WorldWideScience

Sample records for argon iodides

  1. Potassium Iodide

    Science.gov (United States)

    Potassium iodide is used to protect the thyroid gland from taking in radioactive iodine that may be ... damage the thyroid gland. You should only take potassium iodide if there is a nuclear radiation emergency ...

  2. Synthesis of mercuric iodide and bismuth tri-iodide nanoparticles for heavy metal iodide films nucleation

    Energy Technology Data Exchange (ETDEWEB)

    Fornaro, L.; Pereira, H.Bentos [Compound Semiconductors Group, CURE, Universidad de la Republica, Rocha (Uruguay); Aguiar, I.; Perez Barthaburu, M. [Compound Semiconductors Group, Facultad de Quimica, Univ. de la Republica, Montevideo (Uruguay)

    2011-12-15

    We synthesized mercuric iodide and bismuth tri-iodide nanoparticles by suspension in octadecene, from Hg(NO{sub 3}){sub 2}.H{sub 2}O and I{sub 2}, and from Bi(NO{sub 3}){sub 3}.5H{sub 2}O and I{sub 2}, respectively. The best synthesis conditions were 2 h at 70-80 C, followed by 10 min at 110 C for mercuric iodide nanoparticles, and 4 h at 80-110 C, followed by 10 min at 180-210 C for bismuth tri-iodide ones. Nanoparticles were then washed and centrifuged with ether repeatedly. Compounds identity was confirmed by X-ray diffraction (XRD) and energy dispersive spectrometry (EDS). We found shifts of the X-ray diffraction maxima for nanoparticles of both compounds. We characterized the nanoparticles by transmission (TEM) and scanning (SEM) electron microscopy. We obtained disk-like and squared mercuric iodide nanostructures, 80-140 nm and 100-125 nm in size respectively. We also obtained rounded and rod-like bismuth tri-iodide nanoparticles, 30-500 nm in size. Acetonitrile and isopropanol suspensions of mercuric iodide nanoparticles, and acetonitrile suspension of bismuth tri-iodide nanoparticles exhibited peak maxima shifts in their UV-Vis spectra. We synthesized for the first time mercuric iodide and bismuth tri-iodide nanoparticles by the suspension method, although we have not yet obtained uniform shape and size distributions. They offer interesting perspectives for crystalline film nucleation and for improving current applications of these materials, as well as for opening new ones. (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  3. 21 CFR 172.375 - Potassium iodide.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Potassium iodide. 172.375 Section 172.375 Food and... Dietary and Nutritional Additives § 172.375 Potassium iodide. The food additive potassium iodide may be safely used in accordance with the following prescribed conditions: (a) Potassium iodide may be...

  4. Mercuric iodide sensor technology

    International Nuclear Information System (INIS)

    This report describes the improvement in the performance and the manufacturing yield of mercuric iodide detectors achieved by identifying the dominant impurities, carrier traps, and processing steps limiting device performance. Theoretical studies of electron and hole transport in this material set fundamental limits on detector performance and provided a standard against which to compare experimental results. Spectroscopy techniques including low temperature photoluminescence and thermally stimulated current spectroscopy were applied to characterize the deep level traps in this material. Traps and defects that can be introduced into the detector during growth, from the contact, and during the various steps in detector fabrication were identified. Trap energy levels and their relative abundances were determined. Variations in material quality and detector performance at the micron scale were investigated to understand the distribution in electric field in large volume detectors suitable for gamma-ray spectroscopy. Surface aging and contact degradation was studied extensively by techniques including atomic force microscopy, transmission electron microscopy, and variable angle spectroscopic ellipsometry. Preferred handling and processing procedures for maximizing detector performance and yield were established. The manufacturing yield of high resolution gamma-ray detectors was improved from a few percent to more than 30%

  5. Depleted Argon from Underground Sources

    International Nuclear Information System (INIS)

    Argon is a strong scintillator and an ideal target for Dark Matter detection; however 39Ar contamination in atmospheric argon from cosmic ray interactions limits the size of liquid argon dark matter detectors due to pile-up. Argon from deep underground is depleted in 39Ar due to the cosmic ray shielding of the earth. In Cortez, Colorado, a CO2 well has been discovered to contain approximately 600 ppm of argon as a contamination in the CO2. We first concentrate the argon locally to 3% in an Ar, N2, and He mixture, from the CO2 through chromatographic gas separation, and then the N2 and He will be removed by continuous distillation to purify the argon. We have collected 26 kg of argon from the CO2 facility and a cryogenic distillation column is under construction at Fermilab to further purify the argon.

  6. Argon in action

    CERN Multimedia

    Corinne Pralavorio

    2015-01-01

    Over the past few days, the SPS has been accelerating argon ions, which have started to be sent to the NA61/SHINE experiment. This operating mode, using a new type of ion, required a number of modifications to the accelerator.   Picture 1: a “super-cycle” of the SPS, featuring a proton cycle for the LHC, followed by an argon ion cycle for the North Area. Today, the accelerators are once again juggling particles and even performing completely new tricks. The SPS is supplying beams of argon ions for the first time, at energies never before achieved for this type of beam. They are destined for the NA61/SHINE experiment (see box) located in the North Area, which began receiving the beams on 11 February. Argon ions have a relatively large mass, as they consist of 40 nucleons, so they can be used in a similar way to lead ions. The main difficulty in accelerating them lies in the SPS, where the variation in acceleration frequency is limited. “The SPS was designed for a...

  7. Thermophysical properties of argon

    Energy Technology Data Exchange (ETDEWEB)

    Jaques, A.

    1988-02-01

    The entire report consists of tables of thermodynamic properties (including sound velocity, thermal conductivity and diffusivity, Prandtl number, density) of argon at 86 to 400/degree/K, in the form of isobars over 0.9 to 100 bars. (DLC)

  8. 21 CFR 184.1634 - Potassium iodide.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Potassium iodide. 184.1634 Section 184.1634 Food... Specific Substances Affirmed as GRAS § 184.1634 Potassium iodide. (a) Potassium iodide (KI, CAS Reg. No. 7681-11-0) is the potassium salt of hydriodic acid. It occurs naturally in sea water and in...

  9. 21 CFR 582.5634 - Potassium iodide.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Potassium iodide. 582.5634 Section 582.5634 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL... Supplements 1 § 582.5634 Potassium iodide. (a) Product. Potassium iodide. (b) Tolerance. 0.01 percent....

  10. Liquid argon neutrino detectors

    CERN Document Server

    Battistoni, G

    2001-01-01

    The liquid argon imaging technique, as proposed for the ICARUS detector, offers the possibility to perform complementary and simultaneous measurements of neutrinos, as those of CERN to Gran Sasso beam (CNGS) and those from cosmic ray events. For the currently allowed values of the Super-Kamiokande results, the combination of both CNGS and atmospheric data will provide a precise determination of the oscillation parameters. Since one can observe and unambiguously identify nu /sub e/, nu /sub mu / and nu /sub tau / components, this technology allows to explore the full (3*3) mixing matrix. The same class of detector can be proposed for high precision measurements at a neutrino factory. (3 refs).

  11. Isentropic compression of argon

    Energy Technology Data Exchange (ETDEWEB)

    Veeser, L.R.; Ekdahl, C.A.; Oona, H. [and others

    1997-06-01

    The compression was done in an MC-1 flux compression (explosive) generator, in order to study the transition from an insulator to a conductor. Since conductivity signals were observed in all the experiments (except when the probe is removed), both the Teflon and the argon are becoming conductive. The conductivity could not be determined (Teflon insulation properties unknown), but it could be bounded as being {sigma}=1/{rho}{le}8({Omega}cm){sub -1}, because when the Teflon breaks down, the dielectric constant is reduced. The Teflon insulator problem remains, and other ways to better insulate the probe or to measure the conductivity without a probe is being sought.

  12. Uptake of iodide in the marine haptophyte Isochrysis sp. (T.ISO) driven by iodide oxidation.

    Science.gov (United States)

    van Bergeijk, Stef A; Hernández Javier, Laura; Heyland, Andreas; Manchado, Manuel; Pedro Cañavate, José

    2013-08-01

    Uptake of iodide was studied in the marine microalga Isochrysis sp. (isol. Haines, T.ISO) during short-term incubations with radioactive iodide ((125) I(-) ). Typical inhibitors of the sodium/iodide symporter (NIS) did not inhibit iodide uptake, suggesting that iodide is not taken up through this transport protein, as is the case in most vertebrate animals. Oxidation of iodide was found to be an essential step for its uptake by T.ISO and it seemed likely that hypoiodous acid (HOI) was the form of iodine taken up. Uptake of iodide was inhibited by the addition of thiourea and of other reducing agents, like L-ascorbic acid, L-glutathione and L-cysteine and increased after the addition of oxidized forms of the transition metals Fe and Mn. The simultaneous addition of both hydrogen peroxide (H2 O2 ) and a known iodide-oxidizing myeloperoxidase (MPO) significantly increased iodine uptake, but the addition of H2 O2 or MPO separately, had no effect on uptake. This confirms the observation that iodide is oxidized prior to uptake, but it puts into doubt the involvement of H2 O2 excretion and membrane-bound or extracellular haloperoxidase activity of T.ISO. The increase of iodide uptake by T.ISO upon Fe(III) addition suggests the nonenzymatic oxidation of iodide by Fe(III) in a redox reaction and subsequent influx of HOI. This is the first report on the mechanism of iodide uptake in a marine microalga.

  13. Neutron Detection with Mercuric Iodide

    CERN Document Server

    Bell, Z A

    2003-01-01

    Mercuric iodide is a high-density, high-Z semiconducting material useful for gamma ray detection. This makes it convertible to a thermal neutron detector by covering it with a boron rich material and detecting the 478 keV gamma rays resulting from the sup 1 sup 0 B(n, alpha) sup 7 Li* reaction. However, the 374 barn thermal capture cross section of sup n sup a sup t Hg, makes the detector itself an attractive absorber, and this has been exploited previously. Since previous work indicates that there are no low-energy gamma rays emitted in coincidence with the 368 keV capture gamma from the dominant sup 1 sup 9 sup 9 Hg(n, gamma) sup 2 sup 0 sup 0 Hg reaction, only the 368 keV capture gamma is seen with any efficiency a relatively thin (few mm) detector. In this paper we report preliminary measurements of neutrons via capture reactions in a bare mercuric iodide crystal and a crystal covered in sup 1 sup 0 B-loaded epoxy. The covered detector is an improvement over the bare detector because the presence of both ...

  14. Neutron Detection with Mercuric Iodide

    Energy Technology Data Exchange (ETDEWEB)

    Bell, Z.A.

    2003-06-17

    Mercuric iodide is a high-density, high-Z semiconducting material useful for gamma ray detection. This makes it convertible to a thermal neutron detector by covering it with a boron rich material and detecting the 478 keV gamma rays resulting from the {sup 10}B(n, {alpha}){sup 7}Li* reaction. However, the 374 barn thermal capture cross section of {sup nat}Hg, makes the detector itself an attractive absorber, and this has been exploited previously. Since previous work indicates that there are no low-energy gamma rays emitted in coincidence with the 368 keV capture gamma from the dominant {sup 199}Hg(n, {gamma}){sup 200}Hg reaction, only the 368 keV capture gamma is seen with any efficiency a relatively thin (few mm) detector. In this paper we report preliminary measurements of neutrons via capture reactions in a bare mercuric iodide crystal and a crystal covered in {sup 10}B-loaded epoxy. The covered detector is an improvement over the bare detector because the presence of both the 478 and 368 keV gamma rays removes the ambiguity associated with the observation of only one of them. Pulse height spectra, obtained with and without lead and cadmium absorbers, showed the expected gamma rays and demonstrated that they were caused by neutrons.

  15. Rare, severe hypersensitivity reaction to potassium iodide

    DEFF Research Database (Denmark)

    Nielsen, Anne Sofie Korsholm; Ebbehøj, Eva; Richelsen, Bjørn

    2014-01-01

    The literature reports a large variety of adverse reactions to potassium iodide. A severe hypersensitivity reaction to potassium iodide in a 51-year-old woman with Graves' thyrotoxicosis is described. Following administration the patient developed sialadenitis, conjunctivitis, stomatitis and acne...

  16. Depleted argon from underground sources

    Energy Technology Data Exchange (ETDEWEB)

    Back, H.O.; /Princeton U.; Alton, A.; /Augustana U. Coll.; Calaprice, F.; Galbiati, C.; Goretti, A.; /Princeton U.; Kendziora, C.; /Fermilab; Loer, B.; /Princeton U.; Montanari, D.; /Fermilab; Mosteiro, P.; /Princeton U.; Pordes, S.; /Fermilab

    2011-09-01

    Argon is a powerful scintillator and an excellent medium for detection of ionization. Its high discrimination power against minimum ionization tracks, in favor of selection of nuclear recoils, makes it an attractive medium for direct detection of WIMP dark matter. However, cosmogenic {sup 39}Ar contamination in atmospheric argon limits the size of liquid argon dark matter detectors due to pile-up. The cosmic ray shielding by the earth means that Argon from deep underground is depleted in {sup 39}Ar. In Cortez Colorado a CO{sub 2} well has been discovered to contain approximately 500ppm of argon as a contamination in the CO{sub 2}. In order to produce argon for dark matter detectors we first concentrate the argon locally to 3-5% in an Ar, N{sub 2}, and He mixture, from the CO{sub 2} through chromatographic gas separation. The N{sub 2} and He will be removed by continuous cryogenic distillation in the Cryogenic Distillation Column recently built at Fermilab. In this talk we will discuss the entire extraction and purification process; with emphasis on the recent commissioning and initial performance of the cryogenic distillation column purification.

  17. Predissociation dynamics of lithium iodide

    CERN Document Server

    Schmidt, H; Stienkemeier, F; Bogomolov, A S; Baklanov, A V; Reich, D M; Skomorowski, W; Koch, C P; Mudrich, M

    2015-01-01

    The predissociation dynamics of lithium iodide (LiI) in the first excited A-state is investigated for molecules in the gas phase and embedded in helium nanodroplets, using femtosecond pump-probe photoionization spectroscopy. In the gas phase, the transient Li+ and LiI+ ion signals feature damped oscillations due to the excitation and decay of a vibrational wave packet. Based on high-level ab initio calculations of the electronic structure of LiI and simulations of the wave packet dynamics, the exponential signal decay is found to result from predissociation predominantly at the lowest avoided X-A potential curve crossing, for which we infer a coupling constant V=650(20) reciprocal cm. The lack of a pump-probe delay dependence for the case of LiI embedded in helium nanodroplets indicates fast droplet-induced relaxation of the vibrational excitation.

  18. Predissociation dynamics of lithium iodide

    Energy Technology Data Exchange (ETDEWEB)

    Schmidt, H.; Vangerow, J. von; Stienkemeier, F.; Mudrich, M., E-mail: mudrich@physik.uni-freiburg.de [Physikalisches Institut, Universität Freiburg, 79104 Freiburg (Germany); Bogomolov, A. S. [Institute of Chemical Kinetics and Combustion, Novosibirsk 630090 (Russian Federation); Baklanov, A. V. [Institute of Chemical Kinetics and Combustion, Novosibirsk 630090 (Russian Federation); Novosibirsk State University, Novosibirsk 630090 (Russian Federation); Reich, D. M.; Skomorowski, W.; Koch, C. P. [Theoretische Physik, Universität Kassel, Heinrich-Plett-Str. 40, 34132 Kassel (Germany)

    2015-01-28

    The predissociation dynamics of lithium iodide (LiI) in the first excited A-state is investigated for molecules in the gas phase and embedded in helium nanodroplets, using femtosecond pump-probe photoionization spectroscopy. In the gas phase, the transient Li{sup +} and LiI{sup +} ion signals feature damped oscillations due to the excitation and decay of a vibrational wave packet. Based on high-level ab initio calculations of the electronic structure of LiI and simulations of the wave packet dynamics, the exponential signal decay is found to result from predissociation predominantly at the lowest avoided X-A potential curve crossing, for which we infer a coupling constant V{sub XA} = 650(20) cm{sup −1}. The lack of a pump-probe delay dependence for the case of LiI embedded in helium nanodroplets indicates fast droplet-induced relaxation of the vibrational excitation.

  19. The Liquid Argon Purity Demonstrator

    CERN Document Server

    Adamowski, M; Dvorak, E; Hahn, A; Jaskierny, W; Johnson, C; Jostlein, H; Kendziora, C; Lockwitz, S; Pahlka, B; Plunkett, R; Pordes, S; Rebel, B; Schmitt, R; Stancari, M; Tope, T; Voirin, E; Yang, T

    2014-01-01

    The Liquid Argon Purity Demonstrator was an R&D test stand designed to determine if electron drift lifetimes adequate for large neutrino detectors could be achieved without first evacuating the cryostat. We describe here the cryogenic system, its operations, and the apparatus used to determine the contaminant levels in the argon and to measure the electron drift lifetime. The liquid purity obtained by this system was facilitated by a gaseous argon purge. Additionally, gaseous impurities from the ullage were prevented from entering the liquid at the gas-liquid interface by condensing the gas and filtering the resulting liquid before returning to the cryostat. The measured electron drift lifetime in this test was greater than 6 ms, sustained over several periods of many weeks. Measurements of the temperature profile in the argon, to assess convective flow and boiling, were also made and are compared to simulation.

  20. The Liquid Argon Purity Demonstrator

    Energy Technology Data Exchange (ETDEWEB)

    Adamowski, M.; Carls, B.; Dvorak, E.; Hahn, A.; Jaskierny, W.; Johnson, C.; Jostlein, H.; Kendziora, C.; Lockwitz, S.; Pahlka, B.; Plunkett, R.; Pordes, S.; Rebel, B.; Schmitt, R.; Stancari, M.; Tope, T.; Voirin, E.; Yang, T.

    2014-07-01

    The Liquid Argon Purity Demonstrator was an R&D test stand designed to determine if electron drift lifetimes adequate for large neutrino detectors could be achieved without first evacuating the cryostat. We describe here the cryogenic system, its operations, and the apparatus used to determine the contaminant levels in the argon and to measure the electron drift lifetime. The liquid purity obtained by this system was facilitated by a gaseous argon purge. Additionally, gaseous impurities from the ullage were prevented from entering the liquid at the gas-liquid interface by condensing the gas and filtering the resulting liquid before returning to the cryostat. The measured electron drift lifetime in this test was greater than 6 ms, sustained over several periods of many weeks. Measurements of the temperature profile in the argon, to assess convective flow and boiling, were also made and are compared to simulation.

  1. Efficient radiation production in a weakly ionized, low-pressure, nonequilibrium gallium-iodide positive column discharge plasma

    Energy Technology Data Exchange (ETDEWEB)

    Smith, David J; Michael, J Darryl; Midha, Vikas; Cotzas, George M; Sommerer, Timothy J [General Electric Research, One Research Circle, Niskayuna, NY 12309 (United States)

    2007-07-07

    Electric-discharge plasmas in gallium-iodide vapours are experimentally found to convert 40% of input electric power into ultraviolet and visible radiation (200-800 nm). The conditions are a weakly ionized positive column consisting of 5-10 Torr argon, and the gallium-iodide vapour is formed by heating condensed gallium-iodide to 100-120 deg. C. The input power density is 50-100 mW cm{sup -3}. The plasma is contained in a sealed silica tube and excited by an external radiofrequency antenna. Computational analysis and plasma diagnostics lead to a quantitative understanding that gallium atoms are formed by electron-impact dissociation of gallium-iodide compounds that evaporate into the plasma volume, and that further electron collisions excite the gallium atoms, which then decay by photon emission. High efficiency is possible only because several photons are emitted per dissociation event, and because nonradiative power channels such as electron-impact elastic heating and vibrational excitation are not dominant. The dissociated species recombine on the wall to reform the species that evaporates. The plasma properties change discontinuously as the molar ratio of iodine to gallium (I/Ga) in the system crosses the values I/Ga = 3 and I/Ga = 2, consistent with the thermodynamic properties of condensed gallium-iodide compounds.

  2. Plasma etching of cesium iodide

    International Nuclear Information System (INIS)

    Thick films of cesium iodide (CsI) are often used to convert x-ray images into visible light. Spreading of the visible light within CsI, however, reduces the resolution of the resulting image. Anisotropic etching of the CsI film into an array of micropixels can improve the image resolution by confining light within each pixel. The etching process uses a high-density inductively coupled plasma to pattern CsI samples held by a heated, rf-biased chuck. Fluorine-containing gases such as CF4 are found to enhance the etch rate by an order of magnitude compared to Ar+ sputtering alone. Without inert-gas ion bombardment, however, the CF4 etch becomes self-limited within a few microns of depth due to the blanket deposition of a passivation layer. Using CF4+Ar continuously removes this layer from the lateral surfaces, but the formation of a thick passivation layer on the unbombarded sidewalls of etched features is observed by scanning electron microscopy. At a substrate temperature of 220 deg. C, the minimum ion-bombardment energy for etching is Ei∼50 eV, and the rate depends on Ei1/2 above 65 eV. In dilute mixtures of CF4 and Ar, the etch rate is proportional to the gas-phase density of atomic fluorine. Above 50% CF4, however, the rate decreases, indicating the onset of net surface polymer deposition. These observations suggest that anisotropy is obtained through the ion-enhanced inhibitor etching mechanism. Etching exhibits an Arrhenius-type behavior in which the etch rate increases from ∼40 nm/min at 40 deg. C to 380 nm/min at 330 deg. C. The temperature dependence corresponds to an activation energy of 0.13±0.01 eV. This activation energy is consistent with the electronic sputtering mechanism for alkali halides

  3. Fano factor in pure argon

    International Nuclear Information System (INIS)

    The Fano factor for 5.3 MeV alpha particles in pure argon has been measured with a gridded ionization chamber and estimated to be 0.20 (+0.01-0.02). The obtained value is consistent with the theoretical value if the contribution of elastic nuclear collisions to the Fano factor is taken into the consideration. There is no appreciable difference between the values for pure argon and for a gas mixture of Ar (10%)CH4 obtained in the previous measurement. (orig.)

  4. The partitioning of iodides into steam

    International Nuclear Information System (INIS)

    In order to estimate the likely releases of radioactive iodine during steam generator tube rupture (SGTR) faults, it is necessary to know the relevant partition coefficients as a function of temperature and solution composition. It has been suggested previously that, under SGTR fault conditions, partitioning of free or ion-paired I- into the steam may be more extensive than that for molecular HI. This report uses available information on the partitioning of iodides and other salts to provide a means of estimating the partition coefficient of the iodide ion as a function of boric acid concentration and temperature. (author)

  5. Adsorption of radioactive iodide by natural zeolites

    International Nuclear Information System (INIS)

    Two natural zeolites from Iranian deposits (clinoptilolite and natrolite) were characterized and their ability for adsorption of iodide from nuclear wastewaters was evaluated. The adsorption behavior was studied on natural and modified zeolites by γ-spectrometry using 131I as radiotracer. Adsorption isotherms and distribution coefficient (Kd) were measured. The results showed that clinoptilolite is a more promising zeolite for removal of iodide compared to natrolite. Furthermore, the adsorption was higher in silver, lead and thallium forms, whereas the lowest desorption was observed in lead modified zeolite. (author)

  6. Attainable superheat of argon-helium, argon-neon solutions.

    Science.gov (United States)

    Baidakov, Vladimir G; Kaverin, Aleksey M; Andbaeva, Valentina N

    2008-10-16

    The method of lifetime measurement has been used to investigate the kinetics of spontaneous boiling-up of superheated argon-helium and argon-neon solutions. Experiments were made at a pressure of p = 1.5 MPa and concentrations up to 0.33 mol% in the range of nucleation rates from 10 (4) to 10 (8) s (-1) m (-3). The homogeneous nucleation regime has been distinguished. With good agreement between experimental data and homogeneous nucleation theory in temperature and concentration dependences of the nucleation rate, a systematic underestimation by 0.25-0.34 K has been revealed in superheat temperatures over the saturated line attained by experiment as compared with theoretical values calculated in a macroscopic approximation. The revealed disagreement between theory and experiment is connected with the dependence of the properties of new-phase nuclei on their size.

  7. Electrochemical reaction rates in a dye sentisised solar cell - the iodide/tri-iodide redox system

    DEFF Research Database (Denmark)

    Bay, Lasse; West, Keld; Winter-Jensen, Bjørn;

    2006-01-01

    The electrochemical reaction rate of the redox couple iodide / tri-iodide in acetonitrile is characterised by impedance spectroscopy. Different electrode materials relevant for the function of dye-sensitised solar cells (DSSC) are investigated. Preferably, the reaction with the iodide / tri......), and polyaniline (PANI) - all deposited onto fluorine doped tin oxide (FTO) glass. Both Pt and PEDOT are found to have sufficiently high catalytic activities for practical use as counter electrode in DSSC. The reaction resistance on FTO and anatase confirmed the beneficial effect of a compact anatase layer on top...

  8. Binocular indirect argon laser photocoagulator.

    OpenAIRE

    Mizuno, K

    1981-01-01

    The binocular indirect argon laser photocoagulator was newly designed to enable visualisation of the entire fundus during panretinal laser photocoagulation and to treat retinal tears immediately after buckling procedures of the sclera. The lamp housing of the binocular ophthalmoscope was remodelled and adjusted so that the laser beam and illuminating light are coaxial after leaving the ophthalmoscope. The blocking filter was permanently fixed in the eye-pieces to lighten the weight of the oph...

  9. 21 CFR 184.1265 - Cuprous iodide.

    Science.gov (United States)

    2010-04-01

    ... the following specific limitations: Category of food Maximum treatment level in food Functional use... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Cuprous iodide. 184.1265 Section 184.1265 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR...

  10. Electronic and optical properties of lead iodide

    DEFF Research Database (Denmark)

    Ahuja, R.; Arwin, H.; Ferreira da Silva, A.;

    2002-01-01

    The electronic properties and the optical absorption of lead iodide (PbI2) have been investigated experimentally by means of optical absorption and spectroscopic ellipsometry, and theoretically by a full-potential linear muffin-tin-orbital method. PbI2 has been recognized as a very promising...

  11. Liquid Argon Barrel Cryostat Arrived

    CERN Multimedia

    Pailler, P

    Last week the first of three cryostats for the ATLAS liquid argon calorimeter arrived at CERN. It had travelled for 46 days over several thousand kilometers from Japan to CERN. During three years it has been fabricated by Kawasaki Heavy Industries Ltd. at Harima, close to Kobe, under contract from Brookhaven National Laboratory (BNL) of the U.S.. This cryostat consists of two concentric cylinders made of aluminium: the outer vacuum vessel with a diameter of 5.5 m and a length of 7 m, and the inner cold vessel which will contain the electromagnetic barrel calorimeter immersed in liquid argon. The total weight will be 270 tons including the detectors and the liquid argon. The cryostat is now located in building 180 where it will be equipped with 64 feed-throughs which serve for the passage of 122,880 electrical lines which will carry the signals of the calorimeter. After integration of the calorimeter, the solenoidal magnet of ATLAS will be integrated in the vacuum vessel. A final cold test of the cryostat inc...

  12. Cu-catalyzed trifluoromethylation of aryl iodides with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide

    OpenAIRE

    Yuzo Nakamura; Motohiro Fujiu; Tatsuya Murase; Yoshimitsu Itoh; Hiroki Serizawa; Kohsuke Aikawa; Koichi Mikami

    2013-01-01

    The trifluoromethylation of aryl iodides catalyzed by copper(I) salt with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide and Zn dust was accomplished. The catalytic reactions proceeded under mild reaction conditions, providing the corresponding aromatic trifluoromethylated products in moderate to high yields. The advantage of this method is that additives such as metal fluoride (MF), which are indispensable to activate silyl groups for transmetallation in the corresp...

  13. Composing Experimental Environment of PRIDE Argon cell

    Energy Technology Data Exchange (ETDEWEB)

    Noh, Seonho; Jang, Yongkuk; Cho, Il Je [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-10-15

    In PRIDE depleted Uranium feed material and a depleted Uranium mixed with some surrogate material are used for performing engineering scale Pyroprocessing. PRIDE has to maintain inert atmosphere because of the characteristic of Electrolytic Reduction technology, Electro refining technology, Electrowinning technology. The impurity concentration of the Argon cell has to be under 50 ppm(Oxygen, moisture). Atmospheric pressure changes and temperature changes can affect the Argon cell's impurity concentration. In this paper, how to compose the Argon cell impurity concentration under 50 ppm to make the exact optimal experimental environment(Oxygen, moisture) will be introduced. Composing the exact optimal experimental environment by supplying Argon gas have been introduced in this paper. Continuously supplying Argon gas which is heavier than the Oxygen through the bottom of the Argon cell the oxygen eventually discharged through the high vent fan and lower the impurity concentration of Oxygen.

  14. Electrochemical reaction rates in a dye-sensitised solar cell - the iodide/tri-iodide redox system

    DEFF Research Database (Denmark)

    Bay, L.; West, K.; Winther-Jensen, B.;

    2006-01-01

    The electrochemical reaction rate of the redox couple iodide/tri-iodide in acetonitrile is characterised by impedance spectroscopy. Different electrode materials relevant for the function of dye-sensitised solar cells (DSSC) are investigated. Preferably, the reaction with the iodide/tri-iodide co......The electrochemical reaction rate of the redox couple iodide/tri-iodide in acetonitrile is characterised by impedance spectroscopy. Different electrode materials relevant for the function of dye-sensitised solar cells (DSSC) are investigated. Preferably, the reaction with the iodide......), and polyaniline (PANI)-all deposited onto fluorine-doped tin oxide (FTO) glass. Both Pt and PEDOT are found to have sufficiently high catalytic activities for practical use as counter electrodes in DSSC. The reaction resistance on FTO and anatase confirmed the beneficial effect of a compact anatase layer on top...

  15. Composition and properties of thallium mercury iodide

    Science.gov (United States)

    Kennedy, John H.; Schaupp, Christopher; Yang, Yuan; Zhang, Zhengming; Novinson, Thomas; Hoffard, Theresa

    1990-10-01

    Conflicting reports exist in the literature concerning the composition of thallium mercury iodide. Solid state synthesis with HgI 2 and TlI has been reported to give Tl 4HgI 6 while synthesis from solution has been reported to give Tl 2HgI 4. In this report we show that the "orange compound" precipitating from solution is actually a 1:1 mole ratio mixture of Tl 4HgI 6 and HgI 2. Pure Tl 4HgI 6, which is yellow, can be produced by heating the mixture at 100°C for several days to volatilize HgI 2 or more simply, by adding Tl(I) to a solution containing 2:1 KI:K 2HgI 4 to provide the additional iodide ions needed for Tl 4HgI 6. Tl 4HgI 6, unlike Ag 2HgI 4 and Cu 2HgI 4, has no sharp thermochromic changes and has no measurable ionic conductivity. This provides another example of the significant role the metal ion plans in determining structure and properties of metal mercury iodide compounds.

  16. Formation of cyanogen iodide by lactoperoxidase.

    Science.gov (United States)

    Schlorke, Denise; Flemmig, Jörg; Birkemeyer, Claudia; Arnhold, Jürgen

    2016-01-01

    The haem protein lactoperoxidase (LPO) is an important component of the anti-microbial immune defence in external secretions and is also applied as preservative in food, oral care and cosmetic products. Upon oxidation of SCN(-) and I(-) by the LPO-hydrogen peroxide system, oxidised species are formed with bacteriostatic and/or bactericidal activity. Here we describe the formation of the inter(pseudo)halogen cyanogen iodide (ICN) by LPO. This product is formed when both, thiocyanate and iodide, are present together in the reaction mixture. Using (13)C nuclear magnetic resonance spectroscopy and gas chromatography-mass spectrometry we could identify this inter(pseudo)halogen after applying iodide in slight excess over thiocyanate. The formation of ICN is based on the reaction of oxidised iodine species with thiocyanate. Further, we could demonstrate that ICN is also formed by the related haem enzyme myeloperoxidase and, in lower amounts, in the enzyme-free system. As I(-) is not competitive for SCN(-) under physiologically relevant conditions, the formation of ICN is not expected in secretions but may be relevant for LPO-containing products.

  17. Transition probabilities for argon I

    International Nuclear Information System (INIS)

    Transition probabilities for ArI lines have been calculated on the basis of the (j,k)-coupling scheme for more than 16000 spectral lines belonging to the transition arrays 4s-np (n=4 to n=9), 5s-np (n=5 to n=9), 6s-np (n=6 to n=9), 7s-np (n=8 to n=9), 4p-ns (n=5 to n=10), 5p-ns (n=6 to n=9), 6p-ns (n=7 to n=8), 4p-nd (n=3 to n=9), 5p-nd (n=4 to n=9), 3d-np (n=5 to n=9), 4d-np (n=6 to n=9), 5d-np (n=7 to n=9), 3d-nf (n=4 to n=9), 4d-nf (n=4 to n=9), 5d-nf (n=5 to n=9), 4f-nd (n=5 to n=9) 5f-nd (n=6 to n=9), 4f-ng (n=5 to n=9), 5f-ng (n=6 to n=9). Inso far as values by other authors exist, comparison is made with these values. It turns out that the results obtained in (j,k)-coupling are close to those obtained in intermediate coupling except for intercombination lines. For high principal and/or orbital quantum numbers the transition probabilities for a multiplet approach those of the corresponding transitions in atomic hydrogen. The calculated values are applied to construct a simplified argon-atom model, which reflects the real transition properties and which allows simplified but realistic non-equilibrium calculations for argon plasmas which deviate from local thermodynamic equilibrium (LTE)

  18. Effect of nitrogen and oxygen on radiolysis of iodide solution

    Energy Technology Data Exchange (ETDEWEB)

    Karasawa, H.; Endo, M. [Hitachi Ltd., Power and Industrial System R+D Divisions, Ibaraki (Japan)

    1996-12-01

    The effect of nitrogen and oxygen on radiolysis of iodide solution was examined. Direct decomposition of nitrogen by {gamma}-radiation produced nitric acid to decrease a water pH. This resulted in the iodine formation in the radiolysis of iodide solution. Hydrogen peroxide was produced by the radiolysis of water containing oxygen. This worked a reducing agent to suppress the formation of iodine in the radiolysis of iodide solution. In the analytical model, fourteen iodine species were considered and reaction scheme consisted in 124 reactions. The analytical model could estimate the oxidation state of iodide ions. (author) 4 figs., 4 refs.

  19. Mercuric Iodide Anticoincidence Shield for Gamma-Ray Spectrometer Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We utilize a new detector material, polycrystalline mercuric iodide, for background suppression by active anticoincidence shielding in gamma-ray spectrometers. Two...

  20. Mercuric Iodide Anticoincidence Shield for Gamma-Ray Spectrometer Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to utilize a new detector material, polycrystalline mercuric iodide, for background suppression by active anticoincidence shielding in gamma-ray...

  1. Europium-doped barium bromide iodide

    Energy Technology Data Exchange (ETDEWEB)

    Gundiah, Gautam; Hanrahan, Stephen M.; Hollander, Fredrick J.; Bourret-Courchesne, Edith D.

    2009-10-21

    Single crystals of Ba0.96Eu0.04BrI (barium europium bromide iodide) were grown by the Bridgman technique. The title compound adopts the ordered PbCl2 structure [Braekken (1932). Z. Kristallogr. 83, 222-282]. All atoms occupy the fourfold special positions (4c, site symmetry m) of the space group Pnma with a statistical distribution of Ba and Eu. They lie on the mirror planes, perpendicular to the b axis at y = +-0.25. Each cation is coordinated by nine anions in a tricapped trigonal prismatic arrangement.

  2. Novel mercuric iodide polycrystalline nuclear particles counters

    Energy Technology Data Exchange (ETDEWEB)

    Schieber, M. [Hebrew Univ. of Jerusalem (Israel)]|[Sandia National Lab., Livermore, CA (United States); Zuck, A.; Braiman, M.; Nissenbaum, J. [Hebrew Univ. of Jerusalem (Israel)] [and others

    1996-12-31

    Polycrystalline mercuric iodide nuclear radiation detectors having areas between 0.01 to 100 cm{sup 2} and thicknesses 30 to 600 microns, have been fabricated with single, linear strip and square pixel contact. The large area detectors 10 to 600 cm{sup 2} were produced by industrial ceramic equipment while the smaller ones, about 1 cm{sup 2} area, were produced in the laboratory. The large detectors still had large leakage currents and the production process is being revised. The smaller detectors were tested and their response to lower and higher gamma energy, beta and even 100 GeV muons at CERN will be reported.

  3. Large-area mercuric iodide photodetectors

    International Nuclear Information System (INIS)

    This article discusses the limits of the active area of mercuric iodide photodetectors imposed by the size of available crystals, electronic noise, and the uniformity of charge carrier collection. Theoretical calculations of the photodetector electronic noise are compared with the experimental results. Different entrance contacts were studied including semitransparent palladium films and conductive liquids. HgI2 photodetectors with active area up to 4 sq cm are matched with NaI(Tl) and CsI(Tl) scintillation crystals and are evaluated as gamma radiation spectrometers

  4. Transfer of the human sodium/iodide symporter gene enhances iodide uptake in melanoma cells

    International Nuclear Information System (INIS)

    Objective: To obtain human sodium/iodide symporter (hNIS) cDNA and to study its biological property and potential use as a therapeutic radioiodide for melanoma. Methods: hNIS gene cDNA was amplified with total RNA from human thyroid tissue by RT-PCR. The hNIS cDNA was inserted into cloning vector pUCm-T and subcloned into eukaryotic expression vector pcDNA3. The recombinant plasmid pcDNA3-hNIS was introduced into B16 cells using the electroporation technique. The uptake and efflux of iodide was examined in vitro. Results: The cloned hNIS cDNA sequence was identical to the published sequence. Two novel cell lines named B16-A containing hNIS and B16-B containing pcDNA3 only were established. The resultant cell line B16-A accumulated 17 and 19 times more radioiodide in vitro than B16 and B16-B did, respectively. However the efflux of iodide from B16-A was also rapid ( T1/2=10 min). Conclusions: Our preliminary data indicate that the transduction of the hNIS gene per se is sufficient to induce iodide transport in melanoma cells in vitro, but its T1/2 is short. With regard to therapeutic application, however, further investigation is necessary so as to develop a method of maintaining more radioiodide in the cells for long enough to produce greater therapeutic effects

  5. Production of Molecular Iodine and Tri-iodide in the Frozen Solution of Iodide: Implication for Polar Atmosphere.

    Science.gov (United States)

    Kim, Kitae; Yabushita, Akihiro; Okumura, Masanori; Saiz-Lopez, Alfonso; Cuevas, Carlos A; Blaszczak-Boxe, Christopher S; Min, Dae Wi; Yoon, Ho-Il; Choi, Wonyong

    2016-02-01

    The chemistry of reactive halogens in the polar atmosphere plays important roles in ozone and mercury depletion events, oxidizing capacity, and dimethylsulfide oxidation to form cloud-condensation nuclei. Among halogen species, the sources and emission mechanisms of inorganic iodine compounds in the polar boundary layer remain unknown. Here, we demonstrate that the production of tri-iodide (I3(-)) via iodide oxidation, which is negligible in aqueous solution, is significantly accelerated in frozen solution, both in the presence and the absence of solar irradiation. Field experiments carried out in the Antarctic region (King George Island, 62°13'S, 58°47'W) also showed that the generation of tri-iodide via solar photo-oxidation was enhanced when iodide was added to various ice media. The emission of gaseous I2 from the irradiated frozen solution of iodide to the gas phase was detected by using cavity ring-down spectroscopy, which was observed both in the frozen state at 253 K and after thawing the ice at 298 K. The accelerated (photo-)oxidation of iodide and the subsequent formation of tri-iodide and I2 in ice appear to be related with the freeze concentration of iodide and dissolved O2 trapped in the ice crystal grain boundaries. We propose that an accelerated abiotic transformation of iodide to gaseous I2 in ice media provides a previously unrecognized formation pathway of active iodine species in the polar atmosphere.

  6. Phase 2 Methyl Iodide Deep-Bed Adsorption Tests

    Energy Technology Data Exchange (ETDEWEB)

    Soelberg, Nick [Idaho National Lab. (INL), Idaho Falls, ID (United States); Watson, Tony [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2014-09-01

    Nuclear fission produces fission products (FPs) and activation products, including iodine-129, which could evolve into used fuel reprocessing facility off-gas systems, and could require off-gas control to limit air emissions to levels within acceptable emission limits. Research, demonstrations, and some reprocessing plant experience have indicated that diatomic iodine can be captured with efficiencies high enough to meet regulatory requirements. Research on the capture of organic iodides has also been performed, but to a lesser extent. Several questions remain open regarding the capture of iodine bound in organic compounds. Deep-bed methyl iodide adsorption testing has progressed according to a multi-laboratory methyl iodide adsorption test plan. This report summarizes the second phase of methyl iodide adsorption work performed according to this test plan using the deep-bed iodine adsorption test system at the Idaho National Laboratory (INL), performed during the second half of Fiscal Year (FY) 2014. Test results continue to show that methyl iodide adsorption using AgZ can achieve total iodine decontamination factors (DFs, ratios of uncontrolled and controlled total iodine levels) above 1,000, until breakthrough occurred. However, mass transfer zone depths are deeper for methyl iodide adsorption compared to diatomic iodine (I2) adsorption. Methyl iodide DFs for the Ag Aerogel test adsorption efficiencies were less than 1,000, and the methyl iodide mass transfer zone depth exceeded 8 inches. Additional deep-bed testing and analyses are recommended to (a) expand the data base for methyl iodide adsorption under various conditions specified in the methyl iodide test plan, and (b) provide more data for evaluating organic iodide reactions and reaction byproducts for different potential adsorption conditions.

  7. Dissolution of gaseous methyl iodide into aqueous sodium hydroxide solutions

    International Nuclear Information System (INIS)

    Absorption process of gaseous methyl iodide by water or sodium hydroxide solutions was investigated using a semi-flow type experimental apparatus by measuring the concentration of all measurable chemical species in both the gas and the liquid phase. The experimental temperature ranged from 288 to 311 K and the gaseous methyl iodide and aqueous sodium hydroxide concentrations were approximately 0.6 x 10-3 to 7 x 10-3 and 0 to 0.2 mol/dm3, respectively. It is estimated that the dissolution of methyl iodide into the sodium hydroxide solution proceeds according to the following steps. Step (1) Methyl iodide in air dissolves physically into the aqueous phase. Physical dissolution process obeys Henry's law. Step (2) Methyl iodide dissolved into the aqueous phase is decomposed by a base catalytic hydrolysis and produces methyl alcohol and iodide ion. The equilibrium constants of physical dissolution were obtained from the steady concentration in both the gas and the liquid phases in the semi-flow type experiment because the hydrolysis reaction rate of methyl iodide is very slow in comparison with the physical dissolution in this experimental conditions. The obtained value of the standard heat of solution of methyl iodide into water was 7.2 kcal/mol. Salting-out effect was observed when the concentration of sodium hydroxide in the absorbent was over 0.01 mol/dm3. (auth.)

  8. Opacity of Shock-Generated Argon Plasmas

    Institute of Scientific and Technical Information of China (English)

    王藩侯; 陈敬平; 周显明; 李西军; 经福谦; 孟续军; 孙永盛

    2001-01-01

    Argon plasmas with uniform density and temperature are generated by a planar shock wave through argon gas. The opacities of argon plasma, covering the thermodynamic states at temperatures of 1.4-2.2eV and in densities of 0.0083- 0.015 g/cm3, are investigated by measuring the emitted radiance versus time at several visible wavelengths. Comparison of the measured opacities with those calculated demonstrates that the average atom model can be used well to describe the essential transport behaviour of photons in argon plasma under the abovementioned thermodynamic condition. A simplified and self-consistent method to deduce the reflectivity R(λ) at the baseplate surface is applied. It demonstrates that the values of R(λ) are all around 0.4 in the experiments, which are basically in agreement with those given by Erskine previously (1994 J. Quant. Spectrosc. Radiat.Transfer 51 97).

  9. Status and perspecitves of liquid argon calorimeters

    International Nuclear Information System (INIS)

    The status of liquid argon calorimeters is reviewed, and experience obtained with these devices is described. Future perspectives of the liquid ionization chamber technique in calorimetry are also discussed. (orig.)

  10. Clinical periodontics with the argon laser

    Science.gov (United States)

    Finkbeiner, R. L.

    1995-04-01

    The argon laser has proven to be a valuable tool for the thermodynamic debridement of the periodontal lesion, incisions and tissue fusion. Illustrations of clinical applications and discussion of laser parameters will be provided.

  11. Argon plasma irradiation of polypropylene

    Energy Technology Data Exchange (ETDEWEB)

    Slepicka, P., E-mail: petr.slepicka@vscht.c [Department of Solid State Engineering, Institute of Chemical Technology, 16628 Prague (Czech Republic); Vasina, A. [Department of Solid State Engineering, Institute of Chemical Technology, 16628 Prague (Czech Republic); Kolska, Z. [J.E. Purkyne University, Department of Chemistry, 40096 Usti Nad Labem (Czech Republic); Luxbacher, T. [Anton Paar GmbH, 8054 Graz (Austria); Malinsky, P.; Mackova, A. [Nuclear Physics Institute of Academy of Sciences of the Czech Republic, 25068 Rez (Czech Republic); Svorcik, V. [Department of Solid State Engineering, Institute of Chemical Technology, 16628 Prague (Czech Republic)

    2010-06-15

    Polypropylene samples were exposed to argon plasma discharge and the changes of the PP surface properties were studied by different methods. Surface wettability was derived from contact angle measured by standard goniometry and chemical structure of the plasma modified PP was studied using X-ray photoelectron spectroscopy (XPS) and by Rutherford backscattering spectroscopy (RBS), surface morphology and roughness of samples using AFM. Zeta potential of pristine and modified PP was determined with the SurPASS. The presence of incorporated oxygen in the PP surface layer, about 60 nm thick, was observed in RBS spectra. Oxygen concentration is a decreasing function of the depth. With progressing aging time the oxygen concentration on the PP surface decreases. Plasma treatment results in a rapid decrease of the contact angle, which increases again with increasing aging time. In XPS measurement the oxygen containing structures, created by the plasma treatment, were found on the very surface of the modified PP and the zeta potential being changed too. The significant difference in zeta potential between pristine and plasma treated PP clearly indicates that the plasma treatment leads to a more hydrophilic PP surface.

  12. Negative corona current pulses in argon and in mixture argon with SF6

    International Nuclear Information System (INIS)

    Waveforms of the first negative current pulses in a short negative point-to plane gap in pure argon and argon with SF6 admixture have been investigated with a nanosecond time resolution at a gas pressure 50 kPa as a function of applied gap voltage and content of SF6 in the mixture. We have made an attempt to explain the differences in the discharge development in pure argon and in argon with admixture of SF6 based on the observed changes of the pulse shape. The experimental results obtained will be discussed in context with existing computer simulation models (Authors)

  13. Measurements on scintillation light from liquid argon

    International Nuclear Information System (INIS)

    It is shown that an argon calorimeter can operate as a scintillation detector, provided that xenon is added. With the addition of 170 ppm xenon a light yield of 70% has been obtained. In addition the light yield is determined under influence of an electric field, from differently ionising particles and by the use of aluminium mirrors acting as light guides. Finally first measurements with a photomultiplier working at liquid argon temperatures are reported. (orig.)

  14. Argon Laser Photoablation for Postburn Conjunctival Pigmentation

    Directory of Open Access Journals (Sweden)

    Seong Joon Ahn

    2014-01-01

    Full Text Available We report a case of an ocular burn injury from boiling water which resulted in conjunctival pigmentation, 1 week following injury. For cosmetic purposes, 2 sessions of argon laser photoablation were performed. One month after laser treatment, conjunctival pigmentation had been successfully removed and the patient was very satisfied with the results. Argon laser photoablation may be an effective way to remove postburn conjunctival pigmentation.

  15. Argon clusters embedded in helium nanodroplets.

    Science.gov (United States)

    da Silva, Filipe Ferreira; Bartl, Peter; Denifl, Stephan; Echt, Olof; Märk, Tilmann D; Scheier, Paul

    2009-11-14

    Electron impact ionization of argon clusters embedded in helium droplets is investigated. Superior mass resolution makes it possible to distinguish between nominally isobaric cluster ions. An abundance maximum for ArHe(12)(+) is unambiguously confirmed; the spectra also prove the formation of Ar(2)He(n)(+) complexes that had been claimed to fragment into pure Ar(2)(+). Distributions of larger argon cluster ions containing up to 60 atoms closely resemble distributions observed upon electron impact or photoionization of bare argon clusters; caging and evaporative cooling provided by the helium matrix do not suffice to quench fragmentation of the nascent argon cluster ions. Intriguing abundance anomalies are observed in distributions of argon cluster ions that contain water, nitrogen or oxygen impurities. The strong abundance of Ar(55)H(2)O(+), Ar(54)O(2)(+) and Ar(54)N(2)(+) contrasts with the virtual absence of slightly larger cluster ions containing the corresponding impurities. The features are probably related to enhanced cluster ion stability upon closure of the second icosahedral shell but the difference in magic numbers (54 versus 55) and the well-known reactivity of charged argon-nitrogen complexes suggest structural differences. PMID:19851558

  16. Potassium-argon/argon-40-argon-39 geochronology of Cenozoic alkali basalts from the South China Sea

    Institute of Scientific and Technical Information of China (English)

    YAN Quanshu; SHI Xuefa; YANG Yaomin; WANG Kunshan

    2008-01-01

    Based on the isotopic chronologic results of Cenozoic alkali basalts from the South China Sea,the characteristics of volcanic activi-ty of the South China Sea after spreading were studied.The potassium - argon ages of eight alkali basalt samples from the South China Sea,and the argon - argon ages of two samples among them are reported.Apparent ages of the whole rock are 3.80 to 7.91 Ma with an average value of 5.43 Ma (potassium- argon,whole rock),and there is little difference among samples at the same location,e.g.,4.76~5.78 Ma for location S04-12.The argon - argon ages for the two samples are 6.06 and 4.71 Ma,which lie within the age scope of potassium - argon method.The dating results indicate that rock-forming age is from late Miocene to Pli-ocene,which is consistent with erupting event for alkali basalts from adjacent regions of the South China Sea.Volcanic activities occur after the cessation of spreading of the South China Sea,which are controlled by lithospheric fault and the spreading center formed during the spreading period of the South China Sea.These dating results,combined with geochemical characteristics of these basalts,the published chronological data for the South China Sea and its adjacent regions,and the updated geophysical data near Hainan Island,suggest that after the cessation of spreading of the South China Sea,there occur widely distributing magmatic activities which primarily is alkali basalt,and the volcanic activity continues to Quaternary.The activity may be relative to Hainan mantle plume originated from core/mantle boundary.

  17. Novel mercuric iodide polycrystalline nuclear particle counters

    Energy Technology Data Exchange (ETDEWEB)

    Schieber, M. [Hebrew Univ. of Jerusalem (Israel)]|[Sandia National Labs., Livermore, CA (United States); Zuck, A.; Braiman, M.; Nissenbaum, J. [Hebrew Univ. of Jerusalem (Israel); Turchetta, R.; Dulinski, W.; Husson, D.; Riester, J.L. [LEPSI, Strasbourg (France)

    1997-12-01

    Polycrystalline mercuric iodide nuclear radiation detectors have been produced in a novel technology. Unlike the normal single-crystal technology, there is no intrinsic limit to the surface on which these detectors can be produced. Detectors with areas up to about 1.5 cm{sup 2}, thicknesses from 30 to 600 {micro}m, and with single electrodes as well as microstrip and pixel contacts have been fabricated and successfully tested with photons in the range of 40--660 keV, {beta} particle`s emitted from a Sr-Y source, and high energy (100 GeV) muons. Results on both charge collection and counting efficiency are reported as well as some very preliminary imaging results. The experimental results on charge collection have been compared with simulation, and a combined {mu}{tau} product 10{sup {minus}7} cm{sup 2}/V for electrons has been estimated.

  18. Ferroelastic Fingerprints in Methylammonium Lead Iodide Perovskite

    KAUST Repository

    Hermes, Ilka M.

    2016-02-12

    Methylammonium lead iodide (MAPbI3) perovskite materials show an outstanding performance in photovoltaic devices. However, certain material properties, especially the possible ferroic behavior, remain unclear. We observed distinct nanoscale periodic domains in the piezoresponse of MAPbI3(Cl) grains. The structure and the orientation of these striped domains indicate ferroelasticity as their origin. By correlating vertical and lateral piezoresponse force microscopy experiments performed at different sample orientations with x-ray diffraction, the preferred domain orientation was suggested to be the a1-a2-phase. The observation of these ferroelastic fingerprints appears to strongly depend on the film texture and thus the preparation route. The formation of the ferroelastic twin domains could be induced by internal strain during the cubic-tetragonal phase transition.

  19. Conserved charged amino acid residues in the extracellular region of sodium/iodide symporter are critical for iodide transport activity

    Directory of Open Access Journals (Sweden)

    Liang Ji-An

    2010-11-01

    Full Text Available Abstract Background Sodium/iodide symporter (NIS mediates the active transport and accumulation of iodide from the blood into the thyroid gland. His-226 located in the extracellular region of NIS has been demonstrated to be critical for iodide transport in our previous study. The conserved charged amino acid residues in the extracellular region of NIS were therefore characterized in this study. Methods Fourteen charged residues (Arg-9, Glu-79, Arg-82, Lys-86, Asp-163, His-226, Arg-228, Asp-233, Asp-237, Arg-239, Arg-241, Asp-311, Asp-322, and Asp-331 were replaced by alanine. Iodide uptake abilities of mutants were evaluated by steady-state and kinetic analysis. The three-dimensional comparative protein structure of NIS was further modeled using sodium/glucose transporter as the reference protein. Results All the NIS mutants were expressed normally in the cells and targeted correctly to the plasma membrane. However, these mutants, except R9A, displayed severe defects on the iodide uptake. Further kinetic analysis revealed that mutations at conserved positively charged amino acid residues in the extracellular region of NIS led to decrease NIS-mediated iodide uptake activity by reducing the maximal rate of iodide transport, while mutations at conserved negatively charged residues led to decrease iodide transport by increasing dissociation between NIS mutants and iodide. Conclusions This is the first report characterizing thoroughly the functional significance of conserved charged amino acid residues in the extracellular region of NIS. Our data suggested that conserved charged amino acid residues, except Arg-9, in the extracellular region of NIS were critical for iodide transport.

  20. Argon Collection And Purification For Proliferation Detection

    Energy Technology Data Exchange (ETDEWEB)

    Achey, R. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Hunter, D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-10-09

    In order to determine whether a seismic event was a declared/undeclared underground nuclear weapon test, environmental samples must be taken and analyzed for signatures that are unique to a nuclear explosion. These signatures are either particles or gases. Particle samples are routinely taken and analyzed under the Comprehensive Nuclear-Test-Ban Treaty Organization (CTBTO) verification regime as well as by individual countries. Gas samples are analyzed for signature gases, especially radioactive xenon. Underground nuclear tests also produce radioactive argon, but that signature is not well monitored. A radioactive argon signature, along with other signatures, can more conclusively determine whether an event was a nuclear test. This project has developed capabilities for collecting and purifying argon samples for ultra-low-background proportional counting. SRNL has developed a continuous gas enrichment system that produces an output stream containing 97% argon from whole air using adsorbent separation technology (the flow diagram for the system is shown in the figure). The vacuum swing adsorption (VSA) enrichment system is easily scalable to produce ten liters or more of 97% argon within twelve hours. A gas chromatographic separation using a column of modified hydrogen mordenite molecular sieve has been developed that can further purify the sample to better than 99% purity after separation from the helium carrier gas. The combination of these concentration and purification systems has the capability of being used for a field-deployable system for collecting argon samples suitable for ultra-low-background proportional counting for detecting nuclear detonations under the On-Site Inspection program of the CTBTO verification regime. The technology also has applications for the bulk argon separation from air for industrial purposes such as the semi-conductor industry.

  1. Attenuation of vacuum ultraviolet light in liquid argon

    CERN Document Server

    Neumeier, A; Oberauer, L; Potzel, W; Schönert, S; Dandl, T; Heindl, T; Ulrich, A; Wieser, J

    2015-01-01

    The transmission of liquid argon has been measured, wavelength resolved, for a wavelength interval from 118 to 250 nm. The wavelength dependent attenuation length is presented for pure argon. It is shown that no universal wavelength independent attenuation length can be assigned to liquid argon for its own fluorescence light due to the interplay between the wavelength dependent emission and absorption. A decreasing transmission is observed below 130 nm in both chemically cleaned and distilled liquid argon and assigned to absorption by the analogue of the first argon excimer continuum. For not perfectly cleaned argon a strong influence of impurities on the transmission is observed. Two strong absorption bands at 126.5 and 141.0 nm with approximately 2 and 4 nm width, respectively, are assigned to traces of xenon in argon. A broad absorption region below 180 nm is found for unpurified argon and tentatively attributed to the presence of water in the argon sample.

  2. The Effect on Sodium/Iodide Symporter and Pendrin in Thyroid Colloid Retention Developed by Excess Iodide Intake.

    Science.gov (United States)

    Chen, Xiao-Yi; Lin, Chu-Hui; Yang, Li-Hua; Li, Wang-Gen; Zhang, Jin-Wei; Zheng, Wen-Wei; Wang, Xiang; Qian, Jiang; Huang, Jia-Luan; Lei, Yi-Xiong

    2016-07-01

    It is well known that excess iodide can lead to thyroid colloid retention, a classic characteristic of iodide-induced goiter. However, the mechanism has not been fully unrevealed. Iodide plays an important role in thyroid function at multiple steps of thyroid colloid synthesis and transport among which sodium/iodide symporter (NIS) and pendrin are essential. In our study, we fed female BALB/c mice with different concentrations of high-iodine water including group A (control group, 0 μg/L), group B (1500 μg/L), group C (3000 μg/L), group D (6000 μg/L), and group E (12,000 μg/L). After 7 months of feeding, we found that excess iodide could lead to different degrees of thyroid colloid retention. Besides, NIS and pendrin expression were downregulated in the highest dose group. The thyroid iodide intake function detected by urine iodine assay and thyroidal (125)I experiments showed that the urine level of iodine increased, while the iodine intake rate decreased when the concentration of iodide used in feeding water increased (all p control group). In addition, transmission electron microscopy (TEM) indicated a reduction in the number of intracellular mitochondria of thyroid cells. Based on these findings, we concluded that the occurrence of thyroid colloid retention exacerbated by excess iodide was associated with the suppression of NIS and pendrin expression, providing an additional insight of the potential mechanism of action of excess iodide on thyroid gland. PMID:26660892

  3. Expression of the human sodium/iodide symporter (hNIS) in xenotransplanted human thyroid carcinoma

    NARCIS (Netherlands)

    Smit, J.W.A.; Schröder - van der Elst, J.P.; Karperien, M.; Que, I.; Romijn, J.A.; Heide, van der D.

    2001-01-01

    The uptake of iodide in thyroid epithelial cells is mediated by the sodium/iodide symporter (NIS). The uptake of iodide is of vital importance for thyroid physiology and is a prerequisite for radioiodine therapy in thyroid cancer. Loss of iodide uptake due to diminished expression of the human NIS (

  4. Improved Stability of Mercuric Iodide Detectors for Anticoincidence Shields Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to utilize guard ring electrode structures and a new film growth technique to create improved polycrystalline mercuric iodide detectors for background...

  5. Prevention of organic iodide formation in BWR`s

    Energy Technology Data Exchange (ETDEWEB)

    Karjunen, T. [Finnish Centre for Radiation and Nuclear Safety, Helsinki (Finland); Laitinen, T.; Piippo, J.; Sirkiae, P. [VTT Manufacturing Technology (Finland)

    1996-12-01

    During an accident, many different forms of iodine may emerge. Organic iodides, such as methyl iodide and ethyl iodide, are relatively volatile, and thus their appearance leads to increased concentration of gaseous iodine. Since organic iodides are also relatively immune to most accident mitigation measures, such as sprays and filters, they can affect the accident source term significantly even when only a small portion of iodine is in organic form. Formation of organic iodides may not be limited by the amount of organic substances available. Excessive amounts of methane can be produced, for example, during oxidation of boron carbide, which is used in BWR`s as a neutron absorber material. Another important source is cable insulation. In a BWR, a large quantity of cables is placed below the pressure vessel. Thus a large quantity of pyrolyse gases will be produced, should the vessel fail. Organic iodides can be formed as a result of many different reactions, but at least in certain conditions the main reaction takes place between an organic radical produced by radiolysis and elemental iodine. A necessary requirement for prevention of organic iodide production is therefore that the pH in the containment water pools is kept high enough to eliminate formation of elemental iodine. In a typical BWR the suppression pool water is usually unbuffered. As a result, the pH may be dominated by chemicals introduced during an accident. If no system for adding basic chemicals is operable, the main factor affecting pool water pH may be hydrochloric acid released during cable degradation. Should this occur, the conditions could be very favorable for production of elemental iodine and, consequently, formation of organic iodides. Although high pH is necessary for iodine retention, it could have also adverse effects. High pH may, for example, accelerate corrosion of containment materials and alter the characteristics of the solid corrosion products. (author) 6 figs., 1 tab., 13 refs.

  6. A review of polytypism in lead iodide

    Energy Technology Data Exchange (ETDEWEB)

    Beckmann, P.A. [Department of Physics, Bryn Mawr College, Bryn Mawr, Pennsylvania (United States)

    2010-05-15

    Lead Iodide (PbI{sub 2}) is an important inorganic solid for both basic scientific research and possible technological applications and in this brief review we discuss the structure of PbI{sub 2}. Although the basic structure is a simple I-Pb-I layered structure with a[PbI{sub 6}]{sup 4-} near-octahedron being the basic building block, there are many ways of stacking the layers which results in many polytypes. We present 20 of the 23 entries for the structure of PbI{sub 2} from the Inorganic Structural Database and order them by polytype. This represents more than 80 years of crystallographic research in the structure of this compound. We present a simple way to view the 2H, 4H, 6H, and 6R polytypes and extend the procedure to higher-order polytypes. We note a relationship, not generally appreciated, between the distortion of the near [PbI{sub 6}]{sup 4-} octahedrons and the polytype. We suggest that the significance of vacancies has only recently been appreciated. We suggest that small discrepancies in structure determination are probably due to different distributions of vacancies and that there are, in practice, very many structures for macroscopic or even mesoscopic samples of a given polytype when vacancies are considered. (copyright 2010 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  7. Chloride, bromide and iodide scintillators with europium

    Energy Technology Data Exchange (ETDEWEB)

    Zhuravleva, Mariya; Yang, Kan

    2016-09-27

    A halide scintillator material is disclosed where the halide may comprise chloride, bromide or iodide. The material is single-crystalline and has a composition of the general formula ABX.sub.3 where A is an alkali, B is an alkali earth and X is a halide which general composition was investigated. In particular, crystals of the formula ACa.sub.1-yEu.sub.yI.sub.3 where A=K, Rb and Cs were formed as well as crystals of the formula CsA.sub.1-yEu.sub.yX.sub.3 (where A=Ca, Sr, Ba, or a combination thereof and X=Cl, Br or I or a combination thereof) with divalent Europium doping where 0.ltoreq.y.ltoreq.1, and more particularly Eu doping has been studied at one to ten mol %. The disclosed scintillator materials are suitable for making scintillation detectors used in applications such as medical imaging and homeland security.

  8. Scintillation efficiency of liquid argon in low energy neutron-argon scattering

    International Nuclear Information System (INIS)

    Experiments searching for weak interacting massive particles with noble gases such as liquid argon require very low detection thresholds for nuclear recoils. A determination of the scintillation efficiency is crucial to quantify the response of the detector at low energy. We report the results obtained with a small liquid argon cell using a monoenergetic neutron beam produced by a deuterium-deuterium fusion source. The light yield relative to electrons was measured for six argon recoil energies between 11 and 120 keV at zero electric drift field

  9. Scintillation efficiency of liquid argon in low energy neutron-argon scattering

    CERN Document Server

    Creus, W; Amsler, C; Ferella, A D; Rochet, J; Scotto-Lavina, L; Walter, M

    2015-01-01

    Experiments searching for weak interacting massive particles with noble gases such as liquid argon require very low detection thresholds for nuclear recoils. A determination of the scintillation efficiency is crucial to quantify the response of the detector at low energy. We report the results obtained with a small liquid argon cell using a monoenergetic neutron beam produced by a deuterium-deuterium fusion source. The light yield relative to electrons was measured for six argon recoil energies between 11 and 120 keV at zero electric drift field.

