Sample records for ash flow temperature

  1. The Influence Of Calcite On The Ash Flow Temperature For Semi-Anthracite Coal From Donbas District

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    Čarnogurská Mária


    Full Text Available This paper presents the results of research focused on the lowering of ash flow temperature at semianthracite coal from Donbas district by means of additive (calcite dosing. Ash fusion temperatures were set for two coal samples (A, B and for five various states (samples of ash without any additives, with 1%, with 3%, with 5% and with 7% of the additive in total. The macroscopicphotographic method was used for identifying all specific temperatures. Obtained outputs prove that A type coal has a lower value of sphere temperature than B type coal in the whole scope of percentage representation of the additive. The flow temperature dropped in total from 1489 °C to 1280 °C, i.e. by 14% during the test of coal of type A with 7% of the additive; while it was near 10% for coal of type B (from 1450 °C to 1308 °C. Numerical simulations of the process showed that it is not effective to add an additive with a grain size lower than 280 μm by means of wastevapour burners.

  2. High-temperature, large-volume, lavalike ash-flow tuffs without calderas in southwestern Idaho (United States)

    Ekren, E.B.; McIntyre, David H.; Bennett, Earl H.


    Rhyolitic rocks were erupted from vents in and adjacent to the Owyhee Mountains and Owyhee Plateau of southwestern Idaho from 16 m.y. ago to about 10 m.y. ago. They were deposited on a highly irregular surface developed on a variety of basement rocks that include granitic rocks of Cretaceous age, quartz latite and rhyodacite tuffs and lava flows of Eocene age, andesitic and basaltic lava flows of Oligocene age, and latitic and basaltic lava flows of early Miocene age. The rhyolitic rocks are principally welded tuffs that, regardless of their source, have one feature in common-namely internal characteristics indicating en-masse, viscous lavalike flowage. The flowage features commonly include considerable thicknesses of flow breccia at the bases of various cooling units. On the basis of the tabular nature of the rhyolitic deposits, their broad areal extents, and the local preservation of pyroclastic textures at the bases, tops, and distal ends of some of the deposits, we have concluded that the rocks were emplaced as ash flows at extremely high temperatures and that they coalesced to liquids before final emplacement and cooling. Temperatures of l090?C and higher are indicated by iron-titanium oxide compositions. Rhyolites that are about 16 m.y. old are preserved mostly in the downdropped eastern and western flanks of the Silver City Range and they are inferred to have been erupted from the Silver City Range. They rarely contain more than about 2 percent phenocrysts that consist of quartz and subequal amounts of plagioclase and alkali feldspar; commonly, they contain biotite, and they are the only rhyolitic rocks in the area to do so. The several rhyolitic units that are 14 m.y. to about 10 m.y. old contain only pyroxene-principally ferriferous and intermediate pigeonites-as mafic constituents. The rhyolites of the Silver City Range comprise many cooling units, none of which can be traced for great distances. Rocks erupted from the Owyhee Plateau include two sequences

  3. Correlation between the critical viscosity and ash fusion temperatures of coal gasifier ashes

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    Hsieh, Peter Y. [National Energy Technology Lab. (NETL), Albany, OR (United States); Kwong, Kyei-Sing [National Energy Technology Lab. (NETL), Albany, OR (United States); Bennett, James [National Energy Technology Lab. (NETL), Albany, OR (United States)


    Coal gasification yields synthesis gas, an important intermediate in chemical manufacturing. It is also vital to the production of liquid fuels through the Fischer-Tropsch process and electricity in Integrated Gasification Combined Cycle power generation. Minerals naturally present in coal become molten in entrained-flow slagging gasifiers. Molten coal ash slag penetrates and dissolves refractory bricks, leading to costly plant shutdowns. The extent of coal ash slag penetration and refractory brick dissolution depends on the slag viscosity, the gasification temperature, and the composition of slag and bricks. Here, we measured the viscosity of several synthetic coal ash slags with a high-temperature rotary viscometer and their ash fusion temperatures through optical image analysis. We made all measurements in a carbon monoxide-carbon dioxide reducing atmosphere that approximates coal gasification conditions. Empirical correlation models based on ash fusion temperatures were used to calculate critical viscosity temperatures based on the coal ash compositions. These values were then compared with those obtained from thermodynamic phase-transition models. Finally, an understanding of slag viscosity as a function of ash composition is important to reducing refractory wear in slagging coal gasifiers, which would help to reduce the cost and environmental impact of coal for chemical and electricity production.

  4. Gasification of high ash, high ash fusion temperature bituminous coals

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    Liu, Guohai; Vimalchand, Pannalal; Peng, WanWang


    This invention relates to gasification of high ash bituminous coals that have high ash fusion temperatures. The ash content can be in 15 to 45 weight percent range and ash fusion temperatures can be in C. to C. range as well as in excess of C. In a preferred embodiment, such coals are dealt with a two stage gasification process--a relatively low temperature primary gasification step in a circulating fluidized bed transport gasifier followed by a high temperature partial oxidation step of residual char carbon and small quantities of tar. The system to process such coals further includes an internally circulating fluidized bed to effectively cool the high temperature syngas with the aid of an inert media and without the syngas contacting the heat transfer surfaces. A cyclone downstream of the syngas cooler, operating at relatively low temperatures, effectively reduces loading to a dust filtration unit. Nearly dust- and tar-free syngas for chemicals production or power generation and with over 90%, and preferably over about 98%, overall carbon conversion can be achieved with the preferred process, apparatus and methods outlined in this invention.

  5. Behaviour of peat ash in high-temperature processes

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    Moilanen, A.


    The ash-forming constituents are in peat as minerals and bound in the organic framework. The kind of binding is dependent on peat type, plant species composition, acidity of the peatland, etc. Studies carried out with brown coal have indicated that the forms of ash occurrence in the fuel have an influence on the slagging ehaviour of ash in the process. The behaviour is also dependent on the reactor type and conditions in the reactor, for example, on the composition of gas atmosphere, on temperature, and gas flows. For example, the reducing conditions affect especially the occurrence of iron in different oxidation degrees in gasification, and this affects further the melting behaviour of ash. In brown coal gasification, as much as a third of the iron content was found to be reduced to metallic iron in the fluid-bed gasifier. To forecast the slagging behaviour of ash, the melting temperatures of ash are measured. Fouling or partial melting of ash cannot always be monitored with standard measuring methods, as these phenomena may start already at temperatures 200 deg C lower than the lowest melting temperature. THey can be studied for example with thermochemical methods.

  6. False deformation temperatures for ash fusibility associated with the conditions for ash preparation

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    Wall, T.F.; Gupta, S.K.; Gupta, R.P.; Sanders, R.H.; Creelman, R.A.; Bryant, G.W. [University of Newcastle, Callaghan, NSW (Australia). Cooperative Research Centre for Black Coal Utilization, Dept. of Chemical Engineering


    A study was made to investigate the fusibility behaviour of coal ashes of high ash fusion temperatures. Coals and ashes formed in the boiler were sampled in several Australian power stations, with laboratory ashes being prepared from the coals. The laboratory ashes gave lower values for the deformation temperature (DT) than the combustion ashes when the ash had low levels of basic oxide components. Thermo-mechanical analysis, quantitative X-ray diffraction and scanning electron microscopy were used to establish the mechanisms responsible for the difference. Laboratory ash is finer than combustion ash and it includes unreacted minerals (such as quartz, kaolinite and illite) and anhydrite (CaSO{sub 4}). Fusion events which appear to be characteristic of reacting illite, at temperatures from 900 to 1200{degree}C, were observed for the laboratory ashes, these being associated with the formation of melt phase and substantial shrinkage. The combustion ashes did not contain this mineral and their fusion events were observed at temperatures exceeding 1300{degree}C. The low DTs of coal ashes with low levels of basic oxides are therefore a characteristic of laboratory ash rather than that found in practical combustion systems. These low temperatures are not expected to be associated with slagging in pulverised coal fired systems. 10 refs., 3 figs., 2 tabs.

  7. Fly ash particles spheroidization using low temperature plasma energy (United States)

    Shekhovtsov, V. V.; Volokitin, O. G.; Kondratyuk, A. A.; Vitske, R. E.


    The paper presents the investigations on producing spherical particles 65-110 μm in size using the energy of low temperature plasma (LTP). These particles are based on flow ash produced by the thermal power plant in Seversk, Tomsk region, Russia. The obtained spherical particles have no defects and are characterized by a smooth exterior surface. The test bench is designed to produce these particles. With due regard for plasma temperature field distribution, it is shown that the transition of fly ash particles to a state of viscous flow occurs at 20 mm distance from the plasma jet. The X-ray phase analysis is carried out for the both original state of fly ash powders and the particles obtained. This analysis shows that fly ash contains 56.23 wt.% SiO2; 20.61 wt.% Al2O3 and 17.55 wt.% Fe2O3 phases that mostly contribute to the integral (experimental) intensity of the diffraction maximum. The LTP treatment results in a complex redistribution of the amorphous phase amount in the obtained spherical particles, including the reduction of O2Si, phase, increase of O22Al20 and Fe2O3 phases and change in Al, O density of O22Al20 chemical unit cell.

  8. Using thermal remanent magnetisation (TRM) to distinguish block and ash flow and debris flow deposits, and to estimate their emplacement temperature: 1991-1995 lava dome eruption at Mt. Unzen Volcano, Japan (United States)

    Uehara, D.; Cas, R. A. F.; Folkes, C.; Takarada, S.; Oda, H.; Porreca, M.


    The 1991-1995 Mt. Unzen eruption (Kyushu, Japan) produced 13 lava domes, approximately 9400 block and ash pyroclastic flows (BAF) resulting from lava dome collapse events and syn- and post-dome collapse debris flow (DF) events. In the field, it can be very difficult to distinguish from field facies characteristics which deposits are primary hot BAF, cold BAF or rock avalanche, or secondary DF deposits. In this study we use a combination of field observations and thermal remanent magnetisation (TRM) analysis of juvenile, lava dome derived clasts from seven deposits of the 1991-1995 Mt. Unzen eruption in order to distinguish between primary BAF deposits and secondary DF deposits and to determine their emplacement temperature. Four major TRM patterns were identified: (1) Type I: clasts with a single magnetic component oriented parallel to the Earth's magnetic field at time and site of emplacement. This indicates that these deposits were deposited at very high temperature, between the Curie temperature of magnetite (~ 540 °C) and the glass transition temperature of the lava dome (~ 745 °C). These clasts are found in high temperature BAF deposits. (2) Type II: clasts with two magnetic components of magnetisation. The lower temperature magnetic components are parallel to the Earth's magnetic field at time of the Unzen eruption. Temperature estimations for these deposits can range from 80 to 540 °C. We found this paleomagnetic behaviour in moderate temperature BAF or warm DF deposits. (3) Type III: clasts with three magnetic components, with a lower temperature component oriented parallel to the Earth's magnetic field at Unzen. The individual clast temperatures estimated for this kind of deposit are usually less than 300 °C. We interpret this paleomagnetic behaviour as the effect of different thermal events during their emplacement history. There are several interpretations for this paleomagnetic behaviour including remobilisation of moderate temperature BAF, warm DF

  9. The Rheology of Vegetative Ash-laden Debris Flows (United States)

    Burns, K. A.; Gabet, E.


    There is mounting observational evidence that vegetative ash created in a forest fire may play a major role in reducing infiltration and leads to the generation of debris flows on these burned hillslopes. A viscometer was used to measure the viscosity of ash slurries of varying concentrations, as well as slurries containing both fine- grained clastic sediment (sand and silt sized) and vegetative ash at varying concentrations. Initial results from these experiments indicate that increasing the concentration of ash increases effective viscosity of the slurry. Increasing the ash concentration by 5% increases the effective viscosity of the slurry by 10-50% over a range of shear rates. Also, ash-only slurries appear to shear thin with increasing shear rate at all concentrations. For example, with a 60% ash concentration, increasing the shear rate from 5/s to 40/s reduces the effective viscosity by 90%. For the mixed ash and fine-grained sediment slurries, increasing the percentage of ash relative to the percentage of clastic sediment dramatically increases the viscosity of the slurry even though the ash and finest-grained sediment are approximately the same size. A 50% concentration slurry containing only silt-sized clastic particles has a 40-70% lower effective viscosity than a slurry of the same concentration containing only ash particles. Therefore, the ash particles behave differently than clastic sediment particles.

  10. Ash fusion temperatures and the transformations of coal ash particles to slag

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    Gupta, S.K.; Wall, T.F.; Creelman, R.A.; Gupta, R.P. [University of Newcastle, Newcastle, NSW (Australia). CRC for Black Coal Utilisation


    A mechanistic study is detailed in which coal ash is heated with its shrinkage measured continuously up to a temperature of 1600{degree}C. The temperature corresponding to the rapid rate of shrinkage correspond to the formation of eutectics identified on phase diagrams. Samples were therefore heated to these temperatures, cooled rapidly and examined using a scanning electron microscope (SEM) to identify the associated chemical and physical changes. The progressive changes in the range of chemical composition (from SEM), the extent of undissolved ash particles and porosity were then quantified and related to homogenisation, viscosity and ash fusion mechanisms. Alternate ash fusion temperatures based on different levels of shrinkage have also been suggested to characterise the ash deposition tendency of the coals. 13 refs., 9 figs.

  11. Ash fusion temperatures and the transformations of coal ash particles to slag

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    Wall, T.F.; Creelman, R.A.; Gupta, R.; Gupta, S. [Univ. of Newcastle (Australia)


    A mechanistic study is detailed in which coal ash is heated with the shrinkage and electrical resistance measured continuously up to a temperature of 1600{degrees}C. The temperatures corresponding to rapid rates of shrinkage are shown to correspond to the formation of eutectics identified on phase diagrams. Samples where therefore heated to these temperatures, cooled rapidly and examined with an SEM to identify the associated chemical and physical changes. The progressive changes in the range of chemical analysis (from SEM), the extent of undissolved ash particles and porosity are then quantified and related to the shrinkage events and standard ash fusion temperatures.

  12. Effect of refractory agent on ash fusibility temperatures of briquette

    Institute of Scientific and Technical Information of China (English)

    Guo-xing CUI; Kui HUANG; Ming-sui LIN


    To solve the problem of the low ash fusion point of briquette,this paper reported that the ash fusibility temperatures can be elevated by changing ash ingredients through blending refractory agents in briquette ash,which will create favorable conditions for moving bed continuous gasification of briquette with oxygen-rich air.The effects of Al2O3,SiO2,kaolin,dry powder and bentonite on ash fusibility temperatures were studied,based upon the relationship between briquette ash components and ash fusibility.The results show that the increasing of ash fusibility temperatures by adding the same amount (11%,w)of refractory agents follows the sequence of SiO2,bentonite,dry powder,kaolin,Al2O3,with the softening temperatures beingelevated by 37.2,57.6,60.4,82.6 and 104.4 ℃.With the same ratio of SiO2/Al2O3 in briquette,adding the Al2O3 component is more effective than SiO2 for raising ash fusibility temperatures.In this paper,inexpensive kaolin and bentonite rich in Al2O3 are found to be better refractory agents,and the suitable adding quantities are 9% and 11%,respectively.

  13. Ash fusion temperatures and the transformations of coal ash particles to slag

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    Gupta, S.; Wall, T.F.; Creelman, R.A.; Gupta, R. [Univ. of Newcastle, Callaghan (Australia)


    A mechanistic study is detailed in which coal ash is heated with its shrinkage measured continuously up to a temperature of 1600{degrees}C. The temperatures corresponding to the rapid rate of shrinkage are shown to correspond to the formation of eutectics identified on phase diagrams. Samples were therefore heated to these temperatures, cooled rapidly and examined with an SEM to identify the associated chemical and physical changes. The progressive changes in the range of chemical analysis (from SEM), the extent of undissolved ash particles and porosity were then quantified and related to homogenization, viscosity and ash fusion mechanisms.

  14. Low temperature magnetic characterisation of fire ash residues (United States)

    Peters, C.; Thompson, R.; Harrison, A.; Church, M. J.

    Fire ash is ideally suited to mineral magnetic studies. Both modern (generated by controlled burning experiments) and archaeological ash deposits have been studied, with the aim of identifying and quantifying fuel types used in prehistory. Low temperature magnetic measurements were carried out on the ash samples using an MPMS 2 SQUID magnetometer. The low temperature thermo-remanence cooling curves of the modern ash display differences between fuel sources. Wood and well-humified peat ash display an increase in remanence with cooling probably related to a high superparamagnetic component, consistent with room temperature frequency dependent susceptibilities of over 7%. In comparison fibrous-upper peat and peat turf display an unusual decrease in remanence, possibly due to an isotropic point of grains larger than superparamagnetic in size. The differences have been successfully utilised in unmixing calculations to quantify fuel components within four archaeological deposits from the Northern and Western Isles of Scotland.

  15. Ash fusion temperatures and their association with the transformations of coal ash particles to slag

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    Gupta, S.K.; Wall, T.F.; Gupta, R.P. [Cooperative Research Centre for Black Coal Utilisation, Newcastle, NSW (Australia); Creelman, R.A. [Creelman (R.A.) and Associates, Sydney, NSW (Australia)


    Ash deposition on furnace walls in PF (pulverized fuel) furnaces is called slagging when it occurs in the high temperature areas of furnaces directly exposed to flame radiation and fouling in other regions such as tubes in the convection section of the boiler. There are well documented shortcomings of certain approaches relating to their uncertainties as predictive tools for plant performance such as poor repeatability and re-producibility of ash fusion measurements. The nature of physical and chemical changes occurring during melting of coal ash has been investigated in the current study to provide an alternative procedure to the ash fusion test. Shrinkage measurements are frequently used in metallurgy and ceramic science to study the physical properties of materials at high temperatures. The output of this experiment provides three to four `peaks` (maximum rate of shrinkage with temperature) of different intensity and at different temperatures which are related to melting characteristics of the sample. It was concluded that shrinkage extents exceeding 50 percent indicated that the effect of the ash particle size is of secondary importance compared to ash chemistry in determining shrinkage levels, with fine particles giving rapid shrinkage events 10 degrees C lower in temperature. (author). 7 figs., refs.


    Experimental studies were performed to investigate the interactions of elemental mercury vapor with entrained fly ash particles from coal combustion in a flow reactor. The rate of transformation of elemental mercury on fly ash particles was evauated over the temperature range fro...

  17. Pyritic ash-flow tuff, Yucca Mountain, Nevada -- A discussion

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    Weiss, S.I.; Larson, L.T.; Noble, D.C. [Univ. of Nevada, Reno, NV (United States)


    Textural and mineralogic evidence exists for at least one episode of widespread hydrothermal alteration of volcanic rocks deep in Yucca Mountain, Nevada. Despite this evidence, Castor et al. infer that most of the pyrite found in tuffs at Yucca Mountain was introduced as ejecta (lithic fragments) incorporated during the eruptions of the tuffs, rather than by in-situ hydrothermal activity. Their conclusions appear to be based on their observation that most of the pyrite resides in unaltered to variably altered and veined lithic fragments, whereas pyrite-bearing veins are absent in the tuff matrix, titanomagnetite and mafic phenocrysts in the matrix are generally not replaced by pyrite, and feldspar phenocrysts in the pyritic tuff matrix are generally unaltered. Castor et al. dismiss the much smaller quantities of pyrite disseminated in the tuff matrix, including relatively rare pyritized hornblende and biotite grains, as xenolithic as well. The pyritic tuffs belong to large-volume, subalkaline rhyolite ash-flow units (ca. > 150 to 250 km{sup 3} each). The interpretation of Castor et al. has broad implications for the temperature, fO{sub 2} and fS{sub 2} of major ash flow eruptions. Pyrite origin also bears on the nature of past fluid flow and water-rock reactions at Yucca Mountain, which in turn are important factors in assessing the potential for currently undiscovered mineral resources in the area of the proposed nuclear waste repository. We have studied core and cuttings from the same drill holes studied by Castor et al., as well as other drill holes. It is our contention that the inconsistent lateral and stratigraphic distribution of the pyrite, textural features of the pyrite, and phase stability considerations are incompatible with the {open_quotes}lithic{close_quotes} origin of Castor et al., and are more reasonably explained by in-situ formation from hydrothermal fluids containing low, but geochemically significant, concentrations of reduced sulfur.

  18. 煤灰熔融黏温特性及对气流床气化的适应性%Characteristic of cohesiveness-temperature of coal molten ash and its adaptability to entrained flow gasifier

    Institute of Scientific and Technical Information of China (English)

    周志杰; 李德侠; 刘霞; 于广锁


    Based on CaO and Fe2O3 content in coal ash, 21 typical Chinese coal samples are categorized into low-calcium-low-ferric, medium-calcium-medium-ferric, medium-calcium-high-ferric, high-calcium-low-ferric, and high-calcium-high-ferric. The characteristic of cohesiveness-temperature of coal molten ash was measured by a high-temperature rotary viscometer, Factsage. The thermodynamic equilibrium of their molten states was calculated and the relationship between liquid molten slag, solid mineral crystal and viscosity of the slag was studied. Influences of initial SiO2/Al2O3 mass ratio, solid crystals and composition of liquid-slag on the behavior of coal ash melting and characteristic of cohesiveness-temperature of the molten slag were analyzed and discussed in detail. A simple and practical method based on ash composition data of coal is provided to predict coal ash melting behavior and evaluate adaptability to entrained flow gasifier. The order of coal adapting to liquid-state slagging of entrained flow gasifier could be, from high to low, as follows: medium-calcium-high-ferric, high-calcium-low-ferric, medium-calcium-medium-ferric, low-calcium-low-ferric, and high-calcium-high-ferric.%以21个中国典型煤样为研究对象,根据煤灰中CaO和Fe2O3含量,将之分为低钙低铁类、中钙中铁类、中钙高铁类、高钙低铁类、高钙高铁类等类别.利用高温黏度计测量煤灰熔渣黏温特性,并利用计算软件FactSage对煤灰熔融状态进行热力学平衡计算,研究了液相熔渣及固体矿物质结晶与熔渣黏度的关系,分析整理了煤灰最初硅铝比(SiO2/Al2O3)、固体结晶物以及液相熔渣组成3个因素对煤灰熔融特性和熔渣黏温特性的影响,为根据煤灰组分分析来预测不同煤的熔渣黏温特性及对气流床气化的适应性提供了一个简单而实用的判断方法.对气流床气化液态排渣的适应性从高到低依次为:中钙高铁类、高钙低铁类、中钙中铁类

  19. High temperature co-treatment of bottom ash and stabilized fly ashes from waste incineration

    DEFF Research Database (Denmark)

    Sørensen, Mette Abildgaard; Mogensen, E.P.B.; Lundtorp, Kasper


    Bottom ashes from two Danish municipal solid waste incineration plants were heated at 900 degreesC with iron oxide stabilized air pollution control residues at actual mass flow ratios (9:1), simulating a treating method for the residues. The two residues were cotreated, producing one combined...

  20. In Situ Elevated Temperature Testing of Fly Ash Based Geopolymer Composites

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    Les Vickers


    Full Text Available In situ elevated temperature investigations using fly ash based geopolymers filled with alumina aggregate were undertaken. Compressive strength and short term creep tests were carried out to determine the onset temperature of viscous flow. Fire testing using the standard cellulose curve was performed. Applying a load to the specimen as the temperature increased reduced the temperature at which viscous flow occurred (compared to test methods with no applied stress. Compressive strength increased at the elevated temperature and is attributed to viscous flow and sintering forming a more compact microstructure. The addition of alumina aggregate and reduction of water content reduced the thermal conductivity. This led to the earlier onset and shorter dehydration plateau duration times. However, crack formation was reduced and is attributed to smaller thermal gradients across the fire test specimen.

  1. A high temperature granulation process for ecological ash recirculation

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    Sundqvist, Thomas


    This thesis is a summary of three papers dealing with new technologies for facilitating ecological biomass ash recirculation back to forest and farm lands. The present outtake of biomass for paper and energy production may be incompatible with a sustainable forestry. The cycle of nutrients contained in the biomass extracted must be closed by ash recirculation in an environmental compatible way. This implies stabilization of the loose ashes/rest-products to a product with low heavy metal contents, controlled leaching properties and a high spreadability. In the present work, two different techniques were evaluated for the possibilities to separate heavy metals from the nutrient elements by utilizing high process temperatures to vaporize the unwanted metals from the condensed bulk materials. The results indicated that direct in-situ separation in fluidized bed combustion systems is possible, but requires too high process temperatures to be practically attractive. On the other hand, the new proposed high temperature treatment method for granulated raw materials was found to significantly separate As, Cd and Pb, with separation efficiencies exceeding 90 % at optimal operating conditions. In addition, the results indicated that the treatment method could be used to significantly delay and control the leaching characteristics, as well as the content of products of incomplete combustion of the produced granules.


    Institute of Scientific and Technical Information of China (English)


    According to composition and structure properties of low calcium fly ash, the activation and reaction degree of fly ash-lime and fly ash-lime-gypsum system were studied in different alkali surroundings and temperatures by thermal-gravity analysis.The degree of reaction and pore structure analysis test results show that composite alkali play an important role in the activation and degree of reaction of fly ash at room temperature. But when increasing curing temperature, gypsum would play an important role in activation and hydration of fly ash.

  3. The enormous Chillos Valley Lahar: An ash-flow-generated debris flow from Cotopaxi Volcano, Ecuador (United States)

    Mothes, P.A.; Hall, M.L.; Janda, R.J.


    The Chillos Valley Lahar (CVL), the largest Holocene debris flow in area and volume as yet recognized in the northern Andes, formed on Cotopaxi volcano's north and northeast slopes and descended river systems that took it 326 km north-northwest to the Pacific Ocean and 130+ km east into the Amazon basin. In the Chillos Valley, 40 km downstream from the volcano, depths of 80-160 m and valley cross sections up to 337000m2 are observed, implying peak flow discharges of 2.6-6.0 million m3/s. The overall volume of the CVL is estimated to be ???3.8 km3. The CVL was generated approximately 4500 years BP by a rhyolitic ash flow that followed a small sector collapse on the north and northeast sides of Cotopaxi, which melted part of the volcano's icecap and transformed rapidly into the debris flow. The ash flow and resulting CVL have identical components, except for foreign fragments picked up along the flow path. Juvenile materials, including vitric ash, crystals, and pumice, comprise 80-90% of the lahar's deposit, whereas rhyolitic, dacitic, and andesitic lithics make up the remainder. The sand-size fraction and the 2- to 10-mm fraction together dominate the deposit, constituting ???63 and ???15 wt.% of the matrix, respectively, whereas the silt-size fraction averages less than ???10 wt.% and the clay-size fraction less than 0.5 wt.%. Along the 326-km runout, these particle-size fractions vary little, as does the sorting coefficient (average = 2.6). There is no tendency toward grading or improved sorting. Limited bulking is recognized. The CVL was an enormous non-cohesive debris flow, notable for its ash-flow origin and immense volume and peak discharge which gave it characteristics and a behavior akin to large cohesive mudflows. Significantly, then, ash-flow-generated debris flows can also achieve large volumes and cover great areas; thus, they can conceivably affect large populated regions far from their source. Especially dangerous, therefore, are snowclad volcanoes

  4. Coal ash fusion temperatures -- New characterization techniques, and associations with phase equilibria

    Energy Technology Data Exchange (ETDEWEB)

    Wall, T.F.; Gupta, R.P.; Gupta, S. [Univ. of Newcastle, New South Wales (Australia). Dept. of Chemical Engineering; Creelman, R.A. [R.A. Creelman and Associates, Epping, New South Wales (Australia); Coin, C. [ACIRL Ipswich, Booval, Queensland (Australia); Lowe, A. [Pacific Power, Sydney, New South Wales (Australia)


    The well-documented shortcomings of the standard technique for estimating the fusion temperature of coal ash are its subjective nature and poor accuracy. Alternative measurements based on the shrinkage and electrical conductivity of heating samples are therefore examined with laboratory ash prepared at about 800 C in crucibles, as well as combustion ash sampled from power stations. Sensitive shrinkage measurements indicate temperatures of rapid change which correspond to the formation of liquid phases that can be identified on ternary phase diagrams. The existence and extent of formation of these phases, as quantified by the magnitude of peaks in the test, provide alternative ash fusion temperatures. The peaks from laboratory ashes and corresponding combustion ashes derived from the same coals show clear differences which may be related to the evaporation of potassium during combustion and the reactions of the mineral residues to form combustion ash.

  5. Mercury adsorption characteristics of HBr-modified fly ash in an entrained-flow reactor. (United States)

    Zhang, Yongsheng; Zhao, Lilin; Guo, Ruitao; Song, Na; Wang, Jiawei; Cao, Yan; Orndorff, William; Pan, Wei-ping


    In this study, the mercury adsorption characteristics of HBr-modified fly ash in an entrained-flow reactor were investigated through thermal decomposition methods. The results show that the mercury adsorption performance of the HBr-modified fly ash was enhanced significantly. The mercury species adsorbed by unmodified fly ash were HgCl2, HgS and HgO. The mercury adsorbed by HBr-modified fly ash, in the entrained-flow reactor, existed in two forms, HgBr2 and HgO, and the HBr was the dominant factor promoting oxidation of elemental mercury in the entrained-flow reactor. In the current study, the concentration of HgBr2 and HgO in ash from the fine ash vessel was 4.6 times greater than for ash from the coarse ash vessel. The fine ash had better mercury adsorption performance than coarse ash, which is most likely due to the higher specific surface area and longer residence time.

  6. Melting and Sintering of Ashes

    DEFF Research Database (Denmark)

    Hansen, Lone Aslaug


    obtained during coal/straw co-firing, substantive sintering strength was observed to build up in the ashes below the melting onset. The strength obtained was thus assumed to be due to viscous flow sintering, and the sintering onset was for the four ashes investigated simultaneous to a calculated ash......The thesis contains an experimental study of the fusion and sintering of ashes collected during straw and coal/straw co-firing.A laboratory technique for quantitative determination of ash fusion has been developed based on Simultaneous Thermal Analysis (STA). By means of this method the fraction...... of melt in the investigated ashes has been determined as a function of temperature. Ash fusion results have been correlated to the chemical and mineralogical composition of the ashes, to results from a standard ash fusion test and to results from sintering experiments. Furthermore, the ash fusion results...

  7. Prediction of Chinese coal ash fusion temperatures in Ar and H{sub 2} atmospheres

    Energy Technology Data Exchange (ETDEWEB)

    Wen J. Song; Li H. Tang; Xue D. Zhu; Yong Q. Wu; Zi B. Zhu; Shuntarou Koyama [East China University of Science and Technology, Shanghai (China)


    The ash fusion temperatures (AFTs) of 21 typical Chinese coal ash samples and 60 synthetic ash samples were measured in Ar and H{sub 2} atmospheres. The computer software package FactSage was used to calculate the temperatures corresponding to different proportions of the liquid phase and predict the phase equilibria of synthetic ash samples. Empirical liquidus models were derived to correlate the AFTs under both Ar and H{sub 2} atmospheres of 60 synthetic ash samples, with their liquidus temperatures calculated by FactSage. These models were used to predict the AFTs of 21 Chinese coal ash samples in Ar and H{sub 2} atmospheres, and then the AFT differences between the atmospheres were analyzed. The results show that, for both atmospheres, there was an apparently linear correlation and good agreement between the AFTs of synthetic ash samples and the liquidus temperatures calculated by FactSage (R > 0.89, and {sigma} < 30{sup o}C). These models predict the AFTs of coal ash samples with a high level of accuracy (SE < 30{sup o}C). Because the iron oxides in coal ash samples fused under a H{sub 2} atmosphere are reduced to metallic iron and lead to changes of mineral species and micromorphology, the AFTs in a H{sub 2} atmosphere are always higher than those with an Ar atmosphere. 34 refs., 9 figs., 7 tabs.

  8. Coal ash fusion temperatures - new characterization techniques and implications for slagging and fouling

    Energy Technology Data Exchange (ETDEWEB)

    Wall, T.F.; Creelman, R.A.; Gupta, R.P.; Gupta, S.K.; Coin, C.; Lowe, A. [University of Newcastle, Newcastle, NSW (Australia). CRC for Black Coal Utilisation


    The ash fusion test (AFT) is the accepted test for the propensity of coal ash to slag in the furnace. The well-documented shortcomings of this technique for estimating the fusion temperature of coal ash are its subjective nature and poor accuracy. Alternative measurements based on the shrinkage and electrical conductivity of heating samples are therefore examined here with laboratory ash prepared at about 800{degree}C in crucibles, as well as combustion ash samples from power stations. Sensitive shrinkage measurements indicate temperatures of rapid change which correspond to the formation of liquid phases that can be identified on ternary phase diagrams. The existence and extent of formation of these phases, as quantified by the magnitude of `peaks` in the test, provide alternative ash fusion temperatures. The peaks from laboratory ashes and corresponding combustion ashes derived from the same coals show clear differences which may be related to the evaporation of potassium during combustion and the reactions of the mineral residues to form combustion ash. A preliminary evaluation of data from nine power stations indicates that shrinkage measurements can provide an alternative approach to characterizing slagging. 15 refs., 9 figs., 2 tabs.

  9. Ash-flow tuffs of the Galiuro Volcanics in the northern Galiuro Mountains, Pinal County, Arizona (United States)

    Krieger, Medora Louise Hooper


    The upper Oligocene and lower Miocene Galiuro Volcanics in the northern part of the Galiuro Mountains contains two distinctive major ash-flow tuff sheets, the Holy Joe and Aravaipa Members. These major ash-flows illustrate many features of ash-flow geology not generally exposed so completely. The Holy Joe Member, composed of a series of densely welded flows of quartz latite composition that make up a simple cooling unit. is a rare example of a cooling unit that has a vitrophyre at the top as well as at the base. The upper vitrophyre does not represent a cooling break. The Aravaipa Member. a rhyolite, is completely exposed in Aravaipa and other canyons and on Table Mountain. Remarkable exposures along Whitewash Canyon exhibit the complete change from a typical stacked-up interior zonation of an ash flow to a non welded distal margin. Vertical and horizontal changes in welding, crystallization, specific gravity, and lithology are exposed. The ash flow can be divided into six lithologic zones. The Holy Joe and Aravaipa Members of the Galiuro Volcanics are so well exposed and so clearly show characteristic features of ash-flow tuffs that they could be a valuable teaching aid and a source of theses for geology students.

  10. Sequential electrodialytic recovery of phosphorus from low-temperature gasification ashes of chemically precipitated sewage sludge

    DEFF Research Database (Denmark)

    Parés Viader, Raimon; Jensen, Pernille Erland; Ottosen, Lisbeth M.


    availability and the presence of heavy metals. Previously, more than 80% of P was recovered from incineration sewage sludge ashes using a two-compartment electrodialytic cell. In contrast, the recovery was below 30% for ashes from low-temperature gasification using the same setup. The low recovery was due...

  11. Activation of fly ashes by the high temperature and high alkalinity in ASR tests

    Institute of Scientific and Technical Information of China (English)


    High temperature and high alkalinity are typical testing conditions to accelerate the appraisal process of the suppressing effect of fly ashes on alkali silica reaction(ASR),but the reaction mechanism of fly ashes would be quite different under such conditions compared to the normal condition of temperature and alkalinity.To make a reasonable analysis of the suppressing effect of fly ashes,13 types of fly ashes were tested in this paper by both the accelerated mortar bar test method and the 60°C accelerated concrete prism test method.The results showed that the effect of fly ashes would be magnified under the condition of high temperature and high alkalinity.The XRD analysis showed that all the phases of fly ash could react with the hot alkaline solution except for mullite and a small amount of quartz.Fly ash could be significantly activated by the 80°C 1 mol/L NaOH solution,and form mainly C-S-H phase and P type zeolite,but its effect on inhibiting ASR was exaggerated then.According to the mortar strength test and the ASR suppressing test results,C-S-H phase contributed to mortar strength,but its amount did not decide the ASR suppressing effect of fly ash.

  12. Modeling and Prediction of Coal Ash Fusion Temperature based on BP Neural Network

    Directory of Open Access Journals (Sweden)

    Miao Suzhen


    Full Text Available Coal ash is the residual generated from combustion of coal. The ash fusion temperature (AFT of coal gives detail information on the suitability of a coal source for gasification procedures, and specifically to which extent ash agglomeration or clinkering is likely to occur within the gasifier. To investigate the contribution of oxides in coal ash to AFT, data of coal ash chemical compositions and Softening Temperature (ST in different regions of China were collected in this work and a BP neural network model was established by XD-APC PLATFORM. In the BP model, the inputs were the ash compositions and the output was the ST. In addition, the ash fusion temperature prediction model was obtained by industrial data and the model was generalized by different industrial data. Compared to empirical formulas, the BP neural network obtained better results. By different tests, the best result and the best configurations for the model were obtained: hidden layer nodes of the BP network was setted as three, the component contents (SiO2, Al2O3, Fe2O3, CaO, MgO were used as inputs and ST was used as output of the model.

  13. Mineral and chemical variations within an ash-flow sheet from Aso caldera, Southwestern Japan (United States)

    Lipman, P.W.


    Although products of individual volcanic eruptions, especially voluminous ash-flow eruptions, have been considered among the best available samples of natural magmas, detailed petrographic and chemical study indicates that bulk compositions of unaltered Pleistocene ash-flow tuffs from Aso caldera, Japan, deviate significantly from original magmatic compositions. The last major ash-flow sheet from Aso caldera is as much as 150 meters thick and shows a general vertical compositional change from phenocryst-poor rhyodacite upward into phenocryst-rich trachyandesite; this change apparently reflects in inverse order a compositionally zoned magma chamber in which more silicic magma overlay more mafic magma. Details of these magmatic variations were obscured, however, by: (1) mixing of compositionally distinct batches of magma during upwelling in the vent, as indicated by layering and other heterogeneities within single pumice lumps; (2) mixing of particulate fragments-pumice lumps, ash, and phenocrysts-of varied compositions during emplacement, with the result that separate pumice lenses from a single small outcrop may have a compositional range nearly as great as the bulk-rook variation of the entire sheet; (3) density sorting of phenocrysts and ash during eruption and emplacement, resulting in systematic modal variations with distance from the caldera; (4) addition of xenocrysts, resulting in significant contamination and modification of proportions of crystals in the tuffs; and (5) ground-water leaching of glassy fractions during hydration after cooling. Similar complexities characterize ash-flow tuffs under study in southwestern Nevada and in the San Juan Mountains, Colorado, and probably are widespread in other ash-flow fields as well. Caution and careful planning are required in study of the magmatic chemistry and phenocryst mineralogy of these rocks. ?? 1967 Springer-Verlag.

  14. Multivariable Regression and Adaptive Neurofuzzy Inference System Predictions of Ash Fusion Temperatures Using Ash Chemical Composition of US Coals

    Directory of Open Access Journals (Sweden)

    Shahab Karimi


    Full Text Available In this study, the effects of ratios of dolomite, base/acid, silica, SiO2/Al2O3, and Fe2O3/CaO, base and acid oxides, and 11 oxides (SiO2, Al2O3, CaO, MgO, MnO, Na2O, K2O, Fe2O3, TiO2, P2O5, and SO3 on ash fusion temperatures for 1040 US coal samples from 12 states were evaluated using regression and adaptive neurofuzzy inference system (ANFIS methods. Different combinations of independent variables were examined to predict ash fusion temperatures in the multivariable procedure. The combination of the “11 oxides + (Base/Acid + Silica ratio” was the best predictor. Correlation coefficients (R2 of 0.891, 0.917, and 0.94 were achieved using nonlinear equations for the prediction of initial deformation temperature (IDT, softening temperature (ST, and fluid temperature (FT, respectively. The mentioned “best predictor” was used as input to the ANFIS system as well, and the correlation coefficients (R2 of the prediction were enhanced to 0.97, 0.98, and 0.99 for IDT, ST, and FT, respectively. The prediction precision that was achieved in this work exceeded that reported in previously published works.

  15. Characterization of animal manure and cornstalk ashes as affected by incineration temperature

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Y.; Dong, H.; Shang, B.; Zhu, Z. [Institute of Environment and Sustainable Development in Agriculture, Chinese Academy of Agricultural Sciences, Key Laboratory for Agro-environment and Climate Change, Ministry of Agriculture, Beijing 100081 (China); Xin, H. [Department of Agricultural and Biosystems Engineering, Iowa State University, Ames, IA 50011 (United States)


    Incineration has been proposed as an alternative technology to reuse animal manure by producing energy and ash fertilizers. The objective of this study was to assess the impact of incineration temperature on the physical (ash yield) and chemical (nutrient) properties of ashes for different types of animal manure and cornstalk. The source materials were incinerated in a temperature-controlled muffle furnace at the temperature of 400, 500, 600, 700, 800 or 900 C and the properties of the resultant ashes were determined following the procedures set by China National Standards. The results indicated that ash yield (AY, %), total nitrogen (TN) recovery and total potassium (K{sub 2}O) recovery all decreased with increasing incineration temperature. The ranges of AY, ash TN and K{sub 2}O recovery were, respectively, 43.6-30.2%, 6.9-0.6%, and 80-61% for laying-hen manure; 34.3-32.1%, 18.8-15.4%, and 95-56% for cattle manure; 25.3-20.7%, 14-0%, and 78-57% for swine manure; and 8.4-7.5%, 2.1-1.4%, and 37-19% for cornstalk. However, total phosphorus (P{sub 2}O{sub 5}) content of the ashes increased with incineration temperature, being 20.7-24.0% for swine manure, 4.5-7.5% for layer manure, and 2.7-3.4% for cornstalk. Animal manures have greater TN and P{sub 2}O{sub 5} volatilization but less K{sub 2}O and total sodium (Na{sub 2}O) volatilization as compared to the cornstalk. The results provide a basis for incineration as an alternative means to reuse animal manures and cornstalk and suitability of the resultant ash co-product for different applications. (author)

  16. Chemical composition of overland flow produced on soils covered with vegetative ash

    Directory of Open Access Journals (Sweden)

    M.B. Bodí


    Full Text Available The objective of this study was to ascertain the differences between the soluble elements of ash obtained under laboratory conditions and the dissolved in overland flow from soils covered with a layer of ash. The overland flow was obtained during series of rainfall simulations over soils covered with two different types of ash. This study indicates that the soluble elements released from ash can modify water quality increasing its pH, electrical conductivity and especially cation content. The nutrients solubilised are not necessarily the same as the elemental composition of ash itself. Runoff composition depends on the volume of water produced, on the solubility of the ash components and on the chemical interactions with water from rainfall and soil. After the first intense rain event, most of the elements are solubilised and lixiviated or washed out, however, some of them may increase in the runoff or soil water some weeks later due to chemical interactions with water from rainfall and soil nutrients.

  17. Study of thermal-flow processes in ash cooler cooperating with CFB boiler

    Directory of Open Access Journals (Sweden)

    Paweł Regucki


    Full Text Available The article presents an example of thermal-flow analysis of the bottom ash cooler cooperating with the circulating fluidized bed boiler. There is presented a mathematical model of series-parallel hydraulic system supplying the ash cooler in cooling water. The numerical calculations indicate an influence of changes of the pipeline geometrical parameters on the cooling water flow rate in the system. Paper discusses the methodology of the studies and presents examples of the results of thermal balance calculations based on the results of measurements. The numerical results of the thermal-flow analysis in comparison with the measurements on the object indicate that the presented approach could be used as a diagnostic tool investigating the technical state of the bottom ash cooler.

  18. Low-temperature methyl bromide fumigation of emerald ash borer (Coleoptera: Buprestidae) in ash logs. (United States)

    Barak, Alan V; Elder, Peggy; Fraser, Ivich


    Ash (Fraxinus spp.) logs, infested with fully developed, cold-acclimated larval and prepupal emerald ash borer, Agrilus planipennis Fairmaire (Coleoptera: Buprestidae), were fumigated with methyl bromide (MeBr) at 4.4 and 10.0 degrees C for 24 h. Concentrations X time dosages of MeBr obtained were 1579 and 1273 g-h/m3 (24-h exposure) at 4.4 and 10.0 degrees C after applied doses of 112 and 96 g/m3, respectively. MeBr concentrations were simultaneously measured with a ContainIR infrared monitor and Fumiscope thermal conductivity meter calibrated for MeBr to measure the effect of CO2 on Fumiscope concentration readings compared with the infrared (IR) instrument. The presence of CO2 caused false high MeBr readings. With the thermal conductivity meter, CO2 measured 11.36 g/m3 MeBr per 1% CO2 in clean air, whereas the gas-specific infrared ContainIR instrument measured 9.55% CO2 as 4.2 g/m3 MeBr (0.44 g/m3 per 1% CO2). The IR instrument was 0.4% as sensitive to CO2 as the thermal conductivity meter. After aeration, fumigated and control logs were held for 8 wk to capture emerging beetles. No A. planipennis adults emerged from any of the fumigated logs, whereas 262 emerged from control logs (139 and 123/m2 at 4.4 and 10.0 degrees C, respectively). An effective fumigation dose and minimum periodic MeBr concentrations are proposed. The use of a CO2 scrubber in conjunction with nonspecific thermal conductivity instruments is necessary to more accurately measure MeBr concentrations.

  19. Seismicity of block-and-ash flows occurring during the 2006 eruption of Augustine Volcano, Alaska (United States)

    DeRoin, Nicole; McNutt, Stephen R.; Sentman, Davis D.; Reyes, Celso


    In January 2006, Augustine Volcano began erupting following an increase in seismicity that was first noted in late April 2005. Thirteen large explosive eruptions of Augustine occurred from January 11 to 28, 2006, followed by a continuously erupting phase and then by a dome growth phase in which numerous pyroclastic flows and block-and-ash flows occurred. As a new steep-sided and unstable dome grew in spring 2006, rockfalls and related events, likely block-and-ash flows, dominated the seismic record. Relative amplitudes at pairs of seismic stations for 68 block-and-ash flow events were examined to constrain locations of the flow-events. Higher amplitudes were associated with events closer to a given station. These relations were confirmed by images collected on a low-light camera. Captured images show a correlation between flow direction and seismic amplitude ratios from nearby stations AUE and AUW. Seismic amplitudes and energies of the flow signals, measured in several different ways, were found to correlate with the surface areas and run-out distances of the flows. The ML range of rockfalls was 0.1 to 1.1, and seismic efficiencies were estimated to be much less than 1%. Particle motion analyses showed that the seismic waves contained both body waves and surface waves and demonstrate that the flows were acting as moving sources with velocities of 30-93 m/s.

  20. Ash behavior and de-fluidization in low temperature circulating fluidized bed biomass gasifier

    DEFF Research Database (Denmark)

    Narayan, Vikas

    -Temperature Circulating Fluidized Bed System (LTCFB) gasifier allows pyrolysis and gasification of biomass to occur at low temperatures thereby improving the retention of alkali and other ash species within the system and minimizing the amount of ash species in the product gas. In addition, the low reactor temperature......Biomass is increasingly used as a fuel for power generation. Herbaceous fuels however, contain high amounts of alkali metals which get volatilized at high temperatures and forms salts with low melting points and thus condense on pipelines, reactor surfaces and may cause de-fluidization. A Low...... at Risø and a 6 MW LTCFB gasifier owned by DONG ENERGY and placed in Kalundborg. In addition to the analysis of the inorganic elemental composition of the collected samples, SEM and TGA analysis of the samples were made to improve understanding on the behavior of the ash forming species within the system...

  1. Behavior of Alkali Metals and Ash in a Low-Temperature Circulating Fluidized Bed (LTCFB) Gasifier

    DEFF Research Database (Denmark)

    Narayan, Vikas; Jensen, Peter Arendt; Henriksen, Ulrik Birk


    A low-temperature circulating fluidized bed system (LTCFB) gasifier allows for pyrolysis and gasification to occurat low temperatures, thereby improving the retention of alkali and other inorganic elements within the system and minimizingthe amount of ash species in the product gas. In addition......, the low reactor temperature ensures that high-alkali biomass fuels canbe used without risk of bed defluidization. This paper presents the first investigation of the fate of alkali metals and ash in lowtemperaturegasifiers. Measurements on bed material and product gas dust samples were made on a 100 k...

  2. The desulfurization behavior of mineral matter in ash during coal combustion at high temperature

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Tian-hua; Li, Run-dong; Li, Yan-ji; Zhou, Jun-huz; Cen, Ke-fa [Shenyang Institute of Aeronautical Engineering, Shenyang (China)


    In allusion to the desulfurization characteristic of coal ash, the desulfurization of the ash and CaO, Al{sub 2}O{sub 3} added to Changguang coal with different proportions at high temperature was studied. Sulphoaluminate as the main desulfurization product was analyzed by X-ray diffraction and SEM visualization. Experimental results indicate that higher proportion of ash added can improve the desulfurization efficiency. The sulphoaluminate content in residue increases with increasing the addition of ash. The desulfurization efficiency of the additive CaO and Al{sub 2}O{sub 3} is up to 24% at 1300{sup o}C, at the same time the sulphoaluminate is detected in the residue. 6 refs., 10 figs., 2 tabs.

  3. Comenditic and pantelleritic ash-flow tuffs from Volcan Las Navajas, Nayarit, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, S.A.; Hebre, J.A.


    Two distinctive ash-flow tuffs occur around the base of Volcan Las Navajas, a Pleistocene trachyte - peralkaline rhyolite center located in the northwestern segment of the Mexican Volcanic belt. The lower ash-flow unit is locally up to 65 m thick, is lithic rich and contains pumice blocks of comenditic rhyolite. The unit is not extensively exposed, and thus its areal extent and volume cannot be determined. Its chemical characteristics and stratigraphic relationship to other products erupted from Las Navajas suggest that it is related to the formation of the older of the two calderas which occur on Las Navajas. Unconformably overlying this unwelded ash-flow is a pantelleritic airfall pumice unit which is locally welded. This airfall unit is conformably overlain by a welded as-flow tuff that contains fiamme of pantelleritic composition (72 %SiO/sub 2/, 8% FeO*, 900 ppm Zr, agpaitic index of 1.7) as well as pumice blocks that show evidence of various degrees of mixing between pantellerite and trachyte. This suggests eruption from a chemically zoned magma chamber. This unit is locally up to 20 m thick, although its top has been removed by erosion. It is found on all sides of Las Navajas except on the south where it may be covered by Volcan Sanganguey, a Pleistocene to Recent calc-alkaline volcano. The welded ash-flow has been dated by K - Ar at 0.2+/-0.1 m.y. Stratigraphically and chemically this ash-flow appears to be related to the formation of younger of the two calderas.

  4. Fly ash porous material using geopolymerization process for high temperature exposure. (United States)

    Abdullah, Mohd Mustafa Al Bakri; Jamaludin, Liyana; Hussin, Kamarudin; Bnhussain, Mohamed; Ghazali, Che Mohd Ruzaidi; Ahmad, Mohd Izzat


    This paper presents the results of a study on the effect of temperature on geopolymers manufactured using pozzolanic materials (fly ash). In this paper, we report on our investigation of the performance of porous geopolymers made with fly ash after exposure to temperatures from 600 °C up to 1000 °C. The research methodology consisted of pozzolanic materials (fly ash) synthesized with a mixture of sodium hydroxide and sodium silicate solution as an alkaline activator. Foaming agent solution was added to geopolymer paste. The geopolymer paste samples were cured at 60 °C for one day and the geopolymers samples were sintered from 600 °C to 1000 °C to evaluate strength loss due to thermal damage. We also studied their phase formation and microstructure. The heated geopolymers samples were tested by compressive strength after three days. The results showed that the porous geopolymers exhibited strength increases after temperature exposure.

  5. Thermal Barrier Coatings Chemically and Mechanically Resistant to High Temperature Attack by Molten Ashes (United States)

    Gledhill, Andrew

    Thermal barrier coatings (TBCs) are ceramic coatings used on component in the hottest sections of gas turbine engines, used for power generation and aviation. These coatings insulate the underlying metal components and allow for much higher engine operating temperatures, improving the engine efficiency. These increase temperatures engender a new set of materials problems for TBCs. Operating temperatures in engines are now high enough for silicate impurities, either present in the fuel or ingested into the engines, to melt and adhere to the surface of the TBCs. The effects of four such impurities, two coal fly ashes, a petroleum coke-fly ash blend, and volcanic ash from the Eyjafjallajokull volcano were tested with conventional yttria-stabilized zirconia (YSZ) coatings, and found to penetrate through the entire thickness of the coating. This penetration reduces the strain tolerance of the coatings, and can result in premature failure. Testing on a newly built thermal gradient burner rig with simultaneous injection of ash impurities has shown a reduction of life up to 99.6% in these coatings when ash is present. Coatings of an alternative ceramic, gadolinium zirconate (Gd2Zr 2O7), were found to form a dense reaction layer with each of these impurities, preventing further penetration of the molten ash. This dense layer also reduces the strain tolerance, but these coatings were found to have a significantly higher life than the YSZ coatings. Testing with a small amount of ash baked onto the samples showed thirteen times the life of YSZ coatings. When the ash is continuously sprayed onto the hot sample, the life of the Gd2Zr2O7 coatings was nearly twice that of the YSZ. Finally, a delamination model was employed to explain the degradation of both types of coatings. This elastic model that takes into account the degree of penetration, differential cooling in thermal gradient testing, and thermal expansion mismatch with the underlying substrate, predicted the failure of

  6. Influence of temperature and atmosphere on polychlorinated dibenzo-p-dioxins and dibenzofurans desorption from waste incineration fly ash. (United States)

    Yang, Jie; Yan, Mi; Li, Xiaodong; Chen, Tong; Lu, Shengyong; Yan, Jianhua; Buekens, Alfons


    A fly ash sample was heated for 1 h to 200°C, 300°C and 400°C, in order to study the influence of temperature and gas phase composition on the removal of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) from fly ash derived from municipal solid waste incineration. The tests were conducted by treating a fixed bed of fly ash both in an inert (nitrogen) and in a reducing (nitrogen+hydrogen) gas flow in a horizontal bench-scale quartz tubular reactor, heated by a surrounding tubular furnace. The results indicate that most of the PCDD/Fs in fly ash were removed by thermal treatment, especially when the temperature was higher than 300°C: the PCDD/Fs' removal efficiency attained up to 96%. PCDD/Fs dechlorination and destruction were much more important than PCDD/Fs desorption, under either inert or reducing atmosphere. At 200°C and 300°C, the experiments with reducing atmosphere yielded slightly better results than those in nitrogen; yet, this tendency was reversed at 400°C. In general, both treatment modes can fully meet the requirements regarding the concentration of dioxins in fly ash to be sent for landfill in China.

  7. Melting Behavior of Volcanic Ash relevant to Aviation Ash Hazard (United States)

    Song, W.; Hess, K.; Lavallee, Y.; Cimarelli, C.; Dingwell, D. B.


    Volcanic ash is one of the major hazards caused by volcanic eruptions. In particular, the threat to aviation from airborne volcanic ash has been widely recognized and documented. In the past 12 years, more than 60 modern jet airplanes, mostly jumbo jets, have been damaged by drifting clouds of volcanic ash that have contaminated air routes and airport facilities. Seven of these encounters are known to have caused in-flight loss of engine power to jumbo jets carrying a total of more than 2000 passengers. The primary cause of engine thrust loss is that the glass in volcanic ash particles is generated at temperatures far lower than the temperatures in the combustion chamber of a jet engine ( i.e. > 1600 oC) and when the molten volcanic ash particles leave this hottest section of the engine, the resolidified molten volcanic ash particles will be accumulated on the turbine nozzle guide vanes, which reduced the effective flow of air through the engine ultimately causing failure. Thus, it is essential to investigate the melting process and subsequent deposition behavior of volcanic ash under gas turbine conditions. Although few research studies that investigated the deposition behavior of volcanic ash at the high temperature are to be found in public domain, to the best our knowledge, no work addresses the formation of molten volcanic ash. In this work, volcanic ash produced by Santiaguito volcano in Guatemala in November 8, 2012 was selected for study because of their recent activity and potential hazard to aircraft safety. We used the method of accessing the behavior of deposit-forming impurities in high temperature boiler plants on the basis of observations of the change in shape and size of a cylindrical coal ash to study the sintering and fusion phenomena as well as determine the volcanic ash melting behavior by using characteristic temperatures by means of hot stage microscope (HSM), different thermal analysis (DTA) and Thermal Gravimetric Analysis (TGA) to

  8. Effect of biomass on temperatures of sintering and initial deformation of lignite ash

    Energy Technology Data Exchange (ETDEWEB)

    H. Haykiri-Acma; S. Yama; S. Kucukbayrak [Istanbul Technical University, Istanbul (Turkey). Faculty of Chemical and Metallurgical Engineering


    Sintering temperatures and the initial deformation temperatures of ashes from Turkish Elbistan lignite, and biomass species such as hazelnut shell and rice husk were investigated up to 1450{sup o}C by Heating Microscope Technique. Sintering temperatures were found 1300, 1269, and 1320{sup o}C for hazelnut shell, rice husk, and lignite, respectively, while the initial deformation temperatures were >1450, 1370, and >1450{sup o}C. Lignite/biomass blends were prepared by adding of biomass into coal in the ratios of 5 or 10 wt.%, and then effects of biomass presence on sintering temperature and the initial deformation temperature were tested. It was determined that the addition of potassium-rich hazelnut shell reduced the sintering temperatures to 919 and 730{sup o}C for the blends of 5 and 10 wt.%, respectively. Also, initial deformation temperature dropped to 788{sup o}C in case of the blend of 10 wt.%. Such a big antagonistic influence of hazelnut shell on the thermal behaviour of ash is attributed to the interaction of potassium from biomass with silicon compounds found in mineral matter of lignite. In addition, concentration of CaO may be another reason for this. On the other hand, the presence of rice husk showed limited effect on the sintering temperature as well the initial deformation temperature. 20 refs., 3 figs., 5 tabs.

  9. Effects of fire temperature on the physical and chemical characteristics of the ash from two plots of Cork oak (Quercus Suber) (United States)

    Ubeda, X.; Pereira, P.; Outeiro, L.; Martin, D.A.


    also showed that for the same temperature, a higher severity results for Albufeira litter. Potential negative effects on soil properties are observed at medium and higher temperatures. These negative effects include a higher percentage of mass loss, meaning more soil may be exposed to erosion, higher pH values and greater cation release from ash, especially monovalalent cations (K+,Na+) in higher proportions than the divalent ions (Ca2+, Mg2+), that can lead to impacts on soil physical properties like aggregate stability. Furthermore, the ions in ash may alter soil chemistry which may be detrimental to some plants thus altering the recovery of these ecosystems after fire. Low intensity prescribed fire can be a useful tool to land management in these sites, due to the reduced effects of fire temperatures on the physical and chemical properties of surface litter, and can reduce the risk of high temperature wildland fires by reducing fuel loadings. From the perspective of water resources, lower fire temperatures produce fewer impacts on the chemistry of overland flow and there is less probability that the soil surface will be eroded. Copyright ?? 2009 John Wiley & Sons, Ltd.

  10. Dust separation at high temperatures a method for cleaning fly ashes? Final report; Stoftavskiljning vid hoeg temperatur en metod foer rening av flygaska? Slutrapport

    Energy Technology Data Exchange (ETDEWEB)

    Zintl, Frank [TPS Termiska Processer AB, Nykoeping (Sweden)


    An experimental study of separation of fly ashes by a filter at high temperatures, 300-650 deg C, with the purpose to study: Capture of heavy metals (Cd, Hg, Pb, Zn) in the fly ash; Relation between heavy metal capture and temperature; Relation between heavy metal capture and the availability of fuel chlorine. Pelletized forestry waste fuel was doped with heavy metals in two different forms. Pelletized Salix was also used, without doping. The study shows that: There is a strong inverse relation between the capture of heavy metals and the filter temperature; There is a strong relation between the availability of chlorine and the capture of heavy metals. Separation at 300-650 deg C gives much less heavy metals in the fly ash, however the ash is not clean enough to allow disposal in ordinary landfills. Thus, high temperature filtering does not seem to be a promising solution for producing 'clean' fly ash.

  11. The change in the chemical form of copper in fly ash in a suitable temperature region for de novo synthesis

    Energy Technology Data Exchange (ETDEWEB)

    Takaoka, M.; Shiono, A.; Nishimura, K.; Takeda, N.; Oshita, K.; Matsumoto, T.; Harada, H. [Kyoto Univ. (Japan). Dept. of Urban and Environ. Eng.; Yamamoto, T. [Tokyo Inst. of Tech., Yokohama (Japan). Chemical Resources Lab.; Uruga, T. [JASRI, Hyogo (Japan); Tanaka, T. [Kyoto Univ. (Japan). Dept. of Molecular Eng.


    Copper chloride as an important catalyst generates many polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/DFs) and related compounds in heat experiments involving model fly ash. We investigated the chemical forms of copper in actual fly ash before heating experiments and discuss the relationship that we discovered between the copper species Cu(OH){sub 2}, CuO, and Cu(OH){sub 2}.CuCO{sub 3}.H{sub 2}O and the formation of chlorinated aromatics in actual fly ash using X-ray absorption near-edge spectroscopy (XANES). Other results using model fly ash differ from ours. The thermal stabilities of these compounds are not high, so these compounds might not exist in fly ash in the temperature region suitable for de novo synthesis. Therefore, we conducted in situ XANES experiments using actual fly ash and two models of fly ash to understand the behavior of copper in fly ash in the temperature region suitable for de novo synthesis.

  12. Ash deposition and high temperature corrosion at combustion of aggressive fuels

    Energy Technology Data Exchange (ETDEWEB)

    Hede Larsen, O. [I/S Fynsvaerket, Faelleskemikerne, Odense (Denmark); Henriksen, N. [Elsamprojekt A/S, Faelleskemikerne, Fredericia (Denmark)


    In order to reduce CO{sub 2} emission, ELSAM is investigating the possibilities of using biomass - mainly straw - for combustion in high efficiency power plants. As straw has very high contents of chlorine and potassium, a fuel with high corrosion and ash deposition propensities has been introduced. ELSAM has investigated 3 ultra supercritical boiler concepts for combustion of straw alone or together with coal: (1) PF boilers with a relatively low share of straw, (2) CFB boilers with low to high share of straw and (3) vibrating grate boilers with 100% straw. These investigations has mainly been full-scale tests with straw fed into existing boilers. Corrosion tests have been performed in these boilers using temperature regulated probes and in-plant test tubes in existing superheaters. The corrosion has been determined by detailed measurements of wall thickness reduction and light optical microscopic measurements of the material degradation due to high temperature corrosion. Corrosion mechanisms have been evaluated using SEM/EDX together with thermodynamical considerations based on measurements of the chemical environment in the flue gas. Ash deposition is problematic in CFB boilers and in straw fired boilers, especially in years with high potassium and chlorine content of the straw. This ash deposition also is related to condensation of KCl and can probably only be handled by improved cleaning devices. (EG)

  13. Multiphase flow modelling of volcanic ash particle settling in water using adaptive unstructured meshes (United States)

    Jacobs, C. T.; Collins, G. S.; Piggott, M. D.; Kramer, S. C.; Wilson, C. R. G.


    Small-scale experiments of volcanic ash particle settling in water have demonstrated that ash particles can either settle slowly and individually, or rapidly and collectively as a gravitationally unstable ash-laden plume. This has important implications for the emplacement of tephra deposits on the seabed. Numerical modelling has the potential to extend the results of laboratory experiments to larger scales and explore the conditions under which plumes may form and persist, but many existing models are computationally restricted by the fixed mesh approaches that they employ. In contrast, this paper presents a new multiphase flow model that uses an adaptive unstructured mesh approach. As a simulation progresses, the mesh is optimized to focus numerical resolution in areas important to the dynamics and decrease it where it is not needed, thereby potentially reducing computational requirements. Model verification is performed using the method of manufactured solutions, which shows the correct solution convergence rates. Model validation and application considers 2-D simulations of plume formation in a water tank which replicate published laboratory experiments. The numerically predicted settling velocities for both individual particles and plumes, as well as instability behaviour, agree well with experimental data and observations. Plume settling is clearly hindered by the presence of a salinity gradient, and its influence must therefore be taken into account when considering particles in bodies of saline water. Furthermore, individual particles settle in the laminar flow regime while plume settling is shown (by plume Reynolds numbers greater than unity) to be in the turbulent flow regime, which has a significant impact on entrainment and settling rates. Mesh adaptivity maintains solution accuracy while providing a substantial reduction in computational requirements when compared to the same simulation performed using a fixed mesh, highlighting the benefits of an

  14. Subsidence of ash-flow calderas: Relation to caldera size and magma-chamber geometry (United States)

    Lipman, P.W.


    Diverse subsidence geometries and collapse processes for ash-flow calderas are inferred to reflect varying sizes, roof geometries, and depths of the source magma chambers, in combination with prior volcanic and regional tectonic influences. Based largely on a review of features at eroded pre-Quaternary calderas, a continuum of geometries and subsidence styles is inferred to exist, in both island-arc and continental settings, between small funnel calderas and larger plate (piston) subsidences bounded by arcuate faults. Within most ring-fault calderas, the subsided block is variably disrupted, due to differential movement during ash-flow eruptions and postcollapse magmatism, but highly chaotic piecemeal subsidence appears to be uncommon for large-diameter calderas. Small-scale downsag structures and accompanying extensional fractures develop along margins of most calderas during early stages of subsidence, but downsag is dominant only at calderas that have not subsided deeply. Calderas that are loci for multicyclic ash-flow eruption and subsidence cycles have the most complex internal structures. Large calderas have flared inner topographic walls due to landsliding of unstable slopes, and the resulting slide debris can constitute large proportions of caldera fill. Because the slide debris is concentrated near caldera walls, models from geophysical data can suggest a funnel geometry, even for large plate-subsidence calderas bounded by ring faults. Simple geometric models indicate that many large calderas have subsided 3-5 km, greater than the depth of most naturally exposed sections of intracaldera deposits. Many ring-fault platesubsidence calderas and intrusive ring complexes have been recognized in the western U.S., Japan, and elsewhere, but no well-documented examples of exposed eroded calderas have large-scale funnel geometry or chaotically disrupted caldera floors. Reported ignimbrite "shields" in the central Andes, where large-volume ash-flows are inferred to

  15. Temperature effects on ash physical and chemical properties. A laboratory study. (United States)

    Pereira, Paulo; Úbeda, Xavier; Martin, Deborah


    Fire temperatures have different impacts on ash physical and chemical properties that depend mainly of the specie affected and time of exposition. In a real prescribed or wildland fire, the temperatures produce ash with different characteristics. Know the impacts of a specific temperature or a gradient on a certain element and specie is very difficult in real fires, especially in wildland fires, where temperatures achieve higher values and the burning conditions are not controlled. Hence, laboratory studies revealed to be an excellent methodology to understand the effects of fire temperatures in ash physical and chemical. The aim of this study is study the effects of a temperature gradient (150, 200, 250, 300, 350, 400, 450, 500 and 550°C) on ash physical and chemical properties. For this study we collected litter of Quercus suber, Pinus pinea and Pinus pinaster in a plot located in Portugal. The selected species are the most common in the ecosystem. We submitted samples to the mentioned temperatures throughout a time of two hours and we analysed several parameters, namely, Loss on Ignition (LOI%), ash colour - through the Croma Value (CV) observed in Munsell color chart - CaCO3, Total Nitrogen (TN), Total Carbon (TC), C/N ratio, ash pH, Electrical Conductivity (EC), extractable Calcium (Ca2+), Magnesium (Mg2+), Sodium (Na+), Potassium (K+), Aluminium (Al3+), Manganese (Mn2+), Iron (Fe2+), Zinc (Zn2+), Total Phosphorous (TP), Sulphur (S) and Silica (SiO2). Since we considered many elements, in order to obtain a better explanation of all dataset, we applied a Factorial Analysis (FA), based on the correlation matrix and the Factors were extracted according to the Principle Components method. To obtain a better relation between the variables with a specific Factor we rotated the matrix according to the VARIMAX NORMALIZED method. FA identified 5 Factors that explained a total of 95% of the variance. We retained in each Factor the variables that presented an eigenvalue

  16. Parameterizing Aggregation Rates: Results of cold temperature ice-ash hydrometeor experiments (United States)

    Courtland, L. M.; Dufek, J.; Mendez, J. S.; McAdams, J.


    Recent advances in the study of tephra aggregation have indicated that (i) far-field effects of tephra sedimentation are not adequately resolved without accounting for aggregation processes that preferentially remove the fine ash fraction of volcanic ejecta from the atmosphere as constituent pieces of larger particles, and (ii) the environmental conditions (e.g. humidity, temperature) prevalent in volcanic plumes may significantly alter the types of aggregation processes at work in different regions of the volcanic plume. The current research extends these findings to explore the role of ice-ash hydrometeor aggregation in various plume environments. Laboratory experiments utilizing an ice nucleation chamber allow us to parameterize tephra aggregation rates under the cold (0 to -50 C) conditions prevalent in the upper regions of volcanic plumes. We consider the interaction of ice-coated tephra of variable thickness grown in a controlled environment. The ice-ash hydrometers interact collisionally and the interaction is recorded by a number of instruments, including high speed video to determine if aggregation occurs. The electric charge on individual particles is examined before and after collision to examine the role of electrostatics in the aggregation process and to examine the charge exchange process. We are able to examine how sticking efficiency is related to both the relative abundance of ice on a particle as well as to the magnitude of the charge carried by the hydrometeor. We here present preliminary results of these experiments, the first to constrain aggregation efficiency of ice-ash hydrometeors, a parameter that will allow tephra dispersion models to use near-real-time meteorological data to better forecast particle residence time in the atmosphere.

