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Sample records for arsenious quaternary aquifer

  1. Isotopic and chemical investigations of quaternary aquifer in sinai peninsula

    International Nuclear Information System (INIS)

    Sadek, M.A.; Ahmed, M.A.; Awad, M.A.

    2001-01-01

    The present study has been conducted to investigate the renewal activity and mineralization potential of the quaternary aquifer in Sinai peninsula using environmental isotopes and hydrochemistry. The quaternary aquifer is vital for development processes as it has a wide extension and shallow water table. The total dissolved salts vary greatly from one location to another and range widely between 510-7060 mg/1, reflecting all categories from fresh to saline water. The change in salinity all over Sinai can be attributed to variations in the rate of evaporation. Leaching and dissolution of terrestrial salts during floods as well as the effects of sea spray and saline water intrusion. The main sources of groundwater recharge are the infiltration of Local precipitation and surface runoff as well as lateral flow through hydraulic connection with fractured aquifers. Snow melt also contributes to aquifer recharge in some areas in the central part of southern Sinai. The environmental stable isotopic contents of the ground water in the quaternary aquifer in Sinai reflect the isotopic composition of rain water from continental and east Mediterranean precipitation and monsonal air mass which comes from Indian ocean as well as the seepage of partly evaporated floodwater. The southern samples are more suitable for drinking and irrigation purposes due to its lower salinity and sodium hazard

  2. Quaternary climatic variability in the Tarat aquifer (Arlit, Niger)

    International Nuclear Information System (INIS)

    Dodo, A.; Zuppi, G.M.

    1999-01-01

    The concentration of major elements and environmental isotopes in the Carboniferous (Guezouman and Tarat), Triassic (Teloua) and Quaternary aquifers allows to describe the ground-water flow and to define the upward leakage. 18 O and 2 H in water samples from Guezouman and some Tarat aquifers fall on a regressive line with the equation, δ 2 H (8.01±0.50) δ 18 O + (3.85±3.56), similar to that found for old groundwater in the northern and southern Sahara. The isotopic difference between the Arlit area and the easterly Djado basin groundwater results from the combined effects of continentality and altitude on meteoric waters. The carbon 14 ages, the palaeo-temperatures evaluated from oxygen 18 and nitrate contents in the Tarat aquifer show climatic variations consisting of two humid periods at 10 000 and 30 000 years separated by a warmer period at 25 000. The mean temperatures of the palaeo-recharge, estimated using oxygen 18 data, are 18 deg C during the Holocene, 20 deg C at 25 000 years and 16 deg C at 30 000 years. Water infiltrating during the warming period shows 79 mg L -1 nitrates. High nitrates could be due to an important meteorological event which entrained and stored organic matter from the surface vegetation and soil by infiltration. (authors)

  3. Evaluation of quaternary aquifer between qena and luxur. (Nile Valley, Egypt)

    OpenAIRE

    Mohamaden, Mahmoud Ismail Ismail [محمود اسماعيل اسماعيل محمدين

    2001-01-01

    In order to evaluate the hydrogeological setting of the Quaternary aquifer and the related geological structures controlling its characteristics. A total of 50 vertical electrical soundings (VES.s) were conducted along 13 profiles covering the area between Qena and Luxur. As revealed from the present study, the Quaternary section in the area is subdivided into four main geoelectrical zones distributed irregularly in the study area: Zone (A) with very high electrical resistivity values rang...

  4. Water-quality characteristics of quaternary unconsolidated-deposit aquifers and lower tertiary aquifers of the Bighorn Basin, Wyoming and Montana, 1999-2001

    Science.gov (United States)

    Bartos, Timothy T.; Eddy-Miller, Cheryl A.; Norris, Jody R.; Gamper, Merry E.; Hallberg, Laura L.

    2004-01-01

    As part of the Yellowstone River Basin National Water Quality Assessment study, ground-water samples were collected from Quaternary unconsolidated-deposit and lower Tertiary aquifers in the Bighorn Basin of Wyoming and Montana from 1999 to 2001. Samples from 54 wells were analyzed for physical characteristics, major ions, trace elements, nutrients, dissolved organic carbon, radionuclides, pesticide compounds, and volatile organic compounds (VOCs) to evaluate current water-quality conditions in both aquifers. Water-quality samples indicated that waters generally were suitable for most uses, and that natural conditions, rather than the effects of human activities, were more likely to limit uses of the waters. Waters in both types of aquifers generally were highly mineralized, and total dissolved-solids concentrations frequently exceeded the U.S. Environmental Protection Agency (USEPA) Secondary Maximum Contaminant Level (SMCL) of 500 milligrams per liter (mg/L). Because of generally high mineralization, waters from nearly one-half of the samples from Quaternary aquifers and more than one-half of the samples from lower Tertiary aquifers were not classified as fresh (dissolved-solids concentration were not less than 1,000 mg/L). The anions sulfate, fluoride, and chloride were measured in some ground-water samples at concentrations greater than SMCLs. Most waters from the Quaternary aquifers were classified as very hard (hardness greater than 180 mg/L), but hardness varied much more in waters from the lower Tertiary aquifers and ranged from soft (less than 60 mg/L) to very hard (greater than 180 mg/L). Major-ion chemistry varied with dissolved-solids concentrations. In both types of aquifers, the predominant anion changes from bicarbonate to sulfate with increasing dissolved-solids concentrations. Samples from Quaternary aquifers with fresh waters generally were calcium-bicarbonate, calcium-sodium-bicarbonate, and calcium-sodium-sulfate-bicarbonate type waters, whereas

  5. Hydrogeological Investigations of the Quaternary Aquifeer in the Northern Part of El-Sharkia Governorate, Egypt

    International Nuclear Information System (INIS)

    El-Sayed, S.A.; Ezz El Din, M.R.; Deyab, M.E.

    2011-01-01

    The hydraulic characteristics of surficial soils and materials of the Quaternary aquifer in the northern part of El-Sharkia Governorate were investigated. The surficial soil zone represents an aquitard for the aquifer and mainly composed of fine textured materials having vertical hydraulic conductivity ranged from 1.4 x10 -6 cm/sec to 2.15x10 -2 cm/sec. The semi-confined Quaternary aquifer is formed of sand and gravel with occasional clay lenses. The groundwater levels ranged from 9 m (MSL) to 5 m (MSL). The major trend of groundwater flow was from south to north and northwest directions. Another minor flow trend was observed to be from southwest to northeast direction. The aquifer is essentially recharged from Ismaillia Canal. The hydraulic gradient through the flow path was 1.9 x10 -4 , averagely. The hydraulic conductivity values differ vertically and laterally indicating the heterogeneity and anisotropy of the aquifer materials. They ranged from 40.1 to 222 m/day with an average value of about 95.8 m/day. The chemical compositions of groundwater and surface water bodies (canals and drains) were investigated. The chemistry of all water bodies was characterized by a basic nature (ph =7.2-7.9) and showed different salinities values and various hydrochemical facies. The average salinities values were 318.1 mg/l for canal water, 1013.4 mg/l for groundwater and 1260 mg/l for drain water. Canal water was fresh while groundwater and drain were fresh to brackish. The reasons causing the changes in salinity and hydrochemical facies were investigated using the relationships among water dissolved constituents and trends of ionic ratios. Subsurface flow, infiltration, evaporation, ion exchange, leaching, and dissolution were the hydrochemical processes leading to the groundwater modification. The suitability of groundwater and surface water for different uses are discussed and evaluated according to the international standards.

  6. Imaging Quaternary glacial deposits and basement topography using the transient electromagnetic method for modeling aquifer environments

    Science.gov (United States)

    Simard, Patrick Tremblay; Chesnaux, Romain; Rouleau, Alain; Daigneault, Réal; Cousineau, Pierre A.; Roy, Denis W.; Lambert, Mélanie; Poirier, Brigitte; Poignant-Molina, Léo

    2015-08-01

    Aquifer formations along the northern shore of the Saint-Lawrence River in Quebec (Canada) mainly consist of glacial and coastal deposits of variable thickness overlying Precambrian bedrock. These deposits are important because they provide the main water supply for many communities. As part of a continuing project aimed at developing an inventory of the groundwater resources in the Charlevoix and Haute-Côte-Nord (CHCN) regions of the province of Quebec in Canada, the central loop transient electromagnetic (TEM) method was used to map the principal hydrogeological environments in these regions. One-dimensional smooth inversion models of the TEM soundings have been used to construct two-dimensional electrical resistivity sections, which provided images for hydrogeological validation. Electrical contour lines of aquifer environments were compared against available well logs and Quaternary surface maps in order to interpret TEM soundings. A calibration table was achieved to represent common deposits and basements. The calibration table was then exported throughout the CHCN region. This paper presents three case studies; one in the Forestville site, another in the Les Escoumins site and the other in the Saint-Urbain site. These sites were selected as targets for geophysical surveys because of the general lack of local direct hydrogeological data related to them.

  7. Quaternary Aquifer of the North China Plain-assessing and achieving groundwater resource sustainability

    Science.gov (United States)

    Foster, Stephen; Garduno, Hector; Evans, Richard; Olson, Doug; Tian, Yuan; Zhang, Weizhen; Han, Zaisheng

    The Quaternary Aquifer of the North China Plain is one of the world's largest aquifer systems and supports an enormous exploitation of groundwater, which has reaped large socio-economic benefits in terms of grain production, farming employment and rural poverty alleviation, together with urban and industrial water-supply provision. Both population and economic activity have grown markedly in the past 25 years. Much of this has been heavily dependent upon groundwater resource development, which has encountered increasing difficulties in recent years primarily as a result of aquifer depletion and related phenomena. This paper focuses upon the hydrogeologic and socio-economic diagnosis of these groundwater resource issues, and identifies strategies to improve groundwater resource sustainability. L'aquifère Quaternaire de la Plaine du Nord de la Chine est l'un des plus grands systèmes aquifères du monde; il permet une exploitation énorme d'eau souterraine, qui a permis des très importants bénéfices socio-économiques en terme de production de céréales, d'emplois ruraux et de réduction de la pauvreté rurale, en même temps que l'approvisionnement en eau potable et pour l'industrie. La population comme l'activité économique ont remarquablement augmenté au cours de ces 25 dernières années. Elles ont été sous la forte dépendance du développement de la ressource en eau souterraine, qui a rencontré des difficultés croissantes ces dernières années, du fait du rabattement de l'aquifère et des phénomènes associés. Cet article est consacré aux diagnostiques hydrogéologique et socio-économique des retombées de cette ressource en eau souterraine; il identifie les stratégies pour améliorer la pérennité des ressources en eau souterraine. El acuífero cuaternario de la Llanura Septentrional de China es uno de los mayores sistemas acuíferos del mundo y soporta una enorme explotación de su agua subterránea, las cuales han originado grandes

  8. Recharge sources and geochemical evolution of groundwater in the Quaternary aquifer at Atfih area, the northeastern Nile Valley, Egypt

    Science.gov (United States)

    El-Sayed, Salah Abdelwahab; Morsy, Samah M.; Zakaria, Khalid M.

    2018-06-01

    This study addresses the topic of recharge sources and evolution of groundwater in the Atfih area situated in the northeastern part of the Nile Valley, Egypt. Inventory of water wells and collection of groundwater and surface water samples have been achieved. Water samples are analyzed for major ions according to the American Society for Testing and Materials and for the environmental isotopes analysis (oxygen-18 and deuterium) by using a Triple Liquid Isotopic Water Analyzer (Los Gatos). The groundwater is available from the Quaternary aquifer formed mainly of graded sand and gravel interbedded with clay lenses. The hydrogeologic, hydrogeochemical and isotopic investigations indicate the hydrodynamic nature of the aquifer, where different flow paths, recharge sources and evolution mechanisms are distinguished. The directions of groundwater flow are from E, W and S directions suggesting the contribution from Nile River, the Eocene aquifer and the Nile basin, respectively. The groundwater altitudes range from 13 m (MSL) to 44 m (MSL). The hydraulic gradient varies between 0.025 and 0.0015. The groundwater is alkaline (pH > 7) and has salinity ranging from fresh to brackish water (TDS between 528 mg/l and 6070 mg/l). The observed wide range in the ionic composition and water types reflects the effect of different environmental and geological conditions through which the water has flowed. The isotopic compositions of groundwater samples vary between -14.13‰ and +23.56 for δD and between - 2.91‰ and +3.10 for δ18O. The isotopic data indicates that the Quaternary aquifer receive recharge from different sources including the Recent Nile water, surplus irrigation water, old Nile water before the construction of Aswan High Dam, surface runoff of local rains and Eocene aquifer. Evaporation, water rock interaction and mixing between different types of waters are the main processes in the groundwater evolution. Major suggestions are presented to develop the aquifer

  9. Hydrogeological characterization of the Nador Plio-Quaternary aquifer, Tipaza (Algeria); Caracterizacion hidrogeologica del acuifero pliocuaternario de Nador, Tipaza (Argelia)

    Energy Technology Data Exchange (ETDEWEB)

    Bouderbala, A.; Remini, B.; Pulido-Bosch, A.

    2014-06-01

    This paper focuses on the hydrogeological and hydrochemical knowledge of the Nador Plio-Quaternary aquifer in Tipaza, situated along the Algerian coastline. It includes the identification of the hydrodynamic aquifer, hydrogeological and piezometric characteristics and, finally, an overview of the hydro-geochemistry of the area. We carried out this study between 2008 and 2013, with piezometric and hydrochemical monitoring of 24 wells in the study area. The physicochemical analysis of water shows that 25 % of the wells in the coastal zone have values of electrical conductivity greater than 3000 μS/cm The Mg{sup 2}+/Ca{sup 2}+ ratio is also higher than one and there are sodium chloride facies due to the mix of freshwater with seawater exceeding 10 % in some places. However, the comparison of the salinity of the groundwater during the period 2008-2013 with 1988-2004 indicates that there is a low dilution due to the reduction of pumping in the aquifer after the construction of the Boukourdane dam. There has also been a more rainy period and a possible return flow from irrigation in the area. (Author)

  10. Managed aquifer recharge using quaternary-treated wastewater: an economic perspective

    KAUST Repository

    Zekri, Slim Mohamed; Ahmed, Mushtaque; Chaieb, Randa; Ghaffour, NorEddine

    2013-01-01

    An excess of 31 million m3/y of tertiary-treated wastewater is expected in Muscat, Oman, by 2015. This paper addresses the technical and cost estimation of managed aquifer recharge after reverse-osmosis treatment. The results indicate

  11. Alluvial Aquifer

    Data.gov (United States)

    Kansas Data Access and Support Center — This coverage shows the extents of the alluvial aquifers in Kansas. The alluvial aquifers consist of unconsolidated Quaternary alluvium and contiguous terrace...

  12. Isotopic and geochemical evidence of recharge sources and water quality in the Quaternary aquifer beneath Jinchang city, NW China

    International Nuclear Information System (INIS)

    Ma Jinzhu; Pan Feng; Chen Lihua; Edmunds, W. Mike; Ding Zhenyu; He Jianhua; Zhou Kunpeng; Huang Tianming

    2010-01-01

    Multiple isotopic and hydrogeochemical tracers were utilized to understand the recharge sources and geochemical evolution of groundwater in the Quaternary aquifer beneath Jinchang city and the adjacent Gobi desert area. The groundwater shows markedly depleted stable isotopic composition compared to modern rainfall. The signature of groundwaters from Jinchang and the northern Gobi desert area differ clearly from that of the alluvial fan in the south Yongchang basin and modern rainfall, and has lower or non-detectable 3 H activity, implying that the aquifer is likely maintained by palaeowater. This groundwater in the Gobi desert has a 14 C age older than 12 ka, indicating that the groundwater resources are non-renewable. The build-up of dissolved solids through evaporation is a major control on groundwater composition, and the dominant anion species change systematically from HCO 3 - , SO 4 2- to Cl - , but cations from weathering of albite, calcite, dolomite and gypsum also make a significant contribution. The scientific results have important implications for groundwater management in Jinchang city and as well as in the Shiyang River basin under China's West Development Strategy. It is recommended that the water allocation program of diverting water from the Dongda river to the Minqin basin be reconsidered.

  13. Monitoring of emerging contaminants (pharmaceuticals, Personal Care Products, surfactants and heavy metals) in a quaternary detritic aquifer

    Science.gov (United States)

    Candela, L.; Valdes-Abellan, J.; Jiménez-Martínez, J.

    2012-04-01

    The presence of 209 emerging compounds, surfactants, priority substances according to the 2008/105/EC Directive, 10 heavy metals and microbiological organisms in blended water and aquifer samples was investigated in a quaternary aquifer. The effects of these compounds over the environment are not clear in many cases, but many of them have been classified as endocrine disruptor compounds, EDC. Their presence in the media is controlled in one hand by their transformation and/or removal rates and, on the other hand, by their continuous release into the media, due to the broad use of these in many human activities (pharmaceuticals, personal care products, pesticides, heavy metals, LAS and others). The attention of this work focusses on the presence and fate of these substances in the vadose zone and the aquifer. The aquifer catchment (81km2) located in SE Spain presents a high natural salinity (with EC values of ~7,500 μS cm-1, and high concentrations of chloride, sulphate and sodium), making it unsuitable to be used as drinking water or irrigation. Two sampling campaigns (February and June 2011) in wells and springs have been carried out top characterize physic-chemical, microbiological and emerging contaminants presence in the aquifer. A total of 209 emerging pollutants grouped into the following classes were analysed: 125 pharmaceutical compounds (Phs), 20 polyaromatic hydrocarbons (PAHs) and Dioxins, 46 pesticides, 3 volatile priority pollutants as well as the most commonly used anionic surfactants were identified for further analysis. Heavy metals included: Cu, Cd, Pb, Hg, Ni, Zn, Sn, Pt, Pd and Tl. Results showed that 39 out of all compounds were detected: 11 pharmaceuticals, 9 PAHs, 19 pesticides, 4 surfactants and 4 heavy metals. Two of the compounds, endosulfan-α and Ni, were detected in concentrations above the allowed regulation. Although results are limited to 2 sampling campaigns, it is important to note that surfactants (LAS), pesticides PAHs and

  14. Study of the pollution impact from wastewater reuse for irrigation on the groundwater of the quaternary aquifer, west cairo

    International Nuclear Information System (INIS)

    Abd El Samie, S.G.; Ahmed, M.A.; Hassan, H.B.; Hamza, M.S.

    2005-01-01

    The hazards resulting from the extensive application of using sewage and drainage effluent in its form or mixing with fresh water from two sewerage stations(Zenin and Abu-Rawash) for agriculture irrigation were studied by means of chemical, isotopic and biological techniques. The hydrochemical results of major chemical constituents of surface water samples fall in the acceptable range for using this water for irrigation, while minor groups (NO 3 , PO 4 ) and heavy metals measurements showed higher values of Cd, Fe, Ni, Mn, and Pb in the mixed water more than the maximum permissible limits. The collected groundwater samples from the area of study showed high values of the total dissolved solids, minor groups and heavy metals in most wells around Zenin and abu Rawash sewerage stations. These values increase in the direction of the groundwater flow from south-east to north-west. The isotopic enrichment of delta 18 O, delta D enhanced with tritium values for surface and groundwater samples confirms the direct replenishment from surface and groundwater samples confirms the direct replenishment from surface water bodies by downward infiltration to the underlying aquifer, which permits the migration of wastewater contaminants through the soil layers to reach the groundwater level. The influence of wastewater infiltration was also detected from the high counting numbers of microbes obtained in all samples, which selected from some drains and wells close to the sewerage stations. From the previous results the real hazards for using this water not only depend on the quantitative estimates of total major ions, but the harmful pathogenic attack of micro and macro organisms as well as heavy metals will pose the greatest risk to the human health. On the long run the infiltration of the polluted water will threat the groundwater to different depths of the shallow layer of the quaternary aquifer that is the only source of potable water supply in some locations

  15. Quaternary stratigraphy, sediment characteristics and geochemistry of arsenic-contaminated alluvial aquifers in the Ganges-Brahmaputra floodplain in central Bangladesh.

    Science.gov (United States)

    Shamsudduha, M; Uddin, A; Saunders, J A; Lee, M-K

    2008-07-29

    This study focuses on the Quaternary stratigraphy, sediment composition, mineralogy, and geochemistry of arsenic (As)-contaminated alluvial aquifers in the Ganges-Brahmaputra floodplain in the central Bangladesh. Arsenic concentrations in 85 tubewells in Manikganj area, 70 km northwest of Dhaka City, range from 0.25 microg/L to 191 microg/L with a mean concentration of 33 microg/L. Groundwater is mainly Ca-HCO(3) type with high concentrations of dissolved As, Fe, and Mn, but low level of SO(4). The uppermost aquifer occurs between 10 m and 80 m below the surface that has a mean arsenic concentration of 35 microg/L. Deeper aquifer (>100 m depth) has a mean arsenic concentration of 18 microg/L. Sediments in the upper aquifer are mostly gray to dark-gray, whereas sediments in the deep aquifer are mostly yellowing-gray to brown. Quartz, feldspar, mica, hornblende, garnet, kyanite, tourmaline, magnetite, ilmenite are the major minerals in sediments from both aquifers. Biotite and potassium feldspar are dominant in shallow aquifer, although plagioclase feldspar and garnet are abundant in deep aquifer sediments. Sediment composition suggests a mixed provenance with sediment supplies from both orogenic belts and cratons. High arsenic concentrations in sediments are found within the upper 50 m in drilled core samples. Statistical analysis shows that As, Fe, Mn, Ca, and P are strongly correlated in sediments. Concentrations of Cd, Cu, Ni, Zn, and Bi also show strong correlations with arsenic in the Manikganj sediment cores. Authigenic goethite concretions, possibly formed by bacteria, are found in the shallow sediments, which contain arsenic of a concentration as high as 8.8 mg/kg. High arsenic concentrations in aquifers are associated with fine-grained sediments that were derived mostly from the recycled orogens and relatively rapidly deposited mainly by meandering channels during the Early to Middle Holocene rising sea-level conditions.

  16. Managed aquifer recharge using quaternary-treated wastewater: an economic perspective

    KAUST Repository

    Zekri, Slim Mohamed

    2013-10-11

    An excess of 31 million m3/y of tertiary-treated wastewater is expected in Muscat, Oman, by 2015. This paper addresses the technical and cost estimation of managed aquifer recharge after reverse-osmosis treatment. The results indicate that the project is appealing from an economic perspective. The total cost varies between USD 0.353 and USD 0.550 per cubic metre, depending on the cost of electricity, the interest rate and the life span of the project. The project may face rejection from domestic users, who may be unwilling to accept mixing treated wastewater with the current water supply due to health risks. An alternative to indirect potable reuse is the installation of a separate network to service industrial users. © 2013 Taylor & Francis.

  17. Carbon dynamics in a Late Quaternary-age coastal limestone aquifer system undergoing saltwater intrusion.

    Science.gov (United States)

    Bryan, Eliza; Meredith, Karina T; Baker, Andy; Andersen, Martin S; Post, Vincent E A

    2017-12-31

    This study investigates the inorganic and organic aspects of the carbon cycle in groundwaters throughout the freshwater lens and transition zone of a carbonate island aquifer and identifies the transformation of carbon throughout the system. We determined 14 C and 13 C carbon isotope values for both DIC and DOC in groundwaters, and investigated the composition of DOC throughout the aquifer. In combination with hydrochemical and 3 H measurements, the chemical evolution of groundwaters was then traced from the unsaturated zone to the deeper saline zone. The data revealed three distinct water types: Fresh (F), Transition zone 1 (T1) and Transition zone 2 (T2) groundwaters. The 3 H values in F and T1 samples indicate that these groundwaters are mostly modern. 14 C DOC values are higher than 14 C DIC values and are well correlated with 3 H values. F and T1 groundwater geochemistry is dominated by carbonate mineral recrystallisation reactions that add dead carbon to the groundwater. T2 groundwaters are deeper, saline and characterised by an absence of 3 H, lower 14 C DOC values and a different DOC composition, namely a higher proportion of Humic Substances relative to total DOC. The T2 groundwaters are suggested to result from either the slow circulation of water within the seawater wedge, or from old remnant seawater caused by past sea level highstands. While further investigations are required to identify the origin of the T2 groundwaters, this study has identified their occurrence and shown that they did not evolve along the same pathway as fresh groundwaters. This study has also shown that a combined approach using 14 C and 13 C carbon isotope values for both DIC and DOC and the composition of DOC, as well as hydrochemical and 3 H measurements, can provide invaluable information regarding the transformation of carbon in a groundwater system and the evolution of fresh groundwater recharge. Copyright © 2017 Elsevier B.V. All rights reserved.

  18. Geochemical and Isotopic Characteristics of Quaternary Aquifer in Sohag District, Upper Egypt

    International Nuclear Information System (INIS)

    Ahmed, M.A.

    2008-01-01

    Thc Nile River valley represent one of the most important regions for agriculture and land reclamation in our area. Environmental isotopes and hydrochemical compositions in conjunction with geological and hydrogeological data were used to define chemical characteristics, sources of salinity, ground water origin and the possible recharge sources to the Nile Valley aquifer in Sohag district, Upper Egypt. The total dissolved solids of the ground water samples have higher values (445-7828 mg/L) than surface water (291-348 mg/L). The ground water in the Nile flood plain is very similar to that of the river water except at the margins of the basin. This ground water contains isotopic contents comparable to the river Nile with low TDS. The change of water quality at the old alluvium plain could be due to extensive use of fertilizers to improve soil characteristics in new reclamation area. Mineral saturation indices suggest that the dissolution of evaporites and halite is significant in the ground water and responsible for most of the ground water salinization. The relationships between Na + ,Cl - , Ca 2+ , Mg 2+ ,HCO 3 - and SO 4 2- show that complex geochemical processes control the chemical history of ground water: (I) continuous dissolution of evaporites and halite and precipitation of carbonate rocks, (2) cation exchange between ground water and clay minerals, (3) excessive use of fertilizers rich in MgSO 4 in the reclamation projects. The isotopic contents of surface water raged from 2.03 to 2.93%0 for δ 18 O, from 15.3 to 28.4%0 for δ 3 H, and from 4.6 to 7.8 TU for tritium while the isotopic contents of ground water ranged from -8,41 to 3,86% o for δ 18 O, from -67.8 to 29.9%0 for δ 2 H, and from 0.5 to 11.3 TU for tritium. The isotopic data reveals that the rechargability of this water is attributed to Nile flood water which was depleted in its isotopic content. Significant contribution from the palaeowater, which stored in the Nubia sandstone aquifer system

  19. Aquifers

    Data.gov (United States)

    Earth Data Analysis Center, University of New Mexico — This map layer contains the shallowest principal aquifers of the conterminous United States, Hawaii, Puerto Rico, and the U.S. Virgin Islands, portrayed as polygons....

  20. Use of mass balance and statistical correlation for geochemical and isotopic investigation of the groundwater in the quaternary aquifer of the nile delta, Egypt

    International Nuclear Information System (INIS)

    Awad, M.A.A.; Sadek, M.A.; Salem, W.M.

    1999-01-01

    A hydrochemical and environmental isotopic studies were conducted in the nile delta region, to investigate the sources of salinity and replenishment for the groundwater reservoir which are of importance for land reclamation projects and the establishment of new communities on the west and east side of the nile delta. The hydrogeological properties of the main exploitable aquifer (quaternary) was described. The chemistry of the collected surface and ground-waters was outlined through the analysis of major cations (Na + , K + , Ca ++ , Mg ++ ) and major anions (Ci - , SO 4 - , HCO 3 - ). The variation in chemical composition of examined waters is attributed to the use of fertilizers, leaching of terrestrial salts and ion exchange between soil's minerals and water, in addition to, sea water intrusion in some isolated areas near by saline bodies (mediterranean sea, manzala lake, suez canal). Oxygen-18 and deuterium concentrations were used to identify the mechanism of recharge. The results show a mixing between different sources of water: recent Nile, old Nil water before construction of high Aswan dam, coastal precipitation as well as some contribution from both sea water toward north and palaeo-water at the eastern and western fringes of the nile delta. In some localities the recharge occurs indirectly after evaporation and/or vertical leakage of deep water due to over-pumping rates. This paper also demonstrates the implementation of statistical correlation and mass balance approaches to present the chemical and isotopic characterization of the nile delta quaternary aquifer. Recommendations are given for optimal use of water resources in the area of study

  1. Assessment of spatial distrilbution of porosity and aquifer geohydraulic parameters in parts of the Tertiary - Quaternary hydrogeoresource of south-eastern Nigeria

    Science.gov (United States)

    George, N. J.; Akpan, A. E.; Akpan, F. S.

    2017-12-01

    An integrated attempt exploring information deduced from extensive surface resistivity study in three Local Government Areas of Akwa Ibom State, Nigeria and data from hydrogeological sources obtained from water boreholes have been explored to economically estimate porosity and coefficient of permeability/hydraulic conductivity in parts of the clastic Tertiary - Quaternary sediments of the Niger Delta region. Generally, these parameters are predominantly estimated from empirical analysis of core samples and pumping test data generated from boreholes in the laboratory. However, this analysis is not only costly and time consuming, but also limited in areal coverage. The chosen technique employs surface resistivity data, core samples and pumping test data in order to estimate porosity and aquifer hydraulic parameters (transverse resistance, hydraulic conductivity and transmissivity). In correlating the two sets of results, Porosity and hydraulic conductivity were observed to be more elevated near the riverbanks. Empirical models utilising Archie's, Waxman-Smits and Kozeny-Carman Bear relations were employed characterising the formation parameters with wonderfully deduced good fits. The effect of surface conduction occasioned by clay usually disregarded or ignored in Archie's model was estimated to be 2.58 × 10-5 Siemens. This conductance can be used as a corrective factor to the conduction values obtained from Archie's equation. Interpretation aided measures such as graphs, mathematical models and maps which geared towards realistic conclusions and interrelationship between the porosity and other aquifer parameters were generated. The values of the hydraulic conductivity estimated from Waxman-Smits model was approximately 9.6 × 10-5m/s everywhere. This revelation indicates that there is no pronounced change in the quality of the saturating fluid and the geological formations that serve as aquifers even though the porosities were varying. The deciphered parameter

  2. Apports des analyses chimiques et isotopiques à la connaissance du fonctionnement des aquifères plio-quaternaire et turonien de la zone synclinale d'Essaouira, Maroc occidentalGeochemistry of Plio-Quaternary and Turonian aquifers in the Essaouira Basin, western Moroco

    Science.gov (United States)

    Mennani, A.; Blavoux, B.; Bahir, M.; Bellion, Y.; Jalal, M.; Daniel, M.

    2001-05-01

    The Essaouira synclinal zone is one of the Moroccan semi-arid zones with annual rainfalls not exceeding 300 mm yr -1 and very high potential evapo-transpiration of about 920 mm yr -1. This syncline with a Senonian axial zone is bordered by two diapiric structures of Triassic deposits: the Tidzi Diapir that outcrops in the east and south, and the hidden Essaouira diapir in the west, which was found by geophysics. This syncline contains two main superimposed aquifers. (i) The Plio-Quaternary aquifer consists of sands, sandstone and conglomerates and provides the main part of the water supply. This free-water table flows out towards the northwest and its surface is affected by significant piezometric variations. (ii) The calcareous dolomitic Turonian is a confined aquifer under the Senonian marls in the and in direct contact with the Plio-Quaternary. For a few years, the drinking water supply to the town of Essaouira has come from deep drillings. These two aquifers were sampled in June 1995 and in Januray 1996 after exceptional rainfalls. All waters have the same geochemical profile. The interpretation of the total dissolved solids and chloride content of Plio-Quaternary aquifers makes it possible to specify their origins. It emphasises, in particular, the source from the Ksob Wadi in the northeast and the role of the hidden Essaouira diapir. Nitrate levels were raised excessively, increasing at the same time as chloride concentrations during the rains of the winter of 1996, and underline the wells vulnerability to pastoral and domestic activities. The interpretation of O- and H-isotopes distinguishes two contrasting Plio-Quaternary and Turonian aquifers with an Atlantic origin for the rain recharge. A specific campaign was varried out in November 1996 to date water from the Turonian aquifer by 14C. Two boreholes draw water of several thousands years old.

  3. Assessment of spatial distrilbution of porosity and aquifer geohydraulic parameters in parts of the Tertiary – Quaternary hydrogeoresource of south-eastern Nigeria

    Directory of Open Access Journals (Sweden)

    N.J. George

    2017-12-01

    Full Text Available An integrated attempt exploring information deduced from extensive surface resistivity study in three Local Government Areas of Akwa Ibom State, Nigeria and data from hydrogeological sources obtained from water boreholes have been explored to economically estimate porosity and coefficient of permeability/hydraulic conductivity in parts of the clastic Tertiary – Quaternary sediments of the Niger Delta region. Generally, these parameters are predominantly estimated from empirical analysis of core samples and pumping test data generated from boreholes in the laboratory. However, this analysis is not only costly and time consuming, but also limited in areal coverage. The chosen technique employs surface resistivity data, core samples and pumping test data in order to estimate porosity and aquifer hydraulic parameters (transverse resistance, hydraulic conductivity and transmissivity. In correlating the two sets of results, Porosity and hydraulic conductivity were observed to be more elevated near the riverbanks. Empirical models utilising Archie’s, Waxman-Smits and Kozeny-Carman Bear relations were employed characterising the formation parameters with wonderfully deduced good fits. The effect of surface conduction occasioned by clay usually disregarded or ignored in Archie’s model was estimated to be 2.58 × 10−5 Siemens. This conductance can be used as a corrective factor to the conduction values obtained from Archie’s equation. Interpretation aided measures such as graphs, mathematical models and maps which geared towards realistic conclusions and interrelationship between the porosity and other aquifer parameters were generated. The values of the hydraulic conductivity estimated from Waxman-Smits model was approximately 9.6 × 10−5m/s everywhere. This revelation indicates that there is no pronounced change in the quality of the saturating fluid and the geological formations that serve as

  4. Understanding the carbon cycle in a Late Quaternary-age limestone aquifer system using radiocarbon of dissolved inorganic and organic carbon

    Science.gov (United States)

    Bryan, Eliza; Meredith, Karina T.; Baker, Andy; Andersen, Martin S.; Post, Vincent E. A.

    2017-04-01

    expected. LC-OCD chromatography of these groundwaters were found to contain higher concentrations of humic substances, that are most likely attributed to the presence of paleosol horizons at depth in the limestone, which are a common feature in aeolianite deposits along the Western coast of Australia and are related to Quaternary sea level change. The paleosols likely contribute old organic matter to the deeper groundwaters, which may explain the lower 14CDOC values. This study has shown that a combined approach that utilises both DIC and DOC tracers, as well as 3H, is required to identify the sources and evolution of carbon in a groundwater system, as well as the processes that effect the application of 14C dating to groundwaters within a carbonate aquifer.

  5. Quaternary and Geomorphology.

    Science.gov (United States)

    Andrews, J. T.; Graf, W. L.

    1983-01-01

    Highlights conferences and meetings of organizations involved with quaternary geology and geomorphology, including International Union of Quaternary Research Conference held in Moscow. The impetus of a revision of "The Quaternary of the United States" resulted from this conference. Includes activities/aims of "Friends of the…

  6. Geo-Electric and Hydrogeochemical Mapping of Quaternary ...

    African Journals Online (AJOL)

    Michael Horsfall

    basically different from those observed in nearby Warri and indicative of possible ... exist in the Quaternary superficial deposits of the Niger Delta environment. ... the petroleum geology of the area has been subject of ... of Commerce and Industry, 2001; Atakpo and ... purposes of aquifer vulnerability assessments and the.

  7. Carbonate aquifers

    Science.gov (United States)

    Cunningham, Kevin J.; Sukop, Michael; Curran, H. Allen

    2012-01-01

    Only limited hydrogeological research has been conducted using ichnology in carbonate aquifer characterization. Regardless, important applications of ichnology to carbonate aquifer characterization include its use to distinguish and delineate depositional cycles, correlate mappable biogenically altered surfaces, identify zones of preferential groundwater flow and paleogroundwater flow, and better understand the origin of ichnofabric-related karst features. Three case studies, which include Pleistocene carbonate rocks of the Biscayne aquifer in southern Florida and Cretaceous carbonate strata of the Edwards–Trinity aquifer system in central Texas, demonstrate that (1) there can be a strong relation between ichnofabrics and groundwater flow in carbonate aquifers and (2) ichnology can offer a useful methodology for carbonate aquifer characterization. In these examples, zones of extremely permeable, ichnofabric-related macroporosity are mappable stratiform geobodies and as such can be represented in groundwater flow and transport simulations.

  8. Hydrodynamic analysis of the artificial recharge of aquifers during the planning stage. Results obtained in the Quaternary aquifer in the Valley of the Guadalquivir (Spain); Analisis hidrodinamico de la recarga artificial de acuiferos durante la etapa de planificacion. Resultados obtenidos en el acuifero cuaternario del valle del Guadalquivir (Espana)

    Energy Technology Data Exchange (ETDEWEB)

    Murillo, J. M.

    2014-10-01

    This paper shows a study on the viability of an artificial recharge in the flood-plain aquifer of the Guadalquivir River (Andalucia, Spain). The method used to the evaluation of the artificial recharge project is as follows: A simple model (one cell). The code has been made on the use of an EXCEL spreadsheet. A distributed parameters-flow model using a standard code (Modflow). A pilot recharge plant. The simple model has been applied in different zones. The model has only 5 parameters. It evaluates the artificial recharge by means of the depletion coefficient. The model was calibrated for a monthly time-step, although the water balances in the soil and in the aquifer were calculated daily. The calibration the distributed parameter-flow model shows a high transmissivity, storage coefficient and porosity. The pilot recharge plant is a trench with recharge wells within it. The water available for recharge is obtained from an irrigation canal. A network of control points has been established to monitor the piezometric levels. The results obtained show a high storage coefficient and porosity. These parameters show a rapid groundwater velocity. Finally, the paper compares and contrasts the results obtained with the simple model, distributed parameter- flow model and the pilot recharge plant. The results are quite similar. The groundwater velocity is rapid. Water remains in the aquifer for a few days before returning to the river. (Author)

  9. Ozark Aquifer

    Data.gov (United States)

    Kansas Data Access and Support Center — These digital maps contain information on the altitude of the base and top, the extent, and the potentiometric surface of the Ozark aquifer in Kansas. The Ozark...

  10. Second Quaternary dating workshop

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-11-01

    The second Quaternary dating methods workshop was held at Lucas Heights and sponsored by ANSTO and AINSE. Topics covered include, isotope and thermoluminescence dating, usage of accelerator and thermal ionisation mass spectrometry in environmental studies emphasizing on the methodologies used and sample preparation

  11. Second Quaternary dating workshop

    International Nuclear Information System (INIS)

    1999-01-01

    The second Quaternary dating methods workshop was held at Lucas Heights and sponsored by ANSTO and AINSE. Topics covered include, isotope and thermoluminescence dating, usage of accelerator and thermal ionisation mass spectrometry in environmental studies emphasizing on the methodologies used and sample preparation

  12. Guarani aquifer

    International Nuclear Information System (INIS)

    2007-01-01

    The environmental protection and sustain ability develop project of Guarani Aquifer System is a join work from Argentina, Brazil, Paraguay and Uruguay with a purpose to increase the knowledge resource and propose technical legal and organizational framework for sustainable management between countries.The Universities funds were created as regional universities support in promotion, training and academic research activities related to environmental al social aspects of the Guarani Aquifer System.The aim of the project is the management and protection of the underground waters resources taking advantage and assesment for nowadays and future generations

  13. Gravity field separation and mapping of buried quaternary valleys in Lolland, Denmark using old geophysical data

    DEFF Research Database (Denmark)

    Møller, M.J.; Olsen, Henrik; Ploug, C.

    2007-01-01

    In this paper we utilise the old industrial data for planning new surveys. The overall purpose is a detailed mapping of possible aquifers for the island of Lolland, Denmark. This is done through detection and modelling of the buried quaternary valleys, which either can serve as potential aquifers...... or potential aquifer barriers. The present paper deals only with one aspect of a larger study; namely a case story leading to the detection of unknown buried valleys and the first attempts to model them in 3D from gravity and seismics. Also, the emphasis here is not on any theoretical or even methodological...

  14. Hydrogeology of the Umm Er Radhuma Aquifer (Arabian peninsula)

    Science.gov (United States)

    Dirks, Heiko; Al Ajmi, Hussain; Kienast, Peter; Rausch, Randolf

    2018-03-01

    The aim of this article is to enhance the understanding of the Umm Er Radhuma aquifer's genesis, and its hydraulic and hydrochemical development over time. This is a prerequisite for wise use of the fossil groundwater resources contained within. The Umm Er Radhuma is a karstified limestone aquifer, extending over 1.6 Mio. km2 in the eastern part of the Arabian Peninsula. Both epigene and hypogene karstification contributed to the genesis of what is today the most prolific aquifer in the region. Besides man-made abstractions, even the natural outflows are higher than the small recharge (natural storage depletion). The Umm Er Radhuma shows that large aquifers in arid regions are never in "steady state" (where inflows equal outflows), considering Quaternary climate history. The aquifer's adaption to climate changes (precipitation, sea level) can be traced even after thousands of years, and is slower than the climate changes themselves.

  15. Map showing thickness of saturated Quaternary deposits, Sugar House quadrangle, Salt Lake County, Utah, February 1972

    Science.gov (United States)

    Mower, R.W.

    1973-01-01

    Saturated Quaternary deposits in the Sugar Horse quadrangle supply significant quantities of water to wells from which water is withdrawn for domestic, municipal, industrial, and irrigation uses. The deposits consist of clay, silt, sand, and gravel; individual beds range from a few inches to several tens of feet thick. The principal aquifer, which is almost completely within the Quaternary deposits, supplied about 4 percent, or 9,000 acre-feet, of the municipal and industrial water used annually in Salt Lake County during 1964-68.As a general rule, more water is stored and more water will be yielded to a well where aquifers are thicker. This map can be used as a general guide to those areas where greatest amounts of water are stored in the aquifer, and where yields to wells may be greater. Local variations in the ability of saturated deposits to transmit water can alter the general relationship between aquifer thickness and yield of wells.The thickness of saturated Quaternary deposits within the area of the Sugar Horse quadrangle ranges from zero to about 650 feet, as shown on the map. The thickest section of these deposits is near the southwestern corner of the quadrangle, and the thinnest section is along the mountain front adjacent to the approximate eastern limit of saturated Quaternary deposits.The thickness of saturated Quaternary deposits shown on this map is based on drillers’ logs for 55 deep wells (which show the thickness of the Quaternary deposits) and on water-level measurements made in February 1972 in wells in unconfined shallow aquifers.Reports in the following list of selected references contain other information about the saturated Quaternary deposits in this and adjacent parts of Jordan Valley, Utah. The basic-data reports and releases contain well logs, water-level measurements, and other types of basic ground-water data. The interpretive repots contain discussions of the occurrence of ground water, tests to determine hydraulic properties of

  16. Quantification of River Nile/Quaternary aquifer exchanges via ...

    Indian Academy of Sciences (India)

    3Civil Engineering Department, Minia University, Minia, Egypt. ∗ ... This study approach seeks to characterize the hydraulic interactions .... organic compounds are the most common oxidiz- .... Nile and applied irrigation, subsurface drainage.

  17. Interprétation hydrogéologique de l'aquifère des bassins sud-rifains (Maroc) : apport de la sismique réflexionHydrogeological interpretation of the southern Rifean basins aquifer (Morocco): seismic reflexion contribution

    Science.gov (United States)

    Zouhri, Lahcen; Gorini, Christian; Lamouroux, Christian; Vachard, Daniel; Dakki, Mohammed

    2003-03-01

    The aquifer of the Rharb Basin is constituted by heterogeneous material. The seismic reflexion interpretation carried out in this area, highlighted a permeable device compartmentalized in raised and subsided blocks. Depressions identified in the northern and southernmost zones are characterized by Plio-Quaternary fillings that are favourable to the hydrogeological exploitation. Two mechanisms contribute to structure the Plio-Quaternary aquifer: the Hercynian reactivation in the southernmost part, and the gravitational mechanism of the Pre-Rifean nappe. The groundwater flow and the aquifer thickening are controlled by this reactivation.

  18. Quaternary dating methods

    International Nuclear Information System (INIS)

    Mahaney, W.C.

    1984-01-01

    The papers in this book cover absolute, relative and multiple dating methods, and have been written by specialists from a number of different earth sciences disciplines - their common interest being the dating of geological materials within the Quaternary. Papers on absolute dating methods discuss radiocarbon, uranium-series, potassium argon, 40 Ar/ 39 Ar, paleomagnetic, obsidian hydration, thermoluminescence, amino acid racemization, tree rings, and lichenometric techniques. Those on relative dating include discussions on various geomorphic relative age indicators such as drainage density changes, hypsometric integrals, bifurcation ratios, stream junction angles, spur morphology, hillslope geometry, and till sheet characteristics. The papers on multiple dating cite examples from the Rocky Mountains, Australia, Lake Agassiz Basin, and the Southern Andes. Also included is the panel discussion which reviews and assesses the information presented, and a field trip guide which discusses the sequences of Wisconian tills and interlayered lacustrine and fluvial sediments. (orig.)

  19. Research on the neutron flux, secular equilibrium of chlorine-36 and groundwater age of the deep quaternary sediments, Hebei plain

    International Nuclear Information System (INIS)

    Dong Yuean; He Ming; Jiang Songsheng; Wu Shaoyong; Jiang Shan

    2001-01-01

    For the study of the neutron flux, secular equilibrium of chlorine-36 in the deep quaternary sediments of Hebei plain, the main chemical composition of water sand and confining bed was determined by neutron activation analysis. The mean neutron flux is 2.79 x 10 -5 cm -2 s -1 which was calculated by the chemical composition of the strata. The mean 36 Cl/Cl ratio in secular equilibrium is 1.27 x 10 -14 in the deep quaternary sediments, Hebei Plain. For the study of the groundwater age of the deep Quaternary sediments of Hebei Plain, the 36 Cl/Cl ratio of groundwater samples were determined by tandem accelerator mass spectrometry. The mixed groundwater 36 Cl/Cl ratio of the second and the third aquifer of Quaternary sediments in Baoding district is 247 x 10 -15 , that of the fourth aquifer in Baoding city is 224 x 10 -15 and the third aquifer in Cangzhou district is 40.5 x 10 -15 . The groundwater age of Baoding district was young and that of the third aquifer in Cangzhou was 229.2 ka

  20. Quaternary structure of methemoglobin

    International Nuclear Information System (INIS)

    Chevion, M.; Ilan, Y.A.; Samuni, A.; Navok, T.; Czapski, G.

    1979-01-01

    The pulse radiolysis of solutions of adult human methemoglobin was used to reduce a single heme iron within the protein tetramers. The valence hybrids thus formed were reacted with oxygen. Kinetics of the reactions were studied. The effects of pH and inositol hexaphosphate were examined. The kinetics of the ligation of oxygen to stripped valence hybrids showed a single phase behavior at the pH range 6.5 to 9. As the pH was lowered below 6.5, a second, slower phase became apparent. In the presence of inositol hexaphosphate, above pH 8, the kinetics of oxygen binding was of a single phase. As the pH was lowered, a transition to a second, slower phase was noticed. Below pH 7, the slower phase was the only detectable one. On this basis, it is concluded that human adult stripped methemoglobin resides in an R quarternary structure, while the presence of IHP stabilizes the T structure at pH below 7.5. This transition between the quaternary structures of methemoglobin cannot be accounted for by the switch between the high spin and the low spin states of the ferric iron. This switch of spin state takes place at pH>8.2

  1. Sedimentological analysis of a contaminated groundwater aquifer

    International Nuclear Information System (INIS)

    Towse, D.

    1991-01-01

    The use of sedimentological reservoir analysis techniques adapted from standard oilfield practice can improve the efficiency and reduce the costs of the evaluation of groundwater aquifers and the design of restoration programs. An evaluation/restoration program at a site in California drilled over 200 test wells in about 750 ac. All wells were logged lithologically and with wireline. The shallow aquifer is a complex braided alluvial floodplain deposit of Late Quaternary age. Analysis demonstrates depositional and erosional responses to periodic hinterland uplifts and to changing climatic conditions. Channel, overbank, lacustrine, and minor deltaic deposits can be recognized. The aquifer architecture has been interpreted to explain the movement of fuel and halogenated hydrocarbon solvents in the sediments and water. Routine engineering geology techniques and hydrologic tests were used to evaluate contamination and to design experimental restoration processes. As demonstrated here, sedimentological techniques show promise in reducing the costs and time required for this type of study. The abundant detailed data will be used in an attempt to develop a microcomputer-based expert system for rapid preliminary analyses of similar aquifers or reservoirs

  2. Geomorphic Controls on Aquifer Geometry in Northwestern India

    Science.gov (United States)

    van Dijk, W. M.; Densmore, A. L.; Sinha, R.; Gupta, S.; Mason, P. J.; Singh, A.; Joshi, S. K.; Nayak, N.; Kumar, M.; Shekhar, S.

    2014-12-01

    The Indo-Gangetic foreland basin suffers from one of the highest rates of groundwater extraction in the world, especially in the Indian states of Punjab, Haryana and Rajasthan. To understand the effects of this extraction on ground water levels, we must first understand the geometry and sedimentary architecture of the aquifer system, which in turn depend upon its geomorphic setting. We use satellite images and digital elevation models to map the geomorphology of the Sutlej and Yamuna river systems, while aquifer geometry is assessed using ~250 wells that extend to ~300 m depth in Punjab and Haryana. The Sutlej and Yamuna rivers have deposited large sedimentary fans at their outlets. Elongate downslope ridges on the fan surfaces form distributary networks that radiate from the Sutlej and Yamuna fan apices, and we interpret these ridges as paleochannel deposits associated with discrete fan lobes. Paleochannels picked out by soil moisture variations illustrate a complex late Quaternary history of channel avulsion and incision, probably associated with variations in monsoon intensity. Aquifer bodies on the Sutlej and Yamuna fans have a median thickness of 7 and 6 m, respectively, and follow a heavy-tailed distribution, probably because of stacked sand bodies. The percentage of aquifer material in individual lithologs decreases downstream, although the exponent on the thickness distribution remains the same, indicating that aquifer bodies decrease in number down fan but do not thin appreciably. Critically, the interfan area between the Sutlej and Yamuna fans has thinner aquifers and a lower proportion of aquifer material, despite its proximal location. Our data show that the Sutlej and Yamuna fan systems form the major aquifer systems in this area, and that their geomorphic setting therefore provides a first-order control on aquifer distribution and geometry. The large spatial heterogeneity of the system must be considered in any future aquifer management scheme.

  3. Three-Dimensional Geological Model of Quaternary Sediments in Walworth County, Wisconsin, USA

    Directory of Open Access Journals (Sweden)

    Jodi Lau

    2016-07-01

    Full Text Available A three-dimensional (3D geologic model was developed for Quaternary deposits in southern Walworth County, WI using Petrel, a software package primarily designed for use in the energy industry. The purpose of this research was to better delineate and characterize the shallow glacial deposits, which include multiple shallow sand and gravel aquifers. The 3D model of Walworth County was constructed using datasets such as the U.S. Geological Survey 30 m digital elevation model (DEM of land surface, published maps of the regional surficial geology and bedrock topography, and a database of water-well records. Using 3D visualization and interpretation tools, more than 1400 lithostratigraphic picks were efficiently interpreted amongst 725 well records. The final 3D geologic model consisted of six Quaternary lithostratigraphic units and a bedrock horizon as the model base. The Quaternary units include in stratigraphic order from youngest to oldest: the New Berlin Member of the Holy Hill Formation, the Tiskilwa Member of the Zenda Formation, a Sub-Tiskilwa Sand/Gravel unit, the Walworth Formation, a Sub-Walworth Sand/Gravel unit, and a Pre-Illinoisan unit. Compared to previous studies, the results of this study indicate a more detailed distribution, thickness, and interconnectivity between shallow sand and gravel aquifers and their connectivity to shallow bedrock aquifers. This study can also help understand uncertainty within previous local groundwater-flow modeling studies and improve future studies.

  4. Designing Novel Quaternary Quantum Reversible Subtractor Circuits

    Science.gov (United States)

    Haghparast, Majid; Monfared, Asma Taheri

    2018-01-01

    Reversible logic synthesis is an important area of current research because of its ability to reduce energy dissipation. In recent years, multiple valued logic has received great attention due to its ability to reduce the width of the reversible circuit which is a main requirement in quantum technology. Subtractor circuits are between major components used in quantum computers. In this paper, we will discuss the design of a quaternary quantum reversible half subtractor circuit using quaternary 1-qudit, 2-qudit Muthukrishnan-Stroud and 3-qudit controlled gates and a 2-qudit Generalized quaternary gate. Then a design of a quaternary quantum reversible full subtractor circuit based on the quaternary half subtractor will be presenting. The designs shall then be evaluated in terms of quantum cost, constant input, garbage output, and hardware complexity. The proposed quaternary quantum reversible circuits are the first attempt in the designing of the aforementioned subtractor.

  5. Quaternary palaeoceanography and palaeogeography in Northern Denmark

    DEFF Research Database (Denmark)

    Knudsen, Karen Luise; Conradsen, Keld; Heier‐Nielsen, Susanne

    1996-01-01

    Palaeoenvironmental reconstructions from the Skagen record contribute to the understanding of Late Quaternary climatic changes and variations in the oceanographic circulation pattern in the entire North Atlantic region. The Skagen cores penetrated c. 192 m of Quaternary sediments comprising two...... the Holocene, including the Pleistocene-Holocene transition. Results from the study of lithology, foraminifera, stable isotope measurements and radiocarbon dates are reviewed while emphasizing the most important contributions to the general understanding of the North Atlantic Quaternary history....

  6. Nitrate reduction in an unconfined sandy aquifer

    DEFF Research Database (Denmark)

    Postma, Diederik Jan; Boesen, Carsten; Kristiansen, Henning

    1991-01-01

    of total dissolved ions in the NO3- free anoxic zone indicates the downward migration of contaminants and that active nitrate reduction is taking place. Nitrate is apparently reduced to N2 because both nitrite and ammonia are absent or found at very low concentrations. Possible electron donors......Nitrate distribution and reduction processes were investigated in an unconfined sandy aquifer of Quaternary age. Groundwater chemistry was studied in a series of eight multilevel samplers along a flow line, deriving water from both arable and forested land. Results show that plumes of nitrate...... processes of O2 and NO3- occur at rates that are fast compared to the rate of downward water transport. Nitrate-contaminated groundwater contains total contents of dissolved ions that are two to four times higher than in groundwater derived from the forested area. The persistence of the high content...

  7. Recent advances in quaternary geochronology

    International Nuclear Information System (INIS)

    Poupeau, G.

    1983-01-01

    Significant progress has occurred in quaternary geochronology. These include both (i) improvements in Fission Track and Thermoluminescence dating, as well as (ii) new technologies for short-lived (i.e. with half lives 6 yrs) radionuclide measurements as with the 14 C or uranium series desequilibrium dating, and finally (iii) the emergence of entirely new dating approches as the Electron Spin Resonnance Method. The aim of this paper is to review these progresses and the new areas they open geochronology for the past-miocene times. (author) [pt

  8. Southern Dobrogea coastal potable water sources and Upper Quaternary Black Sea level changes

    Science.gov (United States)

    Caraivan, Glicherie; Stefanescu, Diana

    2013-04-01

    Southern Dobrogea is a typical geologic platform unit, placed in the south-eastern part of Romania, with a Pre-Cambrian crystalline basement and a Paleozoic - Quaternary sedimentary cover. It is bordered to the north by the Capidava - Ovidiu fault and by the Black Sea to the east. A regional WNW - ESE and NNE - SSW fault system divides the Southern Dobrogea structure in several tectonic blocks. Four drinking water sources have been identified: surface water, phreatic water, medium depth Sarmatian aquifer, and deep Upper Jurassic - Lower Cretaceous aquifer. Surface water sources are represented by several springs emerged from the base of the loess cliff, and a few small rivers, barred by coastal beaches. The phreatic aquifer develops at the base of the loess deposits, on the impervious red clay, overlapping the Sarmatian limestones. The medium depth aquifer is located in the altered and karstified Sarmatian limestones, and discharges into the Black Sea. The Sarmatian aquifer is unconfined where covered by silty loess deposits, and locally confined, where capped by clayey loess deposits. The aquifer is supplied from the Pre-Balkan Plateau. The Deep Upper Jurassic - Lower Cretaceous aquifer, located in the limestone and dolomite deposits, is generally confined and affected by the regional WNW - ESE and NNE - SSW fault system. In the south-eastern Dobrogea, the deep aquifer complex is separated from the Sarmatian aquifer by a Senonian aquitard (chalk and marls). The natural boundary of the Upper Jurassic - Lower Cretaceous aquifer is the Capidava - Ovidiu Fault. The piezometric heads show that the Upper Jurassic - Lower Cretaceous aquifer is supplied from the Bulgarian territory, where the Upper Jurassic deposits crop out. The aquifer discharges into the Black Sea to the east and into Lake Siutghiol to the northeast. The cyclic Upper Quaternary climate changes induced drastic remodeling of the Black Sea level and the corresponding shorelines. During the Last Glacial

  9. The contribution of environmental isotopes to studies of large aquifers in Morocco

    International Nuclear Information System (INIS)

    Kabbaj, A.; Zeryouhi, I.; Carlier, Ph.

    1979-01-01

    The geochemistry of environmental isotopes has been used for the study of various aquifers in Morocco, some of which are large, such as the Charf el Akab in the Tangiers area, the Oum er Rbia basin and the Turonian aquifer of the Tadla, the free groundwater of the Quaternary lacustrine limestones of the Sais Plain and the Lias limestone aquifer. These isotope studies take hydrogeochemical data into account and have made it possible to determine the conditions of recharge of the aquifers, to distinguish waters of different origin from the Atlas Mountains or from the Phosphate Plateau in the Tadla Basin and the Sais plain, to estimate the recharge of one aquifer by another - for example groundwater of the Lias limestones passing via the folds of the Sais Plain into the lacustrine limestone aquifer - and to test the homogeneity or heterogeneity of these aquifers and their tightness (e.g. the Turonian aquifer of the Tadla and the special case of the Charf el Akab in relation to the marine environment). Altogether, these results made it possible to test the value of the techniques used and to specify the general conditions in which they can profitably be used. (author)

  10. EPA Sole Source Aquifers

    Data.gov (United States)

    U.S. Environmental Protection Agency — Information on sole source aquifers (SSAs) is widely used in assessments under the National Environmental Policy Act and at the state and local level. A national...

  11. Tracers Detect Aquifer Contamination

    National Research Council Canada - National Science Library

    Enfield, Carl

    1995-01-01

    The EPA's National Laboratory (NRMRL) at Ada, OK, along with the University of Florida and the University of Texas, have developed a tracer procedure to detect the amount of contamination in aquifer formations...

  12. Ogallala Aquifer Mapping Program

    International Nuclear Information System (INIS)

    1984-10-01

    A computerized data file has been established which can be used efficiently by the contour-plotting program SURFACE II to produce maps of the Ogallala aquifer in 17 counties of the Texas Panhandle. The data collected have been evaluated and compiled into three sets, from which SURFACE II can generate maps of well control, aquifer thickness, saturated thickness, water level, and the difference between virgin (pre-1942) and recent (1979 to 1981) water levels. 29 figures, 1 table

  13. Late Quaternary changes in climate

    Energy Technology Data Exchange (ETDEWEB)

    Holmgren, K; Karlen, W [Stockholm Univ. (Sweden). Dept. of Physical Geography

    1998-12-01

    This review concerns the Quaternary climate with an emphasis on the last 200 000 years. The present state of art in this field is described and evaluated. The review builds on a thorough examination of classic and recent literature. General as well as detailed patterns in climate are described and the forcing factors and feed-back effects are discussed. Changes in climate occur on all time-scales. During more than 90% of the Quaternary period earth has experienced vast ice sheets, i.e. glaciations have been more normal for the period than the warm interglacial conditions we face today. Major changes in climate, such as the 100 000 years glacial/interglacial cycle, are forced by the Milankovitch three astronomical cycles. Because the cycles have different length climate changes on earth do not follow a simple pattern and it is not possible to find perfect analogues of a certain period in the geological record. Recent discoveries include the observation that major changes in climate seem to occur at the same time on both hemispheres, although the astronomical theory implies a time-lag between latitudes. This probably reflects the influence of feed-back effects within the climate system. Another recent finding of importance is the rapid fluctuations that seem to be a normal process. When earth warmed after the last glaciation temperature jumps of up to 10 deg C occurred within less than a decade and precipitation more than doubled within the same time. The forcing factors behind these rapid fluctuations are not well understood but are believed to be a result of major re-organisations in the oceanic circulation. Realizing that nature, on its own, can cause rapid climate changes of this magnitude put some perspective on the anthropogenic global warming debate, where it is believed that the release of greenhouse gases will result in a global warming of a few C. To understand the forcing behind natural rapid climate changes appears as important as to understand the role

  14. Late Quaternary changes in climate

    International Nuclear Information System (INIS)

    Holmgren, K.; Karlen, W.

    1998-12-01

    This review concerns the Quaternary climate with an emphasis on the last 200 000 years. The present state of art in this field is described and evaluated. The review builds on a thorough examination of classic and recent literature. General as well as detailed patterns in climate are described and the forcing factors and feed-back effects are discussed. Changes in climate occur on all time-scales. During more than 90% of the Quaternary period earth has experienced vast ice sheets, i.e. glaciations have been more normal for the period than the warm interglacial conditions we face today. Major changes in climate, such as the 100 000 years glacial/interglacial cycle, are forced by the Milankovitch three astronomical cycles. Because the cycles have different length climate changes on earth do not follow a simple pattern and it is not possible to find perfect analogues of a certain period in the geological record. Recent discoveries include the observation that major changes in climate seem to occur at the same time on both hemispheres, although the astronomical theory implies a time-lag between latitudes. This probably reflects the influence of feed-back effects within the climate system. Another recent finding of importance is the rapid fluctuations that seem to be a normal process. When earth warmed after the last glaciation temperature jumps of up to 10 deg C occurred within less than a decade and precipitation more than doubled within the same time. The forcing factors behind these rapid fluctuations are not well understood but are believed to be a result of major re-organisations in the oceanic circulation. Realizing that nature, on its own, can cause rapid climate changes of this magnitude put some perspective on the anthropogenic global warming debate, where it is believed that the release of greenhouse gases will result in a global warming of a few C. To understand the forcing behind natural rapid climate changes appears as important as to understand the role

  15. Origin of water salinity in the coastal Sarafand aquifer (South-Lebanon)

    International Nuclear Information System (INIS)

    Hashash, Adnan; Aranyossy, J.F.

    1996-01-01

    Author.The geochemical and isotopic study, based on the analysis of twenty water samples from well in the coastal plain of Sarafand (South-Lebanon), permit to eliminate the hypothesis of marine intrusion in this aquifer. The increase of salinity observed in certain wells is due to the contamination of cretaceous aquifer water by the quaternary formations. The two poles of mixing are respectively characterized: by weak tritium contents (between 2 and 3 UT) and a value of stable isotopes (-5,9<0,18<-5,5) corresponding to the appearance of cretaceous formation area; by the high tritium contents and enrichment relative to heavy isotope in the mineralized water of superficial formations. On the other hand, the isotope contents permit the set a rapid renewal of the cretaceous aquifer water due to quick circulation in the Karstic system

  16. Isotopic and hydro geochemistry study of the granular aquifer from Comarca Lagunera, Mexico

    International Nuclear Information System (INIS)

    Gonzalez Hita, Luis; Sanchez Diaz, Luis Felipe

    1994-01-01

    The Comarca Lagunera is one of Mexico's biggest agricultural regions. Its water sources are the Nazas and Aguanaval Rivers and a quaternary granular aquifer. The over exploitation of the aquifer has led to deteriorated groundwater quality due to the presence of arsenic. This study aims to determine the origin and evolution of the arsenic and to update the system's hydrogeochemical information. The methodology used is based on an analysis of the physical framework and on the hydrogeochemical and isotope characterization of the groundwater. An interpretation of the results shows that the arsenic could have originated in two geological events: first, the magmatic processes that generated the region's intrusive and extrusive igneous rocks, and second, the sedimentation of alluvial-lacustrine materials bearing arsenic, which were transported by the Nazas and Aguanaval Rivers during the aquifer's formation. (author)

  17. Arsenic pollution of groundwater in Vietnam exacerbated by deep aquifer exploitation for more than a century

    Science.gov (United States)

    Winkel, Lenny H. E.; Trang, Pham Thi Kim; Lan, Vi Mai; Stengel, Caroline; Amini, Manouchehr; Ha, Nguyen Thi; Viet, Pham Hung; Berg, Michael

    2011-01-01

    Arsenic contamination of shallow groundwater is among the biggest health threats in the developing world. Targeting uncontaminated deep aquifers is a popular mitigation option although its long-term impact remains unknown. Here we present the alarming results of a large-scale groundwater survey covering the entire Red River Delta and a unique probability model based on three-dimensional Quaternary geology. Our unprecedented dataset reveals that ∼7 million delta inhabitants use groundwater contaminated with toxic elements, including manganese, selenium, and barium. Depth-resolved probabilities and arsenic concentrations indicate drawdown of arsenic-enriched waters from Holocene aquifers to naturally uncontaminated Pleistocene aquifers as a result of > 100 years of groundwater abstraction. Vertical arsenic migration induced by large-scale pumping from deep aquifers has been discussed to occur elsewhere, but has never been shown to occur at the scale seen here. The present situation in the Red River Delta is a warning for other As-affected regions where groundwater is extensively pumped from uncontaminated aquifers underlying high arsenic aquifers or zones. PMID:21245347

  18. Climate predictors of late quaternary extinctions

    DEFF Research Database (Denmark)

    Nogués-Bravo, David; Ohlemüller, Ralf; Batra, Persaram

    2010-01-01

    Between 50,000 and 3,000 years before present (BP) 65% of mammal genera weighing over 44 kg went extinct, together with a lower proportion of small mammals. Why species went extinct in such large numbers is hotly debated. One of the arguments proposes that climate changes underlie Late Quaternary...... extinctions, but global quantitative evidence for this hypothesis is still lacking. We test the potential role of global climate change on the extinction of mammals during the Late Quaternary. Our results suggest that continents with the highest climate footprint values, in other words, with climate changes...... of greater magnitudes during the Late Quaternary, witnessed more extinctions than continents with lower climate footprint values, with the exception of South America. Our results are consistent across species with different body masses, reinforcing the view that past climate changes contributed to global...

  19. PRN 88-2: Clustering of Quaternary Ammonium Compounds

    Science.gov (United States)

    This Notice announces that EPA has clustered the Quaternary Ammonium Compounds into four groups for the purpose of testing chemicals to build a database that will support continued registration of the entire family of quaternary ammonium compounds

  20. Quaternary sediments in Rybalsryi quarry of Dnipropetrovsk

    Directory of Open Access Journals (Sweden)

    Manyuk V.V.

    2014-12-01

    Full Text Available The results of a study of the typical section of Quaternary sediments in the Rybalske quarry and first time been reported to shift to the South boundary of the spread of the Dneprovian ice cover. Long-term observation of the geological structure subaerial and subaqueous deposits in Quaternary escarpment quarry clearly demonstrates the exceptional value, integrity, and at the same time, a certain exclusivity individual elements Quaternary section. Middle-upper Pleistocene section of substantially exceeds disclosed in Sazhovka draw, where the stratotype Kodatskiy fossil soil and elevated section of Quaternary sediments. If old Kodak can see only fragments section, an opened side by deep ravines and conditions of use cleared, the Rybalske quarry ledge submitted in one complete section alternation fossil soil horizons and loess - loess from the Dnieper to the modern black soil, and another ledge next to, well the rest of the section is exposed (from Tilihulske to Shyrokynske klimatolite. Established that among the many famous sections subaerial deposits located in the Middle Dnieper in the north-eastern part of the Dnieper-Donets basin, in the Black Sea and the Crimea and studied by the author in different years, and described loess and soil horizons (from the Black Sea to the Dnieper differ markedly lack of connectivity, flowability and friability. It is logical to assume that lithofacies conditions of the thicker subaerial deposits in the wellhead part Samara, where the Rybalske quarry markedly different from existing in these areas. Despite the obvious influence of the Dnieper glacier, direct signs which surround Dnipropetrovs’k north must be other reasons not yet explored. It is worth noting another important feature of the section of Quaternary sediments in fishing career. The above section is characteristic of the north-eastern part of the quarry, while the north, at higher marks of the watershed in the lower parts of thicker Quaternary

  1. Isotopes to Study the coastal aquifer plain, Cap Bon, Tunisia

    International Nuclear Information System (INIS)

    Ben Hamouda, M. F.; Zouari, Kamel; Tarhouni, J.; Gaye, C.B.; Oueslati, M.N.

    2005-01-01

    The study area is located in the northeastern part of Tunisia about 60 km south of the Tunis city. It is bounded by the Gulf of Haematite in the East, Djebel Sidi Aberahmane in the West, The town of Nabeul in the south and the area of the town Kelibia in the north. The landscape is a coastal plain slightly sloping (3%) towards the sea. The groundwater of the Oriental coast aquifer system occurs mainly at two levels, a shallow aquifer up to depths of about 50 m whose reservoir is consisted by sediments of the Plio quaternary and a deep aquifer between about 150 and 400 m located in the sand stone formations of Miocene of the anticline of Djebel Sidi Abderrahmene. The climate of the region is semi-arid to sub-humid and of Mediterranean type. There are no perennial rivers in this region; but intense storms occasionally cause surface runoff, which is discharged by the oueds. The study is related to a technical cooperation project with the International Atomic Energy Agency, Vienna, Austria, aimed at the use of isotope techniques to study the seawater intrusion into the coastal aquifers of Cap Bon in Tunisia. In this regard, a better understanding of the recharge and flow regime as well as the origin or salinity of the groundwater was required. To reach this goal, isotope and geochemical investigations were carried out. Water samples were taken from wells, boreholes from deep and shallow aquifer of the Oriental coastal aquifer located between Beni Khiar in the south and Kelibia in the north. The samples were analysed for their chemical and isotopic compositions (18O, 2H, 3H, 13C, 14C, 34S). In the following, the results of these analyses are presented and discussed in terms of the recharge and flow regime of the groundwater and the origin and evolution of its salinity. The results of geochemical and isotopic studies have shown that the groundwater is very eterogeneous and suggest the aquifer is replenished by recent water coming from direct infiltration from rain. At

  2. Hydrology of aquifer systems in the Memphis area, Tennessee

    Science.gov (United States)

    Criner, James H.; Sun, P-C. P.; Nyman, Dale J.

    1964-01-01

    The Memphis area as described in .this report comprises about 1,300 square miles of the Mississippi embayment part of the Gulf Coastal Plain. The area is underlain by as much as 3,000 feet of sediments ranging in age from Cretaceous through Quaternary. In 1960, 150 mgd (million gallons per day) of water was pumped from the principal aquifers. Municipal pumpage accounted for almost half of this amount, and industrial pumpage a little more than half. About 90 percent of the water used in the area is derived from the '500-foot' sand, and most of the remainder is from the ?400-foot' sand; both sands are of Eocene age. A small amount of water for domestic use is pumped from the terrace deposits of Pliocene and Pleistocene age. Both the '500-foot' and the '1,400-foot' sands are artesian aquifers except in the southeastern part of the area; there the water level in wells in the '500-foot' sand is now below the overlying confining clay. Water levels in both aquifers have declined almost continuously since pumping began, but the rate of decline has increased rapidly since 1940. Water-level decline in the '1,400-foot' sand has been less pronounced since 1956. The cones of depression in both aquifers have expanded and deepened as a result of the annual increases in pumping, and an increase in hydraulic gradients has induced a greater flow of water into the area. Approximately 135 mgd entered the Memphis area through the '500-foot' sand aquifer in 1960, and, of this amount, 60 mgd originated as inflow from the east and about 75 mgd was derived from leakage from the terrace deposits, from the north, south, and west and from other sources. Of the water entering the '1,400-foot' sand, about 5 mgd was inflow from the east, and about half that amount was from each of the north, south, and west directions. The average rate of movement of water outside the area of heavy withdrawals is about 70 feet per year in the '500-foot' sand and about 40 feet per year in the '1,400-foot' sand

  3. To what extent do long-duration high-volume dam releases influence river–aquifer interactions? A case study in New South Wales, Australia

    KAUST Repository

    Graham, Peter W.