  10. Contraction ionization waves in the argon contracted discharge

    International Nuclear Information System (INIS)

    An investigation of ionization waves in the argon contracted discharge and a definition of their arising propagation mechanism accounting for the specificity of elementary pocesses characteristic of argon are presented. (author)

  11. Thermal decomposition of barium valerate in argon

    DEFF Research Database (Denmark)

    Torres, P.; Norby, Poul; Grivel, Jean-Claude

    2015-01-01

    The thermal decomposition of barium valerate (Ba(C4H9CO2)(2)/Ba-pentanoate) was studied in argon by means of thermogravimetry, differential thermal analysis, IR-spectroscopy, X-ray diffraction and hot-stage optical microscopy. Melting takes place in two different steps, at 200 degrees C and 280...

  12. Antiapoptotic activity of argon and xenon.

    Science.gov (United States)

    Spaggiari, Sabrina; Kepp, Oliver; Rello-Varona, Santiago; Chaba, Kariman; Adjemian, Sandy; Pype, Jan; Galluzzi, Lorenzo; Lemaire, Marc; Kroemer, Guido

    2013-08-15

    Although chemically non-reactive, inert noble gases may influence multiple physiological and pathological processes via hitherto uncharacterized physical effects. Here we report a cell-based detection system for assessing the effects of pre-defined gas mixtures on the induction of apoptotic cell death. In this setting, the conventional atmosphere for cell culture was substituted with gas combinations, including the same amount of oxygen (20%) and carbon dioxide (5%) but 75% helium, neon, argon, krypton, or xenon instead of nitrogen. The replacement of nitrogen with noble gases per se had no effects on the viability of cultured human osteosarcoma cells in vitro. Conversely, argon and xenon (but not helium, neon, and krypton) significantly limited cell loss induced by the broad-spectrum tyrosine kinase inhibitor staurosporine, the DNA-damaging agent mitoxantrone and several mitochondrial toxins. Such cytoprotective effects were coupled to the maintenance of mitochondrial integrity, as demonstrated by means of a mitochondrial transmembrane potential-sensitive dye and by assessing the release of cytochrome c into the cytosol. In line with this notion, argon and xenon inhibited the apoptotic activation of caspase-3, as determined by immunofluorescence microscopy coupled to automated image analysis. The antiapoptotic activity of argon and xenon may explain their clinically relevant cytoprotective effects. PMID:23907115

  13. Keeping argon under a graphene lid-Argon intercalation between graphene and nickel(111)

    Science.gov (United States)

    Späth, Florian; Gotterbarm, Karin; Amende, Max; Bauer, Udo; Gleichweit, Christoph; Höfert, Oliver; Steinrück, Hans-Peter; Papp, Christian

    2016-01-01

    We report on the intercalation of graphene grown on a Ni(111) crystal with argon. Argon is implanted in the Ni(111) crystal by ion bombardment before graphene growth, and diffuses to the surface during the growth of graphene at elevated temperatures. Graphene acts as an atomically thin barrier and keeps the argon underneath. We investigated this system with high resolution X-ray photoelectron spectroscopy. From our experiments we determined the mean quantities of argon under graphene. From our analysis, a simple model to determine the pressure under the graphene layer is presented. In our measurements, we find an increased thermal stability of the intercalated graphene as compared to non-intercalated graphene on Ni(111).

  14. Iodide kinetics and experimental I-131 therapy in a xenotransplanted human sodium-iodide symporter-transfected human follicular thyroid carcinoma cell line

    NARCIS (Netherlands)

    Smit, J.W.A.; Elst, van der J.P.; Karperien, M.; Que, I.; Stokkel, M.; Heide, van der D.; Romijn, J.A.

    2002-01-01

    Uptake of iodide is a prerequisite for radioiodide therapy in thyroid cancer. However, loss of iodide uptake is frequently observed in metastasized thyroid cancer, which may be explained by diminished expression of the human sodium-iodide symporter (hNIS). We studied whether transfection of hNIS int

  15. Evaluation of mercuric iodide ceramic semiconductor detectors

    Energy Technology Data Exchange (ETDEWEB)

    Schieber, M.; Zuck, A.; Braiman, M.; Nissenbaum, J. [Hebrew Univ., Jerusalem (Israel); Turchetta, R.; Dulinski, W.; Husson, D.; Riester, J.L. [LEPSI (ULP/IN2P3), Strasbourg (France)

    1998-02-01

    Mercuric iodide ceramic radiation detectors, which can act as nuclear particle counters, have been fabricated with single continuos electrical contacts and with linear strip contacts. They have been tested with different kinds of {gamma} and {beta} sources as well as in a high energy beam at CERN. The detectors were also successfully tested for radiation hardness with irradiation of 5*10{sup 14} neutrons/cm{sup 2}. The ratio of detected photons over the number of absorbed photons has been measured with {gamma} sources of different energies, and it ranges from 20% at 44 keV up to about 30% at 660 keV. An absolute efficiency of 70% has been measured for a 350 {mu}m thick detector for {beta} particles emitted by a {sup 90}Sr source. Charge collection efficiency, defined as the amount of charge induced on the electrodes by a mminimum ionizing particle (MIP) traversing the detector, has been measured in two samples. The average collected charge fits well with a linear curve with slope of 35 electrons/(kV/cm) per 100 {mu}m. This result is well described by a dynamic device simulation, where the free carrier mean lifetime is used as a free parameter, adjusted to a value of 1.5 ns, i.e. about 1/100 of the corresponding lifetime in single crystal HgI{sub 2} detectors. The response to MIP has also been studied with a high energy (100 GeV) muon beam in CERN. A preliminary beam profile is presented while a more detailed analysis is still in progress and will be presented elsewhere. These results together with the low cost of the material make ceramic HgI{sub 2} detectors excellent candidates for large area particle tracking and imaging applications, even in a radiation harsh environment. (orig.). 14 refs.

  16. Argon Laser Treatment of Strawberry Hemangioma in Infancy

    OpenAIRE

    Achauer, Bruce M.; Vander Kam, Victoria M.

    1985-01-01

    Argon laser therapy is effective for removing port-wine stains and for reducing cutaneous vascular and pigmented lesions. Strawberry hemangiomas, being much thicker lesions than port-wine stains, were considered not appropriate for argon laser treatment. Using argon laser therapy in 13 cases of strawberry hemangioma, we achieved poor to dramatic results.

  17. Argon laser treatment of strawberry hemangioma in infancy.

    Science.gov (United States)

    Achauer, B M; Vander Kam, V M

    1985-11-01

    Argon laser therapy is effective for removing port-wine stains and for reducing cutaneous vascular and pigmented lesions. Strawberry hemangiomas, being much thicker lesions than port-wine stains, were considered not appropriate for argon laser treatment. Using argon laser therapy in 13 cases of strawberry hemangioma, we achieved poor to dramatic results. PMID:4082569

  18. Methyl Iodide Formation Under Postulated Nuclear Reactor Accident Conditions

    International Nuclear Information System (INIS)

    The formation of methyl iodide under conditions of postulated nuclear reactor accidents is discussed. Although thermodynamic calculations indicate the equilibrium methyl iodide concentrations would be quite low, calculations based on a simple kinetic scheme involving reaction between small hydrocarbon species and iodine indicate that concentrations higher than equilibrium can occur during the course of the reaction. Such calculations were performed over a wide range of initial species concentrations and a range of temperatures representative of some reactor accident situations. These calculations suggest that little methyl iodide would be expected within the core volume where temperatures are maximum. As the gas leaves the core volume and expands into the plenum region, it cools and the concentration of methyl iodide increases. At the intermediate temperatures which might characterize this region, the formation of methyl iodide from thermally induced reactions could reach its maximum rate. The gas continues to cool, however, and it is probable that by the time it leaves the plenum region it has cooled to the point where thermally induced reactions may be of little importance. Although the thermally induced reactions will become slower as the gas expands and cools, the radiation-induced reactions will not be slowed to the same extent. The gases leaving the core carry fission products and hence a radiation source is available to initiate reaction by a temperature-independent process. An investigation of the radiation chemical formation and decomposition of methyl iodide in the presence of steam suggests that radiation-induced methyl iodide formation will generally be rapid under the postulated accident situations. Thus, in the plenum region where thermal reactions have become slow, the radiation-induced reaction can still proceed and may well become the dominant factor. The same situation probably pertains as well to the containment region. (author)

  19. Bismuth tri-iodide radiation detector development

    Science.gov (United States)

    Gokhale, Sasmit S.

    Bismuth tri-iodide is an attractive material for room temperature radiation detection. BiI3 demonstrates a number of properties that are apt for semiconductor radiation detection, especially gamma ray spectroscopy. The high atomic number (ZBi = 83 and ZI = 53) and the relatively high density (5.78 g/cm3) cause the material to have good photon stopping power, while the large band-gap (1.67 eV ) allows it to function as a room temperature radiation detector without any cooling mechanism. This work presents the fabrication and characterization of BiI3 radiation detectors. For the purpose of this research detectors were fabricated by cutting BiI3 crystal boules, followed by mechanical and chemical surface treatments. Detectors with various electrode geometries enabling single polarity charge sensing were fabricated. The electrical characteristics and the radiation response of the detectors were measured. The radiation response measurement was performed at room temperature using a 241Am alpha particle source and a 241Am sealed gamma-ray source. The spectral resolutions of the detectors varied from 2.09% - 6.1% for 59.5 keV gamma-rays and between 26% - 40% for 5.48 MeV alpha particles. Charge carrier properties such as the electron and hole mobility and lifetime were also estimated. The electron mobility for an ultrapure BiI 3 detector was estimated to be approximately 433 cm 2/Vs while that for antimony doped BiI3 was estimated to be around 956 cm2/Vs and the mobility-lifetime product for electrons was estimated to be around 5.44 x 10-4 cm 2/V. Detector simulation was performed using the Monte Carlo simulation code MCNP5. A Matlab script which incorporates charge carrier trapping and statistical variation was written to generate a gamma-ray spectrum from the simulated energy deposition spectra. Measured and simulated spectra were compared to extract the charge carrier mobility-lifetime products, which for electrons and holes were estimated to be 5 x 10-3 cm2/V and 1.3 x

  20. Macrosegregation during Plane Front Solidification of Cesium Iodide wt Percent Thallium Iodide Alloy

    Science.gov (United States)

    Sidawi, Ibrahim M. S.

    Macrosegregation produced during directional solidification of CsI-1 wt% TlI by vertical Bridgman technique has been examined in crucibles of varying diameter, from 0.5 to 2.0 cm. Phase diagram and temperature dependence of the thermal conductivity have been determined. The experimentally observed liquid-solid interface shape and the fluid flow behavior have been compared with that computed from the commercially available code FIDAP. Thallium iodide content of the alloy was observed to increase along the length of the directionally solidified specimens, resulting in continuously decreasing light output. The experimentally observed solutal distribution agrees with predictions from the boundary layer model of Favier. The observed macrosegregation behavior suggests that there is a significant convection in the melt even in the smallest crucible diameter of 0.5 cm.

  1. Phase 1 Methyl Iodide Deep-Bed Adsorption Tests

    Energy Technology Data Exchange (ETDEWEB)

    Nick Soelberg; Tony Watson

    2014-08-01

    Nuclear fission results in the production of fission products (FPs) and activation products including iodine-129, which could evolve into used fuel reprocessing facility off-gas systems, and could require off-gas control to limit air emissions to levels within acceptable emission limits. Research, demonstrations, and some reprocessing plant experience have indicated that diatomic iodine can be captured with efficiencies high enough to meet regulatory requirements. Research on the capture of organic iodides has also been performed, but to a lesser extent [Jubin 2012b]. Several questions remain open regarding the capture of iodine bound in organic compounds. Deep-bed methyl iodide adsorption testing has progressed according to a multi-laboratory methyl iodide adsorption test plan. This report summarizes the first phase of methyl iodide adsorption work performed according to this test plan using the deep-bed iodine adsorption test system at the Idaho National Laboratory (INL), performed during Fiscal Year (FY) 2013 and early FY-2014. Testing has been performed to address questions posed in the test plan, and followed the testing outline in the test plan. Tests established detection limits, developed procedures for sample analysis with minimal analytical interferences, and confirmed earlier results that show that the methyl iodide reacts when in contact with the AgZ sorbent, and not significantly in the gas flow upstream of the sorbent. The reaction(s) enable separation of the iodine from the organic moiety, so that the iodine can chemisorb onto the sorbent. The organic moiety can form other compounds, some of which are organic compounds that are detected and can be tentatively identified using GC-FID and GCMS. Test results also show that other gas constituents (NOx and/or H2O) can affect the methyl iodide reactions. With NOx and H2O present in the gas stream, the majority of uncaptured iodine exiting iodine-laden sorbent beds is in the form of I2 or HI, species that

  2. Standard free energy of formation of iron iodide

    Science.gov (United States)

    Khandkar, A.; Tare, V. B.; Wagner, J. B., Jr.

    1983-01-01

    An experiment is reported where silver iodide is used to determine the standard free energy of formation of iron iodide. By using silver iodide as a solid electrolyte, a galvanic cell, Ag/AgI/Fe-FeI2, is formulated. The standard free energy of formation of AgI is known, and hence it is possible to estimate the standard free energy of formation of FeI2 by measuring the open-circuit emf of the above cell as a function of temperature. The free standard energy of formation of FeI2 determined by this method is -38784 + 24.165T cal/mol. It is estimated that the maximum error associated with this method is plus or minus 2500 cal/mol.

  3. Flow Parameters of Argon plasma Discharge

    International Nuclear Information System (INIS)

    Owing to the viscosity, the plasma will be adhering to the inner surface of the outer electrode and outer surface of the inner one. As result that the discharge will be eroding the walls of coaxial system. The thickness of the boundary layer near the walls has been estimated at different positions from the breech of coaxial plasma gun. It is found that the thickness of layer 0.008 cm at the end of inner electrode (17 cm). A coaxial plasma gun device is operated in argon gas at ambient pressure 0.6 Torr and discharge voltage about 10 KV. The electron temperature of argon discharge has been determined by using spectroscopic technique. It is found that kTe=3.4 eV. By knowing the thickness of the boundary layer, the density can be determined. The Reynolds number R=105 and Mach number M=5 i.e. the flow is compressible and hypersonic

  4. Argon laser irradiation of the otolithic organ

    Energy Technology Data Exchange (ETDEWEB)

    Okuno, T.; Nomura, Y.; Young, Y.H.; Hara, M. (Univ. of Tokyo (Japan))

    1990-12-01

    An argon laser was used to irradiate the otolithic organs of guinea pigs and cynomolgus monkeys. After stapedectomy, the argon laser (1.5 W x 0.5 sec/shot) irradiated the utricle or saccule without touching the sensory organs. The stapes was replaced over the oval window after irradiation. The animals used for acute observation were killed immediately for morphologic studies; those used for long-term observation were kept alive for 2, 4, or 10 weeks. Acute observation revealed that sensory and supporting cells were elevated from the basement membrane only in the irradiated area. No rupture of the membranous labyrinth was observed. Long-term observation revealed that the otolith of the macula utriculi had disappeared in 2-week specimens. The entire macula utricili had disappeared in 10-week specimens. No morphologic changes were observed in cochlea, semicircular canals, or membranous labyrinth. The saccule showed similar changes.

  5. Abnormal epidermal changes after argon laser treatment

    Energy Technology Data Exchange (ETDEWEB)

    Neumann, R.A.; Knobler, R.M.; Aberer, E.; Klein, W.; Kocsis, F.; Ott, E. (Univ. of Vienna (Austria))

    1991-02-01

    A 26-year-old woman with a congenital port-wine stain on the forehead was treated three times at 2-month intervals with an argon laser. Six months after the last treatment, moderate blanching and mild scaling confined to the treated area was observed. A biopsy specimen of the treated area revealed a significant decrease in ectatic vessels. However, epidermal changes similar to those of actinic keratosis with disorganized cell layers and marked cytologic abnormalities were seen. Analysis of peripheral blood lymphocytes for a defect in DNA repair was negative. Multiple, argon laser-induced photothermal effects may be responsible for the changes observed in our case and may lead to premalignant epidermal transformation.

  6. Explanation of the memory effect in argon

    Directory of Open Access Journals (Sweden)

    Marković Vidosav

    2005-01-01

    Full Text Available Memory effect - the long time variation of the electrical breakdown time delay on the relaxation time td (τ was observed in argon 24 hours after relaxation times and explained by the long-lived metastable states remaining from the preceding glow. However, the quenching processes reducing the effective lifetime of metastable states several orders of magnitude below that relevant for the time scale of observation were neglected. By applying approximate gas phase models it was found that the early afterglow kinetics up to hundreds of milliseconds is dominated by the decay of molecular argon ions Ar2+ and the approximate value of their ambipolar diffusion coefficient is determined. After that, nitrogen atoms present as impurities and recombined on the cathode surface and/or field emission determine the breakdown time delay down to the cosmic rays and natural radioactivity level.

  7. A novel peculiar mutation in the sodium/iodide symporter gene in spanish siblings with iodide transport defect.

    Science.gov (United States)

    Kosugi, Shinji; Okamoto, Hiroomi; Tamada, Aiko; Sanchez-Franco, F

    2002-08-01

    Previously, we reported two Spanish siblings with congenital hypothyroidism due to total failure of iodide transport. These were the only cases reported to date who received long-term iodide treatment over 10 yr. We examined the sodium/iodide symporter (NIS) gene of these patients. A large deletion was observed by long and accurate PCR using primers derived from introns 2 and 7 of the NIS gene. PCR-direct sequencing revealed a deletion of 6192 bases spanning from exon 3 to intron 7 and an inverted insertion of a 431-base fragment spanning from exon 5 to intron 5 of the NIS gene. The patients were homozygous for the mutation, and their mother was heterozygous. In the mutant, deletion of exons 3-7 was suggested by analysis using programs to predict exon/intron organization, resulting in an in-frame 182-amino acid deletion from Met(142) in the fourth transmembrane domain to Gln(323) in the fourth exoplasmic loop. The mutant showed no iodide uptake activity when transfected into COS-7 cells, confirming that the mutation was the direct cause of the iodide transport defect in these patients. Further, the mutant NIS protein was synthesized, but not properly expressed, on the cell surface, but was mostly accumulated in the cytoplasm, suggesting impaired targeting to the plasma membrane. PMID:12161518

  8. Anatomy of an Inversion - Argon Isotopes

    Science.gov (United States)

    Zamick, L.; Sharon, Y. Y.; Robinson, S. J. Q.

    2012-02-01

    Two different interactions give similar results for excitation energies and g factors of 2+1 states for most even-even argon isotopes except 46Ar. This is explained in terms of an inversion in J = ½+ and levels in 47K which is successfully obtained by one of the interactions but not the other. This example shows the possible dangers of nuclear astrophysics extrapolations.

  9. Enhanced Olefin Cross Metathesis Reactions: The Copper Iodide Effect

    Science.gov (United States)

    Voigtritter, Karl; Ghorai, Subir

    2011-01-01

    Copper iodide has been shown to be an effective co-catalyst for the olefin cross metathesis reaction. In particular, it has both a catalyst stabilizing effect due to iodide ion, as well as copper(I)-based phosphine-scavenging properties that apply to use of the Grubbs-2 catalyst. A variety of Michael acceptors and olefinic partners can be cross-coupled under mild conditions in refluxing diethyl ether that avoid chlorinated solvents. This effect has also been applied to chemistry in water at room temperature using the new surfactant TPGS-750-M. PMID:21528868

  10. Mercuric iodide dosimeter response to high energy electron beams

    Energy Technology Data Exchange (ETDEWEB)

    Loewinger, E.; Nissenbaum, J.; Schieber, M.M.

    1988-01-01

    Mercuric iodide solid state dosimeter response to high energy electron beams of up to 35 MeV is reported. High sensitivity of up to 1.5 V/cGy was observed with a 200 V external bias, as well as several mV/cGy, with no external bias for small volume (approx. 10 mm/sup 3/) detectors. The physical characteristics of the detector response are discussed, showing the feasibility of mercuric iodide as a reliable dosimeter for high energy electron beams.

  11. Uptake of Iodide From Water in Atlantic Halibut Larvae (Hippoglossus Hippoglossus L.)

    DEFF Research Database (Denmark)

    Moren, Mari; Sloth, Jens Jørgen; Hamre, Kristin

    2008-01-01

    relative low levels of iodide (0-22 nM) and except for samples from one site; the levels of iodide and iodate were in agreement with previously published data. The uptake of iodide from seawater was measured by incubating Atlantic halibut larvae in water with a constant level of radioactive iodide (I-125...... is whether Atlantic halibut larvae are capable of absorbing iodide from the water and if so, can the seawater sustain the iodine requirement during larval development and metamorphosis. Levels of iodide and iodate in seawater samples from four different rearing facilities were analysed. All samples contained...... concentration of iodide in the water. The highest level of iodide used was 2000 nM,100 times higher than what was measured in the seawater samples. The uptake curves did not seem to reach equilibrium. This may be due to a constant nonspecific uptake or that the equilibrium level is higher than 2000 n...

  12. The electrosorption of tetraalkylammonium ions on silver iodide

    NARCIS (Netherlands)

    Keizer, de A.

    1981-01-01

    The object of the present investigations was to study the ef fect of the adsorption of charged organic ions on electrically charged, solid-liquid interfaces. To that end, symmetrical quater nary ammonium ions were adsorbed on a silver iodide-electrolyte interface at various surface charges. The elec

  13. Radiation-hard polycrystalline mercuric iodide semiconductor particle counters

    Energy Technology Data Exchange (ETDEWEB)

    Schieber, M. [Hebrew Univ., Jerusalem (Israel)]|[Sandia National Laboratories, Livermore Ca 94556 (United States); Zuck, A.; Melekhov, L.; Nissenbaum, J. [Hebrew Univ., Jerusalem (Israel); Turchetta, R.; Dulinski, W.; Husson, D.; Riester, J.L. [LEPSI (ULP/IN2P3), Strasbourg (France)

    1998-06-01

    Mercuric iodide polycrystalline radiation detectors, which can act as nuclear particle counters and for large area imaging devices, have been fabricated using three different methods. Response to X- and gamma rays, beta particles and to 100GeV muons, as well as radiation hardness results are briefly described. (orig.) 8 refs.

  14. Iodide volatility under condition relevant to PWR steam generator faults

    International Nuclear Information System (INIS)

    The evaluation of iodine volatility during steam generator tube rupture (SGTR) is hampered by three factors: (i) lack of suitable plant data under fault conditions, (ii) lack of experimental data (mainly due to the difficulty of performing experiments under the conditions required) and (iii) uncertainty in theoretical methods to extrapolate experimental data to the required conditions. This report summarises methods of estimating the volatility of hydrogen iodide and iodide salts at the required conditions of temperature and pressure. A thermodynamic method has been used to estimate HI volatility and the density correlation method for iodide salt volatility. It is assumed throughout that it is more conservative to predict higher volatility. Consideration is given to two explanations of experiments carried out at Oak Ridge National Laboratory (ORNL) on the influence of boric acid concentration and pH on the volatility of radioiodine ostensibly under SGTR conditions: (i) the results have been interpreted in terms of reactions involving volatility of iodide salt/ion-pairs and complexation by boric acid in the gas phase and (ii) the possibility is explored that the observed results are due to the influence of oxidation leading to the formation of much more volatile iodine species. (author)

  15. Development of a low-cost inductively coupled argon plasma

    International Nuclear Information System (INIS)

    The aim of this investigation is to drastically reduce running costs of an inductively coupled plasma. This is done by reducing the argon consumption from 20 l/min to about 1 l/min. First, a sample introduction system operating on 0.1 l/min of carrier argon is described. This system ensures a high ratio of plasma argon and carrier argon even at the low total argon consumptions intended. Next, the developed low consumption plasma is presented. In the proposed design, air is blown perpendicularly against the outside of the torch. A different coil has been developed to make air-cooling efficient. Preliminary data on coupling efficiency for the air-cooled plasma are presented. A similarly low argon consumption has been achieved with water as an external coolant medium. It is concluded that a cheaper alternative to the current ICP has become available. (Auth.)

  16. FY-2015 Methyl Iodide Deep-Bed Adsorption Test Report

    Energy Technology Data Exchange (ETDEWEB)

    Soelberg, Nicholas Ray [Idaho National Lab. (INL), Idaho Falls, ID (United States); Watson, Tony Leroy [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-09-30

    Nuclear fission produces fission and activation products, including iodine-129, which could evolve into used fuel reprocessing facility off-gas systems, and could require off-gas control to limit air emissions to levels within acceptable emission limits. Deep-bed methyl iodide adsorption testing has continued in Fiscal Year 2015 according to a multi-laboratory methyl iodide adsorption test plan. Updates to the deep-bed test system have also been performed to enable the inclusion of evaporated HNO3 and increased NO2 concentrations in future tests. This report summarizes the result of those activities. Test results showed that iodine adsorption from gaseous methyl iodide using reduced silver zeolite (AgZ) resulted in initial iodine decontamination factors (DFs, ratios of uncontrolled and controlled total iodine levels) under 1,000 for the conditions of the long-duration test performed this year (45 ppm CH3I, 1,000 ppm each NO and NO2, very low H2O levels [3 ppm] in balance air). The mass transfer zone depth exceeded the cumulative 5-inch depth of 4 bed segments, which is deeper than the 2-4 inch depth estimated for the mass transfer zone for adsorbing I2 using AgZ in prior deep-bed tests. The maximum iodine adsorption capacity for the AgZ under the conditions of this test was 6.2% (6.2 g adsorbed I per 100 g sorbent). The maximum Ag utilization was 51%. Additional deep-bed testing and analyses are recommended to (a) expand the data base for methyl iodide adsorption and (b) provide more data for evaluating organic iodide reactions and reaction byproducts for different potential adsorption conditions.

  17. FY-2015 Methyl Iodide Deep-Bed Adsorption Test Report

    International Nuclear Information System (INIS)

    Nuclear fission produces fission and activation products, including iodine-129, which could evolve into used fuel reprocessing facility off-gas systems, and could require off-gas control to limit air emissions to levels within acceptable emission limits. Deep-bed methyl iodide adsorption testing has continued in Fiscal Year 2015 according to a multi-laboratory methyl iodide adsorption test plan. Updates to the deep-bed test system have also been performed to enable the inclusion of evaporated HNO3 and increased NO2 concentrations in future tests. This report summarizes the result of those activities. Test results showed that iodine adsorption from gaseous methyl iodide using reduced silver zeolite (AgZ) resulted in initial iodine decontamination factors (DFs, ratios of uncontrolled and controlled total iodine levels) under 1,000 for the conditions of the long-duration test performed this year (45 ppm CH3I, 1,000 ppm each NO and NO2, very low H2O levels [3 ppm] in balance air). The mass transfer zone depth exceeded the cumulative 5-inch depth of 4 bed segments, which is deeper than the 2-4 inch depth estimated for the mass transfer zone for adsorbing I2 using AgZ in prior deep-bed tests. The maximum iodine adsorption capacity for the AgZ under the conditions of this test was 6.2% (6.2 g adsorbed I per 100 g sorbent). The maximum Ag utilization was 51%. Additional deep-bed testing and analyses are recommended to (a) expand the data base for methyl iodide adsorption and (b) provide more data for evaluating organic iodide reactions and reaction byproducts for different potential adsorption conditions.

  18. Effects of Nitrogen contamination in liquid Argon

    Science.gov (United States)

    Acciarri, R.; Antonello, M.; Baibussinov, B.; Baldo-Ceolin, M.; Benetti, P.; Calaprice, F.; Calligarich, E.; Cambiaghi, M.; Canci, N.; Carbonara, F.; Cavanna, F.; Centro, S.; Cocco, A. G.; Di Pompeo, F.; Fiorillo, G.; Galbiati, C.; Gallo, V.; Grandi, L.; Meng, G.; Modena, I.; Montanari, C.; Palamara, O.; Pandola, L.; Piano Mortari, G. B.; Pietropaolo, F.; Raselli, G. L.; Roncadelli, M.; Rossella, M.; Rubbia, C.; Segreto, E.; Szelc, A. M.; Ventura, S.; Vignoli, C.

    2010-06-01

    A dedicated test of the effects of Nitrogen contamination in liquid Argon has been performed at the INFN-Gran Sasso Laboratory (LNGS, Italy) within the WArP R&D program. A detector has been designed and assembled for this specific task and connected to a system for the injection of controlled amounts of gaseous Nitrogen into the liquid Argon. The purpose of the test is to detect the reduction of the Ar scintillation light emission as a function of the amount of the Nitrogen contaminant injected in the Argon volume. A wide concentration range, spanning from ~ 10-1 ppm up to ~ 103 ppm, has been explored. Measurements have been done with electrons in the energy range of minimum ionizing particles (γ-conversion from radioactive sources). Source spectra at different Nitrogen contaminations are analyzed, showing sensitive reduction of the scintillation yield at increasing concentrations. Direct PMT signal acquisition exploiting high time resolution by fast waveform recording allowed high precision extraction of the main characteristics of the scintillation light emission in contaminated LAr. In particular, the decreasing behavior in lifetime and relative amplitude of the slow component is found to be appreciable starting from Script O(1 ppm) of Nitrogen concentrations. The rate constant of the quenching process induced by Nitrogen in liquid Ar has been found to be kQ(N2) = 0.11 ± 0.01 μs-1ppm-1, consistent with a previous measurement of this quantity but with significant improvement in precision. On the other hand, no evidence for absorption by N2 impurities has been found up to the higher concentrations here explored.

  19. Argon diffusion from biotite at high temperature and pressure

    Institute of Scientific and Technical Information of China (English)

    陈道公; 贾命命; 李彬贤; 陆全明; 谢鸿森; 侯渭

    1995-01-01

    t The experiments of argon diffusion dynamics for biotite were carried out at 700 -1000℃ and 0.5 - 2,0 GPa and the diffusion coefficient and activation energy using different models have been calculated. The results indicate that the pressure does affect the argon diffusion and its effect is opposite to that of temperature. When p increases, the activation energy increases and diffusion coefficient decreases. The relation between pressure, closure temperature and cooling rate has been obtained. It is postulated that in low T and high p conditions, the argon diffusion from the environment to the system could occur and incur the appearance of the external argon in minerals.

  20. Near-infrared scintillation of liquid argon

    Energy Technology Data Exchange (ETDEWEB)

    Alexander, T. [Fermilab; Escobar, C. O. [Campinas State U.; Lippincott, W. H. [Fermilab; Rubinov, P. [Fermilab

    2016-03-03

    Since the 1970s it has been known that noble gases scintillate in the near infrared (NIR) region of the spectrum (0.7 $\\mu$m < $\\lambda$; < 1.5$\\mu$m). More controversial has been the question of the NIR light yield for condensed noble gases. We first present the motivation for using the NIR scintillation in liquid argon detectors, then briefly review early as well as more recent efforts and finally show encouraging preliminary results of a test performed at Fermilab.

  1. Near-infrared scintillation of liquid argon

    CERN Document Server

    Alexander, T; Lippincott, W H; Rubinov, P

    2016-01-01

    Since the 1970s it has been known that noble gases scintillate in the near infrared (NIR) region of the spectrum (0.7 $\\mu$m < $\\lambda$; < 1.5$\\mu$m). More controversial has been the question of the NIR light yield for condensed noble gases. We first present the motivation for using the NIR scintillation in liquid argon detectors, then briefly review early as well as more recent efforts and finally show encouraging preliminary results of a test performed at Fermilab.

  2. Argon isotope fractionation induced by stepwise heating

    Science.gov (United States)

    Trieloff, Mario; Falter, Martina; Buikin, Alexei I.; Korochantseva, Ekaterina V.; Jessberger, Elmar K.; Altherr, Rainer

    2005-03-01

    Noble gas isotopes are widely used to elucidate the history of the rocks in which they have been trapped, either from distinct reservoirs or by accumulation following radioactive decay. To extract noble gases from their host rocks, stepwise heating is the most commonly used technique to deconvolve isotopically different components, e.g., atmospheric, in situ radiogenic, or excess radiogenic from mantle or crustal reservoirs. The accurate determination of the isotopic composition of these different components is of crucial importance, e.g., for ages obtained by 40Ar- 39Ar stepheating plateaus. However, diffusion theory-based model calculations predict that the stepwise thermal extraction process from mineral phases induces isotope fractionation and, hence, adulterates the original composition. Such effects are largely unconsidered, as they are small and a compelling experimental observation is lacking. We report the first unequivocal evidence for significant mass fractionation of argon isotopes during thermal extraction, observed on shungite, a carbon-rich Precambrian sedimentary rock. The degree of fractionation, as monitored by 38Ar/ 36Ar and 40Ar/ 36Ar ratios, very well agrees with theoretical predictions assuming an inverse square root dependence of diffusion coefficient and atomic mass, resulting in easier extraction of lighter isotopes. Hence, subatmospheric 40Ar/ 36Ar ratios obtained for argon extracted at low temperatures may not represent paleoatmospheric argon. Shungite argon resembles modern atmospheric composition, but constraints on the timing of trapping appear difficult to obtain, as shungites are multicomponent systems. In 40Ar- 39Ar stepwise heating, the isotope fractionation effect could cause systematic underestimations of plateau ages, between 0.15 and 0.4% depending on age, or considerably higher if samples contain appreciable atmospheric Ar. The magnitude of this effect is similar to the presently achieved uncertainties of this increasingly

  3. Argon Purification Studies and a Novel Liquid Argon Re-circulation System

    CERN Document Server

    Mavrokoridis, K; Coleman, J; Lightfoot, P K; McCauley, N; McCormick, K J; Touramanis, C

    2011-01-01

    Future giant liquid argon (LAr) time projection chambers (TPCs) require a purity of better than 0.1 parts per billion (ppb) to allow the ionised electrons to drift without significant capture by any electronegative impurities. We present a comprehensive study of the effects of electronegative impurity on gaseous and liquid argon scintillation light, an analysis of the efficacy of various purification chemicals, as well as the Liverpool LAr setup, which utilises a novel re-circulation purification system. Of the impurities tested - Air, O_2, H_2O, N_2 and CO_2 in the range of between 0.01 ppm to 1000 ppm - H_2O was found to have the most profound effect on gaseous argon scintillation light, and N_2 was found to have the least. Additionally, a correlation between the slow component decay time and the total energy deposited with 0.01 ppm - 100 ppm O_2 contamination levels in liquid argon has been established. The superiority of molecular sieves over anhydrous complexes at absorbing Ar gas, N_2 gas and H_2O vapou...

  4. Thermodynamic analysis of production of high purity titanium by thermal decomposition of titanium iodide

    Institute of Scientific and Technical Information of China (English)

    CHEN Xiao-hu; WANG Hua; LIU Yi-min; FANG Min

    2009-01-01

    High purity titanium was prepared by thermal decomposition of titanium iodide. The feasible synthetic route and optimum decompositon temperaure were obtained by thermodynamic analysis in the process of thermal decomposition of titanium iodide and nucleation growth theory. The temperature for the formation of titanium iodide is in the range of 800-900 K, at which a large amount of titanium iodide vapour can be obtained. The decomposition temperature of titanium iodide is in the range of 1 300-1 500 K, at which a favourable decomposition rate can be achieved. The experiment results show that the purity of the produced titanium is more than 99.995%.

  5. A novel mutation in the sodium/iodide symporter gene in the largest family with iodide transport defect.

    Science.gov (United States)

    Kosugi, S; Bhayana, S; Dean, H J

    1999-09-01

    We previously reported nine children with an autosomally recessive form of congenital hypothyroidism due to an iodide transport defect in a large Hutterite family with extensive consanguinity living in central Canada. Since the original report, we have diagnosed congenital hypothyroidism by newborn TSH screening in 9 additional children from the family. We performed direct sequencing of the PCR products of each NIS (sodium/iodide symporter) gene exon with flanking introns amplified from genomic DNA extracted from peripheral blood cells of the patients. We identified a novel NIS gene mutation, G395R (Gly395-->Arg; GGA-->AGA), in 10 patients examined in the present study. All of the parents tested were heterozygous for the mutation, suggesting that the patients were homozygous. The mutation was located in the 10th transmembrane helix. Expression experiments by transfection of the mutant NIS complimentary DNA into COS-7 cells showed no perchlorate-sensitive iodide uptake, confirming that the mutation is the direct cause of the iodide transport defect in these patients. A patient who showed an intermediate saliva/serum technetium ratio (14.0; normal, > or = 20) and was considered to have a partial or less severe defect in the previous report (IX-24) did not have a NIS gene mutation. It is now possible to use gene diagnostics of this unique NIS mutation to identify patients with congenital hypothyroidism due to an iodide transport defect in this family and to determine the carrier state of potential parents for genetic counseling and arranging rapid and early diagnosis of their infants. PMID:10487695

  6. Ion-beam excitation of liquid argon

    CERN Document Server

    Hofmann, M; Heindl, T; Neumeier, A; Oberauer, L; Potzel, W; Roth, S; Schönert, S; Wieser, J; Ulrich, A

    2015-01-01

    The scintillation light of liquid argon has been recorded wavelength and time resolved with very good statistics in a wavelength interval ranging from 118 nm through 970 nm. Three different ion beams, protons, sulfur ions and gold ions, were used to excite liquid argon. Only minor differences were observed in the wavelength-spectra obtained with the different incident particles. Light emission in the wavelength range of the third excimer continuum was found to be strongly suppressed in the liquid phase. In time-resolved measurements, the time structure of the scintillation light can be directly attributed to wavelength in our studies, as no wavelength shifter has been used. These measurements confirm that the singlet-to-triplet intensity ratio in the second excimer continuum range is a useful parameter for particle discrimination, which can also be employed in wavelength-integrated measurements as long as the sensitivity of the detector system does not rise steeply for wavelengths longer than 190 nm. Using ou...

  7. Argon laser-welded arteriovenous anastomoses.

    Science.gov (United States)

    White, R A; Kopchok, G; Donayre, C; White, G; Lyons, R; Fujitani, R; Klein, S R; Uitto, J

    1987-11-01

    This study compared the healing of laser-welded and sutured canine femoral arteriovenous anastomoses. Arteriovenous fistulas 2 cm in length were created bilaterally in the femoral vessels of 10 dogs and were studied at 1 (n = 2), 2 (n = 2), 4 (n = 3), and 8 (n = 3) weeks. In each animal, one anastomosis (control) was closed with running 6-0 polypropylene sutures, and the contralateral anastomosis (experimental) was sealed with an argon laser (0.5 watt, 4 minutes of exposure, 1830 J/cm2/1 cm length of anastomosis). At removal all experimental anastomoses were patent without hematomas, aneurysms, or luminal narrowing. Histologic examination at 4 weeks revealed that laser-welded anastomoses had less inflammatory response and almost normal collagen and elastin reorientation. At 8 weeks sutured anastomoses had significant intimal hyperplasia whereas laser repairs had normal luminal architecture. Tensile strength and collagen production, measured by the synthesis of hydroxyproline and the steady-state levels of type I and type III procollagen messenger ribonucleic acids, at the anastomoses and in adjacent vein and artery specimens were similar in sutured and laser-welded repairs at 2, 4, and 8 weeks. We conclude that argon laser welding of anastomoses is an acceptable alternative to suture techniques, with the advantage of improved healing without foreign body response and possible diminished intimal hyperplasia at the anastomotic line. PMID:3312648

  8. Electron scattering and transport in liquid argon

    International Nuclear Information System (INIS)

    The transport of excess electrons in liquid argon driven out of equilibrium by an applied electric field is revisited using a multi-term solution of Boltzmann’s equation together with ab initio liquid phase cross-sections calculated using the Dirac-Fock scattering equations. The calculation of liquid phase cross-sections extends previous treatments to consider multipole polarisabilities and a non-local treatment of exchange, while the accuracy of the electron-argon potential is validated through comparison of the calculated gas phase cross-sections with experiment. The results presented highlight the inadequacy of local treatments of exchange that are commonly used in liquid and cluster phase cross-section calculations. The multi-term Boltzmann equation framework accounting for coherent scattering enables the inclusion of the full anisotropy in the differential cross-section arising from the interaction and the structure factor, without an a priori assumption of quasi-isotropy in the velocity distribution function. The model, which contains no free parameters and accounts for both coherent scattering and liquid phase screening effects, was found to reproduce well the experimental drift velocities and characteristic energies

  9. Pollution of liquid argon after neutron irradiation

    CERN Document Server

    Andrieux, M L; Collot, J; de Saintignon, P; Ferrari, A; Hostachy, J Y; Hoummada, A; Martin, P; Merkel, B; Puzo, P; Sauvage, D; Wielers, M

    2001-01-01

    The purpose of the neutron facility installed at SARA is to investigate the behavior of various materials to be used in the ATLAS liquid argon calorimeter, when submitted to fast neutron radiation. The samples are placed in a liquid argon cryostat a few cm away from the neutron source. Various pieces of the electromagnetic calorimeter have been tested in order to evaluate the rate of pollution of the liquid and consequently the possible signal loss in energy measurements. The average fluence was equivalent to the maximum expected in the calorimeter in about 10 years. The most striking feature of the results is that the pollution is not due to oxygen, at least for most of it. Using a particular value of the absorption length derived from these data, a simulation was carried out and the energy signal loss in the calorimeter could be predicted. Within the limits of our present knowledge, the conclusion is that damages due to this pollution will not be a problem. (17 refs).

  10. Pollution of liquid argon after neutron irradiation

    International Nuclear Information System (INIS)

    The purpose of the neutron facility installed at SARA is to investigate the behavior of various materials to be used in the ATLAS liquid argon calorimeter, when submitted to fast neutron radiation. The samples are placed in a liquid argon cryostat a few cm away from the neutron source. Various pieces of the electromagnetic calorimeter have been tested in order to evaluate the rate of pollution of the liquid and consequently the possible signal loss in energy measurements. The average fluence was equivalent to the maximum expected in the calorimeter in about 10 years. The most striking feature of the results is that the pollution is not due to oxygen, at least for most of it. Using a particular value of the absorption length derived from these data, a simulation was carried out and the energy signal loss in the calorimeter could be predicted. Within the limits of our present knowledge, the conclusion is that damages due to this pollution will not be a problem

  11. Defective organification of iodide causing congenital goitrous hypothyroidism.

    Science.gov (United States)

    Ishikawa, N; Eguchi, K; Ohmori, T; Momotani, N; Nagayama, Y; Hosoya, T; Oguchi, H; Mimura, T; Kimura, S; Nagataki, S; Ito, K

    1996-01-01

    A 26-yr-old Japanese woman with congenital goitrous hypo-thyroidism and sensorineural deafness underwent a thyroidectomy. Examination of the thyroid gland revealed characteristic features of multinodular goiter. The T3 and T4 content in thyroglobulin (Tg) were 0.03 and 0.02 mol/mol Tg, respectively. Iodide incorporation into Tg, using slices of the thyroid tissue, revealed that iodide organification of thyroid tissue from our patient was markedly lower than that of normal controls. Then, guaiacol and iodide oxidation activities of thyroid peroxidase (TPO) in our patient's thyroid tissue were lower than those of normal controls (guaiacol assay: 1.92 vs. 30.0 +/- 5.7 mGU/mg protein; iodide assay: 1.1 vs. 6.6 +/- 2.8 mIU/mg protein). Lineweaver-Burk plot analysis of the oxidation rates of guaiacol and iodide indicated that this patient's TPO had a defect in the binding of guaiacol and iodide, but the coupling activity of the patient's TPO was not decreased compared with those of two normal thyroids. In this case and in control subjects, Nothern gel analysis of TPO messenger RNA from unstimulated and TSH-stimulated thyroid cells revealed a 3.2 kilobase species in the former and four distinct messenger RNA species of 4.0, 3.2, 2.1, and 1.7 kilobases in the latter. Western blot analysis of TPOs obtained from this patient and from control subjects identified the same 107 kDa protein, using antimicrosomal antibody-positive serum. We analyzed the coding sequence in the patient's TPO gene by using polymerase chain reaction technique. A single point mutation of G-->C at 1265 base pair was detected only in the TPO gene, but this point mutation does not alter the amino acid residue. It is possible that posttranslational modification such as abnormal glycosylation may occur in the TPO molecules. Furthermore, it is possible that there are differences in the tertiary structures of the TPO molecules between our patient and normal subjects. The above abnormalities of TPO molecules

  12. WARP: a double phase argon programme for dark matter detection

    International Nuclear Information System (INIS)

    WARP (Wimp ARgon Programme) is a double phase Argon detector for Dark Matter search under construction at Laboratori Nazionali del Gran Sasso. We present recent results obtained operating a prototype with a sensitive mass of 2.3 litres deep underground

  13. Stopping Power of Solid Argon for Helium Ions

    DEFF Research Database (Denmark)

    Besenbacher, F.; Bøttiger, Jørgen; Grauersen, O.;

    1981-01-01

    By means of the Rutherford-backscattering method, the stopping cross section of solid argon has been measured for 0.5–3 MeV helium ions to an accuracy of not, vert, similar3%. The results agree within the experimental accuracies with our earlier measurements for gaseous argon over the energy region...

  14. Nitrogen Removal from Molten Steel under Argon DC Glow Plasma

    Institute of Scientific and Technical Information of China (English)

    SUN Ming-shan; DING Wei-zhong; LU Xiong-gang

    2005-01-01

    Under argon DC glow plasma, the nitrogen removal from molten steel was studied. The experimental result showed that nitrogen mass percent could be reduced to 0.000 8%. The change of polarity had no impact on nitrogen removal when the nitrogen mass percent was low. The mechanism of denitrogenation of molten steel under argon DC glow plasma was discussed.

  15. Comparison of Diode and Argon Laser Lesions in Rabbit Retina

    Institute of Scientific and Technical Information of China (English)

    Hui Zhang; Xiaoxin Li; Bin Li; Jiping Da

    2004-01-01

    Purpose: To compare the histological alteration of retina with various spot intensities between diode and argon lasers in order to instruct the clinical use of 810 nm diode laser.Methods: Transpupillary retinal photocoagulations were performed on 42 eyes of 27pigmented rabbits. Histopathologic alteration of lesions in different intensities and different time intervals after irradiation produced by diode and argon laser was observed and compared using light microscopy. Areas of various lesions measured by image analysis system (CMIAS) were compared quantitatively.Results: Histopathologically, two-week-old grade 2 lesions produced by diode laser induced the disappearance of outer nuclear cells. More than a half of all showed reduction in number of outer nuclear layer cells in argon. Fibroblasts appeared in the diode grade 3lesions 5 days after irradiation. CMIAS data showed that all the areas of diode lesions immediately after photocoagulation were to be larger than those of argon laser lesions in the same spot intensity (P < 0.05). However, twenty-four hours after photocoagulation, the area of the diode lesions increased less than that of the argon laser lesions (8%vs.23%).Conclusion: The acute histological effect caused by 810 nm diode laser and argon green laser is similar,while the expansion of lesion area 24 hours after photocoagulation was less with the diode laser compared to the argon. This may be the first report in the literature regarding quantitative analysis of the delayed reaction of argon green lasers.

  16. Synthesis and Structure of Bis(4-nitrobenzaldehyde thiosemicarbazone) Cadmium Iodide

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The title complex, bis(4-nitrobenzaldehyde thiosemicarbazone) cadmium iodide (C16H16CdI2N8O4S2) crystallizes in the triclinic system, space group P1 with a=9.632(2), b=11.227(2), c=14.031(3), α= 67.50(3), β= 86.99(3), γ= 66.64(3)°, V=1278.13, Z = 2, Dc = 2.117gcm-3, F(000) = 772, μ =3.472mm-1 MoKα radiation (λ=0.71073), R = 0.0443, wR= 0.1425 for 4529 observed reflections [I>2σ(I)] of 4731 independent reflections. The result shows that the structure contains CdL2I2 (where L = 4-nitrobenzaldehyde thiosemicarbazone) distorted tetrahedral units in which the two ligands are S-bonded as monodentate to cadmium ion; the two iodide ions are also coordinated to Cd(II).

  17. (1,2-Dicarba-closo-dodecaboranyltrimethylmethanaminium iodide

    Directory of Open Access Journals (Sweden)

    Jong-Dae Lee

    2011-08-01

    Full Text Available The title compound, [1-(CH33NCH2-1,2-C2B10H11]+·I− or C6H22B10N+·I−, was obtained by the reaction of (1,2-dicarba-closo-dodecaboranyldimethylmethanamine with methyl iodide. The asymmetric unit contains two iodide anions and two (o-carboranyltetramethylammonium cations. The bond lengths and angles in the carborane cage are within normal ranges, but the N—Cmethylene—Ccage angle is very large [120.2 (2°] because of repulsion between the carborane and tetramethylammonium units. In the crystal, ions are linked through C—H...I hydrogen bonds.

  18. Methyl iodide production in the ocean: Implications for climate change

    Science.gov (United States)

    Smythe-Wright, Denise; Boswell, Stephen M.; Breithaupt, Petra; Davidson, Russell D.; Dimmer, Claudia H.; Eiras Diaz, Ledicia B.

    2006-09-01

    Methyl iodide concentrations of up to 45 pmol L-1, which flux into the marine boundary layer, have been found in low latitude waters of the Atlantic and Indian oceans. These high concentrations correlate well with the abundance of Prochlorococcus, and we have confirmed the release of methyl iodide by this species in laboratory culture experiments. Extrapolating, we estimate the global ocean flux of iodine to the marine boundary layer from this single source to be 5.3 × 1011 g I yr-1, which is a large fraction of the previously estimated total global flux and the implications are far reaching. Climate prediction models suggest increases in sea surface temperature and changes in biogeographical provenances in response to global warming. Such changes are likely to increase the abundance of Prochlorococcus, and we estimate a concomitant ˜15% increase in the release of iodine species to the atmosphere. Potentially, this could help mitigate global warming.

  19. New applications for the zinc iodide-osmium tetroxide technique.

    OpenAIRE

    Dağdeviren, A; ALP, H.; Ors, U

    1994-01-01

    The zinc iodide-osmium tetroxide (ZIO) fixation/staining method was applied for neurocytological studies and also to examine several other tissue samples including epidermal Langerhans cells, blood and bone marrow cells and lymphoid tissue. Although precise specificity cannot be attributed to the staining reaction, interesting staining patterns for different cell types were observed by using one of the ZIO staining solutions. The significance of ZIO positivity is briefly discussed.

  20. Heterogeneous ice nucleation on silver-iodide-like surfaces

    OpenAIRE

    Fraux, Guillaume; Doye, Jonathan P. K.

    2014-01-01

    We attempt to simulate the heterogeneous nucleation of ice at model silver-iodide surfaces and find relatively facile ice nucleation and growth at the Ag+ termi nated basal face, but never see nucleation at the I- terminated basal face or the prism and normal faces. Water molecules strongly adsorb onto the Ag+ terminate d face to give a well-ordered hexagonal ice-like bilayer that then acts as a template for further ice growth.

  1. Lead iodide perovskite light-emitting field-effect transistor

    OpenAIRE

    Chin, Xin Yu; Cortecchia, Daniele; Yin, Jun; Bruno, Annalisa; Soci, Cesare

    2015-01-01

    Despite the widespread use of solution-processable hybrid organic–inorganic perovskites in photovoltaic and light-emitting applications, determination of their intrinsic charge transport parameters has been elusive due to the variability of film preparation and history-dependent device performance. Here we show that screening effects associated to ionic transport can be effectively eliminated by lowering the operating temperature of methylammonium lead iodide perovskite (CH3NH3PbI3) field-eff...

  2. Radiative efficiency of lead iodide based perovskite solar cells

    OpenAIRE

    Kristofer Tvingstedt; Olga Malinkiewicz; Andreas Baumann; Carsten Deibel; Snaith, Henry J.; Vladimir Dyakonov; Bolink, Henk J.

    2015-01-01

    The maximum efficiency of any solar cell can be evaluated in terms of its corresponding ability to emit light. We herein determine the important figure of merit of radiative efficiency for Methylammonium Lead Iodide perovskite solar cells and, to put in context, relate it to an organic photovoltaic (OPV) model device. We evaluate the reciprocity relation between electroluminescence and photovoltaic quantum efficiency and conclude that the emission from the perovskite devices is dominated by a...

  3. Ionic transport in hybrid lead iodide perovskite solar cells

    OpenAIRE

    Eames, Christopher; Frost, Jarvist Moore; Piers R. F. Barnes; O'Regan, Brian C.; Walsh, Aron; Islam, M. Saiful

    2015-01-01

    Solar cells based on organic–inorganic halide perovskites have recently shown rapidly rising power conversion efficiencies, but exhibit unusual behaviour such as current–voltage hysteresis and a low-frequency giant dielectric response. Ionic transport has been suggested to be an important factor contributing to these effects; however, the chemical origin of this transport and the mobile species are unclear. Here, the activation energies for ionic migration in methylammonium lead iodide (CH3NH...

  4. The sodium iodide symporter: its implications for imaging and therapy

    International Nuclear Information System (INIS)

    The sodium iodide symporter (NIS) is an intrinsic plasma membrane glycoprotein that mediates the active transport of iodide in the thyroid gland and a number of extrathyroidal tissues, in particular lactating mammary gland. In addition to its key function in thyroid physiology, NIS-mediated iodide accumulation allows diagnostic thyroid scintigraphy as well as therapeutic radioiodine application in benign and malignant thyroid disease. NIS therefore represents one of the oldest targets for molecular imaging and therapy. Based on the effective administration of radioiodine that has been used for over 60 years in the management of follicular cell-derived thyroid cancer, cloning and characterization of the NIS gene has paved the way for the development of a novel cytoreductive gene therapy strategy based on targeted NIS expression in thyroidal and nonthyroidal cancer cells followed by therapeutic application of 131I or alternative radionuclides, including 188Re and 211At. In addition, the possibility of direct and non-invasive imaging of functional NIS expression by 123I- and 99mTc-scintigraphy or 124I-PET-imaging allows the application of NIS as a novel reporter gene. In conclusion, the dual role of NIS as diagnostic and therapeutic gene and the detection of extra-thyroidal endogenous NIS expression in breast cancer open promising perspectives in nuclear medicine and molecular oncology for diagnostic and therapeutic application of NIS outside the thyroid gland. (orig.)

  5. Synthesis and evaluation of iodide uptake inhibitors in thyroid gland

    International Nuclear Information System (INIS)

    This work was intended to discover small organic molecules acting as iodide uptake inhibitors in thyroid cells. These compounds can indeed be derivatized into biochemical probes for further characterization of proteins involved in iodide transport mechanisms. On the long term, these inhibitors also appear as attractive drug candidates for treatment of thyroid pathologies or radioprotection against iodine isotopes. A similar strategy was adopted for both of the two inhibitor families. First, we synthesized a chemical library of around 100 analogues; we measured their IC50 against iodide uptake in FRTL-5 cells to get structure-activity relationships. Absolute configuration of stereo-genic centers was also investigated, and a preferential stereochemistry was found to be responsible for activity. From this basis, around twenty 'second-generation' analogues were synthesized by combining fragments contributing to biological activity. Biological evaluation indicated that nine were very potent inhibitors, with IC50 ≤ 6 nM and satisfying physicochemical properties required for drug candidates. Finally, one photoactivatable biotinylated probe was developed in each family and used for photoaffinity labeling. Several specifically labeled proteins are still under identification and constitute new potential therapeutic targets. (author)

  6. Gold nanoelectrode ensembles for direct trace electroanalysis of iodide.

    Science.gov (United States)

    Pereira, Francisco C; Moretto, Ligia M; De Leo, Manuela; Zanoni, Maria V Boldrin; Ugo, Paolo

    2006-08-01

    A procedure for the standardization of ensembles of gold nanodisk electrodes (NEE) of 30 nm diameter is presented, which is based on the analytical comparison between experimental cyclic voltammograms (CV) obtained at the NEEs in diluted solutions of redox probes and CV patterns obtained by digital simulation. Possible origins of defects sometimes found in NEEs are discussed. Selected NEEs are then employed for the study of the electrochemical oxidation of iodide in acidic solutions. CV patterns display typical quasi-reversible behavior which involves associated chemical reactions between adsorbed and solution species. The main CV characteristics at the NEE compare with those observed at millimeter sized gold disk electrodes (Au-macro), apart a slight shift in E1/2 values and slightly higher peak to peak separation at the NEE. The detection limit (DL) at NEEs is 0.3 microM, which is more than one order of magnitude lower than DL at the Au-macro (4 microM). The mechanism of the electrochemical oxidation of iodide at NEEs is discussed. Finally, NEEs are applied to the direct determination of iodide at micromolar concentration levels in real samples, namely in some ophthalmic drugs and iodized table salt.

  7. Enhanced iodide sequestration by 3-biphenyl-5,6-dihydroimidazo 2,1-b thiazole in sodium/iodide sym-porter (NIS)-expressing cells

    International Nuclear Information System (INIS)

    The ability of the sodium/iodide sym-porter (NIS) to take up iodide has long provided the basis for cyto-reductive gene therapy and cancer treatment with radio-iodide. One of the major limitations of this approach is that radio-iodide retention in NIS-expressing cells is not sufficient for their destruction. We identified and characterized a small organic molecule capable of increasing iodide retention in HEK293 cells permanently transfected with human NIS cDNA (hNIS-HEK293) and in the rat thyroid-derived cell line FRTL-5. In the presence of 3-biphenyl-4'-yl-5,6-dihydroimidazo[2,1-b)thiazole (ISA1), the transmembrane iodide concentration gradient was increased up to 4.5-fold. Our experiments indicate that the imidazo-thiazole derivative acts either by inhibiting anion efflux mechanisms, or by promoting the relocation of iodide into subcellular compartments. This new compound is not only an attractive chemical tool to investigate the mechanisms of iodide flux at the cellular level, but also opens promising perspectives in the treatment of cancer after NIS gene transfer. (authors)

  8. Enhanced iodide sequestration by 3-biphenyl-5,6-dihydroimidazo 2,1-b thiazole in sodium/iodide sym-porter (NIS)-expressing cells

    Energy Technology Data Exchange (ETDEWEB)

    Lecat-Guillet, N.; Ambroise, Y. [CEA, DSV, Dept Bioorgan Chem andt IsotopLabelling, Inst Biol and Technol, iBiTecS, F-91191 Gif Sur Yvette (France)

    2008-07-01

    The ability of the sodium/iodide sym-porter (NIS) to take up iodide has long provided the basis for cyto-reductive gene therapy and cancer treatment with radio-iodide. One of the major limitations of this approach is that radio-iodide retention in NIS-expressing cells is not sufficient for their destruction. We identified and characterized a small organic molecule capable of increasing iodide retention in HEK293 cells permanently transfected with human NIS cDNA (hNIS-HEK293) and in the rat thyroid-derived cell line FRTL-5. In the presence of 3-biphenyl-4'-yl-5,6-dihydroimidazo[2,1-b)thiazole (ISA1), the transmembrane iodide concentration gradient was increased up to 4.5-fold. Our experiments indicate that the imidazo-thiazole derivative acts either by inhibiting anion efflux mechanisms, or by promoting the relocation of iodide into subcellular compartments. This new compound is not only an attractive chemical tool to investigate the mechanisms of iodide flux at the cellular level, but also opens promising perspectives in the treatment of cancer after NIS gene transfer. (authors)

  9. Merging of high speed argon plasma jets

    Energy Technology Data Exchange (ETDEWEB)

    Case, A.; Messer, S.; Brockington, S.; Wu, L.; Witherspoon, F. D. [HyperV Technologies Corp., Chantilly, Virginia 22180 (United States); Elton, R. [University of Maryland, College Park, Maryland 20742 (United States)

    2013-01-15

    Formation of an imploding plasma liner for the plasma liner experiment (PLX) requires individual plasma jets to merge into a quasi-spherical shell of plasma converging on the origin. Understanding dynamics of the merging process requires knowledge of the plasma phenomena involved. We present results from the study of the merging of three plasma jets in three dimensional geometry. The experiments were performed using HyperV Technologies Corp. 1 cm Minirailguns with a preionized argon plasma armature. The vacuum chamber partially reproduces the port geometry of the PLX chamber. Diagnostics include fast imaging, spectroscopy, interferometry, fast pressure probes, B-dot probes, and high speed spatially resolved photodiodes, permitting measurements of plasma density, temperature, velocity, stagnation pressure, magnetic field, and density gradients. These experimental results are compared with simulation results from the LSP 3D hybrid PIC code.

  10. Large vessel sealing with the argon laser.

    Science.gov (United States)

    White, R A; Kopchok, G; Donayre, C; Lyons, R; White, G; Klein, S R; Pizzurro, D; Abergel, R P; Dwyer, R M; Uitto, J

    1987-01-01

    This study compared the histology, biochemistry, and tensile strength of laser-welded and sutured canine venotomies, arteriotomies, and arteriovenous fistulas. Twelve animals had bilateral femoral vessels studied, with one repair (control) closed with interrupted 6-0 polypropylene sutures, and the contralateral repair (experimental) welded with the argon laser. Specimens were examined at weekly intervals from 1 to 4 weeks (four animals for each type of repair), and were evaluated histologically by hematoxylin and eosin, elastin, and trichrome stains; biochemically by the formation of [3H]hydroxyproline as an index of collagen synthesis; and mechanically by tensile strength determinations. At removal, all experimental closures were patent without hematomas, aneurysms, or luminal dilatation. Histologic and biochemical examination and tensile strength determinations suggest that laser welding may be an alternative to sutures for repair of large-diameter venotomies, arteriotomies, and arteriovenous fistulas, as healing is comparable to that seen with suture repairs up to 4 weeks postoperatively. PMID:3306233

  11. Vascular Welding Using The Argon Laser

    Science.gov (United States)

    White, Rodney A.; Donayre, Carlos; Kopchok, George; White, Geoffrey; Abergel, R. Patrick; Lyons, Richard; Klein, Stanley; Dwyer, Richard; Uitto, Jouni

    1987-03-01

    This study compared the histology, biochemistry, and tensile strength of laser welded and sutured canine venotomies, arteriotomies and arteriovenous fistulas. Bilateral femoral, carotid or jugular vessels were studied with one repair (control) closed with interrupted 6-0 polypropylene sutures, and the contralatral repair (experimental) welded with the argon laser. Specimens were examined at weekly intervals from 1 to 4 weeks for each type of repair and evaluated histologically by hematoxylineosin, elastin and trichrome stains, biochemically by the formation of [3H] hyaroxyproline as an index of collagen synthesis, ana mechanically by tensile strength determinations. At removal, all experimental closures were patent without hematomas, aneurysms or luminal dilatation. Histologic and biochemical examination and tensile strength determinations suggest that laser welaing may be an alternative to sutures for repair of large diameter venotomies, arteriotomies and arteriovenous fistulas, as they heal comparable to suture repairs up to 4 weeks postoperatively.

  12. Commissioning of the ATLAS liquid argon calorimeters

    CERN Document Server

    Rezaie, Erfan

    ATLAS, a multi-purpose detector built at the LHC at CERN, requires an extensive commissioning campaign to be ready for proton-proton collisions. In this work, we focus on the commissioning of the liquid Argon (LAr) calorimeters, with emphasis on commissioning with cosmic rays. First we outline one phase of the commissioning work, which involves testing of the front-end electronics of the two endcap calorimeters. We then describe two cosmic ray generators as input to a Monte-Carlo simulation of cosmic rays in ATLAS, and compare their results. Finally, we explain a technique developed for this work which uses information from the Tile calorimeters to predict the timing of cosmic rays within the LAr calorimeters, because cosmic rays occur randomly in time whereas the electronics are clocked at [Special characters omitted.] . The results from this analysis tool are compared to default tools, using both simulated and real cosmic ray data in the calorimeters.