  17. Temperature effect on the pressure drop across the cake of coal gasification ash formed on a ceramic filter

    Energy Technology Data Exchange (ETDEWEB)

    Kim, J.H.; Liang, Y.; Sakong, K.M.; Choi, J.H.; Bak, Y.C. [Gyeongsang National University, Jinju (Republic of Korea). Dept. of Biology & Chemical Engineering


    In order to predict the pressure drop across the cake of coal gasification (CG) ash formed on ceramic filter, an empirical equation was developed taking into account several factors, such as the face velocity, ash load, shape factor and size of particles, and especially the operating temperature. The hot air stream of well classified fine particles of CG ash was simulated as the syngas derived from the coal gasification process. The pressure drop behavior and cleaning efficiency of the filter were carefully investigated within the temperature range from room temperature to 673 K. The pressure drop across the ash cake was dominantly governed by the air viscosity, which increased with temperature. It was well expressed by the previously reported-empirical equation (J.H. Choi, Y.C. Bak, H.J. Jang, J.H. Kim, and J.H. Kim, Korean J. Chern. Eng., 21(3) (2004) 726.) with the modification of the viscosity term in the equation for different temperatures. The residual pressure drop rate across the ash cake also increased while the cleaning efficiency of the ceramic filter decreased as temperature increased.

  18. Effects of fluxing agents on gasification reactivity and gas composition of high ash fusion temperature coal

    Directory of Open Access Journals (Sweden)

    Zhao Ruifang


    Full Text Available A Na-based fluxing agent Na2O (NBFA and a composite fluxing agent (mixture of CaO and Fe2O3 with mass ratio of 3:1, CFA for short were used to decrease the ash fusion temperature of the Dongshan and Xishan coal from Shanxi of China and make these coal meet the requirements of the specific gasification process. The main constituents of the fluxing agents used in this study can play a catalyst role in coal gasification. So it is necessary to understand the effect of fluxing agents on coal gasification reactivity and gas composition. The results showed that the ash fusion temperature of the two coal used decreased to the lowest point due to the eutectic phenomenon when 5 wt% of CFA or NBFA was added. Simultaneously, the gas molar ratio of H2/CO changed when CFA was added. A key application was thus found where the gas molar ratio of H2/CO can be adjusted by controlling the fluxing agent amount to meet the synthetic requirements for different chemical products.

  19. Potassium-based sorbents from fly ash for high-temperature CO2 capture. (United States)

    Sanna, Aimaro; Maroto-Valer, M Mercedes


    Potassium-fly ash (K-FA) sorbents were investigated for high-temperature CO2 sorption. K-FAs were synthesised using coal fly ash as source of silica and aluminium. The synthesised materials were also mixed with Li2CO3 and Ca(OH)2 to evaluate their effect on CO2 capture. Temperature strongly affected the performance of the K-FA sorbents, resulting in a CO2 uptake of 1.45 mmol CO2/g sorbent for K-FA 1:1 at 700 °C. The CO2 sorption was enhanced by the presence of Li2CO3 (10 wt%), with the K-FA 1:1 capturing 2.38 mmol CO2/g sorbent at 700 °C in 5 min. This sorption was found to be similar to previously developed Li-Na-FA (2.54 mmol/g) and Li-FA (2.4 mmol/g) sorbents. The presence of 10 % Li2CO3 also accelerated sorption and desorption. The results suggest that the increased uptake of CO2 and faster reaction rates in presence of K-FA can be ascribed to the formation of K-Li eutectic phase, which favours the diffusion of potassium and CO2 in the material matrix. The cyclic experiments showed that the K-FA materials maintained stable CO2 uptake and reaction rates over 10 cycles.

  20. Oil ash corrosion; A review of utility boiler experience

    Energy Technology Data Exchange (ETDEWEB)

    Paul, L.D. (Babcock and Wilcox Co., Alliance, OH (United States)); Seeley, R.R. (Babcock and Wilcox Canada Ltd., Cambridge, ON (Canada))


    In this paper a review of experience with oil ash corrosion is presented along with current design practices used to avoid excessive tube wastage. Factors influencing oil ash corrosion include fuel chemistry, boiler operation, and boiler design. These factors are interdependent and determine the corrosion behavior in utility boilers. Oil ash corrosion occurs when vanadium-containing ash deposits on boiler tube surfaces become molten. These molten ash deposits dissolve protective oxides and scales causing accelerated tube wastage. Vanadium is the major fuel constituent responsible for oil ash corrosion. Vanadium reacts with sodium, sulfur, and chlorine during combustion to produce lower melting temperature ash compositions, which accelerate tube wastage. Limiting tube metal temperatures will prevent ash deposits from becoming molten, thereby avoiding the onset of oil ash corrosion. Tube metal temperatures are limited by the use of a parallel stream flow and by limiting steam outlet temperatures. Operating a boiler with low excess air has helped avoid oil ash corrosion by altering the corrosive combustion products. Air mixing and distribution are essential to the success of this palliative action. High chromium alloys and coatings form more stable protective scaled on tubing surfaces, which result in lower oil ash corrosion rates. However, there is not material totally resistant to oil ash corrosion.

  1. Multiple Temperature Model for Near Continuum Flows

    Energy Technology Data Exchange (ETDEWEB)

    XU, Kun; Liu, Hongwei [Hong Kong University of Science and Technology, Kowloon (Hong Kong); Jiang, Jianzheng [Chinese Academy ofSciences, Beijing (China)


    In the near continuum flow regime, the flow may have different translational temperatures in different directions. It is well known that for increasingly rarefied flow fields, the predictions from continuum formulation, such as the Navier-Stokes equations, lose accuracy. These inaccuracies may be partially due to the single temperature assumption in the Navier-Stokes equations. Here, based on the gas-kinetic Bhatnagar-Gross-Krook (BGK) equation, a multitranslational temperature model is proposed and used in the flow calculations. In order to fix all three translational temperatures, two constraints are additionally proposed to model the energy exchange in different directions. Based on the multiple temperature assumption, the Navier-Stokes relation between the stress and strain is replaced by the temperature relaxation term, and the Navier-Stokes assumption is recovered only in the limiting case when the flow is close to the equilibrium with the same temperature in different directions. In order to validate the current model, both the Couette and Poiseuille flows are studied in the transition flow regime.

  2. Peculiar high temperature corrosion of martensite alloy under impact of Estonian oil shale fly ash

    Energy Technology Data Exchange (ETDEWEB)

    Tallermo, H.; Klevtsov, I. [Thermal Engineering Department of Tallinn Technical University, Tallinn (Estonia)


    The superheaters` surfaces of oil shale steam boiler made of pearlitic and austenitic alloys, are subject to intensive corrosion, mainly due to presence of chlorine in external deposits. The applicability of martensitic alloys X1OCrMoVNb91 and X20CrMoV121 for superheaters is examined here and empirical equations allowing to predict alloys` corrosion resistance in the range of operational temperatures are established. Alloy X1OCrMoVNb91 is found been most perspective for superheaters of boilers firing fossil fuel that contain alkaline metals and chlorine. The abnormal dependence of corrosion resistance of martensitic alloys on temperature is revealed, namely, corrosion at 580 deg C in presence of oil shale fly ash is more intensive than at 620 deg C. (orig.) 2 refs.

  3. Fusion characteristics of volcanic ash relevant to aviation hazards (United States)

    Song, Wenjia; Hess, Kai-Uwe; Damby, David E.; Wadsworth, Fabian B.; Lavallée, Yan; Cimarelli, Corrado; Dingwell, Donald B.


    The fusion dynamics of volcanic ash strongly impacts deposition in hot parts of jet engines. In this study, we investigate the sintering behavior of volcanic ash using natural ash of intermediate composition, erupted in 2012 at Santiaguito Volcano, Guatemala. A material science procedure was followed in which we monitored the geometrical evolution of cylindrical-shaped volcanic ash compact upon heating from 50 to 1400°C in a heating microscope. Combined morphological, mineralogical, and rheological analyses helped define the evolution of volcanic ash during fusion and sintering and constrain their sticking potential as well as their ability to flow at characteristic temperatures. For the ash investigated, 1240°C marks the onset of adhesion and flowability. The much higher fusibility of ash compared to that of typical test sands demonstrates for the need of a more extensive fusion characterization of volcanic ash in order to mitigate the risk posed on jet engine operation.

  4. Superplasticizer Addition to Carbon Fly Ash Geopolymers Activated at Room Temperature

    Directory of Open Access Journals (Sweden)

    Lorenza Carabba


    Full Text Available Present concerns about global warming due to the greenhouse emissions in the atmosphere have pushed the cement industry to research alternatives to ordinary Portland cement (OPC. Geopolymer binder may constitute a possible breakthrough in the development of sustainable materials: understanding the effectiveness and the influences of superplasticizers on geopolymer systems is one of the essential requirements for its large-scale implementation. This study aims to investigate the possibility of using commercially available chemical admixtures designed for OPC concrete, to improve fresh properties of fly ash-based geopolymers and mortars. A special emphasis is laid upon evaluating their influence on mechanical and microstructural characteristics of the hardened material realized under room-temperature curing conditions. Results indicate that the addition of a polycarboxylic ether-based superplasticizer, in the amount of 1.0 wt. % by mass of fly ash, promotes an improvement in workability without compromising the final strength of the hardened material. Moreover, the addition of the polycarboxylic ether- and acrylic-based superplasticizers induces a refinement in the pore structure of hardened mortar leading to a longer water saturation time.

  5. Electrodialytic extraction of phosphorus from ash of low-temperature gasification of sewage sludge

    DEFF Research Database (Denmark)

    Parés Viader, Raimon; Jensen, Pernille Erland; Ottosen, Lisbeth M.


    was from gasification of sewage sludge where P was precipitated with Fe and Al salts, from which it was possible to extract up to 26% of the P. The other ash was from co-gasification of a mixture of biologically precipitated sewage sludge and wheat straw pellets. More promising results were obtained...... with this ash, as up to 90% of the P was extracted from the ashes. For both ashes, P was extracted by ED in acidic aqueous solutions with ratios of Fe, Al and each heavy metal to P considerably below the values found in the initial ashes. Therefore, the 2-compartment ED cell technology was proved as possible...

  6. Objective rapid delineation of areas at risk from block-and-ash pyroclastic flows and surges (United States)

    Widiwijayanti, C.; Voight, B.; Hidayat, D.; Schilling, S.P.


    Assessments of pyroclastic flow (PF) hazards are commonly based on mapping of PF and surge deposits and estimations of inundation limits, and/or computer models of varying degrees of sophistication. In volcanic crises a PF hazard map may be sorely needed, but limited time, exposures, or safety aspects may preclude fieldwork, and insufficient time or baseline data may be available for reliable dynamic simulations. We have developed a statistically constrained simulation model for block-and-ash type PFs to estimate potential areas of inundation by adapting methodology from Iverson et al. (Geol Soc America Bull 110:972-984, (1998) for lahars. The predictive equations for block-and-ash PFs are calibrated with data from several volcanoes and given by A = (0.05 to 0.1) V2/3, B = (35 to 40) V2/3, where A is cross-sectional area of inundation, B is planimetric area and V is deposit volume. The proportionality coefficients were obtained from regression analyses and comparison of simulations to mapped deposits. The method embeds the predictive equations in a GIS program coupled with DEM topography, using the LAHARZ program of Schilling (1998). Although the method is objective and reproducible, any PF hazard zone so computed should be considered as an approximate guide only, due to uncertainties on the coefficients applicable to individual PFs, the authenticity of DEM details, and the volume of future collapses. The statistical uncertainty of the predictive equations, which imply a factor of two or more in predicting A or B for a specified V, is superposed on the uncertainty of forecasting V for the next PF to descend a particular valley. Multiple inundation zones, produced by simulations using a selected range of volumes, partly accommodate these uncertainties. The resulting maps show graphically that PF inundation potentials are highest nearest volcano sources and along valley thalwegs, and diminish with distance from source and lateral distance from thalweg. The model does

  7. Objective rapid delineation of areas at risk from block-and-ash pyroclastic flows and surges (United States)

    Widiwijayanti, C.; Voight, B.; Hidayat, D.; Schilling, S. P.


    Assessments of pyroclastic flow (PF) hazards are commonly based on mapping of PF and surge deposits and estimations of inundation limits, and/or computer models of varying degrees of sophistication. In volcanic crises a PF hazard map may be sorely needed, but limited time, exposures, or safety aspects may preclude fieldwork, and insufficient time or baseline data may be available for reliable dynamic simulations. We have developed a statistically constrained simulation model for block-and-ash type PFs to estimate potential areas of inundation by adapting methodology from Iverson et al. (Geol Soc America Bull 110:972-984, 1998) for lahars. The predictive equations for block-and-ash PFs are calibrated with data from several volcanoes and given by A = (0.05 to 0.1) V 2/3, B = (35 to 40) V 2/3, where A is cross-sectional area of inundation, B is planimetric area and V is deposit volume. The proportionality coefficients were obtained from regression analyses and comparison of simulations to mapped deposits. The method embeds the predictive equations in a GIS program coupled with DEM topography, using the LAHARZ program of Schilling (1998). Although the method is objective and reproducible, any PF hazard zone so computed should be considered as an approximate guide only, due to uncertainties on the coefficients applicable to individual PFs, the authenticity of DEM details, and the volume of future collapses. The statistical uncertainty of the predictive equations, which imply a factor of two or more in predicting A or B for a specified V, is superposed on the uncertainty of forecasting V for the next PF to descend a particular valley. Multiple inundation zones, produced by simulations using a selected range of volumes, partly accommodate these uncertainties. The resulting maps show graphically that PF inundation potentials are highest nearest volcano sources and along valley thalwegs, and diminish with distance from source and lateral distance from thalweg. The model

  8. Holocene block-and-ash flows from summit dome activity of Citlaltépetl volcano, Eastern Mexico (United States)

    Carrasco-Núñez, Gerardo


    A major eruption produced several block-and-ash flows about 4,100 years B.P. at Citlaltépetl volcano (Pico de Orizaba), an ice-capped, 5670-m-high, andesitic, active stratovolcano located at the eastern end of the Mexican Volcanic Belt. Repetitive gravitational collapse of a dacitic dome at the summit crater produced a series of block-and-ash flows, lahars, and floods, which were channeled through two main river-valleys on the west and south flanks of the volcano. The total erupted volume is estimated to be at least 0.27 km 3. The deposits in both areas are similar in composition, and size, but they differ in the area covered, distribution, and structure. The western deposits form a large fan, cover a larger area, and include numerous laharic and fluviatile deposits. In contrast, the southern deposits form prominent terraces where confined in narrow channels, and have associated laharic units in distal areas, where the flows reach a maximum distance of 30 km from the vent. Directed disruptions of a central summit dome occurred, possibly first to the west and then to the southeast, perhaps due to minor modifications of the summit dome morphology, producing the voluminous block-and-ash flow deposits documented here. The flows were strongly controlled by topography, influencing the deposition of the moving particles. Grain-size variations along the flow paths are hardly detectable suggesting no evident lateral downstream transformations. Because sudden changes in dome morphology may cause significant variations in the direction of future dome collapse, specific areas of potential affectation cannot be predicted. Therefore, about 350,000 inhabitants living within a radius of 35-km from the vent could be potentially impacted if catastrophic block-and-ash flows were to recur in the future from similar summit dome activity. Recognition of these deposits is therefore important for hazard assessment because some seemingly safe areas may be at high risk.

  9. GIS-based statistical mapping technique for block-and-ash pyroclastic flow and surge hazards (United States)

    Widiwijayanti, C.; Voight, B.; Hidayat, D.; Schilling, S.


    Assessments of pyroclastic flow (PF) hazards are commonly based on mapping of PF and surge deposits and estimations of inundation limits, and/or computer models of varying degrees of sophistication. In volcanic crises a PF hazard map may be sorely needed, but limited time, exposures, or safety aspects may preclude fieldwork, and insufficient time or baseline data may be available for reliable dynamic simulations. We have developed a statistically constrained simulation model for block-and-ash PFs to estimate potential areas of inundation by adapting methodology from Iverson et al. (1998) for lahars. The predictive equations for block-and-ash PFs are calibrated with data from many volcanoes and given by A = (0.05-0.1)V2/3, B = (35-40)V2/3 , where A is cross-sectional area of inundation, B is planimetric area and V is deposit volume. The proportionality coefficients were obtained from regression analyses and comparison of simulations to mapped deposits. The method embeds the predictive equations in a GIS program coupled with DEM topography, using the LAHARZ program of Schilling (1998). Although the method is objective and reproducible, any PF hazard zone so computed should be considered as an approximate guide only, due to uncertainties on coefficients applicable to individual PFs, DEM details, and release volumes. Gradational nested hazard maps produced by these simulations reflect in a sense these uncertainties. The model does not explicitly consider dynamic behavior, which can be important. Surge impacts must be extended beyond PF hazard zones and we have explored several approaches to do this. The method has been used to supply PF hazard maps in two crises: Merapi 2006; and Montserrat 2006- 2007. We have also compared our hazard maps to actual recent PF deposits and to maps generated by several other model techniques.

  10. Validation of a continuous flow method for the determination of soluble iron in atmospheric dust and volcanic ash. (United States)

    Simonella, Lucio E; Gaiero, Diego M; Palomeque, Miriam E


    Iron is an essential micronutrient for phytoplankton growth and is supplied to the remote areas of the ocean mainly through atmospheric dust/ash. The amount of soluble Fe in dust/ash is a major source of uncertainty in modeling-Fe dissolution and deposition to the surface ocean. Currently in the literature, there exist almost as many different methods to estimate fractional solubility as researchers in the field, making it difficult to compare results between research groups. Also, an important constraint to evaluate Fe solubility in atmospheric dust is the limited mass of sample which is usually only available in micrograms to milligrams amounts. A continuous flow (CF) method that can be run with low mass of sediments (deposited volcanic ash. Both materials tested are easy eroded by wind and are representative of atmospheric dust/ash exported from this region. The uncertainty of the CF method was obtained from seven replicates of one surface sediment sample, and shows very good reproducibility. The replication was conducted on different days in a span of two years and ranged between 8 and 22% (i.e., the uncertainty for the standard method was 6-19%). Compared to other standardized methods, the CF method allows studies of dissolution kinetic of metals and consumes less reagents and time (dust/ash.

  11. Paramagnetic and crystallographic effects of low temperature ashing on human bone and tooth enamel. (United States)

    Tochon-Danguy, H J; Very, J M; Geoffroy, M; Baud, C A


    Low temperature ashing by excited gas (LTA) causes crystallographic and paramagnetic alterations of the human bone and tooth enamel mineral. On the one hand, LTA induces variations of the alpha lattice parameter. These variations depend upon the nature of the gas used, but are little affected by its degree of excitation. Trapping of gas molecules in the crystal structure is demonstrated. On the other hand, LTA produces two preponderant paramagnetic centers in bone and enamel samples at 20 degrees C. Their inorganic origin clearly indicated. One of the two radicals has been identified as O3- (g1 = 2.002, g2 = 2.010, g3 = 2.016) and the other as (CO3-3 (parallel = 1.996, g = perpendicular 2.003). Variations of the alpha lattice parameter and trapping of paramagnetic gas species do not seem to be directly related.

  12. Multiphase flow modelling of volcanic ash particle settling in water using adaptive unstructured meshes


    Jacobs, C.T.; Collins, G S; M. D. Piggott; S. C. Kramer; Wilson, C.R.G.


    Small-scale experiments of volcanic ash particle settling in water have demonstrated that ash particles can either settle slowly and individually, or rapidly and collectively as a gravitationally unstable ash-laden plume. This has important implications for the emplacement of tephra deposits on the seabed. Numerical modelling has the potential to extend the results of laboratory experiments to larger scales and explore the conditions under which plumes may form and persist, but many existing ...

  13. Insight of the fusion behavior of volcanic ash: Implications for Volcanic ash Hazards to Aircraft Safety (United States)

    Song, Wenjia; Hess, Kai-Uwe; Küppers, Ulrich; Scheu, Bettina; Cimarelli, Corrado; Lavallée, Yan; Sohyun, Park; Gattermann, Ulf; Müller, Dirk; Dingwell, Donald Bruce


    The interaction of volcanic ash with jet turbines during via ingestion of ash into engines operating at supra-volcanic temperatures is widely recognized as a potentially fatal hazard for jet aircraft. In the past 12 years, more than 60 modern jet airplanes, mostly jumbo jets, have been damaged by drifting clouds of volcanic ash that have contaminated air routes and airport facilities. Seven of these encounters are known to have caused in flight loss of engine power to jumbo jets carrying a total of more than 2000 passengers. The fusibility of volcanic ash is believed to impact strongly its deposition in the hotter parts of jet engines. Despite this, explicit investigation of ash sintering using standardized techniques is in its infancy. Volcanic ash may vary widely in its physical state and chemical composition between and even within explosive volcanic eruptions. Thus a comparative study of the fusibility of ash which involves a standard recognized techniques would be highly desirable. In this work, nine samples of fine ash, deposited from co-pyroclastic offrom nine different volcanoes which cover a broad range of chemical composition, were investigated. Eight of them were collected from 2001-2009 eruptions. Because of the currently elevated level of eruptive activity and its potential hazards to aircraft safety and the remaining one sample was collected from a 12,121 ± 114 yr B.P. eruption. We used the method of accessing the behavior of deposit-forming impurities in high temperature boiler plants on the basis of observations of the change in shape and size of a cylindrical coal ash to study the fusion phenomena as well as determine the volcanic ash melting behavior by defining four characteristic temperatures (shrinkage temperature, deformation temperature, hemispherical temperature, and flow temperature) by means of heating microscope instrument and different thermal analysis methods. Here, we find that there are similar sticking ability and flow behavior of

  14. Non-equilibrium processes in ash-laden volcanic plumes: new insights from 3D multiphase flow simulations (United States)

    Esposti Ongaro, Tomaso; Cerminara, Matteo


    In the framework of the IAVCEI (International Association of Volcanology and Chemistry of the Earth Interior) initiative on volcanic plume models intercomparison, we discuss three-dimensional numerical simulations performed with the multiphase flow model PDAC (Pyroclastic Dispersal Analysis Code). The model describes the dynamics of volcanic and atmospheric gases (in absence of wind) and two pyroclastic phases by adopting a non-equilibrium Eulerian-Eulerian formulation. Accordingly, gas and particulate phases are treated as interpenetrating fluids, interacting with each other through momentum (drag) and heat exchange. Numerical results describe the time-wise and spatial evolution of weak (mass eruption rate: 1.5 × 106 kg/s) and strong (mass eruption rate: 1.5 × 109 kg/s) plumes. The two tested cases display a remarkably different phenomenology, associated with the different roles of atmospheric stratification, compressibility and mechanism of buoyancy reversal, reflecting in a different structure of the plume, of the turbulent eddies and of the atmospheric circulation. This also brings about different rates of turbulent mixing and atmospheric air entrainment. The adopted multiphase flow model allows to quantify temperature and velocity differences between the gas and particles, including settling, preferential concentration by turbulence and thermal non-equilibrium, as a function of their Stokes number, i.e., the ratio between their kinetic equilibrium time and the characteristic large-eddy turnover time of the turbulent plume. As a result, the spatial and temporal distribution of coarse ash in the atmosphere significantly differs from that of the fine ash, leading to a modification of the plume shape. Finally, three-dimensional numerical results have been averaged in time and across horizontal slices in order to obtain a one-dimensional picture of the plume in a stationary regime. For the weak plume, the results are consistent with one-dimensional models, at

  15. ACARP Project C8050. Making the ash fusion temperature test useful

    Energy Technology Data Exchange (ETDEWEB)

    Juniper, L.; Huber, G.; Jak, E.; Creelman, R.; Wall, T. [Ultra Systems Technology Pty. Ltd., Indooroopilly, Qld. (Australia)


    The report addresses uncertainties with the standard AFT test, including the lack of existing correlations between the AFT measurement and the ash melting characteristics and the errors associated with the test due to operator inconsistencies. The investigations provide a link between AFT and the melting characteristics of coal ash, and between the melting characteristics of coal ash and the chemical constituents in the ash; and developed a basis for a more accurate AFT measurement based on digital imaging techniques, and explored the possibility of extracting additional information on melting behaviour from the AFT test. 17 refs., 6 figs.

  16. Soil application of ash produced by low-temperature fluidized bed gasification: effects on soil nutrient dynamics and crop response

    DEFF Research Database (Denmark)

    Müller-Stöver, Dorette Sophie; Ahrenfeldt, Jesper; Holm, Jens Kai


    Recycling of residual products of bioenergy conversion processes is important for adding value to the technologies and as a potential beneficial soil fertility amendment. In this study, two different ash materials originating from low temperature circulating fluidized bed (LT-CFB) gasification...... of either wheat straw (SA) or residue fibers mainly from citrus peels (CP) were tested regarding their potential to be used as fertilizer on agricultural soils. A soil incubation study, a greenhouse experiment with barley and faba bean, and an accompanying outdoor experiment with maize were carried out...... to investigate the effects of the ashes on soil microbiological and chemical properties and on the response of the three crops. The ash treatments were compared with a control treatment that received only nitrogen, magnesium, and sulphur (CO) and a fully fertilized control (COPK). Soil microbial parameters were...

  17. Low-temperature catalytic oxidation of aldehyde mixtures using wood fly ash: kinetics, mechanism, and effect of ozone. (United States)

    Kolar, Praveen; Kastner, James R


    Poultry rendering emissions contain volatile organic compounds (VOCs) that are nuisance, odorous, and smog and particulate matter precursors. Present treatment options, such as wet scrubbers, do not eliminate a significant fraction of the VOCs emitted including, 2-methylbutanal (2-MB), 3-methylbutanal, and hexanal. This research investigated the low-temperature (25-160 degrees C) catalytic oxidation of 2-MB and hexanal vapors in a differential, plug flow reactor using wood fly ash (WFA) as a catalyst and oxygen and ozone as oxidants. The oxidation rates of 2-MB and hexanal ranged between 3.0 and 3.5 x 10(-9)mol g(-1)s(-1) at 25 degrees C and the activation energies were 2.2 and 1.9 kcal mol(-1), respectively. The catalytic activity of WFA was comparable to other commercially available metal and metal oxide catalysts. We theorize that WFA catalyzed a free radical reaction in which 2-butanone and CO(2) were formed as end products of 2-MB oxidation, while CO(2), pentanal, and butanal were formed as end products of hexanal oxidation. When tested as a binary mixture at 25 and 160 degrees C, no inhibition was observed. Additionally, when ozone was tested as an oxidant at 160 degrees C, 100% removal was achieved within a 2-s reaction time. These results may be used to design catalytic oxidation processes for VOC removal at poultry rendering facilities and potentially replace energy and water intensive air pollution treatment technologies currently in use.

  18. Effects of ash forming temperature on water-soluble fraction of biomass ash and it’s elements%成灰温度对三种生物质灰及其元素水溶性的影响

    Institute of Scientific and Technical Information of China (English)

    何芳; 于如军; 张毅; 朱继英; 高振强; 孙鹏


    The implementation of biomass ash as a fertilizer is beneficial to the sustainable development of agriculture because it can return the elements taken by the plants from soil during the growth. Water solubility of biomass ash together with its elements is a vital property for the fertilizer’s utilization. In this paper, the effects of ash forming temperature on the water solubility of biomass ash and its elements were investigated experimentally. Three typical types of agro-residues in China, i.e. wheat straw, corn stover and rice husk, were chosen for investigation. Materials were collected and the corresponding proximate and elemental analyses were performed. In preparation process, wheat straw and corn stover were milled into powder with the particle size of less than 1 mm. Ashes were prepared in a muffle furnace at different ash forming temperatures in the scope from 400 to 800℃with the temperature interval of 50℃. About 4-5 g of each sample powder and rice husk were put in the crucibles, heated from ambient temperature to ash forming temperature, and then kept at the ash forming temperature for 4 hours in the muffle furnace. After the temperature of the furnace dropped to less than 200℃, the ashes were taken out to the cabinet dryer, cooled to the ambient temperature, and then weighted and sealed in the sample bag for further measurements. It showed that ash contents of wheat straw, corn stover and rice husk decreased significantly with the increase of ash forming temperature. They decreased from 9.8%, 10.9%and 18.4% at 400℃to 6.9%, 8.7%and 16.8%at 800℃respectively. After the preparation of all the ash, two types of measurements were performed. The first was the water solubility measurement of the ashes according to the standard of GB8307-2002. Total ash of about 0.2-0.3 g was put in a beaker of 50 ml and about 25 ml distilled water was added in it. The mixture was heated and boiled for 2 min and then the solution was filtered through a

  19. Hydrothermal Synthesis of Zeolite from Coal Class F Fly Ash. Influence of Temperature

    Directory of Open Access Journals (Sweden)

    Goñi, S.


    Full Text Available The influence of temperature of alkaline hydrothermal treatment on the conversion in zeolite of Spanish coal low calcium-fly ash (ASTM class F is presented in this work. Zeolite Na-P1 gismondine type (Na6Al6Si10O32.12H2O was formed at the temperature of 100ºC, which transformed in zeolite; analcime-C type (Na(Si2AlO6H2O and sodalite (1.08 Na2O.Al2O3.1.68SiO2.1.8H2O at 200ºC together with traces of tobermorite-11Å (Ca5(OH2Si6O16.4H2O. At this temperature the 100% of the fly ash reaction was allowed. An equivalent study was carried out in water as reference. The zeolite conversion of the fly ash was characterized by X ray diffraction (XRD, FT infrared (FTIR spectroscopy, surface area (BET-N2 and thermal analyses.

    En este trabajo se presenta el papel que juega la temperatura durante el tratamiento hidrotermal en medio alcalino para convertir una ceniza volante de bajo contenido en cal (clase F, según la norma ASTM en zeolita. Durante este tratamiento a la temperatura de 100ºC se forma Zeolita Na-P1 tipo gismondina (Na6Al6Si10O32.12H2O; al elevar la temperatura a 200ºC, dicha zeolita se transforma en zeolita Analcima C (Na(Si2AlO6H2O y en fase sodalita (1.08 Na2O.Al2O3.1.68SiO2.1.8H2O junto con trazas de tobermorita-11Å (Ca5(OH2Si6O16.4H2O. A esta temperatura y en estas condiciones se ha conseguido un 100% de reacción. Un estudio equivalente se ha llevado a cabo empleando agua como medio de referencia. La conversión de ceniza volante en zeolita se ha caracterizado mediante técnicas, como difracción de Rayos X (DRX, espectroscopia

  20. Sintesis ZSM-5 dari Fly Ash Sawit Sebagai Sumber Silika dengan Variasi Nisbah Molar Si/Al dan Temperatur Sintesis

    Directory of Open Access Journals (Sweden)

    Ida Zahrina


    Full Text Available Palm fly ash is biomass/waste in the  palm oil industry. Palm fly ash has high content of amorphous silica. ZSM-5 is one of synthetic zeolite which is widely used as catalyst in industries. ZSM-5 has high activity and selectivity to several hydrocarbon conversion reaction. Hence, ZSM-5 is being investigated for the conversion of vegetable oil to hydrocarbon.  It can be synthesized from silica and alumina. Sources of silica that can be added to the ZSM-5 synthesis,  are sodium silicate, hydrated silica, water glass sol silica, gelled silica, clay, precipitated silicaand calcined silica. ZSM-5 was synthesized free-template by using palm fly ash as silica source. In this research synthesis of ZSM-5 was carried out in autoclave at 18 hours and Na2O/Al2O3 molar ratio by various molar ratio from 30 to 40 and temperature in the range of 150 to 190 oC. The product was then analized using FTIR method. The best ZSM-5 product was obtained at Si/Al molar ratio of 40 and process temperature of 150 oC. Keywords: FTIR, Palm fly ash, ZSM-5

  1. Synthesis of zeolite from Italian coal fly ash: differences in crystallization temperature using seawater instead of distilled water. (United States)

    Belviso, Claudia; Cavalcante, Francesco; Fiore, Saverio


    In this study Italian coal fly ash was converted into several types of zeolite in laboratory experiments with temperatures of crystallization ranging from 35 up to 90 degrees C. Distilled and seawater were used during the hydrothermal synthesis process in separate experiments, after a pre-treatment fusion with NaOH. The results indicate that zeolites could be formed from different kind of Italian coal fly ash at low temperature of crystallization using both distilled and seawater. SEM data and the powder patterns of X-ray diffraction analysis show that faujasite, zeolite ZK-5 and sodalite were synthesized when using both distilled and seawater; zeolite A crystallized only using distilled water. In particular the experiments indicate that the synthesis of zeolite X and zeolite ZK-5 takes place at lower temperatures when using seawater (35 and 45 degrees C, respectively). The formation of sodalite is always competitive with zeolite X which shows a metastable behaviour at higher temperatures (70-90 degrees C). The chemical composition of the fly ash source could be responsible of the differences on the starting time of synthesized zeolite with distilled water, in any case our data show that the formation of specific zeolites takes place always at lower temperatures when using seawater.

  2. Fly ash-reinforced thermoplastic starch composites

    Energy Technology Data Exchange (ETDEWEB)

    Ma, X.F.; Yu, J.G.; Wang, N. [Tianjin University, Tianjin (China). School of Science


    As a by-product from the combustion of pulverized coal, fly ash was, respectively, used as the reinforcement for formamide and urea-plasticized thermoplastic starch (FUPTPS) and glycerol-plasticized thermoplastic starch (GPTPS). The introduction of fly ash improved tensile stress from 4.56 MPa to 7.78 MPa and Youngs modulus increased trebly from 26.8 MPa to 84.6 MPa for fly ash-reinforced FUPTPS (A-FUPTPS), while tensile stress increased from 4.55 MPa to 12.86 MPa and Youngs modulus increased six times from 76.4 MPa to 545 MPa for fly ash-reinforced GPTPS (A-GPTPS). X-ray diffractograms illustrated that fly ash destroyed the formation of starch ordered crystal structure, so both A-GPTPS and FUPTPS could resist the starch re-crystallization (retrogradation). Also fly ash improved water resistance of TPS. As shown by rheology, during the thermoplastic processing, the extruder screw speed effectively adjusted the flow behavior of A-FUPTPS, while the increasing of the processing temperature effectively ameliorated the flow behavior of A-GPTPS. However, superfluous ash contents (e.g., 20 wt%) worsened processing fluidity and resulted in the congregation of fly ash in FUPTPS matrix (tested by SEM) rather than in GPTPS matrix. This congregation decreased the mechanical properties and water resistance of the materials.

  3. Experimental evidence for de novo synthesis of PBDD/PBDF and PXDD/PXDF as well as dioxins in the thermal processes of ash samples

    Energy Technology Data Exchange (ETDEWEB)

    Kawamoto, K.; Ishikawa, N. [National Inst. for Environmental Studies, Tsukuba (Japan)


    Fly ash in gasification-melting plants and conventional incineration plants can form dioxins through a process known as de novo synthesis. This paper investigated the de novo synthesis of dioxins formed as a result of fly ash catalysis activities. Thermal experiments using fly ash were performed using a flow-through reactor to investigate the formation of brominated and chlorinated-brominated dibenzodioxins (PBDD/F) and dibenzofurans (PXDD/F). Ash samples were collected at conventional stoker incineration and gasification-melting plants. Samples included ash from a bag filter (Ash A); ash from a fluidized gasification and melting furnace plant (Ash C); boiler ash (Ash B); and ash containing tetrabromobisphenol (Ash D). Samples were subjected to a thermal treatment at 300 degrees C. Results showed that dioxin levels were very high for Ash A, which suggested that temperature had a significant influence on de novo synthesis. Dioxin concentrations for Ash C had a relatively low carbon content. Considerable concentrations of PXDD/PXDF were determined for Ash A. High PBDD, PBDF, PXDD and PXDF were observed for Ash D and Ash B. The total amount of dioxins in Ash A were relatively slow to change before and after the thermal treatment of the sample. The homologue distribution patterns of PCDD and PCDF in Ash A showed significant alterations after treatment. It was concluded that de novo dioxin synthesis occurred during the experimental procedure. Results suggested that carbon content plays an important role in the production of dioxins. 3 refs., 2 tabs., 4 figs.

  4. CO2 uptake capacity of coal fly ash: Influence of pressure and temperature on direct gas-solid carbonation

    DEFF Research Database (Denmark)

    Mazzella, Alessandro; Errico, Massimiliano; Spiga, Daniela


    range 1 ÷ 7.5 bar the CO2 uptake increased with temperature, shortening the time required to capture higher percentage of CO2. Conversely, in the pressure range 10 ÷ 15 bar, the carbonation kinetics slowed down and the effect of temperature was less evident. The best CO2 uptake was found to be 18.2 wt......-solid carbonation treatment on coal fly ash in order to assess the potential of the process in terms of sequestration of CO2 as well as its influence on the leaching behavior of metals and soluble salts. Laboratory tests, performed under different pressure and temperature conditions, showed that in the pressure......% corresponding to a maximum carbonation efficiency of 74%, estimated on the basis of the initial CaO content. The high degree of ash carbonation achieved in the present research, which was conducted under mild conditions, without add of water and without stirring, showed the potential use of coal fly ash in CO2...

  5. Impact of coal fly ash addition on ash transformation and deposition in a full-scale wood suspension-firing boiler

    DEFF Research Database (Denmark)

    Wu, Hao; Bashir, Muhammad Shafique; Jensen, Peter Arendt;


    Ash transformation and deposition during pulverized wood combustion in a full-scale power plant boiler of 800 MWth were studied with and without the addition of coal fly ash. The transient ash deposition behavior was characterized by using an advanced deposit probe system at two boiler locations...... constant after a few hours. The formed deposits, especially those at the location with low flue gas temperatures, contained a considerable amount of K2SO4, KCl, and KOH/K2CO3. With the addition of a large amount (about 4 times of the mass flow of wood ash) of coal fly ash to the boiler, these alkali...

  6. Zeolite synthesis from paper sludge ash at low temperature (90 degrees C) with addition of diatomite. (United States)

    Wajima, Takaaki; Haga, Mioko; Kuzawa, Keiko; Ishimoto, Hiroji; Tamada, Osamu; Ito, Kazuhiko; Nishiyama, Takashi; Downs, Robert T; Rakovan, John F


    Paper sludge ash was partially converted into zeolites by reaction with 3M NaOH solution at 90 degrees C for 24 h. The paper sludge ash had a low abundance of Si and significant Ca content, due to the presence of calcite that was used as a paper filler. Diatomite was added to the NaOH solution to increase its Si content in order to synthesize zeolites with high cation exchange capacity. Diatomite residue was filtered from solution before addition of ash. The original ash without addition of diatomite yielded hydroxysodalite with a cation exchange capacity ca. 50 cmol/kg. Addition of Si to the solution yielded Na-P1 (zeolite-P) with a higher cation exchange capacity (ca. 130 cmol/kg). The observed concentrations of Si and Al in the solution during the reaction explain the crystallization of these two phases. The reaction products were tested for their capacity for PO(4)(3-) removal from solution as a function of Ca(2+) content, suggesting the formation of an insoluble Ca-phosphate salt. The product with Na-P1 exhibits the ability to remove NH(4)(+) as well as PO(4)(3-) from solution in concentrations sufficient for application in water purification. Both NH(4)(+) and PO(4)(3-) removal showed little variation with pH between 5 and 9. Alternative processing methods of zeolite synthesis, including the addition of ash to an unfiltered Si-NaOH solution and addition of a dry ash/diatomite mixture to NaOH solution, were tested. The third process yielded materials with lower cation exchange capacity due to formation of hydroxysodalite. The second process results in a product with relatively high cation exchange capacity, and reduces the number of processing steps necessary for zeolite synthesis.

  7. Trace element partitioning in ashes from boilers firing pure wood or mixtures of solid waste with respect to fuel composition, chlorine content and temperature. (United States)

    Saqib, Naeem; Bäckström, Mattias


    Trace element partitioning in solid waste (household waste, industrial waste, waste wood chips and waste mixtures) incineration residues was investigated. Samples of fly ash and bottom ash were collected from six incineration facilities across Sweden including two grate fired and four fluidized bed incinerators, to have a variation in the input fuel composition (from pure biofuel to mixture of waste) and different temperature boiler conditions. As trace element concentrations in the input waste at the same facilities have already been analyzed, the present study focuses on the concentration of trace elements in the waste fuel, their distribution in the incineration residues with respect to chlorine content of waste and combustion temperature. Results indicate that Zn, Cu and Pb are dominating trace elements in the waste fuel. Highly volatile elements mercury and cadmium are mainly found in fly ash in all cases; 2/3 of lead also end up in fly ash while Zn, As and Sb show a large variation in distribution with most of them residing in the fly ash. Lithophilic elements such as copper and chromium are mainly found in bottom ash from grate fired facilities while partition mostly into fly ash from fluidized bed incinerators, especially for plants fuelled by waste wood or ordinary wood chips. There is no specific correlation between input concentration of an element in the waste fuel and fraction partitioned to fly ash. Temperature and chlorine content have significant effects on partitioning characteristics by increasing the formation and vaporization of highly volatile metal chlorides. Zinc and cadmium concentrations in fly ash increase with the incineration temperature.

  8. Fusion characterization of biomass ash

    DEFF Research Database (Denmark)

    Ma, Teng; Fan, Chuigang; Hao, Lifang;


    The ash fusion characteristics are important parameters for thermochemical utilization of biomass. In this research, a method for measuring the fusion characteristics of biomass ash by Thermo-mechanical Analyzer, TMA, is described. The typical TMA shrinking ratio curve can be divided into two...... stages, which are closely related to ash melting behaviors. Several characteristics temperatures based on the TMA curves are used to assess the ash fusion characteristics. A new characteristics temperature, Tm, is proposed to represent the severe melting temperature of biomass ash. The fusion...... characteristics of six types of biomass ash have been measured by TMA. Compared with standard ash fusibility temperatures (AFT) test, TMA is more suitable for measuring the fusion characteristics of biomass ash. The glassy molten areas of the ash samples are sticky and mainly consist of K-Ca-silicates....

  9. Effect of antecedent-hydrological conditions on rainfall triggering of debris flows in ash-fall pyroclastic mantled slopes of Campania (southern Italy) (United States)

    Napolitano, E.; Fusco, F; Baum, Rex L.; Godt, Jonathan W.; De Vita, P.


    Mountainous areas surrounding the Campanian Plain and the Somma-Vesuvius volcano (southern Italy) are among the most risky areas of Italy due to the repeated occurrence of rainfallinduced debris flows along ash-fall pyroclastic soil-mantled slopes. In this geomorphological framework, rainfall patterns, hydrological processes taking place within multi-layered ash-fall pyroclastic deposits and soil antecedent moisture status are the principal factors to be taken into account to assess triggering rainfall conditions and the related hazard. This paper presents the outcomes of an experimental study based on integrated analyses consisting of the reconstruction of physical models of landslides, in situ hydrological monitoring, and hydrological and slope stability modeling, carried out on four representative source areas of debris flows that occurred in May 1998 in the Sarno Mountain Range. The hydrological monitoring was carried out during 2011 using nests of tensiometers and Watermark pressure head sensors and also through a rainfall and air temperature recording station. Time series of measured pressure head were used to calibrate a hydrological numerical model of the pyroclastic soil mantle for 2011, which was re-run for a 12-year period beginning in 2000, given the availability of rainfall and air temperature monitoring data. Such an approach allowed us to reconstruct the regime of pressure head at a daily time scale for a long period, which is representative of about 11 hydrologic years with different meteorological conditions. Based on this simulated time series, average winter and summer hydrological conditions were chosen to carry out hydrological and stability modeling of sample slopes and to identify Intensity- Duration rainfall thresholds by a deterministic approach. Among principal results, the opposing winter and summer antecedent pressure head (soil moisture) conditions were found to exert a significant control on intensity and duration of rainfall

  10. Shedding of ash deposits

    DEFF Research Database (Denmark)

    Zbogar, Ana; Frandsen, Flemming; Jensen, Peter Arendt;


    Ash deposits formed during fuel thermal conversion and located on furnace walls and on convective pass tubes, may seriously inhibit the transfer of heat to the working fluid and hence reduce the overall process efficiency. Combustion of biomass causes formation of large quantities of troublesome...... ash deposits which contain significant concentrations of alkali, and earth-alkali metals. The specific composition of biomass deposits give different characteristics as compared to coal ash deposits, i.e. different physical significance of the deposition mechanisms, lower melting temperatures, etc....... Low melting temperatures make straw ashes especially troublesome, since their stickiness is higher at lower temperatures, compared to coal ashes. Increased stickiness will eventually lead to a higher collection efficiency of incoming ash particles, meaning that the deposit may grow even faster...

  11. Survey and conceptual flow sheets for coal conversion plant handling-preparation and ash/slag removal operations

    Energy Technology Data Exchange (ETDEWEB)

    Zapp, F.C.; Thomas, O.W.; Silverman, M.D.; Dyslin, D.A.; Holmes, J.M.


    This study was undertaken at the request of the Fossil Fuel Processing Division of the Department of Energy. The report includes a compilation of conceptual flow sheets, including major equipment lists, and the results of an availability survey of potential suppliers of equipment associated with the coal and ash/slag operations that will be required by future large coal conversion plant complexes. Conversion plant flow sheet operations and related equipment requirements were based on two representative bituminous coals - Pittsburgh and Kentucky No. 9 - and on nine coal conversion processes. It appears that almost all coal handling and preparation and ash/slag removal equipment covered by this survey, with the exception of some coal comminution equipment, either is on hand or can readily be fabricated to meet coal conversion plant capacity requirements of up to 50,000 short tons per day. Equipment capable of handling even larger capacities can be developed. This approach appears to be unjustified, however, because in many cases a reasonable or optimum number of trains of equipment must be considered when designing a conversion plant complex. The actual number of trains of equipment selected will be influenced by the total requied capacity of the complex, the minimum on-line capacity that can be tolerated in case of equipment failure, reliability of specific equipment types, and the number of reactors and related feed injection stations needed for the specific conversion process.

  12. Magnetic, structural and geochronologic evidence bearing on volcanic sources and Oligocene Deformation of Ash Flow Tuffs, northeast Nevada (United States)

    Palmer, H. C.; MacDonald, W. D.; Hayatsu, A.


    Magnetic properties of mid-Tertiary volcanic rocks west of Jiggs in northeast Nevada were investigated for the purposes of interpreting igneous, structural, and tectonic processes in this part of the Basin and Range province. Anisotropy of magnetic susceptibility (AMS) patterns reflect flow fabrics and suggest previously unknown sources for these ash flow tuffs. Paleomagnetic and structural evidence suggest counterclockwise relative rotation of the southern part of the area with respect to the north. New stratigraphic, chemical and K-Ar isotopic data support these interpretations. Dacite to rhyolite ash flow tuffs of the Indian Well Formation were subdivided into two main units: the lower and predominant tuff of Jiggs (35.8-37.0 Ma) and the unconformably overlying but areally restricted tuff of Hackwood (30.8 Ma). The Jiggs unit has two polarities whereas the Hackwood has only a reversed polarity remanence. Together these units with tilt correction define a pole (92°E, 87°N, dp = 6°, dm = 8°) for approximately 30-37 Ma. This pole is concordant with coeval North American reference poles, indicating that this zone of approximately 30 km NS extent has not undergone significant vertical axis rotation relative to the North American reference. Andesite lavas of normal magnetic polarity and of 32.5-Ma age characterize the Diamond Hills immediately to the south. We interpret this region, from both structural evidence and discordant paleomagnetic direction, to have rotated approximately 25° counterclockwise relative to the Indian Well volcanic units to the north. The apparent rotation of the Diamond Hills is possibly the result of drag on the left-lateral Garcia fault which limits the Diamond Hills on the southwest. Analysis of AMS data suggests, by patterns of the K1 axes, two distinct sources for the Jiggs unit: a northern buried source and a central partially buried source. Lithologic evidence consistent with proximal vent facies is found near the latter source. An

  13. A fast Eulerian multiphase flow model for volcanic ash plumes: turbulence, heat transfer and particle non-equilibrium dynamics. (United States)

    Cerminara, Matteo; Esposti Ongaro, Tomaso; Carlo Berselli, Luigi


    We have developed a compressible multiphase flow model to simulate the three-dimensional dynamics of turbulent volcanic ash plumes. The model describes the eruptive mixture as a polydisperse fluid, composed of different types of gases and particles, treated as interpenetrating Eulerian phases. Solid phases represent the discrete ash classes into which the total granulometric spectrum is discretized, and can differ by size and density. The model is designed to quickly and accurately resolve important physical phenomena in the dynamics of volcanic ash plumes. In particular, it can simulate turbulent mixing (driving atmospheric entrainment and controlling the heat transfer), thermal expansion (controlling the plume buoyancy), the interaction between solid particles and volcanic gas (including kinetic non-equilibrium effects) and the effects of compressibility (over-pressured eruptions and infrasonic measurements). The model is based on the turbulent dispersed multiphase flow theory for dilute flows (volume concentration <0.001, implying that averaged inter-particle distance is larger than 10 diameters) where particle collisions are neglected. Moreover, in order to speed up the code without losing accuracy, we make the hypothesis of fine particles (Stokes number <0.2 , i.e., volcanic ash particles finer then a millimeter), so that we are able to consider non-equilibrium effects only at the first order. We adopt LES formalism (which is preferable in transient regimes) for compressible flows to model the non-linear coupling between turbulent scales and the effect of sub-grid turbulence on the large-scale dynamics. A three-dimensional numerical code has been developed basing on the OpenFOAM computational framework, a CFD open source parallel software package. Numerical benchmarks demonstrate that the model is able to capture important non-equilibrium phenomena in gas-particle mixtures, such as particle clustering and ejection from large-eddy turbulent structures, as well

  14. Conceptual flow sheets development for coal conversion plant coal handling-preparation and ash/slag removal operations

    Energy Technology Data Exchange (ETDEWEB)


    This report presents 14 conceptual flow sheets and major equipment lists for coal handling and preparation operations that could be required for future, commercial coal conversion plants. These flow sheets are based on converting 50,000 tons per day of clean coal representative of the Pittsburgh and Kentucky No. 9 coal seams. Flow sheets were used by Union Carbide Corporation, Oak Ridge National Laboratory, in a survey of coal handling/preparation equipment requirements for future coal conversion plants. Operations covered in this report include run-of-mine coal breaking, coarse coal cleaning, fine coal cleaning, live storage and blending, fine crushing (crushing to top sizes ranging from 1/4-inch to 20 mesh), drying, and grinding (70 percent minus 200 mesh). Two conceptual flow sheets and major equipment lists are also presented for handling ash or granulated slag and other solid wastes produced by nine leading coal conversion processes. These flow sheets provide for solid wastes transport to an environmentally acceptable disposal site as either dry solids or as a water slurry.

  15. Effect of high temperature curing on the compressive strength of concrete incorporating large volumes of fly ash

    Energy Technology Data Exchange (ETDEWEB)

    Rivera-Villarreal, R. [Universidad Autonoma de Nuevo Leon, Monterrey (Mexico)


    The effect of using different types of heat treatment on the compressive strength of concrete with and without large volumes of fly ash was studied. Curing of concrete is important to obtain a good quality concrete, but it is important to keep concrete from drying until the originally water-filled space in fresh cement paste has been filled to the desired extent by the products of hydration. In hot weather, high temperature promotes faster drying of concrete so a given degree of hydration is reached more rapidly than at lower temperatures. The provision of moist curing is advantageous because of a gradual gain in strength and because of reduced plastic shrinkage and drying shrinkage-cracking. The portland cement content in all the mixtures used in this study was 200 kg per cubic metre and the amount of fly ash varied from 0 to 33, 43, 50 and 56 per cent by mass of the total binder. A superplasticizer was used to obtain 200-220 mm slump. The compressive strength was tested at 3, 7, 14, 28, 56 days and at 6 months. Results showed that, using ASTM standard curing, the compressive strength of portland cement concrete made at 35 degrees C was reduced by about 12 per cent at 28 days compared to that of the concrete made at 23 degrees C. The AASHTO curing strength was found to be a bit higher than with the ASTM curing. The concrete made at 35 degrees C showed no loss of strength when continuous moist-curing was applied. The fly ash concrete mixtures that were cast at 35 degrees C were cured by covering them with membrane curing compounds and placed under ambient conditions. It was crucial to allow enough curing water to promote the pozzolanic reaction. The membrane curing did not allow the ingress of water to the concrete mass. 6 refs., 4 tabs., 13 figs.

  16. Turbulent Flow past High Temperature Surfaces (United States)

    Mehmedagic, Igbal; Thangam, Siva; Carlucci, Pasquale; Buckley, Liam; Carlucci, Donald


    Flow over high-temperature surfaces subject to wall heating is analyzed with applications to projectile design. In this study, computations are performed using an anisotropic Reynolds-stress model to study flow past surfaces that are subject to radiative flux. The model utilizes a phenomenological treatment of the energy spectrum and diffusivities of momentum and heat to include the effects of wall heat transfer and radiative exchange. The radiative transport is modeled using Eddington approximation including the weighted effect of nongrayness of the fluid. The time-averaged equations of motion and energy are solved using the modeled form of transport equations for the turbulence kinetic energy and the scalar form of turbulence dissipation with an efficient finite-volume algorithm. The model is applied for available test cases to validate its predictive capabilities for capturing the effects of wall heat transfer. Computational results are compared with experimental data available in the literature. Applications involving the design of projectiles are summarized. Funded in part by U.S. Army, ARDEC.

  17. Ecotoxicological analysis of fly ash and rice-straw black carbon on Microcystis aeruginosa using flow cytometry. (United States)

    Lou, Liping; Yue, Qiankun; Liu, Feixiang; Chen, Fang; Hu, Baolan; Chen, Yingxu


    Black carbon (BC) has a strong affinity for hydrophobic organic compounds (HOCs), and it is a potential material to control HOCs pollution in aquatic ecosystems. Here, flow cytometry (FCM) was used to evaluate the ecotoxicological effect of fly ash, rice-straw ash, and their acid-demineralised products on the growth of Microcystis aeruginosa. It was found that the BCs had little negative effect on cyanobacteria, when the content of BCs was not above 1mgml(-1). However, higher doses of BCs (>2mgml(-1)) had an obvious negative effect on cell density and esterase activity, especially for BCs with acid treatment, which greatly inhibited cell density caused by its high adsorptivity for cyanobacteria. The BCs had little impact on the fluorescence intensity, only with a slight stimulation in later period, so the fluorescence intensity was a less sensitive indicator than cell density and esterase activity. Considering ecotoxicological effect of BCs on the algae, the application concentration of BCs for HOCs pollution control as in situ remediation material would better not exceed 1mgml(-1).

  18. Ash Properties of Alternative Biomass

    DEFF Research Database (Denmark)

    Capablo, Joaquin; Jensen, Peter Arendt; Pedersen, Kim Hougaard


    The ash behavior during suspension firing of 12 alternative solid biofuels, such as pectin waste, mash from a beer brewery, or waste from cigarette production have been studied and compared to wood and straw ash behavior. Laboratory suspension firing tests were performed on an entrained flow...... analysis into three main groups depending upon their ash content of silica, alkali metal, and calcium and magnesium. To further detail the biomass classification, the relative molar ratio of Cl, S, and P to alkali were included. The study has led to knowledge on biomass fuel ash composition influence...... on ash transformation, ash deposit flux, and deposit chlorine content when biomass fuels are applied for suspension combustion....

  19. Effects of ambient temperature on egg and larval development of the invasive emerald ash borer (Coleoptera: Buprestidae): implications for laboratory rearing. (United States)

    Duan, Jian J; Watt, Tim; Taylor, Phil; Larson, Kristi; Lelito, Jonathan P


    The emerald ash borer, Agrilus planipennis Fairmaire, an invasive beetle from Asia causing large scale ash (Fraxinus) mortality in North America, has been extremely difficult to rear in the laboratory because of its long life cycle and cryptic nature of immature stages. This lack of effective laboratory-rearing methods has not only hindered research into its biology and ecology, but also mass production of natural enemies for biological control of this invasive pest. Using sticks from the alternate host plant, Fraxinus uhdei (Wenzig) Lingelsh, we characterized the stage-specific development time and growth rate of both emerald ash borer eggs and larvae at different constant temperatures (12-35 degrees C) for the purpose of developing effective laboratory-rearing methods. Results from our study showed that the median time for egg hatching decreased from 20 d at 20 degrees C to 7 d at 35 degrees C, while no emerald ash borer eggs hatched at 12 degrees C. The developmental time for 50% of emerald ash borer larvae advancing to third, fourth, and J-larval stages at 20 degrees C were 8.3, 9.1, and 12.3 wk, respectively, approximately two times longer than at 30 degrees C for the corresponding instars or stages. In contrast to 30 degrees C, however, the development times of emerald ash borer larvae advancing to later instars (from oviposition) were significantly increased at 35 degrees C, indicating adverse effects of this high temperature. The optimal range of ambient temperature to rear emerald ash borer larvae should be between 25-30 degrees C; however, faster rate of egg and larval development should be expected as temperature increases within this range.

  20. Ash reduction system using electrically heated particulate matter filter (United States)

    Gonze, Eugene V [Pinckney, MI; Paratore, Jr., Michael J; He, Yongsheng [Sterling Heights, MI


    A control system for reducing ash comprises a temperature estimator module that estimates a temperature of an electrically heated particulate matter (PM) filter. A temperature and position estimator module estimates a position and temperature of an oxidation wave within the electrically heated PM filter. An ash reduction control module adjusts at least one of exhaust flow, fuel and oxygen levels in the electrically heated PM filter to adjust a position of the oxidation wave within the electrically heated PM filter based on the oxidation wave temperature and position.

  1. Simultaneous Temperature and Velocity Diagnostic for Reacting Flows Project (United States)

    National Aeronautics and Space Administration — A diagnostic technique is proposed for measuring temperature and velocity simultaneously in a high temperature reacting flow for aiding research in propulsion. The...

  2. Removal of fly-ash and dust particulate matters from syngas produced by gasification of coal by using a multi-stage dual-flow sieve plate wet scrubber. (United States)

    Kurella, Swamy; Meikap, Bhim Charan


    In this work, fly-ash water scrubbing experiments were conducted in a three-stage lab-scale dual-flow sieve plate scrubber to observe the performance of scrubber in fly-ash removal at different operating conditions by varying the liquid rate, gas rate and inlet fly-ash loading. The percentage of fly-ash removal efficiency increases with increase in inlet fly-ash loading, gas flow rate and liquid flow rate, and height of the scrubber; 98.55% maximum percentage of fly-ash removal efficiency (ηFA) is achieved at 19.36 × 10(-4) Nm(3)/s gas flow rate (QG) and 48.183 × 10(-6) m(3)/s liquid flow rate (QL) at 25 × 10(-3) kg/Nm(3) inlet fly-ash loading (CFA,i). A model has also been developed for the prediction of fly-ash removal efficiency of the column using the experimental results. The predicted values calculated using the correlation matched well with the experimental results. Deviations observed between the experimental and the predicted values were less than 20%.

  3. Analysis of the 2006 block-and-ash flow deposits of Merapi Volcano, Java, Indonesia, using high-spatial resolution IKONOS images and complementary ground based observations (United States)

    Thouret, Jean-Claude; Gupta, Avijit; Liew, Soo Chin; Lube, Gert; Cronin, Shane J.; Surono, Dr


    On 16 June 2006 an overpass of IKONOS coincided with the emplacement of an active block-and-ash flow fed by a lava dome collapse event at Merapi Volcano (Java, Indonesia). This was the first satellite image recorded for a moving pyroclastic flow. The very high-spatial resolution data displayed the extent and impact of the pyroclastic deposits emplaced during and prior to, the day of image acquisition. This allowed a number of features associated with high-hazard block-and-ash flows emplaced in narrow, deep gorges to be mapped, interpreted and understood. The block-and-ash flow and surge deposits recognized in the Ikonos images include: (1) several channel-confined flow lobes and tongues in the box-shaped valley; (2) thin ash-cloud surge deposit and knocked-down trees in constricted areas on both slopes of the gorge; (3) fan-like over bank deposits on the Gendol-Tlogo interfluves from which flows were re-routed in the Tlogo secondary valley; (4) massive over bank lobes on the right bank from which flows devastated the village of Kaliadem 0.5 km from the main channel, a small part of this flow being re-channeled in the Opak secondary valley. The high-resolution IKONOS images also helped us to identify geomorphic obstacles that enabled flows to ramp and spill out from the sinuous channel, a process called flow avulsion. Importantly, the avulsion redirected flows to unexpected areas away from the main channel. In the case of Merapi we see that the presence of valley fill by previous deposits, bends and man-made dams influence the otherwise valley-guided course of the flows. Sadly, Sabo dams (built to ameliorate the effect of high sediment load streams) can actually cause block-and-ash flows to jump out of their containing channel and advance into sensitive areas. Very-high-spatial resolution satellite images are very useful for mapping and interpreting the distribution of freshly erupted volcanic deposits. IKONOS-type images with 1-m resolution provide opportunities to

  4. A Cold Model Experimental Study on the Flow Characterisitcs of Bed Baterial in A Fluidized ed Bottom Ash Cooler in a CFB Boiler

    Institute of Scientific and Technical Information of China (English)

    LuXiaofeng; LiYourong


    A cold model experimental study on the flowing characteristics of bed meterial between a fluidized bed ash cooler and a furnace of CFB boiler were discussed in this paper.The research results showed that flowing status of the bed material in a bubbling bed,which was run with a circulating fluidized bed together in parallel operation,was influenced by the pressure difference between the CFB and the bubbling bed,the switch status of unlocking air ,and the structure of the exit of the bubbling bed.There was a circulating flow of bed material between CFB and bubbling bed.

  5. Skin temperature and subcutaneous adipose blood flow in man

    DEFF Research Database (Denmark)

    Astrup, A; Bülow, J; Madsen, J


    The abdominal subcutaneous adipose tissue blood flow (ATBF) was measured bilaterally by the 133Xe washout method. At one side of the skin (epicutaneous) temperature was varied with a temperature blanket, the other side served as control. There was a significant (P less than 0.001) positive...... correlation between skin temperature and ATBF. In the range from 25 to 37 degrees CATBF increased 9% of the control flow on average per centigrade increase in skin temperature. ATBF at the control side was uninfluenced by the contralateral variations in skin temperature. Although no better correlation could...

  6. Temperature and flow distribution in planar SOFC stacks

    Directory of Open Access Journals (Sweden)

    Monica Østenstad


    Full Text Available Simulation of a planar Solid Oxide Fuel Cell stack requires the solution of the mass balances of the chemical species, the energy balances, the charge balance and the channel flow equations in order to compute the species concentrations, the temperature distributions, the current density and the channel flows. The unit cell geometry can be taken into account by combining detailed modeling of a unit cell with a homogenized model of a whole stack. In this study the effect of the asymmetric temperature distribution on the channel flows in a conventional cross-flow design has been investigated. The bidirectional cross-flow design is introduced, for which we can show more directional temperature and flow distributions.

  7. Integrated flow and temperature modeling at the catchment scale

    DEFF Research Database (Denmark)

    Loinaz, Maria Christina; Davidsen, Hasse Kampp; Butts, Michael


    , the Silver Creek Basin in Idaho, where stream temperature affects the populations of fish and other aquatic organisms. The model calibration highlights the importance of spatially distributed flow dynamics in the catchment to accurately predict stream temperatures. The results also show the value...... of including temperature data in an integrated flow model calibration because temperature data provide additional constraints on the flow sources and volumes. Simulations show that a reduction of 10% in the groundwater flow to the Silver Creek Basin can cause average and maximum temperature increases in Silver...... Creek over 0.3°C and 1.5°C, respectively. In spring-fed systems like Silver Creek, it is clearly not feasible to separate river habitat restoration from upstream catchment and groundwater management....

  8. Spreading dynamic of viscous volcanic ash in stimulated jet engine conditions (United States)

    song, wenjia; Lavallée, Yan; Hess, Kai-Uwe; Kueppers, Ulrich; Cimarelli, Corrado


    The ingestion of volcanic ash is widely recognised as a potentially fatal hazard for aircraft operation. The volcanic ash deposition process in a jet turbine is potentially complex. Volcanic ash in the air stream enters the inner liners of the combustors and partially or completely melts under the flames up to 2000 °C, at which point part of the ash deposits in the combustor fuel nozzle. Molten volcanic particles within high energy airflow escape the combustor to enter the turbine and impact the stationary (e.g., inlet nozzle guide vanes) and rotating airfoils (e.g., first stage high-pressure turbine blades) at high speed (up to Mach 1.25) in different directions, with the result that ash may stick, flow and remain liquid or solidify. Thus, the wetting behaviour of molten volcanic ash particle is fundamental to investigate impingement phenomena of ash droplet on the surface of real jet engine operation. The topic of wetting has received tremendous interest from both fundamental and applied points of view. However, due to the interdisciplinary gap between jet engine engineering and geology science, explicit investigation of wetting behaviour of volcanic ash at high temperature is in its infancy. We have taken a big step towards meeting this challenge. Here, we experimentally and theoretically investigate the wetting behaviour of viscous volcanic ash over a wide temperature range from 1100 to 1550 °C using an improved sessile-drop method. The results of our experiment demonstrate that temperature and viscosity play a critical role in determining the wetting possibility and governing the spreading kinetics of volcanic ash at high temperatures. Our systemic analysis of spreading of molten volcanic ash systems allows us to report on the fundamental differences between the mechanisms controlling spreading of organic liquids at room temperature and molten volcanic ash droplets.

  9. Measuring Water Vapor and Ash in Volcanic Eruptions with a Millimeter-Wave Radar/Imager

    CERN Document Server

    Bryan, Sean; Vanderkluysen, Loÿc; Groppi, Christopher; Paine, Scott; Bliss, Daniel W; Aberle, James; Mauskopf, Philip


    Millimeter-wave remote sensing technology can significantly improve measurements of volcanic eruptions, yielding new insights into eruption processes and improving forecasts of drifting volcanic ash for aviation safety. Radiometers can measure water vapor density and temperature inside eruption clouds, improving on existing measurements with infrared cameras that are limited to measuring the outer cloud surface. Millimeter-wave radar can measure the 3D mass flow of volcanic ash inside eruption plumes and drifting fine ash clouds, offering better sensitivity than existing weather radar measurements and the unique ability to measure ash particle size in-situ. Here we present sensitivity calculations in the context of developing the WAMS (Water and Ash Millimeter-wave Spectrometer) instrument. WAMS, a radar/radiometer system constructed with off-the-shelf components, would be able to measure water vapor and ash throughout an entire eruption cloud, a unique capability.

  10. Volcanic ash melting under conditions relevant to ash turbine interactions. (United States)

    Song, Wenjia; Lavallée, Yan; Hess, Kai-Uwe; Kueppers, Ulrich; Cimarelli, Corrado; Dingwell, Donald B


    The ingestion of volcanic ash by jet engines is widely recognized as a potentially fatal hazard for aircraft operation. The high temperatures (1,200-2,000 °C) typical of jet engines exacerbate the impact of ash by provoking its melting and sticking to turbine parts. Estimation of this potential hazard is complicated by the fact that chemical composition, which affects the temperature at which volcanic ash becomes liquid, can vary widely amongst volcanoes. Here, based on experiments, we parameterize ash behaviour and develop a model to predict melting and sticking conditions for its global compositional range. The results of our experiments confirm that the common use of sand or dust proxy is wholly inadequate for the prediction of the behaviour of volcanic ash, leading to overestimates of sticking temperature and thus severe underestimates of the thermal hazard. Our model can be used to assess the deposition probability of volcanic ash in jet engines.

  11. Durability of class C fly ash belite cement in simulated sodium chloride radioactive liquid waste: Influence of temperature

    Energy Technology Data Exchange (ETDEWEB)

    Guerrero, A. [Eduardo Torroja Institute for Construction Science (CSIC), C/Serrano Galvache 4, 28033 Madrid (Spain)], E-mail:; Goni, S. [Eduardo Torroja Institute for Construction Science (CSIC), C/Serrano Galvache 4, 28033 Madrid (Spain)], E-mail:; Allegro, V.R. [Eduardo Torroja Institute for Construction Science (CSIC), C/Serrano Galvache 4, 28033 Madrid (Spain)], E-mail:


    This work is a continuation of a previous durability study of class C fly ash belite cement (FABC-2-W) in simulated radioactive liquid waste (SRLW) that is very rich in sulphate salts. The same experimental methodology was applied in the present case, but with a SRLW rich in sodium chloride. The study was carried out by testing the flexural strength of mortars immersed in simulated radioactive liquid waste that was rich in chloride (0.5 M), and demineralised water as a reference, at 20 and 40 deg. C over a period of 180 days. The reaction mechanism of chloride ions with the mortar was evaluated by scanning electron microscopy (SEM), porosity and pore-size distribution, and X-ray diffraction (XRD). The results showed that the FABC mortar was stable against simulated chloride radioactive liquid waste (SCRLW) attack at the two chosen temperatures. The enhancement of mechanical properties was a result of the formation of non-expansive Friedel's salt inside the pores; accordingly, the microstructure was refined.