    2014-11-20

    Long-duration high-volume dam releases are unique anthropogenic events with no naturally occurring equivalents. The impact from such dam releases on a downstream Quaternary alluvial aquifer in New South Wales, Australia, is assessed. It is observed that long-duration (>26 days), high-volume dam releases (>8,000 ML/day average) result in significant variations in river–aquifer interactions. These variations include a flux from the river to the aquifer up to 6.3 m3/day per metre of bank (at distances of up to 330 m from the river bank), increased extent and volume of recharge/bank storage, and a long-term (>100 days) reversal of river–aquifer fluxes. In contrast, during lower-volume events (<2,000 ML/day average) the flux was directed from the aquifer to the river at rates of up to 1.6 m3/day per metre of bank. A groundwater-head prediction model was constructed and river–aquifer fluxes were calculated; however, predicted fluxes from this method showed poor correlation to fluxes calculated using actual groundwater heads. Long-duration high-volume dam releases have the potential to skew estimates of long-term aquifer resources and detrimentally alter the chemical and physical properties of phreatic aquifers flanking the river. The findings have ramifications for improved integrated management of dam systems and downstream aquifers.

  4. Arsenic levels in groundwater aquifer

    African Journals Online (AJOL)

    Miodrag Jelic

    resistance (ρ); dielectric constant (ε); magnetic permeability (η); electrochemical activity ..... comprises grey sands of different particle size distribution ..... groundwater: testing pollution mechanisms for sedimentary aquifers in. Bangladesh.

  5. EPA Region 1 Sole Source Aquifers

    Data.gov (United States)

    U.S. Environmental Protection Agency — This coverage contains boundaries of EPA-approved sole source aquifers. Sole source aquifers are defined as an aquifer designated as the sole or principal source of...

  6. Synthesis and antibacterial activity screening of quaternary ...

    Indian Academy of Sciences (India)

    A series of quaternary ammonium derivatives of triazolyl pyranochromen-2-ones have been synthesized and characterized; their antibacterial potential were investigated against two gram negative (Pseudomonas aeruginosa and Escherichia coli) and two gram positive bacterial strains (Bacillus cereus and Staphylococcus ...

  7. The Plio-Quaternary Magdalena Turbidite System

    OpenAIRE

    Estrada, Ferran; Alonso, Belén; Ercilla, Gemma

    2011-01-01

    2006. Estrada F., Alonso B., Ercilla G. The Plio-Quaternary Magdalena Turbidite System. SEPM/Geological Society of London conference “External Controls on Deepwater Depositional Systems”, to be held at the Geological Society in Piccadilly, London, March 27th to 29th.

  8. Palladium-Catalyzed Asymmetric Quaternary Stereocenter Formation

    NARCIS (Netherlands)

    Gottumukkala, Aditya L.; Matcha, Kiran; Lutz, Martin; de Vries, Johannes G.; Minnaard, Adriaan J.

    2012-01-01

    An efficient palladium catalyst is presented for the formation of benzylic quaternary stereocenters by conjugate addition of arylboronic acids to a variety of beta,beta-disubstituted carbocyclic, heterocyclic, and acyclic enones. The catalyst is readily prepared from PdCl2, PhBOX, and AgSbF6, and

  9. Palladium-catalyzed asymmetric quaternary stereocenter formation

    NARCIS (Netherlands)

    Gottumukkala, A.L.; Matcha, K.; Lutz, M.; de Vries, J.G.; Minnaard, A.J.

    2012-01-01

    An efficient palladium catalyst is presented for the formation of benzylic quaternary stereocenters by conjugate addition of arylboronic acids to a variety of β,β-disubstituted carbocyclic, heterocyclic, and acyclic enones. The catalyst is readily prepared from PdCl2, PhBOX, and AgSbF6, and provides

  10. AQUIFER IN AJAOKUTA, SOUTHWESTERN NIGERIA

    African Journals Online (AJOL)

    2005-03-08

    Mar 8, 2005 ... To establish the feasibility of water supply in a basement complex area ofAjaokuta, Southwestern Nigeria, pumping test results were used to investigate the storage properties and groundwater potential of the aquifer. The aquifer system consists of weathered and weathered/fractured zone of decomposed ...

  11. Radiocarbon dating for the Quaternary scientist

    International Nuclear Information System (INIS)

    Pilcher, J.R.

    1991-01-01

    The accuracy of many conventional and accelerator mass spectrometry (AMS) radiocarbon dates is not adequate for the sort of questions now being asked in Quaternary studies. The need for, and effects of, radiocarbon calibration are discussed and guide-lines offered for the selection of a laboratory. High precision laboratories and the use of wiggle matching will go a long way to answering the critical questions of rates of change and durations of events in the Holocene. (Author)

  12. Application of the top specified boundary layer (TSBL) approximation to initial characterization of an inland aquifer mineralization: 2. Seepage of saltwater through semi-confining layers

    Science.gov (United States)

    Rubin, H.; Buddemeier, R.W.

    1998-01-01

    This paper presents a generalized basic study that addresses practical needs for an understanding of the major mechanisms involved in the mineralization of groundwater in the Great Bend Prairie aquifer in south- central Kansas. This Quaternary alluvial aquifer and associated surface waters are subject to contamination by saltwater, which in some areas seeps from the deeper Permian bedrock formation into the overlying freshwater aquifer through semiconfining layers. A simplified conceptual model is adopted. It incorporates the freshwater aquifer whose bottom is comprised of a semiconfining layer through which a hydrologically minor but geochemically important saline water discharge seeps into the aquifer. A hierarchy of approximate approaches is considered to analyze the mineralization processes taking place in the aquifer. The recently developed top specified boundary layer (TSBL) approach is very convenient to use for the initial characterization of these processes, and is further adapted to characterization of head-driven seepage through semi-confining layers. TSBL calculations indicate that the seeping saline water may create two distinct new zones in the aquifer: (1) a completely saline zone (CSZ) adjacent to the semiconfining bottom of the aquifer, and (2) a transition zone (TZ) which develops between the CSZ and the freshwater zone. Some possible scenarios associated with the various mineralization patterns are analyzed and discussed.

  13. To what extent do long-duration high-volume dam releases influence river-aquifer interactions? A case study in New South Wales, Australia

    Science.gov (United States)

    Graham, P. W.; Andersen, M. S.; McCabe, M. F.; Ajami, H.; Baker, A.; Acworth, I.

    2015-03-01

    Long-duration high-volume dam releases are unique anthropogenic events with no naturally occurring equivalents. The impact from such dam releases on a downstream Quaternary alluvial aquifer in New South Wales, Australia, is assessed. It is observed that long-duration (>26 days), high-volume dam releases (>8,000 ML/day average) result in significant variations in river-aquifer interactions. These variations include a flux from the river to the aquifer up to 6.3 m3/day per metre of bank (at distances of up to 330 m from the river bank), increased extent and volume of recharge/bank storage, and a long-term (>100 days) reversal of river-aquifer fluxes. In contrast, during lower-volume events (bank. A groundwater-head prediction model was constructed and river-aquifer fluxes were calculated; however, predicted fluxes from this method showed poor correlation to fluxes calculated using actual groundwater heads. Long-duration high-volume dam releases have the potential to skew estimates of long-term aquifer resources and detrimentally alter the chemical and physical properties of phreatic aquifers flanking the river. The findings have ramifications for improved integrated management of dam systems and downstream aquifers.

  14. Is Quaternary geology ready for the future?

    Science.gov (United States)

    Ritter, Dale F.

    1996-07-01

    Armed with a better understanding of process and an array of developing dating techniques, Quaternary geology is poised to achieve greater recognition in the general scientific community. This recognition however, will require some thought adjustment. Quaternary geologists will have to convince government, industry and a variety of scientific groups that they possess unique training and expertise that is needed as part of the thrust to fully understand and/or resolve major scientific problems. Therefore, future research and education efforts should not focus on developing a rigidly defined identity within geoscience, but instead should seek ways to be integrated with interdisciplinary teams that will investigate complex environmental and climate change problems. Such a scenaria creates and enermous dilemma for Quaternary geologists because they will derive greater intellectual stimulation from scientists working in discplines other than geology, and their scientific collaboratiors will most likely not be their academic colleagues. This outward expansion of our scientific network will require the development of interdsciplinary research collaboration and/or degree-granting programs at the graduate level. To accomplish such goals, universities must resist "turf protection", and funding agencies muts become more efficient at facilitating interdisciplinary research.

  15. DNA Barcoding through Quaternary LDPC Codes.

    Science.gov (United States)

    Tapia, Elizabeth; Spetale, Flavio; Krsticevic, Flavia; Angelone, Laura; Bulacio, Pilar

    2015-01-01

    For many parallel applications of Next-Generation Sequencing (NGS) technologies short barcodes able to accurately multiplex a large number of samples are demanded. To address these competitive requirements, the use of error-correcting codes is advised. Current barcoding systems are mostly built from short random error-correcting codes, a feature that strongly limits their multiplexing accuracy and experimental scalability. To overcome these problems on sequencing systems impaired by mismatch errors, the alternative use of binary BCH and pseudo-quaternary Hamming codes has been proposed. However, these codes either fail to provide a fine-scale with regard to size of barcodes (BCH) or have intrinsic poor error correcting abilities (Hamming). Here, the design of barcodes from shortened binary BCH codes and quaternary Low Density Parity Check (LDPC) codes is introduced. Simulation results show that although accurate barcoding systems of high multiplexing capacity can be obtained with any of these codes, using quaternary LDPC codes may be particularly advantageous due to the lower rates of read losses and undetected sample misidentification errors. Even at mismatch error rates of 10(-2) per base, 24-nt LDPC barcodes can be used to multiplex roughly 2000 samples with a sample misidentification error rate in the order of 10(-9) at the expense of a rate of read losses just in the order of 10(-6).

  16. DNA Barcoding through Quaternary LDPC Codes.

    Directory of Open Access Journals (Sweden)

    Elizabeth Tapia

    Full Text Available For many parallel applications of Next-Generation Sequencing (NGS technologies short barcodes able to accurately multiplex a large number of samples are demanded. To address these competitive requirements, the use of error-correcting codes is advised. Current barcoding systems are mostly built from short random error-correcting codes, a feature that strongly limits their multiplexing accuracy and experimental scalability. To overcome these problems on sequencing systems impaired by mismatch errors, the alternative use of binary BCH and pseudo-quaternary Hamming codes has been proposed. However, these codes either fail to provide a fine-scale with regard to size of barcodes (BCH or have intrinsic poor error correcting abilities (Hamming. Here, the design of barcodes from shortened binary BCH codes and quaternary Low Density Parity Check (LDPC codes is introduced. Simulation results show that although accurate barcoding systems of high multiplexing capacity can be obtained with any of these codes, using quaternary LDPC codes may be particularly advantageous due to the lower rates of read losses and undetected sample misidentification errors. Even at mismatch error rates of 10(-2 per base, 24-nt LDPC barcodes can be used to multiplex roughly 2000 samples with a sample misidentification error rate in the order of 10(-9 at the expense of a rate of read losses just in the order of 10(-6.

  17. Evaluating the rate of migration of an uranium deposition front within the Uitenhage Aquifer

    CSIR Research Space (South Africa)

    Vogel

    1999-07-01

    Full Text Available of Geochemical Exploration 66 (1999) 269?276 www.elsevier.com/locate/jgeoexp Evaluating the rate of migration of an uranium deposition front within the Uitenhage Aquifer J.C. Vogel a,A.S.Talmaa, T.H.E. Heaton b, J. Kronfeld c,* a Quaternary Dating Research Unit... stream_source_info vogel_1999.pdf.txt stream_content_type text/plain stream_size 18078 Content-Encoding ISO-8859-1 stream_name vogel_1999.pdf.txt Content-Type text/plain; charset=ISO-8859-1 ELSEVIER Journal...

  18. Susceptibility to saline contamination of coastal confined aquifer of the Uraba banana axis with hydrogeochemical and isotopic techniques

    International Nuclear Information System (INIS)

    Paredes Zuniga, Vanessa

    2010-01-01

    The project has covered an area of study of 8916 km 2 is located in the Northwestern part of the Department of Antioquia, Colombia. Interest area is geologically constituted by tertiary sedimentary rocks (T1 and T2) and alluvial deposits (Quaternary). Hydrogeological units, potentially better use of groundwater, have been established for the unit T2 (confined aquifer) and quaternary deposits.) The area has been of 2600 mm/year to 3600 mm/year of average rainfall. The susceptibility to saline contamination has been determined of coastal aquifer of the Uraba banana axis. Hydrochemical and geological information, geophysics, hydraulic and hydrochemical is used improving existing conceptual hydrogeological model. A hydrochemical characterization has been performed to evaluate the processes of salinity in the confined aquifer. The integration of geological information, geophysical and hydrogeological has been methodology used to validate the hydraulic characteristics of the aquifer, its geometry and operation, updating the conceptual hydrogeological model. The use of complementary tools been able to determine and identify processes that may affect natural physico-chemical characteristics of groundwater. The results have showed that salinization processes present in the coastal aquifer of Uraba Banana Axis could be linked to water-rock interaction, to mixtures with water have become saline as a result of transgression - regression processes in the former study. The hydrogeochemical techniques have become a complementary tool to the hydrogeology allowing respond the questions were presented in complex systems, such as the case of coastal aquifers, where sanitation is usually associated with saline intrusion processes and can also be obeying the conjunction with other hydroclimatological and hydrodynamic aspects. (author) [es

  19. aquifer in ajaokuta, southwestern nigeria

    African Journals Online (AJOL)

    2005-03-08

    Mar 8, 2005 ... (1969) straight line method (observation well) of draw-down analysis in an unconfined aquifer (B=1) yield ... April) and a short wet season (May-September). .... DECOMPOSED. GRANITIC ROCK WITH. QUARTZ VEINS. 13.

  20. Groundwater Dynamics in Fossil Fractured Carbonate Aquifers in Eastern Arabian Peninsula

    Science.gov (United States)

    Farag, A. Z. A.; Heggy, E.; Helal, M.; Thirunavukkarasu, D.; Scabbia, G.; Palmer, E. M.

    2017-12-01

    The Eastern Arabian Peninsula, notably the Qatar Peninsula, represents one of the highest natural groundwater discharge areas for the Arabian platform fossil aquifer system. Groundwater flow dynamics in these aquifers trace the paleoclimatic conditions that have prevailed the Arabian Peninsula during the Quaternary. In such settings, connections between aquifers strongly affect the flow dynamics, water quality and availability as well as karst formation and landscape evolution. Geological structures such as folds, faults and fractures are central to aquifer connectivity, yet their role on groundwater flow is poorly understood. Herein, we performed a detailed mapping of exposed and buried structural features in Qatar using Landsat, Sentinel and ALOS-PalSAR scenes, correlated with field and laboratory measurements to understand their role in aquifer connectivity and groundwater dynamics. Our results suggest that E-W oriented fold-related faults act as vertical conduits along which artesian upward leakages from the deep aquifers (e.g. Aruma and Umm er Radhuma) take place into the shallower aquifers (e.g. Rus and Dammam). Evidence includes: (1) the high potentiometric surfaces of deep aquifers (6 to 25 m amsl) compare to the shallower aquifers (2-3 m amsl for the same region); (2) anomalous elevation of groundwater levels and steeper hydraulic gradients in densely faulted regions; (3) mixed isotopic composition in shallow aquifers (δ18O: -5 to -2 ‰, δ2H: -40 to -10 ‰) between reported deep fossil waters (δ18O: -6.3 ‰, δ2H: -55 ‰) and modern meteoric waters (weighted average: δ18O: -0.6 ‰, δ2H: 4 ‰); (4) abundant meso-crystalline fibrous gypsum veins along fault zones in the Dammam Formation (up to 28 m amsl) in southern Qatar where the anhydritic member of the Rus Formation predominates the subsurface leading to gypsum oversaturation of groundwater. The similarity of crystal morphology (platy crystals under SEM), mineralogical compositions from XRD

  1. Study of the leakage between two aquifers in Hermosillo, Mexico, using environmental isotopes

    International Nuclear Information System (INIS)

    Payne, B.R.; Quijano, L.; Latorre, D.C.

    1980-01-01

    The Coast of Hermosillo is located in the Gulf of California, Mexico. It is a Quaternary alluvial plain of continental origin. Underlying these deposits is a layer of blue clay about 100m thick which imposes confinement to a deep aquifer in basaltic and pyroclastic rocks. Oxygen-18 and deuterium data support the occurrence of an upwardsleakage. The amount of the leakage was evaluated, on the basis of 14 C data, to a maximum of 20% of the water pumped by the irrigation wells in the upper aquifer. The stable isotope data also support the occurrence of sea-water intrusion by preferential channels in the south and in the area of Kino Bay. (author)

  2. EPA Region 1 Sole Source Aquifers

    Science.gov (United States)

    This coverage contains boundaries of EPA-approved sole source aquifers. Sole source aquifers are defined as an aquifer designated as the sole or principal source of drinking water for a given aquifer service area; that is, an aquifer which is needed to supply 50% or more of the drinking water for the area and for which there are no reasonable alternative sources should the aquifer become contaminated.The aquifers were defined by a EPA hydrogeologist. Aquifer boundaries were then drafted by EPA onto 1:24000 USGS quadrangles. For the coastal sole source aquifers the shoreline as it appeared on the quadrangle was used as a boundary. Delineated boundaries were then digitized into ARC/INFO.

  3. Uranium-series dating of Quaternary deposits

    International Nuclear Information System (INIS)

    Schwarcz, H.; Gascoyne, M.

    1984-01-01

    In view of the interest in the problem of time scales in geomorphology it is fortunate that there exists a number of geochronometers applicable to the measurement of the age of such young deposits. This paper is specifically devoted to those which arise from the disequilibrium between the daughter isotopes of U-238 and U-235, and their respective parents. The authors describe applications to Quaternary continental deposits that can give information about climatic change (travertine, lacrustine limestones, pedogenic carbonates, detrinal sediments, volcanic rocks). (Auth.)

  4. Characterization of recharge processes in shallow and deeper aquifers using isotopic signatures and geochemical behavior of groundwater in an arsenic-enriched part of the Ganga Plain

    International Nuclear Information System (INIS)

    Saha, Dipankar; Sinha, U.K.; Dwivedi, S.N.

    2011-01-01

    Research highlights: → Sub-regional scale aquifers delineated in arsenic-enriched belt in the Ganga Plain. Isotopic fingerprint of the groundwater, from arsenic-enriched and arsenic-safe aquifers established for the first time in the Ganga Plain. → Recharge processes and the water provenances of vertically separated Quaternary aquifers have been established. → Mean residence time of groundwater in the deeper aquifers has been worked out using C-14 isotope. → Water from the deeper aquifer has been correlated with the paleoclimatic model of the Middle Ganga Plain (Mid-Ganga Basin) for 6-2 ka. - Abstract: Arsenic concentrations in groundwater extracted from shallow aquifers in some areas of the Ganga Plain in the states of Bihar and Uttar Pradesh, exceed 50 μg L -1 and locally reach levels in the 400 μg L -1 range. The study covered 535 km 2 of active flood plain of the River Ganga, in Bihar where a two-tier aquifer system has been delineated in a multi-cyclic sequence of Quaternary sand, clay, sandy clay and silty clay all ≤∼250 m below ground surface. The research used isotopic signatures (δ 18 O, δ 2 Η, 3 H, 14 C) and major chemical constituents (HCO 3 - ,SO 4 2- ,NO 3 - ,Cl - ,Ca 2+ ,Mg 2+ ,Na + ,K + ,As total ) of groundwater to understand the recharge processes and groundwater circulation in the aquifers. Values of δ 18 O and δ 2 Η combined with 3 H data indicate that the recharge to the As-enriched top 40 m of the deposits is modern ( -1 ) is hydrologically isolated from the upper aquifer and is characterized by lower 14 C concentration and lower (more negative) δ 18 O values. Groundwater in the lower aquifer is ∼3 ka old, occurs under semi-confined to confined conditions, with hydrostatic head at 1.10 m above the head of the upper aquifer during the pre-monsoon. The recharge areas of the lower aquifer lies in Pleistocene deposits in basin margin areas with the exposed Vindhyan System, at about 55 km south of the area.

  5. Karst Aquifer Recharge: A Case History of over Simplification from the Uley South Basin, South Australia

    Directory of Open Access Journals (Sweden)

    Nara Somaratne

    2015-02-01

    Full Text Available The article “Karst aquifer recharge: Comments on ‘Characteristics of Point Recharge in Karst Aquifers’, by Adrian D. Werner, 2014, Water 6, doi:10.3390/w6123727” provides misrepresentation in some parts of Somaratne [1]. The description of Uley South Quaternary Limestone (QL as unconsolidated or poorly consolidated aeolianite sediments with the presence of well-mixed groundwater in Uley South [2] appears unsubstantiated. Examination of 98 lithological descriptions with corresponding drillers’ logs show only two wells containing bands of unconsolidated sediments. In Uley South basin, about 70% of salinity profiles obtained by electrical conductivity (EC logging from monitoring wells show stratification. The central and north central areas of the basin receive leakage from the Tertiary Sand (TS aquifer thereby influencing QL groundwater characteristics, such as chemistry, age and isotope composition. The presence of conduit pathways is evident in salinity profiles taken away from TS water affected areas. Pumping tests derived aquifer parameters show strong heterogeneity, a typical characteristic of karst aquifers. Uley South QL aquifer recharge is derived from three sources; diffuse recharge, point recharge from sinkholes and continuous leakage of TS water. This limits application of recharge estimation methods, such as the conventional chloride mass balance (CMB as the basic premise of the CMB is violated. The conventional CMB is not suitable for accounting chloride mass balance in groundwater systems displaying extreme range of chloride concentrations and complex mixing [3]. Over simplification of karst aquifer systems to suit application of the conventional CMB or 1-D unsaturated modelling as described in Werner [2], is not suitable use of these recharge estimation methods.

  6. Estimating Groundwater Mounding in Sloping Aquifers for Managed Aquifer Recharge.

    Science.gov (United States)

    Zlotnik, Vitaly A; Kacimov, Anvar; Al-Maktoumi, Ali

    2017-11-01

    Design of managed aquifer recharge (MAR) for augmentation of groundwater resources often lacks detailed data, and simple diagnostic tools for evaluation of the water table in a broad range of parameters are needed. In many large-scale MAR projects, the effect of a regional aquifer base dip cannot be ignored due to the scale of recharge sources (e.g., wadis, streams, reservoirs). However, Hantush's (1967) solution for a horizontal aquifer base is commonly used. To address sloping aquifers, a new closed-form analytical solution for water table mound accounts for the geometry and orientation of recharge sources at the land surface with respect to the aquifer base dip. The solution, based on the Dupiuit-Forchheimer approximation, Green's function method, and coordinate transformations is convenient for computing. This solution reveals important MAR traits in variance with Hantush's solution: mounding is limited in time and space; elevation of the mound is strongly affected by the dip angle; and the peak of the mound moves over time. These findings have important practical implications for assessment of various MAR scenarios, including waterlogging potential and determining proper rates of recharge. Computations are illustrated for several characteristic MAR settings. © 2017, National Ground Water Association.

  7. Characterising aquifer treatment for pathogens in managed aquifer recharge.

    Science.gov (United States)

    Page, D; Dillon, P; Toze, S; Sidhu, J P S

    2010-01-01

    In this study the value of subsurface treatment of urban stormwater during Aquifer Storage Transfer Recovery (ASTR) is characterised using quantitative microbial risk assessment (QMRA) methodology. The ASTR project utilizes a multi-barrier treatment train to treat urban stormwater but to date the role of the aquifer has not been quantified. In this study it was estimated that the aquifer barrier provided 1.4, 2.6, >6.0 log(10) removals for rotavirus, Cryptosporidium and Campylobacter respectively based on pathogen diffusion chamber results. The aquifer treatment barrier was found to vary in importance vis-à-vis the pre-treatment via a constructed wetland and potential post-treatment options of UV-disinfection and chlorination for the reference pathogens. The risk assessment demonstrated that the human health risk associated with potable reuse of stormwater can be mitigated (disability adjusted life years, DALYs aquifer is integrated with suitable post treatment options into a treatment train to attenuate pathogens and protect human health.

  8. QUATERNARY HISTORY OF CEDRUS IN SOUTHERN EUROPE

    Directory of Open Access Journals (Sweden)

    D. Magri

    2012-05-01

    Full Text Available A database of 68 pollen records of Pleistocene age was compiled from the western Mediterranean regions, with the aim of reconstructing the history of Cedrus in south Europe during the last 2 Ma. Marine pollen records from the Alboran Sea suggest that Cedrus was present in Morocco throughout the Quaternary, while it was absent from the Iberian peninsula, except a possible local presence in a coastal site of southern Spain. In France, Cedrus pollen was recorded in Pliocene deposits, but its Quaternary finds are always very sparse and suggest a long distance origin of cedar pollen. Cedrus was widespread in all the Italian sites during the Early Pleistocene, but it is sporadically found in the Middle Pleistocene deposits. Although times and modes of the disappearance of Cedrus from Italy are not known, it appears that the marked climate changes occurred between 0.9 and 0.7 Ma determined its local extinction. A similar trend is found in Greece, where Cedrus may have persisted a little longer than in the Italian Peninsula. On the whole, the history of Cedrus in southern Europe indicates that it is a taxon vulnerable to global climate changes and warns of a future risk of extinction also in the rest of the Mediterranean Basin.

  9. Late Quaternary climate change shapes island biodiversity.

    Science.gov (United States)

    Weigelt, Patrick; Steinbauer, Manuel Jonas; Cabral, Juliano Sarmento; Kreft, Holger

    2016-04-07

    Island biogeographical models consider islands either as geologically static with biodiversity resulting from ecologically neutral immigration-extinction dynamics, or as geologically dynamic with biodiversity resulting from immigration-speciation-extinction dynamics influenced by changes in island characteristics over millions of years. Present climate and spatial arrangement of islands, however, are rather exceptional compared to most of the Late Quaternary, which is characterized by recurrent cooler and drier glacial periods. These climatic oscillations over short geological timescales strongly affected sea levels and caused massive changes in island area, isolation and connectivity, orders of magnitude faster than the geological processes of island formation, subsidence and erosion considered in island theory. Consequences of these oscillations for present biodiversity remain unassessed. Here we analyse the effects of present and Last Glacial Maximum (LGM) island area, isolation, elevation and climate on key components of angiosperm diversity on islands worldwide. We find that post-LGM changes in island characteristics, especially in area, have left a strong imprint on present diversity of endemic species. Specifically, the number and proportion of endemic species today is significantly higher on islands that were larger during the LGM. Native species richness, in turn, is mostly determined by present island characteristics. We conclude that an appreciation of Late Quaternary environmental change is essential to understand patterns of island endemism and its underlying evolutionary dynamics.

  10. Quaternary Ammonium Polyethyleneimine: Antibacterial Activity Ira

    International Nuclear Information System (INIS)

    Farber, Y.; Domb, A.G.; Golenser, J.; Beyth, N.; Weiss, E.I.

    2010-01-01

    Quaternary ammonium polyethyleneimine- (QA-PEI-) based nanoparticles were synthesized using two synthetic methods, reductive amination and N-alkylation. According to the first method, QA-PEI nanoparticles were synthesized by cross-linking with glutaraldehyde followed by reductive amination with octanal and further N-methylation with methyl iodide. The second method is based on crosslinking with dialkyl halide followed by N-alkylation with octyl halide and further N-methylation with methyl iodide. QA-PEI nanoparticles completely inhibited bacterial growth (>106 bacteria), including both Gram-positive, that is, Staphylococcus aureus at 80 μ/mL, and Gram-negative, that is, Escherichia coli at 320 μ/mL. Activity analysis revealed that the degree of alkylation and N-methylation of the QA-PEI nanoparticles plays a significant role in antibacterial activity of the reagent. The most potent compound was octyl alkylated QA-PEI alkylated at 1 : 1 mole ratio (primary amine of PEI monomer units/alkylating agent). Also, cytotoxicity studies on MAT-LyLu and MBT cell lines were performed with QA-PEI nanoparticles. These findings confirm previous reports that poly cations bearing quaternary ammonium moieties inhibit bacterial growth in vitro and have a potential use as additives in medical devices which need antibacterial properties.

  11. Quaternary magnetic excursions recorded in marine sediments.

    Science.gov (United States)

    Channell, J. E. T.

    2017-12-01

    This year is the golden (50th) anniversary of the first documentation of a magnetic excursion, the Laschamp excursion in volcanics from the Chaine des Puys (Bonhommet and Babkine, 1967). The first recording of an excursion in sediments was from the Blake Outer Ridge (Smith and Foster, 1969). Magnetic excursions are directional aberrations of the geomagnetic field apparently involving short-lived reversal of the main dipole field. They have durations of a few kyrs, and are therefore rarely recorded in sediments with mean sedimentation rates Palma), and 670 ka (Osaka Bay), implying at least 11 excursions in the Brunhes Chron. For the Matuyama Chron, excursions have been recorded in marine sediments at 868 ka (Kamikatsura?), 932 ka (Santa Rosa), 1051 ka (Intra-Jaramillo), 1115 ka (Punaruu), 1255 ka (Bjorn), 1476 ka (Gardar), 1580 ka (Gilsa), and 2737 ka (Porcupine). Excursions coincide with minima in relative paleointensity (RPI) records. Ages are from correlation of excursion records to oxygen isotope records in the same cores, and ice-volume calibration of the oxygen isotope template. The marine sediment record of excursions, combined with independent documentation of excursions in lavas with Ar/Ar age control, is progressively strengthening our knowledge of the excursion inventory in the Quaternary, and enhancing the importance of excursions and RPI in Quaternary stratigraphy.

  12. Aquifers Characterization and Productivity in Ellala Catchment ...

    African Journals Online (AJOL)

    user

    Aquifers Characterization and Productivity in Ellala Catchment, Tigray, ... using geological and hydrogeological methods in Ellala catchment (296.5km. 2. ) ... Current estimates put the available groundwater ... Aquifer characterization takes into.

  13. The origins of mercury found in the coastal aquifer of La Plana de Castellon (Eastern Spain)

    International Nuclear Information System (INIS)

    Lopez Gutierrez, J.; Garcia Menendez, O.; Ballesteros Navarro, B. J.

    2010-01-01

    Mercury was detected in the Plio-Quaternary detrital coastal aquifer of La Plana de Castellon in the second half of the 1990s in the area of Nules-Moncofar-Vall d'Uixo at concentrations of between 5 and 12 μg/L according to groundwater analysis. The most reliable hypothesis pointed originally to an anthropic origin, although no precise sources were identified. This paper describes the results of investigation undertaken by the Geological Survey of Spain (IGME) to either corroborate or reject this hypothesis. A wide sampling array was set up to collect groundwater, sediments, wastewaters and rainwater together with an exhaustive inventory of possible anthropic and natural sources of mercurial contamination. All these data were integrated into the geological and metallogenic context of the Plio-Quaternary sediments of the aquifer and the Mesozoic formations of its rim. The results have led us to arrive at a new hypothesis that points to a geogenic origin for the mercury, although is mobilisation would still appear be related to the intensive human exploitation of the groundwater in the area. (Author) 30 refs.

  14. Determination of hydrogeological conditions in large unconfined aquifer: A case study in central Drava plain (NE Slovenia)

    Science.gov (United States)

    Keršmanc, Teja; Brenčič, Mihael

    2016-04-01

    In several countries, many unregulated landfills exits which releasing harmful contaminations to the underlying aquifer. The Kidričevo industrial complex is located in southeastern part of Drava plain in NW Slovenia. In the past during the production of alumina and aluminum approximately 11.2 million tons of wastes were deposit directly on the ground on two landfills covering an area of 61 hectares. Hydrogeological studies were intended to better characterized conditions bellow the landfill. Geological and hydrogeological conditions of Quaternary unconfined aquifer were analyzed with lithological characterization of well logs and cutting debris and XRF diffraction of silty sediments on 9 boreholes. Hydrogeological conditions: hydraulic permeability aquifer was determined with hydraulic tests and laboratory grain size analyses where empirical USBR and Hazen methods were applied. Dynamics of groundwater was determined by groundwater contour maps and groundwater level fluctuations. The impact of landfill was among chemical analyses of groundwater characterised by electrical conductivity measurements and XRF spectrometry of sand sediments. The heterogeneous Quaternary aquifer composed mainly of gravel and sand, is between 38 m and 47.5 m thick. Average hydraulic permeability of aquifer is within the decade 10-3 m/s. Average hydraulic permeability estimated on grain size curves is 6.29*10-3 m/s, and for the pumping tests is 4.0*10-3 m/s. General direction of groundwater flow is from west to east. During high water status the groundwater flow slightly changes flow direction to the southwest and when pumping station in Kidričevo (NW of landfill) is active groundwater flows to northeast. Landfills have significant impact on groundwater quality.

  15. Absolute age determination of quaternary faults

    International Nuclear Information System (INIS)

    Cheong, Chang Sik; Lee, Seok Hoon; Choi, Man Sik

    2000-03-01

    To constrain the age of neotectonic fault movement, Rb-Sr, K-Ar, U-series disequilibrium, C-14 and Be-10 methods were applied to the fault gouges, fracture infillings and sediments from the Malbang, Ipsil, Wonwonsa faults faults in the Ulsan fault zone, Yangsan fault in the Yeongdeog area and southeastern coastal area. Rb-Sr and K-Ar data imply that the fault movement of the Ulan fault zone initiated at around 30 Ma and preliminary dating result for the Yang san fault is around 70 Ma in the Yeongdeog area. K-Ar and U-series disequilibrium dating results for fracture infillings in the Ipsil fault are consistent with reported ESR ages. Radiocarbon ages of quaternary sediments from the Jeongjari area are discordant with stratigraphic sequence. Carbon isotope data indicate a difference of sedimentry environment for those samples. Be-10 dating results for the Suryum fault area are consistent with reported OSL results

  16. Absolute age determination of quaternary faults

    Energy Technology Data Exchange (ETDEWEB)

    Cheong, Chang Sik; Lee, Seok Hoon; Choi, Man Sik [Korea Basic Science Institute, Seoul (Korea, Republic of)] (and others)

    2000-03-15

    To constrain the age of neotectonic fault movement, Rb-Sr, K-Ar, U-series disequilibrium, C-14 and Be-10 methods were applied to the fault gouges, fracture infillings and sediments from the Malbang, Ipsil, Wonwonsa faults faults in the Ulsan fault zone, Yangsan fault in the Yeongdeog area and southeastern coastal area. Rb-Sr and K-Ar data imply that the fault movement of the Ulan fault zone initiated at around 30 Ma and preliminary dating result for the Yang san fault is around 70 Ma in the Yeongdeog area. K-Ar and U-series disequilibrium dating results for fracture infillings in the Ipsil fault are consistent with reported ESR ages. Radiocarbon ages of quaternary sediments from the Jeongjari area are discordant with stratigraphic sequence. Carbon isotope data indicate a difference of sedimentry environment for those samples. Be-10 dating results for the Suryum fault area are consistent with reported OSL results.

  17. Quaternary coastal geology of Pernambuco State

    International Nuclear Information System (INIS)

    Dominguez, J.M.L.; Silva Pinto Bittencourt, A.C. da; Andrade Nery Leao, Z.M. de; Azevedo, A.E.G. de

    1990-01-01

    This paper presents a geological map of Quaternary deposits occuring along the coast of the State of Pernambuco. These deposits comprise: 1. two sets of beach-ridge terraces of Pleistocene (120,000 years B.P.) and Holocene (5,000 years B.P.) age; 2. paleolagoonal deposits (5,140-6,030 years B.P.); 3. sandstone and coralgal reefs with ages spanning from 1,830 to 5,170 years B.P.; and 4, alluvial, freshwater swamp, and coralgal reefs with ages spanning from 1,830 to 5,170 years B.P.; and 4. alluvial, freshwater swamp, and mangrove swamp deposits of Holocene age. Eighteen new radiocarbon dates of paleolagoonal deposits, sandstone reefs, coral, coralline algae, and vermetid gastropod incrustations are also reported herein. (author)

  18. Quaternary ammonium compounds – New occupational hazards

    Directory of Open Access Journals (Sweden)

    Agnieszka Lipińska-Ojrzanowska

    2014-10-01

    Full Text Available Quaternary ammonium compounds (QACs, quats belong to organic ionic chemical agents which display unique properties of both surfactants and disinfectants. Their wide distribution in the work environment and also in private households brings about new occupational hazards. This paper reviews reports about the health effects of QACs. QACs could play a role of sensitizers and irritants to the skin and mucous membranes. It is suspected that particular QACs can display an immunologic crossreactivity between each other and with other chemical compounds containing ammonium ion, such as muscle relaxants widely used in anesthesia. They may promote the development of airway allergy, however, the background mechanisms are still unclear and need to be further investigated. Until now, a few cases of occupational asthma induced by QACs have been described and their involvement in contact dermatitis has been documented. The possibility of anaphylaxis due to QACs cannot be excluded as well. Med Pr 2014;65(5:675–682

  19. Hydration Structure of the Quaternary Ammonium Cations

    KAUST Repository

    Babiaczyk, Wojtek Iwo

    2010-11-25

    Two indicators of the hydropathicity of small solutes are introduced and tested by molecular dynamics simulations. These indicators are defined as probabilities of the orientation of water molecules\\' dipoles and hydrogen bond vectors, conditional on a generalized distance from the solute suitable for arbitrarily shaped molecules. Using conditional probabilities, it is possible to distinguish features of the distributions in close proximity of the solute. These regions contain the most significant information on the hydration structure but cannot be adequately represented by using, as is usually done, joint distance-angle probability densities. Our calculations show that using our indicators a relative hydropathicity scale for the interesting test set of the quaternary ammonium cations can be roughly determined. © 2010 American Chemical Society.

  20. Residence times of groundwater and nitrate transport in coastal aquifer systems: Daweijia area, northeastern China

    International Nuclear Information System (INIS)

    Han, Dongmei; Cao, Guoliang; McCallum, James; Song, Xianfang

    2015-01-01

    Groundwater within the coastal aquifer systems of the Daweijia area in northeastern China is characterized by a large of variations (33–521 mg/L) in NO_3"− concentrations. Elevated nitrate concentrations, in addition to seawater intrusion in the Daweijia well field, both attributable to anthropogenic activities, may impact future water-management practices. Chemical and stable isotopic (δ"1"8O, δ"2H) analysis, "3H and CFCs methods were applied to provide a better understanding of the relationship between the distribution of groundwater mean residence time (MRT) and nitrate transport, and to identify sources of nitrate concentrations in the complex coastal aquifer systems. There is a relatively narrow range of isotopic composition (ranging from − 8.5 to − 7.0‰) in most groundwater. Generally higher tritium contents observed in the wet season relative to the dry season may result from rapid groundwater circulation in response to the rainfall through the preferential flow paths. In the well field, the relatively increased nitrate concentrations of groundwater, accompanied by the higher tritium contents in the wet season, indicate the nitrate pollution can be attributed to domestic wastes. The binary exponential and piston-flow mixing model (BEP) yielded feasible age distributions based on the conceptual model. The good inverse relationship between groundwater MRTs (92–467 years) and the NO_3"− concentrations in the shallow Quaternary aquifers indicates that elevated nitrate concentrations are attributable to more recent recharge for shallow groundwater. However, there is no significant relationship between the MRTs (8–411 years) and the NO_3"− concentrations existing in the carbonate aquifer system, due to the complex hydrogeological conditions, groundwater age distributions and the range of contaminant source areas. Nitrate in the groundwater system without denitrification effects could accumulate and be transported for tens of years, through the

  1. Residence times of groundwater and nitrate transport in coastal aquifer systems: Daweijia area, northeastern China

    Energy Technology Data Exchange (ETDEWEB)

    Han, Dongmei [Key Laboratory of Water Cycle & Related Land Surface Processes, Institute of Geographic Sciences and Natural Resources Research, Chinese Academy of Sciences, Beijing 100101 (China); National Centre for Groundwater Research and Training, Flinders University, GPO Box 2100, Adelaide, SA 5001 (Australia); Cao, Guoliang [National Centre for Groundwater Research and Training, Flinders University, GPO Box 2100, Adelaide, SA 5001 (Australia); Center for Water Research, College of Engineering, Peking University, Beijing 100871 (China); McCallum, James [National Centre for Groundwater Research and Training, Flinders University, GPO Box 2100, Adelaide, SA 5001 (Australia); School of the Environment, Flinders University, GPO Box 2100, Adelaide, SA 5001 (Australia); Song, Xianfang [Key Laboratory of Water Cycle & Related Land Surface Processes, Institute of Geographic Sciences and Natural Resources Research, Chinese Academy of Sciences, Beijing 100101 (China)

    2015-12-15

    Groundwater within the coastal aquifer systems of the Daweijia area in northeastern China is characterized by a large of variations (33–521 mg/L) in NO{sub 3}{sup −} concentrations. Elevated nitrate concentrations, in addition to seawater intrusion in the Daweijia well field, both attributable to anthropogenic activities, may impact future water-management practices. Chemical and stable isotopic (δ{sup 18}O, δ{sup 2}H) analysis, {sup 3}H and CFCs methods were applied to provide a better understanding of the relationship between the distribution of groundwater mean residence time (MRT) and nitrate transport, and to identify sources of nitrate concentrations in the complex coastal aquifer systems. There is a relatively narrow range of isotopic composition (ranging from − 8.5 to − 7.0‰) in most groundwater. Generally higher tritium contents observed in the wet season relative to the dry season may result from rapid groundwater circulation in response to the rainfall through the preferential flow paths. In the well field, the relatively increased nitrate concentrations of groundwater, accompanied by the higher tritium contents in the wet season, indicate the nitrate pollution can be attributed to domestic wastes. The binary exponential and piston-flow mixing model (BEP) yielded feasible age distributions based on the conceptual model. The good inverse relationship between groundwater MRTs (92–467 years) and the NO{sub 3}{sup −} concentrations in the shallow Quaternary aquifers indicates that elevated nitrate concentrations are attributable to more recent recharge for shallow groundwater. However, there is no significant relationship between the MRTs (8–411 years) and the NO{sub 3}{sup −} concentrations existing in the carbonate aquifer system, due to the complex hydrogeological conditions, groundwater age distributions and the range of contaminant source areas. Nitrate in the groundwater system without denitrification effects could accumulate and be

  2. Residence times of groundwater and nitrate transport in coastal aquifer systems: Daweijia area, northeastern China.

    Science.gov (United States)

    Han, Dongmei; Cao, Guoliang; McCallum, James; Song, Xianfang

    2015-12-15

    Groundwater within the coastal aquifer systems of the Daweijia area in northeastern China is characterized by a large of variations (33-521mg/L) in NO3(-) concentrations. Elevated nitrate concentrations, in addition to seawater intrusion in the Daweijia well field, both attributable to anthropogenic activities, may impact future water-management practices. Chemical and stable isotopic (δ(18)O, δ(2)H) analysis, (3)H and CFCs methods were applied to provide a better understanding of the relationship between the distribution of groundwater mean residence time (MRT) and nitrate transport, and to identify sources of nitrate concentrations in the complex coastal aquifer systems. There is a relatively narrow range of isotopic composition (ranging from -8.5 to -7.0‰) in most groundwater. Generally higher tritium contents observed in the wet season relative to the dry season may result from rapid groundwater circulation in response to the rainfall through the preferential flow paths. In the well field, the relatively increased nitrate concentrations of groundwater, accompanied by the higher tritium contents in the wet season, indicate the nitrate pollution can be attributed to domestic wastes. The binary exponential and piston-flow mixing model (BEP) yielded feasible age distributions based on the conceptual model. The good inverse relationship between groundwater MRTs (92-467years) and the NO3(-) concentrations in the shallow Quaternary aquifers indicates that elevated nitrate concentrations are attributable to more recent recharge for shallow groundwater. However, there is no significant relationship between the MRTs (8-411years) and the NO3(-) concentrations existing in the carbonate aquifer system, due to the complex hydrogeological conditions, groundwater age distributions and the range of contaminant source areas. Nitrate in the groundwater system without denitrification effects could accumulate and be transported for tens of years, through the complex carbonate

  3. Aquifer thermal energy stores in Germany

    International Nuclear Information System (INIS)

    Kabus, F.; Seibt, P.; Poppei, J.

    2000-01-01

    This paper describes the state of essential demonstration projects of heat and cold storage in aquifers in Germany. Into the energy supply system of the buildings of the German Parliament in Berlin, there are integrated both a deep brine-bearing aquifer for the seasonal storage of waste heat from power and heat cogeneration and a shallow-freshwater bearing aquifer for cold storage. In Neubrandenburg, a geothermal heating plant which uses a 1.200 m deep aquifer is being retrofitted into an aquifer heat storage system which can be charged with the waste heat from a gas and steam cogeneration plant. The first centralised solar heating plant including an aquifer thermal energy store in Germany was constructed in Rostock. Solar collectors with a total area of 1000m 2 serve for the heating of a complex of buildings with 108 flats. A shallow freshwater-bearing aquifer is used for thermal energy storage. (Authors)

  4. Reaction of subsurface coastal aquifers to climate and land use changes in Greece: modelling of groundwater refreshening patterns under natural recharge conditions

    Science.gov (United States)

    Lambrakis, N.; Kallergis, G.

    2001-05-01

    This paper studies the multicomponent ion exchange process and freshening time under natural recharge conditions for three coastal aquifers in Greece. Due to over-pumping and the dry years of 1980-1990 decline in groundwater quality has been observed in most of the Greek coastal aquifers. This decline is caused by a lack of reliable water resource management, water abstraction from great depths, and seawater intrusion resulting in a rise of the fresh/salt water interface (salinisation process) due to a negative water balance. The reverse phenomenon, which should lead to groundwater freshening, is a long process. The freshening process shows chromatographic patterns that are due to chemical reactions such as calcite dissolution and cation exchange, and simultaneously occurring transport and dispersion processes. Using the geochemical simulation codes PHREEQE and PHREEQM (Parkhurst et al., US Geol. Surv. Water Resour. Invest., 80-96 (1980) 210; Appelo and Postma, Geochemistry, Groundwater and Pollution (1994)), these patterns were analysed and the above-mentioned processes were simulated for carefully selected aquifers in Peloponnesus and Crete (Greece). Aquifers of the Quaternary basin of Glafkos in Peloponnesus, the Neogene formations in Gouves, Crete, and the carbonate aquifer of Malia, Crete, were examined as representative examples of Greek coastal aquifer salinisation. The results show that when pumping was discontinued, the time required for freshening under natural conditions of the former two aquifers is long and varies between 8000 and 10,000 years. The Malia aquifer on the other hand, has a freshening time of 15 years. Freshening time was shown to depend mainly on cation exchange capacities and the recharge rate of the aquifers.

  5. Agricultural contaminants in Quaternary aquitards: A review of occurrence and fate in North America

    Science.gov (United States)

    Rodvang, S. J.; Simpkins, W. W.

    2001-01-01

    The intensity of agriculture has increased significantly during the past 30 years, resulting in increased detection of agricultural contaminants (nutrients, pesticides, salts, trace elements, and pathogens) in groundwater. Till, glaciolacustrine, and loess deposits of Quaternary age compose the most common surficial deposits underlying agricultural areas in North America. Quaternary aquitards generally contain higher concentrations of solid organic carbon (SOC, as much as 1.4%), dissolved organic carbon (DOC, as much as 205 mg/L), and reduced sulfur (as much as 0.9%) than do aquifers. Their potential to sorb pesticides increases with the percent of older SOC, because diagenesis increases Koc. Denitrification consistently reduces nitrate to non-detectable levels in unweathered Quaternary aquitards. Organic carbon of Quaternary age is a more labile electron donor than carbon from shale clasts. Pyrite is a more labile electron donor than carbon in many instances. Unweathered Quaternary aquitards provide a high degree of protection for underlying aquifers, due to their large reserves of SOC and reduced sulfur for sorption and denitrification, combined with their typically low hydraulic conductivity. In contrast, agricultural contaminants are common in weathered Quaternary aquitards. Lower reserves of reduced sulfur and sorptive/labile organic carbon, and a higher bulk K due to fractures, limit their ability to attenuate nitrate and pesticides. Subsurface drainage, which is common in Quaternary aquitards because of high water tables, bypasses the attenuation capacity of Quaternary aquitards and facilitates the transport of agricultural contaminants to surface water. Résumé. L'agriculture s'est significativement accrue au cours des dernières 30 années, provoquant une détection plus fréquente dans les eaux souterraines de contaminants agricoles (engrais, pesticides, sels, éléments en traces et germes pathogènes). Les moraines, les formations glacio-lacustres et

  6. Comparison of GPS and Quaternary slip rates: Insights from a new Quaternary fault database for Central Asia

    Science.gov (United States)

    Mohadjer, Solmaz; Ehlers, Todd; Bendick, Rebecca; Mutz, Sebastian

    2016-04-01

    Previous studies related to the kinematics of deformation within the India-Asia collision zone have relied on slip rate data for major active faults to test kinematic models that explain the deformation of the region. The slip rate data, however, are generally disputed for many of the first-order faults in the region (e.g., Altyn Tagh and Karakorum faults). Several studies have also challenged the common assumption that geodetic slip rates are representative of Quaternary slip rates. What has received little attention is the degree to which geodetic slip rates relate to Quaternary slip rates for active faults in the India-Asia collision zone. In this study, we utilize slip rate data from a new Quaternary fault database for Central Asia to determine the overall relationship between Quaternary and GPS-derived slip rates for 18 faults. The preliminary analysis investigating this relationship uses weighted least squares and a re-sampling analysis to test the sensitivity of this relationship to different data point attributes (e.g., faults associated with data points and dating methods used for estimating Quaternary slip rates). The resulting sample subsets of data points yield a maximum possible Pearson correlation coefficient of ~0.6, suggesting moderate correlation between Quaternary and GPS-derived slip rates for some faults (e.g., Kunlun and Longmen Shan faults). Faults with poorly correlated Quaternary and GPS-derived slip rates were identified and dating methods used for the Quaternary slip rates were examined. Results indicate that a poor correlation between Quaternary and GPS-derived slip rates exist for the Karakorum and Chaman faults. Large differences between Quaternary and GPS slip rates for these faults appear to be connected to qualitative dating of landforms used in the estimation of the Quaternary slip rates and errors in the geomorphic and structural reconstruction of offset landforms (e.g., offset terrace riser reconstructions for Altyn Tagh fault

  7. Quaternary alluvial stratigraphy and palaeoclimatic reconstruction at the Thar margin

    DEFF Research Database (Denmark)

    Jain, M.; Tandon, S.K.

    2003-01-01

    Quaternary alluvial record at the Thar desert margin has been examined using the exposed succession along Mahudi, Sabarmati river, Western India. Different alluvial facies, their associations and granulometry have been studied for palaeoenvironmental reconstruction. Clay mineral indices smectite/...

  8. Potentiometric studies on quaternary complexes of dioxouranium(VI)

    Energy Technology Data Exchange (ETDEWEB)

    Kumari, Vinod; Chaturvedi, G K [Agra Coll., (India). Chemical Laboratories

    1979-10-01

    The formation of quaternary complexes of dioxouranium(VI) with three different organic acids (OX, MALN and SA, SSA, TAR or TMA) has been inferred from the potentiometric studies. The formation constants for the resulting triligand complexes have been evaluated.

  9. Spectroscopic markers of the TR quaternary transition in human hemoglobin.

    Science.gov (United States)

    Schirò, Giorgio; Cammarata, Marco; Levantino, Matteo; Cupane, Antonio

    2005-04-01

    In this work, we use a sol-gel protocol to trap and compare the R and T quaternary states of both the deoxygenated (deoxyHb) and carbonmonoxide (HbCO) derivatives of human hemoglobin. The near infrared optical absorption band III and the infrared CO stretching band are used to detect the effect of quaternary structure on the spectral properties of deoxyHb and HbCO; comparison with myoglobin allows for an assessment of tertiary and quaternary contributions to the measured band shifts. The RT transition is shown to cause a blue shift of the band III by approximately 35 cm(-1) for deoxyHb and a red shift of the CO stretching band by only approximately 0.3 cm(-1) for HbCO. This clearly shows that quaternary structure changes are transmitted to the heme pocket and that effects on deoxyHb are much larger than on HbCO, at least as far as the band energies are concerned. Experiments performed in the ample temperature interval of 300-10K show that the above quaternary structure effects are "static" and do not influence the dynamic properties of the heme pocket, at least as probed by the temperature dependence of band III and of the CO stretching band. The availability of quaternary structure sensitive spectroscopic markers and the quantitative measurement of the quaternary structure contribution to band shifts will be of considerable help in the analysis of flash-photolysis experiments on hemoglobin. Moreover, it will enable one to characterize the dynamic properties of functionally relevant hemoglobin intermediates and to study the kinetics of both the T-->R and R-->T quaternary transitions through time-resolved spectroscopy.

  10. A Quaternary Geomagnetic Instability Time Scale

    Science.gov (United States)

    Singer, B. S.

    2013-12-01

    Reversals and excursions of Earth's geomagnetic field create marker horizons that are readily detected in sedimentary and volcanic rocks worldwide. An accurate and precise chronology of these geomagnetic field instabilities is fundamental to understanding several aspects of Quaternary climate, dynamo processes, and surface processes. For example, stratigraphic correlation between marine sediment and polar ice records of climate change across the cryospheres benefits from a highly resolved record of reversals and excursions. The temporal patterns of dynamo behavior may reflect physical interactions between the molten outer core and the solid inner core or lowermost mantle. These interactions may control reversal frequency and shape the weak magnetic fields that arise during successive dynamo instabilities. Moreover, weakening of the axial dipole during reversals and excursions enhances the production of cosmogenic isotopes that are used in sediment and ice core stratigraphy and surface exposure dating. The Geomagnetic Instability Time Scale (GITS) is based on the direct dating of transitional polarity states recorded by lava flows using the 40Ar/39Ar method, in parallel with astrochronologic age models of marine sediments in which O isotope and magnetic records have been obtained. A review of data from Quaternary lava flows and sediments yields a GITS comprising 10 polarity reversals and 27 excursions during the past 2.6 million years. Nine of the ten reversals bounding chrons and subchrons are associated with 40Ar/39Ar ages of transitionally-magnetized lava flows. The tenth, the Guass-Matuyama chron boundary, is tightly bracketed by 40Ar/39Ar dated ash deposits. Of the 27 well-documented excursions, 14 occurred during the Matuyama chron and 13 during the Brunhes chron; 19 have been dated directly using the 40Ar/39Ar method on transitionally-magnetized volcanic rocks and form the backbone of the GITS. Excursions are clearly not the rare phenomena once thought

  11. Hydro geochemistry and isotopic approach of coastal aquifer systems of Cap Bon : The case of tablecloths and the eastern coast of El Haourai - Tunisia

    International Nuclear Information System (INIS)

    Ben Hammouda, Fethi

    2008-01-01

    As many other semi-arid regions, the Cap Bon peninsula (N.E. Tunisia) shows a parallel increase in overexploitation and mineralization of groundwater resources. In the eastern coast and El Haouaria aquifers, the groundwater quality is threatened. Surveys including level measurements, water sampling, chemical analysis (ions Na+, Cl., Ca2+, Mg2+, Br.) and sotopes (18O, 2H, 3H, 13C, 14C) were performed in 2001, 2002 and 2003. Several analysis types were conducted and results are compared with the hydrodynamic information for identifying the main processes involved in the mineralization increase. Particularly, the isotopes were permitting the understanding of the hydrogeological of the concerned aquifers and the localization of the recharge zones. Because the regional situation along the seashore, the seawater intrusion in the unconfined Plio-quaternary aquifer, resulting from the groundwater overexploitation, and obvious explanation for the rising salinity is identified but is not the only cause of the qualitative degradation: the irrigation development that induces the soil leaching and the fertilizers transfer to groundwater over the whole aquifer extent is another major reason of the mineralization increase. Piezometric and salinity maps of the Plio-quaternary aquifer were established. The continuous increase in pumping has created several depressions in the water table, up to 12 m below msl and induced a deterioration of the water quality. The temporal changes in water-table level and salinity are often similar which suggests a strong link between them. Several geochemical approaches were performed to identify the importance of the marine intrusion in the increase in mineralization. The salinity of the groundwater appears to originate from dissolution of minerals in the aquifer system

  12. Mutagenicity of quaternary ammonium salts containing carbohydrate moieties

    Energy Technology Data Exchange (ETDEWEB)

    Dmochowska, Barbara [Department of Carbohydrate Chemistry, University of Gdansk, Sobieskiego 18, 80-952 Gdansk (Poland); Piosik, Jacek; Woziwodzka, Anna [Intercollegiate Faculty of Biotechnology, University of Gdansk and Medical University of Gdansk, Kladki 24, 80-822 Gdansk (Poland); Sikora, Karol; Wisniewski, Andrzej [Department of Carbohydrate Chemistry, University of Gdansk, Sobieskiego 18, 80-952 Gdansk (Poland); Wegrzyn, Grzegorz, E-mail: wegrzyn@biotech.univ.gda.pl [Department of Molecular Biology, University of Gdansk, Kladki 24, 80-822 Gdansk (Poland)

    2011-10-15

    Highlights: {yields} A series of quaternary ammonium salts containing carbohydrate moieties, with configuration D-galacto, D-gluco and D-manno, was synthesized and characterized. {yields} The quaternary ammonium salts containing carbohydrate moieties revealed potent mutagenic activities, as assessed by using the Vibrio harveyi bioluminescence mutagenicity test. {yields} The N-[2-(D-glycopyranosyloxy)ethyl]-N,N,N-trimethylaminium salts were of the highest activity in the mutagenicity assay. {yields} We suggest that quaternary ammonium salts may be more hazardous than previously supposed. - Abstract: Quaternary ammonium salts are widely used in industrial, agricultural, healthcare and domestic applications. They are believed to be safe compounds, with little or no health hazard to humans. However, in this report, we demonstrate that a series of newly synthesized quaternary ammonium salts containing carbohydrate moieties reveal potent mutagenic activities, as assessed by using the Vibrio harveyi bioluminescence mutagenicity test. D-Gluco- and D-galacto-derivatives were found to have a higher mutagenic potential than D-manno-derivatives. Among the former groups of compounds, the N-[2-(D-glycopyranosyloxy)ethyl]-N,N,N-trimethylaminium salts were of the highest activity in the mutagenicity assay. These results suggest that the safety of quaternary ammonium salts may be lower than previously supposed, indicating a need for testing such compounds for their mutagenicity.

  13. Mutagenicity of quaternary ammonium salts containing carbohydrate moieties

    International Nuclear Information System (INIS)

    Dmochowska, Barbara; Piosik, Jacek; Woziwodzka, Anna; Sikora, Karol; Wisniewski, Andrzej; Wegrzyn, Grzegorz

    2011-01-01

    Highlights: → A series of quaternary ammonium salts containing carbohydrate moieties, with configuration D-galacto, D-gluco and D-manno, was synthesized and characterized. → The quaternary ammonium salts containing carbohydrate moieties revealed potent mutagenic activities, as assessed by using the Vibrio harveyi bioluminescence mutagenicity test. → The N-[2-(D-glycopyranosyloxy)ethyl]-N,N,N-trimethylaminium salts were of the highest activity in the mutagenicity assay. → We suggest that quaternary ammonium salts may be more hazardous than previously supposed. - Abstract: Quaternary ammonium salts are widely used in industrial, agricultural, healthcare and domestic applications. They are believed to be safe compounds, with little or no health hazard to humans. However, in this report, we demonstrate that a series of newly synthesized quaternary ammonium salts containing carbohydrate moieties reveal potent mutagenic activities, as assessed by using the Vibrio harveyi bioluminescence mutagenicity test. D-Gluco- and D-galacto-derivatives were found to have a higher mutagenic potential than D-manno-derivatives. Among the former groups of compounds, the N-[2-(D-glycopyranosyloxy)ethyl]-N,N,N-trimethylaminium salts were of the highest activity in the mutagenicity assay. These results suggest that the safety of quaternary ammonium salts may be lower than previously supposed, indicating a need for testing such compounds for their mutagenicity.

  14. Mobilization of arsenic and other naturally occurring contaminants in groundwater of the Main Ethiopian Rift aquifers.

    Science.gov (United States)

    Rango, Tewodros; Vengosh, Avner; Dwyer, Gary; Bianchini, Gianluca

    2013-10-01

    This study investigates the mechanisms of arsenic (As) and other naturally occurring contaminants (F(-), U, V, B, and Mo) mobilization from Quaternary sedimentary aquifers of the Main Ethiopian Rift (MER) and their enrichment in the local groundwater. The study is based on systematic measurements of major and trace elements as well as stable oxygen and hydrogen isotopes in groundwater, coupled with geochemical and mineralogical analyses of the aquifer rocks. The Rift Valley aquifer is composed of rhyolitic volcanics and Quaternary lacustrine sediments. X-ray fluorescence (XRF) results revealed that MER rhyolites (ash, tuff, pumice and ignimbrite) and sediments contain on average 72 wt. % and 65 wt. % SiO2, respectively. Petrographic studies of the rhyolites indicate predominance of volcanic glass, sanidine, pyroxene, Fe-oxides and plagioclase. The As content in the lacustrine sediments (mean = 6.6 mg/kg) was higher than that of the rhyolites (mean: 2.5 mg/kg). The lacustrine aquifers of the Ziway-Shala basin in the northern part of MER were identified as high As risk zones, where mean As concentration in groundwater was 22.4 ± 33.5 (range of 0.60-190 μg/L) and 54% of samples had As above the WHO drinking water guideline value of 10 μg/L. Field As speciation measurements showed that most of the groundwater samples contain predominantly (~80%) arsenate-As(V) over arsenite-As(III) species. The As speciation together with field data of redox potential (mean Eh = +73 ± 65 mV) and dissolved-O2 (6.6 ± 2.2 mg/L) suggest that the aquifer is predominantly oxidative. Water-rock interactions, including the dissolution of volcanic glass produces groundwater with near-neutral to alkaline pH (range 6.9-8.9), predominance of Na-HCO3 ions, and high concentration of SiO2 (mean: 85.8 ± 11.3 mg/L). The groundwater data show high positive correlation of As with Na, HCO3, U, B, V, and Mo (R(2) > 0.5; p groundwater indicates that Fe-oxides and oxyhydroxides minerals were saturated

  15. Study the mechanisms of recharge of the phreatic aquifers, south east egypt, using environmental isotopes and hydro geochemistry

    International Nuclear Information System (INIS)

    Hassan, T.M.; Awad, M.A.; Hamza, M.S.

    1994-01-01

    The recharge rate is the most critical factor to groundwater resources management especially in semi-arid and arid areas. This paper presents a study on the feasibility of a groundwater development plan for south east egypt area. Environmental stable isotopes (oxygen-18 and deuterium), and hydro geochemistry techniques were used to investigate the recharge sources of groundwater. The examined groundwater wells tap the quaternary, basement and Nubian sandstone aquifers. The isotopic compositions of these groundwater samples indicate that there is a mixing among three different sources of recharge, local precipitation, palaeo water and sea water intrusion along the coastal plain, from the hydrochemical point of view, the predominant water types reflect meteoric, as well as marine waters genesis. The changes in salinity depend upon the dissolution of terrestrial salts, distance from the catchment area and seepage from deep aquifers. 7 figs., 2 tabs

  16. New quaternary ammonium salts based decontaminants

    Directory of Open Access Journals (Sweden)

    Diana M. Popescu

    2014-06-01

    Full Text Available Decontamination after terrorist attacks or industrial accidents with biological and/or chemical agents („bio-chem“ must be fast and efficient, in order to reduce the number of victims and to eliminate the consequent damages. The decontamination of living biological agents (bacteria, viruses or nonliving ones (toxins, regulators and toxic chemicals could be accomplished by reactions of hydrolysis in various experimental conditions, in particular in alkaline medium, reactions with amines or ammonia, alcohols, phenols etc. and by their transformation into less toxic degradation products. “Bio-chem” intentional or unintentional contamination is a real risk, towards which an effective management must be available to prevent and control it. Decontamination is an essential measure to protect the personnel and the environment. Synthesis and testing of new „bio-chem“ decontaminants, based on quaternary ammonium salts, complete the arsenal of protection against chemical and biological agents. The most effective selected substances could be produced and used for decontamination in accordance with legal procedures

  17. Late Quaternary history of the Atacama Desert

    Science.gov (United States)

    Latorre, Claudio; Betancourt, Julio L.; Rech, Jason A.; Quade, Jay; Holmgren, Camille; Placzek, Christa; Maldonado, Antonio; Vuille, Mathias; Rylander, Kate A.; Smith, Mike; Hesse, Paul

    2005-01-01

    Of the major subtropical deserts found in the Southern Hemisphere, the Atacama Desert is the driest. Throughout the Quaternary, the most pervasive climatic influence on the desert has been millennial-scale changes in the frequency and seasonality of the scant rainfall, and associated shifts in plant and animal distributions with elevation along the eastern margin of the desert. Over the past six years, we have mapped modern vegetation gradients and developed a number of palaeoenvironmental records, including vegetation histories from fossil rodent middens, groundwater levels from wetland (spring) deposits, and lake levels from shoreline evidence, along a 1200-kilometre transect (16–26°S) in the Atacama Desert. A strength of this palaeoclimate transect has been the ability to apply the same methodologies across broad elevational, latitudinal, climatic, vegetation and hydrological gradients. We are using this transect to reconstruct the histories of key components of the South American tropical (summer) and extratropical (winter) rainfall belts, precisely at those elevations where average annual rainfall wanes to zero. The focus has been on the transition from sparse, shrubby vegetation (known as the prepuna) into absolute desert, an expansive hyperarid terrain that extends from just above the coastal fog zone (approximately 800 metres) to more than 3500 metres in the most arid sectors in the southern Atacama.

  18. Methane hydrates in quaternary climate change

    International Nuclear Information System (INIS)

    Kennett, J. P.; Hill, T. M.; Behl, R. J.

    2005-01-01

    The hydrate reservoir in marine sediments is known to contain a large volume of exchangeable carbon stored as solid methane hydrate and associated free gas. This reservoir has been shown to be potentially unstable in response to changing intermediate water temperature and sea level (pressure). Evidence continues to grow for past episodes of major methane release at times of climatic warming. Yet few studies of late Quaternary climate change include methane hydrates as an integral part of the global climate system, in spite of the largest known oscillations at this time in sea level and upper ocean temperature changes for the Cenozoic or earlier, conditions that favor instability of the methane hydrate reservoir. Abrupt increases in atmospheric methane recorded in polar ice cores are widely believed to have resulted, not from ocean-floor methane degassing, but instead from continental wetland activation, a hypothesis thus far unsupported by geological data. Furthermore, as part of this Wetland Methane Hypothesis, the abrupt methane increases have been seen as a response to climatic warming rather than contributing significantly to the change. An alternative view (formulated as the Clathrate Gun Hypothesis) is that the speed, magnitude and timing of abrupt climate change in the recent geologic past are consistent with the process of major degassing of methane hydrates. We summarize aspects of this hypothesis here and needs to test this hypothesis. (Author)

  19. Arsenic, microbes and contaminated aquifers

    Science.gov (United States)

    Oremland, Ronald S.; Stolz, John F.

    2005-01-01

    The health of tens of millions of people world-wide is at risk from drinking arsenic-contaminated well water. In most cases this arsenic occurs naturally within the sub-surface aquifers, rather than being derived from identifiable point sources of pollution. The mobilization of arsenic into the aqueous phase is the first crucial step in a process that eventually leads to human arsenicosis. Increasing evidence suggests that this is a microbiological phenomenon.

  20. Aquifer thermal-energy-storage modeling

    Science.gov (United States)

    Schaetzle, W. J.; Lecroy, J. E.

    1982-09-01

    A model aquifer was constructed to simulate the operation of a full size aquifer. Instrumentation to evaluate the water flow and thermal energy storage was installed in the system. Numerous runs injecting warm water into a preconditioned uniform aquifer were made. Energy recoveries were evaluated and agree with comparisons of other limited available data. The model aquifer is simulated in a swimming pool, 18 ft by 4 ft, which was filled with sand. Temperature probes were installed in the system. A 2 ft thick aquifer is confined by two layers of polyethylene. Both the aquifer and overburden are sand. Four well configurations are available. The system description and original tests, including energy recovery, are described.

  1. Investigation of the Present Recharge Rate and Recharge Origins in the Disi Sandstone Aquifer in Southern Jordan

    International Nuclear Information System (INIS)

    Kilani, S.F.

    2003-01-01

    This study presents a thorough investigation of recharge origins of the strategic Disi sandstone aquifer in southern Jordan. This aquifer is of substantial potential and huge extension most of which lies in Saudi Arabia. Disi groundwater infiltrated in the ground thousands of years ago and is not currently being replenished, therefore crucial management for this resource is very important. This aquifer is foreseen to provide 100 MCM/a of high quality drinking water to the Capital Amman in addition to the current use of about 60 MCM/a for agricultural activities in the area and to meet the water demand in the port of Aqaba. Origins and amount of recharge to groundwater is one critical aspect in resource management. A study to estimate recharge rate was conducted in the Quaternary sediments and sandstone's of Al Quwayra in southern Jordan where the average rainfall is less than 70 mm per year. Environmental chloride, deuterium and nitrate in the sand profiles in the vadose zone were the study tools. The study showed that recharge if present is a result of severe infrequent storm events and that the aquifer does not receive significant direct recharge from rain. The pollutant profiles in the unsaturated zone might give chronology of the recharge history

  2. Hydrogeochemical characteristics of groundwater in the coal-bearing aquifer of the Wugou coal mine, northern Anhui Province, China

    Science.gov (United States)

    Chen, Song; Gui, Herong

    2017-07-01

    Major ions, trace elements, and isotope concentrations were measured in 11 representative groundwater samples that were collected from a series of aquifers in the Wugou coal mine, Anhui Province. The geochemical characteristics of the groundwater samples were examined using conventional graphical and multivariate statistical approaches, and the results showed that almost all of the groundwater samples collected from the coal-bearing aquifer were the Na-SO4 type, whereas the samples from the Quaternary and the limestone aquifer were the Ca-SO4 and Na-Cl types, respectively. The groundwater in the study area is not suitable for drinking without treatment because of the higher values of total dissolved solids and other parameters, whereas the lower value of the sodium adsorption ratio indicates that it can be used for irrigation. The total rare earth element concentrations ranged from 0.0398 to 0.1874 mg/L, and had an average of 0.075 mg/L. There were negative cerium and positive europium anomalies in the groundwater. The δD and δ 18O values in groundwater ranged from -9.01 to -8.81 ‰, and from -74.7 to -71.4 ‰, respectively. Meteoric water with variable degrees of evaporation is the main source of the groundwater in the coal-bearing aquifer.

  3. Hydrochemistry of New Zealand's aquifers

    International Nuclear Information System (INIS)

    Rosen, M.R.

    2001-01-01

    Groundwater chemistry on a national scale has never been studied in New Zealand apart from a few studies on nitrate concentrations and pesticides. These studies are covered in Chapter 8 of this book. However general studies of groundwater chemistry, groundwater-rock interaction and regional characteristics of water quality have not been previously addressed in much detail. This is partly because New Zealand aquifers are relatively small on a world scale and are geologically and tectonically diverse (see Chapter 3). But New Zealand has also recently lacked a centralised agency responsible for groundwater quality, and therefore, no national assessments have been undertaken. In recent years, the Institute of Geological and Nuclear Sciences has managed a programme of collecting and analysing the groundwater chemistry of key New Zealand aquifers. This programme is called the National Groundwater Monitoring Programme (NGMP) and is funded by the New Zealand Public Good Science Fund. The programme started in 1990 using only 22 wells, with four regional authorities of the country participating. The NGMP now includes all 15 regional and unitary authorities that use groundwater and over 100 monitoring sites. The NGMP is considered a nationally significant database by the New Zealand Foundation for Research Science and Technology. The NGMP allows a national comparison of aquifer chemistries because the samples are all analysed at one laboratory in a consistent manner and undergo stringent quality control checks. Poor quality analyses are thus minimised. In addition, samples are collected quarterly so that long-term seasonal trends in water quality can be analysed, and the effects of changes in land use and the vulnerability of aquifers to contaminant leaching can be assessed. This chapter summarises the water quality data collected for the NGMP over the past 10 years. Some records are much shorter than others, but most are greater than three years. Additional information is

  4. An evaluation of aquifer intercommunication between the unconfined and Rattlesnake Ridge aquifers on the Hanford Site

    International Nuclear Information System (INIS)

    Jensen, E.J.