  13. Electrochemistry of silver iodide the capacity of the double layer at the silver iodide-water interface

    NARCIS (Netherlands)

    Lyklema, J.; Overbeek, J.Th.G.

    1961-01-01

    A method is described for obtaining differential double layer capacities on silver iodide. Especially the influence of the nature and concentration of indifferent electrolytes was investigated, viz., the nitrates of Li·, K·, Rb·, NH4·, H·, Tl·, Mg··, Ba··, Co··, Cd··, Pb··, La···, Th····, the fluori

  14. Argon laser induced changes to the carbonate content of enamel

    International Nuclear Information System (INIS)

    Argon laser irradiation can be used to cure orthodontic brackets onto teeth in significantly less time than conventional curing lights. In addition, it has been shown that the argon laser seems to impart a demineralization resistance to the enamel. The purpose of this study was to use surface science techniques to ascertain if this demineralization resistance is possibly a result of a decrease in the carbonate content of enamel. Eleven mandibular third molars previously scheduled for extraction were collected and used in the present study. The teeth were sectioned in two and randomly assigned to either the argon laser (457-502 nm; 250 mW cm-2) or the control (no treatment) group. The sections assigned to the argon laser group were cured for 10 s and analyzed. To exaggerate any potential changes the experimental sections were then exposed to a further 110 s of argon laser irradiation. Surface analysis was performed using X-ray photoelectron spectroscopy (XPS) and time-of-flight secondary ion mass spectrometry (ToF-SIMS). The results showed no statistically significant change in the carbonate content of enamel after argon laser irradiation (p > 0.05). Thus, it is suggested that any demineralization resistance imparted to the enamel surface by argon laser irradiation is not due to alterations in carbonate content.

  15. LArGe - A liquid argon scintillation veto for GERDA

    OpenAIRE

    Heisel, M.(Max-Planck-Institut für Kernphysik, Heidelberg, Germany)

    2011-01-01

    LArGe is a Gerda low-background test facility to study novel background suppression methods in a low-background environment, for possible applications in the Gerda experiment. Gerda searches for the neutrinoless double-beta decay in 76Ge, by operating naked germanium detectors submersed into 65 m3 of liquid argon. Similarly, LArGe runs Ge-detectors in 1 m3 (1.4 tons) of liquid argon, which in addition is instrumented with photomultipliers to detect argon scintillation light. The light is used...

  16. Practical reactor production of {sup 41}Ar from argon clathrate

    Energy Technology Data Exchange (ETDEWEB)

    Mercer, J.R. E-mail: jmercer@pharmacy.ualberta.ca; Duke, M.J.M.; McQuarrie, S.A

    2000-06-01

    The radionuclide {sup 41}Ar has many ideal properties as a gas flow tracer. However, the modest cross-section of {sup 40}Ar for thermal neutron activation makes preparation of suitable activities of {sup 41}Ar technically difficult particularly for low flux reactors. Argon can however be trapped in a molecular complex called a clathrate that can then be irradiated. We prepared argon clathrate and explored its irradiation and stability characteristics. Argon clathrate can be used to provide gigabecquerel quantities of {sup 41}Ar even with low power reactors.

  17. Abiotic formation of methyl iodide on synthetic birnessite: A mechanistic study

    Energy Technology Data Exchange (ETDEWEB)

    Allard, Sébastien, E-mail: s.allard@curtin.edu.au; Gallard, Hervé

    2013-10-01

    Methyl iodide is a well-known volatile halogenated organic compound that contributes to the iodine content in the troposphere, potentially resulting in damage to the ozone layer. Most methyl iodide sources derive from biological activity in oceans and soils with very few abiotic mechanisms proposed in the literature. In this study we report that synthetic manganese oxide (birnessite δ-MnO{sub 2}) can catalyze the formation of methyl iodide in the presence of natural organic matter (NOM) and iodide. Methyl iodide formation was only observed at acidic pH (4–5) where iodide is oxidized to iodine and NOM is adsorbed on δ-MnO{sub 2}. The effect of δ-MnO{sub 2}, iodide and NOM concentrations, nature of NOM and ionic strength was investigated. High concentrations of methyl iodide were formed in experiments conducted with the model compound pyruvate. The Lewis acid property of δ-MnO{sub 2} leads to a polarization of the iodine molecule, and catalyzes the reaction with natural organic matter. As manganese oxides are strong oxidants and are ubiquitous in the environment, this mechanism could significantly contribute to the global atmospheric input of iodine. Highlights: • Methyl iodide is formed when iodide, natural organic matter and MnO{sub 2} are in contact. • Iodide is oxidized to iodine by MnO{sub 2} which reacts with NOM already adsorbed on MnO{sub 2}. • High formation of methyl iodide was observed with pyruvate. • This abiotic mechanism could contribute to the input of iodine in the atmosphere. • This abiotic mechanism could impact the ozone layer in the troposphere.

  18. Abiotic formation of methyl iodide on synthetic birnessite: A mechanistic study

    International Nuclear Information System (INIS)

    Methyl iodide is a well-known volatile halogenated organic compound that contributes to the iodine content in the troposphere, potentially resulting in damage to the ozone layer. Most methyl iodide sources derive from biological activity in oceans and soils with very few abiotic mechanisms proposed in the literature. In this study we report that synthetic manganese oxide (birnessite δ-MnO2) can catalyze the formation of methyl iodide in the presence of natural organic matter (NOM) and iodide. Methyl iodide formation was only observed at acidic pH (4–5) where iodide is oxidized to iodine and NOM is adsorbed on δ-MnO2. The effect of δ-MnO2, iodide and NOM concentrations, nature of NOM and ionic strength was investigated. High concentrations of methyl iodide were formed in experiments conducted with the model compound pyruvate. The Lewis acid property of δ-MnO2 leads to a polarization of the iodine molecule, and catalyzes the reaction with natural organic matter. As manganese oxides are strong oxidants and are ubiquitous in the environment, this mechanism could significantly contribute to the global atmospheric input of iodine. Highlights: • Methyl iodide is formed when iodide, natural organic matter and MnO2 are in contact. • Iodide is oxidized to iodine by MnO2 which reacts with NOM already adsorbed on MnO2. • High formation of methyl iodide was observed with pyruvate. • This abiotic mechanism could contribute to the input of iodine in the atmosphere. • This abiotic mechanism could impact the ozone layer in the troposphere

  19. Expression of sodium-iodide symporter in thyroid gland tumors: immunohistochemical study

    Directory of Open Access Journals (Sweden)

    Bondarenko O.O.

    2009-01-01

    Full Text Available One of the key moments of radioiodine therapy, and also radioisotope diagnostics of cancers of a thyroid gland is ability of their cells to accumulate iodide. This ability is provided with activity of the specific transporter – sodium-iodide symporter. Our research has shown disorders of sodium-iodide symporter immunoexpression in all tumors of thyroid gland: from overexpression and absence of plasma membrane expression in differentiated carcinomas, up to weak or actually absent in low differentiated cancers and Hurtle-cells tumors. Thus, there is a prospect of application of the sodium-iodide symporter, as the prognostic marker of thyroid cancers.

  20. Temperature dependent energy levels of methylammonium lead iodide perovskite

    Energy Technology Data Exchange (ETDEWEB)

    Foley, Benjamin J.; Marlowe, Daniel L.; Choi, Joshua J., E-mail: jjc6z@virginia.edu, E-mail: mgupta@virginia.edu, E-mail: scudiero@wsu.edu [Department of Chemical Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Sun, Keye; Gupta, Mool C., E-mail: jjc6z@virginia.edu, E-mail: mgupta@virginia.edu, E-mail: scudiero@wsu.edu [Department of Electrical and Computer Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Saidi, Wissam A. [Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, Pennsylvania 15261 (United States); Scudiero, Louis, E-mail: jjc6z@virginia.edu, E-mail: mgupta@virginia.edu, E-mail: scudiero@wsu.edu [Chemistry Department and Materials Science and Engineering Program, Washington State University, Pullman, Washington 99164 (United States)

    2015-06-15

    Temperature dependent energy levels of methylammonium lead iodide are investigated using a combination of ultraviolet photoemission spectroscopy and optical spectroscopy. Our results show that the valence band maximum and conduction band minimum shift down in energy by 110 meV and 77 meV as temperature increases from 28 °C to 85 °C. Density functional theory calculations using slab structures show that the decreased orbital splitting due to thermal expansion is a major contribution to the experimentally observed shift in energy levels. Our results have implications for solar cell performance under operating conditions with continued sunlight exposure and increased temperature.

  1. Mechanochromic and thermochromic luminescence of a copper iodide cluster.

    Science.gov (United States)

    Perruchas, Sandrine; Le Goff, Xavier F; Maron, Sébastien; Maurin, Isabelle; Guillen, François; Garcia, Alain; Gacoin, Thierry; Boilot, Jean-Pierre

    2010-08-18

    The mechanochromic and thermochromic luminescence properties of a molecular copper(I) iodide cluster formulated [Cu(4)I(4)(PPh(2)(CH(2)CH=CH(2)))(4)] are reported. Upon mechanical grinding in a mortar, its solid-state emission properties are drastically modified as well as its thermochromic behavior. This reversible phenomenon has been attributed to distortions in the crystal packing leading to modifications of the intermolecular interactions and thus of the [Cu(4)I(4)] cluster core geometry. Notably, modification of the Cu-Cu interactions seems to be involved in this phenomenon directly affecting the emissive properties of the cluster. PMID:20698644

  2. Persistent photovoltage in methylammonium lead iodide perovskite solar cells

    OpenAIRE

    Baumann, A.; Tvingstedt, K.; Heiber, M. C.; Väth, S.; C. Momblona; H. J. Bolink; Dyakonov, V.

    2014-01-01

    We herein perform open circuit voltage decay (OCVD) measurements on methylammonium lead iodide (CH3NH3PbI3) perovskite solar cells to increase the understanding of the charge carrier recombination dynamics in this emerging technology. Optically pulsed OCVD measurements are conducted on CH3NH3PbI3 solar cells and compared to results from another type of thin-film photovoltaics, namely, the two reference polymer–fullerene bulk heterojunction solar cell devices based on P3HT:PC60BM and PTB7:PC70...

  3. Temperature dependent energy levels of methylammonium lead iodide perovskite

    International Nuclear Information System (INIS)

    Temperature dependent energy levels of methylammonium lead iodide are investigated using a combination of ultraviolet photoemission spectroscopy and optical spectroscopy. Our results show that the valence band maximum and conduction band minimum shift down in energy by 110 meV and 77 meV as temperature increases from 28 °C to 85 °C. Density functional theory calculations using slab structures show that the decreased orbital splitting due to thermal expansion is a major contribution to the experimentally observed shift in energy levels. Our results have implications for solar cell performance under operating conditions with continued sunlight exposure and increased temperature

  4. Measuring Cell Death by Propidium Iodide Uptake and Flow Cytometry.

    Science.gov (United States)

    Crowley, Lisa C; Scott, Adrian P; Marfell, Brooke J; Boughaba, Jeanne A; Chojnowski, Grace; Waterhouse, Nigel J

    2016-01-01

    Propidium iodide (PI) is a small fluorescent molecule that binds to DNA but cannot passively traverse into cells that possess an intact plasma membrane. PI uptake versus exclusion can be used to discriminate dead cells, in which plasma membranes become permeable regardless of the mechanism of death, from live cells with intact membranes. PI is excited by wavelengths between 400 and 600 nm and emits light between 600 and 700 nm, and is therefore compatible with lasers and photodetectors commonly available in flow cytometers. This protocol for PI staining can be used to quantitate cell death in most modern research facilities and universities. PMID:27371595

  5. Polarized spectral complexes of optical functions of monovalent mercury iodide

    Science.gov (United States)

    Sobolev, V. V.; Sobolev, V. Val.; Anisimov, D. V.

    2015-12-01

    Spectral complexes of optical functions of monovalent mercury iodide Hg2I2 were determined for E ⊥ c and E || c polarizations in the range from 2 to 5.5 eV at 4.2 K. The permittivity and characteristic electron energy loss spectra were expanded in simple components with the determination of their main parameters, including the energy of the maximum and the oscillator strength. The calculations were performed based on known reflectance spectra. Computer programs based on Kramers-Kronig relations and the improved parameter-free method of Argand diagrams were used.

  6. Electronic properties and Compton profiles of silver iodide

    Indian Academy of Sciences (India)

    Alpa Dashora; Ambica Marwal; K R Soni; B L Ahuja

    2010-06-01

    We have carried out an extensive study of electronic properties of silver iodide in - and -phases. The theoretical Compton profiles, energy bands, density of states and anisotropies in momentum densities are computed using density functional theories. We have also employed full-potential linearized augmented plane-wave method to derive the energy bands and the density of states. To compare our theoretical data, isotropic Compton profile measurement on -AgI using 137Cs Compton spectrometer at an intermediate resolution of 0.38 a.u. has been undertaken. The theoretical anisotropies are also interpreted on the basis of energy bands.

  7. The Effects of Dissolved Methane upon Liquid Argon Scintillation Light

    CERN Document Server

    Jones, B J P; Back, H O; Collin, G; Conrad, J M; Greene, A; Katori, T; Pordes, S; Toups, M

    2013-01-01

    In this paper we report on measurements of the effects of dissolved methane upon argon scintillation light. We monitor the light yield from an alpha source held 20 cm from a cryogenic photomultiplier tube (PMT) assembly as methane is injected into a high-purity liquid argon volume. We observe significant suppression of the scintillation light yield by dissolved methane at the 10 part per billion (ppb) level. By examining the late scintillation light time constant, we determine that this loss is caused by an absorption process and also see some evidence of methane-induced scintillation quenching at higher concentrations (50-100 ppb). Using a second PMT assembly we look for visible re-emission features from the dissolved methane which have been reported in gas-phase argon methane mixtures, and we find no evidence of visible re-emission from liquid-phase argon methane mixtures at concentrations between 10 ppb and 0.1%.

  8. Evidence of electric breakdown induced by bubbles in liquid argon

    CERN Document Server

    Bay, F; Murphy, S; Resnati, F; Rubbia, A; Sergiampietri, F; Wu, S

    2014-01-01

    We report on the results of a high voltage test in liquid argon in order to measure its dielectric rigidity. Under stable conditions and below the boiling point, liquid argon was found to sustain a uniform electric field of 100 kV/cm, applied in a region of 20 cm$^2$ area across 1 cm thick gap. When the liquid is boiling, breakdowns may occur at electric fields as low as 40 kV/cm. This test is one of the R&D efforts towards the Giant Liquid Argon Charge Imaging ExpeRiment (GLACIER) as proposed Liquid Argon Time Projection Chamber (LAr TPC) for the LBNO observatory for neutrino physics, astrophysics and nucleon decay searches.

  9. A purity monitoring system for liquid argon calorimeters

    International Nuclear Information System (INIS)

    For liquid argon calorimeters electronegative impurities dissolved in the medium degrade the detector response and deteriorate the energy resolution, especially at high energies. A concept for a purity monitoring system for liquid argon calorimeters has been developed and is presented here. Special combined monitors of 241Am- and 207Bi-cells are used to monitor the concentration of impurities. The working principle as well as results from test measurements are discussed

  10. Size Determination of Argon Clusters from a Rayleigh Scattering Experiment

    Institute of Scientific and Technical Information of China (English)

    LEI An-Le; ZHAI Hua-Jin; LIU Bing-Chen; LI Zhong; NI Guo-Yuan; XU Zhi-Zhan

    2000-01-01

    Argon clusters are produced in the process of adiabatic expansion of a high backing pressure gas into vacuum through a nozzle. The cluster size is determined by a Rayleigh scattering measurement. The scattered signal measured is proportional to the 2.78th power of gas stagnation pressure. The average cluster sizes vary from 100 to more than 12000 atoms/cluster with the argon gas backing pressures ranging between 3 to 45 atm.

  11. Pulse shape discrimination studies in a liquid Argon scintillation detector

    OpenAIRE

    Pollmann, T.

    2007-01-01

    Liquid rare gases have been gaining popularity as detector media in rare event searches, especially dark matter experiments, and one factor driving their adoption is the possibility to recognise different types of ionizing radiation by the pulse shapes they evoke. This work on pulse shape discrimination in a liquid argon scintillation detector was done in the framework of the GERDA experiment, where liquid argon scintillation signals may be used for background suppression purposes. Liquid arg...

  12. Power Consideration for Pulsed Discharges in Potassium Seeded Argon

    Institute of Scientific and Technical Information of China (English)

    XIA Sheng-Guo; HE Jun-Jia; LIU Ke-Fu

    2007-01-01

    Minimization of energy consumed in plasma generation is critical for applications, in which a large volume of plasmas is needed. We suggest that a high electron density atmospheric pressure plasmas can be generated by pulsed discharges in potassium seeded argon at an elevated temperature with a very small power input. The ionization efficiency and power budget of pulsed discharges in such plasmas are analytically studied. The results show that ionization efficiency of argon, especially at small reduced electric field E/N (the ratio of the electric field to the gas number density), is improved effectively in the presence of small amount of potassium additives. Power input of pulsed discharge to sustain a prescribed average level of ionization in potassium seeded argon is three orders of magnitude lower than that in pure argon. Further, unlike in pure argon, it is found that very short high-voltage pulses with very high repetition rates are unnecessary in potassium seeded argon. A pulse with 100ns of pulse duration, 5kHz of repetition rate, and 2Td (1 Td = 1 ×10-21 Vm2) of E/N is enough to sustain an electron density of 10l9m-3 in 1 atm 1500 K Ar+0.1% K mixture, with a very small power input of about 0.08 × 104 W/m3.

  13. Energy resolution for α-particles in doped liquid argon

    International Nuclear Information System (INIS)

    The report describes experiments on the effect of allene doped in liquid argon. In the case of doped argon, a large amount of charge is obtained even at low electric fields and the measured charge increases with the field gradually. This can be explained as follows; part of deposited energy which does not form charge in pure argon contributes to charge signal in doped argon through scintillation photons which ionize allene molecules. The main factors determining the energy resolution for α-particles are considered to be (1) fluctuation in the number of produced ion-electron pairs as expressed by the Fano factor, (2) fluctuation in recombination process, (3) fluctuation in photoionization, (4) fluctuation due to the condition of radioactive source and surface of electrodes, (5) fluctuation in geometrical efficiency due to the range and emission angle of α-particles in liquid argon, and (6) electronic noise of amplifier. The factors (1) and (3) can be neglected because of a large number of associated electrons or photons. In pure liquid argon, the factor (2) may be a cause of bad resolution since the fraction of the produced ion-electron paris which do not recombine is small and the photoionization process never occurs for photons emitted through recombination. (N.K.)

  14. Progress in tumor therapy with human sodium iodide symporter

    International Nuclear Information System (INIS)

    The sodium iodide symporter (NIS) is an intrinsic plasma membrane protein that mediates active iodide transport into the thyroid gland and several extrathyroidal tissues, in particular the lactation mammary gland. Because of the cloning characterization of NIS, its key role in thyroid pathology and physiology could be investigated. The progress would be significant if the mechanisms of NIS expression in lactating mammary gland and breast cancer are elucidated, in which more than 80% of cases express endogenous NIS. In the future, two approaches could extend the use of radioiodide treatment to thyroid cancer and nonthyroidal cancer. One is by using the main mechanisms involving tumorous transformation to treat the tumor, based on the reinducing NIS expression in thyroid and cancer. The other is based on the application of NIS as a novel cytoreductive gene therapy strategy. NIS offers the unique advantage that it can be used both as a reporter and as a therapeutic gene, so that it is possible to image, monitor, and treat the tumor with radioiodide, just as in differentiated thyroid cancer. (authors)

  15. Polymorphic copper iodide clusters: insights into the mechanochromic luminescence properties.

    Science.gov (United States)

    Benito, Quentin; Le Goff, Xavier F; Maron, Sébastien; Fargues, Alexandre; Garcia, Alain; Martineau, Charlotte; Taulelle, Francis; Kahlal, Samia; Gacoin, Thierry; Boilot, Jean-Pierre; Perruchas, Sandrine

    2014-08-13

    An in-depth study of mechanochromic and thermochromic luminescent copper iodide clusters exhibiting structural polymorphism is reported and gives new insights into the origin of the mechanochromic luminescence properties. The two different crystalline polymorphs exhibit distinct luminescence properties with one being green emissive and the other one being yellow emissive. Upon mechanical grinding, only one of the polymorphs exhibits great modification of its emission from green to yellow. Interestingly, the photophysical properties of the resulting partially amorphous crushed compound are closed to those of the other yellow polymorph. Comparative structural and optical analyses of the different phases including a solution of clusters permit us to establish a correlation between the Cu-Cu bond distances and the luminescence properties. In addition, the local structure of the [Cu4I4P4] cluster cores has been probed by (31)P and (65)Cu solid-state NMR analysis, which readily indicates that the grinding process modifies the phosphorus and copper atoms environments. The mechanochromic phenomenon is thus explained by the disruption of the crystal packing within intermolecular interactions inducing shortening of the Cu-Cu bond distances in the [Cu4I4] cluster core and eventually modification of the emissive state. These results definitely establish the role of cuprophilic interactions in the mechanochromism of copper iodide clusters. More generally, this study constitutes a step further into the understanding of the mechanism involved in the mechanochromic luminescent properties of metal-based compounds. PMID:25076411

  16. Nuclear detonation, thyroid cancer and potassium iodide prophylaxis

    Directory of Open Access Journals (Sweden)

    Viroj Wiwanitkit

    2011-01-01

    Full Text Available The recent nuclear disaster at Japan has raised global concerns about effects of radioactive leakage in the environment, associated hazards, and how they can be prevented. In this article, we have tried to explain about the guidelines laid down by World Health Organization for a potassium iodide prophylaxis following a nuclear disaster, and its mechanism of action in preventing thyroid cancer. Data was collected mainly from the studies carried out during the Chernobyl disaster of Russia in 1986 and the hazardous effects especially on the thyroid gland were studied. It was seen that radioactive iodine leakage from the nuclear plants mainly affected the thyroid gland, and especially children were at a higher risk at developing the cancers. Potassium Iodide prophylaxis can be administered in order to prevent an increase in the incidence of thyroid cancers in the population of an area affected by a nuclear disaster. However, one has to be cautious while giving it, as using it without indication has its own risks.

  17. Nonradiometric and radiometric testing of radioiodine sorbents using methyl iodide

    International Nuclear Information System (INIS)

    A nonradiometric test of adsorbents and adsorbers with normal methyl iodide (CH3127I) is desirable. Use of methyl radioiodide (CH3131I) requires special precautions and facilities and results in bed contamination. However, first it must be established to what extent the removal of CH3127I by adsorbents is indicative of the removal of CH3131I. An experimental apparatus was built and used to simultaneously measure the penetrations of CH3I molecules and the radioisotope in CH3131I through charcoal absorbent beds. Gas chromatography with electron capture detection was used to measure CH3I. Radioiodine was measured using charcoal traps within NaI scintillation well crystals. Real time (5-min interval) radioiodine measurement provided immediate penetration results directly comparable to the real time penetrations of methyl iodide. These penetrations were compared for typical charcoal adsorbents with these impregnants: (a) 5% KI3, (b) 5% KI3 + 2% TEDA, (c) 5% TEDA, and (d) metal salts (Whetlerite). Differences between CH3I and CH3131I penetrations observed for the two iodized charcoals were attributed to isotope exchange reactions. Equivalent penetrations were observed for non-iodized adsorbents and for iodized ones at initial time. First order rates were confirmed for reactions with TEDA and for isotope exchange. This was one more confirmation of the lack of a challenge concentration effect on efficiencies at low test bed loadings. In addition to other removal mechanisms, reversible physical adsorption was observed with all charcoals

  18. Numerical modelling of methyl iodide in the eastern tropical Atlantic

    Directory of Open Access Journals (Sweden)

    I. Stemmler

    2013-06-01

    Full Text Available Methyl iodide (CH3I is a volatile organic halogen compound that contributes significantly to the transport of iodine from the ocean to the atmosphere, where it plays an important role in tropospheric chemistry. CH3I is naturally produced and occurs in the global ocean. The processes involved in the formation of CH3I, however, are not fully understood. In fact, there is an ongoing debate whether production by phytoplankton or photochemical degradation of organic matter is the main source term. Here, both the biological and photochemical production mechanisms are considered in a biogeochemical module that is coupled to a one-dimensional water column model for the eastern tropical Atlantic. The model is able to reproduce observed subsurface maxima of CH3I concentrations. But, the dominating source process cannot be clearly identified as subsurface maxima can occur due to both direct biological and photochemical production. However, good agreement between the observed and simulated difference between surface and subsurface methyl iodide concentrations is achieved only when direct biological production is taken into account. Production rates for the biological CH3I source that were derived from published laboratory studies are shown to be inappropriate for explaining CH3I concentrations in the eastern tropical Atlantic.

  19. New argon-argon (40Ar/39Ar) radiometric age dates from selected subsurface basalt flows at the Idaho National Laboratory, Idaho

    Science.gov (United States)

    Hodges, Mary K.; Turrin, Brent D.; Champion, Duane E.; Swisher, Carl C.

    2015-01-01

    In 2011, the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, collected samples for 12 new argon-argon radiometric ages from eastern Snake River Plain olivine tholeiite basalt flows in the subsurface at the Idaho National Laboratory. The core samples were collected from flows that had previously published paleomagnetic data. Samples were sent to Rutgers University for argon-argon radiometric dating analyses.

  20. CuI-catalyzed Synthesis of Aryl Thiocyanates from Aryl Iodides

    Institute of Scientific and Technical Information of China (English)

    Ye Feng WANG; Yuan ZHOU; Jia Rui WANG; Lei LIU; Qing Xiang GUO

    2006-01-01

    An operationally simple and inexpensive catalyst system was developed for the cross coupling of potassium thiocyanate with aryl iodides by using CuI as catalyst, 1, 10-phenanthroline as ligand, and tetraethylammonium iodide as activator. The procedure is applicable for the synthesis of diverse aryl thiocyanates without any exotic, poisonous reagents.

  1. Bibenzimidazole containing mixed ligand cobalt(III) complex as a selective receptor for iodide

    Digital Repository Service at National Institute of Oceanography (India)

    Indumathy, R.; Parameswarana, P.S.; Aiswarya, C.V.; Nair, B.U.

    -, OH- and OAc- do not bring about any dramatic visual colorimetric changes. However, metallo-receptor 2 brings about vivid color change with iodide anion visually and this could be due to charge transfer transition via ion pair formation with iodide ion...

  2. Synthesis, growth, structural, thermal, optical properties of new metal-organic crystals: Methyltriphenylphosphonium iodide thiourea and methyltriphenylphosphonium iodide chloroform hemisolvate

    Science.gov (United States)

    Shivachev, Boris L.; Kossev, Krassimir; Dimowa, Louiza T.; Yankov, Georgi; Petrov, Todor; Nikolova, Rositsa P.; Petrova, Nadia

    2013-08-01

    Crystals of methyltriphenylphosphonium iodide thiourea (1) and methyltriphenylphosphonium iodide chloroform hemisolvate (2) were obtained for the first time. Fourier transform infrared (FTIR) spectral studies have been performed to identify the functional groups. Thermogravimetric analysis (TGA) and differential thermal analysis (DTA) were used to study their thermal properties. The optical transmittance window and the lower cutoff wavelength have been identified by UV-vis studies. Crystals of the title compounds suitable for single crystal X-ray analyses were successfully grown by slow evaporation and diffraction data were collected to elucidate the molecular structure and interactions. The proton donors (phosphonium) and proton acceptor (iodine) in the structure of 1 provide infrastructure to introduce charge asymmetry while in 2 chloroform molecule is not involved in the charge transfer. An optical quality crystal of 1 (5×4×2 mm3) was obtained by macroseeding. The crystal has developed facets with major ones (001) and (00¯1). A crystal of 1 was tested with 1060 nm laser radiation and showed second harmonic generation (SHG).

  3. Fabrication of Efficient Low-Bandgap Perovskite Solar Cells by Combining Formamidinium Tin Iodide with Methylammonium Lead Iodide

    Energy Technology Data Exchange (ETDEWEB)

    Liao, Weiqiang; Zhao, Dewei; Yu, Yue; Shrestha, Niraj; Ghimire, Kiran; Grice, Corey R.; Wang, Changlei; Xiao, Yuqing; Cimaroli, Alexander J.; Ellingson, Randy J.; Podraza, Nikolas J.; Zhu, Kai; Xiong, Ren-Gen; Yan, Yanfa

    2016-09-28

    Mixed tin (Sn)-lead (Pb) perovskites with high Sn content exhibit low bandgaps suitable for fabricating the bottom cell of perovskite-based tandem solar cells. In this work, we report on the fabrication of efficient mixed Sn-Pb perovskite solar cells using precursors combining formamidinium tin iodide (FASnI3) and methylammonium lead iodide (MAPbI3). The best-performing cell fabricated using a (FASnI3)0.6(MAPbI3)0.4 absorber with an absorption edge of ~1.2 eV achieved a power conversion efficiency (PCE) of 15.08 (15.00)% with an open-circuit voltage of 0.795 (0.799) V, a short-circuit current density of 26.86(26.82) mA/cm2, and a fill factor of 70.6(70.0)% when measured under forward (reverse) voltage scan. The average PCE of 50 cells we have fabricated is 14.39 +/- 0.33%, indicating good reproducibility.

  4. Colorimetric sensing of iodide based on triazole-acetamide functionalized gold nanoparticles

    International Nuclear Information System (INIS)

    We have modified gold nanoparticles (AuNPs) with triazole acetamide to obtain a material for the sensitive and selective colorimetric determination of iodide. The functionalized AuNPs were prepared by a reductive single chemical step using a Cu(I)-catalyzed click reaction. The presence of iodide ions induces the aggregation of these AuNPs and results in a color change from wine-red to purple. The iodide-induced aggregation can be detected visually with bare eyes, but also by photometry. The detection limit is as low as 15 nM. The method displays excellent selectivity for iodide over other anions due to the selective interaction with the amido groups of the triazole. The method was applied to the determination of iodide in spiked lake waters. (author)

  5. Evolution of Martian atmospheric argon: Implications for sources of volatiles

    Science.gov (United States)

    Hutchins, Kevin S.; Jakosky, Bruce M.

    We have examined processes affecting isotopes of argon (36Ar, 38Ar, 40Ar) in order to determine important atmospheric sources and sinks. Our simple model for argon evolution incorporates production of radiogenic argon in the mantle, outgassing of all argon species by extrusive and intrusive volcanism, and loss to space by knock-on sputtering above the exobase. Sputtering has been shown previously to be an important loss process for atmospheric species, especially isotopes of noble gases, which have few other mechanisms of escape. The integrated evolution of argon (36Ar, 38Ar, and 40Ar, respectively) is modeled in terms of these variables: (1) the planetary concentration of potassium, (2) the fraction of juvenile argon released catastrophically during the first 600 Myr., (3) potential variation in the time-history of sputtering loss from that suggested by Luhmann et al. [1992], and (4) the volume of total outgassing to the surface as compared to outgassing contributed by volcanic release. Our results indicate that Mars has lost between 85-95% of 36Ar and 70-88% of outgassed 40Ar. Due to this substantial loss, the planet must have outgassed the equivalent of between 10 and 100 times the total volume of gases released by extrusive and intrusive volcanics. This indicates that volcanic outgassing, alone, is insufficient to explain the present-day abundances of 36Ar and 40Ar in the Martian atmosphere. Similar calculations for 20Ne suggest outgassed volumes of between 100 and 1800 times in excess of that due to volcanism. This results in a distinct Ne/Ar elemental fractionation, with a preference for outgassing argon, of the order of 10 to 17. Although the results must be evaluated within the model uncertainties, the results are compelling in that they unequivocally show the existence of additional sources of atmospheric volatiles and helps define a means to identify them.

  6. Horizontal Ampoule Growth and Characterization of Mercuric Iodide at Controlled Gas Pressures for X-Ray and Gamma Ray Spectrometers

    Energy Technology Data Exchange (ETDEWEB)

    McGregor, Douglas S. [Kansas State Univ., Manhattan, KS (United States). Semiconductor Materials and Radiological Technologies Lab., Dept. of Nuclear and Mechanical Engineering; Ariesanti, Elsa [Kansas State Univ., Manhattan, KS (United States). Semiconductor Materials and Radiological Technologies Lab., Dept. of Nuclear and Mechanical Engineering; Corcoran, Bridget [Kansas State Univ., Manhattan, KS (United States). Semiconductor Materials and Radiological Technologies Lab., Dept. of Nuclear and Mechanical Engineering

    2004-04-30

    The project developed a new method for producing high quality mercuric iodide crystals of x-ray and gamma spectrometers. Included are characterization of mercuric iodide crystal properties as a function of growth environment and fabrication and demonstration of room-temperature-operated high-resolution mercuric iodide spectrometers.

  7. Characterisation of GERDA Phase-I detectors in liquid argon

    International Nuclear Information System (INIS)

    GERDA will search for neutrinoless double beta decay in 76Ge by submerging bare enriched HPGe detectors in liquid argon. In GERDA Phase-I, reprocessed enriched-Ge detectors, which were previously operated by the Heidelberg-Moscow and IGEX collaborations, and reprocessed natural-Ge detectors from Genius-TF, will be redeployed. We have tested the operation and performance of bare HPGe detectors in liquid nitrogen and in liquid argon over more than three years with three non-enriched p-type prototype detectors. The detector handling and mounting procedures have been defined and the Phase-I detector technology, the low-mass assembly and the long-term stability in liquid argon have been tested successfully. The Phase-I detectors were reprocessed by Canberra Semiconductor NV, Olen, according to their standard technology but without the evaporation of a passivation layer. After their reprocessing, the detectors have been mounted in their low-mass holders and their characterisation in liquid argon performed. The leakage current, the counting characteristics and the efficiency of the detectors have been measured. The testing of the detectors was carried out in the liquid argon test stand of the GERDA underground Detector Laboratory (GDL) at LNGS. The detectors are now stored underground under vacuum until their operation in GERDA.

  8. The Spectroscopic Detectability of Argon in the Lunar Atmosphere

    CERN Document Server

    Parker, J W; Gladstone, G R; Shull, J M; Parker, Joel Wm.

    1999-01-01

    Direct measurements of the abundance of argon in the lunar atmosphere were made in 1973 by instruments placed on the Moon during the Apollo 17 mission, but the total daytime abundance is unknown due to instrument saturation effects; thus, until we are able to return to the Moon for improved direct measurements, we must use remote sensing to establish the daytime abundance. In this paper, we present a complete analysis of the potential for measuring argon in the lunar atmosphere via emission-line or absorption-line observations. We come to the surprising conclusion that the lower limit established by the in situ lunar argon measurements implies that any absorption-line measurement of argon in the lower, dayside lunar atmosphere requires analysis in the optically-thick regime. In light of this result, we present the results of our EUVS sounding rocket observations of the lunar occultation of Spica, which provide a new upper limit on the abundance of argon in the daytime lunar atmosphere. We also re-analyze a re...

  9. Strawberry growers wavered over methyl iodide, feared public backlash

    Directory of Open Access Journals (Sweden)

    Julie Guthman

    2016-08-01

    Full Text Available Methyl iodide, once promoted as a suitable alternative to methyl bromide for soil fumigation in strawberry systems, was withdrawn from the market in 2012 after a contentious regulatory battle that revolved around its high toxicity. At the time of its withdrawal, Arysta LifeScience, the maker of the chemical, claimed that it was no longer economically viable. In this study, I investigated what made the chemical nonviable, with a specific focus on growers' nonadoption of it. Interviews with strawberry growers in the four top California strawberry-growing counties revealed that growers' decisions not to use it were primarily related to public disapproval, although the continued availability of methyl bromide and other fumigants played a contributing role by making adoption less urgent. The study results suggest that policies in place during the methyl bromide phaseout did not strongly encourage the development and extension of less toxic alternatives, which undermined the strawberry industry's position.

  10. Betaine potassium iodide dihydrate: a new compound of betaine

    International Nuclear Information System (INIS)

    Betaine potassium iodide dihydrate, [(CH3)3N+CH2COO-]2.KI.2H2O, BKI for short, is a new compound of the aminoacid betaine with a triclinic symmetry and the space group P1-bar at room temperature. The study of dielectric properties provided evidence for the existence of a structural phase transition occurring around 100 K. The spontaneous electric polarization is zero in both phases. A study of dielectric dispersion disclosed two relaxational modes with different relevance in the high and in the low temperature phases. The main features observed in BKI are consistently described by the Landau theory, by assuming a quadratic coupling between the primary order parameter and the electric polarization. (author). Letter-to-the-editor

  11. Mercuric iodide crystals obtained by solvent evaporation using ethanol

    International Nuclear Information System (INIS)

    Millimeter-sized mercuric iodide crystals were fabricated by the solvent evaporation technique using pure ethanol as a solvent. Three different conditions for solution evaporation were tested: (i) in the dark at room temperature; (ii) in the presence of light at room temperature and (iii) in an oven at 40 deg. C. Morphology, structure, optical and electrical properties were investigated using several techniques. Crystals fabricated in the dark show better properties and stability than others, possibly because the larger the energy of the system, the larger the number of induced growth defects. The crystals fabricated in the dark have adequate structure for higher resistivity and activation energy close to half the optical band-gap, as desired. With proper encapsulation these crystals might be good candidates for the development of ionizing radiation sensors.

  12. Photon recycling in lead iodide perovskite solar cells

    Science.gov (United States)

    Pazos-Outón, Luis M.; Szumilo, Monika; Lamboll, Robin; Richter, Johannes M.; Crespo-Quesada, Micaela; Abdi-Jalebi, Mojtaba; Beeson, Harry J.; Vrućinić, Milan; Alsari, Mejd; Snaith, Henry J.; Ehrler, Bruno; Friend, Richard H.; Deschler, Felix

    2016-03-01

    Lead-halide perovskites have emerged as high-performance photovoltaic materials. We mapped the propagation of photogenerated luminescence and charges from a local photoexcitation spot in thin films of lead tri-iodide perovskites. We observed light emission at distances of ≥50 micrometers and found that the peak of the internal photon spectrum red-shifts from 765 to ≥800 nanometers. We used a lateral-contact solar cell with selective electron- and hole-collecting contacts and observed that charge extraction for photoexcitation >50 micrometers away from the contacts arose from repeated recycling between photons and electron-hole pairs. Thus, energy transport is not limited by diffusive charge transport but can occur over long distances through multiple absorption-diffusion-emission events. This process creates high excitation densities within the perovskite layer and allows high open-circuit voltages.

  13. Investigation of sodium iodide hydration and dehydration in moist atmosphere

    International Nuclear Information System (INIS)

    Effect of different factors on NaI hydration and dehydration kinetics under nonequilibrium conditions is studied. NaIx2H2O solid or homogeneous solution is established to be formed at sodium iodide interaction with water vapour depending on air humidity. At low humidity water absorption is not observed. Effect of water vapour pressure, the NaI particle size, the air flux rate over a salt on the absorption rate is studied. The latter points to process rate limitation by diffusion in a gaseous phase. The NaI solution decomposition at light with iodine formation is marked. The character of NaIx2H2O dehydration depends on water vapour removing from the over-salt space. Total water removing before and after crystal hydrate thermal degradation when aqueous solution evaporation occurs, is possible. At 143 deg C the water vapour pressure over solution equals the atmospheric one

  14. Development of mercuric iodide detectors for XAS and XRD measurements

    International Nuclear Information System (INIS)

    A prototype element for an energy dispersive detector (EDD) array was constructed using a Mercuric Iodide detector. Both detector and front end FET could be thermoelectrically cooled. Tested at SSRL, the detector had 250 eV electronic noise and 315 eV resolution at 5.9 keV. K line fluorescence spectra were collected for selected elements between Cl (2622 eV) and Zn (8638 eV). Count rate capability to 60,000 cps was demonstrated. Several detector parameters were measured, including energy linearity, resolution vs. shaping time, and detector dead time. An EXAFS (extended x-ray absorption fine structure) spectrum was recorded and compared to simultaneously collected transmission data

  15. Metastable argon beam source using a surface wave sustained plasma

    International Nuclear Information System (INIS)

    A new source of metastable argon atoms in the thermal energy range is reported. The source is based on expanding a plasma sustained by electromagnetic surface waves in a quartz tube through a converging nozzle and extracting a beam from the supersonic free-expansion jet. The beam was characterized by time-of-flight measurements which yielded the absolute intensity and velocity distribution of the argon metastables. The source produced a maximum intensity of 6.2x1014 metastables per second per steradian, the highest time-averaged intensity of thermal argon metastables of any source reported to date. A simple picture of an expanding plasma in a recombination regime is used to explain the dependence of the metastable intensity on absorbed power

  16. On the electric breakdown in liquid argon at centimeter scale

    Science.gov (United States)

    Auger, M.; Blatter, A.; Ereditato, A.; Goeldi, D.; Janos, S.; Kreslo, I.; Luethi, M.; von Rohr, C. Rudolf; Strauss, T.; Weber, M. S.

    2016-03-01

    We present a study on the dependence of electric breakdown discharge properties on electrode geometry and the breakdown field in liquid argon near its boiling point. The measurements were performed with a spherical cathode and a planar anode at distances ranging from 0.1 mm to 10.0 mm. A detailed study of the time evolution of the breakdown volt-ampere characteristics was performed for the first time. It revealed a slow streamer development phase in the discharge. The results of a spectroscopic study of the visible light emission of the breakdowns complement the measurements. The light emission from the initial phase of the discharge is attributed to electro-luminescence of liquid argon following a current of drifting electrons. These results contribute to set benchmarks for breakdown-safe design of ionization detectors, such as Liquid Argon Time Projection Chambers (LAr TPC).

  17. The Simulation of the ATLAS Liquid Argon Calorimetry

    CERN Document Server

    Archambault, J P; Carli, T; Costanzo, D; Dell'Acqua, A; Djama, F; Gallas, M; Fincke-Keeler, M; Khakzad, M; Kiryunin, A; Krieger, P; Leltchouk, M; Loch, P; Ma, H; Menke, S; Monnier, E; Nairz, A; Niess, V; Oakham, G; Oram, C; Pospelov, G; Rajagopalan, S; Rimoldi, A; Rousseau, D; Rutherfoord, J; Seligman, W; Soukharev, A; Strízenec, P; Tóth, J; Tsukerman, I; Tsulaia, V; Unal, G; Grahn, K J

    2008-01-01

    In ATLAS, all of the electromagnetic calorimetry and part of the hadronic calorimetry is performed by a calorimeter system using liquid argon as the active material, together with various types of absorbers. The liquid argon calorimeter consists of four subsystems: the electromagnetic barrel and endcap accordion calorimeters; the hadronic endcap calorimeters, and the forward calorimeters. A very accurate geometrical description of these calorimeters is used as input to the Geant 4-based ATLAS simulation, and a careful modelling of the signal development is applied in the generation of hits. Certain types of Monte Carlo truth information ("Calibration Hits") may, additionally, be recorded for calorimeter cells as well as for dead material. This note is a comprehensive reference describing the simulation of the four liquid argon calorimeteter components.

  18. Energy resolution studies of liquid argon ionization detectors

    International Nuclear Information System (INIS)

    A gridded ionization chamber was used to study the energy resolution in liquid argon with electrons from a 207Bi radioactive source. Argon was purified in the gas phase with a simple and reliable system, capable of reducing the impurity level below 1 ppb O2 equivalent, as inferred by a pulse shape analysis of the ionization signals. The electron spectrum was measured at different drift fields, up to 10.9 KV/cm. At this maximum field, a total energy resolution of 32 keV (fwhm), corresponding to a noise-subtracted energy resolution of 26 keV (fwhm), was obtained for the 976 keV conversion electron line. This value is the best reported so far in liquid argon but is still a factor of seven worse than the theoretical limit set by the Fano factor. The reasons for this discrepancy are discussed. (orig.)

  19. Liquid Argon Calorimetry with LHC-Performance Specifications

    CERN Multimedia

    2002-01-01

    % RD-3 Liquid Argon Calorimetry with LHC-Performance Specifications \\\\ \\\\Good electromagnetic and hadronic calorimetry will play a central role in an LHC detector. Among the techniques used so far, or under development, the liquid argon sampling calorimetry offers high radiation resistence, good energy resolution (electromagnetic and hadronic), excellent calibration stability and response uniformity. Its rate capabilities, however, do not yet match the requirements for LHC. \\\\ \\\\The aim of this proposal is to improve the technique in such a way that high granularity, good hermiticity and adequate rate capabilities are obtained, without compromising the above mentioned properties. To reach this goal, we propose to use a novel structure, the $^{\\prime\\prime}$accordion$^{\\prime\\prime}$, coupled to fast preamplifiers working at liquid argon temperature. Converter and readout electrodes are no longer planar and perpendicular to particles, as usual, but instead they are wiggled around a plane containing particles. ...

  20. A therapeutic experience on Port Wine hemangiomas with Argon Laser

    Directory of Open Access Journals (Sweden)

    Farahvash M

    1997-09-01

    Full Text Available Port wine stains are benign but cosmetically devasting congenital angiomas. The argon laser is a therapeutic device newly applied to this condition. Our program was begun 6 years ago. From the beginning, the study was conceived as a clinical investigation of both the port wine stain and its argon laser therapy. A total of 218 patients with port wine stains have been studied and many aspects of their clinical condition detailed. Employing the Argon laser, test spots have been carried out in patients and the results have been analyzed with clinical aspects of the lesions. Altogether, 501 treatments were performed in 218 patients. Good to excellent results were obtained in 81 patients. Moderate Result was obtained in 31 weak result in 65 patients. Most common complication were hyperpigmentation and depressed scar.

  1. On the Electric Breakdown in Liquid Argon at Centimeter Scale

    CERN Document Server

    Auger, M; Ereditato, A; Goeldi, D; Janos, S; Kreslo, I; Luethi, M; von Rohr, C Rudolf; Strauss, T; Weber, M S

    2015-01-01

    We present a study on the dependence of electric breakdown discharge parameters on electrode geometry and the breakdown field in liquid argon near its boiling point. The measurements were performed with a spherical cathode and a planar anode at distances ranging from 0.1 mm to 10.0 mm. A detailed study of the time evolution of the breakdown volt-ampere characteristics was performed for the first time. It revealed a slow streamer development phase in the discharge. The results of a spectroscopic study of the visible light emission of the breakdowns complement the measurements. The light emission from the initial phase of the discharge is attributed to electro-luminescence of liquid argon following a current of drifting electrons. These results contribute to set benchmarks for breakdown-safe design of ionization detectors, such as Liquid Argon Time Projection Chambers (LAr TPC).

  2. Evaluation of quaternary ammonium halides for removal of methyl iodide from flowing air streams

    International Nuclear Information System (INIS)

    The quaternary ammonium halides of several tertiary amines were used as impregnants on activated carbon and were tested for methyl iodide penetration in accordance with test Method A, ASTM D3803, 1979, ''Standard Test Methods for Radio-iodine Testing of Nuclear Grade Gas Phase Adsorbents''. The results suggest that the primary removal mechanism for methyl iodide-131 is isotopic exchange with the quaternary ammonium halide. For example, a 5 wt% impregnation of each of the tetramethyl, tetraethyl, tetrapropyl and tetrabutyl ammonium iodides on activated carbon yielded percent penetrations of 0.47, 0.53, 0.78, and 0.08 respectively when tested according to Method A of ASTM D3803. A sample impregnated with 5% tetramethyl ammonium hydroxide gave a methyl iodide penetration of 64.87%, thus supporting the isotopic exchange mechanism for removal. It has been a generally held belief that the success of tertiary amines as impregnants for radioiodine removal is a result of their ability to complex with the methyl iodide. The results of the work indicates that the superiority of the tertiary amines similar to triethylene diamine and quinuclidine, when compared to their straight chain analogs, is a result of their ease in reacting with methyl iodide-127 to form the quaternary ammonium iodide followed by isotopic exchange

  3. Vaporization kinetics of Sb2S3 in argon fluid

    Institute of Scientific and Technical Information of China (English)

    杨勇; 华一新

    2003-01-01

    The vaporization kinetics of antimony trisulfide in argon fluid was studied with thermogravimetry at 873- 1 173 K. A theoretical model was developed to calculate the overall rate constant and the mass transfer coefficient ingas phase. The experimental results show that the vaporization rate is enhanced with increasing temperature and ar-gon flow-rate. The evaporation rate is mainly controlled by mass transport in the gas phase. The apparent activationenergy for the process is found to be 55.54 kJ/mol. It is demonstrated that the mass transfer coefficient in gas phaseis decreased with increasing temperature.

  4. Modelling of a supersonic ICP argon-hydrogen expansion

    International Nuclear Information System (INIS)

    An expanding argon-hydrogen plasma is investigated by means of simulations. The model is a hydrodynamical model specific for plasma expansions, taking into account the conservation laws of mass, momentum and energy. The code includes the Rankine-Hugoniot relations to calculate shock jump conditions. Results are shown for the expansion from an inductively coupled plasma (ICP) with a separated Laval nozzle. The expansion discussed here is a 'weakly' under-expanding argon-hydrogen plasma. The results from the ICP expansion are verified with probe measurements

  5. Attosecond-correlated dynamics of two electrons in argon

    Indian Academy of Sciences (India)

    V Sharma; N Camus; B Fischer; M Kremer; A Rudenko; B Bergues; M Kuebel; N G Johnson; M F Kling; T Pfeifer; J Ullrich; R Moshammer

    2014-01-01

    In this work we explored strong field-induced decay of doubly excited transient Coulomb complex Ar** → Ar2++2. We measured the correlated two-electron emission as a function of carrier envelop phase (CEP) of 6 fs pulses in the non-sequential double ionization (NSDI) of argon. Classical model calculations suggest that the intermediate doubly excited Coulomb complex loses memory of its formation dynamics. We estimated the ionization time difference between the two electrons from NSDI of argon and it is 200 ± 100 as (N Camus et al, Phys. Rev. Lett. 108, 073003 (2012)).

  6. Uranium-liquid argon calorimetry: preliminary results from the DO tests

    International Nuclear Information System (INIS)

    The motivations for using uranium and liquid argon in sampling calorimetry are reviewed and the pros and cons of the technique are discussed. Preliminary results of the DO uranium-liquid argon test program are presented. 9 refs., 7 figs

  7. Optical emission spectroscopy of argon and hydrogen-containing plasmas

    Science.gov (United States)

    Siepa, Sarah; Danko, Stephan; Tsankov, Tsanko V.; Mussenbrock, Thomas; Czarnetzki, Uwe

    2015-09-01

    Optical emission spectroscopy (OES) on neutral argon is applied to investigate argon, hydrogen and hydrogen-silane plasmas. The spectra are analyzed using an extensive collisional-radiative model (CRM), from which the electron density and the electron temperature (or mean energy) can be calculated. The CRM also yields insight into the importance of different excited species and kinetic processes. The OES measurements are performed on pure argon plasmas at intermediate pressure. Besides, hydrogen and hydrogen-silane plasmas are investigated using argon as a trace gas. Especially for the gas mixture discharges, CRMs for low and high pressure differ substantially. The commonly used line-ratio technique is found to lose its sensitivity for gas mixture discharges at higher pressure. A solution using absolutely calibrated line intensities is proposed. The effect of radiation trapping and the shape of the electron energy distribution function on the results are discussed in detail, as they have been found to significantly influence the results. This work was supported by the Ruhr University Research School PLUS, funded by Germany's Excellence Initiative [DFG GSC 98/3].

  8. Measurement of the argon plasma temperature by use of pyrometer

    International Nuclear Information System (INIS)

    The author describes in detail how to use pyrometer to measure the plasma temperature. The temperatures of shock-generated argon plasmas are given in the present work. Measured results of temperature-pressure curve are compared with calculated results using Saha-Debye-Huckel model, which are in good agreement

  9. Turbulence and transport in a magnetized argon plasma

    International Nuclear Information System (INIS)

    An experimental study on turbulence and transport in the highly ionized argon plasma of a hollow cathode discharge is described. In order to determine the plasma parameters three standard diagnostics have been used, whilst two diagnostics have been developed to study the plasma turbulence. (Auth.)

  10. Thermophysical properties of multi-shock compressed dense argon.

    Science.gov (United States)

    Chen, Q F; Zheng, J; Gu, Y J; Chen, Y L; Cai, L C; Shen, Z J

    2014-02-21

    In contrast to the single shock compression state that can be obtained directly via experimental measurements, the multi-shock compression states, however, have to be calculated with the aid of theoretical models. In order to determine experimentally the multiple shock states, a diagnostic approach with the Doppler pins system (DPS) and the pyrometer was used to probe multiple shocks in dense argon plasmas. Plasma was generated by a shock reverberation technique. The shock was produced using the flyer plate impact accelerated up to ∼6.1 km/s by a two-stage light gas gun and introduced into the plenum argon gas sample, which was pre-compressed from the environmental pressure to about 20 MPa. The time-resolved optical radiation histories were determined using a multi-wavelength channel optical transience radiance pyrometer. Simultaneously, the particle velocity profiles of the LiF window was measured with multi-DPS. The states of multi-shock compression argon plasma were determined from the measured shock velocities combining the particle velocity profiles. We performed the experiments on dense argon plasmas to determine the principal Hugonoit up to 21 GPa, the re-shock pressure up to 73 GPa, and the maximum measure pressure of the fourth shock up to 158 GPa. The results are used to validate the existing self-consistent variational theory model in the partial ionization region and create new theoretical models. PMID:24559345

  11. Thermal decomposition of Yttrium(III) isovalerate in argon

    DEFF Research Database (Denmark)

    Grivel, Jean-Claude; Yue, Zhao; Tang, Xiao;

    2016-01-01

    The thermal behaviour of yttrium(III) isovalerate (Y(C4H9CO2)3) was studied in argon by means of thermogravimetry, differential thermal analysis, FTIR-spectroscopy, hot-stage optical microscopy and X-ray diffraction with a laboratory Cu-tube source as well as with a synchrotron radiation source...

  12. Thermal decomposition of yttrium(III) valerate in argon

    DEFF Research Database (Denmark)

    Grivel, Jean-Claude; Yue, Zhao; Tang, Xiao;

    2014-01-01

    The thermal decomposition of yttrium(III) valerate (Y(C4H9CO2)3) was studied in argon by means of thermogravimetry, differential thermal analysis, IR-spectroscopy, X-ray diffraction, in-situ synchrotron diffraction and hot-stage microscopy as well as room temperature optical microscopy. Melting...

  13. Thermal decomposition of yttrium(III) hexanoate in argon

    DEFF Research Database (Denmark)

    Grivel, Jean-Claude; Suarez Guevara, Maria Josefina; Attique, Fahmida;

    2015-01-01

    The thermal decomposition of yttrium(III) hexanoate (Y(C5H11CO2)3)·xH2O in argon was studied by means of thermogravimetry, differential thermal analysis, IR-spectroscopy, X-ray diffraction at a laboratory Cu-tube source and in-situ experiments at a synchrotron radiation source as well as hot...

  14. A 2-Dimensional Fluid Model for an Argon Rf Discharge

    NARCIS (Netherlands)

    Passchier, J. D. P.; W. J. Goedheer,

    1993-01-01

    A fluid model for an argon rf discharge in a cylindrical discharge chamber is presented. The model contains the particle balances for electrons and ions and the electron energy balance. A nonzero autobias voltage is obtained by imposing the condition that the time-averaged current toward the powered

  15. Study of Liquid Argon Dopants for LHC Hadron Calorimetry

    CERN Multimedia

    2002-01-01

    Hadron calorimetry based on the Liquid Argon Ionisation Chamber technique is one of the choice techniques for LHC-experimentation. A systematic study of the effect of selected dopants on Liquid Argon (LAr) will be carried out with the aim to achieve an improvement on: \\item (i)~``Fast Liquid Argon'' search and study of dopants to increase the drift velocity. It has been already shown that CH&sub4. added at a fraction of one percent increases the drift velocity by a factor of two or more. \\item (ii)~``Compensated Liquid Argon'' search and study of dopants to increase the response to densely ionising particles, resulting in improved compensation, such as photosensitive dopants. \\end{enumerate}\\\\ \\\\ Monitoring of the parameters involved in understanding the response of a calorimeter is essential. In case of doped LAr, the charge yield, the non-saturated drift velocity and the electron lifetime in the liquid should be precisely and simultaneously monitored as they all vary with the level of dopant concentrati...

  16. LArGe. A liquid argon scintillation veto for GERDA

    International Nuclear Information System (INIS)

    LArGe is a GERDA low-background test facility to study novel background suppression methods in a low-background environment, for possible applications in the GERDA experiment. GERDA searches for the neutrinoless double-beta decay in 76Ge, by operating naked germanium detectors submersed into 65 m3 of liquid argon. Similarly, LArGe runs Ge-detectors in 1 m3 (1.4 tons) of liquid argon, which in addition is instrumented with photomultipliers to detect argon scintillation light. The light is used in anti-coincidence with the germanium detectors, to effectively suppress background events that deposit energy in the liquid argon. This work adresses the design, construction, and commissioning of LArGe. The background suppression efficiency has been studied in combination with a pulse shape discrimination (PSD) technique for various sources, which represent characteristic backgrounds to GERDA. Suppression factors of a few times 103 have been achieved. First background data of LArGe (without PSD) yield a background index of (0.12-4.6).10-2 cts/(keV.kg.y) (90% c.l.), which is at the level of the Gerda phase I design goal. Furthermore, for the first time we measure the natural 42Ar abundance (in parallel to Gerda), and have indication for the 2νββ-decay in natural germanium. (orig.)

  17. LArGe. A liquid argon scintillation veto for GERDA

    Energy Technology Data Exchange (ETDEWEB)

    Heisel, Mark

    2011-04-13

    LArGe is a GERDA low-background test facility to study novel background suppression methods in a low-background environment, for possible applications in the GERDA experiment. GERDA searches for the neutrinoless double-beta decay in {sup 76}Ge, by operating naked germanium detectors submersed into 65 m{sup 3} of liquid argon. Similarly, LArGe runs Ge-detectors in 1 m{sup 3} (1.4 tons) of liquid argon, which in addition is instrumented with photomultipliers to detect argon scintillation light. The light is used in anti-coincidence with the germanium detectors, to effectively suppress background events that deposit energy in the liquid argon. This work adresses the design, construction, and commissioning of LArGe. The background suppression efficiency has been studied in combination with a pulse shape discrimination (PSD) technique for various sources, which represent characteristic backgrounds to GERDA. Suppression factors of a few times 10{sup 3} have been achieved. First background data of LArGe (without PSD) yield a background index of (0.12-4.6).10{sup -2} cts/(keV.kg.y) (90% c.l.), which is at the level of the Gerda phase I design goal. Furthermore, for the first time we measure the natural {sup 42}Ar abundance (in parallel to Gerda), and have indication for the 2{nu}{beta}{beta}-decay in natural germanium. (orig.)

  18. Design of capsules capable of argon-filling

    International Nuclear Information System (INIS)

    The possibility of the use of polycarbosilane capsules as fuel container in inertial confinement fusion experiments was analyzed in the paper. Primary study indicates that the polycarbosilane capsules can be filled with argon by means of diffusion and possess reasonable retention time for deuterium. (author)

  19. Removal efficiency of radioactive methyl iodide on TEDA-impregnated activated carbons

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez-Garcia, C.M.; Gonzalez, J.F.; Roman, S. [Extremadura Univ., Badajoz (Spain). Dept. de Fisica Aplicada

    2011-02-15

    Activated carbons were prepared by different series of carbon dioxide and steam activation from walnut shells for their optimal use as radioactive methyl iodide adsorbents in Nuclear Plants. The knowledge of the most favourable textural characteristics of the activated carbons was possible by the previous study of the commercial activated carbon currently used for this purpose. In order to increase their methyl iodide affinity, the effect of triethylenediamine impregnation was studied at 5 and 10 wt.%. The results obtained indicated that in both cases the adsorption efficiency is markedly improved by the addition of impregnant, which allows the adsorbate uptake to occur not only by physical adsorption, via non-specific interactions (as in non-impregnated carbons) but also by the specific interaction of triethylenediamine with radioactive methyl iodide. Methyl iodide retention efficiencies up to 98.1% were achieved. (author)

  20. Kinetics and mechanism of the mercury(II)-assisted hydrolysis of methyl iodide.

    Science.gov (United States)

    Celo, Valbona; Scott, Susannah L

    2005-04-01

    The kinetics and mechanism of the reaction of aqueous Hg(II) with methyl iodide have been investigated. The overall reaction is best described as Hg(II)-assisted hydrolysis, resulting in quantitative formation of methanol and, in the presence of excess methyl iodide, ultimately, HgI2 via the intermediate HgI+. The kinetics are biexponential when methyl iodide is in excess. At 25 degrees C, the acceleration provided by Hg2+ is 7.5 times greater than that caused by HgI+, while assistance of hydrolysis was not observed for HgI2. Thus, the reactions are not catalytic in Hg(II). The kinetics are consistent with an SN2-M+ mechanism involving electrophilic attack at iodide. As expected, methylation of mercury is not a reaction pathway; traces of methylmercury(II) are artifacts of the extraction/preconcentration procedure used for methylmercury analysis.

  1. Fluorescence characteristics of 5-amino salicylic acid: An iodide recognition study

    Science.gov (United States)

    Arora, Priyanka; Suyal, Kanchan; Joshi, Neeraj K.; Joshi, Hem Chandra; Pant, Sanjay

    In this paper we report the effect of iodide on the fluorescence of 5-amino salicylic acid (5-ASA). In the absence of iodide, prominent blue green (BG) emission band at ˜465 nm (broad) is observed in aprotic solvents whereas violet (V) emission at ˜408 nm, blue green (BG) at ˜480 nm and green (G) at ˜500 nm are observed in case of protic solvents. On the addition of iodide ion (I-), the intensity of BG fluorescence is enhanced in case of aprotic solvents. On the other hand the G band is enhanced in protic solvents and decrease in the intensity of the V band is observed. The effect of hydrogen bonding as well as the interplay of neutral and ionic species is invoked to explain the observed results. The study projects the application of this system in iodide recognition in protic/aprotic environments.

  2. A Direct Transformation of Aryl Aldehydes to Benzyl Iodides Via Reductive Iodination

    Energy Technology Data Exchange (ETDEWEB)

    Ruso, Jayaraman Sembian; Rajendiran, Nagappan; Kumaran, Rajendran Senthil [Univ. of Madras, Chennai (India)

    2014-02-15

    A facile transformation of aryl aldehydes to benzyl iodides through one-pot reductive iodination is reported. This protocol displays remarkable functional group tolerance and the title compound was obtained in good to excellent yield.

  3. Conversion of an atomic to a molecular argon ion and low pressure argon relaxation

    Science.gov (United States)

    M, N. Stankov; A, P. Jovanović; V, Lj Marković; S, N. Stamenković

    2016-01-01

    The dominant process in relaxation of DC glow discharge between two plane parallel electrodes in argon at pressure 200 Pa is analyzed by measuring the breakdown time delay and by analytical and numerical models. By using the approximate analytical model it is found that the relaxation in a range from 20 to 60 ms in afterglow is dominated by ions, produced by atomic-to-molecular conversion of Ar+ ions in the first several milliseconds after the cessation of the discharge. This conversion is confirmed by the presence of double-Gaussian distribution for the formative time delay, as well as conversion maxima in a set of memory curves measured in different conditions. Finally, the numerical one-dimensional (1D) model for determining the number densities of dominant particles in stationary DC glow discharge and two-dimensional (2D) model for the relaxation are used to confirm the previous assumptions and to determine the corresponding collision and transport coefficients of dominant species and processes. Project supported by the Ministry of Education, Science and Technological Development of the Republic of Serbia (Grant No. ON171025).

