stress and phase transformations occur at higher stress during dynamic axial loading.

  7. A high aspect ratio SU-8 fabrication technique for hollow microneedles for transdermal drug delivery and blood extraction

    Science.gov (United States)

    Chaudhri, Buddhadev Paul; Ceyssens, Frederik; De Moor, Piet; Van Hoof, Chris; Puers, Robert

    2010-06-01

    Protein drugs, e.g. hormonal drugs, cannot be delivered orally to a patient as they get digested in the gastro-intestinal (GI) tract. Thus, it is imperative that these kinds of drugs are delivered transdermally through the skin. To provide for real-time feedback as well as to test independently for various substances in the blood, we also need a blood sampling system. Microneedles can perform both these functions. Further, microneedles made of silicon or metal have the risk of breaking inside the skin thereby leading to complications. SU-8, being approved of as being biocompatible by the Food and Drug Agency (FDA) of the United States, is an attractive alternative because firstly it is a polymer material, thereby reducing the chances of breakages inside the skin, and secondly it is a negative photoresist, thereby leading to ease of fabrication. Thus, here we present very tall (around 1600 µm) SU-8 polymer-based hollow microneedles fabricated by a simple and repeatable process, which are a very good candidate for transdermal drug delivery as well as blood extraction. The paper elaborates on the details that allow the fabrication of such extreme aspect ratios (>100).

  8. High aspect ratio tungsten grating on ultrathin Si membranes for extreme UV lithography

    Science.gov (United States)

    Peng, Xinsheng; Ying, Yulong

    2016-09-01

    Extreme ultraviolet lithography is one of the modern lithography tools for high-volume manufacturing with 22 nm resolution and beyond. But critical challenges exist to the design and fabrication of large-scale and highly efficient diffraction transmission gratings, significantly reducing the feature sizes down to 22 nm and beyond. To achieve such a grating, the surface flatness, the line edge roughness, the transmission efficiency and aspect ratio should be improved significantly. Delachat et al (2015 Nanotechnology 26 108262) develop a full process to fabricate a tungsten diffraction grating on an ultrathin silicon membrane with higher aspect ratio up to 8.75 that met all the aforementioned requirements for extreme ultraviolet lithography. This process is fully compatible with standard industrial extreme ultraviolet lithography.

  9. Maintaining high-Q in an optical microresonator coated with high-aspect-ratio gold nanorods

    Science.gov (United States)

    Ganta, D.; Dale, E. B.; Rosenberger, A. T.

    2013-10-01

    We report methods to coat fused-silica microresonators with solution-grown high-aspect-ratio (AR) gold nanorods (NRs). Microresonators coated using our method maintain an optical quality factor (Q) greater than 107 after coating. The more successful method involves silanization of the surface of the microresonator with 3-mercaptopropylmethyldimethoxysilane (MPMDMS), to enable the adhesion of gold NRs. The high-AR NR-coated microresonator combines the field enhancement of localized surface plasmon resonances with the cavity-enhanced evanescent components of high-Q whispering-gallery modes, making it useful for plasmonic sensing applications in the infrared. By coating with NRs having a different aspect ratio, the enhancement regime can be selected within a wide range of wavelengths.

  10. Transmutation of nuclear waste with a low-aspect-ratio Tokamak neutron source

    Energy Technology Data Exchange (ETDEWEB)

    Hong, Bong Guen; Moon, Se Youn [Chonbuk National University, Jeonju (Korea, Republic of)

    2014-10-15

    The transmutation characteristics of transuranics (TRUs) in a transmutation reactor based on a LAR (Low-aspect-ratio) tokamak as a neutron source are investigated. The optimum radial build of a transmutation reactor is found by using a coupled analysis of the tokamak systems and the neutron transport. The dependences of the transmutation characteristics on the aspect ratio A in the range of 1.5 to 2.5 and on the fusion power in the range of 150 to 500 MW are investigated. An equilibrium fuel cycle is developed for effective transmutation, and show that with one unit of the transmutation reactor based on the LAR tokamak producing fusion power in the range of a few hundred MWs, up to 3 PWRs (1.0 GWe capacity) can be supported with a burn-up fraction larger than 50%.

  11. Transmutation of nuclear waste with a low-aspect-ratio tokamak neutron source

    Science.gov (United States)

    Hong, Bong Guen; Moon, Se Youn

    2014-10-01

    The transmutation characteristics of transuranics (TRUs) in a transmutation reactor based on a LAR (Low-aspect-ratio) tokamak as a neutron source are investigated. The optimum radial build of a transmutation reactor is found by using a coupled analysis of the tokamak systems and the neutron transport. The dependences of the transmutation characteristics on the aspect ratio A in the range of 1.5 to 2.5 and on the fusion power in the range of 150 to 500 MW are investigated. An equilibrium fuel cycle is developed for effective transmutation, and show that with one unit of the transmutation reactor based on the LAR tokamak producing fusion power in the range of a few hundred MWs, up to 3 PWRs (1.0 GWe capacity) can be supported with a burn-up fraction larger than 50%.

  12. An implicit wetting and drying approach for non-hydrostatic flows in high aspect ratio domains

    CERN Document Server

    Candy, Adam S

    2013-01-01

    A wetting and drying approach for free surface flows governed by the three-dimensional, non-hydrostatic Navier-Stokes equations in high aspect ratio domains is developed. This has application in the modelling of inundation processes in geophysical domains, where dynamics takes place over a large horizontal extent relative to vertical resolution, such as in the evolution of a tsunami, or an urban fluvial flooding scenario. The approach is novel in that it solves for three dimensional dynamics in these very high aspect ratio domains, to include non-hydrostatic effects and accurately model dispersive processes. These become important in shallow regions with steep gradients, a particularly acute problem where man-made structures exist such as buildings or flood defences in an urban environment. It is implicit in time to allow efficient time integration over a range of mesh element sizes. Specific regularisation methods are introduced to improve conditioning of the full three-dimensional pressure Poisson problem i...

  13. Multiscale Domain Decomposition Methods for Elliptic Problems with High Aspect Ratios

    Institute of Scientific and Technical Information of China (English)

    Jфrg Aarnes; Thomas Y. Hou

    2002-01-01

    In this paper we study some nonoverlapping domain decomposition methods for solving a class of elliptic problems arising from composite materials and flows in porous media which contain many spatial scales. Our preconditioner differs from traditional domain decomposition preconditioners by using a coarse solver which is adaptive to small scale heterogeneous features. While the convergence rate of traditional domain decomposition algorithms using coarse solvers based on linear or polynomial interpolations may deteriorate in the presence of rapid small scale oscillations or high aspect ratios, our preconditioner is applicable to multiplescale problems without restrictive assumptions and seems to have a convergence rate nearly independent of the aspect ratio within the substructures. A rigorous convergence analysis based on the Schwarz framework is carried out, and we demonstrate the efficiency and robustness of the proposed preconditioner through numerical experiments which include problems with multiple-scale coefficients, as well problems with continuous scales.

  14. Selective aspect ratio of CNTs based on annealing temperature by TCVD method

    Science.gov (United States)

    Yousefi, Amin Termeh; Mahmood, Mohamad Rusop; Ikeda, Shoichiro

    2016-07-01

    Various aspect ratios of CNTs reported based on alteration of annealing temperature using thermal-chemical vapor deposition (TCVD) method. Also the growth dependent and independent parameters of the carbon nanotube (CNTs) array were studied as a function of synthesis method. The FESEM images indicate that the nanotubes are approximately perpendicular to the surface of the silicon substrate and form carbon nanotubes in different aspect ratios according to the applied annealing temperature. Furthermore, due to the optimized results it can be observed that, the mechanism of the CNTs growth is still present in the annealing step as well as deposition process and the most CNTs with crystalline aspect, produced in the annealing temperature, which was optimized at 700 - 900 ˚C. This result demonstrates that the growth rate, mass production, diameter, density, and crystallinity of CNT can be controlled by the annealing temperature.

  15. Computational design of low aspect ratio wing-winglets for transonic wind-tunnel testing

    Science.gov (United States)

    Kuhlman, John M.; Brown, Christopher K.

    1989-01-01

    A computational design has been performed for three different low aspect ratio wing planforms fitted with nonplanar winglets; one of the three planforms has been selected to be constructed as a wind tunnel model for testing in the NASA LaRC 7 x 10 High Speed Wind Tunnel. A design point of M = 0.8, CL approx = 0.3 was selected, for wings of aspect ratio equal to 2.2, and leading edge sweep angles of 45 and 50 deg. Winglet length is 15 percent of the wing semispan, with a cant angle of 15 deg, and a leading edge sweep of 50 deg. Winglet total area equals 2.25 percent of the wing reference area. This report summarizes the design process and the predicted transonic performance for each configuration.

  16. High Yield Synthesis of Aspect Ratio Controlled Graphenic Materials from Anthracite Coal in Supercritical Fluids.

    Science.gov (United States)

    Sasikala, Suchithra Padmajan; Henry, Lucile; Yesilbag Tonga, Gulen; Huang, Kai; Das, Riddha; Giroire, Baptiste; Marre, Samuel; Rotello, Vincent M; Penicaud, Alain; Poulin, Philippe; Aymonier, Cyril

    2016-05-24

    This paper rationalizes the green and scalable synthesis of graphenic materials of different aspect ratios using anthracite coal as a single source material under different supercritical environments. Single layer, monodisperse graphene oxide quantum dots (GQDs) are obtained at high yield (55 wt %) from anthracite coal in supercritical water. The obtained GQDs are ∼3 nm in lateral size and display a high fluorescence quantum yield of 28%. They show high cell viability and are readily used for imaging cancer cells. In an analogous experiment, high aspect ratio graphenic materials with ribbon-like morphology (GRs) are synthesized from the same source material in supercritical ethanol at a yield of 6.4 wt %. A thin film of GRs with 68% transparency shows a surface resistance of 9.3 kΩ/sq. This is apparently the demonstration of anthracite coal as a source for electrically conductive graphenic materials.

  17. Fabrication of nanopore and nanoparticle arrays with high aspect ratio AAO masks

    Science.gov (United States)

    Li, Z. P.; Xu, Z. M.; Qu, X. P.; Wang, S. B.; Peng, J.; Mei, L. H.

    2017-03-01

    How to use high aspect ratio anodic aluminum oxide (AAO) membranes as an etching and evaporation mask is one of the unsolved problems in the application of nanostructured arrays. Here we describe the versatile utilizations of the highly ordered AAO membranes with a high aspect ratio of more than 20 used as universal masks for the formation of various nanostructure arrays on various substrates. The result shows that the fabricated nanopore and nanoparticle arrays of substrates inherit the regularity of the AAO membranes completely. The flat AAO substrates and uneven AAO frontages were attached to the Si substrates respectively as an etching mask, which demonstrates that the two kinds of replication, positive and negative, represent the replication of the mirroring of Si substrates relative to the flat AAO substrates and uneven AAO frontages. Our work is a breakthrough for the broad research field of surface nano-masking.

  18. Light emitting diode with high aspect ratio submicron roughness for light extraction and methods of forming

    Science.gov (United States)

    Li, Ting

    2013-08-13

    The surface morphology of an LED light emitting surface is changed by applying a reactive ion etch (RIE) process to the light emitting surface. High aspect ratio, submicron roughness is formed on the light emitting surface by transferring a thin film metal hard-mask having submicron patterns to the surface prior to applying a reactive ion etch process. The submicron patterns in the metal hard-mask can be formed using a low cost, commercially available nano-patterned template which is transferred to the surface with the mask. After subsequently binding the mask to the surface, the template is removed and the RIE process is applied for time duration sufficient to change the morphology of the surface. The modified surface contains non-symmetric, submicron structures having high aspect ratio which increase the efficiency of the device.

  19. Non-destructive automatic determination of aspect ratio and cross-sectional properties of fibres

    DEFF Research Database (Denmark)

    Miettinen, Arttu; Ojala, Antti; Wikström, Lisa

    2015-01-01

    A novel method for computerised estimation of the aspect ratio distribution and various cross-sectional geometrical properties of fibres in short-fibre reinforced composites is proposed. The method, based on X-ray micro-computed tomography, is non-destructive and does not require user intervention....... Based on results on specially fabricated model material, the accuracy and precision of the method seems adequate. The method is applied in analysing a manufacturing process of wood fibre reinforced thermoplastic composite. The results indicate a significant decrease of the aspect ratio of fibres during...... the processing steps. Finally, the feasibility of the method is assessed by estimating parameters of a micromechanical model for flax fibre composites and comparing the results with those from tensile tests. © 2015 Elsevier Ltd. All rights reserved....

  20. Nanofabrication of low extinction coefficient and high-aspect-ratio Si structures for metaphotonic applications

    Science.gov (United States)

    Lee, JeongYub; Song, Byonggwon; Kim, Jaekwan; Lee, Chang-Won; Han, Seunghoon; Baik, Chan-Wook; Jeong, Heejeong; Kim, Yongsung; Lee, Chang Seung

    2016-09-01

    We investigated forming of high refractive index (n), low extinction coefficient (k) of Si dielectrics in visible wavelength ranges. To decrease k, pulsed green laser annealing (GLA) with line beam of a 532-nm wavelength was applied in this study for homogeneous melting. By AFM, XRD and TEM analysis, we examined the defect reduction in various conditions during poly-crystallization. We achieved dielectric nanostructures having optical properties of n>4.2, k<0.06 at 550 nm wavelength and fine pitches down to 40 nm (aspect ratio 3:1) and 130 nm (aspect ratio 7:1) with +/-5% size accuracy. Finally, we realized optical metasurfaces for optical band filters, flat lens and beam deflectors.

  1. Micro precision casting based on investment casting for micro structures with high aspect ratio

    Institute of Scientific and Technical Information of China (English)

    YANG Chuang; LI Bang-sheng; REN Ming-xing; FU Heng-zhi

    2009-01-01

    Microcasting is one of the significant technologies for the production of metallic micro parts with high aspect ratio (ratio of flow length to diameter). A micro precision casting technology based on investment casting using centrifugal method was investigated. The micro parts of Zn-4%Al alloy with an aspect ratio up to 200 was produced at the centrifugal speed of 1 500 r/min and the mold temperature of 270 ℃. The investigations on the relationship between flow length and rotational speed were carried out. For microcasting, the flow length is not only dependent on the centrifugal speed under the constant centrifugal radius, but also on the preheating temperature of mold. The flow length increases as the rotational speed and the mold temperature increase, and is much higher at a mold temperature of 270 ℃ than at other mold temperatures.

  2. RCD Large Aspect-Ratio Tokamak Equilibrium with Magnetic Islands: a Perturbed Approach

    Institute of Scientific and Technical Information of China (English)

    F.L.Braga

    2013-01-01

    Solutions of Grad-Shafranov (GS) equation with Reversed Current Density (RCD) profiles present magnetic islands when the magnetic flux is explicitly dependent on the poloidal angle.In this work it is shown that a typical cylindrical (large aspect-ratio) RCD equilibrium configuration perturbed by the magnetic tield of a circular loop (simulating a divertor) is capable of generate magnetic islands,due to the poloidal symmetry break of the GS equilibrium solution.

  3. Strong geographical variation in wing aspect ratio of a damselfly, Calopteryx maculata (Odonata: Zygoptera

    Directory of Open Access Journals (Sweden)

    Christopher Hassall

    2015-08-01

    Full Text Available Geographical patterns in body size have been described across a wide range of species, leading to the development of a series of fundamental biological rules. However, shape variables are less well-described despite having substantial consequences for organism performance. Wing aspect ratio (AR has been proposed as a key shape parameter that determines function in flying animals, with high AR corresponding to longer, thinner wings that promote high manoeuvrability, low speed flight, and low AR corresponding to shorter, broader wings that promote high efficiency long distance flight. From this principle it might be predicted that populations living in cooler areas would exhibit low AR wings to compensate for reduced muscle efficiency at lower temperatures. I test this hypothesis using the riverine damselfly, Calopteryx maculata, sampled from 34 sites across its range margin in North America. Nine hundred and seven male specimens were captured from across the 34 sites (mean = 26.7 ± 2.9 SE per site, dissected and measured to quantify the area and length of all four wings. Geometric morphometrics were employed to investigate geographical variation in wing shape. The majority of variation in wing shape involved changes in wing aspect ratio, confirmed independently by geometric morphometrics and wing measurements. There was a strong negative relationship between wing aspect ratio and the maximum temperature of the warmest month which varies from west-east in North America, creating a positive relationship with longitude. This pattern suggests that higher aspect ratio may be associated with areas in which greater flight efficiency is required: regions of lower temperatures during the flight season. I discuss my findings in light of research of the functional ecology of wing shape across vertebrate and invertebrate taxa.

  4. Patterned growth of high aspect ratio silicon wire arrays at moderate temperature

    Science.gov (United States)

    Morin, Christine; Kohen, David; Tileli, Vasiliki; Faucherand, Pascal; Levis, Michel; Brioude, Arnaud; Salem, Bassem; Baron, Thierry; Perraud, Simon

    2011-04-01

    High aspect ratio silicon wire arrays with excellent pattern fidelity over wafer-scale area were grown by chemical vapor deposition at moderate temperature, using a gas mixture of silane and hydrogen chloride. An innovative two-step process was developed for in situ doping of silicon wires by diborane. This process led to high p-type doping levels, up to 10 18-10 19 cm -3, without degradation of the silicon wire array pattern fidelity.

  5. Concept definition of KT-2, a large-aspect-ratio diverter tokamak with FWCD

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sung Kyoo; Chang, In Soon; Chung, Moon Kyoo; Hwang, Chul Kyoo; Lee, Kwang Won; In, Sang Ryul; Choi, Byung Ho; Hong, Bong Keun; Oh, Byung Hoon; Chung, Seung Ho; Yoon, Byung Joo; Yoon, Jae Sung; Song, Woo Sub [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of); Chang, Choong Suk; Chang, Hong Yung; Choi, Duk In; Nam, Chang Heui [Korea Advanced Inst. of Science and Technology, Taejon (Korea, Republic of); Chung, Kyoo Sun [Hanyang Univ., Seoul (Korea, Republic of); Hong, Sang Heui [Seoul National Univ., Seoul (Korea, Republic of); Kang, Heui Dong [Kyungpook National Univ., Taegu (Korea, Republic of); Lee, Jae Koo [Pohang Inst. of Science and Technology, Kyungnam (Korea, Republic of)

    1994-11-01

    A concept definition of the KT-2 tokamak is made. The research goal of the machine is to study the `advanced tokamak` physics and engineering issues on the mid size large-aspect-ratio diverter tokamak with intense RF heating (>5 MW). Survey of the status of the research fields, the physics basis for the concept, operation scenarios, as well as machine design concept are presented. (Author) 86 refs., 17 figs., 22 tabs.

  6. SUEX process optimization for ultra-thick high-aspect ratio LIGA imaging

    Science.gov (United States)

    Johnson, Donald W.; Goettert, Jost; Singh, Varshni; Yemane, Dawit

    2011-04-01

    oven, taken out and cooled to RT then relaxed up to 3 days before development to reduce stress. Development was done in PGMEA for up to 3 hours for the 1000μm thick samples followed by a short IPA rinse and drying in air. Very high aspect ratios of 100 or more have been routinely patterned with nearly perfectly straight sidewalls (~1-1.5μm deviation for a 1mm tall structure) and excellent image fidelity.

  7. Flight Loads Prediction of High Aspect Ratio Wing Aircraft Using Multibody Dynamics

    Directory of Open Access Journals (Sweden)

    Michele Castellani

    2016-01-01

    Full Text Available A framework based on multibody dynamics has been developed for the static and dynamic aeroelastic analyses of flexible high aspect ratio wing aircraft subject to structural geometric nonlinearities. Multibody dynamics allows kinematic nonlinearities and nonlinear relationships in the forces definition and is an efficient and promising methodology to model high aspect ratio wings, which are known to be prone to structural nonlinear effects because of the high deflections in flight. The multibody dynamics framework developed employs quasi-steady aerodynamics strip theory and discretizes the wing as a series of rigid bodies interconnected by beam elements, representative of the stiffness distribution, which can undergo arbitrarily large displacements and rotations. The method is applied to a flexible high aspect ratio wing commercial aircraft and both trim and gust response analyses are performed in order to calculate flight loads. These results are then compared to those obtained with the standard linear aeroelastic approach provided by the Finite Element Solver Nastran. Nonlinear effects come into play mainly because of the need of taking into account the large deflections of the wing for flight loads computation and of considering the aerodynamic forces as follower forces.

  8. Neoclassical toroidal plasma viscosity with effects of finite banana width for finite aspect ratio tokamaks

    Science.gov (United States)

    Shaing, K. C.; Sabbagh, S. A.

    2016-07-01

    Theory for neoclassical toroidal plasma viscosity has been developed to model transport phenomena, especially, toroidal plasma rotation for tokamaks with broken symmetry. Theoretical predictions are in agreement with the results of the numerical codes in the large aspect ratio limit. The theory has since been extended to include effects of finite aspect ratio and finite plasma β. Here, β is the ratio of the plasma thermal pressure to the magnetic field pressure. However, there are cases where the radial wavelength of the self-consistent perturbed magnetic field strength B on the perturbed magnetic surface is comparable to the width of the trapped particles, i.e., bananas. To accommodate those cases, the theory for neoclassical toroidal plasma viscosity is further extended here to include the effects of the finite banana width. The extended theory is developed using the orbit averaged drift kinetic equation in the low collisionality regimes. The results of the theory can now be used to model plasma transport, including toroidal plasma rotation, in real finite aspect ratio, and finite plasma β tokamaks with the radial wavelength of the perturbed symmetry breaking magnetic field strength comparable to or longer than the banana width.

  9. Aspect-ratio dependence of transient Taylor vortices close to threshold

    Energy Technology Data Exchange (ETDEWEB)

    Manneville, Paul [Laboratoire d' Hydrodynamique, Ecole Polytechnique, Palaiseau (France); Czarny, Olivier [M2P2, UMR 6181 CNRS, Universites d' Aix-Marseille, I.M.T. La Jetee, Technopole de Chateau-Gombert, Marseilles Cedex 20 (France)

    2009-03-15

    We perform a detailed numerical study of transient Taylor vortices arising from the instability of cylindrical Couette flow with the exterior cylinder at rest for radius ratio {eta}=0.5 and variable aspect ratio {gamma}. The result of Abshagen et al. (J Fluid Mech 476:335-343, 2003) that onset transients apparently evolve on a much smaller time-scale than decay transients is recovered. It is shown to be an artefact of time scale estimations based on the Stuart-Landau amplitude equation which assumes frozen space dependence while full space-time dependence embedded in the Ginzburg-Landau formalism needs to be taken into account to understand transients already at moderate aspect ratio. Sub-critical pattern induction is shown to explain the apparently anomalous behaviour of the system at onset while decay follows the Stuart-Landau prediction more closely. The dependence of time scales on boundary effects is studied for a wide range of aspect ratios, including non-integer ones, showing general agreement with the Ginzburg-Landau picture able to account for solutions modulated by Ekman pumping at the disks bounding the cylinders. (orig.)

  10. Relation between self-organized criticality and grain aspect ratio in granular piles

    Science.gov (United States)

    Denisov, D. V.; Villanueva, Y. Y.; Lőrincz, K. A.; May, S.; Wijngaarden, R. J.

    2012-05-01

    We investigate experimentally whether self-organized criticality (SOC) occurs in granular piles composed of different grains, namely, rice, lentils, quinoa, and mung beans. These four grains were selected to have different aspect ratios, from oblong to oblate. As a function of aspect ratio, we determined the growth (β) and roughness (α) exponents, the avalanche fractal dimension (D), the avalanche size distribution exponent (τ), the critical angle (γ), and its fluctuation. At superficial inspection, three types of grains seem to have power-law-distributed avalanches with a well-defined τ. However, only rice is truly SOC if we take three criteria into account: a power-law-shaped avalanche size distribution, finite size scaling, and a universal scaling relation relating characteristic exponents. We study SOC as a spatiotemporal fractal; in particular, we study the spatial structure of criticality from local observation of the slope angle. From the fluctuation of the slope angle we conclude that greater fluctuation (and thus bigger avalanches) happen in piles consisting of grains with larger aspect ratio.

  11. Low aspect ratio micropores for single-particle and single-cell analysis.

    Science.gov (United States)

    Goyal, Gaurav; Mulero, Rafael; Ali, Jamel; Darvish, Armin; Kim, Min Jun

    2015-05-01

    This paper describes microparticle and bacterial translocation studies using low aspect ratio solid-state micropores. Micropores, 5 μm in diameter, were fabricated in 200 nm thick free-standing silicon nitride membranes, resulting in pores with an extremely low aspect ratio, nominally 0.04. For microparticle translocation experiments, sulfonated polystyrene microparticles and magnetic microbeads in size range of 1-4 μm were used. Using the microparticle translocation characteristics, we find that particle translocations result in a change only in the pore's geometrical resistance while the access resistance remains constant. Furthermore, we demonstrate the ability of our micropore to probe high-resolution shape information of translocating analytes using concatenated magnetic microspheres. Distinct current drop peaks were observed for each microsphere of the multibead architecture. For bacterial translocation experiments, nonflagellated Escherichia coli (strain HCB 5) and wild type flagellated Salmonella typhimurium (strain SJW1103) were used. Distinct current signatures for the two bacteria were obtained and this difference in translocation behavior was attributed to different surface protein distributions on the bacteria. Our findings may help in developing low aspect ratio pores for high-resolution microparticle characterization and single-cell analysis.

  12. Global wake instabilities of low aspect-ratio flate-plates

    CERN Document Server

    Marquet, Olivier

    2014-01-01

    This paper investigates the linear destabilization of three-dimensional steady wakes developing behind flate plates placed normal to the incoming flow. Plates characterized by low length-to-width ratio $L$ are considered here. By varying this aspect ratio in the range $1 \\le L \\le 6$ three destabilization scenarios are identified. For very low aspect ratio $1 \\le L \\le 2$, the flow is first destabilized, when increasing the Reynolds number,by a steady global mode that breaks the top/bottom planar reflectional symmetry. The symmetric steady flow bifurcates, via a pitchfork bifurcation, towards an asymmetric steady wakes, similarly to the case of axisymmetric wakes behind sphere and disks. For long aspect ratio, $2.5 \\le L \\le 6$, the first unstable mode also breaks the top/bottom symmetry but is unsteady. A Hopf bifurcation occurs, as for the wake developing behind a two-dimensional circular cylinder. Finally an intermediate regime $2 \\le L \\le 2.5$ is found for which the flow gets first unstable to an unstead...

  13. Plasma-assisted atomic layer deposition of conformal Pt films in high aspect ratio trenches

    Science.gov (United States)

    Erkens, I. J. M.; Verheijen, M. A.; Knoops, H. C. M.; Keuning, W.; Roozeboom, F.; Kessels, W. M. M.

    2017-02-01

    To date, conventional thermal atomic layer deposition (ALD) has been the method of choice to deposit high-quality Pt thin films grown typically from (MeCp)PtMe3 vapor and O2 gas at 300 °C. Plasma-assisted ALD of Pt using O2 plasma can offer several advantages over thermal ALD, such as faster nucleation and deposition at lower temperatures. In this work, it is demonstrated that plasma-assisted ALD at 300 °C also allows for the deposition of highly conformal Pt films in trenches with high aspect ratio ranging from 3 to 34. Scanning electron microscopy inspection revealed that the conformality of the deposited Pt films was 100% in trenches with aspect ratio (AR) up to 34. These results were corroborated by high-precision layer thickness measurements by transmission electron microscopy for trenches with an aspect ratio of 22. The role of the surface recombination of O-radicals and the contribution of thermal ALD reactions is discussed.

  14. Zeonex-PMMA microstructured polymer optical FBGs for simultaneous humidity and temperature sensing.

    Science.gov (United States)

    Woyessa, Getinet; Pedersen, Jens K M; Fasano, Andrea; Nielsen, Kristian; Markos, Christos; Rasmussen, Henrik K; Bang, Ole

    2017-03-15

    In this Letter, we report for the first time, to the best of our knowledge, the fabrication and characterization of a Zeonex/PMMA microstructured polymer optical fiber (mPOF) Bragg grating sensor for simultaneous monitoring of relative humidity (RH) and temperature. The sensing element (probe) is based on two separate in-line fiber Bragg gratings (FBGs) inscribed in the fabricated mPOF. A root mean square deviation of 0.8% RH and 0.6°C in the range of 10%-90% RH and 20°C-80°C was found. The developed mPOFBG sensor constitutes an efficient route toward low-cost, easy-to-fabricate and compact multi-parameter sensing solutions.

  15. Role of Cellulose Nanocrystals on the Microstructure of Maleic Anhydride Plasma Polymer Thin Films.

    Science.gov (United States)

    Brioude, Michel M; Roucoules, Vincent; Haidara, Hamidou; Vonna, Laurent; Laborie, Marie-Pierre

    2015-07-01

    Recently, it was shown that the microstructure of a maleic anhydride plasma polymer (MAPP) could be tailored ab initio by adjusting the plasma process parameters. In this work, we aim to investigate the ability of cellulose nanocrystals (CNCs) to induce topographical structuration. Thus, a new approach was designed based on the deposition of MAPP on CNCs model surfaces. The nanocellulosic surfaces were produced by spin-coating the CNC suspension on a silicon wafer substrate and on a hydrophobic silicon wafer substrate patterned with circular hydrophilic microsized domains (diameter of 86.9 ± 4.9 μm), resulting in different degrees of CNC aggregation. By depositing the MAPP over these surfaces, it was possible to observe that the surface fraction of nanostructures increased from 20% to 35%. This observation suggests that CNCs can act as nucleation points resulting in more structures, although a critical density of the CNCs is required.

  16. Dispersion-modulation by high material loss in microstructured polymer optical fibers

    DEFF Research Database (Denmark)

    Frosz, Michael Henoch

    2009-01-01

    -induced dispersion significantly modifies the wavelengths for which there is phase-match. Depending on the pump wavelength, the waveguide disper­sion, and the loss peaks, it is possible for the output spectrum to either be unaffected by the loss-induced dispersion modulation, or to show an in......The influence of strong loss peaks on the dispersion (through the Kramers-Kronig relations) of a nonlinear waveguide is investigated theore­ti­cally. It is found specifically for degenerate four-wave mixing in a poly(methyl methacrylate) microstructured polymer optical fiber that the loss......­crea­se in the efficiency of nonlinear spectral broadening, compared to the ex­pected efficiency when ignoring the loss-induced dispersion modulation....

  17. On the microstructural information of the short-lived positron lifetime component in polymer metallic composites

    Energy Technology Data Exchange (ETDEWEB)

    Salgueiro, W. [IFIMAT-UN Centro (Argentina); Somoza, A. [IFIMAT-UN Centro (Argentina); Comision de Investigaciones Cientificas de la Provincia de Buenos Aires, Tandil (Argentina); Goyanes, S. [LPMPyMC, Dept. de Fisica, Facultad de Ciencias Exactas y Naturales, Univ. Nacional de Buenos Aires, Ciudad Univ. (Argentina); Dept. de Materiales, CNEA, Buenos Aires (Argentina); Rubiolo, G. [LPMPyMC, Dept. de Fisica, Facultad de Ciencias Exactas y Naturales, Univ. Nacional de Buenos Aires, Ciudad Univ. (Argentina); Consejo Nacional de Investigaciones Cientificas y Tecnicas (Argentina); Marzocca, A. [LPMPyMC, Dept. de Fisica, Facultad de Ciencias Exactas y Naturales, Univ. Nacional de Buenos Aires, Ciudad Univ. (Argentina); Consolati, G. [Istituto Nazionale di Fisica della Materia, Milan (Italy); Politecnico di Milano, Milan (Italy). Dipt. di Fisica

    2001-07-16

    Composite materials made of a polymer matrix and rigid particles normally display important residual internal stresses produced during the fabrication process. In fact, this phenomenon is a consequence of the differences in the thermal expansion characteristics between both phases. The presence of these internal stresses in the compound has a strong influence on the mechanical behavior of the material and depends on the cure process, filler type, shape, content and dispersion. The internal stresses in the composite with aluminum filler charge were recently evaluated by the authors using mechanical test and positron lifetime spectroscopy. The aim of the present note is to go deeper into the interpretation of the above mentioned data, in particular on the microstructural information that it is possible to extract from the short-lived positron lifetime component. Besides, new experimental evidences on the influence of the different metallic charges on the mechanical properties of an epoxy resin composite are given. (orig.)

  18. Deep proton writing of high aspect ratio SU-8 micro-pillars on glass

    Science.gov (United States)

    Ebraert, Evert; Rwamucyo, Ben; Thienpont, Hugo; Van Erps, Jürgen

    2016-12-01

    Deep proton writing (DPW) is a fabrication technology developed for the rapid prototyping of polymer micro-structures. We use SU-8, a negative resist, spincoated in a layer up to 720 μm-thick in a single step on borosilicate glass, for irradiation with a collimated 12 MeV energy proton beam. Micro-pillars with a slightly conical profile are irradiated in the SU-8 layer. We determine the optimal proton fluence to be 1.02 × 104 μm-2, with which we are able to repeatably achieve micro-pillars with a top-diameter of 138 ± 1 μm and a bottom-diameter of 151 ± 3 μm. The smallest fabricated pillars have a top-diameter of 57 ± 5 μm. We achieved a root-mean-square sidewall surface roughness between 19 nm and 35 nm for the fabricated micro-pillars, measured over an area of 5 × 63.7 μm. We briefly discuss initial testing of two potential applications of the fabricated micro-pillars. Using ∼100 μm-diameter pillars as waveguides for gigascale integration optical interconnect applications, has shown a 4.7 dB improvement in optical multimode fiber-to-fiber coupling as compared to the case where an air-gap is present between the fibers at the telecom wavelength of 1550 nm. The ∼140 μm-diameter pillars were used for mold fabrication with silicone casting. The resulting mold can be used for hydrogel casting, to obtain hydrogel replicas mimicking human tissue for in vitro bio-chemical applications.

  19. Nanometer scale high-aspect-ratio trench etching at controllable angles using ballistic reactive ion etching

    Energy Technology Data Exchange (ETDEWEB)

    Cybart, Shane; Roediger, Peter; Ulin-Avila, Erick; Wu, Stephen; Wong, Travis; Dynes, Robert

    2012-11-30

    We demonstrate a low pressure reactive ion etching process capable of patterning nanometer scale angled sidewalls and three dimensional structures in photoresist. At low pressure the plasma has a large dark space region where the etchant ions have very large highly-directional mean free paths. Mounting the sample entirely within this dark space allows for etching at angles relative to the cathode with minimal undercutting, resulting in high-aspect ratio nanometer scale angled features. By reversing the initial angle and performing a second etch we create three-dimensional mask profiles.

  20. High Confinement Mode and Edge Localized Mode Characteristics in a Near-Unity Aspect Ratio Tokamak.

    Science.gov (United States)

    Thome, K E; Bongard, M W; Barr, J L; Bodner, G M; Burke, M G; Fonck, R J; Kriete, D M; Perry, J M; Schlossberg, D J

    2016-04-29

    Tokamak experiments at near-unity aspect ratio A≲1.2 offer new insights into the self-organized H-mode plasma confinement regime. In contrast to conventional A∼3 plasmas, the L-H power threshold P_{LH} is ∼15× higher than scaling predictions, and it is insensitive to magnetic topology, consistent with modeling. Edge localized mode (ELM) instabilities shift to lower toroidal mode numbers as A decreases. These ultralow-A operations enable heretofore inaccessible J_{edge}(R,t) measurements through an ELM that show a complex multimodal collapse and the ejection of a current-carrying filament.

  1. Morphology and aspect ratio of bismuth nanoparticles embedded in a zinc matrix

    Energy Technology Data Exchange (ETDEWEB)

    Song, Tae Eun; Wilde, Gerhard; Peterlechner, Martin [Institute für Materialphysik, Wilhelm-Klemm-Straße 10, D-48149 Münster (Germany)

    2014-12-15

    Nanoscale Bi particles embedded in a Zn matrix were obtained by casting and melt-spinning, resulting in quenching rate-dependent sizes and shapes. With decreasing Bi particle size, an increasing aspect ratio was observed. Due to high resolution transmission electron microscopy performed for different orientations of the nanoparticles and the matrix, the three-dimensional shape and the respective crystallographic orientations of the Bi nanoparticles as well as the orientation relationship with the matrix have been evaluated. It is suggested that the size-dependence of the nanoparticle morphologies has a strong impact on their thermal stabilities thus affecting the size dependence of the melting temperature.

  2. High aspect ratio MEMS capacitor for high frequency impedance matching applications

    DEFF Research Database (Denmark)

    Yalcinkaya, Arda Deniz; Jensen, Søren; Hansen, Ole

    2003-01-01

    We present a microelectromechanical tunable capacitor with a low control voltage, a wide tuning range and adequate electrical quality factor. The device is fabricated in a single-crystalline silicon layer using deep reactive ion etching (DRIE) for obtaining high-aspect ratio (> 20) parallel comb-...... response and it was found that the device is a suitable passive component to be used in impedance matching applications, band-pass filtering or voltage controlled oscillators in the Very High Frequency (VHF) and Ultra High Frequency (UHF) bands....

  3. Study of blade aspect ratio on a compressor front stage aerodynamic and mechanical design report

    Science.gov (United States)

    Burger, G. D.; Lee, D.; Snow, D. W.

    1979-01-01

    A single stage compressor was designed with the intent of demonstrating that, for a tip speed and hub-tip ratio typical of an advanced core compressor front stage, the use of low aspect ratio can permit high levels of blade loading to be achieved at an acceptable level of efficiency. The design pressure ratio is 1.8 at an adiabatic efficiency of 88.5 percent. Both rotor and stator have multiple-circular-arc airfoil sections. Variable IGV and stator vanes permit low speed matching adjustments. The design incorporates an inlet duct representative of an engine transition duct between fan and high pressure compressor.

  4. Morphology and aspect ratio of bismuth nanoparticles embedded in a zinc matrix

    Science.gov (United States)

    Song, Tae Eun; Wilde, Gerhard; Peterlechner, Martin

    2014-12-01

    Nanoscale Bi particles embedded in a Zn matrix were obtained by casting and melt-spinning, resulting in quenching rate-dependent sizes and shapes. With decreasing Bi particle size, an increasing aspect ratio was observed. Due to high resolution transmission electron microscopy performed for different orientations of the nanoparticles and the matrix, the three-dimensional shape and the respective crystallographic orientations of the Bi nanoparticles as well as the orientation relationship with the matrix have been evaluated. It is suggested that the size-dependence of the nanoparticle morphologies has a strong impact on their thermal stabilities thus affecting the size dependence of the melting temperature.

  5. Differential inertial focusing of particles in curved low-aspect-ratio microchannels

    Energy Technology Data Exchange (ETDEWEB)

    Russom, Aman; Gupta, Amit K; Nagrath, Sunitha; Di Carlo, Dino; Edd, Jon F; Toner, Mehmet [BioMEMS Resource Center, Center for Engineering in Medicine and Surgical Services, Massachusetts General Hospital, Shriners Hospital for Children, and Harvard Medical School, Boston, MA 02114 (United States)], E-mail: aman@kth.se

    2009-07-15

    Microfluidic-based manipulation of particles is of great interest due to the insight it provides into the physics of hydrodynamic forces. Here, we study a particle-size-dependent phenomenon based on differential inertial focusing that utilizes the flow characteristics of curved, low aspect ratio (channel width >> height), microfluidic channels. We report the emergence of two focusing points along the height of the channel (z-plane), where different sized particles are focused and ordered in evenly spaced trains at correspondingly different lateral positions within the channel cross-section. We applied the system for continuous ordering and separation of suspension particles.

  6. Sharp-Tip Silver Nanowires Mounted on Cantilevers for High-Aspect-Ratio High-Resolution Imaging.

    Science.gov (United States)

    Ma, Xuezhi; Zhu, Yangzhi; Kim, Sanggon; Liu, Qiushi; Byrley, Peter; Wei, Yang; Zhang, Jin; Jiang, Kaili; Fan, Shoushan; Yan, Ruoxue; Liu, Ming

    2016-11-09

    Despite many efforts to fabricate high-aspect-ratio atomic force microscopy (HAR-AFM) probes for high-fidelity, high-resolution topographical imaging of three-dimensional (3D) nanostructured surfaces, current HAR probes still suffer from unsatisfactory performance, low wear-resistivity, and extravagant prices. The primary objective of this work is to demonstrate a novel design of a high-resolution (HR) HAR AFM probe, which is fabricated through a reliable, cost-efficient benchtop process to precisely implant a single ultrasharp metallic nanowire on a standard AFM cantilever probe. The force-displacement curve indicated that the HAR-HR probe is robust against buckling and bending up to 150 nN. The probes were tested on polymer trenches, showing a much better image fidelity when compared with standard silicon tips. The lateral resolution, when scanning a rough metal thin film and single-walled carbon nanotubes (SW-CNTs), was found to be better than 8 nm. Finally, stable imaging quality in tapping mode was demonstrated for at least 15 continuous scans indicating high resistance to wear. These results demonstrate a reliable benchtop fabrication technique toward metallic HAR-HR AFM probes with performance parallel or exceeding that of commercial HAR probes, yet at a fraction of their cost.

  7. Aqueous solution route to high-aspect-ratio zinc oxide nanostructures on indium tin oxide substrates.

    Science.gov (United States)

    Ku, Chen-Hao; Wu, Jih-Jen

    2006-07-06

    High-aspect-ratio ZnO nanowires and nanotubes are formed on indium tin oxide (ITO) substrates using a three-step route at low temperatures. The three steps, including successive ionic layer absorption and reaction (SILAR) deposition of the ZnO seed layer, hydrothermal annealing of the seed layer, and chemical bath deposition (CBD) of the one-dimensional (1D) ZnO nanostructures, are all conducted in aqueous solutions at temperatures below 120 degrees C. Both the hydrothermal annealing of the SILAR seed layer and the low-concentration precursor solution employed in the CBD process are crucial in order to synthesize the uniform and high-aspect-ratio ZnO nanostructures on the ITO substrate. TEM analyses reveal that both the nanowire and the nanotube possess the single-crystal structure and are grown along [001] direction. Room-temperature cathodoluminescence spectrum of the 1D ZnO nanostructures shows a sharp ultraviolet emission at 375 nm and a broad green-band emission.

  8. Control of size and aspect ratio in hydroquinone-based synthesis of gold nanorods

    Science.gov (United States)

    Morasso, Carlo; Picciolini, Silvia; Schiumarini, Domitilla; Mehn, Dora; Ojea-Jiménez, Isaac; Zanchetta, Giuliano; Vanna, Renzo; Bedoni, Marzia; Prosperi, Davide; Gramatica, Furio

    2015-08-01

    In this article, we describe how it is possible to tune the size and the aspect ratio of gold nanorods obtained using a highly efficient protocol based on the use of hydroquinone as a reducing agent by varying the amounts of CTAB and silver ions present in the "seed-growth" solution. Our approach not only allows us to prepare nanorods with a four times increased Au3+ reduction yield, when compared with the commonly used protocol based on ascorbic acid, but also allows a remarkable reduction of 50-60 % of the amount of CTAB needed. In fact, according to our findings, the concentration of CTAB present in the seed-growth solution do not linearly influence the final aspect ratio of the obtained nanorods, and an optimal concentration range between 30 and 50 mM has been identified as the one that is able to generate particles with more elongated shapes. On the optimized protocol, the effect of the concentration of Ag+ ions in the seed-growth solution and the stability of the obtained particles has also been investigated.

  9. Diffusion of dilute gas in arrays of randomly distributed, vertically aligned, high-aspect-ratio cylinders

    Science.gov (United States)

    Guerra, Carlos

    2017-01-01

    In this work we modelled the diffusive transport of a dilute gas along arrays of randomly distributed, vertically aligned nanocylinders (nanotubes or nanowires) as opposed to gas diffusion in long pores, which is described by the well-known Knudsen theory. Analytical expressions for (i) the gas diffusion coefficient inside such arrays, (ii) the time between collisions of molecules with the nanocylinder walls (mean time of flight), (iii) the surface impingement rate, and (iv) the Knudsen number of such a system were rigidly derived based on a random-walk model of a molecule that undergoes memoryless, diffusive reflections from nanocylinder walls assuming the molecular regime of gas transport. It can be specifically shown that the gas diffusion coefficient inside such arrays is inversely proportional to the areal density of cylinders and their mean diameter. An example calculation of a diffusion coefficient is delivered for a system of titanium isopropoxide molecules diffusing between vertically aligned carbon nanotubes. Our findings are important for the correct modelling and optimisation of gas-based deposition techniques, such as atomic layer deposition or chemical vapour deposition, frequently used for surface functionalisation of high-aspect-ratio nanocylinder arrays in solar cells and energy storage applications. Furthermore, gas sensing devices with high-aspect-ratio nanocylinder arrays and the growth of vertically aligned carbon nanotubes need the fundamental understanding and precise modelling of gas transport to optimise such processes. PMID:28144565

  10. Thermal behavior in the cracking reaction zone of scramjet cooling channels at different channel aspect ratios

    Science.gov (United States)

    Zhang, Silong; Feng, Yu; Jiang, Yuguang; Qin, Jiang; Bao, Wen; Han, Jiecai; Haidn, Oskar J.

    2016-10-01

    To study the thermal behavior in the cracking reaction zone of regeneratively cooled scramjet cooling channels at different aspect ratios, 3-D model of fuel flow in terms of the fuel's real properties and cracking reaction is built and validated through experiments. The whole cooling channel is divided into non-cracking and cracking reaction zones. Only the cracking reaction zone is studied in this article. The simulation results indicate that the fuel conversion presents a similar distribution with temperature because the fuel conversion in scramjet cooling channels is co-decided by the temperature and velocity but the temperature plays the dominate role. For the cases given in this paper, increasing the channel aspect ratio will increase the pressure drop and it is not beneficial for reducing the wall temperature because of the much severer thermal stratification, larger conversion non-uniformity, the corresponding M-shape velocity profile which will cause local heat transfer deterioration and the decreased chemical heat absorption. And the decreased chemical heat absorption caused by stronger temperature and conversion non-uniformities is bad for the utilization of chemical heat sink, chemical recuperation process and the ignition performance.

  11. Nanofabrication of high aspect ratio structures using an evaporated resist containing metal

    Science.gov (United States)

    Con, Celal; Zhang, Jian; Cui, Bo

    2014-05-01

    Organic electron beam resists are typically not resistant to the plasma etching employed to transfer the pattern into the underlying layer. Here, the authors present the incorporation of a metal hard mask material into negative resist polystyrene by co-evaporation of the polystyrene and the metal onto a substrate. With a volume ratio of 1:15 between Cr and polystyrene, this nanocomposite resist showed an etching selectivity to silicon one order higher than pure polystyrene resist. Silicon structures of 100 nm width and 3.5 μm height (aspect ratio 1:35) were obtained using a non-switching deep silicon etching recipe with SF6 and C4F8 gas. Moreover, unlike the common spin coating method, evaporated nanocomposite resist can be coated onto irregular and non-flat surfaces such as optical fibers and AFM cantilevers. As a proof of concept, we fabricated high aspect ratio structures on top of an AFM cantilever. Nanofabrication on non-flat surfaces may find applications in the fields of (AFM) tip enhanced Raman spectroscopy for chemical analysis and lab-on-fiber technology.

  12. Impact of Aspect Ratio and Solar Heating on Street Conyn Air Temperature

    Directory of Open Access Journals (Sweden)

    Rizwan Ahmed Memon

    2011-01-01

    Full Text Available The results obtained from RNG (Re-Normalization Group version of k-? turbulence model are reported in this study. The model is adopted to elucidate the impact of different building aspect ratios (i.e., ratio of building-height-to-street-canyon-width and solar heating on temperatures in street canyon. The validation of Navier-Stokes and energy transport equations showed that the model prediction for air-temperature and ambient wind provides reasonable accuracy. The model was applied on AR (Aspect Ratios one to eight and surface temperature difference (??s-a of 2 -8. Notably, air-temperatures were higher in high AR street canyons in particular on the leeward side of the street canyon. Further investigation showed that the difference between the air-temperature of high and low AR street canyons ( AR was positive and high with higher ??s-a. Conversely, the AR become negative and low gradually with lower values of ??s-a. These results could be very beneficial for the city and regional planners, civil engineers and HVAC experts who design street canyons and strive for human thermal comfort with minimum possible energy requirements.