    1987-10-01

    During 1986, Pacific Northwest Laboratory conducted a study of a portion of the Rattlesnake Ridge aquifer (confined aquifer) that lies beneath the B Pond - Gable Mountain Pond area of the Hanford Site. The purpose was to determine the extent of intercommunication between the unconfined aquifer and the uppermost regionally extensive confined aquifer, referred to as the Rattlesnake Ridge aquifer. Hydraulic head data and chemical data were collected from the ground water in the study area during December 1986. The hydraulic head data were used to determine the effects caused by water discharged to the ground from B Pond on both the water table of the unconfined aquifer and the potentiometric surface of the confined aquifer. The chemical data were collected to determine the extent of chemical constituents migrating from the unconfined aquifer to the confined aquifer. Analysis of chemical constituents in the Rattlesnake Ridge aquifer demonstrated that communication between the unconfined and confined aquifers had occurred. However, the levels of contaminants found in the Rattlesnake Ridge aquifer during this study were below the DOE Derived Concentration Guides

  5. Aquifer Characterization and Groundwater Potential Assessment

    African Journals Online (AJOL)

    Timothy Ademakinwa

    Keywords: Aquifer Characterization, Groundwater Potential, Electrical Resistivity, Lithologic Logs ... State Water Corporation currently cannot meet the daily water ... METHOD OF STUDY ... sections which were constrained with the available.

  6. Late quaternary history and uranium isotopic compositions of ground water discharge deposits, Crater Flat, Nevada

    International Nuclear Information System (INIS)

    Paces, J.B.; Taylor, E.M.; Bush, C.

    1993-01-01

    Three carbonate-rich spring deposits are present near the southern end of Crater Flat, NV, approximately 18 km southwest of the potential high-level waste repository at Yucca Mountain. We have analyzed five samples of carbonate-rich material from two of the deposits for U and Th isotopic compositions. Resulting U-series disequilibrium ages indicate that springs were active at 18 ± 1, 30 ± 3, 45 ± 4 and >70 ka. These ages are consistent with a crude internal stratigraphy at one site. Identical ages for two samples at two separate sites suggest that springs were contemporaneous, at least in part, and were most likely part of the same hydrodynamic system. In addition, initial U isotopic compositions range from 2.8 to 3.8 and strongly suggest that ground water from the regional Tertiary-volcanic aquifer provided the source for these hydrogenic deposits. This interpretation, along with water level data from near-by wells suggest that the water table rose approximately 80 to 115 m above present levels during the late Quaternary and may have fluctuated repeatedly. Current data are insufficient to allow reconstruction of a detailed depositional history, however geochronological data are in a good agreement with other paleoclimatic proxy records preserved throughout the region. Since these deposits are down gradient from the potential repository site, the possibility of higher ground water levels in the future dramatically shortens both vertical and lateral ground water pathways and reduces travel times of transported radionuclides to potential discharge sites

  7. Late quaternary history and uranium isotopic compositions of ground water discharge deposits, Crater Flat, Nevada

    Science.gov (United States)

    Paces, James B.; Taylor, Emily M.; Bush, Charles

    1993-01-01

    Three carbonate-rich spring deposits are present near the southern end of Crater Flat, NV, approximately 18 km southwest of the potential high-level waste repository at Yucca Mountain. We have analyzed five samples of carbonate-rich material from two of the deposits for U and Th isotopic compositions. Resulting U-series disequilibrium ages indicate that springs were active at 18 ?? 1, 30 ?? 3, 45 ?? 4 and >70 ka. These ages are consistent with a crude internal stratigraphy at one site. Identical ages for two samples at two separate sites suggest that springs were contemporaneous, at least in part, and were most likely part of the same hydrodynamic system. In addition, initial U isotopic compositions range from 2.8 to 3.8 and strongly suggest that ground water from the regional Tertiary-volcanic aquifer provided the source for these hydrogenic deposits. This interpretation, along with water level data from near-by wells suggest that the water table rose approximately 80 to 115 m above present levels during the late Quaternary and may have fluctuated repeatedly. Current data are insufficient to allow reconstruction of a detailed depositional history, however geochronological data are in good agreement with other paleoclimatic proxy records preserved throughout the region. Since these deposits are down gradient from the potential repository site, the possibility of higher ground water levels in the future dramatically shortens both vertical and lateral ground water pathways and reduces travel times of transported radionuclides to potential discharge sites.

  8. Quaternary Magmatism in the Cascades - Geologic Perspectives

    Science.gov (United States)

    Hildreth, Wes

    2007-01-01

    Foreward The Cascade magmatic arc is a belt of Quaternary volcanoes that extends 1,250 km from Lassen Peak in northern California to Meager Mountain in Canada, above the subduction zone where the Juan de Fuca Plate plunges beneath the North American Plate. This Professional Paper presents a synthesis of the entire volcanic arc, addressing all 2,300 known Quaternary volcanoes, not just the 30 or so visually prominent peaks that comprise the volcanic skyline. Study of Cascade volcanoes goes back to the geological explorers of the late 19th century and the seminal investigations of Howel Williams in the 1920s and 1930s. However, major progress and application of modern scientific methods and instrumentation began only in the 1970s with the advent of systematic geological, geophysical, and geochemical studies of the entire arc. Initial stimulus from the USGS Geothermal Research Program was enhanced by the USGS Volcano Hazards Program following the 1980 eruption of Mount St. Helens. Together, these two USGS Programs have provided more than three decades of stable funding, staffing, and analytical support. This Professional Paper summarizes the resultant USGS data sets and integrates them with the parallel contributions of other investigators. The product is based upon an all-encompassing and definitive geological database, including chemical and isotopic analyses to characterize the rocks and geochronology to provide the critical time constraints. Until now, this massive amount of data has not been summarized, and a systematic and uniform interpretation firmly grounded in geological fact has been lacking. Herein lies the primary utility of this Cascade volume. It not only will be the mandatory starting point for new workers, but also will provide essential geological context to broaden the perspectives of current investigators of specific Cascade volcanoes. Wes Hildreth's insightful understanding of volcanic processes and his uncompromising scientific integrity make him

  9. Pseudoimpactites in anthropocenically overprinted quaternary sediments

    Science.gov (United States)

    Huber, Robert; Darga, Robert; Lauterbach, Hans

    2017-04-01

    Whereas typical anthropogenic materials such as plastics can easily be identified in the anthropocene record, other materials such as building materials or industrial waste often closely resemble natural rocks or minerals. Especially transported and weathered anthropocenic matter is hard to distinguish from natural rocks. Whereas most rock samples may easily be distinguished by visual inspection, definite identification of exotic and small sized matter is not always an easy exercise which has been shown during the controversial discussion on the cosmic origin of carbon spherules found in Younger Dryas sediments. Similarly, a variety of exotic materials and lithological phenomena reported from quaternary sediments in Upper Bavaria have been associated to a cosmic impact in the area. Findings of carbonatic regmaglypts, glass coated and fragmented rocks, glassy carbon or pumice like carbon have been proposed to represent impact related rocks, an hypothesis which has further been supported by findings of iron silicides and the postulated detection of nanodiamonds and Carbine. Many of these findings have been strongly doubted within the geoscientific community, however a systematic, independent investigation of these phenomena has not yet been conducted. We present the results of our examinations which have been carried out to critically test the impact related origin of the mentioned strange materials and rocks. We could identify some key sites and independently collected samples of several of the materials and analysed these thoroughly. We found that the majority of these impact related materials is of anthropogenic or biogenic origin, thus they are pseudoimpactites partly originating from old fireplaces and waste pits. The claimed cosmic origin of this matter is an illusion caused by the anthropocene overprint of the original sedimentary record.

  10. Groundwater origin investigation with isotopic compositions for evaluation of high productive deep aquifers in Khon Kaen area, Northeast Thailand

    International Nuclear Information System (INIS)

    Buaphan, C.; Yangme, W.; Wannakao, L.; Sriboonlue, V.; Tassanasorn, A.; Buapeng, S.

    1999-01-01

    Investigation of groundwater origin by using isotopic compositions for evaluation of high productive deep aquifers in Khon Kaen Province is emphasized on hydrogeology and isotopes technique. The study area consists of Mesozoic sedimentary rocks and unconsolidated sediments of Quaternary. Phu Tok aquifers in the southern part of the study area are mainly confined in very well sorted, fine grained sandstone as well as in fractures and joints. They extend from Ban Tha Pra to Ban Phai covering area 500 km 2 . Depth to the aquifers is from 20 to 250 m, while their piezometric surface ranges from 0.35 m to 15 m from the ground surface. Their thickness range from 50 to 100 m. The transmissivity is from 0.45 to 1,047 m 2 /d on the pumping rate of 48-1,200 m 3 /d with drawdown of less than 10% and rough annual safe yield is 83.34x10 6 m 3 . The water is very good in quality for drinking, except for the TDS and total hardness around aquifer boundary. The groundwater and surface water are analysed for stable and radioactive isotopes, including 2 H, 18 O, 3 H and 14 C. The results show that the shallow groundwater of the depth less than 50 m is originated by direct recharge of rainfall between 180 and 6,820 a. The groundwater flow is relatively rapid from west to east and northwest to southeast, the high productive deep aquifer of Phu Tok flow radiate from recharging area to all direction. However, the groundwater flow rate based on 14 C analyses for Phu Tok is 2 to 3 m/a. Within some areas the flow is about 8 m/a, while the unconsolidated aquifers along the Phong River give flow rate about 4 m/a. The deeper aquifers also have direct rain recharge the same as the above aquifers but the flow rate are lower, especially the deepest aquifer at the depth of nearly 200 m indicated no direct rain recharge with age of more than 20 000 a, which is confirmed with the amount of tritium less than 1.0 TU. (author)

  11. Gravimetry contributions to the study of the complex western Haouz aquifer (Morocco): Structural and hydrogeological implications

    Science.gov (United States)

    Chouikri, Ibtissam; el Mandour, Abdennabi; Jaffal, Mohammed; Baudron, Paul; García-Aróstegui, José-Luis; Manar, Ahmed; Casas, Albert

    2016-03-01

    This study provides new elements that illustrate the benefits of combining gravity, structural, stratigraphic and piezometric data for hydrogeological purposes. A combined methodology was applied to the western Haouz aquifer (Morocco), one of the main sources of water for irrigation and human consumption in the Marrakech region. First, a residual anomaly map was calculated from the Bouguer anomaly data. The computed map provided information on the ground density variation, revealing a strong control by a regional gradient. We then used various filtering techniques to delineate the major geological structures such as faults and basins: vertical and horizontal derivatives and upward continuation. This technique highlighted news structures and provided information on their dip. The gravity anomalies perfectly delineated the basement uplifts and the sedimentary thickening in depressions and grabens. The interpretation of gravimetric filtering, geological and hydrogeological data then highlighted two types of groundwater reservoirs, an unconfined aquifer hosted in conglomeratic mio-pliocene and quaternary rocks, covering the entire western Haouz and a deep confined aquifer contained in cenomanian-turonian limestone and eocene dolomitic formations in the south. Combining piezometric and residual anomaly maps revealed that groundwater flow and storage was in perfect agreement with the structures showing a negative anomaly, while structures with positive anomalies corresponded to groundwater divides. The study of gravity gradient zones by contact analysis enhanced the existing structural pattern of the study area and highlighted new structures, mainly oriented N70 and N130. The results of this study present a common framework and provide a notable step forward in the knowledge of the geometry and the groundwater flow pattern of the western Haouz aquifer, and will serve as a solid basis for a better water resource management.

  12. Quaternary naltrexone reverses radiogenic and morphine-induced locomotor hyperactivity

    Energy Technology Data Exchange (ETDEWEB)

    Mickley, G.A.; Stevens, K.E.; Galbraith, J.A.; White, G.A.; Gibbs, G.L.

    1984-04-01

    The present study attempted to determine the relative role of the peripheral and central nervous system in the production of morphine-induced or radiation-induced locomotor hyperactivity of the mouse. Toward this end, we used a quaternary derivative of an opiate antagonist (naltrexone methobromide), which presumably does not cross the blood-brain barrier. Quaternary naltrexone was used to challenge the stereotypic locomotor response observed in these mice after either an i.p. injection of morphine or exposure to 1500 rads /sup 60/Co. The quaternary derivative of naltrexone reversed the locomotor hyperactivity normally observed in the C57BL/6J mouse after an injection of morphine. It also significantly attenuated radiation-induced locomotion. The data reported here support the hypothesis of endorphin involvement in radiation-induced and radiogenic behaviors. However, these conclusions are contingent upon further research which more fully evaluates naltrexone methobromide's capacity to cross the blood-brain barrier.

  13. Absolute age determination of quaternary fault and formation

    Energy Technology Data Exchange (ETDEWEB)

    Cheong, Chang Sik; Lee, Kwang Sik; Choi, Man Sik [Korea Basic Science Institute, Seoul (Korea, Republic of)] (and others)

    2002-04-15

    The annual ('01-'01) objective of this project is to data the fault activity for the presumed quaternary fault zones to the western part of the Ulsam fault system and southeastern coastal area near the Wolseong Nuclear Power Plant. Rb-Sr, K-Ar, OSL, C-14 and U-series disequilibrium methods were applied to the fault rocks, organic matter and quaternary formations collected from the Pyeonghae, Bogyeongsa, Yugyeri, Byegkye, Gacheon-1 and Joil outcrops of the Yangsan fault system, the Baenaegol outcrop of the Moryang fault system, the Susyongji(Madong-2), Singye, Hwalseongri, Ipsil and Wonwonsa outcrops of the Ulsan fault system and from quaternary marine terraces (Oryoo and Kwangseong sites) in the southeastern coastal area. The experimental procedure of the OSL SAR protocol was reexamined to get more reliable dating results.

  14. All-optical conversion scheme: Binary to quaternary and quaternary to binary number

    Science.gov (United States)

    Chattopadhyay, Tanay; Roy, Jitendra Nath

    2009-04-01

    To achieve the inherent parallelism in optics a suitable number system and efficient encoding/decoding scheme for handling the data are very much essential. Binary number is accepted as the best representing number system in almost all types of existing electronic computers. But, binary number (0 and 1) is insufficient in respect to the demand of the coming generation. Multi-valued logic (with radix >2) can be viewed as an alternative approach to solve many problems in transmission, storage and processing of large amount of information in digital signal processing. Here, in this paper all-optical scheme for the conversion of binary to quaternary number and vice versa have been proposed and described. Simulation has also been done. In this all-optical scheme the numbers are represented by different discrete polarized state of light.

  15. Characterization of Quaternary and suspected Quaternary faults, Amargosa area, Nevada and California

    International Nuclear Information System (INIS)

    Anderson, R.E.; Crone, A.J.; Machette, M.N.; Bradley, L.A.; Diehl, S.F.

    1995-01-01

    This report presents the results of geologic studies that help define the Quaternary history of selected faults in the region around Yucca Mountain, Nevada. These results are relevant to the seismic-design basis of a potential nuclear waste repository at Yucca Mountain. The relevancy is based, in part, on a need for additional geologic data that became apparent in ongoing studies by S. Pezzopane (written commun., 1995) that resulted in the identification of 51 relevant and potentially relevant (see appendix A for definitions) individual and compound faults and fault zones in the 100-km-radius region around the Yucca Mountain site. These structures were divided into local and regional categories by Pezzopane (1995); this report deals with selected regional structures. In this introduction, the authors outline the scope and strategy of the studies and the tectonic environment of the studied structures

  16. Characterization of Quaternary and suspected Quaternary faults, Amargosa area, Nevada and California

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, R.E.; Crone, A.J.; Machette, M.N.; Bradley, L.A.; Diehl, S.F.

    1995-12-31

    This report presents the results of geologic studies that help define the Quaternary history of selected faults in the region around Yucca Mountain, Nevada. These results are relevant to the seismic-design basis of a potential nuclear waste repository at Yucca Mountain. The relevancy is based, in part, on a need for additional geologic data that became apparent in ongoing studies by S. Pezzopane (written commun., 1995) that resulted in the identification of 51 relevant and potentially relevant (see appendix A for definitions) individual and compound faults and fault zones in the 100-km-radius region around the Yucca Mountain site. These structures were divided into local and regional categories by Pezzopane (1995); this report deals with selected regional structures. In this introduction, the authors outline the scope and strategy of the studies and the tectonic environment of the studied structures.

  17. Diagnosis of the Ghiss Nekor aquifer in order to elaborate the aquifer contract

    Science.gov (United States)

    Baite, Wissal; Boukdir, A.; Zitouni, A.; Dahbi, S. D.; Mesmoudi, H.; Elissami, A.; Sabri, E.; Ikhmerdi, H.

    2018-05-01

    The Ghiss-Nekor aquifer, located in the north-east of the action area of the ABHL, plays a strategic role in the drinkable water supply of the city of Al Hoceima and of the neighboring urban areas. It also participates in the irrigation of PMH. However, this aquifer has problems such as over-exploitation and pollution. In the face of these problems, the only Solution is the establishment of a new mode of governance, which privileges the participation, the involvement and the responsibility of the actors concerned in a negotiated contractual framework, namely the aquifer contract. The purpose of this study is to diagnose the current state of the Ghiss Nekor aquifer, the hydrogeological characterization of the aquifer, the use of the waters of the aquifer, the Problem identification and the introduction of the aquifer contract, which aims at the participatory and sustainable management of underground water resources in the Ghiss- Nekor plain, to ensure sustainable development.

  18. Quaternary sediment thickness and bedrock topography of the glaciated United States east of the Rocky Mountains

    Science.gov (United States)

    Soller, David R.; Garrity, Christopher P.

    2018-01-26

    is called the Holocene and, together with the Pleistocene, constitutes the Quaternary Period of geologic time; this publication characterizes the three-dimensional geometry of the Quaternary sediments and the bedrock surface that lies beneath.The pre-glacial landscape was underlain mostly by weathered bedrock generally similar in nature to that found in many areas of the non-glaciated United States. Glacial erosion and redeposition of earth materials produced a young, mineral-rich soil that formed the basis for the highly productive agricultural economy in the U.S. midcontinent. Extensive buried sands and gravels within the glacial deposits also provided a stimulus to other economic sectors by serving as high-quality aquifers supplying groundwater to the region’s industry and cities. An understanding of the three-dimensional distribution of these glacial sediments has direct utility for addressing various societal issues including groundwater quality and supply, and landscape and soil response to earthquake-induced shaking.The Quaternary sediment thickness map and bedrock topographic map shown here provide a regional overview and are intended to supplement the more detailed work on which they are based. Detailed mapping is particularly useful in populated areas for site-specific planning. In contrast, regional maps such as these serve to place local, detailed mapping in context; to permit the extrapolation of data into unmapped areas; and to depict large-scale regional geologic features and patterns that are beyond the scope of local, detailed mapping. They also can enhance the reader’s general understanding of the region’s landscape and geologic history and provide a source of information for regional decision making that could benefit by improved predictability of bedrock depth beneath the unconsolidated Quaternary sediments. To enable these maps to be analyzed in conjunction with other types of information, this publication also includes the map data in GIS

  19. Geohydrology of the Cerro Prieto geothermal aquifer

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez R, J.; de la Pena L, A.

    1981-01-01

    The most recent information on the Cerro Prieto geothermal aquifer is summarized, with special emphasis on the initial production zone where the wells completed in the Alpha aquifer are located. These wells produce steam for power plant units 1 and 2. Brief comments also are made on the Beta aquifer, which underlies the Alpha aquifer in the Cerro Prieto I area and which extends to the east to what is known as the Cerro Prieto II and Cerro Prieto III areas. The location of the area studied is shown. The Alpha and Beta aquifers differ in their mineralogy and cementing mineral composition, temperatures, and piezometric levels. The difference in piezometric levels indicates that there is no local communication between the two aquifers. This situation has been verified by a well interference test, using well E-1 as a producer in the Beta aquifer and well M-46 as the observation well in the Alpha aquifer. No interference between them was observed. Information on the geology, geohydrology, and geochemistry of Cerro Prieto is presented.

  20. Estimating Aquifer Properties Using Sinusoidal Pumping Tests

    Science.gov (United States)

    Rasmussen, T. C.; Haborak, K. G.; Young, M. H.

    2001-12-01

    We develop the theoretical and applied framework for using sinusoidal pumping tests to estimate aquifer properties for confined, leaky, and partially penetrating conditions. The framework 1) derives analytical solutions for three boundary conditions suitable for many practical applications, 2) validates the analytical solutions against a finite element model, 3) establishes a protocol for conducting sinusoidal pumping tests, and 4) estimates aquifer hydraulic parameters based on the analytical solutions. The analytical solutions to sinusoidal stimuli in radial coordinates are derived for boundary value problems that are analogous to the Theis (1935) confined aquifer solution, the Hantush and Jacob (1955) leaky aquifer solution, and the Hantush (1964) partially penetrated confined aquifer solution. The analytical solutions compare favorably to a finite-element solution of a simulated flow domain, except in the region immediately adjacent to the pumping well where the implicit assumption of zero borehole radius is violated. The procedure is demonstrated in one unconfined and two confined aquifer units near the General Separations Area at the Savannah River Site, a federal nuclear facility located in South Carolina. Aquifer hydraulic parameters estimated using this framework provide independent confirmation of parameters obtained from conventional aquifer tests. The sinusoidal approach also resulted in the elimination of investigation-derived wastes.

  1. Electrochemical oxidation of quaternary ammonium electrolytes : Unexpected side reactions in organic electrochemistry

    NARCIS (Netherlands)

    Nouri Nigjeh, Eslam; de Vries, Marcel; Bruins, Andries P.; Bischoff, Rainer; Permentier, Hjalmar P.

    Quaternary ammonium salts are among the most widely used electrolytes in organic electrochemistry, but there is little known about their unwanted side oxidation reactions. We have, therefore, studied the constant potential oxidation products of quaternary ammonium electrolytes using mass

  2. Radio-labelled quaternary compounds and their diagnostic use

    International Nuclear Information System (INIS)

    Woo, D.V.

    1984-01-01

    Radio-labelled compounds having a lipophilic cation, which are quaternary ammonium, phosphonium or arsonium halides, in which the halide is a chloride, bromide or iodide, and in which the four quaternary substituents are independently selected from Csub(1-3) alkyl, phenyl and benzyl, at least two substituents being phenyl or benzyl, and one phenyl or benzyl substituent carrying a ring-substituent selected from 123 I, 125 I, 131 I, 77 Br, 82 Br and 18 F. Such compounds can be administered by injection, and a radio-image of the myocardium obtained. (author)

  3. Geochemistry of the Arbuckle-Simpson Aquifer

    Science.gov (United States)

    Christenson, Scott; Hunt, Andrew G.; Parkhurst, David L.; Osborn, Noel I.

    2009-01-01

    The Arbuckle-Simpson aquifer in south-central Oklahoma provides water for public supply, farms, mining, wildlife conservation, recreation, and the scenic beauty of springs, streams, and waterfalls. A new understanding of the aquifer flow system was developed as part of the Arbuckle-Simpson Hydrology Study, done in 2003 through 2008 as a collaborative research project between the State of Oklahoma and the Federal government. The U.S. Geological Survey collected 36 water samples from 32 wells and springs in the Arbuckle-Simpson aquifer in 2004 through 2006 for geochemical analyses of major ions, trace elements, isotopes of oxygen and hydrogen, dissolved gases, and dating tracers. The geochemical analyses were used to characterize the water quality in the aquifer, to describe the origin and movement of ground water from recharge areas to discharge at wells and springs, and to determine the age of water in the aquifer.

  4. On the origins of hypersaline groundwater in the Nile Delta Aquifer

    Science.gov (United States)

    van Engelen, Joeri; Oude Essink, Gualbert H. P.; Kooi, Henk; Bierkens, Marc F. P.

    2017-04-01

    The fresh groundwater resources in the Nile Delta, Egypt, are of eminent socio-economic importance. These resources are under major stress due to population growth, the anticipated sea level rise and increased groundwater extraction rates, making fresh water availability the most challenging issue in this area. Up till now, numerous groundwater studies mainly focused on sea water intrusion on the top 100m of the groundwater system and assumed salinities not exceeding that of Mediterranean sea water, as there was no knowledge on groundwater in the deeper coastal parts of the Quaternary Nile Delta aquifer (that ranges up to 1000m depth). Recently, however, the Egyptian Research Institute for Groundwater (RIGW) collected salinity measurements and found a widespread occurrence of "hypersaline" groundwater: groundwater with salinities largely exceeding that of sea water at 600m depth (Nofal et al., 2015). This hypersaline groundwater greatly influences flow patterns and the fresh water potential of the aquifer. This research focuses on the origins of the hypersaline groundwater and the possible processes causing its transport. We consider all relevant salinization processes in the Nile Delta aquifer, over a time domain of up to 2.5 million years, which is the time span in which the aquifer got deposited. The following hypotheses were investigated with a combination of analytical solutions and numerical modelling: upward salt transport due to a) molecular diffusion, b) thermal buoyancy, c) consolidation-induced advection and dispersion, or downward transport due to d) composition buoyancy (salt inversion). We conclude that hypotheses a) and b) can be rejected, but c) and d) are both possible with the available information. An enhanced chemical analysis is suggested for further research, to determine the origins of this hypersaline water. This information in combination with the conclusions drawn in this research will give more insight in the potential amount of non

  5. Economics of Managed Aquifer Recharge

    Directory of Open Access Journals (Sweden)

    Robert G. Maliva

    2014-05-01

    Full Text Available Managed aquifer recharge (MAR technologies can provide a variety of water resources management benefits by increasing the volume of stored water and improving water quality through natural aquifer treatment processes. Implementation of MAR is often hampered by the absence of a clear economic case for the investment to construct and operate the systems. Economic feasibility can be evaluated using cost benefit analysis (CBA, with the challenge of monetizing benefits. The value of water stored or treated by MAR systems can be evaluated by direct and indirect measures of willingness to pay including market price, alternative cost, value marginal product, damage cost avoided, and contingent value methods. CBAs need to incorporate potential risks and uncertainties, such as failure to meet performance objectives. MAR projects involving high value uses, such as potable supply, tend to be economically feasible provided that local hydrogeologic conditions are favorable. They need to have low construction and operational costs for lesser value uses, such as some irrigation. Such systems should therefore be financed by project beneficiaries, but dichotomies may exist between beneficiaries and payers. Hence, MAR projects in developing countries may be economically viable, but external support is often required because of limited local financial resources.

  6. Identification of palaeo-seawater intrusion in groundwater using minor ions in a semi-confined aquifer of the Río de la Plata littoral (Argentina)

    International Nuclear Information System (INIS)

    Santucci, L.; Carol, E.; Kruse, E.

    2016-01-01

    The hydrochemistry of minor elements and traces such as bromide, lithium, strontium, uranium and selenium, together with the chemical analysis of major ions, has been used in the study of salinization process. This process occurs in a semi-confined aquifer that corresponds to a Pliocene–Pleistocene fluvial environment. The semi-confined aquifer is located in the littoral of the cities of Ensenada and Berisso, in the region of the middle Río de la Plata estuary, Argentina. Groundwater salinization was detected in the semi-confined aquifer in the coastal plain area, with salt contents that increase from the loess plain towards the river. The content of major ions that predominate in sea water (Cl"−, Na"+ and Mg"2"+), as well as the Cl"−/Br"− and U vs. Cl"− ratios, demonstrates that such salinization is related to sea water, which shows no correspondence with estuary water. In the salinized area, Li, Sr and Se enrichments occur, and are used as tracers of the average time that a substance remains in solution in sea water in the aquifer. The study of such minor ions together with the geological evolution of the area made it possible to recognize that the salt water in the semi-confined aquifer corresponds to a palaeo-intrusion of sea water associated with the Pleistocene–Holocene ingressions caused by the climate changes occurring during the Quaternary. - Highlights: • The semi-confined aquifer in a sector of the Río de la Plata estuary is salinized. • Saline content is higher in the aquifer than in the estuary. • Minor elements indicate the occurrence of palaeo-seawater intrusion. • Palaeo-seawater intrusion may be associated with interglacial fluctuations.

  7. Identification of palaeo-seawater intrusion in groundwater using minor ions in a semi-confined aquifer of the Río de la Plata littoral (Argentina)

    Energy Technology Data Exchange (ETDEWEB)

    Santucci, L., E-mail: eleocarol@fcnym.unlp.edu.ar [Centro de Investigaciones Geológicas (CIG), Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) - Universidad Nacional de La Plata - UNLP, Calle 64 y Diag. 113, 1900 La Plata, Buenos Aires (Argentina); Carol, E. [Centro de Investigaciones Geológicas (CIG), Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) - Universidad Nacional de La Plata - UNLP, Calle 64 y Diag. 113, 1900 La Plata, Buenos Aires (Argentina); Kruse, E. [Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Cátedra de Hidrología General de la Facultad de Ciencias Naturales y Museo, Universidad Nacional de La Plata (UNLP), Calle 64 #3, 1900 La Plata, Buenos Aires (Argentina)

    2016-10-01

    The hydrochemistry of minor elements and traces such as bromide, lithium, strontium, uranium and selenium, together with the chemical analysis of major ions, has been used in the study of salinization process. This process occurs in a semi-confined aquifer that corresponds to a Pliocene–Pleistocene fluvial environment. The semi-confined aquifer is located in the littoral of the cities of Ensenada and Berisso, in the region of the middle Río de la Plata estuary, Argentina. Groundwater salinization was detected in the semi-confined aquifer in the coastal plain area, with salt contents that increase from the loess plain towards the river. The content of major ions that predominate in sea water (Cl{sup −}, Na{sup +} and Mg{sup 2+}), as well as the Cl{sup −}/Br{sup −} and U vs. Cl{sup −} ratios, demonstrates that such salinization is related to sea water, which shows no correspondence with estuary water. In the salinized area, Li, Sr and Se enrichments occur, and are used as tracers of the average time that a substance remains in solution in sea water in the aquifer. The study of such minor ions together with the geological evolution of the area made it possible to recognize that the salt water in the semi-confined aquifer corresponds to a palaeo-intrusion of sea water associated with the Pleistocene–Holocene ingressions caused by the climate changes occurring during the Quaternary. - Highlights: • The semi-confined aquifer in a sector of the Río de la Plata estuary is salinized. • Saline content is higher in the aquifer than in the estuary. • Minor elements indicate the occurrence of palaeo-seawater intrusion. • Palaeo-seawater intrusion may be associated with interglacial fluctuations.

  8. Magmatic sulphides in Quaternary Ecuadorian arc magmas

    Science.gov (United States)

    Georgatou, Ariadni; Chiaradia, Massimo; Rezeau, Hervé; Wälle, Markus

    2018-01-01

    New petrographic and geochemical data on magmatic sulphide inclusions (MSIs) are presented and discussed for 15 Quaternary volcanic centers of the Ecuadorian frontal, main and back volcanic arc. MSIs occur mostly in Fe-Ti oxides (magnetite and/or magnetite-ilmenite pair) and to a lesser extent in silicate minerals (amphibole, plagioclase, and pyroxene). MSIs are present in all volcanic centers ranging in composition from basalt to dacite (SiO2 = 50-67 wt.%), indicating that sulphide saturation occurs at various stages of magmatic evolution and independently from the volcano location along the volcanic arc. MSIs also occur in dioritic, gabbroic and hornblenditic magmatic enclaves of the volcanic rocks. MSIs display variable sizes (1-30 μm) and shapes (globular, ellipsoidal, angular, irregular) and occur mostly as polymineralic inclusions composed of Fe-rich and Cu-poor (pyrrhotite) and Cu-rich (mostly chalcopyrite) phases. Aerial sulphide relative abundances range from 0.3 to 7 ppm in volcanic host rocks and from 13 to 24 ppm in magmatic enclaves. Electron microprobe analyses of MSIs indicate maximum metal contents of Cu = 65.7 wt.%, Fe = 65.2 wt.%, Ni = 10.1 wt.% for those hosted in the volcanic rocks and of Cu = 57.7 wt.%, Fe = 60.9 wt.%, Ni = 5.1 wt.%, for those hosted in magmatic enclaves. Relationships of the sulphide chemistry to the host whole rock chemistry show that with magmatic differentiation (e.g., increasing SiO2) the Cu and Ni content of sulphides decrease whereas the Fe and S contents increase. The opposite behavior is observed with the increase of Cu in the whole rock, because the latter is anti-correlated with the SiO2 whole rock content. Laser ablation ICP-MS analyses of MSIs returned maximum values of PGEs and noble metals of Pd = 30 ppm, Rh = 8.1 ppm, Ag = 92.8 ppm and Au = 0.6 ppm and Pd = 43 ppm, Rh = 22.6 ppm, Ag = 89 ppm and Au = 1 ppm for those hosted in volcanic rocks and magmatic enclaves, respectively. These PGE contents display a

  9. Geophysical Characterization of the Quaternary-Cretaceous Contact Using Surface Resistivity Methods in Franklin and Webster Counties, South-Central Nebraska

    Science.gov (United States)

    Teeple, Andrew; Kress, Wade H.; Cannia, James C.; Ball, Lyndsay B.

    2009-01-01

    Formation made accurate interpretation of the resistivity profile sections difficult and less confident because of similar resistivity of this formation and that of the coarser-grained sediment of the Quaternary-age deposits. However, distinct conductive features were identified within the resistivity profile sections that aided in delineating the contact between the resistive Quaternary-age deposits and the resistive Niobrara Formation. Using this information, an interpretive boundary was drawn on the resistivity profile sections to represent the contact between the Quaternary-age alluvial deposits and the Cretaceous-age Niobrara Formation. A digital elevation model (DEM) of the top of the Niobrara Formation was constructed using the altitudes from the interpreted contact lines. This DEM showed that the general trend of top of the Niobrara Formation dips to the southeast. At the north edge of the study site, the Niobrara Formation topographic high trends east-west with an altitude range of 559 meters in the west to 543 meters in the east. Based on the land-surface elevation and the Niobrara Formation DEM, the estimated thickness of the Quaternary-age alluvial deposits throughout the study area was mapped and showed a thinning of the Quaternary-age alluvial deposits to the north, approximately where the topographic high of the Niobrara Formation is located. This topographic high in the Niobrara Formation has the potential to act as a barrier to ground-water flow from the uplands alluvial aquifer to the Republican River alluvial aquifer as shown in the resistivity profile sections. The Quaternary-age alluvial deposits in the uplands and those in the Republican River Valley are not fully represented as disconnected because it is possible that there are ground-water flow paths that were not mapped during this study.

  10. Minimal erosion of Arctic alpine topography during late Quaternary glaciation

    Science.gov (United States)

    Gjermundsen, Endre F.; Briner, Jason P.; Akçar, Naki; Foros, Jørn; Kubik, Peter W.; Salvigsen, Otto; Hormes, Anne

    2015-10-01

    The alpine topography observed in many mountainous regions is thought to have formed during repeated glaciations of the Quaternary period. Before this time, landscapes had much less relief. However, the spatial patterns and rates of Quaternary exhumation at high latitudes--where cold-based glaciers may protect rather than erode landscapes--are not fully quantified. Here we determine the exposure and burial histories of rock samples from eight summits of steep alpine peaks in northwestern Svalbard (79.5° N) using analyses of 10Be and 26Al concentrations. We find that the summits have been preserved for at least the past one million years. The antiquity of Svalbard’s alpine landscape is supported by the preservation of sediments older than one million years along a fjord valley, which suggests that both mountain summits and low-elevation landscapes experienced very low erosion rates over the past million years. Our findings support the establishment of northwestern Svalbard’s alpine topography during the early Quaternary. We suggest that, as the Quaternary ice age progressed, glacial erosion in the Arctic became inefficient and confined to ice streams, and high-relief alpine landscapes were preserved by minimally erosive glacier armour.

  11. Late Quaternary changes in surface productivity and oxygen ...

    Indian Academy of Sciences (India)

    University of Allahabad, Allahabad 211 002, India. ∗ e-mail: ... This process lowers the pH of water which results into increased dissolution of ..... causes a rapid melting of the inland glaciers, an .... Quaternary climate changes; J. Atmos. Sci.

  12. Late Quaternary sea level and environmental changes from relic ...

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    Keywords. Late Quaternary sea level; western margin of India; subsidence; uplift; depositional environment. ...... sea level rise by about 80m (between 12,000 and. 7,000 yr BP) or, .... from the Florida Keys; Palaentology 28 189–206. Carballo ...

  13. Integrating Quaternary science research in land management, restoration, and conservation

    Science.gov (United States)

    C.I. Millar; W.B. Woolfenden

    2001-01-01

    Most of us have come to expect that the general public will ignore the primary message of Quaternary science that change happens. A flurry, however, of recent media attention to 20th-century global warming and its anomalies from climates of the last millennium has brought climate science at least momentarily into popular focus. Similarly, public land-managing agencies...

  14. Quaternary climate changes explain diversity among reptiles and amphibians

    DEFF Research Database (Denmark)

    Bastos Araujo, Miguel; Nogués-Bravo, David; Diniz-Filho, Alexandre F.

    2008-01-01

    debated without reaching consensus. Here, we test the proposition that European species richness of reptiles and amphibians is driven by climate changes in the Quaternary. We find that climate stability between the Last Glacial Maximum (LGM) and the present day is a better predictor of species richness...

  15. Electron paramagnetic resonance: A new method of quaternary dating

    International Nuclear Information System (INIS)

    Poupeau, G.; Rossi, A.; Teles, M.M.; Danon, J.

    1984-01-01

    Significant progress has occurred in the last years in quaternary geochronology. One of this is the emergence of a new dating approach, the Electron Spin Resonance Method. The aim of this paper is to briefly review the method and discuss some aspects of the work at CBPF. (Author) [pt

  16. Electron paramagnetic resonance: a new method of quaternary dating

    International Nuclear Information System (INIS)

    Poupeau, G.; Rossi, A.; Universidade Federal Rural do Rio de Janeiro; Telles, M.; Danon, J.

    1984-01-01

    Significant progress has occurred in the last years in quaternary geochronology. One of this is the emergence of a new dating approach, the Electron Spin Resonance Method. The aim of this paper is to briefly review the method and discuss some aspects of the work at CBPF. (Author) [pt

  17. Fault control on patterns of Quaternary monogenetic vents in the ...

    African Journals Online (AJOL)

    Field and remote sensing data are used to examine the distribution of volcanism and fault geometry in the Ethiopian Rift between Omo-Chew Bahir rift and Tendaho graben during the Quaternary and evaluate their influence on the location and shape of individual vents as well as the development of alignments. The results ...

  18. A revision of the Pliocene and Quaternary Lutrinae from Europe

    NARCIS (Netherlands)

    Willemsen, G.F.

    1992-01-01

    In this paper, a revision of the Pliocene and Quaternary Lutrinae from Europe is presented. Such a revision, including fossil material, has not been published since the work of Pohle (1919). Three tribes within the Lutrinae are recognized: the Lutrini, the Aonyxini and the Enhydrini. The latter

  19. Hydrology of the Claiborne aquifer and interconnection with the Upper Floridan aquifer in southwest Georgia

    Science.gov (United States)

    Gordon, Debbie W.; Gonthier, Gerard

    2017-04-24

    The U.S. Geological Survey conducted a study, in cooperation with the Georgia Environmental Protection Division, to define the hydrologic properties of the Claiborne aquifer and evaluate its connection with the Upper Floridan aquifer in southwest Georgia. The effort involved collecting and compiling hydrologic data from the aquifer in subarea 4 of southwestern Georgia. Data collected for this study include borehole geophysical logs in 7 wells, and two 72-hour aquifer tests to determine aquifer properties.The top of the Claiborne aquifer extends from an altitude of about 200 feet above the North American Vertical Datum of 1988 (NAVD 88) in Terrell County to 402 feet below NAVD 88 in Decatur County, Georgia. The base of the aquifer extends from an altitude of about 60 feet above NAVD 88 in eastern Sumter County to about 750 feet below NAVD 88 in Decatur County. Aquifer thickness ranges from about 70 feet in eastern Early County to 400 feet in Decatur County.The transmissivity of the Claiborne aquifer, determined from two 72-hour aquifer tests, was estimated to be 1,500 and 700 feet squared per day in Mitchell and Early Counties, respectively. The storage coefficient was estimated to be 0.0006 and 0.0004 for the same sites, respectively. Aquifer test data from Mitchell County indicate a small amount of leakage occurred during the test. Groundwater-flow models suggest that the source of the leakage was the underlying Clayton aquifer, which produced about 2.5 feet of drawdown in response to pumping in the Claiborne aquifer. The vertical hydraulic conductivity of the confining unit between the Claiborne and Clayton aquifers was simulated to be about 0.02 foot per day.Results from the 72-hour aquifer tests run for this study indicated no interconnection between the Claiborne and overlying Upper Floridan aquifers at the two test sites. Additional data are needed to monitor the effects that increased withdrawals from the Claiborne aquifer may have on future water resources.

  20. Development and Modelling of a High-Resolution Aquifer Analog in the Guarani Aquifer (Brazil)

    OpenAIRE

    Höyng, Dominik

    2014-01-01

    A comprehensive and detailed knowledge about the spatial distribution of physical and chemical properties in heterogeneous porous aquifers plays a decisive role for a realistic representation of governing parameters in mathematical models. Models allow the simulation, prediction and reproduction of subsurface flow and transport characteristics. This work explains the identification, characterization and effects of small-scale aquifer heterogeneities in the Guarani Aquifer System (GAS) in S...

  1. Quaternary fault in Hwalseong-ri, Oedong-up, Gyeongju, Korea.

    Energy Technology Data Exchange (ETDEWEB)

    Ryoo, Chung-Ryul; Chwae, Uee-Chan; Choi, Sung-Ja [Korea Institute of Geoscience and Mineral Resources, Taejeon(Korea); Son, Moon [Pusan National University, Pusan(Korea)

    2001-09-01

    We describe a Quaternary fault occurring in Hwalseong-ri, Oedong-up, Gyeongju in the eastern part of Ulsan Fault Zone, Korea. This fault (Hwalseongri Fault) is developed around the contact between the early Tertiary granite and the Quaternary gravel layer. Four different faults are distinguished from west to east: (1) fault within Quaternary gravel layer, (2) fault between Quaternary gravel layer and granite, (3) fault between Quaternary gravel layer overlying granite and granite, (4) fault between granite and Quaternary layer. General strike of the fault zone vary from NNW to NE, dipping to east. Two striations, E-W and N-S, are developed. The former is related mainly to the reverse faulting, and the latter to the sinistral shearing. This fault zone was reactivated, and considered as a positive flower structure mainly by the results of the E-W compression in the southeastern part of the Korean Peninsula during Quaternary. (author). 45 refs., 6 figs.

  2. Characterization of Quaternary and suspected Quaternary faults, regional studies, Nevada and California

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, R.E.; Bucknam, R.C.; Crone, A.J.; Haller, K.M.; Machette, M.N.; Personius, S.F.; Barnhard, T.P.; Cecil, M.J.; Dart, R.L.

    1995-12-31

    This report presents the results of geologic studies that help define the Quaternary history of selected faults in the region around Yucca Mountain, Nevada. These results are relevant to the seismic-design basis of a potential nuclear waste repository at Yucca Mountain. The relevancy is based, in part, on a need for additional geologic data that became apparent in ongoing studies that resulted in the identification of 51 relevant and potentially relevant individual and compound faults and fault zones in the 100-km-radius region around the Yucca Mountain site. Geologic data used to characterize the regional faults and fault zones as relevant or potentially relevant seismic sources includes age and displacement information, maximum fault lengths, and minimum distances between the fault and the Yucca Mountain site. For many of the regional faults, no paleoseismic field studies have previously been conducted, and age and displacement data are sparse to nonexistent. In November 1994, the Branch of Earthquake and Landslide Hazards entered into two Memoranda of Agreement with the Yucca Mountain Project Branch to conduct field reconnaissance, analysis, and interpretation of six relevant and six potentially relevant regional faults. This report describes the results of study of those faults exclusive of those in the Pahrump-Stewart Valley-Ash Meadows-Amargosa Valley areas. We also include results of a cursory study of faults on the west flank of the Specter Range and in the northern part of the Last Chance Range. A four-phase strategy was implemented for the field study.

  3. Comparison of aquifer characteristics derived from local and regional aquifer tests.

    Science.gov (United States)

    Randolph, R.B.; Krause, R.E.; Maslia, M.L.

    1985-01-01

    A comparison of the aquifer parameter values obtained through the analysis of a local and a regional aquifer test involving the same area in southeast Georgia is made in order to evaluate the validity of extrapolating local aquifer-test results for use in large-scale flow simulations. Time-drawdown and time-recovery data were analyzed by using both graphical and least-squares fitting of the data to the Theis curve. Additionally, directional transmissivity, transmissivity tensor, and angle of anisotropy were computed for both tests. -from Authors Georgia drawdown transmissivity regional aquifer tests

  4. Calcium isotope fractionation in a silicate dominated Cenozoic aquifer system

    Science.gov (United States)

    Li, Junxia; DePaolo, Donald J.; Wang, Yanxin; Xie, Xianjun

    2018-04-01

    To understand the characteristics of Ca isotope composition and fractionation in silicate-dominated Quaternary aquifer system, hydrochemical and isotope studies (87Sr/86Sr, 13CDIC and 44/40Ca) were conducted on groundwater, sediment and rock samples from the Datong basin, China. Along the groundwater flow path from the basin margin to the center, groundwater hydrochemical type evolves from Ca-HCO3 to Na-HCO3/Na-Cl type, which results from aluminosilicate hydrolysis, vertical mixing, cation exchange between CaX2 and NaX, and calcite/dolomite precipitation. These processes cause the decrease in groundwater Ca concentration and the associated modest fractionation of groundwater Ca isotopes along the flowpath. The groundwater δ44/40Ca value varies from -0.11 to 0.49‰. The elevated δ44/40Ca ratios in shallow groundwater are attributed to vertical mixing involving addition of irrigation water, which had the average δ44/40Ca ratio of 0.595‰. Chemical weathering of silicate minerals and carbonate generates depleted δ44/40Ca signatures in groundwater from Heng Mountain (east area) and Huanghua Uplift (west area), respectively. Along the groundwater flow path from Heng Mountain to central area of east area, cation exchange between CaX2 and NaX on clay mineral results in the enrichment of heavier Ca isotope in groundwater. All groundwater samples are oversaturated with respect to calcite and dolomite. The groundwater environment rich in organic matter promotes the precipitation of carbonate minerals via the biodegradation of organic carbon, thereby further promoting the elevation of groundwater δ44/40Ca ratios.

  5. Steam Injection For Soil And Aquifer Remediation

    Science.gov (United States)

    The purpose of this Issue Paper is to provide to those involved in assessing remediation technologies for specific sites basic technical information on the use of steam injection for the remediation of soils and aquifers that are contaminated by...

  6. Hydrogeologic characterization of devonian aquifers in Uruguay

    International Nuclear Information System (INIS)

    Massa, E.

    1988-01-01

    This article carried out the assistance research project implementation in devonian sedimentary units as a potentials aquifers and their best use to school supplying and rural population in central area of Uruguay.

  7. Aquifer parameter identification and interpretation with different ...

    African Journals Online (AJOL)

    unfortunately, field data deviations from the model type curves are not considered in ... Such an extensive Study can only he done when there is a set of aquifer test data with main and .... 1990; 1995) methods are employed for qualitative.

  8. Environmental isotope study related to groundwater age, flow system and saline water origin in Quaternary aquifers of North China Plain

    International Nuclear Information System (INIS)

    Zhang Zhigan; Payne, B.R.

    1988-01-01

    An isotopic hydrology section across the North China Plain has been studied to investigate problems of groundwater age, flow system and saline water origin in a semi-arid pre-mountain artesian basin. Two local and one regional flow system along the section have been recognized. Turnover time of water for alluvial fan, shallow and regional systems are estimated to be the order of 10 2 , 10 3 , and 10 4 years respectively. Specific flow rates for the three systems have been calculated. Only less than 5 percent of flow from alluvial fan is drained by the regional flow system and the rest, in natural conditions, discharges at surface in the front edge of an alluvial fan and forms a groundwater discharge belt at a good distance away from the mountain foot. Developed in the alluvial plain and coastal plain areas the shallow flow system embraces a series of small local systems. Groundwater in these systems appears to be the salt carrier during continental salinization. It washes salt out of the recharge area and deep-occurred strata by circulating and carries it up to the surface in lowland areas. Consequently, in parallel with salinization at surface a desalinization process occurs at depth, which provides an additional explanation for the existing thick deep fresh water zone in most arid and semi-arid regions, where continental salting process is in progress. (author). 6 refs, 8 figs, 4 tabs

  9. Effects of climate variability on saltwater intrusions in coastal aquifers in Southern Denmark

    Science.gov (United States)

    Meyer, Rena; Sonnenborg, Torben; Engesgaard, Peter; Høyer, Anne-Sophie; Jørgensen, Flemming; Hisnby, Klaus; Hansen, Birgitte; Jensen, Jørn Bo; Piotrowski, Jan A.

    2016-04-01

    As in many other regions of the world fresh water supply in Denmark is based on groundwater resources. Aquifers in the low-lying areas in the south-west of Jutland are particularly vulnerable to saltwater intrusions which are likely to intensify due to relative sea level rise. To understand the dynamics and development of this complex flow system, the initial hydrodynamic conditions imposed by the last Scandinavian Ice Sheet (SIS) must be taken into account. The whole region has undergone changes in climatic and hydraulic conditions within the last 15000 years that may show influence on the present flow conditions. It is likely that the groundwater-flow dynamics, driven by the postglacial hydraulic head drop and the relative sea level rise are not yet equilibrated. Enhanced by the potential future sea level rise due to climate change, contamination of fresh-water aquifers will continue. The 2800-km2 - large coast-to-coast study area located in the southern part of Jutland was partly overridden by the Weichselian ice sheet. Geophysical and geological mapping shows salt water intrusions up to 20 km inland from the present coast. Based on a geological voxel model spanning Miocene through Quaternary deposits a large-scale 3D numerical groundwater flow and salt water transport model has been developed. It includes density-driven flow and simulates the distribution of the current saltwater intrusions and their evolution during the last 15000 years. Particle tracking and direct age simulations are performed to identify recharge areas and constrain groundwater ages. The simulated ages are compared to ages derived from isotope analysis of groundwater samples both from Miocene and Quaternary aquifers. The origin of the groundwater is determined based on isotopic and chemical composition. Additionally, heavy noble gas analysis is carried out to estimate recharge temperatures and mechanisms at locations where groundwater recharge during the last glaciation is indicated. This

  10. A General Solution for Groundwater Flow in Estuarine Leaky Aquifer System with Considering Aquifer Anisotropy

    Science.gov (United States)

    Chen, Po-Chia; Chuang, Mo-Hsiung; Tan, Yih-Chi

    2014-05-01

    In recent years the urban and industrial developments near the coastal area are rapid and therefore the associated population grows dramatically. More and more water demand for human activities, agriculture irrigation, and aquaculture relies on heavy pumping in coastal area. The decline of groundwater table may result in the problems of seawater intrusion and/or land subsidence. Since the 1950s, numerous studies focused on the effect of tidal fluctuation on the groundwater flow in the coastal area. Many studies concentrated on the developments of one-dimensional (1D) and two-dimensional (2D) analytical solutions describing the tide-induced head fluctuations. For example, Jacob (1950) derived an analytical solution of 1D groundwater flow in a confined aquifer with a boundary condition subject to sinusoidal oscillation. Jiao and Tang (1999) derived a 1D analytical solution of a leaky confined aquifer by considered a constant groundwater head in the overlying unconfined aquifer. Jeng et al. (2002) studied the tidal propagation in a coupled unconfined and confined costal aquifer system. Sun (1997) presented a 2D solution for groundwater response to tidal loading in an estuary. Tang and Jiao (2001) derived a 2D analytical solution in a leaky confined aquifer system near open tidal water. This study aims at developing a general analytical solution describing the head fluctuations in a 2D estuarine aquifer system consisted of an unconfined aquifer, a confined aquifer, and an aquitard between them. Both the confined and unconfined aquifers are considered to be anisotropic. The predicted head fluctuations from this solution will compare with the simulation results from the MODFLOW program. In addition, the solutions mentioned above will be shown to be special cases of the present solution. Some hypothetical cases regarding the head fluctuation in costal aquifers will be made to investigate the dynamic effects of water table fluctuation, hydrogeological conditions, and

  11. New quantum codes constructed from quaternary BCH codes

    Science.gov (United States)

    Xu, Gen; Li, Ruihu; Guo, Luobin; Ma, Yuena

    2016-10-01

    In this paper, we firstly study construction of new quantum error-correcting codes (QECCs) from three classes of quaternary imprimitive BCH codes. As a result, the improved maximal designed distance of these narrow-sense imprimitive Hermitian dual-containing quaternary BCH codes are determined to be much larger than the result given according to Aly et al. (IEEE Trans Inf Theory 53:1183-1188, 2007) for each different code length. Thus, families of new QECCs are newly obtained, and the constructed QECCs have larger distance than those in the previous literature. Secondly, we apply a combinatorial construction to the imprimitive BCH codes with their corresponding primitive counterpart and construct many new linear quantum codes with good parameters, some of which have parameters exceeding the finite Gilbert-Varshamov bound for linear quantum codes.

  12. Community ecology in a changing environment: Perspectives from the Quaternary.

    Science.gov (United States)

    Jackson, Stephen T; Blois, Jessica L

    2015-04-21

    Community ecology and paleoecology are both concerned with the composition and structure of biotic assemblages but are largely disconnected. Community ecology focuses on existing species assemblages and recently has begun to integrate history (phylogeny and continental or intercontinental dispersal) to constrain community processes. This division has left a "missing middle": Ecological and environmental processes occurring on timescales from decades to millennia are not yet fully incorporated into community ecology. Quaternary paleoecology has a wealth of data documenting ecological dynamics at these timescales, and both fields can benefit from greater interaction and articulation. We discuss ecological insights revealed by Quaternary terrestrial records, suggest foundations for bridging between the disciplines, and identify topics where the disciplines can engage to mutual benefit.

  13. Study on Quaternary ground siting of nuclear power plant, (1)

    International Nuclear Information System (INIS)

    Kokusho, Takaji; Nishi, Koichi; Honsho, Shizumitsu

    1991-01-01

    A seismic stability evaluation method for a nuclear power plant to be located on a Quaternary sandy/gravelly ground is discussed herein in terms of the geological and geotechnical survey, design earthquake motion evaluation and geotechnical seismic stability analyses. The geological and geotechnical exploration tunnel in the rock-foundation siting will be difficult in the Quaternary ground siting. Boring, geophysical surveys and soil samplings will play a major role in this case. The design earthquake input spectrum for this siting is proposed so as to take account the significant effect of longer period motion on the ground stability. Equivalent and non-linear analyses demonstrate the seismic stability of the foundation ground so long as the soil density is high. (author)

  14. Quaternary ground siting technology of nuclear power plants

    International Nuclear Information System (INIS)

    Nishi, K.; Kokusho, T.; Iwatate, Y.; Ishida, K.; Honsho, S.; Okamoto, T.; Tohma, J.; Tanaka, Y.; Kanatani, M.

    1992-01-01

    A seismic stability evaluation method for a nuclear power plant to be located on Quaternary sandy/gravelly ground is discussed herein in terms of a geological and geotechnical survey, a design earthquake motion evaluation and geotechnical seismic stability analyses. The geological and geotechnical exploration tunnel in the rock foundation siting will be difficult in the Quaternary ground siting. Boring, geophysical surveys and soil sampling will play a major role in this case. A design earthquake input spectrum for this siting is proposed to take in account the significant effect of longer period motion on ground stability. Equivalent and non-linear analyses demonstrate the seismic stability of the foundation ground so long as the soil density is high. (author)

  15. Guarani aquifer hydrogeological synthesis of the Guarani aquifer system. Edicion bilingue

    International Nuclear Information System (INIS)

    2009-01-01

    This work represents the synthesis of current knowledge of the Guarani Aquifer System, based on technical products made by different companies and consultants who participated in the framework of the Project for Environmental Protection and Sustainable Development of the Guarani Aquifer.

  16. Seismic stability analyses of various reactor buildings on quaternary deposit

    International Nuclear Information System (INIS)

    Takeuchi, Y.; Tsutagawa, M.; Asakura, S.; Katoh, T.; Tomura, H.; Uchiyama, S.; Koyama, M.; Oguro, E.; Akino, K.; Iizuka, S.; Hayashi, M.

    1993-01-01

    Many nuclear power plants have been built on Quaternary deposits in Europe and U.S.A., however, Japanese basic policy is to construct the reactor building and other auxiliary buildings on a bed rock which are important to safety, because large earthquakes are postulated to occur. Being limited bed rock sites in Japan, it has become necessary to increase possible place for nuclear power plant in order to cope with the middle and long term siting problems. For the purpose of establishing the draft of guideline on seismic design of reactor building on the Quaternary sand and gravel deposit in Japan, foundation soil stability and seismic resistance of the reactor building and plant equipment have been investigated and studied from 1983 to 1998. The studies have shown the following: 1) The response rotation angles of both common light weight basement (CL) and step basement (ES) plants during the earthquake reduce to 1/2 of the BR plant value, and the bearing pressure between the basement and the soil of improved plant are reduced as well; (2) every structure built on quaternary sand and gravel deposit, having 400m/s shear velocity, maintains enough seismic resistance, because the shear stress caused in the wall is small. The maximum shear strain of soil below the basemat of BR-BWR, which suffers the largest bearing pressure, is 1.1x10 -9 , but it can be said that the soil has enough stability according to the past soil tests for the Quaternary sand and gravel deposit that had been done by authors

  17. Late Quaternary extinctions: The promise of TAMS 14C dating

    International Nuclear Information System (INIS)

    Martin, P.S.

    1987-01-01

    In the last 30 000 years late Quaternary extinctions eliminated over two-thirds of the large land mammals of America and Australia and most of the endemic land vertebrates on oceanic islands. Specimens of extinct animals yielding too little organic material for measurement in decay counters are suitable for TAMS dating. Initial results support older evidence of an extinction chronology that was catastrophic regionally, transgressive globally, and linked to the spread of prehistoric people. (orig.)

  18. Significant differences in late Quaternary bedrock erosion and transport

    DEFF Research Database (Denmark)

    Andrews, John; Bjørk, Anders Anker; Eberl, Dennis

    2015-01-01

    in 10 cores from the two margins. On the East Greenland Shelf (EGS), late Quaternary samples have an average quartz weight per cent of 6.22.3 versus 12.83.9 from the West Greenland Shelf (WGS), and 12.024.8 versus 1.9 2.3wt% for pyroxene. K-means clustering indicated only 9% of the samples did not fit...

  19. Development of antibacterial quaternary ammonium silane coatings on polyurethane catheters

    Czech Academy of Sciences Publication Activity Database

    Zanini, S.; Polissi, A.; Maccagni, E.A.; Dell'Orto, E.C.; Liberatore, Chiara; Riccardi, C.

    2015-01-01

    Roč. 451, Aug (2015), 78-84 ISSN 0021-9797 R&D Projects: GA MŠk EE2.3.20.0143 Grant - others:OP VK 6(XE) CZ.1.07/2.3.00/20.0143 Institutional support: RVO:68378271 Keywords : plasma-induced graft-polymerization * acrylic acid * ATR/FTIR * AFM * quaternary ammonium silane * Escherichia coli Subject RIV: BH - Optics, Masers, Lasers Impact factor: 3.782, year: 2015

  20. A revision of the Pliocene and Quaternary Lutrinae from Europe

    OpenAIRE

    Willemsen, G.F.

    1992-01-01

    In this paper, a revision of the Pliocene and Quaternary Lutrinae from Europe is presented. Such a revision, including fossil material, has not been published since the work of Pohle (1919). Three tribes within the Lutrinae are recognized: the Lutrini, the Aonyxini and the Enhydrini. The latter comprises both Enhydra and the Enhydriodon group. The genus Nesolutra, consisting of three insular species, is not retained. Two are included in Lutra and for N. ichnusae a new genus, Sardolutra, is pr...

  1. Aquifer response to earth tides

    International Nuclear Information System (INIS)

    Kanehiro, B.Y.; Narasimhan, T.N.

    1981-01-01

    The relation presented in the first part of this paper are applicable to packed-off wells and other situations where appreciable flow to the well does not exist. Comparisons of aquifer properties determined from the response to earth tides and from the more standard pumping tests for the two California fields are reasonably good. The case of an open well makes the problem more complicated, since there may be an appreciable amount of flow to the well. This flow to the well is seen as either a phase lag or as a difference in the ratio of the well signal to the tide for the semidiurnal and diurnal components of the tide. The latter is probably the better and more accurate indicator of flow to the well. Analyses of such situations, however, become involved and are probably best done as case-by-case studies. The numerical solutions show that treating the inverse problem through numerical modeling is at least feasible for any individual situation. It may be possible to simplify the inverse problem through the generation of type curves, but general type curves that are applicable to diverse situations are not likely to be practical. 7 figures

  2. Aquifer Storage Recovery (ASR) of chlorinated municipal drinking water in a confined aquifer

    Science.gov (United States)

    Izbicki, John A.; Petersen, Christen E.; Glotzbach, Kenneth J.; Metzger, Loren F.; Christensen, Allen H.; Smith, Gregory A.; O'Leary, David R.; Fram, Miranda S.; Joseph, Trevor; Shannon, Heather

    2010-01-01

    About 1.02 x 106 m3 of chlorinated municipal drinking water was injected into a confined aquifer, 94-137 m below Roseville, California, between December 2005 and April 2006. The water was stored in the aquifer for 438 days, and 2.64 x 106 m3 of water were extracted between July 2007 and February 2008. On the basis of Cl data, 35% of the injected water was recovered and 65% of the injected water and associated disinfection by-products (DBPs) remained in the aquifer at the end of extraction. About 46.3 kg of total trihalomethanes (TTHM) entered the aquifer with the injected water and 37.6 kg of TTHM were extracted. As much as 44 kg of TTHMs remained in the aquifer at the end of extraction because of incomplete recovery of injected water and formation of THMs within the aquifer by reactions with freechlorine in the injected water. Well-bore velocity log data collected from the Aquifer Storage Recovery (ASR) well show as much as 60% of the injected water entered the aquifer through a 9 m thick, high-permeability layer within the confined aquifer near the top of the screened interval. Model simulations of ground-water flow near the ASR well indicate that (1) aquifer heterogeneity allowed injected water to move rapidly through the aquifer to nearby monitoring wells, (2) aquifer heterogeneity caused injected water to move further than expected assuming uniform aquifer properties, and (3) physical clogging of high-permeability layers is the probable cause for the observed change in the distribution of borehole flow. Aquifer heterogeneity also enhanced mixing of native anoxic ground water with oxic injected water, promoting removal of THMs primarily through sorption. A 3 to 4-fold reduction in TTHM concentrations was observed in the furthest monitoring well 427 m downgradient from the ASR well, and similar magnitude reductions were observed in depth-dependent water samples collected from the upper part of the screened interval in the ASR well near the end of the extraction

  3. Review of Aquifer Storage and Recovery Performance in the Upper Floridan Aquifer in Southern Florida

    Science.gov (United States)

    Reese, Ronald S.

    2006-01-01

    Introduction: Interest and activity in aquifer storage and recovery (ASR) in southern Florida has increased greatly during the past 10 to 15 years. ASR wells have been drilled to the carbonate Floridan aquifer system at 30 sites in southern Florida, mostly by local municipalities or counties located in coastal areas. The primary storage zone at these sites is contained within the brackish to saline Upper Floridan aquifer of the Floridan aquifer system. The strategy for use of ASR in southern Florida is to store excess freshwater available during the wet season in an aquifer and recover it during the dry season when needed for supplemental water supply. Each ASR cycle is defined by three periods: recharge, storage, and recovery. This fact sheet summarizes some of the findings of a second phase retrospective assessment of existing ASR facilities and sites.

  4. Ecological impacts of the late Quaternary megaherbivore extinctions.

    Science.gov (United States)

    Gill, Jacquelyn L

    2014-03-01

    As a result of the late Quaternary megafaunal extinctions (50,000-10,000 before present (BP)), most continents today are depauperate of megaherbivores. These extinctions were time-transgressive, size- and taxonomically selective, and were caused by climate change, human hunting, or both. The surviving megaherbivores often act as ecological keystones, which was likely true in the past. In spite of this and extensive research on the causes of the Late Quaternary Extinctions, the long-term ecological consequences of the loss of the Pleistocene megafauna remained unknown until recently, due to difficulties in linking changes in flora and fauna in paleorecords. The quantification of Sporormiella and other dung fungi have recently allowed for explicit tests of the ecological consequences of megafaunal extirpations in the fossil pollen record. In this paper, I review the impacts of the loss of keystone megaherbivores on vegetation in several paleorecords. A growing number of studies support the hypothesis that the loss of the Pleistocene megafauna resulted in cascading effects on plant community composition, vegetation structure and ecosystem function, including increased fire activity, novel communities and shifts in biomes. Holocene biota thus exist outside the broader evolutionary context of the Cenozoic, and the Late Quaternary Extinctions represent a regime shift for surviving plant and animal species.

  5. Hydrological connectivity of perched aquifers and regional aquifers in semi-arid environments: a case study from Namibia

    Science.gov (United States)

    Hamutoko, J. T.; Wanke, H.

    2017-12-01

    Integrated isotopic and hydrological tracers along with standard hydrological data are used to understand complex dry land hydrological processes on different spatial and temporal scales. The objective of this study is to analyse the relationship between the perched aquifers and the regional aquifer using hydrochemical data and isotopic composition in the Cuvelai-Etosha Basin in Namibia. This relation between the aquifers will aid in understanding groundwater recharge processes and flow dynamics. Perched aquifers are discontinuous shallow aquifers with water level ranging from 0 to 30 meters below ground level. The regional aquifer occurs in semi-consolidated sandstone at depths between about 60 and 160 meters below ground level. Water samples were collected from both aquifers in 10 villages and were analysed for major ions and stable isotopes. The results show overlapping hydrochemistry and isotopic compositions of both aquifers in 8 villages which suggest the possibility of perched aquifer water infiltrating into the regional aquifer. In two villages the hydrochemistry and isotopic composition of the aquifers are totally different and this suggests that there is no interaction between this aquifers. Areas where perched aquifers are connected to regional aquifers maybe recharge zones. These finding have important implications for groundwater resource management.

  6. Transient well flow in vertically heterogeneous aquifers

    Science.gov (United States)

    Hemker, C. J.

    1999-11-01

    A solution for the general problem of computing well flow in vertically heterogeneous aquifers is found by an integration of both analytical and numerical techniques. The radial component of flow is treated analytically; the drawdown is a continuous function of the distance to the well. The finite-difference technique is used for the vertical flow component only. The aquifer is discretized in the vertical dimension and the heterogeneous aquifer is considered to be a layered (stratified) formation with a finite number of homogeneous sublayers, where each sublayer may have different properties. The transient part of the differential equation is solved with Stehfest's algorithm, a numerical inversion technique of the Laplace transform. The well is of constant discharge and penetrates one or more of the sublayers. The effect of wellbore storage on early drawdown data is taken into account. In this way drawdowns are found for a finite number of sublayers as a continuous function of radial distance to the well and of time since the pumping started. The model is verified by comparing results with published analytical and numerical solutions for well flow in homogeneous and heterogeneous, confined and unconfined aquifers. Instantaneous and delayed drainage of water from above the water table are considered, combined with the effects of partially penetrating and finite-diameter wells. The model is applied to demonstrate that the transient effects of wellbore storage in unconfined aquifers are less pronounced than previous numerical experiments suggest. Other applications of the presented solution technique are given for partially penetrating wells in heterogeneous formations, including a demonstration of the effect of decreasing specific storage values with depth in an otherwise homogeneous aquifer. The presented solution can be a powerful tool for the analysis of drawdown from pumping tests, because hydraulic properties of layered heterogeneous aquifer systems with

  7. A Black Hills-Madison Aquifer origin for Dakota Aquifer groundwater in northeastern Nebraska.

    Science.gov (United States)

    Stotler, Randy; Harvey, F Edwin; Gosselin, David C

    2010-01-01

    Previous studies of the Dakota Aquifer in South Dakota attributed elevated groundwater sulfate concentrations to Madison Aquifer recharge in the Black Hills with subsequent chemical evolution prior to upward migration into the Dakota Aquifer. This study examines the plausibility of a Madison Aquifer origin for groundwater in northeastern Nebraska. Dakota Aquifer water samples were collected for major ion chemistry and isotopic analysis ((18)O, (2)H, (3)H, (14)C, (13)C, (34)S, (18)O-SO(4), (87)Sr, (37)Cl). Results show that groundwater beneath the eastern, unconfined portion of the study area is distinctly different from groundwater sampled beneath the western, confined portion. In the east, groundwater is calcium-bicarbonate type, with delta(18)O values (-9.6 per thousand to -12.4 per thousand) similar to local, modern precipitation (-7.4 per thousand to -10 per thousand), and tritium values reflecting modern recharge. In the west, groundwater is calcium-sulfate type, having depleted delta(18)O values (-16 per thousand to -18 per thousand) relative to local, modern precipitation, and (14)C ages 32,000 to more than 47,000 years before present. Sulfate, delta(18)O, delta(2)H, delta(34)S, and delta(18)O-SO(4) concentrations are similar to those found in Madison Aquifer groundwater in South Dakota. Thus, it is proposed that Madison Aquifer source water is also present within the Dakota Aquifer beneath northeastern Nebraska. A simple Darcy equation estimate of groundwater velocities and travel times using reported physical parameters from the Madison and Dakota Aquifers suggests such a migration is plausible. However, discrepancies between (14)C and Darcy age estimates indicate that (14)C ages may not accurately reflect aquifer residence time, due to mixtures of varying aged water.

  8. Using hydrochemical data and modelling to enhance the knowledge of groundwater flow and quality in an alluvial aquifer of Zagreb, Croatia

    Energy Technology Data Exchange (ETDEWEB)

    Marković, Tamara, E-mail: tmarkovic@hgi-cgs.hr; Brkić, Željka; Larva, Ozren

    2013-08-01

    The Zagreb alluvial aquifer system is located in the southwest of the Pannonian Basin in the Sava Valley in Croatia. It is composed of Quaternary unconsolidated deposits and is highly utilised, primarily as a water supply for the more than one million inhabitants of the capital city of Croatia. To determine the origin and dynamics of the groundwater and to enhance the knowledge of groundwater flow and the interactions between the groundwater and surface water, extensive hydrogeological and hydrochemical investigations have been completed. The groundwater levels monitored in nested observation wells and the lithological profile indicate that the aquifer is a single hydrogeologic unit, but the geochemical characteristics of the aquifer indicate stratification. The weathering of carbonate and silicate minerals has an important role in groundwater chemistry, especially in the area where old meanders of the Sava River existed. Groundwater quality was observed to be better in the deeper parts of the aquifer than in the shallower parts. Furthermore, deterioration of the groundwater quality was observed in the area under the influence of the landfill. The stable isotopic composition of all sampled waters indicates meteoric origin. NETPATH-WIN was used to calculate the mixing proportions between initial waters (water from the Sava River and groundwater from “regional” flow) in the final water (groundwater sampled from observation wells). According to the results, the mixing proportions of “regional” flow and the river water depend on hydrological conditions, the duration of certain hydrological conditions and the vicinity of the Sava River. Moreover, although the aquifer system behaves as a single hydrogeologic unit from a hydraulic point of view, it still clearly demonstrates geochemical stratification, which could be a decisive factor in future utilisation strategies for the aquifer system. - Highlights: • The Zagreb aquifer is the largest utilised source of

  9. Bactericidal Specificity and Resistance Profile of Poly(Quaternary Ammonium) Polymers and Protein-Poly(Quaternary Ammonium) Conjugates.