  12. Measured gas and particle temperatures in VTT's entrained flow reactor

    DEFF Research Database (Denmark)

    Clausen, Sønnik; Sørensen, L.H.


    Particle and gas temperature measurements were carried out in experiments on VTTs entrained flow reactor with 5% and 10% oxygen using Fourier transform infrared emission spectroscopy (FTIR). Particle temperature measurements were performed on polish coal,bark, wood, straw particles, and bark...

  13. Reproductive and developmental biology of the emerald ash borer parasitoid Spathius galinae (Hymenoptera: Braconidae) as affected by temperature (United States)

    Emerald ash borer Agrilus planipennis Fairmaire (Coleoptera: Buprestidae) is an invasive pest of serious concern in North America. To complement ongoing biological control efforts, Spathius galinae Belokobylskij and Strazenac (Hymenoptera: Braconidae), a recently-described specialist parasitoid of ...

  14. Dielectric properties of fly ash

    Indian Academy of Sciences (India)

    S C Raghavendra; R L Raibagkar; A B Kulkarni


    This paper reports the dielectric properties of fly ash. The dielectric measurements were performed as a function of frequency and temperature. The sample of fly ash shows almost similar behaviour in the frequency and temperature range studied. The large value of dielectric constant in the typical frequency range is because of orientation polarization and tight binding force between the ions or atoms in the fly ash. The sample of fly ash is of great scientific and technological interest because of its high value of dielectric constant (104).

  15. Simulation of turbulent flow and temperature separation in a uni-flow vortex tube

    Directory of Open Access Journals (Sweden)

    Promvonge, P.


    Full Text Available The vortex tube is a mechanical device operating as a refrigerating machine without refrigerants, by separating a compressed gas stream into two streams; the cold air stream at the tube core while the hot airstream near the tube wall. Such a separation of the flow into regions of low and high total temperature is referred to as the temperature separation effect. In this paper, simulation of the turbulent compressible flowand temperature separation in a uni-flow vortex tube with the turbulence model and the algebraic Reynolds stress model (ASM is described. Steady, compressible and two-dimensional flows are assumed through outthe calculation. It has been found that the predicted results of velocity, pressure, and temperature fields are generally in good agreement with available experiment data. Moreover, it can be indicated that the highest temperature separation occurs near the inlet nozzle while the lowest temperature separation is found at the downstream near the control valve.

  16. Temperature measurement in laminar free convective flow using digital holography. (United States)

    Hossain, Md Mosarraf; Shakher, Chandra


    A method for measurement of temperature in laminar free convection flow of water is presented using digital holographic interferometry. The method is relatively simple and fast because the method uses lensless Fourier transform digital holography, for which the reconstruction algorithm is simple and fast, and also the method does not require use of any extra experimental efforts as in phase shifting. The quantitative unwrapped phase difference is calculated experimentally from two digital holograms recorded in two different states of water--one in the quiescent state, the other in the laminar free convection. Unknown temperature in laminar free convection is measured quantitatively using a known value of temperature in the quiescent state from the unwrapped phase difference, where the equation by Tilton and Taylor describing the variation of refractive index of water with temperature is used to connect the phase with temperature. Experiments are also performed to visualize the turbulent free convection flow.

  17. A MEMS-Based Flow Rate and Flow Direction Sensing Platform with Integrated Temperature Compensation Scheme

    Directory of Open Access Journals (Sweden)

    Chia-Yen Lee


    Full Text Available This study develops a MEMS-based low-cost sensing platform for sensing gas flow rate and flow direction comprising four silicon nitride cantilever beams arranged in a cross-form configuration, a circular hot-wire flow meter suspended on a silicon nitride membrane, and an integrated resistive temperature detector (RTD. In the proposed device, the flow rate is inversely derived from the change in the resistance signal of the flow meter when exposed to the sensed air stream. To compensate for the effects of the ambient temperature on the accuracy of the flow rate measurements, the output signal from the flow meter is compensated using the resistance signal generated by the RTD. As air travels over the surface of the cross-form cantilever structure, the upstream cantilevers are deflected in the downward direction, while the downstream cantilevers are deflected in the upward direction. The deflection of the cantilever beams causes a corresponding change in the resistive signals of the piezoresistors patterned on their upper surfaces. The amount by which each beam deflects depends on both the flow rate and the orientation of the beam relative to the direction of the gas flow. Thus, following an appropriate compensation by the temperature-corrected flow rate, the gas flow direction can be determined through a suitable manipulation of the output signals of the four piezoresistors. The experimental results have confirmed that the resulting variation in the output signals of the integrated sensors can be used to determine not only the ambient temperature and the velocity of the air flow, but also its direction relative to the sensor with an accuracy of ± 7.5o error.

  18. A MEMS-Based Flow Rate and Flow Direction Sensing Platform with Integrated Temperature Compensation Scheme. (United States)

    Ma, Rong-Hua; Wang, Dung-An; Hsueh, Tzu-Han; Lee, Chia-Yen


    This study develops a MEMS-based low-cost sensing platform for sensing gas flow rate and flow direction comprising four silicon nitride cantilever beams arranged in a cross-form configuration, a circular hot-wire flow meter suspended on a silicon nitride membrane, and an integrated resistive temperature detector (RTD). In the proposed device, the flow rate is inversely derived from the change in the resistance signal of the flow meter when exposed to the sensed air stream. To compensate for the effects of the ambient temperature on the accuracy of the flow rate measurements, the output signal from the flow meter is compensated using the resistance signal generated by the RTD. As air travels over the surface of the cross-form cantilever structure, the upstream cantilevers are deflected in the downward direction, while the downstream cantilevers are deflected in the upward direction. The deflection of the cantilever beams causes a corresponding change in the resistive signals of the piezoresistors patterned on their upper surfaces. The amount by which each beam deflects depends on both the flow rate and the orientation of the beam relative to the direction of the gas flow. Thus, following an appropriate compensation by the temperature-corrected flow rate, the gas flow direction can be determined through a suitable manipulation of the output signals of the four piezoresistors. The experimental results have confirmed that the resulting variation in the output signals of the integrated sensors can be used to determine not only the ambient temperature and the velocity of the air flow, but also its direction relative to the sensor with an accuracy of ± 7.5° error.

  19. Recycling of Pre-Washed Municipal Solid Waste Incinerator Fly Ash in the Manufacturing of Low Temperature Setting Geopolymer Materials

    Directory of Open Access Journals (Sweden)

    Raffaele Cioffi


    Full Text Available In this work, three samples of municipal solid waste incinerators fly ash (MSWI-FA have been stabilized in systems containing coal fly ash to create geopolymers through a polycondensation reaction. Monolithic products have been obtained with both MSWI fly ash as received and after the partial removal of chloride and sulfate by water washing. The polycondensation products have been characterized qualitatively by means of Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy and quantitatively, through the determination of the volume of reacted water and silicate. Furthermore, the heavy metals and chloride releases together with the physico-mechanical properties have been evaluated on the hardened products. In conclusion, considering the technological and environmental performances of the obtained geopolymers, they could be suitable for many non-structural applications, such as backfilling of abandoned quarries, decorative materials or brick fireplaces, hearths, patios, etc.

  20. Performance at high temperature of alkali-activated slag pastes produced with silica fume and rice husk ash based activators

    Directory of Open Access Journals (Sweden)

    Bernal, S. A.


    Full Text Available This study assessed the mechanical properties, and structural changes induced by high temperature exposure, of alkali-silicate activated slag cements produced with sodium silicates derived from silica fume (SF and rice husk ash (RHA. Similar reaction products were identified, independent of the type of silicate used, but with subtle differences in the composition of the C-S-H gels, leading to different strength losses after elevated temperature exposure. Cements produced with the alternative activators developed higher compressive strengths than those produced with commercial silicate. All samples retained strengths of more than 50 MPa after exposure to 600 °C, however, after exposure to 800 °C only the specimens produced with the RHA-based activator retained measurable strength. This study elucidated that silicate-activated slag binders, either activated with commercial silicate solutions or with sodium silicates based on SF or RHA, are stable up to 600 °C.Este estudio evaluó las propiedades mecánicas, y cambios estructurales inducidos por exposición a temperaturas elevadas, de cementos de escoria activada alcalinamente producidos con silicatos sódicos derivados de humo de sílice (SF y ceniza de cascarilla de arroz (RHA. Se identificaron productos de reacción similares, independiente del tipo de silicato utilizado, pero con diferencias menores en la composición de las geles C-S-H, lo cual indujo diferentes pérdidas de resistencia posterior a exposición a temperaturas elevadas. Los cementantes producidos con los activadores alternativos desarrollaron resistencias a la compresión más altas que aquellos producidos con silicato comercial. Todas las muestras retuvieron resistencias de más de 50 MPa posterior a la exposición a 600 °C, sin embargo, posterior a la exposición a 800 °C únicamente muestras producidas con activadores de RHA retuvieron resistencias medibles. Este estudio elucidó que cementantes de escoria activada con


    Institute of Scientific and Technical Information of China (English)

    ZHAO Wei-guo; ZHANG Ling-xin; SHAO Xue-ming


    The numerical simulation of cavitation flow on a 2D NACA0015 hydrofoil under high pressure and temperature is performed. The Singhal's cavitation model is adopted combined with an improved RNG k-ε turbulence model to study the cavitation flow. The thermal effect in the cavitation flow is taken into account by introducing the energy equation with a source term based on the latent heat transfer. The code is validated by a case of a hydrofoil under two different temperatures in a comparison between the simulation and the experiment. Computational results show that the latent heat of vaporization has a significant impact on the cavitation process in the high temperature state, and the cavity in the high temperature state is thinner and shorter than that in a normal state with the same cavitation number, due to the fact that the heat absorption in the cavitation area reduces the local temperature and the saturated vapor pressure. This numerical study provides some guidance for the design of machineries in the High Pressure and Temperature (HPT) state.

  2. Ash formation, deposition, corrosion, and erosion in conventional boilers

    Energy Technology Data Exchange (ETDEWEB)

    Benson, S.A.; Jones, M.L. [Univ. of North Dakota, Grand Forks, ND (United States)


    The inorganic components (ash-forming species) associated with coals significantly affect boiler design, efficiency of operation, and lifetimes of boiler parts. During combustion in conventional pulverized fuel boilers, the inorganic components are transformed into inorganic gases, liquids, and solids. This partitioning depends upon the association of the inorganic components in the coal and combustion conditions. The inorganic components are associated as mineral grains and as organically associated elements, and these associations of inorganic components in the fuel directly influence their fate upon combustion. Combustion conditions, such as temperature and atmosphere, influence the volatility and the interaction of inorganic components during combustion and gas cooling, which influences the state and size composition distribution of the particulate and condensed ash species. The intermediate species are transported with the bulk gas flow through the combustion systems, during which time the gases and entrained ash are cooled. Deposition, corrosion, and erosion occur when the ash intermediate species are transported to the heat-transfer surface, react with the surface, accumulate, sinter, and develop strength. Research over the past decade has significantly advanced understanding of ash formation, deposition, corrosion, and erosion mechanisms. Many of the advances in understanding and predicting ash-related issues can be attributed to advanced analytical methods to determine the inorganic composition of fuels and the resulting ash materials. These new analytical techniques have been the key to elucidation of the mechanisms of ash formation and deposition. This information has been used to develop algorithms and computer models to predict the effects of ash on combustion system performance.

  3. Controlling formaldehyde emissions with boiler ash. (United States)

    Cowan, Jennifer; Abu-Daabes, Malyuba; Banerjee, Sujit


    Fluidized wood ash reduces formaldehyde in air from about 20 to formaldehyde reduction increases with increasing moisture content of the ash. Sorption of formaldehyde to ash can be substantially accounted for by partitioning to the water contained in the ash followed by rate-controlling binding to the ash solids. Adsorption occurs at temperatures of up to 165 degrees C; oxidation predominates thereafter. It is proposed that formaldehyde could be stripped from an air stream in a fluidized bed containing ash, which could then be returned to a boiler to incinerate the formaldehyde.

  4. High-temperature entrained flow gasification of biomass

    DEFF Research Database (Denmark)

    Qin, Ke; Lin, Weigang; Jensen, Peter Arendt


    Biomass (wood and straw) gasification has been studied in a laboratory scale atmospheric pressure entrained flow reactor. Effects of reaction temperature, steam/carbon molar ratio, excess air ratio, and biomass type on the solid, liquid and gas products were investigated. The biomass was completely...

  5. Vitrification of municipal solid waste incineration fly ash using biomass ash as additives. (United States)

    Alhadj-Mallah, Moussa-Mallaye; Huang, Qunxing; Cai, Xu; Chi, Yong; Yan, JianHua


    Thermal melting is an energy-costing solution for stabilizing toxic fly ash discharged from the air pollution control system in the municipal solid waste incineration (MSWI) plant. In this paper, two different types of biomass ashes are used as additives to co-melt with the MSWI fly ash for reducing the melting temperature and energy cost. The effects of biomass ashes on the MSWI fly ash melting characteristics are investigated. A new mathematical model has been proposed to estimate the melting heat reduction based on the mass ratios of major ash components and measured melting temperature. Experimental and calculation results show that the melting temperatures for samples mixed with biomass ash are lower than those of the original MSWI fly ash and when the mass ratio of wood ash reaches 50%, the deformation temperature (DT), the softening, hemisphere temperature (HT) and fluid temperature (FT) are, respectively, reduced by 189°C, 207°C, 229°C, and 247°C. The melting heat of mixed ash samples ranges between 1650 and 2650 kJ/kg. When 50% wood ash is mixed, the melting heat is reduced by more than 700 kJ/kg for the samples studied in this paper. Therefore, for the vitrification treatment of the fly ash from MSW or other waste incineration plants, wood ash is a potential fluxing assistant.

  6. CFD modeling of stripper ash cooler of circulating fluidized bed boiler

    Directory of Open Access Journals (Sweden)

    Ravi Inder Singh


    Full Text Available The stable operation of a bottom ash cooler is vital for the operation of the circulating fluidized bed boiler. To assess, the stability of the ash cooler, it is important to have a thorough understanding of the flow behaviour. Although, many experimental results been reported in literature, CFD modelling of the ash cooler has not been carried out. In this paper, the transient computational analysis of a novel stripper ash cooler has been carried out using the Eulerian–Eulerian multiphase approach. The phase coupled SIMPLE algorithm has been used to solve the multiphase equations and the Gidaspow drag model has been employed to model the interaction between the fluidized air and ash. Two cases have been analysed in this paper. In the first case, the filling of the ash in the cooler has been analysed and in the second case, the phenomenon of fluidized bed bubbling in the ash cooler has been simulated. The study the of flow characteristics of hot ash has been studied. The contours of temperature, phase volume and bubbling have been analyzed in this paper.

  7. Wildland fire ash: future research directions (United States)

    Bodí, Merche B.; Martins, Deborah A.; Cerdà, Artemi; Balfour, Victoria N.; Santin, Cristina; Doerr, Stefan H.; Pereira, Paulo; Mataix-Solera, Jorge


    Ash is a key component of the forest fires affected land (Cerdà, 1998; Bodí et al., 2011; Pereira et al., 2013a). Ash controls the hydrological processes and determines the water repellency (Dlapa et al., 2012) and the infiltration rates (Cerdà and Doerr, 2008;). Moreover, ash is the key factor on runoff initiation and then on the soil erosion. Little is known about the impact of ash in different ecosystems, but during the last decade a substantial increase in the papers that show the role of ash in the Earth and Soil System were published (Bodí et al., 2012; Pereira et al., 2013b).. Ash is being found as the key component of the post-fire pedological, geomorphological and hydrological response after forest fires (Fernández et al., 2012; Martín et al., 2012; Bodí et al., 2013; Guénon et al., 2013; Pereira et al., 2013c). A recent State-of-the-Art review about wildland fire ash (Bodí et al., 2014) compiles the knowledge regarding the production, composition and eco-hydro-geomorphic effects of wildland fire ash. In the present paper we indicate the knowledge gaps detected and suggest topics that need more research effort concerning: i) data collection and analysis techniques: a) To develop standardized sampling techniques that allow cross comparison among sites and avoid inclusion of the underlying soil unless the burned surface soil forms part of the ash layer, b) To develop standardized methods to define and characterize ash, including its color, physical properties such as particle size distribution or density, proportion of pyrogenic C, chemical and biological reactivity and persistence in the environment, c) To validate, calibrate and test measurements collected through remote sensing with on-the-ground measurements. ii) ash production, deposition redistribution and fate: d) To untangle the significance of the effects of maximum temperature reached during combustion versus the duration of heating, e) To understand the production of ash by measuring its

  8. Volcanic ash infrared signature: realistic ash particle shapes compared to spherical ash particles

    Directory of Open Access Journals (Sweden)

    A. Kylling


    Full Text Available The reverse absorption technique is often used to detect volcanic clouds from thermal infrared satellite measurements. From these measurements particle size and mass loading may also be estimated using radiative transfer modelling. The radiative transfer modelling usually assumes that the ash particles are spherical. We calculate thermal infrared optical properties of highly irregular and porous ash particles and compare these with mass- and volume-equivalent spherical models. Furthermore, brightness temperatures pertinent to satellite observing geometry are calculated for the different ash particle shapes. Non-spherical shapes and volume-equivalent spheres are found to produce a detectable ash signal for larger particle sizes than mass-equivalent spheres. The assumption of mass-equivalent spheres for ash mass loading estimates will underestimate the mass loading by several tens of percent compared to morphologically complex inhomogeneous ash particles.

  9. Volcanic ash infrared signature: realistic ash particle shapes compared to spherical ash particles (United States)

    Kylling, A.; Kahnert, M.; Lindqvist, H.; Nousiainen, T.


    The reverse absorption technique is often used to detect volcanic clouds from thermal infrared satellite measurements. From these measurements particle size and mass loading may also be estimated using radiative transfer modelling. The radiative transfer modelling usually assumes that the ash particles are spherical. We calculate thermal infrared optical properties of highly irregular and porous ash particles and compare these with mass- and volume-equivalent spherical models. Furthermore, brightness temperatures pertinent to satellite observing geometry are calculated for the different ash particle shapes. Non-spherical shapes and volume-equivalent spheres are found to produce a detectable ash signal for larger particle sizes than mass-equivalent spheres. The assumption of mass-equivalent spheres for ash mass loading estimates will underestimate the mass loading by several tens of percent compared to morphologically complex inhomogeneous ash particles.

  10. Nonintrusive fast response oxygen monitoring system for high temperature flows (United States)

    Oh, Daniel B.; Stanton, Alan C.


    A new technique has been developed for nonintrusive in situ measurement of oxygen concentration, gas temperature, and flow velocity of the test media in hypersonic wind tunnels. It is based on absorption of near-infrared radiation from inexpensive GaAlAs laser diodes used in optoelectronics industry. It is designed for simultaneous measurements along multiple lines of sight accessed by fiber optics. Molecular oxygen concentration is measured from the magnitude of absorption signals; rotational gas temperature is measured from the intensity ratio of two oxygen absorption lines; and the flow velocity is measured from the Doppler shift of the absorption line positions. This report describes the results of an extensive series of tests of the prototype instrument in laboratory flames emphasizing assessment of the instruments capabilities for quantitative measurement of O2 concentration (mole fraction) and gas temperature.

  11. Constitutive model of discontinuous plastic flow at cryogenic temperatures

    CERN Document Server

    Skoczen, B; Bielski, J; Marcinek, D


    FCC metals and alloys are frequently used in cryogenic applications, nearly down to the temperature of absolute zero, because of their excellent physical and mechanical properties including ductility. Some of these materials, often characterized by the low stacking fault energy (LSFE), undergo at low temperatures three distinct phenomena: dynamic strain ageing (DSA), plastic strain induced transformation from the parent phase (gamma) to the secondary phase (alpha) and evolution of micro-damage. The constitutive model presented in the paper is focused on the discontinuous plastic flow (serrated yielding) and takes into account the relevant thermodynamic background. The discontinuous plastic flow reflecting the DSA effect is described by the mechanism of local catastrophic failure of Lomer-Cottrell (LC) locks under the stress fields related to the accumulating edge dislocations (below the transition temperature from the screw dislocations to the edge dislocations mode T-1). The failure of LC locks leads to mass...


    Directory of Open Access Journals (Sweden)

    De-Min Liu


    Full Text Available Cavitation is not only related with pressure, but also affected by temperature. Under high temperature, temperature depression of liquids is caused by latent heat of vaporization. The cavitation characteristics under such condition are different from those under room temperature. The paper focuses on thermodynamic cavitation based on the Rayleigh-Plesset equation and modifies the mass transfer equation with fully consideration of the thermodynamic effects and physical properties. To validate the modified model, the external and internal flow fields, such as hydrofoil NACA0015 and nozzle, are calculated, respectively. The hydrofoil NACA0015's cavitation characteristic is calculated by the modified model at different temperatures. The pressure coefficient is found in accordance with the experimental data. The nozzle cavitation under the thermodynamic condition is calculated and compared with the experiment.

  13. Ash in the Soil System (United States)

    Pereira, P.


    Ash is the organic and inorganic residue produced by combustion, under laboratory and field conditions. This definition is far away to be accepted. Some researchers consider ash only as the inorganic part, others include also the material not completely combusted as charcoal or biochar. There is a need to have a convergence about this question and define clear "what means ash". After the fire and after spread ash onto soil surface, soil properties can be substantially changed depending on ash properties, that can be different according to the burned residue (e.g wood, coal, solid waste, peppermill, animal residues), material treatment before burning, time of exposition and storage conditions. Ash produced in boilers is different from the produced in fires because of the material diferent propertie and burning conditions. In addition, the ash produced in boilers is frequently treated (e.g pelletization, granulation, self curing) previously to application, to reduce the negative effects on soil (e.g rapid increase of pH, mycorrhiza, fine roots of trees and microfauna). These treatments normally reduce the rate of nutrients dissolution. In fires this does not happen. Thus the implications on soil properties are logically different. Depending on the combustion temperature and/or severity, ash could have different physical (e.g texture, wettability) and chemical properties (e.g amount and type of total and leached nutrients) and this will have implications on soil. Ash can increase and decrease soil aggregation, wettablity and water retention, bulk density, runoff and water infiltration. Normally, ash increases soil pH, Electrical Conductivity, and the amount of some basic nutrients as calcium, magnesium, sodium and potassium. However it is also a potential source of heavy metals, especially if ash pH is low. However the effect of ash on soil in space and time depends especially of the ash amount and characteristics, fire temperature, severity, topography, aspect

  14. Study on the volcanic ash cloud with Feng Yun-3 meteorological satellite data (United States)

    Gong, Cai-lan T.; Jiang, Shan; Hu, Yong; Meng, Peng


    Volcano eruption can produce a mass of volcanic ash floating in the air for a long period, which will seriously threaten the aerial planes safety, and cause the air pollution, it could do harm to people's living environment and their health. Take the Iceland Eyjafjallajokull volcano as an example which erupted in April to May 2010, the volcano ash cloud were derived with the visible and infrared scanning radiometer of FengYun-3(FY-3 VIRR) meteorological satellite data. The medium wave infrared (MWIR) and the thermal infrared split windows (THIR-SW) data were used separately. the MODIS THIR-SW data were also be used to retrieve ash cloud to test the results derived from FY-3 VIRR data. It showed that the MWIR was more applicable for the ash cloud retrieving than the THIR-SW with FY-3 VIRR data, and the threshold value should be adjusted to around negative 1 rather than 0 for VIRR THIR-SW data. And the threshold should be adjusted with the THIR-SW of FY-3. The ash cloud radiation and bright temperature(BT), spatial distribution characteristics were also analyzed quantitatively with the two channels data. The study could provide parameters for the prediction of volcanic ash cloud dispersion simulate. When the real temperature of lava flow were high enough, the sensor will show a false bright temperature, how to retrieve the real temperature of the higher lava flow is a problem need to be studied in the future.


    Directory of Open Access Journals (Sweden)

    Marián Lázár


    Full Text Available Objective of this paper is to describe innovative solutions of thermal processing of selected components of municipal waste (so-called RDF waste using low-ionized depended plasma arc generated by a progressive and promising technology, which is plasma reactor. Its application can transform hazardous waste into inert waste while significantly reducing the volume of waste. Results given in this paper indicate experimentally achieved outputs with thermal disposal of RDF waste and ash from municipal waste. 

  16. Ash after forest fires. Effects on soil hydrology and erosion (United States)

    Bodí, Merche B.


    Hillslopes were though to be most susceptible to enhanced hydro-geomorphological responses immediately following burning, with susceptibility declining during the first months or years depending on the soil and vegetation recovery. However, Cerdà (1998) found some indices in that immediately after the fire, the thin wettable ash layer that typically covers the ground could absorb rainfall and prevent or delay the onset of overland flow and associated erosion. Therefore the time lag while ash remains on the ground become of crucial importance to protect the soil after a wildfire. The effect of this ash layer was rarely been considered in detail because ash has often been reduced or redistributed by wind or water erosion before the onset of monitoring and thus the data collection typically begun some weeks or month after the fire. The first papers focussed only on ash and its hydrological effects were published by Cerdà and Doerr (2008) and by Woods and Balfour (2008). The results showed that the soil covered with ash indeed reduced and delayed surface runoff, reduced soil splash detachment and produced lower sediment yield compared to bare terrain. However, these findings arose more questions, as for instance: Why in other research there were indices that ash reduces infiltration? what is the mechanism by which why ash reduces overland flow? The research went further with Bodí PhD. First of all, it was crucial the agreement on the fact that the material "ash" is very variable depending on the original vegetation and the type and temperature of combustion. Therefore ash properties are different between wildfires even and within a fire. This is the main reason of its different effects and thus ash not always reduces runoff and sediment yield. In this way, depending on the nature of ash, it can increase overland flow if it is crusted (usually it contains a high content of calcium carbonate), it is water repellent (with high contents of organic carbon and specially

  17. High resolution temperature measurement technique for measuring marine heat flow

    Institute of Scientific and Technical Information of China (English)

    QIN; YangYang; YANG; XiaoQiu; WU; BaoZhen; SUN; ZhaoHua; SHI; XiaoBin


    High resolution temperature measurement technique is one of the key techniques for measuring marine heat flow. Basing on Pt1000 platinum resistance which has the characteristics of high accuracy and good stability, we designed a bridge reversal excitation circuit for high resolution temperature measurement. And the deep ocean floor in-situ test results show that: (1) temperature deviation and peak-to-peak resolution of the first version circuit board (V1) are 1.960-1.990 mK and 0.980-0.995 m Kat 1.2-2.7°C, respectively; and temperature deviation and peak-to-peak resolution of the second circuit board (V2) are 2.260mK and 1.130 mK at 1.2-1.3°C, respectively; (2) During the 2012NSFC-IndOcean cruise, seafloor geothermal gradient at Ind2012HF03,-07 and-12 stations (water depth ranges from 3841 to 4541 m) were successfully measured, the values are 59.1,75.1 and 71.6°C/km, respectively. And the measurement errors of geothermal gradient at these three stations are less than 3.0% in terms of the peak-to-peak resolution. These indicate that the high resolution temperature measurement technique based on Pt1000 platinum resistance in this paper can be applied to marine heat flow measurement to obtain high precision geothermal parameters.

  18. Influence of Bed Ash and Fly Ash Replacement in Mortars

    Directory of Open Access Journals (Sweden)

    S. L. Summoogum-Utchanah


    Full Text Available The study evaluates the influence of fly ash and bottom ash as partial cement substitutes in mortars by studying the particle size distribution, consistency, flow, fresh density, air content, compressive strength and flexural strength characteristics. The results revealed that fly ash and cement had relatively the same particle size distribution unlike bottom ash. In the fresh state, as the amount of pozzolans increased in the mixtures, the mortars showed an enhancement in workability, were susceptible to water loss by bleeding, and exhibited a decline in fresh density. The early strength gains of the fly ash samples were low but reached higher than the control after 28 days of curing. The flexural strength increased as the fly ash content rose to reach a maximum at 20 % replacement. However, the 2-day compressive strength of bottom ash samples was higher than the control but decreased after 28 days of curing while the flexural strength declined with addition of bottom ash except at 5 % substitution.

  19. Experimental studies on pulp and paper mill sludge ash behavior in fluidized bed combustors

    Energy Technology Data Exchange (ETDEWEB)

    Latva-Somppi, J. [VTT Chemical Technology, Espoo (Finland). Process Technology


    reduced. During sludge combustion the largest ash particles, over 200 - 300 lam, were accumulated in the bed due to their size. Ash was also accumulated in the bed as micron-size particles adhered to the sand surface fanning a sintered layer. Bench-scale tests showed that this type of layer, fonmed during bark combustion, initiated bed agglomeration and resulted in defluidization without combustion at 988 deg C. Wirb pulp and paper mill sludges the layer fonnation was not connected to bed agglomeration at the studied temperatures up to 1,000 deg C. Presumably, the bark-derived K species in the layer decreased the ash viscosity and triggered bed agglomeration. Trace elements were not accumulated excessively in the bed. Ash deposits were foamed on the furnace wall above the bed. Ash and sand particles were deposited on the surface roughness probably from the down-flowing particle flux near the wall. Ash sintering densified the structure. Condensed or molten ash species were not detected in the structure. The ash viscosity was lower in the pulp mill sludge resulting in larger deposits than during paper mill sludge firing. Calculations indicate that when the ash viscosity is less than 1,000 - 3,000 Pa s, large ash and sand particles are incorporated in the deposit. (orig.) 121 refs. LIEKKI Research Programme

  20. The Entrance of Pyroclastic Flows into the Sea (United States)

    Freundt, A.


    Explosive volcanoes, especially in subduction-zone and ocean-island settings, can generate pyroclastic flows that enter the sea. Geologic constraints on the interaction mechanisms and hazards are poor since resulting deposits hardly survive coastal erosion. The entrance of hot pyroclastic flows into water has been observed experimentally by letting shooting granular flows of ignimbrite ash heated to up to 420oC run down a chute into a water-filled tank. Flows of relatively cool ash, less than 150oC, impulsively displace some near-shore water generating a tsunami wave and then separate into a fine-ash over-water surge formed near shore and the main, coarser and denser material penetrating the water surface to form a turbulent mixing zone which advances downstream as long as the granular flow is maintained. Pumice floats to the surface, lithics and coarse ash fall out onto the floor, but ash remaining in suspension forms a turbidity current flowing down the tank. At temperatures above 250oC, almost all ash is initially transported along the water surface, rather than immediately penetrating it. Transport over water is facilitated by steam explosions derived from mixing of some of the ash with water across the surface. Ash fountains throw dry ash forward before it contacts the water, triggering the next steam explosion farther away from shore where fountains collapse onto the water surface. Each time ash and heat are consumed by mixing; the distance to where explosions extend thus depends on initial mass flux and temperature. Most fine ash forms an ash-cloud surge travelling over water, loosing sediment plumes that unite on the tank floor to form a turbidity current. Tsunami waves generated by coastal impact appear to be additionally driven by surface-water displacement by massive ash-input from ash fountains. Grain size distribution is also critical in determining interaction processes. Moderately well sorted medium ash generates strong steam explosions and becomes

  1. High-temperature zirconia microthruster with an integrated flow sensor (United States)

    Lekholm, Ville; Persson, Anders; Palmer, Kristoffer; Ericson, Fredric; Thornell, Greger


    This paper describes the design, fabrication and characterization of a ceramic, heated cold-gas microthruster device made with silicon tools and high temperature co-fired ceramic processing. The device contains two opposing thrusters, each with an integrated calorimetric propellant flow sensor and a heater in the stagnation chamber of the nozzle. The exhaust from a thruster was photographed using schlieren imaging to study its behavior and search for leaks. The heater elements were tested under a cyclic thermal load and to the maximum power before failure. The nozzle heater was shown to improve the efficiency of the thruster by 6.9%, from a specific impulse of 66 to 71 s, as calculated from a decrease of the flow rate through the nozzle of 13%, from 44.9 to 39.2 sccm. The sensitivity of the integrated flow sensor was measured to 0.15 mΩ sccm-1 in the region of 0-15 sccm and to 0.04 mΩ sccm-1 above 20 sccm, with a zero-flow sensitivity of 0.27 mΩ sccm-1. The choice of yttria-stabilized zirconia as a material for the devices makes them robust and capable of surviving temperatures locally exceeding 1000 °C.

  2. Fly ash quality and utilization

    Energy Technology Data Exchange (ETDEWEB)

    Barta, L.E.; Lachner, L.; Wenzel, G.B. [Inst. for Energy, Budapest (Hungary); Beer, M.J. [Massachusetts Inst. of Technology, Cambridge, MA (United States)


    The quality of fly ash is of considerable importance to fly ash utilizers. The fly ash puzzolanic activity is one of the most important properties that determines the role of fly ash as a binding agent in the cementing process. The puzzolanic activity, however is a function of fly ash particle size and chemical composition. These parameters are closely related to the process of fly ash formation in pulverized coal fired furnaces. In turn, it is essential to understand the transformation of mineral matter during coal combustion. Due to the particle-to-particle variation of coal properties and the random coalescence of mineral particles, the properties of fly ash particles e.g. size, SiO{sub 2} content, viscosity can change considerably from particle to particle. These variations can be described by the use of the probability theory. Since the mean values of these randomly changing parameters are not sufficient to describe the behavior of individual fly ash particles during the formation of concrete, therefore it is necessary to investigate the distribution of these variables. Examples of these variations were examined by the Computer Controlled Scanning Electron Microscopy (CCSEM) for particle size and chemical composition for Texas lignite and Eagel Butte mineral matter and fly ash. The effect of combustion on the variations of these properties for both the fly ash and mineral matter were studied by using a laminar flow reactor. It is shown in our paper, that there are significant variations (about 40-50% around the mean values) of the above-listed properties for both coal samples. By comparing the particle size and chemical composition distributions of the mineral matter and fly ash, it was possible to conclude that for the Texas lignite mineral matter, the combustion did not effect significantly the distribution of these properties, however, for the Eagel Butte coal the combustion had a major impact on these mineral matter parameters.

  3. Ash melting behavior by Fourier transform infrared spectroscopy

    Institute of Scientific and Technical Information of China (English)

    LI Han-xu; QIU Xiao-sheng; TANG Yong-xin


    A Fourier Transform Infrared Spectroscopic (FTIR) method involving a Fe2O3 flux was used to learn how China's coal ash melts. The relationship between ash fusion temperature and chemical composition, as well as the effects of Fe2O3 flux on the ash fusion temperature were studied. The relationship between ash fusion temperature and chemical composition, mineralogical phases and functional groups was analyzed with the FTIR method. The results show that the ash fusion temperature is related to the location and transmittance of certain absorption peaks, which is of great significance for the study of ash behavior.

  4. Origin of silicic volcanic rocks in Central Costa Rica: a study of a chemically variable ash-flow sheet in the Tiribí Tuff (United States)

    Hannah, Rachel; Vogel, Thomas; Patino, Lina; Alvarado, Guillermo; Pérez, Wendy; Smith, Diane


    Chemical heterogeneities of pumice clasts in an ash-flow sheet can be used to determine processes that occur in the magma chamber because they represent samples of magma that were erupted at the same time. The dominant ash-flow sheet in the Tiribí Tuff contains pumice clasts that range in composition from 55.1 to 69.2 wt% SiO2. It covers about 820 km2 and has a volume of about 25 km3 dense-rock equivalent (DRE). Based on pumice clast compositions, the sheet can be divided into three distinct chemical groupings: a low-silica group (55.1-65.6 wt% SiO2), a silicic group (66.2-69.2 wt% SiO2), and a mingled group (58.6-67.7 wt% SiO2; all compositions calculated 100% anhydrous). Major and trace element modeling indicates that the low-silica magma represents a mantle melt that has undergone fractional crystallization, creating a continuous range of silica content from 55.1-65.6 wt% SiO2. Eu/Eu*, MREE, and HREE differences between the two groups are not consistent with crystal fractionation of the low-silica magma to produce the silicic magma. The low-silica group and the silicic group represent two distinct magmas, which did not evolve in the same magma chamber. We suggest that the silicic melts resulted from partial melting of relatively hot, evolved calc-alkaline rocks that were previously emplaced and ponded at the base of an over-thickened basaltic crust. The mingled group represents mingling of the two magmas shortly before eruption. Electronic supplementary material to this paper can be obtained by using the Springer LINK server located at

  5. Temperature dependence of topological susceptibility using gradient flow

    CERN Document Server

    Taniguchi, Yusuke; Kanaya, Kazuyuki; Kitazawa, Masakiyo; Suzuki, Hiroshi; Umeda, Takashi; Iwami, Ryo; Wakabayashi, Naoki


    We study temperature dependence of the topological susceptibility with the $N_{f}=2+1$ flavors Wilson fermion. We have two major interests in this paper. One is a comparison of gluonic and fermionic definitions of the topological susceptibility. Two definitions are related by the chiral Ward-Takahashi identity but their coincidence is highly non-trivial for the Wilson fermion. By applying the gradient flow both for the gauge and quark fields we find a good agreement of these two measurements. The other is a verification of a prediction of the dilute instanton gas approximation at low temperature region $T_{pc}< T<1.5T_{pc}$, for which we confirm the prediction that the topological susceptibility decays with power $\\chi_{t}\\propto(T/T_{pc})^{-8}$ for three flavors QCD.

  6. Effect of temperature on the hydration process and strength development in blends of Portland cement and activated coal gangue or fly ash

    Institute of Scientific and Technical Information of China (English)

    Pei-ming WANG; Xian-ping LIU


    This paper describes the results of an investigation into the effect of the variation of curing temperatures between 0 and 60 ℃ on the hydration process,pore structure variation,and compressive strength development of activated coal gangue-cement blend (ACGC).Hardened ACGC pastes cured for hydration periods from 1 to 360 d were examined using the non-evaporable water method,thermal analysis,mercury intrusion porosimetry,and mechanical testing.To evaluate the specific effect of activated coal gangue (ACG) as a supplementary cementing material (SCM),a fly ash-cement blend (FAC) was used as a control.Results show that raising the curing temperature accelerates pozzolanic reactions involving the SCMs,increasing the degree of hydration of the cement blends,and hence increasing the rate of improvement in strength.The effect of curing temperature on FAC is greater than that on ACGC.The pore structure of the hardened cement paste is improved by increasing the curing temperature up to 40 ℃,but when the curing temperature reaches 60 ℃,the changing nature of the pore structure leads to a decrease in strength.The correlation between compressive strength and the degree of hydration and porosity is linear in nature.

  7. Corrosion of high temperature resisting alloys exposed to heavy fuel ash; Corrosion de aleaciones resistentes a altas temperaturas expuestas a ceniza de combustoleo pesado

    Energy Technology Data Exchange (ETDEWEB)

    Wong Moreno, Adriana del Carmen


    The objective of the performed research was to study the degradation process by high temperature corrosion of alloys exposed to heavy fuel oil ashes through a comparative experimental evaluation of its performance that allowed to establish the mechanisms involved in the phenomenon. The experimentation carried out involved the determination of the resistance to the corrosion of 14 alloys of different type (low and medium alloy steels, ferritic and austenitic stainless steels, nickel base alloys and a FeCrAl alloy of type ODS) exposed to high temperatures (580 Celsius degrees - 900 Celsius degrees) in 15 ash deposits with different corrosive potential, which were collected in the high temperature zone of boilers of thermoelectric power stations. The later studies to the corrosion tests consisted of the analysis by sweeping electron microscopy supported by microanalysis of the corroded probes, with the purpose of determining the effect of Na, V and S on the corrosivity of the ash deposits and the effect of the main alloying elements on the corrosion resistance of the alloys. Such effects are widely documented to support the proposed mechanisms of degradation that are occurring. The global analysis of the generated results has allowed to propose a model to explain the global mechanism of corrosion of alloys exposed to the high temperatures of ash deposits. The proposed model, complements the processed one by Wilson, widely accepted for fused vanadates, as far as on one hand, it considers the effect of the sodium sulfate presence (in addition to the vanadium compounds) in the deposits, and on the other hand, it extends it to temperatures higher than the point of fusion of constituent vanadium compounds of the deposits. Both aspects involve considering the roll that the process of diffusion of species has on the degradation and the capacity of protection of the alloy. The research performed allowed to confirm what the Wilson model had established for deposits with high

  8. Utilization of ash fractions from alternative biofuels used in power plants

    Energy Technology Data Exchange (ETDEWEB)

    Nikolaisen, L.; Hinge, J.; Christensen, I. (Danish Technological Inst., Aarhus (Denmark)); Dahl, J. (Force Technology, Broendby (Denmark)); Arendt Jensen, P. (DTU-CHEC, Kgs. Lyngby (Denmark)); Soendergaard Birkmose, T. (Dansk Landbrugsraadgivning, Landscentret, Aarhus (Denmark)); Sander, B. (DONG Energy, Fredericia (Denmark)); Kristensen, O. (Kommunekemi A/S, Nyborg (Denmark))


    It is expected, that demand for the traditional biomass resources wood and straw will increase over the next years. In other projects a number of agro industrial waste products has been tested and characterized as fuels for power plants. The annual production in Denmark of these fuels is estimated at roughly 400.000 tons of Dry Matter per year, so the potential is substantial. The agro industrial biomass products include: Grain screening waste, pea shells, soy waste, cocoa waste, sugar beet waste, sunflower waste, shea waste, coffee waste, olive waste, rice shell waste, potato waste, pectin waste, carrageen waste, tobacco waste, rape seed waste and mash from breweries. In the PSO project 5075, 5 different types of fuel pellets was produced, which were rendered suitable for combustion in power plants. In this project, ash is produced from the above mentioned 5 mixtures together with another 2 mixtures produced especially for this project. From the 5 mixtures from PSO 5075, ash is produced at Danish Technological Institute's slag analyzer. These ash products are rendered comparable to ash from grate fired boilers at power plants. The ash/slag from the combustion in the slag analyzer was then grinded - thus resulting in a total of 5 ash products. At DTU CHEC's Entrained Flow Reactor, ash products from the 5+2 mixtures were produced. These ash products are rendered comparable to ash produced form suspension fired boilers at power plants. For each of the 7 mixtures, bottom-, cyclone and filter ash was taken out separately resulting in a total of 21 ash samples. The produced ashes have been evaluated for their properties as directly applied fertilizer. Furthermore, scenarios have been set up to assess the feasibility in producing artificial fertilizer from the ash products, based on known processes. In the main components the content of Na, S, Cl and K is significantly higher in filter ashes, whereas the content of Mg, Al, Si and Ca is significantly lower. The

  9. Adhesion Strength of Biomass Ash Deposits

    DEFF Research Database (Denmark)

    Laxminarayan, Yashasvi; Jensen, Peter Arendt; Wu, Hao


    . Therefore, timely removal of ash deposits is essential for optimal boiler operation. In order to improve the qualitative and quantitative understanding of deposit shedding in boilers, this study investigates the shear adhesion strength of biomass ash deposits on superheater tubes. Artificial biomass ash...... deposits were prepared on superheater tubes and sintered in an oven at temperatures up to 1000 °C. Subsequently, the deposits were sheared off by an electrically controlled arm, and the corresponding adhesion strength was measured. The results reveal the effect of temperature, ash/deposit composition......, sintering duration, and steel type on the adhesion strength....

  10. Surface modification of oil fly ash and its application in selective capturing of carbon dioxide (United States)

    Yaumi, Ali L.; Hussien, Ibnelwaleed A.; Shawabkeh, Reyad A.


    Oil fly ash from power generation plants was activated with 30% NH4OH and used for selective adsorption of carbon dioxide from CO2/N2 mixture. The treated samples were characterized for their surface area, morphology, crystalline phase, chemical composition and surface functional groups. Energy dispersive X-ray analysis showed an increase in the carbon contents from 45 to 73 wt% as a result of leaching out metal oxides. XRD proved that chemical activation of ash resulted in diminishing of major crystalline phases of zeolite, and other alumino-silicates leaving only quartz and mullite. BET analysis showed an increase in surface area from 59 to 318 m2/g after chemical activation and the pore volume increased from 0.0368 to 0.679 cm3/g. This increase in pore volume is supported by the results of SEM, where more micropores were opened with well-defined particle sizes and porous structure. The TGA of the treated fly ash showed stability at higher temperature as the weight loss decreased with increasing temperature. For treated ash, the FTIR displayed new peaks of amine functional group. The treated ash was used for the removal of CO2 from CO2/N2 mixture and the maximum adsorption/capturing capacity was found to be 240 mg/g. This capacity increases with increase in initial gas concentration, inlet flow rate and temperature suggesting the endothermic nature of the interaction between the gas molecules and the surface of the ash.

  11. Study of Solid Particle Behavior in High Temperature Gas Flows (United States)

    Majid, A.; Bauder, U.; Stindl, T.; Fertig, M.; Herdrich, G.; Röser, H.-P.


    The Euler-Lagrangian approach is used for the simulation of solid particles in hypersonic entry flows. For flow field simulation, the program SINA (Sequential Iterative Non-equilibrium Algorithm) developed at the Institut für Raumfahrtsysteme is used. The model for the effect of the carrier gas on a particle includes drag force and particle heating only. Other parameters like lift Magnus force or damping torque are not taken into account so far. The reverse effect of the particle phase on the gaseous phase is currently neglected. Parametric analysis is done regarding the impact of variation in the physical input conditions like position, velocity, size and material of the particle. Convective heat fluxes onto the surface of the particle and its radiative cooling are discussed. The variation of particle temperature under different conditions is presented. The influence of various input conditions on the trajectory is explained. A semi empirical model for the particle wall interaction is also discussed and the influence of the wall on the particle trajectory with different particle conditions is presented. The heat fluxes onto the wall due to impingement of particles are also computed and compared with the heat fluxes from the gas.

  12. Effect of Flow Rate of Side-Type Orifice Intake on Withdrawn Water Temperature


    Xueping Gao; Guangning Li; Yunpeng Han


    Side-type orifice intake is a type of selective withdrawal facility used in managing reservoirs to mitigate the negative effects of low-temperature water. Based on the temperature data of a thermal stratified reservoir in China, an experiment was conducted in flume to study the influence of intake flow rate on withdrawn water temperature with different temperature distributions. Results indicated that withdrawn water temperature changed with different flow rates. The temperature change was de...

  13. Ash transformation during co-firing coal and straw

    DEFF Research Database (Denmark)

    Zheng, Yuanjing; Jensen, Peter Arendt; Jensen, Anker Degn;


    Co-firing straw with coal in pulverized fuel boilers can cause problems related to fly ash utilization, deposit formation, corrosion and SCR catalyst deactivation due to the high contents of Cl and K in the ash. To investigate the interaction between coal and straw ash and the effect of coal...... quality on fly ash and deposit properties, straw was co-fired with three kinds of coal in an entrained flow reactor. The compositions of the produced ashes were compared to the available literature data to find suitable scaling parameters that can be used to predict the composition of ash from straw...... importantly, by reaction with Al and Si in the fly ash. About 70-80% K in the fly ash appears as alumina silicates while the remainder K is mainly present as sulphate. Lignite/straw co-firing produces fly ash with relatively high Cl content. This is probably because of the high content of calcium...

  14. 环境温度对蒸压粉煤灰砖混合料消化的影响%Effect of environmental temperature on slaking of autoclaved fly ash brick mixture

    Institute of Scientific and Technical Information of China (English)



      The paper analyzes the effect of environmental temperature on slaking of autoclaved fly ash brick mixture, and the relationship between mixture and environmental temperature.%  分析了蒸压粉煤灰砖影响混合料消化的因素,分析了混合料与环境温度的关系,并对某企业存在的问题给出了解决办法。

  15. Co-combustion of pulverized coal and solid recovered fuel in an entrained flow reactor- General combustion and ash behavior

    DEFF Research Database (Denmark)

    Wu, Hao; Glarborg, Peter; Frandsen, Flemming


    Co-combustion of a bituminous coal and a solid recovered fuel (SRF) was carried out in an entrained flow reactor, and the influence of additives such as NaCl, PVC, ammonium sulphate, and kaolinite on co-combustion was investigated. The co-combustion experiments were carried out with SRF shares of 7...... corrosion potential during co-combustion of coal and SRF, except for the experiments with NaCl or PVC addition....

  16. Effect of temperature on the durability of class C fly ash belite cement in simulated radioactive liquid waste: Synergy of chloride and sulphate ions

    Energy Technology Data Exchange (ETDEWEB)

    Guerrero, A., E-mail: [Eduardo Torroja Institute for Construction Science (CSIC), C/Serrano Galvache, 4, 28033 Madrid (Spain); Goni, S., E-mail: [Eduardo Torroja Institute for Construction Science (CSIC), C/Serrano Galvache, 4, 28033 Madrid (Spain); Allegro, V.R., E-mail: [Eduardo Torroja Institute for Construction Science (CSIC), C/Serrano Galvache, 4, 28033 Madrid (Spain)


    The durability of class C fly ash belite cement (FABC-2-W) in simulated radioactive liquid waste (SRLW) rich in a mixed sodium chloride and sulphate solution is presented here. The effect of the temperature and potential synergic effect of chloride and sulfate ions are discussed. This study has been carried out according to the Koch-Steinegger test, at the temperature of 20 deg. C and 40 deg. C during a period of 180 days. The durability has been evaluated by the changes of the flexural strength of mortar, fabricated with this cement, immersed in a simulated radioactive liquid waste rich in sulfate (0.5 M), chloride (0.5 M) and sodium (1.5 M) ions - catalogued like severely aggressive for the traditional Portland cement - and demineralised water, which was used as reference. The reaction mechanism of sulphate, chloride and sodium ions with the mortar was evaluated by scanning electron microscopy (SEM), porosity and pore-size distribution, and X-ray diffraction (XRD). The results showed that the chloride binding and formation of Friedel's salt was inhibited by the presence of sulphate. Sulphate ion reacts preferentially with the calcium aluminate hydrates forming non-expansive ettringite which precipitated inside the pores; the microstructure was refined and the mechanical properties enhanced. This process was faster and more marked at 40 deg. C.

  17. Effect of temperature on the durability of class C fly ash belite cement in simulated radioactive liquid waste: synergy of chloride and sulphate ions. (United States)

    Guerrero, A; Goñi, S; Allegro, V R


    The durability of class C fly ash belite cement (FABC-2-W) in simulated radioactive liquid waste (SRLW) rich in a mixed sodium chloride and sulphate solution is presented here. The effect of the temperature and potential synergic effect of chloride and sulfate ions are discussed. This study has been carried out according to the Koch-Steinegger test, at the temperature of 20 degrees C and 40 degrees C during a period of 180 days. The durability has been evaluated by the changes of the flexural strength of mortar, fabricated with this cement, immersed in a simulated radioactive liquid waste rich in sulfate (0.5M), chloride (0.5M) and sodium (1.5M) ions--catalogued like severely aggressive for the traditional Portland cement--and demineralised water, which was used as reference. The reaction mechanism of sulphate, chloride and sodium ions with the mortar was evaluated by scanning electron microscopy (SEM), porosity and pore-size distribution, and X-ray diffraction (XRD). The results showed that the chloride binding and formation of Friedel's salt was inhibited by the presence of sulphate. Sulphate ion reacts preferentially with the calcium aluminate hydrates forming non-expansive ettringite which precipitated inside the pores; the microstructure was refined and the mechanical properties enhanced. This process was faster and more marked at 40 degrees C.

  18. Direct Quantitative Analysis of Arsenic in Coal Fly Ash

    Directory of Open Access Journals (Sweden)

    Sri Hartuti


    Full Text Available A rapid, simple method based on graphite furnace atomic absorption spectrometry is described for the direct determination of arsenic in coal fly ash. Solid samples were directly introduced into the atomizer without preliminary treatment. The direct analysis method was not always free of spectral matrix interference, but the stabilization of arsenic by adding palladium nitrate (chemical modifier and the optimization of the parameters in the furnace program (temperature, rate of temperature increase, hold time, and argon gas flow gave good results for the total arsenic determination. The optimal furnace program was determined by analyzing different concentrations of a reference material (NIST1633b, which showed the best linearity for calibration. The optimized parameters for the furnace programs for the ashing and atomization steps were as follows: temperatures of 500–1200 and 2150°C, heating rates of 100 and 500°C s−1, hold times of 90 and 7 s, and medium then maximum and medium argon gas flows, respectively. The calibration plots were linear with a correlation coefficient of 0.9699. This method was validated using arsenic-containing raw coal samples in accordance with the requirements of the mass balance calculation; the distribution rate of As in the fly ashes ranged from 101 to 119%.

  19. High energy sodium based room temperature flow batteries (United States)

    Shamie, Jack

    As novel energy sources such as solar, wind and tidal energies are explored it becomes necessary to build energy storage facilities to load level the intermittent nature of these energy sources. Energy storage is achieved by converting electrical energy into another form of energy. Batteries have many properties that are attractive for energy storage including high energy and power. Among many different types of batteries, redox flow batteries (RFBs) offer many advantages. Unlike conventional batteries, RFBs store energy in a liquid medium rather than solid active materials. This method of storage allows for the separation of energy and power unlike conventional batteries. Additionally flow batteries may have long lifetimes because there is no expansion or contraction of electrodes. A major disadvantage of RFB's is its lower energy density when compared to traditional batteries. In this Thesis, a novel hybrid Na-based redox flow battery (HNFB) is explored, which utilizes a room temperature molten sodium based anode, a sodium ion conducting solid electrolyte and liquid catholytes. The sodium electrode leads to high voltages and energy and allows for the possibility of multi-electron transfer per molecule. Vanadium acetylacetonate (acac) and TEMPO have been investigated for their use as catholytes. In the vanadium system, 2 electrons transfers per vanadium atom were found leading to a doubling of capacity. In addition, degradation of the charged state was found to be reversible within the voltage range of the cell. Contamination by water leads to the formation of vanadyl acetylacetonate. Although it is believed that vanadyl complex need to be taken to low voltages to be reduced back to vanadium acac, a new mechanism is shown that begins at higher voltages (2.1V). Vanadyl complexes react with excess ligand and protons to reform the vanadium complex. During this reaction, water is reformed leading to the continuous cycle in which vanadyl is formed and then reduced back

  20. Efficiency of using direct-flow burners and nozzles in implementation of dry-bottom ash removal at the TPP-210A boiler furnace (United States)

    Arkhipov, A. M.; Kanunnikov, A. A.; Kirichkov, V. S.; Prokhorov, V. B.; Fomenko, M. V.; Chernov, S. L.


    In reconstruction of operating pulverized coal-fired boilers, one of the main factors is the choice of a method for slag removal: dry bottom ash removal (DBAR) or slag-tap removal (STR). In this case, ecological and economic aspects should be taken into account, and also the early ignition of pulverized coal fuel, the reliability of operation of the furnace walls in the mode without slagging, and the stability of slag removal should be provided. In this work, issues of changeover of the pulverized coal-fired boilers of the TPP-210A type from the STR mode to the DBAR mode are considered. As of today, the main problems during the operation of these boilers are the high emissions of nitrogen oxides together with flue gases into the atmosphere and the appropriated payoffs, a small range of loads available, the necessity of stabilization of the pulverizedcoal flame sustainability by using the highly reactive fuel, large mechanical fuel underburning, etc. Results of studying aerodynamics of a furnace with DBAR obtained in the process of physical simulation are given; technical solutions and preliminary design (configuration of burners and nozzles in the boiler furnace, conceptual design of the pulverized coal burner, configuration of TPP-210A boiler with the low heat liberation of furnace cross-section and volumetric heat release) are set forth, which are associated with the optimization of aerodynamics of furnace volume, when the direct-flow burners and nozzles are used, and with organization of the efficient staged combustion of solid fuel. Two versions of possible modernization of a boiler unit are considered. Under conditions of the planned increase in the steam production capacity, the most promising measures are as follows: the DBAR implementation with reducing heat releases of the cross-section and volume of the furnace approximately by half, the installation of the direct-flow burners and nozzles with injection of recirculation gases into the active combustion

  1. 盐酸改性粉煤灰净化低温低浊水的试验研究%The Experimental Research on Purifying Low Temperature and Low Turbidity Water by Hydrochloric Acid Modified Fly Ash

    Institute of Scientific and Technical Information of China (English)

    刘书贤; 魏晓刚; 王伟; 杜平; 肖利萍


    由于粉煤灰具有良好的吸附性能且富含硅、铝和铁等元素,将其作为助凝剂,用盐酸对粉煤灰改性后与聚合硫酸铁PFS联合使用处理低温低浊水.在用盐酸对粉煤灰进行改性时,研究了振荡时间、振荡速度、盐酸浓度等试验因素对改性粉煤灰吸附助凝效果的影响,得出盐酸改性粉煤灰的最佳试验条件为:振荡器振荡速度80 r/min,100 mL 3.6 mol/L盐酸与5g预处理粉煤灰混合振荡3h,试验温度25℃.改性后粉煤灰的比表面积明显增加,并且粉煤灰中部分硅、铝和铁等元素溶出,转变成具有很好絮凝作用的Al3+、Fe3+和H2SiO3,粘附于粉煤灰表面,在处理低温低浊水的过程中能较好地发挥吸附助凝效果.%Becaouse of the excellent adsorption performance and high containing of silicon, aluminum and iron and other elements, fly ash by hydrochloric acid modified was used as a coagulant to purify low temperature and low turbidity water with reagent PFS. When the fly ash were modified by hydrochloric acid, the experimental factors just as duration of oscillation, speed of oscillation and hydrochloric acid concentration were researched. The best experimental conditions of hydrochloric acid modification were follows: the speed of oscillation 80r/min, 100 mL 3.6 mol/L of hydrochloric acid and 5 g the coal fly ash mixed in the oscillator for about 3 h, the experiment temperature 25 ℃. The specific surface of modified fly ash increased significantly, the elements such as silicon, aluminum and iron dissolved from fly ash and they turned into Al3+, Fe3+ and H2SiO3 (adhesion on the surface of fly ash) whose flocculation were strong. In the process of purifying low temperature and low turbidity water by hydrochloric acid modified fly ash, the adsorptive property can be exerted effectively.

  2. 灰化温度及热解气氛对生物质灰灼烧失重特性的影响%Influence of ashing temperature and pyrolysis atmosphere on weight loss properties of biomass ash obtained by combustion

    Institute of Scientific and Technical Information of China (English)

    姚锡文; 许开立


    Nowadays, sustainable development and increasing fuel demand necessitate the identification of possible energy resources. Biomass resource is regarded as a green renewable energy and will be more important in the future, which attracts the worldwide attention regarding their renewable nature, carbon dioxide-neutral characteristic, and world-wide availability. Consequently, many countries are putting great emphasis on the exploration of bio-energy. However, the use of biomass as fuel generates a large amount of residual ash, which causes serious environmental problems and has great passive influence on the chemical conversion of biomass. The biomass ash is easy to melt and volatilize, and it can not only reduce the utilization efficiency of equipment but also shorten their service life. Moreover, the inorganic species existing in biomass such as alkali oxides and salts can aggravate agglomeration, deposition, and corrosion problems on boiler’s heat transfer surfaces. So during the combustion or gasification processing, the ash with complex composition and high volatility often leads to slugging and erosion/corrosion in thermal conversion processing systems. Rice husk (RH) and rice straw (RS) are the main by-products during the process of rice processing, and they are the clean and renewable energy. Especially, in comparison to other agricultural wastes, the ash content of RH is much higher. So far, a series of studies have been carried out to investigate the characteristics of biomass ash through experiment. But the studies on the influence of ashing temperature and pyrolysis atmosphere on the properties of biomass ash are limited. In this paper, in order to investigate the weight loss regularities of biomass ash at different ashing temperature and pyrolysis atmosphere, thermogravimetric analysis was conducted to comparatively study the pyrolysis weight loss mechanism of rice husk ash (RHA) and rice straw ash (RSA) ashing at 600 and 815℃ in air and nitrogen. The

  3. Characterization of ashes from biofuels

    Energy Technology Data Exchange (ETDEWEB)

    Frandsen, F.J.; Hansen, L.A. [Technical Univ. of Denmark. Dept. of Chemical Engineering (Denmark); Soerensen, H.S. [Geological Survey of Denmark and Greenland (Denmark); Hjuler, K. [dk-TEKNIK. Energy and Environment (Denmark)


    One motivation for initiating the present project was that the international standard method of estimating the deposit propensity of solid fuels, of which a number of variants exist (e.g. ISO, ASTM, SD, DIN), has shown to be unsuitable for biomass ashes. This goal was addressed by the development of two new methods for the detection of ash fusibility behaviour based on Simultaneous Thermal Analysis (STA) and High Temperature Light Microscopy (HTLM), respectively. The methods were developed specifically for ashes from biofuels, but are suitable for coal ashes as well. They have been tested using simple salt mixtures, geological standards and samples from straw CHP and coal-straw PF combustion plants. All samples were run in a nitrogen atmosphere at a heating rate of 10 deg. C/min. In comparison with the standard method, the new methods are objective and have superior repeatability and sensitivity. Furthermore, the two methods enable the melting behavior to be characterized by a continuous measurement of melt fraction versus temperature. Due to this two-dimensional resolution of the results, the STA and HTLM methods provide more information than the standard method. The study of bottom ash and fly ash as well as deposit samples from straw test firings at the Haslev and Slagelse Combined Heat and Power plants resulted in a better understanding of mineral behaviour during straw grate firing. In these tests a number of straws were fired which had been carefully selected for having different qualities with respect to sort and potassium and chlorine contents. By studying bottom ashes from Slagelse it was found that the melting behaviour correlated with the deposition rate on a probe situated at the outlet part of the combustion zone. (EG)

  4. Magnetic properties in an ash flow tuff with continuous grain size variation: a natural reference for magnetic particle granulometry (United States)

    Till, J.L.; Jackson, M.J.; Rosenbaum, J.G.; Solheid, P.


    The Tiva Canyon Tuff contains dispersed nanoscale Fe-Ti-oxide grains with a narrow magnetic grain size distribution, making it an ideal material in which to identify and study grain-size-sensitive magnetic behavior in rocks. A detailed magnetic characterization was performed on samples from the basal 5 m of the tuff. The magnetic materials in this basal section consist primarily of (low-impurity) magnetite in the form of elongated submicron grains exsolved from volcanic glass. Magnetic properties studied include bulk magnetic susceptibility, frequency-dependent and temperature-dependent magnetic susceptibility, anhysteretic remanence acquisition, and hysteresis properties. The combined data constitute a distinct magnetic signature at each stratigraphic level in the section corresponding to different grain size distributions. The inferred magnetic domain state changes progressively upward from superparamagnetic grains near the base to particles with pseudo-single-domain or metastable single-domain characteristics near the top of the sampled section. Direct observations of magnetic grain size confirm that distinct transitions in room temperature magnetic susceptibility and remanence probably denote the limits of stable single-domain behavior in the section. These results provide a unique example of grain-size-dependent magnetic properties in noninteracting particle assemblages over three decades of grain size, including close approximations of ideal Stoner-Wohlfarth assemblages, and may be considered a useful reference for future rock magnetic studies involving grain-size-sensitive properties.

  5. Ash Deposition Trials at Three Power Stations in Denmark

    DEFF Research Database (Denmark)

    Laursen, Karin; Frandsen, Flemming; Larsen, Ole Hede


    the probe temperature did influence the composition of deposits for coals with medium ash deposition propensities. These results may indicate that coals with medium to high ash deposition propensities in existing boilers may cause increasing ash deposit formation in future boilers with higher steam...

  6. Properties and Leachability of Self-Compacting Concrete Incorporated with Fly Ash and Bottom Ash (United States)

    Kadir, Aeslina Abdul; Ikhmal Haqeem Hassan, Mohd; Jamaluddin, Norwati; Bakri Abdullah, Mohd Mustafa Al


    The process of combustion in coal-fired power plant generates ashes, namely fly ash and bottom ash. Besides, coal ash produced from coal combustion contains heavy metals within their compositions. These metals are toxic to the environment as well as to human health. Fortunately, treatment methods are available for these ashes, and the use of fly ash and bottom ash in the concrete mix is one of the few. Therefore, an experimental program was carried out to study the properties and determine the leachability of selfcompacting concrete incorporated with fly ash and bottom ash. For experimental study, self-compacting concrete was produced with fly ash as a replacement for Ordinary Portland Cement and bottom ash as a replacement for sand with the ratios of 10%, 20%, and 30% respectively. The fresh properties tests conducted were slump flow, t500, sieve segregation and J-ring. Meanwhile for the hardened properties, density, compressive strength and water absorption test were performed. The samples were then crushed to be extracted using Toxicity Characteristic Leaching Procedure and heavy metals content within the samples were identified accordingly using Atomic Absorption Spectrometry. The results demonstrated that both fresh and hardened properties were qualified to categorize as self-compacting concrete. Improvements in compressive strength were observed, and densities for all the samples were identified as a normal weight concrete with ranges between 2000 kg/m3 to 2600 kg/m3. Other than that, it was found that incorporation up to 30% of the ashes was safe as the leached heavy metals concentration did not exceed the regulatory levels, except for arsenic. In conclusion, this study will serve as a reference which suggests that fly ash and bottom ash are widely applicable in concrete technology, and its incorporation in self-compacting concrete constitutes a potential means of adding value to appropriate mix and design.

  7. Volcanic ash infrared signature: porous non-spherical ash particle shapes compared to homogeneous spherical ash particles (United States)

    Kylling, A.; Kahnert, M.; Lindqvist, H.; Nousiainen, T.


    The reverse absorption technique is often used to detect volcanic ash clouds from thermal infrared satellite measurements. From these measurements effective particle radius and mass loading may be estimated using radiative transfer modelling. The radiative transfer modelling usually assumes that the ash particles are spherical. We calculated thermal infrared optical properties of highly irregular and porous ash particles and compared these with mass- and volume-equivalent spherical models. Furthermore, brightness temperatures pertinent to satellite observing geometry were calculated for the different ash particle shapes. Non-spherical shapes and volume-equivalent spheres were found to produce a detectable ash signal for larger particle sizes than mass-equivalent spheres. The assumption of mass-equivalent spheres for ash mass loading estimates was found to underestimate mass loading compared to morphologically complex inhomogeneous ash particles. The underestimate increases with the mass loading. For an ash cloud recorded during the Eyjafjallajökull 2010 eruption, the mass-equivalent spheres underestimate the total mass of the ash cloud by approximately 30% compared to the morphologically complex inhomogeneous particles.

  8. ExB mean flows in finite ion temperature plasmas

    CERN Document Server

    Madsen, J; Naulin, V; Nielsen, A H


    The impact of ion pressure dynamics on E x B mean flows is investigated. Three stresses in addition to the Reynolds stress are shown to modify the E x B mean flow. These additional terms in the stress tensor all require ion pressure fluctuations. Quasi-linear analysis indicates that these additional stresses are as important as the standard Reynolds stress and hence must be taken into account in analysis of E x B mean flows.

  9. Water temperature in irrigation return flow from the Upper Snake Rock watershed (United States)

    Water returning to a river from an irrigated watershed could increase the water temperature in the river. The objective of this study was to compare the temperature of irrigation return flow water with the temperature of the diverted irrigation water. Water temperature was measured weekly in the mai...

  10. Experimental Study on an On-Line Measurement of High Temperature Circulating Ash Flux in a Circulating Fluidized Bed Boiler

    Institute of Scientific and Technical Information of China (English)

    Lu Xiaofeng; Li Yourong


    A new kind of measuring method that may be used to measure high temperature circulating solid particles flux in a circulating fluidized bed boiler is studied in this paper. The measuring method is founded on the principle of thermal equilibrium. A series of cold tests and hot tests were carried to optimize the structure and collocation of water-cooling tubes and showed that the method had the advantage of simple, accurate, reliable and good applicability for on-line usage in a circulating fluidized bed boiler.

  11. Volcanic ash: What it is and how it forms

    Energy Technology Data Exchange (ETDEWEB)

    Heiken, G.