  13. FULLY CONVECTIVE MAGNETO-ROTATIONAL TURBULENCE IN LARGE ASPECT-RATIO SHEARING BOXES

    Energy Technology Data Exchange (ETDEWEB)

    Bodo, G.; Rossi, P. [INAF, Osservatorio Astronomico di Torino, Strada Osservatorio 20, I-10025 Pino Torinese (Italy); Cattaneo, F. [The Computation Institute, The University of Chicago, 5735 South Ellis Avenue, Chicago, IL 60637 (United States); Mignone, A., E-mail: bodo@oato.inaf.it [Dipartimento di Fisica, Univesità di Torino, via Pietro Giuria 1, I-10125 Torino (Italy)

    2015-01-20

    We present a numerical study of turbulence and dynamo action in stratified shearing boxes with both finite and zero net magnetic flux. We assume that the fluid obeys the perfect gas law and has finite thermal diffusivity. The latter is chosen to be small enough so that vigorous convective states develop. The properties of these convective solutions are analyzed as the aspect ratio of the computational domain is varied and as the value of the mean field is increased. For the cases with zero net flux, we find that a well-defined converged state is obtained for large enough aspect ratios. In the converged state, the dynamo can be extremely efficient and can generate substantial toroidal flux. We identify solutions in which the toroidal field is mostly symmetric about the mid-plane and solutions in which it is mostly anti-symmetric. The symmetric solutions are found to be more efficient at transporting angular momentum and can give rise to a luminosity that is up to an order of magnitude larger than the corresponding value for the anti-symmetric states. In the cases with a finite net flux, the system appears to spend most of the time in the symmetric states.

  14. Braiding of submarine channels controlled by aspect ratio similar to rivers

    Science.gov (United States)

    Foreman, Brady Z.; Lai, Steven Y. J.; Komatsu, Yuhei; Paola, Chris

    2015-09-01

    The great majority of submarine channels formed by turbidity and density currents are meandering in planform; they consist of a single, sinuous channel that transports a turbid, dense flow of sediment from submarine canyons to ocean floor environments. Braided turbidite systems consisting of multiple, interconnected channel threads are conspicuously rare. Furthermore, such systems may not represent the spontaneous planform instability of true braiding, but instead result from erosive processes or bathymetric variability. In marked contrast to submarine environments, both meandering and braided planforms are common in fluvial systems. Here we present experiments of subaqueous channel formation conducted at two laboratory facilities. We find that density currents readily produce a braided planform for flow aspect ratios of depth to width that are similar to those that produce river braiding. Moreover, we find that stability model theory for river planform morphology successfully describes submarine channels in both experiments and the field. On the basis of these observations, we propose that the rarity of braided submarine channels is explained by the generally greater flow depths in submarine systems, which necessitate commensurately greater widths to achieve the required aspect ratio, along with feedbacks among flow thickness, suspended sediment concentration and channel relief that induce greater levee deposition rates and limit channel widening.

  15. Dynamics of the Coherent Structures in a Supersonic Rectangular Jet of Aspect Ratio 2

    Science.gov (United States)

    Viswanath, Kamal; Corrigan, Andrew; Johnson, Ryan; Kailasanath, Kazhikathra; Gutmark, Ephraim; University of Cincinnati Team; LaboratoriesComputational Physics; Fluid Dynamics Team

    2016-11-01

    Asymmetric exhaust nozzle configurations, in particular rectangular, are likely to become more important in the future for both civilian and military aircraft. Various nozzle geometry features including the presence of sharp corners impact the evolution of the cross-sectional shape of the jet and its mixing features. Asymmetric nozzles potentially offer a passive way of affecting mixing for low aspect ratio jets through both large-scale entrainment due to coherent structures and fine scale mixing at the corners. Data is presented that show the dynamic evolution of the coherent structures for an ideally expanded rectangular nozzle of aspect ratio 2. The sense of the vortex pairs setup through the self-induction at the corners and stretching of the azimuthal vortex ring into streamwise vortices results in diagonal elongation of the time-averaged jet cross-section and contraction at the sides. The phase averaged velocity contours further clearly show the effect of mixing at the sharp corners and the deformation of the rectangular exit cross-section as it propagates downstream. It is observed that the dominant vortex pairs in this case work against axis-switching.

  16. Stable bootstrap-current driven equilibria for low aspect ratio tokamaks

    Energy Technology Data Exchange (ETDEWEB)

    Miller, R.L.; Lin-Liu, Y.R.; Turnbull, A.D.; Chan, V.S. [General Atomics, San Diego, CA (United States); Pearlstein, L.D. [Lawrence Livermore National Lab., CA (United States); Sauter, O.; Villard, L. [Ecole Polytechnique Federale, Lausanne (Switzerland). Centre de Recherche en Physique des Plasma (CRPP)

    1996-09-01

    Low aspect ratio tokamaks can potentially provide a high ratio of plasma pressure to magnetic pressure {beta} and high plasma current I at a modest size, ultimately leading to a high power density compact fusion power plant. For the concept to be economically feasible, bootstrap current must be a major component of the plasma. A high value of the Troyon factor {beta}{sub N} and strong shaping are required to allow simultaneous operation at high {beta} and high bootstrap current fraction. Ideal magnetohydrodynamic stability of a range of equilibria at aspect 1.4 is systematically explored by varying the pressure profile and shape. The pressure and current profiles are constrained in such a way as to assure complete bootstrap current alignment. Both {beta}{sub N} and {beta} are defined in terms of the vacuum toroidal field. Equilibria with {beta} {sub N}{>=}8 and {beta} {approx_equal}35% to 55% exist which are stable to n = {infinity} ballooning modes, and stable to n = 0,1,2,3 kink modes with a conducting wall. The dependence of {beta} and {beta}{sub N} with respect to aspect ratio is also considered. (author) 9 figs., 14 refs.

  17. Planarization of High Aspect Ratio P-I-N Diode Pillar Arrays for Blanket Electrical Contacts

    Energy Technology Data Exchange (ETDEWEB)

    Voss, L F; Shao, Q; Reinhardt, C E; Graff, R T; Conway, A M; Nikolic, R J; Deo, N; Cheung, C L

    2009-03-05

    Two planarization techniques for high aspect ratio three dimensional pillar structured P-I-N diodes have been developed in order to enable a continuous coating of metal on the top of the structures. The first technique allows for coating of structures with topography through the use of a planarizing photoresist followed by RIE etch back to expose the tops of the pillar structure. The second technique also utilizes photoresist, but instead allows for planarization of a structure in which the pillars are filled and coated with a conformal coating by matching the etch rate of the photoresist to the underlying layers. These techniques enable deposition using either sputtering or electron beam evaporation of metal films to allow for electrical contact to the tops of the underlying pillar structure. These processes have potential applications for many devices comprised of 3-D high aspect ratio structures. Two separate processes have been developed in order to ensure a uniform surface for deposition of an electrode on the {sup 10}Boron filled P-I-N pillar structured diodes. Each uses S1518 photoresist in order to achieve a relatively uniform surface despite the non-uniformity of the underlying detector. Both processes allow for metallization of the final structure and provide good electrical continuity over a 3D pillar structure.

  18. Control of size and aspect ratio in hydroquinone-based synthesis of gold nanorods

    Energy Technology Data Exchange (ETDEWEB)

    Morasso, Carlo, E-mail: cmorasso@dongnocchi.it; Picciolini, Silvia; Schiumarini, Domitilla [Fondazione Don Carlo Gnocchi ONLUS, Laboratory of Nanomedicine and Clinical Biophotonics (LABION) (Italy); Mehn, Dora; Ojea-Jiménez, Isaac [European Commission Joint Research Centre, Institute for Health and Consumer Protection (IHCP) (Italy); Zanchetta, Giuliano [Universitá degli Studi di Milano, Dipartimento di Biotecnologie Mediche e Medicina Traslazionale (Italy); Vanna, Renzo; Bedoni, Marzia [Fondazione Don Carlo Gnocchi ONLUS, Laboratory of Nanomedicine and Clinical Biophotonics (LABION) (Italy); Prosperi, Davide [Università degli Studi di Milano Bicocca, NanoBioLab, Dipartimento di Biotecnologie e Bioscienze (Italy); Gramatica, Furio [Fondazione Don Carlo Gnocchi ONLUS, Laboratory of Nanomedicine and Clinical Biophotonics (LABION) (Italy)

    2015-08-15

    In this article, we describe how it is possible to tune the size and the aspect ratio of gold nanorods obtained using a highly efficient protocol based on the use of hydroquinone as a reducing agent by varying the amounts of CTAB and silver ions present in the “seed-growth” solution. Our approach not only allows us to prepare nanorods with a four times increased Au{sup 3+} reduction yield, when compared with the commonly used protocol based on ascorbic acid, but also allows a remarkable reduction of 50–60 % of the amount of CTAB needed. In fact, according to our findings, the concentration of CTAB present in the seed-growth solution do not linearly influence the final aspect ratio of the obtained nanorods, and an optimal concentration range between 30 and 50 mM has been identified as the one that is able to generate particles with more elongated shapes. On the optimized protocol, the effect of the concentration of Ag{sup +} ions in the seed-growth solution and the stability of the obtained particles has also been investigated.

  19. Bifurcation induced by the aspect ratio in a turbulent Von-K\\'arm\\'an swirling flow

    CERN Document Server

    Liot, Olivier

    2016-01-01

    We evaluate the effect of two experimental parameters on the slow dynamics of a Von-K\\'arm\\'an swirling flow driven by two propellers in a closed cylinder. The first parameter is the inertia mo- mentum of the propellers, and the second parameter is the aspect ratio, i.e. the distance between the propellers $H$ divided by the diameter $D$. We use a cell with a fixed diameter $D$ but where the distance between the propellers can be turned continuously and where the inertia from the pro- pellers can also be changed using different gears. No change on the dynamics is observed when the momentum of inertia is modified. Some dramatic changes of the shear layer position are observed modifying the aspect ratio $\\Gamma=H/D$. A bifurcation of the shear layer position appears. Whereas for low $\\Gamma$ the shear layer position has a smooth evolution when turning the asymmetry between the rotation frequency of the propellers, for high $\\Gamma$ the transition becomes abrupt and a symmetry breaking appears. Secondly we obser...

  20. Simulation and Measurement of Neuroelectrodes' Characteristics with Integrated High Aspect Ratio Nano Structures

    Directory of Open Access Journals (Sweden)

    Christoph Nick

    2015-07-01

    Full Text Available Improving the interface between electrodes and neurons has been the focus of research for the last decade. Neuroelectrodes should show small geometrical surface area and low impedance for measuring and high charge injection capacities for stimulation. Increasing the electrochemically active surface area by using nanoporous electrode material or by integrating nanostructures onto planar electrodes is a common approach to improve this interface. In this paper a simulation approach for neuro electrodes' characteristics with integrated high aspect ratio nano structures based on a point-contact-model is presented. The results are compared with experimental findings conducted with real nanostructured microelectrodes. In particular, effects of carbon nanotubes and gold nanowires integrated onto microelectrodes are described. Simulated and measured impedance properties are presented and its effects onto the transfer function between the neural membrane potential and the amplifier output signal are studied based on the point-contact-model. Simulations show, in good agreement with experimental results, that electrode impedances can be dramatically reduced by the integration of high aspect ratio nanostructures such as gold nanowires and carbon nanotubes. This lowers thermal noise and improves the signal-to-noise ratio for measuring electrodes. It also may increase the adhesion of cells to the substrate and thus increase measurable signal amplitudes.

  1. Large-Area High Aspect Ratio Plasmonic Interference Lithography Utilizing a Single High-k Mode.

    Science.gov (United States)

    Chen, Xi; Yang, Fan; Zhang, Cheng; Zhou, Jing; Guo, L Jay

    2016-04-26

    Plasmonic lithography, which utilizes subwavelength confinement of surface plasmon polartion (SPP) waves, has the capability of breaking the diffraction limit and delivering high resolution. However, all previously reported results suffer from critical issues, such as shallow pattern depth and pattern nonuniformity even over small exposure areas, which limit the application of the technology. In this work, periodic patterns with high aspect ratios and a half-pitch of about 1/6 of the wavelength were achieved with pattern uniformity in square centimeter areas. This was accomplished by designing a special mask and photoresist (PR) system to select a single high spatial frequency mode and incorporating the PR into a waveguide configuration to ensure uniform light exposure over the entire depth of the photoresist layer. In addition to the experimental progress toward large-scale applications of plasmonic interference lithography, the general criteria of designing such an exposure system is also discussed, which can be used for nanoscale fabrication in this fashion for various applications with different requirements for wavelength, pitch, aspect ratio, and structure.

  2. An Empirical Jet-Surface Interaction Noise Model with Temperature and Nozzle Aspect Ratio Effects

    Science.gov (United States)

    Brown, Cliff

    2015-01-01

    An empirical model for jet-surface interaction (JSI) noise produced by a round jet near a flat plate is described and the resulting model evaluated. The model covers unheated and hot jet conditions (1 less than or equal to jet total temperature ratio less than or equal to 2.7) in the subsonic range (0.5 less than or equal to M(sub a) less than or equal to 0.9), surface lengths 0.6 less than or equal to (axial distance from jet exit to surface trailing edge (inches)/nozzle exit diameter) less than or equal to 10, and surface standoff distances (0 less than or equal to (radial distance from jet lipline to surface (inches)/axial distance from jet exit to surface trailing edge (inches)) less than or equal to 1) using only second-order polynomials to provide predictable behavior. The JSI noise model is combined with an existing jet mixing noise model to produce exhaust noise predictions. Fit quality metrics and comparisons to between the predicted and experimental data indicate that the model is suitable for many system level studies. A first-order correction to the JSI source model that accounts for the effect of nozzle aspect ratio is also explored. This correction is based on changes to the potential core length and frequency scaling associated with rectangular nozzles up to 8:1 aspect ratio. However, more work is needed to refine these findings into a formal model.

  3. The Universal Aspect Ratio of Vortices in Rotating Stratifi?ed Flows: Experiments and Observations

    CERN Document Server

    Aubert, Oriane; Gal, Patrice Le; Marcus, Philip S

    2012-01-01

    We validate a new law for the aspect ratio $\\alpha = H/L$ of vortices in a rotating, stratified flow, where $H$ and $L$ are the vertical half-height and horizontal length scale of the vortices. The aspect ratio depends not only on the Coriolis parameter f and buoyancy (or Brunt-Vaisala) frequency $\\bar{N}$ of the background flow, but also on the buoyancy frequency $N_c$ within the vortex and on the Rossby number $Ro$ of the vortex such that $\\alpha = f \\sqrt{[Ro (1 + Ro)/(N_c^2- \\bar{N}^2)]}$. This law for $\\alpha$ is obeyed precisely by the exact equilibrium solution of the inviscid Boussinesq equations that we show to be a useful model of our laboratory vortices. The law is valid for both cyclones and anticyclones. Our anticyclones are generated by injecting fluid into a rotating tank filled with linearly-stratified salt water. The vortices are far from the top and bottom boundaries of the tank, so there is no Ekman circulation. In one set of experiments, the vortices viscously decay, but as they do, they c...

  4. Strain Rate Dependent Deformation of a Polymer Matrix Composite with Different Microstructures Subjected to Off-Axis Loading

    Directory of Open Access Journals (Sweden)

    Xiaojun Zhu

    2014-01-01

    Full Text Available This paper aims to investigate the comprehensive influence of three microstructure parameters (fiber cross-section shape, fiber volume fraction, and fiber off-axis orientation and strain rate on the macroscopic property of a polymer matrix composite. During the analysis, AS4 fibers are considered as elastic solids, while the surrounding PEEK resin matrix exhibiting rate sensitivities are described using the modified Ramaswamy-Stouffer viscoplastic state variable model. The micromechanical method based on generalized model of cells has been used to analyze the representative volume element of composites. An acceptable agreement is observed between the model predictions and experimental results found in the literature. The research results show that the stress-strain curves are sensitive to the strain rate and the microstructure parameters play an important role in the behavior of polymer matrix.

  5. Self-Restoration of Superhydrophobicity on Shape Memory Polymer Arrays with Both Crushed Microstructure and Damaged Surface Chemistry.

    Science.gov (United States)

    Lv, Tong; Cheng, Zhongjun; Zhang, Enshuang; Kang, Hongjun; Liu, Yuyan; Jiang, Lei

    2017-01-01

    Recently, self-healing superhydrophobic surfaces have become a new research focus due to their recoverable wetting performances and wide applications. However, until now, on almost all reported surfaces, only one factor (surface chemistry or microstructure) can be restored. In this paper, a new superhydrophobic surface with self-healing ability in both crushed microstructure and damaged surface chemistry is prepared by creating lotus-leaves-like microstructure on the epoxy shape memory polymer (SMP). Through a simple heating process, the crushed surface microstructure, the damaged surface chemistry, and the surface superhydrophobicity that are destroyed under the external pressure and/or O2 plasma action can be recovered, demonstrating that the obtained superhydrophobic surface has a good self-healing ability in both of the two factors that govern the surface wettability. The special self-healing ability is ascribed to the good shape memory effect of the polymer and the reorganization effect of surface molecules. This paper reports the first use of SMP material to demonstrate the self-healing ability of surface superhydrophobicity, which opens up some new perspectives in designing self-healing superhydrophobic surfaces. Given the properties of this surface, it could be used in many applications, such as self-cleaning coatings, microfluidic devices, and biodetection.

  6. Dihedral influence on lateral-directional dynamic stability on large aspect ratio tailless flying wing aircraft

    Institute of Scientific and Technical Information of China (English)

    Song Lei; Yang Hua; Zhang Yang; Zhang Haoyu; Huang Jun

    2014-01-01

    The influence of dihedral layout on lateral-directional dynamic stability of the tailless flying wing aircraft is discussed in this paper. A tailless flying wing aircraft with a large aspect ratio is selected as the object of study, and the dihedral angle along the spanwise sections is divided into three segments. The influence of dihedral layouts is studied. Based on the stability derivatives cal-culated by the vortex lattice method code, the linearized small-disturbance equations of the lateral modes are used to determine the mode dynamic characteristics. By comparing 7056 configurations with different dihedral angle layouts, two groups of stability optimized dihedral layout concepts are created. Flight quality close to Level 2 requirements is achieved in these optimized concepts without any electric stability augmentation system.

  7. Gust response analysis and wind tunnel test for a high-aspect ratio wing

    Directory of Open Access Journals (Sweden)

    Liu Yi

    2016-02-01

    Full Text Available A theoretical nonlinear aeroelastic response analysis for a flexible high-aspect ratio wing excited by harmonic gust load is presented along with a companion wind tunnel test. A multidisciplinary coupled numerical calculation is developed to simulate the flexible model wing undergoing gust load in the time domain via discrete nonlinear finite element structural dynamic analysis and nonplanar unsteady vortex lattice aerodynamic computation. A dynamic perturbation analysis about a nonlinear static equilibrium is also used to determine the small perturbation flutter boundary. A novel noncontact 3-D camera measurement analysis system is firstly used in the wind tunnel test to obtain the spatial large deformation and responses. The responses of the flexible wing under different static equilibrium states and frequency gust loads are discussed. The fair to good quantitative agreements between the theoretical and experimental results demonstrate that the presented analysis method is an acceptable way to predict the geometrically nonlinear gust response for flexible wings.

  8. All-metal transformer core for a low aspect ratio tokamak

    Energy Technology Data Exchange (ETDEWEB)

    Gates, D.A., E-mail: dgates@pppl.gov [Plasma Physics Laboratory, Princeton University, P.O. Box 451, Princeton, NJ 08543 (United States); Jun, C.; Zatz, I.; Zolfaghari, A. [Plasma Physics Laboratory, Princeton University, P.O. Box 451, Princeton, NJ 08543 (United States)

    2011-01-15

    A novel concept for incorporating an iron core transformer within a axisymmetric toroidal plasma containment device with a high neutron flux is described. This design enables conceptual design of low aspect ratio devices which employ standard transformer-driven plasma startup by using all-metal high resistance inserts between the toroidal field windings. This design avoids the inherent problems of a multi-turn air core transformer which will inevitably suffer from strong neutron bombardment and hence lose the integrity of its insulation, both through long term material degradation and short term neutron induced conductivity. A full 3-dimensional model of the concept has been developed within the MAXWELL program and the resultant loop voltage calculated. The utility of the result is found to be dependent on the resistivity of the high resistance inserts. Useful loop voltage time histories have been obtained using expected resistivities.

  9. Surface tension-induced high aspect-ratio PDMS micropillars with concave and convex lens tips

    KAUST Repository

    Li, Huawei

    2013-04-01

    This paper reports a novel method for the fabrication of 3-dimensional (3D) Polydimethylsiloxane (PDMS) micropillars with concave and convex lens tips in a one-step molding process, using a CO2 laser-machined Poly(methyl methacrylate) (PMMA) mold with through holes. The PDMS micropillars are 4 mm high and have an aspect ratio of 251. The micropillars are formed by capillary force drawing up PDMS into the through hole mold. The concave and convex lens tips of the PDMS cylindrical micropillars are induced by surface tension and are controllable by changing the surface wetting properties of the through holes in the PMMA mold. This technique eliminates the requirements of expensive and complicated facilities to prepare a 3D mold, and it provides a simple and rapid method to fabricate 3D PDMS micropillars with controllable dimensions and tip shapes. © 2013 IEEE.

  10. Pilot Study of Inhaled Aerosols Targeted via Magnetic Alignment of High Aspect Ratio Particles in Rabbits

    Directory of Open Access Journals (Sweden)

    Gillian E. S. Redman

    2011-01-01

    Full Text Available Recently, inhaled pharmaceutical aerosols have seen increased investigation in the treatment of lung cancer, where the inability to deliver adequate therapeutic drug concentrations to tumour sites may be overcome with improved targeted delivery to the site of the tumour. In this study, the feasibility of magnetically targeted delivery of high aspect ratio particles loaded with iron oxide nanoparticles was studied in 19 New Zealand White rabbits. Half of the exposed rabbits had a magnetic field placed externally over their right lung. Iron sensitive magnetic resonance images of the lungs were acquired to determine the iron concentrations in the right and left lung of each animal. The right/left ratio increased in the middle and basal regions of the lung where, due to the morphology of the rabbit lung, this method of targeting is most effective. With further optimization, this technique could be an effective method for increasing the dose of drug delivered to a specific site within the lung.

  11. Millijoule femtosecond micro-Bessel beams for ultra-high aspect ratio machining.

    Science.gov (United States)

    Mitra, Sambit; Chanal, Margaux; Clady, Raphaël; Mouskeftaras, Alexandros; Grojo, David

    2015-08-20

    We report on a functional experimental design for Bessel beam generation capable of handling high-energy ultrashort pulses (up to 1.2 mJ per pulse of 50 fs duration). This allows us to deliver intensities exceeding the breakdown threshold for air or any dielectric along controlled micro-filaments with lengths exceeding 4 mm. It represents an unprecedented upscaling in comparison to recent femtosecond Bessel beam micromachining experiments. We produce void microchannels through glass substrates to demonstrate that aspect ratios exceeding 1200∶1 can be achieved by using single high-intensity pulses. This demonstration must lead to new methodologies for deep-drilling and high-speed cutting applications.

  12. Timesaving microwave assisted synthesis of insulin amyloid fibrils with enhanced nanofiber aspect ratio.

    Science.gov (United States)

    Carvalho, Tiago; Pinto, Ricardo J B; Martins, Manuel A; Silvestre, Armando J D; Freire, Carmen S R

    2016-11-01

    Insulin amyloid fibrils with enhanced aspect ratio, were prepared using a timesaving microwave assisted (MW) methodology, reducing the incubation time from 13 to 2h. The fibrillation process was followed indirectly by Thioflavin T Fluorescence and UV-vis analysis, by measuring the amount of β-sheets formed and the insulin present in solution, respectively. TEM and AFM analysis revealed that the insulin fibrils obtained through the MW method, have very similar lengths but are much thinner than the ones obtained using the conventional method (CM). Additionally, it was verified that the nature of the peptides present in the final insulin fibrils was not affected by microwave irradiation. These morphological differences might reflect on noticeably enhanced mechanical and optical properties that can exploited on the development of advanced bionanomaterials.

  13. Surface-diffusion-driven decay of high-aspect-ratio gratings: existence of morphologically related classes.

    Science.gov (United States)

    Madrid, Marcos A; Salvarezza, Roberto C; Castez, Marcos F

    2013-06-01

    We present numerical and theoretical results concerning the technologically important process of evolution of high-aspect-ratio profiles due to surface diffusion under thermal treatment. We show how a broad class of initial gratings adopt, after a short transient stage, a typical shape that can be accurately described as a curve whose curvature has only two single Fourier modes as a function of the arc-length parameter. Moreover, we introduce a set of evolution equations for the relevant parameters that accounts very accurately for both morphological and kinetic aspects of the transformation processes for these curves in a wide region in parameter space. Regarding the decay of rectangular gratings, our numerical results show the existence of geometrically related classes that asymptotically approach to the same trajectory in parameter space. Gratings belonging to the same class pass through the same sequence of morphologies before reaching the final equilibrium state.

  14. The Capabilities of Electrodischarge Microdrilling of High Aspect Ratio Holes in Ceramic Materials

    Directory of Open Access Journals (Sweden)

    Skoczypiec Sebastian

    2015-09-01

    Full Text Available In the first part of the article the review of ceramic materials drilling possibilities was presented. Among the described methods special attention is paid to electrodischarge drilling. This process have especially been predicted for machining difficult-to-cut electrically conductive materials. The second part consist of the results analysis of electrodischarge microdrilling of siliconized silicon carbide. The experiment involves the impact of current amplitude, discharge voltage and pulse time on the hole depth, side gap, linear tool wear and mean drilling speed. The results shows that electrodischarge drilling is a good alternative when machining inhomogeneous ceramic materials and gives possibility to drill high aspect ratio holes with relatively high efficiency (the drilling speed >2 mm/min.

  15. Static Response of Functionally Graded Material Plate under Transverse Load for Varying Aspect Ratio

    Directory of Open Access Journals (Sweden)

    Manish Bhandari

    2014-01-01

    Full Text Available Functionally gradient materials (FGM are one of the most widely used materials in various applications because of their adaptability to different situations by changing the material constituents as per the requirement. Nowadays it is very easy to tailor the properties to serve specific purposes in functionally gradient material. Most structural components used in the field of engineering can be classified as beams, plates, or shells for analysis purposes. In the present study the power law, sigmoid law and exponential distribution, is considered for the volume fraction distributions of the functionally graded plates. The work includes parametric studies performed by varying volume fraction distributions and aspect ratio. The FGM plate is subjected to transverse UDL (uniformly distributed load and point load and the response is analysed.

  16. Measurement and simulation of jet mass caused by a high-aspect ratio pertubation

    Energy Technology Data Exchange (ETDEWEB)

    Keiter, Paul A [Los Alamos National Laboratory; Cooley, James [Los Alamos National Laboratory; Kyrala, George [Los Alamos National Laboratory; Wilson, Doug [Los Alamos National Laboratory; Blue, Brent [LLNL/GA; Elliott, Jim [LLNL; Edwards, John [LLNL; Robey, Harry [LLNL; Spears, Brian [LLNL

    2009-01-01

    Inertial confinement fusion (ICF) capsule performance can be negatively impacted by the presence of hydrodynamic instabilities. To perform a gas fill on an ICF capsule current plans involve drilling a small hole and inserting a fill tube to inject the gas mixture into the capsule. This introduces a perturbation on the capsule, which can seed hydrodynamic instabilities. The small hole can cause jetting of the shell material into the gas, which might adversely affect the capsule performance. We have performed simulations and experiments to study the hydrodynamic evolution of jets from high-aspect ratio holes, such as the fill tube hole. Although simulations using cold materials over predict the amount of mass in the jet, when a reasonable amount of preheat (< 1 eV) is introduced, the simulations are in better agreement with the experiment.

  17. Measurement and simulation of jet mass caused by a high-aspect ratio hole perturbation

    Energy Technology Data Exchange (ETDEWEB)

    Keiter, Paul A [Los Alamos National Laboratory; Cooley, James H [Los Alamos National Laboratory; Wilson, D C [Los Alamos National Laboratory; Kyrala, George A [Los Alamos National Laboratory; Blue, Brent E [LLNL; Edwards, J [LLNL; Elliott, James B [LLNL; Robey, H F [LLNL; Spears, B [Los Alamos National Laboratory

    2009-01-01

    Inertial confinement fusion (ICF) capsule performance can be negatively impacted by the presence of hydrodynamic instabilities. To perform a gas fill on an ICF capsule, current plans involve drilling a small hole and inserting a fill tube to inject the gas mixture into the capsule. This introduces a perturbation on the capsule, which can seed hydrodynamic instabilities. The small hole can cause jetting of the shell material into the gas, which might adversely affect the capsule performance. We have performed simulations and experiments to study the hydrodynamic evolution of jets from high-aspect ratio holes, such as the fill tube hole. Although simulations using cold materials overpredict the amount of mass in the jet, when a reasonable amount of preheat (<1 eV) is introduced, the simulations are in better agreement with the experiment.

  18. Fabrication of High Aspect Ratio Micro-Penning-Malmberg Gold Plated Silicon Trap Arrays

    CERN Document Server

    Narimannezhad, Alireza; Weber, Marc H; Lynn, Kelvin G

    2013-01-01

    Acquiring a portable high density charged particles trap might consist of an array of micro-Penning-Malmberg traps (microtraps) with substantially lower end barriers potential than conventional Penning-Malmberg traps [1]. We report on the progress of the fabrication of these microtraps designed for antimatter storage such as positrons. The fabrication of large length to radius aspect ratio (1000:1) microtrap arrays involved advanced techniques including photolithography, deep reactive ion etching (DRIE) of silicon wafers to achieve through-vias, gold sputtering of the wafers on the surfaces and inside the vias, and thermal compression bonding of the wafers. This paper describes the encountered issues during fabrication and addresses geometry errors and asymmetries. In order to minimize the patch effects on the lifetime of the trapped positrons, the bonded stacks were gold electroplated to achieve a uniform gold surface. We show by simulation and analytical calculation that how positrons confinement time depen...

  19. Laminar flow in radial flow cell with small aspect ratios: Numerical and experimental study

    DEFF Research Database (Denmark)

    Detry, J. G.; Deroanne, C.; Sindic, M.

    2009-01-01

    Studies on the effect of wall shear stress on soil and biofilm attachment and removal from a surface are one of the many applications of radial axisymmetrical flow. The particular nature of this flow allows taking advantage of a wide range of wall shear Stress applied at the analyzed surface...... in a single experiment. This type of experiments provides a critical radius up to which soil removal occurs. Good models are, however, still needed to convert the experimental data into critical wall shear stress. Analytical models are already available for creeping flow but Computational Fluid Dynamics must...... be applied for experiments performed at higher Reynolds numbers. The present study is a numerical analysis of the radial axisymmetrical flow for aspect ratios of 0.125, 0.25, 0.5 and 1 with inlet pipe Reynolds numbers varying from 0 to 2000, aiming at computing the wall shear stress distribution at any...

  20. Effect of large aspect ratio of biomass particles on carbon burnout in a utility boiler

    Energy Technology Data Exchange (ETDEWEB)

    D. Gera; M.P. Mathur; M.C. Freeman; Allen Robinson [Fluent, Inc./NETL, Morgantown, WV (United States)

    2002-12-01

    This paper reports on the development and validation of comprehensive combustion sub models that include the effect of large aspect ratio of biomass (switchgrass) particles on carbon burnout and temperature distribution inside the particles. Temperature and carbon burnout data are compared from two different models that are formulated by assuming (i) the particles are cylindrical and conduct heat internally, and (ii) the particles are spherical without internal heat conduction, i.e., no temperature gradient exists inside the particle. It was inferred that the latter model significantly underpredicted the temperature of the particle and, consequently, the burnout. Additionally, some results from cofiring biomass (10% heat input) with pulverized coal (90% heat input) are compared with the pulverized coal (100% heat input) simulations and coal experiments in a tangentially fired 150 MW{sub e} utility boiler. 26 refs., 7 figs., 4 tabs.

  1. Design and Simulation of BTT Missile with High-Aspect-Ratio Wing Robust H∞ Autopilot

    Institute of Scientific and Technical Information of China (English)

    CUI Sheng-wang; LIU Li; MA Chun-yan

    2007-01-01

    For the strong coupling among the channels of bank-to-turn (BTT) missile with high-aspect-ratio wing,an autopilot is designed with a two loop control structure robust autopilot design methods.By the inner loop design,the question of pole-zero cancellation is solved,and the stabilization of structured uncertainty is achieved.Through the outer loop of H∞ controller design,the flying performance and robustness can be guaranteed.The nonlinear simulation results show that the autopilot designed has perfect time domain response,and can suppress bad influence of the inertial and kinematics couplings.It can make the missile fly stably in the large flying areas.The control is very effective.

  2. Large-area thermoelectric high-aspect-ratio nanostructures by atomic layer deposition

    Science.gov (United States)

    Ruoho, Mikko; Juntunen, Taneli; Tittonen, Ilkka

    2016-09-01

    We report on the thermoelectric properties of large-area high-aspect-ratio nanostructures. We fabricate the structures by atomic layer deposition of conformal ZnO thin films on track-etched polycarbonate substrate. The resulting structure consists of ZnO tubules which continue through the full thickness of the substrate. The electrical and thermal properties of the structures are studied both in-plane and out-of-plane. They exhibit very low out-of-plane thermal conductivity down to 0.15 W m-1 K-1 while the in-plane sheet resistance of the films was found to be half that of the same film on glass substrate, allowing material-independent doubling of output power of any planar thin-film thermoelectric generator. The wall thickness of the fabricated nanotubes was varied within a range of up to 100 nm. The samples show polycrystalline nature with (002) preferred crystal orientation.

  3. Plasmon assisted 3D microstructuring of gold nanoparticle-doped polymers

    Science.gov (United States)

    Jonušauskas, Linas; Lau, Marcus; Gruber, Peter; Gökce, Bilal; Barcikowski, Stephan; Malinauskas, Mangirdas; Ovsianikov, Aleksandr

    2016-04-01

    3D laser lithography of a negative photopolymer (zirconium/silicon hybrid solgel SZ2080) doped with gold nanoparticles (Au NPs) is performed with a 515 nm and 300 fs laser system and the effect of doping is explored. By varying the laser-generated Au NP doping concentration from 4.8 · 10-6 wt% to 9.8 · 10-3 wt% we find that the fabricated line widths are enlarged by up to 14.8% compared to structures achieved in pure SZ2080. While implicating a positive effect on the photosensitivity, the doping has no adverse impact on the mechanical quality of intricate 3D microstructures produced from the doped nanocompound. Additionally, we found that SZ2080 increases the long term (˜months) colloidal stability of Au NPs in isopropanol. By discussing the nanoparticle-light interaction in the 3D polymer structures we provide implications that our findings might have on other fields, such as biomedicine and photonics.

  4. Implications of in vitro dosimetry on toxicological ranking of low aspect ratio engineered nanomaterials.

    Science.gov (United States)

    Pal, Anoop K; Bello, Dhimiter; Cohen, Joel; Demokritou, Philip

    2015-01-01

    In vitro high throughput screening platforms based on mechanistic injury pathways are been used for hazard assessment of engineered nanomaterials (ENM). Toxicity screening and other in vitro nanotoxicology assessment efforts in essence compare and rank nanomaterials relative to each other. We hypothesize that this ranking of ENM is susceptible to dispersion and dosimetry protocols, which continue to be poorly standardized. Our objective was to quantitate the impact of dosimetry on toxicity ranking of ENM. A set of eight well-characterized and diverse low aspect ratio ENMs, were utilized. The recently developed in vitro dosimetry platform at Harvard, which includes preparation of fairly monodispersed suspensions, measurement of the effective density of formed agglomerates in culture media and fate and transport modeling was used for calculating the effective dose delivered to cells as a function of time. Changes in the dose-response relationships between the administered and delivered dose were investigated with two representative endpoints, cell viability and IL-8 production, in the human monocytic THP-1 cells. The slopes of administered/delivered dose-response relationships changed 1:4.94 times and were ENM-dependent. The overall relative ranking of ENM intrinsic toxicity also changed considerably, matching notably better the in vivo inflammation data (R(2 )= 0.97 versus 0.64). This standardized dispersion and dosimetry methodology presented here is generalizable to low aspect ratio ENMs. Our findings further reinforce the need to reanalyze and reinterpret in vitro ENM hazard ranking data published in the nanotoxicology literature in the light of dispersion and dosimetry considerations (or lack thereof) and to adopt these protocols in future in vitro nanotoxicology testing.

  5. Advanced Fuels Reactor using Aneutronic Rodless Ultra Low Aspect Ratio Tokamak Hydrogenic Plasmas

    Science.gov (United States)

    Ribeiro, Celso

    2015-11-01

    The use of advanced fuels for fusion reactor is conventionally envisaged for field reversed configuration (FRC) devices. It is proposed here a preliminary study about the use of these fuels but on an aneutronic Rodless Ultra Low Aspect Ratio (RULART) hydrogenic plasmas. The idea is to inject micro-size boron pellets vertically at the inboard side (HFS, where TF is very high and the tokamak electron temperature is relatively low because of profile), synchronised with a proton NBI pointed to this region. Therefore, p-B reactions should occur and alpha particles produced. These pellets will act as an edge-like disturbance only (cp. killer pellet, although the vertical HFS should make this less critical, since the unablated part should appear in the bottom of the device). The boron cloud will appear at midplance, possibly as a MARFE-look like. Scaling of the p-B reactions by varying the NBI energy should be compared with the predictions of nuclear physics. This could be an alternative to the FRC approach, without the difficulties of the optimization of the FRC low confinement time. Instead, a robust good tokamak confinement with high local HFS TF (enhanced due to the ultra low aspect ratio and low pitch angle) is used. The plasma central post makes the RULART concept attractive because of the proximity of NBI path and also because a fraction of born alphas will cross the plasma post and dragged into it in the direction of the central plasma post current, escaping vertically into a hole in the bias plate and reaching the direct electricity converter, such as in the FRC concept.

  6. High-Aspect Ratio Bio-Metallic Nanocomposites for Cellular Interactions

    Science.gov (United States)

    Deodhar, Sneha; Huckaby, Justin; Delahoussaye, Miles; DeCoster, Mark A.

    2014-08-01

    We synthesized high aspect ratio composites with biological and metal components. Scanning electron microscopy (SEM) and Transmission Electron Microscopy (TEM) revealed linear morphology and smooth surface texture. SEM, TEM and light microscopy showed that composites have scalable dimensions from nano- to micro-, with diameters as low as 60 nm, lengths exceeding 150 pm, and average aspect ratio of 100. The structures are stable, remaining intact for over one year in dried form and in liquid, and did not aggregate, in contrast to metal nanoparticles such as iron and copper. Many metal nanoparticles are toxic to cells, limiting their use for biological applications. The bio-metallic composites characterized here showed lower toxicity compared to their precursor metal nanoparticles in brain tumor cell cultures. Due to these more biocompatible properties, we tested the ability of the composites to interact with cells. Zeta potential analysis indicated that composites carry a net negative charge (-24.3 ± 2.2 mV), while the starting metal nanoparticles measured (43.3 ± 2.4 mV). We labeled the composites with poly-l-lysine fluorescein isothiocyanate (PLL-FITC), which shifted the potential to 3.5 ± 2.9 mV. It was observed by fluorescence microscopy that composites smaller than cells were internalized by some cells and larger composites remained outside. Cells became fluorescent over time due to leakage of PLL-FITC from the composites which lost fluorescence over time. Higher biocompatibility, low aggregation, and ability to control size distribution of the linear composites may make them ideal vehicles to deliver drugs or other materials to cells, and may be used as a scaffolding material for cells.

  7. A study of high-altitude manned research aircraft employing strut-braced wings of high-aspect-ratio

    Science.gov (United States)

    Smith, P. M.; Deyoung, J.; Lovell, W. A.; Price, J. E.; Washburn, G. F.

    1981-01-01

    The effect of increased wing aspect ratio of subsonic aircraft on configurations with and without strut bracing. Results indicate that an optimum cantilever configuration, with a wing aspect ratio of approximately 26, has a 19% improvement in cruise range when compared to a baseline concept with a wing aspect ratio of approximately 10. An optimum strut braced configuration, with a wing aspect ratio of approximately 28, has a 31% improvment in cruise range when compared to the same baseline concept. This improvement is mainly due to the estimated reduction in wing weight resulting from use of lifting struts. All configurations assume the same mission payload and fuel. The drag characteristics of the wings are enhanced with the use of laminar flow airfoils. A method for determining the extent of attainable natural laminar flow, and methods for preliminary structural design and for aerodynamic analysis of wings lifting struts are presented.

  8. Evolution of the microstructure of unmodified and polymer modified asphalt binders with aging in an accelerated weathering tester.

    Science.gov (United States)

    Menapace, Ilaria; Masad, Eyad

    2016-09-01

    This paper presents findings on the evolution of the surface microstructure of two asphalt binders, one unmodified and one polymer modified, directly exposed to aging agents with increasing durations. The aging is performed using an accelerated weathering tester, where ultraviolet radiation, oxygen and an increased temperature are applied to the asphalt binder surface. Ultraviolet and dark cycles, which simulated the succession of day and night, alternated during the aging process, and also the temperature varied, which corresponded to typical summer day and night temperatures registered in the state of Qatar. Direct aging of an exposed binder surface is more effective in showing microstructural modifications than previously applied protocols, which involved the heat treatment of binders previously aged with standardized methods. With the new protocol, any molecular rearrangements in the binder surface after aging induced by the heat treatment is prevented. Optical photos show the rippling and degradation of the binder surface due to aging. Microstructure images obtained by means of atomic force microscopy show gradual alteration of the surface due to aging. The original relatively flat microstructure was substituted with a profoundly different microstructure, which significantly protrudes from the surface, and is characterized by various shapes, such as rods, round structures and finally 'flower' or 'leaf' structures.

  9. High Rayleigh number convection in rectangular enclosures with differentially heated vertical walls and aspect ratios between zero and unity

    Science.gov (United States)

    Kassemi, Siavash A.

    1988-01-01

    High Rayleigh number convection in a rectangular cavity with insulated horizontal surfaces and differentially heated vertical walls was analyzed for an arbitrary aspect ratio smaller than or equal to unity. Unlike previous analytical studies, a systematic method of solution based on linearization technique and analytical iteration procedure was developed to obtain approximate closed-form solutions for a wide range of aspect ratios. The predicted velocity and temperature fields are shown to be in excellent agreement with available experimental and numerical data.

  10. Formation of Foam-like Microstructural Carbon Material by Carbonization of Porous Coordination Polymers through a Ligand-Assisted Foaming Process.

    Science.gov (United States)

    Kongpatpanich, Kanokwan; Horike, Satoshi; Fujiwara, Yu-Ichi; Ogiwara, Naoki; Nishihara, Hirotomo; Kitagawa, Susumu

    2015-09-14

    Porous carbon material with a foam-like microstructure has been synthesized by direct carbonization of porous coordination polymer (PCP). In situ generation of foaming agents by chemical reactions of ligands in PCP during carbonization provides a simple way to create lightweight carbon material with a foam-like microstructure. Among several substituents investigated, the nitro group has been shown to be the key to obtain the unique foam-like microstructure, which is due to the fast kinetics of gas evolution during carbonization. Foam-like microstructural carbon materials showed higher pore volume and specific capacitance compared to a microporous carbon.

  11. A small perturbation based optimization approach for the frequency placement of high aspect ratio wings

    Science.gov (United States)

    Goltsch, Mandy

    Design denotes the transformation of an identified need to its physical embodiment in a traditionally iterative approach of trial and error. Conceptual design plays a prominent role but an almost infinite number of possible solutions at the outset of design necessitates fast evaluations. The corresponding practice of empirical equations and low fidelity analyses becomes obsolete in the light of novel concepts. Ever increasing system complexity and resource scarcity mandate new approaches to adequately capture system characteristics. Contemporary concerns in atmospheric science and homeland security created an operational need for unconventional configurations. Unmanned long endurance flight at high altitudes offers a unique showcase for the exploration of new design spaces and the incidental deficit of conceptual modeling and simulation capabilities. Structural and aerodynamic performance requirements necessitate light weight materials and high aspect ratio wings resulting in distinct structural and aeroelastic response characteristics that stand in close correlation with natural vibration modes. The present research effort evolves around the development of an efficient and accurate optimization algorithm for high aspect ratio wings subject to natural frequency constraints. Foundational corner stones are beam dimensional reduction and modal perturbation redesign. Local and global analyses inherent to the former suggest corresponding levels of local and global optimization. The present approach departs from this suggestion. It introduces local level surrogate models to capacitate a methodology that consists of multi level analyses feeding into a single level optimization. The innovative heart of the new algorithm originates in small perturbation theory. A sequence of small perturbation solutions allows the optimizer to make incremental movements within the design space. It enables a directed search that is free of costly gradients. System matrices are decomposed

  12. High aspect ratio AFM Probe processing by helium-ion-beam induced deposition.

    Science.gov (United States)

    Onishi, Keiko; Guo, Hongxuan; Nagano, Syoko; Fujita, Daisuke

    2014-11-01

    A Scanning Helium Ion Microscope (SHIM) is a high resolution surface observation instrument similar to a Scanning Electron Microscope (SEM) since both instruments employ finely focused particle beams of ions or electrons [1]. The apparent difference is that SHIMs can be used not only for a sub-nanometer scale resolution microscopic research, but also for the applications of very fine fabrication and direct lithography of surfaces at the nanoscale dimensions. On the other hand, atomic force microscope (AFM) is another type of high resolution microscopy which can measure a three-dimensional surface morphology by tracing a fine probe with a sharp tip apex on a specimen's surface.In order to measure highly uneven and concavo-convex surfaces by AFM, the probe of a high aspect ratio with a sharp tip is much more necessary than the probe of a general quadrangular pyramid shape. In this paper we report the manufacture of the probe tip of the high aspect ratio by ion-beam induced gas deposition using a nanoscale helium ion beam of SHIM.Gas of platinum organic compound was injected into the sample surface neighborhood in the vacuum chamber of SHIM. The decomposition of the gas and the precipitation of the involved metal brought up a platinum nano-object in a pillar shape on the normal commercial AFM probe tip. A SHIM system (Carl Zeiss, Orion Plus) equipped with the gas injection system (OmniProbe, OmniGIS) was used for the research. While the vacuum being kept to work, we injected platinum organic compound ((CH3)3(CH3C5H4)Pt) into the sample neighborhood and irradiated the helium ion beam with the shape of a point on the apex of the AFM probe tip. It is found that we can control the length of the Pt nano-pillar by irradiation time of the helium ion beam. The AFM probe which brought up a Pt nano-pillar is shown in Figure 1. It is revealed that a high-aspect-ratio Pt nano-pillar of ∼40nm diameter and up to ∼2000 nm length can be grown. In addition, for possible heating

  13. Jet noise of high aspect-ratio rectangular nozzles with application to pneumatic high-lift devices

    Science.gov (United States)

    Munro, Scott Edward

    Circulation control wings are a type of pneumatic high-lift device that have been extensively researched as to their aerodynamic benefits. However, there has been little research into the possible airframe noise reduction benefits. The key element of noise is the jet noise associated with the jet sheet emitted from the blowing slot. This jet sheet is essentially a high aspect-ratio rectangular jet. This study directly compared far-field noise emissions from a state-of-the-art circulation control wing high lift configuration, and a conventional wing also configured for high lift. Results indicated that a circulation control wing had a significant acoustic advantage over a conventional wing for identical lift performance. A high aspect-ratio nozzle was fabricated to study the general characteristics of high aspect-ratio jets with aspect ratios from 100 to 3000. The results of this study provided the basic elements in understanding how to reduce the noise from a circulation control wing. High aspect-ratio nozzle results showed that the jet noise of this type of jet was proportional to the 8th power of the jet velocity. It was also found that the jet noise was proportional to the slot height to the 3/2 power and slot width to the 1/2 power. Fluid dynamic experiments were also performed on the high aspect-ratio nozzle. Single hot-wire experiments indicated that the jet exhaust from the high aspect-ratio nozzle was similar to a 2-d turbulent jet. Two-wire space-correlation experiments were performed to attempt to find a relationship between the slot height of the jet and the length-scale of the flow noise generating turbulence structure. The turbulent eddy convection velocity was also calculated, and was found to vary with the local centerline velocity, and also as a function of the frequency of the eddy.

  14. Scalable shape-controlled fabrication of curved microstructures using a femtosecond laser wet-etching process

    Energy Technology Data Exchange (ETDEWEB)

    Bian, Hao; Yang, Qing; Chen, Feng, E-mail: chenfeng@mail.xjtu.edu.cn; Liu, Hewei; Du, Guangqing; Deng, Zefang; Si, Jinhai; Yun, Feng; Hou, Xun

    2013-07-01

    Materials with curvilinear surface microstructures are highly desirable for micro-optical and biomedical devices. However, realization of such devices efficiently remains technically challenging. This paper demonstrates a facile and flexible method to fabricate curvilinear microstructures with controllable shapes and dimensions. The method composes of femtosecond laser exposures and chemical etching process with the hydrofluoric acid solutions. By fixed-point and step-in laser irradiations followed by the chemical treatments, concave microstructures with different profiles such as spherical, conical, bell-like and parabola were fabricated on silica glasses. The convex structures were replicated on polymers by the casting replication process. In this work, we used this technique to fabricate high-quality microlens arrays and high-aspect-ratio microwells which can be used in 3D cell culture. This approach offers several advantages such as high-efficient, scalable shape-controllable and easy manipulations. - Highlights: • We demonstrate a flexible method to fabricate curvilinear microstructures. • This method composes of femtosecond laser exposures and chemical etching process. • Concave microstructures with different profiles were fabricated on silica glasses. • High-quality microlens arrays and high-aspect-ratio microwells were fabricated.