  4. Observations of acoustic-wave-induced superluminescence in an argon plasma

    International Nuclear Information System (INIS)

    It is shown that in an argon discharge plasma it is possible to obtain overpopulation of certain electronic levels of atomic argon under the influence of acoustic waves. When the specified threshold is exceeded, then a superluminescence (in the form of light flashes) from the overpopulated electronic levels of atomic argon is observed

  5. 21 CFR 874.4490 - Argon laser for otology, rhinology, and laryngology.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Argon laser for otology, rhinology, and laryngology. 874.4490 Section 874.4490 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND... Argon laser for otology, rhinology, and laryngology. (a) Identification. The argon laser device for...

  6. Horseradish Peroxidase-Mediated, Iodide-Catalyzed Cascade Reaction for Plasmonic Immunoassays.

    Science.gov (United States)

    Xianyu, Yunlei; Chen, Yiping; Jiang, Xingyu

    2015-11-01

    This report outlines an enzymatic cascade reaction for signal transduction and amplification for plasmonic immunoassays by using horseradish peroxidase (HRP)-mediated aggregation of gold nanoparticles (AuNPs). HRP-catalyzed oxidation of iodide and iodide-catalyzed oxidation of cysteine is employed to modulate the plasmonic signals of AuNPs. It agrees well with the current immunoassay platforms and allows naked-eye readout with enhanced sensitivity, which holds great promise for applications in resource-constrained settings.

  7. Argon metastable dynamics and lifetimes in a direct current microdischarge

    Science.gov (United States)

    Stefanović, Ilija; Kuschel, Thomas; Schröter, Sandra; Böke, Marc

    2014-09-01

    In this paper we study the properties of a pulsed dc microdischarge with the continuous flow of argon. Argon metastable lifetimes are measured by tunable diode laser absorption spectroscopy (TDLAS) and are compared with calculated values which yield information about excitation and de-excitation processes. By increasing the gas flow-rate about 5 times from 10 to 50 sccm, the Arm lifetime increases from 1 to 5 μs due to the reduction of metastable quenching with gas impurities. Optical emission spectroscopy reveals nitrogen and water molecules as the main gas impurities. The estimated N2 density [N2] = 0.1% is too low to explain the measured metastable lifetimes. Water impurity was found to be the main de-excitation source of argon metastable atoms due to high quenching coefficients. The water impurity level of [H2O] = 0.15% to 1% is sufficient to bring calculated metastable lifetimes in line with experiments. The maximum value of water content in the discharge compared to the argon atoms is estimated to approximately 6%, due to the large surface to volume ratio of the microdischarge. The current pulse releases the water molecules from the electrode surface and they are either re-adsorbed in the time between 0.4 ms for [H2O] = 1% and 2.6 ms for [H2O] = 0.15% or pumped out of the discharge with the speed equal to the gas flow-rate. Depending on its partial pressure, the water impurity re-adsorption time is of the order of magnitude or less then the argon gas residence time.

  8. Polarization Effects in Methylammonium Lead Iodide Electronic Devices

    Science.gov (United States)

    Labram, John; Fabini, Douglas; Perry, Erin; Lehner, Anna; Wang, Hengbin; Glaudell, Anne; Wu, Guang; Evans, Hayden; Buck, David; Cotta, Robert; Echegoyen, Luis; Wudl, Fred; Seshadri, Ram; Chabinyc, Michael

    The immense success of group IV and III-V semiconductors has resulted in disruptive new photovoltaic (PV) cell technologies emerging extremely infrequently. For this reason, the recent progress in Methylammonium Lead Iodide (MAPbI3) solar cells can be viewed as a highly significant historic event. Despite the staggering recent progress made in reported power conversion efficiency (PCE), debate remains intense on the nature of the various instabilities synonymous with these devices. Using various electronic device measurements, we here present a body of experimental evidence consistent with the existence of a mobile ionic species within the MAPbI3 perovskite. Temperature-dependent transistor measurements reveal operating FET devices only below approximately 210K. This is attributed to ionic screening of the (otherwise charge-neutral) semiconductor-dielectric interface. Temperature-dependent pulsed-gate and impedance spectroscopy experiments also reveal behavior consistent with this interpretation. MAPbI3 PV cells were found to possess a PCE which decreases significantly below 210K. Combined, these set of measurements provide an interesting and consistent description of the internal processes at play within the MAPbI3 perovskite structure.

  9. Thermopower and activation energy of silver iodide based superionic materials

    International Nuclear Information System (INIS)

    Silver iodide based glasses, 60Agl-20Ag sub 2 O-20B sub 2O sub 3, 6 Agl-20Ag sub 2 O-20 MoO sub 3 and 60Agl-20Ag sub 2O-20WO sub 3, all in the mol % ratio, were prepared by rapidly quenching the melts of the chemicals in a stainless steel container; kept in a liquid nitrogen bath. The glassy nature of the as-quenched materials was confirmed by X-ray diffraction (XRD). The electrical conductivity of the glasses was measured at various temperatures ranging from 30 to 70 degree C using an impedance bridge operating in the frequency range between 40 Hz to 100 kHz. The plot of In σT versus 1000/T for each glassy material obeys Arrhenius law and the activation energy obtained is between 0.2 to 0.3 eV. Thermopower measurement was also carried out in the same temperature range as the conductivity measurement to obtain the heat of transport

  10. Chloride, bromide and iodide scintillators with europium doping

    Science.gov (United States)

    Zhuravleva, Mariya; Yang, Kan

    2014-08-26

    A halide scintillator material is disclosed where the halide may comprise chloride, bromide or iodide. The material is single-crystalline and has a composition of the general formula ABX.sub.3 where A is an alkali, B is an alkali earth and X is a halide which general composition was investigated. In particular, crystals of the formula ACa.sub.1-yEu.sub.yI.sub.3 where A=K, Rb and Cs were formed as well as crystals of the formula CsA.sub.1-yEu.sub.yX.sub.3 (where A=Ca, Sr, Ba, or a combination thereof and X=Cl, Br or I or a combination thereof) with divalent Europium doping where 0.ltoreq.y.ltoreq.1, and more particularly Eu doping has been studied at one to ten mol %. The disclosed scintillator materials are suitable for making scintillation detectors used in applications such as medical imaging and homeland security.

  11. Digermylene Oxide Stabilized Group 11 Metal Iodide Complexes.

    Science.gov (United States)

    Yadav, Dhirendra; Siwatch, Rahul Kumar; Sinhababu, Soumen; Karwasara, Surendar; Singh, Dharmendra; Rajaraman, Gopalan; Nagendran, Selvarajan

    2015-12-01

    Use of a substituted digermylene oxide as a ligand has been demonstrated through the isolation of a series of group 11 metal(I) iodide complexes. Accordingly, the reactions of digermylene oxide [{(i-Bu)2ATIGe}2O] (ATI = aminotroponiminate) (1) with CuI under different conditions afforded [({(i-Bu)2ATIGe}2O)2(Cu4I4)] (2) with a Cu4I4 octahedral core, [({(i-Bu)2ATIGe}2O)2(Cu3I3)] (3) with a Cu3I3 core, and [{(i-Bu)2ATIGe}2O(Cu2I2)(C5H5N)2] (4) with a butterfly-type Cu2I2 core. The reactions of compound 1 with AgI and AuI produced [({(i-Bu)2ATIGe}2O)2(Ag4I4)] (5) with a Ag4I4 octahedral core and [{(i-Bu)2ATIGe}2O(Au2I2)] (6) with a Au2I2 core, respectively. The presence of metallophilic interactions in these compounds is shown through the single-crystal X-ray diffraction and atom-in-molecule (AIM) studies. Preliminary photophysical studies on compound 6 are also carried out. PMID:26558406

  12. Persistent photovoltage in methylammonium lead iodide perovskite solar cells

    Directory of Open Access Journals (Sweden)

    A. Baumann

    2014-08-01

    Full Text Available We herein perform open circuit voltage decay (OCVD measurements on methylammonium lead iodide (CH3NH3PbI3 perovskite solar cells to increase the understanding of the charge carrier recombination dynamics in this emerging technology. Optically pulsed OCVD measurements are conducted on CH3NH3PbI3 solar cells and compared to results from another type of thin-film photovoltaics, namely, the two reference polymer–fullerene bulk heterojunction solar cell devices based on P3HT:PC60BM and PTB7:PC70BM blends. We observe two very different time domains of the voltage transient in the perovskite solar cell with a first drop on a short time scale that is similar to the decay in the studied organic solar cells. However, 65%–70% of the maximum photovoltage persists on much longer timescales in the perovskite solar cell than in the organic devices. In addition, we find that the recombination dynamics in all time regimes are dependent on the starting illumination intensity, which is also not observed in the organic devices. We then discuss the potential origins of these unique behaviors.

  13. Lead iodide X-ray and gamma-ray spectrometers for room and high temperature operation

    Energy Technology Data Exchange (ETDEWEB)

    Hermon, H.; James, R.B.; Cross, E. [and others

    1997-02-01

    In this study, we report on the results of the investigation of lead iodide material properties. The effectiveness of zone refining purification methods on the material purity is determined by ICP-MS and ICP-OES and correlated to the electrical and physical material properties. We show that this zone refining method is very efficient in removing impurities from lead iodide and we also determine the segregation coefficient for some of these impurities. Triple axis x- ray diffraction (TAD) analysis has been used to determine the crystalline perfection of the lead iodide after applying various cutting, etching, and fabrication methods. The soft lead iodide crystal was found to be damaged when cleaved by a razor blade, but by using a diamond wheel saw, followed by etching, the crystallinity of the material was improved, as observed by TAD. Low temperature photoluminescence also indicates an improvement in the material properties of the purified lead iodide. Electrical properties of lead iodide such as carrier mobility, were calculated based on carrier- phonon scattering. The results for the electrical properties were in good agreement with the experimental data.

  14. Critical Evaluation of Acetylthiocholine Iodide and Acetylthiocholine Chloride as Substrates for Amperometric Biosensors Based on Acetylcholinesterase

    Directory of Open Access Journals (Sweden)

    Gabriel-Lucian Radu

    2013-01-01

    Full Text Available Numerous amperometric biosensors have been developed for the fast analysis of neurotoxic insecticides based on inhibition of cholinesterase (AChE. The analytical signal is quantified by the oxidation of the thiocholine that is produced enzymatically by the hydrolysis of the acetylthiocholine pseudosubstrate. The pseudosubstrate is a cation and it is associated with chloride or iodide as corresponding anion to form a salt. The iodide salt is cheaper, but it is electrochemically active and consequently more difficult to use in electrochemical analytical devices. We investigate the possibility of using acetylthiocholine iodide as pseudosubstrate for amperometric detection. Our investigation demonstrates that operational conditions for any amperometric biosensor that use acetylthiocholine iodide must be thoroughly optimized to avoid false analytical signals or a reduced sensitivity. The working overpotential determined for different screen-printed electrodes was: carbon-nanotubes (360 mV, platinum (560 mV, gold (370 mV, based on a catalytic effect of iodide or cobalt phthalocyanine (110 mV, but with a significant reduced sensitivity in the presence of iodide anions.

  15. Experimental study of retinoic acid on improving iodide uptake in MCF-7 breast cancer cells

    Institute of Scientific and Technical Information of China (English)

    FU Hong-Liang; WU Jing-Chuan; DU Xue-Liang; LI Jia-Ning; WU Zhen; ZOU Ren-Jian

    2005-01-01

    The study aims to investigate the effect of retinoic acid on the iodide uptake of MCF-7 cells and its mechanism. The iodide uptake and expression of hNIS(human sodium/iodide symporter)mRNA in the breast cancer MCF-7 cells were compared individually before and after the intervention of all-trans retinoic acid (ATRA) with the iodide uptake assay and RT-PCR. The following results are obtained: (1) when treated with all-trans retinoic acid in the concentration of 1.0 μmol/L, the capacity of iodide uptake of MCF-7 cells reached about 1.5 times of the basal state; (2) 12 h after the intervention of 1.0 μmol/L ATRA, the hNISmRNA expression of the MCF-7 cells reached maximum. The study shows that all-trans retinoic acid has the effect to improve the iodide uptake of the MCF-7 cells and this effect may result from its up-regulation of the hNISmRNA expression.

  16. Modelling iodide – iodate speciation in atmospheric aerosol: Contributions of inorganic and organic iodine chemistry

    Directory of Open Access Journals (Sweden)

    S. Pechtl

    2007-01-01

    Full Text Available The speciation of iodine in atmospheric aerosol is currently poorly understood. Models predict negligible iodide concentrations but accumulation of iodate in aerosol, both of which is not confirmed by recent measurements. We present an updated aqueous phase iodine chemistry scheme for use in atmospheric chemistry models and discuss sensitivity studies with the marine boundary layer model MISTRA. These studies show that iodate can be reduced in acidic aerosol by inorganic reactions, i.e., iodate does not necessarily accumulate in particles. Furthermore, the transformation of particulate iodide to volatile iodine species likely has been overestimated in previous model studies due to negligence of collision-induced upper limits for the reaction rates. However, inorganic reaction cycles still do not seem to be sufficient to reproduce the observed range of iodide – iodate speciation in atmospheric aerosol. Therefore, we also investigate the effects of the recently suggested reaction of HOI with dissolved organic matter to produce iodide. If this reaction is fast enough to compete with the inorganic mechanism, it would not only directly lead to enhanced iodide concentrations but, indirectly via speed-up of the inorganic iodate reduction cycles, also to a decrease in iodate concentrations. Hence, according to our model studies, organic iodine chemistry, combined with inorganic reaction cycles, is able to reproduce observations. The presented chemistry cycles are highly dependent on pH and thus offer an explanation for the large observed variability of the iodide – iodate speciation in atmospheric aerosol.

  17. A selective iodide ion sensor electrode based on functionalized ZnO nanotubes.

    Science.gov (United States)

    Ibupoto, Zafar Hussain; Khun, Kimleang; Willander, Magnus

    2013-01-01

    In this research work, ZnO nanotubes were fabricated on a gold coated glass substrate through chemical etching by the aqueous chemical growth method. For the first time a nanostructure-based iodide ion selective electrode was developed. The ZnO nanotubes were functionalized with miconazole ion exchanger and the electromotive force (EMF) was measured by the potentiometric method. The iodide ion sensor exhibited a linear response over a wide range of concentrations (1 × 10-6 to 1 × 10-1 M) and excellent sensitivity of -62 ± 1 mV/decade. The detection limit of the proposed sensor was found to be 5 × 10-7 M. The effects of pH, temperature, additive, plasticizer and stabilizer on the potential response of iodide ion selective electrode were also studied. The proposed iodide ion sensor demonstrated a fast response time of less than 5 s and high selectivity against common organic and the inorganic anions. All the obtained results revealed that the iodide ion sensor based on functionalized ZnO nanotubes may be used for the detection of iodide ion in environmental water samples, pharmaceutical products and other real samples. PMID:23385412

  18. A Selective Iodide Ion Sensor Electrode Based on Functionalized ZnO Nanotubes

    Directory of Open Access Journals (Sweden)

    Magnus Willander

    2013-02-01

    Full Text Available In this research work, ZnO nanotubes were fabricated on a gold coated glass substrate through chemical etching by the aqueous chemical growth method. For the first time a nanostructure-based iodide ion selective electrode was developed. The ZnO nanotubes were functionalized with miconazole ion exchanger and the electromotive force (EMF was measured by the potentiometric method. The iodide ion sensor exhibited a linear response over a wide range of concentrations (1 × 10−6 to 1 × 10−1 M and excellent sensitivity of –62 ± 1 mV/decade. The detection limit of the proposed sensor was found to be 5 × 10−7 M. The effects of pH, temperature, additive, plasticizer and stabilizer on the potential response of iodide ion selective electrode were also studied. The proposed iodide ion sensor demonstrated a fast response time of less than 5 s and high selectivity against common organic and the inorganic anions. All the obtained results revealed that the iodide ion sensor based on functionalized ZnO nanotubes may be used for the detection of iodide ion in environmental water samples, pharmaceutical products and other real samples.

  19. The effect of elemental and hydrocarbon impurities on mercuric iodide gamma ray detector performance

    Science.gov (United States)

    Cross, Eilene S.; Buffleben, George; Soria, Ed; James, Ralph; Schieber, Michael; Natarajan, Raj; Gerrish, Vern

    Mercuric iodide is a room temperature semiconductor material that is used for gamma ray and x-ray radiation detection. Mercuric iodide is synthesized from mercuric chloride and potassium iodide and is then purified by a series of melts and sublimation steps and by zone refining. The mercuric iodide is grown into crystals and platelets and then fabricated into detectors. Elemental contamination may be a determining factor in the performance of these detectors. These contaminates may be present in the starting material or may be introduced during, or be unaffected by, the purification, growth or fabrication steps. Methods have been developed for the analysis of trace levels of elemental contamination. Inductively Coupled Plasma/Mass Spectroscopy (ICP/MS), Inductively Coupled Plasma/Optical Emission Spectroscopy (ICP/OES) and Gas Chromatography/Mass Spectroscopy (GC/MS) are used to determine sub ppm levels of many trace elemental impurities. Trace levels of many elemental impurities in the raw mercuric iodide are significantly reduced during the purification and zone refining processes. Though the levels of impurities are reduced, poor performing mercuric iodide detectors have contamination levels remaining or reintroduced which are higher for Ag, Al, Ca, Cu, Mg, Mn, Na, Pb and Zn than detectors with good gamma ray response. This paper will discuss the analytical methodology, the effects of purification on impurity levels, and the correlation between detector performance and impurity levels.

  20. EFFECTS OF ARGON ON THE PROPERTIES OF RF SPUTTERED AMORPHOUS SILICON

    OpenAIRE

    Shao-Qi, Peng; Qai, Yu; Xian, Zhang; Jing, Ye

    1981-01-01

    The Effects of argon on the properties of rf sputtered amorphous silicon film have been investigated. As the sputtering argon pressure is increased from 2 to 20 mTorr, the content of argon in the amorphous silicon film increases apparently (Argon/Silicon : from 10-2 to 5 x 10-2). The other properties measured as a function of argon pressure PAr show that as the PAr is increased, the photoconductivity, resistivity (300K), conductivity activation energy and optical gap increase also, while the ...

  1. A glucose bio-battery prototype based on a GDH/poly(methylene blue) bioanode and a graphite cathode with an iodide/tri-iodide redox couple.

    Science.gov (United States)

    Wang, Jen-Yuan; Nien, Po-Chin; Chen, Chien-Hsiao; Chen, Lin-Chi; Ho, Kuo-Chuan

    2012-07-01

    A glucose bio-battery prototype independent of oxygen is proposed based on a glucose dehydrogenase (GDH) bioanode and a graphite cathode with an iodide/tri-iodide redox couple. At the bioanode, a NADH electrocatalyst, poly(methylene blue) (PMB), which can be easily grown on the electrode (screen-printed carbon paste electrode, SPCE) by electrodeposition, is harnessed and engineered. We find that carboxylated multi-walled carbon nanotubes (MWCNTs) are capable of significantly increasing the deposition amount of PMB and thus enhancing the PMB's electrocatalysis of NADH oxidation and the glucose bio-battery's performance. The choice of the iodide/tri-iodide redox couple eliminates the dependence of oxygen for this bio-battery, thus enabling the bio-battery with a constant current-output feature similar to that of the solar cells. The present glucose bio-battery prototype can attain a maximum power density of 2.4 μW/cm(2) at 25 °C. PMID:22541949

  2. Characterization of strontium iodide scintillators with silicon photomultipliers

    Science.gov (United States)

    Mitchell, Lee J.; Phlips, Bernard

    2016-06-01

    This work characterizes a commercially available europium-doped strontium iodide detector recently developed by Radiation Monitoring Devices (RMD). The detector has been chosen for a space-based mission scheduled to launch in early 2017. The primary goal of this work was to characterize the detector's response over the expected operational range of -10 °C to 30 °C as well as the expected operational voltage range of +26.5-+28.5 V and identify background interferences that may develop due to neutron activation produced by cosmic-ray interactions. The 8 mm×8 mm×20 mm detectors use KETEK silicon photomultipliers (SiPM), with an active area of 6 mmx6 mm (KETEK PM6660). Our results show substantial integral nonlinearity due to the SiPM ranging from 0% to 25% at room temperature over the energy range of 80-2614 keV. The nonlinearity, a function of temperature and overvoltage, leads to an underestimate of the full width at half max (FWHM), which is 2.6% uncorrected at 662 keV and 3.8% corrected at 662 keV. The temperature dependence of the detector results in a noise threshold that increases substantially above 30 °C due to the SiPM dark rate. In an effort to simulate the harsh environment of space, neutron activation of the detector was also explored. Gamma-ray lines at 127 keV and 164 keV were observed in the detector along with Kα x-rays associated with europium. Beta decay from europium- and iodine-activation products were also observed within the detector.

  3. THERAPY OF GRAVES’ DISEASE WITH SODIUM IODIDE-131

    Directory of Open Access Journals (Sweden)

    I Wayan Hartadi Noor

    2013-11-01

    Full Text Available Normal 0 false false false EN-US X-NONE X-NONE MicrosoftInternetExplorer4 Graves’ disease is the most common form of thyrotoxicosis, with a peak incidence in the 20-40 year of age group. Females are involved about five times more commonly than male. The easiest sign to recognize patients with Graves’ disease is the present of Graves’ ophthalmopathy. The diagnosis of Graves’ disease may sometimes base only on a physical examination and a medical history. Diffuse thyroid enlargement and sign of thyrotoxicosis, mainly ophthalmopathy and to lesser extent dermopathy, usually adequate for diagnosis. TSH test combined with FT4 test is usually the first laboratory test performs in these patients. The patients suffered Graves’ disease can be treated with antithyroid drug therapy or undergo subtotal Thyroidectomy. Another therapy is by using sodium iodide-131, where this therapy has advantages including easy administration, effectiveness, low expense, and absence of pain. /* Style Definitions */ table.MsoNormalTable {mso-style-name:"Table Normal"; mso-tstyle-rowband-size:0; mso-tstyle-colband-size:0; mso-style-noshow:yes; mso-style-priority:99; mso-style-qformat:yes; mso-style-parent:""; mso-padding-alt:0in 5.4pt 0in 5.4pt; mso-para-margin:0in; mso-para-margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:11.0pt; font-family:"Calibri","sans-serif"; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:"Times New Roman"; mso-fareast-theme-font:minor-fareast; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-bidi-font-family:"Times New Roman"; mso-bidi-theme-font:minor-bidi;}

  4. Imaging with polycrystalline mercuric iodide detectors using VLSI readout

    Energy Technology Data Exchange (ETDEWEB)

    Turchetta, R.; Dulinski, W.; Husson, D.; Riester, J.L.; Schieber, M.; Zuck, A.; Melekhov, L.; Saado, Y.; Hermon, H.; Nissenbaum, J

    1999-06-01

    Potentially low cost and large area polycrystalline mercuric iodide room-temperature radiation detectors, with thickness of 100-600 {mu}m have been successfully tested with dedicated low-noise, low-power mixed signal VLSI electronics which can be used for compact, imaging solutions. The detectors are fabricated by depositing HgI{sub 2} directly on an insulating substrate having electrodes in the form of microstrips and pixels with an upper continuous electrode. The deposition is made either by direct evaporation or by screen printing HgI{sub 2} mixed with glue such as Poly-Vinyl-Butiral. The properties of these first-generation detectors are quite uniform from one detector to another. Also for each single detector the response is quite uniform and no charge loss in the inter-electrode space have been detected. Because of the low cost and of the polycrystallinity, detectors can be potentially fabricated in any size and shape, using standard ceramic technology equipment, which is an attractive feature where low cost and large area applications are needed. The detectors which act as radiation counters have been tested with a beta source as well as in a high-energy beam of 100 GeV muons at CERN, connected to VLSI, low noise electronics. Charge collection efficiency and uniformity have been studied. The charge is efficiently collected even in the space between strips indicating that fill factors of 100% could be reached in imaging applications with direct detection of radiation. Single photon counting capability is reached with VLSI electronics. These results show the potential of this material for applications demanding position sensitive, radiation resistant, room-temperature operating radiation detectors, where position resolution is essential, as it can be found in some applications in high-energy physics, nuclear medicine and astrophysics.

  5. Narrow spectral width laser diode for metastable argon atoms pumping

    Science.gov (United States)

    Gao, Jun; Li, Bin; Wang, Xinbing; Zuo, Duluo

    2016-03-01

    Diode laser pump source with narrow emitting spectrum for optically pumped metastable rare gas laser (OPRGL) of argon was achieved by employing a complex external cavity coupled with volume Bragg grating (VBG). A commercially available c-mount laser diode with rated power of 6 W was used and studied in both the free running mode and VBG external cavity. The maximum output power of 3.9 W with FWHM less than 25 pm and peak wavelength locked around 811.53 nm was obtained from the VBG external cavity laser diode. Precise control of VBG temperature enabled fine tuning of the emission wavelength over a range of 450 pm. Future researches on OPRGL of argon will benefit from it.

  6. Evaporation and condensation at a liquid surface. I. Argon

    Science.gov (United States)

    Yasuoka, Kenji; Matsumoto, Mitsuhiro; Kataoka, Yosuke

    1994-11-01

    Molecular dynamics computer simulations were carried out to investigate the dynamics of evaporation and condensation for argon at the temperature of 80 and 100 K. From the decrease of the survival probability of vapor molecules, the ratio of self reflection to collision is estimated to be 12%-15%, only weakly dependent on the temperature. This suggests that argon vapor molecules are in the condition of almost complete capture, and the condensation is considered to be a barrierless process. The total ratio of reflection which is evaluated with the flux correlation of condensation and evaporation is 20% at both temperature. The difference between these two ratios of reflection is ascribed to a phenomenon that vapor molecules colliding with the surface drive out other liquid molecules. This molecule exchange at the surface is as important as the self-reflection, and the conventional picture of condensation as a unimolecular chemical reaction is not appropriate.

  7. The Erosion of Frozen Argon by Swift Helium Ions

    DEFF Research Database (Denmark)

    Besenbacher, F.; Bøttiger, Jørgen; Graversen, O.;

    1981-01-01

    The temperature, energy, and thickness dependence of the erosion rates of frozen argon films when irradiated with 0.1–3 MeV helium ions have been measured. The erosion yields Y are much too high to be explained by the concentional collisional cascade-sputtering theory and are furthermore unequivo......The temperature, energy, and thickness dependence of the erosion rates of frozen argon films when irradiated with 0.1–3 MeV helium ions have been measured. The erosion yields Y are much too high to be explained by the concentional collisional cascade-sputtering theory and are furthermore...... unequivocally associated with electronic processes generated by the bombarding particle. In the present energy region, it is found that Y scales approximately as the electronic stopping power squared, depends on the charge state of the incoming helium ions, and perhaps more important, is independent...

  8. Demonstration of a Lightguide Detector for Liquid Argon TPCs

    CERN Document Server

    Bugel, L; Ignarra, C; Jones, B J P; Katori, T; Smidt, T; Tanaka, H -K

    2011-01-01

    We report demonstration of light detection in liquid argon using an acrylic lightguide detector system. This opens the opportunity for development of an inexpensive, large-area light collection system for large liquid argon time projection chambers. The guides are constructed of acrylic, with TPB embedded in a surface coating with a matching index of refraction. We study the response to early scintillation light produced by a 5.3 MeV alpha. We measure coating responses from 7 to 8 PE on average, compared to an ideal expectation of 10 PE on average. We estimate the attenuation length of light along the lightguide bar to be greater than 0.5 m. The coating response and the attenuation length can be improved; we show, however, that these results are already sufficient for triggering in a large detector.

  9. Trimming a Metallic Biliary Stent Using an Argon Plasma Coagulator

    International Nuclear Information System (INIS)

    Background. Distal migration is one of the common complications after insertion of a covered metallic stent. Stent repositioning or removal is not always possible in every patient. Therefore, trimming using an argon plasma coagulator (APC) may be a good alternative method to solve this problem. Methods. Metallic stent trimming by APC was performed in 2 patients with biliary Wallstent migration and in another patient with esophageal Ultraflex stent migration. The power setting was 60-100 watts with an argon flow of 0.8 l/min. Observations. The procedure was successfully performed and all distal parts of the stents were removed. No significant collateral damage to the nearby mucosa was observed. Conclusions. In a patient with a distally migrated metallic stent, trimming of the stent is possible by means of an APC. This new method may be applicable to other sites of metallic stent migration

  10. Readiness of the ATLAS Liquid Argon Calorimeter for LHC Collisions

    CERN Document Server

    Aad, G; Abdallah, J; Abdelalim, A A; Abdesselam, A; Abdinov, O; Abi, B; Abolins, M; Abramowicz, H; Abreu, H; Acharya, B S; Adams, D L; Addy, T N; Adelman, J; Adorisio, C; Adragna, P; Adye, T; Aefsky, S; Aguilar-Saavedra, J A; Aharrouche, M; Ahlen, S P; Ahles, F; Ahmad, A; Ahmed, H; Ahsan, M; Aielli, G; Akdogan, T; Åkesson, T P A; Akimoto, G; Akimov, A V; Aktas, A; Alam, M S; Alam, M A; Albert, J; Albrand, S; Aleksa, M; Aleksandrov, I N; Alessandria, F; Alexa, C; Alexander, G; Alexandre, G; Alexopoulos, T; Alhroob, M; Aliev, M; Alimonti, G; Alison, J; Aliyev, M; Allport, P P; Allwood-Spiers, S E; Almond, J; Aloisio, A; Alon, R; Alonso, A; Alviggi, M G; Amako, K; Amelung, C; Ammosov, V V; Amorim, A; Amorós, G; Amram, N; Anastopoulos, C; Andeen, T; Anders, C F; Anderson, K J; Andreazza, A; Andrei, V; Anduaga, X S; Angerami, A; Anghinolfi, F; Anjos, N; Antonaki, A; Antonelli, M; Antonelli, S; Antunovic, B; Anulli, F; Aoun, S; Arabidze, G; Aracena, I; Arai, Y; Arce, A T H; Archambault, J P; Arfaoui, S; Arguin, J-F; Argyropoulos, T; Arik, E; Arik, M; Armbruster, A J; Arnaez, O; Arnault, C; Artamonov, A; Arutinov, D; Asai, M; Asai, S; Asfandiyarov, R; Ask, S; Åsman, B; Asner, D; Asquith, L; Assamagan, K; Astbury, A; Astvatsatourov, A; Atoian, G; Auerbach, B; Auge, E; Augsten, K; Aurousseau, M; Austin, N; Avolio, G; Avramidou, R; Axen, D; Ay, C; Azuelos, G; Azuma, Y; Baak, M A; Baccaglioni, G; Bacci, C; Bach, A; Bachacou, H; Bachas, K; Backes, M; Badescu, E; Bagnaia, P; Bai, Y; Bailey, D C; Bain, T; Baines, J T; Baker, O K; Baker, M D; Baltasar Dos Santos Pedrosa, F; Banas, E; Banerjee, P; Banerjee, S; Banfi, D; Bangert, A; Bansal, V; Baranov, S P; Baranov, S; Barashkou, A; Barber, T; Barberio, E L; Barberis, D; Barbero, M; Bardin, D Y; Barillari, T; Barisonzi, M; Barklow, T; Barlow, N; Barnett, B M; Barnett, R M; Baron, S; Baroncelli, A; Barr, A J; Barreiro, F; BarreiroGuimarães da Costa, J; Barrillon, P; Barros, N; Bartoldus, R; Bartsch, D; Bastos, J; Bates, R L; Bathe, S; 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Roa-Romero, D A; Robertson, S H; Robichaud-Veronneau, A; Robinson, D; Robinson, M; Robson, A; Rocha de Lima, J G; Roda, C; Rodriguez, D; Rodriguez Garcia, Y; Roe, S; Røhne, O; Rojo, V; Rolli, S; Romaniouk, A; Romanov, V M; Romeo, G; Romero-Maltrana, D; Roos, L; Ros, E; Rosati, S; Rosenbaum, G A; Rosenberg, E I; Rosselet, L; Rossi, L P; Rotaru, M; Rothberg, J; Rottländer, I; Rousseau, D; Royon, C R; Rozanov, A; Rozen, Y; Ruan, X; Ruckert, B; Ruckstuhl, N; Rud, V I; Rudolph, G; Rühr, F; Ruggieri, F; Ruiz-Martinez, A; Rumyantsev, L; Rusakovich, N A; Rutherfoord, J P; Ruwiedel, C; Ruzicka, P; Ryabov, Y F; Ryadovikov, V; Ryan, P; Rybkin, G; Rzaeva, S; Saavedra, A F; Sadrozinski, H F-W; Sadykov, R; Sakamoto, H; Salamanna, G; Salamon, A; Saleem, M; Salihagic, D; Salnikov, A; Salt, J; Salvachua-Ferrando, B M; Salvatore, D; Salvatore, F; Salvucci, A; Salzburger, A; Sampsonidis, D; Samset, B H; Sanchis Lozano, M A; Sandaker, H; Sander, H G; Sanders, M P; Sandhoff, M; Sandstroem, R; Sandvoss, S; Sankey, D P C; Sanny, B; Sansoni, A; Santamarina Rios, C; Santi, L; Santoni, C; Santonico, R; Santos, D; Santos, J; Saraiva, J G; Sarangi, T; Sarkisyan-Grinbaum, E; Sarri, F; Sasaki, O; Sasaki, T; Sasao, N; Satsounkevitch, I; Sauvage, G; Savard, P; Savine, A Y; Savinov, V; Sawyer, L; Saxon, D H; Says, L P; Sbarra, C; Sbrizzi, A; Scannicchio, D A; Schaarschmidt, J; Schacht, P; Schäfer, U; Schaetzel, S; Schaffer, A C; Schaile, D; Schamberger, R D; Schamov, A G; Schegelsky, V A; Scheirich, D; Schernau, M; Scherzer, M I; Schiavi, C; Schieck, J; Schioppa, M; Schlenker, S; Schlereth, J L; Schmid, P; Schmidt, M P; Schmieden, K; Schmitt, C; Schmitz, M; Schott, M; Schouten, D; Schovancova, J; Schram, M; Schreiner, A; Schroeder, C; Schroer, N; Schroers, M; Schuler, G; Schultes, J; Schultz-Coulon, H-C; Schumacher, J; Schumacher, M; Schumm, B A; Schune, Ph; Schwanenberger, C; Schwartzman, A; Schwemling, Ph; Schwienhorst, R; Schwierz, R; Schwindling, J; Scott, W G; Searcy, J; Sedykh, E; Segura, E; Seidel, S C; Seiden, A; Seifert, F; Seixas, J M; Sekhniaidze, G; Seliverstov, D M; Sellden, B; Seman, M; Semprini-Cesari, N; Serfon, C; Serin, L; Seuster, R; Severini, H; Sevior, M E; Sfyrla, A; Shamim, M; Shan, L Y; Shank, J T; Shao, Q T; Shapiro, M; Shatalov, P B; Shaver, L; Shaw, C; Shaw, K; Sherman, D; Sherwood, P; Shibata, A; Shimojima, M; Shin, T; Shmeleva, A; Shochet, M J; Shupe, M A; Sicho, P; Sidoti, A; Siebel, A; Siegert, F; Siegrist, J; Sijacki, Dj; Silbert, O; Silva, J; Silver, Y; Silverstein, D; Silverstein, S B; Simak, V; Simic, Lj; Simion, S; Simmons, B; Simonyan, M; Sinervo, P; Sinev, N B; Sipica, V; Siragusa, G; Sisakyan, A N; Sivoklokov, S Yu; Sjoelin, J; Sjursen, T B; Skubic, P; Skvorodnev, N; Slater, M; Slavicek, T; Sliwa, K; Sloper, J; Sluka, T; Smakhtin, V; Smirnov, S Yu; Smirnov, Y; Smirnova, L N; Smirnova, O; Smith, B C; Smith, D; Smith, K M; Smizanska, M; Smolek, K; Snesarev, A A; Snow, S W; Snow, J; Snuverink, J; Snyder, S; Soares, M; Sobie, R; Sodomka, J; Soffer, A; Solans, C A; Solar, M; Solfaroli-Camillocci, E; Solodkov, A A; Solovyanov, O V; Soluk, R; Sondericker, J; Sopko, V; Sopko, B; Sosebee, M; Sosnovtsev, V V; Sospedra-Suay, L; Soukharev, A; Spagnolo, S; Spanò, F; Speckmayer, P; Spencer, E; Spighi, R; Spigo, G; Spila, F; Spiwoks, R; Spousta, M; Spreitzer, T; Spurlock, B; St Denis, R D; Stahl, T; Stamen, R; Stancu, S N; Stanecka, E; Stanek, R W; Stanescu, C; Stapnes, S; Starchenko, E A; Stark, J; Staroba, P; Starovoitov, P; Stastny, J; Staude, A; Stavina, P; Stavropoulos, G; Steinbach, P; Steinberg, P; Stekl, I; Stelzer, B; Stelzer, H J; Stelzer-Chilton, O; Stenzel, H; Stevenson, K; Stewart, G; Stockton, M C; Stoerig, K; Stoicea, G; Stonjek, S; Strachota, P; Stradling, A; Straessner, A; Strandberg, J; Strandberg, S; Strandlie, A; Strauss, M; Strizenec, P; Ströhmer, R; Strom, D M; Strong, J A; Stroynowski, R; Strube, J; Stugu, B; Stumer, I; Soh, D A; Su, D; Suchkov, S I; Sugaya, Y; Sugimoto, T; Suhr, C; Suk, M; Sulin, V V; Sultansoy, S; Sumida, T; Sun, X; Sundermann, J E; Suruliz, K; Sushkov, S; Susinno, G; Sutton, M R; Suzuki, T; Suzuki, Y; Sviridov, Yu M; Sykora, I; Sykora, T; Szymocha, T; Sánchez, J; Ta, D; Tackmann, K; Taffard, A; Tafirout, R; Taga, A; Takahashi, Y; Takai, H; Takashima, R; Takeda, H; Takeshita, T; Talby, M; Talyshev, A; Tamsett, M C; Tanaka, J; Tanaka, R; Tanaka, S; Tanaka, S; Tappern, G P; Tapprogge, S; Tardif, D; Tarem, S; Tarrade, F; Tartarelli, G F; Tas, P; Tasevsky, M; Tassi, E; Taylor, C; Taylor, F E; Taylor, G N; Taylor, R P; Taylor, W; Teixeira-Dias, P; Ten Kate, H; Teng, P K; Terada, S; Terashi, K; Terron, J; Terwort, M; Testa, M; Teuscher, R J; Tevlin, C M; Thadome, J; Thananuwong, R; Thioye, M; Thoma, S; Thomas, J P; Thomas, T L; Thompson, E N; Thompson, P D; Thompson, P D; Thompson, R J; Thompson, A S; Thomson, E; Thun, R P; Tic, T; Tikhomirov, V O; Tikhonov, Y A; Timmermans, C J W P; Tipton, P; Tique-Aires-Viegas, F J; Tisserant, S; Tobias, J; Toczek, B; Todorov, T; Todorova-Nova, S; Toggerson, B; Tojo, J; Tokár, S; Tokushuku, K; Tollefson, K; Tomasek, L; Tomasek, M; Tomasz, F; Tomoto, M; Tompkins, D; Tompkins, L; Toms, K; Tong, G; Tonoyan, A; Topfel, C; Topilin, N D; Torrence, E; Torró Pastor, E; Toth, J; Touchard, F; Tovey, D R; Tovey, S N; Trefzger, T; Tremblet, L; Tricoli, A; Trigger, I M; Trincaz-Duvoid, S; Trinh, T N; Tripiana, M F; Triplett, N; Trivedi, A; Trocmé, B; Troncon, C; Trzupek, A; Tsarouchas, C; Tseng, J C-L; Tsiafis, I; Tsiakiris, M; Tsiareshka, P V; Tsionou, D; Tsipolitis, G; Tsiskaridze, V; Tskhadadze, E G; Tsukerman, I I; Tsulaia, V; Tsung, J-W; Tsuno, S; Tsybychev, D; Turala, M; Turecek, D; Turk Cakir, I; Turlay, E; Tuts, P M; Twomey, M S; Tylmad, M; Tyndel, M; Tzanakos, G; Uchida, K; Ueda, I; Uhlenbrock, M; Uhrmacher, M; Ukegawa, F; Unal, G; Underwood, D G; Undrus, A; Unel, G; Unno, Y; Urbaniec, D; Urkovsky, E; Urquijo, P; Urrejola, P; Usai, G; Uslenghi, M; Vacavant, L; Vacek, V; Vachon, B; Vahsen, S; Valenta, J; Valente, P; Valentinetti, S; Valkar, S; Valladolid Gallego, E; Vallecorsa, S; Valls Ferrer, J A; Van Berg, R; van der Graaf, H; van der Kraaij, E; van der Poel, E; Van Der Ster, D; van Eldik, N; van Gemmeren, P; van Kesteren, Z; van Vulpen, I; Vandelli, W; Vandoni, G; Vaniachine, A; Vankov, P; Vannucci, F; Varela Rodriguez, F; Vari, R; Varnes, E W; Varouchas, D; Vartapetian, A; Varvell, K E; Vasilyeva, L; Vassilakopoulos, V I; Vazeille, F; Vegni, G; Veillet, J J; Vellidis, C; Veloso, F; Veness, R; Veneziano, S; Ventura, A; Ventura, D; Venturi, M; Venturi, N; Vercesi, V; Verducci, M; Verkerke, W; Vermeulen, J C; Vetterli, M C; Vichou, I; Vickey, T; Viehhauser, G H A; Villa, M; Villani, E G; Villaplana Perez, M; Villate, J; Vilucchi, E; Vincter, M G; Vinek, E; Vinogradov, V B; Viret, S; Virzi, J; Vitale, A; Vitells, O V; Vivarelli, I; Vives Vaques, F; Vlachos, S; Vlasak, M; Vlasov, N; Vogt, H; Vokac, P; Volpi, M; Volpini, G; von der Schmitt, H; von Loeben, J; von Radziewski, H; von Toerne, E; Vorobel, V; Vorobiev, A P; Vorwerk, V; Vos, M; Voss, R; Voss, T T; Vossebeld, J H; Vranjes, N; Vranjes Milosavljevic, M; Vrba, V; Vreeswijk, M; Vu Anh, T; Vudragovic, D; Vuillermet, R; Vukotic, I; Wagner, P; Wahlen, H; Walbersloh, J; Walder, J; Walker, R; Walkowiak, W; Wall, R; Wang, C; Wang, H; Wang, J; Wang, J C; Wang, S M; Ward, C P; Warsinsky, M; Wastie, R; Watkins, P M; Watson, A T; Watson, M F; Watts, G; Watts, S; Waugh, A T; Waugh, B M; Webel, M; Weber, J; Weber, M D; Weber, M; Weber, M S; Weber, P; Weidberg, A R; Weingarten, J; Weiser, C; Wellenstein, H; Wells, P S; Wen, M; Wenaus, T; Wendler, S; Wengler, T; Wenig, S; Wermes, N; Werner, M; Werner, P; Werth, M; Werthenbach, U; Wessels, M; Whalen, K; Wheeler-Ellis, S J; Whitaker, S P; White, A; White, M J; White, S; Whiteson, D; Whittington, D; Wicek, F; Wicke, D; Wickens, F J; Wiedenmann, W; Wielers, M; Wienemann, P; Wiglesworth, C; Wiik, L A M; Wildauer, A; Wildt, M A; Wilhelm, I; Wilkens, H G; Williams, E; Williams, H H; Willis, W; Willocq, S; Wilson, J A; Wilson, M G; Wilson, A; Wingerter-Seez, I; Winklmeier, F; Wittgen, M; Wolter, M W; Wolters, H; Wosiek, B K; Wotschack, J; Woudstra, M J; Wraight, K; Wright, C; Wright, D; Wrona, B; Wu, S L; Wu, X; Wulf, E; Xella, S; Xie, S; Xie, Y; Xu, D; Xu, N; Yamada, M; Yamamoto, A; Yamamoto, S; Yamamura, T; Yamanaka, K; Yamaoka, J; Yamazaki, T; Yamazaki, Y; Yan, Z; Yang, H; Yang, U K; Yang, Y; Yang, Z; Yao, W-M; Yao, Y; Yasu, Y; Ye, J; Ye, S; Yilmaz, M; Yoosoofmiya, R; Yorita, K; Yoshida, R; Young, C; Youssef, S P; Yu, D; Yu, J; Yu, M; Yu, X; Yuan, J; Yuan, L; Yurkewicz, A; Zaidan, R; Zaitsev, A M; Zajacova, Z; Zambrano, V; Zanello, L; Zarzhitsky, P; Zaytsev, A; Zeitnitz, C; Zeller, M; Zema, P F; Zemla, A; Zendler, C; Zenin, O; Zenis, T; Zenonos, Z; Zenz, S; Zerwas, D; Zevi della Porta, G; Zhan, Z; Zhang, H; Zhang, J; Zhang, Q; Zhang, X; Zhao, L; Zhao, T; Zhao, Z; Zhemchugov, A; Zheng, S; Zhong, J; Zhou, B; Zhou, N; Zhou, Y; Zhu, C G; Zhu, H; Zhu, Y; Zhuang, X; Zhuravlov, V; Zilka, B; Zimmermann, R; Zimmermann, S; Zimmermann, S; Ziolkowski, M; Zitoun, R; Zivkovic, L; Zmouchko, V V; Zobernig, G; Zoccoli, A; zur Nedden, M; Zutshi, V

    2010-01-01

    The ATLAS liquid argon calorimeter has been operating continuously since August 2006. At this time, only part of the calorimeter was readout, but since the beginning of 2008, all calorimeter cells have been connected to the ATLAS readout system in preparation for LHC collisions. This paper gives an overview of the liquid argon calorimeter performance measured in situ with random triggers, calibration data, cosmic muons, and LHC beam splash events. Results on the detector operation, timing performance, electronics noise, and gain stability are presented. High energy deposits from radiative cosmic muons and beam splash events allow to check the intrinsic constant term of the energy resolution. The uniformity of the electromagnetic barrel calorimeter response along eta (averaged over phi) is measured at the percent level using minimum ionizing cosmic muons. Finally, studies of electromagnetic showers from radiative muons have been used to cross-check the Monte Carlo simulation. The performance results obtained u...

  11. Breakdown voltage of metal-oxide resistors in liquid argon

    Energy Technology Data Exchange (ETDEWEB)

    Bagby, L. F. [Fermilab; Gollapinni, S. [Kansas State U.; James, C. C. [Fermilab; Jones, B. J.P. [MIT; Jostlein, H. [Fermilab; Lockwitz, S. [Fermilab; Naples, D. [Pittsburgh U.; Raaf, J. L. [Fermilab; Rameika, R. [Fermilab; Schukraft, A. [Fermilab; Strauss, T. [Bern U., LHEP; Weber, M. S. [Bern U., LHEP; Wolbers, S. A. [Fermilab

    2014-11-07

    We characterized a sample of metal-oxide resistors and measured their breakdown voltage in liquid argon by applying high voltage (HV) pulses over a 3 second period. This test mimics the situation in a HV-divider chain when a breakdown occurs and the voltage across resistors rapidly rise from the static value to much higher values. All resistors had higher breakdown voltages in liquid argon than their vendor ratings in air at room temperature. Failure modes range from full destruction to coating damage. In cases where breakdown was not catastrophic, subsequent breakdown voltages were lower in subsequent measuring runs. One resistor type withstands 131 kV pulses, the limit of the test setup.

  12. A pressurized argon gas TPC as DUNE near detector

    CERN Document Server

    Martin-Albo, J

    2016-01-01

    DUNE is a new international experiment for neutrino physics and nucleon decay searches. It will consist of two detectors, about 1300 km apart, exposed to a multi-megawatt neutrino beam that will be built at Fermilab. One of the two detectors will be installed several hundred meters downstream of the neutrino production point with the primary role of characterising the energy spectrum and composition of the beam as well as performing precision measurements of neutrino cross sections. For the design of this so-called near detector, the DUNE Collaboration is considering, among other technologies, a pressurized argon gas time projection chamber. Such a detector, thanks to its low density and low detection thresholds, would allow the detailed measurement in argon of nuclear effects at the neutrino interaction vertex, which are considered at present one of the most important sources of systematic uncertainty for neutrino oscillation measurements.

  13. Opacity measurements in shock-generated argon plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Erskine, D.

    1993-07-01

    Dense plasmas having uniform and constant density and temperature are generated by passage of a planar shock wave through gas. The opacity of the plasma is accurately measured versus wavelength by recording the risetime of emitted light. This technique is applicable to a wide variety of species and plasma conditions. Initial experiments in argon have produced plasmas with 2 eV temperatures, 0.004--0.04 g/cm{sup 3} densities, and coupling parameters {Gamma} {approximately}0.3--0.7. Measurements in visible light are compared with calculations using the HOPE code. An interesting peak in the capacity at 400 nm is observed for the first time and is identified with the 4s-5p transition in excited neutral argon atoms.

  14. Treatment of facial vascular lesions with an argon laser

    Science.gov (United States)

    Szymanczyk, Jacek; Golebiowska, Aleksandra; Michalska, I.

    1996-03-01

    Two-hundred-ninety-six patients with various vascular lesions of the face have been treated with argon laser LAK-1 in the Department of Dermatology Warsaw Medical Academy since April 1992. The diagnosis of the treated lesions was port-wine stains, multiple telangiectasiae and small, most often induced by trauma hemangioma cavernosum of the lip. Best results were achieved in the patients with small hemangiomas cavernosum of the lip and multiple telangiectasiae on the face. Cure rate in this group was 100%. In 112 port-wine stain cases fading of 50 - 75% comparing with the adjacent skin was achieved. With stress, the argon laser therapy is a method of choice for the treatment of hemangioma cavernosum, port-wine stains and multiple teleagiectasiae of the face.

  15. Development of cryogenic installations for large liquid argon neutrino detectors

    CERN Document Server

    Adamowski, M; Geynisman, M; Hentschel, S; Montanari, D; Nessi, M; Norris, B

    2015-01-01

    A proposal for a very large liquid argon (68,000 kg) based neutrino detector is being studied. To validate the design principles and the detector technology, and to gain experience in the development of the cryostats and the cryogenic systems needed for such large experiments, several smaller scale installations will be developed and implemented, at Fermilab and CERN. The cryogenic systems for these installations will be developed, constructed, installed and commissioned by an international engineering team. These installations shall bring the required cooling power under specific conditions to the experiments for the initial cool-down and the long term operation, and shall also guarantee the correct distribution of the cooling power within the cryostats to ensure a homogeneous temperature distribution within the cryostat itself. The cryogenic systems shall also include gaseous and liquid phase argon purification devices to be used to reach and maintain the very stringent purity requirements needed for these...

  16. Spectroscopy of Argon Excited in an Electron Beam Ion Trap

    Energy Technology Data Exchange (ETDEWEB)

    Trabert, E

    2005-04-18

    Argon is one of the gases best investigated and most widely used in plasma discharge devices for a multitude of applications that range from wavelength reference standards to controlled fusion experiments. Reviewing atomic physics and spectroscopic problems in various ionization stages of Ar, the past use and future options of employing an electron beam ion trap (EBIT) for better and more complete Ar data in the x-ray, EUV and visible spectral ranges are discussed.

  17. Influence of argon pollution on the weld surface morphology

    OpenAIRE

    Krolczyk, G.M.; Nieslony, P.; Krolczyk, J.B.; I. Samardzic; Legutko, S.; S. Hloch; Barrans, Simon; Maruda, R.W.

    2015-01-01

    In this paper the surfaces of butt welded joints in steel tubes were analyzed using an optical 3D measurement system to determine the morphology and topographic parameters. It was established that pollution of the argon shield gas with oxygen did not influence the width of the heat-affected zone. However, the composition of the shield gas significantly influenced the surface asymmetry, Ssk, and its inclination Sku. The measurement of these parameters enabled the selection of a ...

  18. STATUS OF THE ATLAS LIQUID ARGON CALORIMETER AND ITS PERFORMANCE

    CERN Document Server

    Berillari, T; The ATLAS collaboration

    2011-01-01

    The liquid argon (LAr) calorimeters are used in ATLAS for all electromagnetic and for hadron calorimetry. The LAr calorimeter system consists of an electromagnetic barrel calorimeter and two endcaps with electromagnetic, hadronic and forward calorimeters. The latest status of the detector as well as problems and solutions addressed during the last years will be presented. Aspects of operation of a large detector over a long time period will be summarized and selected topics showing the performance of the detector will be shown.

  19. Thermal decomposition of lanthanum(III) butyrate in argon atmosphere

    DEFF Research Database (Denmark)

    Grivel, Jean-Claude; Yue, Zhao; Xiao, Tang;

    2013-01-01

    The thermal decomposition of La(C3H7CO2)3·xH2O (x≈0.82) was studied in argon during heating at 5K/min. After the loss of bound H2O, the anhydrous butyrate presents at 135°C a phase transition to a mesophase, which turns to an isotropic liquid at 180°C. The decomposition of the anhydrous butyrate ...

  20. Operational performance of a large liquid argon photon calorimeter

    International Nuclear Information System (INIS)

    We describe the performance of a large (0.9x1.4 m2) liquid argon photon calorimeter in high energy experiments at Fermilab. Resolutions for π0 and electron showers, obtained under data-taking conditions, are compared with electron-beam calibration results. Exceptional spatial and time resolutions have been achieved for isolated showers (sigmasub(x,y)0 data up to 180 GeV are presented. (orig.)

  1. Unified set of atomic transition probabilities for neutral argon

    OpenAIRE

    Wiese, W.; Brault, J.; Danzmann, K.; Helbig, V.; de Kock, M

    1989-01-01

    The atomic transition probabilities and radiative lifetimes of neutral argon have been the subject of numerous experiments and calculations, but the results exhibit many discrepancies and inconsistencies. We present a unified set of atomic transition probabilities, which is consistent with essentially all recent results, albeit sometimes only after critical reanalysis. The data consistency and scale confirmation has been achieved in two ways. (i) We have carried out some lifetime–branching-ra...

  2. Monte Carlo Simulation of Argon in Nano-Space

    Institute of Scientific and Technical Information of China (English)

    CHEN Min; YANG Chun; GUO Zeng-Yuan

    2000-01-01

    Monte Carlo simulations are performed to investigate the thermodynamic properties of argon confined in nano-scale cubes constructed of graphite walls. A remarkable depression of the system pressures is observed. The simulations reveal that the length-scale of the cube, the magnitude of the interaction between the fluid and the graphite wall and the density of the fluid exhibit reasonable effects on the thermodynamic property shifts of the luid.

  3. Two dimensional condensation of argon adsorbed on lamellar halides

    International Nuclear Information System (INIS)

    Lamellar halides such as NiCl2, FeCl2, NiBr2, MnBr2, MgBr2, CdBr2, CoI2, FeI2, MnI2, CaI2 and PbI2 were sublimed in a rapid stream of dry nitrogen. The adsorption of argon on such materials shows stepped isotherms which reveal two dimensional condensations. From sets of isotherms the Helmholtz free energy, the internal energy and the entropy of the successive layers are determined. From the entropy of the first layer the role of the potential relief of the adsorbent surface on the structure of the adsorbed layer may be determined while the Helmholtz free energy reveals how the ionic character of the adsorbent governs the attractive force of adsorption. The study of the second third and fourth layers shows that their growth follows quite a different behaviour depending on whether the Van der Waals diameter of argon is greater or smaller than the distance between adjacent anions on the crystal surface. A proposition is made to account for the difference in the critical temperatures of the first and second dense layers in terms of the vibrationnal state of their respective substrate. The occurence for the maximum critical temperature observed of corresponding to a triangular layer 3% more expanded than the (111) plane of solid argon is discussed

  4. A liquid argon scintillation veto for the Gerda experiment

    Energy Technology Data Exchange (ETDEWEB)

    Wegmann, Anne [Max-Planck Institut fuer Kernphysik, Heidelberg (Germany); Collaboration: GERDA-Collaboration

    2013-07-01

    Gerda is an experiment to search for the neutrinoless double beta decay of {sup 76}Ge. Bare germanium detectors are operated in a cryostat with 65 m{sup 3} of liquid argon (LAr). To reach the aspired background index of ≤10{sup -3} cts/(keV.kg.yr) for Phase II active background-suppression techniques will be applied, including an active liquid argon veto (LAr veto). A light instrumentation of LAr installed in the LArGe test facility has demonstrated that the detection of argon scintillation light can be used to effectively suppress background events in the germanium, which simultaneously deposit energy in LAr. Based on these results, Gerda pursues several options for the light instrumentation, which have to be compatible with the stringent radiopurity requirements of the experiment and should provide a significant suppression of the background in the region of interest around Q{sub ββ} at 2039 keV. This talk gives an account of the competing design options under investigation in the Gerda collaboration. The design options using photomultiplier tubes (PMT) and silicon photomultipliers (SiPM) are discussed, together with their expected performance from Monte Carlo simulations. In addition, the progress of development is reported, along with the design criteria for light instrumentation in Gerda.

  5. A liquid argon scintillation veto for the Gerda experiment

    International Nuclear Information System (INIS)

    Gerda is an experiment to search for the neutrinoless double beta decay of 76Ge. Bare germanium detectors are operated in a cryostat with 65 m3 of liquid argon (LAr). To reach the aspired background index of ≤10-3 cts/(keV.kg.yr) for Phase II active background-suppression techniques will be applied, including an active liquid argon veto (LAr veto). A light instrumentation of LAr installed in the LArGe test facility has demonstrated that the detection of argon scintillation light can be used to effectively suppress background events in the germanium, which simultaneously deposit energy in LAr. Based on these results, Gerda pursues several options for the light instrumentation, which have to be compatible with the stringent radiopurity requirements of the experiment and should provide a significant suppression of the background in the region of interest around Qββ at 2039 keV. This talk gives an account of the competing design options under investigation in the Gerda collaboration. The design options using photomultiplier tubes (PMT) and silicon photomultipliers (SiPM) are discussed, together with their expected performance from Monte Carlo simulations. In addition, the progress of development is reported, along with the design criteria for light instrumentation in Gerda.

  6. Space-charge effects in liquid argon ionization chambers

    Science.gov (United States)

    Rutherfoord, J. P.; Walker, R. B.

    2015-03-01

    We have uniformly irradiated liquid argon ionization chambers with betas from high-activity 90Sr sources. The radiation environment is similar to that in the liquid argon calorimeters which are part of the ATLAS detector installed at CERN's Large Hadron Collider (LHC). We measured the resulting ionization current over a wide range of applied potential for two different source activities and for three different chamber gaps. These studies provide operating experience at exceptionally high ionization rates. In particular they indicate a stability at the 0.1% level for these calorimeters over years of operation at the full LHC luminosity when operated in the normal mode at an electric field E = 1.0 kV / mm. We can operate these chambers in the normal mode or in the space-charge limited regime and thereby determine the transition point between the two. This transition point is parameterized by a positive argon ion mobility of μ+ = 0.08 ± 0.02mm2 / V s at a temperature of 88.0±0.5 K and at a pressure of 1.02±0.02 bar. In the space-charge limited regime the ionization currents are degraded and show signs of instability. At the highest electric fields in our study (6.7 kV/mm) the ionization current is still slowly rising with increasing electric field.

  7. ARAPUCA a new device for liquid argon scintillation light detection

    International Nuclear Information System (INIS)

    We present a totally innovative device for the detection of liquid argon scintillation light, that has been named ARAPUCA (Argon R and D Advanced Program at UniCAmp). It is composed of a passive light collector and of active devices. The latters are standard SiPMs that operate at liquid argon temperature, while the passive collector is based on a new technology, never explored in this field before. It is a photon trap, that allows to collect light with extremely high efficiency. The total detection efficiency of the device can be tuned by modifying the ratio between the area of the active devices (SiPM) and the area of the optical window. For example, it will allow to reach a detection efficiency at the level of 1% on a surface of 50 × 50 cm2 with an active coverage of 2 × 2 cm2 (two/three large area SiPM). It is also a cheap device, since the major part of its cost is represented by the active devices. For these reason this appears to be the ideal device for scintillation light detection in large Time Projection Chambers. With appropriate modifications it can be used also in next generation Dark Matter detectors

  8. Isotopic fractionation of argon during stepwise release from shungite

    International Nuclear Information System (INIS)

    In previous attempts to determine the 40Ar/36Ar ratio in the ancient atmosphere, the only direct measurement yielding a value below the atmospheric value of today is for argon released at low temperatures from a pre-Cambrian shungite, an amorphous carbon mineral The present work confirms a low value for 40Ar/36Ar in gas released from a type I shungite at low temperatures. But quantitative scrutiny of the accompanying 38AR/36Ar ratios and the enhanced ratio of 40Ar/36Ar for the fractions released at high temperatures shows convincingly that the effect seen here is an artifact of the stepwise heating and the argon diffusion mobilized thereby. The low 40Ar/36Ar previously obtained is very likely from the same cause rather than reflecting the isotopic composition of the pre-Cambrian atmosphere. The vitreous character of and the sharp, conchoidal fractures seen in the specimens of type I shungite suggest that the substance may exhibit simple volume diffusion over macroscopic dimensions as glasses do. If so, the diffusion parameters (D infinitely = 3 x 10-4 cm2/s and E = 11 kcal/mole) obtained from the data imply rapid exchange with the atmosphere for any argon initially trapped in centimenter-thick veins of the material. (orig.)

  9. Isotopic fractionation of argon during stepwise release from shungite

    Science.gov (United States)

    Rison, W.

    1980-05-01

    It is noted that in previous attempts to determine the Ar-40/Ar-36 ratio in the ancient atmosphere, the only direct measurement yielding a value below the atmospheric value of today is for argon released at low temperatures from a pre-Cambrian shungite. In the present work, a low value for Ar-40/Ar-36 in gas released from a type I shungite at low temperatures is confirmed. Attention is given to a study of the accompanying Ar-38/Ar-36 ratios and the enhanced ratio of Ar-40/Ar-36 for the fractions released at high temperatures which shows that the effect observed is a result of the stepwise heating and the argon diffusion mobilized thereby. It is suggested that the low Ar-40/Ar-36 obtained in the past is from the same source rather than reflecting the isotropic composition of the pre-Cambrian atmosphere, and that the type I shungite may exhibit simple volume diffusion over macroscopic dimensions as glasses do. It is concluded that if this is so, the diffusion parameters obtained from the data would imply rapid exchange with the atmosphere for any argon initially trapped in the veins of the material.

  10. Tin LPP plasma control in the argon cusp source

    Science.gov (United States)

    McGeoch, Malcolm W.

    2016-03-01

    The argon cusp plasma has been introduced [1,2] for 500W class tin LPP exhaust control in view of its high power handling, predicted low tin back-scatter from a beam dump, and avoidance of hydrogen usage. The physics of tin ion control by a plasma is first discussed. Experimentally, cusp stability and exhaust disc geometry have previously been proved at full scale [2], the equivalent of 300W-500W usable EUV. Here we verify operation of the plasma barrier that maintains a high argon density next to the collector, for its protection, and a low density in the long path toward the intermediate focus, for efficiency. A pressure differential of 2Pa has been demonstrated in initial work. Other aspects of tin LPP plasma control by the cusp have now been demonstrated using tin ions from a low Hz 130mJ CO2 laser pulse onto a solid tin surface at the cusp center. Plasma is rejected at the design to match a specified exhaust power is discussed. In view of this work, argon cusp exhaust control appears to be very promising for 500W class tin LPP sources.

  11. Bacteria Inactivation Using DBD Plasma Jet in Atmospheric Pressure Argon

    Institute of Scientific and Technical Information of China (English)

    XU Guimin; ZHANG Guanjun; SHI Xingmin; MA Yue; WANG Ning; LI Yuan

    2009-01-01

    A coaxial dielectric barrier discharge plasma jet Was designed,which can be operated in atmospheric pressure argon under an intermediate frequency sinusoidal resonant power supply,and an atmospheric pressure glow-like discharge Was achieved.Two kinds of typical bacteria,i.e.,the Staphylococcus aureus(S.aurens)and Escherichia coil(E.coil),were employed to study the bacterial inactivation mechanism by means of the non-thermal plasma.The killing log value (KLV)of S.aureus reached up to 5.38 with a treatment time of 90 s and that of E.coil up to 5.36 with 60 s,respectively.According to the argon emission spectra of the plasma jet and the scanning electron microscope (SEM) images of the two bacteria before and after the plasma treatment.it is concluded that the reactive species in the argon plasma played a major role in the bacterial inactivation,while the heat,electric field and UV photons had little effect.