    Science.gov (United States)

    Ji, Weihang; Koepsel, Richard R; Murata, Hironobu; Zadan, Sawyer; Campbell, Alan S; Russell, Alan J

    2017-08-14

    Antibacterial polymers are potentially powerful biocides that can destroy bacteria on contact. Debate in the literature has surrounded the mechanism of action of polymeric biocides and the propensity for bacteria to develop resistance to them. There has been particular interest in whether surfaces with covalently coupled polymeric biocides have the same mechanism of action and resistance profile as similar soluble polymeric biocides. We designed and synthesized a series of poly(quaternary ammonium) polymers, with tailorable molecular structures and architectures, to engineer their antibacterial specificity and their ability to delay the development of bacterial resistance. These linear poly(quaternary ammonium) homopolymers and block copolymers, generated using atom transfer radical polymerization, had structure-dependent antibacterial specificity toward Gram positive and negative bacterial species. When single block copolymers contained two polymer segments of differing antibacterial specificity, the polymer combined the specificities of its two components. Nanoparticulate human serum albumin-poly(quaternary ammonium) conjugates of these same polymers, synthesized via "grafting from" atom transfer radical polymerization, were strongly biocidal and also exhibited a marked decrease in the rate of bacterial resistance development relative to linear polymers. These protein-biocide conjugates mimicked the behavior of surface-presented polycationic biocides rather than their nonproteinaceous counterparts.

  10. Groundwater vulnerability mapping of Qatar aquifers

    Science.gov (United States)

    Baalousha, Husam Musa

    2016-12-01

    Qatar is one of the most arid countries in the world with limited water resources. With little rainfall and no surface water, groundwater is the only natural source of fresh water in the country. Whilst the country relies mainly on desalination of seawater to secure water supply, groundwater has extensively been used for irrigation over the last three decades, which caused adverse environmental impact. Vulnerability assessment is a widely used tool for groundwater protection and land-use management. Aquifers in Qatar are carbonate with lots of fractures, depressions and cavities. Karst aquifers are generally more vulnerable to contamination than other aquifers as any anthropogenic-sourced contaminant, especially above a highly fractured zone, can infiltrate quickly into the aquifer and spread over a wide area. The vulnerability assessment method presented in this study is based on two approaches: DRASTIC and EPIK, within the framework of Geographical Information System (GIS). Results of this study show that DRASTIC vulnerability method suits Qatar hydrogeological settings more than EPIK. The produced vulnerability map using DRASTIC shows coastal and karst areas have the highest vulnerability class. The southern part of the country is located in the low vulnerability class due to occurrence of shale formation within aquifer media, which averts downward movement of contaminants.

  11. Potential shallow aquifers characterization through an integrated geophysical method: multivariate approach by means of k-means algorithms

    Directory of Open Access Journals (Sweden)

    Stefano Bernardinetti

    2017-06-01

    Full Text Available The need to obtain a detailed hydrogeological characterization of the subsurface and its interpretation for the groundwater resources management, often requires to apply several and complementary geophysical methods. The goal of the approach in this paper is to provide a unique model of the aquifer by synthesizing and optimizing the information provided by several geophysical methods. This approach greatly reduces the degree of uncertainty and subjectivity of the interpretation by exploiting the different physical and mechanic characteristics of the aquifer. The studied area, into the municipality of Laterina (Arezzo, Italy, is a shallow basin filled by lacustrine and alluvial deposits (Pleistocene and Olocene epochs, Quaternary period, with alternated silt, sand with variable content of gravel and clay where the bottom is represented by arenaceous-pelitic rocks (Mt. Cervarola Unit, Tuscan Domain, Miocene epoch. This shallow basin constitutes the unconfined superficial aquifer to be exploited in the nearly future. To improve the geological model obtained from a detailed geological survey we performed electrical resistivity and P wave refraction tomographies along the same line in order to obtain different, independent and integrable data sets. For the seismic data also the reflected events have been processed, a remarkable contribution to draw the geologic setting. Through the k-means algorithm, we perform a cluster analysis for the bivariate data set to individuate relationships between the two sets of variables. This algorithm allows to individuate clusters with the aim of minimizing the dissimilarity within each cluster and maximizing it among different clusters of the bivariate data set. The optimal number of clusters “K”, corresponding to the individuated geophysical facies, depends to the multivariate data set distribution and in this work is estimated with the Silhouettes. The result is an integrated tomography that shows a finite

  12. Diatom records in the Quaternary marine sequences around the Japanese Islands

    OpenAIRE

    Koizumi, Itaru; Yamamoto, Hirofumi

    2016-01-01

    Understanding the Quaternary is a key to estimating what the Earth's climate will be like in the future. Such studies demand high-resolution analyses based on paleoclimatic proxy records of changing Earth's orbital forcing and solar insolation that affect the climate system. Quaternary diatom biostratigraphy and paleoceanography have been well established based on the Quaternary marine sequences obtained by piston coring and deep-sea drilling around the Japanese Islands. This paper firstly re...

  13. 40 CFR 147.502 - Aquifer exemptions. [Reserved

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Aquifer exemptions. [Reserved] 147.502... (CONTINUED) STATE, TRIBAL, AND EPA-ADMINISTERED UNDERGROUND INJECTION CONTROL PROGRAMS Florida § 147.502 Aquifer exemptions. [Reserved] ...

  14. Simulation of seawater intrusion in coastal aquifers: Some typical ...

    Indian Academy of Sciences (India)

    Springer Verlag Heidelberg #4 2048 1996 Dec 15 10:16:45

    Seawater intrusion; coastal aquifers; density-dependent flow and ... The seawater intrusion mechanism in coastal aquifers generally causes the occurrence of ... (4) The dynamic viscosity of the fluid does not change with respect to salinity and.

  15. Ground Water movement in crystalline rock aquifers

    International Nuclear Information System (INIS)

    Serejo, A.N.C.; Freire, C.; Siqueira, H.B. de; Frischkorn, H.; Torquato, J.R.F.; Santiago, M.M.F.; Barbosa, P.C.

    1984-01-01

    Ground water movement studies were performed in crystalline rock aquifers from the upper Acarau River hydrographic basin, state of Ceara, Brazil. The studies included carbon-14, 18 O/ 16 O and tritium measurements as well as chemical analysis. A total of 35 wells were surveyed during drought seasons. Carbon-14 values displayed little variation which implied that the water use was adequate despite of the slower recharge conditions. Fairly constant isotopic 18 O/ 16 O ratio values in the wells and their similarity with rainwater values indicated that the recharge is done exclusively by pluvial waters. A decreasing tendency within the tritium concentration values were interpreted as a periodic rainwater renewal for these aquifers. The chemical analysis demonstrated that there is in fact no correlation between salinity and the time the water remains in the aquifer itself. (D.J.M.) [pt

  16. Unconsolidated Aquifers in Tompkins County, New York

    Science.gov (United States)

    Miller, Todd S.

    2000-01-01

    Unconsolidated aquifers consisting of saturated sand and gravel are capable of supplying large quantities of good-quality water to wells in Tompkins County, but little published geohydrologic inform ation on such aquifers is available. In 1986, the U.S.Geological Survey (USGS) began collecting geohydrologic information and well data to construct an aquifer map showing the extent of unconsolidated aquifers in Tompkins county. Data sources included (1) water-well drillers. logs; (2) highway and other construction test-boring logs; (3) well data gathered by the Tompkins County Department of Health, (4) test-well logs from geohydrologic consultants that conducted projects for site-specific studies, and (5) well data that had been collected during past investigations by the USGS and entered into the National Water Information System (NWIS) database. In 1999, the USGS, in cooperation with the Tompkins County Department of Planning, compiled these data to construct this map. More than 600 well records were entered into the NWIS database in 1999 to supplement the 350 well records already in the database; this provided a total of 950 well records. The data were digitized and imported into a geographic information system (GIS) coverage so that well locations could be plotted on a map, and well data could be tabulated in a digital data base through ARC/INFO software. Data on the surficial geology were used with geohydrologic data from well records and previous studies to delineate the extent of aquifers on this map. This map depicts (1) the extent of unconsolidated aquifers in Tompkins County, and (2) locations of wells whose records were entered into the USGS NWIS database and made into a GIS digital coverage. The hydrologic information presented here is generalized and is not intended for detailed site evaluations. Precise locations of geohydrologic-unit boundaries, and a description of the hydrologic conditions within the units, would require additional detailed, site

  17. Aquifer thermal energy storage. International symposium: Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-05-01

    Aquifers have been used to store large quantities of thermal energy to supply process cooling, space cooling, space heating, and ventilation air preheating, and can be used with or without heat pumps. Aquifers are used as energy sinks and sources when supply and demand for energy do not coincide. Aquifer thermal energy storage may be used on a short-term or long-term basis; as the sole source of energy or as a partial storage; at a temperature useful for direct application or needing upgrade. The sources of energy used for aquifer storage are ambient air, usually cold winter air; waste or by-product energy; and renewable energy such as solar. The present technical, financial and environmental status of ATES is promising. Numerous projects are operating and under development in several countries. These projects are listed and results from Canada and elsewhere are used to illustrate the present status of ATES. Technical obstacles have been addressed and have largely been overcome. Cold storage in aquifers can be seen as a standard design option in the near future as it presently is in some countries. The cost-effectiveness of aquifer thermal energy storage is based on the capital cost avoidance of conventional chilling equipment and energy savings. ATES is one of many developments in energy efficient building technology and its success depends on relating it to important building market and environmental trends. This paper attempts to provide guidance for the future implementation of ATES. Individual projects have been processed separately for entry onto the Department of Energy databases.

  18. Modelling contaminant transport in saturated aquifers

    International Nuclear Information System (INIS)

    Lakshminarayana, V.; Nayak, T.R.

    1990-01-01

    With the increase in population and industrialization the problem of pollution of groundwater has become critical. The present study deals with modelling of pollutant transport through saturated aquifers. Using this model it is possible to predict the concentration distribution, spatial as well as temporal, in the aquifer. The paper also deals with one of the methods of controlling the pollutant movement, namely by pumping wells. A simulation model is developed to determine the number, location and rate of pumping of a number of wells near the source of pollution so that the concentration is within acceptable limits at the point of interest. (Author) (18 refs., 14 figs., tab.)

  19. Comparison of groundwater flow in Southern California coastal aquifers

    Science.gov (United States)

    Hanson, Randall T.; Izbicki, John A.; Reichard, Eric G.; Edwards, Brian D.; Land, Michael; Martin, Peter

    2009-01-01

    Development of the coastal aquifer systems of Southern California has resulted in overdraft, changes in streamflow, seawater intrusion, land subsidence, increased vertical flow between aquifers, and a redirection of regional flow toward pumping centers. These water-management challenges can be more effectively addressed by incorporating new understanding of the geologic, hydrologic, and geochemical setting of these aquifers.

  20. Groundwater Flow Model of Göksu Delta Coastal Aquifer System

    Science.gov (United States)

    Erdem Dokuz, Uǧur; Çelik, Mehmet; Arslan, Şebnem; Engin, Hilal

    2016-04-01

    Like many other coastal areas, Göksu Delta (Mersin-Silifke, Southern Turkey) is a preferred place for human settlement especially due to its productive farmlands and water resources. The water dependent ecosystem in Göksu delta hosts about 332 different plant species and 328 different bird species besides serving for human use. Göksu Delta has been declared as Special Environmental Protection Zone, Wildlife Protection Area, and RAMSAR Convention for Wetlands of International Importance area. Unfortunately, rising population, agricultural and industrial activities cause degradation of water resources both by means of quality and quantity. This problem also exists for other wetlands around the world. It is necessary to prepare water management plans by taking global warming issues into account to protect water resources for next generations. To achieve this, the most efficient tool is to come up with groundwater management strategies by constructing groundwater flow models. By this aim, groundwater modeling studies were carried out for Göksu Delta coastal aquifer system. As a first and most important step in all groundwater modeling studies, geological and hydrogeological settings of the study area have been investigated. Göksu Delta, like many other deltaic environments, has a complex structure because it was formed with the sediments transported by Göksu River throughout the Quaternary period and shaped throughout the transgression-regression periods. Both due to this complex structure and the lack of observation wells penetrating deep enough to give an idea of the total thickness of the delta, it was impossible to reveal out the hydrogeological setting in a correct manner. Therefore, six wells were drilled to construct the conceptual hydrogeological model of Göksu Delta coastal aquifer system. On the basis of drilling studies and slug tests that were conducted along Göksu Delta, hydrostratigraphic units of the delta system have been obtained. According to

  1. Hydrochemical zonation of the western part of Göksu Delta aquifer system, Southern Turkey

    Science.gov (United States)

    Dokuz, U. E.; Çelik, M.; Arslan, Ş.; Engin, H.

    2012-04-01

    In general, coastal areas are preferred places for human settlement, especially at places where infrastructure routes benefit from rivers, streets, or harbours. As a result, these areas usually suffer from rising population and endure increasingly high demand on natural resources like water. Göksu Delta, located in southern Turkey, is one of the important wetland areas of Turkey at the Mediterranean coast. It is divided into two parts by Göksu River. The western part of the delta, which is the subject matter of this study, hosts fertile agricultural fields, touristic places and a Special Environmental Protection Area. These properties of the region lead to a water-dependent ecosystem where groundwater has widely been used for agricultural and domestic purposes. When the exploitation of groundwater peaked in the middle of 1990s, the groundwater levels dropped and seawater intruded. General Directorate of State Hydraulic Works tried to stop seawater intrusion by building irrigation channels connected to Göksu River and banned drilling of new wells for groundwater exploitation, although it is hard to control the drilling of wells without official permit. Geological studies show that the delta is composed of terrestrial sediments including clay to coarse sand deposited during Quaternary. The heterogeneous sediments of Göksu Delta cause hydrogeological features of the aquifer systems to be heterogeneous and anisotropic. Hydrogeological investigations, therefore, indicate mainly two different aquifers, shallow and deep, separated by an aquitard. The shallow aquifer is under unconfined to confined conditions from north to south while the deep aquifer is under confined conditions. This study focuses on hydrogeochemical zonation in terms of hydrochemical processes that affect the Göksu Delta aquifer systems. For this purpose, hydrogeochemical and isotopic studies are conducted to understand the salinisation and softening processes of groundwater. The physicochemical

  2. Groundwaters of Florence (Italy): Trace element distribution and vulnerability of the aquifers

    Science.gov (United States)

    Bencini, A.; Ercolanelli, R.; Sbaragli, A.; Verrucchi, C.

    1993-11-01

    Geochemical and hydrogeological research has been carried out on 109 wells in the alluvial plain of Florence, in order to evaluate conductivity and main chemistry of ground waters, the pattern of some possible pollutant chemical species (Fe, Mn, Cr, Cu, Pb, Zn, NO2, NO3), and the vulnerability of the aquifers. The plain is made up of Plio-Quaternary alluvial and lacustrine sediments for a maximum thickness of 600 m. Silts and clays, sometimes with lenses of sandy gravels, are dominant, while considerable deposits of sands, pebbles, and gravels occur along the course of the Arno river and its tributary streams, and represent the most important aquifer of the plain. The groundwaters analyzed belong to this aquifer or to the smaller ones, hosted in the gravel lenses. Most waters show conductivity values around 1000 1200 μS, and almost all of them have an alkaline-earth-bicarbonate chemical character; these features are consistent with the mainly calcareous lithology of the aquifers. In the western areas a higher salt content of the groundwaters is evident, probably related to the presence of industrial activities which use water desalinators. Heavy metal and NO2, NO3 analyses point out that no important pollution phenomena affect the groundwaters; all the mean values of the chemical considered species are below the maximum admissible concentration (MAC) fixed by the European Community for drinkable waters. Nevertheless, some anomalies of NO2, NO3, Fe, Mn, and Zn are present in the plain. Apart from Mn, which seems to be released by certain calcareous gravels, the other anomalies have a local influence, since they disappear even in the nearest wells. The most plausible causes can be recognized in losses of the sewage system (NO2=3 4 mg/t); use of nitrate compounds in agriculture (NO3=60 70 mg/l); oxidation of well pipes (Fe ≈ 20 mg/l; Zn ≈ 6 mg/l). As regards Cr, Cu, and Pb, all the observations are below the MAC; therefore, the median values of bacteria oxidation

  3. Acid groundwater in an anoxic aquifer: Reactive transport modelling of buffering processes

    International Nuclear Information System (INIS)

    Franken, Gudrun; Postma, Dieke; Duijnisveld, Wilhelmus H.M.; Boettcher, Juergen; Molson, John

    2009-01-01

    The acidification of groundwater, due to acid rain, was investigated in a Quaternary sandy aquifer in the Fuhrberger Feld, near Hannover, Germany. The groundwater, recharged through an area covered by a coniferous forest, had a pH in the range 4-5 down to a depth of 5 m. The evolution in groundwater chemistry along the flow path was investigated in a transect of multisamplers. A 2D groundwater flow model was established delineating the groundwater flow field and a groundwater flow velocity of around 80 m/a along the flow path was derived. Speciation calculations showed the groundwater to be close to equilibrium with the mineral jurbanite (AlOHSO 4 ) over the pH range 4.0-6.5. This suggests an accumulation of acid rain derived SO 4 2- in the aquifer sediment during the decades with high atmospheric S deposition. The groundwater has a pH of around 4.5 in the upstream part of the flow path increasing to near 6 further downstream. 1D reactive transport modelling, using PHREEQC, was used to analyze different combinations of buffering processes. The first model contains ion exchange in combination with jurbanite dissolution. At the ion exchange front Al 3+ is adsorbed leading to the dissolution of jurbanite and an increase in pH. Comparison with field data showed that the simulated increases in pH and alkalinity are much lower than observed in the field. The second model includes organic matter degradation. In addition to ion exchange and jurbanite dissolution, the model included the reduction of SO 4 2- and Fe-oxides as well as the precipitation of Fe sulfide. This model matches the field data well and illustrates the importance of redox processes for pH buffering in the Fuhrberg aquifer. The current progress of the acidification front is about 4 m/a. This corresponds to an average value of 150 a of acid input, which covers large historical variations. Remediation is expected to take the same time span because it requires desorption and neutralization of adsorbed Al 3

  4. Groundwaters of Florence (Italy): Trace element distribution and vulnerability of the aquifers

    Energy Technology Data Exchange (ETDEWEB)

    Bencini, A.; Ercolanelli, R.; Sbaragli, A. [Univ. of Florence (Italy)] [and others

    1993-11-01

    Geochemical and hydrogeological research has been carried out in Florence, to evaluate conductivity and main chemistry of groundwaters, the pattern of some possible pollutant chemical species (Fe, Mn, Cr, Cu, Pb, Zn, NO{sub 2}, NO{sub 3}), and the vulnerability of the aquifers. The plain is made up of Plio-Quaternary alluvial and lacustrine sediments for a maximum thickness of 600 m. Silts and clays, sometimes with lenses of sandy gravels, are dominant, while considerable deposits of sands, pebbles, and gravels occur along the course of the Arno river and its tributary streams, and represent the most important aquifer of the plain. Most waters show conductivity values around 1000-1200 {mu}S, and almost all of them have an alkaline-earth-bicarbonate chemical character. In western areas higher salt content of the groundwaters is evident. Heavy metal and NO{sub 2}, NO{sub 3} analyses point out that no important pollution phenomena affect the groundwaters; all mean values are below the maximum admissible concentration (MAC) for drinkable waters. Some anomalies of NO{sub 2}, NO{sub 3}, Fe, Mn, and Zn are present. The most plausible causes can be recognized in losses of the sewage system; use of nitrate compounds in agriculture; oxidation of well pipes. All the observations of Cr, Cu, and Pb are below the MAC; the median values of <3, 3.9, and 1.1 {mu}g/l, respectively, could be considered reference concentrations for groundwaters in calcareous lithotypes, under undisturbed natural conditions. Finally, a map of vulnerability shows that the areas near the Arno river are highly vulnerable, for the minimum thickness (or lacking) of sediments covering the aquifer. On the other hand, in the case of pollution, several factors not considered could significantly increase the self-purification capacity of the aquifer, such asdilution of groundwaters, bacteria oxidation of nitrogenous species, and sorption capacity of clay minerals and organic matter. 31 refs., 6 figs., 5 tabs.

  5. Constraints of costal aquifer functioning in a deeply antropized area through a multi-isotope fingerprinting (Recife, Brazil)

    Science.gov (United States)

    Petelet-Giraud, Emmanuelle; Cary, Lise; Bertrand, Guillaume; Hirata, Ricardo; Martins, Veridiana; Montenegro, Suzana; Pauwels, Hélène; Kloppmann, Wolfram; Aquilina, Luc

    2014-05-01

    The Metropolitan Region of Recife (RMR) went through large changes of water and land uses over the last decades due to an increasing demographic pressure (1.5 M of inhabitants). These evolutions gave rise to numerous environmental consequences, such as a dramatic decline of the water levels, groundwater salinization and contamination. This degradation of natural resources is linked to the increase of water demand that is also punctually amplified by drought periods, inducing the construction of thousands of private wells. Recife city was built on an estuarine area, at the geological limits of the two sedimentary basins of Pernambuco (north of the city) and Paraíba (south of the city) separated by a famous shear zone (the Pernambuco lineament). Tectonic and sedimentary events involved in the genesis and evolution of these basins were mainly controlled by the opening of the Atlantic Ocean leading to the deposition of cretaceous sediments which now constitute the two main exploited aquifers, the Beberibe and Cabo aquifers. These two deep aquiferous formations are topped by the unconfined Boa Viagem aquifer of quaternary sediments. It is the most directly exposed to contamination, since it is connected to mangroves, rivers, estuaries and highly urbanized areas. Both the Beberibe and Cabo aquifers contain large clay levels and are separated by a rather continuous clayed formation which seems to play a consistent role of screen and to interfere in the hydraulic connections between the three aquifers. Previous isotopic studies have shown that recharge processes are similar in the aquifers, suggesting that exchanges may occur and may be modified or amplified by overexploitation. This very complex aquifer system is studied through more than 60 water samples, including some surface water samples from the main rivers. A methodology based on multi-isotopes fingerprinting is applied, including stable isotopes of the water molecule, strontium isotopes, boron isotopes, sulfur

  6. Acid resistance of quaternary blended recycled aggregate concrete

    Directory of Open Access Journals (Sweden)

    K Jagannadha Rao

    2018-06-01

    Full Text Available The possibility of reusing the aggregate from demolished structures in fresh concrete, in order to reduce the CO2 impact on the environment [23] and to preserve natural resources, was explored worldwide and it is established that recycled aggregates can be used as a partial replacement of natural aggregates. Due to its potential to be used in eco-friendly structures and shortage of supply of natural aggregates in some parts of the world, there is an increasing interest in using the recycled aggregate. The durability aspects are also of equal concern along with the strength and economy of any material to be used in the construction. Studies reveal that the behaviour of ternary and quaternary blended concretes is superior from durability point of view compared to conventional concrete. Therefore a study is conducted to assess the acid resistance of recycled aggregate based Quaternary Blended Cement Concrete (QBCC of two grades M40 and M60. Fly ash and silica fume are fixed at 20% and 10% respectively from the previous studies while two percentages of Nano silica (2 and 3% were used along with the cement to obtain QBCC. Three percentages of recycled aggregates as partial replacement of conventional aggregate (0%, 50% and 75% were used in this study. Two different acids (HCL and H2SO4 with different concentrations (3 and 5% were used in this study. Acid resistance of QBCC with Recycled Concrete Aggregate (RCA is assessed in terms of visual appearance, weight loss, and compressive strength loss by destructive and non-destructive tests at regular intervals for a period of 56 days. The test results showed marginal weight loss and strength loss in both M40 and M60 grades of concretes. The Ultrasonic Pulse Velocity (UPV results show that the quality of QBCC is good even after being subjected to acid exposure. Keywords: Recycled concrete aggregate (RCA, Quaternary blended cement concrete (QBCC, Acid resistance, Ultrasonic pulse velocity (UPV, Mineral

  7. Aquifer geochemistry at potential aquifer storage and recovery sites in coastal plain aquifers in the New York city area, USA

    Science.gov (United States)

    Brown, C.J.; Misut, P.E.

    2010-01-01

    The effects of injecting oxic water from the New York city (NYC) drinking-water supply and distribution system into a nearby anoxic coastal plain aquifer for later recovery during periods of water shortage (aquifer storage and recovery, or ASR) were simulated by a 3-dimensional, reactive-solute transport model. The Cretaceous aquifer system in the NYC area of New York and New Jersey, USA contains pyrite, goethite, locally occurring siderite, lignite, and locally varying amounts of dissolved Fe and salinity. Sediment from cores drilled on Staten Island and western Long Island had high extractable concentrations of Fe, Mn, and acid volatile sulfides (AVS) plus chromium-reducible sulfides (CRS) and low concentrations of As, Pb, Cd, Cr, Cu and U. Similarly, water samples from the Lloyd aquifer (Cretaceous) in western Long Island generally contained high concentrations of Fe and Mn and low concentrations of other trace elements such as As, Pb, Cd, Cr, Cu and U, all of which were below US Environmental Protection Agency (USEPA) and NY maximum contaminant levels (MCLs). In such aquifer settings, ASR operations can be complicated by the oxidative dissolution of pyrite, low pH, and high concentrations of dissolved Fe in extracted water.The simulated injection of buffered, oxic city water into a hypothetical ASR well increased the hydraulic head at the well, displaced the ambient groundwater, and formed a spheroid of injected water with lower concentrations of Fe, Mn and major ions in water surrounding the ASR well, than in ambient water. Both the dissolved O2 concentrations and the pH of water near the well generally increased in magnitude during the simulated 5-a injection phase. The resultant oxidation of Fe2+ and attendant precipitation of goethite during injection provided a substrate for sorption of dissolved Fe during the 8-a extraction phase. The baseline scenario with a low (0.001M) concentration of pyrite in aquifer sediments, indicated that nearly 190% more water

  8. Quaternary continental deposits in north of Uruguay: stratigraphy and paleontology

    International Nuclear Information System (INIS)

    Goso Aguilar, C.; Ubilla, M.

    2004-01-01

    Conglomeradic and sandstones lithofacies corresponding to fluvial and alluvial environments were recognized. These sediments partially belong to the quaternary Mataojos Formation. A discordant contact with the upper pelitic deposits identified with the Sopas Formation was detected. This paper deals with sedimentological and stratigraphical considerations in order to explain the sedimentary processes during the genesis of these stratigraphic sections as well as to begin a lithostratigraphical discussion about the operability of those units. In turn, chronologic and paleoenvironment comments are provided taken into account vertebrates fossils and tools to perform chronocorrelation with southern sedimentological units of Uruguay [es

  9. Investigating river–aquifer relations using water temperature in an anthropized environment (Motril-Salobreña aquifer)

    DEFF Research Database (Denmark)

    Duque, Carlos; Calvache, Marie; Engesgaard, Peter Knudegaard

    2010-01-01

    Heat was applied as a tracer for determining river–aquifer relations in the Motril-Salobreña aquifer (S Spain). The aquifer has typically been recharged by River Guadalfeo infiltration, nevertheless from 2005 a dam was constructed changing the traditional dynamic river flow and recharge events...

  10. Hydrological controls on transient aquifer storage in a karst watershed

    Science.gov (United States)

    Spellman, P.; Martin, J.; Gulley, J. D.

    2017-12-01

    While surface storage of floodwaters is well-known to attenuate flood peaks, transient storage of floodwaters in aquifers is a less recognized mechanism of flood peak attenuation. The hydraulic gradient from aquifer to river controls the magnitude of transient aquifer storage and is ultimately a function of aquifer hydraulic conductivity, and effective porosity. Because bedrock and granular aquifers tend to have lower hydraulic conductivities and porosities, their ability to attenuate flood peaks is generally small. In karst aquifers, however, extensive cave systems create high hydraulic conductivities and porosities that create low antecedent hydraulic gradients between aquifers and rivers. Cave springs can reverse flow during high discharges in rivers, temporarily storing floodwaters in the aquifer thus reducing the magnitude of flood discharge downstream. To date however, very few studies have quantified the magnitude or controls of transient aquifer storage in karst watersheds. We therefore investigate controls on transient aquifer storage by using 10 years of river and groundwater data from the Suwannee River Basin, which flows over the karstic upper Floridan aquifer in north-central Florida. We use multiple linear regression to compare the effects of three hydrological controls on the magnitude of transient aquifer storage: antecedent stage, recharge and slope of hydrograph rise. We show the dominant control on transient aquifer storage is antecedent stage, whereby lower stages result in greater magnitudes of transient aquifer storage. Our results suggest that measures of groundwater levels prior to an event can be useful in determining whether transient aquifer storage will occur and may provide a useful metric for improving predictions of flood magnitudes.

  11. Can Remote Sensing Detect Aquifer Characteristics?: A Case Study in the Guarani Aquifer System

    Science.gov (United States)

    Richey, A. S.; Thomas, B.; Famiglietti, J. S.

    2013-12-01

    Global water supply resiliency depends on groundwater, especially regions threatened by population growth and climate change. Aquifer characteristics, even as basic as confined versus unconfined, are necessary to prescribe regulations to sustainably manage groundwater supplies. A significant barrier to sustainable groundwater management exists in the difficulties associated with mapping groundwater resources and characteristics at a large spatial scale. This study addresses this challenge by investigating if remote sensing, including with NASA's Gravity Recovery and Climate Experiment (GRACE), can detect and quantify key aquifer parameters and characteristics. We explore this through a case study in the Guarani Aquifer System (GAS) of South America, validating our remote sensing-based findings against the best available regional estimates. The use of remote sensing to advance the understanding of large aquifers is beneficial to sustainable groundwater management, especially in a trans-boundary system, where consistent information exchange can occur within hydrologic boundaries instead of political boundaries.

  12. State Aquifer Recharge Atlas Plates, Geographic NAD83, LDEQ (1999) [aquifer_recharge_potential_LDEQ_1988

    Data.gov (United States)

    Louisiana Geographic Information Center — This is a polygon dataset depicting the boundaries of aquifer systems in the state of Louisiana and adjacent areas of Texas, Arkansas and a portion of Mississippi....

  13. Nutrient Removal during Stormwater Aquifer Storage and Recovery in an Anoxic Carbonate Aquifer.

    Science.gov (United States)

    Vanderzalm, Joanne L; Page, Declan W; Dillon, Peter J; Barry, Karen E; Gonzalez, Dennis

    2018-03-01

    Stormwater harvesting coupled to managed aquifer recharge (MAR) provides a means to use the often wasted stormwater resource while also providing protection of the natural and built environment. Aquifers can act as a treatment barrier within a multiple-barrier approach to harvest and use urban stormwater. However, it remains challenging to assess the treatment performance of a MAR scheme due to the heterogeneity of aquifers and MAR operations, which in turn influences water treatment processes. This study uses a probabilistic method to evaluate aquifer treatment performance based on the removal of total organic C (TOC), N, and P during MAR with urban stormwater in an anoxic carbonate aquifer. Total organic C, N, and P are represented as stochastic variables and described by probability density functions (PDFs) for the "injectant" and "recovery"; these injectant and recovery PDFs are used to derive a theoretical MAR removal efficiency PDF. Four long-term MAR sites targeting one of two tertiary carbonate aquifers (T1 and T2) were used to describe the nutrient removal efficiencies. Removal of TOC and total N (TN) was dominated by redox processes, with median removal of TOC between 50 and 60% at all sites and TN from 40 to 50% at three sites with no change at the fourth. Total P removal due to filtration and sorption accounted for median removal of 29 to 53%. Thus, the statistical method was able to characterize the capacity of the anoxic carbonate aquifer treatment barrier for nutrient removal, which highlights that aquifers can be an effective long-term natural treatment option for management of water quality, as well as storage of urban stormwater. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  14. Risk assessment and management of an oil contaminated aquifer

    International Nuclear Information System (INIS)

    Braxein, A.; Daniels, H.; Rouve, G.; Rubin, H.

    1991-01-01

    This paper concerns the provision of the basic information needed for the decision making process regarding the remedial measures leading to reutilization of an oil contaminated aquifer. The study refers to the case history of jet fuel contamination of an aquifer comprising part of the coastal aquifer of Israel. Due to that contamination two major water supply wells were abandoned. This study examines the use of numerical simulations in order to restore the contamination history of the aquifer. Such simulations also provide quantitative information needed for the decision making process regarding the future management of the contaminated aquifer

  15. Remediation of a contaminated thin aquifer by horizontal wells

    Energy Technology Data Exchange (ETDEWEB)

    Breh, W.; Suttheimer, J.; Hoetzl, H. [Univ. of Karlsruhe (Germany); Frank, K. [GEO-Service GmbH, Rheinmuenster (Germany)

    1997-12-31

    At an industrial site in Bruchsal (Germany) a huge trichloroethene contamination was found. After common remedial actions proved to be widely ineffective, new investigations led to a highly contaminated thin aquifer above the main aquifer. The investigation and the beginning of the remediation of the thin aquifer by two horizontal wells is described in this paper. Special attention was given to the dependence between precipitation and the flow direction in the thin aquifer and to hydraulic connections between the thin and the main aquifer. Also a short introduction into a new remedial technique by horizontal wells and first results of the test phase of the horizontal wells are given.

  16. Groundwater sustainability assessment in coastal aquifers

    Indian Academy of Sciences (India)

    The present work investigates the response of shallow, coastal unconfined aquifers to anticipated overdraft conditions and climate change effect using numerical simulation. The groundwater flow model MODFLOW and variable density groundwater model SEAWAT are used for this investigation. The transmissivity and ...

  17. Biogeochemical aspects of aquifer thermal energy storage

    NARCIS (Netherlands)

    Brons, H.J.

    1992-01-01

    During the process of aquifer thermal energy storage the in situ temperature of the groundwater- sediment system may fluctuate significantly. As a result the groundwater characteristics can be considerably affected by a variety of chemical, biogeochemical and microbiological

  18. Hydrochemical characterization of groundwater aquifer using ...

    African Journals Online (AJOL)

    Hydrochemical data analysis revealed four sources of solutes. The processes responsible for their enrichment include: chemical weathering, leaching of the overlying sediments, domestic activities, climatic condition and the flow pattern of the aquifer. The factors have contributed to the changes of the groundwater chemistry ...

  19. Transient well flow in vertically heterogeneous aquifers.

    NARCIS (Netherlands)

    Hemker, C.J.

    1999-01-01

    A solution for the general problem of computing well flow in vertically heterogeneous aquifers is found by an integration of both analytical and numerical techniques. The radial component of flow is treated analytically; the drawdown is a continuous function of the distance to the well. The

  20. Aquifer restoration: state of the art

    National Research Council Canada - National Science Library

    Knox, Robert C; Knox, R. C

    1986-01-01

    ... of chemicals or waste materials, improper underground injection of liquid wastes, and placement of septic tank systems in hydrologically and geologically unsuitable locations. Incidents of aquifer pollution from man's waste disposal activities have been discovered with increasing regularity. At the same time, demands for groundwater usage have been inc...

  1. VULNERABILITY AND RISK OF CONTAMINATION KARSTIC AQUIFERS

    Directory of Open Access Journals (Sweden)

    Yameli Aguilar

    2013-08-01

    Full Text Available Karstic systems occupy nearly 20% of the surface of the earth and are inhabited by numerous human communities. Karstic aquifers are the most exposed to pollution from human activities. Pollution of karstic aquifers is a severe environmental problem worldwide.  In order to face the vulnerability of karstic aquifers to pollution, researchers have created a diversity of study approaches and models, each one having their own strengths and weaknesses depending on the discipline from which they were originated, thus requiring a thorough discussion within the required multidisciplinary character. The objective of this article was to analyze the theoretical and methodological approaches applied to the pollution of karstic aquifers. The European hydrogeological, land evaluation, hydropedological and a geographic approach were analyzed. The relevance of a geomorphological analysis as a cartographic basis for the analysis of vulnerability and risks were emphasized. From the analysis of models, approaches and methodologies discussed the following recommendation is made: to form an interdisciplinary work team, to elaborate a conceptual model according to the site and the working scale and to e, apply and validate the model.

  2. isotopic characteristics of aquifers in sinai

    International Nuclear Information System (INIS)

    Al-Gamal, S.A.

    2004-01-01

    the environmental isotopes data (expressed as δ 2 d and δ 18 O) of different aquifers in sinai were treated using correlation and regression techniques. whereas, rain water isotopic data were treated using empirical orthogonal functions (EOF) techniques. environmental isotopes for different aquifers expressed in terms of O-18 and H-2, were taken to represent the isotopic characteristics. regression equations using the highly correlated variables of δ 2 d and δ 18 O were constructed for each aquifer. the latitudinal variations (of rainwater in sinai and selected climatic stations east mediterranean ) versus rainwater isotopic compositions were analyzed using the normalized variables. it was found that the latitudinal variations of the rainwater isotopic compositions ( δ 2 D, δ 18 O), vapor pressure, and surface temperature occurred in parallel and decreased with latitude. in the east mediterranean, empirical linear relationship between altitude and δ 2 D has indicted that the rate of change of δ 2 D with height is comparable with the dry lapse rate in the atmosphere.The obtained regression equations of environmental isotopes data have impacted on different slopes and different constants expressing the non-homogeneity in the isotopic composition of rainwater recharging the aquifers of sinai , due to the presence of different air masses

  3. Quaternary Geologic Map of the Lake Superior 4° x 6° Quadrangle, United States and Canada

    Data.gov (United States)

    Department of the Interior — The Quaternary Geologic Map of the Lake Superior 4° x 6° Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as...

  4. The Gediz River fluvial archive : A benchmark for Quaternary research in Western Anatolia

    NARCIS (Netherlands)

    Maddy, D.; Veldkamp, A.; Demir, T.; van Gorp, W.; Wijbrans, J.R.; van Hinsbergen, D.J.J.; Dekkers, M.J.; Schreve, D.; Schoorl, J.M.; Scaife, R.; Stemerdink, C.; van der Schriek, T.; Bridgland, D.R.; Aytaç, A.S.

    2017-01-01

    The Gediz River, one of the principal rivers of Western Anatolia, has an extensive Pleistocene fluvial archive that potentially offers a unique window into fluvial system behaviour on the western margins of Asia during the Quaternary. In this paper we review our work on the Quaternary Gediz River

  5. Hydrogeology - AQUIFER_SYSTEMS_BEDROCK_IDNR_IN: Bedrock Aquifer Systems of Indiana (Indiana Department of Natural Resources, 1:500,000, Polygon Shapefile)

    Data.gov (United States)

    NSGIC State | GIS Inventory — AQUIFER_SYSTEMS_BEDROCK_IDNR_IN is a polygon shapefile that shows bedrock aquifer systems of the State of Indiana. The source scale of the map depicting the aquifers...

  6. Arsenic release during managed aquifer recharge (MAR)

    Science.gov (United States)

    Pichler, T.; Lazareva, O.; Druschel, G.

    2013-12-01

    The mobilization and addition of geogenic trace metals to groundwater is typically caused by anthropogenic perturbations of the physicochemical conditions in the aquifer. This can add dangerously high levels of toxins to groundwater, thus compromising its use as a source of drinking water. In several regions world-wide, aquifer storage and recovery (ASR), a form of managed aquifer recharge (MAR), faces the problem of arsenic release due to the injection of oxygenated storage water. To better understand this process we coupled geochemical reactive transport modeling to bench-scale leaching experiments to investigate and verify the mobilization of geogenic arsenic (As) under a range of redox conditions from an arsenic-rich pyrite bearing limestone aquifer in Central Florida. Modeling and experimental observations showed similar results and confirmed the following: (1) native groundwater and aquifer matrix, including pyrite, were in chemical equilibrium, thus preventing the release of As due to pyrite dissolution under ambient conditions; (2) mixing of oxygen-rich surface water with oxygen-depleted native groundwater changed the redox conditions and promoted the dissolution of pyrite, and (3) the behavior of As along a flow path was controlled by a complex series of interconnected reactions. This included the oxidative dissolution of pyrite and simultaneous sorption of As onto neo-formed hydrous ferric oxides (HFO), followed by the reductive dissolution of HFO and secondary release of adsorbed As under reducing conditions. Arsenic contamination of drinking water in these systems is thus controlled by the re-equilibration of the system to more reducing conditions rather than a purely oxidative process.

  7. Ground-water-quality assessment of the Central Oklahoma Aquifer, Oklahoma: geochemical and geohydrologic investigations

    Science.gov (United States)

    Parkhurst, David L.; Christenson, Scott C.; Breit, George N.

    1993-01-01

    The National Water-Quality Assessment pilot project for the Central Oklahoma aquifer examined the chemical and isotopic composition of ground water, the abundances and textures of minerals in core samples, and water levels and hydraulic properties in the flow system to identify geochemical reactions occurring in the aquifer and rates and directions of ground-water flow. The aquifer underlies 3,000 square miles of central Oklahoma and consists of Permian red beds, including parts of the Permian Garber Sandstone, Wellington Formation, and Chase, Council Grove, and Admire Groups, and Quaternary alluvium and terrace deposits.In the part of the Garber Sandstone and Wellington Formation that is not confined by the Permian Hennessey Group, calcium, magnesium, and bicarbonate are the dominant ions in ground water; in the confined part of the Garber Sandstone and Wellington Formation and in the Chase, Council Grove, and Admire Groups, sodium and bicarbonate are the dominant ions in ground water. Nearly all of the Central Oklahoma aquifer has an oxic or post-oxic environment as indicated by the large dissolved concentrations of oxygen, nitrate, arsenic(V), chromium(VI), selenium(VI), vanadium, and uranium. Sulfidic and methanic environments are virtually absent.Petrographic textures indicate dolomite, calcite, sodic plagioclase, potassium feldspars, chlorite, rock fragments, and micas are dissolving, and iron oxides, manganese oxides, kaolinite, and quartz are precipitating. Variations in the quantity of exchangeable sodium in clays indicate that cation exchange is occurring within the aquifer. Gypsum may dissolve locally within the aquifer, as indicated by ground water with large concentra-tions of sulfate, but gypsum was not observed in core samples. Rainwater is not a major source for most elements in ground water, but evapotranspiration could cause rainwater to be a significant source of potassium, sulfate, phosphate and nitrogen species. Brines derived from seawater are

  8. Mineralogical and geological study of quaternary deposits and weathering profiles

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Gi Young; Lee, Bong Ho [Andong National Univ., Andong (Korea, Republic of)

    2004-01-15

    Movement history of a quaternary reverse fault cutting marine terrace deposit and tertiary bentonite in the Yangnammyon, Gyoungju city was studied by the mineralogical and microtextural analysis of the fault clays and weathered terrace deposits. Two types of fault clays were identified as greenish gray before the deposition of the marine terrace deposits and reddish brown after deposition. Greenish gray fault clay is composed mostly of smectite probably powdered from bentonite showing at least two events of movement from microtextures. After the bentonite was covered by quaternary marine gravel deposits, the reverse fault was reactivated cutting marine gravel deposits to form open spaces along the fault plane which allowed the hydrological infiltration of soil particles and deposition of clays in deep subsurface. The reddish brown 'fault' clays enclosed the fragments of dark brown ultrafine varved clay, proving two events of faulting, and slicken sides bisecting reddish brown clays suggest another faulting event in the final stage. Mineralogical and microtextural analysis of the fault clay show total five events of faulting, which had not been recognized even by thorough conventional paleoseismological investigation using trench, highlighting the importance of microtextural and mineralogical analysis in paleoseismology.

  9. Distribution and metabolism of quaternary amines in salt marshes

    Science.gov (United States)

    King, Gary M.

    1985-01-01

    Quaternary amines such as glycine betaine (GBT) are common osmotically active solutes in much of the marine biota. GBT is accumulated by various bacteria, algae, higher plants, invertebrates, and vertebrates in response to salinity or water stresses; in some species, GBT occurs at tens to hundreds of millimolar concentrations and can account for a significant fraction of total nitrogen. Initial studies suggest that GBT is readily converted to two potential methane precursors, trimethylamine (TMA) and acetate, in anoxic sediments. TMA is apparently the most important methane precursor in surface sediments containing sulfate reducing bacteria. In salt marshes, the bulk of the methane formed may be due to the metabolism of TMA rather than other substrates. Current research is focussed on testing this hypothesis and on determining the role of quaternary amino osmoregulatory solutes in methane fluxes from marine environments. Preliminary studies have dealt with several problems: (1) determination of GBT concentrations in the dominant flora and fauna of salt marshes; (2) synthesis of radiolabelled GBT for metabolic studies; and (3) determination of fates of BGT in marine sediments using radiotracers. Both GC and HPLC techniques have been used to assay GBT concentrations in plant and animal tissues. S. alterniflora is probably the only significant source of GBT (and indirectly of methane) since the biomass and distribution of most other species is limited. Current estimates suggest that S. alterniflora GBT could account for most of the methane efflux from salt marshes.

  10. [Quaternary prevention: An attempt to avoid the excesses of Medicine].

    Science.gov (United States)

    Noble, María

    2015-09-01

    Seduced by technology, biometrics, practical guidelines and the use of medication, medicine has been driven away from the subject of its care. Quaternary prevention is, among other voices around the world, trying to denounce the consequent excesses of medical practice given by this situation. There are visible excesses, such as the long list of studies being performed on patients without indication, and others, much more subtle, as excessive prevention and the continuous and progressive medicalization of life itself that are rooted in our culture and demanded by a society that requests certainty at almost any cost. Quaternary prevention proposes a series of actions leaning towards avoiding and diminishing the damage produced by health care activities, in order to protect the subject of overdiagnosis and overtreatment; offering also ethical and viable alternatives in which the balance of risks and benefits (based on the best evidences) respects the autonomy of the subject by properly informing and allowing him to decide among the best options he has; altogether in a process that contemplates a rational and equitable use of resources. In order to achieve this, reliable sources of information and a medical education not dependent on industries related to technology or pharmaceuticals, are vital; in conjuction with a medicine that restablishes the subject as its main and central interest.

  11. Turbulence and Cavitation Suppression by Quaternary Ammonium Salt Additives.

    Science.gov (United States)

    Naseri, Homa; Trickett, Kieran; Mitroglou, Nicholas; Karathanassis, Ioannis; Koukouvinis, Phoevos; Gavaises, Manolis; Barbour, Robert; Diamond, Dale; Rogers, Sarah E; Santini, Maurizio; Wang, Jin

    2018-05-16

    We identify the physical mechanism through which newly developed quaternary ammonium salt (QAS) deposit control additives (DCAs) affect the rheological properties of cavitating turbulent flows, resulting in an increase in the volumetric efficiency of clean injectors fuelled with diesel or biodiesel fuels. Quaternary ammonium surfactants with appropriate counterions can be very effective in reducing the turbulent drag in aqueous solutions, however, less is known about the effect of such surfactants in oil-based solvents or in cavitating flow conditions. Small-angle neutron scattering (SANS) investigations show that in traditional DCA fuel compositions only reverse spherical micelles form, whereas reverse cylindrical micelles are detected by blending the fuel with the QAS additive. Moreover, experiments utilising X-ray micro computed tomography (micro-CT) in nozzle replicas, quantify that in cavitation regions the liquid fraction is increased in the presence of the QAS additive. Furthermore, high-flux X-ray phase contrast imaging (XPCI) measurements identify a flow stabilization effect in the region of vortex cavitation by the QAS additive. The effect of the formation of cylindrical micelles is reproduced with computational fluid dynamics (CFD) simulations by including viscoelastic characteristics for the flow. It is demonstrated that viscoelasticity can reduce turbulence and suppress cavitation, and subsequently increase the injector's volumetric efficiency.

  12. Uplift of quaternary shorelines in eastern Patagonia: Darwin revisited

    Science.gov (United States)

    Pedoja, Kevin; Regard, Vincent; Husson, Laurent; Martinod, Joseph; Guillaume, Benjamin; Fucks, Enrique; Iglesias, Maximiliano; Weill, Pierre

    2011-04-01

    During his journey on the Beagle, Darwin observed the uniformity in the elevation of coastal Eastern Patagonia along more than 2000 km. More than one century later, the sequences of Quaternary shorelines of eastern Patagonia have been described and their deposits dated but not yet interpreted in terms of geodynamics. Consequently, we i) mapped the repartition of the Quaternary coastal sequences in Argentinean Patagonia, ii) secured accurate altitudes of shoreline angles associated with erosional morphologies (i.e. marine terraces and notches), iii) took into account previous chrono-stratigraphical interpretations in order to calculate mean uplift rates since ~ 440 ka (MIS 11) and proposed age ranges for the higher and older features (up to ~ 180 m), and iv) focused on the Last Interglacial Maximum terrace (MIS 5e) as the best constrained marine terrace (in terms of age and altitude) in order to use it as a tectonic benchmark to quantify uplift rates along the entire passive margin of Eastern South America. Our results show that the eastern Patagonia uplift is constant through time and twice the uplift of the rest of the South American margin. We suggest that the enhanced uplift along the eastern Patagonian coast that interested Darwin during his journey around South America on the Beagle could originate from the subduction of the Chile ridge and the associated dynamic uplift.

  13. Parabolic distribution of circumeastern Snake River Plain seismicity and latest Quaternary faulting: Migratory pattern and association with the Yellowstone hotspot

    Science.gov (United States)

    Anders, Mark H.; Geissman, John Wm.; Piety, Lucille A.; Sullivan, J. Timothy

    1989-02-01

    The Intermountain and Idaho seismic belts within Idaho, Wyoming, and Montana form an unusual parabolic pattern about the axis of the aseismic eastern Snake River Plain (SRP). This pattern is also reflected in the distribution of latest Quaternary normal faults. Several late Cenozoic normal faults that trend perpendicular to the axis of the eastern SRP extend from the aseismic region to the region of latest Quaternary faulting and seismicity. A study of the late Miocene to Holocene displacement history of one of these, the Grand Valley fault system in southeastern Idaho and western Wyoming, indicates that a locus of high displacement rates has migrated away from the eastern SRP to its present location in southern Star Valley in western Wyoming. In Swan Valley the studied area closest to the eastern SRP, isotopic ages, and paleomagnetic data for over 300 samples from 47 sites on well-exposed late Cenozoic volcanic rocks (the tuff of Spring Creek, the tuff of Heise, the Huckleberry Ridge tuff, the Pine Creek Basalt, and an older tuff thought to be the tuff of Cosgrove Road) are used to demonstrate differences in the displacement rate on the Grand Valley fault over the last ˜10 m.y. Tectonic tilts for these volcanic rocks are estimated by comparing the results of paleomagnetic analyses in Swan Valley to similar analyses of samples from undeformed volcanic rocks outside of Swan Valley. Basin geometry and tilt axes are established using seismic reflection profiles and field mapping. Combining these data with the tilt data makes it possible to calculate displacement rates during discrete temporal intervals. An average displacement rate of ˜1.8 mm/yr is calculated for the Grand Valley fault in Swan Valley between 4.4 and 2.0 Ma. In the subsequent 2.0-m.y. interval the rate dropped 2 orders of magnitude to ˜0.014 mm/yr; during the preceding 5.5-m.y. interval the displacement rate is ˜0.15 mm/yr, or about 1 order of magnitude less than the rate between 4.4 and 2.0 Ma

  14. Isotope chemistry of an extensively nitrate-contaminated urban aquifer

    Science.gov (United States)

    Kracht, O.; de Souza, L. C.; de Queiros, M. A.; Stegemann, C.; Hunziker, J.

    2003-04-01

    The supply of drinking water for the approximately 800.000 inhabitants of the city of Natal (Rio Grande do Norte, Brazil) is strongly dependent on the use of local groundwater from the Barreiras Aquifer. Over 70 % of the public production are served by a system of about 130 tubular wells, that are distributed all over the urban area. Yet, no groundwater protection zones have been declared. In addition, a comparable number of private wells also depend on the cities underground water resources. Depending on the local topography, the groundwater table is located several tens of meters below surface. Useable groundwater occurrences are bound to an up to hundred meters thick series of unconsolidated clastic sediments from the younger tertiary (Barreiras Formation), that is underlain by less permeable cretaceous carbonates. Natals topography is dominated by impressive quaternary dunes formations, that play an important role for the infiltration of rain as the only source of recharge for the local groundwater. During the last decades, an extensive and rapidly growing groundwater-contamination with up to over 100 mg/l nitrate was observed by the local authorities. Hydrochemical data indicate this deterioration to be due to a massive spill of sanitary effluents over septic pits, as only 20 % of the city is yet served by a sewer system. The isotopic composition of Natals groundwater shows only small variations, with an average δ18O value of -2,3 per mill and δ2H value of -10,5 per mill vs. SMOW. Its origin from recent local precipitation is revealed by a good correspondence with the annual weighted means for precipitation in Ceara Mirim (nearest GNIP station, situated 45 km NE of Natal). In contrast, a set of samples from different regional surface waters indicated a strong evaporation trend with systematic enrichment in the oxygen and hydrogen isotopic composition. Samples from 33 production wells with a wide variation of nitrate concentrations were investigated for their

  15. Monitoring Aquifer Depletion from Space: Case Studies from the Saharan and Arabian Aquifers

    Science.gov (United States)

    Ahmed, M.; Sultan, M.; Wahr, J. M.; Yan, E.

    2013-12-01

    Access to potable fresh water resources is a human right and a basic requirement for economic development in any society. In arid and semi-arid areas, the characterization and understanding of the geologic and hydrologic settings of, and the controlling factors affecting, these resources is gaining increasing importance due to the challenges posed by increasing population. In these areas, there is immense natural fossil fresh water resources stored in large extensive aquifers, the transboundary aquifers. Yet, natural phenomena (e.g., rainfall patterns and climate change) together with human-related factors (e.g., population growth, unsustainable over-exploitation, and pollution) are threatening the sustainability of these resources. In this study, we are developing and applying an integrated cost-effective approach to investigate the nature (i.e., natural and anthropogenic) and the controlling factors affecting the hydrologic settings of the Saharan (i.e., Nubian Sandstone Aquifer System [NSAS], Northwest Sahara Aquifer System [NWSA]) and Arabian (i.e., Arabian Peninsula Aquifer System [APAS]) aquifer systems. Analysis of the Gravity Recovery and Climate Experiment (GRACE)-derived Terrestrial Water Storage (TWS) inter-annual trends over the NSAS and the APAS revealed two areas of significant TWS depletions; the first correlated with the Dakhla Aquifer System (DAS) in the NSAS and second with the Saq Aquifer System (SAS) in the APAS. Annual depletion rates were estimated at 1.3 × 0.66 × 109 m3/yr and 6.95 × 0.68 × 109 m3/yr for DAS and SAS, respectively. Findings include (1) excessive groundwater extraction, not climatic changes, is responsible for the observed TWS depletions ;(2) the DAS could be consumed in 350 years if extraction rates continue to double every 50 years and the APAS available reserves could be consumed within 60-140 years at present extraction (7.08 × 109 m3/yr) and depletion rates; and (3) observed depletions over DAS and SAS and their

  16. San Pedro River Aquifer Binational Report

    Science.gov (United States)

    Callegary, James B.; Minjárez Sosa, Ismael; Tapia Villaseñor, Elia María; dos Santos, Placido; Monreal Saavedra, Rogelio; Grijalva Noriega, Franciso Javier; Huth, A. K.; Gray, Floyd; Scott, C. A.; Megdal, Sharon; Oroz Ramos, L. A.; Rangel Medina, Miguel; Leenhouts, James M.

    2016-01-01

    The United States and Mexico share waters in a number of hydrological basins and aquifers that cross the international boundary. Both countries recognize that, in a region of scarce water resources and expanding populations, a greater scientific understanding of these aquifer systems would be beneficial. In light of this, the Mexican and U.S. Principal Engineers of the International Boundary and Water Commission (IBWC) signed the “Joint Report of the Principal Engineers Regarding the Joint Cooperative Process United States-Mexico for the Transboundary Aquifer Assessment Program" on August 19, 2009 (IBWC-CILA, 2009). This IBWC “Joint Report” serves as the framework for U.S.-Mexico coordination and dialogue to implement transboundary aquifer studies. The document clarifies several details about the program such as background, roles, responsibilities, funding, relevance of the international water treaties, and the use of information collected or compiled as part of the program. In the document, it was agreed by the parties involved, which included the IBWC, the Mexican National Water Commission (CONAGUA), the U.S. Geological Survey (USGS), and the Universities of Arizona and Sonora, to study two priority binational aquifers, one in the San Pedro River basin and the other in the Santa Cruz River basin. This report focuses on the Binational San Pedro Basin (BSPB). Reasons for the focus on and interest in this aquifer include the fact that it is shared by the two countries, that the San Pedro River has an elevated ecological value because of the riparian ecosystem that it sustains, and that water resources are needed to sustain the river, existing communities, and continued development. This study describes the aquifer’s characteristics in its binational context; however, most of the scientific work has been undertaken for many years by each country without full knowledge of the conditions on the other side of the border. The general objective of this study is to

  17. Aquifer test to determine hydraulic properties of the Elm aquifer near Aberdeen, South Dakota

    Science.gov (United States)

    Schaap, Bryan D.

    2000-01-01

    The Elm aquifer, which consists of sandy and gravelly glacial-outwash deposits, is present in several counties in northeastern South Dakota. An aquifer test was conducted northeast of Aberdeen during the fall of 1999 to determine the hydraulic properties of the Elm aquifer in that area. An improved understanding of the properties of the aquifer will be useful in the possible development of the aquifer as a water resource. Historical water-level data indicate that the saturated thickness of the Elm aquifer can change considerably over time. From September 1977 through November 1985, water levels at three wells completed in the Elm aquifer near the aquifer test site varied by 5.1 ft, 9.50 ft, and 11.1 ft. From June 1982 through October 1999, water levels at five wells completed in the Elm aquifer near the aquifer test site varied by 8.7 ft, 11.4 ft, 13.2 ft, 13.8 ft, and 19.7 ft. The water levels during the fall of 1999 were among the highest on record, so the aquifer test was affected by portions of the aquifer being saturated that might not be saturated during drier times. The aquifer test was conducted using five existing wells that had been installed prior to this study. Well A, the pumped well, has an operating irrigation pump and is centrally located among the wells. Wells B, C, D, and E are about 70 ft, 1,390 ft, 2,200 ft, and 3,100 ft, respectively, in different directions from Well A. Using vented pressure transducers and programmable data loggers, water-level data were collected at the five wells prior to, during, and after the pumping, which started on November 19, 1999, and continued a little over 72 hours. Based on available drilling logs, the Elm aquifer near the test area was assumed to be unconfined. The Neuman (1974) method theoretical response curves that most closely match the observed water-level changes at Wells A and B were calculated using software (AQTESOLV for Windows Version 2.13-Professional) developed by Glenn M. Duffield of Hydro

  18. Source, variability, and transformation of nitrate in a regional karst aquifer: Edwards aquifer, central Texas

    Energy Technology Data Exchange (ETDEWEB)

    Musgrove, M., E-mail: mmusgrov@usgs.gov [U.S. Geological Survey, 1505 Ferguson Lane, Austin, TX 78754 (United States); Opsahl, S.P. [U.S. Geological Survey, 5563 DeZavala, Ste. 290, San Antonio, TX 78249 (United States); Mahler, B.J. [U.S. Geological Survey, 1505 Ferguson Lane, Austin, TX 78754 (United States); Herrington, C. [City of Austin Watershed Protection Department, Austin, TX 78704 (United States); Sample, T.L. [U.S. Geological Survey, 19241 David Memorial Dr., Ste. 180, Conroe, TX 77385 (United States); Banta, J.R. [U.S. Geological Survey, 5563 DeZavala, Ste. 290, San Antonio, TX 78249 (United States)

    2016-10-15

    Many karst regions are undergoing rapid population growth and expansion of urban land accompanied by increases in wastewater generation and changing patterns of nitrate (NO{sub 3}{sup −}) loading to surface and groundwater. We investigate variability and sources of NO{sub 3}{sup −} in a regional karst aquifer system, the Edwards aquifer of central Texas. Samples from streams recharging the aquifer, groundwater wells, and springs were collected during 2008–12 from the Barton Springs and San Antonio segments of the Edwards aquifer and analyzed for nitrogen (N) species concentrations and NO{sub 3}{sup −} stable isotopes (δ{sup 15}N and δ{sup 18}O). These data were augmented by historical data collected from 1937 to 2007. NO{sub 3}{sup −} concentrations and discharge data indicate that short-term variability (days to months) in groundwater NO{sub 3}{sup −} concentrations in the Barton Springs segment is controlled by occurrence of individual storms and multi-annual wet-dry cycles, whereas the lack of short-term variability in groundwater in the San Antonio segment indicates the dominance of transport along regional flow paths. In both segments, longer-term increases (years to decades) in NO{sub 3}{sup −} concentrations cannot be attributed to hydrologic conditions; rather, isotopic ratios and land-use change indicate that septic systems and land application of treated wastewater might be the source of increased loading of NO{sub 3}{sup −}. These results highlight the vulnerability of karst aquifers to NO{sub 3}{sup −} contamination from urban wastewater. An analysis of N-species loading in recharge and discharge for the Barton Springs segment during 2008–10 indicates an overall mass balance in total N, but recharge contains higher concentrations of organic N and lower concentrations of NO{sub 3}{sup −} than does discharge, consistent with nitrification of organic N within the aquifer and consumption of dissolved oxygen. This study demonstrates

  19. Source, variability, and transformation of nitrate in a regional karst aquifer: Edwards aquifer, central Texas

    International Nuclear Information System (INIS)

    Musgrove, M.; Opsahl, S.P.; Mahler, B.J.; Herrington, C.; Sample, T.L.; Banta, J.R.

    2016-01-01

    Many karst regions are undergoing rapid population growth and expansion of urban land accompanied by increases in wastewater generation and changing patterns of nitrate (NO 3 − ) loading to surface and groundwater. We investigate variability and sources of NO 3 − in a regional karst aquifer system, the Edwards aquifer of central Texas. Samples from streams recharging the aquifer, groundwater wells, and springs were collected during 2008–12 from the Barton Springs and San Antonio segments of the Edwards aquifer and analyzed for nitrogen (N) species concentrations and NO 3 − stable isotopes (δ 15 N and δ 18 O). These data were augmented by historical data collected from 1937 to 2007. NO 3 − concentrations and discharge data indicate that short-term variability (days to months) in groundwater NO 3 − concentrations in the Barton Springs segment is controlled by occurrence of individual storms and multi-annual wet-dry cycles, whereas the lack of short-term variability in groundwater in the San Antonio segment indicates the dominance of transport along regional flow paths. In both segments, longer-term increases (years to decades) in NO 3 − concentrations cannot be attributed to hydrologic conditions; rather, isotopic ratios and land-use change indicate that septic systems and land application of treated wastewater might be the source of increased loading of NO 3 − . These results highlight the vulnerability of karst aquifers to NO 3 − contamination from urban wastewater. An analysis of N-species loading in recharge and discharge for the Barton Springs segment during 2008–10 indicates an overall mass balance in total N, but recharge contains higher concentrations of organic N and lower concentrations of NO 3 − than does discharge, consistent with nitrification of organic N within the aquifer and consumption of dissolved oxygen. This study demonstrates that subaqueous nitrification of organic N in the aquifer, as opposed to in soils, might be a

  20. Aquifer thermal energy storage in Finland

    Energy Technology Data Exchange (ETDEWEB)

    Iihola, H; Ala-Peijari, T; Seppaenen, H

    1988-01-01

    The rapid changes and crises in the field of energy during the 1970s and 1980s have forced us to examine the use of energy more critically and to look for new ideas. Seasonal aquifer thermal energy storage (T < 100/sup 0/C) on a large scale is one of the grey areas which have not yet been extensively explored. However, projects are currently underway in a dozen countries. In Finland there have been three demonstration projects from 1974 to 1987. International co-operation under the auspices of the International Energy Agency, Annex VI, 'Environmental and Chemical Aspects of Thermal Energy Storage in Aquifers and Research and Development of Water Treatment Methods' started in 1987. The research being undertaken in 8 countries includes several elements fundamental to hydrochemistry and biochemistry.

  1. Study of Aquifer Thermal Energy Storage

    Science.gov (United States)

    Okuyama, Masaaki; Umemiya, Hiromichi; Shibuya, Ikuko; Haga, Eiji

    Yamagata University 'Aquifer Thermal Energy Storage (ATES)' is the experimental system which has been running since 1982. From the results for along terms of experiments, we obtain many important knowledge. This paper presents the accomplishments for 16 years and the characteristics of thermal energy storage in thermal energy storage well. The conclusions show as follows. 1)In recent years, the thermal recovery factor of warm energy storage well becomes almost constant at about 60%. 2) The thermal recovery factor of cool energy storage well increases gradually and becomes at about 15%. 3) Since the ferric colloidal dam is formed in aquifer, thermal recovery factor increase year after year. 4) Back wash can remove clogging for ferric colloidal dam. 5) The apparent thermal diffusivity decrease gradually due to ferric colloidal dam.

  2. The geological characteristics during the quaternary period around Japan island

    Energy Technology Data Exchange (ETDEWEB)

    Hagiwara, Shigeru [Chuo Kaihatsu Corp., Enterprises Promotion Bureau, Tokyo (Japan); Sakamoto, Yoshiaki; Ogawa, Hiromichi; Nakayama, Shinichi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    2002-11-01

    Radioactive wastes arising from radioisotope facilities and nuclear research facilities should be disposed of in the surface of the earth, the shallow underground, the adequate depth and the deep underground according to radioactivity concentrations, and should be managed during several hundreds years. The earth scientific phenomena observed in Japan island at present occurred continuously from the past, and the same phenomena at the future should occur in the similar factor. Therefore, for the purpose to get the fundamental data for the selection of disposal site, this report reviewed on the genesis and classification of the sediments, earth scientific phenomena observed in Japan island and the feature of each place (10 districts) concerning to the Quaternary period in the newest geological time unit. (author)

  3. Functionalizing aluminum substrata by quaternary ammonium for antifouling performances

    Science.gov (United States)

    He, Xiaoyan; Suo, Xinkun; Bai, Xiuqin; Yuan, Chengqing; Li, Hua

    2018-05-01

    Due to the great loss induced by biofouling, developing new strategies for combating biofouling has attracted extensive attention. Quaternary ammonium salts are potent cationic antimicrobials used in consumer products and their use for surface immobilization could create a contact-active antimicrobial layer. Here we report the facile preparation of a contact-active antifouling coating by tethering polyethyleneimine (PEI) onto flat/nanostructured aluminum surface by hydrogen bonding between PEI and AlOOH. Quaternized PEI (QPEI) is obtained through quaternization reactions. Biofouling testing suggests excellent antifouling performances of the samples by declining the adhesion of 95% Phaeodactylum tricornutum and 98% of Chlorella pyrenoidosa. The antifouling properties of PEI/QPEI are attributed predominately to their hydrophilic and antimicrobial nature. The technical route of PEI/QPEI surface grafting shows great potential for modifying marine infrastructures for enhanced antifouling performances.

  4. Controls on Cyclic Formation of Quaternary Early Diagenetic Dolomite

    Science.gov (United States)

    McCormack, J.; Bontognali, T. R. R.; Immenhauser, A.; Kwiecien, O.

    2018-04-01

    The origin of sedimentary dolomite and the factors that control its formation within the geological record remain speculative. In most models, dolomite formation is linked to evaporative conditions, high water temperature, increasing Mg/Ca ratio, increasing alkalinity, and high amounts of biomass. Here we challenge these archetypal views, by documenting a case example of Quaternary dolomite which formed in Lake Van at constantly low temperature (stress, resulting from reventilation of the water-sediment interface. Independently from the validity of this hypothesis, our results call for a reevaluation of the paleoenvironmental conditions often invoked for early diagenetic dolomite-rich intervals within sedimentary sequences and for caution when interpreting time series of subrecent lacustrine carbonates.

  5. Quaternary oxide halides of group 15 with zinc and cadmium

    International Nuclear Information System (INIS)

    Rueck, Nadia

    2014-01-01

    The present thesis ''Quaternary oxide halides of group 15 with zinc and cadmium'' deals with the chemical class of oxide halides, which contain d-block element cations and pnicogens. Over the past few years compounds containing pnicogene cations are intensively investigated. The reason for this is the free electron pair of the Pn"3"+ cation, which is responsible for some interesting properties. Free electron pairs do not only impact the spatial structure of molecules but also the properties of materials. The object of this work was the synthesis and characterization of compounds containing Pn"3"+ cations with free electron pairs. Due to the structure-determining effect of these free electron pairs and in combination with halides it is possible to synthesize compounds with low-dimensional structures like chains and layers. In these compounds the structure is separated into halophilic and chalcophilic sub-structures, which are held together only by weak Van der Waals forces.

  6. Antibacterial effect of composite resins containing quaternary ammonium polyethyleneimine nanoparticles

    International Nuclear Information System (INIS)

    Yudovin-Farber, Ira; Beyth, Nurit; Weiss, Ervin I.; Domb, Abraham J.

    2010-01-01

    Quaternary ammonium polyethyleneimine (QA-PEI)-based nanoparticles were synthesized by crosslinking with dibromopentane followed by N-alkylation with various alkyl halides and further N-methylation with methyl iodide. Insoluble pyridinium-type particles were prepared by suspension polymerization of 4-vinyl pyridine followed by N-alkylation with alkyl halides. Polyamine-based nanoparticles embedded in restorative composite resin at 1% w/w were tested for antibacterial activity against Streptococcus mutans using direct contact test. Activity analysis revealed that the alkyl chain length of the QA-PEI nanoparticles plays a significant role in antibacterial activity of the reagent. The most potent compound was octyl-alkylated QA-PEI embedded in restorative composite resin at 1% w/w that totally inhibited S. mutans growth in 3-month-aged samples. This data indicates that restorative composite resin with antibacterial properties can be produced by the incorporation of QA-PEI nanoparticles.

  7. Antibacterial effect of composite resins containing quaternary ammonium polyethyleneimine nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Yudovin-Farber, Ira [Hebrew University of Jerusalem, Department of Medicinal Chemistry and Natural Products, School of Pharmacy, Faculty of Medicine (Israel); Beyth, Nurit; Weiss, Ervin I. [Hebrew University of Jerusalem, Department of Prosthodontics, Faculty of Dentistry (Israel); Domb, Abraham J., E-mail: avid@ekmd.huji.ac.i [Hebrew University of Jerusalem, Department of Medicinal Chemistry and Natural Products, School of Pharmacy, Faculty of Medicine (Israel)

    2010-02-15

    Quaternary ammonium polyethyleneimine (QA-PEI)-based nanoparticles were synthesized by crosslinking with dibromopentane followed by N-alkylation with various alkyl halides and further N-methylation with methyl iodide. Insoluble pyridinium-type particles were prepared by suspension polymerization of 4-vinyl pyridine followed by N-alkylation with alkyl halides. Polyamine-based nanoparticles embedded in restorative composite resin at 1% w/w were tested for antibacterial activity against Streptococcus mutans using direct contact test. Activity analysis revealed that the alkyl chain length of the QA-PEI nanoparticles plays a significant role in antibacterial activity of the reagent. The most potent compound was octyl-alkylated QA-PEI embedded in restorative composite resin at 1% w/w that totally inhibited S. mutans growth in 3-month-aged samples. This data indicates that restorative composite resin with antibacterial properties can be produced by the incorporation of QA-PEI nanoparticles.

  8. Reconstructing Quaternary pedogenesis in a paleosol sequence in Hungary

    Energy Technology Data Exchange (ETDEWEB)

    Uveges, J.B.; Horvath, Z.; Micheli, E.; Mindszenty, A.; Nemeth, T. [Szent Istvan University, Godollo (Hungary). Dept. of Agricultural Chemistry & Soil Science

    2003-07-01

    In addition to conducting field observations, mineralogical, chemical, and micromorphological analyses, and scanning electron microscope studies were carried out to reconstruct soil forming processes in a paleosol profile sequence located in an open-cast lignite mine in North Central Hungary (Visonta, pediment of the Matra Mountains). Based on these investigations, several different, sometimes contradictory processes were identified: bioturbation on various scales, shrinking-swelling, leaching, CaCO{sub 3} and Fe-oxide precipitation, erosion, sedimentation, weathering, clay mineral transformation, clay illuviation, organic matter accumulations, reduction and oxidation, and frost action. Joint occurrence of these phenomena indicates environmental changes during the formation of the studied sequence. Many of these processes overlap and might have occurred several times. The presence of erosional surfaces makes it more difficult to establish the exact age of this complex formation. All observations suggest that sedimentation and soil formation on the Matra pediment were not continuous during the Quaternary Period

  9. Quaternary geophysical framework of the northeastern North Carolina coastal system

    Science.gov (United States)

    Thieler, E.R.; Foster, D.S.; Mallinson, D.M.; Himmelstoss, E.A.; McNinch, J.E.; List, J.H.; Hammar-Klose, E.S.