  15. Gust response analysis and wind tunnel test for a high-aspect ratio wing

    Institute of Scientific and Technical Information of China (English)

    Liu Yi; Xie Changchuan; Yang Chao; Cheng Jialin

    2016-01-01

    A theoretical nonlinear aeroelastic response analysis for a flexible high-aspect ratio wing excited by harmonic gust load is presented along with a companion wind tunnel test. A multidisci-plinary coupled numerical calculation is developed to simulate the flexible model wing undergoing gust load in the time domain via discrete nonlinear finite element structural dynamic analysis and nonplanar unsteady vortex lattice aerodynamic computation. A dynamic perturbation analysis about a nonlinear static equilibrium is also used to determine the small perturbation flutter bound-ary. A novel noncontact 3-D camera measurement analysis system is firstly used in the wind tunnel test to obtain the spatial large deformation and responses. The responses of the flexible wing under different static equilibrium states and frequency gust loads are discussed. The fair to good quanti-tative agreements between the theoretical and experimental results demonstrate that the presented analysis method is an acceptable way to predict the geometrically nonlinear gust response for flex-ible wings.

  16. High-aspect-ratio photoresist processing for fabrication of high resolution and thick micro-windings

    Science.gov (United States)

    Anthony, Ricky; Laforge, Elias; Casey, Declan P.; Rohan, James F.; O'Mathuna, Cian

    2016-10-01

    DC winding losses remain a major roadblock in realizing high efficiency micro-magnetic components (inductors/transformers). This paper reports an optimized photoresist process using negative tone and acrylic based THB-151N (from JSR Micro), to achieve one of the highest aspect ratio (17:1) and resolution (~5 µm) resist patterns for fabrication of thick (~80 µm) micro-winding using UV lithography. The process was optimized to achieve photoresist widths from 5 µm to 20 µm with resist thickness of ~85 µm in a single spin step. Unlike SU-8, this resist can be readily removed and shows a near-vertical (~91°) electroplated Cu side-wall profile. Moreover, the high resolution compared to available resist processes enables a further reduction in the footprint area and can potentially increase the number of winding thereby increasing the inductance density for micro-magnetic components. Resistance measurements of electroplated copper winding of air-core micro-inductors within the standard 0402 size (0.45 mm2 footprint area) suggested a 42% decrease in resistance (273 mΩ-159 mΩ) with the increase in electroplated Cu thickness (from 50 µm to 80 µm). Reduction of the spacings (from 10 µm to 5 µm) enabled further miniaturisation of the device footprint area (from 0.60 mm2 to 0.45 mm2) without significant increase in resistance.

  17. Numerical investigation of flow on NACA4412 aerofoil with different aspect ratios

    Directory of Open Access Journals (Sweden)

    Demir Hacımurat

    2016-01-01

    Full Text Available In this study, the flow over NACA4412 was investigated both numerically and experimentally at a different Reynolds numbers. The experiments were carried out in a low speed wind tunnel with various angles of attack and different Reynolds numbers (25000 and 50000. Airfoil was manufactured using 3D printer with a various aspect ratios (AR = 1 and AR = 3. Smoke-wire and oil flow visualization methods were used to visualize the surface flow patterns. NACA4412 aerofoil was designed by using SOLIDWORKS. The structural grid of numerical model was constructed by ANSYS ICEM CFD meshing software. Furthermore, ANSYS FLUENT™ software was used to perform numerical calculations. The numerical results were compared with experimental results. Bubble formation was shown in CFD streamlines and smoke-wire experiments at z / c = 0.4. Furthermore, bubble shrunk at z / c = 0.2 by reason of the effects of tip vortices in both numerical and experimental studies. Consequently, it was seen that there was a good agreement between numerical and experimental results.

  18. Shaping of the plasma column in a small aspect ratio tokamak

    Science.gov (United States)

    Herrera, Julio; Arroyo, Ismael; Chavez, Esteban; Segura, Miguel Angel

    2016-10-01

    This is a follow-up to the work presented in a precious meeting, on the conceptual design of a small aspect ratio tokamak of variable configuration. The base parameters for this device would be similar to those in the START tokamak. The shaping of the plasma column is known to have important effects in the plasma performance, including the value of β, bootstrap currents, and intrinsic rotation. The main feature being explored here is the inclusion of independent control coils in the inboard and outboard sides; six in the first case, and up to seven in the latter. By varying the strength in their currents it is possible to achieve a wide variety of shapes: elliptical, conventional D-shape, inverse D-shape, and Bean-shape. As the control coils are activated, the strength of the toroidal magnetic field needs to he weakened, in order to keep reasonable values of the safety factor q . The study presented here is made by means of the 3D-MAPTOR code, which produces the Poincaré maps of the magnetic field lines, given the currents. For this purpose, a seed plasma current must be provided. All studies presented here assume equatorial symmetry, due to limitations in the code.

  19. Aspect Ratio of Receiver Node Geometry based Indoor WLAN Propagation Model

    Science.gov (United States)

    Naik, Udaykumar; Bapat, Vishram N.

    2016-09-01

    This paper presents validation of indoor wireless local area network (WLAN) propagation model for varying rectangular receiver node geometry. The rectangular client node configuration is a standard node arrangement in computer laboratories of academic institutes and research organizations. The model assists to install network nodes for the better signal coverage. The proposed model is backed by wide ranging real time received signal strength measurements at 2.4 GHz. The shadow fading component of signal propagation under realistic indoor environment is modelled with the dependency on varying aspect ratio of the client node geometry. The developed new model is useful in predicting indoor path loss for IEEE 802.11b/g WLAN. The new model provides better performance in comparison to well known International Telecommunication Union and free space propagation models. It is shown that the proposed model is simple and can be a useful tool for indoor WLAN node deployment planning and quick method for the best utilisation of the office space.

  20. Effect of Aspect Ratio on H-mode and ELM Characteristics

    Science.gov (United States)

    Thome, K. E.; Bodner, G. M.; Bongard, M. W.; Burke, M. G.; Fonck, R. J.; Kriete, D. M.

    2015-11-01

    The H-mode confinement regime is achieved at near-unity aspect ratio (A PLH , behaves quite differently at low- A when compared with high- A operations. PLH /PLH_ITPA 08 increases sharply as A is lowered and no difference in PLH for limited and diverted plasmas is observed at A ~ 1 . 2 . No minimum in PLH with density is observed. Some of these results are consistent with the FM3 model for the L-H transition. Two classes of ELMs have been observed. Small, Type III-like ELMs are present at low input power and have n >PLH , they transition to large, Type-I-like ELMs with intermediate 5 < n < 15 . The Type III ELM magnetic structures behave opposite that of high- A plasmas, with n much higher, presumably due to the naturally higher J / B peeling mode drive at low- A . Long-sought measurements of the Jedge (R , t) pedestal collapse during an ELM event show a complex, multimodal pedestal collapse and the subsequent ejection of a current-carrying filament. Work supported by US DOE grant DE-FG02-96ER54375.

  1. Analysis of Interrupted Rectangular Microchannel Heat Sink with High Aspect Ratio

    Directory of Open Access Journals (Sweden)

    Harshin Kamal

    2017-01-01

    Full Text Available A computational modelling of microchannel heat sinks with high aspect ratio has been performed to compare the geometrical features in the plane parallel to the heating surface and to determine the optimum configuration for the best heat transfer characteristics. A periodic thermal development of flow can cause significant heat transfer enhancement. A consensus on a particular geometrical configuration that provides the best heat transfer characteristics has not been reached in the literature, although many novel ideas have been proposed recently. Firstly the validity and applicability of microchannel sink modelling is presented followed by an optimization of parameters of interrupted microchannel heat sink. Consequences of the multichannel effect due to the introduction of transverse microchamber are also presented. It has been shown that the average Nusselt number of the microchannel heat sink increases by the introduction of a transverse microchamber with the additional advantage of a lower pressure drop. There exists an optimum width for the transverse microchamber for which the interrupted microchannel heat sink shows optimum characteristics.

  2. Fabrication and characterization of large arrays of mesoscopic gold rings on large-aspect-ratio cantilevers

    Energy Technology Data Exchange (ETDEWEB)

    Ngo, D. Q.; Petković, I., E-mail: ivana.petkovic@yale.edu; Lollo, A. [Department of Physics, Yale University, New Haven, Connecticut 06520 (United States); Castellanos-Beltran, M. A. [National Institute for Standards and Technology, Boulder, Colorado 80305 (United States); Harris, J. G. E. [Department of Physics, Yale University, New Haven, Connecticut 06520 (United States); Department of Applied Physics, Yale University, New Haven, Connecticut 06520 (United States)

    2014-10-15

    We have fabricated large arrays of mesoscopic metal rings on ultrasensitive cantilevers. The arrays are defined by electron beam lithography and contain up to 10{sup 5} rings. The rings have a circumference of 1 μm, and are made of ultrapure (6N) Au that is deposited onto a silicon-on-insulator wafer without an adhesion layer. Subsequent processing of the SOI wafer results in each array being supported at the end of a free-standing cantilever. To accommodate the large arrays while maintaining a low spring constant, the cantilevers are nearly 1 mm in both lateral dimensions and 100 nm thick. The extreme aspect ratio of the cantilevers, the large array size, and the absence of a sticking layer are intended to enable measurements of the rings' average persistent current in the presence of relatively small magnetic fields. We describe the motivation for these measurements, the fabrication of the devices, and the characterization of the cantilevers' mechanical properties. We also discuss the devices' expected performance in measurements of .

  3. Tunable Ultra-high Aspect Ratio Nanorod Architectures grown on Porous Substrate via Electromigration.

    Science.gov (United States)

    Mansourian, Ali; Paknejad, Seyed Amir; Wen, Qiannan; Vizcay-Barrena, Gema; Fleck, Roland A; Zayats, Anatoly V; Mannan, Samjid H

    2016-02-29

    The interplay between porosity and electromigration can be used to manipulate atoms resulting in mass fabrication of nanoscale structures. Electromigration usually results in the accumulation of atoms accompanied by protrusions at the anode and atomic depletion causing voids at the cathode. Here we show that in porous media the pattern of atomic deposition and depletion is altered such that atomic accumulation occurs over the whole surface and not just at the anode. The effect is explained by the interaction between atomic drift due to electric current and local temperature gradients resulting from intense Joule heating at constrictions between grains. Utilizing this effect, a porous silver substrate is used to mass produce free-standing silver nanorods with very high aspect ratios of more than 200 using current densities of the order of 10(8) A/m(2). This simple method results in reproducible formation of shaped nanorods, with independent control over their density and length. Consequently, complex patterns of high quality single crystal nanorods can be formed in-situ with significant advantages over competing methods of nanorod formation for plasmonics, energy storage and sensing applications.

  4. PITR: a small-aspect-ratio, small-major-radius ignition test reactor

    Energy Technology Data Exchange (ETDEWEB)

    Jassby, D.L.; Bolton, R.A.; Brown, D.I.

    1978-05-01

    The principal objectives of the PITR are to demonstrate the attainment of thermonuclear ignition in D-T, and to develop optimal start-up methods for tokamak power reactors. The design approach is based on minimizing dependence on a central transformer core, which thereby results in a machine of small aspect ratio (A approximately 2 to 2.5) and smaller major radius (R/sub 0/ approximately 2.8 m). Current induction is achieved by a combination of ''leaky OH'' coils, equilibrium-field flux swing, a small central solenoid, and compression. Impurity control is effected by a bundle divertor during the beam-heating phase, and by a cold plasma blanket during the burn. The vacuum vessel is constructed of thin-gauge, double-wall titanium alloy. Sixteen normal-copper TF coils of the compound constant-tension type enable low-stress operation at B/sub max/ = 12.5 T.

  5. Critical Casimir force scaling functions of the two-dimensional Ising model at finite aspect ratios

    Science.gov (United States)

    Hobrecht, Hendrik; Hucht, Alfred

    2017-02-01

    We present a systematic method to calculate the universal scaling functions for the critical Casimir force and the according potential of the two-dimensional Ising model with various boundary conditions. Therefore we start with the dimer representation of the corresponding partition function Z on an L× M square lattice, wrapped around a torus with aspect ratio ρ =L/M . By assuming periodic boundary conditions and translational invariance in at least one direction, we systematically reduce the problem to a 2× 2 transfer matrix representation. For the torus we first reproduce the results by Kaufman and then give a detailed calculation of the scaling functions. Afterwards we present the calculation for the cylinder with open boundary conditions. All scaling functions are given in form of combinations of infinite products and integrals. Our results reproduce the known scaling functions in the limit of thin films ρ \\to 0 . Additionally, for the cylinder at criticality our results confirm the predictions from conformal field theory.

  6. Effects of Winglets on the Drag of a Low-Aspect-Ratio Configuration

    Science.gov (United States)

    Smith, Leigh Ann; Campbell, Richard L.

    1996-01-01

    A wind-tunnel investigation has been performed to determine the effect of winglets on the induced drag of a low-aspect-ratio wing configuration at Mach numbers between 0.30 and 0.85 and a nominal angle-of-attack range from -2 deg to 20 deg. Results of the tests at the cruise lift coefficient showed significant increases in lift-drag ratio for the winglet configuration relative to a wing-alone configuration designed for the same lift coefficient and Mach number. Further, even larger increases in lift-drag ratio were observed at lift coefficients above the design value at all Mach numbers tested. The addition of these winglets had a negligible effect on the static lateral-directional stability characteristics of the configuration. No tests were made to determine the effect of these winglets at supersonic Mach numbers, where increases in drag caused by winglets might be more significant. Computational analyses were also performed for the two configurations studied. Linear and small-disturbance formulations were used. The codes were found to give reasonable performance estimates sufficient for predicting changes of this magnitude.

  7. Mixing characteristics of a moderate aspect ratio screeching supersonic rectangular jet

    Science.gov (United States)

    Valentich, Griffin; Upadhyay, Puja; Kumar, Rajan

    2016-05-01

    Flow field characteristics of a moderate aspect ratio supersonic rectangular jet were examined at two overexpanded, a perfectly expanded, and an underexpanded jet conditions. The underexpanded and one overexpanded operating condition were of maximum screech, while the second overexpanded condition was of minimum screech intensity. Streamwise particle image velocimetry was performed along both major and minor axes of the jet and the measurements were made up to 30 nozzle heights, h, where h is the small dimension of the nozzle. Select cross planes were examined using stereoscopic particle image velocimetry to investigate the jet development and the role streamwise vortices play in jet spreading at each operating condition. The results show that streamwise vortices present at the nozzle corners along with vortices excited by screech tones play a major role in the jet evolution. All cases except for the perfectly expanded operating condition exhibited axis switching at streamwise locations ranging from 11 to 16 nozzle heights downstream of the exit. The overexpanded condition of maximum screech showed the most upstream switch over, while the underexpanded case showed the farthest downstream. Both of the maximum screeching cases developed into a diamond cross-sectional profile far downstream of the exit, while the ideally expanded case maintained a rectangular shape. The overexpanded minimum screeching case eventually decayed into an oblong profile.

  8. High aspect ratio iridescent three-dimensional metal–insulator–metal capacitors using atomic layer deposition

    Energy Technology Data Exchange (ETDEWEB)

    Burke, Micheal, E-mail: micheal.burke@tyndall.ie; Blake, Alan; Djara, Vladimir; O' Connell, Dan; Povey, Ian M.; Cherkaoui, Karim; Monaghan, Scott; Scully, Jim; Murphy, Richard; Hurley, Paul K.; Pemble, Martyn E.; Quinn, Aidan J., E-mail: aidan.quinn@tyndall.ie [Tyndall National Institute, University College Cork, Cork (Ireland)

    2015-01-01

    The authors report on the structural and electrical properties of TiN/Al{sub 2}O{sub 3}/TiN metal–insulator–metal (MIM) capacitor structures in submicron three-dimensional (3D) trench geometries with an aspect ratio of ∼30. A simplified process route was employed where the three layers for the MIM stack were deposited using atomic layer deposition (ALD) in a single run at a process temperature of 250 °C. The TiN top and bottom electrodes were deposited via plasma-enhanced ALD using a tetrakis(dimethylamino)titanium precursor. 3D trench devices yielded capacitance densities of 36 fF/μm{sup 2} and quality factors >65 at low frequency (200 Hz), with low leakage current densities (<3 nA/cm{sup 2} at 1 V). These devices also show strong optical iridescence which, when combined with the covert embedded capacitance, show potential for system in package (SiP) anticounterfeiting applications.

  9. Highly sensitive glucose biosensor based on Au-Ni coaxial nanorod array having high aspect ratio.

    Science.gov (United States)

    Hsu, Che-Wei; Wang, Gou-Jen

    2014-06-15

    An effective glucose biosensor requires a sufficient amount of GOx immobilizing on the electrode surface. An electrode of a 3D nanorod array, having a larger surface-to-volume ratio than a 2D nanostructure, can accommodate more GOx molecules to immobilize onto the surface of the nanorods. In this study, a highly sensitive Au-Ni coaxial nanorod array electrode fabricated through the integration of nano electroforming and immersion gold (IG) method for glucose detection was developed. The average diameter of the as-synthesized Ni nanorods and that of the Au-Ni nanorods were estimated to be 150 and 250 nm, respectively; both had a height of 30 μm. The aspect ratio was 120. Compared to that of a flat Au electrode, the effective sensing area was enhanced by 79.8 folds. Actual glucose detections demonstrated that the proposed Au-Ni coaxial nanorod array electrode could operate in a linear range of 27.5 μM-27.5mM with a detection limit of 5.5μM and a very high sensitivity of 769.6 μA mM(-1)cm(-2). Good selectivity of the proposed sensing device was verified by sequential injections of uric acid (UA) and ascorbic acid (AA). Long-term stability was examined through successive detections over a period of 30 days.

  10. Dynamics of ferrofluidic flow in the Taylor-Couette system with a small aspect ratio

    Science.gov (United States)

    Altmeyer, Sebastian; Do, Younghae; Lai, Ying-Cheng

    2017-01-01

    We investigate fundamental nonlinear dynamics of ferrofluidic Taylor-Couette flow - flow confined be-tween two concentric independently rotating cylinders - consider small aspect ratio by solving the ferro-hydrodynamical equations, carrying out systematic bifurcation analysis. Without magnetic field, we find steady flow patterns, previously observed with a simple fluid, such as those containing normal one- or two vortex cells, as well as anomalous one-cell and twin-cell flow states. However, when a symmetry-breaking transverse magnetic field is present, all flow states exhibit stimulated, finite two-fold mode. Various bifurcations between steady and unsteady states can occur, corresponding to the transitions between the two-cell and one-cell states. While unsteady, axially oscillating flow states can arise, we also detect the emergence of new unsteady flow states. In particular, we uncover two new states: one contains only the azimuthally oscillating solution in the configuration of the twin-cell flow state, and an-other a rotating flow state. Topologically, these flow states are a limit cycle and a quasiperiodic solution on a two-torus, respectively. Emergence of new flow states in addition to observed ones with classical fluid, indicates that richer but potentially more controllable dynamics in ferrofluidic flows, as such flow states depend on the external magnetic field.

  11. Bosch-like method for creating high aspect ratio poly(methyl methacrylate) (PMMA) structures

    KAUST Repository

    Haiducu, Marius

    2012-02-02

    This paper presents a method for etching millimetre-deep trenches in commercial grade PMMA using deep-UV at 254 nm. The method is based on consecutive cycles of irradiation and development of the exposed areas, respectively. The exposure segment is performed using an inexpensive, in-house built irradiation box while the development part is accomplished using an isopropyl alcohol (IPA):H2O developer. The method was tested and characterized by etching various dimension square test structures in commercial grade, mirrored acrylic. The undercut of the sidewalls due to the uncollimated nature of the irradiation light was dramatically alleviated by using a honeycomb metallic grid in between the irradiation source and the acrylic substrate and by rotating the latter using a direct current (DC) motor-driven stage. By using an extremely affordable set-up and non-toxic, environmentally friendly materials and substances, this process represents an excellent alternative to microfabricating microfluidic devices in particular and high aspect ratio structures in general using PMMA as substrate. © 2012 SPIE.

  12. Numerical investigation of flow on NACA4412 aerofoil with different aspect ratios

    Science.gov (United States)

    Demir, Hacımurat; Özden, Mustafa; Genç, Mustafa Serdar; Çağdaş, Mücahit

    2016-03-01

    In this study, the flow over NACA4412 was investigated both numerically and experimentally at a different Reynolds numbers. The experiments were carried out in a low speed wind tunnel with various angles of attack and different Reynolds numbers (25000 and 50000). Airfoil was manufactured using 3D printer with a various aspect ratios (AR = 1 and AR = 3). Smoke-wire and oil flow visualization methods were used to visualize the surface flow patterns. NACA4412 aerofoil was designed by using SOLIDWORKS. The structural grid of numerical model was constructed by ANSYS ICEM CFD meshing software. Furthermore, ANSYS FLUENT™ software was used to perform numerical calculations. The numerical results were compared with experimental results. Bubble formation was shown in CFD streamlines and smoke-wire experiments at z / c = 0.4. Furthermore, bubble shrunk at z / c = 0.2 by reason of the effects of tip vortices in both numerical and experimental studies. Consequently, it was seen that there was a good agreement between numerical and experimental results.

  13. Development and investigation of a small, high aspect ratio, two-stroke engine

    Science.gov (United States)

    Disseau, Mael Leo David Soliman

    An engine for a novel compact palm sized electric power generator was developed. Due to fabrication and space limitations a flat, rectangular, piston with spring return two-cycle engine was selected. This novel geometry raised many issues that had to be solved. These included: sealing, scavenging, and high aspect ratio (i.e., flame quenching and high heat losses) effects. Engines as thin as 3.175 mm were developed that produced 11.6 W of mechanical power. A somewhat thicker engine (6.35 mm) produced 15W of electrical power when attached to a voice coil generator. To better understand the combustion process in these types of engines, constant volume combustion in thin, flat rectangular combustors was studied. A model was also developed to help determine the parameters that control the behavior in these combustors, some of which could not be measured directly. A range of thicknesses over which combustion propagates was identified and the variation of system efficiency and heat transfer losses as well as overall combustor behavior with thickness were also determined. In addition, a threshold thickness at which the combustor switches from heat generation dominated mode to a heat loss dominated regime was identified. Finally, bulk flow, turbulence and leaks were identified as the parameters that need to be added to the model to enable it to predict the operation of the engine.

  14. Dimensional measurement of micro parts with high aspect ratio in HIT-UOI

    Science.gov (United States)

    Dang, Hong; Cui, Jiwen; Feng, Kunpeng; Li, Junying; Zhao, Shiyuan; Zhang, Haoran; Tan, Jiubin

    2016-11-01

    Micro parts with high aspect ratios have been widely used in different fields including aerospace and defense industries, while the dimensional measurement of these micro parts becomes a challenge in the field of precision measurement and instrument. To deal with this contradiction, several probes for the micro parts precision measurement have been proposed by researchers in Center of Ultra-precision Optoelectronic Instrument (UOI), Harbin Institute of Technology (HIT). In this paper, optical fiber probes with structures of spherical coupling(SC) with double optical fibers, micro focal-length collimation (MFL-collimation) and fiber Bragg grating (FBG) are described in detail. After introducing the sensing principles, both advantages and disadvantages of these probes are analyzed respectively. In order to improve the performances of these probes, several approaches are proposed. A two-dimensional orthogonal path arrangement is propounded to enhance the dimensional measurement ability of MFL-collimation probes, while a high resolution and response speed interrogation method based on differential method is used to improve the accuracy and dynamic characteristics of the FBG probes. The experiments for these special structural fiber probes are given with a focus on the characteristics of these probes, and engineering applications will also be presented to prove the availability of them. In order to improve the accuracy and the instantaneity of the engineering applications, several techniques are used in probe integration. The effectiveness of these fiber probes were therefore verified through both the analysis and experiments.

  15. Development of a low-aspect ratio fin for flight research experiments

    Science.gov (United States)

    Richwine, David M.; Delfrate, John H.

    1994-01-01

    A second-generation flight test fixture, developed at NASA Dryden Flight Research Center, offers a generic testbed for aerodynamic and fluid mechanics research. The new fixture, a low-aspect ratio vertical fin shape mounted on the centerline of an F-15B aircraft lower fuselage, is designed for flight research at Mach numbers up to 2.0. The new fixture is a composite structure with a modular configuration and removable components for functional flexibility. This report describes the multidisciplinary design and analysis approach used to develop the fixture. The approach integrates conservative assumptions with simple analysis techniques to minimize the time and cost associated with its development. Presented are the principal disciplines required for this effort, which include aerodynamics, structures, stability, and operational considerations. In addition, preliminary results from the first phase of flight testing are presented. Acceptable directional stability and flow quality are documented and show agreement with predictions. Future envelope expansion activities will minimize current limitations so that the fixture can be used for a wide variety of high-speed aerodynamic and fluid mechanics research experiments.

  16. Mixing Characteristics and Bubble Behavior in an Airlift Internal Loop Reactor with Low Aspect Ratio

    Institute of Scientific and Technical Information of China (English)

    张伟鹏; 雍玉梅; 张广积; 杨超; 毛在砂

    2014-01-01

    The present study summarizes the results of macro-and micro-mixing characteristics in an airlift inter-nal loop reactor with low aspect ratio (H/D≤5) using the electrolytic tracer response technique and the method of parallel competing reactions respectively. The micro-mixing has never been investigated in airlift loop reactors. The dual-tip electrical conductivity probe technique is used for measurement of local bubble behavior in the reactor. The effects of several operating parameters and geometric variables are investigated. It is found that the increase in su-perficial gas velocity corresponds to the increase in energy input, liquid circulation velocity and shear rate, decreas-ing the macro-mixing time and segregation index. Moreover, it is shown that top clearance and draft diameter affect flow resistance. However, the bubble redistribution with a screen mesh on the perforated plate distributor for macro-mixing is insignificant. The top region with a high energy dissipation rate is a suitable location for feeding reactants. The analysis of present experimental data provides a valuable insight into the interaction between gas and liquid phases for mixing and improves the understanding of intrinsic roles of hydrodynamics upon the reactor de-sign and operating parameter selection.

  17. The Universal Aspect Ratio of Vortices in Rotating Stratified Flows: Theory and Simulation

    CERN Document Server

    Hassanzadeh, Pedram; Gal, Patrice Le

    2012-01-01

    We derive a relationship for the vortex aspect ratio $\\alpha$ (vertical half-thickness over horizontal length scale) for steady and slowly evolving vortices in rotating stratified fluids, as a function of the Brunt-Vaisala frequencies within the vortex $N_c$ and in the background fluid outside the vortex $\\bar{N}$, the Coriolis parameter $f$, and the Rossby number $Ro$ of the vortex: $\\alpha^2 = Ro(1+Ro) f^2/(N_c^2-\\bar{N}^2)$. This relation is valid for cyclones and anticyclones in either the cyclostrophic or geostrophic regimes; it works with vortices in Boussinesq fluids or ideal gases, and the background density gradient need not be uniform. Our relation for $\\alpha$ has many consequences for equilibrium vortices in rotating stratified flows. For example, cyclones must have $N_c^2 > \\bar{N}^2$; weak anticyclones (with $|Ro| \\bar{N}^2$. We verify our relation for $\\alpha$ with numerical simulations of the three-dimensional Boussinesq equations for a wide variety of vortices, including: vortices that are i...

  18. Ultra-high aspect ratio copper nanowires as transparent conductive electrodes for dye sensitized solar cells

    Science.gov (United States)

    Zhu, Zhaozhao; Mankowski, Trent; Shikoh, Ali Sehpar; Touati, Farid; Benammar, Mohieddine A.; Mansuripur, Masud; Falco, Charles M.

    2016-09-01

    We report the synthesis of ultra-high aspect ratio copper nanowires (CuNW) and fabrication of CuNW-based transparent conductive electrodes (TCE) with high optical transmittance (>80%) and excellent sheet resistance (Rs zinc oxide (AZO) thin-film coatings, or platinum thin film coatings, or nickel thin-film coatings. Our hybrid transparent electrodes can replace indium tin oxide (ITO) films in dye-sensitized solar cells (DSSCs) as either anodes or cathodes. We highlight the challenges of integrating bare CuNWs into DSSCs, and demonstrate that hybridization renders the solar cell integrations feasible. The CuNW/AZO-based DSSCs have reasonably good open-circuit voltage (Voc = 720 mV) and short-circuit current-density (Jsc = 0.96 mA/cm2), which are comparable to what is obtained with an ITO-based DSSC fabricated with a similar process. Our CuNW-Ni based DSSCs exhibit a good open-circuit voltage (Voc = 782 mV) and a decent short-circuit current (Jsc = 3.96 mA/cm2), with roughly 1.5% optical-to-electrical conversion efficiency.

  19. Lyapunov exponents for small aspect ratio Rayleigh-Bénard convection.

    Science.gov (United States)

    Scheel, J D; Cross, M C

    2006-12-01

    Leading order Lyapunov exponents and their corresponding eigenvectors have been computed numerically for small aspect ratio, three-dimensional Rayleigh-Benard convection cells with no-slip boundary conditions. The parameters are the same as those used by Ahlers and Behringer [Phys. Rev. Lett. 40, 712 (1978)] and Gollub and Benson [J. Fluid Mech. 100, 449 (1980)] in their work on a periodic time dependence in Rayleigh-Benard convection cells. Our work confirms that the dynamics in these cells truly are chaotic as defined by a positive Lyapunov exponent. The time evolution of the leading order Lyapunov eigenvector in the chaotic regime will also be discussed. In addition we study the contributions to the leading order Lyapunov exponent for both time periodic and aperiodic states and find that while repeated dynamical events such as dislocation creation/annihilation and roll compression do contribute to the short time Lyapunov exponent dynamics, they do not contribute to the long time Lyapunov exponent. We find instead that nonrepeated events provide the most significant contribution to the long time leading order Lyapunov exponent.

  20. Leading-edge vortex burst on a low-aspect-ratio rotating flat plate

    Science.gov (United States)

    Medina, Albert; Jones, Anya R.

    2016-08-01

    This study experimentally investigates the phenomenon of leading-edge-vortex burst on rotating flat plate wings. An aspect-ratio-2 wing was driven in pure rotation at a Reynolds number of Re=2500 . Of primary interest is the evolution of the leading-edge vortex along the wing span over a single-revolution wing stroke. Direct force measurements of the lift produced by the wing revealed a single global lift maximum relatively early in the wing stroke. Stereoscopic particle image velocimetry was applied to several chordwise planes to quantify the structure and strength of the leading-edge vortex and its effect on lift production. This analysis revealed opposite-sign vorticity entrainment into the core of the leading-edge vortex, originating from a layer of secondary vorticity along the wing surface. Coincident with the lift peak, there emerged both a concentration of opposite vorticity in the leading-edge-vortex core, as well as axial flow stagnation within the leading-edge-vortex core. Planar control volume analysis was performed at the midspan to quantify the contributions of vorticity transport mechanisms to the leading-edge-vortex circulation. The rate of circulation annihilation by opposite-signed vorticity entrainment was found to be minimal during peak lift production, where convection balanced the flux of vorticity resulting in stagnation and eventually reversal of axial flow. Finally, vortex burst was found to be correlated with swirl number, where bursting occurs at a swirl threshold of Sw<0.6 .

  1. Simulation studies of the behavior of positrons in a microtrap with long aspect ratio

    CERN Document Server

    Narimannezhad, Alireza; Weber, Marc H; Xu, Jia; Lynn, Kelvin G

    2013-01-01

    The charged particles storage capacity of microtraps (micro-Penning-Malmberg traps) with large length to radius aspect ratios and radii of the order of tens of microns was explored. Simulation studies of the motions of charged particles were conducted with particle-in-cell plasma code WARP and the Charged Particle Optics (CPO) program. This paper presents how to reduce simulation noise by optimizing modeling parameters to achieve an equilibrium distribution. The new design of the trap consisted of an array of microtraps with confinement voltages of only 10 V. It was computationally shown that each microtrap with 50 micron radius stored positrons with density higher than a conventional Penning-Malmberg trap (10^11 cm-3). The results of the simulation of a plasma initialized with a uniform density and Boltzmann energy distributions showed that the plasma tends to transform to a soft edge distribution in radial direction as it approaches the equilibrium. The shorter the plasma we had, the faster the equilibrium ...

  2. Atomic Layer Deposition for Coating of High Aspect Ratio TiO2 Nanotube Layers

    Science.gov (United States)

    2016-01-01

    We present an optimized approach for the deposition of Al2O3 (as a model secondary material) coating into high aspect ratio (≈180) anodic TiO2 nanotube layers using the atomic layer deposition (ALD) process. In order to study the influence of the diffusion of the Al2O3 precursors on the resulting coating thickness, ALD processes with different exposure times (i.e., 0.5, 2, 5, and 10 s) of the trimethylaluminum (TMA) precursor were performed. Uniform coating of the nanotube interiors was achieved with longer exposure times (5 and 10 s), as verified by detailed scanning electron microscopy analysis. Quartz crystal microbalance measurements were used to monitor the deposition process and its particular features due to the tube diameter gradient. Finally, theoretical calculations were performed to calculate the minimum precursor exposure time to attain uniform coating. Theoretical values on the diffusion regime matched with the experimental results and helped to obtain valuable information for further optimization of ALD coating processes. The presented approach provides a straightforward solution toward the development of many novel devices, based on a high surface area interface between TiO2 nanotubes and a secondary material (such as Al2O3). PMID:27643411

  3. Impact of Fullerene Mixing Behavior on the Microstructure, Photophysics, and Device Performance of Polymer/Fullerene Solar Cells.

    Science.gov (United States)

    Huang, Wenchao; Chandrasekaran, Naresh; Prasad, Shyamal K K; Gann, Eliot; Thomsen, Lars; Kabra, Dinesh; Hodgkiss, Justin M; Cheng, Yi-Bing; McNeill, Christopher R

    2016-11-02

    Here, a comprehensive study of the influence of polymer:fullerene mixing behavior on the performance, thin-film microstructure, photophysics, and device physics of polymer solar cells is presented. In particular, blends of the donor polymer PBDTTT-EFT with the acceptor PC71BM that exhibit power conversion efficiencies over 9% are investigated. Through tuning of the fullerene concentration in PBDTTT-EFT:PC71BM blends, the impact of fullerene mixing behavior is systematically investigated via a combination of synchrotron-based X-ray scattering and spectroscopy techniques. The impact of fullerene loading on photophysics and device physics is further explored with steady-state photoluminescence measurements, ultrafast transient absorption spectroscopy, and transient photovoltage measurements. In the low fullerene concentration regime (70 wt %), large fullerene domains result in incomplete PC71BM exciton harvesting with the presence of fullerene molecules also disrupting the molecular packing of polymer crystallites. The optimum fullerene concentration of ∼60-67 wt % balances the requirements of charge generation and charge collection. These findings demonstrate that controlling the fullerene concentration in the mixed phase and optimizing the balance between pure and mixed phases are critical for maximizing the efficiency of highly mixed polymer/fullerene solar cells.

  4. Fiber-optic liquid level monitoring system using microstructured polymer fiber Bragg grating array sensors: performance analysis

    DEFF Research Database (Denmark)

    Marques, C. A. F.; Pospori, A.; Saez-Rodriguez, D.

    2015-01-01

    A highly sensitive liquid level monitoring system based on microstructured polymer optical fiber Bragg grating (mPOFBG) array sensors is reported for the first time. The configuration is based on five mPOFBGs inscribed in the same fiber in the 850 nm spectral region, showing the potential...... of the sensor is found to be 98 pm/cm of water, enhanced by more than a factor of 9 when compared to an equivalent sensor based on a silica fiber around 1550 nm. The temperature sensitivity is studied and a multi-sensor arrangement proposed, which has the potential to provide level readings independent...

  5. Effect of torsional stiffness and inertia on the dynamics of low aspect ratio flapping wings.

    Science.gov (United States)

    Xiao, Qing; Hu, Jianxin; Liu, Hao

    2014-03-01

    Micro air vehicle-motivated aerodynamics in biological flight has been an important subject in the past decade. Inspired by the novel flapping wing mechanisms in insects, birds and bats, we have carried out a numerical study systematically investigating a three-dimensional flapping rigid wing with passively actuated lateral and rotational motion. Distinguishing it from the limited existing studies, this work performs a systematic examination on the effects of wing aspect ratio (AR = 1.0 to infinity), inertia (density ratio σ = 4-32), torsional stiffness (frequency ratio F = 1.5-10 and infinity) and pivot point (from chord-center to leading edge) on the dynamics response of a low AR rectangular wing under an initial zero speed flow field condition. The simulation results show that the symmetry breakdown of the flapping wing results in a forward/backward motion with a rotational pitching. When the wing reaches its stable periodic state, the induced pitching frequency is identical to its forced flapping frequency. However, depending on various kinematic and dynamic system parameters, (i.e. flapping frequency, density ratio and pitching axis), the lateral induced velocity shows a number of different oscillating frequencies. Furthermore, compared with a one degree of freedom (DoF) wing in the lateral direction only, the propulsion performance of such a two DoF wing relies very much on the magnitude of torsional stiffness adding on the pivot point, as well as its pitching axis. In all cases examined here, thrust force and moment generated by a long span wing is larger than that of a short wing, which is remarkably linked to the strong reverse von Kármán vortex street formed in the wake of a wing.

  6. Simulation Research on Stress Intensity Factors of Different Crack Aspect Ratios on Hollow Axles

    Institute of Scientific and Technical Information of China (English)

    ZHOU Suxia; XIE Jilong

    2009-01-01

    Because of the wicked service environment of the high speed train, it is possible that the hollow axle of the train may encounter the foreign object damage and form a sharp notch. Under the fatigue loading a crack can initiate from the notch and propagate to failure. It is noted that the stress intensity factor is the control parameter of the crack propagating, for the purpose of getting the more exact propagation characteristics, the stress intensity factor is studied mainly. The service loads of hollow axles are defined, and the stress distribution of hollow axles is obtained according to the load spectrum. The semi-ellipse crack configuration is defined with three parameters:the aspect ratio, the relative depth and the relative location along the crack front. Quarter point 20-node isoparametric degenerate singular elements are used for the region near the crack tip. The finite element model of crack extension of hollow axle is created, and the crack front is dispersed which can realize orthogonal extension. Based on this the stress intensity factors of crack front were calculated, and the distribution rules of the stress intensity factors of different initial crack shapes are obtained. The conclusions are compared with that of the analytic method and they agree with each other very well, and the calculating results show that there is a close relationship between the stress intensity factor and the initial crack shape. For a round crack the stress intensity factor at the surface point increases faster than the one at the center point with the crack propagation. However, for a narrow crack, the results are in contrast with that of a round one. So, all the cracks with different shapes propagate toward to a similar shape, and they grow at this shape to end. The study may contribute to the crack propagate characteristics research.

  7. GaN nanowire tip for high aspect ratio nano-scale AFM metrology (Conference Presentation)

    Science.gov (United States)

    Behzadirad, Mahmoud; Dawson, Noel; Nami, Mohsen; Rishinaramangalam, Ashwin K.; Feezell, Daniel F.; Busani, Tito L.

    2016-09-01

    In this study we introduce Gallium Nitride (GaN) nanowire (NW) as high aspect ratio tip with excellent durability for nano-scale metrology. GaN NWs have superior mechanical property and young modulus compare to commercial Si and Carbon tips which results in having less bending issue during measurement. The GaN NWs are prepared via two different methods: i) Catalyst-free selected area growth, using Metal Organic Chemical Vapor Deposition (MOCVD), ii) top-down approach by employing Au nanoparticles as the mask material in dry-etch process. To achieve small diameter tips, the semipolar planes of the NWs grown by MOCVD are etched using AZ400k. The diameter of the NWs fabricated using the top down process is controlled by using different size of nanoparticles and by Inductively Coupled Plasma etching. NWs with various diameters were manipulated on Si cantilevers using Focus Ion Beam (FIB) to make tips for AFM measurement. A Si (110) substrate containing nano-scale grooves with vertical 900 walls were used as a sample for inspection. AFM measurements were carried out in tapping modes for both types of nanowires (top-down and bottom-up grown nanowires) and results are compared with conventional Si and carbon nanotube tips. It is shown our fabricated tips are robust and have improved edge resolution over conventional Si tips. GaN tips made with NW's fabricated using our top down method are also shown to retain the gold nanoparticle at tip, which showed enhanced field effects in Raman spectroscopy.

  8. High aspect ratio silicon nanowires control fibroblast adhesion and cytoskeleton organization.

    Science.gov (United States)

    Andolfi, Laura; Murello, Anna; Cassese, Damiano; Ban, Jelena; Dal Zilio, Simone; Lazzarino, Marco

    2017-04-18

    Cell-cell and cell-matrix interactions are essential to the survival and proliferation of most cells, and are responsible for triggering a wide range of biochemical pathways. More recently, the biomechanical role of those interactions was highlighted, showing, for instance, that adhesion forces are essential for cytoskeleton organization. Silicon nanowires (Si NWs) with their small size, high aspect ratio and anisotropic mechanical response represent a useful model to investigate the forces involved in the adhesion processes and their role in cellular development. In this work we explored and quantified, by single cell force spectroscopy (SCFS), the interaction of mouse embryonic fibroblasts with a flexible forest of Si NWs. We observed that the cell adhesion forces are comparable to those found on collagen and bare glass coverslip, analogously the membrane tether extraction forces are similar to that on collagen but stronger than that on bare flat glass. Cell survival did not depend significantly on the substrate, although a reduced proliferation after 36 h was observed. On the contrary both cell morphology and cytoskeleton organization revealed striking differences. The cell morphology on Si-NW was characterized by a large number of filopodia and a significant decrease of the cell mobility. The cytoskeleton organization was characterized by the absence of actin fibers, which were instead dominant on collagen and flat glass support. Such findings suggest that the mechanical properties of disordered Si NWs, and in particular their strong asymmetry, play a major role in the adhesion, morphology and cytoskeleton organization processes. Indeed, while adhesion measurements by SCFS provide out-of-plane forces values consistent with those measured on conventional substrates, weaker in-plane forces hinder proper cytoskeleton organization and migration processes.

  9. Geometrical Nonlinear Aeroelastic Stability Analysis of a Composite High-Aspect-Ratio Wing

    Directory of Open Access Journals (Sweden)

    Chang Chuan Xie

    2008-01-01

    Full Text Available A composite high-aspect-ratio wing of a high-altitude long-endurance (HALE aircraft was modeled with FEM by MSC/NASTRAN, and the nonlinear static equilibrium state is calculated under design load with follower force effect, but without load redistribution. Assuming the little vibration amplitude of the wing around the static equilibrium state, the system is linearized and the natural frequencies and mode shapes of the deformed structure are obtained. Planar doublet lattice method is used to calculate unsteady aerodynamics in frequency domain ignoring the bending effect of the deflected wing. And then, the aeroelastic stability analysis of the system under a given load condition is successively carried out. Comparing with the linear results, the nonlinear displacement of the wing tip is higher. The results indicate that the critical nonlinear flutter is of the flap/chordwise bending type because of the chordwise bending having quite a large torsion component, with low critical speed and slowly growing damping, which dose not appear in the linear analysis. Furthermore, it is shown that the variation of the nonlinear flutter speed depends on the scale of the load and on the chordwise bending frequency. The research work indicates that, for the very flexible HALE aircraft, the nonlinear aeroelastic stability is very important, and should be considered in the design progress. Using present FEM software as the structure solver (e.g. MSC/NASTRAN, and the unsteady aerodynamic code, the nonlinear aeroelastic stability margin of a complex system other than a simple beam model can be determined.

  10. Experiments on a low aspect ratio wing at low Reynolds numbers

    Science.gov (United States)

    Morse, Daniel R.

    At the start of the 21st century much of the focus of aircraft design has been turned to unmanned aerial vehicles (UAVs) which generally operate at much lower speeds in higher risk areas than manned aircraft. One subset of UAVs are Micro Air Vehicles (MAVs) which usually are no larger than 20cm and rely on non-traditional shapes to generate lift at very low velocities. This purpose of this work is to describe, in detail with experimental methods, the flow field around a low aspect ratio wing operating at low Reynolds numbers and at high angles of attack. Quantitative measurements are obtained by Three Component Time Resolved Particle Image Velocimetry (3C TR PIV) which describe the mean and turbulent flow field. This research focuses on the leading edge separation zone and the vortex shedding process which occurs at the leading edge. Streamwise wing tip vortices which dominate the lift characteristics are described with flow visualization and 3C TR PIV measurements. Turbulent Kinetic Energy (TKE) is described at the leading edge over several angles of attack. Turbulent Reynolds stresses in all three directions are described over the wing span and several Reynolds numbers. Two primary cyclic processes are observed within the flow field; one low frequency oscillation in the separated region and one high frequency event associated with leading edge vortex formation and convection. Two length scales are proposed and are shown to match well with each other, one based on leading edge vortex shedding frequency and convective velocity and the other based on mean vortex separation distance. A new method of rendering velocity frequency content over large data sets is proposed and used to illustrate the different frequencies observed at the leading edge.

  11. Diagnostics of BubbleMode Vortex Breakdown in Swirling Flow in a Large-Aspect-Ratio Cylinder

    DEFF Research Database (Denmark)

    Kulikov, D. V.; Mikkelsen, Robert Flemming; Naumov, Igor

    2014-01-01

    We report for the first time on the possible formation of regions with counterflow (bubble-mode vortex breakdown or explosion) at the center of strongly swirling flow generated by a rotating endwall in a large-aspect-ratio cylindrical cavity filled with a liquid medium. Previously, the possibility...... of bubble-mode breakdown was studied in detail for cylindrical cavities of moderate aspect ratio (length to radius ratios up to H/R ∼ 3.5), while flows in large-aspect-ratio cylinders were only associated with regimes of self-organized helical vortex multiplets. In the present study, a regime...... with nonstationary bubble-mode vortex breakdown has been observed in a cylindrical cavity with H/R = 4.5....

  12. EFFECT OF SPECIMEN ASPECT RATIO ON FATIGUE LIFE OF CLOSED CELL Al-Si-Ca ALLOY FOAM

    Institute of Scientific and Technical Information of China (English)

    Amkee Kim; Ilhyun Kim

    2008-01-01

    Quasi-static and compressive fatigue tests on the closed cell Al-Si-Ca alloy foam specimens with three different aspect ratios were performed.It turned out that the onset of cyclic shortening of foam with a lower aspect ratio took place earlier and the fatigue strength was lower compared with the specimen with a higher aspect ratio,although aU the dimensions of specimen satisfied the seven times the cell size criterion,while the quasi-static stress-strain curves were almost same having same Young's modulus,yield stress and plateau stress.Therefore,the seven times the cell size criterion for the quasi-static compression behavior was not applicable to the fatigue analysis of Al-Si-Ca alloy foam.

  13. Bragg Grating Based Sensors in Microstructured Polymer Optical Fibers: Accelerometers and Microphones

    DEFF Research Database (Denmark)

    Stefani, Alessio

    and gluing of polymer to silica fibers are discussed. The realization of gratings in polymer fibers is shown with two different techniques: the UV phase mask technique and the direct writing technique reported here for the first time for polymer fibers. Realization of gratings in PMMA step index fibers...

  14. Fabrication of micro-pin array with high aspect ratio on stainless steel using nanosecond laser beam machining

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Se Won [School of Mechanical and Aerospace Engineering, Seoul National University, Gwanak 599 Gwanak-ro, Gwanak-Gu, Seoul, 151-744 (Korea, Republic of); Shin, Hong Shik, E-mail: shinhs05@ut.ac.kr [Department of Energy System Engineering, Korea National University of Transportation, Chungju, Chungbuk, 380-702 (Korea, Republic of); Chu, Chong Nam [School of Mechanical and Aerospace Engineering, Seoul National University, Gwanak 599 Gwanak-ro, Gwanak-Gu, Seoul, 151-744 (Korea, Republic of)

    2013-01-01

    Highlights: Black-Right-Pointing-Pointer A high aspect ratio micro-pin array was fabricated by laser beam machining using the piling of a recast layer. Black-Right-Pointing-Pointer The recast layer could be piled due to the chromium oxide with high surface tension and viscosity of chromium oxide. Black-Right-Pointing-Pointer The machining characteristics for a high aspect ratio micro-pin array were investigated according to laser beam parameters. Black-Right-Pointing-Pointer Experiments for attaching force relative to the surface roughness of the subject plane were carried out. Black-Right-Pointing-Pointer The developed micro-pin array was successfully attached to vertical wall. - Abstract: In this paper, a micro-pin array with a high aspect ratio was fabricated on AISI 304 using laser beam ablation for attachment to a vertical wall. In recent times, there has been research in various fields, including robotics and bio-MEMS, regarding attachment to vertical walls, and micro-pin arrays may offer the best solution. For vertical wall attachment, the micro-pin should have a high aspect ratio, long length, and sharp tip. The recast layer could be piled due to the chromium oxide with high surface tension and viscosity of chromium oxide, and it composed the micro-pins with high aspect ratio. X-ray photoelectron spectroscopy (XPS) was used to identify the characteristics of the piled recast layer. The machining characteristics for a high aspect ratio micro-pin array were investigated according to laser beam machining parameters. In addition, experiments for attaching force relative to the surface roughness of the subject plane were carried out.