    There are four basic eruption processes that produce volcanic ash: (1) decompression of rising magma, gas bubble growth, and fragmentation of the foamy magma in the volcanic vent (magmatic), (2) explosive mixing of magma with ground or surface water (hydrovolcanic), (3) fragmentation of country rock during rapid expansion of steam and/or hot water (phreatic), and (4) breakup of lava fragments during rapid transport from the vent. Variations in eruption style and the characteristics of volcanic ashes produced during explosive eruptions depend on many factors, including magmatic temperature, gas content, viscosity and crystal content of the magma before eruption, the ratio of magma to ground or surface water, and physical properties of the rock enclosing the vent. Volcanic ash is composed of rock and mineral fragments, and glass shards, which is less than 2 mm in diameter. Glass shard shapes and sizes depend upon size and shape of gas bubbles present within the magma immediately before eruption and the processes responsible for fragmentation of the magma. Shards range from slightly curved, thin glass plates, which were broken from large, thin-walled spherical bubble walls, to hollow needles broken from pumiceous melts containing gas bubbles stretched by magma flow within the volcanic vent. Pumice fragments make up the coarser-grained portions of the glass fraction. Particle sizes range from meters for large blocks expelled near the volcanic vent to nanometers for fine ash and aerosol droplets within well-dispersed eruption plumes. 18 refs., 6 figs., 1 tab.

  12. Combustion of stoker ash in a CFBC

    Energy Technology Data Exchange (ETDEWEB)

    Jia, L.; Anthony, E.J. [Natural Resources Canada, Ottawa, ON (Canada). CANMET Energy Technology Centre


    The ash generated from petroleum coke fired stokers at Georgia Pacific in Wisconsin has an elevated carbon content and a higher fuel value. This paper presents results of a study in which the stoker ash was test fired at the CANMET Energy Technology Centre in a bench scale circulating fluidized bed combustor (CFBC). The objective was to determine if firing the stoker ash in its 'as received' state (with a 40 per cent moisture content) is a viable fuel option for Georgia Pacific's FBC boiler to save fuel costs, or if it should be co-fired with petroleum coke. Mixtures of the stoker ash and petroleum coke were also test fired. Results indicate that the stoker ash alone cannot sustain combustion. However, good ignition and even bed temperature is possible with premixed coke and 10 per cent less moisture content. Emissions of sulphur dioxides, nitrogen oxides carbon monoxide were the same as for firing petroleum coke alone. In addition, the co-firing of stoker ash and petroleum coke did not negatively affect the tendency to foul, compared to firing coke alone. The amount of ash generated from the FBC boiler was high due to the high ash content. An economic evaluation showed that firing a 20/80 coke/stoker ash mixture can save approximately 22 per cent of the limestone usage compared to coke firing alone, if the Ca/S molar ratio remain the same. 8 refs., 2 tabs., 1 fig.

  13. Volcanic ash impacts on critical infrastructure (United States)

    Wilson, Thomas M.; Stewart, Carol; Sword-Daniels, Victoria; Leonard, Graham S.; Johnston, David M.; Cole, Jim W.; Wardman, Johnny; Wilson, Grant; Barnard, Scott T.


    Volcanic eruptions can produce a wide range of hazards. Although phenomena such as pyroclastic flows and surges, sector collapses, lahars and ballistic blocks are the most destructive and dangerous, volcanic ash is by far the most widely distributed eruption product. Although ash falls rarely endanger human life directly, threats to public health and disruption to critical infrastructure services, aviation and primary production can lead to significant societal impacts. Even relatively small eruptions can cause widespread disruption, damage and economic loss. Volcanic eruptions are, in general, infrequent and somewhat exotic occurrences, and consequently in many parts of the world, the management of critical infrastructure during volcanic crises can be improved with greater knowledge of the likely impacts. This article presents an overview of volcanic ash impacts on critical infrastructure, other than aviation and fuel supply, illustrated by findings from impact assessment reconnaissance trips carried out to a wide range of locations worldwide by our international research group and local collaborators. ‘Critical infrastructure’ includes those assets, frequently taken for granted, which are essential for the functioning of a society and economy. Electricity networks are very vulnerable to disruption from volcanic ash falls. This is particularly the case when fine ash is erupted because it has a greater tendency to adhere to line and substation insulators, where it can cause flashover (unintended electrical discharge) which can in turn cause widespread and disruptive outages. Weather conditions are a major determinant of flashover risk. Dry ash is not conductive, and heavy rain will wash ash from insulators, but light rain/mist will mobilise readily-soluble salts on the surface of the ash grains and lower the ash layer’s resistivity. Wet ash is also heavier than dry ash, increasing the risk of line breakage or tower/pole collapse. Particular issues for water

  14. Thermographic investigation of surface temperature of the evaporating liquid layer under the action of gas flow

    Directory of Open Access Journals (Sweden)

    Kreta Aleksei


    Full Text Available An experimental study of the temperature field on the surface of horizontal liquid layer (Ethanol evaporating into gas flow (Air has been performed. Temperature gradient of the gas-liquid interface has been measured with the help of Titanium 570M IR camera. Shear stresses on gas-liquid interface induced by thermocapillary effect and inert gas flow have been defined.

  15. Heat-conduction error of temperature sensors in a fluid flow with nonuniform and unsteady temperature distribution. (United States)

    Khine, Soe Minn; Houra, Tomoya; Tagawa, Masato


    In temperature measurement of non-isothermal fluid flows by a contact-type temperature sensor, heat conduction along the sensor body can cause significant measurement error which is called "heat-conduction error." The conventional formula for estimating the heat-conduction error was derived under the condition that the fluid temperature to be measured is uniform. Thus, if we apply the conventional formula to a thermal field with temperature gradient, the heat-conduction error will be underestimated. In the present study, we have newly introduced a universal physical model of a temperature-measurement system to estimate accurately the heat-conduction error even if a temperature gradient exists in non-isothermal fluid flows. Accordingly, we have been able to successfully derive a widely applicable estimation and/or evaluation formula of the heat-conduction error. Then, we have verified experimentally the effectiveness of the proposed formula using the two non-isothermal fields-a wake flow formed behind a heated cylinder and a candle flame-whose fluid-dynamical characteristics should be quite different. As a result, it is confirmed that the proposed formula can represent accurately the experimental behaviors of the heat-conduction error which cannot be explained appropriately by the existing formula. In addition, we have analyzed theoretically the effects of the heat-conduction error on the fluctuating temperature measurement of a non-isothermal unsteady fluid flow to derive the frequency response of the temperature sensor to be used. The analysis result shows that the heat-conduction error in temperature-fluctuation measurement appears only in a low-frequency range. Therefore, if the power-spectrum distribution of temperature fluctuations to be measured is sufficiently away from the low-frequency range, the heat-conduction error has virtually no effect on the temperature-fluctuation measurements even by the temperature sensor accompanying the heat-conduction error in

  16. Update of Columbia River flow and temperature data measured at Priest Rapids Dam and Vernita Bridge

    Energy Technology Data Exchange (ETDEWEB)

    Whelan, G.; Newbill, C.A.


    Columbia River temperatures and flow rates are collected daily at Priest Rapids Dam and Vernita Bridge. These data are necessary for assessing trends or changes in river conditions downstream of Priest Rapids Dam. In order to analyze this data, Pacific Northwest Laboratory developed a computerized data base using existing US Geological Survey flow and temperature records at Priest Rapids Dam and Vernita Bridge. Daily-averaged temperature and daily flow information on the Columbia River just downstream of Priest Rapids Dam and upstream of river mile 380 were collected and stored in a data base. A newly developed computer model, COLSTAT (Columbia River Statistical Update), used the data base to statistically analyze temperature and flow conditions by computing the frequency of occurrence and duration of selected temperatures and flow rates for the Columbia River. Information regarding the data base is presented, as well as, a description of the COLSTAT model.

  17. Spectral Properties of a Two Component and Two Temperature Advective Flow

    CERN Document Server

    Mandal, S; Mandal, Samir; Chakrabarti, Sandip K.


    Low angular momentum accretion flows very often have centrifugal pressure supported standing shock waves which can accelerate flow particles. The accelerated particles in turn emit synchrotron radiation in presence of magnetic fields. Efficient cooling of the electrons reduces its temperature in comparison to the protons. In this paper, we assume two temperature flows to explore this property of shocks and present an example of the emitted radiation spectrum.

  18. Evaluation of ash deposits during experimental investigation of co-firing of Bosnian coal with wooden biomass

    Energy Technology Data Exchange (ETDEWEB)

    Smajevic, Izet; Kazagic, Anes [JP Elektroprivreda BiH d.d., Sarajevo (Bosnia and Herzegovina); Sarajevo Univ. (Bosnia and Herzegovina). Faculty of Mechanical Engineering


    The paper is addressed to the development and use different criteria for evaluation of ash deposits collected during experimental co-firing of Bosnian coals with wooden biomass. Spruce saw dust was used for the co-firing tests with the Kakanj brown coal and with a lignite blend consisted of the Dubrave lignite and the Sikulje lignite. The coal/biomass mixtures at 93:7 %w and at 80:20 %w were tested. Experimental lab-scale facility PF entrained flow reactor is used for the co-firing tests. The reactor allows examination of fouling/slagging behaviors and emissions at various and infinitely variable process temperature which can be set at will in the range from ambient to 1560 C. Ash deposits are collected on two non-cooled ceramic probes and one water-cooled metal surface. Six different criteria are developed and used to evaluate behavior of the ash deposits on the probes: ash deposit shape, state and structure, which are analyzed visually - photographically and optically by a microscope, rate of adhesion and ash deposit strength, analyzed by physic acting to the ash deposits, and finally deposition rate, determined as a mass of the deposit divided by the collecting area and the time of collecting. Furthermore, chemical composition analysis and AFT of the ash deposits were also done to provide additional information on the deposits. (orig.)

  19. Adhesion Strength of Biomass Ash Deposits

    DEFF Research Database (Denmark)

    Laxminarayan, Yashasvi; Jensen, Peter Arendt; Wu, Hao


    This study investigates the shear adhesion strength of biomass ash deposits on superheater tubes. Artificial biomass ash deposits were prepared on superheater tubes and sintered in an oven at temperatures up to 1000°C. Subsequently, the deposits were sheared off with the help of an electrically...... controlled arm. Higher sintering temperatures resulted in greater adhesion strengths, with a sharp increase observed near the melting point of the ash. Repetition of experiments with fixed operation conditions revealed considerable variation in the obtained adhesion strengths, portraying the stochastic...

  20. Effect of Flow Rate of Side-Type Orifice Intake on Withdrawn Water Temperature

    Directory of Open Access Journals (Sweden)

    Xueping Gao


    Full Text Available Side-type orifice intake is a type of selective withdrawal facility used in managing reservoirs to mitigate the negative effects of low-temperature water. Based on the temperature data of a thermal stratified reservoir in China, an experiment was conducted in flume to study the influence of intake flow rate on withdrawn water temperature with different temperature distributions. Results indicated that withdrawn water temperature changed with different flow rates. The temperature change was determined by the water temperature gradients above and below the intake, whereas the change trend of temperature depended on the difference between the water temperature gradient above and below the intake. We likewise proposed a new equation with which the withdrawn water temperature of a thermal stratified reservoir using a side-type orifice could be calculated. These findings could be directly applied to the design and operation of side-type orifice intake in thermal stratified reservoirs.

  1. Effect of flow rate of side-type orifice intake on withdrawn water temperature. (United States)

    Gao, Xueping; Li, Guangning; Han, Yunpeng


    Side-type orifice intake is a type of selective withdrawal facility used in managing reservoirs to mitigate the negative effects of low-temperature water. Based on the temperature data of a thermal stratified reservoir in China, an experiment was conducted in flume to study the influence of intake flow rate on withdrawn water temperature with different temperature distributions. Results indicated that withdrawn water temperature changed with different flow rates. The temperature change was determined by the water temperature gradients above and below the intake, whereas the change trend of temperature depended on the difference between the water temperature gradient above and below the intake. We likewise proposed a new equation with which the withdrawn water temperature of a thermal stratified reservoir using a side-type orifice could be calculated. These findings could be directly applied to the design and operation of side-type orifice intake in thermal stratified reservoirs.

  2. Constant-temperature hot-wire anemometer practice in supersonic flows. II - The inclined wire (United States)

    Smits, A. J.; Muck, K. C.


    The performance of a constant-temperature inclined hot-wire in a supersonic flow is critically examined. It is shown that calibration techniques applicable to subsonic flow, such as the cosine cooling law cannot be used when the flow is supersonic. Calibration and measurement procedures appropriate to supersonic flow are suggested, together with the possible limits on their validity. Experimental results for different wires indicate that the sensitivities do not seem to depend on flow direction according to any simple correlation. When the sensitivity exhibits a strong dependence on flow direction, the wire should be discarded to avoid errors due to nonlinear effects.

  3. Speciation of Chromium in Bottom Ash Obtained by the Incineration of the Leather Waste Shavings

    Directory of Open Access Journals (Sweden)

    k. louhab


    Full Text Available The evolution of bottom ash morphology and chromium metals behavior during incineration of a leather waste shavings at different incineration temperature have been studied. The Cr, Ca, Mg, Cl rates in bottom ashes, flay ashes and emitted gases in different incineration temperature of the tannery wastes are also determined. The morphology of the bottom ashes obtained by incineration at different temperature from the leather waste shavings was examined by MEB. The result show that the temperature and the length of incineration influence on the structure of the bottom ash and on the chromium in the bottom ash.

  4. Utilization of blended fluidized bed combustion (FBC) ash and pulverized coal combustion (PCC) fly ash in geopolymer. (United States)

    Chindaprasirt, Prinya; Rattanasak, Ubolluk


    In this paper, synthesis of geopolymer from fluidized bed combustion (FBC) ash and pulverized coal combustion (PCC) fly ash was studied in order to effectively utilize both ashes. FBC-fly ash and bottom ash were inter-ground to three different finenesses. The ashes were mixed with as-received PCC-fly ash in various proportions and used as source material for synthesis of geopolymer. Sodium silicate (Na(2)SiO(3)) and 10M sodium hydroxide (NaOH) solutions at mass ratio of Na(2)SiO(3)/NaOH of 1.5 and curing temperature of 65 degrees C for 48h were used for making geopolymer. X-ray diffraction (XRD), scanning electron microscopy (SEM), degree of reaction, and thermal gravimetric analysis (TGA) were performed on the geopolymer pastes. Compressive strength was also tested on geopolymer mortars. The results show that high strength geopolymer mortars of 35.0-44.0MPa can be produced using mixture of ground FBC ash and as-received PCC-fly ash. Fine FBC ash is more reactive and results in higher degree of reaction and higher strength geopolymer as compared to the use of coarser FBC ash. Grinding increases reactivity of ash by means of increasing surface area and the amount of reactive phase of the ash. In addition, the packing effect due to fine particles also contributed to increase in strength of geopolymers.

  5. Effect of Acupuncture Manipulations at LI4 or LI11 on Blood Flow and Skin Temperature. (United States)

    Li, Weihui; Ahn, Andrew


    Acupuncture induces physiological changes, and patients have reported warm or cool sensations with "Burning Fire" (BF) or "Penetrating Cool" (PC) manipulations. This study aimed to evaluate whether these techniques had distinct effects on skin temperature and blood flow and to examine whether skin temperature correlated with blood flow. The participants were 25 healthy volunteers, each receiving acupuncture manipulations on points LI4 and LI11 bilaterally. Skin temperatures and blood flow were recorded continuously on both arms. The study found that acupuncture significantly increased skin temperature on the needling arm by 0.3514°C on average, but decreased it on the contralateral arm by 0.2201°C on average. Blood flow decreased significantly in both arms during needling (-3.4% and -5.97% for the ipsilateral and the contralateral sides, respectively), but the changes in skin temperature did not correlate with the changes in blood flow. Furthermore, these changes were not significantly different between acupuncture techniques and acupuncture points. In conclusion, acupuncture changes local skin temperature and blood flow independent of the manipulation technique. Moreover, blood flow may not be affected by the increased temperature on the needling arm. These results help to verify traditional Chinese medicine concepts and may help in establishing standards for acupuncture treatments.

  6. Heat flow and temperature-depth curves throughout Alaska: finding regions for future geothermal exploration (United States)

    Batir, Joseph F.; Blackwell, David D.; Richards, Maria C.


    The objective of this research is to contribute to the understanding of the thermal regime of Alaska and its relationship to geology, regional tectonics, and to suggest potential sites for future geothermal energy production. New heat flow data were collected and are combined with existing published and unpublished data, although large sections of Alaska still lack data. Fault traces were implemented into the heat flow contouring as an additional gridding constraint, to incorporate both heat flow measurements and geology. New heat flow data supported the use of geologic trends in the heat flow mapping procedure, and a heat flow map of Alaska was produced with this added constraint. The multi-input contouring strategy allows production of a map with a regional interpretation of heat flow, in addition to site-specific heat flow and thermal model interpretations in areas with sufficient data density. Utilizing the new heat flow map, temperature-at-depth curves were created for example areas. Temperature-at-depth curves are calculated to 10 km depth for the areas of Anchorage, Fairbanks, Juneau, the Alaska Peninsula, Bristol Bay, and the Copper River Basin. The temperatures-at-depth predicted near the population centers of Anchorage and Juneau are relatively low, limiting the geothermal resource potential. The Fairbanks area temperature estimates are near conventional power production temperatures (150 °C) between 3.5 and 4 km. All data areas, except at Juneau, have temperatures sufficient for low temperature geothermal applications (40 °C) by 2 km. A high heat flow region exists within the Aleutian Volcanic Arc, although new data show heat flow variations from 59 to 120 mW m-2, so individual geothermal resources within the arc will be irregularly located.

  7. [Ash Meadows Purchase Proposal (United States)

    US Fish and Wildlife Service, Department of the Interior — A proposal sent to the Richard King Mellon Foundation for a loan to fund the purchase of Ash Meadows by the Nature Conservancy. Ash Meadows, set outside of Las Vegas...

  8. Spectroscopic measurements of impurity temperatures and parallel ion flows in the DIII-D divertor

    Energy Technology Data Exchange (ETDEWEB)

    Isler, R.C. [Oak Ridge National Lab., TN (United States); Brooks, N.H.; West, W.P.; Leonard, A.W. [General Atomics, San Diego, CA (United States); McKee, G.R. [Univ. of Wisconsin, Madison, WI (United States); Porter, G.D. [Lawrence Livermore National Lab., CA (United States)


    Impurity ion temperatures and parallel flow velocities in the DIII-D divertor have been measured from the shapes and shifts of visible spectral lines of C II, C III, and B II. Spectral multiplet patterns are analyzed by fitting them to theoretical profiles that incorporate exact calculations for the Zeeman/Paschen-Back effect. Ion temperatures range from 4--20 eV. Both normal flows toward the target plate and reversed flows away from the target plate are observed in the outer divertor leg; only flows toward the plate are detected in the inner leg.

  9. Micromachined lab-on-a-tube sensors for simultaneous brain temperature and cerebral blood flow measurements. (United States)

    Li, Chunyan; Wu, Pei-Ming; Hartings, Jed A; Wu, Zhizhen; Cheyuo, Cletus; Wang, Ping; LeDoux, David; Shutter, Lori A; Ramaswamy, Bharat Ram; Ahn, Chong H; Narayan, Raj K


    This work describes the development of a micromachined lab-on-a-tube device for simultaneous measurement of brain temperature and regional cerebral blood flow. The device consists of two micromachined gold resistance temperature detectors with a 4-wire configuration. One is used as a temperature sensor and the other as a flow sensor. The temperature sensor operates with AC excitation current of 500 μA and updates its outputs at a rate of 5 Hz. The flow sensor employs a periodic heating and cooling technique under constant-temperature mode and updates its outputs at a rate of 0.1 Hz. The temperature sensor is also used to compensate for temperature changes during the heating period of the flow sensor to improve the accuracy of flow measurements. To prevent thermal and electronic crosstalk between the sensors, the temperature sensor is located outside the "thermal influence" region of the flow sensor and the sensors are separated into two different layers with a thin-film Copper shield. We evaluated the sensors for accuracy, crosstalk and long-term drift in human blood-stained cerebrospinal fluid. These in vitro experiments showed that simultaneous temperature and flow measurements with a single lab-on-a-tube device are accurate and reliable over the course of 5 days. It has a resolution of 0.013 °C and 0.18 ml/100 g/min; and achieves an accuracy of 0.1 °C and 5 ml/100 g/min for temperature and flow sensors respectively. The prototype device and techniques developed here establish a foundation for a multi-sensor lab-on-a-tube, enabling versatile multimodality monitoring applications.

  10. Activation Energy for Superplastic Flow Above Critical Temperature of Die Steels

    Institute of Scientific and Technical Information of China (English)

    WEN Jiu-ba; ZHANG Ke-ke; CHEN Fu-xiao; YANG Yong-shun


    Some commercial cold working die steels GCr15 and CrWMn with ultra-fine grain size were chosen as tested materials to research the activation energy for superplastic flow at different temperatures and strain rates above critical temperature. Based on the Arrhenius equation, the activation energy for superplastic flow is evaluated. The activation energy at constant strain rate is estimated by the logσt vs 1/T relationship. The results show that the activation energy is usually small under the conditions of optimal flow. The characteristics of superplastic deformation of steels above the critical temperature were also analyzed.

  11. Reburning Characteristics of Residual Carbon in Fly Ash from CFB Boilers (United States)

    Zhang, S. H.; Luo, H. H.; Chen, H. P.; Yang, H. P.; Wang, X. H.

    The content of residual carbon in fly ash of CFB boilers is a litter high especially when low-grade coal, such as lean coal, anthracite coal, gangue, etc. is in service, which greatly influences the efficiency of boilers and fly ash further disposal. Reburn of fly ash through collection, recirculation in CFB furnace or external combustor is a possibly effective strategy to decrease the carbon content, mainly depending on the residual carbon reactivity. In this work, the combustion properties of residual carbon in fly ash and corresponding original coal from large commercial CFB boilers (Kaifeng (440t/h), and Fenyi (410t/h), all in china) are comparably investigated through experiments. The residual carbon involved was firstly extracted and enriched from fly ash by means of floating elutriation to mitigate the influence of ash and minerals on the combustion behavior of residual carbon. Then, the combustion characteristic of two residual carbons and the original coal particles was analyzed with thermogravimetric analyzer (TGA, STA409C from Nestch, Germany). It was observed that the ignition temperature of the residual carbon is much higher than that of original coal sample, and the combustion reactivity of residual carbon is not only dependent on the original coal property, but also the operating conditions. The influence of oxygen content and heating rate was also studied in TGA. The O2 concentration is set as 20%, 30%, 40% and 70% respectively in O2/N2 gas mixture with the flow rate of 100ml/min. It was found that higher oxygen content is favor for decreasing ignition temperature, accelerating the combustion rate of residual carbon. And about 40% of oxygen concentration is experimentally suggested as an optimal value when oxygen-enriched combustion is put into practice for decreasing residual carbon content of fly ash in CFB boilers.

  12. The Effects of Variable Welding and Devitrification on the Magnetic Fabric of Ash Flow Tuffs: An AMS and AARM Study of the Oligocene Carpenter Ridge Tuff, San Juan Mountains, Colorado (United States)

    Mason, S. N.; Geissman, J. W.


    Anisotropy of magnetic susceptibility (AMS) data have been shown to be a powerful means of estimating the transport direction, and thus inferred source region, for several large volume, regionally extensive ash-flow tuffs (ignimbrites). Anisotropy of anhysteretic remanent magnetization (AARM) data have, on the other hand, corroborated inferred controls by different assemblages of magnetic particles on magnetic fabrics. For ash-flow tuffs, the effects of variable degrees of welding and subsequent devitrification on the magnetic fabric of these pyroclastic deposits are not well understood. We have collected magnetic fabric data from a continuously exposed sequence of outflow facies of the ca. 27.55 Ma Carpenter Ridge Tuff (CRT), one of the major large volume ash-flow tuffs of the Southern Rocky Mountain Volcanic Field, southwest Colorado, about 3 km east of Buffalo Pass on Colorado Highway 114. The CRT, a compound cooling unit, is of reverse polarity (although there is considerable internal variability in direction through the section) and was sourced from the Bachelor Caldera, southwest of the sample locality. Some 21 total independently oriented samples, as very large oriented blocks, were collected in traverse fashion through most of the lowermost cooling unit of the tuff, and an additional ten block samples were collected from the moderately welded and completely devitrified third cooling unit. At least ten and often 20 to 30 discrete specimens were prepared for analyses from each block. Orientation of AMS principal axes are internally consistent at the oriented sample level and, overall, throughout the section sampled, and imply a west to east transport orientation in this area, consistent with several other sampling sites in the CRT in the northeast part of the Southern Rocky Mountain Volcanic Field. AARM data at the block sample level are usually more dispersed. All of the samples have positive T values, implying strong foliations. The degree of anisotropy (P

  13. The effects of water flow and temperature on thermal regime around a culvert built on permafrost

    Institute of Scientific and Technical Information of China (English)

    Loriane Prier; Guy Dor; CR Burn


    Temperature and water flow through a culvert beneath the Alaska Highway near Beaver Creek, Yukon, were measured at hourly intervals between June and October 2013. These data were used to simulate the effect of the culvert on the thermal regime of the road embankment and subjacent permafrost. A 2-D thermal model of the embankment and permafrost was developed with TEMP/W and calibrated using field observations. Empirical relations were obtained between water tem-peratures at the entrance to the culvert, flow into the culvert, and water temperatures inside the structure. Water temper-atures at the entrance and inside the culvert had a linear relation, while water temperatures inside the culvert and water flow were associated by a logarithmic relation. A multiple linear regression was used to summarize these relations. From this relationship, changes in the flow rate and water temperatures at the entrance of the culvert were simulated to obtain pre-dicted water temperatures in the culvert. The temperatures in the culvert were used in the thermal model to determine their effects on the ground thermal regime near the culvert. Variation of ±10%in water flow rate had no impact on the thermal regime underneath the culvert. Variation of water temperature at the entrance of the culvert had a noticeable influence on the thermal regime. A final simulation was conducted without insulation beneath the culvert. The thaw depth was 30 cm with insulation, and 120 cm without insulation, illustrating the importance of insulation to the ground thermal regime.

  14. Modelling near subsurface temperature with mixed type boundary condition for transient air temperature and vertical groundwater flow

    Indian Academy of Sciences (India)

    Rajeev Ranjan Kumar; D V Ramana; R N Singh


    Near-subsurface temperatures have signatures of climate change. Thermal models of subsurface have been constructed by prescribing time dependent Dirichlet type boundary condition wherein the temperature at the soil surface is prescribed and depth distribution of temperature is obtained. In this formulation it is not possible to include the relationship between air temperatures and the temperature of soil surface. However, if one uses a Robin type boundary condition, a transfer coefficient relates the air and soil surface temperatures which helps to determine both the temperature at the surface and at depth given near surface air temperatures. This coefficient is a function of meteorological conditions and is readily available. We have developed such a thermal model of near subsurface region which includes both heat conduction and advection due to groundwater flows and have presented numerical results for changes in the temperature–depth profiles for different values of transfer coefficient and groundwater flux. There are significant changes in temperature and depth profiles due to changes in the transfer coefficient and groundwater flux. The analytical model will find applications in the interpretation of the borehole geothermal data to extract both climate and groundwater flow signals.

  15. Experimental study of temperature fluctuations in forced stably stratified turbulent flows

    CERN Document Server

    Eidelman, A; Gluzman, Y; Kleeorin, N; Rogachevskii, I


    We study experimentally temperature fluctuations in stably stratified forced turbulence in air flow. In the experiments with an imposed vertical temperature gradient, the turbulence is produced by two oscillating grids located nearby the side walls of the chamber. Particle Image Velocimetry is used to determine the turbulent and mean velocity fields, and a specially designed temperature probe with sensitive thermocouples is employed to measure the temperature field. We found that the ratio [(\\ell_x \

  16. Constant-temperature hot-wire anemometer practice in supersonic flows. I - The normal wire (United States)

    Smits, A. J.; Hayakawa, K.; Muck, K. C.


    The performance of a constant-temperature normal hot-wire in a supersonic flow is critically examined. It is shown that this instrument is inherently unsuitable for measuring turbulent temperature correlations because of the highly nonlinear response to temperature fluctuations, particularly at low overheat ratios. The instrument is therefore limited to measurements of mean and fluctuating mass-flow rates. Suitable calibration procedures, as well as the limits on spatial and temporal resolution are discussed, and corrections for mean stagnation temperature changes are suggested.

  17. Plasma Flow and Temperature in a Gliding Reactor with Different Electrode Configurations

    Directory of Open Access Journals (Sweden)

    J. Sláma


    Full Text Available This paper deals with the plasma flow shape depending on the electrode form of a gliding discharge plasma-chemical reactor, and with the temperature distribution along the direction of the plasma flow in one specific electrode form. The shape of the electrodes and their mutual position has a significant influence on the design of a gliding discharge reactor and its applications. It is crucial to know the temperature distribution in the reactor’s chamber design and discharge application. Three configurations with model shapes of wire electrodes were therefore tested (low-divergent, circular, high-divergent and the plasma flow was described. The experiments were performed in air at atmospheric pressure and at room temperature. In order to map the reactive plasma region of the flow we investigated the visible spectral lines that were emitted. The gas temperature was measured using an infrared camera.

  18. Near Continuum Velocity and Temperature Coupled Compressible Boundary Layer Flow over a Flat Plate (United States)

    He, Xin; Cai, Chunpei


    The problem of a compressible gas flows over a flat plate with the velocity-slip and temperature-jump boundary conditions are being studied. The standard single- shooting method is applied to obtain the exact solutions for velocity and temperature profiles when the momentum and energy equations are weakly coupled. A double-shooting method is applied if these two equations are closely coupled. If the temperature affects the velocity directly, more significant velocity slip happens at locations closer to the plate's leading edge, and inflections on the velocity profiles appear, indicating flows may become unstable. As a consequence, the temperature-jump and velocity-slip boundary conditions may trigger earlier flow transitions from a laminar to a turbulent flow state.

  19. 2.8-Ma ash-flow caldera at Chegem River in the northern Caucasus Mountains (Russia), contemporaneous granites, and associated ore deposits (United States)

    Lipman, P.W.; Bogatikov, O.A.; Tsvetkov, A.A.; Gazis, C.; Gurbanov, A.G.; Hon, K.; Koronovsky, N.V.; Kovalenko, V.I.; Marchev, P.


    Diverse latest Pliocene volcanic and plutonic rocks in the north-central Caucasus Mountains of southern Russia are newly interpreted as components of a large caldera system that erupted a compositionally zoned rhyolite-dacite ash-flow sheet at 2.83 ?? 0.02 Ma (sanidine and biotite 40Ar/39Ar). Despite its location within a cratonic collision zone, the Chegem system is structurally and petrologically similar to typical calderas of continental-margin volcanic arcs. Erosional remnants of the outflow Chegem Tuff sheet extend at least 50 km north from the source caldera in the upper Chegem River. These outflow remnants were previously interpreted by others as erupted from several local vents, but petrologic similarities indicate a common origin and correlation with thick intracaldera Chegem Tuff. The 11 ?? 15 km caldera and associated intrusions are superbly exposed over a vertical range of 2,300 m in deep canyons above treeline (elev. to 3,800 m). Densely welded intracaldera Chegem Tuff, previously described by others as a rhyolite lava plateau, forms a single cooling unit, is > 2 km thick, and contains large slide blocks from the caldera walls. Caldera subsidence was accommodated along several concentric ring fractures. No prevolcanic floor is exposed within the central core of the caldera. The caldera-filling tuff is overlain by andesitic lavas and cut by a 2.84 ?? 0.03-Ma porphyritic granodiorite intrusion that has a cooling age analytically indistinguishable from that of the tuffs. The Eldjurta Granite, a pluton exposed low in the next large canyon (Baksan River) 10 km to the northwest of the caldera, yields variable K-feldspar and biotite ages (2.8 to 1.0 Ma) through a 5-km vertical range in surface and drill-hole samples. These variable dates appear to record a prolonged complex cooling history within upper parts of another caldera-related pluton. Major W-Mo ore deposits at the Tirniauz mine are hosted in skarns and hornfels along the roof of the Eldjurta Granite

  20. Mixed Convection Opposing Flow in a Vertical Porous Annulus-Two Temperature Model (United States)

    Al-Rashed, Abdullah A. AA; J, Salman Ahmed N.; Khaleed, H. M. T.; Yunus Khan, T. M.; NazimAhamed, K. S.


    The opposing flow in a porous medium refers to a condition when the forcing velocity flows in opposite direction to thermal buoyancy obstructing the buoyant force. The present research refers to the effect of opposing flow in a vertical porous annulus embedded with fluid saturated porous medium. The thermal non-equilibrium approach with Darcy modal is considered. The boundary conditions are such that the inner radius is heated with constant temperature Tw the outer radius is maintained at constant temperature Tc. The coupled nonlinear partial differential equations such as momentum equation, energy equation for fluid and energy equation for solid are solved using the finite element method. The opposing flow variation of average Nusselt number with respect to radius ratio Rr, Aspect ratioAr and Radiation parameter Rd for different values of Peclet number Pe are investigated. It is found that the flow behavior is quite different from that of aiding flow.

  1. Distributed measurement of flow rate in conduits using heated fiber optic distributed temperature sensing (United States)

    Sánchez, Raúl; Zubelzu, Sergio; Rodríguez-Sinobas, Leonor; Juana, Luis


    In some cases flow varies along conduits, such as in irrigated land drainage pipes and channels, irrigation laterals and others. Detailed knowledge of flow rate along the conduit makes possible analytical evaluation of water distribution and collection systems performance. Flow rate can change continuously in some systems, like in drainage pipes and channels, or abruptly, like in conduits bifurcations or emitter insertions. A heat pulse along the conduit makes possible to get flow rate from continuity and heat balance equations. Due to the great value of specific heat of water, temperature changes along conduit are smaller than the noise that involves the measurement process. This work presents a methodology that, dealing with the noise of distributed temperature measurements, leads to flow rate determination along pressurized pipes or open channel flows.

  2. Dual role of cerebral blood flow in regional brain temperature control in the healthy newborn infant. (United States)

    Iwata, Sachiko; Tachtsidis, Ilias; Takashima, Sachio; Matsuishi, Toyojiro; Robertson, Nicola J; Iwata, Osuke


    Small shifts in brain temperature after hypoxia-ischaemia affect cell viability. The main determinants of brain temperature are cerebral metabolism, which contributes to local heat production, and brain perfusion, which removes heat. However, few studies have addressed the effect of cerebral metabolism and perfusion on regional brain temperature in human neonates because of the lack of non-invasive cot-side monitors. This study aimed (i) to determine non-invasive monitoring tools of cerebral metabolism and perfusion by combining near-infrared spectroscopy and echocardiography, and (ii) to investigate the dependence of brain temperature on cerebral metabolism and perfusion in unsedated newborn infants. Thirty-two healthy newborn infants were recruited. They were studied with cerebral near-infrared spectroscopy, echocardiography, and a zero-heat flux tissue thermometer. A surrogate of cerebral blood flow (CBF) was measured using superior vena cava flow adjusted for cerebral volume (rSVC flow). The tissue oxygenation index, fractional oxygen extraction (FOE), and the cerebral metabolic rate of oxygen relative to rSVC flow (CMRO₂ index) were also estimated. A greater rSVC flow was positively associated with higher brain temperatures, particularly for superficial structures. The CMRO₂ index and rSVC flow were positively coupled. However, brain temperature was independent of FOE and the CMRO₂ index. A cooler ambient temperature was associated with a greater temperature gradient between the scalp surface and the body core. Cerebral oxygen metabolism and perfusion were monitored in newborn infants without using tracers. In these healthy newborn infants, cerebral perfusion and ambient temperature were significant independent variables of brain temperature. CBF has primarily been associated with heat removal from the brain. However, our results suggest that CBF is likely to deliver heat specifically to the superficial brain. Further studies are required to assess the

  3. Two Models of DMFC under Effects of Cathode Humidification Temperature and Anode Flow Rate

    Institute of Scientific and Technical Information of China (English)


    This paper introduced a novel self-adjustment of parameters of fuzzy neural networks. Then,the effects of cathode humidification temperature and anode flow rate on the performance of direct methanol fuel cell (DMFC)were described respectively. Two dynamic performance models of DMFC under the influences of cathode humidification temperature and anode flow rate were established separately based on fuzzy neural networks. The simulation results show the accuracy of the models established is satisfactory.

  4. Instrument for thermal radiation flux measurement in high temperature gas flow (Cuernavaca instrument)

    Energy Technology Data Exchange (ETDEWEB)

    Afgan, N.H. [Universidade Tecnica, Lisbon (Portugal); Leontiev, A.I. [Moscow State Technical University (Russian Federation)


    A new instrument for hemispherical radiation heat flux measurement is proposed. It is based on the theory of blow of the boundary layer, taking into account that at the critical mass flow rate through the porous surface the thermal boundary layer is blown off and only radiation flux from high temperature gases reaches the porous surface. With the measurement of blow of gas flow and the temperature of the porous material, the respective heat flux is obtained. (author)

  5. Numerical Simulation of Coupled Molten Steel Flow and Temperature Fields in Compact Strip Production Casting

    Institute of Scientific and Technical Information of China (English)

    LIU Xu-feng; ZHANG Jie-yu; DU Wei-dong; ZHAI Qi-jie; LI Qiang


    Based on the casting manufacture practice of steel slabs by CSP technology, the flow and the temperature fields of the funnel mould and the secondary cooling segment were simulated using the commercial code,CFX4. Compared with other physical investigations, the correlative data of the present simulation results are in good agreement with them. Therefore, a more comprehensive survey for metallurgy characteristic of the flow and the temperature fields in CSP continuous casting process can be achieved.

  6. Measurement of temperature decrease caused by blood flow in focused ultrasound irradiation by thermal imaging method (United States)

    Tsuchiya, Takenobu; Hatano, Yuichi; Mori, Yashunori; Shen, Rakushin; Endoh, Nobuyuki


    In this study, to estimate the local temperature changes caused by a thick blood vessel, the temperature distribution in a tissue phantom with a thick blood vessel during focused ultrasound irradiation was measured by a thermal imaging method. The blood flow rate in the simulated blood vessel was varied and the relationship between flow rate and temperature decrease was examined. The phantom using the thermal imaging method is divided into two parts, and the increases in temperature distribution as a function of blood flow rate are measured using a thermocamera under constant ultrasound irradiation. The irradiation conditions of ultrasound waves were a central frequency of 1 MHz, a wave number length of 200 cycles, and a duty ratio of 0.2. The irradiation duration was 5 min, and the ultrasound intensity I SPTA was 36 W/cm2. The amount of temperature decrease caused by the cooling effect of blood flow increased with the blood flow rate and it became constant at a certain threshold of blood flow rate. The threshold of blood flow rate is about 250 ml/min.

  7. Numerical Simulation for Effect of Inlet Cooling Rate on Fluid Flow and Temperature Distribution in Tundish

    Institute of Scientific and Technical Information of China (English)

    QU Tian-peng; LIU Cheng-jun; JIANG Mao-fa


    The fluid flow in tundish is a non-isothermal process and the temperature variation of stream from teeming ladle dominates the fluid flow and thermal distribution in tundish. A numerical model was established to investigate the effect of inlet cooling rate on fluid flow and temperature distribution in tundish based on a FTSC (Flexible Thin Slab Casting) tundish. The inlet cooling rate varies from 0. 5 to 0. 25 ~C/rain. Under the present calculation conditions, the following conclusions were made. When the stream temperature from teeming ladle drops seriously (for inlet cooling rate of 0.5℃/min), there is a "backward flow" at the coming end of casting. The horizontal flow along the free surface turns to flow along the bottom of tundish. The bottom flow shortens the fluid flow route in tundish and deteriorates the removal effect of nonmetallic inclusions from molten steel. Nevertheless, when the inlet cooling rate decreases to 0.25℃/min, the horizontal flow is sustained during the whole casting period. The present research provides theoretical directions for temperature control in teeming ladle and continuous casting tundish during production of advanced steels.

  8. Development of a FBG vortex flow sensor for high-temperature applications

    NARCIS (Netherlands)

    Cheng, L.K.; Schiferli, W.; Nieuwland, R.A.; Franzen, A.; Boer, J.J. den; Jansen, T.H.


    A robust fibre optic flow sensor has been developed to measure liquid or gas flows at ambient temperatures up to 300°C and pressures up to 100 bar. While such environmental conditions are typical in pressurized steam systems in the oil and gas industry (downhole and surface), wider applications are

  9. Influence of magnetic field on the turbulence of plane high temperature gas flow

    Energy Technology Data Exchange (ETDEWEB)

    Levitan, Yu.S.


    Expressions are obtained within the framework of the Prandtl hypothesis and proposition on local-isotropic turbulence for turbulent friction and thermal flow in a channel flow of an electrical-conducting medium with a current along the channel's axis in the internal magnetic field, and which account for temperature fluctuations of the medium. 6 references.

  10. Bypass valve and coolant flow controls for optimum temperatures in waste heat recovery systems (United States)

    Meisner, Gregory P


    Implementing an optimized waste heat recovery system includes calculating a temperature and a rate of change in temperature of a heat exchanger of a waste heat recovery system, and predicting a temperature and a rate of change in temperature of a material flowing through a channel of the waste heat recovery system. Upon determining the rate of change in the temperature of the material is predicted to be higher than the rate of change in the temperature of the heat exchanger, the optimized waste heat recovery system calculates a valve position and timing for the channel that is configurable for achieving a rate of material flow that is determined to produce and maintain a defined threshold temperature of the heat exchanger, and actuates the valve according to the calculated valve position and calculated timing.

  11. The behavior of ash species in suspension fired biomass boilers

    DEFF Research Database (Denmark)

    Jensen, Peter Arendt

    technology a long range of research studies have been conducted, to improve our understanding of the influence and behavior of biomass ash species in suspension fired boilers. The fuel ash plays a key role with respect tooptimal boiler operation and influences phenomena’s as boiler chamber deposit formation......, corrosion of steam coils, deactivation of SCR catalysts and utilization of residual products. Abroad range of research tools as probe measurements on power plants, entrain flow reactorstudies and deposit modelling have been used to gain an improved understanding of ash transformation and ash deposit...... to generate ash particles typically in the size range of 50 to 200 μm on biomass suspension fired power plant boilers. A fragmentation rate of fuel particles of 3 have been used to describe both the residual ash formation process in laboratory entrained flow reactors and in full scale boilers.A range...

  12. The inhomogeneous ion temperature anisotropy instabilities of magnetic-field-aligned plasma sheared flow (United States)

    Mikhailenko, V. V.; Mikhailenko, V. S.; Lee, Hae June


    The stability of the magnetic field aligned sheared flow with anisotropic ion temperatures, which have the anisotropic spatial inhomogeneities across the magnetic field and are comparable with or are above the electron temperature, is investigated numerically and analytically. The ion temperatures gradients across the magnetic field affect the instability development only when the inhomogeneous is the ion temperature along the magnetic field irrespective the inhomogeneity of the ion temperature across the magnetic field. In this case, the instability is developed due to the combined effect of the ion Landau damping, velocity shear, ion temperature anisotropy, and anisotropy of the ion temperature gradients. In the case when the ion temperature along the magnetic field is homogeneous, but the ion temperature across the magnetic field is inhomogeneous, the short wavelength instability develops with the wave length less than the thermal ion Larmor radius. This instability excites due to the coupled effect of the ion Landau damping, velocity shear and ion temperature anisotropy.

  13. Electron Temperature and Plasma Flow Measurements of NIF Hohlraum Plasmas (United States)

    Barrios, M. A.; Liedahl, D. A.; Schneider, M. B.; Jones, O.; Brow, G. V.; Regan, S. P.; Fournier, K. B.; Moore, A. S.; Ross, J. S.; Eder, D.; Landen, O.; Kauffman, R. L.; Nikroo, A.; Kroll, J.; Jaquez, J.; Huang, H.; Hansen, S. B.; Callahan, D. A.; Hinkel, D. E.; Bradley, D.; Moody, J. D.; LLNL Collaboration; LLE Collaboration; GA Collaboration; SNL Collaboration


    Characterizing the plasma conditions inside NIF hohlraums, in particular mapping the plasma Te, is critical to gaining insight into mechanisms that affect energy coupling and transport in the hohlraum. The dot spectroscopy platform provides a temporal history of the localized Te and plasma flow inside a NIF hohlraum, by introducing a Mn-Co tracer dot, at strategic locations inside the hohlraum, that comes to equilibrium with the local plasma. K-shell X-ray spectroscopy of the tracer dot is recorded onto an absolutely calibrated X-ray streak spectrometer. Isoelectronic and interstage line ratios are used to infer localized Te through comparison with atomic physics calculations using SCRAM. Time resolved X-ray images are simultaneously taken of the expanding dot, providing plasma (ion) flow information. We present recent results provided by this platform and compare with simulations using HYDRA. This work was performed under the auspices of the U.S. Department of Energy by LLNL under Contract DE-AC52-07NA27344.

  14. Temperature logging as an aid to understanding groundwater flow in boreholes

    Energy Technology Data Exchange (ETDEWEB)

    Conaway, J.G.


    Borehole temperatures are affected by a range of physical phenomena, including drilling and engineering procedures, thermal resistivity of the rock, surface climatic changes, local heat sources and sinks, free convection of the borehole fluid, and water flows inside the borehole. As a result, temperature logs provide unique information not available from other logs. On the other hand, because the temperature log is sensitive to a variety of phenomena, one or more of these may obscure the effect being studied. In the case where groundwater is entering the borehole at one depth and exiting at another depth (or at the surface) the temperature disturbance resulting from this flow is likely to be a prominent feature of the temperature profile of the borehole. Because of this, water flows in boreholes are often a source of noise in temperature logs, obscuring the features of interest. Recently, however, unusual groundwater behavior was noted in several boreholes at the Nevada Test Site (NTS), and temperature logs were run as part of a program to study this phenomenon. In this case the groundwater flow has been the feature of interest in the logs, and the logs have been useful as an aid in understanding the water flow in those boreholes.

  15. Coupled model of deformation and gas flow process with temperature and slippage effect

    Directory of Open Access Journals (Sweden)

    Chunhui ZHANG


    Full Text Available The effects of temperature, slippage effect and effective stress of coal on the coupled mechanism of deformation and gas glow are key issues to control coal and gas outburst and design the methane recovery engineering. Firstly, intact coal from Huaxing mine in Jilin Province is crushed and coal briquette specimen are made. Then the tri-axial coupled test setup of the deformation, gas flow and temperature developed by ourselves is adopted to investigate the effects of pore pressure, effective stress and temperature on the permeability of coal briquette specimen. The results show that: 1 Under the condition of low pore pressure, the permeability first reduces with pore pressure increasing, then at a threshold of pore pressure it rises with pore pressure increasing, which is called “slippage effect”. 2 The effective confining stress significantly influences the permeability. With increasing effective confining stress, the space of pores and cracks are compressed and the permeability reduces. 3 The temperature significantly influences the permeability and the permeability decreases with temperature increasing. The main reason is that the space of pores and cracks is compressed due to the temperature stress. Because of the constraint around, temperature compressive stress appears in internal coal samples. Coal pore and fracture space is compressed, and the sample permeability decreases. Besides, the viscosity of gas increases with temperature increasing. It decreases the trend of coal permeability . The temperature influence on coal permeability approximates to linear relationship. 4 The empirical permeability evolution equation with varying temperature, effective stress and slippage effects is presented. The coal is viewed as elastic medium, combined with effective stress principle and the empirical permeability equation, the coupled model of deformation and gas flow with varying temperature and slippage effects is built. Furthermore, the code

  16. Application of mathematical model for high-temperature resistance of fly ash geopolymers%地聚物固化体抗高温性能及数学模型研究

    Institute of Scientific and Technical Information of China (English)

    金漫彤; 黄彩菊; 邵江平; 许杭俊; 王连军


    地聚物对焚烧飞灰中的重金属具有良好的固定作用.为了进一步探索固化飞灰后的地聚物固化体的抗环境侵蚀性能,开展了固化体高温-恒温时间-地聚物抗压强度的研究及经受高温后固化体的重金属浸出试验,探讨抗压强度与高温、恒温时间之间的关系以及地聚物固化垃圾焚烧飞灰的稳定性.通过对固化体试块的高温试验以及对不同温度、不同恒温时间下固化体抗压强度试验,分析这三者之间的关系,建立数学模型,并根据实验结果拟合温度-恒温时间-抗压强度的三维曲面.%Geopolymers can effectively immobilize the heavy metals in the municipal solid waste incineration fly ash.In order to further explore the environment corrosion resistance of fly ash geopolymer, high temperature test of geopolymer is presented, referring to the relationship between high-temperature, constant temperature and compressive strength.Through the compressive strength test of geopolymer test cubes at different temperature and different constant temperature time, the coupling relationship among temperature, constant temperature time and compressive strength of geopolymer is analyzed, and the mathematical models of these is established.Additionally the leaching concentractions of heavy metals in the fly ash-geopolymers after heating are determined to examine the stability.Based on the results of test, the 3D curved surface of temperature,constant temperature time and compressive strength of geopolymer is fitted.

  17. Mixed convection aiding flow in a vertical porous annulus-two temperature model (United States)

    Salman Ahmed, N. J.; AAAl-Rashed, Abdullah A.; Kamangar, Sarfaraz; Khaleed, H. M. T.; YunusKhan, T. M.; Athani, Abdulgaphur


    The effect of convective heat transfer on mixed convection flow in a vertical porous annulus embedded with fluid saturated porous medium for aiding flow is studied. The inner surface of the annular cylinder is heated with constant temperature whereas the outer surface remains at ambient temperature. The governing partial differential equations are solved using Finite Element Method (FEM). It is assumed that the Darcy law is applicable and thermal nonequilibrium TNE exists between solid and fluid phases of porous medium. The aiding flow behavior of heat transfer with respect to Radius ratioRr, Aspect ratio ArandRadiation parameter Rd for different values of Peclet number Peare investigated.

  18. Effects of non-uniform core flow on peak cladding temperature: MOXY/SCORE sensitivity calculations

    Energy Technology Data Exchange (ETDEWEB)

    Chang, S.C.


    The MOXY/SCORE computer program is used to evaluate the potential effect on peak cladding temperature of selective cooling that may result from a nonuniform mass flux at the core boundaries during the blowdown phase of the LOFT L2-4 test. The results of this study indicate that the effect of the flow nonuniformity at the core boundaries will be neutralized by a strong radial flow redistribution in the neighborhood of core boundaries. The implication is that the flow nonuniformity at the core boundaries has no significant effect on the thermal-hydraulic behavior and cladding temperature at the hot plane.

  19. Multiple temperature model for the information preservation method and its application to nonequilibrium gas flows (United States)

    Zhang, Jun; Fan, Jing; Jiang, Jianzheng


    The information preservation (IP) method has been successfully applied to various nonequilibrium gas flows. Comparing with the direct simulation Monte Carlo (DSMC) method, the IP method dramatically reduces the statistical scatter by preserving collective information of simulation molecules. In this paper, a multiple temperature model is proposed to extend the IP method to strongly translational nonequilibrium gas flows. The governing equations for the IP quantities have been derived from the Boltzmann equation based on an assumption that each simulation molecule represents a Gaussian distribution function with a second-order temperature tensor. According to the governing equations, the implementation of IP method is divided into three steps: molecular movement, molecular collision, and update step. With a reasonable multiple temperature collision model and the flux splitting method in the update step, the transport of IP quantities can be accurately modeled. We apply the IP method with the multiple temperature model to shear-driven Couette flow, external force-driven Poiseuille flow and thermal creep flow, respectively. In the former two cases, the separation of different temperature components is clearly observed in the transition regime, and the velocity, temperature and pressure distributions are also well captured. The thermal creep flow, resulting from the presence of temperature gradients along boundary walls, is properly simulated. All of the IP results compare well with the corresponding DSMC results, whereas the IP method uses much smaller sampling sizes than the DSMC method. This paper shows that the IP method with the multiple temperature model is an accurate and efficient tool to simulate strongly translational nonequilibrium gas flows.

  20. Pulsed Electron Beam Spectroscopy for Temperature Measurements in Hypersonic Flows (United States)


    as rotational-level dependent, so the proper modeling of k i can be important as temperature changes and if tem perature measurements based on the...through a hy drogen thyratron switch into the primary of a step-up transformer. A limited number of off-th e-shelf prod ucts perfor ming the function...of a thyratron drive for pulse switching were identifie d, but none met the specialize d power a nd switchin g wavefor m requirements of the pulsed

  1. Fly ash carbon passivation (United States)

    La Count, Robert B; Baltrus, John P; Kern, Douglas G


    A thermal method to passivate the carbon and/or other components in fly ash significantly decreases adsorption. The passivated carbon remains in the fly ash. Heating the fly ash to about 500 and 800 degrees C. under inert gas conditions sharply decreases the amount of surfactant adsorbed by the fly ash recovered after thermal treatment despite the fact that the carbon content remains in the fly ash. Using oxygen and inert gas mixtures, the present invention shows that a thermal treatment to about 500 degrees C. also sharply decreases the surfactant adsorption of the recovered fly ash even though most of the carbon remains intact. Also, thermal treatment to about 800 degrees C. under these same oxidative conditions shows a sharp decrease in surfactant adsorption of the recovered fly ash due to the fact that the carbon has been removed. This experiment simulates the various "carbon burnout" methods and is not a claim in this method. The present invention provides a thermal method of deactivating high carbon fly ash toward adsorption of AEAs while retaining the fly ash carbon. The fly ash can be used, for example, as a partial Portland cement replacement in air-entrained concrete, in conductive and other concretes, and for other applications.

  2. Effect of fuel properties on the bottom ash generation rate by a laboratory fluidized bed combustor

    Energy Technology Data Exchange (ETDEWEB)

    Rozelle, P.L.; Pisupati, S.V.; Scaroni, A.W. [Penn State University, University Park, PA (United States). Dept. of Energy & Geoenvironmental Engineering


    The range of fuels that can be accommodated by an FBC boiler system is affected by the ability of the fuel, sorbent, and ash-handling equipment to move the required solids through the boiler. Of specific interest is the bottom ash handling equipment, which must have sufficient capacity to remove ash from the system in order to maintain a constant bed inventory level, and must have sufficient capability to cool the ash well below the bed temperature. Quantification of a fuel's bottom ash removal requirements can be useful for plant design. The effect of fuel properties on the rate of bottom ash production in a laboratory FBC test system was examined. The work used coal products ranging in ash content from 20 to 40+ wt. %. The system's classification of solids by particle size into flyash and bottom ash was characterized using a partition curve. Fuel fractions in the size range characteristic of bottom ash were further analyzed for distributions of ash content with respect to specific gravity, using float sink tests. The fuel fractions were then ashed in a fixed bed. In each case, the highest ash content fraction produced ash with the coarsest size consist (characteristic of bottom ash). The lower ash content fractions were found to produce ash in the size range characteristic of flyash, suggesting that the high ash content fractions were largely responsible for the production of bottom ash. The contributions of the specific gravity fractions to the composite ash in the fuels were quantified. The fuels were fired in the laboratory test system. Fuels with higher amounts of high specific gravity particles, in the size ranges characteristic of bottom ash, were found to produce more bottom ash, indicating the potential utility of float sink methods in the prediction of bottom ash removal requirements.

  3. Prediction of Stratified Flow Temperature Profiles in a Fully Insulated Environment

    Directory of Open Access Journals (Sweden)

    Ahmad S. Awad


    Full Text Available The aim of the study is to present an analytical model to predict the temperature profiles in thermal stratified environment. Thermal stratification is encountered in many situations. The flow of contaminants and hydrocarbons in environment often get stratified. The prediction of temperature profiles and flow characteristics are essential for HVAC applications, environment and energy management. The temperature profiles in the stratified region are successfully obtained, in terms of flow-operating functions. The analytical model agrees well with the published experimental data as well as the related closed-form solutions, which is helpful for HVAC applications. The model will be further developed and incorporated within a numerical model in order to investigate the flow field characteristics and establish correlations for a wide range of parameters.

  4. Two-phase Flow Patterns in High Temperature Generator of Absorption Chiller / Heater (United States)

    Furukawa, Masahiro; Kanuma, Hitoshi; Sekoguchi, Kotohiko; Takeishi, Masayuki

    There is a lack of information about vapor-liquid two-phase flow patterns determined using void signals in high temperature generator of absorption chiller/heater. Sensing void fraction has been hampered because lithium bromide aqueous solution of strong alkalinity is employed as working fluid at high temperature and high level of vacuum. New void sensor applicable to such difficult conditions was developed. The void Fractions at 48 locations in a high temperature generator were measured simultaneously in both cooling and heating operations. Analysis of void signals detected reveals that the most violent boiling occurs at the upper part of rear plate of combustion chamber and the first line of vertical tubes located in the flue. The flow patterns are strongly affected by the system pressure difference between the cooling and heating operations: there appear bubbly, slug and froth flows in the cooling operation, but only bubbly flow in the heating operation.

  5. Method for increasing -SiC yield on solid state reaction of coal fly ash and activated carbon powder

    Indian Academy of Sciences (India)

    Sulardjaka; Jamasri; M W Wildan; Kusnanto


    A novel process for increasing -SiC yield on solid state reaction of coal fly ash and micro powder activated carbon powder has been proposed. -SiC powder was synthesized at temperature 1300°C for 2 h under vacuum condition with 1 l/min argon flow. Cycling synthesis process has been developed for increasing -SiC yield on solid state reaction of coal fly ash and activated carbon powder. Synthesized products were analyzed by XRD with Cu-K radiation, FTIR spectrometer and SEM fitted with EDAX. The results show that the amount of relative -SiC is increased with the number of cycling synthesis.

  6. Spectroscopic measurements of impurity temperatures and parallel ion flows in the DIII-D divertor (United States)

    Isler, R. C.; Brooks, N. H.; West, W. P.; Leonard, A. W.; McKee, G. R.; Porter, G. D.

    Impurity ion temperatures and parallel flow velocities in the DIII-D divertor have been measured from the shapes and shifts of visible spectral lines of C II, C III, and B II. Spectral multiplet patterns are analyzed by fitting them to theoretical profiles that incorporate exact calculations for the Zeeman/Paschen-Back effect. Both normal flows toward the target plate and reversed flows away from the target plate are observed in the outer divertor leg; only flows toward the plate are detected in the inner leg.

  7. High temperature flow behaviour of SiC reinforced lithium aluminosilicate composites

    Indian Academy of Sciences (India)

    Santanu Das; V S R Murthy; G S Murty


    The compressive flow behaviour of lithium aluminosilicate (LAS) glass, with and without SiC particulate reinforcements, was studied. The LAS glass crystallized to spodumene during high-temperature testing. The flow behaviour of LAS glass changed from Newtonian to non-Newtonian due to the presence of crystalline phase. Further, with the addition of 40 vol.% SiC additions, the strain rate sensitivity of flow stress decreased. While the activation energy for flow in LAS was 300 kJ/mole, it increased to 995 kJ/mole with the addition of 40 vol.% SiC reinforcements.

  8. The electromagnetic force field, fluid flow field and temperature profiles in levitated metal droplets (United States)

    El-Kaddah, N.; Szekely, J.


    A mathematical representation was developed for the electromagnetic force field, the flow field, the temperature field (and for transport controlled kinetics), in a levitation melted metal droplet. The technique of mutual inductances was employed for the calculation of the electromagnetic force field, while the turbulent Navier - Stokes equations and the turbulent convective transport equations were used to represent the fluid flow field, the temperature field and the concentration field. The governing differential equations, written in spherical coordinates, were solved numerically. The computed results were in good agreement with measurements, regarding the lifting force, and the average temperature of the specimen and carburization rates, which were transport controlled.

  9. Study on the structural change and heat transfer characteristics of ash deposit layers in the coal gasifier

    Energy Technology Data Exchange (ETDEWEB)

    Kazuyoshi Ichikawa; Yuso Oki; Jun Inumaru [Central Research Institute of Electric Power Industry (CREIPI) (Japan)


    Ash deposition is often observed in the coal gasifier. As it may interfere the operation of gasifier, in case of excessive deposition, a study is needed to evaluate the ash deposition characteristics on the gasifier wall, its ability to grow after deposition, and influence of the formation of deposition layers on the heat transfer capability in advance. CRIEPI has conducted a study of the basic gasification process and operational technology using a 2T/D air-blown pressurized entrained-flow coal gasifier (2 T/D gasifier) since 1983. In a previous work, the authors calculated the ash liquid phase ratio as an index of the ash melting characteristics in correspondence to continuous temperature change, and established the relationship with the ash deposition characteristics. We also proposed as the technique to predict ash deposition characteristics in the gasifier by construction of a model based upon the correlation and introduction into the numerical analysis code. In this report, the relationship between the sintering structure and the heat transfer characteristics of deposition layer is studied. The heat transfer mechanism in the layer was also pursued. 7 refs., 6 figs., 1 tab.

  10. Determination of the temperature-dependent cell membrane permeabilities using microfluidics with integrated flow and temperature control. (United States)

    Fang, Cifeng; Ji, Fujun; Shu, Zhiquan; Gao, Dayong


    We developed an integrated microfluidic platform for instantaneous flow and localized temperature control. The platform consisted of a flow-focusing region for sample delivery and a cross-junction region embedded with a microheater for cell trapping and localized temperature control by using an active feedback control system. We further used it to measure the membrane transport properties of Jurkat cells, including the osmotically inactive cell volume (Vb) and cell membrane permeabilities to water (Lp) and to cryoprotective agent (CPA) solutions (dimethyl sulfoxide (DMSO) in this study) (PS) at various temperatures (room temperature, 30 °C, and 37 °C). Such characteristics of cells are of great importance in many applications, especially in optimal cryopreservation. With the results, the corresponding activation energy for water and CPA transport was calculated. The comparison of the results from the current study with reference data indicates that the developed platform is a reliable tool for temperature-dependent cell behavior study, which provides valuable tools for general cell manipulation applications with precise temperature control.

  11. A high-temperature calorimetric flow sensor employing ion conduction in zirconia (United States)

    Persson, A.; Lekholm, V.; Thornell, G.; Klintberg, L.


    This paper presents the use of the temperature-dependent ion conductivity of 8 mol % yttria-stabilized zirconia (YSZ8) in a miniature high-temperature calorimetric flow sensor. The sensor consists of 4 layers of high-temperature co-fired ceramic (HTCC) YSZ8 tape with a 400 μm wide, 100 μm deep, and 12 500 μm long internal flow channel. Across the center of the channel, four platinum conductors, each 80 μm wide with a spacing of 160 μm, were printed. The two center conductors were used as heaters, and the outer, up- and downstream conductors were used to probe the resistance through the zirconia substrate around the heaters. The thermal profile surrounding the two heaters could be made symmetrical by powering them independently, and hence, the temperature sensing elements could be balanced at zero flow. With nitrogen flowing through the channel, forced convection shifted the thermal profile downstream, and the resistance of the temperature sensing elements diverged. The sensor was characterized at nitrogen flows from 0 to 40 sccm, and resistances at zero-flow from 10 to 50 MΩ. A peak sensitivity of 3.1 MΩ/sccm was obtained. Moreover, the sensor response was found to be linear over the whole flow range, with R2 of around 0.999, and easy to tune with the individual temperature control of the heaters. The ability of the sensor to operate in high temperatures makes it promising for use in different harsh environments, e.g., for close integration with microthrusters.

  12. Laminar-Turbulent Transition: The change of the flow state temperature with the Reynolds number

    CERN Document Server

    Chekmarev, Sergei F


    Using the previously developed model to describe laminar/turbulent states of a viscous fluid flow, which treats the flow as a collection of coherent structures of various size (Chekmarev, Chaos, 2013, 013144), the statistical temperature of the flow state is determined as a function of the Reynolds number. It is shown that at small Reynolds numbers, associated with laminar states, the temperature is positive, while at large Reynolds numbers, associated with turbulent states, it is negative. At intermediate Reynolds numbers, the temperature changes from positive to negative as the size of the coherent structures increases, similar to what was predicted by Onsager for a system of parallel point-vortices in an inviscid fluid. It is also shown that in the range of intermediate Reynolds numbers the temperature exhibits a power-law divergence characteristic of second-order phase transitions.

  13. Skin blood flow and local temperature independently modify sweat rate during passive heat stress in humans. (United States)

    Wingo, Jonathan E; Low, David A; Keller, David M; Brothers, R Matthew; Shibasaki, Manabu; Crandall, Craig G


    Sweat rate (SR) is reduced in locally cooled skin, which may result from decreased temperature and/or parallel reductions in skin blood flow. The purpose of this study was to test the hypotheses that decreased skin blood flow and decreased local temperature each independently attenuate sweating. In protocols I and II, eight subjects rested supine while wearing a water-perfused suit for the control of whole body skin and internal temperatures. While 34°C water perfused the suit, four microdialysis membranes were placed in posterior forearm skin not covered by the suit to manipulate skin blood flow using vasoactive agents. Each site was instrumented for control of local temperature and measurement of local SR (capacitance hygrometry) and skin blood flow (laser-Doppler flowmetry). In protocol I, two sites received norepinephrine to reduce skin blood flow, while two sites received Ringer solution (control). All sites were maintained at 34°C. In protocol II, all sites received 28 mM sodium nitroprusside to equalize skin blood flow between sites before local cooling to 20°C (2 sites) or maintenance at 34°C (2 sites). In both protocols, individuals were then passively heated to increase core temperature ~1°C. Both decreased skin blood flow and decreased local temperature attenuated the slope of the SR to mean body temperature relationship (2.0 ± 1.2 vs. 1.0 ± 0.7 mg·cm(-2)·min(-1)·°C(-1) for the effect of decreased skin blood flow, P = 0.01; 1.2 ± 0.9 vs. 0.07 ± 0.05 mg·cm(-2)·min(-1)·°C(-1) for the effect of decreased local temperature, P = 0.02). Furthermore, local cooling delayed the onset of sweating (mean body temperature of 37.5 ± 0.4 vs. 37.6 ± 0.4°C, P = 0.03). These data demonstrate that local cooling attenuates sweating by independent effects of decreased skin blood flow and decreased local skin temperature.

  14. Hydraulic transportation of fly ash: a laboratory-scale investigation

    Energy Technology Data Exchange (ETDEWEB)

    Jain, M.K.; Sastry, B.S. [Anna University, Chennai (India). Dept. of Mining Engineering


    Flow behaviour of fly ash slurry is a very complex phenomenon. The present study tries to examine the relation between flow rate and pressure loss of fly ash slurry under laboratory-scale experiment set up in the light of available theoretical background. Pressure loss increases with the increase in flow rate and solid concentration but pressure losses can be saved by the addition of 2200 PPM (parts per million) concentration of polyacrylamide polymer. 6 refs., 7 figs., 4 tabs.

  15. 1D compressible flow with temperature dependent transport coefficients

    CERN Document Server

    Jenssen, Helge Kristian


    We establish existence of global-in-time weak solutions to the one dimensional, compressible Navier-Stokes system for a viscous and heat conducting ideal polytropic gas (pressure $p=K\\theta/\\tau$, internal energy $e=c_v \\theta$), when the viscosity $\\mu$ is constant and the heat conductivity $\\kappa$ depends on the temperature $\\theta$ according to $\\kappa(\\theta) = \\bar \\kappa \\theta^\\beta$, with $0\\leq\\beta<{3/2}$. This choice of degenerate transport coefficients is motivated by the kinetic theory of gasses. Approximate solutions are generated by a semi-discrete finite element scheme. We first formulate sufficient conditions that guarantee convergence to a weak solution. The convergence proof relies on weak compactness and convexity, and it applies to the more general constitutive relations $\\mu(\\theta) = \\bar \\mu \\theta^\\alpha$, $\\kappa(\\theta) = \\bar \\kappa \\theta^\\beta$, with $\\alpha\\geq 0$, $0 \\leq \\beta < 2$ ($\\bar \\mu, \\bar \\kappa$ constants). We then verify the sufficient conditions in the case...

  16. Rarefaction effects in dilute granular Poiseuille flow: Knudsen minimum and temperature bimodality (United States)

    Mahajan, Achal; Alam, Meheboob


    The gravity-driven flow of smooth inelastic hard-disks through a channel, analog of granular Poiseuille flow, is analysed using event-driven simulations. We find that the variation of the mass-flow rate (Q) with Knudsen number (Kn) can be non-monotonic in the elastic limit (i.e. the restitution coefficient en --> 1) in channels with very smooth walls. The Knudsen minimum effect (i.e. the minimum flow rate occurring at Kn ~ O (1) for the Poiseuille flow of a molecular gas) is found to be absent in a granular gas with en competition between dissipation and rarefaction seems to be responsible for the observed dependence of both mass-flow rate and temperature bimodality on Kn and en . [Alam etal. 2015, JFM (revised)].

  17. Similarity of the Temperature Profile formed by Fluid Flow along a Wall

    CERN Document Server

    Weyburne, David


    A new approach to the study of similarity of temperature profiles is presented. It is applicable for any 2-D fluid flow along an isothermal heated (cooled) wall. The approach is based on a simple concept; the area under a set of scaled temperature profile curves that show similar behavior must be equal. This leads to a new integral-based definition of temperature profile similarity. By taking simple area integrals of the scaled temperature profile and its first derivative, we also obtain a number of new results pertaining to similarity of the temperature profiles. For example, it is shown that if similarity exists, then: 1) the similarity temperature and length scaling parameters are interdependent, 2) the thermal displacement thickness must be a similar length scaling parameter, and 3) the temperature scaling parameter must be proportional to the free stream minus wall temperature values.