    2013-01-01

    The northeastern North Carolina coastal system, from False Cape, Virginia, to Cape Lookout, North Carolina, has been studied by a cooperative research program that mapped the Quaternary geologic framework of the estuaries, barrier islands, and inner continental shelf. This information provides a basis to understand the linkage between geologic framework, physical processes, and coastal evolution at time scales from storm events to millennia. The study area attracts significant tourism to its parks and beaches, contains a number of coastal communities, and supports a local fishing industry, all of which are impacted by coastal change. Knowledge derived from this research program can be used to mitigate hazards and facilitate effective management of this dynamic coastal system.

  10. Quaternary Prevention, an Answer of Family Doctors to Overmedicalization

    Directory of Open Access Journals (Sweden)

    Marc Jamoulle

    2015-02-01

    Full Text Available In response to the questioning of Health Policy and Management (HPAM by colleagues on the role of rank and file family physicians in the same journal, the author, a family physician in Belgium, is trying to highlight the complexity and depth of the work of his colleagues and their contribution to the understanding of the organization and economy of healthcare. It addresses, in particular, the management of health elements throughout the ongoing relationship of the family doctor with his/her patients. It shows how the three dimensions of prevention, clearly included in the daily work, are complemented with the fourth dimension, quaternary prevention or prevention of medicine itself, whose understanding could help to control the economic and human costs of healthcare.

  11. Late Quaternary climatic changes in the Ross Sea area, Antarctica

    International Nuclear Information System (INIS)

    Brambati, A.; Melis, R.; Quaia, T.; Salvi, G.

    2002-01-01

    Ten cores from the Ross Sea continental margin were investigated to detect Late Quaternary climatic changes. Two main climatic cycles over the last 300,000 yr (isotope stages 1-8) were recognised in cores from the continental slope, whereas minor fluctuations over the last 30,000 yr were found in cores from the continental shelf. The occurrence of calcareous taxa within the Last Glacial interval and their subsequent disappearance reveal a general raising of the CCD during the last climatic cycle. In addition, periodical trends of c. 400, c. 700, and c. 1400 yr determined on calcareous foraminifers from sediments of the Joides Basin, indicate fluctuations of the Ross Ice Shelf between 15 and 30 ka BP. (author). 24 refs., 5 figs

  12. Increasing freshwater recovery upon aquifer storage : A field and modelling study of dedicated aquifer storage and recovery configurations in brackish-saline aquifers

    NARCIS (Netherlands)

    Zuurbier, Koen

    2016-01-01

    The subsurface may provide opportunities for robust, effective, sustainable, and cost-efficient freshwater management solutions. For instance, via aquifer storage and recovery (ASR; Pyne, 2005): “the storage of water in a suitable aquifer through a well during times when water is available, and the

  13. Hydrochemistry and isotope geochemistry as management tools for groundwater resources in multilayer aquifers: A study case from the Po plain (Lomellina, South-Western Lombardy, Italy)

    Energy Technology Data Exchange (ETDEWEB)

    Pilla, G; Sacchi, E; Ciancetti, G; Braga, G [Dipartimento di Scienze della Terra, Universita di Pavia, Pavia (Italy); Zuppi, G M [Dipartimento di Scienze Ambientali, Universita Ca' Foscari di Venezia, Venice (Italy)

    2003-07-01

    Full text: The Po plain, located in Northern Italy, hosts a multi-layer alluvial aquifer of Quaternary age constituted by sands interbedded with clays. The plain supports most of the agricultural and industrial activities of Northern Italy, which are associated with groundwater pollution in the shallower portions of the aquifer. The increasing demand of water for industrial and domestic use has led to the exploitation of deeper layers of the aquifer, without a rational management of the resource. Only in the last decade, the government agencies have started a global evaluation of the quality standards of pumped groundwater, urged by the increasing need for clean water for domestic use. The task is particularly difficult because of missing or approximate well logs and the presence of multi-filter wells tapping in different aquifers. In this case the chemical and isotopic characterisation of groundwaters is the only reliable tool to reconstruct the geometry, the interconnections and the characteristics of the aquifers. This study, promoted by the local agency for groundwater management and protection (Amministrazione Provinciale di Pavia, settore tutela e valorizzazione ambientale - U.O.C. Acqua) focused on a limited portion of the Po plain, the Lomellina region, of approximately 900 km{sup 2}. The region is bound to the South by the Po river, to the East and West by the Sesia and the Ticino rivers respectively, and to the North by the administrative boundary. The study aimed at the hydrogeological, hydrochemical and isotopic characterisation of the aquifers, allowing to serve as basis for the correct management of the groundwater resource. A preliminary reconstruction of the hydrogeological asset of the Lomellina plain was performed through the analysis of the stratigraphic data from 102 municipal wells. On this basis, a shallow phreatic aquifer, reaching depths of about 50-60 m from the surface, and two groups of aquifers containing confined groundwater, were

  14. Understanding Uranium Behavior in a Reduced Aquifer

    Science.gov (United States)

    Janot, N.; Lezama-Pacheco, J. S.; Williams, K. H.; Bernier-Latmani, R.; Long, P. E.; Davis, J. A.; Fox, P. M.; Yang, L.; Giammar, D.; Cerrato, J. M.; Bargar, J.

    2012-12-01

    Uranium contamination of groundwater is a concern at several US Department of Energy sites, such Old Rifle, CO. Uranium transport in the environment is mainly controlled by its oxidation state, since oxidized U(VI) is relatively mobile, whereas U(IV) is relatively insoluble. Bio-remediation of contaminated aquifers aims at immobilizing uranium in a reduced form. Previous laboratory and field studies have shown that adding electron donor (lactate, acetate, ethanol) to groundwater stimulates the activity of metal- and sulfate-reducing bacteria, which promotes U(VI) reduction in contaminated aquifers. However, obtaining information on chemical and physical forms of U, Fe and S species for sediments biostimulated in the field, as well as kinetic parameters such as U(VI) reduction rate, is challenging due to the low concentration of uranium in the aquifers (typically bio-remediation experiment at the Old Rifle site, CO, from early iron-reducing conditions to the transition to sulfate-reducing conditions. Several in-well chromatographic columns packed with sediment were deployed and were sampled at different days after the start of bio-reduction. X-ray absorption spectroscopy and X-ray microscopy were used to obtain information on Fe, S and U speciation and distribution. Chemical extractions of the reduced sediments have also been performed, to determine the rate of Fe(II) and U(IV) accumulation.

  15. Carbon-14 measurements in aquifers with methane

    International Nuclear Information System (INIS)

    Barker, J.F.; Fritz, P.; Brown, R.M.

    1979-01-01

    A survey of various groundwater systems indicates that methane is a common trace constituent and occasionally a major carbon species in groundwaters. Thermocatalytic methane had delta 13 Csub(CH 4 )>-45 per mille and microbially produced or biogenic methane had delta 13 Csub(CH 4 ) 13 C values for the inorganic carbon. Thermocatalytic methane had no apparent effect on the inorganic carbon. Because methanogenesis seriously affects the carbon isotope geochemistry of groundwaters, the correction of raw 14 C ages of affected groundwaters must consider these effects. Conceptual models are developed which adjust the 14 C activity of the groundwater for the effects of methanogenesis and for the dilution of carbon present during infiltration by simple dissolution of rock carbonate. These preliminary models are applied to groundwaters from the Alliston sand aquifer where methanogenesis has affected most samples. In this system, methanogenic bacteria using organic matter present in the aquifer matrix as substrate have added inorganic carbon to the groundwater which has initiated further carbonate rock dissolution. These processes have diluted the inorganic carbon 14 C activity. The adjusted groundwater ages can be explained in terms of the complex hydrogeology of this aquifer, but also indicate that these conceptual models must be more rigorously tested to evaluate their appropriateness. (author)

  16. Ground-water pumpage in the Willamette lowland regional aquifer system, Oregon and Washington, 1990

    Science.gov (United States)

    Collins, Charles A.; Broad, Tyson M.

    1996-01-01

    Ground-water pumpage for 1990 was estimated for an area of about 5,700 square miles in northwestern Oregon and southwestern Washington as part of the Puget-Willamette Lowland Regional Aquifer System Analysis study. The estimated total ground-water pumpage in 1990 was about 340,000 acre-feet. Ground water in the study area is pumped mainly from Quaternary sediment; lesser amounts are withdrawn from Tertiary volcanic materials. Large parts of the area are used for agriculture, and about two and one-half times as much ground water was pumped for irrigation as for either public- supply or industrial needs. Estimates of ground- water pumpage for irrigation in the central part of the Willamette Valley were generated by using image-processing techniques and Landsat Thematic Mapper data. Field data and published reports were used to estimate pumpage for irrigation in other parts of the study area. Information on public- supply and industrial pumpage was collected from Federal, State, and private organizations and individuals.

  17. Hydrology of the shallow aquifer and uppermost semiconfined aquifer near El Paso, Texas

    Science.gov (United States)

    White, D.E.; Baker, E.T.; Sperka, Roger

    1997-01-01

    The availability of fresh ground water in El Paso and adjacent areas that is needed to meet increased demand for water supply concerns local, State, and Federal agencies. The Hueco bolson is the principal aquifer in the El Paso area. Starting in the early 1900s and continuing to the 1950s, most of the municipal and industrial water supply in El Paso was pumped from the Hueco bolson aquifer from wells in and near the Rio Grande Valley and the international border. The Rio Grande is the principal surface-water feature in the El Paso area, and a major source of recharge to the shallow aquifer (Rio Grande alluvium) within the study area is leakage of flow from the Rio Grande.

  18. Synthetic Strategies toward Natural Products Containing Contiguous Stereogenic Quaternary Carbon Atoms.

    Science.gov (United States)

    Büschleb, Martin; Dorich, Stéphane; Hanessian, Stephen; Tao, Daniel; Schenthal, Kyle B; Overman, Larry E

    2016-03-18

    Strategies for the total synthesis of complex natural products that contain two or more contiguous stereogenic quaternary carbon atoms in their intricate structures are reviewed with 12 representative examples. Emphasis has been put on methods to create quaternary carbon stereocenters, including syntheses of the same natural product by different groups, thereby showcasing the diversity of thought and individual creativity. A compendium of selected natural products containing two or more contiguous stereogenic quaternary carbon atoms and key reactions in their total or partial syntheses is provided in the Supporting Information. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Recharge and Aquifer Response: Manukan Island’s Aquifer, Sabah, Malaysia

    Directory of Open Access Journals (Sweden)

    Sarva Mangala Praveena

    2010-01-01

    Full Text Available Manukan Island is a small island located in North-West of Sabah, Malaysia was used as a case study area for numerical modeling of an aquifer response to recharge and pumping rates. The results in this study present the variations of recharge into the aquifer under the prediction simulations. The recharge rate increases the water level as indicated by hydraulic heads. This shows that it can alter groundwater of Manukan Island which has been suffering from an overexploration in its unconfined the aquifer. The increase in recharge rate (from 600 mm/year to 750 mm/year increases the water level indicated by hydraulic heads. A reduction in pumping rate (from 0.072 m3/day to 0.058 m3/day not only increases the amount of water levels in aquifer but also reduces the supply hence a deficit in supply. The increase in hydraulic heads depends on the percentage reduction of pumping and recharges rates. The well water has 1978.3 mg/L chloride with current pumping (0.072 m3/day and recharge rates (600 mm/year. However, with an increased of recharge rate and current pumping rate it has decreased about 1.13%. In addition, reduction in pumping rate made the chloride concentration decreased about 2.8%. In general, a reduction in pumping with an increase in recharge rate leads to a decreased in chloride concentrations within the vicinity of cone of depression. Next, to further develop the numerical model, the model should focus on climate change variables such as consequences of climate change are increase in air temperature, increase in sea surface temperature, and more extreme weather conditions. These parameters are considered critical parameters for climate change impact modeling in aquifers. The behavior of the aquifer and its sustainable pumping rate can be done by applying a computer modeling component.

  20. Characteristics of Southern California coastal aquifer systems

    Science.gov (United States)

    Edwards, B.D.; Hanson, R.T.; Reichard, E.G.; Johnson, T.A.

    2009-01-01

    Most groundwater produced within coastal Southern California occurs within three main types of siliciclastic basins: (1) deep (>600 m), elongate basins of the Transverse Ranges Physiographic Province, where basin axes and related fluvial systems strike parallel to tectonic structure, (2) deep (>6000 m), broad basins of the Los Angeles and Orange County coastal plains in the northern part of the Peninsular Ranges Physiographic Province, where fluvial systems cut across tectonic structure at high angles, and (3) shallow (75-350 m), relatively narrow fluvial valleys of the generally mountainous southern part of the Peninsular Ranges Physiographic Province in San Diego County. Groundwater pumped for agricultural, industrial, municipal, and private use from coastal aquifers within these basins increased with population growth since the mid-1850s. Despite a significant influx of imported water into the region in recent times, groundwater, although reduced as a component of total consumption, still constitutes a significant component of water supply. Historically, overdraft from the aquifers has caused land surface subsidence, flow between water basins with related migration of groundwater contaminants, as well as seawater intrusion into many shallow coastal aquifers. Although these effects have impacted water quality, most basins, particularly those with deeper aquifer systems, meet or exceed state and national primary and secondary drinking water standards. Municipalities, academicians, and local water and governmental agencies have studied the stratigraphy of these basins intensely since the early 1900s with the goals of understanding and better managing the important groundwater resource. Lack of a coordinated effort, due in part to jurisdictional issues, combined with the application of lithostratigraphic correlation techniques (based primarily on well cuttings coupled with limited borehole geophysics) have produced an often confusing, and occasionally conflicting

  1. Microbiological risks of recycling urban stormwater via aquifers.

    Science.gov (United States)

    Page, D; Gonzalez, D; Dillon, P

    2012-01-01

    With the release of the Australian Guidelines for Water Recycling: Managed Aquifer Recharge (MAR), aquifers are now being included as a treatment barrier when assessing risk of recycled water systems. A MAR research site recharging urban stormwater in a confined aquifer was used in conjunction with a Quantitative Microbial Risk Assessment to assess the microbial pathogen risk in the recovered water for different end uses. The assessment involved undertaking a detailed assessment of the treatment steps and exposure controls, including the aquifer, to achieve the microbial health-based targets.

  2. Restoration of Wadi Aquifers by Artificial Recharge with Treated Waste Water

    KAUST Repository

    Missimer, Thomas M.; Drewes, Jö rg E.; Amy, Gary L.; Maliva,, Robert G.; Keller, Stephanie

    2012-01-01

    , such as damage to sensitive nearshore marine environments and creation of high-salinity interior surface water areas. An investigation of the hydrogeology of wadi aquifers in Saudi Arabia revealed that these aquifers can be used to develop aquifer recharge

  3. Straddle-packer aquifer test analyses of the Snake River Plain aquifer at the Idaho National Engineering Laboratory

    International Nuclear Information System (INIS)

    Johnson, G.S.; Frederick, D.B.

    1997-01-01

    The State of Idaho INEL Oversight Program, with the University of Idaho, Idaho State University, Boise State University, and the Idaho Geologic Survey, used a straddle-packer system to investigate vertical variations in characteristics of the Snake River Plain aquifer at the Idaho National Engineering Laboratory in southeast Idaho. Sixteen single-well aquifer tests were conducted on.isolated intervals in three observation wells. Each of these wells has approximately 200 feet of open borehole below the water table, penetrating the E through G and I basalt flow groups and interbedded sediments of the Snake River Plain aquifer. The success of the aquifer tests was limited by the inability to induce measurable drawdown in several zones. Time-drawdown data from aquifer tests were matched to type curves for 8 of the 16 zones tested. A single aquifer test at the water table exhibited greater curvature than those at depth. The increased degree of curvature suggests an unconfined response and resulted in an estimate of specific yield of 0.03. Aquifer tests below the water table generally yielded time-drawdown graphs with a rapid initial response followed by constant drawdown throughout the duration of the tests; up to several hours in length. The rapid initial response implies that the aquifer responds as a confined system during brief pumping periods. The nearly constant drawdown suggests a secondary source of water, probably vertical flow from overlying and underlying aquifer layers. Three analytical models were applied for comparison to the conceptual model and to provide estimates of aquifer properties. This, Hantush-Jacob leaky aquifer, and the Moench double-porosity fractured rock models were fit to time-drawdown data. The leaky aquifer type curves of Hantush and Jacob generally provided the best match to observed drawdown. A specific capacity regression equation was also used to estimate hydraulic conductivity

  4. Hydrogeology and Aquifer Storage and Recovery Performance in the Upper Floridan Aquifer, Southern Florida

    Science.gov (United States)

    Reese, Ronald S.; Alvarez-Zarikian, Carlos A.

    2007-01-01

    Well construction, hydraulic well test, ambient water-quality, and cycle test data were inventoried and compiled for 30 aquifer storage and recovery facilities constructed in the Floridan aquifer system in southern Florida. Most of the facilities are operated by local municipalities or counties in coastal areas, but five sites are currently being evaluated as part of the Comprehensive Everglades Restoration Plan. The relative performance of all sites with adequate cycle test data was determined, and compared with four hydrogeologic and design factors that may affect recovery efficiency. Testing or operational cycles include recharge, storage, and recovery periods that each last days or months. Cycle test data calculations were made including the potable water (chloride concentration of less than 250 milligrams per liter) recovery efficiency per cycle, total recovery efficiency per cycle, and cumulative potable water recovery efficiencies for all of the cycles at each site. The potable water recovery efficiency is the percentage of the total amount of potable water recharged for each cycle that is recovered; potable water recovery efficiency calculations (per cycle and cumulative) were the primary measures used to evaluate site performance in this study. Total recovery efficiency, which is the percent recovery at the end of each cycle, however, can be substantially higher and is the performance measure normally used in the operation of water-treatment plants. The Upper Floridan aquifer of the Floridan aquifer system currently is being used, or planned for use, at 29 of the aquifer storage and recovery sites. The Upper Floridan aquifer is continuous throughout southern Florida, and its overlying confinement is generally good; however, the aquifer contains brackish to saline ground water that can greatly affect freshwater storage and recovery due to dispersive mixing within the aquifer. The hydrogeology of the Upper Floridan varies in southern Florida; confinement

  5. The use of O, H and Sr isotopes and carbamazepine to identify the origin of water bodies supplying a shallow alluvial aquifer

    Science.gov (United States)

    Sassine, Lara; Le Gal La Salle, Corinne; Lancelot, Joël; Verdoux, Patrick

    2014-05-01

    Alluvial aquifers are of great socio-economic importance in France since they supply 82% of drinking water production, though they reveal to be very vulnerable to pesticides and emerging organic contaminants. The aim of this work is to identify the origin of water bodies which contribute to the recharge of an alluvial aquifer for a better understanding of its hydrochemistry and transfer of contaminants therein. The study is based on an isotopic and geochemical tracers approach, including major elements, trace elements (Br, Sr),and isotopes (δ18O, δ2H, 87Sr/86Sr), as well as organic molecules. Indeed, organic molecules such as pharmaceutical compounds, more precisely carbamazepine and caffeine, have shown their use as indicators of surface water in groundwater. The study area is a partially-confined shallow alluvial aquifer, the so-called Vistrenque aquifer, located at 15 km from the Mediterranean Sea, in the Quaternary alluviums deposited by an ancient arm of the Rhône River, in Southern France. This aquifer constitutes a shallow alluvial layer in a NE-SW graben structure. It is situated between a karst aquifer in lower Cretaceous limestones, on the NW border, and the Costières Plateau, on the SE border, having a similar geology as the Vistrenque. The alluvial plain is crossed by a surface water network with the Vistre as the main stream, and a canal used for irrigation essentially, the BRL canal, which is fed by the Rhône River. δ18O and δ2H allowed to differentiate the BRL canal water, depleted in heavy isotopes (δ2H = -71.5o vs V-SMOW), and the more enriched local rainwater (δ2H = -35.5o vs V-SMOW). In the Vistre surface water a binary mixing were evidenced with the BRL canal water and the rainwater, as end members. Then, in the Vistrenque groundwater both the BRL and the Vistre contributions could be identified, as they still show contrasting signature with local recharge. This allows to highlight the surface water contribution to a heavily exploited

  6. Groundwater arsenic contamination from parts of the Ghaghara Basin, India: influence of fluvial geomorphology and Quaternary morphostratigraphy

    Science.gov (United States)

    Shah, Babar Ali

    2017-09-01

    A groundwater arsenic (As) distribution in Faizabad, Gonda, and Basti districts of Uttar Pradesh is shown in the entrenched channels and floodplains of the Ghaghara River. Tubewell water samples were analysed for As through flow injection hydride generation atomic absorption spectrometry (FI-HG-AAS) system. About 38, 61, and 42 % of tubewells in Faizabad, Gonda, and Basti districts, respectively, have As >10 µg/l (WHO guideline). Moreover, 15, 45, and 26 % of tubewells in Faizabad, Gonda, and Basti districts, respectively, have As above 50 µg/l. About 86, 69, and 35 % of tubewells in Faizabad, Gonda, and Basti districts, respectively, are from shallow depth (21-45 m), and it is worth noticing that 47 % As-contaminated (As >10 µg/l) tubewells in these three districts are located within the depth of 10-35 m in Holocene Newer Alluvium aquifers. The high content of As (7.11 mg/kg) is measured in suspended river sediments of the Ghaghara River. Most of the As-contaminated villages in the Ghaghara Basin are located close to abandoned or present meander channels and floodplains of the Ghaghara River. In contrast, tubewells in Faizabad, Ayodhya, and Nawabganj towns are As-safe because of their positions on the Pleistocene Older Alluvium upland surfaces. Quaternary geomorphology plays an important role in groundwater arsenic contamination in the Ghaghara Basin. The sources of groundwater arsenic are geogenic and perennial mountainous rivers in the Ghaghara Basin supplied high sediment loads. The arsenic in groundwater of Ghaghara Basin is getting released from associated sediments which were likely deposited from the Himalayas. The process of release of groundwater arsenic is reductive dissolution of iron hydroxides.

  7. Estimation of the groundwater resources of the bedrock aquifers at the Kettle Moraine Springs State Fish Hatchery, Sheboygan County, Wisconsin

    Science.gov (United States)

    Dunning, Charles; Feinstein, Daniel T.; Buchwald, Cheryl A.; Hunt, Randall J.; Haserodt, Megan J.

    2017-10-12

    Groundwater resources information was needed to understand regional aquifer systems and water available to wells and springs for rearing important Lake Michigan fish species at the Kettle Moraine Springs State Fish Hatchery in Sheboygan County, Wisconsin. As a basis for estimating the groundwater resources available, an existing groundwater-flow model was refined, and new groundwater-flow models were developed for the Kettle Moraine Springs State Fish Hatchery area using the U.S. Geological Survey (USGS) finite-difference code MODFLOW. This report describes the origin and construction of these groundwater-flow models and their use in testing conceptual models and simulating the hydrogeologic system.The study area is in the Eastern Ridges and Lowlands geographical province of Wisconsin, and the hatchery property is situated on the southeastern edge of the Kettle Moraine, a north-south trending topographic high of glacial origin. The bedrock units underlying the study area consist of Cambrian, Ordovician, and Silurian units of carbonate and siliciclastic lithology. In the Sheboygan County area, the sedimentary bedrock sequence reaches a thickness of as much as about 1,600 feet (ft).Two aquifer systems are present at the Kettle Moraine Springs State Fish Hatchery. A shallow system is made up of Silurian bedrock, consisting chiefly of dolomite, overlain by unconsolidated Quaternary-age glacial deposits. The glacial deposits of this aquifer system are the typical source of water to local springs, including the springs that have historically supplied the hatchery. The shallow aquifer system, therefore, consists of the unconsolidated glacial aquifer and the underlying bedrock Silurian aquifer. Most residential wells in the area draw from the Silurian aquifer. A deeper confined aquifer system is made up of Cambrian- and Ordovician-age bedrock units including sandstone formations. Because of its depth, very few wells are completed in the Cambrian-Ordovician aquifer system

  8. Planktonic foraminifera from a quaternary deep sea core from the southern Arabian Sea

    Digital Repository Service at National Institute of Oceanography (India)

    Naidu, P.D.; Rao, P.S.; Pattan, J.N.

    An investigation on planktonic foraminifera and calcium carbonate content of a box core collected at a depth of 2556 m from the southern part of the Arabian sea indicates faunal changes depicting Quaternary climatic fluctuations. Based on the study...

  9. Quaternary epitopes of α345(IV) collagen initiate Alport post-transplant anti-GBM nephritis

    DEFF Research Database (Denmark)

    Olaru, Florina; Luo, Wentian; Wang, Xu-Ping

    2013-01-01

    Alport post-transplant nephritis (APTN) is an aggressive form of anti-glomerular basement membrane disease that targets the allograft in transplanted patients with X-linked Alport syndrome. Alloantibodies develop against the NC1 domain of α5(IV) collagen, which occurs in normal kidneys, including...... of alloantibodies against allogeneic collagen IV. Some alloantibodies targeted alloepitopes within α5NC1 monomers, shared by α345NC1 and α1256NC1 hexamers. Other alloantibodies specifically targeted alloepitopes that depended on the quaternary structure of α345NC1 hexamers. In Col4a5-null mice, immunization...... with native forms of allogeneic collagen IV exclusively elicited antibodies to quaternary α345NC1 alloepitopes, whereas alloimmunogens lacking native quaternary structure elicited antibodies to shared α5NC1 alloepitopes. These results imply that quaternary epitopes within α345NC1 hexamers may initiate...

  10. Quaternary association in β-prism I fold plant lectins: Insights from X ...

    Indian Academy of Sciences (India)

    The importance of quaternary association in the structure and function of proteins .... a locally maintained PDB-FTP anonymous server at the. Bioinformatics ... TIP4P water model using the program genbox available in the GROMACS suite.

  11. Thermally Reduced Graphene Oxide Electrochemically Activated by Bis-Spiro Quaternary Alkyl Ammonium for Capacitors.

    Science.gov (United States)

    He, Tieshi; Meng, Xiangling; Nie, Junping; Tong, Yujin; Cai, Kedi

    2016-06-08

    Thermally reduced graphene oxide (RGO) electrochemically activated by a quaternary alkyl ammonium-based organic electrolytes/activated carbon (AC) electrode asymmetric capacitor is proposed. The electrochemical activation process includes adsorption of anions into the pores of AC in the positive electrode and the interlayer intercalation of cations into RGO in the negative electrode under high potential (4.0 V). The EA process of RGO by quaternary alkyl ammonium was investigated by X-ray diffraction and electrochemical measurements, and the effects of cation size and structure were extensively evaluated. Intercalation by quaternary alkyl ammonium demonstrates a small degree of expansion of the whole crystal lattice (d002) and a large degree of expansion of the partial crystal lattice (d002) of RGO. RGO electrochemically activated by bis-spiro quaternary alkyl ammonium in propylene carbonate/AC asymmetric capacitor exhibits good activated efficiency, high specific capacity, and stable cyclability.

  12. Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation.

    Science.gov (United States)

    Fearnley, A F; An, J; Jackson, M; Lindovska, P; Denton, R M

    2016-04-11

    We report a synthesis method for the construction of quaternary aryl phoshonium salts at ambient temperature. The regiospecific reaction involves the coupling of phosphines with aryl radicals derived from diaryliodonium salts under photoredox conditions.

  13. Synthesis and Characterization of Novel Ternary and Quaternary Alkali Metal Thiophosphates

    KAUST Repository

    Alahmary, Fatimah S.

    2014-01-01

    The ongoing development of nonlinear optical (NLO) crystals such as coherent mid-IR sources focuses on various classes of materials such as ternary and quaternary metal chalcophosphates. In case of thiophosphates, the connection between PS4

  14. Hydrogeology of the Cambrian-Ordovician aquifer system in the northern Midwest: B in Regional aquifer-system analysis

    Science.gov (United States)

    Young, H.L.; Siegel, D.I.

    1992-01-01

    The Cambrian-Ordovician aquifer system contains the most extensive and continuous aquifers in the northern Midwest of the United States. It is the source of water for many municipalities, industries, and rural water users. Since the beginning of ground-water development from the aquifer system in the late 1800's, hydraulic heads have declined hundreds of feet in the heavily pumped Chicago-Milwaukee area and somewhat less in other metropolitan areas. The U.S. Geological Survey has completed a regional assessment of this aquifer system within a 161,000-square-mile area encompassing northern Illinois, northwestern Indiana, Iowa, southeastern Minnesota, northern Missouri, and Wisconsin.

  15. Using hydraulic head, chloride and electrical conductivity data to distinguish between mountain-front and mountain-block recharge to basin aquifers

    Science.gov (United States)

    Bresciani, Etienne; Cranswick, Roger H.; Banks, Eddie W.; Batlle-Aguilar, Jordi; Cook, Peter G.; Batelaan, Okke

    2018-03-01

    Numerous basin aquifers in arid and semi-arid regions of the world derive a significant portion of their recharge from adjacent mountains. Such recharge can effectively occur through either stream infiltration in the mountain-front zone (mountain-front recharge, MFR) or subsurface flow from the mountain (mountain-block recharge, MBR). While a thorough understanding of recharge mechanisms is critical for conceptualizing and managing groundwater systems, distinguishing between MFR and MBR is difficult. We present an approach that uses hydraulic head, chloride and electrical conductivity (EC) data to distinguish between MFR and MBR. These variables are inexpensive to measure, and may be readily available from hydrogeological databases in many cases. Hydraulic heads can provide information on groundwater flow directions and stream-aquifer interactions, while chloride concentrations and EC values can be used to distinguish between different water sources if these have a distinct signature. Such information can provide evidence for the occurrence or absence of MFR and MBR. This approach is tested through application to the Adelaide Plains basin, South Australia. The recharge mechanisms of this basin have long been debated, in part due to difficulties in understanding the hydraulic role of faults. Both hydraulic head and chloride (equivalently, EC) data consistently suggest that streams are gaining in the adjacent Mount Lofty Ranges and losing when entering the basin. Moreover, the data indicate that not only the Quaternary aquifers but also the deeper Tertiary aquifers are recharged through MFR and not MBR. It is expected that this finding will have a significant impact on the management of water resources in the region. This study demonstrates the relevance of using hydraulic head, chloride and EC data to distinguish between MFR and MBR.

  16. Using hydraulic head, chloride and electrical conductivity data to distinguish between mountain-front and mountain-block recharge to basin aquifers

    Directory of Open Access Journals (Sweden)

    E. Bresciani

    2018-03-01

    Full Text Available Numerous basin aquifers in arid and semi-arid regions of the world derive a significant portion of their recharge from adjacent mountains. Such recharge can effectively occur through either stream infiltration in the mountain-front zone (mountain-front recharge, MFR or subsurface flow from the mountain (mountain-block recharge, MBR. While a thorough understanding of recharge mechanisms is critical for conceptualizing and managing groundwater systems, distinguishing between MFR and MBR is difficult. We present an approach that uses hydraulic head, chloride and electrical conductivity (EC data to distinguish between MFR and MBR. These variables are inexpensive to measure, and may be readily available from hydrogeological databases in many cases. Hydraulic heads can provide information on groundwater flow directions and stream–aquifer interactions, while chloride concentrations and EC values can be used to distinguish between different water sources if these have a distinct signature. Such information can provide evidence for the occurrence or absence of MFR and MBR. This approach is tested through application to the Adelaide Plains basin, South Australia. The recharge mechanisms of this basin have long been debated, in part due to difficulties in understanding the hydraulic role of faults. Both hydraulic head and chloride (equivalently, EC data consistently suggest that streams are gaining in the adjacent Mount Lofty Ranges and losing when entering the basin. Moreover, the data indicate that not only the Quaternary aquifers but also the deeper Tertiary aquifers are recharged through MFR and not MBR. It is expected that this finding will have a significant impact on the management of water resources in the region. This study demonstrates the relevance of using hydraulic head, chloride and EC data to distinguish between MFR and MBR.

  17. Synthesis of Main-Chain Chiral Quaternary Ammonium Polymers for Asymmetric Catalysis Using Quaternization Polymerization

    Directory of Open Access Journals (Sweden)

    Md. Masud Parvez

    2012-06-01

    Full Text Available Main-chain chiral quaternary ammonium polymers were successfully synthesized by the quaternization polymerization of cinchonidine dimer with dihalides. The polymerization occurred smoothly under optimized conditions to give novel type of main-chain chiral quaternary ammonium polymers. The catalytic activity of the polymeric chiral organocatalysts was investigated on the asymmetric benzylation of N-(diphenylmethylideneglycine tert-butyl ester.

  18. Quaternary Alkylammonium Conjugates of Steroids: Synthesis, Molecular Structure, and Biological Studies

    Directory of Open Access Journals (Sweden)

    Bogumił Brycki

    2015-11-01

    Full Text Available The methods of synthesis as well as physical, spectroscopic (1H-NMR, 13C-NMR, and FT-IR, ESI-MS, and biological properties of quaternary and dimeric quaternary alkylammonium conjugates of steroids are presented. The results were contrasted with theoretical calculations (PM5 methods and potential pharmacological properties (PASS. Alkylammonium sterols exhibit a broad spectrum of antimicrobial activity comparable to squalamine.

  19. The pragmatic roots of American Quaternary geology and geomorphology

    Science.gov (United States)

    Baker, Victor R.

    1996-07-01

    H.L. Fairchild's words from the 1904 Geological Society of America Bulletin remain appropriate today: "Geologists have been too generous in allowing other people to make their philosophy for them". Geologists have quietly followed a methodological trinity involving (1) inspiration by analogy, (2) impartial and critical assessment of hypotheses, and (3) skepticism of authority (prevailing theoretical constraints or paradigms). These methods are described in classical papers by Quaternary geologists and geomorphologists, mostly written a century ago. In recent years these papers have all been criticized in modern philosophical terms with little appreciation for the late 19th century American philosophical tradition from which they arose. Recent scholarly research, however, has revealed some important aspects of that tradition, giving it a coherence that has largely been underappreciated as 20th century philosophy of science pursued its successive fads of logical positivism, critical rationalism, relativism, and deconstructivism — for all of which "science" is synonymous with "physics". Nearly all this ideology is geologically irrelevant. As philosophy of science in the late 20th century has come to be identical with philosophy of analytical physics, focused on explanations via ideal truths, much of geology has remained true to its classical doctrines of commonsensism, fallibilism, and realism. In contrast to the conceptualism and the reductionism of the analytical sciences, geology has emphasized synthetic thinking: the continuous activity of comparing, connecting, and putting together thoughts and perceptions. The classical methodological studies of geological reasoning all concern the formulation and testing of hypotheses. Analysis does not serve to provide the ultimate answers for intellectual puzzles predefined by limiting assumptions imposed on the real world. Rather, analysis in geology allows the investigator to consider the consequential effects of

  20. WTAQ - A computer program for aquifer-test analysis of confined and unconfined aquifers

    Science.gov (United States)

    Barlow, P.M.; Moench, A.F.

    2004-01-01

    Computer program WTAQ was developed to implement a Laplace-transform analytical solution for axial-symmetric flow to a partially penetrating, finite-diameter well in a homogeneous and anisotropic unconfined (water-table) aquifer. The solution accounts for wellbore storage and skin effects at the pumped well, delayed response at an observation well, and delayed or instantaneous drainage from the unsaturated zone. For the particular case of zero drainage from the unsaturated zone, the solution simplifies to that of axial-symmetric flow in a confined aquifer. WTAQ calculates theoretical time-drawdown curves for the pumped well and observation wells and piezometers. The theoretical curves are used with measured time-drawdown data to estimate hydraulic parameters of confined or unconfined aquifers by graphical type-curve methods or by automatic parameter-estimation methods. Parameters that can be estimated are horizontal and vertical hydraulic conductivity, specific storage, and specific yield. A sample application illustrates use of WTAQ for estimating hydraulic parameters of a hypothetical, unconfined aquifer by type-curve methods. Copyright ASCE 2004.

  1. Quaternary structure and spin state of human fetal methemoglobin

    International Nuclear Information System (INIS)

    Chevion, M.; Navok, T.; Ilan, Y.A.; Czapski, G.

    1981-01-01

    Using the pulse-radiolysis technique, solutions of fetal human methemoglobin were irradiated in order to reduce a single heme-iron within the protein tetramers. The valence-hybrids thus formed ere reacted wjth oxygen. Kinetics of the reactions were studied. The effects of p and inositol-hexaphosphate (IHP) were examined. The kinetics of the ligation of oxygen to stripped valence-hybrids showed a single-phase behaviour at the pH range 7-9. As the pH was lowered below 6.5, a second slower phase became apparent. This slow phase consisted of approximately 50% at pH 5.8. In the presence of IHP above pH 7.4, the kinetics of oxygen-binding was of a single-phase. As the pH was lowered a transition to a second, slower phase was noticed. Below pH 7 the slower phase was the only detectable one. The analysis of the relative contribution of the faster phase to the total reaction, as a function of the pH, showed a typical sigmoidal transition curve characterized by a pK = 7.2 and a Hill parameter n = 3.06. On this basis it is concluded that stripped, fetal human methemoglobin resides in an R quaternary structure while the presence of IHP stabilizes the T structure at pH below 7.2. The switch between the high spin aquomet- and the low spin hydroxymet-derivatives of adult and fetal human hemoglobins was studied optically in detail. These switches were found to be only slightly affected by IHP, and exhibited very low cooperativity (pK = 8.04; n = 1.1 and pK = 8.10; n = 1.3 for adult methemoglobin when stripped and in the presence of IHP, respectively; pK = 8.18; n = 1.11 and pK = 8.21; n = 1.28 for fetal methemoglobin when stripped and in the presence of IHP, respectively). These findings lead to the conclusion that the transition between quaternary structures in either human or fetal methemoglobins is not coupled to the switch of the spin state of the ferric heme. (author)

  2. Sequential character of low-energy ternary and quaternary nuclear fission

    Energy Technology Data Exchange (ETDEWEB)

    Kadmensky, S. G., E-mail: kadmensky@phys.vsu.ru; Bulychev, A. O. [Voronezh State University (Russian Federation)

    2016-09-15

    An analysis of low-energy true ternary (quaternary) nuclear fission leads to the conclusion that these fission modes have a sequential two-step (three-step) character such that the emission of a third particle (third and fourth particles) and the separation of fission fragments occur at distinctly different instants, in contrast to the simultaneous emergence of all fission products in the case of onestep ternary (quaternary) fission. This conclusion relies on the following arguments. First, the emission of a third particle (third and fourth particles) from a fissile nucleus is due to a nonevaporative mechanism associated with a nonadiabatic character of the collective deformation motion of this nucleus at the stages preceding its scission. Second, the axial symmetry of the deformed fissile compound nucleus and the direction of its symmetry axis both remain unchanged at all stages of ternary (quaternary) fission. This circumstancemakes it possible to explain themechanism of the appearance of observed anisotropies and T — odd asymmeries in the angular distributions of products of ternary (quaternary) nuclear fission. Third, the T —odd asymmetry discovered experimentally in ternary nuclear fission induced by cold polarized neutrons obeys the T —invariance condition only in the case of a sequential two-step (three-step) character of true ternary (quaternary) nuclear fission. At the same time, this asymmetry is not a T —invariant quantity in the case of the simultaneous emission of products of true ternary (quaternary) nuclear fission from the fissile compound nucleus.

  3. Sequential character of low-energy ternary and quaternary nuclear fission

    International Nuclear Information System (INIS)

    Kadmensky, S. G.; Bulychev, A. O.

    2016-01-01

    An analysis of low-energy true ternary (quaternary) nuclear fission leads to the conclusion that these fission modes have a sequential two-step (three-step) character such that the emission of a third particle (third and fourth particles) and the separation of fission fragments occur at distinctly different instants, in contrast to the simultaneous emergence of all fission products in the case of onestep ternary (quaternary) fission. This conclusion relies on the following arguments. First, the emission of a third particle (third and fourth particles) from a fissile nucleus is due to a nonevaporative mechanism associated with a nonadiabatic character of the collective deformation motion of this nucleus at the stages preceding its scission. Second, the axial symmetry of the deformed fissile compound nucleus and the direction of its symmetry axis both remain unchanged at all stages of ternary (quaternary) fission. This circumstancemakes it possible to explain themechanism of the appearance of observed anisotropies and T — odd asymmeries in the angular distributions of products of ternary (quaternary) nuclear fission. Third, the T —odd asymmetry discovered experimentally in ternary nuclear fission induced by cold polarized neutrons obeys the T —invariance condition only in the case of a sequential two-step (three-step) character of true ternary (quaternary) nuclear fission. At the same time, this asymmetry is not a T —invariant quantity in the case of the simultaneous emission of products of true ternary (quaternary) nuclear fission from the fissile compound nucleus.

  4. Source, variability, and transformation of nitrate in a regional karst aquifer: Edwards aquifer, central Texas.

    Science.gov (United States)

    Musgrove, MaryLynn; Opsahl, Stephen P.; Mahler, Barbara J.; Herrington, Chris; Sample, Thomas; Banta, John

    2016-01-01

    Many karst regions are undergoing rapid population growth and expansion of urban land accompanied by increases in wastewater generation and changing patterns of nitrate (NO3−) loading to surface and groundwater. We investigate variability and sources of NO3− in a regional karst aquifer system, the Edwards aquifer of central Texas. Samples from streams recharging the aquifer, groundwater wells, and springs were collected during 2008–12 from the Barton Springs and San Antonio segments of the Edwards aquifer and analyzed for nitrogen (N) species concentrations and NO3− stable isotopes (δ15N and δ18O). These data were augmented by historical data collected from 1937 to 2007. NO3− concentrations and discharge data indicate that short-term variability (days to months) in groundwater NO3− concentrations in the Barton Springs segment is controlled by occurrence of individual storms and multi-annual wet-dry cycles, whereas the lack of short-term variability in groundwater in the San Antonio segment indicates the dominance of transport along regional flow paths. In both segments, longer-term increases (years to decades) in NO3− concentrations cannot be attributed to hydrologic conditions; rather, isotopic ratios and land-use change indicate that septic systems and land application of treated wastewater might be the source of increased loading of NO3−. These results highlight the vulnerability of karst aquifers to NO3− contamination from urban wastewater. An analysis of N-species loading in recharge and discharge for the Barton Springs segment during 2008–10 indicates an overall mass balance in total N, but recharge contains higher concentrations of organic N and lower concentrations of NO3−than does discharge, consistent with nitrification of organic N within the aquifer and consumption of dissolved oxygen. This study demonstrates that subaqueous nitrification of organic N in the aquifer, as opposed to in soils, might be a previously

  5. Aquifer thermal energy (heat and chill) storage

    Energy Technology Data Exchange (ETDEWEB)

    Jenne, E.A. (ed.)

    1992-11-01

    As part of the 1992 Intersociety Conversion Engineering Conference, held in San Diego, California, August 3--7, 1992, the Seasonal Thermal Energy Storage Program coordinated five sessions dealing specifically with aquifer thermal energy storage technologies (ATES). Researchers from Sweden, The Netherlands, Germany, Switzerland, Denmark, Canada, and the United States presented papers on a variety of ATES related topics. With special permission from the Society of Automotive Engineers, host society for the 1992 IECEC, these papers are being republished here as a standalone summary of ATES technology status. Individual papers are indexed separately.

  6. The detection of boundaries in leaky aquifers

    International Nuclear Information System (INIS)

    Cook, A.J.

    1989-01-01

    Geological faults in sedimentary basins can affect the regional and local groundwater flow patterns by virtue of their enhanced permeability properties. Faults can be regarded as vertical flow boundaries and potentially important routes for radionuclide migration from a theoretical radioactive waste repository. This report investigates the hydraulic testing methods currently available which may be used to locate vertical hydraulic discontinuities (boundaries) within an aquifer. It aims to define the theoretical limitations to boundary detection by a single pumping test, to determine the optimum design of a pumping test for locating boundaries, and to define the practical limitations to boundary detection by a pumping test. (author)

  7. Geopressured-geothermal aquifers. Final contract report

    Energy Technology Data Exchange (ETDEWEB)

    1983-08-01

    Task 1 is to provide petrophysical and reservoir analysis of wells drilled into geopressured-geothermal aquifers containing dissolved methane. The list of Design Wells and Wells of Opportunity analyzed: Fairfax Foster Sutter No. 2 (WOO), Pleasant Bayou No. 2 (Design), Amoco Fee No. 1 (Design), G.M. Koelemay No. 1 (WOO), Gladys McCall No. 1 (Design), P.R. Girouard No. 1 (WOO), and Crown Zellerbach No. 2 (WOO). Petrophysical and reservoir analysis of the above wells were performed based on availability of data. The analysis performed on each well, the assumptions made during simulation, and conclusions reached.

  8. Denitrification in the karstic Floridan Aquifer

    Science.gov (United States)

    Fork, M.; Albertin, A. R.; Heffernan, J. B.; Katz, B. G.; Cohen, M. J.

    2010-12-01

    Nitrate concentrations in the karstic Floridan Aquifer have increased dramatically over the past 50 years, owing to agricultural intensification and urbanization. Due to low concentrations of organic matter and moderately oxic conditions in the Floridan Aquifer, groundwater denitrification has been assumed to be negligible. In this study, we evaluate that assumption using both existing and new data describing dissolved gases (Ne, N2, O2, Ar) and NO3- concentration and isotopic composition (δ18O- and δ15N-NO3) in the aquifer’s artesian springs. For new data, we collected samples from 33 spring vents representing a gradient of both DO and NO3- concentrations in northern Florida and used Membrane Inlet Mass Spectrometry (MIMS) to directly measure dissolved N2 and Ar. We modeled the physical processes (recharge temperature, dissolution of excess air) driving super-saturation of N2 gas using Ne and Ar where data describing Ne were available. Ar concentrations were correlated closely with recharge temperature, which ranged from 15.7 - 22.2°C, while Ne was closely correlated with excess air, which ranged from 1.05 to 2.66 mg L-1 and averaged 1.83 mg L-1. Estimates of physical mechanisms allowed calculation of expected N2 concentrations that were compared to observed N2 concentrations. Where Ne data were unavailable, we assumed excess air equal to the empirical average. Overall, observed N2 exceeded expectations based on physical processes in 33 of 47 cases; average excess N2 was 0.48 mg L-1 across all sites. In addition, excess N2 was negatively correlated with DO (r2 = 0.46); springs with low DO (Aquifer. Low DOC concentrations indicate that alternative electron donors may fuel nitrate reduction. Scaling to regional estimates of N2 production based on springs discharge and DO concentrations indicates that subsurface denitrification may account for some of the imbalance in springshed nutrient budgets. In addition, we conclude that use of δ15N-NO3- to diagnose

  9. SRP baseline hydrogeologic investigation: Aquifer characterization

    Energy Technology Data Exchange (ETDEWEB)

    Strom, R.N.; Kaback, D.S.

    1992-03-31

    An investigation of the mineralogy and chemistry of the principal hydrogeologic units and the geochemistry of the water in the principal aquifers at Savannah River Site (SRS) was undertaken as part of the Baseline Hydrogeologic Investigation. This investigation was conducted to provide background data for future site studies and reports and to provide a site-wide interpretation of the geology and geochemistry of the Coastal Plain Hydrostratigraphic province. Ground water samples were analyzed for major cations and anions, minor and trace elements, gross alpha and beta, tritium, stable isotopes of hydrogen, oxygen, and carbon, and carbon-14. Sediments from the well borings were analyzed for mineralogy and major and minor elements.

  10. The usefulness of multi-well aquifer tests in heterogeneous aquifers

    International Nuclear Information System (INIS)

    Young, S.C.; Benton, D.J.; Herweijer, J.C.; Sims, P.

    1990-01-01

    Three large-scale (100 m) and seven small-scale (3-7 m) multi-well aquifer tests were conducted in a heterogeneous aquifer to determine the transmissivity distribution across a one-hectare test site. Two of the large-scale tests had constant but different rates of discharge; the remaining large-scale test had a discharge that was pulsed at regulated intervals. The small-scale tests were conducted at two well clusters 20 m apart. The program WELTEST was written to analyze the data. By using the methods of non-linear least squares regression analysis and Broyden's method to solve for non-linear extrema, WELTEST automatically determines the best values of transmissivity and the storage coefficient. The test results show that order of magnitude differences in the calculated transmissivities at a well location can be realized by varying the discharge rate at the pumping well, the duration of the aquifer test, and/or the location of the pumping well. The calculated storage coefficients for the tests cover a five-order magnitude range. The data show a definite trend for the storage coefficient to increase with the distance between the pumping and the observation wells. This trend is shown to be related to the orientation of high hydraulic conductivity zones between the pumping and the observation wells. A comparison among single-well aquifer tests, geological investigations and multi-well aquifer tests indicate that the multi-well tests are poorly suited for characterizing a transmissivity field. (Author) (11 refs., 14 figs.)

  11. Bioremediation of a diesel fuel contaminated aquifer: simulation studies in laboratory aquifer columns

    Science.gov (United States)

    Hess, A.; Höhener, P.; Hunkeler, D.; Zeyer, J.

    1996-08-01

    The in situ bioremediation of aquifers contaminated with petroleum hydrocarbons is commonly based on the infiltration of groundwater supplemented with oxidants (e.g., O 2, NO 3-) and nutrients (e.g., NH 4+, PO 43-). These additions stimulate the microbial activity in the aquifer and several field studies describing the resulting processes have been published. However, due to the heterogeneity of the subsurface and due to the limited number of observation wells usually available, these field data do not offer a sufficient spatial and temporal resolution. In this study, flow-through columns of 47-cm length equipped with 17 sampling ports were filled with homogeneously contaminated aquifer material from a diesel fuel contaminated in situ bioremediation site. The columns were operated over 96 days at 12°C with artificial groundwater supplemented with O 2, NO 3- and PO 43-. Concentration profiles of O 2, NO 3-, NO 2-, dissolved inorganic and organic carbon (DIC and DOC, respectively), protein, microbial cells and total residual hydrocarbons were measured. Within the first 12 cm, corresponding to a mean groundwater residence time of < 3.6 h, a steep O 2 decrease from 4.6 to < 0.3 mg l -1, denitrification, a production of DIC and DOC, high microbial cell numbers and a high removal of hydrocarbons were observed. Within a distance of 24 to 40.5 cm from the infiltration, O 2 was below 0.1 mg l -1 and a denitrifying activity was found. In the presence and in the absence of O 2, n-alkanes were preferentially degraded compared to branched alkanes. The results demonstrate that: (1) infiltration of aerobic groundwater into columns filled with aquifer material contaminated with hydrocarbons leads to a rapid depletion of O 2; (2) O 2 and NO 3- can serve as oxidants for the mineralization of hydrocarbons; and (3) the modelling of redox processes in aquifers has to consider denitrifying activity in presence of O 2.

  12. Aquifers in coastal reclaimed lands - real world assessments

    Science.gov (United States)

    Saha, A.; Bironne, A.; Vonhögen-Peeters, L.; Lee, W. K.; Babovic, V. M.; Vermeulen, P.; van Baaren, E.; Karaoulis, M.; Blanchais, F.; Nguyen, M.; Pauw, P.; Doornenbal, P.

    2017-12-01

    Climate change and population growth are significant concerns in coastal regions around the world, where more than 30% of the world's population reside. The numbers continue to rise as coastal areas are increasingly urbanized. Urbanization creates land shortages along the coasts, which has spurred coastal reclamation activities as a viable solution. In this study, we focus on these reclamation areas; reclaimed areas in Singapore, and in the Netherlands, and investigate the potential of these reclaimed bodies as artificial aquifers that could attenuate water shortage problems in addition to their original purpose. We compare how the reclamation methods determine the hydrogeological characteristics of these manmade aquifers. We highlight similarities in freshwater lens development in the artificial shallow aquifers under natural recharge under diverse conditions, i.e. tropical and temperate zones, using numerical models. The characteristics and responses of these aquifers with dynamic freshwater-saltwater interface are contrasted against naturally occurring coastal aquifers where equilibrium was disturbed by anthropogenic activities. Finally, we assess the risks associated with subsidence and saltwater intrusion, combining measurements and numerical models, in case these aquifers are planned for Aquifer Storage and Recovery (ASR) or Managed Aquifer Recharge (MAR) strategies. Relative performances of some ASR schemes are simulated and compared in the reclaimed lands.

  13. Aquifer recharging in South Carolina: radiocarbon in environmental hydrogeology

    International Nuclear Information System (INIS)

    Stone, P.A.; Knox, R.L.; Mathews, T.D.

    1985-01-01

    Radiocarbon activities of dissolved inorganic carbon (and tritium activities where infiltration rates are rapid and aquifers shallow) provide relatively unambiguous and inexpensive evidence for identification of significant recharge areas. Such evidence is for the actual occurrence of modern recharge in the aquifer and thus is less inferential than stratigraphic or potentiometric evidence. These underutilized isotopic techniques are neither arcane nor complex and have been more-or-less standardized by earlier researchers. In South Carolina, isotopic evidence has been used from both calcareous and siliceous sedimentary aquifers and fractured crystalline rock aquifers. The Tertiary limestone aquifer is shown not to be principally recharged in its subcrop area, unlike conditions assumed for many other sedimentary aquifers in southeastern United States, and instead receives considerable lateral recharge from interfingering updip Tertiary sand aquifers in the middle coastal plain. Induced recharging at Hilton Head Island is mixing ancient relict water and modern recharge water. Recharging to deeper portions of the Cretaceous Middendorf basal sand aquifer occurs at least as far coastward as the middle coastal plain, near sampling sites that stratigraphically appear to be confined. Pronounced mineralization of water in fractured rocks cannot be considered as evidence of ancient or relict ground water that is isolated from modern contaminants, some of these waters contain considerable radiocarbon and hydrogen-bomb tritium

  14. Hydraulic properties from pumping tests data of aquifers in Azare ...

    African Journals Online (AJOL)

    Pumping test data from twelve boreholes in Azare area were analysed to determine the hydraulic properties of the aquifers, and the availability of water to meet the conjugate demands of the increasing population. The values of the aquifer constants obtained from the Cooper-Jacob's non-equilibrium graphical method were ...

  15. Estimating aquifer transmissivity from geo-electrical sounding ...

    African Journals Online (AJOL)

    Aquifer resistivity range from 4.26 ohm-m to 755.3 ohm-m with maximum thickness of 52.25m. A maximum 55.52m depth- tobasement was obtained in the study area. Based on the model obtained, aquifer Transmissivity was calculated and was used to delineate the study area into prospective low and high groundwater ...

  16. Hydrologic and isotopic study of the Quito aquifer

    International Nuclear Information System (INIS)

    Villalba, Fabio; Benalcazar, Julio; Garcia, Marco; Altamirano, Cesar; Altamirano, Homero; Sarasti, Santiago; Mancero, Maria; Leiva, Eduardo; Pino, Jose; Alulema, Rafael; Cedeno, Alberto; Burbano, Napoleon; Paquel, Efren; Becerra, Simon; Andrade, Graciela

    2000-10-01

    The dynamics of the Quito basin and surrounding area aquifers were determined through the use of stable and radioactive isotopes, and the monitoring of the freatic levels and of the bacteriological and physico-chemical quality of the water. A conceptual hydrodynamic model of the Quito aquifer was also proposed in order to establish in the future a sustainable management system

  17. Determining shallow aquifer vulnerability by the DRASTIC model ...

    Indian Academy of Sciences (India)

    Shallow aquifer vulnerability has been assessed using GIS-based DRASTIC model by incorporating the major geological and hydrogeological factors that affect and control the groundwater contamination in a granitic terrain. It provides a relative indication of aquifer vulnerability to the contamination. Further, it has been ...

  18. Hydrodynamical, hydrochemical and isotopic characterization of the Kourimat aquifer system (Essaouira basin, Morocco

    Directory of Open Access Journals (Sweden)

    Fernandes, P.

    2008-06-01

    Full Text Available The synclinal basin of Kourimat, subdivided in two sub-basins (Igounzar in the North, and Zeltene in the South, is situated in the oriental part of Essaouira basin shelters a carbonate aquifer system contained in the limestones and dolomitic limestones of the Cenomanian and the Turonian. These ground waters represent the only drinking water and irrigation resource for the region.The geological formations outcropping in the studied area, start with the clay and marly formations of the terminal Jurassic in the south of Zelten watershed, and end with the sandy and loamy Quaternary formations in coastal areas in the Low Qsob watershed. The Middle and Upper Cretaceous (marl, fractured limestone, and dolomites represent the rest of the stratigraphic series especially in the areas of the Igrounzar watershed (up to 85% of the outcrops and in Zelten (up to 50%.The field occupation is not very significant. It basically consists of three types: 1 cultures (essentially cereals where it is possible (on the marly soils of the Cretaceous, the Quaternary and the Eocene; 2 uncovered areas corresponding to the fissured and karstic limestone outcrops of the Cretaceous and the Jurassic formations, and 3 forests (coniferous trees in the downstream part of the catchments area (Plio-quaternary soils and mountainous reinforcements of the Western High Atlas. Like for other undeveloped areas of Morocco, the Meskala basin is also subjected to an intensive deforestation (wood for heating and cooking.The study undertaken on the Cenomano-turonian aquifer has allowed us to characterize it from the hydrodynamical, hydrogeological and hydrogeochemical point of view. The piezometric map of the two regrouped aquifer levels shows water flow senses from the SE to the NW. The hydraulic gradient varies from upstream to downstream, being weak n the central zone relative to the best hydrodynamic characteristics. The time evolution of the piezometry shows annual and seasonal

  19. Statistical Classification Of the Environmental Isotopes and the Hydrochemical data in the main Shallow Coastal Aquifer System in North West, Egypt

    International Nuclear Information System (INIS)

    Nada, A.A.; AL-Gamal, S.A.

    1999-01-01

    Multivariate statistical analysis of hydrochemical data and environmental isotopes were used in differentiating ground waters of different types within the quaternary aquifer in the north western coast of Egypt. Three main groups of water types were differentiated, in close agreement with three isotopic water groups, based on field and laboratory studies. The first group includes the sodium bicarbonate water type of meteoric origin (cluster 1 in multivariate analysis and isotopic water group 1) whereas, the second group includes both sodium chloride and sodium sulphate waters.(cluster in multivariate analysis and isotopic group 2). The third group represents ground water of salt water intrusion whose water type is sodium chloride (cluster 111 and isotopic water groups 3) .The data show that salinity ranges from 385 mg/L representing very fresh water to 12260 mg/L representing water contaminated with marine water due to excessive pumping in some Localities.

  20. Aquifer overexploitation: what does it mean?

    Science.gov (United States)

    Custodio, Emilio

    2002-02-01

    Groundwater overexploitation and aquifer overexploitation are terms that are becoming common in water-resources management. Hydrologists, managers and journalists use them when talking about stressed aquifers or some groundwater conflict. Overexploitation may be defined as the situation in which, for some years, average aquifer ion rate is greater than, or close to the average recharge rate. But rate and extent of recharge areas are often very uncertain. Besides, they may be modified by human activities and aquifer development. In practice, however, an aquifer is often considered as overexploited when some persistent negative results of aquifer development are felt or perceived, such as a continuous water-level drawdown, progressive water-quality deterioration, increase of ion cost, or ecological damage. But negative results do not necessarily imply that ion is greater than recharge. They may be simply due to well interferences and the long transient period that follow changes in the aquifer water balance. Groundwater storage is depleted to some extent during the transient period after ion is increased. Its duration depends on aquifer size, specific storage and permeability. Which level of "aquifer overexploitation" is advisable or bearable, depends on the detailed and updated consideration of aquifer-development effects and the measures implemented for correction. This should not be the result of applying general rules based on some indirect data. Monitoring, sound aquifer knowledge, and calculation or modelling of behaviour are needed in the framework of a set of objectives and policies. They should be established by a management institution, with the involvement of groundwater stakeholders, and take into account the environmental and social constraints. Aquifer overexploitation, which often is perceived to be associated with something ethically bad, is not necessarily detrimental if it is not permanent. It may be a step towards sustainable development. Actually

  1. Mucoadhesive nanoparticles made of thiolated quaternary chitosan crosslinked with hyaluronan.

    Science.gov (United States)

    Zambito, Ylenia; Felice, Francesca; Fabiano, Angela; Di Stefano, Rossella; Di Colo, Giacomo

    2013-01-30

    Mucoadhesive polymeric nanoparticles intended for drug transport across the gastrointestinal mucosa were prepared from quaternary ammonium-chitosan conjugates synthesised from reduced-MW chitosan (32 kDa). Conjugates contained pendant moieties of 2-4 adjacent diethyl-dimethylene-ammonium groups substituted on repeating units (26-55%). Conjugates were thiolated via amide bonds with thioglycolic acid to yield products with thiol content in the 35-87 μmol/g range. Nanoparticles with mean size in the 270-370 nm range and positive zeta-potential (+3.7 to +12.5 mV) resulted from ionotropic gelation of the thiolated conjugates with de-polymerised hyaluronic acid (470 kDa). The nanoparticles were fairly stable in size and thiol content and showed a significant mucoadhesivity, matching and even exceeding that of the constituent polymers. Nanoparticles were internalised by endothelial progenitor cells in direct relation to their surface charge intensity. Nanoparticle uptake significantly improved cell viability and resistance to oxidation. The lyophilised nanoparticles were re-dispersible and could make a manageable formulation for oral use. Copyright © 2012 Elsevier Ltd. All rights reserved.

  2. Quaternary glaciation of the Tashkurgan Valley, Southeast Pamir

    Science.gov (United States)

    Owen, Lewis A.; Chen, Jie; Hedrick, Kathyrn A.; Caffee, Marc W.; Robinson, Alexander C.; Schoenbohm, Lindsay M.; Yuan, Zhaode; Li, Wenqiao; Imrecke, Daniel B.; Liu, Jinfeng

    2012-07-01

    The Quaternary glacial history of Tashkurgan valley, in the transition between the Pamir and Karakoram, in Xinjiang Province, China was examined using remote sensing, field mapping, geomorphic analysis of landforms and sediments, and 10Be terrestrial cosmogenic nuclide dating. Moraines were assigned to four glacial stages: 1) the Dabudaer glacial stage that dates to the penultimate glacial cycle and/or earlier, and may represent one or more glaciations; 2) the Tashkurgan glacial stage that dates to early last glacial, most likely Marine Oxygen Isotope Stage (MIS) 4; 3) the Hangdi glacial stage that dates to MIS 2, possibly early MIS 2; and 4) the Kuzigun glacial stage that dates to the MIS 2, possibly the global Last Glacial Maximum, and is younger than the Hangdi glacial stage. Younger moraines and rock glaciers are present at the heads of tributary valleys; but these were inaccessible because they are located close to politically sensitive borders with Pakistan, Afghanistan and Tajikistan. Glaciers during the Dabudaer glacial stage advanced into the central part of the Tashkurgan valley. During the Tashkurgan glacial stages, glaciers advanced several kilometers beyond the mouths of the tributary valleys into the Tashkurgan valley. Glaciers during the Hangdi and Kuzigun glacial stages advanced just beyond the mouths of the tributary valleys. Glaciation in this part of the Himalayan-Tibetan orogen is likely strongly controlled by northern hemisphere climate oscillations, although a monsoonal influence on glaciation cannot be ruled out entirely.

  3. Antibacterial Activity of Dental Cements Containing Quaternary Ammonium Polyethylenimine Nanoparticles

    International Nuclear Information System (INIS)

    Beyth, N.; Weiss, E.I.; Pilo, R.

    2012-01-01

    Glass ionomer cements (GICs) are commonly used for cementing full cast crown restorations. Regrettably, although the dental cements fill the gap between the tooth and the crown, bacterial micro leakage may occur, resulting in secondary caries. As micro leakage cannot be completely prevented, GCS possessing antibacterial properties are in demand. In the present study the antibacterial activity of insoluble, cross-linked quaternary ammonium polyethylenimine (Qp) nanoparticles incorporated at 1% w/w in two clinically available GCS were studied. The antibacterial activity was tested against Streptococcus mutans and Lactobacillus casei using the direct contact test (Dct) and the agar diffusion test (Ad). Using the direct contact test, antibacterial activity (P<0.05) was found in both tested GICs with incorporated QPEI nanoparticles, the effect lasting for at least one month. However, the ADT showed no inhibition halo in the test bacteria, indicating that the antimicrobial nanoparticles do not diffuse into the agar. The results show that the incorporation of QPEI nanoparticles in glass ionomer cements has a long-lasting antibacterial effect against Streptococcus mutans and Lactobacillus casei. Changing the antibacterial properties of glass ionomer cements by incorporating QPEI antibacterial nanoparticles may prolong the clinical performance of dental crowns.

  4. Preliminary Groundwater Assessment using Electrical Method at Quaternary Deposits Area

    Science.gov (United States)

    Hazreek, Z. A. M.; Raqib, A. G. A.; Aziman, M.; Azhar, A. T. S.; Khaidir, A. T. M.; Fairus, Y. M.; Rosli, S.; Fakhrurrazi, I. M.; Izzaty, R. A.

    2017-08-01

    Alternative water sources using groundwater has increasingly demand in recent years. In the past, proper and systematic study of groundwater potential was varies due to several constraints. Conventionally, tube well point was drilled based on subjective judgment of several parties which may lead to the uncertainties of the project success. Hence, this study performed an electrical method to investigate the groundwater potential at quaternary deposits area particularly using resistivity and induced polarization technique. Electrical method was performed using ABEM SAS4000 equipment based on pole dipole array and 2.5 m electrode spacing. Resistivity raw data was analyzed using RES2DINV software. It was found that groundwater was able to be detected based on resistivity and chargeability values which varied at 10 - 100 Ωm and 0 - 1 ms respectively. Moreover, suitable location of tube well was able to be proposed which located at 80 m from the first survey electrode in west direction. Verification of both electrical results with established references has shown some good agreement thus able to convince the result reliability. Hence, the establishment of electrical method in preliminary groundwater assessment was able to assist several parties in term groundwater prospective at study area which efficient in term of cost, time, data coverage and sustainability.

  5. Electrochemical properties of quaternary ammonium salts for electrochemical capacitors

    Energy Technology Data Exchange (ETDEWEB)

    Ue, Makoto; Takeda, Masayuki; Takehara, Masahiro; Mori, Shoichiro [Mitsubishi Chemical Corp., Inashiki, Ibaraki (Japan). Tsukuba Research Center

    1997-08-01

    The limiting reduction and oxidation potentials and electrolytic conductivities of new quaternary ammonium salts were examined for electrochemical capacitor applications, whose anions have already been tested as lithium salts for lithium battery applications. The anodic stability was in the following order BR{sub 4}{sup {minus}} < ClO{sub 4}{sup {minus}} {le} CF{sub 3}SO{sub 3}{sup {minus}} < (CF{sub 3}SO{sub 2}){sub 2}N{sup {minus}} {le} C{sub 4}F{sub 9}SO{sub 3}{sup {minus}} < BF{sub 4}{sup {minus}} < PF{sub 6}{sup {minus}} {le} AsF{sub 6}{sup {minus}} < SbF{sub 6}{sup {minus}}. The electrolytic conductivities of Me{sub 4{minus}n}Et{sub n}N(CF{sub 3}SO{sub 2}){sub 2}N (n = 0--4) were examined in comparison with Me{sub 4{minus}n}Et{sub n}NBF{sub 4} counterparts. These imide salts showed good solubility, relatively high conductivity, and anodic stability in propylene carbonate. Et{sub 4}N(CF{sub 3}SO{sub 2}){sub 2}N was found to be a good supporting salt for low permittivity organic solvents, and it afforded a highly conductive electrolyte system based on the ethylene carbonate-dimethyl carbonate mixed solvent, which is useful for electrochemical capacitor applications.

  6. Radiolysis of simple quaternary ammonium salt components of Amberlite resin

    International Nuclear Information System (INIS)

    Dhiman, Surajdevprakash B.; LaVerne, Jay A.

    2013-01-01

    The radiation chemical yields of gaseous products, H 2 and CH 4 , in the radiolysis of dry methylammonium chloride, dimethylammonium chloride, trimethylammonium chloride, tetramethylammonium chloride and benzyl trimethylammonium chloride by γ-rays and 5 MeV helium ions have been investigated. Some of these amines are the different components of the quaternary ammonium resin Amberlite, which is a strongly basic anion exchange resin based on a polystyrene divinylbenzene copolymer. Molecular hydrogen yields with γ-radiolysis range from a high of 4.43 molecules per 100 eV for trimethylammonium chloride to 0.07 and 0.05 molecules per 100 eV for tetramethylammonium chloride and benzyl trimethylammonium chloride, respectively. Yields of methane gas are generally negligible except for trimethylammonium chloride and tetramethylammonium chloride, 0.26 and 0.02 molecules per 100 eV, respectively. Isotopic labeling studies suggest that the first step in H 2 production is the breakage of the N-H bond followed by abstraction of H · atom from the methyl groups. EPR analysis shows the formation of both N and C centered radicals. A comparison is made between the radiolysis of Amberlite and its various components

  7. U-series disequilibrium dating of Quaternary carbonates

    International Nuclear Information System (INIS)

    Stirling, C.

    2006-01-01

    One of the key dating methods used in paleoclimate research utilizes the natural radioactive decay of uranium to thorium in archives containing U-bearing minerals, such as the calcium carbonate forming the skeletons of fossil corals and speleothems. More specifically, this chronometer, commonly referred to as the U-series dating method, is based on the decay of 238 U to its longest-lived intermediate daughters, 234 U and 230 Th, and subsequent decay through to stable isotopes of Pb. It is the respective 250,000 and 75,000 year half-lives of these daughter isotopes, which make the U-series system particularly useful for dating Quaternary climate events spanning the last 600,000 years of Earth's history. The U-series thus bridges the gap between the ∼45,000 year upper limit of conventional radiocarbon dating and the ∼200,000 year lower limit of K-Ar and 40 Ar- 39 Ar dating. 2 refs., 5 figs

  8. Antibacterial Activity of Dental Cements Containing Quaternary Ammonium Polyethylenimine Nanoparticles

    Directory of Open Access Journals (Sweden)

    Nurit Beyth

    2012-01-01

    Full Text Available Glass ionomer cements (GICs are commonly used for cementing full cast crown restorations. Regrettably, although the dental cements fill the gap between the tooth and the crown, bacterial microleakage may occur, resulting in secondary caries. As microleakage cannot be completely prevented, GICs possessing antibacterial properties are in demand. In the present study the antibacterial activity of insoluble, cross-linked quaternary ammonium polyethylenimine (QPEI nanoparticles incorporated at 1% w/w in two clinically available GICs were studied. The antibacterial activity was tested against Streptococcus mutans and Lactobacillus casei using the direct contact test (DCT and the agar diffusion test (ADT. Using the direct contact test, antibacterial activity (<0.05 was found in both tested GICs with incorporated QPEI nanoparticles, the effect lasting for at least one month. However, the ADT showed no inhibition halo in the test bacteria, indicating that the antimicrobial nanoparticles do not diffuse into the agar. The results show that the incorporation of QPEI nanoparticles in glass ionomer cements has a long-lasting antibacterial effect against Streptococcus mutans and Lactobacillus casei. Changing the antibacterial properties of glass ionomer cements by incorporating QPEI antibacterial nanoparticles may prolong the clinical performance of dental crowns.

  9. Simple method for quick estimation of aquifer hydrogeological parameters

    Science.gov (United States)

    Ma, C.; Li, Y. Y.

    2017-08-01

    Development of simple and accurate methods to determine the aquifer hydrogeological parameters was of importance for groundwater resources assessment and management. Aiming at the present issue of estimating aquifer parameters based on some data of the unsteady pumping test, a fitting function of Theis well function was proposed using fitting optimization method and then a unitary linear regression equation was established. The aquifer parameters could be obtained by solving coefficients of the regression equation. The application of the proposed method was illustrated, using two published data sets. By the error statistics and analysis on the pumping drawdown, it showed that the method proposed in this paper yielded quick and accurate estimates of the aquifer parameters. The proposed method could reliably identify the aquifer parameters from long distance observed drawdowns and early drawdowns. It was hoped that the proposed method in this paper would be helpful for practicing hydrogeologists and hydrologists.