  12. Metal clusters on supported argon layers; Metallcluster auf dielektrischen Substraten

    Energy Technology Data Exchange (ETDEWEB)

    Faber, Bernhard

    2011-10-21

    The deposition of small sodium clusters on supported Ar(001)-surfaces is simulated. Theoretical description is achieved by a hierarchical model consisting of time-dependent DFT and molecular dynamics. The valence electrons of the sodium atoms are considered by Kohn-Sham-Scheme with self interaction correction. The interaction of argon atoms and sodium ions is described by atom-atom potentials whereas the coupling to the QM electrons is done by local pseudo-potentials. A decisive part of the model is the dynamical polarizability of the rare-gas atoms. The optional metal support is considered by the method of image charges. The influence of the forces caused by image charges and the influence of the number of argon monolayers on structure, optical response and deposition dynamics of Na{sub 6} and Na{sub 8} is investigated. There is very little influence on cluster structure and only a small shift of the cluster perpendicular to the surface. Concerning optical response the position of the Mie plasmon peak stays robust whereas the details of spectral fragmentation react very sensitively to changes. The forces caused by image charges of the metal support play only a little role with the dynamics of deposition while the thickness of the argon surface strongly influences the dissipation. (orig.)

  13. Retinoic acid induces sodium/iodide symporter gene expression and radioiodide uptake in the MCF-7 breast cancer cell line

    OpenAIRE

    Kogai, Takahiko; Schultz, James J.; Johnson, Laura S.; Huang, Min; Brent, Gregory A.

    2000-01-01

    The sodium/iodide symporter (NIS) stimulates iodide uptake in normal lactating breast, but is not known to be active in nonlactating breast or breast cancer. We studied NIS gene regulation and iodide uptake in MCF-7 cells, an estrogen receptor (ER)-positive human breast cancer cell line. All-trans retinoic acid (tRA) treatment stimulated iodide uptake in a time- and dose-dependent fashion up to ≈9.4-fold above baseline. Stimulation with selective retinoid compounds indicated that the inductio...

  14. K-Ar age of young volcanic rocks and excess argon--Binary mixing model and quantitative study of excess argon effect

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    A binary mixing model for excess argon is suggested in the note. According to this model and the data of excess argon component obtained in our experiment , a quantitative study of the effect of excess argon on real K-Ar age of young volcanic rocks is done. The result indicates that the effect of 5% excess argon component in samples on K-Ar age of the samples more than 2 Ma is less than 7.36% and can lead K-Ar age of 0.5 Ma samples to increase by 32.4%, while 1% excess argon component leads K-Ar age of 0.5 Ma samples to increase by 6.26%. Therefore, when pre-processed excess argon component is ≤1%, K-Ar age of the samples more than 0.5 Ma should be credible. On this basis we suggest a principal opinion for evaluation of previous K-Ar dating results and propose that the matrix is used to determine K-Ar age of young volcanic rocks. For the samples less than 0.2 Ma, in the case of high excess argon content, even if only 1% excess argon component exists in their matrix, it can also greatly affect their K-A age. Thus it must be careful to treat the dating result.

  15. Trapping radiodine, in the form of methyl iodide, on nuclear carbon

    Energy Technology Data Exchange (ETDEWEB)

    Nacapricha, D. [Mahidol Univ., Bangkok (Thailand); Taylor, C. [John Moores Univ., Liverpool (United Kingdom)

    1996-12-31

    Studies have been performed on potassium-iodide-impregnated charcoals of the type used in the nuclear industry for trapping radioiodine released during nuclear fission. The effects of various parameters on the trapping efficiency of methyl iodide have been investigated. A variation in particle size within a bulk charcoal caused poor precision in K value measurements because of differences in surface area, pore volume, and bed density, leading to differences in the deposition of the impregnant. Precision is improved by sieving the charcoal to a narrower size because smaller particles have a higher porosity. This finding is supported by surface area and pore measurements. Two methods of impregnation are compared by measuring K values and the deposition of potassium iodide. Charcoal impregnated by rotary evaporation exhibits both higher K values and higher potassium iodide contents than sprayed charcoal. Two designs of spraying drum are compared: a drum with helical vanes allows more efficient deposition and more uniform distribution of impregnant than a drum with axial vanes. A decrease in the K value with increasing humidity correlates with the available surface area. A similar correlation exists between water content and available pore volume. Aging of potassium-iodide-impregnated charcoal, caused by the formation of oxygen complexes on the surface, is associated with significant falls in K value. K values of charcoals also can be restored to at least their original values by heat treatment in the absence of air. 12 refs., 6 figs., 1 tab.

  16. Processes of adsorption/desorption of iodides and cadmium cations onto/from Ag(111

    Directory of Open Access Journals (Sweden)

    VLADIMIR D. JOVIĆ

    2011-02-01

    Full Text Available In this work, the adsorption/desorption processes of iodides and cadmium cations in the presence of iodides onto/from Ag(111 were investigated. It was shown that both processes were complex, characterized by several peaks on the cyclic voltammograms (CVs. By PeakFit analysis of the recorded CVs and subsequent fitting of the obtained peaks by the Frumkin adsorption isotherm, the interaction parameter (f and the Gibbs energy of adsorption (DGads for each adsorbed phase were determined. In the case of iodide adsorption, four peaks were characterized by negative values of f, indicating attractive lateral interaction between the adsorbed anions, while two of them possessed value of f < –4, indicating phase transition processes. The adsorption/desorption processes of cadmium cations (underpotential deposition – UPD of cadmium in the presence of iodide anions was characterized by two main peaks, each of them being composed of two or three peaks with negative values of f. By the analysis of charge vs. potential dependences obtained either from the CVs or current transients on potentiostatic pulses, it was concluded that adsorbed iodides did not undergo desorption during the process of Cd UPD, but became replaced by Cd ad-atoms and remained adsorbed on top of a Cd layer and/or in between Cd the ad-atoms.

  17. [Determination of iodide, thiocyanate and perchlorate ions in environmental water by two-dimensional ion chromatography].

    Science.gov (United States)

    Lin, Li; Wang, Haibo; Shi, Yali

    2013-03-01

    A procedure for the determination of iodide, thiocyanate and perchlorate ions in environmental water by two-dimensional ion chromatography has been developed. At first the iodide, thiocyanate and perchlorate ions were separated from interfering ions by a column (IonPac AS16, 250 mm x 4 mm). The iodide ion, thiocyanate and perchlorate ions were then enriched with an enrichment column (MAC-200, 80 mm x 0.75 mm). In the 2nd-dimensional chromatography, iodide thiocyanate and perchlorate ions were separated and quantified by a capillary column (IonPac AS20 Capillary, 250 mm x 0.4 mm). The linear ranges were 0.05 -100 pg/L with correlation coefficients of 0. 999 9, and the detection limits were 0. 02 - 0.05 micro gg/L. The spiked recoveries of iodide, thiocyanate and perchlorate ions were in the range of 85.1% to 100.1%. The relative standard deviations of the recoveries were 1.7% to 4.9%.

  18. Proton and iodine-127 nuclear magnetic resonance studies on the binding of iodide by lactoperoxidase

    Energy Technology Data Exchange (ETDEWEB)

    Sakurada, J.; Takahashi, S.; Shimizu, T.; Hatano, M.; Nakamura, S.; Hosoya, T.

    1987-10-06

    Interaction of an iodide ion with lactoperoxidase was studied by the use of /sup 1/H NMR, /sup 127/I NMR, and optical difference spectrum techniques. /sup 1/H NMR spectra demonstrated that a major broad hyperfine-shifted signal at about 60 ppm, which is ascribed to the heme peripheral methyl protons, was shifted toward high field by adding KI, indicating the binding of iodide to the active site of the enzyme; the dissociation constant was estimated to be 38 mM at pH 6.1. The binding was further detected by /sup 127/I NMR, showing no competition with cyanide. Both /sup 1/H NMR and /sup 127/I NMR revealed that the binding of iodide to the enzyme is facilitated by the protonation of an ionizable group with a pK/sup a/ value of 6.0-6.8, which is presumably the distal histidyl residue. Optical difference spectra showed that the binding of an aromatic donor molecule to the enzyme is slightly but distinctly affected by adding KI. On the basis of these results, it was suggested that an iodide ion binds to lactoperoxidase outside the heme crevice but at the position close enough to interact with the distal histidyl residue which possibly mediates electron transport in the iodide oxidation reaction.

  19. Alpha-lipoic acid induces sodium iodide symporter expression in TPC-1 thyroid cancer cell line

    International Nuclear Information System (INIS)

    Introduction: Patients with metastatic thyroid cancers that do not uptake iodine need effective therapeutic option. Differentiation-inducing agents have been tried to restore functional expression of sodium iodide symporter (NIS) without success. Our objective was to assess the effect of alpha-lipoic acid (ALA), known as potential antioxidant, on expression of sodium iodide symporter in thyroid cancer cells. Methods: Human thyroid cancer-derived cell lines, TPC-1, were treated with ALA, and changes in NIS mRNA and protein expression were measured. ALA's effect on NIS gene promoter was evaluated, and functional NIS expression was assessed by iodide uptake assay. Results: Treatment with ALA increased NIS mRNA expression up to ten folds of control dose-dependently after 24 h of exposure. ALA increased NIS promoter activity, and increased iodide uptake by 1.6 fold. ALA induced expression of NIS protein, but had no significant effect on the plasma membrane trafficking. ALA increased phosphorylation of CREB and nuclear translocation of pCREB, and co-treatment of ALA and trichostatin A increased iodide uptake by three folds in TPC-1 cells. Conclusions: ALA is a potential agent to increase NIS transcription in TPC-1. It could be used as an adjunctive agent to increase efficacy of radioiodine therapy if combined with a strategy to increase NIS protein trafficking to cell membrane.

  20. Roles of argon seeding in energy confinement and pedestal structure in JT-60U

    International Nuclear Information System (INIS)

    The mechanism of improving energy confinement with argon seeding at high density has been investigated in JT-60U. Better confinement is sustained at high density by argon seeding accompanied by higher core and pedestal temperatures. The electron density profiles become flatter with increasing density in conventional H-mode plasmas, whereas peaked density profiles are maintained with argon seeding. Density peaking and dilution effects lower the pedestal density at a given averaged density. The pedestal density in the argon seeded plasmas, which is lower than that in plasmas with deuterium puff, enables the pedestal temperature to be higher, whereas the increase in the pedestal pressure with argon seeding is small. High pedestal temperature is a boundary condition for high core temperature through profile stiffness, which leads to better confinement with argon seeding. The density peaking is a key factor of sustaining better confinement in argon seeded H-mode plasmas. The radiative loss power density is predominantly enhanced in the edge region by argon puff. The role of argon seeding in the pedestal characteristics has also been examined. The pedestal width becomes larger continuously with edge collisionality, but is nearly independent of the presence of argon seeding. (paper)

  1. X-ray imaging performance of structured cesium iodide scintillators.

    Science.gov (United States)

    Zhao, Wei; Ristic, Goran; Rowlands, J A

    2004-09-01

    Columnar structured cesium iodide (CsI) scintillators doped with Thallium (Tl) have been used extensively for indirect x-ray imaging detectors. The purpose of this paper is to develop a methodology for systematic investigation of the inherent imaging performance of CsI as a function of thickness and design type. The results will facilitate the optimization of CsI layer design for different x-ray imaging applications, and allow validation of physical models developed for the light channeling process in columnar CsI layers. CsI samples of different types and thicknesses were obtained from the same manufacturer. They were optimized either for light output (HL) or image resolution (HR), and the thickness ranged between 150 and 600 microns. During experimental measurements, the CsI samples were placed in direct contact with a high resolution CMOS optical sensor with a pixel pitch of 48 microns. The modulation transfer function (MTF), noise power spectrum (NPS), and detective quantum efficiency (DQE) of the detector with different CsI configurations were measured experimentally. The aperture function of the CMOS sensor was determined separately in order to estimate the MTF of CsI alone. We also measured the pulse height distribution of the light output from both the HL and HR CsI at different x-ray energies, from which the x-ray quantum efficiency, Swank factor and x-ray conversion gain were determined. Our results showed that the MTF at 5 cycles/mm for the HR type was 50% higher than for the HL. However, the HR layer produces approximately 36% less light output. The Swank factor below K-edge was 0.91 and 0.93 for the HR and HL types, respectively, thus their DQE(0) were essentially identical. The presampling MTF decreased as a function of thickness L. The universal MTF, i.e., MTF plotted as a function of the product of spatial frequency f and CsI thickness L, increased as a function of L. This indicates that the light channeling process in CsI improved the MTF of

  2. Argon-41 production and evolution at the Oregon State University TRIGA Reactor (OSTR)

    International Nuclear Information System (INIS)

    In this study, argon-41 concentrations were measured at various locations within the reactor facility to assess the accuracy of models used to predict argon-41 evolution from the reactor tank, and to determine the relationship between argon gas evolution from the tank and subsequent argon-41 concentrations throughout the reactor room. In particular, argon-41 was measured directly above the reactor tank with the reactor tank lids closed, at other accessible locations on the reactor top with the tank lids both closed and open, and at several locations on the first floor of the reactor room. These measured concentrations were then compared to values calculated using a modified argon-41 production and evolution model for TRIGA reactor tanks and ventilation values applicable to the OSTR facility. The modified model was based in part on earlier TRIGA models for argon-41 production and release, but added features which improved the agreement between predicted and measured values. The approximate dose equivalent rate due to the presence of argon-41 in reactor room air was calculated for several different locations inside the OSTR facility. These dose rates were determined using the argon-41 concentration measured at each specific location, and were subsequently converted to a predicted quarterly dose equivalent for each location based on the reactor's operating history. The predicted quarterly dose equivalent values were then compared to quarterly doses measured by film badges deployed as dose-integrating area radiation monitors at the locations of interest. The results indicate that the modified production and evolution model is able to predict argon-41 concentrations to within a factor of ten when compared to the measured data. Quarterly dose equivalents calculated from the measured argon-41 concentrations and the reactor's operating history seemed consistent with results obtained from the integrating area radiation monitors. Given the argon-41 concentrations measured

  3. Doping in mercuric iodide crystals and its influence on electronic properties and material structure

    International Nuclear Information System (INIS)

    Doping of mercuric iodide single crystals with SbI3 was studied. Three major aspects of the influence of doping were investigated: the α to β solid phase transition, the crystal structure and the semiconducting properties. A controlled doping method and a new growth technique from the melt were developed. A quantitative correlation between the antimony concentration and the charge carrier transport properties as well as the nuclear detector characteristics of HgI2 were established for the first time. In the present work the influence of various impurities (Sb, Cu, Ag, Bi) on the solid state phase transformation of mercuric iodide has been investigated. In the second part of the work a new growth method for mercuric iodide single crystals containing a controlled amount of SbI3, has been developed. In the last part of this work the influence of the presence of impurities in the crystal on the charge carrier transport properties has been investigated. (author)

  4. Quantification of propidium iodide delivery with millisecond electric pulses: A model study

    CERN Document Server

    Yu, Miao

    2014-01-01

    A model study of propidium iodide delivery with millisecond electric pulses is presented; this work is a companion of the experimental efforts by Sadik et al. [1]. Both membrane permeabilization and delivery are examined with respect to six extra-cellular conductivities. The transmembrane potential of the permeabilized regions exhibits a consistent value, which corresponds to a bifurcation point in the pore-radius-potential relation. Both the pore area density and membrane conductance increase with an increasing extra-cellular conductivity. On the other hand, the inverse correlation between propidium iodide delivery and extra-cellular conductivity as observed in the experiments is quantitatively captured by the model. This agreement confirms that this behavior is primarily mediated by electrophoretic transport during the pulse. The results suggest that electrophoresis is important even for the delivery of small molecules such as propidium iodide. The direct comparison between model prediction and experimental...

  5. Iodide retention by cinnabar (HgS) and chalcocite (Cu{sub 2}S)

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, H.L.; Balsley, S.D.; Brady, P.V.

    1995-07-01

    Sorption of iodide (I{sup {minus}}) on cinnabar (HgS) and chalcocite (Cu{sub 2}S) was examined as a function of pH at 25{degrees}C in a series of batch experiments. Calculated distribution ratios (K{sub d}) far exceed those reported for other minerals; maximal K{sub d}`s of 1375 cc/g (Cu{sub 2}S) and 3080 c/g (HgS) were observed between pH 4-5, but wre substantial at all pH`s measured (4 < pH < 10). Iodide sorption apparently occurs by the formation of an insoluble surface solid solution with exposed Hg and Cu sites. Surface solid solution formation is favored at low pH due to the lessened electrostatic repulsion of the iodide ion by the sulfide surfaces.

  6. All-Solid-State Iodide Selective Electrode for Iodimetry of Iodized Salts and Vitamin C

    Directory of Open Access Journals (Sweden)

    TIRUWORK MEQUANINT

    2012-12-01

    Full Text Available A laboratory-made all-solid state iodide selective electrode, with Ag2S-AgI coated on a graphite rod recovered from dry cell battery, was prepared according to previous procedures. The electrode’s linear response to iodide was in the concentration range of 10-6 M to 10-1 M with a slope of 56.85 mV/decade and a detection limit of 6×10-7M. Iodate recovery test for laboratory formulated iodate-iodized salt was found to be 98.6 % with a standard deviation of 1.14%. The titratability of the iodized salt solution was at least 10-200 ppm potassium iodate (6-120 ppm iodine, exhibiting distinct endpoints in the range wider than the ones set in regulatory standards and reflecting that QC monitoring in production and stability decline of iodine content upon storage can be performed with the electrode method. On the basis this potentiometric titration, the application of the laboratory-made iodide electrode (vs. a saturated calomel reference electrode was extended to the determination of iodine in commercial iodized salts. In all the iodine assays, the iodate-iodized salt was initially treated with acid and an excess of iodide before titration against Na2S2O3 solution. The iodine content in table salts iodized with iodide was determined by direct potentiometry. The electrode was further used for vitamin C (ascorbic acid determinations in pharmaceutical tablets and orange juice by back titrating excess I3- against standard Na2S2O3 in acidic media. The overall outcome is that the iodide ISE can be used as sharp endpoint indicator for these titrimetric reactions in place of the well known official, but visually monitored, starch- triodide end-point reaction detection.

  7. Modeling of Turing Structures in the Chlorite-Iodide-Malonic Acid-Starch Reaction System

    Science.gov (United States)

    Lengyel, Istivan; Epstein, Irving R.

    1991-02-01

    Recent experiments on the chlorite-iodide-malonic acid-starch reaction in a gel reactor give the first evidence of the existence of the symmetry breaking, reaction-diffusion structures predicted by Turing in 1952. A five-variable model that describes the temporal behavior of the system is reduced to a two-variable model, and its spatial behavior is analyzed. Structures have been found with wavelengths that are in good agreement with those observed experimentally. The gel plays a key role by binding key iodine species, thereby creating the necessary difference in the effective diffusion coefficients of the activator and inhibitor species, iodide and chlorite ions, respectively.

  8. Iodide uptake in human anaplastic thyroid carcinoma cells after transfer of the human thyroid peroxidase gene

    Energy Technology Data Exchange (ETDEWEB)

    Haberkom, U. [Clinical Cooperation Unit Nuclear Medicine, German Cancer Research Center, Heidelberg (Germany); Dept. of Nuclear Medicine, Univ. of Heidelberg (Germany); Altmann, A.; Jiang, S.; Morr, I.; Mahmut, M. [Clinical Cooperation Unit Nuclear Medicine, German Cancer Research Center, Heidelberg (Germany); Eisenhut, M. [Dept. of Nuclear Medicine, Univ. of Heidelberg (Germany)

    2001-05-01

    Human thyroperoxidase (hTPO) is critical for the accumulation of iodide in thyroid tissues. Poorly differentiated and anaplastic thyroid tumours which lack thyroid-specific gene expression fail to accumulate iodide and, therefore, do not respond to iodine-131 therapy. We consequently investigated whether transfer of the hTPO gene is sufficient to restore the iodide-trapping capacity in undifferentiated thyroid and non-thyroid tumour cells. The human anaplastic thyroid carcinoma cell lines C643 and SW1736, the rat Morris hepatoma cell line MH3924A and the rat papillary thyroid carcinoma cell line L2 were used as in vitro model systems. Employing a bicistronic retroviral vector based on the myeloproliferative sarcoma virus for the transfer of the hTPO and the neomycin resistance gene, the C643 cells and SW1736 cells were transfected while the L2 cells and MH3924A cells were infected with retroviral particles. Seven recombinant C643 and seven SW1736 cell lines as well as four recombinant L2 and four MH3924A cell lines were established by neomycin selection. They were studied for hTPO expression using an antibody-based luminescence kit, followed by determination of the enzyme activity in the guaiacol assay and of the iodide uptake capacity in the presence of Na{sup 125}I. Genetically modified cell lines expressed up to 1,800 times more hTPO as compared to wild type tumour cells. The level of hTPO expression varied significantly between individual neomycin-resistant cell lines, suggesting that the recombinant retroviral DNA was integrated at different sites of the cellular genome. The accumulation of iodide, however, was not significantly enhanced in individual recombinant cell lines, irrespective of low or high hTPO expression. Moreover, there was no correlation between hTPO expression and enzyme activity in individual cell lines. The transduction of the hTPO gene per se is not sufficient to restore iodide trapping in non-iodide-concentrating tumour cells. Future

  9. A Selective Iodide Ion Sensor Electrode Based on Functionalized ZnO Nanotubes

    OpenAIRE

    Magnus Willander; Zafar Hussain Ibupoto; Kimleang Khun

    2013-01-01

    In this research work, ZnO nanotubes were fabricated on a gold coated glass substrate through chemical etching by the aqueous chemical growth method. For the first time a nanostructure-based iodide ion selective electrode was developed. The ZnO nanotubes were functionalized with miconazole ion exchanger and the electromotive force (EMF) was measured by the potentiometric method. The iodide ion sensor exhibited a linear response over a wide range of concentrations (1 × 10−6 to 1 × 10−1 M) and ...

  10. Tris(1,2-dimethoxyethane-κ2O,O′iodidocalcium iodide

    Directory of Open Access Journals (Sweden)

    Siou-Wei Ou

    2012-02-01

    Full Text Available In the title complex, [CaI(C4H10O23]I, the CaII atom is seven-coordinated by six O atoms from three 1,2-dimethoxyethane (DME ligands and one iodide anion in a distorted pentagonal–bipyramidal geometry. The I atom and one of the O atoms from a DME ligand lie in the axial positions while the other O atoms lie in the basal plane. The other iodide anion is outside the complex cation.

  11. Efficiency enhancement in dye sensitized solar cells using gel polymer electrolytes based on a tetrahexylammonium iodide and MgI2 binary iodide system.

    Science.gov (United States)

    Bandara, T M W J; Dissanayake, M A K L; Jayasundara, W J M J S R; Albinsson, I; Mellander, B-E

    2012-06-28

    Quasi-solid-state dye-sensitized solar cells have drawn the attention of scientists and technologists as a potential candidate to supplement future energy needs. The conduction of iodide ions in quasi-solid-state polymer electrolytes and the performance of dye sensitized solar cells containing such electrolytes can be enhanced by incorporating iodides having appropriate cations. Gel-type electrolytes, based on PAN host polymers and mixture of salts tetrahexylammonium iodide (Hex4N(+)I(-)) and MgI2, were prepared by incorporating ethylene carbonate and propylene carbonate as plasticizers. The salt composition in the binary mixture was varied in order to optimize the performance of solar cells. The electrolyte containing 120% Hex4N(+)I(-) with respect to weight of PAN and without MgI2 showed the highest conductivity out of the compositions studied, 2.5 × 10(-3) S cm(-1) at 25 °C, and a glass transition at -102.4 °C. However, the electrolyte containing 100% Hex4N(+)I(-) and 20% MgI2 showed the best solar cell performance highlighting the influence of the cation on the performance of the cell. The predominantly ionic behaviour of the electrolytes was established from the dc polarization data and all the electrolytes exhibit iodide ion transport. Seven different solar cells were fabricated employing different electrolyte compositions. The best cell using the electrolyte with 100% Hex4N(+)I(-) and 20% MgI2 with respect to PAN weight showed 3.5% energy conversion efficiency and 8.6 mA cm(-2) short circuit current density.

  12. The effects of argon in the bioenergetics of the hamster and the rat

    Science.gov (United States)

    Tempel, G. E.; Musacchia, X. J.

    1974-01-01

    Oxygen consumption was examined in hamsters and rats exposed to normoxic mixtures of argon at 1 atm. In fasted and nonfasted animals, no marked change in O2 utilization was detectable at 22 C. However, at 7 C a significant decrease in oxygen consumption was observed where the animals were exposed in argon. The data are interpreted in terms of the greater thermal conductivity of nitrogen. The study was prompted by conflicting reports on the metabolic effects of argon and helium.

  13. Studying Equilibrium in the Chemical Reaction between Ferric and Iodide Ions in Solution Using a Simple and Inexpensive Approach

    Science.gov (United States)

    Nikolaychuk, Pavel Anatolyevich; Kuvaeva, Alyona Olegovna

    2016-01-01

    A laboratory experiment on the study of the chemical equilibrium based on the reaction between ferric and iodide ions in solution with the formation of ferrous ions, free iodine, and triiodide ions is developed. The total concentration of iodide and triiodide ions in the reaction mixture during the reaction is determined by the argentometric…

  14. Argon Laser Photoablation for Treating Benign Pigmented Conjunctival Nevi

    Science.gov (United States)

    Alsharif, Abdulrahman M.; Al-Gehedan, Saeed M.; Alasbali, Tariq; Alkuraya, Hisham S.; Lotfy, Nancy M.; Khandekar, Rajiv

    2016-01-01

    Purpose: To evaluate the outcomes of argon laser photoablation of benign conjunctival pigmented nevi with different clinical presentations. Patients and Methods: This interventional case series was conducted between July 2014 and January 2015. Patients presenting with benign conjunctival nevi were included. Data were collected on the clinical features at presentation, argon laser photoablation, and follow-up at 8 and 24 weeks. Postoperative photography allowed recording of the success of each case and the overall success rate. Complete removal of conjunctival pigments was considered an absolute success. Partial pigmentation requiring repeat laser treatment was considered a qualified success. Results: There were 14 eyes (four right eyes and ten left eyes) with benign pigmented conjunctival nevi. There were three males and eight females in the study sample. The median age was 36 (25% percentile: 26 years). Three patients had bilateral lesions. The nevi were located temporally in nine eyes, nasally in three eyes, and on the inferior bulbar conjunctiva in two eyes. The mean horizontal and vertical diameters of nevi were 5 ± 2 mm and 4 ± 2.7 mm, respectively. The mean follow-up period was 5 months. Following laser treatment, no eyes had subconjunctival hemorrhage, infection, scarring, neovascularization, recurrence, or corneal damage. The absolute success rate of laser ablation was 79%. Three eyes with elevated nevi had one to three sessions of laser ablation resulting in a qualified success rate of 100%. Conclusions: Argon laser ablation was a safe and effective treatment for the treatment of selective benign pigmented conjunctival nevi in Arab patients. PMID:27555708

  15. The abundances of neon, sulfur, and argon in planetary nebulae

    Science.gov (United States)

    Beck, S. C.; Lacy, J. H.; Townes, C. H.; Aller, L. H.; Geballe, T. R.; Baas, F.

    1981-01-01

    New infrared observations of Ne II, Ar III, and S IV are used in optical observations of other ionization states of the considered elements to evaluate the abundances of neon, argon, and sulfur in 18 planetary nebulae. Attention is also given to one or more of the infrared lines in 18 other nebulae. It is pointed out that S IV was detected in approximately 90% of the observed objects, while Ar III was found in about 80%, and Ne II in roughly one-third. It is noted that optical observations typically include only a limited region of the nebula, while the infrared measurements frequently involve integration over the entire nebular image.

  16. Ionization coefficients for argon in a micro-discharge

    International Nuclear Information System (INIS)

    Ionization coefficients are measured for electrons in a dc micro-discharge in argon from optical emission profiles. The micro-discharge is operated in the Townsend regime between two parallel-plate electrodes. Axial profiles of emission are obtained with sufficient resolution to provide spatial ionization coefficients. The measured coefficients agree very well with the data obtained from other sources, indicating the operation of the discharge in the Townsend regime and also that Townsend mechanisms do not need extension to describe such discharges. (paper)

  17. Kinetic modeling of the Townsend breakdown in argon

    Science.gov (United States)

    Macheret, S. O.; Shneider, M. N.

    2013-10-01

    Kinetic modeling of the Townsend breakdown in argon was performed in the "forward-back" approximation. The kinetic model was found to adequately describe the left branch of the Paschen curve, and the important role of ionization by fast ions and atoms near the cathode, as well as the increase in secondary emission coefficient in strong electric fields described in the literature, was confirmed. The modeling also showed that the electron energy distribution function develops a beam of high-energy electrons and that the runaway effect, i.e., the monotonic increase of the mean electron energy with the distance from the cathode, occurs at the left branch of the Paschen curve.

  18. Ionization coefficients for argon in a micro-discharge

    Science.gov (United States)

    Kuschel, Thomas; Stefanović, Ilija; Malović, Gordana; Marić, Dragana; Petrović, Zoran Lj

    2013-08-01

    Ionization coefficients are measured for electrons in a dc micro-discharge in argon from optical emission profiles. The micro-discharge is operated in the Townsend regime between two parallel-plate electrodes. Axial profiles of emission are obtained with sufficient resolution to provide spatial ionization coefficients. The measured coefficients agree very well with the data obtained from other sources, indicating the operation of the discharge in the Townsend regime and also that Townsend mechanisms do not need extension to describe such discharges.

  19. Diffusion coefficient of metal vapours into rare gases. Mercury - argon

    International Nuclear Information System (INIS)

    The source information is present as well as the results of analysis and integration of data on mutual diffusion coefficient (MDC) of mercury - argon mixture at Hg concentration → 0 in 300-2500 K temperature range. Reference data on MDC for metal - inert gas binary mixtures obtained on the base of complex analysis of various information, as it exemplified by Hg-Ar pair, can be used as a part of metrological support at calibration of devices for determination MDC of gas - metal vapors

  20. Electron drift velocity in argon-methane mixture

    International Nuclear Information System (INIS)

    Described are the results of a series of measurements of electron drift velocity taken with samples of chemically pure grade gas mixture of Ar-10% CH4 (N2222O<2 ppm). The measured drift velocity is plotted as a function of the ratio of electric field to pressure in the range from 0.05 to 0.8 V/cmxtorr. The measurements are reproducible only to within 4%. The results of numerical calculations employing the well-established argon elastic and methane elastic and inelastic cross sections are also included. The disagreement from the present experimental results, and from those obtained elsewhere, is rather puzzling

  1. High intensity, argon ion laser-jet photochemistry

    Science.gov (United States)

    Wilson, R. Marshall; Schnapp, Karlyn A.; Hannemann, Klaus; Ho, Douglas M.; Memarian, Hamid R.; Azadnia, Ardeshir; Pinhas, Allan R.; Figley, Timothy M.

    A new technique for the study of high intensity solution photochemistry has been developed. With this laser-jet technique, a high velocity microjet is irradiated with the focussed output of an argon ion laser. Under these extremely high intensity conditions, photochemically generated transient species with suitable absorption properties are excited further and produce relatively large amounts of photoproducts which are not observed under low intensity conditions. The application of this laser-jet technique in the study of the photochemistry of radicals, biradicals, photoenols and the higher excited states of carbonyl and polycyclic aromatic compounds is described.

  2. Optical fiber read-out for liquid argon scintillation light

    CERN Document Server

    Csáthy, J Janicskó; Kratz, J; Schönert, S; Wiesinger, Ch

    2016-01-01

    In this paper we describe the performance of a light detector for Ar scintillation light made of wavelength-shifting (WLS) fibers connected to Silicon-Photomultipliers (SiPM). The setup was conceived to be used as anti-Compton veto for high purity germanium (HPGe) detectors operated directly in liquid Argon (LAr). Background suppression efficiencies for different radioactive sources were measured in a test cryostat with about 800 kg LAr. This work was part of the R\\&D effort for the GERDA experiment.

  3. Study of a novel electromagnetic liquid argon calorimeter TGT

    International Nuclear Information System (INIS)

    The concept and the basic design of a fast, highly granular and compact electromagnetic liquid argon calorimeter are described. This novel calorimeter offers uniform energy response and constant energy resolution independent of the production angle of an impinging particle and of its impact position at the calorimeter. An example of a calorimeter with full rapidity coverage in an application in a collider detector is given. An important aspect of the concept is the electronics for fast signal processing matched to the short charge collection time. We report on the experience with the realization of a prototype calorimeter module and on its performance in a test beam exposure. 15 refs., 16 figs., 2 tabs

  4. Activation of copper by nitrogen and argon beams

    Energy Technology Data Exchange (ETDEWEB)

    Chetvertkova, Vera [IAP, Goethe-University, Frankfurt am Main (Germany); GSI Darmstadt (Germany); Mustafin, Edil; Strasik, Ivan [GSI Darmstadt (Germany); Belousov, Anton [TU Darmstadt (Germany); Latysheva, Ludmila; Sobolevsky, Nikolai [INR RAS, Moscow (Russian Federation); Ratzinger, Ulrich [IAP, Goethe-University, Frankfurt am Main (Germany)

    2012-07-01

    Monte Carlo transport codes are widely used for various purposes in nuclear physics, radiation protection, medical applications, accelerator design etc. Code verification by experiments is needed to be sure that the codes give accurate results. New data on the activation of copper by a nitrogen beam of 500 MeV/u is presented and compared with FLUKA and SHIELD simulation results. The activation of copper by a nitrogen beam is compared to activation by an argon beam and respective simulations. This gives a chance to see the accuracy of the codes at different projectile masses. Correspondences and discrepancies of calculations and experiments are discussed.

  5. Study of a Novel Concept for a Liquid Argon Calorimeter \

    CERN Multimedia

    2002-01-01

    % RD33 \\\\ \\\\ The development of a fast, highly granular and compact electromagnetic liquid argon calorimeter prototype is proposed as a generic R\\&D project for a novel concept of calorimetry in proton-proton and electron-positron collider detectors: the $^{\\prime$Thin Gap Turbine$^{\\prime}$ (TGT). The TGT calorimeter has a modular construction, is flexible in its longitudinal and transverse granularity, and offers a uniform energy response and resolution, independent of the production angle of incident particles. An important aspect of the project is the development of fast, radiation-hard front-end electronics which is operating in the cold.

  6. Activation of aluminum by argon: Experimental study and simulations

    Energy Technology Data Exchange (ETDEWEB)

    Chetvertkova, V., E-mail: v.chetvertkova@gsi.de [GSI Helmholtzzentrum fuer Schwerionenforschung Darmstadt, Planckstrasse 1, 64291 Darmstadt (Germany); J. W. Goethe-University Frankfurt am Main, IAP, Max-von-Laue-Strasse 1, 60438 Frankfurt am Main (Germany); Strasik, I. [GSI Helmholtzzentrum fuer Schwerionenforschung Darmstadt, Planckstrasse 1, 64291 Darmstadt (Germany); J. W. Goethe-University Frankfurt am Main, IAP, Max-von-Laue-Strasse 1, 60438 Frankfurt am Main (Germany); Belousov, A. [GSI Helmholtzzentrum fuer Schwerionenforschung Darmstadt, Planckstrasse 1, 64291 Darmstadt (Germany); Iwase, H. [High Energy Accelerator Research Organization, KEK, 1-1 Oho, Tsukuba, Ibaraki 305-0801 (Japan); Mokhov, N. [Fermi National Accelerator Laboratory, P.O. Box 500, Batavia, IL 60510 (United States); Mustafin, E. [GSI Helmholtzzentrum fuer Schwerionenforschung Darmstadt, Planckstrasse 1, 64291 Darmstadt (Germany); Latysheva, L. [Institute for Nuclear Research RAS, 117312 Moscow (Russian Federation); Pavlovic, M. [FEI STU, Ilkovicova 3, 812 19 Bratislava (Slovakia); Ratzinger, U. [J. W. Goethe-University Frankfurt am Main, IAP, Max-von-Laue-Strasse 1, 60438 Frankfurt am Main (Germany); Sobolevsky, N. [Institute for Nuclear Research RAS, 117312 Moscow (Russian Federation)

    2011-06-15

    The paper presents the results of irradiation of aluminum targets by 430 and 500 MeV/u argon beams. Gamma-spectra were measured after the end of the irradiation in order to identify the induced nuclides as well as to determine their residual activity depth-profiles. The results of this experiment are compared with Monte Carlo simulations by FLUKA, GEANT4, MARS, PHITS and SHIELD-A codes. In case of a thin target, the agreement between the experiment and simulations is satisfactory, while in case of a thick target, some discrepancies are observed.

  7. Laser-induced vibrational dynamics of ozone in solid argon

    DEFF Research Database (Denmark)

    Hansen, Flemming Yssing; Amstrup, B.; Henriksen, Niels Engholm

    1997-01-01

    We consider the vibrational dynamics, induced by an intense infrared laser pulse, in an ozone molecule with isotopic substitution, that is, (OOO)-O-16-O-16-O-18 and compare the dynamics in the gas phase and in solid ar on. not perturbed by argon on a time-scale of a few picoseconds and selective...... bond-breaking in the molecule should be possible following the same laser control scheme as suggested in the gas phase. (C) 1997 Elsevier Science B.V....

  8. Electron transport in argon in crossed electric and magnetic fields

    Science.gov (United States)

    Ness; Makabe

    2000-09-01

    An investigation of electron transport in argon in the presence of crossed electric and magnetic fields is carried out over a wide range of values of electric and magnetic field strengths. Values of mean energy, ionization rate, drift velocity, and diffusion tensor are reported here. Two unexpected phenomena arise; for certain values of electric and magnetic field we find regions where the swarm mean energy decreases with increasing electric fields for a fixed magnetic field and regions where swarm mean energy increases with increasing magnetic field for a fixed electric field. PMID:11088933

  9. Analysis of iodide and iodate in Lake Mead, Nevada using a headspace derivatization gas chromatography-mass spectrometry.

    Science.gov (United States)

    Dorman, James W; Steinberg, Spencer M

    2010-02-01

    We report here a derivatization headspace method for the analysis of inorganic iodine in water. Samples from Lake Mead, the Las Vegas Wash, and from Las Vegas tap water were examined. Lake Mead and the Las Vegas Wash contained a mixture of both iodide and iodate. The average concentration of total inorganic iodine (TII) for Lake Mead was approximately 90 nM with an iodide-to-iodate ratio of approximately 1. The TII concentration (approximately 160 nM) and the ratio of iodide to iodate were higher for the Las Vegas Wash (approximately 2). The TII concentration for tap water was close to that of Lake Mead (approximately 90 nM); however, tap water contained no detectable iodide as a result of ozonation and chlorine treatment which converts all of the iodide to iodate. PMID:19184627

  10. Iodide-induced thyrotoxicosis in a thyroidectomized patient with metastatic thyroid carcinoma

    Energy Technology Data Exchange (ETDEWEB)

    Yoshinari, M.; Tokuyama, T.; Okamura, K.; Sato, K.; Kusuda, K.; Fujishima, M.

    1988-04-15

    An unusual case of iodide-induced thyrotoxicosis is documented in this article. The patient was a 64-year-old euthyroid man with acromegaly. He also had multiple follicular and papillary thyroid carcinomas with a metastatic lesion in the lumbar vertebrae. After a total thyroidectomy, he became slightly hypothyroid, and the lumbar lesion began to incorporate /sup 131/I by scintigraphy. When an iodine-containing contrast medium happened to be injected, a transient increase of serum thyroid hormone level was observed. After complete thyroid ablation with 83 mCi of /sup 131/I, the oral administration of 100 mg of potassium iodide for 7 days induced a prominent increase of serum thyroid hormone level. These findings indicated that the metastatic thyroid carcinoma could produce excess thyroid hormone insofar as a sufficient amount of iodide was given. Although this is the first report of such a case, iodide-induced thyrotoxicosis may not be rare in patients with thyroid carcinomas because the Wolff-Chaikoff effect is thought to be lost, and the organic iodinating activity and lysosomal protease activity are well-preserved.

  11. Reductive degradation of perfluoroalkyl compounds with aquated electrons generated from iodide photolysis at 254 nm

    OpenAIRE

    Park, Hyunwoong; vecitis, Chad D.; Cheng, Jie; Dalleska, Nathan F; Mader, Brian T.; Hoffmann, Michael R.

    2011-01-01

    The perfluoroalkyl compounds (PFCs), perfluoroalkyl sulfonates (PFXS) and perfluoroalkyl carboxylates (PFXA) are environmentally persistent and recalcitrant towards most conventional water treatment technologies. Here, we complete an in depth examination of the UV-254 nm production of aquated electrons during iodide photolysis for the reductive defluorination of six aquated perfluoroalkyl compounds (PFCs) of various headgroup and perfluorocarbon tail length. Cyclic voltammograms (CV) show tha...

  12. The sodium iodide symporter (NIS) and potential regulators in normal, benign and malignant human breast tissue.

    LENUS (Irish Health Repository)

    Ryan, James

    2011-01-01

    The presence, relevance and regulation of the Sodium Iodide Symporter (NIS) in human mammary tissue remains poorly understood. This study aimed to quantify relative expression of NIS and putative regulators in human breast tissue, with relationships observed further investigated in vitro.

  13. Relaxation of the Silver/Silver Iodide Electrode in Aqueous Solution

    NARCIS (Netherlands)

    Peverelli, K.J.

    1979-01-01

    The aim of this study is to detect and characterize relaxation processes on silver/silver iodide electrodes in aqueous electrolyte solution. The information obtained is to be used for an estimation of the consequences of similar processes on colloidal AgI particles during encounter.In chapter 1 a ge

  14. LIQUID-CRYSTALLINE AND THERMOCHROMIC BEHAVIOR OF 4-SUBSTITUTED 1-METHYLPYRIDINIUM IODIDE SURFACTANTS

    NARCIS (Netherlands)

    NUSSELDER, JJH; ENGBERTS, JBFN; VANDOREN, HA

    1993-01-01

    The mesogenic behaviour of a series of thirty-one 1-alkyl-4-(or 2-)alkyl-pyridinium salts and of a homologous series of four 1-methyl-4-n-alkoxycarbonylpyridinium iodides is described. The occurrence and stability range of the thermotropic phases depend dramatically on the structure of the surfactan

  15. Theoretical calculations of primary particle condensation for cadmium and caesium iodide vapours

    International Nuclear Information System (INIS)

    This report considers a model of aerosol nucleation from the vapour phase which has been developed by Buckle. The applicability of the model has been tested by considering the condensation of caesium iodide and cadmium vapours under a wide variety of pre-mixed flow conditions of interest to PWR severe accident studies. (U.K.)

  16. Photodissociation of sodium iodide and resonant ionization of sodium atom produced

    Institute of Scientific and Technical Information of China (English)

    HUO Bing-hai; Z.T.Salim; A.H.Bakery

    2004-01-01

    Resonant ionization spectroscopy (RIS) and resonant ionization mass spectroscopy (RIMS) are employed to detect the photodissociation product of sodium iodide molecules in a molecular beam in an intense laser field in the absence of the buffer gases. Time of flight mass spectra is recorded. In particular, the appearances of multiphoton ionization are discussed.

  17. Regioselective iodination of aromatic compounds with potassium iodide in the presence of benzyltriphenylphosphonium perchlorate

    Institute of Scientific and Technical Information of China (English)

    Jalal Albadi; Masoumeh Abedini; Nasir Iravani

    2012-01-01

    A simple and efficient method for the selective iodination of various aromatic compounds by using potassium iodide in the presence of benzyltriphenylphosphonium perchlorate,is reported.This method provides several advantages such as good selectivity between ortho and para positions of aromatic compounds and high yields of the products.

  18. Kinetic modeling of the purging of activated carbon after short term methyl iodide loading

    International Nuclear Information System (INIS)

    A bimolecular reaction model containing the physico-chemical parameters of the adsorption and desorption was developed earlier to describe the kinetics of methyl iodide retention by activated carbon adsorber. Both theoretical model and experimental investigations postulated constant upstream methyl iodide concentration till the maximum break-through. The work reported here includes the extension of the theoretical model to the general case when the concentration of the challenging gas may change in time. The effect of short term loading followed by purging with air, and an impulse-like increase in upstream gas concentration has been simulated. The case of short term loading and subsequent purging has been experimentally studied to validate the model. The investigations were carried out on non-impregnated activated carbon. A 4 cm deep carbon bed had been challenged by methyl iodide for 30, 90, 120 and 180 min and then purged with air, downstream methyl iodide concentration had been measured continuously. The main characteristics of the observed downstream concentration curves (time and slope of break-through, time and amplitude of maximum values) showed acceptable agreement with those predicted by the model

  19. Ammonium-iodide route to anhydrous EuI2:mechanism and preparation

    Institute of Scientific and Technical Information of China (English)

    刁成鹏; 余金秋; 李红卫; 彭鹏; 吴浩; 何华强; 颜世宏; 胡运生

    2015-01-01

    Anhydrous EuI2 is an essential raw material for novel Eu2+-doped halide scintillators such as SrI2:Eu, CsBa2I5:Eu and BaBrI:Eu. An efficient and economic method to produce high purity anhydrous EuI2 is critical for future development and applications of these scintillators. In this paper, the ammonium-iodide route to anhydrous EuI2 was investigated, and anhydrous EuI2 with purity of 99.95 wt.%was successfully prepared. The dehydration mechanisms of europium iodide hydrate and its mixture with NH4I were comparatively investigated by X-ray diffraction (XRD), thermal analysis and fluorescence spectroscopy. The thermal decomposition process of individual europium iodide hydrate was revealed as follows:EuI3·9H2O→EuI3·8H2O→EuI3·7H2O→EuI2·H2O→EuI2, and the hydrolysis mechanism of europium hydrate was comprehensively studied. When europium iodide hydrate was dehydrated with NH4I, NH4Eu2I5 formed as an intermediate product, and the hydrolysis of EuI2 was effectively restrained. The role of NH4I as an io-dination agent was also discussed.

  20. Leaching of iodide (I(-)) and iodate (IO3(-)) anions from synthetic layered double hydroxide materials.

    Science.gov (United States)

    Theiss, Frederick L; Ayoko, Godwin A; Frost, Ray L

    2016-09-15

    Several studies have previously demonstrated that layered double hydroxides (LDHs) show considerable potential for the adsorption of radioiodine from aqueous solution; however, few studies have demonstrated that these materials are able to store radioactive (131)I for an acceptable period. The leaching of iodide (I(-)) and iodate (IO3(-)) form Mg/Al LDHs has been carried out. Contact time appeared to be a more significant variable for the leaching of iodate (IO3(-)) compared to that of iodide (I(-)). Experimental results are fitted to the pseudo second order model, suggesting that diffusion is likely to be the rate-limiting step. The presence of carbonate in the leaching solution appeared to significantly increase the leaching of iodide (I(-)) as did the presence of chloride to a lesser extent. The maximum amount of iodate (IO3(-)) leached using ultrapure water as the leaching solution was 21% of the iodate (IO3(-)) originally present. The corresponding result for iodide (I(-)) was even lower at 3%. PMID:27309951

  1. Activation of lactoperoxidase by heme-linked protonation and heme-independent iodide binding.

    Science.gov (United States)

    Toyama, Akira; Tominaga, Aya; Inoue, Tatsuo; Takeuchi, Hideo

    2010-01-01

    Lactoperoxidase (LPO), a mammalian secretory heme peroxidase, catalyzes the oxidation of thiocyanate by hydrogen peroxide to produce hypothiocyanate, an antibacterial agent. Although LPO is known to be activated at acidic pH and in the presence of iodide, the structural basis of the activation is not well understood. We have examined the effects of pH and iodide concentration on the catalytic activity and the structure of LPO. Electrochemical and colorimetric assays have shown that the catalytic activity is maximized at pH 4.5. The heme Soret absorption band exhibits a small red-shift at pH 5.0 upon acidification, which is ascribable to a structural transition from a neutral to an acidic form. Resonance Raman spectra suggest that the heme porphyrin core is slightly contracted and the Fe-His bond is strengthened in the acidic form compared to the neutral form. The structural change of LPO upon activation at acidic pH is similar to that observed for myeloperoxidase, another mammalian heme peroxidase, upon activation at neutral pH. Binding of iodide enhances the catalytic activity of LPO without affecting either the optimum pH of activity or the heme structure, implying that the iodide binding occurs at a protein site away from the heme-linked protonation site.

  2. Iodide accumulation provides kelp with an inorganic antioxidant impacting atmospheric chemistry

    Science.gov (United States)

    Küpper, Frithjof C.; Carpenter, Lucy J.; McFiggans, Gordon B.; Palmer, Carl J.; Waite, Tim J.; Boneberg, Eva-Maria; Woitsch, Sonja; Weiller, Markus; Abela, Rafael; Grolimund, Daniel; Potin, Philippe; Butler, Alison; Luther, George W.; Kroneck, Peter M. H.; Meyer-Klaucke, Wolfram; Feiters, Martin C.

    2008-01-01

    Brown algae of the Laminariales (kelps) are the strongest accumulators of iodine among living organisms. They represent a major pump in the global biogeochemical cycle of iodine and, in particular, the major source of iodocarbons in the coastal atmosphere. Nevertheless, the chemical state and biological significance of accumulated iodine have remained unknown to this date. Using x-ray absorption spectroscopy, we show that the accumulated form is iodide, which readily scavenges a variety of reactive oxygen species (ROS). We propose here that its biological role is that of an inorganic antioxidant, the first to be described in a living system. Upon oxidative stress, iodide is effluxed. On the thallus surface and in the apoplast, iodide detoxifies both aqueous oxidants and ozone, the latter resulting in the release of high levels of molecular iodine and the consequent formation of hygroscopic iodine oxides leading to particles, which are precursors to cloud condensation nuclei. In a complementary set of experiments using a heterologous system, iodide was found to effectively scavenge ROS in human blood cells. PMID:18458346

  3. Preparation and Luminescence Thermochromism of Tetranuclear Copper(I)-Pyridine-Iodide Clusters

    Science.gov (United States)

    Parmeggiani, Fabio; Sacchetti, Alessandro

    2012-01-01

    A simple and straightforward synthesis of a tetranuclear copper(I)-pyridine-iodide cluster is described as a laboratory experiment for advanced inorganic chemistry undergraduate students. The product is used to demonstrate the fascinating and visually impressive phenomenon of luminescence thermochromism: exposed to long-wave UV light, the…

  4. LArIAT: Liquid Argon In A Testbeam

    CERN Document Server

    Cavanna, F; Raaf, J; Rebel, B

    2014-01-01

    Liquid Argon Time Projection Chambers (LArTPCs) are ideal detectors for precision neutrino physics. These detectors, when located deep underground, can also be used for measurements of proton decay, and astrophysical neutrinos. The technology must be completely developed, up to very large mass scales, and fully mastered to construct and operate these detectors for this physics program. As part of an integrated plan of developing these detectors, accurate measurements in LArTPC of known particle species in the relevant energy ranges are now deemed as necessary. The LArIAT program aims to directly achieve these goals by deploying LArTPC detectors in a dedicated calibration test beam line at Fermilab. The set of measurements envisaged here are significant for both the short-baseline (SBN) and long-baseline (LBN) neutrino oscillation programs in the US, starting with MicroBooNE in the near term and with the adjoint near and far liquid argon detectors in the Booster beam line at Fermilab envisioned in the mid-term...

  5. A liquid argon scintillation veto for the GERDA experiment

    International Nuclear Information System (INIS)

    Gerda is an experiment to search for the neutrinoless double beta decay of 76Ge. Results of Phase I have been published in summer 2013. Currently Gerda is being upgraded to a second phase. To reach the aspired background index of ≤ 10-3 cts/(keV . kg . yr) for Phase II active background-suppression techniques will be applied, including an active liquid argon veto (LAr veto). It has been demonstrated by the LArGe test facility that the detection of argon scintillation light can be used to effectively suppress background events in the germanium, which simultaneously deposit energy in LAr. This talk focusses on the light instrumentation which is being installed in GERDA. Photomultiplier tubes (PMT) and wavelength-shifting fibers connected to silicon photomultipliers (SiPM) are combined to maximize the photoelectron-yield with respect to various background sources. Monte Carlo simulations have been performed to optimize the design for background suppression and low self-induced background. First results of the prototypes and the progress of installation are reported.

  6. A liquid argon scintillation veto for the GERDA experiment

    Energy Technology Data Exchange (ETDEWEB)

    Wegmann, Anne [Max-Planck-Institut fuer Kernphysik, Saupfercheckweg 1, 69117 Heidelberg (Germany); Collaboration: GERDA-Collaboration

    2014-07-01

    Gerda is an experiment to search for the neutrinoless double beta decay of {sup 76}Ge. Results of Phase I have been published in summer 2013. Currently Gerda is being upgraded to a second phase. To reach the aspired background index of ≤ 10{sup -3} cts/(keV . kg . yr) for Phase II active background-suppression techniques will be applied, including an active liquid argon veto (LAr veto). It has been demonstrated by the LArGe test facility that the detection of argon scintillation light can be used to effectively suppress background events in the germanium, which simultaneously deposit energy in LAr. This talk focusses on the light instrumentation which is being installed in GERDA. Photomultiplier tubes (PMT) and wavelength-shifting fibers connected to silicon photomultipliers (SiPM) are combined to maximize the photoelectron-yield with respect to various background sources. Monte Carlo simulations have been performed to optimize the design for background suppression and low self-induced background. First results of the prototypes and the progress of installation are reported.

  7. Some transport properties in plasmas containing argon and fluorine

    Directory of Open Access Journals (Sweden)

    Novaković R.N.V.

    2003-01-01

    Full Text Available In this paper some results of numerical evaluation of transport coefficients in plasmas in the mixtures of argon and fluorine are presented. These transport characteristics are given in the function of the temperature for low pressures ranging from 0,1 kPa to 1,0 kPa and for low temperatures between 500 K and 5 000 K in argon plasmas with 20% and 30% of the fluorine added. It is assumed that the system is kept under constant pressure and that a corresponding state of local thermodynamical equilibrium (LTE is attained in it. The equilibrium plasma composition, necessary for the evaluations, was determined on the ground of the Saha equations for ionization processes and the law of mass action for the thermal dissociation of F2, combined with the charge conservation relation and the assumption that the pressure remained constant in the course of temperature variations. The ionization energy lowering, required in conjunction with the Saha equations, was obtained with the aid of a modified expression for the plasma Debye radius proposed previously. A previously derived expression for the modified Debye radius, offering the possibility to treat the plasmas considered as weakly non-ideal in the whole temperature range, is used. The cut-off at the Landau length rather than of the smallest of ionic radii is introduced. This alteration in the evaluation procedure brings different considerable changes in the final numerical results for the all relevant quantities.

  8. Compilation of electron collision excitation cross sections for neutro argon

    International Nuclear Information System (INIS)

    The present work presents a compilation and critical analysis of the available data on electron collision excitation cross sections for neutral Argon levels. This study includes: 1.- A detailed description in intermediate coupling for all the levels belonging the 20 configurations 3p''5 ns(n=4 to 12), np(n=4 to 8) and nd(n=3 to 8) of neutral Argon. 2.- Calculation of the electron collision excitation cross sections in Born and Born-Oppenheimer-Ochkur approximations for all the levels in the 14 configurations 3p''5 ns(n=4 to 7), np(n=4 to 7) and nd(n=3 to 8). 3.- Comparison and discussion of the compiled data. These are the experimental and theoretical values available from the literature, and those from this work. 4.- Analysis of the regularities and systematic behaviors in order to determine which values can be considered more reliable. It is show that the concept of one electron cross section results quite useful for this purpose. In some cases it has been possible to obtain in this way approximate analytical expressions interpolating the experimental data. 5.- All the experimental and theoretical values studied are graphically presented and compared. 6.- The last part of the work includes a listing of several general purpose programs for Atomic Physics calculations developed for this work. (Author)

  9. Elastic properties of liquid and solid argon in nanopores.

    Science.gov (United States)

    Schappert, Klaus; Pelster, Rolf

    2013-10-16

    We have measured sorption isotherms and determined the intrinsic longitudinal elastic modulus β(Ar,ads) of nanoconfined material via ultrasonic measurements combined with a special effective medium analysis. In the liquid regime the adsorbate only contributes to the measured effective properties when the pores are completely filled and the modulus is bulklike. At partial fillings its contribution is cancelled out by the high compressibility of the vapour phase. In contrast, at lower temperatures frozen argon as well as underlying liquid surface layers cause a linear increase of the effective longitudinal modulus upon filling. During sorption the contribution of the liquid surface layers near the pore wall β(Ar,surf) increases with the thickness of the solid layers reaching the bulk value β(Ar,liquid) only in the limit of complete pore filling. We interpret this effect as due to the gradual stiffening of the solid argon membrane. The measurements and their analysis show that longitudinal ultrasonic waves are well suited to the study of the elastic properties and liquid-solid phase transitions in porous systems. This method should also help to detect the influence of nanoconfinement on elastic properties in further research. PMID:24057946

  10. Experimental study on iodine chemistry (EXSI) - Containment experiments with methyl iodide

    Energy Technology Data Exchange (ETDEWEB)

    Holm, J.; Ekberg, C. (Chalmers Univ. of Technology, Goeteborg (Sweden)); Kaerkelae, T.; Auvinen, A. (VTT, Espoo (Finland)); Glaenneskog, H. (Vattenfall Power Consultant, Goeteborg (Sweden))

    2011-05-15

    An experimental study on radiolytic decomposition of methyl iodide was conducted in co-operation between VTT and Chalmers University of Technology as a part of the NKS-R programs. In year 2008 the NROI project, a Nordic collaboration studying iodine chemistry in the containment, was started. During year 2008 (NROI-1) the radiolytic oxidation of elemental iodine was investigated and during 2009 (NROI-2), the radiolytic oxidation of organic iodine was studied. This project (NROI-3) is a continuation of the investigation of the oxidation of organic iodine. The project has been divided into two parts. 1. The aims of the first part were to investigate the effect of ozone and UV-radiation, in dry and humid conditions, on methyl iodide. 2. The second project was about gamma radiation (approx20 kGy/h) and methyl iodide in dry and humid conditions. 1. Experimental results showed that the methyl iodide concentration in the facility was reduced with increasing temperature and increasing UV-radiation intensity. Similar behaviour occurred when ozone was present in the system. Formed organic gas species during the decomposition of methyl iodide was mainly formaldehyde and methanol. The particle formation was instant and extensive when methyl iodide was exposed to ozone and/or radiation at all temperatures. The size of the formed primary particles was about 10 nm and the size of secondary particles was between 50-200 nm. From the SEM-EDX analyses of the particles, the conclusion was drawn that these were some kind of iodine oxides (I{sub xO{sub y}). However, the correct speciation of the formed particles was difficult to obtain because the particles melted and fused together under the electron beam. 2. The results from this sub-project are more inconsistent and hard to interpret. The particle formation was significant lesser than corresponding experiments when ozone/UV-radiation was used instead of gamma radiation. The transport of gaseous methyl iodide through the facility was

  11. Local effects of ECRH on argon transport at ASDEX upgrade

    International Nuclear Information System (INIS)

    Future deuterium-tritium magnetically confined fusion power plants will most probably rely an high-Z Plasma Facing Components (PFCs) such as tungsten. This choice is determined by the necessity of low erosion of the first wall materials (to guarantee a long lifetime of the wall components) and by the need to avoid the too high tritium wall retention of typical carbon based PFCs. The experience gathered at the ASDEX Upgrade (AUG) tokamak has demonstrated the possibility of reliable and high performance plasma operation with a full tungsten-coated first wall. The observed accumulation of tungsten which can lead to excessive radiation losses is mitigated with the use of Electron Cyclotron Resonance Heating (ECRH). Although this impurity control method is routinely performed at AUG, the underlying physics principles are still not clear. This thesis aims an providing further knowledge an the effects of ECRH an the transport of impurities inside the core plasma. The transport of argon has been therefore investigated in-depth in purely ECR heated L-mode (low-confinement) discharges. Studies an impurity transport in centrally ECR heated nitrogen-seeded H-mode (high-confinement) discharges have also been performed. To this scope, a new crystal X-ray spectrometer of the Johann type has been installed an AUG for argon concentration and ion temperature measurements. New methods for the experimental determination of the total argon density through the integrated use of this diagnostic and of the Soft X-Ray (SXR) diode arrays have been developed. This gives the possibility of evaluating the full profiles of the argon transport coefficients from the linear flux-gradient dependency of local argon density. In comparison to classical χ2-minimization methods, the approach proposed here delivers transport coefficients intrinsically independent of the modelling of periodic relaxation mechanisms such as those Lied to sawtooth MHD (Magneto-Hydro-Dynamic) activity. Moreover, the good

  12. Conversion of Iodide to Hypoiodous Acid and Molecular Iodine at the Air-Water Interface

    Science.gov (United States)

    Pillar, E. A.; Guzman, M. I.

    2013-12-01

    Sea spray aerosols continuously transfer a significant amount of halides to the marine boundary layer, where they play a major role in the depletion of tropospheric ozone. The reactivity of iodide is of special interest in sea spray aerosols, where this species is enriched relative to chloride and bromide in surface seawater. This work presents laboratory experiments that provide mechanistic information to understand the reactivity of halides in atmospheric aerosols. Pneumatically assisted electrospray is used to aerosolize solutions of sodium iodide (0.01-100 μM), which are rapidly (~3 μs) oxidized by ozone at 25 °C. Reaction products include HIO, IO2-, IO3-, I2, HI2O-, and I3-, all identified by mass spectrometry. The distribution of products varies along two different reaction pathways, one favoring the production of I2 and HIO for typical tropospheric ozone levels (~50 ppbv), and another one directed to the production of IO3- at higher oxidizer concentrations. The formation of products increases exponentially with rising concentrations of initial sodium iodide, [NaI]0. The process is determined to be pH independent for the pH range 6-8 representative of surface waters. The substitution of aqueous solutions by organic solvents, such as methanol or acetonitrile, causes a decrease in the surface tension and lifetime of the droplets, leading to larger I2 production. The presence of surface active organic compounds, which alter the structure of the interfacial region, promote the pathway of I2 formation over IO3-. In conclusion, this presentation will show how the oxidation of iodide in aqueous microdroplets can release reactive gas-phase species, such as I2 and HIO, capable to affect tropospheric ozone globally. Normalized intensity of products observed during the ozonolysis of iodide solutions at 130 ppbv ozone. Cone voltage = 70 V, needle voltage = 2.5 kV.

  13. [The application of eosin and propidium iodide in evaluation of vitality of human spermatozoa].

    Science.gov (United States)

    Ploskonos, М В

    2014-11-01

    The article analyzes comparative assessment of vitality of spermatozoa by condition of permeability of membranes for eosin and propidium iodide and comparison of results acquired using technique of light and fluorescent microscopy. The comparison of data of light microscopy with eosin staining with data of fluorescent microscopy with propidium iodide staining demonstrated that percentage of content of spermatozoa separated from ejaculates of 28 fertile males and stained with eosin was reliably higher (34.8 ± 3.2) than percentage of content of spermatozoa with stained with propidium iodide (2.1 ± 4.0). After incubation of spermatozoa under room temperature during 24 hours percentage of unviable cells with stained eosin also was higher than in case of propidium iodide staining correspondingly (44.5 ± 3.3% and 34.7 ± 3.6%). The analysis of vitality of spermatozoa under damaging effect of oxidative stress on cell membrane developed by 4 hours incubation with 200 mkM of hydrogen peroxide (H2O2) demonstrated that under staining of spermatozoa with propidium iodide significantly higher percentage of damaged cells is detected. In such cases, eosin staining is less suitable for detection of vitality of spermatozoa (73.6 ± 5.8% against 51.7 ± 6.4%). The carried out experiment demonstrates that in case of detected effects on spermatozoa (for example, effect of oxidative stress) the light microscopy insufficiently adequate reflects degree of damage of membranes of spermatozoa. The fluorescent microscopy detects a higher percentage of spermatozoa with damaged membrane.