  18. Investigation on the Core Bypass Flow in a Very High Temperature Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Hassan, Yassin


    Uncertainties associated with the core bypass flow are some of the key issues that directly influence the coolant mass flow distribution and magnitude, and thus the operational core temperature profiles, in the very high-temperature reactor (VHTR). Designers will attempt to configure the core geometry so the core cooling flow rate magnitude and distribution conform to the design values. The objective of this project is to study the bypass flow both experimentally and computationally. Researchers will develop experimental data using state-of-the-art particle image velocimetry in a small test facility. The team will attempt to obtain full field temperature distribution using racks of thermocouples. The experimental data are intended to benchmark computational fluid dynamics (CFD) codes by providing detailed information. These experimental data are urgently needed for validation of the CFD codes. The following are the project tasks: • Construct a small-scale bench-top experiment to resemble the bypass flow between the graphite blocks, varying parameters to address their impact on bypass flow. Wall roughness of the graphite block walls, spacing between the blocks, and temperature of the blocks are some of the parameters to be tested. • Perform CFD to evaluate pre- and post-test calculations and turbulence models, including sensitivity studies to achieve high accuracy. • Develop the state-of-the art large eddy simulation (LES) using appropriate subgrid modeling. • Develop models to be used in systems thermal hydraulics codes to account and estimate the bypass flows. These computer programs include, among others, RELAP3D, MELCOR, GAMMA, and GAS-NET. Actual core bypass flow rate may vary considerably from the design value. Although the uncertainty of the bypass flow rate is not known, some sources have stated that the bypass flow rates in the Fort St. Vrain reactor were between 8 and 25 percent of the total reactor mass flow rate. If bypass flow rates are on the

  19. A chirped-pulse Fourier-transform microwave/pulsed uniform flow spectrometer. I. The low-temperature flow system. (United States)

    Oldham, James M; Abeysekera, Chamara; Joalland, Baptiste; Zack, Lindsay N; Prozument, Kirill; Sims, Ian R; Park, G Barratt; Field, Robert W; Suits, Arthur G


    We report the development of a new instrument that combines chirped-pulse microwave spectroscopy with a pulsed uniform supersonic flow. This combination promises a nearly universal detection method that can deliver isomer and conformer specific, quantitative detection and spectroscopic characterization of unstable reaction products and intermediates, product vibrational distributions, and molecular excited states. This first paper in a series of two presents a new pulsed-flow design, at the heart of which is a fast, high-throughput pulsed valve driven by a piezoelectric stack actuator. Uniform flows at temperatures as low as 20 K were readily achieved with only modest pumping requirements, as demonstrated by impact pressure measurements and pure rotational spectroscopy. The proposed technique will be suitable for application in diverse fields including fundamental studies in spectroscopy, kinetics, and reaction dynamics.

  20. Frontal subcutaneous blood flow, and epi- and subcutaneous temperatures during scalp cooling in normal man

    DEFF Research Database (Denmark)

    Bülow, J; Friberg, L; Gaardsting, O;


    Cooling of the scalp has been found to prevent hair loss following cytostatic treatment, but in order to obtain the hair preserving effect the subcutaneous temperature has to be reduced below 22 degrees C. In order to establish the relationship between epicutaneous and subcutaneous temperatures...... of the cooling helmet and after removal of the rewarmed helmet in 10 normal subjects. Subcutaneous blood flow was reduced to about 25% of the postcooling control level during cooling. The flow was constantly reduced until the subcutaneous temperature exceeded 30-32 degrees C. A linear relationship between...... epicutaneous and subcutaneous temperatures could be demonstrated with the regression equation: s = 0.9 c + 4.9 (r = 0.99). In eight of the 10 subjects the subcutaneous temperature could be reduced below 22 degrees C with the applied technique. It is concluded that the hair preserving effect of scalp cooling...

  1. Temperature rise of He Ⅱ forced flow and its negative Joule-Thomson effect

    Institute of Scientific and Technical Information of China (English)

    CHEN Yu; JU Yong-lin; ZHENG Qing-rong; LU Xue-sheng; GU An-zhong


    The temperature rise of He Ⅱ transfer system due to the negative Joule-Thomson (JT) effect is one of the major problems in the He Ⅱ forced flow system design. Negative Joule-Thomson effect of the He Ⅱ forced flow was analyzed and calculated in this paper. The temperature rise due to the heat leak along the transfer pipeline was calculated by the simplified equation and was modified by considering the negative Joule-Thomson effect. The modified results were compared with the temperature rise obtained by non-linear differential equations with consideration of the pressure gradient. The results show that the pressure gradient has strong effect on the temperature distribution. The modified results are in good agreement with the values calculated by the complicated equation, which verifies the effectiveness of the simplified equation in calculating the temperature rise when the negative JT effect of He Ⅱ is known.

  2. Effects of elevated temperatures on the mechanical properties of high fly ash content concrete%高温作用对大掺量粉煤灰混凝土力学性能影响

    Institute of Scientific and Technical Information of China (English)

    贾福萍; 崔艳莉; 孙宜兵; 程勇


    In this paper, the effects of elevated temperatures on the mechanical properties of high fly ash content concrete (HFCC) are presented. The specimens were prepared with three different replacements of cement by fly ash 30%,40% and 50% and were tested after exposure to elevated temperature 250, 450, 550 and 650°C respectively, compared with plain Portland concrete. The results showed that as the elevated temperature increases, the residual compressive strength and the residual tensile strength both apparently decrease and the deterioration of tensile strength was much quicker than the deterioration in compressive strength. The results also showed the influence of fly ash replacement on the degraded ratio of strength is complicated. After an exposure to the elevated temperatures, the degraded ratio of compressive strength is less than plain ordinary Portland concrete (PC) and one of tensile strength, except 30% fly ash replacement, remains the same. Based on the experiments, the alternating simulation formula for determining the relationship between residual strength ratio, elevated temperature and fly ash, the replacement is developed by using regression of results, which provide the theoretical basis for the evaluation and repair of HFCC after elevated temperature.%研究了高温作用对大掺量粉煤灰混凝土(HFCC)立方体力学性能的影响,探讨了不同加热温度、不同粉煤灰掺量与HFCC残余强度的关系.将粉煤灰掺量30%、40%和50%的混凝土立方体试块加热至250,450,550和650℃进行强度测试,并与素混凝土(不掺粉煤灰)试块进行对比.研究结果表明,随着温度升高,HFCC残余抗压、劈裂抗拉强度均出现明显退化,劈裂抗拉强度退化尤为明显;随着粉煤灰的掺入,粉煤灰掺量对强度退化率的影响具有复杂性:高温后HFCC抗压强度退化率均低于普通混凝土强度退化率;劈裂抗拉强度退化率除粉煤灰掺量30%外均低于普通混凝土退化

  3. Crustal heat flow measurements in western Anatolia from borehole equilibrium temperatures

    Directory of Open Access Journals (Sweden)

    K. Erkan


    Full Text Available Results of a crustal heat flow analysis in western Anatolia based on borehole equilibrium temperatures and rock thermal conductivity data are reported. The dataset comprises 113 borehole sites that were collected in Southern Marmara and Aegean regions of Turkey in 1995–1999. The measurements are from abandoned water wells with depths of 100–150 m. Data were first classed in terms of quality, and the low quality data, including data showing effects of hydrologic disturbances on temperatures, were eliminated. For the remaining 34 sites, one meter resolution temperature-depth curves were carefully analyzed for determination of the background geothermal gradients, and any effects of terrain topography and intra-borehole fluid flow were corrected when necessary. Thermal conductivities were determined either by direct measurements on representative surface outcrop or estimated from the borehole lithologic records. The calculated heat flow values are 85–90 mW m−2 in the northern and central parts of the Menderes horst-graben system. Within the system, the highest heat flow values (> 100 mW m−2 are observed in the northeastern part of Gediz Graben, near Kula active volcanic center. The calculated heat flow values are also in agreement with the results of studies on the maximum depth of seismicity in the region. In the Menderes horst-graben system, surface heat flow is expected to show significant variations as a result of active sedimentation and thermal refraction in grabens, and active erosion on horst detachment zones. High heat flow values (90–100 mW m−2 are also observed in the peninsular (western part of Çanakkale province. The heat flow anomaly here may be an extension of the high heat flow zone previously observed in the northern Aegean Sea. Moderate heat flow values (60–70 mW m−2 are observed in eastern part of Çanakkale and central part of Balıkesir provinces.

  4. Cementing Properties of Oil Shale Ash

    Institute of Scientific and Technical Information of China (English)


    The oil crisis has prompted renewed interest in direct burning of oil shale as an alternative energy source.A major problem in this process is the large portion of ash produced.The cementing properties of this ash were investigated to determine its applicability as a building material.By means of XRD, IR, NMR and ICP, we have studied the effects of burning temperature on the reactivity of ash.Maximum reactivity was obtained with ash samples produced at 700 °C to 900 °C.In this range, the strength of oil-shale-based material, with properties similar to cement, which is composed of oil shale and several other kinds of solid wastes, can achieve the standard of 42.5# cement.Our study has provided an experimental foundation and theoretical base for a massive utilization of oil shale.

  5. Clay Improvement with Burned Olive Waste Ash

    Directory of Open Access Journals (Sweden)

    Utkan Mutman


    Full Text Available Olive oil is concentrated in the Mediterranean basin countries. Since the olive oil industries are incriminated for a high quantity of pollution, it has become imperative to solve this problem by developing optimized systems for the treatment of olive oil wastes. This study proposes a solution to the problem. Burned olive waste ash is evaluated for using it as clay stabilizer. In a laboratory, bentonite clay is used to improve olive waste ash. Before the laboratory, the olive waste is burned at 550°C in the high temperature oven. The burned olive waste ash was added to bentonite clay with increasing 1% by weight from 1% to 10%. The study consisted of the following tests on samples treated with burned olive waste ash: Atterberg Limits, Standard Proctor Density, and Unconfined Compressive Strength Tests. The test results show promise for this material to be used as stabilizer and to solve many of the problems associated with its accumulation.

  6. Mass flow discharge and total temperature characterisation of a pyrotechnic gas generator formulation for airbag systems

    Energy Technology Data Exchange (ETDEWEB)

    Neutz, Jochen; Koenig, Andreas [Fraunhofer Institut fuer Chemische Technologie ICT, Pfinztal (Germany); Knauss, Helmut; Jordan, Sebastian; Roediger, Tim; Smorodsky, Boris [Universitaet Stuttgart (Germany). Institut fuer Aerodynamik und Gasdynamik; Bluemcke, Erich Walter [AUDI AG, Department I/EK-523, Ingolstadt (Germany)


    The mass flow characteristics of gas generators for airbag applications have to comply with a number of requirements for an optimal deployment of the airbag itself. Up to now, the mass flow was determined from pressure time histories of so-called can tests. This procedure suffers from the missing knowledge on the temperature of the generated gas entering the can. A new test setup described in this paper could overcome this problem by providing highly time resolved information on the gas's total temperature and the mass flow of the generator. The test setup consisted of a combustion chamber with a specially designed Laval nozzle in combination with a temperature sensor of high time resolution. The results showed a high time resolved temperature signal, which was disturbed by the formation of a slag layer on the sensor. Plausibility considerations with experimentally and thermodynamically determined combustion temperatures led to satisfying results for the overall temperature as characteristic parameter of airbag inflating gases flows from pyrotechnics. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

  7. Effect of Coolant Temperature and Mass Flow on Film Cooling of Turbine Blades (United States)

    Garg, Vijay K.; Gaugler, Raymond E.


    A three-dimensional Navier Stokes code has been used to study the effect of coolant temperature, and coolant to mainstream mass flow ratio on the adiabatic effectiveness of a film-cooled turbine blade. The blade chosen is the VKI rotor with six rows of cooling holes including three rows on the shower head. The mainstream is akin to that under real engine conditions with stagnation temperature = 1900 K and stagnation pressure = 3 MPa. Generally, the adiabatic effectiveness is lower for a higher coolant temperature due to nonlinear effects via the compressibility of air. However, over the suction side of shower-head holes, the effectiveness is higher for a higher coolant temperature than that for a lower coolant temperature when the coolant to mainstream mass flow ratio is 5% or more. For a fixed coolant temperature, the effectiveness passes through a minima on the suction side of shower-head holes as the coolant to mainstream mass flow, ratio increases, while on the pressure side of shower-head holes, the effectiveness decreases with increase in coolant mass flow due to coolant jet lift-off. In all cases, the adiabatic effectiveness is highly three-dimensional.

  8. Hydrogen/Oxygen Reactions at High Pressures and Intermediate Temperatures: Flow Reactor Experiments and Kinetic Modeling

    DEFF Research Database (Denmark)

    Hashemi, Hamid; Christensen, Jakob Munkholt; Glarborg, Peter

    A series of experimental and numerical investigations into hydrogen oxidation at high pressures and intermediate temperatures has been conducted. The experiments were carried out in a high pressure laminar flow reactor at 50 bar pressure and a temperature range of 600–900 K. The equivalence ratio......, ignition occurs at the temperature of 775–800 K. In general, the present model provides a good agreement with the measurements in the flow reactor and with recent data on laminar burning velocity and ignition delay time.......A series of experimental and numerical investigations into hydrogen oxidation at high pressures and intermediate temperatures has been conducted. The experiments were carried out in a high pressure laminar flow reactor at 50 bar pressure and a temperature range of 600–900 K. The equivalence ratio......, the mechanism is used to simulate published data on ignition delay time and laminar burning velocity of hydrogen. The flow reactor results show that at reducing, stoichiometric, and oxidizing conditions, conversion starts at temperatures of 750–775 K, 800–825 K, and 800–825 K, respectively. In oxygen atmosphere...

  9. Debris flow grain size scales with sea surface temperature over glacial-interglacial timescales (United States)

    D'Arcy, Mitch; Roda Boluda, Duna C.; Whittaker, Alexander C.; Araújo, João Paulo C.


    Debris flows are common erosional processes responsible for a large volume of sediment transfer across a range of landscapes from arid settings to the tropics. They are also significant natural hazards in populated areas. However, we lack a clear set of debris flow transport laws, meaning that: (i) debris flows remain largely neglected by landscape evolution models; (ii) we do not understand the sensitivity of debris flow systems to past or future climate changes; and (iii) it remains unclear how to interpret debris flow stratigraphy and sedimentology, for example whether their deposits record information about past tectonics or palaeoclimate. Here, we take a grain size approach to characterising debris flow deposits from 35 well-dated alluvial fan surfaces in Owens Valley, California. We show that the average grain sizes of these granitic debris flow sediments precisely scales with sea surface temperature throughout the entire last glacial-interglacial cycle, increasing by ~ 7 % per 1 ° C of climate warming. We compare these data with similar debris flow systems in the Mediterranean (southern Italy) and the tropics (Rio de Janeiro, Brazil), and find equivalent signals over a total temperature range of ~ 14 ° C. In each area, debris flows are largely governed by rainfall intensity during triggering storms, which is known to increase exponentially with temperature. Therefore, we suggest that these debris flow systems are transporting predictably coarser-grained sediment in warmer, stormier conditions. This implies that debris flow sedimentology is governed by discharge thresholds and may be a sensitive proxy for past changes in rainfall intensity. Our findings show that debris flows are sensitive to climate changes over short timescales (≤ 104 years) and therefore highlight the importance of integrating hillslope processes into landscape evolution models, as well as providing new observational constraints to guide this. Finally, we comment on what grain size

  10. Recovering germanium from coal ash by chlorination with ammonium chloride

    Institute of Scientific and Technical Information of China (English)


    A new process of enriching germanium from coal ash was developed. The process involves in mixing the coal ash and ammonium chloride and then roasting the mixture to produce germanium chloride that is then absorbed by dilute hydrochloric acid and hydrolyzed to germanium oxide. The germanium recovery reached to 80.2% at the optimum condition: mass ratio of NH4Cl/coal ash is 0.15, roasting temperature 400℃ and roasting time 90 min.

  11. Ash chemistry and sintering, verification of the mechanisms

    Energy Technology Data Exchange (ETDEWEB)

    Hupa, M.; Skrifvars, B.J. [Aabo Akademi, Turku (Finland)


    In this project four sintering mechanisms have been studied, i.e., partial melting with a viscous liquid, partial melting with a non-viscous liquid, chemical reaction sintering and solid state sintering. The work has aimed at improving the understanding of ash sintering mechanisms and quantifying their role in combustion and gasification. The work has been oriented in particular on the understanding of biomass ash behavior. The work has not directly focused on any specific technical application. However, results can also be applied on other fuels such as brown coal, petroleum coke, black liquor and different types of wastes (PDF, RDF, MSW). In one part of study the melting behavior was calculated for ten biomass ashes and compared with lab measurements of sintering tendencies. The comparison showed that the T{sub 15} temperatures, i.e. those temperatures at which the ashes contained 15 % molten phase, correlated fairly well with the temperature at which the sintering measurements detected sintering. This suggests that partial melting can be predicted fairly accurate for some ashes already with the today existing thermodynamic calculation routines. In some cases, however the melting calculations did not correlate with the detected sintering temperatures. In a second part detailed measurements on ash behavior was conducted both in a semi full scale CFB and a lab scale FBC. Ashes and deposits were collected and analyzed in several different ways. These analyses show that the ash chemistry shifts radically when the fuel is shifted. Fuels with silicate based ashes behaved totally different than those with an oxide or salt based ash. The chemistry was also affected by fuel blending. The ultimate goal has been to be able to predict the ash thermal behavior during biomass thermal conversion, using the fuel and ash elemental analyses and a few operational key parameters as the only input data. This goal has not yet today been achieved. (author)

  12. Influence of fluid temperature gradient on the flow within the shaft gap of a PLR pump (United States)

    Qian, W.; Rosic, B.; Zhang, Q.; Khanal, B.


    In nuclear power plants the primary-loop recirculation (PLR) pump circulates the high temperature/high-pressure coolant in order to remove the thermal energy generated within the reactor. The pump is sealed using the cold purge flow in the shaft seal gap between the rotating shaft and stationary casing, where different forms of Taylor-Couette flow instabilities develop. Due to the temperature difference between the hot recirculating water and the cold purge water (of order of 200 °C), the flow instabilities in the gap cause temperature fluctuations, which can lead to shaft or casing thermal fatigue cracks. The present work numerically investigated the influence of temperature difference and rotating speed on the structure and dynamics of the Taylor-Couette flow instabilities. The CFD solver used in this study was extensively validated against the experimental data published in the open literature. Influence of temperature difference on the fluid dynamics of Taylor vortices was investigated in this study. With large temperature difference, the structure of the Taylor vortices is greatly stretched at the interface region between the annulus gap and the lower recirculating cavity. Higher temperature difference and rotating speed induce lower fluctuating frequency and smaller circumferential wave number of Taylor vortices. However, the azimuthal wave speed remains unchanged with all the cases tested. The predicted axial location of the maximum temperature fluctuation on the shaft is in a good agreement with the experimental data, identifying the region potentially affected by the thermal fatigue. The physical understandings of such flow instabilities presented in this paper would be useful for future PLR pump design optimization.

  13. Separated flow behind a backward-facing step under a stationary temperature disturbance (United States)

    Boiko, A. V.; Dovgal, A. V.; Sorokin, A. M.


    The flow in the separation region of laminar boundary layer behind a rectangular backward-facing step has been experimentally examined under temperature non-uniformity of the flow. The data were obtained in a subsonic wind tunnel at Reynolds numbers M ≪ 1. The temperature disturbance was generated using a system of Peltier elements provided on the model surface upstream of the separation line. The effect of heating/cooling of the wall on the mean and fluctuating flow components was evaluated using hot-wire measurements. The experimental data were supplemented with calculations of linear-stability characteristics of model velocity profiles in the separated boundary layer. As a result, the response of the separated flow to a stationary thermal perturbation was revealed.

  14. Control of surface temperature of an aluminum alloy billet by air flow during a heating process at elevated temperature

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Young [KITECH, Cheonan (Korea, Republic of); Park, Joon Hong [Dong-A University, Busan (Korea, Republic of)


    The procedure of semi-solid forming is composed of heating a billet, forming, compression holding and ejecting step. There are several methods to heat a billet during semi-solid forming process such as electric heating and induction heating. Usually in semi-solid forming process, induction heating has been adopted to achieve more uniform temperature of semi-solid material. Although induction heating is better method than any others, however, there is still difference of temperature between internal part and surface part of semi-solid material. Worse yet, in case of high liquid fraction of semi-solid material, liquid of the billet will flow down though solid of the billet still remains, which is very difficult to handle. In the present study, induction heating of the billet during thixoforging process with forced surface cooling has been performed to obtain more uniform distribution of temperature, microstructure and shape of the billet. Distribution of temperature of the billets was measured and compared with that of conventional distribution of temperature. Microscopic and macroscopic aspects of the billets were discussed according to location of the measuring points. By this new induction heating method, not only temperature distributions over the whole billet become uniform, but also control of temperature distribution between inside and outside part of the billet is possible as user's experimental intentions,.

  15. Estimation of Joule heating effect on temperature and pressure distribution in electrokinetic-driven microchannel flows. (United States)

    Chein, Reiyu; Yang, Yeong Chin; Lin, Yushan


    In this study we present simple analytical models that predict the temperature and pressure variations in electrokinetic-driven microchannel flow under the Joule heating effect. For temperature prediction, a simple model shows that the temperature is related to the Joule heating parameter, autothermal Joule heating parameter, external cooling parameter, Peclet number, and the channel length to channel hydraulic diameter ratio. The simple model overpredicted the thermally developed temperature compared with the full numerical simulation, but in good agreement with the experimental measurements. The factors that affect the external cooling parameters, such as the heat transfer coefficient, channel configuration, and channel material are also examined based on this simple model. Based on the mass conservation, a simple model is developed that predicts the pressure variations, including the temperature effect. An adverse pressure gradient is required to satisfy the mass conservation requirement. The temperature effect on the pressure gradient is via the temperature-dependent fluid viscosity and electroosmotic velocity.

  16. Cleanup Verification Package for the 126-F-1, 184-F Powerhouse Ash Pit

    Energy Technology Data Exchange (ETDEWEB)

    S. W. Clark and H. M Sulloway


    This cleanup verification package documents completion of remedial action for the 126-F-1, 184-F Powerhouse Ash Pit. This waste site received coal ash from the 100-F Area coal-fired steam plant. Leakage of process effluent from the 116-F-14 , 107-F Retention Basins flowed south into the ash pit, contaminating the northern portion.

  17. Cleanup Verification Package for the 126-F-1, 184-F Powerhouse Ash Pit

    Energy Technology Data Exchange (ETDEWEB)

    S. W. Clark and H. M. Sulloway


    This cleanup verification package documents completion of remedial action for the 126-F-1, 184-F Powerhouse Ash Pit. This waste site received coal ash from the 100-F Area coal-fired steam plant. Leakage of process effluent from the 116-F-14 , 107-F Retention Basins flowed south into the ash pit, contaminating the northern portion.

  18. Improved CFD Model to Predict Flow and Temperature Distributions in a Blast Furnace Hearth (United States)

    Komiyama, Keisuke M.; Guo, Bao-Yu; Zughbi, Habib; Zulli, Paul; Yu, Ai-Bing


    The campaign life of a blast furnace is limited by the erosion of hearth refractories. Flow and temperature distributions of the liquid iron have a significant influence on the erosion mechanism. In this work, an improved three-dimensional computational fluid dynamics model is developed to simulate the flow and heat transfer phenomena in the hearth of BlueScope's Port Kembla No. 5 Blast Furnace. Model improvements feature more justified input parameters in turbulence modeling, buoyancy modeling, wall boundary conditions, material properties, and modeling of the solidification of iron. The model is validated by comparing the calculated temperatures with the thermocouple data available, where agreements are established within ±3 pct. The flow distribution in the hearth is discussed for intact and eroded hearth profiles, for sitting and floating coke bed states. It is shown that natural convection affects the flow in several ways: for example, the formation of (a) stagnant zones preventing hearth bottom from eroding or (b) the downward jetting of molten liquid promoting side wall erosion, or (c) at times, a vortex-like peripheral flow, promoting the "elephant foot" type erosion. A significant influence of coke bed permeability on the macroscopic flow pattern and the refractory temperature is observed.

  19. Tidal reversal and flow velocities using temperature and specific conductance in a small wetland creek (United States)

    Eaton, Timothy T.


    Characterizing flow dynamics in very small tidal creeks is complicated and not well suited to methods developed for upland streams or coastal estuaries, due to low flows, bidirectionality and shallow waters. Simple instrumentation enables thermal and salinity signals to be used to observe flow directions and estimate velocities in these settings. Using multiple inexpensive sensors over 500 m along a tidally influenced wetland creek, I demonstrate how advection of temperature and specific conductance pulses reveal flood and ebb tides and the temporary reversal of flow by warmer, estuarine water from the receiving embayment. The sequential rise of temperature upstream was most evident under hot and dry conditions, after daily peak air temperatures of 25 °C or above, and was subdued or disrupted under cooler or rainy conditions in summertime. Changes in specific conductance at successive sites upstream were less susceptible to environmental influences and confirm tidal flood velocity of between 0.07 and 0.37 m/s. The tidally-induced flow reversal suggests that periodic high tide conditions can interfere with rapid dispersal of pollution discharges, such as from the combined sewer overflow (CSO) located upstream of the studied creek reach. This low-cost approach of temperature and specific conductance sensing in vegetated coastal wetlands where access, precise elevation control and creek discharge measurements are difficult, provides a simple way of tracking water masses when sufficient contrast exists between water sources.

  20. Prediction of Air Flow and Temperature Distribution Inside a Yogurt Cooling Room Using Computational Fluid Dynamics

    Directory of Open Access Journals (Sweden)

    A Surendhar


    Full Text Available Air flow and heat transfer inside a yogurt cooling room were analysed using Computational Fluid Dynamics. Air flow and heat transfer models were based on 3D, unsteady state, incompressible, Reynolds-averaged Navier-Stokes equations and energy equations. Yogurt cooling room was modelled with the measured geometry using 3D design tool AutoCAD. Yogurt cooling room model was exported into the flow simulation software by specifying properties of inlet air, yogurt, pallet and walls of the room. Packing material was not considered in this study because of less thickness (cup-0.5mm, carton box-1.5mm and negligible resistance created in the conduction of heat. 3D Computational domain was meshed with hexahedral cells and governing equations were solved using explicit finite volume method. Air flow pattern inside the room and the temperature distribution in the bulk of palletized yogurt were predicted. Through validation, the variation in the temperature distribution and velocity vector from the measured value was found to be 2.0oC (maximum and 30% respectively. From the simulation and the measured value of the temperature distribution, it was observed that the temperature was non-uniform over the bulk of yogurt. This might be due to refrigeration capacity, air flow pattern, stacking of yogurt or geometry of the room. Required results were achieved by changing the location of the cooling fan.

  1. Trace elements in coal ash (United States)

    Deonarine, Amrika; Kolker, Allan; Doughten, Michael W.


    Coal ash is a residual waste product primarily produced by coal combustion for electric power generation. Coal ash includes fly ash, bottom ash, and flue-gas desulfurization products (at powerplants equipped with flue-gas desulfurization systems). Fly ash, the most common form of coal ash, is used in a range of products, especially construction materials. A new Environmental Protection Agency ruling upholds designation of coal ash as a non-hazardous waste under Subtitle D of the Resource Conservation and Recovery Act, allowing for the continued beneficial use of coal ash and also designating procedures and requirements for its storage.

  2. Modelling of temperature in deep boreholes and evaluation of geothermal heat flow at Forsmark and Laxemar

    Energy Technology Data Exchange (ETDEWEB)

    Sundberg, Jan; Back, Paer-Erik; Laendell, Maerta; Sundberg, Anders (GEO INNOVA AB, Linkoeping (Sweden))


    This report presents modelling of temperature and temperature gradients in boreholes in Laxemar and Forsmark and fitting to measured temperature data. The modelling is performed with an analytical expression including thermal conductivity, thermal diffusivity, heat flow, internal heat generation and climate events in the past. As a result of the fitting procedure it is also possible to evaluate local heat flow values for the two sites. However, since there is no independent evaluation of the heat flow, uncertainties in for example thermal conductivity, diffusivity and the palaeoclimate temperature curve are transferred into uncertainties in the heat flow. Both for Forsmark and Laxemar, reasonably good fits were achieved between models and data on borehole temperatures. However, none of the general models achieved a fit within the 95% confidence intervals of the measurements. This was achieved in some cases for the additional optimised models. Several of the model parameters are uncertain. A good model fit does not automatically imply that 'correct' values have been used for these parameters. Similar model fits can be expected with different sets of parameter values. The palaeoclimatically corrected surface mean heat flow at Forsmark and Laxemar is suggested to be 61 and 56 mW/m2 respectively. If all uncertainties are combined, including data uncertainties, the total uncertainty in the heat flow determination is judged to be within +12% to -14% for both sites. The corrections for palaeoclimate are quite large and verify the need of site-specific climate descriptions. Estimations of the current ground surface temperature have been made by extrapolations from measured temperature logging. The mean extrapolated ground surface temperature in Forsmark and Laxemar is estimated to 6.5 deg and 7.3 deg C respectively. This is approximately 1.7 deg C higher for Forsmark, and 1.6 deg C higher for Laxemar compared to data in the report SKB-TR-06-23. Comparison with

  3. Radiation effect on temperature distribution in three-dimensional Couette flow with suction or injection

    Institute of Scientific and Technical Information of China (English)

    Bhupendra.Kumar Sharma; Mamta Agarwal; R.C.Chaudhary


    A theoretical analysis of three-dimensional Couette flow with radiation effect on temperature distribution has been analysed, when the injection of the fluid at the lower stationary plate is a transverse sinusoidal one and its corresponding removal by constant suction through the upper porous plate is in uniform motion. Due to this type of injection velocity, the flow becomes three-dimensional. The effect of Prandtl number,radiation parameter and injection parameter on rate of heat transfer has been examined by the help of graphs. The Prandtl number has a much greater effect on the temperature distribution than the injection or radiation parameter.

  4. Large concentration changes due to thermal diffusion effects in gas flow microsystems with temperature gradients

    DEFF Research Database (Denmark)

    Quaade, Ulrich; Johannessen, Tue; Jensen, Søren;

    Thermal diffusion, or Sorét diffusion, is shown to cause significant concentration changes and transients in gas flow microsystems with temperature gradients. In a silicon microsystem, a temperature gradient of about 100 oC/mm is measured to produce concentration transients of up to 13.......7 % in an argon/helium mixture, when the flow is abruptly changed from a high value to a low value. Finite element simulations of the thermal diffusion in a geometry similar to the experimental setup reproduce the measurements....

  5. Catalytic oxidation of gaseous reduced sulfur compounds using coal fly ash. (United States)

    Kastner, James R; Das, K C; Melear, Nathan D


    Activated carbon has been shown to oxidize reduced sulfur compounds, but in many cases it is too costly for large-scale environmental remediation applications. Alternatively, we theorized that coal fly ash, given its high metal content and the presence of carbon could act as an inexpensive catalytic oxidizer of reduced sulfur compounds for "odor" removal. Initial results indicate that coal fly ash can catalyze the oxidization of H(2)S and ethanethiol, but not dimethyl sulfide (DMS) and dimethyl disulfide (DMDS) at room temperature. In batch reactor systems, initial concentrations of 100-500 ppmv H(2)S or ethanethiol were reduced to 0-2 ppmv within 1-2 and 6-8 min, respectively. This was contrary to control systems without ash in which concentrations remained constant. Diethyl disulfide was formed from ethanethiol substantiating the claim that catalytic oxidation occurred. The presence of water increased the rate of adsorption/reaction of both H(2)S and ethanethiol for the room temperature reactions (23-25 degrees C). Additionally, in a continuous flow packed bed reactor, a gaseous stream containing an inlet H(2)S concentration of 400-500 ppmv was reduced to 200 ppmv at a 4.6s residence time. The removal efficiency remained at 50% for approximately 4.6h or 3500 reactor volumes. These results demonstrate the potential of using coal fly ash in reactors for removal of H(2)S and other reduced sulfur compounds.


    Institute of Scientific and Technical Information of China (English)

    A.F. Polyakov; D.L.Reviznikov; 沈青; 魏叔如


    Heat and mass transfer of a porous permeable wall in a high temperature gas dynamical flow is considered. Numerical simulation is conducted on the ground of the conjugate mathematical model which includes filtration and heat transfer equations in a porous body and boundary layer equations on its surface. Such an approach enables one to take into account complex interaction between heat and mass transfer in the gasdynamical flow and in the structure subjected to this flow.The main attention is given to the impact of the intraporous heat transfer intensity on the transpiration cooling efficiency.

  7. Effects of Whistling on Temperature Separation in a Swirling Flow-Field : 1st Report : Experiments


    鈴木, 允; 川橋, 正昭; 吉沢, 敦朋


    The total temperature separation of gas is produced by a swirling flow-field in a circular tube. This device is called the vortex-tube or the Ranque-Hilsch tube. When whistling is produced within the swirling flow in the vortex-tube, the tangential velocity distribution in the radial direction is deformed toward the forced vortex type in the whole region. This is caused by the acoustic streaming induced by the whistling. The whistling in the vortex-tube of a counter-flow type is produced by t...

  8. A Study on Flow Behavior of AA5086 Over a Wide Range of Temperatures (United States)

    Asgharzadeh, A.; Jamshidi Aval, H.; Serajzadeh, S.


    Flow stress behavior of AA5086 was determined using tensile testing at different temperatures from room temperature to 500 °C and strain rates varying between 0.002 and 1 s-1. The strain rate sensitivity parameter and occurrence of dynamic strain aging were then investigated in which an Arrhenius-type model was employed to study the serrated flow. Additionally, hot deformation behavior at temperatures higher than 320 °C was evaluated utilizing hyperbolic-sine constitutive equation. Finally, a feed forward artificial neural network model with back propagation learning algorithm was proposed to predict flow stress for all deformation conditions. The results demonstrated that the strain rate sensitivity at temperature range of 25-270 °C was negative due to occurrence of dynamic strain aging leading to significant reduction in fracture strain. The serrated yielding activation energy was found to be 46.1 kJ/mol. It indicated that the migration of Mg-atoms could be the main reason for this phenomenon. The hot deformation activation energy of AA5086 was also calculated about 202.3 kJ/mol while the dynamic recovery was the main softening process. Moreover, the ANN model having two hidden layers was shown to be an efficient structure for determining flow stress of the examined alloy for all temperatures and strain rates.

  9. Research of Heat Transfer Model in Rotary Ash Coolers%滚筒冷渣器传热模型的研究

    Institute of Scientific and Technical Information of China (English)

    司小东; 吕俊复; 王巍; 李金晶


    分析了携带翅片滚筒冷渣器内灰渣颗粒的流动过程和传热过程,提出了滚筒冷渣器一维轴向传热模型,模型中考虑了渣中未燃尽碳的残余燃烧,模型参数根据文献和实验室实验确定.利用该模型对一台300MW循环流化床锅炉上滚筒冷渣器的温度进行了预测,并与实际运行参数进行了比较.结果表明:该模型可以很好地预测滚筒冷渣器出口灰渣的温度和冷却水温度.%By analyzing the flow and heat transfer process of ash particles in a rotary ash cooler with fins, a one-dimensional heat transfer model was proposed, in which the reburning of residual carbon in bottom ash was considered while the model parameters determined in accordance with relevant reference materials and experimental results. Using the model, temperatures of rotary ash cooler for a 300 MW circulating fluidized bed boiler were predicted, which were then compared with actual operation parameters. Comparison results prove the model to be accurate in predicting ash discharge and cooling water temperatures of rotary ash coolers.

  10. Convective heat transfer for incompressible laminar gas flow in micropassage with constant wall temperature

    Institute of Scientific and Technical Information of China (English)

    安刚; 李俊明; 王补宣


    Theoretical investigations have been performed on the convective heat transfer for incompressible laminar flow of gases through microtube and parallel-plates micropassages with constant wall temperature. Considering the change in thermal conductivity and viscosity of gas in wall adjacent region from the kinetic theory, mathematical models are built for both of the micropassages. The dimensionless temperature distribution and the corresponding heat transfer characteristics are simulated numerically, and the results discussed briefly.

  11. Airborne-temperature-survey maps of heat-flow anomalies for exploration geology (United States)

    Delgrande, N. K.


    Precise airborne temperature surveys depicted small predawn surface temperature differences related to heat flow anomalies at the Long Valley, California, KGRA. Zones with conductive heat flow differences of 45 + or - 16 nu cal/sq cm(s) has predawn surface temperature differences of 1.4 + or - 0.3 C. The warmer zones had hot water circulating in a shallow (less than 60-m-deep) aquifer. Hot wate is a useful geochemical indicator of geothermal and mineral resource potential. The precise airborne temperature survey method recorded redundant infrared scanner signals at two wavelengths (10 to 12 micrometers and 4.5 to 5.5 micrometers) and two elevations (0.3 km and 1.2 km). Ground thermistor probes recorded air and soil temperatures during the survey overflights. Radiometric temperatures were corrected for air path and reflected sky radiation effects. Corrected temperatures were displayed in image form with color coded maps which depicted 0.24 C temperature differences.

  12. Failure to phytosanitize ash firewood infested with emerald ash borer in a small dry kiln using ISPM-15 standards. (United States)

    Goebel, P Charles; Bumgardner, Matthew S; Herms, Daniel A; Sabula, Andrew


    Although current USDA-APHIS standards suggest that a core temperature of 71.1 degrees C (160 degrees F) for 75 min is needed to adequately sanitize emerald ash borer, Agrilus planipennis Fairmaire-infested firewood, it is unclear whether more moderate (and economical) treatment regimes will adequately eradicate emerald ash borer larvae and prepupae from ash firewood. We constructed a small dry kiln in an effort to emulate the type of technology a small- to medium-sized firewood producer might use to examine whether treatments with lower temperature and time regimes successfully eliminate emerald ash borer from both spilt and roundwood firewood. Using white ash (Fraxinus americana L.) firewood collected from a stand with a heavy infestation of emerald ash borer in Delaware, OH, we treated the firewood using the following temperature and time regime: 46 degrees C (114.8 degrees F) for 30 min, 46 degrees C (114.8 degrees F) for 60 min, 56 degrees C (132.8 degrees F) for 30 min, and 56 degrees C (132.8 degrees F) for 60 min. Temperatures were recorded for the outer 2.54-cm (1-in.) of firewood. After treatment, all firewood was placed under mesh netting and emerald ash borer were allowed to develop and emerge under natural conditions. No treatments seemed to be successful at eliminating emerald ash borer larvae and perpupae as all treatments (including two nontreated controls) experienced some emerald ash borer emergence. However, the 56 degrees C (132.8 degrees F) treatments did result in considerably less emerald ash borer emergence than the 46 degrees C (114.8 degrees F) treatments. Further investigation is needed to determine whether longer exposure to the higher temperature (56 degrees C) will successfully sanitize emerald ash borer-infested firewood.

  13. Characteristics of MSWI fly ash during vitrification

    Institute of Scientific and Technical Information of China (English)

    TIAN Shu-lei; WANG Qi; WANG Qun-hui; MA Hong-zhi


    The vitrification characteristics of municipal solid waste incinerator (MSWI) fly ash were investigated. Effects of temperature on the binding efficiency of heavy metals, the change of chemical compositions and the weight loss of fly ash in the range of 800 - 1350 ℃ were studied. Toxicity Characteristic Leaching Procedure (TCLP) of the United States was used to analyze the leaching characteristics of heavy metals in fly ash and molten slag. Results indicate that chemical compositions, the weight loss of fly ash and the binding efficiency of heavy metals in fly ash have a tremendous change in the range of 1150 - 1260 ℃. The percentage of CaO, SiO2and AI203 increases with the increasing temperature, whereas it is contrary for SO3 , K2O, Na20 and CI; especially when the temperature is 1260 ℃, the percentage of these four elements decreases sharply from 43.72%to 0. 71%. The weight loss occurs obviously in the range of 1150 - 1260 ℃. Heavy metals of Pb and Cd are almost vaporized above 1000 ℃. Cr is not volatile and its binding efficiency can reach 100% below 1000 ℃. Resuits of TCLP indicate that the heavy metal content of molten slag is beyond stipulated limit values.

  14. Study of a Liquid Plug-Flow Thermal Cycling Technique Using a Temperature Gradient-Based Actuator

    Directory of Open Access Journals (Sweden)

    Yusuke Fuchiwaki


    Full Text Available Easy-to-use thermal cycling for performing rapid and small-volume DNA amplification on a single chip has attracted great interest in the area of rapid field detection of biological agents. For this purpose, as a more practical alternative to conventional continuous flow thermal cycling, liquid plug-flow thermal cycling utilizes a thermal gradient generated in a serpentine rectangular flow microchannel as an actuator. The transit time and flow speed of the plug flow varied drastically in each temperature zone due to the difference in the tension at the interface between temperature gradients. According to thermal distribution analyses in microfluidics, the plug flow allowed for a slow heating process, but a fast cooling process. The thermal cycle of the microfluid was consistent with the recommended temperature gradient for PCR. Indeed, amplification efficiency of the plug flow was superior to continuous flow PCR, and provided an impressive improvement over previously-reported flow microchannel thermal cycling techniques.

  15. Flow and containment characteristics of an air-curtain fume hood operated at high temperatures. (United States)

    Chen, Jia-Kun; Huang, Rong Fung; Hsin, Pei-Yi; Hsu, Ching Min; Chen, Chun-Wann


    The flow and leakage characteristics of the air-curtain fume hood under high temperature operation (between 100°C and 250°C) were studied. Laser-assisted flow visualization technique was used to reveal the hot plume movements in the cabinet and the critical conditions for the hood-top leakage. The sulfur hexafluoride tracer-gas concentration test method was employed to examine the containment spillages from the sash opening and the hood top. It was found that the primary parameters dominating the behavior of the flow field and hood performance are the sash height and the suction velocity as an air-curtain hood is operated at high temperatures. At large sash height and low suction velocity, the air curtain broke down and accompanied with three-dimensional flow in the cabinet. Since the suction velocity was low and the sash opening was large, the makeup air drawn down from the hood top became insufficient to counter act the rising hot plume. Under this situation, containment leakage from the sash opening and the hood top was observed. At small sash opening and high suction velocity, the air curtain presented robust characteristics and the makeup air flow from the hood top was sufficiently large. Therefore the containment leakages from the sash opening and the hood top were not observed. According to the results of experiments, quantitative operation sash height and suction velocity corresponding to the operation temperatures were suggested.


    Institute of Scientific and Technical Information of China (English)

    DONG Yu-hong; LU Xi-yun; ZHUANG Li-xian


    Thermally-stratified shear turbulent channel flow with temperature oscillation on the bottom wall of the channel was investigated with the Large Eddy Simulation (LES) approach coupled with dynamic Sub-Grid-Scale (SGS) models. The effect of temperature oscillation on the turbulent channel flow behavior was examined. The phase-averaged velocities and temperature, and flow structures at different Richardson numbers and periods of the oscillation was analyzed.

  17. Equipment for Measuring Air Flow, Air Temperature, Relative Humidity, and Carbon Dioxide in Schools. Technical Bulletin. (United States)

    Jacobs, Bruce W.

    Information on equipment and techniques that school facility personnel may use to evaluate IAQ conditions are discussed. Focus is placed on the IAQ parameters of air flow, air temperature, relative humidity, as well as carbon dioxide and the equipment used to measure these factors. Reasons for measurement and for when the measurement of these…

  18. Butterfly valve with metal seals controls flow of hydrogen from cryogenic through high temperatures (United States)

    Johnson, L. D.


    Butterfly valve with metal seals operates over a temperature range of minus 423 degrees to plus 440 degrees F with hydrogen as a medium and in a radiation environment. Media flow is controlled by an internal butterfly disk which is rotated by an actuation shaft.

  19. Effects of solid inertial particles on the velocity and temperature statistics of wall bounded turbulent flow

    DEFF Research Database (Denmark)

    Nakhaei, Mohammadhadi; Lessani, B.


    The effect of solid inertial particles on the velocity and temperature statistics of a non-isothermal turbulentchannel flow is studied using direct numerical simulation. The particles inertia is varied by changingthe particles diameter. The density of particles is kept constant. A two-way coupled...

  20. Measurement of Plasma Ion Temperature and Flow Velocity from Chord-Averaged Emission Line Profile

    Indian Academy of Sciences (India)

    Xu Wei


    The distinction between Doppler broadening and Doppler shift has been analysed, the differences between Gaussian fitting and the distribution of chord-integral line shape have also been discussed. Local ion temperature and flow velocity have been derived from the chord-averaged emission line profile by a chosen-point Gaussian fitting technique.

  1. A new fibre-optic sensor for high-temperature flow measurement

    NARCIS (Netherlands)

    Schiferli, W.; Cheng, L.K.; Jansen, T.H.


    Measuring flow is essentia ìn the process and oil & gas ìndustry. In the oil and gas industry, orifice plates and vortex meters are popular, since their lack of moving parts makes them robust. However, the need for electronics limits maximum process temperatures to 150 to 200'C. Special electronics

  2. The ash in forest fire affected soils control the soil losses. Part 2. Current and future research challenges (United States)

    Pereira, Paulo; Cerdà, Artemi


    Ash distribution on soil surface and impacts on soil properties received a great attention in recently (Pereira et al., 2010; Pereira et al., 2013). Ash it is a highly mobile material that can be easily transported wind, especially in severe wildland fires, where organic matter is reduced to dust, due the high temperatures of combustion. In the immediate period after the fire, ash cover rules soil erosion as previous researchers observed (Cerdà, 1998a; 1998b) and have strong influence on soil hydrological properties, such as water retention (Stoof et al. 2011 ) and wettability (Bodi et al., 2011). Ash it is also a valuable source of nutrients important for plant recuperation (Pereira et al., 2011; Pereira et al., 2012), but can act also as a source contamination, since are also rich in heavy metals (Pereira and Ubeda, 2010). Ash has different physical and chemical properties according the temperature of combustion, burned specie and time of exposition (Pereira et al., 2010). Thus this different properties will have different implications on soil properties including erosion that can increase due soil sealing (Onda et al. 2008) or decrease as consequence of raindrop impact reduction (Cerdà and Doerr, 2008). The current knowledge shows that ash has different impacts on soil properties and this depends not only from the type of ash produced, but of the soil properties (Woods and Balfour, 2010). After fire wind and water strong redistribute ash on soil surface, increasing the vulnerability of soil erosion in some areas, and reducing in others. Understand this mobility is fundamental have a better comprehension about the spatial and temporal effects of ash in soil erosion. Have a better knowledge about this mobility is a priority to future research. Other important aspects to have to be assessed in the future are how ash particulates percolate on soil and how ash chemical composition is important to induce soil aggregation and dispersion. How soil micro topography

  3. In-situ coal seam and overburden permeability characterization combining downhole flow meter and temperature logs.

    Directory of Open Access Journals (Sweden)

    Busse Julia


    Full Text Available The planning and design of any coal mine development requires among others a thorough investigation of the geological, geotechnical and hydrogeological subsurface conditions. As part of a coal mine exploration program we conducted heat pulse vertical flow meter testing. The flow data were combined with absolute and differential temperature logging data to gain information about the hydraulic characteristics of two different coal seams and their over- and interburden. For the strata that were localised based on geophysical logging data including density, gamma ray and resistivity hydraulic properties were quantified. We demonstrate that the temperature log response complements the flow meter log response. A coupling of both methods is therefore recommended to get an insight into the hydraulic conditions in a coal seam and its overburden.

  4. The numerical simulation of Taylor-Couette flow with radial temperature gradient (United States)

    Tuliszka-Sznitko, E.; Kiełczewski, K.


    The Taylor-Couette flow with radial temperature gradient is a canonical problem for the study of heat transfer in engineering issues. However, gaining insight into the transitional Taylor-Couette flow with temperature gradient still requires detailed experimental and numerical investigations. In the present paper we have performed computations for the cavity of aspect ratio Γ= 3.76 and radii ratios η= 0.82 and 0.375 with the heated rotating bottom disk and stationary outer cylinder. We analyse the influence of the end-wall boundary conditions and the thermal conditions on the flow structure, and on the distributions of the Nusselt number and torque along the inner and outer cylinders. The averaged values along the inner cylinder of the Nusselt number and torque obtained for different Re are analysed in the light of the results published in [2, 16, 17].

  5. Influence of temperature and addition of fiber in the flow behavior of orange juice

    Directory of Open Access Journals (Sweden)

    Raúl Siche


    Full Text Available In this study the influence of the addition of orange fiber in the flow behavior of orange juice was evaluated, using for this the Herschel-Bulkley model parameters. It was observed that the flow behavior of the juices changed due to the addition of fiber, from Newtonian to Pseudoplastic when its fiber content was 5% and the temperature changed from 30 °C to 20 °C, and from Pseudoplastic to Herschel-Bulkley when its fiber content was 12.5% and the temperature changed from 10 °C to 0 °C. The increase in fiber content resulted in a progressive increase of consistency and a decrease of the flow behavior index.

  6. Investigation of Nano Structural Changes by Annealing Temperature and Uniform Oxygen Flow on Ti Layers

    Directory of Open Access Journals (Sweden)

    Haleh Kangarlou


    Full Text Available Problem statement: Ti films of the same thickness, deposition angle (near normal and deposition rate were deposited on glass substrates at room temperature under UHV conditions. Approach: Different annealing temperatures 423 K, 523 K and 623 K with uniform 7 cm3 sec-1, oxygen flow, were used to produce titanium oxide layers. Results: Thin film structures were studied using AFM, XRD and spectrophotometer methods. Roughness of the films changed due to annealing process. Conclusion/Recommendations: The getting property of Ti and annealing temperature can play an important role on the structure of the films.

  7. Preliminary measurements of velocity, density and total temperature fluctuations in compressible subsonic flow (United States)

    Stainback, P. C.; Johnson, C. B.; Basnett, C. B.


    The heat transfer characteristics of a three-wire hot-wire probe operated with a constant temperature anemometer were investigated in the subsonic compressible flow regime. The sensitivity coefficients, with respect to velocity, density and total temperature, were measured and the results were used to calculate the velocity, density, and total temperature fluctuations in the test section of the Langley 0.3-m Transonic Cryogenic Tunnel (TCT). These results were extended to give estimates for fluctuations due to vorticity, sound, and entropy. In addition, attempts were made to determine the major source of disturbances in the 0.3-m TCT.

  8. Monitoring Temperature in High Enthalpy Arc-heated Plasma Flows using Tunable Diode Laser Absorption Spectroscopy (United States)

    Martin, Marcel Nations; Chang, Leyen S.; Jeffries, Jay B.; Hanson, Ronald K.; Nawaz, Anuscheh; Taunk, Jaswinder S.; Driver, David M.; Raiche, George


    A tunable diode laser sensor was designed for in situ monitoring of temperature in the arc heater of the NASA Ames IHF arcjet facility (60 MW). An external cavity diode laser was used to generate light at 777.2 nm and laser absorption used to monitor the population of electronically excited oxygen atoms in an air plasma flow. Under the assumption of thermochemical equilibrium, time-resolved temperature measurements were obtained on four lines-of-sight, which enabled evaluation of the temperature uniformity in the plasma column for different arcjet operating conditions.

  9. Fire vegetative ash and erosion in the Mediterranean areas. State of the art and future perspectives (United States)

    Pereira, Paulo; Cerdà, Artemi


    erosion. At this point we are dealing with a complex interaction since interactions, since low severity fires due ash, and high severity fires, due temperature induce soil hydrophobicity. After the fire, other ash properties may interact with soil erosion, as particulate size, and chemical composition, that can induce soil particulates flocculation or dispersion. Ash chemistry is strongly related with fire severity (Pereira et al., 2012). Further studies may be directed in the complex interaction between ash physico-chemical properties interaction with the degree of fire impacts on soil. These and other ideas will be discussed during the session. Acknowledgements, The authors appreciated the support of the project "Litfire", Fire effects in Lithuanian soils and ecosystems (MIP-048/2011) funded by the Lithuanian Research Council and FUEGORED (Spanish Network of Forest Fire Effects on Soils References Bodi, M., Doerr, S., Cerdà, A., Mataix-Solera, J. (2012) Hydrological effects of a layer of vegetation ash on underlying wettable and water repellent soil. Geoderma 191: 14-13. Bodi, M., Mataix-Solera, J., Doerr, S., Cerdà, A. (2011) The wettability of ash from burned vegetation and its relationship to Mediterranean plant species type, burn severity and total organic matter content. Geoderma, 160, 599-607. Cerdà, A., Doerr, S.H. (2008). The effect of ash and needle cover on surface runoff and erosion in the immediate post-fire period. Catena, 74, 256-263. Onda Y, Dietrich WE, Booker F. 2008. Evolution of overland flow after a severe forest fire, Point Reyes, California. Catena. 72, 13-20. Pereira, P., Bodi. M., Úbeda, X., Cerdà, A., Mataix-Solera, J., Balfour, V, Woods, S. (2010) Las cenizas y el ecosistema suelo, In: Cerdà, A. Jordan, A. (eds) Actualización en métodos y técnicas para el estudio de los suelos afectados por incendios forestales, 345-398. Càtedra de Divulgació de la Ciència. Universitat de Valencia. ISBN: 978

  10. Heat flow and subsurface temperature distributions in central and western New York. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Hodge, D.S.; Fromm, K.


    Initiation of a geothermal energy program in western and central New York requires knowledge of subsurface temperatures for targeting areas of potential resources. The temperature distribution in possible geothermal reservoirs, calculated from heat flow measurements and modeling techniques, shows that a large area of New York can be considered for exploitation of geothermal resources. Though the temperatures at currently accessible depths show the availability of only a low-temperature (less than 100/sup 0/C), direct-use resource, this can be considered as an alternative for the future energy needs of New York State. From analysis of bottom-hole-temperature data and direct heat flow measurements, estimates of temperatures in the Cambrian Sandstones provide the basis of the economic evaluation of the reservoir. This reservoir contains the extractable fluids needed for targeting a potential geothermal well site in the low-temperature geothermal target zone. In the northern section of the Appalachian basin, reservoir temperatures in the Cambrian are below 50/sup 0/C but may be over 80/sup 0/C in the deeper parts of the basin in southern New York State. Using a minimum of 50/sup 0/C as a useful reservoir temperature, temperatures in excess of this value are encountered in the Theresa Formation at depths in excess of 1300 meters. Considering a maximum depth for economical drilling to be 2500 meters with present technology, the 2500 meters to the Theresa (sea level datum) forms the lower limit of the geothermal resource. Temperatures in the range of 70/sup 0/C to 80/sup 0/C are predicted for the southern portion of New York State.

  11. Effects of Temperature, Humidity and Air Flow on Fungal Growth Rate on Loaded Ventilation Filters. (United States)

    Tang, W; Kuehn, T H; Simcik, Matt F


    This study compares the fungal growth ratio on loaded ventilation filters under various temperature, relative humidity (RH), and air flow conditions in a controlled laboratory setting. A new full-size commercial building ventilation filter was loaded with malt extract nutrients and conidia of Cladosporium sphaerospermum in an ASHRAE Standard 52.2 filter test facility. Small sections cut from this filter were incubated under the following conditions: constant room temperature and a high RH of 97%; sinusoidal temperature (with an amplitude of 10°C, an average of 23°C, and a period of 24 hr) and a mean RH of 97%; room temperature and step changes between 97% and 75% RH, 97% and 43% RH, and 97% and 11% RH every 12 hr. The biomass on the filter sections was measured using both an elution-culture method and by ergosterol assay immediately after loading and every 2 days up to 10 days after loading. Fungal growth was detected earlier using ergosterol content than with the elution-culture method. A student's t-test indicated that Cladosporium sphaerospermum grew better at the constant room temperature condition than at the sinusoidal temperature condition. By part-time exposure to dry environments, the fungal growth was reduced (75% and 43% RH) or even inhibited (11% RH). Additional loaded filters were installed in the wind tunnel at room temperature and an RH greater than 95% under one of two air flow test conditions: continuous air flow or air flow only 9 hr/day with a flow rate of 0.7 m(3)/s (filter media velocity 0.15 m/s). Swab tests and a tease mount method were used to detect fungal growth on the filters at day 0, 5, and 10. Fungal growth was detected for both test conditions, which indicates that when temperature and relative humidity are optimum, controlling the air flow alone cannot prevent fungal growth. In real applications where nutrients are less sufficient than in this laboratory study, fungal growth rate may be reduced under the same operating conditions.

  12. Prediction of flow stress of 7017 aluminium alloy under high strain rate compression at elevated temperatures

    Institute of Scientific and Technical Information of China (English)



    An artificial neural network (ANN) constitutive model and JohnsoneCook (JeC) model were developed for 7017 aluminium alloy based on high strain rate data generated from split Hopkinson pressure bar (SHPB) experiments at various temperatures. A neural network configuration consists of both training and validation, which is effectively employed to predict flow stress. Temperature, strain rate and strain are considered as inputs, whereas flow stress is taken as output of the neural network. A comparative study on JohnsoneCook (JeC) model and neural network model was performed. It was observed that the developed neural network model could predict flow stress under various strain rates and tem-peratures. The experimental stressestrain data obtained from high strain rate compression tests using SHPB over a range of temperatures (25?e300 ?C), strains (0.05e0.3) and strain rates (1500e4500 s?1) were employed to formulate JeC model to predict the flow stress behaviour of 7017 aluminium alloy under high strain rate loading. The JeC model and the back-propagation ANN model were developed to predict the flow stress of 7017 aluminium alloy under high strain rates, and their predictability was evaluated in terms of correlation coefficient (R) and average absolute relative error (AARE). R and AARE for the J-C model are found to be 0.8461 and 10.624%, respectively, while R and AARE for the ANN model are 0.9995 and 2.58%, respectively. The predictions of ANN model are observed to be in consistent with the experimental data for all strain rates and temperatures.

  13. 发电厂除灰泵浆体水击压强的计算与分析%The Calculation and Analysis of Water-hammer of Liquid-Solid Two -Phase Flow for Ash-Water Pump in Steam Power Plant

    Institute of Scientific and Technical Information of China (English)

    周云龙; 孙斌; 蒋诚


    The calculations and analysis on water hammer pressure of liquid-solid two-phase flow and the round velocity of turning back of the pump on ash-water pump in st e am power plant have been done. Based on the calculation results, some protection s against water-hammer for ash-water pump have been presented.%对某电厂除灰泵进行了浆体水击压强及反向转速的计算与分析,根据计算结果提出了除灰泵的水击防护措施。

  14. Molecular Rayleigh Scattering Techniques Developed for Measuring Gas Flow Velocity, Density, Temperature, and Turbulence (United States)

    Mielke, Amy F.; Seasholtz, Richard G.; Elam, Kristie A.; Panda, Jayanta


    Nonintrusive optical point-wise measurement techniques utilizing the principles of molecular Rayleigh scattering have been developed at the NASA Glenn Research Center to obtain time-averaged information about gas velocity, density, temperature, and turbulence, or dynamic information about gas velocity and density in unseeded flows. These techniques enable measurements that are necessary for validating computational fluid dynamics (CFD) and computational aeroacoustic (CAA) codes. Dynamic measurements allow the calculation of power spectra for the various flow properties. This type of information is currently being used in jet noise studies, correlating sound pressure fluctuations with velocity and density fluctuations to determine noise sources in jets. These nonintrusive techniques are particularly useful in supersonic flows, where seeding the flow with particles is not an option, and where the environment is too harsh for hot-wire measurements.

  15. The calibration and operation of a constant-temperature crossed-wire probe in supersonic flow (United States)

    Fernando, E. M.; Donovan, J. F.; Smits, A. J.


    The calibration and operation of a constant-temperature crossed-wire probe in supersonic flow is considered. Crossed-wire probes offer considerable advantages over single, inclined wires: the kinematic shear stress can be derived from a single point measurement; the rms quantities can be derived from the same measurement, and the instantaneous quantities can be obtained as a continuous function of time. However, using a crossed-wire probe in supersonic flow is subject to the following practical difficulties: the problem of flow interference, where the shock waves from one wire and its supports interfere with the flow over the other wire; the necessity for high frequency response to resolve the spectral content, and the sensitivity of the results to small changes in the calibration constants. In the present contribution, each of these problems is addressed. Practical solutions are suggested, and some encouraging results are presented.

  16. Regulation of electron temperature gradient turbulence by zonal flows driven by trapped electron modes

    Energy Technology Data Exchange (ETDEWEB)

    Asahi, Y., E-mail:; Tsutsui, H.; Tsuji-Iio, S. [Tokyo Institute of Technology, Tokyo 152-8550 (Japan); Ishizawa, A.; Watanabe, T.-H. [National Institute for Fusion Science, Gifu 509-5292 (Japan)


    Turbulent transport caused by electron temperature gradient (ETG) modes was investigated by means of gyrokinetic simulations. It was found that the ETG turbulence can be regulated by meso-scale zonal flows driven by trapped electron modes (TEMs), which are excited with much smaller growth rates than those of ETG modes. The zonal flows of which radial wavelengths are in between the ion and the electron banana widths are not shielded by trapped ions nor electrons, and hence they are effectively driven by the TEMs. It was also shown that an E × B shearing rate of the TEM-driven zonal flows is larger than or comparable to the growth rates of long-wavelength ETG modes and TEMs, which make a main contribution to the turbulent transport before excitation of the zonal flows.

  17. Mixed convection film condensation from downward flowing vapors onto a sphere with variable wall temperature (United States)

    Hsu, C.-H.; Yang, S.-A.

    A model is developed for the study of mixed- convection film condensation from downward flowing vapors onto a sphere with variable wall temperature. The model combined natural convection dominated and forced convection dominated film condensation, concerning effects of pressure gradient (P), interfacial vapor shear drag and non-uniform wall temperature variation (A), has been investigated and solved numerically. The effect of pressure gradient on the dimensionless mean heat transfer, NuRe-1/2 will remain almost uniform with increasing P until P={2 / 9} F for various corresponding available values of F. Meanwhile, the dimensionless mean heat transfer, NuRe-1/2 is increasing significantly with F for its corresponding available values of P. Although the non-uniform wall temperature variation has an appreciable influence on the local film flow and heat transfer; however, the dependence of mean heat transfer on A can be almost negligible.

  18. Thermal treatment of ashes[Fly Ash from Municipal Waste Incineration]; Termisk rening av askor

    Energy Technology Data Exchange (ETDEWEB)

    Wikman, Karin; Berg, Magnus; Bjurstroem, Henrik [AaF-Energi och Miljoe AB, Stockholm (Sweden); Nordin, Anders [Umeaa Univ. (Sweden). Dept. of Applied Physics and Electronics


    metal concentrate has to be land filled instead of the total amount of ash. The cost for thermal treatment of ash is today relatively high and this kind of ash treatment has an economic interest only during certain circumstances. The process cost is for example not very important if the residues from the process can be used in commercial glass production. Other situations that can make thermal treatment of ashes attractive are further increased land filling costs or new environmental restrictions. Today the cost for land filling in Sweden is relatively low and therefore it is unprofitable to treat ashes with high temperature processes. However, the development of more effective processes and higher costs and taxes for land filling could result in a better economic situation for thermal treatment processes.

  19. High Temperature Flow Response Modeling of Ultra-Fine Grained Titanium

    Directory of Open Access Journals (Sweden)

    Seyed Vahid Sajadifar


    Full Text Available This work presents the mechanical behavior modeling of commercial purity titanium subjected to severe plastic deformation (SPD during post-SPD compression, at temperatures of 600-900 °C and at strain rates of 0.001-0.1 s−1. The flow response of the ultra-fine grained microstructure is modeled using the modified Johnson-Cook model as a predictive tool, aiding high temperature forming applications. It was seen that the model was satisfactory at all deformation conditions except for the deformation temperature of 600 °C. In order to improve the predictive capability, the model was extended with a corrective term for predictions at temperatures below 700 °C. The accuracy of the model was displayed with reasonable agreement, resulting in error levels of less than 5% at all deformation temperatures.

  20. Measurements of temperature and velocity fluctuations in oscillating flows using thermal anemometry – application to thermoacoustic refrigerators


    Berson, Arganthaël; Poignand, Gaelle; Jondeau, Emmanuel; Blanc-Benon, Philippe; Comte-Bellot, Geneviève


    International audience; This paper summarizes our recent work on the development of thermal anemometry to measure velocity and temperature fluctuations in oscillating flows. First, we demonstrate that velocity cannot be measured accurately by hot-wire anemometry in oscillating flows when the flow reverses its direction. Indeed, there is no unique and well-defined correlation between the flow velocity and heat transfer near flow reversal, which prevents the recovery of velocity fluctuations fr...

  1. Experimental and Analytic Study on the Core Bypass Flow in a Very High Temperature Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Richard Schultz


    Core bypass flow has been one of key issues in the very high temperature reactor (VHTR) design for securing core thermal margins and achieving target temperatures at the core exit. The bypass flow in a prismatic VHTR core occurs through the control element holes and the radial and axial gaps between the graphite blocks for manufacturing and refueling tolerances. These gaps vary with the core life cycles because of the irradiation swelling/shrinkage characteristic of the graphite blocks such as fuel and reflector blocks, which are main components of a core's structure. Thus, the core bypass flow occurs in a complicated multidimensional way. The accurate prediction of this bypass flow and counter-measures to minimize it are thus of major importance in assuring core thermal margins and securing higher core efficiency. Even with this importance, there has not been much effort in quantifying and accurately modeling the effect of the core bypass flow. The main objectives of this project were to generate experimental data for validating the software to be used to calculate the bypass flow in a prismatic VHTR core, validate thermofluid analysis tools and their model improvements, and identify and assess measures for reducing the bypass flow. To achieve these objectives, tasks were defined to (1) design and construct experiments to generate validation data for software analysis tools, (2) determine the experimental conditions and define the measurement requirements and techniques, (3) generate and analyze the experimental data, (4) validate and improve the thermofluid analysis tools, and (5) identify measures to control the bypass flow and assess its performance in the experiment.

  2. Parameter estimation from flowing fluid temperature logging data in unsaturated fractured rock using multiphase inverse modeling

    Energy Technology Data Exchange (ETDEWEB)

    Mukhopadhyay, S.; Tsang, Y.; Finsterle, S.


    A simple conceptual model has been recently developed for analyzing pressure and temperature data from flowing fluid temperature logging (FFTL) in unsaturated fractured rock. Using this conceptual model, we developed an analytical solution for FFTL pressure response, and a semianalytical solution for FFTL temperature response. We also proposed a method for estimating fracture permeability from FFTL temperature data. The conceptual model was based on some simplifying assumptions, particularly that a single-phase airflow model was used. In this paper, we develop a more comprehensive numerical model of multiphase flow and heat transfer associated with FFTL. Using this numerical model, we perform a number of forward simulations to determine the parameters that have the strongest influence on the pressure and temperature response from FFTL. We then use the iTOUGH2 optimization code to estimate these most sensitive parameters through inverse modeling and to quantify the uncertainties associated with these estimated parameters. We conclude that FFTL can be utilized to determine permeability, porosity, and thermal conductivity of the fracture rock. Two other parameters, which are not properties of the fractured rock, have strong influence on FFTL response. These are pressure and temperature in the borehole that were at equilibrium with the fractured rock formation at the beginning of FFTL. We illustrate how these parameters can also be estimated from FFTL data.

  3. Dislodging a sessile drop by a high-Reynolds-number shear flow at subfreezing temperatures. (United States)

    Roisman, Ilia V; Criscione, Antonio; Tropea, Cameron; Mandal, Deepak Kumar; Amirfazli, Alidad


    The drop, exposed to an air flow parallel to the substrate, starts to dislodge when the air velocity reaches some threshold value, which depends on the substrate wetting properties and drop volume. In this study the critical air velocity is measured for different drop volumes, on substrates of various wettabilities. The substrate initial temperatures varied between the normal room temperature (24.5∘C) and subfreezing temperatures (-5∘C and -1∘C). The physics of the drop did not change at the subfreezing temperatures of the substrates, which clearly indicates that the drop does not freeze and remains liquid for a relatively long time. During this time solidification is not initiated, neither by the air flow nor by mechanical disturbances. An approximate theoretical model is proposed that allows estimation of the aerodynamic forces acting on the sessile drop. The model is valid for the case when the drop height is of the same order as the thickness of the viscous boundary in the airflow, but the inertial effects are still dominant. Such a situation, relevant to many practical applications, was never modeled before. The theoretical predictions for the critical velocity of drop dislodging agree well with the experimental data for both room temperature and lower temperatures of the substrates.