  15. Numerical Investigation of the Impact of Different Configurations and Aspect Ratios on Dense Gas Dispersion in Urban Street Canyons

    Institute of Scientific and Technical Information of China (English)

    YANG Rui; ZHANG Jing; SHEN Shifei; LI Xiaomeng; CHEN Jianguo

    2007-01-01

    The dispersion of chlorine gas in urban street canyons was numerically simulated using the fire dynamics simulator, a code developed by the National Institute of Standards and Technology of USA, which uses large eddy simulation coupled with the Smagorinsky sub-grid scale model. The unsteady flow fields were computed by solving the filtered incompressible Navier-Stokes equations under low Mach number approximation by the finite difference method. The studies analyzed the influence of different street canyon configurations and aspect ratios on the flow and chlorine gas dispersion. The geometric configuration and aspect ratio both affect the vortices and the local concentration distributions in street canyons.

  16. Low Reynolds number flow in rectangular cooling channels provided with low aspect ratio pin fins

    Energy Technology Data Exchange (ETDEWEB)

    Armellini, Alessandro; Casarsa, Luca [Dipartimento di Energetica e Macchine, Universita di Udine, Via delle Scienze 208, 33100 Udine (Italy); Giannattasio, Pietro, E-mail: pietro.giannattasio@uniud.i [Dipartimento di Energetica e Macchine, Universita di Udine, Via delle Scienze 208, 33100 Udine (Italy)

    2010-08-15

    The flow structures around single heat transfer promoters of different shapes (square, circular, triangular and rhomboidal) have been investigated experimentally by means of a 2-D Particle Image Velocimetry (PIV) technique. The geometrical configuration and flow conditions considered are typical of real liquid cooling channels. They include low aspect ratio pin fins confined at both ends by the walls of a rectangular channel, water flow at low Reynolds numbers (Re = 800, 1800, 2800), high core flow turbulence and undeveloped boundary layers at the position of the obstacle. In front of the pin fins the high turbulence level is found to promote a strong instability of the horseshoe vortex system that forms at the wall/obstacle junction. In particular, frequent events of break-away of the primary vortices and inrush of core fluid, which are known to enhance the wall heat transfer, are observed in the cases of square and circular pins already from Re = 1800. The near wake downstream of the obstacles appears to be influenced by streamwise oriented vortical structures produced at the wall/obstacle junction. They give rise to spanwise velocity components (up-wash flow) that lead to a three-dimensional mass recirculation behind the pins. The combination of up-wash flows, low Reynolds number and high core flow turbulence gives rise to a competition between the classical alternate vortex shedding and an irregular shedding mode characterized by the decoupling of the shear layers and the absence of well organized primary structures. At Re = 800, the irregular shedding prevails and the mean wake topology is almost insensitive to the obstacle shape. As the Reynolds number is increased, the junction flow structures reduce in size and strength, their effect on the wake flow weakens and the recirculation structures behind the obstacles differentiate significantly according to the pin shape. Besides investigating complex flow structures in geometrical and flow configurations of

  17. Etching high aspect ratio structures in silicon using sulfur hexafluoride/oxygen plasma

    Science.gov (United States)

    Belen, Rodolfo Jun

    Plasma etching of high aspect ratio structures in Si is an important step in manufacturing capacitors for memory devices and integrated components of microelectromechanical systems. In these applications, the goal is to etch deep features anisotropically with high etch rates and selectivities to the mask while maintaining good uniformity and reproducibility. This study investigates the etching of deep sub-half-micron diameter holes in Si using SF6/O 2 plasma. Etching experiments and plasma diagnostics are combined with modeling to gain a fundamental understanding of the etching and passivation kinetics and mechanism necessary in developing and scaling-up processes. Etching experiments are conducted in an inductively coupled plasma reactor with a planar coil. The substrate electrode is biased with a separate rf power supply to achieve independent control of the ion flux and energy. The effects of pressure, rf-bias and SF6-to-O2 ratio in the feed gas on the etch rate, selectivity and feature profile shape are studied using Si wafers patterned with 0.35 mum-diameter holes in a SiO2 mask. Visualization of profiles using scanning electron microscopy is complemented by plasma diagnostics such as mass spectrometry and actinometry. Simultaneous with experiments, reactor-scale and feature-scale models are developed to quantify the etching and passivation kinetics and identify the important kinetic parameters that affect feature profile evolution. Information from plasma diagnostics and previously published data are used to reduce the degrees of freedom in the model. Experiments are designed to directly measure kinetic parameters such as the chemical etch rate constant and the incidence angle dependence of the etching yield. Experimentally inaccessible parameters such as the sticking coefficients, etching yield and ion scattering parameters are determined through feature profile simulation. The key internal plasma parameters that affect profile evolution are the F-to-O and F

  18. Filling high aspect ratio trenches by superconformal chemical vapor deposition: Predictive modeling and experiment

    Science.gov (United States)

    Wang, Wenjiao B.; Abelson, John R.

    2014-11-01

    Complete filling of a deep recessed structure with a second material is a challenge in many areas of nanotechnology fabrication. A newly discovered superconformal coating method, applicable in chemical vapor deposition systems that utilize a precursor in combination with a co-reactant, can solve this problem. However, filling is a dynamic process in which the trench progressively narrows and the aspect ratio (AR) increases. This reduces species diffusion within the trench and may drive the component partial pressures out of the regime for superconformal coating. We therefore derive two theoretical models that can predict the possibility for filling. First, we recast the diffusion-reaction equation for the case of a sidewall with variable taper angle. This affords a definition of effective AR, which is larger than the nominal AR due to the reduced species transport. We then derive the coating profile, both for superconformal and for conformal coating. The critical (most difficult) step in the filling process occurs when the sidewalls merge at the bottom of the trench to form the V shape. Experimentally, for the Mg(DMADB)2/H2O system and a starting AR = 9, this model predicts that complete filling will not be possible, whereas experimentally we do obtain complete filling. We then hypothesize that glancing-angle, long-range transport of species may be responsible for the better than predicted filling. To account for the variable range of species transport, we construct a ballistic transport model. This incorporates the incident flux from outside the structure, cosine law re-emission from surfaces, and line-of-sight transport between internal surfaces. We cast the transport probability between all positions within the trench into a matrix that represents the redistribution of flux after one cycle of collisions. Matrix manipulation then affords a computationally efficient means to determine the steady-state flux distribution and growth rate for a given taper angle. The

  19. Fabrication of novel AFM probe with high-aspect-ratio ultra-sharp three-face silicon nitride tips

    NARCIS (Netherlands)

    Vermeer, Rolf; Berenschot, Erwin; Sarajlic, Edin; Tas, Niels; Jansen, Henri

    2014-01-01

    In this paper we present the wafer-scale fabrication of molded AFM probes with high aspect ratio ultra-sharp three-plane silicon nitride tips. Using (111) silicon wafers a dedicated process is developed to fabricate molds in the silicon wafer that have a flat triangular bottom surface enclosed by th

  20. Narrow conductive structures with high aspect ratios through single-pass inkjet printing and evaporation-induced dewetting

    NARCIS (Netherlands)

    Abbel, R.; Teunissen, P.; Michels, J.; Groen, W.A.

    2015-01-01

    Inkjet printed silver lines contract to widths below 20-μm during drying on an organic planarization coating. Aspect ratios previously unprecedented with single pass inkjet printing on isotropic homogeneous substrates are obtained. This effect is caused by the subsequent evaporation of solvents from

  1. Highly Manufacturable Deep (Sub-Millimeter) Etching Enabled High Aspect Ratio Complex Geometry Lego-Like Silicon Electronics

    KAUST Repository

    Ghoneim, Mohamed T.

    2017-02-01

    A highly manufacturable deep reactive ion etching based process involving a hybrid soft/hard mask process technology shows high aspect ratio complex geometry Lego-like silicon electronics formation enabling free-form (physically flexible, stretchable, and reconfigurable) electronic systems.

  2. Framework to model neutral particle flux in convex high aspect ratio structures using one-dimensional radiosity

    Science.gov (United States)

    Manstetten, Paul; Filipovic, Lado; Hössinger, Andreas; Weinbub, Josef; Selberherr, Siegfried

    2017-02-01

    We present a computationally efficient framework to compute the neutral flux in high aspect ratio structures during three-dimensional plasma etching simulations. The framework is based on a one-dimensional radiosity approach and is applicable to simulations of convex rotationally symmetric holes and convex symmetric trenches with a constant cross-section. The framework is intended to replace the full three-dimensional simulation step required to calculate the neutral flux during plasma etching simulations. Especially for high aspect ratio structures, the computational effort, required to perform the full three-dimensional simulation of the neutral flux at the desired spatial resolution, conflicts with practical simulation time constraints. Our results are in agreement with those obtained by three-dimensional Monte Carlo based ray tracing simulations for various aspect ratios and convex geometries. With this framework we present a comprehensive analysis of the influence of the geometrical properties of high aspect ratio structures as well as of the particle sticking probability on the neutral particle flux.

  3. 3D Viscoelastic Finite Element Modelling of Polymer Flow in the Fiber Drawing Process for Microstructured Polymer Optical Fiber Fabrication

    DEFF Research Database (Denmark)

    Fasano, Andrea; Rasmussen, Henrik K.; Marín, J. M. R.

    2015-01-01

    the numerical modelling of mPOF drawing has mainly beenbased on principles, such as generalized Newtonian fluid dynamics, which are not able to cope with the elasticcomponent in polymer flow. In the present work, we employ the K-BKZ constitutive equation, a non-linearsingle-integral model that combines both...... modelling of the fiber drawingprocess using a fully three-dimensional and time-dependent finite element method, giving significant insightinto this widely spread mPOF production technique. Our computational predictions are physically based on theviscoelastic fluid dynamics of polymers. Until now...

  4. A model for roll stall and the inherent stability modes of low aspect ratio wings at low Reynolds numbers

    Science.gov (United States)

    Shields, Matt

    The development of Micro Aerial Vehicles has been hindered by the poor understanding of the aerodynamic loading and stability and control properties of the low Reynolds number regime in which the inherent low aspect ratio (LAR) wings operate. This thesis experimentally evaluates the static and damping aerodynamic stability derivatives to provide a complete aerodynamic model for canonical flat plate wings of aspect ratios near unity at Reynolds numbers under 1 x 105. This permits the complete functionality of the aerodynamic forces and moments to be expressed and the equations of motion to solved, thereby identifying the inherent stability properties of the wing. This provides a basis for characterizing the stability of full vehicles. The influence of the tip vortices during sideslip perturbations is found to induce a loading condition referred to as roll stall, a significant roll moment created by the spanwise induced velocity asymmetry related to the displacement of the vortex cores relative to the wing. Roll stall is manifested by a linearly increasing roll moment with low to moderate angles of attack and a subsequent stall event similar to a lift polar; this behavior is not experienced by conventional (high aspect ratio) wings. The resulting large magnitude of the roll stability derivative, Cl,beta and lack of roll damping, Cl ,rho, create significant modal responses of the lateral state variables; a linear model used to evaluate these modes is shown to accurately reflect the solution obtained by numerically integrating the nonlinear equations. An unstable Dutch roll mode dominates the behavior of the wing for small perturbations from equilibrium, and in the presence of angle of attack oscillations a previously unconsidered coupled mode, referred to as roll resonance, is seen develop and drive the bank angle? away from equilibrium. Roll resonance requires a linear time variant (LTV) model to capture the behavior of the bank angle, which is attributed to the

  5. The effect of water-soluble polymers on the microstructure and properties of freeze-cast alumina ceramics

    Science.gov (United States)

    Pekor, Christopher Michael

    Porous ceramics can be divided into three separate classes based on their pore size: microporous ceramics with pores less than 2 nm, mesoporous ceramics with pores in the range of 2--50 nm and macroporous ceramics with pores that are greater than 50 nm. In particular, macroporous ceramics are used in a variety of applications such as refractories, molten metal filtration, diesel particulate filters, heterogeneous catalyst supports and biomedical scaffolds. Freeze casting is a novel method used to create macroporous ceramics. In this method growing ice crystals act as a template for the pores and are solidified, often directionally, through a ceramic dispersion and removed from the green body through a freeze drying procedure. This method has attracted some attention over the past few years due to its relative simplicity, flexibility and environmental friendliness. On top of this freeze casting is capable of producing materials with high pore volume fractions, which is an advantage over processing by packing and necking of particles, where the pore volume fraction is typically less than 50%. Many of the basic processing variables that affect the freeze cast microstructure, such as the temperature gradient, interfacial velocity and solid loading of the dispersion have been well established in the literature. On the other hand, areas such as the effect of additives on the microstructure and mechanical properties have not been covered in great detail. In this study the concept of constitutional supercooling from basic solidification theory is used to explain the effects of two water-soluble polymers, polyethylene glycol and polyvinyl alcohol, on the microstructure of freeze cast alumina ceramics. In addition, changes in the observed microstructure will be related to experimentally determined values of permeability and compressive strength.

  6. Modelling of the isothermal replication of surface microstructures in polymer melts

    DEFF Research Database (Denmark)

    Rasmussen, Henrik Koblitz; Eriksson, Torbjörn Gerhard

    2005-01-01

    The forming of micro surface structures on polymer materials is well established in polymer-processing operations. Numerical flow calculations were performed using the Lagrangian Integral Method where the fluid was described by a MSF constitutive model. The numerical modelling of the flow was per...

  7. The impact of changing solar screen rotation angle and its opening aspect ratios on Daylight Availability in residential desert buildings

    KAUST Repository

    Sherif, Ahmed H.

    2012-11-01

    In desert sunny clear-sky regions solar penetration can become excessive. This can cause non-uniform daylight distribution, glare and high solar heat gain, affecting both visual and thermal comfort. Shading devices, such as solar screens, were usually used to diffuse and prevent direct solar penetration into spaces. This paper investigates the impact of changing solar screen axial rotation angle and screen opening aspect ratio on daylighting performance in a typical residential living room space under the desert sunny clear-sky. The larger aim is to arrive at efficient solar screen designs that suit the different orientations.The study was divided into three consecutive phases. In phase one, the effect of the two parameters on Daylight Availability was tested. The solar screen was axially rotated by three different angles at 10° increments. Also, the aspect ratio of the screen opening in both horizontal and vertical directions was changed systematically. Simulation was conducted using the annual Daylight Dynamic Performance Metrics (DDPMs). In phase two, the Annual Daylight Glare Probability (DGP) metric was evaluated for the cases that were found adequate in phase one. In the third phase, the annual solar energy transmittance through the screen was calculated for the cases that achieved acceptable performance in the two previous phases in order to identify the more energy efficient screens.Solar screens with openings having horizontal aspect ratios were found to be the most effective, while those with vertical aspect ratios were achieved the lowest performance. In the North orientation, since almost all the cases that were tested in this research provided acceptable daylighting performance, the designer now have a variety of options to choose from. Preference should be given to screen openings of horizontal aspect ratios, especially the 12:1 and 18:1 (H:V) screens that achieved the best performance where 92% of the space was " daylit" in comparison with only 53

  8. Modeling transmission parameters of polymer microstructured fibers for applications in FTTH networks

    Science.gov (United States)

    Gdula, P.; Welikow, K.; Szczepański, P.; Buczyński, R.; Piramidowicz, R.

    2011-10-01

    This paper is focused on selected aspects of designing and modeling of transmission parameters of plastic optical fibers (POFs), considered in the context of their potential applications in optical access networks and, specifically, in Fiber-To- The-Home (FTTH) systems. The survey of state-of-the-art solutions is presented and possibility of improving transmission properties of POFs by microstructurization is discussed on the basis of the first results of numerical modeling. In particular, the microstructured POF was designed supporting propagation of limited number of modes while keeping relatively large mode area and, simultaneously, significantly lowered bending losses.

  9. Femtosecond fabrication of waveguide-like micro-structures in a photorefractive polymer

    Institute of Scientific and Technical Information of China (English)

    Min Gu; Tom Rodgers; Daniel Day

    2003-01-01

    In this letter, we report on, for the first time, the successful femtosecond micro-fabrication of continu-ous waveguide-like channels in the photorefractive polymer consisting of the nonlinear chromophore 2,5-dimethyl-4-(p-nitrophenylazo)anisole (DMNPAA), the photosensitive compound 2,4,7-trinitro-9-flourenone(TNF), and the plasticiser N-ethylcarbazole (ECZ) all doped in the polymer matrix poly(methyl methacry-late) (PMMA). These channels are caused by the change in refractive index as a result of the localisedheating of the polymer and therefore have an important potential for micro-photonic devices in future.

  10. Injection molding micro patterns with high aspect ratio using a polymeric flexible stamper

    Directory of Open Access Journals (Sweden)

    2011-11-01

    Full Text Available Poor filling occurs during the injection molding process of micro- or nano- scale patterns mainly because the hot polymer melt rapidly cools and its skin quickly solidifies upon contact with the mold surface. In this study, it is proposed to use Polyethylene terephthalate (PET film coated with patterned polyurethane acrylate (PUA as an effective thermal barrier. It can significantly hinder heat transfer into the mold during the molding process and thus may keep the melt viscosity low for longer duration. As a result, the replication would be improved not only during the filling phase but also during the packing phase. In order to verify the validity of the use of polymeric stamper, the melt-film interface temperature was evaluated by numerical simulation. Experimental results indicated that patterns possessing widths within the range of one to tens of micrometers and a height of approximately 10 µm were successfully filled and demolded.

  11. Single phase flow characteristics of FC-72 and ethanol in high aspect ratio rectangular mini- and micro-channels

    Science.gov (United States)

    Wang, Yuan; Wang, Zhen-guo

    2016-11-01

    Single phase flow friction factor of FC-72 and ethanol in mini-and micro-channels are experimentally investigated in the present study. High aspect ratio3 rectangular channels are selected, the hydraulic diameters of which are 571 µm, 762 µm and 1454 µm, and the aspect ratios are 20, 20 and 10 respectively. Degassed ethanol and FC-72 are used as working fluids. All the friction factors acquired in the 571 µm and 762 µm channels agree with the conventional friction theory within  ±20%-±25%. In the 1454 µm channel, however, deviations from the conventional theory occur and a modified empirical correlation of friction factor as a function of Reynolds number is proposed. Early transition from laminar to transitional flow is captured. Besides, effects of liquid physical properties are discussed. Lower viscosity and higher liquid density are responsible for the higher friction factor of FC-72. The influence of liquid properties weakens as the Reynolds number increases.

  12. Experimental Investigation of a High-Speed Hydrofoil with Parabolic Thickness Distribution and an Aspect Ratio of 3

    Science.gov (United States)

    Christopher, Kenneth W.

    1961-01-01

    An experimental investigation has been made to determine the hydro-dynamic characteristics of a 10-percent-thick hydrofoil with an aspect ratio of 3 designed to operate with acceptable efficiency at speeds in the neighborhood of 100 knots (169 fps). A cambered hydrofoil model with parabolic thickness distribution was investigated at a depth of chord over a range of angles of attack from -0.5 deg to 4.0 deg and at speeds from 120 to 210 fps. substantially wider range of operation at acceptable lift-drag ratios as well as higher maximum lift-drag-ratio values than did a hydrofoil of similar design with an aspect ratio of 1.

  13. The field emission properties of high aspect ratio diamond nanocone arrays fabricated by focused ion beam milling

    Directory of Open Access Journals (Sweden)

    Z.L. Wang, Q. Wang, H.J. Li, J.J. Li, P. Xu, Q. Luo, A.Z. Jin, H.F. Yang and C.Z. Gu

    2005-01-01

    Full Text Available High aspect ratio diamond nanocone arrays are formed on freestanding diamond film by means of focused ion beam (FIB milling technology and hot-filament chemical vapor deposition (HFCVD method. The structure and phase purity of an individual diamond nanocone are characterized by scanning electron microscopy (SEM and micro-Raman spectroscopy. The result indicates that the diamond cones with high aspect ratio and small tip apex radius can be obtained by optimizing the parameters of FIB milling and diamond growth. The diamond nanocone arrays were also used to study the electron field emission properties and electric field shielding effect, finding high emission current density, low threshold and weak shielding effect, all attributable to the high field enhancement factor and suitable cone density of the diamond nanocone emitter

  14. The effects of polymer melt rheology on the replication of surface microstructures in isothermal moulding

    DEFF Research Database (Denmark)

    Eriksson, Torbjörn Gerhard; Rasmussen, Henrik Koblitz

    2005-01-01

    Series of isothermal compression moulding experiments were performed with a polycarbonate and a polystyrene melt in a hot press. The bottom plate in the hot press was equipped with a microstructured nickel insert. The insert contained 10 parallel, rectangularly shaped microchannels with a depth o...

  15. The fluid mechanics of a high aspect ratio slot with an impressed pressure gradient and secondary injection

    Science.gov (United States)

    Sobanik, John Bertram

    1993-01-01

    A high aspect ratio slot flow (which emulates the gas leakage path in a gas turbine engine outer turbine air seal) is studied by use of a high aspect ratio slot using water as the working fluid. The cross section of the geometry is similar to a 'T', the slot being the vertical stroke and the main flow being the cross bar. A pressure gradient in the axial direction is created by blocking the main flow at a discreet location with an orifice plate (or blade tip simulator), located above the slot. Seven individually metered secondary flow injectors are located periodically along the bottom of the wall of the slot. Two slot widths, 1/8 and 1/4 inch, were investigated for length to width aspect ratios of 384 and 192 and height to width aspect ratios 33.2 and 16.6 respectively. Orifice plate pressure drops sufficient to give Reynolds numbers based upon half width of the slot, without secondary injection turned on, of 2350 and 4700 in the 1/8 inch slot and 4700 and 9400 in the 1/4 inch slot were run. Various secondary injection scenarios were added to the flow, the cases most studied being the no-injection and the all injectors flowing equal mass rates. Total injection rates for all seven injectors of 3.78 and 7.56 slot volumes per second were run. Laser velocimetry data and flow visualization pictures using fluorescein dye in the secondary flow are compared with computational results form the TEACH 3-D computer code. Major features and trends of the flow are captured by the computational model. Recommendations for further improvement of the numerical accuracy involves modification of the TEACH 3-D code to allow the 'slip condition' on all confining boundaries of the flow, or using a code which permits the 'slip condition' on all boundaries as a built-in option.

  16. Effect of impurity particles on the finite-aspect ratio neoclassical ion thermal conductivity in a tokamak

    Energy Technology Data Exchange (ETDEWEB)

    Chang, C.S.; Hinton, F.L.

    1986-10-01

    The effect of finite-aspect ratio on the impurity contribution to neoclassical ion thermal conductivity is studied. A simple modification to the pure-ion case is obtained with the assumption that the single heavy impurity species is in the Pfirsch-Schlueter regime. It is found that the impurity contribution is larger than the usual approximation: Z/sub eff/ times the pure ion thermal conductivity.

  17. Integrable perturbed magnetic fields in toroidal geometry: An exact analytical flux surface label for large aspect ratio

    Energy Technology Data Exchange (ETDEWEB)

    Kallinikos, N.; Isliker, H.; Vlahos, L.; Meletlidou, E. [Department of Physics, Aristotle University of Thessaloniki, GR-54124 Thessaloniki (Greece)

    2014-06-15

    An analytical description of magnetic islands is presented for the typical case of a single perturbation mode introduced to tokamak plasma equilibrium in the large aspect ratio approximation. Following the Hamiltonian structure directly in terms of toroidal coordinates, the well known integrability of this system is exploited, laying out a precise and practical way for determining the island topology features, as required in various applications, through an analytical and exact flux surface label.

  18. Effects of aspect ratio and concentration on rheology of epoxy suspensions containing model plate-like nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    White, K. L.; Takahara, A. [International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Fukuoka 819-0395 (Japan); Institute for Materials Chemistry and Engineering, Kyushu University, Fukuoka 819-0395 (Japan); Hawkins, S.; Sue, H.-J., E-mail: hjsue@tamu.edu [Department of Materials Science and Engineering, Texas A& M University, College Station, Texas 77843 (United States); Miyamoto, M. [Kaneka US Materials Research Center, Kaneka America Holdings, Inc., College Station, Texas 77843 (United States)

    2015-12-15

    Hexagonal 2-dimensional α-zirconium phosphate crystals were prepared with lateral diameters ranging from 110 nm to 1.5 μm to investigate the effect of particle size on suspension rheology. The nanoplatelets were exfoliated to individual sheets with monodisperse thickness and dispersed in a Newtonian epoxy fluid. The steady shear response of dilute and semi-dilute suspensions was measured and compared to expressions obtained from theory for infinitely dilute suspensions. For suspensions containing the smaller nanoplatelets, aspect ratio ∼160, the low shear rate viscosity and transition to shear thinning behavior were well described by theory for loadings up to 0.5 vol. %. The agreement was improved by assuming a moderate polydispersity in lateral diameter, ∼30%–50%, which is consistent with experimental observation. For the higher aspect ratio nanoplatelets, good agreement between theory and experiment was observed only at high shear rates. At lower shear rate, theory consistently over-predicted viscosity, which was attributed to a progressive shift to non-isotropic initial conditions with increasing particle size. The results suggest that at a fixed Peclet number, there is an increasing tendency for the nanoplatelets to form transient, local stacks as particle size increases. The largest particles, aspect ratio ∼2200, showed unusual shear thinning and thickening behaviors that were attributed to particle flexibility. The findings demonstrate the surprising utility of theory for infinitely dilute suspensions to interpret, and in some cases quantitatively describe, the non-Newtonian viscosity of real suspensions containing high aspect ratio plate-like particles. A simple framework is proposed to interpret deviations from ideal behavior based on the local and collective behavior of the suspended nanoplatelets.

  19. Fiber-optic liquid level monitoring system using microstructured polymer fiber Bragg grating array sensors: performance analysis

    DEFF Research Database (Denmark)

    Marques, C. A. F.; Pospori, A.; Saez-Rodriguez, D.;

    2015-01-01

    to interrogate liquid level by measuring the strain induced in each mPOFBG embedded in a silicone rubber (SR) diaphragm, which deforms due to hydrostatic pressure variations. The sensor exhibits a highly linear response over the sensing range, a good repeatability, and a high resolution. The sensitivity......A highly sensitive liquid level monitoring system based on microstructured polymer optical fiber Bragg grating (mPOFBG) array sensors is reported for the first time. The configuration is based on five mPOFBGs inscribed in the same fiber in the 850 nm spectral region, showing the potential...... of the sensor is found to be 98 pm/cm of water, enhanced by more than a factor of 9 when compared to an equivalent sensor based on a silica fiber around 1550 nm. The temperature sensitivity is studied and a multi-sensor arrangement proposed, which has the potential to provide level readings independent...

  20. Fabrication and characterization of polycarbonate microstructured polymer optical fibers for high-temperature-resistant fiber Bragg grating strain sensors

    DEFF Research Database (Denmark)

    Fasano, Andrea; Woyessa, Getinet; Stajanca, Pavol;

    2016-01-01

    Here we present the fabrication of a solid-core microstructured polymer optical fiber (mPOF) made of polycarbonate (PC), and report the first experimental demonstration of a fiber Bragg grating (FBG) written in a PC optical fiber. The PC used in this work has a glass transition temperature of 145°C....... We also characterize the mPOF optically and mechanically, and further test the sensitivity of the PC FBG to strain and temperature. We demonstrate that the PC FBG can bear temperatures as high as 125°C without malfunctioning. In contrast, polymethyl methacrylate-based FBG technology is generally...

  1. High-Tg TOPAS microstructured polymer optical fiber for fiber Bragg grating strain sensing at 110 degrees

    DEFF Research Database (Denmark)

    Markos, Christos; Stefani, Alessio; Nielsen, Kristian;

    2013-01-01

    We present the fabrication and characterization of fiber Bragg gratings (FBGs) in an endlessly single-mode microstructured polymer optical fiber (mPOF) made of humidity-insensitive high-Tg TOPAS cyclic olefin copolymer. The mPOF is the first made from grade 5013 TOPAS with a glass transition...... temperature of Tg = 135°C and we experimentally demonstrate high strain operation (2.5%) of the FBG at 98°C and stable operation up to a record high temperature of 110°C. The Bragg wavelengths of the FBGs are around 860 nm, where the propagation loss is 5.1dB/m, close to the fiber loss minimum of 3.67d...

  2. Seed-mediated synthesis of gold nanorods: control of the aspect ratio by variation of the reducing agent

    Energy Technology Data Exchange (ETDEWEB)

    Koeppl, Susanne; Ghielmetti, Nico [ETH Zurich, Laboratory for Nanometallurgy, Department of Materials (Switzerland); Caseri, Walter, E-mail: wcaseri@mat.ethz.ch [ETH Zurich, Polymer Technology, Department of Materials (Switzerland); Spolenak, Ralph [ETH Zurich, Laboratory for Nanometallurgy, Department of Materials (Switzerland)

    2013-03-15

    Seed-mediated growth methods involving reduction of tetrachloroaurate(III) with ascorbic acid are common for the synthesis of gold nanorods. This study shows, however, that simply by appropriate choice of the reducing agent a drastic influence on the aspect ratio can be attained. Weaker reducing agents, such as dihydroxybenzene isomers (hydroquinone, catechol or resorcinol) or glucose can increase the aspect ratio of the nanorods by an order of magnitude, up to values as high as 100 (nanowires). The increase in aspect ratio is mainly a consequence of an increase in length of the particles (up to 1-3 {mu}m). This effect is probably associated with a decrease in the reduction rate of gold(III) species by dihydroxybenzenes or glucose compared to ascorbic acid. The reduction potential of the reducing agents strongly depends on the pH value, and related effects on the dimensions of the nanoparticles are also reflected in this study. The nanorods exhibited penta-twinned nature without noteworthy defects (e.g. stacking faults and dislocations).

  3. Prediction of CO Concentration and Maximum Smoke Temperature beneath Ceiling in Tunnel Fire with Different Aspect Ratio

    Directory of Open Access Journals (Sweden)

    S. Gannouni

    2016-01-01

    Full Text Available In a tunnel fire, the production of smoke and toxic gases remains the principal prejudicial factors to users. The heat is not considered as a major direct danger to users since temperatures up to man level do not reach tenable situations that after a relatively long time except near the fire source. However, the temperatures under ceiling can exceed the thresholds conditions and can thus cause structural collapse of infrastructure. This paper presents a numerical analysis of smoke hazard in tunnel fires with different aspect ratio by large eddy simulation. Results show that the CO concentration increases as the aspect ratio decreases and decreases with the longitudinal ventilation velocity. CFD predicted maximum smoke temperatures are compared to the calculated values using the model of Li et al. and then compared with those given by the empirical equation proposed by kurioka et al. A reasonable good agreement has been obtained. The backlayering length decreases as the ventilation velocity increases and this decrease fell into good exponential decay. The dimensionless interface height and the region of bad visibility increases with the aspect ratio of the tunnel cross-sectional geometry.

  4. Bifurcation induced by the aspect ratio in a turbulent von Kármán swirling flow

    Science.gov (United States)

    Liot, Olivier; Burguete, Javier

    2017-01-01

    We evaluate the effect of the aspect ratio, i.e., the distance between the propellers H divided by the diameter D , on the slow dynamics of a von Kármán swirling flow driven by two propellers in a closed cylinder. We use a cell with a fixed diameter D but where the distance between the propellers can be turned continuously and where the inertia from the propellers can also be changed using different gears. No change on the dynamics is observed when the momentum of inertia is modified. Some dramatic changes of the shear layer position are observed modifying the aspect ratio Γ =H /D . A bifurcation of the shear layer position appears. Whereas for low Γ the shear layer position has a smooth evolution when turning the asymmetry between the rotation frequency of the propellers, for high Γ the transition becomes abrupt and a symmetry breaking appears. Secondly we observe that the spontaneous reversals with large residence times already observed in this experiment for Γ =1 [de la Torre and Burguete, Phys. Rev. Lett. 99, 054101 (2007), 10.1103/PhysRevLett.99.054101] exist only in a narrow window of aspect ratio. We show using an experimental study of the mean flow structure and a numerical approach based on a Langevin equation with colored noise that the shear layer position seems to be decided by the mean flow structure, whereas the reversals are linked to the spatial distribution of the turbulent fluctuations in the cell.

  5. Single macroscopic pillars as model system for bioinspired adhesives: influence of tip dimension, aspect ratio, and tilt angle.

    Science.gov (United States)

    Micciché, Maurizio; Arzt, Eduard; Kroner, Elmar

    2014-05-28

    The goal of our study is to better understand the design parameters of bioinspired dry adhesives inspired by geckos. For this, we fabricated single macroscopic pillars of 400 μm diameter with different aspect ratios and different tip shapes (i.e., flat tips, spherical tips with different radii, and mushroom tips with different diameters). Tilt-angle-dependent adhesion measurements showed that although the tip shape of the pillars strongly influences the pull-off force, the pull-off strength is similar for flat and mushroom-shaped tips. We found no tilt-angle dependency of adhesion for spherical tip structures and, except for high tilt angle and low preload experiments, no tilt-angle effect for mushroom-tip pillars. For flat-tip pillars, we found a strong influence of tilt angle on adhesion, which decreased linearly with increasing aspect ratio. The experiments show that for the tested aspect ratios between 1 and 5, a linear decrease of tilt-angle dependency is found. The results of our studies will help to design bioinspired adhesives for application on smooth and rough surfaces.

  6. Fabrication of high aspect ratio tungsten nanostructures on ultrathin c-Si membranes for extreme UV applications.

    Science.gov (United States)

    Delachat, F; Le Drogoff, B; Constancias, C; Delprat, S; Gautier, E; Chaker, M; Margot, J

    2016-01-15

    In this work, we demonstrate a full process for fabricating high aspect ratio diffraction optics for extreme ultraviolet lithography. The transmissive optics consists in nanometer scale tungsten patterns standing on flat, ultrathin (100 nm) and highly transparent (>85% at 13.5 nm) silicon membranes (diameter of 1 mm). These tungsten patterns were achieved using an innovative pseudo-Bosch etching process based on an inductively coupled plasma ignited in a mixture of SF6 and C4F8. Circular ultra-thin Si membranes were fabricated through a state-of-the-art method using direct-bonding with thermal difference. The silicon membranes were sputter-coated with a few hundred nanometers (100-300 nm) of stress-controlled tungsten and a very thin layer of chromium. Nanoscale features were written in a thin resist layer by electron beam lithography and transferred onto tungsten by plasma etching of both the chromium hard mask and the tungsten layer. This etching process results in highly anisotropic tungsten features at room temperature. The homogeneity and the aspect ratio of the advanced pattern transfer on the membranes were characterized with scanning electron microscopy after focus ion beam milling. An aspect ratio of about 6 for 35 nm size pattern is successfully obtained on a 1 mm diameter 100 nm thick Si membrane. The whole fabrication process is fully compatible with standard industrial semiconductor technology.

  7. Nanoimprinting ultrasmall and high-aspect-ratio structures by using rubber-toughened UV cured epoxy resist

    Science.gov (United States)

    Shin, Young Jae; Wu, Yi-Kuei; Guo, L. Jay

    2013-06-01

    A simple and robust scheme is proposed for the fabrication of nanoscale (20 nm line width) and high-aspect-ratio (9:1) structures by using modulus-tunable UV curable epoxy resists. Additionally, the ability to control the Young’s modulus of the imprinted material from hard to rigiflex using these epoxy resists is demonstrated. The physical properties of the new epoxy resists were controlled by adjusting the ratio of bisphenol F-type epoxy resin and acrylonitrile-butadiene rubber-based epoxy resin in the formulation of the resist. The mechanical properties of the resist were tuned to obtain various aspect ratios as well as mold flexibility for conformal contact over non-planar surfaces and large areas. In order to reduce the line width of the imprinted patterns, a process to conformally coat the mold structure by atomic layer deposition of alumina was also developed. Narrow lines with high-aspect-ratio features and with very low defect density were achieved via the new approach and the high mechanical strength of the new resist formulation.

  8. High precision and high aspect ratio laser drilling: challenges and solutions

    Science.gov (United States)

    Uchtmann, Hermann; He, Chao; Gillner, Arnold

    2016-03-01

    Laser drilling is a very versatile tool to produce high accuracy bores in small and large geometries using different technologies. In large and deep hole drilling laser drilling can be found in drilling cooling holes into turbomachinery components such as turbine blades. In micro drilling, the technology is used for the generation of nozzles and filters. However, especially in macro drilling, the process often causes microstructure changes and induces defects such as recast layers and cracks. The defects are caused by the melt dominated drilling process by using pulse durations in the range of some 100 μm up to a few ms. A solution of this problem is the use of ultrashort pulsed laser radiation with pulse durations in the range of some 100 fs up to a few ps, however with the disadvantage of long drilling times. Thus, the aim of this work is to combine the productive process by using ms pulsed fiber laser radiation with subsequent ablation of existing recast layers at the hole wall by using ultrashort pulsed laser radiation. By using fast scanning techniques the recast layer can be avoided almost completely. With a similar technology also very small hole can be produced. Using a rotating dove prism a circular oscillation of the laser spots is performed and holes are drilled at intervals in 1 mm thick stainless steel (1.4301) by ultra-short laser pulses of 7 ps at 515 nm. The formation of hole and the behavior of energy deposition differ from other drilling strategies due to the helical revolution. The temporal evolution of the hole shape is analyzed by means of SEM techniques from which three drilling phases can be distinguished.

  9. Properties and Microstructure of Polymer Emulsions Modified Fibers Reinforced Cementitious Composites

    Institute of Scientific and Technical Information of China (English)

    WU Ying; SUN Qianyao; KONG Lian; FANG He

    2014-01-01

    The synthesis and characterization of a new class of cementitious composites filled with polymer emulsions were investigated, and their superior mechanical strength and durability properties compared to composites devoid of fillers were reported. Polymer emulsions were utilized to mechanically reinforce the composite and bridge the cement, fly ash, aggregate and fibers. The results reveal that the epoxy emulsion and poly (ethylene-co-vinyl acetate) emulsion markedly enhance the mechanical and durability properties of cemetitious composites. The fibers can be pulled out in the form of slip-hardening and the abrasion phenomenon can be observed clearly on the surface of the fibers. The hydration extent of cement is higher than that of the pristine composites. The polymer modified cementitious composites designed on micromechanics, have flexibility and plasticity which could be applied for a novel form of multifunctional materials with a range of pipeline coatings applications.

  10. Effect of chain stiffness and temperature on the dynamics and microstructure of crystallizable bead-spring polymer melts

    Science.gov (United States)

    Nguyen, Hong T.; Hoy, Robert S.

    2016-11-01

    We contrast the dynamics in model unentangled polymer melts of chains of three different stiffnesses: flexible, intermediate, and rodlike. Flexible and rodlike chains, which readily solidify into close-packed crystals (respectively, with randomly oriented and nematically aligned chains), display simple melt dynamics with Arrhenius temperature dependence and a discontinuous change upon solidification. Intermediate-stiffness chains, however, are fragile glass-formers displaying Vogel-Fulcher dynamical arrest, despite the fact that they also possess a nematic-close-packed crystalline ground state. To connect this difference in dynamics to the differing microstructure of the melts, we examine how various measures of structure, including cluster-level metrics recently introduced in studies of colloidal systems, vary with chain stiffness and temperature. No clear static-structural cause of the dynamical arrest is found. However, we find that the intermediate-stiffness chains display qualitatively different dynamical heterogeneity. Specifically, their stringlike motion (cooperative rearrangement) is correlated along chain backbones in a way not found for either flexible or rodlike chains. This activated "crawling" motion is clearly associated with the dynamical arrest observed in these systems, and illustrates one way in which factors controlling the crystallization versus glass formation competition in polymers can depend nonmonotonically on chain stiffness.

  11. Production and Characterization of Polycarbonate Microstructured Polymer Optical Fiber Bragg Grating Sensor

    DEFF Research Database (Denmark)

    Fasano, Andrea; Woyessa, Getinet; Stajanca, P.

    2015-01-01

    , such as casting of pol-ymer granulates into a solid rod, machining and drilling of a 3-ring hexagonal lattice of holes into it, and finally drawing into fiber. We demonstrate that the obtained PC mPOF is photosensitive and FBGs can be conveniently inscribed into it, thereby enabling FBG-based temperature...

  12. Creation of a microstructured polymer optical fiber with UV Bragg grating inscription for the detection of extensions at temperatures up to 125°C

    DEFF Research Database (Denmark)

    Fasano, Andrea; Woyessa, Getinet; Stajanca, Pavol;

    2016-01-01

    We describe the fabrication of a polycarbonate (PC) micro-structured polymer optical fiber (mPOF) and the writing offiber Bragg gratings (FBGs) in it to enable strain and temperature measurements. We demonstrate the photosensitivity ofa dopant-free PC fiber by grating inscription using a UV laser....... We further show that PC Bragg gratings can be extendedup to at least 3% without affecting the initial functionality of the micro-structured fiber. The response of PC FBGs totemperature up to 125°C is also investigated. Polycarbonate has good mechanical properties and its high...

  13. Subsonic and transonic pressure measurements on a high-aspect-ratio supercritical-wing model with oscillating control surfaces

    Science.gov (United States)

    Sandford, M. C.; Ricketts, R. H.; Watson, J. J.

    1981-01-01

    A high aspect ratio supercritical wing with oscillating control surfaces is described. The semispan wing model was instrumented with 252 static orifices and 164 in situ dynamic pressure gases for studying the effects of control surface position and sinusoidal motion on steady and unsteady pressures. Data from the present test (this is the second in a series of tests on this model) were obtained in the Langley Transonic Dynamics Tunnel at Mach numbers of 0.60 and 0.78 and are presented in tabular form.

  14. Shrink film patterning by craft cutter: complete plastic chips with high resolution/high-aspect ratio channel.

    Science.gov (United States)

    Taylor, Douglas; Dyer, David; Lew, Valerie; Khine, Michelle

    2010-09-21

    This paper presents a rapid, ultra-low-cost approach to fabricate microfluidic devices using a polyolefin shrink film and a digital craft cutter. The shrinking process (with a 95% reduction in area) results in relatively uniform and consistent microfluidic channels with smooth surfaces, vertical sidewalls, and high aspect ratio channels with lateral resolutions well beyond the tool used to cut them. The thermal bonding of the layers results in strongly bonded devices. Complex microfluidic designs are easily designed on the fly and protein assays are also readily integrated into the device. Full device characterization including channel consistency, optical properties, and bonding strength are assessed in this technical note.

  15. Designs and processes toward high-aspect-ratio nanostructures at the deep nanoscale: unconventional nanolithography and its applications

    Science.gov (United States)

    Lee, Sori; Park, Byeonghak; Kim, Jun Sik; Kim, Tae-il

    2016-11-01

    The patterning of high-resolution-featured deep-nanoscale structures with a high aspect ratio (AR) has received increasing attention in recent years as a promising technique for a wide range of applications, including electrical, optical, mechanical and biological systems. Despite extensive efforts to develop viable nanostructure fabrication processes, a superior technique enabling defect-free, high-resolution control over a large area is still required. In this review, we focus on recent important advances in the designs and processes of high-resolution nanostructures possessing a high AR, including hierarchical and 3D patterns. The unique applications of these materials are also discussed.

  16. Buckling of ZnS-filled single-walled carbon nanotubes – The influence of aspect ratio

    KAUST Repository

    Monteiro, André O.

    2014-08-16

    The mechanical response of single-walled carbon nanotubes (SWCNT) filled with crystalline zinc sulphide (ZnS) nanowires under uniaxial compression is studied using classical molecular dynamics. These simulations were used to analyse the behaviour of SWCNT, with and without ZnS filling, in terms of critical force and critical strain. Force versus strain curves have been computed for hollow and filled systems, the latter clearly showing an improvement of the mechanical behaviour caused by the ZnS nanowire. The same simulations were repeated for a large range of dimensions in order to evaluate the influence of the aspect ratio on the mechanical response of the tubes.

  17. Real time ablation rate measurement during high aspect-ratio hole drilling with a 120-ps fiber laser.

    Science.gov (United States)

    Mezzapesa, Francesco P; Sibillano, Teresa; Di Niso, Francesca; Ancona, Antonio; Lugarà, Pietro M; Dabbicco, Maurizio; Scamarcio, Gaetano

    2012-01-02

    We report on the instantaneous detection of the ablation rate as a function of depth during ultrafast microdrilling of metal targets. The displacement of the ablation front has been measured with a sub-wavelength resolution using an all-optical sensor based on the laser diode self-mixing interferometry. The time dependence of the laser ablation process within the depth of aluminum and stainless steel targets has been investigated to study the evolution of the material removal rate in high aspect-ratio micromachined holes.

  18. Effect of wing aspect ratio and flap span on aerodynamic characteristics of an externally blown jet-flap STOL model

    Science.gov (United States)

    Smith, C. C., Jr.

    1973-01-01

    An investigation has been conducted to determine the effects of flap span and wing aspect ratio on the static longitudinal aerodynamic characteristics and chordwise and spanwise pressure distributions on the wing and trailing-edge flap of a straight-wing STOL model having an externally blown jet flap without vertical and horizontal tail surfaces. The force tests were made over an angle-of-attack range for several thrust coefficients and two flap deflections. The pressure data are presented as tabulated and plotted chordwise pressure-distribution coefficients for angles of attack of 1 and 16. Pressure-distribution measurements were made at several spanwise stations.

  19. Influence of Molecular Conformations and Microstructure on the Optoelectronic Properties of Conjugated Polymers

    KAUST Repository

    Botiz, Ioan

    2014-03-19

    It is increasingly obvious that the molecular conformations and the long-range arrangement that conjugated polymers can adopt under various experimental conditions in bulk, solutions or thin films, significantly impact their resulting optoelectronic properties. As a consequence, the functionalities and efficiencies of resulting organic devices, such as field-effect transistors, light-emitting diodes, or photovoltaic cells, also dramatically change due to the close structure/property relationship. A range of structure/optoelectronic properties relationships have been investigated over the last few years using various experimental and theoretical methods, and, further, interesting correlations are continuously revealed by the scientific community. In this review, we discuss the latest findings related to the structure/optoelectronic properties interrelationships that exist in organic devices fabricated with conjugated polymers in terms of charge mobility, absorption, photoluminescence, as well as photovoltaic properties. © 2014 by the authors.

  20. Hybrid optics for three-dimensional microstructuring of polymers via direct laser writing

    Science.gov (United States)

    Burmeister, Frank; Zeitner, Uwe D.; Nolte, Stefan; Tünnermann, Andreas

    2012-03-01

    We present an immersion hybrid optics specially designed for focusing ultrashort laser pulses into a polymer for direct laser writing via two-photon polymerization. The hybrid optics enables well corrected focusing over a working distance range of 577 μm with a numerical aperture (NA) of 1.33 thereby causing low internal dispersion. We combine the concepts of an aplanatic solid immersion lens (ASIL) for achieving a high NA with the correction of aberrations with a diffractive optical element (DOE). To demonstrate the improvements for volume structuring of the polymer, we compare achievable feature sizes of structures written with our optics and a commercial available oil immersion objective (100x, NA=1.4).

  1. Influence of Molecular Conformations and Microstructure on the Optoelectronic Properties of Conjugated Polymers

    Directory of Open Access Journals (Sweden)

    Ioan Botiz

    2014-03-01

    Full Text Available It is increasingly obvious that the molecular conformations and the long-range arrangement that conjugated polymers can adopt under various experimental conditions in bulk, solutions or thin films, significantly impact their resulting optoelectronic properties. As a consequence, the functionalities and efficiencies of resulting organic devices, such as field-effect transistors, light-emitting diodes, or photovoltaic cells, also dramatically change due to the close structure/property relationship. A range of structure/optoelectronic properties relationships have been investigated over the last few years using various experimental and theoretical methods, and, further, interesting correlations are continuously revealed by the scientific community. In this review, we discuss the latest findings related to the structure/optoelectronic properties interrelationships that exist in organic devices fabricated with conjugated polymers in terms of charge mobility, absorption, photoluminescence, as well as photovoltaic properties.

  2. Computer Simulation of Spatial Arrangement and Connectivity of Particles in Three-Dimensional Microstructure: Application to Model Electrical Conductivity of Polymer Matrix Composite

    Science.gov (United States)

    Louis, P.; Gokhale, A. M.