  14. Ful distil ation argon producing crud argon column on operating experience%全精馏制氩粗氩塔操作经验浅谈

    Institute of Scientific and Technical Information of China (English)

    马光显

    2015-01-01

    This paper briefly introduces the ful distil ation argon recovery process in the crude argon column in air separation system of cooling,heating and put some matters needing attention in use.%简要介绍了全精馏制氩过程中粗氩塔在空分系统降温、升温及投用中的一些注意事项。

  15. Synergistic Effect of Azadirachta Indica Extract and Iodide Ions on the Corrosion Inhibition of Aluminium in Acid Media

    International Nuclear Information System (INIS)

    The synergistic action caused by iodide ions on the corrosion inhibition of aluminium (Al) in 0.5 M HCl in the presence of Azadirachta Indica (AZI) plant extract has been investigated using potintiodynamic polarization and impedance techniques. It is found that AZI extract inhibits the corrosion of aluminium in 0.5 M HCl. The inhibition efficiency increases with the increase in AZI extract concentration, until 24% v/v of AZI extract, then Inh.% is decreased with father increase in AZI extract concentration. The adsorption of this extract in the studied concentration is found to obey Frewendlish adsorption isotherm. The addition of iodide ions enhances the inhibition efficiency to a considerable extent. The increase in Inh.% values in presence of fixed concentration of iodide ions indicates that AZI extract forms an insoluble complex at lower AZI extract concentrations by undergoing a joint adsorption. But at higher concentrations of AZI extract, competitive adsorption is found between iodide ions and the formed complex leading to less Inh.%. The Inh.% decreased in presence of iodide ions with AZI extract than in presence of AZI extract alone at all studied iodide concentrations. The synergism parameter S θ is defined and calculated from surface coverage values. This parameter in the case of AZI extract is found to be more than unity, indicating that the enhanced inhibition efficiency caused by the addition of iodide ions

  16. Contrasting the surface ocean distribution of bromoform and methyl iodide; implications for boundary layer physics, chemistry and climate

    Energy Technology Data Exchange (ETDEWEB)

    Palmer, C J, E-mail: carl.j.palmer@gmail.co [Department of Oceanography, University of Cape Town, 7701 (South Africa)

    2010-08-15

    Bromoform and methyl iodide are both methane-like hydrocarbons with a halogen atom replacing one or more of the hydrogen atoms. Both of these compounds occur naturally in the environment as a result of their production from seaweed and kelp. They are of interest to climate science as a result of their catalytic destruction of boundary layer ozone (a potent greenhouse gas) and, specifically for methyl iodide, the proposed role in the formation of new cloud condensation nuclei with implications for climate. In this paper, the currently available data on the distribution of bromoform and methyl iodide are analysed and contrasted to show that the concentrations of bromoform and methyl iodide do not correlate, that, in contrast to bromoform, the parameterization of sea surface methyl iodide concentrations demands only the sea surface temperature, and that the pelagic distribution of methyl iodide appears to follow the solar zenith angle. These three observations together suggest that, while the pelagic source of bromoform is mostly biogenic, the source of methyl iodide is photochemical. This has implications for the understanding of planetary boundary layer chemistry and potential organohalogen mediated feedbacks to climate.

  17. Contrasting the surface ocean distribution of bromoform and methyl iodide; implications for boundary layer physics, chemistry and climate

    International Nuclear Information System (INIS)

    Bromoform and methyl iodide are both methane-like hydrocarbons with a halogen atom replacing one or more of the hydrogen atoms. Both of these compounds occur naturally in the environment as a result of their production from seaweed and kelp. They are of interest to climate science as a result of their catalytic destruction of boundary layer ozone (a potent greenhouse gas) and, specifically for methyl iodide, the proposed role in the formation of new cloud condensation nuclei with implications for climate. In this paper, the currently available data on the distribution of bromoform and methyl iodide are analysed and contrasted to show that the concentrations of bromoform and methyl iodide do not correlate, that, in contrast to bromoform, the parameterization of sea surface methyl iodide concentrations demands only the sea surface temperature, and that the pelagic distribution of methyl iodide appears to follow the solar zenith angle. These three observations together suggest that, while the pelagic source of bromoform is mostly biogenic, the source of methyl iodide is photochemical. This has implications for the understanding of planetary boundary layer chemistry and potential organohalogen mediated feedbacks to climate.

  18. Characteristics of atmospheric-pressure, radio-frequency glow discharges operated with argon added ethanol

    Science.gov (United States)

    Sun, Wen-Ting; Li, Guo; Li, He-Ping; Bao, Cheng-Yu; Wang, Hua-Bo; Zeng, Shi; Gao, Xing; Luo, Hui-Ying

    2007-06-01

    Rf, atmospheric-pressure glow discharge (APGD) plasmas with bare metal electrodes have promising prospects in the fields of plasma-aided etching, thin film deposition, disinfection and sterilization, etc. In this paper, the discharge characteristics are presented for the rf APGD plasmas generated with pure argon or argon-ethanol mixture as the plasma-forming gas and using water-cooled, bare copper electrodes. The experimental results show that the breakdown voltage can be reduced significantly when a small amount of ethanol is added into argon, probably due to the fact that the Penning ionization process is involved, and a pure α-mode discharge can be produced more easily with the help of ethanol. The uniformity of the rf APGDs of pure argon or argon-ethanol mixtures using bare metallic electrodes is identified with the aid of the intensified charge coupled device images.

  19. First measurements with ARGONTUBE, a 5 m long drift Liquid Argon TPC

    International Nuclear Information System (INIS)

    The Liquid Argon Time Projection Chamber (LAr TPC) technique is a promising technology for future neutrino detectors. At LHEP of the University of Bern (Switzerland), an R and D program towards large detectors are on-going. The main goal is to show the feasibility of long drift paths over many meters. Therefore, a liquid Argon TPC with 5 m of drift distance was constructed. Many other aspects of the liquid Argon TPC technology are also investigated, such as a new device to generate high voltage in liquid Argon (Greinacher circuit), a recirculation filtering system and the multi-photon ionization of liquid Argon with a UV laser. Two detectors are built: a medium size prototype for specific detector technology studies, and ARGONTUBE, a 5 m long device

  20. Characteristics of atmospheric-pressure, radio-frequency glow discharges operated with argon added ethanol

    International Nuclear Information System (INIS)

    Rf, atmospheric-pressure glow discharge (APGD) plasmas with bare metal electrodes have promising prospects in the fields of plasma-aided etching, thin film deposition, disinfection and sterilization, etc. In this paper, the discharge characteristics are presented for the rf APGD plasmas generated with pure argon or argon-ethanol mixture as the plasma-forming gas and using water-cooled, bare copper electrodes. The experimental results show that the breakdown voltage can be reduced significantly when a small amount of ethanol is added into argon, probably due to the fact that the Penning ionization process is involved, and a pure α-mode discharge can be produced more easily with the help of ethanol. The uniformity of the rf APGDs of pure argon or argon-ethanol mixtures using bare metallic electrodes is identified with the aid of the intensified charge coupled device images

  1. First measurement of the ionization yield of nuclear recoils in liquid argon

    Energy Technology Data Exchange (ETDEWEB)

    Joshi, T. [Univ. of California, Berkeley, CA (United States). Dept. of Nuclear Engineering; Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Sangiorgio, Samuele [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Bernstein, A. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Foxe, Michael P. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Pennsylvania State Univ., University Park, PA (United States). Dept. of Mechanical and Nuclear Engineering; Hagmann, Chris [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Jovanovic, Igor [Pennsylvania State Univ., University Park, PA (United States). Dept. of Mechanical and Nuclear Engineering; Kazkaz, K. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Mozin, Vladimir V. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Norman, E. B. [Univ. of California, Berkeley, CA (United States). Dept. of Nuclear Engineering; Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Pereverzev, S. V. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Rebassoo, Finn O. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Sorensen, Peter F. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

    2014-05-01

    Liquid phase argon has long been used as a target medium for particle detection via scintillation light. Recently there has been considerable interest in direct detection of both hypothetical darkmatter particles and coherent elastic neutrino nucleus scattering. These as-yet unobserved neutral particle interactions are expected to result in a recoiling argon atom O(keV), generally referred to in the literature as a nuclear recoil. This prompts the question of the available electromagnetic signal in a liquid argon detector. In this Letter we report the first measurement of the ionization yield (Qy), detected electrons per unit energy, resulting from nuclear recoils in liquid argon, measured at 6.7 keV. This is also the lowest energy measurement of nuclear recoils in liquid argon.

  2. Management of Liver Cancer Argon-helium Knife Therapy with Functional Computer Tomography Perfusion Imaging.

    Science.gov (United States)

    Wang, Hongbo; Shu, Shengjie; Li, Jinping; Jiang, Huijie

    2016-02-01

    The objective of this study was to observe the change in blood perfusion of liver cancer following argon-helium knife treatment with functional computer tomography perfusion imaging. Twenty-seven patients with primary liver cancer treated with argon-helium knife and were included in this study. Plain computer tomography (CT) and computer tomography perfusion (CTP) imaging were conducted in all patients before and after treatment. Perfusion parameters including blood flows, blood volume, hepatic artery perfusion fraction, hepatic artery perfusion, and hepatic portal venous perfusion were used for evaluating therapeutic effect. All parameters in liver cancer were significantly decreased after argon-helium knife treatment (p liver tissue, but other parameters kept constant. CT perfusion imaging is able to detect decrease in blood perfusion of liver cancer post-argon-helium knife therapy. Therefore, CTP imaging would play an important role for liver cancer management followed argon-helium knife therapy.

  3. Synthesis of cholesteryl-α-D-lactoside via generation and trapping of a stable β-lactosyl iodide

    Science.gov (United States)

    Davis, Ryan A.; Fettinger, James C.; Gervay-Hague, Jacquelyn

    2015-01-01

    The generation of β-lactosyl iodide was carried out under non-in situ-anomerization, metal free conditions by reacting commercially available β-per-O-acetylated lactose with trimethylsilyl iodide (TMSI). The β-iodide was surprisingly stable as evidenced by NMR spectroscopy. Introduction of octanol or cholesterol under microwave conditions gave high yields of α-linked glycoconjugates. Careful analysis of the reaction products and mechanistic considerations suggest an acid catalyzed rearrangement that provides α-linked glycosylation products with a free C2-hydroxyl. Accessibility to these compounds may further advance glycolipidomic profiling of immune modulating bacterial derived-glycans. PMID:26543257

  4. Development of membrane cryostats for large liquid argon neutrino detectors

    CERN Document Server

    Montanari, D; Gendotti, A; Geynisman, M; Hentschel, S; Loew, T; Mladenov, D; Montanari, C; Murphy, S; Nessi, M; Norris, B; Noto, F; Rubbia, A; Sharma, R; Smargianaki, D; Stewart, J; Vignoli, C; Wilson, P; Wu, S

    2015-01-01

    A new collaboration is being formed to develop a multi-kiloton Long-Baseline neutrino experiment that will be located at the Surf Underground Research Facility (SURF) in Lead, SD. In the present design, the detector will be located inside cryostats filled with 68,400 ton of ultrapure liquid argon (less than 100 parts per trillion of oxygen equivalent contamination). To qualify the membrane technology for future very large-scale and underground implementations, a strong prototyping effort is ongoing: several smaller detectors of growing size with associated cryostats and cryogenic systems will be designed and built at Fermilab and CERN. They will take physics data and test different detector elements, filtration systems, design options and installation procedures. In addition, a 35 ton prototype is already operational at Fermilab and will take data with single-phase detector in early 2016. After the prototyping phase, the multi-kton detector will be constructed. After commissioning, it will detect and study ne...

  5. Fluorescence Spectrum of SiO in an Argon Matrix

    Science.gov (United States)

    Scullman, R.; Hormes, J.; Schroeder, W.; Wiggenhauser, H.

    1987-04-01

    Fluorescence from SiO matrix isolated in argon has been investigated in the wavelength region 120-300 nm. Fluorescence emission spectra from the valence states, A1Π, E1Σ+ and G1Π, revealed that nearly all radiation comes from one channel at 305 nm, which was analysed as originating from the b3Π-X1Σ+ transition. Contrary to the A1Π and G1Π states, the E1Σ+ state also decays radiatively, although weakly, through two other channels situated in the vicinity of 305 nm. These two channels were believed to originate from the a3Σ+-X1Σ+ and e3Σ--X1Σ+ transitions.

  6. Electron Neutrino Classification in Liquid Argon Time Projection Chamber Detector

    CERN Document Server

    Płoński, Piotr; Sulej, Robert; Zaremba, Krzysztof

    2015-01-01

    Neutrinos are one of the least known elementary particles. The detection of neutrinos is an extremely difficult task since they are affected only by weak sub-atomic force or gravity. Therefore large detectors are constructed to reveal neutrino's properties. Among them the Liquid Argon Time Projection Chamber (LAr-TPC) detectors provide excellent imaging and particle identification ability for studying neutrinos. The computerized methods for automatic reconstruction and identification of particles are needed to fully exploit the potential of the LAr-TPC technique. Herein, the novel method for electron neutrino classification is presented. The method constructs a feature descriptor from images of observed event. It characterizes the signal distribution propagated from vertex of interest, where the particle interacts with the detector medium. The classifier is learned with a constructed feature descriptor to decide whether the images represent the electron neutrino or cascade produced by photons. The proposed ap...

  7. Large area liquid argon detectors for interrogation systems

    Energy Technology Data Exchange (ETDEWEB)

    Gary, Charles; Kane, Steve; Firestone, Murray I.; Smith, Gregory [Adelphi Technology LLC, Purdue Technology Center, 5225 Exploration Drive, Indianapolis, IN 46241 (United States); Gozani, Tsahi; Brown, Craig; Kwong, John; King, Michael J. [Rapiscan Laboratories, 520 Almanor Avenue, Sunnyvale, CA 94085 (United States); Nikkel, James A.; McKinsey, Dan [Physics Department, Yale University, New Haven, CT 06520 (United States)

    2013-04-19

    Measurements of the efficiency, pulse shape, and energy and time resolution of liquid argon (LAr) detectors are presented. Liquefied noble gas-based (LNbG) detectors have been developed for the detection of dark matter and neutrinoless double-beta decay. However, the same qualities that make LNbG detectors ideal for these applications, namely their size, cost, efficiency, pulse shape discrimination and resolution, make them promising for portal screening and the detection of Special Nuclear Materials (SNM). Two 18-liter prototype detectors were designed, fabricated, and tested, one with pure LAr and the other doped with liquid Xe (LArXe). The LArXe detector presented the better time and energy resolution of 3.3 ns and 20% at 662 KeV, respectively. The total efficiency of the detector was measured to be 35% with 4.5% of the total photons detected in the photopeak.

  8. Argon plasma coagulation for treatment of hemorrhagic radiation gastroduodenitis

    Energy Technology Data Exchange (ETDEWEB)

    Maekawa, Shu-Ji; Aoyama, Nobuo; Shirasaka, Daisuke; Inoue, Takashi; Kuroda, Kohei; Ebara, Shigeyuki; Tamura, Takao; Miyamoto, Masaki; Kasuga, Masato [Kobe Univ. (Japan). Graduate School of Medicine

    2002-01-01

    A 79-year-old man who had received radiotherapy for portal vein thrombosis due to hepatocellular carcinoma (HCC) 5 months earlier, showed progressive anemia and melena. Endoscopy on admission revealed diffuse bleeding from multiple telangiectasias on the anterior wall of the antrum and bulbus. We treated this patient with a new non-contact hemostatic method: the argon plasma coagulator (APC). The melena stopped after the first session and the hemoglobin level remained stable for 7 months. No delayed complications have been observed. Gastrointestinal bleeding from chronic radiation gastroduodenitis is rarely reported compared with radiation proctitis. This case demonstrates that APC is effective for hemostasis of diffuse bleeding from radiation gastroduodenitis, just as for radiation protitis. (author)

  9. Line ratio diagnostics in helium and helium seeded argon plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Boivin, R F [Department of Physics, Auburn University, Auburn, AL 36849-5311 (United States); Loch, S D [Department of Physics, Auburn University, Auburn, AL 36849-5311 (United States); Ballance, C P [Physics Department, Rollins College, White Park, FL 32789 (United States); Branscomb, D [Department of Physics, Auburn University, Auburn, AL 36849-5311 (United States); Pindzola, M S [Department of Physics, Auburn University, Auburn, AL 36849-5311 (United States)

    2007-08-15

    We investigate the potential use of line ratio diagnostics to evaluate electron temperature in either helium or helium seeded argon plasmas. Plasmas are produced in a helicon plasma source. A rf compensated Langmuir probe is used to measure both the electron temperature and plasma density while a spectrometer is used to measure He I line intensities from the plasma. For all plasma densities where the electron temperature remains at 5 {+-} 1 eV, three He line ratios are measured. Each experimental ratio is compared with the prediction of three different collisional radiative models. One of these models makes uses of recent R-matrix with pseudo-states calculations for collisional rate coefficients. A discussion related to the different observations and model predictions is presented.

  10. Photodegradation Mechanisms of Tetraphenyl Butadiene Coatings for Liquid Argon Detectors

    CERN Document Server

    Jones, B J P; Conrad, J M; Pla-Dalmau, A

    2013-01-01

    We report on studies of degradation mechanisms of tetraphenyl butadiene (TPB) coatings of the type used in neutrino and dark matter liquid argon experiments. Using gas chromatography coupled to mass spectrometry we have detected the ultraviolet-blocking impurity benzophenone (BP). We monitored the drop in performance and increase of benzophenone concentration in TPB plates with exposure to ultraviolet (UV) light, and demonstrate the correlation between these two variables. Based on the presence and initially exponential increase in the concentration of benzophenone observed, we propose that TPB degradation is a free radical-mediated photooxidation reaction, which is subsequently confirmed by displaying delayed degradation using a free radical inhibitor. Finally we show that the performance of wavelength-shifting coatings of the type envisioned for the LBNE experiment can be improved by 10-20%, with significantly delayed UV degradation, by using a 20% admixture of 4-tert-Butylcatechol.

  11. Kinetic modeling of the Townsend breakdown in argon

    Energy Technology Data Exchange (ETDEWEB)

    Macheret, S. O.; Shneider, M. N. [Department of Mechanical and Aerospace Engineering, Princeton University, D-414 Engineering Quadrangle, Princeton, New Jersey 08544 (United States)

    2013-10-15

    Kinetic modeling of the Townsend breakdown in argon was performed in the “forward-back” approximation. The kinetic model was found to adequately describe the left branch of the Paschen curve, and the important role of ionization by fast ions and atoms near the cathode, as well as the increase in secondary emission coefficient in strong electric fields described in the literature, was confirmed. The modeling also showed that the electron energy distribution function develops a beam of high-energy electrons and that the runaway effect, i.e., the monotonic increase of the mean electron energy with the distance from the cathode, occurs at the left branch of the Paschen curve.

  12. Uranium (III) precipitation in molten chloride by wet argon sparging

    Science.gov (United States)

    Vigier, Jean-François; Laplace, Annabelle; Renard, Catherine; Miguirditchian, Manuel; Abraham, Francis

    2016-06-01

    In the context of pyrochemical processes for nuclear fuel treatment, the precipitation of uranium (III) in molten salt LiCl-CaCl2 (30-70 mol%) at 705 °C is studied. First, this molten chloride is characterized with the determination of the water dissociation constant. With a value of 10-4.0, the salt has oxoacid properties. Then, the uranium (III) precipitation using wet argon sparging is studied. The salt is prepared using UCl3 precursor. At the end of the precipitation, the salt is totally free of solubilized uranium. The main part is converted into UO2 powder but some uranium is lost during the process due to the volatility of uranium chloride. The main impurity of the resulting powder is calcium. The consequences of oxidative and reductive conditions on precipitation are studied. Finally, coprecipitation of uranium (III) and neodymium (III) is studied, showing a higher sensitivity of uranium (III) than neodymium (III) to precipitation.

  13. The readout driver (ROD) for the ATLAS liquid argon calorimeters

    Science.gov (United States)

    Efthymiopoulos, Ilias

    2001-04-01

    The Readout Driver (ROD) for the Liquid Argon calorimeter of the ATLAS detector is described. Each ROD module receives triggered data from 256 calorimeter cells via two fiber-optics 1.28 Gbit/s links with a 100 kHz event rate (25 kbit/event). Its principal function is to determine the precise energy and timing of the signal from discrete samples of the waveform, taken each period of the LHC clock (25 ns). In addition, it checks, histograms, and formats the digital data stream. A demonstrator system, consisting of a motherboard and several daughter-board processing units (PUs) was constructed and is currently used for tests in the lab. The design of this prototype board is presented here. The board offers maximum modularity and allows the development and testing of different PU designs based on today's leading integer and floating point DSPs.

  14. Characterization of SF6/Argon Plasmas for Microelectronics Applications; TOPICAL

    International Nuclear Information System (INIS)

    This report documents measurements in inductively driven plasmas containing SF(sub 6)/Argon gas mixtures. The data in this report is presented in a series of appendices with a minimum of interpretation. During the course of this work we investigated: the electron and negative ion density using microwave interferometry and laser photodetachment; the optical emission; plasma species using mass spectrometry, and the ion energy distributions at the surface of the rf biased electrode in several configurations. The goal of this work was to assemble a consistent set of data to understand the important chemical mechanisms in SF(sub 6) based processing of materials and to validate models of the gas and surface processes

  15. Photodegradation mechanisms of tetraphenyl butadiene coatings for liquid argon detectors

    Science.gov (United States)

    Jones, B. J. P.; VanGemert, J. K.; Conrad, J. M.; Pla-Dalmau, A.

    2013-01-01

    We report on studies of degradation mechanisms of tetraphenyl butadiene (TPB) coatings of the type used in neutrino and dark matter liquid argon experiments. Using gas chromatography coupled to mass spectrometry we have detected the ultraviolet-blocking impurity benzophenone. We monitored the drop in performance and increase of benzophenone concentration in TPB plates with exposure to ultraviolet (UV) light, and demonstrate the correlation between these two variables. Based on the presence and initially exponential increase in the concentration of benzophenone observed, we propose that TPB degradation is a free radical-mediated photooxidation reaction, which is subsequently confirmed by displaying delayed degradation using a free radical inhibitor. Finally we show that the performance of wavelength-shifting coatings of the type envisioned for the LBNE experiment can be improved by 10-20%, with significantly delayed UV degradation, by using a 20% admixture of 4-tert-Butylcatechol.

  16. Liquid Argon Cryogenic Detector Calibration by Inelastic Scattering of Neutrons

    CERN Document Server

    Polosatkin, Sergey; Dolgov, Alexander

    2014-01-01

    A method for calibration of cryogenic liquid argon detector response to recoils with certain energy -8.2 keV - is proposed. The method utilizes a process of inelastic scattering of monoenergetic neutrons produced by fusion DD neutron generator. Features of kinematics of inelastic scattering cause sufficient (forty times) increase in count rate of useful events relative to traditional scheme exploited elastic scattering with the same recoil energy and compatible energy resolution. The benefits of the proposed scheme of calibration most well implemented with the use of tagged neutron generator as a neutron source that allows to eliminate background originated from casual coincidence of signals on cryogenic detector and additional detector of scattered neutrons.

  17. The liquid argon TPC for the ICARUS experiment

    CERN Document Server

    Arneodo, F

    1997-01-01

    The ICARUS project aims at the realisation of a large liquid argon TPC to be run at the Underground Laboratories of Gran Sasso in Italy. An intense R&D; activity has put on firm grounds this new detector technology and experimentally confirmed its feasibility on a few ton scale. Based on these solid achievements, the collaboration is now confident of being able to build and safely operate a multi-kton detector. The reseach program of the experiment involves the systematic study of a wide spectrum of physical phenomena covering many orders of magnitude in the energy deposited in the detector: from the few MeV of solar neutrino interactions, to the about one GeV of the proton decay and atmospheric neutrinos, up to the higher energies of neutrinos from accelerators.

  18. Response Uniformity of the ATLAS Liquid Argon Electromagnetic Calorimeter

    CERN Document Server

    Aharrouche, M; Di Ciaccio, L; El Kacimi, M; Gaumer, O; Gouanère, M; Goujdami, D; Lafaye, R; Laplace, S; Le Maner, C; Neukermans, L; Perrodo, P; Poggioli, L; Prieur, D; Przysiezniak, H; Sauvage, G; Wingerter-Seez, I; Zitoun, R; Lanni, F; Lü, L; Ma, H; Rajagopalan, S; Takai, H; Belymam, A; Benchekroun, D; Hakimi, M; Hoummada, A; Gao, Y; Stroynowsk, R; Aleksa, M; Carli, T; Fassnacht, P; Gianotti, F; Hervás, L; Lampl, W; Collot, J; Hostachy, J Y; Ledroit-Guillon, F; Malek, F; Martin, P; Viret, S; Leltchouk, M; Parsons, J A; Simion, S; Barreiro, F; Del Peso, J; Labarga, L; Oliver, C; Rodier, S; Barrillon, P; Benchouk, C; Djama, F; Hubaut, F; Monnier, E; Pralavorio, P; Sauvage, D; Serfon, C; Tisserant, S; Tóth, J; Banfi, D; Carminati, L; Cavalli, D; Costa, G; Delmastro, M; Fanti, M; Mandell, L; Mazzanti, M; Tartarelli, F; Kotov, K; Maslennikov, A; Pospelov, G; Tikhonov, Yu; Bourdarios, C; Fayard, L; Fournier, D; Iconomidou-Fayard, L; Kado, M; Parrour, G; Puzo, P; Rousseau, D; Sacco, R; Serin, L; Unal, G; Zerwas, D; Dekhissi, B; Derkaoui, J; EL Kharrim, A; Maaroufi, F; Cleland, W; Lacour, D; Laforge, B; Nikolic-Audit, I; Schwemling, Ph; Ghazlane, H; Cherkaoui El Moursli, R; Idrissi Fakhr-Eddine, A; Boonekamp, M; Kerschen, N; Mansoulié, B; Meyer, P; Schwindlingy, J; Lund-Jensen, B

    2007-01-01

    The construction of the ATLAS electromagnetic liquid argon calorimeter modules is completed and all the modules are assembled and inserted in the cryostats. During the production period four barrel and three endcap modules were exposed to test beams in order to assess their performance, ascertain the production quality and reproducibility, and to scrutinize the complete energy reconstruction chain from the readout and calibration electronics to the signal and energy reconstruction. It was also possible to check the full Monte Carlo simulation of the calorimeter. The analysis of the uniformity, resolution and extraction of constant term is presented. Typical non-uniformities of 0.5% and typical global constant terms of 0.6% are measured for the barrel and end-cap modules.

  19. A Thermodynamic Model for Argon Plasma Kernel Formation

    Directory of Open Access Journals (Sweden)

    James Keck

    2010-11-01

    Full Text Available Plasma kernel formation of argon is studied experimentally and theoretically. The experiments have been performed in a constant volume cylindrical vessel located in a shadowgraph system. The experiments have been done in constant pressure. The energy of plasma is supplied by an ignition system through two electrodes located in the vessel. The experiments have been done with two different spark energies to study the effect of input energy on kernel growth and its properties. A thermodynamic model employing mass and energy balance was developed to predict the experimental data. The agreement between experiments and model prediction is very good. The effect of various parameters such as initial temperature, initial radius of the kernel, and the radiation energy loss have been investigated and it has been concluded that initial condition is very important on formation and expansion of the kernel.

  20. The readout driver (ROD) for the ATLAS liquid argon calorimeters

    CERN Document Server

    Efthymiopoulos, I

    2001-01-01

    The Readout Driver (ROD) for the Liquid Argon calorimeter of the ATLAS detector is described. Each ROD module receives triggered data from 256 calorimeter cells via two fiber-optics 1.28 Gbit/s links with a 100 kHz event rate (25 kbit/event). Its principal function is to determine the precise energy and timing of the signal from discrete samples of the waveform, taken each period of the LHC clock (25 ns). In addition, it checks, histograms, and formats the digital data stream. A demonstrator system, consisting of a motherboard and several daughter-board processing units (PUs) was constructed and is currently used for tests in the lab. The design of this prototype board is presented here. The board offers maximum modularity and allows the development and testing of different PU designs based on today's leading integer and floating point DSPs. (3 refs).

  1. Attosecond Coherent Control of Single and Double Photoionization in Argon.

    Science.gov (United States)

    Hogle, C W; Tong, X M; Martin, L; Murnane, M M; Kapteyn, H C; Ranitovic, P

    2015-10-23

    Ultrafast high harmonic beams provide new opportunities for coherently controlling excitation and ionization processes in atoms, molecules, and materials on attosecond time scales by employing multiphoton two-pathway electron-wave-packet quantum interferences. Here we use spectrally tailored and frequency tuned vacuum and extreme ultraviolet harmonic combs, together with two phase-locked infrared laser fields, to show how the total single and double photoionization yields of argon can be coherently modulated by controlling the relative phases of both optical and electronic-wave-packet quantum interferences. This Letter is the first to apply quantum control techniques to double photoionization, which is a fundamental process where a single, high-energy photon ionizes two electrons simultaneously from an atom. PMID:26551112

  2. Dynamic resonances and tunnelling in the multiphoton ionization of argon

    International Nuclear Information System (INIS)

    We present results of wavepacket simulations for multiphoton ionization in argon. A single active electron model is applied to estimate the single-electron ionization rates and photoelectron energy distributions for λ = 390 nm light with intensities up to I = 2 x 1014 W cm-2. The multiphoton ionization rates are compared with R-matrix Floquet calculations and found to be in very good agreement. The photoelectron energy distribution is used to study the nature of ionization at the higher intensities. Our results are consistent with recent calculations and experiments which show the imprint of the tunnelling process in the multiphoton regime. For few-cycle intense pulses, we find that the strong modulation of intensity and increased bandwidth leads to dynamic mixing of the 3d and 5s resonances.

  3. The ATLAS liquid Argon calorimeters read-out system

    CERN Document Server

    Blondel, A; Fayard, L; La Marra, D; Léger, A; Matricon, P; Perrot, G; Poggioli, L; Prast, J; Riu, I; Simion, S

    2004-01-01

    The calorimetry of the ATLAS experiment takes advantage of different detectors based on the liquid Argon (LAr) technology. Signals from the LAr calorimeters are processed by various stages before being delivered to the Data Acquisition system. The calorimeter cell signals are received by the front-end boards, which digitize a predetermined number of samples of the bipolar waveform and sends them to the Read-Out Driver (ROD) boards. The ROD board receives triggered data from 1028 calorimeter cells, and determines the precise energy and timing of the signals by processing the discrete samplings of the pulse. In addition, it formats the digital stream for the following elements of the DAQ chain, and performs monitoring. The architecture and functionality of the ATLAS LAr ROD board are discussed, along with the final design of the Processing Unit boards housing the Digital Signal Processors (DSP). (9 refs).

  4. Electron-ion recombination study in argon at atmospheric pressure

    International Nuclear Information System (INIS)

    This study deals with a wall-stabilized arc burning in argon at atmospheric pressure. A transient mode is obtained using a fast thyristor connected to the electrodes, which short-circuits the discharge. By means of two wavelengths laser interferometry and spectroscopy measurements we have determined the temporal changes of the electron density, ground state atom density and excited atom density. We have shown that, when the electric field is suppressed, the electron temperature rapidly decreases to the gas temperature before changing electron and atom densities. This phenomenon is applied to determine the gas temperature and to evaluate the role played by ionization in electron density balance. The coefficients of ambipolar diffusion, ionization and recombination and an apparent recombination coefficient are determined versus electron temperature and compared with theoretical values

  5. Part I. Voltammetric studies of potassium iodide at gold and platinum electrodes. Part II. Electrodeposition and characterization of poly(vinylferrocene) films

    Energy Technology Data Exchange (ETDEWEB)

    Holt, R.J.

    1993-01-01

    A mechanism for the adsorption of iodide on platinum and gold has been proposed in the literature which assumes hydrogen gas is evolved along with an adsorbed iodide atom. A rotating platinum ring-disk electrode was used here to detect the presence of any hydrogen produced upon iodide adsorption. No evidence for hydrogen formation was found. A gold-gold/platinum gas permeable double membrane electrode also did not show any evidence of hydrogen gas produced at gold during iodide adsorption. The voltammetry of iodide and iodate was examined using both gold and platinum ring-disk electrodes and a gas permeable double membrane electrode. The oxidation of adsorbed iodide was examined. The successful determination of the various oxidation states of iodide in acid media were performed: I[sub 2], IO[sup [minus

  6. Experimental study on iodine chemistry (EXSI) - Containment experiments with methyl iodide

    Energy Technology Data Exchange (ETDEWEB)

    Holm, J.; Glaenneskog, H.; Ekberg, C. (Chalmers Univ. of Technology (Sweden)); Kaerkelae, T.; Auvinen, A. (VTT Technical Research Centre of Finland (Finland))

    2010-05-15

    An experimental study on radiolytic decomposition of methyl iodide was conducted in co-operation between VTT and Chalmers University of Technology as a part of the NKS-R programs. The behaviour of iodine during a severe accident has been studied in several experimental programs, ranging from the large-scale PHEBUS FP tests and intermediate-scale ThAI tests to numerous separate effect studies. In year 2008 the NROI project, a Nordic collaboration studying iodine chemistry in the containment was started. During 2009, oxidation of iodine, especially organic iodine, was studied within the NROI project. The chemistry of organic iodine in the gas phase is still one of the greatest remaining uncertainties concerning iodine behaviour during a severe accident. During the first year of the NROI project the oxidation of elemental iodine, I2, with ozone and UV-light was investigated. In this study organic iodide, in this case methyl iodide, was investigated in similar conditions as in the NROI-1 project. The experimental facility applied in this study is based on the sampling system built at VTT for the ISTP project CHIP conducted by IRSN. The experimental facility and the measuring technology are sophisticated and unique in the area of nuclear research as well as in the field of aerosol science. Experimental results showed that the methyl iodide concentration in the facility was reduced with increasing temperature and increasing UVC intensity. Similar behaviour occurred when ozone was present in the system. Formed organic gas species during the decomposition of methyl iodide was mainly formaldehyde and methanol. Instant and extensive particle formation occurred when methyl iodide was transported through a UVC radiation field and/or when ozone was present. The size of the formed primary particles was about 10 nm and the size of secondary particles was between 50-150 nm. From the SEM-EDX analyses of the particles, the conclusion was drawn that these were some kind of iodine

  7. Atmospheric dispersion of argon-41 from anuclear research reactor: measurement and modeling of plume geometry and gamma radiation field

    DEFF Research Database (Denmark)

    Lauritzen, Bent; Astrup, Poul; Drews, Martin;

    2003-01-01

    An atmospheric dispersion experiment was conducted using a visible tracer along with the routine release of argon-41 from the BR1 research reactor in Mol, Belgium. Simultaneous measurements of plume geometry and radiation fields for argon-41 decay were performed as well as measurements of the argon...

  8. Reversible radiochromic plate based on polyvinyl alcohol-iodide complex containing silica nanoparticles

    International Nuclear Information System (INIS)

    A radiochromic plate based on a reversible change between iodide and iodine was prepared using a polyvinyl alcohol-iodide complex, silica nanoparticles, and agarose. X-ray (30 kV, 15 mA) irradiation of the plate changed it to a red color, which gradually disappeared and was completely erased within a day after stopping X-ray irradiation. The minimum detection dose was about 0.5 Gy for X-rays and 10 Gy for 137Cs γ-rays. The G-value for the oxidation of I- was estimated to be about 19.6 in a neutral solution and about 20.64 in an acidic solution. (author)

  9. Parametric study on removal efficiency of impregnated activated charcoal and silver zeolite for radioactive methyl iodide

    International Nuclear Information System (INIS)

    The removal efficiency of impregnated activated charcoal and silver zeolite for radioactive methyl iodide is influenced by various parameters such as temperature, relative humidity, face velocity and packing density. This study is to evaluate the dependency of the removal efficiency on each parameter and these combined parameters, quantitatively. Four types of adsorbents, BC-727, AgX, CHC-50 and SS 208C 5KI3, were tested. From experimental data and mass transfer theory, an experimental equation for evaluating the removal efficiency of adsorbents was derived under a series of experiments for radioactive methyl iodine-131. It was concluded that the removal efficiency calculated from the experimental equation agreed well with the experimental value. Effects of experimental specific parameters, such as Pre-flow time, methyl iodide injection time and After-flow time, on the removal efficiency of adsorbent are also described

  10. Iodide Recognition and Sensing in Water by a Halogen-Bonding Ruthenium(II)-Based Rotaxane.

    Science.gov (United States)

    Langton, Matthew J; Marques, Igor; Robinson, Sean W; Félix, Vítor; Beer, Paul D

    2016-01-01

    The synthesis and anion-recognition properties of the first halogen-bonding rotaxane host to sense anions in water is described. The rotaxane features a halogen-bonding axle component, which is stoppered with water-solubilizing permethylated β-cyclodextrin motifs, and a luminescent tris(bipyridine)ruthenium(II)-based macrocycle component. (1) H NMR anion-binding titrations in D2 O reveal the halogen-bonding rotaxane to bind iodide with high affinity and with selectively over the smaller halide anions and sulfate. The binding affinity trend was explained through molecular dynamics simulations and free-energy calculations. Photo-physical investigations demonstrate the ability of the interlocked halogen-bonding host to sense iodide in water, through enhancement of the macrocycle component's Ru(II) metal-ligand charge transfer (MLCT) emission. PMID:26626866

  11. Induction of iodide uptake in transformed thyrocytes: a compound screening in cell lines

    Energy Technology Data Exchange (ETDEWEB)

    Froehlich, Eleonore [University of Tuebingen, Department of Endocrinology, Metabolism, Nephrology and Clinical Chemistry, Internal Medicine, Tuebingen (Germany); Brossart, Peter [University of Tuebingen, Department of Haematology, Oncology, Immunology and Rheumatology, Internal Medicine, Tuebingen (Germany); Wahl, Richard [University of Tuebingen, Department of Endocrinology, Metabolism, Nephrology and Clinical Chemistry, Internal Medicine, Tuebingen (Germany); Department IV, Internal Medicine, Tuebingen (Germany)

    2009-05-15

    Retinoic acid presently is the most advanced agent able to improve the efficacy of radioiodine therapy in differentiated thyroid carcinoma. In order to identify compounds with higher efficacy a panel of pharmacologically well-characterized compounds with antitumour action in solid cancer cell lines was screened. The effects of the compounds on iodide uptake, cell number, proliferation and apoptosis were evaluated. In general, compounds were more effective in cell lines derived from more aggressive tumours. The effectiveness in terms of number of responsive cell lines and maximal increase in iodide uptake achieved decreased in the order: APHA > valproic acid {approx} sirolimus {approx} arsenic trioxide > retinoic acid {approx} lovastatin > apicidine {approx} azacytidine {approx} retinol {approx} rosiglitazone {approx} bortezomib. We hypothesize that testing of cells from primary tumours or metastases in patients may be a way to identify compounds with optimum therapeutic efficacy for individualized treatment. (orig.)

  12. Gap energy studied by optical transmittance in lead iodide monocrystals grown by Bridgman's Method

    Directory of Open Access Journals (Sweden)

    Veissid N.

    1999-01-01

    Full Text Available The bandgap energy as a function of temperature has been determined for lead iodide. The monocrystal was obtained in a vacuum sealed quartz ampoule inside a vertical furnace by Bridgman's method. The optical transmittance measurement enables to evaluate the values of Eg. By a fitting procedure of Eg as a function of temperature is possible to extract the parameters that govern its behavior. The variation of Eg with temperature was determined as: Eg(T = Eg(0 - aT2/(a + T, with: Eg(0 = (2.435 ± 0.008 eV, a = (8.7 ± 1.3 x 10-4 eV/K and a = (192 ± 90 K. The bandgap energy of lead iodide at room temperature was found to be 2.277 ± 0.007 eV.

  13. Non-isothermal adsorption of radioactive methyl iodide at high temperature

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Byung Seon; Park, Geun Il; Lee, Jung Won; Yoon, Ju Hyeon [KAERI, Taejon (Korea, Republic of); Yang, Ho Yeon [KHNPC, Taejon (Korea, Republic of); Ryu, Seung Kon [Chungnam National Univ., Taejon (Korea, Republic of)

    2003-07-01

    Although activated carbon has been successfully used in nuclear power plants, it cannot be considered as a primary adsorbent in a high temperature system, because of its low ignition temperature and its adverse reaction with nitrogen oxide. Therefore, activated carbon is virtually ruled out for high temperature operating systems. The adsorption and dynamic characteristics of gaseous methyl iodide for silver ion-exchanged zeolites at high temperatures up to 400 .deg. C was evaluated. In this study a simple nonisothermal and axially dispersed plug-flow was adopted to simulate the experimental breakthrough curves. The Langmuir-Freundlich isotherm model was used to represent the equilibrium relationship, and the linear driving force (LDF) approximation was used to represent the article uptake. From the viewpoint of silver utilization for the removal of methyl iodide, both the optimal operating temperature and the effective silver ion-exchange level were also determined.

  14. Performance of non-coconut base adsorbers in removal of iodine and organic iodides

    International Nuclear Information System (INIS)

    Systems for the removal of radioactive iodine and organic iodides have used impregnated coconut shell activated carbons almost exclusively. Coconut shell carbons have some disadvantages: their geographical origin determines their trace chemical content; pore structures and impregnant effectiveness are highly dependent on activation and impregnation techniques. The authors report laboratory performance of a group of iodine-organic iodide adsorbers using bases other than coconut shell carbon. These have been evaluated in conformity with USAEC Regulatory Guide 1.52 and RDT M16 1T. Performance with regard to 131I2 and CH3131I penetration and high-temperature elution have equaled or exceeded both the requirements of Guide 1.52 and results on typical coconut-shell carbons. Some performance outside Guide 1.52 ranges is included. Experimental problems in simulated LOCA testing are discussed. (U.S.)

  15. Heck Arylation of Acrylonitrile with Aryl Iodides Catalyzed by a Silica-bound Arsine Palladium(0) Complex

    Institute of Scientific and Technical Information of China (English)

    Ming Zhong CAI; Hong ZHAO; Rong Li ZHANG

    2005-01-01

    Acrylonitrile reacts with aryl iodides in the presence of tri-n-butylamine and a catalytic amount of a silica-bound arsine palladium(0) complex to afford stereoselectively (E)-cinnamonitriles in high yields.

  16. A mercuric ensemble based on a cycloruthenated complex as a visual probe for iodide in aqueous solution

    Science.gov (United States)

    Su, Xianlong; Guo, Lieping; Ma, Yajuan; Li, Xianghong

    2016-01-01

    A new water-soluble cycloruthenated complex Ru(bthiq)(dcbpy)2+ (1, Hbthiq = 1-(2-benzo[b]thiophenyl)isoquinoline, dcbpy = 4,4‧-dicarboxylate-2,2‧-bipyridine) was designed and synthesized to form its mercuric ensemble (1-Hg2+) to achieve visual detection of iodide anions. The binding constant of 1-Hg2+ is calculated to be 2.40 × 104 M-1, which is lower than that of HgI2. Therefore, the addition of I- to the aqueous solution of 1-Hg2+lead to significant color changes from yellow to deep-red by the release of 1. The results showed that iodide anions could be easily detected by the naked eyes. The detection limit of iodide anion is calculated as 0.77 μM. In addition, an easily-prepared test strip of 1-Hg2+ was obtained successfully to detect iodide anions.

  17. Cooperative effect of silver in copper-catalyzed trifluoromethylation of aryl iodides using Me3SiCF3

    KAUST Repository

    Weng, Zhiqiang

    2011-06-13

    An effective model of cooperative effect of silver for the coppercatalyzed trifluoromethylation of activated and unactivated aryl iodides to trifluoromethylated arenes using Me3SiCF3 was achieved with a broad substrate scope. © 2011 American Chemical Society.

  18. Furnace design for the mercuric iodide crystal growth for new semiconductor radiation detector

    International Nuclear Information System (INIS)

    Mercuric iodide has been attracted an interest for 40 years due to its efficiency as room temperature detector for X and γ-rays. It is worthy to note that commercial γ-ray detectors such as Ge semiconductor detectors should cool down to liquid nitrogen temperature. Compared to other semiconductor detectors such as CdZnTe and CdTe, mercuric iodide has higher efficiency, lower leakage current and less degradation. In addition, mercuric iodide has useful properties such as large band gap of 2.15 eV, low electron-hole pair creation energy of 4.2 eV, and high atomic number (Hg : 80 and I : 53). However, it is difficult to obtain high quality single crystals and the long term reliability problem in devices so that the applications of α-HgI2 are limited. Mercuric iodide undergoes a structural phase transition from an orthorhombic yellow phase (β-HgI2) to a tetragonal red phase (α-HgI2) at 127 .deg. C. In addition, the melting temperature of HgI2 is 259 .deg. C. Thus, when it grows through a melting method over 259 .deg. C, the β-HgI2 phase can be included in the final crystals in the room temperature. In general, in order to grow α-HgI2single crystals, the operating temperature is below 127 .deg. C. Note that the crystals from the solution method have contamination problems and the crystals from the physical vapor method usually display a higher quality with a well defined structure. A good thing for the physical vapor method is that α-HgI2 has high vapor pressure (∼0.1 Torr at 120 .deg. C) indicating that α-HgI2 can be grown in closed ampoules

  19. Nickel-catalyzed reductive arylation of activated alkynes with aryl iodides

    Science.gov (United States)

    Dorn, Stephanie C. M.; Olsen, Andrew K; Kelemen, Rachel E.; Shrestha, Ruja; Weix, Daniel J.

    2015-01-01

    The direct, regioselective, and stereoselective arylation of activated alkynes with aryl iodides using a nickel catalyst and manganese reductant is described. The reaction conditions are mild (40 °C in MeOH, no acid or base) and an intermediate organomanganese reagent is unlikely. Functional groups tolerated include halides and pseudohalides, free and protected anilines, and a benzyl alcohol. Other activated alkynes including an amide and a ketone also reacted to form arylated products in good yields. PMID:26028781

  20. Use of potassium iodide in Dermatology: updates on an old drug*

    OpenAIRE

    Costa, Rosane Orofino; de Macedo, Priscila Marques; Carvalhal, Aline; Bernardes-Engemann, Andréa Reis

    2013-01-01

    Potassium iodide, as a saturated solution, is a valuable drug in the dermatologist's therapeutic arsenal and is useful for the treatment of different diseases due to its immunomodulatory features. However, its prescription has become increasingly less frequent in dermatology practice. Little knowledge about its exact mechanism of action, lack of interest from the pharmaceutical industry, the advent of new drugs, and the toxicity caused by the use of high doses of the drug are some possible ex...

  1. Argon Kα measurement on DIII endash D by Ross filters technique (abstract)

    International Nuclear Information System (INIS)

    Techniques to reduce the heat flux to the divertor plates in tokamak power plants and the consequent erosion of, and subsequent damage to the divertor target plates include the injection of impurities such as argon, that can dissipate the energy (through radiative or collisional processes) before it reaches the target plates. An important issue with this type of scheme is poisoning of the plasma core by the impurities introduced in the divertor region. Subsequently, there is a desire to measure the profiles of the injected impurities in the core. X-ray Ross filters with an effective narrow band pass centered on the argon Kα line at 3.2 keV, have been installed on two of the existing x-ray arrays on DIII endash D in order to help determine the argon concentration profiles. Emissivity profiles of the Kα lines and the emissivity profiles for the argon enhanced continuum can be inferred from the inverted filtered x-ray brightness signals if Te, ne, and Ar18+ profiles are known. The MIST code is used to couple the filtered x-ray signals to the time dependent measurements of Te and ne. Further, the Ar16+ profiles measured by charge transfer spectroscopy, are used as a constraint on the MIST code runs to calculate Ar18+ profiles and unfold the argon emissivity profiles. A discussion of the Ross filters, the DIII endash D argon data, and the data analysis scheme for inferring argon emissivity profiles will be discussed. Estimates of the total argon concentration in the core determined from this technique in DIII endash D argon puff experiments will be presented. copyright 1999 American Institute of Physics

  2. Nitro-Grela-type complexes containing iodides - robust and selective catalysts for olefin metathesis under challenging conditions.

    Science.gov (United States)

    Tracz, Andrzej; Matczak, Mateusz; Urbaniak, Katarzyna; Skowerski, Krzysztof

    2015-01-01

    Iodide-containing nitro-Grela-type catalysts have been synthesized and applied to ring closing metathesis (RCM) and cross metathesis (CM) reactions. These new catalysts have exhibited improved efficiency in the transformation of sterically, non-demanding alkenes. Additional steric hindrance in the vicinity of ruthenium related to the presence of iodides ensures enhanced catalyst stability. The benefits are most apparent under challenging conditions, such as very low reaction concentrations, protic solvents or with the occurrence of impurities. PMID:26664602

  3. Peroxide effects of iodide excess on mitochondria in Fischer rat thyroid cell line in the early period

    Institute of Scientific and Technical Information of China (English)

    李敏

    2014-01-01

    Objective To investigate the peroxide effects of iodide excess on mitochondria in Fischer rat thyroid cell line(FRTL)in the early period.Methods After treatment with 0.0 mmol/L(control group)or 0.1 mmol/L potassium iodide(KI)for 2,4 and 24 h,respectively,changes of mitochondrial superoxide formation were assayed by flow cytometry and fluorescence microscopy using mitochondria-targeted hydroethidine(Mito SOX).

  4. Chlorine Dioxide-Iodide-Methyl Acetoacetate Oscillation Reaction Investigated by UV-Vis and Online FTIR Spectrophotometric Method

    OpenAIRE

    Laishun Shi; Xiaomei Wang; Na Li; Jie Liu; Chunying Yan

    2012-01-01

    In order to study the chemical oscillatory behavior and mechanism of a new chlorine dioxide-iodide ion-methyl acetoacetate reaction system, a series of experiments were done by using UV-Vis and online FTIR spectrophotometric method. The initial concentrations of methyl acetoacetate, chlorine dioxide, potassium iodide, and sulfuric acid and the pH value have great influence on the oscillation observed at wavelength of 289 nm. There is a preoscillatory or induction period, and the amplitude and...

  5. Nitro-Grela-type complexes containing iodides – robust and selective catalysts for olefin metathesis under challenging conditions

    Directory of Open Access Journals (Sweden)

    Andrzej Tracz

    2015-10-01

    Full Text Available Iodide-containing nitro-Grela-type catalysts have been synthesized and applied to ring closing metathesis (RCM and cross metathesis (CM reactions. These new catalysts have exhibited improved efficiency in the transformation of sterically, non-demanding alkenes. Additional steric hindrance in the vicinity of ruthenium related to the presence of iodides ensures enhanced catalyst stability. The benefits are most apparent under challenging conditions, such as very low reaction concentrations, protic solvents or with the occurrence of impurities.

  6. Nitro-Grela-type complexes containing iodides – robust and selective catalysts for olefin metathesis under challenging conditions

    Science.gov (United States)

    Tracz, Andrzej; Matczak, Mateusz; Urbaniak, Katarzyna

    2015-01-01

    Summary Iodide-containing nitro-Grela-type catalysts have been synthesized and applied to ring closing metathesis (RCM) and cross metathesis (CM) reactions. These new catalysts have exhibited improved efficiency in the transformation of sterically, non-demanding alkenes. Additional steric hindrance in the vicinity of ruthenium related to the presence of iodides ensures enhanced catalyst stability. The benefits are most apparent under challenging conditions, such as very low reaction concentrations, protic solvents or with the occurrence of impurities. PMID:26664602

  7. Nitro-Grela-type complexes containing iodides - robust and selective catalysts for olefin metathesis under challenging conditions.

    Science.gov (United States)

    Tracz, Andrzej; Matczak, Mateusz; Urbaniak, Katarzyna; Skowerski, Krzysztof

    2015-01-01

    Iodide-containing nitro-Grela-type catalysts have been synthesized and applied to ring closing metathesis (RCM) and cross metathesis (CM) reactions. These new catalysts have exhibited improved efficiency in the transformation of sterically, non-demanding alkenes. Additional steric hindrance in the vicinity of ruthenium related to the presence of iodides ensures enhanced catalyst stability. The benefits are most apparent under challenging conditions, such as very low reaction concentrations, protic solvents or with the occurrence of impurities.

  8. Determination of microamounts of potassium in sodium iodide by atomic absorption spectrometry

    International Nuclear Information System (INIS)

    Microdetermination of potassium in sodium iodide was developed by the standard addition method. Twenty grams of sample were dissolved in 50 ml of water in a quartz beaker. To the solution, 30 ml of concentrated hydrochloric acid and 30 ml of 30% hydrogen peroxide were added, and evaporated to dryness. By this process sodium iodide was converted into sodium chloride. The cake thus obtained was dissolved in water and diluted to exactly 200 ml. To 25 ml aliquots of the solution, the standard potassium and cesium chloride solutions were added and diluted to 50 ml with water; the concentration of potassium was 0 -- 1 mg/l and that of cesium 4 mM. These solutions were introduced into an air-propane flame and the absorbances were measured at 769.9 nm. During the conversion reaction, hydrochloric acid was completely decomposed, and remained hydrogen peroxide had no influence for absorbance, and other backgrounds were negligible. The linear calibration curve was obtained in the range 0 -- 2 mg of potassium per liter. Potassium in sodium iodide was determined by this method within the coefficient of variation of +-(20 -- 3)% in the range (1.7 -- 32.5) ppm. (author)

  9. Iodide Sorption to Clays and the Relationship to Surface Charge and Clay Texture - 12356

    International Nuclear Information System (INIS)

    Iodine is assumed to behave conservatively in clay barriers around nuclear waste repositories and in natural sediments. Batch experiments tend to show little to no sorption, while in column experiments iodine is often retarded relative to tritiated water. Current surface complexation theory cannot account for negatively charged ion sorption to a negatively charged clay particle. Surface protonation and iodide sorption to clay minerals were examined using surface titrations and batch sorption experiments with a suite of clay minerals. Surface titrations were completed spanning a range of both pH values and ionic strengths. For reference, similar titrations were performed on pure forms of an Al-O powder. The titration curves were deconvoluted to attain the pKa distribution for each material at each ionic strength. The pKa distribution for the Al-O shows two distinct peaks at 4.8 and 7.5, which are invariant with ionic strength. The pKa distribution of clays was highly variable between the different minerals and as a function of ionic strength. Iodide sorption experiments were completed at high solid:solution ratios to exacerbate sorption properties. Palygorskite and kaolinite had the highest amount of iodide sorption and montmorillonite had the least. (authors)

  10. Study on multiphoton ionization dissociation processes of ethyl iodide at 800 nm laser radiation

    International Nuclear Information System (INIS)

    Multiphoton ionization-dissociation (MPID) process of ethyl iodide are studied at 800 nm femto-second laser, and time-of-flight mass spectrometer of ethyl iodide are obtained. The result of laser power index shows that the parent-ion mainly undergoes the 3 + 3 resonant enhanced multiphoton ionization (REMPI) process. The percentage of part fragment ions to the total ion current and the laser intensity dependence of the molecule are measured. Based on the experiment results, the multiphoton ionization- dissociation mechanism of ethyl iodide is discussed. The conclusion is that most of ion fragments are produced by C2H5I+ dissociation, this is consistent with the parent-ion dissociation staircase. The two possible dissociation channels of parent-ion are analyzed, but the C-I dissociation is the main channel. We also use Gaussian 03 calculated the energy change of the two channels with B3LYP/3-21G basis set, the theoretical results further demonstrated the experiment. (authors)

  11. Radiofrequency induction on sodium/iodide symporter expression of thyroid cancer

    Institute of Scientific and Technical Information of China (English)

    Youxin Tian; Qinjiang Liu; Yaqiong Ni

    2013-01-01

    Objective:The aim of this study was to investigate the ef ects of radiofrequency treatment on sodium/iodide symporter expression of thyroid cancer cells. Methods:In 29 thyroid cancer patients with low or no expression of soda\\iodide symporter, the radio frequency combined 131I therapy was used, the whole-body scintigraphy and serum Ig were detected before and after the radiofrequency treatment. Results:The whole-body scintigraphy showed that 4 cases (4/29) before radiofrequency treatment had positive iodine uptake, 19 cases (19/29) two weeks after radiofrequency treatment had the positive iodine uptake, 12 cases (12/29) four weeks after radiofrequency treatment had the positive iodine uptake. Four weeks after radiofrequency treatment, 5 cases had increased serum Ig levels, 17 cases had decreased serum Ig levels, 7 cases showed no change. 25 cases (25/29) were ef ective, 15 cases (15/29) were cured. Conclusion:The radiofrequency induced the non-expressed the sodium/iodide symporter of thyroid cancer cells regain the iodine intake ability, it improved the clinical ef icacy of 131I therapy in dedif erentiated thyroid cancer.

  12. Toxic impact of bromide and iodide on drinking water disinfected with chlorine or chloramines.

    Science.gov (United States)

    Yang, Yang; Komaki, Yukako; Kimura, Susana Y; Hu, Hong-Ying; Wagner, Elizabeth D; Mariñas, Benito J; Plewa, Michael J

    2014-10-21

    Disinfectants inactivate pathogens in source water; however, they also react with organic matter and bromide/iodide to form disinfection byproducts (DBPs). Although only a few DBP classes have been systematically analyzed for toxicity, iodinated and brominated DBPs tend to be the most toxic. The objectives of this research were (1) to determine if monochloramine (NH2Cl) disinfection generated drinking water with less toxicity than water disinfected with free chlorine (HOCl) and (2) to determine the impact of added bromide and iodide in conjunction with HOCl or NH2Cl disinfection on mammalian cell cytotoxicity and genomic DNA damage induction. Water disinfected with chlorine was less cytotoxic but more genotoxic than water disinfected with chloramine. For both disinfectants, the addition of Br(-) and I(-) increased cytotoxicity and genotoxicity with a greater response observed with NH2Cl disinfection. Both cytotoxicity and genotoxicity were highly correlated with TOBr and TOI. However, toxicity was weakly and inversely correlated with TOCl. Thus, the forcing agents for cytotoxicity and genotoxicity were the generation of brominated and iodinated DBPs rather than the formation of chlorinated DBPs. Disinfection practices need careful consideration especially when using source waters containing elevated bromide and iodide.

  13. Wetting and evaporation of argon nanodroplets on smooth and rough substrates: Molecular dynamics simulations

    Science.gov (United States)

    Li, Qun; Wang, Baohe; Chen, Yonggang; Zhao, Zongchang

    2016-10-01

    Wetting and evaporation behaviors of argon nanodroplets on smooth and rough substrates are studied using molecular dynamics simulations. Effects of interaction energy between solid and argon atoms on wetting and evaporation and differences between nanodroplets on smooth and rough substrates have been investigated. The results show that for both smooth and rough substrates, as the interaction energy between solid and argon atoms increases, the contact angle and total evaporation increase. For rough substrates, the variations of contact angle and contact radius during evaporation progress are much more complex and the total evaporation is much larger than that of smooth substrates.

  14. A Study of Dielectric Breakdown Along Insulators Surrounding Conductors in Liquid Argon

    CERN Document Server

    Lockwitz, Sarah

    2015-01-01

    High voltage breakdown in liquid argon is an important consideration in the design of liquid argon time projection chambers, which are often used as neutrino and dark matter detectors. We have made systematic measurements of breakdown voltages in liquid argon along insulators surrounding negative rod electrodes. The purpose of these tests is to understand the effects of materials, of breakdown path length, and of surface topology. We have found no material-specific effects other than those due to their permittivity. We have found no dependence on breakdown voltage on the length of the exposed insulator. A model for the breakdown mechanism is presented that can help inform future designs.

  15. Design Principles and Operational Results of the Cryogenic System for the ATLAS Liquid Argon Calorimeter

    CERN Document Server

    Fabre, C; Chalifour, M; Gonidec, G; Passardi, Giorgio; Petit, P; Pezzetti, M; Wicek, F

    2009-01-01

    The ATLAS liquid argon calorimeter housed in three independent cryostats containing a total argon volume of about 78 m3 has been installed in the underground cavern. The three detectors have been cooled down following stringent temperature gradient limits and have been filled with liquid argon. The cryostats are now in a stable condition for periods going up to almost two years. The temperature uniformity within each of the three detector volumes is found to be within 70 mK rms, while the temperature stability stays below 5 mK rms.

  16. A new ozone standard - The vapor pressure of ozone at liquid argon temperatures

    Science.gov (United States)

    Mauersberger, K.; Hanson, D.; Morton, J.

    1985-01-01

    The vapor pressure of ozone has been measured at liquid argon temperatures. At the normal boiling point of argon (-185.9 C) an ozone pressure of 0.0405 torr was obtained with an accuracy of + or - 1.5 percent. Increases and decreases in liquid argon temperatures raised and lowered the ozone vapor pressure, respectively. During the vapor pressure measurements the purity of ozone was monitored with a mass spectrometer. The proposed ozone standard will considerably improve the calibration of experiments for atmospheric research, the determination of absorption cross sections and other laboratory ozone studies.

  17. Surface compositional changes in GaAs subjected to argon plasma treatment

    Energy Technology Data Exchange (ETDEWEB)

    Surdu-Bob, C.C.; Sullivan, J.L.; Saied, S.O.; Layberry, R.; Aflori, M

    2002-12-30

    X-ray photoelectron spectroscopy (XPS) has been employed to study surface compositional changes in GaAs (1 0 0) subjected to argon plasma treatment. The experimental results have been explained in terms of predicted argon ion energies, measured ion densities and etch rates. A model is proposed for the processes taking place at the surface of GaAs in terms of segregation, sputtering and surface relaxation. Stopping and range of ions in matter (SRIM) code has also been employedan aid to identification of the mechanisms responsible for the compositional changes. Argon plasma treatment induced surface oxidation at very low energies and sputtering and surface damage with increasing energy.

  18. Changes in a surface of polycrystalline aluminum upon bombardment with argon ions

    Science.gov (United States)

    Ashkhotov, O. G.; Ashkhotova, I. B.; Bliev, A. P.; Magkoev, T. T.; Krymshokalova, D. A.

    2014-10-01

    The interaction between argon ions and a natural oxide layer of polycrystalline aluminum is studied via Auger electron (AE) and electron energy loss (EEL) spectroscopy. It is found that bombardment with argon ions whose energy is lower than the Al2O3 sputtering threshold results in the accumulation of bombarding ions in interstitial surface voids, thus forming a supersaturated solid solution of target atoms and bombarding ions of argon and nitrogen entrapped by the ion beam from the residual gas of the working chamber of the spectrometer.

  19. Simple and rapid determination of iodide in table salt by stripping potentiometry at a carbon-paste electrode.

    Science.gov (United States)

    Svancara, Ivan; Ogorevc, Bozidar; Nović, Milko; Vytras, Karel

    2002-04-01

    A simple and rapid procedure, utilising constant-current stripping analysis (CCSA) at a carbon-paste electrode containing tricresyl phosphate as a pasting liquid (TCP-CPE), has been developed for the determination of iodide in table salt. Because of a synergistic accumulation mechanism based on ion-pairing and extraction of iodide in combination with electrolytic pretreatment of the TCP-CPE, the method is selective for iodide and enables direct determination of iodide in samples of table salt containing anti-caking agents such as K(4)[Fe(CN)(6)] (food additive "E 536") or MgO. The iodide content (calculated as KI) can be determined in a concentration range of 2 to 100 mg kg(-1) salt, with a detection limit (S/N=3) of 1 mg kg(-1), and a recovery from 90 to 115%. The proposed method has been used to determine iodide in several types of artificially iodised table salt and in one sample of natural sea salt. The results obtained agreed well with those obtained by use of three independent reference methods (titration, spectrophotometry, and ICP-MS) used to validate the CCSA method, indicating that the developed method is applicable as a routine procedure for rapid testing in salt production process control and in the analysis of marketed table salts.