  4. Effects of flow rate and temperature on cyclic gas exchange in tsetse flies (Diptera, Glossinidae). (United States)

    Terblanche, John S; Chown, Steven L


    Air flow rates may confound the investigation and classification of insect gas exchange patterns. Here we report the effects of flow rates (50, 100, 200, 400 ml min(-1)) on gas exchange patterns in wild-caught Glossina morsitans morsitans from Zambia. At rest, G. m. morsitans generally showed continuous or cyclic gas exchange (CGE) but no evidence of discontinuous gas exchange (DGE). Flow rates had little influence on the ability to detect CGE in tsetse, at least in the present experimental setup and under these laboratory conditions. Importantly, faster flow rates resulted in similar gas exchange patterns to those identified at lower flower rates suggesting that G. m. morsitans did not show DGE which had been incorrectly identified as CGE at lower flow rates. While CGE cycle frequency was significantly different among the four flow rates (prate treatment variation. Using a laboratory colony of closely related, similar-sized G. morsitans centralis we subsequently investigated the effects of temperature, gender and feeding status on CGE pattern variation since these factors can influence insect metabolic rates. At 100 ml min(-1) CGE was typical of G. m. centralis at rest, although it was significantly more common in females than in males (57% vs. 43% of 14 individuals tested per gender). In either sex, temperature (20, 24, 28 and 32 degrees C) had little influence on the number of individuals showing CGE. However, increases in metabolic rate with temperature were modulated largely by increases in burst volume and cycle frequency. This is unusual among insects showing CGE or DGE patterns because increases in metabolic rate are usually modulated by increases in frequency, but either no change or a decline in burst volume.

  5. Characterizing human skin blood flow regulation in response to different local skin temperature perturbations. (United States)

    Wu, Y; Nieuwenhoff, M D; Huygen, F J P M; van der Helm, F C T; Niehof, S; Schouten, A C


    Small nerve fibers regulate local skin blood flow in response to local thermal perturbations. Small nerve fiber function is difficult to assess with classical neurophysiological tests. In this study, a vasomotor response model in combination with a heating protocol was developed to quantitatively characterize the control mechanism of small nerve fibers in regulating skin blood flow in response to local thermal perturbation. The skin of healthy subjects' hand dorsum (n=8) was heated to 42°C with an infrared lamp, and then naturally cooled down. The distance between the lamp and the hand was set to three different levels in order to change the irradiation intensity on the skin and implement three different skin temperature rise rates (0.03°C/s, 0.02°C/s and 0.01°C/s). A laser Doppler imager (LDI) and a thermographic video camera recorded the temporal profile of the skin blood flow and the skin temperature, respectively. The relationship between the skin blood flow and the skin temperature was characterized by a vasomotor response model. The model fitted the skin blood flow response well with a variance accounted for (VAF) between 78% and 99%. The model parameters suggested a similar mechanism for the skin blood flow regulation with the thermal perturbations at 0.03°C/s and 0.02°C/s. But there was an accelerated skin vasoconstriction after a slow heating (0.01°C/s) (p-value<0.05). An attenuation of the skin vasodilation was also observed in four out of the seven subjects during the slow heating (0.01°C/s). Our method provides a promising way to quantitatively assess the function of small nerve fibers non-invasively and non-contact.

  6. Coal Ash Corrosion Resistant Materials Testing

    Energy Technology Data Exchange (ETDEWEB)

    D. K. McDonald; P. L. Daniel; D. J. DeVault


    In April 1999, three identical superheater test sections were installed into the Niles Unit No.1 for the purpose of testing and ranking the coal ash corrosion resistance of candidate superheater alloys. The Niles boiler burns high sulfur coal (3% to 3.5%) that has a moderate alkali content (0.2% sodium equivalents), thus the constituents necessary for coal ash corrosion are present in the ash. The test sections were controlled to operate with an average surface metal temperature from approximately 1060 F to 1210 F which was within the temperature range over which coal ash corrosion occurs. Thus, this combination of aggressive environment and high temperature was appropriate for testing the performance of candidate corrosion-resistant tube materials. Analyses of the deposit and scale confirmed that aggressive alkali sulfate constituents were present at the metal surface and active in tube metal wastage. The test sections were constructed so that the response of twelve different candidate tube and/or coating materials could be studied. The plan was to remove and evaluate one of the three test sections at time intervals of 1 year, 3 years, and 5 years. This would permit an assessment of performance of the candidate materials as a function of time. Test Section A was removed in November 2001 after about 24 months of service at the desired steam temperature set point, with about 15.5 months of exposure at full temperature. A progress report, issued in October 2002, was written to document the performance of the candidate alloys in that test section. The evaluation described the condition of each tube sample after exposure. It involved a determination of the rate of wall thickness loss for these samples. In cases where there was more than one sample of a candidate material in the test section, an assessment was made of the performance of the alloy as a function of temperature. Test Sections B and C were examined during the November 2001 outage, and it was decided that

  7. Mössbauer characterization of feed coal, ash and fly ash from a thermal power plant

    Energy Technology Data Exchange (ETDEWEB)

    Reyes Caballero, F.; Martínez Ovalle, S. A., E-mail:; Moreno Gutiérrez, M. [Universidad Pedagógica y Tecnológica de Colombia, UPTC, Grupo de Física Nuclear Aplicada y Simulación (Colombia)


    The aim of this work was apply {sup 57}Fe Transmission Mössbauer Spectroscopy at room temperature in order to study the occurrence of iron-containing mineral phases in: 1) feed coal; 2) coal ash, obtained in different stages of the ASTM D3174 standard method; and 3) fly ash, produced when coal is burned in the TERMOPAIPA IV thermal power plant localized in Boyacá, Colombia. According to obtained results, we can conclude the occurrence of pyrite and jarosite in the feed coal; Fe{sup 2+} and Fe{sup 3+} crystalline paramagnetic phases, superparamagnetic hematite and hematite in coal ash; Fe{sup 2+} and Fe{sup 3+} noncrystalline and crystalline phases, magnetite and hematite in fly ash. Precisely, for a basic understanding, this work discusses some the possible transformations that take place during coal combustion.

  8. Ash cloud aviation advisories

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, T.J.; Ellis, J.S. [Lawrence Livermore National Lab., CA (United States); Schalk, W.W.; Nasstrom, J.S. [EG and G, Inc., Pleasanton, CA (United States)


    During the recent (12--22 June 1991) Mount Pinatubo volcano eruptions, the US Air Force Global Weather Central (AFGWC) requested assistance of the US Department of Energy`s Atmospheric Release Advisory Capability (ARAC) in creating volcanic ash cloud aviation advisories for the region of the Philippine Islands. Through application of its three-dimensional material transport and diffusion models using AFGWC meteorological analysis and forecast wind fields ARAC developed extensive analysis and 12-hourly forecast ash cloud position advisories extending to 48 hours for a period of five days. The advisories consisted of ``relative`` ash cloud concentrations in ten layers (surface-5,000 feet, 5,000--10,000 feet and every 10,000 feet to 90,000 feet). The ash was represented as a log-normal size distribution of 10--200 {mu}m diameter solid particles. Size-dependent ``ashfall`` was simulated over time as the eruption clouds dispersed. Except for an internal experimental attempt to model one of the Mount Redoubt, Alaska, eruptions (12/89), ARAC had no prior experience in modeling volcanic eruption ash hazards. For the cataclysmic eruption of 15--16 June, the complex three-dimensional atmospheric structure of the region produced dramatically divergent ash cloud patterns. The large eruptions (> 7--10 km) produced ash plume clouds with strong westward transport over the South China Sea, Southeast Asia, India and beyond. The low-level eruptions (< 7 km) and quasi-steady-state venting produced a plume which generally dispersed to the north and east throughout the support period. Modeling the sequence of eruptions presented a unique challenge. Although the initial approach proved viable, further refinement is necessary and possible. A distinct need exists to quantify eruptions consistently such that ``relative`` ash concentrations relate to specific aviation hazard categories.

  9. Hybridized electromagnetic-triboelectric nanogenerator for scavenging air-flow energy to sustainably power temperature sensors. (United States)

    Wang, Xue; Wang, Shuhua; Yang, Ya; Wang, Zhong Lin


    We report a hybridized nanogenerator with dimensions of 6.7 cm × 4.5 cm × 2 cm and a weight of 42.3 g that consists of two triboelectric nanogenerators (TENGs) and two electromagnetic generators (EMGs) for scavenging air-flow energy. Under an air-flow speed of about 18 m/s, the hybridized nanogenerator can deliver largest output powers of 3.5 mW for one TENG (in correspondence of power per unit mass/volume: 8.8 mW/g and 14.6 kW/m(3)) at a loading resistance of 3 MΩ and 1.8 mW for one EMG (in correspondence of power per unit mass/volume: 0.3 mW/g and 0.4 kW/m(3)) at a loading resistance of 2 kΩ, respectively. The hybridized nanogenerator can be utilized to charge a capacitor of 3300 μF to sustainably power four temperature sensors for realizing self-powered temperature sensor networks. Moreover, a wireless temperature sensor driven by a hybridized nanogenerator charged Li-ion battery can work well to send the temperature data to a receiver/computer at a distance of 1.5 m. This work takes a significant step toward air-flow energy harvesting and its potential applications in self-powered wireless sensor networks.


    Institute of Scientific and Technical Information of China (English)

    G.S. Fu; W.Z. Chen; K.W. Qian


    The behavior of flow stress of Al sheets used for pressure can prepared by different melt-treatment during plastic deformation at elevated temperature was studied by isothermal compression testusing Gleeble1500 dynamic hot-simulation testing machine. The results show that the A1 sheets possess the remarkable characteristic of steady state flow stress when they are deformed in the temperature range of 350-500℃ at strain rates within the range of 0.01-10.0s-1. A hyperbolic sine relationship is found to correlate well the flow stress with the strain rate, and an Arrhenius relationship with the temperature, which implies that the process of plastic deformation at elevated temperature for this material is thermally activated. Compared with the Al pieces prepared by no or conventional melt-treatment, hot deformation activation energy of Al sheets prepared by high-efficient melt-treatment is the smallest (Q = 168.0kJ/mol), which reveals that the hot working formability of this material is very better, and has directly to do with the effective improvement of its metallurgical quality.

  11. Comparative study of oscillating flow characteristics of cryocooler regenerator at low temperatures

    Institute of Scientific and Technical Information of China (English)

    Yonglin JU; Qingqing SHEN


    A brief review is presented on previous experimental results and correlations on the friction factor of cryocooler regenerators operating at oscillating flow and pulsating pressure conditions, for different mesh sizes of packed woven screens, focusing on the effects of different operating frequencies ranging from 20 to 80 Hz, at room and cryogenic temperatures. A comparison of the friction factor data with those of other studies is presented to clarify the reason for the difference. Finally, a new oscillating flow correlation of regenerators, in terms of several non-dimensional parameters, is discussed and compared.

  12. Temperatures and Heat Flows in a Soil Enclosing a Slinky Horizontal Heat Exchanger


    Pavel Neuberger; Radomír Adamovský; Michaela Šeďová


    Temperature changes and heat flows in soils that host “slinky”-type horizontal heat exchangers are complex, but need to be understood if robust quantification of the thermal energy available to a ground-source heat pump is to be achieved. Of particular interest is the capacity of the thermal energy content of the soil to regenerate when the heat exchangers are not operating. Analysis of specific heat flows and the specific thermal energy regime within the soil, including that captured by the ...

  13. Effect of span length and temperature on the 3-D confined flow around a vortex promoter

    Energy Technology Data Exchange (ETDEWEB)

    Martin, E. [Fluid Mechanics Area, School of Industrial Engineering, Universidad de Vigo, Campus Lagoas-Marcosende, 36310 Vigo (Spain); Velazquez, A., E-mail: [Aerospace Propulsion and Fluid Mechanics Department, School of Aeronautics, Universidad Politecnica de Madrid, Plaza del Cardenal Cisneros 3, 28040 Madrid (Spain)


    Highlights: Black-Right-Pointing-Pointer The article deals with study of vortex promoter flow in a 3-D micro-channel. Black-Right-Pointing-Pointer Aspects studied are: channel aspect ratio and prism surface temperature. Black-Right-Pointing-Pointer Flow is classified into three different regimes depending on different parameters. Black-Right-Pointing-Pointer Results could be used for practical engineering design purposes. - Abstract: This article presents a numerical study on the influence of span length and wall temperature on the 3-D flow pattern around a square section vortex promoter located inside a micro-channel in the low Reynolds number regime. The first objective of the work is to quantify the critical Reynolds number that defines the onset of vortex shedding and to identify the different regimes that appear as a function of the channel aspect ratio (span to height ratio). We found that the critical Reynolds number for the onset of the Karman street regime increases as the aspect ratio decreases. In particular, for the aspect ratio of 1/2 the critical Reynolds number is nearly six times the critical Reynolds number of the 2-D problem. An intermediate oscillating regime between the steady and the Karman street solutions was also found to exist within a rather wide range of Reynolds numbers for small channel aspect ratios. The second objective was to investigate the influence of the vortex promoter wall temperature on both vortex shedding and flow pattern. This has practical engineering implications because the working fluid considered in the article is water that has a viscosity that depends significantly on temperature and promotes a strong coupling between the momentum and energy equations that influences the system behaviour. Results indicate that high surface temperature on the prism promotes the onset of the Karman street, suggesting design guidelines for micro-channel based heat sinks that make use of vortex promoters.

  14. Surface Modification of Fly Ash for Active Catalysis

    Directory of Open Access Journals (Sweden)

    Deepti Jain


    Full Text Available Fly ash based effective solid base catalyst (KF/Al2O3/fly ash473, KF/Al2O3/fly ash673, and KF/Al2O3/fly ash873 was synthesized by loading KF over chemically and thermally activated fly ash. The chemical activation was done by treating fly ash with aluminum nitrate via precipitation method followed by thermal activation at 650°C to increase the alumina content in fly ash. The increased alumina content was confirmed by SEM-EDX analysis. The alumina enriched fly ash was then loaded with KF (10 wt% and calcined at three different temperatures 473 K, 673 K and 873 K. The amount of loaded KF was monitored by XRD, FTIR spectroscopy, SEM-EDX, TEM and Flame Atomic Absorption Spectrophotometer. The catalytic activities of the catalysts were tested in the Claisen-Schmidt condensation of benzaldehyde and 4-methoxybenzaldehyde with 2′-hydroxyacetophenone to produce 2′-hydroxychalcone and 4-methoxy-2′-hydroxychalcone respectively. Higher conversion (83% of benzaldehyde and (89% of 4-methoxybenzaldehyde reveals that among these heterogeneous catalysts KF/Al2O3/fly ash673 is very active.

  15. Sea-surface temperature effects on 3D bora-like flow

    Energy Technology Data Exchange (ETDEWEB)

    Kraljevic, L. [Meteorological and Hydrological Service of Croatia, Zagreb (Croatia); Grisogono, B. [Dept. of Geophysics, Zagreb (Croatia)


    A COAMPS (TM) nonhydrostatic numerical model with a higher order turbulence closure scheme is used to study the effect of the sea-surface temperature (SST) on the idealized nonlinear flow over an idealized mountain in the presence of rotation. The low-level jet (LLJ) that develops at both flanks of the mountain is intensified by the Coriolis effect on the northern flank for a westerly flow. Shooting flow develops down the slope ending over the sea while resembling a hydraulic jump. This is considered as bora (bura) like flow. The front is related to the abrupt slowdown of the shooting flow through the hydraulic jump. Seven different idealized cases are addressed, the control run, nearly linear case with Fr = 1.2, and the cases with the SST 10 K colder, and 2.5 K, 5 K, 7.5 K and 10 K warmer than the control run. The maximum wind speeds in the shooting flow and the LLJs are around two times higher than the background wind speeds. The interplay of SST effects and the effects of the asymmetric lee-side vortices modify the location and the shape of the bora front which is found not to be parallel with the shoreline. The front is not stationary in time but exhibits vibrations which are more pronounced at the southern flank associated with the weaker LLJ. (orig.)

  16. The Mineral Transformation of Huainan Coal Ashes in Reducing Atmospheres

    Institute of Scientific and Technical Information of China (English)

    LI Han-xu; Yoshihiko Ninomiya; DONG Zhong-bing; ZHANG Ming-xu


    By using the advanced instrumentation of a Computer Controlled Scanning Electron Microscope (CCSEM),X-ray diffraction (XRD) and X-ray fluorescence (XRF), the ash composition and the mineral components of six typical Huainan coals of different origins were studied. The transformation of mineral matter at high temperatures was tracked by XRD in reducing conditions. The quartz phase decreased sharply and the anorthite content tended to increase at first and then decreased with increasing temperatures. The formed mullite phase reached a maximum at 1250 ℃ but showed a tendency of slow decline when the temperature was over 1250 ℃. The mullite formed in the heating process was the main reason of the high ash melting temperature of Huainan coals. Differences in peak intensity of mullite and anorthite reflected differences in phase concentration of the quenched slag fractions, which contributed to the differences in ash melting temperatures. The differences in the location of an amorphous hump maximum indicated differences of glass types which may affect ash melting temperatures. For Huainan coal samples with relatively high ash melting temperatures, the intensity of the diffraction lines for mullite under reducing condition is high while for the samples with relatively low ash melting temperature the intensity for anorthite is high.

  17. Phosphorus recovery from sewage sludge char ash

    NARCIS (Netherlands)

    Atienza-Martinez, M.; Gea, G.; Arauzo, J.; Kersten, S.R.A.; Kootstra, A.M.J.


    Phosphorus was recovered from the ash obtained after combustion at different temperatures (600 °C, 750 °C and 900 °C) and after gasification (at 820 °C using a mixture of air and steam as fluidising agent) of char from sewage sludge fast pyrolysis carried out at 530 °C. Depending on the leaching con

  18. Experimental and statistical determination of indicator parameters for the evaluation of fly ash and boiler ash PCDD/PCDF concentration from municipal solid waste incinerators. (United States)

    Streibel, T; Nordsieck, H; Neuer-Etscheidt, K; Schnelle-Kreis, J; Zimmermann, R


    On-line detectable indicator parameters in the flue gas of municipal solid waste incinerators (MSWI) such as chlorinated benzenes (PCBz) are well known surrogate compounds for gas-phase PCDD/PCDF concentration. In the here presented work derivation of indicators is broadened to the detection of fly and boiler ash fractions with increased PCDD/PCDF content. Subsequently these fractions could be subject to further treatment such as recirculation in the combustion chamber to destroy their PCDD/PCDF and other organic pollutants' content. Aim of this work was to detect suitable on-line detectable indicator parameters in the gas phase, which are well correlated to PCDD/PCDF concentration in the solid residues. For this, solid residues and gas-phase samples were taken at three MSWI plants in Bavaria. Analysis of the ash content from different plants yielded a broad variation range of PCDD/PCDF concentrations especially after disturbed combustion conditions. Even during normal operation conditions significantly increased PCDD/PCDF concentrations may occur after unanticipated disturbances. Statistical evaluation of gas phase and ash measurements was carried out by means of principal component analysis, uni- and multivariate correlation analysis. Surprisingly, well known indicators for gas-phase PCDD/PCDF concentration such as polychlorinated benzenes and phenols proved to be insufficiently correlated to PCDD/PCDF content of the solid residues. Moreover, no single parameter alone was found appropriate to describe the PCDD/PCDF content of fly and boiler ashes. On the other hand, multivariate fitting of three or four parameters yielded convenient correlation coefficients of at least r=0.8 for every investigated case. Thereby, comprehension of plant operation parameters such as temperatures and air flow alongside concentrations of inorganic compounds in the gas phase (HCl, CO, SO2, NOx) gave the best results. However, the suitable set of parameters suited best for estimation of

  19. Model of discontinuous plastic flow at temperature close to absolute zero

    CERN Document Server

    Marcinek, Dawid Jarosław; Sgobba, Stefano

    In the present study cryogenic tensile tests performed on different materials (316LN, JK2LB) were used. The discontinuous plastic flow phenomenon was analysed, in order to develop a constitutive model of serrated yielding as a support for analysis of structural materials at low temperatures. Devices and structures, cooled be means of liquid helium, operate at the temperatures equal or lower than 4.2 K, which for the examined materials is below the transition threshold between screw and edge dislocations. It is considered a threshold for the appearance of DPF consisting in cyclic drop of load followed by deformation jumps and generation of heat. Temperature oscillations resulting from the thermodynamic instability in stainless steel can be of the order of dT = 40 K, which is exceptionally dangerous for superconducting cables. Suitably calibrated numerical algorithm allows prediction of the behaviour of the material subjected to deformation at low temperatures. The issues presented in the present study are curr...

  20. Sulphation characteristics of paper sludge ash

    Energy Technology Data Exchange (ETDEWEB)

    Roh, S.A. [Environmental Systems Research Center, Korea Inst. of Machinery and Materials, Daejeon (Korea, Republic of); Kim, S.D. [Environmental Systems Research Center, Korea Inst. of Machinery and Materials, Daejeon (Korea, Republic of). Dept. of Chemical and Biomolecular Engineering


    Landfills are no longer a viable solution for the disposal of sludge produced from waste water treatment plants because of the decrease in available space, rising fees and growing environmental concerns. However, thermal utilization of this waste may be an economic and sustainable disposal solution. Co-combustion of low heating value sludge with fossil fuels has a positive effect for sulfur dioxide (SO{sub 2}) emissions due to the low sulphur content of biomass fuels and increased sulphur retention in the ash. The sulphur retention is attributed to the formation of sulphates, such as CaSO{sub 4}, K{sub 2}SO{sub 4} and Na{sub 2}SO{sub 4}. The amount of fuel-ash-related sulphur sorption increases during co-combustion. Therefore, sorbents for sulphur reduction may not be required if proper control of the biomass feed is maintained. This paper presented a study in which the sulphation characteristics of calcium-rich paper sludge ash were determined for the use of co-combustion of biomass and coal. The calcium in the paper sludge ash came from the limestone filler used in the manufacturing process to increase the density and whiteness of the paper at 2 paper mills in Korea. A thermobalance reactor along with XRD and SEM-EDX were used for the analysis of sulphated ash to determine the effects of sulphation temperature, particle size and SO{sub 2} concentration on sulphation conversion. The activation energy and pre-exponential factor of sulphation reaction of sludge ash were determined based on the uniform-reaction model. X-ray diffraction analysis revealed that most of the sulphation compounds were CaSO{sub 4}. The sulphation occurred uniformly throughout the ash and the CaSO{sub 4} did not block the outer pore of the sludge ash. The uniform distributions of CaO and other inert minerals in the ash resulted in uniform sulphation with good penetration of SO{sub 2} into pores of the sludge ash without pore blocking during sulphation of CaO. 13 refs., 1 tab., 9 figs.

  1. Effects Of Crystallographic Properties On The Ice Nucleation Properties Of Volcanic Ash Particles

    Energy Technology Data Exchange (ETDEWEB)

    Kulkarni, Gourihar R.; Nandasiri, Manjula I.; Zelenyuk, Alla; Beranek, Josef; Madaan, Nitesh; Devaraj, Arun; Shutthanandan, V.; Thevuthasan, Suntharampillai; Varga, Tamas


    Specific chemical and physical properties of volcanic ash particles that could affect their ability to induce ice formation are poorly understood. In this study, the ice nucleating properties of size-selected volcanic ash and mineral dust particles in relation to their surface chemistry and crystalline structure at temperatures ranging from –30 to –38 °C were investigated in deposition mode. Ice nucleation efficiency of dust particles was higher compared to ash particles at all temperature and relative humidity conditions. Particle characterization analysis shows that surface elemental composition of ash and dust particles was similar; however, the structural properties of ash samples were different.

  2. Effects of crystallographic properties on the ice nucleation properties of volcanic ash particles (United States)

    Kulkarni, Gourihar; Nandasiri, Manjula; Zelenyuk, Alla; Beranek, Josef; Madaan, Nitesh; Devaraj, Arun; Shutthanandan, Vaithiyalingam; Thevuthasan, Suntharampillai; Varga, Tamas


    Specific chemical and physical properties of volcanic ash particles that could affect their ability to induce ice formation are poorly understood. In this study, the ice nucleating properties of size-selected volcanic ash and mineral dust particles in relation to their surface chemistry and crystalline structure at temperatures ranging from -30 to -38°C were investigated in deposition mode. Ice nucleation efficiency of dust particles was higher compared to ash particles at all temperature and relative humidity conditions. Particle characterization analysis shows that surface elemental composition of ash and dust particles was similar; however, the structural properties of ash samples were different.

  3. Heat-flow and subsurface temperature history at the site of Saraya (eastern Senegal

    Directory of Open Access Journals (Sweden)

    F. Lucazeau


    Full Text Available New temperature measurements from eight boreholes in the West African Craton (WAC reveal superficial perturbations down to 100 meters below the alteration zone. These perturbations are both related to a recent increase of the surface air temperature (SAT and to the site effects caused by fluids circulations and/or the lower conduction in the alterites. The ground surface temperature (GST inverted from the boreholes temperatures is stable in the past (1700–1940 and then dramatically increases in the most recent years (1.5 °C since 1950. This is consistent with the increase of the SAT recorded at two nearby meteorological stations (Tambacounda and Kedougou, and more generally in the Sahel with a coeval rainfall decrease. Site effects are superimposed to the climatic effect and interpreted by advective (circulation of fluids or conductive (lower conductivity of laterite and of high-porosity sand perturbations. We used a 1-D finite differences thermal model and a Monte-Carlo procedure to find the best estimates of these sites perturbations: all the eight boreholes temperatures logs can be interpreted with the same basal heat-flow and the same surface temperature history, but with some realistic changes of thermal conductivity and/or fluid velocity. The GST trend observed in Senegal can be confirmed by two previous boreholes measurements made in 1983 in other locations of West Africa, the first one in an arid zone of northern Mali and the second one in a subhumid zone in southern Mali. Finally, the background heat-flow is low (30 ± 1 m Wm−2, which makes this part of the WAC more similar with the observations in the southern part (33 ± 8 m Wm−2 rather than with those in the northern part and in the PanAfrican domains where the surface heat-flow is 15–20 m Wm−2 higher.

  4. Heat-flow and subsurface temperature history at the site of Saraya (eastern Senegal) (United States)

    Lucazeau, F.; Rolandone, F.


    New temperature measurements from eight boreholes in the West African Craton (WAC) reveal superficial perturbations down to 100 m below the alteration zone. These perturbations are both related to a recent increase in the surface air temperature (SAT) and to the site effects caused by fluid circulations and/or the lower conduction in the alterites. The ground surface temperature (GST), inverted from the boreholes temperatures, increased slowly in the past (~0.4 °C from 1700 to 1940) and then, more importantly, in recent years (~1.5 °C from 1940 to 2010). This recent trend is consistent with the increase of the SAT recorded at two nearby meteorological stations (Tambacounda and Kedougou), and more generally in the Sahel with a coeval rainfall decrease. Site effects are superimposed to the climatic effect and interpreted by advective (circulation of fluids) or conductive (lower conductivity of laterite and of high-porosity sand) perturbations. We used a 1-D finite differences thermal model and a Monte-Carlo procedure to find the best estimates of these site perturbations: all the eight borehole temperature logs can be interpreted with the same basal heat-flow and the same surface temperature history, but with some realistic changes of thermal conductivity and/or fluid velocity. The GST trend observed in Senegal can be confirmed by two previous borehole measurements made in 1983 in other locations of West Africa, the first one in an arid zone of northern Mali and the second one in a sub-humid zone in southern Mali. Finally, the background heat-flow is low (31±2 mW m-2), which makes this part of the WAC more similar with the observations in the southern part (33±8 mW m-2) rather than with those in the northern part and in the Pan-African domains where the surface heat-flow is 15-20 mW m-2 higher.

  5. Ash particle erosion on steam boiler convective section

    Energy Technology Data Exchange (ETDEWEB)

    Meuronen, V.


    In this study, equations for the calculation of erosion wear caused by ash particles on convective heat exchanger tubes of steam boilers are presented. A new, three-dimensional test arrangement was used in the testing of the erosion wear of convective heat exchanger tubes of steam boilers. When using the sleeve-method, three different tube materials and three tube constructions could be tested. New results were obtained from the analyses. The main mechanisms of erosion wear phenomena and erosion wear as a function of collision conditions and material properties have been studied. Properties of fossil fuels have also been presented. When burning solid fuels, such as pulverized coal and peat in steam boilers, most of the ash is entrained by the flue gas in the furnace. In bubbling and circulating fluidized bed boilers, particle concentration in the flue gas is high because of bed material entrained in the flue gas. Hard particles, such as sharp edged quartz crystals, cause erosion wear when colliding on convective heat exchanger tubes and on the rear wall of the steam boiler. The most important ways to reduce erosion wear in steam boilers is to keep the velocity of the flue gas moderate and prevent channelling of the ash flow in a certain part of the cross section of the flue gas channel, especially near the back wall. One can do this by constructing the boiler with the following components. Screen plates can be used to make the velocity and ash flow distributions more even at the cross-section of the channel. Shield plates and plate type constructions in superheaters can also be used. Erosion testing was conducted with three types of tube constructions: a one tube row, an in- line tube bank with six tube rows, and a staggered tube bark with six tube rows. Three flow velocities and two particle concentrations were used in the tests, which were carried out at room temperature. Three particle materials were used: quartz, coal ash and peat ash particles. Mass loss

  6. Direct numerical simulation of Taylor-Couette flow subjected to a radial temperature gradient

    Energy Technology Data Exchange (ETDEWEB)

    Teng, Hao; Liu, Nansheng, E-mail:; Lu, Xiyun [Department of Modern Mechanics, University of Science and Technology of China, Hefei, Anhui 230026 (China); Khomami, Bamin, E-mail: [Department of Chemical and Biomolecular Engineering, The University of Tennessee, Knoxville, Tennessee 37996 (United States)


    Direct numerical simulations have been performed to study the Taylor-Couette (TC) flow between two rotating, coaxial cylinders in the presence of a radial temperature gradient. Specifically, the influence of the buoyant force and the outer cylinder rotation on the turbulent TC flow system with the radius ratio η = 0.912 was examined. For the co-rotating TC flows with Re{sub i} (inner cylinder) =1000 and Re{sub o} (outer cylinder) =100, a transition pathway to highly turbulent flows is realized by increasing σ, a parameter signifying the ratio of buoyant to inertial force. This nonlinear flow transition involves four intriguing states that emerge in sequence as chaotic wavy vortex flow for σ = 0, wavy interpenetrating spiral flows for σ = 0.02 and 0.05, intermittent turbulent spirals for σ = 0.1 and 0.2, and turbulent spirals for σ = 0.4. Overall, the fluid motion changes from a centrifugally driven flow regime characterized by large-scale wavy Taylor vortices (TVs) to a buoyancy-dominated flow regime characterized by small-scale turbulent vortices. Commensurate changes in turbulence statistics and heat transfer are seen as a result of the weakening of large-scale TV circulations and enhancement of turbulent motions. Additionally, the influence of variation of the outer cylinder rotation, −500 < Re{sub o} < 500 in presence of buoyancy (σ = 0.1) with Re{sub i} = 1000, has been considered. Specifically, it is demonstrated that this variation strongly influences the azimuthal and axial mean flows with a weaker influence on the fluctuating fluid motions. Of special interest, here are the turbulent dynamics near the outer wall where a marked decrease of turbulence intensity and a sign inversion of the Reynolds stress R{sub rz} are observed for the strongly counter-rotating regimes (Re{sub o} = − 300 and −500). To this end, it has been shown that the underlying flow physics for this drastic modification are associated with the modification of the correlation

  7. Redistribution of an inlet temperature distortion in an axial flow turbine stage (United States)

    Butler, T. L.; Sharma, O. P.; Joslyn, H. D.; Dring, R. P.


    The results of an experimental program aimed at determining the extent of the redistribution of an inlet temperature distortion in an axial flow turbine stage are presented. The program was conducted in a large-scale, low speed, single stage turbine where air, seeded with CO2 was introduced at one circumferential location upstream of the inlet guide vane. The migration of the seeded air through the turbine was determined by sensing CO2 concentration inside the stage. A temperature distortion was introduced by heating the seeded air. The CO2 concentration contours measured downstream of the vane showed little change with heating, indicating that the vane flowfield was relatively unaffected by the introduction of the temperature distortion. However, the CO2 contours observed on the rotor airfoil surfaces for the case with inlet heating indicated segregation of hot and cold gas, with the higher temperature gas migrating to the pressure side and the lower temperature gas migrating to the suction side. Significant increases in rotor secondary flow were also observed.

  8. Open Thermodynamic System Concept for Fluviokarst Underground Temperature and Discharge Flow Assessments (United States)

    Machetel, P.; Yuen, D. A.


    In this work, we propose to use Open Thermodynamic System (OTS) frameworks to assess temperatures and discharges of underground flows in fluviokarstic systems. The theoretical formulation is built on the first and second laws of thermodynamics. However, such assumptions would require steady states in the Control Volume to cancel the heat exchanges between underground water and embedding rocks. This situation is obviously never perfectly reached in Nature where flow discharges and temperatures vary with rainfalls, recessions and seasonal or diurnal fluctuations. First, we will shortly show that the results of a pumping test campaign on the Cent-Font (Hérault, France) fluviokarst during summer 2005 are consistent with this theoretical approach. Second, we will present the theoretical formalism of the OTS framework that leads to equation systems involving the temperatures and/or the discharges of the underground and surface flows.Third, this approach will be applied to the white (2003) conceptual model of fluviokarst, and we will present the numerical model built to assess the applicability of these assumptions. The first order of the field hydrologic properties observed at the Cent-Fonts resurgence are well described by the calculations based on this OTS framework. If this agreement is necessary, it is not sufficient to validate the method. In order to test its applicability, the mixing process has been modelized as a cooling reaction in a Continuous Stirred Tank Reactor (CSTR) for which matrix and intrusive flows are introduced continuously while effluent water is recovered at the output. The enthalpy of the various flows is conserved except for the part that exchanges heat with the embedding rocks. However the numerical model shows that in the water saturated part of the CS, the matrix flow swepts heat by convective-advective processes while temporal heat fluctuations from intrusive flows cross the CV walls. The numerical model shows that the convective flow from

  9. Nonlinear Nanofluid Flow over Heated Vertical Surface with Sinusoidal Wall Temperature Variations

    Directory of Open Access Journals (Sweden)

    S. S. Motsa


    Full Text Available The nonlinear density temperature variations in two-dimensional nanofluid flow over heated vertical surface with a sinusoidal wall temperature are investigated. The model includes the effects of Brownian motion and thermophoresis. Using the boundary layer approximation, the two-dimensional momentum, heat, and mass transfer equations are transferred to nonlinear partial differential equations form and solved numerically using a new method called spectral local linearisation method. The effects of the governing parameters on the fluid properties and on the heat and nanomass transfer coefficients are determined and shown graphically.

  10. Integrated LTCC Pressure/Flow/Temperature Multisensor for Compressed Air Diagnostics† (United States)

    Fournier, Yannick; Maeder, Thomas; Boutinard-Rouelle, Grégoire; Barras, Aurélie; Craquelin, Nicolas; Ryser, Peter


    We present a multisensor designed for industrial compressed air diagnostics and combining the measurement of pressure, flow, and temperature, integrated with the corresponding signal conditioning electronics in a single low-temperature co-fired ceramic (LTCC) package. The developed sensor may be soldered onto an integrated electro-fluidic platform by using standard surface mount device (SMD) technology, e.g., as a standard electronic component would be on a printed circuit board, obviating the need for both wires and tubes and thus paving the road towards low-cost integrated electro-fluidic systems. Several performance aspects of this device are presented and discussed, together with electronics design issues. PMID:22163518

  11. Integrated LTCC pressure/flow/temperature multisensor for compressed air diagnostics. (United States)

    Fournier, Yannick; Maeder, Thomas; Boutinard-Rouelle, Grégoire; Barras, Aurélie; Craquelin, Nicolas; Ryser, Peter


    We present a multisensor designed for industrial compressed air diagnostics and combining the measurement of pressure, flow, and temperature, integrated with the corresponding signal conditioning electronics in a single low-temperature co-fired ceramic (LTCC) package. The developed sensor may be soldered onto an integrated electro-fluidic platform by using standard surface mount device (SMD) technology, e.g., as a standard electronic component would be on a printed circuit board, obviating the need for both wires and tubes and thus paving the road towards low-cost integrated electro-fluidic systems. Several performance aspects of this device are presented and discussed, together with electronics design issues.

  12. Study of flow fractionation characteristics of magnetic chromatography utilizing high-temperature superconducting bulk magnet

    Directory of Open Access Journals (Sweden)

    Satoshi Fukui, Yoshihiro Shoji, Jun Ogawa, Tetsuo Oka, Mitsugi Yamaguchi, Takao Sato, Manabu Ooizumi, Hiroshi Imaizumi and Takeshi Ohara


    Full Text Available We present numerical simulation of separating magnetic particles with different magnetic susceptibilities by magnetic chromatography using a high-temperature superconducting bulk magnet. The transient transport is numerically simulated for two kinds of particles having different magnetic susceptibilities. The time evolutions were calculated for the particle concentration in the narrow channel of the spiral arrangement placed in the magnetic field. The field is produced by the highly magnetized high-temperature superconducting bulk magnet. The numerical results show the flow velocity difference of the particle transport corresponding to the difference in the magnetic susceptibility, as well as the possible separation of paramagnetic particles of 20 nm diameter.

  13. Removal of Cryptosporidium sized particle under different filtration temperature, flow rate and alum dosing

    Institute of Scientific and Technical Information of China (English)

    XU Guo-ren; Fitzpatrick S. B. Caroline; Gregory John; DENG Lin-yu


    Recent Cryptosporidium outbreaks have highlighted concerns about filter efficiency and in particular particle breakthrough. It is essential to ascertain the causes of Cryptosporidium sized particle breakthrough for Cryptosporidium cannot be destroyed by conventional chlorine disinfection. This research tried to investigate the influence of temperature, flow rate and chemical dosing on particle breakthrough during filtration. The results showed that higher temperatures and coagulant doses could reduce particle breakthrough. The increase of filtration rate made the residual particle counts become larger. There was an optimal dose in filtration and was well correlated to ζ potential.

  14. Prediction of flow stresses at high temperatures with artificial neural networks

    Institute of Scientific and Technical Information of China (English)

    汪凌云; 郑廷顺; 刘雪峰; 黄光杰


    On the basis of the data obtained on Gleeble-1500 Thermal Simulator, the predicting models for the relation between stable flow stress during high temperature plastic deformation and deformation strain, strain rate and temperature for 1420 Al-Li alloy have been developed with BP artificial neural networks method. The results show that the model on basis of BPNN is practical and it reflects the actual feature of the deforming process. It states that the difference between the actual value and the output of the model is in order of 5%.

  15. Temperature Field of Turbulent Flow in a Well with Account for the Dependence of Thermal Conductivity Coefficient on Temperature (United States)

    Filippov, A. I.; Shabarov, A. B.; Akhmetova, O. V.


    A method of solving the problem on nonstationary heat transfer of turbulent flow with variable coefficients and nonlinearity caused by the dependence of the thermal conductivity of oil on temperature is considered. The method consists of the joint application of the asymptotic methods of small and formal parameters. Based on the analysis of experimental data on the dependence of the thermal conductivity coefficient on temperature, it is shown that this dependence can be presented by a linear function in the form of the Taylor series containing the small parameter. The expansion of the problem in the small parameter leads to a linear problem in zero approximation that can be solved by using the asymptotic method of formal parameter. To determine the first coefficient of the expansion in the small parameter, a unique procedure of uncoupling has been developed. Analytical dependences of temperature in a well and in the surrounding rocks on time and spatial coordinates have been found that account for the orthotropy of the thermophysical properties of the media.

  16. DSMC method on aerodynamic heating and temperature characteristic of hypersonic rarefied flows (United States)

    Ma, Jing; Bao, Xingdong; Mao, Hongxia; Dong, Yanbing


    Aerodynamic heating is one of important factors affecting hypersonic aircraft design. The Direct Simulation Monte Carlo method (DSMC) has evolved years into a powerful numerical technique for the computation of complex, non-equilibrium gas flows. In atmospheric target, non-equilibrium conditions occur at high altitude and in regions of flow fields with small length scales. In this paper, the theoretical basis of the DSMC technique is discussed. In addition, the methods used in DSMC are described for simulation of high temperature, real gas effects and gas-surface interactions. Combined with the solution of heat transfer in material, heat-flux distribution and temperature distribution of the different shape structures was calculated in rarefied conditions.

  17. Transport coefficients and heat fluxes in non-equilibrium high-temperature flows with electronic excitation (United States)

    Istomin, V. A.; Kustova, E. V.


    The influence of electronic excitation on transport processes in non-equilibrium high-temperature ionized mixture flows is studied. Two five-component mixtures, N 2 / N2 + / N / N + / e - and O 2 / O2 + / O / O + / e - , are considered taking into account the electronic degrees of freedom for atomic species as well as the rotational-vibrational-electronic degrees of freedom for molecular species, both neutral and ionized. Using the modified Chapman-Enskog method, the transport coefficients (thermal conductivity, shear viscosity and bulk viscosity, diffusion and thermal diffusion) are calculated in the temperature range 500-50 000 K. Thermal conductivity and bulk viscosity coefficients are strongly affected by electronic states, especially for neutral atomic species. Shear viscosity, diffusion, and thermal diffusion coefficients are not sensible to electronic excitation if the size of excited states is assumed to be constant. The limits of applicability for the Stokes relation are discussed; at high temperatures, this relation is violated not only for molecular species but also for electronically excited atomic gases. Two test cases of strongly non-equilibrium flows behind plane shock waves corresponding to the spacecraft re-entry (Hermes and Fire II) are simulated numerically. Fluid-dynamic variables and heat fluxes are evaluated in gases with electronic excitation. In inviscid flows without chemical-radiative coupling, the flow-field is weakly affected by electronic states; however, in viscous flows, their influence can be more important, in particular, on the convective heat flux. The contribution of different dissipative processes to the heat transfer is evaluated as well as the effect of reaction rate coefficients. The competition of diffusion and heat conduction processes reduces the overall effect of electronic excitation on the convective heating, especially for the Fire II test case. It is shown that reliable models of chemical reaction rates are of great

  18. Numerical Simulation of Temperature Distribution and Material Flow During Friction Stir Welding 2017A Aluminum Alloys

    Directory of Open Access Journals (Sweden)

    Mimouni Oussama


    Full Text Available This study describes the use of fluid dynamic code, FLUENT to model the flow of metal in the AA2017A case around the welding tool pin (FSW. A standard threaded tool profile is used for the analysis of phenomena during welding such as heat generation and flow of the material are included. The main objective is to gain a better understanding of the flow of material around a tool. The model showed a large number of phenomena similar to those of the real process. The model has also generated a sufficient amount of heat, which leads to a good estimate of the junction temperature. These results were obtained using a viscosity which is near the solidus softening.

  19. Temperatures and Heat Flows in a Soil Enclosing a Slinky Horizontal Heat Exchanger

    Directory of Open Access Journals (Sweden)

    Pavel Neuberger


    Full Text Available Temperature changes and heat flows in soils that host “slinky”-type horizontal heat exchangers are complex, but need to be understood if robust quantification of the thermal energy available to a ground-source heat pump is to be achieved. Of particular interest is the capacity of the thermal energy content of the soil to regenerate when the heat exchangers are not operating. Analysis of specific heat flows and the specific thermal energy regime within the soil, including that captured by the heat-exchangers, has been characterised by meticulous measurements. These reveal that high concentrations of antifreeze mix in the heat-transfer fluid of the heat exchanger have an adverse impact on heat flows discharged into the soil.

  20. Film Thickness and Flow Properties of Resin-Based Cements at Different Temperatures

    Directory of Open Access Journals (Sweden)

    Bagheri R.


    Full Text Available Statement of Problem: For a luting agent to allow complete seating of prosthetic restorations, it must obtain an appropriate flow rate maintaining a minimum film thickness. The performance of recently introduced luting agents in this regard has not been evaluated. Purpose: To measure and compare the film thickness and flow properties of seven resin-containing luting cements at different temperatures (37°C, 25°C and10°C. Material and Methods: Specimens were prepared from five resin luting cements; seT (SDI, Panavia F (Kuraray, Varioloink II (Ivoclar, Maxcem (Kerr, Nexus2 (Kerr and two resin-modified glass-ionomer luting cements (RM-GICs; GC Fuji Plus (GC Corporation, and RelyX Luting 2 (3 M/ESPE. The film thickness and flow rate of each cement (n=15 was determined using the test described in ISO at three different temperatures. Results: There was a linear correlation between film thickness and flow rate for most of the materials. Cooling increased fluidity of almost all materials while the effect of temperature on film thickness was material dependent. At 37°C, all products revealed a film thickness of less than 25µm except for GC Fuji Plus. At 25°C, all cements pro-duced a film thickness of less than 27 µm except for seT. At 10°C, apart from seT and Rely X Luting 2, the remaining cements showed a film thickness smaller than 20 µm.Conclusion: Cooling increased fluidity of almost all materials, however. the film thickness did not exceed 35 µm in either condition, in spite of the lowest film thickness being demonstrated at the lowest temperature.

  1. The decomposition of methyltrichlorosilane: Studies in a high-temperature flow reactor

    Energy Technology Data Exchange (ETDEWEB)

    Allendorf, M.D.; Osterheld, T.H.; Melius, C.F.


    Experimental measurements of the decomposition of methyltrichlorosilane (MTS), a common silicon carbide precursor, in a high-temperature flow reactor are presented. The results indicate that methane and hydrogen chloride are major products of the decomposition. No chlorinated silane products were observed. Hydrogen carrier gas was found to increase the rate of MTS decomposition. The observations suggest a radical-chain mechanism for the decomposition. The implications for silicon carbide chemical vapor deposition are discussed.

  2. Agglomeration in Stripper Ash Coolers and Its Possible Remedial Solutions: a Case Study (United States)

    Singh, Ravi Inder


    The bottom ash of circulating fluidized bed (CFB) boiler contains large amounts of physical heat. When low quality coals are used in these types of boilers, the ash content is normally more than 40 % and the physical heat loss is approximately 3 % if the bottom ash is discharged without cooling. Bottom ash cooler (BAC) is often used to treat the high temperature bottom ash to reclaim heat, and to facilitate the easily handling and transportation of ash. The CFB boiler at BLA Power, Newari, MP (India) is facing problems of clinker formation in strip ash coolers of plant since the installation of unit. These clinkers are basically agglomerates, which leads to defluidization of stripper ash cooler (BAC) units. There are two strip ash coolers in unit. Each strip ash cooler is capable of working independently. The proper functioning of both strip coolers is very important as it is going to increase the combustion efficiency of boiler by stripping of fine unburnt coal particles from ash, which are injected into the furnace. In this paper causes, characterization of agglomerates, thermo gravimetric analysis of fuel used, particular size distribution of coal and sand and possible remedial solution to overcome these agglomerates in strip ash coolers has also been presented. High temperature in compact separators, non uniform supply of coal and not removing small agglomerates from stripper ash cooler are among main causes of agglomeration in stripper ash cooler. Control of compact separator temperature, replacing 10-12 % of bed material and cleaning stripper ash cooler periodically will decrease agglomeration in stripper ash cooler of unit.

  3. Modelling of semi-liquid aluminium flow in extrusion with temperature effect

    Directory of Open Access Journals (Sweden)

    G. Skorulski


    Full Text Available material remains stiff and holds its shape so it can be readily handled, but rapidly thins and flows like a liquid when sheared. It is this behaviour that is the key to the thixoforming process where material flows as a semi-liquid slurry into a die, as in conventional die-casting. Modelling the influence of the temperature distribution heterogeneity on deformation mechanisms during extrusion of the aluminium alloys in semi - liquid phase, the way of preparing samples and experimental technique has been analysed in the following work. There were made an analysis on the influence of the possible temperature distribution in recipient obtained during heating it on the extrusion process proceedings. The conclusions concerning stability of the process and appearing during it deformation mechanisms had been drawn on the ground of the received results. The plasticine and rape oil have been choosen as a substitute materials. Some kind of different variants have been investigated used a special experimental stand. The results of the tests presented below prove that the proposed technique can provide valuable insight into the material flow during deformation of aluminium alloys in the semi-liquid state and thus can give some guidance concerning the desirable temperature distribution within the workpiece.

  4. Prediction of Air Flow and Temperature Profiles Inside Convective Solar Dryer

    Directory of Open Access Journals (Sweden)

    Marian Vintilă


    Full Text Available Solar tray drying is an effective alternative for post-harvest processing of fruits and vegetables. Product quality and uniformity of the desired final moisture content are affected by the uneven air flow and temperature distribution inside the drying chamber. The purpose of this study is to numerically evaluate the operation parameters of a new indirect solar dryer having an appropriate design based on thermal uniformity inside the drying chamber, low construction costs and easy accessibility to resources needed for manufacture. The research was focused on both the investigation of different operation conditions and analysis of the influence of the damper position, which is incorporated into the chimney, on the internal cabinet temperature and air flow distribution. Numerical simulation was carried out with Comsol Multiphysics CFD commercial code using a reduced 2D domain model by neglecting any end effects from the side walls. The analysis of the coupled thermal-fluid model provided the velocity field, pressure distribution and temperature distribution in the solar collector and in the drying chamber when the damper was totally closed, half open and fully open and for different operation conditions. The predicted results were compared with measurements taken in-situ. With progressing computing power, it is conceivable that CFD will continue to provide explanations for more fluid flow, heat and mass transfer phenomena, leading to better equipment design and process control for the food industry.

  5. Temperature measurements with two different IR sensors in a continuous-flow microwave heated system. (United States)

    Rydfjord, Jonas; Svensson, Fredrik; Fagrell, Magnus; Sävmarker, Jonas; Thulin, Måns; Larhed, Mats


    In a continuous-flow system equipped with a nonresonant microwave applicator we have investigated how to best assess the actual temperature of microwave heated organic solvents with different characteristics. This is non-trivial as the electromagnetic field will influence most traditional methods of temperature measurement. Thus, we used a microwave transparent fiber optic probe, capable of measuring the temperature inside the reactor, and investigated two different IR sensors as non-contact alternatives to the internal probe. IR sensor 1 measures the temperature on the outside of the reactor whilst IR sensor 2 is designed to measure the temperature of the fluid through the borosilicate glass that constitutes the reactor wall. We have also, in addition to the characterization of the before mentioned IR sensors, developed statistical models to correlate the IR sensor reading to a correct value of the inner temperature (as determined by the internal fiber optic probe), thereby providing a non-contact, indirect, temperature assessment of the heated solvent. The accuracy achieved with these models lie well within the range desired for most synthetic chemistry applications.

  6. Effect of Coal Properties and Operation Conditions on Flow Behavior of Coal Slag in Entrained Flow Gasifiers: A Brief Review

    Energy Technology Data Exchange (ETDEWEB)

    Wang,Ping; Massoudi, Mehrdad


    Integrated gasification combined cycle (IGCC) is a potentially promising clean technology with an inherent advantage of low emissions, since the process removes contaminants before combustion instead of from flue gas after combustion, as in a conventional coal steam plant. In addition, IGCC has potential for cost-effective carbon dioxide capture. Availability and high capital costs are the main challenges to making IGCC technology more competitive and fully commercial. Experiences from demonstrated IGCC plants show that, in the gasification system, low availability is largely due to slag buildup in the gasifier and fouling in the syngas cooler downstream of the gasification system. In the entrained flow gasifiers used in IGCC plants, the majority of mineral matter transforms to liquid slag on the wall of the gasifier and flows out the bottom. However, a small fraction of the mineral matter (as fly ash) is entrained with the raw syngas out of the gasifier to downstream processing. This molten/sticky fly ash could cause fouling of the syngas cooler. Therefore, it is preferable to minimize the quantity of fly ash and maximize slag. In addition, the hot raw syngas is cooled to convert any entrained molten fly slag to hardened solid fly ash prior to entering the syngas cooler. To improve gasification availability through better design and operation of the gasification process, better understanding of slag behavior and characteristics of the slagging process are needed. Slagging behavior is affected by char/ash properties, gas compositions in the gasifier, the gasifier wall structure, fluid dynamics, and plant operating conditions (mainly temperature and oxygen/carbon ratio). The viscosity of the slag is used to characterize the behavior of the slag flow and is the dominating factor to determine the probability that ash particles will stick. Slag viscosity strongly depends on the temperature and chemical composition of the slag. Because coal has varying ash content and

  7. Deposition and immersion-mode nucleation of ice by three distinct samples of volcanic ash (United States)

    Schill, G. P.; Genareau, K.; Tolbert, M. A.


    Ice nucleation of volcanic ash controls both ash aggregation and cloud glaciation, which affect atmospheric transport and global climate. Previously, it has been suggested that there is one characteristic ice nucleation efficiency for all volcanic ash, regardless of its composition, when accounting for surface area; however, this claim is derived from data from only two volcanic eruptions. In this work, we have studied the depositional and immersion freezing efficiency of three distinct samples of volcanic ash using Raman microscopy coupled to an environmental cell. Ash from the Fuego (basaltic ash, Guatemala), Soufrière Hills (andesitic ash, Montserrat), and Taupo (Oruanui eruption, rhyolitic ash, New Zealand) volcanoes were chosen to represent different geographical locations and silica content. All ash samples were quantitatively analyzed for both percent crystallinity and mineralogy using X-ray diffraction. In the present study, we find that all three samples of volcanic ash are excellent depositional ice nuclei, nucleating ice from 225 to 235 K at ice saturation ratios of 1.05 ± 0.01, comparable to the mineral dust proxy kaolinite. Since depositional ice nucleation will be more important at colder temperatures, fine volcanic ash may represent a global source of cold-cloud ice nuclei. For immersion freezing relevant to mixed-phase clouds, however, only the Oruanui ash exhibited appreciable heterogeneous ice nucleation activity. Similar to recent studies on mineral dust, we suggest that the mineralogy of volcanic ash may dictate its ice nucleation activity in the immersion mode.

  8. Effects of gas temperature on nozzle damping experiments on cold-flow rocket motors (United States)

    Sun, Bing-bing; Li, Shi-peng; Su, Wan-xing; Li, Jun-wei; Wang, Ning-fei


    In order to explore the impact of gas temperature on the nozzle damping characteristics of solid rocket motor, numerical simulations were carried out by an experimental motor in Naval Ordnance Test Station of China Lake in California. Using the pulse decay method, different cases were numerically studied via Fluent along with UDF (User Defined Functions). Firstly, mesh sensitivity analysis and monitor position-independent analysis were carried out for the computer code validation. Then, the numerical method was further validated by comparing the calculated results and experimental data. Finally, the effects of gas temperature on the nozzle damping characteristics were studied in this paper. The results indicated that the gas temperature had cooperative effects on the nozzle damping and there had great differences between cold flow and hot fire test. By discussion and analysis, it was found that the changing of mainstream velocity and the natural acoustic frequency resulted from gas temperature were the key factors that affected the nozzle damping, while the alteration of the mean pressure had little effect. Thus, the high pressure condition could be replaced by low pressure to reduce the difficulty of the test. Finally, the relation of the coefficients "alpha" between the cold flow and hot fire was got.

  9. Minimizing ultraviolet noise due to mis-matches between detector flow cell and post column mobile phase temperatures in supercritical fluid chromatography: effect of flow cell design. (United States)

    Berger, Terry A


    A mis-match between the post-column mobile phase temperature and the UV detector flow cell temperature can cause significant UV noise in supercritical fluid chromatography (SFC). Deviations as little as 5 °C can increase noise as much as 5 times, making the detector unsuited for trace analysis. Two approaches were used to minimize this noise. When a flow cell was in direct thermal contact (metal on metal) with the detector optical bench, the mobile phase temperature was actively controlled to the measured flow cell temperature, by using one of the heat exchangers (HX) in the column compartment. However, with some older, but still widely used flow cell designs, this required repeated, hourly monitoring of the flow cell temperature and repeated manual adjustment of the heat exchanger temperature, due to thermal drift. Flow cell design had a strong influence on susceptibility to this thermally induced noise. Thermally insulating the flow cell from the optical bench made some cells much less susceptible to such thermally induced noise. Five different flow cells, some insulated, some un-insulated, were evaluated. Most had a truncated conical flow path, but one had a cylindrical flow path. Using either approach, the ASTM noise, with a 10mm, 13 μL conical flow cell, could be optimized to ≈0.007 mAU at 2.5 Hz, in SFC, which is very near the 0.006 mAU manufacturer's specification for HPLC. The insulated version of this flow cell required far less optimization, compared to the un-insulated version. At 150 bar, an experimental 3mm, 2 μL flow cell, with only one side insulated, yielded noise slightly too high (≈0.16-0.18 mAU) for trace analysis, at 80 Hz. However, at 200 bar, noise at 80 Hz was noise ratio (S/N) >10. Even partially un-insulated, this flow cell design was much less susceptible to thermally induced noise. Further insulating this flow cell design failed to improve performance.

  10. Effect of particle volume fraction on the settling velocity of volcanic ash particles: implications for ash dispersion models (United States)

    Del Bello, E.; Taddeucci, J.; De'Michieli Vitturi, M.; Scarlato, P.; Andronico, D.; Scollo, S.; Kueppers, U.


    We present the first report of experimental measurements of the enhanced settling velocity of volcanic particles as function of particle volume fraction. In order to investigate the differences in the aerodynamic behavior of ash particles when settling individually or in mass, we performed systematic large-scale ash settling experiments using natural basaltic and phonolitic ash. By releasing ash particles at different, controlled volumetric flow rates, in an unconstrained open space and at minimal air movement, we measured their terminal velocity, size, and particle volume fraction with a high-speed camera at 2000 fps. Enhanced settling velocities of individual particles increase with increasing particle volume fraction. This suggests that particle clustering during fallout may be one reason explaining larger than theoretical depletion rates of fine particles from volcanic ash clouds. We provide a quantitative empirical model that allows to calculate, from a given particle size and density, the enhanced velocity resulting from a given particle volume fraction. The proposed model has the potential to serve as a simple tool for the prediction of the terminal velocity of ash of an hypothetical distribution of ash of known particle size and volume fraction. This is of particular importance for advection-diffusion transport model of ash where generally a one-way coupling is adopted, considering only the flow effects on particles. To better quantify the importance of the enhanced settling velocity in ash dispersal, we finally introduced the new formulation in a Lagrangian model calculating for realistic eruptive conditions the resulting ash concentration in the atmosphere and on the ground.

  11. Fire severity effects on ash extractable Total Phosphorous (United States)

    Pereira, Paulo; Úbeda, Xavier; Martin, Deborah


    Phosphorous (P) is a crucial element to plant nutrition and limits vegetal production. The amounts of P in soil are lower and great part of this nutrient is absorbed or precipitated. It is well known that fire has important implications on P cycle, that can be lost throughout volatilization, evacuated with the smoke, but also more available to transport after organic matter mineralization imposed by the fire. The release of P depends on ash pH and their chemical and physical characteristics. Fire temperatures impose different severities, according to the specie affected and contact time. Fire severity is often evaluated by ash colour and this is a low-cost and excellent methodology to assess the fire effects on ecosystems. The aim of this work is study the ash properties physical and chemical properties on ash extractable Total Phosphorous (TP), collected in three wildfires, occured in Portugal, (named, (1) Quinta do Conde, (2) Quinta da Areia and (3) Casal do Sapo) composed mainly by Quercus suber and Pinus pinaster trees. The ash colour was assessed using the Munsell color chart. From all three plots we analyzed a total of 102 ash samples and we identified 5 different ash colours, ordered in an increasing order of severity, Very Dark Brown, Black, Dark Grey, Very Dark Grey and Light Grey. In order to observe significant differences between extractable TP and ash colours, we applied an ANOVA One Way test, and considered the differences significant at a p<0.05. The results showed that significant differences in the extractable TP among the different ash colours. Hence, to identify specific differences between each ash colour, we applied a post-hoc Fisher LSD test, significant at a p<0.05. The results obtained showed significant differences between the extractable TP from Very dark Brown and Black ash, produced at lower severities, in relation to Dark Grey, Very Dark Grey and Light Grey ash, generated at higher severities. The means of the first group were higher

  12. CFD analysis of moderator flow and temperature fields inside a vertical calandria vessel of nuclear reactor

    Energy Technology Data Exchange (ETDEWEB)

    Kansal, Anuj Kumar, E-mail: [Bhabha Atomic Research Centre, Trombay, Mumbai 400085 (India); Joshi, Jyeshtharaj B., E-mail: [Homi Bhabha National Institute, Anushaktinagar, Mumbai 400094 (India); Maheshwari, Naresh Kumar, E-mail: [Bhabha Atomic Research Centre, Trombay, Mumbai 400085 (India); Vijayan, Pallippattu Krishnan, E-mail: [Bhabha Atomic Research Centre, Trombay, Mumbai 400085 (India)


    Highlights: • 3D CFD of vertical calandria vessel. • Spatial distribution of volumetric heat generation. • Effect of Archimedes number. • Non-dimensional analysis. - Abstract: Three dimensional computational fluid dynamics (CFD) analysis has been performed for the moderator flow and temperature fields inside a vertical calandria vessel of nuclear reactor under normal operating condition using OpenFOAM CFD code. OpenFOAM is validated by comparing the predicted results with the experimental data available in literature. CFD model includes the calandria vessel, calandria tubes, inlet header and outlet header. Analysis has been performed for the cases of uniform and spatial distribution of volumetric heat generation. Studies show that the maximum temperature in moderator is lower in the case of spatial distribution of heat generation as compared to that in the uniform heat generation in calandria. In addition, the effect of Archimedes number on maximum and average moderator temperature was investigated.

  13. MAT 126 ASH Course Tutorial / Tutorialoutlet




    For more course tutorials visit   MAT 126 Week 1 DQ 1 (Ash) MAT 126 Week 1 Quiz (Ash) MAT 126 Week 1 Written Assignment (Arithmetic and geometric sequence) (Ash) MAT 126 Week 2 DQ 1 (Ash) MAT 126 Week 2 DQ 2 (Ash) MAT 126 Week 2 Assignment Is It Fat Free (Ash) MAT 126 Week 2 Quiz (Ash) MAT 126 Week 3 DQ 1 (Ash) MAT 126 Week 3 DQ 2 (Ash) MAT 126 Week 3 Assignment Quadratic Equations (Ash) MAT 126 Week 3 Quiz (Ash) MAT 126...

  14. Fluidization characteristics of power-plant fly ashes and fly ash-charcoal mixtures. [MS Thesis; 40 references

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, C.T.


    As a part of the continuing research on aluminum recovery from fly ash by HiChlor process, a plexiglass fluidization column system was constructed for measurement of fluidization parameters for power-plant fly ashes and fly ash-charcoal mixtures. Several bituminous and subbituminous coal fly ashes were tested and large differences in fluidization characteristics were observed. Fly ashes which were mechanically collected fluidized uniformly at low gas flow rates. Most fly ashes which were electrostatically precipitated exhibited channeling tendency and did not fluidize uniformly. Fluidization characteristics of electrostatically collected ashes improve when the finely divided charcoal powder is added to the mixture. The fluidization of the mixture was aided initially by a mechanical stirrer. Once the fluidization had succeeded, the beds were ready to fluidize without the assistance of a mechanical action. Smooth fluidization and large bed expansion were usually observed. The effects of charcoal size and aspect ratio on fluidization characteristics of the mixtures were also investigated. Fluidization characteristics of a fly ash-coal mixture were tested. The mixture fluidized only after being oven-dried for a few days.

  15. Synthesis and characterization of fly ash-zinc oxide nanocomposite

    Directory of Open Access Journals (Sweden)

    Kunal Yeole


    Full Text Available Fly ash, generated in thermal power plants, is recognized as an environmental pollutant. Thus, measures are required to be undertaken to dispose it in an environmentally friendly method. In this paper an attempt is made to coat zinc oxide nano-particles on the surface of fly ash by a simple and environmentally friendly facile chemical method, at room temperature. Zinc oxide may serve as effective corrosion inhibitor by providing sacrificial protection. Concentration of fly ash was varied as 5, 10 and 15 (w/w % of zinc oxide. It was found that crystallinity increased, whereas particle size, specific gravity and oil absorption value decreased with increased concentration of fly ash in zinc oxide, which is attributed to the uniform distribution of zinc oxide on the surface of fly ash. These nanocomposites can potentially be used in commercial applications as additive for anticorrosion coatings.

  16. Extraction of vanadium from athabasca tar sands fly ash (United States)

    Gomez-Bueno, C. O.; Spink, D. R.; Rempel, G. L.


    The production of refinery grade oil from the Alberta tar sands deposits as currently practiced by Suncor (formally Great Canadian Oil Sands Ltd.—GCOS) generates a substantial amount of petroleum coke fly ash which contains appreciable amounts of valuable metals such as vanadium, nickel and titanium. Although the recovery of vanadium from petroleum ash is a well established commercial practice, it is shown in the present work that such processes are not suitable for recovery of vanadium from the GCOS fly ash. The fact that the GCOS fly ash behaves so differently when compared to other petroleum fly ash is attributed to its high silicon and aluminum contents which tie up the metal values in a silica-alumina matrix. Results of experiments carried out in this investigation indicate that such matrices can be broken down by application of a sodium chloride/water roast of the carbon-free fly ash. Based on results from a series of preliminary studies, a detailed investigation was undertaken in order to define optimum conditions for a vanadium extraction process. The process developed involves a high temperature (875 to 950 °C) roasting of the fly ash in the presence of sodium chloride and water vapor carried out in a rotary screw kiln, followed by dilute sodium hydroxide atmosphereic leaching (98 °C) to solublize about 85 pet of the vanadium originally present in the fly ash. It was found that the salt roasting operation, besides enhancing vanadium recovery, also inhibits silicon dissolution during the subsequent leaching step. The salt roasting treatment is found to improve vanadium recovery significantly when the fly ash is fully oxidized. This is easily achieved by burning off the carbon present in the “as received” fly ash under excess air. The basic leaching used in the new process selectively dissolves vanadium from the roasted ash, leaving nickel and titanium untouched.

  17. Fiber-optic flow sensors for high-temperature environment operation up to 800°C. (United States)

    Chen, Rongzhang; Yan, Aidong; Wang, Qingqing; Chen, Kevin P


    This Letter presents an all-optical high-temperature flow sensor based on hot-wire anemometry. High-attenuation fibers (HAFs) were used as the heating elements. High-temperature-stable regenerated fiber Bragg gratings were inscribed in HAFs and in standard telecom fibers as temperature sensors. Using in-fiber light as both the heating power source and the interrogation light source, regenerative fiber Bragg grating sensors were used to gauge the heat transfer from an optically powered heating element induced by the gas flow. Reliable gas flow measurements were demonstrated between 0.066  m/s and 0.66  m/s from the room temperature to 800°C. This Letter presents a compact, low-cost, and multiflexible approach to measure gas flow for high-temperature harsh environments.

  18. Preliminary studies of coolant by-pass flows in a prismatic very high temperature reactor using computational fluid dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Hiroyuki Sato; Richard Johnson; Richard Schultz


    Three dimensional computational fluid dynamic (CFD) calculations of a typical prismatic very high temperature gas-cooled reactor (VHTR) were conducted to investigate the influence of gap geometry on flow and temperature distributions in the reactor core using commercial CFD code FLUENT. Parametric calculations changing the gap width in a whole core length model of fuel and reflector columns were performed. The simulations show the effects of core by-pass flows in the heated core region by comparing results for several gap widths including zero gap width. The calculation results underline the importance of considering inter-column gap width for the evaluation of maximum fuel temperatures and temperature gradients in fuel blocks. In addition, it is shown that temperatures of core outlet flow from gaps and channels are strongly affected by the gap width of by-pass flow in the reactor core.

  19. Generation of volcanic ash: a textural study of ash produced in various laboratory experiments (United States)

    Lavallée, Yan; Kueppers, Ulrich; Dingwell, Donald B.