  10. Potentiometric Surface of the Alluvial Aquifer and Hydrologic Conditions in the Juana Diaz area, Puerto Rico, June 29 - July 1, 2005

    Science.gov (United States)

    Rodriguez, Jose M.; Santigo-Rivera, Luis; Gómez-Gómez, Fernando

    2006-01-01

    A synoptic survey of the hydrologic conditions in the Juana Diaz area, Puerto Rico, was conducted between June 29 and July 1, 2005, to define the spatial distribution of the potentiometric surface of the alluvial aquifer. The study area encompasses 21 square miles of the more extensive South Coastal Plain Alluvial Aquifer system and is bounded along the north by foothills of the Cordillera Central mountain chain, to the south by the Caribbean Sea, the east by the Rio Descalabrado and to the west by the Rio Inabon. Ground water in the Juana Diaz area is in the Quaternary-age alluvial deposits and the middle-Tertiary age Ponce Limestone and Juana Diaz Formation (Giusti, 1968). The hydraulic properties of the Ponce Limestone in the Juana Diaz area are unknown, and the Juana Diaz Formation is a unit of poor permeability due to its high clay content. Consequently, the Ponce Limestone and the Juana Diaz Formation are generally considered to be the base of the alluvial aquifer in the Juana Diaz area with ground-water flow occurring primarily within the alluvial deposits. The potentiometric-surface map of the alluvial aquifer was delineated using ground-water level measurements taken at existing wells. The water-level measurements were taken at wells that were either not pumping during the survey or were shut down for a brief period. In the latter case, a recovery period of 30 minutes was allowed for the drawdown in the wellbore to achieve a near static level position representative of the aquifer at the measurement point. Land-surface altitude from U.S. Geological Survey (USGS) 1:20,000 scale topographic maps (Playa de Ponce, Ponce, Rio Descalabrado, and Santa Isabel) were used to refer ground-water levels to mean sea level datum (National Geodetic Vertical Datum of 1929). In addition to the ground-water level measurements, the potentiometricsurface contours were delineated using hydrologic features, such as drainage ditches and saturated intermittent streams that were

  11. Modeling of CO2 storage in aquifers

    International Nuclear Information System (INIS)

    Savioli, Gabriela B; Santos, Juan E

    2011-01-01

    Storage of CO 2 in geological formations is a means of mitigating the greenhouse effect. Saline aquifers are a good alternative as storage sites due to their large volume and their common occurrence in nature. The first commercial CO 2 injection project is that of the Sleipner field in the Utsira Sand aquifer (North Sea). Nevertheless, very little was known about the effectiveness of CO 2 sequestration over very long periods of time. In this way, numerical modeling of CO 2 injection and seismic monitoring is an important tool to understand the behavior of CO 2 after injection and to make long term predictions in order to prevent CO 2 leaks from the storage into the atmosphere. The description of CO 2 injection into subsurface formations requires an accurate fluid-flow model. To simulate the simultaneous flow of brine and CO 2 we apply the Black-Oil formulation for two phase flow in porous media, which uses the PVT data as a simplified thermodynamic model. Seismic monitoring is modeled using Biot's equations of motion describing wave propagation in fluid-saturated poroviscoelastic solids. Numerical examples of CO 2 injection and time-lapse seismics using data of the Utsira formation show the capability of this methodology to monitor the migration and dispersal of CO 2 after injection.

  12. 14C measurements in aquifers with methane

    International Nuclear Information System (INIS)

    Barker, J.F.; Fritz, P.; Brown, R.M.

    1978-01-01

    A survey of various groundwater systems indicates that methane is a common trace constituent and occasionally a major carbon species in groundwaters. Thermocatalytic methane had delta 13 CCH 4 > -45% 0 and microbially-produced or biogenic methane had delta 13 CCH 4 0 . Groundwaters containing significant biogenic methane had abnormally heavy delta 13 C values for the inorganic carbon. Thermocatalytic methane had no apparent effect on the inorganic carbon. Because methanogenesis seriously affects the carbon isotope geochemistry of groundwaters, the correction of raw 14 C ages of affected groundwaters must consider these effects. Conceptual models are developed which adjust the 14 C activity of the groundwater for the effects of methanogenesis and for the dilution of carbon present during infiltration by simple dissolution of rock carbonate. These preliminary models are applied to groundwaters from the Alliston sand aquifer where methanogenesis has affected most samples. In this system, methanogenic bacteria using organic matter present in the aquifer matrix as substrate, have added inorganic carbon to the groundwater which has initiated further carbonate rock dissolution. These processes have diluted the inorganic carbon 14 C activity. (orig.) [de

  13. Groundwater arsenic contamination affecting different geologic domains in India--a review: influence of geological setting, fluvial geomorphology and Quaternary stratigraphy.

    Science.gov (United States)

    Acharyya, Subhrangsu K; Shah, Babar A

    2007-10-01

    Arsenic contamination in groundwater is pervasive within lowland organic-rich Bengal Delta and narrow entrenched channels in the Middle Ganga floodplains. Local areas of Damodar fan-delta and isolated areas within the Dongargarh Proterozoic rift-zone in central India are also contaminated. In this rift-zone, arsenic is enriched in felsic magmatic rocks and weathered rocks and soils from local areas are enriched further in arsenic and iron. Late Quaternary stratigraphy, geomorphology and sedimentation have influenced groundwater arsenic contamination in alluvium that aggraded during the Holocene sea-level rise. No specific source of arsenic could be identified, although Himalaya is the main provenance for the Ganga floodplain and the Bengal Delta. Gondwana coal seams and other Peninsular Indian rocks might be sources for arsenic in the Damodar fan-delta. As-bearing pyrite or any As-mineral is nearly absent in the aquifer sediments. Arsenic mainly occurs adsorbed on hydrated-iron-oxide (HFO), which coat sediment grains and minerals. Arsenic and iron are released to groundwater by bio-mediated reductive dissolution of HFO with corresponding oxidation of organic matter.

  14. Quaternary tectonic setting of South-Central coastal California

    Science.gov (United States)

    Lettis, William R.; Hanson, Kathryn L.; Unruh, Jeffrey R.; McLaren, Marcia; Savage, William U.; Keller, Margaret A.

    2004-01-01

    Recent geodetic, geologic, and seismologic studies show that the south-central coast of California is a region of active Quaternary deformation. Northeast-directed crustal shortening is occurring in a triangular-shaped region between the Hosgri-San Simeon fault system on the west, the Southern Coast Ranges on the northeast, and the western Transverse Ranges on the south. We informally call this region the Los Osos domain. In this study, we conducted detailed geological, seismological, and geophysical investigations to characterize the nature and rates of deformation in the domain. Locations of active and potentially active faults and folds are compiled at a scale of 1:250,000 for the entire domain based primarily on onshore geologic data and offshore geophysical data. Crustal shortening in the domain is accommodated by a series of prominent northwest-trending reverse faults and localized folding. The reverse faults separate distinct structural blocks that have little or no internal deformation. Hangingwall blocks are being uplifted at rates of up to 0.2 mm/yr. Footwall blocks are either static or slowly subsiding at rates of 0.1 mm/yr or less, except for localized areas of concentrated subsidence directly adjacent to some faults. The cumulative rate of crustal shortening is about 1 to 2 mm/yr across the northern part of the domain based on observed geologic deformation. Cumulative shortening across the central and southern parts of the domain is poorly constrained by geologic data and may approach 2 to 3 mm/yr. Historical and instrumental seismicity generally are spatially associated with the uplifted blocks and bordering reverse faults to depths of about 10 km. Together with near-surface geological data and deeper crustal geophysical imaging that show high-angle faulting, the seismicity data indicate that the reverse faults probably extend to the base of the seismogenic crust. The base of the seismogenic crust may correspond with a mid-crustal detachment or

  15. Equiatomic quaternary Heusler alloys: A material perspective for spintronic applications

    Energy Technology Data Exchange (ETDEWEB)

    Bainsla, Lakhan, E-mail: lakhanbainsla@gmail.com, E-mail: suresh@phy.iitb.ac.in; Suresh, K. G., E-mail: lakhanbainsla@gmail.com, E-mail: suresh@phy.iitb.ac.in [Magnetic Materials Lab, Department of Physics, Indian Institute of Technology Bombay, Mumbai 400076 (India)

    2016-09-15

    Half-metallic ferromagnetic (HMF) materials show high spin polarization and are therefore interesting to researchers due to their possible applications in spintronic devices. In these materials, while one spin sub band has a finite density of states at the Fermi level, the other sub band has a gap. Because of their high Curie temperature (T{sub C}) and tunable electronic structure, HMF Heusler alloys have a special importance among the HMF materials. Full Heusler alloys with the stoichiometric composition X{sub 2}YZ (where X and Y are the transition metals and Z is a sp element) have the cubic L2{sub 1} structure with four interpenetrating fcc sublattices. When each of these four fcc sublattices is occupied by different atoms (XX′YZ), a quaternary Heusler structure with different structural symmetries (space group F-43m, #216) is obtained. Recently, these equiatomic quaternary Heusler alloys (EQHAs) with 1:1:1:1 stoichiometry have attracted a lot of attention due to their superior magnetic and transport properties. A special class of HMF materials identified recently is known as spin gapless semiconductors (SGS). The difference in this case, compared with HMFs, is that the density of states for one spin band is just zero at the Fermi level, while the other has a gap as in the case of HMFs. Some of the reported SGS materials belong to EQHAs family. This review is dedicated to almost all reported materials belonging to EQHAs family. The electronic structure and hence the physical properties of Heusler alloys strongly depend on the degree of structural order and distribution of the atoms in the crystal lattice. A variety of experimental techniques has been used to probe the structural parameters and degree of order in these alloys. Their magnetic properties have been investigated using the conventional methods, while the spin polarization has been probed by point contact Andreev reflection technique. The experimentally obtained values of saturation magnetization are

  16. Pumping Test Determination of Unsaturated Aquifer Properties

    Science.gov (United States)

    Mishra, P. K.; Neuman, S. P.

    2008-12-01

    Tartakovsky and Neuman [2007] presented a new analytical solution for flow to a partially penetrating well pumping at a constant rate from a compressible unconfined aquifer considering the unsaturated zone. In their solution three-dimensional, axially symmetric unsaturated flow is described by a linearized version of Richards' equation in which both hydraulic conductivity and water content vary exponentially with incremental capillary pressure head relative to its air entry value, the latter defining the interface between the saturated and unsaturated zones. Both exponential functions are characterized by a common exponent k having the dimension of inverse length, or equivalently a dimensionless exponent kd=kb where b is initial saturated thickness. The authors used their solution to analyze drawdown data from a pumping test conducted by Moench et al. [2001] in a Glacial Outwash Deposit at Cape Cod, Massachusetts. Their analysis yielded estimates of horizontal and vertical saturated hydraulic conductivities, specific storage, specific yield and k . Recognizing that hydraulic conductivity and water content seldom vary identically with incremental capillary pressure head, as assumed by Tartakovsky and Neuman [2007], we note that k is at best an effective rather than a directly measurable soil parameter. We therefore ask to what extent does interpretation of a pumping test based on the Tartakovsky-Neuman solution allow estimating aquifer unsaturated parameters as described by more common constitutive water retention and relative hydraulic conductivity models such as those of Brooks and Corey [1964] or van Genuchten [1980] and Mualem [1976a]? We address this question by showing how may be used to estimate the capillary air entry pressure head k and the parameters of such constitutive models directly, without a need for inverse unsaturated numerical simulations of the kind described by Moench [2003]. To assess the validity of such direct estimates we use maximum

  17. Conduit enlargement in an eogenetic karst aquifer

    Science.gov (United States)

    Moore, Paul J.; Martin, Jonathan B.; Screaton, Elizabeth J.; Neuhoff, Philip S.

    2010-11-01

    SummaryMost concepts of conduit development have focused on telogenetic karst aquifers, where low matrix permeability focuses flow and dissolution along joints, fractures, and bedding planes. However, conduits also exist in eogenetic karst aquifers, despite high matrix permeability which accounts for a significant component of flow. This study investigates dissolution within a 6-km long conduit system in the eogenetic Upper Floridan aquifer of north-central Florida that begins with a continuous source of allogenic recharge at the Santa Fe River Sink and discharges from a first-magnitude spring at the Santa Fe River Rise. Three sources of water to the conduit include the allogenic recharge, diffuse recharge through epikarst, and mineralized water upwelling from depth. Results of sampling and inverse modeling using PHREEQC suggest that dissolution within the conduit is episodic, occurring only during 30% of 16 sampling times between March 2003 and April 2007. During low flow conditions, carbonate saturated water flows from the matrix to the conduit, restricting contact between undersaturated allogenic water with the conduit wall. When gradients reverse during high flow conditions, undersaturated allogenic recharge enters the matrix. During these limited periods, estimates of dissolution within the conduit suggest wall retreat averages about 4 × 10 -6 m/day, in agreement with upper estimates of maximum wall retreat for telogenetic karst. Because dissolution is episodic, time-averaged dissolution rates in the sink-rise system results in a wall retreat rate of about 7 × 10 -7 m/day, which is at the lower end of wall retreat for telogenetic karst. Because of the high permeability matrix, conduits in eogenetic karst thus enlarge not just at the walls of fractures or pre-existing conduits such as those in telogenetic karst, but also may produce a friable halo surrounding the conduits that may be removed by additional mechanical processes. These observations stress the

  18. CO2/Brine transport into shallow aquifers along fault zones.

    Science.gov (United States)

    Keating, Elizabeth H; Newell, Dennis L; Viswanathan, Hari; Carey, J W; Zyvoloski, G; Pawar, Rajesh

    2013-01-02

    Unintended release of CO(2) from carbon sequestration reservoirs poses a well-recognized risk to groundwater quality. Research has largely focused on in situ CO(2)-induced pH depression and subsequent trace metal mobilization. In this paper we focus on a second mechanism: upward intrusion of displaced brine or brackish-water into a shallow aquifer as a result of CO(2) injection. Studies of two natural analog sites provide insights into physical and chemical mechanisms controlling both brackish water and CO(2) intrusion into shallow aquifers along fault zones. At the Chimayó, New Mexico site, shallow groundwater near the fault is enriched in CO(2) and, in some places, salinity is significantly elevated. In contrast, at the Springerville, Arizona site CO(2) is leaking upward through brine aquifers but does not appear to be increasing salinity in the shallow aquifer. Using multiphase transport simulations we show conditions under which significant CO(2) can be transported through deep brine aquifers into shallow layers. Only a subset of these conditions favor entrainment of salinity into the shallow aquifer: high aspect-ratio leakage pathways and viscous coupling between the fluid phases. Recognition of the conditions under which salinity is favored to be cotransported with CO(2) into shallow aquifers will be important in environmental risk assessments.

  19. Groundwater level responses to precipitation variability in Mediterranean insular aquifers

    Science.gov (United States)

    Lorenzo-Lacruz, Jorge; Garcia, Celso; Morán-Tejeda, Enrique

    2017-09-01

    Groundwater is one of the largest and most important sources of fresh water on many regions under Mediterranean climate conditions, which are exposed to large precipitation variability that includes frequent meteorological drought episodes, and present high evapotranspiration rates and water demand during the dry season. The dependence on groundwater increases in those areas with predominant permeable lithologies, contributing to aquifer recharge and the abundance of ephemeral streams. The increasing pressure of tourism on water resources in many Mediterranean coastal areas, and uncertainty related to future precipitation and water availability, make it urgent to understand the spatio-temporal response of groundwater bodies to precipitation variability, if sustainable use of the resource is to be achieved. We present an assessment of the response of aquifers to precipitation variability based on correlations between the Standardized Precipitation Index (SPI) at various time scales and the Standardized Groundwater Index (SGI) across a Mediterranean island. We detected three main responses of aquifers to accumulated precipitation anomalies: (i) at short time scales of the SPI (24 months). The differing responses were mainly explained by differences in lithology and the percentage of highly permeable rock strata in the aquifer recharge areas. We also identified differences in the months and seasons when aquifer storages are more dependent on precipitation; these were related to climate seasonality and the degree of aquifer exploitation or underground water extraction. The recharge of some aquifers, especially in mountainous areas, is related to precipitation variability within a limited spatial extent, whereas for aquifers located in the plains, precipitation variability influence much larger areas; the topography and geological structure of the island explain these differences. Results indicate large spatial variability in the response of aquifers to precipitation in

  20. Managed aquifer recharge: rediscovering nature as a leading edge technology.

    Science.gov (United States)

    Dillon, P; Toze, S; Page, D; Vanderzalm, J; Bekele, E; Sidhu, J; Rinck-Pfeiffer, S

    2010-01-01

    Use of Managed Aquifer Recharge (MAR) has rapidly increased in Australia, USA, and Europe in recent years as an efficient means of recycling stormwater or treated sewage effluent for non-potable and indirect potable reuse in urban and rural areas. Yet aquifers have been relied on knowingly for water storage and unwittingly for water treatment for millennia. Hence if 'leading edge' is defined as 'the foremost part of a trend; a vanguard', it would be misleading to claim managed aquifer recharge as a leading edge technology. However it has taken a significant investment in scientific research in recent years to demonstrate the effectiveness of aquifers as sustainable treatment systems to enable managed aquifer recharge to be recognised along side engineered treatment systems in water recycling. It is a 'cross-over' technology that is applicable to water and wastewater treatment and makes use of passive low energy processes to spectacularly reduce the energy requirements for water supply. It is robust within limits, has low cost, is suitable from village to city scale supplies, and offers as yet almost untapped opportunities for producing safe drinking water supplies where they do not yet exist. It will have an increasingly valued role in securing water supplies to sustain cities affected by climate change and population growth. However it is not a universal panacea and relies on the presence of suitable aquifers and sources of water together with effective governance to ensure human health and environment protection and water resources planning and management. This paper describes managed aquifer recharge, illustrates its use in Australia, outlining economics, guidelines and policies, and presents some of the knowledge about aquifer treatment processes that are revealing the latent value of aquifers as urban water infrastructure and provide a driver to improving our understanding of urban hydrogeology.

  1. Modelling stream aquifer seepage in an alluvial aquifer: an improved loosing-stream package for MODFLOW

    Science.gov (United States)

    Osman, Yassin Z.; Bruen, Michael P.

    2002-07-01

    Seepage from a stream, which partially penetrates an unconfined alluvial aquifer, is studied for the case when the water table falls below the streambed level. Inadequacies are identified in current modelling approaches to this situation. A simple and improved method of incorporating such seepage into groundwater models is presented. This considers the effect on seepage flow of suction in the unsaturated part of the aquifer below a disconnected stream and allows for the variation of seepage with water table fluctuations. The suggested technique is incorporated into the saturated code MODFLOW and is tested by comparing its predictions with those of a widely used variably saturated model, SWMS_2D simulating water flow and solute transport in two-dimensional variably saturated media. Comparisons are made of both seepage flows and local mounding of the water table. The suggested technique compares very well with the results of variably saturated model simulations. Most currently used approaches are shown to underestimate the seepage and associated local water table mounding, sometimes substantially. The proposed method is simple, easy to implement and requires only a small amount of additional data about the aquifer hydraulic properties.

  2. Functioning of the Primary Aquifer Relating to the Maider Basin, Morocco: Case of the Ordovician aquifer.

    Science.gov (United States)

    Ben-said, E.; Boukdir, A.; Mahboub, A.; Younsi, A.; Zitouni, A.; Alili, L.; Ikhmerdi, H.

    2018-05-01

    The basin of Maider is limited northly by the vast ensemble Oriental Saghro-Ougnate, from the east by the Tafilalet plain, from the west by the oriental Jbel Bani, finally from the south and south-east by the Cretaceous Hamada of Kern-Kem. During last decades, groundwater in the basin of Maider, is confronting degradation in both cases: Quantitative and qualitative, as a result of the drought, the overexploitation and the salinization. The aim of this action research is to understand the current state of water resources in the area of stady. At the end of this work, we can get the following conclusions: the general flow of the ordovician aquifer is always directed from the north to the south-east of the basin by following the principal axes of the wadis:Taghbalt, Hssiya and Fezzou. The recharge of the aquifer is primarily done, either by the underground flow, or by the surface runoff of torrential waters from the upstream of Jbel Saghro. The piezometric anomaly noticed at the level of Ait Saàdane, explained by overexploitation linked to the needs of irrigation water. The physicochemical approach for the Maider basin identifies two essential factors of the salinisation of groundwater: the dissolution of the aquifer which is rich in minerals with high temperature on the one hand, and the decrease of the piezometric surface due to the overexploitation and drought on the other hand.

  3. Atomic-scale properties of Ni-based FCC ternary, and quaternary alloys

    International Nuclear Information System (INIS)

    Tamm, Artur; Aabloo, Alvo; Klintenberg, Mattias; Stocks, Malcolm; Caro, Alfredo

    2015-01-01

    The aim of this study is to characterize some atomic-scale properties of Ni-based FCC multicomponent alloys. For this purpose, we use Monte Carlo method combined with density functional theory calculations to study short-range order (SRO), atomic displacements, electronic density of states, and magnetic moments in equimolar ternary NiCrCo, and quaternary NiCrCoFe alloys. According to our study, the salient features for the ternary alloy are a negative SRO parameter between Ni–Cr and a positive between Cr–Cr pairs as well as a weakly magnetic state. For the quaternary alloy we predict negative SRO parameter for Ni–Cr and Ni–Fe pairs and positive for Cr–Cr and Fe–Fe pairs. Atomic displacements for both ternary and quaternary alloys are negligible. In contrast to the ternary, the quaternary alloy shows a complex magnetic structure. The electronic structure of the ternary and quaternary alloys shows differences near the Fermi energy between a random solid solution and the predicted structure with SRO. Despite that, the calculated EXAFS spectra does not show enough contrast to discriminate between random and ordered structures. The predicted SRO has an impact on point-defect energetics, electron–phonon coupling and thermodynamic functions and thus, SRO should not be neglected when studying properties of these two alloys

  4. The ichthyofauna of limnic systems in Quaternary deposits of extreme southern Brazil

    Directory of Open Access Journals (Sweden)

    Cindy Marques

    2016-12-01

    Full Text Available The Quaternary in the state of Rio Grande do Sul (RS, southern Brazil, is geologically represented by the coastal plain and was originated by successive events of Pleistocene-Holocene marine transgressions and the occurrence of alluvial deposits. This paper aimed to characterize the fish assemblage occurring in a swampy Quaternary area adjacent to Lagoa Pequena, a lacustrine system connected to the west margin of the Laguna dos Patos estuary. A checklist is also provided of the ichthyofauna so far recorded in limnic systems of Quaternary deposits in the state of Rio Grande do Sul. A total of 42 species was recorded, distributed in nine orders, 18 families and 31 genera. Characidae and Cichlidae were the most representative families, comprising 15 and 4 species respectively. A bibliographic revision associated to our sample data revealed the occurrence of 156 species in limnic systems inserted in RS Quaternary deposits (114 limnic, 15 marine/estuarine/limnic, ten marine/estuarine, nine estuarine/limnic and eight marine. Characiformes and Siluriformes are the most diverse orders, corroborating the Neotropical pattern. Seven species can be considered endemic to RS Quaternary deposits.

  5. Hydrologic time and sustainability of shallow aquifers

    Science.gov (United States)

    Back, William; ,

    1994-01-01

    Measurement of water and short intervals of time are coeval events that began about 6000 BC in Mesopotamia. Even though time and hydrology have been intimately entwined, with time terms in the denominator of many hydrologic parameters, hydrology's a priori claim to time has not been consummated. Moreover, time takes on a greater importance now than in the past as the focus shifts to small site-scale aquifers whose sustainability can be physically and chemically threatened. One of the challenges for research in hydrogeology is to establish time scales for hydrologic phenomena such as infiltration rates, groundwater flow rates, rates of organic and inorganic reactions, and rates of groundwater withdrawal over the short term, and the long term and to understand the consequences of these various time scales. Credible monitoring programs must consider not only the spatial scale, but also the time scale of the phenomena being monitored.

  6. Electrical Resistivity Technique for Groundwater Exploration in Quaternary Deposit

    Science.gov (United States)

    Aziman, M.; Hazreek, Z. A. M.; Azhar, A. T. S.; Fahmy, K. A.; Faizal, T. B. M.; Sabariah, M.; Ambak, K.; Ismail, M. A. M.

    2018-04-01

    The water security for University Tun Hussein Onn (UTHM) campus was initiated to find alternative sources of water supply. This research began with finding the soil profiles using the geophysical electrical resistivity method across UTHM campus. The resistivity results were calibrated with previous borehole data as well as via groundwater drilling. The drilling work was discovered the groundwater aquifer characterized by the fractured fresh igneous rock at a depth between 43 meter and 55 meter. Further drilling was continued until 100 meter in depth. However, due to not encounter a new rock fractured zone causes the groundwater quantity did not improve even was drilled up to 100 meter depth. In the perspective of water resources, it showed a good potential for water resources for local usages at 104 m3 per day. In addition, the groundwater quality showed the water treatment was required to fulfil the criterion of the national drinking water standards. This study concluded that the first layer of fractured bedrock at UTHM was able to produce significant amounts of groundwater for local consumption usage.

  7. Optimal Aquifer Pumping Policy to Reduce Contaminant Concentration

    Directory of Open Access Journals (Sweden)

    Ali Abaei

    2012-01-01

    Full Text Available Different sources of ground water contamination lead to non-uniform distribution of contaminant concentration in the aquifer. If elimination or containment of pollution sources was not possible, the distribution of contaminant concentrations could be modified in order to eliminate peak concentrations using optimal water pumping discharge plan. In the present investigation Visual MODFLOW model was used to simulate the flow and transport in a hypothetic aquifer. Genetic Algorithm (GA also was applied to optimize the location and pumping flow rate of wells in order to reduce contaminants peak concentrations in aquifer.

  8. New methodology for aquifer influx status classification for single wells in a gas reservoir with aquifer support

    Directory of Open Access Journals (Sweden)

    Yong Li

    2016-10-01

    Full Text Available For gas reservoirs with strong bottom or edge aquifer support, the most important thing is avoiding aquifer breakthrough in a gas well. Water production in gas wells does not only result in processing problems in surface facilities, but it also explicitly reduces well productivity and reservoir recovery. There are a lot of studies on the prediction of water breakthrough time, but they are not completely practicable due to reservoir heterogeneity. This paper provides a new method together with three diagnostic curves to identify aquifer influx status for single gas wells; the aforementioned curves are based on well production and pressure data. The whole production period of a gas well can be classified into three periods based on the diagnostic curves: no aquifer influx period, early aquifer influx period, and middle-late aquifer influx period. This new method has been used for actual gas well analysis to accurately identify gas well aquifer influx status and the water breakthrough sequence of all wells in the same gas field. Additionally, the evaluation results are significantly beneficial for well production rate optimization and development of an effective gas field.

  9. Isotopic study of the Continental Intercalaire aquifer and its relationship with other aquifers of the northern Sahara

    International Nuclear Information System (INIS)

    Gonfiantini, R.; Sauzay, G.; Payne, B.R.; Conrad, G.; Fontes, J.Ch.

    1974-01-01

    The Northern Sahara contains several aquifers, the largest of which is that of the Continental Intercalaire formations. In its eastern part the aquifer is confined and presents a very homogeneous isotopic composition. The 14 C activity is low or zero except in the outcrop zones of the north (Saharan Atlas), the east (Dahar) and the south (Tinrhert), all of which are recharge zones. In these areas the isotopic composition does not differ appreciably from that of the old water in the confined part of the aquifer. In the western part, where the reservoir outcrops widely, the 14 C activities show the extent of the local recharge. The heavy isotope content indicates the overflow of the surface aquifer of the western Grand Erg into the Continental Intercalaire over the whole Gourara front. The mixtures thus formed pass under the Tademait and drain towards the Touat. In the resurgence zone of the Gulf of G abes in Tunisia the heavy-isotope content confirms the recharging of the aquifer of the Complex terminal by drainage of water from the Continental Intercalaire through the El-Hamma fault system. The water then runs eastwards, mixing with local contributions. The marine Miocene confined aquifer of Zarzis-Djerba in the Gulf of Gabes receives no contribution from the Continental Intercalaire. The water in the aquifer of the western Grand Erg indicates an evaporation mechanism, probably peculiar to the dune systems, which gives rise to heavy-isotope enrichment compared with the recharge of other types of formations. (author) [fr

  10. Hydrogeology and water quality of the Floridan aquifer system and effect of Lower Floridan aquifer withdrawals on the Upper Floridan aquifer at Barbour Pointe Community, Chatham County, Georgia, 2013

    Science.gov (United States)

    Gonthier, Gerard; Clarke, John S.

    2016-06-02

    Two test wells were completed at the Barbour Pointe community in western Chatham County, near Savannah, Georgia, in 2013 to investigate the potential of using the Lower Floridan aquifer as a source of municipal water supply. One well was completed in the Lower Floridan aquifer at a depth of 1,080 feet (ft) below land surface; the other well was completed in the Upper Floridan aquifer at a depth of 440 ft below land surface. At the Barbour Pointe test site, the U.S. Geological Survey completed electromagnetic (EM) flowmeter surveys, collected and analyzed water samples from discrete depths, and completed a 72-hour aquifer test of the Floridan aquifer system withdrawing from the Lower Floridan aquifer.Based on drill cuttings, geophysical logs, and borehole EM flowmeter surveys collected at the Barbour Pointe test site, the Upper Floridan aquifer extends 369 to 567 ft below land surface, the middle semiconfining unit, separating the two aquifers, extends 567 to 714 ft below land surface, and the Lower Floridan aquifer extends 714 to 1,056 ft below land surface.A borehole EM flowmeter survey indicates that the Upper Floridan and Lower Floridan aquifers each contain four water-bearing zones. The EM flowmeter logs of the test hole open to the entire Floridan aquifer system indicated that the Upper Floridan aquifer contributed 91 percent of the total flow rate of 1,000 gallons per minute; the Lower Floridan aquifer contributed about 8 percent. Based on the transmissivity of the middle semiconfining unit and the Floridan aquifer system, the middle semiconfining unit probably contributed on the order of 1 percent of the total flow.Hydraulic properties of the Upper Floridan and Lower Floridan aquifers were estimated based on results of the EM flowmeter survey and a 72-hour aquifer test completed in Lower Floridan aquifer well 36Q398. The EM flowmeter data were analyzed using an AnalyzeHOLE-generated model to simulate upward borehole flow and determine the transmissivity of

  11. Factors Affecting Public-Supply Well Vulnerability in Two Karst Aquifers

    OpenAIRE

    Musgrove, MaryLynn; Katz, Brian G; Fahlquist, Lynne S; Crandall, Christy A; Lindgren, Richard J

    2014-01-01

    Karst aquifers occur in a range of climatic and geologic settings. Nonetheless, they are commonly characterized by their vulnerability to water-quality impairment. Two karst aquifers, the Edwards aquifer in south-central Texas and the Upper Floridan aquifer in western Florida, were investigated to assess factors that control the movement of contaminants to public-supply wells (PSWs). The geochemistry of samples from a selected PSW or wellfield in each aquifer was compared with that from nearb...

  12. Identifying Stream/Aquifer Exchange by Temperature Gradient in a Guarani Aquifer System Outcrop Zone

    Science.gov (United States)

    Wendland, E.; Rosa, D. M. S.; Anache, J. A. A.; Lowry, C.; Lin, Y. F. F.

    2017-12-01

    Recharge of the Guarani Aquifer System (GAS) in South America is supposed to occur mainly in the outcrop zones, where the GAS appears as an unconfined aquifer (10% of the 1.2 Million km2 aquifer extension). Previous evaluations of recharge are based essentially on water balance estimates for the whole aquifer area or water table fluctuations in monitoring wells. To gain a more detailed understanding of the recharge mechanisms the present work aimed to study the stream aquifer interaction in a watershed (Ribeirão da Onça) at an outcrop zone. Two Parshall flumes were installed 1.3 km apart for discharge measurement in the stream. Along this distance an optic fiber cable was deployed to identify stretches with gaining and losing behavior. In order to estimate groundwater discharge in specific locations, 8 temperature sticks were set up along the stream reach to measure continuously the vertical temperature gradient. A temperature probe with 4 thermistors was also used to map the shallow streambed temperature gradient manually along the whole distance. The obtained results show a discharge difference of 250 m3/h between both flumes. Since the last significant rainfall (15 mm) in the watershed occurred 3 months ago, this value can be interpreted as the base flow contribution to the stream during the dry season. Given the temperature difference between groundwater ( 24oC) and surface water ( 17oC) the fiber-optic distributed temperature sensing (FO-DTS) allowed the identification of stretches with gaining behavior. Temperature gradients observed at the streambed varied between 0.67 and 14.33 oC/m. The study demonstrated that heat may be used as natural tracer even in tropical conditions, where the groundwater temperature is higher than the surface water temperature during the winter. The obtained results show that the discharge difference between both flumes can not be extrapolated without detailed analysis. Gaining and loosing stretches have to be identified on order

  13. Groundwater and quaternary geological studies of potential peat production areas - useful tool for sustainable peat production

    Energy Technology Data Exchange (ETDEWEB)

    Valpola, S.E.; Paalijaervi, M. (Geological Survey of Finland, Kokkola (Finland)), Email: samu.valpola@gtk.fi, Email: miikka.paalijarvi@gtk.fi

    2009-07-01

    Potential peat production areas in Finland are often situated in vicinity of eskers or other quaternary (glaciofluvial) formations. Frequently these formations are also important groundwater resources and it is essential for sustainable peat production to assure that these resources will not be endangered. The Geological Survey of Finland (GTK) has concluded several quaternary geological studies on potential peat production areas, which are connected to locally important groundwater areas. These studies have been made using mainly ground penetrating radar (GPR) and light drilling equipment. The main objective of these studies has been to establish the local groundwater flow directions and the quality and extent of quaternary deposits. The increasing need of peat production areas has created an evident demand of cost-effective and fast research methods which can be used for providing reliable information for planning of new production areas. (orig.)

  14. Analysis of polarized photoluminescence emission of ordered III–V semiconductor quaternary alloys

    Energy Technology Data Exchange (ETDEWEB)

    Prutskij, Tatiana, E-mail: tatiana.prutskij@correo.buap.mx [Instituto de Ciencias, BUAP, Privada 17 Norte, No 3417, Col. San Miguel Huyeotlipan, 72050 Puebla, Pue., México (Mexico); Makarov, Nykolay, E-mail: nykolay.makarov@correo.buap.mx [Instituto de Ciencias, BUAP, Privada 17 Norte, No 3417, Col. San Miguel Huyeotlipan, 72050 Puebla, Pue., México (Mexico); Attolini, Giovanni, E-mail: giovanni@imem.cnr.it [IMEM/CNR, Parco Area delle Scienze 37/A, 43010 Parma (Italy)

    2016-04-15

    Ternary and quaternary III–V alloys obtained by metal-organic vapor-phase epitaxy (MOVPE) grow very often with some degree of atomic ordering. Atomic ordering reduces the symmetry of the crystal lattice and thus drastically changes optical properties of the alloy. Moreover, the photoluminescence (PL) emission becomes polarized and its study helps to understand the atomic arrangement within the crystal lattice. In this work we experimentally studied the polarization of the PL emission from different crystallographic planes of several quaternary III–V semiconductor alloys grown on GaAs substrates by MOVPE. We compare the measured PL emission polarization angular patterns with those calculated with a model made for ternary alloys and discuss the limits of application of this model for quaternaries. It is found that the experimentally obtained polarization patterns are consistent with the existence of different ordering crystallographic planes for III- and for V-group atoms.

  15. Study of ternary and quaternary spontaneous fission of 252Cf with the NESSI detector

    International Nuclear Information System (INIS)

    Tishchenko, V.G.; Jahnke, U.; Herbach, C.M.; Hilscher, D.

    2002-11-01

    Ternary and quaternary spontaneous decay of 252 Cf was studied with the NESSI detector, a combination of two 4π detectors for charged particles, neutrons and γ-rays. The applied method of particle identification by measuring the energies and relative time-of-flights of the decay products is shown to be very effective for the study of rare decay modes. The energy and angular distributions of the decay products, the associated neutron multiplicities, the total energy of the prompt γ-radiation as well as correlations between the various observables were measured for the first time in a single full-scale experiment. The characteristics of ternary fission known from previous investigations are confirmed in the frame of a methodically independent experiment. Preliminary estimates of the quaternary fission yield are presented. An attempt is made to determine the mechanism of quaternary fission. (orig.)

  16. Derivatization of peptides as quaternary ammonium salts for sensitive detection by ESI-MS.

    Science.gov (United States)

    Cydzik, Marzena; Rudowska, Magdalena; Stefanowicz, Piotr; Szewczuk, Zbigniew

    2011-06-01

    A series of model peptides in the form of quaternary ammonium salts at the N-terminus was efficiently prepared by the solid-phase synthesis. Tandem mass spectrometric analysis of the peptide quaternary ammonium derivatives was shown to provide sequence confirmation and enhanced detection. We designed the 2-(1,4-diazabicyclo[2.2.2] octylammonium)acetyl quaternary ammonium group which does not suffer from neutral losses during MS/MS experiments. The presented quaternization of 1,4-diazabicyclo[2.2.2]octane (DABCO) by iodoacetylated peptides is relatively easy and compatible with standard solid-phase peptide synthesis. This methodology offers a novel sensitive approach to analyze peptides and other compounds. Copyright © 2011 European Peptide Society and John Wiley & Sons, Ltd.

  17. Late quaternary faulting along the Death Valley-Furnace Creek fault system, California and Nevada

    International Nuclear Information System (INIS)

    Brogan, G.E.; Kellogg, K.S.; Terhune, C.L.; Slemmons, D.B.

    1991-01-01

    The Death Valley-Furnace Creek fault system, in California and Nevada, has a variety of impressive late Quaternary neotectonic features that record a long history of recurrent earthquake-induced faulting. Although no neotectonic features of unequivocal historical age are known, paleoseismic features from multiple late Quaternary events of surface faulting are well developed throughout the length of the system. Comparison of scarp heights to amount of horizontal offset of stream channels and the relationships of both scarps and channels to the ages of different geomorphic surfaces demonstrate that Quaternary faulting along the northwest-trending Furnace Creek fault zone is predominantly right lateral, whereas that along the north-trending Death Valley fault zone is predominantly normal. These observations are compatible with tectonic models of Death Valley as a northwest- trending pull-apart basin

  18. Hydrogeology - AQUIFER_SYSTEMS_UNCONSOLIDATED_IDNR_IN: Unconsolidated Aquifer Systems of Indiana (Indiana Department of Natural Resources, 1:48,000, Polygon Shapefile)

    Data.gov (United States)

    NSGIC State | GIS Inventory — AQUIFER_SYSTEMS_UNCONSOLIDATED_IDNR_IN is a polygon shapefile that shows unconsolidated aquifer systems of the state of Indiana at a scale of 1:48,000. The following...

  19. Geologic framework, regional aquifer properties (1940s-2009), and spring, creek, and seep properties (2009-10) of the upper San Mateo Creek Basin near Mount Taylor, New Mexico

    Science.gov (United States)

    Langman, Jeff B.; Sprague, Jesse E.; Durall, Roger A.

    2012-01-01

    The U.S. Geological Survey, in cooperation with the U.S. Forest Service, examined the geologic framework, regional aquifer properties, and spring, creek, and seep properties of the upper San Mateo Creek Basin near Mount Taylor, which contains areas proposed for exploratory drilling and possible uranium mining on U.S. Forest Service land. The geologic structure of the region was formed from uplift of the Zuni Mountains during the Laramide Orogeny and the Neogene volcanism associated with the Mount Taylor Volcanic Field. Within this structural context, numerous aquifers are present in various Paleozoic and Mesozoic sedimentary formations and the Quaternary alluvium. The distribution of the aquifers is spatially variable because of the dip of the formations and erosion that produced the current landscape configuration where older formations have been exhumed closer to the Zuni Mountains. Many of the alluvial deposits and formations that contain groundwater likely are hydraulically connected because of the solid-matrix properties, such as substantive porosity, but shale layers such as those found in the Mancos Formation and Chinle Group likely restrict vertical flow. Existing water-level data indicate topologically downgradient flow in the Quaternary alluvium and indiscernible general flow patterns in the lower aquifers. According to previously published material and the geologic structure of the aquifers, the flow direction in the lower aquifers likely is in the opposite direction compared to the alluvium aquifer. Groundwater within the Chinle Group is known to be confined, which may allow upward migration of water into the Morrison Formation; however, confining layers within the Chinle Group likely retard upward leakage. Groundwater was sodium-bicarbonate/sulfate dominant or mixed cation-mixed anion with some calcium/bicarbonate water in the study area. The presence of the reduction/oxidation-sensitive elements iron and manganese in groundwater indicates reducing

  20. Analytical solution of groundwater waves in unconfined aquifers with ...

    Indian Academy of Sciences (India)

    Selva Balaji Munusamy

    2017-07-29

    Jul 29, 2017 ... higher-order Boussinesq equation. The homotopy perturbation solution is derived using a virtual perturbation .... reality, seepage face formation is common for tide–aquifer interaction problems. To simplify the complexity of the.

  1. Temporal geoelectric behaviour of dyke aquifers in northern Deccan ...

    Indian Academy of Sciences (India)

    These studies revealed changes in field characters, their attitudes, thickness and structure ... logists. However, information on the relation- .... the water table aquifer occurs at shallow depth .... from the field was processed and modelled using.

  2. Aquifers productivity in the Pan-African context

    Indian Academy of Sciences (India)

    , including 14 near existing boreholes for comparison. Aquifer parameters of hydraulic conductivity and transmissivity were obtained by analyzing pumping test data from existing boreholes. An empirical relationship between hydraulic ...

  3. Radial flow towards well in leaky unconfined aquifer

    Science.gov (United States)

    Mishra, P. K.; Kuhlman, K. L.

    2012-12-01

    An analytical solution is developed for three-dimensional flow towards a partially penetrating large- diameter well in an unconfined aquifer bounded below by a leaky aquitard of finite or semi-infinite extent. The analytical solution is derived using Laplace and Hankel transforms, then inverted numerically. Existing solutions for flow in leaky unconfined aquifers neglect the unsaturated zone following an assumption of instantaneous drainage due to Neuman. We extend the theory of leakage in unconfined aquifers by (1) including water flow and storage in the unsaturated zone above the water table, and (2) allowing the finite-diameter pumping well to partially penetrate the aquifer. The investigation of model-predicted results shows that aquitard leakage leads to significant departure from the unconfined solution without leakage. The investigation of dimensionless time-drawdown relationships shows that the aquitard drawdown also depends on unsaturated zone properties and the pumping-well wellbore storage effects.

  4. Aquifer Vulnerability Investigation Using Geoelectric Method in Parts ...

    African Journals Online (AJOL)

    The generated longitudinal conductance map showed poor protective capacity ... capacity makes the aquifer in the study area vulnerable to contamination ..... Sedimentation and Structure of the Niger Delta. ... Direct application of the Dar.

  5. Borehole depth and regolith aquifer hydraulic characteristics of ...

    African Journals Online (AJOL)

    EJIRO

    composition tend to exhibit similar hydraulic characteristics. But the poor performance of ... mum borehole depth in the regolith aquifer for the area and also reveals that ..... most important end products of chemical weathering of rocks of granitic ...

  6. Redox Conditions in Selected Principal Aquifers of the United States

    Science.gov (United States)

    McMahon, P.B.; Cowdery, T.K.; Chapelle, F.H.; Jurgens, B.C.

    2009-01-01

    Reduction/oxidation (redox) processes affect the quality of groundwater in all aquifer systems. Redox processes can alternately mobilize or immobilize potentially toxic metals associated with naturally occurring aquifer materials, contribute to the degradation or preservation of anthropogenic contami-nants, and generate undesirable byproducts, such as dissolved manganese (Mn2+), ferrous iron (Fe2+), hydrogen sulfide (H2S), and methane (CH4). Determining the kinds of redox processes that occur in an aquifer system, documenting their spatial distribution, and understanding how they affect concentrations of natural or anthropogenic contaminants are central to assessing and predicting the chemical quality of groundwater. This Fact Sheet extends the analysis of U.S. Geological Survey authors to additional principal aquifer systems by applying a framework developed by the USGS to a larger set of water-quality data from the USGS national water databases. For a detailed explanation, see the 'Introduction' in the Fact Sheet.

  7. Hydraulic conductivities of fractures and matrix in Slovenian carbonate aquifers

    Directory of Open Access Journals (Sweden)

    Timotej Verbovšek

    2008-12-01

    Full Text Available Hydraulic conductivities and specific storage coefficients of fractures and matrix in Slovenian carbonate aquifers were determined by Barker’s method for pumping test analysis, based on fractional flow dimension. Values are presented for limestones and mainly for dolomites, and additionally for separate aquifers, divided by age andlithology in several groups. Data was obtained from hydrogeological reports for 397 water wells, and among these, 79 pumping tests were reinterpreted. Hydraulic conductivities of fractures are higher than the hydraulic conductivities of matrix, and the differences are highly statistically significant. Likewise, differences are significant for specific storage, and the values of these coefficients are higher in the matrix. Values of all coefficients vary in separate aquifers, and the differences can be explained by diagenetic effects, crystal size, degree of fracturing, andcarbonate purity. Comparison of the methods, used in the reports, and the Barker’s method (being more suitable for karstic and fractured aquifers, shows that the latter fits real data better.

  8. Fate of triclocarban during soil aquifer treatment: Soil column studies

    KAUST Repository

    Essandoh, H. M K; Tizaoui, Chedly; Mohamed, Mostafa H A; Amy, Gary L.; Brdjanovic, Damir

    2010-01-01

    There are current concerns about the presence of persistent chemicals in recharge water used in soil aquifer treatment systems. Triclocarban (TCC) has been reported as a persistent, high production volume chemical with the potential to bioaccumulate

  9. Soil aquifer treatment of artificial wastewater under saturated conditions

    KAUST Repository

    Essandoh, H. M K; Tizaoui, Chedly; Mohamed, Mostafa H A; Amy, Gary L.; Brdjanovic, Damir

    2011-01-01

    A 2000 mm long saturated laboratory soil column was used to simulate soil aquifer treatment under saturated conditions to assess the removal of chemical and biochemical oxygen demand (COD and BOD), dissolved organic carbon (DOC), nitrogen

  10. Exploring deep potential aquifer in water scarce crystalline rocks

    Indian Academy of Sciences (India)

    out to explore deep groundwater potential zone in a water scarce granitic area. As existing field condi- ... Decision support tool developed in granitic ter- .... cially in terms of fracture system, the aquifer char- acteristics ... Methodologies used.

  11. Water levels of the Ozark aquifer in northern Arkansas, 2013

    Science.gov (United States)

    Schrader, Tony P.

    2015-07-13

    The Ozark aquifer is the largest aquifer, both in area of outcrop and thickness, and the most important source of freshwater in the Ozark Plateaus physiographic province, supplying water to northern Arkansas, southeastern Kansas, southern Missouri, and northeastern Oklahoma. The study area includes 16 Arkansas counties lying completely or partially within the Ozark Plateaus of the Interior Highlands major physiographic division. The U.S. Geological Survey, in cooperation with the Arkansas Natural Resources Commission and the Arkansas Geological Survey, conducted a study of water levels in the Ozark aquifer within Arkansas. This report presents a potentiometric-surface map of the Ozark aquifer within the Ozark Plateaus of northern Arkansas, representing water-level conditions for the early spring of 2013 and selected water-level hydrographs.

  12. Evaluation of karstic aquifers contribution to streams by the statistical ...

    Indian Academy of Sciences (India)

    and water budget balance, have been applied to assess ... Keywords. Recession curve; karstic aquifer; western Mediterranean Basin–Turkey; data analysis; hydrology; modelling. .... on the solution of the general differential equa- tion of the ...

  13. Managing the unseen: Langebaan Road Aquifer System | du Plessis ...

    African Journals Online (AJOL)

    The effective management of groundwater resources is a critical aspect to ... The paper highlights specific problems experienced with the implementation of the Langebaan Road Aquifer well-field as an integrated water resource, and the ...

  14. Lithological and Structural Controls on the Development of Aquifer ...

    African Journals Online (AJOL)

    Bheema

    Research Article ... Based on borehole and structure data presence of multilayer aquifers, their .... Shape of the clasts varies from angular, elliptical and ..... Water quality investigation (i.e. for domestic purpose) is also recommended. 6.

  15. Hydrodynamic characterization of the Paleocene aquifer in the ...

    African Journals Online (AJOL)

    user

    2009-05-15

    May 15, 2009 ... African Journal of Environmental Science and Technology Vol. 3 (5), pp. 141-148 ..... hydrogeological study of the coastal sedimentary basin of. Togo intended to ... isotopic study and modeling of the Paleocene aquifer in the.

  16. Simulation of sea water intrusion in coastal aquifers

    Indian Academy of Sciences (India)

    dependent miscible flow and transport modelling approach for simulation of seawater intrusion in coastal aquifers. A nonlinear optimization-based simulation methodology was used in this study. Various steady state simulations are performed for a ...

  17. ZVI (Fe0) desalination: catalytic partial desalination of saline aquifers

    Science.gov (United States)

    Antia, David D. J.

    2018-05-01

    Globally, salinization affects between 100 and 1000 billion m3 a-1 of irrigation water. The discovery that zero valent iron (ZVI, Fe0) could be used to desalinate water (using intra-particle catalysis in a diffusion environment) raises the possibility that large-scale in situ desalination of aquifers could be undertaken to support agriculture. ZVI desalination removes NaCl by an adsorption-desorption process in a multi-stage cross-coupled catalytic process. This study considers the potential application of two ZVI desalination catalyst types for in situ aquifer desalination. The feasibility of using ZVI catalysts when placed in situ within an aquifer to produce 100 m3 d-1 of partially desalinated water from a saline aquifer is considered.

  18. Web-based global inventory of managed aquifer recharge applications

    NARCIS (Netherlands)

    Stefan, Catalin; Ansems, Nienke

    2017-01-01

    Managed aquifer recharge (MAR) is being successfully implemented worldwide for various purposes: to increase groundwater storage, improve water quality, restore groundwater levels, prevent salt water intrusion, manage water distribution systems, and enhance ecological benefits. To better understand

  19. Determining hydraulic parameters of a karst aquifer using unique ...

    African Journals Online (AJOL)

    2014-07-15

    Jul 15, 2014 ... 1 Faculty of Natural Sciences, Potchefstroom Campus, North-West University, ... a first-ever attempt to utilise various sets of unique historical data ..... Even though the aquifer shows characteristics of all major ...... Earth Sci.

  20. Tephra compositions from Late Quaternary volcanoes around the Antarctic Peninsula

    Science.gov (United States)

    Kraus, S.

    2009-12-01

    /Hf ratios lower than N-MORB, all other volcanoes including the Larsen Rift centers display Zr/Hf higher than N-MORB. It is expected that the correlation of the new data with published data from tephra layers found in ice, lake and marine sediment cores will contribute to a better constrained timing of individual climatic events identified in the northern Antarctic Peninsula area. Late Quaternary volcanoes around the northern Antarctic Peninsula.

  1. Quaternary structure of the lactose transport protein of Streptococcus thermophilus in the detergent-solubilized and membrane-reconstituted state

    NARCIS (Netherlands)

    Friesen, R.H.E.; Poolman, B.; Knol, J.

    2000-01-01

    The quaternary structure of LacS, the lactose transporter of Streptococcus thermophilus, has been determined for the detergent-solubilized and the membrane-reconstituted state of the protein. The quaternary structure of the n-dodecyl-β-D-maltoside-solubilized state was studied using a combination of

  2. Nano-sized quaternary CuGa2In3S8 as an efficient photocatalyst for solar hydrogen production

    KAUST Repository

    Kandiel, Tarek; Anjum, Dalaver H.; Takanabe, Kazuhiro

    2014-01-01

    The synthesis of quaternary metal sulfide (QMS) nanocrystals is challenging because of the difficulty to control their stoichiometry and phase structure. Herein, quaternary CuGa2In3S8 photocatalysts with a primary particle size of ≈4nm

  3. The determination of B and Sr isotopes of quaternary biologic fossils in Yanghuzhuang Yanqing basin and their living environment

    International Nuclear Information System (INIS)

    Xiao Yingkai; Xiao Jun; Zhao Zhiqi; He Maoyong; Li Shizhen

    2007-01-01

    The B and Sr isotopic compositions of early Quaternary biologic fossils in Yanghuzhuang and living bivalves in Weishui river were measured. Comparing with the data of marine foraminifer, the results show a non-marine living environment for these foraminifers lived in early Quaternary in Yanghuzhuang, Yanqing; Basin. (authors)

  4. Bedrock aquifers of eastern San Juan County, Utah

    Science.gov (United States)

    Avery, Charles

    1986-01-01

    This study is one of a series of studies appraising the waterbearing properties of the Navajo Sandstone and associated formations in southern Utah.  The study area is about 4,600 square miles, extending from the Utah-Arizona State line northward to the San Juan-Grand County line and westward from the Utah-Colorado State line to the longitude of about 109°50'.Some of the water-yielding formations are grouped into aquifer systems. The C aquifer is comprised of the DeChelly Sandstone Member of the Cutler Formation.  The P aquifer is comprised of the Cedar Mesa Member of the Cutler Formation and the undifferentiated Cutler Formation. The N aquifer is comprised of the sedimentary section that includes the Wingate Sandstone, Kayenta Formation, Navajo Sandstone, Carmel Formation, and Entrada sandstone.  The M aquifer is comprised of the Bluff Sandstone Member and other sandstone units of the Morrison Formation.  The D aquifer is comprised of the Burro Canyon Formation and Dakota Sandstone.  Discharge from the ground-water reservoir to the San Juan River between gaging stations at Four Corners and Mexican Hat is about 66 cubic feet per second.The N aquifer is the main aquifer in the study area. Recharge by infiltration of precipitation is estimated to be 25,000 acre-feet per year.  A major ground-water divide exists under the broad area east of Monticello.  The thickness of the N aquifer, where the sedimentary section is fully preserved and saturated, generally is 750 to 1,250 feet.   Hydraulic conductivity values obtained from aquifer tests range from 0.02 to 0.34 foot per day.  The total volume of water in transient storage is about 11 million acre-feet. Well discharge somewhat exceeded 2,340 acre-feet during 1981.  Discharge to the San Juan River from the N aquifer is estimated to be 6.9 cubic feet per second. Water quality ranges from a calcium bicarbonate to sodium chloride type water

  5. Wrench tectonics control on Neogene-Quaternary sedimentation along the Mid-Hungarian Mobile Belt

    Science.gov (United States)

    Pogacsas, Gyorgy; Juhász, Györgyi; Mádl-Szőnyi, Judit; Simon, Szilvia; Lukács, Szilveszter; Csizmeg, János

    2010-05-01

    Africa-Europe convergence vector. Pliocene-Quaternary was characterised by 1-5 km left lateral wrenching along the Mid-Hungarian Mobile Belt. Based on high resolution seismic measurements on the Danube river Toth (2003) supposed an even more recent activity along the Paks-Szolnok wrench fault zone. The supposed late Quaternary activity of the Mid-Hungarian Mobile Belt is supported by recent hydrogeologic investigations. According to Mádl-Szőnyi et al (2005) and Simon et al (in press) from the Pre-Neogene basement originates an ascending overpressured highly saline water flow regime. Deep ascending water rises near to the surface, intercepting the aquifer and aquitard layers along conductive strike slipe faults of the Mid-Hungarian Mobile Belt and mixing with shallower groundwater. Acknowledgements The research work was supported by the Hungarian National Research Fund (OTKA 035168, T 047159). References Detzky Lőrinc K. (1997) Detailed tectonic study of the Western edge of the Szolnok flysch zone using seismic and well data. Thesis Candidate of Science. Hungarian Academy of Science. p. 121. Grow J. A., R. E. Mattick, A. Bérczi-Makk, Cs. Péró, D. Hajdú, Gy. Pogácsás, P. Várnai, E. Varga, (1994) Structure of the Békés basin inferred from seismic reflection, well and gravity data. in Teleki P., J. Kókai, R.E. Mattick eds. Basin analysis in petroleum exploration, a case study from the Békés basin, Hungary. Kluwer Academic Publisher, Dordrecht, Netherlands, p. 1-38. Juhász, Gy., Pogácsás Gy., Magyar I. (2007) A giant canyon system incised into the Late-Neogene (pannonian s.l.) sediments? (in Hungarian Óriáskanyon-rendszer szeli át a pannóniai üledékeket? Földtani Közlöny (Bulletin of the Geological Society of Hungary)137/3. 307-326. Mádlné Szőnyi J. Simon Sz. Tóth J. Pogácsás Gy. (2005) Interrelationship between surface and subsurface waters at the Kelemen-szék and Kolon lakes, Duna-Tisza Interfluve, Hungary (in Hungarian Felszíni és felsz

  6. Band gap depiction of quaternary FeMnTiAl alloy using Hubbard (U) potential

    Science.gov (United States)

    Bhat, Tahir Mohiuddin; Yousuf, Saleem; Khandy, Shakeel Ahmad; Gupta, Dinesh C.

    2018-05-01

    We have employed self-consistent ab-initio calculations to investigate new quaternary alloy FeMnTiAl by applying Hubbard potential (U). The alloy is found to be stable in ferromagnetic phase with cubic structure. The alloy shows half-metallic (HM) ferromagnet character. The values of minority band gap FeMnTiAl are found to be 0.33 eV respectively. Electronic charge density reveals that both types of bonds covalent as well as ionic are present in the alloy. Thus the new quaternary alloy can be proved as vital contender for spin valves and spin generator devices.

  7. Towards dating Quaternary sediments using the quartz Violet Stimulated Luminescence (VSL) signal

    DEFF Research Database (Denmark)

    Ankjærgaard, C.; Jain, Mayank; Wallinga, J.

    2013-01-01

    Quaternary sediments using the violet (402 nm) stimulated luminescence (VSL) signal of quartz.We develop and test a new post-blue VSL single aliquot regenerative dose dating protocol, and demonstrate that the VSL signal originates from a deep trap at about 1.9 eV with a thermal lifetime of 1011 years at 10......Quartz optically stimulated luminescence (OSL) dating is widely used to determine the time of deposition and burial of Late Quaternary sediments. Application of the method is usually limited to the past 150,000 years due to early saturation of the OSL signal. Here we explore the potential to date...

  8. Bio-remediation of aquifers polluted by chlorinated solvents

    International Nuclear Information System (INIS)

    Fayolle, F.

    1996-01-01

    Numerous cases of contamination of aquifers by chlorinated aliphatic solvents, largely utilized during the last decades, constitute a public health problem, because of the toxic effect of such compounds. Different types of aerobic or anaerobic bacteria are able to degrade these molecules. Processes of bio remediation are now experimented in order to restore polluted aquifers. We present here the microorganisms and the enzymatic reactions involved in the biodegradation of chlorinated solvents, and different examples of in situ bio remediation operations are described. (author)

  9. Variation of uranium isotopes in some carbonate aquifers

    International Nuclear Information System (INIS)

    Cowart, J.B.

    1980-01-01

    The 234 U/ 238 U alpha activity ratio (AR) and uranium concentrations are reported for 83 springs that issue from carbonate aquifers in Florida, Texas, Nevada-California, and Israel. Data for each aquifer fall within more or less mutually exclusive fields. In general, the spring in a humid climate have AR's approaching secular equilibrium, whereas those in more arid climates have AR's differing greatly from equilibrium

  10. FEWA: a Finite Element model of Water flow through Aquifers

    International Nuclear Information System (INIS)

    Yeh, G.T.; Huff, D.D.

    1983-11-01

    This report documents the implementation and demonstration of a Finite Element model of Water flow through Aquifers (FEWA). The particular features of FEWA are its versatility and flexibility to deal with as many real-world problems as possible. Point as well as distributed sources/sinks are included to represent recharges/pumpings and rainfall infiltrations. All sources/sinks can be transient or steady state. Prescribed hydraulic head on the Dirichlet boundaries and fluxes on Neumann or Cauchy boundaries can be time-dependent or constant. Source/sink strength over each element and node, hydraulic head at each Dirichlet boundary node, and flux at each boundary segment can vary independently of each other. Either completely confined or completely unconfined aquifers, or partially confined and partially unconfined aquifers can be dealt with effectively. Discretization of a compound region with very irregular curved boundaries is made easy by including both quadrilateral and triangular elements in the formulation. Large-field problems can be solved efficiently by including a pointwise iterative solution strategy as an optional alternative to the direct elimination solution method for the matrix equation approximating the partial differential equation of groundwater flow. FEWA also includes transient flow through confining leaky aquifers lying above and/or below the aquifer of interest. The model is verified against three simple cases to which analytical solutions are available. It is then demonstrated by two examples of how the model can be applied to heterogeneous and anisotropic aquifers with transient boundary conditions, time-dependent sources/sinks, and confining aquitards for a confined aquifer of variable thickness and for a free surface problem in an unconfined aquifer, respectively. 20 references, 25 figures, 8 tables

  11. Drilling methods to keep the hydrogeological parameters of natural aquifer

    International Nuclear Information System (INIS)

    Chen Xiaoqin

    2004-01-01

    In hydrogeological drilling, how to keep the hydrogeological parameters of natural aquifer unchanged is a deeply concerned problem for the technicians, this paper introduces the methods taken by the state-owned 'Red Hill' geological company of Uzbekistan. By the research and contrast of different kinds of flush liquid, the company has found the methods to reduce the negative effects of drilling on the permeability of the vicinal aquifer. (author)

  12. FEWA: a Finite Element model of Water flow through Aquifers

    Energy Technology Data Exchange (ETDEWEB)

    Yeh, G.T.; Huff, D.D.

    1983-11-01

    This report documents the implementation and demonstration of a Finite Element model of Water flow through Aquifers (FEWA). The particular features of FEWA are its versatility and flexibility to deal with as many real-world problems as possible. Point as well as distributed sources/sinks are included to represent recharges/pumpings and rainfall infiltrations. All sources/sinks can be transient or steady state. Prescribed hydraulic head on the Dirichlet boundaries and fluxes on Neumann or Cauchy boundaries can be time-dependent or constant. Source/sink strength over each element and node, hydraulic head at each Dirichlet boundary node, and flux at each boundary segment can vary independently of each other. Either completely confined or completely unconfined aquifers, or partially confined and partially unconfined aquifers can be dealt with effectively. Discretization of a compound region with very irregular curved boundaries is made easy by including both quadrilateral and triangular elements in the formulation. Large-field problems can be solved efficiently by including a pointwise iterative solution strategy as an optional alternative to the direct elimination solution method for the matrix equation approximating the partial differential equation of groundwater flow. FEWA also includes transient flow through confining leaky aquifers lying above and/or below the aquifer of interest. The model is verified against three simple cases to which analytical solutions are available. It is then demonstrated by two examples of how the model can be applied to heterogeneous and anisotropic aquifers with transient boundary conditions, time-dependent sources/sinks, and confining aquitards for a confined aquifer of variable thickness and for a free surface problem in an unconfined aquifer, respectively. 20 references, 25 figures, 8 tables.

  13. Structural control on the deep hydrogeological and geothermal aquifers related to the fractured Campanian-Miocene reservoirs of north-eastern Tunisia foreland constrained by subsurface data

    Science.gov (United States)

    Khomsi, Sami; Echihi, Oussema; Slimani, Naji

    2012-03-01

    A set of different data including high resolution seismic sections, petroleum wire-logging well data, borehole piezometry, structural cross-sections and outcrop analysis allowed us to characterise the tectonic framework, and its relationships with the deep aquifers seated in Cretaceous-Miocene deep reservoirs. The structural framework, based on major structures, controls the occurrence of deep aquifers and sub-basin aquifer distributions. Five structural domains can be defined, having different morphostructural characteristics. The northernmost domain lying on the north-south axis and Zaghouan thrust system is a domain of recharge by underflow of the different subsurface reservoirs and aquifers from outcrops of highly fractured reservoirs. On the other hand, the morphostructural configuration controls the piezometry of underground flows in the Plio-Quaternary unconfined aquifer. In the subsurface the Late Cretaceous-Miocene reservoirs are widespread with high thicknesses in many places and high porosities and connectivities especially along major fault corridors and on the crestal parts of major anticlines. Among all reservoirs, the Oligo-Miocene, detritic series are widespread and present high cumulative thicknesses. Subsurface and fieldwork outline the occurrence of 10 fractured sandy reservoirs for these series with packages having high hydrodynamic and petrophysical characteristics. These series show low salinities (maximum 5 g/l) in the northern part of the study area and will constitute an important source of drinkable water for the next generations. A regional structural cross-section is presented, compiled from all the different data sets, allowing us to define the major characteristics of the hydrogeological-hydrogeothermal sub-basins. Eight hydrogeological provinces are defined from north-west to south-east. A major thermal anomaly is clearly identified in the south-eastern part of the study area in Sfax-Sidi Il Itayem. This anomaly is possibly related to

  14. A major change in precipitation gradient on the Chinese Loess Plateau at the Pliocene-Quaternary boundary

    Science.gov (United States)

    Peng, Wenbin; Nie, Junsheng; Wang, Zhao; Qiang, Xiaoke; Garzanti, Eduardo; Pfaff, Katharina; Song, Yougui; Stevens, Thomas

    2018-04-01

    Spatiotemporal variations in East Asian Monsoon (EAM) precipitation during the Quaternary have been intensively studied. However, spatial variations in pre-Quaternary EAM precipitation remain largely uninvestigated, preventing a clear understanding of monsoon dynamics during a warmer climatic period. Here we compare the spatial differences in heavy mineral assemblages between Quaternary loess and pre-Quaternary Red Clay on the Chinese Loess Plateau (CLP) to analyze spatial patterns in weathering. Prior studies have revealed that unstable hornblende is the dominant (∼50%) heavy mineral in Chinese loess deposited over the past 500 ka, whereas hornblende content decreases to climate at Jiaxian must have been initiated since ∼2.7 Ma, preventing hornblende dissolution to amounts change in climatic patterns at ∼2.7 Ma to decreased northward moisture transportation associated with Northern Hemisphere glaciation and cooling in the Quaternary. This study therefore demonstrates the potential usefulness of employing heavy mineral analysis in both paleoclimatic and paleooceanographic reconstructions.

  15. Transient well flow in leaky multiple-aquifer systems

    Science.gov (United States)

    Hemker, C. J.

    1985-10-01

    A previously developed eigenvalue analysis approach to groundwater flow in leaky multiple aquifers is used to derive exact solutions for transient well flow problems in leaky and confined systems comprising any number of aquifers. Equations are presented for the drawdown distribution in systems of infinite extent, caused by wells penetrating one or more of the aquifers completely and discharging each layer at a constant rate. Since the solution obtained may be regarded as a combined analytical-numerical technique, a type of one-dimensional modelling can be applied to find approximate solutions for several complicating conditions. Numerical evaluations are presented as time-drawdown curves and include effects of storage in the aquitard, unconfined conditions, partially penetrating wells and stratified aquifers. The outcome of calculations for relatively simple systems compares very well with published corresponding results. The proposed multilayer solution can be a valuable tool in aquifer test evaluation, as it provides the analytical expression required to enable the application of existing computer methods to the determination of aquifer characteristics.

  16. Sustainable Capture: Concepts for Managing Stream-Aquifer Systems.

    Science.gov (United States)

    Davids, Jeffrey C; Mehl, Steffen W

    2015-01-01

    Most surface water bodies (i.e., streams, lakes, etc.) are connected to the groundwater system to some degree so that changes to surface water bodies (either diversions or importations) can change flows in aquifer systems, and pumping from an aquifer can reduce discharge to, or induce additional recharge from streams, springs, and lakes. The timescales of these interactions are often very long (decades), making sustainable management of these systems difficult if relying only on observations of system responses. Instead, management scenarios are often analyzed based on numerical modeling. In this paper we propose a framework and metrics that can be used to relate the Theis concepts of capture to sustainable measures of stream-aquifer systems. We introduce four concepts: Sustainable Capture Fractions, Sustainable Capture Thresholds, Capture Efficiency, and Sustainable Groundwater Storage that can be used as the basis for developing metrics for sustainable management of stream-aquifer systems. We demonstrate their utility on a hypothetical stream-aquifer system where pumping captures both streamflow and discharge to phreatophytes at different amounts based on pumping location. In particular, Capture Efficiency (CE) can be easily understood by both scientists and non-scientist alike, and readily identifies vulnerabilities to sustainable stream-aquifer management when its value exceeds 100%. © 2014, National Ground Water Association.

  17. Identification of TCE and PCE sorption and biodegradation parameters in a sandy aquifer for fate and transport modelling: batch and column studies.

    Science.gov (United States)

    Kret, E; Kiecak, A; Malina, G; Nijenhuis, I; Postawa, A

    2015-07-01

    The main aim of this study was to determine the sorption and biodegradation parameters of trichloroethene (TCE) and tetrachloroethene (PCE) as input data required for their fate and transport modelling in a Quaternary sandy aquifer. Sorption was determined based on batch and column experiments, while biodegradation was investigated using the compound-specific isotope analysis (CSIA). The aquifer materials medium (soil 1) to fine (soil 2) sands and groundwater samples came from the representative profile of the contaminated site (south-east Poland). The sorption isotherms were approximately linear (TCE, soil 1, K d = 0.0016; PCE, soil 1, K d = 0.0051; PCE, soil 2, K d = 0.0069) except for one case in which the best fitting was for the Langmuir isotherm (TCE, soil 2, K f = 0.6493 and S max = 0.0145). The results indicate low retardation coefficients (R) of TCE and PCE; however, somewhat lower values were obtained in batch compared to column experiments. In the column experiments with the presence of both contaminants, TCE influenced sorption of PCE, so that the R values for both compounds were almost two times higher. Non-significant differences in isotope compositions of TCE and PCE measured in the observation points (δ(13)C values within the range of -23.6 ÷ -24.3‰ and -26.3 ÷-27.7‰, respectively) indicate that biodegradation apparently is not an important process contributing to the natural attenuation of these contaminants in the studied sandy aquifer.

  18. Potentiometric-surface altitude of the confined aquifer, Wood River Valley aquifer system, south-central Idaho, October 2012.

    Data.gov (United States)

    Department of the Interior — Water levels in 93 wells completed in the Wood River Valley aquifer system were measured during October 22–24, 2012; these wells are part of a network established...

  19. Water-table altitude of the unconfined aquifer, Wood River Valley aquifer system, south-central Idaho, October 2012.

    Data.gov (United States)

    Department of the Interior — Water levels in 93 wells completed in the Wood River Valley aquifer system were measured during October 22–24, 2012; these wells are part of a network established...

  20. Quaternary Tectonic and Climatic Processes shaping the Central Andean hyperarid forearc (southern Peru)

    Science.gov (United States)

    Audin, Laurence; Benavente, Carlos; Zerathe, Swann; Saillard, Marianne; Hall, Sarah R.; Farber, Daniel L.

    2015-04-01

    Understanding the forearc structure and processes related to Quaternary evolution and uplift of the Western Andean Cordillera remains an outstanding scientific issue. Models of Andean Plateau evolution based on Tertiary volcanic stratigraphy since 5Ma suggest that the deformation was focused along the eastern margin of the plateau and that minimal uplift occurred along the Pacific margin. On the contrary, new tectonic data and Quaternary surface 10Be dating highlight the presence of recently active deformation, incision and alluvial processes within the upper Andean forearc together with a regional uplift of the coastal zone. Additionally, the high obliquity observed in the northern Arica Bend region makes it an ideal target to discuss whether partitioning of the oblique convergence is accommodated by the neotectonic features that dissect the Quaternary forearc. Our goals are both to decipher the Quaternary tectonic and climatic processes shaping the hyperarid forearc along strike and across strike. Finally, we aim to quantify the respective influence of these factors in the overall uplift of the Western Andes. Indeed, sequences of pediment surfaces, landslide products, paleolake deposits and marine terraces found along the oblique Peruvian margin are a unique set of datable markers that can be used to quantify the rates of Quaternary processes. In this study, we focus on the southern Peru hyperarid Atacama area where regional surfaces and tectonic markers (scarps, folds, temporary streams and paleolake levels offsets…) are well preserved for the Quaternary timescale. Numerous landsliding events align on the major fault segments and reflect Plio-Pleistocene climatic and tectonic activity together with filled and strath terraces. As the present day sea-level is one of the highest levels recorded for Quaternary time span, any emerged marine terrace is preserved by tectonic coastal uplift. In particular, the geomorphic and chronologic correlation between marine and

  1. Arsenic control during aquifer storage recovery cycle tests in the Floridan Aquifer.

    Science.gov (United States)

    Mirecki, June E; Bennett, Michael W; López-Baláez, Marie C

    2013-01-01

    Implementation of aquifer storage recovery (ASR) for water resource management in Florida is impeded by arsenic mobilization. Arsenic, released by pyrite oxidation during the recharge phase, sometimes results in groundwater concentrations that exceed the 10 µg/L criterion defined in the Safe Drinking Water Act. ASR was proposed as a major storage component for the Comprehensive Everglades Restoration Plan (CERP), in which excess surface water is stored during the wet season, and then distributed during the dry season for ecosystem restoration. To evaluate ASR system performance for CERP goals, three cycle tests were conducted, with extensive water-quality monitoring in the Upper Floridan Aquifer (UFA) at the Kissimmee River ASR (KRASR) pilot system. During each cycle test, redox evolution from sub-oxic to sulfate-reducing conditions occurs in the UFA storage zone, as indicated by decreasing Fe(2+) /H2 S mass ratios. Arsenic, released by pyrite oxidation during recharge, is sequestered during storage and recovery by co-precipitation with iron sulfide. Mineral saturation indices indicate that amorphous iron oxide (a sorption surface for arsenic) is stable only during oxic and sub-oxic conditions of the recharge phase, but iron sulfide (which co-precipitates arsenic) is stable during the sulfate-reducing conditions of the storage and recovery phases. Resultant arsenic concentrations in recovered water are below the 10 µg/L regulatory criterion during cycle tests 2 and 3. The arsenic sequestration process is appropriate for other ASR systems that recharge treated surface water into a sulfate-reducing aquifer. Published 2012. This article is a U.S. Government work and is in the public domain in the USA.