  20. The use of mercuric iodide in instruments for safeguards and non-proliferation applications

    International Nuclear Information System (INIS)

    Mercuric Iodide is a material exceptionally suited for solid state detectors operating at room temperature. The high density and the high atomic numbers of the constituent elements provide a large absorption factor and a high full-energy-peak efficiency at gamma ray energies. The large electronic bandgap results in a very high resistivity and therefore a low leakage current at temperatures within and outside the personal comfort range. Constellation Technology has developed the technology to grow large, high quality crystals from mercuric iodide. Spectrometry grade detectors with dimensions of 25 mm x 25 mm x 3 mm and with an energy resolution of approximately 3% FWHM at 662 keV can be fabricated from these mercuric iodide crystals. The resolution of this detector approximately 1.8% FWHM and the peak-to-valley ratio is larger than twelve. Standard semi-Gaussian processing and no pulse-shape discrimination was used. These detectors can be conveniently incorporated into hand-held instruments to detect weak sources or heavily shielded sources. Previous measurements have shown that the Minimum Detectable Activity (MDA) of a 3 mm thick mercuric iodide detector with dimensions as given above is about 10% less than the MDA of a 50 mm x 50 mm sodium iodide detector, due to the superior energy resolution. Software methods are being developed to improve the identification of weak sources against a large background. Results of these measurements will be presented. Smaller detectors can be used in safeguards applications where the intensity of the radiation is relatively high. The spectral resolution of the detectors is high enough to clearly identify the significant energy lines in the spectra of stored uranium and plutonium. The shape of the spectral peaks is constant over a large range of energies so that existing software systems can be used to analyze the spectra. The small size, ruggedness, temperature stability and high efficiency of these detectors makes them good

  1. Reduction of stimulated sodium iodide symporter expression by estrogen receptor ligands in breast cancer cells

    Energy Technology Data Exchange (ETDEWEB)

    Cheong, Su-Jin; Jang, DooRye; Jeong, Hwan-Jeong; Lim, Seok Tae; Sohn, Myung-Hee [Department of Nuclear Medicine, Cyclotron Research Center, Research Institute of Clinical Medicine, Chonbuk National University Medical School, Jeonju, Jeonbuk 561-756 (Korea, Republic of); Katzenellenbogen, John A., E-mail: jkatzene@illinois.ed [Department of Chemistry, University of Illinois, Urbana, IL 61801 (United States); Kim, Dong Wook, E-mail: kimdw@chonbuk.ac.k [Department of Nuclear Medicine, Cyclotron Research Center, Research Institute of Clinical Medicine, Chonbuk National University Medical School, Jeonju, Jeonbuk 561-756 (Korea, Republic of)

    2011-02-15

    Purpose: The sodium iodide symporter (NIS) mediates active iodide uptake in lactating breast tissue, and when its levels are enhanced by all-trans retinoic acid (atRA), NIS has been proposed as a target for the imaging and radiotherapy of breast cancer. Importantly, the estrogen receptor {alpha} (ER{alpha}) is an important regulator of atRA induced NIS gene expression in breast cancer cells. In this study, we investigated the effect of an ER agonist (17{beta}-estradiol, E{sub 2}) or antagonist [trans-hydroxytamoxifen (TOT) or raloxifene (RAL)] treatment on the regulation of NIS gene expression and iodide uptake in an ER{alpha}-positive breast cancer (MCF-7) model. Methods: NIS functional activity was measured in vitro by {sup 125}I uptake assay after incubation with E{sub 2} (from 10{sup -15} to 10{sup -5} M), TOT (from 5x10{sup -8} to 5x10{sup -6} M), or RAL (from 5x10{sup -8} to 5x10{sup -6} M) in the presence or absence of atRA (10{sup -7} M). Under the same conditions, NIS mRNA expression was examined by reverse transcriptase polymerase chain reaction. Athymic mice with MCF-7 xenograft tumors were treated with atRA alone or atRA together with E{sub 2} to evaluate the change of {sup 125}I uptake in tumor tissues in vivo. Results: In the iodide uptake study in cells, E{sub 2}, TOT, or RAL treatment alone did not stimulate {sup 125}I uptake. However, when iodide uptake was stimulated by atRA, cotreatment with E{sub 2}, TOT or RAL decreased {sup 125}I uptake in a concentration-dependent manner. The hormone effects on NIS mRNA expression levels in MCF-7 cells were similar. The results of the in vivo biodistribution study showed that {sup 125}I uptake was reduced 50% in tumor tissues of mice treated with atRA/E{sub 2} as compared to tumors treated only with atRA. Conclusion: Our results suggest that combination treatment of atRA and ER ligands could limit the functional activity of the NIS gene induced by atRA, thereby compromising its use as a target for diagnosis

  2. Self-assembled heterogeneous argon/neon core-shell clusters studied by photoelectron spectroscopy.

    Science.gov (United States)

    Lundwall, M; Pokapanich, W; Bergersen, H; Lindblad, A; Rander, T; Ohrwall, G; Tchaplyguine, M; Barth, S; Hergenhahn, U; Svensson, S; Björneholm, O

    2007-06-01

    Clusters formed by a coexpansion process of argon and neon have been studied using synchrotron radiation. Electrons from interatomic Coulombic decay as well as ultraviolet and x-ray photoelectron spectroscopy were used to determine the heterogeneous nature of the clusters and the cluster structure. Binary clusters of argon and neon produced by coexpansion are shown to exhibit a core-shell structure placing argon in the core and neon in the outer shells. Furthermore, the authors show that 2 ML of neon on the argon core is sufficient for neon valence band formation resembling the neon solid. For 1 ML of neon the authors observe a bandwidth narrowing to about half of the bulk value.

  3. Surface Chemistry of Polymers Physical Adsorption of Nitrogen, Argon, Sulfur Dioxide and Neopentane on Polyvinylidene Fluoride

    OpenAIRE

    Houriet, Jean-Philippe; Ghiste, Patrick; Stoeckli, Fritz

    2007-01-01

    The adsorption of nitrogen, argon, sulfur dioxide and neopentane on polyvinylidene fluoride has been measured by static methods and by gas-solid chromatography. The polymer has a homogeneous surface of low energy, which is not significantly affected by heating.

  4. Surface modification of polypropylene using argon plasma: Statistical optimization of the process variables

    International Nuclear Information System (INIS)

    Low pressure plasma treatment using radiofrequency (rf) discharge of argon gas was employed to improve the hydrophilicity of polypropylene. The effects of argon plasma on the wettability, surface chemistry and surface morphology of polypropylene were studied using static contact angle measurements, Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and atomic force microscopy (AFM). Increase in surface energy of polypropylene was observed as a result of argon plasma treatment. SEM and AFM images revealed the increased surface roughness. A set of identified process variables (rf power, pressure, argon flow rate and time) were used in this study and were optimized using central composite design (CCD) of response surface methodology (RSM). A statistical model was developed to represent the surface energy in terms of the process variables mentioned above. Accuracy of the model was verified and found to be high.

  5. Simulations of argon accident scenarios in the ATLAS experimental cavern a safety analysis

    CERN Document Server

    Balda, F

    2002-01-01

    Some characteristic accidents in the ATLAS experimental cavern (UX15) are simulated by means of STAR-CD, a code using the "Finite-Volume" method. These accidents involve different liquid argon leaks from the barrel cryostat of the detector, thus causing the dispersion of the argon into the Muon Chamber region and the evaporation of the liquid. The subsequent temperature gradients and distribution of argon concentrations, as well as their evolution in time are simulated and discussed, with the purpose of analysing the dangers related to asphyxiation and to contact with cryogenic fluids for the working personnel. A summary of the theory that stands behind the code is also given. In order to validate the models, an experimental test on a liquid argon spill performed earlier is simulated, showing that the program is able to output reliable results. At the end, some safety-related recommendations are listed.

  6. Pose Measurement Performance of the Argon Relative Navigation Sensor Suite in Simulated Flight Conditions

    Science.gov (United States)

    Galante, Joseph M.; Eepoel, John Van; Strube, Matt; Gill, Nat; Gonzalez, Marcelo; Hyslop, Andrew; Patrick, Bryan

    2012-01-01

    Argon is a flight-ready sensor suite with two visual cameras, a flash LIDAR, an on- board flight computer, and associated electronics. Argon was designed to provide sensing capabilities for relative navigation during proximity, rendezvous, and docking operations between spacecraft. A rigorous ground test campaign assessed the performance capability of the Argon navigation suite to measure the relative pose of high-fidelity satellite mock-ups during a variety of simulated rendezvous and proximity maneuvers facilitated by robot manipulators in a variety of lighting conditions representative of the orbital environment. A brief description of the Argon suite and test setup are given as well as an analysis of the performance of the system in simulated proximity and rendezvous operations.

  7. Formation and characterization of magnesium bisozonide and carbonyl complexes in solid argon.

    Science.gov (United States)

    Wang, Guanjun; Gong, Yu; Zhang, Qingqing; Zhou, Mingfei

    2010-10-14

    The reactions of magnesium atoms with dioxygen and dioxygen/carbon monoxide mixture have been investigated by matrix isolation infrared absorption spectroscopy. Magnesium atoms react with dioxygen in solid argon to form the inserted MgO(2) molecules under UV excitation, which were previously characterized. Annealing allows the dioxygen molecules to diffuse and to react with MgO(2) and form the magnesium bisozonide complex, Mg(O(3))(2), which is proposed to be coordinated by two argon atoms in solid argon matrix. The Mg(O(3))(2)(Ar)(2) complex is characterized to have two equivalent side-on bonded ozonide ligands with a D(2h) symmetry. The coordinated argon atoms can be replaced by carbon monoxide to give the magnesium bisozonide dicarbonyl complex, Mg(O(3))(2)(CO)(2), a neutral magnesium carbonyl complex with CO binding to the Mg(2+) center. PMID:20857987

  8. Dynamic range compression in a liquid argon calorimeter

    Energy Technology Data Exchange (ETDEWEB)

    Cleland, W.E. [Univ. of Pittsburgh, PA (United States); Lissauer, D.; Radeka, V.; Rescia, S.; Takai, H. [Brookhaven National Lab., Upton, NY (United States); Wingerter-Seez, I. [LAPP, Annecy-le-Vieux (France)

    1996-12-31

    The anticipated range of particle energies at the LHC, coupled with the need for precision, low noise calorimetry makes severe demands on the dynamic range of the calorimeter readout. A common approach to this problem is to use shapers with two or more gain scales. In this paper, the authors describe their experience with a new approach in which a preamplifier with dynamic gain compression is used. An unavoidable consequence of dynamic gain adjustment is that the peaking time of the shaper output signal becomes amplitude dependent. The authors have carried out a test of such a readout system in the RD3 calorimeter, a liquid argon device with accordion geometry. The calibration system is used to determine both the gain of the individual channels as well as to map the shape of the waveform as a function of signal amplitude. A new procedure for waveform analysis, in which the fitted parameters describe the impulse response of the system, permits a straightforward translation of the calibration waveform to the waveform generated by a particle crossing the ionization gap. They find that the linearity and resolution of the calorimeter is equivalent to that obtained with linear preamplifiers, up to an energy of 200 GeV.

  9. Coherent set of electron cross sections for argon

    Science.gov (United States)

    Alves, L. L.; Ferreira, C. M.

    2011-10-01

    This paper presents a coherent set of electron impact cross sections for argon (elastic momentum-transfer, inelastic for the excitation of 37 levels Ar(4s,4p,3d,5p,4d,6s) and ionization), which was recently uploaded onto the LXcat IST-Lisbon database. The cross section set was validated by comparing calculated swarm parameters (electron mobility and characteristic energy) and rate coefficients (Townsend ionization coefficient and direct + cascade excitation coefficients to the 4s and 4p states) with available experimental data, for E / N = 10-4 - 100 Td and Tg = 300, 77 K. The validation procedure involves the solution to the homogeneous two-term electron Boltzmann equation, resorting to three different solvers: (i) IST-Lisbon's (ii) BOLSIG+ (v1.2) with LXcat; (iii) BOLSIG+ (v1.23). The results obtained with these solvers are compared to evidence the importance of certain numerical features related with both the energy-grid (number of points, grid-type and maximum energy value) and the interpolation scheme adopted for the cross sections. In particular, the latter can cause a 6% variation on the values of swarm parameters at intermediate E/Ns.

  10. An update of argon inelastic cross sections for plasma discharges

    International Nuclear Information System (INIS)

    This paper proposes a coherent set of electron impact inelastic cross sections for argon, based on recent experimental measurements. The updated set is validated by comparing calculated swarm parameters and rate coefficients (obtained by solving the two-term approximation electron Boltzmann equation) with available experimental data. This validation procedure is usually adopted when the cross section set is to be later used in plasma discharge modelling. Simulation results for the electron drift velocity and characteristic energy are in very good agreement with experimental values of these quantities. Calculations, using cross section sets proposed by different authors, of the total (direct + cascade) excitation coefficients to the 4s and 4p states, and of the Townsend ionization coefficient, show that the present set ensures the best overall agreement with measured values. The agreement is particularly good for the excitation coefficient to metastable 4s'[1/2]0 and the Townsend ionization coefficient, which are probably the most relevant electron macroscopic coefficients in the modelling of discharge plasmas

  11. Argon defect complexes in low energy Ar irradiated molybdenum

    Energy Technology Data Exchange (ETDEWEB)

    van Veen, A.; Buters, W.T.M.; van der Kolk, G.J.; Caspers, L.M. (Interuniversitair Reactor Instituut, Delft (Netherlands)); Armstrong, T.R. (Victoria Univ., Wellington (New Zealand). Dept. of Physics)

    1982-03-15

    Thermal desorption spectrometry has been used to study the defects created in Mo irradiated along the <110> direction with Ar ions ranging in energy from 0.1 to 2 keV. In addition to monitoring the release of the implanted Ar, additional information has been obtained by decoration of the defects with low energy helium and subsequent monitoring of the helium release. The studies show evidence that the Ar can be trapped in both substitutional sites and in a configuration in which the Ar is associated with vacancies (ArVsub(n), n >= 2). Most of the Ar implanted at high energy is released at approx. equal to 1500 K by thermal vacancy assisted diffusion. Argon trapped closer to the surface is released at lower temperatures via at least three different surface related release mechanisms. Additional results are presented on the interaction of self interstitial atoms (introduced by 100 eV Xe bombardment) with the Ar defects. Substitutional Ar is found to convert to interstitial Ar which seems to be mobile at room temperature. The Ar-vacancy complexes are found to be reduced to substitutional Ar. The results of atomistic calculations of the release mechanisms will also be presented.

  12. Scintillation Light from Cosmic-Ray Muons in Liquid Argon

    CERN Document Server

    Whittington, Denver

    2014-01-01

    This paper reports the results of the first experiment to directly measure the properties of the scintillation light generated by minimum ionizing cosmic-ray muons in liquid argon. Scintillation light from these muons is of value to studies of weakly-interacting particles in neutrino experiments and dark matter searches, as well as for particle identification. The experiment was carried out at the TallBo facility at Fermilab using prototype light guides and electronics developed for the Long-Baseline Neutrino Experiment. Analysis of the time-resolved structure of the scintillation light from cosmic-ray muons gives $\\langle \\tau_{\\text{T}}\\rangle = 1.43 \\pm 0.04~\\text{(stat.)} \\pm 0.007~\\text{(sys.)}~\\mu$s for the triplet light decay time constant. The ratio of singlet to triplet light measured using surface-coated light guides is $R = 0.39 \\pm 0.01~\\text{(stat.)} \\pm 0.008~\\text{(sys.)}$. There is some evidence that this value is not consistent with $R$ for minimum ionizing electrons. However, the value for $...

  13. State-selective radiative recombination cross sections of argon ions

    International Nuclear Information System (INIS)

    The n-, (n,l)- and fine-structure level state-selective radiative recombinations (RR) cross sections of argon ions Ar18+,Ar13+,Ar7+ and Ar+ are obtained with the semi-classical Kramer formula, the relativistic self-consistent field (RSCF) method and the relativistic configuration interaction (RCI) method. It is found that for the highly charged ions with few electrons, the cross sections calculated with these three methods are in good agreement with each other. But as the number of electrons increases, the Kramer formula deviates from the RSCF and RCI results. For instance, when the energy of the incident electron is larger than 100 eV, the n-state selective cross sections of Ar7+ calculated from the Kramer formula are underestimated for more than 50%. The RSCF results are in general agreement with the RCI results. However, for the low charged ions, a clear distinction appears due to the strong configuration interaction, especially near the Cooper minimum. The n-resolved (n≤10) and total Maxwellian averaged rate coefficients are calculated, and the analytic fitting parameters are also provided. -- Highlights: ► The RR cross sections of Ar18+, Ar13+, Ar7+ and Ar+ are obtained. ► The Kramer formula, the relativistic self-consistent field and RCI methods are used. ► Results from three methods are compared with each other.

  14. Electronics calibration board for the ATLAS liquid argon calorimeters

    International Nuclear Information System (INIS)

    To calibrate the energy response of the ATLAS liquid argon calorimeter, an electronics calibration board has been designed; it delivers a signal whose shape is close to the calorimeter ionization current signal with amplitude up to 100 mA in 50 Ω with 16 bit dynamic range. The amplitude of this signal is designed to be uniform over all calorimeters channels, stable in time and with an integral linearity much better that the electronics readout. The various R and D phases and most of the difficulties met are discussed and illustrated by many measurements. The custom design circuits are described and the layout of the ATLAS calibration board presented. The procedure used to qualify the boards is explained and the performance obtained illustrated: a dynamic range up to 3 TeV in three energy scales with an integral linearity better than 0.1% in each of them, a response uniformity better than 0.2% and a stability better than 0.1%. The performance of the board is well within the ATLAS requirements. Finally, in situ measurements done on the ATLAS calorimeter are shown to validate these performances

  15. Methane from benzene in argon dielectric barrier discharge

    International Nuclear Information System (INIS)

    Highlights: ► Efficient on-line conversion of benzene to methane at room temperature. ► Absence of other H-atom donor suggests new type of chemistry. ► For parent loss > 90%, methane yield was ∼40% of limit due to H-atom availability. ► Surface moisture contributed ·OH radical for trace phenolic products’ formation. ► This method may emerge as an exploitable tactic for pollutants’ usable alterations. -- Abstract: A first-time account of direct, on-line, instantaneous and efficient chemical conversion of gas phase benzene to methane in argon Dielectric Barrier Discharge (DBD) is presented. In the absence of another overt hydrogen-donating source, potency of analogous parents toward methane generation is found to follow the order: benzene > toluene > p-xylene. Simultaneous production of trace amounts of phenolic surface deposits suggest (a) prompt decomposition of the parent molecules, including a large fraction yielding atomic transients (H-atom), (b) continuous and appropriate recombination of such parts, and (c) trace moisture in parent contributing ·OH radicals and additional H-atoms, which suitably react with the unreacted fraction of the parent, and also other intermediates. Results highlight Ar DBD to be a simple and exploitable technology for transforming undesirable hazardous aromatics to usable/useful low molecular weight open-chain products following the principles of green chemistry and engineering

  16. Optically Forbidden Excitations of 3s Electron of Argon by Fast Electron Impact

    Institute of Scientific and Technical Information of China (English)

    朱林繁; 成华东; 刘小井; 田鹏; 苑震生; 李文斌; 徐克尊

    2003-01-01

    The electron energy loss spectrum of argon in the energy region of 24.5-30.5eV was measured at 2.5 keV impact energy. The line profile parameters of the optically forbidden excitations of 3s-1ns (n = 4-6) and 3s-1nd (n = 3-7) of argon, I.e.,Eγ,Г,q and p,were determined.

  17. Benchmarking TPB-coated Light Guides for Liquid Argon TPC Light Detection Systems

    OpenAIRE

    Baptista, B.; Bugel, L.; Chiu, C; Conrad, J. M.; Ignarra, C. M.; Jones, B. J. P.; Katori, T.; Mufson, S.

    2012-01-01

    Scintillation light from liquid argon is produced at 128 nm and thus must be shifted to visible wavelengths in light detection systems used for Liquid Argon Time Projection Chambers (LArTPCs). To date, designs have employed tetraphenyl butadiene (TPB) coatings on photomultiplier tubes (PMTs) or plates placed in front of the PMTs. Recently, a new approach using TPB-coated light guides was proposed. In this paper, we show that the response of lightguides coated with TPB in a UV Transmitting (UV...

  18. TPB-coated Light Guides for Liquid Argon TPC Light Detection Systems

    CERN Document Server

    Ignarra, C M

    2013-01-01

    Light detection systems in Liquid Argon Time Projection Chambers (LArTPCs) require the detection of the 128 nm light produced during argon scintillation. Most detectors use Tetraphenyl Butadiene (TPB) to shift the wavelength of the light into a range visible to Photomultiplier Tubes (PMTs). These proceedings summarize characterizations of light-guides coated with a matrix of TPB in UV transmitting acrylic which are more compact than existing LArTPC light collection systems.

  19. TPB-coated light guides for liquid argon TPC light detection systems

    Science.gov (United States)

    Ignarra, C. M.

    2013-10-01

    Light detection systems in Liquid Argon Time Projection Chambers (LArTPCs) require the detection of the 128 nm light produced during argon scintillation. Most detectors use Tetraphenyl Butadiene (TPB) to shift the wavelength of the light into a range visible to Photomultiplier Tubes (PMTs). These proceedings summarize characterizations of light-guides coated with a matrix of TPB in UV transmitting acrylic which are more compact than existing LArTPC light collection systems.

  20. Effect of Ginkgo biloba on the lesions induced by retinal argon laser photocoagulation in rabbits

    Energy Technology Data Exchange (ETDEWEB)

    Clairambault, P.; Pairault, C.; Droy-Lefaix, M.T.; Magnier, B.; Magnier, M.

    1986-01-09

    In rabbits, retinal argon laser photocoagulation disrupts the arrangement of cell layers and produces interstitial edema. Photochemical and thermal energy is released with production of free oxygenated radicals that are responsible for destruction of cell membranes. Retinal argon laser photocoagulation in rabbits was used as a pharmacologic model to evaluate the protective effect of EGB 761 against membrane lesions and edema. As a strong free radicals scavengers, EGB 761 confirms its protective action on cells membranes and its anti-edema effect.

  1. Configurational Entropy,Diffusivity and Potential Energy Landscape in Liquid Argon

    Institute of Scientific and Technical Information of China (English)

    DUAN Yong-Ping; MA Cong-Xiao; LI Jia-Yun; LI Cong; WANG Dan; LI Mei-Li; SUN Min-Hua

    2009-01-01

    The configurational entropy, diffusion coefficient, dynamics and thermodynamics fragility indices of liquid argon are calculated using molecular dynamics simulations at two densities. The relationship between dynamics and thermodynamics properties is studied. The diffusion coefficient depends linearly on configurational entropy, which is consistent with the hypothesis of Adam-Gibbs. The consistence of dynamics and thermodynamics fragility indices demonstrates that dynamical behaviour is governed by thermodynamics behaviour in glass transition of liquid argon.

  2. Effect of Ginkgo biloba on the lesions induced by retinal argon laser photocoagulation in rabbits

    International Nuclear Information System (INIS)

    In rabbits, retinal argon laser photocoagulation disrupts the arrangement of cell layers and produces interstitial edema. Photochemical and thermal energy is released with production of free oxygenated radicals that are responsible for destruction of cell membranes. Retinal argon laser photocoagulation in rabbits was used as a pharmacologic model to evaluate the protective effect of EGB 761 against membrane lesions and edema. As a strong free radicals scavengers, EGB 761 confirms its protective action on cells membranes and its anti-edema effect

  3. A correction to Birks' Law in liquid argon ionization chamber simulations for highly ionizing particles

    International Nuclear Information System (INIS)

    We present a study of the performance of Birks' Law in liquid argon ionization chamber simulations as applied to highly ionizing particles, such as particles with multiple electric charges or with magnetic charge. We used Birks' Law to model recombination effects in a GEANT4 simulation of heavy ions in a liquid argon calorimeter. We then compared the simulation to published heavy-ion data to extract a highly ionizing particle correction to Birks' Law.

  4. LArGe: Background suppression using liquid argon (LAr) scintillation for 0$\

    CERN Document Server

    Marco, M D; Schönert, S

    2007-01-01

    Measurements with a bare p-type high purity germanium diode (HPGe) submerged in a 19 kg liquid argon (LAr) scintillation detector at MPIK Heidelberg are reported. The liquid argon--germanium system (LArGe) is operated as a 4$\\pi$ anti-Compton spectrometer to suppress backgrounds in the HPGe. This R&D is carried out in the framework of the GERDA experiment which searches for 0$\

  5. Discovery of photospheric argon in very hot central stars of planetary nebulae and white dwarfs

    CERN Document Server

    Werner, K; Kruk, J W

    2007-01-01

    We report the first discovery of argon in hot evolved stars and white dwarfs. We have identified the ArVII 1063.55A line in some of the hottest known (Teff=95000-110000 K) central stars of planetary nebulae and (pre-) white dwarfs of various spectral type. We determine the argon abundance and compare it to theoretical predictions from stellar evolution theory as well as from diffusion calculations. We analyze high-resolution spectra taken with the Far Ultraviolet Spectroscopic Explorer. We use non-LTE line-blanketed model atmospheres and perform line-formation calculations to compute synthetic argon line profiles. We find a solar argon abundance in the H-rich central star NGC1360 and in the H-deficient PG1159 star PG1424+535. This confirms stellar evolution modeling that predicts that the argon abundance remains almost unaffected by nucleosynthesis. For the DAO-type central star NGC7293 and the hot DA white dwarfs PG0948+534 and REJ1738+669 we find argon abundances that are up to three orders of magnitude sma...

  6. Numerical study of breakdown pattern induced by an intense microwave under nitrogen and argon gases

    Science.gov (United States)

    Takahashi, Masayuki; Ohnishi, Naofumi

    2016-07-01

    Filamentary plasma induced by microwave beam irradiation was reproduced in nitrogen and argon by combining fluid or particle plasma models with electromagnetic wave propagation. Transport coefficients used in the fluid model are estimated from particle simulation to maintain consistency of the breakdown structure between the fluid and particle models. A discrete structure was obtained using the one-dimensional (1D) fluid model, because a standing wave is generated in front of the plasma when the incident microwave beam is reflected by the overcritical plasma, which agrees with the breakdown structure obtained using the 1D particle model. A 2D plasma filament was also reproduced using the fluid model in nitrogen and argon. Reflection of the incident microwave in argon becomes stronger than that in nitrogen because of the denser argon plasma. Change in filament shape is induced in argon because the electric field is deformed at the plasma tip owing to stronger wave reflection from the neighboring filament. The propagation speed of the plasma front becomes larger in argon breakdown because of the larger ionization frequency and the larger diffusion coefficient.

  7. Condensed argon isentropic compression with ultrahigh magnetic field pressure: Experimental design. Post-shot report

    Energy Technology Data Exchange (ETDEWEB)

    Bykov, A.I.; Boriskov, G.V.; Dolotenko, M.I. [All-Russian Research Inst. of Experimental Physics, Sarov (Russian Federation)] [and others

    1996-12-31

    This report continues the series of work devoted to experimental study of a high-dense condensed argon state. Remember that according to work of Kwon et. al., hexagonal close-packed structure is profitable in terms of energy rather than face-centered argon structure (stable with zero pressure). What is most interesting and intriguing here is the issue of possible argon metallization, when it is compressed up to the densities more than 9.17 g/cm{sup 3}. In the experiment of 1995 (the arrangement and data are described in a cited reference) the authors recorded appearance of conductivity in argon, which is non-conductive in the initial state, when it is compressed more than a factor of four. The peak value of argon specific conductivity recorded in this experiment did not exceed 10 (Ohm x cm){sup {minus}1}. This value of conductivity is characteristic of semiconductors, but not metals, which have 10{sup 4} (Ohm x cm){sup {minus}1}. At this stage of the work the main attention is paid to recording of argon conductive state and studying the possibilities of multiframed radiography of the sample in the compressed state.

  8. Low radioactivity argon dark matter search results from the DarkSide-50 experiment

    CERN Document Server

    Agnes, P; Albuquerque, I F M; Alexander, T; Alton, A K; Arisaka, K; Back, H O; Baldin, B; Biery, K; Bonfini, G; Bossa, M; Bottino, B; Brigatti, A; Brodsky, J; Budano, F; Bussino, S; Cadeddu, M; Cadonati, L; Cadoni, M; Calaprice, F; Canci, N; Candela, A; Cao, H; Cariello, M; Carlini, M; Catalanotti, S; Cavalcante, P; Chepurnov, A; Cocco, A G; Covone, G; Crippa, L; D'Angelo, D; D'Incecco, M; Davini, S; De Cecco, S; De Deo, M; De Vincenzi, M; Derbin, A; Devoto, 25 A; Di Eusanio, F; Di Pietro, G; Edkins, E; Empl, A; Fan, A; Fiorillo, G; Fomenko, K; Forster, G; Franco, D; Gabriele, F; Galbiati, C; Giganti, C; Goretti, A M; Granato, F; Grandi, L; Gromov, M; Guan, M; Guardincerri, Y; Hackett, B R; Herner, K; Hungerford, E V; Ianni, Al; Ianni, An; James, I; Jollet, C; Keeter, K; Kendziora, C L; Kobychev, V; Koh, G; Korablev, D; Korga, G; Kubankin, A; Li, X; Lissia, M; Lombardi, P; Luitz, S; Ma, Y; Machulin, I N; Mandarano, A; Mari, S M; Maricic, J; Marini, L; Martoff, C J; Meregaglia, A; Meyers, P D; Miletic, T; Milincic, R; Montanari, D; Monte, A; Montuschi, M; Monzani, M; Mosteiro, P; Mount, B J; Muratova, V N; Musico, P; Napolitano, J; Nelson, A; Odrowski, S; Orsini, M; Ortica, F; Pagani, L; Pallavicini, M; Pantic, E; Parmeggiano, S; Pelczar, K; Pelliccia, N; Perasso, S; Pocar, A; Pordes, S; Pugachev, D A; Qian, H; Randle, K; Ranucci, G; Razeto, A; Reinhold, B; Renshaw, A L; Romani, A; Rossi, B; Rossi, N; Rountree, D; Sablone, D; Saggese, P; Saldanha, R; Sands, W; Sangiorgio, S; Savarese, C; Segreto, E; Semenov, D A; Shields, E; Singh, P N; Skorokhvatov, M D; Smallcomb, M; Smirnov, O; Sotnikov, A; Stanford, C; Suvorov, Y; Tartaglia, R; Tatarowicz, J; Testera, G; Tonazzo, A; Trinchese, P; Unzhakov, E V; Vishneva, A; Vogelaar, B; Wada, M; Walker, S; Wang, H; Wang, Y; Watson, A W; Westerdale, S; Wilhelmi, J; Wojcik, M M; Xiang, X; Xu, J; Yang, C; Yoo, J; Zavatarelli, S; Zec, A; Zhong, W; Zhu, C; Zuzel, G

    2015-01-01

    The DarkSide-50 dark matter search reports the first results obtained using a target of low-radioactivity argon extracted from underground sources. The experiment is located at the Laboratori Nazionali del Gran Sasso and uses a two-phase time projection chamber as a detector. A total of 155 kg of low radioactivity argon has been obtained, and we have determined that underground argon is depleted in Ar-39 by a factor (1.4 +- 0.2) x 10^3 relative to atmospheric argon. The underground argon was also found to contain (2.05 +- 0.13) mBq/kg of Kr-85. We found no evidence for dark matter in the form of WIMPs in 70.9 live-days of data with a fiducial mass of (36.9 +- 0.6) kg. When combined with our preceding search with an atmospheric argon target, we set a 90 % C.L. upper limit on the WIMP-nucleon spin-independent cross section of 2.0 x 10^-44 cm^2 (8.6 x 10^-44 cm^2, 8.0 x 10^-43 cm^2 ) for a WIMP mass of 100 GeV/c^2 (1 TeV/c^2 , 10 TeV/c^2 ).

  9. Results from the first use of low radioactivity argon in a dark matter search

    Energy Technology Data Exchange (ETDEWEB)

    Agnes, P. [Universite Paris Diderot (France). et al.

    2016-04-08

    Liquid argon is a bright scintillator with potent particle identification properties, making it an attractive target for direct-detection dark matter searches. The DarkSide-50 dark matter search here reports the first WIMP search results obtained using a target of low-radioactivity argon. DarkSide-50 is a dark matter detector, using two-phase liquid argon time projection chamber, located at the Laboratori Nazionali del Gran Sasso. The underground argon is shown to contain Ar-39 at a level reduced by a factor (1.4 +- 0.2) x 103 relative to atmospheric argon. We report a background-free null result from (2616 +- 43) kg d of data, accumulated over 70.9 live-days. When combined with our previous search using an atmospheric argon, the 90 % C.L. upper limit on the WIMP-nucleon spin-independent cross section based on zero events found in the WIMP search regions, is 2.0 x 10-44 cm2 (8.6 x 10-44 cm2, 8.0 x 10-43 cm2) for a WIMP mass of 100 GeV/c2 (1 TeV/c2 , 10 TeV/c2).

  10. Towards a biochemical and structural characterisation of the sodium-iodide sym-porter (Nis)

    International Nuclear Information System (INIS)

    Iodide is essential for thyroid hormone biosynthesis in mammals, and therefore for the control of cell metabolism and the development of the central nervous system in the foetus and newborns, but is relatively scarce element in the environment. To ensure its accumulation, the thyroid gland has evolved a remarkably efficient system, the sodium-iodide sym-porter (NIS), that was first characterized at the molecular level 10 years ago (1). NIS is an intrinsic protein mainly located in the basolateral membrane of thyroid follicular cells where it actively transports iodide ions using the sodium gradient as a driving force (2,3). In addition, this transporter has been found in lactating mammary gland, stomach, and salivary glands, and its mRNA was detected in brain, ovaries, testis. To date, the physiological role of NIS in these organs is not yet identified (3,4).The capacity of NIS to mediate the accumulation of radioactive iodide has been exploited for many years in the diagnosis of thyroid cancer as well as for the detection and radiotherapy of derived metastases. Moreover, the presence of NIS in some breast tumours and the possibility to express it by targeted gene therapy in tumour cells where it is not naturally present could also widen its medical application (4-7). In case of accidental contamination, NIS would also be responsible for accumulation of radioisotopes in the thyroid and for their transfer to the milk and the newborn, eventually causing thyroid cancers. This has motivated our research program in the perspective of designing novel specific therapeutics. During the last decade, the gene encoding the thyroid NIS has been identified and sequenced in various species including rat, mouse and human (1, 8). It was also demonstrated that the protein expression and activity are highly regulated both at the transcriptional and post-translational levels (3). A preliminary topological mode could be drawn from the protein sequence. It proposes a general

  11. Iodide Sorption to Clays and the Relationship to the Surface Charge Environment

    Science.gov (United States)

    Miller, A. W.; Wang, Y.

    2011-12-01

    In performance assessments of nuclear waste repositories, iodine-129 is often the major contributor to dose at time scales ≥10,000 years. The breakthrough behavior of iodine is determined by the monovalent, anionic nature and the assumed lack of surface reactivity of the iodide ion. This assumption is corroborated by batch sorption data where iodide sorption to clays is typically very small, and only measurable under specific conditions. This result is consistent with charge repulsion arguments due to the fixed negative charge of clays repelling the anionic iodide. However, in compacted column diffusion experiments, iodide is routinely retarded relative to tritium, and is described with Kd values from ≈0.001-2.9ml/g. While small, these values can dramatically change the dose profile in performance assessment calculations. We hypothesize that contributions from the basal plane and edge charge of individual clay particles as well as the physical morphology of the clay particles are contributing to the conflicting behavior. In a series of experiments involving a wide range of clay minerals from the clay bank repository, both surface charge and iodide sorption were examined using surface titrations and batch sorption experiments. The clay minerals studied include: kaolinite, ripidolite, illite, montmorillonite, palygorskite, sepiolite, and an illite/smectite mixed layer clay. Each of these clays was characterized using XRD, and surface titrations in 0.01, 0.1, and 0.5 M NaCl electrolyte. The titrations spanned the pH range from 2.5-10.5 and were automated using an autotitrator. For reference, similar titrations were performed on pure forms of an Al-O powder. The titration curves were interpreted using an inversion method to attain the pKa distribution for each clay and metal oxide at each ionic strength. The pKa distribution for the Al-O shows two distinct peaks at 4.8 and 7.5, which are invariant with ionic strength. The pKa distribution of clays was highly

  12. Inhaled 45–50% argon augments hypothermic brain protection in a piglet model of perinatal asphyxia

    Science.gov (United States)

    Broad, Kevin D.; Fierens, Igor; Fleiss, Bobbi; Rocha-Ferreira, Eridan; Ezzati, Mojgan; Hassell, Jane; Alonso-Alconada, Daniel; Bainbridge, Alan; Kawano, Go; Ma, Daqing; Tachtsidis, Ilias; Gressens, Pierre; Golay, Xavier; Sanders, Robert D.; Robertson, Nicola J.

    2016-01-01

    Cooling to 33.5 °C in babies with neonatal encephalopathy significantly reduces death and disability, however additional therapies are needed to maximize brain protection. Following hypoxia–ischemia we assessed whether inhaled 45–50% Argon from 2–26 h augmented hypothermia neuroprotection in a neonatal piglet model, using MRS and aEEG, which predict outcome in babies with neonatal encephalopathy, and immunohistochemistry. Following cerebral hypoxia–ischemia, 20 Newborn male Large White piglets < 40 h were randomized to: (i) Cooling (33 °C) from 2–26 h (n = 10); or (ii) Cooling and inhaled 45–50% Argon (Cooling + Argon) from 2–26 h (n = 8). Whole-brain phosphorus-31 and regional proton MRS were acquired at baseline, 24 and 48 h after hypoxia–ischemia. EEG was monitored. At 48 h after hypoxia–ischemia, cell death (TUNEL) was evaluated over 7 brain regions. There were no differences in body weight, duration of hypoxia–ischemia or insult severity; throughout the study there were no differences in heart rate, arterial blood pressure, blood biochemistry and inotrope support. Two piglets in the Cooling + Argon group were excluded. Comparing Cooling + Argon with Cooling there was preservation of whole-brain MRS ATP and PCr/Pi at 48 h after hypoxia–ischemia (p < 0.001 for both) and lower 1H MRS lactate/N acetyl aspartate in white (p = 0.03 and 0.04) but not gray matter at 24 and 48 h. EEG background recovery was faster (p < 0.01) with Cooling + Argon. An overall difference between average cell-death of Cooling versus Cooling + Argon was observed (p < 0.01); estimated cells per mm2 were 23.9 points lower (95% C.I. 7.3–40.5) for the Cooling + Argon versus Cooling. Inhaled 45–50% Argon from 2–26 h augmented hypothermic protection at 48 h after hypoxia–ischemia shown by improved brain energy metabolism on MRS, faster EEG recovery and reduced cell death on TUNEL. Argon may provide a cheap and practical therapy

  13. Modelling steel’s homogenization during argon purging

    Directory of Open Access Journals (Sweden)

    J. Pieprzyca

    2012-12-01

    Full Text Available Purpose: One of the primary tasks that put the steel producers to the test is to reduce production costs while maintaining high quality. This objective is achieved among others through the optimization of conducted technological processes. Commonly used technology of steel homogenization with inert gases is an important stage in the production of steel in which that objective can be accomplished.Design/methodology/approach: Tests of hydrodynamic processes occurring during the steel blowing with inert gases process directly in industrial conditions is very difficult or impossible. Therefore, as the primary research method physical modelling was used. In order to carry out the tests described in the article a physical model of the station for the argon purging was used that is working at the VSB-TU, Department of Metallurgy and Foundry in Ostrava.Findings: As a result the study provided values for the investigated process and determined the appropriate location of the gas-permeable fittings in steelmaking ladle’s bottom plug. This allows to obtain the required conditions for the steel mixing in the entire volume of ladle’s workspace.Research limitations/implications: Tests presented in the article were carried out in the VSB-TU in Ostrava. Due to this fact some research limitations occurs that applies to localization and physical model’s specific construction. Therefore, as a result of cooperation between VSB-TU in Ostrava and the Silesian University of Technology will be carried out the construction of the new research station in Katowice.Practical implications: The results of the research constitute the basis to make changes that will allow the optimization to so far used purge of steel technology.Originality/value: The results presented in the article are addressed to the steel producers and it allows to optimize on-going steel homogenization process that takes place in the ladle

  14. Scintillation light from cosmic-ray muons in liquid argon

    Energy Technology Data Exchange (ETDEWEB)

    Whittington, Denver Wade [Indiana Univ., Bloomington, IN (United States). Physics Dept.; Mufson, S. [Indiana Univ., Bloomington, IN (United States). Astronomy Dept.; Howard, B. [Indiana Univ., Bloomington, IN (United States). Physics Dept.

    2016-05-01

    This paper reports the results of an experiment to directly measure the time-resolved scintillation signal from the passage of cosmic-ray muons through liquid argon. Scintillation light from these muons is of value to studies of weakly-interacting particles in neutrino experiments and dark matter searches. The experiment was carried out at the TallBo dewar facility at Fermilab using prototype light guide detectors and electronics developed for the Deep Underground Neutrino Experiment. Two models are presented for the time structure of the scintillation light, a phenomenological model and a physically-motivated model. Both models find tT = 1:52 ms for the decay time constant of the Ar 2 triplet state. These models also show that the identification of the “early” light fraction in the phenomenological model, FE 25% of the signal, with the total light from singlet decays is an underestimate. The total fraction of singlet light is FS 36%, where the increase over FE is from singlet light emitted by the wavelength shifter through processes with long decay constants. The models were further used to compute the experimental particle identification parameter Fprompt, the fraction of light coming in a short time window after the trigger compared with the light in the total recorded waveform. The models reproduce quite well the typical experimental value 0.3 found by dark matter and double b-decay experiments, which suggests this parameter provides a robust metric for discriminating electrons and muons from more heavily ionizing particles.

  15. Scintillation Light from Cosmic-Ray Muons in Liquid Argon

    Energy Technology Data Exchange (ETDEWEB)

    Whittington, Denver Wade [Indiana U.; Mufson, S. [Indiana U., Bloomington, Dept. Astron.; Howard, B. [Indiana U.

    2015-11-13

    This paper reports the results of an experiment to directly measure the time-resolved scintillation signal from the passage of cosmic-ray muons through liquid argon. Scintillation light from these muons is of value to studies of weakly-interacting particles in neutrino experiments and dark matter searches. The experiment was carried out at the TallBo dewar facility at Fermilab using prototype light guide detectors and electronics developed for the Deep Underground Neutrino Experiment. Two models are presented for the time structure of the scintillation light, a phenomenological model and a physically-motivated model. Both models find tT = 1:52 ms for the decay time constant of the Ar 2 triplet state. These models also show that the identification of the “early” light fraction in the phenomenological model, FE 25% of the signal, with the total light from singlet decays is an underestimate. The total fraction of singlet light is FS 36%, where the increase over FE is from singlet light emitted by the wavelength shifter through processes with long decay constants. The models were further used to compute the experimental particle identification parameter Fprompt, the fraction of light coming in a short time window after the trigger compared with the light in the total recorded waveform. The models reproduce quite well the typical experimental value 0.3 found by dark matter and double b-decay experiments, which suggests this parameter provides a robust metric for discriminating electrons and muons from more heavily ionizing particles.

  16. Scintillation light from cosmic-ray muons in liquid argon

    Science.gov (United States)

    Whittington, D.; Mufson, S.; Howard, B.

    2016-05-01

    This paper reports the results of an experiment to directly measure the time-resolved scintillation signal from the passage of cosmic-ray muons through liquid argon. Scintillation light from these muons is of value to studies of weakly-interacting particles in neutrino experiments and dark matter searches. The experiment was carried out at the TallBo dewar facility at Fermilab using prototype light guide detectors and electronics developed for the Deep Underground Neutrino Experiment. Two models are presented for the time structure of the scintillation light, a phenomenological model and a composite model. Both models find τT = 1.52 μs for the decay time constant of the Ar2* triplet state. These models also show that the identification of the ``early'' light fraction in the phenomenological model, FE ≈ 25% of the signal, with the total light from singlet decays is an underestimate. The total fraction of singlet light is FS ≈ 36%, where the increase over FE is from singlet light emitted by the wavelength shifter through processes with long decay constants. The models were further used to compute the experimental particle identification parameter Fprompt, the fraction of light coming in a short time window after the trigger compared with the light in the total recorded waveform. The models reproduce quite well the typical experimental value ~0.3 found by dark matter and double β-decay experiments, which suggests this parameter provides a robust metric for discriminating electrons and muons from more heavily ionizing particles.

  17. Distribution and leaching of methyl iodide in soil following emulated shank and drip application.

    Science.gov (United States)

    Guo, Mingxin; Zheng, Wei; Papiernik, Sharon K; Yates, Scott R

    2004-01-01

    Methyl iodide (MeI) is a promising alternative to methyl bromide in soil fumigation. The pest-control efficacy and ground water contamination risks of MeI as a fumigant are highly related to its gas-phase distribution and leaching after soil application. In this study, the distribution and leaching of MeI in soil following shank injection and subsurface drip application were investigated. Methyl iodide (200 kg ha(-1)) was directly injected or drip-applied at a 20-cm depth into Arlington sandy loam (coarse-loamy, mixed, thermic Haplic Durixeralfs) columns (12-cm i.d., 70-cm height) tarped with virtually impermeable film. Concentration profiles of MeI in the soil air were monitored for 7 d. Methyl iodide diffused rapidly after soil application, and reached a 70-cm depth within 2 h. Relative to shank injection, drip application inhibited diffusion, resulting in significantly lower concentration profiles in the soil air. Seven days after MeI application, fumigated soil was uncapped, aerated for 7 d, and leached with water. Leaching of MeI was significant from the soil columns under both application methods, with concentrations of >10 mug L(-1) in the early leachate. The leaching was greater following shank injection than drip application, with an overall potential of 33 g ha(-1) for shank injection and 19 g ha(-1) for drip application. Persistent residues of MeI remaining in soils after leaching were 50 to 240 ng kg(-1), and the contents were slightly higher following shank injection than drip application. The results suggest that fumigation with MeI may pose a risk of ground water contamination in vulnerable areas. PMID:15537937

  18. Equations of state for crystalline zirconium iodide: The role of dispersion

    Science.gov (United States)

    Rossi, Matthew L.; Taylor, Christopher D.

    2013-02-01

    We present the first-principle equations of state of several zirconium iodides, ZrI2, ZrI3, and ZrI4, computed using density functional theory methods that apply various methods for introducing the dispersion correction. Iodides formed due to reaction of molecular or atomic iodine with zirconium and zircaloys are of particular interest due to their application to the cladding material used in the fabrication of nuclear fuel rods. Stress corrosion cracking (SCC), associated with fission product chemistry with the clad material, is a major concern in the life cycle of nuclear fuels, as many of the observed rod failures have occurred due to pellet-cladding chemical interactions (PCCI) [A. Atrens, G. Dannhäuser, G. Bäro, Stress-corrosion-cracking of zircaloy-4 cladding tubes, Journal of Nuclear Materials 126 (1984) 91-102; P. Rudling, R. Adamson, B. Cox, F. Garzarolli, A. Strasser, High burn-up fuel issues, Nuclear Engineering and Technology 40 (2008) 1-8]. A proper understanding of the physical properties of the corrosion products is, therefore, required for the development of a comprehensive SCC model. In this particular work, we emphasize that, while existing modeling techniques include methods to compute crystal structures and associated properties, it is important to capture intermolecular forces not traditionally included, such as van der Waals (dispersion) correction. Furthermore, crystal structures with stoichiometries favoring a high I:Zr ratio are found to be particularly sensitive, such that traditional density functional theory approaches that do not incorporate dispersion incorrectly predict significantly larger volumes of the lattice. This latter point is related to the diffuse nature of the iodide electron cloud.

  19. Phase partitioning, retention kinetics, and leaching of fumigant methyl iodide in agricultural soils

    International Nuclear Information System (INIS)

    Although it is not currently being sold in the USA, the recent US registration of the fumigant methyl iodide has led to an increased interest in its environmental fate and transport. Although some work has now considered its volatile emissions from soil, there remains a lack of experimental data regarding its ability to be retained in soil and ultimately become transported with irrigation/rain waters. Using laboratory batch and soil column experiments, we aimed to better understand the phase partitioning of MeI, the ability of soils to retain MeI on the solid phase, and the potential for leaching of MeI and its primary degradation product, iodide, down a soil profile. Results indicated that MeI was retained by the solid phase of soil, being protected from volatilization and degradation, particularly in the presence of elevated organic matter. Retention was greater at lower moisture content, and maximum retention occurred after 56 days of incubation. At higher moisture content, the liquid phase also became important in retaining MeI within soil. Together with low observed KD values (0.10 to 0.57 mL g−1), these data suggest that MeI may be prone to leaching. Indeed, in a steady-state soil column study, initially retained MeI was transported with interstitial water. The MeI degradation product, iodide, was also readily transported in this manner. The data highlight a potentially significant process by which MeI fate and transport within the environment may be impacted. -- Highlights: ► Following fumigation and venting, MeI is retained by soil. ► Soil organic matter status is highly significant in MeI retention. ► Retained MeI is protected from degradation and volatilization. ► Retained MeI can be removed from the solid phase to the liquid phase and leached.

  20. Electrical properties of solid iodo mercurates resulting from the reaction of HgI2 with alcaline iodides

    Science.gov (United States)

    Ponpon, J. P.; Amann, M.

    2005-01-01

    Potassium iodide solutions are currently used during the fabrication process of mercuric iodide based nuclear radiation detectors. However, KI treatment leaves the HgI2 surface covered with a residual compound (namely the potassium tri-iodo mercurate) which has a significant influence on the surface properties and stability of mercuric iodide devices and therefore on the detectors characteristics. Looking for other solutions to etch mercuric iodide, we found it interesting to investigate the electrical properties of the compounds which may form when etching HgI2 in NH4I, NaI, and RbI. For this purpose, solid iodo mercurates with the cations ammonium, sodium, and rubidium, have been prepared by reacting HgI2 with the solutions of interest. Study of the electrical properties of these samples and comparison with those of potassium tri-iodo mercurate ones, especially with respect to humidity, indicates noticeable stability differences in presence of water vapour. This could have interesting consequences on the surface cleaning of mercuric iodide.

  1. Synergy between iodide ions and mangrove tannins as inhibitors of mild steel corrosion

    OpenAIRE

    Adam, Mohd Ridhwan; Rahim, Afidah Abdul; Shah, Affaizza Mohamad

    2015-01-01

    Context Corrosion of materials is a problem faced by many industries. One of the solutions to this problem is to apply corrosion inhibitors.Aims In this study, the synergy between iodide ions and mangrove tannin extracted from mangrove bark (waste products of the charcoal industry) was tested on the inhibition of corrosion of mild steel in 0.5 M HCl and 0.25 M H2SO4. It was compared with the inhibition provided by mimosa and chestnut tannins.MethodsPotentiodynamic and electrochemical impedanc...

  2. Indirect Complexometric Determination of Mercury Using Potassium Iodide as Selective Masking Agent

    OpenAIRE

    RAO, B. Muralidhara

    1998-01-01

    This paper describes a indirect complexometric method for the determination of mercury in the presence of co-ions, based on the selective masking ability of potassium iodide. To the mixture of mercury (II) and other metal ion solution, EDTA solution was added in excess of the metal ions present. The pH of the solution was adjusted to 5.0-6.0 using solid hexamine (10 \\pm 2 g) and surplus EDTA was titrated with zinc sulfate solution using xylenol orange indicator. An excess of solid potassium i...

  3. Introduction to fifth international workshop on mercuric iodide nuclear radiation detectors

    International Nuclear Information System (INIS)

    Mercuric iodide is a wide bandgap semiconductor, with Eg approx. = 2.14 eV at room temperature. Therefore, HgI2 is totally different from the well-studied, narrower gap, elemental semiconductors such as Si and Ge, and also different in its physical and chemical properties from the known semiconductor binary zinc-blend compounds such as GaAs or InP. The purpose of studies in the last decade was to further our understanding of HgI2; recent progress is reported

  4. Detection of experimentally produced acute pulmonary arterial occlusion by methyl iodide-131 inhalation imaging

    International Nuclear Information System (INIS)

    Methyl iodide-131 (CH3I-131) is described as an agent for detection of acute experimentally produced pulmonary arterial occlusion in dogs. When gaseous CH3I-131 is inhaled, radioactivity passes instantaneously from the alveoli to the lung capillary bed. Where pulmonary blood flow exists, activity is washed out into the systemic circulation, but in areas of blood stasis, a transient pulmonary hot spot remains. CH3I-131 is easily produced and inexpensive, but administration is awkward and strict radiation safety precautions are mandatory

  5. Atypical cutaneous sporotrichosis in an immunocompetent adult: Response to potassium iodide

    Directory of Open Access Journals (Sweden)

    Nikita Gandhi

    2016-01-01

    Full Text Available Cutaneous sporotrichosis, also known as “Rose Gardener's disease,” caused by dimorphic fungus Sporothrix schenkii, is usually characterized by indolent nodular or nodulo-ulcerative lesions arranged in a linear pattern. We report bizarre nonlinear presentation of Sporotrichosis, in an immunocompetent adult occurring after a visit to Amazon rain forest, speculating infection with more virulent species of Sporothrix. The diagnosis was reached with the help of periodic acid-Schiff positive yeast cells and cigar shaped bodies seen in skin biopsy along with the therapeutic response to potassium iodide.

  6. A study on sodium iodide symporter gene mutation in congenital hypothyroidism

    International Nuclear Information System (INIS)

    Objective: To investigate the mutation of sodium iodide symporter (NIS) gene in the patients with congenital hypothyroidism (CH) in Tianjin area. Methods: Total genomic DNA was extracted from peripheral blood of 18 patients with CH and 35 normal subjects randomly selected. All 15 exons of NIS gene were individually amplified. Mutation was detected by single-strand conformational polymorphism(SSCP) technique and confirmed with direct sequencing. Results: Exons of NIS gene of all the subjects were successfully amplified by polymerase chain reaction. SSCP analysis displayed no abnormality. No mutation was found in these patients Conclusion: The CH in Tianjin urban area had no mutation of NIS gene. (authors)

  7. Towards Renewable Iodide Sources for Electrolytes in Dye-Sensitized Solar Cells

    Directory of Open Access Journals (Sweden)

    Iryna Sagaidak

    2016-03-01

    Full Text Available A novel family of iodide salts and ionic liquids based on different carbohydrate core units is herein described for application in dye-sensitized solar cell (DSC. The influence of the molecular skeleton and the cationic structure on the electrolyte properties, device performance and on interfacial charge transfer has been investigated. In combination with the C106 polypyridyl ruthenium sensitizer, power conversion efficiencies lying between 5.0% and 7.3% under standard Air Mass (A.M. 1.5G conditions were obtained in association with a low volatile methoxypropionitrile (MPN-based electrolyte.

  8. Introduction to fifth international workshop on mercuric iodide nuclear radiation detectors

    Energy Technology Data Exchange (ETDEWEB)

    Schieber, M.

    1982-01-01

    Mercuric iodide is a wide bandgap semiconductor, with Eg approx. = 2.14 eV at room temperature. Therefore, HgI/sub 2/ is totally different from the well-studied, narrower gap, elemental semiconductors such as Si and Ge, and also different in its physical and chemical properties from the known semiconductor binary zinc-blend compounds such as GaAs or InP. The purpose of studies in the last decade was to further our understanding of HgI/sub 2/; recent progress is reported. (WHK)

  9. Zinc iodide-osmium staining of membrane-coating granules in keratinized and non-keratinized mammalian oral epithelium.

    Science.gov (United States)

    Squier, C A

    1982-01-01

    Specimens of keratinized and non-keratinized oral epithelium were examined in the electron microscope after being stained with zinc iodide-osmium. In both types of tissue, reaction was seen in unmyelinated nerves, in the specific granules of epithelial Langerhans cells and within lysosome-like organelles and small vesicles associated with Golgi systems. In keratinized epithelia, the reaction was also present in the membrane-coating granules and between the deepest cells of the keratinized layer. In contrast, the membrane-coating granules of non-keratinized epithelia lacked Zn iodide-osmium staining despite the presence of reaction in adjacent Golgi systems. It is suggested that Zn iodide-osmium stains glycolipid or glycoprotein material in the cell. This material is elaborated in the Golgi systems from which lysosomes and the membrane-coating granules of keratinized tissues are probably derived.

  10. Characterization of thermally evaporated lead iodide films aimed for the detection of X-rays

    International Nuclear Information System (INIS)

    Some semiconductor materials such as lead iodide (PbI2) have applications in the detection of ionizing radiation at room temperature using the direct detection method. In this work we investigate lead iodide films deposited by thermal evaporation. The morphology, structure, and electric properties were investigated as a function of deposition height, i.e. the distance between evaporation-boat and substrates. The results show a morphology of vertical leaves and X-ray diffraction shows just one preferential orientation along the direction 110. Energy dispersive spectroscopy reveals that the films are not stoichiometric, with excess iodine atoms. Electrical resistivity of about 108 Ω cm was measured. This is smaller than for the bulk due to structural defects. The values of activation energy for electric transport increase from 0.52 up to 1.1 eV with decreasing deposition height, what indicates that the best film is the one deposited at the shortest distance. Exposure under X-ray mammographic energy shows a linear behavior up to 500 mR. No variation in sensibility was observed between 22 and 30 kVp.

  11. Sodium Iodide Symporter for Nuclear Molecular Imaging and Gene Therapy: From Bedside to Bench and Back

    Directory of Open Access Journals (Sweden)

    Byeong-Cheol Ahn

    2012-01-01

    Full Text Available Molecular imaging, defined as the visual representation, characterization and quantification of biological processes at the cellular and subcellular levels within intact living organisms, can be obtained by various imaging technologies, including nuclear imaging methods. Imaging of normal thyroid tissue and differentiated thyroid cancer, and treatment of thyroid cancer with radioiodine rely on the expression of the sodium iodide symporter (NIS in these cells. NIS is an intrinsic membrane protein with 13 transmembrane domains and it takes up iodide into the cytosol from the extracellular fluid. By transferring NIS function to various cells via gene transfer, the cells can be visualized with gamma or positron emitting radioisotopes such as Tc-99m, I-123, I-131, I-124 and F-18 tetrafluoroborate, which are accumulated by NIS. They can also be treated with beta- or alpha-emitting radionuclides, such as I-131, Re-186, Re-188 and At-211, which are also accumulated by NIS. This article demonstrates the diagnostic and therapeutic applications of NIS as a radionuclide-based reporter gene for trafficking cells and a therapeutic gene for treating cancers.

  12. The effect of potassium iodide on the production of acid phosphatase by Sporothrix schenckii

    Directory of Open Access Journals (Sweden)

    P. S. Grover

    2003-06-01

    Full Text Available The present study was undertaken to find out the in vitro effect of potassium iodide (KI on the production of acid phosphatase by fully characterized strain of S.schenckii isolated from a patient of Cutaneous Sporotrichosis. The enzyme acid phosphatase was estimated during the 3 phases of growth of S.schenckii, without and with three concentrations of KI incorporated in the culture medium. In the control and in the test proper, with various concentrations of KI, no adverse effect of KI was observed on the production of acid phosphatase in early and mid log phase of fungal growth. Whereas in the exponential phase in test proper, there was a statistical significant decrease in the enzyme production with 0.8% and 3.2% of KI. The low activity at 0.8% and 3.2% KI indicates that KI has inhibitory effect on the growth of S.schenckii and has led to decrease in the activity of the enzyme. (Med J Indones 2003; 12: 65-8 Keywords: S.schenckii, acid phosphatase, potassium iodide

  13. Iodine in raw and pasteurized milk of dairy cows fed different amounts of potassium iodide.

    Science.gov (United States)

    Norouzian, M A

    2011-02-01

    Relation between iodine (I) intake by lactating Holstein cows and iodine concentrations in raw and pasteurized milk were investigated. Four treatment groups with eight cows assigned to each treatment were fed a basal diet containing 0.534 mg I/kg alone or supplemented with potassium iodide at 2.5, 5 or 7.5 mg/kg in 7-week period. Iodine concentrations in raw milk increased with each increase in dietary I from 162.2 ng/ml for basal diet to 534.5, 559.8 and 607.5 ng/ml when 2.5, 5 and 7.5 mg/kg was fed as potassium iodide (P iodine concentration. Iodine supplementation had no significant effect on thyroidal hormones. high-temperature short-time (HTST) pasteurization process reduced I concentration. The mean iodine content found in the milk prior to heating processing was 466.0 ± 205.0 ng/ml, whereas for the processed milk this level was 349.5 ± 172.8 ng/ml. It was concluded that iodine supplementation above of NRC recommendation (0.5 mg/kg diet DM) resulted in significant increases in iodine concentrations in milk, although the effect of heating in HTST pasteurization process on iodine concentration was not negligible.

  14. Sodium iodide symporter (NIS) in extrathyroidal malignancies: focus on breast and urological cancer

    International Nuclear Information System (INIS)

    Expression and function of sodium iodide symporter (NIS) is requisite for efficient iodide transport in thyrocytes, and its presence in cancer cells allows the use of radioiodine as a diagnostic and therapeutic tool in thyroid neoplasia. Discovery of NIS expression in extrathyroidal tissues, including transformed cells, has opened a novel field of research regarding NIS-expressing extrathyroidal neoplasia. Indeed, expression of NIS may be used as a biomarker for diagnostic, prognostic, and therapeutic purposes. Moreover, stimulation of endogenous NIS expression may permit the radioiodine treatment of extrathyroidal lesions by concentrating this radioisotope. This review describes recent findings in NIS research in extrathyroidal malignancies, focusing on breast and urological cancer, emphasizing the most relevant developments that may have clinical impact. Given the recent progress in the study of NIS regulation as molecular basis for new therapeutic approaches in extrathyroidal cancers, particular attention is given to studies regarding the relationship between NIS and clinical-pathological aspects of the tumors and the regulation of NIS expression in the experimental models

  15. Chitosan finishing nonwoven textiles loaded with silver and iodide for antibacterial wound dressing applications.

    Science.gov (United States)

    Aubert-Viard, François; Martin, Adeline; Chai, Feng; Neut, Christel; Tabary, Nicolas; Martel, Bernard; Blanchemain, Nicolas

    2015-02-01

    Polyethylene terephtalate (PET) and Polypropylene (PP) textiles are widely used in biomedical application such as wound dressings and implants. The aim of this work was to develop an antibacterial chitosan (CHT) coating activated by silver or by iodine. Chitosan was immobilized onto PET and PP supports using citric acid (CTR) as a crosslinking agent through a pad-dry-cure textile finishing process. Interestingly, depending on the CHT/CTR molar ratio, two different systems were obtained: rich in cationic ammonium groups when the CTR concentration was 1%w/v, and rich in anionic carboxylate groups when the CTR concentration was 10%w/v. As a consequence, such samples could be selectively loaded with iodine and silver nitrate, respectively.Both types of coatings were analyzed using SEM and FTIR, their sorption capacities were evaluated toward iodide/iodate anions (I(-)/IO3(-)) and the silver cations (Ag(+)) were evaluated using elemental analysis. Finally, in vitro evaluations were carried out to evaluate the cytocompatibility on the epithelial cell line. The silver loaded textile reported a stronger antibacterial effect against E.coli (5 log10 reduction) than toward S. aureus (3 log10) while the antibacterial effect of the iodide loaded textiles was limited to 1 log10 to 2 log10 on both strains. PMID:25730424

  16. Characterization of thermally evaporated lead iodide films aimed for the detection of X-rays

    Energy Technology Data Exchange (ETDEWEB)

    Caldeira Filho, A.M. [Departamento de Fisica, Faculdade de Filosofia, Ciencias e Letras de Ribeirao Preto, Universidade de Sao Paulo - USP, Avenida Bandeirantes 3900, 14040-901, Ribeirao Preto-SP (Brazil); Mulato, M., E-mail: mmulato@ffclrp.usp.b [Departamento de Fisica, Faculdade de Filosofia, Ciencias e Letras de Ribeirao Preto, Universidade de Sao Paulo - USP, Avenida Bandeirantes 3900, 14040-901, Ribeirao Preto-SP (Brazil)

    2011-04-21

    Some semiconductor materials such as lead iodide (PbI{sub 2}) have applications in the detection of ionizing radiation at room temperature using the direct detection method. In this work we investigate lead iodide films deposited by thermal evaporation. The morphology, structure, and electric properties were investigated as a function of deposition height, i.e. the distance between evaporation-boat and substrates. The results show a morphology of vertical leaves and X-ray diffraction shows just one preferential orientation along the direction 110. Energy dispersive spectroscopy reveals that the films are not stoichiometric, with excess iodine atoms. Electrical resistivity of about 10{sup 8} {Omega} cm was measured. This is smaller than for the bulk due to structural defects. The values of activation energy for electric transport increase from 0.52 up to 1.1 eV with decreasing deposition height, what indicates that the best film is the one deposited at the shortest distance. Exposure under X-ray mammographic energy shows a linear behavior up to 500 mR. No variation in sensibility was observed between 22 and 30 kVp.