    In volcanology, ash is commonly understood as a fragment of a bubble wall that gets disrupted during explosive eruptions. Most volcanic ashes are indeed the product of explosive eruptions, but the true definition is however that of a particle size being inferior to 2 mm. The term does not hold any information about its genesis. During fragmentation, particles of all sizes in various amounts are generated. In nature, fragmentation is a brittle response of the material (whether a rock or magma) caused by changes in 1) strain rate and 2) temperature, and/or 3) chemical composition. Here we used different experimental techniques to produce ash and study their physical characteristics. The effects of strain rate were investigated by deforming volcanic rocks and magma (pure silicate melt and crystal-bearing magma) at different temperatures and stresses in a uniaxial compression apparatus. Failure of pure silicate melts is spontaneous and generates more ash particles than fragmentation of crystal-bearing melts. In the latter, the abundance of generated ash correlates positively with the strain rate. We complemented this investigation with a study of particles generated during rapid decompression of porous rocks, using a fragmentation apparatus. Products of decompression experiments at different initial applied pore pressure show that the amount of ash generated by bubble burst increase with the initial applied pressure and the open porosity. The effects of temperature were investigated by dropping pure silicate melts and crystal-bearing magma at 900 and 1100°C in water at room temperature. Quenching of the material is accompanied by rapid contraction and near instantaneous fragmentation. Pure silicate melts respond more violently to the interaction with water and completely fragmented into small particles, including a variety of ash morphologies and surface textures. Crystal-bearing magmas however fragmented only very partially when in contact with water and produced a

  20. Influence of skin temperature on central thermoregulatory control of leg blood flow. (United States)

    Proppe, D W


    This study examined the influence of elevated skin temperature (Tsk) on the central thermoregulatory control of leg blood flow in five unanesthetized, chronically instrumented, resting baboons (Papio anubis and P. cynocephalus). In each experiment, mean iliac blood flow (MIBF), mean arterial blood pressure, arterial blood temperature (Tbl), and Tsk were measured, and iliac vascular conductance (IVC) was calculated. A heat exchanger was incorporated into a chronic arteriovenous femoral shunt to control Tbl. The protocol consisted of raising Tbl approximately 2.6 degrees C in thermoneutral environment (cool Tsk) an then again after Tsk had been elevated by environmental heating. A major influence of raising Tsk was the lowering of threshold Tbl at which the rise in MIBF and IVC commenced. This threshold Tbl was lowered at least 0.8 degrees C on the average. Also, over the whole range of Tbl studied (37.0-39.6 degrees C), MIBF and IVC were higher at high Tsk than at cool Tsk. Thus an elevation of Tsk significantly influences the control of skin blood flow by central thermoreceptors.

  1. CFD Modeling of Flow, Temperature, and Concentration Fields in a Pilot-Scale Rotary Hearth Furnace (United States)

    Liu, Ying; Su, Fu-Yong; Wen, Zhi; Li, Zhi; Yong, Hai-Quan; Feng, Xiao-Hong


    A three-dimensional mathematical model for simulation of flow, temperature, and concentration fields in a pilot-scale rotary hearth furnace (RHF) has been developed using a commercial computational fluid dynamics software, FLUENT. The layer of composite pellets under the hearth is assumed to be a porous media layer with CO source and energy sink calculated by an independent mathematical model. User-defined functions are developed and linked to FLUENT to process the reduction process of the layer of composite pellets. The standard k-ɛ turbulence model in combination with standard wall functions is used for modeling of gas flow. Turbulence-chemistry interaction is taken into account through the eddy-dissipation model. The discrete ordinates model is used for modeling of radiative heat transfer. A comparison is made between the predictions of the present model and the data from a test of the pilot-scale RHF, and a reasonable agreement is found. Finally, flow field, temperature, and CO concentration fields in the furnace are investigated by the model.

  2. Temperature-flow regulation rule in indirect connection heating system and its energy-saving contrast analysis

    Institute of Scientific and Technical Information of China (English)


    Primary and secondary networks are treated as a whole in indirect heating systems, and an advanced new temperature-flow regulation method is presented whose flow ratio is greater than 60% in a secondary network and 30% in a primary network when under a partial load. Through deducing and optimizing an exponential function flow regulation rule, the formulae of flow regulation and the supply and return water temperatures are obtained, and their relevant curves are plotted. After comparison, it is found that this control method has a huge energy conservation space, and it should therefore be generalized soon.

  3. High temperature gradient micro-sensor for wall shear stress and flow direction measurements (United States)

    Ghouila-Houri, C.; Claudel, J.; Gerbedoen, J.-C.; Gallas, Q.; Garnier, E.; Merlen, A.; Viard, R.; Talbi, A.; Pernod, P.


    We present an efficient and high-sensitive thermal micro-sensor for near wall flow parameters measurements. By combining substrate-free wire structure and mechanical support using silicon oxide micro-bridges, the sensor achieves a high temperature gradient, with wires reaching 1 mm long for only 3 μm wide over a 20 μm deep cavity. Elaborated to reach a compromise solution between conventional hot-films and hot-wire sensors, the sensor presents a high sensitivity to the wall shear stress and to the flow direction. The sensor can be mounted flush to the wall for research studies such as turbulence and near wall shear flow analysis, and for technical applications, such as flow control and separation detection. The fabrication process is CMOS-compatible and allows on-chip integration. The present letter describes the sensor elaboration, design, and micro-fabrication, then the electrical and thermal characterizations, and finally the calibration experiments in a turbulent boundary layer wind tunnel.

  4. Tomography-based observation of sublimation and snow metamorphism under temperature gradient and advective flow

    Directory of Open Access Journals (Sweden)

    P. P. Ebner


    Full Text Available Snow at or close to the surface commonly undergoes temperature gradient metamorphism under advective flow, which alters its microstructure and physical properties. Time-lapse X-ray micro-tomography is applied to investigate the structural dynamics of temperature gradient snow metamorphism exposed to an advective airflow in controlled laboratory conditions. The sublimation of water vapor for saturated air flowing across the snow sample was experimentally determined via variations of the porous ice structure. The results showed that the exothermic gas-to-solid phase change is favorable vis-a-vis the endothermic solid-to-gas phase change, thus leading to more ice deposition than ice sublimation. Sublimation has a marked effect on the structural change of the ice matrix but diffusion of water vapor in the direction of the temperature gradient counteracted the mass transport of advection. Therefore, the total net ice change was negligible leading to a constant porosity profile. However, the strong reposition process of water molecules on the ice grains is relevant for atmospheric chemistry.

  5. Pressure, density, temperature and entropy fluctuations in compressible turbulent plane channel flow

    CERN Document Server

    Gerolymos, G A


    We investigate the fluctuations of thermodynamic state-variables in compressible aerodynamic wall-turbulence, using results of direct numerical simulation (DNS) of compressible turbulent plane channel flow. The basic transport equations governing the behaviour of thermodynamic variables (density, pressure, temperature and entropy) are reviewed and used to derive the exact transport equations for the variances and fluxes (transport by the fluctuating velocity field) of the thermodynamic fluctuations. The scaling with Reynolds and Mach number of compressible turbulent plane channel flow is discussed. Correlation coefficients and higher-order statistics of the thermodynamic fluctuations are examined. Finally, detailed budgets of the transport equations for the variances and fluxes of the thermodynamic variables from a well-resolved DNS are analysed. Implications of these results both to the understanding of the thermodynamic interactions in compressible wall-turbulence and to possible improvements in statistical...

  6. Turbulent jet flow generated downstream of a low temperature dielectric barrier atmospheric pressure plasma device (United States)

    Whalley, Richard D.; Walsh, James L.


    Flowing low temperature atmospheric pressure plasma devices have been used in many technological applications ranging from energy efficient combustion through to wound healing and cancer therapy. The generation of the plasma causes a sudden onset of turbulence in the inhomogeneous axisymmetric jet flow downstream of the plasma plume. The mean turbulent velocity fields are shown to be self-similar and independent of the applied voltage used to generate the plasma. It is proposed that the production of turbulence is related to a combination of the small-amplitude plasma induced body forces and gas heating causing perturbations in the unstable shear layers at the jet exit which grow as they move downstream, creating turbulence.

  7. Impact of flows on ion temperatures inferred from neutron spectra produced in NIF DT implosions (United States)

    Gatu Johnson, M.; Frenje, J. A.; Petrasso, R. D.; Knauer, J. P.; Caggiano, J. A.; Callahan, D. A.; Casey, D. T.; Cerjan, C. J.; Doeppner, T.; Eckart, M. J.; Grim, G. P.; Hartouni, E. P.; Hatarik, R.; Hinkel, D. E.; Hurricane, O. A.; Kritcher, A.; Le Pape, S.; Ma, T.; Munro, D. H.; Patel, P.; Ralph, J. E.; Sayre, D. B.; Spears, B. K.; Yeamans, C. B.; Kilkenny, J. D.


    Neutron spectrometers on the NIF provide accurate, directional information of the DT and DD neutron spectra from layered DT implosions. Traditionally, ion temperatures (Tion) , essential for assessing conditions in the hotspot of the implosions, are inferred from the broadening of primary neutron spectra. Directional motion (flow) of the fuel at burn also impacts broadening and may lead to artificially inflated ``Tion'' values. We examine NIF neutron spectra to assess the impact of flows on measured Tion. Measured DT Ti on is consistently higher than measured DD Tion, which suggests that significant energy is lost to radial or turbulent kinetic fuel motion at peak burn. However, explaining the full observed Tion difference with fuel motion, as calculated from a Ballabio and Murphy analysis, leads to a thermal Tion too low to explain observed yields. These results have improved our understanding of hotspot formation and the concept of ``stagnation'' in layered NIF implosions. This work was supported in part by DOE, LLNL and LLE.

  8. Turbulent jet flow generated downstream of a low temperature dielectric barrier atmospheric pressure plasma device. (United States)

    Whalley, Richard D; Walsh, James L


    Flowing low temperature atmospheric pressure plasma devices have been used in many technological applications ranging from energy efficient combustion through to wound healing and cancer therapy. The generation of the plasma causes a sudden onset of turbulence in the inhomogeneous axisymmetric jet flow downstream of the plasma plume. The mean turbulent velocity fields are shown to be self-similar and independent of the applied voltage used to generate the plasma. It is proposed that the production of turbulence is related to a combination of the small-amplitude plasma induced body forces and gas heating causing perturbations in the unstable shear layers at the jet exit which grow as they move downstream, creating turbulence.

  9. Heat-flow and subsurface temperature history at the site of Saraya (eastern Senegal

    Directory of Open Access Journals (Sweden)

    F. Lucazeau


    Full Text Available New temperature measurements from eight boreholes in the West African Craton (WAC reveal superficial perturbations down to 100 m below the alteration zone. These perturbations are both related to a recent increase in the surface air temperature (SAT and to the site effects caused by fluid circulations and/or the lower conduction in the alterites. The ground surface temperature (GST, inverted from the boreholes temperatures, increased slowly in the past (~0.4 °C from 1700 to 1940 and then, more importantly, in recent years (~1.5 °C from 1940 to 2010. This recent trend is consistent with the increase of the SAT recorded at two nearby meteorological stations (Tambacounda and Kedougou, and more generally in the Sahel with a coeval rainfall decrease. Site effects are superimposed to the climatic effect and interpreted by advective (circulation of fluids or conductive (lower conductivity of laterite and of high-porosity sand perturbations. We used a 1-D finite differences thermal model and a Monte-Carlo procedure to find the best estimates of these site perturbations: all the eight borehole temperature logs can be interpreted with the same basal heat-flow and the same surface temperature history, but with some realistic changes of thermal conductivity and/or fluid velocity. The GST trend observed in Senegal can be confirmed by two previous borehole measurements made in 1983 in other locations of West Africa, the first one in an arid zone of northern Mali and the second one in a sub-humid zone in southern Mali. Finally, the background heat-flow is low (31±2 mW m−2, which makes this part of the WAC more similar with the observations in the southern part (33±8 mW m−2 rather than with those in the northern part and in the Pan-African domains where the surface heat-flow is 15–20 mW m−2 higher.

  10. Dating fluid flow in developing passive margins using low-temperature thermochronology (United States)

    Gleadow, A. J.; Seiler, C.; Kohn, B. P.


    Despite the importance of fluid flow for mass flux and remobilisation in the Earth's crust, the age of past fluid flow events is often difficult to determine, particularly in the low-temperature environment of the shallow crust. This is partly because mineral phases precipitated by low-temperature fluids are either lacking or not very easy to date. Low-temperature thermochronometers such as apatite fission track (AFT) and (U-Th)/He (AHe) systems are, in theory, ideally suited to investigate the temperature interval of hydrothermal fluids near the Earth's surface and could be used to date fluid flow in the shallow crust. In passive margins, however, rift-related faulting, exhumation and post-breakup erosion often result in a much stronger regional cooling signal that relates to tectonic events rather than fluid flow. Moreover, the response of low-temperature thermochronometers to transient and potentially short-lived thermal events associated with hydrothermal fluids has not been studied systematically and is poorly known. In this study, we report AFT and AHe results from two young, regionally important faults that were active at different stages of passive margin evolution in the Gulf of California rift system. In the first case, we investigate the thermal history of the Libertad fault in central Baja California, which represents the breakaway fault for Late Miocene to recent rifting. Regional background AFT and AHe ages range between ~60-35Ma, they predate rifting and are likely associated with steady erosional unroofing of the basement. In contrast, a closely spaced 3D grid of samples from the Libertad escarpment records a distinct Late Miocene thermal event at ~9-8Ma that can be traced several kilometres along the base and a few hundred metres up the escarpment face. In the second case, we collected a 2D grid of samples orthogonal to the Ballenas transform, a transform fault located ~3-5km offshore the coast of central Baja California that is part of the current

  11. An Ambient Temperature Molten Sodium-Vanadium Battery with Aqueous Flowing Catholyte. (United States)

    Liu, Caihong; Shamie, Jack S; Shaw, Leon L; Sprenkle, Vincent L


    In this study, we have investigated the key factors dictating the cyclic performance of a new type of hybrid sodium-based flow batteries (HNFBs) that can operate at room temperature with high cell voltages (>3 V), multiple electron transfer redox reactions per active ion, and decoupled design of power and energy. HNFBs are composed of a molten Na-Cs alloy anode, flowing aqueous catholyte, and a Na-β″-Al2O3 solid electrolyte as the separator. The surface functionalization of graphite felt electrodes for the flowing aqueous catholyte has been studied for its effectiveness in enhancing V(2+)/V(3+), V(3+)/V(4+), and V(4+)/V(5+) redox couples. The V(4+)/V(5+) redox reaction has been further investigated at different cell operation temperatures for its cyclic stability and how the properties of the solid electrolyte membrane play a role in cycling. These fundamental understandings provide guidelines for improving the cyclic performance and stability of HNFBs with aqueous catholytes. We show that the HNFB with aqueous V-ion catholyte can reach high storage capacity (∼70% of the theoretical capacity) with good Coulombic efficiency (90% ± 1% in 2-30 cycles) and cyclic performance (>99% capacity retention for 30 cycles). It demonstrates, for the first time, the potential of high capacity HNFBs with aqueous catholytes, good capacity retention and long cycling life. This is also the first demonstration that Na-β″-Al2O3 solid electrolyte can be used with aqueous electrolyte at near room temperature for more than 30 cycles.

  12. The effect of water temperature and flow on respiration in barnacles: patterns of mass transfer versus kinetic limitation. (United States)

    Nishizaki, Michael T; Carrington, Emily


    In aquatic systems, physiological processes such as respiration, photosynthesis and calcification are potentially limited by the exchange of dissolved materials between organisms and their environment. The nature and extent of physiological limitation is, therefore, likely to be dependent on environmental conditions. Here, we assessed the metabolic sensitivity of barnacles under a range of water temperatures and velocities, two factors that influence their distribution. Respiration rates increased in response to changes in temperature and flow, with an interaction where flow had less influence on respiration at low temperatures, and a much larger effect at high temperatures. Model analysis suggested that respiration is mass transfer limited under conditions of low velocity (mass transfer and kinetic limitation are important. Behavioral monitoring revealed that barnacles fully extend their cirral appendages at low flows and display abbreviated 'testing' behaviors at high flows, suggesting some form of mechanical limitation. In low flow-high temperature treatments, however, barnacles displayed distinct 'pumping' behaviors that may serve to increase ventilation. Our results suggest that in slow-moving waters, respiration may become mass transfer limited as temperatures rise, whereas faster flows may serve to ameliorate the effects of elevated temperatures. Moreover, these results underscore the necessity for approaches that evaluate the combined effects of multiple environmental factors when examining physiological and behavioral performance.

  13. Effect of growth temperature on the electron flow for photorespiration in leaves of tobacco grown in the field. (United States)

    Zhang, Wei; Huang, Wei; Yang, Qiu-Yun; Zhang, Shi-Bao; Hu, Hong


    Photorespiration has been indicated as an important mechanism for maintaining CO2 assimilation and alleviating photodamage under conditions of high light and low CO2 . We tested the hypothesis that plants grown under a high temperature had greater electron flow for photorespiration compared with those grown under a relative low temperature. Responses of photosynthetic electron flow and CO2 assimilation to incident light intensity and intercellular CO2 concentration were examined in leaves of tobacco cultivar 'k326'. Plants were cultivated at three sites with different ambient temperatures (Zhengzhou, Zunyi and Jiangchuan). Under high light, plants grown in Zhengzhou (with the highest growth temperature in the three sites) showed higher effective quantum yield of photosystem II and total electron flow through photosystem II than that in Zunyi and Jiangchuan. However, regardless of light intensity and intercellular CO2 status, there were no significant differences among sites in the photosynthetic CO2 assimilation rate or electron flow devoted to the carboxylation of ribulose-1,5-bisphosphate (RuBP). As a result, plants grown at high temperature showed higher electron flow devoted to oxygenation of RuBP than plants grown at low temperature. These results suggested that enhancement of electron flow for photorespiration is an important strategy in tobacco for acclimating to high growth temperature.

  14. Investigation of a zirconia co-fired ceramic calorimetric microsensor for high-temperature flow measurements (United States)

    Lekholm, Ville; Persson, Anders; Klintberg, Lena; Thornell, Greger


    This paper describes the design, fabrication and characterization of a flow sensor for high-temperature, or otherwise aggressive, environments, like, e.g. the propulsion system of a small spacecraft. The sensor was fabricated using 8 mol% yttria stabilized zirconia (YSZ8) high-temperature co-fired ceramic (HTCC) tape and screen printed platinum paste. A calorimetric flow sensor design was used, with five 80 µm wide conductors, separated by 160 µm, in a 0.4 mm wide, 0.1 mm deep and 12.5 mm long flow channel. The central conductor was used as a heater for the sensor, and the two adjacent conductors were used to resistively measure the heat transferred from the heater by forced convection. The two outermost conductors were used to study the influence of an auxiliary heat source on the sensor. The resistances of the sensor conductors were measured using four-point connections, as the gas flow rate was slowly increased from 0 to 40 sccm, with different power supplied through the central heater, as well as with an upstream or downstream heater powered. In this study, the thermal and electrical integrability of microcomponents on the YSZ8 substrate was of particular interest and, hence, the influence of thermal and ionic conduction in the substrate was studied in detail. The effect of the ion conductivity of YSZ8 was studied by measuring the resistance of a platinum conductor and the resistance between two adjacent conductors on YSZ8, in a furnace at temperatures from 20 to 930 °C and by measuring the resistance with increasing current through a conductor. With this design, the influence of ion conductivity through the substrate became apparent above 700 °C. The sensitivity of the sensor was up to 1 mΩ sccm-1 in a range of 0-10 sccm. The results show that the signal from the sensor is influenced by the integrated auxiliary heating conductors and that these auxiliary heaters provide a way to balance disturbing heat sources, e.g. thrusters or other electronics, in

  15. Low cryogen inventory, forced flow Ne cooling system with room temperature compression stage and heat recuperation

    CERN Document Server

    Shornikov, A; Wolf, A


    We present design and commissioning results of a forced flow cooling system utilizing neon at 30 K. The cryogen is pumped through the system by a room-temperature compression stage. To decouple the cold zone from the compression stage a recuperating counterflow tube-in-tube heat exchanger is used. Commissioning demonstrated successful condensation of neon and transfer of up to 30 W cooling power to the load at 30 K using only 30 g of the cryogen circulating in the system at pressures below 170 kPa.

  16. Thin film flow in MHD third grade fluid on a vertical belt with temperature dependent viscosity.

    Directory of Open Access Journals (Sweden)

    Taza Gul

    Full Text Available In this work, we have carried out the influence of temperature dependent viscosity on thin film flow of a magnetohydrodynamic (MHD third grade fluid past a vertical belt. The governing coupled non-linear differential equations with appropriate boundary conditions are solved analytically by using Adomian Decomposition Method (ADM. In order to make comparison, the governing problem has also been solved by using Optimal Homotopy Asymptotic Method (OHAM. The physical characteristics of the problem have been well discussed in graphs for several parameter of interest.

  17. Thin film flow in MHD third grade fluid on a vertical belt with temperature dependent viscosity. (United States)

    Gul, Taza; Islam, Saed; Shah, Rehan Ali; Khan, Ilyas; Shafie, Sharidan


    In this work, we have carried out the influence of temperature dependent viscosity on thin film flow of a magnetohydrodynamic (MHD) third grade fluid past a vertical belt. The governing coupled non-linear differential equations with appropriate boundary conditions are solved analytically by using Adomian Decomposition Method (ADM). In order to make comparison, the governing problem has also been solved by using Optimal Homotopy Asymptotic Method (OHAM). The physical characteristics of the problem have been well discussed in graphs for several parameter of interest.

  18. Cryostabilization of high-temperature superconducting magnets with subcooled flow in microchannels (United States)

    Cha, Y. S.; Hull, J. R.; Choi, U. S.


    Subcooled flow of liquid nitrogen in microchannels is proposed as a means to enhance the stability of a superconducting magnet. Analysis shows high current density or a low stabilizer fraction is obtainable in a cryostable magnet. Increase in stability (using the Stekley criterion) is directly related to coolant velocity and coolant channel aspect ratio, however, there is a corresponding increase in pressure drop of the system. Another constraint is the coolant temperature rise, which is found to be a function of coolant residence time and the coolant to conductor ratio.

  19. A Comparative study Of Catalityc Activity Of Heterogeneous Base Of Banana Stem Ash And Fly Ash On Production Of Biodiesel Byultrasonic

    Directory of Open Access Journals (Sweden)



    Full Text Available Abstract The use of heterogeneous catalysts in the production of biodiesel provides many advantages due to heterogeneous catalysts can be easily separated from the product so that it can be reused. This research using heterogeneous catalysts derived from natural materials namely banana stem ash and coal fly ash containing alkali and alkaline earth elements. The preparation of catalyst from banana stem ash and coal fly ash used activator KOH 1.9 N and impregnation with KNO3 15 and then heated to a temperature of 550 0C for 3 hours. Results of preparation banana stem ash contains potassium of 36.52 and surface area of 41.901 m2g. This work presents the effect of ultrasonic assisted of waste cooking oil with methanol as solvent using banana stem ash and coal fly ash as catalyst. The diameter of catalyst particles of banana stem ash and coal fly ash varied at 50 100 150 200 and 250 mesh. The transesterification reaction was performed in the presence of ultrasonic operating frequency constant at 40 kHz methanol molar ratio to oil of 9 1 and reaction time of 30 minutes. The methyl ester biodiesel content of product was 93.26 of banana stems ash and 57 of coal fly ash respectively. The physical property was compared with the National Indonesia Standard SNI 2006 with a density viscosity cloud point flash point and cetane number.

  20. Theoretical relation between water flow rate in a vertical fracture and rock temperature in the surrounding massif

    CERN Document Server

    Maréchal, Jean-Christophe


    A steady-state analytical solution is given describing the temperature distribution in a homogeneous massif perturbed by cold water flow through a discrete vertical fracture. A relation is derived to express the flow rate in the fracture as a function of the temperature measured in the surrounding rock. These mathematical results can be useful for tunnel drilling as it approaches a vertical cold water bearing structure that induces a thermal anomaly in the surrounding massif. During the tunnel drilling, by monitoring this anomaly along the tunnel axis one can quantify the flow rate in the discontinuity ahead before intersecting the fracture. The cases of the Simplon, Mont Blanc and Gotthard tunnels (Alps) are handled with this approach which shows very good agreement between observed temperatures and the theoretical trend. The flow rates before drilling of the tunnel predicted with the theoretical solution are similar in the Mont Blanc and Simplon cases, as well as the flow rates observed during the drilling....


    Directory of Open Access Journals (Sweden)

    R. Muthucumaraswamy


    Full Text Available An analysis is performed to study the unsteady flow past an exponentially accelerated infinite vertical plate with variable temperature and uniform mass diffusion, in the presence of a homogeneous chemical reaction of first-order. The plate temperature is raised linearly with time and the concentration level near the plate is raised uniformly. The dimensionless governing equations are solved using the Laplace transform. The velocity profiles are studied for different physical parameters such as the chemical reaction parameter, thermal Grashof number, mass Grashof number, a, and time. It is observed that the velocity increases with increasing values of a or t. But the trend is just the reverse in the chemical reaction parameter.

  2. Tensile testing of MANET II in flowing Pb-Bi alloy at elevated temperature

    Energy Technology Data Exchange (ETDEWEB)

    Glasbrenner, H. E-mail:; Viol, D


    Experiments were carried out to study the influence of lead bismuth eutectic (LBE) on the tensile properties of the martensitic CrNiMoVNb steel named MANET II (Martensit for Next European Torus) considered as structural material for the first wall and blanket in fusion reactor conceptual design. In order to investigate a possible liquid metal embrittlement (LME) effect, tensile tests in flowing Pb-Bi at various temperatures (between 180 and 300 deg. C) were carried out. For comparison of the tensile test results achieved in Pb-Bi, tests were also carried out in the same facility but in an Ar atmosphere at the same temperature. After the tests, the fracture faces of the specimens were examined by SEM to analyse the fracture type (brittle or ductile). Additionally the ruptured specimens were longitudinally sectioned and analysed by metallurgical and SEM examinations.

  3. Temperature Impact of Nitrogen Transformation in Technological System: Vertical Flow Constructed Wetland and Polishing Pond (United States)

    Myszograj, Sylwia; Bydałek, Franciszek


    The article describes the results of the research, purpose of which was to evaluate influence of the temperature on the effectiveness of nitrification and denitrification in the sewage treatment system consisting of vertical flow constructed wetland and polishing pond. During the analysed period, the efficiency of removing total nitrogen was low and amounted to 12.7%. In the polishing pond in the summer period, content of total nitrogen in treated sewages was further decreased by nearly 50%. In the winter period, the polishing pond fulfilled mainly retention role and thus did not improve effectiveness of the whole system. Temperature coefficients, calculated on the basis of single first-order kinetics, for nitrification process in the filter bed (N-NH4+) and denitrification process in the polishing pond (N-NO3-) amounted to 1.039 and 1.089, respectively.

  4. Convection in rotating flows with simultaneous imposition of radial and vertical temperature gradients (United States)

    Banerjee, Ayan Kumar; Bhattacharya, Amitabh; Balasubramanian, Sridhar


    Laboratory experiments, with a rotating cylindrical annulus and thermal gradient in both radial and vertical directions (so that radial temperature difference decreases with the elevation), were conducted to study the convection dynamics and heat transport. Temperature data captured using thermocouples, combined with ANSYS Fluent simulation hinted at the co-existence of thermal plume and baroclinicity (inclined isotherms). Presence of columnar plume structure parallel to the rotation axis was found, which had a phase velocity and aided in vertical heat transport. Nusselt number (Nu) plotted as a function of Taylor number (Ta) showed the effect of rotation on heat transport in such systems, where the interplay of plumes and baroclinic waves control the scalar transport. Laser based PIV imaging at a single vertical plane also showed evidence of such flow structures.

  5. Integrated LTCC Pressure/Flow/Temperature Multisensor for Compressed Air Diagnostics†

    Directory of Open Access Journals (Sweden)

    Nicolas Craquelin


    Full Text Available We present a multisensor designed for industrial compressed air diagnostics and combining the measurement of pressure, flow, and temperature, integrated with the corresponding signal conditioning electronics in a single low-temperature co-fired ceramic (LTCC package. The developed sensor may be soldered onto an integrated electro-fluidic platform by using standard surface mount device (SMD technology, e.g., as a standard electronic component would be on a printed circuit board, obviating the need for both wires and tubes and thus paving the road towards low-cost integrated electro-fluidic systems. Several performance aspects of this device are presented and discussed, together with electronics design issues.

  6. Magnetic Resonance Flow Velocity and Temperature Mapping of a Shape Memory Polymer Foam Device

    Energy Technology Data Exchange (ETDEWEB)

    Small IV, W; Gjersing, E; Herberg, J L; Wilson, T S; Maitland, D J


    Interventional medical devices based on thermally responsive shape memory polymer (SMP) are under development to treat stroke victims. The goals of these catheter-delivered devices include re-establishing blood flow in occluded arteries and preventing aneurysm rupture. Because these devices alter the hemodynamics and dissipate thermal energy during the therapeutic procedure, a first step in the device development process is to investigate fluid velocity and temperature changes following device deployment. A laser-heated SMP foam device was deployed in a simplified in vitro vascular model. Magnetic resonance imaging (MRI) techniques were used to assess the fluid dynamics and thermal changes associated with device deployment. Spatial maps of the steady-state fluid velocity and temperature change inside and outside the laser-heated SMP foam device were acquired. Though non-physiological conditions were used in this initial study, the utility of MRI in the development of a thermally-activated SMP foam device has been demonstrated.

  7. Dynamic On-Chip micro Temperature and Flow Sensor for miniaturized lab-on-a-chip instruments Project (United States)

    National Aeronautics and Space Administration — The purpose of this project is to design, fabricate, and characterize a Dynamic On-Chip Flow and Temperature Sensor (DOCFlaTS) to mature and enable miniaturized...

  8. Suspension-firing of wood with coal ash addition: Probe measurements of ash deposit build-up at Avedøre Power Plant (AVV2)

    DEFF Research Database (Denmark)

    Shafique Bashir, Muhammad; Jensen, Peter Arendt; Jappe Frandsen, Flemming;

    This report is about full-scale probe measurements of deposit build-up and removal conducted at the Avedøreværket Unit 2, a 800 MWth suspension boiler, firing wood and natural gas with the addition of coal ash. Coal ash was used as an additive to capture potassium (K) from wood-firing. Investigat......This report is about full-scale probe measurements of deposit build-up and removal conducted at the Avedøreværket Unit 2, a 800 MWth suspension boiler, firing wood and natural gas with the addition of coal ash. Coal ash was used as an additive to capture potassium (K) from wood......-firing. Investigations of deposit formation rate were made by use of an advanced online ash deposition/shedding probe. Quantification of ash deposition and shedding was made via deposit mass uptake signals obtained from the deposit probe. The influence of coal ash, flue gas temperature, probe surface temperature...... and boiler load on ash deposition propensity was investigated. Results of ash deposition propensity showed increasing trend with increasing flue gas temperature. Video monitoring revealed that the deposits formed were not sticky and could be easily removed, and even at very high flue gas temperatures (> 1350...

  9. Experimental study of forced convection heat transfer during upward and downward flow of helium at high pressure and high temperature

    Energy Technology Data Exchange (ETDEWEB)

    Francisco Valentin; Narbeh Artoun; Masahiro Kawaji; Donald M. McEligot


    Fundamental high pressure/high temperature forced convection experiments have been conducted in support of the development of a Very High Temperature Reactor (VHTR) with a prismatic core. The experiments utilize a high temperature/high pressure gas flow test facility constructed for forced convection and natural circulation experiments. The test section has a single 16.8 mm ID flow channel in a 2.7 m long, 108 mm OD graphite column with four 2.3kW electric heater rods placed symmetrically around the flow channel. This experimental study presents the role of buoyancy forces in enhancing or reducing convection heat transfer for helium at high pressures up to 70 bar and high temperatures up to 873 degrees K. Wall temperatures have been compared among 10 cases covering the inlet Re numbers ranging from 500 to 3,000. Downward flows display higher and lower wall temperatures in the upstream and downstream regions, respectively, than the upward flow cases due to the influence of buoyancy forces. In the entrance region, convection heat transfer is reduced due to buoyancy leading to higher wall temperatures, while in the downstream region, buoyancyinduced mixing causes higher convection heat transfer and lower wall temperatures. However, their influences are reduced as the Reynolds number increases. This experimental study is of specific interest to VHTR design and validation of safety analysis codes.

  10. Estimation of Volcanic Ash Plume Top Height using AATSR (United States)

    Virtanen, Timo; Kolmonen, Pekka; Sogacheva, Larisa; Sundström, Anu-Maija; Rodriguez, Edith; de Leeuw, Gerrit


    The AATSR Correlation Method (ACM) height estimation algorithm is presented. The algorithm uses Advanced Along Track Scanning Radiometer (AATSR) satellite data to detect volcanic ash plumes and to estimate the plume top height. The height estimate is based on the stereo-viewing capability of the AATSR instrument, which allows to determine the parallax between the satellite's 55° forward and nadir views, and thus the corresponding height. Besides the stereo view, AATSR provides another advantage compared to other satellite based instruments. With AATSR it is possible to detect ash plumes using brightness temperature difference between thermal infrared (TIR) channels centered at 11 and 12 µm. The automatic ash detection makes the algorithm efficient in processing large quantities of data: the height estimate is calculated only for the ash-flagged pixels. In addition, it is possible to study the effect of using different wavelengths in the height estimate, ranging from visible (555 nm) to thermal infrared (12 µm). The ACM algorithm can be applied to the Sea and Land Surface Temperature Radiometer (SLSTR), scheduled for launch at the end of 2015. Accurate information on the volcanic ash position is important for air traffic safety. The ACM algorithm can provide valuable data of both horizontal and vertical ash dispersion. These data may be useful for comparisons with existing volcanic ash dispersion models and retrieval methods. We present ACM plume top height estimate results for the Eyjafjallajökull eruption, and comparisons against available ground based and satellite observations.

  11. MGT 330 ASH Course Tutorial / Tutorialoutlet




    For more course tutorials visit   MGT 330 Week 1 Individual Assignment Functions of Management Paper (Ash) MGT 330 Week 1 DQ 1 (Ash) MGT 330 Week 1 DQ 2 (Ash) MGT 330 Week 1 DQ 3 (Ash) MGT 330 Week 1 Summary (Ash) MGT 330 Week 2 Team Assignment External Internal Factors Paper (Ash) MGT 330 Week 2 Individual Assignment Delegation (Ash) MGT 330 Week 2 Summary (Ash) MGT 330 Week 2 DQ 1 (Ash) MGT 330 Week 2 DQ 2 (Ash) MGT 330 W...

  12. Biomass-oxygen gasification in a high-temperature entrained-flow gasifier. (United States)

    Zhou, Jinsong; Chen, Qing; Zhao, Hui; Cao, Xiaowei; Mei, Qinfeng; Luo, Zhongyang; Cen, Kefa


    The technology associated with indirect biomass liquefaction is currently arousing increased attention, as it could ensure a supply of transportation fuels and reduce the use of petroleum. The characteristics of biomass-oxygen gasification in a bench-scale laminar entrained-flow gasifier were studied in the paper. Experiments were carried out to investigate the influence of some key factors, including reaction temperature, residence time and oxygen/biomass ratio, on the gasification. The results indicated that higher temperature favored H2 and CO production. Cold gas efficiency was improved by N10% when the temperature was increased from 1000 to 1400 degrees C. The carbon conversion increased and the syngas quality was improved with increasing residence time. A shorter residence resulted in incomplete gasification. An optimal residence time of 1.6 s was identified in this study. The introduction of oxygen to the gasifier strengthened the gasification and improved the carbon conversion, but lowered the lower heating value and the H2/CO ratio of the syngas. The optimal oxygen/biomass ratio in this study was 0.4. The results of this study will help to improve our understanding of syngas production by biomass high-temperature gasification.

  13. Non-Uniformity of the Combustor Exit Flow Temperature in Front of the Gas Turbine

    Directory of Open Access Journals (Sweden)

    Błachnio Józef


    Full Text Available Various types of damages to gas-turbine components, in particular to turbine blades, may occur in the course of gas turbine operation. The paper has been intended to discuss different forms of damages to the blades due to non-uniformity of the exit flow temperature. It has been shown that the overheating of blade material and thermal fatigue are the most common reasons for these damages. The paper presents results from numerical experiments with use of the computer model of the aero jet engine designed for simulations. The model has been purposefully modified to take account of the assumed non-homogeneity of the temperature field within the working agent at the turbine intake. It turned out that such non-homogeneity substantially affects dynamic and static properties of the engine considered as an object of control since it leads to a lag of the acceleration time and to increase in fuel consumption. The summarized simulation results demonstrate that the foregoing properties of a jet engine are subject to considerable deterioration in pace with gradual increase of the assumed non-homogeneity of the temperature field. The simulations made it possible to find out that variations of the temperature field nonhomogeneity within the working agent at the turbine intake lead to huge fluctuation of the turbine rpm for the idle run.

  14. Usage of fly ash as a coal desulphurization reagent

    Energy Technology Data Exchange (ETDEWEB)

    Yaman, S.; Kuecuekbayrak, S. [Istanbul Technical Univ. (Turkey). Chemical and Metallurgical Engineering Faculty


    This paper covers the direct usage of fly ash to remove sulphur from coal. Experiments were carried out on a high sulphur Turkish lignite. 5 g of fly ash was extracted in 200 ml of water under pressure and the dilute solution containing water extractable parts of fly ash was used as desulphurization reagent. Oxygen pressure was created over desulphurization medium during the extraction period by which dissolved oxygen was concentrated in the solution. Effects of temperature, partial pressure of oxygen, and time were investigated in the ranges of 403--498 K, 0.0--1.5 MPa and 15--90 min, respectively.

  15. Results of temperature gradient and heat flow in Santiam Pass Area, Oregon, Volume 1

    Energy Technology Data Exchange (ETDEWEB)

    Cox, B.L.; Gardner, M.C.; Koenig, J.B.


    The conclusions of this report are: (1) There is a weakly defined thermal anomaly within the area examined by temperature-gradient holes in the Santiam Pass area. This is a relict anomaly showing differences in permeability between the High Cascades and Western Cascades areas, more than a fundamental difference in shallow crustal temperatures. (2) The anomaly as defined by the 60 F isotherms at 400 feet follows a north-south trend immediately westward of the Cascade axis in the boundary region. It is clear that all holes spudded into High Cascades rocks result in isothermal and reversal gradients. Holes spudded in Western Cascades rocks result in positive gradients. (3) Cold groundwater flow influences and masks temperature gradients in the High Cascades to a depth of at least 700 feet, especially eastward from the major north-south trending faults. Pleistocene and Holocene rocks are very permeable aquifers. (4) Shallow gradient drilling in the lowlands westward of the faults provides more interpretable information than shallow drilling in the cold-water recharge zones. Topographic and climatological effects can be filtered out of the temperature gradient results. (5) The thermal anomaly seems to have 2 centers: one in the Belknap-Foley area, and one northward in the Sand Mountain area. The anomalies may or may not be connected along a north-south trend. (6) A geothermal effect is seen in holes downslope of the Western-High Cascade boundary. Mixing with cold waters is a powerful influence on temperature gradient data. (7) The temperature-gradient program has not yet examined and defined the geothermal resources potential of the area eastward of the Western Cascades-High Cascades boundary. Holes to 1500-2000 feet in depth are required to penetrate the high permeability-cold groundwater regime. (8) Drilling conditions are unfavorable. There are very few accessible level drill sites. Seasonal access problems and environmental restrictions together with frequent lost

  16. Influence of mineral and chemical composition of coal ashes on their fusibility

    Energy Technology Data Exchange (ETDEWEB)

    Vassilev, S.V.; Kitano, K.; Takeda, S.; Tsurue, T. [Bulgarian Academy of Sciences, Sofia (Bulgaria). Institute of Applied Mineralogy


    The relationships between ash-fusion temperature (AFT) and mineral and chemical composition of coals and coal ashes from a wide variety of deposits (41) were studied by a melting test, X-ray diffractometry, light microscopy, differential-thermal, thermogravimetric and chemical analyses. A reliable explanation and prediction of AFT only from the total chemical composition of coal ash is inadequate because most important are the modes of elemental combination (minerals and phases) in coal and coal ash, as well as their behaviour during heating. The coals, which have low-melting temperature ashes, are lower rank coals with increased concentrations of S, Ca, Mg, Fe and Na and respectively, sulphates, carbonates, sulphides, oxides, montmorillonite, and feldspars. The coals with high-melting temperature ashes have an advanced rank and increased contents of Si, Al and Ti and respectively, quartz, kaolinite, illite and rutile, as well as some Fe oxides and siderite. The behaviour of chemical components and various coal and coal-ash minerals during heating is discussed, and their refractory and fluxing influence on ash fusibility is described. Lower AFT is related to increased proportions of the fluxing sulphate, silicate and oxide minerals such as anhydrite, acid plagioclases, K feldspars, Ca silicates and hematite in high-temperature coal ashes. Higher AFT is a result of decreased fluxing minerals and increased refractory minerals such as quartz, metakaolinite, mullite, and rutile in these ashes. Defined softening, hemispherical and fluid ash-fusion temperatures fit various processes of inorganic transformations which are discussed. A reliable explanation and prediction of ash-fusion characteristics can be made when the coal and coal-ash minerals and their amounts, as well as their refractory and fluxing action during heating, are known. 31 refs., 7 figs., 5 tabs.

  17. Unsteady Hydromagnetic Flow of a Heat Absorbing Dusty Fluid Past a Permeable Vertical Plate with Ramped Temperature

    Directory of Open Access Journals (Sweden)

    m Das


    Full Text Available The unsteady flow and heat transfer of a viscous incompressible, electrically conducting dusty fluid past vertical plate under the influence of a transverse magnetic field is studied with a view to examine the combined effects of suction, heat absorption and ramped wall temperature. The temperature of the wall is assumed to have a temporarily ramped profile which goes on increasing up to a certain time limit and then becomes constant. To investigate the effect of rampedness in wall temperature, the solution for the flow past an isothermal wall is also obtained. The governing partial differential equations are solved using Laplace transformation technique in which the inversion is obtained numerically using Matlab. To validate the results of numerical inversion a comparison between the numerical and analytical values of fluid and particle temperatures and Nusselt number is also presented. The effects of pertinent flow parameters affecting the flow and heat transfer are investigated with the help of graphs and tables. It is found that the increase in suction, heat absorption and particle concentration contribute in thinning the thermal and momentum boundary layers and the velocity and temperature for both the fluid and particle phases are higher in the case of a flow past an isothermal plate than that of a flow past a plate with ramped temperature.

  18. Energy efficiency of a concentration gradient flow battery at elevated temperatures (United States)

    van Egmond, W. J.; Starke, U. K.; Saakes, M.; Buisman, C. J. N.; Hamelers, H. V. M.


    Fast growth of intermittent renewable energy generation introduces a need for large scale electricity storage. The Concentration Gradient Flow Battery (CGFB) is an emerging technology which combines Electrodialysis with Reverse Electrodialysis into a flow battery which is able to safely store very large amounts of energy in environmental friendly NaCl solutions. In this work, (dis)charge efficiency, energy density and power density are both theoretically and experimentally investigated. Fifteen constant current experiments (-47.5 to +37.5 A m-2) are performed at 40 °C and two experiments (-32.5 and 15 A m-2) at 10 and 25 °C. The magnitudes of the three main energy dissipation sources (internal resistance, water transport and co-ion transport) are measured and mitigation strategies are proposed. The effect of current density, state of charge and temperature on the dissipation sources is analysed. Water transport is shown to cause hysteresis, lower (dis)charge efficiencies and lower energy capacity. At constant current and with increasing temperature, internal resistance is reduced but unwanted water transport is increased. This study reports charge efficiencies up to 58% and discharge efficiencies up to 72%. Full charge or discharge of the battery is shown inefficient. The optimal operating range is therefore introduced and identified (concentration difference Δm > 0.5 and energy efficiency η > 0.4).

  19. Simulation of temperature and flow fields in an inductively heated melt growth system

    Energy Technology Data Exchange (ETDEWEB)

    Tavakoli, M.H.; Mohammadi-Manesh, E.; Omid, S. [Physics Department, Bu-Ali Sina University, Hamedan (Iran, Islamic Republic of)


    The goal of the research presented here is to apply a global analysis of an inductively heated Czochralski furnace for a real sapphire crystal growth system and predict the characteristics of the temperature and flow fields in the system. To do it, for the beginning stage of a sapphire growth process, influence of melt and gas convection combined with radiative heat transfer on the temperature field of the system and the crystal-melt interface have been studied numerically using the steady state two-dimensional finite element method. For radiative heat transfer, internal radiation through the grown crystal and surface to surface radiation for the exposed surfaces have been taken into account. The numerical results demonstrate that there are a powerful vortex which arises from the natural convection in the melt and a strong and large vortex that flows upwards along the afterheater side wall and downwards along the seed and crystal sides in the gas part. In addition, a wavy shape has been observed for the crystal-melt interface with a deflection towards the melt. (copyright 2010 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  20. Topological susceptibility in finite temperature (2+1)-flavor QCD using gradient flow

    CERN Document Server

    Taniguchi, Yusuke; Suzuki, Hiroshi; Umeda, Takashi


    We compute the topological charge and its susceptibility in finite temperature (2+1)-flavor QCD on the lattice applying a gradient flow method. With the Iwasaki gauge action and non-perturbatively $O(a)$-improved Wilson quarks, we perform simulations on a fine lattice with~$a\\simeq0.07\\,\\mathrm{fm}$ at a heavy $u$, $d$ quark mass with $m_\\pi/m_\\rho\\simeq0.63$ but approximately physical $s$ quark mass of $m_{\\eta_{ss}}/m_\\phi\\simeq0.74$. In a temperature range from~$T\\simeq174\\,\\mathrm{MeV}$ ($N_t=16$) to $697\\,\\mathrm{MeV}$ ($N_t=4$), we study two topics on the topological susceptibility. One is a comparison of gluonic and fermionic definitions of the topological susceptibility. Because the two definitions are related by chiral Ward-Takahashi identities, their equivalence is not trivial for lattice quarks which violate the chiral symmetry explicitly at finite lattice spacings. The gradient flow method enables us to compute them without being bothered by the chiral violation. We find a good agreement between t...

  1. Limits on Alpha Particle Temperature Anisotropy and Differential Flow from Kinetic Instabilities: Solar Wind Observations

    CERN Document Server

    Bourouaine, Sofiane; Chandran, Benjamin D G; Maruca, Bennett A; Kasper, Justin C


    Previous studies have shown that the observed temperature anisotropies of protons and alpha particles in the solar wind are constrained by theoretical thresholds for pressure-anisotropy-driven instabilities such as the Alfv\\'en/ion-cyclotron (A/IC) and fast-magnetosonic/whistler (FM/W) instabilities. In this letter, we use a long period of in-situ measurements provided by the {\\em Wind} spacecraft's Faraday cups to investigate the combined constraint on the alpha-proton differential flow velocity and the alpha-particle temperature anisotropy due to A/IC and FM/W instabilities. We show that the majority of the data are constrained to lie within the region of parameter space in which A/IC and FM/W waves are either stable or have extremely low growth rates. In the minority of observed cases in which the growth rate of the A/IC (FM/W) instability is comparatively large, we find relatively higher values of $T_{\\perp\\alpha}/T_{\\perp p}$ ($T_{\\parallel\\alpha}/T_{\\parallel p}$) when alpha-proton differential flow vel...

  2. Turbulent heat-and-mass transfer in channel flow at transcritical temperature conditions (United States)

    Kim, Kukjin; Scalo, Carlo; Hickey, Jean-Pierre


    Turbulent heat and mass transfer at transcritical thermodynamic conditions is studied in turbulent channel flow using the high-fidelity DNS for solution to the compressible Navier-Stokes equations in the conservative form closed with the Peng-Robinson state equation. To isolate the real fluid effects on turbulent heat transfer, the bulk pressure is maintained at supercritical pb = 1 . 1pc and the isothermal walls are set to ΔT / 2 above and below the local pseudo-boiling temperature Tpb of the fluid (R-134a) where ΔT is 5K, 10K, and 20K. This setup allows the flow to reach a statistically-steady state while capturing the highest thermodynamic gradients, thus allowing a detailed study on thermodynamics of transcritical turbulent heat transfer. All thermodynamic and turbulent scales are fully resolved which is shown through a careful grid convergence analysis. The time-averaged density and compressibility factor are highly dependent on the temperature field and their large near-wall gradient causes thermodynamically-induced peaks in the RMS quantities resulting in strong turbulent mixing. The ejection of heavy pseudo-liquid blobs by near-wall turbulent structures into the channel core leads to a third RMS peak which is not observable in ideal gas simulations.

  3. Impact of flows on ion temperatures inferred from neutron spectra in asymmetrically driven OMEGA DT implosions (United States)

    Gatu Johnson, M.; Frenje, J. A.; Seguin, F. H.; Petrasso, R. D.; Aappelbe, B.; Chittenden, J.; Walsh, C.; Knauer, J. P.; Glebov, V. Yu.; Forrest, C.; Marshall, F.; Michel, T.; Stoeckl, C.; Sangster, T. C.; Zylstra, A.


    Ion temperatures (Tion) in Inertial Confinement Fusion (ICF) experiments have traditionally been inferred from the broadening of primary neutron spectra. Directional motion (flow) of the fuel at burn, expected to arise due to asymmetries imposed by engineering features (such as stalks, fill tubes, tents, or capsule imperfections) or drive non-uniformity, also impacts broadening and may lead to artificially inflated ``Tion'' values. Flow due to low-mode asymmetries is expected to give rise to line-of-sight variations in measured Tion, as observed in OMEGA cryogenic DT implosions but not in similar experiments at the NIF. In this presentation we report on an OMEGA experiment with intentionally asymmetric drive, designed to test the ability to accurately predict and measure line-of-sight differences in apparent Tion due to low-mode asymmetry-seeded flows. The results provide insight into the complexity of hot-spot dynamics, which is a problem that must be mastered to achieve ICF ignition. This work was supported in part by LLE, the U.S. DoE (NNSA, NLUF) and LLNL.

  4. Continuous flowing micro-reactor for aqueous reaction at temperature higher than 100 °C. (United States)

    Xie, Fei; Wang, Baojun; Wang, Wei; Dong, Tian; Tong, Jianhua; Xia, Shanhong; Wu, Wengang; Li, Zhihong


    Some aqueous reactions in biological or chemical fields are accomplished at a high temperature. When the reaction temperature is higher than 100 °C, an autoclave reactor is usually required to elevate the boiling point of the water by creating a high-pressure environment in a closed system. This work presented an alternative continuous flowing microfluidic solution for aqueous reaction with a reaction temperature higher than 100 °C. The pressure regulating function was successfully fulfilled by a small microchannel based on a delicate hydrodynamic design. Combined with micro heater and temperature sensor that integrated in a single chip by utilizing silicon-based microfabrication techniques, this pressure regulating microchannel generated a high-pressure/high-temperature environment in the upstream reaction zone when the reagents continuously flow through the chip. As a preliminary demonstration, thermal digestion of aqueous total phosphorus sample was achieved in this continuous flowing micro-reactor at a working pressure of 990 kPa (under the working flow rate of 20 nl/s) along with a reaction temperature of 145 °C. This continuous flowing microfluidic solution for high-temperature reaction may find applications in various micro total analysis systems.

  5. CO2 capture using fly ash from coal fired power plant and applications of CO2-captured fly ash as a mineral admixture for concrete. (United States)

    Siriruang, Chaichan; Toochinda, Pisanu; Julnipitawong, Parnthep; Tangtermsirikul, Somnuk


    The utilization of fly ash as a solid sorbent material for CO2 capture via surface adsorption and carbonation reaction was evaluated as an economically feasible CO2 reduction technique. The results show that fly ash from a coal fired power plant can capture CO2 up to 304.7 μmol/g fly ash, consisting of 2.9 and 301.8 μmol/g fly ash via adsorption and carbonation, respectively. The CO2 adsorption conditions (temperature, pressure, and moisture) can affect CO2 capture performance of fly ash. The carbonation of CO2 with free CaO in fly ashes was evaluated and the results indicated that the reaction consumed most of free CaO in fly ash. The fly ashes after CO2 capture were further used for application as a mineral admixture for concrete. Properties such as water requirement, compressive strength, autoclave expansion, and carbonation depth of mortar and paste specimens using fly ash before and after CO2 capture were tested and compared with material standards. The results show that the expansion of mortar specimens using fly ash after CO2 capture was greatly reduced due to the reduction of free CaO content in the fly ash compared to the expansion of specimens using fresh fly ash. There were no significant differences in the water requirement and compressive strength of specimens using fly ash, before and after CO2 capture process. The results from this study can lead to an alternative CO2 capture technique with doubtless utilization of fly ash after CO2 capture as a mineral admixture for concrete.

  6. Numerical simulation of seepage flow field in groundwater source heat pump system and its influence on temperature field

    Institute of Scientific and Technical Information of China (English)

    Jihua HU; Yanjun ZHANG; Danyan DU; Gang WU; Ziwang YU; Chen WANG; Fuquan NI


    Energy utilization in the aquifers is a new technology closely related to development of heat pump technique. It is significant for the flow distribution to be predicted in the aquifer surrounding the Groundwater Source Heat Pump System (GSHPS). The authors presented a new concept of "flow transfixion" by analyzing general features of aquifers, and then discussed interaction of the flow transfixion with the heat transfixion, which has practical significance to projects. A numerical model of groundwater flow was established based on the basic tenets of water-heat transferring in the aquifer. On this basis the flow field and the temperature field of GSHPS for a site in Shenyang City were numerically simulated. The basis of the flow transfixion was obtained; it was discussed for the influence of the flow transfixion on the heat transfixion. To a certain extent, the study offers some reference for the projects' design of GSHP in the studied area.


    Energy Technology Data Exchange (ETDEWEB)

    Dr. Joseph N.D. Dodoo; Dr. Joseph M. Okoh


    Surface area analyses performed on fly ash samples reveal that the surface area is controlled by carbon content. The higher surface areas found in large particles are due to the presence of highly porous carbonaceous particles. Adsorption-desorption isotherms and t-plots of fly ash samples indicate that fly ash is porous. BJH Adsorption/Desorption pore size analysis reveal that pore diameters are independent of sieve size. They appear to be dependent only on the nature of the material which confers porosity. Based on the results of Brown and Dykstra (41) it is reasonable to assume that calculations of reaction rates at temperatures above 550 C were confounded by weight losses from processes other than carbon oxidation and, therefore, are not useful in determination of the temperature dependence of carbon oxidation in fly ash. The results of the present study indicate that temperatures below 550 C should be used for future studies in order to satisfactorily assess the temperature dependence of carbon oxidation in fly ash. Furthermore, it is also advisable that percent carbon determinations be performed on fly ash samples after the oxidation reactions to determine whether all carbon present in fly ash is oxidized. This will ensure that reaction rates are representative of the complete oxidation of carbon. An inverse relationship was determined between reaction rates and oxygen concentration for this study. As discussed, this may be due to volatilization of volatiles from fly ash and ease of transport of products away from the reaction sites by the action of the vacuum applied to the samples. A more accurate determination of oxygen dependence of carbon oxidation can be accomplished by the use of specialty gases containing different concentrations of oxygen which could eliminate the need to apply vacuum to the samples.

  8. Flow and failure of an aluminium alloy from low to high temperature and strain rate

    Directory of Open Access Journals (Sweden)

    Sancho Rafael


    Full Text Available The mechanical behaviour of an aluminium alloy is presented in this paper. The study has been carried out to analyse the flow and failure of the aluminium alloy 7075-T73. An experimental study has been planned performing tests of un-notched and notched tensile specimens at low strain rates using a servo-hydraulic machine. High strain rate tests have been carried out using the same geometry in a Hopkinson Split Tensile Bar. The dynamic experiments at low temperature were performed using a cryogenic chamber, and the high temperature ones with a furnace, both incorporated to the Hopkinson bar. Testing temperatures ranged from − 50 ∘C to 100 ∘C and the strain rates from 10−4 s−1 to 600 s−1. The material behaviour was modelled using the Modified Johnson-Cook model and simulated using LS-DYNA. The results show that the Voce type of strain hardening is the most accurate for this material, while the traditional Johnson-Cook is not enough accurate to reproduce the necking of un-notched specimens. The failure criterion was obtained by means of the numerical simulations using the analysis of the stress triaxiality versus the strain to failure. The diameters at the failure time were measured using the images taken with an image camera, and the strain to failure was computed for un-notched and notched specimens. The numerical simulations show that the analysis of the evolution of the stress triaxiality is crucial to achieve accurate results. A material model using the Modified Johnson-Cook for flow and failure is proposed.

  9. Magmatic and fragmentation controls on volcanic ash surface chemistry (United States)

    Ayris, Paul M.; Diplas, Spyros; Damby, David E.; Hornby, Adrian J.; Cimarelli, Corrado; Delmelle, Pierre; Scheu, Bettina; Dingwell, Donald B.


    The chemical effects of silicate ash ejected by explosive volcanic eruptions on environmental systems are fundamentally mediated by ash particle surfaces. Ash surfaces are a composite product of magmatic properties and fragmentation mechanisms, as well as in-plume and atmospheric alteration processes acting upon those surfaces during and after the eruption. Recent attention has focused on the capacity of alteration processes to shape ash surfaces; most notably, several studies have utilised X-ray photoelectron spectroscopy (XPS), a technique probing the elemental composition and coordination state of atoms within the top 10 nm of ash surfaces, to identify patterns of elemental depletions and enrichments relative to bulk ash chemical composition. Under the presumption of surface and bulk equivalence, any disparities have been previously attributed to surface alteration processes, but the ubiquity of some depletions (e.g., Ca, Fe) across multiple ash studies, irrespective of eruptive origin, could suggest these to be features of the surface produced at the instant of magma fragmentation. To investigate this possibility further, we conducted rapid decompression experiments at different pressure conditions and at ambient and magmatic temperature on porous andesitic rocks. These experiments produced fragmented ash material untouched by secondary alteration, which were compared to particles produced by crushing of large clasts from the same experiments. We investigated a restricted size fraction (63-90 μm) from both fragmented and crushed materials, determining bulk chemistry and mineralogy via XRF, SEM-BSE and EPMA, and investigated the chemical composition of the ash surface by XPS. Analyses suggest that fragmentation under experimental conditions partitioned a greater fraction of plagioclase-rich particles into the selected size fraction, relative to particles produced by crushing. Trends in surface chemical composition in fragmented and crushed particles mirror that

  10. Influence of temperature-dependent material properties on heat transfer in the turbulent flow over a flat plate (United States)

    Wehle, F.; Brandt, F.

    The influence of temperature dependence of material properties on heat transfer in a turbulent plate boundary layer is investigated using differential equations for the velocity and temperature fields of even, steady, and compressible boundary layer flows. The results are compared with the well-known material property correction factors of Zhukauskas (1966), Sieder and Tate (1936), and Hufschmidt and Bruck (1968).

  11. Effect of coal ash disposal upon an unconfined alluvial system

    Energy Technology Data Exchange (ETDEWEB)

    Shergill, B.S.; Sendlein, L.V.A. (Univ. of Kentucky, Lexington, KY (United States). Dept. of Geological Sciences); Dinger, J.S. (Univ. of Kentucky, Lexington, KY (United States). Kentucky Geological Survey)


    Fly and bottom ash from coal combustion has been disposed in four ash ponds in an alluvial valley. Three of the ash ponds are receiving ash and one was filled and closed. Twenty eight monitoring wells ranging in depth from 10 feet to 65 feet have been installed at the site to study groundwater flow and chemistry. Hydraulic heads are influenced by the stage of the Kentucky River, and the flow direction is vertical below the ash ponds and predominantly horizontal a short distance from the pond all the way to the river. Three different groundwater flow zones were observed and have unique water chemistry. The deep zone (near bedrock) has a low Eh (< [minus]80), and high concentration of Fe, ammonia nitrogen, below detection sulfate values (< 5 mg/l) and trace metals. The age of the deep groundwater as determined by tritium analyses is between 20 to 30 years old (5.68 TU). The intermediate groundwater zone (from ash pond) has relatively higher Eh (> 100) and lower concentrations of Fe and ammonia nitrogen, median sulfate concentration (114 mg/l), and arsenic is below detection limits. The shallow groundwater zone is through the closed out ash point and has higher concentrations of nearly all cations and anions, including sulfate (888 mg/l) and arsenic (exists as arsenite) at concentration of 0.9 mg/l, low Eh (< [minus]100), and high pH. When shallow flow enters the alluvium, the sulfate are attenuated by sulfate reduction and this results in high bicarbonate values. Saturation indices (SI) as calculated by the geochemical model, MINTEQA2, indicate that deep and intermediate groundwater are unsaturated and shallow groundwater is at or near equilibrium with respect to calcite, dolomite, and gypsum.

  12. Sensitive biomolecule detection in lateral flow assay with a portable temperature-humidity control device. (United States)

    Choi, Jane Ru; Hu, Jie; Feng, Shangsheng; Wan Abas, Wan Abu Bakar; Pingguan-Murphy, Belinda; Xu, Feng


    Lateral flow assays (LFAs) have currently attracted broad interest for point-of-care (POC) diagnostics, but their application has been restricted by poor quantification and limited sensitivity. While the former has been currently solved to some extent by the development of handheld or smartphone-based readers, the latter has not been addressed fully, particularly the potential influences of environmental conditions (e.g., temperature and relative humidity (RH)), which have not yet received serious attention. The present study reports the use of a portable temperature-humidity control device to provide an optimum environmental requirement for sensitivity improvement in LFAs, followed by quantification by using a smartphone. We found that a RH beyond 60% with temperatures of 55-60°C and 37-40°C produced optimum nucleic acid hybridization and antigen-antibody interaction in LFAs, respectively representing a 10-fold and 3-fold signal enhancement over ambient conditions (25°C, 60% RH). We envision that in the future the portable device could be coupled with a fully integrated paper-based sample-to-answer biosensor for sensitive detection of various target analytes in POC settings.

  13. Modeling of Air Temperature for Heat Exchange due to Vertical Turbulence and Horizontal Air Flow

    Institute of Scientific and Technical Information of China (English)

    ZHANG Lei; MENG Qing-lin


    In order to calculate the air temperature of the near surface layer in urban environment,the Sur-face layer air was divided into several layers in the vertical direction,and some energy bakmce equations were de-veloped for each air layer,in which the heat exchange due to vertical turbulence and horizontal air flow was tak-en into account.Then,the vertical temperature distribution of the surface layer air was obtained through the coupled calculation using the energy balance equations of underlying surfaces and building walls.Moreover,the measured air temperatures in a small area (with a horizontal scale of less than 500 m) and a large area (with ahorizontal scale of more than 1000 m) in Guangzhou in summer were used to validate the proposed model.The calculated results agree well with the measured ones,with a maximum relative error of 4.18%.It is thus con-cluded that the proposed model is a high-accuracy method to theoretically analyze the urban heat island and the thermal environment.

  14. Consistent multi-internal-temperature models for vibrational and electronic nonequilibrium in hypersonic nitrogen plasma flows

    Energy Technology Data Exchange (ETDEWEB)

    Guy, Aurélien, E-mail:; Bourdon, Anne, E-mail:; Perrin, Marie-Yvonne, E-mail: [CNRS, UPR 288, Laboratoire d' Énergétique Moléculaire et Macroscopique, Combustion (EM2C), Grande Voie des Vignes, 92295 Châtenay-Malabry (France); Ecole Centrale Paris, Grande Voie des Vignes, 92295 Châtenay-Malabry (France)


    In this work, a state-to-state vibrational and electronic collisional model is developed to investigate nonequilibrium phenomena behind a shock wave in an ionized nitrogen flow. In the ionization dynamics behind the shock wave, the electron energy budget is of key importance and it is found that the main depletion term corresponds to the electronic excitation of N atoms, and conversely the major creation terms are the electron-vibration term at the beginning, then replaced by the electron ions elastic exchange term. Based on these results, a macroscopic multi-internal-temperature model for the vibration of N{sub 2} and the electronic levels of N atoms is derived with several groups of vibrational levels of N{sub 2} and electronic levels of N with their own internal temperatures to model the shape of the vibrational distribution of N{sub 2} and of the electronic excitation of N, respectively. In this model, energy and chemistry source terms are calculated self-consistently from the rate coefficients of the state-to-state database. For the shock wave condition studied, a good agreement is observed on the ionization dynamics as well as on the atomic bound-bound radiation between the state-to-state model and the macroscopic multi-internal temperature model with only one group of vibrational levels of N{sub 2} and two groups of electronic levels of N.

  15. Ash Management Review—Applications of Biomass Bottom Ash

    Directory of Open Access Journals (Sweden)

    Harpuneet S. Ghuman


    Full Text Available In industrialized countries, it is expected that the future generation of bioenergy will be from the direct combustion of residues and wastes obtained from biomass. Bioenergy production using woody biomass is a fast developing application since this fuel source is considered to be carbon neutral. The harnessing of bioenergy from these sources produces residue in the form of ash. As the demand for bioenergy production increases, ash and residue volumes will increase. Major challenges will arise relating to the efficient management of these byproducts. The primary concerns for ash are its storage, disposal, use and the presence of unburned carbon. The continual increase in ash volume will result in decreased ash storage facilities (in cases of limited room for landfill expansion, as well as increased handling, transporting and spreading costs. The utilization of ash has been the focus of many studies, hence this review investigates the likely environmental and technological challenges that increased ash generation may cause. The presence of alkali metals, alkaline earth metals, chlorine, sulphur and silicon influences the reactivity and leaching to the inorganic phases which may have significant impacts on soils and the recycling of soil nutrient. Discussed are some of the existing technologies for the processing of ash. Unburned carbon present in ash allows for the exploration of using ash as a fuel. The paper proposes sieve fractionation as a suitable method for the separation of unburnt carbon present in bottom ash obtained from a fixed-bed combustion system, followed by the application of the gasification technology to particle sizes of energy importance. It is hoped that this process will significantly reduce the volume of ash disposed at landfills.

  16. Using isotopic, hydrogeochemical-tracer and temperature data to characterize recharge and flow paths in a complex karst groundwater flow system in northern China (United States)

    Sun, Ziyong; Ma, Rui; Wang, Yanxin; Ma, Teng; Liu, Yunde


    Isotopic and hydrogeochemical analysis, combined with temperature investigation, was conducted to characterize the flow system in the carbonate aquifer at Taiyuan, northern China. The previous division of karst subsystems in Taiyuan, i.e. the Xishan (XMK), Dongshan (DMK) and Beishan (BMK) mountain systems, were also examined. The measured δD, δ 18O and 3He/4He in water indicate that both thermal and cold groundwaters have a meteoric origin rather than deep crustal origin. Age dating using 3H and 14C shows that groundwater samples from discharge zones along faults located at the margin of mountains in the XMK and DMK are a mixture of paleometeoric thermal waters and younger cold waters from local flow systems. 14C data suggest that the average age was about 10,000 years and 4,000 years for thermal and cold groundwater in discharge zones, respectively. Based on the data of temperature, water solute chemical properties, 14C, δ 34SSO4, 87Sr/86Sr and δ 18O, different flow paths in the XMK and DMK were distinguished. Shallow groundwater passes through the upper Ordovician formations, producing younger waters at the discharge zone (low temperature and ionic concentration and enriched D and 18O). Deep groundwater flows through the lower Ordovician and Cambrian formations, producing older waters at the discharge zone (high ionic concentration and temperature and depleted D and 18O). At the margin of mountains, groundwater in deep systems flows vertically up along faults and mixes with groundwater from shallow flow systems. By contrast, only a single flow system through the entire Cambrian to Ordovician formations occurs in the BMK.

  17. MGT 401 ASH Course Tutorial / Tutorialoutlet




    For more course tutorials visit   MGT 401 Week 1 Individual Assignment Strategic Management Process Paper (Ash) MGT 401 Week 1 Class Activity Week 1 (Ash) MGT 401 Week 1 DQ 1 (Ash) MGT 401 Week 1 DQ 2 (Ash) MGT 401 Week 2 Learning Team Business Model Comparison Example (Ash) MGT 401 Week 2 DQ 1 (Ash) MGT 401 Week 2 DQ 2 (Ash) MGT 401 Week 2 Class Activity (Ash) MGT 401 Week 3 Individual Assignment Business Plan Evaluation (Ash) ...

  18. Wellbore and groundwater temperature distribution eastern Snake River Plain, Idaho: Implications for groundwater flow and geothermal potential (United States)

    McLing, Travis L.; Smith, Richard P.; Smith, Robert W.; Blackwell, David D.; Roback, Robert C.; Sondrup, Andrus J.


    A map of groundwater temperatures from the Eastern Snake River Plain (ESRP) regional aquifer can be used to identify and interpret important features of the aquifer, including aquifer flow direction, aquifer thickness, and potential geothermal anomalies. The ESRP is an area of high heat flow, yet most of this thermal energy fails to reach the surface, due to the heat being swept downgradient by the aquifer to the major spring complexes near Thousand Springs, ID, a distance of 300 km. Nine deep boreholes that fully penetrate the regional aquifer display three common features: (1) high thermal gradients beneath the aquifer, corresponding to high conductive heat flow in low-permeability hydrothermally-altered rocks; (2) isothermal temperature profiles within the aquifer, characteristic of an actively flowing groundwater; and (3) moderate thermal gradients in the vadose zone with values that indicate that over half of the geothermal heat flow is removed by advective transport in the regional aquifer system. This study utilized temperature data from 250 ESRP aquifer wells to evaluate regional aquifer flow direction, aquifer thickness, and potential geothermal anomalies. Because the thermal gradients are typically low in the aquifer, any measurement of groundwater temperature is a reasonable estimate of temperature throughout the aquifer thickness, allowing the construction of a regional aquifer temperature map for the ESRP. Mapped temperatures are used to identify cold thermal plumes associated with recharge from tributary valleys and adjacent uplands, and warm zones associated with geothermal input to the aquifer. Warm zones in the aquifer can have various causes, including local circulation of groundwater through the deep conductively dominated region, slow groundwater movement in low-permeability regions, or localized heat flow from deeper thermal features.