    1996-01-01

    Computer simulation is a powerful tool for analyzing the geometry of three-dimensional microstructure. A computer simulation model is developed to represent the three-dimensional microstructure of a two-phase particulate composite where particles may be in contact with one another but do not overlap significantly. The model is used to quantify the "connectedness" of the particulate phase of a polymer matrix composite containing hollow carbon particles in a dielectric polymer resin matrix. The simulations are utilized to estimate the morphological percolation volume fraction for electrical conduction, and the effective volume fraction of the particles that actually take part in the electrical conduction. The calculated values of the effective volume fraction are used as an input for a self-consistent physical model for electrical conductivity. The predicted values of electrical conductivity are in very good agreement with the corresponding experimental data on a series of specimens having different particulate volume fraction.

  3. Three-dimensional wake topology and propulsive performance of low-aspect-ratio pitching-rolling plates

    Science.gov (United States)

    Li, Chengyu; Dong, Haibo

    2016-07-01

    The wake topology and propulsive performance of low-aspect-ratio plates undergoing a pitching-rolling motion in a uniform stream were numerically investigated by an in-house immersed-boundary-method-based incompressible Navier-Stokes equation solver. A detailed analysis of the vortical structures indicated that the pitching-rolling plate produced double-loop vortices with alternating signs from its trailing edge every half period. These vortices then shed and further evolved into interconnected "double-C"-shaped vortex rings, which eventually formed a bifurcating wake pattern in the downstream. As the wake convected downstream, there was a slight deflection in the spanwise direction to the plate tip, and the contained vortex ring size gradually increased. In addition, the analysis of the propulsive performance indicated that the shedding process of the double-loop vortices led to two peaks in the lift and thrust force production per half cycle. The observation of the double peaks in the force production is in agreement with previous flapping wing studies. Simulations were also used to examine the variations in the wake structures and propulsive performance of the plates over a range of major parameters. The aforementioned vortex structures were found to be quite robust over a range of Strouhal numbers, Reynolds numbers, and plate aspect ratios.

  4. Effects of AC/DC magnetic fields, frequency, and nanoparticle aspect ratio on cellular transfection of gene vectors

    Science.gov (United States)

    Ford, Kris; Mair, Lamar; Fisher, Mike; Rowshon Alam, Md.; Juliano, Rudolph; Superfine, Richard

    2008-10-01

    In order to make non-viral gene delivery a useful tool in the study and treatment of genetic disorders, it is imperative that these methodologies be further refined to yield optimal results. Transfection of magnetic nanoparticles and nanorods are used as non-viral gene vectors to transfect HeLa EGFP-654 cells that stably express a mutated enhanced green fluorescent protein (EGFP) gene. We deliver antisense oligonucleotides to these cells designed to correct the aberrant splicing caused by the mutation in the EGFP gene. We also transfect human bronchial endothelial cells and immortalized WI-38 lung cells with pEGFP-N1 vectors. To achieve this we bind the genes to magnetic nanoparticles and nanorods and introduce magnetic fields to effect transfection. We wish to examine the effects of magnetic fields on the transfection of these particles and the benefits of using alternating (AC) magnetic fields in improving transfection rates over direct (DC) magnetic fields. We specifically look at the frequency dependence of the AC field and particle aspect ratio as it pertains to influencing transfection rate. We posit that the increase in angular momentum brought about by the AC field and the high aspect ratio of the nanorod particles, is vital to generating the force needed to move the particle through the cell membrane.

  5. A sub-atmospheric chemical vapor deposition process for deposition of oxide liner in high aspect ratio through silicon vias.

    Science.gov (United States)

    Lisker, Marco; Marschmeyer, Steffen; Kaynak, Mehmet; Tekin, Ibrahim

    2011-09-01

    The formation of a Through Silicon Via (TSV) includes a deep Si trench etching and the formation of an insulating layer along the high-aspect-ratio trench and the filling of a conductive material into the via hole. The isolation of the filling conductor from the silicon substrate becomes more important for higher frequencies due to the high coupling of the signal to the silicon. The importance of the oxide thickness on the via wall isolation can be verified using electromagnetic field simulators. To satisfy the needs on the Silicon dioxide deposition, a sub-atmospheric chemical vapor deposition (SA-CVD) process has been developed to deposit an isolation oxide to the walls of deep silicon trenches. The technique provides excellent step coverage of the 100 microm depth silicon trenches with the high aspect ratio of 20 and more. The developed technique allows covering the deep silicon trenches by oxide and makes the high isolation of TSVs from silicon substrate feasible which is the key factor for the performance of TSVs for mm-wave 3D packaging.

  6. The Space-Time CESE Method Applied to Viscous Flow Computations with High-Aspect Ratio Triangular or Tetrahedral Meshes

    Science.gov (United States)

    Chang, Chau-Lyan; Venkatachari, Balaji

    2016-11-01

    Flow physics near the viscous wall is intrinsically anisotropic in nature, namely, the gradient along the wall normal direction is much larger than that along the other two orthogonal directions parallel to the surface. Accordingly, high aspect ratio meshes are employed near the viscous wall to capture the physics and maintain low grid count. While such arrangement works fine for structured-grid based methods with dimensional splitting that handles derivatives in each direction separately, similar treatments often lead to numerical instability for unstructured-mesh based methods when triangular or tetrahedral meshes are used. The non-splitting treatment of near-wall gradients for high-aspect ratio triangular or tetrahedral elements results in an ill-conditioned linear system of equations that is closely related to the numerical instability. Altering the side lengths of the near wall tetrahedrons in the gradient calculations would make the system less unstable but more dissipative. This research presents recent progress in applying numerical dissipation control in the space-time conservation element solution element (CESE) method to reduce or alleviate the above-mentioned instability while maintaining reasonable solution accuracy.

  7. Microstructuring of polymer films by femtosecond pulses through optically trapped polystyrene microspheres

    Energy Technology Data Exchange (ETDEWEB)

    Astaf' ev, A A; Shakhov, A M; Sarkisov, Oleg M; Nadtochenko, V A

    2013-04-30

    We report the laser ablation of polymers by femtosecond (18 and 54 fs) pulses focused by 1 and 3.8 {mu}m diameter spherical microlenses, which are held by optical traps. It is shown that this technique allows one to produce surface structures with lateral dimensions up to {lambda}/6 (125 nm). It is found that the size of the structures depends on the diameter of the microlens; the highest spatial resolution is achieved by using 1 {mu}m diameter microlenses. (extreme light fields and their applications)

  8. Effect of crystalline microstructure on the photophysical performance of polymer/perylene composite films

    Institute of Scientific and Technical Information of China (English)

    封伟; 徐友龙; 易文辉; 周峰; 王晓工; 吉野勝美

    2003-01-01

    To obtain high carrier mobility, better charge injection capability, and high photovoltaic device conversion efficiency, a powerful strategy is to improve the morphology of the polymer/dye composite films. Conjugated conducting polymer (CP) thin films doped with perylene derivative (PV) of various concentrations were prepared by spin-casting method, and their morphology and photovoltaic characteristics were examined. The change in morphology and molecular reorientation occurring in CP-PV composite films upon annealing at different temperatures was investigated using scanning electron microscopy, x-ray diffraction, Fourier transform infrared and UV-vis absorption. By changing the annealing temperature, PV microcrystallines of 8-10μm in size lying parallel to the substrate surface can be obtained.Annealing effect improved the photovoltaic performance of ITO/CP-PV/A1 Schottky-type solar cells, which can be attributed to the formation of an electron conducting PV crystal network. Preliminary studies indicate that the morphological structure in CP-PV composite films has an important influence to their photovoltaic properties.

  9. Inorganic polymers from laterite using activation with phosphoric acid and alkaline sodium silicate solution: Mechanical and microstructural properties

    Energy Technology Data Exchange (ETDEWEB)

    Lassinantti Gualtieri, Magdalena, E-mail: magdalena.gualtieri@unimore.it [Dipartimento di Ingegneria " Enzo Ferrari" , Università degli studi di Modena e Reggio Emilia, Via Vignolese 905/a, I-41125 Modena (Italy); Romagnoli, Marcello [Dipartimento di Ingegneria " Enzo Ferrari" , Università degli studi di Modena e Reggio Emilia, Via Vignolese 905/a, I-41125 Modena (Italy); Pollastri, Simone; Gualtieri, Alessandro F. [Dipartimento di Scienze Chimiche e Geologiche, Università degli studi di Modena e Reggio Emilia, Via S. Eufemia 19I, I-41121 Modena (Italy)

    2015-01-15

    Geopolymers from laterite, an iron-rich soil available in developing countries, have great potential as building materials. In this work, laterite from Togo (Africa) was used to prepare geopolymers using both phosphoric acid and alkaline sodium silicate solution. Microstructural properties were investigated by scanning electron microscopy, X-ray powder diffraction and mercury porosimetry, whereas thermal properties were evaluated by thermal analyses. The local environment of iron was studied by X-ray Absorption Spectroscopy (XANES region). The mechanical properties were determined. Modulus of Rupture and Young's modulus fell in the ranges 3.3–4.5 MPa and 12–33 GPa, respectively, rendering the materials good candidates for construction purposes. Heating above 900 °C results in weight-gain, presumably due to iron redox reactions. X-ray Absorption Spectroscopy data evidence changes in the chemical and structural environments of iron following thermal treatment of geopolymers. These changes indicate interaction between the geopolymer structure and iron during heating, possibly leading to redox properties. -- Highlights: •Geopolymerization of laterite is promising for fabrication of building materials. •Both phosphoric acid and alkaline sodium silicate solution can be used for activation. •Thermally activated redox properties of the inorganic polymers were observed.

  10. Characterisation and microstructure of reduced-fat chicken patties made with a novel polymer from Agrobacterium radiobacter k84.

    Science.gov (United States)

    Calliari, Caroline Maria; de Souza, Evandro Leite; Castro-Goméz, Raúl Jorge Hernan; Honório, Vanessa Gonçalves; Magnani, Marciane

    2015-04-15

    Chicken patties elaborated with a novel polymer from Agrobacterium radiobacter k84 (ARB) were characterised during 60days of frozen storage. After cooking, formulations without ARB (F0), with ARB 5 g/100 g (F5) and ARB 10 g/100 g (F10) presented 4.23%, 2.83% and 0.11% fat, respectively. No differences were observed to water holding capacity, cooking yield and shear force among formulations. Microstructural analysis showed formation of meat emulsion for F5 and gel for F10. Colour and chicken flavour decreased with increase of ARB; no difference was found for tenderness among the formulations. Overall acceptance showed higher scores for F0 when compared to F5 and F10. Lipid oxidation was not a limiting factor for stability of patties; all formulations presented suitable microbiological quality over the assessed period. These results suggest ARB as a promising fat substitute, capable of maintain the quality aspects of chicken patties, although a negative impact in colour has been found.

  11. The glass transition temperature and microstructure of polyurethane/epoxy resin interpenetrating polymer networks nanocomposites

    Institute of Scientific and Technical Information of China (English)

    JIA Qingming; ZHENG Maosheng; SHEN Renjie; CHEN Hongxiang

    2006-01-01

    Nanocomposites with various contents of organophilic montmorillonite (oMMT) have been prepared by adding oMMT to interpenetrating polymer networks (IPNs) of polyurethane and epoxy resin (PU/EP) which had been prepared by a sequential polymeric technique. DSC experiment indicates a novel phenomenon that the glass transition temperature (Tg) of the nanocomposites increases with the oMMT content up to 3 %, then decreases with further increasing oMMT content. In order to explain this phenomenon, crosslink density, hydrogen bonding in the hard segments, crystallization of the nanocomposites and the exfoliation degree of oMMT in the nanocomposites have been investigated by swelling method, FT-IR, XRD, SEM and TEM, respectively. The results indicate that the crosslink density and the hydrogen bonding index of the nanocomposites increase, but the crystallization degree of the nanocomposites decreases with increasing oMMT content. In addition, oMMT improves the network structure of PU/EP.

  12. Multifunctional microstructured polymer films for boosting solar power generation of silicon-based photovoltaic modules.

    Science.gov (United States)

    Leem, Jung Woo; Choi, Minkyu; Yu, Jae Su

    2015-02-04

    We propose two-dimensional periodic conical micrograting structured (MGS) polymer films as a multifunctional layer (i.e., light harvesting and self-cleaning) at the surface of outer polyethylene terephthalate (PET) cover-substrates for boosting the solar power generation in silicon (Si)-based photovoltaic (PV) modules. The surface of ultraviolet-curable NOA63 MGS polymer films fabricated by the soft imprint lithography exhibits a hydrophobic property with water contact angle of ∼121° at no inclination and dynamic advancing/receding water contact angles of ∼132°/111° at the inclination angle of 40°, respectively, which can remove dust particles or contaminants on the surface of PV modules in real outdoor environments (i.e., self-cleaning). The NOA63 MGS film coated on the bare PET leads to the reduction of reflection as well as the enhancement of both the total and diffuse transmissions at wavelengths of 300-1100 nm, indicating lower solar weighted reflectance (RSW) of ∼8.2%, higher solar weighted transmittance (TSW) of ∼93.1%, and considerably improved average haze ratio (HAvg) of ∼88.3% as compared to the bare PET (i.e., RSW ≈ 13.5%, TSW ≈ 86.9%, and HAvg ≈ 9.1%), respectively. Additionally, it shows a relatively good durability at temperatures of ≤160 °C. The resulting Si PV module with the NOA63 MGS/PET has an enhanced power conversion efficiency (PCE) of 13.26% (cf., PCE = 12.55% for the reference PV module with the bare PET) due to the mainly improved short circuit current from 49.35 to 52.01 mA, exhibiting the PCE increment percentage of ∼5.7%. For light incident angle-dependent PV module current-voltage characteristics, superior solar energy conversion properties are also obtained in a broad angle range of 10-80°.

  13. High fidelity replication of surface texture and geometric form of a high aspect ratio aerodynamic test component

    Science.gov (United States)

    Walton, Karl; Fleming, Leigh; Goodhand, Martin; Racasan, Radu; Zeng, Wenhan

    2016-06-01

    This paper details, assesses and validates a technique for the replication of a titanium wind tunnel test aerofoil in polyurethane resin. Existing resin replication techniques are adapted to overcome the technical difficulties associated with casting a high aspect ratio component. The technique is shown to have high replication fidelity over all important length-scales. The blade chord was accurate to 0.02%, and the maximum blade thickness was accurate to 2.5%. Important spatial and amplitude areal surface texture parameter were accurate to within 2%. Compared to an existing similar system using correlation areal parameters the current technique is shown to have lower fidelity and this difference is discussed. The current technique was developed for the measurement of boundary layer flow ‘laminar to turbulent’ transition for gas turbine compressor blade profiles and this application is illustrated.

  14. Propagation delay and power dissipation for different aspect ratio of single-walled carbon nanotube bundled TSV

    Science.gov (United States)

    Goyal, Tanu; Majumder, Manoj Kumar; Kaushik, Brajesh Kumar

    2015-06-01

    Through-silicon vias (TSVs) have provided an attractive solution for three-dimensional (3D) integrated devices and circuit technologies with reduced parasitic losses and power dissipation, higher input-output (I/O) density and improved system performance. This paper investigates the propagation delay and average power dissipation of single-walled carbon nanotube bundled TSVs having different via radius and height. Depending on the physical configuration, a comprehensive and accurate analytical model of CNT bundled TSV is employed to represent the via (vertical interconnect access) line of a driver-TSV-load (DTL) system. The via radius and height are used to estimate the bundle aspect ratio (AR) and the cross-sectional area. For a fixed via height, the delay and the power dissipation are reduced up to 96.2% using a SWCNT bundled TSV with AR = 300 : 1 in comparison to AR = 6 : 1.

  15. Hydrothermal Synthesis of ZnO Structures Formed by High-Aspect-Ratio Nanowires for Acetone Detection.

    Science.gov (United States)

    Cao, Zhen; Wang, Yong; Li, Zhanguo; Yu, Naisen

    2016-12-01

    Snowflake-like ZnO structures originating from self-assembled nanowires were prepared by a low-temperature aqueous solution method. The as-grown hierarchical ZnO structures were investigated by X-ray diffraction (XRD) and field-emission scanning electron microscopy (FESEM). The results showed that the snowflake-like ZnO structures were composed of high-aspect-ratio nanowires. Furthermore, gas-sensing properties to various testing gases of 10 and 50 ppm were measured, which confirms that the ZnO structures were of good selectivity and response to acetone and could serve for acetone sensor to detect low-concentration acetone.

  16. Internal Laser Writing of High-Aspect-Ratio Microfluidic Structures in Silicate Glasses for Lab-on-a-Chip Applications

    Directory of Open Access Journals (Sweden)

    Ya Cheng

    2017-02-01

    Full Text Available Femtosecond laser direct writing is unique in allowing for fabrication of 3D micro- and nanofluidic structures, thereby enabling rapid and efficient manipulation of fluidic dynamics in 3D space to realize innovative functionalities. Here, I discuss the challenges in producing fully functional and highly integrated 3D micro- and nanofluidic systems with potential applications ranging from chemical and biological analyses to investigations of nanofluidic behaviors. In particular, I review the achievements we have made in the past decade, which have led to 3D microchannels with controllable cross-sectional profiles and large aspect ratios, 3D nanofluidic channels with widths of several tens of nanometers, and smooth inner walls with roughness on the order of ~1 nm. Integration of the microfluidics with other functional microcomponents including microoptics and microelectrodes will also be discussed, followed by conclusions and the future perspective.

  17. Freestanding membrane composed of micro-ring array with ultrahigh sidewall aspect ratio for application in lightweight cathode arrays

    Science.gov (United States)

    Wang, Lanlan; Liu, Hongzhong; Jiang, Weitao; Gao, Wei; Chen, Bangdao; Li, Xin; Ding, Yucheng; An, Ningli

    2014-12-01

    A freestanding multilayer ultrathin nano-membrane (FUN-membrane) with a micro-ring array (MRA) is successfully fabricated through the controllable film deposition. Each micro-ring of FUN-membrane is 3 μm in diameter, 2 μm in height and sub-100 nm in sidewall thickness, demonstrating an ultrahigh sidewall aspect ratio of 20:1. In our strategy, a silica layer (200 nm in thickness), a chromium transition layer (5 nm-thick) and a gold layer (40 nm-thick), were in sequence deposited on patterned photoresist. After removal of the photoresist by lift-off process, a FUN-membrane with MRA was peeled off from the substrate, where the gold layer acted as a protecting layer to prevent the MRA from fracture. The FUN-membrane was then transferred to a flexible polycarbonate (PC) sheet coated with indium tin oxide (ITO) layer, which was then used as a flexible and lightweight cathode. Remarkably, the field emission effect of the fabricated FUN-membrane cathode performs a high field-enhancement factor of 1.2 × 104 and a low turn-on voltage of 2 V/μm, indicating the advantages of the sharp metal edge of MRA. Due to the rational design and material versatility, the FUN-membrane thus could be transferred to either rigid or flexible substrate, even curved surface, such as the skin of bio-robot's arm or leg. Additionally, the FUN-membrane composed of MRA with extremely high aspect ratio of insulator-metal sidewall, also provides potential applications in optical devices, lightweight and flexible display devices, and electronic eye imagers.

  18. Conductivity and methanol permeability of Nafion-zirconium phosphate composite membranes containing high aspect ratio filler particles

    Energy Technology Data Exchange (ETDEWEB)

    Bagnasco, G.; Micoli, L.; Turco, M. [Dipartimento di Ingegneria Chimica, Universita di Napoli Federico II, P.le V. Tecchio 80, 80125 - Napoli (Italy); Donnadio, A.; Pica, M.; Sganappa, M. [Dipartimento di Chimica, Universita di Perugia, via Elce di Sotto 8, 06123 - Perugia (Italy); Casciola, M.

    2009-08-15

    Gels of exfoliated {alpha}-zirconium phosphate (ZrP{sub exf}) in dimethylformamide (DMF) were used to prepare Nafion/ZrP{sub exf} composite membranes with filler loadings up to 7 wt.-% by casting mixtures of Nafion 1100 solutions in DMF and suitable amounts of 2 wt.-% ZrP gels in DMF. TEM pictures showed that the ZrP{sub exf} particles had aspect ratio of at least 20. All samples were characterised by methanol permeability (P) and through-plane ({sigma}{sub thp}) and in-plane ({sigma}{sub inp}) conductivity measurements at 40 C and 100% RH. The methanol permeability of Nafion membranes containing in situ grown ZrP particles with low aspect ratio (Nafion/ZrP{sub isg}) was also determined. The methanol permeability and the swelling behaviour of the composite membranes turned out to be strongly dependent on the filler morphology. As a general trend, both permeability and swelling decreased according to the sequence: Nafion/ZrP{sub isg} > Nafion > Nafion/ZrP{sub exf}. The maximum selectivity ({sigma}{sub thp}/P = 1.4 x 10{sup 5} S cm{sup -3} s) was found for the membrane filled with 1 wt.-% ZrP{sub exf}: this value is seven times higher than that of Nafion. For the Nafion/ZrP{sub exf} membranes, the ratio {sigma}{sub inp}/{sigma}{sub thp} increases with the filler loading, thus indicating that the preferred orientation of the ZrP sheets is parallel to the membrane surface. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

  19. Microstructural, Chemical and Mechanical Characterization of Polymer-Derived Hi-Nicalon Fibers with Surface Coatings

    Science.gov (United States)

    Bansal, Narottam P.; Chen, Yuan L.

    1998-01-01

    Room temperature tensile strengths of as-received Hi-Nicalon fibers and those having BN/SiC, p-BN/SiC, and p-B(Si)N/SiC surface coatings, deposited by chemical vapor deposition, were measured using an average fiber diameter of 13.5 microns. The Weibull statistical parameters were determined for each fiber. The average tensile strength of uncoated Hi-Nicalon on was 3.19 +/- 0.73 GPa with a Weibull modulus of 5.41. Strength of fibers coated with BN/SiC did not change. However, coat with p-BN/SiC and p-B(Si)N/SiC surface layers showed strength loss of approx. 10 and 35 percent, respectively, compared with as-received fibers. The elemental compositions of the fibers and the coatings were analyzed using scanning Auger microprobe and energy dispersive x-ray spectroscopy. The BN coating was contaminated with a large concentration of carbon and some oxygen. In contrast, p-BN, p-B(Si)N, and SiC coatings did not show any contamination. Microstructural analyses of the fibers and the coatings were done by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and selected area electron diffraction. Hi-Nicalon fiber consists of the P-SIC nanocrystals ranging in size from 1 to 30 nm embedded in an amorphous matrix. TEM analysis of the BN coating revealed four distinct layers with turbostatic structure. The p-BN layer was turbostratic and showed considerable preferred orientation. The p-B(Si)N was glassy and the silicon and boron were uniformly distributed. The silicon carbide coating was polycrystalline with a columnar structure along the growth direction. The p-B(Si)N/SiC coatings were more uniform, less defective and of better quality than the BN/SiC or the p-BN/SiC coatings.

  20. Electrodeposition of Gold to Conformally Fill High Aspect Ratio Nanometric Silicon Grating Trenches: A Comparison of Pulsed and Direct Current Protocols

    OpenAIRE

    Znati, Sami A.; Chedid, Nicholas; Miao, Houxun; Chen,Lei; Bennett, Eric E.; Wen, Han

    2015-01-01

    Filling high-aspect-ratio trenches with gold is a frequent requirement in the fabrication of x-ray optics as well as micro-electronic components and other fabrication processes. Conformal electrodeposition of gold in sub-micron-width silicon trenches with an aspect ratio greater than 35 over a grating area of several square centimeters is challenging and has not been described in the literature previously. A comparison of pulsed plating and constant current plating led to a gold electroplatin...

  1. Numerical investigation of non-Newtonian fluids in annular ducts with finite aspect ratio using lattice Boltzmann method.

    Science.gov (United States)

    Khali, S; Nebbali, R; Ameziani, D E; Bouhadef, K

    2013-05-01

    In this work the instability of the Taylor-Couette flow for Newtonian and non-Newtonian fluids (dilatant and pseudoplastic fluids) is investigated for cases of finite aspect ratios. The study is conducted numerically using the lattice Boltzmann method (LBM). In many industrial applications, the apparatuses and installations drift away from the idealized case of an annulus of infinite length, and thus the end caps effect can no longer be ignored. The inner cylinder is rotating while the outer one and the end walls are maintained at rest. The lattice two-dimensional nine-velocity (D2Q9) Boltzmann model developed from the Bhatnagar-Gross-Krook approximation is used to obtain the flow field for fluids obeying the power-law model. The combined effects of the Reynolds number, the radius ratio, and the power-law index n on the flow characteristics are analyzed for an annular space of finite aspect ratio. Two flow modes are obtained: a primary Couette flow (CF) mode and a secondary Taylor vortex flow (TVF) mode. The flow structures so obtained are different from one mode to another. The critical Reynolds number Re(c) for the passage from the primary to the secondary mode exhibits the lowest value for the pseudoplastic fluids and the highest value for the dilatant fluids. The findings are useful for studies of the swirling flow of non-Newtonians fluids in axisymmetric geometries using LBM. The flow changes from the CF to TVF and its structure switches from the two-cells to four-cells regime for both Newtonian and dilatant fluids. Contrariwise for pseudoplastic fluids, the flow exhibits 2-4-2 structure passing from two-cells to four cells and switches again to the two-cells configuration. Furthermore, the critical Reynolds number presents a monotonic increase with the power-law index n of the non-Newtonian fluid, and as the radius ratio grows, the transition flow regimes tend to appear for higher critical Reynolds numbers.

  2. An implicit wetting and drying approach for non-hydrostatic baroclinic flows in high aspect ratio domains

    Science.gov (United States)

    Candy, A. S.

    2017-04-01

    A new approach to modelling free surface flows is developed that enables, for the first time, 3D consistent non-hydrostatic baroclinic physics that wets and drys in the large aspect ratio spatial domains that characterise geophysical systems. This is key in the integration of physical models to permit seamless simulation in a single consistent arbitrarily unstructured multiscale and multi-physics dynamical model. A high order continuum representation is achieved through a general Galerkin finite element formulation that guarantees local and global mass conservation, and consistent tracer advection. A flexible spatial discretisation permits conforming domain bounds and a variable spatial resolution, whilst atypical use of fully implicit time integration ensures computational efficiency. Notably this brings the natural inclusion of non-hydrostatic baroclinic physics and a consideration of vertical inertia to flood modelling in the full 3D domain. This has application in improving modelling of inundation processes in geophysical domains, where dynamics proceeds over a large range of horizontal extents relative to vertical resolution, such as in the evolution of a tsunami, or in urban environments containing complex geometric structures at a range of scales.

  3. Ionic transport through sub-10 nm diameter hydrophobic high-aspect ratio nanopores: experiment, theory and simulation.

    Science.gov (United States)

    Balme, Sébastien; Picaud, Fabien; Manghi, Manoel; Palmeri, John; Bechelany, Mikhael; Cabello-Aguilar, Simon; Abou-Chaaya, Adib; Miele, Philippe; Balanzat, Emmanuel; Janot, Jean Marc

    2015-06-03

    Fundamental understanding of ionic transport at the nanoscale is essential for developing biosensors based on nanopore technology and new generation high-performance nanofiltration membranes for separation and purification applications. We study here ionic transport through single putatively neutral hydrophobic nanopores with high aspect ratio (of length L = 6 μm with diameters ranging from 1 to 10 nm) and with a well controlled cylindrical geometry. We develop a detailed hybrid mesoscopic theoretical approach for the electrolyte conductivity inside nanopores, which considers explicitly ion advection by electro-osmotic flow and possible flow slip at the pore surface. By fitting the experimental conductance data we show that for nanopore diameters greater than 4 nm a constant weak surface charge density of about 10(-2) C m(-2) needs to be incorporated in the model to account for conductance plateaus of a few pico-siemens at low salt concentrations. For tighter nanopores, our analysis leads to a higher surface charge density, which can be attributed to a modification of ion solvation structure close to the pore surface, as observed in the molecular dynamics simulations we performed.

  4. Mild oxide-hydrothermal synthesis of different aspect ratios of monoclinic BiVO{sub 4} nanorods tuned by temperature

    Energy Technology Data Exchange (ETDEWEB)

    Dong, Fengqiang; Wu, Qingsheng; Ma, Jie; Chen, Yijun [Department of Chemistry, Tongji University, Shanghai (China)

    2009-01-15

    The monoclinic scheelite BiVO{sub 4} nanocrystals were easily prepared via an oxide-hydrothermal synthesis (OHS) method directly utilizing bulk-phase materials of V{sub 2}O{sub 5} and Bi{sub 2}O{sub 3} as precursor. In the presence of PEG 4000, the reactions were performed in the mild temperature range from 130 C to 200 C. The products were characterized with FTIR, XRD, TEM and UV-vis DRS. These data clearly demonstrated that monoclinic scheelite structure BiVO{sub 4} could be synthesized by the feasible OHS route. The aspect ratios of nanorods were increased with the synthesized temperature. The as-prepared BiVO{sub 4} showed high photocatalytic activity, which was demonstrated by degradation of methylene blue (MB) solution under visible-light irradiation ({lambda}>420 nm). A growth mechanism of bismuth vanadate was proposed. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  5. Application of Self-Assembled Monolayers to the Electroless Metallization of High Aspect Ratio Vias for Microelectronics

    Science.gov (United States)

    Bernasconi, R.; Molazemhosseini, A.; Cervati, M.; Armini, S.; Magagnin, L.

    2016-10-01

    All-wet electroless metallization of through-silicon vias (TSVs) with a width of 5 μm and a 1:10 aspect ratio was carried out. Immersion in a n-(2-aminoethyl) 3-aminopropyl-trimethoxysilane (AEAPTMS) self-assembled monolayer (SAM) was used to enhance the adhesion between the metal film and substrate. Contact angle variation and atomic force microscopy were used to verify the formation of a SAM layer. A PdCl2 solution was later used to activate the silanized substrates, exploiting the affinity of the -NH3 functional group of AEAPTMS to palladium. A nickel-phosphorus-boron electroless bath was employed to deposit the first barrier layer onto silicon. The NiPB growth rate was evaluated on flat silicon wafers, while the structure of the coating obtained was investigated via glow discharge optical emission spectroscopy. Cross-sectional scanning electron microscope observations were carried out on metallized TSVs to characterize the NiPB seed, the Cu seed layer deposited with a second electroless step, and the Cu superfilling obtained with a commercial solution. Complete filling of TSV was achieved.

  6. Tailoring femtosecond 1.5-μm Bessel beams for manufacturing high-aspect-ratio through-silicon vias

    Science.gov (United States)

    He, Fei; Yu, Junjie; Tan, Yuanxin; Chu, Wei; Zhou, Changhe; Cheng, Ya; Sugioka, Koji

    2017-01-01

    Three-dimensional integrated circuits (3D ICs) are an attractive replacement for conventional 2D ICs as high-performance, low-power-consumption, and small-footprint microelectronic devices. However, one of the major remaining challenges is the manufacture of high-aspect-ratio through-silicon vias (TSVs), which is a crucial technology for the assembly of 3D Si ICs. Here, we present the fabrication of high-quality TSVs using a femtosecond (fs) 1.5-μm Bessel beam. To eliminate the severe ablation caused by the sidelobes of a conventional Bessel beam, a fs Bessel beam is tailored using a specially designed binary phase plate. We demonstrate that the tailored fs Bessel beam can be used to fabricate a 2D array of approximately ∅10-μm TSVs on a 100-μm-thick Si substrate without any sidelobe damage, suggesting potential application in the 3D assembly of 3D Si ICs. PMID:28098250

  7. The effect of aspect ratio on vortex rings within the wake of impulsively-started flat plates

    Science.gov (United States)

    Fernando, John; Rival, David

    2014-11-01

    Vortex pinch-off has been the focus of many studies since it was first observed for vortices produced via piston-cylinder arrangements. Minimal work has been performed on other vortex generation methods. The current study investigates vortex rings behind impulsively-started circular, square, and elliptical flat plates. Preliminary force and PIV measurements show temporal/spatial similarities between vortex growth in the wake of the circular and square plates. Forces and vortex evolution are also shown to be strongly coupled; the presence of stable wake vortex rings results in a reduction of plate drag. For all three plates, pinch-off is initiated by the formation of a positive pressure gradient on the leeward side of the plate, which terminates mass transport to the vortex. It is hypothesized that an increase in aspect ratio (AR) from unity results in isolated vortex lines with non-uniform vorticity along the leading edges. Strong spanwise velocity gradients and stretching near the plate tips facilities vortex detachment. Results from experiments on rectangular plates with varying ARs are discussed and the effect of stretching and tilting in the tip region is investigated. The United States Air Force Office of Scientific Research.

  8. Ionic transport through sub-10 nm diameter hydrophobic high-aspect ratio nanopores: experiment, theory and simulation

    Science.gov (United States)

    Balme, Sébastien; Picaud, Fabien; Manghi, Manoel; Palmeri, John; Bechelany, Mikhael; Cabello-Aguilar, Simon; Abou-Chaaya, Adib; Miele, Philippe; Balanzat, Emmanuel; Janot, Jean Marc

    2015-01-01

    Fundamental understanding of ionic transport at the nanoscale is essential for developing biosensors based on nanopore technology and new generation high-performance nanofiltration membranes for separation and purification applications. We study here ionic transport through single putatively neutral hydrophobic nanopores with high aspect ratio (of length L = 6 μm with diameters ranging from 1 to 10 nm) and with a well controlled cylindrical geometry. We develop a detailed hybrid mesoscopic theoretical approach for the electrolyte conductivity inside nanopores, which considers explicitly ion advection by electro-osmotic flow and possible flow slip at the pore surface. By fitting the experimental conductance data we show that for nanopore diameters greater than 4 nm a constant weak surface charge density of about 10−2 C m−2 needs to be incorporated in the model to account for conductance plateaus of a few pico-siemens at low salt concentrations. For tighter nanopores, our analysis leads to a higher surface charge density, which can be attributed to a modification of ion solvation structure close to the pore surface, as observed in the molecular dynamics simulations we performed. PMID:26036687

  9. Direct investigation of the ablation rate evolution during laser drilling of high-aspect-ratio micro-holes

    Science.gov (United States)

    Mezzapesa, Francesco P.; Sibillano, Teresa; Columbo, Lorenzo L.; Di Niso, Francesca; Ancona, Antonio; Dabbicco, Maurizio; De Lucia, Francesco; Lugarà, Pietro M.; Scamarcio, Gaetano

    2012-03-01

    The recent development of ultrafast laser ablation technology in precision micromachining has dramatically increased the demand for reliable and real-time detection systems to characterize the material removal process. In particular, the laser percussion drilling of metals is lacking of non-invasive techniques able to monitor into the depth the spatial- and time-dependent evolution all through the ablation process. To understand the physical interaction between bulk material and high-energy light beam, accurate in-situ measurements of process parameters such as the penetration depth and the removal rate are crucial. We report on direct real time measurements of the ablation front displacement and the removal rate during ultrafast laser percussion drilling of metals by implementing a contactless sensing technique based on optical feedback interferometry. High aspect ratio micro-holes were drilled onto steel plates with different thermal properties (AISI 1095 and AISI 301) and Aluminum samples using 120-ps/110-kHz pulses delivered by a microchip laser fiber amplifier. Percussion drilling experiments have been performed by coaxially aligning the diode laser probe beam with the ablating laser. The displacement of the penetration front was instantaneously measured during the process with a resolution of 0.41 μm by analyzing the sawtooth-like induced modulation of the interferometric signal out of the detector system.

  10. Facile synthesis of ultrafine TiO{sub 2} nanowires with large aspect ratio and its photoactivity

    Energy Technology Data Exchange (ETDEWEB)

    Anjusree, G.S.; Asha, A.M.; Subramanian, K.R.V.; Sivekumar, N.; Nair, A. Sreekumaran; Nair, Shantikumar V.; Balakrishnan, Avinash [Amrita Center for Nanoscience, Kochi (India). Nano Solar Div.

    2013-06-15

    In the present study, ultrafine TiO{sub 2} nanowires ({proportional_to} 80nm in diameter) exhibiting large aspect ratio in the order of 10{sup 3} were synthesized hydrothermally. Phase and morphological analysis of the nanowires was carried out using X-ray diffractometry, X-ray photoelectron spectroscopy and scanning electron microscopy. High resolution transmission electron microscopy revealed the wire exhibiting growth in (101). A Tauc plot derived from UV analysis showed the average band gap values for nanowires to be less than for nanoparticles of similar diameter. It was observed that nanowires exhibited a high degree of photoactivity in an eosin-based dye system which was found to be 20-30% more than that of nanoparticles. This high photoactivity in nanowires was attributed to the longer charge retention which was observed during lifetime measurements, resulting in easy radical formation and dye degradation. Lifetime measurements on the nanowires showed the recombination time to be 54 ns as compared to 43 ns for nanoparticles. (orig.)

  11. Investigation of Vortical Flow Patterns in the Near Field of a Dynamic Low-Aspect-Ratio Cylinder

    Science.gov (United States)

    Gildersleeve, Samantha; Amitay, Michael

    2016-11-01

    The flowfield and associated flow structures of a low-aspect-ratio cylindrical pin were investigated experimentally in the near-field as the pin underwent wall-normal periodic oscillations. Under dynamic conditions, the pin is driven at the natural wake shedding frequency with an amplitude of 33% of its mean height. Additionally, a static pin was also tested at various mean heights of 0.5, 1.0, and 1.5 times the local boundary layer thickness to explore the effect of the mean height on the flowfield. Three-dimensional flowfields were reconstructed and analyzed from SPIV measurements where data were collected along streamwise planes for several spanwise locations under static and dynamic conditions. The study focuses on the incoming boundary layer as it interacts with the pin, as well as two main vortical formations: the arch-type vortex and the horseshoe vortex. Under dynamic conditions, the upstream boundary layer is thinner, relative to the baseline, and the downwash in the wake increases, resulting in a reduced wake deficit. These results indicate enhanced strength of the aforementioned vortical flow patterns under dynamic conditions. The flow structures in the near-field of the static/dynamic cylinder will be discussed in further detail. Supported by The Boeing Company.

  12. Nanoscale tomographic reconstruction of the subsurface mechanical properties of low-k high-aspect ratio patterns

    Science.gov (United States)

    Stan, Gheorghe; Mays, Ebony; Yoo, Hui Jae; King, Sean W.

    2016-12-01

    In this work, intermittent contact resonance atomic force microscopy (ICR-AFM) was performed on high-aspect ratio a-SiOC:H patterned fins (100 nm in height and width from 20 to 90 nm) to map the depth and width dependencies of the material stiffness. The spatial resolution and depth sensitivity of the measurements were assessed from tomographic cross-sections over various regions of interest within the 3D space of the measurements. Furthermore, the depth-dependence of the measured contact stiffness over the scanned area was used to determine the sub-surface variation of the elastic modulus at each point in the scan. This was achieved by iteratively adjusting the local elastic profile until the depth dependence of the resulted contact stiffness matched the depth dependence of the contact stiffness measured by ICR-AFM at that location. The results of this analysis were assembled into nanoscale sub-surface tomographic images of the elastic modulus of the investigated SiOC:H patterns. A new 3D structure-property representation emerged from these tomographic images with direct evidence for the alterations sustained by the structures during processing.

  13. Synthesis of well-dispersed silver nanorods of different aspect ratios and their antimicrobial properties against Gram positive and negative bacterial strains.

    Science.gov (United States)

    Ojha, Animesh K; Forster, Stefan; Kumar, Sumeet; Vats, Siddharth; Negi, Sangeeta; Fischer, Ingo

    2013-12-20

    In the present contribution, we describe the synthesis of highly dispersed silver nanorods (NRs) of different aspect ratios using a chemical route. The shape and size of the synthesized NRs were characterized by Transmission Electron Microscopy (TEM) and UV-visible spectroscopy. Longitudinal and transverse absorptions bands confirm the rod type structure. The experimentally recorded UV-visible spectra of NRs solutions were fitted by using an expression of the extinction coefficient for rod like nano structures under the dipole approximation. Simulated and experimentally observed UV-visible spectra were compared to determine the aspect ratios (R) of NRs. The average values of R for NR1, NR2 and NR3 solutions are estimated to be 3.0 ± 0.1, 1.8 ± 0.1 and 1.2 ± 0.1, respectively. These values are in good agreement with those obtained by TEM micrographs. The silver NRs of known aspect ratios are used to study antimicrobial activities against B. subtilis (gram positive) and E. coli (gram negative) microbes. We observed that the NRs of intermediate aspect ratio (R = 1.8) have greater antimicrobial effect against both, B. subtilis (gram positive) and E. coli (gram negative). The NRs of aspect ratio, R = 3.0 has better antimicrobial activities against gram positive than on the gram negative.

  14. Optimization of process parameters of the activated tungsten inert gas welding for aspect ratio of UNS S32205 duplex stainless steel welds

    Institute of Scientific and Technical Information of China (English)

    G. MAGUDEESWARAN; Sreehari R. NAIR; L. SUNDAR; N. HARIKANNAN

    2014-01-01

    The activated TIG (ATIG) welding process mainly focuses on increasing the depth of penetration and the reduction in the width of weld bead has not been paid much attention. The shape of a weld in terms of its width-to-depth ratio known as aspect ratio has a marked influence on its solidification cracking tendency. The major influencing ATIG welding parameters, such as electrode gap, travel speed, current and voltage, that aid in controlling the aspect ratio of DSS joints, must be optimized to obtain desirable aspect ratio for DSS joints. Hence in this study, the above parameters of ATIG welding for aspect ratio of ASTM/UNS S32205 DSS welds are optimized by using Taguchi orthogonal array (OA) experimental design and other statistical tools such as Analysis of Variance (ANOVA) and Pooled ANOVA techniques. The optimum process parameters are found to be 1 mm electrode gap, 130 mm/min travel speed, 140 A current and 12 V voltage. The aspect ratio and the ferrite content for the DSS joints fabricated using the optimized ATIG parameters are found to be well within the acceptable range and there is no macroscopically evident solidification cracking.

  15. Optimization of process parameters of the activated tungsten inert gas welding for aspect ratio of UNS S32205 duplex stainless steel welds

    Directory of Open Access Journals (Sweden)

    G. Magudeeswaran

    2014-09-01

    Full Text Available The activated TIG (ATIG welding process mainly focuses on increasing the depth of penetration and the reduction in the width of weld bead has not been paid much attention. The shape of a weld in terms of its width-to-depth ratio known as aspect ratio has a marked influence on its solidification cracking tendency. The major influencing ATIG welding parameters, such as electrode gap, travel speed, current and voltage, that aid in controlling the aspect ratio of DSS joints, must be optimized to obtain desirable aspect ratio for DSS joints. Hence in this study, the above parameters of ATIG welding for aspect ratio of ASTM/UNS S32205 DSS welds are optimized by using Taguchi orthogonal array (OA experimental design and other statistical tools such as Analysis of Variance (ANOVA and Pooled ANOVA techniques. The optimum process parameters are found to be 1 mm electrode gap, 130 mm/min travel speed, 140 A current and 12 V voltage. The aspect ratio and the ferrite content for the DSS joints fabricated using the optimized ATIG parameters are found to be well within the acceptable range and there is no macroscopically evident solidification cracking.

  16. Computational modeling of elastic properties of carbon nanotube/polymer composites with interphase regions. Part I: Micro-structural characterization and geometric modeling

    KAUST Repository

    Han, Fei

    2014-01-01

    A computational strategy to predict the elastic properties of carbon nanotube-reinforced polymer composites is proposed in this two-part paper. In Part I, the micro-structural characteristics of these nano-composites are discerned. These characteristics include networks/agglomerations of carbon nanotubes and thick polymer interphase regions between the nanotubes and the surrounding matrix. An algorithm is presented to construct three-dimensional geometric models with large amounts of randomly dispersed and aggregated nanotubes. The effects of the distribution of the nanotubes and the thickness of the interphase regions on the concentration of the interphase regions are demonstrated with numerical results. © 2013 Elsevier B.V. All rights reserved.

  17. Numerical investigation of the interaction between upstream cavity purge flow and main flow in low aspect ratio turbine cascade

    Institute of Scientific and Technical Information of China (English)

    Jia Wei; Liu Huoxing

    2013-01-01

    In modem gas turbines,rim seal located between the stator-disc and rotor-disc is used to prevent hot-gas ingestion into the inner stage-gap of high pressure turbine.However,the purge flow supplied to the cavity through the rim seal interacts with the main flow,producing additional aerodynamic loss due to the mixing process which plays a significant role in the formation,development and evolution of downstream secondary flow.In this paper,a set of cascade representative of low aspect ratio turbine is selected to numerically investigate the influence of upstream cavity purge flow on the hub secondary flow structure and aerodynamic loss.Cascade with/without upstream cavity and four different purge mass flow rates are all taken into account in this simulation.Then,a deep insight into the loss mechanism of interaction between purge flow and main flow is gained.The results show that the presence of cavity and purge flow has a significant impact on the main flow which not only changes the vortex structure in both the passage and upstream cavity,but also alters the cascade exit flow angle distribution along the spanwise.Moreover,aerodynamic loss in the cascade rises with the increase of purge flow rate while the sealing effect is also enhanced.Therefore,the effect of upstream cavity purge flow must be considered in the process of turbine aerodynamic design.What is more,it is necessary to minimize the purge flow rate in order to reduce aerodynamic loss on the premise of satisfying cooling requirements.

  18. On the onset of secondary flow and unsteady solutions through a loosely coiled rectangular duct for large aspect ratio

    Science.gov (United States)

    Shaha, Poly Rani; Rudro, Sajal Kanti; Poddar, Nayan Kumar; Mondal, Rabindra Nath

    2016-07-01

    The study of flows through coiled ducts and channels has attracted considerable attention not only because of their ample applications in Chemical, Mechanical, Civil, Nuclear and Biomechanical engineering but also because of their ample applications in other areas, such as blood flow in the veins and arteries of human and other animals. In this paper, a numerical study is presented for the fully developed two-dimensional flow of viscous incompressible fluid through a loosely coiled rectangular duct of large aspect ratio. Numerical calculations are carried out by using a spectral method, and covering a wide range of the Dean number, Dn, for two types of curvatures of the duct. The main concern of the present study is to find out effects of curvature as well as formation of secondary vortices on unsteady solutions whether the unsteady flow is steady-state, periodic, multi-periodic or chaotic, if Dn is increased. Time evolution calculations as well as their phase spaces are performed with a view to study the non-linear behavior of the unsteady solutions, and it is found that the steady-state flow turns into chaotic flow through various flow instabilities, if Dn is increased no matter what the curvature is. It is found that the unsteady flow is a steady-state solution for small Dn's and oscillates periodically or non-periodically (chaotic) between two- and twelve-vortex solutions, if Dn is increased. It is also found that the chaotic solution is weak for small Dn's but strong as Dn becomes large. Axial flow distribution is also investigated and shown in contour plots.

  19. Effects of wing shape, aspect ratio and deviation angle on aerodynamic performance of flapping wings in hover

    Science.gov (United States)

    Shahzad, Aamer; Tian, Fang-Bao; Young, John; Lai, Joseph C. S.

    2016-11-01

    This numerical study is focused on assessing the effect on the aerodynamic hovering performance of wing shapes defined by the radius of the first moment of the wing area ( r 1 ¯ ) and aspect ratio (AR). In addition, the effect of introducing a deviation angle in the kinematics is examined. The performance of r 1 ¯ = 0 . 43 , 0.53, and 0.63 wings with AR of 1.5, 2.96, 4.5, and 6.0 is investigated at Reynolds numbers (Re) = 12, 400, and 13 500. The performance trends of the wing shapes have been observed to be independent of Re for both 2-angle and 3-angle kinematics. This is because high suction pressures associated with the leading-edge vortex are predominantly spread in the distal (away from the wing root) and leeward regions (towards the trailing-edge) of high flapping velocities for all the cases. While the deviation angle is detrimental to the production of lift and power economy (PE, defined as the ratio of the mean lift coefficient to the mean aerodynamic power coefficient) at Re = 12 due to strong viscous effects, it improves PE at Re = 400 and 13 500. A high instantaneous angle of attack at the stroke reversal results in high lift peak for 3-angle kinematics but its effect at Re = 400 and 13 500 is attenuated by strong vortical structures on the underside of the wing. Maximum PE is achieved at AR = 2.96, as a low AR wing does not produce enough lift and high AR wings consume more aerodynamic power. Although the lift is maximized using high r 1 ¯ and AR wings, our results show that low r 1 ¯ and high AR wings are best for maximizing PE for a given lift in insects.