  17. Observation of crystallization and characterizations on thiourea cadmium iodide: A semi-organic optical material

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Preeti; Hasmuddin, Mohd. [Crystal Growth and XRD Lab, Department of Physics, Jamia Millia Islamia, New Delhi 110025 (India); Abdullah, M.M. [Crystal Growth and XRD Lab, Department of Physics, Jamia Millia Islamia, New Delhi 110025 (India); Promising Centre for Sensors and Electronic Devices (PCSED), Department of Physics, Faculty of Sciences and Arts, Najran University, P.O. Box 1988, Najran 11001 (Saudi Arabia); Shkir, Mohd. [Crystal Growth and XRD Lab, Department of Physics, Jamia Millia Islamia, New Delhi 110025 (India) and Department of Physics, ARSD College, University of Delhi, New Delhi 110021 (India); Wahab, M.A., E-mail: aries.pre84@gmail.com [Crystal Growth and XRD Lab, Department of Physics, Jamia Millia Islamia, New Delhi 110025 (India)

    2013-10-15

    Graphical abstract: - Highlights: • Thiourea cadmium iodide (TCI) was grown by slow evaporation solution technique. • Morphology and growth rate of the grown compound are determined with the help of inverted microscope. • Optical band gap has been determined. • Microstructure analysis has been reported. • Electrical study has been reported and discussed. - Abstract: In this work, the single crystals of thiourea cadmium iodide were grown by slow evaporation solution technique in two different ratios 2:1 and 1:1. During the formation of their single crystals the morphological features and its live growth process were recorded with the help of inverted microscope. Structural studies of the grown crystals have been carried out by powder X-ray diffraction to confirm the crystal system and vibrational modes by Raman spectroscopy. The optical energy band gaps were investigated through UV–vis spectroscopy study. The surface morphology of the grown single crystals was analyzed by using Scanning Electron Microscope and thermal analysis was carried out by using thermogravimetric analysis. The electrical properties were also studied as a function of frequency and the obtained results are discussed.

  18. Argon gas concentration effects on nanostructured molybdenum nitride layer growth using 100 Hz pulsed dc glow discharge

    Science.gov (United States)

    Ikhlaq, U.; Ahmad, R.; Saleem, S.; Shah, M. S.; Umm-i-Kalsoom; Khan, N.; Khalid, N.

    2012-08-01

    The effect of argon concentration (10%-40%) on the surface properties of molybdenum is studied in nitrogen-argon mixture using 100 Hz pulsed dc glow discharge. The analysis is carried out by using X-ray diffractometer (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM) and Vickers microhardness tester to investigate surface properties of the nitrided samples. XRD results exhibit the formation of molybdenum nitrides. Crystallite size analysis and SEM morphology confirm the growth of nanostructured molybdenum nitride layers. Moreover, significant increase in surface hardness (by a factor of about two times) is found when the sample is treated for 30% argon in nitrogen-argon mixed plasma.

  19. Analysis of perchlorate, thiocyanate, nitrate and iodide in human amniotic fluid using ion chromatography and electrospray tandem mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Blount, Benjamin C. [Division of Laboratory Sciences, National Center for Environmental Health, Centers for Disease Control and Prevention, Atlanta, GA 30341 (United States)]. E-mail: bblount@cdc.gov; Valentin-Blasini, Liza [Division of Laboratory Sciences, National Center for Environmental Health, Centers for Disease Control and Prevention, Atlanta, GA 30341 (United States)

    2006-05-10

    Because of health concerns surrounding in utero exposure to perchlorate, we developed a sensitive and selective method for quantifying iodide, as well as perchlorate and other sodium-iodide symporter (NIS) inhibitors in human amniotic fluid using ion chromatography coupled with electrospray ionization tandem mass spectrometry. Iodide and NIS inhibitors were quantified using a stable isotope-labeled internal standards (Cl{sup 18}O{sub 4} {sup -}, S{sup 13}CN{sup -} and {sup 15}NO{sub 3} {sup -} with excellent assay accuracy of 100%, 98%, 99%, 95% for perchlorate, thiocyanate, nitrate and iodide, respectively, in triplicate analysis of spiked amniotic fluid sample). Excellent analytical precision (<5.2% RSD for all analytes) was found when amniotic fluid quality control pools were repetitively analyzed for iodide and NIS-inhibitors. Selective chromatography and tandem mass spectrometry reduced the need for sample cleanup, resulting in a rugged and rapid method capable of routinely analyzing 75 samples/day. Analytical response was linear across the physiologically relevant concentration range for the analytes. Analysis of a set of 48 amniotic fluid samples identified the range and median levels for perchlorate (0.057-0.71, 0.18 {mu}g/L), thiocyanate (<10-5860, 89 {mu}g/L), nitrate (650-8900, 1620 {mu}g/L) and iodide (1.7-170, 8.1 {mu}g/L). This selective, sensitive, and rapid method will help assess exposure of the developing fetus to low levels of NIS-inhibitors and their potential to inhibit thyroid function.

  20. Improved TPB-coated light guides for liquid argon TPC light detection systems

    International Nuclear Information System (INIS)

    Scintillation light produced in liquid argon (LAr) must be shifted from 128 nm to visible wavelengths in light detection systems used for liquid argon time-projection chambers (LArTPCs). To date, LArTPC light collection systems have employed tetraphenyl butadiene (TPB) coatings on photomultiplier tubes (PMTs) or plates placed in front of the PMTs. Recently, a new approach using TPB-coated light guides was proposed. In this paper, we report on light guides with improved attenuation lengths above 100 cm when measured in air. This is an important step in the development of meter-scale light guides for future LArTPCs. Improvements come from using a new acrylic-based coating, diamond-polished cast UV transmitting acrylic bars, and a hand-dipping technique to coat the bars. We discuss a model for connecting bar response in air to response in liquid argon and compare this to data taken in liquid argon. The good agreement between the prediction of the model and the measured response in liquid argon demonstrates that characterization in air is sufficient for quality control of bar production. This model can be used in simulations of light guides for future experiments

  1. Improved TPB-coated light guides for liquid argon TPC light detection systems

    Science.gov (United States)

    Moss, Z.; Bugel, L.; Collin, G.; Conrad, J. M.; Jones, B. J. P.; Moon, J.; Toups, M.; Wongjirad, T.

    2015-08-01

    Scintillation light produced in liquid argon (LAr) must be shifted from 128 nm to visible wavelengths in light detection systems used for liquid argon time-projection chambers (LArTPCs). To date, LArTPC light collection systems have employed tetraphenyl butadiene (TPB) coatings on photomultiplier tubes (PMTs) or plates placed in front of the PMTs. Recently, a new approach using TPB-coated light guides was proposed. In this paper, we report on light guides with improved attenuation lengths above 100 cm when measured in air. This is an important step in the development of meter-scale light guides for future LArTPCs. Improvements come from using a new acrylic-based coating, diamond-polished cast UV transmitting acrylic bars, and a hand-dipping technique to coat the bars. We discuss a model for connecting bar response in air to response in liquid argon and compare this to data taken in liquid argon. The good agreement between the prediction of the model and the measured response in liquid argon demonstrates that characterization in air is sufficient for quality control of bar production. This model can be used in simulations of light guides for future experiments.

  2. Fast-imaging and spectroscopic analysis of atmospheric argon streamers for large gap arc breakdown

    Science.gov (United States)

    Pachuilo, Michael; Stefani, Francis; Bengtson, Roger; Raja, Laxminarayan

    2014-10-01

    A non-equilibrium plasma source has been developed to assist in the low-voltage arc breakdown of large electrode gaps. The source consists of a dielectric embedded wire helically wound around a confining cylindrical quartz chamber. Annular electrodes cap the ends of the quartz chamber. An argon feed gas is used to provide a uniform environment and exhausts to ambient atmospheric conditions. A negative polarity 50 kV trigger pulse is applied to the embedded trigger wire to initiate the arc breakdown. Application of the trigger pulse produces a localized coronal discharges along the inner surface of the quartz tube. The corona provides seed electrons through which streamers propagate from one of the main discharge electrode along the quartz surface until it reaches the opposite electrode to bridge the gap. Once the gap is bridged a spark over occurs and robust arc discharge is formed in the chamber volume. Fast imaging of the streamer propagation establishes its velocity in the range of ~ 100 km/s. Spectroscopy of the streamer discharge in atmospheric argon has been conducted and electron temperature and number density estimated from a collision radiative model. Argon spectrum is dominated by neutral argon lines in the 650--950 nm range, and singly ionized argon lines are observed in the ultra-violet to near UV (300--400 nm). Research was performed in connection with AFOSR Contract FA9550-11-1-0062.

  3. Prediction of the thermophysical properties of pure neon, pure argon, and the binary mixtures neon-argon and argon-krypton by Monte Carlo simulation using ab initio potentials.

    Science.gov (United States)

    Nasrabad, A E; Laghaei, R; Deiters, U K

    2004-10-01

    Gibbs ensemble Monte Carlo simulations were used to test the ability of intermolecular pair potentials derived ab initio from quantum mechanical principles, enhanced by Axilrod-Teller triple-dipole interactions, to predict the vapor-liquid phase equilibria of pure neon, pure argon, and the binary mixtures neon-argon and argon-krypton. The interaction potentials for Ne-Ne, Ar-Ar, Kr-Kr, and Ne-Ar were taken from literature; for Ar-Kr a different potential has been developed. In all cases the quantum mechanical calculations had been carried out with the coupled-cluster approach [CCSD(T) level of theory] and with correlation consistent basis sets; furthermore an extrapolation scheme had been applied to obtain the basis set limit of the interaction energies. The ab initio pair potentials as well as the thermodynamic data based on them are found to be in excellent agreement with experimental data; the only exception is neon. It is shown, however, that in this case the deviations can be quantitatively explained by quantum effects. The interaction potentials that have been developed permit quantitative predictions of high-pressure phase equilibria of noble-gas mixtures.

  4. Replacement of monochromator and proportional gas counter by mercuric iodide detector in X-ray powder diffraction

    Energy Technology Data Exchange (ETDEWEB)

    Nissenbaum, J.; Levi, A.; Burger, A.; Schieber, M. (Hebrew Univ., Jerusalem (Israel). School of Applied Science and Technology)

    1983-02-01

    Low resolution and therefore low-cost mercuric iodide detectors have successfully been applied to replace the combination of a graphite monochromator and a proportional gas radiation counter used in X-ray diffractometers. The mercuric iodide detector requires a lower DC bias of only 200 V rather than the 1500 V bias needed for the proportional gas counter. The much better stopping power of HgI/sub 2/ allows higher counting efficiency and therefore a better signal-to-noise ratio. Results are shown for X-ray powder diffractions of polycrystalline cubic silicon and tetragonal HgI/sub 2/.

  5. First measurement of surface nuclear recoil background for argon dark matter searches

    CERN Document Server

    Xu, Jingke; Westerdale, Shawn; Calaprice, Frank; Wright, Alexander; Shi, Zhiming

    2016-01-01

    One major background in direct searches for weakly interacting massive particles (WIMPs) comes from the deposition of radon progeny on detector surfaces. The most dangerous surface background is the $^{206}$Pb recoils produced by $^{210}$Po decays. In this letter, we report the first characterization of this background in liquid argon. The scintillation signal of low energy Pb recoils is measured to be highly quenched in argon, and we estimate that the 103keV $^{206}$Pb recoil background will produce a signal equal to that of a ~5keV (30keV) electron recoil ($^{40}$Ar recoil). In addition, we demonstrate that this dangerous $^{210}$Po surface background can be suppressed by a factor of ~100 or higher using pulse shape discrimination methods, which can make argon dark matter detectors near background-free and enhance their potential for discovery of medium- and high-mass WIMPs. We also discuss the impact on other low background experiments.

  6. The WArP Experiment: A Double-Phase Argon Detector for Dark Matter Searches

    International Nuclear Information System (INIS)

    Cryogenic noble liquids emerged in the previous decade as one of the best media to perform WIMP dark matter searches, in particular due to the possibility to scale detector volumes to multiton sizes. The WArP experiment was then developed as one of the first to implement the idea of coupling Argon in liquid and gas phase, in order to discriminate β/γ-interactions from nuclear recoils and then achieve reliable background rejection. Since its construction, other projects spawned, employing Argon and Xenon and following its steps. The WArP 100l detector was assembled in 2008 at the Gran Sasso National Laboratories (LNGS), as the final step of a years-long R&D programme, aimed at characterising the technology of Argon in double phase for dark matter detection. Though it never actually performed a physics run, a technical run was taken in 2011, to characterise the detector response

  7. Operation of a GERDA phase I prototype detector in liquid argon and nitrogen

    International Nuclear Information System (INIS)

    A GERDA phase I prototype detector, consisting of a bare non-enriched high-purity (HP) p-type germanium diode mounted in a low mass holder has been operated both in liquid nitrogen and liquid argon. Because of its high density, liquid argon has been selected as cryogenic liquid and shield for GERDA experiment. The testing of this detector assembly has been carried out in the underground detector laboratory at LNGS, and at the detector manufacturer. The best resolution achieved is 2.2 keV FWHM at 1.332 MeV, which is the same as the resolution measured in a standard test cryostat. The long-term measurements with the prototype detector are performed in liquid argon. Up to now, 38 thermal cycles have been carried out with this detector. The operations, measurements and results of the prototype detector testing are summarized. (orig.)

  8. Lattice gas model for fragmentation from argon on scandium to gold on gold

    CERN Document Server

    Das-Gupta, S; Gupta, Subal Das; Pan, Jicai

    1995-01-01

    The recent fragmentation data for central collisions of Gold on Gold are even qualitatively different from those for central collisions of Argon on Scandium. The latter can be fitted with a lattice gas model calculation. Effort is made to understand why the model fails for Gold on Gold. The calculation suggests that the large Coulomb interaction which is operative for the larger system is responsible for this discrepancy. This is demonstrated by mapping the lattice gas model to a molecular dynamics calculation for disassembly. This mapping is quite faithful for Argon on Scandium but deviates strongly for Gold on Gold. The molecular dynamics calculation for disassembly reproduces the characteristics of the fragmentation data for both Gold on Gold and Argon on Scandium.

  9. Theoretical and experimental comparisons of Gamble 2 argon gas puff experiments

    International Nuclear Information System (INIS)

    A one-dimensional radiative MHD analysis of an imploding argon gas puff plasma is performed. The calculations are set up to approximate the conditions of a series of argon gas puff experiments that were carried out on the NRL Gamble II generator. Annular gas puffs (2.5 cm diameter) are imploded with a 1.2-MA peak driving current for different initial argon mass loadings. Comparisons are made with the experimental results for implosion times, K, L-shell x-ray emission, and energy coupled from the generator to the plasma load. The purpose of these calculations is to provide a foundation from which a variety of physical phenomena which influence the power and total energy of the x-ray emission can be analyzed. Comparisons with similar experimental and theoretical results for aluminum plasmas are discussed

  10. Atomistic-Continuum Hybrid Simulation of Heat Transfer between Argon Flow and Copper Plates

    CERN Document Server

    Mao, Yijin; Chen, C L

    2016-01-01

    A simulation work aiming to study heat transfer coefficient between argon fluid flow and copper plate is carried out based on atomistic-continuum hybrid method. Navier-Stokes equations for continuum domain are solved through the Pressure Implicit with Splitting of Operators (PISO) algorithm, and the atom evolution in molecular domain is solved through the Verlet algorithm. The solver is validated by solving Couette flow and heat conduction problems. With both momentum and energy coupling method applied, simulations on convection of argon flows between two parallel plates are performed. The top plate is kept as a constant velocity and has higher temperature, while the lower one, which is modeled with FCC copper lattices, is also fixed but has lower temperature. It is found that, heat transfer between argon fluid flow and copper plate in this situation is much higher than that at macroscopic when the flow is fully developed.

  11. Argon: Systematic Review on Neuro- and Organoprotective Properties of an “Inert” Gas

    Directory of Open Access Journals (Sweden)

    Anke Höllig

    2014-10-01

    Full Text Available Argon belongs to the group of noble gases, which are regarded as chemically inert. Astonishingly some of these gases exert biological properties and during the last decades more and more reports demonstrated neuroprotective and organoprotective effects. Recent studies predominately use in vivo or in vitro models for ischemic pathologies to investigate the effect of argon treatment. Promising data has been published concerning pathologies like cerebral ischemia, traumatic brain injury and hypoxic ischemic encephalopathy. However, models applied and administration of the therapeutic gas vary. Here we provide a systematic review to summarize the available data on argon’s neuro- and organoprotective effects and discuss its possible mechanism of action. We aim to provide a summary to allow further studies with a more homogeneous setting to investigate possible clinical applications of argon.

  12. Surface modification of poly (vinyl chloride) by long-distance and direct argon RF plasma

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    This paper reports the effects of long- distance and direct argon radio frequency (RF) plasma surface treatment on polyvinyl chloride (PVC) films in terms of changes in surface wettability and surface chemistry. The surface properties are characterized by the water contact angle measurement, X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). The mechanism is further analyzed and the role of all kinds of active species, e.g. electrons, ions and free radicals involved in plasma surface modification is further evaluated. Results show that the long-distance and direct RF plasma treatments modify the PVC surface in morphology and composition, and both modifications cause surface oxidation of PVC films, in the forming of functional groups enhancing polymer wettability. The effect of the long-distance argon RF plasma is more notable. This suggests that long-distance argon RF plasma could restrain the ion and electron eroding effect and enhance free radical reaction.

  13. The effects of accelerated heavy nuclei of neon and argon on mammalian cells in culture

    International Nuclear Information System (INIS)

    The survival of human T-1 kidney cells in high-energy neon (400MeV/nucleon) and argon (500MeV/nucleon) beams has been studied at the Berkeley Bevalac. Cells were plated in monolayers on glass and studied at different residual-range values. The survival curves depend on LET and on particle velocity. The effectiveness of the beams increases as the range decreases, except for argon beams with very low range values, where the effectiveness decreases again. The 'oxygen effect' is high at high particle energies (2.6 for neon and 2.4 for argon); it decreases to values between 1.1 and 1.3 near the Bragg peak. (author)

  14. Synodic and semiannual oscillations of argon-40 in the lunar exosphere

    Science.gov (United States)

    Hodges, R. Richard; Mahaffy, Paul R.

    2016-01-01

    The neutral mass spectrometer on the Lunar Atmosphere and Dust Environment Explorer (LADEE) spacecraft collected a trove of exospheric data, including a set of high-quality measurements of radiogenic 40Ar over a period of 142 days. Data synthesis studies, using well-established exosphere simulation tools, show that the LADEE argon data are consistent with an exosphere-regolith interaction that is dominated by adsorption and that the desorption process generates the Armand distribution of exit velocities. The synthesis work has uncovered an apparent semiannual oscillation of argon that is consistent with temporal sequestration in the seasonal cold traps created at the poles by the obliquity of the Moon. In addition, the LADEE data provide new insight into the pristine nature of lunar regolith, its spatially varying sorption properties, and the influence of sorption processes on the synodic oscillation of the argon exosphere.

  15. Atomistic Simulation of Properties of Ultra-thin Layer of Liquid Argon Compressed Between Diamond Surfaces

    Directory of Open Access Journals (Sweden)

    A.V. Khomenko

    2016-03-01

    Full Text Available Using the method of classical molecular dynamics we investigate the properties of ultrathin film of liquid argon, which consists of one or two layers of molecules and is confined by two atomically smooth crystalline diamond surfaces. The aim of the research is validating the use of rigid surfaces and one of the available models of the argon molecule. We study the behavior of the equilibrium and dynamic characteristics of the system. It is shown that at increasing external load the transition of film in the solid-like state occurs, which is indicated by the behavior of the velocity autocorrelation function of argon molecules, reduction of the magnitude of the diffusion coefficient and the shear viscosity increase. The organization of molecules in layers and the presence of their in-plane ordering are revealed. The dependences of the kinetic friction force on time and load are obtained. The results are compared with experimental data.

  16. Coherent and incoherent Thomson scattering on an argon/hydrogen microwave plasma torch with transient behaviour

    Science.gov (United States)

    Obrusník, A.; Synek, P.; Hübner, S.; van der Mullen, J. J. A. M.; Zajíčková, L.; Nijdam, S.

    2016-10-01

    A new method of processing time-integrated coherent Thomson scattering spectra is presented, which provides not only the electron density and temperature but also information about the transient behaviour of the plasma. Therefore, it is an alternative to single-shot Thomson scattering measurements as long as the scattering is coherent. The method is applied to a microwave plasma torch operating in argon or a mixture of argon with hydrogen at atmospheric pressure. Electron densities up to 8\\cdot {{10}21} m-3 (ionization degree above 10-3) were observed, which is more than two times higher than presented in earlier works on comparable discharges. Additionally, a parametric study with respect to the argon/hydrogen ratio and the input power was carried out and the results are discussed together with earlier Stark broadening measurements on the same plasma.

  17. Ionic Wind Phenomenon and Charge Carrier Mobility in Very High Density Argon Corona Discharge Plasma

    Science.gov (United States)

    Nur, M.; Bonifaci, N.; Denat, A.

    2014-04-01

    Wind ions phenomenon has been observed in the high density argon corona discharge plasma. Corona discharge plasma was produced by point to plane electrodes and high voltage DC. Light emission from the recombination process was observed visually. The light emission proper follow the electric field lines that occur between point and plane electrodes. By using saturation current, the mobilities of non-thermal electrons and ions have been obtained in argon gas and liquid with variation of density from 2,5 1021 to 2 1022 cm-3. In the case of ions, we found that the behaviour of the apparent mobility inversely proportional to the density or follow the Langevin variation law. For non-thermal electron, mobility decreases and approximately follows a variation of Langevin type until the density <= 0,25 the critical density of argon.

  18. Operation of a high purity germanium crystal in liquid argon as a Compton suppressed radiation spectrometer

    CERN Document Server

    Orrell, J L; Amsbaugh, J F; Doe, P J; Hossbach, T W; Orrell, John L.; Aalseth, Craig E.; Amsbaugh, John F.; Doe, Peter J.; Hossbach, Todd W.

    2007-01-01

    A high purity germanium crystal was operated in liquid argon as a Compton suppressed radiation spectrometer. Spectroscopic quality resolution of less than 1% of the full-width half maximum of full energy deposition peaks was demonstrated. The construction of the small apparatus used to obtain these results is reported. The design concept is to use the liquid argon bath to both cool the germanium crystal to operating temperatures and act as a scintillating veto. The scintillation light from the liquid argon can veto cosmic-rays, external primordial radiation, and gamma radiation that does not fully deposit within the germanium crystal. This technique was investigated for its potential impact on ultra-low background gamma-ray spectroscopy. This work is based on a concept initially developed for future germanium-based neutrinoless double-beta decay experiments.

  19. A reversible fluorescent INHIBIT logic gate for determination of silver and iodide based on the use of graphene oxide and a silver–selective probe DNA

    International Nuclear Information System (INIS)

    We describe a reversible fluorescent DNA–based INHIBIT logic gate for the determination of silver(I) and iodide ions using graphene oxide (GO) as a signal transducer and Ag(I) and iodide as mechanical activators. The basic performance, optimized conditions, sensitivity and selectivity of the logic gate were investigated and revealed that the method is highly sensitive and selective over potentially interfering ions. The limits of detection for Ag(I) and iodide are 10 nM and 50 nM, respectively. This logic gate was successfully applied to the determination of Ag(I) and iodide in (spiked) tap water and river water. It was also used for the determination of iodide in human urine samples with satisfactory results. Compared to other methods, this INHIBIT logic gate is simple in design and has small background interference. (author)

  20. DarkSide-50 WIMP search results with low radioactivity argon

    Science.gov (United States)

    Xiang, Xin; DarkSide Collaboration

    2016-03-01

    Located at the Laboratori Nazionali del Gran Sasso, DarkSide-50 is the first physics detector of the DarkSide dark matter search program. The experiment features a dual-phase Time Projection Chamber as the WIMP detector, surrounded by an organic liquid-scintillator neutron veto and a water-Cherenkov muon detector. We report the results from the first use of low radioactivity argon extracted from underground sources in a dark matter search. We have determined that underground argon is depleted in 39Ar by a factor (1 . 4 +/- 0 . 2) ×103 relative to atmospheric argon whose 39Ar activity is 1 bq/kg. The underground argon is also found to contain (2 . 05 +/- 0 . 13) mBq/kg of 85Kr. We find no evidence for dark matter in the form of WIMPs in 70.9 live-days of data with a fiducial mass of (36 . 9 +/- 0 . 6) kg. When combined with our preceding search with an atmospheric argon target, we set a 90 % C.L. upper limit on the WIMP-nucleon spin-independent cross section of 2 . 0 ×10-44 cm2 (8 . 6 ×10-44 cm2, 8 . 0 ×10-43 cm2) for a WIMP mass of 100 GeV/c2 (1 TeV/c2, 10 TeV/c2). DS-50 will continue dark matter search with the underground argon target for a total of 3 years. See also the DS-50 presentations by E. Edkins and G. Koh.

  1. Sorption, degradation, and transport of methyl iodide and other iodine species in geologic media

    International Nuclear Information System (INIS)

    Iodine is an important element in studies of human nutrition to combat I deficiency disorders, and in protection of the environment and human health from anthropogenic release of radioactive I. Biogeochemical cycling of I in the subsurface environment is complex, because it occurs in multiple oxidation states and as inorganic and organic species that may be volatile, hydrophilic and biophilic. Predicting the fate and transport of anthropogenic radioiodine deposited from the atmosphere or released into the subsurface requires knowledge of the sorption and degradation behavior of the various I species that may interact with soils and sediments. In this study, sorption, degradation, and transport behavior of I species (iodide, iodate, methyl iodide, and 4-iodoaniline) were examined in 12 geologic samples of differing physico-chemical characteristics, collected at numerous nuclear facilities in the USA. In particular, this work focuses on the sorption and degradation behavior of CH3I in geologic media, for which few studies are available, even though it is recognized as an important gaseous form of I in the marine atmosphere, and as a major form released from nuclear fuel reprocessing facilities and during nuclear accidents. Results from complementary batch and column experiments show that different I species exhibit very different sorption and transport behavior in geologic media. Sorption of I− is in general minimal, but a low concentration (5 10−13 M) of radioactive 125I is found to be strongly sorbed onto samples with high organic matter. Sorption of IO3- is consistently greater than that of I−, and sorption of 4-iodoaniline is generally strong and seems to be related to the amount of organic matter in the media. Methyl iodide is weakly sorbed onto 12 geologic samples with a distribution coefficient of about 1 mL/g, but its degradation varies greatly as a function of organic matter content, with a regression line of t1/2 = 0.084 × OM + 0.088 (R2 = 0.898, N

  2. Calculation of ion energy distributions of argon excimer ions generated in helicon plasma

    Institute of Scientific and Technical Information of China (English)

    Fang Tong-Zhen; Jiang Nan; Wang Long

    2005-01-01

    A program is developed to calculate the ion energy distributions (IEDs) of Ar2+ making use of a simplified kinetic model with a combination of Monte Carlo method. Several coefficients are used to realize good match between the calculated and measured results. Some important assumptions are confirmed: argon excimer ions have short lifetime,hence they are formed in a short range before the collecting electrode. The excimer ions that encounter collisions will be discarded because they turn to other ion species after they collide with argon atoms. From the calculated results some plasma parameters such as the cross section or neutral density in discharge could be evaluated.

  3. Transport coefficients of helium-argon mixture based on ab initio potential.

    Science.gov (United States)

    Sharipov, Felix; Benites, Victor J

    2015-10-21

    The viscosity, thermal conductivity, diffusion coefficient, and thermal diffusion factor of helium-argon mixtures are calculated for a wide range of temperature and for various mole fractions up to the 12th order of the Sonine polynomial expansion with an ab initio intermolecular potential. The calculated values for these transport coefficients are compared with other data available in the open literature. The comparison shows that the obtained transport coefficients of helium-argon mixture have the best accuracy for the moment. PMID:26493894

  4. Heat Transfer During Evaporation of Cesium From Graphite Surface in an Argon Environment

    Directory of Open Access Journals (Sweden)

    Bespala Evgeny

    2016-01-01

    Full Text Available The article focuses on discussion of problem of graphite radioactive waste formation and accumulation. It is shown that irradiated nuclear graphite being inalienable part of uranium-graphite reactor may contain fission and activation products. Much attention is given to the process of formation of radioactive cesium on the graphite element surface. It is described a process of plasma decontamination of irradiated graphite in inert argon atmosphere. Quasi-one mathematical model is offered, it describes heat transfer process in graphite-cesium-argon system. Article shows results of calculation of temperature field inside the unit cell. Authors determined the factors which influence on temperature change.

  5. Evolution of precipitate in nickel-base alloy 718 irradiated with argon ions at elevated temperature

    Science.gov (United States)

    Jin, Shuoxue; Luo, Fengfeng; Ma, Shuli; Chen, Jihong; Li, Tiecheng; Tang, Rui; Guo, Liping

    2013-07-01

    Alloy 718 is a nickel-base superalloy whose strength derives from γ'(Ni3(Al,Ti)) and γ″(Ni3Nb) precipitates. The evolution of the precipitates in alloy 718 irradiated with argon ions at elevated temperature were examined via transmission electron microscopy. Selected-area electron diffraction indicated superlattice spots disappeared after argon ion irradiation, which showing that the ordered structure of the γ' and γ″ precipitates became disordered. The size of the precipitates became smaller with the irradiation dose increasing at 290 °C.

  6. A 20-Liter Test Stand with Gas Purification for Liquid Argon Research

    CERN Document Server

    Li, Yichen; Tang, Wei; Joshi, Jyoti; Qian, Xin; Diwan, Milind; Kettell, Steve; Morse, William; Rao, Triveni; Stewart, James; Tsang, Thomas; Zhang, Lige

    2016-01-01

    We describe the design of a 20-liter test stand constructed to study fundamental properties of liquid argon (LAr). This system utilizes a simple, cost-effective gas argon (GAr) purification to achieve ultra-high purity, which is necessary to study electron transport properties in LAr. An electron drift stack with up to 25 cm length is constructed to study electron drift, diffusion, and attachment at various electric fields. A gold photocathode and a pulsed laser are used as a bright electron source. The operational performance of this system is reported.

  7. Pulse Compression by Filamentation in Argon with an Acoustic Optical Programmable Dispersive Filter for Predispersion Compensation

    Institute of Scientific and Technical Information of China (English)

    CHEN Xiao-Wei; JIANG Yong-Liang; LENG Yu-Xin; LIU Jun; GE Xiao-Chun; LI Ru-Xin; XU Zhi-Zhan

    2006-01-01

    @@ We have experimentally demonstrated pulses 0.4 mJ in duration smaller than 12 fs with an excellent spatial beam profile by self-guided propagation in argon. The original 52fs pulses from the chirped pulsed amplification laser system are first precompressed to 32 fs by inserting an acoustic optical programmable dispersive filter instrument into the laser system for spectrum reshaping and dispersion compensation, and the pulse spectrum is subsequently broadened by filamentation in an argon cell. By using chirped mirrors for post-dispersion compensation, the pulses are successfully compressed to smaller than 12fs.

  8. The Discovery of Argon in Comet C/1995 O1 (Hale-Bopp)

    CERN Document Server

    Stern, S A; Festou, M C; Parker, J W; A'Hearn, M F; Wilkinson, E; Gladstone, G R

    2000-01-01

    On 30.14 March 1997 we observed the EUV spectrum of the bright comet C/1995 O1 (Hale-Bopp) at the time of its perihelion, using our EUVS sounding rocket telescope/spectrometer. The spectra reveal the presence H Ly beta, O+, and, most notably, Argon. Modelling of the retrieved Ar production rates indicates that comet Hale-Bopp is enriched in Ar relative to cosmogonic expectations. This in turn indicates that Hale-Bopp's deep interior has never been exposed to the 35-40 K temperatures necessary to deplete the comet's primordial argon supply.

  9. Physiological responses of Vigna radiata L. to nitrogen and argon+ laser irradiation - Short Communication

    International Nuclear Information System (INIS)

    The effect of nitrogen laser (337.1 nm) and argon+ laser (514.5 nm) irradiation on physiological responses in the green gram seedlings was studied. The shoot and root lengths and fresh and dry weights of the seedlings increased with 30 min exposure to nitrogen laser and 5 min exposure to Argon+ laser. Protein content was maximum with 20 min exposure to N laser and 5 min exposure to Ar+ laser, while DNA and RNA contents were maximum at 5 min exposure with both the laser treatments

  10. Inner-shell Annihilation of Positrons in Argon, Iron and Copper Atoms

    CERN Document Server

    Abdel-Raouf, M A; El-Bakry, S Y

    2007-01-01

    The annihilation parameters of positrons with electrons in different shells of Argon, Iron and Copper atoms are calculated below the positronium (Ps) formation thresholds. Quite accurate ab initio calculations of the bound state wavefunctions of Argon, Iron and Copper orbitals are obtained from Cowan computer code. A least-squares variational method (LSVM) is used for determining the wavefunction of the positrons. The program is employed for calculating the s-wave partial cross sections of positrons scattered by Iron and Copper atoms. Our results of the effective charge are compared with available experimental and theoretical ones. --

  11. Application of argon laser LAK-1 for therapy in selected blood vessel diseases

    Science.gov (United States)

    Szymanczyk, Jacek; Golebiowska, Aleksandra; Michalska, I.; Nowakowski, Wlodzimierz

    1995-03-01

    Argon laser was applied in 172 patients with various vascular disorders and epidermal nevi. The best therapeutical results were obtained in facial telangiectasia and in cavernous hemangiomas, in which there was a complete or almost complete regression. In capillary facial hemangiomas in 49 patients (79%) clearing of 50% to 75% was obtained, and in epidermal nevi the full regression was in 4 (44%) of the cases, and 50% regression in 4 (44%). In telangiectasia of the lower limbs the results were not satisfactory. We stress that cavernous, and capillary hemangiomas, as well as facial telangiectasia are an indication for the argon laser therapy.

  12. Performance of the Electronic Readout of the ATLAS Liquid Argon Calorimeters

    CERN Document Server

    Abreu, H; Aleksa, M; Aperio Bella, L; Archambault, JP; Arfaoui, S; Arnaez, O; Auge, E; Aurousseau, M; Bahinipati, S; Ban, J; Banfi, D; Barajas, A; Barillari, T; Bazan, A; Bellachia, F; Beloborodova, O; Benchekroun, D; Benslama, K; Berger, N; Berghaus, F; Bernat, P; Bernier, R; Besson, N; Binet, S; Blanchard, JB; Blondel, A; Bobrovnikov, V; Bohner, O; Boonekamp, M; Bordoni, S; Bouchel, M; Bourdarios, C; Bozzone, A; Braun, HM; Breton, D; Brettel, H; Brooijmans, G; Caputo, R; Carli, T; Carminati, L; Caughron, S; Cavalleri, P; Cavalli, D; Chareyre, E; Chase, RL; Chekulaev, SV; Chen, H; Cheplakov, A; Chiche, R; Citterio, M; Cojocaru, C; Colas, J; Collard, C; Collot, J; Consonni, M; Cooke, M; Copic, K; Costa, GC; Courneyea, L; Cuisy, D; Cwienk, WD; Damazio, D; Dannheim, D; De Cecco, S; De La Broise, X; De La Taille, C; de Vivie, JB; Debennerot, B; Delagnes, E; Delmastro, M; Derue, F; Dhaliwal, S; Di Ciaccio, L; Doan, O; Dudziak, F; Duflot, L; Dumont-Dayot, N; Dzahini, D; Elles, S; Ertel, E; Escalier, M; Etienvre, AI; Falleau, I; Fanti, M; Farooque, T; Favre, P; Fayard, Louis; Fent, J; Ferencei, J; Fischer, A; Fournier, D; Fournier, L; Fras, M; Froeschl, R; Gadfort, T; Gallin-Martel, ML; Gibson, A; Gillberg, D; Gingrich, DM; Göpfert, T; Goodson, J; Gouighri, M; Goy, C; Grassi, V; Gray, J; Guillemin, T; Guo, B; Habring, J; Handel, C; Heelan, L; Heintz, H; Helary, L; Henrot-Versille, S; Hervas, L; Hobbs, J; Hoffman, J; Hostachy, JY; Hoummada, A; Hrivnac, J; Hrynova, T; Hubaut, F; Huber, J; Iconomidou-Fayard, L; Iengo, P; Imbert, P; Ishmukhametov, R; Jantsch, A; Javadov, N; Jezequel, S; Jimenez Belenguer, M; Ju, XY; Kado, M; Kalinowski, A; Kar, D; Karev, A; Katsanos, I; Kazarinov, M; Kerschen, N; Kierstead, J; Kim, MS; Kiryunin, A; Kladiva, E; Knecht, N; Kobel, M; Koletsou, I; König, S; Krieger, P; Kukhtin, V; Kuna, M; Kurchaninov, L; Labbe, J; Lacour, D; Ladygin, E; Lafaye, R; Laforge, B; Lamarra, D; Lampl, W; Lanni, F; Laplace, S; Laskus, H; Le Coguie, A; Le Dortz, O; Le Maner, C; Lechowski, M; Lee, SC; Lefebvre, M; Leonhardt, K; Lethiec, L; Leveque, J; Liang, Z; Liu, C; Liu, T; Liu, Y; Loch, P; Lu, J; Ma, H; Mader, W; Majewski, S; Makovec, N; Makowiecki, D; Mandelli, L; Mangeard, PS; Mansoulie, B; Marchand, JF; Marchiori, G; Martin, D; Martin-Chassard, G; Martin dit Latour, B; Marzin, A; Maslennikov, A; Massol, N; Matricon, P; Maximov, D; Mazzanti, M; McCarthy, T; McPherson, R; Menke, S; Meyer, JP; Ming, Y; Monnier, E; Mooshofer, P; Neganov, A; Niedercorn, F; Nikolic-Audit, I; Nugent, IM; Oakham, G; Oberlack, H; Ocariz, J; Odier, J; Oram, CJ; Orlov, I; Orr, R; Parsons, JA; Peleganchuk, S; Penson, A; Perini, L; Perrodo, P; Perrot, G; Perus, A; Petit, E; Pisarev, I; Plamondon, M; Poffenberger, P; Poggioli, L; Pospelov, G; Pralavorio, P; Prast, J; Prudent, X; Przysiezniak, H; Puzo, P; Quentin, M; Radeka, V; Rajagopalan, S; Rauter, E; Reimann, O; Rescia, S; Resende, B; Richer, JP; Ridel, M; Rios, R; Roos, L; Rosenbaum, G; Rosenzweig, H; Rossetto, O; Roudil, W; Rousseau, D; Ruan, X; Rudert, A; Rusakovich, N; Rusquart, P; Rutherfoord, J; Sauvage, G; Savine, A; Schaarschmidt, J; Schacht, P; Schaffer, A; Schram, M; Schwemling, P; Seguin Moreau, N; Seifert, F; Serin, L; Seuster, R; Shalyugin, A; Shupe, M; Simion, S; Sinervo, P; Sippach, W; Skovpen, K; Sliwa, R; Soukharev, A; Spano, F; Stavina, P; Straessner, A; Strizenec, P; Stroynowski, R; Talyshev, A; Tapprogge, S; Tarrade, F; Tartarelli, GF; Teuscher, R; Tikhonov, Yu; Tocut, V; Tompkins, D; Thompson, P; Tisserant, S; Todorov, T; Tomasz, F; Trincaz-Duvoid, S; Trinh, Thi N; Trochet, S; Trocme, B; Tschann-Grimm, K; Tsionou, D; Ueno, R; Unal, G; Urbaniec, D; Usov, Y; Voss, K; Veillet, JJ; Vincter, M; Vogt, S; Weng, Z; Whalen, K; Wicek, F; Wilkens, H; Wingerter-Seez, I; Wulf, E; Yang, Z; Ye, J; Yuan, L; Yurkewicz, A; Zarzhitsky, P; Zerwas, D; Zhang, H; Zhang, L; Zhou, N; Zimmer, J; Zitoun, R; Zivkovic, L

    2010-01-01

    The ATLAS detector has been designed for operation at the Large Hadron Collider at CERN. ATLAS includes electromagnetic and hadronic liquid argon calorimeters, with almost 200,000 channels of data that must be sampled at the LHC bunch crossing frequency of 40 MHz. The calorimeter electronics calibration and readout are performed by custom electronics developed specifically for these purposes. This paper describes the system performance of the ATLAS liquid argon calibration and readout electronics, including noise, energy and time resolution, and long term stability, with data taken mainly from full-system calibration runs performed after installation of the system in the ATLAS detector hall at CERN.

  13. Experimental Measurement for Shock Velocity-Mass Velocity Relationship of Liquid Argon Up to 46 GPa

    Institute of Scientific and Technical Information of China (English)

    孟川民; 施尚春; 董石; 杨向东; 谭华; 经福谦

    2003-01-01

    Shock properties of liquid argon were measured in the shock pressure up to 46 GPa by employing the two-stage light gas gun. Liquid nitrogen was used as coolant liquid. The cryogenic target system has been improved to compare with the previous work. Shock velocities were measured with self-shorting electrical probes. Impactor velocities were measured with an electrical-magnetic induction system. Mass velocities were obtained by mean of shock impedance matching method. The experimental data shows that the slope of experimental Hugoniot curve of liquid argon begins to decrease above 30 GPa.

  14. Intermolecular interaction potentials of methane-argon complex calculated using LDA approaches

    Institute of Scientific and Technical Information of China (English)

    Bai Yu-Lin; Chen Xiang-Rong; Zhou Xiao-Lin; Yang Xiang-Dong; Wang Hai-Yan

    2004-01-01

    The intermolecular interaction potential for methane-argon complex is calculated by local density approximation (LDA) approaches. The calculated potential has a minimum when the intermolecular distance of methane-argon complex is 6.75 a.u.; the corresponding depth of the potential is 0.0163eV which has good agreement with experimental data. We also have made a nonlinear fitting of our results for the Lennard-Jones (12-6) potential function and obtain that V(R) = 143794365.332/R12 - 3032.093/R6 (R in a.u. and V(R) in eV).

  15. Ablation of Barrett’s esophagus using the second-generation argon plasma coagulation

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Objective To investigate the efficacy and safety of the second-generation argon plasma coagulation (VIO APC) in ablation of Barrett’s esophagus. Methods Eighteen patients with Barrett’s esophagus (12 males, median age of 55 years, median length of 2.1 cm,1 low-grade dysplasia, 13 cases of short segment Barrett’s esophagus) received VIO APC, which was performed at a power setting of 40W and argon gas flow at 1.5-2.0 L/min, "forced" mode, in 1-3 sessions (mean 1.3). All the patients received treatment with hi...

  16. Research of On-line Analytical Method of Trace Oxygen and Water in Argon

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Metal sodium has an active chemical quality. When it is used as a coolant in a fast neutron reactor, it must be protected by a cover gas argon for safety operation of the reactor. But oxygen and water in argon can produce chemical reaction with sodium. Then sodium hydroxide, sodium oxide and hydrogen can be produced. This will be harmful to the safety operation of reactor. The purpose of controlling a level of impurity in the cover gas is for controlling a level of impurity in sodium. The research is to find an on-line determining method and a sampling system to monitor

  17. ArgonCube: a novel, fully-modular approach for the realization of large-mass liquid argon TPC neutrino detectors

    CERN Document Server

    Amsler, C; Asaadi, J; Auger, M; Barbato, F; Bay, F; Bishai, M; Bleiner, D; Borgschulte, A; Bremer, J; Cavus, E; Chen, H; De Geronimo, G; Ereditato, A; Fleming, B; Goldi, D; Hanni, R; Kose, U; Kreslo, I; La Mattina, F; Lanni, F; Lissauer, D; Luthi, M; Lutz, P; Marchionni, A; Mladenov, D; Nessi, M; Noto, F; Palamara, O; Raaf, J L; Radeka, V; Rudolph Von Rohr, Ch; Smargianaki, D; Soderberg, M; Strauss, Th; Weber, M; Yu, B; Zeller, G P; Zeyrek, M; CERN. Geneva. SPS and PS Experiments Committee; SPSC

    2015-01-01

    The Liquid Argon Time Projection Chamber is a prime candidate detector for future neutrino oscillation physics experiments, underground neutrino observatories and proton decay searches. A large international project based on this technology is currently being considered at the future LBNF facility in the United States on the very large mass scale of 40 kton. In this document, following the long standing R&D work conducted over the last years in several laboratories in Europe and in the United States, we intend to propose a novel Liquid Argon TPC approach based on a fully-modular, innovative design, the ArgonCube. The related R&D work will proceed along two main directions; one aimed at on the assessment of the proposed modular detector design, the other on the exploitation of new signal readout methods. Such a strategy will provide high performance while being cost-effective and robust at the same time. According to our plans, we will firstly realize a detector prototype hosted in a cryostat that is a...

  18. Cyclization of 2′-hydroxychalcones to flavones using ammonium iodide as an iodine source: An eco-friendly approach

    OpenAIRE

    Kulkarni Pramod S.; Kondhare Dasharath D.; Varala Ravi; Zubaidha Pudukulathan K.

    2013-01-01

    Ammonium iodide in open air decomposes to ammonia and iodine. The in situ generated iodine has been used for cyclization of 2′-hydroxychalcones to corresponding flavones under solvent free conditions with good to excellent yields. This method would serve as an attractive alternative to the existing methods for synthesis of flavones and use of toxic molecular iodine is avoided.

  19. Cyclization of 2′-hydroxychalcones to flavones using ammonium iodide as an iodine source: An eco-friendly approach

    Directory of Open Access Journals (Sweden)

    Kulkarni Pramod S.

    2013-01-01

    Full Text Available Ammonium iodide in open air decomposes to ammonia and iodine. The in situ generated iodine has been used for cyclization of 2′-hydroxychalcones to corresponding flavones under solvent free conditions with good to excellent yields. This method would serve as an attractive alternative to the existing methods for synthesis of flavones and use of toxic molecular iodine is avoided.

  20. Polymer adsorption and its effect on the Stability of hydrophobic colloids. III. Kinetics of th Flocculation of silver iodide sols

    NARCIS (Netherlands)

    Fleer, G.J.; Lyklema, J.

    1976-01-01

    In a previous study on the flocculation of silver iodide sols by polyvinyl alcohol (PVA) it was demonstrated that the extent of flocculation depends critically on the way in which sol particles and polymer are mixed. Optimal flocculation was shown to occur if a two-portion method of mixing is applie

  1. N,N-Dimethylbenzimidazolium iodide as a green catalyst for cross-coupling of aromatic aldehydeswith unactivated imines

    Directory of Open Access Journals (Sweden)

    Viwat Hahnvajana wong

    2016-03-01

    Full Text Available Cross-coupling of aromatic aldehydes with unactivated iminescatalyzed by N,N-dimethylbenzimidazolium iodide in ethanolic sodium hydroxide solution gave α-amino ketonesin satisfactory yields. Benzoin condensation and further oxidation of the resulted aroins also occurred as side reactions.

  2. Efficient Method for the Determination of the Activation Energy of the Iodide-Catalyzed Decomposition of Hydrogen Peroxide

    Science.gov (United States)

    Sweeney, William; Lee, James; Abid, Nauman; DeMeo, Stephen

    2014-01-01

    An experiment is described that determines the activation energy (E[subscript a]) of the iodide-catalyzed decomposition reaction of hydrogen peroxide in a much more efficient manner than previously reported in the literature. Hydrogen peroxide, spontaneously or with a catalyst, decomposes to oxygen and water. Because the decomposition reaction is…

  3. Evaluation of iodide deficiency in the lactating rat and pup using a biologically based dose-response model

    Science.gov (United States)

    A biologically-based dose response (BBDR) model for the hypothalamic-pituitary thyroid (BPT) axis in the lactating rat and nursing pup was developed to describe the perturbations caused by iodide deficiency on the HPT axis. Model calibrations, carried out by adjusting key model p...

  4. Evaluation of iodide deficiency in the lactating rat and pup using a biologically based dose response (BBDR) Model***

    Science.gov (United States)

    A biologically-based dose response (BBDR) model for the hypothalamic-pituitary thyroid (HPT) axis in the lactating rat and nursing pup was developed to describe the perturbations caused by iodide deficiency on the 1-IPT axis. Model calibrations, carried out by adjusting key model...

  5. The lactoperoxidase system : the influence of iodide and the chemical and antimicrobial stability over the period of about 18 months

    NARCIS (Netherlands)

    Bosch, EH; Van Doorne, H; De Vries, S

    2000-01-01

    The lactoperoxidase (LP) system is a natural antimicrobial system, the use of which has been suggested as a preservative in foods and pharmaceuticals. The effect of adding iodide to the LP system, the chemical stability and the change in antimicrobial effectiveness during storage was studied. Additi

  6. Role of endoplasmic reticulum stress-induced apoptosis in rat thyroid toxicity caused by excess fluoride and/or iodide.

    Science.gov (United States)

    Liu, Hongliang; Hou, Changchun; Zeng, Qiang; Zhao, Liang; Cui, Yushan; Yu, Linyu; Wang, Lingzhi; Zhao, Yang; Nie, Junyan; Zhang, Bin; Wang, Aiguo

    2016-09-01

    Excess fluoride and iodide coexist in drinking water in many regions, but few studies have investigated the single or interactive effects on thyroid in vivo. In our study, Wistar rats were exposed to excess fluoride and/or iodide through drinking water for 2 or 8 months. The structure and function of the thyroid, cells apoptosis and the expression of inositol-requiring enzyme 1 (IRE1) pathway-related factors were analyzed. Results demonstrated that excess fluoride and/or iodide could change thyroid follicular morphology and alter thyroid hormone levels in rats. After 8 months treatment, both single and co-exposure of the two microelements could raise the thyroid cells apoptosis. However, the expressions of IRE1-related factors were only increased in fluoride-alone and the combined groups. In conclusion, thyroid structure and thyroid function were both affected by excess fluoride and/or iodide. IRE1-induced apoptosis were involved in this cytotoxic process caused by fluoride or the combination of two microelements. PMID:27522547

  7. Congenital Hypothyroidism Caused by a PAX8 Gene Mutation Manifested as Sodium/Iodide Symporter Gene Defect

    Directory of Open Access Journals (Sweden)

    Wakako Jo

    2010-01-01

    Full Text Available Loss-of-function mutations of the PAX8 gene are considered to mainly cause congenital hypothyroidism (CH due to thyroid hypoplasia. However, some patients with PAX8 mutation have demonstrated a normal-sized thyroid gland. Here we report a CH patient caused by a PAX8 mutation, which manifested as iodide transport defect (ITD. Hypothyroidism was detected by neonatal screening and L-thyroxine replacement was started immediately. Although 123I scintigraphy at 5 years of age showed that the thyroid gland was in the normal position and of small size, his iodide trapping was low. The ratio of the saliva/plasma radioactive iodide was low. He did not have goiter; however laboratory findings suggested that he had partial ITD. Gene analyses showed that the sodium/iodide symporter (NIS gene was normal; instead, a mutation in the PAX8 gene causing R31H substitution was identified. The present report demonstrates that individuals with defective PAX8 can have partial ITD, and thus genetic analysis is useful for differential diagnosis.

  8. 40 CFR 63.10686 - What are the requirements for electric arc furnaces and argon-oxygen decarburization vessels?

    Science.gov (United States)

    2010-07-01

    ... Hazardous Air Pollutants for Area Sources: Electric Arc Furnace Steelmaking Facilities Standards and Compliance Requirements § 63.10686 What are the requirements for electric arc furnaces and argon-oxygen... arc furnaces and argon-oxygen decarburization vessels? 63.10686 Section 63.10686 Protection...

  9. Numerical Simulation of the Thermal Conductivity of Thermal Insulation Pipe by Vacuum and High Pressure Argon Pre-filled

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    [Abstract]By analyzing the insulation effect of argon-filled tubing and vacuum-insulated tubing before and after hydrogen permeation respectively, a conclusion can be drawn that the insulated tubing filled with high pressure argon is better than the vacuum insulated tubing considering the lifetime and heat insulation effect.

  10. Grain-Size-Limited Mobility in Methylammonium Lead Iodide Perovskite Thin Films

    Energy Technology Data Exchange (ETDEWEB)

    Reid, Obadiah G.; Yang, Mengjin; Kopidakis, Nikos; Zhu, Kai; Rumbles, Garry

    2016-09-09

    We report a systematic study of the gigahertz-frequency charge carrier mobility found in methylammonium lead iodide perovskite films as a function of average grain size using time-resolved microwave conductivity and a single processing chemistry. Our measurements are in good agreement with the Kubo formula for the AC mobility of charges confined within finite grains, suggesting (1) that the surface grains imaged via scanning electron microscopy are representative of the true electronic domain size and not substantially subdivided by twinning or other defects not visible by microscopy and (2) that the time scale of diffusive transport across grain boundaries is much slower than the period of the microwave field in this measurement (-100 ps). The intrinsic (infinite grain size) minimum mobility extracted form the model is 29 +/- 6 cm2 V-1 s-1 at the probe frequency (8.9 GHz).

  11. Photoemission and optical constant measurements of Cesium Iodide thin film photocathode

    CERN Document Server

    Triloki,; Gupta, Nikita; Jammal, Nabeel F A; Singh, B K

    2014-01-01

    Performance of cesium iodide (CsI) as a reflective photocathode is presented. Absolute quantum efficiency (QE) measurement of 500 nm thick CsI film has been carried out in the wavelength range of 150 nm to 200 nm. Optical absorbance of 500 nm thick CsI film in the spectral range of 190 nm to 900 nm is analyzed and optical energy band gap is calculated using Tauc plot. To see the dispersive behavior of CsI film, refractive index has been determined by envelop plot of transmittance data, using Swanepoel method. Additional information on morphological and elemental composition results of CsI film, gained by atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS), respectively are also reported in present work.

  12. Coordination-Induced Syntheses of Two Hybrid Framework Iodides: A Thermochromic Luminescent Thermometer.

    Science.gov (United States)

    Zhang, Ren-Chun; Wang, Jun-Jie; Zhang, Jing-Chao; Wang, Meng-Qi; Sun, Min; Ding, Feng; Zhang, Dao-Jun; An, Yong-Lin

    2016-08-01

    Two new 3D hybrid framework iodides, Hmta[(Hmta)Ag4I4] (1; Hmta = hexamethylenetetramine) and [(Hmta)2Ag8I6]I2 (2), have been synthesized under solvothermal conditions. Compound 1 consists of a neutral 3D framework built up from alternation of the tetrahedral Ag4I4 unit and Hmta with dia-b topology. Compound 2 features a 3D cationic framework with flu topology, constructed by cationic [Ag8I6](2+) units linked with Hmta. Tetrahedral Hmta plays crucial structure-directing roles in the formation of these 3D frameworks with high symmetry. The temperature-dependent photoluminescent measurement reveals luminescent thermochromism of the compounds, the emission maximum of which shows a gradual blue shift with increasing temperature. The results indicate that 1 is a promising wavelength- and intensity-dependent luminescent thermometer applicable in two different temperature ranges. PMID:27438190

  13. A review of recent measurements of optical and thermal properties of. alpha. -mercuric iodide

    Energy Technology Data Exchange (ETDEWEB)

    Burger, A.; Morgan, S.H.; Silberman, E. (Fisk Univ., Nashville, TN (United States). Dept. of Physics); Nason, D.; Cheng, A.Y. (EG and G Energy Measurements, Inc., Goleta, CA (United States). Santa Barbara Operations)

    1991-01-01

    The knowledge of the physical properties of a crystal and their relation to the nature and content of defects are essential for both applications and fundamental reasons. Alpha-mercuric iodide ({alpha}-HgI{sub 2}) is a material which was found important applications as room temperature X-ray and gamma ray detectors. Some recent thermal and optical measurements of this material, using the samples of improved crystallinity which are now available, are reviewed below. Heretofore, these properties have received less attention than the mechanical and electrical properties, particularly at elevated temperatures. In the technology of {alpha}-HgI{sub 2} where there is a continuing motivation to obtain larger single crystals without compromising the material quality, a better knowledge of the thermal and optical properties may lead to improvements in the processes of material purification, crystal growth and device fabrication.

  14. Electric field effects on the quantum efficiency of Cesium-iodide photocathodes in gas media

    International Nuclear Information System (INIS)

    We have measured the quantum efficiency (QE) of Cesium iodide photocathodes as a function of the electric field strength in a parallel-plate geometry, in CH4, C2H6 AND i-C4H10 both in charge collection and multiplication modes. It was found that in the collection mode the QE value in gases is lower compared to that of vacuum and is independent on the field; in gas media the QE starts to increase at the transition between collection and multiplication modes and reaches the vacuum value at high gas gain. We explain this effect by a decrease of the electron-molecule elastic backscattering while entering the multiplication mode. We conclude that the electric field effects observed here, would also apply for other photocathodes and gas mixtures. An enhancement of the QE after micro discharges was observed and is discussed in detail. (authors) 30 refs, 10 figs

  15. Efficient organic solar cells using copper(I) iodide (CuI) hole transport layers

    International Nuclear Information System (INIS)

    We report the fabrication of high power conversion efficiency (PCE) polymer/fullerene bulk heterojunction (BHJ) photovoltaic cells using solution-processed Copper (I) Iodide (CuI) as hole transport layer (HTL). Our devices exhibit a PCE value of ∼5.5% which is equivalent to that obtained for control devices based on the commonly used conductive polymer poly(3,4-ethylenedioxythiophene): polystyrenesulfonate as HTL. Inverted cells with PCE >3% were also demonstrated using solution-processed metal oxide electron transport layers, with a CuI HTL evaporated on top of the BHJ. The high optical transparency and suitable energetics of CuI make it attractive for application in a range of inexpensive large-area optoelectronic devices

  16. A coupled chemical burster: The chlorine dioxide-iodide reaction in two flow reactors

    Science.gov (United States)

    Dolnik, Milos; Epstein, Irving R.

    1993-01-01

    The dynamical behavior of the chlorine dioxide-iodide reaction has been studied in a system consisting of two continuous flow stirred tank reactors (CSTRs). The reactors are coupled by computer monitoring of the electrochemical potential in each reactor, which is then used to control the input into the other reactor. Two forms of coupling are employed: reciprocally triggered, exponentially decreasing stimulation, and alternating mass exchange. The reaction, which exhibits oscillatory and excitable behavior in a single CSTR, displays neuronlike bursting behavior with both forms of coupling. Reciprocal stimulation yields bursting in both reactors, while with alternating mass exchange, bursting is observed in one reactor and complex oscillation in the other. A simple model of the reaction gives good agreement between the experimental observations and numerical simulations.

  17. Lead iodide films as X-ray sensors tested in the mammography energy region

    International Nuclear Information System (INIS)

    We present an alternative method for the deposition of thin films of lead iodide (PbI2), which is a promising semiconductor candidate for applications in medical digital radiography. The spray pyrolysis technique enables the fabrication of thick films with a deposition rate of about 3.3 As-1. We investigate the influence of the main deposition parameters on the final properties of the films. They were substrate temperature from 150 up to 270 oC and nozzle-spray distance to substrate from 13.0 to 16.5 cm. The films were mainly investigated using X-ray diffraction (XRD), Atomic Force Microscopy (AFM), and Photoluminescence (PL) spectroscopy. Also, electrical characterizations were made in the dark as a function of temperature, and with the samples submitted to X-ray exposures in the energy range of mammography diagnosis

  18. Mercuric iodide composite films using polyamide, polycarbonate and polystyrene fabricated by casting

    International Nuclear Information System (INIS)

    Mercuric iodide (HgI2) composite films were obtained by using the casting technique. Insulator polymers such as polyamide, polycarbonate and polystyrene were mixed to HgI2 crystallites forming a final sub-millimeter thick self-standing film. Fabrication temperature varied from 10 to 100 oC, and total fabrication time reached at most 5 min. The larger the fabrication temperature, the thinner the film and the smaller its electrical resistivity. Electrical characterization was performed in the dark, under UV illumination and under mammographic X-ray exposure. The final properties of the films are discussed and related to fabrication conditions. The optimized composite film might be a better candidate for use as X-ray detector for medical imaging, in place of the single HgI2 crystalline device.

  19. Electron and Hole Drift Mobility Measurements on Methylammonium Lead Iodide Perovskite Solar Cells

    Energy Technology Data Exchange (ETDEWEB)

    Maynard, Brian; Long, Qi; Schiff, Eric A.; Yang, Mengjin; Zhu, Kai; Kottokkaran, Ranjith; Abbas, Hisham; Dalal, Vikram L.

    2016-04-25

    We report nanosecond domain time-of-flight measurements of electron and hole photocarriers in methylammonium lead iodide perovskite solar cells. The mobilities ranged from 0.06 to 1.4 cm2/Vs at room temperature, but there is little systematic difference between the two carriers. We also find that the drift mobilities are dispersive (time-dependent). The dispersion parameters are in the range of 0.4-0.7, and they imply that terahertz domain mobilities will be much larger than nanosecond domain mobilities. The temperature-dependences of the dispersion parameters are consistent with confinement of electron and hole transport to fractal-like spatial networks within nanoseconds of their photogeneration.

  20. Determination of iodide by volumetric titration in support of the oil eletrolabeling with {sup 123}I

    Energy Technology Data Exchange (ETDEWEB)

    Kenup-Cantuaria, Hericka O.H.; Brandao, Luis E.B., E-mail: hkenup@ien.gov.br, E-mail: brandao@ien.gov.br [Instituto de Engenharia Nuclear (IEN/CNEN-RJ), Rio de Janeiro, RJ (Brazil); Silva, Ademir X., E-mail: ademir@nuclear.ufrj.br [Coordenacao dos Programas de Pos-Graduacao em Engenharia (PEN/COPPE/UFRJ), Rio de Janeiro, RJ (Brazil). Programa de Engenharia Nuclear

    2015-07-01

    The accuracy in measuring flow rate in pipelines is essential task to control various technical parameters in an industrial plant in oil industry and its derivatives. For this reason, it becomes increasingly widespread the uses of organic molecules labeled with radioactive isotopes mainly because of the wide possibility in use of different radioisotopes also due to the new labeling techniques. This paper presents a study to develop an electrochemical technique for oil labeling with iodine -123 and to determine the yield of production by measuring the concentration of iodide (I{sup -}) during this process. The volumetric titration technique was applied as a basis for quantitative and qualitative measures to monitor the labeling process. The results indicate the technical proposal as a viable alternative for monitoring electro labeling process of lubricating oils with iodine -123. (author)