  2. Geochemical processes in a calcareous sandstone aquifer during managed aquifer recharge with desalinated seawater

    Science.gov (United States)

    Ganot, Yonatan; Russak, Amos; Siebner, Hagar; Bernstein, Anat; Katz, Yoram; Guttman, Jospeh; Kurtzman, Daniel

    2017-04-01

    In the last three years we monitor Managed Aquifer Recharge (MAR) of post-treated desalinated seawater (PTDES) in an infiltration pond, at the Menashe site that overlies the northern part of the Israeli Coastal Aquifer. The PTDES are stabilized with CaCO3 during post-treatment in the desalination plant and their chemical composition differs from those of any other water recharged to the aquifer and of the natural groundwater. We use suction cups in the unsaturated zone, shallow observation wells within the pond and production wells that encircles the MAR Menashe site, to study the geochemical processes during MAR with PTDES. Ion-enrichment (remineralization) of the recharged water was observed in both unsaturated zone and shallow observation wells samples. Enrichment occurs mainly in the first few meters below the pond surface by ion-exchange processes. Mg2+ enrichment is most prominent due to its deficiency in the PTDES. It is explained by ion-exchange with Ca2+, as the PTDES (enriched with Ca2+) infiltrates through a calcareous-sandstone aquifer with various amount of adsorbed Mg2+ (3-27 meq/kg). Hence, the higher concentration of Ca+2 in the PTDES together with its higher affinity to the sediments promotes the release of Mg2+ ions to the recharged water. Water isotopes analysis of the production wells were used to estimate residence time and mixing with local groundwater. At the end of 2016, it was found that the percentage of PTDES in adjacent down-gradient production wells was around 10%, while more distant or up-gradient wells show no mixing with PTDES. The distinct isotope contrast between the recharged desalinated seawater (δ2H=+11.2±0.2‰) and the local groundwater (δ2H ranged from -22.7 to -16.7‰) is a promising tool to evaluate future mixing processes at the Menshae MAR site. Using the Menashe MAR system for remineralization could be beneficial as a primary or complementary post-treatment technique. However, the sustainability of this process is

  3. Behaviour and fate of nine recycled water trace organics during managed aquifer recharge in an aerobic aquifer

    Science.gov (United States)

    Patterson, B. M.; Shackleton, M.; Furness, A. J.; Bekele, E.; Pearce, J.; Linge, K. L.; Busetti, F.; Spadek, T.; Toze, S.

    2011-03-01

    The fate of nine trace organic compounds was evaluated during a 12 month large-scale laboratory column experiment. The columns were packed with aquifer sediment and evaluated under natural aerobic and artificial anaerobic geochemical conditions, to assess the potential for natural attenuation of these compounds during aquifer passage associated with managed aquifer recharge (MAR). The nine trace organic compounds were bisphenol A (BPA), 17β-estradiol (E2), 17α-ethynylestradiol (EE2), N-nitrosodimethylamine (NDMA), N-nitrosomorpholine (NMOR), carbamazepine, oxazepam, iohexol and iodipamide. In the low organic carbon content Spearwood sediment, all trace organics were non-retarded with retardation coefficients between 1.0 and 1.2, indicating that these compounds would travel at near groundwater velocities within the aquifer. The natural aerobic geochemical conditions provided a suitable environment for the rapid degradation for BPA, E2, iohexol (half life NDMA and NMOR) did not degrade under either aerobic or anaerobic aquifer geochemical conditions (half life > 50 days). Field-based validation experiments with carbamazepine and oxazepam also showed no degradation. If persistent trace organics are present in recycled waters at concentrations in excess of their intended use, natural attenuation during aquifer passage alone may not result in extracted water meeting regulatory requirements. Additional pre treatment of the recycled water would therefore be required.

  4. Uranium series geochemistry in aquifers: quantification of transport mechanisms of uranium and daughter products: the chalk aquifer (Champagne, France)

    International Nuclear Information System (INIS)

    Hubert, A.

    2005-09-01

    With the increase of contaminant flux of radionuclides in surface environment (soil, river, aquifer...), there is a need to understand and model the processes that control the distribution of uranium and its daughter products during transport within aquifers. We have used U-series disequilibria as an analogue for the transport of uranium and its daughter products in aquifer to understand such mechanisms. The measurements of uranium ( 234 U et 238 U), thorium ( 230 Th et 232 Th), 226 Ra and 222 Rn isotopes in the solid and liquid phases of the chalk aquifer in Champagne (East of France) allows us to understand the processes responsible for fractionation within the uranium decay chain. Fractionations are induced by physical and chemical properties of the elements (leaching, adsorption) but also by radioactive properties (recoil effect during α-decay). For the first time a comprehensive sampling of the solid phase has been performed, allowing quantifying mechanisms responsible for the long term evolution of the aquifer. A non steady state 1D model has been developed which takes into account leaching, adsorption processes as well as radioactive filiation and α-recoil effect. Retardation coefficients have been calculated for uranium, thorium and radium. The aquifer is characterised by a double porosity, and the contribution of fracture and matrix porosity on the water/rock interaction processes has been estimated. (author)

  5. Behaviour and fate of nine recycled water trace organics during managed aquifer recharge in an aerobic aquifer.

    Science.gov (United States)

    Patterson, B M; Shackleton, M; Furness, A J; Bekele, E; Pearce, J; Linge, K L; Busetti, F; Spadek, T; Toze, S

    2011-03-25

    The fate of nine trace organic compounds was evaluated during a 12month large-scale laboratory column experiment. The columns were packed with aquifer sediment and evaluated under natural aerobic and artificial anaerobic geochemical conditions, to assess the potential for natural attenuation of these compounds during aquifer passage associated with managed aquifer recharge (MAR). The nine trace organic compounds were bisphenol A (BPA), 17β-estradiol (E2), 17α-ethynylestradiol (EE2), N-nitrosodimethylamine (NDMA), N-nitrosomorpholine (NMOR), carbamazepine, oxazepam, iohexol and iodipamide. In the low organic carbon content Spearwood sediment, all trace organics were non-retarded with retardation coefficients between 1.0 and 1.2, indicating that these compounds would travel at near groundwater velocities within the aquifer. The natural aerobic geochemical conditions provided a suitable environment for the rapid degradation for BPA, E2, iohexol (half life aquifer geochemical conditions (half life >50days). Field-based validation experiments with carbamazepine and oxazepam also showed no degradation. If persistent trace organics are present in recycled waters at concentrations in excess of their intended use, natural attenuation during aquifer passage alone may not result in extracted water meeting regulatory requirements. Additional pre treatment of the recycled water would therefore be required. Crown Copyright © 2010. Published by Elsevier B.V. All rights reserved.

  6. Ground-water levels in aquifers used for residential supply, Campton Township, Kane County, Illinois

    Science.gov (United States)

    Kay, Robert T.; Kraske, Kurt A.

    1996-01-01

    The U.S. Geological Survey, in cooperation with the Campton Township Board of Trustees, measured water levels in the aquifers used for residential supply in Campton Township, Kane County, Illinois. Aquifers used for residential supply are the shallow and deep aquifers in the glacial drift, composed of unconsolidated sand and gravels; the Alexandrian-Maquoketa aquifer, composed of dolomite and shale of the Alexandrian Series and the Maquoketa Group; the Galena-Platteville aquifer, composed of dolomite of the Platteville and Galena Groups; and the Ancell aquifer, composed of sandstones of the Glenwood Formation and the St. Peter Sanstone. Water-level altitudes in the shallow drift aquifers generally follow surface topography. Analysis of water-level data does not clearly indicate overutilization of these aquifers. Water-level altitudes in the deep drift aquifers decrease from west to east. Comparison of historical depth to water measurements with current (1995) measurements indicates large decreases in water levels in some areas. The deep drift aquifers may be overutilized at these locations. Water-level altitudes in the Alexandrian-Maquoketa aquifer generally decrease from west to east. The potentiometric surface of the aquifer follows the bedrock-surface topography in some locations. Localized low water-level altitudes and large decreases in water levels indicate the Alexandrian-Maquoketa aquifer is overutilized in several areas. Water-level altitudes in the wells finished in the Galena- Platteville aquifer vary by more than 300 feet. Large decreases in water levels in wells finished in the Galena-Platteville aquifer indicate the Galena-Platteville and Alexandrian-Maquoketa aquifers are overutilized in the northern part of the township. Water-level altitudes in the wells finished in the Ancell aquifer are also highly variable. There is no indication that the Ancell aquifer is overutilized.

  7. Late Quaternary Megafaunal Extinctions in Northern Eurasia: Latest Results

    Science.gov (United States)

    Stuart, Anthony

    2010-05-01

    Anthony J. Stuart1 & Adrian M. Lister2 1 Biological and Biomedical Sciences, Durham University, South Road, Durham DH1 3LE, UK. Email: tony.s@megafauna.org.uk 2 Department of Palaeontology, The Natural History Museum, Cromwell Road, London SW7 5BD, UK. Email: a.lister@nhm.ac.uk. The global extinction of many spectacular species of megafauna (large terrestrial mammals, together with a few large reptiles and birds) within the last c. 50,000 years (Late Quaternary) has been attributed on the one hand to ‘overkill' by human hunters and on the other to environmental change. However, in spite of more than half a century of active interest and research the issue remains unresolved, largely because there are insufficient dated records of megafaunal species for most parts of the world. Northern Eurasia is an especially fruitful region in which to research megafaunal extinctions as it has a wealth of megafaunal material and crucially most extinctions occurred well within the range of radiocarbon dating. Our approach, in a series of projects over the last decade funded by the UK Natural Environment Research Council (NERC), involves amassing radiocarbon dates made directly on megafaunal material from across the entire region: a) by submitting a substantial number of samples (so far c. 500 dates) for AMS dating at Oxford (ORAU); b) obtaining AMS dates from colleagues working on aDNA projects; and c) carefully screening (‘auditing') dates from the literature. The dates (calibrated using OxCal) are plotted as time-sliced maps and as chronological/geographical charts. In our previous work we targeted a range of extinct species from Northern Eurasia: woolly mammoth, woolly rhinoceros, giant deer, cave bear (in collaboration with Martina Pacher), cave lion, and spotted hyaena (which survives today only in Sub-Saharan Africa). By this means we have established a reliable chronology for these extinctions which we are able to compare with the climatic, vegetational and

  8. Development of Managed Aquifer Recharge in China

    Energy Technology Data Exchange (ETDEWEB)

    Wang, W.; Zhou, Y.; Sun, X.; Wang, W.

    2014-10-01

    China has a long history in managed aquifer recharge (MAR). The historic development can be divided into 4 stages based on a summary of typical MAR projects. The first stage is MAR applied to agricultural production, the second is MAR applied to industrial production and alleviation of agricultural problems, the third is MAR applied to ecological protection and the increase in urban water supplies, and the fourth is multi-source MAR. In addition, geothermal reinjection and ground source heat pumps are also effective uses of MAR. Nevertheless, the MAR framework is defective, there is a lack of water quality studies, and the recharge rate of most projects is low. However, China has achieved a great effect on industrial and agricultural production, ecological protection, drinking water supplies and urban reclaimed water reuse, amongst others. But there are still many issues to be improved. A feasible, convenient and economic technique of MAR which fits local hydrogeological conditions needs to be developed and guidelines for both MARs and management regulations to ensure the successful running of MAR projects also need to be established. MAR will make a great difference to improving potable water quality, alleviating geological hazards, long distance water diversion, urban water supplies, agriculture irrigation, etc. (Author)

  9. DNAPL migration in a coastal plain aquifer

    International Nuclear Information System (INIS)

    DiGuiseppi, W.H.; Jung, A.D.

    1995-01-01

    Soil and ground water at the Dover Gas Light Superfund Site, a former manufactured gas plant (1859 to 1948), are contaminated with polynuclear aromatic hydrocarbons and volatile organic compounds. Contaminants of concern include light aromatics, such as benzene, toluene, ethylbenzene, and xylenes (BTEX), and heavy aromatics, including naphthalene, acenaphthylene, phenanthrene, and benzo(a)pyrene. Although ground-water contaminant levels are elevated near the site, only naphthalene and acenaphthylene are present within an order of magnitude of their solubility limits, indicating the possibility of dense non-aqueous phase liquids (DNAPL) in the subsurface. The unconfined Columbia Aquifer, which is characterized by interfingering and discontinuous sand, silt, and clay Coastal Plain deposits, overlies a clay aquitard at a depth of 60 feet. The ground water beneath the intermediate clay horizon exhibited little or no contamination, even immediately downgradient from the site. The relationship between the more permeable granular sand horizons and the less permeable interfingering clay zones controls the migration of both the aqueous-phase contamination and the DNAPL. A detailed horizontal and vertical characterization of the subsurface stratigraphy was critical to the accurate interpretation of the extent and magnitude of contamination and the identification and delineation of DNAPL zones

  10. Soil aquifer treatment using advanced primary effluent

    KAUST Repository

    Sharma, Saroj K.; Hussen, Mustefa; Amy, Gary L.

    2011-01-01

    Soil aquifer treatment (SAT) using primary effluent (PE) is an attractive option for wastewater treatment and reuse in many developing countries with no or minimal wastewater treatment. One of the main limitations of SAT of PE is rapid clogging of the infiltration basin due to high suspended solid concentrations. Some pre-treatment of PE before infiltration is likely to reduce this limitation, improve performance of SAT and help to implement this technology effectively. The effects of three pre-treatment options namely sedimentation (SED), coagulation (COAG) and horizontal roughing filtration (HRF) on SAT were analyzed by conducting laboratory-scale batch and soil column experiments. The sedimentation and coagulation pre-treatments led to less head loss development and reduction of clogging effect. The head loss development in soil column using PE + COAG and PE + SED was reduced by 85 and 72%, respectively, compared to PE alone without any pretreatment. The overall dissolved organic carbon (DOC) removal of pre-treatments and soil column collectively were 34, 44, 51 and 43.5% for PE without any pre-treatment, PE + SED, PE+ COAG and PE + HRF, respectively. Coagulation pre-treatment of PE was found to be the most effective option in terms of suspended solids, DOC and nitrogen removal. Sedimentation pre-treatment of PE could be attractive where land is relatively less expensive for the construction of sedimentation basins. © IWA Publishing 2011.

  11. Modeling contaminant plumes in fractured limestone aquifers

    DEFF Research Database (Denmark)

    Mosthaf, Klaus; Brauns, Bentje; Fjordbøge, Annika Sidelmann

    Determining the fate and transport of contaminant plumes from contaminated sites in limestone aquifers is important because they are a major drinking water resource. This is challenging because they are often heavily fractured and contain chert layers and nodules, resulting in a complex transport...... model. The paper concludes with recommendations on how to identify and employ suitable models to advance the conceptual understanding and as decision support tools for risk assessment and the planning of remedial actions....... behavior. Improved conceptual models are needed for this type of site. Here conceptual models are developed by combining numerical models with field data. Several types of fracture flow and transport models are available for the modeling of contaminant transport in fractured media. These include...... the established approaches of the equivalent porous medium, discrete fracture and dual continuum models. However, these modeling concepts are not well tested for contaminant plume migration in limestone geologies. Our goal was to develop and evaluate approaches for modeling the transport of dissolved contaminant...

  12. Soil aquifer treatment using advanced primary effluent

    KAUST Repository

    Sharma, Saroj K.

    2011-08-01

    Soil aquifer treatment (SAT) using primary effluent (PE) is an attractive option for wastewater treatment and reuse in many developing countries with no or minimal wastewater treatment. One of the main limitations of SAT of PE is rapid clogging of the infiltration basin due to high suspended solid concentrations. Some pre-treatment of PE before infiltration is likely to reduce this limitation, improve performance of SAT and help to implement this technology effectively. The effects of three pre-treatment options namely sedimentation (SED), coagulation (COAG) and horizontal roughing filtration (HRF) on SAT were analyzed by conducting laboratory-scale batch and soil column experiments. The sedimentation and coagulation pre-treatments led to less head loss development and reduction of clogging effect. The head loss development in soil column using PE + COAG and PE + SED was reduced by 85 and 72%, respectively, compared to PE alone without any pretreatment. The overall dissolved organic carbon (DOC) removal of pre-treatments and soil column collectively were 34, 44, 51 and 43.5% for PE without any pre-treatment, PE + SED, PE+ COAG and PE + HRF, respectively. Coagulation pre-treatment of PE was found to be the most effective option in terms of suspended solids, DOC and nitrogen removal. Sedimentation pre-treatment of PE could be attractive where land is relatively less expensive for the construction of sedimentation basins. © IWA Publishing 2011.

  13. Commercialization of aquifer thermal energy storage technology

    Energy Technology Data Exchange (ETDEWEB)

    Hattrup, M.P.; Weijo, R.O.

    1989-09-01

    Pacific Northwest Laboratory (PNL) conducted this study for the US Department of Energy's (DOE) Office of Energy Storage and Distribution. The purpose of the study was to develop and screen a list of potential entry market applications for aquifer thermal energy storage (ATES). Several initial screening criteria were used to identify promising ATES applications. These include the existence of an energy availability/usage mismatch, the existence of many similar applications or commercial sites, the ability to utilize proven technology, the type of location, market characteristics, the size of and access to capital investment, and the number of decision makers involved. The in-depth analysis identified several additional screening criteria to consider in the selection of an entry market application. This analysis revealed that the best initial applications for ATES are those where reliability is acceptable, and relatively high temperatures are allowable. Although chill storage was the primary focus of this study, applications that are good candidates for heat ATES were also of special interest. 11 refs., 3 tabs.

  14. The economics of aquifer storage recovery technology

    International Nuclear Information System (INIS)

    David, R.; Pyne, G.

    2014-01-01

    Aquifer storage recovery (ASR) technology is increasingly being utilized around the world for storing water underground through one or more wells during wet months and other times when water is available for storage. The water is then recovered from the same wells when needed to meet a growing variety of water supply objectives. The economics of ASR constitute the principal reason for its increasing utilization. ASR unit capital costs are typically less than half those of other water supply and water storage alternatives. Unit operating costs are usually only slightly greater than for conventional production well-fields. Marginal costs for ASR storage and recovery provide a powerful tool for making more efficient use of existing infrastructure, providing water supply sustainability and reliability at relatively low cost. The opportunity exists for a careful analysis of the net present value of ASR well-fields, addressing not only the associated capital and operating costs but also the value of the benefits achieved for each of the water supply objectives at each site. (Author)

  15. The economics of aquifer storage recovery technology

    Energy Technology Data Exchange (ETDEWEB)

    David, R.; Pyne, G.

    2014-10-01

    Aquifer storage recovery (ASR) technology is increasingly being utilized around the world for storing water underground through one or more wells during wet months and other times when water is available for storage. The water is then recovered from the same wells when needed to meet a growing variety of water supply objectives. The economics of ASR constitute the principal reason for its increasing utilization. ASR unit capital costs are typically less than half those of other water supply and water storage alternatives. Unit operating costs are usually only slightly greater than for conventional production well-fields. Marginal costs for ASR storage and recovery provide a powerful tool for making more efficient use of existing infrastructure, providing water supply sustainability and reliability at relatively low cost. The opportunity exists for a careful analysis of the net present value of ASR well-fields, addressing not only the associated capital and operating costs but also the value of the benefits achieved for each of the water supply objectives at each site. (Author)

  16. Fertilizers mobilization in alluvial aquifer: laboratory experiments

    Science.gov (United States)

    Mastrocicco, M.; Colombani, N.; Palpacelli, S.

    2009-02-01

    In alluvial plains, intensive farming with conspicuous use of agrochemicals, can cause land pollution and groundwater contamination. In central Po River plain, paleo-channels are important links between arable lands and the underlaying aquifer, since the latter is often confined by clay sediments that act as a barrier against contaminants migration. Therefore, paleo-channels are recharge zones of particular interest that have to be protected from pollution as they are commonly used for water supply. This paper focuses on fertilizer mobilization next to a sand pit excavated in a paleo-channel near Ferrara (Italy). The problem is approached via batch test leaking and columns elution of alluvial sediments. Results from batch experiments showed fast increase in all major cations and anions, suggesting equilibrium control of dissolution reactions, limited availability of solid phases and geochemical homogeneity of samples. In column experiments, early elution and tailing of all ions breakthrough was recorded due to preferential flow paths. For sediments investigated in this study, dispersion, dilution and chemical reactions can reduce fertilizers at concentration below drinking standards in a reasonable time frame, provided fertilizer loading is halted or, at least, reduced. Thus, the definition of a corridor along paleo-channels is recommended to preserve groundwater quality.

  17. Depth of the base of the Jackson aquifer, based on geophysical exploration, southern Jackson Hole, Wyoming, USA

    Science.gov (United States)

    Nolan, Bernard T.; Campbell, David L.; Senterfit, Robert M.

    A geophysical survey was conducted to determine the depth of the base of the water-table aquifer in the southern part of Jackson Hole, Wyoming, USA. Audio-magnetotellurics (AMT) measurements at 77 sites in the study area yielded electrical-resistivity logs of the subsurface, and these were used to infer lithologic changes with depth. A 100-600ohm-m geoelectric layer, designated the Jackson aquifer, was used to represent surficial saturated, unconsolidated deposits of Quaternary age. The median depth of the base of the Jackson aquifer is estimated to be 200ft (61m), based on 62 sites that had sufficient resistivity data. AMT-measured values were kriged to predict the depth to the base of the aquifer throughout the southern part of Jackson Hole. Contour maps of the kriging predictions indicate that the depth of the base of the Jackson aquifer is shallow in the central part of the study area near the East and West Gros Ventre Buttes, deeper in the west near the Teton fault system, and shallow at the southern edge of Jackson Hole. Predicted, contoured depths range from 100ft (30m) in the south, near the confluences of Spring Creek and Flat Creek with the Snake River, to 700ft (210m) in the west, near the town of Wilson, Wyoming. Résumé Une campagne géophysique a été entreprise pour préciser la profondeur du mur de l'aquifère dans le secteur sud de Jackson Hole (Wyoming, États-Unis). Des mesures audio-magnétotelluriques (audio MT) sur 77 sites de ce secteur ont fourni des logs de résistivitéélectrique du sous-sol ; les variations de la lithologie en fonction de la profondeur en ont été déduites. Un niveau géoélectrique à 100-600ohm.m, dénommé "aquifère de Jackson", a servi à définir des dépôts superficiels quaternaires saturés en eau et non consolidés. La profondeur médiane de la base de l'aquifère de Jackson est de l'ordre de 61m, à partir des 62 sites ayant fourni suffisamment de données de résistivité. Les valeurs audio MT mesur

  18. Assessment of the groundwater chemistry of a complex aquifer system in the context of urbanization in Sub-Saharan Africa: case study in semiarid southwest Niger

    Science.gov (United States)

    Boubakar Hassane, A.; Favreau, G.; Leduc, C.; Ousmane, B.; Soumaila, A.

    2010-12-01

    reactions, and mixing by upward leakage from hard-rock semi-confined aquifers. Typically, water samples from aquifers formed by Precambrian altered hard-rock formations and Quaternary alluvial formations contain high amounts of bicarbonate, sodium, calcium and magnesium related to water-rock interaction and low flow in the aquifer. The chemistry of the groundwater in the Continental Terminal (CT3) sandy to clayey sandstone aquifer significantly differs from other groundwaters found in the altered and fissured hard rock aquifers. Higher levels of nitrate and sodium were observed in the CT3 aquifer due to contaminated recharge water. Nitrate is the main ionic contaminant and its content is seasonally or permanently above the World Health Organization guidelines for drinking water quality limit of 0.81 meq.L-1 in 44 % of sampled wells. As expected, samples from dug-wells located in the central city with numerous pollutant sources had the highest concentrations of leached elements indicating that land-use is the primary control on groundwater contamination.

  19. Ground-water quality of the surficial aquifer system and the upper Floridan Aquifer, Ocala National Forest and Lake County, Florida, 1990-99

    Science.gov (United States)

    Adamski, J.C.; Knowles, Leel

    2001-01-01

    Data from 217 ground-water samples were statistically analyzed to assess the water quality of the surficial aquifer system and Upper Floridan aquifer in the Ocala National Forest and Lake County, Florida. Samples were collected from 49 wells tapping the surficial aquifer system, 141 wells tapping the Upper Floridan aquifer, and from 27 springs that discharge water from the Upper Floridan aquifer. A total of 136 samples was collected by the U.S. Geological Survey from 1995 through 1999. These data were supplemented with 81 samples collected by the St. Johns River Water Management District and Lake County Water Resources Management from 1990 through 1998. In general, the surficial aquifer system has low concentrations of total dissolved solids (median was 41 milligrams per liter) and major ions. Water quality of the surficial aquifer system, however, is not homogeneous throughout the study area. Concentrations of total dissolved solids, many major ions, and nutrients are greater in samples from Lake County outside the Ocala National Forest than in samples from within the Forest. These results indicate that the surficial aquifer system in Lake County outside the Ocala National Forest probably is being affected by agricultural and (or) urban land-use practices. High concentrations of dissolved oxygen (less than 0.1 to 8.2 milligrams per liter) in the surficial aquifer system underlying the Ocala National Forest indicate that the aquifer is readily recharged by precipitation and is susceptible to surface contamination. Concentrations of total dissolved solids were significantly greater in the Upper Floridan aquifer (median was 182 milligrams per liter) than in the surficial aquifer system. In general, water quality of the Upper Floridan aquifer was homogeneous, primarily being a calcium or calciummagnesium- bicarbonate water type. Near the St. Johns River, the water type of the Upper Floridan aquifer is sodium-chloride, corresponding to an increase in total dissolved

  20. Tertiary and Quaternary sedimentation in a part of the Duero Basin Palencia, (Spain)

    NARCIS (Netherlands)

    Mabesoone, J.M.

    1959-01-01

    Sediments in the foreland of a mountain chain are sometimes suited to reconstitute the conditions in these mountains at the time of deposition of the sediments. The present study gives the results of a sedimentological investigation of the Tertiary and Quaternary deposits in a part of the Duero

  1. Coating of adenovirus type 5 with polymers containing quaternary amines prevents binding to blood components

    Czech Academy of Sciences Publication Activity Database

    Šubr, Vladimír; Kostka, Libor; Selby-Milic, T.; Fisher, K.; Ulbrich, Karel; Seymour, W.; Carlisle, R. C.

    2009-01-01

    Roč. 135, č. 2 (2009), s. 152-158 ISSN 0168-3659 R&D Projects: GA AV ČR KJB400500803 EU Projects: European Commission(XE) 512087 - GIANT Institutional research plan: CEZ:AV0Z40500505 Keywords : quaternary ammonium * HPMA * adenovirus Subject RIV: CD - Macromolecular Chemistry Impact factor: 5.949, year: 2009

  2. Numerical modelling of Quaternary terrace staircase formation in the Ebro foreland basin, southern Pyrenees, NE Iberia

    NARCIS (Netherlands)

    van Balen, R.T.; Stange, K.M.; Cloetingh, S.A.P.L.; Garcia-Castellanos, D.

    2016-01-01

    The southern foreland basin of the Pyrenees (Ebro basin) is an exorheic drainage basin since Late Miocene times. Remnants of an early exorheic Ebro drainage system are not preserved, but morphology provides evidence for the Pliocene–Quaternary drainage development. The incision history of the Ebro

  3. Different virucidal activities of hyperbranched quaternary ammonium coatings on poliovirus and influenza virus

    NARCIS (Netherlands)

    Tuladhar, E.; Koning, de M.C.; Fundeanu, I.; Beumer, R.R.; Duizer, E.

    2012-01-01

    Virucidal activity of immobilized quaternary ammonium compounds (IQACs) coated onto glass and plastic surfaces was tested against enveloped influenza A (H1N1) virus and nonenveloped poliovirus Sabin1. The IQACs tested were virucidal against the influenza virus within 2 min, but no virucidal effect

  4. Late Quaternary stratigraphy and depositional history of the Long Island Sound basin

    Science.gov (United States)

    Lewis, Ralph S.; Stone, Janet R.

    1991-01-01

    The stratigraphy of Late Quaternary geologic units beneath Long Island Sound (LIS) is interpreted from 3,500 km of high-resolution, seismic-reflection profiles supplemented by vibracore data. Knowledge gained from onshore regional geologic studies and previous offshore investigations is also incorporated in these interpretations.

  5. Epoxidation of Alkenes with Aqueous Hydrogen Peroxide and Quaternary Ammonium Bicarbonate Catalysts

    DEFF Research Database (Denmark)

    Mielby, Jerrik Jørgen; Kegnæs, Søren

    2013-01-01

    A range of solid and liquid catalysts containing bicarbonate anions were synthesised and tested for the epoxidation of alkenes with aqueous hydrogen peroxide. The combination of bicarbonate anions and quaternary ammonium cations opens up for new catalytic systems that can help to overcome...

  6. External controls on Quaternary fluvial incision and terrace formation at the Segre River, Southern Pyrenees

    NARCIS (Netherlands)

    Stange, K.M.; van Balen, R.T.; Vandenberghe, J.; Peña, J.L.; Sancho, C.

    2013-01-01

    Focusing on climatic- and structural (tectonic) controls, we aim to determine their relative importance for the (Pliocene to Quaternary) fluvial landscape evolution in the Southern Pyrenees foreland. We investigate the Segre River, which is one of the major streams of the Southern Pyrenees that

  7. Mechanism of Osmotic Activation of the Quaternary Ammonium Compound Transporter (QacT) of Lactobacillus plantarum

    NARCIS (Netherlands)

    Glaasker, Erwin; Heuberger, Esther H.M.L.; Konings, Wil N.; Poolman, Bert

    1998-01-01

    The accumulation of quaternary ammonium compounds in Lactobacillus plantarum is mediated via a single transport system with a high affinity for glycine betaine (apparent Km of 18 μM) and carnitine and a low affinity for proline (apparent Km of 950 μM) and other analogues. Mutants defective in the

  8. Diverse range dynamics and dispersal routes of plants on the Tibetan Plateau during the late Quaternary.

    Directory of Open Access Journals (Sweden)

    Haibin Yu

    Full Text Available Phylogeographical studies have suggested that several plant species on the Tibetan Plateau (TP underwent recolonization during the Quaternary and may have had distinct range dynamics in response to the last glacial. To further test this hypothesis and locate the possible historical dispersal routes, we selected 20 plant species from different parts of the TP and modeled their geographical distributions over four time periods using species distribution models (SDMs. Furthermore, we applied the least-cost path method together with SDMs and shared haplotypes to estimate their historical dispersal corridors. We identified three general scenarios of species distribution change during the late Quaternary: the 'contraction-expansion' scenario for species in the northeastern TP, the 'expansion-contraction' scenario for species in the southeast and the 'stable' scenario for widespread species. During the Quaternary, we identified that these species were likely to recolonize along the low-elevation valleys, huge mountain ranges and flat plateau platform (e.g. the Yarlung Zangbo Valley and the Himalaya. We inferred that Quaternary cyclic glaciations along with the various topographic and climatic conditions of the TP could have resulted in the diverse patterns of range shift and dispersal of Tibetan plant species. Finally, we believe that this study would provide valuable insights for the conservation of alpine species under future climate change.

  9. Auxotrophy-stimulated sensitivity to quaternary ammonium salts and its relation to active transport in yeast

    International Nuclear Information System (INIS)

    Lachowicz, T.M.; Oblak, E.; Piatkowski, J.

    1992-01-01

    In previous studies we have observed that auxotrophic mutants of yeast were much more sensitive to quaternary ammonium salts than the corresponding isogenic wild type strains. The super sensitivity of the auxotrophs seems to be a characteristic feature of yeast and yeast-like microorganisms: the level of sensitivity of the quaternary ammonium salts of the bacterial auxotrophs and their original prototrophic forms appeared to be the same. The super sensitivity of yeast auxotrophs disappeared on minimal media with ammonium as a nitrogen source. In this report there are presented the data indicating that enrichment of the minimal medium with arginine restores the super sensitivity of auxotrophic yeast mutants to the quaternary ammonium salts. The results of amino-acid transport into the auxotrophic yeast cells treated with a quaternary ammonium salt in the presence and absence of arginine are given. A working hypothesis of the mechanism of these salts action as a specific inhibition of nutrient transport is discussed. (author). 19 refs, 3 figs, 8 figs

  10. High order quaternary arrangement confers increased structural stability to Brucella Spp. lumazine synthase

    Energy Technology Data Exchange (ETDEWEB)

    Zylberman, V.; Craig, P.O.; Klinke, S.; Cauerhff, A.; Goldbaum, F.A. [Instituto Leloir, Buenos Aires (Argentina); Braden, B.C. [Bowie State Univ., Maryland (United States)

    2004-07-01

    The penultimate step in the pathway of riboflavin biosynthesis is catalyzed by the enzyme lumazine synthase (LS). One of the most distinctive characteristics of this enzyme is the structural quaternary divergence found in different species. The protein exists as pentameric and icosahedral forms, built from practically the same structural monomeric unit. The pentameric structure is formed by five 18 kDa monomers, each extensively contacting neighboring monomers. The icosahedral structure consists of 60 LS monomers arranged as twelve pentamers giving rise to a capsid exhibiting icosahedral 532 symmetry. In all lumazine synthases studied, the topologically equivalent active sites are located at the interfaces between adjacent subunits in the pentameric modules. The Brucella spp. lumazine synthase (BLS) sequence clearly diverges from pentameric and icosahedral enzymes. This unusual divergence prompted to further investigate on its quaternary arrangement. In the present work, we demonstrate by means of solution Light Scattering and X-ray structural analyses that BLS assembles as a very stable dimer of pentamers representing a third category of quaternary assembly for lumazine synthases. We also describe by spectroscopic studies the thermodynamic stability of this oligomeric protein, and postulate a mechanism for dissociation/unfolding of this macromolecular assembly. The higher molecular order of BLS increases its stability 20 deg C compared to pentameric lumazine synthases. The decameric arrangement described in this work highlights the importance of quaternary interactions in the stabilization of proteins. (author)

  11. High order quaternary arrangement confers increased structural stability to Brucella Spp. lumazine synthase

    International Nuclear Information System (INIS)

    Zylberman, V.; Craig, P.O.; Klinke, S.; Cauerhff, A.; Goldbaum, F.A.; Braden, B.C.

    2004-01-01

    The penultimate step in the pathway of riboflavin biosynthesis is catalyzed by the enzyme lumazine synthase (LS). One of the most distinctive characteristics of this enzyme is the structural quaternary divergence found in different species. The protein exists as pentameric and icosahedral forms, built from practically the same structural monomeric unit. The pentameric structure is formed by five 18 kDa monomers, each extensively contacting neighboring monomers. The icosahedral structure consists of 60 LS monomers arranged as twelve pentamers giving rise to a capsid exhibiting icosahedral 532 symmetry. In all lumazine synthases studied, the topologically equivalent active sites are located at the interfaces between adjacent subunits in the pentameric modules. The Brucella spp. lumazine synthase (BLS) sequence clearly diverges from pentameric and icosahedral enzymes. This unusual divergence prompted to further investigate on its quaternary arrangement. In the present work, we demonstrate by means of solution Light Scattering and X-ray structural analyses that BLS assembles as a very stable dimer of pentamers representing a third category of quaternary assembly for lumazine synthases. We also describe by spectroscopic studies the thermodynamic stability of this oligomeric protein, and postulate a mechanism for dissociation/unfolding of this macromolecular assembly. The higher molecular order of BLS increases its stability 20 deg C compared to pentameric lumazine synthases. The decameric arrangement described in this work highlights the importance of quaternary interactions in the stabilization of proteins. (author)

  12. 40 CFR 721.9075 - Quaternary ammonium salt of fluorinated alkylaryl amide.

    Science.gov (United States)

    2010-07-01

    ... fluorinated alkylaryl amide. 721.9075 Section 721.9075 Protection of Environment ENVIRONMENTAL PROTECTION... amide. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as quaternary ammonium salt of fluorinated alkylaryl amide (PMN No. P-92-688) is...

  13. QuaBingo: A Prediction System for Protein Quaternary Structure Attributes Using Block Composition

    Directory of Open Access Journals (Sweden)

    Chi-Hua Tung

    2016-01-01

    Full Text Available Background. Quaternary structures of proteins are closely relevant to gene regulation, signal transduction, and many other biological functions of proteins. In the current study, a new method based on protein-conserved motif composition in block format for feature extraction is proposed, which is termed block composition. Results. The protein quaternary assembly states prediction system which combines blocks with functional domain composition, called QuaBingo, is constructed by three layers of classifiers that can categorize quaternary structural attributes of monomer, homooligomer, and heterooligomer. The building of the first layer classifier uses support vector machines (SVM based on blocks and functional domains of proteins, and the second layer SVM was utilized to process the outputs of the first layer. Finally, the result is determined by the Random Forest of the third layer. We compared the effectiveness of the combination of block composition, functional domain composition, and pseudoamino acid composition of the model. In the 11 kinds of functional protein families, QuaBingo is 23% of Matthews Correlation Coefficient (MCC higher than the existing prediction system. The results also revealed the biological characterization of the top five block compositions. Conclusions. QuaBingo provides better predictive ability for predicting the quaternary structural attributes of proteins.

  14. Species-specific responses of Late Quaternary megafauna to climate and humans

    DEFF Research Database (Denmark)

    Lorenzen, Eline; Nogues, David Bravo; Orlando, Ludovic Antoine Alexandre

    2011-01-01

    Despite decades of research, the roles of climate and humans in driving the dramatic extinctions of large-bodied mammals during the Late Quaternary period remain contentious. Here we use ancient DNA, species distribution models and the human fossil record to elucidate how climate and humans shape...

  15. Antibacterial Activity of Orthodontic Cement Containing Quaternary Ammonium Polyethylenimine Nanoparticles Adjacent to Orthodontic Brackets

    OpenAIRE

    Eldad Sharon; Revital Sharabi; Adi Eden; Asher Zabrovsky; Gilad Ben-Gal; Esi Sharon; Yoav Pietrokovski; Yael Houri-Haddad; Nurit Beyth

    2018-01-01

    Enamel demineralization is a common problem found in patients using orthodontic devices, such as orthodontic braces. It was found that Streptoccocus mutans growth increases adjacent to orthodontic devices, which may result in caries development. Incorporated antibacterial quaternary ammonium polyethylenimine (QPEI) nanoparticles were previously shown to be highly efficacious against various bacteria. Combining antibacterial materials in orthodontic cement may be advantageous to prevent bacter...

  16. Phytolith analysis in fluvial quaternary sediment (San Salvador and Palmar formation) Uruguay river and Argentina eastern

    International Nuclear Information System (INIS)

    Patterer, N.; Passeggi, E.; Zucol, A.; Brea, M.; Krohling, D.

    2012-01-01

    This work is about two microfossils fluvial units deposited by the Uruguay river during the Quaternary. These are San Salvador and Palmar formation (Plio-Pleistocene - Upper Pleistocene).The Palmar formation is a band of 4-15 km along the right bank of the Uruguay river outcropping from the eastern provinces of Corrientes and Entre Rios, to Concepcion del Uruguay

  17. Quaternary phosphorites from the continental margin off Chennai, southeast India: Analogs of ancient phosphate stromatolites

    Digital Repository Service at National Institute of Oceanography (India)

    Rao, V.P.; Rao, K.M.; Raju, D.S.N.

    . The microbial mats were formed on the outer shelf, most probably during conditions of low sea level in the Quaternary, and microbial processes played a major role in direct phosphatization of these mats. The primary phosphorus source seems to have been...

  18. Poly(3,4-ethylenedioxythiophene)-Poly(styrenesulfonate) Interlayer Insertion Enables Organic Quaternary Memory.

    Science.gov (United States)

    Cheng, Xue-Feng; Hou, Xiang; Qian, Wen-Hu; He, Jing-Hui; Xu, Qing-Feng; Li, Hua; Li, Na-Jun; Chen, Dong-Yun; Lu, Jian-Mei

    2017-08-23

    Herein, for the first time, quaternary resistive memory based on an organic molecule is achieved via surface engineering. A layer of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT-PSS) was inserted between the indium tin oxide (ITO) electrode and the organic layer (squaraine, SA-Bu) to form an ITO/PEDOT-PSS/SA-Bu/Al architecture. The modified resistive random-access memory (RRAM) devices achieve quaternary memory switching with the highest yield (∼41%) to date. Surface morphology, crystallinity, and mosaicity of the deposited organic grains are greatly improved after insertion of a PEDOT-PSS interlayer, which provides better contacts at the grain boundaries as well as the electrode/active layer interface. The PEDOT-PSS interlayer also reduces the hole injection barrier from the electrode to the active layer. Thus, the threshold voltage of each switching is greatly reduced, allowing for more quaternary switching in a certain voltage window. Our results provide a simple yet powerful strategy as an alternative to molecular design to achieve organic quaternary resistive memory.

  19. Artificial Intelligence-Based Models for the Optimal and Sustainable Use of Groundwater in Coastal Aquifers

    Science.gov (United States)

    Sreekanth, J.; Datta, Bithin

    2011-07-01

    Overexploitation of the coastal aquifers results in saltwater intrusion. Once saltwater intrusion occurs, it involves huge cost and long-term remediation measures to remediate these contaminated aquifers. Hence, it is important to have strategies for the sustainable use of coastal aquifers. This study develops a methodology for the optimal management of saltwater intrusion prone aquifers. A linked simulation-optimization-based management strategy is developed. The methodology uses genetic-programming-based models for simulating the aquifer processes, which is then linked to a multi-objective genetic algorithm to obtain optimal management strategies in terms of groundwater extraction from potential well locations in the aquifer.

  20. Unconfined aquifer response to infiltration basins and shallow pump tests

    Science.gov (United States)

    Ostendorf, David W.; DeGroot, Don J.; Hinlein, Erich S.

    2007-05-01

    SummaryWe measure and model the unsteady, axisymmetric response of an unconfined aquifer to delayed, arbitrary recharge. Water table drainage follows the initial elastic aquifer response, as modeled for uniform, instantaneous recharge by Zlotnik and Ledder [Zlotnik, V., Ledder, G., 1992. Groundwater flow in a compressible unconfined aquifer with uniform circular recharge. Water Resources Research 28(6), 1619-1630] and delayed drainage by Moench [Moench, A.F., 1995. Combining the Neuman and Boulton models for flow to a well in an unconfined aquifer. Ground Water 33(3), 378-384]. We extend their analyses with a convolution integral that models the delayed response of an aquifer to infiltration from a circular infiltration basin. The basin routes the hydrograph to the water table with a decay constant dependent on a Brooks and Corey [Brooks, R.H., Corey, A.T., 1966. Properties of porous media affecting fluid flow. Journal of the Irrigation and Drainage Division ASCE 92(2), 61-88] unsaturated permeability exponent. The resulting closed form model approaches Neuman's [Neuman, S.P., 1972. Theory of flow in unconfined aquifers considering delayed response of the water table. Water Resources Research 8(4), 1031-1045] partially penetrating pump test equation for a small source radius, instantaneous, uniform drainage and a shallow screen section. Irrigation pump data at a well characterized part of the Plymouth-Carver Aquifer in southeastern Massachusetts calibrate the small source model, while infiltration data from the closed drainage system of State Route 25 calibrate the infiltration basin model. The calibrated permeability, elasticity, specific yield, and permeability exponent are plausible and consistent for the pump and infiltration data sets.

  1. Hydrogeochemistry and pollution effects of an aquifer in Quaternary loess like sediments in the landflling area of Mar del Plata, Argentina

    Directory of Open Access Journals (Sweden)

    Daniel E. Martínez

    2013-01-01

    Full Text Available Sedimentos de tipo loéssico cubren una superficie aproximada de 1.800.000 km2 en la llanura Pampeana de Argentina, formando un sistema acuífero que es utilizado para abastecimiento de agua a ciudades y la población rural en la región. Este sistema acuífero suministra el agua que sustenta las actividades productivas que contribuyen en un 60% al producto bruto nacional. Es este trabajo se realiza un estudio detallado en un sector del acuífero próximo a la ciudad de Mar del Plata, provincia de Buenos Aires, en el que se localizan tres rellenos sanitarios. El principal objetivo es caracterizar los procesos geoquímicos que dan origen a la composición observada del agua subterránea. Se perforaron cinco pozos para la toma de muestras de agua y sedimentos, y evaluar el impacto de la infiltración del lixiviado sobre esos procesos. Se determinó la composición textural y mineralógica de los sedimentos y la composición química del agua. Las relaciones de equilibrio entre la fase sólida y la solución se determinó utilizando programas específicos. Se concluye que la composición química observada en la aguas es consecuencia principalmente de procesos de equilibrio con calcita e intercambio catiónico con adsorción de calcio y liberación de sodio. La disolución de minerales de sílice amorfo, y la hidrólisis de silicatos en forma subordinada, da origen a altas concentraciones de sílice en las aguas. La mezcla con la infiltración del lixiviado incrementa las concentraciones de los iones conservativos cloruro y nitrato, pero no se modifican en general los procesos hidrogeoquímicos mayoritarios.

  2. Managed Aquifer Recharge Using Treated Wastewater: An Option to Manage a Coastal Aquifer In Oman For Better Domestic Water Supply

    Science.gov (United States)

    Al-Maktoumi, Ali; Zekri, Slim; ElRawy, Mustafa

    2016-04-01

    Arid countries, such as the Sultanate of Oman, are facing challenges of water shortages threatening economic development and social stability. Most of those countries are vulnerable to the potential adverse impacts of climate change, the most significant of which are increased average temperatures, less and more erratic precipitation, sea level rise, and desertification. The combined effect of existing adverse conditions and likely impacts of future climate change will make water management even more difficult than what it is today. Tremendous efforts have been devoted to augment the water resources. Managed Aquifer Recharge (MAR) is practiced widely to store water during periods of surpluses and withdraw during deficits from an aquifer. In Muscat, there will be a surplus of >100,000 m3/day of TWW during winter months in the coming few years. The aquifer along the northern coast of Oman (Al-Khawd Aquifer) is conducive for MAR. Data show that TWW volumes will increase from 7.6 Mm3 in 2003 to 70.9 Mm3 in 2035 in Muscat city only. This study assesses, using MODFLOW 2005 numerical code, the impact of MAR using TWW on better management of the Al-Khawd unconfined coastal aquifer for better urban water supply. Specifically, aiming to maximize withdrawals from the domestic wells with minimize adverse effect of seawater intrusion. The model operates under a number of constrains that minimize the loss to the sea and the injected TWW must not migrates upstream (due to developed mound) and reach the wellfields used for domestic supply. The hypothetical injection wells are located downstream the domestic wellfield zone. The results of different managerial scenarios show that MAR produces a hydraulic barrier that decelerates the seawater intrusion which allows higher abstraction of pristine water from the upstream part of the aquifer. MAR along with redistribution/relocation of public wells allows abstraction of 2 times the current abstraction rate (around 6 Mm3/year to 12 Mm3

  3. Using solute and heat tracers for aquifer characterization in a strongly heterogeneous alluvial aquifer

    Science.gov (United States)

    Sarris, Theo S.; Close, Murray; Abraham, Phillip

    2018-03-01

    A test using Rhodamine WT and heat as tracers, conducted over a 78 day period in a strongly heterogeneous alluvial aquifer, was used to evaluate the utility of the combined observation dataset for aquifer characterization. A highly parameterized model was inverted, with concentration and temperature time-series as calibration targets. Groundwater heads recorded during the experiment were boundary dependent and were ignored during the inversion process. The inverted model produced a high resolution depiction of the hydraulic conductivity and porosity fields. Statistical properties of these fields are in very good agreement with estimates from previous studies at the site. Spatially distributed sensitivity analysis suggests that both solute and heat transport were most sensitive to the hydraulic conductivity and porosity fields and less sensitive to dispersivity and thermal distribution factor, with sensitivity to porosity greatly reducing outside the monitored area. The issues of model over-parameterization and non-uniqueness are addressed through identifiability analysis. Longitudinal dispersivity and thermal distribution factor are highly identifiable, however spatially distributed parameters are only identifiable near the injection point. Temperature related density effects became observable for both heat and solute, as the temperature anomaly increased above 12 degrees centigrade, and affected down gradient propagation. Finally we demonstrate that high frequency and spatially dense temperature data cannot inform a dual porosity model in the absence of frequent solute concentration measurements.

  4. Quaternary tectonic evolution of the Pamir-Tian Shan convergence zone, Northwest China

    Science.gov (United States)

    Thompson Jobe, Jessica Ann; Li, Tao; Chen, Jie; Burbank, Douglas W.; Bufe, Aaron

    2017-12-01

    The Pamir-Tian Shan collision zone in the western Tarim Basin, northwest China, formed from rapid and ongoing convergence in response to the Indo-Eurasian collision. The arid landscape preserves suites of fluvial terraces crossing structures active since the late Neogene that create fault and fold scarps recording Quaternary deformation. Using geologic and geomorphic mapping, differential GPS surveys of deformed terraces, and optically stimulated luminescence dating, we create a synthesis of the active structures that delineate the timing, rate, and migration of Quaternary deformation during ongoing convergence. New deformation rates on eight faults and folds, when combined with previous studies, highlight the spatial and temporal patterns of deformation within the Pamir-Tian Shan convergence zone during the Quaternary. Terraces spanning 130 to 8 ka record deformation rates between 0.1 and 5.6 mm/yr on individual structures. In the westernmost Tarim Basin, where the Pamir and Tian Shan are already juxtaposed, the fastest rates occur on actively deforming structures at the interface of the Pamir-Tian Shan orogens. Farther east, as the separation between the Pamir-Tian Shan orogens increases, the deformation has not been concentrated on a single structure, but rather has been concurrently distributed across a zone of faults and folds in the Kashi-Atushi fold-and-thrust belt and along the NE Pamir margin, where shortening rates vary on individual structures during the Quaternary. Although numerous structures accommodate the shortening and the locus of deformation shifts during the Quaternary, the total shortening across the western Tarim Basin has remained steady and approximately matches the current geodetic rate of 6-9 mm/yr.

  5. Factors affecting public-supply well vulnerability in two karst aquifers.

    Science.gov (United States)

    Musgrove, MaryLynn; Katz, Brian G; Fahlquist, Lynne S; Crandall, Christy A; Lindgren, Richard J

    2014-09-01

    Karst aquifers occur in a range of climatic and geologic settings. Nonetheless, they are commonly characterized by their vulnerability to water-quality impairment. Two karst aquifers, the Edwards aquifer in south-central Texas and the Upper Floridan aquifer in western Florida, were investigated to assess factors that control the movement of contaminants to public-supply wells (PSWs). The geochemistry of samples from a selected PSW or wellfield in each aquifer was compared with that from nearby monitoring wells and regional PSWs. Geochemistry results were integrated with age tracers, flow modeling, and depth-dependent data to refine aquifer conceptual models and to identify factors that affect contaminant movement to PSWs. The oxic Edwards aquifer is vertically well mixed at the selected PSW/wellfield, although regionally the aquifer is geochemically variable downdip. The mostly anoxic Upper Floridan aquifer is affected by denitrification and also is geochemically variable with depth. In spite of considerable differences in geology and hydrogeology, the two aquifers are similarly vulnerable to anthropogenic contamination. Vulnerability in studied PSWs in both aquifers is strongly influenced by rapid karst flowpaths and the dominance of young (aquifers (nitrate, atrazine, deethylatrazine, tetrachloroethene, and chloroform). Specific consideration of water-quality protection efforts, well construction and placement, and aquifer response times to land-use changes and contaminant loading are discussed, with implications for karst groundwater management. © 2014 The Authors. Groundwater published by Wiley Periodicals, Inc. on behalf of National Ground Water Association.

  6. Aquifer test at well SMW-1 near Moenkopi, Arizona

    Science.gov (United States)

    Carruth, Rob; Bills, Donald J.

    2012-01-01

    The Hopi villages of Lower Moencopi and Upper Moenkopi are on the Hopi Indian Reservation south of Tuba City in northern Arizona. These adjacent Hopi villages, located west and north of the confluence of Pasture Canyon Wash and Moenkopi Wash, are dependent on groundwater withdrawals from three wells that penetrate the N aquifer and from two springs that discharge from the N aquifer. The N aquifer is the principal aquifer in this region of northern Arizona and is composed of thick beds of sandstone between less permeable layers of siltstone and mudstone. The fine-grained character of the N aquifer inhibits rapid movement of water and large yields to wells; however, the aquifer is moderately productive at yields generally less than 25 gallons per minute in the study area. In recent years, the water level has declined in the three public-supply wells and the flow from the springs has decreased, causing concern that the current water supply will not be able to accommodate peak demand and allow for residential and economic growth. In addition to the challenge imposed by declining groundwater levels, the water-supply wells and springs are located about 2 miles downgradient from the Tuba City Landfill site where studies are ongoing to determine if uranium and other metals in groundwater beneath the landfill are higher than regional concentrations in the N aquifer. In August 2008, the U.S. Geological Survey, in cooperation with the Hopi Tribe, conducted an aquifer test on well SMW-1, designed to help the Hopi Tribe determine the potential yield and water quality of the N aquifer south of Moenkopi Wash as a possible source of additional water supply. Well SMW-1 was drilled south of Moenkopi Wash to a depth of 760 feet below land surface before being backfilled and cased to about 300 feet. The well penetrates, in descending order, the Navajo Sandstone and the Kayenta Formation, both units of the N aquifer. The pre-test water level in the well was 99.15 feet below land

  7. Groundwater vulnerability mapping in Guadalajara aquifers system (Western Mexico)

    Science.gov (United States)

    Rizo-Decelis, L. David; Marín, Ana I.; Andreo, Bartolomé

    2016-04-01

    Groundwater vulnerability mapping is a practical tool to implement strategies for land-use planning and sustainable socioeconomic development coherent with groundwater protection. The objective of vulnerability mapping is to identify the most vulnerable zones of catchment areas and to provide criteria for protecting the groundwater used for drinking water supply. The delineation of protection zones in fractured aquifers is a challenging task due to the heterogeneity and anisotropy of hydraulic conductivities, which makes difficult prediction of groundwater flow organization and flow velocities. Different methods of intrinsic groundwater vulnerability mapping were applied in the Atemajac-Toluquilla groundwater body, an aquifers system that covers around 1300 km2. The aquifer supplies the 30% of urban water resources of the metropolitan area of Guadalajara (Mexico), where over 4.6 million people reside. Study area is located in a complex neotectonic active volcanic region in the Santiago River Basin (Western Mexico), which influences the aquifer system underneath the city. Previous works have defined the flow dynamics and identified the origin of recharge. In addition, the mixture of fresh groundwater with hydrothermal and polluted waters have been estimated. Two main aquifers compose the multilayer system. The upper aquifer is unconfined and consists of sediments and pyroclastic materials. Recharge of this aquifer comes from rainwater and ascending vertical fluids from the lower aquifer. The lower aquifer consists of fractured basalts of Pliocene age. Formerly, the main water source has been the upper unit, which is a porous and unconsolidated unit, which acts as a semi-isotropic aquifer. Intense groundwater usage has resulted in lowering the water table in the upper aquifer. Therefore, the current groundwater extraction is carried out from the deeper aquifer and underlying bedrock units, where fracture flow predominates. Pollution indicators have been reported in

  8. Conceptual and numerical modeling approach of the Guarani Aquifer System

    Directory of Open Access Journals (Sweden)

    L. Rodríguez

    2013-01-01

    Full Text Available In large aquifers, relevant for their considerable size, regional groundwater modeling remains challenging given geologic complexity and data scarcity in space and time. Yet, it may be conjectured that regional scale groundwater flow models can help in understanding the flow system functioning and the relative magnitude of water budget components, which are important for aquifer management. The Guaraní Aquifer System is the largest transboundary aquifer in South America. It contains an enormous volume of water; however, it is not well known, being difficult to assess the impact of exploitation currently used to supply over 25 million inhabitants. This is a sensitive issue because the aquifer is shared by four countries. Moreover, an integrated groundwater model, and therefore a global water balance, were not available. In this work, a transient regional scale model for the entire aquifer based upon five simplified, equally plausible conceptual models represented by different hydraulic conductivity parametrizations is used to analyze the flow system and water balance components. Combining an increasing number of hydraulic conductivity zones and an appropriate set of boundary conditions, the hypothesis of a continuous sedimentary unit yielded errors within the calibration target in a regional sense. The magnitude of the water budget terms resulted very similar for all parametrizations. Recharge and stream/aquifer fluxes were the dominant components representing, on average, 84.2% of total inflows and 61.4% of total outflows, respectively. However, leakage was small compared to stream discharges of main rivers. For instance, the simulated average leakage for the Uruguay River was 8 m3 s−1 while the observed absolute minimum discharge was 382 m3 s−1. Streams located in heavily pumped regions switched from a gaining condition in early years to a losing condition over time. Water is discharged through

  9. Conceptual and numerical modeling approach of the Guarani Aquifer System

    Science.gov (United States)

    Rodríguez, L.; Vives, L.; Gomez, A.

    2013-01-01

    In large aquifers, relevant for their considerable size, regional groundwater modeling remains challenging given geologic complexity and data scarcity in space and time. Yet, it may be conjectured that regional scale groundwater flow models can help in understanding the flow system functioning and the relative magnitude of water budget components, which are important for aquifer management. The Guaraní Aquifer System is the largest transboundary aquifer in South America. It contains an enormous volume of water; however, it is not well known, being difficult to assess the impact of exploitation currently used to supply over 25 million inhabitants. This is a sensitive issue because the aquifer is shared by four countries. Moreover, an integrated groundwater model, and therefore a global water balance, were not available. In this work, a transient regional scale model for the entire aquifer based upon five simplified, equally plausible conceptual models represented by different hydraulic conductivity parametrizations is used to analyze the flow system and water balance components. Combining an increasing number of hydraulic conductivity zones and an appropriate set of boundary conditions, the hypothesis of a continuous sedimentary unit yielded errors within the calibration target in a regional sense. The magnitude of the water budget terms resulted very similar for all parametrizations. Recharge and stream/aquifer fluxes were the dominant components representing, on average, 84.2% of total inflows and 61.4% of total outflows, respectively. However, leakage was small compared to stream discharges of main rivers. For instance, the simulated average leakage for the Uruguay River was 8 m3 s-1 while the observed absolute minimum discharge was 382 m3 s-1. Streams located in heavily pumped regions switched from a gaining condition in early years to a losing condition over time. Water is discharged through the aquifer boundaries, except at the eastern boundary. On average

  10. A New Boundary for the High Plains - Ogallala Aquifer Complex

    Science.gov (United States)

    Haacker, E. M.; Nozari, S.; Kendall, A. D.

    2017-12-01

    In the semi-arid Great Plains, water is the key ingredient for crop growth: the difference between meager yields for many crops and an agricultural bonanza. The High Plains-Ogallala Aquifer complex (HPA) underlies 452,000 square kilometers of the region, and over 95% of water withdrawn from the aquifer is used for irrigation. Much of the HPA is being pumped unsustainably, and since the region is heavily reliant on this resource for its social and economic health, the High Plains has been a leader in groundwater management planning. However, the geographic boundary of the High Plains region fails to reflect the hydrogeological realities of the aquifer. The current boundary, recognizable from countless textbooks and news articles, is only slightly modified from a version from the 1980's, and largely follows the physiographic borders of the High Plains - defined by surface features such as escarpments and rivers - rather than the edges of water-bearing sediment sufficient for high-volume pumping. This is supported by three lines of evidence: hydrogeological observations from the original aquifer boundary determination; the extent of irrigated land, as estimated by MODIS-MIrAD data; and statistical estimates of saturated thickness, incorporating improved maps of the aquifer base and an additional 35 years of water table measurements. In this project, new maps of saturated thickness are used to create an updated aquifer boundary, which conforms with the standard definition of an aquifer as a package of sediment that yields enough water to be economically pumped. This has major implications for social and physical models, as well as water planning and estimates of sustainability for the HPA. Much of the area of the HPA that has been labeled `sustainable' based upon estimates of recharge relative to pumping estimates falls outside the updated aquifer boundary. In reality, the sustainably-pumped area of this updated aquifer boundary is far smaller—a fact that if more

  11. Toward an Economic Definition of Sustainable Yield for Coastal Aquifers

    Science.gov (United States)

    Jenson, J. W.; Habana, N. C.; Lander, M.

    2016-12-01

    The concept of aquifer sustainable yield has long been criticized, debated, and even disparaged among groundwater hydrologists, but policy-makers and professional water resource managers inevitably ask them for unequivocal answers to such questions as "What is the absolute maximum volume of water that could be sustainably withdrawn from this aquifer?" We submit that it is therefore incumbent upon hydrologists to develop and offer valid practical definitions of sustainable yield that can be usefully applied to given conditions and types of aquifers. In coastal aquifers, water quality—in terms of salinity—is affected by changes in the natural water budget and the volume rate of artificial extraction. In principle, one can identify a family of assay curves for a given aquifer, showing the specific relationships between the quantity and quality of the water extracted under given conditions of recharge. The concept of the assay curve, borrowed from the literature of natural-resource extraction economics, has to our knowledge not yet found its way into the literature of applied hydrology. The relationships between recharge, extraction, and water quality that define the assay curve can be determined empirically from sufficient observations of groundwater response to recharge and extraction and can be estimated from models that have been reliably history-matched ("calibrated") to such data. We thus propose a working definition of sustainable yield for coastal aquifers in terms of the capacity that ultimately could be achieved by an ideal production system, given what is known or can be assumed about the natural limiting conditions. Accordingly, we also offer an approach for defining an ideal production system for a given aquifer, and demonstrate how observational data and/or modeling results can be used to develop assay curves of quality vs. quantity extracted, which can serve as reliable predictive tools for engineers, managers, regulators, and policy

  12. FEMA: a Finite Element Model of Material Transport through Aquifers

    International Nuclear Information System (INIS)

    Yeh, G.T.; Huff, D.D.

    1985-01-01

    This report documents the construction, verification, and demonstration of a Finite Element Model of Material Transport through Aquifers (FEMA). The particular features of FEMA are its versatility and flexibility to deal with as many real-world problems as possible. Mechanisms included in FEMA are: carrier fluid advection, hydrodynamic dispersion and molecular diffusion, radioactive decay, sorption, source/sinks, and degradation due to biological, chemical as well as physical processes. Three optional sorption models are embodied in FEMA. These are linear isotherm and Freundlich and Langmuir nonlinear isotherms. Point as well as distributed source/sinks are included to represent artificial injection/withdrawals and natural infiltration of precipitation. All source/sinks can be transient or steady state. Prescribed concentration on the Dirichlet boundary, given gradient on the Neumann boundary segment, and flux at each Cauchy boundary segment can vary independently of each other. The aquifer may consist of as many formations as desired. Either completely confined or completely unconfined or partially confined and partially unconfined aquifers can be dealt with effectively. FEMA also includes transient leakage to or from the aquifer of interest through confining beds from or to aquifers lying below and/or above

  13. Developing Methods For Linking Surficial Aquifers With Localized Rainfall Data

    Science.gov (United States)

    Lafrenz, W. B.; van Gaalen, J. F.

    2008-12-01

    Water level hydrographs of the surficial aquifer can be evaluated to identify both the cause and consequence of water supply development. Rainfall, as a source of direct recharge and as a source of delayed or compounded recharge, is often the largest influence on surficial aquifer water level responses. It is clear that proximity of the rain gauge to the observation well is a factor in the degree of correlation, but in central Florida, USA, rainfall patterns change seasonally, with latitude, and with distance from the coast . Thus, for a location in central Florida, correlation of rain events with observed hydrograph responses depends on both distance and direction from an observation well to a rain gauge. In this study, we examine the use of extreme value analysis as a method of selecting the best rainfall data set for describing a given surficial aquifer monitor well. A surficial aquifer monitor well with a substantial suite of data is compared to a series of rainfall data sets from gauges ranging from meters to tens of kilometers in distance from the monitor well. The gauges vary in a wide range of directions from the monitor well in an attempt to identify both a method for rainfall gauge selection to be associated with the monitor well. Each rainfall gauge is described by a correlation coefficient with respect to the surficial aquifer water level data.

  14. Laboratory evidence of MTBE biodegradation in Borden aquifer material

    Science.gov (United States)

    Schirmer, Mario; Butler, Barbara J.; Church, Clinton D.; Barker, James F.; Nadarajah, Nalina

    2003-02-01

    Mainly due to intrinsic biodegradation, monitored natural attenuation can be an effective and inexpensive remediation strategy at petroleum release sites. However, gasoline additives such as methyl tert-butyl ether (MTBE) can jeopardize this strategy because these compounds often degrade, if at all, at a slower rate than the collectively benzene, toluene, ethylbenzene and the xylene (BTEX) compounds. Investigation of whether a compound degrades under certain conditions, and at what rate, is therefore important to the assessment of the intrinsic remediation potential of aquifers. A natural gradient experiment with dissolved MTBE-containing gasoline in the shallow, aerobic sand aquifer at Canadian Forces Base (CFB) Borden (Ontario, Canada) from 1988 to 1996 suggested that biodegradation was the main cause of attenuation for MTBE within the aquifer. This laboratory study demonstrates biologically catalyzed MTBE degradation in Borden aquifer-like environments, and so supports the idea that attenuation due to biodegradation may have occurred in the natural gradient experiment. In an experiment with batch microcosms of aquifer material, three of the microcosms ultimately degraded MTBE to below detection, although this required more than 189 days (or >300 days in one case). Failure to detect the daughter product tert-butyl alcohol (TBA) in the field and the batch experiments could be because TBA was more readily degradable than MTBE under Borden conditions.

  15. FEMA: a Finite Element Model of Material Transport through Aquifers

    Energy Technology Data Exchange (ETDEWEB)

    Yeh, G.T.; Huff, D.D.

    1985-01-01

    This report documents the construction, verification, and demonstration of a Finite Element Model of Material Transport through Aquifers (FEMA). The particular features of FEMA are its versatility and flexibility to deal with as many real-world problems as possible. Mechanisms included in FEMA are: carrier fluid advection, hydrodynamic dispersion and molecular diffusion, radioactive decay, sorption, source/sinks, and degradation due to biological, chemical as well as physical processes. Three optional sorption models are embodied in FEMA. These are linear isotherm and Freundlich and Langmuir nonlinear isotherms. Point as well as distributed source/sinks are included to represent artificial injection/withdrawals and natural infiltration of precipitation. All source/sinks can be transient or steady state. Prescribed concentration on the Dirichlet boundary, given gradient on the Neumann boundary segment, and flux at each Cauchy boundary segment can vary independently of each other. The aquifer may consist of as many formations as desired. Either completely confined or completely unconfined or partially confined and partially unconfined aquifers can be dealt with effectively. FEMA also includes transient leakage to or from the aquifer of interest through confining beds from or to aquifers lying below and/or above.

  16. Characterization of California Central Coast Aquifers using Pneumatic Slug Tests

    Science.gov (United States)

    Aurelius, S.; Platt, D.; Whetsler, B.; Malama, B.

    2017-12-01

    The recent prolonged drought in California, where about 75% of the population depends to some extent ongroundwater, has led to increased stresses on the state's groundwater resources due to reduced recharge andincreased abstraction to supplement dwindling surface water supplies for irrigation and other urban uses.These factors have conspired to cause historic lows in groundwater levels, lost aquifer storage capacity dueincreased potential for land subsidence, and degraded water quality in coastal aquifers faced with increasedrates of seawater intrusion. Groundwater accounts for about a third of the total water uses in California,with some coastal communities being 100% dependent on groundwater. Irrigation accounts for over 60%of all state groundwater withdrawals in California. In light of this, the state of California recently passedthe Sustainable Groundwater Management Act (SGMA) aimed at bringing the State's groundwater basinsinto sustainable regimes of abstraction, recharge and storage. Groundwater ow models are critical to thesuccessful implementation of the SGMA legislation. However, the usefulness of the models is severely limitedby a lack of detailed knowledge of aquifer properties at spatial scales that allow for accurate projections tobe made about groundwater basin sustainability by resource managers. We report here the results of highresolution pneumatic slug tests performed in two shallow aquifers in San Luis Obispo County on the CaliforniaCentral Coast to obtain detailed information about aquifer properties, including permeability and storage,and their spatial variability.

  17. Geochemical Triggers of Arsenic Mobilization during Managed Aquifer Recharge.

    Science.gov (United States)

    Fakhreddine, Sarah; Dittmar, Jessica; Phipps, Don; Dadakis, Jason; Fendorf, Scott

    2015-07-07

    Mobilization of arsenic and other trace metal contaminants during managed aquifer recharge (MAR) poses a challenge to maintaining local groundwater quality and to ensuring the viability of aquifer storage and recovery techniques. Arsenic release from sediments into solution has occurred during purified recycled water recharge of shallow aquifers within Orange County, CA. Accordingly, we examine the geochemical processes controlling As desorption and mobilization from shallow, aerated sediments underlying MAR infiltration basins. Further, we conducted a series of batch and column experiments to evaluate recharge water chemistries that minimize the propensity of As desorption from the aquifer sediments. Within the shallow Orange County Groundwater Basin sediments, the divalent cations Ca(2+) and Mg(2+) are critical for limiting arsenic desorption; they promote As (as arsenate) adsorption to the phyllosilicate clay minerals of the aquifer. While native groundwater contains adequate concentrations of dissolved Ca(2+) and Mg(2+), these cations are not present at sufficient concentrations during recharge of highly purified recycled water. Subsequently, the absence of dissolved Ca(2+) and Mg(2+) displaces As from the sediments into solution. Increasing the dosages of common water treatment amendments including quicklime (Ca(OH)2) and dolomitic lime (CaO·MgO) provides recharge water with higher concentrations of Ca(2+) and Mg(2+) ions and subsequently decreases the release of As during infiltration.

  18. Aquifer restoration at uranium in situ leach sites

    International Nuclear Information System (INIS)

    Anastasi, F.S.; Williams, R.E.

    1985-01-01

    In situ mining of uranium involves injection of a leaching solution (lixiviant) into an ore-bearing aquifer. Frequently, the ground water in the mined aquifer is a domestic or livestock water supply. As the lixiviant migrates through the ore body, uranium and various associated elements such as arsenic, selenium, molybdenum, vanadium and radium-226 are mobilized in the ground water. Aquifer restoration after in situ mining is not fully understood. Several methods have been developed to restore mined aquifers to pre-mining (baseline) quality. Commonly used methods include ground water sweeping, clean water injection, and treatment by ion exchange and reverse osmosis technologies. Ammonium carbonate lixiviant was used at one RandD in situ mine. Attempts were made to restore the aquifer using a variety of methods. Efforts were successful in reducing concentrations of the majority of contaminants to baseline levels. Concentrations of certain parameters, however, remained at levels above baseline six months after restoration ceased. Relatively large quantities of ground water were processed in the restoration attempt considering the small size of the project (1.25 acre). More thorough characterization of the hydrogeology of the site may have enhanced the effectiveness of restoration and reduced potential environmental impacts associated with the project. This paper presents some of the findings of a research project conducted by the Mineral Resources Waste Management Team at the University of Idaho in Moscow, Idaho. Views contained herein do not reflect U.S. Nuclear Regulatory Commission policy

  19. Hydrogeologic characterization of a fractured granitic rock aquifer, Raymond, California

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, Andrew J.B. [Univ. of California, Berkeley, CA (United States)

    1993-10-01

    The hydrogeologic properties of a shallow, fractured granitic rock aquifer in the foothills of the Sierra Nevada, California were investigated via the analysis of borehole geophysical logs and pumping tests. The drawdowns produced during these tests are not indicative of any simple conceptual aquifer model, and borehole logs show that the granite is intensely fractured. These observations are suggestive of a complex fracture-flow geometry which is extremely difficult to decipher. However, through the measurement of orientations of individual subsurface fractures from acoustic televiewer logs, and correlation between particular fractures and electrical resistivity and thermal-pulse flowmeter logs, it was found that the aquifer is, in general, comprised of two subhorizontal and nearly parallel zones of unloading fractures. Downhole flowmeter measurements taken in several wells provide further evidence for the inferred dual-layer structure of the aquifer, as well as yield quantitative measures of the contribution of flow from each zone. Analysis of drawdowns in pumped wells reveals that there are zones of relatively high transmissivity immediately around them. It was found that these properties, as well as a nearby zone of lower transmissivity, can account for their observed drawdowns. A numerical model was constructed to test whether these major heterogeneities could also account for the drawdowns in observation wells. This stepwise analysis of both the geophysical and hydrological data resulted in the formulation of a conceptual model of the aquifer which is consistent with observations, and which can account for its behavior when subjected to pumping.