  20. pH-Dependent Toxicity of High Aspect Ratio ZnO Nanowires in Macrophages Due to Intracellular Dissolution

    KAUST Repository

    H. Müller, Karin

    2010-11-23

    High-aspect ratio ZnO nanowires have become one of the most promising products in the nanosciences within the past few years with a multitude of applications at the interface of optics and electronics. The interaction of zinc with cells and organisms is complex, with both deficiency and excess causing severe effects. The emerging significance of zinc for many cellular processes makes it imperative to investigate the biological safety of ZnO nanowires in order to guarantee their safe economic exploitation. In this study, ZnO nanowires were found to be toxic to human monocyte macrophages (HMMs) at similar concentrations as ZnCl2. Confocal microscopy on live cells confirmed a rise in intracellular Zn2+ concentrations prior to cell death. In vitro, ZnO nanowires dissolved very rapidly in a simulated body fluid of lysosomal pH, whereas they were comparatively stable at extracellular pH. Bright-field transmission electron microscopy (TEM) showed a rapid macrophage uptake of ZnO nanowire aggregates by phagocytosis. Nanowire dissolution occurred within membrane-bound compartments, triggered by the acidic pH of the lysosomes. ZnO nanowire dissolution was confirmed by scanning electron microscopy/energy-dispersive X-ray spectrometry. Deposition of electron-dense material throughout the ZnO nanowire structures observed by TEM could indicate adsorption of cellular components onto the wires or localized zinc-induced protein precipitation. Our study demonstrates that ZnO nanowire toxicity in HMMs is due to pH-triggered, intracellular release of ionic Zn2+ rather than the high-aspect nature of the wires. Cell death had features of necrosis as well as apoptosis, with mitochondria displaying severe structural changes. The implications of these findings for the application of ZnO nanowires are discussed. © 2010 American Chemical Society.

  1. Sharp high-aspect-ratio AFM tips fabricated by a combination of deep reactive ion etching and focused ion beam techniques.

    Science.gov (United States)

    Caballero, David; Villanueva, Guillermo; Plaza, Jose Antonio; Mills, Christopher A; Samitier, Josep; Errachid, Abdelhamid

    2010-01-01

    The shape and dimensions of an atomic force microscope tip are crucial factors to obtain high resolution images at the nanoscale. When measuring samples with narrow trenches, inclined sidewalls near 90 degrees or nanoscaled structures, standard silicon atomic force microscopy (AFM) tips do not provide satisfactory results. We have combined deep reactive ion etching (DRIE) and focused ion beam (FIB) lithography techniques in order to produce probes with sharp rocket-shaped silicon AFM tips for high resolution imaging. The cantilevers were shaped and the bulk micromachining was performed using the same DRIE equipment. To improve the tip aspect ratio we used FIB nanolithography technique. The tips were tested on narrow silicon trenches and over biological samples showing a better resolution when compared with standard AFM tips, which enables nanocharacterization and nanometrology of high-aspect-ratio structures and nanoscaled biological elements to be completed, and provides an alternative to commercial high aspect ratio AFM tips.

  2. FFT-impedance spectroscopy analysis of the growth of magnetic metal nanowires in ultra-high aspect ratio InP membranes

    Science.gov (United States)

    Gerngross, M.-D.; Carstensen, J.; Föll, H.; Adelung, R.

    2016-01-01

    This paper reports on the characterization of the electrochemical growth process of magnetic nanowires in ultra-high-aspect ratio InP membranes via in situ fast Fourier transform impedance spectroscopy in a typical frequency range from 75 Hz to 18.5 kHz. The measured impedance data from the Ni, Co, and FeCo can be very well fitted using the same electric equivalent circuit consisting of a series resistance in serial connection to an RC-element and a Maxwell element. The impedance data clearly indicate the similarities in the growth behavior of Ni, Co and FeCo nanowires in ultra-high aspect ratio InP membranes—the beneficial impact of boric acid on the metal deposition in ultra-high aspect ratio membranes and the diffusion limitation of boric acid, as well as differences such as passivation or side reactions.

  3. The effect of channel height and electrode aspect ratio on redox cycling at carbon interdigitated array nanoelectrodes confined in a microchannel.

    Science.gov (United States)

    Heo, Jeong-Il; Lim, Yeongjin; Shin, Heungjoo

    2013-11-07

    Redox cycling is a commonly used electrochemical sensing scheme for enhancing faradaic current signals. This effect can be improved by either optimizing electrode geometries or restricting electrochemical reactions within a limited volume. Here, we demonstrate a simple batch fabrication of 1 : 1 aspect ratio carbon interdigitated array nanoelectrodes integrated in a polydimethylsiloxane microchannel that enables current amplification by up to 1116 times. We also examine the factors that influence the effect of redox cycling, including the electrode aspect ratio and channel height, by using experiments and simulations.

  4. Low initial aspect-ratio direct-drive target designs for shock- or self-ignition in the context of the laser Megajoule

    OpenAIRE

    2014-01-01

    Analysis of low initial aspect ratio direct-drive target designs is carried out by varying the implosion velocity and the fuel mass. Starting from two different spherical targets with a given 300?g-DT mass, optimization of laser pulse and drive power allows to obtain a set of target seeds referenced by their peak implosion velocities and initial aspect ratio (A = 3 and A = 5). Self-ignition is achieved with higher implosion velocity for A = 5-design than for A = 3-design. Then, rescaling is d...

  5. Nanostructured conjugated polymers for photovoltaic devices

    Science.gov (United States)

    Xi, Dongjuan

    This dissertation focuses on making new systems of interdigitated bilayer structures for organic solar cells from two aspects: (i) fabricating vertically aligned semiconductor nanorod arrays by low-temperature solution process; (ii) applying the resulting nanorods arrays in solar cell devices with pre-formed or in-situ electropolymerized conjugated polymers. Two low-temperature solution methods are investigated to fabricate vertically aligned semiconductor nanorod arrays. The first method is using porous templates to prepare vertically aligned conjugated polymer nanorods arrays. In-situ anodized nanoporous alumina film is specifically designed to suspend on substrates to improve the wettability of organic solution to the alumina film, and to generate a big foot anchoring the polymer nanorods. With this specific design, vertically aligned polymer nanotube arrays with high density, 3x1010/cm2, is achieved and the nanotubes can stand vertically at the aspect ratio of 5. The second method is low-temperature direct growth of high quality semiconductor nanorod arrays without any templates by electrochemical deposition. Vertically aligned cadmium sulfide nanorod arrays are achieved by studying the growth mechanism of cadmium sulfide nanocrystal deposition and fine tuning the solution composition of the electrolyte. Chlorine doping, as a function of chlorine ion concentration in the electrolyte, modifies crystal lattice, and therefore the build-in stress, which dominates the morphology of the deposited nanocrystals as nanorods or thin films. Scanning electron microscopy, x-ray diffraction and transmission electron microscopy are applied to study the microstructures of the nanorods. Optical, electrical and field emission properties of the cadmium sulfide nanorod arrays are also studied in detail to pursue further applications of the nanorod arrays as nano-lasers and cold field emitters. Organic solar cells based on template-processed polythiophene nanotube arrays will be

  6. On the Effect of Aspect Ratio of Open Heated Channel Including an Active Obstacle upon the Turbulent Characteristics of a Thermal Plume: Experimental Analysis

    Directory of Open Access Journals (Sweden)

    Taoufik Naffouti

    2016-01-01

    Full Text Available This paper reports an experimental investigation of aspect ratio effect of open vertical channel on turbulent characteristics of a thermal plume. The physical configuration is constituted essentially by a prallelepipedic channel and an obstacle of a rectangular section. The thermal plume is generated by a rectangular obstacle heated uniformly at the upper surface. This active source is placed at the entry of a vertical channel open at the ends. The symmetrical heating of channel walls by joule effect and by thermal radiation emitted by the plume, causes the appearance of a thermosiphon flow which interacts with this one. To investigate the flow fluctuations, an anemometer at constant current (CCA is used. The results carried out with air (Pr = 0.71 are performed for Rayleigh number equal to 0.63 107 over a wide range of aspect ratio 1.25 ≤ A ≤ 30. Effects of this pertinent parameter are displayed upon thermal and dynamic turbulent fields. Using Taylor hypothesis, time and length scales of turbulent thermal field are studied. It is found that the turbulent characteristics of the flow are significantly influenced by the variation of aspect ratio. An optimum aspect ratio of channel characterized by a strong homogenization of turbulence of the flow is observed. The fine analysis of temperature fluctuations spectra shows the evolution of the vortices in energy cascade owing to the strong effect of thermosiphon flow which favours the vortex stretching.

  7. Forces and Moments on Flat Plates of Small Aspect Ratio with Application to PV Wind Loads and Small Wind Turbine Blades

    Directory of Open Access Journals (Sweden)

    Xavier Ortiz

    2015-03-01

    Full Text Available To improve knowledge of the wind loads on photovoltaic structures mounted on flat roofs at the high angles required in high latitudes, and to study starting flow on low aspect ratio wind turbine blades, a series of wind tunnel tests were undertaken. Thin flat plates of aspect ratios between 0.4 and 9.0 were mounted on a sensitive three-component instantaneous force and moment sensor. The Reynolds numbers varied from 6 × 104 to 2 × 105. Measurements were made for angles of attack between 0° and 90° both in the free stream and in wall proximity with increased turbulence and mean shear. The ratio of drag to lift closely follows the inverse tangent of the angle of incidence for virtually all measurements. This implies that the forces of interest are due largely to the instantaneous pressure distribution around the plate and are not significantly influenced by shear stresses. The instantaneous forces appear most complex for the smaller aspect ratios but the intensity of the normal force fluctuations is between 10% and 20% in the free-steam but can exceed 30% near the wall. As the wind tunnel floor is approached, the lift and drag reduce with increasing aspect ratio, and there is a reduction in the high frequency components of the forces. It is shown that the centre of pressure is closer to the centre of the plates than the quarter-chord position for nearly all cases.

  8. Studies on a novel mask technique with high selectivity and aspect-ratio patterns for HgCdTe trenches ICP etching

    Science.gov (United States)

    Ye, Z. H.; Hu, W. D.; Li, Y.; Huang, J.; Yin, W. T.; Lin, C.; Hu, X. N.; Ding, R. J.; Chen, X. S.; Lu, W.; He, L.

    2012-06-01

    A novel mask technique, combining high selectivity silicon dioxide patterns over high aspect-ratio photoresist (PR) patterns has been exploited to perform mesa etching for device delineation and electrical isolation of HgCdTe third-generation infrared focal plane arrays (IRFPAs). High-density silicon dioxide film covering high aspect-ratio PR patterns was deposited at the temperature of 80°C and silicon dioxide film patterns over high aspect-ratio PR patterns of HgCdTe etching samples was developed by standard photolithography and wet chemical etch. Scanning electron microscopy (SEM) shows that the surfaces of inductively coupled plasma (ICP) etched samples are quite clean and smooth. The etching selectivity between the novel mask and HgCdTe of the samples is increased to above 32: 1 while the side-wall impact of etching plasma is suppressed by the high aspect ratio patterns. These results show that the combined patterning of silicon dioxide film and thick PR film is a readily available and promising masking technique for HgCdTe mesa etching.

  9. Fabrication of high aspect ratio TiOsub>2sub> and Alsub>2sub>O>3sub> nanogratings by atomic layer deposition

    DEFF Research Database (Denmark)

    Shkondin, Evgeniy; Takayama, Osamu; Michael-Lindhard, Jonas

    2016-01-01

    The authors report on the fabrication of TiO2 and Al2O3 nanostructured gratings with an aspect ratio of up to 50. The gratings were made by a combination of atomic layer deposition (ALD) and dry etch techniques. The workflow included fabrication of a Si template using deep reactive ion etching...

  10. Breaking the limits of line width and aspect ratio for inkjet printed conductive lines by controlling post-deposition ink contraction

    NARCIS (Netherlands)

    Teunissen, P.; Abbel, R.J.; Michels, J.J.; Groen, P.

    2014-01-01

    Electrically conductive structures comprising both narrow line widths and high aspect ratios are indispensable components of many electronic devices. Producing them reliably on an industrial scale by inkjet printing of metal-based inks is a serious challenge. Firstly, due to spreading of the ink on

  11. Unravelling the correlation between the aspect ratio of nanotubular structures and their electrochemical performance to achieve high-rate and long-life lithium-ion batteries.

    Science.gov (United States)

    Tang, Yuxin; Zhang, Yanyan; Deng, Jiyang; Qi, Dianpeng; Leow, Wan Ru; Wei, Jiaqi; Yin, Shengyan; Dong, Zhili; Yazami, Rachid; Chen, Zhong; Chen, Xiaodong

    2014-12-01

    The fundamental understanding of the relationship between the nanostructure of an electrode and its electrochemical performance is crucial for achieving high-performance lithium-ion batteries (LIBs). In this work, the relationship between the nanotubular aspect ratio and electrochemical performance of LIBs is elucidated for the first time. The stirring hydrothermal method was used to control the aspect ratio of viscous titanate nanotubes, which were used to fabricate additive-free TiO2 -based electrode materials. We found that the battery performance at high charging/discharging rates is dramatically boosted when the aspect ratio is increased, due to the optimization of electronic/ionic transport properties within the electrode materials. The proof-of-concept LIBs comprising nanotubes with an aspect ratio of 265 can retain more than 86 % of their initial capacity over 6000 cycles at a high rate of 30 C. Such devices with supercapacitor-like rate performance and battery-like capacity herald a new paradigm for energy storage systems.

  12. Chemical and microstructural characterizations of plasma polymer films by time-of-flight secondary ion mass spectrometry and principal component analysis

    Science.gov (United States)

    Cossement, Damien; Renaux, Fabian; Thiry, Damien; Ligot, Sylvie; Francq, Rémy; Snyders, Rony

    2015-11-01

    It is accepted that the macroscopic properties of functional plasma polymer films (PPF) are defined by their functional density and their crosslinking degree (χ) which are quantities that most of the time behave in opposite trends. If the PPF chemistry is relatively easy to evaluate, it is much more challenging for χ. This paper reviews the recent work developed in our group on the application of principal component analysis (PCA) to time-of-flight secondary ion mass spectrometric (ToF-SIMS) positive spectra data in order to extract the relative cross-linking degree (χ) of PPF. NH2-, COOR- and SH-containing PPF synthesized in our group by plasma enhanced chemical vapor deposition (PECVD) varying the applied radiofrequency power (PRF), have been used as model surfaces. For the three plasma polymer families, the scores of the first computed principal component (PC1) highlighted significant differences in the chemical composition supported by X-Ray photoelectron spectroscopy (XPS) data. The most important fragments contributing to PC1 (loadings > 90%) were used to compute an average C/H ratio index for samples synthesized at low and high PRF. This ratio being an evaluation of χ, these data, accordingly to the literature, indicates an increase of χ with PRF excepted for the SH-PPF. These results have been cross-checked by the evaluation of functional properties of the plasma polymers namely a linear correlation with the stability of NH2-PPF in ethanol and a correlation with the mechanical properties of the COOR-PPF. For the SH-PPF family, the peculiar evolution of χ is supported by the understanding of the growth mechanism of the PPF from plasma diagnostic. The whole set of data clearly demonstrates the potential of the PCA method for extracting information on the microstructure of plasma polymers from ToF-SIMS measurements.

  13. Bragg grating photo-inscription in doped microstructured polymer optical fiber by 400 nm femtosecond laser pulses

    DEFF Research Database (Denmark)

    Hu, X.; Woyessa, Getinet; Kinet, D.;

    2016-01-01

    In this paper, we report the manufacturing of high-quality endlessly single-mode doped microstructured poly(methyl methacrylate) (PMMA) optical fibers. Bragg gratings are photo-inscribed in such fibers by means of 400 nm femtosecond laser pulses through a 1060-nm-period uniform phase mask...

  14. Numerical design of X-ray tabletop Talbot interferometer using polycapillary optics as two-dimensional gratings with high aspect ratio

    Science.gov (United States)

    Sun, Weiyuan; Liu, Zhiguo; Sun, Tianxi; Sun, Xuepeng; Li, Fangzuo; Jiang, Bowen; Ding, Xunliang

    2015-12-01

    The polycapillary optics was proposed to be used as two-dimensional X-ray gratings with high aspect ratios for high energy X-rays. The X-ray Talbot interferometer was designed numerically using the polycapillary X-ray gratings and a conventional X-ray source. The simulation showed that it was available to get a high-aspect-ratio pattern of the polycapillary X-ray gratings for higher energies than 60 keV. Moreover, this design of polycapillary gratings decreased the requirement for high power of the X-ray source. The polycapillary X-ray gratings had potential applications in X-ray imaging technology for medical fields, industrial nondestructive tests, public security, physical science, chemical analysis, life science, nanoscience biology and energy science.

  15. High-Yield Synthesis of Uniform Ag Nanowires with High Aspect Ratios by Introducing the Long-Chain PVP in an Improved Polyol Process

    Directory of Open Access Journals (Sweden)

    Jie-Jun Zhu

    2011-01-01

    Full Text Available Polyvinyl pyrrolidone (PVP with different molecular weights was used as capping agent to synthesize silver nanowires through a polyol process. The results indicated that the yields and aspect ratios of silver nanowires were controlled by the chain length of PVP and increased with increasing the molecular weight (MW of PVP. When the long-chain PVP-K90 (MW = 800,000 was used, the product was uniform in size and was dominated by nanowires with high aspect ratios. The growth mechanism of the nanowires was studied. It is proposed that the chemical adsorption of Ag+ on the PVP chains at the initial stage promotes the growth of Ag nanowires.

  16. Supersonic aerodynamic characteristics of a low-aspect-ratio missile model with wing and tail controls and with tails in line and interdigitated

    Science.gov (United States)

    Graves, E. B.

    1972-01-01

    A study has been made to determine the aerodynamic characteristics of a low-aspect ratio cruciform missile model with all-movable wings and tails. The configuration was tested at Mach numbers from 1.50 to 4.63 with the wings in the vertical and horizontal planes and with the wings in a 45 deg roll plane with tails in line and interdigitated.

  17. Effect of the glassy carbon structure on the aspect ratio of micropoints of matrix field-emission cathodes prepared by thermochemical etching

    Science.gov (United States)

    Pleshkova, L. S.; Shesterkin, V. I.

    2016-11-01

    The application of thermochemical etching technology makes it possible to reveal and investigate the structure of SU-2000 glassy carbon using electron microscopy. The glassy carbon structure at the microscopic and nanoscopic levels is inhomogeneous and consists of pockets with an irregular cross section separated by partitions. This structure sets the limits on the aspect ratio of geometrical sizes and micropoint packing density in the matrix prepared by thermochemical etching.

  18. Transonic steady- and unsteady-pressure measurements on a high-aspect-ratio supercritical-wing model with oscillating control surfaces

    Science.gov (United States)

    Sandford, M. C.; Ricketts, R. H.; Cazier, F. W., Jr.

    1980-01-01

    A supercritical wing with an aspect ratio of 10.76 and with two trailing-edge oscillating control surfaces is described. The semispan wing is instrumented with 252 static orifices and 164 in situ dynamic-pressure gages for studying the effects of control-surface position and motion on steady- and unsteady-pressures at transonic speeds. Results from initial tests conducted in the Langley Transonic Dynamics Tunnel at two Reynolds numbers are presented in tabular form.

  19. Low initial aspect-ratio direct-drive target designs for shock- or self-ignition in the context of the laser Megajoule

    Science.gov (United States)

    Brandon, V.; Canaud, B.; Temporal, M.; Ramis, R.

    2014-08-01

    Analysis of low initial aspect ratio direct-drive target designs is carried out by varying the implosion velocity and the fuel mass. Starting from two different spherical targets with a given 300 µg-DT mass, optimization of laser pulse and drive power allows to obtain a set of target seeds referenced by their peak implosion velocities and initial aspect ratio (A = 3 and A = 5). Self-ignition is achieved with higher implosion velocity for A = 5-design than for A = 3-design. Then, rescaling is done to extend the set of designs to a huge amount of mass, peak kinetic energies and peak areal densities. Self-ignition kinetic energy threshold Ek is characterized by a dependance of Ek ˜ vβ with β-values which depart from self-ignition models. Nevertheless, self-ignition energy is seen lower for smaller initial aspect ratio. An analysis of Two-Plasmons Decay threshold and Rayleigh-Taylor instability e-folding is carried out and it is shown that two-plasmon decay threshold is always overpassed for all designs. The hydrodynamic stability analysis is performed by embedded models to deal with linear and non-linear regime. It is found that the A = 5-designs are always at the limit of disruption of the shell.

  20. Engineered high aspect ratio vertical nanotubes as a model system for the investigation of catalytic methanol synthesis over Cu/ZnO.

    Science.gov (United States)

    Güder, Firat; Frei, Elias; Kücükbayrak, Umut M; Menzel, Andreas; Thomann, Ralf; Luptak, Roman; Hollaender, Bernd; Krossing, Ingo; Zacharias, Margit

    2014-02-12

    Catalytically synthesized methanol from H2 and CO2 using porous Cu/ZnO aggregates is a promising, carbon neutral, and renewable alternative to replace fossil fuel based transport fuels. However, the absence of surface-engineered model systems to understand and improve the industrial Cu/ZnO catalyst poses a big technological gap in efforts to increase industrial methanol conversion efficiency. In this work, we report a novel process for the fabrication of patterned, vertically aligned high aspect ratio 1D nanostructures on Si that can be used as an engineered model catalyst. The proposed strategy employs near-field phase shift lithography (NF-PSL), deep reactive ion etching (DRIE), and atomic layer deposition (ALD) to pattern, etch, and coat Si wafers to produce high aspect ratio 1D nanostructures. Using this method, we produced a model system consisting of high aspect ratio Cu-decorated ZnO nanotubes (NTs) to investigate the morphological effects of ZnO catalyst support in comparison to the planar Cu/ZnO catalyst in terms of the catalytic reactions. The engineered catalysts performed 70 times better in activating CO2 than the industrial catalyst. In light of the obtained results, several important points are highlighted, and recommendations are made to achieve higher catalytic performance.

  1. Electrically conducting, ultra-sharp, high aspect-ratio probes for AFM fabricated by electron-beam-induced deposition of platinum

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Jason, E-mail: jason.brown@physics.ox.ac.uk [Clarendon Laboratory, Department of Physics, University of Oxford, Oxford OX1 3PU (United Kingdom); Kocher, Paul; Ramanujan, Chandra S; Sharp, David N [Clarendon Laboratory, Department of Physics, University of Oxford, Oxford OX1 3PU (United Kingdom); Torimitsu, Keiichi [NTT Basic Research Laboratories, NTT Corporation, Atsugi, 243-0198 (Japan); Ryan, John F [Clarendon Laboratory, Department of Physics, University of Oxford, Oxford OX1 3PU (United Kingdom)

    2013-10-15

    We report on the fabrication of electrically conducting, ultra-sharp, high-aspect ratio probes for atomic force microscopy by electron-beam-induced deposition of platinum. Probes of 4.0 ±1.0 nm radius-of-curvature are routinely produced with high repeatability and near-100% yield. Contact-mode topographical imaging of the granular nature of a sputtered gold surface is used to assess the imaging performance of the probes, and the derived power spectral density plots are used to quantify the enhanced sensitivity as a function of spatial frequency. The ability of the probes to reproduce high aspect-ratio features is illustrated by imaging a close-packed array of nanospheres. The electrical resistance of the probes is measured to be of order 100 kΩ. - Highlights: • Electrically conducting, ultra-sharp, high aspect-ratio probes for AFM with radius-of-curvature 4.0±±1.0 nm. • AFM probe fabrication by electron-beam-induced deposition of platinum. • Enhanced spatial resolution demonstrated through AFM of sputtered gold grains. • AFM imaging of deep clefts and recesses on a close-packed array of nanospheres.

  2. Electrochemical growth of Co nanowires in ultra-high aspect ratio InP membranes: FFT-impedance spectroscopy of the growth process and magnetic properties

    Science.gov (United States)

    2014-01-01

    The electrochemical growth of Co nanowires in ultra-high aspect ratio InP membranes has been investigated by fast Fourier transform-impedance spectroscopy (FFT-IS) in the frequency range from 75 Hz to 18.5 kHz. The impedance data could be fitted very well using an electric circuit equivalent model with a series resistance connected in series to a simple resistor-capacitor (RC) element and a Maxwell element. Based on the impedance data, the Co deposition in ultra-high aspect ratio InP membranes can be divided into two different Co deposition processes. The corresponding share of each process on the overall Co deposition can be determined directly from the transfer resistances of the two processes. The impedance data clearly show the beneficial impact of boric acid on the Co deposition and also indicate a diffusion limitation of boric acid in ultra-high aspect ratio InP membranes. The grown Co nanowires are polycrystalline with a very small grain size. They show a narrow hysteresis loop with a preferential orientation of the easy magnetization direction along the long nanowire axis due to the arising shape anisotropy of the Co nanowires. PMID:25050088

  3. Electrochemical growth of Co nanowires in ultra-high aspect ratio InP membranes: FFT-impedance spectroscopy of the growth process and magnetic properties

    Science.gov (United States)

    Gerngross, Mark-Daniel; Carstensen, Jürgen; Föll, Helmut

    2014-06-01

    The electrochemical growth of Co nanowires in ultra-high aspect ratio InP membranes has been investigated by fast Fourier transform-impedance spectroscopy (FFT-IS) in the frequency range from 75 Hz to 18.5 kHz. The impedance data could be fitted very well using an electric circuit equivalent model with a series resistance connected in series to a simple resistor-capacitor ( RC) element and a Maxwell element. Based on the impedance data, the Co deposition in ultra-high aspect ratio InP membranes can be divided into two different Co deposition processes. The corresponding share of each process on the overall Co deposition can be determined directly from the transfer resistances of the two processes. The impedance data clearly show the beneficial impact of boric acid on the Co deposition and also indicate a diffusion limitation of boric acid in ultra-high aspect ratio InP membranes. The grown Co nanowires are polycrystalline with a very small grain size. They show a narrow hysteresis loop with a preferential orientation of the easy magnetization direction along the long nanowire axis due to the arising shape anisotropy of the Co nanowires.

  4. A hybrid method for predicting the microstructure of polymers with complex architecture: combination of single-chain simulation with density functional theory.

    Science.gov (United States)

    Cao, Dapeng; Jiang, Tao; Wu, Jianzhong

    2006-04-28

    A hybrid method is proposed to investigate the microstructure of various polymeric fluids confined between two parallel surfaces. The hybrid method combines a single-chain Monte Carlo (MC) simulation for the ideal-gas part of the Helmholtz energy and a density functional theory (DFT) for the excess part that arises from nonbonded intersegment interactions. The latter consists of a modified fundamental measure theory for excluded-volume effect, the first-order thermodynamics perturbation theory for chain connectivity, and a mean-field approximation for the van der Waals attraction. In comparison with a conventional DFT, the hybrid method avoids calculation of the time-consuming recursive functions and is directly applicable to polymers with arbitrary molecular architecture. Its numerical performance has been validated by extensive comparisons with MC data for the density distributions of totally flexible, semiflexible, or rigid polymers and those with starlike architecture. Special attention is also given to the formation of a nematic monolayer by rigid molecules laying perpendicular to a planar surface. The hybrid method predicts the surface pressure versus surface coverage in good agreement with experiment.

  5. Experimental observations and dissipative particle dynamic simulations on microstructures of pH-sensitive polymer containing amorphous solid dispersions.

    Science.gov (United States)

    Sun, Mengchi; Li, Bingyu; Li, Yanchun; Liu, Yangdan; Liu, Qi; Jiang, Hailun; He, Zhonggui; Zhao, Yongshan; Sun, Jin

    2017-01-30

    Amorphous solid dispersion (ASD) technique is an effective strategy to increase the dissolution rate of poorly soluble drugs. However, it is inherently unstable, and the molecular basis for achieving kinetic stability is not well understood. In this study, lacidipine-Eudragit_E_100 solid dispersions with 20% drug loading were prepared using the solvent evaporation. Dissolution tested showed that ASD had a significantly high rate, which was dependent on the pH of the medium. Based on time-dependent measurement of supersaturation and particle size, inhibition of crystal growth by Eudragit_E_100 differed at pH 1.2 and 6.8 to a great extent. Dissipative particle dynamic (DPD) simulation revealed that at pH 1.2, the swollen microstructures of the particles were associated with rapid drug release. At pH 6.8, a compacted microstructure of small amorphous particle-aggregated large particles was associated with slow dissolution. The DPD simulation provides insight into the structural basis for experimental observations, and thus is a useful tool to investigate the microstructures of ASD.

  6. Three-dimensional nanometrology of microstructures by replica molding and large-range atomic force microscopy

    DEFF Research Database (Denmark)

    Stöhr, Frederik; Michael-Lindhard, Jonas; Simons, Hugh

    2015-01-01

    We have used replica molding and large-range atomic force microscopy to characterize the threedimensional shape of high aspect ratio microstructures. Casting inverted replicas of microstructures using polydimethylsiloxane (PDMS) circumvents the inability of AFM probes to measure deep and narrow c...

  7. On the influence of magnetic field processing on the texture, phase assemblage and properties of low aspect ratio Bi2 Sr2 CaCu2 Ox /AgMg wire

    Directory of Open Access Journals (Sweden)

    Xiaotao Liu and Justin Schwartz

    2009-01-01

    Full Text Available Bi2 Sr2 CaCu2 Ox /AgMg conductors are potentially important for many applications up to 20 K, including magnets for cryogen-free magnetic resonance imaging and high field nuclear magnetic resonance research. One promising approach to increased critical current density is partial-melt processing in the presence of a magnetic field which has been shown to enhance c-axis texturing of wide, thin tape conductors. Here, we report on low aspect ratio rectangular conductors processed in an 8 T magnetic field. The magnetic field is applied during different stages of the heat treatment process. The conductors are electrically characterized using four-point critical current measurements as a function of magnetic field and magnetic field orientation relative to the conductor. The superconductive transition and magnetization hysteresis are measured using a SQUID magnetometer. The microstructures are characterized using scanning electron microscopy and energy dispersive spectroscopy and analyzed using digital image processing. It is found that the presence of a magnetic field during split melt processing enhances the electrical transport and magnetic behavior, but that the anisotropy is not consistently affected. The magnetic field also affects development of interfilamentary Bi2212 bridges, and that this depends on the initial shape of the Bi2212 filament. At least two behaviors are identified; one impacts the oxide phase assemblage and the other impacts textured growth.

  8. Complex microstructures of ABC triblock copolymer thin films directed by polymer brushes based on self-consistent field theory.

    Science.gov (United States)

    Jiang, Zhibin; Xu, Chang; Qiu, Yu Dong; Wang, Xiaoliang; Zhou, Dongshan; Xue, Gi

    2014-01-01

    The morphology and the phase diagram of ABC triblock copolymer thin film directed by polymer brushes are investigated by the self-consistent field theory in three dimensions. The polymer brushes coated on the substrate can be used as a good soft template to tailor the morphology of the block copolymer thin films compared with those on the hard substrates. The polymer brush is identical with the middle block B. By continuously changing the composition of the block copolymer, the phase diagrams are constructed for three cases with the fixed film thickness and the brush density: identical interaction parameters, frustrated and non-frustrated cases. Some ordered complex morphologies are observed: parallel lamellar phase with hexagonally packed pores at surfaces (LAM3 (ll) -HFs), perpendicular lamellar phase with cylinders at the interface (LAM(⊥)-CI), and perpendicular hexagonally packed cylinders phase with rings at the interface (C2 (⊥)-RI). A desired direction (perpendicular or parallel to the coated surfaces) of lamellar phases or cylindrical phases can be obtained by varying the composition and the interactions between different blocks. The phase diagram of ABC triblock copolymer thin film wetted between the polymer brush-coated surfaces is very useful in designing the directed pattern of ABC triblock copolymer thin film.

  9. Effect of microstructure of nano- and micro-particle filled polymer composites on their tribo-mechanical performance

    Energy Technology Data Exchange (ETDEWEB)

    Devaprakasam, D; Moebus, G; Inkson, B J [Department of Engineering Materials, University of Sheffield (United Kingdom); Hatton, P V [Centre for Biomaterials and Tisssue Engineering and Department of Clinical Dentistry, University of Sheffield (United Kingdom)], E-mail: D.Deivasagayam@sheffield.ac.uk

    2008-08-15

    In this work we have investigated the influence of nanoscale and microscale structure on the tribo-mechanical performance and failure mechanisms of two biocompatible dental polymer composites, with different reinforcing particulates, using advanced microscopy techniques. Nano- and micro structural analysis reveals the shape, size and distribution of the particles in the composites. In the microparticle filled polymer composite (microcomposite), the particles are of irregular shape with sharp edges with non-uniform distribution in the matrix. However, in the nanoparticle filled composites (nanocomposite), filler particles are spherical in shape with uniform distribution in the matrix. From nanoindentation measurements, hardness and reduced modulus of the microcomposite were found to be heterogeneous. However, the hardness and reduced modulus of the nanocomposite were found to be homogeneous. The nanocomposite shows better tribo-mechanical performance compared to that of the microcomposite.

  10. Effect of microstructure of nano- and micro-particle filled polymer composites on their tribo-mechanical performance

    Science.gov (United States)

    Devaprakasam, D.; Hatton, P. V.; Möbus, G.; Inkson, B. J.

    2008-08-01

    In this work we have investigated the influence of nanoscale and microscale structure on the tribo-mechanical performance and failure mechanisms of two biocompatible dental polymer composites, with different reinforcing particulates, using advanced microscopy techniques. Nano- and micro structural analysis reveals the shape, size and distribution of the particles in the composites. In the microparticle filled polymer composite (microcomposite), the particles are of irregular shape with sharp edges with non-uniform distribution in the matrix. However, in the nanoparticle filled composites (nanocomposite), filler particles are spherical in shape with uniform distribution in the matrix. From nanoindentation measurements, hardness and reduced modulus of the microcomposite were found to be heterogeneous. However, the hardness and reduced modulus of the nanocomposite were found to be homogeneous. The nanocomposite shows better tribo-mechanical performance compared to that of the microcomposite.

  11. Effects of building aspect ratio,diurnal heating scenario,and wind speed on reactive pollutant dispersion in urban street canyons

    Institute of Scientific and Technical Information of China (English)

    Nelson Y.O.Tong; Dennis Y.C.Leung

    2012-01-01

    A photochemistry coupled computational fluid dynamics (CFD) based numerical model has been developed to model the reactive pollutant dispersion within urban street canyons,particularly integrating the interrelationship among diurnal heating scenario (solar radiation affections in nighttime,daytime,and sun-rise/set),wind speed,building aspect ratio (building-height-to-street-width),and dispersion of reactive gases,specifically nitric oxide (NO),nitrogen dioxide (NO2) and ozone (O3) such that a higher standard of air quality in metropolitan cities can be achieved.Validation has been done with both experimental and numerical results on flow and temperature fields in a street canyon with bottom heating,which justifies the accuracy of the current model.The model was applied to idealized street canyons of different aspect ratios from 0.5 to 8 with two different ambient wind speeds under different diurnal heating scenarios to estimate the influences of different aforementioned parameters on the chemical evolution of NO,NO2 and O3.Detailed analyses of vertical profiles of pollutant concentrations showed that different diurnal heating scenarios could substantially affect the reactive gases exchange between the street canyon and air aloft,followed by respective dispersion and reaction.Higher building aspect ratio and stronger ambient wind speed were revealed to be,in general,responsible for enhanced entrainment of O3 concentrations into the street canyons along windward walls under all diurnal heating scenarios.Comparatively,particular attention can be paid on the windward wall heating and nighttime uniform surface heating scenarios.

  12. Balancing the daylighting and energy performance of solar screens in residential desert buildings: Examination of screen axial rotation and opening aspect ratio

    KAUST Repository

    Sabry, Hanan

    2014-05-01

    Solar screens are typically used to control solar access into building spaces. They proved their usefulness in improving the daylighting and energy performance of buildings in the hot arid desert environments which are endowed with abundance of clear skies.The daylighting and energy performance of solar screens is affected by many parameters. These include screen perforation, depth, reflectivity and color, aspect ratio of openings, shape, tilt angle and rotation. Changing some of these parameters can improve the daylighting performance drastically. However, this can result in increased energy consumption. A balanced solution must be sought, where acceptable daylighting performance would be achieved at minimum energy consumption.This paper aims at defining solar screen designs that achieve visual comfort and at the same time minimum energy consumption in residential desert settings. The study focused on the effect of changing the solar screen axial rotation and the aspect ratio of its openings under the desert clear-sky. The individual and combined effects of changing these parameters were studied.Results of this study demonstrated that a non-rotated solar screen that has wide horizontal openings (aspect ratio of 18:1) proved to be successful in the north and south orientations. Its performance in the east/west orientations was also superior. In contrast, the screen that was rotated along its vertical axis while having small size openings (aspect ratio of 1:1) proved to be more successful in the east/west orientations. Its performance in the north orientation was also good. These solutions enhanced daylighting performance, while maintaining the energy consumption at a minimum.Moreover, it was observed that combining two screen parameters which proved useful in previous studies on daylighting or thermal performance does not add up to better solutions. The combined solutions that were tested in this study did not prove successful in satisfying daylighting and thermal

  13. High aspect ratio, nanostructured, platinum based electrodes for proton exchange membrane fuel cells: Design, development and ionic conduction of the proposed structures

    Science.gov (United States)

    Paschos, Odysseas

    High aspect ratio nanostructures can provide substantial benefits when used as fuel cell electrodes since they can alleviate problems associated with conventional carbon supports. In this work the potential of incorporating high aspect ratio nanostructures as electrodes for fuel cells was studied. Moreover, a model was created that demonstrated the potential for the nanostructures to yield high performance. The creation of Pt nanorods using anodic aluminum oxide templates was investigated and experiments showed complete utilization of the electrodes surface area. However, the Pt nanorod structure was found to not be effective in terms of Pt mass utilization, since only the outer surface of the rod is utilized for catalytic activity. An alternate method was developed to coat (with Pt) high aspect ratio structures made from a cost-effective support material. Thus far, methods used to conformally coat Pt either cannot be used directly on several materials or tend not to be cost-effective. A non-vacuum method based on an Aerosol Assisted Deposition (AAD) technique was developed and optimized. Initial experiments showed feasibility of the technique to coat a large variety of substrates. Dimensions of the particles were controlled by the deposition parameters and ranged from 4 nm up to several hundreds of nm in diameter. Experiments where Pt nanoparticles were deposited on gas diffusion layer substrates, showed higher electrochemical performance compared to commercial catalyst. The need for electrolyte coating on the high aspect ratio structures was also investigated. Initial experiments were performed by splitting an MEA in half and using an intermediate Pt film. These experiments showed that ionic conduction on Pt surface is possible. Moreover these studies indicated that ionic conduction on Pt could result from hydrophilic groups that can exist on its surface. Since these groups can either be physisorbed due to presence of water or chemisorbed on the oxidized Pt

  14. Statistical convergence and the effect of large-scale motions on turbulent Rayleigh-Bénard convection in a cylindrical domain with 6.3 aspect ratio

    Science.gov (United States)

    Sakievich, Philip; Peet, Yulia; Adrian, Ronald

    2016-11-01

    At high Rayleigh numbers in moderate aspect-ratio cylindrical domains turbulent Rayleigh-Bénard convection (RBC) exhibits coherent large-scale motions with patterns like some of those found in laminar flow. In this work we show how the patterns of the largest scales in turbulent RBC affect the bias and convergence of the flow statistics at aspect-ratio 6.3 (diameter/ height). Large scale motions influence two of the finite-time statistical mean's inherent properties: 1) the orientation of the patterns changes so slowly that it may appear almost fixed during a finite averaging time interval, thereby imbedding a preferred azimuthal direction in the sampled data; 2) they also have at least two states associated with the occurrence of up and down motions near the center of the convection cell. We will present a novel technique for triggering additional states of RBC in DNS simulations that are targeted for improving the statistical convergence of the flow. This technique gently perturbs the flow so that the new variations of the large scale patterns can be sampled. Funding through U. S. National Science Foundation Grants CBET-1335731, CMMI-1250124 and XSEDE research allocation TG-CTS150039.

  15. Protein-enabled layer-by-layer syntheses of aligned, porous-wall, high-aspect-ratio TiO{sub 2} nanotube arrays

    Energy Technology Data Exchange (ETDEWEB)

    Berrigan, John D.; Cai, Ye; Sandhage, Kenneth H. [School of Materials Science and Engineering, Air Force Center of Excellence on Bio-Nano-Enabled Inorganic/Organic Nanocomposites and Improved Cognition (BIONIC), Georgia Institute of Technology, 771 Ferst Drive, Atlanta, Georgia 30332-0400 (United States); Kang, Tae-Sik; Deneault, James R.; Durstock, Michael F. [Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright-Patterson Air Force Base, Ohio, 45433-7702 (United States)

    2011-05-10

    An aqueous, protein-enabled (biomimetic), layer-by-layer titania deposition process is developed, for the first time, to convert aligned-nanochannel templates into high-aspect-ratio, aligned nanotube arrays with thin (34 nm) walls composed of co-continuous networks of pores and titania nanocrystals (15 nm ave. size). Alumina templates with aligned open nanochannels are exposed in an alternating fashion to aqueous protamine-bearing and titania precursor-bearing (Ti(IV) bis-ammonium-lactato-dihydroxide, TiBALDH) solutions. The ability of protamine to bind to alumina and titania, and to induce the formation of a Ti-O-bearing coating upon exposure to the TiBALDH precursor, enables the layer-by-layer deposition of a conformal protamine/Ti-O-bearing coating on the nanochannel surfaces within the porous alumina template. Subsequent protamine pyrolysis yields coatings composed of co-continuous networks of pores and titania nanoparticles. Selective dissolution of the underlying alumina template through the porous coating then yields freestanding, aligned, porous-wall titania nanotube arrays. The interconnected pores within the nanotube walls allow enhanced loading of functional molecules (such as a Ru-based N719 dye), whereas the interconnected titania nanoparticles enable the high-aspect-ratio, aligned nanotube arrays to be used as electrodes (as demonstrated for dye-sensitized solar cells with power conversion efficiencies of 5.2 {+-} 0.4%). (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  16. High Aspect Ratio Silver Conductive Tracks in Inkjet Printing%喷墨打印制备高“高宽比”银导线工艺

    Institute of Scientific and Technical Information of China (English)

    张磊; 朱云龙; 程晓鼎; 王驰远

    2016-01-01

    传统丝网印刷技术因其接触式印刷工艺难以提高金属导线的精度和“高宽比”,为实现高“高宽比”的金属导线制造,以低黏度纳米银墨水为喷墨材料,采用自主研发的喷墨打印设备在多种基材表面打印银导线.通过喷墨打印实验方法研究了喷墨打印过程的“咖啡环”及“马鞍型”缺陷产生原理及影响因素,通过在Teslin、Kapton、多晶硅硅片及高光相纸4种基材上多层打印及改变基板温度制备银导线,研究了银导线“高宽比”及三维形貌的变化关系.实验结果表明:基板温度在60℃时,打印的银导线呈“拱型”;基板温度在80℃时,打印的银导线“高宽比”最佳且受基材影响减弱.打印层数为20层时,导线边缘出现波浪纹;打印层数为80层时,波浪纹消失,导线形貌均匀.烧结温度为200℃时,银导线导电能力得到极大提升,Teslin基材形成的银导线电阻率最低至2.13μΩ·cm.%It' s difficult to improve the accuracy and aspect ratio of conductive tracks for the traditional screen printing technology. In order to achieve high aspect ratio of conductive tracks, an ink jet printing method for fabrication of high aspect ratio silver tracks was described. The mechanisms and influence factors of coffee-ring and M-type effect were revealed by experiments. The experiments of multi-pass inkjet printing on Teslin, Kapton, Polycrystalline silicon, glossy photo paper and altering substrates temperature procedure were carried out. The results show that when the substrate temperature is 60℃, the arch-type silver tracks are formed. When the substrate temperature is 80 ℃, the optimized aspect ratio of silver tracks is formed and the influence by different substrates is weak. As inkjet printing runs 20 pass, wave form on the edge of silver tracks comes out. When inkjet printing runs 80 pass, wave form fades away and high aspect ratio silver tracks are fabricated instead. When

  17. Transport properties and microstructure of La0.7Sr0.3MnO3 nanocrystalline thin films grown by polymer-assisted chemical solution deposition

    Institute of Scientific and Technical Information of China (English)

    Min Zhang; Li Lv; Zhantao Wei; Xinsheng Yang; Xin Zhang

    2014-01-01

    Perovskite-based materials can be widely used in the aerospace and transportation field. Perovskite man-ganese oxides La0.7Sr0.3MnO3 (LSMO) thin films were grown on LaAlO3 (100) and Si (100) single crystal sub-strates by the polymer-assisted chemical solution deposi-tion (PACSD) method. Electronic transport behavior, microstructure, and magnetoresistance (MR) of LSMO thin films on different substrates were investigated. The resis-tance of LSMO films fabricated on LaAlO3 substrates is smaller than that on the Si substrates. The magnetic field reduces resistance of LSMO films both on Si and LAO in the wide temperature region, when the insulator-metal transition temperature shifts to higher temperature. The low-field magnetoresistance of LSMO films on Si in low temperature range at 1 T is larger than that of LSMO films on LAO. However, the MR of LSMO film on LAO films at room-temperature is about 5.17%. The thin films are smooth and dense with uniform nanocrystal size grain. These results demonstrate that PACSD is an effective technique for producing high quality LSMO films, which is significant to improve the magnetic properties and the application of automotive sensor.

  18. 3-D Numerical Simulation and Analysis of Complex Fiber Geometry RaFC Materials with High Volume Fraction and High Aspect Ratio based on ABAQUS PYTHON

    Science.gov (United States)

    Jin, BoCheng

    2011-12-01

    Organic and inorganic fiber reinforced composites with innumerable fiber orientation distributions and fiber geometries are abundantly available in several natural and synthetic structures. Inorganic glass fiber composites have been introduced to numerous applications due to their economical fabrication and tailored structural properties. Numerical characterization of such composite material systems is necessitated due to their intrinsic statistical nature, which renders extensive experimentation prohibitively time consuming and costly. To predict various mechanical behavior and characterizations of Uni-Directional Fiber Composites (UDFC) and Random Fiber Composites (RaFC), we numerically developed Representative Volume Elements (RVE) with high accuracy and efficiency and with complex fiber geometric representations encountered in uni-directional and random fiber networks. In this thesis, the numerical simulations of unidirectional RaFC fiber strand RVE models (VF>70%) are first presented by programming in ABAQUS PYTHON. Secondly, when the cross sectional aspect ratios (AR) of the second phase fiber inclusions are not necessarily one, various types of RVE models with different cross sectional shape fibers are simulated and discussed. A modified random sequential absorption algorithm is applied to enhance the volume fraction number (VF) of the RVE, which the mechanical properties represents the composite material. Thirdly, based on a Spatial Segment Shortest Distance (SSSD) algorithm, a 3-Dimentional RaFC material RVE model is simulated in ABAQUS PYTHON with randomly oriented and distributed straight fibers of high fiber aspect ratio (AR=100:1) and volume fraction (VF=31.8%). Fourthly, the piecewise multi-segments fiber geometry is obtained in MATLAB environment by a modified SSSD algorithm. Finally, numerical methods including the polynomial curve fitting and piecewise quadratic and cubic B-spline interpolation are applied to optimize the RaFC fiber geometries

  19. Turbulent natural convection in a differentially heated cavity of aspect ratio 5 filled with non-participating and participating grey media

    Energy Technology Data Exchange (ETDEWEB)

    Capdevila, R; Trias, F X; Perez-Segarra, C D [Centre Tecnologic de Transferencia de Calor (CTTC), Lab.Termotecnia i Energetica, Universitat Politecnica de Catalunya (UPC), C/Colom, 11, E08222 Terrassa, Barcelona (Spain); Lehmkuhl, O; Colomer, G, E-mail: cttc@cttc.upc.edu, E-mail: termofluids@termofluids.com [Termofluids, S. L., Magi Colet 8, E08204 Sabadell, Barcelona (Spain)

    2011-12-22

    In the present work, turbulent natural convection in a tall differentially heated cavity of aspect ratio 5:1, filled with air (Pr = 0.7) under a Rayleigh number based on the height of 4.5 {center_dot} 10{sup 10}, is studied numerically. Two different situations have been analysed. In the first one, the cavity is filled with a transparent medium. In the second one, the cavity contains a grey participating gas. The turbulent flow is described by means of Large Eddy Simulation (LES) using symmetry-preserving discretizations. Simulations are compared with experimental data available in the literature and with Direct Numerical Simulations (DNS). Surface and gas radiation have been simulated using the Discrete Ordinates Method (DOM). The influence of radiation on fluid flow behaviour has also been analysed.

  20. Aspect ratio plays a role in the hazard potential of CeO2 nanoparticles in mouse lung and zebrafish gastrointestinal tract.