  19. Thermal behaviour of ESP ash from municipal solid waste incinerators. (United States)

    Yang, Y; Xiao, Y; Wilson, N; Voncken, J H L


    Stricter environmental regulations demand safer treatment and disposal of incinerator fly ashes. So far no sound technology or a process is available for a sustainable and ecological treatment of the waste incineration ashes, and only partial treatment is practised for temporary and short-term solutions. New processes and technology need to be developed for comprehensive utilization and detoxification of the municipal solid waste (MSW) incinerator residues. To explore the efficiency of thermal stabilisation and controlled vitrification, the thermal behaviour of electrostatic precipitator (ESP) ash was investigated under controlled conditions. The reaction stages are identified with the initial moisture removal, volatilization, melting and slag formation. At the temperature higher than 1100 degrees C, the ESP ashes have a quicker weight loss, and the total weight loss reaches up to 52%, higher than the boiler ash. At 1400 degrees C a salt layer and a homogeneous glassy slag were formed. The effect of thermal treatment on the leaching characteristics of various elements in the ESP ash was evaluated with the availability-leaching test. The leaching values of the vitrified slag are significantly lowered than that of the original ash.

  20. Radiative, two-temperature simulations of low luminosity black hole accretion flows in general relativity

    CERN Document Server

    Sadowski, A; Narayan, R; Abarca, D; McKinney, J C


    We present a numerical method which evolves a two-temperature, magnetized, radiative, accretion flow around a black hole, within the framework of general relativistic radiation magnetohydrodynamics. As implemented in the code KORAL, the gas consists of two sub-components -- ions and electrons -- which share the same dynamics but experience independent, relativistically consistent, thermodynamical evolution. The electrons and ions are heated independently according to a standard prescription from the literature for magnetohydrodynamical turbulent dissipation. Energy exchange between the particle species via Coulomb collisions is included. In addition, electrons gain and lose energy and momentum by absorbing and emitting synchrotron and bremsstrahlung radiation, and through Compton scattering. All evolution equations are handled within a fully covariant framework in the relativistic fixed-metric spacetime of the black hole. Numerical results are presented for five models of low luminosity black hole accretion. ...

  1. Ir Thermographic Measurements of Temperatures and Heat Fluxes in Hypersonic Plasma Flow (United States)

    Cardone, G.; Tortora, G.; del Vecchio, A.


    The technological development achieved in instruments and methodology concerning both flights and ground hypersonic experiment (employed in space plane planning) goes towards an updating and a standardization of the heat flux technical measurements. In fact, the possibility to simulate high enthalpy flow relative to reentry condition by hypersonic arc-jet facility needs devoted methods to measure heat fluxes. Aim of this work is to develop an experimental numerical technique for the evaluation of heat fluxes over Thermal Protection System (TPS) by means of InfraRed (IR) thermographic temperature measurements and a new heat flux sensor (IR-HFS). We tackle the numerical validation of IR-HFS, apply the same one to the Hyflex nose cap model and compare the obtained results with others ones obtained by others methodology.

  2. Electrodialytic treatment of fly ash

    DEFF Research Database (Denmark)

    Jensen, Pernille Erland; Pedersen, Anne Juul; Kirkelund, Gunvor Marie;

    Heavy metals are removed from the fly ashes by an electrodialytic treatment with the aim of up-grading the ashes for reuse in stead of disposal in landfill.A great potential for upgrading of bio- and waste incineration ashes by electrodialytic treatment exists. In the future, the applicability...... of the treated products for reuse in construction or farming sectors should be explored further, as should the possibility of recycling of valuable, extracted elements in the metallurgical industry....

  3. Extracting kinetic freeze-out temperature and radial flow velocity from an improved Tsallis distribution

    CERN Document Server

    Lao, Hai-Ling; Lacey, Roy A


    We analyze the transverse momentum ($p_T$) spectra of identified particles ($\\pi^{\\pm}$, $K^{\\pm}$, $p$, and $\\bar p$) produced in gold-gold (Au-Au) and lead-lead (Pb-Pb) collisions over a $\\sqrt{s_{NN}}$ (center-of-mass energy per nucleon pair) range from 14.5 GeV [one of the Relativistic Heavy Ion Collider (RHIC) energies] to 2.76 TeV [one of the Large Hadron Collider (LHC) energies]. For the spectra with a narrow $p_T$ range, an improved Tsallis distribution which is in fact the Tsallis distribution with radial flow is used. For the spectra with a wide $p_T$ range, a superposition of the improved Tsallis distribution and an inverse power-law is used. Both the extracted kinetic freeze-out temperature ($T_0$) and radial flow velocity ($\\beta_T$) increase with the increase of $\\sqrt{s_{NN}}$, which indicate a higher excitation and larger expansion of the interesting system at the LHC. Both the values of $T_0$ and $\\beta_T$ in central collisions are slightly larger than those in peripheral collisions, and they...

  4. Radiative, two-temperature simulations of low-luminosity black hole accretion flows in general relativity (United States)

    Sądowski, Aleksander; Wielgus, Maciek; Narayan, Ramesh; Abarca, David; McKinney, Jonathan C.; Chael, Andrew


    We present a numerical method that evolves a two-temperature, magnetized, radiative, accretion flow around a black hole, within the framework of general relativistic radiation magnetohydrodynamics. As implemented in the code KORAL, the gas consists of two sub-components - ions and electrons - which share the same dynamics but experience independent, relativistically consistent, thermodynamical evolution. The electrons and ions are heated independently according to a prescription from the literature for magnetohydrodynamical turbulent dissipation. Energy exchange between the particle species via Coulomb collisions is included. In addition, electrons gain and lose energy and momentum by absorbing and emitting synchrotron and bremsstrahlung radiation and through Compton scattering. All evolution equations are handled within a fully covariant framework in the relativistic fixed-metric space-time of the black hole. Numerical results are presented for five models of low-luminosity black hole accretion. In the case of a model with a mass accretion rate dot{M}˜ 4× 10^{-8} dot{M}_Edd, we find that radiation has a negligible effect on either the dynamics or the thermodynamics of the accreting gas. In contrast, a model with a larger dot{M}˜ 4× 10^{-4} dot{M}_Edd behaves very differently. The accreting gas is much cooler and the flow is geometrically less thick, though it is not quite a thin accretion disc.

  5. Flow Rates Measurement and Uncertainty Analysis in Multiple-Zone Water-Injection Wells from Fluid Temperature Profiles. (United States)

    Reges, José E O; Salazar, A O; Maitelli, Carla W S P; Carvalho, Lucas G; Britto, Ursula J B


    This work is a contribution to the development of flow sensors in the oil and gas industry. It presents a methodology to measure the flow rates into multiple-zone water-injection wells from fluid temperature profiles and estimate the measurement uncertainty. First, a method to iteratively calculate the zonal flow rates using the Ramey (exponential) model was described. Next, this model was linearized to perform an uncertainty analysis. Then, a computer program to calculate the injected flow rates from experimental temperature profiles was developed. In the experimental part, a fluid temperature profile from a dual-zone water-injection well located in the Northeast Brazilian region was collected. Thus, calculated and measured flow rates were compared. The results proved that linearization error is negligible for practical purposes and the relative uncertainty increases as the flow rate decreases. The calculated values from both the Ramey and linear models were very close to the measured flow rates, presenting a difference of only 4.58 m³/d and 2.38 m³/d, respectively. Finally, the measurement uncertainties from the Ramey and linear models were equal to 1.22% and 1.40% (for injection zone 1); 10.47% and 9.88% (for injection zone 2). Therefore, the methodology was successfully validated and all objectives of this work were achieved.

  6. Ash Aggregates in Proximal Settings (United States)

    Porritt, L. A.; Russell, K.


    Ash aggregates are thought to have formed within and been deposited by the eruption column and plume and dilute density currents and their associated ash clouds. Moist, turbulent ash clouds are considered critical to ash aggregate formation by facilitating both collision and adhesion of particles. Consequently, they are most commonly found in distal deposits. Proximal deposits containing ash aggregates are less commonly observed but do occur. Here we describe two occurrences of vent proximal ash aggregate-rich deposits; the first within a kimberlite pipe where coated ash pellets and accretionary lapilli are found within the intra-vent sequence; and the second in a glaciovolcanic setting where cored pellets (armoured lapilli) occur within Diamond Mine, Canada, are the residual deposits within the conduit and vent of the volcano and are characterised by an abundance of ash aggregates. Coated ash pellets are dominant but are followed in abundance by ash pellets, accretionary lapilli and rare cored pellets. The coated ash pellets typically range from 1 - 5 mm in diameter and have core to rim ratios of approximately 10:1. The formation and preservation of these aggregates elucidates the style and nature of the explosive phase of kimberlite eruption at A418 (and other pipes?). First, these pyroclasts dictate the intensity of the kimberlite eruption; it must be energetic enough to cause intense fragmentation of the kimberlite to produce a substantial volume of very fine ash (sustained plume attended by concomitant production of pyroclastic density currents. The size and internal structure of the armoured lapilli provide constraints on the nature of the initial explosive phase of eruption at Kima'Kho. Their proximity to the vent also indicates rapid aggregation within the eruption plume. Within both sequences rapid aggregation of ash particles occurred in proximity to the vent. However, the conditions were substantially different leading to the production of armoured

  7. Influence of feed and sampling systems on element partitioning in Kentucky fly ash

    Energy Technology Data Exchange (ETDEWEB)

    Valentim, Bruno V. [Centro e Departamento de Geologia Faculdade de Ciencias da Universidade do Porto, Rua do Campo Alegre 687, 4169-007, Porto (Portugal); Hower, James C. [University of Kentucky Center for Applied Energy Research (CAER), Lexington, Kentucky, 40511 (United States)


    Pentannual surveys of the production of coal combustion byproducts in Kentucky utility power plants, along with other studies in the intervening years has resulted in a large amount of data relating coal chemistry, fly ash (FA) chemistry, and, to a lesser degree, bottom ash chemistry. Therefore, this important collection of data enables to perform studies on a wide variety of fly ash types. The chemical classification, based on major oxides (acid, alkaline, and Fe{sub 2}O{sub 3}), of coal high-temperature ash (HTA) and FA from Kentucky Power Plants shows that the majority of the coal HTAs are Sialic, Sialic-Ferrisialic, and Ferrisialic. The FA classification not only depends of the coal HTA chemistry but also the ash-collection system and the sampling position, with the implications of flue gas temperature and ash particle size, within the system. (author)

  8. Thermal treatment and vitrification of boiler ash from a municipal solid waste incinerator. (United States)

    Yang, Y; Xiao, Y; Voncken, J H L; Wilson, N


    Boiler ash generated from municipal solid waste (MSW) incinerators is usually classified as hazardous materials and requires special disposal. In the present study, the boiler ash was characterized for the chemical compositions, morphology and microstructure. The thermal chemical behavior during ash heating was investigated with thermal balance. Vitrification of the ash was conducted at a temperature of 1400 degrees C in order to generate a stable silicate slag, and the formed slag was examined with chemical and mineralogical analyses. The effect of vitrification on the leaching characteristics of various elements in the ash was evaluated with acid leaching. The study shows that the boiler ash as a heterogeneous fine powder contains mainly silicate, carbonate, sulfates, chlorides, and residues of organic materials and heavy metal compounds. At elevated temperatures, the boiler ash goes through the initial moisture removal, volatilization, decomposition, sintering, melting, and slag formation. At 1400 degrees C a thin layer of salt melt and a homogeneous glassy slag was formed. The experimental results indicate that leaching values of the vitrified slag are significantly reduced compared to the original boiler ash, and the vitrification could be an interesting alternative for a safer disposal of the boiler ash. Ash compacting, e.g., pelletizing can reduce volatilization and weight loss by about 50%, and would be a good option for the feed preparation before vitrification.

  9. Effect of the Additives on the Desulphurization Rate of Flash Hydrated and Agglomerated CFB Fly Ash (United States)

    Li, D. X.; Li, H. L.; Xu, M.; Lu, J. F.; Liu, Q.; Zhang, J. S.; Yue, G. X.

    CFB fly ash from separators was mixed with water or the mixture of water and additives under the temperature of 363K by use of a blender. Then, this compound of fly ash and water or additives was pumped into a CFB combustion chamber by a sludge pump. Because the temperature of flue gas was high in CFB, the fly ash was hydrated fast and agglomerated in the same time. Through this process, the size of agglomerating fly ash is larger than the original particle and the relative residence time of agglomerated fly ash in CFB becomes longer. Therefore, the rate of utility of calcium in fly ash improves and the content of carbon in fly ash decreases. This results in a low Ca/S and low operational cost for CFB boiler. The additive is one key factor, which affects the rate of desulfurization of agglomerated fly ash. Effect of different additives on rate of desulfurization is not same. Cement and limestone are beneficiated to sulfur removal of agglomerated fly ash, but sodium silicate does not devote to the rate of sulfur removal of agglomerated fly ash.

  10. Can pore-clogging by ash explain post-fire runoff?

    NARCIS (Netherlands)

    Stoof, Cathelijne R.; Gevaert, Anouk I.; Baver, Christine; Hassanpour, Bahareh; Morales, Verónica L.; Zhang, Wei; Martin, Deborah; Giri, Shree K.; Steenhuis, Tammo S.


    Ash plays an important role in controlling runoff and erosion processes after wildfire and has frequently been hypothesised to clog soil pores and reduce infiltration. Yet evidence for clogging is incomplete, as research has focussed on identifying the presence of ash in soil; the actual flow pro

  11. Flow of an Oldroyd-B Fluid past an Unsteady Bidirectional Stretching Sheet with Constant Temperature and Constant Heat Flux

    Directory of Open Access Journals (Sweden)

    Manzoor Ahmad


    Full Text Available This article describes the time dependent flow of a non-Newtonian fluid with heat transfer. We consider three dimensional unsteady flow and heat transfer of an Oldroyd-B fluid for constant temperature (CT and constant heat flux (CH cases over an unsteady bidirectional stretching surface. Homotopic solutions of the governing boundary value problems have been computed. Convergence for both velocity and temperature profiles is explored. The effects of emerging parameters on the velocity and temperature fields are investigated with the help of graphs and tabular data. It is observed that due to unsteadiness temperature in both the constant temperature and constant heat flux cases decrease significantly. Comparison of obtained and previously published results is found in excellent agreement.

  12. Synthesis of ZSM-5 zeolite from lignite fly ash and rice husk ash

    Energy Technology Data Exchange (ETDEWEB)

    Chareonpanich, Metta; Namto, Teerapong; Kongkachuichay, Paisan [Department of Chemical Engineering, Kasetsart University, 50 Paholyothin Rd., Chatuchak, Bangkok 10900 (Thailand); Limtrakul, Jumras [Department of Chemistry, Kasetsart University, Chatuchak, Bangkok 10900 (Thailand)


    The lignite fly ash from the Mae-Moh power plant, Thailand, and rice husk ash were used as raw materials for ZSM-5 zeolite synthesis. Factors affecting the yield of ZSM-5 zeolite synthesized from fly ash, i.e., the SiO{sub 2}/Al{sub 2}O{sub 3} mole ratio, the presence of tetrapropyl ammonium bromide (TPABr, the structure-directing material for ZSM-5 zeolite synthesis), the holding temperature and time, and the initial pressure were investigated. It was found that without TPABr only zeolite P could be synthesized at SiO{sub 2}/Al{sub 2}O{sub 3} mole ratios of 2.8-200. In order to synthesize ZSM-5 zeolite, sodium silicate solution was added to adjust the SiO{sub 2}/Al{sub 2}O{sub 3} mole ratio in raw ash. The yield of ZSM-5 zeolite was as high as 59 wt.% when following conditions were used: SiO{sub 2}/Al{sub 2}O{sub 3} mole ratio, 40; the holding temperature, 210 C; the holding time, 4 h and the initial pressure, 4 bar. The catalytic performance for CO{sub 2} hydrogenation reaction of the ZSM-5 zeolite was preliminary tested and compared with that of commercial one. It was observed that there was no significant difference in the catalytic performance between these two catalysts.

  13. Utilization of coal combustion fly ash in terracotta bodies

    Energy Technology Data Exchange (ETDEWEB)

    Kara, A.; Kurama, S. [Dept. of Materials Science and Engineering, Anadolu Univ., Eskisehir (Turkey); Kurama, H.; Kara, Y. [Osmangazi Univ., Mining Engineering Dept., Eskisehir (Turkey)


    In this present work, coal combustion fly ash from a power plant in Turkey was used in combination with a traditional raw material in terracotta production with the aim of having a product with improved physico-mechanical properties and lower production cost. Several compositions were prepared by adding different amounts of fly ash (ranging from 0 to 20%) in a yellow firing terracotta formulation and shaped by wet pressing. Following firing at a suitable temperature, some of the physical properties of the resultant tiles were determined as a function of the fly ash content. A combination of XRD, SEM and EDX techniques were also employed to correlate the properties with the phase composition. The results indicated that fly ash could be utilized easily in certain amounts in such an application. (orig.)

  14. Ash properties of some dominant Greek forest species

    Energy Technology Data Exchange (ETDEWEB)

    Liodakis, S. [Laboratory of Inorganic and Analytical Chemistry, Department of Chemical Engineering, National Technical University of Athens (NTUA), 9 Iroon Polytechniou Street, Athens 157 73 (Greece)]. E-mail:; Katsigiannis, G. [Laboratory of Inorganic and Analytical Chemistry, Department of Chemical Engineering, National Technical University of Athens (NTUA), 9 Iroon Polytechniou Street, Athens 157 73 (Greece); Kakali, G. [Laboratory of Inorganic and Analytical Chemistry, Department of Chemical Engineering, National Technical University of Athens (NTUA), 9 Iroon Polytechniou Street, Athens 157 73 (Greece)


    The elemental and chemical wood ash compositions of six dominant Greek fuels was investigated using a variety of techniques, including thermal gravimetric analysis (TG), differential thermal analysis (DTA), atomic absorption spectroscopy (AAS) and X-ray diffraction (XRD). In addition, the alkalinity of wood ash was determined by titration. The ash was prepared by combustion at low (600 deg. C), middle (800 deg. C) and high temperatures (1000 deg. C). The ash composition is very important because thousands of hectares of wildlands are burned annually in Greece. The resulting deposits affect soil properties (i.e., pH) and provide a source of inorganic constituents (i.e., Ca, K, Na, Mg, etc.), while the most soluble compounds (i.e., sodium and potassium hydroxides and carbonates) do not persist through the wet season. The samples selected were: Pinus halepensis (Aleppo pine), Pinus brutia (Calabrian pine), Olea europaea (Olive), Cupressus sempervirens (Italian cypress), Pistacia lentiscus (Mastic tree), Quercus coccifera (Holly oak)

  15. Magnetic resonance flow velocity and temperature mapping of a shape memory polymer foam device

    Directory of Open Access Journals (Sweden)

    Wilson Thomas S


    Full Text Available Abstract Background Interventional medical devices based on thermally responsive shape memory polymer (SMP are under development to treat stroke victims. The goals of these catheter-delivered devices include re-establishing blood flow in occluded arteries and preventing aneurysm rupture. Because these devices alter the hemodynamics and dissipate thermal energy during the therapeutic procedure, a first step in the device development process is to investigate fluid velocity and temperature changes following device deployment. Methods A laser-heated SMP foam device was deployed in a simplified in vitro vascular model. Magnetic resonance imaging (MRI techniques were used to assess the fluid dynamics and thermal changes associated with device deployment. Results Spatial maps of the steady-state fluid velocity and temperature change inside and outside the laser-heated SMP foam device were acquired. Conclusions Though non-physiological conditions were used in this initial study, the utility of MRI in the development of a thermally-activated SMP foam device has been demonstrated.

  16. Analysis on flow stress of magnesium alloys during high temperature deformation

    Institute of Scientific and Technical Information of China (English)


    The flow stress of magnesium alloys during hot compression at different temperatures and strain rates was studied by experiments. Materials used were AZ91D alloys in as-cast, homogeneous treatment states, AZ31 and ZK60 alloys in as-cast state.The results show that the thermal simulation curves of different alloys differ from one another at the same deforming condition. The general curves of AZ31 and AZ91D alloys have the character of dynamic recrystallization. There are increase of true stress, drastic falling of true stress and increase of true stress in most curves of ZK60 alloy, while the other curves have the characteristics of dynamic recrystallization. From the analysis the reasonable deforming temperature should be selected from 523 to 673 K for AZ31 and the unhomogenized AZ91D alloy, from 473 to 673 K for the homogenized AZ91D alloy, and it was concluded to be 473 K or 673 K for ZK60 alloy.

  17. Natural Convection Flow along an Isothermal Vertical Flat Plate with Temperature Dependent Viscosity and Heat Generation

    Directory of Open Access Journals (Sweden)

    Md. Mamun Molla


    Full Text Available The purpose of this study is to investigate the natural convection laminar flow along an isothermal vertical flat plate immersed in a fluid with viscosity which is the exponential function of fluid temperature in presence of internal heat generation. The governing boundary layer equations are transformed into a nondimensional form and the resulting nonlinear system of partial differential equations is reduced to a convenient form which are solved numerically using an efficient marching order implicit finite difference method with double sweep technique. Numerical results are presented in terms of the velocity and temperature distribution of the fluid as well as the heat transfer characteristics, namely, the wall shear stress and the local and average rate of heat transfer in terms of the local skin-friction coefficient, the local and average Nusselt number for a wide range of the viscosity-variation parameter, heat generation parameter, and the Rayleigh number. Increasing viscosity variation parameter and Rayleigh number lead to increasing the local and average Nusselt number and decreasing the wall shear stress. Wall shear stress and the rate of heat transfer decreased due to the increase of heat generation.

  18. Convection in rotating flows with simultaneous imposition of radial and vertical temperature gradients

    CERN Document Server

    Banerjee, Ayan Kumar; Bhattacharya, Amitabh; Balasubramanian, Sridhar


    Laboratory experiments were conducted to study heat transport characteristics in a nonhomogeneously heated fluid annulus subjected to rotation along the vertical axis (z). The nonhomogeneous heating was obtained by imposing radial and vertical temperature gradient ({\\Delta}T). The parameter range for this study was Rayleigh number, Ra=2.43x10^8-3.66x10^8, and Taylor number, Ta=6.45x10^8-27x10^8. The working fluid was water with a Prandtl number, Pr=7. Heat transport was measured for varying rotation rates ({\\Omega}) for fixed values of {\\Delta}T. The Nusselt number, Nu, plotted as a function of Ta distinctly showed the effect of rotation on heat transport. In general, Nu was found to have a larger value for non-rotating convection. This could mean an interplay of columnar plumes and baroclinic wave in our system as also evident from temperature measurements. Laser based imaging at a single vertical plane also showed evidence of such flow structure.

  19. Fly ash reinforced thermoplastic vulcanizates obtained from waste tire powder. (United States)

    Sridhar, V; Xiu, Zhang Zhen; Xu, Deng; Lee, Sung Hyo; Kim, Jin Kuk; Kang, Dong Jin; Bang, Dae-Suk


    Novel thermoplastic composites made from two major industrial and consumer wastes, fly ash and waste tire powder, have been developed. The effect of increasing fly ash loadings on performance characteristics such as tensile strength, thermal, dynamic mechanical and magnetic properties has been investigated. The morphology of the blends shows that fly ash particles have more affinity and adhesion towards the rubbery phase when compared to the plastic phase. The fracture surface of the composites shows extensive debonding of fly ash particles. Thermal analysis of the composites shows a progressive increase in activation energy with increase in fly ash loadings. Additionally, morphological studies of the ash residue after 90% thermal degradation shows extensive changes occurring in both the polymer and filler phases. The processing ability of the thermoplastics has been carried out in a Monsanto processability testing machine as a function of shear rate and temperature. Shear thinning behavior, typical of particulate polymer systems, has been observed irrespective of the testing temperatures. Magnetic properties and percolation behavior of the composites have also been evaluated.

  20. [Study on mercury re-emissions during fly ash utilization]. (United States)

    Meng, Yang; Wang, Shu-Xiao


    The amount of fly ash produced during coal combustion is around 400 million tons per year in China. About 65%-68% of fly ash is used in building material production, road construction, architecture and agriculture. Some of these utilization processes include high temperature procedures, which may lead to mercury re-emissions. In this study, experiments were designed to simulate the key process in cement production and steam-cured brick production. A temperature programmed desorption (TPD) method was used to study the mercury transformation in the major utilization processes. Mercury re-emission during the fly ash utilization in China was estimated based on the experimental results. It was found that mercury existed as HgCl2 (Hg2 Cl2), HgS and HgO in the fly ash. During the cement production process, more than 98% of the mercury in fly ash was re-emitted. In the steam-curing brick manufacturing process, the average mercury re-emission percentage was about 28%, which was dominated by the percentage of HgCl2 (Hg2 Cl2). It is estimated that the mercury re-emission during the fly ash utilization have increased from 4.07 t in 2002 to 9.18 t in 2008, of which cement industry contributes about 96.6%.


    Directory of Open Access Journals (Sweden)

    Jolanta Latosińska


    Full Text Available The study shows the results of zeolitization of municipal sewage sludge ash with the indirect fusion method followed by a hydrothermal method. The zeolitization of sewage sludge ash was conducted at the melting temperature of 550°C and the melting time of 60 minutes, crystallization temperatures of 60°C and 90°C, crystallization time of 6 hours and the SSA:NaOH ratio of 1:1.8; 1:1.4. The research of modified sewage sludge ashes included the observation of changes of ash particles surface and the identification of crystalized phases. The zeolitization of sewage sludge ash at the ratio of SSA:NaOH 1.0:1.4 did not cause the formation of zeolite phases. On the other hand, the zeolitization at the ratio of SSA:NaOH 1.0:1.8 resulted in the formation of desired zeolite phases such as zeolite Y (faujasite and hydroxysodalite. The presented method of sewage sludge ash zeolitization allows to obtain highly usable material. Synthesized zeolites may be used as adsorbents and ion exchangers. They can be potentially used to remove heavy metals as well as ammonia from water and wastewater.

  2. Ash transformation in suspension fired boilers co-firing coal and straw

    DEFF Research Database (Denmark)

    Zheng, Yuanjing; Jensen, Peter Arendt; Jensen, Anker Degn;

    The properties of the ash from co-firing of coal and straw have a large influence on boiler operation, flue gas cleaning equipment and appropriate utilization of the fly ash. A study on the fuel composition and local conditions influence on fly ash properties has been done by making entrained flow...... reactor experiments with co-firing of coal and straw, making mineral and alkali vapor laboratory reactor experiments and by developing a model of KCl reaction with kaolin. The results include correlations that can be used to estimate the speciation of potassium in the fly ash when co-firing straw...

  3. Convective heat transfer studies at high temperatures with pressure gradient for inlet flow Mach number of 0.45 (United States)

    Pedrosa, A. C. F.; Nagamatsu, H. T.; Hinckel, J. A.


    Heat transfer measurements were determined for a flat plate with and without pressure gradient for various free stream temperatures, wall temperature ratios, and Reynolds numbers for an inlet flow Mach number of 0.45, which is a representative inlet Mach number for gas turbine rotor blades. A shock tube generated the high temperature and pressure air flow, and a variable geometry test section was used to produce inlet flow Mach number of 0.45 and accelerate the flow over the plate to sonic velocity. Thin-film platinum heat gages recorded the local heat flux for laminar, transition, and turbulent boundary layers. The free stream temperatures varied from 611 R (339 K) to 3840 R (2133 K) for a T(w)/T(r,g) temperature ratio of 0.87 to 0.14. The Reynolds number over the heat gages varied from 3000 to 690,000. The experimental heat transfer data were correlated with laminar and turbulent boundary layer theories for the range of temperatures and Reynolds numbers and the transition phenomenon was examined.

  4. Deposition and immersion mode nucleation of ice by three distinct samples of volcanic ash using Raman spectroscopy (United States)

    Schill, G. P.; Genareau, K.; Tolbert, M. A.


    Ice nucleation on volcanic ash controls both ash aggregation and cloud glaciation, which affect atmospheric transport and global climate. Previously, it has been suggested that there is one characteristic ice nucleation efficiency for all volcanic ash, regardless of its composition, when accounting for surface area; however, this claim is derived from data from only two volcanic eruptions. In this work, we have studied the depositional and immersion freezing efficiency of three distinct samples of volcanic ash using Raman Microscopy coupled to an environmental cell. Ash from the Fuego (basaltic ash, Guatemala), Soufrière Hills (andesitic ash, Montserrat), and Taupo (Oruanui euption, rhyolitic ash, New Zealand) volcanoes were chosen to represent different geographical locations and silica content. All ash samples were quantitatively analyzed for both percent crystallinity and mineralogy using X-ray diffraction. In the present study, we find that all three samples of volcanic ash are excellent depositional ice nuclei, nucleating ice from 225-235 K at ice saturation ratios of 1.05 ± 0.01, comparable to the mineral dust proxy kaolinite. Since depositional ice nucleation will be more important at colder temperatures, fine volcanic ash may represent a global source of cold-cloud ice nuclei. For immersion freezing relevant to mixed-phase clouds, however, only the Oruanui ash exhibited heterogeneous ice nucleation activity. Similar to recent studies on mineral dust, we suggest that the mineralogy of volcanic ash may dictate its ice nucleation activity in the immersion mode.

  5. Preparation and characterization of the porous ceramics from fly ash

    Institute of Scientific and Technical Information of China (English)

    REN Xiang-jun; ZHANG Xue-bin; MENG Guang-yao; LIU Xing-qin


    Porous ceramics was made from coal fly ash,and the microstructure and other properties were characterized as a function of the amount of the pore-forming agent and firing temperature.The results indicated that the proper sintering temperature for the useful ceramic materials is 1250 ℃.and a liquid-phase was involved in the dansification process.

  6. Effects of wall shear stress on unsteady MHD conjugate flow in a porous medium with ramped wall temperature.

    Directory of Open Access Journals (Sweden)

    Arshad Khan

    Full Text Available This study investigates the effects of an arbitrary wall shear stress on unsteady magnetohydrodynamic (MHD flow of a Newtonian fluid with conjugate effects of heat and mass transfer. The fluid is considered in a porous medium over a vertical plate with ramped temperature. The influence of thermal radiation in the energy equations is also considered. The coupled partial differential equations governing the flow are solved by using the Laplace transform technique. Exact solutions for velocity and temperature in case of both ramped and constant wall temperature as well as for concentration are obtained. It is found that velocity solutions are more general and can produce a huge number of exact solutions correlative to various fluid motions. Graphical results are provided for various embedded flow parameters and discussed in details.

  7. Can pore-clogging by ash explain post-fire runoff? (United States)

    Stoof, Cathelijne R.; Gevaert, Anouk I.; Baver, Christine; Hassanpour, Bahareh; Morales, Veronica L.; Zhang, Wei; Martin, Deborah; Giri, Shree K.; Steenhuis, Tammo S.


    Ash plays an important role in controlling runoff and erosion processes after wildfire and has frequently been hypothesised to clog soil pores and reduce infiltration. Yet evidence for clogging is incomplete, as research has focussed on identifying the presence of ash in soil; the actual flow processes remain unknown. We conducted laboratory infiltration experiments coupled with microscope observations in pure sands, saturated hydraulic conductivity analysis, and interaction energy calculations, to test whether ash can clog pores (i.e. block pores such that infiltration is hampered and ponding occurs). Although results confirmed previous observations of ash washing into pores, clogging was not observed in the pure sands tested, nor were conditions found for which this does occur. Clogging by means of strong attachment of ash to sand was deemed unlikely given the negative surface charge of the two materials. Ponding due to washing in of ash was also considered improbable given the high saturated conductivity of pure ash and ash–sand mixtures. This first mechanistic step towards analysing ash transport and attachment processes in field soils therefore suggests that pore clogging by ash is unlikely to occur in sands. Discussion is provided on other mechanisms by which ash can affect post-fire hydrology.

  8. Effects of Straight and Serpentine Flow Field Designs on Temperature Distribution in Proton Exchange Membrane (PEM Fuel Cell

    Directory of Open Access Journals (Sweden)

    Zaman Izzuddin


    Full Text Available Proton exchange membrane fuel cells or sometimes called as polymer electrolyte membrane (PEM fuel cells is a device for energy transformation in a changing process from one form of energy to another form of energy. It became as an alternative especially for future use in stationary and vehicular applications. PEM fuel cells provide high efficiency and power density with null emission, low operating temperature, quickly start and long life. One of the aspects that are crucial in optimizing the PEM fuel cells performance is a flow field geometry. In this paper, a simulation case of PEM fuel cells was simulated to determine effects of a straight and serpentine flow field on temperature distribution in PEM fuel cells. ANSYS Fluent software was used to simulate 3-dimensional models of single PEM fuel cells in order to determine the effects of changes in the geometry flow field on temperature distributions. Results showed that the serpentine flow field design produces a better temperature distribution along the membrane. The simulation result shows a good agreement with the experiment, thus boost a higher confidence in the results to determine the effectiveness of the flow field design in PEM fuel cells.

  9. Production of fired construction brick from high sulfate-containing fly ash with boric acid addition. (United States)

    Başpinar, M Serhat; Kahraman, Erhan; Görhan, Gökhan; Demir, Ismail


    The increase of power plant capacity has led to the production of an increasing amount of fly ash that causes high environmental impact in Turkey. Some of the fly ash is utilized within the fired brick industry but high sulfate-containing fly ash creates severe problems during sintering of the fired brick. This study attempted to investigate the potential for converting high sulfate-containing fly ash into useful material for the construction industry by the addition of boric acid. The chemical and mineralogical composition of fly ash and clay were investigated. Boric acid (H(3)BO(3)) was added to fly ash-clay mixtures with up to 5 wt.%. Six different series of test samples were produced by uniaxial pressing. The samples were fired at the industrial clay-brick firing temperatures of 800, 900 and 1000 degrees C. The microstructures of the fired samples were investigated by scanning electron microscopy and some physical and mechanical properties were measured. It was concluded that the firing at conventional brick firing temperature of high sulfate fly ash without any addition of boric acid resulted in very weak strength bricks. The addition of boric acid and clay simultaneously to the high sulfate- containing fly ash brick dramatically increased the compressive strength of the samples at a firing temperature of 1000 degrees C by modifying the sintering behaviour of high sulfate fly ash.

  10. Volcanic ash vs. sand and dust - "to stick or not to stick" in jet engines (United States)

    Kueppers, U.; Song, W.; Lavallée, Y.; Hess, K. U.; Cimarelli, C.; Dingwell, D. B.


    Safe air travel activity requires clean flight corridors. But particles scattered in the atmosphere, whether volcanic ash, dust or sand, may present a critical threat to aviation safety. When these foreign particles are ingested into jet engines, whose interiors (e.g., the combustor and turbine blades) reach 1200-2000 °C, they can abrade, melt, and stick to the internal components of the engine, clogging ventilation traps of the cooling system as well as imparting substantial damage and potentially resulting in catastrophic system failure. To date, no criterion predicts ash behaviour at high temperature. Here, we experimentally develop the first quantitative model to predict melting and sticking conditions for the compositional range of volcanic ash encountered worldwide (Fig.1). The assumption that volcanic ash can be approximated by sand or dust is wholly inadequate, leading to an overestimation of sticking temperature and a correspondingly severe underestimation of the thermal hazard. Our findings confirm that the melting/softening behaviour of volcanic ash at high temperatures is essentially controlled by the composition of erupted ash - which may serve as an accurate proxy of the thermal hazard potential of volcanic ash interaction with jet engines. The criterion proposed here successfully parameterizes the potentially complex "melting" process of volcanic ash and can be used to assess the deposition probability of volcanic ash upon ingestion into hot jet engines.

  11. HIS 103 ASH course tutorial/tutorialoutlet


    NARESH 1


    For more course tutorials visit   HIS 103 Week 1 DQ 1 (Transition to Agriculture) (Ash) HIS 103 Week 1 DQ 2 (Early Complex Societies) (Ash) HIS 103 Week 1 Quiz (Ash) HIS 103 Week 1 Assignment (Ash) HIS 103 Week 2 Assignment Greco Roman Influence Paper (Ash) HIS 103 Week 2 DQ 1 Chinese Social and Political Order Systems (Ash) HIS 103 Week 2 DQ 2 Caste System (Ash) HIS 103 Week 2 Quiz (Ash) HIS 103 Week 3 Assignment Black Death Dra...

  12. Simultaneous measurements of temperature, density, and pressure in a supersonic turbulent flow using laser-induced fluorescence (United States)

    Mckenzie, R. L.; Gross, K. P.; Logan, P.


    A pulsed laser-induced fluorescence technique is described that provides simultaneous measurements of temperature, density, and pressure in low-temperature, turbulent flows. The measurements are made with spatial and temporal resolution comparable to that obtained with modern laser anemometer techniques used for turbulent boundary layer research. The capabilities of the method are briefly described and its demonstration in a simple two-dimensional turbulent boundary layer at Mach 2 is reported. The results are compared with conventional hot-wire anemometer data obtained in the same flow.

  13. Assessing the potential of coal ash and bagasse ash as inorganic amendments during composting of municipal solid wastes. (United States)

    Mohee, Romeela; Boojhawon, Anuksha; Sewhoo, Babita; Rungasamy, Selven; Somaroo, Geeta D; Mudhoo, Ackmez


    This study investigates the potential of incorporating inorganic amendments such as coal and bagasse ashes in different composting mixes. 10 different composting mixes were assessed as follows: A-20% bagasse ash (BA) with unsorted municipal solid wastes (UMSW); B-40% BA with UMSW; C-UMSW; D-20% BA with sorted municipal solid wastes (SMSW); E-40% BA with SMSW; F-SMSW; G-20% coal ash (CA) with UMSW; H-40% CA with UMSW; I-20% CA with SMSW and J-40% CA with SMSW. The composting processes were carried out in rotary drum composters. Composting mixes D, F, G and I achieved a temperature above 55 °C for at least 3 days, with the following peak temperatures: D-62 °C, F-57 °C, G-62 °C and I-58 °C. D resulted in the highest average net Volatile solids (VS) degradation of 68.6% and yielded the highest average volume reduction of 66.0%. The final compost from D, G, I, C and F were within range for electrical conductivities (EC) (794-1770 μS/cm) and pH (6.69-7.12). The ashes also helped in maintaining high average water holding capacities within the range of 183-217%. The C/N ratio of sorted wastes was improved by the addition of 20% coal ash and bagasse ash. Higher germination indices, above 0.8 were obtained for the ash-amended compost (D, G, I), indicating the feasibility and enhancement of using bagasse and coal ash as inorganic amendment in the composting process. Regarding heavy metals content, the chromium concentration for the composting mix G was found to be the highest whereas mixes D and I showed compliance with the MS (Mauritian Standards) 164 standards.

  14. Leaching from biomass combustion ash

    DEFF Research Database (Denmark)

    Maresca, Alberto; Astrup, Thomas Fruergaard


    The use of biomass combustion ashes for fertilizing and liming purposes has been widely addressed in scientific literature. Nevertheless, the content of potentially toxic compounds raises concerns for a possible contamination of the soil. During this study five ash samples generated at four...

  15. Emerald Ash Borer (Coleoptera: Buprestidae) (United States)

    The emerald ash borer, Agrilus planipennis Fairmaire, is an invasive beetle from Asia that has caused large scale ash (Fraxinus spp.) mortality in North America. This book chapter reviews the taxonomy, biology, life history of this invasive pest and its associated natural enemies in both its native ...

  16. Study on the Volatility of Cesium in Dry Ashing Pretreatment and Dissolution of Ash by Microwave Digestion System - 13331

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Kwang-Soon; Lee, Chang Heon; Ahn, Hong-Joo; Park, Yong Joon; Song, Kyuseok [Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Daedeok-daero 989-111, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)


    Based on the regulation of the activity concentration of Cs-137, Co-58, Co-60, Fe-55, Ni-59, Ni-63, Sr-90, Nb-94, and Tc-99, and the total alpha from the radioactive waste acceptance criteria, the measurement of the activity concentration of these nuclides in low and intermediate levels of radioactive waste such as in paper, cotton, vinyl and plastic samples was investigated. A dry ashing method was applied to obtain a concentration effect of the samples. Owing to the temperature dependence of the volatility for cesium, the temperature of 300 to 650 deg. C was examined. It was found that 450 deg. C is the optimum dry ashing temperature. After dry ashing, the produced ash was dissolved with HNO{sub 3}, HCl, and HF by a high-performance microwave digestion system. The ash sample, for the most part, was completely dissolved with 10 mL of HNO{sub 3}, 4 mL of HCl, and 0.25 mL of HF by a high-performance microwave digestion system using a nova high temperature rotor at 250 deg. C for 90 min until reaching 0.2 g. To confirm the reliability of cesium loss after the performance of the dry ashing procedure, a cesium standard solution for AAS and a Cs-137 standard solution for gamma spectrometry were added to a paper towel or a planchet of stainless steel, respectively. Cesium was measured by AAS, ICP-MS, and gamma spectrometry. The volatility of cesium did not occur until 450 deg. C ashing. (authors)

  17. An atmospheric pressure high-temperature laminar flow reactor for investigation of combustion and related gas phase reaction systems

    Energy Technology Data Exchange (ETDEWEB)

    Oßwald, Patrick; Köhler, Markus [Institute of Combustion Technology, German Aerospace Center (DLR), Pfaffenwaldring 38-40, D-70569 Stuttgart (Germany)


    A new high-temperature flow reactor experiment utilizing the powerful molecular beam mass spectrometry (MBMS) technique for detailed observation of gas phase kinetics in reacting flows is presented. The reactor design provides a consequent extension of the experimental portfolio of validation experiments for combustion reaction kinetics. Temperatures up to 1800 K are applicable by three individually controlled temperature zones with this atmospheric pressure flow reactor. Detailed speciation data are obtained using the sensitive MBMS technique, providing in situ access to almost all chemical species involved in the combustion process, including highly reactive species such as radicals. Strategies for quantifying the experimental data are presented alongside a careful analysis of the characterization of the experimental boundary conditions to enable precise numeric reproduction of the experimental results. The general capabilities of this new analytical tool for the investigation of reacting flows are demonstrated for a selected range of conditions, fuels, and applications. A detailed dataset for the well-known gaseous fuels, methane and ethylene, is provided and used to verify the experimental approach. Furthermore, application for liquid fuels and fuel components important for technical combustors like gas turbines and engines is demonstrated. Besides the detailed investigation of novel fuels and fuel components, the wide range of operation conditions gives access to extended combustion topics, such as super rich conditions at high temperature important for gasification processes, or the peroxy chemistry governing the low temperature oxidation regime. These demonstrations are accompanied by a first kinetic modeling approach, examining the opportunities for model validation purposes.

  18. The Low Temperature Oxidation of 2,7-Dimethyloctane in a Pressurized Flow Reactor (United States)

    Farid, Farinaz

    The complexity of real fuels has fostered the use of simple mixtures of hydrocarbons whose combustion behavior approximates that of real fuels in both experimental and computational studies to develop models of the combustion of the real fuel. These simple mixtures have been called surrogates. Lightly branched paraffins are an important class of constituents in gasoline, diesel and aviation turbine fuels and therefore are primary candidates for use as a component in a surrogate. Unfortunately, fundamental studies on combustion characteristics of high molecular weight mono- and di-methylated iso-paraffins are scarce. Therefore, this study was designed to investigate the low-temperature oxidation of 2,7-dimethyloctane (2,7-DMO) (C10H22), a lightly branched isomer of decane. Replicate 2,7-DMO oxidation experiments were conducted in a pressurized flow reactor (PFR) over the temperature range of 550 -- 850 K, at a pressure of 8 atm and an equivalence ratio of 0.3 in 4.21% oxygen / nitrogen. The reactivity was mapped by continuous monitoring of CO, CO 2, and O2 using a non-dispersive infrared (NDIR) carbon monoxide / carbon dioxide analyzer and an electrochemical oxygen sensor. For examining the underlying reaction chemistry, detailed speciation of samples was performed at selected temperatures using a gas chromatograph with a flame ionization detector coupled to a mass spectrometer. Comparable oxidation experiments for n-decane were carried out to examine the unique effects of branching on fuel reactivity and distribution of major stable intermediates. For both isomers, the onset of negative temperature coefficient (NTC) region was observed near 700 K, with the reactivity decreasing with increasing the temperature. The flow reactor study of n-decane oxidation confirmed that the isomerization reduces the amount of CO produced at peak reactivity. In addition to reaction inhibition, branching affected the distribution of C2-C 4 olefin intermediates. While the oxidation of

  19. Prediction total specific pore volume of geopolymers produced from waste ashes by fuzzy logic

    Directory of Open Access Journals (Sweden)

    Ali Nazari


    Full Text Available In the present work, total specific pore volume of inorganic polymers (geopolymers made from seeded fly ash and rice husk bark ash has been predicted by fuzzy logic. Different specimens, made from a mixture of fly ash and rice husk bark ash in fine and coarse form together with alkali activator made of water glass and NaOH solution, were subjected to porosimetry tests at 7 and 28 days of curing. The curing regime was different: one set of the specimens were cured at room temperature until reaching to 7 and 28 days and the other sets were oven cured for 36 hours at the range of 40-90 °C and then cured at room temperature until 7 and 28 days. A model based on fuzzy logic for predicting the total specific pore volume of the specimens has been presented. To build the model, training and testing using experimental results from 120 specimens were conducted. The used data as the inputs of fuzzy logic models are arranged in a format of six parameters that cover the percentage of fine fly ash in the ashes mixture, the percentage of coarse fly ash in the ashes mixture, the percentage of fine rice husk bark ash in the ashes mixture, the percentage of coarse rice husk bark ash in the ashes mixture, the temperature of curing and the time of water curing. According to the input parameters, in the fuzzy logic model, the pore volume of each specimen was predicted. The training and testing results in the fuzzy logic model have shown a strong potential for predicting the total specific pore volume of the geopolymer specimens in the considered range.

  20. Experimental and numerical investigations of high temperature gas heat transfer and flow in a VHTR reactor core (United States)

    Valentin Rodriguez, Francisco Ivan

    High pressure/high temperature forced and natural convection experiments have been conducted in support of the development of a Very High Temperature Reactor (VHTR) with a prismatic core. VHTRs are designed with the capability to withstand accidents by preventing nuclear fuel meltdown, using passive safety mechanisms; a product of advanced reactor designs including the implementation of inert gases like helium as coolants. The present experiments utilize a high temperature/high pressure gas flow test facility constructed for forced and natural circulation experiments. This work examines fundamental aspects of high temperature gas heat transfer applied to VHTR operational and accident scenarios. Two different types of experiments, forced convection and natural circulation, were conducted under high pressure and high temperature conditions using three different gases: air, nitrogen and helium. The experimental data were analyzed to obtain heat transfer coefficient data in the form of Nusselt numbers as a function of Reynolds, Grashof and Prandtl numbers. This work also examines the flow laminarization phenomenon (turbulent flows displaying much lower heat transfer parameters than expected due to intense heating conditions) in detail for a full range of Reynolds numbers including: laminar, transition and turbulent flows under forced convection and its impact on heat transfer. This phenomenon could give rise to deterioration in convection heat transfer and occurrence of hot spots in the reactor core. Forced and mixed convection data analyzed indicated the occurrence of flow laminarization phenomenon due to the buoyancy and acceleration effects induced by strong heating. Turbulence parameters were also measured using a hot wire anemometer in forced convection experiments to confirm the existence of the flow laminarization phenomenon. In particular, these results demonstrated the influence of pressure on delayed transition between laminar and turbulent flow. The heat

  1. Coal fly ash interaction with environmental fluids: Geochemical and strontium isotope results from combined column and batch leaching experiments

    Energy Technology Data Exchange (ETDEWEB)

    Brubaker, Tonya M; Stewart, Brian W; Capo, Rosemary C; Schroeder, Karl T; Chapman, Elizabeth C; Spivak-Birndorf, Lev J; Vesper, Dorothy J; Cardone, Carol R; Rohar, Paul C


    The major element and Sr isotope systematics and geochemistry of coal fly ash and its interactions with environmental waters were investigated using laboratory flow-through column leaching experiments (sodium carbonate, acetic acid, nitric acid) and sequential batch leaching experiments (water, acetic acid, hydrochloric acid). Column leaching of Class F fly ash samples shows rapid release of most major elements early in the leaching procedure, suggesting an association of these elements with soluble and surface bound phases. Delayed release of certain elements (e.g., Al, Fe, Si) signals gradual dissolution of more resistant silicate or glass phases as leaching continues. Strontium isotope results from both column and batch leaching experiments show a marked increase in {sup 87}Sr/{sup 86}Sr ratio with continued leaching, yielding a total range of values from 0.7107 to 0.7138. For comparison, the isotopic composition of fluid output from a fly ash impoundment in West Virginia falls in a narrow range around 0.7124. The experimental data suggest the presence of a more resistant, highly radiogenic silicate phase that survives the combustion process and is leached after the more soluble minerals are removed. Strontium isotopic homogenization of minerals in coal does not always occur during the combustion process, despite the high temperatures encountered in the boiler. Early-released Sr tends to be isotopically uniform; thus the Sr isotopic composition of fly ash could be distinguishable from other sources and is a useful tool for quantifying the possible contribution of fly ash leaching to the total dissolved load in natural surface and ground waters.

  2. Temporal and spatial variations in fly ash quality (United States)

    Hower, J.C.; Trimble, A.S.; Eble, C.F.


    Fly ash quality, both as the amount of petrographically distinguishable carbons and in chemistry, varies in both time and space. Temporal variations are a function of a number of variables. Variables can include variations in the coal blend organic petrography, mineralogy, and chemistry; variations in the pulverization of the coal, both as a function of the coal's Hardgrove grindability index and as a function of the maintenance and settings of the pulverizers; and variations in the operating conditions of the boiler, including changes in the pollution control system. Spatial variation, as an instantaneous measure of fly ash characteristics, should not involve changes in the first two sets of variables listed above. Spatial variations are a function of the gas flow within the boiler and ducts, certain flow conditions leading to a tendency for segregation of the less-dense carbons in one portion of the gas stream. Caution must be applied in sampling fly ash. Samples from a single bin, or series of bins, m ay not be representative of the whole fly ash, providing a biased view of the nature of the material. Further, it is generally not possible to be certain about variation until the analysis of the ash is complete. ?? 2001 Elsevier Science B.V. All rights reserved.

  3. Influence of Coal Blending on Ash Fusibility in Reducing Atmosphere

    Directory of Open Access Journals (Sweden)

    Mingke Shen


    Full Text Available Coal blending is an effective way to organize and control coal ash fusibility to meet different requirements of Coal-fired power plants. This study investigates three different eutectic processes and explains the mechanism of how coal blending affects ash fusibility. The blended ashes were prepared by hand-mixing two raw coal ashes at five blending ratios, G:D = 10:90 (G10D90, G:D= 20:80 (G20D80, G:D = 30:70 (G30D70, G:D = 40:60 (G40D60, and G:D = 50:50 (G50D50. The samples were heated at 900 °C, 1000 °C, 1100 °C, 1200 °C, and 1300 °C in reducing atmosphere. XRD and SEM/EDX were used to identify mineral transformations and eutectic processes. The eutectic processes were finally simulated with FactSage. Results show that the fusion temperatures of the blended ashes initially decrease and then increase with the blending ratio, a trend that is typical of eutectic melting. Eutectic phenomena are observed in D100, G10D90, and G30D70 in different degrees, which do not appear in G100 and G50D50 for the lack of eutectic reactants. The main eutectic reactants are gehlenite, magnetite, merwinite, and diopside. The FactSage simulation results show that the content discrepancy of merwinite and diopside in the ashes causes the inconsistent eutectic temperatures and eutectic degrees, in turn decrease the fusion temperature of the blended ash and then increase them with the blending ratio.

  4. A fine-wire thermocouple probe for measurement of stagnation temperatures in real gas hypersonic flows of nitrogen (United States)

    Hollis, Brian R.; Griffith, Wayland C.; Yanta, William J.


    A fine-wire thermocouple probe was used to determine freestream stagnation temperatures in hypersonic flows. Data were gathered in a N2 blowdown wind tunnel with runtimes of 1-5 s. Tests were made at supply pressures between 30 and 1400 atm and supply temperatures between 700 and 1900 K, with Mach numbers of 14 to 16. An iterative procedure requiring thermocouple data, pilot pressure measurements, and supply conditions was used to determine test cell stagnation temperatures. Probe conduction and radiation losses, as well as real gas behavior of N2, were accounted for during analysis. Temperature measurement error was found to be 5 to 10 percent. A correlation was drawn between thermocouple diameter Reynolds number and temperature recovery ratio. Transient probe behavior was studied and was found to be adequate in temperature gradients up to 1000 K/s.

  5. Simultaneous measurement of temperature and velocity of air flow over 1000°C using two color phosphor thermometry (United States)

    Fukuta, Masatoshi; Someya, Satoshi; Munakata, Tetsuo; LCS Team


    Thermal barrier coatings were applied to the gas turbines and the internal combustion engines for the high thermal efficiency. The evaluation and the improvement of coatings require to measure transient gaseous flow near the wall with coatings. An aim of this study is to combine a two color phosphor thermometry with the PIV to measure simultaneously temperature and velocity of the gas over 1000°C. The temperature and velocity distribution of an impinging jet of high temperature air was simultaneously visualized in experiments. The temperature was estimated from an intensity ratio of luminescent in different ranges of wavelength, 500 600 nm and 400 480 nm. Uncertainty of measured temperature was less than 10°C. Temperatures measured by the developed method and by thermocouples were agreed well. The measured velocity by the PIV with phosphor particles were also agreed well with the velocity measured by a Laser Doppler Velocimeter.

  6. Emplacement temperatures of the November 22, 1994 nuee ardente deposits, Merapi Volcano, Java (United States)

    Voight, B.; Davis, M.J.


    A study of emplacement temperatures was carried out for the largest of the 22 November 1994 nuée ardente deposits at Merapi Volcano, based mainly on the response of plastic and woody materials subjected to the hot pyroclastic current and the deposits, and to some extent on eyewitness observations. The study emphasizes the Turgo–Kaliurang area in the distal part of the area affected by the nuée ardente, where nearly 100 casualties occurred. The term nuée ardente as used here includes channeled block-and-ash flows, and associated ash-clouds of surge and fallout origins. The emplacement temperature of the 8 m thick channeled block-and-ash deposit was relatively high, ∼550°C, based mainly on eyewitness reports of visual thermal radiance. Emplacement temperatures for ash-cloud deposits a few cm thick were deduced from polymer objects collected at Turgo and Kaliurang. Most polymers do not display a sharp melting range, but polyethylene terephthalate used in water bottles melts between 245 and 265°C, and parts of the bottles that had been deformed during fabrication molding turn a milky color at 200°C. The experimental evidence suggests that deposits in the Turgo area briefly achieved a maximum temperature near 300°C, whereas those near Kaliurang were <200°C. Maximum ash deposit temperatures occurred in fallout with a local source in the channeled block-and-ash flow of the Boyong river valley; the surge deposit was cooler (∼180°C) due to entrainment of cool air and soils, and tree singe-zone temperatures were around 100°C.

  7. Thermodynamic Characteristic Study of a High-temperature Flow-rate Control Valve for Fuel Supply of Scramjet Engines

    Institute of Scientific and Technical Information of China (English)

    ZENG Wen; TONG Zhizhong; LI Songjing; LI Hongzhou; ZHANG Liang


    Thermodynamic characteristics are of great importance for the performance of a high-temperature flow-rate control valve,as high-temperature environment may bring problems,such as blocking of spool and increasing of leakage,to the valve.In this paper,a high-temperature flow-rate control valve,pilot-controlled by a pneumatic servo system is developed to control the fuel supply for scramjet engines.After introducing the construction and working principle,the thermodynamic mathematical models of the valve are built based on the heat transfer methods inside the valve.By using different boundary conditions,different methods of simulations are carried out and compared.The steady-state and transient temperature field distribution inside the valve body are predicted and temperatures at five interested points are measured.By comparing the simulation and experimental results,a reasonable 3D finite element analysis method is suggested to predict the thermodynamic characteristics of the high-temperature flow-rate control valve.

  8. On Mattering: A Coal Ash Flood and the Limits of Environmental Knowledge

    Directory of Open Access Journals (Sweden)

    Hatmaker, Susie


    Full Text Available This paper investigates the largest flood of coal ash in United States history as an event at once monumental and insignificant. It traces affective forces generative of both the ash, and its invisibility. In the moment of rupture, the ash flowed out of a large holding pond in a spill of layered sediments – each layer of particulate a temporary resting place for a forceful trajectory of matter spurned into motion elsewhere in space and time. This paper takes up the atemporal matter of this coal ash flood to ask: out of what movements and connections was the ash formed? How did this particular landscape change to accommodate its accumulation? What trajectories flowed into the pond, and what hidden memories sat buried in its mass? Drawing on ethnographic and archival research, this paper weaves together juxtaposed scenes that form (some of the backstory of this event, and invites a reconsideration of the practices of knowledge that helped condition it.

  9. Binary effect of fly ash and palm oil fuel ash on heat of hydration aerated concrete. (United States)

    Mehmannavaz, Taha; Ismail, Mohammad; Radin Sumadi, Salihuddin; Rafique Bhutta, Muhammad Aamer; Samadi, Mostafa; Sajjadi, Seyed Mahdi


    The binary effect of pulverized fuel ash (PFA) and palm oil fuel ash (POFA) on heat of hydration of aerated concrete was studied. Three aerated concrete mixes were prepared, namely, concrete containing 100% ordinary Portland cement (control sample or Type I), binary concrete made from 50% POFA (Type II), and ternary concrete containing 30% POFA and 20% PFA (Type III). It is found that the temperature increases due to heat of hydration through all the concrete specimens especially in the control sample. However, the total temperature rises caused by the heat of hydration through both of the new binary and ternary concrete were significantly lower than the control sample. The obtained results reveal that the replacement of Portland cement with binary and ternary materials is beneficial, particularly for mass concrete where thermal cracking due to extreme heat rise is of great concern.

  10. Relaxation and Flow of Polymer Thin Films in Isothermal Temperature Jump Measurements (United States)

    Beaucage, G.; Banach, M. J.; Vaia, R. A.


    The dynamic behavior of thin polymer films is of interest in fabrication of microelectronics, optoelectronics and for the coatings industry. It is known that polymer relaxation is effected by film thickness and by the particular substrate/polymer pair. Recently, we have used a spectroscopic ellipsometer to investigate the glass transition in thin films. In addition to information on modification of thermal transitions, the spectroscopic ellipsometer allows for direct observation of the isothermal dimensions of a thin polymer film as a function of time following a rapid temperature change. Recent results will be presented on the observation of time dependence in film-normal thickness and normalized, in-plane, lateral dimension (explained in talk) as well as simple fits to this relaxation behavior in terms of a normalized viscosity and relaxation time. Initial results support a highly asymmetric initial thermal expansion followed by close to isotropic relaxation and anisotropic flow. These features may elucidate models for chain orientation in thin polymer films. Beaucage, G.; Composto, R.; Stein, R.S. (1993). J. Poly. Sci., Polym. Phys. Ed., 31 319. Kovacs, A. J.; Hutchinson, J. M.; Aklonis, J. J. (1977) in "The Structure of Non-Crystalline Materials", Ed. P. H. Gaskell, Taylor and Francis, London. Banach, M. J.; Clarson, S. J.; Beaucage, G.; Kramer, E. J.; Benkoski, J.; Vaia, R. Submitted Macromolecules (1999). Beaucage, G.; Banach, M. J.; Vaia, R. A. Submitted Macromolecules (1999).

  11. Modeling and measuring neighborhood scale flow, turbulence, and temperature within Chicago heat island (United States)

    Conry, Patrick; Sharma, Ashish; Leo, Laura; Fernando, H. J. S.; Potosnak, Mark; Hellmann, Jessica


    The modeling of urban heat island (UHI) requires a multi-scale approach as it involves numerous physical phenomena spanning a range of scales. We have performed a comprehensive study of Chicago's UHI via coupling of mesoscale Weather Research and Forecasting (WRF) and micro-scale ENVI-met models. The application of the latter model to a Lincoln Park neighborhood and a parallel observational campaign will be the primary focus of this presentation. ENVI-met employs a computational fluid dynamics model to represent heterogeneity of urban areas, providing fine resolution output of UHI dynamics. In the field campaign, two stations located on rooftops of DePaul University buildings were each equipped with a sonic anemometer and vertical array of thermocouples, allowing investigations of spatial variability of flow, turbulent fluxes, and temperature profiles in an urban roughness sublayer. One of these was located above a rooftop garden and the other above a conventional rooftop. Downscaled output from the WRF model or a set of observational data served as initial and boundary conditions for the ENVI-met model. The model's predicative capabilities were assessed through comparison with another set of observational data, and dynamical causes for the model's poor behavior were identified. Funded by NSF Grant No. 0934592 and ND-ECI.

  12. Producing a synthetic zeolite from secondary coal fly ash. (United States)

    Zhou, Chunyu; Yan, Chunjie; Zhou, Qi; Wang, Hongquan; Luo, Wenjun


    Secondary coal fly ash is known as a by-product produced by the extracting alumina industry from high-alumina fly ash, which is always considered to be solid waste. Zeolitization of secondary coal fly ash offers an opportunity to create value-added products from this industrial solid waste. The influence of synthesis parameters on zeolite NaA such as alkalinity, the molar ratio of SiO2/Al2O3, crystallization time and temperature was investigated in this paper. It was found that the types of synthetic zeolites produced were to be highly dependent on the conditions of the crystallization process. Calcium ion exchange capacity and whiteness measurements revealed that the synthesized product meets the standard for being used as detergent, indicating a promising use as a builder in detergent, ion-exchangers or selective adsorbents. Yield of up to a maximum of 1.54 g/g of ash was produced for zeolite NaA from the secondary coal fly ash residue. This result presents a potential use of the secondary coal fly ash to obtain a high value-added product by a cheap and alternative zeolitization procedure.

  13. Formation of Humic Substances in Weathered MSWI Bottom Ash

    Directory of Open Access Journals (Sweden)

    Haixia Zhang


    Full Text Available The study aimed at evaluating the humic substances (HSs content from municipal solid waste incinerator (MSWI bottom ash and its variation with time and the effect of temperature on HSs formation. The process suggested by IHSS was applied to extract HSs from two different bottom ash samples, and the extracted efficiency with NaOH and Na4P2O7 was compared. MSWI bottom ash samples were incubated at 37∘C and 50∘C for 1 year. HSs and nonhumic substances were extracted from the bottom ash sample with different incubated period by 0.1 M NaOH/Na4P2O7. Results show that the rate of humic acid formation increased originally with incubation time, reached a maximum at 12th week under 37∘C and at 18th week under 50∘C, and then decreased with time. More humic acid in MSWI bottom ash was formed under 50∘C incubated condition compared with that incubated under 37∘C. Also, the elemental compositions of HSs extracted from bottom ash are reported.

  14. Damping properties of fly ash/epoxy composites

    Institute of Scientific and Technical Information of China (English)

    Jian Gu; Gaohui Wu; Xiao Zhao


    An inexpensive fly ash (FA), which is from a waste product, was employed to prepare fly ash/epoxy composites. The purpose of this study is to characterize the contributions of matrix viscoelasticity, hollow structure characteristic (porosity), and filler/matrix interface friction to the high vibration damping capacity of such composites. The damping properties of the composites were investigated in the temperature range of-40 to 150℃C and in the frequency range of 10 to 800 Hz by using a tension-compression mode. The results indicate that the peak value of damping loss factor (tanδ) for the fly ash/epoxy composites can reach 0.70-0.90 in test specification, and the attenuation of damping loss factor is inconspicuous with increasing frequency. In addition, scanning electron microscope (SEM) was used to observe the morphology of the fly ash as well as its distribution in the matrix, which will help to analyze the effect of fly ash on the damping properties of the fly ash/epoxy composites.

  15. Analysis of Fluid Flow and Heat Transfer Model for the Pebble Bed High Temperature Gas Cooled Reactor

    Directory of Open Access Journals (Sweden)

    S. Yamoah


    Full Text Available The pebble bed type high temperature gas cooled nuclear reactor is a promising option for next generation reactor technology and has the potential to provide high efficiency and cost effective electricity generation. The reactor unit heat transfer poses a challenge due to the complexity associated with the thermalflow design. Therefore to reliably simulate the flow and heat transport of the pebble bed modular reactor necessitates a heat transfer model that deals with radiation as well as thermal convection and conduction. In this study, a model with the capability to simulate fluid flow and heat transfer in the pebble bed modular reactor core has been developed. The developed model was implemented on a personal computer using FORTRAN 95 programming language. Several important fluid flow and heat transfer parameters have been examined: including the pressure drop over the reactor core, the heat transfer coefficient, the Nusselt number and the effective thermal conductivity of the fuel pebbles. Results obtained from the simulation experiments show a uniform pressure in the radial direction for a core to fuel element diameter (D/d ratio>20 and the heat transfer coefficient increases with increasing temperature and coolant mass flow rate. The model can adequately account for the flow and heat transfer phenomenon and the loss of pressure through friction in the pebble bed type high temperature nuclear reactor.

  16. Pure zeolite synthesis from silica extracted from coal fly ashes

    Energy Technology Data Exchange (ETDEWEB)

    Moreno, N.; Querol, X.; Plana, F.; Andres, J.M.; Janssen, M.; Nugteren, H. [CSIC, Barcelona (Spain). Inst. Earth Science ' Jaume Almera'


    Pure zeolites can be synthesised from silica extracted from fly ash by alkaline leaching. If the process is optimised the solid residue arising from this extraction may also contain a relatively high content of zeolitic material mixed with residual fly ash components. Both the pure and the impure zeolitic material have a high potential for application in waste-water and flue gas-cleaning technologies. The silica extraction potential of 23 European coal fly ashes covering most of the possible fly ash types is investigated in this study. Optimisation of leaching processes, by varying temperature, time and alkali/fly ash rates, permitted extraction yields up to 140 g of SiO{sub 2} per kg using a single step process, but the extraction yields may reach up to 210 g kg{sup -1} by applying thermal pre-treatments prior to the extraction. The solid residue arising from the silica extraction experiments shows a high NaP1 zeolite content. A high Si/Al ratio of the glass matrix, the occurrence of easily soluble silica phases in the original fly ash and a high reactive surface area were found to be the major parameters influencing silica extraction. High purity 4A and X zeolitic material was obtained by combining the silica extracts from the Meirama fly ash and a waste solution from the Al-anodising industry. The results allowed conversion of the silica extraction yields to an equivalent 630 g of pure 4A-X zeolite per kg of fly ash with a cation exchange capacity of 4.7 meq g{sup -1}.

  17. Exergy analysis of integrated photovoltaic thermal solar water heater under constant flow rate and constant collection temperature modes

    NARCIS (Netherlands)

    Tiwari, Arvind; Dubey, Swapnil; Sandhu, G.S.; Sodha, M.S.; Anwar, S.I.


    In this communication, an analytical expression for the water temperature of an integrated photovoltaic thermal solar (IPVTS) water heater under constant flow rate hot water withdrawal has been obtained. Analysis is based on basic energy balance for hybrid flat plate collector and storage tank, resp

  18. Convective heat transfer by oscillating flow in an enclosure with non-uniform spatial bottom wall temperature profile (United States)

    Raheimpour Angeneh, Saeid; Aktas, Murat Kadri


    Effects of the acoustic streaming motion on convective heat transfer in a rectangular shallow enclosure with sinusoidal spatial bottom wall temperature distribution are investigated numerically. Acoustic excitation is generated by the periodic vibration of left wall. The top wall of the enclosure is isothermal while the side walls are adiabatic. A FORTRAN code is developed to predict the oscillatory and mean flow fields by considering the compressible form of the Navier -Stokes equation and solved by flux-corrected transport algorithm. In order to validate the results of the simulations, a case with an unheated bottom wall is considered and compared with the existing literature. Applying the sinusoidal temperature profile to the bottom wall provides axial and transverse temperature gradients. In return these gradients strongly affect the flow pattern in the enclosure. Heat transfer depends on the flow structure considerably. This is the first time that the effect of nonzero mean vibrational flow on thermal convection from a surface with sinusoidal temperature profile investigated. Results of this study may lead up to design of new heat removal applications.

  19. Free Convective Fluctuating MHD Flow through Porous Media Past a Vertical Porous Plate with Variable Temperature and Heat Source

    Directory of Open Access Journals (Sweden)

    A. K. Acharya


    Full Text Available Free convective magnetohydrodynamics (MHD flow of a viscous incompressible and electrically conducting fluid past a hot vertical porous plate embedded i