  20. Evaluation of permeable fractures in rock aquifers

    Science.gov (United States)

    Bok Lee, Hang

    2015-04-01

    In this study, the practical usefulness and fundamental applicability of a self-potential (SP) method for identifying the permeable fractures were evaluated by a comparison of SP methods with other geophysical logging methods and hydraulic tests. At a 10 m-shallow borehole in the study site, the candidates of permeable fractures crossing the borehole were first determined by conventional geophysical methods such as an acoustic borehole televiwer, temperature, electrical conductivity and gamma-gamma loggings, which was compared to the analysis by the SP method. Constant pressure injection and recovery tests were conducted for verification of the hydraulic properties of the fractures identified by various logging methods. The acoustic borehole televiwer and gamma-gamma loggings detected the open space or weathering zone within the borehole, but they cannot prove the possibility of a groundwater flow through the detected fractures. The temperature and electrical conductivity loggings had limitations to detect the fractured zones where groundwater in the borehole flows out to the surrounding rock aquifers. Comparison of results from different methods showed that there is a best correlation between the distribution of hydraulic conductivity and the variation of the SP signals, and the SP logging can estimate accurately the hydraulic activity as well as the location of permeable fractures. Based on the results, the SP method is recommended for determining the hydraulically-active fractures rather than other conventional geophysical loggings. This self-potential method can be effectively applied in the initial stage of a site investigation which selects the optimal location and evaluates the hydrogeological property of fractures in target sites for the underground structure including the geothermal reservoir and radioactive waste disposal.

  1. Shallow Aquifer Methane Gas Source Assessment

    Science.gov (United States)

    Coffin, R. B.; Murgulet, D.; Rose, P. S.; Hay, R.

    2014-12-01

    Shale gas can contribute significantly to the world's energy demand. Hydraulic fracturing (fracking) on horizontal drill lines developed over the last 15 years makes formerly inaccessible hydrocarbons economically available. From 2000 to 2035 shale gas is predicted to rise from 1% to 46% of the total natural gas for the US. A vast energy resource is available in the United States. While there is a strong financial advantage to the application of fracking there is emerging concern about environmental impacts to groundwater and air quality from improper shale fracking operations. Elevated methane (CH4) concentrations have been observed in drinking water throughout the United States where there is active horizontal drilling. Horizontal drilling and hydraulic-fracturing can increase CH4 transport to aquifers, soil and the vadose zone. Seepage can also result from casing failure in older wells. However, there is strong evidence that elevated CH4 concentrations can be associated with topographic and hydrogeologic features, rather than shale-gas extraction processes. Carbon isotope geochemistry can be applied to study CH4source(s) in shallow vadose zone and groundwater systems. A preliminary TAMU-CC isotope data set from samples taken at different locations in southern Texas shows a wide range of CH4 signatures suggesting multiple sources of methane and carbon dioxide. These data are interpreted to distinguish regions with methane contributions from deep-sourced horizontal drilling versus shallow system microbial production. Development of a thorough environmental assessment using light isotope analysis can provide understanding of shallow anthropogenic versus natural CH4sources and assist in identifying regions that require remedial actions.

  2. Mobilization of uranium isotopes in Brazilian aquifers

    International Nuclear Information System (INIS)

    Bonotto, Daniel Marcos

    1994-01-01

    The uranium isotopes 234 U and 238 U have been extensively used to study geochemical problems, mainly related to the hydrological medium. Active dissolution of these isotopes is occurring in groundwaters from several aquifers at southeastern region of Brazil. The dissolved uranium concentration showed variability related to the rainwater infiltration with the U content of groundwaters increasing during wet periods. The amount of uranium mobilized during rainwater infiltration showed an inverse correlation with the thickness of unsaturated silty clay at Morro do Ferro area. The experimental data favour the possibility of formation of soluble complexes of U and dissolved organic compounds at Morro do Ferro area, and also some absorption of U by clays during rainwater infiltration. Enhanced 234 U/ 238 U activity ratios for dissolved uranium have been found and explained in terms of combined chemical etch and leach processes for groundwaters of the Pocos de Caldas alkaline complex. These processes are considered responsible for the bulk dissolution of rock matrix rather then alpha-recoil effects. Several direct correlations have been found for groundwaters of Agua da Prata, which supported the effectiveness of etch/lead mechanisms, for example, between 234 U/ 238 U activity ratio and dissolved solids, ionic strength, C O 2 partial pressure, 'traditional' index of base exchange and 'new' index of base exchange (involving the anion fluoride). A higher 234 U/ 238 U activity ratio was found to be directly related to a higher value of dissolution rate and a higher value of 222 Rn content was found to be related with a higher value of specific surface area. These relationships explained a good inverse logarithmic correlation between 234 U/ 238 U activity ratio and 222 Rn content of the spring waters of Aguas da Prata. (author)

  3. Removal of geosmin and 2-methylisoborneol during managed aquifer recharge: Batch and column studies

    KAUST Repository

    Maeng, Sungkyu; Abel, Chol D T; Sharma, Saroj K.; Park, Nosuk; Amy, Gary L.

    2012-01-01

    Managed aquifer recharge is a robust barrier in the multi-barrier approach to supply safe drinking water. The removal performance of gesomin and 2-methylisoborneol through managed aquifer recharge was investigated using batch and column experiments

  4. Regional assessment of aquifers for thermal-energy storage. Volume 2: Regions 7 through 12

    Science.gov (United States)

    1981-06-01

    The geologic and hydrologic framework, major aquifers, aquifers which are suitable and unsuitable for annual thermal energy storage (ATES) and the ATES potential of the unglaciated central region, glaciated Appalachians, unglaciated Appalachians, coastal plain, Hawaii, and Alaska are discussed.

  5. Managed Aquifer Recharge: from Local Research and Experiences to Regional Aquifer Storage and Recovery

    Science.gov (United States)

    Hendriks, D.; Faneca, M.; Oude Essink, G.; van Baaren, E.; Stuurman, R.; Delsman, J. R.; van Kempen, C.; de Louw, P.

    2016-12-01

    Many areas in the world experience periodic water shortages due to meteorological drought, salt water intrusion or over-exploitation of the water resources. Recently, it was established that the depletion of aquifers in many areas of the world is in an advanced state (Gleeson et al, 2012). This poses enormous challenges as 2.5 billion people and many companies depend on groundwater now and in the future (UN, 2015; ESG, 2016). A solution to increase robustness of water systems and prevent water shortage is subsurface storage of water during wet periods using Managed Aquifer Research (MAR). In addition to mitigation of water shortage, MAR can also reduce the occurrence and degree of flooding. Here, we present an overview of Deltares MAR expertise and available tools for up-scaling MAR. Deltares has experience with both research and implementation of MAR in different parts of the world under various hydro(geo)logical, climatic and socio-economic conditions. Various MAR techniques were assessed/tested in coastal areas of the Netherlands, Spain, New York, New Orleans and in Bangladesh. In some of these areas specific groundwater shortage related issues occur, such as salt water intrusion or subsidence. In Singapore, monitoring campaigns and modeling were done to design MAR by infiltration of water in over-exploited aquifers. In Abu Dhabi, geophysical methods were used to detect the optimal conditions for MAR systems. To effectively increase the robustness of groundwater systems up-scaling of MAR is required. For this purpose, Deltares developed tools that provide insight in the potential demand, possibilities and effectiveness of MAR at larger scales. The Quick scan tool for Fresh Groundwater Buffering provides insight on regional to national scale and is based on GIS-information of water demand, water resources, and subsurface properties. This quick scan tool has been applied for Mozambique, Kenya, India and Bangladesh. The Fresh Water Optimizer assesses the

  6. Hydrogeology, Pesticide DRASTIC for the Intermediate Aquifer. Pesticide DRASTIC coverage for the Intermediate Aquifer System. Drastic maps are most useful as a generalized tool to assess regional potential aquifer vulnerability., Published in 1998, 1:24000 (1in=2000ft) scale, Florida Department of Environmental Protection (FDEP).

    Data.gov (United States)

    NSGIC State | GIS Inventory — Hydrogeology dataset current as of 1998. Pesticide DRASTIC for the Intermediate Aquifer. Pesticide DRASTIC coverage for the Intermediate Aquifer System. Drastic maps...

  7. Hydrologic analysis of data for the Lost Lake Aquifer Zone of the Steel Pond Aquifer at recovery well RWM-16

    International Nuclear Information System (INIS)

    Wells, D.G.; Cook, J.W.; Hiergesell, R.A.

    1993-04-01

    This report presents the results of an analysis of data obtained from a large-scale, multiple-well aquifer test of the sandy unit referred to as the Lost Lake Aquifer Zone of the Steed Pond Aquifer in an area just south of the A and M Areas. Pumping was conducted at recovery well RWM-16, which is located near the MSB-40 well cluster, approximately 4000 feet south of the M-Area Basin. RWM-16 is located in the lower left portion of Figure 1, which also illustrates the general relationship of the testing site to the A and M Areas and other monitor wells. The data generated from testing RWM-16 was used to calculate estimates of transmissivity and storage for the aquifer system within which RWM-16 is screened. These parameters are related to hydraulic conductivity and storativity of the aquifer system by the vertical thickness of the unit. The leakage coefficient for the overlying confining unit is also estimated. This information is needed to refine conceptual understanding of the groundwater flow system beneath the A and M Areas. The refined conceptual model will more adequately describe the pattern of groundwater flow, and will contribute to updating the open-quotes Zone of Captureclose quotes model that has been used in the initial phases of designing a groundwater remediation system in the A and M Areas

  8. A Novel Analytical Solution for Estimating Aquifer Properties and Predicting Stream Depletion Rates by Pumping from a Horizontally Anisotropic Aquifer

    Science.gov (United States)

    Huang, Y.; Zhan, H.; Knappett, P.

    2017-12-01

    Past studies modeling stream-aquifer interactions commonly account for vertical anisotropy, but rarely address horizontal anisotropy, which does exist in certain geological settings. Horizontal anisotropy is impacted by sediment deposition rates, orientation of sediment particles and orientations of fractures etc. We hypothesize that horizontal anisotropy controls the volume of recharge a pumped aquifer captures from the river. To test this hypothesis, a new mathematical model was developed to describe the distribution of drawdown from stream-bank pumping with a well screened across a horizontally anisotropic, confined aquifer, laterally bounded by a river. This new model was used to determine four aquifer parameters including the magnitude and directions of major and minor principal transmissivities and storativity based on the observed drawdown-time curves within a minimum of three non-collinear observation wells. By comparing the aquifer parameters values estimated from drawdown data generated known values, the discrepancies of the major and minor transmissivities, horizontal anisotropy ratio, storativity and the direction of major transmissivity were 13.1, 8.8, 4, 0 and managers to exploit groundwater resource reasonably while protecting stream ecosystem.

  9. Effect of Groundwater Pumping on Seawater Intrusion in Coastal Aquifers

    Directory of Open Access Journals (Sweden)

    M.M. Sherif

    2002-06-01

    Full Text Available Many aquifers around the globe are located in coastal areas and are thus subjected to the seawater intrusion phenomenon. The growth of population in coastal areas and the conjugate increase in human, agricultural, and industrial activities have imposed an increasing demand for freshwater. This increase in water demand is often covered by extensive pumping of fresh groundwater, causing subsequent lowering of the water table (or piezometric head and upsetting the dynamic balance between freshwater and saline water bodies. The classical result of such a development is seawater intrusion. This paper presents a review for the seawater intrusion phenomenon in coastal aquifers. The effect of pumping activities on the seawater intrusion in the Nile Delta aquifer of Egypt is investigated. It was concluded that any additional pumping should be located in the middle Delta and avoided in the eastern and western sides of the Delta.

  10. Processes Affecting Groundwater Quality in the La Digue Aquifer, Seychelles

    Energy Technology Data Exchange (ETDEWEB)

    Alcindor, A. [Public Utilities Corporation, Victoria (Seychelles); Sacchi, E. [Dipartimento di Scienze della Terra e dell' ambiente, Universita di Pavia (Italy); Taigbenu, A. E. [University of the Witwatersrand, Johannesburg (South Africa)

    2013-07-15

    This paper presents the results obtained by the public utilities corporation (PUC), within the framework of an IAEA TC project, which aims to evaluate the potential of the la digue aquifer. Several monitoring activities and hydrochemical and isotopic surveys have been conducted. Results indicate the presence of brackish water at shallow depths, and low redox potentials, attesting to the presence of H{sub 2}S and heavy metals. Groundwater quality is affected by the concomitant presence of different adverse factors, namely aquifer characteristics, hydrogeology, and anthropogenic pressure. In addition, seawater penetrates the river course during high tides and infiltrates through the recharge area of the aquifer that is close to the actual pumping station. The positioning of non return high tide gates, an easy and low cost intervention, could enhance groundwater quality. The understanding of the main processes affecting groundwater quality helped in the identification of areas favourable for new wells, located at higher elevations. (author)

  11. Aquifer storage and recovery: recent hydrogeological advances and system performance.

    Science.gov (United States)

    Maliva, Robert G; Guo, Weixing; Missimer, Thomas M

    2006-12-01

    Aquifer storage and recovery (ASR) is part of the solution to the global problem of managing water resources to meet existing and future freshwater demands. However, the metaphoric "ASR bubble" has been burst with the realization that ASR systems are more physically and chemically complex than the general conceptualization. Aquifer heterogeneity and fluid-rock interactions can greatly affect ASR system performance. The results of modeling studies and field experiences indicate that more sophisticated data collection and solute-transport modeling are required to predict how stored water will migrate in heterogeneous aquifers and how fluid-rock interactions will affect the quality of stored water. It has been well-demonstrated, by historic experience, that ASR systems can provide very large volumes of storage at a lesser cost than other options. The challenges moving forward are to improve the success rate of ASR systems, optimize system performance, and set expectations appropriately.

  12. Onset of density-driven instabilities in fractured aquifers

    Science.gov (United States)

    Jafari Raad, Seyed Mostafa; Hassanzadeh, Hassan

    2018-04-01

    Linear stability analysis is conducted to study the onset of density-driven convection involved in solubility trapping of C O2 in fractured aquifers. The effect of physical properties of a fracture network on the stability of a diffusive boundary layer in a saturated fractured porous media is investigated using the dual porosity concept. Linear stability analysis results show that both fracture interporosity flow and fracture storativity play an important role in the stability behavior of the system. It is shown that a diffusive boundary layer under the gravity field in fractured porous media with lower fracture storativity and/or higher fracture interporosity flow coefficient is more stable. We present scaling relations for the onset of convective instability in fractured aquifers with single and variable matrix block size distribution. These findings improve our understanding of density-driven flow in fractured aquifers and are important in the estimation of potential storage capacity, risk assessment, and storage site characterization and screening.

  13. On the migration of uranium isotopes in sandstone aquifers

    International Nuclear Information System (INIS)

    Froehlich, K.; Gellermann, R.

    1982-01-01

    Measurements of natural 238 U and 234 U activity in groundwater of sandstone aquifers have been used to study the migration of these uranium isotopes. Regarding the uranium exchange between liquid phase and rock surface during migration, two different models were applied for evaluating the experimental results. Values of corresponding parameters (retardation factor K, removal rate R) reflecting different behaviour concerning this exchange were determined. For example, the values obtained for 238 U in a Triassic sandstone aquifer of the GDR are K = 8.6 x 10 6 and R = 1.3 x 10 -3 a -1 , respectively. It was found that, under the conditions of the sandstone aquifer concerned, the removal rate model is better suited for calculating uranium-isotope migration in groundwater. (author)

  14. Geothermal reservoir simulation of hot sedimentary aquifer system using FEFLOW®

    Science.gov (United States)

    Nur Hidayat, Hardi; Gala Permana, Maximillian

    2017-12-01

    The study presents the simulation of hot sedimentary aquifer for geothermal utilization. Hot sedimentary aquifer (HSA) is a conduction-dominated hydrothermal play type utilizing deep aquifer, which is heated by near normal heat flow. One of the examples of HSA is Bavarian Molasse Basin in South Germany. This system typically uses doublet wells: an injection and production well. The simulation was run for 3650 days of simulation time. The technical feasibility and performance are analysed in regards to the extracted energy from this concept. Several parameters are compared to determine the model performance. Parameters such as reservoir characteristics, temperature information and well information are defined. Several assumptions are also defined to simplify the simulation process. The main results of the simulation are heat period budget or total extracted heat energy, and heat rate budget or heat production rate. Qualitative approaches for sensitivity analysis are conducted by using five parameters in which assigned lower and higher value scenarios.

  15. Water quality management of aquifer recharge using advanced tools.

    Science.gov (United States)

    Lazarova, Valentina; Emsellem, Yves; Paille, Julie; Glucina, Karl; Gislette, Philippe

    2011-01-01

    Managed aquifer recharge (MAR) with recycled water or other alternative resources is one of the most rapidly growing techniques that is viewed as a necessity in water-short areas. In order to better control health and environmental effects of MAR, this paper presents two case studies demonstrating how to improve water quality, enable reliable tracing of injected water and better control and manage MAR operation in the case of indirect and direct aquifer recharge. Two water quality management strategies are illustrated on two full-scale case studies, including the results of the combination of non conventional and advanced technologies for water quality improvement, comprehensive sampling and monitoring programs including emerging pollutants, tracer studies using boron isotopes and integrative aquifer 3D GIS hydraulic and hydrodispersive modelling.

  16. Integrated and sustainable management of the shared aquifer systems in the Sahel region

    International Nuclear Information System (INIS)

    Edwerd, Mickel

    2012-01-01

    It highlights the project Justification, the long term objective, the specific objectives and the project implementation strategy. The countries which participate to this project are the following: Algeria, Benin, Burkina Faso, Cameroon, central African Republic, Chad, Gambia, Guinea-Bissau, Mali, Mauritania, Niger, Nigeria and Senegal. Regarding Aquifer System we have: Chad Basin, Liptako-Gourma Aquifer, Iullemeden Aquifer, Senegalo-Mauritanian Aquifer and Taoudeni/Tanezrouft Basin.

  17. Summary of the Snake River plain Regional Aquifer-System Analysis in Idaho and eastern Oregon

    Science.gov (United States)

    Lindholm, G.F.

    1996-01-01

    Regional aquifers underlying the 15,600-square-mile Snake River Plain in southern Idaho and eastern Oregon was studied as part of the U.S. Geological Survey's Regional Aquifer-System Analysis program. The largest and most productive aquifers in the Snake River Plain are composed of Quaternary basalt of the Snake River Group, which underlies most of the 10,8000-square-mile eastern plain. Aquifer tests and simulation indicate that transmissivity of the upper 200 feet of the basalt aquifer in the eastern plain commonly ranges from about 100,000 to 1,000,000 feet squared per day. However, transmissivity of the total aquifer thickness may be as much as 10 million feet squared per day. Specific yield of the upper 200 feet of the aquifer ranges from about 0.01 to 0.20. Average horizontal hydraulic conductivity of the upper 200 feet of the basalt aquifer ranges from less than 100 to 9,000 feet per day. Values may be one to several orders of magnitude higher in parts in individual flows, such as flow tops. Vertical hydraulic conductivity is probably several orders of magnitude lower than horizontal hydraulic conductivity and is generally related to the number of joints. Pillow lava in ancestral Snake River channels has the highest hydraulic conductivity of all rock types. Hydraulic conductivity of the basalt decreases with depth because of secondary filling of voids with calcite and silica. An estimated 80 to 120 million acre-feet of water is believed to be stored in the upper 200 feet of the basalt aquifer in the eastern plain. The most productive aquifers in the 4,800-square-mile western plain are alluvial sand and gravel in the Boise River valley. Although aquifer tests indicate that transmissivity of alluvium in the Boise River valley ranges from 5,000 to 160,000 feet squared per day, simulation suggests that average transmissivity of the upper 500 feet is generally less than 20,000 feet squared per day. Vertically averaged horizontal hydraulic conductivity of the upper

  18. Localized sulfate-reducing zones in a coastal plain aquifer

    Science.gov (United States)

    Brown, C.J.; Coates, J.D.; Schoonen, M.A.A.

    1999-01-01

    High concentrations of dissolved iron in ground water of coastal plain or alluvial aquifers contribute to the biofouling of public supply wells for which treatment and remediation is costly. Many of these aquifers, however, contain zones in which microbial sulfate reduction and the associated precipitation of iron-sulfide minerals decreases iron mobility. The principal water-bearing aquifer (Magothy Aquifer of Cretaceous age) in Suffolk County, New York, contains localized sulfate-reducing zones in and near lignite deposits, which generally are associated with clay lenses. Microbial analyses of core samples amended with [14C]-acetate indicate that microbial sulfate reduction is the predominant terminal-electron-accepting process (TEAP) in poorly permeable, lignite-rich sediments at shallow depths and near the ground water divide. The sulfate-reducing zones are characterized by abundant lignite and iron-sulfide minerals, low concentrations of Fe(III) oxyhydroxides, and by proximity to clay lenses that contain pore water with relatively high concentrations of sulfate and dissolved organic carbon. The low permeability of these zones and, hence, the long residence time of ground water within them, permit the preservation and (or) allow the formation of iron-sulfide minerals, including pyrite and marcasite. Both sulfate-reducing bacteria (SRB) and iron-reducing bacteria (IRB) are present beneath and beyond the shallow sulfate-reducing zones. A unique Fe(III)-reducing organism, MD-612, was found in core sediments from a depth of 187 m near the southern shore of Long Island. The distribution of poorly permeable, lignite-rich, sulfate-reducing zones with decreased iron concentration is varied within the principal aquifer and accounts for the observed distribution of dissolved sulfate, iron, and iron sulfides in the aquifer. Locating such zones for the placement of production wells would be difficult, however, because these zones are of limited aerial extent.

  19. Geothermal characterization of the coastal aquifer near Ravenna (Italy

    Directory of Open Access Journals (Sweden)

    M. Antonellini

    2012-12-01

    Full Text Available The coastal aquifer near Ravenna (Italy contains a large volume of groundwater (2,5x109 m3 whose quality has been compromised by sea-water intrusion. Today, the phreatic groundwater is mostly brackish with some lenses of freshwater floating on top of more saline water. This water, although impossible to use as drink-water or for irrigation, is still important to guarantee the health of wetland habitats and especially of the roman historical and coastal pine forests of Ravenna. With the objective of defining the flow pattern within the aquifer and the exchange between surface and ground water, we characterized the temperature distribution in the shallow subsurface by means of a dense network of piezometers. At the same time we had the opportunity to characterize the phreatic aquifer from the geothermal point of view, so that it could eventually be considered for use as a “low enthalpy” heat source. Heat pumps are able to extract heat during the winter and dissipate it during the summer. The temperature of the groundwater in the top layer of the aquifer (surficial zone is sensitive to the changes in atmospheric temperature throughout the year whereas the temperature of the deeper groundwater follows the geothermal gradient (geothermal zone. One of the scopes of the project is to discover at what depth is located the geothermal zone, so that the aquifer has a constant temperature throughout the year. A constant temperature is needed for storage of heat at low enthalpy. The thickness of the surficial zone and the temperature at the top of the geothermal zone are essentially related to land use, distance from the sea, sediment type, and amount of interaction between surface and groundwater. A knowledge of these factors allows to better exploit the geothermal potential of the aquifer when choosing the optimal placement of the heat pumps.

  20. Development of A Mississippi River Alluvial Aquifer Groundwater Model

    Science.gov (United States)

    Karakullukcu, R. E.; Tsai, F. T. C.; Bhatta, D.; Paudel, K.; Kao, S. C.

    2017-12-01

    The Mississippi River Alluvial Aquifer (MRAA) underlies the Mississippi River Valley of the northeastern Louisiana, extending from the north border of Louisiana and Arkansas to south central of Louisiana. The MRAA has direct contact with the Mississippi River. However, the interaction between the Mississippi River and the alluvial aquifer is largely unknown. The MRAA is the second most used groundwater source in Louisiana's aquifers with about 390 million gallons per day, which is about 25% of all groundwater withdrawals in Louisiana. MRAA is the major water source to agriculture in the northeastern Louisiana. The groundwater withdrawals from the MRAA increases annually for irrigation. High groundwater pumping has caused significant groundwater level decline and elevated salinity in the aquifer. Therefore, dealing with agricultural irrigation is the primary purpose for managing the MRAA. The main objective of this study is to develop a groundwater model as a tool for the MRAA groundwater management. To do so, a hydrostratigraphy model of the MRAA was constructed by using nearly 8,000 drillers' logs and electric logs collected from Louisiana Department of Natural Resources. The hydrostratigraphy model clearly shows that the Mississippi River cuts into the alluvial aquifer. A grid generation technique was developed to convert the hydrostratigraphy model into a MODFLOW model with 12 layers. A GIS-based method was used to estimate groundwater withdrawals for irrigation wells based on the crop location and acreage from the USDACropScape - Cropland Data Layer. Results from the Variable Infiltration Capacity (VIC) model were used to determine potential recharge. NHDPlusV2 data was used to determine water level for major streams for the MODFLOW River Package. The groundwater model was calibrated using groundwater data between 2004 and 2015 to estimate aquifer hydraulic conductivity, specific yield, specific storage, river conductance, and surficial recharge.

  1. Origin and residence time of water in the Lima Aquifer

    OpenAIRE

    Montoya, Modesto; Mamani, Enoc

    2014-01-01

    The 8 million inhabitants of the coastal city Lima are supplied with water from the Rimac and Chillon rivers and water wells in the Lima aquifer. The history of the Rimac River flow and static level of water in its wells have been correlated to calculate the residence time of water in the aquifer it is recharged by the Rimac River until it reaches a well located 12 km away in the Miraflores District near the sea. The relative abundance of H-2 and O-18 are used to identify the origins of the w...

  2. Isotopic hydrodynamic of the aquifer systems Jaruco and Aguacate, Cuba

    International Nuclear Information System (INIS)

    Moleiro Leon, L.F.; Guerra Oliva, M.G.; Maloszewski, P.; Arellano Acosta, D.M.

    2002-01-01

    An isotopic dispersive model is applied to the Jaruco and Aguacate karstic groundwater basins of Western Cuba. The best fit of the model was validated with stable ( 18 O and 2 H ) and radioactive ( 3 H) isotopes. Modeling showed an aquifer stratification in two basic levels with turnover times of three month to upper level and close to 100 years to the lower level. The last one mainly supplies the base flow of the Ojo de agua and Bello springs and therefore, controls the dry season exploitation yields of the aqueducts of El Gato and Bello. Model results introduces an important constraint in the exploitation of groundwater resource of both aquifer systems

  3. Estimating aquifer transmissivity from specific capacity using MATLAB.

    Science.gov (United States)

    McLin, Stephen G

    2005-01-01

    Historically, specific capacity information has been used to calculate aquifer transmissivity when pumping test data are unavailable. This paper presents a simple computer program written in the MATLAB programming language that estimates transmissivity from specific capacity data while correcting for aquifer partial penetration and well efficiency. The program graphically plots transmissivity as a function of these factors so that the user can visually estimate their relative importance in a particular application. The program is compatible with any computer operating system running MATLAB, including Windows, Macintosh OS, Linux, and Unix. Two simple examples illustrate program usage.

  4. Degradation of herbicides in shallow Danish aquifers - an integrated laboratory and field study

    DEFF Research Database (Denmark)

    Albrechtsen, Hans-Jørgen; Mills, M.; Aamand, J.

    2001-01-01

    Degradation of pesticides in aquifers has been evaluated based on a number of co-ordinated field and laboratory studies carried out in Danish aquifers. These studies included investigations of vertical and horizontal variability in degradation rates from the vadose zone to an aquifer, the effects...

  5. Characterization of the sediments overlying the Floridan aquifer system in Alachua County, Florida

    OpenAIRE

    Green, Richard; Duncan, Joel; Seal, Thomas; Weinberg, J. Michael; Rupert, Frank

    1989-01-01

    The primary purpose of this project is to attempt to improve the existing hydrogeologic information through lithologic and hydrogeologic characterizations of the sediments overlying the Floridan aquifer system in Alachua County. These sediments locally comprise both the intermediate aquifer system and associated confining beds and the surficial aquifer system. (PDF has 119 pages.)

  6. Potentiometric surfaces, summer 2013 and winter 2015, and select hydrographs for the Southern High Plains aquifer, Cannon Air Force Base, Curry County, New Mexico

    Science.gov (United States)

    Collison, Jake

    2016-04-07

    Cannon Air Force Base (Cannon AFB) is located in the High Plains physiographic region of east-central New Mexico, about 5 miles west of Clovis, New Mexico. The area surrounding Cannon AFB is primarily used for agriculture, including irrigated cropland and dairies. The Southern High Plains aquifer is the principal source of water for Cannon AFB, for the nearby town of Clovis, and for local agriculture and dairies. The Southern High Plains aquifer in the vicinity of Cannon AFB consists of three subsurface geological formations: the Chinle Formation of Triassic age, the Ogallala Formation of Tertiary age, and the Blackwater Draw Formation of Quaternary age. The Ogallala Formation is the main water-yielding formation of the Southern High Plains aquifer. Groundwater-supplied, center-pivot irrigation dominates pumping from the Southern High Plains aquifer in the area surrounding Cannon AFB, where the irrigation season typically extends from early March through October. The U.S. Geological Survey has been monitoring groundwater levels in the vicinity of Cannon AFB since 1954 and has developed general potentiometric-surface maps that show groundwater flow from northwest to southeast in the study area. While previous potentiometric-surface maps show the general direction of groundwater flow, a denser well network is needed to show details of groundwater flow at a local scale. Groundwater levels were measured in 93 wells during summer 2013 and 100 wells during winter 2015.The summer and winter potentiometric-surface maps display the presence of what is interpreted to be a groundwater trough trending from the northwest to the southeast through the study area. This groundwater trough may be the hydraulic expression of a Tertiary-age paleochannel. Groundwater north of the trough flows in a southerly direction into the trough, and groundwater south of the trough flows in an easterly direction into the trough.During the 18-month period between summer 2013 and winter 2015, changes

  7. Evidences of late quaternary neotectonic activity and sea-level changes along the western continental margin of India

    Digital Repository Service at National Institute of Oceanography (India)

    Rao, V.P.; Veerayya, M.; Thamban, M.; Wagle, B.G.

    The offshore data on sea-level changes along the western margin of India have been reviewed and evidences of Late Quaternary neotectonic activity and subsidence are documented, based on the diagenetic textures of limestones from deeper submarine...

  8. Multi-process Late Quaternary landscape evolution modelling reveals lags in climate response over small spatial scales

    NARCIS (Netherlands)

    Temme, A.J.A.M.; Veldkamp, A.

    2009-01-01

    Landscapes evolve in complex, non-linear ways over Quaternary timespans. Integrated geomorphological field studies usually yield plausible hypotheses about timing and impact of process activity. Landscape Evolution Models (LEMs) have the potential to test and falsify these landscape evolution

  9. Identification of the microbes mediating Fe reduction in a deep saline aquifer and their influence during managed aquifer recharge.

    Science.gov (United States)

    Ko, Myoung-Soo; Cho, Kyungjin; Jeong, Dawoon; Lee, Seunghak

    2016-03-01

    In this study, indigenous microbes enabling Fe reduction under saline groundwater conditions were identified, and their potential contribution to Fe release from aquifer sediments during managed aquifer recharge (MAR) was evaluated. Sediment and groundwater samples were collected from a MAR feasibility test site in Korea, where adjacent river water will be injected into the confined aquifer. The residual groundwater had a high salinity over 26.0 psu, as well as strong reducing conditions (dissolved oxygen, DOaquifer were found to be Citrobacter sp. However, column experiments to simulate field operation scenarios indicated that additional Fe release would be limited during MAR, as the dominant microbial community in the sediment would shift from Citrobacter sp. to Pseudomonas sp. and Limnohabitans sp. as river water injection alters the pore water chemistry. Copyright © 2015 Elsevier B.V. All rights reserved.

  10. Global assessment of coastal aquifer state and its vulnerability respect to Sea Water Intrusion. Application to several Mediterranean Coastal Aquifers.

    Science.gov (United States)

    Baena, Leticia; Pulido-Velazquez, David; Renau-Pruñonosa, Arianna; Morell, Ignacio

    2017-04-01

    In this research we propose a method for a global assessment of coastal aquifer state and its vulnerability to Sea Water Intrusion (SWI). It is based on two indices, the MART index, which summarize the global significance of the SWI phenomenon, and the L_GALDIT for a lumped assessment of the vulnerability to SWI. Both of them can be useful as a tool to assess coastal groundwater bodies in risk of not achieving good status in accordance with the Water Framework Directive (WFD, 2000) and to identify possible management alternative to reduce existing impacts. They can be obtained even from a reduced number of data (in the MART case only depend on the geometry and available aquifer state data) with simple calculations, which have been implemented in a general GIS tool that can be easily applied to other case studies. The MART index in an aquifer is related with the total mass of chloride in the aquifer due to sea water intrusion and can be obtained by simple linear operations of volume and concentrations that can be deduced from a schematic conceptual cross-section approach (orthogonal to the shore line) defined to summarize the intrusion volume in the aquifer. At a certain historical time, this representative aquifer cross-section can be defined in a systhematic way from the aquifer geometry, the specific yield, and the hydraulic head and chloride concentration fields that can be deduced from the available information by using appropriate interpolation methods. Following the proposed procedure we will finally obtain a summary of the historical significance of the SWI in an aquifer at different spatial resolution: 3D salinity concentration maps, 2D representative conceptual cross-section of intrusion and the MART lumped significance index. The historical evolution of the MART can be employed to perform a global assessment of the resilience and trends of global significance of the SWI in an aquifer. It can be useful to compare the significance of intrusion problems in

  11. Accounting for the Decreasing Reaction Potential of Heterogeneous Aquifers in a Stochastic Framework of Aquifer-Scale Reactive Transport

    Science.gov (United States)

    Loschko, Matthias; Wöhling, Thomas; Rudolph, David L.; Cirpka, Olaf A.

    2018-01-01

    Many groundwater contaminants react with components of the aquifer matrix, causing a depletion of the aquifer's reactivity with time. We discuss conceptual simplifications of reactive transport that allow the implementation of a decreasing reaction potential in reactive-transport simulations in chemically and hydraulically heterogeneous aquifers without relying on a fully explicit description. We replace spatial coordinates by travel-times and use the concept of relative reactivity, which represents the reaction-partner supply from the matrix relative to a reference. Microorganisms facilitating the reactions are not explicitly modeled. Solute mixing is neglected. Streamlines, obtained by particle tracking, are discretized in travel-time increments with variable content of reaction partners in the matrix. As exemplary reactive system, we consider aerobic respiration and denitrification with simplified reaction equations: Dissolved oxygen undergoes conditional zero-order decay, nitrate follows first-order decay, which is inhibited in the presence of dissolved oxygen. Both reactions deplete the bioavailable organic carbon of the matrix, which in turn determines the relative reactivity. These simplifications reduce the computational effort, facilitating stochastic simulations of reactive transport on the aquifer scale. In a one-dimensional test case with a more detailed description of the reactions, we derive a potential relationship between the bioavailable organic-carbon content and the relative reactivity. In a three-dimensional steady-state test case, we use the simplified model to calculate the decreasing denitrification potential of an artificial aquifer over 200 years in an ensemble of 200 members. We demonstrate that the uncertainty in predicting the nitrate breakthrough in a heterogeneous aquifer decreases with increasing scale of observation.

  12. A novel analytical solution for estimating aquifer properties within a horizontally anisotropic aquifer bounded by a stream

    Science.gov (United States)

    Huang, Yibin; Zhan, Hongbin; Knappett, Peter S. K.

    2018-04-01

    Past studies modeling stream-aquifer interaction commonly account for vertical anisotropy in hydraulic conductivity, but rarely address horizontal anisotropy, which may exist in certain sedimentary environments. If present, horizontal anisotropy will greatly impact stream depletion and the amount of recharge a pumped aquifer captures from the river. This scenario requires a different and somewhat more sophisticated mathematical approach to model and interpret pumping test results than previous models used to describe captured recharge from rivers. In this study, a new mathematical model is developed to describe the spatiotemporal distribution of drawdown from stream-bank pumping with a well screened across a horizontally anisotropic, confined aquifer, laterally bounded by a river. This new model is used to estimate four aquifer parameters including the magnitude and directions of major and minor principal transmissivities and storativity based on the observed drawdown-time curves within a minimum of three non-collinear observation wells. In order to approve the efficacy of the new model, a MATLAB script file is programmed to conduct a four-parameter inversion to estimate the four parameters of concern. By comparing the results of analytical and numerical inversions, the accuracy of estimated results from both inversions is acceptable, but the MATLAB program sometimes becomes problematic because of the difficulty of separating the local minima from the global minima. It appears that the new analytical model of this study is applicable and robust in estimating parameter values for a horizontally anisotropic aquifer laterally bounded by a stream. Besides that, the new model calculates stream depletion rate as a function of stream-bank pumping. Unique to horizontally anisotropic and homogeneous aquifers, the stream depletion rate at any given pumping rate depends closely on the horizontal anisotropy ratio and the direction of the principle transmissivities relative to

  13. Ground-water flow directions and estimation of aquifer hydraulic properties in the lower Great Miami River Buried Valley aquifer system, Hamilton Area, Ohio

    Science.gov (United States)

    Sheets, Rodney A.; Bossenbroek, Karen E.

    2005-01-01

    The Great Miami River Buried Valley Aquifer System is one of the most productive sources of potable water in the Midwest, yielding as much as 3,000 gallons per minute to wells. Many water-supply wells tapping this aquifer system are purposely placed near rivers to take advantage of induced infiltration from the rivers. The City of Hamilton's North Well Field consists of 10 wells near the Great Miami River, all completed in the lower Great Miami River Buried Valley Aquifer System. A well-drilling program and a multiple-well aquifer test were done to investigate ground-water flow directions and to estimate aquifer hydraulic properties in the lower part of the Great Miami River Buried Valley Aquifer System. Descriptions of lithology from 10 well borings indicate varying amounts and thickness of clay or till, and therefore, varying levels of potential aquifer confinement. Borings also indicate that the aquifer properties can change dramatically over relatively short distances. Grain-size analyses indicate an average bulk hydraulic conductivity value of aquifer materials of 240 feet per day; the geometric mean of hydraulic conductivity values of aquifer material was 89 feet per day. Median grain sizes of aquifer material and clay units were 1.3 millimeters and 0.1 millimeters, respectively. Water levels in the Hamilton North Well Field are affected by stream stage in the Great Miami River and barometric pressure. Bank storage in response to stream stage is evident. Results from a multiple-well aquifer test at the well field indicate, as do the lithologic descriptions, that the aquifer is semiconfined in some areas and unconfined in others. Transmissivity and storage coefficient of the semiconfined part of the aquifer were 50,000 feet squared per day and 5x10-4, respectively. The average hydraulic conductivity (450 feet per day) based on the aquifer test is reasonable for glacial outwash but is higher than calculated from grain-size analyses, implying a scale effect

  14. Evaluating the Significance of Paleophylogeographic Species Distribution Models in Reconstructing Quaternary Range-Shifts of Nearctic Chelonians

    OpenAIRE

    R?dder, Dennis; Lawing, A. Michelle; Flecks, Morris; Ahmadzadeh, Faraham; Dambach, Johannes; Engler, Jan O.; Habel, Jan Christian; Hartmann, Timo; H?rnes, David; Ihlow, Flora; Schidelko, Kathrin; Stiels, Darius; Polly, P. David

    2013-01-01

    The climatic cycles of the Quaternary, during which global mean annual temperatures have regularly changed by 5-10°C, provide a special opportunity for studying the rate, magnitude, and effects of geographic responses to changing climates. During the Quaternary, high- and mid-latitude species were extirpated from regions that were covered by ice or otherwise became unsuitable, persisting in refugial retreats where the environment was compatible with their tolerances. In this study we combine ...

  15. Biotic response to late Quaternary rapid climate switches in Santa Barbara Basin: Ecological and evolutionary implications

    International Nuclear Information System (INIS)

    Cannariato, K.G.; Kennett, J.P.; Behl, R.J.

    1999-01-01

    Benthic foraminiferal assemblages from Santa Barbara Basin exhibit major faunal and ecological switches associated with late Quaternary millennial- to decadal-scale global climate oscillations. Repeated turnovers of entire faunas occurred rapidly (<40--400 yr) without extinction or speciation in conjunction with Dansgaard-Oeschger shifts in thermohaline circulation, ventilation, and climate, confirming evolutionary model predictions of Roy et al. Consistent faunal successions of dysoxic taxa during successive interstadials reflect the extreme sensitivity and adaptation of the benthic ecosystem to the rapid environmental changes that marked the late Quaternary and possibly other transitional intervals in the history of the Earth's ocean-atmosphere-cryosphere system. These data support the hypothesis that broad segments of the biosphere are well adapted to rapid climate change

  16. Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams

    KAUST Repository

    Behenna, Douglas C.

    2011-12-18

    The enantioselective synthesis of nitrogen-containing heterocycles (N-heterocycles) represents a substantial chemical research effort and resonates across numerous disciplines, including the total synthesis of natural products and medicinal chemistry. In this Article, we describe the highly enantioselective palladium-catalysed decarboxylative allylic alkylation of readily available lactams to form 3,3-disubstituted pyrrolidinones, piperidinones, caprolactams and structurally related lactams. Given the prevalence of quaternary N-heterocycles in biologically active alkaloids and pharmaceutical agents, we envisage that our method will provide a synthetic entry into the de novo asymmetric synthesis of such structures. As an entry for these investigations we demonstrate how the described catalysis affords enantiopure quaternary lactams that intercept synthetic intermediates previously used in the synthesis of the Aspidosperma alkaloids quebrachamine and rhazinilam, but that were previously only available by chiral auxiliary approaches or as racemic mixtures. © 2012 Macmillan Publishers Limited. All rights reserved.

  17. EVALUATION OF THE ANTIMICROBIAL EFFECTS OF NEW HETEROCYCLIC BIS-QUATERNARY AMMONIUM COMPOUNDS ON BIOFILMS

    Directory of Open Access Journals (Sweden)

    OANA E. CONSTANTIN

    2016-07-01

    Full Text Available Considering the well-known mechanism of adaptable resistance of microorganisms to chemical compounds through biofilms formation and the widespread use of N-heterocyclic quaternary ammonium salts (QAC as disinfectants, in this study we have evaluate the effect of 8 newly synthesized symmetrical and unsymmetrical diquaternary ammonium salts of 1,2-bis-(4-pyridil-ethane on bacterial biofilms produced by three different bacterial strains. The effect of the exposure to quaternary ammonium salts on biofilm communities was investigated within biofilms obtained in a conventional testing system, on stainless steel and glass surfaces. Differential plate counts were used to characterize the developed communities and the effects of QAC exposure and the results were correlated with epifluorescence microphotographs. The data obtained revealed a significant reduction of bacterial cells in the biofilms tested with 4-7 log CFU for all the QAC.

  18. Paleomagnetic dating of tectonically influenced Plio-Quaternary fan-system deposits from the Apennines (Italy

    Directory of Open Access Journals (Sweden)

    Michele Saroli

    2015-03-01

    Full Text Available The Roveto Valley is a narrow, elongated, NW-trending depression filled with continental Plio-Quaternary deposits that outcrop at different topographic elevations. A morpho-lithostratigraphic succession of the continental deposits has been defined in order to reconstruct the geological Quaternary evolution of the area. These deposits do not contain materials suitable for biostratigraphic dating; therefore, in order to determine their chronology, three different units were sampled for magnetostratigraphic investigations. Paleomagnetic results demonstrated that standard demagnetization techniques are effective in removing secondary remanence components and in isolating the characteristic remanent magnetization, allowing us to determine, for each cycle, whether it was deposited before or after the Brunhes-Matuyama geomagnetic reversal at 781 ka. Preliminary rock magnetic analyses indicated that magnetite is the main magnetic carrier and that hematite, which gives the pink colour to the matrix, is in the superparamagnetic grain-size range and thus does not retain any paleomagnetic remanence.

  19. Polarization encoded all-optical quaternary successor with the help of SOA assisted Sagnac switch

    Science.gov (United States)

    Chattopadhyay, Tanay; Roy, Jitendra Nath

    2011-06-01

    The application of multi-valued (non-binary) signals can provide a considerable relief in transmission, storage and processing of large amount of information in digital signal processing. Optical multi-valued logical operation is an interesting challenge for future optical signal processing where we can expect much innovation. A novel all-optical quaternary successor (QSUC) circuit with the help of semiconductor optical amplifier (SOA)-assisted Sagnac switch is proposed and described. This circuit exploits the polarization properties of light. Different logical states are represented by different polarization state of light. Simulation result confirming described method is given in this paper. Proposed all-optical successor circuit can take an important and significant role in designing of all-optical quaternary universal inverter and modulo arithmetic unit (addition and multiplication).

  20. Quaternary system LiF-LiCl-LiVO3-Li2MoO4

    International Nuclear Information System (INIS)

    Anipchenko, B.V.; Garkushin, I.K.

    2000-01-01

    Interactions in the LiF-LiCl-LiVO 3 -Li 2 MoO 4 system are studied by differential thermal analysis. Rate of heating/cooling of the samples comprised 15 Grad/min, mass of sample composed 0.2 g. The system was investigated in the 300-650 Deg C range. X-ray diffraction method was used for determination of purity of the reagents. Composition and temperature of quaternary component eutectics are determined: 16.5 mol. % of LiF, 47.0 mol. % of LiCl, 28.8 mol. % of LiVO 3 , 7.6 mol. % of Li 2 MoO 4 ; 387 Deg C. Mean value of melting enthalpy of quaternary eutectics mixture in the LiF-LiCl-LiVO 3 -Li 2 MoO 4 system on the results of the tests was in the range of 222 kJ/kg [ru

  1. A new quaternary phase observed in a laser treated Zn–Al–Mg–Si coating

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Z., E-mail: zchen@uowmail.edu.au [School of Mechanical, Materials and Mechatronic Engineering, Faculty of Engineering and Information Sciences, University of Wollongong, Wollongong, NSW 2522 (Australia); Peng, C.-T. [School of Mechanical, Materials and Mechatronic Engineering, Faculty of Engineering and Information Sciences, University of Wollongong, Wollongong, NSW 2522 (Australia); Liu, Q.; Smith, R.; Nolan, D. [Bluescope Steel Research, Bluescope Steel Limited, Locked Bag 8825, Wollongong DC, NSW 2500 (Australia)

    2014-03-15

    Highlights: • A new quaternary phase was discovered in laser treated Zn–55Al–2Mg–1Si coating. • The crystal structure of the new phase was determined by TEM. • The new phase was not a metastable phase induced by the rapid cooling of the laser treatment. • Laser treatment led to not only a much finer microstructure but also changes of phases in the interdendritic areas of the coating. -- Abstract: The microstructure of laser resurfaced Zn–55Al–2Mg–1.5Si coating produced on a hot-dip simulator was characterised by transmission electron microscopy. A new quaternary phase was observed and its crystal structure was determined by electron diffraction.

  2. A new quaternary phase observed in a laser treated Zn–Al–Mg–Si coating

    International Nuclear Information System (INIS)

    Chen, Z.; Peng, C.-T.; Liu, Q.; Smith, R.; Nolan, D.

    2014-01-01

    Highlights: • A new quaternary phase was discovered in laser treated Zn–55Al–2Mg–1Si coating. • The crystal structure of the new phase was determined by TEM. • The new phase was not a metastable phase induced by the rapid cooling of the laser treatment. • Laser treatment led to not only a much finer microstructure but also changes of phases in the interdendritic areas of the coating. -- Abstract: The microstructure of laser resurfaced Zn–55Al–2Mg–1.5Si coating produced on a hot-dip simulator was characterised by transmission electron microscopy. A new quaternary phase was observed and its crystal structure was determined by electron diffraction

  3. Thermoelectric properties of quaternary (Bi,Sb){sub 2}(Te,Se){sub 3} compound

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Pengfei, E-mail: photon.bupt@gmail.com [State Key Laboratory of Information Photonics and Optical Communications, Ministry of Education, Beijing University of Posts and Telecommunications, P.O. Box 72, Beijing 100876 (China); Li, Yiluan; Wu, Chengjie; Yu, Zhongyuan; Cao, Huawei; Zhang, Xianlong; Cai, Ningning; Zhong, Xuxia [State Key Laboratory of Information Photonics and Optical Communications, Ministry of Education, Beijing University of Posts and Telecommunications, P.O. Box 72, Beijing 100876 (China); Wang, Shumin [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China); Photonics Laboratory, Department of Microtechnology and Nanoscience, Chalmers University of Technology, 41296 Gothenburg (Sweden)

    2014-01-25

    Highlights: • Sb and Se spin–orbit coupling play a key role in the band structure. • Substituted Bi/Sb and Te/Se have a limited impact on the transport coefficients. • n-Type doping will be preferred for quaternary (Bi,Sb){sub 2}(Te,Se){sub 3} compound. -- Abstract: The quaternary (Bi,Sb){sub 2}(Te,Se){sub 3} compounds are investigated using first-principles study and Boltzmann transport theory. The energy band structure and density of states are studied in detail. The electronic transport coefficients are then calculated as a function of chemical potential. The figure of merit ZT is obtained assuming a constant relaxation time and an averaged thermal conductivity. Our theoretical result agrees well with previous experimental data.

  4. Thermoelectric properties of quaternary (Bi,Sb)2(Te,Se)3 compound

    International Nuclear Information System (INIS)

    Lu, Pengfei; Li, Yiluan; Wu, Chengjie; Yu, Zhongyuan; Cao, Huawei; Zhang, Xianlong; Cai, Ningning; Zhong, Xuxia; Wang, Shumin

    2014-01-01

    Highlights: • Sb and Se spin–orbit coupling play a key role in the band structure. • Substituted Bi/Sb and Te/Se have a limited impact on the transport coefficients. • n-Type doping will be preferred for quaternary (Bi,Sb) 2 (Te,Se) 3 compound. -- Abstract: The quaternary (Bi,Sb) 2 (Te,Se) 3 compounds are investigated using first-principles study and Boltzmann transport theory. The energy band structure and density of states are studied in detail. The electronic transport coefficients are then calculated as a function of chemical potential. The figure of merit ZT is obtained assuming a constant relaxation time and an averaged thermal conductivity. Our theoretical result agrees well with previous experimental data

  5. Kinematics of the quaternary fault zones in the Kyeongju area of the southeastern Korean Peninsula

    Energy Technology Data Exchange (ETDEWEB)

    Kim, In Seob; Lee, Byeong Hyui; Kwon, Hyeok Sang [Korea Advanced Institute of Science and Technology, Taejon (Korea, Republic of)] (and others)

    1998-09-15

    The purposes of this study are to interpret the kinematics of the Quaternary fault zones in the Kyeongju area, to determine deformation mechanisms during faulting by analyzing micorstrucutres of fault rocks from the fault zones, and to unravel the technic evaluation of the regional fault structures in the Kyeongju-Wolsung area. The scope of this study consists of ; collection and interpretation of structural elements through a detailed geologic investigation on the Quaternary faults in the Kyeongju-Wolsung area, interpretation of fault-rock microstructures from the fault zones using oriented samples of faults rocks, determination of deformation processes and mechanisms of the fault rocks and, interpretation of faulting kinematics and evaluation of the fault zones.

  6. Kinematics of the quaternary fault zones in the Kyeongju area of the southeastern Korean Peninsula

    International Nuclear Information System (INIS)

    Kim, In Seob; Lee, Byeong Hyui; Kwon, Hyeok Sang

    1998-09-01

    The purposes of this study are to interpret the kinematics of the Quaternary fault zones in the Kyeongju area, to determine deformation mechanisms during faulting by analyzing micorstrucutres of fault rocks from the fault zones, and to unravel the technic evaluation of the regional fault structures in the Kyeongju-Wolsung area. The scope of this study consists of ; collection and interpretation of structural elements through a detailed geologic investigation on the Quaternary faults in the Kyeongju-Wolsung area, interpretation of fault-rock microstructures from the fault zones using oriented samples of faults rocks, determination of deformation processes and mechanisms of the fault rocks and, interpretation of faulting kinematics and evaluation of the fault zones

  7. Novel immobilization of a quaternary ammonium moiety on keratin fibers for medical applications.

    Science.gov (United States)

    Yu, Dan; Cai, Jackie Y; Liu, Xin; Church, Jeffrey S; Wang, Lijing

    2014-09-01

    This paper introduces a new approach for immobilizing a quaternary ammonium moiety on a keratinous substrate for enhanced medical applications. The method involves the generation of thiols by controlled reduction of cystine disulfide bonds in the keratin, followed by reaction with [2-(acryloyloxy)ethyl]trimethylammonium chloride through thiol-ene click chemistry. The modified substrate was characterized with Raman and infrared spectroscopy, and assessed for its antibacterial efficacy and other performance changes. The results have demonstrated that the quaternary ammonium moiety has been effectively attached onto the keratin structure, and the resultant keratin substrate exhibits a multifunctional effect including antibacterial and antistatic properties, improved liquid moisture management property, improved dyeability and a non-leaching characteristic of the treated substrate. Crown Copyright © 2014. Published by Elsevier B.V. All rights reserved.

  8. Mineralogy of auriferous deposits of the quaternary deposits in the San Luis Province, Argentina

    International Nuclear Information System (INIS)

    Karlsson, A.; Ayala, R. . E mail: Karlsson@arnet.com.ar

    2004-01-01

    The objective of this work is to study the mineralogy of the sands and clays of the quaternary deposits in the San Luis Mountain, Argentina. A series of algorithms applied to the sand fraction has permitted to determine sedimentary discontinuities. The two micron fraction of the sediments has been studied by a quantification technique based on X-ray diffraction by means of oriented preparations and run with copper tube. These quaternary silts have received fluvial lateral contributions. The high cristalinidad of non expandibles and fireclay clay show the antique of the silts. The polygenic processes have generated a great variety of clay mineral species like a large quantities of illite and in lesser extend kaolinite and smectites. The illite was probably generated by diagenetic changes. The high cristalinidad of non expandibles and fireclay clay show the antique of the silts [es

  9. Plio-quaternary deposits in the Eastern Rharb (Nw Morocco): Electrosequential characterization

    Science.gov (United States)

    Al Mazini, Imane; Mridekh, Abdelaziz; Kili, Malika; El Mansouri, Bouâbid; El Bouhaddioui, Mohamed; Magrane, Bouchaib

    2018-02-01

    The Rharb basin, of which our study area is part, is located at the western extremity of the south Rif corridor. It corresponds to a subsiding zone that appeared in the Upper Miocene, between two major structural domains: the Rif to the north and east and the Meseta domain to the south. The eastern part of this basin is characterized by a Plio-Quaternary continental fill. Its geographical position and its structural and paleo-environmental contexts are reflected by a great facies heterogeneity. This work aims to image the subsurface structure and to characterize the distribution mode of Plio-Quaternary deposits of the eastern Rharb. The use of a database consisting of geo-electrical cross sections, hydrogeological drilling and wireline logging integrated in a Geographic Information System (GIS) allowed us to establish a new three-dimensional model of the top of the Mio-Pliocene substratum, new geo-electrical cross sections, as well as the isopach maps of lower, intermediate, upper and superficial geo-electric interval. This approach allowed us to characterize the Plio-Quaternary deposits of the study area and to highlight the effects of the tectonic regime and the relative sea level fluctuations on the sequential organization of these deposits. Our new model shows the development of prograding, aggrading and retrograding parasequences denoting the existence of autogenic mechanisms in the organization of plio-quaternary deposits of the eastern part of the Rharb basin. Therefore, it opens new perspectives for the exploration of water resources and monitoring their quality throughout the basin.

  10. Multiple ash layers in late Quaternary sediments from the Central Indian Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Mascarenhas-Pereira, M.B.L.; Nath, B.N.; Iyer, S.D.; Borole, D.V.; Parthiban, G.; Jijin, R.; Khedekar, V.D.

    to those originated from Toba, the age (>180 ka) of the shard-bearing sediments was different from the major Quaternary Toba eruptions namely Young, Middle and Old Toba Tuff (YTT, MTT and OTT) and other rhyolitic eruptions in the Indian Ocean. This fact.... 4. Discussion Prior to delving into the discussion it would be pertinent to clarify certain aspects that may have a bearing on the distribution, characteristics, composition, source and age of the volcanic horizons. The premises that we have...

  11. Abundance and size variation of Globorotalia menardii in the Northeastern Indian Ocean during the Late Quaternary

    Digital Repository Service at National Institute of Oceanography (India)

    Bhonsale, S.; Saraswat, R.

    reconstructions. Palaeogeogra., Palaeoclimatol., Palaeoecol. 160, 193-212. Kennett, J.P., Huddlestun, P., 1972. Late Pleistocene paleoclimatology, foraminiferal biostratigraphy and tephrochronology, western Gulf of Mexico. Quat. Res. 2, 3-9. Knappertsbusch, M... monsoon 2001. Deep-Sea Res. 50, 881-896. Malmgren, B., Healy-Williams, N., 1978. Variation in test diameter of Orbulina universa in the paleoclimatology of the late Quaternary of the Gulf of Mexico. Palaeogeogra., Palaeoclimatol., Palaeoecol. 25, 235...

  12. Synthesis and Characterization of Novel Ternary and Quaternary Alkali Metal Thiophosphates

    KAUST Repository

    Alahmary, Fatimah S.

    2014-05-01

    The ongoing development of nonlinear optical (NLO) crystals such as coherent mid-IR sources focuses on various classes of materials such as ternary and quaternary metal chalcophosphates. In case of thiophosphates, the connection between PS4-tetrahedral building blocks and metals gives rise to a broad structural variety where approximately one third of all known ternary (A/P/S) and quaternary (A/M/P/S) (A = alkali metal, M = metal) structures are acentric and potential nonlinear optical materials. The molten alkali metal polychalcophosphate fluxes are a well-established method for the synthesis of new ternary and quaternary thiophosphate and selenophosphate compounds. It has been a wide field of study and investigation through the last two decades. Here, the flux method is used for the synthesis of new quaternary phases containing Rb, Ag, P and S. Four new alkali metal thiophosphates, Rb4P2S10, RbAg5(PS4), Rb2AgPS4 and Rb3Ag9(PS4)4, have been synthesized successfully from high purity elements and binary starting materials. The new compounds were characterized by single crystal and powder X-ray diffraction, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), ultraviolet-visible (UV-VIS), Raman spectroscopy, thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). These compounds show interesting structural variety and physical properties. The crystal structures feature 3D anionic framework built up of PS4 tetrahedral units and charge balanced by Ag and alkali metal cations. All prepared compounds are semiconductors with band gap between 2.3 eV to 2.6 eV and most of them are thermally stable up to 600ºC.

  13. A glimpse of the Quaternary monsoon history from India and adjoining seas

    Digital Repository Service at National Institute of Oceanography (India)

    Saraswat, R.; Nigam, R.; Correge, T.

    /plain; charset=UTF-8 1    Author version: Palaeogeogr. Palaeoclimatol. Palaeoecol., vol.397; 2014; 1-6 A glimpse of the Quaternary monsoon history from India and adjoining seas Rajeev Saraswat1, Rajiv Nigam1, Thierry Correge2 1 National... and radionuclide (210Pb) analyses to understand past environmental changes from the sediment cores collected from mudflat regions of central west coast of India. A significant shift in sediment characteristics is observed post 1980, probably in response...

  14. Thermoelectric performance of tellurium-reduced quaternary p-type lead–chalcogenide composites

    International Nuclear Information System (INIS)

    Aminorroaya Yamini, Sima; Wang, Heng; Gibbs, Zachary M.; Pei, Yanzhong; Mitchell, David R.G.; Dou, Shi Xue; Snyder, G. Jeffrey

    2014-01-01

    Graphical abstract: - Abstract: A long-standing technological challenge to the widespread application of thermoelectric generators is obtaining high-performance thermoelectric materials from abundant elements. Intensive study on PbTe alloys has resulted in a high figure of merit for the single-phase ternary PbTe–PbSe system through band structure engineering, and the low thermal conductivity achieved due to nanostructuring leads to high thermoelectric performance for ternary PbTe–PbS compounds. Recently, the single-phase p-type quaternary PbTe–PbSe–PbS alloys have been shown to provide thermoelectric performance superior to the binary and ternary lead chalcogenides. This occurs via tuning of the band structure and from an extraordinary low thermal conductivity resulting from high-contrast atomic mass solute atoms. Here, we present the thermoelectric efficiency of nanostructured p-type quaternary PbTe–PbSe–PbS composites and compare the results with corresponding single-phase quaternary lead chalcogenide alloys. We demonstrate that the very low lattice thermal conductivity achieved is attributed to phonon scattering at high-contrast atomic mass solute atoms rather than from the contribution of secondary phases. This results in a thermoelectric efficiency of ∼1.4 over a wide temperature range (650–850 K) in a p-type quaternary (PbTe) 0.65 (PbSe) 0.1 (PbS) 0.25 composite that is lower than that of single-phase (PbTe) 0.85 (PbSe) 0.1 (PbS) 0.05 alloy without secondary phases

  15. Quaternary faulting in the Tatra Mountains, evidence from cave morphology and fault-slip analysis

    OpenAIRE

    Szczygieł Jacek

    2015-01-01

    Tectonically deformed cave passages in the Tatra Mts (Central Western Carpathians) indicate some fault activity during the Quaternary. Displacements occur in the youngest passages of the caves indicating (based on previous U-series dating of speleothems) an Eemian or younger age for those faults, and so one tectonic stage. On the basis of stress analysis and geomorphological observations, two different mechanisms are proposed as responsible for the development of these displacements. The firs...

  16. Quantitative analysis of deuterium using the isotopic effect on quaternary {sup 13}C NMR chemical shifts

    Energy Technology Data Exchange (ETDEWEB)

    Darwish, Tamim A., E-mail: tamim.darwish@ansto.gov.au [National Deuteration Facility, Australian Nuclear Science and Technology Organisation, Locked Bag 21, Kirrawee DC, NSW 2232 (Australia); Yepuri, Nageshwar Rao; Holden, Peter J. [National Deuteration Facility, Australian Nuclear Science and Technology Organisation, Locked Bag 21, Kirrawee DC, NSW 2232 (Australia); James, Michael [Australian Synchrotron, 800 Blackburn Road, Clayton, Victoria 3168 (Australia)

    2016-07-13

    Quantitative analysis of specifically deuterated compounds can be achieved by a number of conventional methods, such as mass spectroscopy, or by quantifying the residual {sup 1}H NMR signals compared to signals from internal standards. However, site specific quantification using these methods becomes challenging when dealing with non-specifically or randomly deuterated compounds that are produced by metal catalyzed hydrothermal reactions in D{sub 2}O, one of the most convenient deuteration methods. In this study, deuterium-induced NMR isotope shifts of quaternary {sup 13}C resonances neighboring deuterated sites have been utilized to quantify the degree of isotope labeling of molecular sites in non-specifically deuterated molecules. By probing {sup 13}C NMR signals while decoupling both proton and deuterium nuclei, it is possible to resolve {sup 13}C resonances of the different isotopologues based on the isotopic shifts and the degree of deuteration of the carbon atoms. We demonstrate that in different isotopologues, the same quaternary carbon, neighboring partially deuterated carbon atoms, are affected to an equal extent by relaxation. Decoupling both nuclei ({sup 1}H, {sup 2}H) resolves closely separated quaternary {sup 13}C signals of the different isotopologues, and allows their accurate integration and quantification under short relaxation delays (D1 = 1 s) and hence fast accumulative spectral acquisition. We have performed a number of approaches to quantify the deuterium content at different specific sites to demonstrate a convenient and generic analysis method for use in randomly deuterated molecules, or in cases of specifically deuterated molecules where back-exchange processes may take place during work up. - Graphical abstract: The relative intensities of quaternary {sup 13}C {"1H,"2H} resonances are equal despite the different relaxation delays, allowing the relative abundance of the different deuterated isotopologues to be calculated using NMR fast

  17. A multi-disciplinary review of late Quaternary palaeoclimates and environments for Lesotho

    Directory of Open Access Journals (Sweden)

    Jennifer M. Fitchett

    2016-07-01

    Full Text Available Lesotho provides a unique context for palaeoclimatic research. The small country is entirely landlocked by South Africa, yet has considerable variation in topography, climate, and associated vegetation over an approximate east-west transect. The region has been of archaeological interest for over a century, and hosts many Early to Late Stone Age sites with occupation preceding 80 000 years before present. The eastern Lesotho highlands are of interest to periglacial and glacial geomorphologists because of their well-preserved relict landforms and contentious evidence for permafrost and niche glaciation during the late Quaternary. However, continuous proxy records for palaeoenvironmental reconstructions for Lesotho are scarce and hampered by a range of methodological shortfalls. These challenges include uncertain ages, poor sampling resolution, and proxies extracted from archaeological excavations for which there may be bias in selection. Inferences on palaeoclimates are thus based predominantly on archaeological and palaeogeomorphological evidence for discrete periods during the late Quaternary. This review paper presents a more detailed multidisciplinary synthesis of late Quaternary conditions in Lesotho. We simultaneously considered the varying data that contribute to the under-studied palaeoenvironmental record for southern Africa. The collective palaeoenvironmental data for eastern Lesotho were shown to be relatively contradictory, with considerable variations in contemporaneous palaeoclimatic conditions within the study area. We argue that although methodological challenges may contribute to this variation, the marked changes in topography result in contrasting late Quaternary palaeoenvironments. Such environments are characterised by similar contrasting microclimates and niche ecologies as are witnessed in the contemporary landscape. These spatial variations within a relatively small landlocked country are of importance in understanding

  18. Soft antimicrobial agents: synthesis and activity of labile environmentally friendly long chain quaternary ammonium compounds.

    Science.gov (United States)

    Thorsteinsson, Thorsteinn; Másson, Már; Kristinsson, Karl G; Hjálmarsdóttir, Martha A; Hilmarsson, Hilmar; Loftsson, Thorsteinn

    2003-09-11

    A series of soft quaternary ammonium antimicrobial agents, which are analogues to currently used quaternary ammonium preservatives such as cetyl pyridinium chloride and benzalkonium chloride, were synthesized. These soft analogues consist of long alkyl chain connected to a polar headgroup via chemically labile spacer group. They are characterized by facile nonenzymatic and enzymatic degradation to form their original nontoxic building blocks. However, their chemical stability has to be adequate in order for them to have antimicrobial effects. Stability studies and antibacterial and antiviral activity measurements revealed relationship between activity, lipophilicity, and stability. Their minimum inhibitory concentration (MIC) was as low as 1 microg/mL, and their viral reduction was in some cases greater than 6.7 log. The structure-activity studies demonstrate that the bioactive compounds (i.e., MIC for Gram-positive bacteria of <10 microg/mL) have an alkyl chain length between 12 and 18 carbon atoms, with a polar headgroup preferably of a small quaternary ammonium group, and their acquired inactivation half-life must be greater than 3 h at 60 degrees C.

  19. Physical, chemical and antimicrobial evaluation of a composite material containing quaternary ammonium salt for braces cementation

    Energy Technology Data Exchange (ETDEWEB)

    Sugii, Mari Miura [Departamento de Odontologia Restaurativa, Faculdade de Odontologia de Piracicaba – Universidade de Campinas, Piracicaba, SP 13414-903 (Brazil); Ferreira, Fábio Augusto de Souza, E-mail: ferreira.fabio.a.s@gmail.com [Grupo de Química de Materiais Híbridos e Inorgânicos, Instituto de Química de São Carlos – Universidade de São Paulo, São Carlos, SP 13563-120 (Brazil); Müller, Karina Cogo [Departamento de Ciências Fisiológicas, Área de Farmacologia, Anestesiologia e Terapeutica, Faculdade de Odontologia de Piracicaba – Universidade de Campinas, Piracicaba, SP 13414-903 (Brazil); Lima, Debora Alves Nunes Leite [Departamento de Odontologia Restaurativa, Faculdade de Odontologia de Piracicaba – Universidade de Campinas, Piracicaba, SP 13414-903 (Brazil); Groppo, Francisco Carlos [Departamento de Ciências Fisiológicas, Área de Farmacologia, Anestesiologia e Terapeutica, Faculdade de Odontologia de Piracicaba – Universidade de Campinas, Piracicaba, SP 13414-903 (Brazil); Imasato, Hidetake; Rodrigues-Filho, Ubirajara Pereira [Grupo de Química de Materiais Híbridos e Inorgânicos, Instituto de Química de São Carlos – Universidade de São Paulo, São Carlos, SP 13563-120 (Brazil); and others

    2017-04-01

    The antibiofilm effect of iodide quaternary ammonium methacryloxy silicate (IQAMS) in Transbond XT Light Cure Adhesive resin used for braces cementation was evaluated. Fourier Transform Infrared (FTIR) spectroscopy confirmed IQAMS formation and Scanning Electron Microscopy coupled to Energy-Dispersive X-ray Spectroscopy (SEM-EDS) revealed that as coating, the quaternary ammonium groups from IQAMS were homogeneously dispersed throughout the surface. When incorporated, the composite material presented homogeneous dispersion throughout the resin. Assays with Streptococcus mutans demonstrated enhanced antibiofilm effect for the IQAMS coated resin, with much lower colony-forming units (CFU), in comparison to incorporated IQAMS. Such a difference was assigned to low availability of quaternary ammonium groups at the surface of resin when IQAMS was incorporated, hindering its antibiofilm effect. Additionally, the incorporation of IQAMS led to slight decrease in ultimate bond strength (UBS) and shear bond strength (SBS), in comparison to the neat commercial resin. Thus, the synthesized IQAMS displays great potential as antibiofilm coating or sealant to prevent oral infections in brackets during orthodontic treatment. - Highlights: • Synthesis of ORMOSIL-based material with antibiofilm activity is performed. • Antibiofilm activity of the ORMOSIL-based material on commercial available resin for braces cementation is evaluated. • Antibiofilm ORMOSIL-based coating with potential application as varnish or sealant in orthodontic appliances is presented.

  20. Phase study in Sr-Th-P-O system: Structural and thermal investigations of quaternary compounds

    International Nuclear Information System (INIS)

    Keskar, Meera; Phatak, Rohan; Sali, S.K.; Krishnan, K.; Dahale, N.D.; Kulkarni, N.K.; Kannan, S.

    2011-01-01

    The sub-solidus phase relations in Sr-Th-P-O quaternary system were determined at 1223 K in air. To confirm the formation and stability of reported phases, ternary and quaternary compounds in Sr-Th-O, Sr-P-O, Th-P-O and Sr-Th-P-O systems were synthesized by solid state reactions of SrCO 3 , ThO 2 and NH 4 H 2 PO 4 in desired molar proportions at 1223 K. A pseudo-ternary phase diagram of SrO-ThO 2 -P 2 O 5 system was drawn on the basis of the phase analysis of various phase mixtures and phase fields were established by powder X-ray diffraction. In the phase diagram, three quaternary compounds SrTh(PO 4 ) 2 , SrTh 4 (PO 4 ) 6 and Sr 7 Th(PO 4 ) 6 were identified. When heated in air at 1673 K, these compounds decompose to ThO 2 . Structures of SrTh(PO 4 ) 2 , SrTh 4 (PO 4 ) 6 and Sr 7 Th(PO 4 ) 6 were derived from X-ray powder data using the Rietveld refinement method. Thermal expansion behaviors of SrTh(PO 4 ) 2 , SrTh 4 (PO 4 ) 6 and Sr 7 Th(PO 4 ) 6 were investigated using high-temperature X-ray diffraction in the temperature range of 298-1273 K.