    Science.gov (United States)

    Lin, Sijie; Wang, Xiang; Ji, Zhaoxia; Chang, Chong Hyun; Dong, Yuan; Meng, Huan; Liao, Yu-Pei; Wang, Meiying; Song, Tze-Bin; Kohan, Sirus; Xia, Tian; Zink, Jeffrey I; Lin, Shuo; Nel, André E

    2014-05-27

    We have previously demonstrated that there is a relationship between the aspect ratio (AR) of CeO2 nanoparticles and in vitro hazard potential. CeO2 nanorods with AR ≥ 22 induced lysosomal damage and progressive effects on IL-1β production and cytotoxicity in the human myeloid cell line, THP-1. In order to determine whether this toxicological paradigm for long aspect ratio (LAR) CeO2 is also relevant in vivo, we performed comparative studies in the mouse lung and gastrointestinal tract (GIT) of zebrafish larvae. Although oropharyngeal aspiration could induce acute lung inflammation for CeO2 nanospheres and nanorods, only the nanorods with the highest AR (C5) induced significant IL-1β and TGF-β1 production in the bronchoalveolar lavage fluid at 21 days but did not induce pulmonary fibrosis. However, after a longer duration (44 days) exposure to 4 mg/kg of the C5 nanorods, more collagen production was seen with CeO2 nanorods vs nanospheres after correcting for Ce lung burden. Using an oral-exposure model in zebrafish larvae, we demonstrated that C5 nanorods also induced significant growth inhibition, a decrease in body weight, and delayed vertebral calcification. In contrast, CeO2 nanospheres and shorter nanorods had no effect. Histological and transmission electron microscopy analyses showed that the key injury mechanism of C5 was in the epithelial lining of the GIT, which demonstrated blunted microvilli and compromised digestive function. All considered, these data demonstrate that, similar to cellular studies, LAR CeO2 nanorods exhibit more toxicity in the lung and GIT, which could be relevant to inhalation and environmental hazard potential.

  1. Ultra-high aspect ratio Si nanowires fabricated with plasma etching: plasma processing, mechanical stability analysis against adhesion and capillary forces and oleophobicity

    Science.gov (United States)

    Zeniou, A.; Ellinas, K.; Olziersky, A.; Gogolides, E.

    2014-01-01

    Room-temperature deep Si etching using time-multiplexed deep reactive ion etching (DRIE) processes is investigated to fabricate ultra-high aspect ratio Si nanowires (SiNWs) perpendicular to the silicon substrate. Nanopatterning is achieved using either top-down techniques (e.g. electron beam lithography) or colloidal polystyrene (PS) sphere self-assembly. The latter is a faster and more economical method if imperfections in diameter and position can be tolerated. We demonstrate wire radii from below 100 nm to several micrometers, and aspect ratios (ARs) above 100:1 with etching rates above 1 μm min-1 using classical mass flow controllers with pulsing rise times of seconds. The mechanical stability of these nanowires is studied theoretically and experimentally against adhesion and capillary forces. It is shown that above ARs of the order of 50:1 for spacing 1 μm, SiNWs tend to bend due to adhesion forces between them. Such large adhesion forces are due to the high surface energy of silicon. Wetting the SiNWs with water and drying also gives rise to capillary forces. We find that capillary forces may be less important for SiNW collapse/bending compared to adhesion forces of dry SiNWs, contrary to what is observed for polymeric nanowires/nanopillars which have a much lower surface energy compared to silicon. Finally we show that SiNW arrays have oleophobic and superoleophobic properties, i.e. they exhibit excellent anti-wetting properties for a wide range of liquids and oils due to the re-entrant profile produced by the DRIE process and the well-designed spacing.

  2. Jamming of Semiflexible Polymers

    Science.gov (United States)

    Hoy, Robert S.

    2017-02-01

    We study jamming in model freely rotating polymers as a function of chain length N and bond angle θ0. The volume fraction at jamming ϕJ(θ0) is minimal for rigid-rodlike chains (θ0=0 ), and increases monotonically with increasing θ0≤π /2 . In contrast to flexible polymers, marginally jammed states of freely rotating polymers are highly hypostatic, even when bond and angle constraints are accounted for. Large-aspect-ratio (small θ0) chains behave comparably to stiff fibers: resistance to large-scale bending plays a major role in their jamming phenomenology. Low-aspect-ratio (large θ0) chains behave more like flexible polymers, but still jam at much lower densities due to the presence of frozen-in three-body correlations corresponding to the fixed bond angles. Long-chain systems jam at lower ϕ and are more hypostatic at jamming than short-chain systems. Implications of these findings for polymer solidification are discussed.

  3. Complex shaped ZnO nano- and microstructure based polymer composites: mechanically stable and environmentally friendly coatings for potential antifouling applications.

    Science.gov (United States)

    Hölken, Iris; Hoppe, Mathias; Mishra, Yogendra K; Gorb, Stanislav N; Adelung, Rainer; Baum, Martina J

    2016-03-14

    Since the prohibition of tributyltin (TBT)-based antifouling paints in 2008, the development of environmentally compatible and commercially realizable alternatives is a crucial issue. Cost effective fabrication of antifouling paints with desired physical and biocompatible features is simultaneously required and recent developments in the direction of inorganic nanomaterials could play a major role. In the present work, a solvent free polymer/particle-composite coating based on two component polythiourethane (PTU) and tetrapodal shaped ZnO (t-ZnO) nano- and microstructures has been synthesized and studied with respect to mechanical, chemical and biocompatibility properties. Furthermore, antifouling tests have been carried out in artificial seawater tanks. Four different PTU/t-ZnO composites with various t-ZnO filling fractions (0 wt%, 1 wt%, 5 wt%, 10 wt%) were prepared and the corresponding tensile, hardness, and pull-off test results revealed that the composite filled with 5 wt% t-ZnO exhibits the strongest mechanical properties. Surface free energy (SFE) studies using contact angle measurements showed that the SFE value decreases with an increase in t-ZnO filler amounts. The influence of t-ZnO on the polymerization reaction was confirmed by Fourier transform infrared-spectroscopy measurements and thermogravimetric analysis. The immersion tests demonstrated that fouling behavior of the PTU/t-ZnO composite with a 1 wt% t-ZnO filler has been decreased in comparison to pure PTU. The composite with a 5 wt% t-ZnO filler showed almost no biofouling.

  4. Design, fabrication and characterization of high-stroke high-aspect ratio micro electro mechanical systems deformable mirrors for adaptive optics

    Science.gov (United States)

    Fernandez Rocha, Bautista

    Adaptive optic (AO) systems for next generation of extremely large telescopes (30--50 meter diameter primary mirrors) require high-stroke (10 microns), high-order (100x100) deformable mirrors at lower-cost than current technology. The required specifications are achievable with Micro Electro Mechanical Systems (MEMS) devices fabricated with high-aspect ratio processing techniques. This dissertation will review simulation results compared with displacement measurements of actuators utilizing a white-light interferometer. It will also review different actuator designs, materials and post-processing procedures fabricated in three different high-aspect ratio processes, Microfabrica's Electrochemical Fabrication (EFAB(TM)), HT-Micro's Precision Fabrication Technology (HTPF(TM)), and Innovative Micro Technologies (IMT) fabrication process. These manufacturing processes allow high-precision multilayer fabrication and their sacrificial layer thicknesses can be specified by the designer, rather than by constraints of the fabrication process. Various types of high-stroke gold actuators for AO consisting of folded springs with rectangular and circular membranes as well as X-beam actuators supported diagonally by beams were designed, simulated, fabricated, and tested individually and as part of a continuous facesheet DM system. The design, modeling and simulation of these actuators are compared to experimental measurements of their pull-in voltages, which characterizes their stiffness and maximum stroke. Vertical parallel plate ganged actuators fabricated with the EFAB(TM) process have a calculated pull-in voltage of 95V for a 600mum size device. In contrast, the pull-in voltages for the comb-drive actuators ranged from 55V for the large actuator, to 203V for the smallest actuator. Simulations and interferometer scans of actuator designs fabricated with HT-Micro's Precision Fabrication (HTPF(TM)) two wafer bonded process with different spring supports have shown the ability of

  5. Synchronized vortex shedding and sound radiation from two side-by-side rectangular cylinders of different cross-sectional aspect ratios

    Energy Technology Data Exchange (ETDEWEB)

    Octavianty, Ressa, E-mail: ressa-octavianty@ed.tmu.ac.jp; Asai, Masahito, E-mail: masai@tmu.ac.jp [Department of Aerospace Engineering, Tokyo Metropolitan University, 6-6 Asahigaoka, Hino, Tokyo 191-0065 (Japan)

    2015-10-15

    Synchronized vortex shedding from two side-by-side cylinders and the associated sound radiation were examined experimentally at Reynolds numbers of the order of 10{sup 4} in low-Mach-number flows. In addition to a pair of square cylinders, a pair of rectangular cylinders, one with a square cross section (d × d) and the other with a rectangular cross section (d × c) having a cross-sectional aspect ratio (c/d) of 1.2–1.5, was considered. The center-to-center distance between the two cylinders L/d was 3.6, 4.5, and 6.0; these settings were within the non-biased flow regime for side-by-side square cylinders. In case of a square cylinder pair, anti-phase synchronized vortex shedding occurring for L/d = 3.6 and 4.5 generated a quadrupole-like sound source which radiated in-phase, planar-symmetric sound in the far field. Synchronized vortex shedding from the two rectangular cylinders with different c/d also occurred with almost the same frequency as the characteristic frequency of the square-cylinder wake in the case of the small center-to-center distance, L/d = 3.6, for all the cylinder pairs examined. The synchronized sound field was anti-phase and asymmetric in amplitude, unlike the case of a square cylinder pair. For larger spacing L/d = 4.5, synchronized vortex shedding and anti-phase sound still occurred, but only for close cross-sectional aspect ratios (c/d = 1.0 and 1.2), and highly modulated sound was radiated with two different frequencies due to non-synchronized vortex shedding from the two cylinders for larger differences in c/d. It was also found that when synchronized vortex shedding occurred, near-wake velocity fluctuations exhibited high spanwise-coherency, with a very sharp spectral peak compared with the single-cylinder case.

  6. Variable Deflection Response of Sensitive CNT-on-Fiber Artificial Hair Sensors from CNT Synthesis in High Aspect Ratio Microcavities (Postprint)

    Science.gov (United States)

    2015-04-01

    microstructures such as tailored hair shapes, micro-antennae, brushes, or filters . The CNT arrays are synthesized in a 1” diameter quartz tube furnace...Microstructure Growth,” ACS Nano, 8(6), 5799-5812 (2014). [17] P. B. Amama, C. L. Pint, L. McJilton et al., “Role of Water in Super Growth of Single...Garcia et al., “High-yield growth and morphology control of aligned carbon nanotubes on ceramic fibers for multifunctional enhancement of structural

  7. Sub percolation threshold carbon nanotube based polyvinylidene fluoride polymer-polymer composites

    Science.gov (United States)

    Jacob, Cedric Antony

    The study of piezoelectric materials has traditionally focused largely on homogeneous crystalline or semi-crystalline materials. This research focuses on the concept of piezoelectric composites using selective microstructural reinforcement in the piezoelectric material to improve the piezoelectric properties. This is done using a polyvinylidene fluoride (PVDF) and carbon nanotube composite as the model system. A multi-tiered engineering approach is taken to understand the material (experimental and computational analyses) and design a composite system which provides an effective platform for future research in piezoelectric improvement. A finite element analysis is used to evaluate the ability of carbon nanotubes to generate a heterogeneous electric field where local improvements in electric field produce an increase in the effective piezoelectric strength. The study finds that weight percent and aspect ratio of the carbon nanotubes are of key importance while formations of percolating networks are detrimental to performance. This motivates investigation into electrospinning into a method of producing sub percolation threshold composites with large carbon nanotube content. However, the electrospun fabrics have too low of a dielectric strength to sustain high strength electric fields. This is studied within the context of high voltage physics and a solution inspired by traditional composites manufacturing is proposed wherein the electrospun fiber mat is used as the fiber reinforcing component of a polymer-polymer composite. This composite is thoroughly analyzed to show that it allows for a high dielectric strength combined with high carbon nanotube content. It is also shown that the PVDF contains the proper crystal structure to allow for piezoelectric properties. Furthermore, the addition of carbon nanotubes greatly improves the strength and stiffness of the composite, as well as affecting the internal electric field response to an applied voltage. These qualities

  8. Ultra-thin resin embedding method for scanning electron microscopy of individual cells on high and low aspect ratio 3D nanostructures.

    Science.gov (United States)

    Belu, A; Schnitker, J; Bertazzo, S; Neumann, E; Mayer, D; Offenhäusser, A; Santoro, F

    2016-07-01

    The preparation of biological cells for either scanning or transmission electron microscopy requires a complex process of fixation, dehydration and drying. Critical point drying is commonly used for samples investigated with a scanning electron beam, whereas resin-infiltration is typically used for transmission electron microscopy. Critical point drying may cause cracks at the cellular surface and a sponge-like morphology of nondistinguishable intracellular compartments. Resin-infiltrated biological samples result in a solid block of resin, which can be further processed by mechanical sectioning, however that does not allow a top view examination of small cell-cell and cell-surface contacts. Here, we propose a method for removing resin excess on biological samples before effective polymerization. In this way the cells result to be embedded in an ultra-thin layer of epoxy resin. This novel method highlights in contrast to standard methods the imaging of individual cells not only on nanostructured planar surfaces but also on topologically challenging substrates with high aspect ratio three-dimensional features by scanning electron microscopy.

  9. The effects of winglets on low aspect ratio wings at supersonic Mach numbers. M.S. Thesis Report Feb. 1989 - Apr. 1991

    Science.gov (United States)

    Keenan, James A.; Kuhlman, John M.

    1991-01-01

    A computational study was conducted on two wings, of aspect ratios 1.244 and 1.865, each having 65 degree leading edge sweep angles, to determine the effects of nonplanar winglets at supersonic Mach numbers. A Mach number of 1.62 was selected as the design value. The winglets studied were parametrically varied in alignment, length, sweep, camber, thickness, and dihedral angle to determine which geometry had the best predicted performance. For the computational analysis, an available Euler marching technique was used. The results indicated that the possibility existed for wing-winglet geometries to equal the performance of wing-alone bodies in supersonic flows with both bodies having the same semispan. The first wing with winglet used NACA 1402 airfoils for the base wing and was shown to have lift-to-pressure drag ratios within 0.136 percent to 0.360 percent of the NACA 1402 wing-alone. The other base wing was a natural flow wing which was previously designed specifically for a Mach number of 1.62. The results obtained showed that the natural wing-alone had a slightly higher lift-to-pressure drag than the natural wing with winglets.

  10. Mosquitofish (Gambusia affinis preference and behavioral response to animated images of conspecifics altered in their color, aspect ratio, and swimming depth.

    Directory of Open Access Journals (Sweden)

    Giovanni Polverino

    Full Text Available Mosquitofish (Gambusia affinis is an example of a freshwater fish species whose remarkable diffusion outside its native range has led to it being placed on the list of the world's hundred worst invasive alien species (International Union for Conservation of Nature. Here, we investigate mosquitofish shoaling tendency using a dichotomous choice test in which computer-animated images of their conspecifics are altered in color, aspect ratio, and swimming level in the water column. Pairs of virtual stimuli are systematically presented to focal subjects to evaluate their attractiveness and the effect on fish behavior. Mosquitofish respond differentially to some of these stimuli showing preference for conspecifics with enhanced yellow pigmentation while exhibiting highly varying locomotory patterns. Our results suggest that computer-animated images can be used to understand the factors that regulate the social dynamics of shoals of Gambusia affinis. Such knowledge may inform the design of control plans and open new avenues in conservation and protection of endangered animal species.

  11. Fractionation and Characterization of High Aspect Ratio Gold Nanorods Using Asymmetric-Flow Field Flow Fractionation and Single Particle Inductively Coupled Plasma Mass Spectrometry

    Directory of Open Access Journals (Sweden)

    Thao M. Nguyen

    2015-07-01

    Full Text Available Gold nanorods (GNRs are of particular interest for biomedical applications due to their unique size-dependent longitudinal surface plasmon resonance band in the visible to near-infrared. Purified GNRs are essential for the advancement of technologies based on these materials. Used in concert, asymmetric-flow field flow fractionation (A4F and single particle inductively coupled mass spectrometry (spICP-MS provide unique advantages for fractionating and analyzing the typically complex mixtures produced by common synthetic procedures. A4F fractions collected at specific elution times were analyzed off-line by spICP-MS. The individual particle masses were obtained by conversion of the ICP-MS pulse intensity for each detected particle event, using a defined calibration procedure. Size distributions were then derived by transforming particle mass to length assuming a fixed diameter. The resulting particle lengths correlated closely with ex situ transmission electron microscopy. In contrast to our previously reported observations on the fractionation of low-aspect ratio (AR GNRs (AR < 4, under optimal A4F separation conditions the results for high-AR GNRs of fixed diameter (≈20 nm suggest normal, rather than steric, mode elution (i.e., shorter rods with lower AR generally elute first. The relatively narrow populations in late eluting fractions suggest the method can be used to collect and analyze specific length fractions; it is feasible that A4F could be appropriately modified for industrial scale purification of GNRs.

  12. Effect of Partial Shrouds on the Performance and Flow Field of a Low-Aspect-Ratio Axial-Flow Fan Rotor

    Directory of Open Access Journals (Sweden)

    N. Sitaram

    2011-01-01

    Full Text Available The flow field at the rotor exit of a low aspect ratio axial flow fan for different tip geometries and for different flow coefficients is measured in the present study. The following configurations are tested: (1 rotor without partial shroud, designated as rotor (wos, (2 rotor with partial shroud, designated as rotor (ws, and (3 rotor with perforated (perforations in the shape of discrete circular holes partial shroud, designated as rotor (wps. From steady state measurements, the performance of rotor (wps is found to be the best. Both the rotors with partial shrouds have stalled at a higher flow coefficient compared to that of rotor (wos. From periodic flow measurements, it is concluded that the low velocity region near the tip section is considerably reduced with the use of partial shrouds with perforations. The extent of this low velocity region for both rotor (wos and rotor (wps increases with decreasing flow coefficient due to increased stage loading. This core of low momentum fluid has moved inwards of the annulus and towards the pressure side as the flow coefficient decreases. The extent of the low momentum fluid is smaller for rotor (wps than that of rotor (wos at all flow coefficients.

  13. Catalytic Synthesis of Substrate-Free, Aligned and Tailored High Aspect Ratio Multiwall Carbon Nanotubes in an Ultrasonic Atomization Head CVD Reactor

    Directory of Open Access Journals (Sweden)

    Fahad Ali Rabbani

    2016-01-01

    Full Text Available Chemical vapor deposition (CVD method has proven its benchmark, over other methods, for the production of different types of carbon nanotubes (CNT on commercial and lab scale. In this study, an injection vertical CVD reactor fitted with an ultrasonic atomization head was used in a pilot-plant scale (height 274 cm, radius 25 cm for semicontinuous production of multiwall carbon nanotubes (MWCNTs. p-Xylene was used as a hydrocarbon precursor in which ferrocene was dissolved and provided the cracking catalyst. Atomization of the feed solution resulted in full and even dispersion of the catalytic solution. This dispersion led to the production of high aspect ratio MWCNTs (ranging from 8,000 to 12,000 at 850°C. Different experimental parameters affecting the quality and quantity of the produced CNTs were investigated. These included temperature, reaction time, and flow rate of the reaction and carrier gases. Different properties of the produced CNTs were characterized using SEM and TEM, while TGA was used to evaluate their purity. Specific surface area of selected samples was calculated by BET.

  14. 高厚径比HDI板电镀能力研究%Plating ability Of HDI with high aspect ratio item

    Institute of Scientific and Technical Information of China (English)

    班向东

    2013-01-01

    With the development of information technology, more layers, thickness, aperture smaller, thicker wiring denser PCB needs PCB manufacturers put forward higher requirements. High aspect ratio and BMV plating are two different processing direction of PCB plating, and the two requirements of both the product processing is the dififculty of electroplating. So to ifnd a balance between the two is very important. Through the experiment, we found the electroplating parameters, achieved the balance of the blind holes.%随着信息技术的不断发展,层数更多、板厚更厚、孔径更小、布线更密的PCB需求给PCB生产厂家提出的更高的要求。高纵横比与盲孔电镀是PCB电镀的两个不同的加工方向,而这两种要求并存的产品加工是电镀的难点,因此找到两者之间的平衡点至关重要。本文通过实验,找到两者兼顾的电镀参数,达到通盲孔兼顾的效果。

  15. Numerical Investigation of Wind Conditions for Roof-Mounted Wind Turbines: Effects of Wind Direction and Horizontal Aspect Ratio of a High-Rise Cuboid Building

    Directory of Open Access Journals (Sweden)

    Takaaki Kono

    2016-11-01

    Full Text Available From the viewpoint of installing small wind turbines (SWTs on rooftops, this study investigated the effects of wind direction and horizontal aspect ratio (HAR = width/length of a high-rise cuboid building on wind conditions above the roof by conducting large eddy simulations (LESs. The LES results confirmed that as HAR decreases (i.e., as the building width decreases, the variation in wind velocity over the roof tends to decrease. This tendency is more prominent as the angle between the wind direction and the normal vector of the building’s leeward face with longer roof edge increases. Moreover, at windward corners of the roof, wind conditions are generally favorable at relatively low heights. In contrast, at the midpoint of the roof's windward edge, wind conditions are generally not favorable at relatively low heights. At leeward representative locations of the roof, the bottoms of the height range of favorable wind conditions are typically higher than those at the windward representative locations, but the favorable wind conditions are much better at the leeward representative locations. When there is no prevailing wind direction, the center of the roof is more favorable for installing SWTs than the corners or the edge midpoints of the roof.

  16. Multi scale modeling of the elastic properties of polymer-clay nanocomposites

    Science.gov (United States)

    Pahlavan Pour, Maryam

    Polymer-Clay Nanocomposites (PCN) are known to improve the mechanical properties of bulk polymers, even for modest clay loadings. This enhancement is due to the high aspect ratio and mechanical properties of the nanoclay platelets. Additionally, the interphase zone created by altered polymer chains in the vicinity of the nanoclays plays an important reinforcing role. Several analytical approaches exist for predicting the elastic properties of PCN, ranging from simplified two-step models to more complex one-step methods. However, no thorough study has yet rigorously verified the accuracy of these models. On the other hand, the numerical models that are commonly used to evaluate the analytical models are still far from modeling the real PCN microstructure reported in the literature. For example, most of the models have failed to model the detailed 3D microstructure considering randomly positioned reinforcing particles, the large nanoclay aspect ratio and the explicit incorporation of the constituent phases. More significantly, most of numerical studies have been reported without a thorough determination of the appropriate Representative Volume Element (RVE) due its computational burden, resulting in benchmark results of questionable accuracy. The main purpose of this thesis was to evaluate the accuracy of homogenization models for predicting the mechanical behavior of nanoclay nanocomposites. First, the validity of commonly used analytical micromechanical models for the prediction of exfoliated PCN elastic properties was evaluated with the help of 3D Finite Element (FE) simulations. In particular, special attention was devoted to the interphase around the nanoclays. The modeling strategy was a two-step procedure relying on the Effective Particle (EP) concept, in which the multi-layer reinforcing stacks were replaced by homogenized particles. The accuracy of the numerical models was guaranteed, within a given tolerance, by rigorous determination of the RVE. It was

  17. Freeze-thaw cycle test and microstructural analysis on lightweight polymer mortar%轻质聚合物抹面砂浆冻融循环及微观机理研究

    Institute of Scientific and Technical Information of China (English)

    苏志杰; 路永华; 宋跃军

    2014-01-01

    It was studied on the mechanical properties and strain of polymer plaster mortars for external thermal insulation composite systems(ETICS) under freeze-thaw cycle test.The results demonstrated that after freeze-thaw cycle test,the total micro-strain and incre-ment of the flexural and compressive strength ratio of lightweight polymer mortar were less than commonly used polymer mortar.As a re-sult,the lightweight polymer mortar have better flexibility and durability.At the same time,it was studied on the microstructure using SEM about these three mortars.%针对外墙外保温体系用聚合物抹面砂浆在经受冻融循环试验条件下的应变和力学性能进行研究,结果表明:聚合物抹面砂浆经历一定次数的冻融循环后,轻质系列聚合物抹面砂浆总微应变量和压折比增加量均小于常用聚合物抹面砂浆,具有更好的柔韧性,提高了砂浆的耐久性。同时,利用 SEM 对三种砂浆进行了微观机理研究。

  18. Effect of Aspect Ratio, Channel Orientation, Rib Pitch-to-Height Ratio, and Number of Ribbed Walls on Pressure Drop Characteristics in a Rotating Channel with Detached Ribs

    Directory of Open Access Journals (Sweden)

    K. Arun

    2007-01-01

    Full Text Available The present work involves experimental investigation of the effects of aspect ratio, channel orientation angle, rib pitch-to-height ratio (P/e, and number of ribbed walls on friction factor in orthogonally rotating channel with detached ribs. The ribs are separated from the base wall to provide a small region of flow between the base wall and the ribs. Experiments have been conducted at Reynolds number ranging from 10000–17000 with rotation numbers varying from 0–0.38. Pitch-to-rib height ratios (P/e of 5 and 10 at constant rib height-to-hydraulic diameter ratio (e/D of 0.1 and a clearance ratio (C/e of 0.38 are considered. The rib angle of attack with respect to mainstream flow is 90∘. The channel orientation at which the ribbed wall becomes trailing surface (pressure side on which the Coriolis force acts is considered as the 0∘ orientation angle. For one-wall ribbed case, channel is oriented from 0∘ to 180∘ about its axis in steps of 30∘ to change the orientation angle. For two-wall ribbed case, the orientation angle is changed from 0∘ to 90∘ in steps of 30∘. Friction factors for the detached ribbed channels are compared with the corresponding attached ribbed channel. It is found that in one-wall detached ribbed channel, increase in the friction factor ratio with the orientation angle is lower for rectangular channel compared to that of square channel for both the pitch-to-rib height ratios of 5 and 10 at a given Reynolds number and rotation number. Friction factor ratios of two-wall detached ribbed rectangular channel are comparable with corresponding two-wall detached ribbed square channel both under stationary and rotating conditions.

  19. Aspect ratio control of Au nanorods via covariation of the total amount of HAuCl{sub 4} and ascorbic acid

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Xiao [State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, 122 Luoshi Road, Hongshan District, Wuhan 430070, Hubei (China); Wang, Moo-Chin, E-mail: mcwang@kmu.edu.tw [Department of Fragrance and Cosmetic Science, Kaohsiung Medical University, 100 Shih-Chuan 1st Road, Kaohsiung 80708, Taiwan (China); Feng, Jinyang [State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, 122 Luoshi Road, Hongshan District, Wuhan 430070, Hubei (China); Zhao, Xiujian, E-mail: opluse@whut.edu.cn [State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, 122 Luoshi Road, Hongshan District, Wuhan 430070, Hubei (China)

    2015-07-15

    Highlights: • The AR value decreased as the total amount of [HAuCl{sub 4}] and [AA] increasing. • The UV–vis absorption spectra showed the peak wavelength of TSPR at around 530 nm. • The wavelength of LSPR had a red-shifted effect. - Abstract: Controlling the aspect ratio (AR) of gold nanorods (GNRs) via covariation of the total concentrations of HAuCl{sub 4} ([HAuCl{sub 4}]) and ascorbic acid ([AA]) has been studied. Characteristics of GNRs were examined by transmission electron microscopy (TEM) and ultraviolet–visible (UV–vis) absorption spectrophotometry. TEM results showed that single crystalline GNRs grew along an elongated growth direction of [100]. TEM results also revealed that the quantity of plate shaped and nearly spherical nanoparticles increased as the total amount of [HAuCl{sub 4}] and [AA] decreased. The AR value measured from TEM images decreased from 4.74 to 2.41 as the total amount of [HAuCl{sub 4}] and [AA] was increased from 0.305 to 2.44 mM. The UV–vis absorption spectra of all samples showed that the wavelength of transverse surface plasmon resonance (TSPR) peak appeared at around 530 nm for all samples. The wavelength of longitudinal surface plasmon resonance (LSPR) peak increased from 640 to 894 nm as the total amount of [HAuCl{sub 4}] and [AA] decreased from 2.44 to 0.305 mM. The wavelength of LSPR peak shows a red-shifted effect except when the total amount of [HAuCl{sub 4}] and [AA] was 0.122 mM.

  20. Nonlinear microstructured polymer optical fibres

    DEFF Research Database (Denmark)

    Frosz, Michael Henoch

    . The combination of a small core size and zero-dispersion wavelength at the operating wavelength of widely available femtosecond Ti:sapphire lasers led to an extensive research in supercontinuum generation and other nonlinear effects in PCFs. It is crucial for the efficiency of many nonlinear mechanisms...... that the pump laser wavelength is close to the zero-dispersion wavelength and that the core size is small. Recently, work in fabricating PCFs from materials other than silica has intensified. One of the advantages of using alternative materials can be a higher inherent material nonlinearity, which...... to accurately obtain a small core size while maintaining small structural variations during fibre drawing. This talk will give a presentation of how the mPOFs are fabricated and the route to obtaining nonlinear effects in them....

  1. Enhancing the Wettability of High Aspect-Ratio Through-Silicon Vias Lined with LPCVD Silicon Nitride or PE-ALD Titanium Nitride for Void-Free Bottom-Up Copper Electroplating

    NARCIS (Netherlands)

    Saadaoui, M.; van Zeijl, H.; Wien, W. H. A.; Pham, H. T. M.; Kwakernaak, C.; Knoops, H. C. M.; Kessels, W. M. M.; R. van de Sanden,; Voogt, F. C.; Roozeboom, F.; Sarro, P. M.

    2011-01-01

    One of the critical steps toward producing void-free and uniform bottom-up copper electroplating in high aspect-ratio (AR) through-silicon vias (TSVs) is the ability of the copper electrolyte to spontaneously flow through the entire depth of the via. This can be accomplished by reducing the concentr

  2. Wetting and dispersion in ceramic/polymer melt injection molding systems: Progress report

    Energy Technology Data Exchange (ETDEWEB)

    Sacks, M.D.; Williams, J.W.; Batich, C.D.

    1986-11-01

    Research progress is reported in the areas of rheological characterization, mixing/deagglomeration, ceramic/polymer interface modification, polymer matrix chemistry, and microstructure characterization. (DLC)

  3. Technological and material related challenges for large area, high aspect-ratio, near teradot/inch2 areal density and three-dimensional structuring of polyaniline.

    Science.gov (United States)

    Jedrasik, Piotr; Vlad, Alexandru; Södervall, Ulf

    2011-10-01

    In this manuscript we report on a newly developed technology for the nanoscale processing of the conducting polyaniline (PANI) with an unprecedented areal patterning order and density control exceeding 0.25 teradot/inch2. High resolution electron beam lithography was used to generate ordered 2D and 3D templates. A novel type of resist and dose-modulated 3D-electron beam lithography (RDM-3D-EBL), extensively exploiting the intrinsic properties of resist-electron beam interaction is detailed. Surface initiated and template confined aniline polymerization, through catalytic activity of metallic platinum, was then exploited to provide a genuine method for controlled nanoscale processing of polyaniline, a prototypical conjugated polymer that definitively settled the concept of synthetic metals. Using nanoscale polymerization reactors, ultimate resolution patterning and processing control of single polyaniline nanostructures was feasible. Aspects of the nanoscale polyaniline growth mechanism are discussed and the highly controllable, sub-picogram scale fabrication is emphasized. Near teradot/inch2 pattern transfer technology, complex 3D structuring and physico-chemical functionalization of polyaniline can be subsequently harnessed to build a large variety of architectures with potential for emerging optoelectronic technologies. The method is scalable, can be applied on virtually any type of flexible or rigid substrates and provides a generic approach for nanopatterning surfaces with functional polymers. Technological and material related fabrication challenges are detailed and discussed.

  4. Double layer resist process scheme for metal lift-off with application in inductive heating of microstructures

    DEFF Research Database (Denmark)

    Ouattara, Lassana; Knutzen, Michael; Keller, Stephan Urs

    2010-01-01

    We present a new method to define metal electrodes on top of high-aspect-ratio microstructures using standard photolithography equipment and a single chromium mask. A lift-off resist (LOR) layer is implemented in an SU-8 photolithography process to selectively remove metal at the end of the proce...

  5. Urease-induced calcification of segmented polymer hydrogels - a step towards artificial biomineralization.

    Science.gov (United States)

    Rauner, Nicolas; Meuris, Monika; Dech, Stephan; Godde, Julia; Tiller, Joerg C

    2014-09-01

    Natural organic/inorganic composites, such as nacre, bones and teeth, are perfectly designed materials with exceptional mechanical properties. Numerous approaches have been taken to synthetically prepare such composites. The presented work describes a new way of mineralizing bulk materials on a large scale following the approach of bioinduced mineralization. To this end, a series of polymer conetworks with entrapped urease were prepared. After polymerization, the entrapped urease shows high enzymatic activity. The bioactive polymer conetworks were then treated with an aqueous mixture of urea and CaCl2. The urease-induced calcification indeed allows formation of carbonate crystals exclusively within the hydrogel even at room temperature. The influence of network composition, degree of cross-linking, immobilized urease concentration and temperature of calcification were investigated. By varying these parameters, spherical, monolithic clusters, as well as bar-like nanocrystals with different aspect ratios in spherical or dendritic arrays, are formed. The grown nanocrystals improve the stiffness of the starting material by up to 700-fold, provided that the microstructure shows a dense construction without pores and strong interaction between crystals and network. The process has the potential to generate a new class of hybrid materials that would be available on the macroscopic scale for use in lightweight design and medicine.

  6. Thermal Conductivity of Polymer-Based Composites with Magnetic Aligned Hexagonal Boron Nitride Platelets.

    Science.gov (United States)

    Yuan, Chao; Duan, Bin; Li, Lan; Xie, Bin; Huang, Mengyu; Luo, Xiaobing

    2015-06-17

    Hexagonal boron nitride (hBN) platelets are widely used as the reinforcing fillers for enhancing the thermal conductivity of polymer-based composites. Since hBN platelets have high aspect ratio and show a highly anisotropic thermal property, the thermal conductivity of the hBNs-filled composites should be strongly associated with the platelets' orientation. However, the orientation effect has been explored less frequently due to the technical difficulties in precontrol of the platelets' orientation in the polymer matrix. In this paper, we report the use of magnetic fields to assemble the platelets into various microstructures and to study the thermal conductivities of the designed composites. The experimental results showed that thermal conductivities are dramatically different among these composites. For instance, the thermal conductivities of the composites with platelets oriented parallel and perpendicular to the heat flux direction are respectively 44.5% higher and 37.9% lower than that of unaligned composites at the volume fraction of 9.14%. The results were also analyzed by a theoretical model. The model suggests that the orientation of the hBN platelets is the main reason for the variance in the thermal conductivity.

  7. The use of Functionalized Nanoparticles as Non-specific Compatibilizers for Polymer Blends

    Energy Technology Data Exchange (ETDEWEB)

    W Zhang; M Lin; A Winesett; O Dhez; L Kilcoyne; H Ade; M rubinstein; K Shafi; A Ulman; et al.

    2011-12-31

    The ability to form blends of polymers offers the opportunity of creating a new class of materials with enhanced properties. In addition to the polymer components, recent advances in nanoengineering have resulted in the development of nanosized inorganic particles that can be used to improve the properties of the blend, such as the flammability and the mechanical properties. While traditional methods using copolymer compatibilizers have been used to strengthen polymer blends, here, we show that the inorganic nanosized filler additive can also serve as a compatibilizer as it can localize to the interface between the polymers. We use experimental and theoretical studies to show the fundamental mechanisms by which inorganic fillers with large aspect ratio and at least one-dimension in the nanometer range, can act as non-specific compatibilizers for polymer blends. We examine a series of nanosized fillers, ranging from nanotubes to nanoclays (with varying aspect ratios) in a model polystyrene (PS)/poly(methylmethacyralate) (PMMA) blend. Using a number of experimental techniques such as transmission electron microscopy (TEM), scanning tunneling X-ray microscopy (STXM), and atomic force microscopy (AFM) we postulate that the mechanism of compatibilization occurs as a result of the fillers forming in situ grafts with the immiscible polymers. We also use theoretical studies to show that the aspect ratio and the bending energy of the fillers play a key role in the compatibilization process. Our results indicate that the compatibilization is a general phenomenon, which should occur with all large aspect ratio nanofiller additives to polymer blends.

  8. Physico-Mechanical Properties of Cellulose Acetate Butyrate/ Yellow Poplar Wood Fiber Composites as a Function of Fiber Aspect Ratio, Fiber Loading, and Fiber Acetylation

    Directory of Open Access Journals (Sweden)

    M. E. Enyiegbulam

    2012-10-01

    Full Text Available In order to achieve completely biodegradable thermoplastic polymer composite, the development of yellow poplar wood fiber (YPWF-reinforced cellulose acetate butyrate (CAB composites was carried out. The CAB/YPWF composite was prepared using a two-roll mill. Composite samples were prepared with two different fiber types with fiber content of 0, 10, 20, 30, and 40wt %. While the untreated fibers (UTF were used as obtained without treatment and chemical modification, the other fiber type, Acetylated Alkali-Extracted Steam Exploded Fibers (AAEF were subjected to different physical and chemical treatments. Some physico-mechanical properties of the composites as well as the swelling characteristics in dimethylformamide were investigated. Also, scanning electron microscope (SEM was used to investigate the morphological characteristics of the tensile fracture surfaces of the composites. The modified wood fibers (AAEF enhanced both the physico-mechanical properties and the swelling characteristics of the composites studied.

  9. Can Nanorods Emulsify Immiscible Polymer Blends?

    Science.gov (United States)

    Hore, Michael J. A.

    2005-03-01

    The addition of nanoscale rods to immiscible binary polymer blends has a pronounced effect on the dynamics of phase separation. The results of computer simulations of the Dissipative Particle Dynamics (DPD) model in three dimensions (3D) indicate that when nanorods prefer one of two components in an immiscible binary polymer blend, the rate of phase separation decreases when the volume fraction of nanorods is increased, or as the aspect ratio (L/D) of the rods is increased. Interestingly, anisotropic nanoparticles have a much more pronounced effect on phase separation dynamics in the system when compared to the effects of spherical nanoparticles, which, generically, do not alter the characteristics of the kinetics in the system. In particular, it may be the case that at high volume fractions -- or alternatively, low volume fractions and large aspect ratio of nanorods -- the system may undergo micro-phase separation only, indicating that the nanorods may be excellent emulsifying agents.

  10. Study on the change of aspect ratios of small surface cracks emanated from a toe of corner boxing; Mawashi yosetsudome tanbu kara hassei denpasuru bishi bisho hyomen kiretsu no aspect hi henka ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Toyosada, M.; Yamaguchi, K.; Takeda, K.; Watanabe, Y. [Kyushu University, Fukuoka (Japan). Faculty of Engineering

    1997-10-01

    The fatigue test of specimens with a stiffener was carried out to examine the change in aspect ratio (crack depth/length) of fatigue cracks in a stress concentration field and residual stress field. The aspect ratio of surface cracks just after generation can be represented with the single virtual surface crack with the same value as K value at the deepest point considering an interference effect from near cracks. No discontinuous change in K value is found at the deepest point even during growth and combination of cracks on a surface. The change in K value at the deepest point is thus the criterion to represent growth and combination of surface cracks considering the interference effect. The change in aspect ratio of the typical single virtual surface crack linearly decreases with an increase in crack depth. The shape of surface cracks generating and growing in a residual stress field is more flat than that in no residual stress field. In addition, in a residual stress field, surface cracks are longer at the same crack depth, and fatigue lives are shorter. 7 refs., 12 figs.

  11. AFD高标清幅型变换信息在MXF文件的表示方法%A Method for Information Representation of Aspect Ratio Conversion between HDTV and SDTV

    Institute of Scientific and Technical Information of China (English)

    凌坚; 周春燕

    2012-01-01

    Aspect Ratio Conversion is necessary to achieve HDTV and SDTV simulcast and material sharing. In this paper, based on the analysis of the characteristics of the AFD standard, the MXF file structure and data encapsulation method, a method for embedding aspect ratio conversion information which accords with AFD standard is put forward. In accordance with the MXF file metadata extension specification, the aspect ratio conversion between HDTV and SDTV and the information of the conversion and material data binding are a- chieved by the method.%实现高标清同播和素材共享必须对视频进行画幅变换。在分析AFD标准的特点、MXF文件的结构与数据封装方法的基础上,提出了一种在MXF文件中嵌入采用AFD标准描述符的幅型变换信息的方法,该方法将AFD数据作为元数据,依照MXF文件中元数据的扩展规范,实现了画幅变换信息与素材数据的绑定。

  12. Electrical and thermal percolation in carbon nanotube- polymer composites

    OpenAIRE

    Kim, Byung-Wook

    2014-01-01

    Electrical and thermal properties of carbon-nanotube (CNT) /polymer composites were investigated through percolating behavior of conducting fillers in insulating matrix. Synthesis methodology has been found using a blend of solution processing, which was adapted to facilitate uniformly distributed CNTs in polymer matrix and consequently to contribute to percolation. The onset of percolation thresholds depending on aspect ratio of fillers were theoretically estimated by the excluded volume met...

  13. Effect of lanthanide on the microstructure and structure of LnMn{sub 0.5}Fe{sub 0.5}O{sub 3} nanoparticles with Ln=La, Pr, Nd, Sm and Gd prepared by the polymer precursor method

    Energy Technology Data Exchange (ETDEWEB)

    Romero, Mariano [Centro NanoMat/Cryssmat Lab/Cátedra de Física—DETEMA, Facultad de Química—UdelaR, Montevideo (Uruguay); Centro Interdisciplinario de Nanotecnología, Química y Física de Materiales—UdelaR, Montevideo (Uruguay); Faccio, Ricardo, E-mail: rfaccio@fq.edu.uy [Centro NanoMat/Cryssmat Lab/Cátedra de Física—DETEMA, Facultad de Química—UdelaR, Montevideo (Uruguay); Centro Interdisciplinario de Nanotecnología, Química y Física de Materiales—UdelaR, Montevideo (Uruguay); Martínez, Javier [Departamento de Física de La Plata, Universidad Nacional de La Plata, La Plata (Argentina); Instituto de Física de La Plata, CCT-La Plata—CONICET, La Plata (Argentina); Universidad Nacional del Noroeste de la Provincia de Buenos Aires, Corrientes (Argentina); Pardo, Helena; Montenegro, Benjamín [Centro NanoMat/Cryssmat Lab/Cátedra de Física—DETEMA, Facultad de Química—UdelaR, Montevideo (Uruguay); Centro Interdisciplinario de Nanotecnología, Química y Física de Materiales—UdelaR, Montevideo (Uruguay); Plá Cid, Cristiani Campos; Pasa, André A. [Laboratorio Central de microscopía electrónica, Universidad Federal de Santa Catarina, Florianópolis (Brazil); and others

    2015-01-15

    The synthesis of LnMn{sub 0.5}Fe{sub 0.5}O{sub 3} perovskite nanoparticles by the polymer precursor method showed a strong intrinsic dependence with different lanthanides (Ln=La, Pr, Nd, Sm and Gd). The polymerization level reached in the polymer precursor was proportional to the atomic number of lanthanide with exception of samarium, which showed the formation of a different precursor based in a citrate chelate with ethyleneglycol bonded as adduct. The increasing level of polymerization of the polymer precursors showed the formation of large-size perovskite nanoparticles after its calcination. SAXS and TEM analyses suggested that nanoparticles obtained, using this method, have a squared-like microstructure in connection with the polymer precursor microstructure. Structural analysis showed an orthorhombic structure with a slight decline in the Jahn–Teller distortion when the atomic number of lanthanide increases. Mössbauer spectroscopy showed the presence of a majority site in agreement with the Pbnm orthorhombic structure best fitted with Rietveld refinements and in some cases, a more distorted site attributed to local inhomogeneities and oxygen vacancies. - Highlights: • Precursor polymerization level is lower in the presence of lighter lanthanides. • Lighter lanthanide perovskite nanoparticles after calcination are lower-sized. • Nanoparticles obtained by this method have lamellae microstructure. • Jahn–Teller distortion declines for heavier lanthanide perovskites. • Oxygen vacancy phase was observed in lighter lanthanide perovskites.

  14. Nuclear Instruments and Methods in Physics Research. Section B; Microstructural Characterization of Semi-Interpenetrating Polymer Networks by Positron Lifetime Spectroscopy

    Science.gov (United States)

    Singh, Jag J.; Pater, Ruth H.; Eftekhari, Abe

    1998-01-01

    Thermoset and thermoplastic polyimides have complementary physical/mechanical properties. Whereas thermoset polyimides are brittle and generally easier to process, thermoplastic polyimides are tough but harder to process. It is expected that a combination of these two types of polyimides may help produce polymers more suitable for aerospace applications. Semi-Interpenetrating Polymer Networks (S-IPNs) of thermoset LaRC(Trademark)-RP46 and thermoplastic LARC(Trademark)-IA polyimides were prepared in weight percent ratios ranging from 100:0 to 0: 100. Positron lifetime measurements were made in these samples to correlate their free volume features with physical/mechanical properties. As expected, positronium atoms are not formed in these samples. The second life time component has been used to infer the positron trap dimensions. The "free volume" goes through a minimum at about 50:50 ratio, suggesting that S-IPN samples are not merely solid solutions of the two polymers. These data and related structural properties of the S-IPN samples have been discussed in this paper.

  15. 大展弦比飞翼布局飞机的三轴稳定特性%Three-axis stability characteristics of flying wing with high aspect ratio

    Institute of Scientific and Technical Information of China (English)

    张子军; 王磊; 王立新; 王晋军

    2012-01-01

    飞翼布局飞机取消了平尾和垂尾,构型的改变和阻力方向舵的使用使其呈现出与常规布局飞机不同的三轴稳定特性.以大展弦比飞翼布局飞机为研究对象,开展了其三轴静、动稳定特性的研究;通过与常规大展弦比飞机进行对比,揭示了飞翼构型参数、典型飞行状态对其稳定性的影响规律;分析了阻力方向舵的偏转对此类飞机稳定性的影响.研究结果表明,大展弦比飞翼布局飞机的本体稳定性存在诸多的不足.%A flying wing cancels horizontal and vertical tails, but the changes of configuration and the use of drag rudder make it differ much from the conventional configuration aircraft in three-axis stability characteristics. The aircraft chosen for the study is a flying wing with high aspect ratio. Its three-axis static and dynamic stability characteristics are studied. Comparing with the conventional configuration aircraft with high aspect ratio, the effects of configuration parameters and typical flight condition on the stabilities of the flying wing are discussed. The impact of the drag rudder on the stabilities of such aircraft types is also analyzed. Results show that there are many deficiencies in the inherent three-axis stabilities of the high aspect ratio flying wing.

  16. High-efficiency microstructured semiconductor neutron detectors that are arrayed, dual-integrated, and stacked

    Energy Technology Data Exchange (ETDEWEB)

    Bellinger, Steven L., E-mail: slb3888@ksu.edu [Department of Mechanical and Nuclear Engineering, Kansas State University, Manhattan, KS 66506 (United States); Fronk, Ryan G. [Department of Mechanical and Nuclear Engineering, Kansas State University, Manhattan, KS 66506 (United States); Sobering, Timothy J. [Electronics Design Laboratory, Kansas State University, Manhattan, KS 66506 (United States); McGregor, Douglas S. [Department of Mechanical and Nuclear Engineering, Kansas State University, Manhattan, KS 66506 (United States)

    2012-07-15

    Silicon diodes with large aspect ratio 3D microstructures backfilled with {sup 6}LiF show a significant increase in neutron detection efficiency beyond that of conventional thin-film coated planar devices. Described in this work are advancements in the technology using detector stacking methods and summed-detector 6 Multiplication-Sign 6-element arraying methods to dramatically increase the sensitivity to thermal neutrons. The intrinsic detection efficiency of the 6 Multiplication-Sign 6 array for normal-incident 0.0253 eV neutrons was found 6.8% compared against a calibrated {sup 3}He proportional counter. - Highlights: Black-Right-Pointing-Pointer Solid-state semiconductor neutron detectors utilizing {sup 6}LiF. Black-Right-Pointing-Pointer Large aspect ratio 3D microstructured silicon diodes. Black-Right-Pointing-Pointer Arrayed solid-state semiconductor neutron detectors.

  17. Microstructure synthesis control of biological polyhydroxyalkanoates with mass spectrometry

    Science.gov (United States)

    Pederson, Erik Norman

    Polyhydroxyalkanoates (PHA's) are a class of biologically produced polymers, or plastic, that is synthesized by various microorganisms. PHA's are made from biorenewable resources and are fully biodegradable and biocompatible, making them an environmentally friendly green polymer. A method of incorporating polymer microstructure into the PHA synthesized in Ralstonia eutropha was developed. These microstructures were synthesized with polyhydroxybutyrate (PHB) and poly(hydroxybutyrate-co-hydroxyvalerate) (PHBV) as the polymer domains. To synthesize the PHB V copolymer, the additional presence of valerate was required. To control valerate substrate additions to the bioreactor, an off-gas mass spectrometry (MS) feedback control system was developed. Important process information including the cell physiology, growth kinetics, and product formation kinetics in the bioreactor was obtained with MS and used to control microstructure synthesis. The two polymer microstructures synthesized were core-shell granules and block copolymers. Block copolymers control the structure of the individual polymer chains while core-shell granules control the organization of many polymer chains. Both these microstructures result in properties unattainable by blending the two polymers together. The core-shell structures were synthesized with controlled domain thickness based on a developed model. Different block copolymers compositions were synthesized by varying the switching time of the substrate pulses responsible for block copolymer synthesis. The block copolymers were tested to determine their chemical properties and cast into films to determine the materials properties. These block copolymer films possessed new properties not achieved by copolymers or blends of the two polymers.

  18. Low-speed aerodynamic performance of a high-aspect-ratio supercritical-wing transport model equipped with full-span slat and part-span double-slotted flaps

    Science.gov (United States)

    Morgan, H. L., Jr.; Paulson, J. W., Jr.

    1979-01-01

    An investigation was conducted in the Langley V/STOL tunnel to determine the static longitudinal and lateral-directional aerodynamic characteristics of an advanced high-aspect-ratio supercritical-wing transport model equipped with a full-span leading-edge slat and part-span double-slotted trailing-edge flaps. This wide-body transport model was also equipped with spoiler and aileron control surfaces, flow-through nacelles, landing gear, movable horizontal tails, and interchangeable wing tips with aspect ratios of 10 and 12. The model was tested with leading-edge slat and trailing-edge flap combinations representative of cruise, climb, takeoff, and landing wing configurations. The tests were conducted at free-stream conditions corresponding to Reynolds numbers (based on mean geometric chord) of 0.97 to 1.63 x 10 to the 6th power and corresponding Mach numbers of 0.12 to 0.20, through an angle-of-attack range of -2 deg to 24 deg and a sideslip-angle range of -10 deg to 5 deg.

  19. Effect of storage on microstructural changes of Carbopol polymers tracked by the combination of positron annihilation lifetime spectroscopy and FT-IR spectroscopy.

    Science.gov (United States)

    Szabó, Barnabás; Süvegh, Károly; Zelkó, Romána

    2011-09-15

    Different types of Carbopols are frequently applied excipients of various dosage forms. Depending on the supramolecular structure, their water sorption behaviour could significantly differ. The purpose of the present study was to track the supramolecular changes of two types of Carbopol polymers (Carbopol 71G and Ultrez 10NF) alone and in their physical mixture with a water-soluble drug, vitamin B(12), as a function of storage time. The combination of FT-IR spectroscopy, positron annihilation lifetime spectroscopy (PALS) and Doppler-broadening spectroscopy was applied to follow the effect of water uptake on the structural changes. Our results indicate that water-induced interactions between polymeric chains can be sensitively detected. This enables the prediction of stability of dosage forms in the course of storage.

  20. 高宽比对生态复合墙体破坏模式的影响%Influence of Aspect Ratio on Failure Patterns of Eco-composite Walls

    Institute of Scientific and Technical Information of China (English)

    侯莉娜; 卢俊龙; 黄炜; 田英侠

    2015-01-01

    生态复合墙体是生态复合墙结构的主要受力构件,其破坏模式不单一。高宽比是影响墙体破坏模式的重要因素之一。在不同高宽比生态复合墙体试验研究的基础上,介绍了墙体破坏机理及破坏模式,对比分析了不同高宽比墙体破坏模式及原因,建立非线性有限元模型,对不同高宽比墙体破坏模式进行分析。结果表明:生态复合墙体破坏模式本质上由复合墙板及边框柱的相对强弱决定,对于填充加气混凝土砌块生态复合墙体,当墙体高宽比<1.5时,墙体发生合理的剪切型破坏;对于填充秸秆泥坯砖生态复合墙体,当墙体高宽比<1.7时,墙体发生剪切型破坏。研究结果对于生态复合墙体的抗震优化设计具有一定的参考意义。%As the main bearing member of the eco-composite wall structure ,the eco-composite wall has various failure patterns .Aspect ratio is one of the most important parameters which affects on failure patterns of the walls .Based on the test results of the eco-composite walls with various aspect ratios ,the main failure processes and patterns of the walls were introduced .Contrast analysis on the reason of the walls’ failure patterns with different aspect ratios was conducted .A nonlinear finite element model was set up to study the influence of different aspect ratios on failure patterns of eco -com-posite walls .Results indicate that the failure patterns of the eco-composite walls are essentially determined by the relative strength of the eco-composite slabs and the side-frame columns .For the eco-composite walls with air-entraining concrete blocks ,when the aspect ratio < 1 .5 ,shear failure which is the reasonable failure mechanism occurs ;For the walls with straw mud blocks ,when < 1 .7 ,shear failure occurs .These findings will provide certain reference for optimal a seismic design of eco-composite wall structures .

  1. Processing and quantitative analysis of biodegradable polymers (PLLA and PCL) thermal bonding

    Science.gov (United States)

    Boutry, C. M.; Kiran, R.; Umbrecht, F.; Hierold, C.

    2010-08-01

    A quantitative analysis of the bond strength and microstructure integrity achieved when bonding the biodegradable polymers poly(L-lactide) (PLLA) and poly(ɛ-caprolactone) (PCL) has been performed using the response surface methodology. The respective influence of the bonding parameters (temperature, pressure, duration) on the bond strength and microchannel integrity was investigated. PLLA and PCL were identified as suitable candidates for packaging materials for bioelectronic circuits of conductive biodegradable polymers. For a future packaging application, the bonding parameters were adapted to optimize the bond strength; the estimated values for the bond strength and channel integrity that were predicted by the surface plots were 2.32 ± 0.26 MPa and 33.7 ± 12.9% for PLLA, and 0.81 ± 0.11 MPa and 50.9 ± 5.7% for PCL. These values were in good agreement with the experimentally determined bond strength of 2.00 ± 1.10 MPa (PLLA) and 0.67 ± 0.22 MPa (PCL) and deformation of 31.4 ± 7.0% (PLLA) and 52.9 ± 4.1% (PCL). Microchannels with an aspect ratio of 1:12.5 were successfully fabricated. The impact of the fabrication process on the PLLA and PCL chemical properties was also investigated through differential scanning calorimetry and gel permeation chromatography measurements. It was observed that the weight average molecular weight Mw decreases after each fabrication step, as much as 68% for PLLA and 59% for PCL. The strongest reduction was observed after the compression molding (above the melting temperature) which should be kept as short as possible. An annealing step allowed increasing the crystallinity and improved the overall polymer stiffness.

  2. Microcontact printing of proteins inside microstructures.

    Science.gov (United States)

    Foley, Jennifer; Schmid, Heinz; Stutz, Richard; Delamarche, Emmanuel

    2005-11-22

    Microfluidic devices are well suited for the miniaturization of biological assays, in particular when only small volumes of samples and reagents are available, short time to results is desirable, and multiple analytes are to be detected. Microfluidic networks (MFNs), which fill by means of capillary forces, have already been used to detect important biological analytes with high sensitivity and in a combinatorial fashion. These MFNs were coated with Au, onto which a hydrophilic, protein-repellent monolayer of thiolated poly(ethyleneglycol) (HS-PEG) was self-assembled, and the binding sites for analytes were present on a poly(dimethylsiloxane) (PDMS) sealing cover. We report here a set of simple methods to extend previous work on MFNs by integrating binding sites for analytes inside the microstructures of MFNs using microcontact printing (muCP). First, fluorescently labeled antibodies (Abs) were microcontact-printed from stamps onto planar model surfaces such as glass, Si, Si/SiO2, Au, and Au derivatized with HS-PEG to investigate how much candidate materials for MFNs would quench the fluorescence of printed, labeled Abs. Au coated with HS-PEG led to a fluorescence signal that was approximately 65% weaker than that of glass but provided a convenient surface for printing Abs and for rendering the microstructures of the MFNs wettable. Then, proteins were inked from solution onto the surface of PDMS (Sylgard 184) stamps having continuous or discontinuous micropatterns or locally inked onto planar stamps to investigate how the aspect ratio (depth:width) of microstructures and the printing conditions affected the transfer of protein and the accuracy of the resulting patterns. By applying a controlled pressure to the back of the stamp, Abs were accurately microcontact-printed into the recessed regions of MFNs if the aspect ratio of the MFN microstructures was lower than approximately 1:6. Finally, the realization of a simple assay between Abs (used as antigens

  3. Anisotropic ferromagnetic polymer: A first step for their implementation in microfluidic systems

    Directory of Open Access Journals (Sweden)

    Damien Le Roy

    2016-05-01

    Full Text Available Here we report on the influence of anisotropic microstructure on the performances of magnetically soft micro-patterns intended to integrate microfluidic systems. These micro-patterns are made of a composite obtained by mixing carbonyl iron particles with polydimethylsiloxane, which offers practical integration advantages. We investigated a wide range of magnetic particle loadings, from 10wt% to 83wt%, reaching magnetization as high as 630 kA/m. A homogeneous field was applied during the polymer’s cross-linking phase so that to obtain a 1D arrangement of the particles in the solidified polymer, along the field direction. Here we present the results obtained for square-based micro-pillars prepared under a magnetic field applied along one of its diagonal. We assessed the magnetic anisotropy owing to the particles’ spatial arrangement by comparing the magnetization processes along the two diagonals of the micro-pillar’s base. The magnetic susceptibilities along the two directions differ from a factor greater than three. The results can be described in terms of high aspect ratio and porous magnetic agglomerates.

  4. Deformation microstructures

    DEFF Research Database (Denmark)

    Hansen, N.; Huang, X.; Hughes, D.A.

    2004-01-01

    Microstructural characterization and modeling has shown that a variety of metals deformed by different thermomechanical processes follows a general path of grain subdivision, by dislocation boundaries and high angle boundaries. This subdivision has been observed to very small structural scales of...

  5. 不同高宽比的矩形空腔内流体浮升流动特性分析%Flow characteristics of free fluid driven by buoyancy in rectangular cavities with different aspect ratios

    Institute of Scientific and Technical Information of China (English)

    赵忠超; 张娇娇; 成华; 丰威仙

    2014-01-01

    In this paper, the mathematic model of buoyant lift flow in a rectangular cavity was developed by the dimensionless analysis.The effects of aspect ratio of the rectangular cavity on the heat convection were simulated and analyzed through this mathematic model under same working conditions.The results show that the aspect ra-tio of rectangular cavity has great effects on the character of buoyant lift flow and heat convection efficiency.With the aspect ratio increased, the transition layer of laminar flow has the tendency to decrease the Rayleigh number. When the Rayleigh number is kept constant, the average Nusselt number dramatically approaches the maximum and then decreases gradually.The eddy amount, intensity of buoyant flow and the average Nusselt number in-crease with the Rayleigh number.The maximum of average Nusselt number also has the tendency to move in the direction of smaller aspect ratio.%应用无量纲分析方法,建立了矩形空腔内流体浮升流动的数学模型,研究了相同工况下不同高宽比对其流动换热的影响。研究结果表明:不同高宽比对流体的浮升流动具有较大影响,随着高宽比的增大,空腔内流体流动的层流过渡层向Ra值减小的方向偏移,且当Ra数一定时,Numean随高宽比迅速地达到最大值后缓慢减小;随着Ra值的增加,空腔中涡的数量逐渐增加,浮升流动强度增大,Numean增大,且Numean的最大值向高宽比减小的方向偏移。

  6. Injection Molding of High Aspect Ratio Nanostructures

    DEFF Research Database (Denmark)

    Matschuk, Maria; Larsen, Niels Bent

    We present a process for injection molding of 40 nm wide and >100 nm high pillars (pitch: 200 nm). We explored the effects of mold coatings and injection molding conditions on the replication quality of nanostructures in cyclic olefin copolymer. We found that optimization of molding parameters...

  7. Damage evolution in nanoclay-reinforced polymers: A three-dimensional computational study

    DEFF Research Database (Denmark)

    Dai, Gaoming; Mishnaevsky, Leon

    2013-01-01

    Initiation and growth of microcracks in the nanoclay reinforced polymer composites were analyzed in numerical experiments using 3D micromechanical unit cell models. An original program code for the automatic generation of FE unit cells with multiple disk-shaped nanoplatelets, with high aspect ratio...

  8. Analytical and numerical techniques for predicting the interfacial stresses of wavy carbon nanotube/polymer composites

    NARCIS (Netherlands)

    Yazdchi, K.; Salehi, M.; Shokrieh, M.M.

    2009-01-01

    By introducing a new simplified 3D representative volume element for wavy carbon nanotubes, an analytical model is developed to study the stress transfer in single-walled carbon nanotube-reinforced polymer composites. Based on the pull-out modeling technique, the effects of waviness, aspect ratio, a

  9. Wind-tunnel investigation of longitudinal and lateral-directional stability and control characteristics of a 0.237-scale model of a remotely piloted research vehicle with a thick, high-aspect-ratio supercritical wing

    Science.gov (United States)

    Byrdsong, T. A.; Brooks, C. W., Jr.

    1980-01-01

    A 0.237-scale model of a remotely piloted research vehicle equipped with a thick, high-aspect-ratio supercritical wing was tested in the Langley 8-foot transonic tunnel to provide experimental data for a prediction of the static stability and control characteristics of the research vehicle as well as to provide an estimate of vehicle flight characteristics for a computer simulation program used in the planning and execution of specific flight-research mission. Data were obtained at a Reynolds number of 16.5 x 10 to the 6th power per meter for Mach numbers up to 0.92. The results indicate regions of longitudinal instability; however, an adequate margin of longitudinal stability exists at a selected cruise condition. Satisfactory effectiveness of pitch, roll, and yaw control was also demonstrated.

  10. Quantitative control of aspect ratios of hollow glass microspheres used for inertial confinement fusion targets%惯性约束聚变靶用空心玻璃微球纵横比的调控

    Institute of Scientific and Technical Information of China (English)

    漆小波; 高聪; 张占文; 李波; 魏胜

    2012-01-01

    为实现对惯性约束聚变(ICF)靶用空心玻璃微球(HGM)纵横比的调控,基于对干凝胶法制备HGM炉内成球过程的分析,建立了HGM纵横比的定量控制模型,实验研究了载气组分和压力对HGM直径和纵横比的影响.结果表明:通过调节载气中氩气分压可以控制熔融玻璃液泡的膨胀程度,从而定量控制最终HGM的直径和纵横比.但是,通过大幅度降低载气中的氩气分压来提高HGM半径和纵横比是不可行的.为提高载气的传热能力,确保HGM球形度、表面粗糙度和合格率满足ICF制靶的要求,必须在载气中添加一定分压的氦气.除部分极端工艺条件外,提出的HGM纵横比控制模型预测值与实验结果吻合良好.%To quantitatively control the aspect ratio of hollow glass microspheres (HGMs) for inertial confinement fusion (ICF) targets, a model was developed to describe the relationship between HGM aspect ratios and compositions and pressures- of furnace gas, based on the process analysis of transformation mechanism from gel microspheres to HGMs in the drop-tower furnace. Furthermore, the mean diameters and aspect ratios of HGM batches under different compositions and pressures of furnace gas were experimentally investigated. The results showed that the shell-blowing process from the initial molten glass bubble to the resulting liquid HGM could be regulated by the partial pressures of argon gas in the furnace atmosphere, and therefore the diameters and aspect ratios of HGMs could be quantitatively controlled by the partial pressure of argon gas in the furnace atmosphere. However, it was infeasible to produce large-diameter HGMs with target quality by simply reducing the partial pressures of argon gas to zero. To meet the stringent requirements of ICF targets, special furnace gases with enough partial pressures of helium gas must be used to obtain high quality HGMs with good sphericity, surface finish and high yield. Except for the extreme

  11. Atomic Oxygen Erosion Yield Dependence Upon Texture Development in Polymers

    Science.gov (United States)

    Banks, Bruce A.; Loftus, Ryan J.; Miller, Sharon K.

    2016-01-01

    The atomic oxygen erosion yield (volume of a polymer that is lost due to oxidation per incident atom) of polymers is typically assumed to be reasonably constant with increasing fluence. However polymers containing ash or inorganic pigments, tend to have erosion yields that decrease with fluence due to an increasing presence of protective particles on the polymer surface. This paper investigates two additional possible causes for erosion yields of polymers that are dependent upon atomic oxygen. These are the development of surface texture which can cause the erosion yield to change with fluence due to changes in the aspect ratio of the surface texture that develops and polymer specific atomic oxygen interaction parameters. The surface texture development under directed hyperthermal attack produces higher aspect ratio surface texture than isotropic thermal energy atomic oxygen attack. The fluence dependence of erosion yields is documented for low Kapton H (DuPont, Wilmington, DE) effective fluences for a variety of polymers under directed hyperthermal and isotropic thermal energy attack.

  12. PMMA microstructure as KrF excimer-laser LIGA material

    Science.gov (United States)

    Yang, Chii-Rong; Chou, Bruce C. S.; Chou, Hsiao-Yu; Lin, Frank H. S.; Kuo, Wen-Kai; Luo, Roger G. S.; Chang, Jer-Wei; Wei, Z. J.

    1998-08-01

    PMMA (polymethyl methacrylate) has been widely used as x-ray LIGA material for its good features of electrical acid plating of all common metals to industrial applications. Unlike the tough characteristics of polyimide in almost all alkaline and acid solutions, PMMA is easily removed in chemical etchants after electroplating process. For this reason, ablation- etching characteristics of PMMA material for 3D microstructures fabrication using a 248 nm KrF excimer laser were investigated. Moreover, the uses of the laminated dry film were also studied in this work. Experimental results show that PMMA microstructures can produce the near-vertical side- wall profile as the laser fluence up to 2.5 J/cm2. PMMA templates with high aspect ratio of around 25 were demonstrated, and the sequential electroplating processes have realized the metallic microstructures. Moreover, the microstructures fabricated in dry film show the perfect side- wall quality, and no residues of debris were found.

  13. Optimized SU-8 Processing for Low-Cost Microstructures Fabrication without Cleanroom Facilities

    Directory of Open Access Journals (Sweden)

    Vânia C. Pinto

    2014-09-01

    Full Text Available The study and optimization of epoxy-based negative photoresist (SU-8 microstructures through a low-cost process and without the need for cleanroom facility is presented in this paper. It is demonstrated that the Ultraviolet Rays (UV exposure equipment, commonly used in the Printed Circuit Board (PCB industry, can replace the more expensive and less available equipment, as the Mask Aligner that has been used in the last 15 years for SU-8 patterning. Moreover, high transparency masks, printed in a photomask, are used, instead of expensive chromium masks. The fabrication of well-defined SU-8 microstructures with aspect ratios more than 20 is successfully demonstrated with those facilities. The viability of using the gray-scale technology in the photomasks for the fabrication of 3D microstructures is also reported. Moreover, SU-8 microstructures for different applications are shown throughout the paper.

  14. PZT-Polymer 1-3 Composite for High Resolution Ultrasonic Imaging

    Institute of Scientific and Technical Information of China (English)

    Shinan Wang; Jing-Feng Li; Katsuhiro Wakabayashi; Masayoshi Esashi

    2000-01-01

    @@ A novel process has been developed to construct PZT-polymer 1-3 micro composites for high-resolution ultrasonic imaging for medical diagnosis. The key technology is the lost silicon (Si) mold process, by which PZT micro-rod arrays have been successfully fabricated with the finest rod size being 7 μm, the highest aspect ratio exceeding 15. Such fine-scale high-aspect-ratio PZT structures, which are essential for realizing high imaging performance, have never been realized by any conventional technique.

  15. Recrystallization microstructure modelling from superimposed deformed microstructure on microstructure model

    Indian Academy of Sciences (India)

    Prantik Mukhopadhyay

    2009-08-01

    The recovered cold rolled microstructure obtained from orientation image microstructure of Al–4%Mg–0.5%Mn alloy (AA5182 alloy) was superimposed on the grid of cellular automata based microstructure model. The Taylor factors of deformed/cold rolled orientations were considered as the driving force for recrystallization. The local development of recrystallized microstructure and texture were simulated with orientation dependent grain boundary mobility and compared with the experimental results.

  16. Bilaterally Microstructured Thin Polydimethylsiloxane Film Production

    DEFF Research Database (Denmark)

    Vudayagiri, Sindhu; Yu, Liyun; Hassouneh, Suzan Sager;

    2015-01-01

    Thin PDMS films with complex microstructures are used in the manufacturing of dielectric electro active polymer (DEAP) actuators, sensors and generators, to protect the metal electrode from large strains and to assure controlled actuation. The current manufacturing process at Danfoss Polypower A/...

  17. Surface microstructure replication in injection molding

    DEFF Research Database (Denmark)

    Theilade, Uffe Arlø; Hansen, Hans Nørgaard

    2006-01-01

    In recent years, polymer components with surface microstructures have been in rising demand for applications such as lab-on-a-chip and optical components. Injection molding has proven to be a feasible and efficient way to manufacture such components. In injection molding, the mold surface topogra...

  18. Flows in polymers, reinforced polymers and composites a multi-scale approach

    CERN Document Server

    Binetruy, Christophe; Keunings, Roland

    2015-01-01

    This book gives a detailed and practical introduction to complex flows of polymers and reinforced polymers as well as the flow of simple fluids in complex microstructures. Over the last decades, an increasing number of functional and structural parts, made so far with metals, has been progressively reengineered by replacing metallic materials by polymers, reinforced polymers and composites. The motivation for this substitution may be the weight reduction, the simpler, cheaper or faster forming process, or the ability to exploit additional functionalities. The present Brief surveys modern developments related to the multi-scale modeling and simulation of polymers, reinforced polymers, that involve a flowing microstructure and continuous fiber-reinforced composites, wherein the fluid flows inside a nearly stationary multi-scale microstructure. These developments concern both multi-scale modeling, defining bridges between the micro and macro scales - with special emphasis on the mesoscopic scale at which kinetic...

  19. 小展弦比飞翼标模纵航向气动特性低速实验研究%Low speed experiment on longitudinal and lateral aerodynamic characteristics of the low aspect ratio flying wing calibration model

    Institute of Scientific and Technical Information of China (English)

    吴军飞; 秦永明; 黄湛; 魏忠武; 贾毅

    2016-01-01

    对小展弦比飞翼气动布局外形,通过常规测力风洞实验方法得到其纵向气动特性和偏航控制特性,在分析其气动特性后,选取典型的状态采用 PIV 实验方法对其流动机理进行研究,研究表明小展弦比飞翼在较小的迎角下即出现前缘分离涡,随着迎角的增大,前缘分离涡强度增大,且逐渐往机体对称面方向移动,随着迎角进一步增大,分离涡变得不稳定,涡核开始摆动,最终破裂,破裂位置从后缘开始,逐渐前移。对小展弦比飞翼气动布局飞机的控制难点偏航控制进行研究,结果表明该飞翼布局模型在实验迎角范围内偏航方向是静稳定的,在小迎角下具有可操纵性,迎角大于6°后嵌入面处于破裂的前缘涡尾迹之中,操纵性降低。%longitudinal and lateral aerodynamic characteristics of the low aspect ratio flying wing calibration model are investigated in a low speed wind tunnel.Normal force measuring ex-periment is conducted to gain the longitudinal aerodynamic characteristics and yaw control charac-teristics,and the PIV test is also conducted to investigate the flow mechanism of the low aspect ratio flying wing.The results indicate that the leading-edge separation vortex appears on the wing’s spine surface when the attack angle is at 6 degree.The vortex intensity increases and the vortex core shifts to the symmetric plane of flying wing with the increase of attack angle.Increas-ing the attack angle further,the vortex core becomes unsteady and begins to oscillate,finally break entirely.The broken position shifts from the ending edge to the leading edge.Yaw control characteristics of low aspect ratio flying wing is also studied in this paper.The results indicate that the flying wing is static stabile at the test attack angle.When the attack angle is less than 6 degree,it is controllable in yaw direction.And when attack angle is more than 6 degree,the yaw control

  20. Biomimetic mushroom-shaped microfibers for dry adhesives by electrically induced polymer deformation.

    Science.gov (United States)

    Hu, Hong; Tian, Hongmiao; Li, Xiangming; Shao, Jinyou; Ding, Yucheng; Liu, Hongzhong; An, Ningli

    2014-08-27

    The studies on bioinspired dry adhesion have demonstrated the biomimetic importance of a surface arrayed with mushroom-shaped microfibers among other artificially textured surfaces. The generation of a mushroom-shaped microfiber array with a high aspect ratio and a large tip diameter remains to be investigated. In this paper we report a three-step process for producing mushroom-shaped microfibers with a well-controlled aspect ratio and tip diameter. First, a polymer film coated on an electrically conductive substrate is prestructured into a low-aspect-ratio micropillar array by hot embossing. In the second step, an electrical voltage is applied to an electrode pair composed of the substrate and another conductive planar plate, sandwiching an air clearance. The Maxwell force induced on the air-polymer interface by the electric field electrohydrodynamically pulls the preformed micropillars upward to contact the upper electrode. Finally, the micropillars spread transversely on this electrode due to the electrowetting effect, forming the mushroom tip. In this paper we have demonstrated a polymer surface arrayed with mushroom-shaped microfibers with a large tip diameter (3 times the shaft diameter) and a large aspect ratio (above 10) and provided the testing results for dry adhesion.

  1. Finite Element Analysis of Screw Conveyor of Horizontal Screw Centrifuge with Large Aspect Ratio%大长径比卧螺离心机螺旋输送器的有限元分析

    Institute of Scientific and Technical Information of China (English)

    杨钊; 黄维菊; 高志惠; 陈文梅

    2011-01-01

    应用SolidWorks对大长径比卧螺离心机的转鼓-螺旋输送器系进行了三维建模,采用与SolidWorks无缝衔接的有限元分析插件Simulation对其进行了有限元仿真。通过SolidWorks Simulation对螺旋输送器在正常工况下的整体结构进行了静力分析和模态分析,得到了螺旋输送器前5阶固有频率、应力分布和径向、轴向变形。研究了导程、转速和叶片厚度等主要参数的变化对螺旋输送器应力和变形的影响,以实现对离心机的优化。通过对大长径比卧螺离心机和普通卧螺离心机转鼓-螺旋输送器系的比较,在保证强度、刚度要求和相同生产能力的条件下,大长径比卧螺离心机具有更强的分离能力,螺旋输送器具有更好的应力和变形分布,并且临界转速也得到了提高。%The drum and screw conveyor of Horizontal Screw Centrifuge with Large Aspect Ratio are modeled by SolidWorks.FEA simulation was conducted by a finite element analysis software-Simulation embedded in SolidWorks,Mode and static monolithic structure of the screw conveyor under the normal working state was analysed.The 5 rank frequencies,stress distribution,the radial and axial deformation were obtained.Through changing parameters such as the lead 、the half cone angle rotational speed and the blade thickness,the paper investigates the impact of parameters on the strength,displacement and vibration form,in order to realize the optimization of centrifuge.The comparison between the common drum with the Large Aspect Ratio one was implemented,the paper finds that the former has a better separation capacity,better stress and deformation distribution of screw conveyor and the rotors has higher critical speed.

  2. 大长细比反射镜侧面支撑结构设计与分析%Design and Analysis of Side Support for Large Aspect Ratio Mirror

    Institute of Scientific and Technical Information of China (English)

    罗廷云; 张凤芹; 范斌

    2013-01-01

    With the application of wide field of view and lightweight TMA camera in high resolution imag-ing area, design of support structures for large aperture rectangular mirrors with large aspect ratio becomes a critical technique for space cameras in recent years. In this paper, mirror size reaches 986mm×246mm,in order to meet the requirement of high rigidity and high surface figure stability for large aspect ratio mirror, A flexible sup-port structure is designed with a method of combining theoretical research and finite element analysis. The results demonstrate that the first order frequency of the mirror component is 114.9Hz. The surface figure error(RMS value) is only 4.9nm under the condition of ground gravity and 2℃ temperature change. The mechanical test re-sults of the simulated part are consistent with the theoretical analysis. Analysis results demonstrate that design of the mirror support structure is effective, which can meet the requirement of space application.%随着近几年离轴三反(Three-Mirror Anastigmat, TMA)相机在大视场高分辨率成像领域的应用,大长细比反射镜的支撑技术成为离轴 TMA 相机研制的关键技术之一。文章研究的反射镜尺寸达到986mm×246mm,为了使大长细比反射镜的支撑结构同时满足高刚度和高面形稳定的要求,采用理论研究和有限元分析相结合的方法设计了一种侧面柔性支撑结构。分析结果表明,反射镜组件一阶频率达到114.9Hz,在重力和2℃温变耦合下综合面形变化均方根值只有4.9nm,工艺件的力学振动试验结果和仿真分析基本吻合,反射镜支撑结构设计合理,满足空间应用要求。

  3. Relationships between structure and rheology in polymer nanocomposites probed via X-ray scattering

    Science.gov (United States)

    Pujari, Saswati

    Polymer nanocomposites have received intense attention due to their potential for significantly enhanced polymer properties like mechanical strength, thermal stability, electrical conductivity, etc. Melt state processing of these materials exposes the nanofillers to complex flow fields, which can induce changes in nanocomposite microstructure, including particle dispersion and the orientation of anisotropic nanoparticles in the polymer matrix. Since nanocomposite properties are strongly correlated with both these structural features, it is essential to develop methods to characterize such microstructural changes. This thesis reports extensive measurements of mechanical rheology and particle orientation during flow of nanocomposites based on multi-walled carbon nanotubes, clays, and graphene nanosheets. Changes in orientation of anisotropic nanoparticles are manifested in x-ray scattering images collected during shear. In-situ studies of orientation are enabled by custom designed x-ray adapted shear cells and high energy synchrotron radiation at the Advanced Photon Source in Argonne National Laboratory where these experiments were conducted. Studies of flow induced orientation in model nanotube dispersions revealed increasing sample anisotropy with increasing shear rate across concentrations and aspect ratios. In dilute dispersions the orientation dynamics was dominated by flow induced aggregation/disaggregation of MWNTs, with anisotropy primarily attributed to individually dispersed nanotubes. In concentrated suspensions, sample anisotropy resulted from flow induced elastic deformation within entangled MWNT clusters. Release of elastic energy upon flow cessation resulted in an unexpected relaxation of induced anisotropy. These studies were followed with study of more complex, but, industrially relevant nanocomposites made with polypropylene as the dispersing matrix. The high viscosity of polypropylene makes dispersion of nanoparticles difficult, and hence a careful

  4. Magnetoelectric polymer nanocomposite for flexible electronics

    KAUST Repository

    Alnassar, M.

    2015-03-06

    This paper reports the fabrication and characterization of a new type of magnetoelectric polymer nanocomposite that exhibits excellent ferromagnetism and ferroelectricity simultaneously at room temperature. The multiferroic nanocomposite consists of high aspect ratio ferromagnetic iron nanowires embedded inside a ferroelectric co-polymer poly(vinylindene fluoride-trifluoroethylene), P(VDF-TrFE). The nanocomposite has been fabricated via a simple low temperature spin coating technique. Structural, ferromagnetic, ferroelectric, and magnetoelectric properties of the developed nanocomposite have been characterized. The nanocomposite films showed isotropic magnetic properties due to the random orientation of the iron nanowires inside the film. In addition, the embedded nanowires did not hinder the ferroelectric phase development of the nanocomposite. The developed nanocomposite showed a high magnetoelectric coupling response of 156 mV/cmOe measured at 3.1 kOe DC bias field. This value is among the highest reported magnetoelectric coupling in two phase particulate polymer nanocomposites.

  5. Influence of blend microstructure on bulk heterojunction organic photovoltaic performance.

    Science.gov (United States)

    Brabec, Christoph J; Heeney, Martin; McCulloch, Iain; Nelson, Jenny

    2011-03-01

    The performance of organic photovoltaic devices based upon bulk heterojunction blends of donor and acceptor materials has been shown to be highly dependent on the thin film microstructure. In this tutorial review, we discuss the factors responsible for influencing blend microstructure and how these affect device performance. In particular we discuss how various molecular design approaches can affect the thin film morphology of both the donor and acceptor components, as well as their blend microstructure. We further examine the influence of polymer molecular weight and blend composition upon device performance, and discuss how a variety of processing techniques can be used to control the blend microstructure, leading to improvements in solar cell efficiencies.

  6. Study on Static Test Technology for High-Aspect Ratio Wing of Full Scale Aircraft%全尺寸飞机大展弦比机翼静力试验技术研究

    Institute of Scientific and Technical Information of China (English)

    刘兴科; 刘冰; 张建锋

    2014-01-01

    In the bearing capability static test of wing structure,because of the high-aspect ratio, the large deformation will arouse load direction changed.Taking the full scale aircraft structure as research obj ect,a test loading technology is proposed,which can realize the extractive wing loading.The static test of a certain type aircraft structure solves the problems of large deforma-tion loading,which has great realistic significance and application value.%在大展弦比飞机的机翼承载能力试验中,试验加载方向会因其大变形发生变化。本文以全尺寸结构机翼为研究对象,提出一种试验加载技术,最大程度实现机翼载荷的准确施加。通过此静强度试验,很好地解决了机翼试验大变形加载问题,具有较大的现实意义和应用价值。

  7. Aeroelastic response for straight wing with high aspect ratio due to sharp edge gust%锐边突风对大展弦比机翼的气动弹性响应影响

    Institute of Scientific and Technical Information of China (English)

    刘伏虎; 马晓平

    2012-01-01

    基于Theodorsen非定常气动力理论,以大展弦比均匀直机翼为研究对象,建立了系统的气动弹性响应方程.选取二阶弯曲和二阶扭转模态,采用V-g法求解了系统的颤振速度.基于Kussner函数,建立了锐边突风系统模型,并推导了在弯曲和扭转模态阶数为Nw和Na下的系统状态方程,仿真研究了加入突风后系统的气动弹性响应.结果表明,加入突风后翼尖响应振幅增大.%Based on Theodorsen unsteady aerodynamics theory, the equation of aeroelastic response for straight wing with high aspect ratio is established. Flutter speed is determined for two bending modes and two torsional modes using V-g methods. The sharp edge gust system model is established and the system state equations are derived with Nw bending modes and Na torsional modes wing systems based on the function Kussner. The aeroelastic response of system shows that the amplitude oscillation becomes higher. The modeling method may offer reference for research of gust response.

  8. Self-organization and FORC-based magnetic characterization of ultra-high aspect ratio epitaxial Co nanostrips produced by oblique deposition on an ordered step-bunched silicon surface

    Science.gov (United States)

    Ognev, A. V.; Ermakov, K. S.; Samardak, A. Yu; Kozlov, A. G.; Sukovatitsina, E. V.; Davydenko, A. V.; Chebotkevich, L. A.; Stancu, A.; Samardak, A. S.

    2017-03-01

    Further development of microelectronics requires novel or improved technological approaches for device nanofabrication and functional properties characterization. In this paper, we studied the crystal structure and magnetic properties of epitaxial Co nanostrips with the average width of 32.6, 45.3, and 62.6 nm grown on a step-bunched Si(111)5.55 × 5.55-Cu/Cu surface. Technological conditions, under which the ultra-high aspect ratio (∼104) structurally solid, straight nanostrips of hcp-Co with crystallographic axis [0001] oriented along their long side can be grown, were determined. The dependence of the coercive force on the width of the nanostrips was demonstrated. Magnetization reversal through the transverse domain-wall nucleation and propagation in a Co nanostrip was defined with an analytical approach based on the Stoner–Wohlfarth model. Using the first-order reversal curve method, we analyzed the effect of nanostrip uniformity degree on magnetic behavior and the influence of the magnetostatic interactions on the coercive force of individual nanostrips.

  9. Heat transport by turbulent Rayleigh-B\\'enard convection for $\\Pra\\ \\simeq 0.8$ and $4\\times 10^{11} \\alt \\Ra\\ \\alt 2\\times10^{14}$: Ultimate-state transition for aspect ratio $\\Gamma = 1.00$

    CERN Document Server

    He, Xiaozhou; Bodenschatz, Eberhard; Ahlers, Guenter

    2012-01-01

    We report experimental results for heat-transport measurements by turbulent Rayleigh-B\\'enard convection in a cylindrical sample of aspect ratio $\\Gamma \\equiv D/L = 1.00$ ($D = 1.12$ m is the diameter and $L = 1.12$ m the height). They are for the Rayleigh-number range $4\\times10^{11} \\alt \\Ra \\alt 2\\times10^{14}$ and for Prandtl numbers \\Pra\\ between 0.79 and 0.86. For $\\Ra \\Ra_1^*$ the data rise above the classical-state power-law and show greater scatter. In analogy to similar behavior observed for $\\Gamma = 0.50$, we interpret this observation as the onset of the transition to the ultimate state. Within our resolution this onset occurs at nearly the same value of $\\Ra_1^*$ as it does for $\\Gamma = 0.50$. This differs from an earlier estimate by Roche {\\it et al.} which yielded a transition at $\\Ra_U \\simeq 1.3\\times 10^{11} \\Gamma^{-2.5\\pm 0.5}$. A $\\Gamma$-independent $\\Ra^*_1$ would suggest that the boundary-layer shear transition is induced by fluctuations on a scale less than the sample dimensions r...

  10. Synergistic effects of the aspect ratio of TiO2 nanowires and multi-walled carbon nanotube embedment for enhancing photovoltaic performance of dye-sensitized solar cells.

    Science.gov (United States)

    Ahn, Ji Young; Kim, Ji Hoon; Moon, Kook Joo; Park, So Dam; Kim, Soo Hyung

    2013-08-07

    The existence of numerous interfacial boundaries among TiO2 nanoparticles (NPs) accumulated in the photoelectrode layer of dye-sensitized solar cells (DSSCs) hinders the effective transport of photogenerated electrons to an electrode. Therefore, as a replacement for TiO2 NPs, one-dimensional TiO2 nanowires (NWs) can be suggested to provide pathways for fast electron transport by significantly reducing the number of interfacial boundaries. In order to provide direct evidence for the better performance of such longer TiO2 NWs than shorter TiO2 NWs, we examine the effect of the controlled aspect ratio of the TiO2 NWs randomly accumulated in the photoelectrode layer on the photovoltaic performance of DSSCs. It is clearly found that longer TiO2 NWs significantly improve the electron transport by reducing the TiO2/dye/electrolyte interfacial contact resistance. Furthermore, the embedment of multi-walled carbon nanotubes (MWCNTs) as an effective charge transfer medium in longer TiO2 NWs is proposed in this study to promote more synergistic effects, which lead to significant improvements in the photovoltaic properties of DSSCs.

  11. Low-Speed Investigation of a Full-Span Internal-Flow Jet-Augmented Flap on a High-Wing Model with a 35 deg Swept Wing of Aspect Ratio 7.0

    Science.gov (United States)

    Turner, Thomas R.

    1960-01-01

    An investigation of a full-span 17-percent-chord internal-flow jet-augmented flap on an aspect-ratio-7.0 wing with 35 deg of sweepback has been made in the Langley 300-MPH 7- by 10-foot tunnel. Blowing over the conventional elevator and blowing down from a nose jet were investigated as a means of trimming the large diving moments at the high momentum and high lift coefficients. The results of the investigation showed that the model with the horizontal tail 0.928 mean aerodynamic chord above the wing-chord plane was stable to the maximum lift coefficient. The large diving-moment coefficients could be trimmed either with a downward blowing nose jet or by blowing over the elevator. Neither the downward blowing nose jet nor blowing over the elevator greatly affected the static longitudinal stability of the model. Trimmed lift coefficients up to 8.8 with blowing over the elevator and up to 11.4 with blowing down at the nose were obtained when the flap was deflected 70 deg and the total momentum coefficients were 3.26 and 4.69.

  12. Low-speed aerodynamic performance of an aspect-ratio-10 supercritical-wing transport model equipped with a full-span slat and part-span and full-span double-slotted flaps

    Science.gov (United States)

    Morgan, H. L., Jr.

    1981-01-01

    An investigation was conducted in the Langley 4 by 7 Meter Tunnel to determine the static longitudinal and lateral directional aerodynamic characteristics of an advanced aspect ratio 10 supercritical wing transport model equipped with a full span leading edge slat as well as part span and full span trailing edge flaps. This wide body transport model was also equipped with spoiler and aileron roll control surfaces, flow through nacelles, landing gear, and movable horizontal tails. Six basic wing configurations were tested: (1) cruise (slats and flaps nested), (2) climb (slats deflected and flaps nested), (3) part span flap, (4) full span flap, (5) full span flap with low speed ailerons, and (6) full span flap with high speed ailerons. Each of the four flapped wing configurations was tested with leading edge slat and trailing edge flaps deflected to settings representative of both take off and landing conditions. Tests were conducted at free stream conditions corresponding to Reynolds number of 0.97 to 1.63 x 10 to the 6th power and corresponding Mach numbers of 0.12 to 0.20, through an angle of attack range of 4 to 24, and a sideslip angle range of -10 deg to 5 deg. The part and full span wing configurations were also tested in ground proximity.

  13. Polymer films

    Science.gov (United States)

    Granick, Steve; Sukhishvili, Svetlana A.

    2008-12-30

    A film contains a first polymer having a plurality of hydrogen bond donating moieties, and a second polymer having a plurality of hydrogen bond accepting moieties. The second polymer is hydrogen bonded to the first polymer.

  14. Polymer Composites Reinforced by Nanotubes as Scaffolds for Tissue Engineering

    Directory of Open Access Journals (Sweden)

    Wei Wang

    2014-01-01

    Full Text Available The interest in polymer based composites for tissue engineering applications has been increasing in recent years. Nanotubes materials, including carbon nanotubes (CNTs and noncarbonic nanotubes, with unique electrical, mechanical, and surface properties, such as high aspect ratio, have long been recognized as effective reinforced materials for enhancing the mechanical properties of polymer matrix. This review paper is an attempt to present a coherent yet concise review on the mechanical and biocompatibility properties of CNTs and noncarbonic nanotubes/polymer composites, such as Boron nitride nanotubes (BNNTs and Tungsten disulfide nanotubes (WSNTs reinforced polymer composites which are used as scaffolds for tissue engineering. We also introduced different preparation methods of CNTs/polymer composites, such as in situ polymerization, solution mixing, melt blending, and latex technology, each of them has its own advantages.

  15. A model study of the role of workfunction variations in cold field emission from microstructures with inclusion of field enhancements

    Science.gov (United States)

    Qiu, H.; Joshi, R. P.; Neuber, A.; Dickens, J.

    2015-10-01

    An analytical study of field emission from microstructures is presented that includes position-dependent electric field enhancements, quantum corrections due to electron confinement and fluctuations of the workfunction. Our calculations, applied to a ridge microstructure, predict strong field enhancements. Though quantization lowers current densities as compared to the traditional Fowler-Nordheim process, strong field emission currents can nonetheless be expected for large emitter aspect ratios. Workfunction variations arising from changes in electric field penetration at the surface, or due to interface defects or localized screening, are shown to be important in enhancing the emission currents.

  16. A study on nanocomposites made of a conducting polymer and metallic nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Mohammed Ahmed Khalil, Rania [Nanochemistry and Nanoengineering, Institute for Materials Science, Faculty of Engineering, Christian-Albrechts-University of Kiel (Germany); Multicomponent Materials, Institute for Materials Science, Faculty of Engineering, Christian-Albrechts-University of Kiel (Germany); Abdelaziz Mahmoud Abdelaziz, Ramzy [Nanochemistry and Nanoengineering, Institute for Materials Science, Faculty of Engineering, Christian-Albrechts-University of Kiel (Germany); Strunkus, Thomas; Faupel, Franz [Multicomponent Materials, Institute for Materials Science, Faculty of Engineering, Christian-Albrechts-University of Kiel (Germany); Elbahri, Mady [Nanochemistry and Nanoengineering, Institute for Materials Science, Faculty of Engineering, Christian-Albrechts-University of Kiel (Germany); Helmholtz-Zentrum Geesthacht GmbH, Institute of Polymer Research, Nanochemistry and Nanoengineering (Germany)

    2011-07-01

    Conducting polymers offer a unique combination of properties that makes them attractive materials for many electronic applications. PEDOT:PSS is one of the most successful conductive materials which is considered to be highly stable and resisting degradation under typical ambient conditions. In this study, we have prepared two sets of conducting polymer nano-composites. The first set is composed of PEDOT:PSS doped with different aspect ratios of gold nanorod and the other one is PEDOT:PSS doped with different sizes of gold nanosphere. The chemical reduction method was used for preparing the nano-particles. Indeed, gold nanorods and nanosphere which exhibit tunable absorption as a function of their size and aspect ratio, respectively, have tuned the absorption coefficient for PEDOT: PSS. The nature of the dopant as well as the degree of doping has played a significant role in the improvement of the electrical conductivity of conducting polymer.

  17. Homogeneity of microstructure and Vickers hardness in cold closed-die forged spur-bevel gear of 20CrMnTi alloy

    Institute of Scientific and Technical Information of China (English)

    DONG Li-ying; LAN Jian; ZHUANG Wu-hao

    2015-01-01

    Cold closed-die forging is a suitable process to produce spur-bevel gears due to its advantages, such as saving materials and time, reducing costs, increasing die life and improving the quality of the product. The homogeneity of microstructure of cold closed-die forged gears can highly affect their service performance. The homogeneity of microstructure and Vickers hardness in cold closed-die forged gear of 20CrMnTi alloy is comprehensively studied by using optical microscopy and Vickers hardness tester. The results show that the distribution homogeneity of the aspect ratio of grain and Vickers hardness is the same. In the circumferential direction of the gear tooth, the distribution of the aspect ratio of grain and Vickers hardness is inhomogeneous and they gradually decrease from the surface to the center of the tooth. In the radial direction, the distribution of the aspect ratio of grain and Vickers hardness is inhomogeneous on the surface of the gear tooth; while it is relatively homogeneous in the center of the gear tooth. In the axial direction of the gear tooth, the distribution of the aspect ratio of grain and Vickers hardness is relatively homogeneous from the small-end to the large-end of the gear tooth.

  18. POROUS MEMBRANE TEMPLATED SYNTHESIS OF POLYMER PILLARED LAYER

    Institute of Scientific and Technical Information of China (English)

    Zhong-wei Niu; Dan Li; Zhen-zhong Yang

    2003-01-01

    The anodic porous alumina membranes with a definite pore diameter and aspect ratio were used as templates to synthesize polymer pillared layer structures. The pillared polymer was produced in the template membrane pores, and the layer on the template surfaces. Rigid cured epoxy resin, polystyrene and soft hydrogel were chosen to confirm the methodology. The pillars were in the form of either tubes or fibers, which were controlled by the alumina membrane pore surface wettability. The structural features were confirmed by scanning electron microscopy results.

  19. A conducting polymer artificial muscle with 12% linear strain

    DEFF Research Database (Denmark)

    Bay, Lasse; West, Keld; Sommer-Larsen, P.;

    2003-01-01

    in a freely suspended polymer foil in response to a potential change and it includes attention to the composition of the polymer, to the synthesis conditions, and involves microstructuring of the polymer. As such, an analysis of the influence of the alkyl chain length on the properties of PPy doped with ABSs...

  20. Preparation and Cytotoxicity of High-aspect-ratio Gold Nanorods at Single Cell Level%大长径比金纳米棒的合成及其单细胞毒性研究

    Institute of Scientific and Technical Information of China (English)

    周海英; 周瑞; 熊斌; 何彦

    2012-01-01

    利用三步晶种生长法合成长径比约为14的大长径比金纳米棒(GNR),利用巯基十一酸(MUDA)对金纳米棒表面进行了生物适应性修饰,并在宏观水平上研究了修饰前后的金纳米棒在对细胞活性的影响.利用单细胞方法分别考察了修饰后的纳米金棒对细胞贴壁过程、增殖速率、细胞内ROS以及骨架排布的影响.虽然MTT细胞活性结果显示内吞后的金纳米棒对细胞无毒,但单细胞毒性分析方法发现,不同浓度纳米金棒对早期贴壁过程有较小的影响,且内吞的纳米金棒在一定程度上促进了细胞的增殖,而高浓度下纳米金棒引起了细胞内ROS含量的升高,并破坏了细胞内骨架纤维排布.本研究建立了用单细胞行为分析纳米颗粒对细胞毒性的方法,证明了以往仅仅利用MTT等宏观手段分析纳米材料生物适应性是不足的.纳米材料在生物医学领域的进一步应用还应考虑单细胞及分子水平上的毒性效应.%We have synthesized high-aspect-ratio gold nanorods (GNR) by using a three-step seed-mediated growth method. The aspect ratio of the GNRs is approximately 14. The modification of the GNRs was achieved by replacing the CTAB molecules on the surface of gold nanorods with the 11-mercaptoundecanoic (MUDA) molecules. The cytotoxicity of the as-prepared GNRs and their effects on endocytosis, adhesion, proliferation, intracellular reactive oxygen species (ROS) level and cytoskeleton of the cells were studied. Interestingly, by using the 3-(4, 5-dimethylthiazol-2-yl) 2,5-diphenyl-tetrazolium bromide (MTT) assay, the GNRs did not show a significant toxicity to HeLa cells. However, single cell viability assays showed that GNR uptake could influence the cell adhesion at the early stage, though the effect was not much, and the cell proliferation was promoted to some degree. Moreover, large amounts of GNR uptake will lead to increased intracellular ROS level and impaired the cell skeleton.